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WI0300148_Regional Office Historical File Pre 2018 (2)
August 3, 2012 UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 RE: Final Report,- UIC permitW'I0300.148.._� BP Charlotte Terminal No. 4762 7401 Old Mount Holy Rd Charlotte, Mecklenburg County, North Carolina Groundwater Incident Numbers 06771, 15159, 15618, 17002, 17263, 17264, and 20622 URS Corporation — North Carolina, on behalf of BP Products North America, Inc., has prepared the attached Corrective Action Plan (CAP) Addendum. The CAP Addendum summarizes data through December 2011. A final sampling event was conducted in February 2012 as part;of UW permit W103.00,1,484or=injection of Epsom salts and bromide tracer at BP Charlotte Terminal No. 4762 (formerly Southeast Terminals). Tables 1 and 2 provide a summary of analytical data collected from June 2011 through February 2012, following injections from select wells. Figure 1 is attached for reference. Injectant material was delivered via direct push and soil borings grouted at the time of injection. N:oradditio- nal injection- is-planned_at this>time:;under:this permit_(WI:0300148)�- If you require further information or have any questions regarding this submittal, please contact me at (919) 461-1423. Sincerely, URS Corporation — North Carolina A), Margaret M. Ness Project Manager Attachments: Final Report (Corrective Action Plan Addendum) (2 copies) Table 1, Table 2, Figure 1 (2 copies) Cc: Greg Frisch, BP (via enfos) URS Site File 38436729 URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-46-1415 RECE(VEDIDENRIDWQ AUG 0 6 2012 Aquifer Protection Section RECEIVED/DENWDWQ INJECTION EVENT RECORD AUG 0 6 2012 North Carolina Department of Environment and Natural Resources — Division w c` v Section Permit Number WI 0 300148 1. Permit Information BP Products North America Inc. Permittee Paw Creek BP Terminal Site (BP 4762) Facility Name 7401 Old Mt. Holly Rd Charlotte, NC Facility Address 2. Injection Contractor Information Margaret Ness/URS Corporation Injection Contractor / Company Name 1600 Perimeter Park Dr. Street Address Suite 400 Morrisville NC 27560 City State Zip Code (919 ) 461-1423 Area code — Phone number 3. Well Information 10 SBs Area 1 Number of wells used for injection 10 SBs Area 2 Al-I1 through -I10 and Well names A2 - I1 through - I 10 Were any new wells installed during this injection event? © Yes n No 20 soil borings If yes, please provide the following information: Number of Monitoring Wells Number of Injection Wells NA-20 soil borings Type of Well Installed (Check applicable type): ❑ Bored ❑ Drilled VI Direct -Push ❑ Hand -Augured ❑ Other (specify) Please include two copies of form GW-1 b for each well installed. Were any wells abandoned during this injection event? X❑ Yes n No 20 borings at time of injection If yes, please provide the following information: Number of Monitoring Wells Number of Injection Wel1sNA-20 soil borings Please include two copies of the GW-30 for each well abandoned. 4. Injectant Information Magnesium Sulfate & Bromide tracer Injectant Type Mg Sulfate @ 2,000 mg/L ConcentrationBromide tracer @ 1,000 mg/ If the injectant is diluted please indicate the source dilution fluid. municipal water supply 1640 gal Area 1 Total Volume Injected 2700 ga 1 Area 15 - 400 gallons Volume Injected per well per soil boring 5. Injection History Injection date(s) 5 / 16 - 5 / 2 3 , 2011 Injection number (e.g. 3 of 5) 1 of 1 Is this the last injection at this site? ❑X Yes ❑ No I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITHIN THE STANDARDS LAID OUT IN THE PERMIT. JI;z SIGNATURE OF INJECTION CONTRACTOR DATE PRINT NAM F PERSON PERFORMING THE INJECTION Submit the original of this form to the Division of Water Quality within 30 days of injection. Attn: UIC Program, 1636 Mail Service Center, Raleigh, NC 27699-1636, Phone No. 919-733-3221 Form UIC-IER Rev. 07/09 s 0 a 0 MW65 U V. U V. U U U. U 1 MW65 N N I MW26 N CT I MW26 N O1 N CT N CT N CT N ON N CN MW26 N CN 1 MW26 MW-21 N �, N ., N r NJ MW21 N -- N -, N --' N -, N -- N -- N ., N -, MWO5 MWO5 O U O V. MWO5 MWO5 O U O U O U MWO5 MWO5 O U MWO5 _I MWOS1 Unit: Sample IDlSamp.Date NJ .., CN N O IJ 11/22/2011 CO ..-. C� t N O ,-, +] NJ N O .- D1 N W ,, N O -- 00 N O .- O1 00 N O -, N 00 N O O N 00 N O O 8/30/20101 2/16/2012 11/22/2011 CO ..-. CT „ N O •--' -4 N -- „ N O •- CT N W „ N O .- O`1 00 N O *. 12/8/2010 ,, VD N O ,-+ O N VD N O CD VD 6/4/2009 12/3/2008 W N O CD CO N . N O CD-, �l 6/14/2007 N .—j. CT N O_ N r N N N CD ., 8/16/2011 -4 N N CD -- CT N w N CD -+ 00 N CD ., N 00 N CD O a1 l0 N CD O N,, 1p N CD CD �D ? N C) C) VD 12/3/2008 CT .p N CD CD.-' 00 12/4/20071 6/14/2007 2/16/2012 -- N N N CD r- 00 ,-+ 01 N CD --' +l IJ N CD .-. 6/23/2011 1 O„ 0000 N CD .+ N 00 N O_ O CT 4D N CD O N �D N CD CD VD A N CD CD VD 12/4/2008 6/3/2008 12/4/2007 6/14/2007 13,0001 14,0001 15,000 Oh O O O U O O O N O O O W O O O 21,000 00 O O O 17,000 200 �. O 290 W O O 290 230 220 CD 00 O — .-- 410 .- VD O 4.5 w CO N 174 4,3001 00 U O O In 0 O O v. 0 O O 14,0001 11,000j u D O CD O 14,000 U C. O O .p W O O 4,400 5,000 `. '-h O1 O O O Oo O O �-. 30 A. N O .N N O N O 39 'C CT O N J ti 9.8 O ' ti N U ,-( 0.56 J <10UJ 3.4 J V. VD ug/L Benzene ..+ U 0 0 N A 0 0 .+ �I O 0 .r �] CD 0 .... �O CD CD .-. LA CD ,CD ... LAO� CD CD ... CD CD ... G1 CD CD .-. �--• CD CDO. 4.1 00 .A. vp La 0o •--' A 0o U 44 2.7 '""' w ti w LA A CD LA,, O �D CT N 360 470 1,200 .- N CD~O CD — u CD 810 390 CT ,_. CD 350 470 390 W 00 CD 572 CACDCDn CD4," W ,-IL.N U 55 49 45 W .-. .- C1 ,-. .-' CD n CD •- N CT ti 0 in 0 A .-+ 0 c', ,r 7.3 J LA iv ti C Toluene 2,000 2,200 2,000 N O O 2,000 1,4001 1,4001 2,400 2,400 N O O U 00 �l 24 N . —. U 58. 2.7 U 36 D ,. 8.5 n LA.- 'J • _ • �''� CT 8001 12001 .-..-. O O O O r. O O 1,4001 .-. 0 0 -- _ 0 0 1,300 �. O O .- O O .-. _ O O 1710 1350 J 170 1200 920 450 W 00 N .-' 4.7 Iv N 4> 28 J O, N• — .' 0 0 -4 470 ug/L Ethylbenzene U W O O SIN r O O ON W O O CN O O O ON N O 0 VO O 0 A �1 O 0 CT CT O 0 ON U O 0 W O CD .-' VD •-' W O w :1 M w VO A CT O O V. .- "' 00 ti r J n 0 in • 0 -' 00 c.r • 00 .r .--• VD 0 O N ? 0 O .P W O O .A V. O O ? U O O W W O O W O O O N 00 O O N 00 O O w O O O 00S`Z N 00 O O w `D .--' O 4240 J N +l O N 4 O O 2,400 " O\ O O 00 N . W 01 N. --' •-" U ^" .-. •--' O O N O a-. N O -- O U U O C +G< CD y n -- O n NJ O < 20 <20 n NJ•-' O A O n O < 20'1 n .- O n .- O no to O o O n .- A O— n AAAAAAAAAA CD V. CD V. CD V. CD V. CD V. CD .- CD U CD IQ CD U V. CD <10 <10 <10 < 20 A NJ CD n NJ < 20 A 1,..) U <10 <10 A 41. O U •-' A .-+ O n U n r � O r ;4) ; ti n 0 1-, n 0 — n 0 .- n 0 -, n 0 N o LA O <10UJ n N n U C 1,2-DCA <10 <20 A NJ O < 2 0 1 n NJ C) n --' CD <10 A NJ--' CD <10 n CD O In CD O :- CD--' n A -- CD.- n n 0 LA n 0 LA 2.6 A C) U 0.74 J 0.34 J AAAA CD LA CD iv CD U LAn 0 0 AAA r, 0 n 0 0 < 20 1 < 20 NJ N ,-+ N CD n N LA <10 n ,_, CD n 4, CD NJn N U —' O <5 n -- A !-', O A n 0 --' n 0 •-' r n O --' n CD N O U O <10UJ n NJ n U cCroo r. 1-, tr1 N .-' C. ND +1 C. NJ CT C. 33 JI 35 J1 35 J 35 J1 VD CD c.., 00 .- 4, W '--i CD IA +7 c, O NJ ,y `- A O A .-. CD O� U Cy CD ON O1 C. N .- C. n O U 1.3 J 1.2 n O in A 0 N U Ln N ti N V Jam. W ti 47 J ,, VD '-- 46 J CT O . I 54J'1 I 1401 CT U ._, W 4, W O ti 35 J 54.2 JI 98.8 A --' O <5 n --' A r O n •-' n 0 n 0 n 0 •-' n 0 •-' n 0 N 0 U O A O c-. ,, n N U A U C [�0' MTBE C1 . CD CA W CD O1 LA CD O'. ,4 CD 480 4001 w VD CD 01 . CD CT - CD 630 49 NJ 00 481 LA CD NJ., LA LA'-. A "" 54 1201 N .- `-' U ..... W N A O w C, „ 4, LA LA 0 LACN VD 0 '.D O V CD-- O LA O ON NJ O 840I 520I —1 VD O - 00 O 8401 830I CT CT ON rn w VD ti .-. 00 0 - CD 0 _ lJ CDU O ,P. O +l 341 .-' +] 221 -4 83 J 941 440 JI \D +] •- 828 C C -� 0) �7 w CD C C) a 0 n V "O 3 0cp 0-C1 o — C E m C ta C —12 a re' ct =• r. CI rn In CD CO RI .r Table 1 VOC Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID: Samp.Date Benzene Toluene Ethylbenzene Xylenes 1,2-DCA IPE MTBE Naphthalene Unit: ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Area 2 UW06 6/9/2010 2.1 0.15 J 4.2 < 0.1 < 0.1 0.13 J 8.8 1.1 UW06 12/8/2010 3.3 0.34 J 4.9 0.19 J 0.26 J 0.34 J 21 2.2 UW06 6/8/2011 2.6 0.17 J 6.2 1.2 < 0.1 0.27 J 17 1.6 UW06 6/23/2011 4.9 0.19 J 13 5.3 0.67 0.36 J 20 5.9 UW06 7/21/2011 3.7 0.20 J 6.5 1.9 0.61 0.52 25 3.7 UW06 8/16/2011 3.1 0.16 J 1.6 1.6 0.25 J 0.18 J 15 4.2 UW06 11/22/2011 2.1 0.33 J 0.5 0.62 0.83 0.59 24 0.42 J UW06 2/16/2012 1.7 0.12 J 5.6 1.2 2.7 1.0 30 1.8 UW08 6/14/2007 816 J 9.2 87.5 13.8 < 0.5 42.8 2390 J 90.4 UW08 6/14/2007 816 14.1 84.7 25.8 J < 5 43.5 2260 J 93.5 UW08 12/5/2007 61.9 J 2 13.8 J < 0.56 2.3 J 45.1 71.6 25.7 UW08 12/5/2007 47.8 J 1.3 10.4 J < 0.56 < 0.2 UJ 41.3 62.4 21.1 UW08 6/4/2008 1,000 6.8 J 80 3.8 J < 2 34 3,200 78 UW08 12/4/2008 220 2.1 J 35 2.5 J 9.8 J 28 610 19 UW08 6/4/2009 770 11 J 69 16 J < 5 26 2,300 110 UW08 12/8/2009 270 3.2 J 36 2.6 J < 2 21 940 29 UW08 6/9/2010 530 13 77 49 < 1 28 1,600 97 UW08 12/8/2010 120 1.5 J 24 2.2 J 5.4 18 390 14 UW08 6/8/2011 720 14 110 36 < 1 26 1,500 100 UW08 6/23/2011 680 16 J 80 16 J < 5 22 J 1,800 66 UW08 7/21/2011 1,100 16 J 110 29 <5.0 26 2,600 130 UW08 8/16/2011 360 12 J 32 61 < 5 20 J 1,600 31 UW08 11/22/2011 180 2.7 20 13 1.9 21 440 5.6 UW08 2/16/2012 320 6.5 J 42 17 <2.0 19 1,100 33 MW68 8/30/2010 18 2.4 6.7 58 12 4.2 43 0.96 MW68 12/8/2010 390 27 91 270 26 6.8 220 71 MW68 6/8/2011 160 33 73 510 < 1 6.7 240 57 MW68 6/23/2011 90 14 30 150 17 6.1 130 17 MW68 7/21/2011 99 15 45 110 15 6.0 130 25 MW68 8/16/2011 100 11 7.5 120 14 6.5 180 9.1 MW68 11/22/2011 57 2.4 8.4 21 19 8.6 190 3.1 MW68 2/16/2012 46 1.8 J 8.1 18 20 7.7 250 2.9 MW69 5/24/2011 0.12 J < 0.1 < 0.1 0.17 J 0.46 J 6.5 95 5.6 MW69 6/8/2011 < 0.1 < 0.1 . < 0.1 < 0.1 0.23 J 2.8 41 0.4 J MW69 6/23/2011 <0.1 <0.1 <0.1 <0.1 0.32J 5.1 70 0.19J MW69 7/21/2011 <0.10 <0.10 <0.10 <0.10 0.28 J 5.2 68 0.36 J MW69 8/16/2011 <0.1 <0.1 <0.1 0.12J 0.26J 3 41 2.1 MW69 11/22/2011 <0.10 <0.10 <0.10 0.26 J 0.29 J 2.9 34 3.2 MW69 2/16/2012 < 0.10 < 0.10 0.12 J 0.40 J 0.28 J 2.6 30 2.8 A blank cell indicates that the analyte was not determined by the associated method. All results presented in ug/L. DCA Dichloroethane IPE Isopropyl ether J Estimated value MTBE Methyl tert-butyl ether ug/L Micrograms per liter UJ Not detected and the detection limit is estimated value U Not present above the associated level; blank contamination exists shaded cells indicate sampled ;after injection (May 20111_ 2 of 2 Table 2 MNA Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID ample Date Br° CI H2S g ' Methane NO3 Depth to NO2 SO4 , S2 Water DO pH specific: Temp conductance Unite..,. rmg/L mg/L mg/L : mg/L mg/L. mg/L" mg/L .a Feet SU oC uS/cni Batch 5/16/2011 766 Area 1 MWO5 12/9/2009 4.3 J 8.34 2.43 8.95 MWO5 6/9/2010 < 2 1.2 J < 0.4 < 0.054 19.6 < 0.25 < 0.4 5.5 0.11 J 7.05 2.5 6.08 17.71 ---771' 17.91 0.057 MWO5 12/8/2010 0.1 6.00 0.55 6.85 MWO5 _ 6/8/2011 . <2 2.3 '<,0.4 , 0.12 J . 4.15 , 0.45 <.0.25 <- :4 1 <0.054 .:858 0:19 7.25 MW05 . 6/23/2011 , . < 2 3.1 J < 0.4. 0.43 208 1.9 J < 0.4 12.1 J. 0.36 7.47 1.66 6.00 19.98 0.094 17.91 0.073 28.31 , 0.111 M 05 7 21 2011 <2 ° 8 <0.40 U.075 J 8.42 1.6 , <0.25 <0.40 <1.5 <0.54 8.87 1.52 7.21 19.2 .05 MWO5 8/16/2011 <2 3. < 0:4 0.11 J 23.2 L.3 0.69 <0.4 5.9 <0.11 5.67 2.37 : 6.43. 20.46 0.81 MWO5 ": 11/22/2011 <2 . 1.8 J .. <0.4 0.062J 2.15 2.9 ..< 0.25 < 0.40 <1.5 <0.54 10.06 0.28 ' 6.25 MWO5 2/16/2012 <2.0 ` 1.3 J <0:40 0.057 J 8.41 3.2 <0.25 <:0.40 < 1.5 ; 0,069 J . 9.63 1.24 ' 8.04 MW21 12/9/2009 - 1.6 J 6.34 1.52 7.98 20:88 82.9 18.03 123 19.86 0.94 MW21 6/9/2010 < 2 31.3 < 0.4 < 0.054 19.5 < 0.25 < 0.4 < 1.5 < 0.054 5.33 1.55 6.44 21.44 0.606 MW21 12/8/2010 6 8.59 0.47 6.68 MW21 6/8/2011 < 2 ; 33.7 < 0.4 < 0.054 ' 19 5.9 < 0.25 < 0:4 6.6 < 0.054 6.24 U.27 6.42 W21 23 2 1 < 7 <0. <0.05 9.3 .2 < 5 < < 1.5 . < 54 9 . 151.614 MW21 7/21/2011, <2 _ 36.9 <0.40 <0.054 <0.25 <0.40 <LS <0.054 7 7 p M 1 011 <2 <0.4 ' <0.054 <0.25 <0.4 <1.5' <0.054 .82 .22'i 2 MW21 11/22/2011 < 2 33.2 < 0.4 < 0.054 18.8 7.4 . < 0.25 < 0.40 < 1.5 < 0:054 .. 8.27, 22.71 0.544 22.12 0.627 2 7 2 2 .72 ' 1 2. .592 0.52 6.08.23.85 , . 59 MW21. 2/16/2012 . <2.0 40.6 <0.40 <0.054 20. 6.5 < 0.25 <.0.40 . < 1.5 <0.054 7.66 0.47 7.55 . 19.99 . 716 MW26 12/9/2009 8.4 6.26 0.34 7.87 20.42 0.900 MW26 6/9/2010 < 2 6.2 < 0.4 < 0.054 9.54 < 0.25 < 0.4 < 1.5 0.061 J 5.20 0.49 6.45 22.06 0.338 MW26 12/8/2010 2.9 8.39 0.31 6.91 23.12 0.313 MW26 6/8/2011 <2 : , 6.1 . < 0.4 <0.054 , 4.55 5. < .25 - <0. .8 J 0.061 J 6.26 Q.15 6.65 23,00 . 0.304 MW26 - 6/23/2011 < 2 6.5 < 0.4 < 0.054 7.17 6.1 < 0.25' < 0.4 3.6 J < 0.054 6.57 0.1.7 6.25 21.61 0.264 MW26 7/21/2011 <2 <0.40 <0.054 <0.25 <0.40 <1.5 .7 7 72 23. 5 0:3 7 MW26 - 8/16/2011 < 2 6.3 < 0.4 < 0.054 6,64 6' < 0,25 : < 0.4 . < 1.5 0.14 J 6.79 0.12 '. 6.55 24.08 0. 11 MW26 11/22/2011< 2 3.1 < 0.4 < 0.054 1.27 5. 0. <0. 0 4 J <`0.054 8.18 0.23 6.35 24.48 8 <.0.40 < 0.25 < 0.40 < 1.5 < 0.054 . 7.59 0.32 . 7.26 .. 20 18 407 MW26 2/16/2012 < 2.0 �•2 <0.054 9.25 7.2 MW65 MW65 1278/2010 2.8 8.76 1.46 6.91 23.47 0.327 MW65 12/8/2010 3.1 MW65 6/8/2011 - 128 . 7.8 < 0.4 < 0.054 : , 43.9 . 1.4 < 0.25 <0.4 .' 109 ` <0.54 6.56 0.3 6.51 22.8 0.648 MW 5. 23 2011: 80. 7 . < < .054 35. < .25 < 7 <0.05 .93 .17 .77 0.43 MW65 7/21/2011 24.5 ' ,8.1 ` <0.40 <0:054 27.1 2.2 <0.25 <0.40 12.6 <0.054 7.13 - � 7 .5 77 MW65. 8/16/2011 26.6 7.9 <0.4 <.0.054 27.2 . 2 . 0.29 J ` < 0.4 10.1 < 0.054 7. .1 2 • O. 9 MW65 11/22/2011 44.5 5.9 ' < 0.4 < 0.054 , 23.4 2.6 < 0.25 <0.40 <1.5 . <0.054 8.48 0.40 6.29 24.64 " 410 MW65 ` 2/16/2012 17.0 6.0 < 0.40 < 0.054 23.0 3.2 <0.25 : <0.40 < 1.5 < 0.054 7.99 0.49 : 7.39 19.91. ; 469 1 of 2 Table 2 MNA Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID Sainple Date - Br Cl F H2S Mg Methane NO3 NO2 SO4 S2 Depth to Water . DO pH Temp specific conductance Unit: mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Feet mg/L SU oC uS/cm Area 2 UW06 6/9/2010 < 2 3.7 < 0.4 0.061 J 1.8 - < 0.25 < 0.4 2.1 J 0.061 J 6.25 2.84 4.97 17.23 0.155 UW06 12/8/2010 - - - - - 0.2 - - - - 6.93 3.99 5.95 19.59 0.048 UW06 6/8/2011 < 2 4.3 < 0.4 < 0.054 2.23 0.24 < 0.25 < 0.4 3.5 J < 0.054 7.06 0.95 6.05 18.31 0.039 UW06 6/23/2011 < 2 5.5 < 0.4 < 0.054 3.13 0.19 < 0.25 < 0.4 2.7 J < 0.054 6.70 0.68 5.00 19.11 0.058 UW06 7/21/2011 <2 5.2 <0.40 <0.054 2.86 0.18 <0.25 <0.40 <1.5 <0.054 6.81 1.13 5.14 20.75 0.038 UW06 8/16/2011 < 2 4.4 < 0.4 < 0.054 1.7 0.22 < 0.25 < 0.4 1.81 < 0.054 5.32 0.17 5.29 21.47 0.062 UW06 11/22/2011 <2 4.2 <0.4 <0.054 2.94 0.34 <0.25 <0.40 1.9J <0.054 6.64 0.40 5.84 20.58 106 UW06 2/16/2012 <2.0 4.8 < 0.40 < 0.054 3.14 0.260 . < 0.25 < 0.40 < 1.5 < 0.054 7.17 2.71 7.57 15.76 66 UW08 6/9/2010 < 2 14.2 < 0.4 < 0.054 41.1 - < 0.25 < 0.4 8.7 < 0.054 4.51 2.1 6.25 18.88 0.87 UW08 12/8/2010 - - - - - 0.36 - - - - 5.65 3.03 6.01 15.53 0.856 UW08 6/8/2011 < 2 14.3 < 0.4 < 0.054 42.2 0.29 < 0.25 < 0.4 15.1 < 0.054 5.45 0.53 6.23 21.56 0.843 UW08 6/23/2011 < 2 13.4 < 0.4 < 0.054 38.3 0.16 < 0.25 < 0.4 14.3 < 0.054 5.26 0.99 5.73 20.78 0.712 UW08 7/21/2011 <2 13.3 <0.40 <0.054 40.3 0.14 <0.25 <0.40 8.7 <0.054 5.16 1.13 6.22 22.27 0.825 UW08 8/16/2011 < 2 13.1 J < 0.4 < 0.054 35.5 0.15 J < 0.25 < 0.4 13.5 J < 0.054 4.2 0.32 5.86 25.71 0.732 UW08 11/22/2011 < 2 13.6 < 0.4 < 0.054 36.3 0.22 < 0.25 < 0.40 15.3 < 0.054 5.21 1.78 6.37 20.48 763 UW08 2/16/2012 < 2.0 12.5 < 0.40 < 0.054 38.6 0.730 0.32 J < 0.40 12.2 < 0.054 5.57 6.09 , 6.09 15.6 830 MW68 8/30/2010 < 2 20.8 < 0.4 < 0.054 5.37 0.015 J 1 < 0.4 3.7 J < 0.054 6.77 4.9 5.15 21.53 0.212 MW68 12/8/2010 - - - - - 0.35 - - - - 6.65 0.44 6.65 18.46 0.342 MW68 6/8/2011 250 20.5 < 0.4 < 0.054 37.5 0.24 < 0.25 < 0.4 197 < 0.054 7.08 0.62 6.62 20.84 0.642 MW68 6/23/2011 188 22.3 < 0.4 < 0.054 30.5 0.12 < 0.25 < 0.4 131 < 0.054 6.78 0.92 5.83 20.58 0.505 MW68 7/21/2011 152 27.2 <0.40 <0.054 23.8 0.15 0.45 J <0.40 100 <0.054 6.91 0.37 6.18 21.27 0.540 MW68 8/16/2011 120 24.6 < 0.4 < 0.054 22.6 0.16 < 0.25 < 0.4 81.6 < 0.054 5.48 0.22 5.54 22.45 0.462 MW68. 11/22/2011 72.3 24.1 < 0.4 < 0.054 14.9 0.31 < 0.25 < 0.40 47.2 < 0.054 6.70 0.48 6.05 20.12 440 MW68 2/16/2012 55.8 23.7 < 0.40 < 0.054 14.1 0.270 < 0.25 < 0.40 37.7 < 0.054 7.15 2.02 6.65 15.66 413.000 MW69 5/24/2011 < 2 12.6 < 0.4 < 0.054 41.6 - .32 J < 0.4 28.7 <0.11 9.14 8.69 6.01 17.94 0.304 MW69 6/8/2011 < 2 10.9 < 0.4 <0.054 8.73 0.039 < 0.25 < 0.4 28.4 < 0.054 6.10 4.54 6.33 ` 19.76 0.246 MW69 6/23/2011 <2 . 10.5 <0.4 <0.054 22.7 0.012J <0.25 <0.4 17.8 <0.054 6.67 4.07 5.40 18.31 0.163 MW69 7/21/2011 <2 10.9 <0.40 <0.054 34.4 0.005 J <0.25 <0.40 10.8 <0.054 6.26 4.05 4.41 20.69 0.185 MW69 8/16/2011 <2 11.6 < 0.4 < 0.054 7.76 0.015 < 0.25 < 0.4 15.6 < 0.054 5.79 2.62 5.61 19.7 0.177 MW69 11/22/2011 < 2 10.7 < 0.4 < 0.054 7.26 0.12 < 0.25 < 0.40 17.5 < 0.054 6.03 0.38 6.76 18.18 215 MW69 2/16/2012 < 2.0 8.9 < 0.40 < 0.054 7.72 0.260 < 0.25 < 0.40 12.3 < 0.054 6.33 2.17 6.06 13.38 205 Analyte was not determined by the associated method J Estimated value UJ Not detected and the detection limit is estimated value U Not present above the associated level; blank contamination exists mg/L Milligrams per liter Br Bromide Ca Cl F H2S Mg Na NO2 NO3 Calcium Chloride Fluoride Hydrogen sulfide Magnesium Sodium Nitrite Nitrate S SO4 TOC DO Temp SU oC, uS/cm Sulfide Sulfate Total Organic Carbon Dissolved oxygen Temperature standard units Degrees Celcius .shaded cells indicate sampled after injection (May 2011) 2 of 2 �I I I DWO6 -\ • DW10• • ESOBDFR ES13 /COVERED LOADING RACK ES12 • ES01 7e < \ N` •DWO5 ES20 ES15 I • ES31 MULTIPLE PIPES ~; ; i • DPEW02 UW05''- ,I AS06 MW6_7 j MW661 • ;'AREA 2 _- .n i !I '1• = _ ; VEE07 RW03 S ' Gil ES,10 �. • ; MW27 _.x f; �MW20 AR/EA 1 1 [,`r2;] f 'ES05DR.. ES05SR ES18• I • r-DW01 A. i w �k TO1• `�' INO1 , I! • ES26 TANK /• ES28 c, a 7' t, t II ij ES30 • Ii ' UW02� i �U�11 ! 1 VEtb3 EL W> 6 'MWi48.. _.__ _..._ ES37 I • DW02 • •VE02 _� �•' ES38 — • 4- : Jr =1� MW47 II MWzial Ia �`I • i�l'al '�/ �� ray t, 1i MW51 l,rg I oa I — i Ili 1 1'i 1 �'v 1 • I 11.�1` T-------1-17-- ES11 MW4—• MV/44 /Tx :; • ,-s tJ RWO2 ~_�9k1W37 -_ Tart l MW39 • •f ±M 45 -• MW56° ; -- --ASO5 � _ a! AREA 3 • MW — MW36 MW41 / - _• >--- i ' i `---- /` .__ / M1N49t�.:MW02 ' MW08 _-- T 117 I1 r I • TO2A tt TC�i,< 1_ 4 MW 57 • • ••AS01 MPO6 •PM' 3 / Legend — — Property Line DWO1 • MOM Groundwater Monitoring Well Biosparge Well Abandoned Monitoring Well Injection Location of Sulfate/Bromide Former DVE/Pump & Treat System Layout (1985-1994, 1994-2000) Injection Pilot Study Wells 0 80 AS SHOWN COWDE,mAL-ALL RIGHTS RESERVED-PRLPERTY DF RDU. NORTH CAROUNA 27560 DESIGNED BY DATE DRAWN BY DATE TSH 04AUG11 CHECKED BY DATE MN 04AUG11 Figure 1. Injection Pilot Study Well Locations BP Terminal 4762/ Southeast Terminal CONTRACT ND. DRAWING NO. APPROVED BY DATE MN 04AUG11 J3-00004762.01 FIGURE-1 REV. 0 CORRECTIVE ACTION PLAN ADDENDUM BP CHARLOTTE TERMINAL NO. 4762 (FORMERLY SOUTHEAST TERMINALS) 7401 OLD MOUNT HOLLY ROAD CHARLOTTE, NORTH CAROLINA NCDENR GROUNDWATER INCIDENT NUMBERS 6771, 15159, 15618, 17002, 17263, 17264, AND 20622 Prepared for: Atlantic Richfield Company (ARCO) A BP Products of North America Inc. affiliated company 501 Westlake Park Blvd, MC 28.152C Houston, Texas 77079 June 15, 2012 Prepared by: URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 Tel. 919-461-1100 Fax 919-461-1415 URS Project No. 38436703 URS RECEIVEDIDENRIDWQ AUG 0 6 2012 Aquifer Protection Section CERTIFICATION PAGE Corrective Action Plan Addendum BP Charlotte Terminal No. 4762 (Formerly Southeast Terminals) 7401 Old Mount Holly Road Charlotte, North Carolina NC DENR Groundwater Incident Numbers 6771, 15159, 15618, 17002, 17263, 17264, and 20622 Report Date: Responsible Party (RP): RP Consultant: Project Manager: Registered Professional Supervision: June 1, 2012 Atlantic Richfield Company (ARCO) a BP Products of North America Inc. affiliated company 501 Westlake Park Blvd, MC 28.152C Houston, Texas 77079 281-366-6920 Fax: 281-366-7094 Attn: Paul Taylor TransMontaigne Product Services Inc. 200 Mansell Court East, Suite 600 Roswell, Georgia 30076 770-518-3662 Attn: Jim Sligh URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 919-461-1100 Margaret Ness, PG Jon Kucera, PE This Report was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my thorough inquiry of the person or persons who manage the investigation, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. Jonathan J. Kucera Jr., PE NC License No. Date iiP:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 11 TABLE OF CONTENTS EXECUTIVE SUMMARY ES-1 1.0 INTRODUCTION 1-1 1.1 Site Location and Description 1-1 1.2 Site Topographic and Geologic/Hydrogeologic Setting 1-2 1.3 Site Monitoring Well Network 1-4 1.4 Summary of Light Non -Aqueous Phase Liquid (LNAPL) Occurrence 1-4 1.5 Site Release and Remediation History 1-4 1.5.1 Historical Site Release Incidents 1-4 1.5.2 Remediation Activities 1-4 1.6 Existing ISOC® System 1-5 1.7 Semi -Annual Groundwater Sampling Results 1-5 1.8 Evaluation of Groundwater Sampling Data 1-6 1.9 Receptor Information 1-8 1.9.1 Water Wells and Surface Water 1-8 1.9.2 Migration Pathways and Subsurface Structures 1-8 1.9.3 Contaminant Exposure Risks 1-8 1.9.4 Routes of Exposure 1-8 1.9.5 Potential Receptors 1-9 2.0 REMEDIAL STRATEGY 2-1 2.1 CAP Addendum Objective 2-1 2.2 Extent of Contamination 2-1 2.3 Remedial Considerations 2-1 2.4 Remediation Technology Evaluation 2-2 2.4.1 Technology Screening 2-2 2.4.2 Selected Technology and Further Evaluation 2-5 3.0 PROPOSED CORRECTIVE ACTION 3-1 3 1 System Components 3-1 3.1.1 Process Flow 3-1 3.1.2 Trenching and Well Installation 3-2 4.0 MONITORING PLAN 4-1 4.1 Groundwater Monitoring 4-1 4.2 System Monitoring 4-1 4.3 Reporting 4-1 4.4 Estimated System Operation Schedule 4-2 5.0 SCHEDULE 5-1 5.1 Schedule for Implementation 5-1 5.2 Permitting 5-1 6.0 REFERENCES 6-1 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 111 TABLE OF CONTENTS TABLES Table 1 Well Construction Details Table 2 Bulk Fuel Storage Tank Inventory Table 3 Summary of Site Release Incidents Table 4 Summary of Remediation Activities Table 5 ISOC® Well Gauging Data Table 6 Potential Technology Screening Matrix Table 7 Conceptual CAP Addendum Implementation Schedule FIGURES Figure 1 Location Map Figure 2 Site Plan Figure 3 Cross Section Location Map Figure 4 Cross Section A - A' Figure 5 Cross Section B - B' Figure 6 Locations of Historical Terminal Releases Figure 7 Historical Remediation Activities Figure 8 Existing ISOC® Groundwater Remediation System Layout Figure 9 Water Table Contour Map, December 2011 Figure 10 Benzene Isoconcentration Map, December 2011 Figure 11 Toluene Isoconcentration Map, December 2011 Figure 12 Ethylbenzene Isoconcentration Map, December 2011 Figure 13 Xylenes Isoconcentration Map, December 2011 Figure 14 MTBE Isoconcentration Map, December 2011 Figure 15 Naphthalene Isoconcentration Map, December 2011 Figure 16 1,2-Dichloroethane Isoconcentration Map, December 2011 Figure 17 Isopropyl Ether Isoconcentration Map, December 2011 Figure 18 Groundwater Sampling Data Evaluation Areas Figure 19 Dissolved Oxygen Map, December 2008 Figure 20 Proposed Remediation System Layout P:\BP\Projects\Terminals\4762\5.0 Deliverables \5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc iV SECTIONONE INTRODUCTION On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, URS Corporation — North Carolina (URS) presents this Corrective Action Plan (CAP) Addendum for the facility located at 7401 Old Mount Holly Road in Charlotte, North Carolina (formerly "Southeast Terminals"). The Site has been assigned Groundwater Incident Nos. 06771, 15159, 15618, 17002, 17263, 17264, and 20622 by the North Carolina Department of Environment and Natural Resources (NCDENR) in response to various historical petroleum product release incidents at the facility. The Site priority ranking is currently 100B due to the presence of potable water -supply wells within a 1,500 foot radius of the Site. In a letter dated October 14, 2008, NCDENR issued a Notice of Regulatory Requirement (NORR) requiring BP to provide remediation system modification recommendations in the first 2009 semi-annual groundwater monitoring and remediation report for the Site. A follow-up letter, sent by NCDENR on April 29, 2009 indicated the requirement to submit a revised CAP to "implement corrective action in the central plume area." A copy of the letter is included as Appendix A. This CAP Addendum is intended to address both the October 2008 and April 2009 NORR letters. BP proposed the performance of a pilot study in 2010 and 2011 to collect critical design parameters necessary to complete the remedy selection and properly design the remedy. 1.1 SITE LOCATION AND DESCRIPTION Maps showing the Site area and layout are provided as Figure 1 and Figure 2. Figure 2 includes the locations of all Site monitoring wells. Monitoring well construction information is presented on Table 1. The Site is located in the Paw Creek area of Charlotte, North Carolina, an area predominantly occupied by petroleum terminal and light industrial facilities. The facility occupies approximately 26 acres and is bordered by Old Mount Holly Road to the north, a Kinder -Morgan terminal to the east, vacant property (former National Oil terminal) to the west, and undeveloped woods to the south. Railroad tracks operated by Piedmont and Northern Railroad are located directly south of the facility property, beyond which is situated a Duke Power transmission line right-of-way. The Site is a petroleum distribution terminal that has been in operation since the 1940s and was formerly owned jointly by BP and TransMontaigne. Since February 2006 the facility has been solely owned and operated by BP. The facility contains 19 bulk fuel storage tanks that are contained within earthen bermed areas and/or excavated areas with earthen cut -banks. The tank number, current fuel type, and capacity for the bulk fuel storage tanks are listed on Table 2. In addition to the bulk fuel storage tanks, the facility contains a terminal office building, miscellaneous storage and warehouse buildings, nine process aboveground storage tanks (ASTs), three underground storage tanks (USTs), a covered tanker truck loading rack, and associated process piping. The tanker truck loading rack is located near the northern border of the facility, with access from Old Mount Holly Road. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-1 SECTIONONE INTRODUCTION Six of the process ASTs, ranging in size from 180 gallons to 8,000 gallons, contain fuel additives. Two 10,000-gallon ASTs contain petroleum contact water. One 2,000-gallon AST contains mixed (slop) products. The USTs consist of one 1,000-gallon wastewater UST (located at the sump near tank 110), one 2,000-gallon used oil UST (located adjacent to two 10,000- gallon underground oil/water separators), and one 2,000-gallon vapor recovery unit (VRU) moisture separator UST. A total of seven USTs have been decommissioned at the terminal. The Site underwent a modification between September and December 2008 to include ethanol fuel storage, and an expanded truck loading rack and driveway widening to accommodate the expansion. The terminal is supplied with petroleum products from underground pipelines owned by Colonial Pipeline Co. and Plantation Pipe Line Co. Two 14-inch diameter feed lines from Colonial Pipeline enter the facility below ground from the northwest corner. One 10-inch and one 12-inch feed line from Plantation Pipe Line enter the facility from the southwest corner. Two abandoned 14-inch underground pipelines enter the facility's west side near the warehouse from the former National Oil terminal. These pipelines formerly supplied product to the former National Oil terminal via the BP terminal product manifold. Facility utilities are shown in Figure 2. Onsite utilities primarily consist of aboveground process piping from the bulk storage tanks to the truck loading rack, overhead electrical and telephone services, underground low -voltage communication cables, stormwater drain lines, and a septic system located south of the terminal office. The Charlotte -Mecklenburg Utility Department (CMUD) supplies potable water service to the facility, Duke Power provides overhead electrical service to the facility, and Bell South provides overhead telephone service. The area surrounding the loading rack, office, warehouse, and motor truck shop is paved with concrete or asphalt. Grass areas exist on the north side of the property along Old Mount Holly Road. Tank berms, access roads to the tank areas, and the area between the tank areas and the office/loading rack area are graded with gravel. Stormwater from the bulk fuel storage tank basins is discharged to a ditch in the southern portion of the site under a facility National Pollutant Discharge Elimination System (NPDES) permit. Stormwater from the loading rack containment area is collected in a 10,000-gallon AST and treated/disposed offsite at licensed facilities. Tank bottom water is collected into tanker trucks and treated/disposed offsite at licensed facilities. 1.2 SITE TOPOGRAPHIC AND GEOLOGIC/HYDROGEOLOGIC SETTING The facility is situated on the crest and slope of a hill centered on Old Mount Holly Road. Ground -surface elevations at the facility range from approximately 795 feet relative to mean sea level (msl) at the northern border of the facility adjacent to Old Mount Holly Road to approximately 740 feet msl at the southern border of the facility. South of Old Mount Holly P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-2 SECTIONONE INTRODUCTION Road, surface drainage is south toward Paw Creek. North of Old Mount Holly Road, surface drainage is north toward Long Creek. The Site is located in the Piedmont physiographic province, which is characterized by moderately level interstream areas separated by broad valleys. Bedrock in Charlotte, North Carolina is mapped within the Charlotte Belt lithologic division of the Piedmont, which includes mafic gneisses, amphibolites, metagabbros, and metavolcanic rocks. According to the Geologic Map of North Carolina (NCGS, 1985), bedrock beneath the facility consists of metamorphosed quartz diorite or quartzite. Groundwater in the Piedmont province occurs in the overburden under unconfined (i.e., water table) conditions, and in the underlying bedrock under both unconfined and confined conditions. Groundwater in the overburden occurs within pore spaces of the unconsolidated medium, including relict bedrock structures (i.e., fractures, foliations, etc.). Due to the typical fine-grained nature and low permeability of saprolite, the formation is not usually utilized for groundwater production. Groundwater in the underlying bedrock occurs along zones of secondary porosity, such as fractures, foliations, solution voids, etc. Most water -supply wells in the Piedmont are completed in bedrock with surface casings extending through the overburden. Competent bedrock in the Piedmont province is typically overlain by variable thicknesses of saprolite and soil, collectively referred to as "overburden." Saprolite consists of rock that has been subject to chemical weathering, removing up to 60% of the rock mass by solution, but not affecting volume (Cleaves, 1974). Saprolite commonly retains relict structures from the parent bedrock. Thicknesses of the overburden in the Piedmont typically range from 10 to 75 feet, depending on rock composition and topographic setting (LeGrand, 1988). Geologic cross sections of the Site were created for this CAP Addendum. Cross section locations are presented on Figure 3. Cross sections are illustrated on Figures 4 and 5. The cross sections are located in the central/upgradient area of the Site. This area will be the targeted area for remediation as indicated in the April 29, 2009 NORR letter and as further discussed in Section 1.8. Based on Site boring logs, subsurface materials at the Site consist of soil and saprolite overburden, including silty/clayey sand, sandy clay/silt, and silt/clay, overlying weathered and competent bedrock. Bedrock, meeting the description of metamorphosed quartz diorite referenced above, has been encountered in Site borings at depths ranging from approximately 10 to 40 feet below grade. Based on historical hydraulic conductivity tests completed for various wells at the Site, the average test result for monitoring wells screened in the overburden was 8.2 feet per day (CRA, 2004). Assuming groundwater viscosity and density of 0.001 kilogram per meter -second and 1 gram per cubic centimeter, the average intrinsic permeability can be calculated as 2.95 x 10"8 cm2 or 2.95 darcy. These values represent semi -pervious conditions and are consistent with typical P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-3 SECTIONONE INTRODUCTION values for fine sand and silt (Bear, 1972). A seepage velocity of 1.09 ft/day has been calculated using the above reference hydraulic conductivity of 8.2 ft/day, a hydraulic gradient of 0.02 ft/ft and an effective porosity of 0.15. URS notes the aforementioned K value was calculated using a linear average which tends to skew the average K to much higher values. This can cause an overestimation of the seepage velocity. URS has revisited and recalculated the hydraulic conductivity utilizing a geometric mean to a value of 1.2 ft/day. This results in a predicted seepage velocity of 0.16 ft/day. 1.3 SITE MONITORING WELL NETWORK The locations of Site groundwater monitoring and remediation wells are shown in Figure 2. Site well construction details are listed in Table 1. The depths of Site monitoring and remediation wells range from 7 to 110 feet below grade. Ten Site monitoring wells are completed in bedrock and one Site monitoring well is completed in saprolite directly above bedrock. The remaining Site monitoring wells are completed in the shallow overburden (i.e., water -table monitoring wells). 1.4 SUMMARY OF LIGHT NON -AQUEOUS PHASE LIQUID (LNAPL) OCCURRENCE LNAPL has been historically detected in some Site monitoring wells. LNAPL was not measureable in any Site monitoring well during the December 2011 gauging event and was last detected in 2005. Inspection and replacement of LNAPL-absorbent socks for select wells (ES- 05SR, ES-25, ES-33, MW-12, MW-51, UW-10, and VE-02) is completed periodically. LNAPL gauging data, along with groundwater level gauging data, is included in Appendix B. 1.5 SITE RELEASE AND REMEDIATION HISTORY 1.5.1 Historical Site Release Incidents Historical releases at the Site have included tank overfills, pipeline leaks, tank releases, dike leaks, a tanker truck release, and underground storage tank (UST) leaks discovered upon UST removal. Released products have included diesel fuel, kerosene, gasoline, virgin oil, and heating oil. A summary of past Site release incidents, as documented in historical Site documents submitted to NCDENR, is presented on Table 3. Figure 6 presents the location of each release with reference numbers corresponding to numbers presented on Table 3. 1.5.2 Remediation Activities Remediation activities at the Site have included soil excavation, groundwater pump and treat, dual phase vapor extraction, and groundwater recovery and treatment through an interceptor trench. A permeable reactive barrier (PRB) was installed in February 2005 downgradient of Tank 118 in the eastern area of the Site. In -situ submerged oxygen curtain (ISOC®) units are currently installed in the northwestern area of the Site (the existing ISOC® is discussed further in Section 1.6). Absorbent socks have historically and are currently being used to detect and P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-4 SECTIONONE INTRODUCTION recover LNAPL in select Site monitoring wells. A summary of Site environmental remediation activities conducted in response to the various historical facility product releases is present on Table 4. Locations of Site remediation activities are indicated on Figure 7. 1.6 EXISTING ISOC® SYSTEM The layout of the existing ISOC® system is shown on Figure 8. ISOC® devices are installed in six existing monitoring wells along the northwest terminal boundary (MW-02, MW-19, MW-36, MW-38, MW-39 and MW-41) that span the width of the current plume of elevated constituent of concern (COC) concentrations. The wells have an average spacing of approximately 20-feet perpendicular to the apparent direction of groundwater flow. The ISOC® devices are supplied oxygen from two, 200 cubic feet, oxygen cylinders located within a metal warehouse adjacent to the ISOC® wells (Figure 8). Oxygen feed lines (1/4-inch I.D. polyethylene tubing) are connected to the ISOC® devices through PVC conduit. Oxygen is injected in to the subsurface in each of the ISOC® wells under injection permit No. WI0300106 issued on December 31, 2007 by the NCDENR Division of Water Quality. Following startup of ISOC® system in November 2005, groundwater dissolved oxygen (DO) measurements have been measured in the ISOC wells and other surrounding monitoring wells on a routine basis. ISOC® well gauging data is listed in Table 5. System tubing to all wells was replaced in late March and early April of 2009 due to previously observed damage. 1.7 SEMI-ANNUAL GROUNDWATER SAMPLING RESULTS Semi-annual groundwater sampling events are conducted at the Site in accordance with the NCDENR-approved August 2005 Site groundwater monitoring plan, including sampling of the ISOC® system monitoring wells and additional monitoring wells. The most recent report submitted to NCDENR was the December 2011 semi-annual groundwater monitoring and remediation report (URS, 2009). This CAP Addendum was developed utilizing all available groundwater elevation and groundwater sampling data up to and including the December 2011 monitoring event. A water -table contour map based on the December 2011 site groundwater levels is provided as Figure 9. The December 2011 water -table contour map indicates a generally southern direction of groundwater flow. Site water -table contours and apparent groundwater flow directions for December 2011 are consistent with previous monitoring events. Historical groundwater elevation data are included in Appendix B. December 2011 groundwater isoconcentration contour maps for benzene, toluene, ethylbenzene, and xylenes (BTEX), methyl tertiary butyl ether (MTBE), naphthalene, 1,2 dichloroethane (1,2-DCA), and isopropyl ether (IPE) are provided as Figures 10 through 17, respectively. Historical analytical data is included in Appendix C. Field parameter measurements (pH, dissolved oxygen (DO), specific conductance, and temperature) for the December 2011 groundwater monitoring event are included in Appendix D. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-5 SECTIONONE INTRODUCTION 1.8 EVALUATION OF GROUNDWATER SAMPLING DATA Groundwater concentrations are variable across the site. Several groundwater plumes can be identified based on historical groundwater data. A side by side comparison of historical isoconcentration maps for numerous past sampling events for benzene, MTBE, naphthalene and 1,2-DCA are included in Appendix E to visually aid in determining the movement and/or stabilization of the plumes. Currently, the major plumes are: • In the eastern portion of the Site in the vicinity of Tank 118 and surrounding area. The PRB (installed in February 2005) is downgradient of this plume. • In the northwestern portion of the Site from approximately the truck loading rack to the western property boundary and north (uphill) of the ASTs. • In the southwestern corner of the site. This plume is related to a pipeline release currently being remediated by a separate party. Historical analytical data was further evaluated to determine the most cost-effective remediation system modification. In order to synthesize the large amount of analytical data for the Site, monitoring wells were grouped into five geographic areas (Figure 18). For each analyte, all positive results (nondetects excluded) for each group for each sampling event were averaged using the geometric mean of the results'. The resulting data were plotted on time -trend graphs to determine if trends to variations in the data can be identified. The resulting graphs are included in Appendix F. Graph F-1 shows the data for the entire Site. Each symbol on the graph represents the geometric mean concentration of one analyte during a sampling event (several day events are plotted as one). The line represents a straight-line best fit (on a semilog graph) of the data from January 1, 2000 to the present2. These results show an overall decrease in concentrations of all constituents analyzed for the entire site for the last eight years. A similar analysis was performed for the five geographic areas of the Site shown on Figure 18 • Area 1 — East Side (Graph F-2): The wells in the vicinity of the Tank 118 release show a pronounced decrease in concentrations for all constituents except isopropyl ether (IPE), which decreased only slightly. • Area 2 — Truck Loading Rack Area (Graph F-3): The wells in the truck loading rack area have historically had concentrations much lower than the three major plume 1 The geometric mean is calculated by taking the logarithm of each value, averaging these log values, then raising 10 by the log mean as the exponent. This method is more accurate than a simple average when using values that span more than one order of magnitude because it gives all values an equal weight. 2 Data prior to 2000 were excluded from the best -fit analysis to better determine the effectiveness of current remediation activities. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-6 SECTIONONE INTRODUCTION areas. However, these wells show a pronounced decrease in concentrations for all constituents except ethylbenzene, which decreased only slightly. • Area 3 — Central/Upgradient Area (Graph F-4): This area includes the wells from the northwestern corner of the site to near the center of the Site, but upgradient of the ASTs. This area includes some of the highest concentrations on the Site, and was previously remediated by the pump -and -treat and dual -phase systems. Constituents show varying trends in this area. Concentrations of 1,2 DCA are decreasing slowly. Concentrations of benzene, MTBE, and IPE are nearly stable. Concentrations of ethylbenzene, naphthalene, toluene, and xylenes are increasing. • Area 4 — Central/Downgradient Area (Graph F-5A): This area includes the wells from near the center of the Site to the southern property boundary, and includes much of the AST area. Concentrations in this area are much lower than the major plume areas, and are generally stable to decreasing slightly. Concentrations of some analytes showed an increase during 2005 and 2006, but appear to be decreasing since then (Graph F-5B). The cause of this increase is not known, but may be a delayed response to the Curtis Oil spill that occurred at the truck loading rack in December 2003. • Area 5 — ISOC® Area (Graph F-6A): This area includes wells near the western property boundary. This area includes some of the highest concentrations on the Site, and was previously remediated by the pump -and -treat and dual -phase systems. These wells show an apparent decrease in concentrations for all constituents. To determine the effectiveness of the ISOC® system, the best fit was divided to show trends before and after the ISOC® system was started in December 2004 (Graph F-6B). This plot shows variable, with possibly some increasing, trends from 2000 through 2004, but decreasing trends for most constituents from 2005 through 2008. This suggests that the ISOC® system may be effectively remediating this portion of the Site. The groundwater sampling data evaluation presented above shows that concentrations are stable or decreasing over most of the Site. The only area with persistent elevated concentrations is the central/upgradient area. The central/upgradient area wells generally correspond with the elevated COC concentrations comprising the northwestern plume discussed previously. The extent of this plume, determined from wells containing elevated COC concentrations, is generally encompassed by the 1.0 µg/L benzene isoconcentration contour illustrated on Figure 10. The most elevated COC concentrations were detected along the center of the plume in monitoring wells UW-10, MW-51, MW-2, ES-05SR, MW-36, MW-44, MW-21, and MW-19. Consequently, the central/upgradient area, specifically the area of elevated COC concentrations within the northwestern major plume, is the target area for remediation. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-7 SECTION ONE INTRODUCTION 1.9 RECEPTOR INFORMATION 1.9.1 Water Wells and Surface Water Water supply wells in the Paw Creek terminal area are currently addressed in the context of all terminals located in the area. There is one known potable water supply well within 1,500 feet and downgradient of the Site. The well is located at 6516/6518 Freedom Drive and is approximately 1000 feet from the targeted remediation area. No public water supply systems were located within a 1,500 foot radius of the Site (CRA, 2004). An intermittent stream is located southwest of the Site approximately 700 feet from the targeted remediation area. 1.9.2 Migration Pathways and Subsurface Structures Subsurface structures including petroleum pipelines, DPVE system conveyance lines, storm water drainage lines, underground low -voltage communication cables are located on the Site. Stormwater drainage lines carrying water off -site are located along the southeastern boundary of the Site. Major utilities (i.e. sanitary sewer and water) are located along Mount Holly Road, upgradient of the Site. Groundwater ranges between 5 and 15 feet below ground surface at the Site. As such, impacted groundwater may be in the vicinity of buried utilities. No known underground utilities, other than the conveyance lines for the former DPVE system, are located within the vicinity of the targeted remediation area. No basements are known to be located on the Site (Abernathy, 2009). 1.9.3 Contaminant Exposure Risks Based on residual hydrocarbon impacts at the Site described in previous sections, the following potential transport mechanisms for COCs at the Site are recognized: 1. Dissolved -phase COC transport in groundwater 2. Discharge of COCs in groundwater to surface water 3. Leaching of COCs from "smear zone" to groundwater 1.9.4 Routes of Exposure Based on Site and surrounding area characteristics and the reasonable foreseeable future uses of the Site and surrounding properties, the following potential routes of exposure to COCs from the Site are recognized: 1. Incidental ingestion and dermal absorption of COCs, or ingestion of aquatic organisms, from potentially impacted surface water. 2. Ingestion of COCs via future potable well water user at the Site. 3. Indoor and outdoor direct inhalation of vapor -phase COCs during implementation of corrective action or possible redevelopment of the site. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-8 SECTIONONE INTRODUCTION 1.9.5 Potential Receptors There appear to be no completed pathways between impacted groundwater and potential receptors, but based on the reasonable future use of the Site and surrounding area, the following potential receptors may exist: 1. Construction workers and employees disturbing the subsurface (ingestion, inhalation, and dermal absorption of COCs from impacted soils and/or groundwater during construction). 2. On -site employees (indoor/outdoor inhalation of vapor -phase COCs). 3. Future on -site personnel (ingestions/dermal absorption of COCs in groundwater and/or surface water, and indoor/outdoor inhalation of vapor -phase COCs). P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 1-9 SECTIONTWO REMEDIAL STRATEGY 2.1 CAP ADDENDUM OBJECTIVE The primary target area for remediation is the central/upgradient area, specifically the area of elevated COC concentrations within the northwestern major plume. The recommended course of action to satisfy the requirements of the NORR is to install and operate active remediation along the center of the northwestern plume. The objective of the CAP Addendum is to reduce groundwater concentrations comprising the northwestern plume and to continue the offsite migration mitigation efforts in the targeted area. Treatment will be applied to the saturated overburden soils. Vadose zone soils are not targeted because of the high water table and the assumption that the majority of impacts are currently located within the saturated zone or within "smear zone" soils. Impacts within competent bedrock will also not be treated due to the difficulty accessing this area for treatment. However, treatment of the saturated overburden will decrease the source of COCs so that as concentrations decrease naturally in underlying bedrock they are less likely to be replenished by overlying COC concentrations. Groundwater impacts will be monitored during remediation with the goal of reducing elevated concentrations. The performance of the corrective action will be assessed after 3 years of operation and recommendations for continued operation and monitoring will be provided. 2.2 EXTENT OF CONTAMINATION The primary COCs present in the groundwater are BTEX, MTBE, naphthalene, 1,2-DCA, and IPE. The contaminant mass of petroleum compounds within the northwestern plume was estimated from December 2008 groundwater assessment data. Estimated contaminant mass calculations are provided in Appendix G. The plume was assumed to extend to 50 feet below ground surface (bgs) due to existing, but relatively lower, concentrations within DW-01 and ES-05DR. The total contaminant mass in the subsurface is based on combining the mass estimates for each phase: saturated adsorbed phase, dissolved phase, and free phase (LNAPL). The mass of LNAPL was assumed to be zero. The estimated contaminant mass dissolved in the groundwater was calculated as 221 pounds. Based on the assumption that the saturated adsorbed mass is approximately ten times the dissolved mass, the contaminant mass in the saturated soil is estimated at 2,210 pounds. Consequently, the total estimated contaminant mass within the northwestern plume is approximately 2,430 pounds. 2.3 REMEDIAL CONSIDERATIONS There are several logistical issues to be considered in selecting, designing and implementing a remedial action in the targeted remediation area. The area is generally flat, but slopes southward at its southern end where it is terraced with numerous ASTs and above -ground piping. The area contains several buildings, above -ground pipes, and work areas. Most of the area is asphalt, concrete pavement or covered by gravel. The water table in the area is approximately 5 to 10 feet below ground surface. Access to some areas is limited or impractical due to the existing P:\BP\Projects\Terminals\4762\5.0 Deliverables \5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 2-1 SECTIONTWO REMEDIAL STRATEGY structures and layout. The area is located within a high traffic section of an operational terminal Treating groundwater in the targeted area poses several limitations including: • Groundwater is present at approximately 5 to 10 feet bgs • Above ground product piping and electrical lines in the area of remediation • Terminal structures, including occupied buildings, in the area of remediation • Ground disturbance would require removal and replacement of asphalt and/or concrete • Regular traffic in the area of remediation • Saprolite / bedrock interface is not uniform across the site 2.4 REMEDIATION TECHNOLOGY EVALUATION 2.4.1 Technology Screening and Pilot Study A potential technology screening table is included as Table 6. The technologies presented on the table include biosparging, continuous ozone injection, continuous ozone and peroxide injection, ISOC®, and BOS 200 Trap and Treat® injection. Pump and treat and DPVE were not considered because they were utilized in the targeted remediation area from 1985 to 2000 and elevated COC concentrations have persisted. In addition, air sparge combined with soil vapor extraction (SVE) was not considered because of historical high water table elevations, particularly in the eastern portion of the targeted area (e.g. MW-21, MW-26, UW-8, and UW-10), make soil vapor extraction impractical. Based on the evaluation presented on Table 6, continuous ozone injection, ozone and peroxide injection, and Trap and Treat have the highest capital costs. All options other than MNA are implementable and may be effective at the Site. Other than MNA, the least expensive but potentially effective alternatives are a biosparge system installation or an expansion of the current ISOC® system. Ozone or peroxide injection, Trap and Treat® injection, and ISOC® system modification will require an underground injection control (UIC) permit through NCDENR. A permit exists for the current ISOC® system (No. WI0300106) and would be modified if the system is expanded. A modified ISOC® UIC permit is anticipated to be the most easily obtained of the options evaluated. A UIC permit is not required for air injection (i.e. biosparging or air sparging). 2.4.2 Previous Pilot Test(s) 2.4.2.1 CIA Pilot Test 2002 CRA performed an air sparge and SVE pilot test in two areas of the Site (Area 1 and Area 2) in June 2002. Area 1 was located along the western boundary within the targeted remediation area and Area 2 was located on the eastern boundary of the Site near the PRB. Results from CRA pilot test and implications for proposed system design are listed below. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 2-2 SECTIONTWO REMEDIAL STRATEGY • The Area 1 SVE test showed a vacuum radius of influence (ROI) of 17.5 ft. The limited ROI would make air sparging vapor control with SVE difficult. Additionally, because water table elevations are as high as 5 feet bgs in portions of the targeted remediation area, use of SVE is not technically sound or cost efficient due to the handling of water. • The pilot test report included a calculated intrinsic permeability of 1.5x10-9 cm2 (0.15 darcy). This represents a lower permeability than the permeability of 2.95 darcy calculated based on previously reported hydraulic conductivities (Section 1.2) and confirms that the permeability is low to moderate in the targeted treatment area. The permeability indicates that air sparging or biosparging is feasible based on established site condition criteria but indicates that effectiveness may be limited by permeability in the area. • The air sparge test in Area 1 resulted in an estimated pressure ROI of approximately 30 feet (an ROI of 74 feet was seen for Area 2). This ROI is large enough to be practical for use at the Site. • The Area 1 air sparge test showed an injection pressure at the well of approximately 10 pounds per square inch (psi) for flows of approximately 5 cubic feet per minute (cfm) or less. • Vapor monitoring in surrounding monitoring wells during the Area 1 air sparge test showed volatile organic compound (VOC) vapors as high as 1000 ppm during sparging. Detected VOCs were generally higher during higher air sparge flows (7 cfm) and were generally lower (around 30 ppm) during lower flows (3-5 cfm). Biosparging would operate at <3 cfm. • DO concentrations decreased during the Area 1 air sparge test and increased during the Area 2 air sparge test. This indicates that the Area 1 air sparge pilot test did not show the intended result of biosparging. However, increases in Area 2 DO concentrations were significant and suggest that biosparging can be successful and that the Area 1 result may have been incidental. In addition, breakthrough appears to have occurred at the 5 minute mark based on observed PSI in Area 1, which suggest that soils are permeable. 2.4.2.2 URS Pilot Test 2010 2011 URS performed an air sparge and anerobic bioremediation pilot test in several areas of the Site (Area 2 and Area 3) from June 2011-February 2012. A fully detailed description of the two pilot tests are presented in Appendix H. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 2-3 SECTIONTWO REMEDIAL STRATEGY Biosparging Test Results • The biosparging test results were consistent with the results of the CRA pilot test in as far as the anticipated radius of influence and injection pressures. The test indicated that one might expect a 20 to 25 foot radius of influence within the treatment areas at pressures ranging from 16 to 25 psi and flows averages 2-3 scfm. • The test did illustrate potential preferential pathways that can distribute air other portions of the site. • VOC analysis for the biosparge testing showed an increase in concentrations from the baseline sampling to sampling conducted in December 2010 and January 2011. Increased concentrations in Area 3 were likely caused by shutdown of the ISOC system during pilot study biosparge activities. However thie pilot test was only performed for 3 months and while concentration decreases were not exhibited the area around the injection well maintained dissolved oxygen within the aquifer at levels able to support microbial growth. • The long term biosparge test appeared to indicate that VOC concentration reduction is possible over time. Sulfate Injection Results • Analytical results showed that VOCs in monitoring wells MW-65, MW-21, and MW- 26, wells in the immediate areas of the sulfate injections, have decreased while inorganic concentrations have generally increased or remained relatively unchanged from baseline results through July 21, 2011 results. Monitoring well MW-68, which is within the boundary of the Area 2 injection, showed an increase in VOCs. • Analytical results from June 8, 2011 sampling showed the greatest difference from the baseline sample results. Subsequent sampling events show results moving closer to baseline reporting. • Bromide was reported in monitoring wells MW-65 and MW-68 during sampling conducted following injection events. All baseline samples and pilot study samples were non -detect for bromide in all sampled wells except pilot study samples of MW- 65 and MW-68, which are located within the injection areas. Correlating concentrations of sulfate were also detected in monitoring wells MW-65 and MW-68 following injection events. Initial sulfate concentrations were lower than expected following the injection events in both Areas 1 and 2. The sulfate concentrations also appeared to decrease steadily over the post -injection sampling events in correlation with the decreasing bromide concentrations indicating that physical processes present in the aquifer are more dominant than biological processes and calls into question the efficacy of the sulfate injection technology. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 2-4 SECTIONTWO REMEDIAL STRATEGY 2.4.3 Selected Technology and Further Evaluation Biosparging was selected for treatment of the targeted remediation area. General descriptions of the technologies are presented on Table 6. The applicability of the technologies was further evaluated using observed Site conditions and the results of an air sparge pilot test performed by Conestoga Rovers and Associates (CRA) in 2002 (CRA, 2002). 2.4.3.1 Site Conditions Site conditions were evaluated to assess the applicability of the selected remediation technology. The following criteria were evaluated based on established criteria for required Site conditions for the selected technologies (USEPA, 2004). Site COCs should be determined to be aerobically biodegradable. All COCs for the Site have been shown to be aerobically biodegradable. Site permeability will affect air sparging effectiveness. A higher permeability will allow greater air flow. Soil conditions at the Site should at least exhibit moderate permeability (approximately greater than 0.1 darcy (USEPA, 2004)). The average permeability at the Site is approximately 2.95 darcy (Section 1.2) but may be less in some areas. The groundwater pH should be between 6 and 8 for effective aerobic degradation (USEPA, 2004). During the December 2011 sampling event, 45 of the 48 samples in which pH was field measured had pH between 6 and 8 (Appendix D). Of the samples outside the range, only one was above 8.5 and none were below 5. The groundwater temperature should be between 10°C and 45°C for effective aerobic degradation (USEPA, 2004). During the December 2011 sampling event all 46 of the samples in which temperature was field measured had temperature between 10°C and 45°C (Appendix D). Furthermore, the temperatures were generally around 18°C which is within the optimum range for microbial activity. In addition, historic DO data collected suggests that supplying oxygen to the targeted remediation area is a valid strategy. As shown on Figure 19, DO concentrations appear to be lowest in the area of the COC plume, with the exception of the western end of the plume, where the existing ISOC® system is operating. The depleted DO concentrations suggest that aerobic degradation is already occurring at the edges of the plume but is limited by the available oxygen. Supplying oxygen to the center of the plume should allow aerobic bacteria to thrive and will accelerate degradation of the targeted COCs. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 2-5 SECTIONTHREE PROPOSED CORRECTIVE ACTION The corrective action proposed for the Site is to be accomplished by implementing the following: • Biosparging to treat dissolved -phase groundwater impacts and to minimize contaminant migration. • Long term groundwater monitoring to observe the effectiveness of enhanced aerobic degradation at the Site. Groundwater monitoring will include the evaluation of DO to monitor the effect of the proposed corrective action. Biosparging will be utilized along the two "axes" of the northeast COC plume to mitigate off -site migration of the plume. Figure 20 illustrates the location of the proposed well network. Based on both air sparging pilot test, a conservative ROI of 20 feet will be utilized for design of the proposed remediation system. The well network illustrated on Figure 20 includes 19 remediation wells with an estimated 20 foot ROI. Conveyance piping will be installed to allow for the potential future expansion of up to five additional remediation wells in the northern portion of the plume. 3.1 SYSTEM COMPONENTS Implementation of the system is described below. The main components of the proposed biosparging system are as follows: • Air compressor • Coalescing filters • Air supply piping • Biosparging wells • Control panel including remote access • Various system appurtenances, including flow meters and pressure, temperature, and flow gauges 3.1.1 Process Flow Conceptual design schematics for biosparging systems, including a conceptual process and instrumentation diagram, are included in Appendix I. Worksheets for the preliminary sizing of the system components are provided in Appendix J. The calculations show a predicted injection pressure requirement at the well of approximately 15 psi, (similar to the results of the 2002 CRA pilot test. The total required pressure at the manifold, including supply piping and fitting friction loss and a 25 percent safety factor, will be approximately 25 psi. An air compressor will be selected that is capable of providing approximately 70 scfm at 25 psi. Pulsing will be utilized to operate only half of the biosparging wells at any given time. This schedule will allow the biosparging system to reach equilibrium and optimize influence while reducing the risk of flow channelization. P:\BP\Projects\Terminals\4762\5.0 Deliverables \5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 3-1 SECTIONTHREE PROPOSED CORRECTIVE ACTION Air will be supplied by an air compressor and conveyed to the biosparging wells through a series of supply lines. The air supplied by the compressor will pass through two coalescing filters to remove any liquid oil, water aerosols, and fine particulate matter. The filters will be used to provide redundancy and eliminate the potential of introducing any oils into the wells. The control panel will contain a programmable logic controller (PLC) that will allow timed operation of individual sparge wells. The system will allow for remote access to check the compressor's and sparge well operational status. 3.1.2 Trenching and Well Installation The conceptual design conveyed in this document envisions placing the biosparging wells at the intersection of the partially weathered bedrock and the more competent bedrock, or approximately 30 feet deep in most portions of the site. Prior to installation of biosparging wells a short duration tracer gas study will be performed to verify vertical influence of the air sparging wells. Based on these results final depths of the biosparging wells will be finalized in the bid plans and specifications. Prior to installing vertical wells and trenching, utility clearance will be performed to locate any on -site underground utilities. Conveyance piping for the former DPVE system will likely be crossed during trenching for the proposed system. The former system has been abandoned and the lines are not under vacuum. DPVE piping will be cut and capped where crossed if necessary. Biosparge wells will be set as deep as possible above competent bedrock. Biosparge wells will contain at least one foot of screen and based on the approximately 25 foot water column thickness between bedrock and the water table (see Figures 4 and 5), there is no potential for screen to be exposed to the vadose zone during operation. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 3-2 SECTIONFOUR MONITORING PLAN 4.1 GROUNDWATER MONITORING Semi-annual groundwater monitoring of the Site will continue in accordance with the NCDENR- approved August 2005 Site groundwater monitoring plan. MW-47 and MW-55 will be sampled on a semi-annual basis in addition to the currently sampled wells. Analytical parameters for all wells will include BTEX, MTBE, naphthalene, IPE, and 1,2-DCA. Additional analytical parameters (alkalinity, methane-ethane-ethene (MEE), nitrate, orthophosphate, sulfate, ammonia-N, and total organic carbon (TOC)), and field parameters (ferrous iron and oxidation reduction potential (ORP)) were collected at monitoring wells ES-01, UW-10, MW-51 and ES-38 during the June 2009 groundwater monitoring event to establish baseline conditions prior to implementation of the CAP Addendum. The additional parameters will continue to be monitored at ES-01, UW-10, MW-51 and ES-38 during each groundwater monitoring event following CAP implementation. 4.2 SYSTEM MONITORING Monthly operations and maintenance (O&M) visits will be made after system startup and shakedown. All applicable operational parameters will be recorded during each O&M event. Filters will be checked and cleaned/replaced as necessary. Required maintenance will be performed on all system components per manufacturer's recommendation. Performance monitoring for system effectiveness will primarily be through the measurement of dissolved oxygen concentrations within the groundwater. DO measurements will be collected periodically during the normal operations and maintenance of the system the frequency of which will be defined in an O&M plan. 4.3 REPORTING The current semi-annual groundwater monitoring reporting performed for the Site will be submitted to NCDENR after each groundwater monitoring event. The data transmittal will include: • Description of sampling activities with a discussion of any changes from the previous monitoring event or abnormal observations • Analytical data summary tables and figures for groundwater • Laboratory Analytical Reports • Tabulated DO measurements • Tabulated biosparge O&M data (system performance, pressure, flow) • Recommendations for monitoring and operational changes P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 4-1 SECTIONFOUR MONITORING PLAN 4.4 ESTIMATED SYSTEM OPERATION SCHEDULE The estimated system operation time is 4 years. Actual system operation time will be based on system performance. Uncertainties associated with this estimate include variations in Site conditions and Site assessment limitations, such as water level fluctuations and site geology characterization, and other environmental factors. System operations will be revaluated approximately three years after the beginning of system operation, and recommendations for continued operation and monitoring or system modifications will be submitted to NCDENR. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 4-2 SECTIONFIVE SCHEDULE 5.1 SCHEDULE FOR IMPLEMENTATION A general schedule for implementation of the remedial activities described above is shown on Table 7. Upon approval of the CAP Addendum by NCDENR, planning and detailed system design will begin. The following is a list of activities to be completed prior to system start-up. • Design and Planning • Prepare Detail Design and Prepare Technical Specifications for System Equipment and Installation • Select Drilling Contractor • Permitting • Purchase System Equipment and Materials • System Construction • Drilling and Well Installation • Trenching and Pipe Installation • Equipment Installation • O&M manual development • System Start-up / Shakedown 5.2 PERMITTING The current UIC permit for the ISOC wells will be terminated. Mecklenburg County requires air permits for discharge of toxic air pollutants. Typically, a discharge permit or permit exception is obtained for air sparge and soil vapor extraction systems. In the case of biosparge systems, the vapor discharge is small, difficult to accurately quantify, and is not limited to a single discharge point. However, an air permit exemption should be obtained for active biosparging from Mecklenburg County Air Quality (MCAC). Submittal of a letter to MCAC describing the system and process commonly results in an air permit exception for sparging systems (Rayfield, 2009). The letter will be submitted 90 days prior to biosparge system installation if applicable. In addition, an application for a well permit will be submitted to Mecklenburg County Groundwater and Wastewater Services for each well installed during CAP implementation. Finally, all required permits for fire, electrical, building, and construction related to the remediation equipment compound will be obtained prior to system installation. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 5-1 SECTIONSIX REFERENCES Abernathy, 2009. Personal communication between Scott Smida of URS Corporation and Larry Abernathy of BP, June 3, 2009. Bear, J., 1972. Dynamics of Fluids in Porous Media. Dover Publications. 1972. Cleaves, E. T., 1974, Petrologic and Chemical Investigation of Chemical Weathering in Mafic Rocks, Eastern Piedmont of Maryland: Maryland Geological Survey, Report of Investigation, v. 25, 28 p. CRA, 2002. Semi -Annual Active Remediation Monitoring Report, Conestoga Rovers & Associates, September 10, 2002. CRA, 2004. Semi -Annual Monitoring report January 1, 2004 — June 30, 2004, Conestoga Rovers & Associates, September 2004. ISOC®, 2009. Design Schematics, http://www.isocinfo.com/DocumentRoot/14 /Design Schematics.pdf Viewed June 16, 2009. LeGrand, H. E., 1988, Region 21, Piedmont and Blue Ridge, in Back, W., Rosenshein, J. S., and Seaber, P. R., eds., Hydrogeology: Boulder, Colorado, Geological Society of America, The Geology of North America, v. 0-2. NCDENR, 2008. Re: Notice of Regulatory Requirements, North Carolina Department of Environment and Natural Resources, October 14, 2008. NCDENR, 2009. Re: Notice of Regulatory Requirements, North Carolina Department of Environment and Natural Resources, April 29, 2009. NCGS, 1985, Geologic Map of North Carolina: 1:500,000 North Carolina Geological Survey, 1985. Piedmont, 2005. Proposal for In -situ Submerged Oxygen Curtain System Installation, Piedmont Geologic, P.C., August 26, 2005. Rayfield, 2009. Personal communication between Caleb Krouse of URS Corporation and Jason Rayfield, Air Quality Supervisor, of Mecklenburg County Air Quality, June 1, 2009. URS, 2009. Semi -Annual Groundwater Monitoring and Remediation Report: December 2008, URS Corporation — North Carolina, April 3, 2009. USEPA, 2004. How to Evaluate Alternative Cleanup Technologies for Underground Storage Tank Sites, A Guide for Corrective Action Plan Reviewers, United States Environmental Protection Agency, EPA 510-R-04-002, May 2004. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\4762 CAP Addendum 061512.doc 6-1 TABLES Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No: Northing (Fset)' Easting (Feet), Top of ,Casing Elevation e . " (Feet . Realtive to 'tdGVD} , Screen Interval- (Feet Below Ground) Total Depot (Feet �, Below Ground) Approximate Date Installed i Geologic Zone °nitoretl� ;.. Parcel Number AS01 N/A N/A 759.69 13.0 - 15.5 15.5 06/02 N/A 05724302 AS02 N/A N/A 784.98 23.5 - 25.0 25.0 06/02 05724302 ASO4 N/A N/A 785.36 34.0 - 39.0 39.0 08/10 ASO5 N/A N/A 785.45 34.0 - 39.0 39.0 08/10 AS06 N/A N/A 780.66 22.0 - 27.0 27.0 08/10 DPEW01 561296.8174 1423986.6534 763.19 3.0 - 10.5 10.5 09/97 N/A 05724301 DPEW02 561602.7889 1423835.0786 781.18 4.0 - 14.0 14.0 09/97 N/A 05724301 DW01 561586.0405 1423656.5762 784.12 52.0 - 57.0 57.0 05/92 Bedrock 05724301 DW01A 561582.9012 1423696.9568 782.50 14.0 - 19.0 19.0 N/A N/A 05724301 DW02 561352.6126 1423618.9074 776.17 24.0 - 29.0 29.0 05/92 Bedrock 05724301 DW03 N/A N/A 762.28 45.0 - 50.0 50.0 05/92 Bedrock 05724301 DW04 561216.8708 1423328.0896 769.29 4.5 - 9.5 9.5 N/A 05724302 DW05 561844.7793 1423435.7268 786.60 49.0 - 54.0 54.0 N/A N/A 05724302 DWO6 561840.6986 1423913.5373 791.69 41.0 - 46.0 46.0 N/A N/A 05724301 DW08 561115.2978 1423948.3161 759.86 37.5 - 42.5 42.5 04/97 Bedrock 05724302 DW09 N/A N/A 760.09 44.0 - 49.0 49.0 12/99 Bedrock 05724302 DW10 N/A N/A N/A N/A N/A N/A N/A N/A ES01 561872.3080 1423594.5933 791.38 18.0 - 28.0 28.0 01/93 Weathered Granite 05724302 ES02 561225.4682 1423602.1330 770.32 4.0 - 44.0 44.0 03/93 05724301 ES03 561467.3861 1423617.7245 781.26 8.0 - 23.0 23.0 03/93 Saprolite 05724301 ESO4 561892.5678 1423594.9569 791.79 16.0 - 46.0 46.0 03/93 05724302 ES05 561733.8004 1423495.1581 785.77 10.0 - 45.0 45.0 03/93 05724302 ES05SR N/A N/A 786.67 10.0 - 30.0 30.0 05/05 Saprolite 05724302 ES05DR N/A N/A 786.79 45.0 - 55.0 55.0 05/05 Bedrock 05724302 ES06 561873.1015 1423452.3497 789.94 5.0 - 40.0 40.0 03/93 05724302 ES07 561852.3894 1423797.3489 791.23 2.0 - 22.0 22.0 03/93 Saprolite 05724301 ES08 561680.6126 1423873.7317 790.56 10.0 - 35.0 35.0 03/93 05724301 ES08SR** N/A N/A 792.83 10.0 - 25.0 25.0 05/05 N/A N/A ES08DR** N/A N/A 792.70 47.0 - 57.0 57.0 05/05 N/A N/A ES09 561621.2498 1423841.3317 788.04 5.0 - 45.0 45.0 03/93 05724301 ES10 561795.5151 1423598.5891 791.36 3.5 - 21.0 21.0 03/93 Sandy Clay 05724302 ES11 561641.1089 1423484.5621 785.33 5.0 - 25.0 25.0 08/93 Silty Clay 05724302 ES12 561755.9851 1423826.6505 791.76 7.0 - 22.0 22.0 08/93 Saprolite 05724301 ES13 561824.1833 1423875.9617 791.83 5.0 - 25.0 25.0 08/93 Clayey Sand 05724301 ES14 561691.2600 1423926.5230 790.70 3.0 - 23.0 23.0 08/93 Silty Clay 05724301 ES15 561723.2821 1423769.0074 790.25 8.0 - 18.0 18.0 N/A N/A 05724301 ES16 561641.5922 1423982.1524 790.25 5.0 - 25.0 25.0 01/94 05724301 ES17 561938.0508 1423551.3382 791.47 5.0 - 20.0 20.0 01/94 Silty Clay 05724302 ES18 561737.3383 1423401.7600 786.31 4.0 - 14.0 14.0 01/94 Silty Clay 05724302 ES19** 561739.5557 1424051.3416 795.13 6.0 - 26.0 26.0 01/94 Silty Clay 05724301 ES20 561902.7571 1423416.4770 787.36 6.0 - 21.0 21.0 N/A Silty Clay 05724302 ES21* 561807.7732 1424136.5114 792.59 5.0 - 15.0 15.0 02/94 N/A 05724301 ES22 N/A N/A N/A N/A N/A N/A ES23 561245.9817 1424171.6421 764.38 4.0 - 9.0 9.0 N/A N/A 05724301 ES24 N/A N/A N/A N/A N/A N/A ES25 560892.4859 1423292.5796 754.69 N/A 24.0 N/A N/A 05724302 ES26 561460.6103 1423752.7862 777.81 29.0 - 39.0 39.0 05/96 Saprolite 05724301 ES28 561440.0360 1423683.4472 774.01 12.0 - 22.0 22.0 05/96 Saprolite 05724301 P:\BP\Projects\Terminals\4762\5.0 Deliverables \5.2 Final Deliverables \December 2011\tables\Table 1 Update July 2011 (MW-69)\T1 Page 1 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing =• (Feet) Eas#ing (Feet) •t Top -of - Casing Elevation (Feet ` Realtive to NGVD) Screen Inteeval (Feet Below Ground) Total Depth (Feet Below Ground) Approximate Date installed Geologic Zone Monitored;,, Parcel Number `" ES29 561875.0050 1423798.4872 791.37 N/A 25.0 N/A N/A 05724301 ES30 561289.7215 1423767.9827 768.21 5.0 - 15.0 15.0 N/A N/A 05724301 ES31 561463.4581 1423920.8296 779.22 6.0 - 16.0 16.0 N/A N/A 05724301 ES32 561225.0002 1423996.5307 762.94 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES33 561288.4598 1424006.1705 763.33 4.0 - 14.0 14.0 10/96 Silty Sand 05724301 ES34 561510.6321 1424372.9606 777.18 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES35 561494.7313 1424106.5233 774.74 2.5 - 15.0 15.0 10/96 Silty Sand - Saprolite 05724301 ES36" 561568.9915 1423805.4128 782.83 15.0 - 25.0 25.0 10/96 N/A 05724301 ES37 561396.2246 1423611.6336 777.88 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES38 561503.0391 1423621.9763 782.60 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES39 561565.2874 1424118.7755 781.88 4.0 - 9.0 9.0 02/97 Sandy Clay 05724301 ES40 561449.2345 1424347.7368 779.47 1.0 - 11.0 11.0 02/97 Sandy Clay 05724301 ES41 561569.1222 1424343.6774 784.60 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES42 561364.3171 1424047.1854 774.77 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES43 561358.1419 1424262.8673 777.18 8.0 - 18.0 18.0 02/97 Silty Sand - Saprolite 05724301 ES44 561604.1033 1424189.8355 790.22 8.0 - 18.0 18.0 04/97 Silty Sand 05724301 MP01 561288.8127 1423998.0869 763.10 2.5 - 12.5 12.5 09/97 05724301 MPO2 561301.5317 1423976.0820 763.19 3.0 - 13.0 13.0 09/97 05724301 MP03 561300.1281 1423989.2201 763.10 2.0 - 12.0 12.0 09/97 05724301 MP04* 561603.9098 1423830.9426 781.28 1.5 - 14.0 14.0 09/97 N/A 05724301 MP05 561578.0162 1423828.7206 779.96 2.0 - 14.5 14.5 09/97 05724301 MPO6 N/A N/A 759.42 2.5 - 12.5 12.5 06/02 N/A 05724302 MW01 N/A N/A N/A N/A N/A 01/85 MW02 561487.2640 1423357.7902 781.37 5.5 - 25.0 25.0 01/85 Silty Sand - Weathered Bedrock 05724302 MWO3W 561207.3791 1423326.9060 769.21 N/A 12.0 N/A N/A 05724302 MWO4 N/A N/A N/A 3.6 - 18.0 18.0 10/84 MWO4R 560935.1424 1423590.1046 754.94 2.0 - 11.0 11.0 02/98 Saprolite 05724302 MW05 561625.8587 1423574.6324 786.65 4.0 - 14.0 14.0 01/85 Silty Sand 05724302 MWO6 N/A N/A N/A 4.0 - 9.0 9.0 10/84 MW06R 560933.5686 1423672.4778 755.29 2.0 - 7.0 7.0 02/98 Saprolite 05724302 MWO7 561354.2347 1423341.1936 774.36 2.0 - 19.5 19.5 03/85 Saprolite 05724302 MWO8 561427.0882 1423348.3463 777.69 2.0 - 12.0 12.0 03/85 Saprolite 05724302 MWO9 561546.8653 1423389.3473 784.65 5.0 - 20.0 20.0 03/85 05724302 MW10 561224.7864 1423594.3738 N/A N/A N/A 03/85 MW11 N/A N/A N/A N/A N/A 03/85 MW12 561719.8840 1423618.9475 786.16 1.0 - 21.0 21.0 03/85 Saprolite 05724301 MW13 561676.7002 1423472.4878 N/A N/A N/A 03/85 MW14 N/A N/A N/A 1.0 - 15.6 15.7 02/85 MW14R 560891.2195 1423346.8273 756.41 2.5 - 15.0 15.0 02/98 Saprolite 05724302 MW15 N/A N/A N/A N/A N/A 03/85 MW16 561747.3621 1423577.1715 787.27 2.0 - 16.0 16.0 10/85 Saprolite 05724302 MW17 N/A N/A N/A N/A N/A 10/85 MW18* N/A N/A 780.90 2.5 - 22.5 22.5 10/85 MW19 561514.7100 1423363.7049 782.64 2.0 - 21.0 21.0 10/85 Saprolite 05724302 MW20 561703.5305 1423608.1548 787.34 10.0 - 25.0 25.0 10/85 Saprolite 05724302 MW21 561675.2283 1423607.2603 785.76 6.0 - 20.0 20.0 10/85 Saprolite 05724302 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\December 2011\tables\Table 1 Update July 2011 (MW-69)\T1 Page 2 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) Easting (Feet) Top -of- Casing Elevation (Feet Realtive to NGVD) Screen ` Interval (Feet Below Ground) ` ` Total °Depth (Feet Below Ground). Approximate Date Installed Geologic Zone Monitored Parcel Number MW22 N/A N/A N/A N/A N/A 10/85 MW23 N/A N/A N/A N/A N/A 10/85 MW24 N/A N/A N/A N/A N/A 10/85 MW25 N/A N/A N/A N/A N/A 10/85 MW26 561705.2878 1423572.6623 785.38 5.0 - 20.0 20.0 10/85 Saprolite 05724302 MW27 561726.9164 1423606.3704 786.93 4.0 - 14.0 14.0 10/85 Saprolite 05724302 MW28 N/A N/A N/A 3.5 - 23.5 23.5 12/85 MW29 N/A N/A N/A 3.7 - 17.7 20.0 12/85 MW30 N/A N/A N/A 4.4 - 19.4 20.0 12/85 MW31 N/A N/A N/A 4.2 - 19.2 20.0 12/85 MW32 N/A N/A N/A 2.1 - 22.1 24.0 12/85 MW33 N/A N/A N/A 4.6 - 19.6 20.0 12/85 MW34 N/A N/A N/A 3.8 - 18.8 19.0 12/85 MW35 N/A N/A N/A 4.0 - 19.0 19.0 12/85 MW36 561526.4378 1423389.4123 785.94 5.0 - 25.0 25.0 12/85 Sandy Silt - Silty Sand 05724302 MW37 561566.9736 1423430.5503 785.17 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW38 561582.4723 1423394.7559 785.54 5.0 - 25.0 25.0 12/85 Sandy Clayey Silt 05724302 MW39 561609.9127 1423420.9725 785.28 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW40 561644.0901 1423444.7051 N/A 4.0 - 24.0 24.0 12/85 MW41 561637.3588 1423398.8937 785.64 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW42 561606.8920 1423477.4229 785.95 5.0 - 25.0 25.0 12/85 Silty Sand 05724302 MW43 561572.0617 1423568.5897 788.36 4.0 - 24.0 24.0 12/85 Silty Sand 05724302 MW44 561573.8919 1423463.5270 785.77 3.5 - 26.0 26.0 12/85 Sandy Silt 05724302 MW45 561539.1703 1423432.3766 786.91 3.0 - 28.0 28.0 12/85 Sandy Silt 05724302 MW46 N/A N/A N/A 6.3 - 16.3 16.5 01/86 MW47 561546.0782 1423573.4010 788.05 7.0 - 17.0 17.0 01/86 Sandy Clayey Silt 05724302 MW48 561560.3416 1423606.0845 788.19 2.5 - 15.0 15.0 01/86 Sandy Silt 05724301 MW49 561553.2264 1423361.8991 784.17 5.0 - 19.5 19.5 01/86 Sandy Silt 05724302 MW50 561511.9326 1423433.2840 783.50 5.0 - 25.0 25.0 02/86 Sandy Clayey Silt 05724302 MW51 561576.7167 1423524.7096 786.41 8.0 - 18.0 18.0 12/86 Clayey Sandy Silt 05724302 MW52 N/A N/A N/A N/A N/A 10/86 MW53 N/A N/A N/A N/A N/A 10/86 MW54 N/A N/A N/A N/A N/A 10/86 MW55 N/A N/A N/A N/A N/A 10/86 MW56 N/A N/A N/A N/A N/A 10/86 MW57 N/A N/A N/A N/A N/A 10/86 MW58 N/A N/A N/A N/A N/A 10/86 MW59 N/A N/A N/A N/A N/A 10/86 MW60 N/A N/A N/A N/A N/A 10/86 MW61 N/A N/A N/A N/A N/A 10/86 MW62 N/A N/A N/A N/A N/A 10/86 MW-65 N/A N/A 785.72 5.0 - 20.0 20.0 08/10 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\December 2011\tables\Table 1 Update July 2011 CAW-69)\T1 Page 3 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) , Easting (Feet) Top -of Casing Elevation (Feet Realtive to NGVD) Screen Interval (Feet Below Ground) Total Depth (Feet.: Below Ground) Approximate Date , Installed Geologic Zone Monitored ; Parcel Number MW-66 N/A N/A 781.04 5.0 - 15.0 15.0 08/10 MW-67 N/A N/A 780.44 5.0 - 15.0 15.0 08/10 MW-68 N/A N/A 782.47 5.0 - 20.0 20.0 08/10 MW-69 N/A N/A 774.72 2.0 17.0 17.0 05/11 Sandy Silt PMW01 561124.4362 1424041.9674 761.06 5.0 - 15.0 15.0 06/92 Sandy Silt 05724302 PMWO2 561125.5177 1423964.5881 760.76 6.0 - 16.0 16.0 06/92 Sandy Silt Saprolite 05724302 PMWO3 561128.1760 1423878.0757 758.52 8.0 - 18.0 18.0 06/92 Sandy Silt Saprolite 05724302 PMWO4 560675.8867 1423430.5786 750.27 11.0 - 21.0 21.0 06/92 Sand Silt 05723114 PMWO5 560662.9922 1423502.4158 743.41 10.0 - 20.0 20.0 06/92 Sandy Silt Saprolite 05723114 PMWO6 561036.5314 1423856.2959 754.27 2.0 - 7.0 7.0 08/93 Silty Clay 05724302 PMWO7 561019.1837 1423982.5768 753.66 3.0 - 8.0 8.0 08/93 Silty Clay 05724302 PMWO8 561140.6727 1424080.3010 760.98 4.0 - 9.0 9.0 08/93 Silty Clay 05724302 PMWO9 560989.1019 1423862.8722 750.93 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW10 560846.3905 1423724.5687 746.86 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW11 560579.1482 1423436.2214 746.42 N/A 20.0 N/A N/A 05723114 PMW12 560394.9714 1423299.1239 732.48 N/A 12.5 N/A N/A 05723114 RW01 561092.3515 1423700.3608 N/A N/A N/A 05/86 RWO2 561590.5007 1423420.7633 784.71 6.0 - 26.0 26.0 05/86 Sandy Silt - Silty Sand 05724302 RWO3 561720.1317 1423614.0215 788.20 2.0 - 28.5 28.5 05/86 Sandy Silt 05724301 TO1 (trench) 561572.6969 1423690.8304 785.15 N/A 17.0 N/A N/A 05724301 T01A 561347.4489 1423879.9408 765.31 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 T02 (trench) 561558.4972 1423768.6401 783.08 N/A 22.0 N/A N/A 05724301 TO2A 561192.7742 1423857.4115 761.77 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 UW01* 561589.3852 1423826.6607 781.23 1.0 - 16.0 16.0 08/91 N/A 05724301 UW02 561606.2226 1423647.4684 785.44 3.0 - 18.0 18.0 08/91 Saprolite 05724301 UW03 561623.4532 1423644.3421 785.50 2.5 - 17.5 17.5 08/91 05724301 UW04 561649.6681 1423753.4841 787.59 5.0 - 20.0 20.0 09/91 Saprolite 05724301 UW05 561651.6699 1423810.2421 789.59 4.0 - 14.0 14.0 09/91 Saprolite 05724301 UW06 561547.4955 1423695.4543 782.00 1.0 - 16.0 16.0 08/91 Saprolite 05724301 UW07* 561560.8461 1423919.6721 780.03 2.5 - 15.0 15.0 09/91 N/A 05724301 UW08 561581.0603 1423770.9912 780.97 5.0 - 15.0 15.0 02/92 Saprolite 05724301 UW09* N/A N/A 778.00 2.0 - 12.0 12.0 02/92 UW10 561650.8426 1423655.9836 785.56 3.0 - 18.0 18.0 02/92 Saprolite 05724301 UW11 561573.1870 1423648.4289 784.79 4.0 - 19.0 19.0 02/92 Saprolite 05724301 VE01 561610.1204 1423594.3698 N/A N/A 10.0 N/A 05724302 VE02 561635.7696 1423612.0386 785.42 N/A 10.5 N/A N/A 05724301 VE03 561597.8544 1423617.7069 785.41 N/A 12.0 N/A N/A 05724301 VE04 561654.3003 1423576.2976 785.46 N/A 12.5 N/A N/A 05724302 VE05 561684.7491 1423590.9811 784.83 N/A 13.0 N/A 05724302 VE06 561728.0120 1423583.0234 785.19 N/A 11.5 N/A 05724302 VE07 561689.8509 1423654.3951 785.52 N/A 13.0 N/A 1 N/A 05724301 NOTES: 1) N/A - Data Not Available. 2) * Missing as of 03/2005 3) ** Abandoned September 2002 4) NGVD = National Geodetic Vertical Datum P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\December 2011\tables\Table 1 Update July 2011 (MW-69)\T1 Page 4 of 4 Table 2 Bulk Fuel Storage Tank Inventory BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina TANK NO. CURRENT STATUS FUEL TYPE CAPACITY (BBLS = Barrels) 101 Not in service. Empty - previously contained premium unleaded gasoline 17,600 102 Not in service. Empty - previously contained unleaded plus gasoline 14,000 103 Not in service. Empty - previously contained super unleaded gasoline 11,700 104 In service. Jet fuel 9,200 105 Not in service. Empty - previously contained tank condensate water 2,500 106 In service. Regular unleaded gasoline 29,500 107 In service. High -sulfur No. 2 fuel oil 51,000 108 In service. Regular unleaded gasoline 51,000 109 In service. Regular unleaded gasoline 63,943 110 In service. Regular unleaded gasoline 57,500 111 Not in service. Empty - previously contained low -sulfur diesel fuel 17,400 112 Not in service. Empty - previously contained kerosene 15,000 113 Not in service. Empty - previously contained regular unleaded gasoline 11,800 114 Not in service. Empty - previously contained diesel fuel 14,000 115 In service. 93 Octane premium unleaded gasoline 21,300 116 In service. Low -sulfur diesel fuel 32,800 117 In service. 93 Octane premium unleaded gasoline 26,000 118 In service. 93 Octane, low -sulfur, premium unleaded gasoline 25,250 119 In service. Low -sulfur diesel fuel 40,100 P:\BP\Projects\Terminals14762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 2 1 Of 1 Table 3 Summary of Site Release Incidents BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Reference No. Approximate Date Substance Released Amount of Release NCDENR Incident No. Description 1 Circa 1950 diesel fuel unknown -- tank overfill 2 Circa 1978 unknown unknown -- pipeline leak (1) 3 1979 kerosene 70,00 (2jallons -- release from tank 4 1985 diesel, gasoline & kerosene unknown -- pipeline leak (3) 5 1985 & 1989 IIIIAGU unknown -- pipeline leak 6 1991 unknown unknown -- product seeps in dike walls 7 1991 unknown unknown -- groundwater contamination discovered 8 1992 diesel unknown -- release from tank 119 9 1992 diesel unknown -- release from tank 119 10 circa 1994 unknown unknown -- pipeline leak (4) 11 1996 used oil unknown 17263/ 17624 1,000 gallon UST removal 12 1996 virgin oil unknown 550 gallon UST removal 13 1996 diesel unknown 8,000 gallon UST removal 14 Feb. 26, 1996 diesel unknown 15159 release from tank 111 15 1-May-96 diesel unknown 15618 product seeps in dike wall near tank 112 16a Oct-92 unknown unknown 6771 groundwater contamination discovered 16b Jan. 2, 1999 unleaded gasoline 77,784 gallons (5) 17002/ 20622 release from tank 118 17 Jun-02 unknown product unknown -- pipeline leak (6) 18 Dec. 17, 2003 heating oil 300 gallons -- release from tanker truck (7) Notes (1) Product seep from abandoned Fina pipeline discovered in dike wall (2) 68,866 gallons were recovered (3) Lines owned and operated by Publix Oil (National Oil terminal) (4) Lines owned and operated by Phibro Company (5) 51,660 gallons were recovered (6) Lines owned and operated by Plantation Pipe Line Company (responsible party) (7) Tanker truck owned and operated by Curtis Oil Company (responsible party) = No incident number issued P:1BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft- Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 3 1 of 1 Table 4 Summary of Remediation Activities BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Approximate Date Area Desciption* Treatment Method Amount Removed/Treated Soil Remediation Sep-91 Area North of tank 111 Excavation Unknown Sep-96 Former UST locations Excavation 133 tons Oct-96 Area west of tank 111 Excavation 7 tons Mar-97 Area near tanks 117 and 118 Excavation 24 tons Apr-98 Area north of tank 112 (excavation during installation of interceptor trench) Excavation Unknown May-98 A19a around tanks 111,116,117,118and Excavation 312 tons Jan-99 Area surrounding tanks 117 and 118 Excavation 420 tons Apr-04 Ditches near tanks 117 and 118 Excavation 13 tons Jan-05 Ditches near tanks 117 and 118 Excavation 120 tons Groundwater Remediation 1985 - 1994 see Figure 7 Pump and Treat 4,882,088 gallons 1994 - July 2000 see Figure 7 DPVE 472,135 gallons 1998 - 2005 see Figure 7 Interceptor Trench 217,867 gallons February 2005 - Present see Figure 7 PRB NA November 2005 - Present see Figure 7 ISOC® NA LNAPL Recovery 1993 - 1994 see Figure 7 Pump and Treat 6,000 gallons 1994 - July 2000 see Figure 7 DPVE 500 gallons On -going see Figure 7 Absorbent Socks NA. LNAPL last recorded 2005. Notes - * Remediation area locations illustrated on Figure 7 - NA = Not Applicable or Not Available - PRB = Permeable reactive barrier. The PRB is filled with granular gypsum and organic topsoil and is designed to mitigate groundwater COC concentrations, and prevent further downgradient migration of the groundwater COC plume through enhanced anaerobic biodegradation. - ISOC®= In -Situ Submerged Oxygen Curtain - DPVE = Dual Phase Vacuum Extraction P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 4 1 of 1 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-2 21.3 11 / 10/05 9.07 12.23 12.23 01/24/06 9.95 11.35 >20 02/23/06 9.79 11.51 5.60 03/07/06 10.70 10.60 1.30 04/11/06 10.89 10.41 >30 04/27/06 11.55 9.75 1.70 05/17/06 11.79 9.51 >20 06/22/06 10.58 10.72 NM 08/01/06 10.13 11.17 11.70 08/15/06 10.89 10.41 2.83 08/31/06 9.11 12.19 >20 09/25/06 9.19 12.11 >20 11/02/06 9.81 11.49 1.93 01/17/07 9.12 12.18 5.10 02/06/07 NM NM NM 06/25/07 10.21 11.09 15.80 08/17/07 11.13 10.17 25.86 10/10/07 11.95 9.35 4.04 12/06/07 12.74 8.56 10.51 01/23/08 11.73 9.57 1.21 02/28/08 11.49 9.81 1.89 03/14/08 10.84 10.46 2.08 04/11/08 10.26 11.04 >19.99 05/08/08 10.57 10.73 42.56 06/02/08 10.72 10.58 42.93 07/15/08 10.54 10.76 3.99 08/18/08 10.71 10.59 11.31 09/25/08 10.35 10.95 7.64 10/28/08 10.48 10.82 >19.99 12/03/08 10.96 10.34 0.44 MW-8 NA 09/25/06 7.44 NA 5.29 11/02/06 8.08 NA 1.86 01/23/08 8.52 NA 7.14 02/28/08 7.36 NA 10.44 03/14/08 9.03 NA 7.98 04/11/08 8.29 NA 7.43 05/08/08 9.09 NA 4.71 06/02/08 8.93 NA 5.46 07/15/08 8.69 NA 6.35 08/08/08 9.1 NA 3.58 09/25/08 8.8 NA 5.80 12/03/08 6.94 NA 8.13 P:\BP\Projects\Terminals 476215.0 Deliverables\5.1 Draft- Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 5 Page 1 of 7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-19 20.5 11/10/05 9.38 11.12 11.12 01/24/06 10.49 10.01 12.39 02/23/06 10.36 10.14 >20 03/07/06 11.00 9.50 >20 04/11/06 11.16 9.34 >30 04/27/06 12.25 8.25 0.76 05/17/06 12.38 8.12 >20 06/14/06 NM NM >30 06/22/06 11.46 9.04 6.20 08/01/06 11.04 9.46 13.30 08/15/06 11.83 8.67 14.20 08/31/06 10.27 10.23 >20 09/25/06 9.94 10.56 >20 11/02/06 10.60 9.90 1.90 01/17/07 9.46 11.04 14.96 02/06/07 NM NM NM 06/25/07 10.51 9.99 16.38 08/17/07 11.39 9.11 37.25 10/10/07 12.25 8.25 >19.99 12/06/07 13.20 7.30 17.17 01/23/08 12.28 8.22 35.51 02/28/08 11.97 8.53 24.28 03/14/08 11.41 9.09 45.98 04/11/08 10.80 9.70 >19.99 05/08/08 11.01 9.49 44.34 06/02/08 11.18 9.32 38.32 07/15/08 11.03 9.47 64.05 08/18/08 11.18 9.32 25.24 09/25/08 10.83 9.67 >19.99 ' 10/28/08 10.94 9.56 1.30 12/03/08 12.25 8.25 1.09 P:\BP1Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 5 Page 2 of 7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-36 23.0 11/10/05 12.78 10.22 10.22 01/24/06 14.8 8.20 15.48 02/23/06 13.86 9.14 >20 02/23/06 13.86 9.14 >20 04/11/06 14.75 8.25 >30 04/27/06 15.82 7.18 1.35 05/17/06 15.85 7.15 >20 06/14/06 NM NM >30 06/22/06 14.81 8.19 NM 08/01/06 14.34 8.66 NM 08/15/06 15.14 7.86 1.80 08/31/06 13.76 9.24 >20 09/25/06 13.22 9.78 >20 11/02/06 13.90 9.10 1.81 01/17/07 12.95 10.05 11.95 02/06/07 NM NM NM 06/25/07 14.01 8.99 14.23 08/17/07 14.84 8.16 31.93 10/10/07 15.68 7.32 15.85 12/06/07 17.07 5.93 16.86 01/23/08 15.86 7.14 34.56 02/28/08 15.60 7.40 19.55 03/14/08 14.99 8.01 43.33 04/11/08 14.45 8.55 >19.99 05/08/08 14.55 8.45 40.63 06/02/08 14.69 8.31 38.33 07/15/08 14.60 8.40 63.87 08/08/08 14.72 8.28 42.88 09/25/08 14.39 8.61 >19.99 10/28/08 14.07 8.93 >19.99 12/04/08 15.80 7.20 27.66 P:18P\Projects\Terminals1476215.0 Deliverables15.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 5 Page 3 of 7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-38 23.0 11/10/05 12.86 10.14 10.14 01/24/06 14.5 8.50 15.20 02/23/06 13.28 9.72 >20 03/07/06 13.77 9.23 >20 04/11/06 14.14 8.86 >30 04/27/06 15.11 7.89 5.00 05/17/06 15.22 7.78 5.00 06/14/06 NM NM >30 06/22/06 14.01 8.99 19.50 08/01/06 13.65 9.35 8.40 08/15/06 14.53 8.47 13.30 08/31/06 13.06 9.94 7.20 09/25/06 12.55 10.45 15.71 11/02/06 13.08 9.92 1.97 01/17/07 12.41 10.59 6.94 02/06/07 12.48 10.52 3.83 06/25/07 13.06 9.94 15.61 08/17/07 14.06 8.94 33.32 10/10/07 14.97 8.03 >19.99 12/06/07 15.97 7.03 10.29 01/23/08 15.42 7.58 32.80 02/28/08 15.14 7.86 8.29 03/14/08 14.62 8.38 42.58 04/11/08 14.01 8.99 >19.99 05/08/08 13.97 9.03 39.70 06/02/08 14.13 8.87 38.97 07/15/08 14.16 8.84 61.97 08/08/08 14.18 8.82 42.16 09/25/08 13.88 9.12 >19.99 10/28/08 14.07 8.93 >19.99 12/04/08 _ 14.68 8.32 39.87 P:\BP\Projects\Terminals 4762\5.0 Deliverables\5.1 Draft- Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 5 Page 4of7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Uni1 Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-39 21.7 11/10/05 12.05 9.65 9.65 01/24/06 13.44 8.26 1.17 02/23/06 13.03 8.67 >20 03/07/06 13.59 8.11 >20 04/11/06 13.95 7.75 >30 04/27/06 14.98 6.72 2.40 05/17/06 14.99 6.71 >20 06/14/06 NM NM >30 06/22/06 13.89 7.81 NM 08/01/06 13.54 8.16 13.70 08/15/06 14.28 7.42 2.42 08/31/06 13.05 8.65 >20 09/25/06 12.44 9.26 18.16 11/02/06 12.9 8.80 1.69 01/17/07 12.26 9.44 4.33 02/06/07 12.05 9.65 6.61 06/25/07 13.03 8.67 19.99 08/17/07 13.82 7.88 23.49 10/10/07 14.74 6.96 >19.99 12/06/07 15.76 5.94 8.30 01/23/08 15.30 6.40 27.82 02/28/08 15.02 6.68 6.06 03/14/08 14.51 7.19 30.89 04/11/08 13.91 7.79 >19.99 05/08/08 13.93 7.77 40.08 06/02/08 14.00 7.70 31.98 07/15/08 14.05 7.65 51.68 08/08/08 14.02 7.68 34.04 09/25/08 13.75 7.95 >19.99 12/04/08 14.52 7.18 7.48 P:\BP\Pmjects\Terminals\4762\5.0 Deliverables15.1 Draft- Interim Deliverables\CAP Modification Document 6-1-20121Tables\Table 5 Page 5 of 7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-41 21.6 11/10/05 12.44 9.16 9.16 01/24/06 13.73 7.87 >20 02/23/06 13.43 8.17 >20 03/07/06 13.95 7.65 >20 04/11/06 14.36 7.24 >30 04/27/06 15.39 6.21 1.80 05/17/06 15.46 6.14 >20 06/14/06 NM NM >30 6/22/06 14.33 7.27 17.54 8/1/06 13.98 7.62 12.00 8/15/06 14.87 6.73 5.34 8/31/06 13.28 8.32 >20 9/25/06 12.87 8.73 18.13 11/2/06 13.31 8.29 1.86 1/17/07 12.43 9.17 4.88 2/6/07 12.10 9.50 11.17 6/25/07 12.10 9.50 16.02 8/17/07 14.20 7.40 10.32 10/10/07 15.11 6.49 4.67 12/6/07 15.95 5.65 1.77 1/23/08 15.61 NA 4.67 2/28/08 15.29 NA 2.02 3/14/08 14.68 NA 0.48 4/11/08 13.99 NA 3.30 5/8/08 14.03 NA 1.18 6/2/08 14.54 NA 0.59 7/15/08 14.37 NA 0.34 8/8/08 14.43 NA 0.31 9/25/08 14.08 NA 0.18 12/4/08 14.69 NA 0.26 MW-45 NA 09/25/06 13.10 NA 0.36 11/02/06 13.67 NA 2.04 01/23/08 16.20 NA 0.74 02/28/08 15.91 NA 1.68 03/14/08 15.37 NA 0.48 04/11/08 14.78 NA 0.95 05/08/08 14.86 NA 0.40 12/04/08 15.40 NA NM P:\BP1Projects\Terminals\4762\5.0 Deliverables15.1 Draft- Interim Deliverables\CAP Modification Document 6-1-2012\TableslTable 5 Page 6 of 7 Table 5 ISOC Well Gauging Data BP Charlotte Terminal No. 4762 Southeast Terminals - Charlotte 7401 Old Mount Holly Road Charlotte, North Carolina Well No. Depth to top of ISOC Unit Date Depth to Groundwater Water Column above ISOC Unit (ft) Dissolved Oxygen (mg/L) MW-49 NA 02/23/06 12.17 NA 4.24 04/27/06 14.45 NA 0.90 06/14/06 NM NA >30 06/22/06 12.74 NA 1.00 08/01/06 12.43 NA 0.60 08/31/06 11.80 NA 0.60 09/25/06 11.30 NA 0.86 11/02/06 11.80 NA 2.19 02/06/07 NM NA NM 06/25/07 12.52 NA 10.66 08/17/07 13.18 NA 14.94 10/10/07 14.04 NA 4.96 12/06/07 14.83 NA 1.33 01/23/08 14.25 NA 0.38 02/28/08 13.94 NA 1.98 03/14/08 13.36 NA 1.15 04/11/08 12.76 NA 2.50 05/08/08 12.88 NA 0.36 06/02/08 13.30 NA 0.35 07/15/08 13.01 NA 6.46 08/08/08 13.13 NA 0.29 09/25/08 12.79 NA 1.79 12/04/08 13.48 NA 1.66 NOTES (1) Measured in feet below top of well casing. NA = Not applicable. NM = Not measured. P:\BP\Projects\Terminals41762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 5 Page 7 of 7 TABLE 6: POTENTIAL TECHNOLOGY SCREENING MATRIX BP Terminal 4762 7401 Old Mount Holly Road, Charlotte, NC Remediation Technology Technology Description / Site Applicability Implementability Effectiveness Estimated Cost Installation of Biosparge System Biosparging is a well developed technology used to effectively remediate dissolved phase groundwater VOC contamination. Biosparging involves injecting compressed air into the subsurface at low flow (less than 5 cfm) to reduce groundwater concentrations. Biosparging is designed to provide the majority of treatment through increased biological activity due to increased oxygen levels in the aquifer. Due to the low design flows, physical removal of contaminant mass through mass -phase transfer within the aquifer matrix is minimal, and vapor containment (soil vapor extraction) is not typically required. • This system could be easily implemented at the site. Based on conservative assumptions and using the design parameters from the installation of numerous systems, the system could be implemented by procurement of a relatively small air compressor and installation of approximately 17 wells. Wells can likely be installed in accessible locations with the necessary design spacing. Trenching to each well may present a minor obstacle but is possible based on an initial assessment of the targeted treatment area. An underground injection control permit would not be required. Biosparging is a proven technology at reducing concentrations of dissolved organics at petroleum sites. Effectiveness of biosparging would vary based on the increase microbial activity. This estimate is based on the installation of 17 biosparging wells and the installation of 600 linear feet of trench line, procurement of an adequately sized air compressor/blower to supply air for the sparging sells. Capital Costs: Well Drilling: $30,000 Trenching, Piping and Well Vaults: $75,500 Oversight Services: $16,500 Equipment: $55,000 Total Capital Costs: $177,000 Additional Incremental O&M Costs: Total Additional Yearly O&M Cost: $18,000 Ozone (Continuous System) This technology involves the installation of in -situ injection points for the application of ozone. The technology is a variation of in -situ chemical oxidation. The ozone oxidizes the contaminants and degrades into oxygen, thereby increasing aerobic biological activity. One of the advantages of this type of system is that it continuously injects the ozone into the subsurface instead of relying on one-time injections for contact. While a relatively new technology in the environmental remediation field ozone generation and application is well known in other industries. Given the right access the system is readily implementable. The major obstacles to installation are to obtain underground injection control permits for ozone. However, the product does not normally require in depth review by the State because the materials are not pathogenic. The system requires operation and maintenance but is generally comparable to other continuously operating systems (biosparge and ISOC®). Ozone injection has been proven to be particularly effective at achieving significant concentration reduction in a short period of time. It is an aggressive remediation technology that does not depend on microbial activity. However, an added benefit of ozone injection is that ozone quickly degrades into oxygen thereby leaving a highly aerobic environment that can be conducive to aerobic degradation polishing of the resulting lower concentrations of dissolved phase constituents. This estimate is based on the installation of 8 ozone injection points and the installation of 550 linear feet of trench line, and procurement of an adequately sized ozone production system. Capital Costs: Well Drilling: $26,000 Trenching, Piping and Well Vaults: $80,000 Oversight Services: $20,000 Equipment: $83,000 Total Capital Costs: $209,000 Additional Incremental O&M Costs: Total Additional Yearly O&M Cost: $15,000 Ozone / Peroxide Injection (ContinuousOversight System) This technology involves the installation of nested in -situ injection points for the application of hydrogen peroxide and ozone. The technology is a variation of in -situ chemical oxidation. The system continuously injects the ozone and peroxide into the subsurface instead of relying on one-time injections for contact. The ozone and peroxide oxidizes the contaminants and the ozone degrades into oxygen, therebyincreasingaerobic biological g yg g activity. When the ozone comes in contact with the peroxide the reaction forms hydroxyl radicals that have the required energy to break down more recalcitrant compounds such as MTBE and Acetone. While a relatively new technology in the environmental remediation field ozone generation and application is well known in other industries. Given the right access the system is readily implementable. The major obstacles to installation are to obtain underground injection control permits for ozone and peroxide. However, theproducts do not normallyrequire in depth review bythat q p the State because the materials are not pathogenic. The system requires operation and maintenance but is generally comparable to other continuously operating systems (biosparge and ISOC®). Ozone and peroxide injection has been proven to be particularly effective at achieving significant concentration reduction in a short period of time. It is an aggressive remediation technology that does not depend on microbial activity. However, an added benefit of ozone injection is ozone quicklydegrades into oxygen therebyleavinga g yg highly aerobic environment that can be conducive to aerobic degradation of the resulting lower concentrations of dissolved phase constituents. This estimate is based on the installation of 8 ozone injection points and the installation of 550 linear feet of trench line, and procurement of an adequately sized ozone production system. Capital Costs: Well Drilling: Piping an $26,000 Trenching, and Well Vaults: $80,000 Services: $20,000 Equipment: $95,000 Total Capital Costs: $221,000 Additional Incremental O&M Costs: Total Additional Yearly O&M Cost: $25,000 ISOC® System Expansion This technology involves installation of in -situ submerged oxygen curtain (ISOC®) units and connection the units to aboveground oxygen cylinder. Units are installed in existing or remediation specific wells and deliver oxygen to the groundwater through hydrophobic microporous hollow fibers that allow the unit to supersaturate the groundwater with dissolved oxygen. The increased oxygen levels stimulate aerobic biological activity to degrade petroleum hydrocarbons. This system expansion would be easily implemented. Based on conservative assumptions and using the design parameters from the installation of the numerous systems, the system could be implemented by procurement by upgrading the current aboveground oxygen distribution equipment and the installation of approximately 17 wells. Wells can likely be easily installed in accessible locations. Trenching to each well may present a minor obstacle but is possible based on an initial assessment of the targeted treatment area. A modification of the current underground injection control permit will be required. ISOC® systems are relatively simple and easy to maintain. ISOC® is a proven technology to reduce concentrations of dissolved organics at petroleum sites. The current ISOC® system, which currently includes wells downgradient of the targeted treatment area, appears to have been effective at reducing concentrations in that area. Effectiveness of ISOC would vary based on microbial activity. This estimate is based on the installation of 17 additional ISOC injection wells, installation of trenching and backfill, procurement and installation of the ISOC head works. Capital Costs: Well Drilling: $30,000 Trenching and Install: $70,000 Oversight Services: $15,000 Equipment: $80,000 Total Capital Costs: $195,000 Additional Incremental O&M Costs: Total Additional Yearly O&M Cost: $12,000 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 6 Charlotte Technology Screening ck 051809_JJK2_mn_ r1.DOC 1 of 2 TABLE 6: POTENTIAL TECHNOLOGY SCREENING MATRIX BP Terminal 4762 7401 Old Mount Holly Road, Charlotte, NC Remediation Technology Technology Description / Site Applicability Implementability Effectiveness Estimated Cost _ Trap and Treat® Injection This technology involves "one-time" injections of a specially -formulated blend of activated carbon, sulfate reduction media, micronutrients, and facultative microbes. The mixture, BOS 200®, is designed to capture COCs and degrade them biologically. This technology could be implemented at the site. Desirable spacing of injection points can likely be achieved in accessible locations within the targeted treatment area. However the injection will require an underground control permit that may be scrutinized by the State due to the injection of microbes. The technology would be difficult to implement at the site because of the heavy traffic within the targeted area and large number of injection points required. The technology would not require continued operations and maintenance activities. BOS 200® has been reportedly effective at significantly reducing concentrations at petroleum impacted sites. The technology is an aggressive on time injection that provides short-term treatment through adsorpotion of contaminants and long-term biological treatment. This estimate is based on 216 injection points with injection at eight intervals and the injection of 45,000 pounds of BOS 200®. Capital Costs: BOS 200 Injection: $455,000 Oversight Services: $16,000 Total Capital Costs: $471,000 Additional Incremental O&M Costs: Total Additional Yearly O&M Cost: $0 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-2012\Tables\Table 6 Charlotte Technology Screening ck 051809_JJK2_mn_ rl.DOC 2 of 2 TABLE 7 CONCEPTUAL CAP ADDENDUM IMPLEMENTATION SCHEDULE BP CHARLOTTE TERMINAL NO. 4762 CHARLOTTE, NORTH CAROLINA ACTIVITY/TASK 2012 2013 2014 J J A S ONDJ FMAMJ J A SONDJFMAMJJ A SOND 1. CAP Submittal 2. Regulatory Approval 3. Detailed Design 4. Bid and Award Phase 5. Permitting and Equipment Procurement 6. System Construction Site Prep Drilling System Procurement System Installation 7. Startup / Shakedown 8. GW Monitoring III 9. O&M manual 10. Reporting and Record Drawings ® - FIGURES O C) Orri RC) iv L 0 0 • SCALE IN FEET 0 2000 QUADRANGLE LOCATION SOURCE: USGS 7.5' TOPOGRAPHIC QUADRANGLE MTN. ISLAND LAKE, NC — DATED 1993 S I Wlls' v. 1500' Radius''( Fa. FIGURE 1. LOCATION MAP BP/TRANSMONTAIGNE TERMINAL BP SITE NO. 4762/SOUTHEAST TERMINAL CHARLOTTE, NORTH CAROLINA Prepared for: BP PRODUCTS DRAWN BY: TSH DATE:. 01 MAR04. PROJECT NO. ROU, NORTH CAROLINA 27560 Fig. tt' 6S05DR EDUIPUEVT / ENCLOSURE E470 5 ES05SR -.E ''.ES33 aUN1 P A�' MPD1 ES32 ;... PMWO5 PMWO4 • PMW11 • PMW12 • Legend Treeline Fence Line Property Line PMW12 SUMP G UW07 764 Railroad Topographic Contours Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Groundwater Monitoring Well Sump Groundwater Monitoring Well Missing as of 03/05 ESOS Groundwater Monitoring Well Abandoned 05/05 ESIO Groundwater Monitoring Well Abandoned 09/08 SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF RDU, NORTH CARDONA 2750 DRAWN HY TSH DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 2. Site Plan BP Terminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED BY MN DATE 02JUL07 CONTRACT NO, J3-00004762.01 DRAWING NO. 4762-2 ES07 I • • �I\ l�,' • I \ I / / / I'�4 II j 1I1 v �I Delivernhle • ESO1 r--------'-- --.i _ f.'UL � iP, F 1_u`s `--- L - CUV=_RED I .-r_---=_ __ - -; I , 1 ! lL DPEW02 '- ES12 I I t ® ---- 1. _ I UWo1 uwo5 / • ES15 f I 1 ; ; iI Ii / ♦ - . i i�• DW01 /r---•/• VE07/C ♦♦ !uwo2/ UWO i-=aUiWWi2 / t `- RWO3=t=9 20 Ar--.y./® 1 4WO86 ES38I ®0 2 I I 0 W27f MW21 , VE08 / Q VE06N°/V05 • SE05SR•• 0 ES05 n- ES18• E WO I1A={ _ / /•UW /Oi= TOl VE03 • MW4B OVE01i • 4• -r-- • E,1 MVV47 ` V E02 E ` MW42 • DPVES EQUIPM:NT FNCI OSURF MW39 MW5.1 f _ MW44 , MW37` ggg� RW02 !� - MW45,, • AS02 �- • - _=- -` 1 ---__! MW41 n `.. MW361 • ES26 I III it ( Nt: II , ij 11 I0j' ES37--- ES30 • MW50 UO Former National Oil Terminal Property 1 r s �MW49® •I MWO ti ///®28 --MWO8 , -- • MW-55 /11 L LI ( DW01 • UWCii7 ESO5 0 Legend Treeline — — Fence Line Property Line Sump Groundwater Monitoring Well Groundwater Monitoring Well Missing as of 03/05 Groundwater Monitoring Well Abandoned 05/05 • - - — Cross Section Location MW20 Well Boring Log Used to Create Geologic Cross Section A -A' (Projected onto Cross Section Line) Es10 Well Boring Log Used to Create Geologic Cross Section B-B' (Projected onto Cross Section Line) 1 Benzene Isoconcentration Contour (ug/L) Approximate Direction of Groundwater Flow 0 20 60 N SCALE AS SHOWN • DESIGNED BY DATE CONFIDENRAL—ALL RIGHTS RESERVED —PROPERTY OF lintS mu, NORTH CAROUNA 27560 I DRAWN BY TSH DATE 26APR12 CHECKED TEY AWS DATE 26APR12 Figure 3. Plan View BPTerminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED HY AWS DATE 26APR12 CONTRACT NO, J3-00004762.01 ' DRAWING NO. FIGURE-3 REV. 0 c u 800 780 760 J (/) N 0 _o LL. z O w w 740 720 O N (n w ML/CL PARKING LOT BEDROCK LEGEND �— GROUNDWATER LEVEL (DECEMBER 2011) MONITORING WELL WITH SCREEN INTERVAL (777.21) GROUNDWATER ELEVATION (DECEMBER 2011) 0 0 (.n w (772.85) z 0 0 w U) SITE PROPERTY (ASPHALT COVERED) O N 1 .. .. .• .. .• .. 1 kill al ME •• Il• ME ME ME ME ME !ME ME ME ME ME EMI ME ME ME ML/CL (778.95) BEDROCK SOIL DESCRIPTIONS 0 Estimated USCS classification based on well boring logs ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay N 0 0 0 CMULTIPLC PIPES 0 co 0 CONTAINMENT PIT FOR TANK 111 BEDROCK N w CONTAINMENT PIT FOR TANK 112 8.08) 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X DESIGNED BY AS SHOWN DATE CONFIDENTIAL -AIL RIGHTS RESERVED -PROPERTY OF RCU, NORTH CPROLINA Z7350 DRAWN BY TSH DATE 26APR1 2 CHECKED BY AWS DATE 26APR1 2 Figure 4. Crass Section A —A' BP Terminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED BY AWS DATE 26APR1 2 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-4 REV. 0 c 11 c L -c 0 c 0 0 Tr c CL 800 780 (Ft. Above MSL) z 0 760 1- W J w 740 720 3 0 M L/CL M L/S M ML/CL SITE PROPERTY (ASPHALT COVERED) BEDROCK N ro (771.53) SOIL DESCRIPTIONS Estimated USCS classification based on well boring logs (771 .4-1 /`-- BEDROCK ML — SILT ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay a7 0 ML/SM FORMER NATIONAL OIL TERMINAL PROPERTY BOUNDARY (770.92) LEGEND GROUNDWATER LEVEL (DECEMBER 2011) MONITORING WELL WITH SCREEN INTERVAL (771.41) GROUNDWATER ELEVATION (DECEMBER 2011) 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -AU_ I>1CHTS RESERVED -PROPERTY OF URS RR1. NORTH CAROLINA P560 DRAWN Bf TSH DATE 26APR12 CHECKED BY AWS DATE 26APR12 Figure 5. Cross Section B—B' BP Terminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED BY AWS DATE 26APR1 2 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-5 REV. 0 E3: :. .. - • ES41 1 / > / ,l ESOOD OPAL'S (j f CJ r �`11:7 ri 11P-;f2 17tA1ilj 7 l ESLO ( L 1 0 a TV,, 11 E` 0 ICi li 0 jr ES44 0 ES3 E i0%._ EJ36• ES31 ES43 Ea=G ES23 rJ T02 P. U!�14 0 {..OW03 it DviFl Fsar _ ` , l�o r Ir �i._ r tinz J — "` Tr 1 ii '"_"_---- �...r' �"' <.. b Ph1Via l P141102 .. 0W08 (1 PMM1W PlAWDE, P,'MWD9 �., ie Former Oil Terminal Propert' s c P,i'W10 SUi.1P I.....,._... PMWOSS 0 PMWO P:''-,01/`1 (1) 8311012 ., PMW12 • SUiAP C I0 0 50 150 Legend Groundwater Monitoring Well Sump Location of Release Incident (See Table 3 For Description) SCALE AS SHOWN DESIGNED Bf DATE CONFIDENTIAL —ALL RIGHTS RESERVED —PROPERTY OF RDU, NDRIH CMOLNA 27560 DRAWN BY TSH DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 6. Locations of Historical Terminal Releases BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 02JUL07 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-3 REV. 0 ES19 • t29•ESD7 4 -%ES15 WOB =� r S lllllllllll' ,p .o ES14 ® UW07 ES31 • • 100000001 TAW 111 ES2 0 MWO7 • ` PMWOO PMWO1 PMWO2 • DWO8 • PMWO7\ Q DWO9 • PM•WO3 • 0 0 0 0 ®MWO6•MWOS i2A DWO3 SUMP B • 411111 MW14R PMW10 • PMWO5 • PMWO4 • PMW1 1 • PMW12 • IMMEEN i% V//i 0 0 0 0 50 150ft Legend Area 0f Dual —Phase Vacuum Extraction System (DPVES) Influence (From CRA, 2004) Approximate Location Of Soil Excavation Area, 09/06/91 — AT&E, 04/92 Approximate Location 0f Soil Excavation Areas, 09/30/96 And 10/01/96 — S&ME, 10/97 Approximate Location 0f Soil Excavation Area, 03/04/97 — CBM 04/97 Approximate Location 0f Soil Excavation Area, 04/01/98 — G&E Engineering, 02/98 Approximate Location 0f Soil Excavation Areas, 05/13/98 — EHS Field Notes, 05/98 Approximate Location Of Soil Excavation Areas, 10/18/96 — CBM, 11/96 Approximate Location 0f Soil Excavation Areas, 01/07/00 — CRA, 05/99 Approximate Location 0f Soil Excavation Areas 01/09/04 and 01/18/05 — Shield, 02/05 Approximate Location 0f Permeable Reactive Barrier Installed 02/05 — Piedmont Geologic 05/05 Area of ISOC Influence — Piedmont Geologic 01/06 SCALE AS SHOWN. DESIGNED BY DATE CONFIDENTIAL -AIL RIGHTS RESERVED -PROPERTY OF IBX1, NORM CAROUNA 27510 DRAWN BY TS H DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 7. Historical Remediation Activities BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 02JUL07 CONTRACT N0. J3-00004762.01 DRAWING N0. 4762-7 REV. 0 ❑ o a) Q ED El . c c d 0) 0 0 N T - En 0 U N m r 0 c E L En U O a_ m d ESO5DR Oxygen • • Cylinder ESO5SR Bank ES11 • MW42 • MW51 • MW44 Asphalt - • Warehouse MW-39 MW49 • M W50 0 Legend PMW12 • Groundwater Monitoring Well UW07 i$i ISOC Groundwater Injection Well ISOC Supply Lines 60 120 APPROXIMATE SCALE, FEET SCALE AS SHOWN CONFIDENTIAL —ALL RIGHTS RESERVED —PROPERTY OF ROU, NOR(H CAROUNA 27560 DESIGNED BY DATE DRAWN BY DATE TSH 02JUL07 CHECKED BY DATE LV 02JUL07 Figure 8. Existing ISOC Groundwater Remediation System Layout BP Terminal 4762/ Southeast Terminal CONTRACT NO. DRAWING NO. REV. APPROVED BY DATE MN 02JUL07 J3-00004762.01 4762-8 0 \`! raLIPMEVT hSCLOVJ E52 i/ E53? 7558.49 • TO2A 755.6 • • ES191 7 V7RFT LOADIND FtAICK 2 MW-59 775.99 ES14• 779.19 ,I UW054 779.37i V• ES15 1171 O.Fi /---•-- . 1 UVva4 1 1 Tril- 1 • VE07/ --- '-- T-{_77s:Fi4 1777.7 1-,--�--•._MY'J12 % 777.45 'RW03` •ES074 )10•;` J MW2 r' t �• VE04 i ( MW26• MW65 • -, 777.21 G V 9 ^ 5 77d.77 • •TM - w(� � •771159+ I RWO W Z13398• 37 iM1W�Si7N1'S2D W39 1 \\ '� as18• • ? i146' MW1E104 MW41 - - •774.41p•DW05 775.2E ES4 4 774.1 1 • ES35 771.31 1 • MW07_ Former National Oil Terminal Property I1(757.4�; DWO• co L0 MW3W MW02 753.97 DW0 (TM .•1) (753.D7) DW03 • Perm Re.: tive rrier • PMW09 746.93 e 4\` MW1AR• 71528 748.24 PMW10 • — $II II PMWOS • PMW04 • PMW11 • PMW12 • 0 50 150 Legend N M Treeline — - - Fence Line - - Property Line Railroad DPVES Dual Phase Vacuum Extraction System A Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump SUMP C 5 PMWD2 754.73 • (773.90) Groundwater Monitoring Well With Water Table Elevation (ft) Groundwater Elevation (ft) (Not Used for Contouring) 750 — Water -Table Contour (ft) SCALE AS SHOWN DESIGNED BY DATE CGNFIOENDAL-ALL RICHE RESERVED -PROPERTY OF ROD, NORTH CAROUNA 27500 DRAWN ETY TSH DATE 15FEB12 CHECKED BY SD DATE 15FEB 12 Figure 9. Water Table Contour Map, 12/5-7/2011 BP Terminal 4762/ Southeast Terminal APPROVED TW MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-9 REV. 0 .01 1* —7 r_1 `1 1; R._I { 1 I DWO6 \ <0 5 • E514 _ .1 DW10 II 1 4.2 y-1 <0.1 • ESN DRj jL81158it1 ♦ , II i ES131ccucocr, 05 ..ain:- II 1i r ; t� ll� Ij E529 E507) <0.1 I iI F ,.., i. • i ` ( c� I::' �rr 1 11II. ; 11I W 27 C 34/ 10 ' •ES4140 i f ,�' ES4302 MW-59• <0.1 I I ES19\ \ % l' u —i 1 I to /{ MW-56 0.64 • • ES31 <0.1 11I E523•, ,,211J 1, �� _l 1.0 DWO9• -.1. i r11 •.sal 1r , ;II MPO6 •PMW03 I/ / 1 MW66' ♦ J Ugti oo .a 10! (ryDW01A n • Loa; i I j TO ' U 02• VE03 110 • MW651 2 1 2:,f 2• VIM- Myym- V• y 1 I 1 1—'I I i ! I ES10 r- RW I I't4, • ES01 )' • u 7 I, /1:3-5 rr ,. II i I I J . MW51• / �_ 1 .0Z) (! /'' 1 S050 1 E 200 —moo t I I 1 • // / (62) ^- E511 • •MW42 �• I l_ \ < 1! 1 MW44• ii I \J 1 / - 1 3;500 I ,� o - 100 9.000 OEM r 7 MW87 �,♦ES2D 7 1— i1` _ MW39•, • Ml / Esta• L �30 -"-• i 1 `._--—^- +W41•M035 0J • ` I `'='`= jf- ce,v(<Myy2t2g;9_ \ _-^-.7—r— 2/ -k . 1r---._---_.-; 2too MW02 ESIS � gal 11 • ES26 0.1 . 4 MW69- �' WOB k , 1 \ ,• r 01 I p -- ES28 .2 I 1 r,-- , 1— 1 J it 11 1.0\ ES36 �— - 71 • DWO 2.B • L.. TO2A <0.1 2PMWO7 •. DW03 Permeable i Leect/Ve Befrrier \ PMWOB • PMWO9 • <0.1 •<0.1 , PC • MW56 '1 1<0.1 `------ 1 -- _.MW-57 % \) I _MJ47 I ---.-...� _� 1-------_____- I� \\ , / i �` .___ 4 �1 MAr_55 MW50'�/ 1. •7J-/ \\ 7t \ \\ 1/ �` PMW10 • \\ /MW-53 =, •.n�< MW-52 1 • MW14a• <0.1 (Tht co,, ti) _`_. � ..—_=---•_._.� "Egg' I _Li 1 \1 PMWDS • PMW04 • PMW11 • PMW12 • DW01 • 0.2J (<0.1) J UJ 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Benzene Concentration (ug/I) Groundwater Benzene Concentration (ug/l) (Not Used for Contouring) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well Benzene Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENOAL-ALL RIGHTS RESEWEO-PROPERTY Or ROU, NORTH CAROUNA 27560 DRAWN BY TSH DATE 15FEB12 CHECKED BY SD DATE 15FEB12 Figure 10. Benzene Isoconcentration Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED sY MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-10 REV. 0 Ir u ES43• t, ti ES23 � ES35 2.9J il I i' I ° , E 14• I11 I .1 • '{ ES 3DR : ES C i 11 0 I r ES12 ! l � 1 • � --,-_:�_ ES29 ESo7�� —• U 11 DPEW92 i •: i 1� [: .� �) > ) I M a.W67 ° i�_: �G.1!•J.• -515 i NGA88• •191 ! _ J--,_�{� t�-f -e530 "�i j Toe ` • III J.�� Lluwoa• • �szfi 1` n ;l I' at I I Dwo1A• �I uwDs 1 �` II 1 '{ j � � tl7 Lj LI TO =0�2 2 h - . mil � Z8 I' 1.1 7 ' P _0-! VPQT I UW02• •UWtt �I ! 'r-.�.,.� li I i t NW12 i 1 ,, VE03� -'ES03 _.t f `-n _ I' • MW40--- • •, E537f• DW02'-'-= i E510 _ �i �" •NyV21 VE02 '_ ---� 0536--.- -__ ,- •-------<6.1 i • • i. II MWYI • I J7Q 11 TS ry: E901 L.I .<0.5 2� , 04 NW05 • , • I `�/ ii MW43i-- MW-5S 1 1 ES� J i 1 11 i/ 1 I • E931 • <0.1 73 -_, 1 •73 DPEW01 I •'-"�ES3� y • DWOO j " j.,, ii,— �TfJ m9 't` a <$111/ 0•A501 $� MP06 •PMW03 102A• I_,.. , . <o.1 11 1 �‘ES05DRN ESOSSR _--_`MW?1 ��.-.-'_I i ..� II I�._ � •Dwus l / 0 30J ,____ E$111 • I �".__--�-./ �` ✓� 7f 1, . / MW4t MW44• . "� NV-66 cr RWD2 I}1 W37 w 1 f MW39 �1 •-h145•NIW50 / • c0.6✓ E510 r 21 MW30i $._ i 3 0.14J• Lf._� I MW�—/'��•N:25-] •MW3fi l \ 671 •+ ___ N 'ifr�2.'LJ MW09 MW07_ i r,'.-- -9-• r3 �_ NW3W7( li -0--------... , -_____---1 - --=-17-7-__:- -._ 'MWO1 iPMW02 t93 • PMWO7 DWO3 • <0.1 MW-56 Permc'l, [le Reactive Barrier PMWDO • PMW09 • 0.1 `"arrr,l INa/i:.n51011 Te. min.! Proi,eriv Mew33` \\i \\ MW-52 1 • PMW10 • J, J 2 f PMWCS • PMW04 • PMW11 • PMWI2 • 0 50 150 DWO11 • 0.OJ uJ Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Toluene Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well SCALE AS SHOWN DESIGNED BY DATE DONFIOENIIAL-N-L RIGHTS RESERVED -PROPERTY OF ROU, NORTH CAROUNA 27560 DRAWN BY TSH DATE 15FEB 12 CHECKED BY 5D DATE 1 5FEB1 2 Figure 11. Toluene Isoconcentration Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 1 5FEB 1 2 CONTRACT NO. J3-000D4762.01 DRAPING NO. FIGURE-11 REV. 0 1 / 380 • // <. -/ 758 R i I % E/ 0.47J 7 7ES11 i 500 • I M 42 • MW39�iy-- 4=-•MW50" i - 1 :ic 25 • '' .s6001 p�g•c N "'--- '•tom--:—._ __.-----:-.MVV3W ,/' c STk E50SG[�EsYJut VN7IYC RACK ES12 W7 D• �= �..y 49D, I f TO1 01 • I� rr� I r _. !� t— • /�--• ULIi 02 60 WO (W0lAz• •IJw11 �I i� MW12 VE03 RWD3 5-5' 21 • MW46 ----3 6 � -_... --.• . • DwD2 • asa - _ • j MW2rL - MW65�� M -57 j .MW2 r�MW�6 D� 4—fv1WQ5L-..✓ -��_ r_ 290 1-) Former National Oil i ermina! Property I J Permeable Reactive Barrier PMW05 • PMW04 • PMW11 • PMW12 • 0 50 150 Snip G'a DW01 • 13.8.1 J w Legend Treellne Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Ethylbenzene Concentration (ug/1) Estimated Value Not Detected and Detection Limit is Estimated X Abandoned Monitoring Well 600 Ethylbenzene Isoconcentration Contour (ug/I) SCALE AS SHOWN: DESIGNED BT DATE CONFIDENRAL—ALL RIGHTS RESERVED —PROPERTY OF URS RDU. NORM CAROUN4 27560 DRAWN BY TSH DATE 15FEB12 CHECKED BY 5D DATE 15FEB12 Figure 12. Ethylbenzene Isoconc. Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING N0. FIGURE-12 REV. 0 _— -- --- -..,..).. \ -• ...-' )`-' O i ES41 ',47.7:„1-.‘, p-.7- ',. .....• 1 ,...----71--'-\\----,,, • '?. i A' '‘.:.,„ ES43. ,. ,------ \ ' -.: E523 , // ' Permeable ,-.›,-, 7. 7..eacve \:,',A ,/ ,, ..-.-_,,,_ .•-,..\,:v ,, / -,:-:,Y.t-- i • 0E.s7L5 %.,/,,,, ( I , I 0 I ( .----,,, M<W0-.51911! / /,i ..,„..11111,,,, \ l'-----‘ : \ t , • (r ) MW-58 50(9,;^,Es33_ 11 PMWOB ( \ I / \ ,.., E19 \ \11( \ \ , i y 7-7k, / 0 i \ ' 1 ' 41.MW•01 \ \.` i • I, • 0 / 3000 5.,3Lly'F' fid 1 DPEIN,i0( ,.,. E1532 gkn 90 • ) .7\ 2 3PMWO2 • Dwi 1 il os PMWO7 1 , 1 1 \ ?t: I D.W.106‘'c.\_ 11545e I A else' I ; i 1 !.lI.Ii .. I iW• 1f, I°<7 / ..153 Ti -1•_. -----6-. a._,.-W•. i_It_r1E•1_G,L1s7:•.'.2_i„ •_-\i j-_,-_U;-,;,: 1 11,, )1 -..-.- , A,)../....r.__..f,...„_....___• ._-T,.„_,,_, '_''_. Ir__;- ;... L Ii , .•„ i Tt' s„iA.sS01 j I l .ne.pm, w'seD-- , PCAWO6 , pmmi'g.; ,.'.''',',,.,‘,',,,, ,, ''',,,N,• ‘-, ,.`\,i• §i•1.•<o.l i E.2 !11 uwco_OPEV02 7IEs2gEs07/ .oie0wES30I,N1L- v .,if in040-•ES26 (PMW1\.,0,__i fi,iia0.1 .‘.—mv6gs,DWO3 -‘---'iV--/\•<01 •,-.'i5oDWD1A•1ii(‘I i VE4 ipLL701 ,• 5s28 t upr.MW56 s• , , •,L1,1,-/,-..,,,,-.,.,.,,;.,.--:)...e-,.,,__•--/,_- ‘,-‘-.--,.--__-') ,.. .-1\,.1,11 I; --r -„'--E''---'SC,-,---2---\• i-/0,--' \1 ,\ ...e.\1 .7S'/',I,.L/<'/,(L•,.0t/: -:•-.'.1/_ _Ii_,-_/._,i-•-_-.,_ W8,,,7,_,,,•-:1_:2 -.1 _5-i602kr,--i_11i,5F0t.w,' ,2 i 10_01am0amTJ'w w 1,1_-i1._41.m__.,•—_v_--r'' _-4.-v:'__r.'_.-4i-if t-:ii.-l -.t-i,..-_._-:.i-e _.-i .'-.1r-.‘ _-.6_--1a_1_.•9..9;._ z„._.0_......„z-. --'-_--_4_----.__---_7-,—'_ o. /T- _e..'__.•.,,_)\ _•_ ../....._ \ _ ,..5\_ 3 ,/ RW03-MW21\ •;MW48-.7:1I/ Es103 1 7 :w65yre11,ES•:.mv47 ,., 11M,,•W\ 5..,21E517/ 52• 1 / MW2 /MW26 VE04-1W-MW4;r117'-__---1- ,6; I IC/ : 7( ,iiIII,,r0IFlC\'1, 1 ///1//ES0 53RlE1°5SR1-j,,.; LI -) m55 •7/ -__,,.W_.„(7) \; 311/l._,- w9, o.mwo2-mwoa__"37 ,-m444R/ _mw31 -iF M Ik t' Foi.f‘rier Niatiena.1 TE:anizial Property 31 PMWDS • PMWD4 • PMW11 • PMW12 • 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant p- Lamp Post Protective Steel Bollard Power Pole Sump DWO1 • 0.65J Groundwater Monitoring Well Groundwater Xylenes Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well — 500 Xylenes lsoconcentration Contour (ug/I) SCALE AS SHOWN DEIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OP MU, NORTH CAROUNA 27560 DRAWN BY TSH DATE 1 5FEB1 2 CHECKED EfY SD DATE 1 5FEB1 2 Figure 13. Xylenes Isoconc. Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 1 5FEB1 2 COMACT NO. J3-00004762.01 DRAWING NO. FIGURE-13 h V c • / r. Imo._ �\ ,\ / //� r,i'' /5:>-'. 4...,- -'' ES34 ,,..4 `�, - 038J E540 0:16J /' \ ES43• ! J // A\'......_'\\ \� ES23• r:.. } MW-59j ' <a.i I t • ES35 _ • 0.64J • Permeable Reactive Barrier 7 I/ / �\ Ea \ j I ,„ _, ! PMWOB i I/\ t A /�� 0.39-J• �MW01ir. 2U03,200 E593/i I t J 'I- '� ° ] i -' � Di 0\1 >r`2^0F.1,0;n E! S• �il .`-�,, I CW1201!,800DWo 307.3ES132 0�;rESO3GIiI--_71,217.,.rrt.s;!..., i��. __�I !"-_•2.8E51a�I•E531 Q _ i\20' I2m,. 1• y1- �L,:D• W•OA !�;230y PM� 62(6•PoMf W03 PMWOB •PMW09•owns 2Q♦ 0.63PMW07 i 4.2 j ! IJW05f` , r^ /., Y'`- ES29 E507 12 • M ,,7 '�f D;,�� 1 ,,,, -•E`� `<o I• • I_ ss� •180. �� h L i +!'� t�`/ ES1528�- TO - I �'--�--J� E530 c' i `�.. "��• I, !� �` / r/' • .fu o4• u o5 i • Es26 • ., �F... L. t �� 1 0.59 1 . `,._. ! �e �--- r\� . ju IVIW68 ; MW r \+, I L'^1 ':, rI i I(,: WQBI r I / . r 20• W03 / \�; ' J IDWO,tA• Ir( 70 / I��•-� / t iW011 TO <..., S28 I�A\ .-'� l % ! ,. ! U 10 240.�� !: 1• - r,�---�.-,.� JrM1f= a M• W-56 I xn ! �` I i • UW02• 1 U 11— t 3\ iMW--53 IT Mw1 VE03 Ei503--_'ES37-�20_'_"'-_—________I _-' ° / t jt I I {_-<� f RWQ3, SI,1 MW21 •VE02• •�48-- E5 6.._..• ._...,_ • "�:•�52 a2 <.� ,'�� `�`� `� I. Es(T1/' ESIi-4• !� MW27• MW6 6900�, t 24 -------_--_- - MW 57 — `,� 11 1E517/ i <0.5/ / ,MW2 �• • VE04I • __ k �.�.� �� `t - .t.._% """„. 15017 ! t (�. MW28 II WOS MW 3 i-�,a--.\ ,�c_._„ln ~ r" �.I;.IPG /.' ! rt'' / 20'I MW51• I _f yr/�- `\ / . ! `' .1= .. I J / 20 ES05SR - off __ 860 \ ., l �� i' + / `E6d5D 3.O4 2 000 / ? l \ ` �i ,`� ' 77 r `tE5111, MW42 i ` �� r^ �� �\` `�� �f \ i _-; !! i MWp4--- 'i\-,J.,j MY�55 am/ / 7 ` \�� �� �� _ 20 INVITE r f -� RWO W3 j �!.•ES20 4T I` L MW39 � M�45 MW50 ! -`-� I ES16 t..,_ 5 7 3 - � . O M 6 ( 1 h \ i . ,.- . I" C �f 0.15,• �_._ • ....•41 n oc__ 94 / % t� ..� 1 / / MW14R•2.7 L 11 ° 70 r r Pc)rfrc:.._:iic, - —•_ _ - - MW3W Zy.ti� PMW10 • MW-52 • h I� I$ 2 f PMWDS • PMVVU4 • PMW11 • PMW12 • 0 50 150 Sump DW01 • 0.71J (ro 11) UJ 20 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater MTBE Concentration (ug/I) Groundwater Benzene Concentration (ug/I) (Not Used for Contouring) Estimated Value Not Detected and Detection Limit Is Estimated Abandoned Monitoring Well MTBE Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL-N1 RIGHTS RESERVED -PROPERTY OF RDU. NORTH CAROUNA 27560 DRAWN BY TSH DATE 15FEB12 CHECKED BY 5D DATE 15FEB12 Figure 14. MTBE Isoconcentration Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED 6Y MN DATE 1 5FEB 12 CONTRACT N0, J3-00004762.01 DRAWING NO. FIGURE-14 REV. 0 O ' <<\ ,..<_,__;,---\'',,,,,,,l'. ,,.-',.f''':;;;-";''r'.'"':'I'j::C''rr<E'D:.13:':::: >" 55 ,, ( II <0.1 j 1 i • 3335 !. i i ��^-� 1'8Esiii[fl_s_siRi.,.,71; j /%025J1cJ�- � i ��I�DOWO6 �DW10 1I / I<0.1 • IES09DRII' !P.",if•�_UWO5�OPEW02� - 81067a.��I �'-``I t, ES29 ES07� 01 •_2 _ t.. D J 1r „F, l 11 • , --:�I I i;! %__ES15 64i 1 �`=--` n J ES30 .' r". AM04 • ; I -' 11 _til-al `--^-1 i i- r1 RW E510 I i //Jv1W2 3 / / \ES sD DR• �` i 4.0 / 1 ES18 ' — � 3,6 • =--._' IW1 58'' MW26 VV01 .�3 OJ:J 7 UW021 v MW21 . MW65 5402 -� VE 4-fMWQS- 11 601' ESDSSR 30 \ 60 • / ,MW58 - • ES26 <0.1 W6 *MW69--k ✓ssM 56 47 j t 1 / • £ I PMWDB \ ' 4-A I h • Y._\�4., PMW01 I 1 PMW02 �I 50 • DW09 <p.K AS01 21I MPO6 •PMW03 Dw0s <0.1 ti�s4 Reactive Bar ilor PMWO7 •� PMWO6 • UWO61 ! 1 •II" • ' MW51 ✓;...--- 510 ES11 1 V,A42 JI•MW 4 ;; , RWO2 43 W37 MW39• ' • :Mw45 •1 00 • _7 . �.,I 8.63 •470 ;--01--• --MW02'-_..-MW08-----^- -""---=_._ 19- 43� "-- MW07 21 _. 60 MW38, I( N5 Dom, J,7 �Yr • SSUrd DW03 • <O.1 �_--- ti ti PMWO9 • <0.1 \-\ \,\ f MW14R• 0.33J 1 17, L• zl4 W-53 \ 6 PMWDS • PMVV04 • PMW11 • PMW12 • 0 50 150 Legend ------•- ---- - Treeline Fence Line — — Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DW01 • 92.3 (0.45J) J UJ u Groundwater Monitoring Well Groundwater Naphthalene Concentration (ug/I) Groundwater Naphthalene Concentration (ugh) (Not Used for Contouring) Estimated Value Not Detected and Detection Limit is Estimated Not Detected Due to Blank Contamination Abandoned Monitoring Well Naphthalene Isoconcentration Contour (ug/I) SCALE AS SHOWN Or3IGNE0 BY DATE CONFIDENTIAL —ALL RIGN1S RE5ERVED—PROPERI7 OF RDU, NORM CAROUNA 27560 DRAWN BY TSH DATE 15FEB12 CHECKED BY 5D DATE 15FEB12 Figure 15. Naphthalene Isoconc. Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-15 REV. 0 <D.1 j•ES41 1 ter. ) f x S yr ..` ft ITti�' I ' I� 2.3J, 2.9 ES14 1 10-4 • 061_--- 1 I ES r-tSP.': ( ri ES03D Ftj 3u:jJii I•ES12 UW05•= i DPEW02 • '\ .. Iyl „•. 1 E929 E507 cp.1 • MWfi7 • • / MW66 • I r •.„ i-�(f ES15 I�-cl <0 8 I<1'p;,4 .�_ -• • ' EN40 <0.1 ES43• \yam MW-59 <0.1 // � x r tUW04• 1 J^•� I 402 f., !---..1 t I wfiB•f,` MW691 UW10' 1Dw01A• I-�uw06' ---L-�-=.��i VEO7 I UW02• !Uwt'I 7 �2 RWOill ,•1 MW21 • IMYJ48`-•--E�38� ES10 Ipi •7' • vE02 ``'•-, E535 <D.2• ES3Y <a t • f' ( • MW27i 6r ES17; I `0 % I/ %.MW2 • VO4 /VV05- • 7747 .._,_,_::_d7 ' MW28 11 it • ill i ( \• `i� ) �- `9SOS E5956R----.55.01 ( 1' 't <1.0 I ij-- % 1 L / -_-_jESi1•MW42•v__ M▪ W44 ii - -___ ..— -- - 1 RW021 - MW37 0:25J E918• MW3 ' '- 0.91 -`----MW41 Q4 4 M1249 ^ i M�145 • MWSo �i i \. <0.5.`..- W36 • MWp36c ��g'*SMVZV002 -MW08--. Na ES20.' Y / MW-58 / FS'29 <0.1=...... I •<io 4J;�P DPEW01 •ES32 I ' �•� -� <p.5 /+II1 1.0 ¶MWD1 47J4 D3 OB 1!!� DASD ill ••AS01 IMP PMW03 -MW57 _MW3yy f: ( it Q cjC' n=7i 01 i :"Prooperty tl PMWO7 Pert r1eais Reactive r > : 0.4 1 PMW06• • PMW09 0.11J 1 Li • MW-52 1 • MW14R• <0.1 It PMW10 • PMW05 • PMWO4 • PMW11 • PMW12 • 0 50 150 Sun, S_ DWOY • D.99J J UJ 0.40 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater 1,2-Dichloroethane Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Esti mated Abandoned Monitoring Well 1,2-Dichloroethane Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGH15 RESERVED -PROPERTY OF ROLL NORTH CAROUNA 17560 DRAWN BY TSH DATE 15FEB12 CHECKED BY SD DATE 15FEB12 Figure 16. 1,2—Dichloroethane Isoconc. Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-16 REV. 0 a a C ES17 EL L1 /' +•ES41 // I�' �_ ES43• r \\ `4 , / f � t F'' . v' U Y MW-59, -* ' <0.1 I / 1 • ES 35 r\. i w s �", �• �� �-� �� / • - -- (' t I PMWOS ES10 1 /,� , i \\ / / �• 1 \ ` /, MW-56 YMW01 1 �-- j - 1 I • 0.26J / ES33 7`!I li ,/ \.� .� DPEW01 ((I -_ •2 i -Ljf. _ "'---," '-. r-- I %7 099? I PMW02 f2 • D 15 DIMO6_ 08 Es14• • 70 ES31 I % I <0.1 rill - I DW10 h--T•,il t / 0.34J • ESO8DIY CS08S 71 II �'- / I _ , 11 ES1 70 t 130 PStz 1 tp�� - ;. 6 • 1 I uwas--=_ I DPEW02 \ ; -- 1 ES29 E507 U. t 3J • I ; ''_ . t ES15 II-Ti uw0 j • 1Iuw04 '' -Y1 •j 4Di i •ES26 _ f 1 1 A� �_ , 0.11J C-__) y l: 1.4 � MW69--.. I t_ I .• _. UW101 fDWD1A• ��,�UWC6 _ '4 I' _ l 70 i I j I -10?Wo1 t ,.• i =- : '__3v•A7uwo2Li•i 183 ✓ ES28I 1 t •UW11—t---L - i �� , Slit ."� • l MW 66 .__-J�- R -,,,,_ .l2 MW21 „ • 3;MW48--• - •�3 -JE .. • 0WD7 `.-_ ESN} tl 3 • , • VE02 t •�_ ES38" -_- i 4.9 /. •,Li MW27t.. •MW65 26 1`J--_.___ _'. 0.38J--_-._._.___ _--"--_ •• TM-- 1 / ,MW2D- MW26 VI 4 MW05"- • • I`=-- MW43 i if �70\{t / — - Y%�, � Sao <0.1 • ". A40 ` <0.1 ES05SR it,-----MW51 ' 'ES050RN .4T1 !1 'I - i / 3.6 �/ .-=1 ;\ \ . / MW4 - �3 w� j __..- MV5 •DW05 r__---.RW02 jNW37_�, ES20�4i_-_-I1f�•••MW0. /16 ES18I 1_,._M0W3 .739,•MWL358M1R45'ttM<055:-' i <0.1 • `--1W-<D-W36 --M•MW49`.---� __ - MWO2 �-- - ... c ES30 I^ • I ,.:-Tina. P.oper.v MW 57 I 1 1 <!j riAS01 tih MPO6 •PMW03 PMWO6 •PMW09 •L.. • 0.54 TO2A `-` PMW07 • PMW1 D • \ MW-62 • t11 jIt MW1.1R• 0.44J ES26', -- PMWD5 • PMW04 • PMW11 • PMW12 • 0 50 150 ti4 DWO1 • 0.97J 70 J Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Isopropyl Ether Concentration (ug/I) Estimated Value uJ Not Detected and Detection Limit is Estimated Abandoned Monitoring Well Isopropyl Ether Isoconcentration Contour (ug/I) SCALE AS SHOWN D6IGNE0 BY DATE DONFIOENRAL-NJ. RIGHTS RESERVED -PROPERTY OF URS ROLL N2RTH CAROLINA 27560 DRAWN BY TSH DATE 15FEB12 CHECKED 8Y 5D DATE 1 5FEB1 2 Figure 17. Isopropyl Ether Isoconc. Map, December 2011 BP Terminal 4762/ Southeast Terminal APPROVED 8T MN DATE 15FEB12 CONTRACT NO. J3-00004762.01 DRAWING N0. FIGURE-17 REV. 0 ¶52 rrss- ES19\ X \ \, v __/, ES1S,' 1 ; DWD6 \ j �t� •ES14 j 1 DW10 I, -"ri } ! I ESOHDP II 1 • • 1 �,�� } ES13 ccvcPro I Li��Tic a--�_—.:L I ! I O DINC ll 1� = 1 ES12 1 ES060- DPEWD2 + r� � r Li iro4'�. •MP05 ES OS E507) • UWO • UW011 E ` ,9) • lit\ 1• i-1 f _ E515 I WD l !l f it 1 II fr' !S34 j•ES41 1 '' I S44 I ES39•.! MW-59! 1 / } Ltl f (r / it 3,/ /f Es050R•• ES05SR ;l— / ESt15L- .SO6' • ` •DWO5 E'S40 ES35 P 1 PMWDB \ MW-58 • \ ® � PMW01 1• '-1 } •DPEW01 SES32 }1 PMW02 IPe2 } fj • 'I • DWD6 •ES3' a .-� �. If Pi..i ' . DWO9• Si ••AS01 j �. MPO6 • j PMW03 T02A = • ES26 `L• ES43• � ES42• i 1 Es33 i u+n az� ES30 • PMWO7 PMWO6 • • PMW09 ?UWO : \ N'N / I TOT 3W01 t,. f �• ,/1 ,.� I • � MWU3R \. n 1 r} UW,10 i'.! }�P '- P - E528 11 `Y:.,, j 7 `\ SU,.4i� L • • 1�---• UWD2 r { „,_�1 t MW56 i 1 • i - .--U.___ vr07 • •UW11---!_ ��_ =., !MW-53 r L -- -� 'r 4 i / 11 1} MW12 ;J Uv,403 VEa3. - �- ��jES371---_. 4 lx ('� RWD3,_ MW20 • IMW48 •-- • DW07 - • ' / 1 E510 •r • • •VE02-- --(• ES38`E503 _ • E50o MW-57 / 1 • ES01 �S • ! J MW27 �VEOG MVV?7 OVE1 -- _,_ w' t 1 i V--06 • VE{15 • • MW47 t _"'___ .�/ MW26 VE04- WD5- • w " ...--„-_-a._ __"�� i _-__ -+-'' / MW51• } '; ,` 1 I; � :{ s11 } it } MW4 • MW44 /-, ----t RW02 _ MW87-,_..( _"., e- 45 MW50' / L MW360 ! MW45 / MW38 1 MV55 ! ; - 1----'-_=,�,--_- ", MW„9• `_•I�" MW02'_'_MW08- .�_-' Former National Oil Terminal Property MW04R • ,-i MW14R• It = Spb# PMW10 • MW-52 lk • PMWOS • PMW04 • PMW11 • PMW12 • 0 50 150 ❑m, DW01 • UWIi7 ESD5 0 Legend Treeli ne Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Monitoring Well Missing as of 03/05 Groundwater Monitoring Well Abandoned 05/05 ES1n Groundwater Monitoring Well Abandoned 09/08 EVALUATION AREAS 1 EAST SIDE 2 TRUCK LOADING RACK 3 CENTRAUUPGRADIENT 4 CENTRAUDOWNGRADIENT 5 ISOC SCAT AS SHOWN DESIGNED BY DATE DONFIDENDAL-ALL RIGHT RESERVER -PROPERTY OF RDU, NORM CAROUNA 27560 DRAWN BY TSH DATE 27MAR09 CHECKED BY JW DATE 27MAR09 Figure 18. Groundwater Sampling Data Evaluation Areas BP Terminal 4762/ Southeast Terminal APPROVED BY JW DATE 27MAR09 CONTRACT NO. J3-00004762.01 DRAW NO N0. FIGURE-18 REV. 0 • L.. a, 0 col c c4, 4) a, 0 It L \?:' I , 1 1Iir \ , .-- .,.• 0.DWO6 -0--- !1 1,-•...-..-IE' . :.'S,.A.‘..1, 4-- •S1+1, 1 l • —• -f1I1j 1 1 1 TA1•NK E77.S6_4_1 i I DW10• 1 1 / I ESO8DK ,"„_' 1 / i / ES13 'COVERED --r'i/ I LOADING muZipEpiF----c t0.34I1/ ..1 RACK C-I1/ I I I • \ „\IP i UW05--1DPEW02\ ES9ES07 6.15 • SL012 4.07•/ --.l 1\ 1! \ I ;V ES15 -"-,i ES.i1 3...-0 _u,pII • II iUW0•/ o IIii Id; .- fili I ) I 11, 1 111 1 I/ '''4i.2 il ,,,..-rf,-----,-1-'27-7-r-10 I iw /- \ 1, ,.. , 1 II DW01A TANK ) ii I 7 I 1 I 1 , . / ' 'fa z I rf I 41- jUW06 ( — 11 // r ft,--- "ff. •01/L3'• 1, ; , il ( / / i ' ' ' TO1 i Awpi 19 \N /0 11 I TANa i 1 a 1,2> „ , I 1 , 0 i il 1 j Li (7-- I R0.44 -7---.-----/ ES28 ;I \ 115 ! i \ I 1 II II II. i i 1 ; I i f • ES01 i / RW03109/ 1 i i ; i • ES10 in; I I I. • HI MW27-.,- ,/ MW21 'i0E0092 / 7----1--,----- ,,,NM - 1 :;'-:, _ ; 1 L-7-7 1-_-__T--7-1..1•// 0 36 1----' ' --1-_- 1 /UW10 • / •UW11----Q-- I: 1--- i____.' VE07 •TI----• ,, mw fi-- • • • / - _... I • NM ----------e_ 4..97 / Imw4.-8—____• ...--- ------ES37 i • DW02 UW02 _S-0_3---------11 I L;=-------- , ; ...1 1 1 ,, ii 1_ 1111 \ • 1 1 II/ I ES171 1 ‘.... / e , /0--------/ I i , , i• / / / i..._ _.... , ,...„ , O .31 i / '----j , / / ,MW20 // 0 / // i // 0.19 / MW26 vainA r7 h I it 911VO° 5 MI I IV V -4, 311I- i'll7 1.-- v E,- .- i 1 , 1 /1 .. .1,. '-----=----=----------MW47 _ - ..,...4 / L____. r 1 If : RI I a. 1 „------ -----„, \ i , --_.----------_ , --- I ,- \ r..:__-7A \ — 7 — IILI I: MW-57 ----_, \ i I „ / // 11 I f 7 i , (3.24) •441 : ;13,---__..--J.i, TANK 1 1 il I . / I / \ \ TA1 cf,J.K 1 i 1 / i 1 /' '-' ----7--- ----------MP.W4551 '‘': ! 1 i 1 / t / , /7‘f,, ,...;Dsti wirA,... EoS.4065SR 'ES05 /I I •\-.,__,-_,.- 1_ ---7 1 •-,_ i ' N \ ,, // .... -... - -....,....,.. ; __ . f---- •6'2±11. I .1v5N37_ -1„1--;(--------lcl , -----) -7/TANi.e) 1 . \ 105 MW-55 • ,. -____---/ 1 1 , ,- 17-1 ES11 • I , Ii 1 1---- '1 Ti/fc,N2K ;i aTt.,, \ \ / / • ------- I ,.. 1 MW 42,---____WIIA/ 44 1 ! ; \\ DWO5 1 1 ----------a---1 R 2- :1 1 .t-___ 1• OW. 2461-41V-11W--3—:w77-7--- t r I \ a ES20 e- , I I 1.409 I M 11 1; I 1 • ES26 2.93 TANK ,04 p; .,/-rtr` 11 fft MW3W 9 TANK I 17 ) t , DW 9 5.4 • ?( .0AS01 w • MPO6 • PMWO3 • TO2A 1.70 • DWO8 DWO3 • 2.23 Ei • MW-56 ---------- Ree,c 1.110 _ i 1'-1,",..g.;,' _ I -'1. f 1,...-;4Qess- Illig 1.-6:444.2411-L-..,43*`":4 il.. ' : i t--„, 4 0.,:_ir--,, ,,_ lif 14ez.bN.1) 7,C) _17. ,..,,,,...„,.._ r,-„,-,-----7:,,zzlz,,,,,,, - -.• - '---- -----5:4,,,,,..-....--..:- •- .. SITE MAP :Zf.1tIrno, 12_ Legend Treeline Fence Line Property Line Sump DWO1 • Groundwater Monitoring Well Abandoned Monitoring Well 1144 (3.24) Dissolved Oxygen (ug/L) (Not Used for Delineation) Dissolved Oxygen (ug/L) <1 mg/L Dissolved Oxygen Boundary (Approximate) 80 SCALE AS SHOWN DESIGNED BY DA1E C0NROEN11AL—ALL RIGHTS RESERVED —PROPERTY OF RDU, NORTH CARCUNA 275R0 DRAWN BY TSH DA1E 21JANO9 CHECKED BY MN DATE 21JANO9 Figure 19. Dissolved Oxygen Map, December 2008 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DAM 21JANO9 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-19 REV. 0 Document 6-1 y a 0 • DWO6r----_ - DW10• I • ES13 (COVERED 'I, • DWO5 • ES20 r— LOADING •ES1 i RACK ES 12 j T • ES31 r1 1.0 i^ 1=-i�FI: ESO8DR ES08S•R1 I LLI- n1 MULTIPLE PIPE -_ S UW05, I DPEW02 ri.-f ,,N!c ES 15 `'D 0I,• _.._--= UWO; //\MW20 ES18• • ES26 06 I 01 t -- E•S28 1 — ES03 — �!ES — —._ E• S -- • --2M W47 MW ��� ���'r', MW41 MW3 FORMER bPVES EQUIPMENT`' ----ENCLOSURE - M W� MW50 W36 4/0 MWO 0 �r- 1.0 ! I /7! II, I I ( TANK II 1.0 71 • DWO • MW-55 --MW08-_------MW07 -- `- MW3W 02 r TANK \1 .-� DW 9• z � •AS01 i MPO6 PMW03 • L, TO2A TANK 5 MW 57 DWO3 • 1 • MW-56 DPVES u�. DWDI • 1 Legend Treeline Fence Line Property Line Railroad • Dual Phase Vacuum Extraction System Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Abandoned Monitoring Well Benzene Isoconcentraton Contour (ug/l) Proposed Trench Location Biosparge Well Estimated Radius of Influence 0 80 SCALE AS SHOWN DESIGNED BY DATE CONRDENIAL-ALL RICHES RESERVED -PROPERTY OF URS ROU. NOM CAROLINA 775130 DRAWN BY TSH DATE 26APR12 CHECKED BY AWS DATE 26APR12 Figure 20. Biosparge Well Layout BP Terminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED BY AWS DATE 26APR12 CONTRACT NO. J3-00004762.01 DRAWING NO. FIGURE-20 REV. 0 APPENDIX A APRIL 29, 2009 LETTER FROM NCDENR ArA NCDENR North Carolina Department of Environment and. Natural Resources Beverly Eaves Perdue, Govemor Division of Waste Management UST Section ARCO, a BP Products of North America Inc affiliated Co.... 501 Westlake Park Blvd., MC 20.111C Houston, TX 77079 Attn: Paul Taylor TransMontaigne Product Services, Inc. 200 Mansell Court East, Suite 600 Roswell, GA 30076 Dear Mr. Taylor: April 29, 2009 Dee Freeman, Secretary Dexter R. Matthews, Director Re: Notice of Regulatory Requirements 15A NCAC 2I, .0106(c) and (h) Corrective Action Paw Creek -`BP/TransMontaigne:Terminal 7325 01d Mount Holly Rd., Charlotte Mecklenburg County Incident Numbers: 6771, 15159, 15618, 17002, 17262 & 20622 Ranking: H250D The Active Remediation Monitoring Report (ARMR) received on April 6, 2009 has been reviewed by the UST Section, Mooresville Regional Office (MOR). The review indicates that: 1. Welts ES-15, 23, 32, 33 & 34 were repaired in December 2008; 2. An obstruction was removed from well VE-02; 3. Tubing for the ISOC wells was scheduled to be replaced in March 2009; and, 4. Your consultant requested a site meeting to discuss potential modification in the CAP required in the October 14, 2008 Notice of Regulatory Requirements. Current travel restrictions made a site meeting between the UST Section incident manager, currently myself, and URS Corporation — North..Carolina (URS) representatives infeasible. In telephone discussion, Margaret Ness=of URS indicated that biosparging or ISOC technology were being considered as remediation technologies for the central plume area (centered on UW10 and MW21), and that implementation of a treatment system in the area of the eastern plume was not recommended. An Equal Opportunity / Affirmative Action Employer- 50 % Recycled 110 % Post Consumer Paper CAP Addendum Required — BP/TransMontaigne April 29, 2009 Page Two I concur with URS's recommendation to implement active corrective action in the central plume area at this time and to continue to monitor the eastern plume. A revised Corrective Action;Plan (CAP) with a schedule for; implementation must be received by this office within 75 days of the date,of.this notice.-. Failure to implement the plan and schedule in the Manner and time cpprifiMrl may raenit in t1hP acceeempnt of civil r naltiae and/nr the lice of nthrr Pnfnrr.Pmpnt mechanisms. Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer, certified by the State of North Carolina, is required .to .prepare and certify all reports submitted to the Depaitnient in accordance with 15A NCAC 2L .0103(e) and 2L .0111(b). If you have any questions regarding the actions that must be taken or the rules mentioned in this letter, please contact me at (704) 235 — 2171 or at the address for the MOR listed below. Sincerely, Edward G. Leach, III Hydrogeologist II Mooresville Regional Office cc; Margaret Ness, P G., URS Corp. - NC 1600.Perimeter Park Dr., Suite 400 Morrisville, NC 27560 Shawna.Caldwell, P.G:, Mecklenburg Co: Government GW & WW Services 700 N. Tryon Street- Charlotte,NC 28202 UST Regional Offices Asheville (ARO) — 2090 US Highway 70, Swannanoa, NC 28778 (828) 2964500 Fayetteville (FAY) — 225 Green Street, Suite 714, Systel Building, Fayetteville, NC 28301 (910) 433-3300 Mooresville (MOR) — 610 East Center Avenue, Suite 301, Mooresville, NC 28115 (704) 663-1699 Raleigh (RRO) —1628 Mail Service Center, Raleigh, NC 27699 (919) 791-4200 Washington (WAS) — 943 Washington Square Mall, Washington, NC 27889 (252) 946-6481 Wilmington (WIL) —127 Cardinal Drive Extension, Wilmington, NC 28405 (910) 796-7215 Winston-Salem (WS) — 585 Waughtown Street, Winston-Salem, NC 27107 (336) 771-5000 Guilford County Environmental Health, 1203 Maple Street, Greensboro, NC 27405, (336) 641-3771 FTP: CAP reqst nonustNOR0209.dot APPENDIX B SUMMARY OF HISTORICAL GROUNDWATER EVALUATION DATA t � I Li Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well (Datum Elev, ft MSL) Date Depth To LNAPL (ft) Depth To Water (ft) LNAPL Thick- ness (ft) Ground- water Elevation (ft MSL) Well (Datum Elev, ft MSL) Date Depth To LNAPL (ft) Depth To Water (ft) LNAPL Thick- ness (ft) Ground - water Elevation (ft MSL) AS01 (759.69) 7/1/2002 12/29/2003 1/14/2004 3/22/2004 3/4/2005 6/6/2005 3.42 3.45 8.25 3.42 3.45 3.39 3.24 3.12 0.00 0.00 751.44 756.27 756.24 756.30 756.45 756.57 2/17/2005 6/7/2005 11/28/2005 6/19/2006 8/1/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 12/4/2008 6/8/2010 12/8/2010 6/7/2011 12/6/2011 6/6/2012 6.28 5.09 7.31 6.39 7.69 6.19 6.82 8.70 6.62 7.53 4.75 5.50 6.06 6.34 6.42 777.84 779.03 776.81 777.73 776.43 777.93 777.30 775.42 777.50 776.59 779.37 778.62 778.06 777.78 777.70 AS02 (784.98) 7/2/2002 1/14/2004 15.45 12.87 769.53 772.11 DPEW01 (763.19) 9/17/1997 6/22/1998 12/16/1998 1/8/1999 3/25/1999 6/21/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/19/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/23/2005 6/7/2005 6.05 1.86 1.86 3.55 3.10 2.84 3.62 4.21 1.21 3.03 6.58 1.11 1.86 1.86 2.52 2.98 3.56 3.00 5.00 3.10 1.83 2.84 1.10 3.62 2.31 1.67 1.76 1.05 0.53 0.00 0.00 0.01 0.00 0.00 0.00 758.98 761.98 760.16 756.61 762.08 761.33 761.33 760.67 760.21 759.63 760.19 758.19 760.09 761.36 760.35 762.09 759.57 760.88 761.52 761.43 762.14 DW01A (782.5) 3/25/1999 1/14/2004 2/17/2005 6/7/2005 5.44 6.81 5.44 5.53 5.65 0.00 775.69 777.06 776.97 776.85 DWO2 (776.17) 3/25/1996 6/4/1996 10/24/1996 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/4/2005 6/6/2005 6/19/2006 8/1/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 12/4/2008 6/2/2009 12/8/2009 6/8/2010 4.15 3.94 3.50 4.40 5.12 4.81 4.57 5.10 5.03 5.30 4.60 6.24 4.55 4.28 3.51 5.21 7.40 5.27 4.71 4.61 4.45 5.66 9.13 4.76 5.65 6.13 4.73 5.31 4.18 6.29 7.59 772.02 772.23 772.67 771.77 771.05 771.36 771.60 771.07 771.14 770.87 771.57 769.93 771.62 771.89 772.66 770.96 768.77 770.90 771.46 771.56 771.72 770.51 767.04 771.41 770.52 770.04 771.44 770.86 771.99 769.88 768.58 DPEW02 (781.18) 9/16/1997 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/7/2001 6/18/2002 12/16/2002 6/4/2003 12/16/2003 1/14/2004 6/7/2004 12/6/2004 2/17/2005 6/7/2005 6.51 5.11 7.21 6.43 5.50 7.13 5.72 7.93 6.28 5.99 3.35 6.62 5.86 6.25 5.30 5.74 4.97 774.67 776.07 773.97 774.75 775.68 774.05 775.46 773.25 774.90 775.19 777.83 774.56 775.32 774.93 775.88 775.44 776.21 DW01 (784.12) 3/25/1996 6/4/1996 10/24/1996 1/14/2004 6.10 5.72 6.30 7.21 778.02 778.40 777.82 776.91 July, 23, 2012 Page 1 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES09 10/24/1996 10.82 777.22 (788.04) 9/16/1997 11.27 776.77 3/25/1999 10.78 777.26 6/5/2000 10.80 777.24 1/14/2004 10.65 777.39 2/18/2005 10.78 777.26 ES10 3/26/1996 7.65 783.71 (791.36) 6/4/1996 7.70 783.66 10/24/1996 9.10 9.10 0.00 782.26 6/22/1998 7.90 783.46 11/30/1998 10.80 780.56 3/25/1999 4.65 786.71 6/21/1999 9.88 781.48 12/13/1999 11.30 780.06 6/5/2000 9.85 781.51 12/5/2000 11.56 779.80 6/4/2001 10.42 780.94 12/5/2001 13.31 778.05 6/18/2002 11.10 780.26 12/16/2002 10.11 781.25 6/4/2003 6.45 784.91 12/15/2003 8.94 782.42 1/14/2004 9.17 782.19 6/7/2004 9.68 781.68 12/6/2004 9.40 781.96 3/7/2005 9.41 781.95 6/7/2005 8.41 782.95 ES11 3/26/1996 11.14 11.14 0.00 774.19 (785.33) 6/4/1996 11.15 11.15 0.00 774.18 10/24/1996 11.10 11.10 0.00 774.23 6/5/2000 9.97 775.36 1/14/2004 9.90 775.43 3/7/2005 9.95 775.38 3/22/2005 9.55 775.78 12/9/2009 9.62 775.71 ES12 3/26/1996 9.95 9.95 0.00 781.81 (791.76) 6/4/1996 9.55 782.21 10/24/1996 10.35 10.35 0.00 781.41 6/22/1998 10.10 781.66 11/30/1998 13.18 778.58 3/25/1999 11.30 780.46 6/21/1999 7.62 784.14 12/13/1999 13.35 778.41 6/5/2000 11.61 780.15 12/5/2000 14.00 777.76 6/4/2001 12.36 779.40 12/5/2001 15.54 776.22 6/18/2002 13.55 778.21 12/16/2002 12.47 779.29 6/4/2003 9.84 781.92 12/15/2003 11.35 780.41 1/14/2004 11.61 780.15 2/15/2004 11.78 779.98 6/7/2004 11.68 780.08 12/6/2004 11.77 779.99 6/7/2005 10.35 781.41 ES13 3/26/1996 10.90 780.93 (791.83) 6/4/1996 11.92 11.92 0.00 779.91 10/24/1996 11.40 780.43 2/27/1998 9.66 782.17 6/22/1998 11.24 780.59 11/30/1998 14.62 777.21 3/25/1999 12.35 779.48 6/21/1999 12.34 779.49 12/13/1999 14.51 777.32 6/5/2000 12.81 779.02 12/5/2000 15.42 776.41 6/4/2001 13.36 778.47 12/5/2001 17.21 774.62 6/18/2002 14.66 777.17 12/16/2002 12.81 779.02 6/4/2003 8.19 783.64 12/15/2003 11.82 780.01 1/14/2004 12.35 779.48 6/7/2004 12.77 779.06 12/6/2004 12.51 779.32 3/4/2005 11.58 780.25 6/7/2005 11.10 780.73 11/28/2005 14.14 777.69 6/19/2006 13.25 778.58 12/4/2006 11.66 780.17 6/11/2007 12.55 779.28 12/3/2007 16.23 775.60 6/2/2008 13.19 778.64 12/4/2008 14.52 777.31 6/4/2009 11.58 780.25 12/8/2009 11.81 780.02 6/7/2010 10.46 781.37 12/7/2010 14.96 776.87 6/6/2011 12.32 779.51 12/5/2011 14.31 777.52 6/6/2012 12.29 779.54 ES14 3/26/1996 10.35 10.35 0.00 780.35 (790.7) 6/4/1996 10.66 10.66 0.00 780.04 10/24/1996 11.22 779.48 9/16/1997 11.11 779.59 6/22/1998 10.50 780.20 11/30/1998 12.51 778.19 3/25/1999 11.60 779.10 6/21/1999 10.03 780.67 July, 23, 2012 Page 6 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES14 12/13/1999 12.75 777.95 (790.7) 6/5/2000 11.29 779.41 12/5/2000 13.28 777.42 6/4/2001 12.13 778.57 12/5/2001 14.58 776.12 6/18/2002 12.78 777.92 12/16/2002 12.39 778.31 6/4/2003 9.05 781.65 12/15/2003 10.71 779.99 1/14/2004 11.27 779.43 6/7/2004 11.21 779.49 12/6/2004 11.36 779.34 2/15/2005 11.77 778.93 6/7/2005 10.42 780.28 11/28/2005 12.29 778.41 6/19/2006 11.60 779.10 12/4/2006 11.25 779.45 6/11/2007 11.26 779.44 12/3/2007 13.49 777.21 6/2/2008 11.63 779.07 12/4/2008 12.59 778.11 6/2/2009 9.71 780.99 12/8/2009 10.25 780.45 6/7/2010 9.49 781.21 12/9/2010 12.02 778.68 6/6/2011 10.48 780.22 12/5/2011 11.51 779.19 6/6/2012 9.89 780.81 ES15 3/26/1996 7.08 783.17 (790.25) 6/4/1996 7.05 783.20 10/24/1996 7.25 783.00 9/16/1997 9.51 780.74 3/25/1999 9.02 781.23 12/29/2003 9.38 780.87 1/14/2004 9.72 780.53 3/22/2004 9.07 781.18 3/7/2005 9.13 781.12 ES16 3/26/1996 6.95 783.30 (790.25) 6/4/1996 9.60 780.65 10/24/1996 6.55 783.70 2/27/1998 9.85 780.40 1/14/2004 11.21 779.04 5/24/2005 10.50 779.75 ES17 3/26/1996 18.01 773.46 (791.47) 6/4/1996 18.35 773.12 10/24/1996 18.75 772.72 3/25/1999 18.16 773.31 6/5/2000 19.18 772.29 12/5/2000 22.13 769.34 1/14/2004 17.02 774.45 2/18/2005 3/7/2006 18.55 772.92 18.30 773.17 ES18 3/26/1996 10.90 775.41 (786.31) 6/5/1996 14.58 771.73 10/24/1996 10.93 775.38 2/25/1998 11.83 774.48 3/25/1999 14.43 771.88 1/14/2004 13.42 772.89 3/7/2005 13.80 772.51 3/22/2005 13.27 773.04 11/28/2005 16.21 770.10 6/19/2006 15.42 770.89 12/4/2006 13.60 772.71 6/11/2007 13.91 772.40 12/3/2007 17.58 768.73 6/2/2008 15.60 770.71 12/3/2008 16.34 769.97 6/3/2009 13.84 772.47 12/8/2009 13.59 772.72 6/8/2010 12.35 773.96 12/8/2010 16.28 770.03 6/6/2011 14.57 771.74 12/7/2011 16.27 770.04 6/6/2012 14.84 771.47 ES19 3/26/1996 (795.13) 6/6/1996 10/24/1996 2/27/1998 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/4/2005 6/7/2005 11/28/2005 6/19/2006 12/4/2006 6/11/2007 14.05 16.01 14.53 13.11 14.80 18.46 15.94 16.68 18.34 16.40 19.39 19.37 21.11 18.53 16.84 10.50 16.67 15.94 16.31 16.29 15.05 14.91 18.02 13.67 12.05 12.66 781.08 779.12 780.60 782.02 780.33 776.67 779.19 778.45 776.79 778.73 775.74 775.76 774.02 776.60 778.29 784.63 778.46 779.19 778.82 778.84 780.08 780.22 777.11 781.46 783.08 782.47 July, 23, 2012 Page 7 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES19 12/3/2007 16.37 778.76 (795.13) 6/2/2008 13.28 781.85 ES20 3/26/1996 7.98 779.38 (787.36) 6/3/1996 14.65 772.71 10/24/1996 14.42 772.94 3/25/1999 15.89 771.47 6/5/2000 16.35 771.01 12/5/2000 19.12 768.24 1/14/2004 14.56 772.80 3/7/2005 15.15 772.21 3/7/2006 15.85 771.51 ES21 3/26/1996 12.67 779.92 (792.59) 6/3/1996 14.60 777.99 10/24/1996 12.60 779.99 2/25/1998 9.71 782.88 3/25/1999 14.40 778.19 6/5/2000 15.06 777.53 12/5/2000 DRY DRY 1/14/2004 14.50 778.09 ES23 9/17/1997 5.02 759.36 (764.38) 6/22/1998 3.66 760.72 11/30/1998 4.66 759.72 1/8/1999 3.65 760.73 3/25/1999 3.76 760.62 6/21/1999 3.40 760.98 6/21/1999 3.40 760.98 12/13/1999 3.75 760.63 12/13/1999 3.75 760.63 6/5/2000 3.80 760.58 12/5/2000 4.05 760.33 6/4/2001 3.21 761.17 12/5/2001 6.45 757.93 6/18/2002 4.15 760.23 12/16/2002 3.25 761.13 6/4/2003 3.68 760.70 12/15/2003 2.40 761.98 1/14/2004 3.60 760.78 6/7/2004 3.72 760.66 12/6/2004 3.45 760.93 2/17/2005 1.88 762.50 6/6/2005 1.66 762.72 ES25 3/26/1996 4.12 750.57 (754.69) 6/5/1996 4.50 750.19 3/4/1998 4.53 750.16 6/22/1998 6.55 748.14 11/30/1998 9.01 745.68 3/25/1999 5.29 749.40 6/21/1999 6.13 748.56 12/13/1999 12.01 742.68 6/5/2000 8.99 745.70 12/5/2000 13.50 741.19 6/4/2001 5.45 749.24 12/5/2001 8.90 745.79 6/19/2002 8.95 8.95 0.00 745.74 12/16/2002 5.84 5.85 0.01 748.84 6/4/2003 5.15 749.54 12/15/2003 2.96 751.73 1/14/2004 3.73 750.96 6/7/2004 4.26 750.43 12/6/2004 5.25 749.44 2/18/2005 3.88 750.81 6/7/2005 3.21 751.48 11/28/2005 3.92 750.77 12/4/2006 5.97 748.72 6/11/2007 6.21 748.48 12/3/2007 SHEEN 9.25 SHEEN 745.44 6/2/2008 4.88 749.81 12/3/2008 4.39 750.30 6/2/2009 3.17 751.52 12/8/2009 4.95 749.74 6/8/2010 3.82 750.87 12/8/2010 7.49 747.20 6/6/2011 5.34 749.35 12/7/2011 6.45 748.24 6/6/2012 4.30 750.39 ES26 9/16/1997 (777.81) 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/8/2005 6/6/2005 11/28/2005 6/19/2006 8/1/2006 6/11/2007 12/3/2007 6/2/2008 10.26 9.73 10.35 10.00 9.67 10.22 9.92 10.33 9.67 10.85 9.93 9.46 9.16 7.97 10.18 10.08 9.84 9.61 9.43 10.08 9.53 9.59 10.18 10.64 9.73 767.55 768.08 767.46 767.81 768.14 767.59 767.89 767.48 768.14 766.96 767.88 768.35 768.65 769.84 767.63 767.73 767.97 768.20 768.38 767.73 768.28 768.22 767.63 767.17 768.08 July, 23, 2012 Page 8 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES26 12/4/2008 9.63 768.18 (777.81) 6/4/2009 9.44 768.37 12/8/2009 9.69 768.12 6/7/2010 9.17 768.64 12/7/2010 9.95 767.86 6/7/2011 9.68 768.13 12/6/2011 9.73 768.08 6/6/2012 9.61 768.20 ES28 3/25/1999 2.81 771.20 (774.01) 1/14/2004 3.23 770.78 3/8/2005 2.43 771.58 6/7/2005 2.11 771.90 ES29 6/22/1998 10.71 780.66 (791.37) 11/30/1998 14.13 777.24 3/25/1999 11.88 779.49 6/21/1999 12.18 779.19 12/13/1999 14.04 777.33 6/5/2000 12.34 779.03 12/5/2000 15.95 775.42 6/4/2001 12.82 778.55 12/5/2001 17.72 773.65 6/18/2002 14.14 777.23 12/16/2002 12.26 779.11 6/4/2003 7.66 783.71 12/15/2003 11.32 780.05 1/14/2004 11.86 779.51 6/7/2004 12.31 779.06 12/6/2004 12.00 779.37 3/4/2005 11.00 780.37 6/6/2005 10.65 780.72 11/28/2005 13.66 777.71 6/19/2006 12.72 778.65 12/4/2006 12.05 779.32 6/11/2007 12.04 779.33 12/3/2007 15.75 775.62 6/2/2008 12.73 778.64 12/4/2008 14.05 777.32 6/4/2009 11.08 780.29 12/8/2009 11.20 780.17 6/7/2010 10.25 781.12 12/7/2010 14.48 14.49 0.01 776.88 6/6/2011 11.83 779.54 12/5/2011 13.85 777.52 6/6/2012 11.84 779.53 ES30 6/22/1998 6.16 762.05 (768.21) 11/30/1998 7.49 760.72 3/25/1999 6.50 761.71 6/21/1999 5.98 762.23 12/13/1999 6.55 761.66 6/5/2000 7.55 760.66 12/5/2000 7.84 760.37 6/4/2001 5.82 762.39 12/5/2001 8.33 759.88 6/18/2002 7.27 760.94 12/16/2002 6.21 762.00 6/4/2003 7.43 760.78 12/15/2003 6.29 761.92 1/14/2004 6.68 761.53 6/7/2004 6.33 761.88 12/6/2004 6.25 761.96 2/18/2005 6.52 761.69 11/28/2005 7.60 760.61 6/6/2006 4.83 763.38 ES31 9/16/1997 12.52 766.70 (779.22) 9/17/1997 12.54 766.68 3/25/1999 11.91 767.31 1/14/2004 11.95 767.27 2/15/2005 11.30 767.92 6/7/2005 10.60 768.62 11/28/2005 12.90 766.32 6/19/2006 11.36 767.86 12/4/2006 10.71 768.51 6/11/2007 11.72 767.50 12/3/2007 12.65 766.57 6/2/2008 9.81 769.41 12/4/2008 10.68 768.54 6/2/2009 8.45 770.77 12/8/2009 9.19 770.03 6/7/2010 8.11 771.11 12/7/2010 11.64 767.58 6/6/2011 9.63 769.59 12/5/2011 10.13 769.09 6/6/2012 9.20 770.02 ES32 9/17/1997 5.69 757.25 (762.94) 1/8/1999 4.84 5.32 0.48 757.62 3/25/1999 4.58 4.93 0.35 758.01 12/13/1999 4.91 5.27 0.36 757.67 12/16/1999 4.91 5.27 0.36 757.67 6/5/2000 5.61 757.33 12/5/2000 5.92 6.14 0.22 756.80 6/4/2001 5.68 5.83 0.15 757.11 12/5/2001 7.40 7.73 0.33 755.21 3/23/2002 4.21 758.73 6/19/2002 6.36 6.39 0.03 756.55 12/16/2002 5.83 757.11 6/4/2003 4.85 4.85 0.00 758.09 12/15/2003 4.91 758.03 1/14/2004 5.52 5.52 0.00 757.42 6/7/2004 6.00 756.94 9/21/2004 5.42 757.52 July, 23, 2012 Page 9 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES32 12/6/2004 5.16 757.78 (762.94) 6/7/2005 4.91 758.03 11/28/2005 6.14 756.80 6/19/2006 5.60 757.34 12/4/2006 4.21 758.73 6/2/2009 1.27 761.67 12/8/2009 2.23 760.71 6/7/2010 8.08 754.86 12/8/2010 5.38 757.56 6/6/2011 3.70 759.24 12/5/2011 4.45 758.49 6/6/2012 3.78 759.16 ES33 9/17/1997 3.50 759.83 (763.33) 6/22/1998 1.35 761.98 11/30/1998 3.27 760.06 1/8/1999 2.41 760.92 3/25/1999 2.58 2.59 0.01 760.74 6/21/1999 2.62 760.71 6/21/1999 2.62 760.71 12/13/1999 2.85 760.48 12/13/1999 2.85 760.48 6/5/2000 2.70 760.63 12/5/2000 3.46 3.47 0.01 759.86 6/4/2001 2.65 760.68 12/5/2001 5.03 758.30 6/19/2002 3.27 3.27 0.00 760.06 12/16/2002 2.63 760.70 6/4/2003 2.39 760.94 12/15/2003 2.39 760.94 1/14/2004 2.61 760.72 6/7/2004 2.81 760.52 12/6/2004 2.49 760.84 2/15/2005 2.69 760.64 3/23/2005 2.43 760.90 6/7/2005 1.95 761.38 11/28/2005 3.54 759.79 6/19/2006 3.53 759.80 12/4/2006 2.06 761.27 6/11/2007 2.93 760.40 12/3/2007 3.47 759.86 6/2/2008 1.59 761.74 12/4/2008 1.71 761.62 6/2/2009 1.15 762.18 12/8/2009 2.59 760.74 6/7/2010 1.61 761.72 12/7/2010 3.45 759.88 6/6/2011 0.88 762.45 12/5/2011 1.02 762.31 6/6/2012 0.81 762.52 ES34 6/22/1998 1.92 775.26 11/30/1998 4.95 772.23 6/21/1999 2.62 774.56 12/16/1999 7.77 769.41 6/5/2000 2.41 774.77 12/5/2000 5.34 771.84 6/4/2001 3.34 773.84 12/5/2001 7.11 770.07 6/18/2002 3.76 773.42 12/16/2002 3.65 773.53 6/4/2003 1.41 775.77 12/15/2003 2.97 774.21 1/14/2004 3.58 773.60 6/7/2004 2.45 774.73 12/6/2004 2.81 774.37 6/7/2005 1.12 776.06 11/28/2005 4.94 772.24 6/19/2006 3.02 774.16 12/4/2006 2.06 775.12 6/2/2009 1.55 775.63 12/8/2009 2.55 774.63 6/7/2010 0.85 776.33 6/6/2011 1.12 776.06 12/5/2011 1.90 775.28 6/6/2012 0.96 776.22 ES35 6/22/1998 (774.74) 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 2/15/2005 3/23/2005 6/7/2005 11/28/2005 6/19/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 12/4/2008 1.35 6.72 4.40 4.93 5.87 4.55 7.26 5.05 8.50 5.59 4.25 1.32 1.59 4.58 4.57 4.23 3.65 3.69 3.38 6.21 3.71 3.40 4.19 5.80 3.18 4.09 773.39 768.02 770.34 769.81 768.87 770.19 767.48 769.69 766.24 769.15 770.49 773.42 773.15 770.16 770.17 770.51 771.09 771.05 771.36 768.53 771.03 771.34 770.55 768.94 771.56 770.65 July, 23, 2012 Page 10 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES35 6/2/2009 4.09 770.65 (774.74) 12/8/2009 2.72 772.02 6/7/2010 2.11 772.63 12/7/2010 4.59 770.15 6/6/2011 2.88 771.86 12/5/2011 3.43 771.31 6/6/2012 2.89 771.85 ES36 9/16/1997 9.10 773.73 (782.83) 3/25/1999 8.58 774.25 ES37 6/22/1998 4.87 773.01 (777.88) 11/30/1998 6.11 771.77 3/25/1999 5.22 772.66 6/21/1999 4.38 773.50 12/13/1999 6.01 771.87 6/5/2000 5.99 771.89 12/5/2000 5.73 772.15 6/4/2001 4.18 773.70 12/5/2001 7.20 770.68 6/18/2002 5.39 772.49 12/16/2002 4.23 773.65 6/4/2003 2.31 775.57 12/15/2003 2.25 775.63 1/14/2004 6.19 771.69 6/7/2004 6.39 771.49 12/6/2004 5.50 772.38 3/4/2005 4.84 773.04 6/6/2005 2.22 775.66 (777.18) 12/7/2010 2.89 774.29 ES38 6/22/1998 7.21 775.39 (782.6) 11/30/1998 8.04 774.56 3/25/1999 6.29 776.31 6/21/1999 6.70 775.90 12/13/1999 6.96 775.64 6/5/2000 7.14 775.46 12/5/2000 8.01 774.59 6/4/2001 6.25 776.35 12/5/2001 8.82 773.78 6/18/2002 7.55 775.05 12/16/2002 6.37 776.23 6/4/2003 5.75 776.85 12/15/2003 6.30 776.30 1/14/2004 8.18 774.42 6/7/2004 7.55 775.05 12/6/2004 7.07 775.53 3/4/2005 6.88 775.72 6/6/2005 6.47 776.13 11/28/2005 7.66 774.94 6/19/2006 5.74 776.86 12/4/2006 6.87 775.73 6/11/2007 8.17 774.43 12/3/2007 8.99 773.61 6/2/2008 6.75 775.85 12/4/2008 6.94 775.66 6/3/2009 6.91 775.69 12/9/2009 5.99 776.61 6/8/2010 6.16 776.44 12/8/2010 7.80 774.80 6/7/2011 6.81 775.79 12/6/2011 7.47 775.13 6/6/2012 6.18 776.42 ES39 2/27/1998 1.89 779.99 (781.88) 3/25/1999 6.13 775.75 1/14/2004 6.21 775.67 3/4/2005 4.79 777.09 6/7/2005 5.64 776.24 11/28/2005 DRY DRY ES40 3/25/1999 6.15 773.32 (779.47) 1/14/2004 6.55 772.92 2/15/2005 5.87 773.60 6/7/2005 5.97 773.50 11/28/2005 9.71 769.76 6/19/2006 7.06 772.41 12/4/2006 5.61 773.86 6/11/2007 7.33 772.14 12/3/2007 8.27 771.20 6/2/2008 5.04 774.43 12/4/2008 6.14 773.33 6/2/2009 4.59 774.88 12/8/2009 5.05 774.42 6/7/2010 4.37 775.10 12/7/2010 6.05 773.42 6/6/2011 4.71 774.76 12/5/2011 5.31 774.16 6/6/2012 4.45 775.02 ES41 3/25/1999 8.42 776.18 (784.6) 1/14/2004 8.66 775.94 2/15/2005 6.21 778.39 6/7/2005 8.23 776.37 12/3/2007 12.45 772.15 6/2/2008 8.88 775.72 12/4/2008 10.40 774.20 ES42 9/17/1997 (774.77) 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 11.17 9.96 12.06 10.04 10.53 11.72 10.40 12.05 10.80 763.60 764.81 762.71 764.73 764.24 763.05 764.37 762.72 763.97 July, 23, 2012 Page 11 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES42 12/5/2001 DRY DRY (774.77) 6/18/2002 11.24 763.53 12/16/2002 10.83 763.94 6/4/2003 9.54 765.23 12/15/2003 10.88 763.89 1/14/2004 10.68 764.09 6/7/2004 10.27 764.50 12/6/2004 10.55 764.22 2/15/2005 9.92 764.85 3/23/2005 9.06 765.71 6/7/2005 9.26 765.51 11/28/2005 DRY DRY ES43 3/25/1999 10.27 766.91 (777.18) 1/14/2004 10.29 766.89 2/15/2005 13.10 764.08 6/7/2005 10.71 766.47 ES44 2/27/1998 11.29 778.93 (790.22) 3/25/1999 13.26 776.96 1/14/2004 14.41 775.81 2/15/2005 13.10 777.12 6/7/2005 12.59 777.63 MP01 9/17/1997 3.16 759.94 (763.1) 1/8/1999 2.36 760.74 3/25/1999 2.33 760.77 6/5/2000 2.52 760.58 1/14/2004 2.25 760.85 2/17/2005 2.17 760.93 3/23/2005 1.77 761.33 MPO2 9/17/1997 4.52 758.67 (763.19) 1/8/1999 3.12 760.07 3/25/1999 2.86 760.33 6/5/2000 2.25 760.94 1/14/2004 1.81 761.38 5/25/2005 1.05 762.14 MPO3 9/17/1997 3.00 760.10 (763.1) 1/8/1999 4.05 4.06 0.01 759.04 6/5/2000 2.26 760.84 1/14/2004 2.52 2.52 0.00 760.58 5/23/2005 2.15 760.95 MPO4 9/16/1997 10.98 770.30 (781.28) 3/25/1999 5.30 775.98 MP05 9/16/1997 5.82 774.14 (779.96) 3/25/1999 5.35 774.61 1/14/2004 5.43 774.53 2/18/2005 5.31 774.65 5/24/2005 3.53 776.43 MPO6 7/1/2002 4.20 755.22 (759.42) 12/29/2003 3.06 3.06 0.00 756.36 1/14/2004 3.09 3.09 0.00 756.33 3/22/2004 4.00 755.42 3/4/2005 6/6/2005 3.16 756.26 2.74 756.68 MWO2 3/26/1996 10.32 771.05 (781.37) 6/4/1996 10.95 770.42 10/24/1996 10.56 10.56 0.00 770.81 6/22/1998 10.22 771.15 11/30/1998 12.27 769.10 3/25/1999 11.47 769.90 6/21/1999 11.62 769.75 12/13/1999 12.57 768.80 6/5/2000 11.48 769.89 12/5/2000 13.10 768.27 6/4/2001 12.30 769.07 12/5/2001 14.61 766.76 6/19/2002 13.19 768.18 12/16/2002 11.57 769.80 6/4/2003 8.23 773.14 12/15/2003 10.90 770.47 1/14/2004 11.42 769.95 6/7/2004 11.77 769.60 12/6/2004 11.07 770.30 3/8/2005 10.41 770.96 6/7/2005 9.07 772.30 11/28/2005 11.23 770.14 1/24/2006 9.95 771.42 (780.28) 2/23/2006 9.79 770.49 3/7/2006 10.70 769.58 6/19/2006 10.58 769.70 8/1/2006 10.13 770.15 8/15/2006 10.89 769.39 9/25/2006 9.19 771.09 11/2/2006 9.81 770.47 12/4/2006 9.24 771.04 6/11/2007 10.28 770.00 (781.37) 12/3/2007 12.74 768.63 6/2/2008 10.72 770.65 12/3/2008 10.96 770.41 6/2/2009 9.10 772.27 12/8/2009 9.05 772.32 6/8/2010 7.83 773.54 12/8/2010 11.59 769.78 6/7/2011 9.63 771.74 12/7/2011 10.45 770.92 6/6/2012 9.95 771.42 MWO3W 3/25/1996 (769.21) 3/4/1998 3/25/1999 12/16/2002 12/15/2003 1/14/2004 5.62 3.91 4.17 3.22 3.71 3.03 763.59 765.30 765.04 765.99 765.50 766.18 July, 23, 2012 Page 12 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW03W 6/7/2004 2.82 766.39 (769.21) 12/6/2004 1.55 767.66 3/8/2005 1.27 767.94 6/6/2005 1.68 767.53 11/28/2005 3.60 765.61 MW04R 3/4/1998 4.12 750.82 (754.94) 3/4/1998 4.12 750.82 3/25/1999 7.88 747.06 1/14/2004 3.52 751.42 3/4/2005 6.91 748.03 6/6/2005 2.71 752.23 8/29/2005 8.61 746.33 MW05 3/25/1996 6.93 6.93 0.00 779.72 (786.65) 6/6/1996 9.10 777.55 10/24/1996 7.00 7.00 0.00 779.65 3/25/1999 8.43 778.22 1/14/2004 8.48 778.17 3/7/2005 8.69 777.96 6/7/2005 7.55 779.10 11/28/2005 9.78 776.87 6/19/2006 8.97 777.68 12/4/2006 8.11 778.54 6/11/2007 8.85 777.80 12/3/2007 11.27 775.38 6/2/2008 9.50 777.15 12/4/2008 9.22 777.43 6/4/2009 7.98 778.67 12/9/2009 8.34 778.31 6/9/2010 7.05 779.60 12/8/2010 6.00 780.65 6/8/2011 8.58 778.07 12/7/2011 10.21 776.44 6/6/2012 8.86 777.79 MW06R 3/4/1998 3.00 752.29 (755.29) 3/4/1998 3.00 752.29 6/25/1998 4.87 750.42 11/30/1998 DRY DRY 3/25/1999 8.21 747.08 6/21/1999 7.51 747.78 12/13/1999 8.50 746.79 6/5/2000 8.63 746.66 12/5/2000 DRY DRY 6/4/2001 DRY DRY 12/5/2001 DRY DRY 6/19/2002 9.83 745.46 12/16/2002 8.43 746.86 6/4/2003 6.23 749.06 12/15/2003 5.31 749.98 1/14/2004 9.66 745.63 6/7/2004 6.84 748.45 12/6/2004 8.75 746.54 3/4/2005 7.91 747.38 6/6/2005 7.99 747.30 11/28/2005 DRY DRY MW07 3/25/1996 6.18 768.18 (774.36) 6/6/1996 4.40 769.96 10/24/1996 3.00 771.36 3/25/1999 4.45 769.91 12/13/1999 5.62 768.74 6/5/2000 0.50 773.86 12/5/2000 6.56 767.80 6/4/2001 3.96 770.40 12/5/2001 8.39 765.97 6/19/2002 6.27 768.09 12/16/2002 2.42 771.94 6/4/2003 0.81 773.55 12/15/2003 1.49 772.87 1/14/2004 4.62 769.74 6/7/2004 5.62 768.74 12/6/2004 4.07 770.29 2/18/2005 4.46 769.90 6/6/2005 2.42 771.94 11/28/2005 5.80 768.56 MW08 3/25/1996 (777.69) 6/6/1996 10/24/1996 3/25/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/19/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/8/2005 6/6/2005 11/28/2005 6/19/2006 9/25/2006 11/2/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 12/3/2008 10.52 9.95 3.20 8.45 9.32 0.50 10.31 8.64 11.78 10.30 7.77 1.12 3.92 8.47 9.02 8.00 5.12 6.86 9.73 8.68 7.44 8.08 7.69 8.80 11.14 8.93 6.94 767.17 767.74 774.49 769.24 768.37 777.19 767.38 769.05 765.91 767.39 769.92 776.57 773.77 769.22 768.67 769.69 772.57 770.83 767.96 769.01 770.25 769.61 770.00 768.89 766.55 768.76 770.75 July, 23, 2012 Page 13 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW08 6/2/2009 7.11 770.58 (777.69) 12/8/2009 6.96 770.73 6/8/2010 4.77 772.92 12/8/2010 3.80 773.89 6/7/2011 8.13 769.56 12/7/2011 8.94 768.75 6/6/2012 8.11 769.58 MW09 3/25/1996 11.23 773.42 (784.65) 6/6/1996 14.05 770.60 10/24/1996 11.73 772.92 2/25/1998 9.87 774.78 3/25/1999 12.58 772.07 1/14/2004 13.77 770.88 3/7/2005 12.64 772.01 5/26/2005 10.99 773.66 MW12 3/25/1996 7.63 778.53 (786.16) 6/6/1996 6.50 779.66 10/24/1996 5.05 5.05 0.00 781.11 3/25/1999 5.94 7.44 1.50 778.72 6/5/2000 4.62 4.62 0.00 781.54 12/29/2003 6.25 6.25 0.00 779.91 1/14/2004 7.16 7.16 0.00 779.00 3/22/2004 6.23 6.47 0.24 779.69 3/7/2005 5.82 6.02 0.20 780.14 5/24/2005 4.99 5.01 0.02 781.15 6/7/2005 4.89 781.27 11/28/2005 6.02 780.14 6/19/2006 6.52 779.64 12/4/2006 5.60 780.56 6/11/2007 6.27 779.89 12/3/2007 9.44 776.72 6/2/2008 6.82 779.34 12/3/2008 17.15 769.01 6/4/2009 5.46 780.70 12/9/2009 5.20 780.96 6/8/2010 2.94 783.22 12/7/2010 6.00 780.16 6/7/2011 5.78 780.38 12/5/2011 7.62 778.54 6/6/2012 5.91 780.25 MW14R 3/4/1998 2.99 753.42 (756.41) 3/4/1998 2.99 753.42 6/26/1998 4.02 752.39 11/30/1998 10.80 745.61 3/25/1999 7.17 749.24 6/21/1999 7.80 748.61 12/13/1999 8.80 747.61 6/5/2000 7.97 748.44 12/5/2000 10.22 746.19 6/4/2001 7.49 748.92 12/5/2001 12.27 744.14 6/19/2002 10.34 746.07 12/16/2002 5.86 750.55 6/4/2003 4.14 752.27 12/15/2003 6.25 750.16 1/14/2004 7.37 749.04 6/7/2004 8.02 748.39 12/6/2004 6.22 750.19 2/18/2005 5.89 750.52 6/6/2005 5.53 750.88 11/28/2005 8.45 747.96 12/4/2006 5.79 750.62 6/11/2007 7.66 748.75 12/3/2007 10.44 745.97 6/2/2008 7.10 749.31 12/3/2008 7.27 749.14 6/2/2009 5.48 750.93 12/8/2009 5.83 750.58 6/8/2010 5.84 750.57 12/8/2010 9.52 746.89 6/6/2011 7.11 749.30 12/7/2011 8.13 748.28 6/6/2012 6.80 749.61 MW16 3/25/1996 8.62 778.65 (787.27) 6/6/1996 8.10 779.17 10/24/1996 7.00 780.27 6/5/2000 1.67 785.60 1/14/2004 8.04 779.23 3/7/2005 7.43 779.84 6/7/2005 6.42 780.85 8/29/2005 8.62 778.65 MW18 6/6/1996 10.73 770.17 (780.9) 10/24/1996 4.70 776.20 MW19 3/25/1996 11.95 770.69 (782.64) 6/6/1996 15.10 767.54 10/24/1996 12.67 12.67 0.00 769.97 3/25/1999 11.90 770.74 1/14/2004 12.42 770.22 3/7/2005 11.68 770.96 3/23/2005 10.71 771.93 6/7/2005 9.38 773.26 11/28/2005 11.61 771.03 1/24/2006 10.49 772.15 2/23/2006 10.36 772.28 3/7/2006 11.00 771.64 6/19/2006 11.46 771.18 8/1/2006 11.04 771.60 8/15/2006 11.83 770.81 9/25/2006 9.94 772.70 11/2/2006 10.60 772.04 July, 23, 2012 Page 14 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW19 12/4/2006 10.40 772.24 (781.6) 6/11/2007 10.50 771.10 (782.64) 12/3/2007 13.70 768.94 6/2/2008 11.18 771.46 12/3/2008 12.25 770.39 6/3/2009 10.40 772.24 12/8/2009 10.15 772.49 6/8/2010 8.43 774.21 12/8/2010 11.94 770.70 6/7/2011 10.12 772.52 12/7/2011 10.95 771.69 6/6/2012 10.99 771.65 MW20 3/25/1996 7.66 779.68 (787.34) 6/6/1996 7.71 779.63 10/24/1996 6.75 780.59 3/25/1999 7.73 779.61 12/29/2003 5.87 781.47 1/14/2004 8.15 779.19 3/22/2004 7.44 779.90 3/7/2005 5.01 782.33 6/7/2005 4.06 783.28 MW21 3/7/2005 6.42 779.34 (785.76) 6/7/2005 5.66 780.10 11/28/2005 8.22 777.54 6/19/2006 7.24 778.52 12/4/2006 9.00 776.76 6/11/2007 6.62 779.14 12/3/2007 9.62 776.14 6/2/2008 7.46 778.30 12/3/2008 8.48 777.28 6/4/2009 5.98 779.78 12/9/2009 6.34 779.42 6/9/2010 5.33 780.43 12/8/2010 8.59 777.17 6/8/2011 6.24 779.52 12/7/2011 8.31 777.45 6/6/2012 6.79 778.97 MW26 3/25/1996 4.50 780.88 (785.38) 6/6/1996 6.31 779.07 10/24/1996 4.53 780.85 2/25/1998 4.33 781.05 3/25/1999 6.64 778.74 1/14/2004 7.64 777.74 3/7/2005 6.42 778.96 6/7/2005 5.52 779.86 11/28/2005 7.62 777.76 6/19/2006 7.12 778.26 12/4/2006 5.82 779.56 6/11/2007 6.51 778.87 12/3/2007 9.46 775.92 6/2/2008 7.48 777.90 12/3/2008 8.57 776.81 6/4/2009 5.96 779.42 12/9/2009 6.26 779.12 6/9/2010 5.20 780.18 12/8/2010 8.39 776.99 6/8/2011 6.26 779.12 12/7/2011 8.17 777.21 6/6/2012 6.71 778.67 MW27 3/25/1996 5.45 5.45 0.00 781.48 (786.93) 6/6/1996 5.90 5.90 0.00 781.03 10/24/1996 5.90 5.95 0.05 780.98 3/25/1999 6.70 6.78 0.08 780.15 6/5/2000 6.25 6.25 0.00 780.68 1/14/2004 6.95 7.05 0.10 779.88 3/7/2005 6.83 780.10 6/7/2005 5.11 5.62 0.51 781.31 MW36 3/25/1999 14.83 771.11 (785.94) 1/14/2004 15.61 770.33 3/7/2005 14.13 771.81 3/22/2005 13.68 772.26 6/7/2005 12.78 773.16 11/28/2005 14.99 770.95 1/24/2006 14.80 771.14 2/23/2006 13.86 772.08 3/7/2006 14.60 771.34 6/19/2006 14.81 771.13 8/15/2006 15.14 770.80 8/31/2006 13.76 772.18 9/25/2006 13.22 772.72 11/2/2006 13.90 772.04 12/4/2006 13.51 772.43 6/11/2007 13.91 772.03 12/3/2007 17.09 768.85 6/2/2008 14.69 771.25 12/4/2008 15.80 770.14 6/3/2009 13.41 772.53 12/8/2009 13.60 772.34 6/8/2010 11.95 773.99 12/8/2010 15.52 770.42 6/7/2011 13.65 772.29 12/7/2011 14.53 771.41 6/6/2012 14.39 771.55 MW37 3/25/1996 14.10 771.07 (785.17) 6/6/1996 14.95 770.22 10/24/1996 14.15 14.15 0.00 771.02 2/25/1998 11.72 773.45 3/25/1999 12.81 772.36 1/14/2004 13.27 771.90 3/7/2005 12.88 772.29 July, 23, 2012 Page 15 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW37 3/22/2005 12.52 772.65 (785.17) 6/7/2005 12.09 773.08 12/9/2009 12.37 772.80 MW38 3/25/1996 14.50 771.04 (785.54) 6/6/1996 16.01 769.53 10/24/1996 14.70 14.70 0.00 770.84 2/25/1998 12.38 773.16 3/25/1999 13.91 771.63 7/2/2002 16.05 769.49 4/8/2003 12.83 772.71 6/4/2003 11.25 774.29 12/15/2003 13.34 772.20 1/14/2004 13.65 771.89 3/7/2005 13.51 772.03 3/23/2005 12.86 772.68 11/28/2005 14.32 771.22 1/24/2006 14.50 771.04 2/23/2006 13.28 772.26 3/7/2006 13.77 771.77 6/19/2006 14.01 771.53 8/15/2006 14.53 771.01 8/31/2006 13.06 772.48 9/25/2006 12.55 772.99 11/2/2006 13.08 772.46 12/4/2006 12.71 772.83 6/11/2007 13.13 772.41 12/3/2007 15.97 769.57 6/2/2008 14.13 771.41 12/4/2008 14.68 770.86 6/3/2009 12.63 772.91 12/8/2009 12.68 772.86 6/8/2010 11.41 774.13 12/8/2010 15.16 770.38 6/7/2011 13.10 772.44 12/7/2011 14.08 771.46 6/6/2012 13.48 772.06 MW39 3/25/1996 12.10 773.18 (785.28) 6/6/1996 12.28 773.00 10/24/1996 14.24 14.24 0.00 771.04 6/22/1998 11.99 773.29 11/30/1998 14.01 771.27 3/25/1999 13.51 771.77 6/21/1999 13.70 771.58 12/13/1999 14.59 770.69 6/5/2000 13.41 771.87 12/5/2000 15.00 770.28 6/4/2001 14.55 770.73 12/5/2001 16.59 16.59 0.00 768.69 6/19/2002 15.32 769.96 7/2/2002 15.49 769.79 12/16/2002 14.07 771.21 4/8/2003 12.41 772.87 6/4/2003 11.88 773.40 12/15/2003 13.06 772.22 1/14/2004 13.28 772.00 6/7/2004 13.26 772.02 12/6/2004 12.89 772.39 3/7/2005 12.77 772.51 6/7/2005 12.05 773.23 11/28/2005 14.13 771.15 1/24/2006 13.44 771.84 2/23/2006 13.03 772.25 3/7/2006 13.59 771.69 6/19/2006 13.89 771.39 8/15/2006 14.28 771.00 8/31/2006 13.05 772.23 9/25/2006 12.44 772.84 11/2/2006 12.90 772.38 12/4/2006 12.57 772.71 6/11/2007 12.90 772.38 12/3/2007 15.76 769.52 6/2/2008 14.00 771.28 12/4/2008 14.52 770.76 6/3/2009 12.31 772.97 12/9/2009 12.59 772.69 6/8/2010 11.34 773.94 12/8/2010 14.75 770.53 6/7/2011 13.18 772.10 12/7/2011 13.92 771.36 6/6/2012 13.35 771.93 MW41 3/25/1996 11.62 11.62 0.00 774.02 (785.64) 6/6/1996 13.88 13.88 0.00 771.76 10/24/1996 14.65 14.65 0.00 770.99 2/25/1998 12.39 773.25 6/22/1998 12.51 773.13 11/30/1998 14.63 771.01 3/25/1999 14.01 771.63 6/21/1999 14.28 771.36 12/13/1999 15.20 770.44 6/5/2000 13.94 771.70 12/5/2000 15.67 769.97 6/4/2001 15.11 770.53 12/5/2001 17.21 17.21 0.00 768.43 6/19/2002 15.90 769.74 7/2/2002 16.10 769.54 12/16/2002 14.65 770.99 4/8/2003 12.92 772.72 6/4/2003 11.31 774.33 12/15/2003 12.59 773.05 1/14/2004 13.35 772.29 July, 23, 2012 Page 16 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW41 6/7/2004 13.72 771.92 (785.64) 12/6/2004 13.33 772.31 3/23/2005 12.72 772.92 6/7/2005 12.44 773.20 11/28/2005 14.62 771.02 1/24/2006 13.73 771.91 2/23/2006 13.43 772.21 3/7/2006 13.95 771.69 6/19/2006 14.33 771.31 8/15/2006 14.87 770.77 8/31/2006 13.28 772.36 9/25/2006 12.87 772.77 11/2/2006 13.31 772.33 12/4/2006 12.90 772.74 6/11/2007 13.25 772.39 12/3/2007 15.95 769.69 6/2/2008 14.54 771.10 12/4/2008 14.69 770.95 6/3/2009 12.84 772.80 12/8/2009 12.88 772.76 6/8/2010 11.63 774.01 12/8/2010 15.01 770.63 6/7/2011 13.52 772.12 12/7/2011 14.17 771.47 6/6/2012 13.69 771.95 MW42 3/25/1996 14.21 771.74 (785.95) 6/6/1996 14.95 771.00 10/24/1996 14.19 771.76 3/25/1999 13.45 772.50 6/5/2000 13.26 772.69 1/14/2004 12.82 773.13 3/7/2005 12.83 773.12 3/22/2005 12.59 773.36 12/9/2009 12.44 773.51 MW43 3/25/1996 6.21 782.15 (788.36) 6/6/1996 11.99 776.37 10/24/1996 6.34 782.02 3/25/1999 9.91 778.45 1/14/2004 9.76 778.60 3/7/2005 8.29 780.07 6/7/2005 7.16 781.20 MW44 3/25/1996 14.32 14.32 0.00 771.45 (785.77) 6/6/1996 15.94 15.94 0.00 769.83 10/24/1996 14.44 771.33 2/25/1998 11.81 773.96 3/25/1999 13.60 772.17 6/5/2000 13.55 772.22 7/2/2002 15.59 770.18 4/8/2003 12.41 773.36 6/4/2003 10.77 775.00 12/15/2003 12.85 772.92 1/14/2004 13.22 772.55 3/7/2005 13.09 772.68 3/22/2005 12.68 773.09 11/28/2005 14.43 771.34 6/19/2006 13.78 771.99 12/4/2006 12.49 773.28 (786.77) 6/11/2007 13.28 773.49 (785.77) 12/3/2007 15.98 769.79 6/2/2008 14.23 771.54 12/4/2008 14.66 771.11 6/4/2009 12.43 773.34 12/8/2009 12.51 773.26 6/8/2010 11.44 774.33 12/8/2010 15.05 770.72 6/7/2011 13.19 772.58 12/7/2011 14.18 771.59 6/6/2012 13.27 772.50 MW45 3/27/1996 15.98 770.93 (786.91) 6/6/1996 16.85 770.06 10/24/1996 16.00 770.91 2/25/1998 13.60 773.31 3/25/1999 15.32 771.59 1/14/2004 15.19 771.72 3/7/2005 14.76 772.15 3/22/2005 14.34 772.57 9/25/2006 13.10 773.81 11/2/2006 13.67 773.24 12/9/2009 13.16 773.75 MW47 3/24/1996 7.63 780.42 (788.05) 6/6/1996 7.50 7.50 0.00 780.55 10/24/1996 7.72 780.33 3/25/1999 9.68 778.37 1/14/2004 10.18 777.87 3/7/2005 9.52 778.53 6/7/2005 8.21 779.84 MW48 3/24/1996 5.13 783.06 (788.19) 6/6/1996 4.90 783.29 10/24/1996 5.00 783.19 3/25/1999 5.88 782.31 1/14/2004 7.84 7.84 0.00 780.35 3/24/2005 5.12 783.07 6/7/2005 5.02 783.17 MW49 3/24/1996 (784.17) 6/6/1996 10/24/1996 3/25/1999 7/2/2002 4/8/2003 6/4/2003 13.29 12.60 13.33 12.39 15.16 12.73 10.61 770.88 771.57 770.84 771.78 769.01 771.44 773.56 July, 23, 2012 Page 17 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW49 12/15/2003 12.61 771.56 (784.17) 1/14/2004 13.02 771.15 3/7/2005 12.34 771.83 3/23/2005 11.53 772.64 6/7/2005 11.06 773.11 11/28/2005 13.37 770.80 6/19/2006 12.74 771.43 8/1/2006 12.43 771.74 8/31/2006 11.80 772.37 9/25/2006 11.30 772.87 11/2/2006 11.80 772.37 12/4/2006 11.44 772.73 6/11/2007 11.22 772.95 12/3/2007 14.83 769.34 6/2/2008 13.30 770.87 12/4/2008 13.48 770.69 6/3/2009 11.28 772.89 12/8/2009 11.48 772.69 6/8/2010 10.30 773.87 12/8/2010 14.01 770.16 6/7/2011 12.03 772.14 12/7/2011 12.88 771.29 6/6/2012 12.09 772.08 MW50 3/24/1996 9.10 774.40 (783.5) 6/6/1996 12.75 770.75 10/24/1996 8.85 774.65 3/25/1999 11.97 771.53 1/14/2004 11.60 771.90 3/7/2005 11.36 772.14 3/22/2005 10.79 772.71 11/28/2005 12.78 770.72 6/19/2006 12.07 771.43 12/4/2006 10.76 772.74 6/11/2007 12.69 770.81 12/3/2007 14.37 769.13 6/2/2008 11.25 772.25 12/4/2008 12.84 770.66 6/3/2009 10.49 773.01 12/9/2009 sheen 10.52 sheen 772.98 6/8/2010 9.47 774.03 12/8/2010 13.27 770.23 6/7/2011 11.43 772.07 12/7/2011 12.26 771.24 6/6/2012 11.37 772.13 MW51 3/24/1996 10.90 775.51 (786.41) 6/6/1996 10.40 10.40 0.00 776.01 10/24/1996 10.55 775.86 6/25/1998 9.09 777.32 11/30/1998 11.57 774.84 3/25/1999 10.93 775.48 6/21/1999 10.49 775.92 12/15/1999 11.95 11.96 0.01 774.45 6/5/2000 10.90 775.51 12/5/2000 12.07 774.34 6/4/2001 11.01 775.40 12/5/2001 13.90 13.90 0.00 772.51 6/19/2002 11.73 774.68 12/16/2002 10.87 775.54 6/4/2003 7.74 778.67 12/15/2003 10.19 776.22 1/14/2004 10.86 775.55 6/7/2004 11.08 775.33 12/6/2004 10.40 776.01 3/8/2005 10.34 776.07 6/7/2005 9.54 776.87 11/28/2005 11.78 774.63 6/19/2006 11.23 775.18 12/4/2006 10.22 776.19 6/11/2007 11.19 775.22 12/3/2007 13.22 773.19 6/2/2008 12.40 774.01 12/4/2008 11.94 774.47 6/3/2009 9.92 776.49 12/9/2009 10.12 776.29 6/8/2010 9.24 777.17 12/8/2010 12.63 773.78 6/7/2011 10.82 775.59 12/7/2011 11.64 774.77 6/6/2012 10.82 775.59 MW52 2/23/2006 12.04 744.01 MW53 3/8/2006 8.00 746.42 MW55 2/23/2006 11.86 770.50 (782.36) 3/8/2006 18.40 763.96 MW56 2/23/2006 8.43 754.41 (762.84) 3/8/2006 8.80 754.04 MW57 2/23/2006 28.45 741.09 (769.54) 3/8/2006 8.65 760.89 6/19/2006 7.63 761.91 MW58 2/23/2006 (777.14) 3/8/2006 6/11/2007 12/3/2007 12/4/2008 6/2/2009 12/8/2009 6/7/2010 12/7/2010 6/6/2011 12/5/2011 6/6/2012 12.19 12.45 12.87 14.53 12.40 10.19 10.85 9.86 12.97 9.32 9.83 8.42 764.95 764.69 764.27 762.61 764.74 766.95 766.29 767.28 764.17 767.82 767.31 768.72 July, 23, 2012 Page 18 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW59 2/23/2006 5.83 775.81 (781.64) 3/8/2006 5.80 775.84 6/11/2007 6.76 774.88 12/3/2007 8.05 773.59 6/2/2008 3.69 777.95 12/4/2008 4.90 776.74 6/2/2009 2.22 779.42 12/8/2009 2.68 778.96 6/7/2010 1.69 779.95 12/7/2010 6.39 775.25 6/6/2011 3.42 778.22 12/5/2011 5.65 775.99 6/6/2012 3.90 777.74 MW65 8/30/2010 6.98 778.74 (785.72) 12/8/2010 8.76 776.96 6/8/2011 6.56 779.16 12/5/2011 8.52 777.20 6/6/2012 7.12 778.60 MW66 8/30/2010 4.55 776.49 (781.04) 12/7/2010 5.17 775.87 6/7/2011 4.37 776.67 12/6/2011 4.39 776.65 6/6/2012 3.66 777.38 MW67 8/30/2010 4.10 776.34 (780.44) 12/7/2010 4.73 775.71 6/7/2011 3.78 776.66 12/6/2011 3.85 776.59 6/6/2012 3.33 777.11 MW68 8/30/2010 6.77 775.70 (782.47) 12/8/2010 6.65 775.82 6/8/2011 7.08 775.39 12/6/2011 6.97 775.50 6/6/2012 3.92 778.55 MW69 6/8/2011 6.10 771.63 (774.72) 12/6/2011 5.85 768.87 6/6/2012 5.90 768.82 PMW01 3/24/1996 3.33 757.73 (761.06) 6/6/1996 2.59 758.47 10/24/1996 3.10 757.96 1/8/1999 5.93 755.13 3/25/1999 6.08 754.98 12/13/1999 6.09 754.97 12/16/1999 6.09 754.97 6/5/2000 6.97 754.09 12/5/2000 7.35 753.71 6/4/2001 6.78 754.28 12/5/2001 8.87 752.19 6/18/2002 7.40 753.66 12/16/2002 4.80 756.26 6/3/2003 4.84 756.22 12/15/2003 6.44 754.62 1/14/2004 5.78 755.28 6/7/2004 7.41 753.65 9/21/2004 6.07 754.99 12/6/2004 6.15 754.91 3/4/2005 5.52 755.54 6/6/2005 5.81 755.25 11/28/2005 5.58 755.48 PMW02 3/24/1996 3.21 757.55 (760.76) 6/6/1996 6.35 754.41 10/24/1996 3.20 757.56 1/8/1999 7.04 753.72 3/25/1999 5.75 755.01 12/13/1999 6.59 754.17 12/16/1999 6.59 754.17 6/5/2000 7.11 753.65 12/5/2000 7.71 753.05 6/4/2001 6.95 753.81 12/5/2001 8.93 751.83 6/18/2002 8.09 752.67 7/1/2002 8.29 752.47 12/16/2002 6.05 754.71 6/3/2003 5.35 755.41 12/15/2003 6.32 754.44 12/29/2003 6.38 754.38 1/14/2004 6.41 754.35 3/22/2004 5.91 754.85 6/7/2004 6.87 753.89 9/21/2004 7.16 753.60 12/6/2004 6.50 754.26 3/4/2005 5.72 755.04 6/7/2005 6.23 754.53 11/28/2005 3.32 757.44 6/19/2006 7.01 753.75 12/4/2006 6.01 754.75 6/11/2007 7.62 753.14 12/3/2007 8.40 752.36 6/26/2008 6.99 753.77 12/3/2008 6.53 754.23 6/3/2009 6.75 754.01 12/9/2009 6.03 754.73 6/9/2010 6.15 754.61 12/9/2010 7.49 753.27 6/8/2011 6.78 753.98 12/7/2011 6.79 753.97 6/7/2012 6.49 754.27 PMW03 3/24/1996 (758.52) 6/6/1996 10/24/1996 6/22/1998 4.15 6.13 3.00 3.08 754.37 752.39 755.52 755.44 July, 23, 2012 Page 19 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) PMWO3 11/30/1998 3.76 754.76 (758.52) 1/8/1999 2.83 755.69 3/25/1999 2.93 755.59 6/21/1999 3.02 755.50 6/21/1999 3.02 755.50 12/13/1999 3.02 755.50 12/13/1999 3.02 755.50 6/5/2000 2.71 755.81 12/5/2000 3.74 754.78 6/4/2001 3.47 755.05 12/5/2001 4.40 754.12 6/18/2002 3.56 754.96 7/1/2002 3.43 755.09 12/16/2002 1.93 756.59 6/3/2003 2.57 755.95 12/15/2003 1.98 756.54 12/29/2003 2.19 2.19 0.00 756.33 1/14/2004 2.23 2.23 0.00 756.29 3/22/2004 2.91 755.61 6/7/2004 2.97 755.55 9/21/2004 2.26 756.26 12/6/2004 4.10 754.42 3/4/2005 1.45 757.07 6/7/2005 1.82 756.70 PMW04 3/24/1996 4.13 746.14 (750.27) 6/6/1996 5.30 744.97 10/24/1996 4.65 745.62 3/11/1999 13.30 736.97 3/25/1999 13.10 737.17 12/13/1999 14.65 735.62 6/5/2000 13.53 736.74 12/5/2000 15.10 735.17 6/4/2001 14.12 736.15 12/5/2001 16.95 733.32 6/18/2002 14.98 735.29 12/16/2002 13.94 736.33 6/3/2003 9.61 740.66 12/15/2003 8.93 741.34 1/14/2004 13.72 736.55 6/7/2004 13.61 736.66 12/6/2004 13.19 737.08 3/4/2005 11.02 739.25 6/9/2005 12.44 737.83 11/28/2005 15.11 735.16 PMW05 3/24/1996 4.20 739.21 (743.41) 6/6/1996 5.44 737.97 10/24/1996 4.55 738.86 3/11/1999 6.69 736.72 3/25/1999 7.51 735.90 1/14/2004 5.54 737.87 3/4/2005 4.33 739.08 PMW06 3/24/1996 3.78 750.49 (754.27) 6/6/1996 3.70 750.57 10/24/1996 3.90 750.37 3/25/1999 3.80 750.47 7/1/2002 4.60 749.67 12/29/2003 4.12 4.12 0.00 750.15 1/14/2004 4.08 750.19 3/22/2004 4.14 750.13 3/4/2005 4.26 750.01 (753.66) 11/28/2005 4.42 749.24 3/8/2006 4.60 749.06 PMW07 3/24/1996 3.40 750.26 (753.66) 6/6/1996 4.30 749.36 10/24/1996 3.44 750.22 3/25/1999 4.31 749.35 6/5/2000 5.13 748.53 12/5/2000 5.01 748.65 1/14/2004 4.74 748.92 3/4/2005 3.51 750.15 3/8/2006 3.60 750.06 PMW08 3/24/1996 3.41 757.57 (760.98) 6/6/1996 4.47 756.51 10/24/1996 3.30 757.68 6/22/1998 5.75 755.23 11/30/1998 6.10 754.88 1/8/1999 3.76 757.22 3/25/1999 4.34 756.64 6/21/1999 5.16 755.82 6/21/1999 5.16 755.82 12/13/1999 4.44 756.54 12/13/1999 4.44 756.54 6/5/2000 5.66 755.32 12/5/2000 6.08 754.90 6/4/2001 5.01 755.97 12/5/2001 7.81 753.17 6/18/2002 6.56 754.42 12/16/2002 4.41 756.57 6/3/2003 4.97 756.01 12/15/2003 3.48 757.50 12/29/2003 3.50 757.48 1/14/2004 3.52 757.46 3/22/2004 3.68 757.30 6/7/2004 6.28 754.70 9/21/2004 4.93 756.05 12/6/2004 4.16 756.82 3/4/2005 3.56 757.42 6/6/2005 4.28 756.70 PMW09 3/24/1996 (750.93) 6/6/1996 3.59 747.34 3.10 747.83 July, 23, 2012 Page 20 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) PMW09 10/24/1996 3.41 747.52 (750.93) 6/22/1998 4.21 746.72 11/30/1998 3.61 747.32 3/25/1999 3.45 747.48 6/21/1999 3.57 747.36 6/21/1999 3.57 747.36 12/13/1999 3.61 747.32 12/13/1999 3.61 747.32 6/5/2000 3.92 747.01 12/5/2000 4.30 746.63 6/4/2001 3.55 747.38 12/5/2001 4.05 746.88 6/18/2002 5.28 745.65 12/16/2002 3.48 747.45 6/3/2003 3.54 747.39 12/15/2003 3.39 747.54 1/14/2004 3.46 747.47 6/7/2004 5.63 745.30 9/21/2004 4.08 746.85 12/6/2004 3.73 747.20 3/4/2005 3.82 747.11 6/6/2005 4.05 746.88 11/28/2005 3.54 747.39 6/19/2006 4.56 746.37 12/4/2006 3.88 747.05 6/11/2007 4.69 746.24 12/3/2007 4.79 746.14 6/26/2008 4.83 746.10 12/3/2008 3.90 747.03 6/3/2009 4.25 746.68 12/10/2009 3.51 747.42 6/9/2010 4.18 746.75 12/9/2010 3.96 746.97 6/8/2011 4.68 746.25 12/7/2011 4.00 746.93 6/7/2012 4.57 746.36 PMW10 6/22/1998 5.11 741.75 (746.86) 11/30/1998 4.35 742.51 3/25/1999 4.71 742.15 6/21/1999 4.11 742.75 12/13/1999 3.89 742.97 6/5/2000 4.51 742.35 12/5/2000 4.65 742.21 6/4/2001 4.02 742.84 12/5/2001 5.01 741.85 6/18/2002 5.95 740.91 12/16/2002 4.70 742.16 6/3/2003 5.28 741.58 12/15/2003 3.57 743.29 12/29/2003 4.04 742.82 1/14/2004 4.06 742.80 3/22/2004 3.61 743.25 6/7/2004 5.23 741.63 12/6/2004 5.64 741.22 3/4/2005 3.98 742.88 6/6/2005 4.20 742.66 11/28/2005 3.86 743.00 6/19/2006 13.91 732.95 PMW11 6/23/1998 13.53 732.89 (746.42) 11/30/1998 16.01 730.41 3/11/1999 13.20 733.22 3/25/1999 12.91 733.51 1/14/2004 12.87 733.55 3/4/2005 14.45 731.97 11/28/2005 15.59 730.83 PMW12 3/11/1999 7.46 725.02 (732.48) 3/25/1999 7.26 725.22 6/21/1999 8.68 723.80 12/13/1999 9.15 723.33 6/5/2000 8.71 723.77 12/5/2000 9.33 723.15 6/4/2001 8.66 723.82 12/5/2001 DRY DRY 6/18/2002 10.58 721.90 12/16/2002 7.15 725.33 6/3/2003 5.63 726.85 12/15/2003 5.02 727.46 1/14/2004 8.40 724.08 6/7/2004 9.17 723.31 12/6/2004 7.53 724.95 6/9/2005 7.79 724.69 11/28/2005 9.05 723.43 RW02 1/14/2004 12.32 772.39 (784.71) 3/23/2005 11.65 773.06 RW03 3/24/1996 7.62 780.58 (788.2) 6/6/1996 6.59 781.61 10/24/1996 5.90 782.30 3/25/1999 8.11 780.09 1/14/2004 8.13 780.07 3/7/2005 7.89 780.31 T01 (Tr) 3/25/1999 9.98 775.17 (785.15) 1/14/2004 9.82 775.33 3/23/2005 8.55 776.60 T01A 3/24/1996 11.42 11.42 0.00 753.89 (765.31) 6/6/1996 11.40 11.40 0.00 753.91 10/24/1996 11.34 11.34 0.00 753.97 3/25/1999 3.87 761.44 6/5/2000 2.88 762.43 12/29/2003 3.24 3.24 0.00 762.07 1/14/2004 4.15 761.16 July, 23, 2012 Page 21 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) T01A 3/22/2004 2.97 762.34 (765.31) 3/23/2005 2.92 762.39 6/7/2005 2.93 762.38 8/29/2005 1.19 764.12 T02 (Tr) 3/25/1999 7.91 775.17 (783.08) 1/14/2004 7.21 775.87 3/23/2005 6.51 776.57 T02A 3/24/1996 8.65 8.65 0.00 753.12 (761.77) 6/6/1996 8.23 8.33 0.10 753.44 10/24/1996 8.55 8.55 0.00 753.22 3/25/1999 4.38 757.39 6/5/2000 4.27 757.50 7/1/2002 4.46 757.31 12/29/2003 5.38 756.39 1/14/2004 5.39 756.38 3/22/2004 6.44 755.33 3/23/2005 2.22 759.55 6/7/2005 5.33 756.44 11/28/2005 5.29 756.48 6/19/2006 5.35 756.42 12/4/2006 3.88 757.89 6/11/2007 5.71 756.06 12/3/2007 8.98 752.79 6/2/2008 4.57 757.20 12/3/2008 5.79 755.98 6/2/2009 4.72 757.05 12/9/2009 4.98 756.79 6/8/2010 4.68 757.09 12/8/2010 5.21 756.56 6/7/2011 4.93 756.84 12/6/2011 5.15 756.62 6/7/2012 4.96 756.81 UW01 3/27/1996 6.25 774.74 (780.99) 6/6/1996 6.63 774.36 10/24/1996 6.15 774.84 9/16/1997 6.79 774.20 3/25/1999 6.26 774.73 1/14/2004 7.02 773.97 UW02 3/27/1996 5.55 5.85 0.30 779.59 (785.44) 6/3/1996 4.80 6.05 1.25 779.39 10/24/1996 5.70 5.70 0.00 779.74 1/14/2004 8.26 777.18 3/8/2005 6.24 779.20 6/7/2005 5.41 780.03 UW03 3/27/1996 5.25 780.25 (785.5) 6/3/1996 4.55 780.95 10/24/1996 5.10 5.10 0.00 780.40 3/25/1999 6.55 778.95 1/14/2004 6.56 6.56 0.00 778.94 3/8/2005 5.80 779.70 UW04 3/27/1996 6.76 780.83 (787.59) 6/5/1996 7.59 780.00 10/24/1996 6.85 780.74 9/16/1997 8.22 779.37 3/25/1999 7.37 780.22 1/14/2004 7.81 779.78 3/8/2005 4.35 783.24 6/7/2005 6.02 781.57 UW05 3/27/1996 9.63 779.96 (789.59) 6/3/1996 9.55 780.04 10/24/1996 9.40 780.19 9/16/1997 10.74 778.85 3/25/1999 9.91 779.68 1/14/2004 10.17 779.42 3/8/2005 9.41 780.18 6/7/2005 8.58 781.01 11/28/2005 11.13 778.46 6/19/2006 9.89 779.70 12/4/2006 9.62 779.97 6/11/2007 9.98 779.61 12/3/2007 12.65 776.94 6/2/2008 9.92 779.67 12/4/2008 10.88 778.71 6/2/2009 8.33 781.26 12/8/2009 9.11 780.48 6/7/2010 7.90 781.69 12/7/2010 11.19 778.40 6/7/2011 9.23 780.36 12/5/2011 10.22 779.37 6/6/2012 3.92 785.67 UW06 3/27/1996 6.75 775.25 (782) 6/3/1996 6.31 775.69 10/24/1996 6.75 775.25 6/22/1998 7.18 774.82 11/30/1998 7.55 774.45 3/25/1999 6.75 775.25 6/21/1999 6.45 775.55 12/13/1999 6.75 775.25 6/5/2000 5.96 776.04 12/5/2000 6.37 775.63 6/4/2001 5.70 776.30 12/5/2001 6.80 775.20 6/18/2002 6.44 775.56 12/16/2002 5.91 776.09 6/4/2003 4.91 777.09 12/15/2003 5.54 776.46 1/14/2004 6.40 6.40 0.00 775.60 6/7/2004 6.10 775.90 12/6/2004 5.85 776.15 3/8/2005 6.40 775.60 July, 23, 2012 Page 22 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) UWO6 6/7/2005 5.61 776.39 (782) 6/9/2010 6.25 775.75 12/8/2010 6.93 775.07 6/8/2011 7.06 774.94 12/6/2011 6.89 775.11 6/6/2012 3.94 778.06 UW07 3/27/1996 6.03 774.00 (780.03) 6/5/1996 7.38 772.65 10/24/1996 6.10 773.93 9/16/1997 8.07 771.96 3/25/1999 7.62 772.41 1/14/2004 6.97 773.06 UW08 3/27/1996 5.27 775.70 (780.97) 6/4/1996 6.43 774.54 10/24/1996 5.15 775.82 9/16/1997 6.25 774.72 3/25/1999 5.49 775.48 1/14/2004 4.92 776.05 2/17/2005 4.95 776.02 6/7/2005 4.12 776.85 11/28/2005 5.66 775.31 6/19/2006 5.89 775.08 12/4/2006 5.11 775.86 6/11/2007 5.03 775.94 12/3/2007 5.67 775.30 6/2/2008 4.85 776.12 12/4/2008 4.88 776.09 6/4/2009 4.60 776.37 12/8/2009 4.77 776.20 6/9/2010 4.51 776.46 12/8/2010 5.65 775.32 6/8/2011 5.45 775.52 12/6/2011 5.31 775.66 6/6/2012 5.14 775.83 UW09 3/27/1996 4.75 4.75 0.00 773.25 (778) 6/4/1996 4.25 773.75 10/24/1996 4.21 773.79 UW10 3/27/1996 6.61 778.95 (785.56) 6/6/1996 5.10 780.46 10/24/1996 5.95 779.61 1/14/2004 7.30 7.50 0.20 778.06 3/8/2005 6.42 779.14 6/7/2005 5.03 780.53 11/28/2005 7.54 778.02 6/19/2006 6.29 779.27 12/4/2006 6.07 779.49 (788.56) 6/11/2007 6.34 782.22 (785.56) 12/3/2007 8.86 776.70 6/2/2008 6.51 779.05 12/4/2008 7.51 778.05 6/3/2009 5.45 780.11 12/9/2009 5.92 779.64 6/8/2010 4.51 781.05 12/7/2010 7.19 778.37 6/7/2011 5.56 780.00 12/5/2011 6.61 778.95 6/6/2012 5.68 779.88 UW11 3/27/1996 6.15 6.15 0.00 778.64 (784.79) 6/3/1996 5.95 778.84 10/24/1996 6.15 6.15 0.00 778.64 3/25/1999 7.22 777.57 3/25/1999 7.22 777.57 1/14/2004 7.60 777.19 3/7/2005 6.97 777.82 6/7/2005 6.38 778.41 VE02 3/27/1996 4.09 781.33 (785.42) 6/4/1996 4.20 781.22 10/24/1996 4.10 781.32 3/25/1999 6.27 779.15 1/14/2004 6.20 6.50 0.30 778.92 3/7/2005 6.05 6.15 0.10 779.27 5/24/2005 5.31 5.34 0.03 780.08 6/7/2005 5.16 5.28 0.12 780.14 11/28/2005 7.86 7.92 0.06 777.50 6/19/2006 6.93 778.49 12/4/2006 6.12 779.30 6/11/2007 6.57 778.85 12/3/2007 9.18 776.24 6/2/2008 7.01 778.41 12/4/2008 7.74 777.68 6/4/2009 5.83 779.59 12/8/2009 6.25 779.17 6/8/2010 4.90 780.52 12/8/2010 8.47 776.95 6/7/2011 6.15 779.27 12/6/2011 7.63 777.79 6/6/2012 6.38 779.04 VE03 3/27/1996 5.10 780.31 (785.41) 6/4/1996 4.30 781.11 10/24/1996 4.44 780.97 3/25/1999 4.45 780.96 1/14/2004 6.31 6.31 0.00 779.10 3/7/2005 5.84 5.85 0.01 779.56 5/24/2005 4.18 4.18 0.00 781.23 6/7/2005 2.33 783.08 VE04 3/27/1996 5.23 780.23 (785.46) 6/4/1996 5.45 780.01 10/24/1996 4.95 780.51 3/25/1999 7.03 778.43 1/14/2004 6.87 6.87 0.00 778.59 July, 23, 2012 Page 23 of 24 Appendix B Summary of Historical Groundwater Elevation Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) VE04 3/7/2005 3.81 781.65 (785.46) 5/23/2005 5.67 779.79 6/7/2005 5.54 5.55 0.01 779.91 VE05 3/27/1996 5.44 779.39 (784.83) 6/4/1996 4.98 779.85 10/24/1996 4.55 780.28 3/25/1999 4.81 780.02 1/14/2004 5.52 5.52 0.00 779.31 VE06 3/27/1996 5.13 780.06 (785.19) 6/4/1996 4.55 780.64 10/24/1996 4.95 780.24 3/25/1999 5.98 779.21 1/14/2004 3.40 781.79 VE07 3/27/1996 4.02 781.50 (785.52) 6/4/1996 4.03 781.49 10/24/1996 3.35 782.17 3/25/1999 4.27 781.25 12/29/2003 4.91 4.91 0.00 780.61 1/14/2004 5.25 780.27 3/22/2004 4.55 780.97 (785.22) 3/7/2005 4.39 780.83 (785.52) 6/7/2005 3.61 781.91 Note: MSL = Mean Sea Level Groundwater elevations not corrected for LNAPL thickness. Data prior to 2007 were reported by previous suppliers and have not been verified. July, 23, 2012 Page 24 of 24 APPENDIX C SUMMARY OF HISTORICAL ANALYTICAL DATA Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ASOI 6/9/2005 <1.0 <1.0 <1.0 <3.0 39.5 <2.0 12/8/2009 <2 <2 <2 <2 480 <2 DPEW01 6/24/1998 410 70 14 97 6/8/2010 <2 <2 <2 <2 700 <2 12/17/1998 70 7 <5 10 <5 <10 12/8/2010 <2 <2 <2 <2 570 <2 6/24/1999 11000 3600 50000 20000 180000 390 6/7/2011 0.2 J <0.2 <0.2 <0.2 180 <0.2 12/15/1999 10000 8400 63000 49000 120000 12/6/2011 <0.2 <0.2 <0.2 <0.2 240 <0.2 6/7/2000 12100 4680 58600 25800 67800 339 DWO1A 6/9/2005 2.1 <1.0 <1.0 <3.0 450 <2.0 12/7/2000 1150 659 1970 2660 1990 474 DWO2 8/21/1996 1.9 <1 <1 <1 <5 6/5/2001 5400 3500 38000 20400 83000 730 6/24/1998 7 2 12/7/2001 22 16 180 107 170 620 12/3/1998 32 <1 <5 3 <5 3 6/20/2002 5.1 5.2 46 36 23 930 6/23/1999 8 <1 <5 <2 <5 <1 12/17/2002 2900 3230 30500 21200 18700 <500 12/14/1999 62 <1 <5 <2 <5 <1 6/5/2003 2630 3060 22600 18900 17500 710 6/7/2000 17.8 <0.500 <0.500 1.76 3.1 <2.00 12/18/2003 2040 3080 21800 20100 19300 725 12/6/2000 <0.500 <0.500 <0.500 2.1 4.2 <2.00 6/8/2004 1570 1970 16700 12100 17300 397 6/5/2001 3 <1.0 <1.0 <2.0 <1.0 <1.7 12/8/2004 1180 2190 8620 15300 13900 789 12/6/2001 23 <1.0 <1.0 <2.0 5.7 <2.0 6/28/2005 1140 1950 8110 17000 12600 590 6/19/2002 4.1 <1.0 <1.0 <2.0 1.3 <2.0 DPEW02 6/24/1998 7 2 12/18/2002 21 <0.50 <0.50 <0.70 9.3 <1.0 12/3/1998 15 <1 <5 <2 150 1 6/4/2003 4.2 <2.0 <2.0 <6.0 3.5 <2.0 6/23/1999 42 11 <5 5 57 9 12/17/2003 19.3 <2.0 2.5 <6.0 11.6 <2.0 12/14/1999 13 <1 <5 2.1 170 <1 6/7/2004 1.8 <2.0 <2.0 <6.0 3.9 <2.0 6/7/2000 18.8 2.37 0.93 2.69 51 <2.00 12/7/2004 1.7 <2.0 <2.0 <6.0 12.4 <2.0 12/7/2001 <1.0 <1.0 <1.0 <2.0 120 <2.0 6/9/2005 <1.0 <1.0 0.53 <3.0 2.6 <2.0 6/19/2002 <2.0 <2.0 <2.0 <4.0 120 <4.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 0.67 <2.0 12/18/2002 0.84 <0.70 1.7 2.1 23.4 <1.0 6/23/2006 12.1 6.7 2.4 42.1 2 6.7 6/4/2003 39.4 13.3 <5.0 <15 121 62.9 12/4/2006 1.4 <1 1.2 <1 35.7 <2 12/17/2003 3.9 <2.0 1 <6.0 76 1.2 6/13/2007 0.75 J <0.5 <0.5 <1 37.2 <1 6/7/2004 4.4 <2.0 <2.0 1.2 98.1 5 12/4/2007 3.6 <0.2 <0.27 <0.56 44.1 <0.44 12/7/2004 <1.0 <2.0 <2.0 <6.0 28.7 3.5 6/4/2008 <0.1 <0.1 <0.1 <0.1 10 0.28 J 6/10/2005 2.2 <1.0 0.67 <3.0 30.5 1.4 12/4/2008 0.29 J <0.1 <0.1 <0.1 27 <0.1 DW01 6/9/2005 <1.0 <1.0 <1.0 <3.0 74.3 <2.0 6/2/2009 <0.5 <0.8 <0.7 <0.8 3.4 J <1 12/5/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 12/8/2009 0.39 J <0.1 <0.1 <0.1 23 <0.1 6/21/2006 <1.0 <1.0 1.7 <3.0 0.53 <2.0 6/8/2010 0.11 J <0.1 <0.1 <0.1 29 <0.1 12/5/2006 <2 <2 <2 <6 95.8 <4 12/8/2010 1.3 <0.1 <0.1 <0.1 37 <0.1 6/14/2007 <0.5 <0.5 <0.5 <1 69.4 <1 6/7/2011 0.14 J <0.1 <0.1 <0.1 37 <0.1 12/5/2007 0.35 J <0.2 <0.27 <0.56 168 <0.44 12/6/2011 2.8 <0.1 <0.1 <0.1 52 <0.1 6/4/2008 0.12 J <0.1 <0.1 <0.1 260 <0.1 DWO3 6/24/1998 62 12/4/2008 0.12 J <0.1 <0.1 <0.1 600 <0.1 12/4/1998 3 <1 <5 4 52 <1 6/3/2009 <0.5 <0.8 <0.7 1 J 850 2.6 J 6/23/1999 <1 <1 <5 <2 54 <1 July 23, 2012 Page 1 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene DWO3 12/14/1999 <1 <1 <5 <2 72 <1 6/7/2000 <0.500 <0.500 <0.500 <0.500 50.3 <2.00 12/6/2000 <0.500 <0.500 <0.500 1.42 51.6 <2.00 6/5/2001 <1.0 <1.0 <1.0 <2.0 40 <1.5 12/6/2001 <2.0 <2.0 <2.0 <4.0 61 <4.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 53 <2.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 70.5 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 63.4 <2.0 12/16/2003 <1.0 <2.0 0.97 <6.0 60.1 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 83.8 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 63.9 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 67.1 <2.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 63.4 <2.0 6/20/2006 <1.0 <1.0 0.97 <3.0 66 <2.0 6/13/2007 <0.5 <0.5 <0.5 <1 66.2 <1 12/5/2007 <0.2 <0.2 <0.27 <0.56 64.1 <0.44 6/3/2008 <0.1 <0.1 <0.1 <0.1 59 <0.1 12/3/2008 <0.1 <0.1 <0.1 <0.1 59 <0.1 6/2/2009 <0.5 <0.8 <0.7 <0.8 68 <1 12/9/2009 <0.1 <0.1 <0.1 <0.1 68 <0.1 6/8/2010 <0.1 <0.1 <0.1 <0.1 61 <0.1 12/8/2010 <0.1 <0.1 <0.1 <0.1 71 <0.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 60 <0.1 12/6/2011 <0.1 <0.1 <0.1 <0.1 70 <0.1 DWO4 12/4/1998 2 1 <5 5 <5 <1 6/25/1999 <1 <1 <5 <2 <5 <1 12/14/1999 <1 <1 <5 <2 <5 <1 6/8/2000 0.652 0.502 <0.500 <0.500 2.02 <2.00 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 12/5/2001 <1.0 <1.0 <1.0 <2.0 1.2 <2.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 6/6/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 DW05 6/9/2005 <1.0 <1.0 <1.0 <3.0 41.6 <2.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 19.2 <2.0 6/21/2006 0.71 <1.0 0.73 <3.0 40.9 <2.0 12/5/2006 <1 <1 <1 <3 38.8 <2 6/13/2007 <0.5 <0.5 <0.5 <1 48.2 <1 12/5/2007 <0.2 <0.2 <0.27 <0.56 43 <0.44 6/3/2008 <0.1 <0.1 <0.1 <0.1 50 J <0.1 12/3/2008 <0.1 <0.1 <0.1 <0.1 37 <0.1 6/4/2009 <0.1 <0.1 <0.1 <0.1 30 <0.1 12/9/2009 <0.1 <0.1 <0.1 <0.1 38 <0.1 6/8/2010 <0.1 <0.1 <0.1 <0.1 36 <0.1 12/7/2010 0.74 0.24 J <0.1 0.6 47 <0.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 34 <0.1 12/6/2011 0.2 J <0.1 <0.1 <0.1 47 <0.1 DWO6 6/24/1998 12/3/1998 24 <1 <5 2 11000 1 6/24/1999 <1 <1 <5 <2 13000 <1 12/15/1999 <10 <10 <50 <20 12000 <1 6/8/2000 <0.500 <0.500 4.6 <0.500 4050 <2.00 12/6/2000 0.631 <0.500 <0.500 <0.500 3800 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 8600 <1.5 12/6/2001 <1.0 <1.0 <1.0 <2.0 810 <2.0 6/19/2002 <5.0 <5.0 <5.0 <10.0 4100 <10 12/18/2002 <50 <70 <50 <100 6350 <100 6/4/2003 <100 <200 <200 <600 3720 <200 12/17/2003 11.9 7.6 1 1.2 33.8 8.2 6/8/2004 <1.0 <2.0 <2.0 <6.0 972 <2.0 12/7/2004 <100 <200 <200 <600 4980 <200 6/13/2005 <1.0 <1.0 <1.0 <3.0 6240 <2.0 12/6/2005 <100 <100 <100 <300 4990 <200 6/21/2006 <50 <50 <50 <150 4840 <100 12/5/2006 <100 <100 <100 <300 6290 <200 6/14/2007 <50 <50 53.1 J 94.9 J 4200 <50 J 12/4/2007 <10 <10 <14 <28 4600 <22 6/3/2008 <5 <5 <5 5.3 J 4100 14 J 12/4/2008 <2 <2 <2 <2 3400 <2 6/3/2009 <2.5 <4 <3.5 <4 3000 <5 12/8/2009 <5 <5 <5 <5 2200 <5 6/7/2010 <5 <5 <5 <5 1200 <5 12/7/2010 <5 <5 <5 <5 1700 <5 6/7/2011 <1 <1 <1 <1 1400 <1 12/5/2011 <0.5 <0.5 <0.5 <0.5 1800 <0.5 DWO7 6/7/1995 BDL BDL BDL BDL BDL BDL July 23, 2012 Page 2 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene DWO7 6/23/1998 710 92 220 700 26 12/4/1998 22 3 <5 5 300 2 6/22/1999 15 2 <5 3 180 <1 12/14/1999 100 13 8 24 660 <1 DWO8 9/13/1994 1 BDL BDL BDL 15 BDL 6/23/1998 12/4/1998 <1 <1 <5 <2 <5 <1 6/22/1999 <1 <1 <5 <2 <5 6 12/14/1999 <1 <1 <5 <5 <5 <1 6/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.8 12/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 9/21/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <4.9 12/6/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 6/20/2006 <1.0 <1.0 <1.0 <1.0 0.5 <2.0 12/5/2006 0.7 0.5 <I <3 0.6 <2 6/13/2007 <0.5 <0.5 <0.5 <I 0.54 J <1 12/5/2007 <0.2 <0.2 <0.27 <0.56 0.71 J <0.44 6/26/2008 <0.1 <0.1 <0.1 <0.1 0.85 <0.1 12/3/2008 <0.2 <0.2 <0.2 <0.2 0.77 J <0.2 6/3/2009 <0.1 <0.1 <0.1 <0.1 0.83 <0.1 12/9/2009 <0.1 <0.1 <0.1 <0.1 1.1 <0.1 6/9/2010 <0.1 <0.1 <0.1 <0.1 1.2 <0.1 12/9/2010 <0.1 <0.1 <0.1 <0.1 1.4 <0.1 6/8/2011 <0.1 <0.1 <0.1 <0.1 1.5 <0.1 12/7/2011 <0.1 <0.1 <0.1 <0.1 2 <0.1 DWO9 6/6/2000 <0.500 <0.500 <0.500 <0.500 5.3 <2.00 12/6/2000 1.31 1.56 0.864 8.16 11.9 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 12 <1.8 12/5/2001 <2.0 <2.0 <2.0 <4.0 11 <4.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 20 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 10.9 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 15.3 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 11.1 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 121 <2.0 9/21/2004 <1.0 <2.0 <2.0 <6.0 90.6 <4.9 12/6/2004 <2.0 <4.0 <4.0 <12 116 <4.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 32.7 <2.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 126 <2.0 6/19/2006 <2.0 <2.0 <1.0 <6.0 101 <4.0 12/5/2006 <5 <5 <5 <15 177 <10 6/13/2007 <0.5 <0.5 <0.5 <1 129 <1 12/5/2007 <0.4 <0.4 <0.54 <1.1 185 <0.88 6/26/2008 <0.1 <0.1 <0.1 <0.1 190 <0.1 12/3/2008 0.35 J <0.1 <0.1 <0.1 180 <0.1 6/3/2009 <0.5 <0.8 <0.7 <0.8 190 <I 12/9/2009 <0.5 <0.5 <0.5 <0.5 200 <0.5 6/9/2010 2 J <0.5 <0.5 <0.5 220 <0.5 12/9/2010 <0.5 <0.5 <0.5 <0.5 210 <0.5 6/8/2011 0.53 J <0.5 <0.5 <0.5 180 <0.5 12/7/2011 2.1 J <0.5 <0.5 <0.5 230 <0.5 DWIO 12/5/2005 0.56 <1.0 <1.0 <3.0 61.7 <2.0 6/21/2006 <1.0 <1.0 0.84 <3.0 62.9 <2.0 12/4/2006 0.8 <1 <1 <3 63.2 <2 6/14/2007 0.51 J <0.5 J <0.5 J <1 J 52.6 J <1 J 12/5/2007 <0.2 <0.2 <0.27 <0.56 58.6 <0.44 6/3/2008 0.32 J <0.1 <0.1 <0.1 52 <0.1 12/4/2008 0.13 J <0.1 <0.1 <0.1 45 <0.1 6/4/2009 <0.1 <0.1 0.1 J <0.1 3.9 0.22 J 12/8/2009 <0.1 <0.1 <0.1 <0.1 7.7 <0.1 6/7/2010 0.16 J <0.1 <0.1 <0.1 31 <0.1 12/8/2010 <0.1 <0.1 <0.1 <0.1 26 <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 30 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 30 <0.1 ES01 6/9/2005 12.9 27.6 1 104 <1.0 37.7 11/30/2005 61.3 39.3 1.3 123 <1.0 39.2 6/20/2006 103 80.6 3.6 117 <2.0 60.9 12/5/2006 47.8 78.6 2.2 108 <1 94.6 July 23, 2012 Page 3 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ES01 6/14/2007 39.2 72 1.7 J 67 <1 77.3 12/4/2007 44 122 1.7 J 55.8 <0.5 120 6/3/2008 32 63 1.6 36 0.51 64 12/3/2008 24 91 J 1.4 31 0.48 J 67 J 6/3/2009 13 57 0.98 J 17 <0.5 60 12/8/2009 3 26 0.36 J 8.6 J <0.5 41 6/8/2010 2.2 17 0.19 J 5.6 <0.5 39 J 12/7/2010 9.5 28 0.37 J 9.7 0.34 J 47 6/7/2011 2.4 J 16 J <1 4.8 J <1 33 J 12/7/2011 3.5 22 <0.5 5.2 <0.5 40 ES02 6/24/1998 6 12/4/1998 <1 <1 <5 <2 6 <1 6/23/1999 <1 <1 <5 <2 8 4 12/14/1999 <1 <1 <5 <2 11 <1 6/7/2000 <0.500 <0.500 <0.500 <0.500 8.9 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 5.42 <2.00 6/5/2001 <1.0 <1.0 <1.0 <2.0 8.3 <2.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 14 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 20 <2.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 8.5 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 8.1 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 5.5 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 9.6 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 5 1.2 ES03 12/13/1994 BDL BDL BDL BDL 12 BDL 3/13/1995 BDL BDL BDL BDL BDL BDL 6/7/1995 BDL BDL BDL BDL 15 BDL 9/18/1995 BDL BDL BDL BDL 5 BDL 12/6/1995 BDL BDL BDL BDL BDL 10/9/1996 <1 <1 <1 <1 6.5 <5 5/27/1997 <1 <1 <1 <1 <1 <5 3/8/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 ESO4 9/12/1994 1 12 BDL 4 12 10 3/10/1995 BDL BDL BDL BDL BDL BDL 6/7/1995 BDL BDL 4 3 BDL BDL 9/18/1995 5 110 200 650 8 BDL 12/5/1995 4 2 1 4 BDL 10/9/1996 <I <1 <1 2.8 1.5 <5 5/23/1997 5 2.9 <1 4.1 21 <6 12/3/1998 <1 <1 <5 <2 42 <1 6/24/1999 2 <1 <5 <2 32 <1 12/15/1999 1.6 <1 <5 <1 60 <1 6/8/2000 2.26 <0.500 5.8 0.559 51.3 <2.00 12/7/2000 <0.500 <0.500 0.74 <0.500 14.5 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.6 12/6/2001 1.6 <1.0 7.4 <2.0 33 32 6/19/2002 <1.0 <1.0 <1.0 <2.0 21 8.5 12/18/2002 12 2.5 0.89 2.5 10.3 5.4 6/4/2003 <1.0 <2.0 <2.0 <6.0 0.84 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 1.3 <2.0 6/8/2004 1.4 <2.0 <2.0 <6.0 56 1.6 12/7/2004 1.6 0.86 <2.0 <6.0 33.5 4.8 ES05 9/13/1994 2700 390 BDL 770 BDL 106 12/12/1994 1800 400 BDL 740 BDL 110 6/7/1995 2460 500 25 980 BDL 136 6/25/1998 2100 910 2400 410 12/18/2002 696 130 6 194 <5.0 23.2 6/4/2003 1720 527 15.3 1010 <40 142 12/18/2003 606 131 6.1 242 <20 38.2 6/8/2004 579 131 <20 206 6.1 39.7 12/8/2004 746 408 7.8 746 6.2 110 ESO5DR 6/28/2005 185 36.1 <5.0 59 12.8 10.2 12/6/2005 60.9 17.2 0.56 24.8 18.5 4.6 6/20/2006 115 17.8 1.3 29.5 24.5 5.9 12/5/2006 195 21 <5 36.2 29.5 5.1 6/13/2007 198 25.6 1.6 50.6 50.4 23.2 12/4/2007 74.8 2.9 0.4 J 1.9 J 38.2 4.4 6/3/2008 90 4.6 0.49 J 7.7 46 6.4 12/3/2008 77 1.7 0.4 J 1.9 44 4.3 6/4/2009 100 7.9 0.65 14 65 6.3 12/9/2009 110 2.6 0.6 J 4.1 58 6.9 6/8/2010 110 3.8 0.87 J 12 72 11 12/7/2010 71 0.62 J 0.38 J 1.9 71 6.1 6/7/2011 110 2.6 0.6 J 8.4 66 6.6 12/6/2011 62 0.47 J 0.38 J 1.7 77 4 ESO5SR 6/28/2005 905 65.1 5 174 4.4 27.1 July 23, 2012 Page 4 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ESO5SR 11/30/2005 2870 266 5.9 351 3.7 46.8 6/23/2006 2420 195 <50 284 <50 52.6 12/6/2006 1060 59.9 <20 112 <20 22.6 6/13/2007 2520 336 <25 604 <25 132 12/4/2007 2690 255 <14 362 <13 <114 U 6/3/2008 1700 110 5.7 86 3 J 49 12/3/2008 1900 130 6.7 J 100 3.1 J 55 6/4/2009 700 44 2.4 J 83 2.8 23 12/9/2009 1100 20 3.5 J 34 2.9 J 25 6/8/2010 2800 240 10 380 3.3 J 110 12/7/2010 1700 66 5.9 45 3 J 51 6/6/2011 2100 180 9.4 280 2.7 J 99 12/6/2011 1200 7.8 4.4 J 8.9 3 J 30 ES06 9/12/1994 BDL BDL BDL BDL BDL BDL 3/10/1995 BDL BDL BDL BDL BDL BDL 6/7/1995 BDL BDL BDL BDL 4 BDL 9/18/1995 BDL BDL BDL BDL 1 BDL 12/5/1995 BDL BDL BDL BDL BDL 10/9/1996 <I <1 <1 <1 1.9 <5 5/23/1997 <1 <1 <1 <1 10 <6 6/5/1997 <I <1 <I <1 7 <2 6/24/1998 8 12/2/1998 <1 <1 <5 <2 10 <10 6/24/1999 <1 <1 <5 <2 12 <10 12/15/1999 <1 <1 <5 <2 17 <10 6/8/2000 <0.500 <0.500 0.98 <0.500 14.4 <2.00 12/7/2000 <0.500 <0.500 <0.500 <0.500 11.8 <2.00 6/6/2001 <1.0 <1.0 <1.0 <2.0 7.6 <5.1 12/6/2001 <1.0 <1.0 <1.0 <2.0 16 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 23 <2.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 14.9 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 9.8 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 8.8 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 10.6 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 9.5 <2.0 ES07 9/12/1994 4 2 BDL 2 BDL BDL 12/12/1994 BDL BDL BDL BDL BDL BDL 3/10/1995 BDL BDL BDL BDL BDL BDL 6/5/1995 BDL BDL BDL BDL BDL BDL 9/18/1995 0.6 BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL 10/9/1996 <1 <1 <1 <I <1 <5 5/23/1997 1.3 <1 <1 <1 1.3 <6 6/5/1997 <1 <1 <1 <1 <2 <2.1 3/7/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 ES08 9/12/1994 520 970 87 3,100 270 370 6/6/1995 2520 480 17 280 670 335 9/19/1995 3000 540 15 300 680 370 12/5/1995 220 420 34 2,020 280 10/3/1996 4100 610 <50 230 770 440 5/23/1997 810 140 <5 78 75 320 6/5/1997 2640 320 10 130 520 440 6/24/1998 4100 350 200 720 180 12/3/1998 1500 71 <50 44 440 110 6/24/1999 2100 460 <50 400 280 77 12/15/1999 1000 98 5.9 <I 400 98 6/8/2000 1360 157 <5.00 39.9 359 36.9 12/6/2000 443 40.5 0.768 19.4 215 63.7 6/5/2001 660 61 <1.0 17.1 620 89 12/6/2001 350 <25 <25 <50 340 <50 6/19/2002 450 25 <10 13 470 71 12/17/2002 320 27 0.55 13.8 260 61 6/4/2003 546 103 <10 12.6 124 104 12/17/2003 334 50.8 <20 <60 222 77.1 6/8/2004 525 158 <20 12 301 150 12/7/2004 196 57.8 0.91 7.5 271 69.1 ESO8DR 6/13/2005 4.6 2 <1.0 3.4 3.8 <2.0 12/5/2005 2.6 <1.0 <1.0 <3.0 3 <2.0 6/21/2006 1.5 <1.0 1.5 <3.0 4.6 <2.0 12/5/2006 65.1 <I 0.7 <3 17.7 17.8 6/13/2007 <0.5 <0.5 <0.5 <1 3.5 <1 12/4/2007 3.2 <0.2 <0.27 <0.56 10.3 <1.6 U 6/3/2008 0.76 <0.1 <0.1 <0.1 4.3 0.67 ESO8SR 6/13/2005 1710 46.1 4.7 224 337 52.6 11/28/2005 2910 190 3.7 302 274 319 6/22/2006 2380 146 2.2 270 374 402 July 23, 2012 Page 5 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ESO8SR 12/6/2006 2040 177 <50 131 370 450 6/13/2007 1760 136 <25 54 J 353 296 12/4/2007 1920 290 <14 <28 339 397 6/3/2008 1200 87 <1 10 290 300 ES09 9/13/1994 5 BDL BDL BDL BDL BDL 12/13/1994 8 BDL BDL BDL BDL BDL 3/10/1995 4 BDL BDL BDL 6 BDL 6/7/1995 BDL BDL BDL BDL 12 BDL 9/20/1995 0.6 BDL BDL BDL 8 BDL 12/4/1995 BDL BDL BDL BDL BDL 10/3/1996 <1 <1 <1 <1 17 <5 5/27/1997 <10 <10 <10 <10 24 <5 6/5/1997 <1 <1 <1 <1 23 <2.2 ES10 9/12/1994 1200 5 BDL 160 190 40 6/7/1995 1020 BDL BDL 140 120 58 9/18/1995 1100 BDL BDL 220 160 35 5/23/1997 860 2 1.9 110 130 8 6/5/1997 600 2 1 70 90 12 6/24/1998 760 1 100 73 32 12/2/1998 1100 <10 <50 150 120 28 6/24/1999 1000 <10 <50 120 95 20 12/15/1999 1000 <100 <500 <200 <500 <10 6/8/2000 440 <0.500 1.47 22.2 39.9 <2.00 12/7/2000 328 2.76 8.28 48 32.3 <2.00 6/6/2001 310 <1.0 <1.0 40 31 <5.0 12/6/2001 460 <5.0 <5.0 32 19 50 6/19/2002 370 1.1 <1.0 22.5 35 50 12/18/2002 353 0.94 <0.50 21.6 14.5 76.3 6/4/2003 453 2.6 <10 6.7 19.9 45.8 12/17/2003 225 <10 <10 5.5 11.4 55.9 6/8/2004 305 <10 <10 <30 9.3 32 12/8/2004 114 <2.0 <2.0 10.9 6.7 36.2 6/14/2005 130 <2.0 <2.0 2.3 4.8 46.9 ESII 9/13/1994 25000 1400 BDL 3200 BDL 550 12/12/1994 15000 1600 640 3900 5000 520 3/13/1995 21000 1700 870 4300 4600 450 6/8/1995 22700 2520 630 5490 2970 520 9/18/1995 14000 1300 49 3500 2400 410 5/23/1997 <10 <10 <10 <10 24 <5 6/5/1997 9100 1100 400 3200 650 495 3/23/2005 1790 1170 54.5 748 <25 314 12/9/2009 430 1200 21 310 4 J 400 ES12 9/12/1994 530 940 12 330 BDL BDL 12/12/1994 560 1100 BDL 4500 BDL 590 9/19/1995 260 710 50 2800 180 490 12/5/1995 3000 470 19 181 BDL 6/24/1998 7 59 12/2/1998 13 <1 <5 3 71 <10 6/24/1999 14 <1 <5 <2 200 <10 12/15/1999 4.7 <1 <5 <2 80 <10 6/8/2000 1.5 0.83 0.86 2.36 20.6 <2.00 12/7/2000 0.89 0.88 0.77 <0.500 19.5 <2.00 6/6/2001 1.3 <1.0 <1.0 <3.0 11 <5.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 17 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 10 <2.0 12/17/2002 4.4 <0.70 <0.50 <1.0 16.5 <0.50 6/4/2003 20 <2.0 <2.0 <6.0 23.9 2 12/16/2003 12.9 <2.0 <2.0 <6.0 13.2 2.5 6/8/2004 5.6 <2.0 <2.0 <6.0 13.2 <2.0 12/7/2004 1.3 <2.0 <2.0 <6.0 13.6 <2.0 6/13/2005 0.57 <1.0 <1.0 <3.0 9.3 <2.0 ES13 9/12/1994 14 6 BDL 5 14000 BDL 12/13/1994 11 2 7 4 18000 BDL 3/10/1995 71 BDL BDL BDL 18000 BDL 6/7/1995 BDL BDL BDL BDL 11700 7 9/18/1995 16 4 2 8 13000 BDL 12/5/1995 11 BDL 2 4 BDL 10/3/1996 13 2.1 1.4 8.3 8800 <5 5/23/1997 19 <1 2.2 5.9 5400 <6 6/5/1997 12 2 2 9 6100 2 6/24/1998 3 12000 12/2/1998 3 3 <5 3 13000 <10 6/24/1999 140 12 <50 55 7000 16 12/15/1999 <10 3.6 <5 11 8500 <10 6/8/2000 1.8 1.05 0.86 1.12 4080 <2.00 12/7/2000 <20.0 <20.0 359 242 4940 <2.00 July 23, 2012 Page 6 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ES13 6/6/2001 1.2 <1.0 <1.0 <3.0 7400 <5.2 12/6/2001 <20 <20 <20 <40 7800 <40 6/19/2002 <20 <20 <20 <40 3400 <40 12/17/2002 <0.50 <0.70 <0.50 <1.0 43.1 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 8660 <2.0 12/16/2003 <100 <200 <200 <600 3860 <200 6/8/2004 <100 <200 60.3 <600 3740 <200 12/7/2004 <100 <200 <200 <600 5810 <200 6/13/2005 <10 <10 <10 <30 4920 <20 11/29/2005 2.4 <1.0 <1.0 <3.0 4510 <2.0 6/20/2006 <100 <100 <100 <300 4640 <200 12/5/2006 <20 <20 <20 <60 1500 68.6 6/14/2007 0.57 J <0.5 <0.5 <1 218 <1 12/4/2007 <0.4 <0.4 <0.54 <1.1 26.5 <0.88 6/3/2008 <0.1 <0.1 <0.1 <0.1 25 0.33 J 12/4/2008 0.15 J <0.1 <0.1 <0.1 24 <0.1 6/4/2009 0.11 J <0.1 <0.1 <0.1 22 <0.1 12/8/2009 <0.5 <0.5 <0.5 <0.5 140 1.7 J 6/7/2010 0.39 J <0.1 0.16 J 0.2 J 57 0.46 J 12/7/2010 <0.5 <0.5 <0.5 <0.5 9.9 <0.5 6/6/2011 0.53 J <0.5 <0.5 <0.5 16 <0.5 12/5/2011 <0.5 <0.5 <0.5 <0.5 7.3 <0.5 ES14 9/12/1994 BDL BDL BDL BDL BDL 610 6/7/1995 835 17 BDL 3 3 81 9/18/1995 820 21 BDL 21 22 160 12/5/1995 480 24 BDL 14 100 10/3/1996 560 42 <5 <5 <5 220 5/27/1997 7 2 BDL 9 63 44 6/5/1997 300 40 <5 35 25 92 6/24/1998 1200 160 290 190 12/2/1998 100 8 <5 3 <5 53 6/24/1999 1000 260 <50 710 <50 190 12/14/1999 100 33 6 <1 <5 6.4 6/8/2000 45.5 3.66 0.86 3.41 <0.500 <2.00 12/6/2000 4.65 1.43 <0.500 2.23 <0.500 <2.00 6/6/2001 8.2 <1.0 <1.0 <3.0 <1.0 <1.7 12/6/2001 15 2.6 3.7 7.3 2.6 16 6/19/2002 18 2.3 <1.0 <2.0 <1.0 14 12/17/2002 11.8 2.9 <0.50 <1.0 0.65 20.9 6/4/2003 982 213 10.6 548 <20 312 12/16/2003 349 88.8 <20 34.1 <20 363 6/8/2004 93.6 17.9 <2.0 3.1 2.5 79.6 12/7/2004 188 55 <10 39.8 3.3 142 6/13/2005 132 32.2 2 43.5 2.3 51.5 11/29/2005 10.5 4.1 <1.0 <3.0 1.9 5.1 6/23/2006 9 2.2 <1.0 <3.0 2.2 3.9 12/5/2006 26.3 10.5 <1 <3 2.6 13.5 6/14/2007 36.4 10.8 <0.5 <1 2 9.2 12/4/2007 12.8 4.2 <0.27 <0.56 1.9 5.4 6/3/2008 7.9 2.2 <0.1 0.14 J 1.2 1.6 12/4/2008 0.72 1.5 <0.1 0.13 J 1.4 0.86 6/2/2009 340 160 4.3 J 310 3.3 J 300 12/8/2009 86 31 0.7 43 4.4 65 6/7/2010 75 40 0.18 J 18 3.8 89 12/9/2010 20 12 <0.1 1.5 3.8 28 6/6/2011 69 33 0.44 J 34 3.2 110 12/5/2011 4.2 5.5 <0.1 0.55 2.8 7.2 ES15 9/12/1994 14 6 BDL 5 14000 BDL 3/10/1995 BDL BDL BDL BDL BDL BDL 6/6/1995 1.2 BDL BDL BDL 9.3 2.1 9/18/1995 1.2 BDL BDL BDL 2 BDL 12/5/1995 BDL BDL BDL BDL BDL 10/3/1996 <1 <1 <1 <1 <1 <5 5/23/1997 <1 <1 <I 1.6 <1 <6 6/5/1997 <1 <1 <1 <1 <2 <2.1 ES17 9/18/1995 BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <I <1 <1 <10 <2 6/2/1997 <1 <1 <1 <1 <10 <2.3 3/7/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 ES 18 3/23/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 12/1/2005 <1.0 <1.0 <1.0 <3.0 <1.0 8.1 6/20/2006 <1.0 <1.0 <1.0 <3.0 I 9.1 12/5/2006 <1 <1 <1 <3 <1 7.7 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J 0.99 J 2.2 J 12/4/2007 <0.2 0.46 J <0.27 <0.56 <0.25 <1.2 U July 23, 2012 Page 7 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ES18 6/3/2008 <0.1 0.4 J 0.13 J 0.39 J 0.13 J 3.7 12/3/2008 0.1 J 0.52 0.21 J 0.35 J <0.1 13 6/3/2009 <0.5 <0.8 <0.7 <0.8 <0.5 <1.6 U 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.13 J 1.8 6/8/2010 0.14 J 0.2 J 0.23 J <0.1 0.2 J 4.1 12/8/2010 0.76 0.33 J 0.48 J 0.41 J 0.42 J 7.7 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/7/2011 <0.1 0.12 J 0.14 J <0.1 0.15 J 3.6 ES19 6/24/1998 9 2 5 11 12/3/1998 5 2 <5 <2 <5 <1 6/24/1999 5 4 <5 3 <5 <1 12/15/1999 <1 <1 <5 <1 <5 <1 6/8/2000 0.694 <0.500 6.72 <0.500 <0.500 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 6/19/2002 3.2 3.1 <1.0 <2.0 <1.0 5 12/17/2002 14.9 111 55.7 292 <1.0 115 6/4/2003 <1.0 2.2 <2.0 6.2 <2.0 6.4 12/16/2003 2.2 174 4.7 595 <2.0 190 6/8/2004 0.84 56.4 <2.0 91.3 <2.0 63.5 12/7/2004 0.82 26.2 <2.0 26.4 <2.0 23.3 6/10/2005 0.92 4.4 <1.0 5 <1.0 4.6 11/29/2005 2.1 27.4 <1.0 88.8 <1.0 53.5 6/20/2006 <1.0 <1.0 <1.0 1.2 <1.0 2.9 12/5/2006 0.7 <1 0.6 <3 <1 1.6 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J <0.5 J <1 J 12/4/2007 0.24 J 0.33 J <0.27 <0.56 <0.25 <0.96 U 6/3/2008 0.3 J 0.16 J 0.12 J 0.14 J <0.1 0.7 ES20 6/5/1995 BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <1 <1 <1 <10 <2 5/23/1997 <1 <1 <1 <1 <1 <6 6/2/1997 <1 <1 <1 <1 <10 <2.2 3/7/2006 <1.0 <1.0 <1.0 <3.0 0.62 <2.0 ES23 6/24/1998 15 12/2/1998 <1 <1 <5 <2 17 6/23/1999 <I <I <5 <2 16 <1 <1 12/15/1999 <1 <1 <5 <2 8.2 <1 6/7/2000 <0.500 <0.500 2.44 <0.500 12 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 3.44 <2.00 6/5/2001 <1.0 <1.0 <1.0 <2.0 3.1 <1.5 12/6/2001 <1.0 <1.0 <1.0 <2.0 1.5 <2.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 1.5 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 0.5 5.9 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 2 <3.0 <1.0 <2.0 ES25 6/5/1995 BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <I <1 <1 <10 <2 6/2/1997 <1 <1 <1 <1 <10 <2.2 12/1/1998 <1 <1 <5 <2 <5 <1 6/25/1999 <1 <I <5 <2 <5 <1 12/16/1999 <1 <1 <5 <2 <5 <1 6/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 12/5/2001 <1.0 <1.0 <1.0 <2.0 3.9 <2.0 6/20/2002 700 20 530 204 9.5 9.9 12/18/2002 13000 746 16000 5340 <130 <250 6/5/2003 6440 1330 22700 9110 <500 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6/20/2006 1.4 2.6 <1.0 <3.0 2.2 2.8 12/5/2006 <1 1.8 <1 <3 0.7 2.1 6/14/2007 0.72 J 0.71 J <0.5 <1 1.8 <1 12/4/2007 0.64 J 0.47 J <0.27 0.65 J 2 <1.2 U 6/4/2008 0.2 J 0.95 <0.1 0.52 <0.1 3.3 12/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/2/2009 <0.5 <0.8 <0.7 <0.8 <0.5 <1 12/8/2009 <0.1 <0.1 <0.1 <0.1 <0.1 0.44 J 6/7/2010 <0.1 <0.1 <0.1 <0.1 <0.1 0.34 J 12/7/2010 <0.1 0.48 J <0.1 1.4 <0.1 13 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/5/2011 <0.1 2.1 <0.1 2.5 <0.1 15 ES32 10/23/1996 2900 650 340 2200 80 230 12/17/2002 8270 2360 8120 10900 67500 1040 6/5/2003 6470 1830 4980 8460 61700 1010 12/16/2003 6350 1880 3130 9210 56900 1070 6/8/2004 5730 2200 2550 10900 40700 892 9/21/2004 6750 2320 1770 11900 44100 1140 12/8/2004 4780 1620 1050 8150 35400 671 6/28/2005 3060 1480 503 7420 6840 550 12/1/2005 4050 1800 597 8590 26800 868 6/22/2006 4080 1420 386 6650 22300 1020 12/6/2006 732 902 135 4020 1040 595 6/2/2009 0.72 J 1.6 J <0.7 5.2 1.3 J 5.7 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.39 J <0.1 6/7/2010 0.24 J <0.1 <0.1 0.1 J 0.98 0.23 J 12/8/2010 33 7.1 0.86 8.7 47 8.7 6/6/2011 68 18 0.95 2.8 520 1.5 12/5/2011 150 41 1.1 J 7.2 470 5.8 ES33 6/24/1998 9100 380 160 870 1100 26 12/2/1998 8700 210 <500 270 3000 41 6/23/1999 11000 2500 27000 12000 51000 670 12/15/1999 13000 4600 36000 23000 120000 290 6/7/2000 17200 5550 35300 28800 117000 124 12/7/2000 4790 268 5940 3370 37000 740 6/5/2001 8400 2600 12000 12100 130000 <1.6 12/6/2001 10000 <5,000 11000 17400 59000 <10,000 6/19/2002 8300 3000 8100 16400 40000 830 12/17/2002 9660 2670 4940 12900 30300 <1,000 6/5/2003 8520 2110 3510 11600 23300 888 12/16/2003 9080 2110 2470 12000 28200 911 6/8/2004 10500 2180 1940 13300 31200 1110 12/7/2004 8630 2000 1310 11600 16500 645 6/28/2005 8110 1800 826 10100 18800 688 12/1/2005 6870 1710 631 10300 13300 1100 6/22/2006 7080 1020 471 8710 15600 919 12/6/2006 5950 1360 340 7820 12100 842 6/14/2007 5730 J 1330 J 305 J 7550 J 9180 1180 J 12/4/2007 5650 1360 276 7210 8410 636 6/4/2008 4400 1000 200 5900 8500 740 12/4/2008 4100 970 150 5000 5900 790 6/2/2009 3800 1000 130 6000 5900 1000 12/8/2009 3100 910 110 5100 3900 900 6/7/2010 3700 890 95 4800 3700 830 12/7/2010 3200 750 81 3900 2700 810 J 6/6/2011 3500 790 77 4200 2600 930 12/5/2011 3700 670 73 3000 3200 660J ES34 6/24/1998 270 1 12/2/1998 <1 <1 <5 <2 230 3 6/23/1999 <1 <1 <5 <2 250 <1 12/16/1999 <1 <1 <5 <2 140 <1 6/7/2000 <0.500 <0.500 <0.500 <0.500 164 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 114 <2.00 6/5/2001 <1.0 <1.0 <1.0 <2.0 160 <1.6 12/6/2001 <5.0 <5.0 <5.0 <10.0 160 <10.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 100 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 88.8 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 33 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 84.9 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 55.8 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 71.3 <2.0 6/10/2005 <1.0 <1.0 <1.0 <3.0 50.3 <2.0 11/29/2005 <1.0 <1.0 <1.0 <3.0 96.8 <2.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 37.1 <2.0 12/6/2006 <1 <1 <1 <3 34.5 <2 6/2/2009 <0.1 <0.1 <0.1 <0.1 0.65 <0.1 July 23, 2012 Page 10 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ES34 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.14 J <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 2.1 <0.1 12/7/2010 <0.1 <0.1 <0.1 <0.1 0.84 <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 1.1 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 0.38 J <0.1 ES35 6/25/1998 6900 26 43 150 12/2/1998 6100 <100 <500 <200 <500 52 6/24/1999 5500 20 <50 26 520 110 12/15/1999 3900 18 <50 21 <50 87 6/7/2000 3630 51.2 25.4 153 57.1 18.5 12/6/2000 786 <10.0 <10.0 <10.0 <10.0 48.5 6/5/2001 3300 <200 <200 <400 220 <1.5 12/6/2001 1800 <100 <100 <200 <100 <200 6/20/2002 2800 <50 <50 <100 <50 <100 12/17/2002 2520 <35 <25 <50 <25 <50 6/4/2003 2370 <100 <100 <300 <100 122 12/16/2003 1360 <40 <40 <120 <40 86.2 6/7/2004 1900 18.5 13.5 <120 <40 168 12/7/2004 1190 6.2 3.7 2.8 <2.0 88.3 6/28/2005 1180 <50 <50 <150 <50 <100 12/ 1 /2005 651 5.1 1.3 <6.0 1.1 47.6 6/22/2006 1630 12.1 4.2 3.3 1 177 12/6/2006 822 <20 <20 <60 <20 55.3 6/14/2007 1460 32 16.3 J <20 <10 110 12/4/2007 530 <2 <2.7 <5.6 <2.5 38.5 6/4/2008 960 5.8 J 2.5 J <2 <2 75 12/4/2008 370 2.3 1.1 J 0.56 J 0.86 J 37 6/2/2009 800 15 6.9 J 4.2 J <1 83 12/8/2009 520 8.2 2.6 J 1.6 J <2 40 6/7/2010 700 14 5.6 5.5 <2 54 12/7/2010 290 2.8 1.4 J 0.54 J 1.2 J 36 6/6/2011 670 5.6 J 3.1 J <2 <2 54 12/5/2011 400 4.6 2.2 J 0.77 J 0.64 J 33 ES37 10/23/1996 460 81 430 210 40 22 6/24/1998 1 12/2/1998 <1 <1 <5 <2 65 <1 6/23/1999 <1 <1 <5 <2 <5 <1 12/14/1999 <1 <1 <5 <2 <5 <1 6/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.6 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 ES38 6/24/1998 3 3 13 12/2/1998 5 <1 <5 2 <5 <1 6/23/1999 4 1 <5 <2 <5 4 12/14/1999 2.1 <1 <5 <2 <5 <1 6/7/2000 2.6 0.94 <0.500 0.55 2.8 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/5/2001 1.4 <1.0 <1.0 <2.0 1 <1.6 12/6/2001 <1.0 <1.0 <1.0 <2.0 2.5 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/4/2003 2.2 0.54 <2.0 1.4 0.99 4.1 12/17/2003 <1.0 <2.0 <2.0 <6.0 2.4 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 4.3 <2.0 12/7/2004 0.78 0.9 <2.0 <6.0 1.4 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 4.8 <2.0 11/30/2005 <1.0 <1.0 <1.0 <3.0 3.4 <2.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 2 <2.0 12/5/2006 <1 <1 <1 <3 2.1 <2 6/13/2007 <0.5 <0.5 <0.5 <1 5 <1 12/4/2007 0.57 J 0.29 J <0.27 <0.56 3.6 <0.53 U 6/4/2008 0.11 J <0.1 <0.1 <0.1 0.79 0.4 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 6/3/2009 <0.1 <0.1 <0.1 <0.1 1.4 <0.1 12/9/2009 <0.1 <0.1 <0.1 <0.1 2.9 <0.1 6/8/2010 <0.1 <0.1 <0.1 <0.1 4.5 <0.1 12/8/2010 <0.1 <0.1 <0.1 <0.1 5.8 <0.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 0.76 <0.1 July 23, 2012 Page 11 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene ES38 12/6/2011 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 ES39 6/10/2005 0.79 0.95 <1.0 <3.0 <1.0 <2.0 ES40 6/10/2005 136 7.5 2.7 5.6 1.2 9.1 11/29/2005 168 6.3 3.8 3.8 <2.0 18.3 6/22/2006 420 17.4 7.1 <30 <10 132 12/5/2006 126 6.1 2 2.4 <2 22.7 6/14/2007 177 J 8.6 3.6 7.1 <0.5 20.8 12/4/2007 285 16.9 7.1 14.5 J <1.3 35.7 6/4/2008 38 0.83 0.29 J 1 0.14 J 4 12/4/2008 13 1.3 0.32 J 0.48 J 0.16 J 1.5 6/2/2009 4.2 <0.1 <0.1 0.13 J <0.1 0.36 J 12/8/2009 8.9 0.67 0.23 J 0.53 0.14 J 2.6 6/7/2010 11 0.96 0.26 J 0.51 0.11 J 3.9 12/7/2010 94 2.3 2.2 2.6 0.25 J 58 6/6/2011 6.3 1.1 0.27 J 0.29 J <0.1 0.56 12/5/2011 62 2.6 2.3 3.7 0.16J 55 ES41 6/10/2005 0.55 0.61 <1.0 <3.0 <1.0 <2.0 12/5/2007 <0.2 <0.2 <0.27 <0.56 <0.25 <0.44 6/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 0.29 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 ES42 6/25/1998 240 42 2 6/24/1999 240 28 <5 37 <5 15 12/15/1999 <10 20 <50 39 <50 4.8 6/7/2000 157 13.5 4.3 21.7 5 5.29 6/5/2001 23 <1.0 <1.0 6.2 1.7 <2.1 6/20/2002 47 <1.0 <1.0 3.6 <1.0 15 12/17/2002 102 9.1 1.5 13 <1.0 10.9 6/5/2003 75.3 1.8 1.2 8.2 1.2 5.2 12/16/2003 17.6 1.1 0.53 3 <2.0 3.2 6/7/2004 16.7 0.73 0.74 2.6 <2.0 2.5 12/7/2004 16.6 1 0.61 3.9 <2.0 2.8 6/13/2005 4.2 <1.0 <1.0 <3.0 0.52 <2.0 ES43 6/10/2005 0.7 1.2 <1.0 <3.0 15.3 <2.0 ES44 6/10/2005 <1.0 0.58 <1.0 <3.0 <1.0 <2.0 MPO6 6/9/2005 8.5 120 1.5 35.3 124 52.5 MWO2 3/14/1995 4000 830 BDL 2000 BDL 250 9/20/1995 2700 290 240 970 600 120 12/6/1995 5600 550 480 1860 180 5/23/1997 11000 1000 740 2900 2600 6/25/1998 4100 280 830 1000 180 12/3/1998 12000 960 <500 2500 2800 150 6/24/1999 9800 740 <500 1900 2700 270 12/16/1999 8100 660 <500 1600 1800 84 6/8/2000 8150 482 180 1220 2210 165 12/7/2000 7290 716 150 1540 2410 158 6/6/2001 4600 300 76 640 1600 80 12/6/2001 9100 700 130 1190 4300 680 6/20/2002 8400 440 <200 830 5200 200 12/18/2002 4460 355 65.3 609 2360 258 6/5/2003 1320 128 <100 227 374 54.5 12/17/2003 6760 414 74.8 814 5120 309 6/8/2004 3030 197 50.8 493 2080 140 12/8/2004 9340 595 91.5 1150 9350 481 6/28/2005 1830 79.6 24.4 237 1590 85.7 12/1/2005 7070 382 57.9 495 7790 288 3/7/2006 1170 <100 <100 248 7390 <200 6/23/2006 4670 274 37 422 4170 226 9/25/2006 4000 330 <500 460 4400 <500 12/6/2006 7260 439 73.6 612 5400 350 6/14/2007 7980 J 461 55.6 630 6280 J 375 12/4/2007 4910 222 42.6 J 308 6170 <134 U 6/3/2008 4300 200 33 310 3100 130 12/3/2008 1300 99 10 110 810 84 6/2/2009 200 17 1.4 J 17 230 10 12/8/2009 1500 130 15 J 160 1100 88 6/8/2010 210 26 3 27 100 21 12/8/2010 4100 330 35 400 2200 270 6/7/2011 1200 83 10 110 1300 69 12/7/2011 190 48 2.2 J 35 70 43 MWO3W 12/18/2002 2.1 <0.70 2.4 2.3 <0.50 <1.0 12/17/2003 <1.0 <2.0 1.4 <6.0 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 MW05 6/27/2005 13.7 9.1 1.7 27.3 2.2 15.8 11/30/2005 10.6 109 7.3 314 <2.0 178 July 23, 2012 Page 12 of 22 v co co 0 N O, N 01 N a1 N 00 0o .- (:n .-• Nco O O N O N OAOOO�A W W N Cr, O\ 0, so O VD A A A A A w A 6\o A 0 0 0 0 00 0 0 A A A A N �--. rA-. cAi. n O O A n O O O O O N o O O O O O O O A A A A A �'" A 0 0 in O O O O O 'A o o O O o O A A was Oni N O W A O O © O O O O 00 N A A A A A A AAA ©© A l l N O O O O O Q O O O O co A A A A A .A- A A A A O O O O O O �''� O v O 0 00 O O N A 0, Crs - \- .V1 00 N as N CO ON 0 O O O O A O W N Cr, O O N Os N CO N � O O a\ O A A A A A 0 A A O O O O C O W n A A A A a n 0 A A O O O O O 0 O O r-- O A N A N. 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N O W O O O O O O O U O Benzene Ethylbenzene Toluene X (D CD co m m (D !D Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene MW14R 6/26/1998 26 12/2/1998 <1 <1 <5 <2 <5 38 6/25/1999 <1 <1 <5 <2 <5 <1 12/16/1999 <1 <1 <5 <2 <5 17 6/8/2000 1.6 <0.500 0.57 3.76 1.6 <2.00 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/6/2001 <1.0 <1.0 <1.0 <3.0 2 <1.6 12/5/2001 <5.0 <5.0 <5.0 <10.0 <5.0 39 6/20/2002 <5.0 <5.0 <5.0 <10.0 <5.0 <10 12/18/2002 <0.50 <0.70 <0.50 <1.0 1.5 <1.0 6/5/2003 5.4 <2.0 <2.0 <6.0 2.4 <2.0 12/17/2003 7.9 <2.0 <2.0 <6.0 2.3 1.4 6/8/2004 1.3 <2.0 <2.0 <6.0 2.8 <2.0 12/7/2004 0.7 <2.0 <2.0 <6.0 2.4 1.9 6/8/2005 <1.0 <1.0 <1.0 <3.0 2.4 3.5 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J 3.2 J <1 J 12/4/2007 <0.2 <0.2 <0.27 <0.56 3.3 <2.2 U 6/3/2008 <0.1 <0.1 <0.1 <0.1 3.1 1.1 12/3/2008 <0.1 <0.1 <0.1 <0.1 3.3 <0.1 6/2/2009 <0.1 <0.1 <0.1 <0.1 3.1 0.76 12/8/2009 <0.1 <0.1 <0.1 <0.1 4.1 0.99 6/8/2010 <0.1 <0.1 <0.1 <0.1 3.5 0.87 12/8/2010 <0.1 <0.1 <0.1 <0.1 4.4 0.58 6/6/2011 <0.1 <0.1 <0.1 <0.1 3.5 <0.1 12/7/2011 <0.1 <0.1 <0.1 <0.1 2.7 0.33 J MW16 6/28/2005 5.6 5 17.9 26.3 <1.0 4.2 MW18 12/14/1994 5 2 14 3 1200 BDL 6/8/1995 2320 382 BDL 810 225 210 9/20/1995 8500 1100 680 3800 3000 260 12/6/1995 BDL BDL BDL BDL BDL 10/9/1996 480 110 140 700 1800 33 MW19 3/23/2005 3980 744 37.4 396 901 216 12/1/2005 5790 900 <100 488 1090 182 3/7/2006 6020 705 <100 277 1770 212 6/22/2006 3730 546 <100 321 1040 206 9/25/2006 830 350 <250 240 160 <250 12/6/2006 2880 704 28.6 498 927 288 6/14/2007 6770 J 776 J 30.8 J 479 J 1380 J 330 J 12/4/2007 5970 665 <27 352 1290 <213 U 6/3/2008 730 270 8.4 J 270 230 180 12/3/2008 1600 150 6.2 J 100 620 110 6/3/2009 210 110 2.9 J 46 43 52 12/8/2009 2000 180 7.1 J 120 300 100 6/8/2010 1500 220 7 J 120 160 160 12/8/2010 4300 500 17 390 580 290 1/17/2011 5600 650 20 J 460 590 270 6/7/2011 780 110 3.6 67 170 66 12/7/2011 2300 290 9.7 160 260 150 MW20 6/27/2005 1070 195 78.3 486 <50 128 MW21 6/27/2005 11400 630 654 2110 227 224 11/30/2005 9000 1060 345 3120 78 881 6/22/2006 7480 1130 578 2970 <200 609 12/6/2006 5490 943 324 2150 <500 519 6/14/2007 10800 J 1350 J 603 J 4240 J 98.8 639 J 12/4/2007 11600 1710 572 3910 54.2 J 666 6/4/2008 5000 1100 380 2800 35J 830 12/3/2008 4400 1200 390 2500 30 J 840 6/4/2009 4300 1200 470 3000 34 780 12/9/2009 5500 1300 350 2800 65 J 790 6/9/2010 14000 1100 610 2800 140 520 12/8/2010 9100 1500 390 3000 54 J 840 6/8/2011 11000 1400 810 3300 60J 620 6/23/2011 14000 1700 1100 4500 46 J 510 7/21/2011 15000 1700 1200 4500 49 J 700 8/16/2011 15000 1600 1200 4300 47 J 690 11/22/2011 8500 1200 470 2400 43 J 590 2/16/2012 4300 800 360 1900 27 550 MW26 6/27/2005 22 22.7 8.2 55.7 <1.0 6.7 11/30/2005 2.7 3 <1.0 <3.0 <1.0 <2.0 6/22/2006 263 10.5 12.9 14 2.1 2.2 12/6/2006 217 130 6.7 <15 <5 15.3 6/14/2007 174 13.6 6.2 9.8 J 0.52 J 6.4 12/4/2007 38.2 1.1 0.49 J 0.58 J <0.25 <0.93 U 6/3/2008 4.5 <0.5 <0.5 <0.5 <0.5 3.2 12/3/2008 190 8.5 3.5 1.7 1.2 15 J 6/4/2009 410 9.6 J 13 J 18 J 1.3 J 21 July 23, 2012 Page 14 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene MW26 12/9/2009 91 36 2.7 5.1 <0.5 120 6/9/2010 980 56 44 100 2.1 J 54 12/8/2010 220 2.7 5 4.6 0.66 J 41 J 6/8/2011 230 58 4.8 3.9 0.65 J 15 6/23/2011 290 15 8.1 7.8 <1 25 7/21/2011 300 24 9.3 13 <1 50 8/16/2011 290 24 8.4 10 <1 48 11/22/2011 110 4.7 4.1 13 0.22 J 28 2/16/2012 200 5.8 7.6 19 0.57 J 49 MW27 6/27/2005 884 91.9 30.3 507 <50 295 MW36 3/23/2005 11300 1140 133 1330 484 284 12/6/2005 9180 932 123 1420 550 376 3/7/2006 3160 255 23 444 780 81.9 9/25/2006 3600 1000 <250 1400 300 390 12/6/2006 45.3 36.1 <5 39.7 118 30.5 6/12/2007 5580 614 68.4 J 984 553 201 12/4/2007 5170 919 131 1280 162 <222 U 6/3/2008 6700 1100 150 1600 140 370 12/4/2008 3100 700 71 900 110 280 6/3/2009 2200 300 29 430 260 150 12/8/2009 3100 850 69 790 71 340 6/8/2010 4400 480 33 300 330 240 12/8/2010 4700 970 62 550 340 440 1/17/2011 4800 910 49 400 220 380 6/7/2011 1600 280 20 J 150 120 110 12/7/2011 2900 1100 67 610 94 470 MW37 3/23/2005 1000 58.1 <20 42.3 89.2 41.4 12/9/2009 4.3 J 2.3 J <0.7 1.5 J <0.5 <1 MW38 6/5/2003 6260 1780 15800 10700 754 550 3/23/2005 3910 1610 13800 10700 358 479 12/1/2005 704 459 3400 4300 40.3 175 3/7/2006 201 444 757 2930 25.4 236 6/22/2006 110 194 411 1330 15.8 180 9/25/2006 34 94 74 340 <1.0 65 12/6/2006 71.6 108 346 710 <5 79.4 6/12/2007 433 264 847 1570 41.3 138 12/4/2007 63.7 112 138 822 10.8 71.5 6/3/2008 1 J 52 11 360 <1 43 12/4/2008 <0.5 2.4 J 0.73 J 10 <0.5 2.1 J 6/3/2009 0.22 J 4.7 1.6 36 <0.2 6 12/8/2009 <0.1 0.84 0.23 J 6.8 <0.1 1.3 6/8/2010 <0.1 0.42 J 0.15 J 1.7 <0.1 0.45 J 12/8/2010 3.1 1.6 1.1 23 0.94 1.2 1/17/2011 86 410 J 85 J 1600 14 290 J 6/7/2011 <0.1 0.19 J <0.1 0.72 <0.1 0.25 J 12/7/2011 <0.25 2.1 <0.25 8 <0.25 3.3 MW39 9/13/1994 11000 1800 5200 12000 5400 520 3/13/1995 9100 470 5000 5400 8400 490 12/6/1995 14000 590 9800 8100 420 5/23/1997 18000 970 16000 9200 6000 420 6/5/1997 1700 1000 15000 8000 6500 480 6/25/1998 1200 170 1200 1900 1300 100 12/3/1998 7300 350 3300 3300 3200 110 6/23/1999 10000 470 5900 3800 2500 150 12/16/1999 10000 420 6500 3600 1400 200 6/8/2000 10600 526 8040 3880 1900 207 12/7/2000 5120 101 2150 1130 872 79.4 6/6/2001 5300 <500 3700 2400 960 150 12/6/2001 16 <1.0 6.6 5.3 <1.0 <2.0 6/19/2002 9100 710 5300 4500 1500 <200 12/18/2002 11600 1180 8310 6640 919 348 6/5/2003 9460 803 6670 4930 794 292 12/17/2003 7430 701 3190 3950 720 287 6/8/2004 4890 507 2720 3200 441 203 12/8/2004 7610 806 4070 4500 500 384 6/28/2005 6860 610 2890 3700 331 165 12/1/2005 3870 417 1760 2550 79.9 <200 3/7/2006 4670 483 2590 2990 151 151 6/23/2006 2160 221 1010 1230 64.2 83.8 9/25/2006 85 58 73 250 <1.0 39 12/6/2006 663 112 237 576 19.6 96.2 6/14/2007 582 94.6 197 413 22.1 144 12/4/2007 473 43.5 98.1 184 32.7 <11 U 6/3/2008 340 31 34 100 4 13 12/4/2008 150 16 23 64 4.4 5.1 6/3/2009 340 190 280 850 6.4 73 July 23, 2012 Page 15 of 22 ZZ Jo g; a6ed Z LOZ 'EZ AInf 09 Lb 9L 69 1£ 06b OIOZ/8/ZI 6E LI °E 8 ZI £L OIOZ/8/9 817 OZ L9 9'6 ZZ OH 600Z/8/ZI 9E 81 LI £.8 L'L 051 600Z/£/9 LS LZ 0E1 LI SS OEI 800Z/17/ZI ZE I£ IE L•6 OZ 0171 800Z/E/9 C175 6' IL 8.EZ b'0I 17'9Z OZE LOOZ/b/ZI f b'1E f 9.0S f CbI f CS f E.S f 90Z LOOZ/b1/9 I Sb IS LOZ £.S 6.£I 51Z 900Z/9/ZI 005> 00I> 00E> 00I> 00I> OEZ 900Z/SZ/6 S'6Z E.9S £'ZI 9.E E'E 6171 900Z/ZZ/9 Z.81 L'I9 SI> 9.Z 0'5> Z9I SOOZ/I/ZI b I 6L9 COE 8'E 9'LZ L8I 500Z/EZ/E 6'I 6 6'5 8'1 CS S•Z£ £00Z/5/9 WAIN 6 ZI 19 I'£9 S'Z CI I 6.E£ 500Z/LZ/9 8bMNI S•SZ L'9Z 96 E'L 8.bb b.ZS SOOZ/LZ/9 L17Mh! 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O O O O .N- 00 O N \0 00 O O O D O\ O N 00 N O_ 0 N b O_ 0 N N D 0 N O 0 0 0 N N O 0 a) m t t1 Z w to F- 2 tl) CD T x Ethylbenzene Toluene a) CU 0 CO 77) tri N O O O \O Q\ r) t M 7 V1 00 - N 00 00 t O D N 00\ V \D 00 M N 0 7 D O N N r' O\ r \D CO C. 0 O 0 0 0 CD M 0.00 l— 00 (+) t� 00 M N N rn N O O O '-' v --u7 .-. .. u, .; 0 0 0 0 0 0 0 0 0 V V V V V V V V V V V V oo n OMi or, 000 o00 000 Cr, QS N N 00 O M 7 -- "� N —~ • o H V o oV V ti N N \D O O M M O N t� N • M 00 — rn \D 00 -- CO (` t- M N ^-, \0 V M y V N 0 0 0 0 0 O O 0 O 0 O 0 NNNNNN M -- to \D 7 7 N - N N M \D \D 0 N O O V oo V O 00 O N D 00 N .N- 0\ O N 0 O O -N- O_ O N 00 D O_ O N 00 N VD VD s 0 O O N N O 0 0 O O O O 0 N 0 0 0 N 00 \D 'ch 00 N v1 0 O\ N 0\ 0o D1 VD V f M \D t` 0o v) u1 O t` t— 7 M rn N M N N N ^ 7 cn t- N V V( Vl M ul M [- M ul 0 0 0 0 0 0 o 0 O 0 0 0 .--� N 0 0 0 O O 0 O O 0 0 0 0 0 0 0 0 0 0 0 0 t� 00 O O O -- O\ \O N vl 7 M t-- 00 \D -- -- N 00 \D -- CO 01 00 C\ •--. N V) M \D 00 0o 0\ u1 N 7 N M N N N N 0 0 0 0 0 CD CD O O O O O 0 O 0 O 0 O 0 0 0 0 0 0 0 o N o cc) 7 N M O Vl 00 00 - 00 CD rn M 0 N M 0V M M N --- 0 N 0 O ^N- -- N a\ O O 0 O O O 0 CD O O - t0 O O O \0 Cisul l0 0 7 N 00 01oo N N N M N M \O D\ C.-'r \O V O 0 O 0 00 0 M M O O 0 M 0 N r. V7 M 0\ N t— VD to t-- ,_- r- v) O VD ch ch D1 -- 0 t` --. V rn N O\ lD 7 Vj t� ,_- 0\ 00 •--. v '0 h VD t� l0 M d' V V M 'r O O 0 0 0 O O O 0 0 0 0 0 O 0 0 O O C. O 0 O O 0 0 0 0 0 O C 00 O O O O\ 00 t- (n t- O O 00 N 0o N M (7\ \D 0 -- N U u1 N 7 \D \O 00 00 'cr 0 M 00 a\ l� \D 00 01 01 D\ M \0 \0 N 00 CO t� \D \D t� t t� \O to \D t, 00 00 O\ O\ O\ O 0\ O\ 0\ O\ 0\ O\ C\ C\ 0\ C\ C\ -M- M N N N N Q\ M •--• V7 \O •--. \D O O O N 00 D O N b N D O O 0 O O N N 0 O VD N M O M O 7 0 O 0 0 N CD CD0 N —C.N N \D N \D cF N V1 b \O O O 0 O 0 O 0 0 0 0 NNNNN 00 CO -- M \D -N- iD .-. \D - Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene MW65 12/8/2010 21000 2400 1600 6600 90 J 670 6/8/2011 13000 1400 1500 4900 35 J 400 6/23/2011 15000 2000 1900 6200 35J 480 7/21/2011 16000 2100 1700 6000 33J 670 8/16/2011 15000 2000 1700 6300 26J 650 11/22/2011 14000 2200 2400 6100 27 J 630 2/16/2012 13000 2000 1500 5300 21 J 640 MW66 8/30/2010 180 22 8.9 41 24 78 12/7/2010 380 46 6.2 38 540 86 6/7/2011 190 91 7.9 48 110 81 12/6/2011 84 58 6 30 28 47 MW67 8/30/2010 570 660 26 66 220 850 12/7/2010 520 860 26 140 220 1000 6/7/2011 340 660 20 98 130 800 12/6/2011 410 610 19 38 180 810 MW68 8/30/2010 18 6.7 2.4 58 43 0.96 12/8/2010 390 91 27 270 220 71 6/8/2011 160 73 33 510 240 57 6/23/2011 90 30 14 150 130 17 7/21/2011 99 45 15 110 130 25 8/16/2011 100 7.5 11 120 180 9.1 11/22/2011 57 8.4 2.4 21 190 3.1 2/16/2012 46 8.1 1.8 J 18 250 2.9 MW69 5/24/2011 0.12 J <0.1 <0.1 0.17 J 95 5.6 6/8/2011 <0.1 <0.1 <0.1 <0.1 41 0.4 J 6/23/2011 <0.1 <0.1 <0.1 <0.1 70 0.19 J 7/21/2011 <0.1 <0.1 <0.1 <0.1 68 0.36 J 8/16/2011 <0.1 <0.1 <0.1 0.12 J 41 2.1 11/22/2011 <0.1 <0.1 <0.1 0.26 J 34 3.2 2/16/2012 <0.1 0.12 J <0.1 0.4 J 30 2.8 PMW01 12/15/1994 BDL BDL BDL BDL 16 6/8/1995 BDL BDL BDL BDL 15 BDL 12/6/1995 BDL BDL BDL BDL BDL 6/6/1997 <1 <1 <1 <1 15 <2 12/16/1999 <1 <1 <5 <2 39 6/7/2000 <0.500 <0.500 <0.500 <0.500 61.4 12/6/2000 <0.500 <0.500 <0.500 <0.500 65.8 6/4/2001 <1.0 <1.0 <1.0 <2.0 55 12/5/2001 <5.0 <5.0 <5.0 <10 110 <10 6/19/2002 <5.0 <5.0 <5.0 <10.0 100 <10 12/17/2002 <0.50 <0.70 <0.50 <1.0 73.5 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 95.8 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 119 <2.0 6/7/2004 <2.0 <4.0 <4.0 <12 105 <4.0 9/21/2004 <1.0 <2.0 <2.0 <6.0 162 <5.0 12/6/2004 <2.0 <4.0 <4.0 <12 113 <4.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 90.8 <2.0 PMWO2 12/15/1994 4400 970 3100 4400 BDL 6/8/1995 6570 1660 4280 7700 BDL BDL 12/6/1995 4400 800 2200 3600 6/6/1997 3950 1200 1400 4900 <100 255 12/16/1999 2100 660 <5 2700 <500 6/7/2000 2640 769 745 3000 <5.00 12/6/2000 1430 314 342 1210 <0.500 6/4/2001 1900 440 450 1730 <100 12/5/2001 1700 670 480 2500 <100 220 6/19/2002 2300 950 900 4000 <50 330 12/17/2002 834 210 189 887 7.6 139 6/3/2003 3040 965 817 4060 <100 297 12/16/2003 2130 628 393 2310 18.5 384 6/7/2004 2260 547 385 2010 <100 216 9/21/2004 3250 667 429 3240 20.7 196 12/6/2004 1380 452 193 1250 22.1 220 6/14/2005 50.5 124 29.2 544 <5.0 63.4 12/5/2005 11.3 1.2 0.56 2 <1.0 <2.0 6/20/2006 664 134 35.9 287 0.52 36.1 12/5/2006 28.2 48.2 2.4 106 <I 23.3 6/13/2007 148 74.1 8.5 127 1.1 44.7 12/5/2007 595 157 34.4 259 15.4 92.3 6/3/2009 780 150 23 120 8 25 12/9/2009 970 190 110 350 60 75 6/9/2010 1600 320 110 310 42 100 12/9/2010 950 250 110 440 32 86 6/8/2011 430 190 64 370 22 68 12/7/2011 710 290 93 590 35 150 PMWO3 12/15/1994 760 170 BDL 370 BDL July 23, 2012 Page 18 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene PMWO3 6/8/1995 1300 180 96 500 38 71 12/6/1995 950 180 2200 3600 6/6/1997 1650 270 200 780 510 64.3 6/23/1998 1000 140 76 350 970 10 12/4/1998 350 42 <50 110 810 12 6/22/1999 1300 200 87 460 1900 28 12/14/1999 790 120 67 240 2600 20 6/6/2000 <0.500 <0.500 <0.500 5.17 21.5 <2.00 12/6/2000 1.26 <0.500 <0.500 2.33 311 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 220 <1.6 12/5/2001 <20 <20 <20 <40 460 <40 6/19/2002 <1.0 <1.0 <1.0 <2.0 130 <2.0 12/17/2002 <2.5 <3.5 <2.5 <5.0 360 <5.0 6/3/2003 1.9 <4.0 <4.0 <12 160 <4.0 12/16/2003 <5.0 <10 <10 <30 256 <10 3/22/2004 <10 6/7/2004 <5.0 <10 <10 <30 257 <10 9/21/2004 <1.0 <2.0 <2.0 <6.0 339 <5.0 12/6/2004 <5.0 <10 <10 <30 209 <10 6/14/2005 <1.0 <1.0 <1.0 <3.0 180 <2.0 PMWO4 3/11/1999 <5 <5 <5 <5 320 <5 12/14/1999 <1 <1 <5 <2 370 <1 6/6/2000 <0.500 <0.500 <0.500 <0.500 280 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 327 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 400 <1.8 12/5/2001 <10 <10 <10 <20 450 <20 6/19/2002 <1.0 <1.0 <1.0 <2.0 200 2.2 12/17/2002 <2.5 <3.5 <2.5 <5.0 375 <5.0 6/3/2003 <5.0 <10 <10 <30 238 <10 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.6 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 353 <2.0 12/6/2004 <10 <20 <20 <60 346 <20 6/9/2005 <1.0 <1.0 <1.0 <3.0 323 2.4 PMW05 6/7/1995 BDL BDL BDL BDL 132 BDL 12/6/1995 BDL BDL BDL BDL 125 BDL 3/11/1999 <5 <5 <5 <5 180 <5 PMWO6 12/15/1994 BDL BDL BDL BDL 820 6/8/1995 BDL 1 BDL BDL 300 6 12/6/1995 BDL BDL BDL BDL 6/6/1997 <1 <I <1 <1 116 2 3/22/2004 <10 3/8/2006 <1.0 <1.0 <1.0 <3.0 1.5 <2.0 PMWO7 12/15/1994 BDL BDL BDL BDL 14 6/7/1995 BDL BDL BDL BDL 90 BDL 12/6/1995 BDL BDL BDL BDL 920 BDL 12/2/1996 <1 <1 <I <1 <10 <2 1/12/1998 <1 <1 <1 <1 6.1 3/8/2006 <1.0 <1.0 <1.0 <3.0 4.9 <2.0 PMWO8 12/15/1994 BDL BDL BDL BDL BDL 6/8/1995 BDL BDL BDL BDL 20 BDL 12/6/1995 BDL BDL BDL BDL 6/6/1997 <1 <1 <1 <1 42 <2 6/23/1998 50 12/4/1998 <1 <1 <5 <2 72 <10 6/22/1999 <1 <1 <5 <2 83 <10 12/14/1999 <10 <1 <5 <2 <5 <10 6/6/2000 <0.500 <0.500 <0.500 <0.500 74.4 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 80.4 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 55 <5.4 12/5/2001 <1.0 <1.0 <1.0 <2.0 61 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 90.8 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 15 <2.0 6/7/2004 <2.0 <4.0 <4.0 <12 150 <4.0 9/21/2004 <1.0 <2.0 <2.0 <6.0 10.1 3.1 12/6/2004 <1.0 <2.0 <2.0 <6.0 57.5 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 84 <2.0 PMWO9 12/15/1994 BDL BDL BDL BDL 1700 6/8/1995 BDL BDL BDL BDL 20 BDL 12/6/1995 BDL BDL BDL BDL 6/23/1998 9 12/4/1998 <1 <1 <5 <2 180 <10 6/22/1999 <1 <1 <5 <2 190 <10 12/14/1999 <1 <1 <5 <2 170 <10 6/6/2000 <0.500 <0.500 0.79 3.02 115 <2.00 July 23, 2012 Page 19 of 22 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene PMWO9 12/6/2000 <0.500 <0.500 <0.500 <0.500 129 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 68 <5.3 12/5/2001 <2.0 <2.0 <2.0 <4.0 92 <4.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 110 <2.0 12/17/2002 <1.0 <1.4 <1.0 <2.0 93.8 <2.0 6/3/2003 <2.0 <4.0 <4.0 <12 135 <4.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 92.6 <2.0 3/22/2004 <10 6/7/2004 <2.0 <4.0 <4.0 <12 137 <4.0 9/21/2004 <1.0 <2.0 <2.0 <6.0 130 <5.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 73.9 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 100 <2.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 32 <2.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 68.3 <2.0 12/5/2006 <1 <1 <1 <3 58.4 <2 6/13/2007 <0.5 <0.5 <0.5 <1 23.4 <1 12/5/2007 <0.2 <0.2 <0.27 <0.56 8.2 <0.44 6/26/2008 <0.1 <0.1 <0.1 <0.1 16 <0.1 12/3/2008 0.31 J <0.1 <0.1 <0.1 180 <0.1 6/3/2009 <0.1 <0.1 <0.1 <0.1 17 <0.1 12/10/2009 <0.1 <0.1 <0.1 <0.1 9.6 <0.1 6/9/2010 <0.1 <0.1 <0.1 <0.1 11 <0.1 12/9/2010 <0.1 <0.1 <0.1 <0.1 0.67 <0.1 6/8/2011 <0.1 <0.1 <0.1 <0.1 7.8 <0.1 12/7/2011 <0.1 <0.1 <0.1 <0.1 0.63 <0.1 PMW10 6/23/1998 180 12/4/1998 <1 <1 <5 <2 76 <1 6/22/1999 <1 <5 <2 120 <1 12/14/1999 <1 <1 <1 <2 34 <1 6/6/2000 <0.500 <0.500 <0.500 <0.500 101 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 164 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 5.4 <1.6 12/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 1.2 <2.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 2.2 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 2.3 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.1 <2.0 3/22/2004 <10 6/7/2004 <1.0 <2.0 <2.0 <6.0 0.9 <2.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 0.77 <2.0 PMW11 12/2/1996 <1 <1 <1 <I 234 <2 6/23/1998 43 12/1/1998 <1 <1 <5 <2 390 <10 3/11/1999 <5 <5 <5 <5 220 <5 PMWI2 3/11/1999 <5 <5 <5 <5 <5 <5 6/22/1999 <1 <1 <5 <2 <5 <10 12/14/1999 <I <1 <5 <2 <5 <1 6/6/2000 <0.500 <0.500 <0.500 <0.500 1.6 <2.00 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 6/4/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.8 6/18/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 12/16/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 6/3/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.1 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 RWO2 3/23/2005 778 262 19.5 295 119 178 UW02 10/24/1996 350 1.1 <1 11 <8 <5 6/27/2005 558 172 33.8 281 25 132 UW04 6/13/2005 1.2 <1.0 0.58 <3.0 3.6 <2.0 UW05 6/13/2005 <1.0 <1.0 <1.0 <3.0 18.4 <2.0 11/30/2005 <1.0 <1.0 0.9 1.3 49.4 <2.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 6.4 <2.0 12/5/2006 <I <1 <1 <3 7.1 <2 6/13/2007 <0.5 <0.5 <0.5 <I 8.1 <1 12/4/2007 <0.2 <0.2 <0.27 <0.56 4.8 <0.44 6/4/2008 <0.1 <0.1 <0.1 <0.1 3 0.33 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 1.6 <0.1 6/4/2009 <0.1 <0.1 <0.1 <0.1 0.93 <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 1.5 <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 1.3 <0.1 12/7/2010 0.15 J <0.1 0.24 J 0.13 J 2 <0.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 0.97 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 1.2 <0.1 July 23, 2012 Page 20 of 22 to O R R 0 0 V O O 5.st m re Z < = ip z O ) c0 a co c o rn as EE �c <2 G)-o C O d Y z'm E E E ' 7 O W ` f0 L 0 0) N co 0 Z w CD N X Benzene Ethylbenzene Toluene VD .-. O O .M.M . M CD CD 0 0 O O O co 7 oo N M N 0 0 10 N vl N N 000 O9 0 000 N h 10 cn ^ M N oo 0 O O N N N en •--i 1p N N 0 h 00 O N N N O N O N 0 0 O O N N N 0 0 0 O 0 O_ 0 O1 h O 00 1D 1D N N M vt 0 0 O 00 O v M ci ci Q W CO C1 O 0 0 0 0 00o VDvf) O O O 10 O M .Nr .h-• M .-• O\ O .M. o O 3 1a O1 O O C. O 01 N � ON N O M — �0 h O O O 0 O O ~' h Vl CDO M 00 O O 01 N O V O M lD V V1 00 Vl 7 h N '7 '7 re. M M h 00 h O M O 0 O O 'I 00 h 'el-\D en N V vt N V 00 M N N N V' 00. 001 Oh V O O O O O O O O NO N h 01 O 00 O 00 O O vl oo V tr. vl M M V M M OC N 0 N O .�-, ND O N ti 00 vl Ul �O �O h .--• M-. Z 00 1p n 00 00 h .. 00 0 0 0 00 0 0 M O O O O O O _O O OON h r O h h00 V V O O O O 0 0 O O O 0 0 O 0 0 N h CO h 01 O1 0 0 0 0 0 0 0 O O '7 00 h h O M N 00 00 10 \0 7 v1 7 7 kr, V lin 'c. "el- d. )n kr, kn O O N N O Vl O N O 10 1O h C- O O O 0 0 O 0 O NNNN r1 NO d' hi NO O oo O O N O O O N 0 N M O O tV O N 00 O O_ O N hi hi O N N O O N N N n en O 1D n O O O CA N ' 0 0 0 0 0 O O 0 0 v) 1D h M r1 V '7 'C' V' v") el0 N h O O O co CDO 0 00 h M vl N N v'� O v1 01 ._. V M V ._. N oo .D O O O O O O 0 0 0 0 0 0 O— ON1 '0 1N0 M M ( . N M O CD ON h O _O 0 ON 0 0 0 0 00 M N N M r) N r) M O N 10. M h N N O O O O O O O 1D O1 ‘.0O 0 M N v1i ‘.0 4-1 en ,t1Oh 00 VD O O O 0 0 O ' v1 O O O O O O M n M O V O O N N 0 v1 rn N O O O N b O oo N N O N 00 O O N 00 N N O O N e 0 416) L 0 z I1) CO 0) a0) X Ethylbenzene Toluene 0) N 0) O O 0 0 ci M N v b V c`i hl V V M M N V V Lal - CO ti O`1 N vl 1p ,� N tD O h N N V chi) N N •--. Vi M V �T 0 0 0 0 10 co O O h 071 N N N v.) �' 1D h N N 10 N h 'U N 1MD 7 00 00 r O v1 d' 0 00 N N N N M 10 M O 0 M 0 0 N Lei . ^. o O1 ? vl V1 • p 00 O O N O 00 M h.. Cr,N 1p M V V V V V V V 0 0 0 0 0 0 0 0 0 --. O N N N ‘..07 0• C N N V N V N O N rn 4.1 1O vt 1O . V 'V' '.0 O vl `� 10 N Ut .--• � .--� h O M O O 1p '7 • 00 M 1D O. h •--• --- h V N N D\ 1D M<VD CT V ri N h c`I ri N d' M h oo oo ON CA N O Cr, Cr, O1 0 0 CD 0 O M 0 0 v1 0 — ,^ '� .- 001 001 O O O- 0 O 0 N N 0 N N 0 N 0hi p N N N O N oo h 00 O V N h h ` 10 01 7 .--. h h Q. Q. 00 M 10 O O O .N. O N. N. O N. 10 N. 10 N O V VD O h 00 10 O O N N O O N p O rl ONM N h 00 01 9O Cs h re)— M 7 M N Cs N h N 01 O O V 0 co N O O0 co 0( 0 OO 0 O 001 7 00 00 N M 10 O M O O 00 O N V V N O OO O ['J M NO N N • V •N V rn M 0 7 v1 ti 01 O M h V1 M M 00 M-r 00 M N 10 " 00 -� NO N ^ p ON N N N N O v1 01 1D h 7 00 M 10 M h N ti O O O h O • O O co co co N M N N N N n N v-)co 10 01 O 'S O 00 O O O N O \O tel O O N O D 1D h h 0 0 0 0 O 0 0 O NNNN M 10 9. vl O - '.0 00 O O N O 00 O O N O O O N 7 '.D 01 O O N N O O N July 23, 2012 Appendix C Summary of Historical Analytical Data BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene VE03 6/27/2005 13.8 7.1 2 18.4 1.6 3.2 VE04 6/27/2005 74 24.3 31.9 183 48.3 20.3 VE07 6/27/2005 3410 1490 14900 8330 <250 383 Note: Concentrations in ug/I J = Estimated value U = Below detection limit Data prior to 2007 were reported by previous suppliers and have not been verified. July 23, 2012 Page 22 of 22 APPENDIX D FIELD PARAMETER MEASUREMENTS, DECEMBER 2011 P:1BP\Projects\Terminals14762\5.0 Deliverables\5.1 Draft - Interim Deliverables\CAP Modification Document 6-1-20121AppendiceslApp D Field Data m GO N Ln MW-14R <CC-3 t17 O N ,_,O O to o N D PMW-09 O N 4 00 00 4 D\ -4 4 QN 0, 4 cn VD 4 to 00 4 In .--• c In O 4 A LO A A -P .-- MW-39 W 00 t,, 0, N 0\ N .-• .-- VD N O 00 ES-38 ES-40 MW-02 W to W A W W W N N VD N 01 — .--• 00 v,v, A W IES-05DR ES-05SR riC7CJCI0C1C)C7C7 C4 O �--' O O VD O 00 O 0\ O LA O W O N O -- Well Designation 00 01 CN C1 6.77 01 0\ 0 0\ J 0\ 0\ U 01 U 01 ,rnrnD CN In 1 01 6.33 01 in 0\ is •-• 01 in W 0\ A J o l I O W rn ,l rn N 6.82 O VD 6.31 Oob W In N 11, W ,7 is N j, VD a N ►Oi-A ► O W O LID �1 VD 19.27 -4 A VD 20.85 20.50 N O 00 -4 -- to Cr, to 14.33 16.82 •- 00 Lo -4 -- �l Cr, LA 18.80 ► 00 Lo VD .--. LO Cr, -1 .--. LO W 18.84 N O ► ► N LA �D LA N ► �1 N 22.13 20.64 N O N ► 23.45 22.64 -- VD 0 to 21.14 N O tJ 00 18.99 17.43 20.13 .--. -4 O VD .-- ,l in LA .- W VD �1 .. -4 �1 O .- D 'co -- N O LA to 19.04 N O �1 N N .-• Cr, N VD N W N W �1 VD 23.70 N ► N 00 N O O 0\ A �O VD A 00 N O in LA N N A O VD -1 ► 00 D, VD \D in N H n 9 o O n -, `." W n ,1 467 494 438 396 AJ�. A 348 765 400 344 306 W 152 618 54 607 193 ► A 0, VD 34 735 315 VD 548 00 77 80 463 CD 461 LA 808 361 La La.►-. 200 145 1 178 728 J 215 O 104 73 331 O0o Obi 387 478 682 Specific Conductance (mS/cm) 0\ 01 W O VD 0.32 O �1 N 5.28 1.33 4.89 N 0, �1 O Cr, to 1.03 -1 01 5.85 A in 00 0.80 W W W L4 �1 0.32 0.44 5.27 U ,1 00 ► to 4 0.45 O W \O N O -1 O Cr, VD In A O 4.36 0.32 2.17 2.75 O VD W 1.78 ► 0\ In A O O N 00 00 0\ -1 0.26 O W O 0.34 0.24 0.42 -- LA O V. V. 'D A (n 00 VD 0\ -1 N N --1 \D 4.09 3.48 _ I In N LA W O LA Dissolved Oxygen (mg/L) n 90. o •y m A z m 4 2 nr fD L to 9 y 'O 1 tro R y o ° 2 G. 7 7 - 7 = N" O d m n 3 n 07 A '7 O N O I APPENDIX E HISTORICAL ISOCONCENTRATION MAPS EL 0 Ln cu C7 N L d 3 L N L. 1 _i, `' r I\� ® .Sea f • �i—\ '`.\ �s\", ..t'^\ /% ` .�,•. 7.�\ 1 _• :l/\�`\1, '' \\;• •`m ('.m .... Y i"\ s �� r: \�1 �t„�`�''`,• III n,, \ — fi"j \ yam\ '.. \_ '�"'•- � ! ' '~�.�t • ,r\ I I i ' i • �..�'le" a� l I µ Ir I 1 ' 7 I N? .. � r ,-. �"1 •i r"' //I 1 ^ %• � I% ! ~,-S. ii -,;•9'/! n,a1 1 1- i, , '. ' • f'.I -\r/ il n1 ;ra/1,,,,,,,'•.' i. `•�� l `/r• /yi • • t !I +—. f.. p ef. �.1., _ ,w If 1i J�r' s � •� '( _L .•yt _._ i ._�, i." •:•=•,.,..1 . i „S— ✓ , it( 'iW_ ,I .__' _ — ,--�`1 f I. .m t—/"^• :� _V� I,. . - �} re \ • Fo \ i J• '\(t '1 I i' (, • :.,r`. I :Jr I 1�.L V _^\- I' —\-"- 1'\!-J r r"_v I _i li L : `!/ .I.d �.t ._ _ 1' _=.._�` %•1: ii _•�Ur DECEMBER 2009� JUNE 2010 DECEMBER 2010 -- • _ ....--" . --=',#:::1 "i% �� 0 350 , _ 4 uf' 1I.w\ 4 �t fir. '4w•e\` \ +. , • Legend \ I — — — Property Line - •i ,• • rrr DN01 • Groundwater Monitoring Well •` '^ •" rf tt Abandoned Monitoring Well J•_= i i._ Isoconcentration 1 Benzene t f f i ,. •_ Contour (ugll) .?_ • JUNE 2011 i, :• :.�� • - -i_' -ice. DECEMBER 2011 I' if SCALE AS SHOWN ➢ESIGNED BY DATE Historical Benzene Isocon ce ntration Mops CDNFIIENTIAL-ALL RIGHTS RESERVED-PRIPERTY OF DRAWN BY DATE BF Terminal 4762/ Milli TSH 17FEB12 Southeast Terminal CHECKED BY CF DATE 17FEB 12 CONTRACT NO. DRAVING NO. REV. APPROVED BY DATE ROU, NORTH CAROLINA 2/59D MN 17FEB12 J3-00004762.01 1—BENZENE 0 CU Cd CU r i L d 3 L s D, L� l 1 .1- -.;:� �''. I' \ / I '1 I ... I --\ IL-... 1 I (i J ;\t f •! S G --. % II er:' �.' DECEMBER 2009 tip` ti J 1• :ro �_Z.._.-_- -, _'o,I QG'J 1.....• . - 'I I ILL\' / r• . ♦.� > ' I ` - I� ; , "- i • . ` ...• . ' '' I , 1 t --��',/ • A - rr' f Ii ' '". f ,. !2• / -- JUNE 2010 11 A...„: \ .. 1 r,- ' !_ ,, ,.•m iWf . • •4—.—^ ` � o• 1 i � - Lbw._ 'M=-- • d I I _ � • '�. l'l "( � _- / - \ - .. \. . I -iI •1 l �1 ' t" - �-. r �, :�=- LJ I ''r 1 C /ram — , ". ` ..-� -! _ DECEMBER 2010 �b 1 1 .~ -_ L '-\ w, - / - !.. t _ •_ _ .+` •• •. _ \ " _ l ,I'Ix .vs , F t � - _. r•f i ,. 7 -..., , .' . _ _ . 1 , J• ! r � f, ,, JUNE 2011 �\ / +. • e." • _ -Ire '(!= r J _ K." \ i Y�� ` I , ` i �_ "• i j 1_ I r' 1 r- . ;= DECEMBER 2011 � \ _ _ J = _ 0 ` ; " _ / s" ( \ '9" _ , / 1 ' :"" 0 350 — — DW01 • Ti Legend — Property Groundwater Abandoned Line Monitoring Well Monitoring Well Isoconcentration Contour (As of 1/1/2010) Isoconcentration Contour 20 200 MTBE (ugll) MTBE 1 SCALE AS SHOWN DESIGNED BY DATE Historical MTBE Isoconcentration Maps BP Terminal 4762/ Southeast Terminal CDNFIIENTIAL-ALL RIGHTS RESERVED-PRIPERTY OF IIIRS RDU. NDR11 CARDUNA 2756D DRAWN BY TSH DATE 17FEB12 CHECKED BY CF DATE 17FEB 12 CONTRACT ND. J3-00004762.01 DRAWING NO. 2-MTBE REV. 0 APPROVED BY MN DATE 17FEB12 ..-.\ \ \, `•\` - _ ^` }\ " V I i �` , • • f.9 II ' I Aw \ ,.e I.Te f1._ (_.'S.. ,f '� i� i . i - • l /^ `.,i I ro .n I I, �� ': DECEMBER 2009 --_ , �. I I (� I 1 •'r�fi1..n .,/ %/ , JUNE 2010 = ,r `"I } - I r.. j. \ If ,, . :.� ;`\ ` ( '�. \ t \�_-L 1t • - ......1 r -_� i _ -- ': - -- —%' 7 1' ti -\ / _\ .\ ;I ... r, . - - ice' \ �' I • I ,� 6•.. •_ j ! '• I �,. Y. /, I ✓ 1 r-,r) 1 • �% r i I i J- DECEMBER 2010 f i . `. .%� 0 350 I - ... I . - •;.� " �• •`s ��1 '� �• t I `_ I •' — — — Property Line D'i°D1 • Groundwater Monitoring Well k"* Abandoned Monitoring Well ® 21 I .. .�dr - a' - Naphthalene Isoconcentration Contour (ug/l) • �. a rr I JUNE 2011 � fI' 4- , DECEMBER 2011 6 Naphthalene Isoconcentration Contour (ug/I) (As of 1/1/2010)�fy,. SCALE AS SHOWN DESIGNED BY DATE Historical Naphthalene Isoconcentration Maps curMENTAL-ALLRIGHTS RESERVED -PROPERTY OF lintS DRAWN BY TSH DATE 17FEB12 BP Terminal 4762/ CHECKED BY DATE Southeast Terminal CF 17FEB12 CONTRACT Na DRAWING NO. REV, Rou, NORTH CAROLINA 27560 APPROVED BY MN DATE 17 FEB 12 J3-00004762.01 3—NAPH 0 DECEMBER 2009 DECEMBER 2010 r" _,#71 D 350 DWO1• Legend Property Line Groundwater Monitoring Well Abandoned Monitoring Well - 0.38 1,2-Dichloroethane Isoconcentration Contour (ugh) - 0.40 1,2-Dichloroethane Isoconcentration Contour (ug/I) (As of 1/1/2010) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PREPERTY OF RDU, NORM CAROUNA 275BD DRAWL BY TSH DATE 17FEB12 CHECKED BY CF DATE 17FEB12 Historical 1 ,2—Dichloroethane Isoconcentration Maps BP Terminal 4762/ Southeast Terminal APPROVED BY MN • DATE 17FEB12 CONTRACT NO. J3-00004762.01 BRAVING NO. 4-1,2—DCA REV. 0 APPENDIX F GROUNDWATER SAMPLING EVALUATION GRAPHS 10000 _ 1000 All Wells • • ■ 4• ♦ • • 100 - ♦■ g f • o ♦ . --e CO - ® os • - • ♦ x x o C — x R O — k ,} ♦ ■ c0 — V X+ x • C — X • + ✓ + + C + 10 — + + • ■ • ■ • ' s e • x x • 2 e♦ *♦ �° • ■ ■ ■ •• ♦ *• • x • • • • ♦ ■ A • • •• '• • • •g4 • i• • • z! • • n + X ■ X • ■ X ■ X • 4 • e • • e • • ■ ■ X x X 1 _ X X • ■ X + X 111 {F 0.1 • 1994 1996 1998 Legend o Benzene ■ Toluene ♦ Ethylbenzene • Xylene • MTBE + 12DCA X IPE • Naphthalene 1 I I I 2000 2002 2004 2006 2008 2010 Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F1 Time -Trend Graph of Average Groundwater Concentrations for All Wells Project No. 38436703 10000 Area 1 - East Side 1000- 0.1 ■ a • • • ♦ •, e ♦ • • • ■ • • • +I • ■x x • • ■ • • ♦ ■ • • ♦ * x x x x X x x x X x x +x • • + I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene • Toluene • Ethylbenzene • Xylene • MTBE • 12DCA x IPE Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F2 Time -Trend Graph of Average Groundwater Concentrations for Area 1 - East Side Project No. 38436703 10000 _ 1000 - Area 2 - Truck Loading Rack Area • ++ + 1 - x■ • 0.1 • ♦ • x • • • x 4 v ■ ♦ X X- ♦ • • • • + • • x • x • * • • • • • x • x ■ ■ ■ x ■ • • • • • + • ♦ • ■ ■ I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene ▪ Toluene • Ethylbenzene • Xylene • MTBE • 12DCA x IPE Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F3 Time -Trend Graph of Average Groundwater Concentrations for Area 2 - Truck Loading Rack Area Project No. 38436703 10000 _ Area 3 - Central/Upgradient Area ■ • 1 000 _ ■ • °♦ ,r • * * ° ♦ ° X • •° * • • • _ 4 • •a * ♦ ° • - ♦ •• • ° ♦ • • C - O - • - ■ X • • + ♦ ♦ * ♦ • • ■ • V + • # ■ ■ ■ ■ V0 10 _ ■* X ■ + ■ X ■ ■ - + + X ■ X ■ { + X ■ - X + X + X X X X • X° !+ X .. X X X X E ♦ + X X X .X X + • + 1 — MIX ■ ■ XX■ X+ ++ ■ 0.1 • + X I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene Toluene • Ethylbenzene • Xylene • MTBE • 12DCA IPE Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F4 Time -Trend Graph of Average Groundwater Concentrations for Area 3 - Central/Upgradient Area Project No. 38436703 10000 _ Area 3 - Central/Upgradient Area ♦■ ♦ ♦ 1000 : ■ — • ■ - ♦ ♦ - ♦ ■ ♦♦ ♦ - • it * • x _ ♦ ■ • ♦ • • • • ♦ ♦ 100 - :r ♦ ♦ 3 ¥ a ♦ i ,r ♦ • • x v ■ + 2 ♦ • • ■ • U• 10 _ ■ x..■ + ■ x ■ ■ + +4 X MIx■+ + X ■ X + + X X x X X - X♦ + + + + x X X X X ♦ + X x x X+ X X ■ + — + ♦ + • ,r • ♦ • • • ♦ a • ♦ ♦ ♦ • • • ♦ ♦ ♦ ° ♦ ♦ $ ♦ • • • • • s • ♦ Ir—in"—A • • ■ + .} + 1 — X■x ■ ■ x x ■ x + + + ■ — x ♦ • .4 • 0.1 X I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend ° Benzene • Toluene ♦ Ethylbenzene ♦ Xylene • MTBE + 12DCA X IPE Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2004 and January 1, 2005 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F5 Time -Trend Graph of Average Groundwater Concentrations for Area 3 - Central/Upgradient Area Project No. 38436703 10000 _ 1000- Area 4 - Central/Downgradient Area • 100 - x c, — 7 • • • • • 0 �� :7 • • • 1 • • C 4'♦ ♦ d • ♦ + • • • 0 • C • V10 - . x x • • • • • • • • y • • + x • ♦ x • • :, - ♦ •' x — f• + + + + _ ,r + • * + • • x X + 1 0.1 ■ • i ♦ ■ ■ ■ i 4 x • + ■ • ♦ x • ♦ 4 I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene • Toluene • Ethylbenzene • Xylene • MTBE • 12DCA x IPE * Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others uRs BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F6 Time -Trend Graph of Average Groundwater Concentrations for Area 4 - Central/Downgradient Area Project No. 38436703 Area 4 - Central/Downgradient Area I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene • Toluene • Ethylbenzene • Xylene • MTBE • 12DCA X IPE • Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2004 and January 1, 2005 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F7 Time -Trend Graph of Average Groundwater Concentrations for Area 4 - Central/Downgradient Area Project No. 38436703 • 10000 _ 1000 0.1 •e • Area Area 5 - ISOC Area • A • ♦ • A ♦ A A • A® _■ vv ■ • • ■ • • • • 7z- • • • A • + .a. X + „• ■ ♦ A • • A • A ♦ • • * X • A A ♦ • • ■ • ■ VA x x® 1 + X.7 • A ♦ • •• A ♦ • • • ■ 7 • A X X • F X x • X X • + •X•• IN X X X • X + + • + + + ++ +1+l + + + • x x x I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene • Toluene • Ethylbenzene • Xylene • MTBE • 12DCA x IPE Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others URS BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F8 Time -Trend Graph of Average Groundwater Concentrations for Area 5 - ISOC Area Project No. 38436703 10000 _ 0.1 c Area 5 - ISOC Area e _ • ••♦ ••® • • • x* x ■ ■x■* ■ x x x • X + + * + + + ++ +111+11E • e 1 I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 Legend • Benzene • Toluene • Ethylbenzene • Xylene • MTBE • 12DCA x IPE • Naphthalene Solid lines are straight line best fit for each analyte from January 1, 2000 through December 31, 2004 and January 1, 2005 through December 31, 2011 Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others uRs BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, North Carolina Figure F9 Time -Trend Graph of Average Groundwater Concentrations for Area 5 - ISOC Area Project No. 38436703 APPENDIX G CONTAMINANT MASS CALCULATION Contaminant Mass Calculation Project: BP Terminal 4762 Prepared by: CJK Charlotte, North Carolina Checked by: JK Objective: Estimate the mass of contaminants in the (dissolved) groundwater phase and saturated adsorbed phase in targeted remediation area plume. Assumptions: 1. Saturated adsorbed mass is estimated at 10 times the dissolved mass 2. Concentration calculated is total of BTEX, MTBE, naphthalene, 1,2 DCA, and isopropyl ether concentrations 3. Plume area estimated as conservative area containing wells within December 2008 1 ug/L benzene contour area (Figure 10) 4. No LNAPL is present 5. Does not include contamination above the water table Groundwater and Adsorbed Phase Mass Calculation Area of 1 ug/I benzene isocontour (Figure 10). This area contains elevated concentrations in plume (i.e. all Plume Surface Area = 112,757 sq ft wells listed below). Porosity = 0.20 Conservative estimate (assumed previously to be 0.10 (CRA, 2004)) Average Water Table = 8 ft bls Approximate Bottom of Groundwater Plume = 60 ft bls Estimated extent based on detections in bedrock wells Average Concentration = 3.02 mg/L December 2008 groundwater sampling data, using average COC concentrations for DW-01, ES-01, ES-05DR, ES-05SR, MW-02, MW-05, MW-19, MW-21, MW-26, MW-36, MW-39, MW-41 MW-44, MW-49, MW-51, UW-08, UW-10, VE-02 (combined BTEX+MTBE+ Naphthalene+1,2-Dichloroethane+Isopropyl ether). Groundwater Volume (f13) = Surface Area (ft2) x Plume Depth (ft) x Porosity Groundwater Mass (kg) = Volume (fe) x Concentration (ug/L) x (28.3 L / ft') x (1 E-09 kg / ug) Average Groundwater Combined Average Petroleum Average Petroleum Average Petroleum Average Petroleum Groundwater Plume Plume Groundwater Groundwater Saturated Adsorbed Groundwater & Saturated Groundwater & Saturated Surface Area Volume Concentration Mass Mass Adsorbed Mass Adsorbed Mass (ft2) (ft3) (uglL) (kg) (kg) (kg) (Ib) 112,757 1,172,673 3,020 100 1,002 1,102 2,431 LNAPL Phase Mass Calculation LNAPL Volume (ft3) = Surface Area (ft2) x LNAPL Thickness (ft) x Porosity LNAPL Volume (gal) = LNAPL Volume (ft3) x 7.48 gal/ft3 LNAPL Mass (Ib) = LNAPL Volume (ft3) x Specific Gravity x 62.4 Ib/ft3 LNAPL Mass (kg) = LNAPL Mass (Ib) x 0.454 kg/Ib LNAPL LNAPL LNAPL LNAPL LNAPL Surface Area Volume Volume Mass Mass (ft2)' (ft3) (gal) (Ib) (kg) 0 0 0 0 0 Summary: Mass Estimate Groundwater Phase Saturated Adsorbed Phase LNAPL Phase Total Petroleum Mass 100 kg 1,002 kg 0 kg 221 Ib 2,210 Ib 0 Ib 1,102 kg 2,431 Ib URS P:\BP\Projects\TerminalsallgadDiwtrableM5.1 Draft -Interim Deliverables\CAP Modification Document 6-1-2012Vappendl o'App G Gals Estimated Petroleum Mass Groundwater APPENDIX H PILOT TEST SUMMARY REPORT August 30, 2011 Mr. Edward Leach DENR-DWQ Mooresville Regional Office 610 East Center Avenue, Suite 301 Mooresville, NC 28115 RE: 2010-2011 Pilot Study Summary — August 2011 BP/TransMontaigne Terminal — Paw Creek (Southeast Terminals) 7401 Old Mount Holly Road, Charlotte, North Carolina Groundwater Incident Numbers 06771, 15159, 15618, 17002, 17263, 17264, and 20622 Dear Mr. Leach: Enclosed is one copy of the 2010-2011 Pilot Study Summary — August 2011, for the BP Products North America, Inc. bulk -fuel storage terminal (formerly Southeast Terminals) in Charlotte, North Carolina. The report includes a summary of the biosparge and sulfate injection pilot studies and methods which occurred in 2010 and 2011. Groundwater sampling events to monitor sulfate injection is ongoing. The In -Situ Submerged Oxygen Curtain (ISOCTM) groundwater remediation system remained off during the biosparge study activities, operation resumed on March 1, 2011. If you have any questions or would like any additional information, please do not hesitate to call me at (919) 461-1423. Sincerely, URS Corporation — North Carolina Margaret M. Ness, P.G. Project Manager Enclosure cc: Greg Frisch, BP (enfos / electronic) Doug Hall, TransMontaigne (CD) Jim Sligh, TransMontaigne (2 hard copies, 1 CD) Aquifer Protection Section-UIC Staff, Raleigh (UIC Permit #WI0300148), 1636 Mail Service Road, Raleigh, NC 27699 URS project file 38436615 URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-46-1415 REPORT 2010-2011 PILOT STUDY SUMMARY AUGUST 2011 BP CHARLOTTE TERMINAL NO. 4762 (FORMERLY SOUTHEAST TERMINALS) 7401 OLD MOUNT HOLLY ROAD CHARLOTTE, NORTH CAROLINA NCDENR GROUNDWATER INCIDENT NUMBERS 6771, 15159, 15618, 17002, 17263, 17264, AND 20622 UIC PERMIT NO. WI0300148 Prepared for: Atlantic Richfield Company (ARCO) a BP Products of North America Inc. affiliated company 4850 E. 49th Street MBC-3 Room 155C Cuyahoga Heights, OH 44125 August 30, 2011 URS URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 Tel. 919.461.1100 URS Project 38436615 TITLE PAGE 2010-2011 PILOT STUDY SUMMARY AUGUST 2011 BP Charlotte Terminal No. 4762 (Formerly Southeast Terminals) 7401 Old Mount Holly Road. Charlotte, North Carolina NCDENR Groundwater Incident Numbers 6771, 15159, 15618, 17002, 17263, 17264, and 20622 Report Date: August 30, 2011 Responsible Party (RP): Atlantic Richfield Company (ARCO) a BP Products of North America Inc. affiliated company 4850 E. 49th Street MBC-3 Room 155C Cuyahoga Heights, OH 44125 Direct: 216 271-8740 Fax: 216 271-8242 Attn: Greg Frisch RP Consultant: TransMontaigne Product Services Inc. 200 Mansell Court East, Suite 600 Roswell, Georgia 30076 URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 919-461-1100 Project Manager: Margaret Ness, PG Registered Professional Jon Kucera, PE Supervision: This Report was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my thorough inquiry of the person or persons who manage the investigation, or those persons directly responsible for gathering the information, the information submitted to the best of my knowledge and belief, true, accurate, and complete. Jon Kucera, PE C6i NC License No. URS P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx ii TABLE OF CONTENTS Section 1 Introduction 1-1 Section 2 Background 2-1 2.1 Site Location and Description 2.2 Site Topographic and Geologic/Hydrogeologic Setting 2.2.1 Significant Changes in Lithology 2.3 Site Monitoring Well Network 2.4 Summary of Light Non -Aqueous Phase Liquid Occurrence 2.5 Site Release and Remediation History 2.5.1 2.5.2 2.5.3 2.5.4 2-1 2-1 2-1 2-2 2-2 2-2 Historical Site Release Incidents 2-2 Remediation Activities 2-2 Existing ISOC® System 2-2 Corrective Action Studies 2-3 Section 3 Groundwater Sampling 3-1 3.1 Groundwater Sampling and Analysis Methods 3-1 3.2 Groundwater Analysis Validation 3-1 Section 4 Pilot Study 4-1 4.1 Summary of Remedial Alternatives Pilot Study 4-1 4.2 Biosparge and Monitoring Well Installation 4-1 4.3 Baseline and Post Pilot Study Groundwater Analysis 4-2 4.4 Pilot Study .Implementation 4-2 4.4.1 Biosparge 4-2 4.4.2 Biosparge Results 4-3 4.4.3 Sulfate Injection 4-4 4.4.4 Sulfate Injection Results 4-5 Section 5 Conclusions and Recommendations 5-1 5.1 Conclusions 5-1 5.2 Recommendations 5-1 Section 6 References 6-1 P:\BP1Projects\Terminals'4762\5.0 Deliverables \5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx iii TABLE OF CONTENTS TABLES Table 1 Table 2A Table 2B Table 3 Table 4A Table 4B Table 5 Table 6 FIGURES Figure 1 Figure 2 Figure 3 Figure 4 Well Construction Details Biosparge Study Short Term Test - Area 2 Biosparge Study Short Term Test - Area 3 Biosparge Study — Area 3 Long Term Area 1 Injection Detail Area 2 Injection Detail VOC Analytical Summary — Injection Study MNA Analytical Summary — Injection Study Location Map Site Plan Biosparge Test Well Locations Injection Pilot Study Well Locations APPENDICES Appendix A Laboratory Analytical Reports (Baseline through July 21, 2011) Appendix B Biosparge Test Wells and Monitoring Well Boring Logs URS P:\BP\Projects\Terminals14762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx iv SECTIONONE Introduction On behalf of Atlantic Richfield Company (ARCO), a BP Products North America, Inc. (BP) affiliated company, URS Corporation — North Carolina (URS) presents this progress report of remedial pilot study activities conducted between June 2010 and July 2011 at the facility located at 7401 Old Mount Holly Road in Charlotte, North Carolina (formerly "Southeast Terminals"). The Site has been assigned Groundwater Incident Nos. 06771, 15159, 15618, 17002, 17263, 17264, and 20622 by the North Carolina Department of Environment and Natural Resources (NC DENR) in response to various historical petroleum product release incidents at the facility. The Site priority ranking is currently 100B due to the presence of potable water -supply wells within a 1,500 foot radius of the Site. The following pilot study activities have been completed at the Site through the delivery of this report: • Pilot Study groundwater sampling and analysis June 2010 through July 2011). • Biosparge Pilot Study (October 22, 2010 through January 17, 2011). • Sulfate Injection Pilot Study (May 16, 2011 through July 21, 2011). URSP:\BP\Projects\Terminals\476215.0 Deliverables\5.2 Final Deliverables\ Pilot Study\2010-2011 Pilot Study Summary.docx 1-1 SECTIONTWO Background 2.1 SITE LOCATION AND DESCRIPTION Maps showing the Site area and layout are provided as Figure 1 and Figure 2. The Site is located in the Paw Creek area of Charlotte, North Carolina, an area predominantly occupied by petroleum terminals and light industrial facilities. 2.2 SITE TOPOGRAPHIC AND GEOLOGIC/HYDROGEOLOGIC SETTING The Site is located in the Piedmont physiographic province, which is characterized by moderately level interstream areas separated by broad valleys. Bedrock in Charlotte, North Carolina is mapped within the Charlotte Belt lithologic division of the Piedmont, which includes mafic gneisses, amphibolites, metagabbros, and metavolcanic rocks. According to the Geologic Map of North Carolina (North Carolina Geological Survey, 1985), bedrock beneath the facility consists of metamorphosed quartz diorite or quartzite. Competent bedrock in the Piedmont province is typically overlain by variable thicknesses of saprolite and soil, collectively referred to as "overburden." Saprolite consists of rock that has been subject to chemical weathering, removing up to 60% of the rock mass by solution, but not affecting volume (Cleaves, 1974). Saprolite commonly retains relict structures from the parent bedrock. Thicknesses of the overburden in the Piedmont typically range from 10 to 75 feet, depending on rock composition and topographic setting (LeGrand, 1988). 2.2.1 Significant Changes in Lithology Based on Site boring logs, subsurface materials at the Site consist of soil and saprolite overburden, including silty/clayey sand, sandy clay/silt, and silt/clay, overlying weathered and competent bedrock. Bedrock, meeting the description of metamorphosed quartz diorite referenced above, has been encountered in Site borings at depths ranging from approximately 10 to 40 feet below grade and elevations ranging from approximately 729 to 774 feet above mean sea level (msl). Groundwater in the Piedmont province occurs in the overburden under unconfined (i.e., water table) conditions, and in the underlying bedrock under both unconfined and confined conditions. Groundwater in the overburden occurs within pore spaces of the unconsolidated medium, including relict bedrock structures (i.e., fractures, foliations, etc.). Due to the typical fine-grained nature and low permeability of saprolite, the formation is not usually utilized for groundwater production. Groundwater in the underlying bedrock occurs along zones of secondary porosity, such as fractures, foliations, solution voids, etc. Most water -supply wells in the Piedmont are completed in bedrock with surface casings extending through the overburden. URSP:\BP\Projects\Terminals\476215.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 2-1 SECTIONTWO Background 2.3 SITE MONITORING WELL NETWORK The locations of Site groundwater monitoring and remediation wells are shown in Figure 2. Site well construction details are listed in Table 1. Total depths of Site monitoring and remediation wells range from 7 to 110 feet below top of casings. Ten Site monitoring wells are completed in bedrock and one Site monitoring well is completed in saprolite directly above bedrock. The remaining Site monitoring wells are completed in the shallow overburden (i.e., water -table monitoring wells). 2.4 SUMMARY OF LIGHT NON -AQUEOUS PHASE LIQUID OCCURRENCE Light non -aqueous phase liquid (LNAPL) has been detected periodically in some Site monitoring wells. Inspection and replacement of the LNAPL-absorbent socks for select wells (ES-05SR, ES-25, ES-33, MW-12, MW-51, UW-10, and VE-02) is completed periodically. Refer to the December 2010 Semi Annual Groundwater Monitoring and Remediation Report for specific details. 2.5 SITE RELEASE AND REMEDIATION HISTORY 2.5.1 Historical Site Release Incidents Historical releases at the Site have included tank overfills, pipeline leaks, tank releases, dike leaks, a tanker truck release, and underground storage tank (UST) leaks discovered upon UST removal. Released products have included diesel fuel, kerosene, gasoline, virgin oil, and heating oil. A summary of past Site release incidents can be found in historical Site documents submitted to NCDENR. 2.5.2 Remediation Activities Remediation activities at the Site have included soil excavation, groundwater pump and treat, dual phase vapor extraction, and groundwater recovery and treatment through an interceptor trench. A permeable reactive barrier (PRB) was installed in February 2005 downgradient of Tank 118 in the eastern area of the Site. In -situ submerged oxygen curtain (ISOC®) units are currently installed in the northwestern area of the Site. Absorbent socks have historically and are currently being used to detect and recover LNAPL in select Site monitoring wells. 2.5.3 Existing ISOC® System The existing ISOC® system includes devices installed in six existing monitoring wells along the northwest terminal boundary (MW-02, MW-19, MW-36, MW-38, MW-39 and MW-41) that span the width of the current plume of elevated constituent of concern (COC) concentrations. The wells have an average spacing of approximately 20-feet perpendicular to the apparent direction of groundwater flow. The ISOC® devices are supplied oxygen from two, 200 cubic URSP:\BP\Projects\Terminals\476215.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 2-2 SECTIONTWO Background feet, oxygen cylinders located within a metal warehouse adjacent to the ISOC® wells. Oxygen feed lines (1/4-inch I.D. polyethylene tubing) are connected to the ISOC® devices through PVC conduit. Oxygen is injected in to the subsurface in each of the ISOC® wells under injection permit No. WI0300106 issued on December 31, 2007 by the NCDENR Division of Water Quality. Following startup of ISOC® system in November 2005, groundwater dissolved oxygen (DO) measurements have been measured in the ISOC wells and other surrounding monitoring wells on a routine basis. 2.5.4 Corrective Action Studies In October 2008, NCDENR issued a Notice of Regulatory Requirement (NORR) requiring BP to provide remediation system modification recommendations. Through additional correspondence between URS and NCDENR, a revised CAP to implement corrective action in the central plume area is to be issued. As part of CAP development, a pilot study plan of biosparge and sulfate injection was submitted and approved in 2010. Pilot Study scope and results are discussed in later sections of this report. P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 2-3 SECTIONTHREE Groundwater Sampling 3.1 GROUNDWATER SAMPLING AND ANALYSIS METHODS Groundwater sampling activities are conducted semi-annually at the Site. Sampling events are completed in June and December each year, in accordance with the NCDENR-approved August 2005 Site Groundwater Monitoring Plan, which include sampling the ISOC system monitoring wells and additional monitoring wells. Prior to collecting groundwater samples, depth to groundwater is measured in the Site monitoring wells using an oil/water interface probe. Following well gauging, groundwater samples are collected from the Site monitoring wells using the purge/sample method described as follows: 1. Temperature, pH, dissolved oxygen, and specific conductance measurements are collected in -situ prior to purging activities. 2. The monitoring wells are purged of three standing volumes of groundwater, or until dry, using a dedicated, disposable bailer and nylon rope. 3. The groundwater samples are collected using a dedicated, disposable bailer and nylon rope. The samples are immediately transferred to laboratory supplied containers and placed on ice in a cooler. Groundwater samples collected from the monitoring wells are transferred to pre -labeled, laboratory -prepared containers and promptly placed on ice in a cooler with a temperature and trip blank and submitted under chain of custody to Lancaster Laboratories located in Lancaster, Pennsylvania. Samples are analyzed for benzene, toluene, ethylbenzene, total xylenes (BTEX), methyl tert-butyl ether (MTBE), 1-2 dichloroethane (1, 2-DCA), isopropyl ether (IPE), and naphthalene by SW-846 Method 8260B or other EPA approved comparable method. A select number of wells are analyzed for inorganic parameters including: total calcium and total sodium by SW-846 Method 6010B, alkalinity by SM Method 2320B, hydrogen sulfide and total sulfide by SM Method 4500-S2F, methane, ethane, ethene (MEK) by RSK.175, orthophosphate by SM 4500EP, and nitrate and/or sulfate by EPA Method 300 as part of the Baseline and Post Pilot Study analysis discussed in this report. 3.2 GROUNDWATER ANALYSIS VALIDATION URS validates analytical results for the groundwater monitoring events performed at the Site. The data review is modeled after the USEPA Contract Laboratory Program National Functional Guidelines (NFG) for Superfund Organic Methods Data Review (EPA, June 2008) and USEPA Contract Laboratory Program NFG Inorganic Superfund Data Review (USEPA, January 2010). Qualitative and quantitative limitations associated with the analytical results are determined based on the results of specific quality control (QC) criteria. Accuracy is determined from the review of spike recoveries. Precision is based on the evaluation of laboratory and field duplicate URSP:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\ Pilot Study\2010-2011 Pilot Study Summary.docx 3-1 SECTIONTHREE Groundwater Sampling results. Representativeness is evaluated from the review of holding times and blank data. Sample results are qualified based on the results of the data review process. Qualified data are valid and usable for their intended purpose. A copy of the data validation report is available upon request. Laboratory analytical reports for Pilot Study groundwater monitoring on January 17, June 23, and July 21, 2011 are included in Appendix A. URSP:\BP\Projects\Terminals1476215.0 Deliverables15.2 Final Deliverables\Pilot Study12010-2011 Pilot Study Summary.docx 3-2 SECTIONFOUR Pilot Study 4.1 SUMMARY OF REMEDIAL ALTERNATIVES PILOT STUDY This Pilot Study is the result of two separate pilot studies in response to a Notice of Regulatory Requirements (NORR) letter from the NCDENR. BP/URS submitted a proposed Pilot Study Plan dated December 15, 2009, and received approval by NCDENR to implement the pilot studies (March 5, 2010). The NCDENR NORR requested a more proactive approach to address areas of high concentrations of dissolved hydrocarbons at the Site, specifically the area in the vicinity of the ISOC system. The BP and URS team completed a remedial alternatives analysis which eventually proposed performance of a pilot test utilizing biosparging and injection technologies for comparison. Submitted in this section of the report is a summary of remedial pilot study activities completed at the Site from June 2010 through July 2011. 4.2 BIOSPARGE AND MONITORING WELL INSTALLATION Three biosparge test wells (AS-04, AS-05, and AS-06) and four monitoring wells (MW-65, MW- 66, MW-67, and MW-68) were installed using hollow stemmed auger drilling methods from August 25 through August 30, 2010. An additional monitoring well, MW-69, was installed on May 23, 2011 for down gradient groundwater monitoring for sulfate injection analysis. Boring logs for the biosparge test wells and monitoring wells are included as Appendix B. URS personnel contacted NC One Ca11 for location of public utilities. Taylor Wiseman & Taylor (TWT), a private utility locate contractor, was onsite prior to drilling to mark the Site for any private utilities near the well locations. In addition to utility locating, TWT cleared the monitoring wells using air knife to a depth of 6.5 ft bgs. Mad Dawg Inc. was subcontracted to perform drilling tasks as outlined below. The biosparge wells and monitoring wells were installed at the locations shown on Figure 3. AS-04 and AS-05 were advanced to a depth of 39 ft bgs and AS-06 was advanced to a depth of 26 ft bgs. A 5-foot length of 0.010-inch continuous slot screen, 2-inch ID, Schedule 40 PVC and 2-inch ID, Schedule 40 PVC riser was placed in the borings. The type II monitoring wells (MW-65, MW-66, MW-67, MW-68, and MW-69) were completed to depths of 20, 15, 15, 20, and 17 ft bgs, respectively. MW-65 and MW-68 used a 15-foot, 0.010-inch machine -slotted, 2-inch ID, Schedule 40 PVC riser, while MW-66, MW-67, and MW-69 used a 10-foot, 0.010- inch machine -slotted, 2-inch ID, Schedule 40 PVC well screen and 2-inch ID, Schedule 40 PVC riser. The annular space around the well screen was filled with graded sand. A minimum 1-foot thickness of bentonite was placed over the sand and hydrated. The remaining annular space was filled with grout to the ground surface. A well pad and protective casing was also installed. The wells were completed flush with the ground surface. Monitoring well MW-69 was completed as a stick-up, finished approximately 3 ft. above the ground surface with protective casing. URNS P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 4-1 SECTIONFOUR Pilot Study Following installation, the wells were developed to ensure proper hydraulic connection between the well and surrounding geologic conditions. Development activities were terminated once the water produced was essentially clear and free of suspended sediment or until conditions remain unchanged. 4.3 BASELINE AND POST PILOT STUDYGROUNDWATER ANALYSIS Groundwater sampling events were conducted in June 2010, August 2010, and May 2011 to obtain baseline information on particular constituents in order to make accurate comparisons upon completion of the biosparge and injection pilot studies. Baseline VOC analysis for biosparge pilot study occurred in June 2010 for monitoring wells MW-19, 36, 38, 39, 41, 49, and 50 in Area 3. Monitoring wells in Area 2 were sampled for baseline biosparge VOC analysis as part of the June 2010 Semi-annual Groundwater Sampling event and newly installed monitoring wells MW-65, 66, 67, and 68 were sampled in August 2010. Groundwater samples were collected in June 2010 from monitoring wells MW-05, MW-21, MW-26, UW-06, and UW-08. Monitoring well MW-69 was installed for an additional down gradient monitoring point for injection analysis in discussion with NCDENR Division of Water Quality for the Underground Injection Control (UIC) permit. Installed on May 23, 2011, MW-69 was sampled to obtain baseline data on May 24, 2011. Since completion of the Biosparge and Sulfate Injection Pilot Studies, several groundwater sampling events have been performed to analyze the effectiveness of the remedial alternatives. Pilot study sampling events were conducted on January 17, June 8, June 23, and July 21, 2011. Pilot study sampling will continue per the monitoring schedule included in the UIC Permit Application (UIC Permit NO. WI0300148). 4.4 PILOT STUDY IMPLEMENTATION 4.4.1 Biosparge Following the installation of air sparge and monitoring wells, biosparge pilot study was performed from October 25, 2010 to January 17, 2011. The sparge pilot test was conducted in two different areas of the site, shown in Figure 3; Area 2 and Area 3. One air sparge (AS) well is located in Area 2 (AS-06) and two AS wells are located in Area 3 (AS-04 and AS-05). An attempt to install an additional sparge well and monitoring wells in an area designated as "Area 1" was unsuccessful due to shallow auger refusal in several attempts to install wells. Biosparge testing consisted of a "short" term pilot study of less than one week in Areas 2 and 3. Air was delivered via tubing to air sparge wells at an average air flow rate of three standard cubic feet per minute (scfm) with and average 25 pounds per square inch (psi) recorded at the AS well head for Area 2. The average air flow rate and pressure recorded at the AS well head for Area 3 was 2.4 scfm and 15 psi, respectively. Depth to water (DTW), dissolved oxygen (DO), volatile organic compounds (VOCs), carbon dioxide (CO2) and methane were recorded using field instruments hourly, then daily in select wells surrounding the air sparge wells. Secondary wells URSP:\BP1Projects\Terminals\4762\5.0 Deliverables \5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 4-2 SECTIONFOUR Pilot Study located at a further distance from the air sparge wells were measured at a less frequent basis. Field measurements of the short term tests are included in Tables 2A and 2B. Testing started October 25, 2010 and ended on October 29, 2010 in Area 2. Testing in Area 3, which is located in the vicinity of the ISOC system, began on November 2, 2010 through November 5, 2010. The long-term biosparge pilot study operated from November 9, 2010 through January 17, 2011 to monitor the effects of biosparging in relation to analytical testing. Table 3 shows the analytical results before and after biosparge pilot testing. The ISOC system was turned off in April 2010 to allow the area to acclimate to surrounding conditions for the pilot test and June semi-annual sampling event for baseline analysis. Following the biosparge pilot study and ISOC system repairs, operation of the ISOC resumed on March 1, 2011. 4.4.2 Biosparge Results Area 2 Short Term Pilot Test (AS-06) • Field VOC concentrations increase in closest monitoring wells MW-66 and MW-67 • CO2 concentrations decreased in closest wells MW-66, MW-67 and UW-08 • DO measurements were highest on the initial day of the pilot study then leveling off and remaining fairly constant at lower results for the remainder of the test (MW-66, MW-67, UW-04, and UW-08) Area 3 Short and Long Term Pilot Tests (AS-05 and AS-05) • Field VOC concentrations increase in the eight wells surrounding the sparge area • CO2 increased in several wells. CO2 readings increased in concentrations as the pilot study carried into the long term test. Air flow remained constant between short and long term tests. • DO measurements were highest during the initial days of the pilot test. • Methane analysis increased in several wells as the test continued in the second and third weeks. Analytical Findings (Area 3 Long Term Plot Test) • MTBE concentrations increased in MW-19 post pilot study. MW-19 is an ISOC well and may show effects from ISOC influence when operating. • MW-36 had increased analytical results after the pilot study for all analytes, especially ethylbenzene and naphthalene. As described above, URS collected field parameters from select Site monitoring wells as part of the short and long term biosparge test. Natural attenuation is microbially driven through oxygen reducing reactions. To evaluate the success of natural attenuation in the subsurface, three components are typically evaluated: P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 4-3 SECTIONFOUR Pilot Study • The presence of organic carbon as a microbial food source (hydrocarbons in this case); • Electron acceptors to provide energy transfer pathways; and • The presence of metabolic end products, which illustrates degradation. Dissolved Oxygen DO is an important parameter to monitor because biodegradation of hydrocarbons occurs most rapidly under aerobic conditions. In general, DO concentrations of approximately 2 mg/L or greater indicate the presence of sufficient oxygen to support aerobic biodegradation, and levels below 2 mg/L would be considered facultative and/or anaerobic. As shown on Tables 2A and 2B, DO is present across the Site, and ranges from 0.55 to 6.63 mg/L. DO concentrations are generally lower in the impacted wells, and greater in the upgradient and sidegradient wells. These data suggest that oxygen is being consumed for biodegradation in the subsurface under aerobic conditions. Methane Methanogenesis is the process of degrading hydrocarbons with the end product being methane gas (CH4) and carbon dioxide (CO2). The presence of methane suggests that methanogenesis has occurred (or is occurring) in the impacted area of the Site. As shown on Tables 2A and 2B, methane analysis increased in several wells, particularly during the Long Term testing in Area 3. 4.4.3 Sulfate Injection Injection work began on May 16, 2011 and continued through May 23, 2011. The sulfate injection pilot study consisted of the application of an Epsom salt and sodium bromide solution to the subsurface utilizing an injection system delivered by GeoprobeTM. Each batch of sulfate solution consisted of 757 grams of Epsom salt and 378.5 grams of sodium bromide, mixed into solution in 100 gallons of potable water. GeoprobeTM rods, fitted with an injection tip that opens at 100 psi, were advanced to a select depth where the solution was pumped to subsurface via the hollow stemmed rods plumbed and fitted to gasoline powered diaphragm pumps which were pressured to approximately 100 psi to activate the injection tool. Some injections occurred simultaneously at two locations, e.g.) Al-I3 and Al-I5. Care was taken during simultaneous injecting to select locations that were at as great of distances apart as possible to prevent communication between the two active soil borings. The sulfate solution was injected at each depth interval until the prescribed amount was injected or until friction loss to the ground surface was realized. Injections were completed in two separate locations, referred to as Area 1 and Area 2, shown in Figure 4. Area 1, centered around monitoring well MW-65, received injections at 10 soil boring locations spaced evenly within a 20 ft. by 20 ft. area and labeled Al-I1 (Area 1- Injection 1) through Al-I10. Similarly, a 20 ft. by 20 ft. area identified as Area 2 was established P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study12010-2011 Pilot Study Summary.docx 4-4 SECTIONFOUR Pilot Study around monitoring well MW-68 and injected with the sulfate solution at 10 locations labeled A2-I1 through A2-I10. Injection details are presented for Area 1 and Area 2 in Tables 4a and 4b, respectively. Based on the UIC permit application dated June 11, 2010 and presented in Appendix C of this report, each injection point had the potential to receive a maximum of 400 gallons of the sulfate solution or 4,000 gallons total per area. Area 1 received a total of 1,640 gallons of the sulfate solution, while total injections for Area 2 totaled 2,700 gallons. Injection intervals ranged from 10 ft. below ground surface (bgs) to 24 ft. bgs. Soil borings were terminated at refusal in very tight soils. Having loose soils from 0 — 6.5 ft. bgs, due to the required 6.5 ft. client hand dig requirement at each boring location, injections did not begin until 10 ft. bgs. Refer to Tables 4A and 4B for specific injection details. After the injection event groundwater samples were collected from select wells in Areas 1 and 2 for laboratory analysis of VOC analytes along with MNA parameters. Sampling events of selected wells were conducted on June 8, June 23, and July 21, 2011. VOC analysis and MNA analysis results are presented on Tables 5 and 6, respectively. Laboratory Reports are included in Appendix A. 4.4.4 Sulfate Injection Results • Area 1 increased in BTEX and Naphthalene; however concentrations were also seen historically at these levels. • Area 2 increased in several wells for BTEX but no discernible trend is seen. • No discernible trend is observed for DO, pH or specific conductance. • Bromide, the injection tracer, was only detected in the area of injection (wells MW-61 in Area 1 and MW-68 in Area 2). Bromide was not detected outside the injection area. Field groundwater parameter measurements that were recorded subsequent to sampling the monitoring wells are presented in Table 6. The pH, specific conductance, temperature, DO ranges for the monitoring wells were as follows: • pH ranged from 4.41 to 8.95 standard units (SU), • Specific conductance ranged from 0.039 to 0.900 millisiemens per centimeter (mS/cm), • Temperature ranged from 15.53 to 28.31 degrees Celsius (°C), • DO ranged from 0.13 to 8.69 milligrams per liter (mg/L), Nitrate and sulfate serve as electron acceptors in the degradation process. Nitrate is reduced to nitrite, and sulfate to sulfide, while the hydrocarbons are oxidized to carbon dioxide, methane, and water. Typically, these degradation processes will occur in sequence with nitrate used first, then iron is used until only sulfate is available, then sulfate reduction takes over. This would then be followed by methanogenesis. P:\BP\Projects\Terminals14762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 4-5 SECTIONFOUR Pilot Study Nitrate was not detected during this sampling event. Low nitrate levels could indicate that degradation processes have depleted the nitrate or there is little available nitrate. Ferrous iron was detected at variable concentrations, indicating that iron reduction may have occurred at the Site. Sulfate concentrations across the Site indicate that very little sulfate is present in the area of greatest impacts, but historical data indicate that there is sulfate available downgradient of the impacted area. This may indicate that sulfate reduction has already occurred in the impacted area. Methane is generated as a byproduct of anaerobic hydrocarbon biodegradation. Nitrates presence would be used for biodegradation before methanogenesis could occur. An increase in dissolved methane concentrations, as groundwater travels downgradient, would be indicative of natural biodegradation occurring. Methane is present in groundwater across the Site. Methane concentrations are greatest in the center and downgradient of the impacted area. Methane concentrations were low or not detected in sidegradient wells. This indicates that methanogenesis has occurred at the Site. DO concentrations across the Site show limited potential for aerobic degradation. Nitrate is not available for the degradation process. Low sulfate concentrations in the impacted area suggest that sulfate may have been reduced in the impacted area. The presence of methane suggests that methanogenesis has occurred (or is occurring) in the impacted area of the Site. URSP:\BP\Projects\Terminals 4762\5.0 Deliverables15.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 4-6 SECTIONFIVE Conclusions and Recommendations 5.1 CONCLUSIONS • VOC analysis for the biosparge testing showed an increase in concentrations from the baseline sampling to sampling conducted in December 2010 and January 2011. Increased concentrations in Area 3 were likely caused by shutdown of the ISOC system during pilot study biosparge activities. • Analytical results showed that VOCs in monitoring wells MW-65, MW-21, and MW- 26, wells in the immediate areas of the sulfate injections, have decreased while inorganic concentrations have generally increased or remained relatively unchanged from baseline results through July 21, 2011 results. Monitoring well MW-68, which is within the boundary of the Area 2 injection, showed an increase in VOCs. • Analytical results from June 8, 2011 sampling showed the greatest difference from the baseline sample results. Subsequent sampling events show results moving closer to baseline reporting. • Bromide was reported in monitoring wells MW-65 and MW-68 during sampling conducted following injection events. All baseline samples and pilot study samples were non -detect for bromide in all sampled wells except pilot study samples of MW- 65 and MW-68, which are located within the injection areas. Correlating concentrations of sulfate were also detected in monitoring wells MW-65 and MW-68 following injection events. Initial sulfate concentrations were lower than expected following the injection events in both Areas 1 and 2. The sulfate concentrations also appeared to decrease steadily over the post -injection sampling events in correlation with the decreasing bromide concentrations indicating that physical processes present in the aquifer are more dominant than biological processes and calls into question the efficacy of the sulfate injection technology. • The long term biosparge test appeared to indicate that VOC concentration reduction is possible over time, however further sampling and we believe more data analysis would be necessary to validate this trend. 5.2 RECOMMENDATIONS URS will continue with Pilot Study sampling per the monitoring schedule submitted as part of the Pilot Plan. Recommendations will be provided following review of data at the conclusion of Pilot Study sampling activities. Upon review of all analytical data URS will make recommendations for future remedial activities as part of the December semi-annual groundwater sampling event, in accordance with the NCDENR-approved August 2005 Site Groundwater Monitoring Plan. UP:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study12010-2011 Pilot Study Summary.docx 5-1 SECTION SIX References North Carolina Geological Survey, 1985, Geologic Map of North Carolina: 1:500,000. Cleaves, E. T., 1974, Petrologic and Chemical Investigation of Chemical Weathering in Mafic Rocks, Eastern Piedmont of Maryland: Maryland Geological Survey, Report of Investigation, v. 25, 28 p. LeGrand, H. E., 1988, Region 21, Piedmont and Blue Ridge, in Back, W., Rosenshein, J. S., and Seaber, P. R., eds., Hydrogeology: Boulder, Colorado, Geological Society of America, The Geology of North America, v. 0-2. USEPA, 2008 and USEPA, 2010, USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review and USEPA CLP NFG Inorganic Superfund Data Review. URS, 2011. Semi -Annual Groundwater Monitoring and Remediation Report: December 2010, URS Corporation —North Carolina, February 28, 2011. URSP:\BP\Projects\Terminals\4762\5.0 Deliverables\5.2 Final Deliverables\Pilot Study\2010-2011 Pilot Study Summary.docx 6-1 TABLES Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No: Northing (Feet) , Easting (Feet) Top -of Casing Elevation, �{Feet Realtive•to -- 4. _ Screen = Interval « (Feet Below Ground ' ) ` Total Depth - : (Feet Below < Ground) Approximate Date = Installed: - Geologic Zone Monitored Parcel Number AS01 N/A N/A 759.69 13.0 - 15.5 15.5 06/02 N/A 05724302 AS02 N/A N/A 784.98 23.5 - 25.0 25.0 06/02 05724302 ASO4 N/A N/A 785.36 34.0 - 39.0 39.0 08/10 AS05 N/A N/A 785.45 34.0 - 39.0 39.0 08/10 AS06 N/A N/A 780.66 21.0 - 26.0 , 26.0 08/10 DPEW01 561296.8174 1423986.6534 763.19 3.0 - 10.5 10.5 09/97 N/A 05724301 DPEW02 561602.7889 1423835.0786 781.18 4.0 - 14.0 14.0 09/97 N/A 05724301 DW01 561586.0405 1423656.5762 784.12 52.0 - 57.0 57.0 05/92 Bedrock 05724301 DW01A 561582.9012 1423696.9568 782.50 14.0 - 19.0 19.0 N/A N/A 05724301 DW02 561352.6126 1423618.9074 776.17 24.0 - 29.0 29.0 05/92 Bedrock 05724301 DW03 N/A N/A 762.28 45.0 - 50.0 50.0 05/92 Bedrock 05724301 DW04 561216.8708 1423328.0896 769.29 4.5 - 9.5 9.5 N/A 05724302 DW05 561844.7793 1423435.7268 786.60 49.0 - 54.0 54.0 N/A N/A 05724302 DW06 561840.6986 1423913.5373 791.69 41.0 - 46.0 46.0 N/A N/A 05724301 DW08 561115.2978 1423948.3161 759.86 37.5 - 42.5 42.5 04/97 Bedrock 05724302 DW09 N/A N/A 760.09 44.0 - 49.0 49.0 12/99 Bedrock 05724302 DW10 N/A N/A N/A N/A N/A N/A N/A N/A ES01 561872.3080 1423594.5933 791.38 18.0 - 28.0 28.0 01/93 Weathered Granite 05724302 ES02 561225.4682 1423602.1330 770.32 4.0 - 44.0 44.0 03/93 05724301 ES03 561467.3861 1423617.7245 781.26 8.0 - 23.0 23.0 03/93 Saprolite 05724301 ESO4 561892.5678 1423594.9569 791.79 16.0 - 46.0 46.0 03/93 05724302 ES05 561733.8004 1423495.1581 785.77 10.0 - 45.0 45.0 03/93 05724302 ESO5SR N/A N/A 786.67 10.0 - 30.0 30.0 05/05 Saprolite 05724302 ESO5DR N/A N/A 786.79 45.0 - 55.0 55.0 05/05 Bedrock 05724302 ES06 561873.1015 1423452.3497 789.94 5.0 - 40.0 40.0 03/93 05724302 ES07 561852.3894 1423797.3489 791.23 2.0 - 22.0 22.0 03/93 Saprolite 05724301 ESO8 561680.6126 1423873.7317 790.56 10.0 - 35.0 35.0 03/93 05724301 ES08SR" N/A N/A 792.83 10.0 - 25.0 25.0 05/05 N/A N/A ES08DR" N/A N/A 792.70 47.0 - 57.0 57.0 05/05 N/A N/A ES09 561621.2498 1423841.3317 788.04 5.0 - 45.0 45.0 03/93 05724301 ES10 561795.5151 1423598.5891 791.36 3.5 - 21.0 21.0 03/93 Sandy Clay 05724302 ES11 561641.1089 1423484.5621 785.33 5.0 - 25.0 25.0 08/93 Silty Clay 05724302 ES12 561755.9851 1423826.6505 791.76 7.0 - 22.0 22.0 08/93 Saprolite 05724301 ES13 561824.1833 1423875.9617 791.83 5.0 - 25.0 25.0 08/93 Clayey Sand 05724301 ES14 561691.2600 1423926.5230 790.70 3.0 - 23.0 23.0 08/93 Silty Clay 05724301 ES15 561723.2821 1423769.0074 790.25 8.0 - 18.0 18.0 N/A N/A 05724301 ES16 561641.5922 1423982.1524 790.25 5.0 - 25.0 25.0 01/94 05724301 ES17 561938.0508 1423551.3382 791.47 5.0 - 20.0 20.0 01/94 Silty Clay 05724302 ES18 561737.3383 1423401.7600 786.31 4.0 - 14.0 14.0 01/94 Silty Clay 05724302 ES19" 561739.5557 1424051.3416 795.13 6.0 - 26.0 26.0 01/94 Silty Clay 05724301 ES20 561902.7571 1423416.4770 787.36 6.0 - 21.0 21.0 N/A Silty Clay 05724302 ES21` 561807.7732 1424136.5114 792.59 5.0 - 15.0 15.0 02/94 N/A 05724301 ES22 N/A N/A N/A N/A N/A N/A ES23 561245.9817 1424171.6421 764.38 4.0 - 9.0 9.0 N/A N/A 05724301 ES24 N/A N/A N/A N/A N/A N/A ES25 560892.4859 1423292.5796 754.69 N/A 24.0 N/A N/A 05724302 ES26 561460.6103 1423752.7862 777.81 29.0 - 39.0 39.0 05/96 Saprolite 05724301 ES28 561440.0360 1423683.4472 774.01 12.0 - 22.0 22.0 05/96 Saprolite 05724301 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\Active Remediation Monitoring Report\Tables\Table 1 Update July 2011 (MW-69)\T1 Page 1 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No; Northing (Feet) Easting (Fee;) Top -of- Casing Elevation {Feet Realtive to -'NGVDI Screen - Interval =� .(Feet Below Ground); Total Depth (Feet .Below Ground) Approximate Date Installed Geologic,Zone Monitored Parcel ` Number ES29 561875.0050 1423798.4872 791.37 N/A 25.0 N/A N/A 05724301 ES30 561289.7215 1423767.9827 768.21 5.0 - 15.0 15.0 N/A N/A 05724301 ES31 561463.4581 1423920.8296 779.22 6.0 - 16.0 16.0 N/A N/A 05724301 ES32 561225.0002 1423996.5307 762.94 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES33 561288.4598 1424006.1705 763.33 4.0 - 14.0 14.0 10/96 Silty Sand 05724301 ES34 561510.6321 1424372.9606 777.18 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES35 561494.7313 1424106.5233 774.74 2.5 - 15.0 15.0 10/96 Silty Sand -Saprolite 05724301 ES36' 561568.9915 1423805.4128 782.83 15.0 - 25.0 25.0 10/96 N/A 05724301 ES37 561396.2246 1423611.6336 777.88 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES38 561503.0391 1423621.9763 782.60 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES39 561565.2874 1424118.7755 781.88 4.0 - 9.0 9.0 02/97 Sandy Clay 05724301 ES40 561449.2345 1424347.7368 779.47 1.0 - 11.0 11.0 02/97 Sandy Clay 05724301 ES41 561569.1222 1424343.6774 784.60 2.0 - 12.0 12.0 02/97 Silty Sand- Saprolite 05724301 ES42 561364.3171 1424047.1854 774.77 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES43 561358.1419 1424262.8673 777.18 8.0 - 18.0 18.0 02/97 Silty Sand - Saprolite 05724301 ES44 561604.1033 1424189.8355 790.22 8.0 - 18.0 18.0 04/97 Silty Sand 05724301 MP01 561288.8127 1423998.0869 763.10 2.5 - 12.5 12.5 09/97 05724301 MP02 561301.5317 1423976.0820 763.19 3.0 - 13.0 13.0 09/97 05724301 MP03 561300.1281 1423989.2201 763.10 2.0 - 12.0 12.0 09/97 05724301 MP04' 561603.9098 1423830.9426 781.28 1.5 - 14.0 14.0 09/97 N/A 05724301 MP05 __ 5.61578.0162 _ 1423828.7206 779.96 2.0 - 14.5 14.5 09/97 05724301 MPO6 N/A N/A 759.42 2.5 - 12.5 12.5 06/02 N/A 05724302 MW01 N/A N/A N/A N/A N/A 01/85 MWO2 561487.2640 1423357.7902 781.37 5.5 - 25.0 25.0 01/85 Silty Sand - Weathered Bedrock 05724302 MW03W 561207.3791 1423326.9060 769.21 N/A 12.0 N/A N/A 05724302 MW04 N/A N/A N/A 3.6 - 18.0 18.0 10/84 MWO4R 560935.1424 1423590.1046 754.94 2.0 - 11.0 11.0 02/98 Saprolite 05724302 MW05 561625.8587 1423574.6324 786.65 4.0 - 14.0 14.0 01/85 Silty Sand 05724302 MW06 N/A N/A N/A 4.0 - 9.0 9.0 10/84 MW06R 560933.5686 1423672.4778 755.29 2.0 - 7.0 7.0 02/98 Saprolite 05724302 MW07 561354.2347 1423341.1936 774.36 2.0 - 19.5 19.5 03/85 Saprolite 05724302 MW08 561427.0882 1423348.3463 777.69 2.0 - 12.0 12.0 03/85 Saprolite 05724302 MWO9 561546.8653 1423389.3473 784.65 5.0 - 20.0 20.0 03/85 05724302 MW10 561224.7864 1423594.373E N/A N/A N/A 03/85 MW11 N/A N/A N/A N/A N/A 03/85 MW12 561719.8840 1423618.9475 786.16 1.0 - 21.0 21.0 03/85 Saprolite 05724301 MW13 561676.7002 1423472.4878 N/A N/A N/A 03/85 MW14 N/A N/A N/A 1.0 - 15.6 15.7 02/85 MW14R 560891.2195 1423346.8273 756.41 2.5 - 15.0 15.0 02/98 Saprolite 05724302 MW15 N/A N/A N/A N/A N/A 03/85 MW16 561747.3621 1423577.1715 787.27 2.0 - 16.0 16.0 10/85 Saprolite 05724302 MW17 N/A N/A N/A N/A N/A 10/85 MW18' N/A N/A 780.90 2.5 - 22.5 22.5 10/85 MW19 561514.7100 1423363.7049 782.64 2.0 - 21.0 21.0 10/85 Saprolite 05724302 MW20 561703.5305 1423608.1548 787.34 10.0 - 25.0 25.0 10/85 Saprolite 05724302 MW21 561675.2283 1423607.2603 785.76 6.0 - 20.0 20.0 10/85 Saprolite 05724302 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\Active Remediation Monitoring Report\Tables\Table 1 Update July 2011 (MW-69)\T1 Page 2 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Noy Northing (Feet} Easttng (Feet Top -of- Casing Elevation (Feel Reactive to NGVOI Screen` Interval (Feet Below Ground) Total Depth: (Feet' Betoty, Ground) Approximate Date' , Installed Geatoglc,Zone Monitored Parcel ;Number �< < MW22 N/A N/A N/A N/A N/A 10/85 MW23 N/A N/A N/A N/A N/A 10/85 MW24 N/A N/A N/A N/A N/A 10/85 MW25 N/A N/A N/A N/A N/A 10/85 MW26 561705.2878 1423572.6623 785.38 5.0 - 20.0 20.0 10/85 Saprolite 05724302 MW27 561726.9164 1423606.3704 786.93 4.0 - 14.0 14.0 10/85 Saprolite 05724302 MW28 N/A N/A N/A 3.5 - 23.5 23.5 12/85 MW29 N/A N/A N/A 3.7 - 17.7 20.0 12/85 MW30 N/A N/A N/A 4.4 - 19.4 20.0 12/85 MW31 N/A N/A N/A 4.2 - 19.2 20.0 12/85 MW32 N/A N/A N/A 2.1 - 22.1 24.0 12/85 MW33 N/A N/A N/A 4.6 - 19.6 20.0 12/85 MW34 N/A N/A N/A 3.8 - 18.8 19.0 12/85 MW35 N/A N/A N/A 4.0 - 19.0 19.0 12/85 MW36 561526.4378 1423389.4123 785.94 5.0 - 25.0 25.0 12/85 Sandy Silt - Silty Sand 05724302 MW37 561566.9736 1423430.5503 785.17 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW38 561582.4723 1423394.7559 785.54 5.0 - 25.0 25.0 12/85 Sandy Clayey Silt 05724302 MW39 561609.9127 1423420.9725 785.28 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW40 561644.0901 1423444.7051 N/A 4.0 - 24.0 24.0 12/85 MW41 561637.3588 1423398.8937 785.64 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW42 561606.8920 1423477.4229 785.95 5.0 - 25.0 25.0 12/85 Silty Sand 05724302 MW43 561572.0617 1423568.5897 788.36 4.0 - 24.0 24.0 12/85 Silty Sand 05724302 MW44 561573.8919 1423463.5270 785.77 3.5 - 26.0 26.0 12/85 Sandy Silt 05724302 MW45 561539.1703 1423432.3766 786.91 3.0 - 28.0 28.0 12/85 Sandy Silt 05724302 MW46 N/A N/A N/A 6.3 - 16.3 16.5 01/86 MW47 561546.0782 1423573.4010 788.05 7.0 - 17.0 17.0 01/86 Sandy Clayey Silt 05724302 MW48 561560.3416 1423606.0845 788.19 2.5 - 15.0 15.0 01/86 Sandy Silt 05724301 MW49 561553.2264 1423361.8991 784.17 5.0 - 19.5 19.5 01/86 Sandy Silt 05724302 MW50 561511.9326 1423433.2840 783.50 5.0 - 25.0 25.0 02/86 Sandy Clayey Silt 05724302 MW51 561576.7167 1423524.7096 786.41 8.0 - 18.0 18.0 12/86 Clayey Sandy Silt 05724302 MW52 N/A N/A N/A N/A N/A 10/86 MW53 N/A N/A N/A N/A N/A 10/86 MW54 N/A N/A N/A N/A N/A 10/86 MW55 N/A N/A N/A N/A N/A 10/86 MW56 N/A N/A N/A N/A N/A 10/86 MW57 N/A N/A N/A N/A N/A 10/86 MW58 N/A N/A N/A N/A N/A 10/86 MW59 N/A N/A N/A N/A N/A 10/86 MW60 N/A N/A N/A N/A N/A 10/86 MW61 N/A N/A N/A N/A N/A 10/86 MW62 N/A N/A N/A N/A N/A 10/86 MW-65 N/A N/A 785.72 5.0 - 20.0 20.0 08/10 P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\Active Remediation Monitoring Report\Tables\Table I Update July 2011 (MW-69)\TI Page 3 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No Northing : _ (Feet) Easting (Feet) Top -of- Casing Elevation (Feet Reaitive to NGVDI Screen Interval (Feet Below Ground) Total Depth (Feet, . Below Ground) Apprortmate Date -, Installed Geologic Zone Monitored F- Parcel Number MW-66 N/A N/A 781.04 5.0 - 15.0 15.0 08/10 MW-67 N/A N/A 780.44 5.0 - 15.0 15.0 08/10 MW-68 N/A N/A 782.47 5.0 - 20.0 20.0 08/10 MW-69 N/A N/A 774.72 7.0 17.0 17.0 05/11 Sandy Silt PMW01 561124.4362 1424041.9674 761.06 5.0 - 15.0 15.0 06/92 Sandy Silt 05724302 PMWO2 561125.5177 1423964.5881 760.76 6.0 - 16.0 16.0 06/92 Sandy Silt Saprolite 05724302 PMWO3 561128.1760 1423878.0757 758.52 8.0 - 18.0 18.0 06/92 Sandy Silt Saprolite 05724302 PMWO4 560675.8867 1423430.5786 750.27 11.0 - 21.0 21.0 06/92 Sand Silt 05723114 PMWO5 560662.9922 1423502.4158 743.41 10.0 - 20.0 20.0 06/92 Sandy Silt Saprolite 05723114 PMWO6 561036.5314 1423856.2959 754.27 2.0 - 7.0 7.0 08/93 Silty Clay 05724302 PMWO7 561019.1837 1423982.5768 753.66 3.0 - 8.0 8.0 08/93 Silty Clay 05724302 PMWO8 561140.6727 1424080.3010 760.98 4.0 - 9.0 9.0 08/93 Silty Clay 05724302 PMWO9 560989.1019 1423862.8722 750.93 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW10 560846.3905 1423724.5687 746.86 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW11 560579.1482 1423436.2214 746.42 N/A 20.0 N/A N/A 05723114 PMW12 560394.9714 1423299.1239 732.48 N/A 12.5 N/A N/A 05723114 RW01 561092.3515 1423700.3608 N/A N/A N/A 05/86 RWO2 561590.5007 1423420.7633 784.71 6.0 - 26.0 26.0 05/86 Sandy Silt - Silty Sand 05724302 RWO3 561720.1317 1423614.0215 788.20 2.0 - 28.5 28.5 05/86 Sandy Silt 05724301 T01 (trench) 561572.6969 1423690.8304 785.15 N/A 17.0 N/A N/A 05724301 T01A 561347.4489 1423879.9408 765.31 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 T02 (trench) 561558.4972 1423768.6401 783.08 N/A 22.0 N/A N/A 05724301 TO2A 561192.7742 1423857.4115 761.77 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 UW01* 561589.3852 1423826.6607 781.23 1.0 - 16.0 16.0 08/91 N/A 05724301 UW02 561606.2226 1423647.4684 785.44 3.0 - 18.0 18.0 08/91 Saprolite 05724301 UW03 561623.4532 1423644.3421 785.50 2.5 - 17.5 17.5 08/91 05724301 UW04 561649.6681 1423753.4841 787.59 5.0 - 20.0 20.0 09/91 Saprolite 05724301 UW05 561651.6699 1423810.2421 789.59 4.0 - 14.0 14.0 09/91 Saprolite 05724301 UW06 561547.4955 1423695.4543 782.00 1.0 - 16.0 16.0 08/91 Saprolite 05724301 UW07* 561560.8461 1423919.6721 780.03 2.5 - 15.0 15.0 09/91 N/A 05724301 UW08 561581.0603 1423770.9912 780.97 5.0 - 15.0 15.0 02/92 Saprolite 05724301 UW09' N/A N/A 778.00 2.0 - 12.0 12.0 02/92 UW10 561650.8426 1423655.9836 785.56 3.0 - 18.0 18.0 02/92 Saprolite 05724301 UW11 561573.1870 1423648.4289 784.79 4.0 - 19.0 19.0 02/92 Saprolite 05724301 VE01 561610.1204 1423594.3698 N/A N/A 10.0 N/A 05724302 VE02 561635.7696 1423612.0386 785.42 N/A 10.5 N/A N/A 05724301 VE03 561597.8544 1423617.7069 785.41 N/A 12.0 N/A N/A 05724301 VE04 561654.3003 1423576.2976 785.46 N/A 12.5 N/A N/A 05724302 VE05 561684.7491 1423590.9811 784.83 N/A 13.0 N/A 05724302 VE06 561728.0120 1423583.0234 785.19 N/A 11.5 N/A 05724302 VE07 561689.8509 1423654.3951 785.52 N/A 13.0 N/A N/A 05724301 NOTES: 1) N/A - Data Not Available. 2) * Missing as of 03/2005 3) ** Abandoned September 2002 4) NGVD = National Geodetic Vertical Datum P:\BP\Projects\Terminals\4762\5.0 Deliverables\5.1 Draft - Interim Deliverables\Active Remediation Monitoring Report\Tables\Table 1 Update July 2011 (MW-69)\T1 Page 4 of 4 Table 2A Biosparge Study Short Term Test - Area 2 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina SampleID Nan-INDate 'me Hour' ;r DTW btoc "_ D® ,; •n?' a V®C C{)2;_ To` Nle h e % - LT t PPM MW-66 10/22/2010 Baseline 5.38 0.80 62.8 5.4 17.4 MW-66 10/25/2010 9:00 5.12 1.20 46.9 4.7 2.2 MW-66 10/26/2010 8:30 4.89 1.39 90.2 0.0 99.9 MW-66 10/26/2010 10:02 6.39 1.01 173.0 6.1 OR MW-66 10/26/2010 11:09 5.93 0.61 274.5 5.7 OR MW-66 10/26/2010 12:43 6.21 1.16 296.2 5.3 OR MW-66 10/26/2010 13:46 6.23 0.84 396.2 5.1 OR MW-66 10/26/2010 14:47 6.09 0.73 393.1 4.9 OR MW-66 10/26/2010 15:45 NR NR NR NR NR MW-66 10/27/2010 7:55 6.58 0.77 393.7 3.5 OR MW-66 10/27/2010 14:34 6.54 0.87 482.4 2.9 OR MW-66 10/28/2010 7:56 6.84 0.75 678.7 2.9 OR MW-66 10/28/2010 14:49 6.93 0.72 727.2 2.8 OR MW-66 10/29/2010 8:44 6.73 0.55 1017.0 3.1 OR MW-67 10/22/2010 Baseline 4.90 0.81 312.0 4.4 >99.9 MW-67 10/25/2010 9:15 4.43 0.86 248.2 5.6 OR MW-67 10/26/2010 8:34 4.18 1.68 250.1 6.3 OR MW-67 10/26/2010 10:07 6.32 0.87 257.4 5.6 OR MW-67 10/26/2010 11:13 6.03 1.01 299.3 5.0 OR MW-67 10/26/2010 12:48 6.93 1.08 344.2 4.6 OR MW-67 10/26/2010 13:50 6.20 0.74 393.3 4.3 OR MW-67 10/26/2010 14:52 6.19 0.85 399.9 4.1 OR MW-67 10/26/2010 15:45 NR NR NR NR NR MW-67 10/27/2010 8:03 6.54 0.76 594.2 3.0 OR MW-67 10/27/2010 14:40 6.78 0.66 404.1 2.2 OR MW-67 10/28/2010 8:02 6.88 0.54 910.3 2.5 OR MW-67 10/28/2010 14:55 6.93 0.63 795.6 2.0 OR MW-67 10/29/2010 9:06 6.93 0.80 1009.0 2.4 OR MW-68 10/22/2010 Baseline 6.99 0.86 258.0 13.8 >99.9 MW-68 10/29/2010 10:55 6.78 0.74 345.1 1.4 2.3 UW-04 10/22/2010 Baseline 9.35 3.20 8.0 0.8 0.0 UW-04 10/25/2010 9:34 9.38 1.74 0.0 0.5 0.0 UW-04 10/26/2010 8:40 8.24 4.66 0.0 0.2 0.5 UW-04 10/26/2010 10:41 8.49 3.65 0.0 0.0 0.0 UW-04 10/26/2010 11:04 8.51 4.12 0.0 0.0 0.0 UW-04 10/26/2010 13:22 8.66 3.99 0.0 0.8 0.0 UW-04 10/26/2010 14:10 8.66 3.90 0.9 1.2 0.0 UW-04 10/26/2010 15:22 8.66 3.63 0.7 0.9 0.0 UW-04 10/26/2010 NR NR NR NR NR NR UW-04 10/27/2010 8:37 8.65 3.59 0.0 1.2 0.2 UW-04 10/27/2010 15:05 8.65 3.55 0.0 1.1 0.2 UW-04 10/28/2010 8:33 8.65 3.59 0.0 0.6 0.1 UW-04 10/28/2010 15:31 8.65 3.57 0.0 0.4 0.1 UW-04 10/29/2010 10:20 8.95 2.69 0.0 1.5 0.0 Page 1 of 3 Table 2A Biosparge Study Short Term Test - Area 2 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample D ;Samp.Date ' Time `; a D DU .p VOC CCi2 Methane Unit: Hour btoc . ri g/L 4 PPm, % UW-06 10/22/2010 Baseline 7.35 0.95 0.2 1.3 0.0 UW-06 10/29/2010 10:33 6.85 0.74 0.0 1.2 0.0 UW-08 10/22/2010 Baseline 5.83 1.04 1.2 7.1 0.0 UW-08 10/25/2010 9:19 5.83 0.97 0.0 6.1 0.5 UW-08 10/26/2010 8:48 5.72 0.86 0.0 5.6 0.0 UW-08 10/26/2010 10:13 5.70 1.19 0.0 5.0 0.6 UW-08 10/26/2010 11:18 5.69 1.08 0.6 4.3 0.5 UW-08 10/26/2010 12:52 5.63 1.06 3.4 4.0 1.2 UW-08 10/26/2010 13:56 5.61 0.51 7.4 3.1 0.2 UW-08 10/26/2010 14:58 5.59 1.27 3.5 3.1 0.1 UW-08 10/26/2010 15:40 NR NR NR NR NR UW-08 10/27/2010 8:09 5.44 0.89 3.7 1.5 0.5 UW-08 10/27/2010 14:45 5.44 0.56 0.0 1.1 4.4 UW-08 10/28/2010 8:09 5.38 0.69 0.0 2.2 1.1 UW-08 10/28/2010 15:01 5.34 0.52 0.0 1.6 3.6 UW-08 10/29/2010 9:14 5.38 1.09 2.9 3.1 0.3 TO-1 10/22/2010 Baseline 10.44 0.88 1.3 1.6 0.0 TO-1 10/29/2010 10:39 10.00 0.80 2.7 1.0 0.0 TO-2 10/22/2010 Baseline 8.62 0.89 14.7 0.0 0.0 TO-2 10/25/2010 9:26 8.58 0.58 585.0 0.2 0.1 TO-2 10/26/2010 8:54 8.53 2.17 280.9 0.1 0.0 TO-2 10/26/2010 10:23 8.50 1.54 0.0 0.0 0.1 TO-2 10/26/2010 11:24 8.49 2.67 1046.0 0.0 0.0 TO-2 10/26/2010 12:57 8.49 0.91 0.0 0.0 0.3 TO-2 10/26/2010 14:02 8.49 0.76 0.0 0.0 0.0 TO-2 10/26/2010 15:01 8.49 0.81 0.0 0.0 0.0 TO-2 10/26/2010 15:45 NR NR NR NR NR TO-2 10/27/2010 8:17 8.45 2.68 1.2 0.0 0.2 TO-2 10/27/2010 14:50 8.42 2.57 1.0 0.0 0.0 TO-2 10/28/2010 8:14 7.96 0.99 0.0 0.1 0.1 TO-2 10/28/2010 15:07 7.95 1.01 0.0 0.1 0.0 TO-2 10/29/2010 9:21 8.02 2.71 1.3 0.1 0.2 UW-05 10/22/2010 Baseline 10.93 1.07 70.2 3.2 0.0 UW-05 10/29/2010 9:54 10.66 2.03 0.0 1.2 0.0 ES-12 10/22/2010 Baseline 12.91 0.74 124.0 8.9 0.4 ES-12 10/29/2010 10:15 12.88 0.59 103.0 2.1 0.2 ES-14 10/22/2010 Baseline 11.47 0.26 131.0 0.0 99.9 ES-14 10/29/2010 9:47 11.43 0.16 306.0 0.0 99.9 ES-15 10/22/2010 Baseline 10.96 0.80 235.0 11.1 0.0 ES-15 10/29/2010 10:02 10.62 0.42 57.8 1.2 0.0 ES-31 10/22/2010 Baseline 11.47 3.01 119.0 0.6 0.0 ES-31 10/26/2010 9:02 11.39 2.06 530.6 1.3 0.4 ES-31 10/26/2010 10:31 11.41 2.25 938.0 0.6 1.2 ES-31 10/26/2010 11:36 11.41 2.31 3.1 0.4 0.1 Page 2 of 3 Table 2A Biosparge Study Short Term Test - Area 2 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina SampleeID Samp.•Date Time DTW DO VOC COZ`= .. Methane Unit. Hour ; btoc mgn- ppm % % ES-31 10/26/2010 13:10 11.40 2.40 2.4 0.4 0.1 ES-31 10/26/2010 14:05 11.40 2.37 11.6 0.2 0.1 ES-31 10/26/2010 15:15 11.40 2.34 23.4 0.3 0.2 ES-31 10/26/2010 15:45 NR NR NR NR NR ES-31 10/27/2010 8:25 11.42 2.33 127.9 0.2 0.9 ES-31 10/27/2010 14:56 11.42 2.34 55.8 0.3 0.7 ES-31 10/28/2010 8:21 11.42 2.78 111.2 1.3 0.2 ES-31 10/28/2010 15:14 11.42 2.64 98.7 0.6 0.8 ES-31 10/29/2010 9:32 11.46 3.83 98.3 0.9 0.1 DW-01A 10/22/2010 Baseline 7.24 1.09 0.8 2.5 0.0 DW-01A 10/29/2010 10:47 6.83 0.89 8.1 2.7 0.0 Notes: AS-06 Flow (SCFM) average = 3.0 SCFM; AS-06 Pressure (PSI) average = 25 PSI btoc - below top of casing mg/L - milligrams per liter ppm - parts per million NR - No Reading OR - Out of Range Page 3 of 3 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID 1 Samp.Date Time DTW ' ''' DO '':-. - ',. VOC CO2i, -,. Methane - ------" , Unit: l' Hour btoc -::,-..,ff Ingil-f- 7-*-' 1)pm:4 ,:;.,--% -17: %. MW19 11/1/2010 9:45 11.52 0.81 0.0 0.0 0.0 MW19 11/2/2010 9:08 11.50 1.23 10.8 0.7 0.0 MW19 11/2/2010 10:50 11.45 0.89 5.3 2.6 0.0 MW19 11/2/2010 13:12 11.43 0.90 7.9 1.9 0.0 MW19 11/2/2010 14:31 11.39 0.77 5.9 1.3 0.0 MW19 11/2/2010 15:55 11.38 0.64 5.4 1.4 0.0 MW19 11/3/2010 8:52 11.38 0.89 13.3 2.7 0.0 MW19 11/3/2010 15:00 11.31 0.91 9.7 3.1 0.0 MW19 11/4/2010 15:31 11.25 0.55 19.5 8.4 0.0 MW19 11/5/2010 10:29 11.33 0.65 3.9 6.0 0.0 MW19 11/8/2010 9:16 11.38 1.09 12.2 12.0 0.0 MW19 11/15/2010 9:48 11.62 - 1.49 238.0 ' 7.7 30.4 MW19 11/22/2010 10:01 11.85 - 0.62 346.1 17.1 ' 21.7 MW19 11/29/2010 10:06 ,12.03 1.36 9.0 17.5 0.0 ' MW19 -1.2/6/2010 13:10 11.94 0.68 : 8.8 21.3 - '. ' 8.0 MW19 12/22/2010 NR 12.12 1.59 117.0 18.2 0.0 MW19 1/4/2011 10:57 12.10 , 0.65 , 0.0 16.3 0.0 MW19 1/17/2011 10:15 12.07 0.89 , 42.9 13.0 0.0 MW36 11/1/2010 9:49 15.01 0.73 0.0 0.0 0.0 MW36 11/2/2010 9:22 14.92 1.03 0.0 4.3 0.0 MW36 11/2/2010 10:55 14.90 0.64 0.4 3.6 0.0 MW36 11/2/2010 13:17 14.88 5.44 1.4 4.6 0.0 MW36 11/2/2010 14:36 14.85 4.66 2.3 5.5 0.0 MW36 11/2/2010 16:01 14.83 4.94 3.7 5.9 0.0 MW36 11/3/2010 8:58 14.85 2.12 6.4 8.3 0.0 MW36 11/3/2010 15:06 14.80 1.17 26.3 9.5 0.3 MW36 11/4/2010 15:39 14.74 0.44 169.5 0.0 0.0 MW36 11/5/2010 10:35 14.83 0.55 170.4 0.0 0.0 MW36 11/8/2010 9:22 14.89 0.73 293.4 . 14.7 OR MW36 11/15/2010 '9:53 15.10 0.99 ' . 634.0 14.7 -= 46.1 MW-36 11/22/2010 10:06 15.35 0.57 476.3 18.0 7.0 MW-36 11/29/2010 10:15 15.55 1.09 277.0 17.3, - 0.8 MW-36 12/6/2010 13:32 15.52 " 0.37 .- 102.0 19:7 0.3 MW-36 12/22/2010 NR 15.63 1.56 644.0 14.8 10.0 MW, -36 1/4/2011 . 11:02 - 15.62 . 0.61 - 451.6 11.1 2.4 MW-36 -1/17/2011 10:20 15.65 0.55 296.7 - 8.3 - 2.3 MW38 11/1/2010 10:13 14.30 3.59 0.0 2.0 0.8 MW38 11/2/2010 9:58 13.54 2.95 2.2 4.4 0.0 MW38 11/2/2010 11:20 13.60 1.74 90.5 6.4 0.8 MW38 11/2/2010 13:37 13.68 0.86 328.4 8.6 10.9 MW38 11/2/2010 15:04 13.69 0.77 319.2 8.9 29.1 MW38 11/2/2010 16:26 13.71 0.80 363.1 9.0 42.7 MW38 11/3/2010 9:27 13.85 2.95 471.2 10.1 OR MW38 11/3/2010 15:25 13.86 2.81 513.0 10.9 OR Page 1 of 6 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID Samp.Date . Time DTW DO VOC CO2 Methane Unit: Hour btoc m4mg/L ppm % MW38 11/4/2010 15:59 13.70 2.36 767.4 5.2 34.4 MW38 11/5/2010 11:39 13.86 2.53 870.4 2.4 10.9 MW38 11/8/2010 9:43 ' 14.07 ' _ 2.24 910.0 6.6 26.1 MW38 11/15/2010 10:29 ` . 14.33 1.71 573.0 : - - 2.8 10.4 MW38 11/22/2010 ;' 10:32. 14.58 1.49 °' 497.3 2.3 .5 MW38 ° 11/29/2010 10:36 ' 14.75. `' 1.91 ' ` ��'" 1034.0 . 1.9 7.5 MW38 12/6/2010 16:31 ' ' 15.16 3.39 442.0 0.9 2.0 MW38 12/22/2010 NR ° 14.96 < ° ° 1.66 994.6 , : 2.6 40.2 MW38 1/4/2011 11:24 ;' 15.05 0.67 793.4 2.4 22.5 MW38 1/17/2011° - 10:40 r 15.09 -: ; 0.51 938.9 ,� - �. ° '1.8:13.8 MW39 11/1/2010 10:45 14.06 0.82 0.0 2.1 0.0 MW39 11/2/2010 10:15 13.74 0.54 117.9 2.3 0.0 MW39 11/2/2010 11:31 13.72 0.87 398.7 1.9 0.7 MW39 11/2/2010 13:47 13.64 4.20 481.2 3.4 9.2 MW39 11/2/2010 15:19 13.61 3.75 512.6 3.5 17.3 MW39 11/2/2010 16:39 13.59 3.71 541.2 3.5 22.4 MW39 11/3/2010 9:43 13.72 1.71 807.4 3.7 8.4 MW39 11/3/2010 15:38 13.70 1.05 443.6 4.9 11.3 MW39 11/4/2010 16:14 13.52 1.03 523.6 0.5 0.2 MW39 11/5/2010 11:53 13.73 1.01 616.4 0.4 0.2 MW39 11/8/2010 9:55 ,`. ' 13.89 0.85 684.3 0.9 1.1 MW39 11/15/2010 10:42 14.10 ` 1.58 480.0 0.3 1.0 MW39 11/22/2010 11:07. 14.32 0.76 425.4 0.4 0.9 MW39. 11/29/2010 11:30 , ' .° 14.50 . 1.62 306.0 0.2 0.4 MW39 12/6/2010 16:36°: 14.78 2.45 ° ` 35.9 0.3 0.3 MW39 ' 12/22/2.010 NR 14.70 1.70 236.6 0.3 0.8 MW39 1/4/2011 11:41 14.80 ` 1.29 192.0 0.3 0.5 MW39 1/17/2011 10:56 ` 14.87 ` 0.76 366.7 0.1 1.4 MW41 11/1/2010 12:12 14.50 6.63 0.0 4.5 0.0 MW41 11/2/2010 10:09 14.42 6.30 0.0 3.6 0.0 MW41 11/2/2010 11:26 14.36 0.81 0.0 4.1 0.0 MW41 11/2/2010 13:42 14.32 3.41 1.2 1.8 0.0 MW41 11/2/2010 15:11 14.28 1.96 5.7 2.0 0.0 MW41 11/2/2010 16:31 14.28 1.31 13.9 6.7 0.3 MW41 11/3/2010 9:35 14.28 0.73 667.1 4.9 11.1 MW41 11/3/2010 15:31 14.24 1.25 550.8 10.6 69.2 MW41 11/4/2010 16:06 14.10 0.79 330.4 2.2 2.7 MW41 11/5/2010 11:46 14.28 0.85 334.6 0.0 0.0 MW41 11/8/2010 9:48 - 4. 14.40 `. 1.19 ' � _: 401.6 10.1 - 42.1. MW-41 11/15/2010 10:36w .,.` : 14.59 :�'�. 1.11 � ` 614.0 ` � - � `6.1 34.7 MW-41 11/22/2010. = 11:03 14.80 1.63 371.9 -', ° 3.9 27.6 MW-41 11/29/2010 11:25 14.96 2.03 902.0 '° °. ` 2.9 27.2 MW 141 12/6/2010 16:15 15.01 °` : 2.66 ` 2163.0 3.2 40.1 MW-41 12/22/2010 . NR ` :; ;.' ` 15.21 .;_ .. .. 2.02 1269.0 2.5 69.9 Page 2 of 6 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID Samp.Date Time DTW DO VOC CO2 Methane Unit: Hour btoc mg/L ppm % MW-41 1/4/2011 11:30 15.34 0.91 996.4 7.5 75.7 MW-41 1/17/2011 10:49 15.40 0.68 1075.0 2.6 62.1 MW45 11/1/2010 10:00 15.27 1.04 0.0 0.2 0.0 MW45 11/2/2010 9:33 15.13 1.53 0.0 2.8 0.0 MW45 11/2/2010 11:06 15.14 0.73 5.2 3.8 0.0 MW45 11/2/2010 13:27 15.12 0.61 16.4 4.1 0.0 MW45 11/2/2010 14:48 15.12 0.53 34.8 5.6 0.0 MW45 11/2/2010 16:12 15.12 0.55 62.4 6.3 0.0 MW45 11/3/2010 9:14 15.12 0.67 235.1 8.5 4.1 MW45 11/4/2010 15:45 15.08 0.48 234.0 3.9 21.4 MW45 11/5/2010 10:41 15.13 0.61 277.9 2.2 20.9 MW45 11/8/2010 10:32 15.18 0.57 395.7 13.3 OR MW45 11/15/2010 10:17 15.39 0.74 546.0 12.7 54.5 MW-45 11/22/2010 10:17 15.65 0.84 578.4 10.5 12.6 MW-45 11/29/2010 10:24. ` 15.83 1.34 729.0 6.4 9.6 MW-45 12/6/2010 13:43 15.81 1.03 612.0 , 5.0 12.2 MW-45 12/22/2010 NR 16.02 1.77 859.0 4.6 59.6 MW-45 1/4/2011 11:09 16.03 0.57 741.7 3.6 21.1 MW-45 1./17/201' 1 10:27 16.02 0.60 570.9 2.8 11.8 MW49 11/1/2010 10:06 13.35 1.13 25.3 0.1 0.1 MW49 11/2/2010 9:47 12.97 0.77 203.7 0.0 99.9 MW49 11/2/2010 11:13 13.05 0.84 263.4 0.0 99.9 MW49 11/2/2010 13:32 13.04 0.23 323.3 8.8 OR MW49 11/2/2010 14:57 13.05 0.11 271.1 7.2 OR MW49 11/2/2010 16:19 13.05 0.10 305.4 6.9 OR MW49 11/3/2010 9:22 13.13 0.28 307.7 9.9 OR MW49 11/3/2010 15:18 13.06 0.77 396.3 10.1 OR MW49 11/4/2010 15:53 13.11 0.56 309.0 0.0 OR MW49 11/5/2010 11:30 13.20 0.93 292.4 0.0 0.0 MW49 11/8/2010 9:38 13.32 0.64 284.5 10.7 OR MW49 11/15/2010 10:23 13.51 1.07 435.0 14.1 OR MW49 11/22/2010 10:27 13.78 0.49 528.2 16.5 OR MW49 11/29/2010 10:31 14.01 1.12 753.0 15.8 OR MW49 12/6/2010 16:21 14.01 0.33 1258.0 18.3 OR MW49 12/22/2010 NR 14.15` 1.23 881.8 13.7 99.9 MW49 1/4/2011 11:16 14.15 0.73 540.6 11.8 OR MW49 1/17/2011 10:34 14.24 0.50 644.6 7.8 OR MW50 11/1/2010 9:55 12.75 0.83 0.0 0.7 0.0 MW50 11/2/2010 9:27 12.76 1.32 0.0 0.5 0.0 MW50 11/2/2010 11:00 12.73 0.78 0.6 0.6 0.0 MW50 11/2/2010 13:22 12.71 0.91 0.0 0.5 0.0 MW50 11/2/2010 14:42 12.67 0.96 0.0 0.5 0.0 MW50 11/2/2010 16:09 12.66 0.87 0.0 0.5 0.0 MW50 11/3/2010 9:05 12.66 0.99 0.0 3.4 0.0 Page 3 of 6 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID Sainp.Date Methane btoc MW50 11/3/2010 15:11 12.62 0.59 1.7 2.7 0.0 MW50 MW50 MW50 11/4/2010 11/5/2010 11/8/2010 9:26 Not gauged standing water over well from heavy rain. Not gauged standing water over well from heavy rain. 2.61 0.64' 148.9 4.7! 16.9 MW50 11/15/2010 9:58 12.88 1°.03 77.5 2.8 0.6 MW50' 11/22/2010 .10:11. 13.16' 0.56 20.7 4..3`. 0.1 • MW50 11/29/2010 10:20'' 13.39 -1.52' 81.1 5.2, 5.4 MW50 12/6/2,010 13:34 13.27' 0.39 665.0 6.5 23.6 MWSO . 12/22/2010, Could Not Access mud MWSO 1/4/2011 Could Not Access - mud MW50 1/17/2011 Could Not Access - mud ES-18 11/1/2010 12:19 16.06 0.20 18.3 14.6 31.1 ES-18 11/5/2010 12:10 16.08 0.56 15.3 9.5 18.7 ES-18 11/15/2010 10:48. 16.30 0.32 15.2 9.1 `23.9 ES-18 . 11/22/2010 11:14 16.40 0.16 37.0 7.5 16.7 ES-18 11/29/2010 1:36 zr 16.52 0.62 35.4 x 111s 29.2 ES-18 12/6/2010 16:07 16.28 0.39 37.2. 11.2 30.3 ES-18. 12/22/2010 NR 16.53 1.39 38.0 7.1 8.7 ES-18 1/4/2011: 11:48` 16.40 0.66 19.6 2.3 1' ES-18 1/17/2011 -Could Not Access - Under Ice, ES-05SR 11/1/2010 12:25 11.49 0.81 0.2 5.4 0.0 ES-05SR 11/5/2010 12:17 11.42 0.87 2.9 1.8 0.0 ES-05SR 11/15/2010 10:53 1.64 0.98 1.7, 8.1 0.0 'ES-05SR 11/22/2010 11:19 11.63 2.54 0.0 3.9 0.0 ES-OSSR 11/2,9/2010 11:40 1.90' 0.92 1.2 0.7 0.0 ES-05SR 12/6/2010 16:03" 11.93 0.59 3.7 5.0 0.0 ES-05SR 12/22/2010 NR . 12.10 1.42 530.6 10.6 32.6 ES-05SR ES-05SR '1/4/2011 1/17/2011 :54"e.. 11:04' 12.19 12.09 0:65: 0:42; 162.7 438.6 181 15.8 31.7 21.4 MW-07 11/1/2010 9:22 5.94 5.32 0.0 0..6 0.2 MW-07 11/5/2010 9:49 1.94 6.84 0.0 0.0 0.0 MW-07 11/15/2010 9:30 6.57' 4.96 OM 0.7 `00 MW-07 11/22/2010 `7.07' 5.43 0.0, 0.6 0.8 MW-07, 11/29/2010 9:50 7.30 4.61r 2.5' 0.5 0 0 MW-07 MW-07 12/6/2010 12/22/2010 NR MW-07 1/4/2011 10:40. 4.771 8.601 0.01 1.0 0.0 MW-07-' ES-11 1/17/2011 11/1/2010 12:34 11.01 0.94 N. 0.0 2.3 0.3 ES-11 11/5/2010 12:22 10.93 0.30 856.7 8.8 26.7 ES-11. 11/15/2010 11:11 11.15 0.70 2,16.0 3.6 1.0 ES-1 11/22/2010 11:27 - .37 5.78 1`,872 3 ES- it 11/29/2010 -1:47 11.58 1.39 .7; 29 08 ES-11. 12/6/2010 16:57 11.55. 0.90 54.9' 0.7 0.1 Page 4 of 6 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina 1p Sainp.Date Time DTW DO VOc Methane; Unit Hour °btoc P ES-11 12/22/2010 NR 11.80 1.10 164.7 2.5 0.6 ES-11 1/4/2011 12:18 11.87` 0.94 58.4 0.8 0.0 ES-11 1/17/2011 11:11' 11.81: 0.48; 188.1 .5 0.2 MW-42 11/1/2010 12:49 14.00 0.54 0.0 7.7 0.0 MW-42 11/5/2010 12:42 13.93 0.48 6.1 6.4 0.0 MW-42 11/15/2010 1:18 14.15 1.18 532.0` 13.8. ;..15.2 MW-42 11/22/2010 11:43,: 14.35 0.65 399.6 4.1 7.5 MW-42 11/29/20,10' 12:01 14.53 1.75 399.0 12.4 9.2 MW-42.. 12/6/2010 16:59 14.67 2.95 1328.0 1.9 15.7 MW-42 12/22/2010 14.82 .41 496.3 7.0 26.8 'MW-42 /4/2011 12:01 14.90 1.03 4872 43` 23.7 MW-42 1/17/2011 11:15 14.95 0.53 857.3 3.1 13.5' MW-51 11/1/2010 12:43 12.14 0.48 154.3 11.3 0.5 MW-51 11/5/2010 12:33 12.14 0.50 137.7 2.9 0.1 -51' 11/15/2010 11:37 12.37 0.89 142.0 6.9 5.1 MW-51 11/22/2010 11:35 12.59 .0.51 190.4 62 .3.6 MW-51 11/29/2010 `11:56 12.86 1.14 262.0 4.6 2.1 MW-51 12/6/2010 16:54. 12.63 1.53 930.0 15.0 2.6 MW-51 42/22/2010 10.98. 071; 221.4 5; 37.4 MW-51 1/4/2011 12:07 12.60 0.70 375.4 14.8 43.9 MW-51 1/17/2011 11:30 '. 12.79 0.54 890.6' 14.7 29.91 MW-44 11/1/2010 12:58 14.40 0.52 0.0 0.6 0.0 MW-44 11/5/2010 12:47 14.25 0.23 747.7 14.4 72.5 NTW-44 '11/15/2010 11:44 14.55 1.12 87.1.0 9.6 25.5 MW-44 . ° 14/22/2010 11:48 114.86 0.57 449.0 89 1.4 MW II/1 11/29/2010 12:07 15.04 1.21 1057.0 6.3. 8.8 MW-44 12/6/2010 16:41 15.05 4.51 456.0 26' 1.5. .MW-44 12/22/2010 NR 15.32 0.98 890.8 4.0. 19.7; MW-44 1/4/2011 12:12 15.39 1.11 743.2' 4.5 6.1 MW-44 1/17/2011 1/17/2011 11:22 15.33' 0.35 891.8 2.6 9.1 MW-02 11/1/2010 9:37 11.32 0.98 0.0 0.9 0.0 MW-02 11/5/2010 10:23 11.11 3.41 13.8 0.0 0.0 -02 11/15/2010 9:42 11.39 1.29 0.0 3.9 0.0 MW-02 11/22/2010 9:56 11.67 0.59 0.0 0.0 MW-02 11/29/2010 10:01 11.82 1.66 0.3 40 O. MW-02 12/6/2010 13:03"- 1.59 6.76i 872.0' 6 12.6 MW-02 12/22/2010 NR 11.73 1.72 1181.0 5.0 4.1 t-02 41/4/2011 10:52 11.63 074 647.1 5.1 13.9 `.MW-02 1/17/2011 '10:10 11.60 071 353.6 8.9 5.9 MW-08 11/1/2010 9:30 10.65 4.81 0.0 0.4 0.0 MW-08 11/5/2010 10:17 5.63 6.14 1.4 0.0 0.0 'MW-08 1/15/2010 9:35 10.02 4.19 0.0 .0.3 MW-08 11/22/2010 9:51 10.31' 2.94' 0.0 0.3 '0.0 MW-o8A 1`1/29/2010 9:55 0.44 3.55 3.1 0.4 0.0 Page 5 of 6 Table 2B Biosparge Study Short Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID I SampDate Time DTW DO VOC CO2 Methane Uhit: Hour btoc _:.. mg/L ; ppm MW-08 12/6/2010 12:54 : 9.73 5.12 ` 1.1 0.5 0.0 MW-08 12/22/2010 NR 9.80 7.01 10.6 0.7 0.0 MW-08 1/4/2011 10:46 8.07 6.79 0.0 0.5 0.0 MW-08 1/17/2011 0:00 9.48 6.20 3.1. 0.4 0.0 Notes: [Grayed - collected as mart of long term biosparge test AS-04 Flow (SCFM) average = 2.3 SCFM; AS-04 Pressure (PSI) average = 16 PSI AS-05 Flow (SCFM) average = 2.5 SCFM; AS-05 Pressure (PSI) average = 14 PSI btoc - below top of casing mg/L - milligrams per liter ppm - parts per million NR - Not Recorded OR - Out of Range Page 6 of 6 Table 3 Biosparge Study Long Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID I Samp.Date Benzene Toluene Ethylbenzene Xylenes ,2-DCA TPE MTBE Naphthalene Unit: ug/L �, ug/L; ug/L ug/L ' ug/L u ug/L N ug/L a, MW19 6/14/2007 6770 J 30.8 J 776 J 479 J < 0.5 UJ 78.2 J 1380 J 330 J MW19 12/4/2007 5970 < 27 665 352 < 20 74.7 J 1290 < 213 U MW19 6/3/2008 730 8.4 J 270 270 < 2 9 J 230 180 MW19 12/3/2008 1,600 6.2 J 150 100 < 2 29 620 110 MW19 6/3/2009 210 2.9 J 110 46 < 1 2.2 J 43 52 MW19 12/8/2009 2,000 7.1 J 180 120 < 2 16 300 100 MW19 6/8/2010 1,500 7J 220 120 <2 11 160 160 MW19 12/8/2010 4,300 17 _ 500 390 < 2 36 580 ' 290 MW19 1/17/2011 5,600 20.1 650 460 < 5 36 590 270 MW19 6/7/2011 780 3.6 110 67 < 0.5 11 170 66 MW36 6/12/2007 5580 68.4 J 614 984 < 50 < 50 553 201 MW36 12/4/2007 5170 131 919 1280 < 20 < 20 162 < 222 U MW36 6/3/2008 6,700 150 1,100 1,600 < 10 < 10 140 370 MW36 12/4/2008 3,100 71 700 900 < 10 < 10 110 280 MW36 6/3/2009 2,200 29 300 430 < 2 12 260 150 MW36 12/8/2009 3,100 69 850 790 <2 3.7J 71 340 MW36 6/8/2010 4,400 33 480 300 < 2 21 330 240 MW36 12/8/2010 4,700 62 970 550 < 2 18 340 440 .MW36 1/17/2011 4,800 49 : 910 400 < 5 12 J 220 380 MW36 6/7/2011 1,600 20 J 280 150 < 5 6.2 J 120 110 MW38 6/12/2007 433 847 264 1570 9.4 3.1 41.3 138 MW38 12/4/2007 63.7 138 112 822 2 J < 1 10.8 71.5 MW38 6/3/2008 1 J 11 52 360 < 1 < 1 < 1 43 MW38 12/4/2008 < 0.50 0.73 J 2.4 J 10 < 0.50 < 0.50 < 0.50 2.1 J MW38 6/3/2009 0.22 J 1.6 4.7 36 < 0.2 < 0.2 < 0.2 6 MW38 12/8/2009 < 0.1 0.23 J 0.84 6.8 < 0.1 < 0.1 < 0.1 1.3 MW38 6/8/2010 < 0.1 0.15 J 0.42 J 1.7 < 0.1 < 0.1 < 0.1 0.45 J MW38 12/8/2010 3.1 1.1 1.6 : 23 0.49 J 0.°15 J 0.94 1.2 MW38 1/17/2011 84 67 J 230 J 1,600 < 2 < 2 14 160 J MW38 1/17/2011 :: 86 85;1 410'J 1,400 of ° < 2 < 2 14 ; 290 J MW38 6/7/2011 < 0.1 < 0.1 0.19 J 0.72 < 0.1 < 0.1 < 0.1 0.25 J MW39 6/14/2007 582 197 94.6 413 < 5 < 5 22.1 144 MW39 12/4/2007 473 98.1 43.5 184 6.3 J 3 J 32.7 < 11 U MW39 6/3/2008 340 34 31 100 < 0.5 < 0.5 4 13 MW39 12/4/2008 150 23 16 64 < 0.50 0.59 J 4.4 5.1 MW39 6/3/2009 340 280 190 850 < 1 < 0.8 6.4 73 MW39 12/9/2009 29 11 11 50 1.4 0.22 J 1.9 5.3 MW39 6/8/2010 120 110 81 280 < 0.1 0.29 J 2.2 44 t111W39 12/8/2010 170 94 97 :. 400 < 0.1 4 6 67, 52 MW39 1/17/2011 1,600, 190. ;`. 160 540 ,. ; ` < 1 5:4 MW39 6/7/2011 91 10 15 38 < 0.1 0.22 J 3.5 5.9 Page 1 of 2 Table 3 Biosparge Study Long Term Test - Area 3 BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID Samp.Date :, Benzene' .=,Toluen F ;Ethylben7ene Xylenes ,2-DCA . <`;,IPE ;; MTBE eNaphthalene Unit uglL ug/L ', u /L ug/%' ugfL n0,, MW41 6/13/2007 33.1 11.7 22.6 192 < 0.5 < 0.5 1.4 62.3 MW41 6/13/2007 32.5 11 22.5 187 < 0.5 < 0.5 1.2 60.8 MW41 12/4/2007 52.6 39.3 99.9 565 < 0.4 < 0.4 4.7 160 MW41 12/4/2007 55.2 35.8 88.6 580 < 1 < 1 4.7 J 142 MW41 6/3/2008 17 16 24 360 < 0.5 < 0.5 2.5 100 MW41 12/4/2008 18 26 90 560 < 0.50 < 0.50 1.1 J 180 MW41 6/3/2009 11 38 68 590 < 1 < 0.8 1.3 J 230 MW41 12/8/2009 1.9 3.8 12 96 < 0.1 < 0.1 0.28 J 38 MW41 6/8/2010 3 5.3 16 110 < 0.1 <0.1 0.12J 54 M /41, 12/8/2010 17; w 26 53 "` 400 = . ,.. < 0 1 : < 0.1: 0 24 J °.150 1I17/2011 27 7 Y' ; 94 :.790 1 1 <` 1 ' ..., .- 1 .. ' . H , ,'. 220 MW41 6/7/2011 1.1 2.8 8.4 88 < 0.1 0.15 J 0.11 J 35 MW49 6/14/2007 206 J 5.7 J 5.3 J 14.7 J < 2.5 UJ < 2.5 UJ 50.6 J 34.4 J MW49 12/4/2007 320 10.4 26.4 23.8 < 1 < 1 71.9 54.7 MW49 6/3/2008 140 9.7 20 31 < 0.5 0.9 J 31 32 MW49 12/4/2008 130 17 55 130 < 0.50 0.86 J 27 57 MW49 6/3/2009 150 8.3 7.7 17 < 1 < 0.8 18 36 MW49 12/8/2009 110 9.6 22 67 3.8 0.6 J 20 48 MW49 6/8/2010 73 8 12 30 < 0.2 0.57 J 17 39 MW49. . `,.12/8/2010 490 °``: 9, '3=l .76 ;,`; :.<0 5 3 1 =; 7 w£60 MW49 :.F1117/201.1 690 s, 5.8{? " ..: 68 '._ 590 '.; . :`2 7.73 ',.... ~100 ` $' Yr69 MW49 6/7/2011 840 15 15 36 < 2 11 160 15 MW50 6/14/2007 1 J 1.1 J 73.7 J 108 J < 0.5 UJ < 0.5 UJ < 0.5 UJ 116 MW50 12/4/2007 2.6 1.9 J 83.5 100 < 0.4 < 0.4 < 0.5 178 MW50 6/3/2008 0.66 1 140 180 < 0.1 < 0.1 < 0.1 180 MW50 12/4/2008 2.4 1.3 34 42 < 0.10 < 0.10 < 0.10 130 MW50 6/3/2009 < 0.5 0.83 J 300 520 < 1 < 0.8 < 0.5 370 MW50 12/9/2009 < 0.5 < 0.5 63 94 < 0.5 < 0.5 < 0.5 89 MW50 6/8/2010 < 0.5 < 0.5 83 86 < 0.5 < 0.5 < 0.5 140 MW50 , , :` 12/8/2010 - = 0 81 J , ` 0:7'J 110 ` - ` `.150 :, .<:0,5 ; ' ?' <,0 5 < 0 5 ..4..<r s . ; 230 MW50 6/7/2011 < 0.5 < 0.5 82 92 < 0.5 < 0.5 < 0.5 150 Notes: Sampling acca rat 2010 thra Janua DCA - Dichloroethane IPE - Isopropyl ether J - Estimated value MTBE - Methyl tert-butyl ether ug/L - Micrograms per liter UJ - Not detected and the detection limit is estimated value U - Not present above the associated level; blank contamination exists Page 2 of 2 Table 4A Area 1 Injection Detail BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Injection Point ID Injection Depth (bgs) Date Time Stark Time End Total Gallons GPM Comments/Reason for Termination: Al-I1 10 5/17/2011 1447 1449 3 1.50 Friction Loss 14 1501 1505 7 1.75 18 1518 1519 4 4.00 Friction Loss. Injection terminated, very tight soils at next depth interval. A1-I2 10 5/17/2011 0948 1018 60 0.857 Friction Loss 12 1026 1045 45 2.368 Screen for pump plugged, stop for repair. 12 1052 1104 35 0.673 14 1115 1150 80 2.286 Friction Loss 16 1201 1219 45 2.50 Pump empty, stop to fill. 16 1224 1243 35 1.842 18 1341 1345 7 1.75 Friction Loss 20 1413 1415 5 2.50 Friction Loss. Refusal in very tight soils. A1-I3 10 5/18/2011 1055 1102 20 0.426 Loss through Al-12. 14 1107 1125 40 2.222 Loss through Al-I2. 18 1139 1242 150 1.456 Loss through A1-I2. Injection terminated, very tight soils at next depth interval. A1-I4 10 5/17/2011 1453 1529 100 1.316 Loss through MW-65. 14 1533 1534 5 5.00 Loss through Al-I1. Injection terminated due to friction losses. Al-I5 10 5/18/2011 1055 1124 90 1.30 14 1139 1140 5 5.00 Friction Loss 18 1154 1154 0 0.00 Fricton Loss. Injection terminated, very tight soils at next depth interval. A1-I6 10 5/17/2011 0850 0852 5 2.50 Friction Loss 14 0900 0938 100 2.632 18 1005 1009 12 3.00 Friction Loss. Injection terminated, very tight soils at next depth interval. Al-17 20 5/18/2011 1024 1024 0 0.00 Friction Loss. Very tight soils. End injection. l0 1354 1428 65 0.878 Loss through A1-I5. 14 1445 1457 20 1.667 Loss through Al-I6. 18 5/19/2011 0856 0903 20 0.426 Loss through A1-I9. Injection terminated, very tight soils at next depth interval. A1-I8 10 5/18/2011 1354 1427 100 1.37 14 1445 1532 180 2.069 18 5/19/2011 0856 0925 100 1.449 Prescribed amount injected into boring. A1-I9 10 5/16/2011 1526 1527 5 5.00 Friction Loss 15 1534 1535 5 5.00 Friction Loss, remove rods to install friction collar. 15 1549 1600 25 0.49 20 1615 1618 5 1.667 20 1626 1630 20 5.00 20 1637 1642 20 4.00 20 5/17/2011 0847 0859 50 4.167 22 0921 0921 5 0.00 Friction Loss. Refusal in very tight soils. Al-I10 10 5/17/2011 0852 0920 60 0.882 Loss through A1-19. 14 0928 0948 80 4.00 18 1005 1009 30 7.50 Loss through A1-I9. 20 1024 1024 0 0.00 Loss through A1-I9. Refusal in very tight soils. Total Gallons: 1643 Notes: Friction Loss - Loss of solution to ground surface through active injection boring. bgs - below ground surface GPM - gallons per minute Page 1 of 1 Table 4B Area 2 Injection Detail BP Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Injection Point ID Injection Depth ('bgs) Date Time Start Time End Total Gallons GPM Comments/Reason for Termination: A2-I1 10 5/19/2011 1101 1146 100 2.222 Friction Loss 14 1213 1218 20 4.00 Loss from DW-01A, tightened well plug and restarted. 14 1222 1246 80 3.333 18 1353 1405 30 0.577 Loss at ground surface. (unpaved area) 22 1420 1438 70 3.889 24 1449 1523 100 1.351 End of injection, very tight soils. A2-I2 12 5/20/2011 1128 1153 100 4.00 12 1158 1221 100 1.587 18 1254 1258 30 7.50 Loss at ground surface(unpaved area). Injection terminated, tight soils at next depth interval. A243 16 5/20/2011 1609 1611 10 5.00 Rods leaking, out of replacement 0-rings. Shutdown for the day. 17 5/23/2011 1235 1247 40 3.333 Loss to ground surface. Efforts to prevent loss by decreasing flow were unsuccessful. A2-I4 12 5/20/2011 1128 1235 200 1.869 18 1254 1259 30 6.00 Loss at ground surface(unpaved area). Injection terminated, tight soils at next depth interval. A245 10 5/19/2011 1101 1126 100 4.00 14 1213 1256 100 2.326 18 1353 1427 100 1.351 20 1443 1605 100 0.617 Prescribed amount injected into boring. A2-I6 16 5/20/2011 1603 1608 30 6.00 Loss from A2-I5. Shutdown for the day, out of replacement 0-rings. 18 5/23/2011 1235 1245 40 4.00 Loss from A2-15. Injection terminated, tight soils at next depth interval. A2-17 12 5/20/2011 1334 1350 70 4.375 12 1357 1426 100 1.449 Brief delay for batch mixing. 18 1437 1503 100 1.515 18 1509 1526 80 4.706 Brief delay for batch mixing. Prescribed amount injected into boring. A2-I8 10 5/20/2011 0831 0831 0 0.00 Fitting leaking on drill rods. 10 0836 0904 100 1.471 14 0920 0929 30 3.333 Brief shutdown for SIMOPS. Power shutdown for electrical contractors. 14 0945 1002 70 1.228 18 1016 1040 100 4.167 Injection terminated, tight soils at next depth interval. A2-I9 12 5/20/2011 1334 1352 90 5.00 12 1357 1421 100 1.563 18 1437 1500 100 1.587 18 1509 1527 80 4.444 Prescribed amount injected into boring. A2-I10 10 5/20/2011 0831 0907 100 1.316 14 0920 0929 20 2.222 Brief shutdown for SIMOPS. Power shutdown for electrical contractors. 14 0945 1006 80 1.311 18 1016 1049 100 3.03 Injection terminated, tight soils at next depth interval. Total Gallons: 2700 Notes: Friction Loss - Loss of solution to ground surface through active injection boring. bgs - below ground surface GPM - gallons per minute Page 1 of 1 Table 5 VOC Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample ID I,Samp.Date Benzene -`Toluene Ethylbenzene Xylenes'' 'r..1,2=DCA IPE MTBE. Naphthalene Unit: ug/L ug/L uglL ug/ tig7L ug/L .;- Area 1 MWO5 6/14/2007 19 5.2 J 470 1550 < 5 < 5 < 5 828 MWO5 12/4/2007 3.4 J 7.3 J 707 2010 < 2 < 2 < 2.5 971 MWO5 6/3/2008 < 10 UJ < 10 UJ 130J 290 J < 10 UJ < 10 UJ < 10 UJ 440 J MWO5 12/4/2008 0.56 J < 0.50 62 100 < 0.50 < 0.50 < 0.50 94 MWO5 6/4/2009 2.5 J 0.26 J 28 J 51 J < 0.2 < 0.2 < 0.2 83 J MWO5 12/9/2009 0.19 J < 0.1 2.4 4.1 < 0.1 < 0.1 < 0.1 7 MWO5 6/9/2010 9.8 1.9 12 21 < 0.1 < 0.1 < 0.1 22 MWO5 12/8/2010 0.27 J 0.16 J 4.7 6.6 < 0.1 < 0.1 < 0.1 17 MWOS= 6/8/2011 8.6 1.8 21 - 43 < 0.1 ` < 0.1 < 0.1 ',.': 34 MWO5 , 6/23/2011 39 4.3J'. 38 `° 82 9J . f, <1 .._`.<1 57 MWO5 ' .7/21/2011; ` 210 45 450 ,600 <1.0 ;<1.0 <1.0 410 MW21 6/14/2007 10800 J 603 J 1350 J 4240 J 5.1 22.5 98.8 639 J MW21 12/4/2007 11600 572 1710 3910 < 40 < 40 54.2 J 666 MW21 6/4/2008 5,000 380 1,100 2,800 < 10 < 10 35 J 830 MW21 12/3/2008 4,400 390 1,200 2,500 < 10 < 10 30 J 840 MW21 6/4/2009 4,300 470 1,200 3,000 < 2.5 < 2.5 34 780 MW21 12/9/2009 5,500 350 1,300 2,800 < 20 < 20 65 J 790 MW21 6/9/2010 14,000 610 1,100 2,800 < 20 22 J 140 520 MW21 12/8/2010 9,100 390 1,500 3,000 < 20 < 20 54 J 840 MW21 ' 6/8/2011 11,000 810 . 1,400 3,300 `<20 <20 '. ; , 60 J = 620 MW21 6/23/2011 ' 14,000 1,100 1,700 °` 4,500 < 10 < 10 . '46 J 510 MW21 7/24/2011 15,000 1,200 ' = 1,700 "; 4,500 `_ <10 <10 .. ` 49 J . - 700 MW26 6/14/2007 174 6.2 13.6 9.8 J < 0.5 < 0.5 0.52 J 6.4 MW26 12/4/2007 38.2 0.49 J 1.1 0.58 J < 0.2 < 0.2 < 0.25 < 0.93 U MW26 6/3/2008 4.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 3.2 MW26 12/3/2008 190 3.5 8.5 1.7 < 0.1 0.34 J 1.2 15 J MW26 6/4/2009 410 13 J 9.6 J 18 J < 0.5 0.74 J 1.3 J 21 MW26 12/9/2009 91 2.7 36 5.1 < 0.5 < 0.5 < 0.5 120 MW26 6/9/2010 980 44 56 100 < 0.5 2.6 2.1 J 54 MW26 12/8/2010 220 5 2.7 4.6 < 0.5 < 0.5 0.66 J 41 J MW26 6/8/2011 230 4.8 58 3.9 <0.5 <0.5 0.65J 15 MW26 6/23/2011 290 8.1 15 7.8 <1 < 1 < 1 ' 25 MW26' . 7/21/2011 , 300 ; 9.3 ° 24 , _ `13 <1.0 <1.0 <1.0 50 MW65 8/30/2010 17,000 1,100 2,200 6,300 < 10 < 10 43 J 630 MW65 12/8/2010 18,000 1,600 2,400 6,500 < 10 < 10 81 670 MW65 12/8/2010 21,000 1,600 2,400 6,600 < 20 < 20 90 J 640 MW65 6/8/2011 13,000 1,500 1,400 ° ` 4,700 - < 10 <' 10 35 J 390 MW65 6/8/2011 12,000 1,500 1,400 4,900 <10 <10 351 400 MW65 6/23/2011 _ 15,000 1,900 2,000 .6,200 <20 <20 „,'-351 480 MW65 7/21/2011 16,000 1,700 2,100 6,000 . <20 ., <20 33 J 670 Page 1 of 2 Table 5 VOC Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Sample JD I Samp.Date Benzene Toluene Ethylbez zene Xylenes ` 1,2-DCA IPE MTBE' Naphthalene Unit: ug/L ug/L ug/L; ug/L ' ug/L ugh ugh- :ug/L Area 2 UW06 6/9/2010 2.1 0.15 J 4.2 < 0.1 < 0.1 0.13 J 8.8 1.1 UW06 12/8/2010 3.3 0.34 J 4.9 0.19 J 0.26 J 0.34 J 21 2.2 UW06 6/8/2011 2.6 0.17 J = 6.2 1.2 < 0.1 0.27 J 17 1.6 UW06 6/23/2011 4.9 0.19 3 13 5.3 0.67 0.36 J 20 5.9 UWO6 7/21/2011. 3.7 0.20 J 6.5 1.9 0.61 0.52 25 3.7 UW08 6/14/2007 816 J 9.2 87.5 13.8 < 0.5 42.8 2390 J 90.4 UW08 6/14/2007 816 14.1 84.7 25.8 J < 5 43.5 2260 J _ 93.5 UW08 12/5/2007 61.9 J 2 13.8 J < 0.56 2.3 J 45.1 71.6 25.7 UW08 12/5/2007 47.8 J 1.3 10.4 J < 0.56 < 0.2 UJ 41.3 62.4 21.1 UW08 6/4/2008 1,000 6.8 J 80 3.8 J < 2 34 3,200 78 UW08 12/4/2008 220 2.1 J 35 2.5 J 9.8 J 28 610 19 UW08 6/4/2009 770 11 J 69 16 J < 5 26 2,300 110 UW08 12/8/2009 270 3.2 J 36 2.6 J < 2 21 940 29 UW08 6/9/2010 530 13 77 49 < 1 28 1,600 97 UW08 12/8/2010 120 1.5 J 24 2.2 J 5.4 18 390 14 UW08 6/8/2011 720 14 110 36 < 1 26 1,500 100 UW08 6/23/2011 680 16 J 80 16J < 5 221 , 1,800 66 UW08 7/21/2011 1,100 16 J 110 29 <5.0 26 2,600 130 MW68 8/30/2010 18 2.4 6.7 58 12 4.2 _ 43 _ 0.96 MW68 12/8/2010 390 27 91 270 26 6.8 220 71 MW68 6/8/2011 160 33 73 510 < 1 6.7 240 57 MW68 6/23/2011 _ 90 14 30 150 17 6.1 130 17 MW68 7/21/2011 99 15 45 110 15 6.0 130 25 MW69 5/24/2011 0.12 J < 0.1 < 0.1 0.17 J 0.46 J 6.5 95 5.6 MW69 6/8/2011 <0.1 < 0.1 < 0.1 < 01 0.23 J 2.8 41 0.4 J MW69 6/23/2011 < 0.1 < 0.1 < 0.1 < 0.1 0.32 J 5.1' ` 70 0.19 J MW69 7/21/2011 <0.10 <0.10 <0.10 <0.10 0.28 J 5.2 68 0.36 J Notes: A blank cell indicates that the analyte was not determined by the associated method. All results presented in ug/L. IA shaded cell indicates sampled after injection (May2011) DCA - Dichloroethane IPE - Isopropyl ether J - Estimated value MTBE - Methyl tert-butyl ether ug/L - Micrograms per liter UJ - Not detected and the detection limit is estimated value U - Not present above the associated level; blank contamination exists Page 2 of 2 This page intentionally left blank Table 6 MNA Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Laboratory Analysis Field Measurement Sample ID Sample Date Br Cl F H2S Mg Methane NO3 NO2 SO4 S2 Depth to Water DO pH Temp Specific Conductance Unit: mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Feet mg/L SU °C uS/cm Batch 5/16/2011 - - - - - - - - 766 - - - - - - Area 1 MWO5 12/9/2009 - - - - - - - - 4.3 J - 8.32c 2.43 8.95' IT. 7T 0.1 MWO5 6/9/2010 <2 1.2 J <0.4 <0.054 19.6 - <0.25 <0.4 5.5 0.11 J 7.03 2.5 6.08 17.91 0.057 MWO5 12/8/2010 - - - - - 0.1 - - - - 6.66 0.55 6.83 I9.9$ 0.094 MWO5 6/8/2011 < 2 ' 2.3 < 0.4 0.12 J 4.15 0.45 ' < 0.25 < 0.4 14.8 < 0.054 8.58 0.0 7.25' 17.91 0.073 MWO5 6/23/2011 < 2 • . 3.1 J < 0.4 0.43 208 1.9 1.2 J < 0.4 12.1 J 0.36 7.47 1.66 6.0TY 28.31 0.111 MWO5 7/21/2011 <2 3.8 <0.40 0.075 J 8.42 1.6 <0.25 <0.40 <1.5 <0.54 8.87 1.52 7.21 19.72 0.085 MW21 12/9/2009 - - - - - - - - 1.6 J - 6.34 1.52' 7.98 19.86 0.94 MW21 6/9/2010 < 2 31.3 < 0.4 < 0.054 19.5 - < 0.25 < 0.4 < 1.5 < 0.054 5.33 1.55 6.44 21.44 0.606 MW21 12/8/2010 - - - - - 6 - - - - 8.59 0.47 6.68 22.71 0.544 MW21 6/8/2011 < 2 33.7 < 0.4 < 0.054 19 5.9 < 0.25 < 0.4 6.6 < 0.054 6.24 0.27 6.42 22.12 0.627 MW21 6/23/2011 < 2 32.7 < 0.4 < 0.054 19.3 7.2 < 0.25 <0.4 < 1.5 < 0.054 6.89 0.15 6.14 21.97. 0.529 MW21 7/21/2011; <2 36.9 <0.40 <0.054 . 18.9 5.1 <0.25 <0.40 <1.5 ; <0.054 6.79 0.73 6.40 24.72 20.4. 0.612 -lea MW26 12/9/2009 - - - - - - - - 8.4 - 6.26 0.34 7.87 MW26 6/9/2010 < 2 6.2 < 0.4 < 0.054 9.54 - < 0.25 < 0.4 < 1.5 0.061 J 5.20 0.49 6.45- 22 06 0.338 MW26 12/8/2010 - - - - - 2.9 - - - - 8.39 0.31 6.91 23.12 0.313 MW26 6/8/2011 < 2 6.1 < 0.4 < 0.054 4.55 5.8 < 0.25 < 0.4 1.8 J - 0.061 J 6.26 0.15 6.65 23.00 0.304 MW26 6/23/2011 < 2 6.5 < 0.4 < 0.054 7.17 6.1 < 0.25 < 0.4 3.6 J < 0.054 6.57 0.17 - 6.25 21.61 0.264 MW26 7/21/2011 <2 7.4 <0.40 <0.054 8.14 8.6 <0.25 <0.40 <1.5 0.17 6.79 0.27 6.72 23.35 0.327 MW65 8/30/2010 < 2 4.8 < 0.4 < 0.054 20.5 1.6 < 0.25 < 0.4 1.9 J < 0.054 6.98 1.64 5.25 23.2 U.03 /3 MW65 12/8/2010 - - - - - 2.8 - - - - 8.76 1.46 6.91 23.47 0.327 MW65 12/8/2010 - - - - - 3.1 - - - - - - - - - MW65 6/8/2011 128 7.8 < 0.4 <0.054 43.9 1.4 < 0.25 < 0.4 109 . < 0.54 - 6.56 0.3 6.51 22.8 0.648 MW65 6/23/2011 80.9 6.7 = < 0.4 < 0.054 35.9 2.1 < 0.25 < 0.4 70.3 < 0.054 6.93 0.13 6.17 22.77 0.433' MW65 7/21/2011, • 24.5 8.1 <0.40 <0.054 27.1 2.2 <0.25 <0.40 12.6 , <0.054 7.13 0.43 6.47 24.52 0.423 Page 1 of 2 J UJ U mg/L Br Ca Table 6 MNA Analytical Summary - Injection Study BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Laboratory Analysis Field Measurement Sample ID Sample Date Br Cl F H2S Mg Methane NO3 NO2 SO4 S2 Depth to Water DO „ pH Temp Specific Conductance Unit mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L Feet mg/L SU °C uS/cm Area 2' UW06 6/9/2010 < 2 3.7 < 0.4 0.061 J 1.8 - < 0.25 < 0.4 2.1 J 0.061 J 6.25 2.84 4.97 17.23 0.155 UW06 12/8/2010 - - - - - 0.2 - - - - 6.93 3.99 5.95 19.59 0.048 UW06 6/8/2011 < 2 4.3 < 0.4 < 0.054 ' 2.23 0.24 < 0.25 <:0.4 3.5 J < 0.054 7.06 0.95 ; 6.05 18.31° 0.039 UW06 ' 6/23/2011 < 2 5.5 < 0.4 < 0.054 . 3.13 0.19 < 0.25 ;< 0.4 2.7 J < 0.054 6.70 0.68 5 00 19.11 0.058 UW06 ` 7/21/2011 <2 5.2 <0.40 <0.054 ° 2.86 0.18 <0.25 <0.40 <1.5 <0.054 UJ 6.81 1.13 5.14 20.75 0.038 UW08 6/9/2010 < 2 14.2 < 0.4 < 0.054 41.1 - < 0.25 < 0.4 8.7 < 0.054 4.51 2.1 6.25 18.88 0.87 UW08 12/8/2010 - - - - - 0.36 - - - - 5.65 3.03 6.01 15.53 0.856 UWO8 6/8/2011 < 2 14.3 < 0.4 < 0.054 42.2 0.29 < 0.25 < 0.4 15.1 < 0.054 5.45 0.53 6.23 21.56 0.843 UW08 6/23/2011 < 2 13.4 < 0.4 <0.054 38.3 0.16 < 0.25 < 0.4 14.3 < 0.054 5.26 0.99 5.73 20.78 0.712 UW08 7/21/2011 <2 13.3 <0.40 <0.054 40.3 0.14 <0.25 <0.40 8.7 <0.054 5.16 1.13 6.22 22.27 0.825 MW68 8/30/2010 < 2 20.8 < 0.4 < 0.054 5.37 � 1 < 0.4 3.7 J < 0.054 6.77 4.9 5.15 21.53 0.212 MW68 12/8/2010 - - - - - 0.35 - - - - 6.65 0.44 6.65 18.46 0.342 MW68 6/8/2011 250 20.5 < 0.4 < 0.054 37.5 0.24 < 0.25 < 0.4 197 < 0.054 7.08 0.62 6.62 20.84 0.642 MW68 6/23/2011 188 22.3 < 0.4 < 0.054 30.5 0.12 < 0.25 < 0.4 131 < 0.054 6.78 0.92 5.83 20.58 0.505 MW68 7/21/2011 152 27.2 <0.40 <0.054 23.8 0.15 0.45 J <0.40 100 <0.054 6.91 0.37 6.18 21.27 0.540 MW69 5/24/2011 < 2 12.6 < 0.4 < 0.054 41.6 - .32 J < 0.4 28.7 < 0.11 9.14 8.69 6.01 17.94 0.304 MW69 6/8/2011 < 2 10.9 < 0.4 < 0.054 8.73 0.039 < 0.25 < 0.4 28.4 < 0.054 6.10 4.54 6.33 19.76 0.246 MW69 6/23/2011 < 2 10.5 < 0.4 < 0.054 22.7 0.012 J < 0.25 < 0.4 17.8 < 0.054 6.67 4.07 5.40 18.31 0.163 MW69 7/21/2011 <2 10.9 <0.40 <0.054 34.4 0.005 J <0.25 <0.40 10.8 <0.054 6.26 4.05 4.41 20.69 0.185 Notes: A shaded cell indicates sampled; after injection (May 2011). 1 Analyte was not determined by the associated method Estimated value Not detected and the detection limit is estimated value Not present above the associated level; blank contamination exists Milligrams per liter Bromide Calcium Cl F H2S Mg Na NO2 NO3 Chloride Fluoride Hydrogen sulfide Magnesium Sodium Nitrite Nitrate S SO4 TOC DO Temp SU °C uS/cm Sulfide Sulfate Total Organic Carbon Dissolved oxygen Temperature standard units Degrees Celcius microsiemens per centimeter Page 2 of 2 Si80J1H SCALE IN FEET 0 2000 QUADRANGLE LOCATION SOURCE: USGS 7.5' TOPOGRAPHIC QUADRANGLE MTN. ISLAND LAKE, NC — DATED 1993 805` a fl A) y�j (1 FIGURE 1. LOCATION MAP BP/TRANSMONTAIGNE TERMINAL BP SITE NO. 4762/SOUTHEAST TERMINAL CHARLOTTE, NORTH CAROLINA Prepared for: BP PRODUCTS DRAWN BY: TSH ROU, HORN CAROUNA 27580 • sc DATE: 0IMAR04 PROJECT NO. Fig. 1 • ■ V u ■■ ■ Fes% • ES41 r\ ES19,:,. i j� `\ • • \ _/ i - I` ES33' '\ OMP01 • r MPo3 ii A___ ^ 5 ES32 :i PMW07 •� i J-�_i� __;�` .. ---- -_ Ip DPEW01 `V PMW02 jI ,�n'Poz \ ij • \ i I I l ,, l i • Dwoe i DW06 \ i i _ •E514 _� •ES31 �� --'� 'I I it i • ..� 11 ..� UW07 it . '� DW09 • I; ,I V � y _ f� ••AS01 ii 11 E513 ! I I i MPO6 •PMW03 11 11-IPL. 1 f !COVERED MU LEPIPEs ,___-+� I I • �:., I / I LoaDiNc -� n -'DP 0 — T02A i 11 I I J ancK ES12 -! !_NI;0134 AS-6 I �= =- _ -____ i ES29 E507 / • UWO I UW 1 f, E§36 1-Y� -a,«« 1 i 1 I .: • • ' MW66� i ---/----1�— �P'\ - ! °.' Es15 — NIlN67 Es30• I li N j j �i i �oz i I I-`-; I IUWO7n 7 In i i illi I . ' �\ MW68� ' , ..-.-_._-_ - i 1 DW01A• iw UWO6 i a• i1 I rot• .wo1 �. I UW10 ' E; --'' ES26 1 I i I---- ��--• UWO2 i I I !� —� v�o7 • •uw11—II f _ - -, MW12,� ,IUVV� VE03 • E803-ES37 t - •_ W20 • W48-- • -`-- • DW02 l i ESO4 ES.10• I' MW27, -• •MW2�VE02-� �- •--- iES38 _- =• -rv---- - ES020 MW 57 I I I o • E'so1 ,4 rEb8 •MW65 oV-eoi_ _. I _._._ ----- ------------- I VE06 • • .•_MW47 -_... I ES I 1 // • VE04-MW05- • -_ I' ......._ _._ ._ ;,•,,--- �� MW43 is I it N. j i /'- ES05SR �----- W51 ▪ i --"‘ I i - l� ESO:ref .__.-.,E911•i �! i 1 �ESO6\ C� `EOU PMENT MW42 ,l • MW-55 • IO,� Nc�osugEIRW02 MW37_ _ �.., - • DWOS-.T I •�� •MW50 :, ES20 ---7 _ __ - MW3�� M�45 A - ES18• \ AS-5 W36 AS 4, ,t > ` ='� I MW� AS02 �...�� •MW36; • ES26 x _ • P WO8 \ ' YW01 \ MVYUO-_-- 7 r - �:=©wo4--MW3W Former National Oil Terminal Property DWO3 • PW06 •PMWO9 • • W56 /MW-53 MW-52 • MW14R• ic PMWO5 • PMWO4 • PMW11 • PMW12 • 0 50 150 Legend m Y- Treeline — — Fence Line — — Property Line Railroad DPVES Dual Phase Vacuum Extraction System Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DW01 • Groundwater Monitoring Well uwo7 Groundwater Monitoring Well Missing as of 03/05 ES05 0 Groundwater Monitoring Well Abandoned 05/05 AS- V Air Sparging (AS) Well MW-. Pilot Study Monitoring Well SCALE AS SHOWN CONFlDENTVL-ALL RIGHTS RESERVED -PROPERTY OF ROD NORTH CAROUNA 27560 DESIGNED Br DATE Figure 2. Site Plan DRAWN B, DATEBP Terminal 4762/ TSH 04AUG11 Southeast Terminal CHECKED BY DATE Charlotte, North Carolina MN 04AUG11 CONTRACT NO. DRAWING NO. REV. APPROVEDDATE MNN 04AUG11 J3-00004762.01 FIGURE-2 0 DW10• •I ES13 !COVERED ILOADING L., RACK ES9 ES07 Ii• • ES1 • ES01 ;" I? MW27 "; ®MW65 if B r / ` .,MW20 ; f MW26 VE04--MW05 - ,. a - 1 rn -- _..----- - =_-- i MW43 @ I _ 'ti -- - -- AREA 1 ESO8DR ES12 ES14 I` L. ESOSSf- I UW05! ES15 -IU� MULTIPLE PIPES •- �----- _ 11L 767 ._. IE- I,r-- �, AREA2=��- ;if L' i i; TII T02 4 • 1' ! MW69 • 1 II l� I li j l DPEW02 AS06* i MW6 `(y�Tz_I ,fie MW6 UVV10-DW_01A• l W06 TAw; • f 1 ES28 i`t" I - __ 1 __-__.- VE07 `! @ UWO2 1 •UW11.--- ' ,I 1! -j-�_NIW1'2 x@ VE 3 t @ • ES03 _ _ _. - �! M 21 ' • MWt48 _.._._ - -. • DWO2 VEO > -7 -t— -, r,--- ---- ---_- ES30 • @ — ES37 t� RW03 _ _e + ES38 • .._ I II ES26 r @ _- -_ •®4-- .®-fir. a IVV47 I @I �, a1 - MW1 1 @j 5ji --; 7 p.N1'.: / ES05SR -- --.� i @ 11 2 ES05Df 1 @ 1 -------; ES1 ,' @' MV�144 MW42 RWO2 -, MW39 SO5 M1N MW4 W37-_ W50 1 REA-3 W36 r, • MW-55 TANK • • ••AS01 MPO6 •PM • L< TO2A • MW-57 DWO1 • 0 Legend Property Line Groundwater Monitoring Well Biosparge Well Abandoned Monitoring Well Former DVE/Pump & Treat System Layout (1985-1994, 1994-2000) Primary Test Well Secondary Test Well 80 SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED-PRRPERTY OF RDU, NORTH CAROLINA 27560 DRAWN BY TSH CHECKED BY MN APPROVED BY MN DATE 14APR10 DATE 14APR10 Figure 3. Biosparge Test Well Locations BP Terminal 4762/ Southeast Terminal CONTRACT NO, DRAWING NO. DATE 14APR10 J3-00004762.01 FIGURE-3 REV, 0 I i DWO6 �. •ES14 i i DW10 : ES08DF ., o.. E I ES13 COVERED ES29 ES07 i• • L.• • LOADING RACK ES12 • UW05 • I 1` �UW04 II \� UW101} , —4i V• 7 _-_MW12 RWO3 • ES01 ES10 • /LJ/ MW27 jj`�' r MULTIPLE PIPES • DPEWO 2 AS06*I MW66• •MW67 I sT- . //AF T, r, • • 1 1 UW02" i V i---- - 1 / ,MW20 VE04 AREA 1 • ES31 a • Q TANK S UU I� D 112 MW43 1 • MW5 1 I / o ' f-- __ / / / • --—_IVI,V�l44 i �� �� MW42 • ==; I ,,---„ �` •DWO5 RWO2 /j'�k41N37-.__.._.__/' TANK yi /fQES20 ` r-- _ _I MW39 jjMMW50 /IE8/ —=AS0n'i.bII• •AEA3 c W4.1 M/ W38 M17U36 I \„ --_� 47 • ES26 TANK 111 --�� • 28 II 1 ESO3 _---—E---S37I • DWO2 • TANK 11, TANK 117 • L TO2A ES30 # III • IL -,/ ,f ESO5DRN ESO5SR ES11• TANK`` ost • MW-55 „_• • MW-57 TANK 10� /1 ) • )9 • ••AS01 MPO6 •PM' GIMP B 0 p DWO1 • Legend Property Line Groundwater Monitoring Well Biosparge Well X Abandoned Monitoring Well Injection Location of Sulfate/Bromide Former DVE/Pump & Treat System Layout (1985-1994, 1994-2000) Injection Pilot Study Wells hSW, 0 80 SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF RDU, NORTH CMOUNA 27560 DRAWN BY TS H CHECKED BY MN APPROVED BY MN DATE 04AUG11 DATE 04AUG11 DATE 04AUG11 J3-00004762.01 Figure 4. Injection Pilot Study Well Locations BP Terminal 4762/ Southeast Terminal CONTRACT NO. DRAWING NO. FIGURE-4 REV. 0 Appendix A Laboratory Analytical Reports • January 17, 2011 • June 23, 2011 • July 21, 2011 liLancaster r Laboratories Analysis Report 2425 Now Holland Pike, PO Box 12425, Lancesler, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www-lancasterlabs.com ANALYTICAL RESULTS Prepared by: Lancaster Laboratories 2425 New Holland Pike Lancaster, PA 17605-2425 January 24, 2011 Project: BP 4762 Submittal Date: 01/18/2011 Group Number: 1229416 PO Number: 003 W6-0011 Release Number: FRISCH State of Sample Origin: NC Client Sample Description Trip Blank Water MW-19 Water MW-36 Water MW-38 Water MW-39 Water MW-41 Water MW-49 Water DUP Water Prepared for: Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 Lancaster Labs (LLI) # 6185351 6185352 6185353 6185354 6185355 6185356 6185357 6185358 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC URS Corporation COPY TO Attn: Martha Meyers -Lee *Erorao asertries Analysis Report 2425 Now Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2661 • www.lancasterlabs.com Questions? Contact your Client Services Representative Lynn M Frederiksen at (717) 656-2300 Ext. 1501 Respectfully Submitted, Lawrence_Psi. Tayior Senior Specialist *Imarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasteriabs.com Sample Description: Trip Blank Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC Project Name: BP 4762 Collected: 01/17/2011 Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 762TB Page 1 of 1 LLI Sample # WW 6185351 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Dilution Factor 1 1 1 1 1 1 1 1 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 5030B 1 C110202AA 1 C110202AA Analysis Analyst Dilution Date and Time Factor 01/20/2011 17:45 Kerri E Legerlotz 1 01/20/2011 17:45 Kerri E Legerlotz 1 *=This limit was used in the evaluation of the final result 1ILancaster L aboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-19 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-19 Project Name: BP 4762 Collected: 01/17/2011 15:00 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76219 Page 1 of 1 LLI Sample # WW 6185352 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 5,600 N.D. 650 36 590 270 20 J 460 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 50 5.0 5.0 5.0 5.0 5.0 5.0 5.0 250 25 25 25 25 25 25 25 Dilution Factor 500 50 50 50 50 50 50 50 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110202AA 1 C110202AA 2 C110202AA Analysis Analyst Date and Time 01/20/2011 18:07 Kerri E Legerlotz 01/20/2011 18:29 Kerri E Legerlotz 01/20/2011 18:07 Kerri E Legerlotz 01/20/2011 18:29 Kerri E Legerlotz Dilution Factor 50 500 50 500 *=This limit was used in the evaluation of the final result ilVEzarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-36 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-36 Project Name: BP 4762 Collected: 01/17/2011 14:15 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76236 Page 1 of 1 LLI Sample # WW 6185353 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 4,800 N.D. 910 12 J 220 380 49 400 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 50 5.0 5.0 5.0 5.0 5.0 5.0 5.0 250 25 25 25 25 25 25 25 Dilution Factor 500 50 50 50 50 50 50 50 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110202AA 1 C110202AA 2 C110202AA Analysis Analyst Dilution Date and Time Factor 01/20/2011 18:51 Kerri E Legerlotz 50 01/20/2011 19:12 Kerri E Legerlotz 500 01/20/2011 01/20/2011 18:51 19:12 Kerri E Legerlotz 50 Kerri E Legerlotz 500 *--This limit was used in the evaluation of the final result •Ezarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.Iancasterlabs.com Sample Description: MW-38 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-38 Project Name: BP 4762 Collected: 01/17/2011 14:20 Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76368 by SS Page 1 of 1 LLI Sample # WW 6185354 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 84 N.D. 230 N.D. 14 160 67 1,600 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 2.0 2.0 2.0 2.0 2.0 2.0 2.0 20 10 10 10 10 10 10 10 100 Dilution Factor 20 20 20 20 20 20 20 200 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Laboratory Sample Analysis Record Method Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110202AA 1 C110202AA 2 C110202AA Analysis Date and Time 01/20/2011 19:34 01/20/2011 01/20/2011 01/20/2011 19:56 19:34 19:56 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Dilution Factor 20 200 20 200 *=This limit was used in the evaluation of the final result 416Lancaster lir Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax;717-656-2681 • w.ww.lancasterlabs.com Sample Description: MW-39 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-39 Project Name: BP 4762 Collected: 01/17/2011 14:45 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76239 Page 1 of 1 LLI Sample # WW 6185355 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 1,600 N.D. 160 5.4 78 61 190 540 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 10 1.0 1.0 1.0 1.0 1.0 1.0 10 50 5.0 5.0 5.0 5.0 5.0 5.0 50 Dilution Factor 100 10 10 10 10 10 10 100 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA Analysis Analyst Dilution Date and Time Factor' 01/20/2011 20:18 Kerri E Legerlotz 10 1 C110202AA 01/20/2011 20:39 Kerri E Legerlotz 100 1 C110202AA 01/20/2011 20:18 2 C110202AA 01/20/2011 20:39 Kerri E Legerlotz 10 Kerri E Legerlotz 100 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605=2425 •717-656-2300 Fax: 717-656-2681• www.lancasterlabs.com Sample Description: MW-41 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-41 Project Name: BP 4762 Collected: 01/17/2011 14:40 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76241 Page l of 1 LLI Sample # WW 6185356 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 27 N.D. 94 N.D. N.D. 220 76 790 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 1.0 1.0 1.0 1.0 1.0 1.0 1.0 10 5.0 5.0 5.0 5.0 5.0 5.0 5.0 50 Dilution Factor 10 10 10 10 10 10 10 100 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110202AA 1 C110202AA 2 C110202AA Analysis Analyst Date and Time 01/20/2011 21:01 Kerri E Legerlotz 01/20/2011 21:23 Kerri E Legerlotz 100 Dilution Factor 10 01/20/2011 21:01 Kerri E Legerlotz 10 01/20/2011 21:23 Kerri E Legerlotz 100 *=This limit was used in the evaluation of the final result ILaboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-49 Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC MW-49 Project Name: BP 4762 Collected: 01/17/2011 14:40 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 76249 Page 1 of 1 LLI Sample # WW 6185357 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 690 N.D. 68 7.7 J 100 69 580 590 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 5.0 2.0 2.0 2.0 2.0 2.0 5.0 2.0 25 10 10 10 10 10 25 10 Dilution Factor 50 20 20 20 20 20 50 20 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110211AA 1 C110202AA 2 C110211AA Analysis Analyst Date and Time 01/20/2011 21:45 Kerri E Legerlotz 01/21/2011 12:35 Stephanie A Selis 01/20/2011 21:45 Kerri E Legerlotz 01/21/2011 12:35 Stephanie A Selis Dilution Factor 50 20 50 20 *--This limit was used in the evaluation of the final result IILaboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • wwwiancasterlabs.com Sample Description: DUP Water 4762 COC: 7401 Old Mount Holly Rd -Charlotte, NC DUP Project Name: BP 4762 Collected: 01/17/2011 by SS Submitted: 01/18/2011 11:45 Reported: 01/24/2011 12:24 762FD Page 1 of 1 LLI Sample # WW 6185358 LLI Group # 1229416 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 As Received Result ug/1 86 N.D. 410 N.D. 14 290 85 1,400 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 2.0 2.0 2.0 2.0 2.0 2.0 2.0 50 10 10 10 10 10 10 10 250 Dilution Factor 20 20 20 20 20 20 20 500 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep Laboratory Sample Analysis Record Method Trial# Batch# SW-846 82608 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B 1 C110202AA 1 C110211AA 1 C110202AA 2 C110211AA Analysis Date and Time 01/20/2011 22:28 01/21/2011 12:57 01/20/2011 01/21/2011 22:28 12:57 Analyst Kerri E Legerlotz Stephanie A Selis Kerri E Legerlotz Stephanie A Selis Dilution Factor 500 20 500 20 *=This limit was used in the evaluation of the final result 4&Lancaster lir Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.Iancasterlabs.com Quality Control Summary Client Name: Atlantic Richfield c/o URS Group Number: 1229416 Reported: 01/24/11 at 12:24 PM Matrix QC may not be reported if site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. Analysis Name Page 1 of 2 Laboratory Compliance Quality Control Blank Blank Blank Report LCS LCSD LCS/LCSD Result MDL** LOO Units %REC %REC Limits RPD RPD Max Batch number: C110202AA Sample number(s): 6185351-6185358 Benzene N.D. 0.10 0.50 ug/1 99 95 80-120 4 30 1,2-Dichloroethane N.D. 0.10 0.50 ug/1 107 104 80-127 3 30 Ethylbenzene N.D. 0.10 0.50 ug/1 100 96 80-120 5 30 di -Isopropyl Ether N.D. 0.10 0.50 ug/1 94 93 80-120 1 30 Methyl Tertiary Butyl Ether N.D. 0.10 0.50 ug/1 94 93 73-120 0 30 Naphthalene N.D. 0.10 0.50 ug/1 86 88 77-120 2 30 Toluene N.D. 0.10 0.50 ug/1 98 95 80-120 3 30 Xylene (Total) N.D. 0.10 0.50 ug/1 98 94 80-120 5 30 Batch number: C110211AA Sample number(s): 6185357-6185358 Benzene N.D. 0.10 0.50 ug/1 96 96 80-120 0 30 1,2-Dichloroethane N.D. 0.10 0.50 ug/1 94 93 80-127 1 30 Ethylbenzene N.D. 0.10 0.50 ug/1 95 96 80-120 1 30 di -Isopropyl Ether N.D. 0.10 0.50 ug/1 95 96 80-120 1 30 Methyl Tertiary Butyl Ether N.D. 0.10 0.50 ug/1 93 93 73-120 0 30 Naphthalene N.D. 0.10 0.50 ug/1 91 93 77-120 2 30 Toluene N.D. 0.10 0.50 ug/1 95 96 80-120 1 30 Xylene (Total) N.D. 0.10 0.50 ug/1 94 95 80-120 0 30 Sample Matrix Quality Control Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max Batch number: C110202AA Sample number(s): 6185351-6185358 UNSPK: P186808 Benzene 108 87-126 1,2-Dichloroethane 115 83-143 Ethylbenzene 110 80-140 di -Isopropyl Ether - 103 75-123 Methyl Tertiary Butyl Ether 99 73-125 Naphthalene 91 55-132 Toluene 108 83-127 Xylene (Total) 107 84-125 Batch number: C110211AA Sample number(s): 6185357-6185358 UNSPK: P187229 Benzene 103 87-126 1,2-Dichloroethane 112 83-143 Ethylbenzene 104 80-140 di -Isopropyl Ether 97 75-123 Methyl Tertiary Butyl Ether 94 73-125 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. 4&Lancaster lir Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Quality Control Summary Client Name: Atlantic Reported: 01/24/11 at Richfield c/o URS 12:24 PM Unspiked (UNSPK) = the sample Background (BKG) = the sample Analysis Name Naphthalene Toluene Xylene (Total) Sample Matrix Quality used in conjunction with the matrix spike used in conjunction with the duplicate MS %REC 89 104 102 MSD %REC MS/MSD Limits 55-132 83-127 84-125 Group Number: 1229416 Control RPD BKG RPD MAX Conc Surrogate Quality Control Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: EPA SW846/8260 (water-25m1) #1 Batch number: C110202AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene DUP Conc DUP RPD Page 2 of 2 Dup RPD Max 6185351 6185352 6185353 6185354 6185355 6185356 Blank LCS LCSD MS 110 104 .105 104 100 101 109 104 103 104 103 97 97 98 98 98 100 98 101 98 100 101 101 102 101 102 100 103 103 103 96 101 101 108 100 102 97 103 103 103 Limits: 77-114 74-113 77-110 78-110 Analysis Name: EPA SW846/8260 (water-25m1) #1 Batch number: C110211AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 6185357 6185358 Blank LCS LCSD MS 103 103 104 101 101 105 99 99 102 100 99 100 100 103 100 102 103 103 104 110 98 100 102 103 Limits: 77-114 74-113 77-110 78-110 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. `Lancaster ler Laboratories Case Narrative Project Name: BP 4762 LLI Group #: 1229416 General Comments: Through our technical processes and second person review of data, we have established that our data/deliverables are in compliance with the methods and project requirements unless otherwise noted or previously resolved with the client. The compliance signature is located on the cover page of the Analysis Reports. see the Laboratory sample Analysis Record section of the Analysis Report for the method references. All QC met criteria unless otherwise noted in an Analysis Specific Comment below. Refer to the QC summary for specific values and acceptance criteria. Project specific QC samples are not included in this data set Matrix QC may not be reported if site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. surrogate recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in an Analysis specific comment below. The samples were received at the appropriate temperature and in accordance with the chain of custody unless otherwise noted. Analysis specific comments: No additional comments are necessary. v 1.8.5 1/24/2011 12:26:34PM ucnhueld company 0 A BP affiliated company 12-3971r22q.Y,L /(9rg5 35 / -SS Laboratory Management Program LAMP Chain of Custody Record Page 1 of 1 BP/ARC Project Name: BP/ARC Facility No: Paw Creek -BP Req Due Date (mmfddlyy): 10-business days from receipt Rush TAT: Yes No X Lab Work Order Number: Lab Name: Lancaster Laboratories BP/ARC Facility Address: 7401 Old Mount Holly Road Consultant/Contractor: URS Corporation - North Carolina Lab Address: 2425 New Holland Pike, Lancaster, PA 17605 City, State, ZIP Code: Charlotte, NC Consultant/Contractor Project No: Paw Creek -BP - 38436544.104018 Lab PM: Lynn Frederiksen Lead Regulatory Agency: NCDENR DWM - UST Section Address: 1600 Perimeter Park Road, Suite 400, Morrisville, NC 27560 Lab Phone: 717.656-2300 California Global ID No.: Consultant/Contractor PM: Margaret Ness Lab Shipping Accnt: Lancaster: 1077-8526-4 Enfos Proposal No: 003W6-0011 Phone: 919-461-1100 Lab Bottle Order No: Accounting Mode: Provision X OOC-BU OOC-RM Emall EDD To: Martha_Meyers-Lee © urscorp.com Other Info: Stage: 40 Activity: 18 - Construclllnstall Remedial SystE lnvolce To: BP/ARC X Contractor Soil / Solid Water / Liquids' I m Requested Analyses Report Type & QC Level BP/ARC EBM: Greg Frisch EBM Phone: 216 271-8740 Total Number of Containers Unpreserved H2SO4 HNO3 HCI Methanol Standard X Full Data Package EBM Email: Greg.Frisch@bp.com Lab No. Sample Description Date Time 20 ea Comments Note: If sample not collected, indicate 'No Sample' in comments and single -strike out and Initial any preprinted sample description. Trip Blank I —) 7- j j -- V /� a 2 _X -- j j� W 9 I ,Soo 3 3 M MIN - 3t. 1-1 IS M Mir - 32 iq 20 M MO'29 l-tti5 m mo-ql lNO W WO - Lig 14410 - . -At Sampler's Name: S ckmes. s :5k Relinquishedd By / Affiliation Date Time Accepted By / Affiliation Date Time Samplers Company: URS Corporation - North Carolina // D y / ` - ���� '•fir j -17 -)I /700N , Shipment Method: FedEX Ship Date: j .- f' .) j Shipment Tracking No: 8 7 p 0 59 3T 30 35 --� } L� [ 1 1 r ! 1 C 1 1{J Special Instructions: Refer to attached Sample Kit Request for analytical scope of work. Contact Martha Meyers -Lee (919-461-1519) regarding all sample receipt and analytical non-conformance issues. THIS LINE - LAB USE ONLY: Custody Seals In Pla l eo Temp Blank No I Cooler Temp on Receipt: °F/47 ( Trip Blank:( No 1 MS/MSD Sample Submitted: Yes / €o Enfos Work Release W I:1991M7 BP/ARC LAMP COC Rev- 8 01/01/2099 Client: Client PM: Project: Location: Enfos Node: Enfos Project #: Date Needed: Sample Date: Invoice To: Analytical SOW: Subcontract No. Revision No. Date Page N/A 0 1/10/11 1 of2 BOTTLE REQUEST FORM (Email to: lfrederiksen(ntlancastcrlabs.com, TSpaide(slancasterlabs.com) BP Greg Frisch BP 4762 Epsom Salt Pilot Study 7401 Old Mount Holly Road, Charlotte, NC BP > USA > NC > MECKLENBURG > Paw Creek -BP > Install -Passive System >Amend Existing System To Be Determined Thursday. January 13, 2010 COB Week of January 17, 2010 [X] BP (Direct bill): [ ] Submit via Enfos system OR [ ] URS Corporation (subcontract) Consultant: Consultant PM: Consultant TL: URS Project #: ENFOS Work Release: URS Corporation Margaret Ness Scott Smida 38436645.1.04080 TBD Provision: 10 Account Mode: 40 WBS Activity: 80 Project Chemist: Martha Meyers -Lee, Morrisville Phone No.: 919-461-1519 [X] Submit to URS Corporation Methods Analyte List Reporting Limit Requirements' Ref No. Unit Rate Number of Water Samples SW-846 8260B (25 ml purge) Benzene Toluene Ethylbenzene Xylenes MTBE IPE Naphthalene 1,2-DCA 1 600 600 500 20 70 6 0.4 X-434 $95 7 (6 primary and 1 field duplicate), and 1 trip blank trg/1 Micrograms per liter DCA Diehloroethane IPE Isopropyl ether MTBE Methyl tcrt-butyl ether Analytical work is to he conducted in accordance with: • Technical Requirements For Environmental Laboratory Analytical Services BP Laboratory Management Program (141MP), Atlantic Rich field Company- a BP- affiliated company, Revision 09 — FINAL Issued: 07/30/2007 • UST Section Guidelines For The Investigation And Remediation Of Contamination From Non. -UST Petroleum Releases„ NC DENR, UST Section, July 1, 2007 , which is available at http://www.wastenotnc.orc/ust/docs/Non-t1STGuid053107.pdf Sample results are to be analyzed at the lowest dilution possible without harm to the instrument, and then at the proper dilution to ensure that regulatory levels arc achieved. Results are to be reported to the Method Detection Limit. Sample concentrations that are less than the PQL, but greater than the MDL are to be J-flagged. A trip blank will be included in the each shipment of VOA samples submitted to the laboratory. Analytical TAT: Laboratory Certification: Applicable Standard(s): Electronic Deliverable: Electronic Deliverable to: Standard (10 business days) NC DWQ NC 2L Laboratory report containing Case Narrative, summary of sample results and associated QC results, Sample Receipt paperwork, and COC record; HOD formatted in Excel for the EnviroData program; and electronic copy (pdf) of the invoice Martha Meyers -lee@ ursco.rp.com, (919) 461-15I9 Supplies Needed2: • 24 40-m1 VOA vials, prc-preserved with HCI, for the SW-846 8260B analysis (based on 3 vials per sample plus a spare set) • 1 Trip blank, consisting of 2-40 ntL VOA vials preserved with HC1 acid to a p11 <2. • Integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) DI H20: None 1 Detection limits shall be less than the PQL or NC Groundwater Protection Standard (21. ), whichever is lower, 2 Container types and numbers per State Guidelines P:1BP1ProjectsATerminals14762\Analytical\Analytical Requcsts1201 1\BP4762 Bottle Request Form Pilot Study_OI-10-11.doc Last printed 1 / 10/2011 10:20:00 AM Ship Supplies To: [ ] [Name] URS Corporation 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Phone No. (9191 461-1100 I X] Scott Smida URS Corporation 6135 Park South Drive, Suite 300 Charlotte, NC 28210 Phone No. 704-522-0330 [] Subcontract No. Revision No. Late Page N/A 0 1/10/11 2 of 2 JNamel PLEASE INCLUDE "4762-GWM" on the outside off the cooler to facilitate retrieval from our mailroom. Kit Request Taken By: Date: Kit Completed By: Date Sent: P_\RP\Projects\Terminal..s\4762\ nalytical\AnalyticalRequests\2011\BP476213ottle Request Form Pilot Study_01-10-11.doc Page 2 of 2 4&Lancaster lir Laboratories Environmental Sample Administration Receipt Documentation Log Client/Project: W LS Date of Receipt: I t < Time of Receipt: IRS Source Code: SO Unpacker Emp. No.: 730 Shipping Container Sealed: NO Custody Seal Present * : NO * Custody seal was intact unless otherwise noted in the discrepancy section Package: Not Chilled Temperature of Shipping Containers Cooler # Thermometer ID Temperature CC) Temp Bottle (TB) or Surface Temp (ST) Wet Ice (WI) or Dry Ice (DI) or Ice Packs (IP) Ice Present? Y/N Loose (L) Bagged Ice (B) NA Comments 1 o1li:cs t 0 Co` ` G �1 'I/ 6.))or 2 3 4 5 6 Number of Trip Blanks received NOT listed on chain of custody. Paperwork Discrepancy/Unpacking Problems: Sample Administration Internal Chain of Custody Name Date Time Reaso for Trans .. l \, Un ackin t c4 16I i i i 3 i t Place in Storage or ntt Entry Entry Issued by Dept. 6042 Management 2174.05 1IEties Y Explanation of Symbols and Abbreviations p The following defines common symbols and abbreviations used in reporting technical data: RL N.D. TNTC IU umhos/cm C meq g ug ml m3 J ppm ppb Dry weight basis Reporting Limit none detected Too Numerous To Count International Units micromhos/cm degrees Celsius milliequivalents gram(s) microgram(s) milliliter(s) cubic meter(s) BMQL MPN CP Units NTU ng F Ib. kg mg ul Below Minimum Quantitation Level Most Probable Number cobalt-chloroplatinate units nephelometric turbidity units nanogram(s) degrees Fahrenheit pound(s) kilogram(s) milligram(s) liter(s) microliter(s) less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be reliably determined using this specific test. greater than estimated value — The result is L. the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ). parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/I), because one liter of water has a weight very close to a kilogram. For gases or vapors, one ppm is equivalent to .one microliter of gas per liter of gas. parts per billion Results printed under this heading have been adjusted for moisture content. This increases the analyte weight concentration to approximate the value present in a similar sample without moisture. All other results are reported on an as -received basis. U.S. EPA CLP Data Qualifiers: Organic. Qualifiers A TIC is a possible aldol-condensation product B Analyte was also detected in the blank C Pesticide result confirmed by GC/MS D Compound quantitated on a diluted sample E Concentration exceeds the calibration range of the instrument N Presumptive evidence of a compound (TICs only) P Concentration difference between primary and confirmation columns >25% U Compound was not detected X,Y,Z Defined in case narrative Inorganic Qualifiers B Value is <CRDL, but >_IDL E Estimated due to interference M Duplicate injection precision not met N Spike sample not within control limits S Method of standard additions (MSA) used for calculation U Compound was not detected W Post digestion spike out of control limits * Duplicate analysis not within control limits + Correlation coefficient for MSA <0.995 Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis. Measurement uncertainty values, as applicable, are available upon request. Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our staff. This report shall not be reproduced except in full, without the written approval of the laboratory. WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF MERCHANTABILITY. IN NO EVENT SHALL LANCASTER LABORATORIES BE LIABLE FOR INDIRECT, SPECIAL, CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF LANCASTER LABORATORIES AND (B) WHETHER LANCASTER LABORATORIES HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Lancaster Laboratories which includes any conditions that vary from the Standard Terms and Conditions, and Lancaster hereby objects to any conflicting terms contained in any acceptance or order submitted by client. .Lancaster, Laboratores Analysis Report 2425 New Holland Pike, PO Sax 12425, Lancaster, PA 1760&2425.717.65B,2300.Faxi717.656.2661 • www.IancasterIabs.com ANALYTICAL RESULTS Prepared by: Lancaster Laboratories 2425 New Holland Pike Lancaster, PA 17605-2425 July 07, 2011 Project: BP 4762 Submittal Date: 06/24/2011 Group Number: 1253284 PO Number: 006KN-0002 Release Number: FRISCH State of Sample Origin: NC Client Sample Description Trip Blank Water MW-05 Water MW-21 Water MW-26 Water MW-65 Water MW-68 Water MW-69 Water UW-06 Water UW-08 Water Prepared for: Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 Lancaster Labs (LLI) # 6327437 6327438 6327439 6327440 6327441 6327442 6327443 6327444 6327445 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC URS Corporation COPY TO Attn; Martha Meyers -Lee 1 Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605.2425 •717-656-2300 Fax:717-656.2661 • www.lar oasteilabs.com Questions? Contact your Client Services Representative Lynn M Frederiksen at (717) 656-2300 Ext. 1501 Respectfully Submitted, Senior SpBcia1ist •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax; 717-656-2681 • www.lancasterlabs.com Sample Description: Trip Blank Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC Page 1 of 1 LLI Sample # WW 6327437 LLI Group # 1253284 Account # 12397 Project Name: BP 4762 Collected: 06/07/2011 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 TBMHC 11 CAT No. r Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge As Received Result ug/1 As Received As Received Method Limit of Detection Limit* Quantitation ug/1 ug/1 Dilution Factor 02898 Benzene 71-43-2 N.D. 0.10 0.50 1 02898 1,2-Dichloroethane 107-06-2 N.D. 0.10 0.50 1 02898 Ethylbenzene 100-41-4 N.D. 0.10 0.50 1 02898 di -Isopropyl Ether 108-20-3 N.D. 0.10 0.50 1 02898 Methyl Tertiary Butyl Ether 1634-04-4 N.D. 0.10 0.50 1 02898 Naphthalene 91-20-3 N.D. 0.10 0.50 1 02898 Toluene 108-88-3 N.D. 0.10 0.50 1 02898 Xylene (Total) 1330-20-7 N.D. 0.10 0.50 1 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. Laboratory Sample Analysis Record CAT Analysis Name Method Trial# Batch# Analysis Analyst Dilution No. Date and Time Factor 02898 VOC 25m1 SW-846 8260B 25mL 1 C111801AA 06/30/2011 00:04 Jason M Long 1 BTEX/MTBE/IPE/Nap,DCA purge 01163 GC/MS VOA Water Prep SW-846 5030B 1 C111801AA 06/30/2011 00:04 Jason M Long 1 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-05 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-05 Project Name: BP 4762 Collected: 06/23/2011 13:00 by SS Submitted: 06/24/2011 Reported: 07/07/2011 M5MHC Page 1 of 2 LLI Sample # WW 6327438 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) Reporting limits were raised due GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 to interference As Received Result ug/1 39 1.9 J 38 N.D. N.D. 57 4.3 J 82 from the sample RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010B EPA 300.0 ug/1 1,900 mg/1 7439-95-4 208 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F mg/1 N.D. 3.1 N.D. 1.2 N.D. 12.1 mg/1 7783-06-4 0.43 SM20 2510 B 00280 Specific Conductance n.a. 00200 pH The 40 CFR (within 15 the result umhos/cm 116 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 matrix. ug/1 50 mg/1 0.0335 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 mg/1 0.054 umhos/cm 1.7 SM20 4500 H/B Std. Units Std. Units n.a. 6.3 0.010 Part 136 requires that this analysis be performed immediately minutes) upon sample collection. Because this was not possible, may not be used for reporting purposes. SM20 4500 S2 D 10499 Dissolved Sulfide n.a. 0.50 00230 Sulfide 18496-25-8 0.36 Reporting limits were raised due to interference from mg/1 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 ug/1 150 mg/1 0.500 mg/1 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 0.16 umhos/cm 5.0 Std. Units 0.010 mg/1 mg/1 0.054 0.11 the sample matrix. 0.16 0.32 Dilution Factor 10 10 10 10 10 10 10 10 10 5 5 5 5 5 5 5 1 1 1 1 2 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-05 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-05 Project Name: BP 4762 `Collected: 06/23/2011 13:00 Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MSMHC Page 2 of 2 LLI Sample # WW 6327438 LLI Group # 1253284 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. ICAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 101848 WW SW846 ICP Digest (tot rec) 01505 Bromide 00224 Chloride __ 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide - 00230 Sulfide Laboratory Sample Analysis Record Method Trial# Batch# Analysis Analyst Dilution Date and Time Factor SW-846 8260B 25mL 1 C111801AA 06/29/2011 18:35 Jason M Long 10 purge SW-846 5030B 1 C111801AA 06/29/2011 18:35 Jason M Long 10 RSKSOP-175 1 111790026A 06/30/2011 19:15 Elizabeth J Marin 10 08/11/94 modified SW-846 6010B 1 111781848002 06/28/2011 17:28 John P Hook 5 SW-846 3005A 1 111781848002 06/27/2011 12:46 James L Mertz 1 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D. S2 D 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11175196602A 06/24/2011 21:59 Ashley M Adams 5 1 11179023001A 06/28/2011 10:40 Susan E Hibner 1 1 11181028002B 06/30/2011 21:30 Luz M Groff 1 1 11175020001A 06/24/2011 21:40 Luz M Groff 1 1 11179023001A 06/28/2011 10:40 Susan E Hibner 1 1 11179023001A 06/28/2011 10:40 Susan E Hibner 2 *=This limit was used in the evaluation of the final result •Ezarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681• wwwjancasterlabs.com Sample Description: MW-21 Water 4762 COC: 7401 Old Mount Holly Rd Project Name: BP 4762 Collected: 06/23/2011 13:20 Submitted: 06/24/2011 Reported: 07/07/2011 MHC21 - Charlotte, NC MW-21 Page 1 of 2 LLI Sample # WW 6327439 LLI Group # 1253284 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles SW-846 82 purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S CAS Number 60B 25mL 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010B 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. 00200 pH The 40 CFR (within 15 the result As Received Result ug/1 14,000 N.D. 1,700 N.D. 46 J 510 1,100 4,500 ug/1 7,200 mg/1 19.3 mg/1 N.D. 32.7 N.D. N.D. N.D. N.D. mg/1 N.D. umhos/cm 551 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 100 10 10 10 10 10 10 10 500 50 50 50 50 50 50 50 ug/1 ug/1 100 300 mg/1 mg/1 0.0067 0.100 mg/1 mg/1 2.0 2.0 0.40 0.25 0.40 1.5 mg/1 0.054 umhos/cm 1.7 SM20 4500 H/B Std. Units Std. Units n.a. 6.2 0.010 Part 136 requires that this analysis be performed immediately minutes) upon sample collection. Because this was not possible, may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. 2.5 4.0 0.50 0.50 0.50 5.0 mg/1 0.16 umhos/cm 5.0 Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 1000 100 100 100 100 100 100 100 20 1 5 10 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Sample 1 Description: MW-21 Water 4762 COC: 7401 Old Mount Holly Rd - Project Name: BP 4762 Collected: 06/23/2011 13:20 by SS Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC21 Fax:717-656-2681 • www.lancasterlabs.com Charlotte, NC MW-21 Page 2 of 2 LLI Sample # WW 6327439 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 100228 Sulfate 110293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide ,00230 Sulfide Laboratory Sample Analysis Record Method Trial# Batch# SW-846 8260B 25mL 1 C111801AA purge Analysis Date and Time 06/29/2011 19:19 SW-846 8260B 25mL 1 C111801AA 06/29/2011 19:41 purge SW-846 5030B 1 C111801AA 06/29/2011 19:19 SW-846 5030B 2 C111801AA 06/29/2011 19:41 RSKSOP-175 1 111790026A 06/30/2011 19:32 08/11/94 modified SW-846 6010B 1 111781848002 06/27/2011 21:31 SW-846 3005A 1 111781848002 06/27/2011 12:46 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 11175196602A 06/24/2011 1 11175196602A 06/28/2011 1 11175196602A 06/24/2011 1 11175196602A 06/24/2011 1 11175196602A 06/24/2011 1 11175196602A 06/24/2011 1 11179023001A 06/28/2011 1 11181028002B 06/30/2011 1 11175020001A 06/24/2011 1 11179023001A 06/28/2011 1 11179023001A 06/28/2011 22:43 19:45 22:43 22:43 22:43 22:43 10:40 21:30 21:40 10:40 10:40 Analyst Jason M Long Jason M Long Jason M Long Jason M Long Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 100 1000 100 1000 20 1 1 5 10 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.Iancasterlabs.com Sample Description: MW-26 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-26 Project Name: BP 4762 Collected: 06/23/2011 13:45 by SS Submitted: 06/24/2011 Reported: 07/07/2011 MHC26 LLI Sample LLI Group Account Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 Page 1 of 2 # WW 6327440 # 1253284 # 12397 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified As Received Result ug/1 290 N.D. 15 N.D. N.D. 25 8.1 7.8 ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 10 1.0 1.0 1.0 1.0 1.0 1.0 1.0 50 5.0 5.0 5.0 5.0 5.0 5.0 5.0 ug/1 ug/1 74-82-8 6,100 100 300 SW-846 6010B EPA 300.0 mg/1 7439-95-4 7.17 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 N.D. 6.5 N.D. N.D. N.D. 3.6 J mg/1 N.D. umhos/cm 228 mg/1 mg/1 0.0067 0.100 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.1 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 100 10 10 10 10 10 10 10 20 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result 4&Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-26 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-26 Project Name: BP 4762 Collected: 06/23/2011 13:45 Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC26 by SS Page 2 of 2 LLI Sample # WW 6327440 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep 007105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen - 01506 Nitrite Nitrogen 00228 Sulfate I,10293 Sulfide as H2S - 00280 Specific Conductance 00200 pH +` 10499 Dissolved Sulfide 00230 Sulfide Method SW-846 purge SW-846 purge SW-846 SW-846 Laboratory Sample Analysis Record Trial# Batch# 8260B 25mL 1 C111801AA Analysis Date and Time 06/29/2011 20:03 8260B 25mL 1 C111801AA 06/29/2011 20:25 5030B 5030B RSKSOP-175 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C111801AA 2 C111801AA 1 111790026A 1 111781848002 1 111781848002 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11179023001A 1 11181028002B 1 11175020001A 1 11179023001A 1 11179023001A 06/29/2011 20:03 06/29/2011 20:25 06/30/2011 19:48 06/27/2011 21:35 06/27/2011 12:46 06/24/2011 22:58 06/24/2011 22:58 06/24/2011 22:58 06/24/2011 22:58 06/24/2011 22:58 06/24/2011 22:58 06/28/2011 10:40 06/30/2011 21:30 06/24/2011 21:40 06/28/2011 10:40 06/28/2011 10:40 Analyst Jason M Long Jason M Long Jason M Long Jason M Long Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 10 100 10 100 20 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •23tarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-65 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-65 Project Name: BP 4762 Collected: 06/23/2011 14:10 by SS Submitted: 06/24/2011 Reported: 07/07/2011 MHC65 Page 1 of 2 LLI Sample # WW 6327441 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010B EPA 300.0 As Received Result ug/1 15,000 N.D. 2,000 N.D. 35 J 480 1,900 6,200 ug/1 2,100 mg/1 7439-95-4 35.9 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 80.9 6.7 N.D. N.D. N.D. 70.3 mg/1 N.D. umhos/cm 551 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 200 20 20 20 20 20 20 20 1,000 100 100 100 100 100 100 100 ug/1 ug/1 50 150 mg/1 mg/1 0.0067 0.100 mg/1 4.0 1.0 0.40 0.25 0.40 1.5 mg/1 5.0 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.2 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 2000 200 200 200 200 200 200 200 10 1 10 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result 1 i IILaboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-65 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-65 Project Name: BP 4762 Collected: 06/23/2011 14:10 Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC65 by SS Page 2 of 2 LLI Sample # WW 6327441 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep ,07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 100228 Sulfate )10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method SW-846 purge SW-846 purge SW-846 Laboratory Sample Analysis Record Trial# Batch# Analysis Date and Time 8260B 25mL 1 C111801AA 06/29/2011 20:46 8260B 25mL 1 C111801AA 06/29/2011 21:08 5030B SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C111801AA 06/29/2011 20:46 2 C111801AA 06/29/2011 21:08 1 111790026A 06/30/2011 20:05 1 111781848002 06/27/2011 21:39 1 111781848002 06/27/2011 12:46 1 11175196602A 06/28/2011 20:30 1 11175196602A 06/24/2011 23:13 1 11175196602A 06/24/2011 23:13 1 11175196602A 06/24/2011 23:13 1 11175196602A 06/24/2011 23:13 1 11175196602A 06/24/2011 23:13 1 11181023001A 06/30/2011 10:00 1 11181028002B 06/30/2011 21:30 1 11175020001A 06/24/2011 21:40 1 11181023001A 06/30/2011 10:00 1 11179023001A 06/28/2011 10:40 Analyst Jason Jason Jason M Long M Long M Long Jason M Long Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Ashley M Ashley M Ashley M Ashley M Ashley M Adams Adams Adams Adams Adams Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 200 2000 200 2000 10 1 1 10 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result *Eaairao ncasterories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-68 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-68 Project Name: BP 4762 Collected: 06/23/2011 14:30 by SS Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC68 Page 1 of 2 LLI Sample # WW 6327442 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified As Received Result ug/1 90 17 30 6.1 130 17 14 150 ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 1.0 0.20 0.20 0.20 1.0 0.20 0.20 1.0 5.0 1.0 1.0 1.0 5.0 1.0 1.0 5.0 ug/1 ug/1 74-82-8 120 10 15 SW-846 6010B EPA 300.0 mg/1 7439-95-4 30.5 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 mg/1 0.0067 0.100 mg/1 mg/1 mg/1 188 22.3 N.D. N.D. N.D. 131 mg/1 N.D. umhos/cm 684 8.0 1.0 0.40 0.25 0.40 6.0 10.0 2.0 0.50 0.50 0.50 20.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 5.7 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 10 2 2 2 10 2 2 10 1 1 20 5 5 5 5 20 1 1 1 1 1 *=This limit was used in the evaluation of the fmal result 1 1 �!I 02898 •Ezarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-68 Water 4762 COC: 7401 Old Mount Holly Rd Project Name: BP 4762 Collected: 06/23/2011 14:30 Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC68 - Charlotte, NC MW-68 Page 2 of 2 LLI Sample # WW 6327442 LLI Group # 1253284 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA VOC 25m1 BTEX/MTBE/IPE/Nap;DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep N07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) '01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen ' 01506 Nitrite Nitrogen 100228 Sulfate. 10293 Sulfideas H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C111801AA 1 G111861AA 1 C111801AA 2 G111861AA 1 111790026A 1 111781848002 1 111781848002 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11181023001A 1 11181028002B 1 11175020001A 1 11181023001A 1 11179023001A Analysis Date and Time 06/29/2011 21:30 07/06/2011 04:43 06/29/2011 21:30 07/06/2011 04:43 06/29/2011 22:58 06/27/2011 21:42 06/27/2011 12:46 06/28/2011 20:45 06/24/2011 23:57 06/24/2011 23:57 06/24/2011 23:57 06/24/2011 23:57 06/28/2011 20:45 06/30/2011 10:00 06/30/2011 21:30 06/24/2011 21:40 06/30/2011 10:00 06/28/2011 10:40 Analyst Jason M Long Sara E Johnson Jason M Long Sara E Johnson Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Ashley M Ashley M Ashley M Ashley M Ashley M Adams Adams Adams Adams Adams Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 10 2 10 2 1 1 1 20 5 5 5 5 20 1 1 1 1 1 *=This limit was used in the evaluation of the final result 416Lancaster lt Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-69 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-69 Project Name: BP 4762 Collected: 06/23/2011 14:50 by SS Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC69 Page 1 of 2 LLI Sample # WW 6327443 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals SW-846 6010B 01757 Magnesium 7439-95-4 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 Wet Chemistry EPA 300.0 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 N.D. 0.32 J N.D. 5.1 70 0.19 J N.D. N.D. ug/1 12 J mg/1 22.7 mg/1 N.D. 10.5 N.D. N.D. N.D. 17.8 mg/1 N.D. umhos/cm 278 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 0.10 0.10 0.10 0.10 1.0 0.10 0.10 0.10 0.50 0.50 0.50 0.50 5.0 0.50 0.50 0.50 ug/1 ug/1 10 15 mg/1 mg/1 0.0067 0.100 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 ' mg/1 0.054 umhos/cm 1.7 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 5.9 0.010 The 40 CFR Part 136 requires that this analysis be'performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. mg/1 0.054 0.054 mg/1 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 0.16 umhos/cm 5.0 Std. Units 0.010 mg/1 0.16 0.16 Dilution Factor 1 1 1 1 10 1 1 1 5 5 5 5 5 1 1 1 *=This limit was used in the evaluation of the final result • Lancaster. Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-69 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-69 _ Project Name: BP 4762 Collected: 06/23/2011 14:50 _Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHC69 Page 2 of 2 LLI Sample # WW 6327443 LLI Group # 1253284 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name --No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep ,.07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 101505 Bromide '00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate '10293 Sulfide as H2S - 00280 Specific Conductance 00200 pH ' 10499 Dissolved Sulfide 00230 Sulfide Laboratory Sample Analysis Record Method Trial# Batch# SW-846 purge SW-846 purge SW-846 5030B 1 C111801AA SW-846 5030B 2 C111801AA RSKSOP-175 1 111790026A 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 111781848002 1 111781848002 8260B 25mL 1 C111801AA 8260B 25mL 1 C111801AA 06/29/2011 22:36 Analysis Date and Time 06/29/2011 22:14 06/29/2011 06/29/2011 06/29/2011 06/27/2011 06/27/2011 1 11175196602A 06/25/2011 1 11175196602A 06/25/2011 1 11175196602A 06/25/2011 1 11175196602A 06/25/2011 1 11175196602A 06/25/2011 1 11175196602A 06/25/2011 1 11181023001A 06/30/2011 1 11181028002B 06/30/2011 1 11175020001A 06/24/2011 1 11181023001A 06/30/2011 1 11179023001A 06/28/2011 22:14 22:36 23:13 21:46 12:46 00:11 00:11 00:11 00:11 00:11 00:11 10:00 21:30 21:40 10:00 10:40 Analyst Jason M Long Jason M Long Jason M Long Jason M Long Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 1 10 1 10 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result IILaneaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: UW-06 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-06 Project Name: BP 4762 Collected: 06/23/2011 15:15 by SS Submitted: 06/24/2011 Reported: 07/07/2011 MHCU6 Page 1 of 2 LLI Sample # WW 6327444 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals SW-846 6010B 01757 Magnesium 7439-95-4 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S RSKSOP-175 08/11/94 modified EPA 300.0 74-82-8 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 4.9 0.67 13 0.36 J 20 5.9 0.19 J 5.3 ug/1 190 mg/1 3.13 mg/1 N.D. 5.5 N.D. N.D. N.D. 2.7 J mg/1 N.D. umhos/cm 89.7 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 ug/1 ug/1 10 15 mg/1 mg/1 0.0067 0.100 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 5.7 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 1 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: UW-06 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-06 Project Name: BP 4762 'Collected: 06/23/2011 15:15 Submitted: 06/24/2011 Reported: 07/07/2011 MHCU6 Page 2 of 2 LLI Sample # WW 6327444 LLI Group # 1253284 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive 09:45 Suite 400 14:06 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 01505 Bromide 00224 Chloride 01504 Fluoride ,00368 Nitrate Nitrogen '01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method SW-846 8260B 25mL purge SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D Laboratory Sample Analysis Record Trial# Batch# Analysis Date and Time 1 C111801AA 06/29/2011 22:58 1 C111801AA 06/29/2011 22:58 1 111790026A 06/29/2011 23:43 1 111781848002 06/27/2011 21:49 1 111781848002 06/27/2011 12:46 1 11175196602A 06/25/2011 00:26 1 11175196602A 06/25/2011 00:26 1 11175196602A 06/25/2011 00:26 1 11175196602A 06/25/2011 00:26 1 11175196602A 06/25/2011 00:26 1 11175196602A 06/25/2011 00:26 1 11181023001A 06/30/2011 10:00 1 11181028003A 06/30/2011 22:10 1 11175020001B 06/24/2011 21:40 1 11181023001A 06/30/2011 10:00 1 11179023001A 06/28/2011 10:40 Analyst Jason M Long Jason M Long Elizabeth J Marin John W Yanzuk II James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 1 1 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Ealicoarao sterries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: UW-08 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-08 Project Name: BP 4762 Collected: 06/23/2011 15:35 by SS Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHCU8 Page 1 of 2 LLI Sample # WW 6327445 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified As Received Result ug/1 680 N.D. 80 22 J 1,800 66 16 J 16 J ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 5.0 5.0 5.0 5.0 50 5.0 5.0 5.0 25 25 25 25 250 25 25 25 ug/1 ug/1 74-82-8 160 10 15 SW-846 6010B EPA 300.0 mg/1 7439-95-4 38.3 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 mg/1 0.0067 0.100 mg/1 mg/1 mg/1 N.D. 13.4 N.D. N.D. N.D. 14.3 mg/1 N.D. umhos/cm 736 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.3 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 50 50 50 50 500 50 50 50 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result *Ezarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: UW-08 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-08 Project Name: BP 4762 Collected: 06/23/2011 15:35 by SS Submitted: 06/24/2011 09:45 Reported: 07/07/2011 14:06 MHCU8 Page 2 of 2 LLI Sample # WW 6327445 LLI Group # 1253284 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep ,07105 Volatile Headspace Hydrocarbon 01757 Magnesium 01848 WW SW846 ICP Digest (tot rec) 01505 Bromide '00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010B SW-846 3005A EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C111801AA 1 C111801AA 1 C111801AA 2 C111801AA 1 111790026A Analysis Analyst Date and Time 06/29/2011 23:19 Jason M Long 06/29/2011 23:42 Jason M Long 06/29/2011 23:19 06/29/2011 23:42 06/29/2011 23:58 Jason M Long Jason M Long Elizabeth J Marin 1 111781848002 06/27/2011 21:53 John W Yanzuk II 1 111781848002 06/27/2011 12:46 James L Mertz 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11175196602A 1 11181023001A 1 11181028003A 1 11175020001B 1 11181023001A 1 11179023001A 06/25/2011 00:41 06/25/2011 00:41 06/25/2011 00:41 06/25/2011 00:41 06/25/2011 00:41 06/25/2011 00:41 06/30/2011 10:00 06/30/2011 22:10 06/24/2011 21:40 06/30/2011 10:00 06/28/2011 10:40 Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Susan E Hibner Luz M Groff Luz M Groff Susan E Hibner Susan E Hibner Dilution Factor 50 500 50 500 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result ���Laboratories Analysis Report 2425 New Holland Pike, Po Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Page 1 of 4 Quality Control Summary Client Name: Atlantic Richfield c/o URS Group Number: 1253284 Reported: 07/07/11 at 02:06 PM Matrix QC may not be reported if site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. Analysis Name Laboratory Compliance Quality Control Blank Blank Blank Report LCS LCSD LCS/LCSD Result MDL** LOO Units %REC %REC Limits RPD RPD Max Batch number: C111801AA Sample number(s): 6327437-6327445 Benzene N.D. 0.10 0.50 ug/1 98 99 80-120 1 30 1,2-Dichloroethane N.D. 0.10 0.50 ug/1 97 98 80-127 2 30 Ethylbenzene N.D. 0.10 0.50 ug/1 99 99 80-120 0 30 di -Isopropyl Ether N.D. 0.10 0.50 ug/1 83 85 80-120 3 30 Methyl Tertiary Butyl Ether N.D. 0.10 0.50 ug/1 85 87 73-120 2 30 Naphthalene N.D. 0.10 0.50 ug/1 77 79 77-120 2 30 Toluene N.D. 0.10 0.50 ug/1 101 101 80-120 0 30 Xylene (Total) N.D. 0.10 0.50 ug/1 102 101 80-120 1 30 Batch number: G111861AA Sample number(s): 6327442 1,2-Dichloroethane N.D. 0.10 0.50 ug/1 115 80-127 Ethylbenzene N.D. 0.10 0.50 ug/1 101 80-120 di -Isopropyl Ether N.D. 0.10 0.50 ug/1 104 80-120 Naphthalene N.D. 0.10 0.50 ug/1 102 77-120 Toluene N.D. 0.10 0.50 ug/1 100 80-120 Batch number: 111790026A Sample number(s): 6327438-6327445 Methane N.D. 10. 15 ug/1 107 80-120 Batch number: 111781848002 Magnesium Sample number(s): 6327438-6327445 N.D. 0.0067 0.100 mg/1 101 89-110 Batch number: 11175196602A Sample number(s): 6327438-6327445 Bromide N.D. 0.40 0.50 mg/1 107 90-110 Chloride N.D. 0.20 0.40 mg/1 104 90-110 Fluoride N.D. 0.080 0.10 mg/1 109 90-110 Nitrate Nitrogen N.D. 0.050 0.10 mg/1 105 90-110 Nitrite Nitrogen N.D. 0.080 0.10 mg/1 102 90-110 Sulfate N.D. 0.30 1.0 mg/1 103 90-110 Batch number: 11175020001A Sample number(s): 6327438-6327443 pH 100 99-101 Batch number: 11175020001B Sample number(s): 6327444-6327445 pH 100 99-101 Batch number: 11179023001A Dissolved Sulfide Sulfide Sample number(s): 6327438-6327445 N.D. 0.054 0.16 mg/1 N.D. 0.054 0.16 mg/1 Batch number: 11181023001A Sample number(s): 6327441-6327445 Dissolved Sulfide N.D. 0.054 0.16 mg/1 104 104 102 90-110 90-110 90-110 Batch number: 11181028002B Sample number(s): 6327438-6327443 Specific Conductance N.D. 1.7 5.0 umhos/cm 101 98-106 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. 1 I Labnora�tories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681• www.lancasterlabs.com Quality Control Summary Client Name: Atlantic Reported: 07/07/11 at Analysis Name Batch number: 11181028003A Specific Conductance Page 2 of 4 Richfield c/o URS Group Number: 1253284 02:06 PM Blank Blank Blank Report LCS LCSD LCS/LCSD Result MDL** LOO Units %REC %REC Limits RPD RPD Max Sample number(s): 6327444-6327445 N.D. 1.7 5.0 umhos/cm 101 98-106 Unspiked (UNSPK) = the sample Background (BKG) = the sample Analysis Name Batch number: C111801AA Benzene 1,2-Dichloroethane Ethylbenzene Toluene Xylene (Total) Batch number: G111861AA 1,2-Dichloroethane Ethylbenzene di -Isopropyl Ether Naphthalene Toluene Batch number: 111790026A Methane Batch number: 111781848002 Magnesium Batch number: 11175196602A Bromide Chloride Fluoride Nitrate Nitrogen Nitrite Nitrogen Sulfate Batch number: 11175020001A pH Batch number: 11175020001B pH Sample Matrix Quality Control used in conjunction with the matrix spike used in conjunction with the duplicate MS %REC MSD %REC MS/MSD Limits RPD BKG RPD MAX Conc DUP Conc Sample number(s): 6327437-6327445 BKG: P328604 N.D. N.D. 0.11 J N.D. N.D. N.D. N.D. N.D. N.D. N.D. Sample 114 108 112 101 108 Sample -1332 (2) number(s) 114 110 112 104 109 : 6327442 UNSPK: 83-143 0 80-140 2 75-123 1 55-132 3 83-127 1 P334441 30 30 30 30 30 number(s): 6327438-6327445 UNSPK: 6327438 -1166 35-157 9 20 (2) DUP RPD Dup RPD Max 0 (1) 30 200* (1) 30 0 (1) 30 0 (1) 30 0 (1) 30 Sample number(s): 6327438-6327445 UNSPK: 6327438 BKG: 6327438 -2786 -2049 75-125 9 20 208 179 15 20 (2) (2) Sample number(s): 6327438-6327445 UNSPK: 6327438 118* 90-110 N.D. 112* 90-110 3.1 119* 90-110 N.D. 114* 90-110 1.2 108 90-110 N.D. 122* 90-110 12.1 Sample number(s): 6327438-6327443 BKG: P327398 5.5 Sample number(s): 6327444-6327445 BKG: 6327444 5.7 Batch number: 11179023001A Sample number(s): 6327438-6327445 UNSPK: 6327445 Dissolved Sulfide 98 100 50-130 2 10 N.D. Sulfide 98 100 50-130 2 10 N.D. Batch number: 11181023001A Sample number(s): 6327441-6327445 UNSPK: P329071 Dissolved Sulfide 32* 33* 50-130 4 10 0.49 J Batch number: 11181028002B Sample number(s): 6327438-6327443 BKG: 6327443 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. BKG: 6327438 N.D. 3.2 N.D. 1.2 N.D. 11.9 5.5 5.7 BKG: 6327445 N.D. N.D. BKG: P329071 0.47 J 0 (1) 20 4 (1) 20 0 (1) 20 3 (1) 20 0 (1) 20 2 (1) 20 0 3 0 3 0 (1) 5 0 (1) 5 4 (1) 5 Labo*EII .2itarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2661 • www.lancasterlabs.com Page 3 of 4 Quality Control Summary Client Name: Atlantic Richfield c/o URS Group Number: 1253284 Reported: 07/07/11 at 02:06 PM Sample Matrix Quality Control Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max Specific Conductance 278 278 0 3 Batch number: 11181028003A Sample number(s): 6327444-6327445 BKG: P329036 Specific Conductance 699 698 0 3 Surrogate Quality Control Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: EPA SW846/8260 (water-25m1) #1 Batch number: C111801AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 6327437 94 99 100 94 6327438 96 92 100 101 6327439 93 95 103 99 6327440 93 95 101 98 6327441 92 95 101 97 6327443 91 94 103 94 6327444 92 95 101 100 6327445 92 96 103 98 Blank 101 99 99 92 DUP 104 100 98 93 LCS 96 94 103 103 LCSD 97 94 102 103 Limits: 77-114 74-113 77-110 78-110 Analysis Name: EPA SW846/8260 (water-25m1) #1 Batch number: G111861AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 6327442 105 104 99 100 Blank 105 107 98 100 LCS 103 108 98 102 MS 106 101 99 100 MSD 104 103 99 101 Limits: 77-114 74-113 77-110 78-110 Analysis Name: Volatile Headspace Hydrocarbon Batch number: 111790026A Propene 6327438 94 6327439 100 6327440 80 6327441 93 6327442 61 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. _ 1I'Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681• www.lancasterlabs.com Quality Control Summary Client Name: Atlantic Richfield c/o URS Reported: 07/07/11 at 02:06 PM 6327443 58 6327444 65 6327445 51 Blank 113 LCS 113 MS 71 MSD 71 Group Number: 1253284 Surrogate Quality Control Page 4 of 4 Limits: 42-131 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. ILancaster r Laboratories Case Narrative Project Name: BP 4762 LLI Group #: 1253284 General Comments: Through our technical processes and second person review of data, we have established that our data/deliverables are in compliance with the methods and project requirements unless otherwise noted or previously resolved with the client. The compliance signature is located on the cover page of the Analysis Reports. See the Laboratory Sample Analysis Record section of the Analysis Report for the method references. All QC met criteria unless otherwise noted in an Analysis specific Comment below. Refer to the QC summary for specific values and acceptance criteria. Project specific QC samples are not included in this data set Matrix QC may not be reported if site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. Surrogate recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in an Analysis specific comment below. The samples were received at the appropriate temperature and in accordance with the chain of custody unless otherwise noted. Analysis specific Comments: sw-846 8260E 25mL purge. GC/Ms volatiles Batch #: C111801AA (Sample number(s): 6327437-6327445 BKG: P328604) The duplicate RPD for the following analyte(s) exceeded the acceptance window: 1,2-Dichloroethane Sample #s: 6327438 Reporting limits were raised due to interference from the sample matrix. RSKSOP-175 08/11/94 modified. GC Miscellaneous Batch #: 111790026A (Sample number(s): 6327438-6327445 UNSPK: 6327438) The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: Methane Sw-846 6010B, Metals Batch #: 111781848002 (sample number(s): 6327438-6327445 UNSPK: 6327438 BKG: 6327438) The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: Magnesium v 1.8.6 7/7/2011 2:10:11PM EPA 300.0. wet chemistry Batch #: 11175196602A (Sample number(s): 6327438-6327445 uNSPK: 6327438 BKG: 6327438) The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Bromide The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: chloride The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Fluoride The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Nitrate Nitrogen The recovery(ies) for the following analyte(s) in the MS was outside the acceptance window: Sulfate SM20 4500 S2 D. Wet Chemistry Batch #: 11181023001A (Sample number(s): 6327441-6327445 UNSPK: P329071 BKG: P329071) The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: Dissolved Sulfide Sample #s: 6327438 Reporting limits were raised due to interference from the sample matrix. v 1.8.6 7/7/2011 2:10:11PM jgr lanti icnlleld company A BP affiliated company I e- —I I LC re 41 ft LS 3 'z-'K 4f .�Q-r+.i, p 1 C F I. J c. C 'i 9 I— �i J Laboratory Management Program LaMP Chain of Custody Record Page _L of BP/ARC Project Name: BP/ARC Facility No: Paw Creek -BP Req Due Date (mmlddlyy): 10-business days trom receipt Rush TAT: Yes No X Lab Work Order Number: Lab Name: Lancaster Laboratories BP/ARC Facility Address: 7401 Old Mount Holly Road Consultant/Contractor: URS Corporation - North Carolina Lab Address: 2425 New Holland Pike, Lancaster, PA 17605 City, State, ZIP Code: Charlotte, NC Consuilant/Contractor Project No: Paw Creek -BP - 38436615.104080 Lab PM: Lynn Frederiksen Lead Regulatory Agency: NCDENR DWQ - GW Section Address: 1600 Perimeter Park Road, Suite 400, Morrisville, NC 27560 Lab Phone: 717-656-2300 California Global ID No.: Consultant/Contractor PM: Margaret Ness Lab Shipping Accnt: Lancaster: 1077-8526-4 Enfos Proposal No: 006KN-0002 Phone: 919-461-1100 Lab Bottle Order No: Accounting Mode: Provision X OOC-BU OOC-RM _ Email EDD To: Martha_Meyers-Lee@urscorp.com Other Info: Stage: 40 Activity: SO - Operate / Project Spend Invoice To: BP/ARC X Contractor_ BP/ARC EBM: Greg Frisch Matrix No. Containers 1 Preservative Requested Analyses Report Type & QC Level EBM Phone: 216 271-8740 :Q a reO T3 Water / Liquid Air / Vapor Total Number of Containers Unpreserved S = HCI = O 2 c O z BTEX, MTBE, IPE, Naphthalene, & 1,2-OCA (8260B) F- (EPA 300) & H2S (pH & conductance) (4500 S2F) H2S (dissolved 52-) (4500 S2F) Total Magnesium (6010C) Br-, Cl-, NO3-, NO2-, & SO4-2 (EPA 300) Methane (RSKSOP-175) Total Sulfide (4500 S2 13) Standard ....2L Full Data Package EBM Email: Greg.Frisch@bp.com Lab No. Sample Description Date Time Comments Note: If sample not collected, indicate 'No Sample in comments and single -strike out and initial any preprinted sample dewel:4ton. Trip Blank fil-' II x 2 . _ o. 1v1- 0s `1231s1 rgoo x 11 3 1 5 1 1 3 1 1 1 2 2 1 MW —/I (.41 11f t'y o x 11 3 1 5 1 1 3 1 1 1 2 2 1 Mwz/ Mel 1it ISIc. x 11 3 1 5 1 1 3 1 1 1 2 2 1 %4wo-US- irr121Ili ILItb x 11 3 1 5 1 1 3 1 1 1 2 2 1 iMW—LS tab"' I[ )LA6 x 11 3 1 5 1 1 3 1 1 1 2 2 1 Mw_Lp U1t,1I( )'b x 11 3 1 5 1 1 3 1 1 1 2 2 1 �b UK/ O i,I it I( Ins x 11 3 1 5 1 1 3 1 1 1 2 2 1 UIn► "Oft trt;1 <i fists x 11 3 1 5 1 1 3 1 1 1 2 2 1 0 Sampler's Name: 5 c..'IT SrM 1 b r / Ti a -Di LiiG.f;y Relinquished By / Affiliation Date r Time Accepted By/ Affiliation Date Time Sampler's Company: URS Corporation - North Carolina Xigi Tt A I1 bh.l f / 1 3a Shipment Method: FedEX Ship Date: & les 1 1 i J....- Shipment Tracking No: 9700 q3 q gDrz, Ale d rl3 .207 / / 904 c* 7.2 6a ,7_,- 32 eFkiiiri Special Instructions: Refer to attached Sample Kit Request for analytical scope of work. NOTE: Short Holding times (pH, nitrate, and nitrite)! H2S is date :m dissolved Contact Martha Meyers -Lee (919.451-1519) regarding all sample receipt end analytical non-conformance tissues. sulfide, pH, and specific conductance. THIS LINE - LAB USE ONLY: Custody Seals In Place:' / No 1 Temp Biankla45 I No I Cooler Temp on Receipt:).4 ' A °FIC I Trip Blank:19/ No I MS/MSD Sample Submitted: Yes /ap Enfos Work Release W R232184 BP/ARC LaMP cOC Rsv. 6 DU01[20oe f -e -r 1 i z.39'7 Oce,a: Z8y SANPL t ; Client: Client PM: Project: Location: Date Needed: Sample Date: Invoice To: 432—N31'1C Analytical SOW: BP Subcontract No. Revision No. Date Page BOTTLE REQUEST FORM (Email to: IfrederiksenC lancasterlabs.com, TSpaidektlancasterlabs.com) Greg Frisch BP 4762 Epsom Salt Pilot Study U7401 Old Mount lull Road, Charlotte, NC Week of May 16, 2011 and specific intervals thereafter' [X] BP (Direct bill): [ ] Submit via Enfos system OR [ ] URS Corporation (subcontract) Consultant: Consultant PM: Consultant TL: URS Project #: Project Chemist: Phone No.: URS Corporation Margaret Ness Scott Smida 38436615,104080 Martha Meyers -Lee. Morrisville 919-461-1519 [X] Submit to URS Corporation . :�•.; ., ..., Methods .• .,. .; .:,�^•,. •�i :. I::, ¢ i4r/ii;,;r:. ✓'; !/ rt` , •::,y •� :•'%%:i,'..•: ��.j ,%�l. rry4 :"• )q� ;-•, �, i4 ; r i%{ / z' )� ' �• %^i�.� *ice "l:•.:• 7 ' '. ''r ;;;� r , r 1►.. Unit Rate TI SW-846 8260B (25 ml purge) Benzene Toluene Ethylbenzene Xylenes MTBE 1PE Naphthalene 1,2-DCA 1 600 600 500 20 70 6 0.4 X-434 $95 1 0 8 8 8 8 8 41 SM18 4500 S2 F Hydrogen Sulfide: (Dissolved Sulfide, Calculation, Conductance, pH) - - X-065 NA X-059 X-046 $53 ($23 $I0 $12 $8) 1 8 8 8 8 8 8 49 SM20 4500 S2 D Total Sulfide - X-065 $23 SW-846 6010B Total Magnesium - X-113 $30 EPA 300 Bromide Chloride Fluoride Nitrate Nitrite Sulfate - 250,000 2,000 1,000 10,000 250,000 X-005 X-010 X-020 X-035 X-036 X-064 $19 $19 $19 $19 $19 $19 EPA 300 Sulfate 250,000 X-064 $J.9 1 0 0 0 0 0 0 1 RSKSOP-175 08/11/94 Met/cane - X-295 $65 - 8 8 8 8 8 8 48 µg/L. Micrograms per liter SM Standard Methods DCA Dichloroethane 1PE isopropyl ether MTBE Methyl tert-butyl ether Analytical work is to be conducted in accordance with: , • Technical Requirements For Environmental Laboratory Analytical Services BP Laboratory Management Program (LaMP), Atlantic Richfield Company- a BP- affiliated company, Revision 09 — FINAL Issued: 07/30/2007 • UST Section Guidelines For The Investigation And Remediation Of Contamination From Non -UST Petroleum Releases„ NC DENR, UST Section, current version , which is available at http://www.wastenotnc.ore,/ust/docs/Non-USTGuid053107.pdf Sample results are to be analyzed at the lowest dilution possible without harm to the instrument, and then at the proper dilution to ensure that regulatory levels are achieved. Results are to be reported to the Method Detection Limit. Sample concentrations that are less than the PQL, but greater than the MDL are to be J-flagged. A trip blank will be included in the each shipment of VOA samples submitted to the laboratory. lit is anticipated that samples will be collected the week of May 16, June 16 and 22, July 20, August 17, and November 16, 2011, and February 15, 2012 2 Detection limits shall be less than the PQL or NC Groundwater Pmtection Standard (2L), whichever is lower. 3 Week of May 16, 2011 Week of June 6, 2011 5 Week of June 22, 2011 6 Week of July 20, 2011 7 Week of August 17, 2011 ti Week of November 16, 2011 9 Week of February 15, 2012 P:\BP\Projects\Terminals\476214.0 Site Data\4.6 Lab Reports - Data Validation\Analytical Requests\2011\BP 4762 Bottle Request Form Pilot Study (05-25-11, v4).doc Last printed 6/1/2011 1:52:00 PM i}Qe-r : Iz3 4 7 GKcjP : t zi 32&-! SAMiLr:: 12.7`13--45 Analytical TAT: Standard'10 business days) Laboratory Certification: NC DWO Applicable Standard(s): NC 2L Subcontract No. N Revision No. 4 Date 6/1/11 Page 2 of 3 Electronic Deliverable: Laboratory report containing Case Narrative. summary+ of sample results and associated OC results. Sample Receipt paperwork, and COC record: EDD formatted in Excel for the EnviroData program and electronic covv (pdf) of the invoice Electronic Deliverable to: Martha Meyers-lee@�urscorp.com, (919) 461-1519 Supplies Needed10: Batch 1— Week of May 16, 2011 • 6 40-ml VOA vials, pre -preserved with HCI, for the SW-846 8260E analysis (based on 3 vials per sample plus a spare set) • 6 40-m1 VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples must be shipped on the day of sample collection • because of a 48-hour holding there) (2 per sample, 2 spare) • 1 500-ml plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 1 glass bottles of sufficient size, pre -preserved with Zinc Acetate and NaOH, for the determination of total sulfide (1 per sample) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 1 glass 500 niL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 1 plastic bottles of sufficient size, pie -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • 1 Trip blank, consisting of 2-40 mL VOA vials preserved with HCI acid to a pH Q. Integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) Batch 2 — Week of' June 6, 2011 • 18 40-m1 VOA vials, pre -preserved with HCI, for the R SKSOP-l75 analysis (based on 2 vials per sample plus a .spare .set) • 18 40-m1 VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples must be shipped on the day of sample collection • because of a 48-hour holding time) (2 per sample, 2 spare) • 8 500-m1 plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 9 glass bottles of sufficient size, pre -preserved with Zinc Acetate and NaOH, for the determination of total sulfide (I per sample, 1 spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 9 glass 500 mL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample, 1 spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 8 plastic bottles of sufficient size, pre -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • I Trip blank, consisting of 2-40 niL VOA vials preserved with HCI acid to a pH 2. Integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) Batches 3-7 — Week of June 22, July 20, August 17, November 16, 2011, and February 15, 2011 • 27 40-ml VOA vials, pre preserved with HCI, for the SW-846 8260B analysis (based on 3 vials per sample plus a spare set) • 18 40-m1 VOA vials, pre preserved with HC4 for the RSKSOP-175 analysis (based on 2 vials per sample plus a spare seat) • 18 40-nil VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples must be shipped on the day of sample collection • because of a 48-hour holding time) (2 per sample, 2 spare) • 8 500-m1 plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 9 glass bottles of sufficient size, pre -preserved with Zlnc Acetate and NaOH, for the determination of total sulfide (1 per sample, 1 spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 9 glass 500 mL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample,) spare) (NOTE: Collect sample with mininnun aeration and fill bottle completely) • 8 plastic bottles of sufficient size, pre -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • 1 Trip blank, consisting of 2-40 mL VOA vials preserved with HC1 acid to a pH Q. Integrity seals and bottle labels • Coolers labeled with laboratory name and address • insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) 10 Container types and numbers per State Guidelines P:\BFtProjects\Terrninals\4762\4.0 Site Data14.6 Lab Reports - Data Validation\Analytical Requests\2011\BP 4762 Bottle Request Fonn Pilot Study (05-25-11, v4).doc Page 2 of 3 c4 CC1= i z39 "7 P:z13z(-! 5—/1MP Lt:: (p3z-7 —t 3 7 - YS DI H20: None Ship Supplies To: [ 1 JNamel URS Corporation 1600 Perimeter Park Drive. Suite 400 Morrisville, NC 27560 Phone No. (919) 461-1100 [ Scott Smida URS Corporation 6135 Park South Drive. Suite 300 Charlotte, NC 28210 Phone No. 704-522-0330 Subcontract No. Revision No. Date Page N/A 4 6/1/11 3 of 3 [ 1 JNamcl PLEASE INCLUDE "4162-PilotStudy" on the outside of the cooler to facilitate retrieval from our mailroom. Kit Request Taken By: Date: Kit Completed By: Date Sent: P:\BP\Projects\Terminals\476214.0 Site Data\4.6 Lab Reports - Data Validation\ Analytical Requests\2011\BP 4762 Bottle Request Form Pilot Study (05-25-11, v4).doc Page 3 of 3 Lancaster Laboratories Environmental Sample Administration Receipt Documentation Log Client/Project: V O. Date of Receipt: tD jay 1 I t Time of Receipt: Source Code: 50--( 0315 Shipping Container Sealed: ES. NO Custody Seal Present* : S NO * Custody seal was intact unless otherwise noted in the discrepancy section Package: (gad Not Chilled w Temperature of Shipping Containers Cooler # Thermometer ID Temperature CC) Temp Bottle (TB) or Surface Temp (ST) Wet Ice (WI) or Dry Ice (DI) or Ice Packs op) Ice Present? YIN Loose (L) Bagged Ice (B) or NA Comments 1 61 aloe 1 y '--/ t ")-. '(..., '..- ..--- .------ 4 5 6 Number of Trip Blanks received NOT listed on chain of custody:0 Paperwork Discrepancy/Unpacking Problems: Unpacker Signature/Em. Date/Time: (ML1 I I 1 1115 Issued by Dept. 6042 Management 2174.06 �Laabncast Laratoreries Explanation of Symbols and Abbreviations The following defines common symbols and abbreviations used in reporting technical data: RL N.D. TNTC IU umhos/cm C meq g ug ml m3 Reporting Limit none detected Too Numerous To Count International Units micromhos/cm degrees Celsius milliequivalents gram(s) microgram(s) milliliter(s) cubic meter(s) BMQL. MPN CP Units NTU ng F Ib. kg mg ul Below Minimum Quantitation Level Most Probable Number cobalt-chloroplatinate units nephelometric turbidity units nanogram(s) degrees Fahrenheit pound(s) kilogram(s) milligram(s) liter(s) microliter(s) < less than - The number following the sign is the limit of quantitation, the smallest amount of analyte which can be reliably determined using this specific test. > greater than J estimated value — The result is >_ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ). ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/I), because one liter of water has a weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter of gas per liter of gas. ppb parts per billion Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight basis concentration to approximate the value present in a similar sample without moisture. All other results are reported on an as -received basis. U.S. EPA CLP Data Qualifiers: Organic Qualifiers A TIC is a possible aldol-condensation product B Analyte was also detected in the blank C Pesticide result confirmed by GC/MS D Compound quantitated on a diluted sample E Concentration exceeds the calibration range of the instrument N Presumptive evidence of a compound (TICs only) P Concentration difference between primary and confirmation columns >25% U Compound was not detected X,Y,Z Defined in case narrative Inorganic Qualifiers B Value is <CRDL, but E Estimated due to interference M Duplicate injection precision not met N Spike sample not within control limits S Method of standard additions (MSA) used for calculation U Compound was not detected W Post digestion spike out of control limits * Duplicate analysis not within control limits + Correlation coefficient for MSA <0.995 Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis. Measurement uncertainty values, as applicable, are available upon request. Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our staff. This report shall not be reproduced except in full, without the written approval of the laboratory. WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. THE FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF MERCHANTABILITY. IN NO EVENT SHALL LANCASTER LABORATORIES BE LIABLE FOR INDIRECT, SPECIAL, CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF LANCASTER LABORATORIES AND (B) WHETHER LANCASTER LABORATORIES HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Lancaster Laboratories which includes any conditions that vary from the Standard Terms and Conditions, and Lancaster hereby objects to any conflicting terms contained in any acceptance or order submitted by client. Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656.230D Fax:717-656-2661 • www.lancasterlabs.com ANALYTICAL RESULTS Prepared by: Lancaster Laboratories 2425 New Holland Pike Lancaster, PA 17605-2425 August 08, 2011 Project: BP 4762 Submittal Date: 07/22/2011 Group Number: 1257767 PO Number: 006KN-0002 Release Number: FRISCH State of Sample Origin: NC Client Sample Description Trip Blank Water MW-05 Water MW-26 Water UW-06 Water MW-21 Water MW-65 Water MW-69 Water UW-08 Water MW-68 Water Prepared for: Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 Lancaster Labs (LLI) # 6352931 6352932 6352933 6352934 6352935 6352936 6352937 6352938 6352939 The specific methodologies used in obtaining the enclosed analytical results are indicated on the Laboratory Sample Analysis Record. ELECTRONIC URS Corporation COPY TO Attn: Martha Meyers -Lee •Eaair3Koarttoerries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Questions? Contact your Client Services Representative Lynn M Frederiksen at (717) 656-2300 Ext. 1501 Respectfully Submitted, Valerie L Tomayko Principal Specialist ikaagcoaratries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Page 1 of 1 Sample Description: Trip Blank Water LLI Sample # WW 6352931 4762 COC: LLI Group # 1257767 7401 Old Mount Holly Rd - Charlotte, NC Account # 12397 Project Name: BP 4762 Collected: 07/06/2011 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMHTB CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge As Received Result ug/1 As Received As Received Method Limit of Detection Limit* Quantitation ug/1 ug/1 Dilution Factor 02898 Benzene 71-43-2 N.D. 0.10 0.50 1 02898 1,2-Dichloroethane 107-06-2 N.D. 0.10 0.50 1 02898 Ethylbenzene 100-41-4 N.D. 0.10 0.50 1 02898 di -Isopropyl Ether 108-20-3 N.D. 0.10 0.50 1 02898 Methyl Tertiary Butyl Ether 1634-04-4 N.D. 0.10 0.50 1 02898 Naphthalene 91-20-3 N.D. 0.10 0.50 1 02898 Toluene 108-88-3 N.D. 0.10 0.50 1 02898 Xylene (Total) 1330-20-7 N.D. 0.10 0.50 1 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. Laboratory Sample Analysis Record CAT Analysis Name Method Trial# Batch# Analysis Analyst Dilution No. Date and Time Factor 02898 VOC 25m1 SW-846 8260B 25mL 1 C112061AA 07/25/2011 17:59 Kerri E Legerlotz 1 BTEX/MTBE/IPE/Nap,DCA purge 01163 GC/MS VOA Water Prep SW-846 5030B 1 C112061AA 07/25/2011 17:59 Kerri E Legerlotz 1 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681• www.lancasterlabs.com Sample Description: MW-05 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-05 Project Name: BP 4762 Collected: 07/21/2011 10:30 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH05 by SS Page 1 of 2 LLI Sample # WW 6352932 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified As Received Result ug/1 ug/l ug/1 210 N.D. 450 N.D. N.D. 410 45 1,600 As Received Method Detection Limit* 1.0 1.0 10 1.0 1.0 10 1.0 10 As Received Limit of Quantitation 5.0 5.0 50 5.0 5.0 50 5.0 50 ug/1 ug/1 ug/1 74-82-8 1,600 25 75 SW-846 6010C 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. 00200 pH The 40 CFR (within 15 the result mg/1 mg/1 mg/1 8.42 0.0067 0.200 mg/1 N.D. 3.8 N.D. N.D. N.D. N.D. mg/1 0.075 J umhos/cm 77.9 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units n.a. 6.3 0.010 Part 136 requires that this analysis be performed immediately minutes) upon sample collection. Because this was not possible, may not be used for reporting purposes. SM20 4500 S2 D 10499 Dissolved Sulfide n.a. 00230 Sulfide 18496-25-8 N.D. Reporting limits were raised due to interference from mg/1 0.086 J Std. Units 0.010 mg/1 mg/1 0.054 0.54 the sample matrix. 0.16 1.6 Dilution Factor 10 10 100 10 10 100 10 100 5 1 5 5 5 5 5 5 1 1 1 1 10 *=This limit was used in the evaluation of the final result II Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-05 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-05 Project Name: BP 4762 Collected: 07/21/2011 10:30 by SS Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH05 Page 2 of 2 LLI Sample # WW 6352932 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Laboratory Sample Analysis Record Method Trial# Batch# SW-846 8260B 25mL 1 C112061AA purge Analysis Date and Time 07/25/2011 18:43 SW-846 8260B 25mL 1 C112061AA 07/26/2011 01:41 purge SW-846 5030B 1 C112061AA SW-846 5030B 2 C112061AA RSKSOP-175 1 112110022A 08/11/94 modified SW-846 6010C 1 112040651001 SM19 3030 C 1 112040651001 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 07/25/2011 07/26/2011 08/02/2011 07/23/2011 07/23/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11207023002A 07/26/2011 1 11213028001A 08/01/2011 1 11203020002A 07/22/2011 1 11207023002A 07/26/2011 1 11207023001A 07/26/2011 18:43 01:41 00:25 15:31 09:50 22:24 22:24 22:24 22:24 22:24 22:24 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 10 100 10 100 5 1 1 5 5 5 5 5 5 1 1 1 1 10 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-26 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-26 Project Name: BP 4762 Collected: 07/21/2011 10:40 by SS Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH26 Page 1 of 2 LLI Sample # WW 6352933 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010C EPA 300.0 As Received Result ug/1 300 N.D. 24 N.D. N.D. 50 9.3 13 ug/1 8,600 mg/1 7439-95-4 8.14 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 N.D. 7.4 N.D. N.D. N.D. N.D. mg/1 N.D. umhos/cm 209 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 10 1.0 1.0 1.0 1.0 1.0 1.0 1.0 50 5.0 5.0 5.0 5.0 5.0 5.0 5.0 ug/1 ug/1 250 750 mg/1 mg/1 0.0067 0.200 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.3 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. 0.17 mg/1 0.054 0.054 Std. Units 0.010 mg/1 0.16 0.16 Dilution Factor 100 10 10 10 10 10 10 10 50 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Ezarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-26 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-26 Project Name: BP 4762 Collected: 07/21/2011 10:40 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH26 by SS Page 2 of 2 LLI Sample # WW 6352933 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260E 25mL 1 C112061AA purge Analysis Date and Time 07/25/2011 19:05 SW-846 8260B 25mL 1 C112061AA 07/25/2011 19:27 purge SW-846 5030B 1 C112061AA 07/25/2011 19:05 SW-846 5030B 2 C112061AA 07/25/2011 19:27 RSKSOP-175 1 112110022A 08/02/2011 00:41 08/11/94 modified SW-846 6010C 1 112040651001 07/23/2011 15:53 SM19 3030 C 1 112040651001 07/23/2011 09:50 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11207023002A 07/26/2011 1 11213028001A 08/01/2011 1 11203020002A 07/22/2011 1 11207023002A 07/26/2011 1 11207023001A 07/26/2011 23:08 23:08 23:08 23:08 23:08 23:08 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 10 100 10 100 50 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681 • www.lancasterlabs.com Sample Description: UW-06 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-06 Project Name: BP 4762 Collected: 07/21/2011 10:50 Submitted: 07/22/2011 Reported: 08/08/2011 OMH06 Page 1 of 2 LLI Sample # WW 6352934 LLI Group # 1257767 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive 10:10 Suite 400 11:13 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010C 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 3.7 0.61 6.5 0.52 25 3.7 0.20 J 1.9 ug/1 180 mg/1 2.86 mg/1 N.D. 5.2 N.D. N.D. N.D. N.D. mg/1 N.D. umhos/cm 98.4 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 ug/1 ug/1 5.0 15 mg/1 mg/1 0.0067 0.200 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 5.8 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 1 1 1 1 1 1 1 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: UW-06 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-06 Project Name: BP 4762 Collected: 07/21/2011 10:50 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH06 by SS Page 2 of 2 LLI Sample # WW 6352934 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL purge SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010C SM19 3030 C EPA EPA EPA EPA EPA 300.0 300.0 300.0 300.0 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C112061AA 1 C112061AA 1 112110022A 1 112040651001 1 112040651001 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11207023002A 1 11213028001A 1 11203020002A 1 11207023002A 1 11207023001A Analysis Date and Time 07/25/2011 18:21 07/25/2011 18:21 08/01/2011 18:26 07/23/2011 07/23/2011 07/22/2011 07/22/2011 07/22/2011 07/22/2011 07/22/2011 07/22/2011 07/26/2011 08/01/2011 07/22/2011 07/26/2011 07/26/2011 15:57 09:50 23:23 23:23 23:23 23:23 23:23 23:23 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 1 1 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-21 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-21 Project Name: BP 4762 Collected: 07/21/2011 11:00 by SS Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH21 Page 1 of 2 LLI Sample # WW 6352935 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010C 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 15,000 N.D. 1,700 N.D. 49 J 700 1,200 4,500 ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 100 10 10 10 10 10 10 10 500 50 50 50 50 50 50 50 ug/1 ug/1 5,100 250 750 mg/1 mg/1 mg/1 18.9 0.0067 - 0.200 mg/1 N.D. 36.9 N.D. N.D. N.D. N.D. mg/1 N.D. umhos/cm 520 mg/1 mg/1 2.0 2.0 0.40 0.25 0.40 1.5 2.5 4.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.4 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 1000 100 100 100 100 100 100 100 50 1 5 10 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result IILaboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-21 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-21 Project Name: BP 4762 Collected: 07/21/2011 11:00 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH21 by SS Page 2 of 2 LLI Sample # WW 6352935 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 01163 GC/MS VOA Water Prep 01163 GC/MS VOA Water Prep 07105 Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL 1 C112061AA purge Analysis Date and Time 07/25/2011 19:49 SW-846 8260B 25mL 1 C112061AA 07/25/2011 20:11 purge SW-846 5030B 1 C112061AA 07/25/2011 19:49 SW-846 5030B 2 C112061AA 07/25/2011 20:11 RSKSOP-175 1 112110022A 08/02/2011 00:57 08/11/94 modified SW-846 6010C 1 112040651001 07/23/2011 16:07 SM19 3030 C 1 112040651001 07/23/2011 09:50 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 11203196601A 07/22/2011 1 11203196601A 07/24/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11203196601A 07/22/2011 1 11207023002A 07/26/2011 1 11213028001A 08/01/2011 1 11203020002A 07/22/2011 1 11207023002A 07/26/2011 1 11207023001A 07/26/2011 23:38 17:58 23:38 23:38 23:38 23:38 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 100 1000 100 1000 50 1 1 5 10 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result 4&Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-65 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-65 Project Name: BP 4762 Collected: 07/21/2011 11:10 by SS Submitted: 07/22/2011 Reported: 08/08/2011 OMH65 Page 1 of 2 LLI Sample # WW 6352936 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 10:10 Suite 400 Morrisville NC 27560 11:13 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 01506 00228 Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010C 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 16,000 N.D. 2,100 N.D. 33 J 670 1,700 6,000 ug/1 2,200 mg/1 27.1 mg/1 24.5 8.1 N.D. N.D. N.D. 12.6 mg/1 N.D. umhos/cm 429 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 200 20 20 20 20 20 20 20 1,000 100 100 100 100 100 100 100 ug/1 ug/1 100 300 mg/1 mg/1 0.0067 0.200 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 mg/1 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.4 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 2000 200 200 200 200 200 200 200 20 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result LLaboancasterator ries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • wwwiancasterlabs.com Sample Description: MW-65 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-65 Project Name: BP 4762 Collected: 07/21/2011 11:10 Submitted: 07/22/2011 Reported: 08/08/2011 11:13 OMH65 Page 2 of 2 LLI Sample # WW 6352936 LLI Group # 1257767 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive 10:10 Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA GC/MS VOA Water Prep GC/MS VOA Water Prep Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide 01163 01163 07105 Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL 1 C112061AA purge Analysis Date and Time 07/25/2011 20:33 SW-846 8260B 25mL 1 C112061AA 07/25/2011 20:55 purge SW-846 5030B 1 C112061AA 07/25/2011 20:33 SW-846 5030B 2 C112061AA 07/25/2011 20:55 RSKSOP-175 1 112110022A 08/02/2011 01:13 08/11/94 modified SW-846 6010C 1 112040651001 07/23/2011 16:11 SM19 3030 C 1 112040651001 07/23/2011 09:50 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11207023002A 07/26/2011 1 11213028001A 08/01/2011 1 11203020002A 07/22/2011 1 11207023002A 07/26/2011 1 11207023001A 07/26/2011 00:22 00:22 00:22 00:22 00:22 00:22 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 200 2000 200 2000 20 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result 416Lancaster lir Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2661 • www.lancasterlabs.com Sample Description: MW-69 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-69 Project Name: BP 4762 Collected: 07/21/2011 12:45 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH69 by SS Page 1 of 2 LLI Sample # WW 6352937 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 CAT No. Analysis Name CAS Number GC/MS Volatiles SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified 74-82-8 SW-846 6010C 7439-95-4 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 N.D. 0.28 J N.D. 5.2 68 0.36 J N.D. N.D. ug/1 5.1 J mg/1 34.4 mg/1 N.D. 10.9 N.D. N.D. N.D. 10.8 mg/1 N.D. umhos/cm 260 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 0.10 0.10 0.10 0.10 1.0 0.10 0.10 0.10 0.50 0.50 0.50 0.50 5.0 0.50 0.50 0.50 ug/1 ug/1 5.0 15 mg/1 mg/1 0.0067 0.200 mg/1 mg/1 2.0 1.0 0.40 0.25 0.40 1.5 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. units Std. Units 00200 pH n.a. 5.9 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 1 1 1 1 10 1 1 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Laacrao casterLaboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2661 • www.lancasterlabs.com Sample Description: MW-69 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-69 Project Name: BP 4762 Collected: 07/21/2011 12:45 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH69 Page 2 of 2 LLI Sample # WW 6352937 LLI Group # 1257767 Account # 12397 by SS Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name - No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA GC/MS VOA Water Prep GC/MS VOA Water Prep Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide 01163 01163 07105 Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260B 25mL 1 C112061AA purge SW-846 8260B 25mL 1 C112061AA 07/25/2011 21:40 purge SW-846 5030B 1 C112061AA 07/25/2011 21:18 SW-846 5030B 2 C112061AA 07/25/2011 21:40 RSKSOP-175 1 112110022A 08/01/2011 19:14 08/11/94 modified SW-846 6010C 1 112040651001 07/23/2011 16:15 SM19 3030 C 1 112040651001 07/23/2011 09:50 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D Analysis Date and Time 07/25/2011 21:18 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11203196601A 07/23/2011 1 11207023002A 07/26/2011 1 11213028001A 08/01/2011 1 11203020002A 07/22/2011 1 11207023002A 07/26/2011 1 11207023001A 07/26/2011 00:37 00:37 00:37 00:37 00:37 00:37 10:30 21:10 20:30 10:30 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James,L Mertz Ashley M Adams Ashley M Adams Ashley M,Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 1 10 1 10 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result .Lancaster.Laoraes Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681.www.lancasterlabs.com Sample Description: UW-08 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-08 Project Name: BP 4762 Collected: 07/21/2011 13:00 by SS Submitted: 07/22/2011 Reported: 08/08/2011 11:13 OMH08 Page 1 of 2 LLI Sample # WW 6352938 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 10:10 Suite 400 Morrisville NC 27560 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals SW-846 6010C 01757 Magnesium 7439-95-4 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 Wet Chemistry 01505 00224 01504 00368 01506 00228 Bromide Chloride Fluoride Nitrate Nitrogen Nitrite Nitrogen Sulfate 10293 Sulfide as H2S RSKSOP-175 08/11/94 modified 74-82-8 EPA 300.0 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. As Received Result ug/1 1,100 N.D. 110 26 2,600 130 16 J 29 ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 5.0 5.0 5.0 5.0 50 5.0 5.0 5.0 25 25 25 25 250 25 25 25 ug/1 ug/1 140 5.0 mg/1 mg/1 40.3 0.0067 mg/1 mg/1 N.D. 13.3 N.D. N.D. N.D. 8.7 2.0 1.0 0.40 0.25 0.40 '1.5 mg/1 mg/1 N.D. 0.054 umhos/cm 808 umhos/cm 1.7 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 6.3 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. mg/1 0.054 0.054 15 mg/1 0.200 mg/1 2.5 2.0 0.50 0.50 0.50 5.0 mg/1 0.16 umhos/cat 5.0 Std. Units 0.010 mg/1 0.16 0.16 Dilution Factor 50 50 50 50 500 50 50 50 1 1 5 5 5 5 5 1 1 1 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681 • www.lancasterlabs.com Sample Description: UW-08 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC UW-08 Project Name: BP 4762 Collected: 07/21/2011 13:00 by SS Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH08 Page 2 of 2 LLI Sample # WW 6352938 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA GC/MS VOA Water Prep GC/MS VOA Water Prep Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide 01163 01163 07105 Method Laboratory Sample Analysis Record Trial# Batch# SW-846 8260E 25mL purge SW-846 8260B 25mL purge SW-846 5030B SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010C SM19 3030 C EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C112061AA 1 C112061AA 1 C112061AA 2 C112061AA 1 112110022A 1 112040651001 1 112040651001 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11203196601A 1 11207023002A 1 11213028001A 1 11203020002A 1 11207023002A 1 11207023001A Analysis Analyst Date and Time 07/25/2011 22:02 Kerri E Legerlotz 07/25/2011 22:45 Kerri E Legerlotz 07/25/2011 22:02 07/25/2011 22:45 08/02/2011 00:09 07/23/2011 16:18 07/23/2011 09:50 07/23/2011 00:51 07/23/2011 00:51 07/23/2011 00:51 07/23/2011 00:51 07/23/2011 00:51 07/23/2011 00:51 07/26/2011 10:30 08/01/2011 21:10 07/22/2011 20:30 07/26/2011 10:30 07/26/2011 09:15 Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 50 500 50 500 1 1 1 5 5 5 5 5 5 1 1 1 1 1 *=This limit was used in the evaluation of the final result •Lancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Sample Description: MW-68 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-68 Project Name: BP 4762 Collected: 07/21/2011 13:10 by SS Submitted: 07/22/2011 Reported: 08/08/2011 OMH68 Page 1 of 2 LLI Sample # WW 6352939 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive 10:10 Suite 400 Morrisville NC 27560 11:13 CAT No. Analysis Name GC/MS Volatiles CAS Number SW-846 8260B 25mL purge 02898 Benzene 02898 1,2-Dichloroethane 02898 Ethylbenzene 02898 di -Isopropyl Ether 02898 Methyl Tertiary Butyl Ether 02898 Naphthalene 02898 Toluene 02898 Xylene (Total) GC Miscellaneous 07105 Methane Metals 01757 Magnesium Wet Chemistry 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 71-43-2 107-06-2 100-41-4 108-20-3 1634-04-4 91-20-3 108-88-3 1330-20-7 RSKSOP-175 08/11/94 modified As Received Result ug/1 99 15 45 6.0 130 25 15 110 ug/1 As Received Method Detection Limit* As Received Limit of Quantitation ug/1 ug/1 2.0 0.20 0.20 0.20 2.0 0.20 0.20 2.0 10 1.0 1.0 1.0 10 1.0 1.0 10 ug/1 ug/1 74-82-8 150 5.0 15 SW-846 6010C EPA 300.0 mg/1 7439-95-4 23.8 24959-67-9 16887-00-6 16984-48-8 14797-55-8 14797-65-0 14808-79-8 SM18 4500 S2 F 7783-06-4 SM20 2510 B 00280 Specific Conductance n.a. mg/1 152 27.2 N.D. 0.45 J N.D. 100 mg/1 N.D. umhos/cm 595 mg/1 mg/1 0.0067 0.200 mg/1 mg/1 8.0 1.0 0.40 0.25 0.40 6.0 10.0 2.0 0.50 0.50 0.50 20.0 mg/1 mg/1 0.054 0.16 umhos/cm umhos/cm 1.7 5.0 SM20 4500 H/B Std. Units Std. Units 00200 pH n.a. 5.9 0.010 The 40 CFR Part 136 requires that this analysis be performed immediately (within 15 minutes) upon sample collection. Because this was not possible, the result may not be used for reporting purposes. 10499 Dissolved Sulfide 00230 Sulfide SM20 4500 S2 D n.a. 18496-25-8 mg/1 N.D. N.D. Std. Units 0.010 mg/1 mg/1 0.054 0.16 0.054 0.16 Dilution Factor 20 2 2 2 20 2 2 20 1 1 20 5 5 5 5 20 1 1 1 1 1 *=This limit was used in the evaluation of the final result *Eaagcoarierries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2661 • www.lancasterlabs.com Sample Description: MW-68 Water 4762 COC: 7401 Old Mount Holly Rd - Charlotte, NC MW-68 Project Name: BP 4762 Collected: 07/21/2011 13:10 Submitted: 07/22/2011 10:10 Reported: 08/08/2011 11:13 OMH68 by SS Page 2 of 2 LLI Sample # WW 6352939 LLI Group # 1257767 Account # 12397 Atlantic Richfield c/o URS 1600 Perimeter Park Drive Suite 400 Morrisville NC 27560 General Sample Comments State of North Carolina Lab Certification No. 521 All QC is compliant unless otherwise noted. Please refer to the Quality Control Summary for overall QC performance data and associated samples. CAT Analysis Name No. 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA 02898 VOC 25m1 BTEX/MTBE/IPE/Nap,DCA GC/MS VOA Water Prep GC/MS VOA Water Prep Volatile Headspace Hydrocarbon 01757 Magnesium 10651 3030C (IV) Acid -Extract Metals 01505 Bromide 00224 Chloride 01504 Fluoride 00368 Nitrate Nitrogen 01506 Nitrite Nitrogen 00228 Sulfate 10293 Sulfide as H2S 00280 Specific Conductance 00200 pH 10499 Dissolved Sulfide 00230 Sulfide 01163 01163 07105 Laboratory Sample Analysis Record Method Trial# Batch# 911-846 8260B 25mL 1 C112061AA purge Analysis Date and Time 07/25/2011 23:07 SW-846 8260B 25mL 1 C112061AA 07/25/2011 23:29 purge SW-846 5030B SW-846 5030B RSKSOP-175 08/11/94 modified SW-846 6010C SM19 3030 C EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 EPA 300.0 SM18 4500 SM20 2510 SM20 4500 SM20 4500 SM20 4500 S2 F B H/B S2 D S2 D 1 C112061AA 07/25/2011 23:07 2 C112061AA 07/25/2011 23:29 1 112110022A 08/01/2011 20:03 1 112040651001 07/23/2011 16:22 1 112040651001 07/23/2011 09:50 1 11203196601A 07/24/2011 18:13 1 11203196601A 07/23/2011 01:06 1 11203196601A 07/23/2011 01:06 1 11203196601A 07/23/2011 01:06 1 11203196601A 07/23/2011 01:06 1 11203196601A 07/24/2011 18:13 1 11207023002A 07/26/2011 10:30 1 11213028001A 08/01/2011 21:10 1 11203020002B 07/22/2011 20:30 1 11207023002A 07/26/2011 10:30 1 11207023001A 07/26/2011 09:15 Analyst Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Kerri E Legerlotz Elizabeth J Marin John P Hook James L Mertz Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Ashley M Adams Michele L Graham Luz M Groff Luz M Groff Michele L Graham Michele L Graham Dilution Factor 2 20 2 20 1 1 1 20 5 5 5 5 20 1 1 1 1 1 *=This limit was used in the evaluation of the final result Ezasterratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Quality Control Summary Client Name: Atlantic Richfield c/o URS Reported: 08/08/11 at 11:13 AM Matrix QC may not be reported if insufficient sample or site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. Analysis Name Batch number: C112061AA Benzene 1,2-Dichloroethane Ethylbenzene di -Isopropyl Ether Methyl Tertiary Butyl Naphthalene Toluene Xylene (Total) Group Number: 1257767 Laboratory Compliance Quality Control Blank Blank Blank Report LCS Result MDL** LOO Units %REC Sample number(s): 6352931-6352939 N.D. 0.10 0.50 ug/1 108 N.D. 0.10 0.50 ug/1 102 N.D. 0.10 0.50 ug/1 106 N.D. 0.10 0.50 ug/1 99 Ether N.D. 0.10 0.50 ug/1 99 N.D. 0.10 0.50 ug/1 105 N.D. 0.10 0.50 ug/1 106 N.D. 0.10 0.50 ug/1 105 Batch number: 112110022A Methane Batch number: 112040651001 Magnesium Batch number: 11203196601A Bromide Chloride Fluoride Nitrate Nitrogen Nitrite Nitrogen Sulfate Batch number: pH Batch number: pH Batch number: Sulfide 11203020002A 11203020002B 11207023001A Batch number: 11207023002A Dissolved Sulfide Sample number(s): 6352932-6352939 N.D. 5.0 15 ug/1 98 Sample number(s): 6352932-6352939 N.D. 0.0067 0.200 mg/1 100 Sample number(s): 6352932-6352939 N.D. 0.40 0.50 mg/1 96 N.D. 0.20 0.40 mg/1 101 N.D. 0.080 0.10 mg/1 105 N.D. 0.050 0.10 mg/1 96 N.D. 0.080 0.10 mg/1 96 N.D. 0.30 1.0 mg/1 92 Sample number(s): 6352932-6352938 100 Sample number(s): 6352939 100 Sample number(s): 6352932-6352939 N.D. 0.054 0.16 mg/1 109 Sample number(s): 6352932-6352939 N.D. 0.054 0.16 mg/1 102 Batch number: 11213028001A Sample number(s): 6352932-6352939 Specific Conductance N.D. 1.7 5.0 umhos/cm 101 Page 1 of 3 LCSD LCS/LCSD %REC Limits RPD RPD Max 104 80-120 4 30 102 80-127 1 30 102 80-120 4 30 97 80-120 2 30 98 73-120 0 30 106 77-120 0 30 103 80-120 3 30 102 80-120 3 30 Sample Matrix Quality Control *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. 80-120 89-110 90-110 90-110 90-110 90-110 90-110 90-110 99-101 99-101 90-110 90-110 98-106 *Imarries Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax: 717-656-2681• www.Iancasterlabs.com Page 2 of 3 Quality Control Summary Client Name: Atlantic Richfield c/o URS Group Number: 1257767 Reported: 08/08/11 at 11:13 AM Unspiked (UNSPK) = the sample used in conjunction with the matrix spike Background (BKG) = the sample used in conjunction with the duplicate MS MSD MS/MSD RPD BKG DUP DUP Dup RPD Analysis Name %REC %REC Limits RPD MAX Conc Conc RPD Max Batch number: C112061AA Sample number(s): 6352931-6352939 BKG: 6352938 Benzene 1,100 1,100 4 30 1,2-Dichloroethane N.D. N.D. 0 (1) 30 Ethylbenzene 110 110 4 (1) 30 di -Isopropyl Ether 26 26 3 (1) 30 Methyl Tertiary Butyl Ether 2,800 2,700 2 30 Naphthalene 130 120 2 (1) 30 Toluene 16 J 16 J 4 (1) 30 Xylene (Total) 29 27 7 (1) 30 Batch number: 112110022A Sample number(s): 6352932-6352939 UNSPK: 6352932 Methane -1382 -1632 35-157 22* 20 (2) (2) Batch number: 112040651001 Sample number(s): 6352932-6352939 UNSPK: 6352932 BKG: 6352932 Magnesium 239 (2) 237 (2) 75-125 0 20 8.42 9.81 15 20 Batch number: 11203196601A Sample number(s): 6352932-6352939 UNSPK: 6352932 BKG: 6352932 Bromide 98 90-110 N.D. N.D. 0 (1) 20 Chloride 110 90-110 3.8 3.7 0 (1) 20 Fluoride 103 90-110 N.D. N.D. 0 (1) 20 Nitrate Nitrogen 102 90-110 N.D. N.D. 0 (1) 20 Nitrite Nitrogen 97 90-110 N.D. N.D. 0 (1) 20 Sulfate 100 90-110 N.D. N.D. 0 (1) 20 Batch number: 11203020002A Sample number(s): 6352932-6352938 BKG: P352815 pH 7.4 7.4 1 3 Batch number: 11203020002B Sample number(s): 6352939 BKG: 6352939 pH 5.9 5.9 0 3 Batch number: 11207023001A Sample number(s): 6352932-6352939 UNSPK: 6352934 BKG: 6352934 Sulfide 86 97 50-130 12* 10 N.D. N.D. 0 (1) 5 Batch number: 11207023002A Sample number(s): 6352932-6352939 UNSPK: P349524 BKG: P349524 Dissolved Sulfide 81 93 50-130 14* 10 N.D. N.D. 0 (1) 5 Batch number: 11213028001A Sample number(s): 6352932-6352939 BKG: 6352932 Specific Conductance 77.9 78.0 0 3 Surrogate Quality Control Surrogate recoveries which are outside of the QC window are confirmed unless attributed to dilution or otherwise noted on the Analysis Report. Analysis Name: EPA SW846/8260 (water-25m1) #1 Batch number: C112061AA Dibromofluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromofluorobenzene 6352931 97 98 103 98 6352932 95 97 103 104 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. IILancaster Laboratories Analysis Report 2425 New Holland Pike, PO Box 12425, Lancaster, PA 17605-2425 •717-656-2300 Fax:717-656-2681 • www.lancasterlabs.com Page 3 of 3 Quality Control Summary Client Name: Atlantic Richfield c/o URS Group Number: 1257767 Reported: 08/08/11 at 11:13 AM Surrogate Quality Control 6352933 95 99 102 101 6352934 96 98 102 102 6352935 93 104 102 100 6352936 95 101 102 100 6352937 95 98 102 98 6352938 96 99 102 100 6352939 95 102 103 101 Blank 99 100 102 100 DUP 95 100 102 100 LCS 98 97 102 102 LCSD 97 98 103 101 Limits: 77-114 74-113 77-110 78-110 Analysis Name: Volatile Headspace Hydrocarbon Batch number: 112110022A Propene 6352932 85 6352933 88 6352934 50 6352935 89 6352936 66 6352937 47 6352938 43 6352939 44 Blank 90 LCS 89 MS 56 MSD 54 Limits: 42-131 *- Outside of specification **-This limit was used in the evaluation of the final result for the blank (1) The result for one or both determinations was less than five times the LOQ. (2) The unspiked result was more than four times the spike added. I Lancaster Laboratories Case Narrative Project Name: BP 4762 LLI Group #: 1257767 General Comments: Through our technical processes and second person review of data, we have established that our data/deliverables are in compliance with the methods and project requirements unless otherwise noted or previously resolved with the client. The compliance signature is located on the cover page of the Analysis Reports. See the Laboratory sample Analysis Record section of the Analysis Report for the method references. A11 QC met criteria unless otherwise noted in an Analysis Specific Comment below. Refer to the QC Summary for specific values and acceptance criteria. Project specific QC samples are not included in this data set Matrix QC may not be reported if site -specific QC samples were not submitted. In these situations, to demonstrate precision and accuracy at a batch level, a LCS/LCSD was performed, unless otherwise specified in the method. Surrogate recoveries (if applicable) which are outside of the QC window are confirmed unless attributed to a dilution or otherwise noted in an Analysis Specific Comment below. The samples were received at the appropriate temperature and in accordance with the chain of custody unless otherwise noted. Analysis specific comments: RSKSOP-175 08/11/94 modified, GC Miscellaneous Batch #: 112110022A (Sample number(s): 6352932-6352939 UNSPK: 6352932) The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: Methane The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Methane sw-846 6010c, Metals Batch #: 112040651001 (Sample number(s): 6352932-6352939 UNSPK: 6352932 BKG: 6352932) The recovery(ies) for the following analyte(s) in the MS and/or MSD was outside the acceptance window: Magnesium v 1.8.6 8/8/2011 11:17:43AM SM20 4500 52 D. wet Chemistry Batch #: 11207023001A (Sample number(s): 6352932-6352939 UNSPK: 6352934 BKG: 6352934) The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: sulfide Batch #: 11207023002A (Sample number(s): 6352932-6352939 UNSPK: P349524 BKG: P349524) The relative percent difference(s) for the following analyte(s) in the MS/MSD were outside outside acceptance windows: Dissolved Sulfide Sample #s: 6352932 Reporting limits were raised due to interference from the sample matrix. v 1.8.6 8/8/2011 11:17:43AM Yc neld ompany Q A BP affiliated company Geri. MS77497 c�,+,.►Q1�* 3Sag3l-39 Laboratory Management Program LaMP Chain of Custody Record Page of 1 10-business days from receipt Rush TAT: Yes _ No X BP/ARC Project Name: BP/ARC Facility No: Paw Creek -BP Req Due Date (mm/ddlyy): Lab Work Order Number: Lab Name: Lancaster Laboratories BP/ARC Facility Address: 7401 Old Mount Holly Road Consultant/Contractor: URS Corporation - North Carolina Lab Address: 2425 New Holland Pike, Lancaster, PA 17605 City, State, ZIP Code: Charlotte, NC Consultant/Contractor Project No: Paw Creek -BP - 38436615.104080 Lab PM: Lynn Frederiksen Lead Regulatory Agency: NCDENR DWG - GW Section Address: 1600 Perimeter Park Road, Suite 400, Morrisville, NC 27560 Lab Phone: 717-656-2300 California Global ID No.: Consultant/Contractor PM: Margaret Ness Lab Shipping Accnt: Lancaster: 1077-8526.4 Enfos Proposal No: 006KN-0002 Phone: 919-461-1100 Lab Bottle Order No: Accounting Mode: Provision X OOC-BU OOC-RM Email EDD To: Martha Meyers-Lee@urscorp.com Other Info: Stage: 40 Activity: 80 - Operate / Project Spend Invoice To: BP/ARC X Contractor_ BP/ARC EBM: Greg Frisch Matrix No. Containers / Preservative Requested Analyses Report Type & GC Level EBM Phone: 216 271-8740 a A 3 g a Total Number of Containers Unpreserved vN x Z s HCI NaOH .a c = p z BTEX, MTBE, IPE, Naphthalene, & 1,2-I]CA (8260B) F- (EPA 300) & H2S (pH & conductance) (4500 S2F) H2S (dissolved S2-) (4500 S2F) (Total Magnesium (6010C) J Br-, Cl-, NO2-, NO2-, & SO4-2 (EPA 300) Methane (RSKSOP-175) Total Sulfa (4500 S2 D) Standard Full Data Package _L_ EBM Email: Greg.Frisch@bp.com No. Sample Description Date Time Comments Nate: If sample not collected, indicate "No Sample" in comments and single -strike out and initial any preprinted sample description. Trip Blank J .71(A i/ — x g 3. r� _ i'r Viac 7411 ll _% c a& x 11 3 1 5 1 1 3 1 1 1 2 2 1 II 1 IV --4 V '71a1ji1 Imo x 11 3 1 5 1 1 3 1 1 1 2 2 1 1)1.41—"01./ 7/211,1 /OM — x` 11 3 1 5 1 1 3 1 1 1 2 2 1 lhtv-At ?121IiL fop x 11_ 3 1 5 1 1 3 1 1 1 2 2 1 JJ r-i(A/-6J /hill/ lilt. x 11 3 1 5 1 1 3 1 1 1 2 2 1 01w ! q lilt lli /a lir x 11 3 1 5 1 1 3 1 1 1 2 2 1 1 }i —"Of)�f ! FI I160 x 11 3 1 5 1 1 3 1 1 1 2 2 1 f►2rGrG0 ill iii jg1D 11 3 1 5 1 1 3 1 1 1 2 2 1 a `x 0 Sampler's Name: 5-. r BA I Slap 5 45 _ Relinquished By / Affiliation Date Time -_Accepted By / Affiliation Date Time Sampler's Company: URS Corporation - North Carolina i U 1-5 712111 i r706 Shipment Method: FedEX Ship Date: 71211 if Shipment Tracking No: 3 S j,1L3 3.. t t t �+�t.l, I N D Special Instructions: Reter to attached Sample Kit Request for analytical scope of work. NOTE: Short Holding times (pH, nitrate, and nitrite)! H2S Is determin m dissolved sulfide, pH, and specific conductance. Contact Martha Meyers -Lee (919-461-1519) regarding all sample receipt and analytical non-conformance Issues. THIS LINE - LAB USE ONLY: Custody Seals In Ptat ys4 No I Temp Blad / No I Cooler Temp on Receipt: � -la...' _`F/C I Trip Bla ' No 1 MSIMSD Sample Submitted: YescriG�`� nlos or lielease 21 mbi BP/ARC LAMP COC Rev. 6 01/01/2009 Subcontract No. N/A Client: Client PM: Project: Location: Date Needed: Sample Date: Invoice To: SOW: Revision No. 4 Date Page 7/19/11 1 of 3 BOTTLE REQUEST FORM (Email to: ifrcderiksen@lancasterlabs.com, TSnaide@lancasterlabs.com) BP Greg Frisch BP 4762 Epsom Salt Pilot Study U7401 Old Mount Holly Road, Charlotte. NC Week of May 16, 2011 and specific intervals thereafter' [X] BP (Direct bill): [ ] Submit via Enfos system OR [ ] URS Corporation (subcontract) Consultant: Consultant PM: Consultant TL: URS Project #: Project Chemist: Phone No.: URS Corporation Margaret Ness Scott Smida 38436615.104080 Martha Meyers -Lee. Morrisville 919-461-1519 [X] Submit to URS Corporation -. i i�•a naS uas't�. i'II:�i:i� 7 pi " ll,l rr'tir•!.�1!�.. !� ��a:, .np p.: ;.eIac:u1ys61.'4 .. d`i "wft,:t1. ,I, 41 .4:1 fir[ IPI � : �4 W �ix 4 y'h !I:(axyy : :NI ��.Y9]:��� ," II iup " l Y Unit Rateistiit<! SW-846 8260B (25 ml purge) Benzene Toluene Ethylbenzene Xylenes MTBE IPE Naphthalene 1,2-DCA 1 600 600 500 20 70 6 0.4 X-434 $95 1 0 8 8 8 8 8 41 SM18 4500 S2 F Hydrogen Sulfide: (Dissolved Sulfide, Calculation, Conductance, PH) - - X-065 NA X-059 X-046 $53 ($23 $10 $ l2 $8) 1 8 8 8 8 8 8 49 SM20 4500 S2 D Total Sulfide - X-065 $23 SW-846 6010B Total Magnesium - X-113 $30 EPA 300 Bromide Chloride Fluoride Nitrate Nitrite Sulfate - 250,000 2,000 1,000 10,000 250,000 X-005 X-010 X-020 X-035 X-036 X-064 $19 $19 $19 $19 $19 $19 EPA 300 Sulfate 250,000 X-064 $19 1 0 0 0 0 0 0 1 KShSOP- 175 08/11/94 . Methane - X-295 $65 - 8 8 8 8 8 8 48 µ!/- SM Micrograms per liter Standard Methods DCA Dichloroethane IPE Isopropyl ether MTBE Methyl tent-bu yl ether Analytical work is to be conducted in accordance with: • Technical Requirements For Environmental Laboratory Analytical Services BP Laboratory Management Program (LaMP), Atlantic Richfield Company- a BP- affiliated company, Revision 09 — FINAL Issued: 07/30/2007 • UST Section Guidelines For The Investigation And Remediation Of Contamination From Non -UST Petroleum Releases„ NC DENR, UST Section, current version , which is available at http://www.wastenotnc.org/ust/docs/Non-USTGuid053107.pdf Sample results are to be analyzed at the lowest dilution possible without harm to the instrument, and then at the proper dilution to ensure that regulatory levels are achieved. Results are to be reported to the Method Detection Limit. Sample concentrations that are less than the PQL, but greater than the MDL are to be J-flagged. A trip blank will be included in the each shipment of VOA samples submitted to the laboratory. It is anticipated that samples will be collected the week of May 16, June 16 and 22, July 20, August 17, and November 16, 2011, and February 15, 2012 2 Detection limits shall be less than the PQL or NC Groundwater Protection Standard (2L), whichever is lower. 3 Week of May 16, 2011 4 Week of June 6, 2011 5 Week of June 22, 2011 6 Week of July 20, 2011 7 Week of August 17, 2011 8 Week of November 16, 2011 9 Week of February 15, 2012 P:\BPWrojects\Terminals\4762\4.0 Site Data\4.6 Analytical\Analytical.Requests\2011\BP 4762 Bottle Request Form Pilot Study (05-25-11, v4).doc Last printed 7/19/2011 3:13:00 PM Subcontract No. N/A Revi.xian No. 4 Date 7/19/11 Analytical TAT: Standard (10 business days) Laboratory Certification: NC DWO ' Applicable Standard(s): NC 2L Electronic Deliverable: Page 2 of 3 Laboratory report containing Case Narrative, summary of sample results and associated OC results, Sample Receipt paperwork, and COC record; EDD formatted in Excel for the EnviroData program; and electronic copy (pdf) of the invoice Electronic Deliverable to: Martha Meyers-lee@urscorp.com, (919) 461-1519 Supplies Needed10: Batch 1— Week of May 16, 2011 • 6 40-m1 VOA vials, pre -preserved with HCI, for the SW-846 8260B analysis (based on 3 vials per sample plus a spare set) • 6 40-m1 VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples must be shipped on the day of sample collection • because of a 48-hour holding time) (2 per sample, 2 spare) • 1 500-m1 plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 1 glass bottles of sufficient size, pre -preserved with Zinc Acetate and NaOH, for the determination of total sulfide (1 per sample) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 1 glass 500 mL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 1 plastic bottles of sufficient size, pre -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • 1 Trip blank, consisting of 2-40 mL VOA vials preserved with HCI acid to a pH 2. Integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) Batch 2 — Week of June 6, 2011 • 18 40-ml VOA vials, pre preserved with HCI, for the RSKSOP-175 analysis (based on 2 vials per sample plus a spare set) • 18 40-m1 VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples mast be shipped on the day of sample collection • because of a 48-hour holding time) (2 per sample, 2 spare) • 8 500-ml plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 9 glass bottles of sufficient size, pre -preserved with Zinc Acetate and NaOH, for the determination of total sulfide (1 per sample, 1 spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 9 glass 500 mL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample, 1 spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 8 plastic bottles of sufficient size, pre -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • 1 Trip blank, consisting of 2-40 mL VOA vials preserved with HCI acid to a pH <2. integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) Batches 3-7 — Week of June 22, July 20, August 17, November 16, 2011, and February 15, 2011 • 27 40-m1 VOA vials, pre -preserved with HCI, for the SW-846 8260B analysis (based on 3 vials per sample plus a spare set) • 18 40-rnl VOA vials, pre preserved with HCI,, for the RSKSOP-175 analysis (based on 2 vials per sample plus a spare set) • 18 40-m1 VOA vials, unpreserved, for the EPA 300 analysis (NOTE: Nitrate and sulfate samples must be shipped on the day of sample collection • because of a 4/3-hour holding time) (2 per sample, 2 spare) • 8 500-ml plastic bottles, unpreserved, for the determination of pH and specific conductance (NOTE: Samples must be shipped on the day of sample collection because of short holding time for pH) (1 per sample) • 9 glass bottles of sufficient size, pre -preserved with Zinc Acetate and NaOH, for the determination of total sulfide (1 per sample, / spare) (NOTE: Collect sample with ntittimum aeration and fill bottle completely) • 9 glass 500 mL bottles, pre -preserved with NaOH, for the determination of hydrogen sulfide (1 per sample,l spare) (NOTE: Collect sample with minimum aeration and fill bottle completely) • 8 plastic bottles of sufficient size, pre -preserved with nitric acid (HNO3), for the determination of total magnesium (1 per sample) • 1 Trip blank, consisting of 2-40 mL VOA vials preserved with HCl acid to a pH <2. Integrity seals and bottle labels • Coolers labeled with laboratory name and address • Insulation and absorbent packing material • Temperature blank (1 per cooler) • Federal Express air bills (1 per cooler) 1° Container types and numbers per State Guidelines P:1BP\Projects\Terminals\4762\4.0 Site Data14.6 Analytical\Analytical Requests\2011\BP 4762 Bottle Request Form Pilot Study (05-25-11, v4).doc Page 2 of 3 Subcontract No. N/A DI H2O: None Ship Supplies To: [ ] JNamel URS Corporation 1600 Perimeter Park Drive. Suite 400 Morrisville, NC 27560 Phone No. (919) 461-1100 Scott Smida URS Corporation 6135 Park South Drive, Suite 300 Charlotte. NC 28210 Phone No. 704-522-0330 Revision .No. 4 Date Page 7/19/11 3 of 3 [ ] JNamel PLEASE INCLUDE "4762-PilotStudy" on the outside of the cooler to facilitate retrieval from our mailroom. Kit Request Taken By: Date: Kit Completed By: Date Sent: P:1BP\Projects\Terminals\476244.0 Site Data14.6 Analytical\Analytical Requests120111BP 4762 Bottle Request Form Pilot Study (05-25-11, v4).doc Page 3 of 3 Lancaster Laboratories Environmental Sample Administration Receipt Documentation Log Client/Project: \ C t& .) Lakt 1tL�'f Shipping Container Sealed: `OFF NO Date of Receipt: c o�+1 . Time of Receipt: Source Code: 5 Custody Seal Present * : NO * Custody seal was intact unless otherwise noted in the discrepancy section Package: Not Chilled Temperature of Shipping Containers Cooler # Thermometer ID Temperature CC) Temp Bottle (TB) or Surface Temp (ST) Wet Ice (WI) or Dry Ice (DI) or Ice Packs (IP) Ice Present? Y/N Loose (L) Bagged Ice (B) or NA Comments 1 9V:3. Q. -ce i \Y 13 2 . .y 3 \\.) 3\J VV V 4 5 6 Number of Trip Blanks received NOT listed on chain of custody: Paperwork Discrepancy/Unpacking Problems: Unpacker Signature/Emp#5.., t Date/Time: Issued by Dept. 6042 Management 2174.06 1IEes Explanation of Symbols and Abbreviations The following defines common symbols and abbreviations used in reporting technical data: RL N.D. TNTC IU umhos/cm C meq g ug ml m3 Reporting Limit none detected Too Numerous To Count International Units micromhos/cm degrees Celsius milliequivalents gram(s) microgram(s) milliliter(s) cubic meter(s) BMQL MPN CP Units NTU ng F Ib. kg mg ul Below Minimum Quantitation Level Most Probable Number cobalt-chloroplatinate units nephelometric turbidity units nanogram(s) degrees Fahrenheit pound(s) kilogram(s) milligram(s) liter(s) microliter(s) < less than - The number following the sign is the limit of auantitation, the smallest amount of analyte which can be reliably determined using this specific test. > greater than J estimated value — The result is >_ the Method Detection Limit (MDL) and < the Limit of Quantitation (LOQ). ppm parts per million - One ppm is equivalent to one milligram per kilogram (mg/kg), or one gram per million grams. For aqueous liquids, ppm is usually taken to be equivalent to milligrams per liter (mg/I), because one liter of water has a weight very close to a kilogram. For gases or vapors, one ppm is equivalent to one microliter of gas per liter of gas. ppb parts per billion Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight basis concentration to approximate the value present in a similar sample without moisture. All other results are reported on an as -received basis. U.S. EPA CLP Data Qualifiers: Organic Qualifiers A TIC is a possible aldol-condensation product B Analyte was also detected in the blank C Pesticide result confirmed by GC/MS D Compound quantitated on a diluted sample E Concentration exceeds the calibration range of the instrument N Presumptive evidence of a compound (TICs only) P Concentration difference between primary and confirmation columns >25% U Compound was not detected X,Y,Z Defined in case narrative Inorganic Qualifiers B Value is <CRDL, but E Estimated due to interference M Duplicate injection precision not met N Spike sample not within control limits S Method of standard additions (MSA) used for calculation U Compound was not detected W Post digestion spike out of control limits * Duplicate analysis not within control limits + Correlation coefficient for MSA <0.995 Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis. Measurement uncertainty values, as applicable, are available upon request. Tests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved, the test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact us. We cannot be held responsible for sample integrity, however, unless sampling has been performed by a member of our staff. This report shall not be reproduced except in full, without the written approval of the laboratory. WARRANTY AND LIMITS OF LIABILITY - In accepting analytical work, we warrant the accuracy of test results for the sample as submitted. -- THE FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED. WE DISCLAIM ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF MERCHANTABILITY. IN NO EVENT SHALL LANCASTER LABORATORIES BE LIABLE FOR INDIRECT, SPECIAL, CONSEQUENTIAL, OR INCIDENTAL DAMAGES INCLUDING, BUT NOT LIMITED TO, DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS OF (A) THE NEGLIGENCE (EITHER SOLE OR CONCURRENT) OF LANCASTER LABORATORIES AND (B) WHETHER LANCASTER LABORATORIES HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal responsibility for the purposes for which the client uses the test results. No purchase order or other order for work shall be accepted by Lancaster Laboratories which includes any conditions that vary from the Standard Terms and Conditions, and Lancaster hereby objects to any conflicting terms contained in any acceptance or order submitted by client. Appendix B Biosparge Test Wells and Monitoring Well Boring Logs URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/27/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-04 DATE FINISHED: 8/27/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 10 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE / SAMPLE NUMBER Blow Counts w J 0 cc a DESCRIPTION co U E n 0 WELL CONSTRUCTION 0.0 -5.0 -10.0 - 15.0 - 20.0 -5 -10 -15 -20 -25.0 -25 Air Knife 1{ f, x Backfill: Air Knife backfill Backfill 15.2 273 50 980 WSW/ . . 4.25 HSA Sandy Silt: reddish brown, soft, moist ML Sandy Silt: light brown, soft, moist Sandy Silt: light brown, wet '.- Sandy Silt: light brown to gray, moist Partially Weathered Rock: sandy silt light brown to gray, firm, moist Clay: reddish brown tograyCL . Y / _@� °-_• Sandy Silt: light brown to gray, soft, wet 41410 Concrete Pad Locking Well Cap Steel •Well Vault Grout PVC Casing URS Air Sparge Well AS-04 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina o� z1-:v in (0 (0 W co F2 a M SHEET: AS-04 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/27/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-04 DATE FINISHED: 8/27/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 10 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts W -J O cc 0 DESCRIPTION U co E 0 n. WELL CONSTRUCTION -25.0 -25 -30.0 -35.0 -30 -35 Sandy Silt: light brown, stiff, moist ML 873 1127 Bentonite Plug #2 Filter Sand 0.010 Slot Screen URS Air Sparge Well AS-04 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina } U) SHEET: AS-04 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 9/10/2010 DRILLER:William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-05 DATE FINISHED: 9/10/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 28 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE / SAMPLE NUMBER Blow Counts w J 1 0 a DESCRIPTION E O. 0 a WELL CONSTRUCTION 0.0 0 -5.0 -10.0 -15.0 -20.0 -5 -10 -15 -20 -25.0 -25 Air Knife )+i '°,., •'`" 1°',c, o z 511 1i Gravelly Sand: Grey; Air Knife backfill SW 4.25 HSA \\ kS14 Clay: Reddish brown, dry CL „ Silty Clay: Reddish brown, dry T. odd Concrete Pad Locking Well Cap Steel Well Vault Grout PVC Casing URS Air Sparge Well AS-05 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina 03 co Y w 6 ov z1.0 wM 3 a. M0. SHEET: AS-05 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 9/10/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-05 DATE FINISHED: 9/10/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 28 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts w J u- O cc a. DESCRIPTION E n 0 a WELL CONSTRUCTION -25.0 -25 -30.0 -35.0 -30 -35 Bentonite Plug #2 Filter Sand 0.010 Slot Screen URS Air Sparge Well AS-05 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina g a c co ov z. )-LO w cam+) Nr co a. ce> SHEET: AS-05 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/25/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-06 DATE FINISHED: 8/25/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE / SAMPLE NUMBER Blow Counts w J O 0 DESCRIPTION E 0. Q. 0 WELL CONSTRUCTION 0.0 0 -5.0 -10.0 -15.0 -5 -10 -15 -20.0 -20 Clay: reddish brown; Air Knife backfill e® 35.7 CL r° Silty/Sandy Clay: reddish brown to light brown, wet 334 M Air Knife Clayey Silt: light brown, wet ML 44.7 rew -W .` Silty Sand: brown grading to light brown, stiff, dry grading to wet rTsx." ir ufi ba. rn`, :im Dae` ae.ii m;a, 380 JAW Concrete Pad Locking Well Cap Steel Well Vault Grout PVC Casing Bentonite Plug URS Air Sparge Well AS-06 BP Terminal 4762 7401 Old Mount. Holly Road Charlotte; North Carolina 0 rn 0 0 U U • ov zv 1-co w co c3 a cam') SHEET: AS-06 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/25/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: AS-06 DATE FINISHED: 8/25/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts w J 0 0 DESCRIPTION U U) E a WELL CONSTRUCTION -20.0 -20 -25.0 -25 4.25 HSA aT -0'- • Partially Weathered Rock: silty sand, light brown, stiff, wet SM #2 Filter Sand 0.010 Slot Screen Air Sparge Well AS-06 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina o� ov zv }-U) w r a co SHEET: AS-06 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/25/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: MW-65 DATE FINISHED: 8/25/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts w J u- O cc o_ DESCRIPTION 0) U CO E 0. 0 0 WELL CONSTRUCTION 0.0 0 -5.0 - 10.0 - 15.0 -5 -10 -15 - 20.0 -20 Air Knife \ Clay: reddish brown, moist; Air Knife backfillo CL 58.8 1227 555 928 ""'� "° AZOIO • .. 4.25 NSA '‘%\\ Clay: brown, wetk i imi �°s , ww. micu ' C: 51 ° Clay: light brown, wet inii Cr. iI Silty Clay: light brown, wet Concrete Pad Locking Well Cap Steel Well Vault Grout Bentonite Plug PVC Casing #2 Filter Sand 0.010 Slot Screen URS Monitoring Well MW-65 BP Terminal 4762 7401 Old Mount Holly Road Charlotte; North Carolina } 0 0 w u) ov z1-0 0(O w . co SHEET: MW-65 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/26/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: MW-66 DATE FINISHED: 8/26/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts DESCRIPTION E a a WELL CONSTRUCTION 0.0 0 -5.0 -10.0 -5 -10 -15.0 -15 Air Knife a< x6s` ' gc Gravelly Sand: with clay; Air Knife backfill SW 292 58.7 i/ 4.25 HSA�T��� - W_' - Sandy Silt: greenish gray to brown, moist ML ` —_ t `,`� Clay: light brown, wet CL gs Gravelly Sand: gray, stiff, dry.'4 SW — Silt: gray to light brown, firm, slightly moist ML i%€ Concrete Pad Locking Well Cap Steel Well Vault Grout Bentonite Plug PVC Casing #2 Filter Sand 0.010 Slot Screen URS Monitoring Well MW-66 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina >- co ° o U) CHECKED BY: o.v zv 0(.0 tam a M SHEET: MW-66 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/26/2010 DRILLER: William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: MW-67 DATE FINISHED: 8/26/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE TYPE/ SAMPLE NUMBER Blow Counts w J L 0 a DESCRIPTION E a 0 0- WELL CONSTRUCTION 0.0 0 -5.0 -10.0 -5 -10 -15.0 -15 Airy Knife A o` d 741 rmz ecl CicAl a Gravelly Sand: Air Knife backfill SW 373 %/NIL o - , 3 Sandy Silt: brown and gray, moist 4.25 HSA ML 172 • `_� _ Sandy Silt: brown and gray, moist; grades to partially weathered rock: brown and gray, silty sand, dense, dry 1— Pad Locking Well Cap Steel Well Vault Grout Bentonite Plug PVC Casing #2 Filter Sand 0.010 Slot Screen URS Monitoring Well MW-67 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina ga o� W U 0fx ov zV W(0 U V a.M SHEET: MW-67 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436544 DATE BEGAN: 8/26/2010 DRILLER:William B. Kicker TOP OF CASING ELEVATION: Not yet surveyed DRILLING METHOD: Hollow Stem Auger CONTRACTOR: Mad Dawg, Inc. BORING NO: MW-68 DATE FINISHED: 8/26/2010 NORTH: Not yet surveyed GWL DATE/TIME: DRILL EQUIP: Air Knife; Hollow Stem Auger PROJECT NAME: BP 4762 FIELD ENGINEER: Scott A. Smida EAST: Not yet surveyed GWL DEPTH: 8 ft bgs CHECKED BY: URS ELEV (FT.) DEPTH (FT.) DRILLING METHOD SAMPLE Blow TYPE / Counts SAMPLE NUMBER w J L 0 a DESCRIPTION 0) U co E a a WELL CONSTRUCTION 0.0 0 -5.0 -5 -20.0 -20 Air Knife 4 Silt: light brown, stiff, dry; Air Knife backfill ML 326 737 4.8 4.25 HSA '� Sandy Silt: light brown, stiff, dry �`== ` 1 eR a Sandy Silt: gray, silt grading to dark brown, sandy silt, firm to loose, dry to moist 1.1 Concrete Pad Locking Well Cap Steel Well Vault Grout Bentonite Plug PVC Casing 44- #2 Filter Sand 0.010 Slot Screen Monitoring Well MW-68 BP Terminal 4762 7401 Old Mount Holly Road Charlotte, North Carolina c U) CHECKED BY: SHEET: MW-68 URS LITHOLOGIC LOG / WELL CONSTRUCTION LOG PROJECT NO: 38436614 BORING NO: MW-69 PROJECT NAME: BP 4762 DATE BEGAN: 5/23/2011 DATE FINISHED: 5/23/11 FIELD ENGINEER: Scott Smida DRILLER: William Kicker NORTH: EAST: TOP OF CASING ELEVATION: GWL DATE/TIME: 5/24/2011 GWL DEPTH: 9.14 ft btoc DRILLING METHOD: 4 1/4" ID HOLLOW STEM AUGER DRILL EQUIP: Geoprobe 6620DT CHECKED BY: URS CONTRACTOR: Mad Dawg, Inc. DEPTH (FT.) DRILLING METHOD SAMPLE TYPE / SAMPLE NUMBER Blow Counts w J 0 CC a. DESCRIPTION E n a 0 0 WELL CONSTRUCTION 0.0 -5.0 -10.0 -15.0 0 -5 -10 -15 0.0 0.0 0.7 10.3. Hand Auger I ' ra Sandy Silt: light brown, moist SM ..• L - 9 Sandy Silt: light brown, dry Hollow Stem Auger i` - Sandy Silt: light brown, dry to moist Sandy Silt: light brown, moist Locking Well Cap Protective Steel Cover Concrete Pad Grout Bentonite Plug 2" PVC Casing #2 Filter Sand 0.010. Slot Screen URS MW-69 Well Installation Log BP 4762 7401 Old Mount Holly Road Charlotte, NC Q> K U) r m G W Z o 2 SHEET: MW-69 APPENDIX I BIOSPARGE DESIGN CALCULATIONS Table 1: Biosparge Well Air Flow and Cycle Schedule BP 4762 Revised May 2012 Flow Distribution Well ID Well flow (cfm) AS-1 3 AS-2 3 AS-3 3 AS-4 3 AS-5 3 AS-6 3 AS-7 3 AS-8 3 AS-9 3 AS-10 3 AS-11 3 AS-12 3 AS-13 3 AS-14 3 AS-15 3 AS-16 3 AS-17 3 AS-18 3 AS-19 3 Total 57 Totall2 28.5 Total/2*1.25 35.625 Notes Proposed Cycle Descriptions Cycle Description Cycle Flow Cycle Flow*1.25 1 = Vertical Well Set 1 30 37.5 2 = Vertical Well Set 2 27 33.75 Proposed Cycle Sequence Time Period Cycle 0:00-2:00 1 2:00-4:00 2 4:00-6:00 1 6:00-8:00 2 8:00-10:00 1 10:00-12:00 2 12:00-14:00 1 14:00-16:00 2 16:00-18:00 1 18:00-20:00 2 20:00-22:00 1 22:00-24:00 2 Vertical Well Set 1 Vertical Well Set 2 AS-1 AS-2 AS-3 AS-4 AS-5 AS-6 AS-7 AS-8 AS-9 AS-10 AS-11 AS-12 AS-13 AS-14 AS-15 AS-16 AS-17 AS-18 AS-19 APPENDIX J ISOC® DESIGN SCHEMATICS Draft - Interim Deliverables\RSDD and SCM\Draft\FIqures\Appendix H Figure 1_ - Blosparge PID dw P:\BP\Pro_Jects\Terminals\4762\5,0 Deliverables\5,1 1/2" 304 STAINLESS STEEL PIPE 1/2" RUBBER AIR HOSE 1 /2" 304 STAINLESS STEEL & 3/8" POLY TUBING 19 SPARGE LEGS 0 ❑S �•� I // y '/ 1 /2" 304 STAINLESS STEEL & 3/8" POLY TUBING 19 SPARGE LEGS 2" 304 STAINLESS STEEL AIR SPARGE WELL #1 1/2" 304 PI I® STAINLESS STEEL PIPE 1/2" RUBBER AIR HOSE AIR SPARGE WELL #2 LEGEND G4 BALL VALVE N CHECK VALVE l�Cl SOLENOID VALVE I I M 4 PNEUMATIC VALVE UNION DIAPHRAGM VALVE PRESSURE RELIEF VALVE OIL REMOVAL FILTER LIQUID SEPARATOR PRESSURE INDICATOR PRESSURE INDICATOR/TRANSMITTER TEMPERATURE INDICATOR VACUUM INDICATOR FLOW INDICATOR FLOW IN DICATOR/TRANSM ITT ER DISTRIBUTION BOX PRESSURE REGULATOR // //_ POLY TUBING VENT AIR RECEIVER PRESSURE GAUGE 2" 304 STAINLESS STEEL NOTES: AIR HOSE FOR COMPRESSOR MAINTENANCE ZI u ROTARY SCREW COMPRESSOR 70 SCFM @ 50 PSI (Approx.) (EQUIPPED w/ AFTER COOLER AND FILTER) CONDENSATE/OIL COLLECTION AND TREATMENT SYSTEM AUTO DRAIN FILTERED WASTEWATER TO CONTAINER OR SANITARY SEWER 1. SOLENOID VALVES SHALL CYCLE AUTOMATICALLY USING PROGRAMMABLE LOGIC CONTROLLER (PLC). EQUIPMENT VENDOR SHALL PROGRAM PLC ACCORDING TO A SCHEDULE PROVIDED BY THE ENGINEER. 2. FLOW (FIT) AND PRESSURE (PIT) TRANSMITTERS SHALL INDICATE LOCALLY IN SCFM AND PSIG (RESPECTIVELY) AND OUTPUT 4-20MA SIGNAL TO PLC. 3. REFER TO SPECIFICATIONS FOR AUTODIALER ALARM REQUIREMENTS. 4. EQUIPMENT VENDOR SHALL SUBMIT A PROCESS & INSTRUMENTATION DIAGRAM WHICH INCLUDES ALL CONTROL AND MONITORING COMPONENTS. AIR SCALE NONE DESIGNE➢ BY DATE CONFIDENTIAL -ALL RII3ITS RESERVED-PREPERTY OF KW, NDRIH CAROLINA 27560 DRAWN BY TSH DATE 24MAY12 CHECKED BY AWS DATE 24MAY12 APPROVED BY JK DATE 24MAY12 Appendix J: Biosparge Process and Instrumentation Diagram BP Terminal 4762/Southeast Terminal, Charlotte, NC CONTRACT NO. J3-00004762.01 ➢RAVING NO. FIGURE-1 REV. 0