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WI0300192_Regional Office Historical File Pre 2018
Water Resources Environment& Quality February 5, 2018 Calista E. Campbell, EJI, Project Manager ExxonMobil Environrrlental Services Company 1900E. Linden Avenue, Building 28a Linden, NJ 07036 Subject: Permit Rescission Permit No. WI0300192 In -Situ Groundwater Remediation Permit Mecklenburg County Dear Ms, Campbell: ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Interim Director Reference is made to your request for rescission of the subject permit located at Former ExxonMobil Retail Facility #42094 in Mecklenburg County NC. Staff from the Mooresville Regional Office has agreed that a permit is no longer required. Therefore, in accordance with your request, In -Situ Groundwater Remediation Permit WI0300192 is rescinded, effective immediately. If in the future, you wish to operate a IN -Situ Groundwater Remediation system, you must first apply for and receive a new permit. Operating an injection system without a valid permit may result in the assessment of civil penalties and/or the use of other enforcement mechanisms available to the state, If it would be helpful to discuss this matter further, please do not hesitate to call Shristi Shrestha at (919) 807--6406. Sincerely, nda Culpepper, Interim Director Division of Water Resources Attachment(sj cc: Mooresville Regional Office - WQROS Central Files - Permit No, W10300.191 Scott Bostian, Arcadis, 801 Corporate Center Drive, Suite 300, Raleigh, NC 27607 Stale of North Carol ty i D'ivitiiora O Water Resource, Water Quality? egtotaat Operation Section 1 636 .MEut Service Center f ',Raleigh, North Carolina 27699-➢ 636 i19.707-9129 6/4112 3721 freedom drive, charlotte, nc - Googke Mips Goog To see all the details that are visible on the screen, use the "Print"' link next to the map. ikaaaroM maps.,,googie,corrthruaps?sugexp=chrome mod%3DO&q 3?21+freedonn+drive +charMatte,+nc&um= 18,'iew,... 111 Well Information System 2. Mecklenburg County, P o 1 33174 5502, Y: 55172&612 t Action✓ Morro Mar ARCADIS Infrastructure Water •Environrnent 8utldings ExxonMobil Environmental Services Corporation 1 St Quarterly Corrective Action Plan Monitoring Report — 2013 Former ExxonMobil Facility #42094 3721 Freedom Drive Charlotte, Mecklenburg County, North Carolina Groundwater Incident #6867 March 2013 Imagine the result ARCADIS Ryan Habersang, P.E. Enviror rental Eng C. Scott Bostlan, P.E. North Carolina P.E. No, 256 Senior Engineer SEAL 0✓5659 60 tQ 1St Quarterly Corrective Action Plan Monitoring Report — 2013 Former ExxonMobii Facility #42094 Prepared for: ExxonMobil Environmental Services Ms. Jewel Gox Project Manager 1016 W, Poplar Avenue Suite 106#232 Collierville, Tennessee 38017' Prep/free ©y. ARCADIS G&M of North Carolina, tnc, 801 Corporate Center Drive Suite 300 Raleigh, North Carolina 27607 Tel 919.854.1282 Fax 919.854.5448 Our Ref B0085851.0026 March 21, 2013 This document is intended only for the use of the individual or entity for which it was prepared and may contain information that is privileged, confidential and exempt from disclosure under applicable law. Any dissemination, distribution or copying of this document is strictly prohibited. 15T QUARTERLY CORRECTIVE ACTION PLAN MONITORING REPORT — 2013 Former ExxonMobil Facility #42094 3721 Freedom Drive Charlotte, Mecklenburg County, North Carolina Latitude 35°14'57" Longitude-80°53'53" (Reference Figure 1) Groundwater Incident #: Risk Classification: Reason for Risk Classification: Land Use Category: Source of Release: Date of Release Discovery: Estimated Quantity of Release: Cause of Release: Responsible Party: Property Owner: 15t Quarterly Corrective Action Plan Monitoring Report — 2013 6867 Intermediate Initial sampling above GCLs Industrial/Commercial Gasoline UST system November 1990 Unknown Unknown ExxonMobil Corporation ExxonMobil Environmental Service Attn: Ms. Jewel Cox 1016 W. Poplar Avenue Suite 106 #232 Collierville, TN 38017 901.850.9009 Robert Morris 5804 Sharon Road, Unit J Charlotte, NC 28226 704.399.0854 , a Professional Engineer for ARCADIS G&M of North Carolina, Inc. do certify that the information contained in this report is correct and accurate to the best of my knowledge. ARCADIS G&M of North Carolina, Inc. is licensed to practice geology and engineering in North Carolina. The certification numbers of the company are C-155 (geology) and C-1869 (engineering). 1st Quarterly Corrective Action Plan Monitoring Report — 2013 Executive Summary On behalf of ExxonMobil Environmental Services (EMES), ARCADIS G&M of North Carolina, Inc. (ARCADIS) completed the 2`d post -chemical injection groundwater monitoring and sampling event at former ExxonMobil Facility #42094 located at 3721 Freedom Drive in Charlotte, Mecklenburg County, North Carolina (the site). On February 19 — 20, 2013, ARCADIS completed the post -injection groundwater monitoring and sampling event to evaluate the effectiveness of the surfactant injection and to maintain compliance with the North Carolina Department of Environment and Natural Resources (NCDENR) Underground Storage Tank (UST) Program requirements. On February 19, 2013, nine (9) existing groundwater monitoring wells, MW-5, MW-6, MW- 7, MW-8, MW-9, MW-10, DW-1, DW-2, and DW-3, and two (2) injection wells, INJ-1 and INJ-2, were gauged to determine depth to bottom (DTB), depth to water (DTW), and depth to product (DTP), if present. DTW ranged from 15.07 feet below top of casing (btoc) in groundwater monitoring well MW-7 to 27.35 feet btoc in groundwater monitoring well MW-6. Groundwater was observed to flow towards the south which is consistent with historical observed groundwater flow. Free product was detected in groundwater monitoring well, MW-9 and injection well, INJ-2 during the February 19, 2013 groundwater gauging event at an apparent thicknesses of 0.45 feet and 1.89 feet, respectively. On February 20, 2013, groundwater samples were collected from seven (7) existing groundwater monitoring wells, MW-5, MW-6, MW-8, MW-10, DW-1, DW-2, and DW-3. Groundwater samples were collected on February 19, 2013 from monitoring well MW-7. The maximum concentrations of select dissolved phase chemicals of concern (COCs) detected during the February 19 - 20, 2013 groundwater sampling event are summarized in the table below: 1st Quarterly Corrective Action Plan Monitoring Report — 2013 Maximum Groundwater Concentrations (February 19 - 20, 2013) Chemical of Concern (CDC) Monitoring Well ID Concentration (pg/L) GCL (pg/L) Benzene MW-5 15,300 5,000 Toluene MW-10 23,600 260,000 Ethylbenzene MW-10 2,230 84,500 Xylenes (total) MW-10 13,900 85,500 MTBE MW-10 3,090 20,000 Diisopropyl ether DW-2 8,160 25,000 Naphthalene MW-10 899 6,000 Ethylene Dibromide MW-5 81.6 50 1,2-Dichloroethane DW-2 1,470 400 Trichforoethene MW-7 131 3,000 Tetrachloroethylene MW-7 464 700 Note: Concentrations in Bold exceed the applicable GCL ug/L = micrograms per liter MTBE = methyl -tertiary butyl ether The most recent monitoring and sampling data collected on February 19 - 20, 2013 compared to historical data indicates that COC concentrations have decreased or remained stable since the September 2012 surfactant injection and subsequent post -injection Aggressive Fluid Vapor Recovery (AFVR) events. Benzene, ethylene dibromide and 1,2- dicholorethane were the only COCs detected in concentrations exceeding the applicable North Carolina Gross Contamination Levels (GCLs). ARCADIS recommends further monitoring of groundwater COCs to evaluate the effectiveness of the September 2012 surfactant injection. The potential value of a second surfactant injection will be evaluated based on post -injection data trends. ARCADIS will continue monthly free product gauging and bailing activities at the site. Free product will be hand bailed and stored onsite in North Carolina Department of Transportation (NCDOT) approved 55-gallon steel drums pending removal and disposal. ARCADIS recommends adjusting the quarterly groundwater monitoring and sampling schedule to a semi-annual basis. A semi-annual groundwater monitoring and sampling Iv 1 st Quarterly Corrective Action Plan Monitoring Report — 2013 event is scheduled for September 2013. As outlined by the NCDENR Aquifer Protection Section — Underground Injection Control (UIC) Program's approved monitoring and sampling plan, all existing monitoring wells (MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and DW-1, DW-2 and DW-3) and injection wells (INJ-1 and INJ-2) associated with the site will be gauged to check for the presence of free product and to determine the potentiometric surface. As per the monitoring and sampling requirements of the UIC permit, groundwater samples will be collected using low flow methods from existing monitoring wells MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and DW-1, DW-2 and DW-3 for analysis of volatile organic compounds (VOCs) by Standard Method (SM) 6200B. Additionally, field parameters will be collected including conductivity, oxidation-reduction potential (ORP), and pH. A semi-annual Corrective Action Plan (CAP) monitoring report detailing the post - chemical injection groundwater monitoring and sampling event will be submitted to NCDENR Division of Water Quality — Aquifer Protection UIC Program and the NCDENR Division of Waste Management — UST Section for review and approval 45 days following receipt of the laboratory analytical results. Table of Contents Executive Summary 1.0 Site History and Characterization 2.0 Current Site Assessment Information 2.1 Free Product 2.2 Groundwater Gauging 2.3 Groundwater Sampling 2.4 Groundwater Analytical Results 3.0 Site Remediation 3.1 Remediation Activities to Date 4.0 Conclusions and Recommendations Tables Table 1 Table 2 Table 3 Figures Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 Groundwater Gauging Data Groundwater Parameters Groundwater Analytical Data Site Location Map Site Map Potentiometric Surface Map - February 19, 2013 Dissolved Phase Concentration Map - February 19 - 20, 2013 Benzene Isoconcentration Map - February 19 - 20, 2013 1,2-Dichloroethane Isoconcentration Map - February 19 - 20, 2013 Ethylene dibromide Isoconcentration Map - February 19 - 20, 2013 1 2 2 2 3 4 5 5 6 1st Quarterly Corrective Action Plan Monitoring Report -- 2013 1St Quarterly Corrective Action Plan Monitoring Report — 2013 Appendix Appendix A Approved NCDENR UIC Permit # W10300192 Appendix B Groundwater Analytical Report — February 19 - 20, 2013 1st Quarterly Corrective Action Plan Monitoring Report — 2013 1.0 Site History and Characterization Former ExxonMobil (Exxon) facility #42094 located at 3721 Freedom Drive, Charlotte, Mecklenburg County, North Carolina operated as a gasoline retail store and service station between 1970 and October 1990. All underground storage tanks (USTs) and ancillary equipment were closed by removal in November 1990 and prior to divestment of the site by Exxon. The UST system consisted of one 6,000-gallon gasoline UST, two 4,000-gallon gasoline USTs, one 4,000-gallon used oil UST and one 550-gallon heating oil UST. The site was re -developed as a vehicle repair facility between 1993 and 2001. Petroleum -impacted soil was discovered during the November 1990 UST closure at the base of the gasoline UST field and below one dispenser island. The cause and quantity of the release is unknown. A soil -vapor extraction (SVE) system utilizing two extraction wells operated intermittently at the site between August 1992 and July 1996. Additional soil samples were collected by Environmental Resources Management Inc. (ERM) in the vicinity of the former gasoline UST field, eastern dispenser island and former used oil UST in 2001 and 2002. Nineteen volatile organic compounds (VOCs) were detected above the soil -to -groundwater Maximum Soil Contaminant Concentrations (MSCCs), but below the applicable industrial/commercial MSCCs. Four VOCs (benzene, naphthalene, C5-C8 Aliphatics and C9-C12 Aromatics) were detected in concentrations above the residential MSCCs. Soil data indicated that the bulk of the petroleum -impacted soil is located between 11 and 15 feet below ground surface (bgs). The petroleum -impacted soil in areas away from the former UST field and dispenser island is attributed to the migration of petroleum - impacted ground water within the smear zone. The site is owned by Mr. Robert Morris and currently operates as a vehicle repair facility. The area surrounding the site is composed of commercially developed properties, mixed -use properties and residential properties. The nearest single-family residence is located approximately 130 feet west of the source area. ERM conducted a water supply well survey for the site in February 2001. Five inactive water supply wells have been identified within a 1,500-foot radius of the site. All wells were located northwest and topographically upgradient of the subject property. The nearest well was located approximately 1,350 feet from the source area. Municipal water service provided by the Charlotte -Mecklenburg Utilities Department is available to all properties in the surrounding area. No surface water bodies have been identified within 500 feet of the site. The site is located within the Charlotte geologic belt of the Piedmont physiographic province and is underlain by saprolite, a layer of weathered and variably decomposed bedrock. Soils at the site consist primarily of silt and clay based on soil boring logs for site monitoring wells and direct push soil borings. Saprolitic soil was encountered in all borings at depths greater than 10 feet bgs. Imported fill soil consisting of semi -plastic clay with 1s1 Quarterly Corrective Action Plan Monitoring Report — 2013 gravels was observed over much of the site. Partially weathered bedrock was encountered in soil borings at 22 feet and 55 feet bgs. Depth to groundwater at the site ranges from 17 to 28 feet bgs on average. The North Carolina Department of Environment and Natural Resources (NCDENR) Risk Classification for the site is "Intermediate" due to the presence of free product and exceedances of chemicals of concern (COCs) above the applicable North Carolina Gross Contamination Levels (GCLs) Standard. A site location map is presented as Figure 1 and a site map is presented as Figure 2. On June 27, 2012, ARCADIS received an approved Underground Injection Control (UIC) Permit #WI0300192 to conduct a surfactant chemical injection at the site. A surfactant injection was completed at the site on September 17 —19, 2012. The approved UIC Permit is included as Appendix A. 2.0 Current Site Assessment Information 2.1 Free Product Gauging activities performed on February 19, 2013 indicated the presence of free product in monitoring well MW-9 and injection well INJ-2 at an apparent thickness of 0.45 feet and 1.89 feet, respectively. Free product from monitoring well MW-9 and injection well INJ-2 were bailed by using a polyethylene bailer and nylon rope and stored onsite in a North Carolina Department of Transportation (NCDOT) approved steel 55-gallon drum pending disposal at an ExxonMobil approved waste disposal facility. Petroleum absorbent socks were also placed in monitoring well MW-9 and injection well INJ-2 at the completion of the free product recovery activities to facilitate passive free product recovery. Current and historical groundwater elevations along with free product thicknesses are summarized in Table 1. 2.2 Groundwater Gauging On February 19, 2013, ARCADIS personnel gauged existing groundwater monitoring wells MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and DW-1, DW-2 and DW-3 chemical injection wells INJ-1 and INJ-2. Gauging was conducted with an oil/water interface probe (IP) prior to purging and sampling to determine depth to bottom (DTB), depth to water (DTW) and depth to product (DTP), if present. The IP and attached tape, marked in 0.01-foot increments, were properly decontaminated before each use with Alconox soap and rinsed with distilled water. The DTW was measured from the marked survey point on the top of well casing (TOC). All measurements were recorded to the nearest 0.01-foot increment. Current and historical groundwater elevations are summarized in Table 1. 1st Quarterly Corrective Action Plan Monitoring Report — 2013 Depths to water on February 19, 2013 ranged from 15.07 feet below top of casing (btoc) in groundwater monitoring well MW-7 to 27.35 feet btoc in groundwater monitoring well MW-6. Potentiometric surface map for the February 19, 2013 groundwater gauging event are provided as Figure 3. The observed groundwater flow direction for the February 19, 2013 groundwater gauging event is towards the south. Groundwater elevation and flow direction are consistent with past trends at the site. 2.3 Groundwater Sampling On February 19, 2013, groundwater monitoring well MW-7 was purged of stagnant water. On February 20, 2013, groundwater monitoring wells MW-5, MW-6, MW-8, MW-10, DW-1, DW-2, and DW-3 were purged of stagnant water. Prior to purging, the amount of water to be removed was calculated using the following formula: 3,1415 x r2 x (TD-DTW) x 7.481 = gallons of water (1 well volume) Where: r = radius of well (in feet) TD = total depth of well (in feet) DTW = depth to water (in feet) In order to ensure that the water in the well after purging is representative of the water in the aquifer, a minimum of three well volumes were removed. Groundwater monitoring wells that did not generate three well volumes of water were purged dry and then given sufficient time to allow for recharging. All sampling tasks were completed within 24 hours of purging. Groundwater samples were obtained using a PROACTIVE SS Mega -Typhoon Pump & control box with low flow groundwater sampling techniques to collect groundwater parameters and to minimize turbidity during sample collection. Groundwater parameters were collected utilizing an YSI 556 Multi -Probe System (MPS) and flow through cell. A turbidity reading was collected before, during, and after purging. When turbidity decreased to below 10 Nephelometric Turbidity Units (NTU), or remained stable, a groundwater sample was collected from the tubing. Groundwater parameters including temperature, dissolved oxygen (DO), pH, conductivity, oxidation reduction potential (ORP), and turbidity are presented in Table 2. Groundwater samples collected from the monitoring wells on February 19 - 20, 2013 were placed in laboratory supplied containers and shipped on wet ice to TestAmerica Inc. in Nashville, Tennessee, for analysis of VOCs by Standard Method (SM) 6200B. The samples for analysis of VOCs by SM 6200B were collected in triplicate 40-milliliter volatile organic analysis (VOA) glass vials with Teflon -lined septa screw caps preserved with hydrochloric 1s` Quarterly Corrective Action Plan Monitoring Report — 2013 acid. The laboratory analytical reports and chain -of -custodies for the February 19 - 20, 2013 groundwater sampling event are included as Appendix B. 2.4 Groundwater Analytical Results Groundwater analytical data from the February 19 - 20, 2013 groundwater sampling event indicate the following: • Dissolved -phase concentrations of benzene were detected in concentrations exceeding the applicable North Carolina GCL standard of 5,000 pglL in groundwater monitoring wells MW-5 at 15,300 pgfL, MW-10 at 9,590 pg/L, and DW-2 at 5,850 pg/L. • Dissolved -phase concentrations of 1,2-dichloroethane were detected in concentrations exceeding the applicable North Carolina GCL standard of 400 pg/L in groundwater monitoring wells MW-5 at 928 pglL and DW-2 at 1,470 pg/L. • Dissolved -phase concentrations of ethylene dibromide were detected in concentrations exceeding the applicable North Carolina GCL standard of 50 pglL in groundwater monitoring wells MW-5 at 81.6 pg/L. The maximum dissolved -phase concentrations for select COCs from the February 19 - 20, 2013 groundwater sampling event and the associated groundwater monitoring wells in which they were detected are listed below: Maximum Groundwater Concentrations (February 19 - 20, 2013) Chemical of Concern (COC) Monitoring Well ID Concentration (pg/L) GCL. (pg/L) Benzene MW-5 15,300 5,000 Toluene MW-10 23,600 260,000 Ethylbenzene MW-10 2,230 84,500 Xylenes (total) MW-10 13,900 85,500 MTBE MW-10 3,090 20,000 Diisopropyl ether DW-2 8,160 25,000 Naphthalene MW-10 899 6,000 Ethylene Dibromide MW-5 81.6 50 1,2-Dichloroethane DW-2 1,470 400 Trichloroethene MW-7 131 3,000 Tetrachloroethylene MW-7 464 700 Note: 1st Quarterly Corrective Action Plan Monitoring Report — 2013 Concentrations in Bold exceed the applicable GCL pg/L = micrograms per liter MTBE = methyl -tertiary butyl ether Current and historical groundwater analytical results are presented in Table 3. A groundwater analytical map is presented as Figure 4. Isoconcentration maps depicting the dissolved -phase extent of COCs exceeding the applicable North Carolina GCL Standards are presented as Figure 5 through Figure 7, respectively. 3.0 Site Remediation 3.1 Remediation Activities to Date Summarized in the table below is a chronology of remediation activities performed at the site to date: Remediation Activities to Date Date Activity 1990 Closure by removal of all UST systems. 1992-1996 Soil -Vapor Extraction soil remediation (SVE). March 2002 AFVR free product recovery. January 27-February 3, 2003 Mobile Multi -Phase Extraction (MMPE) Event —15.5 gallons of vapor phase hydrocarbons removed from monitoring wells MW-5 and MW-9. April 22, 2003 Passive free product skimmers installed in monitoring wells MW-5 and MW-9. November 2009 96-hour MMPE event conducted on MW-9. 37.87 pounds of TPH recovered March 2010 96-hour MMPE event conducted on MW-5 and MW-9. 239.81 pounds of TPH and 3,520 gallons of groundwater recovered. June 2010 96-hour MMPE event conducted on MW-5 and MW-9. 34.13 pounds of TPH and 6,735 gallons of groundwater recovered. September 27th - October 1, 2010 96-hour MMPE event conducted on MW-5 and MW-9. 36.39 pounds of TPH and 4,700 gallons of groundwater recovered. December 13th — 16th, 2010 96-hour MMPE event conducted on MW-5 and MW-9. 46.55 pounds of TPH and 2,600 gallons of groundwater recovered. June 9, 2011 Manual hand bailing of free product from MW-5. 0.08 gallons of free product recovered. June 29, 2011 8-hour AFVR event conducted on MW-5. 8.81 pounds of TPH and 264 gallons of groundwater recovered. August 24, 2011 Manual hand bailing of free product from MW-5. 0.01 gallons of 1st Quarterly Corrective Action Pian Monitoring Report — 2013 free product recovered September 19, 2011 Manual bailing of free product from MW-5. 0.01 gallons of free product recovered October 6, 2011 Manual bailing of free product from MW-9. 0.50 gallons of free product recovered October 12, 2011 Manual bailing of free product from MW-9. 0.09 gallons of free product recovered November 29, 2011 Manual bailing of free product from MW-9. 0.5 gallons of free product recovered January 16, 2012 Manual bailing of free product from MW-9. 0.02 gallons of free product recovered September 17-19, 2012 Surfactant Injection. 1,150 gallons of surfactant injected into MW- 5, MW-9, INJ-1, and INJ-2. September 20, 2012 8-hour AFVR event conducted on MW-5, MW-9, INJ-1, and INJ-2. 97.29 pounds of TPH and 303 gallons of petroleum impacted groundwater and surfactant recovered. September 21, 2012 8-hour AFVR event conducted on MW-5, MW-9, INJ-1, and INJ-2. 30.12 pounds of TPH and 222 gallons of petroleum impacted groundwater and surfactant recovered. September 28, 2012 8-hour AFVR event conducted on MW-5, MW-9, and MW-10. 28.69 pounds of TPH and 226 gallons of petroleum impacted groundwater and surfactant recovered. October 2, 2012 8-hour AFVR event conducted on MW-5, MW-9, MW-10, and INJ- 1. 40.38 pounds of TPH and 303 gallons of petroleum impacted groundwater and surfactant recovered. October 3, 2012 8-hour AFVR event conducted on MW-5, MW-9, MW-10, and INJ- 1. 34.34 pounds of TPH and 320 gallons of petroleum impacted groundwater and surfactant recovered. 4.0 Conclusions and Recommendations Free product was detected at the site during the February 19, 2013 groundwater gauging events. Post -chemical injection groundwater sampling activities conducted on February 19 - 20, 2013 indicated benzene was detected in groundwater samples collected from monitoring wells MW-5 at 15,300 pgIL, MW-10 at 9,590 pgfL, and DW-2 at 5,850 pglL exceeding the applicable North Carolina GCL standard of 5,000 pgtL. 1,2-dicholoroethane was detected in groundwater samples collected from MW-5 at 928 pgIL and DW-2 at 1,470 pg/L exceeding the North Carolina GCL standard of 400 pglL. Ethylene dibromide was detected in 1st Quarterly Corrective Action Plan Monitoring Report-2013 groundwater samples collected from monitoring well MW-5 at 81.6 pgfL exceeding the applicable North Carolina GCL standard of 50 pg/L. Dissolved -phase concentrations of COCs at the site decreased or remained stable following the September 2012 surfactant injection and subsequent post -injection AFVR events. Groundwater parameters collected before and after the surfactant injection and AFVR events have remained stable. ARCADIS recommends further monitoring of groundwater COCs to evaluate the effectiveness of the surfactant injection. The value of a second surfactant injection will be evaluated based on post -injection data trends. ARCADIS will continue monthly free product gauging and bailing activities at the site. Free product will be hand bailed and stored onsite in North Carolina Department of Transportation (NCDOT) approved 55-gallon steel drums pending removal and disposal. ARCADIS recommends adjusting the quarterly groundwater monitoring and sampling schedule to a semi-annual basis. A semi-annual groundwater monitoring and sampling event is scheduled for September 2013. As outlined by the NCDENR Aquifer Protection Section — Underground Injection Control (U1C) Program's approved monitoring and sampling plan, ail existing monitoring wells associated with the site (MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and DW-1, DW-2 and DW-3), and injection wells (INJ-1 and 1NJ-2) will be gauged to check for the presence of free product and to determine the potentiometric surface of the site. As per the monitoring and sampling requirements of the UIC permit, groundwater samples will be collected using low flow methods from existing monitoring wells MW-5, MW-6, MW-7, MW-8, MW-9, MW-10 and DW-1, DW-2 and DW-3 for analysis of VOCs by SM 6200B. Additionally, field parameters will be collected including conductivity, oxidation-reduction potential (ORP), and pH. A quarterly Corrective Action Plan (CAP) monitoring report detailing the post -chemical injection groundwater monitoring and sampling event will be submitted to NCDENR Division of Water Quality — Aquifer Protection U1C Program and the NCDENR Division of Waste Management — UST Section for review and approval 45 days following receipt of the laboratory analytical results. ARCAD S Tables Table 9: Groundwater Gauging Data Revision Date: 3/25/2013 Incident Number: 6867 Facility I.D. # Former ExxonMobll Faeilitvj(42094 Monitoring Well I.D. Date Installed Gauging i Date Total Casing Depth (ftbgs) Screened Interval (ft bgs) Top of Casing Elevation (ft) Depth to Water (ft 6TDC) Depth to Product (N BTDC) Product Thickness (ft) Ground Water Elevation (ftASL) Measured Depth to Bottom (ft) Well Diameter MW-1 1/7/1991 1/8/1991 10.00 10-25 94.14 14.42 - - 79.72 25.00 2' 1996 Well Abandoned / Destroyed MW-2 1A11991 1/8/1991 10.00 ( 10-25 92.85 12.77 - - 80.08 1 25.00 1 2' 1996 Well Abandoned / Destroyed MW-2R 2/13/2001 2/14/2001 13.00 13-26 - 19.74 - - - - 1" 6/6/2001 - 18.03 - - - - 1" 10/12/2001 - 21.15 21.11 0.04 - - 1" 11/6/2001 - 21.40 21.37 0.03 - - 1" 12/4/2001 - 21.81 21.80 0.01 - - 1' 1/10/2002 - 21.62 21.59 0.03 - - 1' Well abandoned and replaced by MW-5 n January 2002 NIVJ.9 1Rl1991 1/8/1991 5 5-20 91.74 11.43 - - 80.31 20.00 2' 1996 Well Abandoned / Destroyed MW-4 1/7/1991 1/8/1991 10 1 10-25 1 97.02 1 15.50 r - - 1 81.52 1 25.00 1 2" 1996 Well Abandoned 1 Destroyed MW-5 1/1612002 1/23/2002 15.00 15-35 96.52 21.10 20.75 0.35 75.68 - 4' 2/5/2002 96.52 20.30 19.95 0.35 76.48 - 4" 3/19/2002 96.52 19.50 19.35 0.15 77.13 - 4' 4/13/2002 96.52 19.08 18.70 0.38 77.72 - 4' 5/10/2002 96.52 19.13 19.12 0.01 77.40 -- 4' 6/27/2002 96.52 21.94 20.22 1.72 75.85 - 4' 7/25/2002 96.52 22.79 21.11 1.68 74.97 - 4' 8/15/2002 96.52 23.32 21.58 1.74 74.49 - 4' 9/16/2002 96.52 23.26 21.55 1.71 74.53 - 4" 10/4/2002 96.52 23.30 21.52 1.78 74.54 - 4' 11/25/2002 96.52 21.16 19.05 2.11 76.92 - 4' 12/23/2002 98.52 19.70 18.75 0.95 77.52 - 4" 1/16/2003 96.52 18.68 18.30 0.38 78.12 - 4' 2/19/2003 96.52 17.91 17.85 0.06 78.65 - 4' 3/19/2003 96.52 19.72 19.63 0.09 76.87 - 4" 4/22/2003 96.52 13.96 13.95 0.01 82.57 - 4' 5/30/2003 96.52 12.64 12.63 0.01 83.89 - 4' 6/27/2003 96.52 12.37 - - 84.15 - 4" 7/15/2003 96.52 12.36 12.35 0.01 84.17 - 4' 8/11/2003 96.52 12.44 12.43 0.01 84.09 - 4' 9/2/2003 96.52 12.39 12.38 0.01 84.14 - 4" 11/22/2004 96.52 17.16 - - 79.36 - 4' 1114/2005 96.52 20.99 - - 75.53 - 4' 1015/2006 96.52 17.43 - - 79.09 - 4" 6/12/2007 96.52 16.35_ - - 80.17 - 4' 6/19/2008 96.52 19.61 - - 76.91 35.67 4' 4/28/2009 96.52 17.21 16.91 0.30 79.53 35.67 4" 12,3/2009 96.52 18.40 18.35 0.05 78.16 - 4' 3/2812010 96.52 14.81 - - 81.71 - 4' 4/2/2010 96.52 23.75 - - 72.77 - 4" 4/28/2010 96.52 15.57 - - 80.95 - 4' 6/28/2010 96.52 17.09 - - 79.43 - 4' 7/2/2010 96.52 21.59 - - 74.93 - 4" 10/21/2010 96.52 2022 - - 76.30 35.63 4" 5/17/2011 96.52 18.29 18.03 0.26 78.42 - 4' 6/9/2011 96.52 18.53 18.27 0.26 78.18 35.63 4' 8/24/2011 96.52 20.40 20.38 0.02 76.13 - 4' 9/19/2011 96.52 21.16 21.11 0.05 75.40 - 4' 10/6/2011 96.52 20.66 - - 75.86 - 4' 10/12/2011 96.52 20.90 - - 75.62 - 4" 11/29/2011 96.52 20.43 - - 76.09 - 4' 12119/2011 96.52 20.20 - - 76.32 - 4" 1/16/2012 98.52 19.41 - -- 77.11 - 4' 2/6/2012 96.52 18.79 - - 77.73 - 4' 311/2012 96.52 18.73 - - 77.79 - 4' 5/17/2012 96.52 16.29 - - 78.23 - 4" 915/2012 778.85 19.96 -- _ - 758.89 - 4' 11/18/2012 778.85 21.49 - - 757.36 - 4" 2/19/2013 778.65 19.53 - - 759.32 35.3 4" MW-6 1/16/2002 21512002 15.00 15-40 105.17 28.24 - - 76.93 - 2' 10/5/2006 105.17 24.33 - - 80.84 - 2" 6/12/2007 105.17 22.94 - - 82.23 - 2' 4/2812009 105.17 25.52 - - 79.65 40.00 2' 1213/2009 105.17 25.64 - - 79.53 40.00 2' 4/28/2010 105.17 22.63 - - 82.54 - 2" 10/21/2010 105.17 24.61 - -- 80.56 40.00 2' 5/17/2011 105.17 26.22 - - 78.95 40.03 2' 10/6/2011 105.17 27.97 - - 77.20 - 2" 3/1/2012 105.17 26.42 - - 78.75 40.03 2' 9/5/2012 787.51 26.13 - - 761.38 40.05 2' 11/18/2012 787.51 28.74 - - 758.77 40.05 2" 2119/2013 787.51 27.35 - - 760.16 39.90 2" Page 1 of 3 Table 1: Groundwater Gauging Data Revision Date: 3/25/2013 Incident Number: 6867 Facility I.D. Former ExxonMobil Facility #42094 Monitoring Well I.D. Date Installed Gauging Date Total Casing Depth (ft bgs) Sntervald (ft bgs) Top of Casing Elevation (ft) Dyyatertho ((ft BTOC) Dpth to Product (ft BTOG) Product Thl kne55 (ft) Ground Water Elevation (ft ASL) Measured Depth to Bottom (ft) Well Diameter MW-7 1/17/2002 2/5/2002 15.00 15-30 91.33 16.41 - - 74.92 - 2' 11/22/2004 91.33 13.89 - - 77.44 - 2" 10/5/2006 91.33 13.77 - - 77.56 - 2" 6/12/2007 91.33 13.10 - - 78.23 - 2' 6/19/2008 91.33 15.33 - - 76.00 29.88 2' 4/28/2009 91.33 13.32 - - 78.01 30.02 2' 12/3/2009 91.33 14.44 - - 76.89 30.00 2' 4/28/2010 91.33 12.13 - - 79.20 - 2' 10/21/2010 91.33 20.07 - - 71.26 31.01 2' 5/17/2011 91.33 14.57 - - 76.76 30.01 2' 10/6/2011 91.33 16.18 - - 75.15 - 2" 311/2012 91.33 14.75 - - 76.58 30.01 2' 9/5/2012 773.62 15.51 - - 758.11 29.90 2" 11/18/2012 773.62 16.98 - - 756.64 29.90 2' 2/19/2013 773.62 15.07 - - 758.55 29.90 _ 2" MW-8 1/17/2002 2/5/2002 14.00 14-24 92.59 16.98 - - 75.61 - 2' 11/22/2004 92.59 12.59 - - 80.00 - 2' 10/512006 92.59 13.86 - - 78.73 - 2' 6/12/2007 92.59 12.81 - - 79.78 - 2" 6/1912008 92.59 16.16 - - 76.43 23.84 2' 4/28/2009 92.59 13.52 - - 79.07 23.97 2" 12/3/2009 92.59 _ _ 14.97 - - 77.62 24.00 2' _ 4/28/2010 92.59 12.16 - - 80.43 - 2' 10/21/2010 92.59 20.11 - - 72.48 23.97 2' 5/17/2011 92.59 14.04 - - 78.55 23.98 2' 10/6/2011 92.59 17.11 - - 75.48 - 2' 3/1/2012 92.59 15.15 - - 77.44 23.98 2' 9/5/2012 774,33 16.39 - - 757.94 24.00 2' 11/18/2012 774.33 17.67 - - 756.66 24.00 2' 2/19/2013 774,33 16.18 - - 758.15 23.90 2' _ AdY1/-9 6/ 212002 9/16/2002 17.00 17$2 98.47 23.91 23.62 0.29 74.77 32.00 2' 10/4/2002 98.47 23.75 23.49 0.26 74.91 - 2' 11/25/2002 98.47 21.19 - - 77.28 - 2" 12/23/2002 98.47 20.60 - - 77.87 - 2' 1/16/2003 98.47 20.03 - - 78,44 - 2' 2/19/2003 98.47 19.46 - - 79.01 - 2" 3/19/2003 98.47 19.03 18.72 0.31 79.67 - 2' 4/22/2003 98.47 15.73 15.71 0.02 82.75 - 2' 5/30.12003 98.47 14.65 14.64 0.01 83.83 - 2" 6/27/2003 98.47 14.18 - - 84.29 - 2' 7115/2003 98.47 14.11 - - 84.36 - 2' 8/11/2003 98.47 14.10 - - 84.37 - 2" 9/2/2003 98.47 14.00 - - _ 84.A7 - 2' 11/2212004 98.47 18.88 - - 79.59 - 2' 11/4/2005 98.47 20.90 - - 77.57 - 2" 10/5/2006 98.47 19.19 - - 79.28 - _ 2' 6/12/2007 98.47 18.00 - - 80.47 - 2' 6/19/2008 98.47 21:24 - - 77.23 31.81 2" 4128/2009 98.47 19.66 18.60 1.06 79.59 - 2' 12/3/2009 98.47 20.22 20.20 0.02 78.26 -- 2' 3128/2010 98.47 15.53 -- - 82.94 - 2" 4/212010 98.47 21.10 - - 77.37 - 2' 4/28/2010 98.47 17.27 -- - 81.20 - 2' 6/28/2010 98.47 18.81 - - 79.66 - 2' 7/212010 98.47 20.92 - - 77.55 - 2" 10/2112010 98.47 21.73 - - 76.74 32.02 2' 5/17/2011 98.47 19.88 - - 78.59 31.95 2" 14/6/2011 98.47 22.73 22.00 0.73 76.27 _ - 2' 10112/2011 98.47 22.74 22.21 0.53 76.12 - 2' 11/129/11 98.47 23.27 21.89 1.38 76.21 - 2' 12/19/2011 98,47 22.23 21.91 0.32 76.47 - 2" 1/1612012 98.47 21.32 21.30 0.02 77.16 - 2' 2/6/2012 98.47 20.65 - - _ 77.82 - 2' 311/2012 98.47 20.50 - - 77.97 - 2' 5/17/2012 98.47 20.30 - - 78.17 - 2' 9/5/2012 781.03 21.69 - - 759.34 - 2' 11/18/2012 781.03 23.04 - - 757.99 - 2" 2/19/2013 781.03 21.75 21.30 0.45 759.61 32.15 2" Page 2 of 3 Table 1: Groundwater Gauging Data Revision Date: 3/25/2013 Incident Number: 6867 Facility I.D. # Former ExxonMobil Facility/142094 Monitoring Well LD. Date installed Gauging Date Total Casing Depth(ff Screened interval (ft bgs) Top of Casing Elevation( Depth to Water (ft BTOC) Depth to Product (ft BTOC) Product Thickness (ft) Ground Water Elevation ASL) Measured Depth to Bottom ft} Welt Diameter MW-10 8/27/2012 9/5/2012 27.00 12-27 780.83 21.70 - - 759.13 26.33 2' 11/18/2012 23.15 - - 757.68 26.33 2' 2/19/2013 21.47 - - 759.36 26.35 2" DW-1 1/18/2002 2/52002 65.00 70-79 96.32 20.60 - - 75.72 - 2" 10/5/2006 96.32 17.49 - - 78.83 - 2' 6112/2007 96.32 16.55 - - 79.77 - 2' 6/19/2008 96.32 19.35 - - 76.97 80.27 2" 4/28/2009 96.32 17.40 - - 78.92 81.60 2' 12/3/2009 96.32 18.36 - - 77.96 80.25 2" 4/28/2010 96.32 15.62 - - 80.70 - 2" 10121I2010 96.32 19.43 - - 76.89 80.49 2" 5/17/2011 96.32 18.04 - - 7828 80.31 2" 10/6/2011 96.32 20.48 - - 75.84 - 2' 3/1/2012 96.32 18.72 - - 77.60 81.50 2' 9/5/2012 NS 19.82 - - NS 81.39 2" 11/18/2012 NS 21.33 - - NS 81.30 2" 2119/2013 NS 19.55 - - NS 80.00 2" DW-2 8/27/2012 9/5/2012 44.00 34-44 778.26 19.49 - - 758.77 44.96 2' 11/18/2012 20.57 - - 757.69 44.96 2' 2/19/2013 19.44 - - 758.82 45.00 2' DW-3 8/29/2012 9/5/2012 44.00 34-44 780.95 21.52 - - 759.43 43.75 2" 11/18/2012 22.83 - - 758.12 43.75 2" 2/19/2013 21.50 - - 759.45 43.40 2" INJ-1 8/28/2012 9/5/2012 23.00 13-23 781.07 21.65 - - 759.42 23.00 2' 11/18/2012 22.71 - - 758.36 23.00 2" 2/19/2013 21.39 - - 759.68 23.09 2' INJ-2 8/28 8/29/12 9/5/2012 23.00 13-23 778.89 20.10 - - 758.79 23.00 2" 11/18/2012 21.61 - -- 757.28 23.00 2" 2/19/2013 21.27 19.38 1.89 759.00 23.00 2" Notes: Site resurveyed by ARCADIS U.S. Inc on September 27, 2012 NS = Not surveyed BTOC = Below top of well casing - = Not measured or not available ft = feet ft ASL = feet below arbitrary site revel bgs = below ground surface Groundwater elevation corrected for the presence of free product using the formula: Top of Casing Etevation - (Depth to Water - (Product Thickness x 0.73)) Page 3 of 3 1 Table 2: Groundwater Parameters Revision Date: 3/25/2013 Incident Number: 6867 Facility ID #: Former ExxonMobil Facility #42094 Well ID Date Temp (°C) pH (SU) DO (mg/!_) Cond. (pmhos/c 196 Turbidity (NTU) 8.79 Redox (mV) -55.5 MW-5 9/5/2012 24.30 5.88 0.06 11/19/2012 22.31 6.30 0.13 610 71.26 -17.8 2/20/2013 20.29 6.31 0.86 904 28.54 -180.8 MW-6 9/5/2012 23.06 4.96 1.06 87 24.0 135.0 11/19/2012 20.35 5.50 1.65 9.6 132.8 120.0 2/20/2013 19.68 5.33 2.12 105 86.87 76.8 MW-7 9/5/2012 25.33 6.13 0.18 174 22.9 91.5 11/19/2012 20.73 6.23 0.18 181 448.0 93.8 2/19/2013 16.01 6.21 1.37 189 227.1 84.8 MW-8 9/6/2012 24.21 5.62 0.38 104 21.9 116.9 11/19/2012 21.22 5.87 0.22 121 166.6 134.9 2/20/2013 20.73 5.81 0.59 124 89.84 33.0 MW-9 9/6/2012 22.77 6.03 0.18 320 17.10 19.9 11/19/2012 17.74 6.31 0.16 677 42.44 -12.0 MW-10 9/6/2012 22.84 5.64 6.33 144 4.50 126.2 11/19/2012 19.17 5.79 0.26 169 28.93 118.5 2/20/2013 17.04 5.99 1.01 252 40.37 -51.6 DW-1 9/5/2012 23.59 5.66 0.09 166 1.69 -45.0 11/19/2012 21.55 6.60 0.08 177 4.57 -101.8 2/20/2013 20.37 6.55 0.72 185 6.03 -252.9 DW-2 9/6/2012 26.03 6.20 1.24 380 - 57.1 -102.9 11/19/2012 23.20 6.25 0.17 418 170.5 11.6 2/20/2013 17.99 6.37 1.37 446 80.99 -151.3 DW-3 9/6/2012 21.92 5.75 3.97 258 11.4 109.0 11/19/2012 18.65 6.04 0.16 286 9.93 16.9 2/20/2013 18.55 5.94 0.62 274 47.28 3.0 Page 1 of 1 Table 3: Groundwater Analytical Data Revision Date: 3/25/2013 Incident Number 6867 Facility ID 0: Former ExxonnMobil Facility #42094 Methods---> MADEP VPH/EPH (pg/L) Voiatle Organic Compounds by SM6200 S {his orical data used 602/6230D) (pg/L)' 504.1/6200B 3030C 300 6010C Metals Contaminate of Concern}-> C5-C8 Aliphatics (Unadjusted) C9-C1 2 Aliphatics (Unadjusted) C9-C1 D Aromatics Total BTEX Benzene Ethylbenzene Total xylenes w o. w c o o cv cis -1, 2-D l chtoroet h o n e Trans-1,2-Dichloroethene a 0 a o a t d n-Butylbenzene a c a N a a coU va, n-Aropylbenzene a c a)a. N c a 0 $ w a c a. `d n z Trichloroethene Tetrachloroethene a a 1,3,5-Trimethyl benzene 1,2,4-Trimethylbenzene (Ethanol m W i m Sulfate (mglL) E E -if Q..o E u Calcium (mg1L) Well ID Date GCLs--> NE NE NE NE 5,000 260.000 ; 84,500 85,500 20.000 70,000 400 70,000 100,000 600 6.900 8,500 30.000 25,000 6,000 3,000 700 70.000 25,000 28,500 NE 50 15,000 NE NE NE NE NE MW-1 12/1/1990 - -- -- 564 509 6 2 47 18 193 ND 13 - - - - - - - ND ND - - - - ND - - - - - - 2/1/1991 - - - 1,654 1,500 36 ND 118 ND 1,800 - - - - - - - - - - ND -- -- - - - - - - - - - - 511N991 - - -- 649 590 16 ND 43 44 410 - -- - - - - - - - ND - - - - - - - - - - -- - 8/1/1991 - - - 849 830 7 2 10 ND 300 - -- - - -- - - - - ND - - _- - - -- - -- -- - - - -- 10/1/1991 - - - 702 630 25 8 39 4 180 - -- - - - - - - - ND - - - - - - - - - - - -- 1/1/1992 - - - 492 440 16 7 29 55 200 -- -- - - - - - -- - ND - -- -_ - - - - - -. -- - - 10/1/1992 - - - 106 86 9 2.7 8.2 11 170 - - - - - - - - - ND - - - - - - - - - -- - - 3/1/1993 -- - - 236 170 16 13 37 16 190 - - - - - - - - - ND - - - - - - - - - - - -- Well Abandoned/Destroyed MW-2 12/1/1990 -- -- - 13,720 6,355 2,083 1,206 4,076 757 1,377 - - - - - - - - - ND - -- -- -- ' - - - - - -- -- - 2/1/1991 - - - 71,500 29,000 30,000 2,000 10,500 ND 4,700 - - - - - - - - - ND - - - - - - - - - - - - 5/1/1991 -- -- - 76.000 32,000 31,000 2,200 10,800 ND 4,700 - - - -- - - - - - ND - - -- -. - - - - - - - -- 8/1/1991 - - - 66.700 28,000 27,000 1,800 9,900 ND 5,000 - - - - - - - - - ND - - - - - - - - - - - - 10/1/1991 - - - 69.300 28,000 29,000 2,000 10,300 ND 4,100 - -- -- -- - -- - - - ND - - - - - - - -- - - - - 3/1/1993 - - - 51.400 21,000 21,000 1,400 8,000 ND 3,000 - - - - - - - - - ND - - - - - - - - - - - - 3/1/1994 - - - 43.040 17,000 17,300 1,280 7,460 ND 3,680 r -- -- -- -- - -- -- -- -- ND -- - - -- -- - - - -- -- - - 1/1/1995 - - - 114,800 53,600 43,200 2,700 15,300 ND - 1.200 ND - - - - - - - ND ND - - - - 700 - - - - - - 2/6/1996 - - - 139,500 27,400 43,200 10.100 58,800 ND 7,480 600 400 - - - - - - - ND 880 -- - - - ND - - - -- -- - 11/511997 - - - 20,150 2,950 2.480 1.690 13.030 5,000 ND ND ND - - - - - - - ND NO - - - - ND - - - - - - Well Abandoned/Destroyed MW-2R 2/14/2001 ND I ND I ND 101,900 45,400 I 37,900 2,000 16,600 ND 13,800 I 1,550 ND I - - - - - -- - ND ND - - - - 550 83 - - - - - WeII abandoned and replaced by MW-5 in January 2002 MW-3 12/1/1990 - - - 3 ND ND ND 3 ND ND - - - - - - - - - ND - -- - - -- - - - - - - - 2/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - - - - - - - - -- - - - 5/1/1991 - -- -- 13 5 6 ND 2 ND ND - - - - - - - - - ND - - - - - - - -- - - - - 8/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - -- - -- - - - - -. - - - 1/1/1992 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - - - __ - - - - - -- __ - 10/1/1992 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - -- - - - - - - - - - - 3/1/1993 - - - ND ND ND ND ND ND ND - - - - _ - - - - - ND - -- - -- - - - - - -- __ - 2/1/1991 - _ - ND ND ND ND ND ND ND - - - - - - - - - ND - -- - - - - - - - - - - 5/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - -- - -- - - - - - _- -_ __ 8/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - - - - - - - - - - - - 10/1/1991 - - - 40 17 15 2 6 ND ND - - - - - - - - - ND -- - - - - - - - - - -. __ 1/1/1992 - - - ND ND ND ND ND ND ND - - - - - - - - - ND - - - - - - - - - - - - 10/1/1992 - -- -- ND ND ND ND ND ND ND - - - - - - - - - ND - -- - - - - - - .. -- - -- 3/1/1993 - - - ND ND ND ND ND ND ND - - - - - - - _ - - ND - - - - - - - - - - - Well Abandoned/Destroyed MW-4 12/1/1990 - - - I 3 I ND ND ND 3 ND I ND 1 - - - - - - ND - - - - - - - - - - Well MW-5 1/23/2002 102,000 15.900 ND 60.940 33.200 18.700 1,240 7.800 680 8,910 2,390 ND ND 1.7 - - - -- - 2.2 5.8 - - - - 260 122 - - - - - 6/19/2008 - - - 81.390 34,000 28,700 2.390 16,300 311 7,020 - - - - - - - - - - _. - - - - - - - - - _. - 4/28/2010 - - - 68.750 31,100 24,100 1.750 11.800 302 6,360 - - - - - - - - - - - - - - - - - - - - - - 10/21/2010 - - - 64.610 25,800 25,100 1,610 12,100 210 5,400 - - - - - - - - - - - - - __ - - - - - - - - 10/6/2011 - - - 64.110 31,800 20,800 2,240 9.270 114 5,850 1,710 276 0.950 <0.500 55.0 8.23 185 61.9 947 8.96 6.33 402 490 1,750 398 136 -- - - - - - 3/1/2012 - - - 43,810 22,200 13,000 1.760 6.850 59.8 2,760 1,110 224 <10.0 RL1 <10.0 RL1 56.2 <10.0 RL1 202 55.6 970 12.6 <10.0 RL1 317 478 1,630 <2,000 RL1 56.98 - - - - - - 9/5/2012 - - - 66,830 30,300 24,400 1.730 10,400 116 6.650 1,820 225 1.40 <0.500 59.2 7.24 145 46.9 848 25.0 13.8 524 546 1,730 <100 184 - 1.07 <0.0100 7.05 <0.0500 24.3 11/19/2012 - - - 24,361 13,000 6,120 841 4.400 65.6 3.050 796 102 <50 <50 66.4 <50 <50 <50 <500 <50 <50 <50 343 1,170 <10.000 <50.0 - - - - - - 2/20/2013 - - - 27,986 15,300 7.720 816 4,150 86.5 4.600 928 133 <5.00 <5.00 37.4 5.47 86.3 25.3 431 8.99 9.06 144 290 952 <1.000 81.6 - -- -- - - - M1N 6 1/23/2002 ND ND ND ND ND ND ND ND ND ND ND ND ND ND - - - - - ND ND - - - -- ND ND - - - - - r 12/3/2009 - - - ND <1.00 <1.00 <1.00 <3.00 <1.00 r - - - - - - - -- - -- - - - - - - - - - - - - 5/17/2011 - - - ND <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.540 - <0.500 - - - - - - 9/5/2012 - - - ND <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 <100 <0.500 - <1.00 <0.0100 0.388 <0.0500 11.0 11/1912012 - - - 74 24.2 31.0 2.54 16.0 <0.500 2.44 1.84 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 <0.500 <0.500 0.604 1.67 <100 <0.500 - - - - - - 2/20/2013 -- - - 101 16.5 35.4 4.67 44.6 <0.500 0.881 <0.500 <0.500 <0.500 <0.500 0.916 <0.500 1.01 <1.00 <5.00 <0.500 <0.500 <0.500 4.95 15.9 <100 <0.500 -- -- - - - - Page 1 of 2 Table 3: Groundwater Analytical Data Revision Date: 312512013 Incident Number: 6867 Facility ID #: Former ExsonMobll Facility #42094 Methods-> MADEP VPH/EPH (pg1L) Volatile Organic Compounds by SM6200 B (his orical data used 60216230D) (141L)1 504.1/62006 3030C 300 6010C Metals Contaminate of Concern--> C5-CB3 Allphatics (Unadjusted) C9-C12 Allphatics (Unadjusted) E G v Total BTEX Benzene Ethytbenzene Total xylenes - 1,2-Dichloroethane cis-1,2-Dichloraethene m c .c 41 o U 1,2-Dichloropropane n-Butyibenzerte sec-Butylbenzene n-Propyibenzene IyN C N Naphthalene Trichloraethene Tetrachloroethene m a r i7' r 1, 2,4-Trimethyl b e nzena `o u w Lead (pgnL) Sulfate (mglL) Arsenic (mgIL) g Q E is Calcium (mg/L) Well ID Dale GCLs---> NE NE NE NE 5,000 260,000 84,500 85,500 20,00D 70,000 400 70,000 100,000 600 6,900 8,500 30.000 25,000 6,000 3,000 700 70,000 25,000 28,500 ' NE 50 15,000 NE NE NE NE NE MW-7 1123/2002 1,880 ND ND 42 40.3 1.7 ND ND 12.4 114 3.3 170 , 5.5 ND ` - -- -- - - 940 5,760 -- -- - - ND 7 - - - -- - 12)312009 - - - 38 31 <1.00 <1.00 6.96 3.34 <1.00 - - - - - - - - - - - - -- - - - - - - -- -- - 5/1712011 - - - 7 7.39 <0.500 <0.500 <1.00 0.72 19.0 3.5 204 3.44 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 571 2,290 <0.500 <0.500 <0.500 - <0.500 - - - - - - 10/6/2011 - - - 5 4.86 <0.500 <0.500 <0.500 0.740 15.0 2.50 222 3.25 <0.500 <0.500 0.540 <0.500 <1.00 <5.00 611 2,300 <0.500 <0.500 <0.500 <0.500 <0.500 -- - -- -- -- -- 3/112012 - - - 6 5.78 <0.500 <0.500 <0.500 0.800 16.2 2.91 177 3.44 <0.500 <0.500 0.540 <0.500 <1.00 <5.00 603 2,210 <0.500 <0.500 <0.500 <100 <0.500 - - - - - - 9/512012 - - - 2 1.76 <0.500 <0.500 <0.500 1.31 <0.500 <0.500 114 0.989 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 194 651 <0.500 <0.500 <0.500 <100 <0.500 -- 3.92 <0.0100 0.478 <0,0500 16.3 11/19/2012 -- -- - 49 7.01 28.6 2.13 11.7 1.28 1.81 <0.500 106 1.40 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 176 633 <0.500 <0.500 1.08 <100 <0.500 - - -- -- - - 2/19/2013 - - - 8 1-51 2.89 0.520 2.58 1.25 <0.500 1.120 79.3 0.700 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 131 464 <0.500 <0.500 0.610 <100 <0.500 - - - - - - MW 8 1/23/2002 289 ND ND ND ND ND ND ND 1.6 85.2 ND 78.2 ND ND - - - - - 60.5 422 - - - - ND ND - - - - - 1213/2009 - - - NO <1.00 <1.00 <1.00 <3.00 4.84 <1.00 - - - - - - - - - - - - - - - - -- - - - - - 5/17/2011 - - - ND <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 11.8 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 11.7 19.8 <0.500 <0.500 <0.500 - <0.500 - -- - -- - - 9/612012 - - - 60 10.1 26.1 3.62 20.0 <0.500 0.947 <0.500 11.2 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 5.33 11.1 0.609 1.22 3.89 <100 <0.500 - 13.6 <0.0140 0.150 <0.0500 9.71 11/19/2012 - - - 37 5.88 28.4 2.40 <0.500 <0.500 <0.500 <0.500 7.26 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 4.45 10.0 <0.500 0.709 2.39 <100 <0.500 - - - - - - 212012013 - - - 37 17.3 17.2 2.60 15.5 <0.500 0.874 <0.500 4.39 <0.500 <0.500 <0.500 <0.500 <0.500 <1.00 <5.00 3.74 10.9 <0.500 1.21 3.60 <100 <0.500 - - - - - MW-9 6119/2008 - - - 31,520 10,400 11,400 1,340 8,380 6,140 4,380 - - - - -- - - - - - - - - - - - - - - - -- - 4128/2010 - - - 31,390 5,420 15,300 1,470 9,200 1,020 1,790 - - - - -- - - - - - - - - - - - - - - - - - 10/21/2010 - - - 38,720 10,300 15,800 1,520 11,100 9,060 5.500 -- - - - -- -- -- -- - - -- - -- - -- -- -- - - - - - 5/1712011 - - - 50,710 12,100 20,200 2,510 15,900 4.700 3.810 <25.0 RL1 <25.0 RL1 <25.0 RL1 <25.0 RL1 99.5 <25.0 RLi 289 84.5 1,030 <250 RL1 <250 RL1 525 740 2,760 <2.500 RL1 <25.0 RL1 - - - - - - 3/1/2012 - - - 38,670 12,500 16,800 1,650 7.720 5,320 3.330 <10.0 RL1 <10.0 RL1 <10.0 RL1 <10.0 RL1 63.6 <10.0 RL1 217 58.0 1,090 <10.0 RL1 <10.0 RL1 285 512 1,810 <2,000 RL1 0.3343 - -- - - - -- 9/6f2012 - - - 39,880 11.600 16,800 1,850 9.630 6,360 4.080 <0.500 <0.500 <0.500 <0.500 75.6 10.1 215 59.5 697 <0.500 <0.500 334 502 1,780 <100 <0.500 - <1.00 <0.0100 11.4 <0.0500 39.9 11/19/2012 - - - 33,110 9,350 14,300 1,320 8.140 6.960 4.400 <50 <50 <50 <50 85.8 <50 184 <50 <500 <50 <50 259 471 1,740 14.500 <50 - - - - - - MW-10 916/2012 -- -- -- 54,900 12,400 27,300 2,400 12,800 4.560 2.960 <0.500 <0.500 <0.500 <0.500 53.4 7.70 195 66.5 766 <0.500 <0.500 426 500 1.770 <100 8.90 -- 2.65 <0.0100 <0.100 <0.0500 19.7 11/19/2012 - - - 47,590 10,100 23,800 1,990 11,700 3.050 2,230 198 <0.500 <0.500 <0.500 82.6 9.80 206 52.2 893 <0.500 <0.500 367 535 2.130 <100 <0.500 - - - - - - 2/2012013 - - - 49,320 9,590 23,600 2,230 13,900 3,090 2,050 <10,0 <10.0 <10.0 <10.0 66.4 13.2 229 56.2 899 <10,0 <10.0 434 621 2.350 <2,000 <10.0 - - - - - -- DW-1 _ 1/23/2002 1,070 ND ND 221 219 2.2 ND ND 44.3 464 167 2.2 ND ND - - -- - - 1.5 5.7 - - - - ND ND - - - - -- 12/312009 - - - ND <1.00 <1.00 <1.00 <3.00 30.7 161 -- - - - -- - -- - - - - - - - - - - - - - - - 5/17/2011 -- -- -- ND <0.500 <0.500 <0.500 <1.00 60.6 275 39.3 1.43 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 0.59 2.84 <0.500 <0.500 <0.500 - <0.500 - - - - - -- 9/5/2012 - - - 2 <0.500 1.17 <0.500 1.27 25.4 108 9.80 1.23 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 1.08 <0.500 0.549 <0.500 <100 <0.51)0 - 3.22 <0.0100 <0.100 <0.0500 20.8 11/19/2012 - - - 18 8.48 f 9.5 <5.00 <5.00 <5.00 12.1 <5.00 <5.00 <5.00 <5.00 <5.00 <5.00 <5.00 <5.00 <50 <5.00 <5.00 <5.00 <5.00 <5.00 <1,000 <5.00 - - - - - - 2/20/2013 - - - 141 50.1 56.4 <5.00 34.2 <5.00 17.0 <5.00 <5.00 <5.00 <5.00 <5.00 <5.00 <5.00 <10.0 <50.0 <5.00 <5.00 <5.00 <5.00 5 <1.000 <5.00 - - - - - - DW-2 91612012 - - - 8,864 8,450 179 61.6 173 1,080 9,500 1,630 71.6 0.537 <0.500 <0.500 4.31 61.7 47.2 261 2.09 2.01 25.6 20.2 54.9 <100 <0.500 - 2.94 <0.0100 0.453 <0.0500 44.4 11/19)2012 - - -- 10,479 10,200 142 45.6 91.1 991 10,100 1,490 46.8 <0.500 <0.500 13.5 4.50 66.5 44.1 259 1.52 1.58 22.1 9.52 18.8 <100 <0.500 - - - - - -- 2120/2013 - - - 5,951 5.850 .50.2 25.5 25.6 1,040 8,160 1,470 <5.00 <5.00 <5.00 7.30 <5.00 40.8 32.7 196 <5.00 <5.00 12.1 <5.00 <5.00 <1.000 <5.00 - - - - - - DW-3 9/6/2012 - - - 695 603 54.6 8.53 28.7 228 185 <0.500 <0.500 <0.500 <0.500 1.64 <0.500 2.99 9.15 37.8 <0.500 <0.500 10.3 2.09 4.56 '<100 <0.500 - 1.66 <0.0100 0.126 <0.0500 34.8 11/19)2012 -- -- - 734 635 73,7 3.59 21.4 157 154 <0.500 <0.500 <0.500 <0.500 3.15 1.48 2.43 9.45 115 <0.500 <0.500 11.9 1.30 3.36 <100 <0.500 -- - -- -- - - 2/2012013 - - - 486 278 . 122 12.5 73.6 145 116 <0.500 <0.500 <0.500 <0.500 1.64 1.10 2.17 6.44 54.1 <0.500 <0.500 5.24 3.79 13.40 <100 <0.503 - - - - - Notes: GCLs = Gross Contamination Levels NE = Not Established <# = Non -Detect below laboratory reporting limits ND = Below Detection Limits BTEX = Benzene Toluene Ethylbenzene Xylenes MTBE = Methyl tert-butyl ether IPE = Diisopropyl Ether EDB = Ethylene Dibromide BOLD = Concentration exceeds GCL standard - = Not Analyzed for specific compound 1 = Prior to May 2011 event, samples were analyzed via Environmental Protection Agency (EPA) 602 (historical data used 602/6230D), May 2011 samples were analyzed vla SM6200 B. 2 = Prior to May 2011 event, samples were analyzed via EPA 504.1, May 2011 samples were analyzed via SM6200 B. RL1 = Reporting limit raised due to sample matrbc effects MADEP = Massachusetts Department of Environmental Protection VPH/EPH = Volatile Petroleum Hydrocarbons 1 Extractable Petroleum Hydrocarbons pg1L = micrograms per liter Page 2 of 2 ARCADIS Figures REFERENCE: BASE MAP USGS 7.5. MIN. TOPO. QUAD., CHARLOTTE WEST, NC, 1993 AND MOUNTAIN ISLAND LAKE, NC, 1993, 0 2000' 4000" Approximate Scale: 1 in. = 2000 ft, NORTH CAROLINA EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL SERVICES STATION #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC 1ST QUARTERLY CAP MONITORING REPORT - 2013 SITE LOCATION MAP ARCAD1S FIGURE r UNKNOWN) UNKNOWN ti FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET LEGEND: Glh MONITORING WELL ABANDONED MONITORING WE A SOIL BORING O IN,1ECTPON WELL lit SEWER MANHOLE. ca WATER METER O WATER VALVE 4 GAS VALVE UTILPTY POLE x CHAIN LINK FENCE WOOD FENCE GUARDRAIL. UwIL- OVERHEAD ELECTRIC 0 NOTE: 1, THIS FIGURE 45 BASED UPON A SURVEY BY ARCADIS US, INC. ON 10/2/2012. FORMER LOCATIONS AND SOIL BOOR6NGS WERE NOT SURVEYED AND ARE THEREFORE APPROXIMATE, 40' GRAPHIC SCALE 80 EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY *42094 3721 FREEDOM DRIVE, CHARLOTTE, NC 1ST QUARTERLY CAP MONITORING REPORT - 2013 SITE MAP ARCADIS RE MAJOR STREET rn LEGEND: MONITORING WELL ABANDONED MONITORING WELL ♦ SOIL BORING O INJECTION WELL 41 SEWER MANHOLE Ca WATER METER o WATER VALVE © GAS VALVE UTILITY POLE ---x- *— CHAIN LINK FENCE WOOD FENCE ,a t GUARDRAIL -- c OVERHEAD ELECTRIC GROUNDWATER ELEVATION (FEET) 757 00 -..�. � � GROUNDWATER ELEVATION CONTOUR (DASHED WHERE INFERRED) 41111mmommou GROUNDWATER FLOW DIRECTION NOT SURVEYED 0 NOTE: 1, THIS FIGURE IS BASED UPON A SURVEY BY ARCADIS US, INC. ON I ©`2/2012,. FORMER LOCATIONS AND SOIL BORINGS WERE NOT SURVEYED AND ARE THEREFORE APPROKVMATE, 2, MONITORING WELLS DW-1, OW-2 AND DW-3 ARE DEEP MONITORING WELLS AND WERE NOT UTILIZED TO DEVELOP POTENTIOMETRIC SURFACE. MW-5 WAS ALSO NOT UTILZED TO DEVELOP POTENTIOMETRIC SURFACE, 40' 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC T QUARTERLY CAP MONITORING REPORT - 2013 POTENTIOMETRIC SURFACE MAP FEBRUARY 19, 2013 ARCADIS FIGURE 1PE 120CE h <50 EDST . <0 NAP <d14 AP 'TCE_ FTE TR NM 10 972012 2Z20 20 10 223 600 ."230._._. _, 0 13,900_.. 3,090 0 ,. .. .: .d5O....w..,.,__. 11 t 201 i3xliNCl..._ I. 6,120 841 4,400 65..6� IPE 3, 120CE 798 .._ EDS <50,0 NAP <500 TCE I <50 TETR F1PE 12DCE EDS NAP TCE TETR 0 3_ 7,720 616 ,_ 4,150 ....,._.. 86.5 4,600 928 .mm....M. 81.8 431 28,4 17.2 2,40 2,60 <0.500 15,5 <0.500 t<d 500 <0.500 0 874 <0,500 <0,500 <J 500 s <0.500 -- t <_._ - <5.dd . <5 Od .� 4,45 i4 10.0 2.54. 7 16.0 ._..W. 44,6 <0.500 <0.500 ^ 2.44 0..881 120CE84 ,_.. _ ..„_<0 500 E©B <0.50d NAP.... L<5.00..,_ <5.0O 0---- LICE.Sd4 <0,500 0.580 <0.500 UNKNOWN) FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET -UNKNOWN E NAP TCE 11.52 TE TR 7 1 58 �157 ?154 200E <0.500 <0.500 NAP TCE <0 TETR _, r1/19/2©12 2LL20J2013 50.2 45,6 1 25.5 91,1 25,6 991 ' 1,040 10,100 8,160 2DCE 1 1 "" 70 00 6 IPE 12 1 17 0 12DCE , :00_1 00 EBB <5 00 NAP <5d <50 O TCE <5.00 [ <5.PO <5.dd PE 120 as NAF ICE .81 00 0 0 7 2.89 D.520 2,.58 464 LEGEND: MONITORING WELL ABANDONED MONITORING WELL SOIL BORING INJECTION WELL SEWER MANHOLE WATER METER 6+ WATER VALVE © GAS VALVE 11 U11LITY POLE °^-- x�-- CHAIN LINK FENCE �•— WOOD FENCE GUARDRAIL OVERHEAD ELEC'f'RIC FREE PRODUCT / Legend COG GCLS B 5,000 enzena 260 O0© Toluene WMRY 1 87O4 5OQdd q Ethypentt1z- 3.oerE.t Lrtnl e 1EO2DBCE 50 6Odd ,dOONAP TMdaheahlxy1 1,2 —Dtc Lene ltorhaIon85,50O 20dO0 ttly1 TC3009 TETR 70d Tetrachl BOLD Exceed GCLS GCLs Gross Con.amonetion Leveos FP: Fr Product NS: Not Sampled 1ST NOTE: 1. THIS FIGURE IS BASED UPON A SURVEY BY ARCADIS US, INC. ON 10/2/2012. FORMER LOCATIONS AND SOIL BORINGS WERE NOT SURVEYED AND ARE THEREFORE APPROXIMATE, 0 40' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC UARTERLY CAP MONITORING REPORT - 2013 DISSOLVED PHASE CONCENTRATION MAP ARCADIS FIGURE BUILDING 420)4 FOP,t4FR WASTE O. TANK k (UNKNOWN) ,(4,55%SS3^ ---5,000 FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET UNKNOWN 0 5,000- LEGEND: MONITORING WELL n ABANDONED MONITORING WELL A SOIL BORING Qj INJECTION WELL SEWER MANHOLE .o WATER METER 33 WATER VALVE GAS VALVE M UTILITY POLE — — CHAIN LINK FENCE WOOD FENCE GUARDRAIL OVERHEAD ELECTRIC wg/L MICROGRAMS PER LITER BOLD EXCEED GCL STANDARD ^ 4 ;3 O BENZENE CONCENTRATION (PRA) BENZENE ISOCONCENTRATION CONTOUR (DASHED WHERE INFERRED) (pg/L) rP) FREE PRODUCT NOTE: 1, THIS FIGURE 65 BASED UPON A SURVEY BY ARCADIS US, INC, ON 10/ 2012. FORMER LOCATIONS AND 'SOIL BORINGS WERE NOT SURVEYED AND ARE THEREFORE APPROXIMATE.. 2. NORTH CAROLINA GROSS CONTAMINANT LEVEL (GCL) STANDARD FOR BENZENE. (5,000 pg/t) 4©° 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC T QUARTERLY CAP MONITORING REPORT - 2013 BENZENE ISOCONCENTRATION MAP FEBRUARY 19-20, 2013 ARCADIS I T 0 Oa,f OFII' 2DCE (UNKNOWN) FORMER CHARLIE BROWN'S DRY CLEANERS 44O MAJOR STREET STREET -UNKNOWN Dot 2DC DW-3 mate .._.2 2O 201 2DCE <Tk.0T atlWl0 Dante 2/20/2 ©cite mm 2/29/2 12DCE 1,470 Drate 2/20/2.0 0 Pg/L BOLD 400-- NOTE: LEGEND: MONITORING WELL ABANDONED MONITORVNG WELL SOIL BORING INJECTION WELL SEWER MANHOLE WATER METER WATER VALVE GAS VALVE UTILITY POLE CHAIN LINK FENCE WOOD FENCE GUARDRAIL OVERHEAD ELECTRIC MICROGRAMS PER LITER EXCEED GCL STANDARD 1,2—DICNLO'ROETHANE CONCENTRATION (Ng/L) 1,2—DICHLOROETHANE ISOCONCENTRATION CONTOUR (DASHED WHERE INFERRED) (Mg/L) FREE PRODUCT 1. THIS FIGURE IS BASED UPON A SURVEY 9Y ARCADIS US, INC. ON 1 Q 2 2012, FORMER LOCATIONS AND SOIL BORINGS WERE NOT SURVEYED AND ARE THEREFORE APPROXIMATE,. 2, NORTH CAROLINA GROSS CONTAMINANT LEVEL (GCL) STANDARD FOR 1,2—DICHLOROETHANE (400 Hg/L) 40. 8O° GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY *42094 3721 FREEDOM DRIVE, CHARLOTTE, NC ST QUARTERLY CAP MONITORING REPORT - 2013 1,2-DICHL©R©ETHANE ISOCONCENTRATION MAP FEBRUARY 19-20, 2013 ARCADIS I "" s BUILDING FORMER CHARUE BROWN'S DRY CLEANERS 440 MAJOR STREET 0 1 W10 2 20/2013 10.0 A. LEGEND: MONITORING WELL ABANDONED MONITORING WELL SOIL BORING 0 INJECTION WELL SEWER MANHOLE ca WATER METER WATER VALVE. 4 GAS VALVE UTIUTY POLE CHAIN PLINK FENCE VCCat FENCE', GUARDRAIL rIE OVERHEAD ELECTRIC pg/L MICROGRAMS PER LITER BOLD EXCEED GCL STANDARD i :1 ETHYLENE DIBROMIDE (EDB) CONCENTRATION (NgA) 50 - ED8 ISOCONCENTRATION CONTOUR (DASHED WHERE INFERRED) (pg/L) FREE PRODUCT NOTE: 1. THIS FIGURE IS BASED UPON A SURVEY BY ARCADIS US, INC. ON 10/2/2012. FORMER LOCATIONS AND SOIL BORINGS WERE NOT SURVEYED AND ARE THEREFORE APPROXIMATE, 2, NORTH CAROLVNA GROSS CONTAMINANT LEVEL (GCL) STANDARD FOR ETHYLENE DIBROMIDE (50 NgA ) 40' 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC ST QUARTERLY CAP MONITORING REPORT - 2 ETHYLENE DIBROMIDE ISOCONCENTRATION MAP FEBRUARY 19-20, 2013 ARCADIS FIGURE A CADIS Appendix A Approved NCDENR UIC Permit # W I03000192 NODE A North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P.E. Dee Freeman Governor Director Secretary June 27, 2012 Jewel Cox — Project Manager Exxon Mobil .Environmental Services 1016 Poplar Avenue, Suite 106 — Number 232 Collierville, TN 38017 Ref: Fssuance of Injection Permit WI0300192 Former ExxonMobil Retail Facility # 42094 Charlotte, Mecklenburg County, North Carolina. Cox: Iit accordance with the application received on March 2, 2012, and the supporting data received May 14, 2012 and June 19, 2012, we are forwarding permit numberW10300192. This permit is to inject BioSolve for the mobilization, dispersal, and bi©enhanced renediation of free -phase and dissolved petroleum hydrocarbons in the soil and ground water at the facility referenced above. This permit shall be effective from the date of issuance until May 31, 2014, and shall he subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS, Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. Please note that the sampling program has been modified. You will need to notify this office by telephone 48 hours prior to initiation of operation of the .facility, In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the perrnit 120 days prior to its expiration date. Please contact me at 91.9-807-6352 or at david.goodrich@ncdenr.gov if you have any questions about your permit, Best Regards, David. Goodrich, L.G. Hydrageologist cc: Andrew Pitney, Mooresville Regional Office Daniel Bowser, Division of Waste Management -UST Section Scott Bastian, ARCADIS, 801 Corporate Center Drive, Suite 300, Raleigh, NC 27607 WI0300192 Pennit File AQUIFER PROTECTION' SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location; 512 N, Salisbury St., Raleigh, North Carolina 27604 Phone: 919-807-6464 t FAX, 919 607-6496 kntemet www.rnwatergp alitY.g_i 01.rturrrty North Caro One a /Vatiirallji NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO ExxonMobil Environmental Services FOR THE CONSTRUCTION AND/OR OPERATION OF 4 CLASS 5 INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(5)(b)(viii), to inject BioSolve, for the mobilization, dispersal, and bioenhanced remediation of petroleum hydrocarbons. These injection wells/points will be located at the former Exxon Mobil Retail Facility Number 42094, 3721 Freedom Drive, Charlotte, Mecklenburg County, North Carolina, and will be operated in accordance with the application submitted March 2, 2012, and in conformity with the specifications and supporting data submitted May 14, 2012 and June 19, 2012, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until May 31, 2014, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the 27th day of June, 2012. J Charles Wakild, P.E., Director Division of Water Quality By Authority of the Environmental Management Commission. Permit No. WI0300192 PAGE 1 OF 7 ver. June 2011 UIC-5I/5T PART I - WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200) and Well Construction Standards applicable to monitor wells (15A NCAC 2C 0100). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. This permit is valid only for construction of the number of injection wells described in the application and other supporting data. Construction of additional injection wells must be approved in advance by the Aquifer Protection Section. 4. Each injection well or monitor well shall not hydraulically connect separate aquifers. 5. Each injection well or monitor well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 6. Each injection well or monitor well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes or monitor purposes and the entrance to each well must be secured with a locking cap. 7. Each injection well or monitor well shall be afforded reasonable protection against damage during construction and use. 8. Each injection well or monitor well shall have permanently affixed an identification plate. PART II - WELL CONSTRUCTION SPECIAL CONDITIONS 1. Prior to beginning injection, a deep monitor well shall be constructed downgradient of injection area INJ-2/MW-5 near existing well MW-2R. A well pair consisting of one shallow monitor well and one deep monitor well shall be constructed downgradient of injection area INJ-1/MW-9. All three of these wells shall be included in the monitoring program. 2. At least forty-eight (48) hours prior to constructing each injection well or monitor well, the Permittee shall notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office staff, telephone number 919-807-6352 and the Mooresville Regional Office Aquifer Protection Section Staff, telephone number (704) 663-1699. 3. Bentonite grout shall not be used to seal any water -bearing zone with a chloride concentration equal to or greater than 1,500 milligrams per liter. In areas where elevated chloride levels are known to exist or are probable, such as coastal areas, chloride levels shall be verified in the field to determine existing conditions. Permit No. WI0300192 PAGE 2 OF 7 ver. June 2011 UIC-5115T PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate of injection, and number of injection wells as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes, rules, regulations, or ordinances that may be imposed by other local, state, and federal agencies having jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV - PERFORMANCE STANDARDS 1. The wellheads of the existing monitor wells shall be secured against tampering, and conditions such as missing padlocks, missing bolts, etc. shall be corrected before injection operations commence. 2. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. 3. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 4. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V - OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central Office staff, telephone number 919-807-6352. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. Permit No. WI0300192 PAGE 3 OF 7 ver. June 2011 UIC-5I/5T PART VI - INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS 1. Within 30 days of completion of well construction, a completed Well Construction Record (Form GW-1) must be submitted for each injection well to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 2. The proposed monitoring plan included in the application shall be followed with some modifications. As per the proposed monitoring program, monitor wells MW-5, MW-6, MW- 7, MW-8, MW-9, and DW-1 will be measured for free -product thickness after injection and vapor recovery activities. Monitor wells MW-5, MW-7, MW-9, the new pair of monitor wells installed downgradient of injection area INJ-1/MW-9, the new deep monitor well installed downgradient of injection area INJ-2/MW-5, and monitor wells DW-1, MW-2R, MW-6 and MW-8 will be sampled for Volatile Organic Compounds, water level, free product thickness, and for the field parameters of Conductivity, pH, and ORP. Sampling will be performed each quarter after the final injection event for a full year. The field parameters of Conductivity, pH and ORP will serve as an indicator of injectant/ treatment products, and any significant change in any of these parameters in a particular well shall initiate an expansion of the sampling parameters for that well to include Calcium, Arsenic, Iron, Zinc, and Sulfates. All sample results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office and the Raleigh Central Office. Any monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to ensure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. 3. The Permittee shall submit an Injection Event Record within 30 days of completing each injection. 4. The Permittee shall produce a final project evaluation within 9 months after completing all injection -related activity associated with this permit or produce a project interim evaluation Permit No. WI0300192 PAGE 4 OF 7 ver. June 2011 UIC-5I/5T before submitting a renewal application for this permit. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plume maps and potentiometric surface maps. 5. The monitoring results and the final project evaluation shall be submitted to: UIC Program Staff DWQ — Aquifer Protection Section and 1636 Mail Service Center Raleigh, NC 27699-1636 DWQ - Aquifer Protection Section Mooresville Regional Office 610 East Center Avenue / Suite 301 Mooresville, NC 28115 6. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Mooresville Regional Office, telephone number (704) 663-1699, any of the following: (A) Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 7. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 8. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. PART VIII - PERMIT RENEWAL In order to continue uninterrupted legal use of the injection facility for the stated purpose, the Permittee must submit an application to renew the permit 120 days prior to its expiration date. PART IX - CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0240, Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 1 5A NCAC 2C .0240, including but not limited to the following: Permit No. WI0300192 PAGE 5 OF 7 ver. June 2011 UIC-51J5T (A) All casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout or bentonite grout, which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0225(k)(1)(A) within 30 days of completion of abandonment. 3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with the product proposed to be used are as follows: eye, skin, nose, throat, and lung irritation. Significant inhalation exposure can cause central nervous system depression and lung, liver, and kidney injury. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 2. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Permit No. WI0300192 PAGE 6 OF 7 ver. June 2011 UIC-5I/5T 3. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 4. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. 6. Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. Permit No. WI0300192 PAGE 7 OF 7 ver. June 2011 UIC-51/5T A CADIS Appendix B Groundwater Laboratory Analytical Report and Chain -of -Custody Record - February 19 -- 20, 2013 TestAmerica THE LEADER IN ENVIRONMENTAL TESTING ANALYTICAL REPORT TestAmerica Laboratories, Inc. TestAmerica Nashville 2960 Foster Creighton Drive Nashville, TN 37204 Tel: (615)726-0177 TestAmerica Job ID: 490-20114-1 TestAmerica SDG: 3721 Freedom Drive, Charlotte, NC Client Project/Site: EM 42094 For: ARCADIS U,S. Inc 111-D Sanders Lane Bluefield, Virginia 24605 Attn: Jon Farley Authorized for release by: 2/28/2013 1.:44:10 PM Leah Klingensmith Senior Project Manager leah.klingensmithtestamericainc.com Designee for Jennifer Huckaba Project Manager I jennifer.huckabaannericainc,com The test results in this report rrteet all 2003 NELAC and 2009 TIN requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager a( the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory, Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature, Results relate only to the items tested and the sample(s) as received by the laboratory. Client: ARCADIS U.S. Inc TestAmerica Job ID: 490-20114-1 Project/Site: EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Table of Contents Cover Page 1 Table of Contents 2 Sample Summary 3 Case Narrative 4 Definitions 5 Client Sample Results 6 QC Sample Results 24 QC Association 39 Chronicle 40 Method Summary 42 Certification Summary 43 Chain of Custody 44 Receipt Checklists 46 El TestAmerica Nashville Page 2 of 46 2/28/2013 Sample Summary Client: ARCADIS U.S. Inc TestAmerica Job ID: 490-20114-1 Project/Site: EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID Client Sample ID Matrix Collected Received 490-20114-1 MVV.5 Ground Water 02120/13 14:00 02/21/13 08:45 490-20114-2 MW-6 Ground Water 02/20/13 16:00 02/21/13 08:45 490-20114-3 MW-7 Ground Water 02/19/13 16:50 02/21/13 08:45 490-20114-4 MW-8 Ground Water 02/20/13 15:00 02/21/13 08:45 490-20114-5 MVV-10 Ground Water 02/20/13 10:15 02/21/13 08:45 490-20114-6 DW-1 Ground Water 02/20/13 13:15 02/21/13 08:45 490-20114-7 DW-2 Ground Water 02/20/13 08:50 02121/13 08:45 490-20114-8 DVV-3 Ground Water 02120/13 11:05 02/21/13 08:45 490-20114-9 Trip Blank Water 02/19/13 00:01 02/21/13 08:45 TestAmerica Nashville Page 3 of 46 2/28/2013 Case Narrative Client ARCADIS U,S. Inc Project/Site: EM 42094 Job ID: 490-20114- Laboratory:, TestAmerica Nashville Narrative Comments No additional comments. Job Narrative 490-20114-1 TestAmerica Job 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Receipt The samples were received on 2/21/2013 8:45 AM: the samples arrived in good condition, properly preserved and, where required, on ice, The temperature of the cooler at receipt was 13° C. GC/MS VOA Method(s) SM6200-B: The laboratory control sample (LCS) and 1 or laboratory control sample duplicate (LGS©) for batch 60479, exceeded control limits for the following analytes: n-butylbenzene. These analytes were biased high in the LCS and were not detected in the associated samples: therefore, the data have been reported. Method(s) SM6200-B: The matrix spike / matrix spike duplicate (MS MS©) recoveries for batch 60479 were outside control limits for n-butylbenzene. These analytes were biased high in the LCSD and were not detected in the associated samples. Method(s) SM6200-B: The following sample(s) contained residual chlorine upon receipt: DW-2 (490-20114-7). Method(s) SM6200-B: The following volatiles samples) was diluted due to foaming at the time of purging during the original sample analysis: DW-1 (490-20114-6), Elevated reporting limits (RLs) are provided. Method(s) SM6200-B: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for batch 61502 exceeded control limits for the following analytes: 1,1-dichloroethene. These analytes were biased high in the LCS and were not detected in the associated samples: therefore, the data have been reported. Method(s) SM6200-B: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch 61502 were outside control limits for 1,1-dichloroethene, This analyte was biased high in the LCS and was not detected in the associated samples,. No other analytical or quality issues were noted, VOA Prep No analytical or quality issues were noted, TestArnerica Nashvi9le Page 4 of 46 2/28/2013 Definitions/Glossary Client: ARCADIS U,S, Inc Pro.ect/Site: EM 42094 Qualifiers GC/MS VOA Qualifier Qualifier Description LCS or LCSD exceeds the control limits MS or MSD exceeds the control limits Glossary Abbreviation Th %R CNF DER DL, RA, RE, IN DLC MDA MDC MDL ML ND PQL QC RER RL R PD TEF TEQ rri� may or may not be present in this Listed under the'"D" column to design Percent Recovery Contains no Free Liquid Duplicate error ratio (normalized absolute difference) Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample Decision tevel concentration Minimum detectable activity Estimated Detection Limit Minimum detectable concentration Method Detection Limit Minimum Level (Dioxin) Not detected at the reporting iimit(or MDL or EDL if shown) Practical Quantitation Limit Quality Control Relative error ratio Reporting Limit or Requested Limit (Radiochemistry) Relative Percent Difference, a measure of the relative difference between two points Toxicity Equivalent Factor (Dioxin) Toxicity Equivalent Quotient (Dioxin) is reported on a dry weight basis TestAmerica Job ID: 490-20114-1 SDC. 3721 Freedom Drive, Charlotte, NC TeslArtaerica Nashville Page 5 of 46 2/28/2013 Client Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: MW Date Collected: 02/20/13 14:00 Date Received; 02121/13 08;45 Method: SM6200413 • Volatile Organic Compounds Analyte Result Qualifier RL MDL Unit Benzene 15e30g 50,0 ug1L Bromobenzene NO 5-00 ug/L Bromochloromethane NO 5.00 ug/L. modichloromethane ND 5.00 ug/L orm NO 5.00 ug/L thane NO 5.00 ug/L Cartoon tetrachloride ND 5.00 ug/L Chlorobenzene NO 5.00 ug/L Chloroethane ND 5.00 ug/L Chloroform 9.21 5.00 ug/L Chloromelhane ND 5,00 ug/L 4-Chloratoluene ND 5,00 ugh.. 2-Chlorotoluene ND 5.00 ugh. cis-1,24DichIoroethene 133 5.00 ugh, cis-1,3-Dochloropropene ND 5.00 ugfL Dibromochloromethane ND 5,00 ug/L 1,2-Dibrorno-3-Chloropropane ND 5,00 ug/L 1,2•L7itrrcantl7etitatae 1EDBI 81.6 5.00 ug/L Dibromorrrethane 1, 2-Dichl©robenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene D ichlor©difl uorometh a ne 1,1-DichIoroethane 1,2-QYchloroethane 1,1-Dichloroethene 1,2-Dichloropropane 1.3-Dichloropropane 2,2-Dichloropropane 1 „1-Dichloropropene Dilsopropyl ether Ethanol Ethylbenzene Hexachlor©butediene irtopropytbenzene Methylene Chloride Methyl tent -butyl ether Naphthalene n-Butylbenzene N-Prepylbenzene pAsoprapyttoluene -Butytbenzene ne ibenzene 2-Tetrachloroethane -Tetrechloroethane Tetrachloroethene Toluene trams lag -Di ND 5,00 ug/L ND 5,00 ugh. ND 5.00 ug/L ND 5.00 ugh_ ND 5.00 ug/L NO 5,00 ug/L 928 5.00 ug/L ND 5.00 ug/L ND 5,00 ug/L NO 5,00 ug/L ND 5.00 ug/L NO 5.00 ug/L 8e0 50.0 ugh. ND 1000 ug/L 816 5,00 ugh_ ND 10.0 ug/L 25,3 10.0 ug/L ND 50.0 ug/L 86.5 5,00 ug/L 431 50.0 ug/L 37-4 5,00 ug/L 86.3 5.00 ugh, 5:76 5.00 ugh_ 5.47 5.00 ug/L 144 5-00 ug/L ND 5.00 ugh. ND 5,00 ug/L ND 5.00 ug/L 9.06 5.00 ug/L. 7720 50.0 ugJL. oroethene ND 5.00 ug/L. TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-1 Matrix: Ground Water Prepared Analyzed Di1 Fac 02/22/13 18:40 100 02/22/13 1 8: 74 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18;14 10 02/22113 18:14 10 02/22/13 18:14 10 02122/13 18;1' 4 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18,14 10 02122/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18;14 10 02122/13 18:14 10 02/22/1318:14 10 02/22/13 18`14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18.14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18;14 10 02/22/13 18:14 10 02/22/13 18;14 10 02/22/13 18.14 14 02/22/13 18,40 100 02/22/13 18:14 10 02/22113 18 14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/27/13 16'49 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 1814 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18:14 10 02/22/13 18,14 10 02/22/13 18:40 100 02/22/13 18;14 10 TestAmerica Nashville Page 6 of 46 2/28/2013 Client Sample Results 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1, 1,2- Trichloroetha n e 1.1,1-Trichloroethene Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene Vinyl chloride Xyfenee, Total Surrogate 1,2-Dichlorootharle-EM (Surr) 1,2-Dichloroethane-d4 (Surr) 1,2-Dichloroethane-d4 (Surr) Toluene-16 (Surr) Toluener-d8 (Surr) Toluene -dB (Surr) 4-Brernotluorubenzene (Surr) 4.-13romofluombenzene (Surr) 4-8romofluorobenzene (Surr) ; Dibromofluoromethane (Surr) Dibrornoffuoromethane (Surr) Dibromofluoromethane (Surr) Client: ARCADIS U S Inc Project/Site EM 42094 Client Sample ID: MW-5 Date Collected: 02120/13 14:00 Date Received: 02121/13 08:45 Method: SM6200-B - Volatile Organic Compounds (Continued) Analyte Result Qualifier inms4,3-Dichlorepropene NO ND ND NO ND 8,99 ND ND 290 952 ND 4150 RL 5 00 5 00 5.00 5.00 5 00 5.00 5 00 5.00 5.00 5 00 5 00 5 00 %Recovery Qualifier Limits 93 70130 95 70 .130 90 70 -130 98 97 97 102 101 70 _130 93 70 .130 92 70 -130 94 70 .130 95 70 .130 70 .130 70 .130 70 .130 70 _130 MOL Unit ug/L ug/L ug/L. ug/L ug/L ug/L ug1L ug/L ug/L ug/k. ug/L ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-1 Matrix: Ground Water D Prepared Anatyze 02/22/13 8:14 02/22/13 18:14 02/22/13 18:14 02/22/13 18:14 02/22/13 18:14 02/22/13 18:14 02J22/13 18:14 02/22/13 18:14 02/22/13 18°14 02/22/13 18:14 02/22/13 18:14 02/22/13 18:14 011 Fac 10 10 10 10 10 10 10 10 10 10 10 10 Prepared Ariaiyzed DllFac 02/22113 18:14 02/22/13 18:40 100 02/27/13 16:49 10 02/22/13 18.-14 10 02/22/13 18'40 100 02/27/13 16:49 10 02122/13 16:14 10 02/22/13 18:40 100 02/27/13 16:49 10 02/22/13 /8:14 10 02/22/13 18:40 100 02/27/13 16:49 10 TestAmerica Nashville Page 7 of 46 2/28/2013 Client: ARCADIS U.S. Inc ProjectlSite: EM 42094 Client Sample ID: IMW-6 Date Collected: 02/20/13 16:00 Date Received: 02/21/13 08:45 Method: SM6200-B - Volatile Organic Compounds Analyte zene Bromobenzene Bromochloramethane B romodichlorornetha ne Bromoform Bromomethane Carbon tetrachloride C hlarobenzene Cliioroethane Chloroform C hloromethane 4-Chlorotoluene 2-Chlorotoluene -1,2-Dichloroethene ropropene Dibromochloromethane 1, 2- D'i b ram o'-3- C h l o rop ropa n e 1,21Dibrornoethane (E©B) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4.Dichlorobenzene Dlchlorodifl uoromethane 1,1-Dichloroethane 1,2r'Dichloroethane 1,1-Dichloroethene 1,2-Dichloroprapane 1,3-Dichloroproparne 2,2-Dichloropropane 1-Dicb orapropene ropyi ether thanoi th Hexachlorobutadiene tsoptopylbenzene Methylene Chloride Methyl tart -butyl ether Naphthalene etllyibenzene N-Propylbenzene p-1 sopropyitol uene se-Butylbenzene Stytrie terVeutylbenzene 1,1,1,2-Tetrachloroethane 1 „1, 2,2-Tetrachio meth a ne Tetrachloroethene Toluene Iran s-1,2-Dichloroethene Client Sample Results Result Qualtfier RL Mi1L U 0.500 u ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND O.ra00 ug/L ND 0,500 ug/L ND 0.500 ug/L ND 0.500 ug/L. ND 0,500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0,500 ug/L. ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0.500 ug/L ti„61 0,500 ug/L ND 100 ug/L 4,67 0.500 ug/L ND 1.00 ug/L ND 1,00 ug/L ND 5.00 ug/L NO 0.500 ug/L ND 5.00 ug/L. 0,016 0,500 ug/L 1.01 0.500 ug/L ND 0 500 ug/L ND 0,500 ug/L ND 0.500 ugfL ND 0,500 ug/L. NO 0.500 ug/L NO 0.500 ug/L ND 0.500 ugh, 35,4 0.500 ug/L ND 0.500 ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-2 Matrix: Ground Water Prepared Analyzed E"1il Fac 02/22/ 13 02/22/13 16:31 1 02122/13 16:31 1 02/22/13 16:31 1 02/22/13 16.31 1 02122/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/1316:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22113 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1' 02/22/13 16:31 1 02122/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02122/13 16:31 1 02/22/13 1631 1 02/22/13 16:31 1 02/22/13 15:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/27113 15:31 1 02/22J 13 16:31 1 0222113 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 02122/13 16:31 1 02/22/13 16:31 1 02122/13 16:31 1 02/22/13 16:31 1 02/22/13 16:31 1 TestAmerica Nashville Page 8 of 46 2/28/2013 Client Sample Results Client ARCADIS U.S. Inc Project/Site. EM 42094 Client Sample ID: MW-6 Date Collected: 02/20/13 16:00 Date Received: 02/21/13 08:45 Method: SM6200-B - Volatile Organic Compounds (Continued) Anelyte Result Qualifier RL trans-1,3-t21c.hloropropene ND 0,500 1,2,3-Trichlorobenzene NO 0,560 1,2,4-Trichlorotienzene NO 0,560 1,1,2-Trichloroethene ND 0,500 1,1,1-Trichloroethene ND 0.500 Trichloroethene NO 0.500 Trichlorofluororriethane NO 0,500 1,2,3-Trichloroprope.ne NO 0.500 1,3,54rirnethylbenzene 4.95 0.500 1,2,4•Trimethylbenzene 1,5,9 0,500 Vinyl chloride ND 0,500 Xylenes, Total 44.6 0.500 Surrogate 1,2-Dchloroetharte44 (Surr) I.2-Dicriforoethane-44 (Surr) Toluene-ri8 (Surr) Toluene-d8 (Surr) 4-Bromoffuorobenzene (Surr) 4-Bromorluorobenzene (Surr) Dibromofluorometharte (Surr) Dibromofluoromethane (Surr) %Recovery 97 97 102 68 101 100 97 98 Qualifier Limits 70 _130 70 . 130 70 -130 70 .130 70 .130 70 -130 70 _130 70 _130 AWL Unit ug/L ug/L ug/L ug/L ug/L ug/L ugIL ug/L ug/L ug/L ugit ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-2 Matrix; Ground Water Prepared Analyzed Oil Fac 02/22/13 1631 1 02/22/13 1631 1 02/22/13 1631 1 02/22/13 1631 1 02/22/13 16:31 1 02/22/13 1631 1 02122/13 16:31 1 02/22/13 16:31 1 02/22/13 1631 1 02/22/13 16:31 1 02/22/13 1631 1 02/22/13 16;31 1 Prepared Analyzed Di/ Fac 02/22/13 1631 1 02/27/13 1531 02/22/13 16:31 02/27/13 1531 02/22/13 1631 02/27/13 1531 02/22031631 02/27/13 1531 TestAmerica Nashville Page 9 of 46 2/28/2013 Client Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: MW-7 Date Collected: 02119/13 16:50 Date Received: 02/2 113 08:45 Method: SM6200-B - Volatile Organic Compounds Analyte Result Qualifier Benzene.1,51 obe nzene ND NO ND ND ND NO ND NO ND ND NO ND 79,3 NO ND NO ND ND ND ND ND ND ND 1,12 ND ND NO ND ND ND NO 0.520 ND ND ND 1,25 ND ND ND ND ND NO ND ND ND 464 2.89 0,700 ochloromethane aromethane form ethane Carbon tetrachloride Chlorobenzene Chloroethene Chloroform Chloromethane -�ne�oraatuuene 2-Chlorotoluene -Dichioro there Dichlaropropene hloromethane 12-Oibalatna-3-Chloropropa ne 1,2-Dibromoethane (EDB) Dibromomelhane 1,2-Dichlorobenzene 1,3-Dlchlorobenzene 1,4-Dichlorobenzene Dich lorod ifluoro metha ne 1, "1-Dichloroethane 1,2-Dichlor thane 1,1-Dichloroethene 1, 2--Dichlon3propene 1,3-Diehlompropane 2,2-Dichloropropane 1,1-Dichloroprapene D//sopropyl ether Ethanol Ethyltmanzene Hexachlarobutadiene lsopropylbenzene Methylene Chloride hlhyl ri `Eetyi ether llaphthatene n-Butylbenzene NYPropylbenzene p-Isopropyltoluene sec-Butyibenzene Styrene ten l3utylbenzene 1,1,1,2-Tetrachloroethene 1,1,2,24Tetrachloroethane Tetrachloroethene Toluene trans•1,2-Dichioroethene RL MDL Unit 0.500 uglL 0,500 ug/L 0.500 ug11, db.500 m WL 0,500 0.500 ug/L 0.500 ug/L 0.500 uglL 0, 500 ug L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 ug/L 0.500 0-500 ug/'L 0.500 ugh 0.500 ugh 0.500 ug/L 0,500 ugfL 0.500 ug/L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 ugh 0,500 ug/L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0,500 ug)L 100 ug/L 0.500 ug/L 1.00 ug/L 1,00 ug/L 5,00 ug/L 0.500 ug/L 5 00 ug/L 0.500 u0/L 0,500 ug/L 0,500 ug/L 0,500 ug/L 0,500 ug/L 0,500 ug/L 0,500 ug1L. 0,500 ug/L 2,50 ug/L 0,500 ug/L 0,500 ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-3 Matrix: Ground Water Prepared Ana 02/22/ 1 16:57 Di1 Fac 1 02/22/13 16.57 1 02/22/13 16:57 1 02122/13 16'57 1 02/22113 16;5'7 1 02/22113 16:57 1 02/22113 16:57 1 02/22/ 13 16; 57 1 02/22/13 16:57 1 02122/13 16:57 1 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16: 57 1 02/22/13 16;57 1 02122/13 16:57 1 02/22/13 16:57 1 02/22/13 16 57 1 02/22/13 16'57 1 02/22/13 16`:57 02/22/13 16 57 1 02/22/13 16:57 1 02/22/13 16::57 1 02/22/13 16;57 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16'57 02/22/13 16'57 1 02/22/13 16;57 1 02/22/13 16;; 57 1 02/22/13 16:57 1 02/22/13 16757 1 02/22/13 16;57 1 02/22113 16;57 1 02122/13 16:57 1 02/22/13 16:57 1 0212203 16:57 1 02122/13 16:57 1 02122113 16.57 1 02/22/13 16;57 1 02/22/13 16:57 1 02/22/13 16;57 1 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16; 57 1 02/27/13'16;23 5 02/22/13 16:57 1 02/22/13 16:57 1 TestAmerica Nashville Page 10 of 46 2/28/2013 Client: ARCADIS U,S. Inc Project/Site : EM 42094 Client Sample ID: MW-7 Date Collected: 02/19/13 16:50 Date Received: 02/21/13 08:45 Client Sample Results Method, SM6200-B - Volatile Organic Compoun Analyte trans-1,3-Dichloropropene 1,2,3-Trichlorobenzene 1,2, 4ETrichlorobenzene 1,1,2-Trichlor'oethane 1,1,1-Trichloroethane Tiichioroethene Tric h I orofluo roan e t h a n e 1,2,3-Trichlor propane 5-Tnanethylbenzene 1,2,4= Trimethy lbenzene Vinyl chloride xylenes, Total Surrogate 1„2-©ichlormethane-d4 (Satan) 1,2-0Ich/oroethane-d4 (Surr) Toluene46 (Surr) Litduene-d8 (Sun-) 4-Bromartu©rmbenzene (Surr) 4-Bromofluombenzene (Surr) Dibromofluoronneltlane (Suer) CD ibromoQuoromethane (Surr) Result ND NO ND 6,01 ND 131 ND ND ND 0,610 ND 2,58 %Recovery Qualifier 98 106 90 102 102 96 100 MDL Unit ug/L ug1L 0.500 ug/L 0.500 ugfL 0.500 u,g/L 0.500 ugfL 0.500 ug/L. 0.500 ug/L 0.500 ug/L 0-500 ug/L 0.500 ug1L 0.500 ug/l. Limits 70.130 70. 130 70. 130 70 -130 70_130 70 130 70-130 70. 130 TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ilk: 490-20114-3 Matrix: Ground Water Prepared Analyzed 02r22/ 13 1d:57 02/22113 16:57 1 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16:57 1 02/22/13 16 57 1 02/22/13 16' 57 1 02/22/13 16:57 1 02/'22/13 16:57 1 02/22/13 16:57' 1 02/22/13 16:5. 1 02122/13 16:57 1 Analyzed L?1d Fac 02 22/13 16r57. ..- 02/27/1316:23 5 02/22/13 '16:57 1 0227/1316,23 5 02/22/13 16; 57 1 02'27/13 /6,23 5 02/22'13 16:57 1 02/27/1316:23 5 TestAmerica Nashville Page 11 of 46 2/28/2013 Client Sample Results Client: ARCADIS U S Inc TestAmerica Job ID; 490-20114-1 Project/Site: EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: MW-8 Date Collected: 02J20/13 15:00 Date Received: 02/21/13 08:45 Lab Sample ID: 490-20114-4 Matrix: Ground Water Method: SM6200-B - Volatile Organic Compounds e AnakW Result Qualifier RL MDL Unit D PreAnalyzd pared Oil Pac , , Benzene 17,3 ug/L 1 02/22/13 13:30 0 500 Eromobenzene ND 0.500 ug/L 02/22/13 13:30 1 Bromochloromethane ND 0500 ug/L 02/22/13 13:30 1 , Brornodichloromethane ND 0.500 ug/L 02122/13 13:30 1 Bromolorm ND 0500 ug/L 02/22/13 13:30 1 , Eromomethane ND 0500 ug/i. 02/22113 13:30 1 Carbon tetrachloride ND 0 500 ug/L 02/22/13 13:30 1 Chlorobenzene NO 0.500 ug/L 02122/13 13:30 1 Chloroethane NO 0.500 ug/L 02/22/13 13:30 1 Chloroform NO 0500 ug/L 02/22/13 13:30 1 , Chlorom0500 ethane NO ugil. 02/22/13 13:30 1 4-Chlorotoluene ND 0,500 ug/L 02122/13 13:30 1 2-chiorotowene NO 0.500 ug/L 02/22/13 13;30 1 cls-1,2-Dichtoroethene 4,39 0,500 ug/L. 02122/13 13:30 1 cis-1,3-Dichlorooropene ND 0,500 ug(L 02,22/13 13:30 1 Dibromochlorornethane ND 0.500 ugil.. 02/22/13 13:30 1 ! 1,2-Dibromo-3-Chloropropane ND 0,500 ug/L 02122113 13:30 1 12-Dibromoethane (EDB) NO 0500 ug/L 02/22/13 13:30 1 , Dibrornornethane ND 0,500 ug/L 02/22/13 13:30 1 1,2-Dichlombenzene ND 0.500 ug/L 02/2203 13:30 1 105,00 ug/1.. ,3-Dichlorobenzene ND 02/22/13 13:30 1 1,4-Dichlorobenzene ND 0,500 ug/L 02122113 13:30 1 Dichlorodffluoromethane ND 0.500 ug/L. 92122113 13:30 1 1,1-Dichloroethane ND ug/L 1 0.500 02/22/13 1,3:30 1,2-Dichlomethane ND 0,500 ug/L, 02122113 13:30 1 1,1-Dichloroethene ND 9500 ug/L 02/22/13 13:30 1 1,2-Dichloropropene ND , 0.500 ug/L 02/22/13 13:30 1 1 ,3-Dic,hlo rop ropa ne ND uglL 02/22/13 13:30 1 0.500 2,2-Dichloropropane ND 0500 ug/L 02/22/13 13:30 1 , 1,1-Dichloropropene ND 0,500 ug/L 02/22/13 13:30 1 Diisopropyl ether 0874 0,500 ug/L 02J22.113 13:30 1 Ethanol . NO 100 ug/L 02/2,2/13 13:30 1 Ethylbenzene 2,80 0.500 uge, 02/22/13 13;30 1 Hexathlorobutadiene NO 1.00 ug/L 02/22/13 13:30 1 lsopropylbenzene ND 1.00 ug/L 02/22/13 13:30 1 Methylene Chloride ND 5,00 ug/L 02/22/13 13:30 1 Methyl tel-butyl ether ND 0.500 ugiL 02122/13 13:30 1 Naphthalene ND 5,00 ug/L 02122/13 13:30 1 n-Eutylbenzene NO 1 0,500 ug/L 02/22113 13:30 1 N-Propyibenzene ND 0 500 ug/t. 02/22/13 13:30 1 p-Isopropyttoluene ND 0.500 tig/L. 02/22/13 13:30 1 sec-Butylbenzene ND 0,500 ug/L 02/22/13 13:30 1 Styrene ND 0.500 ug/L 02/22/13 13:30 1 ten-Butyibenzene ND 0.500 ug/L 02122/13 13:30 1 1 ,1 „1,2-Tetrachloroethane ND 0,500 ug/L 02/22/13 13;30 1 1,1 ,2,2-Tetrachloroethane ND 0500 Ligil, 02122/13 13:30 1 Tetrachioroathene 10.9 0.500 ugii, 02/22113 13:30 1 Toluene 17,2 0 500 ogit 02/22/13 13:30 1 trans-1,2-Dichloroethene ND 0.500 ug/L 02/22/13 13:30 1 TestAmerica Nashville Page 12 of 46 2/28/2013 Client Sample Results Client ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: MW-8 Date Collected: 02/20113 15:00 Date Received: 02121113 08:45 Method: SM6200-B - Volatile Organic Compounds (Continued) Anaiyte Result. Qualifier trans 1,3-Dochloropropene ND 1,2, 3-Tnchlorobenzene ND 1,2,4-Tnchlorobenzene 1,1,2-Trlchloroethane 1,1,1-Trichloroethane Trizhloroethene Tnc h lorofluoro meth a n e 1, 2, 3-Trchloroptopane 1, 3,5-Trlrnethyl benzene 1,2,4-Trirne/trylbenzenn Vinyl chloride Xylenes,, Total Surrogate 1,2-Di'ccloroet1ane-de (Sun.) Toluene-d8 (Surr) 4-Bn3mniluo,rbenzene (Surr) Dibromofluorr.methane (Surr) ND ND ND 3,74 ND ND 1,21 3.60 ND 15,5 %Recovery Qualifier /00 97 101 99 MDL 0.500 0,500 0-500 0.500 0.500 0.500 0500 0.500 0.500 0-500 0 500 0.500 70. 130 70. 130 70. 130 Unit ug/L ug1L ugiL ugil ug)L u91L ug1L ug)L. ug1L. u9)L u,9)L ug/L TestAmer ca Job ID: 490.20114-1 SDG: 3721 Freedom Driver Charlotte, NC Lab Sample ID: 490-20114-4 Matrix: Ground Water D Prepared Analyzed Dil Fes 02/22/13 13:30 1 02,22/13 13:30 1 02/22/13 13:30 1 02/22/13 13:30 1 02/22/13 13:30 1 02/22113 13:30 1 02,22/13 13:30 1 02.122113 13;30 1 02,22,13 13:30 1 02/22/13 13:30 1 02/22/13 13:30 1 02122/13 13:30 1 Prepared Anafy d Fes 0 1 02/22/1313:30 1 02/22/13 13:30 1 TestAmerica Nashville Page 12r o 46 2/28/2013 Client Sample Results Client; ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: MW-10 Date Collected: 02120/13 10:15 Date Received: 02/21/13 08:45 Method: SM6200-B - Volatile Orgarn'ic. Compounds Analyte Result Qualifier Benzene rom©benzene abtttorc111retharte Carbon tetrachloride Chlorobertnzene Chloroethane Chloroform Chloromethane 4-Ch orotoluene 2-Chlarotoluene ,2-Dichloroethene Dichloropropene D"rbromochlorome tha ne 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane (EOB) Dibromamethane 1,2-Dichlorobenzene 1.3 Dichlorobenzene 1,4-Dichlorobenzene Dichl orodifluoromethane 1,1-DPchloroethane 1,2-Dichloroethane 1,1-Dich/oraetlhene 1,2-Dichloropropane 1,3-Dichloropropane 22-D'ichloropropane Dichloropropene propyl ether Ethylbenzene Hexachlorobutarliene pyiberizene ylene Chloride Methyl tert-butyl ether Naphthalene n-autylbenzene N-Propylbenzene p-Isopropyitoluene -Butylbenzene !benzene Tetrachloroethane ,2, 2-Tetrachloroethane Tetrachloroethene ToPuone trans-1,2-Dichloroethene ND ND ND NO NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2050 ND 2230 ND 53.2 ND 3090 899 66.,4 229 ND 13.2 434 ND NO ND ND 23600 ND RL IWtaL Unit 100 10.0 ug/L 10,0 ug/L 10.0 ug/L 10,0 ug/L 10,0 ug/L 10.0 ug/L 10.0 ug/L 10,0 ug/L 10,0 ug/L 10.0 ug/L 10,0 ug/L 1110 ug/L 10,0 ug/L 10,0 ug/L 10,0 ug/L 10,0 ug/L 10.0 ug/L 10,0 ug/I. 100 ug/L 10,0 ug/L 10,0 ug/L 10.0 ug/L 10.0 ug/L 10,0 ug/L 10.0 ug/L 10,0 ug/L 10,0 ug/L 10,0 ug/L 10,0 ug/L 10.0 ug/L 2000 ug/L 10,0 uglL 20,0 ug/L, 20,0 ug/L 100 ug/L 10.0 ug/L 100 ug/L 10,0 ug/L. 10,0 ug/L 10.0 ug/L 10.0 ug/L 10,0 ug/L, 10,0 ug/L 10,0 ug/L 10.0 ug/L 10.0 ug/L 100 ug/L. 10,0 ug/L TestAmerica Job ID: 490-20114-1 SDG'. 3721 Freedom ©rive, Charlotte, NC Lab Sample ID: 490-20114-5 Matrix: Ground Water Anatlrz Dill Fab 02/22/1319:32 200 02/22/13 18 06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319.06 20 02/22/1319:06 20 02122/1319,06 20 02/22/1319:06 20 02/22/1319;06 20 02/22/1319:06 20 02/22/13 19:06 20 02/22/1319:06 20 02/22/1319,06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/13'19.06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319;06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319:06 20 02122113 19,06 20 02/22/1319:06 20 02/22/13 19:06 20 02/22/1319;06 20 02/22/1319:06' 20 02/22/1319:06 20 02/2211319;06 20 02/22/13 19:06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/13 19:06 20 02/22/1319:06 20 02/22/13 19:06 20 02/27/13 17:15 20 02/22/1319:06 20 02/22/13 19:06 20 02/22/1319:06 20 02/22/1319:06 20 02/22/13 19:06 20 02/22/1319:06 20 02122/1319:06 20 02/22/1319;06 20 02/22/1319:32 200 02/22/1319:06 20 TestAmerica Nashville Page 14 1f 46 2/28/2013 Client Sample Results Client: ARCADIS U,5. Inc Project/Site: EM 42094 Client Sample ID: MW-10 Date Collected: 02/20/13 10:15 Date Received: 02121113 08:45 Method: SM6200-B - Volatile Organic Compounds (Continued) Acolyte Result Qualifier trans-1, 3-D ichlor©propene ND 1, 2, 3-T ric h l o robe nze n e 1, 2,4-Tnchl©robe nzene 1,1,2-Tnchloroethane 1,1,1-Tnchloroethane Trichloroethene Trichlorotl uoromethane 1,2, 3-Trichloropropa ne 1,3,5•Trkrnethy kbenzene 1.2,4-Trimethylbenze ie Vinyl chloride Xy,lenes, Total Surrogate 1 2-O chtortrethane-c4 (Sur) 1,2-Oichloroethene-d4 (Surr) 1,2-Dichloroethane-d4 (Sun) Toluene-d8 (Surr) Toluene-d8 (Surr) Toluene-d8 (Surr) 4-Bmmo6uorobenzene (Surr) 4-Bromofluorobenzene (Surr) 4-8r4mofluombenzene (Surr) Dibromaftuoromethane (Surr) UUibromofluoromethane (Surr) Dibromofluoromethene (Surr) ND NO NO ND NO ND NO 621 2350 NO 13900 RL 10.0 100 10,0 10,0 10,0 10.0 10.0 10,0 10,0 10,0 10,0 100 %Recovery Qualifier Limits 96 70.130 98 100 99 100 87 104 102 102 95 96 101 70s.130 70- 130 70. 130 70. 130 70_130 70.130 70 .130 70_130 70- 130 70. 130 70.130 MDL Unit ug/L ug/L ug/L ug/L ug/L ugh, ug/L ug/L ug/L ug/L ug/L ug/L TestAmerica Job ID. 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC b Sample ID: 490-20114-5 Prepared Prepared 02/22/13 19: 32 02/27/13 17 15 02/22/13 19:06 02/2 /13 19:32 02/27/13 '1 7 15 02/22/13 19.:06 0,2/22/13 19:32 02/27/13 17:15 02/22/13 19:06 02/22/13 19:32 02/27/13 17:15 Matrix: Ground Water Anatylwed 02 22113 19:06 02/22/13 19.06 02/22/13 19:06 02/22/13 19:06 02/22/13 19:06 02/22/13 19:06 02/22/13 19:06 02/22/13 19:06 02/22/13 19:06 02/22/13 19,06 02/22/13 19[06 02/22/13 19 32 ©ll Fec 20 20 20 20 20 20 20 20 20 20 20 200 Analyzed Dil Fac 22r°P 19:06 20 200 20 200 20 20 200 20 20 200 20 TestAmerica Nashville Page 15 of 46 2/28/2013 Client Sample Results Client ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: DW-1 Date Collected: 02/20113 13:15 Date Received: 02/21/13 08:45 Method: SM6200-13 - Volatile Organic Compounds Analyte Result Qualifier Benzene Bromobenzene Bromochloromethane Bromodiichlorometl ane Bromoform Bromomethane Carbon tetrachloride Chiorobenzene Chloroethene Chloroform Chloromethane 4-Chlorotoluene 2-Chlorotoluene cis-1 „2 •Dichloroethene cis-1„3-Dichloroprogene Dibromochioromethane 1,2•Dibromo-3-Chloropropane 1,2-Dibrornoethene (EDB) D'ibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodilluorornelha ne 1,1-Dichloroethene 1,2-Dichloroethane 1,1-Dichloroethene 1,2-Dtchloroprapene 1, 3-Dichloropropene 2,2-Dichloropropane 1,1-Dichloropropene Diisopropyl ether Ethanol Ethylbenzene Hexachlorobutadiene sopropylbenzene hylene Chloride utyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-Isopropyltoluene sec-Buhylbenzene Styrene tert-Butylbenzene 1„1,1,2-Tetrachloroethane 1,1,22-Tetrachloroethane Tetrechloroethene Toluene trans-1, 2-Dichloroethene ND ND Nfl ND ND ND ND ND ND ND NO NOD ND ND ND ND ND ND ND ND ND ND ND ND N' D NO ND ND ND 17,0 ND NO NO ND ND ND ND NO ND ND ND ND ND ND NO ND 56.4 ND TestArrterica Job ID, 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-6 Matrix: Ground Water RL INDL Unit D Pre ared Art lyzed Dll Fac ug1L 02/22113 17:23 5.00 ug/L 02/22/1317:23 10 5,00 ug/L 02/22/13 17:23 10 5-00 ug/L 02/22/1317'23 10 5,00 ug/L 02/22/13 17:23 10 5,00 ug/L 02/22/13 17:23 10 5,00 ugfL 02/22/13 17:23 10 5.00 ug/L 02/22/1317,23 10 5.00 ug/L 02122/13 17:23 10 5.00 ugfL 02/22/13 17:23 10 5.00 ug/L 02122/1317:23 10 5,00 ug/L 02/22/13 17:23 10 5.00 ugfL 02/22/13 17:23 10 5.00 u9/L 02/22/13 17:23 10 5.00 ug/L 02/22/13 17:23 10 5.00 ug/L 02/22/1317.23 10 5,00 ug/L 02/22J13 17:23 10 5.00 ug/L 02/22/13 17:23 10 5.00 u0/L 02/22/1317;23 10 5.00 ug/L 02/22113 17:23 10 5.00 ug/L 02/22/13 17:23 10 5.00 ug/L 02/22/13 17:23 10 5.00 ug/L 02/22/1317,-23 10 5,00 ugh. 02/22/13 17:2310 5.00 ug/L 02/22/13 17:23 10 5.00 ug/L 02122/1317:23 10 5.00 ugh. 02/22/13 17:23 10 5.00 ug/L 02/22/13 17:23 10 5,00 ug/L 02122/1317:23 10 5.00 ug/L 02/22/13 17`23 10 5-00 ug/L 02/22/1317:23 10 1000 u0/L 02/22,1317:23 10 5.00 ug/L 02/22/1317.23 10 10,0 u0/L 02/22/13 17:23 10 10.0 ug/L 02/22113 17:23 10 50.0 ug/L 02/2211317:23 10 5,00 ug/L 02/22/1317.23 10 50,0 ug/L 02/22/1317-23 10 5,00 ug/L 02/22/1317.'23 10 5,00 ug/L 02€22/1317:23 10 5.00 ugfL 02/22/13 17:23 10 5,00 ug/L 02/22/1317''23 10 5,00 ug/L 02/22/13 17:23 10 5,00 u0/L 02/22/13 17:23 10 5.00 ugfL 02/22/13 17:23 10 5,00 ugh. 02/22/1317:23 10 5,00 ug/L 02/22/1317,23 10 5.00 ug/L 02/22/1317,23 10 5.00 ug/L 02/22/13 17:23 10 TestAmerit Nashville Page 16 of 46 2128/2013 Client Sample Results Clierit ARCADIS U,S, Inc Project/Site: EM 42094 Client Sample ID: DW-1 Date Collected 02120/13 13:15 Date Received: 02/21/13 08:45 Method: SM620043 Volatile Organic Compounds (Continued) Analyte Result Qualifier trans-1,3-Dichloropropene ND 1 2,3-Tnchlorebenzene ND 1,2,4-Trich4orobenzene ND 1,102-Tnchlornothane ND 1,1 1-Tnchlernethane ND inctiParoethene ND inchforofluommethane ND 1 2 3-Tnchlerapmpane ND 1,5 5-Trunethyl benzene ND 1,2,4-TrimethyPbenzene 541 Vinyl chloride ND Xy Penes , Total 34.2 Surrogate %Recovery Qualifier 1,2-Dichloroefhane-04 (Surr) 95 Toluene -dB (Surr) 99 4-Bromonuorabenzena (Surr) 101 Dibromoffuorornethane (Surr) 95 RL MM. Unit 5,00 ug/L 5,00 ug/L 5.00 ug/L 5.00 ug/L 5 00 ug/L 5 00 ug/L 5 00 ug/L 5 00 ug/t. 5.00 ug/L 5.00 ugii. 5.00 ug/L 5.00 ug/L Umfts 70 _ 130 70 _130 70 -130 TestAmerica Job ID: 490-20114-1 SDG; 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-6 Matrix: Ground Water D Prepared Analyzed Dil Fac 02/22/13 1723 10 02/22/13 17:23 10 02/22/13 17:23 10 02/22/13 17:23 10 02/.22/13 1723 10 02/22/13 1723 10 02122/13 1723 10 02/22/13 17:.23 10 02./22/13 1723 10 02/22/13 1723 10 02122113 1723 10 02122/13 1723 10 Prepared Analyzed Da Fee 02/22/13 17:23 10 02/22/13 1723 02/22/13 1723 02/22/13 1723 10 10 10 TestAmerica Nashville Page 17 of 46 2/28/2013 Client: ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: aW-2 Date Collected: 02/20/13 08:50 Date Received: 02/21/13 08:45 Method: SM6200-B Volatile Organic Compounds Result Qualifier 5850 ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND 1470 ND ND ND ND ND 8160 ND 25,5 ND 32.7 ND 1040 196 7.30 40.8 38.1 ND 12,1 ND ND ND ND 50,2 NO Analyte 8romobenzene tlrrimec h l or©methane 13 romod ich l oro me th a n e Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chlorbethane Chloroform Chforomethane 4-Chloroicluene 2-Chlorotoluene cis-1,2-Dechloroethene cis-1, 3-Dichloropropene Dnbromochlor methane 1,2-Debromo-3•C hloropropane 1,2-D/bromoethane (ED13) Dibromomethane 1,2-D1chIorobenzene chlerobenzene 1 „4-Dichlorobenzene Dichlorod'ifluoromethane 1,1-Dichloreethane 1,2-Dichloroethane 1,1-Dichtoroethene 1,2•Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene Dilsopropyl ether Ethanol Ethylbenzene Hexachlarobutadiene lsopropylbenzene Methylene Chloride Methyl tent -butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-Isapropyl'toluene see-8utylbenzene Styrene tart-Butylbenzene 1,1,1,2-Tetrachloroethane 1,1 „2,2-Tetrachloroethane Tetrachloroethene Toluene Iran& 1,2-Dichloroethene Client Sample Results RL MDL. Unit 0.0 ug/L 5.00 ug/L 5.00 ug/L 5.00 ug/L 5,00 ug/L 5.00 ug/L 5,00 ug/L 5.00 ug/L 5,00 ug/L. 5.00 ug/L 5.00 ug/L 5,00, ug/L 5,00 ug/L 5,00 ug/L 5.00 ug/L 5,00 ug/L 5.00 ug/L 5,00 ug1L 5.00 ug/L 5.00 ug/L 5..00 ug/L 5.00 ug/L 5.00 ug/L 5,00 ug/L 5,00 ug/L 5,00 ug/L 5.00 ug/L 5,00 ug/L 5.00 ug/L 5.00 ug/L 50,0 ug/L 1000 ug/L 5,00 ug/L 10,0 ug/L 10.0 ug./L 50,0 ug/L 5.00 ug/L 50.0 ug/L 5.00 ug/L 5.00 ug/L 5,00 ug/L 5.00 ug/L 5.00 ug/L 5.00 ug/L 5.00 ug/L 5.00 ug/L 5.00 ugh. 5.00 ug/L 5.00 ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 49O-20114-7 Matrix: Ground Water Prepared Analyzed DO Pat �02/22/13 20r24 100 02/22113 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19.58 10 02/22/13 19.58 10 02/22/13 '19,58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19,58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19;58 10 02/22/13 19.58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19.58 10 02/22/13 19:58 10 02122/13 19:58 10 02/22113 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 20:24 100 02122113 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/27/ 13 17:41 10 02/22/13 19:58 10 02122/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19:58 10 02/22/13 19;58 10 TestAmerica Nashville Page 18 of 46 2/28/2013 Client: ARCADIS U S. Inc Project/Sate: EM 42094 Client Sample ID: DW-2 Date Collected: 02/20/13 08:50 Date Received: 02121/13 08:45 Method: SM6200-B - Volatile 4rga Analyte trans 1.3-Dichlorppropene 1, 2, 3-Tric h lei robe nze n e 1,2,4-Trichlorobenzene 1,1,2-Trichl©roethane 1,1,1-Trichloroethane Trichloroethene Trichlorofluoromethene 1, 2, 3-Trlchloropropa ne 5-Trimethyl benzene 1 „2,4-Tn methyl benzene vinyl chloride Xylenes, Total Surrogate 1„2-Dichloroethane4 (Suer} -13/chkrethane-d4 (Surr) -Dichl©roothene-d4 (Surr) e-d8 (Surr) Toluenead8 (Surr) Toluene-d8 (Surr) 4-Br©mo8uombenzene (Surr) 4-Brorno1Yuombenzene (Surr) 4-Hromolluombenzene (Sure) Dibromoiluoromethana (Sure) ©ibromo8uammethane (Surr) Dibromofuoromethene (Surr) Client Sample Results is Compounds (Continued) Result Qualifier ND ND ND 6,30 ND ND ND ND ND ND 5.12 2566 %Recovery Qualifier 95 92 97 100 98 90 103 101 100 95 94 98 RL 5,00 5,00 5.00 5,00 5.00 5,00 5.00 5,00 5.00 5.00 5.00 70> 130 70.. 130 70. 130 70.130 70. 130 70 .130 70,,130 70, 130 70.130 70. 130 70. 130 70.130 MDL Unit ug/L ug/L ug/L ug/L. Ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L TestAmerica Job ID: 490-20114-1 721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-7 Matrix„ Ground Water Prepared Analyzed 0i1 Fac 02/22/13 19.58 10 02/22/13 19: 58 02/22/13 19:58 02/22/13 19:58 02/22/13 19 58 02/22/13 19,58 02/22/13 19:58 02/22/13 19:58 02/22/13 19:58 02/22/13 '19:58 02/22/13 19:58 02/22/13 19:.58 Prepared Analyzed 20.24 02/27/13 17.41 02/22/13 19: 58 02/22/13 20:24 02/27/13 17:41 02/221/3 19:58 02^22/13 20:24 02/27/13 17.41 02/22/13 19.58 02/22/13 20.24 02/27/13 '17:41 10 10 10 10 10 10 10 10 10 10 10 it Fos 10 100 10 10 100 10 10 100 10 10 100 10 TestAmerica Nashville Page 19 of 46 2/28/2013 Client: ARCADIS U.S, Inc ProjectiSite: EM 42094 Client Sample ID: DW Date Collected: 02120/13 1 Date Received: 02/21/13 08:45 Method. SM620043 - Volatile Organic Compounds Analyte Bromobenzene Bromochloromethane Bromodichloromethane Bromotoran Brc momethane Carbon tetrachloride C hlorobe nzene Chloroe'thane C hloroform Chbrclme1hane 4-Chlorotoluene 2-Chlorolotuene cis-1 „2-Dichloroethane cis-1,3-Dichloropropene CDibromochlorometh a ne 1,2-DTbromo-3-ChYoropropane 1,2-Dibromoethane (EDB) 0ibromomethane 1,2-Dichlorobenzene 1,3-Dlchlorobenzene 1,4-Dichlorobenzene Dk hIorodi1ucwwmethane 1,1-Dichloroethane 1,2-Drchlbroethane 1,1-Dichloroethene 1,2-D/chtoropropane 1,3-Dichloropropane 2,2-D)chloropropane 1,1-Dichloropropene Diisopropyl ether Ethanol Ethylbenzene Hexachlorobutadiene Isopropytbenzene Methylene Chloride Methyl tart -butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-Isopropyttoluene sec-Butylber1zene tyrene utylbenzene , 2 -Te tra c h l o roeth a ne -Tetrachloroethane Tetrachloroethene Toluene trans-1.2-Dichloroethene Client Sample Results Result Qualifier 2 ND ND ND ND NO ND ND ND ND ND ND ND NO ND ND ND NO NO NO ND NO ND ND ND NO ND ND ND ND 116 ND 12,5 ND 6,44 NO 145 54.1 1,64 2,17 ND 1,10 5,"24 NO ND NO NO 122 ND RL 2.50 0, 500 0,500 0.500 0,500 0,500 0.500 0,500 0,500 0.500 0.500 0,500 0.500 0,500 0,500 0.500 0,500 0.500 0.500 0.500 0,500 0,500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0,500 100 0.500 1..00 1,00 5.00 0,500 5,00 0.500 0.500 0.500 0,500 0,500 0,500 0,500 0.500 0.500 0,500 0.500 MDL Unit ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ugfL ug/L ug/L u g/L ug/L ug/L ug/L ug/L u g1L ug/L ug)L ug/L. ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug1L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L. ug/L ug1L ug/L ug/L ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-8 Matrix: Ground Water Prepared Analyzed Dil Fat 2 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22113 15:40 1 02/22/13 15.40 1 02/22/13 15:40 1 02/22/13 15:40 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22113 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22113 15:40 1 02/22/13 15:40 t 02/22113 15:40 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15c40 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15'40 1 02/22/13 15'40 1 02/22/13 15:40 1 02/22/13 '15:40 1 02/22/13 1540 1 02/22/13 15:40 1 02/27/13 15:57 1 02/22/13 15:40 1 02/22/13 15:40 1 02/22/13 15:40 1 02122/13 15:40 1 02J22113 15:40 02/22/13 15:40 1 02/22/13 15:40 1 02P22/13 15:40 1 02/22113 15:40 1 02/22/13 15:40 1 TestAmerica Nashville Page 20 of 46 2/28/2013 Client Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: DW-3 Date Collected: 02/20/13 11:05 Date Received: 02/21/13 08:45 Method: SM6200-B - Volatile Organic Compounds (Continued) Anatyte trans-1,3-Dichloropropene 1,23-Trichlorobenzene 1„2,4-Trichlorobenzene 1,,1,2-Trichloroethane 1,1,1-Trichloroethane TricNoroethene Trichlorofluororrtethane 1,2,3-Trichforopropane 1,3,5-Trimelthylbenzene 1,2,4-Trimethylbenzene Vinyl chloride xylenes, Total Surrogate 1,2-Dichforoethane-O4 (Surr) 1,2-Dich1eroetriane-d4 (Surr) 1,2-Dichloroethane-O4 (Sun') Toluene -dB (Surr) Toluene-d8 (Sun') Toluene-d8 (Sun') 4.8romolluerobenzene (Surr) 4-Bromofluorobenzene (Surr) 4-Bromoffuorobenzene (Surr) Debromofluoromethene (Surr) Dibromofluoromethene (Surr) Dibromofluoromethane (Surr) Result Qualifier RL ND 0 500 ND 0 500 ND 0 500 ND 0 500 ND 0 500 ND 0 500 ND 0 500 ND 0 500 3,79 0 500 13,4 0 500 ND 0 500 73.6 0 500 %Recovery Qualifier Limits 94 70 _130 94 70 .130 97 70 -130 99 70 _130 100 70 , 130 88 70 _130 102 70 .130 100 70 _130 102 70 _130 94 70 _130 96 70 _130 97 70 .130 MOL Unit ug/L ug/L ug/L ug/L ugiL ug/L ug/L ug/L ug/L ug/L ug/L ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-8 Matrix: Ground Water 0 Prepared Analyzed 02/22/13 1540 02/22/13 1540 02/22/13 15:40 02/22/13 154.0 02/22/13 15:40 02/22/13 1540 02/22/13 15:40 02/22/13 15:40 02/22/13 15:40 02/22/13 15:40 02/22/13 1540 02/22/13 1540 Oil Fac 1 1 1 1 1 1 1 Prepared Analyzed Di! Fac 2/13 1540 1 02/22/13 16:05 5 02/27/13 /557 02/22113 1540. 02/22/13 1605 02/27/13 15:57 02/22/13 1540 02/22/13 1605 02/27/13 1557 02/22/13 1540 02/22/13 16:05 02/27/13 15:57 1 5 1 5 1 1 TestAmerica Nashville Page 21 of 46 2/28/2013 Anatyte Benzene romobenzene h Bromo Bromomethacne Carbon tetrachloride C hlorobenzene C hloroethane Chloroform Chloromethane 4-Chlorotoluene 2-Chlorotoluene cis-1, 2-Dichloroethene c/s-1.3-D ich l oro p rope ne Dibromochloromethane 1, 2-Dibromo-3-C hlo ropropane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichi'orobenzene 1, 3-Dich/orobenzene 1,4-Dichlo robenzene D ich lorod i0 u ono me the n e 1,1-Dichk roethane 1,2-Dichkoroethane 1,1-Dichle roethene 1,2-Dichloropropane 1, 3-Dichloropropane 2 2-Dichloropropane 1,1-Dlchloropronpene Diisopropyl ether Ethanol Ethylbenzene I-t ex a c h I o robu t ad i e n e Isopropylbenzene Methylene Chloride Methyl tert-butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-llsopropyltoluene sec-Butylbenzene Styrene tosrt--B uty I Benz e n e 1 1,2-Tetrachloroethane 2,2-Tetrachloroethane Tetrachloroethene Toluene trans-1,2--Dichloroethene Client Sample Results CI ent: ARCADIS U,S, Inc Project/Site: EM 42094 Client Sample ID: Trap Blank Date Collected: 02119113 00:01 bate Received: 02/21/13 08:45 d: SM620043 Volatile Organic Compounds Result Qualifier ND N' D ne ND oromethane ND ND ND ND ND ND ND ND ND ND ND NO NO NO ND ND NO ND ND ND ND ND ND NO NO NO ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND RL MDL Untt 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ugiL 0,500 ugfL 0,500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0-500 ug/L 0.500 ug/L 0.500 uglL 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L. 0.500 ug/L. 0,500 ug/L 0.500 ug/L 0,500 ugiL 0.500 ug/L. 0..500 ug/L 0.500 ug/L 100 ug/L 0.500 ug/L 1.00 ug/L. 1.00 ug/L 5.00 ug/L 0 500 ug/L 5.00 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug/L 0.500 ug1L 0.500 ug/L 0.500 ugfL 0 500 ug/L TestAmsrica Job I SDC : 3721 Freedom drive Lab Sample ID: Prepared D: 490-20114.1 Charlotte, NC 490-20114-9 Matrix: Water Analyzed Dit Fac 02122/'t 3 13:04 1 02/22/13 13'04 1 02/22/13 13:04 1 02122113 13:04 1 02/22/13 13:04 1 02/22/13 13.04 1 02122113 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22113 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 02/22113 13:04 1 02122/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02122/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04. 1 02/22/13 13:04 1 02/22/13 13:04 1 02122/13 13:04 1 02/22/13 13:04 1 02122/13 13:04 1 02/22/13 13104 1 02/22113 '13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13104 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22113 13:04 1 02122113 13:04 1 02/22/13 13:04 1 02122/13 13:04 1 02/22,13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 TestAmerica Nashville Page 22 of 46 2/2812©13 Client: ARCADIS U.S. Inc Project/Site: EM 42094 Client Sample ID: Trip Stank Date Collected: 02/19113 00:01 Date Received: 02(21/13 08:45 Method: SM6200- Anafyte trans-1, 3-Dichloropropene 1,2,3-Tr chiorobenzene 1, 2,4-Trichlorobenzene 1,1,2-Trichloroethane 1,1,1-Trichloroethe ne Trochloroethene TrichIoro luoromethene 1, 2, 3-Trichloropropane 1, 3, 5-Trimethylbenzene 1, 2,4-Trimethyl benzene Vinyl chloride Xylenes, Total Surrogate Client Sample Results Volatile Organic Compounds Con Result Duniifier ND ND ND ND ND ND ND NO ND ND ND ND 1,2-©ichloroethane-d4 (Surr) Toluene-d8 (Surr) 4-Bromofuorobenzene (Surr) Dibramofluoromethane (Surr) %Recovery Qualifier 95 97 102 97 RL ©,500 0,500 0,500 0,500 0,500 0,500 0.500 0,500 0,500 0.500 0.500 0,500 Limns 70 130 70-130 70. 130 70,130 MDL Unit U9PL, ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L TestAmerica Job ID: 490-20114-1 SDC: 3721 Freedom Drive, Charlotte, NC Lab Sample ID: 490-20114-9 Matrix: Water 0 Prepared Analyzed Dil Fac 02/22/13 13:04 1 02/22113 13.04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22,/13 13,04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 92/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 02/22/13 13:04 1 Analyzed f3ff Fac 1 02/22/13 13:04 1 02/22/13 13:04 1 TestArnerica Nashville Page 23 of 46 2/26/2013 QC Sample Results Client: ARCADIS U,S, Inc Project/Site: EM 42094 Method: SM6200-B - V'olatiOrganic Compounds Lab Sample Id. MB 490-60479/7 Matrix; Water Analysis Batch: 60479 MB MB Acolyte Result Qualifier RL MDL Unit Benzene ND 0.50t1 rrg/1. Bromobenzene ND 0.500 ug/L Brornochlorornethane ND 0,500 ug/L Bromodichloromethane ND 0-500 ug/L Bramofomi ND 0.500 t10/L Bromomethane ND 0.500 ug/L Carbon tetrachloride ND 0.500 ug/L Chlorobenzene ND 0,500 ugfL Chloroethane ND 0.500 ug/L Chloroform ND 0.500 ug/L Chloromettrane ND 0,500 ug,/in 4-Chlorotoluene ND 0.500 ug/L 2-Chiorotoluene ND 0,500 ug/L cis,-1,2.D/chloraethene NO 0,500 ug/L cis-1,3-Dichtoropropene ND 0.500 ug/L Dibromochloromethane ND 0.500 ugfL 1,2-Dibromo-3-Chloropropane ND 0,500 ug/L 1„2.Dibromoethane (EDB) NO 0.500 ug/L Dlbromomethane NO 0,500 ug/L 1,2-Dichlorvbenzene ND 0.500 ug/L 1,3-Dichlorobenzene ND 0,500 ug/L 1,4•Dichlorobenzene ND 0.500 ug/L Dichiorod'ifluoromethane ND 0.500 ug/L 1,1-Dichloroethane ND 0.500 ug/L 1,2-Dichlorcethane ND 0,500 ug/L 1,1-Dichloroetflene ND 0,500 ug/L 1,2-Dichloropropane ND 0,500 ug/L 1,3-Dichloropropane ND 0,500 ug/L 2,,2-Dichloropropane ND 0,500 ug/L 1.1•Dichlorepropene N0 0,500 crpl. 0rrsopropyl ether ND 0.500 ug/L Ethanol ND 100 ug/L Ethylbenzene ND 0,500 ugfL Hexachlarobutadiene ND 1,00 ug/L tsopropylbenzene ND 1.00 ug/L 8lethylene Chloride ND 5.00 ug/L Methyl tert-butyt ether ND 0.500 ug/L Naphthalene NO 5.00 ug/L n-8utylbenzene ND 0,500 ug/L N-Propylbenzene NO 0.500 ug/L p-isopropytloluene NO 0.500 ug/L sec-Butylbenzene ND 0.500 ug/L styrene ND 0.500 ug/L tert-Butylbenzene ND 0.500 ug/L 2-Tetrachloroethane ND 0.500 ug/L 1,1,2,2-Tetrachloroethane ND 0,500 ug/L Tetracthoroethene ND 0,500 ug/L j Toluene ND 0.500 ug/L TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: Method Hank Prep Type: Tote NA Prepared A alyzed Dil Fac 22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02122/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12.38 1 02/22/13 12:38 1 02122/13 12:38 1 02122/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 022,213 12:38 1 02/22/13 12:38 1 02/22/13 1238 1 02/22/13 12:38 02/22/13 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 02/22/13 12:38 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1. 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02122/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02122/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 02/22/13 12:38 1 TestAmerica Nashville Page 24 of 46 2/28/2013 QC Sample Results CIi'ent: ARCADIS U.S. Inc Project/Site: EM 42094 Method: SM6200-B - Volatile Organic Compounds Lab Sample ID: MB 490-60479/7 Matrix° Water Analysis Batch: 60479 Analyte trans-1 „2-Dichloraethene trap s-1, 3-Dichloropropene 1., 2, 3-Trichtororobenzene 1,2,4-Trtchtorobenzene 1,1„2 Trichloroeihane a 1-Tnchioroelhane Trichloroethene Tnchloro5uoromeihane 1, 2, 3=Trichloropropane 1, 3,5-Tnmethylbenzene 1, 2,4-Trenethyl benzen e Vinyl chloride Xylenes, Total MB MB Result Qualifier ND ND ND ND ND ND ND ND ND ND ND ND ND ontanued 0 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0.500 0 500 TestAmenca Job ID 490-20114-1 SDG: 3721 Freedom ©rive„ Charlotte, NC Client SalTlple tO: Method Blank Prep Type: Total/NA MOL Unit D Prepared Analyzed ug/L 02/227't3 12... ugfL 02/22/13 12'.38 ugfL 02/22113 12.38 ugfL, 02122/13 12:38 ugfL 02/22/13 12`38 ugfL. 02/22/13 12:38 ugfL 02/22/13 12`38 ugfL 02/22/13 12:38 ug/L 02/22/13 12:38 ugfL 02/22/13 12:38 ugIL 02/'22/13 12:38 ug/L 02/22/13 12.38 ugfL 02/22/13 12:38 MB MB Surrogate %Recovery Qualifier Limits Prepared Analyzed 1,2-Dich1oroethane-d4 (Surr) 97 70'_ 130 7oluen dB (Surr) 104 70. 130 4-8romofluarob®nzene (Surr) 104 70. 130 O+bromofuoromethane (Surd 95 70. 130 Lab Sample ID: LCS 490-60479/3 Matrix: Water Analysis Batch: 60479 Analyte Benzene Bromobenzone BromachIoromethane Bromodichloromethane Bromoform 02/22/13 12:38 02/22/13 12:38 02/22f13 12:38 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS SORac„ Added Result Qualifier Unit D %Ric Limits 50,0 5169 ug/L 104 70..130 50.0 51.99 ugfL 104 70.130 50,0 52.67 u9/L 105 70.130 50,0 55.24 ugfL 110 70.130 50.0 51,39 ug/L 103 70.130 nta 50.0 51.89 u9/L 104 60.140 tllOrtde 50 0 52,69 ugfL 105 70.130 50.0 53.52 ugfL 107 70. 130 Ghlurtaettsane 50.0 51,41 ug/L 103 60 -140 Chloroform 50.0 50.10 ugfL 100 70.130 CChlonamethane 50.0 44,92 ug/L 90 60.140 4-Chlorotoluene 50,0 57.54 ug/L 115 70. 130 2-Chlorotofuene 50.0 55.64 ug/L 111 70. 130 cis-1,2-Dichloreethene 50.0 50,08 ug/L 100 70 _ 130 cis l,3 hloropropene 50.0 54,13 ug/L 108 70. 130 Dibromochloromethane 50.0 54.02 ug/L 108 70-130 1,2-Dlbromo-3-Chloropropane 50,0 55,11 ug/L 110 70.130 Dibrom©metllane 50.0 53.26 ug/L 107 70.130 1,2-Dichlorobenzene 50.0 54,65 ug/L 109 70 _ 130 1,3-Dichtorobenzene 50.0 54,71 ug/L 109 70 - 130 ,4-Dichlorobenzene 50.0 52.60 ug/L 105 70.130 irod,1luoromethane 50.0 49.54 ug/L 99 60 _ 140 ichloroethane 50,0 53,76 ug/L 108 70.130 ene TestAmerica Nashville Page 25 of 46 2/28/2013 QC Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Method: SM6200-B - Vo atiie Or ani Co npound Lab Sample ID: LCS 490-60479/3 Matrix: Water Analysis Batch; 60479 Anatyte 1,2-Dichloroethane 1 ,1 -Dichloroethene t ,2-Dichloropropane 1.3-Dichloropropane 2„2-Dichloropropane 1,1=Dichionapropene Dilsopropyi ether Ethanol Ethylbenzene Fiexachlorobutedlene Isopropylbenzene Methylene Chloride Methyl tert-butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-is.opropyltoluene sec-Butylbenzene Styrene tert-Butylbenzene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetracihloroethane Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1, 3-Dichloropropane 1.2, 3-Trlchlorobenzene 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1-Tmchloroethane Trichloroethane Tnc hlorofluo rornetha ne 1, 2, 3-Trichloropropa ne 1,3,5-Trimethylbenzene 1, 2,4-Trimethylbenzene Vinyl chloride Xylenes, Total ate TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: Lab Control Sample Prep Type; Total/NA Spike LCS LCS %Rec. Added Result Qualifier Unit D %Rec Limits. 0�0 47,49 ugJL 95 70.130 50..0 61,19 ug/L 122 70 - 130 50.0 48,91 u9/L 98 70 - 130 50.0 51.30 ug/L 103 70.130 50.0 56,21 ug/L 112 70 _ 130 50.0 51,73 ug/L 103 70 _ 130 50,0 52,75, ug/L 105 70 _ 130 5000 4292 u9/L 86 60. 140 50.0 55.91 u91L 112 70.130 50.0 54,42 ug/L 109 70 _ 130 50.0 57,00 ugJL 114 70.1343 50,0 57.40 ug/L 115 70-130 50.0 55.59 ug/L 111 70-130 50,0 52.22 ug/L 104 70 _, 130 50.0 63.92 ugJL. 128 70 _ 130 50.0 57,49 ug/L 115 70-130 50,0 59,15 ugJL 118 70.130 50.0 60.85 ug/L 122' 70. 130 50,0 55.76 ug/L '112 70-130 50.0 59,00 ug/L 118 70.130 50,0 52.25 u9/L 104 70 - 130 50.0 54.37 ug/L 109 70 _ 130 50.0 51.99 ugfl. 104 70. 130 50,0 53,01 ug/L 106 70. 130 50,0 56,29 ug/L 113 70.130 50.0 52.09 u9/L 104 70.130 50.0 51,65 ug/L 103 70. 130 50.0 52-50 ug/L 105 70. 130 50.0 50.28 u9/L 101 70-130 50.0 53.02 ug/L 106 70 _ 130 50-0 53-39 ug/L 107 70 _ 130 50.0 49-84 ug/L 10o ear} _ 140 50.0 51,96 ug/L 104 70 m 130 50.0 59.60 u9/L 119 70 _ 130 50.0 59.48 ug/L 119 70. 130 50.0 54,28 u9/L 109 60 _140 150 164.1 ugJL 109 70.130 LCS LCS %Recovery Qualifier Lim 2-[irchloroethartat-d4 (Surr) 94 70 - 130 e48 (Surr) 99 70. 130 uoretierizene (Sure) 102 70. 130 9aro/11sNtane (Surr) 98 70. 130 TestAmerica Nashville Page26of46 2/28/2013 QC Sample Results Client: ARCADIS U.S. Inc Project/Site: BM 42094 Method: SM6200-B - Volatile Organic Compounds (Continued Lab Sample ID LCSD 490-6047914 Matrixr Water Analysis Batch: 60479 Analyte Benzene Bromobenzene Bromochlorontethane Bromodichloromethane Sromotorm Bromomethane Carbon tetrachloride Chlorobenzene Chioroethane Chloroform Chloromethane 4-Chlorotoluene 2-Chlorotoluene cis-1, 2-Dichloroeth ene cis-1.3-Dich oropropene D i bromochlorometh a ne 1,2-Dibromo-3-Chloropropane Dibrom©methane 1,2-Dichlorobenzene ,3-Dichlorobenzene banzene ic11Ior'cldditiuol"tlrtlethta ne -Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene 1, 2-Dichloropropane 1,3-Dichloropropane 2,2-Dich oropropane 1,1-Dichloropropene Diisopropyl ether Ethanol Ethylbenzene Hexachlorobutadlene lsopropylbenzene Methylene Chloride Methyl tort -butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-isopropyltotuene -Butylbenzene re utytbenzene ,2-Tetrachloroethane „2-Tetrachloroethane Tetrachloroethene Toluene trans-1,2 Dichloroethene Spike Added 50.0 50.0 50,0 50.0 50,0 50,0 50,0 50.0 50.0 50.0 50,0 50.0 50.0 50,0 50,0 50.0 50,0 50.0 50.0 50.0 50.0 50,0 50,0 50.0 50,0 50,0 50,0 50.0 50,0 5000 50.0 50,0 50.0 50.0 50,0 50.0 50.0 50,0 50,0 50.0 50,0 50.0 50,0 50.0 50.0 50,0 50,0 LC'SD LCSD Result Qualifier Unit 51.56 53,73 ug/L 51,98 ug/L 54.84 ug/L 51.18 ug/L 52-55 ug/L 52.01 ug/L 53.12 ug/L 50.31 ug/L 49,96 ug/L 43.06 ug/L 57.85 ug/L 56.21 ug/L 48.86 ug/L 54,38 ug/L 52.98 ug/L 54.87 ug/L 51,89 uglL 57,14 ug/L 56.62 ug/L 53,33 ug/L 47.99 ug/L 53,17 ug/L 47.44 uglL 58.98 ug/L 47,83 ug/L 51.58 ug/L. 54.13 ug/L 51,07 ug/L 52.98 ug/L 3793 ug/L 55.14 ug/L 55.28 ug/L 57,22 ug1L 56.00 ug/L 55,38 ug/L 53.50 ug/L 66.07 * ug/L 58.94 ug/L 60.47 ug/L 62,04 ug/L 55,94 ug/L 60,08 ug/L 5'1,89 ug/L 56,26 ug/L 52.23 ug/L 52,37 ug/L 54.46 ug/L TestAmerica Job ID: 490-20114-1 SDG' 3721 Freedom drive, Charlotte, NC Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA %Rec %Rec. RPD Limits RPD Limit 78.130 2.0 107 70.130 3 20 104 70.130 1 20 110 73 - 130 1 20 102 70.130 0 20 105 60 _ 140 1 20 104 70. 130 1 20 106 70 m 130 1 20 101 60 _ 140 2 20' 100 70.130 0 20 86 60..140 4 20 116 70. 130 1 20 112 70 _ 130 1 20 98 70 _ 130 2 20 109 70.130 0 20 106 70 - 130 2 20 110 70_130 0 20 104 70 _ 130 3 20 114 70 _ 130 4 20 113 70.130 3 20 107 70 _ 130 1 20 96 60 - 140 3 20 106 70. 130 1 20 95 70 _ 130 0 20 118 70. 130 4 20 96 70 _ 130 2 20 103 70 _ 130 1 20 108 70 .- 130 4 20 102 70 -.130 1 20 106 70 _ 130 0 20 76 60 _ 140 12 20 110 70.130 1 20 111 70 _ 130 2 20 114 70 _ 130 0 20 112 70.130 2 20 111 70 _130 0 20 107 70.130 2 20 132 70 _ 130 3 20 118 70 - 130 2 20 121 70. 130 2 20 124 70.130 2 20 112 70-130 0 20 120 70 - 130 2 20 104 70.1.30 1 20 113 70- 130 3 20 104 70 _ 130 0 20 105 70.130 1 20 109 70.130 3 20 TestAmerica Nashville Page 27 of 46 2/28/2013 QC Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Method: SM62OO B - Volatile Organic Compound Lab Sample MD: LCSD 490-6O479I4 Nlatnx: Water Analysis Batch: 60479 Analyte trans-1 3- D is h l oro p rope n e 1, 2, 3-Tric h l orobe nz ene 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1,1,1-Tnchl0roethane Trichlorcethene Trichlorofl uoromethane 1,2,3 Trichloropropane 1,3„5-Trimethylbenzene 1, 2,4-Tnmethylbenzene Vinyl chloride Xylenes, Total Continued TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample tD: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD Added Raeutt Qualifier Unit 0 %Rec 50.0 52.02 ugh 104 70,.130 0 20 50,0 52,25 ug/L 105 70. 130 1 20 50.0 52.60 ug/L 105 70. 130 0 20 50,0 51.26 u9/L 103 70 .130 2 20 50,0 52.60 ug/L 105 70.130 1 20 50.0 53.02 ugh 106 70 _130 1 20 50,0 48.65 ugh 97 60-140 2 20 50,0 53,43 u9/L 107 70.130 3 20 50.0 60,52 ug/L 121 70 _ '130 2 20 50,0 60.15 ug/L 120 70 -130 1 20 50.0 51.39 ug/L 103 60 _ 140 5 20 150 164.2 ugh 109 70 _ 130 0 20 LCSD LCSD Surrogate %Recovery Qualifier Limits rpethene-d4 (Sun) 94 70 _ 130 Toluene -de (SLIM) 98 70.. 130 4-8romotfuorobenzene (Surr) 105 70. 130 d?ihrt�mofuoromethane (Sun) 97 70.130 Lab Sample ID: 490-20114-4 MS Matrix: Ground Water Analysis Batch: 60479 Analyte Benzene benzene hloromethane B romod ichloro meth a n e oform th Sample Sample Spike MS MS Result Qualifier Added Resutt Qualifier Untt 0 %Rec 17.3 ..,._._. 50.0 68.06 ug/L..� 102 70 ND 50.0 2.16 ug/L 104 70 - 130 ND 50.0 52.27 ugh 105 70 _ 130 ND 50.0 54.41 ug/L 109 70. 130 NO 50-0 50.39 ugh 101 70-130 ND 50.0 51,69 ug/L 103 60,.140 ND 50,0 53,43 ug/L 107 70.130 Chlorobenzene NO 50.0 54.54 ug/L 109 70..130 Chloroethane NO 50.0 51,39 ug/L ugh 103 60-.140 Chlormform ND 50.0 50.100 70.130.130 Chloromethane ND 50.0 40 p522 uglL 80 60 n 140 4-Chlorotoluene ND 50.0 57,71 ug/L 115 70 _ 130 2-Chlorotaluene ND 50.0 56.87 ugh 114 70 _130 ras1,2-Dichlormethene 4,39 50.0 52,11 ugh 95 70.130 cis-1,3-Dichloropropene ND 50,0 53.83 ug/L 108 70.130 Dibrornochloromethane NO 50,0 54.25 ugh. 109 70.130 1,2-Dibroma-3-Ch1oropropane NO 50.0 51,07 ugh. 102 70.130 Dibromomethane ND 50.0 50.52 ugh 101 70.130 1,2-Dichl lrobezene ND 50.0 55.08 ugh 110 70.130 1,3-Di l4orobenzene ND 50.0 55.99 uglL 112 70.130 1p4-Dichlorobenzene ND 50..0 53.03 ugh 106 70.130 Dichlorodifluoromeihane ND 50.0 39.97 ug/L 80 60.140 1„1-Dichloroethane ND 50.0 53.50 ugh 107 70.130 1,2-Dichloroethane ND 50.0 47,36 ug/L 95 70_ 130 %Rea. Client Sample ID: MW-B Prep Type: Total/NA %Rec. RPD RP0 Limit TestAmerica Nashville Page 28 of 46 2/28/2013 QC Sample Results Client: ARCADIS U.S, Inc Project/Site: EM 42094 thod: SM6200-B - Volatile Organic Compounds Lab Sample ID: 490-20114-4 MS Matrix: Ground Water Analysis Batch: 60479 Analyte 1,1-Dichloroethene� 1 „2-Dichloropropane 1.3-Dishl0r0propane 2,2-Dichloropropane ,1-Dichloropropene ropyl ether Manor Ethylbenzene Hexachlorobutadiene Isapropylbenzene ene Chloride Methyl tert-butyl ether Naphthalene n-8utylbenzene N-Propylbenzene p-lsopropyltoluene sec--Butylbenzene Styrene tert-Butylbenzene 1 r 1,1,2•Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene trans-1,2-D ichioroethene trans-1, 3-D'ichioropropene 1, 2, 3-Tric h l oro be nzene 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1,1,1-Trichloroethane i r tlloroethene Trishlo roll uo rometh a n e 1„2,, 3-Tnchloropropane 13,5-Trirnethylbenzene 1,2,,4-Trimethylbenzene Vinyl chloride Xylenes, Total Continued Sample Sample Spike Result Qualifier Added ND 50.0 ND 50.0 N D 50.0 ND 50.0 NO 0.874 ND 2,60 NO ND NO NO ND ND ND ND NC) ND ND ND ND 10.9 17.2 ND ND ND ND ND ND 3.74 NO ND 1 21 3.60 ND 15-5 TestAmerica Job ID: 490-20114-1 SDG. 3721 Freedom Drive, Charlotte, NC Client Sample ID: MW-4 Prep Type: Total/NA MS MS %oRac. Result Qualifier Unit 0 %Rec Limits 60, 07 ugit 120 70 130 47.64 ug/L 95 70,130 51,25 ug/1_ 103 70.130 51.98 ug&L 104 70 _ 130 53,16 ug/L 106 70 _ 130 50,0 53,15 ug/L 105 70,130 5000 4767 ugfL 95 60 _ 140 50,0 59,04 ug/L 113 70. 130 50.0 54,81 ug/L '110 70.130 50.0 58.41 ugfL 117 70. 130 50.0 56,08 u91L 112 70 - 130 50.0 53,69 ug/L 107 70 - 130 50,0 52,23 ug/L 104 70.130 50,0 65.65 F ug/L 131 70.130 50.0 59,55 u9/L 118 70 -130 50.0 60,65 ugfL 121 70. 130 50,0 63.28 ug/L 127 70. 130 50,0 55.97 ug/L 112 70 .130 50,0 60.90 u9/L 122 70 _. 130 50,0 51.62 ug/L 103 70 - 130 50,0 52.64 ug/L 105 70 - 130 50.0 65.02 ug/L 108 70 - 130 50.0 71,98 ugfL 109 70. 130 50.0 56,57 u9/L 113 70.130 50.0 51.38 ug/L 103 70.130 50.0 48-00 ug/L 96 70_ 130 50.0 51.96 ugfL 104 70-130 50.0 50.78 ug/L 102 70 -130 50.0 54.15 ug/L 108 70..130 50,0 57,38 ug/L 107 70 .131) 50.0 50,55 ug/L 101 60.140 50.0 50.49 uglL 101 70 - 130 50.0 61.49 ug/L 121 70 - 130 50.0 64.56 ug/L 122 70.130 50.0 52.17 ug/L 104 60 - 140 10 182.6 u9/L 111 70.130 MS MS Surrogate & ieotrvery Qualifier Limits 1,2-D1 hloroethane-.i4 (Sum) 95 70. 130 Toluene•d. (Surr) 100 70_ 130 4-8romofluarobenzene (Suer) 102 70. 130 D 8rornofuommethane (Suer) 97 70 - 130 TestAmerica Nashville Page 29 of 46 2/28/2013 2 2 ZZ Z Z Z Z Z 2 Z a 0 0 0 0 0 0 0© 0© '0 rn en sn 06 CrS N 0.M1i Gt4 )0 0 3 h.) 0 na 'TB z z z z z x 'x z z z z z z a Z w z z Z z z Z z z Z z z Z 7.4 P© 0 0 0 0 © 0 0 0 0 0 0 0 0 o D 0 0 0©©©©© 0 0 0 w N -+ 4t1 h7 Rk9 NI 4 -` 0 0 IV txx 07 05 0-) kt5 N O co -,+ to 0 .•+ m, ..z. 4 y fiJ `4 G'F+ o o o 444 h.) ,..s «x. ^" tia A+J 65.7 ..:e. f43 -� fl7 n L. QC Sample Results Client: ARCADIS t1,S. Inc Project/Site: EM 42094 Method: SM6200-B - V©I Rile Organi Compound Lab Sample ID: 490-20114-4 MSD Matrix: Ground Water Analysis Batch: 60479 Anatyte trans-1;3-Dichloropropene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,2-Trichloroethane 1 „1,1-Trichloroethane Trichtoroethene Tr lc h l o rof I u ©romet ha n e 1 ,2,3-Trichloropropane 5-Trimethylbenzene 1,2,4-Trimethylbenzene Vinyl chloride Xylenes, Total Sample Sample Result Qualifier ND ND ND ND ND 374 ND ND 1.21 3.60 ND 15.5 Continued) Spike Added 50.0 50,0 50.0 50,0 50.0 50,0 50.0 50.0 50.0 50..0 MSD MSD Surrograle °%Recovery Qualifier Limits 7r72-D1cr/or etfiarse-d4(Sarr) 92 7t}- /30 (Surr) 102 70. 130 4-Bromofuornbenzene (Surr) 101 70. 130 t dbrornofluoromethane (Sure) 97' 70.130 Lab Sample ID: MB 490-61502/7 Matrix: Water Analysis Batch: 61502 Analyte Benzene Bromobenzene Bromochlorornethane Bromodichloromethane 8romoform tsromomattaane Cartaorl tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 4-Chlorotoluene 2-hlorotoluene cis-1, 2- D i ch t o meth a ne D d brornochloromethane 1,2-Dibromo-3-Chloropropane 1',2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1„3-Dichlorobenzene 1,4-Dichlorobenzene D ichlorodifluorometha ne 4,1-Dichloroethane MSD MSD Result Qualifier Unit 52 73 ug/L 50,30 ug/L 52.07 ug1L 54,66 54.15 56.64 50,65 52,25 62.06 65.19 51.39 1'82,8 MB MB Result Quainter RL MDL Unit ND 0.500 ug/L NO 0,500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0,500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0,500 ugdi. NO 0-500 ug/L ND 0,500 ug/t- ND 0.500 ug/L ND 0.500 ug/L ND 0,500 ug/L ND 0 500 ug/L ND 0,500 ug/L ND0.500 ug/L ND 0,500 ugIL ND 0,500 ug/L ND 0.500 ug/L ND 0.500 ug/L ND 0 500 ugfL ND 0 500 ug/L ND 0,500 ug/L NO 0.500 ugfL ug/L ug/L ug/L ug/L ug/L ug/L ug/L TestAmerica Job ID: 490-20114-1 SDG 3721 Freedom Drive, Charlotte, NC Client Sample ID: MW-8 Prep Type: Total/NA %Rec. RPD %Ric Limits RPD Limit 105 70.130 5 20 101 70. 130 5 20 104 70.130 0 20 109 70 130 7 20 108 79.130 0 20 106 70 _ 130 1 20 101 60,- 140 0 20 105 70.130 3 20 122 70 _ 130 1 20 123 70 _ 130 1 20 103 60 - 140 2 20 112 70..130 0 20 Client Sample ID, Method Blank Prep Type: Total/NA Analyzed Dil Fac 02127/13 13:5 02/27/13 13:55 1 02/27/13 13,55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02127/13 13.55 1 02/27/ 13 1 3, 55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13;55 1 02/27/13 13,55 1 02/27/13 13;55 1 02/27/13 13.55 1 02/27/13 13:55 1 02/27/13 13.55 1 02/27/13 13.55 1 02/27/13 13 55 1 02/27/13 13:55 1 02/27/13 13,55 1 02/27/13 13.55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13.55 1 TestAmerica Nashville Page 31 of 46 2/28/2013 QC Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 hod: SM6200-B - Vo Lab Sample ID: MB 490-61502/7 Matrix: Water Analysis Batch: 61502 Analyte Organic Compound 1, 2-Dichloroethane 1,1-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene Diisopropyl ether Ethanol Ethylbenzene Hexachlorobutadiene Isopropylbenzene Methylene Chloride Methyl tert-butyl ether Naphthalene n-Butylbenzene N-Propylbenzene p-Isopropyltoluene sec-Butylbenzene Styrene tert-Butylbenzene 1,1, i , 2-Tetrachtoroethane 1,1,2,2-Tetrachtoroethane Tetrachloroethene Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene 1, 2, 3-Tnchlorobenzene 1, 2,4-Trichlorobenzene 1,1,2-Tnchloroethane 1,1,1-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2„3-7richloropropa ne 1, 3, 5-Trirnethylbenzene 1, 2,4-Tnmethylbenzene Vinyl chloride Xytenes, Total 1,2-Dichloroethane-d4 (Surr) Toluene- i8 (Surr) Bromofuorobenzene (Surr) Oibromoiluoromethane (Surr) MB MB Result Qualifier ND ND ND ND ND ND NO ND ND ND ND ND ND NO ND ND ND ND ND ND NO ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND MB MB %Recovery Qualifier 94 93 99 100 Continued RL MDL Unit 0.500 ug/L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0,500 ug/L 0,500 ug/L 0.500 ug/L 100 ug/L 0.500 ug/L 1.00 uglL 1.00 ug/L 5.00 ug/L 0.500 ug/L 5,00 ug/L 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 uglL 0„500 ug/L 0.500 ug/L 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 uglL 0,500 ug/L 0.500 ug/L 0.500 uglL 0.500 uglL 0.500 ug/L 0,500 ug/L 0.500 ug/L 0.500 uglL 0.500 ug/L 0.500 ug/L 70 70. 130 70. 130 70. 130 TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: Method Blank Prep Type: Total/NA D Prepared Analyzed Dil Fac 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02J27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 Prepared Analyzed Dr! Fac 02/27/13 13:55 _ T 02/27/13 13:55 1 02/27/13 13:55 1 02/27/13 13:55 1 TestAmerica Nashville Page 32 of 46 2/28/2013 QC Sample Results Client. ARCADIS U.S. Inc TestAmerica Job ID: 490-20114-1 Project/Site: EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Method: SM6200-B - Volatile Organic Compounds (Continued Lab Sample ID: LCS 490-6150213 Matrix: Water Analysis Batch; 61502 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike LCS LCS %Roc. Added Amain° Result Qualifier Unit D %Rec Limits Benzene 50 0 57.09 ug/L. 114 70.130 Bromobenzene 50,0 51.72 ug/L 103 70 - 130 Bromochlorornethane 50.0 5878 ug/L 118 70.130 , Brornodichlorornethane 50.0 59.60 ug/L 119 70 - 130 50.0 51.32 ug/L Sromoform 103 70 . 130 Bromomethane 50,0 61,26 ug1_, /123 60 .140 Carbon tetrachloride 50 0 57,72 ug/L 115 '70 . 130 Chlorobenzene 50.0 53,83 ug/L 108 70 . 130 Chloroethane 50.0 57.72 ug/L 115 60-140 Chloroform 50 0 ug/L 111 70 . 130 Chloromethane 50.0 5505.32 ugfL 102 60 - 140 4-Chlorotoluene 50,0 55.62 ug/L 111 70_130 2-Chiorotoluene 50.0 54.58 ug/L 109 70 .130 cis-1„2-Dichloroethene 50.0 53.34 ug/L 107 70 - 130 cis-1„3-Dichloropropene 50.0 ug/L 105 70 _ 130 4:361 Dibromochloromethane 50.0 ug/L 107 70 - 130 1,2-Dibromo-3-Chloropropane 50,0 5266, ug/L105 70 . 130 Dibromomethane 50.0 56.58 uWL 113 70.130 1,2-Dichlorobenzene 50.0 54.37 ug/L 109 70. 130 1,3-Dichlorobenzene 50.0 54.62 ug/L 109 70 . 130 1,4-D1chlorobenzene 50.0 52,63 ow_ 105 70 - 130 Dichlorodifluoromethane 50.0 58.60 ug/L 117 60-140 1,1-Dichloroethane 50.0 58.46 ug/L 117 70.130 1,2-Dichloroethane 50.0 50.61 ug/L 101 70.130 1,1-Dichloroethene 50,0 67.21 ug/L 134 70 - 130 ' 1,2-Dic,hloropropane 50,0 53ug/L 107 70.. 130 1,3-Dichlorepropene 50,0 ,3,9 51,16 ugfL 102 70. 130 2,2-Dichloropropane 50.0 ,59.1 8 ug/L 118 70-130 1,1.Dichloropropene 50.0 56.58 ug/L 113 70. 130 Diisopropyl ether 50.0 57,85 ugn. 116 70.130 Ethanol 5000 6178 ug/L 124 60 - 140 Ethylbenzene 50,0 56.38 ug/l. 113 70 ,- 130 Hexachlorobutadtena 50.0 52,61 ug/L 105 70 - 130 lsopropyibenzene 50.0 57.73 ug/L 115 70..130 Methylene Chloride 50.0 61,61 ug/L 123 70 _ 130 Methyl tert-butyl ether 50.0 59 72 ug/1_ 119 70 .130 Naphthalene 50,0 49,95 ug/L 100 70 - 130 n-Butylbenzene 50.0 62.16 ug/L 124 70.130 N-Propylbenzene 50.0 57,48 ugfL 115 70. 130 p-Isopropyttoluene 50.0 59.00 ugiL 118 70.130 sec-Butylbenzene 50.0 6083 ugfL 122 70 .130 Styrene 50.0 , ug/L 111 70 _130 tert-Butylbenzene 50.0 55.56 58.23 ug/L 116 70.130 1,101.2.Tetrachlonoethane 50.0 52 16 ug/L 104 70 - 130 1,1,2,2-Tetrachloroethane 50.0 51.99 ug/L 104 70.130 Teirathloroethene 50.0 ugit. 105 70 .130 Toluene 50.0 55229 ug/L 105 70 .130 trans-1,2-Dichloroethene 50.0 61.09 ug/L 122 70 - 130 TestArnerica Nashville Page 33 of 46 2/28/2013 QC Sample Results Client: ARCADIS US. Inc Project/Site: EM 42094 Method: SM6200-B - Volatile Organic Compounds (Continued Lab Sample ID: LCS 490-61 Matrix: Water Analysis !:'etch; 61502 Analyte trans-1 „3-Dichloropropene 1, 2„3-Trichlorubenzene 1, 2, 4-Trichlorobe nz ene Trichloroethene 1, &,1-Trichloroethene Trichloroethene Tric h l orof ruo rom eth a n e -Trichloroprope ne 1, 3, 5-Trimethylbenzene 1, 2,4-Trimelhylbenzene Vinyl chloride Xylenes„ Total e-d4 (Sun) Toluene -dB (Sur!) 4-8romotluorobenzene (Sure) Dibromofluoromethene (Surr) Spike LCS LCS Added Result Qua1if1er' Unit 50,0 49,36 ug/L 50,0 49.13 ug/L 50.0 49.98 ug/L 50.0 50.57 ug/L 50.0 59,08 ug/L 50,0 59.68 ug/L 50.0 55,13 ug/L 50.0 51,15 ug/L 50.0 58,58 ug/L 50.0 59,16 ug/L 50.0 60.75 uWL 150 164.4 ug/L LCS LCS %Recovery Quaflfler Limits 93 7@_ 130 .92 70.. 130 102 70.130 99 7©_ 130 Lab Sample ID: LCSD 490-61502/4 Matrix: Water Analysis Batch: 61502 ' Analyte obenzene romochioronlethane odichloromethane orm ethane n tetrachloride Chlorobenzene Chloroethene Chloroform Chloromethane 4-Chlorotoluene 2 hlorstoluene cis-1,2 Dicltloroethene cis-1, 3-Dlchloropropene Dibromochloromethane 1,2-Di bromo-3-C hloropropane Dibromomethane 1, 2-Dichlorobenzene 1„-Dichlorobenzene 1,4-Dichlorobenzene Dict4orod 4iuoromethane 11-Dichloroethane 1>2-Diclhloroethene TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: Lab Control Sample Prep Type: Total/NA. D %Rec %Rec. Limits 98 70 130 100 70. 130 101 70,. 130 118 70.130 119 70.. 130 110 60 -140 102 70-130 117 70 _ 130 118 70., 130 121 60-140 110 70. 130 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec. RPD Added Result Qualifier Unit D %Rec Limits RPD Unlit 50,0 56,35 ug/L 113 70 - 130 1 20 50,0 50,80 ugJL 102 70-130 2 20 50,0 57,58 ug/L 115 70. 130 2 20 50.0 60.4.0 ug/L 121 70.130 1 20 50.0 51,64 ug/L 103 70. 130 1 20 50.0 59.17 ug/L 118 60 - 140 3 20 50.0 57.23 u9/L 114 70 - 130 1 20 50.0 53,33 ups 107 70 _ 130 1 20 50,0 56.47 ug/L 113 60. 140 2 20 50.0 54,07 u9/L 108 70 _ 130 2 20 50,0 49.71 ug/L 99 60 - 140 2 20 50.0 54 34 ug(L 109 70 _ 130 2 20 50.0 53.07' ug/L 106 70 _ 130 3 20 50.0 53.27 ug/L 107 70 _ 130 0 20 50,0 52.84 ugit 106 70 _ 130 1 20 50.0 54.94 uglL 110 70- 130 3 20 50.0 51.77 u9/L 104 70.130 2 20 50.0 55.56 uglL. 111 70. 130 2 20 50.0 53.48 ug.L 107 70 _ 130 2 20 50,0 53.544 ug/L 107' 70.130 2 20 50,0 51.87 ug/L 104 70 - 130 1 20 50,0 57.63 u9/L 115 60. 140 2 20 50,0 56.36 ug/L 113 70 - 130 4 20 50.0 49,97 ug/L 100 70. 130 1 20 TestAmerica Nashville Page 34 of 46 2/28/2013 QC Sample Results Client, ARCADIS U.S. Inc Project/Site: EM 42094 Method: SM6200-B - Volatile Organic Compounds Lab Sample ID' LCSD 490-6150214 Matrix: Water Analys#s Batch, 61502 Analyte 1,1-0ichloroethene 1,2-0lchloropropane 1,3-Dichloropnypane 2.2-0ichloropropane 1,1-0ichloropropene Diisopropyl ether Ethanol Ethylbenzene Hexechlorobutadiene Isopropylbenzene Methylene Chloride Methyl terl-butyl ether Naphthalene n Butylbenzene N-Propyttbenzene p Isopropyltoluene seButylbenzene Styrene tart-Butylbenzene 1,1,1„2-Tetrachloroethane i ,1,2„2-Tetrachloroethane Tetrachloroethene Toluene trans-1,2-0 iehloroethene Vans-1,3.Dichloropi urea to 1,2, 3-Trichlorobenzene 1,2„4-Trichlorobenzene 2-Trichloroethane 1„1,1-Trichlon ethane Trichloroethene Trichlorofluoromethane 3- T ric h to roprop e ne 5-Tri meththenzen e 1,2 „4-Trimethylbenzene Vinyl chloride Xylenes, Total Continued TestAmerica Job ID: 490-20114-1 SD: 3721 Freedom Drive, Charlotte, NC Client Sam pltt ID: Lab Control Sample Dup Prep Type: Total/NA Spike LCSD LCSD %Rec. Added Result Qualifier Unit n %Rec i,,g11Ets 50.0 64.95 ugh 130 70.130 50..0 51,88 ug/L 104 70 - 130 50,0 52.09 u9(L 104 70.130 50.0 57..87 ug/L 116 70- 130 50.0 56,87 ug/L 114 70 _ 130 50,0 5648 ugh 113 70_ 130 5000 5137 u9ll. 103 60 - 140 50,0 55,01 ugh. 110 70 _130 50.0 51.22 ugh 102 70 _ '130 50,0 57.17 ug/L 114 70 _130 50,0 60,23 ug/L 120 70 _ 130 50.0 60,20 u9✓L 120 70 _ 130 0,0 49.47 u9/L 99 70. 130 50.0 60.61 ug/L 121 70 -130 50.0 55.01 u9/L 110 70 - 130 50,0 57,22 ug/L 114 70.130 50 0 58.82 u90, 118 70.130 50.0 54,84 ug/L 110 70.130 50.0 56,75 ugh 113 70.130 50,0 52.34 ugh 105 70-130 50.0 51.97 ug/L 104 70 _ 130 50,0 53,54 ug/L 107 70.130 50.0 52,30 ugh 105 70,130 50.0 59.69 ugh 119 70 - 130 50,0 50.88 ug/L 102 70.130 50,0 48.52 u9/L 97 70.130 50,0 49-83 ug/L 100 70 - 130 50.0 52.06 ug1L 104 70 -130 50.0 57,33 u9/L 115 70- 130 50,0 57.54 ug/L 115 70..130 50.0 54.68 ug/L 109 60 - 140 50.0 51,22 u9/L 102 70 - 130 50,0 56.70 ugh. 113 70 _ 130 50 0 5'7.16 ugh 114 70- 130 50.0 58,63 u9/L 117 80.140 150 161.7 ug/L 108 70 _ 130 LCSD LCSD %Recovery Qualifier Limits 94 70. 130 94 70. 130 101 70-130 99 70-130 RFD Ur* 20 3 20 2 20 2 20 1 20 2 20 18 20 2 20 3 20 1 20 2 20 1 20 1 20 3 20 4 20 3 20 3 20 1 20 3 20 0 20 0 20 2 20 1 20 2 20 3 20 1 20 0 20 3 20 3 20 4 20 1 20 0 20 3 20 3 20 4 20 2 20 TestAmerica Nashville Page 35 of 46 2/226/2013 QC Sample Results Client: ARCADIS U.S. Inc Project/Ste: EM 42094 Method: SM6200-B - Volatile Organic Compounds (Continued Lab Sample ID: 490-20368-B-1 MS Matrix: Water Analysis Batch: 61502 Analyte Benzene Bromobenzene Bromochlorometha.ne Bromod ichl oro meths ne Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 4-Chlorutoluene 2-Chlorotoluene cis-1, 2-Dichloroethene cis-1, 3-Dichlompropene D I bro mocill o rometh 8 ne 1,2-Dibromo-3-Chloropropane Dibromomethane 1, 2-Dichlorobenzene 1, 3-Dichlorobemzene 1,4-Dichlorobenzene Dichlorodifiuorometha ne 1 1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene 1,2-Dichioropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene D'iopropyl ether Ethanol Ethylbenzene Hexachlorobutadiene Isopropylbenzene Methylene Chloride Methyl ter1-butyl ether phthalene (benzene N-Propylbenzene p-Isopropyltoluene sec-Butylbenzene Styrene test-13utyiibenzene 1, 2-Te trachlo roeth a ne 1,1, 2,2-Tetrachloroethane Tetrachloroethene Toluene trans-1 „2-Dichloroethene Sample Sample Spike Result Qualifier Added ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND Np ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO NO 50.0 500 50,0 500 50,0 50.0 50-0 50,0 50,0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50,0 50.0 50,0 50,0 50,0 50.0 50,0 50,0 50,0 50,0 50,0 50,0 5000 50.0 50,0 50.0 50.0 50.0 50.0 50.0 50,0 50,0 50,0 50.0 50,0 50,0 50,0 50,0 500 MS MS Result Qualifier Unit 50.01 58.67' 60, 21 48.76 50,60 58.90 52.41 57.84 55.66 46.34 52,64 51.83 54.51 48 92 50.21 48.25 57.16 51.58 52,42 50.46 55.35 60,29 51.14 66.37 F 48.28 58.80 58.13 57.97 5853 50,58 55,79 59.91 46,26 60.34 54.75 56,28 58.24 54,06 57,01 5075 51,06 50 82 48.90 61.68 TestAmerica. Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Sample ID: Matrix Spike Prep Type: Total/NA %Rec. © %Roc Limits ug/L t13 70. 130 ug/L 100 70 _ 130 ug/L 117 70.130 ug/L 120 70. 130 ug/L 98 70. 130 ug/L 101 60 _ 140 ug/L 118 70_ 130 ug/L 105 70- 130 ug/L 116 60 - 140 ugL 112 70-130 ug/L 93 60.140 ug/L 106 70.130 ug/L 104 70 - 130 ug/L 109 70 _ 130 ugiL 98 70 _ 130 u,g/L. 100 70 - 130 ug/L 97 70-130 ug/L 114 70 - 130 ug/L 103 70. 130 ug/L 105 70 - 130 ugfL 101 70 _ 130 ug/L 111 60 _ 140 ug/L 121 70-130 ugJL 102 70.130 ug/L 137 70. 130 ugJL 107 70. 130 ug/L 97 70.130 ug/L 118 70- 130 ug/L 116 70.130 ugfL 116 70.130 ug/L 117 60 _ 140 ug/L 109 70.130 ugfL 101 70 _ 130 ug/L 112 70, 130 ug/L 125 70 -130 ug/L 120 70.130 ug/L 93 70 - 130 ug/L 121 70 _ 130 ug/L 110 70.130 ug/L 113 70.130 ug/L 116 70.130 ug/t. 108 70.130 ug/L 114 70-130 ug/L 102 70.130 ugJL 102 70.130 ug/L 102 70. 130 ug/L 97 70 - 130 ug/L 124 70 _ 130 TestAmerica Nashville Page 36 of 46 2/2B/2013 QC Sample Results Client: ARCADIS U.S. Inc TestAmerica Job ID: 490-20114-1 Project/Site EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Method: SM6200_13 - Volatile Organic Compounds (Continued) Lab Sample ID: 490.20368=B-1 MS Matrix: Water Analysis Batch: 61502 Client Sample ID: Matrix Spike Prep Type: Total/NA Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit 0 %Rec Limits trans-1,3 Dichloropropene ND 50,0 47,03 ug/L_ 94 70. 130 1,2,3-Trichlorobenzene ND 50,0 45,34 ug/L 91 70. 130 1,2,4-Trichlorobenzene ND 50,0 47,22 ug/L 94 70.130 1,1,2-TrlchIoroethane ND 50,0 48.08 ug/L 96 70.130 1,1,1-Trichknoethane ND 50.0 59,52 ug/L 119 70 -130 Trichloroethene ND 50,0 58,53 ug/L 11'7 70 _ 130 Trichlorafluoromethane ND 50,0 56.62 ug/L 113 60 - 140 1,2,3-Trichloropropane ND 50.0 49.01 ug/L 98 70.130 1,3 S-Trimethyibenzene ND 50.0 55,42 u0/L 111 70-130 1.2,4-Trimethylbenzene ND 50.0 55,79 ugh 112 70.130 Vinyl chloride ND 50.0 60,75 ugh 121 60 - 140 Xylenes, Total ND 150 160,9 ug/L 107 70. 130 Surrogate 1„2- 011/omethane-d'4 (Surr) Toluene -dB (Surr) 4-Bromottuorobenzene (Surr) Dibromofluoromethene (Surr) Lab Sample ID: 490-2036 Matrix: Water Analysis Batch: 61502 C- MS MS %Recovery Qualifier Limits 98 .. _ . 70.. 130 87 70.130 100 70.- 130 100 70. 130 SD Client Sample la: Matrix Spike Dupllcite Prep Type: Total/NA Sample Sample Spike MSD MSD %Rec. RPO Anelyte Result Qualifier Added Result Qualifier Unit D %Rec limits RPD Limit Benzene ND 50.0 57,4Ta ug(L 11 70 -130 1 20 Bromobenzene ND 50,0 49,93 ugh 100 70. 130 0 20 Brornochloromethane ND 50.0 57,56 ugiL 115 70. 130 2 20 Bromodichloromethane ND 50.0 60,83 ug/L 122 70..130 1 20 Bromoform ND 50.0 48,99 ug/L 98 70 - 130 0 20 Bromomethane NO 50,0 54,07 ug/L 108 60.140 7 20 Carbon tetrachloride NO 50,0 59 69 ug/L 119 70-130 1 20 Chioroberizene ND 50.0 52 98 ugfL 106 70. 130 1 20 Crrioroethane ND 50-0 57,59 ug/L 115 60 - 140 0 20 Chloroform ND 50.0 54,95 ug/L 110 70. 130 2 20 Chforomethane ND 50.0 48.81 ug/L 98 60 - 140 5 20 4-Chlorotoiuene ND 50,0 53,68 ug/L 107 70. 130 2 20 2-Chlorotoluene ND 50.0 52,84 ug/L 106 70.130 2 20 cis 1,2-Dichloreethene ND 50.0 54,17 ug/L 108 70. 130 1 20 cts 1,3-Dichloropropene ND 50,0 49,46 ug/L 99 70. 130 1 20 Dlbromochloromethane ND 50,0 54,51 ug/L 109 70.130 8 20 1,2-Dibromo-3-Chlor6propane ND 50,0 48,55 ugh, 97 70 - 130 1 20 Dibromomethane ND 50.0 57,81 ugfL 116 70 _ 130 1 20 1,2-DichIcrotenzene ND 50.0 51,85 ugh. 104 70-130 1 20 1,3-Dichlorobenzene ND 50.0 52'.88 ug/L 106 70. 130 1 20 1,4-Dichlorobenzene ND 50.0 50,83 ug/L 102 70.130 1 20 ' Dichlorodifluoromethane ND 50,0 55.78 ug/L 112 60.140 1 20 1„1-Dichloroethane ND 50,0 59,13 u0IL 118 70 _ 130 2 20 1,2-Dichlornethane ND 50,0 50.93 ugil. 102 70 _ 130 0 20 TestAmerica Nashville Page 37 of 46 2/28/2'013 1 „2-Dich oropropane 1„3.Dichloropropane 2, 2-DichI0r0propane 1„1-Dichloropropene Diisopro pyl ether Ethanol Ethylbenzene Hexachlorobutediene Isopropylbenzene Methylene Chloride Methyl tert-butyl ether Naphthalene n-Butylbenzene N-Propyibenzene p-Isopropyitoluene eecWButylbenzene Styrene tert-Butylbenzene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethene Tetrachioroethene Toluene trans-1, 2-Dichtoroethene trans-1,3-Dichloropropene 1;2,3-Trichlorobenzene 1, 2 , 4- Trichto robe nze n e 1,1, 2- Trichto roe th e n e 1,1,1-Trichlorbethene Trichtoroethene Trichlorofuoromethane 1 , 2, 3-Trictuo roprope n e 1,3.5-Trimethylbenzene 1, 2,4-Trirnethylbenzene Vinyl chloride 7tylenes, Total QC Sample Results Client: ARCADIS U.S. Inc Project/Site: EM 42094 Method: SM6200-'8 - Volatile Crg nfu Compounds (Continued) Lab Sample ID:490-20368-C-1 MSD Matrix: Water Analysis Batch: 61502 TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Client Sample ID: Matrix Spike Du rticate Prep Type: Total/NA Sample Sample Spike MSD MSD '/ Rec. RPD Anat^ate Result Qualifier Added Result Qualifier Unit D Rec Umtta RPD Limit ND 50.0 66,75 F ug/L 137 70.130 1 20 ND 50.0 53.69 ug/L 107' 70 - 130 0 20 ND 50.0 48.62 ug/L 97 70 _ 130 1 20 ND 50,0 59.44 ug/L 119 70-130 1 20 ND 50.0 58,47 ug/L 117 70 _130 1 20 ND 50.0 57.23 u9/L 114 70_130 1 20 ND 5000 4828 ug/L 97 60 _ 140 19 20 ND 50.0 55.37 ug/L 111 70 _ 130 1 20 ND 50.0 52,26 ugfL 105 70 - 130 3 20 ND 50.0 56..64 ug/'L 113 70-130 2 20 ND 50.0 62,21 ug/L 124 70 -, 130 1 20 ND 50.0 59.28 ug/L 119 70 - 130 1 20 ND 50.0 46.80 ug/L 94 70. 130 1 20 ND 50.0 61,.70 ug/L 123 70.130 2 20 ND 50.0 55.95 u9IL 112 70 - 130 2 20 ND 50.0 57.45 ug/L 115 70. 130 2 20 ND 50.0 59,68 ug/L 119 70 - 130 2 20 ND 50,0 53.67 ug/L 107 70_130 1 20 ND 50,0 58.11 ug/L 116 70 _ 130 2 20 ND 50,0 5'1,86 ug/L 104 76.130 2 20 ND 50.0 50,02 ugfL 100 70_130 2 20 ND 50,0 52.61 u91L 105 70. 130 3 20 NO 50,0 50,66 ug/L 101 70. 130 4 20 ND 50.0 62.05 ug/L 124 70.130 0 20 ND 50.0 48.41 u91L 97 70 - 130 3 20 ND 50,0 46,52 ug/L, 93 70 _ 130 3 20 ND 50,0 48.72 ugfL 97 70m 130 3 20 ND 50.0 49,69 ug/L 99 70.130 3 20 ND 50.0 59.57 ug11_ 119 70.-130 0 20 ND 50,0 59.64 ug/L 119 70_ 130 2 20 NO 50.0 58.41 u9/L 117 60.140 3 20 ND 50.0 48.49 ug/L 97 70 - 130 1 20 ND 50.0 56.50 ug/L 113 70.130 2 20 ND 50,0 56.'38 u9/L 113 70.130 1 20 ND 50.0 61.26 ug/L 123 60 - 140 1 20 ND 150 160.7 ug/L 107 70. 130 0 20 NSA MSD %Recovery Qualifier LNnlcs 2-C1rchCrzrrt811aarte d4 (Surrj 95 70.130 al8 (Swr 90 70. 130 4-8romo tuorobenzene (Surr) 102 70. 730 Chbromonuor©methane (Surr) 99 70. 130 TestAmerica Nashville Page 38 of 46 2/28/2013 Client: ARCADIS U.'S, Inc. Project/Site: EM 42094 GC/MS VOA Analysis Batch:60479 Lab Sample ID 490-20114-1 490-20114-1 490-20114-2 490-20114-3 490-20114-4 490-20114-4 MS 490-20114-4 MSD 490-20114-5 490-20114-5 490-20114-6 490-20114-7 490-20114-7 490-20114-8 490-20114-8 490-20114-9 LCS 490-60479/3 LCSD 490-60479/4 MB 490-60479/7 Analysis Batch: 61502 Lab Sample ID 490-20114-1 490-20114-2 490-20114-3 490-20114-5 490-20114-7 490-20114-8 490-20368-B-1 MS 490-20368-C-1 MSD LCS 490-61502/3 490-61502/4 -61502/7 ID MW-5 MW-6 MW-7 M W-8 MVV-8 MW-8 MW-10 MW-10 OW-1 OW-2 DW-2 DVV-3 OW-3 Trip Blank Lab Control Sample Lab Control Sample Dup Method Blank Cited pie ID MW-6 MW-7 MW-10 D W-2 DW-3 Matrix Spike Matrix Spike Duplicate Lab Control Sample Lab Control Sample Dup Method Blank QC Association Summary TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Prep Type Matrix Me!hod Total/NA Ground ? ter 0M6200-B Total/NA Ground Water SM6200-B Total/NA Ground, Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-8 Total/NA Ground Water SM6200-8 Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Water SM6200-B Total/NA Water SM6200-B Total/NA Water SM6200-B Total/NA Water SM6200-B Prep Type Matrix Method Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-8 Total/NA Ground Water SM6200-B Total/NA Ground Water SM6200-8 Total/NA Ground Water SM6200-8 Total/NA Water SM6200-8 Total/NA Water SM6200-B Total/NA Water SMS200-B Total/NA Water SM6200-8 Total/NA Water SM6200-t3 Prep Batch Prep Batch TestAmerica Nashville Page 39 of 46 2/28/2013 Lab Chronicle Client ARCADIS U.S. Inc ProjectlSiite: EM 42094 Client Sample ID:: MW-5 Date Collected: 02/20/13 14:00 Date Received: 02/21/13 08:45 Prep Type TotaVNA Total/NA Total/NA Batch Batch Type Method Analysis SM6200-8 Analysis SM6200-B Analysis SM6200-8 Client Sample ID: MW-6 Date Collected: 02/20/13 16:00 Date Received: 02/21/13 08:45 Prett TYP. TotWNA Total/NA Batch Typo Analysis Analysis Client Sample ID: MW-7 Date Collected: 02119/13 16:50 Date Received: 02/21/13 08:45 Prep Type Total/NA Total/NA Batch Method SM6200-B SM6200-B Batch Batch type Method Analysis Si1±t6200-8 Analysis SM6200-6 Client Sample ID: MW-8 M1 Date Collected: 02/20/13 15:00 Date Received: 02/21/13 08:45 To Batch Type Analysis Client Sample ID: MW-10 Date Collected: 02/20/13 10:15 Date Received: 02/21/13 08:45 Prep Ty1» Total/NA Total/NA Total/NA Batch SM6200-B Batch Batch Tv Method Analysis SM6200-B Analysis SM6200-B Analysis SM6200-B Run Run Run Run Run Dilution Factor 10 TestAmerica Job ID: 490-20114-1 SDG: 3721 Freedom Drive, Charlotte, NC Batch Pcepantd Number or Analyzed Analyst 60479 02/2211318:14 EL 100 60479 02/22/1318:40 EL 10 61502 02/27/1316:49 EL Dilution Batch Prepared Factor Number or Analyzed 1 60479 02/22/1316'31 1 61502 02127/13 15:31 Dilution Factor 5 Dilution Factor Lab Sample ID: 490-20114-1 Matrix: Ground Water Lab TAL NSH TAL NSH TAL NSH D: 490-20114-2 ix: Ground Water Analyst Lab EL TAL NSH EL TAL NSH Lab Sample ID: 490.20'i14 Matrix: Ground Water Batch Prepared Number or Analyzed Analyst Lab 60479 02/22/13 16:57 EL TAL NSH 61502 02/27/13 16:23 EL Batch Prepared Number or Ana 7 2 TAL NSH pie ID: 490-20114 Matrix: Ground Water Lab TAL NSH. Lab Sample D: 490-20114�5 Matrix: Ground Water Dilution Batch Prepared Factor Number or Anatyzed Analyst Lab 20 60479 02/22/13 19:06 EL..._. TAL NSH 200 60479 02/22/13 19:32 EL TAL NSH 20 61502 02/27/113 1'7.15 EL TAL NSH TestAmerica Nashville Page 40 of 46 2/28/2013 Lab Chronicle Client: ARCADIS U.S, Inc Project/Site: EM 42094 Client Sample ID: DW-1 Date Collected: 02J20/13 13:15 Date Received: 02/21/13 08:45 Prep TYPe TotaUNA Batch Type Analysis Client Sample ID: DW-2 Date Collected: 02/20/13 08:50 Date Received: 02/21/13 08:45 Prep Type Total/NA Total/NA Tota/NA. Batch Method SM6200-B Batch Batch Type Method Analysis M6200-B Analyses SM6200-B Analysis SM6200-6 Client Sample ID: DW-3 Date Collected: 02/20/13 11:05 Date Received: 02/21/13 08:45 Prep Type Total/NA" Total/NA Total/NA Batch TYPe Analysis Analysis Analysis Batch Method SM6200-B SM6200-B SM6200-B Client Sample ID: Trip Blank Date Collected: 02/19/13 00:01 Date Received: 02/21/13 08:45 Prep Type Total/NA Batch Typo Analysis Run Run Run Dilution Factor 10 Batch Number TestAmerica Job I SDG: 3721 Freedom Drive Lab Sample ID: Matrix: Prepared or Analyzed Analyst Lab 2/22/13 17:23 EL TAL NSH Dilution Batch Prepared Factor Number or Analyzed 10 66479 02 22131 g:5 100 60479 02/22/13 20:24 EL 10 61502 02/27/13 17 41 EL D: 490-20114-1 , Charlotte, NC 490-20114-6 Ground Water Lab Sample ID: 490-20114-7 Matrix: Ground Water Analyst Lab TAL NSH TAL NSH TAL NSH Lab Sample ID: 490-20114-8 Matrix: Ground Water lutlon Batch Prepared Factor Number or Analyzed Analyst Lab 1 60479 02/23,'13 15t40 EL TAL NSH 5 60479 02122/13 16:05 EL 1 61502 02/27/13 15.57 EL Batch Prepared Number or Analyzed Analyst 60479 02/22/1 13:04 EL Laboratory Raferences: TAL NSH = TestAmerica Nashville„ 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726'1177 TAL NSH TAL NSH Lab Sample D: 490-20114-9 Matrix: Water Lab TAL NSH TestAmerica Nashville Page 41 of 46 2/28/2013 Method Summary Client: ARCADIS U.S. Inc TestAmerica Job ID: 490-20114-1 Project/Site: EM 42094 SDG: 3721 Freedom Drive, Charlotte, NC Method Method Description Protocol Laboratory SM6200-B Volatile Organic Compounds SM TAL NSH Protocol References: SM "Standard Methods For The Examination Of Water And Wastewater". Laboratory References: TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL (615)726-0177 TestAmerica Nashville 10 Page 42 of 46 2/28/2013 Client: ARCADIS ILS. Inc Project/Srte: EM 42094 Laboratory: TestAmerica Nashville The certifications listed below are applicable to this report Authority North Carolina DENR Program State Program Certification Summary EPA Region 4 Certification ID 1 TestAmerica Job ID: 490-2O114-1 SDG: 3721 Freedom Drive, Charlotte, NC 12-31-13 TestAmerica Nashville Page 43 of 46 2/28/2013 TestAmerica THE LEADER IN ENVIRONMENTAL TESTING Nashville, TN Cooler Received/Opened On : 02/21/13 @ 0845 Tracking # tfq t. V (last 4 digits, FedEx) Courier: Fed -ex IR Gun ID: 95610066 COOLER RECEIPT FORT 1. Temperature of rep. sample or temp blank when opened: ° r Degrees Celsius Charlotte 490 20114 Chain of Custody 3. If Item #2 temperature Is 0°C or less, was the representative sample or temp blank frozen? YES NO. NA 4. Were custody seals on outside of cooler? If yes, how many and where: (F-ami .NO...NA 5. Were the seals Intact, signed, and dated correctly? 6. Were custody papers Inside cooler? I certify that I opened the cooler and answered questions 1-6 (Intial] YES and Intact YES NO YES...NO.. Paper Other None Dry Ice Other None �..NO...NA .NO...NA �.NO...NA .NO...NA YES. a.NA ..NO...NA If multiple coolers, sequence # 7. Were custody seals on containers: Were these signed and dated correctly? 8. Packing matt used? 9. Cooling process: Plastic bag Peanuts Vermiculite Foam Insert Ice -pack Ice (direct contact) 10. Did all containers arrive In good condition (unbroken)? 11. Were all container labels complete (#, date, signed, pres., etc)? 12. Did all container labels and tags agree with custody papers? 13a. Were VOA vials received? b. Was there any observable headspace present In any VOA vlal? 14. Was there a Trip Blank in this cooler? I certif]vthat I unloaded the cooler and answered questions 7-14 finliafl 15a. On pres'd bottles, did pH test strips suggest preservation reached the correct pH level? YES...NO.. b. Did the bottle labels Indicate that the correct preservatives were used .NO...NA 16. Was residual chlorine present? YES...NO...lVbJ I certify that I checked for chlorine and pH as per SOP and answered questions 15-16 (intiall 17. Were custody papers properly filled out (ink, signed, etc)? NO...NA 18. Did you sign the custody papers In the appropriate place? CADIO...NA 19. Were correct containers used for the analysis requested? O...NA 20. Was sufficient amount of sample sent In each container? .NO...NA I certify that 1 entered this prolect Into LIMS and answered questions 17-20 Untie!) I certify that I attached a label with the unique LIMS number to each container fintlall 21. Were there Non -Conformance issues at login? YES. as a NCM generated? YES... BIS — Broken in shipment Cooler Receipt Form.doc LF-1 Eof Fm Page 44 Or 46 Revised 1128/12 2/28/2013 :� 9-I. 11 : r .r 1, 1 _ .i _ y •:lam 1 ti 0. c ci 286(1 Faster f e EhrIsion Tes Amen[relghtan T -46 LEAOER IN ENVIRONMENTAL TESTING, NashviIIe, TN 37204 Consultant Name: Arcade US. Inc Phone: 815-72E-0177 Toll Frei): 800-765-0980 Foe 616-725-3404 Address: 704 Blared Street &a 105. Sura 301 CttylStatelZp: Bluefield. WV 24701 Fxxo Mobs Project Mgr. obit TA PROJECTS': 49001431 ICo1a-rrEkthZtoG' r.,33-`.'%i14,s3itg$P iMr1 # w" Ffr i7?t"r tg Raped Tea Jan F ,0 Wes-:?*- PROJECT i% 42094 . . l tKtli9'itt'7 n;�n•eM7 i :ct.,' ritq."V a+.1,-k Vz?7 "v''. .'"F =: "e' .`9if,.r'd -::.-' -Lr711 Consultant Telephone Number: 27,�-3870x23807 Fax No: Site Address 3721 Freedom Dew Sampler Name:{Film) KYAx3 at;crtErAaj6 Cray, State, Zip Cnadotte.NC SamplerSlgoatruo: � Regulatory District (CA) Consultant Project Mgr. Jon Farley • Sample lDorFedfD � O t m.j'fti U O I. U Raid Fltered !!llhiii1! Full l2st VOCs by 8200 I I I :YfiFii p0 5 4-tit .€1v. .rYV 4'. rAT request (In Bus Dare) =ax Results (yea or no) 711a Data of Ropwt 114-5 .2-a.o 100 3 )e X x x ,. - , _ ' n lw- cc, 2-20 16aa . x x ass mu" - 2- iQ 149 x x • � - • •cif, k4l - - S 2 -AA I5B x x 0 rr fl w- i a a-2o Ia t6- x x u -NA) -1 2-X0 MIS- x x j 't•NA1- A - al) D$so 'x x % "D W — 9-) !(& x x 1 e 'AL.A.J le- A 1Ie x x x x CammentsdSpecial Instructions: TA Nashville Project f: 49001431 Laharabwwy Commends: Temperature Upon Receipt Semple Containers Intact? Y N VOCs Free of Handsome?Y N QCDernerabiesfoicpsecircle 09111 Ralln4 by: I/� u �,/ /1 Zt yr r' /' {,.� �� C� , r L� L 'AEO S AIS J�D[a1te .pb '1 1 ""_ t J a _ l UJ R by. - /y�n at i- Data I J 13 ' limo lilli &KJ Love12 Level 3 Level 4 Other e{,3y rrY, ateev t t "Ff ""4. � K+ + c,3 #q;�+a'S`.?7'� �4 $ �'i�ri4stcd 7-IeA F� �r,��'r' , -�r e r_Le,la ,, SY; notheunq9ab Date 13 Tla'ie 17 bi _ -- 2_a H-� 3 Tines 65: Page 45 of 46 Login Sample Receipt Checklist Client: ARCADIS U.S. Inc Job Number: 490-20114-1 SDG Number: 3721 Freedom Drive, Charlotte, NC Login Number: 20114 List Number: 1 Creator: Ford, Easton Question Answer Comment List Source: TestAmerica Nashville Radioactivity wasn't checked or is <J= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time. True Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. N/A There is sufficient vol. for all requested analyses, incl. any requested True MSIMSDS Containers requiring zero headspace have no headspace or bubble is NIA <6mm (1I4'"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. NIA El TestAmerica Nashville Page 46 of 46 2/28/2013 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wald& P.E.Dee Freeman Governor Director Secretary June 27, 2012 Jewel Cox —Project Manager Exxon Mobil Environmental Services 1016 Poplar Avenue, Suite 106 — Number 232 Collierville, TN 38017 Ref: Issuance of Injection Permit W10300192 Former ExxonMobil Retail Facility # 42094 Charlotte,Mecklenburg County, North Carolina, Dear Mr. Cox: In accordance with the application received on March 2, 2012, and the supporting data received May 14, 201:2 and June 19, 2012, we are forwarding permit number W10300192. This permit is to inject BioSolve for the mobilization, dispersal, and bioenhanced remediation of free -phase and dissolved petroleum hydrocarbons in the soil and ground water at the facility referenced above. This permit shall be effective from the date of issuance until May 31, 2014,.and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII MONITORING AND REPORTING REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. Please note that the sampling program. has been modified. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at 919-8.07-6352 or at david,goodrich@ncdenr.gov if you have any questions about your permit. David Goodrich, L.G. .Flydrogeologist Daniel Bowser, Division of Waste Managenie -UST Section Scott Bostian, ARCADIS, 801 Corporate Center lDdve, Suite 300, Raleigh, NC 27607 WI0300192 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 512 N, Salisbury St., Raleigh, Nell Carolina 27604 Phone: 919.807-6464 t FAX: 919-807-6496 Internet wwwocwaterottality,ore An Equat Op.portiinity Afflintaiive Action Erriployer One NorthCarolina laturallff NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT .OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO ExxonMobil Environmental Services FOR THE CONSTRUCTION AND/OR OPERATION OF 4 CLASS 5 INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(5)(b)(viii), to inject BioSolve, for the mobilization, dispersal, and bioenhanced remediation of petroleum hydrocarbons. These injection wells/points will be located at the former Exxon Mobil Retail Facility Number 42094, 3721 Freedom Drive, Charlotte, Mecklenburg County, North Carolina, and will be operated in accordance with the application submitted March 2, 2012, and in conformity with the specifications and supporting data submitted May 14, 2012 and June 19, 2012, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until May 31, 2014, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the 27th day of June, 2012. (Afb- Charles Wakild, P.E., Director Division of Water Qt ality By Authority of the Environmental Management Commission. Permit No. W10300192 PAGE 1 OF 7 ver. June 2011 UIC-5I15T PART I - WELL CONSTRUCTION GENERAL CONDITIONS The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200) and Well Construction Standards applicable to monitor wells (15A NCAC 2C 0100). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. This permit is valid only for construction of the number of injection wells described in the application and other supporting data. Construction of additional injection wells must be approved in advance by the Aquifer Protection Section. 4. Each injection well or monitor well shall not hydraulically connect separate aquifers. 5. Each injection well or monitor well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 6. Each injection well or monitor well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes or monitor purposes and the entrance to each well must be secured with a locking cap. 7. Each injection well or monitor well shall be afforded reasonable protection against damage during construction and use. Each injection well or monitor well shall have permanently affixed an identification plate. PART II - WELL CONSTRUCTION SPECIAL CONDITIONS Prior to beginning injection, a deep monitor well shall be constructed downgradient of injection area INJ-2/MW-5 near existing well MW-2R. A well pair consisting of one shallow monitor well and one deep monitor well shall be constructed downgradient of injection area [NJ-1/1\4W-9. All three of these wells shall be included in the monitoring program. 2. At least forty-eight (48) hours prior to constructing each injection well or monitor well, the Permittee shall notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office staff, telephone number 919-807-6352 and the Mooresville Regional Office Aquifer Protection Section Staff, telephone number (704) 663-1699. Bentonite grout shall not be used to seal any water -bearing zone with a chloride concentration equal to or greater than 1,500 milligrams per liter. In areas where elevated chloride levels are known to exist or are probable, such as coastal areas, chloride levels shall be verified in the field to determine existing conditions. Permit No. WI0300192 PAGE 2 OF 7 ver. June 2011 UIC-51/5T PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate of injection, and number of injection wells as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any aid all statutes, rules, regulations, or ordinances that may be imposed by other local, state, and federal agencies having jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatoryrequirements have been met. PART IV - PERFORMANCE STANDARDS 1. The wellheads of the existing monitor wells shall be secured against tampering, and conditions such as missing padlocks, missing bolts, etc. shall be corrected before injection operations commence. 2. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. 3. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 4. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V -. OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall he properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central Office staff, telephone number 919-807-6352. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. Permit No. W10300192 PAGE 3 OF 7 ver. June 2011 UIC-5115T PART VI - INSPECTIONS Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for inN.C.G.S. 87-90. • Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS Within 30 days of completion of well construction, a completed Well Construction Record (Forrn GW-1) must be submitted for each injection well to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 2. The proposed monitoring plan included in the application shall be followed with some modifications. As per the proposed monitoring program, monitor wells MW-5, MW-6, MW- 7, MW-8, MW-9, and DW-1 will be measured for free -product thickness after injection and vapor recovery activities. Monitor wells MW-5, MW-7, MW-9, the new pair of monitor wells installed downgradient of injection area [NJ-1/MW-9, the new deep monitor well installed downgradient of injection area INJ-2/MW-5, and monitor wells DW-I, MW-2R, MW-6 and MW-8 will be sampled for Volatile Organic Compounds, water level, free product thickness, and for the field parameters of Conductivity, pH, and ORP. Sampling will be performed each quarter after the final injection event for a full year. The field parameters of Conductivity, pH and ORP will serve as an indicator of injectantl treatment products, and any significant change in any of these parameters in a particular well shall initiate an expansion of the sampling parameters for that well to include Calcium, Arsenic, Iron, Zinc, and Sulfates. All sample results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office and 'the Raleigh Central Office. Any monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to ensure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. The Permittee shall submit an Injection Event Record within 30 days of completing each injection. 4. The Permittee shall produce a final project evaluation within 9 months after completing all injection -related activity associated with this permit or produce a project interim evaluation PermitNo. WI0300192 PAGE 4 OF 7 ver. _Tune 2011 U1C-51/5T before submitting a renewal application for this permit. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plume maps and potentiometric surface maps. 5. The monitoring results and the final project evaluation shall be submitted to: UIC Program Staff DWQ — Aquifer Protection Section and 1636 Mail Service Center Raleigh, NC 27699-1636 DWQ - Aquifer Protection Section Mooresville Regional Office 610 East Center Avenue / Suite 301 Mooresville, NC 28115 6. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Mooresville Regional Office, telephone number (704) 663-1699, any of the following: (A)Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such asmechanical or electrical failures. 7. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 8. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. PART VIII - PERMIT RENEWAL In order to continue uninterrupted legal use of the injection facility for the stated purpose, the Permittee must submit an application to renew the permit 120 days prior to its expiration date. PART IX - CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0240, Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C .0240, including but not limited to the following: Permit No. WI0300192 PAGE 5 OF 7 ver. June 2011 UIC-5I/5T (A)A1.1 casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout or bentonite grout, which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) .1n those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0225(k)(1)(A) within 30 days of completion of abandonment. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRECAUTIONS DURING APPLICATION Some effects reported to be associated with the product proposed to be used are as follows: eye, skin, nose, throat, and lung irritation. Significant inhalation exposure can cause central nervous system depression and lung, liver, and kidney injury. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 2. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Permit No. WI0300192 PAGE 6 OF 7 ver. June 2011 U1C-5 5T 3. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 4. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. 6. Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. Permit No. W10300192 PAGE 7 OF 7 ver. June 2011 UIC-5115T NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources -Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 • 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE City or Town NC 28625 Stale Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(rr applicable) SITE WELL ID #(rf applicable) INJ-1 3. WELL USE (Check One Box) Monitoring ❑ Municipal/Public ❑ Industrial/Commercial 0 Agricultural ❑ Recovery ❑ Injection i( Irrigation❑ Other 0 (list use) DATE DRILLED 08/28/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY; CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Slope ❑Valley "Flat ❑Ridge ❑Other LATITUDE 35 ° 14 • 56.5900 - DMS OR DD LONGITUDE 80 ° 53 ' 51.9800 " DMS OR DD Latitude/ongilude source: VGPS Ofopographic map (location of well must be shown on a USGS topo map andattached to this form if not using GPS) 5. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 N/A Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBILt. Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 23.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO Lv c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use "+" if Above Top of Casing) 40 ° d. TOP OF CASING IS 0.0 FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST NIA f. DISINFECTION: Type NIA Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom 7. CASING: Depth Diameter Top 0.0 Bottom 13.0 FL 2 INCH Top Bottom Ft. Top Bottom Ft. Thickness! Weight Material SCH 40 PVC 8. GROUT: Depth Material Method Top 0.0 Bottom 9.0 Ft. PORTIAN06ENi°NriE SLURRY Top Bottom Ft. Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 FL 2.0 in. .010 in. PVC Top Bottom Ft. in. in. Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK: Depth Size Material Top 11.0 Bottom 23.0 Ft. 20-40 FINE SILICA SAND Top _ Bottom Ft. Top Bottom Ft. 11. DRILLING LOG Top Bottom 0.0 / 8.0 8.0 / 18.0 18.0 / 23.0 / Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY r- „ p is � z` .EPt3 2f112 al>.,r matron r'rorel!";sitig 1•L'O1B O G 12. REMARKS: BENTONITE SEAL FROM 9.0 TO 11.0 FEET_ I DO HEREBY CERTIFY THAT THIS WELL WA 15A NCA L CONST- CTION STA RECORI ,- B', P ' •_DTOTH ONSTRUCTED IN ACCORDANCE WITH DS, AND THAT A COPY OF THIS 09/05/12 SI ,PURE O'ERTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to Division of Water Quality Information Processing, 5 161T.Mail Se'nnce Center, Ralelgh,'NC 77699 161, Phone (919) 807 63od ,mot Form GW-lb Rev. 2/09 Y y r� a ;i f. 1. WELL CONTRACTOR: JOHNNY BURR NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town • State Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(inapplicable) SITE WELL ID #(if applicable) INJ-2 3. WELL USE (Check One Box) Monitoring 0 Municipal/Public 0 IndustriaUCommercial 0 Agricultural 0 Recovery 0 Injection gr irrigation❑ Other 0 (list use) DATE DRILLED 08/28/12 - 08/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No„ Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC 1 LAND SETTING: (check appropriate box) ❑Slope ❑Valley ig'Flat DRidge DOther LATITUDE 35 ° 14 ' 55.8700 ^ DMS OR DD LONGITUDE 80 ° 53 ' 51.6200 ^ DMS OR OD Latitude/longitude source: VGPS topographic map (location of well must be shown on a L/SGS topo map andattached to this form if not using GPS) 5. FACILITY. (Name of the business where the well is located.) EXXONMOBIL - 42094 N/A Facility Name 3709 FREEDOM DRIVE Facility ID# (if applicable) Street Address CHARLOTTE City or Town EXXONMOBIL NC 28208 State Zip Code Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code ( ) Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 23.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES 0 NO d c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use "+" if Above Top of Casing) 408171 d. TOP OF CASING IS 0.0 FT. Above Land Surface" *Top of casing terminated at/or below land surface may'require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): NIA METHOD OF TEST N/A f. DISINFECTION: Type N/A - Amount N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 13.0 Ft. 2 INCH SCH 40 PVC Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Method Top 0.0 Bottom 9.0 Ft. PORTL'NOBCNTDN1E SLURRY Top Bottom Ft. Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 Ft. 2.0 in. .010 in. PVC Top Bottom Ft. in. in. Top Bottom Ft. in. in. ID. SAND/GRAVEL PACK: Depth Size Material Top 11.0 Bottom 23.0 Ft. 20-40 FINE SILICA SAND Top Bottom Ft. Top Bottom Ft. 11. DRILLING LOG Top Bottom Formation Description 0.0 / 8.0 BACK FILL 8.0 / 18.0 TAN SILTY CLAY 18.0 / 22.0 WHITE ROCK 22.0 / 23.0 TAN SILTY CLAY / SEP 2 1 2012 *s� S. _ �c a 51t19 Ltrtli_ 12. REMARKS: u1.1.1Qle3Or, BENTONITE SEAL FROM 9.0 TOJ 1.0 FEET - I o0 HEREBY CERTIFY THAT TH{S WELL WA ONSTRUCTED IN ACCORDANCE WITH 15A NCA asaa • LL CONST- CTION STA 1 ADS, AND THAT A COPY OF THIS RECOR81 IA PR Ir DT07li WC44 09/05/12 SI �� URE O' ' RTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submitwithin30 daysof rcompletion to Division of Water'Quali' 1617 Mail Service CenterRaletgh, NC 27699.161, Phone ;(919) 807 6300 Inforrnation Rrocesstjlg,'' Form GW-lb Rev. 2/09 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources -Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION. INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE . City or Town (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# NC 28625 State Zip Code OTHER ASSOCIATED PERMIT#(if applicable) SITE WELL ID #(if applicable) DW-10 3. WELL USE (Check One Box) Monitoring Rf Municipal/Public 0 Industrial/Commercial ❑ Agricultural 0 Recovery 0 Injection 0 trrigation❑ Other ❑ (list use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) Slope ['Valley p(Fiat ❑Ridge ❑Other LATITUDE 35 ^ 14 •56.5100 ' DMS OR DD LONGITUDE 80 ° 53 52.0400 • DMS OR DD Latitude/longitude source: 17PS Qropographic map (location of well must be shown on a USGS topo map andattached to this form if not using GPS) 5. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 N/A Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town Stale Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code. Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 27.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES 0 NO Cif c. WATER LEVEL Below Top of Casing: 20.0 FT. (Use `+' if Above Top of Casing) 408172 d. TOP OF CASING IS 0.0 FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a variance In accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST N/A f. DISINFECTION: Type N/A Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Top 0.0 Bottom 12.0 FL 2 INCH SCH 40 Top Bottom Ft. Top Bottom _ Ft. 8. GROUT: Depth Material Top 0.0 Bottom 8.0 Ft. POR1LANOOENTCMTE Top Bottom Ft. Top Bottom Ft. Material PVC Method SLURRY 9. SCREEN: Depth Diameter Slot Size Top 12.0 Bottom 27.0 Ft. 2.0 in. .010 in. Top Bottom Ft. in. in. Top Bottom Ft. in. in. Material PVC 10. SAND/GRAVEL PACK: Depth Size Top 10.0 Bottom 27.0 _ Ft. 20-40 Top Bottom Ft. Top Bottom FL 11. DRILLING LOG Top Bottom 0.0 / 8.0 8.0 / 18.0 18.0 / 27.0 /• / / / / / Material FINE SILICA SAND Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY i • r� 51 • .. +.r' $- �� ai312 12. REMARKS: BENTONITE SEAL FROM 8.0 TO 10.0 FEET I DO HEREBY CERTIFY THAT THIS WELL W 15A N 2C, ELL CONS RUCTION ST RECOEEN EDTOTHE ATURE CONSTRUCTED IN ACCORDANCE WITH ARDS, AND THAT A COPY OF THIS 09/05/12 ERTJFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL „Subrnitwithin 30 days ofcompletton to=; Division of Water Quality Information Processing,- ,,::,. _ � ,� .:;�W .•_Y �._:,•::_, 1617 [Mat[ Service Center, Raleigh, NC 27699 161-Phone (919)807-6.300 >.�.,r. 4'•- . s �,w .. .�... ,.�--5....-.may--ar.mow- ..+4 .;.�.. ��..., ._ __-": _. _ .-.., ._.:=vi...7...'.r ,. .e.:x-Y - ..h... , Form GW-lb Rev. 2/09 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION. INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE City or Town ( 704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# NC State 28625 Zip Code OTHER ASSOCIATED PERMIT#(1f applicable) SITE WELL ID #(ir applicable) DI" 3. WELL USE (Check One Box) Monitoring El Municipal/Public ❑ Industrial/Commercial 0 Agricultural ❑ Recovery 0 Injection 0 Irrigation❑ Other ❑ (list use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑S1ope ❑Valley 'Flat ❑Ridge ❑Other LATITUDE 35 ° 14 ' 56.5100 "DMS OR DD LONGITUDE 80 ° 53 ' 52.0400 " DMS OR DD Latitude/longitude source: VGPS Qropographic map (location of well must be shown on a USGS topo map andattached to This form it not using GPS) 5. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 N/A Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code_.Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO V c. WATER LEVEL Below Top of Casing: 20.0 FT. (Use "+" if Above Top of Casing) 408173 d. TOP OF CASING IS 0.0 FT. Above Land Surface* 'Top of casing terminated at/or below land surface may require a variance In accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST N/A f. DISINFECTION: Type N/A Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 34.0 Ft. 2 INCH SCH40 PVC Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Top 0.0 Bottom 29.0 Top Bottom Top Bottom Material FL roeTLANo 5EKrowrE Ft. Ft. Method SLURRY 9. SCREEN: Depth Diameter Slot Size Material Top 34.0 Bottom 44.0 Ft. 2.0 in. .010 in. PVC Top Bottom Ft. in. in. Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK: Depth Size Material Top. 32.0 Bottom 44.0 FL 20-40 FINE SILICA SAND Top Bottom FL To Bottom Ft. 11. DRILLING LOG Top Bottom 0.0 / 8.0 8.0 1 18.0 18,0 1 23.0 23.0 / 44.0 Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY TAN/GRAY SANDY CLAY it At i ! t .,. S-EP 2 1 2012 12. REMARKS: BENTONITE SEAL FROM 29.0 TO 32.0 FEET I DO HEREBY CERTIFY THAT THIS WELL 15A NCA LL CONSTUCTION ST RECOR ° S B' N PROM • D TO THE W CONSTRUCTED IN ACCORDANCE WITH DS,S, AND THAT A COPY OF THIS wNEf�L/ " 09/05/12 SI �l REO'T' RTIFIEDWELL CONTRACr R DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL 2,)Subrnit within 3D days of.comp[etion to -Division of Water QualiInformation Processing;- 1617)MailService Center, Raleigh,NG27699 161, Phone -(919) 807-6300 } ��'C S..aEr:�'v�-.:...nuc., c5 ..���.�3k..�t�'�r--:�:c- ..','Q•. x �.�-r+l�,'�.lx,..�,:x:".,y.��..wt,'? .3�'..--:;w�i'F��...rs .r. a...?� ry:�.nT„f,^F,.a:.z:.:,A�.r ...d-r�•�ii Form GW-lb Rev. 2/09 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION. INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMlT#(d applicable) SITE WELL ID #(if applicable) DW-3 3. WELL USE (Check One Box) Monitoring d Municipal/Public 0 Industrial/Commercial 0 Agriculture! ❑ Recovery ❑ Injection 0 irrigation❑ Other ❑ (list use) DATE DRILLED 08/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Slope ❑Valley Q'Ftat ❑Ridge ❑Other LATITUDE 35 ^ 14 55.8300 - DMS OR DD LONGITUDE 80 • 53 • 51.5400 - DMS OR DD • Latitude/longitude source: IMPS Dfopographic map (location of well must be shown on a USGS topo map andaftached to this form if not using GPS) 5. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 NIA Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO Iirt c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use `+" if Above Top of Casing) 3098 408174. d. TOP OF CASING 15 0.0 FT. Above Land Surface' `Top of casing terminated attor below !and surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST NIA f. DISINFECTION: Type N/A Amount N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness! 7. CASING: Depth Diameter Weight Materiat Top 0.0 Bottom 34.0 Ft. 2 INCH SCH 40 PVC Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Method Top 0.0 Bottom 29.0 Ft. MRTL NI)EEHMPWIa SLURRY Top Bottom _ Ft. Top Bottom Ft. 9. SCREEN: Depth Top 34.0 Bottom 44.0 Top Bottom Top Bottom Diameter Slot Size Material Ft. 2.0 in. .010 in. PVC Ft. in. in. Ft. in. in. 10. SAND/GRAVEL PACK: Depth Size Top 32.0 Bottom 44.0 Ft. 20-40 Top Bottom FL Top Bottom FL Material FINE SILICA SAND 11. DRILLING LOG Top Bottom Formation Description 0.0 1 8.0 BACK FILL 8.0 1 25.0 ORANGE SILTY CLAY 25.0 / 34.0 TAN SILTY CLAY 34.0 1 44.0 GRAY SILTY CLAY / 1 1 SEP 2 1 2012 `IAA 1f". 12. REMARKS: BENTONITF SEAL FROM 29.0 TO 32,0 FEET I DO HER CERTIFY THAT THIS WELL W: CONSTRUCTED IN ACCORDANCE WITH ISA, _LL CONST UCTION ST �1i • RDS. AND THAT A COPY OF THIS RECOD TO T • )1 S '�ATURE 0 CERTIFIED WELL CONTRACT R DATE JOHNNY BURR 09/05/12 PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW-lb Rev. 2/09 Attn:: Ms, Sherri Knight C/O: Mr, David Goodrich NCDENR - Division of Water Quality Aquifer Protection Section - LAC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Injection Performance Record Former ExxonMobil Facility #42094 3721 Freedom Drive Charlotte, NC 28208 U1C Permit W19300192 Incident Number: 6867 Dear Ms. Knight: On behalf of ExxonMobil Environmental Services (EMES), ARCADIS G&M of North Carolina, Inc. (ARCADIS) is submitting an Injection Performance Record to the North Carolina Department of Natural Resources (NCDENR) Division of Water Quality - Aquifer Protection Section for Former ExxonMobil Facility #42094 located in Charlotte, Mecklenburg County, -North Carolina, On August 27 - August 29, 2012, ARCADIS provided oversight of Geologic Exploration Inc. (GEX) to install two injection wells (INJ-1 and INJ-2), one shallow monitoring well (MW=16), and two deep monitoring wells (DW-2 and DW-3), as required by the underground injection control (UIC) Permit approved for the site. On September 17 - September 19, 2012, ARCADIS personnel completed a BioSolveV Surfactant injection at the site, Approximately 1,150 gallons of BioSolve® Surfactant mixture was injected in monitoring wells MW-5 and MW-9 and injection wells INJ-1 and INJ-2. Post -injection Aggressive Fluid Vapor Recovery (AFVR) events were conducted on September 20, 2012, September 21, 2012, September 28, 2012, October 2, 2012, and October 3, 2012, Approximately 1,374 gallons of liquids have been recovered from the post chemical injection AFVR events to date. An injection event record is included as Appendix A. Well construction records for R)e) ARCADIS GSM of North Caro Inc. 801 Corporate Center Drive Suite 300 Raleigh North Carolina 2.7607 Tel 919 854 1252 Fax` 919 854 8448 www.arcadts-us.com Environment Date: October 12, 2012 Contact: Scott Bostian Phone: 919.415.2291 Scott.Bostian@a arcadis- us.com Our ref B0085851.0026 ARCADIS G&M of North Carolina, Inc. NC Engineering Icene # C-1869 NC Surveying license'# C-1869 ifle t1 result ;olterarol de("°` 1,16 C if? p/ssovs ARCADIS r of 'f\fdr ■G� tja, Inc. u' fL• O 9 :'y r 1 i Scott Bo i Senior Ent�"o.0°i.'e©�86190,11004 ARCADIS RECE WED!DE. Riff.' OCR 16 /Vi Aquifer Protection Section shallow monitoring well MW-10, deep monitoring wells DW-2 and DW-3, and injection wells 1NJ-1 and INJ-2, are included as Appendix B. ARCADIS will conduct quarterly post -injection groundwater monitoring and sampling events as indicated in the approved UIC Permit to evaluate the effectiveness of the BioSolve® surfactant injection. A comprehensive groundwater monitoring and sampling event is scheduled for November 2012. A groundwater monitoring report further detailing the BioSolve® surfactant injection and the results of the comprehensive groundwater monitoring and sampling event will be submitted to the NCDENR for review and approval in the fourth quarter 2012. Sincerely, Copies: Ms. Jewel Cox — EMES Mr. Daniel Bowser — NCDENR UST Section File — EM 42094 Jon Farley, P.E. Certified Project Manager! 41. Ms. Sherri Knight October 12, 2012 n IFNNFrer6kiASMnhr,tsiun W raiinandOni- Medea NC-AFPRONEDUiedm EMI RemdsSeoluatsr2012 Iriodon RecabEM 42094 • triea0an RaoydCaw Leda. ThIcice Page: 2/2 INJECTION EVENT RECORD North Carolina Department of Environment and Natural Resources — Division of Water Quality Permit Number 4I0300192 1. Permit Information Exxon Mobil Corporation Permittee Former Exxon Mobil Retail Facility #42094 Facility Name 3721 Freedom Drive, Charlotte, North Carolina Facility Address 2. Injection Contractor Information ARCADIS G&M of North Carolina, Inc. Injection Contractor / Company Name 801 Corporate Center Dr. #300 Street Address Raleigh NC 27607 City State Zip Code ( 919) 854-1282 Area code — Phone number .3. Well Information Number of welts used for injection 4 Well names Mw-5, MW-9, INJ-1, and INJ-2 Were any new wells installed during this injection event? ® Yes ❑ No If yes, please provide the following information: Number of Monitoring Wells 3 Number of Injection Wells 2 Type of Well Installed (Check applicable type): ❑ Bored 0 Drilled ❑ Direct -Push ❑ Hand -Augured ❑ Other (specify) Please include two copies of form GW-1 b for each well installed. Were any wells abandoned during this injection event? ❑ Yes 0 No If yes, please provide the following information: Number of Monitoring Wells Number of Injection Wells Please include two copies of the GW-30 for each well abandoned. 4. Injectant Information aioSolve surfactant Injectant Type Concentration 6s by volume If the injectant is diluted please indicate the source dilution fluid. Fire hydrant (municipal) Total Volume Injected 1,150 gallons Volume Injected per well 50 to 550 gallons 5. Injection History Injection date(s) 9, 17, 2012 - 9/19/2012 Injection number (e.g. 3 of 5) 1 of 2 (estimated) is this the last injection at this site? ❑ Yes El No . I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITHIN THE STDARDS LAID OUT IN THE PERMIT. SIGNATURE OF INJECTION C 0/islia TRACTOR DATE Ryan Habersang and Jared Fino PRINT NAME OF PERSON PERFORMING THE INJECTION Submit the original of this form to the Division of Water Quality within 30 days of injection. Attn: UIC Program, I636 Mail Service Center, Raleigh, NC 27699-1636, Phone No. 9I9-733-3221 Form UIC-IER Rev. 07/09 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE City or Town (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(if applicable) SITE WELL ID #(if applicable) INJ-1 3. WELL USE (Check One Box) Monitoring ❑ Municipaf?Public ❑ Indusbial/Commercial 0 Agricultural Q Recovery ❑ Injection I' IrrigationD Other ❑ (list use) DATE DRILLED 08/28/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 NC 28625 State Zip Code (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CfTY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) DSfope ❑Valley Flat DRidge ❑Other LATITUDE 35 ° 14 •56_5900 ° DMS OR DD LONGITUDE 80 " 53 ' 51-9800 ° DMS OR DD Latitude/longitude source: VGPS 1:Topographic map (location of well must be shown on e USGS topo map endattached.to this form if not using GPS) 5. FACILITY (Narne of the business where the well is located.) EXXONMOBIL - 42094 Fa ditty Name 3709 FREEDOM DRIVE N/A Facility ID# (if applicable) Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL'. Contact Name 3709 FREEDOM DRIVE Malting Address CHARLOTTE NC 28208 City or Town State Zip Code Area -code P,bone number 6. WELL DETAILS: a. TOTAL DEPTH: 23.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO gif c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use °+' if Above Top of Casing) d. TOP OF CASING is 0.0 FT. Above land Surface' 'Top of casing terminated atfor below land surface may require a variance In accordance with 15A NCAC 2C .0118. e. YIELD (gpm): NIA METHOD OF TEST NIA f. DISINFECTION: Type N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weigh! Material Top 0.0 Bottom 13.0 Ft. 2 INCH SCH 4o PVC Top Bottom FL Top Bottom Ft. Amount N/A 8. GROUT: Depth Material Top 0.0 Bottom 9.0 Ft. PCRTtu413E2I QNrrE Top Bottom Ft. Top Bottom Ft. Method SLURRY 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 Ft. 2.0 In. .010 In. PVC Top Bottom Ft. In. ' in. Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK: Depth Top 11.0 Bottom 23.0 FL 20-40 FINE SILICA SAND Tap Bottom Ft. Top Bottom Ft. 11. DRILLING LOG Top Bottom 0.0 8.0 18.0 8.0 18.0 23.0 / / / Size Material t Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY 12. REMARKS: BENTONITE SFAL FROM 9 0 TO 11.0 FEET I DO HEREBY CERTIFY THAT ThS.WELLWA ISA NCA l3 . CONST CTION ST RECOR��•B'. "�; •TO NSTRUCTEO IN ACCORDANCE WITH OS. AND THAT A COPY OF THIS 09/05/12 SI e,i TORE 0 ERTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL �Suht7il v ithrn 3D tiays,igf.cali pletion'to D(vtsr'ori of Water Quality °;Iriforrrtabon Processing, 1 ST IIllafl 5eivlce Center, RaEergh, l+iC27S99 161, hone (91 ) 807-63b0 .t F• Form GW-lb Rev. 2/09 1. WELL CONTRACTOR.' JOHNNY BURR NON ONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION 3098 d. TOP OF CASING IS OD FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): NIA METHOD OF TEST NIA Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL. CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT applicable) SITE WELL ID Rifapplkabte) INJ-2 3. WELL USE (check One Box) Monitoring p Municipal/Public 0 Industial/Commercial ❑ Agricultural ❑ Recovery Injection se. Irrigation❑ Other ❑ Qist use) DATE DRILLED 08/28/12 - 08/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC) LAND SETTING: (check appropriate box) ❑Slope [Valley Eir,Flal ❑Ridge ❑Other LATITUDE 35 ° 14 ' 55.8700 • DMS OR DD LONGITUDE 80 ""53 ' 51.6200 ' DMS OR DD Latitudeilongitude source: OPS topographic map (location of well must be shown on a USGS topo map andattached to this form if not using GPS) b. FAC1LITY (Name of the business where the well is located.) EXXONMOBIL- 42094 NJA Facility Name Fealty ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State 71p Code EXXX ONMOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 2820B City or Town State Zip Code Areasgde Pbpne number 6. WELL DETAILS: a. TOTAL DEPTH: 23.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES 0 NO13/ c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use "4-- if Above Top of Casing) • f. DISINFECTION: Type N/A 9• Top WATER ZONES (depth): ' Bottom Top .Bottom Top Bottom Top Bottom Top Bottom Top Bottom Amount N/A Thickness, 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 13.0 Ft. 2INCH SCH40 PVC Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Top 0,0 Bottom 9.0 FI, PORILAND BENTONITE Top Bottom Ft. Top Bottom Ft. Method SLURRY 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 Ft. 2.0 in. .010 In. PVC Top Bottom FL in. in. Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK: Depth Size Material Top 11.0 Bottom 23.0. Ft. 20-40 Top Bottom Ft. Top Bottom Ft. FINE SILICA SAND 11. DRILLING LOG Top Bottom Formation Description 0.0 / 8.0 BACK FILL 8.0 / 18.0 TAN SILTY CLAY 18.0 1 22.0 WHITE ROCK 22.0 / 23.0 TAN SILTY CLAY / 12. REMARKS: BENTONITE SEAL FROM 9.0 TO 11.0 FEET I a0 HEREBY CERTIFY THATTHIS WELL W 15A NCA LL Co LION ST ,!" RCS, AND THAT A COPY OF THIS RECORI PR Q DTO TRUCTED IN ACCORDANCE WITH 09/05/12 SIGiTURE ORTIFI€D WELL CONTRACTOR DATE JOHNNY BURR • PRINTED NAME OF PERSON CONSTRUCTING THE WELL ti�tx►lt •cult hin�30 slay o• f aQr> pl tiara to Ol�tsidri of YVater•Qtialttjr' trxformatlon Pracesstrag, �1817tMa11`Service Ce'nEery ffa]e1gh, NC �7fi99 161, Pitons �979• j t)07-6300 Form GW-lb Rev. 2/09 NON ESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Narne GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 ) 872-7686 Area code Phone number 2, WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(ir applienbie) SITE WELL ID /Airapplicabie) DW-3 3. WELL USE (Check One Box) Monitoring ljMunicipal/Pubiic ❑ Industriet/Cornmerdar 0 Agricultural ❑ Recovery ❑ Infection ❑ Inlgation0 Other ❑ (list use) DATE DRILLED 08/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Commuriii y, Subdivision, Lot No.. Parcel, Zap Code) CITY_ CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC 1 LAND SETTING (check appropriate box) °Slope ❑Valley liFlat ❑Ridge !]Other LATITUDE 35 • 14 ' 55.8300 ° DMS OR LONGITUDE80 ° 53 ' 51.5400 DMS OR Latitudetlongitude source: MPS Topographic map (location of well must be shown on a USGS topo map andattachedto this form if not using GPS) 5. FACILITY (Name ofthe business where the well is located.) . EXXONMOBIL - 42094 NIA DD DD Facility Name Facility ID# (d applicabte) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXON MOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town Stale Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES O - NO tali c. WATER LEVEL Below Top of Casing: 21-0 FT. (Use "+" if Above Top of Casing) d. TOP OF CASING IS 0.0 FT. Above Land Surface *Top of casing terminated atlor below land surface may require a variance In accordance with 15A NCAC 2C .0118. e. YIELD (gpm): NIA METHOD OF TEST N/A L DISINFECTION: Type N/A Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom- 7. CASING: Depth Diameter Top 0.0 Bottom 34.0 Ft.2INCH Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Top Bottom Top Bottom Top Bottom Thickness) Weight Material scH 40 PVC Top 0.0 Bottom 29.0 FL Pa" -A" EMOr"M Top Bottom Ft. Top Bottom Ft. 9. SCREEN: Depth Diameter Top 34.0 _ Bottom 44.0 Ft. 2.0 in. Top Bottom Ft. In. Top Bottom Ft. in. 10. SANDIGRAVEL PACK: Depth Size Top 32.0 Bottom 44.0 Ft. 20-40 Top. Bottom FL Tap Bottom Ft. 11. DRILLING LOG Top Bottom 0.0 / 8.0 8.0 / 25.0 25.0 / 34.0 34.0 / 44.0 / 1 / / / / Method SLURRY Slot Size Material .010' in. PVC in. in. Material FINE SILICA SAND Formation Description BACK FILL ORANGE SILTY CLAY TAN SILTY CLAY GRAY SILTY CLAY 12. REMARKS: BENTONITF SEAL FROM29.0 TO 37 0 FEET I DO HER 16A NC RECO S CERTIFY THAT THIS WELL W CON r LIMONST en ro CONSTRUCTED IN ACCORDANCE WITH DS, AND THAT A COPY OF THIS 09/05/12 ATURE 0 CERTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW-lb Rev. 2109 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (IndLvldual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# DTHER ASSOCIATED PERMIT#(tt applicable) SITE WELL ID #(If applicable} MW-10 3. WELL USE (Check One Box) Monitoring Ni Municipal/Public 0 Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection 0 Irrigation❑ Other ❑ (11st use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, 5ubdlvMslon, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Slope °Valley efat ❑Ridge DOther LATITUDE 35 ° 14 56.5100 • DMS OR. DD LONGITUDE 80 ° 53 52.0400 ° DMS OR DD Latitude/longitude source: 3PS []Topographic map (location of well must be shown on a USGS topo map andatteched to this form if not using GPS) 6. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 NSA Facility Name Facility fD# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name . 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 27.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO d c. WATER LEVEL Below Top of Casing: 20.0 FT, (Use "+" if Above Top of Casing) d. TOP OF CASING 1S 0.0 FT. Above Land Surface' *Top of casing terminated at/or below land surface may require a variance In accordance with 16A NCAC 2C .0118. o. YIELD (gpm): N/A METHOD OF TEST N/A f. DISINFECTION; Type N/A Amount N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bollom Top Bottom Top Bottom Top Bottom Thickness! 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 12.0 Ft. 2 INCH 60140 PVC Top Bottom FL Top Bottom Ft. 8, GROUT: Depth Material Method Top 0.0 Bottom 8.0 Ft. rW11-AND°Erlra"' SLURRY Top Bottom Ft. Top 8oltom Fl. 9. SCREEN: Depth Diameter Slot Size Materiel Top 12.0 Bottom 27.0 Ft. 2.0 in. .010 In. PVC Top Bottom Ft. In. In. Top Bottom Ft. in. In. 10. SAND/GRAVELPACK: Depth Size Material Top 10.0 Bottom 27.0 Ft. 20-40 ,FINE SILICA SAND Top Bottom FL Top Bottom Ft. 11. DRILLING LOG Top Bottom Formation Description 0.0 / 8.0 BACK FILL 8.0 - / 18.0 ORANGE SANDY CLAY 18.0 / 27.0 TAN SANDY CLAY / / / 12. REMARKS: BENTONITE SEAL FROM 8.0 TO 10.0 FEET I DO HEREBY CERTIFY THAT THIS WELL WAS C 15A NCAC 2 EL ONSTRLC ION STAND • ; f RECORD EE 00THE L TRLICTED 114 ACCORDANCE WITH , AND THAT A COPY OF THIS ER /M°."09/05/12 SIGNRE OF CERTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW-1b Rev. 2/09 NON ONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department ofEnvironment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(If applicable) SITE WELL ID #(IFapplicable) 3. WELL USE (Check One Box) Monitoring [j MunicipallPublic ❑ Industrial/Commercial ❑ Agricultural ❑ Recovery ❑ Injection ❑ Irrigation❑ Other ❑ (list use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC I LAND SETTING: (check appropriate box) ❑Slope ❑Valley Q"Flat ID Ridge ❑Other LATITUDE 35 ° 14 .56.5100 "DMS 0R DD LONGITUDE 80 ' 53 . 62.0400 " DMS OR DD Latitude/longitude source: g_ PS pfopographic map (location of well must be shown on a USGS topo map andattached to this form if not using GPS) 5. FACILITY (Name of the business where the well Is located.) EXXONMOBIL - 42094 NIA Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO [i c. WATER LEVEL Berow Top of Casing: 20.0 FT. (Use if Above Top of Casing) 3098 d. TOP OF CASING IS 0.0 FT. Above Land Surface' "Top of casing terminated atlor below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST N/A f. DISINFECTION: Typo N/A Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness! 7. CASING: Depth Diameter Weight Material Top 0,0 Bottom 34.0 _ FL 2 INCH SCH 40 PVC Top Bottom Ft. Top Bottom - Ft. 8. GROUT: Depth Top 0.0 Bottom 29.0 Material Ft. PORTUWO BENTONITE Top Bottom Ft. Top Bottom Ft. Method SLURRY 9, SCREEN: Depth Diameter Slot Size Material Top 34.0 Bottom 44.0 FL 2.0 In. .010 In. PVC Top Bottom FL In. In. Top Bottom Ft. In. in. 10. SANDIGRAVEL PACK: Depth Size Material Top 32.0 Bottom 44.0 Ft, 20-40 Top Bottom Ft, Top Bottom Ft. 11. DRILLING LOG Top Bottom 0.0 1 8.0 8.0 / 18.0 18.0 / 23.0 23.0 / 44.0 FINE SILICA SAND Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY TAN/GRAY SANDY CLAY 12. REMARKS: BENTONITE SEAL FROM 29.0 TO 32.0 FEET 1 CO HEREBY CERTIFY THAT THIS WELL WA 15ANCA C, W LCONS -UCT10NSTA RECOR►g S B: N PRO IOTO TI-fE CONSTRUCTED INACCOROANCEWITH RDS,S, ANDTHATAACCOPY OF THIS 09105(12 SI �� RE 0 1 ERTIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Fi'ly � ' •,, y a, at } rf� i-it1 �x Si'� �fi,�.c �: <c`�+_. ��i.yF�S�r-. i �x x"A�'� -4 ,J rSy 3 f rz . � a i _ y�Cl`}�s.�r �h��;+ is Su6mltwttJnptt 30 dayTs,of completion to, l�tsran of�Water Qu8IIty ;In ormatlon P---- -'-- kY 617 114i CS rjSer1 ce Centr, Ra(eI9h 1�G 2 699 1G i>lon �Tu{g19j 8D7 6 �Ur Form GW-1b Rev, 2)09 NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Narne GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zip Code (704 .) 872:7586 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#Of applicable) SITE WELL ID #(ii appfrcable) INJ-1 3. WELL USE (Check One Box) Monitoring ❑ Municipal/Public 0 Industrial/Commercial {3 Agricultural 0 Recovery 0 Injection Irrigation❑ Other ❑ (list use) DATE DRILLED 08/28/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community. Subdivision, Lot No., Parcel, Zip Code) CiTY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Slope ❑Valley (Flat ❑Ridge ❑Other LATITUDE 35 ^ 14 56.5900 ^ DMS OR .DD LONGITUDE 80 ^ 53 ' 51-9800 " DMS OR • DD Latitude/longitude source: Qj3PS ['Topographic map (location of well must be shown on a USGS topo map andaftached to this form if not using GPS) 6. FACILITY (Name of the business where the well is located.) EXXONMOSIL - 42094 Facility Name 3709 FREEDOM 'DRIVE Street Address CHARLOTTE City or Town EXXONMOBIL'. N/A Facility ID# (if applicable) NC 28208 State Zip Code Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE City or Town Area_cgde Phone number.. 6. WELL DETAILS: . a. TOTAL. DEPTH: 23.0 FEET NC 28208 State Zip Code b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO tat' c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use °+° if Above Top of Casing) SI d. TOP OF CASING IS 0.0 Ft Above Land Surface* "Top of casing terminated atior below tend surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gprn): N/A METHOD OF TEST NIA f. DISINFECTION: Type N/A Amount N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top_ 0.0 Bottom 13.0 Ft. 2 INCH SCH 40 PVC Top Bottom Ft. Top Bottom R. 8. GROUT: Depth Material Method Top 0.0 Bottom 9.0 Ft. POR7IANDEEMO41rE SLURRY Top Bottom FL Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 Ft 2.0 in. .010 In. PVC Top Bottom Ft in. in. - Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK; Depth are Material Top 11.0 Bottom 23.0 Ft. 2D-40 FINE SILICA SAND _ Top Bottom Ft Top Bottom Ft 11. DRILLING LOG Top Bottom Formation Description 0.0 / 8.0 BACK FILL 8.0 / 18.0 ORANGE SANDY CLAY 18.0 / 23.0 TAN SANDY CLAY 12. REMARKS: BENTONITF SEA, FRO 9.0 TO 11 0 FEFT I DO HEREBY CERTIFY MATTE'S WELL WA 16ANCp L{ , CONST' CT1ONSTA RECOR.W • B', "• DTOT e, �TURE O'" ERTIFIED WELL CONTRACTOR DATE NSTRUCTED IN ACCORDANCE WITH DS. MD THAT A COPY OF THIS 09/05/12 JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL a, 5t bin/ wtthirt 30 days Hof com Ietaoi tn .Division of Water Quality- • ;ltiformation t'�ocess1ng, -4t17 Matl ,Seiv ce Center,SRaleigti h�C 27699-1 fi 1, PFione {8 i5� 807-83b0 • Form GW-1 b Rev. 2109 NON _RESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION II 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176.COMMERCE BLVD Street Address STATESVILLE City or Town • NC 28625 State Zip Code (704 ) 872-76B6 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(ifapplicabie) SITE WELL ID or applkahle) l NJ-2 3. WELL USE (Check One Box) Monitoring 0 Munidpa&Publlc ❑ tndustriaVCommercial ❑ Agricultural 0 Recovery t7 Injection 6d Irrigation❑ Other 0 (fist use) DATE DRILLED 08/28/12 - OB/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zrp Code) on-: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC I LAND SETTING: (check appropriate box) DSlope DVatley 'Hat ❑Ridge ❑Other LATITUDE. 35 •14 •56.8700 •OMS OR DD LONGITUDE 80 • 53 • 51.6200 • DMS OR DD Latitude/longitude source: 3PS oropographic map (location of well must be shown on a USGS topo map andaltached to this form if not using GPS) 5. FACILITY (Name of the business where the well is located.) EXXONMOBIL - 42094 N�4 Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Malting Address CHARLOTTE NC 28208 City or Town Stale Zip Code AreaCRde P.hpne number 6. WELL DETAILS: a. TOTAL DEPTH: 23.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ NO c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use •+• if Above Top of Casing) d. TOP OF CASING IS 0.0 FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): NIA METHOD OF TEST N/A f. DISINFECTION: Type N/A Amount NIA g. WATER ZONES (depth): ' Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom 7. CASING: Depth Diameter Top 0.0 Bottom 13.0 FI. 2 INCH Top Bottom Ft. Top Bottom Ft. Thickness! Wolght Material SCH4O PVC 8. GROUT: Depth Material Method Top 0.0 Bottom 9.0 Fi. PORTLAND861°NAE SLURRY Top Bottom Ft Top Bottom Ft. 9. SCREEN: Depth Diameter Slot Size Material Top 13.0 Bottom 23.0 Ft. 2.0 in. .010 In. PVC Top Bottom FL in. in. Top Bottom Ft. in. in. 10. SAND/GRAVEL PACK: Depth Size r Material Top 11.0 Bottom 23.0 Ft. 20-40 FINE SILICA SAND Top Bottom Ft. Top Bottom Ft 11. DRILLING LOG Top Bottom 0.0 / 8.0 Formation Description BACK FILL 8.0 / 18.0 TAN SILTYCLAY 18.0 1 22.0 WHITE ROCK 22.0 / 23.0 TAN SILTY CLAY / / / / / / 12. REMARKS: BENTONITE SEAL FROM 9,0 TO 11.0 FEET I DO HEREBY CERTIFY THAT THE WELL W 15A NCAC/It 1tNNS�LL CON C1ICN ST RECORB lJ PR D TO NSTRUCTED IN ACCORDANCE WITH DS,'AND THAT AACCOPY OF THIS 09/05/12 SIICTURE 0> RT1F1ED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL SrJ�mtt wtEt iti: 0 d`ay of`o impreiion ie .Divlsron of Water Quality lrifotTnatiisn Pracessii�g; 1617sNi ilSgrp�c� e'itter; Raleigh, NNiC �7699.16`1,.Phone':'(9t9)807 6300 ; Form GW-lb Rev. 2/09 NON RESIDENTIAL WELL CONSTRUCiIQN RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR JOHNNY BURR Well Contractor (lndlvfdual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town Stele Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(a eppliabte) SITE WELL ID #(if applicab(c) DW 3 3. WELL USE (Check One Box) Monitoring i( Municipal/Public 0 Industrial/Commercial 0 Agricufhrral ❑ Recovery 0 Injection 0 Irrigation❑ Other ❑ (list use) DATE DRILLED 08/29/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zp Coda) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) °Slope ❑Valley 'Flat ❑Ridge DOther LATITUDE 35 a 14 •55.8300 - DMS OR DD LONGITUDE 80 ° 53 . 51.5400 F DMS OR DD Latitude/longitude source: MPS []topographic map (location of well must be shown on a USGS tope map endattachedto this form if not using GAS) 5. FACILITY (Name of the business where the well Is located.) . EXXONMOBIL - 42094 N/A Facility Name 3709 FREEDOM DRIVE Street Address CHARLOTTE City or Town EXXONMOBIL Facility ID# (if applicable) NC 28208 State Zip Code Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone Number 6, WELL DETAILS: a. TOTAL DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES 0 NO p� c. WATER LEVEL Below Top of Casing: 21.0 FT. (Use "-"if Above Top of Casing) d. TOP OF CASING IS 0.0 FT. Above Land Surface* "Top of casing terminated atior below land surface may require a variance In accordance with 15A NCAC 2C .0118. e. YIEL.D (ppm); NIA METHOD OF TEST N/A I. DISINFECTION: Type N/A Amount NIA g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness! 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 34.0 Ft. 2 INCH sCH 40 PVC Top Bottom Ft. Top Bottom Ft. 8. GROUT: Depth Material Top 0.0 Bottom 29.0 FL mut.'" BENTotgrE Top Bottom Ft. Top Bottom Ft. Method SLURRY 9. SCREEN: Depth Diameter SlotSize Material Top 34.0 Bottom 44.0 Ft 2.0 in. .010 in. PVC Top Bottom FL In. in. Top Bottom FI. in. in. 10. SAND/GRAVEL PACK: r Depth Size Material Top 32.0 Bottom 44.0 Ft. 20-40 FINE SILICA SAND Top ' Bottom Ft Top Bottom FL 11. DRILLING LOG Tap Bottom 0.0 / 8.0 8.0 1 25.0 25.0 / 34.0 34.0 1 44.0 Formation Descrfplion BACK FILL ORANGE SILTY CLAY TAN SILTY CLAY GRAY SILTY CLAY 12. REMARKS: BENTONITE SEAL FROM29 0 TO 32.0_FEET IDOHER 16A NC RECO S CONSTRUCTED IN ACCORDANCE WITH OS, AND THAT A COPY OF THIS 09/05/12 ATURE 0 CERTIFIED WELL CONTRATOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL Form GW-lb Rev. 2/09 i e NONRESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 3098 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 City or Town State Zfp Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(€! applicable) SITE WELL ID #(lr applicable) MW-10 3. WELL USE (Check One Box) Monitoring tj MunlcrpatuPubllc ❑ Industrial/Commercial ❑ Agricultural 0 Recovery ❑ Infection ❑ Irrigation❑ Other in (list use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208 (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC 1 LAND SETTING: (check appropriate box) ❑Slope ❑Valley &Flat ❑Ridge ❑Other LATITUDE 35 °14 • 56.5100 ° DMS OR DO LONGITUDE 80 • 53 62.0400 " DMS OR DD Latitude/longitude source: cjPS ['Topographic map - .. (location of well must be shown on a USGS topo map andettached to this form if not using GPS) 6. FACILITY (Name of the business where the well Is located.) EXXONMOBIL - 42094 N/A Facility Name 3709 FREEDOM DRIVE Street Address CHARLOTTE City or Town EXXONMOBIL Facility ID# (if applicable) NC State 28208 Zip Code Contact Name 3709 FREEDOM DRIVE Mailing Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL DEPTH: 27.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES ❑ c. WATER LEVEL Below Top of Casing: - 20.0 (Use +" if Above Top of Casing) NO I), Ff. d. TOP OF CASING IS 0.0 FT. Above Land Surface' 'Top of casing terminated atlor below lend surface may require a varianco In accordance with 15A NCAC 2C .0118. o. YIELD (gpm): N/A METHOD OF TEST f. DISINFECTION: Typo N/A Amount g. WATER ZONES (depth): NiA N/A Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom 7. CASING: Depth Diameter Top 0.0 Bottom 12.0 Ft. 2INCH Top Bottom FL Top Bottom FL 8, GROUT: Depth Top. 0.0 Bottom 8.0 Thickness/ Weight Material SCH 40 PVC Material Ft. PORTIAND BENTONRE Top Bottom Ft. Top Bottom Ft. Method SLURRY 9. SCREEN: Depth Diameter Slot Size Material Tap 12.0 Bottom 27.0 Ft. 2.0 In. .010 In. PVC Top Bottom Ft. tn. in. Top Bottom Ft. in. In. 10. SAN DI'GRAVEL PACK; Depth Sfze Material Top 10.0 Bottom 27.0 FL 20-40 FINE SILICA SAND Top Bottom FL Top. Bottom Ft. • 11. DRILLING LOG Top Bottom 0.0 / 8.0 8.0 / 18.0 18.0 / 27.0 / / / • / 1 Formation Description BACK FILL ORANGE SANDY CLAY TAN SANDY CLAY / / 12. REMARKS: BENTONITE SEALFRQM 8.0 TO 10.0 FFET 100 HEREBY CERTIFY TitAT THIS WELL WAS 15ANCAC 'y+ L •NSTR iONSTAN RECORD EE y 0 -' O THE STRUCTED IN ACCORDANCE WITH , AND THAT A COPY OF THIS ER J09/05/12 SIG .F RE OF .' TIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL tap4 tt Process) g .1'S rk'Y�S it4. Form GW-lb Rev. 2/09 NON RESIDENTIAL WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources- Division of Water Quality WELL CONTRACTOR CERTIFICATION # 1. WELL CONTRACTOR: JOHNNY BURR Well Contractor (Individual) Name GEOLOGIC EXPLORATION, INC Well Contractor Company Name 176 COMMERCE BLVD Street Address STATESVILLE NC 28625 CIIy or Town State Zip Code (704 ) 872-7686 Area code Phone number 2. WELL INFORMATION: WELL CONSTRUCTION PERMIT# OTHER ASSOCIATED PERMIT#(If applicable) SITE WELL ID #(if applicable) ' DWW2 3. WELL USE (Check One Box) Monitoring 0/Municipal/Public ❑ industrfal/Commerclal ❑ Agriculluraf D Recovery ID Injection ❑ Irrigationp Other ❑ (list use) DATE DRILLED 08/27/12 4. WELL LOCATION: 3709 FREEDOM DRIVE 28208. (Street Name, Numbers, Community, Subdivision, Lot No., Parcel, Zip Code) CITY: CHARLOTTE COUNTY MECKLENBURG TOPOGRAPHIC / LAND SETTING: (check appropriate box) ❑Sfope [Valley d(Ftat ❑Ridge ❑Other LATITUDE 35 •14 66.5100 ° DMS OR DD LONGITUDE 80 • 53 • 52.0400 " DMS OR DD Latitudeltangllude sotirce: IMPS °topographic map (location o1 well must be shown on a USGS topo map andattached to this form if not using GPS) 5. FACILITY (Name of the business where the well Is located.) EXXON MOBIL - 42094 N/A Facility Name Facility ID# (if applicable) 3709 FREEDOM DRIVE Street Address CHARLOTTE NC 28208 City or Town State Zip Code EXXONMOBIL Contact Name 3709 FREEDOM DRIVE Malting Address CHARLOTTE NC 28208 City or Town State Zip Code Area code Phone number 6. WELL DETAILS: a. TOTAL. DEPTH: 44.0 FEET b. DOES WELL REPLACE EXISTING WELL? YES 0 NO 4/ c. WATER LEVEL Below Top of Casing: 20.0 Fr. (Use'+" if Above Top of Casing) 3098 d. TOP OF CASING IS 0,0 FT. Above Land Surface' 'Top of casing terminated at/or below land surface may require a variance in accordance with 15A NCAC 2C .0118. e. YIELD (gpm): N/A METHOD OF TEST N/A f. DISINFECTION: Type NIA Amount N/A g. WATER ZONES (depth): Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Top Bottom Thickness/ 7. CASING: Depth Diameter Weight Material Top 0.0 Bottom 34.0 , Ft., 2 INCH sal 40 PVC Top Bottom Ft. Top Bottom Fi. • B. GROUT: Depth Material Top 0.0 Bottom 29.0 Ft, PORn. NODENTONRE Top Bottom Ft. Top Bottom FL Method SLURRY 9. SCREEN: Depth Diameter Slot Size Material Top 34.0 Bottom 44.0 Ft. 2.0 In. .010 In. PVC Top Bottom •Ft. fn. In. Top Bottom Ft. En. in. 10. SAND/GRAVEL PACK: Depth Size Material Top 32.0 Bottom 44.0 Ft. 20-40 Top Bottom - Ft. FINE SILICA SAND Top Bottom Ft: - 11. DRILLING LOG Tap Bottom Formation Description 0,0 / 8.0 BACK FILL 8.0 / 18.0 ORANGE SANDY CLAY 18.0 / 23.0 TAN SANDY CLAY 23.0 / 44.0 TAN/GRAY SANDY CLAY / 12. REMARKS: BENTONITE SEAL FROM 29.0 TO 32.0 FEET 100 HEREBY CERTIFY THAT THIS WELL WA 15A NCA C. W LL CONST - 11CTION STA RECORBPR• r DTOTHE CONSTRUCTED INACCORDANCEWRH DS.S. AND THAT AACCOPY OF THIS 09/05/12 SI r► URE 0 p' TIFIED WELL CONTRACTOR DATE JOHNNY BURR PRINTED NAME OF PERSON CONSTRUCTING THE WELL j ��-ing,' S .ibmitwifhinf30 diays.of compie tonItbr Dtvrsiont of.Wa en:Qualify ..tinfotmatiatiRrocessi Y a�. ✓' / 0 ,s kgSa»'j� g..i4.5r.a M� i Serrttrce e,pnter h, f 4 269 3469 Phone �91.9);807. 63QOr#? „w11Ati h-' �t� ?' ��.a �S n'� =.. :fix.._. S'i, zs,.y;..5i x.>tmw. L F�..>�•�rx,Yi+�t.�.�.:,d'dna,.�3_.i�-�.�.,�.,.r. �E�:�, Form GW-lb Rev. 2/09 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P,E. Dee Freeman Governor Director Secretary March 12, 2012 Jewel Cox -- Project Manager Exxon Mobil Environmental Services 1016 W. Poplar Avenue Suite 106 - Number 232 Collierville, TN 38017 Dear Ms, Cox: Subject.: Acknowledgement of Application No, W10300192 Former ExxonMobil Retail Facility #42094 Injection In situ. Groundwater Remediation Well. (51) System Mecklenburg County The Aquifer Protection Section acknowledges receipt of your permit application and supporting documentation received on March 2, 2012. Your application package has been assigned the number listed above, and the primary reviewer is David Goodrich. Central and Mooresville Regional Office staff will perform a detailed review of the provided application, and may contact you with a request for additional information. To ensure maximum efficiency in processing permit applications, the Aquifer Protection Section requests your assistance in providing a timely and complete response to any additional information requests. Please note that processing standard. review permit applications may take as long as 60 to 90 days after receipt of a complete application, If you have any questions, please contact David Goodrich at (919) 807-6352 or david.,goodriecdenr,gov. Sincerely, Debra .l. Wa Groundwater Protection Unit Supervisor cc: Mooresville Regional Office, Aquifer Protection Section Scott Bostian a_ ARCADIS Permit File WI0300192 AQUIFER PROTECTION SECTION 1636 Mall Service Center, Raleigh, North Carolina 27699-1536 Location: 512 N, Salisbury St.,, Raleigh, North Carolina 27604 Phone:919.B07-6464 i FAX:919-807-6496 Internet: wtiww,ncweterqualityorq An Equal Opprtuniry 4 AFflrnaEve Ac tr(tn Employer None E?rhCa1fC"1Iinat Natterrttj Date: Vllstrch 12, 2 To: 'LIFER PROT 7TION ,SE "TI : . P . 'CATION REVI AV REQUEST FORM ndon Davidson, ARO-A.PS rt Barnhardt, FRO-APS drew Pitner, MRO-APS Timmerman, RRO-A PS From: Dar id Goodrich , Land Appllication C nit Telephone: (9,19) 807- 52 E-Mail:: davidapodriclt"ncde¢rtaov id Ma\, War'"a.RO-A P.S arlie Stehnlan..' iRO-CAPS t.rri. Knight, V SRO-APS Fax: (919) 807-6496 A. Permit Number: W10300192 B. Own Exx nmobil Enc=iro nrnental Services C. Facility°/Operation: Foilner L xxonrnubile,Ret4i facili42094 X Proposed D. Anpl cation: I. .Permit Type: ri Animal I xistin goon UIC - (5,A7) open loop geothermal For Residuals D Land App. 1111 D&M 111] 503 Exempt 2. Project Type: X New l Major Mod. j :Minor Mod. X Facility tion [1 Reuse Recycle Li 503 E. Cornrnents/Other Information: X Operation k I-R Infiltration X CiiW Rernediation (ND) 51 lnj. wells Ren fl Surface Disposal El Animal �a. Renewal w/ Mod. d like to accomtsan you on a site visit. Attached, you will find all information submitted in support of the above -referenced app review, comment, and/or action. Within 30 calendar dais, please take the following ac.tiu ? _ R.etum a Completed APSARR Form, - .Please comment [ 1 Attach Well Construction Data :Sheet. [1 Attach Attachment E3 for C'ertificati rr f.y the I..APCI1. El Issue an Attachment 13 Certification from the RO,* * Remember that you will be responsible for coordinating site visits and reviev7s, as v�e1l as additional information requests. with other RC)-APS representatives in order to prepare a complete Ania.chm.ent 13 for certification. Refer to the RPP S()P for additional dciu1.. \Vh.en you receive this request form, please write your name and date; in t:l)e spaces below, :mike a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Re iewer: FORM: Al.)SARR 07/06 Pagc 1 of 1 Permit Number W10300192 Central Files: APS• ' SWP 03/12/12 Permit Tracking Slip Program Category Ground Water Status Project Type In review New Project Permit Type Version Permit Classification Injection In situ Groundwater Remediation Well (51) Individual Primary Reviewer david.goodrich Coastal SW Rule Permitted Flow Facility Facility Name Former ExxonMobil Retail Facility #42094 Location Address 3721 Freedom Dr Charlotte NC 28208 Owner Permit Contact Affiliation Scott Bostian Engineer Environmental Sr 801 Corporate Center Dr Raleigh NC 27607 Major/Minor Region Minor Mooresville County Mecklenburg Facility Contact Affiliation Owner Name Exxonmobil Environmental Services Dates/Events Owner Type Non -Government Owner Affiliation Jewel Cox 1016 W Poplar Ave Collierville TN 38017 Orig Issue App Received Draft Initiated 03/02/12 Scheduled Issuance Public Notice Issue Regulated Activities RequestedtReceived Events RO staff report requested RO staff report received Outfall NULL Effective Expiration Waterbody Name Stream Index Number Current Class Subbasin 4 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P.E. Dee Freeman Governor Director Secretary March 12, 2012 Jewel Cox — Project Manager Exxon Mobil Environmental Services 1016 W. Poplar Avenue Suite 106 - Number 232 Collierville, TN 38017 Subject: Acknowledgement of Application No. WI0300192 Former ExxonMobil Retail Facility #42094 Injection In situ Groundwater Remediation Well (5I) System Mecklenburg County Dear Ms. Cox: The Aquifer Protection Section acknowledges receipt of your permit application and supporting documentation received on March 2, 2012. Your application package has been assigned the number listed above, and the primary reviewer is David Goodrich. Central and Mooresville Regional Office staff will perform a detailed review of the provided application, and may contact you with a request for additional information. To ensure maximum efficiency in processing permit applications, the Aquifer Protection Section requests your assistance in providing a timely and complete response to any additional information requests. Please note that processing standard review permit applications may take as long as 60 to 90 days after receipt of a complete application. If you have any questions, please contact David Goodrich at (919) 807-6352 or david.goodrich@ncdenr.gov. Sincerely, for Debra J. Watts Groundwater Protection Unit Supervisor cc: Mooresville Regional Office, Aquifer Protection Section Scott Bastian — ARCADIS Per-init File WI0300192 AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 512 N. Salisbury St., Raleigh, North Carolina 27604 Phone: 919-807-6464 I FAX: 919-807-6496 Internet: www.ncwaternuality.orq NorthCarolina ;Vat/La/4 An Equal Opportunity 1 Affirmative Action Employer State of North Carolina Department of Environment and Natural Resources Division of Water Quality APPLICATION FOR PER IIT TO CONSTRUCT AND/OR USE A Type 51 Wells — In Situ Groundwater Remediation / Type 5T FOR INJECTION • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated grotandwater. • Submit TWO copies of the completed application and all attachments to the address cm the last page of this ftwm. • Any changes made to this form will result in the application package being returned, A. Application Number (to be competed by DWQ): 1. GENERAL INFORMATION: 1. Applicant's Name. (generally the responsible party): Jewel Cox (ExxonMob nvirotunentalSentices) 2. Signing Official's Name*: * Signing Official must be in accordance with instructio sin part VI on page 7. 3. Mailing address of applicant:... _1016 W.1'p ar Ave, Suite 106, Number 2 2 City. C:"ollterville Telephone number:, 901 State: TN Zip t17 Fax number: 262.313.1 s30 4. Property C vner's Name (if different from Applicant): Robert.Morris Property Owner's mailing address: 5804 Sharon Road. City: Charlotte State: NC Zip:_S 6. Name and address oontact person who can answer questions about the proposed injection project: Name: Scott Bostian ..._. Title: Senior Environmental anf*ineer Company:_ Address: City: ARCADIS aleijh Telephone number: Email Address: Sco It. PER' II:T INFORMATION: Project ( Rene er Drive., Suite 300 919.854.1282 ext 222 )arcadis-us.c ( Modification of exist' State:a-.NC:Zip: 27607 Fax number: 919.854.5448 ( Renewal of existing permit without modification f existing permit with modification If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number and the issuance date For renewal without modifications, fill out sections I & 11 only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). For a51 renew°ats, submit a status report including monitoring results of all injection activities to date. Revised 6/09 Page 1 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection HI. INCIDENT & FACILITY DATA B. FACILITY INFORMATION 1. Facility name: Former ExxonMobil Retail Facility #42094 2. Complete physical address of the facility: 3721 Freedom Drive City: Charlotte County: Mecklenburg State: NC Zip: 28208 C. INCIDENT DESCRIPTION 1. Describe the source of the contamination: Underground Storage Tanks (USTs) onsite stored unleaded gasoline, heating oil, and used motor oil at the above site. In 1990 the property was divested by Exxon and the USTs and ancillary components were removed. Petroleum impacted soil was discovered during UST removal activities at the base of the UST pit and beneath one dispenser island. Soil and groundwater samples collected in 1990 indicated that volatile hydrocarbon contamination present in the soil was in contact with groundwater at the site. The amount and cause of the release is unknown. The site facilities were demolished and USTs closed by removal in 1990. The site is currently operating as a vehicle repair facility. 2. List all contaminants present in soils or groundwater at the site (contaminants may be Listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Soil: volatile hydrocarbons Groundwater: volatile hydrocarbons 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ( es If yes, list maximum measured separate phase thickness Historical maximum thickness of 0.53 feet in MW-1 on October I0, 2008. Last NAPL detection was on October 6, 2011 in MW-9 at a thickness of 0.73 feet. ( No If no, list maximum concentration of total VOCs observed at site: The most recent sampling event on October 6, 2011 indicated dissolved -phase concentrations of benzene (31,800 ppb), 1.2-dichloroethane (1,710 ppb), and EDB (136 ppb) which exceed the applicable North Carolina Gross Contamination Levels (GCLs) standards. Tetrachloroethvlene, a constituent associated with dry cleaning releases, was detected in MW-7 at a concentration of 2,300 ppb and exceeds the applicable North Carolina GCL standard. 4. Agency managing the contamination incident: (tST Secti(Superfund Section (including REC Program and DSCA sites) (DWQ Aquifer Protection Section ( Solid Waste Section ( Hazardous Waste Section ( Other: 5. Incident managers name: Daniel Bowser and phone number: 704.663.1699 6. Incident number or other site number assigned by the agency managing the contamination incident: Groundwater Incident #6867 Revised 6/09 UIC-5I/5T Page 2 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection D. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: NA 2. DWQ Non -Discharge or NPDES permits: NA 3. County or DEH subsurface wastewater disposal permits: NA 4. Other environmental permits required by state or federal law: NA Revised 6/09 UIC-5I/5T Page 3 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — Jn Situ Groundwater Remediation / Type 5T Wells — Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA List all proposed injectants. NOTE: Any ,substance to he it lcc.tc>d as et tr cer or to rrc artc to in situ reined: eztr rra rrrar t be r°ev.ei,=ed by the Occupational and Enr it°crnrrre rttal Epide, iolo y Se:°ctaon t EES`j cof the Division al Public Ifcalth, Department Health and Human ,service~. Review the lr+t e r l�r° a ri � cic t: or contact the WC Program to eletcr•rninc // St Injectat c proposing have been rew ,,'d by OFFS B iosolve,, I isted as an Approved Injectant by NCDENR Concentration at point of injection: maximum of 6°/ volume,/volume (aqueous solution) Percent if in a mixture with other inaectants: no other injectants Concentration at point of injc Percent if in a mixture with other inuectants:_ Concentration at point of injection: Percent if in a mixture with other injectants: tnlectant: Concentration at point of injection:� Percent if in a mixture with other injectants,— Source of fluid s used to dilute a ted above: undwa.ter from private well or any well within If any well within `/ mile of in. the following information: rite hydrant, will have water delivered by private ve'd a. Location/ID number of source: b. Depth of source: site, a private well, or surface water is to be used as the fluid source, supply c. Formation:. d. Rock/Sediment type: e. In Attachment C, provide a current, complete chemical anaiy°sof the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. .NOTE: I/` contaminated groundwater is to be used as the dilution or chaset brad, this° is not the properperrnit applicationlorrra. Your must apply fOr ca elosed-loop groundwater r renu'diatimt pert ojP!i zFr li'I�wS". Revised 6109 tJIC->PST Page 4 of tt APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: approximately 10 hours/event a. Maximum number of separate injection events: 2 b. Expected duration of each injection event: 1 day (injecting 4 wells simultaneously) c. Expected duration between events (if more than one event): approximately 6 months 2. Injection rate per well: 1.0 gallons per minute (gpm) 3. Total Injection volume: -2400 gallons per day (gpd); -2400 gallons per event (if separate events) 4. Injection pressure: gravity feed preferred. If that's unsuccessful, low pressure (maximum of 5 psi) will be applied pounds/square inch (psi) 5. Temperature at point of injection: dependent upon water source (fire hydrant) and weather conditions; no heated water will be injected °F 6. Briefly describe how the above parameters will be measured and controlled: pressure gauges, flow meters/totalizers, field groundwater parameter meters (YSI, Horiba or similar) 7. Estimated hydraulic capacity of the well: 1.0 C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: gpm xistin s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. (oposed s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: TBD (Geologic Exploration, Parratt Wolf or SAEDACCO) NC Well Contractor Certification number: TBD (NC#2401, #2489, or #2332., respectively) 3. Date to be constructed: Subsequently upon permit approval Number of borings: Two 2- inch injection wells) Approximate depth of each boring (feet):23 feet below grade (proposed), 35 ft bgs (MW-5), 32 ft bgs (MW-9) 4. Screened interval/Injection interval of injection wells: Depth: 13-23 (proposed), 15-35 (MW-5), 17-32 (MW-9)_ feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: CPVC ( Stainless steel( Other: Casing depth: 0 to 13 ft (23 ft proposed well), 0-15 (MW-5), 0-17 (MW-9). 6. Grout (N/A if injection is through direct push rods): Type: Cement ( Bentonite ( Other: Bentonite depth: 0 to 3 feet below grade. Revised 6/09 UIC-5I/5T Page 5 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — in Situ Groundwater Remediation / Type 5T Wells — Tracer Injection V. ATTACHMENTS Provide the following items as separate attachments with the given headings: A. SITE HISTORY Provide a brief description of the site history including: (1) (2) (3) site usage historically and present, origin of the contamination, previous remedial action(s). NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under their direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work prepared or approved by a licensed geologist, or a subordinate under their direction, be signed and sealed by the licensed geologist. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) (2) (3) (4) the regional geologic setting; significant changes in lithology; the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and the depth to the mean seasonal high water table. C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. Ha private well or a well within % mile of the injection site is used as the source well, include chemical analysis of source fluid here. D. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) goals of the injection project; (2) explanation and/or calculations of how the proposed injectant volume and concentration were determined; (3) a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (4) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: (1) construction plans and materials; (2) operation procedures; (3) a detailed diagram of the surface and subsurface portions of the system; and (4) a planned injection schedule. Revised 6/09 UIC-5I/5T Page 6 of 8 NO products, or cont(arr roar parameters bt41ic11 nun. 45' other electron acceptors reactions and rate o/,.transport G. \Nl l l Dry A Provide a tabula proposed injection Such data shall borehole depth MAPS Attach the followin APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WEI L(S) FOR IN .II° 'Cr :ON Type 51 'Wells — In Situ Groundwater Re.n>ediation / Type 5T Wells — Tracer Io,jec NITORING PLAN ide a plan for morrito f'the injectiratty irrc.luding: a list. of existing and proposed monitoring wells to be used; a list of monitoring parameters and analytical methods to be use a schedule for sampling to monitor the proposed ir• jectarort. The selected monitoring oc.°e'lls must be located so fluids outside the irlt`ce.licort ctre lurt° or it:termed Oleo the progress The monitoring 1%i'C`to,ti and contarttinant% and U. to detect a f data on all existing or abandoned we wwithin ' mile of the injec zone,. including, but not limited to, monitoring wells and wells proposed ludo a description of each ww°elPs. use (awttter supply, monitoring, etc), total depth, screened or open 1, ttrtd well construction or abandonment record, if available. scaled, site specili maps. Area map based on the most recent i.JSGS 7.5' topographie map ofthe area, at a scale of 1a:4,i'l it and showing the location of the proposed injection site. Site map including: a. all property boundaries; b. all buildings within the property boundary, c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater col treatment or disposal systems within !/1 mile ofthe injection w e. all surface water bodies within °4 mile of the injection well or w f. all existing or abandoned wells within !bi mile ofthc injection well(,) wwkhiclt pettet ate the pro tc, including, but not limited to, monitoring wells and wells proposed for use as in () Pot.entiometr`ic surface inap(s) including: a, direction of groundwater movement b. existing and proposed monitoring wells c, exxisting tend proposed injection Wells (4) Contaminant plunge rnap(s) including. a, the horizontal extent of the contaminant plume, includin b, existing and proposed monitoring ww°t 91s c. existing and proposed injection Cross-section(s) to the known or projected depth of eorrt trnirtaliort, inc ding: a. horizontal and vertical extent of the contaminant plain°, inc,lttelirtg isocortc b. major changes in lithology c. existing and proposed monitoring 'yells d. existing and proposed injection ww'cl.ls 'entration lines. ding waste storage, lines ed Revised 6i09 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELLS) FOR INJECTION Type 51 Wells — In Situ Groundwater Remediation / Type 5T Welts — Tracer injec,tioiti VI. CERTIFICATION (to be signed as required below or by that person authorized agen NCAC 15A 2C .0211(b) requires that all permit applications shall be signed as folic ii' R - 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specif cations and conditions of the Permit, Printed Na ne nd Title* Si Date: VII. CONSENT +PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" means any person who holds the fee real property and its construction on land shall contrary agreement in writing.) other property rights in the well being constructed. A well is deemed to vest ownership in the land owner, in the absence of As owner of the property on which the injection well(s) are to be canstru.cted and operated, l hereby co. allow the applicant to construct each injection well as outlined in this application and agree that it shall responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200). Printed Name and Title: Signature: Date: Submit TWO copies of the completed application package, including all attachtents, to: UIC Program Aquifer Protection. Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 Revised 6/09 UIC-5I/5T Page 8 of 8 ARCADI S Infrastructure Water E,t virc rrrnccn ExxonMobil Environmental Services Corporation Attachment to the Application for Permit to Use Wells for Injection Former ExxonMobil Facility #42094 3721 Freedom Drive Charlotte, North Carolina Groundwater Incident #6867 Februa2012 Imagine the result ARCADIS Pau Goodell, CES Envi +nmenta.l Scie Pro oRt t3ol Senior Env Attachment to the Application for Permit to Use Wells for Injection Prepared Farr ExxonMobil Corporation ExxonMobil EnvironmentalServices Ms. Jewel Cox - Progect. Manager 1016 W. Poplar Avenue Suite 106 #232 Collierville, Tennessee 38017 Prepared ty. ARCADIS G&M of North Carolina„ inc, 801 Corporate Center Drive Suite 301 Raleigh, North Carolina 27607 Tel 919.854.1 282 Fax 919,854,5448 E nvironmerrtal ©ur let: B0085851.0026 Cale: February 22, 2012 This € ocunment is intended' only for the use of the indivldual or entity for which it was prepared and may contain information that is privileged confidential and exempt from disclosure under applicable law. My dissemination. distribution o- dying of this document is strictly prohibited. ARCADIS LIST OF ACROYMS ARCADIS ARCADIS, Inc. bgs below ground surface BTEX Benzene, Toluene, Ethytbenzene, and Xylenes (total) DCE Dichloroethene DO Dissolved Oxygen DRO diesel range organics ERD Enhanced Reductive Dechiorination GIS geological information system GRO gasoline range organics IDW Investigative Derived Waste ISCO In -Situ Chemical Oxidation MCLGs Maximum Contaminant Level Goals MCLs Maximum Contaminant Levels MDL Maximum Detection Limit Mg/kg milligrams per kilogram MgJL milligrams per liter MNA Monitored Natural Attenuation MSCC Maximum Soil Contaminant Concentration NAPL Non -Aqueous Phase Liquid NCDENR North Carolina Department of Environment and Natural Resources O&M Operations and Maintenance ORP Oxidation Reduction Potential PCE tetrachloroethene PID photo -ionization detector ppm parts per millions SVOC Semi -Volatile Organic Compound TCE trichl©roethene TCLP Toxicity Characteristic Leaching Procedure TPH total petroleum hydrocarbons TOC Total Organic Carbon pglkg micrograms per kilogram pg/L micrograms per liter USEP'A U.S. Environmental Protection Agency VOCs Volatile Organic Compounds Attachment to the Application for Permit Use Wells for Injection ARCADIS SITE INFORMATION SECTION n 1. Site tdentifigat n Date of Report: Facility ID: _mM Site Risk: Land Use Classification: Site Name: Site Street Address: City/Town: Attachment to the Application for Permit to Use Wells for Injection 1NFORi A February 22, 2012 Former ExxonMobil #42094 1 UST Incident Number: 6867 I Intermediate Site Rank: Not Available T ` Unknown Former ExxonMobil #42094 3721 Freedom Drive Charlotte Zip Code:: = 28208 County: 1 Mecklenburg Description of Geographical Data : Former UST and dispense Point: t parking lot, Location Method: I Map Latitude/Longitude I 14" 57" / 80° 53' 53" Iocated under current property's asphalt Section 2: information About Contacts Associated with the Leaking UST Sys UST Owner: ExxonMobil Environmental 38017 UST Operator: ExxonMobil Corporation Phone: 901.850.9009 Services Corporation, 1016 W. Poplar Avenue, Suite 106 #232, Collierville, TN Former ExxonMobil #42094 Phone: Unavailable Former ExxonMobil #42094, 3721 Freedom Drive, Charlotte, NC 28208 Property Owner: Robert Morrjs ._-PI7one: 704.399.2090 5804 Sharon Road, Unit J, Charlotte, NC 28210 Property Occupant: Retail Vehicle Repair Shop..__, N _ Phone: 3721 Freedom Drive, Charlotte, NC 28210 Consultant .�.__...__ ARCADIS G&M of North Carolina Phone: 919.854,1282 801 Corporate Center Drive, Suite 301, Raleigh, North Carolina 27607 Analytical � �.... Laboratory: Test America Laboratories, Inc. Phone: 800.765.0980 Certification Number: NC DWQ: 269, NC DHHS: 13701 Section 3 Inform Date Discovered: Quantity of Release: Cause of Release: Source of Release: Size/Content of UST: ut Release November 1990 Unknown Unknown Former gasoline UST system 1 6,000G Unleaded Gasoline, 2 4,000 Gallon Unleaded Gasoline, 4,000G used oil UST and 1 550G heating oil UST Criteria Used to Classify Release: Source Concentrations and Site conditions is ARCAD1S Table of Contents LIST OF ACRONYMS SITE INFORMATION SECTION 1.0 Introduction It 2.0 Site istory 2 3.0 Hyrogeologic Description 3.1 Regional Geology and Hydrogeotogy 3,2 Site Geology and Hydrogeology 4.0 Injection Fluid Composition 3 4 4 4 5.0 Injection Rational 5 6.0 Injection Procedures and Equipment 5 7.0 Monitoring Plan 6 8,0 References 8 Tablas Table 1 Monitoring Well Construction Data Table 2 Groundwater Gauging Data Table 3 Groundwater Analytical Data Figures Figure 1 Site Location Map Figure 2 Site Map Figure 3 Potentiornetric Surface Map . October 6, 2011 Figure 4 Groundwater Analytical Map - October 6, 2011 Figure 5 Proposed Surfactant Application Locations Figure 6 Proposed Injection Well Locations Figure 7 Typical Injection Well Construction Diagram Figure 8A Cross Section Location Map Attachment to the Application for Permit to Use Wells for Injection ARCAD1S Figure 8B Cross Section A - A' Figure 8C Cross Section B - B" Appendix A Biosolve® Surfactant MSDS B Biosolve® Surfactant Data Sheet Attachment to the Application for Permit to Use Wells for Injection ARCADIS 1.0 Introduction ARCADIS G&M of North Carolina (ARCADIS) has prepared this Attachment to the Application for Permit to Use Wells for Injection on ExxonMobil Environmental Services (EMES) for the former ExxonMobil Facility #42094 located in Charlotte, Mecklenburg County, North Carolina. The purpose of this attachment is to provide additional site data and remedial system details to facilitate evaluation of the proposed injection plan. This attachment is organized into the following sections: Section 1, Introduction discusses the purpose and organization of the attachment; Section 2, Site History - discusses the information relevant to the site history in regards to site usage, origin of contamination, and previous remedial activities; Section 3, Hydrogeologic Description - discuses the regional geologic setting, lithology, and hydraulic conductivity; Section 4, Injection Fluid Composition - describes the chemical and physical characteristics of the injectant; Section 5, Injection Rational - di ses rational for selection the injectants; Section 6, Injection Procedure and Equipment - provides a detailed description of the all planned activities related to the proposed injection; Section 7, Monitoring Plan - describes the plan for monitoring t he results of the injection: Tables Section, Well data - provides tabulation of data on all existing or abandoned wells; and Figures Section - provides supporting figures. Attachment to the Application for Permit to Use Wells for Injection ARCADIS 2.0 Site History Former ExxonMobil (Exxon) facility #42094 located at 3721 Freedom Drive, Charlotte, Mecklenburg County, North Carolina operated as a gasoline retail store and service station between 1970 and October 1990. All underground storage tanks (USTs) and ancillary equipment was closed by removal in November 1990 prior to divestment of the site by Exxon. The UST system consisted of one 6,000-gallon gasoline UST, two 4,000-gallon gasoline USTs, one 4,000-gallon used oil UST and one 550-gallon heating oil UST. The site was re -developed as a vehicle repair facility between 1993 and 2001. Petroleum -affected soil was discovered during the November 1990 UST closure at the base of the gasoline UST field and below one dispenser island. The cause and quantity of the release is unknown. A soil -vapor extraction (SVE) system utilizing two extraction wells operated intermittently at the site between August 1992 and July 1996. Additional soil samples were collected by Environmental Resources Management Inc. (ERM) in the vicinity of the former gasoline UST field, eastern dispenser island and former used oil UST in 2001 and 2002. Petroleum affected soil has been documented beneath the former gasoline UST and dispenser island. Concentrations of 19 volatile organic compounds (VOCs) above soil -to -ground water Maximum Soil Concentrations (MSCCs), but below the applicable industrial/commercial MSCCs, were detected in 2001 and 2002 soil samples, Four VOCs (benzene, naphthalene, C5-C8 Aliphatics and C9-C12 Aromatics) were detected in concentrations above the residential MSCCs. The bulk of petroleum -affected soil is located between 11 and 15 feet below ground surface in the capillary fringe above the water table. The petroleum -affected soil within the capillary fringe, in areas away from the former UST field and dispenser island, is attributed to the migration of petroleum -affected ground water beneath the site, The smear zone left by the petroleum -affected ground water across the capillary fringe is suspected to be the source of the petroleum -affected soils at depths across much of the site. The site is owned by Mr. Robert Morris and currently operates as a vehicle repair facility. The area surrounding the site is composed of commercially developed properties, mixed -use properties and residential properties. The nearest single-family residence is located approximately 130 feet west of the source area. ERM conducted a water supply well survey for the site in February 2001. Five inactive water supply wells have been identified within a 1,500-foot radius of the site. All wells are located Attachment to the Application for Permit Use Wells for Injection 2 ARCADIS northwest and topographically upgradient of the subject property. The nearest well is located approximately 1,350 feet from the source area. Municipal water service provided by the Charlotte -Mecklenburg Utilities Department is available to all properties in the surrounding area. No surface water bodies have been identified within 500 feet of the site. The site is located within the Charlotte geologic belt of the Piedmont physiographic province and is underlain by saprolite, a layer of weathered and variably decomposed bedrock. Soils at the site consist primarily of silt and clay based on soil boring logs for site monitoring wells and direct push soil borings. Saprohitic soil was encountered in all borings at depths greater than 10 feet below ground surface (bgs). Imported fill soil consisting of semi -plastic clay with gravels was observed over much of the site. Partially weathered bedrock was encountered in soil borings at 22 feet and 55 feet below ground surface. Depth to groundwater at the site, on average, ranges from 11 to 28 feet bgs. The North Carolina Department of Environment and Natural Resources (NCDENR) Risk Classification for the site is Intermediate" due to the presence of free product and exceedances of the groundwater Gross Contamination Levels (GCLs) for benzene, naphthalene, C5-C8 aliphatics and C9-C12 aromatics. A site Iocation map is presented in Figure 1 and a site map is shown as Figure 2. 3.0 Hydrogeologic Description Site topography is relatively flat with minimal topographic relief. Drinking water in the area is provided by the Charlotte -Mecklenburg Utility Department (CMUD) which is located approximately 15 miles northeast of the site. The source of CMUD drinking water, Mountain Island Lake Reservoir, is not hydraulically connected to the site. Well construction data is presented in Table 1. Current and historical groundwater elevations measured in the site monitoring wells are presented on Table 2. A potentiometric surface map is provided as Figure 3. Historical groundwater elevation data obtained during previous groundwater gauging events indicate the shallow groundwater flows generally to the southeast with a horizontal gradient of approximately 0.01 feet per year (ERM, 2002). Cross section maps of the site are presented as Figures 8A — 8C. Attachment to the Application for Permit to Use Wells for Injection ARCAD1S Analytical data from groundwater collected in site monitoring wells from December 1990 to October 2011 is presented in Table 3. The data from the most recent sampling events is presented in Figure 4. Analytical data from groundwater collected in site monitoring wells from 1990 to February 2011 is presented in Table 3. A dissolved -phase analytical map from the most recent groundwater sampling event on May 17, 2011 is presented as Figure 4. 3.1 Regional Geology and Hydrogeology Former ExxonMobil facility #42094 in Charlotte is located in the Piedmont physiographic province of North Carolina. The site lies within the upland section of the Piedmont province which is characterized by rolling hills. The site lies at an elevation of about 790 feet above mean sea level. Saprolite, a zone of weathered and variably decomposed bedrock, commonly mantles bedrock in this region. Saprolite has the appearance of compact clayey to sandy soil with the original bedrock textures and features preserved. Saprolite is created through the chemical weathering of bedrock over a long period of time in areas of limited erosion. The city of Charlotte is underlain by granitic plutons and metamorphic volcanic sediments within the Charlotte geologic belt according to the Geologic Map of North Carolina (1985) and Goldsmith, et. al. (1988), 3.2 Site Geology and Hydrogeology Native soils at the site consist primarily of silt and clay based on soil boring logs. Saprolitic soil was encountered at depths greater than 10 feet. Imported fill soils consisting of semi -plastic sandy clay with gravels were observed over much of the site. The sill soil did not extend greater than 10 feet below ground surface (bgs). Partially weathered bedrock was encountered in borings for wells MW-7 and DW-1 at depths of 18 and 47 feet bgs, respectively. Competent bedrock was encountered in these two borings at 22 feet bgs and 55 feet bgs, respectively. 4.0 Injection Fluid Composition The proposed injection fluid will be composed of potable water from the CMUD, mixed with Biosolve® Surfactant, a NCDENR approved injectant, to a maximum concentration of 6% volume of surfactant/volume of water. A Material Data Safety Attachment to the Application for Permit to Use Wells for Injection 4 ARCAD1S Sheet (MSDS) and Product Description for Biosolve® Surfactant are included as Appendices A and B. 5.0 Injection Rational The goal of the planned remediation injections is to eliminate periodic free product and concentrations of dissolved -phase chemicals of concern (COC) at monitoring wells MW-5 and MW-9 to below the applicable North Carolina Gross Contaminant Levels (GCLs). The surfactant application will not likely achieve all groundwater standards immediately, but the intent is to significantly reduce concentrations to levels that will allow natural attenuation to achieve groundwater standards on a reasonable timeframe, Under the proposed approach, active remediation would be conducted via in -situ injection of surfactant to the target monitoring and injection wells, A non-ionic or anionic surfactant reagent that is readily biodegradable in the subsurface will be applied directly to the target monitoring and proposed injection wells (MW-5, MW-9, INJ-1, and INJ-2). The surfactant will be applied as an aqueous solution not exceeding 6 percent (v/v). A potable water flush will then be applied to the target monitoring and injection wells. Injection volumes per well for the proposed events were estimated by multiplying the vertical height of the well screen or target interval by the radial surface area required to achieve complete distribution within the treatment area. This value was converted from cubic feet to gallons and then multiplied by the anticipated porosity of the subsurface that will accept fluid during the injection (the mobile porosity). Based on ARCADIS' experience, mobile porosities are less than 10% at sites with similar iithologies to that observed at former ExxonMobil Facility #42094, Therefore the anticipated injection volume per wells = 10 ft X 3.14 (rr) x (5 ft x 5 ft) x 10% x 7,481 gal.cg — maximum of 2,400 gallons, 6.0 Injection Procedure and Equipment The proposed surfactant application locations (MW-5, MW-9, INJ-1 and INJ-2) are presented as Figure 5. Approximately 2,400 gallons of the surfactant solution will be delivered in total to the two existing monitoring wells (MW-5 and MW-9) and two proposed injection wells (INJ-1 and INJ-2). During the surfactant application event, field crews will mobilize to the site to set up and stage the required above -ground equipment. Tanks, manifolds, and the pump will be configured to allow injection in all four wells simultaneously. Flow will be regulated by adjusting the noted valves and Attachment to the Application for Permit to Use Wells for Injection ARCADIS pumping rates and caution will be taken to ensure that wellhead pressures are kept below 5 psi, Based on the total estimated volume per well (600 gallons) and the anticipated injection rate (1.0 gpm), each injection event will take approximately one day to complete. The injection schedule will consist of an initial injection event which would occur within approximately one to two months of approval of the UIC permit. The initial injection event would occur over approximately one day and would be followed within 48 hours by a one -day aggressive fluid vapor recovery (AFVR) event. The AFVR event will take place over one day, and will operate for an estimated eight continuous hours. However, the duration of the AFVR event will be adjusted to achieve target recovery volumes. The one day AFVR will be conducted on monitoring and injection wells MW- 5, MW-9, INJ-1, and INJ-2 to push/pull the surfactant/potable water mixture through the subsurface to degrade free product and recover dissolved -phase CDC concentrations exceeding the applicable North Carolina GCL standards. Groundwater recovery will be monitored to ensure recovery of at least two times the injected volumes. Following each event, recovered petroleum impacted groundwater will be disposed of properly at the EMES-approved HAZ-MAT Environmental Services (HAZ-MAT) facility located at 210 Dalton Avenue, Charlotte, Mecklenburg County, North Carolina. Following the Biosolve® surfactant application and one day 8-hour AFVR event, ARCADIS will conduct a comprehensive groundwater sampling event of monitoring wells MW-5 and MW-9. Based on the evaluation of the data gathered during the groundwater monitoring event, a potential second injection event may be conducted. Timing of the potential second injection event would take place approximately six months after the completion of the first injection event, 7.0 Monitoring Plan Following the completion of the surfactant application and the one -day AFVR event, ARCADIS will gauge all monitoring wells associated with the site (MW-5, MW-6, MW-7, MW-8, MW-9, and DW-1) and sample monitoring wells MW-5, MW-7, and MW-9 to determine the effectiveness of the in -situ surfactant application and one -day AFVR event. All groundwater samples collected from monitoring wells MW-5 , MW-7, and MW-9 will be placed in laboratory -supplied containers and shipped to TestAmerica, Inc. in Nashville, Tennessee for laboratory analysis, In accordance with Table 5 - Approved Methods for Groundwater Analyses at Petroleum UST Release Investigations of the North Carolina Guidelines for Assessment and Corrective Action for Underground Storage Tank (UST) Releases, July 15, 2008 edition, groundwater Attachment to the Application for Permit to Use Wells for Injection 6 ARCADIS samples will be submitted for analysis of Volatile Organic Compounds (V©Cs) by Standard Method (SM) 62006. If warranted based on evaluation of the monitoring data, an additional injection event may be conducted approximately six months after completion of the first injection event. The second injection and subsequent monitoring events would be conducted in a similar manner to the first injection. Pending evaluation of data from the second injection event, a third injection may be necessary. Attachment to the Application for Permit to Use Wells for Injection 7 AR ADI5 8,0 References BBL, 2003, System Enhancement Recommendation Report. Brown, P.M. Geologic Map of North Carolina. North Carolina Department of Natural Resources and Community Development. Raleigh, North Carolina ERM-Southeast (ERM). 2002. Comprehensive Site Assessment Report. Exxon Retail Location #4-2094. 3721 Freedom Drive, Charlotte, North Carolina, November 7. ERMSoutheast (ERM). 2002. Limited Site Assessment Report, Exxon Retail Location #4-2094. 3721 Freedom Drive, Charlotte, North Carolina, April 3. Goldsmith, R., et al. Geologic Map of the Charlotte 1' x 2" Quadrangle, North and South Carolina. U.S.G.S 1-1251-E. NCDENR — Division of Waste Management, UST Section. Guidelines for Assessment and Corrective Action for UST Releases, July 15, 2008 version, December 1, 2008. Attachment to the Application for Permit to Use Wells for Injection ARCAD Tables Table 9: Monitoring Well Construction Data Revision Date: 2/28/2012 Incident Number: 6867 Facility ID #: Former ExxonMobil #42094 Well Designation Well Diameter (inches) Screen Interval (ft-bgs) Total Depth (ft-bgs) Top of Casing Elevation (ft-msl) Well Use MW-5 4 15-35 35 96.52 MonitoringlAFVR Monitoring MW-6 2 15-40 _ 40 105.17 MW-7 2 15-30 30 91.33 Monitoring MW-8 2 14-24 , 24 92.59 Monitoring MW-9 2 17-32 32 98.47 Monitoring DW-1 2 70-80 80 96.32 Monitoring Notes: ft-bgs = Feet below ground surface. ft-btoc = Feet below top of casing. ft-msl = Feet above mean sea level. 1 of 1 Table 2: Groundwater Gauging Data Revision Date: 2128/2012 Incident Number: 6867 Facility I.D. # Former ExxonMobil Facility #42094 Monitoring Well1.D. Date Installed Gauging Dale Total Casing Depth (ft bgs) Screened interval (ft bgs) Top of Casing Elevation (ft) Depth to Water (ft BTOC) Depth to Product (ft BTOC) Product Thickness (ft) Ground Water Elevation (ft ASL) Measured Depth to Bottom (ft) Well Diameter MW-1 1l711991 1/8/1991 10.00 10-25 94.14 14.42 - - 79.72 25.00 2' 1996 Well Abandoned / Destroyed MIN-2 117l1991 1/8/1991 10.00 10-25 92.85 12.77 -- - 80.08 25.00 2' 1996 Well Abandoned 1 Destroyed MW-2R 2/13/2001 2/14/2001 13.00 13-28 - 19.74 - - - - 1" 6/6/2001 - 18.03 - - - - 1' 10/12/2001 -- 21.15 21.11 0.04 - - 1' 11/6/2001 - 21.40 21.37 0.03 - - 1' 12/4/2001 - 21.81 21.80 0.01 - -- 1' 1/10/2002 - 21.62 21.59 0.03 - - 1' Well abandoned and replaced by MW-5 In January 2002 MW-3 1/7/1991 1/8/1991 5 5-20 1 91.74 11.43 - - 80.31 20.00 2' 1996 Well Abandoned / Destroyed MW-4 1/7/1991 1/8/1991 10 I 10-25 I 97.02 I 15.50 [ - - 81.52 I 25.00 I 2" 1996 Well Abandoned / Destroyed MW-5 1/16/2002 1/23/2002 15.00 15-35 96.52 21.10 20.75 0.35 75.68 - 4' 2/5/2002 96.52 20.30 19.95 0.35 76.48 - 4' 3/19/2002 96.52 19.50 19.35 0.15 77.13 - 4' 4/13/2002 96.52 19.08 18.70 0.38 77.72 - 4" 5/10/2002 96.52 19.13 19.12 0.01 77.40 - 4' 6/27/2002 96.52 21.94 20.22 1.72 75.85 - 4' 7/25/2002 96.52 22.79 21.11 1.68 74.97 - 4' 8/15/2002 96.52 23.32 21.58 1.74 74.49 - 4" 9/16/2002 96.52 23.26 21.55 1.71 74.53 - 4' 10/4/2002 96.52 23.30 21.52 1.78 74.54 - 4" 11/25/2002 96.52 21.16 19.05 2.11 76.92 - 4' 12/23/2002 96.52 19.70 18.75 0.95 77.52 - 4° 1/16/2003 96.52 18.6E 18.30 0.38 78.12 - 4' 2/19/2003 96.52 17.91 17.85 0.06 78.65 - 4' 3/19/2003 96.52 19.72 19.63 0.09 76.87 - 4" 4/22/2003 96.52 13.96 13.95 0.01 82.57 - 4" 5/30/2003 96.52 12.64 12.63 0.01 83.89 - 4" 6/27/2003 96.52 12.37 T - - 84.15 - 4' 7/15/2003 96.52 12.36 12.35 0.01 84.17 -- 4' 8/11/2003 96.52 12.44 12.43 0.01 84.09 - 4' 9/2/2003 96.52 12.39 12.38 0.01 84.14 - 4' 11/22/2004 96.52 17.16 - - 79.36 - 4" 11/4/2005 96.52 20.99 - - 75.53 - 4' 10/5/2006 96.52 17.43 - - 79.09 - 4' 6/12/2007 96.52 16.35 - - 80.17 - 4' 6/19/2008 96.52 19.61 - - 76.91 35.67 4' 4/28/2009 96.52 17.21 16.91 0.30 79.53 35.67 4" 12/3/2009 96.52 18.40 18.35 0.05 78.16 - 4' 3/28/2010 96.52 14.81 -- - 81.71 - 4" 4/2/2010 96.52 23.75 - - 72.77 - 4" 4/28/2010 96.52 15.57 - - 80.95 - 4' 6/28/2010 96.52 17.09 - - 79.43 - 4' 7/2/2010 96.52 21.59 -- - 74.93 - 4' 10/21/2010 96.52 20.22 - - 76.30 35.63 4" 5/17/2011 96.52 18.29 18.03 0.26 78.42 - 4" 6/9/2011 96.52 18.53 18.27 0.26 78.18 35.63 4" 8/24/2011 96.52 20.40 20.38 0.02 76.13 - 4" 9/19/2011 96.52 21.16 21.11 0.05 75.40 - 4' 10/6/2011 96.52 20.66 - - 75.86 - 4" 10/12/2011 96.52 20.90 - - 75.62 - 4" MW-6 1/16/2002 2/5/2002 15.00 15-40 105.17 28.24 - - 76.93 - 2" 10/5/2006 105.17 24.33 - - 80.84 - 2' 6/12/2007 105.17 22.94 - - 82.23 - 2" 412B/2009 105.17 25.52 - - 79.65 40.00 2' 12/3/2009 105.17 25.64 - - 79.53 40.00 2" 4/28/2010 105.17 22.63 - - 82.54 - 2' 10/21/2010 105.17 24.61 - - 80.56 40.00 2' 5/17/2011 105.17 26.22 - - 78.95 40.03 2' 10/6/2011 105.17 27.97 - - 77.20 - 2' Page 1 of 2 Table 2: Groundwater Gauging Data Revision Date: 2128/2012 Incident Number. 6867 Facility I.D. # Former ExxonMobll Facility #42094 Monitoring Well I.D. Date Installed Gauging Date Total Casing Depth (ft bgs) Screened interval {ft bgs) Top of Casing Elevation (ft) Depth to Water (ft BTOC) Depth to Product (ft BTOC) Product Thickness (ft) Ground Water Elevation (ft ASL) Measured Depth 10 Bottom (ft) Well Diameter MW-7 1/17/2002 2/5/2002 - 15.00 15-30 91.33 16.41 - - 74.92 - 2" 11/22/2004 91.33 13.89 - - 77.44 - 2' 10/5/2006 91.33 13.77 - - 77.56 - 2" 6/1212007 91.33 13.10 - - 78.23 - 2" 6/19/2008 91.33 15.33 - - 76.00 29.88 2" 4/28/2009 91.33 13.32 - - 78.01 30.02 2" 12/3/2009 91.33 14.44 - - 76.89 30.00 2' 4/28/2010 91.33 12.13 - - 79.20 - 2' 10/21/2010 91.33 20.07 - - 71.26 31.01 2" 5/17/2011 91.33 14.57 - -- 76.76 30.01 2' 10/6/2011 91.33 16.18 - - 75.15 - 2' MW-8 1/17/2002 2/5/2002 14.00 14.24 92.59 16.98 - - 75.61 - 2' 11/22/2004 92.59 12.59 - - 80.00 - 2' 10/5/2006 92.59 13.86 - - 78.73 - 2' 6/12/2007 92.59 12.81 - - 79.78 - 2' 6/19/2008 92.59 16.16 - - 76.43 23.84 2' 4128/2009 92.59 13.52 - - 79.07 23.97 2' 12/3/2009 92.59 14.97 - - 77.62 24.00 2' 4/28/2010 92.59 12.16 - - 80.43 - 2' 10/21/2010 92.59 20.11 - - 72.48 23.97 2' 5/17/2011 92.59 14.04 - - 78.55 23.98 2' 10/6/2011 92.59 17.11 - - 75.48 - 2' MW-9 6/12/2002 9/16/2002 17.00 17-32 98.47 23.91 23.62 0.29 74.77 32.00 2' 10/4/2002 98.47 23.75 23.49 0.26 74.91 - 2' 11/25/2002 98.47 21.19 - - 77.28 - 2' 12/23/2002 98.47 20.60 - - 77.87 - 2' 1/16/2003 98.47 20.03 - - 78.44 - 2' 2/19/2003 98.47 19.46 -- - 79.01 - 2' 3/19/2003 98.47 19.03 18.72 _ 0.31 79.67 - 2' 4/22/2003 98.47 15.73 15.71 0.02 82.75 - 2' 5/30/2003 98.47 14.65 14.64 0.01 83.83 - 2" 6/27/2003 98.47 14.18 - - 84.29 - 2" 7/15/2003 98.47 14.11 - - 84.36 - 2' 8/11/2003 98.47 14.10 - - 84.37 - 2' 9/2/2003 98.47 14.00 - - _ 84.47 - 2' 11/22/2004 98.47 18.88 - - 79.59 - 2' 11/4/2005 98.47 20.90 - - 77.57 - 2' 10/5/2006 98.47 19.19 - - 79.28 - 2" 6/12/2007 98.47 18.00 -- - 80.47 - 2" 6/19/2008 98.47 21.24 - - 77.23 31.81 2" 4128/2009 98.47 19.66 18.60 1.06 79.59 - 2' 12/3/2009 98.47 20.22 20.20 0.02 78.26 - 2' 3/28/2010 98.47 15.53 -- - 82.94 - 2' 4/2/2010 98.47 21.10 - - 77.37 - 2' 4/28/2010 98.47 17.27 - - 81.20 - 2' 6/28/2010 98.47 18.81 - - 79.66 - 2' 7/2/2010 98.47 20.92 - - 77.55 - 2' 10/21/2010 98.47 21.73 - -- 76.74 32.02 2' 5/17/2011 98.47 19.88 - - 78.59 31.95 2' 10/6/2011 98.47 22.73 22.00 0.73 76.27 - 2' 10/12/2011 98.47 22.74 22.21 0.53 76.12 - 2' DW-1 111812002 2/5/2002 65.00 70-79 96.32 20.60 - - 75.72 - 2' 10/5/2006 96.32 17.49 - - 78.83 - 2' 6/12/2007 96.32 16.55 - - 79.77 - 2' 6/19/2008 96.32 19.35 - - 76.97 80.27 2' 4/28/2009 96.32 17.40 - - 78.92 81.60 2' 12/3/200996.32 18.36 - - 77.96 80.25 2" 4/28/2010 96.32 15.62 - - 80.70 - 2" 10/21/2010 96.32 19.43 - - 76.89 80.49 2' 5/17/2011 96.32 18.04 - - 78.28 80.31 2" 10/6/2011 96.32 20.48 - - 75.84 - 2" Notes: BTOC = Below top of well casing -= Not measured or not available ft=feet ft ASL = feet below arbitrary site level bgs = below ground surface Groundwater elevation corrected for the presence of free product using the formula: Top of Casing Elevation - (Depth to Water - (Product Thickness x 0.73)) Page 2 of 2 Table 3: Groundwater Analytical Data Revision Date: 2/28/2012 Incident Number: 6867 Facility ID #: Former ExxonMobil Facility #42094 Methods-> MADEP VPHIEPH ({rg/L) Volatile Organic Compounds by SM6200 B (historical data used 602/6230D) (pg1L)' 504.116200' 3030C Contaminate of Concern-> YS m .+ O. Bch V C9-C12 Aliphatics (Unadjusted) C9-C10 Aromatics Total BTEX Benzene ' Ethylbenzene Total xylenes W w uuo}osolt{D CD m a' o Q 1,1-Dichloroethene cis-1,2-D i c h10 roeth en e m c 0 rg� L' o r 0 �° 1,2-Dichloropropane m act c m OD c m n-Propylbenzene Isopropylbenzene c a) o �, _ & Naphthalene Trichloroethene Tetrachioroethylene Styrene 1,3,5-Trimethytbenzene ' 1,2,4-Trimethylbenzene Bromoethane Ethanol o 'o j °° w al -J Well ID Date GCLs-> NE NE NE NE 5,000 260,000 84,500 85,500 20,000 70,000 70,000 400 7,000 70,000 100,000 600 6,900 8,500 30,000 ' 25,000 NE 6,000 3,000 700 70.000 25,000 28,500 NE NE 30 50 15.000 MW-1 12/1/1990 - - - 564 509 6 2 47 18 193 - ND - 13 - - - - - - - - ND ND - - - - -- - ND -- 2/1/1991 - - - 1,654 1,500 36 ND 118 ND 1.800 - - - - - - - - - - - - ND - - - - - - - - - 5/111991 - - - 649 590 16 ND 43 44 410 - - - - - - - - - - - - ND - - - - - - - - - 811/1991 - - - 849 830 7 2 10 ND 300 - - - - - - - - - - - - ND - - - - - - - - - 10/1/1991 - - - 702 630 25 8 39 4 180 - - - - - - - - - - - - ND - - - - - - - - - 111/1992 - - - 492 440 18 7 29 55 200 - - - - - - - - - - - - ND - - - - - - - - - 10/111992 - - - 106 86 9 2.7 8.2 11 170 - - - - - - - - - - - - ND - - - - - - - - - 311/1993 -- - � -- 236 170 16 13 37 16 190 - - - - - - - _ - - - - - ND - - - - - - - - - Well Abandoned/Destroyed MW-2 12/1/1990 _ - - - 13.720 6,355 2,083 1,206 4,076 757 1,377 - - - - - - - - - _ - - - ND - - - - - - - - - 2)111991 - - - 71,500 29,000 30,000 2,000 10,500 ND 4,700 - - - - - - - - - - - - ND - - - - - - - - - 5/1/1991 - - - 76,000 32,000 31,000 2,200 10,800 ND 4,700 - - - - -- - - - - - - - ND - - - - - - - - - 81111991 - - - 66.700 28,000 27,000 1,800 9,900 ND 5,000 - - - - - - - - - - -- - ND - - - - - - - - - 10/111991 - - - 69,300 28,000 29.000 2,000 10,300 ND 4,100 - - 1 - - - - -- - - - - - ND - - - - - - - - - 31111993 - - - 51,400 21,00D 21,000 1,400 8,000 ND 3,000 - - - - - - - - - - - - ND - - - - - - - - - 311/1994 - - - 43,040 17,00D 17,300 1,280 7,460 ND 3,680 - - - - - - - - - - - - ND - - - - - - - - - 1/1/1995 - - - 114,800 53,60D 43,200 2,700 15,300 ND - - 1,200 - NO -- - - - - - - - ND ND - - - - - - 700 - 2/6/1996 - - - 139,500 27,400 43,200 10,100 58,800 ND 7,480 - 600 - 400 - - - - - - - - ND 880 - - - - - - ND - 11/511997 - - - 20,150 2,950 2,480 1,690 13,030 5,000 ND - ND - ND .. - - - - - - - ND ND - - - - -- - ND - Well Abandoned/Destroyed MW-2R 2114/2001 ND ND ND 1101,900 45,400 37,900 2,000 16,600 ND 13,800 - 1,550 1 - ND L - - - - - - f - - 1 ND I ND I - - - - - - I 550 I 83 Well abandoned and replaced by MW-5 in Janu,y 2002 MW-3 121111990 - - - 3 ND ND ND 3 ND ND - - - - - - - - - - - - ND - - - - - - - - - 2/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 511/1991 - - - 13 5 6 ND 2 ND ND - - - - - - - - - - - - ND - - - - - - - - -- 811/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 11111992 - - - ND _ ND ND NO ND ND ND - - - - - - - - - - - - ND -- - - - - - - - - 10/1/1992 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 311/1993 - - - ND ND ND ND ND ND ND - - - - - - - - - - - _ ND - - - - - - - - 2/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 5/1/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 811/1991 - - - ND ND ND ND ND ND ND - - - - - - - - - - -- - ND - - - -- - - - - -- 10/1/1991 - -. - 40 17 15 2 6 ND ND - - - -- - - - - - - - - ND - - - - - - - - - 111/1992 - - - ND ND ND ND ND ND ND - - - - - - - - - - - - ND - - - - - - - - - 10/1/1992 - - - ND ND ND NO ND ND ND - - - - - - - - - - - - ND - - - - - - - - .- 31111993 - - - ND ND ND ND ND ND ND -- - - - - - - - - - - - ND - - - - - - - - - Well AbandonedlDestroyed MW-4 12/1/1990 - - - L 3 ND ND ND 3 ND ND - - - ND - - - - I - Well Abandoned/Destroyed MW-5 1/23/2002 102,000 15,900 ND 60,940 33,200 18,700 1.240 7,800 680 8,910 ND 2,390 - ND ND 1.7 -- - - - - - 2.2 5.8 - -- - 2.1 - - 260 122 6/19/2008 - - - 81,390 34,00D 28,700 2,390 16,300 311 7,020 - - - - - - - - - - - - - - - - - - - - -- 4/2812010 - - - 68,750 31,10D 24,100 1,750 11,800 302 6,360 - - - - -- - - - - - - - - - - - - - -- - - - 10121/2010 - - - 64,610 25,800 25,100 1,610 12,100 210 5,400 - - - - - - - - - - - - - - . - - - - - - - - 1016I2011 - - - 64,110 31,800 20.800 2,240 9,270 114 5,850 <0.500 1.710 <0.500 276 0.950 <0.500 55.0 8.23 185 61.9 6.66 947 8.96 6.33 402 490 1,750 <0.500 398 3.03 136 - MW-6 1/23/2002 ND ND ND ND ND ND ND ND ND ND ND ND - NO ND ND - - - - - - ND ND , - - - ND - - ND ND 121312009 - - - ND <1.00 <1.00 <1.00 <3.00 <1.00 <1.00 - - - - - - - - - - - - - - - - - - -- - - 5/17/2011 - . - - ND <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 <0.500 <0.500 <0.500 <0.500 <0.500 - - - <0.500 - MW-7 1/23/2002 1,880 ND ND 42 40.3 1.7 ND ND 12.4 114 8.7 3.3 - 170 5.5 ND - - - - - - 940 5,760 - - - ND - - ND 7 12/3/2009 - - - 37.96 31 <1.00 <1.00 6.96 3.34 <1.00 - - - - - - - - - - - - - - - - - - - - - - 5/17/2011 - - - 7.39 7.39 <0.500 <0.500 <1.00 0.72 19.0 0.84 3.5 0.5 204 3.44 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 571 2,299 . <0.500 <0.500 <0.500 - - - <0.500 - 10/6/2011 - - - 4.86 4,86 <0.500 <0,500 <0.500 0.740 15.0 0.820 2.50 0.600 222 3.25 <0.500 <0.500 0.540 <0.500 <1.00 <0.500 <5.00 611 2,300 . <0.500 <0.500 <0.500 <0.500 <0.500 0.590 <0.500 - MW-8 1/23/2002 289 ND ND ND ND ND ND ND 1.6 85.2 2.8 ND - 78.2 ND _ ND - - - - - - 60.5 422 - - - Nb - - N❑ ND 12/3/2009 - - - ND <1.00 <1.00 <1.00 <3.00 4.84 <1.00 - - - - - - -- - - - - - - - ' - -- - - -- - - - 5/17/2011 - - - ND <0.500 <0.500 <0.500 <1.00 <0.500 <0.500 <0.500 <0.500 <0.500 11.8 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 11.7 19.8 <0.500 <0.500 <0.500 - - - <0.500 - page 1 of 2 Table 3: Groundwater Analytical Data Revision Date: 2/28/2012 Incident Number: 6867 Facility ID #: Former ExxonMobil Facility #42094 Methods-> MADEP VPH/EPH (pglL) Volatile Organic Compounds by SM6200 B (historical data used 60216230D) (pg/L)1 504.1/62002 3030C Contaminate of Concem-> C5-C8 Aliphatics (Unadjusted) C9-C12 Aliphatics (Unadjusted) C9-C10 Aromatics Total BTEX Benzene m m o 1- Ethylhenzene Total xylenes w co ~ 2 w a. P t v 1,2-Dichloroethane 1,1-Dichloroethene cls-1,2-Dichloroethene in c m .c m d N c § 1,2-Dichloropropane cNN C .0 r co.cc c sec-Butylbenzene n-Propylbenzene Isopropylbenzene m 2 - a. q a Naphthalene Trichloroetherte a) c .cID' Q O Styrene 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene Bromoethane a u! N t O U C j m w Lead (NgtL) Welt ID Date GCLs-> NE NE NE NE 5,000 260,000 84,500 85,500 20,000 70,000 70,000 400 7,000 70,000 100,000 600 6,900 8,500 30,000 25,000 NE 6,000 3,000 700 70,000 25,000 28,500 NE NE 30 50 15,000 MW-9 6/19/2008 - - - 31,520 10,400 11:400 1,340 8,380 6,140 4,380 - - - - - - - - - - - ' - - - - - - _ _ _ _ _ 4/2812010 - - - 31,390 5.420 15,300 1,470 9,200 1,020 1,790 - - - - - - - - - - - - - - - - - - - - 10/21/2010 - - - 38,720 10,300 15,800 1,520 11,100 9,060 5,500 - - -- - - - - - -- - - - - -- - - - - - - - - 5/17/2011 - - -- 50,710 12,100 20,200 2.510 15,900 4,700 3,810 <25.0 RL1 <25.0 RL1 <25.0 RL1 <25.0 RL1 <25.0 RL1 <25.0 RL1 99.5 <25.0 RL1 289 84.5 <25.0 RL1 1,030 <250 RL1 <250 RL1 525 740 2,760 - <2500 RL1 <25.0 RL1 <25.0 RL1 - DW-1 1/23/2002 1,070 ND ND 221 219 2.2 ND ND 44.3 464 1.8 167 - 2.2 ND ND - - - - - - 1.5 5.7 - - - ND - - NO ND 1213(2009 - - - ND <1.00 <1.00 <1.00 <3.00 30.7 161 - - - - - - - - - - - - - - - _ - - _ - - 5117/2011 - - - ND <0.500 <0.500 <0.500 <1.00 60.6 275 7.3 39.3 <0.500 1.43 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <0.500 <5.00 0.59 2.84 <0.500 <0.500 <0.500 <0.500 - <0.500 <0.500 - Notes: GCLs = Gross Contamination Levels NE = Not Established <# = Non -Detect below laboratory reporting limits ND = Below Detection Limits BTEX = Benzene Toluene Ethyl benzene Xylenes MTBE = Methyl tert-butyl ether IPE = Diisopropyl Ether EDB = Ethylene Dibromide BOLD = Concentration exceeds GCL standard - = Not Analyzed for specific compound 1 = Prior to May 2011 event, samples were analyzed via Environmental Protection Agency (EPA) 602 (historical data used 602/6230D), May 2011 samples were analyzed via SM6200 B. 2 = Prior to May 2011 event, samples were analyzed via EPA 504.1, May 2011 samples were analyzed via SM6200 B. RL1 = Reporting limit raised due to sample matrix effects MADEP = Massachusetts Department of Environmental Protection VPHIEPH = Volatile Petroleum Hydrocarbons / Extractable Petroteum Hydrocarbons ug/L = micrograms per liter Page 2 of 2 ARCADIS Figures EXXONMOBIL ENVIRONMENTAL SERVICES EXXONMOBIL SERVICES STATION /42094 3721 FREEDOM ©RIVE CHARLOTTE, NC SURFACTANT APPLICATION WORKPLAN » 2012 NORTH CAROLINA FORYIER REARM T ANK FORUM %%STE ok TARR FoRit.yho.C. "DWI FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET FIRMER PROPERTY BOUNDARY LEGEND MONITORING WELL ABANDONED MONITORING WELL 40' 80' RAPHIC SCALE R N FORMER EXX 3721 FREED� URFACTANT APP F*C1 fICES ,NC - 20 2 SITE MAP ARCAD1S FIGURE 2 FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREEE,P' FORMER PROPERTY a°UNOAR), 1 1 MONITORING WELL ABANDONED MONITORING WELL GROUNDWATER ELEVATION CONTOUR (DASHED 77.00--"""-- WHERE INFERRED) (76,271 GROUNDWATER ELEVATION (FEET BELOW ARBITRARY SITE LEVEL) GROUNDWATER FLOW DIRECTION NOTE: BASEMAP PREPARED FROM DRAWING FILE PREPARED BY 'GROUNDWATER AND ENVIRONMENTAL SERVICES, INC." (GES), TITLED: SITE MAP, AT A SCALE OF 1 =50., DATED; NOVEMBER 21, 2008, 0 40' 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC SURFACTANT APPLICATION WORK PLAN - 2012 POTENTIOMETRIC SURFACE MAP OCTOBER 6, 2011 ARCAD1S T FORMER CHARLIE BROWN'S DRY CLEANERS 440 MMOR STREET MAJOR STREET X TETR 0,72 18.0 0:84 2 571 7 20,800 t270 7 2 10-8-111 0„740 0; 820 811 CHI 12€3E C12D 7CE TETR O 250,000 7 0 70,000 700 SOLD EXCEEDS GCL9 GCLs « GROSS CONTAMINATION LEVELS NS NOT SAMPLED NOT ANALYZED MONITORING WELL ABANDONED MONITORING WELL E ENE TOLUENE ETI CO NE N1 T—BUTYL ETHER ROPYL ETHER ENE DIBROMIOE CHLOROFORM TETRACHLOROE ENE. NOTE. MY!-5 NOT SAMPLED ON MAY 17, 2011 DUE TO THE PRESENCE OF FREE PRODUCT 40' 80' GRAPHIC SCALE E 4+ 1NMOBR. ENVIRONMENTAL SERVIt #I R �ONMOSIL FACILITY 14209A 3721 FREEDOM DR. CHARLOTTE, NC SURFACTANT APPUUCA N WORK PLAN 2012' DISSOLVED -PHASE CONCENTRATION MAP OCTOBER 6, 20111 - OCTOBER 6, 2012 A' CADIS FIGURE 4 FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET LEGEND 1 ) MONITORING WELL ABANDONED MONITORING WELL INJECTION WELL LOCATION TARGETED SURFACTANT LOCATION 0 40 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE CHARLOTTE, NC SURFACTANT APPUCATION WORK PLAN 2012 PROPOSED SURFACTANT APPLICATION LOCATIONS ARCADIS FORMER **STE OIL TAM FORMER PROPERTY BOUNGARy \ —\ INJ-2 FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET — 2R -2 LEGO() MONITORING WELL ABANDONED MONITORING WELL INJECTION WELL LOCATION 49' so' GRAPHIC SCALE EXXONFAOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBL FACILITY X42094 3721 FREEDOM DRIVE CHARLOTTE, NC SURFACTANT APPLICATION WORK PLAN 20 2 PROPOSED INJECTION WELL LOCATIONS ARCMS GROUND SURFACE: 500.00 TOP OF RISER PIPE: 499.50 TOP OF SEAL: BOTTOM OF SEAL: TOP OF SCREEN: BOTTOM OF SCREEN: BOTTOM OF WELL SUMP: BOTTOM OF BOREHOLE: FLUSH MOUNTED COVER LOCKING CAP RISER PIPE: 2" Diameter Sch. 40 PVC GROUT: CementBent©nite Mixture WELL SEAL BOREHOLE DIAMETER: 4.25" GRADED SAND PACK: SCREEN PIPE: 2" diameter Sch. 40 PVC SCREEN SLOT SIZE: O.©2" Former ExxonMobil Facility #4-2094 3721 Freedom Drive, Charlotte, North Carolina TYPICAL INJECTION WELL CONSTRUCTION DIAGRAM ARCA S ti FORMER Ct ARLIE BROWN'S DRY CLEANERS 41O MAJOR STREET IWAJOR STREET MONITORING WELL ABANDONED b6ONIT0R(NG WELL PROPOSED INJECTION WELL D` RADIUS OF INFLUENCE A A' Cl SS SECTtSN LINE SO L SAMPLE LOCATION A ,,! ADVANCED IN 2002 (LOCATION IS APPROXIMATED) 40' 8O GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA CHEMICAL INJECTION CROSS SECTION LOCATION MAP ARCAD1 S FIGURE BA MW- 4 NORTH (ABANDONED) 95 - 90 85 80 70 - 6 60 GP-2* 25 - 9/GP- B-B CROSSES A -A' MW-1 /GP-3 ABANDONED) GP- S \\:\ MW- 5 W-2* DW-1 MW- 5 10/21/2010 X 25,800 25,100 1,610 12,100 * ,4 GP-12* \ \ \ \ " \ \\\ „, \\,\ \\'„\\\ \\\\\ \ :\\\„, \ ' \ \ \ \ \ \ •= ", \ \ \ \ \ MW-7 5/17/2011 7.39 <0.5 <0.5 X MW- 7 A' SOUTH - 95 90 85 0 75 70 65 60 DW-1 5/17/2011 <0,5, <0.5 <0.5 FEET ABOVE MEAN SEA LEVEL LEGEND RED TO BROWN CLAY, SILTY CLAY, SILTY SAND, CLAYEY SILT, DRY TO MOIST WHITE, GRAY, TAN TO UGH T BROWN, OLIVE GREEN SAND, SILTY CLAY, SILTY SAND, CLAY, CLAYEY SILT, MOIST TO WET PARTIALLY WEATHERED -ROCK, GRAY TO WHITE, PRESENTED AS SAND, SANDY SILT, CLAYEY SILT, SILTY SAND BEDROCK GROUNDWATER ELEVATION (COLLECTED 5/17/11) IN FEET. COORDINATE SYSTEM IS AN ARBITRARY SYSTEM WHERE THE ELEVATION OF THE NORTHEAST CORNER OF THE FORMER EXXON STATION = 100 FEET. INFERRED LITHOLOGIC CONTACT SCREENED INTERVAL NOTES: 1. GROUND SURFACE ELEVATIONS NOT AVAILABLE, THERE FORE USING TOP OF CASING ELEVATION! AS GROUND SURFACE FOR CROSS SECTIONS. 2. IW-1 AND IW-2 ARE PROPOSED INJECTION WELLS TO BE INSTALLED. DEPTHS/LOCATIONS ARE APPROXIMATE 3. * - ESTIMATES GROUND ELEVATION. 4, PWR - PARTIALLY WEATHERED ROCK, 5. MW- 4, MW-1, MW-5, AND DW-1 WERE LOGGED EVERY FIVE FEET. 6, < : NOT DETECTED AT THE REPORTING LIMIT SHOWN 7. CONCENTRATIONS IN MICROGRAMS PER U TER 8, ND = NONDETECT 9. GROUNDWATER CONCENTRATIONS IN BOLD EXCEED THE NORTH CAROLINA GROSS CONTAMINATION LEVELS 0 0 HORIZONTAL GRAPHIC SCALE VERTICAL GRAPHIC SCALE 50' 10' EXXONMOBIL ENVIRONMENTAL SERVICES EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA CHEMICAL INJECTION CROSS SECTION AA' ARCADES FIGURE A —A' CROSSES B—B' MW-5 IW-2* POtND BENZENE TOULENE E = ETH ENZENE X = TOTAL X NES LEGEND RED TO BROM'I CLAY, SILTY CLAY, SILTY SAND, CLAYEY SILT, DRY TO MOIST WHITE, GRAY, TAN TO LIGHT BROWN, OLIVE GREEN SAND, SILTY CLAY, SILTY SAND, CLAY, CLAYEY SILT, MOIST TO WET PARTIALLY WEATHERED —ROCK, GRAY TO WHITE, PRESENTED AS SAND, SANDY SILT, CLAYEY SILT, SILTY SAND GROUNDWATER ELEVATION M. (COLLECTED 5/17/11) IN FEET, INFERRED LITHOLOGIC CONTACT iSCREENED INTERVAL NOTES: 80 1, GROUND SURFACE ELEVATIONS NOT AVAILABLE, TOP Of CASING ELEVATIONS USED AS GROUND SURFACE FOR CROSS SECTIONS. 2. IW-2 IS A PROPOSED INJECTION WELL TO BE INSTALLED. DEPTH/LOCATION ARE APPROXIMATE. 3. * ESTIMATED GROUND ELEVATION. 4, PWR — PARTIALLY WEATHERED ROCK. 5, COORDINATE SYSTEM IS AN ARBITRARY SYSTEM WHERE THE ELEVATION OF THE NORTHEAST CORNER OF THE FORMER EXXON STATION = 100 FEET. 6. MW-5 WAS LOGGED EVERY FIVE FEET. 7. GROUNDWATER SAMPLES COLLECTED 70 10/21/2010 8. CONCENTRATIONS IN MILLIGRAMS PER LITER (,cog/L). 9. CONCENTRATIONS IN BOLD EXCEED THE. NORTH CAROLINA GROSS CONTAMINATION LEVELS. 20' HORIZONTAL GRAPHIC SCA 5' 10' VERTICAL CRAP SCALE EXXONMOBIL ENVIRONMENTAL SERVICES EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA CHEMICAL INJECTION CROSS SECTION B-B' ARCADIS FIGURE 8C ARCADIS Appendix A MATERIAL SAFETY DATA SHEET THE BIOSOLVE® COMPANY 329 Massachusetts Avenue Lexington, Massachusetts 02420 USA Ref. No.: 2001 Date: 7/26/2010 Phone: +1 (781) 482-7900 Fax: +1 (781) 482-7909 E-Mail: info@biosolve.com Emergency Phone-24 Hours: +1 (800) 225-3909 Web Site: www.biosolve.com Name: CAS #: Formula: Chemical Family: HMIS Code: HMIS Key: SECTION I - IDENTITY BioSolve® 138757-63-8 Proprietary Water Based, Biodegradable, Wetting Agents & Surfactants Health 1, Fire 0, Reactivity 0 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Insignificant SECTION II - HAZARDOUS INGREDIENTS Massachusetts Right to Know Law or 29 C.F.R. (Code of Federal Regulations) 1910.1000 require listing of hazardous ingredients. This product does not contain any hazardous ingredients as defined by CERCLA, Massachusetts Right to Know Law and California's Prop. 65. DOT Class: Not Regulated/Non Hazardous SECTION IH - PHYSICAL - CHEMICAL CHARACTERISTICS Boiling Point : 265°F Specific Gravity : 1.00 +1--.01 Melting Point : 32°F Vapor Pressure mm/Hg : Not Applicable Surface Tension- 6% Solution : 29.1 Dyne/cm at 25°C Vapor Density Air = 1 : Not Applicable Reactivity with Water : No Viscosity - Concentrate : 490 Centipoise Evaporation Rate : >1 as compared to Water Viscosity - 6% Solution : 15 Centipoise Appearance : Clear Liquid unless Dyed Solubility in Water : Complete : 9.1+/-.3 Odor : Pleasant Fragrance pH Pounds per Gallon : 8.38 SECTION IV - FIRE AND EXPLOSION DATA Special Fire Fighting Procedures Unusual Fire and Explosion Hazards Solvent for Clean -Up Flash Point : None : None : Water : None Flammable Limit Auto Ignite Temperature Fire Extinguisher Media : None : None : Not Applicable PAGE I OF 2 Date:7/1/2010 MSDS Ref. No. 2001 BloSolve® SECTION V - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be taken in Handling and Storage: Use good normal hygiene. Precautions to be taken in case of Spill or Leak - Small spills, in an undiluted form, contain. Soak up with absorbent materials. Large spills, in an undiluted form, dike and contain. Remove with vacuum truck or pump to storage/salvage vessel. Soak up residue with absorbent materials. Waste Disposal Procedures - Dispose in an approved disposal area or in a manner which complies with all local, provincial, and federal regulations. SECTION VI - HEALTH HAZARDS Threshold Limit Values: Not applicable Signs and Symptoms of Over Exposure - Acute : Moderate eye irritation. Skin: Causes redness, edema, drying of skin. Chronic: Pre-existing skin and eye disorders may be aggravated by contact with this product. Medical Conditions Generally Aggravated by Exposure: Unknown Carcinogen: No Emergency First Aid Procedures - Eyes: Flush thoroughly with water for 15 minutes. Get medical attention. Skin: Remove contaminated clothing. Wash exposed areas with soap and water. Wash clothing before reuse. Get medical attention if irritation develops. Ingestion: Get medical attention. Inhalation: None considered necessary. SECTION VII - SPECIAL PROTECTION INFORMATION Respiratory Protection : Not necessary Local Exhaust Required : No, except in confined space as required. Ventilation : Normal Protective CIothing : Neoprene or other chemical Required resistant gloves, safety goggles or chemical face shield. Wash clothing before reuse. WHEN UTILIZED IN CONFINED SPACE OPERATIONS ADDITIONAL PPE MAYBE REQUIRED AS PER OSHA GUIDELINES. Stability : Stable Polymerization : No SECTION VIII - PHYSICAL HAZARDS Incompatible Substances Hazardous Decomposition Products : None Known : None Known SECTION IX - TRANSPORT & STORAGE DOT Class : Not Regulated/Non Hazardous Freeze Temperature : 28°F Storage : 35°F-120°F Freeze Harm : None (thaw & stir) Shelf Life : Unlimited Unopened SECTION X - REGULATORY INFORMATION The Information on this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties, and handling of this product under the recommended conditions of use. Any use of this product or method of application, which is not described on the Product label or in this Material Safety Data Sheet, is the sole responsibility of the user. This Material Safety Data Sheet was prepared to comply with the OSHA Hazardous Communication Regulation and Massachusetts Right to Know Law. PAGE 2 OF 2 ARCAD S Appendix B BioSolveTechnical Bulletin The Product and How It Works BioSolve is a proprietary, water -based blend of non-ionic and anionic surfactants, and other ingredients specifically formulated to provide unique benefits for the mitigation of hydrocarbons, When applied as a .3% - 6% solution BioSolve works on a wide range of crude oil and hydrocarbon products to: • Reduce volatility, rendering spills non-flammable, reducing risk from hazardous vapors: • Enable extraction of contaminants from sail, sand and water: and, • Increase bioavailability, making hydrocarbons more readily biodegradable, Surfactants Surfactants (a contraction of surface active agents") are compounds that lower the surface tension of liquids, allowing easier spreading or "wetting," and lower interfacial tension between two liquids (such as oil and water) or between a liquid and a solid. These functional characteristics are attributable to the structure of the surfactant molecule, which includes a hydrophilic "head" and a hydrophobic "tail." This means that a surfactant has both a water insoluble component (or oil soluble component) and a water soluble component. Surfactant molecules forming a micelle - encapsulating an oil droplet Surfactant molecules will migrate to the water surface, where the insoluble hydrophobic group may extend out of the bulk water phase, either into the air or, if water is mixed with oil, into the oil phase, while the water soluble head remains in the water phase. This alignment and aggregation of surfactant molecules at the surface acts to alter the surface properties of water at the water/air, water/oil or water/solid interface. Under the right conditions, surfactant molecules will create micelles - spherical structures that can completely encapsulate an oil droplet so that it will be emulsified in an aqueous solution. The BioSolve formula has been optimized to achieve this encapsulation and emulsification for crude oil and hydrocarbons. BloSolve in Practice When applied to oils spills, BioSolve encapsulates hydrocarbons, reducing vapor pressure and,, when properly agitated, will make the spill non-flammable. The same principle makes BioSolve an excellent treatment for controlling fugitive vapors at active remediation sites, for temporary storage piles of contaminated material and for reducing LPL readings in enclosed spaces, such as storage tanks, For in -situ and ex -situ remediation projects, BioSolve reduces interfacial tensions, mobilizing hydrocarbons trapped in the soil matrix and encapsulating them in an aqueous solution. This allows for efficient removal and treatment of hydrocarbons with less water than other remediation protocols. For aquifer remediation, BioSolve strips and desorbs NAPLs from the matrix and solubilizes them in a tension reduced spherical micellular emulsion. 44•11,)4X11°:ArtrKA 1.*TbGATPC,AN TrrG7,INt`Aik,PA1..Y Trapped Dil alt Residual Saturation Surfactant Flush Solubilization (microemuisions) Mobilization Waste collected from remediation projects can be treated in many activated sludge ponds or POTWs, subject to local regulations. Tests have shown that BioSolve will not harm aerobic or anaerobic bacteria in activated sludge operations. BioSolve also supports biodegradation by increasing bioavailability of hydrocarbons. This natural process i accelerated when hydrocarbons are microencapsulated - increasing the surface area available to bacteria. In fact, bacteria produce a surfactant to do much the same thing; so BioSolve is just helping the natural process along. Where soil nutrients are depleted, BioSolve has produced excellent results when used in conjunction with commercially available bacteria cultures and nutrients commonly used in bioremediation. The final products of biodegradation are mostly carbon dioxide, water and cell mass. BioSolve has been tested under laboratory and field conditions for over 30 years, providing consulting engineers, regulators and contractors with a high level of confidence in its performance. BioSolve Technical Data Freeze Temperature: 28°F .. Freeze Harm: None may require stir Boiling Point: 265°F Specific Gravity: 1.00 +/- .01 Surface Tension: 29.1 dyne/cm 4 25°F pH: 9.1 +/_ 0.3 depending on dilution w Solvent for Cleanup: water Shelf Life: Unlimited - Unopened 9) er Odor P'ieasant Fragrance Flammability: None Health: Minor Skin Irritant {NCIS Rated 1) Density: 8.38 pounds per gallon Viscosity (Concentrate): 490 centipoise Viscosity (6% Solution): 15 centipoise Color: Clear Liquid or Dyed Red DOT Crass: Not Regulated BioSolve is listed on the US EPA's NCP Product Schedule. This fisting. DOES NOT mean that EPA approves, rec©rnmends, licenses,, certifies or authorizes the use of BioSolve on any oil discharge. This Misting means only that data has been submitted to EPA as required by Subpart J of the National Contingency Plan, 300,915, This material is made available for use by professionals or persons having proper technical skills to be used at their own discretion, The statements made herein are guidelines only and may require modification to site specific conditions. Nothing contained herein is a warranty or is to be token as a license to use without proper authority. BioSolve should always be used in accordance with all Federal, State and Local rules and regulations, The BioSolve Company 329 Massachusetts Avenue • Lexington, Massachusetts 02420 USA Telephone: +1 (781) 482-7900 • Fax: +1 (781) 482-7909 Email.( nfoAbipsolve.com • vvww.biosolve.corn BioSolve The trusted solution for over 30 years 7BC TB1001RevO411 l.ntrastrucadre Waler ..Env,roornt • Ruildings ,;,4) 4t• „.itmo 1„„1 Ay 2 2012 Mr, David Goodrich North Carolina Department of Environment and Natural Resources Division of Water Quality Aquifer Protection Section 1636 Mail Service Center Raleigh, North Carolina, 27699 Subject Additional Information Request Former Exxon Facility #42094 3721 Freedom Drive Charlotte, North Carolina Groundwater Incident #6867 Dear Mr, Goodrich: On behalf of ExxonMobil Environmental Services (EMES), ARCADIS G&M of North Carolina (ARCADIS), is submitting this Response to an Additional Information Request from the North Carolina Department of Environment and Natural Resources (NCDENR) requesting additional information for an injection permit at the above referenced site for your review. Inquiries from correspondence dated March 13, 2012 are included as Attachment 1 and their respective responses are listed below. 1, "Sections B (3) and B (4) of the UIC-51/5T Application Form require the submission of a hydrogeologic description that includes the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters, and the depth to the mean seasonal high water table, Please submit this information for each of the four sites. Soils at the site consist primarily of silt and clay based on soil boring logs for the site monitoring wells and soil borings. Saprolitic soil was encountered in all the borings at depths greater than 10 feet. Imported fill soils consisting of semi -plastic sandy clay with gravels were observed over much of the site. The fill soil did not extend greater than 10 feet bgs. Partially weathered bedrock was intersected in monitoring well borings for MW-7 and DW-1 at depths of 18 feet and 47 feet bgs, respectively. Competent bedrock was encountered in these two monitoring well borings at 22 feet Imagine the result ARCADIS G8.4 of North Caroiina, Inc, 801 Corpora e Center Dnve Suite 300 Raleigh North CaroOina 27607 Tel 919 854 1282 Fax 919 854 5448 wwwarcadis-us.corn Environment Date: May 10, 2012 Contact Scott Bastian Phone 919.854.1282 x 52291 Emaii Scott.Bostian©arcadis- US.COM Our ref B0085851.0045 ARCADIS G&M of North Carolina, Inc NC Engineering License # C.1869 NC Surveying License # C-1869 RECEIVEDIDENR/DN MAY 1 4 2012 Aquifer Protection Section \officenata1taleigh-octenv Enotenrnottil \north carVtna (7,,jection sote,642094'response to cornments4extkern 42094 - response t.o nc uic comments.d ARCADIS and 55 feet bgs, respectively (ERM, Comprehensive Site Assessment Report, November 2002). The depth -to -groundwater at the site is approximately 14 to 26 feet bgs at present (Table 1). However, the historic depth -to -groundwater data indicate that the water table elevation across the site has decreased by nearly ten feet since 1991. Groundwater elevation data indicate that ground water flows to the southeast as shown on Figure 1 (ERM, Comprehensive Site Assessment Report, November 2002). The hydraulic conductivity of the water table saprolite aquifer was calculated using slug test data collected from monitoring wells MW-7, MW-8 and MW-9 and the Bouwer-Rice method (1976). The hydraulic conductivity of MW-7 is 6.59 x 10-4 centimeters per second (cm/sec), MW-8 is 1.54 x 10-3 cm/sec and MW-9 is 9.88 x 10- 4 cm/sec for a geometric mean of 1.00 x 10-3. Hydraulic conductivity in the range of the calculated geometric mean is typical of a silt aquifer matrix. Slug test data and calculations are provided in Attachment 2. The groundwater velocity, assuming an effective porosity of 40%, is calculated to be approximately 0.07 feet/day (25.9 ft/year) (ERM, Comprehensive Site Assessment Report, November 2002). Transmissivity is calculated by multiplying the hydraulic conductivity (K) and the saturated thickness of the aquifer. The hydraulic conductivity value was previously calculated from monitoring wells MW-7 as 6.59 x 10`4 cm/sec, MW-8 as 1.54 x 10"3 cm/sec and MW-9 as 9.88 x 10"4 cm/sec. The saturated thickness of the aquifer was calculated by subtracting the assumed soil bedrock interface at 47 feet below ground surface (ft bgs) from the most recent depth to water in monitoring well MW-7 of 14.75 feet below top of casing (ft btoc). The transmissivity for MW-7 is 60.24 square feet per day (ft2lday), MW-8 is 140.78 ft2lday and MW-9 is 90.32 ft2lday. The average transmissivity is 97.11 ft2lday. Calculations are included in Attachment 2. A potentiometric surface map from the most recent gauging event on March 14, 2012 is included as Figure 1. Monitoring well MW-5 was selected for the depth to the seasonal high water table calculations because it is considered representative of the aquifer. The depth to the seasonal high water table was calculated by averaging the gauging data in monitoring well MW-5 from the months of March through May from 2002 to the present. The depth to the mean seasonal high water table was calculated as 17.70 feet below ground surface (ft bgs). The calculations are presented in Attachment 2. Mr. David Goodrich May 10, 2012 MreadsusloincedadRalsbh-NCIENNEracrbobANorth Carolina Il'eclion siles1.420941Response to Cammors4TexJ EM 42094 Response Ia NC UIC Comments.doex Page: 2/5 ARCADIS 2. "Sections D (3) and D (4) of the UIC-51/5T Application Form require the submission of a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injections, and summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. Please submit this information for Retail Facility 42094 (Permit Application W10300192) and Retail Facility 46477 (Permit Application W10400243)." BioSolve® is a proprietary formulation of surfactants and other specialty chemicals developed specifically as a water -based hydrocarbon mitigation agent. BioSolve® does not have any chemical reaction with the contaminants. BioSolve® will 1) mobilize contaminants by reducing interfacial tension and 2) solubilize contaminants, creating a microemuision, both with the intention of hydraulically removing contaminants from the soil. Under the application scenario proposed, most BioSolve® solution injected into the subsurface will be recovered and disposed of off -site. At least two times the volume of injected solution will be recovered. A small volume of Biosolve® may remain in the subsurface and aquifer groundwater. If so, residual Biosolve® would continue to be diluted and degraded over time. Most constituents in BioSolve® are readily degraded in -situ. The most recalcitrant ingredient in BioSolve® is the nonionic surfactant nonylphenol ethoxylate (NPE). Biodegradation of NPEs is accomplished by a stepwise shortening of the ethoxylate chain. This produces a complex mixture of nonylphenol (NP) compounds that can be divided into three main groups: short -chain nonylphenol ethoxylates, nonylphenol carboxylic acids and nonylphenol. This initial degradation typically takes place in a matter of 5 to 10 days as the hydrophilic chain is readily degraded. Subsequent degradation of NP compounds proceeds relatively rapidly under aerobic conditions with degradation of approximately 80% of NP in 30 days (Chang, 2006). Under anaerobic conditions, half-lives for NP range from 23.9 to 69.3 days (Mao, 2012). 3. "Section E (3) of the UIC-51/5T Application Form requires the submission of a detailed diagram of the surface and subsurface portions of the system. Please submit This diagram for each of the four injection systems." An injection diagram is included as Figure 2. Mr. David Goodrich May 10, 2012 lWradstuslolhcedold Raleigh-NCIENY1ExtonN dSWerth Cerane hgedion silest4209elleapeose W CanmenlslTe,kEM 42a94 • Response la NC UIC Cammenls.dc Page: 3/5 ARCADiS 4. "Sections H (2) (d), (e) and (t) of the UIC-51/5T Application Form requires the submission of a site map that includes any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within % mile of the injection well or well system; all surface water bodies within '4 mile of the injection well or well system; and all existing or abandoned wells within mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Please .submit a map for each of the four sites." A local area map is included as Figure 3. 5. "Section H (4) (a) of the UIC-51/5T Application Form requires the submission of a contaminant plume map that includes the horizontal extent of the contaminant plume, including isoconcentration lines. Please submit a map for each of the four sites." A benzene plume map is included as Figures 4. 6. "Section H (5) (a) of the UiC-51/5T Application Form requires the submission of a cross-section to the known or projected depth of contamination that includes the horizontal and vertical extent of the contaminant plume, including isoconcentration lines. Please submit a cross-section for each of the four sites." Cross -Sections are included as Figures 5 through 7. If you any questions regarding the injection permit response to the request for additional information or the proposed environmental investigation please contact me at 919.854.1282, extension 52291. "XI f 1 G 4 g,� s I I Fc --ACzich7-6tal Ai) Q 025 rn n �� ,.j�.ott '4 vegedismot Attachments: Table 1 — Groundwater Elevations 2SSs9 qi'ental Engineer Jon Farley, EIT Certified Project Manager i RECEIVEDJDENR/DWQ MAY T 4 2012 Aquifer Protection Section Mr. David Goodrich May 10, 2012 SWeidsusblfieedatalRaleigh NCWOPAEmonMohiniorlh Carolina Injection silesV42094iResponse to Cammentsl1eo EM 42094 • Response Io NC UiC Comrew.decx Page: 4/5 ARCADIS Figure 1 — Potentiometric Surface Map — March 1, 2012 Figure 2 — Injection Diagram Figure 3 — Local Area Map Figure 4 — Benzene Isoconcentration Map Figure 5 — Cross -Section Location Map Figure 6 — Cross -Section A -A' Figure 7 — Cross -Section B-B' Attachment 1 —Additional Information Request Attachment 2 — Hydrogeological Calculations Attachment 3 — Boring Logs and Monitoring Well Construction Diagrams Copies! Ms. Jewel Cox - EMES File — EM 42094 Mr. David Goodrich May 10, 2012 Mea6s-usb15ceni aUlaleigMICIEi{J4Eooataballorth CavEna oq iris aSest42099Resporrse to CcmeisiTei.1VE.142094- Response Io NC IOC Cammn9s.Eacs Page: 5/5 ARCADE Figures 1 n yr Ei ET. ece soio— ‘1�i F0.UER AEG OIL I L- w 8 0. FORMER WASTE OIL TANK F\\. 1 \ \I (77.49) \ \ 1 FORMERIISMK.- w-21, r—FlE.D yr_ I� iPi , i, ii;i.60) 7-19UNKNOWN FORMFfI' CHARLIE B.ROWN'S DRY CI,NERS 440 MAJOR STREET 61(77.44) MAJOR STREET 5.` (78.75) \ FORMER PROPERTY BOUNDARY ^4f \ MW3(UNKNO FORMER DISPENSER ISLANDS \• • v •• \[\\ `\\ N0PPP p czl 77.5O LEGEND (76.58) MONITORING WELL ABANDONED MONITORING WELL GROUNDWATER ELEVATION CONTOUR (DASHED WHERE INFERRED) GROUNDWATER ELEVATION (FEET BELOW ARBITRARY SITE LEVEL) GROUNDWATER FLOW DIRECTION NOTE: BASEMAP PREPARED FROM DRAWING FILE PREPARED BY "GROUNDWATER AND ENVIRONMENTAL SERVICES, INC.' (GES), TITLED: SITE MAP, AT A SCALE OF DATED: NOVEMBER 21, 2008. 0 40' 80' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC RESPONSE TO COMMENTS POTENTiOMETR1C SURFACE MAP MARCH 1 , 2012 ARCAD1 5 FIGURE 1 5 1 W TAN}( M lho By-T ev-z INJECTION PUMP LEGEND BALL VALVE FLOW DIRECTION CAMLOCK CONNECTION PRESSURE INDICATOR TDTAIThNC FLOW METER 1' CHEMICAL HOSE INJECTION PUMP EXXONMOBIL REFINING & SUPPLY COMPANY EXXON SERVICE STATION #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC . RESPONSE TO COMMENTS PROPOSED INJECTION DIAGRAM ARCADIS FIGURE 2 0 a 0 m NOTE: BASE MAP PREPARED FROM A COMBINATION OF AERIAL VIEWS FROM POLARIS.MECKLENBURG000NTRYNC.GOV AND GOGGLE MAPS. SCALE IS APPROXIMATE BASED UPON PARCEL DIMENSIONS. 0 400' 800' APPROXIMATE GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC RESPONSE TO COMMENTS LOCAL AREA MAP FIGURE 3 0 0 y6 N 0 o 3m3� ZZ 0 ) 1-1,..".1 I FOritOERTAEK NG I I MW-(UNKND kg FORMER PROPERTY 'BOUNDARY • FORMER \ DISPENSER \ ISLANDS • 1 • FORMER WASTE 01L TANK 1 1 wi (5.78) (NS) roR11iFR r--Flan 1, � �, '1, (NS) - - ----9UNKNOWN FORMER CHARLIE BROWN'S DRY CI F_ANERS 440 MAJOR STREET MAJOR STREET o Qa LEGEND IQI MONITORING WELL ABANDONED MONITORING WELL • DISSOLVED -PHASE BENZENE CONCENTRATION 5,000�� CONTOUR (GCL STANDARD - DASHED WHERE INFERRED) (22,00m DISSOLVED -PHASE BENZENE CONCENTRATION (ug/L) (ug/L) MICROGRAMS PER LITER (NS) NOT SAMPLED NOTES: NORTH CAROLINA GROSS CONTAMINAT LEVEL STANDARD FOR BENZENE (5,000 ug/L) BASEMAP PREPARED FROM DRAWING F1LE PREPARED BY "GROUNDWATER AND ENVIRONMENTAL SERVICES, INC." (GES). TITLED: SITE MAP, AT A SCALE OF 1 "=50', DATED: NOVEMBER 21, 2008. 0 40' 80' J GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NC RESPONSE TO COMMENTS BENZENE 1SOCONCENTRATION MAP MARCH 1, 2012 FIGURE 4 i FORMER HEATING I 01L TANK I _ 1 FORMER WASTE 01L TANK r AGP-16 IQI "MW-3 AGP-15 v A GP-17 GP®4 1!W-4 FORMER PROPERTY Y / BOUNDARY • FORMER \ DISPENSER '\ ISLANDS \ �.i \ GP-2r \1 \ QE.. t \ \ \ )r1\ 1 1 111\�� 1 1 \ 1 GP-41A11 \.` '-• \ GP-18 A GP-10 GP GP-B r Iy B FORfAF„R� . �. r^ FTELD_ f ; LAW-2 Ij^�;iT;j 11 1 j III II 111 GP-13 LL-AGP-7 ---BUNKNOWN FORMER CHARLIE BROWN'S DRY CLEANERS 440 MAJOR STREET MAJOR STREET MW-1/GP-3 \ 1 \ a GP-6 \ \•I \•\ ��f. GP-12 LEGEND: 19 MONITORING WELL I ABANDONED MONITORING WELL PROPOSED INJECTION WELL. 1 10' RADIUS OF INFLUENCE 11/4 Al CROSS SECTION LINE SOIL SAMPLE LOCATION ADVANCED IN 2002 (LOCATION 15 APPROXIMATED) 0 40' BO' GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES EXXONMOBIL FACILITY #42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA RESPONSE TO COMMENTS CROSS-SECTION LOCATION MAP ARCADIS FIGURE 5 a U a w FEET ABOVE MEAN SEA LEVEL IJ -W, °a a � NE A MW-4 NORTH (ABANDONED) 95 90 -- 85 80 75 70 65 - GP-2* MW-9 IW--1* GP-1 -8' CROSSES A -A' MW--1 GP-3 (ABANDONED) *4+ • t••• 4.• .4.44 ••• , *44 4'44.4.$ 4•4*# $4* "404*, 44+4 4.44 $ *4* **WO $1 **ASA 0 • 0 4•4.• *4 v 4, 04 4.• , #4•4. 4; 4A1 Iv 4"4•4 '4 4.• • 44 #•4•4. $ St 44 $++40 $4° 40+4++ 44 r i t•44 4.4*4 PS' 4* $14+++ 444 4., 4*4•4.4 1 "4•4tv 44: 4*. 4•4• 4°4••••• ir 4••• 4* t 4•4* e 1 f 4*, 0 *No $ 4' ; 4•44" +4•4•44 **4* "N4••• ( , 4A+ . 0 ; ./ OI O #####$ e 4•••1 Ne ... • /S+ /' / / / / / / / / / / / / / / / / / / / / / MW- 5 GP-5* IW-2* MW-9 TYPE GROUNDWATER DATE 3-1-12 B 12,500 T 16,800 E 1,650 X 7,720 M 5,320 MW-5 TYPE GROUNDWATER DATE 3-1-12 B 22,200 T 13,000 E 1,760 X 6,850 M 59.8 / DW-1 \\\\ \\ \\\\\\\\\ \k\ /\\\kk \ 1 \\\ \\\\ \\\\ \k\\\ \\\\ \\\\\\\\- 60-i\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\\�\\ 25 - 15 \\\\ \\\\\\\\\\\.\\ \\\ \\\\\\\\\\ \\\ \\\ \\\\\\ \\\ \\\\ NOTES _ B BENZENE T TOLUENE _ E ETHYL9ENZENE X TOTAL XYLENES M METHYL TERTIARY -BUTYL ETHER BOLD CONCENTRATIONS EXCEED GCL GLC GROSS CONTAMINATION LEVELS GP-12* MW-7 / / /////,/ ,/ /,/L ./ // ,/„ / / /////, / /. , / / �\\\\\�\\\\ \\\\�\\\\\\\\\ \\\4\\\\\\\�\\>- A' souTH — 95 g0 r/A LEGEND RED TO BROWN CLAY, SILTY CLAY, SILTY SAND, CLAYEY SILT, DRY TO MOIST WHITE, GRAY, TAN TO LIGHT BROWN, OLIVE GREEN SAND, SILTY CLAY, SILTY SAND, CLAY, CLAYEY SILT, MOIST TO WET PARTIALLY WEATHERED -ROCK, GRAY TO WHITE, PRESENTED AS SAND, SANDY SILT, CLAYEY SILT, SILTY SAND BEDROCK GROUNDWATER ELEVATION (COLLECTED 5/17/11) IN FEET. COORDINATE SYSTEM IS AN ARBITRARY SYSTEM WHERE THE ELEVATION OF THE NORTHEAST CORNER OF ° 0 THE FORMER EXXON STATION = 100 FEET. 85 J INFERRED LITHOLOGIC CONTACT SCREENED INTERVAL lc NOTES: 80 J w U) z Lu 75 0 .m ti — DISSOLVED -PHASE BENZENE CONCENTRATION ISOCONTOUR (DASHED WHERE INFERRED) ESTIMATED GROUNDWATER ELEVATION CONTOUR 70• 65 60 25 15 1. GROUND SURFACE ELEVATIONS NOT AVAILABLE, THERE FORE USING TOP OF CASING ELEVATIONS AS GROUND SURFACE FOR CROSS SECTIONS. 2, IW-1 AND IW-2 ARE PROPOSED INJECTION WELLS TO BE INSTALLED. DEPTHS/LOCATIONS ARE APPROXIMATE. 3. * - ESTIMATES GROUND ELEVATION. 4. PWR - PARTIALLY WEATHERED ROCK. • 5. MW-4, MW-1, MW-5, AND DW-1 WERE LOGGED EVERY FIVE FEET. 6. BENZENE CONCENTRATIONS ARE SHOWN IN MILLIGRAMS PER KILOGRAM (mg/kg) GCLs B 5.000 T 260,000 E 84,500 X 85,500 20,000 0 25' 50' J HORIZONTAL GRAPHIC SCALE 0 5' imaENJ 10' VERTICAL GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES FORMER EXXONMOBIL FACILITY#42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA RESPONSE TO COMMENTS CROSS SECTION A -A' ARCADS FIGURE 6 0 B WEST GP-8* 95 — 90 — Ci B5 J w J 80 w 0 E- 75 — W UJ / / A -A' CROSSES B-B' MW-5 IW-2* MW-5 TYPE GROUNDWATER DATE 3-1-12 B 22,200 T 13,000 E 1,760 X 6,850 M 59.8 B' EAST GP-5* r- 95 / 9// 70 -- \/ \\\\\\\\: - Y WigI \`-- 70 \\.\\\\\k\\\\\ \\ \\\\ `\\ \\\\\\\\ \\\\\\ 65 -- \\\ `.� \\\�+1.14 \\\+ \\\\\ \\!\\\\ \\\\\\ .. ' \' 60 90 85 — 80 /// \\ NOTES: LEGEND RED TO BROWN CLAY, SILTY CLAY, SILTY SAND, CLAYEY SILT, DRY TO MOIST WHITE, GRAY, TAN TO LIGHT BROWN, OLIVE GREEN SAND, SILTY CLAY, SILTY SAND, CLAY, CLAYEY SILT, MOIST TO WET PARTIALLY WEATHERED -ROCK, GRAY TO WHITE, PRESENTED AS SAND, SANDY SILT, CLAYEY SILT, SILTY SAND GROUNDWATER ELEVATION (COLLECTED 5/17/11) IN FEET. INFERRED LITHOLOGIC CONTACT SCREENED INTERVAL 1. GROUND SURFACE ELEVATIONS NOT AVAILABLE, TOP OF CASING ELEVATIONS USED AS GROUND SURFACE FOR CROSS SECTIONS. 2. IW-2 IS A PROPOSED INJECTION WELL TO BE INSTALLED. DEPTH/LOCATION ARE APPROXIMATE. 3. * - ESTIMATED GROUND ELEVATION. 4. PWR - PARTIALLY WEATHERED ROCK. 5. COORDINATE SYSTEM IS AN ARBITRARY SYSTEM WHERE THE ELEVATION OF THE 75 NORTHEAST CORNER OF THE FORMER EXXON STATION = 100 FEET. 6. MW-5 WAS LOGGED EVERY FIVE FEET. 60 — -- DISSOLVED —PHASE BENZENE CONCENTRATION ISOCONTOUR (DASHED WHERE INFERRED) — ESTIMATED GROUNDWATER ELEVATION CONTOUR GCLs B 5,000 T E 260,000 84,500 X 85,500 20,000 NOTES B BENZENE T TOLUENE E ETHYLBENZENE X TOTAL XYLENES M METHYL TERT1ARY—BUTYL ETHER BOLD CONCENTRATIONS EXCEED GCL 0 20' 40' I Molt HORIZONTAL GRAPHIC SCALE 0 5' 10' • VERTICAL GRAPHIC SCALE EXXONMOBIL ENVIRONMENTAL SERVICES • FORMER EXXONMOBIL FACILITY#42094 3721 FREEDOM DRIVE, CHARLOTTE, NORTH CAROLINA RESPONSE TO COMMENTS CROSS SECTION B-B' 03 [Ll�+l4 RCAIS FIGURE 7 ARCADIS Attachment 1 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P.B. Dee Freeman Governor Director Secretary March 13, 2012 Mr. Jewel Cox — Project Manager Exxon Mobil Environmental Services 1016 W. Poplar Avenue Suite 106 — Number 232 CollierviIle, TN 38017 Subject: Additional Information Request WI0300192, WI0300193, WI0400242 & WI0400243 Permit Applications ExxonMobil Retail Facilities 42094, 46475, 42650 & 46477 Injection In situ Groundwater Remediation Well (5I) Systems Mecklenburg, Gaston, Alamance & Forsyth Counties Dear Mr. Cox: The Non -Discharge Permitting Unit is reviewing the subject permit application packages received February 28, 2012 and March 2, 2012. Additional information is required before we may continue our review. PIease address the foIIowing items no later than April 13, 2012: 1) Sections B (3) and B (4) of the UIC-51/5T Application Form require the submission of a hydrogeo]ogic description that includes the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters, and the depth to the mean seasonal high water table. Please submit this information for each of the four sites. 2) Sections D (3) and D (4) of the UIC-5I/5T Application. Form require the submission of a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injections, and summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. Please submit this information for Retail Facility 42094 (Permit Application WI0300192) and Retail Facility 46477 (Permit Application WI0400243). 3) Section E (3) of the UIC-5I/5T Application Form requires the submission ofa detailed diagram of the surface and subsurface portions of the system. Please submit this diagram for each of the four injection systems. 4) Sections H (2) (d), (e) and (f) of the UIC-5U5T Application Form requires the submission of a site map that includes any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within'/ mile of the injection well or well system; all AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 512 N. Salisbury St., Raleigh, North Carolina 27604 Phone: 919-807-6464 L FAX: 919-807-6496 Internet: www.ncwaterquality.orq North Carolina Naturally An Equal opportunity 1Affirmative Action Employer Jewel Cox March 13, 2012 Page 2 of 2 surface water bodies within'/ mile of the injection well or well system; and all existing or abandoned wells within A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Please submit a map for each of the four sites. 5) Section H (4) (a) of the UIC-5I15T Application Form requires the submission of a contaminant plume map that includes the horizontal extent of the contaminant plume, including isoconcentration lines. Please submit a map for each of the four sites. 6) Section H (5) (a) of the UIC-5I/5T Application Form requires the submission of a cross-section to the known or projected depth of contamination that includes the horizontal and vertical extent of the contaminant plume, including isoconcentration lines. Please submit a cross-section for each of the four sites. Please be aware that you are responsible for meeting all requirements set forth in North Carolina rules and regulations. Any oversights that occurred in the review of the subject application package are still the responsibility of the applicant. Please reference the subject application number when providing the requested information. Three copies of all revised and/or additional documentation should be signed, sealed, dated, and submitted to my attention at the address at the bottom of the cover page of this letter. Please note that failure to provide this additional information on or before the above requested date may result in your application being returned as incomplete. If additional time is necessary, the application may be withdrawn to avoid being returned as incomplete. Either the applicant or the applicant's consultant may request withdrawal by email message or letter if this is desired. If you have any questions regarding this request, please do not hesitate to contact me at (919) 807-6352 or at david.goodrich@ncdenr.gov. Thank you for your cooperation. Sincerely, David Goodrich Aquifer Protection Section cc: Scott Bastian, ARCADIS, 801 Corporate Center Drive, Suite 300, Raleigh, NC 27607 Andrew Pitner, Mooresville Regional Office, Aquifer Protection Section Sherri Knight, Winston-Salem Regional Office, Aquifer Protection Section APS Central Files WI0300192, WI0300193, WI0400242, and WI0400243 ARCADIS Attachment 2 Displacement (ft) 1. 0.1 0.01 0. 40. 80. 120. Time (sec) 160. 200. Data Set: Date: 10/31/02 WELL TEST ANALYSIS Time: 09:25:21 PROJECT INFORMATION Company: ERM Client: ExxonMobil Project: 5941 Test Location: Exxon 4-2094 Test Well: MW-7 Test Date: 8/15/02 AQUIFER DATA Saturated Thickness: 22. ft Anisotropy Ratio (KzlKr): 1. initial Displacement: 0.65 ft Casing Radius: 0.083 ft Screen Length: 15. ft WELL DATA Water Column Height: 12. ft Wellbore Radius: 0.333 ft Gravel Pack Porosity: 0.25 Aquifer Model: Unconfined Solution Method: Bouwer-Rice SOLUTION K = 2,162E-05 ft/sec y0=0.6904ft 6,51 X(or4 Cam^ (SeG Displacement (ft) 1. 0.1 0.01 0. 100. 200. 300. Time (sec) 400. 500. Data Set: Date: 10/31/02 WELL TEST ANALYSIS Time: 10:57:43 PROJECT INFORMATION Company: ERM Client: ExxonMobil Project: 5941 Test Location: Exxon 4-2094 Test Well: MW-8 Test Date: 8/15/02 AQUIFER DATA Saturated Thickness: 23. ft Anisotropy Ratio (Kz/Kr): 1. Initial Displacement: 0.82 ft Casing Radius: 0.083 ft •Screen Length: 10. ft WELL DATA Water Column Height: 5.3 ft Wellbore Radius: 0.333 ft Gravel Pack Porosity: 0.25 Aquifer Model: Unconfined Cnit .iron ItReo+hnrl• Rnl hIlror_Riro SOLUTION K = 5.067E-05 ft/sec �. .in -nQa7.aff 4" ib13 ef-iste_, Displacement (ft) 0.01 ' 0. 40. 80. 120. Time (sec) 160. 200. WELL TEST ANALYSIS Data Set T:IEXXON--114-20941CSA1MW-9.AQT Date: 10/31/02 Time: 09:11:54 PROJECT INFORMATION Company: ERM Client: ExxonMobil Project: 5941 Test Location: Exxon 4-2094 Test Well: MW-9 Test Date: 8/15/02 AQUIFER DATA Saturated Thickness: 23. ft Anisotropy Ratio (KzlKr): 1. Initial Displacement: 0.74 ft Casing Radius: 0.083 ft Screen Length: 15. ft WELL DATA Water Column Height: 8. ft Wellbore Radius: 0,333 ft Gravel Pack Porosity: 0.25 Aquifer Model: Unconfined Solution Method: Bouwer-Rice SOLUTION K : 3.239E-05 ftlsec y0=0.7943ft ERM-Southeast, Inc. • Charlotte, NC 28226 • (704) 541-8345 File ERM e.L Project Koti 4 Subject (pGJ Chkd by Project No. Sheet of By Date Date F --i---4------ --- -I- —144 -•-• 7)+____k. ..t.iit.,...,....____Iii_....... _ f _ ...._;..... :... -C ----I-- 7 emt . : i r i 4; . i...4.....4........±._1_ _i...... -1- W PCB..� ._ �...�._..-... _ K. .. 4-...i _.._L r , ..'.! --- 21 •- 1-1 1 i €' ,-;r i ! ! ! f Transmissivity Calculations T =Kxd Where: T = transmissivity K = hydraulic conductivity d = saturated thickness of the aquifer _ 6.59 x 10-4 cm 60 sec 60 min 24 hrs 1 ft T I\ 1 sec x 1 minx 1 hr x 1 day x 30.48 cmx 32.25 ft T = 60.24 f t2/day (1.54 x 10' cm 60 sec 60 min 24 hrs 1 ft ) x32.25ft T= x x x x 1 sec 1 min 1 hr 1 day 30.48 cm T = 140.78 ft2/day _ (9.88x10_4cm 60sec 60min 24hrs 1 ft T 1 sec x 1 minx 1 hr x 1 day x 30.48 cm x 32.25 ft T = 90.32 f t2/day Average T = 60.24 + 140.78 + 90.32 3 Average T = 97.11 ft2/day Mean Seasonal High Water Table Calculations Revision Date: 4/25/2012 Incident Number: 6867 Facility I.D. # Former ExxonMobil Facility 042094 ~ Monitoring Wet I.D. Date instated Gauging Date Total Casing Depth (ft bgs) Screened interval (ft bgs) Top of Casing Elevation Elevation (ft) Depth to Water (ft BTOC) Depth to Product (ft BTOC) Product Thickness (ft) Ground Water (ft ASL) Measured Depth 10 Bottom (ft) Well Diameter MW-5 1/1612002 3/19/2002 15.00 15-35 96.52 19.50 19.35 0.15 77.13 -- 4" 4/13/2002 96.52 19.08 18.70 0.38 77.72 - 4" 5/10/2002 96,52 19.13 19.12 0.01 77.40 - 4" 3/19/2003 96,52 19.72 19.63 0.09 76.87 - 4" 4/22/2003 96,52 13.96 13,95 0.01 82.57 - 4' 5/30/2003 96.52 12.64 12.63 0.01 83.89 - 4" 4/28/200996.52 17.21 16.91 0.30 79.53 35.67 4' 3/28/2010 96.52 14.81 - - 81.71 -- 4" 4/2/2010 96.52 23.75 - - 72.77 - 4' 4/28/2010 96.52 15.57 - - 80.95 - 4" 5/17/2011 96.52 18.29 18.03 0.26 78.42 - 4' 3/1/2012 96,52 18.73 - - 77.79 - 4` Dep h to mean seasonal high water table: 17.70 Notes: BTOC = Below top of well casing - = Not measured or not available it = feel ft ASL = feet below arbitrary site level bgs = below ground surface Groundwater elevation corrected for the presence of free product using the formula: (Top of Casing Elevation- Depth to Water) + (Product Thickness x 0.73) Average elevation: 78.90 Page 1 of 1 ARCADIS Attachment 3 EA ENGINEERING, SCIENCE & TECHNOLOGY, INC. (704) 521-8713 Charlotte, North Carolina SOIL BORING LOG 3E 1 OF 2 irdinates: NIA race Elevation: pig Below Surface: :erence Elevation: ference Description: t Date: 11-29-90 imp. Date: 11-29-90 Sather. do. 1 Sample 2 3 4 5 Type SS SS SS SS SS Dpth 0 inch Inch Blows/6' Drvn Revd 18 18 18 18 18 18 18 18 18 18 9-10-12 • 4-5-7 5-5-7 6-8-10 7-9-13 BORING NO. Project No. Client Location: OVA ppm 100 180 40 40 EA-1 80005.16 Bacon Company, U.S.A. Freedom Drive Charlotte, NC (4-2094) Surface Conditions: Paved Lot Downgradient from Pump Island SOIL DESCRIPTION: 30 Red Silty Clay with Some Weathered Feldspar Limonite Staining and Magnesium Fill Same as Above Same as Above, Except More Magnesium Fill and Weathered Feldspar Same as Above to 19.0 Feet, Then Turning to Saprolite White Tan Sand with Fine to Coarse Sand Small Mica Flakes, Weathered Feldspar, Very Strong Ether Odor. Same as Above Sampler Type SS - Driven Split Spoon Sli - Pressed Shelby Tube OST -- Ostenburg Piston Sampler DEN - Denison Core Barrel Sampler SPT - Standard Penetration Test (ASTM D 1586-84) Drilling Method: Sampling Method: EA Geologist: Driller: Hollow Stem Auger • Split Spoon Stewart Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY, INC. (7m) 521-8713 Charlotte, North Carolina SOIi. BORING LOG 3E 2OF 2 rdinates: NIA irface Elevation: jing Below Surface: .ference Elevation: ference Description: it Date: 11-29-90 Amp. Date: 11-29-90 'eather. No. Sample rOpth Type 25 30 35 40 Inch Drvn 45 50 Inch Rcvd Blows/6' OVA ppm Sampler Type SS - Driven Split Spoon SH - Pressed Shelby Tube OST -- Ostenburg Piston Sampler DEN - Denison Core Barrel Sampler SPT - Standard Penetration Test (ASTM D 1586-84) BORING NO. Project No. Client: Location: EA-1 80005.16 Exxon Company, U.S.A. Freedom Drive Charlotte, NC (4-2094) Surface Conditions: Paved Lot Downgradient from Pump Island SOIL DESCRIPTION: Boring Terminated at 28 Feet Screen 28 to 13 Ft Riser 13 to 0 Ft. Sand Pack 28 to 11 Ft Bentonite 11 to 9 Ft Grout 10to0Ft Drilling Method: Sampling Method: EA Geologist: D rii(er: Hollow Stem Auger Split Spoon Stewart Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY, INC. (704) 521-8713 Charlotte, North Carolina SOLL BORING LOG ,E 1 OF 2 cdinates: N/A face Elevation: ng Below Surface: )rence Elevation: erence Description: it Date: 11-29-90 ip. Date: 11-29-90 :ati�er. Sample lo. Type Dpth Inch Inch Blows/6` Drvn Rcvd 1 3 4 5 SS SS SS SS SS 0 • >720 18 18 18 18 18 18 18 18 18 18 5-10-13 6-10-12 8-6-5 5--6-7 5-5-6 OVA ppm 300 1000+ 1000+ ;ampler Type 3S - Driven Split Spoon >i{ - Pressed Shelby Tube DST - Ostenburg Piston Sampler DEN - Denison Core Barrel Sampler SPT - Standard Penetration Test (ASTM D 1586-84) BORING NO. Project No. Client: Location: 600 250 EA-2 80005.16 Exxon Company, U.S.A. Freedom Drive Charlotte, NC (4-2094) Surface Conditions: Paved Lot Downgradient from Tank SOIL DESCRIPTION: Red Silty Clay with Some Weathered Feldspar Limonite Staining and Magnesium Fill Same as Above, Except Relic Foliation Present and More Weathered Feldspar Strong Hydrocarbon Odor Same as Above, More Magnesium Fill Strong Hydrocarbon Odor Tan to Olive Green Silty Clay with Weathered Feldspar, Limonite Staining and an Abundance of Magnesium Fill Olive Green Silty Clay with limonite Staining Magnesium Fill, Weathered Olivine and Very Fine Sand Drilling Method: Sampling Method: EA Geologist: D tiller: Hollow Stem Auger Split Spoon Stewart Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY, INC. (704) 521--8713 Charlotte, North Carolina SOIL BORING LOG SE 2 OF 2 irdinates: N/A iriace Elevation: tng Below Surface: ;erenoe Elevation: :ference Description: in Date: 11-29-90 !alp. Date: 11-29-90 'eater: ' Sample No. 5 Type Dptih 25 30 35 40 45 Inch Drvn 50 Inch Revd Blows/6* OVA Ppm L `Sampler Type 'SS - Driven Split Spoon SH - Pressed Shelby Tube OST - Ostenburg Piston Sampler • DEN - Denison Core Barrel Sampler SPT -- Standard Penetration Test (ASTM D 1586-84) BORING NO. Project No. Client: Location: EA-2 • 80005.16 Exxon Company, U.S.A. . Freedom Drive Charlotte, NC (4-2094) Surface Conditions: Paved Lot Downgradient from Tank SOIL DESCRIPTION: Boring Terminated at 25 Feet Screen 25 to 10 Ft Riser 10 to 0 Ft Sand Pack 25 to 8 Ft Bentonite 8 to 6 Ft Grout 6to0Ft Drilling Method: Sampling Method: EA Geologist: Driller: Hollow Stem Auger Split Spoon Stewart Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY, IN•C. (704) 521-8713 Charlotte, North Carolina SOIL BORING LOG 1 OF 1 1idinates: N/A fface Elevation: ing Below Surface: rence Elevation: `erence Description: t Date: 11-29-90 asp. Date: 11-29-90 ather: BORING NO. Project No. Client: Location: EA-3 80005.16 Exxon Company, U.S.A. Freedom Drive Charlotte, NC (4-2094) Sample Inch Drvn Inch Rcvd Blows/6' OVA ppm Surface Conditions: Grass Area Behind Station, Downgradient Waste Oil Tanks o. Type Dpth SOIL DESCRIPTION: 0 1 SS ;g/$ { • 18 18 7-12-15 2 Red Silty Clay with Some Weathered Feldspar �. F•• Limonite Staining and Magnesium Fill 2 SS % � ,' . `4;` �, 0,. 18 18 5-8-10 4 Reddish Tan Silty Clay with Weathered Feldspar Limonite Staining and Magnesium.Fill 3 SS :.f 18 18 7-4-4 8 Same as Above 4 SS '" ` 18 18 5-8-10 5 Olive Green Silty Clay with Very Fine Sand • is Magnesium Fill and Limonite Staining 9 - Stringers - Boring Terminated at 20 Ft. - Screen 20 to 5 Ft Bentonite 3 to S Ft 25 Sand 20 to 3 Ft Grout 2 to 0 Ft ►mpler Type 5 - Driven Split Spoon 1- Pressed Shelby Tube 3T - Ostenburg Piston Sampler - Denison Core Barrel Sampler 2T - Standard Penetration Test (ASTM D 1586-84) Drilling Method: Sampling Method: EA Geologist: Driller: Hollow Stem Auger Split Spoon Stewart Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY,CarINC. (704) 521-$713 lina SOIL BORING LOG aE 1 OF 2 rdinates: NIA rface Elevation: ing Below Surface: ''erence Elevation: :Terence Description: st Date: 11-29-90 rnp. Date: 11-29-90 eather: Sample No. 1 2 3 I. 4 Type SS 5 SS SS SS SS Dpth Inch Drvn inch Rcvd 18 18 18 18 18 18 18 18 ■ 6 Blowsl6' 8--11-1 S 18 4-4-6 4--3--4 3-4-5 4-7-8 OVA ppm Sampler Type SS - Driven Split Spoon . SH - Pressed Shelby Tube OST-.Ostenburg Piston Sampler DEN - Denison Core Barrel Sampler SPT - Standard Penetration Test (ASTM D 1586-84) BORING NO. Project No. Client Location: EA-4 80005.16 Exxon Company, U.S.A. Freedom Drive Charlotte, NC Surface Conditions: Paved Lot, Upgradient SOIL DESCRIPTION: 1 Red Silty Clay with Some Weathered Feldspar Limonite Staining and Magnesium Fill 0 Same as Above 0 Same as Above, Saprolite 1 0 Same as Above, Except Relic Foliation, More Magnesium Fill in Weathered Feldspar; Saprolite Olive Green Silty Clay with Very Fine Sand Magnesium Fill and Limonite Staining Drilling Method: Sampling Method: EA Geologist: Driller: Hollow Stem Auger Split Spoon Steward Williford Lake Norman Well Drilling EA ENGINEERING, SCIENCE & TECHNOLOGY,dotte, North INC. (704) 521-8713 lina SOIL BORING LOG 3E 2 OF 2 ordinates: N/A Irface Elevation: ding Below Surface: Terence Elevation: ;Terence Description: Ft Date: 11-29-90 imp. Date: 11-29-90 eathen BORING NO. Project No. Client Location: EA-4 80005.16 Exxon Company, U.S.A. Freedom Drive Charlotte, NC No. Sample 'Inch Inch Blowsl6" OVA Drvn Revd PPm Type rDpth 25 30 35 40 45 50 , Sampler Type SS - Driven Split Spoon SH .. Pressed Shelby Tube OST - Ostenburg Piston Sampler DEN - Denison Core Barrel -Sampler SPT - Standard Penetration Test (ASTM D 1586-84) Surface Conditions: Paved Lot, Upgradient SOIL DESCRIPTION: Boring Terminated at 25 Ft Drilling Method: Sampling Method: EA Geologist Driller. Hollow Stem Auger Split Spoon Steward Williford Lake Norman Well Drilling 5941rdW—S.OWG 2/1 1-1 CH/r14 1°� 2' X 2' CONCRETE PAD NEAT CEMENT GROUT —fi--� TOP OF BENTONITE (FT.) BOTTOM OF BENTONITE (FT‘) 1_ .Z."_DIA. SCH. 40 PVC RISER PIPE, LENGTH TOP OF SCREEN (FT.) 20 ' DEPTH TO GROUND WATER (Fr.) 21.101 SCHEDULE 40 PVC THREADED FLUSH JOINT 0.01" MILL sLd}TTED WELL SCREEN WASHED SAN) PACK BOTTOM OF SCREEN (FT.) _35 TOTAL DEPTH OF BORING (FT.) 35 = BOREHOLE DIA. (IN.) 5 78 8" DIAMETER BOLT DOWN WELL COVER WATER TIGHT, LOCKABLE WELL CAP PVC END CAP MW-5 Interval (feet) Type! Number VOCs (ppm) Sample Description 5 MW Red silty CLAY, with some weathered feldspar limonite staining and manesium fill. 10 MW Same as above 15 MW Same as above, strong odor 20 MW Tan to Light Brown clayey SILT, moderate plasticity, soft, no sfainina. moderate odor. moist 25 MW 380 Tan to light gray CLAY, high plasticity, soft, no staining mild odor, moist. 30 MW 200 Gray white silty SAND, low plasticity, no staining moderate odor, moist. quartz, feldspar. PWR Granite. 35 MW 120 Brown fine grained sandy SILT, low plasticity, slight odor, no staining, moist. DATE 1-16.02 DRILLING METHOD ROLLER CONE DRILLING CO SAEDACCO TOP OF CASING ELEVATION (ft.) 96.52 DRILLER ROBERT MILLER LOG 6Y THOMAS HEDRICK EXXON 4•2094 • 3721 FREEDOM DRIVE NORTH CAROLINA MW-5 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM Environmental Resources ERM Management 'Mk) `k)' S WELL CONSTRUCTION.RECORD North Carolina - Department of Envirotuaent and N esources - Division of Water Quality - Groundwater Section n WELL COnfutCTOR (rNDIVW UAL) NAME �(prfat) ,a -lr/�,)C, 14 �is/ L1' Ej CERTIFICATION ri WELL COivTRACTOR COMPANY NAME V i E,M rC / PHONE NPO,<bL-J ) 2 I STATE WELL CONSTRUCTION PERMIT# ASSOCIATED WQ PERMIT# (if applicable) (if applicable) 1. WELL USE (Check Applicable Box): Residential 0 Municipal/Public L7 Industrial 0 Agricultural 0 Monitoring ®'.—Recovery 0 Heat Pump Water Injection 0 Other 0 If Other, List Use; 2. WELL LOCATI Nearest To County M ec'kC eiv.ise E'� (Street Name, Numbers, Cornsauusity, Subdivision, Lot No., Zip Code) 3. OWNER: � 6. '22' ee (degteeslmltnlreslseconds) Address - i�($ i cloin • j'. Latitude/longitude source:0GPS0Topographic map oom,(Street or Rouse No.) (check box) GQi✓ Ai.0 PEPTi� PRILLING LOG City or Town State Zip Code From o FormatioaDesc on (), �J !, SPA . Si �� A� ter- Phone number1 r 7` 4. DATE DRILLED / f (4' " O i .5. TOTAL DEPTH: `c'` 6. DOES WELL REPLACE EXISTING WELL? YES 0 NO IE 7. STATIC WATER LEVEL Below Top of Casing: _ FT. (Use"." if Above Top ofCaSing) S. TOP OF CASING IS () FT. Above Land Surface" "Top of casing terrafnzttd et/or below land surface requires a variance in accordance with ISA NCAC 2C .DI16. 9. YIELD (gpm): METHOD OF TEST I0. WATER ZONES (depth): Topographic/Land setting DRidge L]Slope 1]ValIey era.t (chock appropriate box) Latitude/longitude of well location 11. DISINFECTION: Type Amount 12. CASING: Wall Thickness Dept, 1 Diie oete: or Weight/FL 4aterial Franz . To Mf5' FL 9 rl �k 90 rat:-, From. To Ft_ From To Ft 13. GROUT: Depth ateria1 --Method From 0 To _1/ Ft. %G90 1 4 Frar>_ To Ft.._ 14. SCREEN: • Di peter Slot Sic te,iet Front 25- `' To �3 Ft in. ().4) in. L// From To Ft._in. in. 15. SAND/GRAVEL PACK: , Depth ---�--$�--Material From %�� To t3S Ft. . 5 PCr., 5-9/i1 From_ To Ft. 16. REMARKS: , ' carom efe c L t 5 t l' Ta 1, ' LOCATION SKETCH Show irectioa and distance in miles from at least two S : to Roads or County Roads. include the road numb - and common rogd names. Kgeezom DR. hvig- 46- I DO HEREBY CER CONSTRUCTION S ..rlT r IS WELL WAS CONSTRUCTED IN ACCORDANCE WITH ISANCAC 2C, WELL '41 AND THAT A COPY OF THIS REC RD HAS BEEN PROVIDED TO THE WELL OWNEIL , ' ' %-. t 7 -,o Z_ SIGNATURE F PERSON CONSTRUCTING THE WELL DATE Submit the original to the Division or Water Quality, Groundwater Section, 1636 Mail Service Center -Raleigh, NC 27699-1636 Phone Na. (919) 733-3221, within 30 days. GW-I REV. 07/2001 53411AW--B.BWG 2/15/02 1-1 CH/I i• 2' X 2' CONCRETE PAD 8° DIAMETER BOLT DOWN WELL COVER WATER TIGHT, LOCKABLE WELL CAP ;iiE?k`"a1_ — &ISM ii L NEAT CEMENT GROUT ��— TOP OF BENTONITE (FT.) 2L BOTTOM OF BENTONTTE (Fr.) 23 2.",DIA. SCH. 40 PVC RISER PIPE, LENGTH TOP OF SCREEN (FT.) 25 DEPTH TO GROUND WATER (FT,) 29.0441 SCHEDULE 40 PVC THREACED FLUSH JOINT 0.01" MILL SLOTTED WELL SCREEN WASHED SAND. PACK BOTTOM OF SCREEN (FT.) 40 TOTAL DEPTH OF BORING (FT.) 40 ii BOREHOLE DIA. (IN.) 5 718 PVC END CAP MW-6 Interval (feet) Sample Type! Number VOCs (Ppm) Sample Description 5 GP 42 Brown silty SAND, no plasticity, soft, no staining, no odor. dry. 10 GP 0 Red CLAY, mottled, manganese, dance, no staining, no odor, dry. 15 GP 10 Red silty CLAY, moderate plastic, no odor no staininq,manganese, dry 20 GP 20 Same as above 25 GP 10 Brown orange clayey SILT, moderate plastic, manganese, no odor, no staining, moist soft, feldspar. 30 GP 20 Same as above 35 GP 20 Same as above 40 GP 22 Brown silty CLAY, moist manganese, no odor, no staining. soft: highly plastic. DATE 1-16-02 DRILLING CO. SAEDACCO DRILi R ROBERT MILLER DRUING METHOD ROLLER CONE TOP OF CASING ELEVATION (ft.) 105.17 LOG BY THOMAS HEDRICK EXXON 4-2094 3721 FREEDOM DRIVE CHARLOTTE, NORTH CAROLWA MW-6 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM Environmental Resources EEM Management WELL CONSTRUCTION RECORD North Carolina - Department of Environment and Nat L eisources - Division of Waste Quality - Groundwater Section WELL CONTRACTOR (INDIVIDUAL) NAME (print) I L . 7lL LE CER CATlon x____ WELL CONTRACTOR COMPANY NAME // Ea.M PRONE a PG7S1 J'✓ '— 9/ 7. STATE WELL CONSTRUCTION PERMfT# ASSOCIATED WQ PERMTT# (if applicable) (if applicable) 1. WELL USE (C1 ck Applicable Box): Residential 0 Municipal/Public ❑ Industrial 0 Agricultural Monitoring L ' Recovers' CI Scat Pump Water Injection 0 Other 0 If Other, List Use 2. WELL LOCATIO 1.r s� e.:Lt Nearest own:_ .0 P1'c `r — County /J ed i (Street Name, Numbers, Community, Subdivision, Lot No., 23p Code) 3. OWNER. CY ry ciem ee Address is ttet or Route No.) City or Town State Zip Coda Area code -phone number Topograghic/l and setting ❑Ridge MSlope ❑Valley DF1at (check appropriate box) Latitude/longitude of well location (degleesimioiteth ec0Ad6) Latitude/longitude source:0GPSDTopographic map (check box) DEFT DRILLING LOG $ C) TQ TWFormatio3 p / C ' Ilan 4. DATE DRILLED / " /6 " a 5. TOTAL DEPTH. 'f0. 6, DOES WELL REPLACE EXISTING WELL? YES 0 NO 0 7. STATIC WATER LEVEL Below Top of Casing: _FT. (Use "+" if Above Top of Casing) 8. TOP OF CASING IS 0 FT. Above Land Surface* 'Tap of rasing terminated aUer below land surface requires s variance in accordance with ISA NCAC 2C .0113. 9 YIELD (gpm): _ METHOD OF TEST 10. WATER. ZONES (depth): 1.1. DISINFECTION: Type . 12. CASING: Dep Front_ el To , Amount Wail 'Ihickaless 8meter or Weight/Ft Material Ft. Scil4 o TVG, From To FL---Y— From�.To Ft. . ' • 13. Depth J ;1Ma1`ijj yo ¢� From ic, From 0 To FL 'Floe I Erato_ To Ft - 14 SCREEN: , Depth . Diameter Slot Size •Material From �K . To 4 O Ft. I" in_ O. G d in. V From_ To Ft. in. in. 15. SAND/GRAVEL PACK: � � eriai From_ LIt c�Fo.'.. L....._ f.. `at SRs From_To Ft. 16. R.EMAR1 S: a+ e ir0N de GI, l's 2,' To 22 ' )1 LOCATION SKETCH Show direction and distance in mules from at least two State Roads or County Roads. Include the toad numbers d common ro • u names. 1 DO HEREBY CERTIFY THAT THIS WAS CONSTRUCTED IN ACCORDANCE WITH 1SA NCAC 2C, WELL CONSTRUCTION STANDARDS A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNATURE OF PEP ON CONSTRUCTING THE WELL DATE Submit the original to the Division of Water Q':slity, Groundwater Section, 1636 Mall Service Center -Raleigh, NC 276994636 Phone No. (919) 733-3221, wi:hlti 20 days. GW-I REV. 07/2001 5941 MW-7.DWC 2/i S/02 2' X 2' CONCRETE PAD NEAT CEMENT GROUT TOP OF BENTONITE (FT.) 11 BOTTOM OF BENTONITE (FT.). 13 B" DIAMETER BOLT • DOWN WELL COVER WATER TIGHT, LOCKABLE WELL CAP iiiEff.MMECIR=ITIFSIM OW! 2"DIA. SCH. 40 PVC RISER PIPE, LENGTH TOP OF SCREEN (FT.) 15 DEPTH TO GROUND WATER (FT.) 16.95 SCHEDULE 40 PVC THREADED FLUSH JOINT WELi..01 MILL SLOTTED SCREEN WASHED SAND PACK BOTTOM OF SCREEN (FT.)' 30 TOTAL DEPTH OF BORING (FT.) 30 BOREHOLE DIA. (IN.) 5 7/8 A 40 PVC END CAP MW-7 Interval (feet) Sample Type/ Number VOCs (pnm) Sample Description 5 MW 55 Red silty, CLAY, no odor, no staining, moderately plastic. dry 10 MW 38 Red orange silty CLAY. no odor, no staining, highly plastic. drv. 15 MW Q0 Brown tan silty SAND, no odor, no staining, not plastic, slightly moist. 18 Hit Rock 20 MW Fine grained SCHIST, salt and pepper, size from lrnm to 10 mm. quartz. feldspar. 25 MW Same as above 30 MW Same as above DATE 1-17-02 DRILLING CO. SAEOACCO DRILLER ROBERT MILLER DRILLING METHOD _ROLLER CONE TOP OF CASING ELEVATION (ft.) 91.33 LOG BY THOMAkSJ1El}RICK FXXON 4-2094 3721 FREEDOM DRIVE CHARLOTTE, NORTH CAROLINA MW-7 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM nvi ronmenta1 Resources EgM Management WELL CONSTRUCTION RECORD North Carolina - Department of Environment and Na ures - Division/of Wateer�Quality - Grotl ndwater S ectio���n/// �]� WELL CONTRACTOR (IND[v.IDUAL) NAME (print) /► , I . /' /1L' € CERTIFICATION # : fir, WELL CONTRACTOR COMPANY NAME .,�r7�Di PHONE # . ` 6 STATE WELL CONSTRUCr1ON maim, ,ASSOCIATED WQ PERMIT# (if aoolicahle) (if aaalicable) 1. WELL USE (Check Applicable Box): Residential 0 Municipal/Public ❑ Industrial ❑ Agrict1ltural [7 Monitoring 63VRccavery 0 Heat Pump Water Injection ❑ Other Cl If Other, List Use 2. WELL LOCATION:,,,`� ,,,,� Neale Town; C ero County '`VI j prey DR, �. (Street Name, Numbers, Community, Subdivision. Lot No., Zip Code) CAiela City or 'DAM State ' Zlp Code Arta code- none 'lumber , 4. DATE DRILLED- /r' S. TOTAL DEPTH: '.--SC' 6. DOES WELL REPLACE EXISTING WELL? YES 0 NO ki 7. STATIC WATER LEVEL Below Top of Casing: FT. (Use "+- if -Above Top of Casing) 8. TOP OF CASING IS FT. Above Land Surface* 'Top of easing terminated odor below land surface requires a variance in accordance with ISA iYC AC 2C .011s. 9. YIELD (gpm): METHOD OF TEST 10. WATER ZONES (depth): 3. OWNER: C G� _ r ti47 eie Address Z-4 I" fry JTvp+ trees or G a No.) 11. DISINFECTION: Type 12. CASING: Depth ., Diameter From C) _To 1S .Ft. ¢ " From To Ft. From To_ Ft. 13. GROUT: Depth From () To Ft. From To, ,Ft. 14. S Depth Diameter Slot Vie From__ To ...51Ft Au in. 0.G 1 in. From To Ft in. in. 15. SAND/GRAVEL PACK: Size Fro,, n>f3t Depth.,_ ---!.Ft • From^, .._To Ft, Amount Wall Thickness cfa etho i ,tea 1N 16. REMARKS' Material A S-iL G4.J-4. Topographic/Land setting DRidge DSlope DValley (Ft (check appropriate box) Latitude/Iottgitude of well location (degleethrdnutes(seeaads) Latitude/longitude source:DGPS0 topogaphic map (check box) DEPTH MULLING LOG From FQ A, lion DesgriiEtir LOCATION SKETCH Show direction and distance in miles from at least two State Roads or County Roads. Include the road numbers ar mon road naives. S jrr'o /3 ` 1/ tDi Mw'i rree.6CM D . I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 1 SA NCAC 2C, WELL CONSTRUCTION S, AND THAT A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNA OF PERSON CONSTRUCTING THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section, 1636 Mali Service Center -Raleigh, NC 27699.1636 Phone No. (919) 733-3221, within 30 days. GW-1 REV. 07/2001 .. A/• ...r..: 2' X 2' CONCRETE PAD NEAT CEMENT GROUT TOP OF BENTONITE (FT.) :10 BOTTOM OF BENTONITE (FT.) -.2 3201A. SCFI. 40 PVC RISER PIPE. LENGTH TOP OF SCREEN (FT.) 14 DEPTH TO GROUND WATER (FT.) 17.96 e" :DIAMETER BOLT DOWN WELL COVER WATER TIGHT, LOCKABLE WELL CAP SCHEDULE 40 PVC THREADED FLUSH JOINT 0.01" MILL SLOTTED WELL SCREEN WASHED SAND PACK BOTTOM OF SCREEN (FT.) 24 TOTAL DEPTH OF BORING (FT.) . 24 BOREHOLE DIA. (IN.) 5 7/8 EXXON 4-2094 3721 FREEDOM DRIVE NORTH CAROLINA 111 MW-8 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 40 Red silty CLAY, dence, no odor, no staining, moderatty plastic. dry. manganese 10 GP 24 Light brown silty CLAY, no odor, no staining, moist, moderately plastic. 15 GP 22 Light brown clayey SILT, moist no odor, no staining, slightly plastic 20 GP 40 Light brown silty CLAY, no odor, no staining, moist, moderately plastic. 25 GP 40 ,Same as above PVC END CAP DATE 1--17-02 DRILLING METHOD ROLLER CONE DRIWNG CO. SAEDACCO TOP OF CASING ELEVATION (ft.) 92.59 DRILLER RO9ERT MILLER MW-8 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM LOG BY JHOMAS HEDRICK Environmental Resources ERM Management m EA) -( WELL CONSTRUCTION RECORD North Carolina - Department of Environment and Na esourees- Division of Water Quality - Groundwater Section WZLL CONTRACTOR. (INDIVIDUAL) NAME (print) / Olee �Z1 7 )/1' . CERTIFICATION N WELL COrrimiCTOa COMPANY NAME �R !�lllC.•�-"�/ PHONE iF ; it S& T�1 'O STATE WELL CONSTRUCTION PERMIT4 (if awIicable) ASSOCIATED WQ PERMITO if •licable I. WELL USE (Check Applicable Box): Residential ❑ Municipal/Public ❑ Industrial 0 Agricultural ❑ Monitoring kecovery 0 neat Pump Water Injection El Other Li If Other, List Use 2. WELL LOCATiOA�i Nears 'o [ 03 �� (Street Name, Numbers, Community, Subdivision, Lot No, zip Code) County edievvivrc 3. OWNER: .k� e Address �fZIO City or Town State Zip Code Arm coda- Plume number 4. DATE DRILLED 5. TOTAL DEPTH: oc-L 6. DOES WELL REPLACE EXISTING WELL? YES ❑ NO 7. STATIC WATER LEVEL Below Top of Casing: T. (Use "+" if Above Top of Casing) 8. TOP OF CASING IS 10IP FT. Above Land Surface"' *Top or easing terminoted otfor below land surface requires a eariaoce in accordance with ISA NCAC 2C .0118. 9. YIELD (gpm): METHOD OF TEST 10. WATER ZONES (depth): Topographic/Land setting [Midge ❑Slope ❑Valley [fit (check Appropriate box) Latitude/longitude of well location (degrees/minutes/seconds) Latitude/longitude source:❑GPS0Topographic map (5tre_t or Route No.) (cheek box) Ci N G- DEPTIi DRILLING LOG From To Formation Description (3 Scf 11. DISINFECTION: Type 12. CASING: th From ( To /.'.� From__ To From _ To 13. GROUT,,,,,' Depth From To IL' From.. To 14. SCREEN: Depth From ? / - To y From To I5. SAND/GRAVEL PACK Demeter Ft'f Mount Wall Thiclmess or Weight/Ft. bAtcrial Ft tt Ft .)"F i t7ef�e7111/0 Ft. Ft Diameter Slot S�se II" Di in. d. _ n. <✓ Ft. Fro 1 T th -t t F in, in. Size Material LOCATION STETC14 Show direction and distance in miles from at least two State Roads or County Pcieds. Include the road numhersd common roatames. `•o ti From To _ . Ft16. REMARKS: _ • oNI CL. IPS Q' I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C, WELL CONSTRUCTION STANDARDS, ANF� COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNATURE OF PERSO CONSTRUCTING THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section,1636 Mail Service Center -Raleigh, NC 27699-1636 Phone No. (919) 733-3221, within 30 days. GW-1 REV. 07/2001 ll 4iW9.0Wt:" ..M1/6/C12- 1=I • -.bi/AM 2' X 2' CONCRETE PAD 8" DIAMETER BOLT DOWN WELL COVER WATER TIGHT, LOCKABLE WELL CAP NEAT CEMENT GROUT TOP OF BENTONITE. (FT.) 13 BOTTOM OF BENTONITE (FT.) 15 2 "DIA. SCH. 40 PVC RISER PIPE, LENGTH TOP OF SCREEN (FT.) 17 DEPTH TO GROUND WATER (FT_) 23.75 A A SCHEDULE 40 PVC THREADE FLUSH JOINT 0.01" MILL. SLOTT WELL SCREEN WASHED SAND BOTTOM OF SCREEN (FT.) 32 DTAL DEPTH OF BORING (FT) 32 BOREHOLE DIA. (IN.) 9.25 FORMER E7ON 4-2094 3'721 FREEDOM DRIVE :IIARLOTTE, NORTH CARMEN ED ACK i PVC END CAP MW-91GP-1 Interval {feel) Sample Typed Number VOCs (ppm) Sample Descd)prion 2 GP 0 Red -Brown silty CLAY, dry, demo, some mica, no odor 4 GP 0 Same as above 0 GP 20 Same as above, mild odor 8 GP 225 Same es above, strong odor 10 GP 100 Samo as above, strong odor 12 GP 200 Same as above, strung odor 14 _ GP 4.000 Same as above, strong odor 18 GP 10,000 Soma as ahoye, moist 18 GP 2,000 Brown CLAY Mtn mica, motet, strong odor 20 GP 10,000 Tan silty CLAY, melee, dense, strong odor 24 GP — Same es above, wet 28 GP — Sams as above, wet 32 GP — Some as above. wet - DATE 6/12/02 DRILLING METHOD HOLLOW STEM AUGER DRILLING CO. SAEDACCO TOP OF CASING ELEVATION (ft) gt3.47 DRILLER STEVE POLONIEWICZ MVP-9 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM LOG BY @. BAGGFT Environmental Resources ERM Management fnL)1 WELL CONSTRUCTION RECORD North Carolina - Department of Environment and Natural Resources - Division of Water Quality - Groundwater Section /I WELL CONTRACTOR (INDIVIDUAL) NAME (print) ,_5' TE-t��' • POW L 1/ '/G CERTIgICATION # 27. Fr", WELL CONTRACTOR COMPANY NAME 56/34 Ltd PHONE # (7( ,Icsci —17 i. STATE WELL CONSTRUCTION PEILMITfi A.) C--- ASSOCIATED WQ PERMIT# _ (ifglicabie) (ifapplicable) I. WELL USE (Check Applicable Box): Residential 0 Municipal/Public 0 Industrial Cl Agricultural 0 Monitoring Er -Recovery 0 Heat Pump Water Injection ❑ Other ❑ If Other, List Use 2. • WELL LOCATION: Nearest Town: al 47 r • County f r1& 1L 35 P2 Grp /�►� ,J2 r ut (Street Name. Numbers. Community. Subdivision, Lot No.. Zip Code) 3. OWNER: rar►� i}�1D�LJ Address 3. 70 qi P/i,`.-r 00Vh I1(LI CAL:. (Street or Route No.) CH Art( t City or Town State Zip Code Topographic/Land setting I:3Ridge ❑Slope 0Valley ❑Flat (check appropriate box] Latitude/longitude of well location (degrees/minutes/seconds) Latitude/longitude source:0GPS0Topographic map (check box) DEPTH DRILLING LOG From To Formation Description Area code- Phone number C.) t0 ,,on .qie ]r Gj 44 4. DATE DRILLED 6 - Id.- -0 a. r n • .1-U t 5. TOTAL DEPTH: 1� r :',...).03 2 i t r t 6. DOES WELL REPLACE EXISTING WELL? YES CINO Er" 7. STATIC WATER LEVEL Below Top of Casing: FT. (Use "+" if Above Top of Casing) _ 8. TOP OF CASING LS 0 - FT: Above Land Surface* •Top of easing terminated at/or below land surface requires a variance in accordance with 15A NCAC 2C .O11 s. 9. YIELD (gpm): METHOD OF TEST 10. WATER ZONES (depth): l I . DISINFECTION: Type_ Amount 13. CASING: Wall Thickness Depth r Diameter or Weight/Ft. Material From 0..4 To_ 1 '7- Ft._,.. _. 4G/fteQ pc)( - From To Ft. From To Ft. 13. GROUT: r Depth t Material Method Frorn_l__ . To J g Ft. por'-CAl; f.J0 Till l+''re- ij From To Ft. i� 14. SCREEN: Depth t Diameter Slot Size Material From I) t To Sot Ft. art .in. -010 in. rJ - From To Ft. in. in. IS. SAND/GRAVEL PACK: I Depth i Size Material on lF To 4,,?... Ft —S-t&( 7 M From_ To Ft. 16. REMARKS: LOCATION IKETCH Show direction and distance in miles from at least two State Roads or County Roads. Include the road numbers and common road names. rt J 3' Q • Q ht t. z I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRU D IN ACCORDANCE WITH I5A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THOPY OF S RECORD -HAS BEEN PROVIDED TO THE WELL OWNER SIGNATURE OF PERSON&UCTING THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section, 1636 Mail Service Center - Raleigh, NC 27699-1636 Phone No. (919) 733-3221, within 30 days. GW-1 REV. 07/2001 5941DW-1.DWG 2/15/02 1=1 CH(TH 2" WATER TIGHT LOCKABLE WELL CAP 2' X p2' cONCRETEAr r AD NEAT CEMENT GROUT -411prioll AdO fi4 , Idr UPPER WELL BORE DIA. (IN.) 9 7/8 6" PVC SURFACE CASING TO (Fr.) 65 DEPTH TO 2i.05 GROUNDWATER (Fr.) SCHEDULE 40 PVC RISER DIAMETER (IN.) LOWER WELL BORE DIAMETER (IN.) 5 7/8 TOP OF BENTONITE (FT.) 66 BOTTOM OF BENTONfTE (Er.) 68 TOP OF SCREEN (FT.) 70 SCHEDULE 40 PVC THREADED FLUSH JOINT .010" MILL SLOTTED WELL SCREEN BOTTOM 0P SCREEN (FT.) 80 BORINGEPTH OF (Fr.) 80 8" DIAMETER BOLT DOWN WELL COVER WASHED SAND PACK PVC END CAP DW-1 Interval (feet) Sample Type/ Number VOCs ' (ppm) Sample Description 5 SS Red slity CLAY, with some weathered feldspar limonite staining and manesium fill. 10 SS Same as above 15 SS Same as above. strong odor 20 SS Tan to Liq_ht Brown clayey SILT. moderate plasticity, 25 SS 380 Tan to tight gray CLAY, high plasticity, soft, no staining mild odor. moist. 30 SS 200 Gray white silty SAND, Iow plasticity, no staining moderate odor, moist, quartz, feldspar, PWR granite._ 35 SS 120 Brown fine grained sandy SILT, Iow plasticity, slight odor, no staining. moist. 40 SS 200 Brown Clayey SILT, saturated no odor, no staining, medium plasticity. 45 SS 180 Brown Silty SAND, saturated. slightly plastic, no odor no staininc{. 47 Hit Rock 50 BS Fine grained salt and pepper SCHIST. 55 BS Same as above 60 BS Same as above 65 BS Same as above 70 BS Same as above, quartz 30? 80 BS Same as_abave . quartz 50% DATE/DRILLED 1-18/1--19-02 DRILLING COMPANY SAEDACCO DRILLER STEVE POLONIEWICZ DRILLING METHOD ROLLER CONE TOP OF CASING ELEV. (Fr) 96.32 LOG BY THOMAS HEDRICK SON 4-2094 3721 FREEDOM DRIVE cnARLOWE, NOR= CAROLINA DW4 DRILLING LOG AND MONITOR WELL CONSTRUCTION DIAGRAM Environmental Resources ERNI Management WELL CONSTRUCTION RECORD North Carolina - Department of Environment and Natural Resources - Division of Water Quality - Groundwater Section WELL CONTRACTOR (INDIVIDUAL) NAMC (print) c45` t3t7!. b y G"-'16 CERTIFICATION# aeZ t1 WELL CONTRACTOR COMPANY. NAME 454 --plow PFIONE # ( STATE WELL CONSTRUCTION PERMIT# (iFaprtlicabte) ASSOCIATED WQ PER%IIT# (if applicable) 1. WELL USE (C ck Applicable Box): Residential 0 Municipal/Public 0 Industrial ❑ Agricultural 0 Monitoring Q Recovery 0 Heat Pump Water Injection 0 Other 0 If Other, List Use 2. WELL LOCATION: Nearest Town: Ghr-A✓LLC tTi - County Pit.,e're+zv-• g .t/G/ 2. (Street Name, Numbers, Community, Subdivision, Lot No., Zip Code) 3. OWNER: PU.2,hj3/L w- .-o,.7 .I?Ai/osv Address .r-gr.S CsJ P4rLZ5l f (L/t - (Strcet or Route No.) City or Town State Zip Code Arca code- Phone number •4. DATE DRILLED i- `Sri - 5. TOTAL DEPTH: fsb' 6. DOES WELL REPLACE EXISTING WELL? YES 0 NO 0 7. STATIC WATER LEVEL Below Top of Casing: FT. (Use "+" if Above Top of Casing) 8. TOP OF CASING IS C • C7 FT. Above Land Surface* 'Top of casing terminated aIfor below toad surface requires a variance In accordance with 1SA NCAC IC.e118. 9. YIELD (gpm): METHOD OF TEST 10. WATER ZONES (depth): 11. DISINFECTION: Type Amount 12. CASING: Wall Thickness Depth / Diameter or Weight/Ft. Material From 0,15 To 70 Ft. 1 % deliYE> 9✓C From To Ft. From _ To Ft. 13. GROUT: Depth f Material FroLL m To Ft, f0rir.,,wh From To Ft. 14. SCREEN: t Depth .t Diami jer Slot Size From 7U To Se" FL, 2 ,in. •o'r O in. From To FL in. in. 15. SAND/GRAVEL PACK: / Depth- / • Size Material From A e- To_ Ft. A/4v t. c 64 5.4.4.41 From To Ft. Method 16. REMARKS: Topographic/Land setting ❑Ridge. ❑Slopo ©Valley ❑Flat (check appropriate box) Latitude/longitude of well location (degrees/minutestscconds) Latitude/longitude source:❑GPS❑Topographic map (check box) DEPTH DR1LL1Ng LOG From To Formation Description • 0 — dfJ k(? LO- uS /lt3 s.4 --Y [� y- �u n 4b- 6L! ;0 -t L LOCATION SKETCH Show direction and distance in miles from at least two State Roads or County Roads. Include the road numbers and common road names. a 1 DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH I5A NCAC 2C, WELL CONSTRUCTION STANDARDS, AND THA ,A COPY OF THIS RECORD HAS BEEN PROVIDED TO THE WELL OWNER SIGNATURE PERSON CONSTRUCTING THE WELL DATE Submit the original to the Division of Water Quality, Groundwater Section, 1636 Mail Service Center - Raleigh, NC 27699-1636 Phone No. (9t9) 733-3221, within 30 days. GW-1 REV. 07/2001 MW-9/G P-'1 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 . GP 0 Red -Brown silty CLAY, dry, dense, some mica, no odor 4 GP 0 Same as above 6 GP 20 Same as above, mild odor 8 - GP 225 Same as above, strong odor 10 GP 100 Same as above, strong odor 12 GP 200 Same as above, strong odor 14 GP 4,000 Same as above, strong odor 16 GP 10,000 Same as above, moist 18 GP 2,000 Brown CLAY with mica, moist, strong odor 20 GP 10,000 Tan silty CLAY, moist, dense, strong odor 24 GP — Same as above, wet 28 GP — Same as above, wet 32 GP — Same as above, wet GP-2 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown CLAY, dry, dense, no odor 4 GP 0 Same as above 6 GP _ 0 Same as above 8 GP 0 Same as above, soft 10 GP 0 Same as above 12 GP 250 Brown silty CLAY, dry, medium hardness, no odor 14 GP 20 Same as above 16 GP 100 Same as above, moist, mild odor 18 GP 0 Gray CLAY, wet, dense, no odor 20 GP 0 Same as above GP-3 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown silty CLAY, dry, dense, no odor 4 GP 0 Same as above 6 GP 20 Same as above 8 GP 80 Same as above 10 GP 250 Same as above, medium hardness no..odor 12 GP 400 Same as above, soft, mild odor 14 GP 30 Brown CLAY, dry, dense, mild odor 16 GP 10 Gray tan CLAY, moist, dense, some odor 18 GP 0 Gray silty SAND, wet, soft, no odor 20 GP 0 Same as above GP-4 Interval (feet) Sample Type/ Number VOCs (ppm) . Sample Description 2 GP 0 Red -brown CLAY, dry, dense, no odor 4 GP 40 Same as above 6 GP 70 Same as above 8 GP 100 Same as above 10 GP 150 Same as above, medium hardness 12 GP 200 Same as above, moist, 14 GP 130 Gray silty CLAY, moist, dense, no odor 16 GP 120 Same as above 18 GP 120 Tan CLAY, wet, dense, no odor 20 GP 110 Same as above GP-5 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown silty SAND, dry, soft, strong odor 4 GP 100 Same as above 6 GP 250 Same as above 8 GP 350 Same as above 10 GP 10,000 Tan -brown silty SAND, dry, soft, strong odor 12 GP 10,000 _ Same as above 14 GP 10,000 Red -brown silty CLAY with sand, dry, soft, strong odor 16 GP 10,000 Gray -white silty SAND, dry, soft, strong odor 18 GP 10,000 Same as above, moist 20 GP 10,000 Same as above GP-6 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown CLAY, dry, dense, no odor 4 GP 0 Same as above 6 GP 100 Same as above *8 GP 100 Red -brown silty CLAY, dry, softer, no odor 10 GP 100 Brown silty CLAY, dry, medium hardness, no odor 12 GP 85 Tan silty CLAY, moist, medium hardness, no odor 14 GP 30 Same as above 16 GP 0 Same as above, soft, mild odor 18 GP 120 Gray -tan silty CLAY, moist, medium hardness, mild odor 20 GP 120 _ Same as above GP-7 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown CLAY, dry, hard, no odor _ 4 GP ' 0 Same as above 6 GP 0 Same as above 8 GP 30 Same as above 10 - GP 40 Red silty CLAY, dry, hard, no odor 12 GP 2,000 Same as above 14 GP 8,000 Same as above, strong odor 16 GP 10,000 Same as above, strong odor 18 GP 9,000 Gray -tan silty CLAY, soft, moist, moderate odor 20 GP 100 _,Gray -tan silty CLAY, soft, moist, moderate odor GP-8 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 2 GP 0 Red -brown CLAY, dense, dry, no odor 4 GP 200 Same as above 6 GP 350 Same as above 5 GP 0 Same as above, mild odor 10 GP 200 Same as above, strong odor 12 GP 10,000 Same as above 14 GP 10,000 Same as above, strong odor, moist 16 GP 10,000 Same as above 18 GP 10,000 Tan silty SAND with day, moist, strong odor 20 GP 10,000 Brown silty CLAY, dense, moist, strong odor GP-9 Interval (feet) Sample Type/ Number VOCs (ppm) ` Sample Description 5 GP 64 Brown -red silty CLAY, slightly dense, moderately plastic, fill, mild odor 10 GP 41 Orange -tan clayey SAND, slightly dense, non -plastic, saprolite, mild odor 15 GP >10,000 Same as above interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 55 Red -brown sandy CLAY, moist, plastic, soft, fill material, intermixed with gravels, mild odor, 10 GP 880 Same as above 15 GP 410 Tan -red clayey SILT, soft, moist to wet, mottled, mild odor A 1]A&A Qnriral I role vie GP-11 interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 68 Red -brown sandy CLAY, dense, dry, non -plastic, fill material, mild odor 10 GP 610 Tan -red clayey SILT, dry, dense, mottled, saprolite, non• plastic, mild odor 15 GP 925 Tan silty SAND, loose, soft, dry, weathered rock, mild odor GP-12 Interval (feet) Sample Type/ Number VOCs (ppm) • Sample Description 5 GP 3.5 Red -brown sandy CLAY, dry, dense, slightly plastic, fill material, Intermixed with gravels, no odor 10 GP 3.1 Tan -red clayey SILT, dense, dry, non -plastic, mottled, saprolite, no odor 15 GP 12 Orange -tan silty CLAY, slightly dense, moist, plastic, mottled, no odor GP 13 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 12.0 Red -brown clayey SILT, dense, dry, fill, intermixed with gravels mild odor 10 GP 91.0 Tan -orange silty CLAY, dry, slight to moderately plastic, mild odor 15 GP 9,200 Same as above, moderate odor at 15' GP-14 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 21 Red -brown sandy CLAY, dense, dry, moderately plastic, few organics, fill, no odor 10 GP 144 Tan -orange silty CLAY, dry, slight to moderately plastic, mild odor 5 GP —1100 Sam b moderate odor-15' GP-15 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 57 Brown -red sandy CLAY, dense, dry, slightly plastic, fill material, few organics, no odor 10 GP 34 Orange -tan clayey SAND, moist, moderately dense, saprolite, slightly plastic, mottled, no odor 15 GP 48 Tan silty CLAY, soft, very plastic, moist, no odor GP-16 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 26 Red -brown sandy CLAY, dense, dry, slightly plastic, intermixed with gravels, fill material, no odor 10 GP 18 Orange -tan clayey SILT, moist, moderately dense, slightly plastic, mottled, saprolite, no odor 15 GP 43 Same as above GP-17 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 16 Red -brown sandy CLAY, dense, dry, moderately plastic, intermixed with gravels, fill material, no odor 10 GP 22 Tan -orange sandy SILT, loose, slightly moist, dense, mottled, saprolite, no odor 15 GP 31 White -tan clayey SILT, plastic, moist, heavily mottled, plastic, mild odor GP-18 Interval (feet) Sample Type/ Number VOCs (ppm) Sample Description 5 GP 45 Red -brown sandy CLAY, dense, dry, intermixed with gravels, slightly plastic, fill, no odor 10 GP 77 Red -orange clayey SILT, moderately dense, slightly moist, slightly plastic, saprolite, mild odor 15 GP 120 Same as above