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WI0300148_Regional Office Historical File Pre 2018
NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Charles Wakild, P. E. Dee Freeman Governor Director Secretary February 14, 2013 Scott Ziegler BP Products North America, Inc. 28100 Torch Parkway, MC 2 South Warrenville, IL 60555 Subject: Completion of Injection Well Permit WI0300148 Paw Creek — BP Terminal Mecklenburg County Dear Mr. Ziegler: On August 3, 2012, the Aquifer Protection Section received the Final Project Evaluation for injection activities conducted under the permit referenced above. This report completes the monitoring and compliance reporting requirements of the permit. Staff from the Mooresville Regional Office confirmed that there are no outstanding reporting, compliance, or enforcement issues associated with this permit. Any other compliance monitoring or reporting requirements of any other regulatory programs shall continue as needed. If you wish to conduct future injection operations you must first apply for and receive a new injection well permit. Operating an injection well without a valid permit could result in a civil penalty of up to $25,000 per day. Please contact me at 919-807-6412 or thomas.slusser@ncdenr.gov if you have any questions. cc: Best R gards, 4=.- fry-n<0 .SLAAA—OZk_ Thomas Slusser, L.G. Underground Injection Control Program Manager iclr,egionalLO ce—, Margaret Ness — URS Corporation — North Carolina (email) Ed Leach — DWM Mooresville Regional Office (email) Jon Bandzul — Sage Environmental Consulting, L.P. (email) WI0300148 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury St. Raleigh, North Carolina 27604 Phone: 919-807-64641 FAX: 919-807-6496 Internet: www.ncwaterqualitv.org/web/wq/aps One orthCarolina Naturally An Equal Opportunity i Affirmative Action Employer North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director July 9, 2010 Scott Ziegler BP Products North America Inc. 28100 Torch. Parkway, MC 2 South Warrenville, I1 60555 • Ref: Additional Information Request Injection Well Permit Application No. WI0300148 Paw Creek — BP Terminal Mecklenburg County Dear Mr. Ziegler: SEP 2 2 2010 NC 1' EN MRO EM10,w AoLiifer P ntectian Dee Freeman Secretary The Aquifer Protection Section is currently reviewing the above referenced Permit Application received June 22, 2010 and has identified an item that needs additional information. Address the following issue as required: • A discrepancy exists between the injectant volume indicated in Section IV.B which, appears to total 40,000 gallons (2000 gallons per event for 20 events), and that indicated in Attachment D paragraph 2 which would be approximately 8,000 gallons (4,000 gallons per test area in two test areas). Please provide a more concise explanation of the injection as based on a per boring estimate for the twenty borings proposed. • In the above requested per boring explanation, also provide the estimated injection depth intervals for each zone. In addition, if a boring needs to be advanced by auger, please provide a description of the method injection will occur. • Does Figure 1 a. of Attachment H indicate the true dimensions (32' x 21') of the proposed injection areas? If you have any questions regarding this request, please contact me at (919) 715. 6168 or email me at john.mccray@ncmail.net. Thank you in advance for your cooperation and timely response. Sincerely, John McCray Environmental Specialist AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 Phone: 919-733-3221 \ FAX 1: 919-715-0588; FAX 2: 919-715-6048 \ Customer Service: 1-877-623-6748 Internet: www.ncwateraualitv.orq An Equal Opportunity \ Affirmative Acton Employer NorthCarolina Native, Cc: Margaret Ness, URS Corporation — North Carolina Ed d Leach NCDENR, Mooresville Regional Office oostesville Regional Office Permit File I0300 8 Beverly Eaves Perdue Governor North Carolina Department of Environment and Natural Resources Division of Neater Quality Coieen H. Sullins Director March 28, 2011 BP Products North America lnc. Attn:-Scott Ziegler, RM Operations Project Manager 28100 Torch Parkway, MC 2 South Warrenville, IL 60555 Ref: Issuance of Injection Permit WI0300148 Paw Creek BP Terminal Site Charlotte, Mecklenburg County, North Carolina. Dear Mr. Ziegler: APR -12011 Dee Freeman Secretary Protection In accordance with the application received on June 22, 2010 and subsequent information received November 12, 2010 and January 24 and February 15, 2011, we are forwarding permit number WI0300148.. This permit is to inject a magnesium sulfate (Epsom Salt) and Sodium Bromide solution to remedidte groundwater contaminated with petroleum products at the Paw Creek BP Terminal facility. This permit shall be effective from the date of issuance until February 28, 2013, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS. Please note that some of the monitoring requirements have changed from your application. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at (919)715-6168 or at john.mccray@ncdenr.gov if you have any questions about your permit. cc: ooresVilre7Region.47Officcil Margaret Ness, Project Manager, URS Corporation — North Carolina Ed Leach, NCDENR DWQ Aquifer Protection Section WI0300148 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh. . North Carolina. 27604 Phone: 919-733-3221 1 FAX 1: 919-716-0588, FAX 2: 919-715601 ustc er Se 43 i C , m- �.,t vim: 1-377-623-6748 Internet: www.ncwaterouaiity.orc Best Regards, John R. McCray Environmental Specialist N orth Car .11Ea } .. `_ruual c.uor rini"'r`," +.1t:rm NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO BP Products North America. Inc. FOR THE CONSTRUCTION AND OPERATION OF 20 TYPE 5I INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject a magnesium sulfate and sodium. bromide solution, for the enhancement of anaerobic bioremediation of petroleum products. These injection wells/points will be located at 7401.O1d Mount holly Rd, Charlotte, Mecklenburg County, North Carolina, and will be operated in accordance with the application submitted June 22, 20 1.0, and in conformity with the specifications and supporting data submitted November 12, 2010 and January 24 and February 1.5, 2011, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be incompliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until February 28. 2013, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the 28th day of March, 2011. Coleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission. Permit No. WI0 3OC ..t PAGE 1 OF 7 ver. Oct 2010 _ AP/UIC-6 PART I - WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. This permit is valid only for construction of the number of injection wells described in the application and other supporting data. Construction of additional injection wells must be approved in advance by the Aquifer Protection Section. 4. Each injection well shall not hydraulically connect separate aquifers. 5. Each injection well shall be constructed in such a manner that water from land surface cannot migrate into the subsurface. 6. Utilized direct push equipment shall be afforded reasonable security against misuse and vandalism during injection activities. 7. Each injection point shall be located and recorded so that its general location can be reasonably identified. 8. Within 30 days of completion of well construction, a completed Well Construction Record (Form GW-1) must be submitted for each injection well to; Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART II - WELL CONSTRUCTION SPECIAL CONDITIONS At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office staff, telephone number (919) 715-6168 and the Mooresville Regional Office Aquifer Protection Section Staff, telephone number (704) 663-1699. Permit No. WI0 00 } = ,> PAGE 2 OF 7 ver. Oct.2010 AP/UIC-6 PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate ofinjection, and number of injection wells as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes, rules, regulations,' or ordinances which may be imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV - PERFORMANCE STANDARDS . 1. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. .2. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V - OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all tunes. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central Office staff, telephone number (919) 715-6168. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. Permit No. WI0 3OO 148 PAGE 3 OF 7 ver. Oct.2010 AP/UIC-6 PART VI - INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Depaitment representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injectionand any related facilities as provided for in N.C.G.S. 87- 90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS 1. In addition to the proposed monitoring schedule identified in the permit application, the applicant shall add two quarterly sampling events to be held at six and nine months after the injection event. These events will be sampled in accordance with the parameters laid out by the applicant for the original sampling plan. 2. The monitoring plan as modified by the Aquifer Protection Section shall be followed. All sample results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office and the Raleigh Central Office. An monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to ensure surface and ground water protection, will be established and an acceptable. sampling reporting schedule shall be followed. 3. The Permittee shall submit an Injection Event Record within 30 days of completing each injection. 4. The Permittee shall produce a final project evaluation within 9 months after completing all injection -related activity associated with this permit or produce a project interim evaluation before submitting a renewal application for this permit. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plume maps and potentiometric surface maps. 5. The monitoring results and the final project evaluation shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 Permit No. WI0%0I <- PAGE 4 OF 7 ver. Oct2010 AP/UIC-6 and to: Aquifer Protection Section DENR-DWQ Mooresville Regional Office 610 East Center Ave. Suite 301 Mooresville, NC 28115 6. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Mooresville Regional Office, telephone number (704) 66 I 699, any of the following: (A) Any occurrence at the inj ection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 7. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 8. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may berequired by the Director. PART VIII - PERMIT RENEWAL In order to continue -uninterrupted legal use of the injection facility for the stated purpose, the Permittee must submit an application to renew the permit 120 days prior to its expiration date. PART IX - CHANGE OF WELL STATUS 1. The Pennittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Pennittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0214, Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C .0214, including but not limited to the following: (A) All casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. Permit No. W10300148 PAGE 5 OF 7 ver. Oct.2010 AP/UIC-6 (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout or bentonite grout, which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In _ the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a mariner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment. 3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRl✓+ CAUTIONS DURING APPLICATION . Some effects reported. to be associated with exposure of proposed in]ectan.ts are as follows: (A) Technical grade Epsom salt: eye, nose, and throat irritation; early flushing, nausea, vomiting.. hypotension, ECG changes, CNS depression, respiratory depression, impairment of neuromuscular transmission, and gastrointestinal hemorrhaging. (B) Sodium Bromide: drowsiness, irritability, dizziness, skin rashes, decreased blood pressure, increased heart rate, difficulty breathing, nausea, vomiting, and eye irritation. In addition, sodium bromide may also cross the placenta and may be detected in milk of nursing mothers. Case reports suggest that prenatal exposure may cause growth retardation, craniofacial abnormalities, and developmental delay. 'Workers should use proper personal protective equipment if the products are released into the environment in a v,av that could result in a suspension of fine solid or liquid particles (e.g. grin diilg bi ending, UOruiis Shaking or rnixi?'g). T1R. application process Should berei'iewed o' an iil%t.?I stri al hygienist nisi to ensure drat the most appropriate personal protective equipment is used. Permit No. WI03001 PAGE 6 OF 7 ver. Oct20] 0 AP/UIC-6 Persons working with these products should wear goggles or a face shield., gloves. and protective clothing. Face and body protection should be used for anticipated splashes or sprays. Eating, drinking, srnoki,n_ handling contact lenses, and applying cosmetics should not be permitted in the application area. during or immediately following application. 4. Safer\ controls should be in place to ensure that the check valve and the pressure delivery systems ar;., workin<.:, properly S. The Material Saler;j Data Sheets should b:; to prevent incompatible or adverse reactions iorn and inIurf s. Permit No. WI03001 _ PAGE 7 OF 7 ver. Oct.201 0 AP/UIC-6 AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: July 2, 2010 To: ❑ Landon Davidson, ARO-APS ❑ Art Barnhardt, FRO-APS ® Andrew Pitner, MRO-APS ❑ Jay Zimmerman, RRO-APS From: John McCray , Groundwater Protection Unit Telephone: (919) 715-6168 E-Mail: john.mccray(a ncmail.net A. Permit Number: WI0300148 B. Owner: BP Products North America, Inc. C. Facility/Operation: Paw Creek — BP Terminal ❑ Proposed ® Existing J ❑ David May, WaR0- l,T.711 t.: ❑ Charlie Stehman, Wil O7APS -` _ t _ ❑ Sherri Knight, WSRO-APS r - \. Fax: (919) 715-0588 ❑ Facility ❑ Operation D. Application: 1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle 111 I/E Lagoon ❑ GW Remediation (ND) ® UIC - (51) in -situ groundwater remediation For Residuals: ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: ® New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal ❑ Renewal w/ Mod. E. Comments/Other Information: ❑ I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: ® Return a Completed Form APSSRR. ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO*. * Remember that you will be responsible for coordinating site visits, reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 02/06 Page 1 of 1 NCDENR North Carolina Department of Environment and Natural Resources Beverly Eaves Perdue Governor Scott Zeigler - RM Ops Project Mgr BP Products North America, Inc 28100 Torch Parkway MC 2 South Warrenville, IL 60555 Division of Water Quality Coleen H. Sullins Director June 22, 2010 Subject: Acknowledgement of Application No. WI0300148 Paw Creek - BP Terminal Injection In situ Grounwater Remediation Well (5I) Mecklenburg Dear Mr. Ziegler: JUL - 7 201() DWG fo 1.. ec,.._.d Dee Freeman Secretary The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on June 22, 2010. This application package has been assigned the number listed above and will be reviewed by John McCray. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact John McCray at 919-715-6168, or via e-mail at john.mccray@ncdenr.gov. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart,. go to http://h2o.enr.state.nc.us/documents/dwq orgchart.pdf. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sincerely, for Debra J. Watts Supervisor cco esvill'e:Regional Office,_Aquifer Protection.Sectiori Margaret Ness (URS Corporation NC - 1600 Perimeter Park Drive, Suite 400, Morrisville, NC 27560) Permit Application File WI0300148 AQUIFER PROTECTION SECTION 1636 Mall Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh. North Carolina 27604 Phone: 919-733-3221 1 FAX 1: 919-715-0588; FAX 2: 919-715-60481 Customer Service: 1-877-623-6748 Internet: www.ncwateraualitv.orq An Equal Opportunity \ Affirmative Action Employer One N rtii Carolina • 2dtu mil State of North Carolina Department of Environment and Natural Resources Division of Water Quality RECEIVED !DENRI A r Prot ection a APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WE RI, 1414K ibWON Type 5I Wells - In Situ Groundwater Remediation / Type 5T Wells - Tr n'eeliona- -@-.� 2010 • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated !groundwater • Submit TWO copies of the completed application and all attachments to the address on the last page of this forr} il'`rli • Any changes made to this form will result in the application package being returned. Application Number (to be completed by DWQ): I. GENERAL INFORMATION: 1. Applicant's Name (generally the responsible party): BP Products North America Inc. 2. Signing Official's Name*: Scott Ziegler Title: RM O.erations 'ro'ect Manager* Signing Official must be in accordance with instructions in part VI on page 7. 3. Mailing address of applicant: 28100 Torch Parkway, MC 2 South > ti 7 r ,r (Prj City: Warrenville State: IL Zip: 60555 Telephone number: 630-836-5663 Fax number: 630-836-6336 4. Property Owner's Name (if different from Applicant): 5. Property Owner's mailing address: City: State: Zip: 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Margaret Ness Company: URS Corporation — North Carolina Address: 1600 Perimeter Park Drive, Suite 400 Title: Project Manager City: Morrisville State: NC Zip: 27560 Telephone number: 919-461-1423 Fax number: 919-461-1415 Email Address: Margaret Ness@urscorp.com II. PERMIT INFORMATION: 1. Project is: 2. ( New ( Modification of existing permit ( Renewal of existing permit without modification ( Renewal of existing permit with modification If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number and the issuance date For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). For all renewals, submit a status report including monitoring results of all injection activities to date. Revised 6/09 UIC-5I/5T Page 1 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION 1. Facility name: Paw Creek — BP Terminal 2. Complete physical address of the facility: 7401 Old Mount Holly Road City: Charlotte B. INCIDENT DESCRIPTION County: Mecklenburg State: NC Zip: 28214 1. Describe the source of the contamination: See Appendix 1 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Gasoline, diesel, mixed products (or unknowns), used oil, virgin oil, heating oil (see Attachment A for source) 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ( IYes If yes, list maximum measured separate phase thickness 3.44 feet (ES06 in 1996) ( No If no, list maximum concentration of total VOCs observed at site: ppb 4. Agency managing the contamination incident: ( UST Section ( DWQ Aquifer Protection Section ( Hazardous Waste Section ( Superfund Section (including REC Program and DSCA sites) ( Solid Waste Section ( Other: 5. Incident managers name Ed Leach and phone number 704-235-2171 6. Incident number or other site number assigned by the agency managing the contamination incident: NC DENR Groundwater Incident Numbers 6771,15159, 15618, 17002, 17263, 17264, and 20622 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: 2. DWQ Non -Discharge or NPDES permits: 3. County or DEH subsurface wastewater disposal permits: 4. Other environmental permits required by state or federal law: Mecklenburg County Monitoring Well Permit Revised 6/09 UIC-5I/5T Page 2 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA 1. List all proposed injectants. NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the Occupational and Environmental Epidemiology Section (OEES) of the Division of Public Health, Department of Health and Human Services. Review the list of approved injectants or contact the UIC Program to determine if the injectants you are proposing have been reviewed by OEES. Injectant: Area 1 — Sulfate Solution consisting of Magnesium Sulfate (i.e Epsom Salt) Concentration at point of injection: 2,000 mg/L or PPM Percent if in a mixture with other injectants: 0.2% Injectant: Area 2 — Sulfate Solution consisting of Magnesium Sulfate (i.e Epsom Salt) Concentration at point of injection: 2,000 mg/L or PPM Percent if in a mixture with other injectants: Injectant: Area 1 — Bromide mixed in with Epsom Salts as Tracer Concentration at point of injection: up to 1,000 mg/L Percent if in a mixture with other injectants: 0.1% Injectant: Area 2 — Bromide mixed in with Epsom Salts as Tracer Concentration at point of injection: up to 1,000 mg/L Percent if in a mixture with other injectants: 0.1% 2. Source of fluids used to dilute or chase the injectants listed above: ( None ( Municipal water supply ( Groundwater from private well or any well within 'A mile of injection site ( Air ( Other: 3. If any well within VI mile of injection site, a private well, or surface water is to be used as the fluid source, supply the following information: a. Location/ID number of source: b. Depth of source: c. Formation: NA NA NA d. Rock/Sediment type: NA e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit application form. You must apply for a closed -loop groundwater remediation permit using application form GWRS. Revised 6/09 UIC-5I/5T Page 3 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WEIMEgfitt j&EN§Tft Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells-JeripjiifilBection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Approximately 5 days per area a. Maximum number of separate injection events: 20 b. Expected duration of each injection event 4-8 hours c. Expected duration between events (if more than one event): 2 hours 2. Injection rate per well: 5-36 gallons per minute (gpm) 3. Total Injection volume: 4,000 gallons per day (gpd); 2,000 gallons per event (if separate events) 4. Injection pressure: 50-300 pounds/square inch (psi) 5. . Temperature at point of injection: 65 °F Briefly describe how the above parameters will be measured and controlled: The application apparatus will include a diaphram injection pump with controller able to moderate flow down below 5 gpm. The infection manifold will also include a pressure gauge to monitor injection pressure. It is possible that multiple points will be injected at any one time. 6. Estimated hydraulic capacity of the well: 10 • gpm JUN 2 2 2010 C. INJECTION WELL CONSTRUCTION DATA 1 Injection will be via: ( Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. (X)Prepesed well() Soil Borings (i.e. direct push) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: AST Environmental or MAD DAWG (currently going though vetting) NC Well Contractor Certification number: .3395-A or 2555-A 3. Date to be constructed: August 2010 Number of borings: 10 per area (20 total) Approximate depth of each boring (feet): 20 to 40 feet 4. Screened interval/Injection interval of injection wells: NA Depth: 10 to 40 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: ( PVC ( Stainless steel( Other: NA Casing depth: to ft. 6. Grout (N/A if injection is through direct push rods): Type: ( Cement ( Bentonite ( Other: NA Grout depth: to ft. Revised 6/09 UIC-5I/5T Page 4 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Approximately 5 days per area a. M imum number of separate injection events: 15 - 24 b. Expec d duration of each injection event 4-8 hours c. Expected • ration between events (if more than one event): 2 hoofs 2. Injection rate per 11: 5-36 gallons per minute (gpm) 3. Total Injection volum. 400 — 4,000 gallons per day (gpd); 4. Injection pressure: -300 pounds/square inch (psi) 5. Temperature at point of injec on: 65 °F Briefly describe how the above . ameters will be measured and .ntrolled: The application apparatus will include a diaphram injection pump 'th controller able to mode ate flow down below 5 gpm. The injection manifold will also include a pressure ga •e to monitor injection pressure. It is possible that multiple points will be injected at any one time. 6. Estimated hydraulic capacity of the well: 10 gpm 1 C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: i -i ( Existing well(s) proposed for use as an injec on well. Pr•kide the data in (2) through (6) below to the best of your knowledge. (X)PFep^ss) Soil Borings (i.e. direct .ush) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed co truction specifications. 2. Well Drilling Contractor's Name: • ST Environmental or MAD D : WG (currently going though vetting) NC Well Contractor Certification numer: 3395-A or 2555-A 3. Date to be constructed: Au st 2010 Number of borings: 7 to 12 .er area u. to 24 Approximate depth of each boring feet): 20 to 40 feet 4. Screened interval/Injection inter al of injection wells: NA Depth: to feet b-.'ow ground surface (if multiple intervals, indicate shallows st and deepest depth). 5. Well casing (N/A if injectio a is through direct push rods): Type: ( PVC ( tainless steel( Other: NA Casing depth: to ft. 6. Grout (N/A if injection is through direct push rods): Type: ( Cement ( Bentonite ( Other: NA Grout depth: to ft. Revised 6/09 UIC-51/5T Page 4 of 8 1 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection V. ATTACHMENTS Provide the following items as separate attachments with the given headings: A. SITE HISTORY Provide a brief description of the site history including: (1) site usage historically and present, (2) origin of the contamination, (3) previous remedial action(s). NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under their direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work prepared or approved by a licensed geologist, or a subordinate under their direction, be signed and sealed by the licensed geologist. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) (2) (3) (4) the regional geologic setting; significant changes in lithology; the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and the depth to the mean seasonal high water table. C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within 1/4 mile of the injection site is used as the source well, include chemical analysis of source fluid here. Magnesium sulfate solution (2,000 mg/L) is completely miscible in water. Magnesium sulfate completely disassociates in water and creates a sulfate salt solution. The solution is non -toxic (see MSDS) and stable in the environment. Additional information is provided in Attachment C. D. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) (2) (3) (4) goals of the injection project; explanation and/or calculations of how the proposed injectant volume and concentration were determined; a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: construction plans and materials; operation procedures; a detailed diagram of the surface and subsurface portions of the system; and a planned injection schedule. Revised 6/09 UIC-5I/5T Page 5 of 8 ' n APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection Below is a brief description of the injection procedure and equipment. Additional information can be found in Attachment D. 1. It is anticipated that a direct push technology (DPT) will be used as a delivery platform. The probe injection pint will be advanced to the specified depth then the injection point will be uncovered. An injection manifold inclusive of quick connect couplings, a ball valve, and a pressure gauge will be attached to the top of the DPT rods. Concurrent with the DPT advancement an Epsom salt solution will be mixed with municipal water to a sulfate concentration of 2,000 mg/L. Concentrations will be based on calculations and the first batch will be checked by laboratory analysis; 2. This is a temporary mobile system that is vendor supplied. General components consist of a mixing tank, product pump, metering and measuring system and affiliated conveyance hose. 3. It is anticipated that the injections will take place in late August 2010. The injection points will be installed using a Direct Push Technology drilling rig. It is anticipated that several points will be installed at the same time and then injected solution delivered to several point at the same time. It is anticipated that no more than a 4-5 foot section will be injected at a time then the DPT will be advanced to the next 4-5 foot interval until the entire 20- foot depth is complete. Revised 6/09 UIC-5I/5T Page 6 of 8 F. MONITORING PLAN Provide a plan for monitoring the results of the injection, including: APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection r (1) a list of existing and proposed monitoring wells to be used; (2) a list of monitoring parameters and analytical methods to be used; and (3) A schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by- products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target contaminants as well as secondary or intermediate contaminants which may result from the injection and other parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated reactions and rate of transport of the injectants and contaminants. -) G. WELL DATA Provide a tabulation of data on all existing or abandoned wells within 'A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open borehole depth interval, and well construction or abandonment record, if available. �l y a: H. MAPS Attach the following scaled, site -specific maps: (1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site. (2) Site map including: a. all property boundaries; b. all buildings within the property boundary; c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within 'A mile of the injection well or well system; e. all surface water bodies within 'A mile of the injection well or well system; and f. all existing or abandoned wells within 'A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. (3) Potentiometric surface map(s) including: a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant plume, including isoconcentration lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross-section(s) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology c. existing and proposed monitoring wells d. existing and proposed injection wells Revised 6/09 UIC-5U5T Page 7 of 8 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — fit Situ Groundwater Remediation / Type 5T Wells — Tracer Injection VI. CERTIFICATION (to be signed as required below or by that person's authorized agent) NCAC 15A 2C .0211(b) requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Printed Name and Title: Scott Ziegler, RM Operations Project Manager On behalf of BP Products North America Inc. & BP Pipelines (North America) Inc. Signature: Date: 5 /ZS(20/v VII. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) RECEIVED / DENR / Q ("Owner" means any person who holds the fee or other proper �j lsr or �ng constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing.) LUN 22 2010 As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined ' -a , 's application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200). Printed Name and Title: RE _ EIVED / DENR / Aquifer Signature: Date: Submit TWO copies of the completed application package, including all attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 Revised 6/09 UIC-51/5T Page 8 of Et APPENDIX 1 Historical Site Release Incidents The following is a summary of Site release incidents as documented in historical Site documents. Reference numbers correspond to the locations shown in Figure 3. Summary of Site Release Incidents Reference No. Approximate Date Substance Released Amount of Release NC DENR Incident No. Description 1 Circa 1950 diesel fuel unknown -- tank overfill 2 Circa 1978 unknown unknown -- pipeline leak (1) 3 1979 kerosene 70,000 gallons (2) -- release from tank 4 1985 diesel, gasoline & kerosene unknown -- pipeline leak (3) 5 1985 & 1989 mixed products unknown -- pipeline leak 6 1991 unknown unknown __ product seeps in dike walls 7 1991 unknown unknown -- groundwater contamination discovered 8 1992 diesel unknown -- release from tank 119 9 1992 diesel unknown -- release from tank 119 10 circa 1994 unknown unknown -- pipeline leak (4) 11 1996 used oil unknown 17263/ 17624 1,000 gallon UST removal 12 1996 virgin oil unknown 550 gallon UST removal 13 1996 diesel unknown 8,000 gallon UST removal 14 Feb. 26, 1996 diesel unknown 15159 release from tank 111 15 May 1, 1996 diesel unknown 15618 product seeps in dike wall near tank 112 16a October 1992 unknown unknown 6771 groundwater contamination discovered 16b Jan. 2, 1999 unleaded gasoline 77,784 gallons (5) 17002/ 20622 release from tank 118 17 June 2002 unknown product unknown -- pipeline leak (6) 18 Dec. 17, 2003 heating oil 300 gallons __ release from tanker truck (7) (1) Product seep from abandoned Fina pipeline discovered in dike wall (2) 68,866 gallons were recovered (3) Lines owned and operated by Publix Oil (National Oil terminal) (4) Lines owned and operated by Phibro Company (5) 51,660 gallons were recovered (6) Lines owned and operated by Plantation Pipe Line Company (responsible party) (7) Tanker truck owned and operated by Curtis Oil Company (responsible party) -- No incident number issued i f , i,-;- ----_,) / I j\ . r. r i', r ' A , \ 7' /I 1 1 \ 1 I Y ' f 1 ,f,--i---Jf •,, • , I \ i \ f 1 ' I I F,,,-,irrIli'..fri 1 i I LAA'67 11 l' !I II i N i ;:-, ,:;- .,-.L , 1, ; 1 i , II 11,' ii i r -„--,----- ETI:.!:11 i 1I i ,i i III1 Ii 111 i 1 ' !Ib I 1Iir1 I1 •i '-i.I 1i !, ,'-f1:-,,._-:;.• !/C1,,Vl-,4-,t:,:C''—.1.I'T:n'tI'.:'0Ci'l1,,.-'V/,7-'E'cR-y2'j-,C„'lE.,.-...3r., " d24•'\,,A,I,rtiI';18'%r 1' ,,. L+1I ---- : -- l ? T2 1U, V; ) !..! \i \I' A/ 7/ // . 1c/,\ I , — , ' ; •:i-''-,-,.-'--:'41-i11;L,;- , / ) ( t„—) / - II1Tti. --• . i 1 V NIVil.TE I, li: I J ---f5!-.=--- -1--E„\C2 5 !i' Fornler NationalO Trrrn Proioetly • "". pmn., v,14,5 PII,F;1 I I F1.iIN 2 p 2 .3 ScciCAP 0 50 150 Legend Groundwater Monitoring Well Sump Location of Release Incident (See Narrative Far Description) F.F.41 F AS SHOWN DESIGNED BY DATE CONF1DENTAL-ALL RIGHTS RESERVED -PROPERTY OF URS MU. NORTH CAROLINA Z7E60 DRAWN BY TSH DATE 02JUL07 CHECKED EfY LV DATE 02JUL07 Figure 3. Locations of Historical Terminal Releases laID Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 02JUL07 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-3 REV. 0 ATTACHMENT A - SITE HISTORY 1) Site Usage The Site is located in the Paw Creek area of Charlotte, North Carolina, an area predominantly occupied by petroleum terminal and light industrial facilities. The facility occupies approximately 26 acres and is bordered by Old Mount Holly Road to the north, a Kinder -Morgan terminal to the east, vacant property (former National Oil terminal) to the west, and undeveloped woods to the south. Railroad tracks operated by Piedmont and Northern Railroad are located directly south of the facility property, beyond which is situated a Duke Power transmission line right-of-way. The Site is a petroleum distribution terminal that has been in operation since the 1940s and was formerly owned jointly by BP and TransMontaigne. Since February 2006 the facility has been solely owned and operated by BP. The facility contains 19 bulk fuel storage tanks that are contained within earthen bermed areas and/or excavated areas with earthen cut -banks. In addition to the bulk fuel storage tanks, the facility contains a terminal office building, miscellaneous storage and warehouse buildings, nine process aboveground storage tanks (ASTs), three underground storage tanks (USTs), a covered tanker truck loading rack, associated process piping, and an inactive dual -phase vacuum extraction (DPVE) soil/groundwater remediation system which was removed. The tanker truck loading rack is located near the northern border of the facility, with access from Old Mount Holly Road. Six of the process ASTs, ranging in size from 180 gallons to 8,000 gallons, contain fuel additives. Two 10,000-gallon ASTs contain petroleum contact water. One 2,000-gallon AST contains mixed (slop) products. The USTs consist of one 1,000-gallon wastewater UST (located at the sump near tank 110), one 2,000-gallon used oil UST (located adjacent to two 10,000-gallon underground oil/water separators), and one 2,000-gallon vapor recovery unit (VRU) moisture separator UST. A total of seven USTs have been decommissioned at the terminal. The Site underwent a modification between September and December 2008 to include ethanol fuel storage, and an expanded truck loading rack and driveway widening to accommodate the expansion. Fuel lines were added beginning late 2009. The terminal is supplied with petroleum products from underground pipelines owned by Colonial Pipeline Co. and Plantation Pipe Line Co. Two 14-inch diameter feed lines from Colonial Pipeline enter the facility below ground from the northwest corner. One 10-inch and one 12-inch feed line from Plantation Pipe Line enter the facility from the southwest corner. Two abandoned 14-inch underground pipelines enter the facility west side near the warehouse from the former National Oil terminal. These pipelines formerly supplied product to the former National Oil terminal via the BP terminal product manifold. 2) Origin of the contamination Eighteen releases of known and unknown quantities of material have been released at the site since circa 1950. Refer to Appendix 1 for release information and locations. 3) Previous Remedial Action(s) The following is a summary of Site environmental remediation activities conducted in response to various historical facility product releases. Remedial activities are shown in Figure 4. Soil Remediation • September 1991: unknown volume of soil excavated from the area north of tank 111. • September 1996: approximately 133 tons of soil excavated from former UST locations. • October 1996: approximately 7 tons of soil excavated from the area west of tank 111. • March 1997: approximately 24 tons of soil excavated from the area near tanks 117 and 118. • April 1998: unknown volume of soil excavated from the area north of tank 112 during installation of interceptor trench. • May 1998: approximately 312 tons of soil excavated from around tanks 111, 116, 117, 118, and 119. • January 1999: approximately 420 tons of soil excavated from area surrounding tanks 117 and 118. • April 2004: approximately 13 tons of soil excavated from ditches near tanks 117 and 118. • January 2005: approximately 120 tons of soil excavated from ditches near tanks 117 and 118. Groundwater Remediation • Pump and treat: approximately 4,882,088 gallons of groundwater processed between 1985 and 1994. • DPVE: approximately 472,135 gallons of groundwater processed between 1994 and July 2000. • Interceptor trench: approximately 217,867 gallons of groundwater processed between 1998 and 2005. • A Groundwater Permeable Reactive Barrier (PRB) was installed in February 2005. The PRB is filled with granular gypsum and organic topsoil and is designed to mitigate groundwater contaminant of concern (COC) concentrations, and prevent further downgradient migration of the groundwater COC plume through enhanced anaerobic biodegradation. • An In -Situ Submerged Oxygen Curtain (ISOCTM) was installed from October 31 to November 3, 2005 in the northwestern area of the terminal and is currently operating. LNAPL Recovery • Pump and treat: approximately 6,000 gallons of LNAPL recovered between 1993 and 1994. • DPVE: approximately 500 gallons of LNAPL recovered between 1994 and July 2000. • On -going LNAPL recovery using absorbent socks if present. Measureable LNAPL last recorded 2005. ES19 • ui'i10• icoVERED ES0 1 ^'xilAlPaw.a.. ES1J �" O I®29Es 07 \ , ES180 VPO WIMPLE UW07 E942 • l00000001 Mwo8 0 MWO7 PMWOO PMWO1 PMWO2 ° DW08 • DWO9 • PWO3 • 00001 c MW3W DWO3 SUMP 8 e PMWO7 ® SUMP C W14R a ES2 PMW10 • PMWO5 PMWO4 • •PMW11 PMW12 • v t 000 0 50 150ft Legend Area Of Dual —Phase Vacuum Extraction System (DPVES) Influence (From CRA, 2004) Approximate Location 0f Soil Excavation Area, 09/06/91 — AT&E. 04/92 Approximote Location Of Soil Excavation Areas, 09/30/96 And 10/01/96 — S&ME, 10/97 Approximate Location Of Soil Excavation Area, 03/04/97 — CBM 04/97 Approximate Location Of Soil Excavation Area, 04/01/98 — G&E Engineering, 02/98 Approximate Location Of Soil Excavation Areas, 05/13/98 EHS Field Notes, 05/98 Approximate Location 0f Soil Excavation Areas, 10/18/96 — CBM, 11/96 Approximate Location Of Soil Excavation Areas, 01/07/00 CRA, 05/99 Approximate Location Of Soil Excavation Areas 01/09/04 and 01/18/05 — Shield, 02/05 Approximate Location Of Permeable Reactive Barrier Installed 02/05 — Piedmont Geologic 05/05 Area of ISOC Influence — Piedmont Geologic 01/06 SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL —ALL RIGHTS RESERVED —PROPERTY OF URS RIXI, NORTH CAROLINA 27550 DRAWN BY TSH DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 4. Historical Remediation Activities BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 02JUL07 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-4 REV. 0 ATTACHMENT B - HYDROGEOLOGIC DESCRIPTION 1) Regional Geologic Setting The facility is situated on the crest and slope of a hill centered on Old Mount Holly Road. Ground -surface elevations at the facility range from approximately 795 feet relative to mean sea level (msl) at the northern border of the facility adjacent to Old Mount Holly Road to approximately 740 feet msl at the southern border of the facility. South of Old Mount Holly Road, surface drainage is south toward Paw Creek. North of Old Mount Holly Road, surface drainage is north toward Long Creek. The Site is located in the Piedmont physiographic province, which is characterized by moderately level interstream areas separated by broad valleys. Bedrock in Charlotte, North Carolina is mapped within the Charlotte Belt lithologic division of the Piedmont, which includes mafic gneisses, amphibolites, metagabbros, and metavolcanic rocks. According to the Geologic Map of North Carolina (North Carolina Geological Survey, 1985), bedrock beneath the facility consists of metamorphosed quartz diorite or quartzite. Competent bedrock in the Piedmont province is typically overlain by variable thicknesses of saprolite and soil, collectively referred to as "overburden." Saprolite consists of rock that has been subject to chemical weathering, removing up to 60% of the rock mass by solution, but not affecting volume (Cleaves, 1974). Saprolite commonly retains relict structures from the parent bedrock. Thicknesses of the overburden in the Piedmont typically range from 10 to 75 feet, depending on rock composition and topographic setting (LeGrand, 1988). 2) Significant Changes in Lithology Based on Site boring logs, subsurface materials at the Site consist of soil and saprolite overburden, including silty/clayey sand, sandy clay/silt, and silt/clay, overlying weathered and competent bedrock. Bedrock, meeting the description of metamorphosed quartz diorite referenced above, has been encountered in Site borings at depths ranging from approximately 10 to 40 feet below grade and elevations ranging from approximately 729 to 774 feet msl. Groundwater in the Piedmont province occurs in the overburden under unconfined (i.e., water table) conditions, and in the underlying bedrock under both unconfined and confined conditions. Groundwater in the overburden occurs within pore spaces of the unconsolidated medium, including relict bedrock structures (i.e., fractures, foliations, etc.). Due to the typical fine-grained nature and low permeability of saprolite, the formation is not usually utilized for groundwater production. Groundwater in the underlying bedrock occurs along zones of secondary porosity, such as fractures, foliations, solution voids, etc. Most water -supply wells in the Piedmont are completed in bedrock with surface casings extending through the overburden. 3) Hydraulic Conductivity, etc. The following is from Piedmont Geologic (August 19, 2005) for the submittal of ISOC usage under UIC permit WI0300106: The following is a summary of results of historical hydraulic conductivity (K) tests completed in various monitoring wells located in different topographical areas of the Terminal: HYDRAULIC CONDUCTIVITY TEST RESULTS Well No. Total Depth (feet below grade) Screen Interval (feet below grade) Hydraulic Conductivity (feet per day) MWO2 24.0 Unknown 0.48 MWO4 18.0 3.6-18.0 0.16 ES27 11.7 1.7-11.7 0.8 ES32 12.5 2.5-12.5 4.7 ES35 17.5 2.5-17.5 45.8 ES37 15.0 5.0-15.0 5.1 DWO2 28.3 23.3-28.3 7.2 DWO6 49.0 44.0-49.0 12 DWO7 33.0 28.0-33.0 1.3 DW08 40.0 35.0-40.0 4.2 DPEW01 10.5 2.7-10.2 0.06 MW14R 15.0 2.4-14.9 0.06 Based upon (1) the most recent hydraulic conductivity test results (i.e., from MW14R) with a hydraulic conductivity of 0.06 feet per day (ft/d), (2) the maximum historical observed groundwater gradient across the Terminal of 0.11 foot vertical per foot horizontal (ft/ft), and (3) an estimated effective porosity of 10 percent, the calculated porosity -corrected groundwater flow velocity is 0.066 ft/d or approximately 24 feet per year (G&E, March 13, 1998). Transmissivity (T) and specific yield have not been determined for this site as pumping tests have not been conducted. (4) Depth to Mean Seasonal High Water Table Based on recent and historical depth to groundwater measurements, the depth to groundwater across the site varies seasonally from around 3 feet bgs to over 13 feet bgs, with the shallower depths occurring during the dry summer months. Depth to groundwater measurements in Sulfate Injection Area 1 (near monitoring well MW-26) varied from 6 feet in June 2009 to about 6.3 feet in December 2009. Depth to groundwater in Sulfate Injection — Area 2 (near monitoring well (UW-08) varied from 4.6 feet in June 2009 to 4.77 feet in December 2009. The estimated depth to the mean seasonal high water table is on the order of 7.5 feet bgs at this site. M) 12610 ATTACHMENT C - INJECTION FLUID COMPOSITION The proposed injectant is a magnesium sulfate solution. Magnesium sulfate solution (2,000 mg/L) is completely miscible in water. Magnesium sulfate completely disassociates in water and creates a sulfate salt solution. The solution is non -toxic (see MSDS) and is stable in the environment. The use of magnesium sulfate has been previously approved for injection by the NCDENR UIC program. Additional details regarding the injection mixture are provided in Attachment D (2). A sodium bromide solution (up to 1,000 mg/L) will be added to the magnesium sulfate solution as a tracer. The MSDS is attached. The use of bromide has been previously approved for injection by the NCDENR UIC program. Attachments: Magnesium sulfate MSDS Sodium Bromide MSDS *PQCorporation MSDS MATERIAL SAFETY DATA SHEET Trade Name.: Epsom Salt, Magnesium Sulfate, U.S.P. Date Prepared: 07/24/06 Page.• 1 of 4 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: Epsom Salt, Magnesium Sulfate, U.S.P. Product description: Magnesium sulfate, heptahydrate Manufacturer: PQ Corporation P. O. Box 840 Valley Forge, PA 19482 USA Telephone: 610-651-4200 In case of emergency call: 610-651-4200 For transportation emergency Call CHEMTREC: 800-424-9300 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical and Common Name CAS Registry Wt. % OSHA PEL ACGIH TLV Number Magnesium sulfate, heptahydrate; 10034-99-8* 100% Not Established Not Established Epsom salt * Under the Toxic Substances Control Act (TSCA), hydrates are considered as mixtures of their anhydrous salt and water. Accordingly, the CAS Numbers 7487-88-9, 7732-18-5 are used for purposes of TSCA. 3. HAZARDS IDENTIFICATION Emergency Overview: White or transparent crystalline odorless powder. Noncombustible. At very high temperatures, magnesium oxide, sulfur dioxide, and sulfur trioxide may be generated. Causes mild eye irritation. Eye contact: Causes mild irritation to the eyes. Skin contact.• No known adverse effects. Inhalation: Causes nausea, vomiting, abdominal cramps, and diarrhea. Ingestion: Causes nausea, vomiting, abdominal cramps, and diarrhea. Chronic hazards: No known chronic hazards. Not listed by NTP, IARC or OSHA as a carcinogen. Physical hazards: Spilled material can be slippery. 4. FIRST AID MEASURES Eye: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Skin: Not applicable. Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. r Trade Name: Epsom Salt, Magnesium Sulfate, U.S.P. Date Prepared: 07/24/06 Page: 2 of 4 Ingestion: If large quantities of this material are swallowed, call a physician immediately. Do NOT induce vomiting unless directed to do so by a physician. Never give anything by mouth to an unconscious person. 5. FIRE FIGHTING MEASURES Flammable limits: Extinguishing Media: Hazards to fire-fighters: _1 Fire -fighting equipment: �J This material is noncombustible. This material is compatible with all extinguishing media. See Section 3 for information on hazards when this material is present in the area of a fire. The following protective equipment for fire fighters is recommended when this material is present in the area of a fire: chemical goggles, body -covering protective clothing, self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal protection: Environmental Hazards: Small spill cleanup: Large spill cleanup: CERCLA RQ.• Wear chemical goggles, See section 8. Sinks and mixes with water. No adverse effects known. Not a listed toxic chemical under SARA Title III, §313 40 CFR Part 372. Not a CERCLA Hazardous Substance under 40 CFR Part 302. Sweep, scoop or vacuum discharged material. Flush residue with water. Observe environmental regulations. Keep unnecessary people away; isolate hazard area and deny entry. Do not touch or walk through spilled material. Sweep, scoop or vacuum discharged material. Flush residue with water. Observe environmental regulations. There is no CERCLA Reportable Quantity for this material. 7. HANDLING AND STORAGE Handling: Storage: Avoid breathing dust. Promptly clean up pills. Keep containers closed. Protect from extremes of temperature and humidity during storage. Recommended storage conditions 68-110° F and 54-87% relative humidity. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye protection: Use with adequate ventilation. Safety shower and eyewash fountain should be within direct access. Use a NIOSH-approved dust respirator where dust occurs. Observe OSHA regulations for respirator use (29 C.F.R. §1910.134) Wear gloves if abrasion or irritation occurs. Wear chemical goggles. L. _ Trade Name: Epsom Salt, Magnesium Sulfate, U.S.P. Date Prepared: 07/24/06 Page: 3 of 4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Crystalline odorless powder. Color: White or transparent. Odor: Odorless. pH: Approximately 6-7 Specific gravity: 1.76 g/cm3, Bulk Density Approximately 1.05 g/cm3 Solubility in water: 71g/100 ml at 20° C, 91g/100 ml at 40° C 10. STABILITY AND REACTIVITY Stability: This material is stable under all conditions of use and storage. Conditions to avoid: None. Materials to avoid: Metal hydrides and other water reactive materials. Hazardous decomposition products: At very high temperatures, magnesium oxide, sulfur dioxide, and sulfur trioxide may be generated. 11. TOXICOLOGICAL INFORMATION Acute Data: When tested for primary irritation potential, this material caused mild eye irritation. RTECS reports Oral TDLo= 428 mg/kg in man 351 mg/kg in women 12. ECOLOGICAL INFORMATION Eco toxicity: Data not available. Environmental Fate: This material is not persistent in aquatic systems and does not contribute to BOD. It does not bioconcentrate up the food chain. Physical/Chemical: Sinks and mixes with water. 13. DISPOSAL CONSIDERATIONS Classification: Disposal Method: Disposed material is not a hazardous waste. Landfill according to local, state, and federal regulations. Disposed material is not a RCRA Hazardous waste. 14. TRANSPORT INFORMATION DOT UN Status: This material is not regulated hazardous material for transportation. 15. REGULATORY INFORMATION CERCLA: No CERCLA Reportable Quantity has been established for this material. Trade Name: Epsom Salt, Magnesium Sulfate, U.S.P. Date Prepared: 07/24/06 Page: 4 of 4 SARA TITLE III.: Not an Extremely Hazardous Substance under §302. Not a Toxic Chemical under §313. Hazard Categories under §§311/312: Acute TSCA: All ingredients of this material are listed on the TSCA inventory. I ' FDA: Magnesium sulfate is an FDA GRAS substance pursuant to 21 CFR 184.1443. 16. OTHER INFORMATION Prepared by: John G. Blumberg Supersedes revision of 03/07/05 THE INFORMATION ON THIS SAFETY DATA SHEET IS BELIEVED TO BE ACCURATE AND IT IS THE BEST INFORMATION AVAILABLE TO PQ CORPORATION THIS DOCUMENT IS INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONS FOR HANDLING A CHEMICAL BY A PERSON TRAINED IN CHEMICAL HANDLING. PQ CORPORATION MAKES NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED WITH RESPECT TO SUCH INFORMATION OR THE PRODUCT TO WHICH IT RELATES, AND WE ASSUME NO LIABILITY RESULTING FROM THE USE OR HANDLING OF THE PRODUCT TO WIIICH THIS SAFETY DATA SHEET RELATES. USERS AND HANDLERS OF THIS PRODUCT SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION PROVIDED HEREIN FOR THEIR OWN PURPOSES. Science Chemicals & Laboratory Equipment Material Safety Data Sheet Sodium bromide MSDS Health 2 0 Fire ',° rt, Personal Protection Section 1: Chemical Product and Company Identification Product Name: Sodium bromide Catalog Codes: SLS3820, SLS1600 CAS#: 7647-15-6 RTECS: VZ3150000 TSCA: TSCA 8(b) inventory: Sodium bromide CI#: Not available. Synonym: Bromide salt of sodium Chemical Name: Sodium Bromide Chemical Formula: NaBr Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 Order Online: ScienceLab.com CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non -emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Sodium bromide 7647-15-6 100 Toxicological Data on Ingredients: Sodium bromide: ORAL (LD50): Acute: 3500 mg/kg [Rat]. 7000 mg/kg [Mouse]. Section 3:.HazardsIdentification Potential Acute Health Effects: Hazardous in case of eye contact (irritant), of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant). Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section 4: First Aid Measures Eye Contact: p. 1 Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. Skin Contact: Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Serious Skin Contact: Not available. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation: Not available. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Serious Ingestion: Not available. Section 5::Fire and Explosion Data Flammability of the Product: Non-flammable. Auto -Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Not applicable. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: Not applicable. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available. Section :6: Accidental Release Measures Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Large Spill: Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section :7 Handling and Storage ii I � L Precautions: Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids. Storage: Keep container tightly closed. Keep container in a cool, well -ventilated area. Do not store above 25°C (77°F). ection,8a,Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available. Section 9: Physical and Chemical Properties Physical state and appearance: Solid. Odor: Not available. Taste: Not available. Molecular Weight: 102.91 g/mole Color: Not available. pH (1% soln/water): 6.5-8.0 Boiling Point: 1390°C (2534°F) Melting Point: 755°C (1391°F) Critical Temperature: Not available. Specific Gravity: 3.21 (Water = 1) Vapor Pressure: Not applicable. Vapor Density: Not available. Volatility: Not available. Odor Threshold: Not available. Water/Oil Dist. Coeff.: Not available. tonicity (in Water): Not available. Dispersion Properties: See solubility in water, methanol. p. 3 Solubility: Easily soluble in cold water, hot water. Soluble in methanol. 1 g dissolves in 1.1 ml of water. 1 g dissolves in about 16 ml of alcohol. 1 g dissolves in 6 ml of methanol Section 10: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Incompatible materials, moisture Incompatibility with various substances: Reactive with oxidizing agents, acids. Corrosivity: Non -corrosive in presence of glass. Special Remarks on Reactivity: Absorbs moisture from the air but is not deliquescent. Hygroscopic. Also incompatible with alkaloidal and heavy metal salts, and Bromine Trifluoride. Special Remarks on Corrosivity: Not available. Polymerization: Will not occur. Section 11 Toxicological Information Routes of Entry: Inhalation. Ingestion. Toxicity to Animals: Acute oral toxicity (LD50): 3500 mg/kg [Rat]. Chronic Effects on Humans: Not available. Other Toxic Effects on Humans: Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant). Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects (male and female effects on fertility and effects on newborns and fetotoxicity) based on animal data Human: passes the placental barrier, detected in maternal milk. Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: May cause mild skin irritation. Eyes: Causes eye irritation. Inhalation: May cause respiratory tract irritation. Ingestion: May cause gastrointestinal tract irritation with nausea and vomiting, abdominal pain, constipation. Bromide poisoning following acute ingestion is more rare and may affect the central nervous system (CNS depression - somnolence, confusion, ataxia, coma and other symptoms similar to chronic ingestion), cardiovascular system (hypotension, tachycardia), kidneys (acute renal failure, urinary incontinence), and respiration (acute respiratory distress syndrome). It may also cause eye disturbances such as mydriasis and nystagmus, disturbances of apparent color of objects, blurring or indistinctness of vision, apparent movement or wiggling and change in apparent size of objects, large pupils, subnormal reaction to light, diplopia, and photophobia. p. 4 Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause skin rashes. Eyes: Prolonged or repeated eye contact may cause blepharitis, and conjunctivitis. Prolonged or repeated ingestion may cause skin rashes (bromoderma, acne, pyoderma gangrenosum, erythema multiforme), affect the liver, endocrine system (thyroid), metabolism(anorexia), blood, vision (visual disturbances, permanently decreased vision and may produce a toxic syndrome, "Bromism" which may be characterized by behavior/central nervous symptoms such CNS depression, irritability, headache, confusion, slurred speech, memory Toss, lethargy, ataxia, tremor, agitation, delusion, disoriented, paranoia, aggressiveness, hallucinations, mania, fatigue, seizure, neuropathy, muscle weakness, coma. Also, in individuals with chronic bromism, the tongue may have a coated or furred appearance. Section.12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information DOT Classification: Not a DOT controlled material (United States). Identification: Not applicable. Special Provisions for Transport: Not applicable. Section 15: Other Regulatory Information Federal and State Regulations: TSCA 8(b) inventory: Sodium bromide Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications: WHMIS (Canada): Not controlled under WHMIS (Canada). DSCL (EEC): R36- Irritating to eyes. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label. HMIS (U.S.A.): p. 5 Health Hazard: 2 Fire Hazard: 0 Reactivity: 0 Personal Protection: E National Fire Protection Association (U.S.A.): Health: 2 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Section 16: Other Information References: Not available. Other Special Considerations: Not available. Created: 10/10/2005 08:26 PM Last Updated: 11/06/2008 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. p. 6 ATTACHMENT D — Injection Rational (1) Remedial Goals The goal of this project is to evaluate the efficacy of anaerobic bioremediation of petroleum based contaminants at the site. Much research has indicated that plumes that are depressed of oxygen are intrinsically capable of reducing BTEX contamination but are limited by the concentration of sulfate or other reducing compounds. (2) Contaminant / Injectant Reactions The concentration and volume of injectant have been calculated and estimated based on estimated pore volume within the soil matrix and previous site experience. The available pore volume is calculated at 12,000 gallons per area. Based on injection experience it is estimated that approximately 4,000 gallons of solution could be injected into each area. Based on this volume and the available pore space an injection concentration of 2,000 mg/1 is proposed. It is assumed that within days of injection the concentration will be diluted by 50% by mixing with the surrounding groundwater that would yield an effective concentration of 1,000 mg/L for anaerobic reduction. Based on a range of 1st order biological reduction rates (k) between 0.043/day and 0.130/day it is estimated that the ending concentration of sulfate at the end of the approximate 3-month pilot test will be below 250 ppm (secondary MCL). URS evaluated the potential fate of sulfate injected into the groundwater at the site. Calculations were made using dispersion as the only mechanism for reducing concentrations (i.e., assumed no retardation, precipitation, or uptake during contaminant degradation). A single injection of 4,000 gallons of water containing 2,000 mg/L dissolved sulfate was assumed. The calculation also assumed a minimum travel path to the property boundary and calculated travel time of 173 days along that path based on site conditions. Using very conservative estimates of dispersion, the maximum sulfate concentration projected at the property boundary was calculated to be less than 100 mg/L, which is well below the MCL of 250 mg/L. Details of the calculations are available upon request. Bromide solutions are well known in industry as a tracer due to the relative ease of detecting it in groundwater. The bromide will be added as a tracer in the Sulfate solution as an aid to further evaluate the flow regime and as a control for estimated biological uptake of sulfates. (3) Summary Results of Previous Modeling or Testing URS evaluated the potential fate of sulfate injected into the groundwater at the site. Calculations were made using dispersion as the only mechanism for reducing concentrations (i.e., assumed no retardation, precipitation, or uptake during contaminant degradation). A single injection of 4,000 gallons of water containing 2,000 mg/L dissolved sulfate was assumed. The calculation also assumed a minimum travel path to the property boundary and calculated travel time of 173 days along that path based on site conditions. Using very conservative estimates of dispersion, the maximum sulfate concentration at the property was calculated to be less than 100 mg/L, which is well below the MCL of 250 mg/L. Details of the calculations are available upon request. See the attached paper for additional information and case studies. The reactions utilize sulfate to reduce BTEX concentrations to CO2 and varying concentrations of sulfate reduction daughter products. Hydrogen sulfide can be produced but it is anticipated that most of the sulfate will be converted into sulfite. Attachments: Journal of Hydrology, 2001 ti v J ELSEVIER JOURNAL OF Contaminant Hydrology Journal of Contaminant Hydrology 51 (2001) 179-195 www.elsevier.com/locate/jconhyd In situ assessment of microbial sulfate reduction in a petroleum -contaminated aquifer using push—pull tests and stable sulfur isotope analyses M.H. Schroth a'*, J. Kleikemper a, C. Bolliger a, S.M. Bernasconi b, J. Zeyer a a Institute of Terrestrial Ecology -Soil Biology, Swiss Federal Institute of Technology Zurich (ETHZ), Grabenstrasse 3, CH-8952 Schlieren, Switzerland b Institute of Geology, Swiss Federal Institute of Technology Zurich (ETHZ), CH-8092 Zurich, Switzerland Received 18 October 2000; received in revised form 14 March 2001; accepted 3 Apri1 2001 Abstract Anaerobic microbial activities such as sulfate reduction are important for the degradation of petroleum hydrocarbons (PHC) in contaminated aquifers. The objective of this study was to evaluate the feasibility of single -well push-pull tests in combination with stable sulfur isotope analyses for the in situ quantification of microbial sulfate reduction. A series of push-pull tests was performed in an existing monitoring well of a PHC-contaminated aquifer in Studen (Switzer- land). Sulfate transport behavior was evaluated in a first test. In three subsequent tests, we injected anoxic test solutions (up to 1000 1), which contained 0.5 mM bromide (Br-) as conservative tracer and 1 mM sulfate (SO,a-) as reactant. After an initial incubation period of 42.5 to 67.9 h, up to 1100 1 of test solution/groundwater mixture was extracted in each test from the same location. During the extraction phases, we measured concentrations of relevant species including Br-, SO4_ and sulfide (S(-II)), as well as stable sulfur isotope ratios (834S) of extracted, unconsumed SO. and extracted S(-II). Results indicated sulfate reduction activity in the vicinity of the test well. Computed first -order rate coefficients for sulfate reduction ranged from 0.043 ± 0.013 to 0.130 ± 0.015 day-1. Isotope enrichment factors (e) computed from sulfur isotope fractionation of extracted, unconsumed SO - ranged from 20.2 ± 5.5%o to 22.8 ± 3.4%0. Together with observed fractionation in extracted S(-II), isotope enrichment factors provided strong evidence for microbially mediated sulfate reduction. Thus, push-pull tests combined with stable sulfur isotope Corresponding author. Tel.: +41-1-633-6039; fax: +41-1-633-1122. E-mail address: schroth@ito.umnw.ethz.ch (M.H. Schroth). 0169-7722/01/S - see front matter ©2001 Elsevier Science B.V. All rights reserved. PII: S0169-7722(01)00128-0 180 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 analyses proved useful for the in situ quantification of microbial sulfate reduction in a PHC-con- taminated aquifer. © 2001 Elsevier Science B.V. All rights reserved. Keywords: Bioremediation; Microbial activity; Sulfate reduction; Single -well test; Stable isotopes; Petroleum hydrocarbons 1. Introduction Microbial sulfate reduction is an important metabolic activity in many petroleum hydrocarbon (PHC)-contaminated aquifers (Lovley, 1997; Wiedemeier et al., 1999). During dissimilatory sulfate reduction, bacteria reduce sulfate (S(V-) to sulfide (S(-II), defined here as the sum of H 2 S, HS - and S 2 - ). Concurrently, PHC and other indigenous organic compounds are oxidized and often mineralized to carbon dioxide (CO2) and water. Thus, microbial sulfate reduction contributes to the removal of PHC constituents from contaminated aquifers (Thierrin et al., 1993; Vroblesky et al., 1996; Reinhard et al., 1997; Anderson and Lovley, 2000). Quantitative information on microbial sulfate reduction is needed to assess its contribution to overall PHC removal at a site. Over the last decade, it has become increasingly apparent that in situ test methods are required to accurately assess subsurface microbial activities (Gillham et al., 1990; Madsen, 1991, 1998). Recently, single -well injection -withdrawal tests, which we call "push-pull" tests, have been used for the in situ quantification of microbial activities in PHC-contaminated aquifers (Istok et al., 1997; Reinhard et al., 1997; Schroth et al., 1998). In a push-pull test, a prepared test solution that contains a non -reactive, conservative tracer and one or more reactive solutes (reactants) is injected ("pushed") into the aquifer through an existing well. During the following initial incubation period (i.e., a rest phase without pumping), indigenous microorganisms consume reactants and generate metabolic products. Thereafter, the test solution/groundwater mixture is extracted ("pulled") from the same location. Rates of microbial activities are then determined from an analysis of solute breakthrough curves obtained by measuring concentrations of tracer, reactants and/or metabolic products at the injection/extraction well during the extraction phase of the test (Haggerty et al., 1998; Snodgrass and Kitanidis, 1998). So far, push-pull tests have been employed to quantify several microbial processes in PHC-contaminated aquifers including aerobic respiration, denitri- fication, sulfate reduction and methanogenesis (Istok et al., 1997), and degradation of PHC constituents under nitrate- and sulfate -reducing conditions (Reinhard et al., 1997). In addition, push-pull tests were used to assess spatial variability in aerobic respiration and denitrification (Schroth et al., 1998). However, despite their efforts Istok et al. (1997) were unsuccessful in determining rates of microbial sulfate reduction, as essen- tially none of the injected SO4- was consumed during their tests, possibly due to the relatively short incubation periods (- 7 h) employed. Quantification of microbial sulfate reduction based on reactant (SO4 -) consumption or product (S(-II)) formation may be obscured by concurrent abiotic transformations, e.g., by dissolution/precipitation of gypsum (CaSO4, Stumm and Morgan, 1981), or by M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 181 precipitation of S(-II) as iron sulfides (Anderson and Lovley, 2000). As a tool to discern microbial activity from abiotic transformations, stable isotope analyses have found increasing application in recent years. For example, sulfur in natural environments consists largely of two stable isotopes: 32 S (95.02% natural abundance) and 34 S (4.21 natural abundance) (Hoefs, 1997). Microbial sulfate reduction usually results in signifi- cant isotope fractionation, i.e., an enrichment of 34S in unconsumed SO4- coupled to an enrichment of 32S in produced S(-II) (Krouse, 1980; Clark and Fritz, 1997; Hoefs, 1997). Sulfur isotope fractionation in groundwater was previously observed in forest hydrology studies (Robertson and Schiff, 1994; Alewell and Giesemann, 1996) as well as in contaminated aquifers, e.g., at a waste disposal site (Bottrell et al., 1995). Thus, sulfur isotope fractionation appears to be a valuable indicator for microbial sulfate reduction in various environments. Unfortunately, little is known about sulfur isotope fractionation in PHC-contaminated aquifers. The main objective of this study was to evaluate the feasibility of push—pull tests in combination with stable sulfur isotope analyses for the in situ quantification of microbial sulfate reduction in a PHC-contaminated aquifer. Sulfate reduction was quantified based on sulfate consumption observed during push—pull tests. In addition, stable sulfur isotope analyses of extracted, unconsumed SO4 - and of extracted S(-II) were used to determine isotope enrichment factors, which served as indicators for microbial sulfate reduction. 2. Materials and methods 2.1. Field site description The study was conducted in a heating oil -contaminated aquifer in Studen, Switzer- land (Fig. la), which was characterized in detail by Bolliger et al. (1999). In 1993, a spill from a leaking underground heating oil pipe was discovered at the site. Engineered remediation was limited to the removal of free -phase heating oil (— 34 m3) by partial excavation of contaminated soil and by pumping until 1996. At that time, engineered remediation was terminated and monitored natural attenuation was selected as the follow-up remediation strategy. The 20- to 25-m-thick unconfined aquifer consists of unconsolidated glaciofluvial outwash deposits with interbedded layers of poorly sorted silt, sand and gravel. The ground water table is generally between 2 and 4 m below ground surface. Hydraulic conductivity ranges from 1.0 X 10-4 to 9.3 X 10-3 m s I, porosity is estimated at 0.19, and the average pore water velocity is ^- 0.4 m day-1 (Bolliger et al., 1999). Push—pull tests described in this paper were conducted in monitoring well PS3, which is located within the contaminant source zone (free -phase PHC present) (Fig. 1a). Well PS3 is constructed of 11.5 cm I.D. polyvinyl chloride casing and partially penetrates the aquifer to a depth of — 1 m below the ground water table. Compared to the uncontaminated, upgradient well P20 (Fig. la), groundwater in PS3 exhibited reduced conditions and contained up to 1 mg 1-' dissolved PHC (Bolliger et al., 1999). Monitoring of geochemical parameters along a center flow line revealed that dissolved oxygen (not shown) and nitrate were almost completely depleted and SO4- was 182 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 (a) Source zone • Monitoring wells x Leak — Center flow line (b) • 0.4 0 0.3 a) = 0.2 0 0.1 Cr 0.0 z I Buildings — Roads Ground water flow direction 0.8 2 0.6 c 0 0.4 d U 0.2 cai 0.0 2 v 0 50 100 Distance (m) Fig. 1. (a) Site map of the heating oil -contaminated aquifer in Studen, Switzerland, and (b) concentrations of selected geochemical parameters along the center flow line as determined by Bolliger et al. (1999). Push—pull tests described in this paper were conducted in monitoring well PS3. partially depleted by the time groundwater reached PS3 (Fig. lb, adopted from Bolliger et al., 1999). Conversely, methane (CH4) concentrations increased considerably down - gradient from PS3. Long-term monitoring for this site provided additional evidence that PS3 is located within a transition zone where both sulfate -reducing and methanogenic conditions are found (Bolliger et al., 2000). 2.2. Push—pull tests and sample collection procedures Four push—pull tests, denoted PPT 1 through PPT4, were performed over a 9-month period from August 1999 until April 2000. First, PPT1 was performed to evaluate M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 183 sulfate transport behavior during a push-pull test. Then PPT2, PPT3 and PPT4were performed to repeatedly quantify rates of microbial sulfate reduction. For each push-pull test, groundwater was first withdrawn from PS3 using a submersible pump (Gmndfos MP-1, Grundfos Pumpen, Fallanden, Switzerland) and collected in 500-1 plastic carboys. Test solutions were then prepared by adding bromide (Br-, prepared from KBr, Fluka, Buchs, Switzerland) as non -reactive, conservative tracer and SO4 - (prepared from K2 SO4 Fluka) as reactant to achieve final concentrations of 0.5 mM Br- and 1.0 or 2.0 mM SO4- (Table 1). In PPT2, PPT3 and PPT4, the carboys were continuously sparged with nitrogen gas to minimize 02 dissolution from air into test solutions during preparation and subsequent injection. For each push-pull test, injection of a specified volume of test solution into PS3 began at time t = 0 h and was completed within 0.92 to 2.83 h using gravity drainage (Table 1). In PPT1, continuous extraction began 1.1 h after the injection was terminated. Longer initial incubation periods were used in PPT2, PPT3 and PPT4 before continuous extraction was initiated in PPT2 and stepwise extraction over four consecutive days (batches of 200 to 300 1 each per day) was employed in PPT3 and PPT4. In this fashion, we extracted between 380 and 1100 1 of test solution mixed with native groundwater in each test at nearly constant flow rates. Total test duration varied from 4.1 h in PPT1 up to 119.9 h in PPT3 (Table 1). Water samples for chemical/isotope analyses were obtained during the collection of groundwater in carboys (background concentrations), during the injection of test solu- tions (injection concentrations), and at regular intervals during the extraction phase of the push-pull tests. Samples for Br- and SO4- were filtered in the field using 0.45-µm polyvinylidenefluoride filters (Millipore, Bedford, USA) and stored in 12-m1 plastic vials. Samples for alkalinity and pH were collected without headspace in 117-m1 serum bottles using butyl rubber stoppers. All samples were stored at 4°C prior to analysis. Samples collected for dissolved 02, S(-II) and ferrous iron (Fe(II)) determination were analyzed immediately in the field (see below), as was groundwater temperature using an appropriate electrode (Cyberscan pH100, Eutech Cybernetics, Singapore) fitted to a flow cell. Samples for sulfur isotope measurements of SO4 - (PPT2-PPT4) were collected in 1-1 glass bottles acidified with 2 ml of 32% HCl (Fluka). Sulfate was subsequently precipitated as BaSO4 by replacing 10 ml of sample with 10 ml of a 1.2-M BaC12 Table 1 Summary of experimental conditions during four push-pull tests performed to evaluate sulfate transport behavior (PPT1) and microbial sulfate reduction (PPT2, PPT3, and PPT4) in a PHC-contaminated aquifer Test SO4- injection Injection Injection Initial Total Total test concentration volume (1) duration (h) incubation extracted duration (h) (mM) period (h) volume (I) PPT1 2.0 190 0.92 1.1 380 4.1 PPT2 1.0 500 1.83 67.9 1000 73.0 PPT3 1.0 1000 2.83 44.1 1100 119.9 PPT4 1.0 1000 2.17 42.5 1100 117.3 184 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 solution. Samples for sulfur isotope measurements of S(-II) (PPT4 only) were collected in 25-1 plastic carboys with 5 1 of headspace. Immediately after collection, samples were acidified using 180 ml of 1 M HC1 and vigorously sparged with nitrogen gas for at least 30 min. During sparging, S(-II) was precipitated as Ag, S in a gas trap. The trap contained 40 ml of 12.75 mM AgNO3 buffered at pH = 4 using 100 mM acetic acid/20 mM sodium acetate (Moncaster and Bottrell, 1991). 2.3. Analytical methods Bromide and SO4 - concentrations were determined using a DX-100 ion chromato- graph system equipped with a conductivity detector (Dionex, Sunnyvale, CA, USA). Alkalinity was measured by potentiometric titration using Gran plots for graphical determination of the end point (Stumm and Morgan, 1981) and pH was measured in the laboratory with a MP 225 pH meter equipped with an InLab407 electrode (both Mettler -Toledo, Schwerzenbach, Switzerland). Dissolved inorganic carbon (DIC, sum of H2CO3, HCO3 and CO3-) concentrations were calculated from alkalinity and pH (Stumm and Morgan, 1981). Dissolved 0,, S(-II) and Fe(II) were measured colorimetri- cally using a DR/890 colorimeter (Hach, Loveland, CO, USA) following standard protocols. For stable sulfur isotope measurements, BaSO4 and Ag2 S were separately recovered on 0.45-µm HVLP membrane filters (Millipore). After drying at 80°C, - 0.7 mg BaSO4 or Ag2 S were weighted in tin cups together with ^- 1.4 mg vanadium pentoxide (added as catalyst). Sulfur isotope ratios (34S/32S) were subsequently measured on an Optima mass spectrometer (Fisons, Middlewich, Cheshire, UK) coupled in continuous -flow to an elemental analyzer (Carlo Erba Instruments, Milan, Italy). The system was calibrated using international standards IAEA NZ1, IAEA NZ2, and NBS127 (IAEA, 1995). Analytical reproducibility of the measurements was ± 0.3%0. Isotope data are reported in the conventional 8-notation relative to the Vienna -Canyon Diabolo Troilite (V-CDT) standard using: 834S (%0) - 2.4. Determination of first -order rate coefficients First -order rate coefficients for sulfate reduction were determined from sulfate consumption using the method of Haggerty et al. (1998). This method is based on an analysis of tracer and reactant transport in the alternating diverging/converging radial flow field surrounding a monitoring well during a push-pull test. The method assumes that the injected reactant is transformed within the aquifer according to the first -order type reaction dCr/dt = -kCr, where Cr is the reactive solute concentration and k is the rate coefficient. The method also assumes that the injected test solution is well mixed within the aquifer and that the advection-dispersion-sorption transport properties of M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 185 tracer and reactant are similar. With these assumptions, the rate coefficient may be determined from (Haggerty et al., 1998): ( Cr* (t*) (1-e-kr;,u) In Ctr ( *) t = 1n kt kt*(2) n� where C * is relative concentration (i.e., measured concentration divided by the concen- tration in the injected test solution), subscripts r and tr denote reactant and tracer, respectively, t * is time elapsed since the end of the test solution injection, and tini is duration of the test solution injection. Hence, a plot of ln(Cr* /C,*) versus t * generates a straight line with a slope - k and an intercept ln[(1 - e-k`Ini)/ktini)]. A nonlinear least -squares routine was used to fit Eq. (2) (both slope and intercept) to experimental breakthrough data to obtain estimates of first -order rate coefficients for sulfate reduction. The 95% confidence interval for k (k ± 2 crk) was computed from the variance of the estimated k, o-k2 using (Schroth et al., 1998): z " 1-ek`mmt+ktin. t k(ek`.fli - 1) (3) ok -t with i = 1 to n, where n is the total number of observations, and o-' is the variance of errors in In (Cr* /C« ). 2.5. Determination of isotope enrichment factors Sulfur isotope fractionation was quantified by computing isotope enrichment factors, e (in %o). In a closed system, enrichment factors can be determined by fitting Rayleigh distillation equations to experimental data (Mariotti et al., 1981). Specifically, enrich- ment factors of extracted, unconsumed SO4 - and extracted S(-II) may be determined from measured 834 S values using (Bottcher et al., 1999): b34S(SO4-) = 634S(SO4-)0 + elnf (4) 834S(S(-II)) = 534S(SO4 )0 - e(.flnf)/(1 -f) (5) where f is the fraction of extracted, unconsumed SO4-, and 534S(SO4-)0 is the initial isotope composition of sulfate in the injected test solution. 3. Results and discussion 3.1. Push-pull tests Breakthrough curves for Br- and SO4 - showed a gradual decline in C * as extracted test solution was increasingly diluted with native groundwater during PPT1 (Fig. 2). In addition, relative concentrations of SO4- and Br- were nearly identical throughout the extraction phase. This indicates that SO4- transport behavior in general was similar to that of Br- and that SO4- sorption to aquifer solids in particular was negligible during 186 M.H. Schroth et al. /Journal of Contatninant Hydrology 51 (2001) 179-195 PPT1 (Schroth et al., 2000). Thus, results from PPT1 confirmed the assumption of similar transport behavior for tracer and reactant, which is required for the accurate computation of rate coefficients in subsequent tests using the method of Haggerty et al. (1998). Moreover, by the end of PPT1 78% of the injected Br- mass and 77% of the injected SO4- mass was recovered (computed by integrating solute breakthrough curves shown in Fig. 2). Recovery of similar relative solute masses clearly indicates that the total test duration (4.1 h, Table 1) was sufficiently short to prevent notable SO4- consumption during PPT1. Extraction phase breakthrough curves for Br- and SO4- during PPT2, PPT3 and PPT4 (Fig. 3) showed gradual declines in C * similar to that observed during PPT1 (Fig. 2). However, relative SO4- concentrations were smaller than relative Br- concentra- tions during most of PPT2-PPT4 extraction phases, which indicated that sulfate was consumed during those tests, presumably due to microbial activity. Relative concentra- tions of SO4- slightly larger than those of Br- were only observed in samples collected near the end of PPT2-PPT4 extraction phases (Fig. 3). This is due to SO4- contained in native groundwater (- 0.03 mM at the time the tests were conducted), which was extracted together with the injected test solutions. To account for SO4 - contained in native groundwater, we computed corrected sulfate concentrations (` SO4 -) using Br - breakthrough curves as a measure of dilution of test solution with native groundwater and assuming constant SO4- background concentrations for each test (Schroth et al., 1998). As a consequence, relative `SO4- concentrations were smaller than relative Br - concentrations throughout PPT2-PPT4 extraction phases (Fig. 3). Note that in PPT1 no correction of SO4- data was necessary due to the higher SO4- concentrations em- ployed in this test. During the extraction phases of PPT2, PPT3 and PPT4, we recovered between 25% and 31% of the injected Br- mass and between 20% and 23% of the injected SO4- Relative concentration, C* 1.0 - 0.8 - 0.6 - 0.4 - 0.2 - PPT 1 • Br" • SO42- 0.0 . 1. 1. 1, 1. 1. 1, 1. 1• 1" 1 0 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 Extracted volume / injected volume Fig. 2. Breakthrough curves for Br- and SO4- obtained during the extraction phase of PPT1, which was performed to assess SOq _ transport behavior during a push-pull test. M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 187 mass. Differences between recovered relative Br- and SO4- masses (21.3 ± 7.2% on average for PPT2-PPT4) illustrate that total test durations (Table 1) were sufficiently long to allow notable sulfate consumption during these tests. Conversely, mass recovery of injected Br- tracer in PPT2-PPT4 (25-31%) was poor compared to that in PPT1 (78%). This is likely due to longer test durations in PPT2-PPT4 (Table 1) in combina- tion with a fairly high average pore water velocity (- 0.4 m day-1) at the site. Thus, during PPT2-PPT4, a significant portion of test solution migrated beyond the radius of influence of PS3. However, it is important to note that no complete tracer mass recovery is required during push-pull tests for an accurate quantification of rate coefficients (Haggerty et al., 1998; see next section). Sulfide increased from background concentrations (9.3-16.8 µM) to maximum concentrations ranging from 14.0 to 50.9 µM during PPT2-PPT4 extraction phases (not shown). For each test, produced S(-II) mass was computed by integrating measured S(-II) concentrations after they were corrected for background and injected test solution S(-II) concentrations. Produced S(-II) mass recovered during PPT2-PPT4 ranged from 2.3 to 14.9 mmol, which is much less than expected based on measured SO4 - consumption (41.4-50.0 mmol). Loss of produced S(-II) during our tests was presum- ably due to FeS precipitation, as Fe(II) concentrations up to 59.1 µM were measured during the extraction phases (solubility product for FeS(s) is Kso = 10 -181 at 25°C; Stumm and Morgan, 1981). Increased Fe(II) concentrations are commonly encountered within reduced zones of contaminated aquifers (e.g., Lovley, 1997; Lovley and Ander- son, 2000), often rendering S(-II) data useless for the quantification of microbial sulfate reduction. Other geochemical parameters did not vary significantly during PPT2-PPT4 extrac- tion phases (not shown). In particular, calculated DIC concentrations ranged from 11.1 to 13.2 mM during the extraction phases without an obvious trend and were even slightly smaller than DIC background concentrations (13.3 to13.8 mM) in PS3. This is at least in part due to somewhat smaller DIC injection concentrations (9.7 to 13.3 mM, due to sparging of test solutions prior to and during injection) compared to DIC background concentrations. Moreover, based on measured SO4- consumption and given the follow- ing reaction stoichiometry (Bolliger et al., 1999): 1.37CH1 85 + SO4—+ 2H+- 1.37CO2 + H2S + 1.26H20 (6) we would expect minimal DIC production during our tests (up to 68.5 mmol DIC in 1000 1 of extracted test solution) compared to DIC contained in test solutions and native groundwater. Thus, DIC data obtained during our tests did not provide additional information for the quantification/verification of microbial sulfate reduction. This result contrasts results for DIC analyses performed across entire contaminated sites, which often provide useful information on overall metabolic activities (e.g., Chapelle et al., 1996; Bolliger et al., 1999; Hunkeler et al., 1999). 3.2. Quantification of microbial sulfate reduction First -order rate coefficients for sulfate reduction were computed for PPT2, PPT3 and PPT4 based on Br- and ° SO4- breakthrough data (Fig. 3) using the method of 188 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 Haggerty et al. (1998) (Fig. 4). Note that best fit lines in Fig. 4 are intentionally extended to the y-axis intercept (not forced through the origin) as both slope and y-axis intercept were fitted (Eq. (2)). Simultaneous fitting of slope and intercept effectively forces k to be the same throughout an entire push-pull test, i.e., during injection as well as during subsequent incubation and extraction. Also note that PPT2 results were unamenable for display due to the different extraction mode used in that test. Computed values of k ranged from 0.043 to 0.130 day-1 with 95% confidence intervals ranging from 0.010 to 0.015 day-1 (Table 2). Thus, values of k varied by less than a factor of four between the tests. On the other hand, variations in k were significant to the 95% 0.0 . 1. 1. 1• 1. 1' 1• 1. 1. 1• 1 0 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 Extracted volume / injected volume C 0.6 - 0.5 - c 0.4 - c 0 0.3 - a) 0.0 • 1 • 1 • 1 ' 1 I 0 0 0.2 0.4 0.6 0.8 1.0 Extracted volume / injected volume Fig. 3. Breakthrough curves for Br- and SO4- obtained during extraction phases of (a) PPT2, (b) PPT3, and (c) PPT4. Open symbols show corrected SO, - concentrations (`SO4 ), which were computed using Br - data as a measure of dilution between test solutions and native groundwater. 12 J1 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 189 0.8 0.0 i i 1 i t . 0 0 0.2 0.4 0.6 0.8 1.0 Extracted volume / injected volume Fig. 3 (continued). 12 confidence level and may at least in part be attributed to the difference in groundwater temperature at the time each test was conducted (Table 2). Specifically, values of k increased with increasing temperature in our tests, which is the generally expected response of microorganisms to changes in temperature within a specific interval suitable for growth (Madigan et al., 2000). Conversely, some scatter in the experimental data are visible in Fig. 4, which may indicate that the method's underlying assumption of 0 0.0 -0.1 - -0.4 - -0.5 Fig. 4. Determination of first -order rate coefficients of microbial sulfate reduction for PPT3 and PPT4. Lines show the best fit of Eq. (2) to experimental data obtained using the method of Haggerty et al. (1998). Time since injection ended, t*(h) 20 40 60 80 100 120 . 1 . 1 . 1 . 1 . 1 . 1 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 191 Isotope ratio, S34S(SO42) (%o) 30 25 - • measured A corrected — Rayleigh fit (a) PPT 3 20 - AA 0 0 15- 10- 5 30 i 1 i 1 0 0.9 0.8 0.7 Sulfate fraction, f o ' 25 - N 0 co y 20 - Q 20 10 (n 5 • measured o corrected — Rayleigh fit I 1 0 0.9 0.8 0.7 Sulfate fraction, f 06 06 Fig. 5. Stable sulfur isotope ratios of remaining, unconsumed SO4- obtained during (a) PPT3 and (b) PPT4 extraction phases. Corrected isotope ratios (`534S(SO4-)) were computed using Br- data as a measure of dilution between test solutions and native groundwater. The solid lines represent Rayleigh distillation curves (Eq. (4)), which were fitted to `834S(SO4 -) data using linear regression analyses. breakthrough data as a measure of dilution between test solutions and native groundwa- ter (Fig. 5). By fitting the Rayleigh equation (Eq. (4)) to °b34S(SO4-) data, we then obtained a values of 22.8 ± 3.4%o for PPT3 and 20.2 ± 5.5%o for PPT4 (Table 2). Note that we were unable to compute `b34S(SO4-) data for PPT2 due to an unreliable measurement of the background SO4- isotope composition for the time this test was conducted. Consequently, no e value was computed for this test. Enrichment factors computed for our tests agreed well with e values obtained by others for microbial sulfate reduction in different environments, e.g., e values of 16%0 192 M.H. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 to 42%0 (Habicht and Canfield, 1997), 19%0 (Bottcher et al., 1999), and 21.4%o to 28%0 (Asmussen and Strauch, 1998). Moreover, s values we obtained were significantly larger than those commonly observed during physical/chemical transformations of SO4 - (Krouse, 1980), and they were within a range that is indicative for microbial sulfate reduction (- 20%o to 40%0, Clark and Fritz, 1997). Hence, stable sulfur isotope fractionation of extracted, unconsumed SO4 - provided strong evidence for microbial sulfate reduction during our tests. On the other hand, the magnitude of sulfur isotope fractionation depends on many environmental parameters (e.g., Clark and Fritz, 1997; Bottcher et al., 1999). Thus, a fully quantitative interpretation of s values obtained in natural systems such as PHC-contaminated aquifers, including the quantification of reaction rate coefficients based on isotope enrichment factors (Aggarwal et al., 1997), is not feasible to date. Consequently, we cannot unequivocally exclude the possibility that a portion of injected SO4 may have been abiotically consumed during our tests. However, inorganic sulfate reduction is usually not significant in ground waters (Clark and Fritz, 1997), and, at least for PPT1, SO4- precipitation did not appear to play a major role during the test (Fig. 2). Concurrent to an increase in 534 S(SO4 ), a decrease in 834 S(S(-II)) was measured in samples collected during the extraction phase of PPT4 (not shown). This would be expected for a closed system, in which enrichment of 34S in unconsumed SO4- must lead to a depletion of 34S in produced S(-II). However, due to the small quantity of produced S(-II) recovered during the test and the relatively high S(-II) background concentration in native groundwater (see above), computation of s was not straightfor- ward in this case. Depending on the (unknown) composition of extracted S(-II) (produced or background S(-II)), we computed hypothetical values of s by fitting Eq. (5) to experimental data. Computed values of s ranged from 14.8 ± 2.7%0 (for the case that samples were composed of produced S(-II) only) to 30.1 ± 6.5%0 (for the case that samples were composed of 100% background S(-II) and variable amounts of produced S(-II)). For the case that samples were composed of 50% produced/50% background S(-II), we calculated s = 22.9 ± 5.4%0. The latter value of s in particular agreed well with values of s calculated from cO34 S(SO4 ) data for PPT3 and PPT4 (Table 2), but an unbiased comparison between the different s values was obviously impossible. Never- theless, the general observation of isotope fractionation in extracted S(-II) during PPT4 provided additional qualitative evidence for microbial sulfate reduction. 4. Summary and conclusions Microbial sulfate reduction was quantified in situ in a PHC-contaminated aquifer based on sulfate consumption observed during single -well push-pull tests. In three consecutive tests, calculated first -order rate coefficients for sulfate reduction varied by less than a factor of four. These variations were attributed in part to observed differences in groundwater temperature between the tests. However, variations in other parameters such as e.g., substrate concentration and pH may also have contributed to differences in measured rates of sulfate reduction between consecutive tests. Although some scatter in the field data was observed, we were able to determine rate coefficients for sulfate M.N. Schroth et al. /Journal of Contaminant Hydrology 51 (2001) 179-195 I93 reduction with reasonable accuracy, as indicated by relatively small 95% confidence intervals. Additional studies should be conducted at common field sites to compare rate coefficients for sulfate reduction obtained by our method with those obtained by other in situ methods such as, e.g., in situ microcosms. We demonstrated that quantification and/or verification of microbial sulfate reduc- tion based on metabolic product formation (S(-II), DIC) was not feasible during our push-pull tests. On the other hand, we provided strong evidence for microbial sulfate reduction during our tests using stable sulfur isotope analyses. From measured isotope fractionation of extracted, unconsumed SO4 -, we computed enrichment factors that suggested microbial activity as the major mechanism for SO4- consumption. Further evidence for microbial sulfate reduction during one push-pull test was obtained from stable isotope measurements of extracted S(-II), even though a straightforward analysis of 534 S(S(-II)) data was hampered by the small quantity of produced S(-II) compared to the high S(-II) background concentration. Further experiments will be required to interpret computed isotope enrichment factors resulting from microbial sulfate reduction in a more quantitative fashion. Nonetheless, push-pull tests combined with stable sulfur isotope analyses proved useful for the in situ quantification of microbial sulfate reduction in a PHC-contaminated aquifer. Acknowledgements We wish to thank J.P. Clement (Amt fur Gewasserschutz and Abfallwirtschaft, Kanton Bern, Switzerland) for his cooperation at the field site. This study was funded by the Swiss National Science Foundation, Priority Program Environment, and by the Swiss Agency for the Environment, Forests and Landscape (BUWAL). References Adrian, N.R., Robinson, J.A., Suflita, J.M., 1994. Spatial variability in biodegradation rates as evidenced by methane production from an aquifer. Appl. Environ. Microbiol. 60 (10), 3632-3639. Aggarwal, P.K., Fuller, M.E., Gurgas, M.M., Manning, J.F., Dillon, M.A., 1997. Use of stable oxygen and carbon isotope analyses for monitoring the pathways and rates of intrinsic and enhanced in situ biodegradation. Environ. Sci. Technol. 31 (4), 590-596. Alewell, C., Giesemann, A., 1996. Sulfate reduction in a forested catchment as indicated by 634S values of sulfate in soil solutions and runoff. Isot. Environ. Health Stud. 32, 203-210. 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Wiley, New York, 617 pp. ATTACHMENT E - INJECTION PROCEDURE AND EQUIPMENT (1) Construction Plans & Materials URS proposes to inject a magnesium sulfate solution (with bromide tracer) in two areas on the Site; Sulfate Injection Area 1 and Sulfate Injection Area 2 (see attached map in Attachment H). Two areas are proposed to evaluate the effectiveness in an area of predominately benzene contamination and an area of both benzene and MTBE. Both areas will be similar in size with the advancement of 7 to 12 borings per area. Spacing of the points will be in grid pattern (i.e. offset rows with approximately 8 foot spacing between each point). Borings are to be advanced between 20 and 40 feet bgs. It is anticipated that a direct push technology (DPT) will be used as a delivery platform. Due to the potential for weathered bedrock (saprolite), a direct -push vehicle capable of turning an auger may be utilized. The probe injection point will be advanced to the specified depth then the injection point will be uncovered. An injection manifold inclusive of quick connect couplings, a ball valve, and a pressure gauge will be attached to the top of the DPT rods. Concurrent with the DPT advancement an Epsom salt and bromide solution will be mixed with potable water to a sulfate concentration of 2,000 mg/L and bromide concentration of up to 1,000 mg/L. Concentrations will be based on calculations and the first batch will be checked by laboratory analysis. (2) Operation Procedures This is a temporary mobile system that is vendor supplied. General components consist of a mixing tank, product pump, metering and measuring system and affiliated conveyance hose. The application apparatus will include a diaphragm injection pump with controller able to modulate flow to below 5 gpm. The Injection pressure will be monitored at the injection manifold through pressure gauges The mobile system will be equipped with tanks for mixing the injection solution. Municipal water will be used for the solution mixing. The solution will be injected at ambient temperatures. High pressure hose will extend from the mixing tank, to the injection pump, to the injection. A pressure gauge, shut-off valves, and pressure bleed -off will also be installed in -line. Injection will be performed using a diaphragm pump. Injection pressures may range from 50 to 300 psi and injection flow rates may range from 5 to 36 gpm. The injection pressure will be monitored continuously using a pressure gauge and the injection rate will be adjusted using the injection pump and valves. After injection, the injection pump will be turned off and the shut-off valve will be closed. The residual pressure in the formation will then be monitored. (3) Diagrams & Figures See the attached figure in Attachment H for proposed area(s) of injection and the references below for injection area within the boring. (4) Planned Injection Schedule It is anticipated that the injections will take place in late August 2010. The injection points will be installed using a Direct Push Technology drilling rig. It is anticipated that several points will be installed at the same time and then injected solution delivered to several points at the same time. It is anticipated that no more than a 4-5 foot section will be injected at a time then the DPT will be advanced to the next 4-5 foot interval until the boring depth is complete. Each of the two areas will be completed in approximately 5-8 days. ATTACHMENT F - MONITORING PLAN (1) Existing and Proposed Monitoring Wells Sulfate Injection Area 1 —Installation of one new monitoring well is scheduled for completion in July/August 2010. The existing and proposed well locations are shown on Figure la located in Attachment H. A well construction diagram for the proposed monitoring well is included in Attachment H. Sulfate Injection Area 2 —Installation of one new monitoring well is scheduled for completion in July/August 2010. The existing and proposed well locations are shown on Figure la located in Attachment H. A well construction diagram for the proposed monitoring well is included in Attachment H. (2) Monitoring Parameters and Analytical Methods To monitor the effectiveness of the injection activities, groundwater samples will be collected from the proposed well and existing monitoring wells MW-21, MW-26 and MW-05 in Area 1 and monitoring wells UW-08 and UW-06 and the proposed well in Area 2. Groundwater samples will be analyzed for: • Volatile organics (BTEX, MTBE, IPE, Naphthalene, 1,2-DCA) by Method SW-846 8260B, • Total Magnesium by SW-846 6010B, • Total Sulfide by SM20 4500 S2 D, • Hydrogen Sulfide (Dissolved Sulfide, calculation, Conductance, pH) by Method SM18 4500 S2 F. • Dissolved Methane by RSK SOP 175. In addition, to monitor parameters related to reduction and the injected fluids, groundwater samples will be analyzed by EPA Method 300 for • Nitrate, • Nitrite, • Bromide, • Chloride, • Fluoride, • Sulfate Measurements of dissolved oxygen, pH, temperature, specific conductivity and oxidation/reduction potential will also be collected in the field. To monitor the effectiveness of the injection activities, groundwater samples will be collected from the proposed well and existing monitoring wells UW-08 and UW-06 as described above. (3) Sampling Schedule Groundwater samples will be collected from the wells specified above prior to injection and at two weeks, one month, two months, and three months. ATTACHMENT G — WELL DATA The following Information was provided previously by Piedmont Geologic (August 19, 2005) (1) Public Water Supply Systems Based upon information provided by previous site consultants (G&E, 1998), 19 public water supply (PWS) systems are located within an approximate 3-mile radius of the facility. No PWS systems have been identified within a 1,500-foot radius of the facility. (2) Private Water Supply Wells CRA (2004) identified and located private water -supply wells within an approximately 1,500-foot radius of the facility using a portable global positioning system (GPS). Private water well locations are shown relative to the current distribution of site groundwater COCs on Figure 6. The current disposition of the wells, as described below, was confirmed by Mr. Keith Lewis of TransMontaigne, the Southeast Terminals facility manager, in January and February 2005. Three private potable water wells are situated within a 1,500-foot radius of the facility boundaries. Information regarding the potable water -supply wells is summarized as follows. Summary of Potable Water -Supply Wells Within 1,500-foot Radius of Facilit Well No. (Figure 6) Property Address Property Owner Distance/Direction Relative to Site 2 721 Wingate Dr James and Laura Wingate 1,450 ft downgradient of southern facility boundary 1,850 ft downgradient of tank 117/118 area 2,025 ft downgradient of northwest area 5 6516/6518 Freedom Dr Emmitt and Belinda Thomas 900 ft sidegradient of southern facility boundary 1,200 ft downgradient of northwest area 1,550 ft sidegradient of tank 117/118 area 6 7214 Old Mount Holly Rd Jack Bennett 1,000 ft upgradient of northern facility boundary 1,250 ft upgradient of tank 117/118 area 1,350 upgradient of northwest area Two properties within a 1,500-foot radius of the facility boundaries contain private water -supply wells. However, these same properties are also connected to city water and have water accounts with CMUD. Based on this condition, these wells are considered non -potable water -supply well. Information regarding the non -potable water -supply wells is summarized as follow: Summary of Non -Potable Water -Supply Wells Within 1,500-foot Radius of Facilit Well No. (Figure 6) Property Address Property Owner Distance/Direction Relative to Site 1 633 Wingate Dr. Joy Florine 1,100 ft downgradient of southern facility boundary 1,550 ft downgradient of tank 117/118 area 1,600 ft downgradient of northwest area 3 700 Wingate Dr. Juan C. and Blanca Saldana Martinez 825 ft downgradient of southern facility boundary 1,550 ft downgradient of tank 117/118 area 1,300 ft downgradient of northwest area (3) Monitoring Wells Well construction details for monitoring wells are included in Table 1. L \1\/710n No/17 14, Rai;♦\ . \ ay / Wingate •2 1 \.Nrs \O�ke 1 1 ♦ \ Vacant (formerly BP /Transmontaigne National Oil Terminal) ' O T9gninal O ♦ 0 ♦ O i it 0 100 300ft \ 1 -TT-n -T^T 1 1 1 1 1 1 1 1 1 1 I II 11111 l01 1 1 1 1 1 1 1 1 1 1 tinder -Morgan Terminal 1 • 1 0 / e ♦�, 0o0.r. • 1 ��. 0 0 i i i J Old Mount Holly Road Well No. Address Well Location Water Well Use Northing F.as ing 1 633 Wingate Dr. 559956.37 1422988.45 Non -potable 2 721 Wingate Dr. 559990/12 1422618.85 Potable (private) 3 700 Wingate Dr. • 560228.32 1422782.79 Non -potable • 5 651616518 Freedom Dr. 560699.77 1422609.42 Potable (private) 6 7214 Old Mount Holly Rd. 562276.62 1425065.58 Potable (private) IMO Legend Q Private Potable Water Well • Non -potable Water Well Non -potable Water Well (Decommissioned In 6/05) Terminal Property Line Property Line Designed: Detailed:" PIEDMONT GEOLOGIC, P.C. Environmental Consultants Gauging Date: I Drawing Date ACAD rye: 8/3/05 I Fig 2.dwq Site Area Map Ghent: Southeast Terminals Project No.: 2531 Vhecked: Location: 7401 Old Mount Holly Rd. Charlotte. N. Carolina Figure:6 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No: ., Northing (Feet) •, Basting .. �, (Feet) . Top -of- ' Casing " °Elevation (Feet .,•: Realtive to NGVD) Screen Interval (Feet Below Ground) Depth's (Feet' Below -Ground) Approximate ,- Date Installed • Geologic Zone Monitored ' Parcel Number AS01 N/A N/A 759.69 13.0 - 15.5 15.5 06/02 N/A 05724302 AS02 N/A N/A 784.98 23.5 - 25.0 25.0 06/02 05724302 DPEW01 561296.8174 1423986.6534 763.19 3.0 - 10.5 10.5 09/97 N/A 05724301 DPEW02 561602.7889 1423835.0786 781.18 4.0 - 14.0 14.0 09/97 N/A 05724301 DW01 561586.0405 1423656.5762 784.12 52.0 - 57.0 57.0 05/92 Bedrock 05724301 DW01A 561582.9012 1423696.9568 782.50 14.0 - 19.0 19.0 N/A N/A 05724301 DW02 561352.6126 1423618.9074 776.17 24.0 - 29.0 29.0 05/92 Bedrock 05724301 DW03 N/A N/A 762.28 45.0 - 50.0 50.0 05/92 Bedrock 05724301 DW04 561216.8708 1423328.0896 769.29 4.5 - 9.5 9.5 N/A 05724302 DW05 561844.7793 1423435.7268 786.60 49.0 - 54.0 54.0 N/A N/A 05724302 DWO6 561840.6986 1423913.5373 791.69 41.0 - 46.0 46.0 N/A N/A 05724301 DW08 561115.2978 1423948.3161 759.86 37.5 - 42.5 42.5 04/97 Bedrock 05724302 DW09 N/A N/A 760.09 44.0 - 49.0 49.0 12/99 Bedrock 05724302 DW10 N/A N/A N/A N/A N/A N/A N/A N/A ES01 561872.3080 1423594.5933 791.38 18.0 - 28.0 28.0 01/93 Weatered Granite 05724302 ES02 561225.4682 1423602.1330 770.32 4.0 - 44.0 44.0 03/93 05724301 ES03 561467.3861 1423617.7245 781.26 8.0 - 23.0 23.0 03/93 Saprolite 05724301 ESO4 561892.5678 1423594.9569 791.79 16.0 - 46.0 46.0 03/93 05724302 ES05 561733.8004 1423495.1581 785.77 10.0 - 45.0 45.0 03/93 05724302 ES05SR N/A N/A 786.67 10.0 - 30.0 30.0 05/05 Saprolite 05724302 ES05DR N/A N/A 786.79 45.0 - 55.0 55.0 05/05 Bedrock 05724302 ES06 561873.1015 1423452.3497 789.94 5.0 - 40.0 40.0 03/93 05724302 ES07 561852.3894 1423797.3489 791.23 2.0 - 22.0 22.0 03/93 Saprolite 05724301 ES08 561680.6126 1423873.7317 790.56 10.0 - 35.0 35.0 03/93 05724301 ES08SR" N/A N/A 792.83 10.0 - 25.0 25.0 05/05 N/A N/A ES08DR" N/A N/A 792.70 47.0 - 57.0 57.0 05/05 N/A N/A ES09 561621.2498 1423841.3317 788.04 5.0 - 45.0 45.0 03/93 05724301 ES10 561795.5151 1423598.5891 791.36 3.5 - 21.0 21.0 03/93 Sandy Clay 05724302 ES11 561641.1089 1423484.5621 785.33 5.0 - 25.0 25.0 08/93 Silty Clay 05724302 ES12 561755.9851 1423826.6505 791.76 7.0 - 22.0 22.0 08/93 Saprolite 05724301 ES13 561824.1833 1423875.9617 791.83 5.0 - 25.0 25.0 08/93 Clayey Sand 05724301 ES14 561691.2600 1423926.5230 790.70 3.0 - 23.0 23.0 08/93 Silty Clay 05724301 ES15 561723.2821 1423769.0074 790.25 8.0 - 18.0 18.0 N/A N/A 05724301 ES16 561641.5922 1423982.1524 790.25 5.0 - 25.0 25.0 01/94 05724301 ES17 561938.0508 1423551.3382 791.47 5.0 - 20.0 20.0 01/94 Silty Clay 05724302 ES18 561737.3383 1423401.7600 786.31 4.0 - 14.0 14.0 01/94 Silty Clay 05724302 ES19" 561739.5557 1424051.3416 795.13 6.0 - 26.0 26.0 01/94 Silty Clay 05724301 ES20 561902.7571 1423416.4770 787.36 6.0 - 21.0 21.0 N/A Silty Clay 05724302 ES21 * 561807.7732 1424136.5114 792.59 5.0 - 15.0 15.0 02/94 N/A 05724301 ES22 N/A N/A N/A N/A N/A N/A ES23 561245.9817 1424171.6421 764.38 4.0 - 9.0 9.0 N/A N/A 05724301 ES24 N/A N/A N/A N/A N/A N/A P:\ BP\Projects \ Terminals \4762\ Reports \ June 2009\Tables\Table 1.xls\T1 Page 1 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. _ Northing (Feet) Easting -(Feet) Top -of - Casing Elevation (Feet Reaitive,to NGVD Screen Interval (Feet:Below = Ground): " Total Depth ,(Feet '- Below _-Installed Ground) Approximate Date= Geologic Zone Monitored Parcel < Number, ES25 560892.4859 1423292.5796 754.69 N/A 24.0 N/A N/A 05724302 ES26 561460.6103 1423752.7862 777.81 29.0 - 39.0 39.0 05/96 Saprolite 05724301 ES28 561440.0360 1423683.4472 774.01 12.0 - 22.0 22.0 05/96 Saprolite 05724301 ES29 561875.0050 1423798.4872 791.37 N/A 25.0 N/A N/A 05724301 ES30 561289.7215 1423767.9827 768.21 5.0 - 15.0 15.0 N/A N/A 05724301 ES31 561463.4581 1423920.8296 779.22 6.0 - 16.0 16.0 N/A N/A 05724301 ES32 561225.0002 1423996.5307 762.94 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES33 561288.4598 1424006.1705 763.33 4.0 - 14.0 14.0 10/96 Silty Sand 05724301 ES34 561510.6321 1424372.9606 777.18 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES35 561494.7313 1424106.5233 774.74 2.5 - 15.0 15.0 10/96 Silty Sand - Saprolite 05724301 ES36' 561568.9915 1423805.4128 782.83 15.0 - 25.0 25.0 10/96 N/A 05724301 ES37 561396.2246 1423611.6336 777.88 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES38 561503.0391 1423621.9763 782.60 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES39 561565.2874 1424118.7755 781.88 4.0 - 9.0 9.0 02/97 Sandy Clay 05724301 ES40 561449.2345 1424347.7368 779.47 1.0 - 11.0 11.0 02/97 Sandy Clay 05724301 ES41 561569.1222 1424343.6774 784.60 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES42 561364.3171 1424047.1854 774.77 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES43 561358.1419 1424262.8673 777.18 8.0 - 18.0 18.0 02/97 Silty Sand - Saprolite 05724301 ES44 561604.1033 1424189.8355 790.22 8.0 - 18.0 18.0 04/97 Silty Sand 05724301 MP01 561288.8127 1423998.0869 763.10 2.5 - 12.5 12.5 09/97 05724301 MP02 561301.5317 1423976.0820 763.19 3.0 - 13.0 13.0 09/97 05724301 MP03 561300.1281 1423989.2201 763.10 2.0 - 12.0 12.0 09/97 05724301 MP04* 561603.9098 1423830.9426 781.28 1.5 - 14.0 14.0 09/97 N/A . 05724301 MP05 561578.0162 1423828.7206 779.96 2.0 - 14.5 14.5 09/97 05724301 MP06 N/A N/A 759.42 2.5 - 12.5 12.5 06/02 N/A 05724302 MW01 N/A N/A N/A N/A N/A 01/85 MW02 561487.2640 1423357.7902 781.37 5.5 - 25.0 25.0 01/85 Silty Sand - Weathered Bedrock 05724302 MW03W 561207.3791 1423326.9060 769.21 N/A 12.0 N/A N/A 05724302 MW04 N/A N/A N/A 3.6 - 18.0 18.0 10/84 MW04R 560935.1424 1423590.1046 754.94 2.0 - 11.0 11.0 02/98 Saprolite 05724302 MW05 561625.8587 1423574.6324 786.65 4.0 - 14.0 14.0 01/85 Silty Sand 05724302 MWO6 N/A N/A N/A 4.0 - 9.0 9.0 10/84 MW06R 560933.5686 1423672.4778 755.29 2.0 - 7.0 7.0 02/98 Saprolite 05724302 MW07 561354.2347 1423341.1936 774.36 2.0 - 19.5 19.5 03/85 Saprolite 05724302 MW08 561427.0882 1423348.3463 777.69 2.0 - 12.0 12.0 03/85 Saprolite 05724302 MW09 561546.8653 1423389.3473 784.65 5.0 - 20.0 20.0 03/85 05724302 MW10 561224.7864 1423594.3738 N/A N/A N/A 03/85 MW11 N/A N/A N/A N/A N/A 03/85 MW12 561719.8840 1423618.9475 786.16 1.0 - 21.0 21.0 03/85 Saprolite 05724301 MW13 561676.7002 1423472.4878 N/A N/A N/A 03/85 MW14 N/A N/A N/A 1.0 - 15.6 15.7 02/85 P:\BP\Projects\Terminals\4762\Reports\June 2009\Tables \Table 1.xls\T1 Page 2 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing ; ' (Feet)v ; Easting • • (Feet) . Top -of ,� Casing ; Elevation; (Feet Realtivo to NGVD) Screen : Interval (Feet Below Ground) Total . Depth , ` (Feet - Below Ground) . Approximate ' Date �' - Installed Geologic Zone Monitored Parcel Number MW14R 560891.2195 1423346.8273 756.41 2.5 - 15.0 15.0 02/98 Saprolite 05724302 MW15 N/A N/A N/A N/A N/A 03/85 MW16 561747.3621 1423577.1715 787.27 2.0 - 16.0 16.0 10/85 Saprolite 05724302 MW17 N/A N/A N/A N/A N/A 10/85 MW18' N/A N/A 780.90 2.5 - 22.5 22.5 10/85 MW19 561514.7100 1423363.7049 782.64 2.0 - 21.0 21.0 10/85 Saprolite 05724302 MW20 561703.5305 1423608.1548 787.34 10.0 - 25.0 25.0 10/85 Saprolite 05724302 MW21 561675.2283 1423607.2603 785.76 6.0 - 20.0 20.0 10/85 Saprolite 05724302 MW22 N/A N/A N/A N/A N/A 10/85 MW23 N/A N/A N/A N/A N/A 10/85 MW24 N/A N/A N/A N/A N/A 10/85 MW25 N/A N/A N/A N/A N/A 10/85 MW26 561705.2878 1423572.6623 785.38 5.0 - 20.0 20.0 10/85 Saprolite 05724302 MW27 561726.9164 1423606.3704 786.93 4.0 - 14.0 14.0 10/85 Saprolite 05724302 MW28 N/A N/A N/A 3.5 - 23.5 23.5 12/85 MW29 N/A N/A N/A 3.7 - 17.7 20.0 12/85 MW30 N/A N/A N/A 4.4 - 19.4 20.0 12/85 MW31 N/A N/A N/A 4.2 - 19.2 20.0 12/85 MW32 N/A N/A N/A 2.1 - 22.1 24.0 12/85 MW33 N/A N/A N/A 4.6 - 19.6 20.0 • 12/85 MW34 N/A N/A N/A 3.8 - 18.8 19.0 12/85 MW35 N/A N/A N/A 4.0 - 19.0 19.0 12/85 MW36 561526.4378 1423389.4123 785.94 5.0 - 25.0 25.0 12/85 Sandy Silt - Silty Sand 05724302 MW37 561566.9736 1423430.5503 785.17 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW38 561582.4723 1423394.7559 785.54 5.0 - 25.0 25.0 12/85 Sandy Clayey Silt 05724302 MW39 561609.9127 1423420.9725 785.28 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW40 561644.0901 1423444.7051 N/A 4.0 - 24.0 24.0 12/85 MW41 561637.3588 1423398.8937 785.64 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW42 561606.8920 1423477.4229 785.95 5.0 - 25.0 25.0 12/85 Silty Sand 05724302 MW43 561572.0617 1423568.5897 788.36 4.0 - 24.0 24.0 12/85 Silty Sand 05724302 MW44 561573.8919 1423463.5270 785.77 3.5 - 26.0 26.0 12/85 Sandy Silt 05724302 MW45 561539.1703 1423432.3766 786.91 3.0 - 28.0 28.0 12/85 Sandy Silt 05724302 MW46 N/A N/A N/A 6.3 - 16.3 16.5 01/86 MW47 561546.0782 1423573.4010 788.05 7.0 - 17.0 17.0 01/86 Sandy Clayey Silt 05724302 MW48 561560.3416 1423606.0845 788.19 2.5 - 15.0 15.0 01/86 Sandy Silt 05724301 MW49 561553.2264 1423361.8991 784.17 5.0 - 19.5 19.5 01/86 Sandy Silt 05724302 MW50 561511.9326 1423433.2840 783.50 5.0 - 25.0 25.0 02/86 Sandy Clayey Silt 05724302 MW51 561576.7167 1423524.7096 786.41 8.0 - 18.0 18.0 12/86 Clayey Sandy Silt 05724302 MW52 N/A N/A N/A N/A N/A 10/86 MW53 N/A N/A N/A N/A N/A 10/86 MW54 N/A N/A N/A N/A N/A 10/86 MW55 N/A N/A N/A N/A N/A 10/86 P:\ BP\ Projects\ Terminals \4762\ Reports\June 2009\Tables \ Table 1.xls\T1 Page 3 of 4 Table 1 Well Construction Details BP Charlotte Terminal No. 4762 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina .1 Well No. - Northing :, (Feet) „ Easting , - , , (Feet) - Top -of- Casing • Elevation (Feet Realtive to NGVD)' ',",-- - -', ' , Screen., - Interval , • . (Feet Below , round) - , - .. , '. ' mtal Depth • .., (Feet Groundt, „ , ,', , Aooroxirn te • - a ' Date , , , ,',,:, , ' ' : , ' Geologic Zone Monitored ' , -, ' `,•‘ '-‘,"1- Parcel Number ' ,, , , ' MW56 N/A N/A N/A N/A N/A 10/86 MW57 N/A N/A N/A N/A N/A 10/86 MW58 N/A N/A N/A N/A N/A 10/86 MW59 N/A N/A N/A N/A N/A 10/86 MW60 N/A N/A N/A N/A N/A 10/86 MW61 N/A N/A N/A N/A N/A 10/86 MW62 N/A N/A N/A N/A N/A 10/86 PMW01 561124.4362 1424041.9674 761.06 5.0 - 15.0 15.0 06/92 Sandy Silt 05724302 PMWO2 561125.5177 1423964.5881 760.76 6.0 - 16.0 16.0 06/92 Sandy Silt Saprolite 05724302 PMWO3 561128.1760 1423878.0757 758.52 8.0 - 18.0 18.0 06/92 Sandy Silt Saprolite 05724302 P MWO4 560675.8867 1423430.5786 750.27 11.0 - 21.0 21.0 06/92 Sand Silt 05723114 P MWO5 560662.9922 1423502.4158 743.41 10.0 - 20.0 20.0 06/92 Sandy Silt Saprolite 05723114 PMWO6 561036.5314 1423856.2959 754.27 2.0 -' 7.0 7.0 08/93 Silty Clay 05724302 P MWO7 561019.1837 1423982.5768 753.66 3.0 - 8.0 8.0 08/93 Silty Clay 05724302 PMWO8 561140.6727 1424080.3010 760.98 4.0 - 9.0 9.0 08/93 Silty Clay 05724302 PMWO9 560989.1019 1423862.8722 750.93 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW10 560846.3905 1423724.5687 746.86 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW11 560579.1482 1423436.2214 746.42 N/A 20.0 N/A N/A 05723114 PMW12 560394.9714 1423299.1239 732.48 N/A 12.5 N/A ' N/A 05723114 RW01 561092.3515 1423700.3608 N/A N/A N/A 05/86 RWO2 561590.5007 1423420.7633 784.71 6.0 - 26.0 26.0 05/86 Sandy Silt - Silty Sand 05724302 RWO3 561720.1317 1423614.0215 788.20 2.0 - 28.5 28.5 05/86 Sandy Silt 05724301 TO1 (trench) 561572.6969 1423690.8304 785.15 N/A 17.0 N/A N/A 05724301 T01A 561347.4489 1423879.9408 765.31 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 T02 (trench) 561558.4972 1423768.6401 783.08 N/A 22.0 N/A N/A 05724301 TO2A 561192.7742 1423857.4115 761.77 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 UW01* 561589.3852 1423826.6607 781.23 1.0 - 16.0 16.0 08/91 N/A 05724301 UW02 561606.2226 1423647.4684 785.44 3.0 - 18.0 18.0 08/91 Saprolite 05724301 UW03 561623.4532 1423644.3421 785.50 2.5 - 17.5 17.5 08/91 05724301 UW04 561649.6681 1423753.4841 787.59 5.0 - 20.0 20.0 09/91 Saprolite 05724301 UW05 561651.6699 1423810.2421 789.59 4.0 - 14.0 14.0 09/91 Saprolite 05724301 UWO6 561547.4955 1423695.4543 782.00 1.0 - 16.0 16.0 08/91 Saprolite 05724301 UW07* 561560.8461 1423919.6721 780.03 2.5 - 15.0 15.0 09/91 N/A 05724301 UW08 561581.0603 1423770.9912 780.97 5.0 - 15.0 15.0 02/92 Saprolite 05724301 UW09* N/A N/A 778.00 2.0 - 12.0 12.0 02/92 UW10 561650.8426 1423655.9836 785.56 3.0 - 18.0 18.0 02/92 Saprolite 05724301 UW11 561573.1870 1423648.4289 784.79 4.0 - 19.0 19.0 02/92 Saprolite 05724301 VE01 561610.1204 1423594.3698 N/A N/A 10.0 N/A 05724302 VE02 561635.7696 1423612.0386 785.42 N/A 10.5 N/A N/A 05724301 VE03 561597.8544 1423617.7069 785.41 N/A 12.0 N/A N/A 05724301 VE04 561654.3003 1423576.2976 785.46 N/A 12.5 N/A N/A 05724302 VE05 561684.7491 1423590.9811 784.83 N/A 13.0 N/A 05724302 VE06 561728.0120 1423583.0234 785.19 N/A 11.5 N/A 05724302 VE07 561689.8509 1423654.3951 785.52 N/A 13.0 N/A N/A 05724301 NOTES: 1) N/A - Data Not Available. 2) * Missing as of 03/2005 3) **Abandoned September 2002 4) NGVD = National Geodetic Vertical Datum P: \ BP \ Projects \ Terrninals \ 4762 \ Reports \June 2009 \ Tables \ Table 1.xls \ T1 Page 4 of 4 ATTACHMENT H - MAPS Note that the attached Figures were submitted in previous reports and therefore may not be sequential. FIGURES Figure 1: Location Map Figure 2: Site Plan Figure 3: Location of Historical Releases Figure 3: Cross -Section Location Map Figure 4a: Cross -Section A -A' — Benzene Figure 4b: Cross -Section A -A' — MTBE Figure 4c: Cross -Section A -A' — Naphthalene Figure 5a: Cross -Section B'B' — Benzene Figure 5b: Cross -Section B'B' — MTBE Figure 5c: Cross -Section B'B' — Naphthalene Figure 7: Water Table Contour Map Figure 8: Benzene Isoconcentration Map Figure 9: Toluene Isoconcetration Map Figure 10: Ethylbenzne Isoconcetration Map Figure 11: Xylenes Isoconcetration Map Figure 12: MTBE Isoconcetration Map Figure 13: Naphthalene Isoconcetration Map Figure 19: Dissolved Oxygen Map Figure la: Proposed Injection Locations (and New Monitoring Wells) Figure: Generalized Monitoring Well Construction Diagram of Proposed Well(s) I; ••••,* •I -1 ,- • 111 f • ( A ••" _ • , • -- • -•••••i' j rk- • - •••:.• • „ "-- ; .;;2:-..;•, ••• I sm " • • !.•;•,,;;i i .--,-'•' V ''z.l. , "•:- -'1 ;; ' ••• . • • i• . 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ISLAND LAKE, NC - DATED 1993 ' FIGURE 1. LOCATION MAP BP/TRANSMONTAIGNE TERMINAL BP SITE NO. 4762/SOUTHEAST TERMINAL CHARLOTTE, NORTH CAROLINA Prepared for: BP PRODUCTS DRAWN BY: TSH URS U. foN111.1 CAOLIKA 275•6() DATE: 01MAR04 PROJECT NO. Fig. me t S21 li V '—'4LI. i 1 A I I ' 1 . I 1 n 1 ririr----4 '' i„. . I G ,G\ \ , I DWO6 ,),- , I • --r eEsia -, UW07 1 1. 42-40/4 DW10 ES41 0 MW-590 r Esio,, \ e ‘-,, \ -.,. -,..,„, -,,, i1 01 i 4 .,. „-,.R..,....4„ n .EW,P Sl1ru2it03„1,w8G 7•LSRf ESO8DR••I • ES13 tmuL4,pLE"g1'v4- w.i'vr•_-1L"-3n4_i 1I- I t LOADING W02c1 AGKES12 ',-'\1;-iliuw,5:uw01 S3ES2S ESO7a1 1l 0• ES15 1 j:73.1f 10 ; • -gEs' \'\Si_. 2 6. ' .' 11 4 I JUVOt64 f iI ''''1 E G G 4I• t. D4 WG; --t - O. 3I r Dwomuw06 $ i 7i1 I 428 MW6 1 Nqui VE03—ES03EsiT,ebioi 11\S040 •ES01 ESG0w MW48-Es38—•_ES02Q \\ L /VE05eV 10)T7C. - - ; l,M •W\ -5\3 fgM-i\, W „Igtt - 5\L,2, lEs171.iMW26VE04-W05-m43Thi71 i/ ,.'. '„. •&- 4 14,, • ES35 •ES31 ES430 • PMW07 I' - 4 ' . ( '';t:' I \ \\ \ i 'ESO5DRB ./ ESO5SR "1-------)MW51 I 1131 ''', '''' /II ES05 E----LESli1 • of_ 1ii____ "--://--;1_„/(-.„ .11 ,f fiE,S,066i01 ','N D-e W.r-.,-O,1, 5 - ...--5-7 MW•-5 5 7+_MW390uM!5 iwe ! Rg1 :.,... i •LiS4 ,,2„mwt s-et% .704r4• • mwoa ,mwo7 ) • liff,:,,,If \ \ - •11 1 \ 1-: C , •I . i ' ,1 „ - GN • 4\\,1- Yt/iPMWO8 N •MW-58 tS33 .mwai • mp0,0MF10 'E61,s32 PMWO2 I •DWO8 1DWO9• 1 8 1 ES30E.L - .-.„ eAS01 MPO6• • TO2A PMWD3 PMWO9 •• ts • MW3W 0 00 Former National Oil Terminal Property FtilW14R • L. IE I 3 1/ 1 1 4 4 i 4 • PMWO5 • — ' PMWO4 • PMW11 • PMW12 • DPVES Sump C,• owoi • UW07 ; 1 7 ES05 0 S3 0 50 150 Legend Treeline Fence Line Property Line — Railroad Dual Phase Vacuum Extraction System Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Monitoring Well Missing as of 03/05 Groundwater Monitoring Well Abandoned 05/05 SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESEFIVED-PROPERIT OF URS RDU, NORTH CMOUNA 27560 DRAWN BY TSH DATE 04DECO8 CHECKED BY BM DATE 04DECO8 Figure 2. Site Plan BP Terminal 4762/ Southeast Terminal Charlotte, North Carolina APPROVED BY MN DATE 04DECO8 CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-2 RD/. SS:ib 0 • 1 1326 11 ES4 , LANCT li 3 771.7-L • \ N r L n FSIC h'.7-1 --fINDC TIO4 I it, r•-.41 igk, j ,t-,----T- ...-.,,,• ,5r-1-_`,,.._,,;„1',''•N"n--------.--_--,.°-'--a,-7 ,, -,II Ji 7-! S., j:2V -''-D\t-.,-1-7-sV,_--'-W4-0-V-:-:-..-_ ,.._1-15.- 4-aM1 -V7T01' .Y1,3'- i-,E''-1 ,. 4,- —,'v:,• \ (--,' ;--F,_---°-,--,AI---''-W-------i---,A,_-- 6---_ t—_-- ---'- c'-.--'--'----1-:__, ' -_-._--" ,L,:„i 1.!'7 i,1 .,.-,-....- -":---.\ .-- \'- ,-....---r,:/ i< /;:3N ---- 7 I 1Y 110 -\- 04K ) \ \' \\..,-.,..‘- , ,... , V-,—,_---_-1 , _ 11 \\ (/ EL ) -CN- i) 4.,R 0' jf F43:10 Forme c National Oil Terminal Property o iU2A F.L'MP 0 [31-Art 0. I _Li cr P \PNO4 PMW 1 1 1101312 PMV/12 0 SUMP C C1 0 C) 50 150 Legend Groundwater Monitoring Well Sump Location of Release Incident (See Narrotive For Description) SCALE AS SHOWN DESIGNED BY DATE CONF1DENTIAL-ALL PICHTS RESERVED -PROPERTY OF URS NORM CAROLINA 27580 DRAWN BY TSH DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 3. Locations of Historical Terminal Releases BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 02JUL07 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-3 REV. c a c c C\ o , 0 ESO4O ES29 • ES0'1 ES07 • 1� 7 e. ES06 \ L) ®DWO5 ES20 / 0 VE07/ ' 4MW{2 RW03 V=MW20 #' 1�1W27�L?z `� '/ MW21 I i• VEJS ((�� S VE05 VE06L �/ ## i' • v• UW05 01 0 • • • • • • • DPVES EQUIPMENT ENCLOSURE • • • DWO1 • • • rf • MW41 MW47 • MW51 MW39 • 0P1,,V,V1-0\2 1:491An• ‘ •M:37171 ▪ MW5P`..„., • • ES26 • • Former Natibi-ial Oil Terminal Property 101 • 105 • MW-55 AS SHOWN • IXINRDENITAL—All IGGHTS RESERVED —PROPERTY OF MI al Legend Treeline Fence Line Property Line Sump Groundwater Monitoring Well Groundwater Monitoring Well Missing as of 03/05 Groundwater Monitoring Well Abandoned 05/05 Cross Section Location MW20 Well Boring Log Used to Create Geologic Cross Section A -A' (Projected onto Cross Section Line) DESIGNED BY DATE DRAWN BY DATE BA 09JUNO9 APPROVED BY DATE MN 09JUNO9 Well Boring Log Used to Create Geologic Cross Section B-B' (Projected onto Cross Section Line) 0 20 60 111 Figure 3. Cross Section Location Map BP Terminal 4762/ Southeast Terminal CONTRACT NO. DRAWING NO. 4762-3 REV. 0 • • • • 14 Q 790 770 J N 0 0 a 750 z 0 i= W -J 730 710 A O N W (769.11) PARKING LOT LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) BENZENE ISO —CONTOUR (Dashed where Infered) 0 O N w 0 O -um ■S i a� is M MiN MNga EN NIII ,Nal Sini �0. cs ai, II 00 3.113 ii NE 3111 EN MIE EN EA OM EN Eli MO El VII NO LW 13.3 iNM •11 MC EN am i ; a• SOIL DESCRIPTIONS Estimated USCS classification based on well boring logs ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay N 0 0 0 MULTIPLE PIPES ;� CONTAINMENT 1113 PIT FOR TANK ow :o\\\\ 111 lr \moo O N off. ‘.141/4 �`Sena i11o V%toV"+4 ♦ ♦.4 (7 ° - — :,_w♦ ♦��♦`♦♦♦♦♦ .♦ +♦ * S *** t44 4 k *A 6 A41 1 'W 4 SA," ♦ ♦�♦ ♦♦♦48 ♦ �� y ♦ 44"*. ..:** •4" \ ♦+ :fo s• `,sw#s ♦ ♦+ ♦♦♦♦ • • s % . v• • s 44, --. " A • 4♦♦40 =, •• Ae,„,",„ 44, Ay N N W A CONTAINMENT PIT FOR TANK 112 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE GONFlDENRAL-ALL RIGHTS RESERVED -PROPERTY OF URS RDD. NORTH CAROLINA 27560 DRAWN BY TS H 26DATE APR10 CHECKED BY MN 26DATE APR10 Figure 4a. Cross Section A —A' BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 26APR10 CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-4A REV. 0 790 770 J N a) O 0 u✓ 750 z O 1- W J W 730 710 A ♦♦ ♦♦♦♦ ♦�♦�p 4 i♦♦♦♦♦♦♦ O♦�♦♦ ♦4:4� • ' •♦♦'* *44# #8. • 44. *••• rs -.41;\ 44:1, • 40v4,1,.... • • 444 .00444. 44 ss" ♦♦♦♦%♦O♦♦O♦�� (769.11) PARKING LOT LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) MTBE ISO —CONTOUR (Dashed where Infered) ce O W O N CO N SOIL DESCRIPTIONS O Estimated USCS classification based on well boring logs ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay 0 0 CULTIPLE PIPE` 0 CO 0 CONTAINMENT PIT FOR TANK 111 N V) W A' CONTAINMENT PIT FOR TANK 112 0 50 OFWPThifRO HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS R6ERVED-PROPERIY OF 'URS RDU. NORIH CAROUNA 27560 DRAWN BY TS H 26DATE APR10 CHECKED BY MN 26DATE APR10 Figure 4b. Cross Section A —A' BP Terminal 4762/ Southeast Terminal APPROVED BY MN 26DATE APR10 CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-4B 790 770 730 710 A O V) w Vlitot PARKING ♦�♦ LOT 44.4 • +.8 S. ss 4073 it. *** . • +♦i♦4i♦''♦' A" 404 r • #.• • \\\\\\ \S‘. .\\\\‘ 11. (769.11) LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) ce 0 N O N w NAPHTHALENE ISO —CONTOUR (Dashed where Infered) Z ON HO m U ce = H LA ~ ~ w Z3 N (0 N N SOIL DESCRIPTIONS Estimated USCS based on well ML/SM — Sandy ML/CL — Clayey 0 classification boring logs Silt/Silty Sand Silt/Sandy Clay N 0 0 0 MULTIPLE PIPES 00 O CONTAINMENT PIT FOR TANK 111 N N w A CONTAINMENT PIT FOR TANK 112 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE CONFlDEMIAL ALL RIGHTS RESERVED -PROPERLY OF URS RDU, NORTH CAROHNA 27580 DRAWN BY TS H 26DATE APR10 CHECKED BY MN 26DATE APR10 Figure 4c. Cross Section A —A' BP Terminal 4762/ Southeast Terminal APPROVED BY MN 26DATE APR10 CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-4C REV. 0 800 780 L z 2 760 1- w J w 740 720 SOIL DESCRIPTIONS Estimated USCS classification based on well boring logs ML — SILT ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay M l M O 1, \ ,yy lee\\ � "116- B (769.11) LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) BENZENE ISO —CONTOUR (Dashed where Infered) 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED-PROPERIY OF URS RDU. NORTH CAROUNA 27560 DRAWN BY TS H DATE 26APR10 CHECKED BY BA DATE 26APR10 Figure 5a. Cross Section B—B' BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 26APR10 CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-5A REV. 0 J N a) O 0 L1 z 2 760 w J w MO as :S Se 7.i sa :c O■ 00 MO s: ■i NM ON ■0 %1 SOIL DESCRIPTIONS Estimated USCS based on well ML — SILT ML/SM — Sandy ML/CL — Clayey 0 N w H w IN\ N4 4 Oa_C►�C1III� ON 00 /, ..■� MO SI El MN WI IA 12 S.7 Di .\ e II B ,. �� OM W► MO In N00 am .• �t lag �an ni irA .N 1.1 SS KU MI Si VIM SO Mg MR ME ISM 11i; •I2 PM UM SS MS OM NM OS All 10611‘\all ON 00 NM NM EU i.WI INS OM � SS SS OS OR NM MO MS 00 EEO MNMC MN •01 TIC 4‘.1110 x\klii classification boring logs Silt/Silty Sand Silt/Sandy Clay AS SHOWN CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF RDU. NORTH CAROLINA 27580 DESIGNED BY DRAWN BY TS H CHECKED BY BA APPROVED BY MN LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) MTBE ISO —CONTOUR (Dashed where Infered) HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X DATE 26APR10 DATE 26APR10 DATE 26APR10 Figure 5b. Cross Section B—B' BP Terminal 4762/ Southeast Terminal CONTRACT NO. J3-00004762.01 DRAWING NO. FIG-5B • • C. CC 800 780 740 720 B O N w (0 N ce 0 lt') O N W ISS MS NO NZ SS le NS rs ►i as MIN SR ON 00 ■o izu. a r N• /Li MN GE NM SOIL DESCRIPTIONS Estimated USCS classification based on well boring logs ML — SILT ML/SM — Sandy Silt/Silty Sand ML/CL — Clayey Silt/Sandy Clay hib 00 X� ief ea ■1 NM INN o' MO Me I. 110. OM NN ON hu� NS aal minI ON iO ea ■7 MS LIE ON SS sS i© ii (o N 0 B (769.1 1) LEGEND GROUNDWATER LEVEL (DECEMBER 2009) MONITORING WELL WITH SCREEN INTERVAL GROUNDWATER ELEVATION (DECEMBER 2009) NAPHTHALENE ISO —CONTOUR (Dashed where Infered) 0 50 HORIZONTAL SCALE, ft. VERTICAL EXAGERATION = 5X SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF RDU. NORTH CAROUNA 27560 DRAWN BY TS H DATE 26APR1 0 CHECKED BY BA DATE 26APR10 Figure 5c. Cross Section B-9' BP Terminal 4762/ Southeast Terminal CONTRACT NO. APPROVED BY DATE MN 26APR10 J3-00004762.01 DRAWING NO. FIG-5C REV. 0 • Or CC 1I 1 Dw1D• (780.01) • CcvreBn E806D• II ES1 LNQ lK 780. 2 ES29 r--' • 1 780!17 ES07 / UW05 • TO • / 780.48! -ES15 •DP• 02 $ JMP ES40 774.42 772.02 E52 68.12 D 01A �UWO• J i 1 1 1 01•f ;•. VE07 UW1 D::I40' 01 •i I• • ', _4 �( E I I *MW12 780.96 i / 779.17 UW02 11__.� YE02 • SO E501 ES70 1r �. -;• al/ VEO ; 4S`ES 8 • •,.;I m771.2412 W21 i o i 1,77 81' t1 778.21 / -- / 779.42 VE04 _-,MW43 MW47 ES17 I ,!/�. %. MWZ6 • .. • • 15--_,• • 7,13 Ai'' ( �a 77831 p r I % / / / // ' ''ESOSDR••ESOSSR .__._,.. .;; / (.775.58) 774.65 ES71 / :LDS ENT C7 iRW02 3a� r .�MW50;' 772 98_ MW39 • M 45\ �_ IP.. ES18• -772-692 j -+__Z7272 MW41 I __ �772.34p -173'!-_ - 772.89 772.49 1 776.29 MyV08` ermeab React' e er W-5: )� • 766. = -/ • PMW01 E533- •760.74 •SLA P A \ • i u.'EW01 769,7 -55 8 MW07__ i, Farmer National 011 Terminal Property (757.14 •PMWD9 747.42 (763.84) M 56 S PAP B [BSI'.1PC • -,, I !i 111 %MW-53 a� PMW10 • MW-52 1 MW14R• I 750.58 8 ES25 \,$'`r49.74 PMWO5 • PMWD4 • PMW11 • PMW12 • 0 50 150 Legend = Treeline ----- Fence Line — — Property Line Railroad DPVES Dual Phase Vacuum Extraction System Fire Hydrant Lamp Post Protective Steel Bollard Power Pole SUMP C Sump 7MWOs2• Groundwater Monitoring Well With Water Table Elevation (ft) 750 — Water -Table Contour (ft) SCALE AS SHOWN DESIGNED BY DATE CONROENTL#L-ALL RIGHTS RESERVED -PROPERTY OF RDU, NORTH C4ROLINA 27580 DRAWN BY TSH DATE 17FEB1 0 CHECKED BY MN DATE 17FEB1 0 Figure 7. Water Table Contour Map, 12/8-9/09 BP Terminal 4762/ Southeast Terminal APPROVED ETY DATE CONTRACT N0. MN 17FEB10 J3-00004762.01 DRAWING NO- FIG-7 REV- 0 1 1 I \y I t jDWO6 1 ; `5 0 C.\\ ES1§fit, I DW10 j <0.1 • 0 MW-59• <0.1 •-- ram r. 1 • i. J j P Jz�o1 D' I I l (�. i • ES26 Lur I rRW03, • E§01 WIla in MW2741 3.0 Lr ,IMW2 1 0 80. • ;N \ `;�.` `` ES23•4. • ♦ `� ♦ r•` • ES35 520 MW-se. �'\10 • ES31 <0.1 1.0 1dao. (j ES33 II I!%<� ll IN f DW05 _ ES20 / •<00.1 , to - loon ritooa 8 00 ESO R ail A iD 1,10I 1.70 1.7___7ES11 • •MW 10 100 �1. w41 ES18•\ • MV -55 ----MVO? <0.1 / 1 D8 1 ID1 I Sc20 " ✓' S28 •IUW11--L.___..1 u I;I'\, - • D1NO2 f..1< 1. Ps I 8110J=1zz9D ----. -- _xVaw—/ll - =i; • , PMWDB 100 MW02 970 • DW08 <0.1 DV9• ••AS01 MD'O6 •PMW03 T <0.1 SUM PMW07 •\ DWO3 •<0.1 Permeable Reactive Barrier PMWO8 • PMW09 ♦ •<0.1 3 ft L MW-50 0 LAC' Former National Oil Terminal Property • MW52 • MW� <0.1 1.0 PMW1 0 • I/• 3t / lr PMWO5 • PMW01 • PMW11 • PMW12 • •-=#=1 0 50 150 Legend Treeli ne — Fence Line — — — — Property Line n DWO1 • 0.12J J Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Benzene Concentration (ug/I) Estimated Value uJ Not Detected and Detection Limit is Estimated Abandoned Monitoring Well 1 Benzene Isoconcentration Contour (ug/l) SCALE AS SHOWN DESIGNED BY DATE DONFI0ENRAL-ALL RI0I115 RESERVED -PROPERTY Or lintS RDU. NORBI CAROUNA 27560 DRAWN BY TSH DATE 17FEB 10 CHECKED BY MN DATE 17FEB 10 Figure 8. Benzene Isacancentration Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 17FEB10 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-8 REV. 0 I1, I DM ES14 • • 0.7 1 i <0DWW .1 • ES05DRESGit$?t)I i E•3 iC0+nfutu ` ; rwx •__.-_-.._._. UW05= 1 DPEW02'`. E029 E507 <0.1 • i --32J'-� j ,' e... i..?ulvo4s,` i OW=UWOR U 01A W1 i_ • I• !1 65 I l I i TO/1 bW01 i\ • i, ). i i} t ee • • I 3<2:0 f E628 l;� i i VE07 I UW02• • UW11 I _,; I � i MW12 1• VC031 'ESC3 l!E537 -- RVJO�.•�0%36J•• i • • {MW40' ES•3R. -• 1 • DW02 �`. i • ESIS• j ;I MWZJ MW21� 32Q2 r • r<O1 0.1 E517r l 0.30J' .MW20 ! M- VE04"MW05 •:MW47 • „'_ I `�rv9 /r 27 11 <�.1 MW431 j1Fi` _ i 1 i I' , i 'l.t_-�! \ i ',-._._ MW 1 I I�1 �. 0.0 5DR••3.SJ -' ; f `'� / -`2S71•,N42* I li ; - p ti• � I 100 M 444• •_<O.Y MW-65 OW05—.-._,�1 RWO2�W37 { •..0.1 I l 1! • MW5Or J I_-._- I -' -. j0• t MW30794 \ 05 __ E518•-.._.�...__! -_.-• {``�,•023J=t •69 30 13 °C----=6L 18-__ J4J.� W07_ Former National Oil Terminal Property ¶MW01 MW02 110 • • DW00 <0.1 • ••A501 M7O6 •PMW03 • f:l.. T0.02A1 MWS7 sW3w PMWO7 DW03 •<0.1 MW-56 . Permeable Reactive Barrier PMWO6 • PMW03 • <0.1 PMW10 • r 1 MW 52 • +s MW14R• 0-I 1.000 _• 1i 4,620 1' PMWC5 • PMWO4 • SCALE PMW11 • AS SHOWN PMWI2 • 0 50 150 DWO1 • 6.0J Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Toluene Concentration (ug/I) Estimated Value UJ Not Detected and Detection Limit is Estimated i Abandoned Monitoring Well -1,000- Toluene Isoconcentration Contour (ug/I) DESIGNED BY DATE DONFIDENRAL-ALL RIGHTS RESERYEO-PROPERLY OF URS ROIL NORTH CAROUNA 27560 DRAWN BY TSH DATE 17FEB 10 CHECKED BY MN DATE 17FEB10 Figure 9. Toluene lsoconc. Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 17FEB10 CONTRACT N0. J3-00004762.01 DRAMS N0. 4762-9 REV. 0 DWOO \ ES14 ,I <5 0 cA 31 • + DW10 • Eg08SF,! i I <0.1 • ESOSDF? _�fr ES13 CCUCP10 <0.5 WADING ( RACK ES12 ES41 MIN-59. <0.1 ! I 1 uw05I===- DPE▪ W02 II` \ <E529 ES071 <0.1 • ! )' 1 i• • / 1 f ,:1 i I- 11 i " UYV04•,- PCit T02 • -- l f ;� DWO1A'r_UW00 ' 1 J VE07• �' 1/ U1N10: a / it-1 1 ES28 - 'I L`/ 1 U 02• •UW11-- 1 '1 Ii 1;-' RWU3�r S10 • _ ES314 ES40 0.67 ES35 82 • E531 <0.1 i ). • Lfi MW27:-/ • 1MW4ti"__.. MSN211 ego'Tits 1,300 47 MW• 26 VE 4 "f�WD5--- • IB'. / 2.4 MW43I :,a, 36 lI I MW51y r/`. ES05SR —..— 380 J/ 'rat / 'E605DR•• 20 T�50 all `� / 2,6 - ES 51 D -I '--. . �1.2r� !— MW44+$ JJ 380_ I DWOS �} RW02 f�,VIW37 / _ �1 ES20���<0.1 !� i.MW39��,- M 4 •MW50��) i• 11 • 1,000,63 I ES18 MW36 MW41 t0 t. ij 850 ^-, 'r ,. • r ®'. •MW02 -MVV08 `}1 • ES26 <0:1 ES43• s. • MW-58 47 ES23 • 550\ • E533 910 •T DPEWD1•7 `,,ES32 '�<0.1 j } P WDS • ES30 EMWO1 MW42 190 • • OW08 <0-1 DW}09 • ---I 4fil ••AS01 MP06 •PMWO3 e TO2A <0.1 S03-; -- ..__ES37 •• DW02.:� _ A i4.1 ®c -_._. • MVVige -550 49- MW55 MWO7__ MW 57 ..__MW3W Former National Oil Terminal Property PMW07 • Permeable Reactive Barrier PMW08 • pMW09 • • <0.1 DWO3 •<0.1 1',, • W-56 1\ _Li /MW / MW52 • fr MW14R• <0.1 ---- ES2& 550 1# / i PMW10 • £I PMWD5 • PMW04 • PMW11 • PMW12 • 0 50 150 uJ DWO1 • 13.8J J uJ 550 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Ethylbenzene Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well Ethylbenzene Isocon cent ration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENOAL-ALL RIGHTS RESERVED -PROPERTY OF URS ROU, NORM CARDUIIA 275E0 DRAWN BY TSH DATE 17FEB10 CHECKED BY MN DATE 17FEB10 Figure 10. Ethylbenzene Isoconc. Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED 8Y MN DATE 17FEB10 CONTRACT N0. J3-00004762.01 DRAWING N0. 4762-10 REV. 0 Ec-4 4•;'' MW-590 <0.1 • / <0.1 E540 0.59 • (' ES430 E523•‘-‘1. 1 • 1ic11!7! \ .., 1 !II -2• 53: /0i/. r1 \ 4k /4MWaI15 S1303 --i, .r• \1i s,;,,,, , • PMW1O11R3mwcii r , • I . • , ..:,;',.... '' 9.31 /1 MW02 PMWO7 . 11 DPEWD r,/ I / 350 • ' \ e-6,0 i ! DW06 '1 ES14. 43 ''' . 'I 'I ia j.--,1•4, 1 \ .:' 44 1 D 9 r 1 • <ODW.1°8 1 ES29 ES07 ) 1/0 r!' , I 11 1 ES13 1,,cvEur,, DW1 ' / , •a RACK ES12 1 1 111------ UW054-4-1 ! DPEW02 'a ••••• ES06D =L.." OF.i f '' 1 •111l2.1:1/t?ly, PIPEa T,,,, ''' '2,-,--,,,,.. :,..,..7.,,,,--- ----- -'-- -,-Z,L71-111,__ __, i 1 , <0.1 • 1 ',OBER'', ; 111 • \ ' 1-.--r ?.c•I !.. I: 11 4 i I 1 .,_ _ _ ._ ,.._/;::,.....__:.,___,,.. vil Ili „.. i ' -''' ''; MI:1111(37A68P:M173 PIVW°8 IIPMWal •,..,.,069.311 1. , ' '''', c r 1 'I', r 11 TO.,062.1AL7'----,,,,,,,. 1 -..r.. • <o.i iyxo.1 • • .,_ 1 1 , tiroi'v),04`,•:.'--7-6.:__!,-7 i 7 ,--.-. ES15 4 44 444---c--I i c:-.- ! h' y...:3 4 UWA. i i . , , : , , . • <7.216 ----1:,! •\•- -•'- ES30 !!! ! „..--..„! 1c 11 11 • •13W<O°.31 c --.4--.-, 444-;•, i•-•-744:!...z.„, • •!`"1"4,-, • I •• I - si , ! TOwoi 1 \ DWD1A ,F41.1w0.5 1 ,..,,... !\, ,....:1,..4,IE,S28 __1!„) .,,,.\..),J.t,_..1 jivvI.- 02 _,!!!,,,!„_ , 11 - / c' \ -I , ,_.-- •_. , / 1 i f' • i \ 7 '--4 c--0. I c . I 1,' n.- Rwo3112,51 s,-,.---mw12/ ...,, 530 vEaa ,_. --- - - -. -.. , _ tiS a 3 ----- -1' 7.7 :- - - I. "T._ - - ' / . la • .,,,,,-,i, ___L yEpi..„4 „,,,d2 a( l;:tf2.0 iii 0 i Ni! VE02 3,900 ' ,ilk • IMW411-- •-- ' , 1 1 11 ' ==: I \,, 1-",,,T.c.,-_-_,-42: MW-57 • _...Ir. • r-, MW-66 4 // \ ' \ /,', \ ; / /MW-53 \ \\. / • 0 ,..,. v. . 1,: -- ES/ ) E91 0 114 /I- • 1, MW27--. .8 0 1 5,00 ) 1 \‘‘ 4, 1 1 I 7'N/ i 1.. /MW2 • VE04 -1165----• / 5.1 / MW" '-• 4.1 MW43! -1' ' N L.3.71 L ,--,. ,,,,,,,,,,, ,. \ - / , .,, 1 i _---1 ; 1E5171 c I.--1 1 - MW-52. 1",g 1 ,,,,3 t 1 ' --' Y ' '1 ;> ( ' i I 1 / 72 ' 97.31 — •••-' ) \ '''' / • c; ._1= --- _ . , \ 11,1/1 .4 .. \ / I l_ // ‘,..... i1 i 3 / I : C 171 .7,, / 'ES05DR0034ESa5SR 11I --- - - •--'7 1 ); ; '''')-' 1 ; v• • s".. ' / 1--V <,--, j / ,/ i i / 4.1 ,--- ---- ES110 153° 1 II 1------.2.------• - 'I- -"'• , "-----I 310 m MW4,1 t , / 7/7'. 1,p ---O3D429- .--":-1120.M4'71W3._5 034J . \ ,...,-- -MW•-„55z/ f1 E420/ S I B , / -0L'/ t '4---__•-/\/ -NC414I _ \ \ _rc_ •.3 -,/ 8,04MWO2MM7-4R..5,. 4-._My,',<0.111' 500„\3i ' 1 0° 'Il'ifSi?1:IiI ---_• Permeable Reactive Barrier • ES35 1.6J Former National Oil Terminal Property c") PMW10 12,000 / ; PMWO5 • PMVV01 • PMW11 PMW12 • 0 50 150 1•11•111 DWO1 • 0.1154 uJ xt — 530 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Xylenes Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well Xylenes lsoconcentration Contour (ug/l) SCALE AS SE-IOWN DESIGNED BY DATE CONFIDENDAL-ALL RIGHTS RESERVED -PROPERTY Or URS RDU, NORTH CAROUNA 275E0 DRAWN BY TSH DATE 17FEB10 CHECKED BY MN DATE 17FEB10 Figure 11. Xylenes Isoconc. Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 17FEB10 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-11 3 i o l MW-59j <0.1 i / ES19 N \ C '\ \ vv ) •E 4144. / 2,000 1 ,tt ESOSDf% t �J( I• GGVCRECJ AIUL1ml_V Il `7 I m4D )1I OIDINC ( J�F� — ?o i • !I1I • l uwas— ! OPEWO2 , i ! ES29 E507 ' 1.5 •• 1 it it 1/ If I i� Y �Pf i 0 •0.14J ES43• r, \\ I i 1 j � 1 !_ L. 1 ' [� I Al r-3. / 1 . -} VE07.�'U11U• _.._'-_...'.'1.4_ __ -T-..I RW031<--0: ES10• IL, MW27! - MW21 6655JJ E04 /MW2 • 1'-1 MW26 Mw45 1 �///)<0.5<0.1 , r / j1i 200 / (` {{// ES05SR f// �'ESOS 1 % 8 12 J 1EA1 • • ES15 'f`-- f U1N040s c OB DWD1A'• i 11 ImoI. ro1•. ,480J\ is UW02• •U VE03 • VEO2M 1,100- .' J MW43 Mg511 -`i 1,100 I MW42 1 I ''fF 1�(,—-�� E�52—D - -`_�3B �=-Y1�- __.�J'. -"�1 -_4M�W39/. •c0'��."1°'�i'+ '_' (, WM<136n VV p1 o3WW3•075 2I,dW5___/RW02 M55 ES_18• MW41 W > > • 0 • \\ se • ES35 <2.0 rl • \ / 54 • ES31 { • E526 it i �_`•\0.8 '' uwD8 1 ( . , '1 ilil l.__- Ili if . =a 4`\t \_\ ES23•r.„ 2,000; "'Mai g 'yIF ] o.3a1 MWO • 1 i ES33 •3.eDD I1 ES30 1 i • Ij • DWOB 1.1 • ••AS01 MP00 •PMWD3 PMWO6 PMWO9 • T32 • •s6 4.2 PMW07 Permeable Reactive Barrier 20 .1 • PMW0B DWO3 •68 SJL1r 3 • MW-50 �y t tiff. MW-53 I ES38t_,-•-'.--.-�__ ._ • 23 ."• +t2f 1 \ 2,000 ti Former National Oil Terminal Property -,yer In: MWL2 • ll M R• 4.1 01 J I# I, ES2li PMW10 • 3 i I 1 - / PMWDS • PMW04 • PMW11 • PMW12 • 0 50 150 Legend Treeline Fence Line Property Line 0 ' Cca DWO1 • 0.71J J UJ X -- 200 Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater MTBE Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Abandoned Monitoring Well MTBE Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE DONFIDENOAL--ALL RIGHTS RESERVED -PROPERTY OF URS ROLL NORTH CAROUNA 27560 DRAWN BY TSH DATE 17FEB10 CHECKED BY MN DATE 17FEB10 Figure 12. MTBE Isoconcentration Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED 6Y MN DATE 17FEB10 CONTRACT N0. J3-00004762.01 DRAWING N0. 4762-12 REV. 0 G it 21 /S i-- z ., S34 0.1 f 5,, it// )i \ 0 i MW-59• 0.47J r rr { ESOs"Rt.! I J I E 113! SOYD .iu.2L._ i� /I IccVEREf) LT�TEPIPEu '-'" ' AIU r I 1,74 10AGING---j--f " lt- FLACK_._ ES12 J I-.i t • \\ \\ __._.' 1UW05-- DPEW02 \ \ ES07 % ES29 ,<0.1 f• <0.1 • •T02 ! I J - f—' RWD ES10 frit • v.4 MW2 /MW2 /\ ESO50 R /% 6.9 •DWO5 Es2o-Lm.1 ES 8 • I_ ice••.- .""..r__--. �11 E815 • ES35 40 • ES31 0.441 ES43• 21 ~,‘. E523 • MW-5s 17 1J �� 533- •90D WD, _ •"1 210 E62 / 0.1 i .s l - / �a �J ES3O• .ti • PMWCB W09• c••AS01 MPOB • PMW63 • '�- TO2A �e 0.38J \. Permeable Reactive Barrier \'`yr '-� • �, �. MW01 \• \ • Dwos <0.1 PMW07 •\ DWO3 •<0.1 SUMP B • MW56 r,a MW-57 126 VEO4`fAW05 • jj ,S"'' • ES26 <0.1 1 01•?W01 i , ,-.-% ` 28 J-1• t I, 0E .31• E503" ES3I• • ! PMWO8 • PMWO9 • <0.1 ESOSSR 25 ` \ I \. SUMP r �, ES11 ! 460 �Z10121 izj `\ f f J1S `\ •400 MW42 1...._ ._ .__ ,�r.,t �--'� + �--� •' _� �•�._........ • MW-5▪ 5 M 4n4 fN• \\\� f ••tom J MW45 oMyy ,.l11-7-0,6.77'. �• v Y6� RWO2 I7 MI 3 0• MW41---- . r-• .38 • MW38 - MW49 •�':a-OrM u J \ ��--' o Q 5 Former National Oil Terminal Property PMWDS • PMWO4 • PMW11 • PMW12 • 0 50 150 <r Bump CE, DWO1 • 92.3 J uJ u X —21 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Naphthalene Concentration (ug/I) Estimated Value Not Detected and Detection Limit is Estimated Not Detected Due to Blank Contamination Abandoned Monitoring Well Naphthalene Isoconcentratlon Contour (ug/I) SCALE AS SHOWN DE5ICNE0 BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY Or URS ROU, NORM CAROUNA 275G0 DRAWN BY TSH DATE 17FEB10 CHECKED BY MN DATE 17FEB10 Figure 13. Naphthalene Isoconc. Map, December 2009 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 17FEB10 CONTRACT NO. J3-00004762.01 DRAWING NO. 4762-13 REV. 0 111 • ES31 7.64: � . ES08 � I , 7.77 ` ES08D{ f� j ES13 COVERED i �. �._ _. 11, j LOADING I f M�LTfPLE PIPES --�- III /� .! RACK �.=-i--�.. _ -- —=° 1._ r� , >_.._._._ iI ES29 ES07 ! 6. 50 • `''''''" '� y�_jrle 6 11f2 4: TAhIK , ,Q, 4.071• • -_ it ���ill ' I 1 I r3 ES15 i -, • ..!! �� I , �i _� !# f L.. e --/ '02 j # ( f r •� 0:05' it • ES26 I ( a I I �UW04/ 1,L i IF i II 2:93 ;. I I 1 r r� / /a I 11 % 1 I j i :` t DW01A [a UW06 If l r i ¢ �'} / i I 1 T01, ° ®W01 l �E 1 ; 1' I I I j i Ii0.44 �� ES28 �� ��� _ il VE07 I i { f J j( f • t + `� i ♦ 0.39 UW02 i...___ __l , ...._ II I -MWI2 E03 _ ES03 �' ___=- ,- -__�` I ' / I t - �� , i �- _ -__ - ES37 f • - - (� ,__._.-- 1.89 j i i• MW48� •_...•`� ` D1NO2 `\ j i 1 �I RW03 404 •+• ES38�--__ _ ...__.___ •4.97♦ _--...._._--_ES10 ,,�I • IVE02 i "'__,.`•_._£NIVI_.._ • I 1 1:.• 1MW27 W21 MW-57 I �' ._ � j • � 301 � �' I----Ij .57 0:09� � %� j ---_ � ___ ___--- (I (ES17 f N'� i �MW20 i • VE04-��M11V05 • ..°' • MW47�_ �� :_ - J _ __. . _ - // M W26 i- 1, 1.90. M W437 I a I _-- / ._ ___ ___.._. ^ -!-- a \ ' •// 0.19 ! ♦�` I I�w �_.� __ - = _ i 0//L( / `ti I --4 — ( TANK TANK . .rr/ t ESO5SR "'-----___.. 3 10; `4 ' ES05DRww " 0.45 I 106 / ` 0.46 i / / --(2 IK MW42 r------, .0•27 / _` M34 W 55 1 �� M�IV50� �� �¢ .. • ES20 ' 4 0 - � 9 48 • 45 1.76- �.,.��♦ _. �� t MW41 �,39..87�'.w�-.�__•29?66� 1 `I yt� 17 �- �—w� , 66 • 11 119 I 0_.4.4�At; � M 308..E MW07 'a �1 8:.. _� f u TANK 117 9• DWO61 •0 424i._� • DW10• j !_ / ♦..0.34 / �._ ES12 •DW05 _.. i/ I / 11 11' Ij ES30 • r, • DWO8 ••AS01 MPO6 • PMWO3 • ;``-, TO2A 1.70. I / ; TANK 11- TANK ji 104 SCALE DW 54 DWO3 • 2.23 SUMP B• MW-56 t� AS SHOWN St Legend Yw - Treeline - ' Fence Line Property Line 9,.1111p c� Sump DWO1• Groundwater Monitoring Well X Abandoned Monitoring Well DESIGN!D BY 0.44 Dissolved Oxygen (ug/L) (3.24) Dissolved Oxygen (ug/L) (Not Used for Delineation) DATE CONFlDENIIAL-ALL RIGHTS RESERVED -PROPERTY OF URS RDO. NORTH CAROIINA 27560 DRAWN BY TSH DATE 21JANO9 CHECKED BY MN DATE 21 JANO9 <1 mg/L Dissolved Oxygen Boundary (Approximate) 0 80 Figure 19. Dissolved Oxygen Map, December 2008 BP Terminal 4762/ Southeast Terminal APPROVED BY MN DATE 21JANO9 CONTRACT N0. J3-00004762.01 DRAWING N0. 4762-19 REV. 0 PI\BP\Pro_.Lects\Terminals\4762\CAD URS\Decerber 2009\Fiqure ES15 IJI t i 1'' • I. ES29 1• • �--10 • E S 1 4 1 I.�+ / Ii DW10 ES08Di ES 8 11 I� f • I #r «r. V i I ! ES13 !COVERED 7-~__~__ 1 .. :31-. —_ I iF jJ t LOADING f !. RACK I II irnn ' � I r ES12 I _._ ES07 2,000 f -) I1. I ESIO • ES01 ;t= • �— 1. / \} •DW05 ES20 Iil(<til� ES18 • ` \. UWO5L-I D. • • MW3 _..__ MW41 11 M. • ES30 o i Il� • i iItI li ff —�( i TAN p I Lit r s pp � II t K D Benzene Isoconcentration 1— �(_—_ ! L` �� 7 Contour (ug/I) JII �I ------�._.__..__ ES03`— lt- - .---= ==`= =-- _-_.,___ {L MTBE Isoconcentration _ • — .._..:-.__._ __ E§.37 / • DW-02 --! Contour (ugf) CC4G • _ MW-57 -.=MV1(47 IiLL Y 1 o_ i 1l ;_ [AN;< 101 • ES31 • ES26 REA 2 '\‘ TANK 1 •28 I.� 1.0 . . . ( A1.1( 117 c.11:117.11 , MW02 • 100 • DW 9• ••AS01 1 MP06 •PM • r(-,, -- • T02A ) • MW-55 .I TAN MW50° 1 200 TANK 10. SCALE AS SHOWN DESIGNED BY APPROVED BY MN DW01 • DATE Legend Property Line Groundwater Monitoring Well O Proposed Groundwater Monitoring Well Abandoned Monitoring Well DATE 14APR10 DATE 14APR10 Injection Location of Sulfate/Bromide 0 80 Fig. 1 a: Proposed Injection Locations for December 2009 BP Terminal 4762/ Southeast Terminal CONTRACT NO. DATE 14APR10 J3-00004762.01 DRAWING NO. FIGURE-1 A REV. 0 September 30, 2015 Mr. Edward Leach North Carolina Dept. of Environment & Natural Resources Div. of Waste Management - Underground Storage Tanks 610 East Center Avenue, Suite 301 Mooresville, NC 28115 RECEIVED/NCDENR/DWR OCT 12015 WORDS MOORESVILLE REGIONAL OFFICE RE: Semi -Annual Groundwater Monitoring and Remediation Report: June 2015 Marathon Charlotte East Terminal — Paw Creek (Formerly BP/Southeast Terminals No. 4762) 7401 Old Mount Holly Road, Charlotte, North Carolina Groundwater Incident Numbers 06771, 15159, 15618, 17002, 17263, 17264, and 20622 Dear Mr. Leach: Enclosed is one copy of the Semi -Annual Groundwater Monitoring and Remediation Report: June 2015, for the Marathon Petroleum Company, LP (MPC) bulk -fuel storage terminal (formerly BP/Southeast Terminals) in Charlotte, North Carolina. This semi-annual report includes methods and results of groundwater monitoring. The In -Situ Submerged Oxygen Curtain (ISOCTM) system has been removed from the site and is being replaced by a biosparge system. If you have any questions or would like any additional information, please do not hesitate to call the undersigned at (919) 461-1423. Sincerely, URS Corporation — North Carolina Margaret M. Ness, P.G. Project Manager Enclosure: Hard Copy and CD cc: Mark Ehrman, MPC (1 hard copy, 1 CD) Doug Hall, TransMontaigne (CD) Jim Sligh, TransMontaigne (2 hard copies, 1 CD) Aquifer Protection Section-UIC Staff, Raleigh (UIC Permit #WI0300106), 1636 Mail Service Road, Raleigh, NC 27699 �D,_WQ_`—"Aquifer Protection Section, Mooresville Regional Office, 610 E. Center Ave., Mooresville, NC 28115 URS project file 31829547 URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-461-1415 REPORT RECEIVED/NCDENR/DVVR OCT 1 ZUi5 MOORESVILLWQROS E REGIONAL OFFICE SEMI-ANNUAL GROUNDWATER MONITORING AND REMEDIATION REPORT: JUNE 2015 MARATHON CHARLOTTE EAST TERMINAL (FORMERLY BP/SOUTHEAST TERMINALS NO. 4762) 7401 OLD MOUNT HOLLY ROAD CHARLOTTE, NORTH CAROLINA NCDENR GROUNDWATER INCIDENT NUMBERS 06771, 15159, 15618, 17002, 17263, 17264, AND 20622 Prepared for: Marathon Petroleum Company, LP (MPC) 8902 Vincennes, Suite D Indianapolis, IN 46268 Attn: Mr. Mark Ehrman September 30, 2015 URS URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 Tel. 919.461.1100 URS Project 31829547 M MARATHON TITLE PAGE SEMI-ANNUAL GROUNDWATER MONITORING AND REMEDIATION REPORT: JUNE 2015 Marathon Charlotte East Terminal RECEIVED/NCDENR/DWR (Formerly BP/Southeast Terminals Noo 4762) 7401 Old Mount Holly Road O C T 12015 Charlotte, North Carolina NCDENR Groundwater Incident Numbers 0677WQROS RESVILLE REGIONAL OFFICE 15159, 15618, 17002, 17263, 17264, and 20622 Report Date: September 30, 2015 Responsible Party (RP): Marathon Petroleum Company, LP (MPC) 8902 Vincennes, Suite D Indianapolis, IN 46268 Direct: 317-871-7824 Attn: Mark W. Ehrman, P.E. RP Consultant: Project Manager: Registered Professional Supervision: TransMontaigne Product Services Inc. 200 Mansell Court East, Suite 600 Roswell, Georgia 30076 Attn: Mr. Jim Sligh URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, North Carolina 27560 919-461-1100 Margaret Ness, PG Margaret Ness, PG This Report was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my thorough inquiry of the person or persons who manage the investigation, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,. 4;i,and complete. CA .4:14140. is 2028 Margaret Ness, PG PVC se Date `a7.. r' fi 'Daoao4o'g ,,t sa 91342615 P: Jobs4\_Projects\Miarathon (Fmr BP 4782)1.5.0 Deliverables \5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.docx it — TABLE OF CONTENTS Section 1 Introduction 1-1 Section 2 Background 2-1 2.1 Site Location and Description 2-1 2.2 Site Topographic and Geologic/Hydrogeologic Setting 2-3 2.3 Site Monitoring Well Network 2-4 2.4 Summary of Light Non -Aqueous Phase Liquid Occurrence 2-4 2.5 Summary of Historical Site Release Incidents and Remediation Activities 2-5 2.5.1 Historical Site Release Incidents 2-5 2.5.2 Remediation Activities 2-6 2.6 In -Situ Submerged Oxygen Curtain System 2-7 Section 3 Semi -Annual Groundwater Sampling and Analysis 3-1 3.1 Groundwater Sampling and Analysis Methods 3-1 3.2 Groundwater Sampling and Analysis Results 3-1 3.3 Concentration Versus Time Trends 3-2 Section 4 Conclusions and Recommendations 4-1 4.1 Conclusions 4-1 4.2 Recommendations 4-1 Section 5 References 5-1 URSP:Wobs4\_Projects\Marathon (Fmr BP 4762)15.0 Deliverables\5.3 Reparts\June 20151Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 111 TABLE OF CONTENTS TABLES Table 1 Table 2 Table 3 Table 4 Table 5 FIGURES Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 Figure 8 Figure 9 Figure 10 Figure 11 Figure 12 Figure 13 Well Construction Details June 2015 Groundwater Elevation Data Semi -Annual Groundwater Sampling Plan Summary of Monitored Natural Attenuation Results Summary of Groundwater Results Compared to NC 2L Groundwater Quality Standards Location Map Site Plan Locations of Historical Terminal Releases Historical Remediation Activities Water -Table Contour Map, June 1-4, 2015 Benzene Isoconcentration Map, June 2015 Toluene Isoconcentration Map, June 2015 Ethylbenzene Isoconcentration Map, June 2015 Xylenes Isoconcentration Map, June 2015 MTBE Isoconcentration Map, June 2015 Naphthalene Isoconcentration Map, June 2015 1,2-Dichloroethane Isoconcentration Map, June 2015 Isopropyl Ether Isoconcentration Map, June 2015 APPENDICES Appendix A Appendix B Appendix C Appendix D Appendix E Summary of Historical Groundwater Elevation Data Laboratory Analytical Reports Summary of Historical Analytical Data Concentration Versus Time Trend Graphs Historical Isoconcentration Maps UPS P:1Jobs4\Projects\Marathon (Fmr BP 4762)\5.0 Deliverables15.3 Reports Juno 20151Charlotte Semi -Annual GWM and Remediation Report June 2015.docx iv RECEIVED/NCDENR/DWR OCT 12015 SECTIONONE wORns Introduction MOORESVILLE REGIONAL OFFICE On behalf of Marathon Petroleum Company, LP (MPC), URS Corporation — North Carolina (URS) presents this report of groundwater monitoring and remediation activities conducted between December 2014 and June 2015 at the facility located at 7401 Old Mount Holly Road in Charlotte, North Carolina (formerly a BP facility and formerly known as "Southeast Terminals"). On February 1, 2013, the facility was sold from BP Products of North America (BP) to MPC. The Site has been assigned groundwater Incident Nos. 06771, 15159, 15618, 17002, 17263, 17264, and 20622 by the North Carolina Department of Environment and Natural Resources (NCDENR) in response to various historical petroleum product release incidents at the facility. The Site priority ranking is currently 100B due to the presence of potable water -supply wells within a 1,500-foot radius of the Site. The following groundwater monitoring and remediation activities were completed at the Site during the first half of the 2015 reporting period: • Groundwater sampling and analysis of the typical semi-annual monitoring wells; • Abandonment of wells ASO1, DW08, DW09, MP-06, PMW01, PMW02, PMW03, PMW06, TO2A, and T02; • Removal of the ISOCTM system building in May 2015. URSP:llobs41_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables15.3 Reports June 20151Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 1 —1 J +f� J SECTIONTWO Background 2.1 SITE LOCATION AND DESCRIPTION Maps showing the Site location area and layout are provided as Figure 1 and Figure 2, respectively. The Site is located in the Paw Creek area of Charlotte, North Carolina, an area predominantly occupied by petroleum terminal and light industrial facilities. The facility occupies approximately 26 acres and is bordered by Old Mount Holly Road to the north, a bulk fuel terminal to the east, vacant property (former National Oil terminal) to the west, and undeveloped woods to the south. Railroad tracks operated by Piedmont and Northern Railroad are located directly south of the facility property, beyond which is situated a Duke Power transmission line right-of-way. The Site is a bulk petroleum distribution terminal that has been in operation since the 1940s and was formerly owned jointly by BP and TransMontaigne. From February 2006 until February 1, 2013, the facility was solely owned and operated by BP. On February 1, 2013, the facility was sold to MPC, who is the current owner and operator. The facility contains 19 bulk fuel storage aboveground storage tanks (ASTs) that are contained within earthen bermed areas and/or excavated areas with earthen cut -banks. The tank number, current fuel type, and capacity for the bulk fuel storage tanks are listed below. Note that 2015 AST construction activity is underway and tank inventory will be revised in future reporting. Bulk Fuel Storage Tank Inventory TANK NO. CURRENT STATUS FUEL TYPE CAPACITY (BBLS = Barrels) 101 Not in service. Empty - previously contained premium unleaded gasoline 17,600 102 Not in service. Empty - previously contained unleaded plus gasoline 14,000 103 Not in service. Empty - previously contained super unleaded gasoline 11,700 104 In service. Jet fuel 9,200 105 Not in service. Empty - previously contained tank condensate water 2,500 106 In service. Regular unleaded gasoline 29,500 107 In service. High -sulfur No. 2 fuel oil 51,000 108 In service. Regular unleaded gasoline 51,000 109 In service. Regular unleaded gasoline 63,943 110 In service. Regular unleaded gasoline 57,500 111 Not in service. Empty - previously contained low -sulfur diesel fuel 17,400 112 Not in service. Empty - previously contained kerosene 15,000 113 Not in service. Empty - previously contained regular unleaded gasoline 11,800 114 Not in service. Empty - previously contained diesel fuel 14,000 URSP:\Jobs4\ Projects\Marathon (Fmr BP 4782)\5.0 Deliverables\5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.dorx 2-1 SECTIONTWO Background TANK NO. CURRENT STATUS FUEL TYPE CAPACITY (BBLS = Barrels) 115 In service. 93 Octane premium unleaded gasoline 21,300 116 In service. Low -sulfur diesel fuel 32,800 117 In service. 93 Octane premium unleaded gasoline 26,000 118 In service. 93 Octane, low -sulfur, premium unleaded gasoline 25,250 119 In service. Low -sulfur diesel fuel 40,100 In addition to the bulk fuel storage tanks, the facility contains a terminal office building, miscellaneous storage and warehouse buildings, nine process ASTs, three underground storage tanks (USTs), a covered tanker truck loading rack, associated process piping, and underground piping associated with a decommissioned dual -phase vacuum extraction (DPVE) soil/groundwater remediation system which had operated at the facility and has since been removed. The tanker truck loading rack is located near the northern border of the facility, with access from Old Mount Holly Road. Six of the process ASTs, ranging in size from 180 to 8,000 gallons, contain fuel additives. Two 10,000-gallon ASTs contain petroleum contact water. One 2,000-gallon AST contains mixed ("slop") products. The USTs consist of one 1,000-gallon wastewater UST (located at the sump near tank 110), one 2,000-gallon used oil UST (located adjacent to two 10,000-gallon underground oil/water separators), and one 2,000-gallon vapor recovery unit (VRU) moisture separator UST. A total of seven USTs have been decommissioned at the terminal. The Site underwent a modification between September and December 2008 to include ethanol fuel storage, an expanded truck loading rack, and a driveway widening to accommodate the expansion. Fuel lines were added beginning late 2009. AST modifications is ongoing in 2015. The terminal is supplied with petroleum products from underground pipelines owned by Colonial Pipeline Company (Colonial) and Plantation Pipe Line Company (Plantation). Two 14-inch diameter feed lines from Colonial enter the facility below ground from the northwest corner. One 10-inch and one 12-inch feed line from Plantation enter the facility from the southwest corner. Two abandoned 14-inch underground pipelines enter the facility from the west side near the warehouse from the former National Oil terminal. These pipelines formerly supplied product to the former National Oil terminal via the MPC terminal product manifold. Onsite utilities primarily consist of aboveground process piping from the bulk storage tanks to the truck loading rack, overhead electrical and telephone services, underground low -voltage communication cables, stormwater drain lines, inactive DPVE system piping, and a septic system located south of the terminal office. The Charlotte -Mecklenburg Utility Department URSP: Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\Chadotte Semi -Annual GWM and Remediation Report June 2015.docx 2-2 SECTIONTWO Background (CMUD) supplies potable water service to the facility, Duke Power provides overhead electrical service to the facility, and Bell South provides overhead telephone service. The area surrounding the loading rack, office, warehouse, and motor truck shop is paved with concrete or asphalt. Grass areas exist on the north side of the property along Old Mount Holly Road. Tank berms, access roads to the tank areas, and the area between the tank areas and the office/loading rack area are graded with gravel. Stormwater from the bulk fuel storage tank basins is discharged to a ditch in the southern portion of the site under a facility National Pollutant Discharge Elimination System (NPDES) permit. Stormwater from the loading rack containment area is collected in a 10,000-gallon AST and treated/disposed offsite at licensed facilities. Tank bottom water is collected into tanker trucks and treated/disposed offsite at licensed facilities. In late 2014/early 2015 the site starting undergoing construction projects regarding ASTs piping and stormwater. Updated figures and tables will be provided in subsequent reports to reflect these changes. 2.2 SITE TOPOGRAPHIC AND GEOLOGIC/HYDROGEOLOGIC SETTING The facility is situated on the crest and slope of a hill centered on Old Mount Holly Road. Ground -surface elevations at the facility range from approximately 795 feet relative to mean sea level (msl) at the northern border of the facility adjacent to Old Mount Holly Road to approximately 740 feet msl at the southern border of the facility. South of Old Mount Holly Road, surface drainage is south toward Paw Creek. North of Old Mount Holly Road, surface drainage is north toward Long Creek. The Site is located in the Piedmont physiographic province, which is characterized by moderately level inter -stream areas separated by broad valleys. Bedrock in Charlotte, North Carolina is mapped within the Charlotte Belt lithologic division of the Piedmont, which includes mafic gneisses, amphibolites, metagabbros, and metavolcanic rocks. According to the Geologic Map of North Carolina (North Carolina Geological Survey, 1985), bedrock beneath the facility consists of metamorphosed quartz diorite or quartzite. Competent bedrock in the Piedmont province is typically overlain by variable thicknesses of saprolite and soil, collectively referred to as "overburden." Saprolite consists of rock that has been subject to chemical weathering, removing up to 60% of the rock mass by solution, but not affecting volume (Cleaves, 1974). Saprolite commonly retains relict structures from the parent bedrock. Thicknesses of the overburden in the Piedmont typically range from 10 to 75 feet, depending on rock composition and topographic setting (LeGrand, 2004). Based on Site boring logs, subsurface materials at the Site consist of soil and saprolite overburden, including silty/clayey sand, sandy clay/silt, and silt/clay, which overlie weathered URSP:\Jobs41_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 2-3 n SECTIONTWO Background and competent bedrock. Bedrock, meeting the description of metamorphosed quartz diorite referenced above, has been encountered in Site borings at depths ranging from approximately 10 to 40 feet below grade and elevations ranging from approximately 729 to 774 feet above msl. Groundwater in the Piedmont province occurs in the overburden under unconfined (i.e., water table) conditions and in the underlying bedrock under both unconfined and confined conditions. j Groundwater in the overburden occurs within pore spaces of the unconsolidated medium, including relict bedrock structures (e.g., fractures, foliations, etc.). Due to the typically fine- grained nature and low permeability of saprolite, the formation is not usually utilized for groundwater production. Groundwater in the underlying bedrock occurs along zones of secondary porosity, such as fractures, foliations, solution voids, etc. Most water -supply wells in the Piedmont are completed in bedrock with surface casings extending through the overburden. I 2.3 SITE MONITORING WELL NETWORK The locations of Site groundwater monitoring and remediation wells are shown on Figure 2. Site well construction details are listed in Table 1. The depths of Site monitoring and remediation wells range from 7 to 57 feet below ground surface (bgs). Site monitoring wells are completed in bedrock, weathered bedrock, or in saprolite and shallow overburden (i.e., water -table monitoring wells). In March 2015, the following wells were abandoned: ASO1, DW08, DW09, MP-06, PMW01, PMW02, PMW03, PMW06, T02A, and T02. These wells were located in an area of a proposed storm water pond. Replacement wells are to be installed in the 3rd quarter of 2015. 2.4 SUMMARY OF LIGHT NON -AQUEOUS PHASE LIQUID OCCURRENCE Historically, LNAPL was removed from the site and spotty occurrences were detected on the groundwater in only a few of the 60+ monitoring wells. The most recent notable occurrence of LNAPL occurred during the summer of 2013 at MW48. In June 2013, approximately 0.18 feet of LNAPL was detected as accumulating over a nine year period of time in monitoring well MW48. As a result of the LNAPL detection, URS implemented a program to remove the LNAPL with absorbent socks. When the absorbent became stained/saturated with LNAPL, it was removed from the well and properly disposed. Since increased monitoring began at MW48 in early 2014, measurable LNAPL was only detected twice; in January 2014 (0.03 ft) and May 2014 (0.02 ft). Prior to the June 2013 sampling event, LNAPL was last detected at monitoring well ES29 at 0.01 feet, during the December 2010 gauging event and prior to that, LNAPL was not measurable since 2005 (Appendix A). During the June 2015 sampling event, LNAPL was not visibly detected in well MW48. An absorbent sock was not replaced in well MW48. P:\Jobs4\_Projects\Marathon (Fmr BP 4762)15.0 Deliverables\5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.dooc 2-4 SECTIONTWO Background 2.5 SUMMARY OF HISTORICAL SITE RELEASE INCIDENTS AND REMEDIATION ACTIVITIES 2.5.1 Historical Site Release Incidents The following is a summary of Site release incidents as documented in historical Site documents. Reference numbers correspond to the locations shown on Figure 3. Summary of Site Release Incidents Reference No. Approximate Date Substance Released Amount of Release NCDENR Incident No. Description 1 Circa 1950 diesel fuel unknown -- tank overfill 2 Circa 1978 unknown unknown -- pipeline leak (1) 3 1979 kerosene 70,000 gallons (2) -- release from tank 4 1985 diesel, gasoline & kerosene unknown -- pipeline leak (3) 5 1985 & 1989 mixed products unknown -- pipeline leak 6 1991 unknown unknown -- product seeps in dike walls 7 1991 unknown unknown -- groundwater contamination discovered 8 1992 diesel unknown -- release from tank 119 9 1992 diesel unknown -- release from tank 119 10 circa 1994 unknown unknown -- pipeline leak (4) 11 1996 used oil unknown 17263/ 17624 1,000-gallon UST removal 12 1996 virgin oil unknown 550-gallon UST removal 13 1996 diesel unknown 8,000-gallon UST removal 14 Feb. 26, 1996 diesel unknown 15159 release from tank 111 15 May 1, 1996 diesel unknown 15618 product seeps in dike wall near tank 112 16a October 1992 unknown unknown 6771 groundwater contamination discovered 16b Jan. 2, 1999 unleaded gasoline 77,784 gallons (5) 17002/ 20622 release from tank 118 17 June 2002 unknown product unknown -- pipeline leak (6) 18 Dec. 17, 2003 heating oil 300 gallons -- release from tanker truck (7) (1) Product seep from abandoned Fina pipeline discovered in dike wall (2) 68,866 gallons were recovered (3) Lines owned and operated by Publix Oil (National Oil terminal) (4) Lines owned and operated by Phibro Company (5) 51,660 gallons were recovered (6) Lines owned and operated by Plantation Pipe Line Company (responsible party) (7) Tanker truck owned and operated by Curtis Oil Company (responsible party) -- No incident number issued URSP:Wobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.dou 2-5 SECTIONTWO Background 2.5.2 Remediation Activities The following is a summary of Site environmental remediation activities conducted in response to various historical facility product releases. Areas of Site remediation activities are shown on Figure 4. Soil Remediation • September 1991: unknown volume of soil excavated from the area north of tank 111. • September 1996: approximately 133 tons of soil excavated from former UST locations. • October 1996: approximately 7 tons of soil excavated from the area west of tank 111. • March 1997: approximately 24 tons of soil excavated from the area near tanks 117 and 118. • April 1998: unknown volume of soil excavated from the area north of tank 112 during installation of interceptor trench. • May 1998: approximately 312 tons of soil excavated from around tanks 111, 116, 117, 118, and 119. • January 1999: approximately 420 tons of soil excavated from area surrounding tanks 117 and 118. • January 2004: approximately 13 tons of soil excavated from ditches near tanks 117 and 118. • January 2005: approximately 120 tons of soil excavated from ditches near tanks 117 and 118. Groundwater Remediation • Pump and treat: approximately 4,882,088 gallons of groundwater processed between 1985 and 1994. • DPVE: approximately 472,135 gallons of groundwater processed between 1994 and July 2000. • Interceptor trench: approximately 217,867 gallons of groundwater processed between 1998 and 2005. • A groundwater permeable reactive barrier (PRB) was installed in February 2005. The PRB is filled with granular gypsum and organic topsoil and is designed to mitigate groundwater contaminant of concern (COC) concentrations, and prevent further URSP:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.dooz 2-6 SECTIONTWO Background downgradient migration of the groundwater COC plume through enhanced anaerobic biodegradation. • An ISOCTM was installed from October 31 to November 3, 2005 in the northwestern area of the terminal and operated through the end of 2014. • A biosparge system installation began June 1, 2015 with operations to begin in Fall 2015. LNAPL Recovery • Pump and treat: approximately 6,000 gallons of LNAPL recovered between 1993 and 1994. i • DPVE: approximately 500 gallons of LNAPL recovered between 1994 and July 2000. • LNAPL removal utilizing absorbent socks and/or hand -bailing, as appropriate (i.e., MW48). 2.6 IN -SITU SUBMERGED OXYGEN CURTAIN SYSTEM The ISOCTM device is a commercially available micro -porous oxygen diffusion system utilized to diffuse oxygen into groundwater without producing bubbles. The device is 1.6-inches in diameter and 15-inches long (about the size of a small submersible pump) and fits into 2-inch and larger diameter wells. Oxygen is delivered to the device from standard oxygen cylinders via 1/-inch diameter polyethylene tubing. The ISOCTM technology is specifically intended for use as a barrier remediation technology. The typical radius of influence ranges from approximately 20 to 30 feet for these ISOCTM devices. Following startup of the ISOCTM system in November 2005, groundwater dissolved oxygen (DO) concentrations have been measured in the ISOCTM wells and other surrounding monitoring wells on a routine basis. On December 2, 2014 three of the wells were found to be flooded and oxygen supply tubing was found to be damaged. In response, the system was shut down to allow for ISOCTM system building demolition to allow for the proposed biosparge/soil vapor extraction (SVE) system install scheduled for installation in 2015. The ISOCTM system building was removed in May 2015. A Corrective Action Plan (CAP) Addendum was submitted to NCDENR in June 2012 and approved July 19, 2012. The CAP proposed a biosparge system to address dissolved hydrocarbons. Installation began June 1, 2015. IMMS P:Wobs41_ProjectsWarathon (Fmr BP 4762)15.0 Deliverables15.3 Reports\June 20151Chadotte Semi -Annual GWM and Remediation Report June 2015.docx 2-7 SECTIONTHREE Semi -Annual Groundwater Sampling and Analysis 3.1 GROUNDWATER SAMPLING AND ANALYSIS METHODS Groundwater sampling activities were conducted on June 2-4, 2015. Over 60 monitoring wells were sampled according to the methods discussed below. Prior to collecting groundwater samples, depth to groundwater was measured in the Site monitoring wells utilizing an electric oil/water interface probe. Site groundwater elevation data are presented in Table 2. Measurable LNAPL was not detected in any monitoring wells during the June 2015 gauging event. Historical groundwater elevation data are presented as Appendix A. Following well gauging, groundwater samples were collected from the Site monitoring wells utilizing the purge/sample method described as follows: 1. Temperature, pH, DO, and specific conductance measurements were collected in - situ prior to purging activities. Two (2) wells, DW10 and ES26 were not sampled as construction material or equipment prohibited access. Well MW55 was under water and therefore not sampled. 2. Each monitoring well was purged of a minimum of three standing volumes of groundwater, or until dry, utilizing new, disposable bailers and nylon rope or a submersible pump and new poly tubing. New nitrile gloves were donned for each well and the submersible pump was decontaminated both prior to initial use and between monitoring wells to prevent cross -contamination. 3. Each groundwater sample was collected utilizing new, disposable bailers and nylon rope. The sample was immediately decanted into pre -preserved laboratory supplied containers and labeled with unique sample identifying information. Groundwater samples collected from the monitoring wells during the June 2015 sampling event were placed on ice in a cooler with temperature and trip blanks and submitted under standard chain of custody protocol to Accutest Laboratories Gulf Coast located in Scott, Louisiana (Accutest). The groundwater samples were analyzed for volatile organic compounds (VOCs), including benzene, toluene, ethylbenzene, total xylenes (BTEX), methyl tert-butyl ether (MTBE), 1-2 dichloroethane (1,2-DCA), isopropyl ether (IPE), and naphthalene utilizing SW- 846 Method 8260B, as shown on Table 3. Groundwater samples collected from well PMWO9 are analyzed for monitored natural attenuation (MNA) parameters according to Table 3. 3.2 GROUNDWATER SAMPLING AND ANALYSIS RESULTS URS validated analytical results from the June 2015 groundwater monitoring event at the Site. The data review was modeled after the USEPA Contract Laboratory Program (CLP) National Functional Guideline (NFG) for Superfund Organic Methods Data Review (USEPA, 2008) and URS• P:Jobs4\_Projecta\Marathon (Fmr BP 4762)\5.0 Deliverables15.3 Reports1June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.decx 3-1 SECTIONTHREE Semi -Annual Groundwater Sampling and Analysis USEPA CLP NFG for Inorganic Superfund Data Review (USEPA, 2010). Qualitative and quantitative limitations associated with the analytical results were determined based on the results of specific quality control (QC) criteria. Accuracy was determined from the review of spike recoveries. Precision was based on the evaluation of laboratory and field duplicate results. Representativeness was evaluated from the review of holding times and blank data. Sample results have been qualified based on the results of the data review process. Qualified data are valid and usable for their intended purpose. A copy of the data validation report is available upon request. Monitored natural attenuation parameters from select wells are presented in Table 4. A summary of analytical sample results from the June 2015 sampling event is presented in Table 5. Copies of the laboratory analytical data and chain of custody forms are provided as Appendix B. Historical analytical data are presented as Appendix C. A groundwater elevation contour map based on June 2015 Site data is provided as Figure 5. As shown on Figure 5, groundwater flow is generally to the south and generally consistent with historical flow direction. June 2015 groundwater isoconcentration contour maps for benzene, toluene, ethylbenzene, xylenes, MTBE, naphthalene, 1,2-DCA, and IPE are provided as Figures 6 through 13, respectively. Graphs of groundwater COC concentrations versus time for individual monitoring wells are presented as Appendix D. 3.3 CONCENTRATION VERSUS TIME TRENDS The concentration versus time trend plots, included as Appendix D, were divided into five areas for localized trend evaluation. The areas include: the truck loading rack area to the north, west side of site, the east side of the terminal, the interior (lower parking lot), and the central or downgradient portion of the Site. A map is included in Appendix D illustrating the wells and areas evaluated. Laboratory results for 1,2-DCA and IPE are not graphed, but discussed where relevant in this section, and included in Appendix C. Truck -Loading Rack Area • ES 13 COC concentrations have been decreasing with minor fluctuations since 2006. In June 2015, there were no exceedances of the NC 2L Standard. • Well ES 14 continues to show COC fluctuations with an overall decreasing trend. COC concentrations remain below the NC 2L Standards, except benzene. • ES29 (an upgradient well for the whole project site) COC concentrations remain below the NC 2L Standards. • DWO6 (the most upgradient bedrock screened well for the site) continues to indicate the presence of MTBE above the NC 2L Standard; however, the overall trend is P:Vobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 20151Chadotte Semi -Annual GWM and Remediation Report June 2015.docx 3-2 SECTIONTHREE Semi -Annual Groundwater Sampling and Analysis decreasing. The remaining COCs are below their respective NC 2L Standards. Refer to Appendix C as DWO6 was not graphed. West Side of Site • After decreasing COC trends since the December 2013 sampling event for well MW02, all COC concentrations increased in June 2015. Benzene and MTBE concentrations were present in exceedance of their respective NC 2L Standards. • All COC concentrations in MWO8 remain below the NC 2L Standards. • Well MW19 continues to show COC fluctuations with an overall decreasing trend. MTBE, benzene and naphthalene concentrations were present in exceedance of their respective NC 2L Standard. • Well MW36 continues to show COC fluctuations with an overall decreasing trend. During the June 2015 sampling event, benzene, MTBE, and naphthalene concentrations were still present in exceedance of their respective NC 2L Standards. • Well MW39 continues to show COC fluctuations with an overall decreasing trend. During the June 2015 sampling event, benzene was detected at a concentration above the NC2L Standard. • Well MW41 continues to exhibit fluctuations in COC concentrations with benzene and naphthalene remaining above their respective NC 2L Standards. The overall COC concentration trends are decreasing. Interior Wells (lower parking lot and office building area) • Well UW08 continues to indicate the presence of benzene, naphthalene and MTBE, well above their respected NC2L Standards. • Well MW51 has generally exhibited an overall stable and decreasing trend in COC concentrations, historically. Concentrations of benzene, MTBE, naphthalene, and 1,2-DCA remain well above their respected NC 2L Standards. • Well MW21 continues to indicate the presence of benzene, ethylbenzene, xylenes, MTBE, and naphthalene above their respected NC 2L Standards, although COC concentrations remain relatively stable since 2005. East Side of the Site • ES33, located up gradient of the groundwater permeable reactive barrier (PRB), located just south of ASTs 116 and 117, has exhibited overall decreasing trends of COCs since the mid-1990s. Concentrations of benzene, xylenes, MTBE, and naphthalene remain above their respected NC 2L Standards. URSP:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables15.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 3-3 5 SECTIONTHREE Semi -Annual Groundwater Sampling and Analysis • ES34 is the monitoring well located farthest north on the east site of the site and is considered an upgradient well. Concentrations detected from this well are likely from an off -site source. The overall trends of the COCs detected in the groundwater from this well are decreasing and have remained below the NC 2L Standards for years. • ES35 continues to show COC fluctuations with an overall decreasing trend since 1998. Refer to Appendix C as ES35 was not graphed. • PMW09, the southernmost sampled monitoring well located down gradient of the groundwater PRB, continued to exhibit concentrations below the NC 2L Standards for all COCs. Central / Downgradient Portion of the Site • MTBE concentrations in DWO2 continue to exhibit an increasing trend since 2008, which exceeds the NC 2L Standard. The elevated concentrations of MTBE in well DWO2 are believed to be associated with elevated MTBE concentrations in the upgradient ES28 area that started out at 1,000 µg/L in 1996 and steadily decreased to 160 µg/L in 2014 (Appendix C and Figure 10). Concentrations of benzene continue to increase. • From 1998 to 2015 concentrations of MTBE have consistently been in the range of about 50 to 100 µg/L in DW03; above the NC 2L Standard. The COC 1,2-DCA (Appendix C) has consistently been quantified slightly over the NC 2L standard (0.4 µg/L) ranging from <0.34 to 1.8 µg/L over the last decade. The remaining COCs are below below the laboratory method detection limits. • All COC concentrations in ES38 remain below the NC 2L Standards. A second form of time trend evaluation is illustrated in the side -by -side comparison of historical isoconcentration contour maps from the past five sampling events for benzene, MTBE, naphthalene and 1,2-DCA included in Appendix E to visually aid in identifying the movement and/or stabilization of the plumes. The following observations are presented: Benzene Plume • The Tank 118 plume located to the east side of the site remains similar to previous sampling events. • The plume in the northwestern portion of the site appears similar in size to previous sampling events. MTBE Plume URSP:\Jobs4V_Projects\Marathon (Fmr BP 4752)\5.0 Deliverables\5.3 ReportsUune 20151Chadotte Semi -Annual GWM and Remediation Report June 2015.docx 3-4 SECTIONTHREE Semi -Annual Groundwater Sampling and Analysis • There is no significant change in the size of the Tank 118 plume located to the east side of the site since December 2000. Contouring in June 2013 reflects the current MTBE NC 2L Standard of 20 µg/L and additional wells sampled (i.e. PMW01). Prior to 2010, PMW01 remained below the MTBE NC 2L Standard of 200 µg/L. • The northwestern plume, as depicted in Appendix E, on Figure 2-MTBE, and historical MTBE concentrations tabulated in Appendix C, indicate little change in plume size or distribution since the 1990s. • The plume near the truck loading rack has remained stable in size and associated concentrations appear to be fluctuating with an overall decreasing trend especially at DWO6 (site up gradient well; Appendix C). For example, MTBE was quantified at 11,000 µg/L in 1998 and has steadily decreased to 383 µg/L in 2015. Naphthalene Plume • The Tank 118 area naphthalene plume remained comparable to the past four sampling events. • Naphthalene concentrations at the northeastern property boundary in the vicinity of ES40 continues to exceed the NC 2L. However, this well is located at the extreme northeast corner of the site in an up gradient position inferring impacts are likely from an off -site source. 1,2-DCA Plume • The NC 2L Standard for 1,2-DCA is very low at 0.4 µg/L; therefore, the plume shape easily changes based on seasonal fluctuations. With that being said, the 1,2- DCA plumes on the MPC property have been consistently in the same areas for many years. URSP:\Jobs4\ Projects\Marathan (Fmr BP 4762)15.0 Deliverables15.3 Reports\June 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 3-5 SECTIONFOUR Conclusions and Recommendations 4.1 CONCLUSIONS • Groundwater flow across the Site is generally toward the south, which is generally consistent with historical data. • In general, groundwater COC distributions across the site indicate that COCs have fluctuated slightly during the recent groundwater monitoring events, with a decreasing trend over the years. • The ISOCTM interim groundwater treatment system was damaged and turned off in December 2014 and permanently removed in May 2015. • A biosparge system installation began in June 2015 with operations expected to begin in Fall 2015. • Due to construction, monitoring wells located in the southeast portion of the site were removed. Replacement wells are being installed in Fall 2015. 4.2 RECOMMENDATIONS URS recommends continued semi-annual groundwater monitoring. The next sampling event will occur in December 2015 and will follow the proposed sampling plan as outlined in Table 3. A system installation summary and revised figures and tables will be included in future reporting. URSP:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.O Deliverables\5.3 Reports\une 2015\Charlotte Semi -Annual GWM and Remediation Report June 2015.docx 4-1 SECTIONFIVE References North Carolina Geological Survey, 1985, Geologic Map of North Carolina: 1:500,000. Cleaves, E. T., 1974, Petrologic and Chemical Investigation of Chemical Weathering in Mafic Rocks, Eastern Piedmont of Maryland: Maryland Geological Survey, Report of Investigation, v. 25, 28 p. LeGrand, H.E., 2004, A Master Conceptual Model for Hydrogeological Site Characterization in the Piedmont and Mountain Region of North Carolina, North Carolina Department of Environment and Natural Resources Division of Water Quality, Groundwater Section. USEPA, 2008 and USEPA, 2010, USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review and USEPA CLP NFG Inorganic Superfund Data Review. P:Wobs4\_Projects\Marathon (Fmr BP 4762)15.0 Deliverables15.3 ReportsUJune 20151Charlotte Semi -Annual GWM and Remediation Report June 2015.docz 5-1 Tables Table 1 Well Construction Details Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) Easting (Feet) Top -of - Casing Elevation (Feet Realtive to NGVD) Screen Interval (Feet Below Ground) Total Depth (Feet Below Ground) Approximate Date Installed Geologic Zone Monitored Parcel Number AS01 561143.0063 1423896.4106 759.69 13.0 - 15.5 15.5 06/02 N/A 05724302 AS02 N/A N/A 784.98 23.5 - 25.0 25.0 06/02 05724302 ASO4 N/A N/A 785.36 34.0 - 39.0 39.0 08/10 AS05 N/A N/A 785.45 34.0 - 39.0 39.0 08/10 AS06 N/A N/A 780.66 22.0 - 27.0 27.0 08/10 DPEW01 561296.8174 1423986.6534 763.19 3.0 - 10.5 10.5 09/97 N/A 05724301 DPEW02 561602.7889 1423835.0786 781.18 4.0 - 14.0 14.0 09/97 N/A 05724301 DW01 561586.0405 1423656.5762 784.12 52.0 - 57.0 57.0 05/92 Bedrock 05724301 DW01A 561582.9012 1423696.9568 782.50 14.0 - 19.0 19.0 N/A N/A 05724301 DW02 561352.6126 1423618.9074 776.17 24.0 - 29.0 29.0 05/92 Bedrock 05724301 DW03 561092.3516 1423700.3608 762.28 45.0 - 50.0 50.0 05/92 Bedrock 05724301 DW04 561216.8708 1423328.0896 769.29 4.5 - 9.5 9.5 N/A 05724302 DW05 561844.7793 1423435.7268 786.60 49.0 - 54.0 54.0 N/A N/A 05724302 DW06 561840.6986 1423913.5373 791.69 41.0 - 46.0 46.0 N/A N/A 05724301 DWO8 561115.2978 1423948.3161 759.86 37.5 - 42.5 42.5 04/97 Bedrock 05724302 DW09 561152.7624 1423909.4264 760.09 44.0 - 49.0 49.0 12/99 Bedrock 05724302 DW10 561828.5249 1423892.8305 N/A N/A N/A N/A N/A N/A ES01 561872.3080 1423594.5933 791.38 18.0 - 28.0 28.0 01/93 Weathered Granite 05724302 ES02 561225.4682 1423602.1330 770.32 4.0 - 44.0 44.0 03/93 05724301 ES03 561467.3861 1423617.7245 781.26 8.0 - 23.0 23.0 03/93 Saprolite 05724301 ESO4 561892.5678 1423594.9569 791.79 16.0 - 46.0 46.0 03/93 05724302 ES05 561733.8004 1423495.1581 785.77 10.0 - 45.0 45.0 03/93 05724302 ES05SR 561726.1502 1423501.7299 786.67 10.0 - 30.0 30.0 05/05 Saprolite 05724302 ES05DR 561735.4533 1423502.7228 786.79 45.0 - 55.0 55.0 05/05 Bedrock 05724302 ES06 561873.1015 1423452.3497 789.94 5.0 - 40.0 40.0 03/93 05724302 ES07 561852.3894 1423797.3489 791.23 2.0 - 22.0 22.0 03/93 Saprolite 05724301 ES08 561680.6126 1423873.7317 790.56 10.0 - 35.0 35.0 03/93 05724301 ES08SR" 561673.2505 1423883.6821 792.83 10.0 - 25.0 25.0 05/05 N/A N/A ES08DR" 561685.6809 1423883.9346 792.70 47.0 - 57.0 57.0 05/05 N/A N/A ES09 561621.2498 1423841.3317 788.04 5.0 - 45.0 45.0 03/93 05724301 ES10 561795.5151 1423598.5891 791.36 3.5 - 21.0 21.0 03/93 Sandy Clay 05724302 ES11 561641.1089 1423484.5621 785.33 5.0 - 25.0 25.0 08/93 Silty Clay 05724302 ES12 561755.9851 1423826.6505 791.76 7.0 - 22.0 22.0 08/93 Saprolite 05724301 ES13 561824.1833 1423875.9617 791.83 5.0 - 25.0 25.0 08/93 Clayey Sand 05724301 ES14 561691.2600 1423926.5230 790.70 3.0 - 23.0 23.0 08/93 Silty Clay 05724301 ES15 561723.2821 1423769.0074 790.25 8.0 - 18.0 18.0 N/A N/A 05724301 ES16 561641.5922 1423982.1524 790.25 5.0 - 25.0 25.0 01/94 05724301 ES17 561938.0508 1423551.3382 791.47 5.0 - 20.0 20.0 01/94 Silty Clay 05724302 ES18 561737.3383 1423401.7600 786.31 4.0 - 14.0 14.0 01/94 Silty Clay 05724302 ES19** 561739.5557 1424051.3416 795.13 6.0 - 26.0 26.0 01/94 Silty Clay 05724301 ES20 561902.7571 1423416.4770 787.36 6.0 - 21.0 21.0 N/A Silty Clay 05724302 ES21 * 561807.7732 1424136.5114 792.59 5.0 - 15.0 15.0 02/94 N/A 05724301 ES22 N/A N/A N/A N/A N/A N/A ES23 561245.9817 1424171.6421 764.38 4.0 - 9.0 9.0 N/A N/A 05724301 ES24 N/A N/A N/A N/A N/A N/A ES25 560892.4859 1423292.5796 754.69 N/A 24.0 N/A N/A 05724302 ES26 561460.6103 1423752.7862 777.81 29.0 - 39.0 39.0 05/96 Saprolite 05724301 ES28 561440.0360 1423683.4472 774.01 12.0 - 22.0 22.0 05/96 Saprolite 05724301 P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 1 - Well Constr Data.xls\T1 Page 1 of 4 Table 1 Well Construction Details Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) Easting (Feet) Top -of - Casing Elevation (Feet Realtive to NGVD) Screen Interval (Feet Below Ground) Total Depth (Feet Below Ground) Approximate Date Installed Geologic Zone Monitored Parcel Number ES29 561875.0050 1423798.4872 791.37 N/A 25.0 N/A N/A 05724301 ES30 561289.7215 1423767.9827 768.21 5.0 - 15.0 15.0 N/A N/A 05724301 ES31 561463.4581 1423920.8296 779.22 6.0 - 16.0 16.0 N/A N/A 05724301 ES32 561225.0002 1423996.5307 762.94 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES33 561288.4598 1424006.1705 763.33 4.0 - 14.0 14.0 10/96 Silty Sand 05724301 ES34 561510.6321 1424372.9606 777.18 2.5 - 12.5 12.5 10/96 Silty Sand 05724301 ES35 561494.7313 1424106.5233 774.74 2.5 - 15.0 15.0 10/96 Silty Sand - Saprolite 05724301 ES36* 561568.9915 1423805.4128 782.83 15.0 - 25.0 25.0 10/96 N/A 05724301 ES37 561396.2246 1423611.6336 777.88 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES38 561503.0391 1423621.9763 782.60 5.0 - 15.0 15.0 02/97 Saprolite 05724301 ES39 561565.2874 1424118.7755 781.88 4.0 - 9.0 9.0 02/97 Sandy Clay 05724301 ES40 561449.2345 1424347.7368 779.47 1.0 - 11.0 11.0 02/97 Sandy Clay 05724301 ES41 561569.1222 1424343.6774 784.60 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES42 561364.3171 1424047.1854 774.77 2.0 - 12.0 12.0 02/97 Silty Sand - Saprolite 05724301 ES43 561358.1419 1424262.8673 777.18 8.0 - 18.0 18.0 02/97 Silty Sand - Saprolite 05724301 ES44 561604.1033 1424189.8355 790.22 8.0 - 18.0 18.0 04/97 Silty Sand 05724301 MP01 561288.8127 1423998.0869 763.10 2.5 - 12.5 12.5 09/97 05724301 MP02 561301.5317 1423976.0820 763.19 3.0 - 13.0 13.0 09/97 05724301 MPO3 561300.1281 1423989.2201 763.10 2.0 - 12.0 12.0 09/97 05724301 MP04* 561603.9098 1423830.9426 781.28 1.5 - 14.0 14.0 09/97 N/A 05724301 MP05 561578.0162 1423828.7206 779.96 2.0 - 14.5 14.5 09/97 05724301 MP06 561151.4182 1423889.8832 759.42 2.5 - 12.5 12.5 06/02 N/A 05724302 MW01 N/A N/A N/A N/A N/A 01/85 MW02 561487.2640 1423357.7902 781.37 5.5 - 25.0 25.0 01/85 Silty Sand - Weathered Bedrock 05724302 MW03W 561207.3791 1423326.9060 769.21 N/A 12.0 N/A N/A 05724302 MW04 N/A N/A N/A 3.6 - 18.0 18.0 10/84 MW04R 560935.1424 1423590.1046 754.94 2.0 - 11.0 11.0 02/98 Saprolite 05724302 MW05 561625.8587 1423574.6324 786.65 4.0 - 14.0 14.0 01/85 Silty Sand 05724302 MW06 N/A N/A N/A 4.0 - 9.0 9.0 10/84 MW06R 560933.5686 1423672.4778 755.29 2.0 - 7.0 7.0 02/98 Saprolite 05724302 MW07 561354.2347 1423341.1936 774.36 2.0 - 19.5 19.5 03/85 Saprolite 05724302 MW08 561427.0882 1423348.3463 777.69 2.0 - 12.0 12.0 03/85 Saprolite 05724302 MW09 561546.8653 1423389.3473 784.65 5.0 - 20.0 20.0 03/85 05724302 MW10 561224.7864 1423594.3738 N/A N/A N/A 03/85 MW11 N/A N/A N/A N/A N/A 03/85 MW12 561719.8840 1423618.9475 786.16 1.0 - 21.0 21.0 03/85 Saprolite 05724301 MW13 561676.7002 1423472.4878 N/A N/A N/A 03/85 MW14 N/A N/A N/A 1.0 - 15.6 15.7 02/85 MW14R 560891.2195 1423346.8273 756.41 2.5 - 15.0 15.0 02/98 Saprolite 05724302 MW15 N/A N/A N/A N/A N/A 03/85 MW16 561747.3621 1423577.1715 787.27 2.0 - 16.0 16.0 10/85 Saprolite 05724302 MW17 N/A N/A N/A N/A N/A 10/85 MW18" N/A N/A 780.90 2.5 - 22.5 22.5 10/85 MW19 561514.7100 1423363.7049 782.64 2.0 - 21.0 21.0 10/85 Saprolite 05724302 MW20 561703.5305 1423608.1548 787.34 10.0 - 25.0 25.0 10/85 Saprolite 05724302 MW21 561675.2283 1423607.2603 785.76 6.0 - 20.0 20.0 10/85 Saprolite 05724302 P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 1- Well Constr Data.xls\T1 Page 2 of 4 Table 1 Well Construction Details Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) Easting (Feet) Top -of - Casing Elevation (Feet Realtive to NGVD) Screen Interval (Feet Below Ground) Total Depth (Feet Below Ground) Approximate Date Installed Geologic Zone Monitored Parcel Number MW22 N/A N/A N/A N/A N/A 10/85 MW23 N/A N/A N/A N/A N/A 10/85 MW24 N/A N/A N/A N/A N/A 10/85 MW25 N/A N/A N/A N/A N/A 10/85 MW26 561705.2878 1423572.6623 785.38 5.0 - 20.0 20.0 10/85 Saprolite 05724302 MW27 561726.9164 1423606.3704 786.93 4.0 - 14.0 14.0 10/85 Saprolite 05724302 MW28 N/A N/A N/A 3.5 - 23.5 23.5 12/85 MW29 N/A N/A N/A 3.7 - 17.7 20.0 12/85 MW30 N/A N/A N/A 4.4 - 19.4 20.0 12/85 MW31 N/A N/A N/A 4.2 - 19.2 20.0 12/85 MW32 N/A N/A N/A 2.1 - 22.1 24.0 12/85 MW33 N/A N/A N/A 4.6 - 19.6 20.0 12/85 MW34 N/A N/A N/A 3.8 - 18.8 19.0 12/85 MW35 N/A N/A N/A 4.0 - 19.0 19.0 12/85 MW36 561526.4378 1423389.4123 785.94 5.0 - 25.0 25.0 12/85 Sandy Silt - Silty Sand 05724302 MW37 561566.9736 1423430.5503 785.17 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW38 561582.4723 1423394.7559 785.54 5.0 - 25.0 25.0 12/85 Sandy Clayey Silt 05724302 MW39 561609.9127 1423420.9725 785.28 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW40 561644.0901 1423444.7051 N/A 4.0 - 24.0 24.0 12/85 MW41 561637.3588 1423398.8937 785.64 5.0 - 25.0 25.0 12/85 Sandy Silt 05724302 MW42 561606.8920 1423477.4229 785.95 5.0 - 25.0 25.0 12/85 Silty Sand 05724302 MW43 561572.0617 1423568.5897 788.36 4.0 - 24.0 24.0 12/85 Silty Sand 05724302 MW44 561573.8919 1423463.5270 785.77 3.5 - 26.0 26.0 12/85 Sandy Silt 05724302 MW45 561539.1703 1423432.3766 786.91 3.0 - 28.0 28.0 12/85 Sandy Silt 05724302 MW46 N/A N/A N/A 6.3 - 16.3 16.5 01/86 MW47 561546.0782 1423573.4010 788.05 7.0 - 17.0 17.0 01/86 Sandy Clayey Silt 05724302 MW48 561560.3416 1423606.0845 788.19 2.5 - 15.0 15.0 01/86 Sandy Silt 05724301 MW49 561553.2264 1423361.8991 784.17 5.0 - 19.5 19.5 01/86 Sandy Silt 05724302 MW50 561511.9326 1423433.2840 783.50 5.0 - 25.0 25.0 02/86 Sandy Clayey Silt 05724302 MW51 561576.7167 1423524.7096 786.41 8.0 - 18.0 18.0 12/86 Clayey Sandy Silt 05724302 MW52 560869.4058 1423546.3673 N/A N/A N/A 10/86 MW53 560932.7862 1423655.7433 N/A N/A N/A 10/86 MW54 N/A N/A N/A N/A N/A 10/86 MW55 561350.9150 1423466.1091 N/A N/A N/A 10/86 MW56 561092.9604 1423666.9997 N/A N/A N/A 10/86 MW57 561191.1414 1423606.5747 N/A N/A N/A 10/86 MW58 561366.7327 1424032.1626 777.14 N/A N/A 10/86 MW59 561565.2875 1424118.7755 781.64 N/A N/A 10/86 MW60 N/A N/A N/A N/A N/A 10/86 MW61 N/A N/A N/A N/A N/A 10/86 MW62 N/A N/A N/A N/A N/A 10/86 MW65 561685.7057 1423587.8862 785.72 5.0 - 20.0 20.0 08/10 P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table ] - Well Constr Data.xls\Tl Page 3 of 4 Table 1 Well Construction Details Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well No. Northing (Feet) Easting (Feet) Top -of - Casing Elevation (Feet Realtive to NGVD) Screen Interval (Feet Below Ground) Total Depth (Feet Below Ground) Approximate Date Installed Geologic Zone Monitored Parcel Number MW-66 561590.4521 1423794.7772 781.04 5.0 - 15.0 15.0 08/10 MW-67 561563.2546 1423798.0394 780.44 5.0 - 15.0 15.0 08/10 MW-68 561567.8782 1423717.2986 782.47 5.0 - 20.0 20.0 08/10 MW-69 561504.0530 1423724.1203 774.72 5.0 20.0 20.0 05/11 Sandy Silt PMW01 561124.4362 1424041.9674 761.06 5.0 - 15.0 15.0 06/92 Sandy Silt 05724302 PMWO2 561125.5177 1423964.5881 760.76 6.0 - 16.0 16.0 06/92 Sandy Silt Saprolite 05724302 PMWO3 561128.1760 1423878.0757 758.52 8.0 - 18.0 18.0 06/92 Sandy Silt Saprolite 05724302 PMWO4 560675.8867 1423430.5786 750.27 11.0 - 21.0 21.0 06/92 Sand Silt 05723114 PMWO5 560662.9922 1423502.4158 743.41 10.0 - 20.0 20.0 06/92 Sandy Silt Saprolite 05723114 PMWO6 561036.5314 1423856.2959 754.27 2.0 - 7.0 7.0 08/93 Silty Clay 05724302 PMWO7 561019.1837 1423982.5768 753.66 3.0 - 8.0 8.0 08/93 Silty Clay 05724302 PMWO8 561140.6727 1424080.3010 760.98 4.0 - 9.0 9.0 08/93 Silty Clay 05724302 PMWO9 560989.1019 1423862.8722 750.93 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW10 560846.3905 1423724.5687 746.86 3.0 - 8.0 8.0 N/A Silty Clay 05724302 PMW11 560579.1482 1423436.2214 746.42 N/A 20.0 N/A N/A 05723114 PMW12 560394.9714 1423299.1239 732.48 N/A 12.5 N/A N/A 05723114 RWO1 561092.3515 1423700.3608 N/A N/A N/A 05/86 RWO2 561590.5007 1423420.7633 784.71 6.0 - 26.0 26.0 05/86 Sandy Silt - Silty Sand 05724302 RWO3 561720.1317 1423614.0215 788.20 2.0 - 28.5 28.5 05/86 Sandy Silt 05724301 TO1 (trench) 561572.6969 1423690.8304 785.15 N/A 17.0 N/A N/A 05724301 T01A 561347.4489 1423879.9408 765.31 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 T02 (trench) 561558.4972 1423768.6401 783.08 N/A 22.0 N/A N/A 05724301 TO2A 561192.7742 1423857.4115 761.77 2.0 - 8.0 8.0 05/95 Sandy Clay 05724301 UW01* 561589.3852 1423826.6607 781.23 1.0 - 16.0 16.0 08/91 N/A 05724301 UW02 561606.2226 1423647.4684 785.44 3.0 - 18.0 18.0 08/91 Saprolite 05724301 UW03 561623.4532 1423644.3421 785.50 2.5 - 17.5 17.5 08/91 05724301 UW04 561649.6681 1423753.4841 787.59 5.0 - 20.0 20.0 09/91 Saprolite 05724301 UW05 561651.6699 1423810.2421 789.59 4.0 - 14.0 14.0 09/91 Saprolite 05724301 UWO6 561547.4955 1423695.4543 782.00 1.0 - 16.0 16.0 08/91 Saprolite 05724301 UW07* 561560.8461 1423919.6721 780.03 2.5 - 15.0 15.0 09/91 N/A 05724301 UW08 561581.0603 1423770.9912 780.97 5.0 - 15.0 15.0 02/92 Saprolite 05724301 UW09* N/A N/A 778.00 2.0 - 12.0 12.0 02/92 UW10 561650.8426 1423655.9836 785.56 3.0 - 18.0 18.0 02/92 Saprolite 05724301 UW11 561573.1870 1423648.4289 784.79 4.0 - 19.0 19.0 02/92 Saprolite 05724301 VE01 561610.1204 1423594.3698 N/A N/A 10.0 N/A 05724302 VE02 561635.7696 1423612.0386 785.42 N/A 10.5 N/A N/A 05724301 VE03 561597.8544 1423617.7069 785.41 N/A 12.0 N/A N/A 05724301 VE04 561654.3003 1423576.2976 785.46 N/A 12.5 N/A N/A 05724302 VE05 561684.7491 1423590.9811 784.83 N/A 13.0 N/A 05724302 VE06 561728.0120 1423583.0234 785.19 N/A 11.5 N/A 05724302 VE07 561689.8509 1423654.3951 785.52 N/A 13.0 N/A N/A 05724301 NOTES: 1) N/A - Data Not Available. 2) * Missing as of 03/2005 3) " Abandoned September 2002 4) NGVD = National Geodetic Vertical Datum P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables \5.3 Reports\June 2015\tables\Table 1 - Well Constr Data.xls\T1 Page 4 of 4 r Table 2 June 2015 Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Datum Date Depth to Depth to LNAPL Groundwater Elevation LNAPL (feet) Water (feet) Thickness Elevation (feet, MSL) (feet) (feet, MSL) DW01 784.12 6/1/2015 4.79 779.33 DW02 776.17 6/1/2015 5.75 770.42 DW03 762.28 6/1/2015 9.10 753.18 DW05 786.60 6/1/2015 13.30 773.30 DW06 791.69 6/1/2015 11.13 780.56 DW08 abandoned 3/20/15 DW09 abandoned 3/20/15 DW10 791.49 6/1/2015 Inaccessible: construction activity ES01 791.38 6/3/2015 7.01 784.37 ES05DR 786.79 6/3/2015 10.18 776.61 ES05SR 786.67 6/3/2015 8.25 778.42 ES13 791.83 6/3/2015 11.11 780.72 ES14 790.70 6/3/2015 9.26 781.44 ES18 786.31 6/3/2015 12.67 773.64 ES25 754.69 6/3/2015 9.11 745.58 ES26 777.81 6/1/2015 Inaccessible: construction activity ES28 774.01 6/1/2015 4.58 769.43 ES29 791.37 6/3/2015 10.62 780.75 ES31 779.22 6/1/2015 9.88 769.34 ES32 762.94 6/1/2015 3.82 759.12 ES33 763.33 6/1/2015 1.00 762.33 ES34 777.18 6/1/2015 1.39 775.79 ES35 774.74 6/1/2015 2.26 772.48 ES38 782.60 6/1/2015 8.66 773.94 ES40 779.47 6/1/2015 5.05 774.42 MW02 781.37 6/3/2015 8.37 773.00 MW05 786.65 6/1/2015 5.77 780.88 MW08 777.69 6/3/2015 6.92 770.77 MW 12 786.16 6/3/2015 1.71 784.45 MW 14R 756.41 6/3/2015 7.78 748.63 MW19 782.64 6/3/2015 8.32 774.32 MW21 785.76 6/3/2015 4.15 781.61 MW26 785.38 6/1/2015 3.96 781.42 MW36 785.94 6/1/2015 11.77 774.17 M W 38 785.54 6/1/2015 10.83 774.71 MW39 785.28 6/1/2015 10.50 774.78 MW41 785.64 6/1/2015 10.87 774.77 MW44 786.77 6/1/2015 10.79 775.98 MW49 784.17 6/1/2015 9.92 774.25 M W 50 783.50 6/1/2015 9.49 774.01 MW 51 786.41 6/1/2015 8.51 777.90 MW52 756.05 6/1/2015 11.85 744.20 MW53 754.42 6/1/2015 8.48 745.94 MW55 782.36 6/1/2015 Inaccessible: under water MW57 769.54 6/4/2015 7.62 761.92 MW58 777.14 6/1/2015 9.52 767.62 MW59 781.64 6/1/2015 3.46 778.18 M W 65 785.72 6/1/2015 4.04 781.68 MW66 781.04 6/1/2015 3.71 777.33 MW67 780.44 6/1/2015 3.36 777.08 MW68 782.47 6/1/2015 7.27 775.20 8/26/2015 Page 1 of 2 Table 2 June 2015 Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Datum Date Depth to Depth to LNAPL Groundwater Elevation LNAPL (feet) Water (feet) Thickness Elevation (feet, MSL) (feet) (feet, MSL) M W 69 774.72 6/1/2015 8.28 766.44 PMW01 abandoned 3/20/15 PMW02 abandoned 3/20/15 PMW04 750.27 6/1/2015 13.42 736.85 PMW05 743.41 6/1/2015 7.31 736.10 PMW09 750.93 6/1/2015 5.05 745.88 PMW 10 746.86 6/4/2015 2.10 744.76 PMW 11 746.42 6/1/2015 13.53 732.89 T02A abandoned 3/20/15 UW05 789.59 6/1/2015 8.29 781.30 U W 06 782.00 6/1/2015 7.53 774.47 UW08 780.97 6/1/2015 5.52 775.45 U W 10 788.56 6/1/2015 4.45 784.11 VE02 785.42 6/1/2015 4.22 781.20 LNAPL = Light Non -Aqueous Phase Liquid MSL = mean sea level 8/26/2015 Page 2 of 2 Table 3 Semi -Annual Groundwater Sampling Plan Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well ID Number BTEX, MTBE, IPE, 1,2-DCA, Naphthalene Analysis (1) Monitored Natural Attenuation Parameters (2) DPEW01 DPEW02 DW01 • DW01A DWO2 • DWO3 • DWO5 • DWO6 • DW10 • ES01 • ES03 ESO5SR • ESO5DR • ES07 ES10 ES11 ES12 ES13 • ES14 • ES15 ES18 • ES20 ES23 ES25 • ES26 • ES28 • ES29 • ES30 ES31 • ES32 • ES33 • ES34 • ES35 • ES37 ES38 • ES40 • ES41 ES43 MPO6 MWO2 • MWO3 W MWO5 • Well ID Number BTEX, MTBE, IPE, 1,2-DCA, Naphthalene Analysis (1) Monitored Natural Attenuation Parameters (2) MWO7 MWO8 • MW12 • MW14R • MW19 • MW20 MW21 • MW26 • MW27 MW36 • MW37 MW38 • MW39 • MW41 • MW42 MW43 MW44 • MW45 MW47 MW48* MW49 • MW50 • MW51 • MW52 • MW53 • MW55 • MW56 MW57 • MW58 • MW59 • MW-65 • MW-66 • MW-67 • MW-68 • MW-69 • PMWO3 PMWO4 • PMW05 • PMWO6 PMWO7 0 PMWO8 PMWO9 • • P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 3 - Sampling Plan.xls\Table 4 Page 1 of 2 Table 3 Semi -Annual Groundwater Sampling Plan Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well ID Number BTEX, MTBE, IPE, 1,2-DCA, Naphthalene Analysis (1) Monitored Natural Attenuation Parameters (2) PMW10 0 PMW11 • TO1 (trench) T02 (trench) UW05 • UW06 • UW08 • UW10 • UW11 UW02 UW04 VE02 • VE03 VE04 VE07 Total: 61 1 NOTES: (1) _ Benzene, toluene, ethylbenzene, xylenes (BTEX), methyl tert-butyl ether (MTBE), isopropyl ether (IPE), 1,2-dichloroethane (1,2-DCA), and naphthalene analysis by SW- (2) - MNA parameters include: Alkalinity, hydrogen sulfide, nitrogen, nitrate, specific conductivity, sulfate, sulfide, pH, calcium, and sodium by various analytical methods. 0 - Wells to be added to semi-annual sampling events. • - Wells currently part of semi-annual sampling events * - MW48 will be gauged for depth to water and depth to product AS - Air sparge well DPE - Dual phase extraction well DW - Deep monitoring well ES - Ecological Services, Inc. installed monitoring well MP - Monitoring point MW - Monitoring well PMW - Monitoring well RW - Recovery well T - Trench well UW - Unocal monitoring well VE - Vapor extraction well P:\Jobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 3 - Sampling Plan.xls\Table 4 Page 2 of 2 Table 4 Summary of Monitored Natural Attenuation Results Marathon East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, NC Sample Location: PMWO9 Collection Date: 6/4/2015 Parameters Units Metals Calcium mg/1 28.9 Sodium mg/1 <30.6 U Other Alkalinity, Total (as CaCO3) mg/1 208 Hydrogen Sulfide mg/1 4 Nitrate mg/1 <0.011 Sulfate mg/1 16.2 Sulfide mg/1 5.1 Notes: < - Not detected at the specified detection limit CaCO3 - Calcium carbonate mg/L - Milligrams per Liter U - Not present above the associated level, blank contamination exists This table presents the results of the MNA analyses. Sample results have been qualified by URS based on the results of the data review process, which is modeled after the USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Inorganic Superfund Data Review (USEPA, January 2010). P:Vobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 4 - MPC East Terminal - 2015-06 - MNA Results 2015- 07-29.xlsx 9/21/201512:06 PM Table 5 Summary of Groundwater Results Compared to NC 2L Groundwater Quality Standards Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, NC Parameter: Benzene Toluene Ethyl benzene Xylenes (Total) 1,2-DCA Isopropyl ether MTBE Naphthalene ' i ;C:L`U.g 1 600 600 500 0.4 70 20 6 Sample Location Collection Date ----- DW01 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 1.9 DWO2 6/4/2015 <0.21 <0.21 <0.27 <0.39 ; 7�;2 5.7 fir ✓ J I <0.34 DW03 6/4/2015 <0.21 <0.21 <0.27 <0.39 I )l,a� 1 2.2 'C `i J 1 <0.34 DW05 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 4.4 10.'.3, 1 <0.34 DWO6 6/3/2015 <0.21 <0.21 <0.27 <0.39 ° 38.7 � 7', 1 <0.34 DWO6 6/3/2015 <0.21 <0.21 <0.27 <0.39 2.2 39.5 3u; <0.34 ES01 6/3/2015 1 11A I <0.21 1.3 J <0.39 <0.32 <0.2 <0.28 2.1 ES01 6/3/2015 . 2! j <0.21 <0.27 UJ <0.39 <0.32 <0.2 <0.28 1.8 ES05DR 6/3/2015 l r �'(o I 4 16.4 11.8 <0.32 10.4 2.1 i 24 _J ES05SR 6/3/2015 ` 43 _ <0.21 <0.27 <0.39 <0.32 5.5 ` :1(�J' <0.34 ES13 ES13 6/3/2015 0.93 J <0.21 <0.27 <0.39 <0.32 20.6 14 <0.34 ES14 6/3/2015 1 Z1_-- _ 1 <0.21 6.7 <0.39 L_ z5,ff. 1 4.6 0.48 J 0.93 J ES18 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 ES25 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 ES28 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 0,.11' j <0.34 ES29 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 ES31 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 ES33 6/2/2015 4 U) _] 222 498 11,572(0) 1 <16 55.6 I , 7 ' _I! 4c`°f°e`s_] ES34 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 ES35 6/2/2015 • I' i r1^ 2.3 J 3.1 J 3.2 J 1i 11 1, 9.8 J <0.28 N 1",I; j ES35 6/2/2015 -0Xi 1 4.9 J 14.3 J 7.4 J ^ 3,1. ..�_I 26.2 J <0.28 ? 2 ,4„ ES38 6/2/2015 <0.21 <0.21 <0.27 <0.39 L '��:9,5;f1 _ 0.98 J 8.6 <0.34 ES40 6/2/2015 1 7/7,6 1 0.9 J <0.27 1.8 <0.32 <0.2 <0.28 1 __11/3 MWO2 6/3/2015 , % _I 0.58 J <0.27 1.7 <0.32 0.25 J , 2 _] 3 MWO5 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 0.75 J MWO8 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 MW12 6/3/2015 1 z„1: J <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 5 MW14R 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 MW19 6/3/2015 1((1; 6.4 288 69 <0.32 6.8 L F 71_ __11 _ 1 S4- _] MW21 6/3/2015 'i / C. i j 444 C44111l i-::57 .--I <16 35.6 J f 1/.* -]i 52.2, j MW26 6/3/2015 i 11.39 2.1 178 8.3 <0.32 <0.2 0.38 J 1- (C�a--yL J MW36 6/3/2015 ' %�, � 1 8.9 198 52.1 <0.32 7.2 r -11 1,!_ 11 1,Co' , MW38 6/3/2015 0.75 J <0.21 0.61 J <0.39 <0.32 <0.2 <0.28 1.9 MW39 6/3/2015 ! 61,2i - ] 5.7 18.8 49.6 <0.32 <0.2 2.8 5.2 MW41 6/3/2015 a,2 <0.21 1.8 73.7 <0.32 <0.2 <0.28 0: 6 MW44 6/3/2015 > 316d. J 11.5 415 33.2 I2:: ---1 45.5 C--11„91 Q, 1 `' MW44 6/3/2015 34,:' /C"r 1 11.8 399 32.9 1 5- - ---_1 45.6 1- J1-972 o - 11 :fa, MW49 6/3/2015 U Jg 1 5.6 <0.27 20.7 0.36 J 0.62 J 14.3 i J MW50 6/3/2015 0.93 J <0.21 8.4 6.4 <0.32 <0.2 <0.28 _ 2 ;:/ MW51 6/3/2015 1-3.7igd 1 33 191 331 1 143 1 69.9 a °i7 11 4C4 MW52 6/3/2015 0.35 J <0.21 <0.27 <0.39 <0.32 0.36 J ,s, 1 <0.34 MW53 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 MW57 6/4/2015 <0.21 <0.21 <0.27 <0.39 <0.32 0.79 J 1 44 -1 <0.34 P:Vobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 5 - MPC East Terminal - 2015-06 - VOCs Compared to 2L, revised 2015- 07-29.xlsx 9/21/201512:06 PM Table 5 Summary of Groundwater Results Compared to NC 2L Groundwater Quality Standards Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, NC Parameter: Benzene Toluene Ethyl benzene Xylenes (Total) 1,2-DCA Isopropyl ether MTBE Naphthalene 1K )1,;I 1 600 600 500 0.4 70 20 6 Sample Location Collection Date ----- MW58 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 MW59 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 0.6 J <0.34 MW65 6/3/2015 � E,.l4 9;' _1 ).;:41fi, I. -0C. I � JF : { 5.5 J 18 J e d 7, MW65 6/3/2015 - �-- Etit�1�1 - - - - Ti��,�l ��---�.� a � i hml ��,�` �� 23 Si � 5.3 17.6 i S�-�� MW66 6/2/2015 _�L I 7. 1 1.5 20.6 9.2 <0.32 0.98 J 5.3 af„ 1 MW67 6/2/2015 j , 11.011 1 11.9 1-().T17 1, 19.3 <0.32 1.3 10.1 j___ ✓. `,'4,_ j MW68 6/2/2015 e 201,2' I 4.1 39.6 32.3 r la. 1, 9.3 i- 1tC,EL 11 1 ,1, r� MW69 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 6.5 ; *55) 1 0.52 J PMWO4 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 0.8 J 1 316 2 1 <0.34 PMWO5 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 0.57 J ; 4,6 1 <0.34 PMWO7 6/4/2015 <0.21 0.55 J <0.27 <0.39 ' Cu'.�(iz, _.1i_ I _ 2.6 14.8 <0.34 PMWO9 6/4/2015 <0.21 <0.21 <0.27 <0.39 _C .1; _1 4.5 2.7 <0.34 PMW10 6/4/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 <0.28 <0.34 PMW11 6/2/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 7.4 <0.34 UW05 6/3/2015 <0.21 <0.21 <0.27 <0.39 <0.32 <0.2 0.53 J <0.34 UW06 6/2/2015 0.69 J <0.21 1.8 <0.39 <0.32 <0.2 11.6 1.1 UW08 6/2/2015 j �� 1 1 I 5.2 41.6 5.9 91.,1; 1 20.6 & aJ _ UW10 6/2/2015 3,7(11C1 1 85.4 414 1 J,,,,/ 'tJ, 1 <0.32 1.3 J 12.1 J j SO,1; UW10 6/2/2015 j 3 g.e, I 74.8 348 1_1±. C1 1 <3.2 <2 12 ( C ' -1 VE02 6/2/2015 1 ) J J G5 I1 6-J1 s _ 1 558 i > C)i 0 1 <6.5 28.9 I,___ _ L i 1! l'C ` .. Notes < - Not detected at the specified detection limit DCA - Dichloroethane J - Estimated value µg/L - Micrograms per Liter MTBE - Methyl tert-butyl ether NC 2L - NC 2L Groundwater Quality Standards UJ - Not detected and the associated detection limit is estimated This table presents the results of the volatile organic analytes. Sample results have been qualified by URS based on the results of the data review process, which is modeled after the USEPA Contract Laboratory Program (CLP) National Functional Guidelines (NFG) for Superfund Organic Methods Data Review (EPA, June 2008). All results reported in micrograms per Liter (µg/L). NC Groundwater quality standards for the protection of the groundwater are specified in 15A NCAC 2L .0200. A shaded cell with a bold border indicates the concentration is greater than the standard. P:Uobs4\_Projects\Marathon (Fmr BP 4762)\5.0 Deliverables\5.3 Reports\June 2015\tables\Table 5 - MPC East Tenninal - 2015-06 - VOCs Compared to 2L, revised 2015- 07-29.xlsx 9/21/201512:06 PM Figures s\June 2014\ op u-5 7 SCALE IN FEET oisciam 0 2000 QUADRANGLE LOCATION SOURCE: USGS 7.5' TOPOGRAPHIC QUADRANGLE MTN. ISLAND LAKE, NC — DATED 1993 FIGURE 1. LOCATION MAP MARATHON CHARLOTTE EAST TERMINAL CHARLOTTE, NORTH CAROLINA Prepared for: MARATHON PROJECT NO. 31828983 ROU, NORTH CAROLINA 27560 750 Fig. tr. c U r d c ES29 • DWO6 • Dw1o• E•3 ES07 • •ES14 #3 ES0t1DR COV=RLC LOADING 'A_K_ _ ES12 •E341 MW59� • u AI07 t1ULi1P,E PIPES DPpW02AS-6 uwos= hpo�s>u • , UWo1Es36, MW66' �• - � MW6T - UW08 17'4 • ES35 ",-MW68 MW69 . DW01A •cUWO6 T•1- bW01 UW� UWO2 • - I - I V,, Q • •UWN- - UUVUd • - �,MW12 • � VE03' - RWO3�_ MW20 • MW48- ESu_} E510• MW27fV • •MW2PVE02 • _ E•8 -0 •ES01 lEU6 •MW65 OVEOi VE05P V!_OS •• ._ - MW47 MW ES17 ' MW26 VE04 MWO5 - •43 • �, • ESoidb •DWO5 • ES20 ES15 #11_ ,#21.1 W #4 ES055R ' - MW ESO5DRM ES95 ES11 • °"'E`- ' MW42• " �MW44 EOLliPM1IEN' - =N^LDS kF Rwa 2 ES18• MW37 MW39•�' "M!45•MW50 AS-5�7l MW38 AS-4 .. -- - MWo n8112 •isn1�P •MW36 _ MW490 • - MWO2 MWOB 4 • ES31 • ES26 • E 28 ES03 • ES43• \ • MW58 ES23 • ES33 • MPu3 OMpot • (JDPEW01 ES32 'YPC2 Pro�WO2r j n'VO8 DlA,M9tt r tASO1 'IMP 6 i-P 4YJ03 PMWO8 3 PMWO1 ES30 • _ES37 • DWO2 • M�5 MW07 IU2A ESO.O • MW57 Former National Oil Terminal Property PMW07 • DWO3 • MW56 PMWO6 •PMWO9 ' MW53 MW52 • MW14R• • ES25 PMW10 • PMWO5 • PMWO4 • PMW11 • \ DPVES DW01 • UW07 FSO5 0 AS-. u #2 PMW12 • 0 50 150 Legend Treeline Fence Line Property Line Railroad Dual Phase Vacuum Extraction System Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Monitoring Well Missing as of 03/05 Groundwater Monitoring Well Abandoned 05/05 Air Sparging (AS) Well Abandoned Monitoring Well Site Buildings SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED-PROPER1I' OF URS RDO, NORTH CAROUNA 27580 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 2. Site Plan Marathon Charlotte East Terminal Charlotte, North Carolina APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-2 REV. 0 c L 0 50 150 Legend Groundwater Monitoring Well Sump Location of Release Incident (See Narrative Far Description) SCALE AS SHOWN DESIGNED BY DATE CONFlOEMNL-ALL Potl1TS RESERVED -PROPERTY OF URS RDU, NORTH CAROLINA 27560 DRAWN BY TSH DATE 02JUL07 CHECKED BY LV DATE 02JUL07 Figure 3. Locations of Historical Terminal Releases Marathon Charlotte East Terminal APPROVED BY MN DATE 02JUL07 CONTRACT N0, 31825953.10000 DRAWING N0. FIG-3 REV. 0 • c c Cc Ir _c C c N r 0 CC L£i r 0 0 0 a c 0 cc s c /\\ C Eszt ES� \o ESC DF CC Rt© 0 C)y.JV / J' cClUlp.El" 0 DWDS ES20 �44 u ES42 0 Esau ,='' ES34� ✓1\ 0 ES40 P4 UW07 ES31 Io 0 0 0 0 o O' Marff EES3 0 ES7W VPCI MVJOE L{R'G7 SUMP 0 TO2A CI' PL1W07 PUUW02 0 DV/08 0 0WO5 0 FM /03 0 0 0 0 0 n DV/03 0 SUMP B at roSUMP C TANN 110 ;m ,Nx 4 PMWOS W09 % 0 \\\ \ i ii 1 \ .).\:11 F R MW14R Es 25 !( ` 0 0° \l PVV/10 0 if 7-- 0 Immo Legend Area Of Dual —Phase Vacuum Extraction Approximate Location Of Soil Excavation Area, 09/06/91 — AT&E, 04/92 Approximate Location Of Soil Excavation Areas, 09/30/96 And 10/01/96 — S&ME, 10/97 Approximate Location Of Soil Excavation Area, 03/04/97 — CBM 04/97 Approximate Location Of Soil Excavation Area, 04/01/98 — G&E Engineering, 02/98 Approximate Location Of Soil Excavation Areas, 05/13/98 — EHS Field Notes, 05/98 Approximate Location Of Soil Excavation Approximate Location Of Soil Excavation Areas, 01/07/99 — CRA, 05/99 Approximate Location Of Sail Excavation 02/05 Approximate Location Of Permeable Reactive Barrier Installed 02/05 — Piedmont Geologic o5/o5 Area of ISOC Influence — Piedmont Geologic 01/06 SCALE AS SHOWN DESIGNED BY DATE CONFIDE/VITAL—ALL RIGHTS RESERVED-PROPERTf OF URS DRAWN BY TSH DATE CHECKED Eff LV DATE Figure 4. Historical Remediotion Activities Marathon Charlotte East Terminal APPROVED BY MN DATE CONTRACT NO. 31828983.10000 DRAWING NO. cc Tic C n CPnfemhP n71\fi.n np rfs\ Mnrnthnn L c DW06 (780.56)0 i.E •ES34 775.79 ES14 • 781.44 ' DW10• NM COVERED ES(75D • LOADING ES13 RACK 780.72 IES29• •ES07 780.751 ES1`SR I1L W05 • 7 1.30 I u U 04•Y 7 -- - VE070 UW7 784.45,' , RWO3 MW12' 81.61 0• MW27 (773.30) MW65 1.'424.781.68 •ES05DR_ESO5SR (776.61) Tire — \�if1AW37; -. MW39. 1-S M!45 ES18• 774.78_ 773.64 • /•MW38 MW41 774.71 • — 774.77 DERRS—��MW49•. EOLAL,AENr 774.25- 774.32 ENCLOSURE - -• • ES41 MW59 778.18 1' PPLE Pli • 777.3 MW E02 • VE PEW 1• 779. •'' WO` W1 777.90 44 775.98 ~ ES30• D 02 (77 .42) ES40 • 774.42 • ES43 .767 2 • : 533 -- - - - • 62.33 • ES2: 769.43 ES03- MW50 774.01 Former National 011 Terminal Property PArf/Ira -)f;10102 PMW07 •\ Permeable Reactive Barrier up uv . i MilHIP soi IP CO "1PMv 0 - ^ 1. PMWO9 � 745.88 �012n L 11 P (WOG W56 PMW10 744.76• MW53 745.94\ ..MW.14R ES25 ' 745.58 PMW11 • 732.89 PMW12 • SUMP C PMWO 753.862 • DW08 • (778.72) 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well With Water Table Elevation (ft) Groundwater Elevation (ft) (Not Used for Contouring) Abandoned Monitoring Well NM Not Measured 750 — Water -Table Contour (ft) Approximate Direction of Groundwater Flow SCALE AS SHOWN DESIGNED BY DATE CONFIDINRAL-AU. RIGHTS RESERVED -PROPERLY OF URS RDU, NORTH CAROUNA 27580 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 5. Water Table Contour Map, June 1-4, 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT ND. 60393333 DRAWING ND. FIGURE-5 REV. 0 IC a 9. EC 9: EC 9. 2 <1 1.0\ES7.640 ESi9 ES14 '1.0, i • DWO6-/ _. . � •3.8 _\ -- •ES31 <0.211 \ DW10• / E5084 / Esoao < 71 E•3 --- -' 0.93J ES29 ES07 <0.21 • • • /• ES12 • DP 2 UW05' • .(<0.21)• MW66` 7.1 ES15 U B• ,..'uwo4•fj 70' 100` MW68•. 89.2 UW10 DW01A0 3,790 7 ; T01•I 07 1 WO1.• 0.21), ! _ U 2 •U 1 - . 1II 17.600 VE • 03 -- - ES03 E 10' R 03t• •2,11 _ M " .ES38— • W 7� • I - •-- - ',<0.21 VE04 A. yy M20 == 47 M 20 W26• 6 6-5 ,�M 43 - - 9 10 .0 ES05D"• (554) 1, 00 MW51 SR \ __ 3,280 - I �MW42� W441/ •DW05 Rv�ti;; MVV3 <0.21 W39 • MW50 1.8• ��� 0.93J ES18 <021• 100 N 11 • r " (0. 536_ MW49 69.8 9s- 11 1,76IT • • ES26 •MW69 <021 UWO6 0.69J ES2 •<0.21 ES43. ES30 - ES37 • DW02 <021 • MW55 MWO8 _ 050.21_ �MW07- • oigohI r1r'nel---'-3pmwo3 TO2A PNaWos1=( MW57. <0.21 MWO3W • DWO3 • <0.21 • MW56 PMW09 •<0.21 \ • MW53, <0.21 MW52 0.35J• • MW14R• <0.21 •-. ES25— <021 PMW10 •<0.21 PMWO5 <0.21 • PMW04 <0.21 • PMW11• <0.21 PMW12 • 0 50 150 Legend Treeline - Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DWo1 • Groundwater Monitoring Well 0.12J Groundwater Benzene Concentration (ug/I) (<0.21) Groundwater Benzene Concentration (ug/I) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well 1 - — — - Benzene Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL —ALL RIGHTS RESERVED —PROPERTY OF URS RDU, NORTH CAROLINA 27580 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 6. Benzene Isoconcentration Map, June 2015 Marathon. Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-6 REV. 0 0. c ES29 c CL c Cs a a E L, a -c c ES01 0.21• •ES17 E_S^g DWO6 •<p 21 •<021 DW10• I _r-517"._q. • FSO,IUFt J�`1`,` ," ES13 <0.21: •ES07 • ES12 ES15•_ • ES41 • \ ES40 0.9J MW59 <0.21 • ES35 4.9J • DPEW02 UW05 • <0.210 MW67 MW66. •119: 1:5 UW080 1'T02 UW04• 5.2' ES•43 ES23 • \ PMWO8• MW58 • <0.21 •ES23 DPEW01 . \ • ES32 PM r,'Wp2 0.55J.55J u�.vnd±i i • ES31 \ <0.21 LwnlUd. .. ' ,ir-.0(:)-1 sP oPnI,+ 02A1-. , PMW09 TL PL1WpJ?� •<0.21 • ES26 MW68 •MW69 -1 •4:1 <0.21 _ DW01 • •UW06 • UW10 • •<0.21 85.41 ' , TO1 , DW01 VE07'- ' •/<0.21 , en211- •- ESO3UW02• •UW11- 600 VEO3 RW03 _M••W48 MW?7•• 68' . •ES10 ; 1E <0.2 MW2 . •MW05 - �MW47 <0.21 . • ' 2.1 MW43 ES ES05DRM 21SR, 4.0 - - ES11 • MW51• 33 • MW42 MW44• 11.8 DW05 c��,qa.• MW37 ES20 �<0.21 ' MW39 -. • MX45 • MW50 • 5.7•) <0.21 S10 <E0.21• MMyyyygg8 MW36 0 21<p.218.9• MW49 �5.6• A"W1 • 52 58Oj 6.4- - •<ES0.2126 ES30 • ES37 • DW02 • <0.21 • MW55 MWO8 =0.21 •MW07 MW57 • <0.21 MWO3W • DW03 • <0.21 • MW56 • th <0 21 MW52 <021 • MW14R • <0.21 • ES25- <0.21 PMW10 • <0.21 PMWO5 <0.21 • PMW0244<0.• PMW11• <0.21 PMW12 • DWO1• • 0.12J (<0.21) J 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Toluene Concentration (ug/I) Groundwater Toluene Concentration (ug/I) (Not Used for Contouring) Estimated Value 1:: Abandoned Monitoring Well 600 - - - Toluene Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -AU. RIGHTS RESERVED -PROPERTY of URS RDU, NORTH CAROUNA 27560 DRAWN BY TS H DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 7. Toluene Isoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-7 REV. 0 L i cc c c a r c DW06 _ • <0.27:, DW10• ES13 <0.271 ES29 ES07 <0.27'• • •6E �14 E503DRESric SR ES•40 <0.27 MW59 <0.27 • ES35 14.3J •<o 27 ES12 • DPEW02 UW05 -- ' <0.27• MW66 •MW67 _ "20.6! 617- -- - __--- Es15__ - -_ uwo8• )- 172 UW04•- ,(41:61 -'-•MW68 •MW269-. DW01A 39.6 UW10' ;' „- • , •UW06 414i/1 i T01•; 1.8 �ES28 DW01 _•<0.27 - VE074. •/<0.27 <0.27-. UW112• •UW11 - _ MW12 - 1, OJ / - - RW03 21.. •VE03 W48 -E•8 .E503- - ES37 •DW02 ES10 1 • VE02>=;,, <0.27 1 3J1• ' • • � ! MW27 � , . 1 II 558 <0.27- . _ _. _ VEf14 MW47 ES17. MW26•LMW0gS'-<0.27_ _• : • 1 - • _ ,' 178 V1,700 , 61 MW43,, \ / SES0SDR00EO O5SR 16.4 27 . ES11• ES•43 ES23 • /\ MW58 • <0.27 ES33 •498 DPEWO1 • DW05 _' •<0.27 • ES20 — MW51. • 191 •MW42 MW44• 415 P,W09 37 - —. MEP. 1 M! MW39 45 •MW50 .8,4. • ES26 ES30 • • MW55 ES18 - • - .27• -- mW41 483g8' MW36 MW49 - _ <027• 288• • UW27 =27 MWO7• PMW08• \ PM1.IWQ • \ ES32 P PNIT/O2 <0.27V. • Dams;_( D7O9I1 ti0t PMW09 TO2A)-; PMWD6 , • <0.27 •<0.27 MW57 - MW03W DW03 •<0.27 , • MW56 •<0.27'MW53 ' MW52 <027• MW14R• <0.27 ES25 <037 PMW10 •<0.27 PM<027• PMW04 <0.27• \ PMW11• <0.27 PMW12 • 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DWo1 • Groundwater Monitoring Well 0 12J Groundwater Ethylbenzene Concentration (ug/l) <o:z7) Groundwater Ethylbenzene Concentration (ugll) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well 600 — — — Ethylbenzene lsoconcentration Contour (ugfl) SCALE AS SHOWN DESIGNED BY DATE CONFIDEMUL-ALL RIGHTS RESERVED -PROPERTY OF IURS RDU, NORTH CAROIEU 27550 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 8. Ethylbenzene lsoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING N0. FIGURE-8 REV. 0 C CC tr C n r c a. -c Cc c x a u c c c n cc r a Q C c -c <p .• ES41 E•0 \ 1.8 MW59 • <0.39 • ES35 7.4J ES'? DW06_ • <0.39• 0 �<0.39.- ow10• ESOSDR j-,jY �ESD8 F ES13 • - --- <0.39' '- --- - ES12 • DPEW02 -• _ _ ^ UW05- - ES29 ES07 <0.39• • ES01 <0.39• •ES17 • ES20 <0.39• MW66• •MW67 9.2 .19.3- -- ES15•. _I = UW080 )11,02 UW040.., .:9•'. u - . ' - MW68 •MW69 _ _ -- -- DW01A • 32.3 <0.39 UW10 - • -•`W06 1,700 T01•' 0.39 �ES8 ' - 500 ' DWO1 ; '�•39 <0.39 I UW02 •UW11- '' I. _ MW12 2,30E --- - RW03 - MW21 •VE03 NW48 _ ES38 • •ES03- :ES37 •D 392 ES10• . MW27� • 5 3.010 • <0.39 - - - -- 0- •io MW- MW20MW26• , VE 4 •<0395 •W • 8.3 t mW43 -- - -., X 1 \ 3311• ES31 • <0.39 • \ ES43 ES23 • MW58 • <0.39 % ES33 ._ - /'1 20i DPE'O1•j00 DWO5 '<0.39 VE07 ES05DR•• <0 395R 11.8 - ES11• ES18• , <0.39 •MW42 - MW44• 33.2 W37 MW369•-4 M�45, • 6 4 50 kry•WM39 • M52.1 W36 V <0 • MW49•'-' — 20:7 n�VV g 69. • ES26 ES30 • PMW08• \ •' \ ES32 PMWO7 • PrvS:^;02 <0.39 T-t DIVO -. t ASO1 TOZ.c •• PMWO9 (PMWO6 <0.39 • <0.39 MW67 DWO3 • <0,39 • MW56 • MW53; <0.39-, MW52 <0.39• PMW10 • <0.39 PMW05 <0.39• • MW55 •MW02 - MW08 1.7 - •<0.39- MWO7 MWO3W - •- MW14R• <0.39 ES25 ! . <0:39— PMW04 <0.39• 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DWO1 • Groundwater Monitoring Well 0.12J Groundwater Xylenes Concentration (ug/l) Groundwater Xylenes Concentration (ug/I) (Not Used for Contouring) Estimated Value PMW12 • (<0.39) Abandoned Monitoring Well 500 — — — Xylenes Isoconcentration Contour (ug/l) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF URS RDU, NORTH CAROUNA 27580 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 9. Xylenes Isoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-9 REV. 0 c h r a a .0 C l ,• DWO6 383 zoo _I DW10 • ES13 14 ES29 ES07 <0.28'• • ES01 <0.28• ES17 ES10 ES15 •E514 0.48J ESOYDR tSbdS! ES12 ES15• VE07• -<0.28 MW.12 RW0�3 MW2�( 111/ MW20 18J MW26• E04 0.38J v uD ES05DR (24) " •20 ES1 B• <0.28 20 UW05- Ist • \ ES40 <0.28 MW59 � 0.6J • ES35 <0.28 • DPEW02 MW6 �MW69- 16B� 38.9 UW10 DW01A0�UWo6 (12.1J) ' TO1•' (11.6) •ES28 DW01 UWO� 2 ES23 • \ __ 20" MW58 // �1 ' \ \ ) ., PM..., • <0.28 I /, 2,000 \ l - \ 3,470 . \ DPEWZj\ • 200 I ! / • \ ES32 / \` 1 /P61N,,U2 `\� „�/ j-t DWU< • ES31 <0.28 DNib93:1 1jAS01 MPOC ttPMWO3 T02A1/ PAV'O<}1 PMW08• \ 51.1 ES30 • 20 VE03 ' -- -ES03_ .- — - MW48- 8 08... • -� • 78.7 .._ 78.7 •WOS M •W M47 f\ 97• 20 1 `. 1' \ MW44 -1 ; 1,980 / W37 r' M •< W42 MW39• r • MW50 2.8 _ 028 y W36 <9.28 <M0 288 , ' 04 • MW49� • �4W19 -4 8TT — 02 MW08 2 •<0.28 - _�MW07 • MW55 MW57 • 43.4 MW03W NOTE: Elevated concentrations of MTBE have been observed in a few of the wells within the 2013 and 2014 depiction of the elongated plume dating back to 1999. Additional wells were sampled during the 2013 and 2014 sampling events; therefore, making the plume better defined. \ PMW07 • 14.8 DW03 �.' • 99.5 • MW56 PMW09 •2.7 \ • 0 28 `. MW52 65.6 • MW14R• <0.28 ES25 • <0.28— :I PMW05• 46 PMW047 1• 36.2� PM PMW12 • DW01 • 0.12J (<0.28) J 20 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater MTBE Concentration (ug/I) Groundwater MTBE Concentration (ug/I) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well MTBE Isoconcentration Contour (ug/l) (Dashed where Inferred) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF 'URS RDU, NORTH CAROLINA 27560 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 10. MTBE Isoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT ND. 60393333 DRAYANG NO. FIGURE-10 REV. 0 c Sp.ntemhPr 71 z c. c c 0. a 1 DW06 • <0.34 DW10• • ES13 <0.34 ES29 ES07 <0.34• • ES01• 2.1 •ES17 ES 19., •ES14 0.93J ES0'.L)R )2U i LSDRSI:: ES12 • ES15•. MW12 5.0-- ES10 RWO3 • MW27 DW05 • ES20 0c034 MW20 VE 80 UW05 <0.34• uw044 •ES41 ESI3 MO59 34 • ( • ES35 ' 6 , 27.4J 6▪ 0▪ - •48` DPE . • • - ES32 • DPEW02 M 5 ••. 65I UW08•60Ff T:2 34.3: 6 DWO1A uvula365J• U ,2• 523 , MW21 • •VE,'- 6W365 305 05 VE04-- -(0 75J) • 67 68 10.1 ES23 • • PMWOS• •ES31 <0.34 UYVD9 td E'O ) PMWD3 Tu2A • PMW09 j.i PIvIlVa. <0.34 •MW69 0.52J • •UW06 T , 1.1 •�DW01 <0.34 •UW11-- VE03 W48 68 •M5 - <0.34 0... - MW47 • 6 MW51• 443 ES05D • 0*(ESOS' 24 0.34) ES18• <0.34 E1• eMW42 60 MW44• • 307 MW37 MW39 MW45 ' (5.2)• t A 441 MW18.6 �3) MW49 _- — __ 18 W36• 106 MW B 164— M 23 50 • ES26 ES28 • <0.34 . ES03 ES3O • \ PMWO7 • <0.34 �ES37 • DW02 - MW57 <0.34 • <0.34 - • MW55 �•MWO2 MWO8 _3.0 •<0;347 - •MW0 MWO3W • DWO3 •<0.34 • MW56 \ • MW53. <0.34 - MW52 <0.34 • MW14R• <0.34 ES25 m PMW10 • <0.34 PMWO5• <0.34 PMWO4• <0.34 PMW11• <0.34 PMW12 • 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump DWO1 • Groundwater Monitoring Well 0.12J Groundwater Naphthalene Concentration (ug/l) (<0.34) Groundwater Naphthalene Concentration (ug/1) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well 6 - — — - Naphthalene Isoconcentration Contour (ugh) (Dashed where Inferred) SCALE AS SHOWN DESIGNED BY DATE CONFlDENTW.-ALL RIGHTS RESERVED -PROPERTY OF URS RDU, NORM CAROLEEA 27560 DRAWN BY TSH DATE 19AUG15 CHECKED BY AB DATE 19AUG15 Figure 11. Naphthalene lsoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-11 REV. 0 cc 3 -C rc c C C .1 u u. L L P 47671\5 n a _c c ES1D 0.4- 0.4 ! ES14 •2 DW10• • E 13 <0.32 ES29 ES07 <0.32 • • •ES17 ESO$DR Dsoa F; ES12 • ES15•' / 0 • \ • ES41 MW59 • <0.32 / • ES3 3.0J 0.4 • DPEW02 UW05 - 50.32• • M0.36• •MW67 W08• .,...Scuo2 1:2 'UW04• 4. 0.4 • ES26 -i� ES40 <0.32 ESd3 ES23 • \' MW58 • <0.32 ES33 •<16 DPEW01 • • , ES32 • ES31 <0.32 M' •MW69 - Uyy10 DW01 • 8 W06 <0.32 <0;32'] ' T0,•� <0.32 i ' 'DW01 VE07 - <0.32� • •UW11 MW12 <16' VE03 - • •ES03 ES10 ` RWO�, • MW21 •VE02• - : IAW48 S38 - - ES37• ES01 • MW2 - -- -" - - w2 VE04 0.32 _�W4- _ .a • MW51 •‘ ESO5SR 0.4 4 15.3-- ; ES30 • ES20 <0.32 ES1 •MW42 1 ESO5DR-� ...vim• /. 3:1 •DWOS <0.32 MW39 `fNvu2 W3'7 • M' <0.34• p7 � M,45 0.32 MW41 M •8.. MW38• <0.32 <0.32 <0:32 MW49• • MWO2 MWO8 _0,38_J`M037 •`0.32 •<0.32 MW07 • <0.32 ES18 <0.32 • ES28 • <0.32 ' MW55. • \ PMW08• \ Ph,1\ f I, D':'JvR y DWD _t pock f LZPIV 0 •<0.32 MW57 MW03W / PMWD7 O.6/J 0.4 1 1 1 � `V • PMW09/ 1.Ir1W0G?..1 \ 0.83J • • MW53 <0.32' <032 • MW14R• <0.32 - - ES25 _ PMW05• <0.32 PMW04 <0.32 • PMW11• <0.32 PMW12 • DWO1 • 0.12J (<0.32) 0 50 150 0.40 - - - Legend. Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater 1,2-Dichloroethane Concentration (ugll) Groundwater 1,2-Dichloroethane Concentration (ug/I) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well 1,2-Dichloroethane Isoconcentration Contour (ug/I) (Dashed where Inferred) SCALE AS SHOWN CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF URS RDU, NORM CAROLRU 27580 DESIGNED BY DATE DRAWN BY DATE TSH 19AUG15 CHECKED BY DATE AB 19AUG15 Figure 12. 1 ,2-Dichloroethane Isoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY DATE MN 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-12 REV. 0 c a U C a -c c tr. C -c c c -c c DWO6� •ES14 • ES13,' 20.6 ESOSDF. ESDB' JR' ES12 ES15• UW05 <O.2• MW59 • <0.2 • DPEW02 • MW66 •MW67 0.98J UW080 3T32. • ES35 26.2J • ES26 MW68 �s 5 w. 9.3• DW01A UW06 , UW3,7 1 T01•_�<0.2 • <0.ES228 I I 'DW01 1.9 Wog. _•UW11 -- _. ., VE03 -0- -- ESO3 ES100 MW27• _MW65 VE0228.9 • .MW20 ` .S:SJ• •MWO5 -•MW47 MW26• VE04 - <0.2 ,<0.2 DWO5 • ES20 . •4.4 VE07• -<0.2 - u MW12 35.6J RW03t - MW21 • • MW48 ES38 ESO5DR••5505SR 10.4 - , ES11• ES18, <0.2 W43, ' MW51ij 69.9 •MW42 MW44• 45.6 MW9 RA'O2 W37 -•MW50 <••0.2 • }-: MW45 • <0.2 MW41'I MW 8_MW36•` <0.2- .<0.2 - . -..7.2___ • i. MW49, �h,W19—-.0.25J. MW58 •<0.2 ES33 , t •55.6. DPEW01 ES30 • •ES37 • DWO2 5.7 MWO8 �<0.2 - . MW07 • ES32 Niro O2A MW57 • 0.79J MWO3W PMWO7 • rP;r,IWU2 2.6 OWE SO1 Pr.!WO MW14R• <0.2 PMW11• <0.2 PMW12 • DWO1 • 0.12J (<0.2) 0 50 150 Legend Treeline Fence Line Property Line Railroad Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Sump Groundwater Monitoring Well Groundwater Isopropyl Ether Concentration (ug/I) Groundwater Isopropyl Ether Concentration (ug/I) (Not Used for Contouring) Estimated Value Abandoned Monitoring Well SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -AU. RIGHTS RESERVED -PROPERTY OF URS RDU, NORTH CAROUNA 27560 DRAWN BY TSH DATE 19AUG15 CHECKED BY 'AB DATE 19AUG15 Figure 13. Isopropyl Ether Isoconcentration Map, June 2015 Marathon Charlotte East Terminal APPROVED BY MN DATE 19AUG15 CONTRACT NO. 60393333 DRAWING NO. FIGURE-13 REV. 0 Appendix A Summary of Historical Groundwater Elevation Data Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) AS01 7/1/2002 8.25 751.44 (759.69) 12/29/2003 3.42 3.42 0.00 756.27 1/14/2004 3.45 3.45 0.00 756.24 3/22/2004 3.39 756.30 3/4/2005 3.24 756.45 6/6/2005 3.12 756.57 6/10/2013 2.37 757.32 AS02 7/2/2002 15.45 769.53 (784.98) 1/14/2004 12.87 772.11 DPEW01 9/17/1997 4.21 758.98 (763.19) 6/22/1998 1.21 761.98 12/16/1998 3.03 760.16 1/8/1999 6.05 6.58 0.53 756.61 3/25/1999 1.11 762.08 6/21/1999 1.86 1.86 0.00 761.33 6/21/1999 1.86 1.86 0.00 761.33 12/13/1999 2.52 760.67 6/5/2000 2.98 760.21 12/5/2000 3.55 3.56 0.01 759.63 6/4/2001 3.00 760.19 12/5/2001 5.00 758.19 6/19/2002 3.10 3.10 0.00 760.09 12/16/2002 1.83 761.36 6/4/2003 2.84 2.84 0.00 760.35 12/15/2003 1.10 762.09 1/14/2004 3.62 3.62 0.00 759.57 6/7/2004 2.31 760.88 12/6/2004 1.67 761.52 3/23/2005 1.76 761.43 6/7/2005 1.05 762.14 6/10/2013 0.19 763.00 DPEW02 9/16/1997 6.51 774.67 (781.18) 6/22/1998 5.11 776.07 11/30/1998 7.21 773.97 3/25/1999 6.43 774.75 6/21/1999 5.50 775.68 12/13/1999 7.13 774.05 6/5/2000 5.72 775.46 12/7/2001 7.93 773.25 6/18/2002 6.28 774.90 12/16/2002 5.99 775.19 6/4/2003 3.35 777.83 12/16/2003 6.62 774.56 1/14/2004 5.86 775.32 6/7/2004 6.25 774.93 12/6/2004 5.30 775.88 2/17/2005 5.74 775.44 6/7/2005 4.97 776.21 6/12/2013 2.57 778.61 DW01 3/25/1996 6.10 778.02 6/4/1996 5.72 778.40 10/24/1996 6.30 777.82 1/14/2004 7.21 776.91 2/17/2005 6.28 777.84 6/7/2005 5.09 779.03 11/28/2005 7.31 776.81 6/19/2006 6.39 777.73 8/1/2006 7.69 776.43 12/4/2006 6.19 777.93 6/11/2007 6.82 777.30 12/3/2007 8.70 775.42 6/2/2008 6.62 777.50 12/4/2008 7.53 776.59 6/8/2010 4.75 779.37 12/8/2010 5.50 778.62 6/7/2011 6.06 778.06 12/6/2011 6.34 777.78 6/6/2012 6.42 777.70 12/4/2012 7.92 776.20 6/4/2013 6.11 778.01 12/3/2013 6.88 777.24 6/3/2014 4.76 779.36 12/2/2014 5.40 778.72 6/2/2015 4.79 779.33 DW01A 3/25/1999 6.81 775.69 (782.5) 1/14/2004 5.44 5.44 0.00 777.06 2/17/2005 5.53 776.97 6/7/2005 5.65 776.85 6/12/2013 5.46 777.04 DWO2 3/25/1996 (776.17) 6/4/1996 10/24/1996 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/4/2005 6/6/2005 4.15 3.94 3.50 4.40 5.12 4.81 4.57 5.10 5.03 5.30 4.60 6.24 4.55 4.28 3.51 5.21 7.40 5.27 4.71 4.61 4.45 772.02 772.23 772.67 771.77 771.05 771.36 771.60 771.07 771.14 770.87 771.57 769.93 771.62 771.89 772.66 770.96 768.77 770.90 771.46 771.56 771.72 URS Corporation - North Carolina Page 1 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) DW02 6/19/2006 5.66 770.51 (776.17) 8/1/2006 9.13 767.04 12/4/2006 4.76 771.41 6/11/2007 5.65 770.52 12/3/2007 6.13 770.04 6/2/2008 4.73 771.44 12/4/2008 5.31 770.86 6/2/2009 4.18 771.99 12/8/2009 6.29 769.88 6/8/2010 7.59 768.58 12/8/2010 5.43 770.74 6/7/2011 5.04 771.13 12/6/2011 4.75 771.42 6/7/2012 4.91 771.26 12/4/2012 6.29 769.88 6/5/2013 5.64 770.53 12/3/2013 5.24 770.93 6/3/2014 4.49 771.68 12/2/2014 4.54 771.63 6/4/2015 5.75 770.42 DW03 3/25/1996 8.21 754.07 (762.28) 6/4/1996 8.40 753.88 10/24/1996 7.00 755.28 3/4/1998 8.02 754.26 6/22/1998 8.84 753.44 11/30/1998 10.38 751.90 3/25/1999 8.85 753.43 6/21/1999 8.63 753.65 12/13/1999 9.39 752.89 6/5/2000 9.30 752.98 12/5/2000 11.46 750.82 6/4/2001 8.65 753.63 12/5/2001 11.61 750.67 6/18/2002 11.05 751.23 12/16/2002 7.81 754.47 6/3/2003 7.31 754.97 12/15/2003 9.15 753.13 1/14/2004 9.03 753.25 6/7/2004 9.88 752.40 12/6/2004 8.95 753.33 3/4/2005 8.21 754.07 6/6/2005 2.56 759.72 11/28/2005 10.71 751.57 6/19/2006 8.83 753.45 8/1/2006 9.23 753.05 6/11/2007 9.89 752.39 12/3/2007 11.41 750.87 6/2/2008 8.72 753.56 12/3/2008 9.68 752.60 6/2/2009 8.05 754.23 12/9/2009 8.44 753.84 6/8/2010 7.96 754.32 12/8/2010 10.44 751.84 6/7/2011 9.00 753.28 12/6/2011 9.21 753.07 6/7/2012 8.65 753.63 12/4/2012 11.83 750.45 6/5/2013 8.51 753.77 12/4/2013 10.13 752.15 6/4/2014 8.48 753.80 12/3/2014 8.76 753.52 6/4/2015 9.10 753.18 DW04 6/22/1998 4.05 765.24 (769.29) 11/30/1998 5.43 763.86 3/25/1999 4.19 765.10 6/21/1999 3.97 765.32 12/13/1999 5.25 764.04 6/5/2000 4.75 764.54 12/5/2000 5.55 763.74 6/4/2001 4.41 764.88 12/5/2001 6.03 763.26 6/19/2002 5.34 763.95 6/4/2003 2.32 766.97 1/14/2004 3.21 766.08 3/8/2005 1.92 767.37 3/8/2005 2.67 766.62 DW05 3/25/1999 15.40 771.20 (786.6) 1/14/2004 14.29 772.31 3/7/2005 14.65 771.95 6/6/2005 13.66 772.94 11/28/2005 18.72 767.88 6/19/2006 18.72 767.88 8/1/2006 17.68 768.92 12/4/2006 14.45 772.15 6/11/2007 14.44 772.16 12/3/2007 18.12 768.48 6/2/2008 16.17 770.43 12/3/2008 17.49 769.11 6/4/2009 14.45 772.15 12/9/2009 14.92 771.68 6/8/2010 12.64 773.96 12/7/2010 17.09 769.51 6/7/2011 15.23 771.37 12/6/2011 17.19 769.41 6/6/2012 15.74 770.86 12/4/2012 18.77 767.83 6/5/2013 15.86 770.74 12/3/2013 16.84 769.76 6/4/2014 13.42 773.18 12/3/2014 14.76 771.84 URS Corporation - North Carolina Page 2 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) DWO5 6/3/2015 13.30 773.30 DWO6 3/25/1996 12.66 779.03 (791.69) 6/4/1996 11.85 779.84 6/22/1998 11.20 780.49 11/30/1998 14.54 777.15 3/25/1999 12.24 779.45 6/21/1999 12.54 779.15 12/13/1999 14.35 777.34 6/5/2000 12.74 778.95 12/5/2000 15.33 776.36 6/4/2001 13.28 778.41 12/5/2001 17.11 774.58 6/18/2002 14.58 777.11 12/16/2002 12.63 779.06 6/4/2003 8.03 783.66 12/15/2003 11.76 779.93 1/14/2004 12.24 779.45 6/7/2004 12.71 778.98 12/6/2004 12.40 779.29 3/4/2005 11.38 780.31 6/7/2005 11.19 780.50 11/28/2005 14.07 777.62 6/19/2006 13.18 778.51 8/1/2006 13.34 778.35 12/4/2006 11.58 780.11 6/11/2007 12.48 779.21 12/3/2007 16.13 775.56 6/2/2008 13.13 778.56 12/4/2008 14.30 777.39 6/3/2009 11.54 780.15 12/8/2009 11.67 780.02 6/7/2010 10.40 781.29 12/7/2010 17.84 773.85 6/6/2011 12.25 779.44 12/5/2011 14.17 777.52 6/6/2012 12.22 779.47 12/4/2012 15.99 775.70 6/4/2013 11.98 779.71 12/3/2013 13.84 777.85 6/3/2014 10.29 781.40 12/2/2014 12.04 779.65 6/3/2015 11.13 780.56 DWO7 6/22/1998 3.27 755.41 (758.68) 11/30/1998 3.90 754.78 1/8/1999 3.04 755.64 3/25/1999 3.81 754.87 6/21/1999 3.04 755.64 6/21/1999 3.04 755.64 12/13/1999 3.46 755.22 12/13/1999 3.46 755.22 DWO8 ABANDONED 3/20/15 (759.86) 6/22/1998 3.97 755.89 11/30/1998 4.89 754.97 1/8/1999 3.88 755.98 3/25/1999 3.36 756.50 3/25/1999 3.36 756.50 6/21/1999 3.77 756.09 6/21/1999 3.77 756.09 12/13/1999 3.96 755.90 12/13/1999 3.96 755.90 6/5/2000 4.40 755.46 12/5/2000 5.02 754.84 6/4/2001 4.20 755.66 12/5/2001 6.28 753.58 6/18/2002 5.10 754.76 12/16/2002 3.42 756.44 6/3/2003 2.47 757.39 12/15/2003 2.23 757.63 12/29/2003 3.90 755.96 1/14/2004 3.91 755.95 3/22/2004 3.40 756.46 6/7/2004 4.71 755.15 9/21/2004 3.80 756.06 12/6/2004 3.51 756.35 3/4/2005 2.92 756.94 6/6/2005 3.59 756.27 11/28/2005 4.49 755.37 6/19/2006 3.90 755.96 8/1/2006 3.50 756.36 12/4/2006 2.82 757.04 6/11/2007 4.58 755.28 12/3/2007 5.35 754.51 6/26/2008 3.74 756.12 12/3/2008 3.54 756.32 6/3/2009 2.90 756.96 12/9/2009 2.72 757.14 6/9/2010 2.61 757.25 12/9/2010 4.31 755.55 6/8/2011 3.23 756.63 12/7/2011 3.25 756.61 6/7/2012 2.98 756.88 12/5/2012 5.38 754.48 6/6/2013 2.68 757.18 12/4/2013 3.54 756.32 6/4/2014 2.79 757.07 12/3/2014 3.01 756.85 DWO9 ABANDONED 3/20/15 (760.09) 12/22/1999 3.15 756.94 6/5/2000 3.84 756.25 12/5/2000 4.32 755.77 URS Corporation - North Carolina Page 3 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) DW09 6/4/2001 3.55 756.54 (760.09) 12/5/2001 5.23 754.86 6/18/2002 4.54 755.55 7/1/2002 4.65 755.44 12/16/2002 2.41 757.68 6/3/2003 2.28 757.81 12/15/2003 2.10 757.99 12/29/2003 3.07 757.02 1/14/2004 3.11 756.98 3/22/2004 2.99 757.10 6/7/2004 4.11 755.98 9/21/2004 3.35 756.74 12/6/2004 3.58 756.51 3/4/2005 2.59 757.50 6/7/2005 2.95 757.14 11/28/2005 3.92 756.17 6/19/2006 3.38 756.71 8/1/2006 4.03 756.06 12/4/2006 2.51 757.58 6/11/2007 3.83 756.26 12/3/2007 4.55 755.54 6/26/2008 3.22 756.87 12/3/2008 3.00 757.09 6/3/2009 2.35 757.74 12/9/2009 2.31 757.78 6/9/2010 2.18 757.91 12/9/2010 3.40 756.69 6/8/2011 2.76 757.33 12/7/2011 2.69 757.40 6/7/2012 2.53 757.56 12/5/2012 4.58 755.51 6/6/2013 2.29 757.80 12/4/2013 3.34 756.75 6/4/2014 2.36 757.73 12/3/2014 2.43 757.66 DW10 11/28/2005 14.33 777.16 (791.49) 8/1/2006 14.21 777.28 12/4/2006 12.14 779.35 6/11/2007 12.41 779.08 12/3/2007 14.45 777.04 6/2/2008 13.08 778.41 12/4/2008 14.75 776.74 6/4/2009 11.32 780.17 12/8/2009 11.48 780.01 6/7/2010 11.60 779.89 12/8/2010 14.67 776.82 6/6/2011 12.56 778.93 12/5/2011 14.01 777.48 6/6/2012 12.08 779.41 12/4/2012 15.86 775.63 6/5/2013 11.85 779.64 12/3/2013 13.90 777.59 6/3/2014 9.89 781.60 12/2/2014 11.92 779.57 ES01 3/25/1996 12.70 12.70 0.00 778.68 (791.38) 6/4/1996 14.15 14.15 0.00 777.23 10/24/1996 13.10 13.10 0.00 778.28 3/25/1999 15.31 776.07 6/5/2000 11.20 780.18 1/14/2004 14.41 776.97 3/7/2005 13.65 777.73 6/6/2005 13.72 777.66 11/28/2005 17.62 773.76 6/19/2006 17.97 773.41 12/4/2006 14.17 777.21 6/11/2007 15.11 776.27 12/3/2007 19.39 771.99 6/2/2008 16.34 775.04 12/3/2008 17.63 773.75 6/3/2009 13.34 778.04 12/8/2009 13.17 778.21 6/8/2010 10.95 780.43 12/7/2010 17.76 773.62 6/7/2011 15.13 776.25 12/7/2011 16.64 774.74 6/6/2012 15.15 776.23 12/4/2012 19.80 771.58 6/4/2013 14.14 777.24 12/3/2013 16.86 774.52 6/3/2014 12.09 779.29 12/2/2014 13.49 777.89 6/3/2015 7.02 784.36 ES02 3/25/1996 (770.32) 6/4/1996 10/24/1996 3/4/1998 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 5.85 6.90 5.95 10.62 10.57 10.81 10.74 9.23 9.69 9.43 10.71 9.29 11.82 10.27 9.26 7.63 9.48 9.51 764.47 763.42 764.37 759.70 759.75 759.51 759.58 761.09 760.63 760.89 759.61 761.03 758.50 760.05 761.06 762.69 760.84 760.81 URS Corporation - North Carolina Page 4 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES02 6/7/2004 9.45 760.87 (770.32) 12/6/2004 9.06 761.26 3/4/2005 8.69 761.63 ES03 3/25/1996 8.62 772.64 (781.26) 6/4/1996 9.80 771.46 10/24/1996 7.62 773.64 3/25/1999 6.66 774.60 1/14/2004 7.76 773.50 3/4/2005 6.25 775.01 3/8/2006 7.70 773.56 6/11/2013 5.01 776.25 ESO4 3/25/1996 15.20 776.59 (791.79) 6/4/1996 14.95 776.84 10/24/1996 16.48 775.31 6/22/1998 15.48 776.31 11/30/1998 19.45 772.34 3/25/1999 17.54 774.25 6/21/1999 18.58 773.21 12/13/1999 20.50 771.29 6/5/2000 18.40 773.39 12/5/2000 22.31 769.48 6/4/2001 19.08 772.71 12/5/2001 17.00 774.79 6/18/2002 20.95 770.84 12/16/2002 18.86 772.93 6/4/2003 12.05 779.74 12/15/2003 15.86 775.93 1/14/2004 3.89 787.90 6/7/2004 17.66 774.13 12/6/2004 17.58 774.21 3/7/2005 16.41 775.38 5/24/2005 15.99 775.80 ES05 3/25/1996 10.10 775.67 (785.77) 6/4/1996 11.40 11.70 0.30 774.07 10/24/1996 10.65 10.65 0.00 775.12 2/25/1998 11.04 11.07 0.03 774.70 6/22/1998 10.01 775.76 11/30/1998 13.22 13.88 0.66 771.89 3/25/1999 12.15 12.16 0.01 773.61 6/21/1999 12.80 13.11 0.31 772.66 12/13/1999 14.15 14.45 0.30 771.32 6/5/2000 12.45 12.45 0.00 773.32 12/5/2000 14.80 15.19 0.39 770.58 6/4/2001 13.56 13.69 0.13 772.08 12/7/2001 16.35 16.56 0.21 769.21 6/18/2002 15.18 15.19 0.01 770.58 12/16/2002 13.97 771.80 6/4/2003 9.45 776.32 12/15/2003 11.33 774.44 1/14/2004 11.25 774.52 6/7/2004 11.89 773.88 12/6/2004 7.98 777.79 3/7/2005 8.50 777.27 5/24/2005 10.51 775.26 ESO5DR 5/27/2005 11.36 775.43 (786.79) 6/7/2005 10.67 776.12 11/28/2005 12.94 773.85 6/19/2006 13.55 773.24 8/1/2006 13.45 773.34 12/4/2006 11.32 775.47 6/11/2007 11.54 775.25 12/3/2007 14.95 771.84 6/2/2008 13.04 773.75 12/3/2008 14.35 772.44 6/4/2009 11.39 775.40 12/9/2009 10.21 776.58 6/8/2010 9.80 776.99 12/7/2010 12.72 774.07 6/7/2011 12.42 774.37 12/6/2011 13.94 772.85 6/6/2012 12.97 773.82 12/5/2012 15.08 771.71 6/5/2013 12.31 774.48 12/4/2013 14.56 772.23 6/4/2014 10.14 776.65 12/3/2014 11.05 775.74 6/3/2015 10.18 776.61 ESO5SR 5/27/2005 9.08 777.59 (786.67) 6/7/2005 8.96 777.71 11/28/2005 11.48 775.19 6/19/2006 10.76 775.91 12/4/2006 10.02 776.65 6/11/2007 9.77 776.90 12/3/2007 12.83 773.84 6/2/2008 11.19 775.48 12/3/2008 12.35 774.32 6/4/2009 9.82 776.85 12/9/2009 12.01 774.66 6/8/2010 9.28 777.39 12/7/2010 11.93 774.74 6/6/2011 10.23 776.44 12/6/2011 11.94 774.73 6/6/2012 10.63 776.04 12/4/2012 13.01 773.66 6/5/2013 10.59 776.08 12/4/2013 11.66 775.01 6/4/2014 8.86 777.81 12/3/2014 9.75 776.92 6/3/2015 8.25 778.42 ES06 3/26/1996 16.35 16.35 0.00 773.59 URS Corporation - North Carolina Page 5 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES06 6/4/1996 11.70 15.14 3.44 774.80 (789.94) 10/24/1996 16.95 772.99 2/25/1998 14.70 775.24 6/22/1998 15.44 774.50 11/30/1998 19.23 770.71 3/25/1999 17.85 772.09 6/21/1999 18.81 771.13 12/13/1999 20.47 769.47 6/5/2000 18.36 771.58 12/5/2000 21.20 768.74 6/4/2001 19.50 770.44 12/5/2001 22.59 767.35 6/19/2002 20.94 769.00 12/16/2002 19.55 770.39 6/4/2003 13.36 776.58 12/15/2003 16.23 773.71 1/14/2004 16.51 773.43 6/7/2004 17.56 772.38 12/6/2004 17.79 772.15 3/7/2005 17.05 772.89 5/24/2005 16.24 773.70 ES07 3/26/1996 10.25 780.98 (791.23) 6/4/1996 10.55 780.68 10/24/1996 9.00 782.23 3/25/1999 11.71 779.52 12/29/2003 11.19 780.04 1/14/2004 11.67 779.56 3/22/2004 10.80 780.43 3/4/2005 10.90 780.33 3/7/2006 11.60 779.63 6/12/2013 10.62 780.61 ES08 3/26/1996 11.05 779.51 (790.56) 6/4/1996 10.80 10.80 0.00 779.76 10/24/1996 11.15 779.41 9/16/1997 11.27 779.29 6/22/1998 10.37 780.19 11/30/1998 12.56 778.00 3/25/1999 11.45 779.11 6/21/1999 8.69 781.87 12/13/1999 12.00 778.56 6/5/2000 11.31 779.25 12/5/2000 13.10 777.46 6/4/2001 12.13 778.43 12/5/2001 14.47 776.09 6/18/2002 12.70 777.86 12/16/2002 11.82 778.74 6/4/2003 8.75 781.81 12/15/2003 10.67 779.89 1/14/2004 11.34 779.22 6/7/2004 11.33 779.23 12/6/2004 11.22 779.34 2/15/2005 11.73 778.83 ES08DR 5/27/2005 20.51 772.19 (792.7) 6/7/2005 10.71 781.99 11/28/2005 12.89 779.81 6/19/2006 12.47 780.23 8/1/2006 12.38 780.32 12/4/2006 11.27 781.43 6/11/2007 11.72 780.98 12/3/2007 14.50 778.20 6/2/2008 12.42 780.28 ES08SR 5/27/2005 10.72 778.39 (789.11) 6/7/2005 10.44 778.67 11/28/2005 12.32 776.79 6/19/2006 12.32 776.79 12/4/2006 11.24 777.87 6/11/2007 11.51 777.60 12/3/2007 13.56 775.55 6/2/2008 11.88 777.23 ES09 3/26/1996 9.20 9.20 0.00 778.84 (788.04) 6/4/1996 9.64 778.40 10/24/1996 10.82 777.22 9/16/1997 11.27 776.77 3/25/1999 10.78 777.26 6/5/2000 10.80 777.24 1/14/2004 10.65 777.39 2/18/2005 10.78 777.26 ES10 3/26/1996 7.65 783.71 (791.36) 6/4/1996 7.70 783.66 10/24/1996 9.10 9.10 0.00 782.26 6/22/1998 7.90 783.46 11/30/1998 10.80 780.56 3/25/1999 4.65 786.71 6/21/1999 9.88 781.48 12/13/1999 11.30 780.06 6/5/2000 9.85 781.51 12/5/2000 11.56 779.80 6/4/2001 10.42 780.94 12/5/2001 13.31 778.05 6/18/2002 11.10 780.26 12/16/2002 10.11 781.25 6/4/2003 6.45 784.91 12/15/2003 8.94 782.42 1/14/2004 9.17 782.19 6/7/2004 9.68 781.68 12/6/2004 9.40 781.96 3/7/2005 9.41 781.95 6/7/2005 8.41 782.95 6/11/2013 9.16 782.20 ES11 3/26/1996 11.14 11.14 0.00 774.19 URS Corporation - North Carolina Page 6 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES11 6/4/1996 11.15 11.15 0.00 774.18 (785.33) 10/24/1996 11.10 11.10 0.00 774.23 6/5/2000 9.97 775.36 1/14/2004 9.90 775.43 3/7/2005 9.95 775.38 3/22/2005 9.55 775.78 12/9/2009 9.62 775.71 6/11/2013 9.74 775.59 ES12 3/26/1996 9.95 9.95 0.00 781.81 (791.76) 6/4/1996 9.55 782.21 10/24/1996 10.35 10.35 0.00 781.41 6/22/1998 10.10 781.66 11/30/1998 13.18 778.58 3/25/1999 11.30 780.46 6/21/1999 7.62 784.14 12/13/1999 13.35 778.41 6/5/2000 11.61 780.15 12/5/2000 14.00 777.76 6/4/2001 12.36 779.40 12/5/2001 15.54 776.22 6/18/2002 13.55 778.21 12/16/2002 12.47 779.29 6/4/2003 9.84 781.92 12/15/2003 11.35 780.41 1/14/2004 11.61 780.15 2/15/2004 11.78 779.98 6/7/2004 11.68 780.08 12/6/2004 11.77 779.99 6/7/2005 10.35 781.41 6/12/2013 11.12 780.64 ES13 3/26/1996 10.90 780.93 (791.83) 6/4/1996 11.92 11.92 0.00 779.91 10/24/1996 11.40 780.43 2/27/1998 9.66 782.17 6/22/1998 11.24 780.59 11/30/1998 14.62 777.21 3/25/1999 12.35 779.48 6/21/1999 12.34 779.49 12/13/1999 14.51 777.32 6/5/2000 12.81 779.02 12/5/2000 15.42 776.41 6/4/2001 13.36 778.47 12/5/2001 17.21 774.62 6/18/2002 14.66 777.17 12/16/2002 12.81 779.02 6/4/2003 8.19 783.64 12/15/2003 11.82 780.01 1/14/2004 12.35 779.48 6/7/2004 12.77 779.06 12/6/2004 12.51 779.32 3/4/2005 11.58 780.25 6/7/2005 11.10 780.73 11/28/2005 14.14 777.69 6/19/2006 13.25 778.58 12/4/2006 11.66 780.17 6/11/2007 12.55 779.28 12/3/2007 16.23 775.60 6/2/2008 13.19 778.64 12/4/2008 14.52 777.31 6/4/2009 11.58 780.25 12/8/2009 11.81 780.02 6/7/2010 10.46 781.37 12/7/2010 14.96 776.87 6/6/2011 12.32 779.51 12/5/2011 14.31 777.52 6/6/2012 12.29 779.54 12/4/2012 16.10 775.73 6/4/2013 12.10 779.73 12/3/2013 13.94 777.89 6/3/2014 10.36 781.47 12/2/2014 12.16 779.67 6/3/2015 11.11 780.72 ES14 3/26/1996 10.35 10.35 0.00 780.35 (790.7) 6/4/1996 10.66 10.66 0.00 780.04 10/24/1996 11.22 779.48 9/16/1997 11.11 779.59 6/22/1998 10.50 780.20 11/30/1998 12.51 778.19 3/25/1999 11.60 779.10 6/21/1999 10.03 780.67 12/13/1999 12.75 777.95 6/5/2000 11.29 779.41 12/5/2000 13.28 777.42 6/4/2001 12.13 778.57 12/5/2001 14.58 776.12 6/18/2002 12.78 777.92 12/16/2002 12.39 778.31 6/4/2003 9.05 781.65 12/15/2003 10.71 779.99 1/14/2004 11.27 779.43 6/7/2004 11.21 779.49 12/6/2004 11.36 779.34 2/15/2005 11.77 778.93 6/7/2005 10.42 780.28 11/28/2005 12.29 778.41 6/19/2006 11.60 779.10 12/4/2006 11.25 779.45 6/11/2007 11.26 779.44 12/3/2007 13.49 777.21 6/2/2008 11.63 779.07 URS Corporation - North Carolina Page 7 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES14 12/4/2008 12.59 778.11 (790.7) 6/2/2009 9.71 780.99 12/8/2009 10.25 780.45 6/7/2010 9.49 781.21 12/9/2010 12.02 778.68 6/6/2011 10.48 780.22 12/5/2011 11.51 779.19 6/6/2012 9.89 780.81 12/4/2012 12.83 777.87 6/4/2013 9.82 780.88 12/3/2013 11.15 779.55 6/3/2014 8.28 782.42 12/2/2014 9.78 780.92 6/3/2015 9.26 781.44 ES15 3/26/1996 7.08 783.17 (790.25) 6/4/1996 7.05 783.20 10/24/1996 7.25 783.00 9/16/1997 9.51 780.74 3/25/1999 9.02 781.23 12/29/2003 9.38 780.87 1/14/2004 9.72 780.53 3/22/2004 9.07 781.18 3/7/2005 9.13 781.12 6/12/2013 8.19 782.06 ES16 3/26/1996 6.95 783.30 (790.25) 6/4/1996 9.60 780.65 10/24/1996 6.55 783.70 2/27/1998 9.85 780.40 1/14/2004 11.21 779.04 5/24/2005 10.50 779.75 ES17 3/26/1996 18.01 773.46 (791.47) 6/4/1996 18.35 773.12 10/24/1996 18.75 772.72 3/25/1999 18.16 773.31 6/5/2000 19.18 772.29 12/5/2000 22.13 769.34 1/14/2004 17.02 774.45 2/18/2005 18.55 772.92 3/7/2006 18.30 773.17 ES18 3/26/1996 10.90 775.41 (786.31) 6/5/1996 14.58 771.73 10/24/1996 10.93 775.38 2/25/1998 11.83 774.48 3/25/1999 14.43 771.88 1/14/2004 13.42 772.89 3/7/2005 13.80 772.51 3/22/2005 13.27 773.04 11/28/2005 16.21 770.10 6/19/2006 15.42 770.89 12/4/2006 13.60 772.71 6/11/2007 13.91 772.40 12/3/2007 17.58 768.73 6/2/2008 15.60 770.71 12/3/2008 16.34 769.97 6/3/2009 13.84 772.47 12/8/2009 13.59 772.72 6/8/2010 12.35 773.96 12/8/2010 16.28 770.03 6/6/2011 14.57 771.74 12/7/2011 16.27 770.04 6/6/2012 14.84 771.47 12/4/2012 18.04 768.27 6/5/2013 14.70 771.61 12/3/2013 15.90 770.41 6/4/2014 11.92 774.39 12/3/2014 13.96 772.35 6/3/2015 12.67 773.64 ES19 3/26/1996 14.05 781.08 (795.13) 6/6/1996 16.01 779.12 10/24/1996 14.53 780.60 2/27/1998 13.11 782.02 6/22/1998 14.80 780.33 11/30/1998 18.46 776.67 3/25/1999 15.94 779.19 6/21/1999 16.68 778.45 12/13/1999 18.34 776.79 6/5/2000 16.40 778.73 12/5/2000 19.39 775.74 6/4/2001 19.37 775.76 12/5/2001 21.11 774.02 6/18/2002 18.53 776.60 12/16/2002 16.84 778.29 6/4/2003 10.50 784.63 12/15/2003 16.67 778.46 1/14/2004 15.94 779.19 6/7/2004 16.31 778.82 12/6/2004 16.29 778.84 3/4/2005 15.05 780.08 6/7/2005 14.91 780.22 11/28/2005 18.02 777.11 6/19/2006 13.67 781.46 12/4/2006 12.05 783.08 6/11/2007 12.66 782.47 12/3/2007 16.37 778.76 6/2/2008 13.28 781.85 ES20 3/26/1996 (787.36) 6/3/1996 10/24/1996 3/25/1999 6/5/2000 7.98 14.65 14.42 15.89 16.35 779.38 772.71 772.94 771.47 771.01 URS Corporation - North Carolina Page 8 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES20 12/5/2000 19.12 768.24 (787.36) 1/14/2004 14.56 772.80 3/7/2005 15.15 772.21 3/7/2006 15.85 771.51 6/11/2013 15.24 772.12 ES21 3/26/1996 12.67 779.92 (792.59) 6/3/1996 14.60 777.99 10/24/1996 12.60 779.99 2/25/1998 9.71 782.88 3/25/1999 14.40 778.19 6/5/2000 15.06 777.53 12/5/2000 DRY DRY 1/14/2004 14.50 778.09 ES23 9/17/1997 5.02 759.36 (764.38) 6/22/1998 3.66 760.72 11/30/1998 4.66 759.72 1/8/1999 3.65 760.73 3/25/1999 3.76 760.62 6/21/1999 3.40 760.98 6/21/1999 3.40 760.98 12/13/1999 3.75 760.63 12/13/1999 3.75 760.63 6/5/2000 3.80 760.58 12/5/2000 4.05 760.33 6/4/2001 3.21 761.17 12/5/2001 6.45 757.93 6/18/2002 4.15 760.23 12/16/2002 3.25 761.13 6/4/2003 3.68 760.70 12/15/2003 2.40 761.98 1/14/2004 3.60 760.78 6/7/2004 3.72 760.66 12/6/2004 3.45 760.93 2/17/2005 1.88 762.50 6/6/2005 1.66 762.72 6/10/2013 0.54 763.84 ES25 3/26/1996 4.12 750.57 (754.69) 6/5/1996 4.50 750.19 3/4/1998 4.53 750.16 6/22/1998 6.55 748.14 11/30/1998 9.01 745.68 3/25/1999 5.29 749.40 6/21/1999 6.13 748.56 12/13/1999 12.01 742.68 6/5/2000 8.99 745.70 12/5/2000 13.50 741.19 6/4/2001 5.45 749.24 12/5/2001 8.90 745.79 6/19/2002 8.95 8.95 0.00 745.74 12/16/2002 5.84 5.85 0.01 748.84 6/4/2003 5.15 749.54 12/15/2003 2.96 751.73 1/14/2004 3.73 750.96 6/7/2004 4.26 750.43 12/6/2004 5.25 749.44 2/18/2005 3.88 750.81 6/7/2005 3.21 751.48 11/28/2005 3.92 750.77 12/4/2006 5.97 748.72 6/11/2007 6.21 748.48 12/3/2007 SHEEN 9.25 SHEEN 745.44 6/2/2008 4.88 749.81 12/3/2008 4.39 750.30 6/2/2009 3.17 751.52 12/8/2009 4.95 749.74 6/8/2010 3.82 750.87 12/8/2010 7.49 747.20 6/6/2011 5.34 749.35 12/7/2011 6.45 748.24 6/6/2012 4.30 750.39 12/4/2012 8.69 746.00 6/5/2013 5.26 749.43 12/4/2013 7.14 747.55 6/4/2014 7.75 746.94 12/3/2014 10.01 744.68 6/3/2015 9.11 745.58 ES26 9/16/1997 (777.81) 6/22/1998 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/8/2005 6/6/2005 11/28/2005 6/19/2006 8/1/2006 6/11/2007 12/3/2007 10.26 9.73 10.35 10.00 9.67 10.22 9.92 10.33 9.67 10.85 9.93 9.46 9.16 7.97 10.18 10.08 9.84 9.61 9.43 10.08 9.53 9.59 10.18 10.64 767.55 768.08 767.46 767.81 768.14 767.59 767.89 767.48 768.14 766.96 767.88 768.35 768.65 769.84 767.63 767.73 767.97 768.20 768.38 767.73 768.28 768.22 767.63 767.17 URS Corporation - North Carolina Page 9 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES26 6/2/2008 9.73 768.08 (777.81) 12/4/2008 9.63 768.18 6/4/2009 9.44 768.37 12/8/2009 9.69 768.12 6/7/2010 9.17 768.64 12/7/2010 9.95 767.86 6/7/2011 9.68 768.13 12/6/2011 9.73 768.08 6/6/2012 9.61 768.20 12/3/2012 10.85 766.96 6/4/2013 9.37 768.44 12/3/2013 9.93 767.88 6/3/2014 9.49 768.32 12/2/2014 9.49 768.32 ES28 3/25/1999 2.81 771.20 (774.01) 1/14/2004 3.23 770.78 3/8/2005 2.43 771.58 6/7/2005 2.11 771.90 6/11/2013 1.66 772.35 6/3/2014 2.14 771.87 12/2/2014 2.55 771.46 6/2/2015 4.58 769.43 ES29 6/22/1998 10.71 780.66 (791.37) 11/30/1998 14.13 777.24 3/25/1999 11.88 779.49 6/21/1999 12.18 779.19 12/13/1999 14.04 777.33 6/5/2000 12.34 779.03 12/5/2000 15.95 775.42 6/4/2001 12.82 778.55 12/5/2001 17.72 773.65 6/18/2002 14.14 777.23 12/16/2002 12.26 779.11 6/4/2003 7.66 783.71 12/15/2003 11.32 780.05 1/14/2004 11.86 779.51 6/7/2004 12.31 779.06 12/6/2004 12.00 779.37 3/4/2005 11.00 780.37 6/6/2005 10.65 780.72 11/28/2005 13.66 777.71 6/19/2006 12.72 778.65 12/4/2006 12.05 779.32 6/11/2007 12.04 779.33 12/3/2007 15.75 775.62 6/2/2008 12.73 778.64 12/4/2008 14.05 777.32 6/4/2009 11.08 780.29 12/8/2009 11.20 780.17 6/7/2010 10.25 781.12 12/7/2010 14.48 14.49 0.01 776.88 6/6/2011 11.83 779.54 12/5/2011 13.85 777.52 6/6/2012 11.84 779.53 12/4/2012 15.62 775.75 6/4/2013 11.62 779.75 12/3/2013 13.50 777.87 6/3/2014 9.84 781.53 12/2/2014 11.70 779.67 6/3/2015 10.62 780.75 ES30 6/22/1998 6.16 762.05 (768.21) 11/30/1998 7.49 760.72 3/25/1999 6.50 761.71 6/21/1999 5.98 762.23 12/13/1999 6.55 761.66 6/5/2000 7.55 760.66 12/5/2000 7.84 760.37 6/4/2001 5.82 762.39 12/5/2001 8.33 759.88 6/18/2002 7.27 760.94 12/16/2002 6.21 762.00 6/4/2003 7.43 760.78 12/15/2003 6.29 761.92 1/14/2004 6.68 761.53 6/7/2004 6.33 761.88 12/6/2004 6.25 761.96 2/18/2005 6.52 761.69 11/28/2005 7.60 760.61 6/6/2006 4.83 763.38 6/11/2013 5.16 763.05 ES31 9/16/1997 (779.22) 9/17/1997 3/25/1999 1/14/2004 2/15/2005 6/7/2005 11/28/2005 6/19/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 12/4/2008 6/2/2009 12/8/2009 6/7/2010 12/7/2010 6/6/2011 12/5/2011 6/6/2012 12.52 12.54 11.91 11.95 11.30 10.60 12.90 11.36 10.71 11.72 12.65 9.81 10.68 8.45 9.19 8.11 11.64 9.63 10.13 9.20 766.70 766.68 767.31 767.27 767.92 768.62 766.32 767.86 768.51 767.50 766.57 769.41 768.54 770.77 770.03 771.11 767.58 769.59 769.09 770.02 URS Corporation - North Carolina Page 10 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES31 12/3/2012 12.62 766.60 (779.22) 6/4/2013 7.36 771.86 12/2/2013 11.15 768.07 6/3/2014 8.61 770.61 12/2/2014 9.69 769.53 6/2/2015 9.88 769.34 ES32 9/17/1997 5.69 757.25 (762.94) 1/8/1999 4.84 5.32 0.48 757.62 3/25/1999 4.58 4.93 0.35 758.01 12/13/1999 4.91 5.27 0.36 757.67 12/16/1999 4.91 5.27 0.36 757.67 6/5/2000 5.61 757.33 12/5/2000 5.92 6.14 0.22 756.80 6/4/2001 5.68 5.83 0.15 757.11 12/5/2001 7.40 7.73 0.33 755.21 3/23/2002 4.21 758.73 6/19/2002 6.36 6.39 0.03 756.55 12/16/2002 5.83 757.11 6/4/2003 4.85 4.85 0.00 758.09 12/15/2003 4.91 758.03 1/14/2004 5.52 5.52 0.00 757.42 6/7/2004 6.00 756.94 9/21/2004 5.42 757.52 12/6/2004 5.16 757.78 6/7/2005 4.91 758.03 11/28/2005 6.14 756.80 6/19/2006 5.60 757.34 12/4/2006 4.21 758.73 6/2/2009 1.27 761.67 12/8/2009 2.23 760.71 6/7/2010 8.08 754.86 12/8/2010 5.38 757.56 6/6/2011 3.70 759.24 12/5/2011 4.45 758.49 6/6/2012 3.78 759.16 12/3/2012 6.15 756.79 6/6/2013 3.66 759.28 12/2/2013 4.16 758.78 6/3/2014 0.47 762.47 12/2/2014 3.78 759.16 6/2/2015 3.82 759.12 ES33 9/17/1997 3.50 759.83 (763.33) 6/22/1998 1.35 761.98 11/30/1998 3.27 760.06 1/8/1999 2.41 760.92 3/25/1999 2.58 2.59 0.01 760.74 6/21/1999 2.62 760.71 6/21/1999 2.62 760.71 12/13/1999 2.85 760.48 12/13/1999 2.85 760.48 6/5/2000 2.70 760.63 12/5/2000 3.46 3.47 0.01 759.86 6/4/2001 2.65 760.68 12/5/2001 5.03 758.30 6/19/2002 3.27 3.27 0.00 760.06 12/16/2002 2.63 760.70 6/4/2003 2.39 760.94 12/15/2003 2.39 760.94 1/14/2004 2.61 760.72 6/7/2004 2.81 760.52 12/6/2004 2.49 760.84 2/15/2005 2.69 760.64 3/23/2005 2.43 760.90 6/7/2005 1.95 761.38 11/28/2005 3.54 759.79 6/19/2006 3.53 759.80 12/4/2006 2.06 761.27 6/11/2007 2.93 760.40 12/3/2007 3.47 759.86 6/2/2008 1.59 761.74 12/4/2008 1.71 761.62 6/2/2009 1.15 762.18 12/8/2009 2.59 760.74 6/7/2010 1.61 761.72 12/7/2010 3.45 759.88 6/6/2011 0.88 762.45 12/5/2011 1.02 762.31 6/6/2012 0.81 762.52 12/3/2012 3.61 759.72 6/6/2013 0.74 762.59 12/2/2013 2.52 760.81 6/3/2014 0.90 762.43 12/2/2014 1.23 762.10 6/2/2015 1.00 762.33 ES34 6/22/1998 (777.18) 11/30/1998 6/21/1999 12/16/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 6/7/2005 1.92 4.95 2.62 7.77 2.41 5.34 3.34 7.11 3.76 3.65 1.41 2.97 3.58 2.45 2.81 1.12 775.26 772.23 774.56 769.41 774.77 771.84 773.84 770.07 773.42 773.53 775.77 774.21 773.60 774.73 774.37 776.06 URS Corporation - North Carolina Page 11 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES34 11/28/2005 4.94 772.24 (777.18) 6/19/2006 3.02 774.16 12/4/2006 2.06 775.12 6/2/2009 1.55 775.63 12/8/2009 2.55 774.63 6/7/2010 0.85 776.33 12/7/2010 2.89 774.29 6/6/2011 1.12 776.06 12/5/2011 1.90 775.28 6/6/2012 0.96 776.22 12/3/2012 4.52 772.66 6/4/2013 0.92 776.26 12/2/2013 2.65 774.53 6/3/2014 0.78 776.40 12/2/2014 1.72 775.46 6/2/2015 1.39 775.79 ES35 6/22/1998 1.35 773.39 (774.74) 11/30/1998 6.72 768.02 3/25/1999 4.40 770.34 6/21/1999 4.93 769.81 12/13/1999 5.87 768.87 6/5/2000 4.55 770.19 12/5/2000 7.26 767.48 6/4/2001 5.05 769.69 12/5/2001 8.50 766.24 6/18/2002 5.59 769.15 12/16/2002 4.25 770.49 6/4/2003 1.32 773.42 12/15/2003 1.59 773.15 1/14/2004 4.58 770.16 6/7/2004 4.57 770.17 12/6/2004 4.23 770.51 2/15/2005 3.65 771.09 3/23/2005 3.69 771.05 6/7/2005 3.38 771.36 11/28/2005 6.21 768.53 6/19/2006 3.71 771.03 12/4/2006 3.40 771.34 6/11/2007 4.19 770.55 12/3/2007 5.80 768.94 6/2/2008 3.18 771.56 12/4/2008 4.09 770.65 6/2/2009 4.09 770.65 12/8/2009 2.72 772.02 6/7/2010 2.11 772.63 12/7/2010 4.59 770.15 6/6/2011 2.88 771.86 12/5/2011 3.43 771.31 6/6/2012 2.89 771.85 12/3/2012 5.96 768.78 6/4/2013 2.43 772.31 12/2/2013 4.47 770.27 6/3/2014 2.09 772.65 12/2/2014 2.96 771.78 6/2/2015 2.26 772.48 ES36 9/16/1997 9.10 773.73 (782.83) 3/25/1999 8.58 774.25 ES37 6/22/1998 4.87 773.01 (777.88) 11/30/1998 6.11 771.77 3/25/1999 5.22 772.66 6/21/1999 4.38 773.50 12/13/1999 6.01 771.87 6/5/2000 5.99 771.89 12/5/2000 5.73 772.15 6/4/2001 4.18 773.70 12/5/2001 7.20 770.68 6/18/2002 5.39 772.49 12/16/2002 4.23 773.65 6/4/2003 2.31 775.57 12/15/2003 2.25 775.63 1/14/2004 6.19 771.69 6/7/2004 6.39 771.49 12/6/2004 5.50 772.38 3/4/2005 4.84 773.04 6/6/2005 2.22 775.66 6/11/2013 2.47 775.41 ES38 6/22/1998 (782.6) 11/30/1998 3/25/1999 6/21/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/4/2003 12/15/2003 1/14/2004 6/7/2004 12/6/2004 3/4/2005 6/6/2005 11/28/2005 6/19/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 7.21 8.04 6.29 6.70 6.96 7.14 8.01 6.25 8.82 7.55 6.37 5.75 6.30 8.18 7.55 7.07 6.88 6.47 7.66 5.74 6.87 8.17 8.99 6.75 775.39 774.56 776.31 775.90 775.64 775.46 774.59 776.35 773.78 775.05 776.23 776.85 776.30 774.42 775.05 775.53 775.72 776.13 774.94 776.86 775.73 774.43 773.61 775.85 URS Corporation - North Carolina Page 12 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) ES38 12/4/2008 6.94 775.66 (782.6) 6/3/2009 6.91 775.69 12/9/2009 5.99 776.61 6/8/2010 6.16 776.44 12/8/2010 7.80 774.80 6/7/2011 6.81 775.79 12/6/2011 7.47 775.13 6/6/2012 6.18 776.42 12/4/2012 9.71 772.89 6/4/2013 7.40 775.20 12/3/2013 7.32 775.28 6/3/2014 6.58 776.02 12/2/2014 5.84 776.76 6/2/2015 8.66 773.94 ES39 2/27/1998 1.89 779.99 (781.88) 3/25/1999 6.13 775.75 1/14/2004 6.21 775.67 3/4/2005 4.79 777.09 6/7/2005 5.64 776.24 11/28/2005 DRY DRY ES40 3/25/1999 6.15 773.32 (779.47) 1/14/2004 6.55 772.92 2/15/2005 5.87 773.60 6/7/2005 5.97 773.50 11/28/2005 9.71 769.76 6/19/2006 7.06 772.41 12/4/2006 5.61 773.86 6/11/2007 7.33 772.14 12/3/2007 8.27 771.20 6/2/2008 5.04 774.43 12/4/2008 6.14 773.33 6/2/2009 4.59 774.88 12/8/2009 5.05 774.42 6/7/2010 4.37 775.10 12/7/2010 6.05 773.42 6/6/2011 4.71 774.76 12/5/2011 5.31 774.16 6/6/2012 4.45 775.02 12/3/2012 7.76 771.71 6/4/2013 4.77 774.70 12/2/2013 5.48 773.99 6/3/2014 4.58 774.89 12/2/2014 5.02 774.45 6/2/2015 5.05 774.42 ES41 3/25/1999 8.42 776.18 (784.6) 1/14/2004 8.66 775.94 2/15/2005 6.21 778.39 6/7/2005 8.23 776.37 12/3/2007 12.45 772.15 6/2/2008 8.88 775.72 12/4/2008 6/10/2013 10.40 774.20 4.27 780.33 ES42 9/17/1997 11.17 763.60 (774.77) 6/22/1998 9.96 764.81 11/30/1998 12.06 762.71 3/25/1999 10.04 764.73 6/21/1999 10.53 764.24 12/13/1999 11.72 763.05 6/5/2000 10.40 764.37 12/5/2000 12.05 762.72 6/4/2001 10.80 763.97 12/5/2001 DRY DRY 6/18/2002 11.24 763.53 12/16/2002 10.83 763.94 6/4/2003 9.54 765.23 12/15/2003 10.88 763.89 1/14/2004 10.68 764.09 6/7/2004 10.27 764.50 12/6/2004 10.55 764.22 2/15/2005 9.92 764.85 3/23/2005 9.06 765.71 6/7/2005 9.26 765.51 11/28/2005 DRY DRY ES43 3/25/1999 10.27 766.91 (777.18) 1/14/2004 10.29 766.89 2/15/2005 13.10 764.08 6/7/2005 10.71 766.47 6/10/2013 9.18 768.00 ES44 2/27/1998 11.29 778.93 (790.22) 3/25/1999 13.26 776.96 1/14/2004 14.41 775.81 2/15/2005 13.10 777.12 6/7/2005 12.59 777.63 MPO1 9/17/1997 3.16 759.94 (763.1) 1/8/1999 2.36 760.74 3/25/1999 2.33 760.77 6/5/2000 2.52 760.58 1/14/2004 2.25 760.85 2/17/2005 2.17 760.93 3/23/2005 1.77 761.33 MPO2 9/17/1997 4.52 758.67 (763.19) 1/8/1999 3.12 760.07 3/25/1999 2.86 760.33 6/5/2000 2.25 760.94 1/14/2004 1.81 761.38 5/25/2005 1.05 762.14 MPO3 9/17/1997 3.00 (763.1) 1/8/1999 4.05 4.06 0.01 6/5/2000 2.26 1/14/2004 2.52 2.52 0.00 760.10 759.04 760.84 760.58 URS Corporation - North Carolina Page 13 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) WeII Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MP03 5/23/2005 2.15 760.95 MP04 9/16/1997 10.98 770.30 (781.28) 3/25/1999 5.30 775.98 MP05 9/16/1997 5.82 774.14 (779.96) 3/25/1999 5.35 774.61 1/14/2004 5.43 774.53 2/18/2005 5.31 774.65 5/24/2005 3.53 776.43 MPO6 7/1/2002 4.20 755.22 (759.42) 12/29/2003 3.06 3.06 0.00 756.36 1/14/2004 3.09 3.09 0.00 756.33 3/22/2004 4.00 755.42 3/4/2005 3.16 756.26 6/6/2005 2.74 756.68 6/12/2013 2.05 757.37 MW02 3/26/1996 10.32 771.05 (781.37) 6/4/1996 10.95 770.42 10/24/1996 10.56 10.56 0.00 770.81 6/22/1998 10.22 771.15 11/30/1998 12.27 769.10 3/25/1999 11.47 769.90 6/21/1999 11.62 769.75 12/13/1999 12.57 768.80 6/5/2000 11.48 769.89 12/5/2000 13.10 768.27 6/4/2001 12.30 769.07 12/5/2001 14.61 766.76 6/19/2002 13.19 768.18 12/16/2002 11.57 769.80 6/4/2003 8.23 773.14 12/15/2003 10.90 770.47 1/14/2004 11.42 769.95 6/7/2004 11.77 769.60 12/6/2004 11.07 770.30 3/8/2005 10.41 770.96 6/7/2005 9.07 772.30 11/28/2005 11.23 770.14 1/24/2006 9.95 771.42 (780.28) 2/23/2006 9.79 770.49 3/7/2006 10.70 769.58 6/19/2006 10.58 769.70 8/1/2006 10.13 770.15 8/15/2006 10.89 769.39 9/25/2006 9.19 771.09 11/2/2006 9.81 770.47 12/4/2006 9.24 771.04 6/11/2007 10.28 770.00 (781.37) 12/3/2007 12.74 768.63 6/2/2008 10.72 770.65 12/3/2008 10.96 770.41 6/2/2009 9.10 772.27 12/8/2009 9.05 772.32 6/8/2010 7.83 773.54 12/8/2010 11.59 769.78 6/7/2011 9.63 771.74 12/7/2011 10.45 770.92 6/6/2012 9.95 771.42 12/4/2012 12.63 768.74 6/5/2013 9.77 771.60 12/4/2013 11.45 769.92 6/4/2014 8.30 773.07 12/3/2014 8.95 772.42 6/3/2015 8.37 773.00 MW03W 3/25/1996 5.62 763.59 (769.21) 3/4/1998 3.91 765.30 3/25/1999 4.17 765.04 12/16/2002 3.22 765.99 12/15/2003 3.71 765.50 1/14/2004 3.03 766.18 6/7/2004 2.82 766.39 12/6/2004 1.55 767.66 3/8/2005 1.27 767.94 6/6/2005 1.68 767.53 11/28/2005 3.60 765.61 6/11/2013 0.50 768.71 MW04R 3/4/1998 4.12 750.82 (754.94) 3/4/1998 4.12 750.82 3/25/1999 7.88 747.06 1/14/2004 3.52 751.42 3/4/2005 6.91 748.03 6/6/2005 2.71 752.23 8/29/2005 8.61 746.33 MW05 3/25/1996 6.93 6.93 0.00 779.72 (786.65) 6/6/1996 9.10 777.55 10/24/1996 7.00 7.00 0.00 779.65 3/25/1999 8.43 778.22 1/14/2004 8.48 778.17 3/7/2005 8.69 777.96 6/7/2005 7.55 779.10 11/28/2005 9.78 776.87 6/19/2006 8.97 777.68 12/4/2006 8.11 778.54 6/11/2007 8.85 777.80 12/3/2007 11.27 775.38 6/2/2008 9.50 777.15 12/4/2008 9.22 777.43 6/4/2009 7.98 778.67 12/9/2009 8.34 778.31 6/9/2010 7.05 779.60 12/8/2010 6.00 780.65 URS Corporation - North Carolina Page 14 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MWO5 6/8/2011 8.58 778.07 (786.65) 12/7/2011 10.21 776.44 6/6/2012 8.86 777.79 12/4/2012 11.30 775.35 6/4/2013 1.84 784.81 12/3/2013 10.07 776.58 6/3/2014 6.98 779.67 12/2/2014 7.28 779.37 6/2/2015 5.77 780.88 MWO6R 3/4/1998 3.00 752.29 (755.29) 3/4/1998 3.00 752.29 6/25/1998 4.87 750.42 11/30/1998 DRY DRY 3/25/1999 8.21 747.08 6/21/1999 7.51 747.78 12/13/1999 8.50 746.79 6/5/2000 8.63 746.66 12/5/2000 DRY DRY 6/4/2001 DRY DRY 12/5/2001 DRY DRY 6/19/2002 9.83 745.46 12/16/2002 8.43 746.86 6/4/2003 6.23 749.06 12/15/2003 5.31 749.98 1/14/2004 9.66 745.63 6/7/2004 6.84 748.45 12/6/2004 8.75 746.54 3/4/2005 7.91 747.38 6/6/2005 7.99 747.30 11/28/2005 DRY DRY MWO7 3/25/1996 6.18 768.18 (774.36) 6/6/1996 4.40 769.96 10/24/1996 3.00 771.36 3/25/1999 4.45 769.91 12/13/1999 5.62 768.74 6/5/2000 0.50 773.86 12/5/2000 6.56 767.80 6/4/2001 3.96 770.40 12/5/2001 8.39 765.97 6/19/2002 6.27 768.09 12/16/2002 2.42 771.94 6/4/2003 0.81 773.55 12/15/2003 1.49 772.87 1/14/2004 4.62 769.74 6/7/2004 5.62 768.74 12/6/2004 4.07 770.29 2/18/2005 4.46 769.90 6/6/2005 2.42 771.94 11/28/2005 5.80 768.56 6/11/2013 1.46 772.90 MWO8 3/25/1996 10.52 767.17 (777.69) 6/6/1996 9.95 767.74 10/24/1996 3.20 774.49 3/25/1999 8.45 769.24 12/13/1999 9.32 768.37 6/5/2000 0.50 777.19 12/5/2000 10.31 767.38 6/4/2001 8.64 769.05 12/5/2001 11.78 765.91 6/19/2002 10.30 767.39 12/16/2002 7.77 769.92 6/4/2003 1.12 776.57 12/15/2003 3.92 773.77 1/14/2004 8.47 769.22 6/7/2004 9.02 768.67 12/6/2004 8.00 769.69 3/8/2005 5.12 772.57 6/6/2005 6.86 770.83 11/28/2005 9.73 767.96 6/19/2006 8.68 769.01 9/25/2006 7.44 770.25 11/2/2006 8.08 769.61 12/4/2006 7.69 770.00 6/11/2007 8.80 768.89 12/3/2007 11.14 766.55 6/2/2008 8.93 768.76 12/3/2008 6.94 770.75 6/2/2009 7.11 770.58 12/8/2009 6.96 770.73 6/8/2010 4.77 772.92 12/8/2010 3.80 773.89 6/7/2011 8.13 769.56 12/7/2011 8.94 768.75 6/6/2012 8.11 769.58 12/4/2012 11.36 766.33 6/5/2013 1.34 776.35 12/4/2013 9.64 768.05 6/4/2014 5.77 771.92 12/3/2014 7.28 770.41 6/3/2015 6.92 770.77 MWO9 3/25/1996 11.23 773.42 (784.65) 6/6/1996 14.05 770.60 10/24/1996 11.73 772.92 2/25/1998 9.87 774.78 3/25/1999 12.58 772.07 1/14/2004 13.77 770.88 3/7/2005 12.64 772.01 5/26/2005 10.99 773.66 MW12 3/25/1996 7.63 778.53 (786.16) 6/6/1996 6.50 779.66 URS Corporation - North Carolina Page 15 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW12 10/24/1996 5.05 5.05 0.00 781.11 (786.16) 3/25/1999 5.94 7.44 1.50 778.72 6/5/2000 4.62 4.62 0.00 781.54 12/29/2003 6.25 6.25 0.00 779.91 1/14/2004 7.16 7.16 0.00 779.00 3/22/2004 6.23 6.47 0.24 779.69 3/7/2005 5.82 6.02 0.20 780.14 5/24/2005 4.99 5.01 0.02 781.15 6/7/2005 4.89 781.27 11/28/2005 6.02 780.14 6/19/2006 6.52 779.64 12/4/2006 5.60 780.56 6/11/2007 6.27 779.89 12/3/2007 9.44 776.72 6/2/2008 6.82 779.34 12/3/2008 17.15 769.01 6/4/2009 5.46 780.70 12/9/2009 5.20 780.96 6/8/2010 2.94 783.22 12/7/2010 6.00 780.16 6/7/2011 5.78 780.38 12/5/2011 7.62 778.54 6/6/2012 5.91 780.25 12/5/2012 9.50 776.66 6/5/2013 1.32 784.84 12/3/2013 7.42 778.74 6/3/2014 3.73 782.43 12/2/2014 5.52 780.64 6/3/2015 1.71 784.45 MW14R 3/4/1998 2.99 753.42 (756.41) 3/4/1998 2.99 753.42 6/26/1998 4.02 752.39 11/30/1998 10.80 745.61 3/25/1999 7.17 749.24 6/21/1999 7.80 748.61 12/13/1999 8.80 747.61 6/5/2000 7.97 748.44 12/5/2000 10.22 746.19 6/4/2001 7.49 748.92 12/5/2001 12.27 744.14 6/19/2002 10.34 746.07 12/16/2002 5.86 750.55 6/4/2003 4.14 752.27 12/15/2003 6.25 750.16 1/14/2004 7.37 749.04 6/7/2004 8.02 748.39 12/6/2004 6.22 750.19 2/18/2005 5.89 750.52 6/6/2005 5.53 750.88 11/28/2005 8.45 747.96 12/4/2006 5.79 750.62 6/11/2007 7.66 748.75 12/3/2007 10.44 745.97 6/2/2008 7.10 749.31 12/3/2008 7.27 749.14 6/2/2009 5.48 750.93 12/8/2009 5.83 750.58 6/8/2010 5.84 750.57 12/8/2010 9.52 746.89 6/6/2011 7.11 749.30 12/7/2011 8.13 748.28 6/6/2012 6.80 749.61 12/4/2012 10.67 745.74 6/5/2013 6.78 749.63 12/4/2013 9.14 747.27 6/4/2014 6.01 750.40 12/3/2014 8.17 748.24 6/3/2015 7.78 748.63 MW16 3/25/1996 8.62 778.65 (787.27) 6/6/1996 8.10 779.17 10/24/1996 7.00 780.27 6/5/2000 1.67 785.60 1/14/2004 8.04 779.23 3/7/2005 7.43 779.84 6/7/2005 6.42 780.85 8/29/2005 8.62 778.65 MW18 6/6/1996 10.73 770.17 (780.9) 10/24/1996 4.70 776.20 MW19 3/25/1996 11.95 770.69 (782.64) 6/6/1996 15.10 767.54 10/24/1996 12.67 12.67 0.00 769.97 3/25/1999 11.90 770.74 1/14/2004 12.42 770.22 3/7/2005 11.68 770.96 3/23/2005 10.71 771.93 6/7/2005 9.38 773.26 11/28/2005 11.61 771.03 1/24/2006 10.49 772.15 2/23/2006 10.36 772.28 3/7/2006 11.00 771.64 6/19/2006 11.46 771.18 8/1/2006 11.04 771.60 8/15/2006 11.83 770.81 9/25/2006 9.94 772.70 11/2/2006 10.60 772.04 12/4/2006 10.40 772.24 (781.6) 6/11/2007 10.50 771.10 (782.64) 12/3/2007 13.70 768.94 6/2/2008 11.18 771.46 12/3/2008 12.25 770.39 URS Corporation - North Carolina Page 16 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW19 6/3/2009 10.40 772.24 (782.64) 12/8/2009 10.15 772.49 6/8/2010 8.43 774.21 12/8/2010 11.94 770.70 6/7/2011 10.12 772.52 12/7/2011 10.95 771.69 6/6/2012 10.99 771.65 12/4/2012 13.01 769.63 6/5/2013 11.12 771.52 12/4/2013 12.28 770.36 6/4/2014 8.81 773.83 12/3/2014 9.34 773.30 6/3/2015 8.32 774.32 MW20 3/25/1996 7.66 779.68 (787.34) 6/6/1996 7.71 779.63 10/24/1996 6.75 780.59 3/25/1999 7.73 779.61 12/29/2003 5.87 781.47 1/14/2004 8.15 779.19 3/22/2004 7.44 779.90 3/7/2005 5.01 782.33 6/7/2005 4.06 783.28 6/11/2013 4.56 782.78 MW21 3/7/2005 6.42 779.34 (785.76) 6/7/2005 5.66 780.10 11/28/2005 8.22 777.54 6/19/2006 7.24 778.52 12/4/2006 9.00 776.76 6/11/2007 6.62 779.14 12/3/2007 9.62 776.14 6/2/2008 7.46 778.30 12/3/2008 8.48 777.28 6/4/2009 5.98 779.78 12/9/2009 6.34 779.42 6/9/2010 5.33 780.43 12/8/2010 8.59 777.17 6/8/2011 6.24 779.52 12/7/2011 8.31 777.45 6/6/2012 6.79 778.97 12/5/2012 9.31 776.45 6/5/2013 6.58 779.18 12/3/2013 8.01 777.75 6/3/2014 5.21 780.55 12/2/2014 5.81 779.95 6/3/2015 4.15 781.61 MW26 3/25/1996 4.50 780.88 (785.38) 6/6/1996 6.31 779.07 10/24/1996 4.53 780.85 2/25/1998 4.33 781.05 3/25/1999 6.64 778.74 1/14/2004 7.64 777.74 3/7/2005 6.42 778.96 6/7/2005 5.52 779.86 11/28/2005 7.62 777.76 6/19/2006 7.12 778.26 12/4/2006 5.82 779.56 6/11/2007 6.51 778.87 12/3/2007 9.46 775.92 6/2/2008 7.48 777.90 12/3/2008 8.57 776.81 6/4/2009 5.96 779.42 12/9/2009 6.26 779.12 6/9/2010 5.20 780.18 12/8/2010 8.39 776.99 6/8/2011 6.26 779.12 12/7/2011 8.17 777.21 6/6/2012 6.71 778.67 12/5/2012 9.36 776.02 6/5/2013 5.80 779.58 12/3/2013 7.82 777.56 6/3/2014 4.77 780.61 12/2/2014 5.47 779.91 6/3/2015 3.96 781.42 MW27 3/25/1996 5.45 5.45 0.00 781.48 (786.93) 6/6/1996 5.90 5.90 0.00 781.03 10/24/1996 5.90 5.95 0.05 780.98 3/25/1999 6.70 6.78 0.08 780.15 6/5/2000 6.25 6.25 0.00 780.68 1/14/2004 6.95 7.05 0.10 779.88 3/7/2005 6.83 780.10 6/7/2005 5.11 5.62 0.51 781.31 6/11/2013 4.29 782.64 MW36 3/25/1999 (785.94) 1/14/2004 3/7/2005 3/22/2005 6/7/2005 11/28/2005 1/24/2006 2/23/2006 3/7/2006 6/19/2006 8/15/2006 8/31/2006 9/25/2006 11/2/2006 12/4/2006 6/11/2007 12/3/2007 6/2/2008 14.83 15.61 14.13 13.68 12.78 14.99 14.80 13.86 14.60 14.81 15.14 13.76 13.22 13.90 13.51 13.91 17.09 14.69 771.11 770.33 771.81 772.26 773.16 770.95 771.14 772.08 771.34 771.13 770.80 772.18 772.72 772.04 772.43 772.03 768.85 771.25 URS Corporation - North Carolina Page 17 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW36 12/4/2008 15.80 770.14 (785.94) 6/3/2009 13.41 772.53 12/8/2009 13.60 772.34 6/8/2010 11.95 773.99 12/8/2010 15.52 770.42 6/7/2011 13.65 772.29 12/7/2011 14.53 771.41 6/6/2012 14.39 771.55 12/4/2012 16.51 769.43 6/5/2013 14.50 771.44 12/4/2013 15.25 770.69 6/4/2014 12.30 773.64 12/3/2014 12.84 773.10 6/3/2015 11.77 774.17 MW37 3/25/1996 14.10 771.07 (785.17) 6/6/1996 14.95 770.22 10/24/1996 14.15 14.15 0.00 771.02 2/25/1998 11.72 773.45 3/25/1999 12.81 772.36 1/14/2004 13.27 771.90 3/7/2005 12.88 772.29 3/22/2005 12.52 772.65 6/7/2005 12.09 773.08 12/9/2009 12.37 772.80 6/11/2013 12.82 772.35 MW38 3/25/1996 14.50 771.04 (785.54) 6/6/1996 16.01 769.53 10/24/1996 14.70 14.70 0.00 770.84 2/25/1998 12.38 773.16 3/25/1999 13.91 771.63 7/2/2002 16.05 769.49 4/8/2003 12.83 772.71 6/4/2003 11.25 774.29 12/15/2003 13.34 772.20 1/14/2004 13.65 771.89 3/7/2005 13.51 772.03 3/23/2005 12.86 772.68 11/28/2005 14.32 771.22 1/24/2006 14.50 771.04 2/23/2006 13.28 772.26 3/7/2006 13.77 771.77 6/19/2006 14.01 771.53 8/15/2006 14.53 771.01 8/31/2006 13.06 772.48 9/25/2006 12.55 772.99 11/2/2006 13.08 772.46 12/4/2006 12.71 772.83 6/11/2007 13.13 772.41 12/3/2007 15.97 769.57 6/2/2008 14.13 771.41 12/4/2008 14.68 770.86 6/3/2009 12.63 772.91 12/8/2009 12.68 772.86 6/8/2010 11.41 774.13 12/8/2010 15.16 770.38 6/7/2011 13.10 772.44 12/7/2011 14.08 771.46 6/6/2012 13.48 772.06 12/4/2012 15.79 769.75 6/5/2013 13.58 771.96 12/4/2013 14.54 771.00 6/4/2014 11.68 773.86 12/3/2014 12.51 773.03 6/3/2015 10.83 774.71 MW39 3/25/1996 12.10 773.18 (785.28) 6/6/1996 12.28 773.00 10/24/1996 14.24 14.24 0.00 771.04 6/22/1998 11.99 773.29 11/30/1998 14.01 771.27 3/25/1999 13.51 771.77 6/21/1999 13.70 771.58 12/13/1999 14.59 770.69 6/5/2000 13.41 771.87 12/5/2000 15.00 770.28 6/4/2001 14.55 770.73 12/5/2001 16.59 16.59 0.00 768.69 6/19/2002 15.32 769.96 7/2/2002 15.49 769.79 12/16/2002 14.07 771.21 4/8/2003 12.41 772.87 6/4/2003 11.88 773.40 12/15/2003 13.06 772.22 1/14/2004 13.28 772.00 6/7/2004 13.26 772.02 12/6/2004 12.89 772.39 3/7/2005 12.77 772.51 6/7/2005 12.05 773.23 11/28/2005 14.13 771.15 1/24/2006 13.44 771.84 2/23/2006 13.03 772.25 3/7/2006 13.59 771.69 6/19/2006 13.89 771.39 8/15/2006 14.28 771.00 8/31/2006 13.05 772.23 9/25/2006 12.44 772.84 11/2/2006 12.90 772.38 12/4/2006 12.57 772.71 6/11/2007 12.90 772.38 12/3/2007 15.76 769.52 6/2/2008 14.00 771.28 URS Corporation - North Carolina Page 18 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW39 12/4/2008 14.52 770.76 (785.28) 6/3/2009 12.31 772.97 12/9/2009 12.59 772.69 6/8/2010 11.34 773.94 12/8/2010 14.75 770.53 6/7/2011 13.18 772.10 12/7/2011 13.92 771.36 6/6/2012 13.35 771.93 12/4/2012 15.54 769.74 6/5/2013 13.43 771.85 12/4/2013 14.35 770.93 6/4/2014 11.47 773.81 12/3/2014 12.34 772.94 6/3/2015 10.50 774.78 MW41 3/25/1996 11.62 11.62 0.00 774.02 (785.64) 6/6/1996 13.88 13.88 0.00 771.76 10/24/1996 14.65 14.65 0.00 770.99 2/25/1998 12.39 773.25 6/22/1998 12.51 773.13 11/30/1998 14.63 771.01 3/25/1999 14.01 771.63 6/21/1999 14.28 771.36 12/13/1999 15.20 770.44 6/5/2000 13.94 771.70 12/5/2000 15.67 769.97 6/4/2001 15.11 770.53 12/5/2001 17.21 17.21 0.00 768.43 6/19/2002 15.90 769.74 7/2/2002 16.10 769.54 12/16/2002 14.65 770.99 4/8/2003 12.92 772.72 6/4/2003 11.31 774.33 12/15/2003 12.59 773.05 1/14/2004 13.35 772.29 6/7/2004 13.72 771.92 12/6/2004 13.33 772.31 3/23/2005 12.72 772.92 6/7/2005 12.44 773.20 11/28/2005 14.62 771.02 1/24/2006 13.73 771.91 2/23/2006 13.43 772.21 3/7/2006 13.95 771.69 6/19/2006 14.33 771.31 8/15/2006 14.87 770.77 8/31/2006 13.28 772.36 9/25/2006 12.87 772.77 11/2/2006 13.31 772.33 12/4/2006 12.90 772.74 6/11/2007 13.25 772.39 12/3/2007 15.95 769.69 6/2/2008 14.54 771.10 12/4/2008 14.69 770.95 6/3/2009 12.84 772.80 12/8/2009 12.88 772.76 6/8/2010 11.63 774.01 12/8/2010 15.01 770.63 6/7/2011 13.52 772.12 12/7/2011 14.17 771.47 6/6/2012 13.69 771.95 12/4/2012 16.01 769.63 6/5/2013 13.73 771.91 12/4/2013 14.68 770.96 6/4/2014 11.69 773.95 12/3/2014 12.57 773.07 6/3/2015 10.87 774.77 MW42 3/25/1996 14.21 771.74 (785.95) 6/6/1996 14.95 771.00 10/24/1996 14.19 771.76 3/25/1999 13.45 772.50 6/5/2000 13.26 772.69 1/14/2004 12.82 773.13 3/7/2005 12.83 773.12 3/22/2005 12.59 773.36 12/9/2009 12.44 773.51 6/11/2013 12.96 772.99 MW43 3/25/1996 6.21 782.15 (788.36) 6/6/1996 11.99 776.37 10/24/1996 6.34 782.02 3/25/1999 9.91 778.45 1/14/2004 9.76 778.60 3/7/2005 8.29 780.07 6/7/2005 7.16 781.20 6/11/2013 7.61 780.75 MW44 3/25/1996 14.32 14.32 0.00 771.45 (785.77) 6/6/1996 15.94 15.94 0.00 769.83 10/24/1996 14.44 771.33 2/25/1998 11.81 773.96 3/25/1999 13.60 772.17 6/5/2000 13.55 772.22 7/2/2002 15.59 770.18 4/8/2003 12.41 773.36 6/4/2003 10.77 775.00 12/15/2003 12.85 772.92 1/14/2004 13.22 772.55 3/7/2005 13.09 772.68 3/22/2005 12.68 773.09 11/28/2005 14.43 771.34 6/19/2006 13.78 771.99 12/4/2006 12.49 773.28 (786.77) 6/11/2007 13.28 773.49 URS Corporation - North Carolina Page 19 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW44 12/3/2007 15.98 769.79 (785.77) 6/2/2008 14.23 771.54 12/4/2008 14.66 771.11 6/4/2009 12.43 773.34 12/8/2009 12.51 773.26 6/8/2010 11.44 774.33 12/8/2010 15.05 770.72 6/7/2011 13.19 772.58 12/7/2011 14.18 771.59 6/6/2012 13.27 772.50 12/4/2012 15.94 769.83 6/5/2013 13.43 772.34 (786.77) 12/4/2013 14.53 772.24 6/4/2014 11.74 775.03 12/3/2014 12.17 774.60 6/3/2015 10.79 775.98 MW45 3/27/1996 15.98 770.93 (786.91) 6/6/1996 16.85 770.06 10/24/1996 16.00 770.91 2/25/1998 13.60 773.31 3/25/1999 15.32 771.59 1/14/2004 15.19 771.72 3/7/2005 14.76 772.15 3/22/2005 14.34 772.57 9/25/2006 13.10 773.81 11/2/2006 13.67 773.24 12/9/2009 13.16 773.75 6/11/2013 13.56 773.35 MW47 3/24/1996 7.63 780.42 (788.05) 6/6/1996 7.50 7.50 0.00 780.55 10/24/1996 7.72 780.33 3/25/1999 9.68 778.37 1/14/2004 10.18 777.87 3/7/2005 9.52 778.53 6/7/2005 8.21 779.84 6/11/2013 8.07 779.98 MW48 3/24/1996 5.13 783.06 (788.19) 6/6/1996 4.90 783.29 10/24/1996 5.00 783.19 3/25/1999 5.88 782.31 1/14/2004 7.84 7.84 0.00 780.35 3/24/2005 5.12 783.07 6/7/2005 5.02 783.17 6/11/2013 7.94 8.12 0.18 780.07 1/24/2014 8.02 8.05 0.03 780.14 5/6/2014 6.38 6.40 0.02 781.79 7/10/2014 sock* 6.39 781.80 8/7/2014 sock* 6.42 781.77 9/11/2014 sock* 6.85 781.34 10/16/2014 sock*; LNAPL not on water 12/11/2014 sock*; LNAPL not on water MW49 3/24/1996 13.29 770.88 (784.17) 6/6/1996 12.60 771.57 10/24/1996 13.33 770.84 3/25/1999 12.39 771.78 7/2/2002 15.16 769.01 4/8/2003 12.73 771.44 6/4/2003 10.61 773.56 12/15/2003 12.61 771.56 1/14/2004 13.02 771.15 3/7/2005 12.34 771.83 3/23/2005 11.53 772.64 6/7/2005 11.06 773.11 11/28/2005 13.37 770.80 6/19/2006 12.74 771.43 8/1/2006 12.43 771.74 8/31/2006 11.80 772.37 9/25/2006 11.30 772.87 11/2/2006 11.80 772.37 12/4/2006 11.44 772.73 6/11/2007 11.22 772.95 12/3/2007 14.83 769.34 6/2/2008 13.30 770.87 12/4/2008 13.48 770.69 6/3/2009 11.28 772.89 12/8/2009 11.48 772.69 6/8/2010 10.30 773.87 12/8/2010 14.01 770.16 6/7/2011 12.03 772.14 12/7/2011 12.88 771.29 6/6/2012 12.09 772.08 12/4/2012 14.84 769.33 6/5/2013 12.17 772.00 12/4/2013 14.32 769.85 6/4/2014 10.58 773.59 12/3/2014 11.18 772.99 6/3/2015 9.92 774.25 MW50 3/24/1996 9.10 774.40 (783.5) 6/6/1996 12.75 770.75 10/24/1996 8.85 774.65 3/25/1999 11.97 771.53 1/14/2004 11.60 771.90 3/7/2005 11.36 772.14 3/22/2005 10.79 772.71 11/28/2005 12.78 770.72 6/19/2006 12.07 771.43 12/4/2006 10.76 772.74 6/11/2007 12.69 770.81 12/3/2007 14.37 769.13 6/2/2008 11.25 772.25 URS Corporation - North Carolina Page 20 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW50 12/4/2008 12.84 770.66 (783.5) 6/3/2009 10.49 773.01 12/9/2009 sheen 10.52 sheen 772.98 6/8/2010 9.47 774.03 12/8/2010 13.27 770.23 6/7/2011 11.43 772.07 12/7/2011 12.26 771.24 6/6/2012 11.37 772.13 12/4/2012 14.40 769.10 6/6/2013 11.20 772.30 12/4/2013 12.76 770.74 6/4/2014 9.91 773.59 12/3/2014 10.41 773.09 6/3/2015 9.49 774.01 MW51 3/24/1996 10.90 775.51 (786.41) 6/6/1996 10.40 10.40 0.00 776.01 10/24/1996 10.55 775.86 6/25/1998 9.09 777.32 11/30/1998 11.57 774.84 3/25/1999 10.93 775.48 6/21/1999 10.49 775.92 12/15/1999 11.95 11.96 0.01 774.45 6/5/2000 10.90 775.51 12/5/2000 12.07 774.34 6/4/2001 11.01 775.40 12/5/2001 13.90 13.90 0.00 772.51 6/19/2002 11.73 774.68 12/16/2002 10.87 775.54 6/4/2003 7.74 778.67 12/15/2003 10.19 776.22 1/14/2004 10.86 775.55 6/7/2004 11.08 775.33 12/6/2004 10.40 776.01 3/8/2005 10.34 776.07 6/7/2005 9.54 776.87 11/28/2005 11.78 774.63 6/19/2006 11.23 775.18 12/4/2006 10.22 776.19 6/11/2007 11.19 775.22 12/3/2007 13.22 773.19 6/2/2008 12.40 774.01 12/4/2008 11.94 774.47 6/3/2009 9.92 776.49 12/9/2009 10.12 776.29 6/8/2010 9.24 777.17 12/8/2010 12.63 773.78 6/7/2011 10.82 775.59 12/7/2011 11.64 774.77 6/6/2012 10.82 775.59 12/4/2012 14.34 772.07 6/5/2013 10.87 775.54 12/3/2013 11.93 774.48 6/4/2014 9.39 777.02 12/3/2014 9.66 776.75 6/3/2015 8.51 777.90 MW52 2/23/2006 12.04 744.01 (756.05) 6/11/2013 11.15 744.90 12/4/2013 12.93 743.12 6/4/2014 11.37 744.68 12/3/2014 12.81 743.24 6/3/2015 11.85 744.20 MW53 3/8/2006 8.00 746.42 (754.42) 6/11/2013 3.68 750.74 6/4/2014 7.76 746.66 MW55 2/23/2006 11.86 770.50 (782.36) 3/8/2006 18.40 763.96 6/11/2013 8.75 773.61 6/4/2014 10.46 771.90 MW56 2/23/2006 8.43 754.41 (762.84) 3/8/2006 8.80 754.04 6/11/2013 7.21 755.63 MW57 2/23/2006 28.45 741.09 (769.54) 3/8/2006 8.65 760.89 6/19/2006 7.63 761.91 6/11/2013 6.99 762.55 12/4/2013 9.22 760.32 6/3/2014 7.16 762.38 12/3/2014 7.98 761.56 6/4/2015 7.62 761.92 MW58 2/23/2006 12.19 764.95 (777.14) 3/8/2006 12.45 764.69 6/11/2007 12.87 764.27 12/3/2007 14.53 762.61 12/4/2008 12.40 764.74 6/2/2009 10.19 766.95 12/8/2009 10.85 766.29 6/7/2010 9.86 767.28 12/7/2010 12.97 764.17 6/6/2011 9.32 767.82 12/5/2011 9.83 767.31 6/6/2012 8.42 768.72 12/3/2012 13.43 763.71 6/4/2013 9.52 767.62 12/2/2013 10.40 766.74 6/3/2014 7.46 769.68 12/2/2014 8.97 768.17 6/2/2015 9.52 767.62 MW59 2/23/2006 (781.64) 3/8/2006 6/11/2007 5.83 5.80 6.76 775.81 775.84 774.88 URS Corporation - North Carolina Page 21 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) MW59 12/3/2007 8.05 773.59 (781.64) 6/2/2008 3.69 777.95 12/4/2008 4.90 776.74 6/2/2009 2.22 779.42 12/8/2009 2.68 778.96 6/7/2010 1.69 779.95 12/7/2010 6.39 775.25 6/6/2011 3.42 778.22 12/5/2011 5.65 775.99 6/6/2012 3.90 777.74 12/3/2012 7.94 773.70 6/4/2013 3.50 778.14 12/2/2013 6.13 775.51 6/3/2014 2.25 779.39 12/2/2014 3.79 777.85 6/2/2015 3.46 778.18 MW65 8/30/2010 6.98 778.74 (785.72) 12/8/2010 8.76 776.96 6/8/2011 6.56 779.16 12/5/2011 8.52 777.20 6/6/2012 7.12 778.60 12/5/2012 9.32 776.40 6/5/2013 6.86 778.86 12/3/2013 8.13 777.59 6/3/2014 5.12 780.60 12/2/2014 5.68 780.04 6/3/2015 4.04 781.68 MW66 8/30/2010 4.55 776.49 (781.04) 12/7/2010 5.17 775.87 6/7/2011 4.37 776.67 12/6/2011 4.39 776.65 6/6/2012 3.66 777.38 12/3/2012 5.88 775.16 6/4/2013 3.77 777.27 12/3/2013 4.50 776.54 6/3/2014 3.05 777.99 12/2/2014 3.60 777.44 6/2/2015 3.71 777.33 MW67 8/30/2010 4.10 776.34 (780.44) 12/7/2010 4.73 775.71 6/7/2011 3.78 776.66 12/6/2011 3.85 776.59 6/6/2012 3.33 777.11 12/3/2012 5.47 774.97 6/4/2013 3.42 777.02 12/3/2013 4.15 776.29 6/3/2014 2.77 777.67 12/2/2014 3.48 776.96 6/2/2015 3.36 777.08 MW68 8/30/2010 6.77 775.70 12/8/2010 6.65 775.82 6/8/2011 7.08 775.39 12/6/2011 6.97 775.50 6/6/2012 3.92 778.55 12/4/2012 7.60 774.87 6/4/2013 5.16 777.31 12/3/2013 7.03 775.44 6/3/2014 6.15 776.32 12/2/2014 6.97 775.50 6/2/2015 7.27 775.20 MW69 6/8/2011 6.10 771.63 (774.72) 12/6/2011 5.85 768.87 6/6/2012 5.90 768.82 12/3/2012 8.45 766.27 6/4/2013 6.25 768.47 12/3/2013 7.34 767.38 6/3/2014 5.71 769.01 12/2/2014 6.08 768.64 6/2/2015 8.28 766.44 PMW01 ABANDONED 3/20/15 (761.06) 3/24/1996 3.33 757.73 6/6/1996 2.59 758.47 10/24/1996 3.10 757.96 1/8/1999 5.93 755.13 3/25/1999 6.08 754.98 12/13/1999 6.09 754.97 12/16/1999 6.09 754.97 6/5/2000 6.97 754.09 12/5/2000 7.35 753.71 6/4/2001 6.78 754.28 12/5/2001 8.87 752.19 6/18/2002 7.40 753.66 12/16/2002 4.80 756.26 6/3/2003 4.84 756.22 12/15/2003 6.44 754.62 1/14/2004 5.78 755.28 6/7/2004 7.41 753.65 9/21/2004 6.07 754.99 12/6/2004 6.15 754.91 3/4/2005 5.52 755.54 6/6/2005 5.81 755.25 11/28/2005 5.58 755.48 6/12/2013 4.78 756.28 12/4/2013 6.25 754.81 6/4/2014 5.54 755.52 12/3/2014 5.39 755.67 PMW02 ABANDONED 3/20/15 (760.76) 3/24/1996 3.21 757.55 6/6/1996 6.35 754.41 10/24/1996 3.20 757.56 URS Corporation - North Carolina Page 22 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) PMWO2 1/8/1999 7.04 753.72 (760.76) 3/25/1999 5.75 755.01 12/13/1999 6.59 754.17 12/16/1999 6.59 754.17 6/5/2000 7.11 753.65 12/5/2000 7.71 753.05 6/4/2001 6.95 753.81 12/5/2001 8.93 751.83 6/18/2002 8.09 752.67 7/1/2002 8.29 752.47 12/16/2002 6.05 754.71 6/3/2003 5.35 755.41 12/15/2003 6.32 754.44 12/29/2003 6.38 754.38 1/14/2004 6.41 754.35 3/22/2004 5.91 754.85 6/7/2004 6.87 753.89 9/21/2004 7.16 753.60 12/6/2004 6.50 754.26 3/4/2005 5.72 755.04 6/7/2005 6.23 754.53 11/28/2005 3.32 757.44 6/19/2006 7.01 753.75 12/4/2006 6.01 754.75 6/11/2007 7.62 753.14 12/3/2007 8.40 752.36 6/26/2008 6.99 753.77 12/3/2008 6.53 754.23 6/3/2009 6.75 754.01 12/9/2009 6.03 754.73 6/9/2010 6.15 754.61 12/9/2010 7.49 753.27 6/8/2011 6.78 753.98 12/7/2011 6.79 753.97 6/7/2012 6.49 754.27 12/5/2012 8.85 751.91 6/6/2013 6.35 754.41 12/4/2013 7.52 753.24 6/4/2014 6.43 754.33 12/3/2014 6.90 753.86 PMWO3 3/24/1996 4.15 754.37 (758.52) 6/6/1996 6.13 752.39 10/24/1996 3.00 755.52 6/22/1998 3.08 755.44 11/30/1998 3.76 754.76 1/8/1999 2.83 755.69 3/25/1999 2.93 755.59 6/21/1999 3.02 755.50 6/21/1999 3.02 755.50 12/13/1999 3.02 755.50 12/13/1999 3.02 755.50 6/5/2000 2.71 755.81 12/5/2000 3.74 754.78 6/4/2001 3.47 755.05 12/5/2001 4.40 754.12 6/18/2002 3.56 754.96 7/1/2002 3.43 755.09 12/16/2002 1.93 756.59 6/3/2003 2.57 755.95 12/15/2003 1.98 756.54 12/29/2003 2.19 2.19 0.00 756.33 1/14/2004 2.23 2.23 0.00 756.29 3/22/2004 2.91 755.61 6/7/2004 2.97 755.55 9/21/2004 2.26 756.26 12/6/2004 4.10 754.42 3/4/2005 1.45 757.07 6/7/2005 1.82 756.70 6/12/2013 0.95 757.57 PMWO4 3/24/1996 4.13 746.14 (750.27) 6/6/1996 5.30 744.97 10/24/1996 4.65 745.62 3/11/1999 13.30 736.97 3/25/1999 13.10 737.17 12/13/1999 14.65 735.62 6/5/2000 13.53 736.74 12/5/2000 15.10 735.17 6/4/2001 14.12 736.15 12/5/2001 16.95 733.32 6/18/2002 14.98 735.29 12/16/2002 13.94 736.33 6/3/2003 9.61 740.66 12/15/2003 8.93 741.34 1/14/2004 13.72 736.55 6/7/2004 13.61 736.66 12/6/2004 13.19 737.08 3/4/2005 11.02 739.25 6/9/2005 12.44 737.83 11/28/2005 15.11 735.16 6/11/2013 11.92 738.35 12/2/2013 15.57 734.70 6/3/2014 12.55 737.72 12/2/2014 14.28 735.99 6/2/2015 13.42 736.85 PMWO5 3/24/1996 (743.41) 6/6/1996 10/24/1996 3/11/1999 3/25/1999 1/14/2004 4.20 5.44 4.55 6.69 7.51 5.54 739.21 737.97 738.86 736.72 735.90 737.87 URS Corporation - North Carolina Page 23 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) PMW05 3/4/2005 4.33 739.08 (743.41) 6/11/2013 4.73 738.68 12/2/2013 8.65 734.76 6/3/2014 5.89 737.52 12/2/2014 6.80 736.61 6/2/2015 7.31 736.10 PMW06 3/24/1996 3.78 750.49 (754.27) 6/6/1996 3.70 750.57 10/24/1996 3.90 750.37 3/25/1999 3.80 750.47 7/1/2002 4.60 749.67 12/29/2003 4.12 4.12 0.00 750.15 1/14/2004 4.08 750.19 3/22/2004 4.14 750.13 3/4/2005 4.26 750.01 (753.66) 11/28/2005 4.42 749.24 3/8/2006 4.60 749.06 (754.27) 6/12/2013 4.57 749.70 PMW07 3/24/1996 3.40 750.26 (753.66) 6/6/1996 4.30 749.36 10/24/1996 3.44 750.22 3/25/1999 4.31 749.35 6/5/2000 5.13 748.53 12/5/2000 5.01 748.65 1/14/2004 4.74 748.92 3/4/2005 3.51 750.15 3/8/2006 3.60 750.06 6/12/2013 3.52 750.14 PMW08 3/24/1996 3.41 757.57 (760.98) 6/6/1996 4.47 756.51 10/24/1996 3.30 757.68 6/22/1998 5.75 755.23 11/30/1998 6.10 754.88 1/8/1999 3.76 757.22 3/25/1999 4.34 756.64 6/21/1999 5.16 755.82 6/21/1999 5.16 755.82 12/13/1999 4.44 756.54 12/13/1999 4.44 756.54 6/5/2000 5.66 755.32 12/5/2000 6.08 754.90 6/4/2001 5.01 755.97 12/5/2001 7.81 753.17 6/18/2002 6.56 754.42 12/16/2002 4.41 756.57 6/3/2003 4.97 756.01 12/15/2003 3.48 757.50 12/29/2003 3.50 757.48 1/14/2004 3.52 757.46 3/22/2004 3.68 757.30 6/7/2004 6.28 754.70 9/21/2004 4.93 756.05 12/6/2004 4.16 756.82 3/4/2005 3.56 757.42 6/6/2005 4.28 756.70 6/12/2013 3.35 757.63 PMW09 3/24/1996 (750.93) 6/6/1996 10/24/1996 6/22/1998 11/30/1998 3/25/1999 6/21/1999 6/21/1999 12/13/1999 12/13/1999 6/5/2000 12/5/2000 6/4/2001 12/5/2001 6/18/2002 12/16/2002 6/3/2003 12/15/2003 1/14/2004 6/7/2004 9/21/2004 12/6/2004 3/4/2005 6/6/2005 11/28/2005 6/19/2006 12/4/2006 6/11/2007 12/3/2007 6/26/2008 12/3/2008 6/3/2009 12/10/2009 6/9/2010 12/9/2010 6/8/2011 12/7/2011 6/7/2012 12/5/2012 6/6/2013 12/4/2013 6/4/2014 12/3/2014 6/4/2015 3.59 3.10 3.41 4.21 3.61 3.45 3.57 3.57 3.61 3.61 3.92 4.30 3.55 4.05 5.28 3.48 3.54 3.39 3.46 5.63 4.08 3.73 3.82 4.05 3.54 4.56 3.88 4.69 4.79 4.83 3.90 4.25 3.51 4.18 3.96 4.68 4.00 4.57 5.27 3.64 4.35 4.42 3.86 5.05 747.34 747.83 747.52 746.72 747.32 747.48 747.36 747.36 747.32 747.32 747.01 746.63 747.38 746.88 745.65 747.45 747.39 747.54 747.47 745.30 746.85 747.20 747.11 746.88 747.39 746.37 747.05 746.24 746.14 746.10 747.03 746.68 747.42 746.75 746.97 746.25 746.93 746.36 745.66 747.29 746.58 746.51 747.07 745.88 URS Corporation - North Carolina Page 24 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) PMW10 6/22/1998 5.11 741.75 (746.86) 11/30/1998 4.35 742.51 3/25/1999 4.71 742.15 6/21/1999 4.11 742.75 12/13/1999 3.89 742.97 6/5/2000 4.51 742.35 12/5/2000 4.65 742.21 6/4/2001 4.02 742.84 12/5/2001 5.01 741.85 6/18/2002 5.95 740.91 12/16/2002 4.70 742.16 6/3/2003 5.28 741.58 12/15/2003 3.57 743.29 12/29/2003 4.04 742.82 1/14/2004 4.06 742.80 3/22/2004 3.61 743.25 6/7/2004 5.23 741.63 12/6/2004 5.64 741.22 3/4/2005 3.98 742.88 6/6/2005 4.20 742.66 11/28/2005 3.86 743.00 6/19/2006 13.91 732.95 PMW11 6/23/1998 13.53 732.89 (746.42) 11/30/1998 16.01 730.41 3/11/1999 13.20 733.22 3/25/1999 12.91 733.51 1/14/2004 12.87 733.55 3/4/2005 14.45 731.97 11/28/2005 15.59 730.83 6/11/2013 9.13 737.29 6/3/2014 12.49 733.93 12/2/2014 14.99 731.43 6/2/2015 13.53 732.89 PMW12 3/11/1999 7.46 725.02 (732.48) 3/25/1999 7.26 725.22 6/21/1999 8.68 723.80 12/13/1999 9.15 723.33 6/5/2000 8.71 723.77 12/5/2000 9.33 723.15 6/4/2001 8.66 723.82 12/5/2001 DRY DRY 6/18/2002 10.58 721.90 12/16/2002 7.15 725.33 6/3/2003 5.63 726.85 12/15/2003 5.02 727.46 1/14/2004 8.40 724.08 6/7/2004 9.17 723.31 12/6/2004 7.53 724.95 6/9/2005 7.79 724.69 11/28/2005 9.05 723.43 RW02 1/14/2004 12.32 772.39 (784.71) 3/23/2005 11.65 773.06 RW03 3/24/1996 7.62 780.58 (788.2) 6/6/1996 6.59 781.61 10/24/1996 5.90 782.30 3/25/1999 8.11 780.09 1/14/2004 8.13 780.07 3/7/2005 7.89 780.31 6/11/2013 3.05 785.15 T01 3/25/1999 9.98 775.17 (785.15) 1/14/2004 9.82 775.33 3/23/2005 8.55 776.60 6/11/2013 9.23 775.92 T01A 3/24/1996 11.42 11.42 0.00 753.89 (765.31) 6/6/1996 11.40 11.40 0.00 753.91 10/24/1996 11.34 11.34 0.00 753.97 3/25/1999 3.87 761.44 6/5/2000 2.88 762.43 12/29/2003 3.24 3.24 0.00 762.07 1/14/2004 4.15 761.16 3/22/2004 2.97 762.34 3/23/2005 2.92 762.39 6/7/2005 2.93 762.38 8/29/2005 1.19 764.12 T02 3/25/1999 7.91 775.17 (783.08) 1/14/2004 7.21 775.87 3/23/2005 6.51 776.57 6/11/2013 7.26 775.82 T02A ABANDONED 3/20/15 (761.77) 3/24/1996 8.65 8.65 0.00 753.12 6/6/1996 8.23 8.33 0.10 753.44 10/24/1996 8.55 8.55 0.00 753.22 3/25/1999 4.38 757.39 6/5/2000 4.27 757.50 7/1/2002 4.46 757.31 12/29/2003 5.38 756.39 1/14/2004 5.39 756.38 3/22/2004 6.44 755.33 3/23/2005 2.22 759.55 6/7/2005 5.33 756.44 11/28/2005 5.29 756.48 6/19/2006 5.35 756.42 12/4/2006 3.88 757.89 6/11/2007 5.71 756.06 12/3/2007 8.98 752.79 6/2/2008 4.57 757.20 12/3/2008 5.79 755.98 6/2/2009 4.72 757.05 12/9/2009 4.98 756.79 6/8/2010 4.68 757.09 URS Corporation - North Carolina Page 25 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) T02A 12/8/2010 5.21 756.56 (761.77) 6/7/2011 4.93 756.84 12/6/2011 5.15 756.62 6/7/2012 4.96 756.81 12/4/2012 5.64 756.13 6/5/2013 4.55 757.22 12/4/2013 5.03 756.74 6/4/2014 4.64 757.13 12/3/2014 4.95 756.82 UW01 3/27/1996 6.25 774.74 (780.99) 6/6/1996 6.63 774.36 10/24/1996 6.15 774.84 9/16/1997 6.79 774.20 3/25/1999 6.26 774.73 1/14/2004 7.02 773.97 UW02 3/27/1996 5.55 5.85 0.30 779.59 (785.44) 6/3/1996 4.80 6.05 1.25 779.39 10/24/1996 5.70 5.70 0.00 779.74 1/14/2004 8.26 777.18 3/8/2005 6.24 779.20 6/7/2005 5.41 780.03 6/11/2013 6.01 779.43 UW03 3/27/1996 5.25 780.25 (785.5) 6/3/1996 4.55 780.95 10/24/1996 5.10 5.10 0.00 780.40 3/25/1999 6.55 778.95 1/14/2004 6.56 6.56 0.00 778.94 3/8/2005 5.80 779.70 UW04 3/27/1996 6.76 780.83 (787.59) 6/5/1996 7.59 780.00 10/24/1996 6.85 780.74 9/16/1997 8.22 779.37 3/25/1999 7.37 780.22 1/14/2004 7.81 779.78 3/8/2005 4.35 783.24 6/7/2005 6.02 781.57 6/12/2013 5.25 782.34 UW05 3/27/1996 9.63 779.96 (789.59) 6/3/1996 9.55 780.04 10/24/1996 9.40 780.19 9/16/1997 10.74 778.85 3/25/1999 9.91 779.68 1/14/2004 10.17 779.42 3/8/2005 9.41 780.18 6/7/2005 8.58 781.01 11/28/2005 11.13 778.46 6/19/2006 9.89 779.70 12/4/2006 9.62 779.97 6/11/2007 9.98 779.61 12/3/2007 12.65 776.94 6/2/2008 9.92 779.67 12/4/2008 10.88 778.71 6/2/2009 8.33 781.26 12/8/2009 9.11 780.48 6/7/2010 7.90 781.69 12/7/2010 11.19 778.40 6/7/2011 9.23 780.36 12/5/2011 10.22 779.37 6/6/2012 3.92 785.67 12/4/2012 12.54 777.05 6/4/2013 8.89 780.70 12/3/2013 10.32 779.27 6/3/2014 7.30 782.29 12/2/2014 8.72 780.87 6/3/2015 8.29 781.30 UW06 3/27/1996 6.75 775.25 (782) 6/3/1996 6.31 775.69 10/24/1996 6.75 775.25 6/22/1998 7.18 774.82 11/30/1998 7.55 774.45 3/25/1999 6.75 775.25 6/21/1999 6.45 775.55 12/13/1999 6.75 775.25 6/5/2000 5.96 776.04 12/5/2000 6.37 775.63 6/4/2001 5.70 776.30 12/5/2001 6.80 775.20 6/18/2002 6.44 775.56 12/16/2002 5.91 776.09 6/4/2003 4.91 777.09 12/15/2003 5.54 776.46 1/14/2004 6.40 6.40 0.00 775.60 6/7/2004 6.10 775.90 12/6/2004 5.85 776.15 3/8/2005 6.40 775.60 6/7/2005 5.61 776.39 6/9/2010 6.25 775.75 12/8/2010 6.93 775.07 6/8/2011 7.06 774.94 12/6/2011 6.89 775.11 6/6/2012 3.94 778.06 12/4/2012 7.80 774.20 6/4/2013 4.87 777.13 12/3/2013 7.06 774.94 6/3/2014 6.14 775.86 12/2/2014 6.93 775.07 6/2/2015 7.53 774.47 UW07 3/27/1996 (780.03) 6/5/1996 10/24/1996 6.03 7.38 6.10 774.00 772.65 773.93 URS Corporation - North Carolina Page 26 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) UW07 9/16/1997 8.07 771.96 (780.03) 3/25/1999 7.62 772.41 1/14/2004 6.97 773.06 UW08 3/27/1996 5.27 775.70 (780.97) 6/4/1996 6.43 774.54 10/24/1996 5.15 775.82 9/16/1997 6.25 774.72 3/25/1999 5.49 775'.48 1/14/2004 4.92 776.05 2/17/2005 4.95 776.02 6/7/2005 4.12 776.85 11/28/2005 5.66 775.31 6/19/2006 5.89 775.08 12/4/2006 5.11 775.86 6/11/2007 5.03 775.94 12/3/2007 5.67 775.30 6/2/2008 4.85 776.12 12/4/2008 4.88 776.09 6/4/2009 4.60 776.37 12/8/2009 4.77 776.20 6/9/2010 4.51 776.46 12/8/2010 5.65 775.32 6/8/2011 5.45 775.52 12/6/2011 5.31 775.66 6/6/2012 5.14 775.83 12/3/2012 4.50 776.47 6/4/2013 5.52 775.45 12/3/2013 5.16 775.81 6/3/2014 5.28 775.69 12/2/2014 5.09 775.88 6/2/2015 5.52 775.45 UW09 3/27/1996 4.75 4.75 0.00 773.25 (778) 6/4/1996 4.25 773.75 10/24/1996 4.21 773.79 UW10 3/27/1996 6.61 778.95 (785.56) 6/6/1996 5.10 780.46 10/24/1996 5.95 779.61 1/14/2004 7.30 7.50 0.20 778.06 3/8/2005 6.42 779.14 6/7/2005 5.03 780.53 11/28/2005 7.54 778.02 6/19/2006 6.29 779.27 12/4/2006 6.07 779.49 (788.56) \ 6/11/2007 6.34 782.22 (785.56) 12/3/2007 8.86 776.70 6/2/2008 6.51 779.05 12/4/2008 7.51 778.05 6/3/2009 5.45 780.11 12/9/2009 5.92 779.64 6/8/2010 4.51 781.05 12/7/2010 7.19 778.37 6/7/2011 5.56 780.00 12/5/2011 6.61 778.95 6/6/2012 5.68 779.88 12/4/2012 8.48 777.08 6/4/2013 5.58 779.98 (788.56) 12/3/2013 6.67 781.89 6/3/2014 4.45 784.11 12/2/2014 5.32 783.24 6/2/2015 4.45 784.11 UW11 3/27/1996 _ 6.15 6.15 0.00 778.64 (784.79) 6/3/1996 5.95 778.84 10/24/1996 6.15 6.15 0.00 778.64 3/25/1999 7.22 777.57 3/25/1999 7.22 777.57 1/14/2004 7.60 777.19 3/7/2005 6.97 777.82 6/7/2005 6.38 778.41 6/11/2013 6.54 778.25 VE02 3/27/1996 4.09 781.33 (785.42) 6/4/1996 4.20 781.22 10/24/1996 4.10 781.32 3/25/1999 6.27 779.15 1/14/2004 6.20 6.50 0.30 778.92 3/7/2005 6.05 6.15 0.10 779.27 5/24/2005 5.31 5.34 0.03 780.08 6/7/2005 5.16 5.28 0.12 780.14 11/28/2005 7.86 7.92 0.06 777.50 6/19/2006 6.93 778.49 12/4/2006 6.12 779.30 6/11/2007 6.57 778.85 12/3/2007 9.18 776.24 6/2/2008 7.01 778.41 12/4/2008 7.74 777.68 6/4/2009 5.83 779.59 12/8/2009 6.25 779.17 6/8/2010 4.90 780.52 12/8/2010 8.47 776.95 6/7/2011 6.15 779.27 12/6/2011 7.63 777.79 6/6/2012 6.38 779.04 12/4/2012 8.91 776.51 6/4/2013 6.30 779.12 12/3/2013 7.76 777.66 6/3/2014 4.86 780.56 12/2/2014 5.89 779.53 6/2/2015 4.22 781.20 VE03 3/27/1996 (785.41) 6/4/1996 10/24/1996 5.10 4.30 4.44 780.31 781.11 780.97 URS Corporation - North Carolina Page 27 of 28 Appendix A Summary of Historical Groundwater Elevation Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) Well Date Depth To Depth To LNAPL Ground - (Datum Elev, LNAPL Water Thick- water ft MSL) (ft) (ft) ness Elevation (ft) (ft MSL) VE03 3/25/1999 4.45 780.96 (785.41) 1/14/2004 6.31 6.31 0.00 779.10 3/7/2005 5.84 5.85 0.01 779.56 5/24/2005 4.18 4.18 0.00 781.23 6/7/2005 2.33 783.08 6/11/2013 6.35 779.06 VE04 3/27/1996 5.23 780.23 (785.46) 6/4/1996 5.45 780.01 10/24/1996 4.95 780.51 3/25/1999 7.03 778.43 1/14/2004 6.87 6.87 0.00 778.59 3/7/2005 3.81 781.65 5/23/2005 5.67 779.79 6/7/2005 5.54 5.55 0.01 779.91 6/11/2013 7.06 778.40 VE05 3/27/1996 5.44 779.39 (784.83) 6/4/1996 4.98 779.85 10/24/1996 4.55 780.28 3/25/1999 4.81 780.02 1/14/2004 5.52 5.52 0.00 779.31 VE06 3/27/1996 5.13 780.06 (785.19) 6/4/1996 4.55 780.64 10/24/1996 4.95 780.24 3/25/1999 5.98 779.21 1/14/2004 3.40 781.79 VE07 3/27/1996 4.02 781.50 (785.52) 6/4/1996 4.03 781.49 10/24/1996 3.35 782.17 3/25/1999 4.27 781.25 12/29/2003 4.91 4.91 0.00 780.61 1/14/2004 5.25 780.27 3/22/2004 4.55 780.97 (785.22) 3/7/2005 4.39 780.83 (785.52) 6/7/2005 3.61 781.91 6/11/2013 4.49 781.03 Note: MSL = Mean Sea Level Groundwater elevations not corrected for LNAPL thickness. Data prior to 2007 were reported by previous suppliers and have not been verified. A trace of LNAPL was detected as denoted with a thickness of 0.00 feet and if blank, it was not detected. sock* = The trace of LNAPL encountered in late 2013 was removed from well (MW48) with absorbent socks during the 7 events in 2014. URS Corporation - North Carolina Page 28 of 28 Appendix B Laboratory Analytical Reports (See CD for laboratory reports) Appendix C Summary of Historical Analytical Data Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE AS01 6/9/2005 <1.0 <1.0 <1.0 <3.0 39.5 <2.0 57.2 DPEW01 6/24/1998 410 70 14 97 3 25 12/17/1998 70 7 <5 10 <5 <10 3 14 6/24/1999 11000 3600 50000 20000 180000 390 <1,000 <5,000 12/15/1999 10000 8400 63000 49000 120000 <100 <5,000 6/7/2000 12100 4680 58600 25800 67800 339 <50.0 864 12/7/2000 1150 659 1970 2660 1990 474 2.4 <0.500 6/5/2001 5400 3500 38000 20400 83000 730 <100 <100 12/7/2001 22 16 180 107 170 620 <1.0 6/20/2002 5.1 5.2 46 36 23 930 <1.0 12/17/2002 2900 3230 30500 21200 18700 <500 <250 6/5/2003 2630 3060 22600 18900 17500 710 <500 12/18/2003 2040 3080 21800 20100 19300 725 <200 6/8/2004 1570 1970 16700 12100 17300 397 <200 12/8/2004 1180 2190 8620 15300 13900 789 <200 6/28/2005 1140 1950 8110 17000 12600 590 <50 6/10/2013 6.5 J 817 45.8 4050 <5.3 338 <5.6 <6.3 DPEW02 6/24/1998 7 2 7 12/3/1998 15 <1 <5 <2 150 1 <1 <5 6/23/1999 42 11 <5 5 57 9 <1 <5 12/14/1999 13 <1 <5 2.1 170 <1 <1 <2 6/7/2000 18.8 2.37 0.93 2.69 51 <2.00 <0.500 <0.500 12/7/2001 <1.0 <1.0 <1.0 <2.0 120 <2.0 <1.0 6/19/2002 <2.0 <2.0 <2.0 <4.0 120 <4.0 <2.0 12/18/2002 0.84 <0.70 1.7 2.1 23.4 <1.0 <0.50 6/4/2003 39.4 13.3 <5.0 <15 121 62.9 <5.0 12/17/2003 3.9 <2.0 1 <6.0 76 1.2 0.79 6/7/2004 4.4 <2.0 <2.0 1.2 98.1 5 1 12/7/2004 <1.0 <2.0 <2.0 <6.0 28.7 3.5 <2.0 6/10/2005 2.2 <1.0 0.67 <3.0 30.5 1.4 0.74 6/12/2013 0.32 J <0.29 <0.2 <0.5 3.7 <1 <0.22 0.53 J DW01 6/9/2005 <1.0 <1.0 <1.0 <3.0 74.3 <2.0 0.95 12/5/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 6/21/2006 <1.0 <1.0 1.7 <3.0 0.53 <2.0 <1.0 <1.0 12/5/2006 <2 <2 <2 <6 95.8 <4 1.4 1.5 6/14/2007 <0.5 <0.5 <0.5 <1 69.4 <1 2.1 2.6 12/5/2007 0.35 J <0.2 <0.27 <0.56 168 <0.44 2.9 4.1 6/4/2008 0.12 J <0.1 <0.1 <0.1 260 <0.1 2.1 6.1 12/4/2008 0.12 J <0.1 <0.1 <0.1 600 <0.1 0.77 8.4 6/3/2009 <0.5 <0.8 <0.7 1 J 850 2.6 J <1 9.9 12/8/2009 <2 <2 <2 <2 480 <2 <2 5.1 J 6/8/2010 <2 <2 <2 <2 700 <2 <2 8.4 J 12/8/2010 <2 <2 <2 <2 570 <2 <2 6.3 J 6/7/2011 0.2 J <0.2 <0.2 <0.2 180 <0.2 <0.2 5.9 12/6/2011 <0.2 <0.2 <0.2 <0.2 240 <0.2 <0.2 8.1 6/6/2012 <0.2 <0.2 <0.2 <0.2 110 <0.2 <0.2 7.6 12/4/2012 0.39 J <0.1 <0.1 0.15 J 39 <0.1 0.19 J 9.7 6/4/2013 0.65 J <0.29 <0.2 <0.5 335 <1 <0.22 19.3 12/3/2013 <0.21 <0.2 <0.27 <0.2 79 <0.92 <0.34 7.5 6/3/2014 <0.21 <0.27 <0.21 <0.63 45 <0.34 <0.32 4.2 J 12/2/2014 <0.21 <0.27 J <0.21 <0.63 33 <0.78 J <0.32 2.9 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 29.6 <0.34 <0.32 1.9 URS Corporation - North Carolina Page 1 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE DW01A 6/9/2005 2.1 <1.0 <1.0 <3.0 450 <2.0 46 6/12/2013 0.66 J <0.58 <0.4 <0.99 406 <2 24.3 17.2 DW02 8/21/1996 1.9 <1 <1 <1 <5 6/24/1998 7 2 4 7 12/3/1998 32 <1 <5 3 <5 3 9 6/23/1999 8 <1 <5 <2 <5 <1 19 9 12/14/1999 62 <1 <5 <2 <5 <1 15 <2 6/7/2000 17.8 <0.500 <0.500 1.76 3.1 <2.00 4.03 7.27 12/6/2000 <0.500 <0.500 <0.500 2.1 4.2 <2.00 14.9 <0.500 6/5/2001 3 <1.0 <1.0 <2.0 <1.0 <1.7 <1.0 4.8 12/6/2001 23 <1.0 <1.0 <2.0 5.7 <2.0 10 7.1 6/19/2002 4.1 <1.0 <1.0 <2.0 1.3 <2.0 <1.0 4.5 12/18/2002 21 <0.50 <0.50 <0.70 9.3 <1.0 6.7 6/4/2003 4.2 <2.0 <2.0 <6.0 3.5 <2.0 5.3 12/17/2003 19.3 <2.0 2.5 <6.0 11.6 <2.0 5.5 6/7/2004 1.8 <2.0 <2.0 <6.0 3.9 <2.0 4.2 12/7/2004 1.7 <2.0 <2.0 <6.0 12.4 <2.0 5.3 6/9/2005 <1.0 <1.0 0.53 <3.0 2.6 <2.0 2.4 12/5/2005 <1.0 <1.0 <1.0 <3.0 0.67 <2.0 <1.0 <1.0 6/23/2006 12.1 6.7 2.4 42.1 2 6.7 2.8 1.1 12/4/2006 1.4 <1 1.2 <1 35.7 <2 18.8 6.1 6/13/2007 0.75 J <0.5 <0.5 <1 37.2 <1 14.6 5.8 12/4/2007 ' 3.6 <0.2 <0.27 <0.56 44.1 <0.44 16.2 6.1 6/4/2008 <0.1 <0.1 <0.1 <0.1 10 0.28 J 2.1 3.1 12/4/2008 0.29 J <0.1 <0.1 <0.1 27 <0.1 5.8 4.6 6/2/2009 <0.5 <0.8 <0.7 <0.8 3.4 J <1 1.5 J <0.8 12/8/2009 0.39 J <0.1 <0.1 <0.1 23 <0.1 6.9 2.9 6/8/2010 0.11 J <0.1 <0.1 <0.1 29 <0.1 3.2 4.7 12/8/2010 1.3 <0.1 <0.1 <0.1 37 <0.1 9.1 3.7 6/7/2011 0.14 J <0.1 <0.1 <0.1 37 <0.1 4.9 4.6 12/6/2011 2.8 <0.1 <0.1 <0.1 52 <0.1 12 4.9 6/7/2012 0.2 J <0.1 <0.1 <0.1 63 <0.1 9.2 5.1 12/4/2012 5.6 <0.1 <0.1 0.12 J 78 <0.1 15 5.5 6/5/2013 <0.21 <0.29 <0.2 <0.5 78.8 <1 11.7 5.1 12/3/2013 2.1 <0.2 <0.27 <0.2 81 <0.47 13 5.3 6/3/2014 <0.21 <0.27 <0.21 <0.63 56 <0.34 5.9 4.4 J 12/2/2014 3.8 <0.27 J <0.21 <0.63 95 <0.34 J 12 5.5 6/4/2015 <0.21 <0.27 <0.21 <0.39 78.7 <0.34 7.2 5.7 DW03 6/24/1998 62 12/4/1998 3 <1 <5 4 52 <1 <1 <5 6/23/1999 <1 <1 <5 <2 54 <1 1 <1 12/14/1999 <1 <1 <5 <2 72 <1 1.8 <2 6/7/2000 <0.500 <0.500 <0.500 <0.500 50.3 <2.00 1.54 0.756 12/6/2000 <0.500 <0.500 <0.500 1.42 51.6 <2.00 1.5 <0.500 6/5/2001 <1.0 <1.0 <1.0 <2.0 40 <1.5 <1.0 <1.0 12/6/2001 <2.0 <2.0 <2.0 <4.0 61 <4.0 <2.0 <2.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 53 <2.0 <1.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 70.5 <1.0 0.95 6/4/2003 <1.0 <2.0 <2.0 <6.0 63.4 <2.0 1.1 12/16/2003 <1.0 <2.0 0.97 <6.0 60.1 <2.0 0.99 6/7/2004 <1.0 <2.0 <2.0 <6.0 83.8 <2.0 0.99 12/7/2004 <1.0 <2.0 <2.0 <6.0 63.9 <2.0 0.89 URS Corporation - North Carolina Page 2 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE DWO3 6/9/2005 <1.0 <1.0 <1.0 <3.0 67.1 <2.0 0.8 12/5/2005 <1.0 <1.0 <1.0 <3.0 63.4 <2.0 1.2 0.95 6/20/2006 <1.0 <1.0 0.97 <3.0 66 <2.0 1.8 1.1 6/13/2007 <0.5 <0.5 <0.5 <1 66.2 <1 1.7 1.1 12/5/2007 <0.2 <0.2 <0.27 <0.56 64.1 <0.44 1.5 0.97 J 6/3/2008 <0.1 <0.1 <0.1 <0.1 59 <0.1 1.5 1 12/3/2008 <0.1 <0.1 <0.1 <0.1 59 <0.1 1.3 1.1 6/2/2009 <0.5 <0.8 <0.7 <0.8 68 <1 1.4 J 1 J 12/9/2009 <0.1 <0.1 <0.1 <0.1 68 <0.1 1.4 1.1 6/8/2010 <0.1 <0.1 <0.1 <0.1 61 <0.1 1.3 1.2 12/8/2010 <0.1 <0.1 <0.1 <0.1 71 <0.1 1.2 1.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 60 <0.1 0.94 1 12/6/2011 <0.1 <0.1 <0.1 <0.1 70 <0.1 1.3 1.3 6/7/2012 <0.1 <0.1 <0.1 <0.1 78 <0.1 1.3 1.5 12/4/2012 <0.1 <0.1 <0.1 <0.1 76 <0.1 1.2 1.5 6/5/2013 <0.21 <0.29 <0.2 <0.5 71.9 <1 1.5 1.5 12/4/2013 <0.21 <0.2 <0.27 <0.2 81 <0.47 <0.34 2 J 6/4/2014 <0.21 <0.27 <0.21 <0.63 86 <0.57 1.3 1.9 J 12/3/2014 <0.21 <0.27 <0.21 <0.63 82 <0.34 1.2 1.7 J 6/4/2015 <0.21 <0.27 <0.21 <0.39 99.5 <0.34 1.5 2.2 DWO4 12/4/1998 2 1 <5 5 <5 <1 <1 <5 6/25/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/14/1999 <1 <1 <5 <2 <5 <1 <1 <1 6/8/2000 0.652 0.502 <0.500 <0.500 2.02 <2.00 <0.500 <0.500 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 <1.0 <1.0 12/5/2001 <1.0 <1.0 <1.0 <2.0 1.2 <2.0 <1.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/6/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 DW05 6/9/2005 <1.0 <1.0 <1.0 <3.0 41.6 <2.0 4.2 12/5/2005 <1.0 <1.0 <1.0 <3.0 19.2 <2.0 <1.0 3.3 6/21/2006 0.71 <1.0 0.73 <3.0 40.9 <2.0 <1.0 5.4 12/5/2006 <1 <1 <1 <3 38.8 <2 0.7 4.6 6/13/2007 <0.5 <0.5 <0.5 <1 48.2 <1 0.64 J 5 12/5/2007 <0.2 <0.2 <0.27 <0.56 43 <0.44 0.5 J 4.4 6/3/2008 <0.1 <0.1 <0.1 <0.1 50 J <0.1 0.5 5 12/3/2008 <0.1 <0.1 <0.1 <0.1 37 <0.1 0.41 J 4.4 6/4/2009 <0.1 <0.1 <0.1 <0.1 30 <0.1 0.44 J 4 12/9/2009 <0.1 <0.1 <0.1 <0.1 38 <0.1 0.37 J 4.3 6/8/2010 <0.1 <0.1 <0.1 <0.1 36 <0.1 0.35 J 4.7 12/7/2010 0.74 0.24 J <0.1 0.6 47 <0.1 0.32 J 4 6/7/2011 <0.1 <0.1 <0.1 <0.1 34 <0.1 0.22 J 3.7 12/6/2011 0.2 J <0.1 <0.1 <0.1 47 <0.1 0.25 J 4.6 6/6/2012 <0.1 <0.1 <0.1 <0.1 42 <0.1 0.23 J 3.9 12/4/2012 0.26 J <0.1 <0.1 0.1 J 47 <0.1 0.22 J 4.5 6/5/2013 <0.21 <0.29 <0.2 <0.5 52.3 <1 <0.22 4.2 12/3/2013 <0.21 J <0.2 J <0.27 J <0.2 J 58 <0.54 <0.34 5.2 6/4/2014 <0.21 <0.27 <0.21 <0.63 54 <0.44 <0.32 4.6 J 12/3/2014 <0.21 29 J <0.21 17 <0.28 54 J <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 50.5 <0.34 <0.32 4.4 DW06 6/24/1998 370 12/3/1998 24 <1 <5 2 11000 1 9 74 URS Corporation - North Carolina Page 3 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE DWO6 6/24/1999 <1 <1 <5 <2 13000 <1 11 93 12/15/1999 <10 <10 <50 <20 12000 <1 11 100 6/8/2000 <0.500 <0.500 4.6 <0.500 4050 <2.00 7.87 93.7 12/6/2000 0.631 <0.500 <0.500 <0.500 3800 <2.00 5.08 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 8600 <1.5 4.3 67 12/6/2001 <1.0 <1.0 <1.0 <2.0 810 <2.0 <1.0 5.5 6/19/2002 <5.0 <5.0 <5.0 <10.0 4100 <10 <5.0 66 12/18/2002 <50 <70 <50 <100 6350 <100 57.6 6/4/2003 <100 <200 <200 <600 3720 <200 <200 12/17/2003 11.9 7.6 1 1.2 33.8 8.2 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 972 <2.0 10.7 12/7/2004 <100 <200 <200 <600 4980 <200 <200 6/13/2005 <1.0 <1.0 <1.0 <3.0 6240 <2.0 47.7 12/6/2005 <100 <100 <100 <300 4990 <200 <100 <100 6/21/2006 <50 <50 <50 <150 4840 <100 <50 30.5 12/5/2006 <100 <100 <100 <300 6290 <200 <100 <100 6/14/2007 <50 <50 53.1 J 94.9 J 4200 <50 J <50 34.8 J 12/4/2007 <10 <10 <14 <28 4600 <22 2.2 37 J 6/3/2008 <5 <5 <5 5.3 J 4100 14 J <5 24 12/4/2008 <2 <2 <2 <2 3400 <2 <2 24 J 6/3/2009 <2.5 <4 <3.5 <4 3000 <5 <5 25 12/8/2009 <5 <5 <5 <5 2200 <5 <5 35 6/7/2010 <5 <5 <5 <5 1200 <5 <5 36 12/7/2010 <5 <5 <5 <5 1700 <5 1.9 J 32 6/7/2011 <1 <1 <1 <1 1400 <1 1.6 J 28 12/5/2011 <0.5 <0.5 <0.5 <0.5 1800 <0.5 2.3 J 37 6/6/2012 <5 <5 <5 <5 1500 <5 1.6 J 22 J 12/4/2012 <2 <2 <2 <2 1500 <2 1.8 J 22 6/4/2013 <5.3 <7.3 <5 <12 1400 <25 2.1 22.2 J 12/3/2013 <0.21 <0.2 <0.27 <0.2 990 <0.47 3 42 6/3/2014 <1.1 <1.4 <1 <3.2 820 <1.7 2 35 12/2/2014 <1.1 <1.4 <1 <3.2 820 J <1.7 J 9.7 J 53 J 6/3/2015 <0.21 <0.27 <0.21 <0.39 383 <0.34 2.2 39.5 DWO7 6/7/1995 BDL BDL BDL BDL BDL BDL BDL BDL 6/23/1998 710 92 220 700 26 100 12/4/1998 22 3 <5 5 300 2 13 47 6/22/1999 15 2 <5 3 180 <1 10 37 12/14/1999 100 13 8 24 660 <1 5.1 66 DW08 9/13/1994 1 BDL BDL BDL 15 BDL 5 BDL 6/23/1998 34 41 12/4/1998 <1 <1 <5 <2 <5 <1 49 52 6/22/1999 <1 <1 <5 <2 <5 6 46 52 12/14/1999 <1 <1 <5 <5 <5 <1 55 72 6/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 35.2 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 37.6 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.8 35 46 12/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 59 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 43 56 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 32 72.4 6/3/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 36.4 69.3 12/16/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 15.3 12.8 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 37.9 76.5 URS Corporation - 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North Carolina Page 6 of 40 URS Corporation - North, Carolina Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ESO5DR 12/7/2010 71 0.62 J 0.38 J 1.9 71 6.1 4.9 3.3 6/7/2011 110 2.6 0.6 J 8.4 66 6.6 5.4 3.2 12/6/2011 62 0.47 J 0.38 J 1.7 77 4 2.6 3.5 6/6/2012 25 0.28 J <0.2 1 140 1.4 3.8 4 12/5/2012 51 0.37 J 0.42 J 1.1 79 2.7 2.9 4 6/5/2013 40.6 0.71 J 0.25 J 1.1 J 173 1.6 J 4.3 4.3 12/4/2013 83 <0.2 0.65 J 4.13 J 110 11 2.8 4.3 J 6/4/2014 74 2.3 J 0.54 J <3.9 210 J <4.9 3.4 4.1 J 12/3/2014 88 0.8 J 0.63 J 4.4 J 200 8.1 3 4.9 J 6/3/2015 554 16.4 4 11.8 2.1 24 <0.32 10.4 ESO5SR 6/28/2005 905 65.1 5 174 4.4 27.1 4.8 20.9 11/30/2005 2870 266 5.9 351 3.7 46.8 <5.0 16.1 6/23/2006 2420 195 <50 284 <50 52.6 <50 <50 12/6/2006 1060 59.9 <20 112 <20 22.6 <20 15.6 6/13/2007 2520 336 <25 604 <25 132 <25 43.7 J 12/4/2007 2690 255 <14 362 <13 <114 <10 21.7 J 6/3/2008 1700 110 5.7 86 3 J 49 <1 16 12/3/2008 1900 130 6.7 J 100 3.1 J 55 <2 16 6/4/2009 700 44 2.4 J 83 2.8 23 <0.5 13 12/9/2009 1100 20 3.5 J 34 2.9 J 25 <1 14 6/8/2010 2800 240 10 380 3.3 J 110 <1 17 12/7/2010 1700 66 5.9 45 3 J 51 <1 13 6/6/2011 2100 180 9.4 280 2.7 J 99 <1 14 12/6/2011 1200 7.8 4.4 J 8.9 3 J 30 <1 14 6/6/2012 1100 29 4.3 J 36 2.8 J 30 <1 14 12/4/2012 1800 15 6.1 20 2.7 38 <0.5 14 6/5/2013 3.2 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/4/2013 1100 49 6.7 J 29.9 2.9 J 44 <1.7 14 J 6/4/2014 1100 58 6.7 J 29.4 2.3 J 44 <1.6 9.8 J 12/3/2014 1300 120 9.5 J 41 3.6 J 65 <1.6 16 J 6/3/2015 4 <0.27 <0.21 <0.39 302 <0.34 <0.32 5.5 ES06 9/12/1994 BDL BDL BDL BDL BDL BDL 3 3/10/1995 BDL BDL BDL BDL BDL BDL BDL BDL 6/7/1995 BDL BDL BDL BDL 4 BDL 1 BDL 9/18/1995 BDL BDL BDL BDL 1 BDL BDL 0.6 12/5/1995 BDL BDL BDL BDL BDL BDL 10/9/1996 <1 <1 <1 <1 1.9 <5 <1 <1 5/23/1997 <1 <1 <1 <1 10 <6 1.3 1.2 6/5/1997 <1 <1 <1 <1 7 <2 <1 <2 6/24/1998 8 2 12/2/1998 <1 <1 <5 <2 10 <10 1 <5 6/24/1999 <1 <1 <5 <2 12 <10 <1 <5 12/15/1999 <1 <1 <5 <2 17 <10 <1 <5 6/8/2000 <0.500 <0.500 0.98 <0.500 14.4 <2.00 <0.500 1.03 12/7/2000 <0.500 <0.500 <0.500 <0.500 11.8 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <2.0 7.6 <5.1 <1.0 1.5 12/6/2001 <1.0 <1.0 <1.0 <2.0 16 <2.0 <1.0 1.4 6/19/2002 <1.0 <1.0 <1.0 <2.0 23 <2.0 <1.0 1.6 12/18/2002 <0.50 <0.70 <0.50 <1.0 14.9 <1.0 1.5 6/4/2003 <1.0 <2.0 <2.0 <6.0 9.8 <2.0 1.2 12/17/2003 <1.0 <2.0 <2.0 <6.0 8.8 <2.0 0.86 6/8/2004 <1.0 <2.0 <2.0 <6.0 10.6 <2.0 0.99 URS Corporation - North Carolina Page 8 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES06 12/7/2004 <1.0 <2.0 <2.0 <6.0 9.5 <2.0 0.85 ES07 9/12/1994 12/12/1994 3/10/1995 6/5/1995 9/18/1995 12/4/1995 4 BDL BDL BDL 0.6 BDL 2 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1 BDL BDL BDL BDL BDL 10/9/1996 <1 <1 <1 <1 <1 <5 <1 <1 5/23/1997 1.3 <1 <1 <1 1.3 <6 <1 1.2 6/5/1997 <1 <1 <1 <1 <2 <2.1 <1 <2 3/7/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 6/12/2013 <0.21 <0.29 <0.2 <0.5 1.8 1.1 J <0.22 0.67 J ES08 9/12/1994 520 970 87 3,100 270 370 BDL 6/6/1995 2520 480 17 280 670 335 64 BDL 9/19/1995 3000 540 15 300 680 370 76 39 12/5/1995 220 420 34 2,020 280 BDL 10/3/1996 4100 610 <50 230 770 440 <50 <50 5/23/1997 810 140 <5 78 75 320 51 <5 6/5/1997 2640 320 10 130 520 440 60 <20 6/24/1998 4100 350 200 720 180 50 12/3/1998 1500 71 <50 44 440 110 62 <50 6/24/1999 2100 460 <50 400 280 77 16 <50 12/15/1999 1000 98 5.9 <1 400 98 44 19 6/8/2000 1360 157 <5.00 39.9 359 36.9 14.4 14 12/6/2000 443 40.5 0.768 19.4 215 63.7 33.2 <0.500 6/5/2001 660 61 <1.0 17.1 620 89 39 7 12/6/2001 350 <25 <25 <50 340 <50 <25 <25 6/19/2002 450 25 <10 13 470 71 39 10 12/17/2002 320 27 0.55 13.8 260 61 24.6 8.3 6/4/2003 546 103 <10 12.6 124 104 10.7 2.8 12/17/2003 334 50.8 <20 <60 222 77.1 16 <20 6/8/2004 525 158 <20 12 301 150 7.1 <20 12/7/2004 196 57.8 0.91 7.5 271 69.1 11.7 4.8 ESO8DR 6/13/2005 4.6 2 <1.0 3.4 3.8 <2.0 0.89 <1.0 12/5/2005 2.6 <1.0 <1.0 <3.0 3 <2.0 0.53 <1.0 6/21/2006 1.5 <1.0 1.5 <3.0 4.6 <2.0 0.98 <1.0 12/5/2006 65.1 <1 0.7 <3 17.7 17.8 4.6 0.8 6/13/2007 <0.5 <0.5 <0.5 <1 3.5 <1 1.8 <0.5 12/4/2007 3.2 <0.2 <0.27 <0.56 10.3 <1.6 5.6 0.71 J 6/3/2008 0.76 <0.1 <0.1 <0.1 4.3 0.67 2.3 0.25 J ES08SR 6/13/2005 1710 46.1 4.7 224 337 52.6 138 16.3 11/28/2005 2910 190 3.7 302 274 319 85.9 13.5 6/22/2006 2380 146 2.2 270 374 402 83.1 11.8 12/6/2006 2040 177 <50 131 370 450 83.1 <50 6/13/2007 1760 136 <25 54 J 353 296 76.9 <25 12/4/2007 1920 290 <14 <28 339 397 32.6 J 12.5 J 6/3/2008 1200 87 <1 10 290 300 62 J 8.2 ES09 9/13/1994 5 BDL BDL BDL BDL BDL BDL 12/13/1994 8 BDL BDL BDL BDL BDL 4 BDL 3/10/1995 4 BDL BDL BDL 6 BDL 4 BDL 6/7/1995 BDL BDL BDL BDL 12 BDL 8 BDL 9/20/1995 0.6 BDL BDL BDL 8 BDL 3 3 URS Corporation - 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North Carolina Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES12 12/7/2004 1.3 <2.0 <2.0 <6.0 13.6 <2.0 <2.0 6/13/2005 0.57 <1.0 <1.0 <3.0 9.3 <2.0 <1.0 6/12/2013 14.6 <0.29 2.8 0.65 J 7.8 <1 <0.22 <0.25 ES13 9/12/1994 14 6 BDL 5 14000 BDL 10 12/13/1994 11 2 7 4 18000 BDL BDL BDL 3/10/1995 71 BDL BDL BDL 18000 BDL 4 380 6/7/1995 BDL BDL BDL BDL 11700 7 BDL 350 9/18/1995 16 4 2 8 13000 BDL BDL 480 12/5/1995 11 BDL 2 4 BDL 2.2 10/3/1996 13 2.1 1.4 8.3 8800 <5 4.4 380 5/23/1997 19 <1 2.2 5.9 5400 <6 <50 270 6/5/1997 12 2 2 9 6100 2 2 302 6/24/1998 3 12000 330 12/2/1998 3 3 <5 3 13000 <10 5 410 6/24/1999 140 12 <50 55 7000 16 <10 330 12/15/1999 <10 3.6 <5 11 8500 <10 3.9 410 6/8/2000 1.8 1.05 0.86 1.12 4080 <2.00 1.81 281 12/7/2000 <20.0 <20.0 359 242 4940 <2.00 <20.0 <20.0 6/6/2001 1.2 <1.0 <1.0 <3.0 7400 <5.2 1.7 250 12/6/2001 <20 <20 <20 <40 7800 <40 <20 230 6/19/2002 <20 <20 <20 <40 3400 <40 <20 210 12/17/2002 <0.50 <0.70 <0.50 <1.0 43.1 <1.0 1.2 6/4/2003 <1.0 <2.0 <2.0 <6.0 8660 <2.0 323 12/16/2003 <100 <200 <200 <600 3860 <200 162 6/8/2004 <100 <200 60.3 <600 3740 <200 131 12/7/2004 <100 <200 <200 <600 5810 <200 179 6/13/2005 <10 <10 <10 <30 4920 <20 177 11/29/2005 2.4 <1.0 <1.0 <3.0 4510 <2.0 1.1 146 6/20/2006 <100 <100 <100 <300 4640 <200 <100 195 12/5/2006 <20 <20 <20 <60 1500 68.6 <20 135 6/14/2007 0.57 J <0.5 <0.5 <1 218 <1 0.82 J 149 12/4/2007 <0.4 <0.4 <0.54 <1.1 26.5 <0.88 0.97 J 158 6/3/2008 <0.1 <0.1 <0.1 <0.1 25 0.33 J 0.65 120 12/4/2008 0.15 J <0.1 <0.1 <0.1 24 <0.1 0.9 140 6/4/2009 0.11 J <0.1 <0.1 <0.1 22 <0.1 0.92 120 12/8/2009 <0.5 <0.5 <0.5 <0.5 140 1.7 J 1.5 J 140 6/7/2010 0.39 J <0.1 0.16 J 0.2 J 57 0.46 J 0.62 110 12/7/2010 <0.5 <0.5 <0.5 <0.5 9.9 <0.5 0.82 J 140 6/6/2011 0.53 J <0.5 <0.5 <0.5 16 <0.5 <0.5 130 12/5/2011 <0.5 <0.5 <0.5 <0.5 7.3 <0.5 0.9 J 130 6/6/2012 0.3 J <0.2 <0.2 <0.2 11 <0.2 0.49 J 120 12/4/2012 0.27 J <0.2 <0.2 <0.2 9.3 <0.2 0.82 J 120 6/4/2013 0.37 J <0.29 <0.2 <0.5 12.4 <1 <0.22 95.1 12/3/2013 0.92 J <0.2 <0.27 <0.2 8.5 <0.71 <0.34 99 6/3/2014 <0.21 <0.27 <0.21 <0.63 24 <0.34 <0.32 38 12/2/2014 0.77 J <0.27 <0.21 <0.63 5.9 <0.34 <0.32 69 6/3/2015 0.93 J <0.27 <0.21 <0.39 14 <0.34 <0.32 20.6 ES14 9/12/1994 BDL BDL BDL BDL BDL 610 BDL 6/7/1995 835 17 BDL 3 3 81 23 23 9/18/1995 820 21 BDL 21 22 160 BDL 31 12/5/1995 480 24 BDL 14 100 26 10/3/1996 560 42 <5 <5 <5 220 4.4 46 URS Corporation - North Carolina Page 11 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES14 5/27/1997 7 2 BDL 9 63 44 8 6/5/1997 300 40 <5 35 25 92 30 35 6/24/1998 1200 160 290 190 58 57 12/2/1998 100 8 <5 3 <5 53 47 37 6/24/1999 1000 260 <50 710 <50 190 56 54 12/14/1999 100 33 6 <1 <5 6.4 55 49 6/8/2000 45.5 3.66 0.86 3.41 <0.500 <2.00 23.2 39.1 12/6/2000 4.65 1.43 <0.500 2.23 <0.500 <2.00 18.6 <0.500 6/6/2001 8.2 <1.0 <1.0 <3.0 <1.0 <1.7 19 30 12/6/2001 15 2.6 3.7 7.3 2.6 16 13 30 6/19/2002 18 2.3 <1.0 <2.0 <1.0 14 <1.0 23 12/17/2002 11.8 2.9 <0.50 <1.0 0.65 20.9 9.3 29 6/4/2003 982 213 10.6 548 <20 312 32.1 33.6 12/16/2003 349 88.8 <20 34.1 <20 363 <20 32 6/8/2004 93.6 17.9 <2.0 3.1 2.5 79.6 <2.0 31.1 12/7/2004 188 55 <10 39.8 3.3 142 6.9 26.9 6/13/2005 132 32.2 2 43.5 2.3 51.5 <2.0 15.7 11/29/2005 10.5 4.1 <1.0 <3.0 1.9 5.1 6.1 21.5 6/23/2006 9 2.2 <1.0 <3.0 2.2 3.9 3.7 19.9 12/5/2006 26.3 10.5 <1 <3 2.6 13.5 6 135 6/14/2007 36.4 10.8 <0.5 <1 2 9.2 5.3 25.1 12/4/2007 12.8 4.2 <0.27 <0.56 1.9 5.4 6.7 24.2 6/3/2008 7.9 2.2 <0.1 0.14 J 1.2 1.6 3.5 12 12/4/2008 0.72 1.5 <0.1 0.13 J 1.4 0.86 4.4 17 6/2/2009 340 160 4.3 J 310 3.3 J 300 23 18 12/8/2009 86 31 0.7 43 4.4 65 9.9 19 6/7/2010 75 40 0.18 J 18 3.8 89 <0.1 19 12/9/2010 20 12 <0.1 1.5 3.8 28 <0.1 17 6/6/2011 69 33 0.44 J 34 3.2 110 7.9 14 12/5/2011 4.2 5.5 <0.1 0.55 2.8 7.2 2.9 15 6/6/2012 21 12 <0.1 7.1 1.8 37 3.3 9.2 12/4/2012 1.4 2.4 <0.1 0.16 J 1.9 5.2 2.6 12 6/4/2013 15.6 10.5 <0.2 6.7 0.75 J 38.3 2.9 5.9 12/3/2013 7.9 5 <0.27 1.2 J 1 12 1.9 7.6 6/3/2014 7.6 5.1 <0.21 <1.4 <0.28 14 1.5 4.2 J 12/2/2014 5 9.1 J <0.21 4.55 J 0.46 J 38 J 1.2 2.9 J 6/3/2015 3.8 6.7 <0.21 <0.39 0.48 J 0.93 J 1.8 4.6 ES15 9/12/1994 14 6 BDL 5 14000 BDL 10 3/10/1995 BDL BDL BDL BDL BDL BDL BDL BDL 6/6/1995 1.2 BDL BDL BDL 9.3 2.1 BDL BDL 9/18/1995 1.2 BDL BDL BDL 2 BDL BDL 1 12/5/1995 BDL BDL BDL BDL BDL BDL 10/3/1996 <1 <1 <1 <1 <1 <5 <1 <1 5/23/1997 <1 <1 <1 1.6 <1 <6 <1 <1 6/5/1997 <1 <1 <1 <1 <2 <2.1 <1 <2 6/12/2013 <0.21 <0.29 <0.2 <0.5 113 <1 <0.22 0.48 J ES17 9/18/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <1 <1 <1 <10 <2 <1 <10 6/2/1997 <1 <1 <1 <1 <10 <2.3 <1 <10 3/7/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 ES18 3/23/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 URS Corporation - North Carolina Page 12 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES18 12/1/2005 <1.0 <1.0 <1.0 <3.0 <1.0 8.1 <1.0 <1.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 1 9.1 <1.0 <1.0 12/5/2006 <1 <1 <1 <3 <1 7.7 <1 <1 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J 0.99 J 2.2 J <0.5 J <0.5 J 12/4/2007 <0.2 0.46 J <0.27 <0.56 <0.25 <1.2 <0.2 <0.2 6/3/2008 <0.1 0.4 J 0.13 J 0.39 J 0.13 J 3.7 <0.1 <0.1 12/3/2008 0.1 J 0.52 0.21 J 0.35 J <0.1 13 <0.1 <0.1 6/3/2009 <0.5 <0.8 <0.7 <0.8 <0.5 <1.6 <1 <0.8 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.13 J 1.8 <0.1 <0.1 6/8/2010 0.14 J 0.2 J 0.23 J <0.1 0.2 J 4.1 <0.1 <0.1 12/8/2010 0.76 0.33 J 0.48 J 0.41 J 0.42 J 7.7 <0.1 0.15 J 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/7/2011 <0.1 0.12 J 0.14 J <0.1 0.15 J 3.6 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 0.22 J <0.1 <0.1 12/4/2012 0.55 0.43 J 0.3 J 0.18 J 0.1 J 3.9 <0.1 <0.1 6/5/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/3/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 1.3 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 ES19 6/24/1998 9 2 5 11 12/3/1998 5 2 <5 <2 <5 <1 <1 <5 6/24/1999 5 4 <5 3 <5 <1 <1 <5 12/15/1999 <1 <1 <5 <1 <5 <1 <1 <5 6/8/2000 0.694 <0.500 6.72 <0.500 <0.500 <2.00 <0.500 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/19/2002 3.2 3.1 <1.0 <2.0 <1.0 5 <1.0 12/17/2002 14.9 111 55.7 292 <1.0 115 <1.0 6/4/2003 <1.0 2.2 <2.0 6.2 <2.0 6.4 <2.0 12/16/2003 2.2 174 4.7 595 <2.0 190 <2.0 6/8/2004 0.84 56.4 <2.0 91.3 <2.0 63.5 <2.0 12/7/2004 0.82 26.2 <2.0 26.4 <2.0 23.3 <2.0 6/10/2005 0.92 4.4 <1.0 5 <1.0 4.6 <1.0 11/29/2005 2.1 27.4 <1.0 88.8 <1.0 53.5 <1.0 <1.0 6/20/2006 <1.0 <1.0 <1.0 1.2 <1.0 2.9 <1.0 <1.0 12/5/2006 0.7 <1 0.6 <3 <1 1.6 <1 <1 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J <0.5 J <1 J <0.5 J <0.5 J 12/4/2007 0.24 J 0.33 J <0.27 <0.56 <0.25 <0.96 <0.2 <0.2 6/3/2008 0.3 J 0.16 J 0.12 J 0.14 J <0.1 0.7 <0.1 <0.1 ES20 6/5/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <1 <1 <1 <10 <2 <1 <10 5/23/1997 <1 <1 <1 <1 <1 <6 <1 <1 6/2/1997 <1 <1 <1 <1 <10 <2.2 <1 <10 3/7/2006 <1.0 <1.0 <1.0 <3.0 0.62 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 0.48 J <1 <0.22 <0.25 ES23 6/24/1998 15 12/2/1998 <1 <1 <5 <2 17 <1 <1 <5 6/23/1999 <1 <1 <5 <2 16 <1 <1 <5 12/15/1999 <1 <1 <5 <2 8.2 <1 <1 <5 URS Corporation - North Carolina Page 13 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES23 6/7/2000 <0.500 <0.500 2.44 <0.500 12 <2.00 <0.500 1.55 12/6/2000 <0.500 <0.500 <0.500 <0.500 3.44 <2.00 <0.500 <0.500 6/5/2001 <1.0 <1.0 <1.0 <2.0 3.1 <1.5 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 1.5 <2.0 <1.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 1.5 <2.0 <1.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 0.5 5.9 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 2 <3.0 <1.0 <2.0 <1.0 6/10/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 ES25 6/5/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/4/1995 BDL BDL BDL BDL BDL BDL BDL BDL 12/2/1996 <1 <1 <1 <1 <10 <2 <1 <10 6/2/1997 <1 <1 <1 <1 <10 <2.2 <1 <10 12/1/1998 <1 <1 <5 <2 <5 <1 <1 <5 6/25/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/16/1999 <1 <1 <5 <2 <5 <1 <1 <5 6/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.5 <1.0 <1.0 12/5/2001 <1.0 <1.0 <1.0 <2.0 3.9 <2.0 <1.0 6/20/2002 700 20 530 204 9.5 9.9 <1.0 12/18/2002 13000 746 16000 5340 <130 <250 <130 6/5/2003 6440 1330 22700 9110 <500 261 <500 12/18/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2004 2200 1730 16700 11200 <400 606 <400 12/7/2004 2440 1320 11200 9580 <200 265 <200 6/28/2005 1380 671 6530 4800 28.4 134 <50 6/14/2007 943 J 1770 J 6860 J 10700 J 20.6 505 J <0.5 94.4 12/4/2007 <0.2 <0.2 <0.27 <0.56 <0.25 <0.44 <0.2 <0.2 6/3/2008 660 1400 5400 8400 22 J 480 <5 100 12/3/2008 620 2000 5700 10000 13 J 570 <10 98 6/2/2009 560 1900 6200 13000 22 J 550 <10 160 12/8/2009 230 2000 4600 12000 22J 550 <5 130 6/8/2010 12 100 23 430 3.1 100 <0.5 8.9 12/8/2010 2.2 13 5.5 150 2.7 33 <0.2 7 6/6/2011 0.19 J 1.7 0.76 15 0.76 2.8 <0.1 3.3 12/7/2011 0.17 J 4.6 0.48 J 35 0.68 11 <0.1 3.1 6/6/2012 <0.1 0.24 J 0.15 J 2.5 <0.1 0.57 <0.1 <0.1 12/4/2012 <0.1 0.12 J <0.1 <0.1 <0.1 <0.1 <0.1 0.11 J 6/5/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/4/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/3/2014 <0.21 <0.27 J <0.21 <0.63 <0.28 <0.34 J <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 ES26 12/3/1998 <1 <1 <5 <2 <5 <1 <1 <5 6/23/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/15/1999 <1 <1 <5 <2 <5 <1 <1 <5 6/7/2000 <0.500 <0.500 1.23 <0.500 <0.500 <2.00 <0.500 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 URS Corporation - North Carolina Page 14 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES26 6/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.6 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 0.85 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 12/5/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 6/23/2006 10.6 8.3 1.8 44.2 <1.0 6.2 <1.0 <1.0 6/14/2007 <0.5 <0.5 <0.5 <1 <0.5 <1 <0.5 <0.5 12/4/2007 <0.2 <0.2 <0.27 <0.56 2.4 <0.44 0.99 J <0.2 6/4/2008 <0.1 <0.1 <0.1 <0.1 0.83 <0.1 0.58 0.13 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 4.1 <0.1 1.3 0.15 J 6/4/2009 <0.1 <0.1 <0.1 <0.1 2.1 <0.1 1.2 0.13 J 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.6 <0.1 0.68 0.12 J 6/7/2010 <0.1 <0.1 <0.1 <0.1 0.72 <0.1 0.93 0.19 J 12/7/2010 <0.1 <0.1 <0.1 <0.1 2.8 <0.1 1.6 0.16 J 6/7/2011 <0.1 <0.1 <0.1 <0.1 0.63 <0.1 0.7 0.11 J 12/6/2011 <0.1 <0.1 <0.1 <0.1 0.59 <0.1 0.49 J 0.11 J 6/6/2012 <0.1 <0.1 <0.1 <0.1 1 <0.1 0.8 0.15 J 12/3/2012 <0.1 <0.1 <0.1 <0.1 0.2 J <0.1 0.52 <0.1 6/4/2013 <0.21 <0.29 <0.2 <0.5 0.4 J <1 0.6 J <0.25 12/3/2013 <0.21 <0.2 <0.27 <0.2 1.8 <0.47 0.9 J <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 1.6 <0.34 1 <0.2 12/2/2014 <0.21 <0.27 J <0.21 <0.63 2.4 <0.34 J <1 <0.2 ES28 10/23/1996 560 1.4 <1 1.6 1000 23 22 <8 6/14/2005 <1.0 <1.0 <1.0 <3.0 1120 <2.0 3.5 6/11/2013 <1.1 8.2 <1 <2.5 281 10 J <1.1 <1.3 6/3/2014 <0.21 <0.27 <0.21 <0.63 240 <0.34 1.1 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 160 <0.41 1.4 0.63 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 51.1 <0.34 <0.32 <0.2 ES29 12/2/1996 <1 <1 <1 <1 <10 <2 <1 <10 6/2/1997 <1 <1 <1 <1 <10 <2 <1 <10 12/2/1998 <1 <1 <5 <2 <5 <1 <1 <5 6/24/1999 <1 <1 <5 <2 <5 4 <1 <5 12/15/1999 <1 <1 <5 <2 <5 <1 <1 <5 6/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 1.6 <1.5 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 11/29/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 12/5/2006 <1 <1 <1 <3 <1 <2.0 <1 <1 URS Corporation - North Carolina Page 15 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES29 6/14/2007 <0.5 <0.5 <0.5 <1 <0.5 <1 <0.5 <0.5 12/4/2007 <0.2 <0.2 <0.27 <0.56 <0.25 <0.44 <0.2 <0.2 6/3/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/4/2009 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/7/2010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/4/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/4/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/3/2013 <0.21 J <0.2 J <0.27 J <0.2 J <0.2 <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 ES30 6/25/1998 3 5 3 320 12/2/1998 2 3 <5 <2 260 <1 <1 <5 6/23/1999 <1 <1 <5 <2 230 <1 <1 <5 12/15/1999 1.4 1.1 <5 <2 270 <1 1.3 <5 6/7/2000 1.3 <0.500 2.41 0.59 199 <2.00 <0.500 0.541 12/6/2000 0.5 <0.500 0.78 <0.500 173 <2.00 <0.500 <0.500 6/5/2001 <1.0 <1.0 <1.0 1 110 <1.5 <1.0 <1.0 12/6/2001 <5.0 <5.0 <5.0 <10.0 130 <10.0 <5.0 6/19/2002 <5.0 <5.0 <5.0 <10.0 120 <10 <5.0 12/18/2002 <1.0 <1.4 <1.0 <2.0 103 <2.0 <1.0 6/4/2003 0.71 1.2 <2.0 <6.0 65.2 1.9 <2.0 12/16/2003 <1.0 <2.0 <2.0 1.6 80.1 1.9 <2.0. 6/7/2004 <2.0 <4.0 <4.0 <12 166 <4.0 <4.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 83.2 <2.0 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 93.1 3.3 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 2.8 <1 <0.22 <0.25 ES31 6/13/2005 2.2 3.5 <1.0 1.5 2.6 5.8 5.7 11/29/2005 <1.0 <1.0 <1.0 <3.0 2.5 <2.0 3.9 4.3 6/20/2006 1.4 2.6 <1.0 <3.0 2.2 2.8 3.5 4.4 12/5/2006 <1 1.8 <1 <3 0.7 2.1 1.1 1.1 6/14/2007 0.72 J 0.71 J <0.5 <1 1.8 <1 3.2 3.9 12/4/2007 0.64 J 0.47 J <0.27 0.65 J 2 <1.2 2.4 3.1 6/4/2008 0.2 J 0.95 <0.1 0.52 <0.1 3.3 <0.1 <0.1 12/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/2/2009 <0.5 <0.8 <0.7 <0.8 <0.5 <1 <1 <0.8 12/8/2009 <0.1 <0.1 <0.1 <0.1 <0.1 0.44 J <0.1 <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 <0.1 0.34 J 0.17 J <0.1 12/7/2010 <0.1 0.48 J <0.1 1.4 <0.1 13 <0.1 <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/5/2011 <0.1 2.1 <0.1 2.5 <0.1 15 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/3/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.11 J 6/4/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/2/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 URS Corporation - North Carolina Page 16 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES31 12/2/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/2/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 ES32 10/23/1996 2900 650 340 2200 80 230 3.8 230 12/17/2002 8270 2360 8120 10900 67500 1040 <500 <500 6/5/2003 6470 1830 4980 8460 61700 1010 <2,000 <2,000 12/16/2003 6350 1880 3130 9210 56900 1070 <2,000 <2,000 6/8/2004 5730 2200 2550 10900 40700 892 <20 <20 9/21/2004 6750 2320 1770 11900 44100 1140 <200 59.9 12/8/2004 4780 1620 1050 8150 35400 671 <1,000 <1,000 6/28/2005 3060 1480 503 7420 6840 550 <100 <100 12/1/2005 4050 1800 597 8590 26800 868 <100 <100 6/22/2006 4080 1420 386 6650 22300 1020 <100 <100 12/6/2006 732 902 135 4020 1040 595 <50 <50 6/2/2009 0.72 J 1.6 J <0.7 5.2 1.3 J 5.7 <1 <0.8 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.39 J <0.1 <0.1 <0.1 6/7/2010 0.24 J <0.1 <0.1 0.1 J 0.98 0.23 J <0.1 <0.1 12/8/2010 33 7.1 0.86 8.7 47 8.7 1.1 0.13 J 6/6/2011 68 18 0.95 2.8 520 1.5 <0.1 1.6 12/5/2011 150 41 1.1 J 7.2 470 5.8 <0.5 0.99 J 6/6/2012 78 6.4 0.67 J 3.8 450 2.1 J <0.5 0.89 J 12/3/2012 180 12 2.3 J 18 790 15 <0.5 1.4 J 6/6/2013 71 1.2 0.56 J 5.6 218 3.3 J <0.22 <0.25 12/2/2013 37 5.6 0.71 J 18.6 12 11 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 2.2 <0.34 <0.32 <0.2 12/2/2014 0.38 J <0.27 <0.21 <0.63 0.55 J <0.34 <0.32 <0.2 ES33 6/24/1998 9100 380 160 870 1100 26 120 300 12/2/1998 8700 210 <500 270 3000 41 <100 <500 6/23/1999 11000 2500 27000 12000 51000 670 <1,000 <5,000 12/15/1999 13000 4600 36000 23000 120000 290 <1,000 <5,000 6/7/2000 17200 5550 35300 28800 117000 124 <50.0 1090 12/7/2000 4790 268 5940 3370 37000 740 <5.00 <5.00 6/5/2001 8400 2600 12000 12100 130000 <1.6 <100 220 12/6/2001 10000 <5,000 11000 17400 59000 <10,000 <5,000 <5,000 6/19/2002 8300 3000 8100 16400 40000 830 <250 <250 12/17/2002 9660 2670 4940 12900 30300 <1,000 <500 <500 6/5/2003 8520 2110 3510 11600 23300 888 <1000 <1000 12/16/2003 9080 2110 2470 12000 28200 911 <1,000 <1,000 6/8/2004 10500 2180 1940 13300 31200 1110 <1,000 <1,000 12/7/2004 8630 2000 1310 11600 16500 645 <200 68.2 6/28/2005 8110 1800 826 10100 18800 688 68.8 12/1/2005 6870 1710 631 10300 13300 1100 <100 <100 6/22/2006 7080 1020 471 8710 15600 919 <100 69.2 12/6/2006 5950 1360 340 7820 12100 842 <200 <200 6/14/2007 5730 J 1330 J 305 J 7550 J 9180 1180 J <50 J 68.1 J 12/4/2007 5650 1360 276 7210 8410 636 <20 60.3 J 6/4/2008 4400 1000 200 5900 8500 740 <10 47 J 12/4/2008 4100 970 150 5000 5900 790 <10 45 J 6/2/2009 3800 1000 130 6000 5900 1000 <20 43 J 12/8/2009 3100 910 110 5100 3900 900 <10 42 J 6/7/2010 3700 890 95 4800 3700 830 <10 46 J 12/7/2010 3200 750 81 3900. 2700 810 J <10 36 J 6/6/2011 3500 790 77 4200 2600 930 <10 42 J URS Corporation - North Carolina Page 17 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES33 12/5/2011 3700 670 73 3000 3200 660 J <10 52 6/6/2012 3600 550 65 2500 3200 740 <10 53 12/3/2012 3300 560 59 2100 2700 540 <10 48 J 6/6/2013 3350 573 57.7 2120 2800 674 <11 49 J 12/2/2013 3200 J 610 J 61 J 1880 J 3800 700 J <3.4 66 6/3/2014 1200 240 J 23 J 598 J 1300 230 J <1.6 23 J 12/2/2014 2700 530 48 J 1393 3500 580 <3.2 60 6/2/2015 3030 498 222 1520 3470 488 <16 55.6 ES34 6/24/1998 270 1 6 12/2/1998 <1 <1 <5 <2 230 3 <1 6 6/23/1999 <1 <1 <5 <2 250 <1 <1 7 12/16/1999 <1 <1 <5 <2 140 <1 <1 <5 6/7/2000 <0.500 <0.500 <0.500 <0.500 164 <2.00 <0.500 4.44 12/6/2000 <0.500 <0.500 <0.500 <0.500 114 <2.00 <0.500 <0.500 6/5/2001 <1.0 <1.0 <1.0 <2.0 160 <1.6 <1.0 4 12/6/2001 <5.0 <5.0 <5.0 <10.0 160 <10.0 <1.0 <5.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 100 <2.0 3 12/17/2002 <0.50 <0.70 <0.50 <1.0 88.8 <1.0 2.6 6/4/2003 <1.0 <2.0 <2.0 <6.0 33 <2.0 1.3 12/16/2003 <1.0 <2.0 <2.0 <6.0 84.9 <2.0 2.8 6/7/2004 <1.0 <2.0 <2.0 <6.0 55.8 <2.0 2.6 12/7/2004 <1.0 <2.0 <2.0 <6.0 71.3 <2.0 2.4 6/10/2005 <1.0 <1.0 <1.0 <3.0 50.3 <2.0 2.1 11/29/2005 <1.0 <1.0 <1.0 <3.0 96.8 <2.0 <1.0 3.1 6/20/2006 <1.0 <1.0 <1.0 <3.0 37.1 <2.0 <1.0 2.2 12/6/2006 <1 <1 <1 <3 34.5 <2 <1 1.7 6/2/2009 <0.1 <0.1 <0.1 <0.1 0.65 <0.1 <0.1 <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 0.14 J <0.1 <0.1 <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 2.1 <0.1 <0.1 <0.1 12/7/2010 <0.1 <0.1 <0.1 <0.1 0.84 <0.1 <0.1 <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 1.1 <0.1 <0.1 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 0.38 J <0.1 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 0.78 <0.1 <0.1 <0.1 12/3/2012 <0.1 <0.1 <0.1 <0.1 0.44 J <0.1 <0.1 <0.1 6/4/2013 <0.21 <0.29 <0.2 <0.5 0.59 J <1 <0.22 <0.25 12/2/2013 <0.21 <0.2 <0.27 <0.2 0.66 J <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/2/2014 <0.21 <0.27 J <0.21 <0.63 0.31 J <0.34 J <0.32 <0.2 6/2/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 ES35 6/25/1998 6900 26 43 150 700 510 12/2/1998 6100 <100 <500 <200 <500 52 800 <500 6/24/1999 5500 20 <50 26 520 110 580 <50 12/15/1999 3900 18 <50 21 <50 87 170 490 6/7/2000 3630 51.2 25.4 153 57.1 18.5 <20.0 339 12/6/2000 786 <10.0 <10.0 <10.0 <10.0 48.5 <10.0 <10.0 6/5/2001 3300 <200 <200 <400 220 <1.5 <200 <200 12/6/2001 1800 <100 <100 <200 <100 <200 <100 360 6/20/2002 2800 <50 <50 <100 <50 <100 <50 310 12/17/2002 2520 <35 <25 <50 <25 <50 <25 140 6/4/2003 2370 <100 <100 <300 <100 122 <100 280 12/16/2003 1360 <40 <40 <120 <40 86.2 <40 263 6/7/2004 1900 18.5 13.5 <120 <40 168 13.4 924 URS Corporation - North Carolina Page 18 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES35 12/7/2004 1190 6.2 3.7 2.8 <2.0 88.3 3.2 199 6/28/2005 1180 <50 <50 <150 <50 <100 202 12/1/2005 651 5.1 1.3 <6.0 1.1 47.6 2.2 174 6/22/2006 1630 12.1 4.2 3.3 1 177 <1.0 143 12/6/2006 822 <20 <20 <60 <20 55.3 <20 111 6/14/2007 1460 32 16.3 J <20 <10 110 14 J 76.2 12/4/2007 530 <2 <2.7 <5.6 <2.5 38.5 <2 173 6/4/2008 960 5.8 J 2.5 J <2 <2 75 30 J 95 12/4/2008 370 2.3 1.1 J 0.56 J 0.86 J 37 <0.5 110 6/2/2009 800 15 6.9 J 4.2 J <1 83 28 67 12/8/2009 520 8.2 2.6 J 1.6 J <2 40 <2 58 6/7/2010 700 14 5.6 5.5 <2 54 22 J 110 12/7/2010 290 2.8 1.4 J 0.54 J 1.2 J 36 <2 110 6/6/2011 670 5.6 J 3.1 J <2 <2 54 <2 98 12/5/2011 400 4.6 2.2 J 0.77 J 0.64 J 33 <0.5 59 6/6/2012 410 7.3 J 2.6 J 1.5 J 0.64 J 34 <2 62 12/3/2012 200 1.8 0.97 J 0.39 J 0.82 J 15 <0.25 69 6/4/2013 442 5.4 2.1 J 0.76 J <1.1 41.7 3.9 57.5 J 12/2/2013 130 1.5 J 0.58 J <0.2 1.7 J 16 0.61 J 99 6/3/2014 230 J 3.6 J 1.4 J <2.14 0.6 J 9.5 2.7 39 12/2/2014 98 1.7 J 0.68 J 0.69 J 1.7 9 1.5 78 6/2/2015 355 J 3.1 J 4.9 J 7.4 J <0.28 7.9 J 3 J 9.8 J ES37 10/23/1996 460 81 430 210 40 22 8.1 100 6/24/1998 1 12/2/1998 <1 <1 <5 <2 65 <1 <1 <5 6/23/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/14/1999 <1 <1 <5 <2 <5 <1 <1 <2 6/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.6 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 <1.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/4/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 ES38 6/24/1998 3 3 13 12/2/1998 5 <1 <5 2 <5 <1 <1 <5 6/23/1999 4 1 <5 <2 <5 4 <1 <5 12/14/1999 2.1 <1 <5 <2 <5 <1 1.8 <2 6/7/2000 2.6 0.94 <0.500 0.55 2.8 <2.00 1.84 1.57 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 2.81 <0.500 6/5/2001 1.4 <1.0 <1.0 <2.0 1 <1.6 <1.0 <1.0 12/6/2001 <1.0 <1.0 <1.0 <2.0 2.5 <2.0 3.3 2.1 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 <1.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/4/2003 2.2 0.54 <2.0 1.4 0.99 4.1 0.56 12/17/2003 <1.0 <2.0 <2.0 <6.0 2.4 <2.0 1.5 6/7/2004 <1.0 <2.0 <2.0 <6.0 4.3 <2.0 2 URS Corporation - North Carolina Page 19 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES38 12/7/2004 0.78 0.9 <2.0 <6.0 1.4 <2.0 0.61 6/8/2005 <1.0 <1.0 <1.0 <3.0 4.8 <2.0 1.2 11/30/2005 <1.0 <1.0 <1.0 <3.0 3.4 <2.0 2.4 1.3 6/20/2006 <1.0 <1.0 <1.0 <3.0 2 <2.0 0.62 0.97 12/5/2006 <1 <1 <1 <3 2.1 <2 1 0.8 6/13/2007 <0.5 <0.5 <0.5 <1 5 <1 2.4 1.6 12/4/2007 0.57 J 0.29 J <0.27 <0.56 3.6 <0.53 1.6 1.4 6/4/2008 0.11 J <0.1 <0.1 <0.1 0.79 0.4 J 0.26 J 0.43 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 0.81 0.65 6/3/2009 <0.1 <0.1 <0.1 <0.1 1.4 <0.1 0.45 J 0.33 J 12/9/2009 <0.1 <0.1 <0.1 <0.1 2.9 <0.1 0.71 0.43 J 6/8/2010 <0.1 <0.1 <0.1 <0.1 4.5 <0.1 1.2 1.2 12/8/2010 <0.1 <0.1 <0.1 <0.1 5.8 <0.1 1.2 1.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 0.76 <0.1 0.18 J 0.31 J 12/6/2011 <0.1 <0.1 <0.1 <0.1 2.4 <0.1 0.37 J 0.38 J 6/6/2012 0.16 J <0.1 <0.1 <0.1 2.9 0.13 J 0.26 J 0.69 12/4/2012 <0.1 <0.1 <0.1 <0.1 8 <0.1 1.4 1.2 6/4/2013 1.3 0.86 J 0.28 J 1.3 J 0.51 J 5.1 <0.22 <0.25 12/3/2013 <0.21 <0.2 <0.27 <0.2 3 <0.52 0.48 J 0.58 J 6/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 2.6 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 4.2 <0.43 J <0.32 0.59 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 8.6 <0.34 0.96 J 0.98 J ES39 6/10/2005 0.79 0.95 <1.0 <3.0 <1.0 <2.0 <1.0 ES40 6/10/2005 136 7.5 2.7 5.6 1.2 9.1 <1.0 11/29/2005 168 6.3 3.8 3.8 <2.0 18.3 <2.0 <2.0 6/22/2006 420 17.4 7.1 <30 <10 132 <10 <10 12/5/2006 126 6.1 2 2.4 <2 22.7 <2 <2 6/14/2007 177 J 8.6 3.6 7.1 <0.5 20.8 4.2 J <0.5 12/4/2007 285 16.9 7.1 14.5 J <1.3 35.7 <1 <1 6/4/2008 38 0.83 0.29 J 1 0.14 J 4 <0.1 <0.1 12/4/2008 13 1.3 0.32 J 0.48 J 0.16 J 1.5 <0.1 <0.1 6/2/2009 4.2 <0.1 <0.1 0.13 J <0.1 0.36 J 0.16 J <0.1 12/8/2009 8.9 0.67 0.23 J 0.53 0.14 J 2.6 0.32 J <0.1 6/7/2010 11 0.96 0.26 J 0.51 0.11 J 3.9 <0.1 <0.1 12/7/2010 94 2.3 2.2 2.6 0.25 J 58 <0.1 <0.1 6/6/2011 6.3 1.1 0.27 J 0.29 J <0.1 0.56 <0.1 <0.1 12/5/2011 62 2.6 2.3 3.7 0.16J 55 <0.1 <0.1 6/6/2012 9.5 0.47 J 0.31 J 0.48 J <0.1 1.6 <0.1 <0.1 12/3/2012 22 0.75 1.4 1.8 0.11 J 21 <0.1 <0.1 6/4/2013 2.1 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/2/2013 30 1.4 J 1.8 J 2.84 J <0.2 34 <0.34 <0.21 6/3/2014 6.8 0.55 J 0.63 J <2.08 <0.28 9.4 <0.32 <0.2 12/2/2014 20 1.1 J 1.6 J 2.1 J <0.28 29 <0.32 <0.2 6/2/2015 7.6 <0.27 0.9 J 1.8 <0.28 17.4 <0.32 <0.2 ES41 6/10/2005 0.55 0.61 <1.0 <3.0 <1.0 <2.0 <1.0 12/5/2007 <0.2 <0.2 <0.27 <0.56 <0.25 <0.44 <0.2 <0.2 6/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 0.29 J <0.1 <0.1 12/4/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/10/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 ES42 6/25/1998 240 42 2 6/24/1999 240 28 <5 37 <5 15 15 43 12/15/1999 <10 20 <50 39 <50 4.8 <10 <50 URS Corporation - North Carolina Page 20 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE ES42 6/7/2000 157 13.5 4.3 21.7 5 5.29 3.35 58.5 6/5/2001 23 <1.0 <1.0 6.2 1.7 <2.1 <1.0 24 6/20/2002 47 <1.0 <1.0 3.6 <1.0 15 <1.0 21 12/17/2002 102 9.1 1.5 13 <1.0 10.9 26 6/5/2003 75.3 1.8 1.2 8.2 1.2 5.2 30 12/16/2003 17.6 1.1 0.53 3 <2.0 3.2 18.6 6/7/2004 16.7 0.73 0.74 2.6 <2.0 2.5 16.1 12/7/2004 16.6 1 0.61 3.9 <2.0 2.8 18.6 6/13/2005 4.2 <1.0 <1.0 <3.0 0.52 <2.0 8.6 ES43 6/10/2005 0.7 1.2 <1.0 <3.0 15.3 <2.0 1.7 6/10/2013 1.6 <0.29 0.54 J 1.7 J 2.8 <1 <0.22 3.1 ES44 6/10/2005 <1.0 0.58 <1.0 <3.0 <1.0 <2.0 <1.0 MP06 6/9/2005 8.5 120 1.5 35.3 124 52.5 67.7 6/12/2013 <0.21 <0.29 <0.2 <0.5 124 <1 0.48 J 44.4 MW02 3/14/1995 4000 830 BDL 2000 BDL 250 BDL BDL 9/20/1995 2700 290 240 970 600 120 2 160 12/6/1995 5600 550 480 1860 180 BDL 5/23/1997 11000 1000 740 2900 2600 <500 330 6/25/1998 4100 280 830 1000 180 12/3/1998 12000 960 <500 2500 2800 150 <100 <500 6/24/1999 9800 740 <500 1900 2700 270 <100 <500 12/16/1999 8100 660 <500 1600 1800 84 <100 <500 6/8/2000 8150 482 180 1220 2210 165 <10.0 270 12/7/2000 7290 716 150 1540 2410 158 <20.0 <20.0 6/6/2001 4600 300 76 640 1600 80 <10 62 12/6/2001 9100 700 130 1190 4300 680 <100 140 6/20/2002 8400 440 <200 830 5200 200 <200 <200 12/18/2002 4460 355 65.3 609 2360 258 35.6 6/5/2003 1320 128 <100 227 374 54.5 <100 12/17/2003 6760 414 74.8 814 5120 309 63.7 6/8/2004 3030 197 50.8 493 2080 140 29.2 12/8/2004 9340 595 91.5 1150 9350 481 3.2 68.3 6/28/2005 1830 79.6 24.4 237 1590 85.7 <1.0 15.5 12/1/2005 7070 382 57.9 495 7790 288 <100 <100 3/7/2006 1170 <100 <100 248 7390 <200 <100 6/23/2006 4670 274 37 422 4170 226 <50 25.7 9/25/2006 4000 330 <500 460 4400 <500 <100 <100 12/6/2006 7260 439 73.6 612 5400 350 <100 <100 6/14/2007 7980 J 461 55.6 630 6280 J 375 <5 33.8 12/4/2007 4910 222 42.6 J 308 6170 <134 <20 <20 6/3/2008 4300 200 33 310 3100 130 <5 13 J 12/3/2008 1300 99 10 110 810 84 <2 4 J 6/2/2009 200 17 1.4 J 17 230 10 <1 1.2 J 12/8/2009 1500 130 15 J 160 1100 88 <5 <5 6/8/2010 210 26 3 27 100 21 <0.2 0.76 J 12/8/2010 4100 330 35 400 2200 270 <0.5 11 6/7/2011 1200 83 10 110 1300 69 <2 5.5 J 12/7/2011 190 48 2.2 J 35 70 43 <2 <2 6/6/2012 76 13 0.85 J 10 110 10 <0.2 0.58 J 12/4/2012 1100 95 9 J 93 1500 59 <2 5.3 J 6/5/2013 61 J 22.7 J 0.75 J 4.8 J 27 J 15.1 J <0.22 J <0.25 J 12/4/2013 270 41 3.8 J 29.2 210 20 <0.34 1.2 J URS Corporation - North Carolina Page 21 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW02 6/4/2014 0.45 J <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <1.3 <0.32 <0.2 6/3/2015 75 <0.27 0.58 J 1.7 48.2 3 <0.32 0.25 J MW03W 12/18/2002 2.1 <0.70 2.4 2.3 <0.50 <1.0 <0.50 12/17/2003 <1.0 <2.0 1.4 <6.0 <2.0 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 MW05 6/27/2005 13.7 9.1 1.7 27.3 2.2 15.8 <1.0 11/30/2005 10.6 109 7.3 314 <2.0 178 <2.0 <2.0 6/22/2006 3.1 260 6 994 <5.0 401 <5.0 <5.0 12/6/2006 1.5 119 1.8 377 <2 200 <2 <2 6/14/2007 19 470 5.2 J 1550 <5 828 <5 <5 12/4/2007 3.4 J 707 7.3 J 2010 <2.5 971 <2 <2 6/3/2008 <10 J 130 J <10 J 290 J <10 J 440 J <10 J <10 J 12/4/2008 0.56 J 62 <0.5 100 <0.5 94 <0.5 <0.5 6/4/2009 2.5 J 28 J 0.26 J 51 J <0.2 83 J <0.2 <0.2 12/9/2009 0.19 J 2.4 <0.1 4.1 <0.1 7 <0.1 <0.1 6/9/2010 9.8 12 1.9 21 <0.1 22 <0.1 <0.1 12/8/2010 0.27 J 4.7 0.16 J 6.6 <0.1 17 <0.1 <0.1 6/8/2011 8.6 21 1.8 43 <0.1 34 <0.1 <0.1 6/23/2011 39 38 4.3 J 82 <1 57 1.9 J <1 7/21/2011 210 450 45 1600 <1 410 <1 <1 8/16/2011 420 920 49 2400 <1 1200 <1 <1 11/22/2011 420 1200 55 2400 <5 700 <5 <5 2/16/2012 30 170 5.6 270 <1 180 <1 <1 6/6/2012 2.3 J 120 1.2 J 130 <1 160 <1 <1 12/4/2012 1.7 J 150 1.2 J 140 <1 200 <1 <1 6/4/2013 <0.42 70.5 0.51 J 33.7 <0.42 122 <0.44 <0.51 12/3/2013 <1 J 300 J <1.4 J 221.4 J <1 540 <1.7 <1 6/3/2014 0.32 J 1.5 J <0.21 <1.13 <0.28 5.4 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 51 <0.34 <0.32 4.6 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 <0.28 0.75 J <0.32 <0.2 MW06R 6/25/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/16/1999 <1 <1 <5 • <2 <5 <1 <1 <5 6/8/2000 0.8 <0.500 <0.500 1.08 <0.500 <2.00 <0.500 <0.500 6/20/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 <1.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/5/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 0.82 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 0.69 <6.0 1.2 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 MW07 12/16/1999 <1 <1 <5 <2 <5 <1 <1 <5 6/8/2000 0.794 <0.500 <0.500 0.988 <0.500 <2.00 <0.500 <0.500 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 <1.0 <1.7 <1.0 <1.0 12/5/2001 <5.0 <5.0 <5.0 <10.0 <5.0 290 <5.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 <1.0 2.3 <1.0 12/18/2002 3.9 1.2 5.4 6.3 <0.50 <1.0 <0.50 6/5/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 URS Corporation - North Carolina Page 22 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW07 12/17/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 MW08 12/16/1999 <1 <1 <5 <2 <5 <1 <1 <5 6/8/2000 1.1 <0.500 <0.500 1.12 0.98 <2.00 <0.500 <0.500 12/7/2000 1.05 0.614 <0.500 1.18 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.5 <1.0 <1.0 12/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/20/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 12/18/2002 21.1 6.3 25.3 33.3 <0.50 3 <0.50 6/5/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/17/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 12/1/2005 0.52 1.3 <1.0 6 <1.0 1.8 <1.0 <1.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 12/6/2006 <1 <1 <1 <3 <1 <2 <1 <1 6/12/2007 <0.5 <0.5 <0.5 <1 <0.5 <1 <0.5 <0.5 12/4/2007 <0.2 <0.2 <0.27 <0.56 <0.25 <0.44 <0.2 <0.2 6/3/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/3/2008 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/2/2009 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/8/2010 <0.1 <0.1 <0.1 <0.1 J <0.1 <0.1 <0.1 <0.1 12/8/2010 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/7/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/4/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/5/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/4/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 MW12 6/27/2005 840 67.7 36.4 251 <10 960 <10 11/30/2005 885 40.3 20.1 41.1 <20 746 <20 <20 12/6/2006 938 55 23.9 <60 <20 890 <20 <20 6/14/2007 1010 23.6 23.7 <20 <10 455 <10 <10 12/4/2007 833 25.2 24.4 24 J <5 578 <4 <4 6/4/2008 860 22 18 15 <1 400 <1 <1 12/3/2008 15 3.3 1.1 2.2 <0.1 55 <0.1 <0.1 6/4/2009 1.5 J 3.5 <0.5 3 <0.5 79 <0.5 <0.5 12/9/2009 19 2.1 0.36 J 2.5 <0.1 23 <0.1 <0.1 6/8/2010 40 3.3 0.51 2.9 <0.1 37 <0.1 <0.1 12/7/2010 11 1.9 0.32 J 3.4 <0.1 25 0.43 J <0.1 6/7/2011 84 6.7 1.4 9.1 <0.1 85 <0.1 <0.1 12/5/2011 70 5.5 1 6.2 <0.1 58 <0.1 <0.1 6/6/2012 11 2.5 0.17 J 1.4 <0.1 16 <0.1 <0.1 12/5/2012 3.3 0.67 0.22 J 1.1 <0.1 6.6 <0.1 <0.1 URS Corporation - North Carolina Page 23 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW12 6/5/2013 3.4 <0.29 <0.2 <0.5 <0.21 9.7 <0.22 <0.25 12/3/2013 2.6 0.28 J <0.27 <0.2 <0.2 <4.8 <0.34 <0.21 6/3/2014 4.4 0.61 J <0.21 <1.14 <0.28 5.6 <0.32 <0.2 12/2/2014 2.2 <0.27 <0.21 <0.63 <0.28 <3.6 <0.32 <0.2 6/3/2015 2.1 <0.27 <0.21 <0.39 <0.28 5 <0.32 <0.2 MW14R 6/26/1998 26 12/2/1998 <1 <1 <5 <2 <5 38 <1 <5 6/25/1999 <1 <1 <5 <2 <5 <1 <1 <5 12/16/1999 <1 <1 <5 <2 <5 17 <1 <5 6/8/2000 1.6 <0.500 0.57 3.76 1.6 <2.00 <0.500 <0.500 12/7/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/6/2001 <1.0 <1.0 <1.0 <3.0 2 <1.6 <1.0 <1.0 12/5/2001 <5.0 <5.0 <5.0 <10.0 <5.0 39 <5.0 6/20/2002 <5.0 <5.0 <5.0 <10.0 <5.0 <10 <5.0 12/18/2002 <0.50 <0.70 <0.50 <1.0 1.5 <1.0 <0.50 6/5/2003 5.4 <2.0 <2.0 <6.0 2.4 <2.0 <2.0 12/17/2003 7.9 <2.0 <2.0 <6.0 2.3 1.4 <2.0 6/8/2004 1.3 <2.0 <2.0 <6.0 2.8 <2.0 <2.0 12/7/2004 0.7 <2.0 <2.0 <6.0 2.4 1.9 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 2.4 3.5 <1.0 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J 3.2 J <1 J <0.5 J <0.5 J 12/4/2007 <0.2 <0.2 <0.27 <0.56 3.3 <2.2 <0.2 <0.2 6/3/2008 <0.1 <0.1 <0.1 <0.1 3.1 1.1 <0.1 0.22 J 12/3/2008 <0.1 <0.1 <0.1 <0.1 3.3 <0.1 <0.1 0.39 J 6/2/2009 <0.1 <0.1 <0.1 <0.1 3.1 0.76 <0.1 0.63 12/8/2009 <0.1 <0.1 <0.1 <0.1 4.1 0.99 <0.1 1 6/8/2010 <0.1 <0.1 <0.1 <0.1 3.5 0.87 <0.1 1.2 12/8/2010 <0.1 <0.1 <0.1 <0.1 4.4 0.58 <0.1 0.7 6/6/2011 <0.1 <0.1 <0.1 <0.1 3.5 <0,1 <0.1 0.72 12/7/2011 <0.1 <0.1 <0.1 <0.1 2.7 0.33 J <0.1 0.44 J 6/6/2012 <0.1 <0.1 <0.1 <0.1 1.7 0.42 J <0.1 0.28 J 12/4/2012 <0.1 <0.1 <0.1 <0.1 2.2 0.55 <0.1 0.28 J 6/5/2013 <0.21 <0.29 <0.2 <0.5 0.89 J <1 <0.22 <0.25 12/4/2013 <0.21 <0.2 <0.27 <0.2 1.1 <0.47 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 MW16 6/28/2005 5.6 5 17.9 26.3 <1.0 4.2 <1.0 MW18 12/14/1994 5 2 14 3 1200 BDL BDL BDL 6/8/1995 2320 382 BDL 810 225 210 41 BDL 9/20/1995 8500 1100 680 3800 3000 260 4 440 12/6/1995 BDL BDL BDL BDL BDL BDL 10/9/1996 480 110 140 700 1800 33 <250 34 MW19 3/23/2005 3980 744 37.4 396 901 216 41.1 12/1/2005 5790 900 <100 488 1090 182 <100 <100 3/7/2006 6020 705 <100 277 1770 212 <100 6/22/2006 3730 546 <100 321 1040 206 <100 <100 9/25/2006 830 350 <250 240 160 <250 <50 <50 12/6/2006 2880 704 28.6 498 927 288 63.4 33.1 6/14/2007 6770 J 776 J 30.8 J 479 J 1380 J 330 J <0.5 J 78.2 J 12/4/2007 5970 665 <27 352 1290 <213 <20 74.7 J 6/3/2008 730 270 8.4 J 270 230 180 <2 9 J URS Corporation - North Carolina Page 24 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW19 12/3/2008 1600 150 6.2 J 100 620 110 <2 29 6/3/2009 210 110 2.9 J 46 43 52 <1 2.2 J 12/8/2009 2000 180 7.1 J 120 300 100 <2 16 6/8/2010 1500 220 7 J 120 160 160 <2 11 12/8/2010 4300 500 17 390 580 290 <2 36 1/17/2011 5600 650 20 J 460 590 270 <5 36 6/7/2011 780 110 3.6 67 170 66 <0.5 11 12/7/2011 2300 290 9.7 160 260 150 <0.5 16 6/6/2012 270 30 1.2 J 23 18 19 <1 1.6 J 12/4/2012 2800 120 6.1 J 55 300 49 <5 20 J 6/5/2013 121 34.5 0.73 J 8.5 J 6.3 20.3 J <1.1 0.73 J 12/4/2013 210 41 1.3 J 12.84 33 19 <0.34 2 J 6/4/2014 150 16 0.53 J <4.42 20 5.3 <0.32 1.2 J 12/3/2014 1100 120 4.3 J 22 J 140 89 <1.6 8 J 6/3/2015 1760 288 6.4 69 87.2 164 <0.32 6.8 MW20 6/27/2005 1070 195 78.3 486 <50 128 <50 6/11/2013 260 57.5 13 40.6 <1.1 32.2 <1.1 <1.3 MW21 6/27/2005 11400 630 654 2110 227 224 <200 11/30/2005 9000 1060 345 3120 78 881 <100 <100 6/22/2006 7480 1130 578 2970 <200 609 <200 <200 12/6/2006 5490 943 324 2150 <500 519 <500 <500 6/14/2007 10800 J 1350 J 603 J 4240 J 98.8 639 J 5.1 22.5 12/4/2007 11600 1710 572 3910 54.2 J 666 <40 <40 6/4/2008 5000 1100 380 2800 35 J 830 <10 <10 12/3/2008 4400 1200 390 2500 30 J 840 <10 <10 6/4/2009 4300 1200 470 3000 34 780 <2.5 <2.5 12/9/2009 5500 1300 350 2800 65 J 790 <20 <20 6/9/2010 14000 1100 610 2800 140 520 <20 22 J 12/8/2010 9100 1500 390 3000 54 J 840 <20 <20 6/8/2011 11000 1400 810 3300 60 J 620 <20 <20 6/23/2011 14000 1700 1100 4500 46 J 510 <10 <10 7/21/2011 15000 1700 1200 4500 49 J 700 <10 <10 8/16/2011 15000 1600 1200 4300 47 J 690 <10 <10 11/22/2011 8500 1200 470 2400 43 J 590 <10 <10 2/16/2012 4300 800 360 1900 27 550 <5 <5 6/6/2012 3800 1100 330 1800 31 J 640 <10 <10 12/5/2012 10000 1400 440 1900 52 610 <10 <10 6/5/2013 5750 1670 626 3130 47.9 J 953 <22 <25 12/3/2013 6200 1400 700 2420 70 660 <6.8 9.4 J 6/3/2014 5500 1600 480 2420 47 910 <3.2 5.2 J 12/2/2014 11000 1400 430 2095 190 540 <16 23 J 6/3/2015 17600 1400 J 444 2300 345 523 <16 35.6 J MW26 6/27/2005 22 22.7 8.2 55.7 <1.0 6.7 <1.0 11/30/2005 2.7 3 <1.0 <3.0 <1.0 <2.0 <1.0 <1.0 6/22/2006 263 10.5 12.9 14 2.1 2.2 11.7 2.8 12/6/2006 217 130 6.7 <15 <5 15.3 <5 <5 6/14/2007 174 13.6 6.2 9.8 J 0.52 J 6.4 <0.5 <0.5 12/4/2007 38.2 1.1 0.49 J 0.58 J <0.25 <0.93 <0.2 <0.2 6/3/2008 4.5 <0.5 <0.5 <0.5 <0.5 3.2 <0.5 <0.5 12/3/2008 190 8.5 3.5 1.7 1.2 15 J <0.1 0.34 J 6/4/2009 410 9.6J 13J 18J 1.3J 21 <0.5 0.74J 12/9/2009 91 36 2.7 5.1 <0.5 120 <0.5 <0.5 URS Corporation - North Carolina Page 25 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW26 6/9/2010 980 56 44 100 2.1 J 54 <0.5 2.6 12/8/2010 220 2.7 5 4.6 0.66 J 41 J <0.5 <0.5 6/8/2011 230 58 4.8 3.9 0.65 J 15 <0.5 <0.5 6/23/2011 290 15 8.1 7.8 <1 25 <1 <1 7/21/2011 300 24 9.3 13 <1 50 <1 <1 8/16/2011 290 24 8.4 10 <1 48 <1 <1 11/22/2011 110 4.7 4.1 13 0.22 J 28 <0.1 <0.1 2/16/2012 200 5.8 7.6 19 0.57 J 49 <0.5 <0.5 6/6/2012 160 7.2 5.7 13 <0.5 43 <0.5 <0.5 12/5/2012 360 55 11 40 <0.5 110 <0.5 <0.5 6/5/2013 48.1 25.6 1.6 5.7 <0.21 26.8 <0.22 <0.25 12/3/2013 230 46 10 36.2 <1 150 <1.7 <1 6/3/2014 230 J 85 J 7.1 24 <0.28 110 <0.32 <0.2 12/2/2014 220 220 J 6 9.8 J <0.28 110 <0.32 <0.2 6/3/2015 139 178 2.1 8.3 0.38 J 80.9 <0.32 <0.2 MW27 6/27/2005 884 91.9 30.3 507 <50 295 <50 6/11/2013 1480 J 142 18.7 J 72.6 <4.2 873 J <4.4 <5.1 MW36 3/23/2005 11300 1140 133 1330 484 284 <250 12/6/2005 9180 932 123 1420 550 376 <1.0 29.8 3/7/2006 3160 255 23 444 780 81.9 <10 9/25/2006 3600 1000 <250 1400 300 390 <50 <50 12/6/2006 45.3 36.1 <5 39.7 118 30.5 <5 3.1 6/12/2007 5580 614 68.4 J 984 553 201 <50 <50 12/4/2007 5170 919 131 1280 162 <222 <20 <20 6/3/2008 6700 1100 150 1600 140 370 <10 <10 12/4/2008 3100 700 71 900 110 280 <10 <10 6/3/2009 2200 300 29 430 260 150 <2 12 12/8/2009 3100 850 69 790 71 340 <2 3.7 J 6/8/2010 4400 480 33 300 330 240 <2 21 12/8/2010 4700 970 62 550 340 440 <2 18 1/17/2011 4800 910 49 400 220 380 <5 12 J 6/7/2011 1600 280 20 J 150 120 110 <5 6.2 J 12/7/2011 2900 1100 67 610 94 470 <5 <5 6/6/2012 1100 270 15 160 110 120 <1 4.9 J 12/4/2012 1000 310 21 210 190 91 <1 9.8 6/5/2013 755 236 11.9 109 69 94.6 <0.22 2.8 12/4/2013 1400 590 39 436 140 260 <1.7 7.7 J 6/4/2014 1500 290 11 J 77 130 140 <1.6 7.7 J 12/3/2014 430 180 10 66 92 78 <0.32 5.3 6/3/2015 796 198 8.9 52.1 104 106 <0.32 7.2 MW37 3/23/2005 1000 58.1 <20 42.3 89.2 41.4 <20 12/9/2009 4.3 J 2.3 J <0.7 1.5 J <0.5 <1 6/11/2013 5.6 0.89 J 0.21 J <0.5 <0.21 12 <0.22 <0.25 MW38 6/5/2003 6260 1780 15800 10700 754 550 <400 3/23/2005 3910 1610 13800 10700 358 479 <200 12/1/2005 704 459 3400 4300 40.3 175 <50 <50 3/7/2006 201 444 757 2930 25.4 236 <20 6/22/2006 110 194 411 1330 15.8 180 <10 <10 9/25/2006 34 94 74 340 <1.0 65 <1.0 <1.0 12/6/2006 71.6 108 346 710 <5 79.4 <5 <5 6/12/2007 433 264 847 1570 41.3 138 9.4 3.1 12/4/2007 63.7 112 138 822 10.8 71.5 2 J <1 URS Corporation - North Carolina Page 26 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW38 6/3/2008 1 J 52 11 360 <1 43 <1 <1 12/4/2008 <0.5 2.4 J 0.73 J 10 <0.5 2.1 J <0.5 <0.5 6/3/2009 0.22 J 4.7 1.6 36 <0.2 6 <0.2 <0.2 12/8/2009 <0.1 0.84 0.23 J 6.8 <0.1 1.3 <0.1 <0.1 6/8/2010 <0.1 0.42 J 0.15 J 1.7 <0.1 0.45 J <0.1 <0.1 12/8/2010 3.1 1.6 1.1 23 0.94 1.2 0.49 J 0.15 J 1/17/2011 86 410 J 85 J 1600 14 290 J <2 <2 6/7/2011 <0.1 0.19 J <0.1 0.72 <0.1 0.25 J <0.1 <0.1 12/7/2011 <0.25 2.1 <0.25 8 <0.25 3.3 <0.25 <0.25 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/4/2012 0.25 J <0.1 <0.1 <0.1 0.11 J <0.1 <0.1 <0.1 6/5/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/4/2013 <0.21 0.21 J <0.27 <0.2 <0.2 <1.5 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.62 <0.32 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 <0.2 6/3/2015 0.75 J 0.61 J <0.21 <0.39 <0.28 1.9 <0.32 <0.2 MW39 9/13/1994 11000 1800 5200 12000 5400 520 BDL 3/13/1995 9100 470 5000 5400 8400 490 BDL BDL 12/6/1995 14000 590 9800 8100 420 820 5/23/1997 18000 970 16000 9200 6000 420 <1,000 460 6/5/1997 1700 1000 15000 8000 6500 480 500 <1,000 6/25/1998 1200 170 1200 1900 1300 100 100 130 12/3/1998 7300 350 3300 3300 3200 110 180 <500 6/23/1999 10000 470 5900 3800 2500 150 130 <500 12/16/1999 10000 420 6500 3600 1400 200 <100 <500 6/8/2000 10600 526 8040 3880 1900 207 160 265 12/7/2000 5120 101 2150 1130 872 79.4 48.7 <10.0 6/6/2001 5300 <500 3700 2400 960 150 <500 <500 12/6/2001 16 <1.0 6.6 5.3 <1.0 <2.0 <1.0 <1.0 6/19/2002 9100 710 5300 4500 1500 <200 <100 <100 12/18/2002 11600 1180 8310 6640 919 348 <50 <50 6/5/2003 9460 803 6670 4930 794 292 <400 <400 12/17/2003 7430 701 3190 3950 720 287 <200 <200 6/8/2004 4890 507 2720 3200 441 203 48.2 17.9 12/8/2004 7610 806 4070 4500 500 384 <200 <200 6/28/2005 6860 610 2890 3700 331 165 <50 12/1/2005 3870 417 1760 2550 79.9 <200 <100 <100 3/7/2006 4670 483 2590 2990 151 151 <50 6/23/2006 2160 221 1010 1230 64.2 83.8 <50 <50 9/25/2006 85 58 73 250 <1.0 39 <1.0 <1.0 12/6/2006 663 112 237 576 19.6 96.2 <10 <10 6/14/2007 582 94.6 197 413 22.1 144 <5 <5 12/4/2007 473 43.5 98.1 184 32.7 <11 6.3 J 3 J 6/3/2008 340 31 34 100 4 13 <0.5 <0.5 12/4/2008 150 16 23 64 4.4 5.1 <0.5 0.59 J 6/3/2009 340 190 280 850 6.4 73 <1 <0.8 12/9/2009 29 11 11 50 1.9 5.3 1.4 0.22 J 6/8/2010 120 81 110 280 2.2 44 <0.1 0.29 J 12/8/2010 770 97 94 400 67 52 <0.1 4.6 1/17/2011 1600 160 190 540 78 61 <1 5.4 6/7/2011 91 15 10 38 3.5 5.9 <0.1 0.22 J 12/7/2011 430 25 21 62 3.7 11 0.91 0.73 URS Corporation - North Carolina Page 27 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW39 6/6/2012 29 5.3 2.7 19 <0.1 3.1 <0.1 <0.1 12/4/2012 290 22 21 63 3.1 6.2 1.2 0.67 6/5/2013 68.5 3.7 1.7 3.7 <0.21 <1 <0.22 <0.25 12/4/2013 70 6.9 3.8 J 15.5 2.8 <1.8 0.47 J <0.21 6/4/2014 <0.21 40 32 109 1.4 11 <0.32 <0.2 12/3/2014 94 11 6.2 25 0.89 J <2.5 <0.34 <0.2 6/3/2015 91.8 18.8 5.7 49.6 2.8 5.2 <0.32 <0.2 MW41 9/13/1994 BDL BDL 41000 BDL BDL 390 BDL 3/13/1995 670 150 220 1000 BDL 240 BDL BDL 5/23/1997 850 210 330 1100 <50 170 <25 <50 6/25/1998 810 210 330 1200 140 12/3/1998 720 250 350 1200 <50 260 <10 <50 6/24/1999 510 170 230 970 <50 130 <10 <50 12/15/1999 550 290 410 1500 <50 <10 <50 6/8/2000 383 189 256 994 <0.500 123 <0.500 39.8 12/7/2000 314 246 347 1240 <0.500 185 <0.500 <0.500 6/6/2001 <200 <200 210 1160 <200 190 <200 <200 12/6/2001 <500 <500 <500 1500 <500 190 <500 <500 6/19/2002 140 190 170 1100 <10 330 <10 <10 12/18/2002 140 177 126 1000 <5.0 318 <5.0 6/5/2003 197 173 209 1100 <20 283 <20 12/17/2003 141 128 75.8 910 <10 261 <10 6/8/2004 71.8 75.3 52.3 548 <10 153 <10 12/8/2004 99.1 131 68.4 767 <20 210 <20 6/28/2005 31 30.1 18.3 212 <5.0 53.4 <5.0 12/1/2005 18.6 22.7 8 190 <2.0 42.8 <2.0 <2.0 3/7/2006 16.1 21.4 10.3 142 <1.0 37.9 <1.0 6/22/2006 21.4 26.2 10.5 111 <1.0 49.5 <1.0 <1.0 9/25/2006 4.8 6 <5.0 60 <1.0 21 <1.0 <1.0 12/5/2006 6.1 6.9 2.6 64.6 <1 23.1 <1 <1 6/13/2007 33.1 22.6 11.7 192 1.4 62.3 <0.5 <0.5 12/4/2007 55.2 99.9 39.3 580 4.7 J 160 <1 <1 6/3/2008 17 24 16 360 2.5 100 <0.5 <0.5 12/4/2008 18 90 26 560 1.1 J 180 <0.5 <0.5 6/3/2009 11 68 38 590 1.3 J 230 <1 <0.8 12/8/2009 1.9 12 3.8 96 0.28 J 38 <0.1 <0.1 6/8/2010 3 16 5.3 110 0.12 J 54 <0.1 <0.1 12/8/2010 17 53 26 400 0.24 J 150 <0.1 <0.1 1/17/2011 27 94 76 790 <1 220 <1 <1 6/7/2011 1.1 8.4 2.8 88 0.11 J 35 <0.1 0.15 J 12/7/2011 24 48 21 520 0.19 J 200 0.29 J 0.68 6/6/2012 3.2 3.9 1.6 44 <0.1 20 <0.1 0.11 J 12/4/2012 14 10 4.7 170 0.19 J 36 0.22 J 0.66 6/5/2013 3.7 3.2 1.1 36.3 <0.21 15.9 <0.22 <0.25 12/4/2013 1.9 2.2 J 0.98 J 45.9 <0.2 20 <0.34 <0.21 6/4/2014 4.1 5.1 1.9 J 93 <0.28 40 <0.32 <0.2 12/3/2014 14 6.7 J 2.8 J 151 <0.28 72 J <0.32 <0.2 6/3/2015 5.2 1.8 <0.21 73.7 <0.28 18.6 <0.32 <0.2 MW42 3/23/2005 3860 302 76.9 2100 173 419 <50 12/9/2009 1700 380 100 610 350 900 6/11/2013 2340 459 J 82.2 J 952 J 38.1 J 836 J <5.6 <6.3 MW43 6/27/2005 5730 642 194 617 4260 208 70.3 URS Corporation - North Carolina Page 28 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW43 6/11/2013 4840 1050 122 659 1140 525 <22 <25 MW44 6/5/2003 4730 703 49.5 1310 4500 320 81.8 3/23/2005 5710 584 <100 429 2900 437 52.1 12/1/2005 4170 454 <100 132 2820 280 <100 <100 6/22/2006 4290 490 <100 153 2480 415 <100 <100 12/6/2006 3520 514 <50 157 2360 380 <50 40.3 6/14/2007 3620 J 388 15 139 1940 J 379 <5 37.7 12/4/2007 4410 615 <27 122 J 2330 372 <20 52.3 J 6/3/2008 3600 420 16 J 73 2000 350 <5 33 12/4/2008 4000 510 17 J 86 1900 400 <5 36 J 6/4/2009 4800 700 19 J 190 2300 500 <5 39 12/8/2009 3300 510 14 J 120 2100 370 <5 32 6/8/2010 3800 510 9.4 J 130 2200 340 <5 42 12/8/2010 2800 400 11 J 54 2500 350 <5 36 6/7/2011 3800 420 15 J 44 2700 360 <5 40 12/7/2011 3500 500 15 J 40 2500 430 <5 34 6/6/2012 2900 420 14 J 32 2100 350 <5 30 12/4/2012 3200 430 12 J 34 2700 350 <5 35 6/5/2013 2500 428 14.3 J 34.1 1900 J 437 <5.6 28.5 J 12/4/2013 2700 520 16 J 50 J 2400 420 <3.4 42 J 6/4/2014 2100 410 13 J 30 1700 370 J 9.7 J 28 J 12/3/2014 3300 470 J 15 J 31.4 J 2500 390 <3.2 41 J 6/3/2015 2170 415 11.8 33.2 1980 307 3.1 45.6 MW45 3/23/2005 110 986 70.5 2200 <20 556 <20 12/9/2009 34 1000 19 730 100 540 6/11/2013 96.8 J 7260 J 28.1 J 1510 J <4.2 5850 J <4.4 <5.1 MW47 6/27/2005 52.4 44.8 7.3 96 26.7 25.5 0.78 6/11/2013 11.6 93.8 2.7 115 <0.21 48.4 <0.22 <0.25 MW48 6/27/2005 33.9 11.7 2.5 63.1 61 12.9 0.76 MW49 6/5/2003 32.5 5.7 1.8 5.9 9 1.9 <2.0 3/23/2005 187 27.6 3.8 30.7 67.9 31.4 <5.0 12/1/2005 162 <5.0 2.6 <15 61.7 18.2 <5.0 <5.0 6/22/2006 149 3.3 3.6 12.3 56.3 29.5 <5.0 <5.0 9/25/2006 230 <100 <100 <300 <100 <500 <100 <100 12/6/2006 215 13.9 5.3 20.7 51 45.1 <5 <5 6/14/2007 206 J 5.3 J 5.7 J 14.7 J 50.6 J 34.4 J <2.5 J <2.5 J 12/4/2007 320 26.4 10.4 23.8 71.9 54.7 <1 <1 6/3/2008 140 20 9.7 31 31 32 <0.5 0.9 J 12/4/2008 130 55 17 130 27 57 <0.5 0.86 J 6/3/2009 150 7.7 8.3 17 18 36 <1 <0.8 12/8/2009 110 22 9.6 67 20 48 3.8 0.6 J 6/8/2010 73 12 8 30 17 39 <0.2 0.57 J 12/8/2010 490 31 69 76 47 60 <0.5 3.1 1/17/2011 690 68 580 590 100 69 <2 7.7 J 6/7/2011 840 15 15 36 160 15 <2 11 12/7/2011 360 20 9.7 47 96 21 12 5.6 6/6/2012 330 4.5 6.1 14 96 16 <0.5 5.3 12/4/2012 390 5.6 10 9.6 73 31 <0.5 4.7 6/5/2013 95.9 8.1 4.7 20.7 29 19.2 0.32 J <0.25 12/4/2013 92 19 8.8 16.6 53 23 <0.34 2.4 J 6/4/2014 69 2.9 J 4.1 J 11 14 11 <0.32 0.8 J 12/3/2014 85 1.4 J 5.9 24.3 26 23 <0.32 1.3 J URS Corporation - North Carolina Page 29 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW49 6/3/2015 69.8 <0.27 5.6 20.7 14.3 18 0.36 J 0.62 J MW50 3/23/2005 <10 402 6.7 586 <10 337 <10 12/1/2005 3.3 132 3.2 172 <5.0 216 <5.0 <5.0 6/23/2006 <5.0 116 4.8 193 <5.0 209 <5.0 <5.0 12/6/2006 <2 127 2 181 <2 185 <2 <2 6/14/2007 1 J 73.7 J 1.1 J 108 J <0.5 J 116 <0.5 J <0.5 J 12/4/2007 2.6 83.5 1.9 J 100 <0.5 178 <0.4 <0.4 6/3/2008 0.66 140 1 180 <0.1 180 <0.1 <0.1 12/4/2008 2.4 34 1.3 42 <0.1 130 <0.1 <0.1 6/3/2009 <0.5 300 0.83 J 520 <0.5 370 <1 <0.8 12/9/2009 <0.5 63 <0.5 94 <0.5 89 <0.5 <0.5 6/8/2010 <0.5 83 <0.5 86 <0.5 140 <0.5 <0.5 12/8/2010 0.81 J 110 0.7 J 150 <0.5 230 <0.5 <0.5 6/7/2011 <0.5 82 <0.5 92 <0.5 150 <0.5 <0.5 12/7/2011 0.97 J 77 <0.5 94 <0.5 150 <0.5 <0.5 6/6/2012 <0.5 37 <0.5 40 <0.5 82 <0.5 <0.5 12/4/2012 1.1 J 23 0.55 J 22 <0.5 83 <0.5 <0.5 6/6/2013 1.1 J 82.7 <0.4 86 <0.42 169 <0.44 <0.51 12/4/2013 1.3 62 <0.27 61.61 <0.2 120 <0.34 <0.21 6/4/2014 0.25 J 150 0.25 J 180.59 <0.28 250 <0.32 <0.2 12/3/2014 <0.21 96 <0.21 120 <0.28 190 <0.32 <0.2 6/3/2015 0.93 J 8.4 <0.21 6.4 <0.28 23.7 <0.32 <0.2 MW51 9/13/1994 10000 970 3000 4300 11000 350 BDL 3/13/1995 9800 660 1900 3500 12000 300 BDL BDL 10/9/1996 7500 450 540 2000 13000 290 <500 250 5/27/1997 6300 <250 540 2400 14000 320 <10 6/25/1998 8900 770 580 3100 8800 290 530 12/4/1998 9600 1100 950 4000 8600 280 <100 <500 6/24/1999 9000 970 690 3600 9100 290 <100 <500 6/8/2000 9170 853 515 3300 5170 160 <20.0 700 12/7/2000 3280 163 167 662 2280 447 <10.0 <10.0 6/6/2001 6900 <2,000 <2,000 <4,000 4800 350 <2,000 <2,000 12/6/2001 6500 660 230 2230 2600 730 <100 170 6/20/2002 7200 540 230 1740 3100 260 <200 <200 12/18/2002 8490 643 286 2020 1810 474 63.4 6/5/2003 8680 790 359 2330 1990 585 90.4 12/17/2003 7670 611 256 2000 1860 552 66.6 6/8/2004 6830 392 135 997 1920 358 60 12/8/2004 6870 477 167 1250 2150 507 99.5 6/28/2005 7400 415 195 1180 2240 376 82 12/1/2005 7000 443 174 1280 2530 714 <100 <100 6/23/2006 7380 339 142 919 2310 378 <100 91.5 12/6/2006 6820 422 168 1180 1670 542 <100 78.4 6/12/2007 5540 423 128 1190 1600 459 <50 78.9 J 12/4/2007 5280 464 123 1270 1790 643 <20 95.4 J 6/3/2008 3800 320 76 770 960 440 <5 63 12/4/2008 6200 380 99 860 1000 530 <5 72 6/3/2009 4400 570 90 J 1400 820 1400 <20 59 J 12/9/2009 6100 380 86 720 1100 460 <5 68 6/8/2010 5300 250 71 480 900 340 <5 70 12/8/2010 5200 310 75 640 960 490 <5 74 6/7/2011 4400 250 56 470 760 430 <5 67 URS Corporation - North Carolina Page 30 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW51 12/7/2011 6100 380 77 560 860 510 <5 71 6/6/2012 5600 340 J 64 450 840 J 390 J <5 65 12/4/2012 4500 340 56 430 610 420 <5 56 6/5/2013 3330 229 44.4 J 289 498 405 <11 39 J 12/3/2013 4100 690 83 J 764 590 1400 <6.8 56 J 6/4/2014 3000 200 37 247 540 510 <1.6 38 12/3/2014 3800 310 48 J 364 570 360 <6.5 <4 6/3/2015 3280 191 33 331 597 443 15.3 69.9 MW52 3/8/2006 <1.0 <1.0 <1.0 <3.0 92.1 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 59.9 <1 <0.22 <0.25 12/4/2013 <0.21 <0.2 <0.27 <0.2 10 <0.47 <0.34 <0.21 6/4/2014 <0.21 <0.27 <0.21 <0.63 61 <0.34 1.4 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 56 <2.5 <0.32 <0.2 6/3/2015 0.35 J <0.27 <0.21 <0.39 65.6 <0.34 <0.32 0.36 J MW53 3/8/2006 <1.0 <1.0 <1.0 <3.0 20.8 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 22.4 <1 <0.22 16.3 6/4/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 1.1 <0.2 12/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.93 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 MW55 3/8/2006 <1.0 <1.0 <1.0 <3.0 147 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 50.1 <1 <0.22 <0.25 6/4/2014 <0.21 <0.27 <0.21 <0.63 43 <0.34 0.84 J <0.2 12/3/2014 0.89 J <0.27 <0.21 <0.63 18 <0.34 <0.32 0.39 J MW56 3/8/2006 <1.0 <1.0 <1.0 <3.0 77.6 <2.0 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 9.8 <1 <0.22 0.35 J MW57 3/8/2006 1.5 2 <1.0 5.4 31.5 1.5 3.4 6/11/2013 <0.21 <0.29 <0.2 <0.5 37.4 <1 <0.22 0.82 J 12/4/2013 1.6 0.75 J <0.27 1.6 J 23 <8.5 <0.34 1 J 6/3/2014 0.3 J <0.27 <0.21 <0.79 36 <0.81 0.37 J 0.71 J 12/3/2014 1.4 0.95 J <0.21 2.6 J 23 <4.9 <0.95 1.3 J 6/4/2015 <0.21 <0.27 <0.21 <0.39 43.4 <0.34 <0.32 0.79 J MW58 3/8/2006 1200 215 18.3 182 27 107 10.5 6/14/2007 977 201 13.7 129 <5 95.8 6.5 J 87.9 12/4/2007 431 105 6.3 J 48.4 52 47.1 4.8 J 80.7 6/4/2008 720 170 9.8 J 91 45 74 <2 66 12/4/2008 360 88 4.1 49 60 52 <0.5 70 6/2/2009 640 130 8.4 J 79 46 54 <2 70 12/8/2009 220 47 1.9 J 8.8 54 17 8.6 57 6/7/2010 350 56 2.7 12 38 11 <0.5 53 12/7/2010 140 10 1.7 J 8.8 59 27 <0.5 76 6/6/2011 15 2.2 0.21 J 2.2 1.3 1.5 <0.1 1.4 12/5/2011 0.64 0.11 J <0.1 0.12 J 0.39 J 0.25 J <0.1 0.26 J 6/6/2012 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/3/2012 2.8 0.16 J <0.1 0.27 J 4.1 0.22 J <0.1 2.7 6/4/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/2/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.632 <0.28 <0.6 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.53 <0.32 <0.2 6/2/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 MW59 3/8/2006 1.2 12.1 <2.0 36.6 89.6 11.8 14.9 6/14/2007 <0.5 J <0.5 J <0.5 J <1 J 155 <1 J 26.4 J 5.6 J 12/5/2007 0.98 J 1.6 <0.27 <0.56 81.4 5.9 17.5 4.8 URS Corporation - North Carolina Page 31 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW59 6/4/2008 0.38 J 0.46 J <0.1 <0.1 12 10 4 1.5 12/4/2008 <0.1 <0.1 <0.1 <0.1 1.2 0.34 J 0.86 0.18 J 6/2/2009 <0.1 <0.1 <0.1 <0.1 0.23 J 5.7 0.25 J <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 <0.1 0.47 J <0.1 <0.1 6/7/2010 <0.1 <0.1 <0.1 <0.1 <0.1 0.41 J <0.1 <0.1 12/7/2010 <0.1 <0.1 <0.1 <0.1 0.12 J 0.73 0.19 J <0.1 6/6/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 6/6/2012 <0.1 <0.1 <0.1 <0.1 1.2 <0.1 0.44 J <0.1 12/3/2012 <0.1 <0.1 <0.1 <0.1 <0.1 0.27 J <0.1 <0.1 6/4/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 12/2/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.42 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 <0.28 <0.34 <0.32 J <0.2 6/2/2015 <0.21 <0.27 <0.21 <0.39 0.6 J <0.34 <0.32 <0.2 MW65 8/30/2010 17000 2200 1100 6300 43 J 630 <10 <10 12/8/2010 21000 2400 1600 6600 90 J 670 <20 <20 6/8/2011 13000 1400 1500 4900 35 J 400 <10 <10 6/23/2011 15000 2000 1900 6200 35 J 480 <20 <20 7/21/2011 16000 2100 1700 6000 33 J 670 <20 <20 8/16/2011 15000 2000 1700 6300 26 J 650 <20 <20 11/22/2011 14000 2200 2400 6100 27 J 630 <20 <20 2/16/2012 13000 2000 1500 5300 21 J 640 <10 <10 6/6/2012 14000 2000 1600 5400 20 J 630 <10 <10 12/5/2012 15000 2500 J 2300 6100 20 J 690 <10 <10 6/5/2013 12100 J 2140 1170 5140 7.7 J 790 <5.6 <6.3 12/3/2013 9300 2100 J 1300 J 4970 J 18 J 880 <6.8 <4.2 6/3/2014 11000 2000 1200 4970 21 J 640 <16 <10 12/2/2014 7600 J 97 J 920 J 4720 J 20 J 670 J <6.5 <4 J 6/3/2015 8810 1700 1410 4970 18 J 563 23.2 J 5.5 J MW66 8/30/2010 180 22 8.9 41 24 78 <0.1 3.5 12/7/2010 380 46 6.2 38 540 86 <1 14 6/7/2011 190 91 7.9 48 110 81 <1 4.9 J 12/6/2011 84 58 6 30 28 47 <0.2 2.6 6/6/2012 47 37 2.5 18 36 11 <0.2 3.5 12/3/2012 37 15 2.9 18 13 20 <0.2 2.4 6/4/2013 57.5 51.3 8.8 31.7 17.5 41.4 <0.22 1.5 12/3/2013 37 28 5 J 19.1 12 34 <0.34 <0.21 6/3/2014 16 25 3.2 J 17.7 7.7 77 <0.32 0.82 J 12/2/2014 16 16 <0.21 13.3 <0.28 35 <0.32 0.84 J 6/2/2015 7.1 20.6 1.5 9.2 5.3 26.5 <0.32 0.98 J MW67 8/30/2010 570 660 26 66 220 850 <1 16 12/7/2010 520 860 26 140 220 1000 <1 19 6/7/2011 340 660 20 98 130 800 <1 7.5 12/6/2011 410 610 19 38 180 810 <1 9 6/6/2012 380 680 17 30 67 760 <1 <1 12/3/2012 330 550 15 18 47 720 <1 <1 6/4/2013 221 622 15.7 24.8 J 33.5 780 <2.2 2.7 J 12/3/2013 190 450 14 J 17.8 J 30 580 <1.7 <1 6/3/2014 140 540 14 J <3.2 21 820 <1.6 1.4 J 12/2/2014 140 510 13 674.5 23 760 <0.32 J 2 J 6/2/2015 101 617 11.9 19.3 10.1 794 <0.32 1.3 URS Corporation - North Carolina Page 32 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE MW68 8/30/2010 18 6.7 2.4 58 43 0.96 12 4.2 12/8/2010 390 91 27 270 220 71 26 6.8 6/8/2011 160 73 33 510 240 57 <1 6.7 6/23/2011 90 30 14 150 130 17 17 6.1 7/21/2011 99 45 15 110 130 25 15 6 8/16/2011 100 7.5 11 120 180 9.1 14 6.5 11/22/2011 57 8.4 2.4 21 190 3.1 19 8.6 2/16/2012 46 8.1 1.8 J 18 250 2.9 20 7.7 6/6/2012 73 29 1.2 19 300 13 15 8.1 12/4/2012 54 5.4 0.37 J 3.5 340 3.2 15 9.6 6/4/2013 67.8 17.4 1.5 J 16.4 325 7.6 J 18.3 8.6 12/3/2013 31 8.1 0.58 5.15 180 9.4 15 10 6/3/2014 130 41 3.4 J 23.1 230 8.3 15 9.9 12/2/2014 70 31 2.7 J 26.8 140 8.7 11 9.6 6/2/2015 89.2 39.6 4.1 32.3 168 10.1 8.4 9.3 MW69 5/24/2011 0.12 J <0.1 <0.1 0.17 J 95 5.6 0.46 J 6.5 6/8/2011 <0.1 <0.1 <0.1 <0.1 41 0.4 J 0.23 J 2.8 6/23/2011 <0.1 <0.1 <0.1 <0.1 70 0.19 J 0.32 J 5.1 7/21/2011 <0.1 <0.1 <0.1 <0.1 68 0.36 J 0.28 J 5.2 8/16/2011 <0.1 <0.1 <0.1 0.12 J 41 2.1 0.26 J 3 11/22/2011 <0.1 <0.1 <0.1 0.26 J 34 3.2 0.29 J 2.9 2/16/2012 <0.1 0.12 J <0.1 0.4 J 30 2.8 0.28 J 2.6 6/6/2012 <0.1 0.2 J <0.1 0.58 23 10 0.25 J 1.6 12/3/2012 <0.1 <0.1 <0.1 0.13 J 43 0.19 J 0.38 J 5.7 6/4/2013 <0.21 <0.29 <0.2 <0.5 31.7 1.4 J 0.45 J 4.3 12/3/2013 <0.21 <0.2 <0.27 0.86 J 44 <6.4 <0.34 6.6 6/3/2014 <0.21 <0.27 <0.21 <0.63 32 <1.2 0.44 J 3.8 J 12/2/2014 <0.21 <0.27 <0.21 <0.63 28 <1.1 <0.32 4.1 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 38.9 0.52 J <0.32 6.5 PMW01 12/15/1994 BDL BDL BDL BDL 16 39 6/8/1995 BDL BDL BDL BDL 15 BDL 41 34 12/6/1995 BDL BDL BDL BDL BDL 31 6/6/1997 <1 <1 <1 <1 15 <2 17 20 12/16/1999 <1 <1 <5 <2 39 19 26 6/7/2000 <0.500 <0.500 <0.500 <0.500 61.4 16.4 21.4 12/6/2000 <0.500 <0.500 <0.500 <0.500 65.8 16.1 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 55 15 18 12/5/2001 <5.0 <5.0 <5.0 <10 110 <10 9.4 21 6/19/2002 <5.0 <5.0 <5.0 <10.0 100 <10 6.9 18 12/17/2002 <0.50 <0.70 <0.50 <1.0 73.5 <1.0 6.8 16.1 6/3/2003 <1.0 <2.0 <2.0 <6.0 95.8 <2.0 10.9 20.7 12/16/2003 <1.0 <2.0 <2.0 <6.0 119 <2.0 8.6 21.2 6/7/2004 <2.0 <4.0 <4.0 <12 105 <4.0 6.6 17.8 9/21/2004 <1.0 <2.0 <2.0 <6.0 162 <5.0 6.6 19.5 12/6/2004 <2.0 <4.0 <4.0 <12 113 <4.0 6.1 16.9 6/9/2005 <1.0 <1.0 <1.0 <3.0 90.8 <2.0 3.7 10.9 6/12/2013 <0.21 <0.29 <0.2 <0.5 26.8 <1 1.5 6.5 12/4/2013 <0.21 <0.2 <0.27 <0.2 31 <0.47 1.8 7.8 6/4/2014 <0.21 <0.27 <0.21 <0.63 30 <0.85 2.4 8 12/3/2014 <0.21 <0.27 <0.21 <0.63 20 <0.55 1.5 6.5 PMWO2 12/15/1994 4400 970 3100 4400 BDL BDL 6/8/1995 6570 1660 4280 7700 BDL BDL 41 216 URS Corporation - 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A 0) • Cn .Aa N N A N L L Cn O O O O O J 0p O N W CO A CO A A W N W CON Ul CA j 01 A J N o O Ln Cn L O CA W CO O O J J CO A CA O A W O O O V W O O O O Cn O 0 A A O O 0 0 CD CO CD CND CD (D m Q CD N N CD CD 0 CD CD CD G co co co —1 W m z CD (D IV 0 m Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE PMW03 6/14/2005 <1.0 <1.0 <1.0 <3.0 180 <2.0 17.8 90.4 6/12/2013 3.3 <0.29 <0.2 <0.5 269 <1 7 87 PMWO4 3/11/1999 <5 <5 <5 <5 320 <5 <5 12/14/1999 <1 <1 <5 <2 370 <1 1.3 <2 6/6/2000 <0.500 <0.500 <0.500 <0.500 280 <2.00 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 327 <2.00 1.01 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 400 <1.8 <10 1.1 12/5/2001 <10 <10 <10 <20 450 <20 <10 <10 6/19/2002 <1.0 <1.0 <1.0 <2.0 200 2.2 <1.0 <1.0 12/17/2002 <2.5 <3.5 <2.5 <5.0 375 <5.0 <2.5 6/3/2003 <5.0 <10 <10 <30 238 <10 <10 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.6 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 353 <2.0 0.7 12/6/2004 <10 <20 <20 <60 346 <20 <20 6/9/2005 <1.0 <1.0 <1.0 <3.0 323 2.4 0.76 6/11/2013 <0.42 <0.58 <0.4 <0.99 91.8 6.3 J <0.44 0.68 J 12/2/2013 <0.21 <0.2 <0.27 <0.2 66 <0.47 0.64 J 1 J 6/3/2014 <0.21 <0.27 <0.21 <0.63 55 <0.37 0.49 J 0.75 J 12/2/2014 <0.21 <0.27 <0.21 <0.63 39 <0.34 <0.5 0.89 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 36.2 <0.34 <0.32 0.8 J PMW05 6/7/1995 BDL BDL BDL BDL 132 BDL 4 BDL 12/6/1995 BDL BDL BDL BDL 125 BDL 4 BDL 3/11/1999 <5 <5 <5 <5 180 <5 <5 6/11/2013 <0.21 <0.29 <0.2 <0.5 60.9 <1 0.33 J 0.62 J 12/2/2013 <0.21 <0.2 <0.27 <0.2 75 <0.82 <0.34 0.95 J 6/3/2014 <0.21 <0.27 <0.21 <0.63 76 <0.36 0.49 J 0.61 J 12/2/2014 <0.21 <0.27 <0.21 <0.63 69 <0.34 <0.32 0.8 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 46 <0.34 <0.32 0.57 J PMW06 12/15/1994 BDL BDL BDL BDL 820 BDL 6/8/1995 BDL 1 BDL BDL 300 6 BDL BDL 12/6/1995 BDL BDL BDL BDL BDL 6/6/1997 <1 <1 <1 <1 116 2 <1 3 3/22/2004 <10 3/8/2006 <1.0 <1.0 <1.0 <3.0 1.5 <2.0 <1.0 6/12/2013 <0.21 <0.29 <0.2 <0.5 2.8 <1 <0.22 5 PMW07 12/15/1994 BDL BDL BDL BDL 14 BDL 6/7/1995 BDL BDL BDL BDL 90 BDL BDL BDL 12/6/1995 BDL BDL BDL BDL 920 BDL BDL BDL 12/2/1996 <1 <1 <1 <1 <10 <2 <1 <10 1/12/1998 <1 <1 <1 <1 6.1 <1 <1 3/8/2006 <1.0 <1.0 <1.0 <3.0 4.9 <2.0 <1.0 6/12/2013 <0.21 <0.29 <0.2 <0.5 1.1 <1 <0.22 0.37 J 6/4/2015 <0.21 <0.27 0.55 J <0.39 14.8 <0.34 0.62 J 2.6 PMW08 12/15/1994 BDL BDL BDL BDL BDL BDL 6/8/1995 BDL BDL BDL BDL 20 BDL 36 13 12/6/1995 BDL BDL BDL BDL 20 6/6/1997 <1 <1 <1 <1 42 <2 17 9 6/23/1998 50 15 8 12/4/1998 <1 <1 <5 <2 72 <10 21 11 6/22/1999 <1 <1 <5 <2 83 <10 12 9 12/14/1999 <10 <1 <5 <2 <5 <10 <1 <2 6/6/2000 <0.500 <0.500 <0.500 <0.500 74.4 <2.00 10.9 URS Corporation - North Carolina Page 35 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE PMW08 12/6/2000 <0.500 <0.500 <0.500 <0.500 80.4 <2.00 11.7 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 55 <5.4 8.2 7 12/5/2001 <1.0 <1.0 <1.0 <2.0 61 <2.0 5.6 8.1 6/19/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 <1.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/3/2003 <1.0 <2.0 <2.0 <6.0 90.8 <2.0 5.9 12/16/2003 <1.0 <2.0 <2.0 <6.0 15 <2.0 0.72 6/7/2004 <2.0 <4.0 <4.0 <12 150 <4.0 5.7 9/21/2004 <1.0 <2.0 <2.0 <6.0 10.1 3.1 <2.0 <2.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 57.5 <2.0 2.6 6/9/2005 <1.0 <1.0 <1.0 <3.0 84 <2.0 1.6 2.8 6/12/2013 <0.21 <0.29 <0.2 <0.5 14.7 <1 <0.22 2.6 PMW09 12/15/1994 6/8/1995 12/6/1995 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 1700 20 BDL BDL 36 36 13 6/23/1998 9 12/4/1998 <1 <1 <5 <2 180 <10 <1 8 6/22/1999 <1 <1 <5 <2 190 <10 <1 11 12/14/1999 <1 <1 <5 <2 170 <10 <1 8.5 6/6/2000 <0.500 <0.500 0.79 3.02 115 <2.00 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 129 <2.00 <0.500 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 68 <5.3 <1.0 4.9 12/5/2001 <2.0 <2.0 <2.0 <4.0 92 <4.0 3.1 6/19/2002 <1.0 <1.0 <1.0 <2.0 110 <2.0 5.4 12/17/2002 <1.0 <1.4 <1.0 <2.0 93.8 <2.0 4.7 6/3/2003 <2.0 <4.0 <4.0 <12 135 <4.0 8.2 12/16/2003 <1.0 <2.0 <2.0 <6.0 92.6 <2.0 6.5 3/22/2004 <10 6/7/2004 <2.0 <4.0 <4.0 <12 137 <4.0 6.8 9/21/2004 <1.0 <2.0 <2.0 <6.0 130 <5.0 0.69 5.5 12/6/2004 <1.0 <2.0 <2.0 <6.0 73.9 <2.0 6.1 6/9/2005 <1.0 <1.0 <1.0 <3.0 100 <2.0 0.81 6.3 12/5/2005 <1.0 <1.0 <1.0 <3.0 32 <2.0 2.4 6/20/2006 <1.0 <1.0 <1.0 <3.0 68.3 <2.0 1.2 7.1 12/5/2006 <1 <1 <1 <3 58.4 <2 0.9 7.1 6/13/2007 <0.5 <0.5 <0.5 <1 23.4 <1 0.75 J 4.6 12/5/2007 <0.2 <0.2 <0.27 <0.56 8.2 <0.44 0.43 J 4.9 6/26/2008 <0.1 <0.1 <0.1 <0.1 16 <0.1 0.93 6 12/3/2008 0.31 J <0.1 <0.1 <0.1 180 <0.1 12 70 6/3/2009 <0.1 <0.1 <0.1 <0.1 17 <0.1 1.2 6.4 12/10/2009 <0.1 <0.1 <0.1 <0.1 9.6 <0.1 0.8 3.9 6/9/2010 <0.1 <0.1 <0.1 <0.1 11 <0.1 1.2 7.1 12/9/2010 <0.1 <0.1 <0.1 <0.1 0.67 <0.1 0.1 J 0.41 J 6/8/2011 <0.1 <0.1 <0.1 <0.1 7.8 <0.1 1.3 7.1 12/7/2011 <0.1 <0.1 <0.1 <0.1 0.63 <0.1 0.11 J 0.64 6/7/2012 <0.1 <0.1 <0.1 <0.1 5.2 <0.1 1 4.7 12/5/2012 <0.1 <0.1 <0.1 <0.1 1.3 <0.1 0.41 J 1.8 6/6/2013 <0.21 <0.29 <0.2 <0.5 1.5 <1 0.4 J 2.2 12/4/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 0.6 J 6/4/2014 <0.21 <0.27 <0.21 <0.63 2.7 <0.34 1.6 3.5 J 12/3/2014 <0.21 <0.27 <0.21 <0.63 1.6 <0.34 <0.32 1.3 J 6/4/2015 <0.21 <0.27 <0.21 <0.39 2.7 <0.34 0.83 J 4.5 URS Corporation - North Carolina Page 36 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE PMW10 6/23/1998 180 12/4/1998 <1 <1 <5 <2 76 <1 <1 <5 6/22/1999 <1 <5 <2 120 <1 <1 <5 12/14/1999 <1 <1 <1 <2 34 <1 <1 <2 6/6/2000 <0.500 <0.500 <0.500 <0.500 101 <2.00 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 164 <2.00 <0.500 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 5.4 <1.6 <1.0 <1.0 12/5/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 6/19/2002 <1.0 <1.0 <1.0 <2.0 1.2 <2.0 <1.0 12/17/2002 <0.50 <0.70 <0.50 <1.0 2.2 <1.0 <0.50 6/3/2003 <1.0 <2.0 <2.0 <6.0 2.3 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.1 <2.0 <2.0 3/22/2004 <10 6/7/2004 <1.0 <2.0 <2.0 <6.0 0.9 <2.0 <2.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/8/2005 <1.0 <1.0 <1.0 <3.0 0.77 <2.0 <1.0 12/11/2014 <0.21 0.84 J <0.21 <0.63 <0.28 <3.1 <0.32 <0.2 6/4/2015 <0.21 <0.27 <0.21 <0.39 <0.28 <0.34 <0.32 <0.2 PMW11 12/2/1996 <1 <1 <1 <1 234 <2 <1 <10 6/23/1998 43 12/1/1998 <1 <1 <5 <2 390 <10 <1 <5 3/11/1999 <5 <5 <5 <5 220 <5 <5 6/11/2013 <0.21 <0.29 <0.2 <0.5 0.74 J <1 <0.22 <0.25 6/3/2014 <0.21 <0.27 <0.21 <0.63 2.6 <0.34 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 19 <0.34 <0.32 <0.2 J 6/2/2015 <0.21 <0.27 <0.21 <0.39 7.4 <0.34 <0.32 <0.2 PMW12 3/11/1999 <5 <5 <5 <5 <5 <5 <5 6/22/1999 <1 <1 <5 <2 <5 <10 <1 <5 12/14/1999 <1 <1 <5 <2 <5 <1 <1 <2 6/6/2000 <0.500 <0.500 <0.500 <0.500 1.6 <2.00 <0.500 12/6/2000 <0.500 <0.500 <0.500 <0.500 <0.500 <2.00 <0.500 <0.500 6/4/2001 <1.0 <1.0 <1.0 <2.0 <1.0 <1.8 <1.0 <1.0 6/18/2002 <1.0 <1.0 <1.0 <2.0 <1.0 <2.0 <1.0 12/16/2002 <0.50 <0.70 <0.50 <1.0 <0.50 <1.0 <0.50 6/3/2003 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/16/2003 <1.0 <2.0 <2.0 <6.0 1.1 <2.0 <2.0 6/7/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 12/6/2004 <1.0 <2.0 <2.0 <6.0 <2.0 <2.0 <2.0 6/9/2005 <1.0 <1.0 <1.0 <3.0 <1.0 <2.0 <1.0 RW02 3/23/2005 778 262 19.5 295 119 178 <20 T01 6/11/2013 6.2 J <2.9 <2 <5 600 <10 4.3 J 7.2 J TO1A 6/13/2005 <1.0 <1.0 <1.0 <3.0 2.5 <2.0 5.4 T02 6/11/2013 1420 230 430 575 3870 <50 <11 47.7 J TO2A 6/13/2005 <1.0 <1.0 <1.0 <3.0 27 <2.0 1.3 11/30/2005 <1.0 <1.0 <1.0 <3.0 10.3 <2.0 <1.0 <1.0 6/21/2006 <1.0 <1.0 <1.0 <3.0 12.8 <2.0 <1.0 1.4 12/5/2006 <1 <1 <1 <3 7.5 <2 <1 1 6/13/2007 <0.5 <0.5 <0.5 3.3 7.3 3.2 <0.5 1 12/5/2007 <0.2 <0.2 <0.27 <0.56 2.7 <0.44 <0.2 <0.2 6/3/2008 <0.1 <0.1 <0.1 <0.1 4.8 0.39 J 0.25 J 0.84 12/3/2008 <0.1 <0.1 <0.1 <0.1 4.5 <0.1 0.33 J 1.4 6/2/2009 <0.5 <0.8 <0.7 <0.8 4.9 J <1 <1 1.2 J URS Corporation - North Carolina Page 37 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE TO2A 12/9/2009 <0.1 <0.1 <0.1 <0.1 4.2 0.38 J 0.33 J 0.97 6/8/2010 0.16 J <0.1 <0.1 <0.1 7.3 <0.1 0.77 1.8 12/8/2010 <0.1 <0.1 <0.1 <0.1 3.9 . <0.1 0.18 J 1.1 6/7/2011 <0.1 <0.1 <0.1 <0.1 5.4 <0.1 0.61 1.6 12/6/2011 <0.1 <0.1 <0.1 <0.1 4.2 <0.1 0.46 J 1.4 6/7/2012 <0.1 <0.1 <0.1 <0.1 4.2 <0.1 0.48 J 1.3 12/4/2012 <0.1 <0.1 <0.1 <0.1 3.2 <0.1 <0.1 1 6/5/2013 <0.21 <0.29 <0.2 <0.5 3.4 <1 0.34 J 0.89 J 12/4/2013 <0.21 <0.2 <0.27 <0.2 11 <0.47 <0.34 1.1 J 6/4/2014 <0.21 <0.27 <0.21 <0.63 4.7 <0.34 1 1.4 J 12/3/2014 <0.21 <0.27 <0.21 <0.63 3.6 <0.53 <0.32 0.74 J UW02 10/24/1996 350 1.1 <1 11 <8 <5 2.7 <8 6/27/2005 558 172 33.8 281 25 132 <10 6/11/2013 70.1 56.3 2.1 4.7 J <0.42 37.9 <0.44 <0.51 UW04 6/13/2005 1.2 <1.0 0.58 <3.0 3.6 <2.0 <1.0 6/12/2013 <0.21 <0.29 <0.2 <0.5 <0.21 <1 <0.22 <0.25 UW05 6/13/2005 <1.0 <1.0 <1.0 <3.0 18.4 <2.0 <1.0 11/30/2005 <1.0 <1.0 0.9 1.3 49.4 <2.0 <1.0 <1.0 6/20/2006 <1.0 <1.0 <1.0 <3.0 6.4 <2.0 <1.0 <1.0 12/5/2006 <1 <1 <1 <3 7.1 <2 <1 <1 6/13/2007 <0.5 <0.5 <0.5 <1 8.1 <1 <0.5 <0.5 12/4/2007 <0.2 <0.2 <0.27 <0.56 4.8 <0.44 <0.2 <0.2 6/4/2008 <0.1 <0.1 <0.1 <0.1 3 0.33 J <0.1 0.15 J 12/4/2008 <0.1 <0.1 <0.1 <0.1 1.6 <0.1 <0.1 <0.1 6/4/2009 <0.1 <0.1 <0.1 <0.1 0.93 <0.1 <0.1 <0.1 12/8/2009 <0.1 <0.1 <0.1 <0.1 1.5 <0.1 <0.1 0.12 J 6/7/2010 <0.1 <0.1 <0.1 <0.1 1.3 <0.1 <0.1 0.25 J 12/7/2010 0.15 J <0.1 0.24 J 0.13 J 2 <0.1 <0.1 0.39 J 6/7/2011 <0.1 <0.1 <0.1 <0.1 0.97 <0.1 <0.1 <0.1 12/5/2011 <0.1 <0.1 <0.1 <0.1 1.2 <0.1 <0.1 0.13 J 6/6/2012 <0.1 <0.1 <0.1 <0.1 1 <0.1 <0.1 0.21 J 12/4/2012 <0.1 <0.1 <0.1 <0.1 0.63 <0.1 <0.1 <0.1 6/4/2013 <0.21 <0.29 <0.2 <0.5 0.45 J <1 <0.22 <0.25 12/3/2013 <0.21 <0.2 <0.27 <0.2 <0.2 <0.47 <0.34 <0.21 6/3/2014 <0.21 <0.27 <0.21 <0.63 0.77 J <0.34 <0.32 <0.2 12/2/2014 <0.21 <0.27 <0.21 <0.63 0.96 J <0.34 <0.32 <0.2 6/3/2015 <0.21 <0.27 <0.21 <0.39 0.53 J <0.34 <0.32 <0.2 UW06 6/8/1995 BDL BDL BDL BDL 54 BDL BDL BDL 6/6/1997 <1 5 <1 6 14 3 <1 <2 6/25/1998 16 14 19 54 46 25 2 62 12/4/1998 13 29 <5 17 140 <10 <1 <5 6/22/1999 22 42 <5 25 160 6 <1 <5 12/14/1999 25 21 <5 16 170 <10 <1 <2 6/7/2000 68.3 23.1 3.79 14.8 125 <2.00 <0.500 5.81 12/7/2000 93.1 <10.0 <10.0 <10.0 126 <2.00 <10.0 <10.0 6/5/2001 91 16 2.8 9.4 160 <5.1 <1.0 2.7 12/6/2001 67 14 <5.0 <10 210 <5.3 <5.0 6/19/2002 60 30 <5.0 8.6 130 35 <5.0 12/18/2002 36.3 10.7 2.2 3.1 72.7 3.2 1.1 6/4/2003 49 29.5 1.9 9.4 44.9 25.4 0.94 12/17/2003 <1.0 <2.0 <2.0 <6.0 22.2 <2.0 <2.0 6/7/2004 35.6 41.7 1.8 7.6 63.2 37.2 0.91 URS Corporation - North Carolina Page 38 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE UW06 12/7/2004 22.4 26.6 1.3 6.3 42.2 16.5 0.64 6/9/2005 7.8 14.6 0.65 1.1 13.5 26.6 <1.0 6/9/2010 2.1 4.2 0.15 J <0.1 8.8 1.1 <0.1 0.13 J 12/8/2010 3.3 4.9 0.34 J 0.19 J 21 2.2 0.26 J 0.34 J 6/8/2011 2.6 6.2 0.17 J 1.2 17 1.6 <0.1 0.27 J 6/23/2011 4.9 13 0.19 J 5.3 20 5.9 0.67 0.36 J 7/21/2011 3.7 6.5 0.2 J 1.9 25 3.7 0.61 0.52 8/16/2011 3.1 1.6 0.16 J 1.6 15 4.2 0.25 J 0.18 J 11/22/2011 2.1 0.5 0.33 J 0.62 24 0.42 J 0.83 0.59 2/16/2012 1.7 5.6 0.12 J 1.2 30 1.8 2.7 1 6/6/2012 2.1 4.3 0.21 J 0.22 J 35 1.5 0.71 0.5 12/4/2012 1.1 1.8 0.48 J <0.1 11 0.7 0.27 J 0.25 J 6/4/2013 1.8 3.1 <0.2 3.7 22.3 1.4 J <0.22 <0.25 12/3/2013 1.7 3.2 J 0.47 J <0.2 37 <1.8 <0.34 0.4 J 6/3/2014 1 2.6 J <0.21 <0.63 35 <1.4 0.74 J 0.41 J 12/2/2014 0.69 J 2 J <0.21 <0.63 34 <0.82 1.1 0.66 J 6/2/2015 0.69 J 1.8 <0.21 <0.39 11.6 1.1 <0.32 <0.2 UW08 10/24/1996 1700 150 48 200 20000 130 3 <8 6/10/2005 250 54.1 <10 <30 864 30 64.6 11/30/2005 319 59.3 5.2 18.1 404 44.3 1.5 87.1 6/23/2006 267 30.6 2.3 13.9 810 3.9 4.9 61.8 12/6/2006 250 33.4 <20 <60 813 29.3 <20 37.7 6/14/2007 816 J 87.5 9.2 25.8 J 2390 J 93.5 <5 43.5 12/5/2007 61.9 J 13.8 J 2 <0.56 71.6 25.7 2.3 J 45.1 6/4/2008 1000 80 6.8 J 3.8 J 3200 78 <2 34 12/4/2008 220 35 2.1 J 2.5 J 610 19 9.8 J 28 6/4/2009 770 69 11 J 16 J 2300 110 <5 26 12/8/2009 270 36 3.2 J 2.6 J 940 29 <2 21 6/9/2010 530 77 13 49 1600 97 <1 28 12/8/2010 120 24 1.5 J 2.2 J 390 14 5.4 18 6/8/2011 720 110 14 36 1500 100 <1 26 6/23/2011 680 80 16 J 16 J 1800 66 <5 22 J 7/21/2011 1100 110 16 J 29 2600 130 <5 26 8/16/2011 360 32 12 J 61 1600 31 <5 20 J 11/22/2011 180 20 2.7 13 440 5.6 1.9 21 2/16/2012 320 42 6.5 J 17 1100 33 <2 19 6/6/2012 490 65 9.2 J 15 1300 73 2.2 J 22 12/3/2012 62 21 1.1 J 1.1 J 360 7.2 1.5 J 25 6/4/2013 403 84.9 10.8 25.8 1250 91 <0.22 24.6 12/3/2013 83 22 1.5 J 1.57 J 320 13 1.2 26 6/3/2014 250 29 3.8 J <4.5 780 41 1.3 19 12/2/2014 130 47 2.9 J 2.1 J 360 25 <0.32 28 6/2/2015 270 41.6 5.2 5.9 632 34.3 1.2 20.6 UW09 9/13/1994 230 800 BDL 410 2100 230 BDL 12/13/1994 150 640 BDL 340 2800 180 BDL BDL 6/8/1995 170 540 BDL 190 3690 210 7.8 BDL 9/20/1995 36 120 1 58 770 21 BDL 14 10/9/1996 170 440 <25 160 5600 200 <50 56 UW10 6/27/2005 5020 1060 150 5140 341 372 <100 11/30/2005 5470 1810 265 8090 267 659 <100 <100 6/23/2006 4880 891 115 4690 238 403 <10 6.4 12/6/2006 4770 1010 136 5240 207 514 <100 <100 URS Corporation - North Carolina Page 39 of 40 Appendix C Summary of Historical Analytical Data Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, Mecklenburg County, North Carolina Well Date Benzene Ethylbenzene Toluene Xylenes MTBE Naphthalene 1,2-DCA IPE UW10 6/14/2007 4790 1030 140 5770 169 806 <25 <25 12/4/2007 5090 632 98.2 3940 143 537 <10 <10 6/4/2008 4100 760 64 5300 J 150 480 <5 5.6 J 12/4/2008 5300 740 73 J 4800 120 790 <5 5.1 J 6/3/2009 4200 950 88 7800 J 110 1500 J <5 4.7 J 12/9/2009 4800 700 85 3800 110 490 <5 <5 6/8/2010 4800 750 75 3600 J 95 420 <2 4.3 J 12/7/2010 5600 830 J 110 5000 J 68 700 J <10 <10 6/7/2011 5600 410 110 2500 47 340 <5 <5 12/5/2011 5400 490 87 2600 J 28 J 380 J <10 <10 6/6/2012 4900 590 74 1600 21 J 340 <10 <10 12/4/2012 5200 650 83 2900 19 J 380 <10 <10 6/4/2013 5370 J 504 J 98.4 2860 J 28.2 J 625 <22 <25 12/3/2013 4400 630 J 96 J 2660 J <4.1 480 J <6.8 <4.2 6/3/2014 4900 960 J 99 J 4180 J 15 J 830 <65 <40 12/2/2014 3600 J 450 80 1790 17 400 <3.2 <2 J 6/2/2015 3790 414 85.4 1700 12.1 J 365 J <3.2 1.3 J UW11 6/14/2005 0.72 1.6 0.65 5.3 7.6 2.1 <1.0 6/11/2013 <0.21 <0.29 <0.2 <0.5 1.8 <1 <0.22 <0.25 VE02 6/27/2005 33.5 31.6 90.5 10300 11.3 51.2 <1.0 11/30/2005 764 673 2450 9270 <100 544 <100 <100 6/22/2006 1400 977 872 6410 372 625 <50 <50 12/6/2006 561 652 1050 6230 37 550 <50 <50 6/14/2007 386 392 350 3130 <50 380 <50 <50 12/4/2008 95 200 210 3400 20 390 <2 <2 6/4/2009 430 560 240 3700 120 480 <5 <5 12/8/2009 1000 630 320 5000 1100 490 <5 6.3 J 6/8/2010 1500 550 380 2400 2500 460 <5 15 J 12/8/2010 1600 700 280 3200 1900 490 <5 12 J 6/7/2011 2400 810 380 3000 8500 490 <5 39 12/6/2011 2100 670 370 3000 6900 540 <5 28 6/6/2012 2700 790 360 2900 11000 500 <5 43 12/4/2012 2500 600 180 1400 10000 440 <5 34 6/4/2013 975 338 244 1490 1760 489 <4.4 10 J 12/3/2013 2200 540 580 1810 6800 340 <6.8 32 J 6/3/2014 2100 440 380 1710 9900 280 <6.5 32 J 12/2/2014 2300 620 650 3250 7400 290 <6.5 32 J 6/2/2015 2110 558 618 3010 7880 305 <6.5 28.9 VE03 6/27/2005 13.8 7.1 2 18.4 1.6 3.2 <1.0 6/11/2013 148 4.6 2.9 5.1 J 10 4.6 J <0.44 1.4 J VE04 6/27/2005 74 24.3 31.9 183 48.3 20.3 0.62 6/11/2013 6600 362 332 862 2730 <100 <22 187 VE07 6/27/2005 3410 1490 14900 8330 <250 383 <250 6/11/2013 2220 1390 2820 6550 <0.42 469 <0.44 <0.51 Note: Concentrations in ug/I J = Estimated value U = Below detection limit Data prior to 2007 were reported by previous suppliers and have not been verified. URS Corporation - North Carolina Page 40 of 40 Appendix D Concentration Versus Trend Graphs Truck -Loading Rack Area ES13 ES14 ES29 Concentration (ug/L) ES13 - 780 I I I I I I I I I I I I I I 1` 1 1 1 1 1 1 720 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 • LEGEND Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES13 Project No. 31829547 1000000 100000 Concentration (ug/L) 10000 1000 100 10 1 0.1 ES14 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE ■ o Toluene * * Naphthalene Ethylbenzene Groundwater Elevation Xylenes NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES14 Project No. 31829547 1000000 - 100000 = J • 1000 - ES29 10000 = = Toluene Ethylbenzene G - Xylenes r �a w d c 100 c0 MTBE 10 1 0.1 I I I I I I I I I I I I I 1 4°R°4c3R I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 Naphthalene Benzene 800 — 790 — - 780 770 760 750 - 740 — 730 LEGEND Benzene • o MTBE ■ i3 Toluene * * Naphthalene Ethylbenzene Groundwater Elevation Xylenes - NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES29 Project No. 31829547 West Side of Site MWO2 MWO8 MW19 MW36 MW39 MW41 1000000 100000 — Concentration (ug/L) 10000 - 1000 - 100 10 1 0.1 MWO2 800 — 790 — 780 770 760 750 - 740 — 730 I I I I I I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE Toluene * * Naphthalene Ethylbenzene Groundwater Elevation Xylenes - NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MWO2 Project No. 31829547 MWO8 1000000 100000 Concentration (ug/L) 10000 800 — - 790 — - 780 1000 = x 100 — 10 0.1 770 760 750 — 740 — 730 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene Toluene Ethylbenzene Xylenes * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlote East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MWO8 Project No. 31829547 MW19 1000000 800 — 790 100000 10000 - 100 10 1 0.1 - 780 770 760 750 = Naphthalene ,� - _ — 740 - 730 I I I I I I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 Benzene • Toluene LEGEND Ethylbenzene Xylenes * * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW19 Project No. 31829547 1 1000000 _ 100000 — Concentration (ug/L) 10000 = 1000 100 10 — r ...._... — 740 0.1 MW36 800 — 790 — 780 — 770 760 — 750 — 730 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE Toluene ** Naphthalene Ethylbenzene Groundwater Elevation Xylenes NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW36 Project No. 31829547 t 1000000 100000 Concentration (ug/L) 10000 1000 100 10 1 0.1 MW39 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 i LEGEND Benzene Toluene Ethylbenzene Xylenes * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW39 Project No. 31829547 MW41 1000000 _ _ 800 100000 - Concentration (ug/L) ■ 10000 - 1000 - Eth = To 100 10 0.1 I I 1 1 1 1 1 1 1 1 1 1 1 1 1 — - 790 - 780 770 760 750 — 740 - 730 I I" I I I I 720 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012. 2014 2016 Benzene ■ o Toluene LEGEND Ethylbenzene • n Xylenes MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW41 Project No. 31829547 Interior [Parking] Area UW08 MW21 MW51 1000000 _ 100000 Concentration (ug/L) 10000 1000 — 100 = 10 — 0.1 UW08 800 — 790 — 780 770 760 — 750 — 740 — 730 I I I I I I I I I I I I I I I I 1 1 1 I 1 I 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE Toluene * * Naphthalene Ethylbenzene Groundwater Elevation Xylenes NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URZ Marithon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for UW08 Project No. 31829547 MW21 1000000 _ 100000 - Concentration (ug/L) 10000 800 — 790 — 780 _ TnL inno F4hvlhomcno 100 10 0.1 770 760 — 750 — 740 - 730 I I I I I I I I I I I I I I I I I I I I I I 1994 1996 1998 2000 2002 2004 2006. 2008 2010 2012 2014 2016 LEGEND Benzene Toluene Ethylbenzene Xylenes * * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marithon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW21 Project No. 31829547 1000000 100000 = Concentration (ug/L) 10000 1000 — 100 — 10 1 0.1 MW51 lenes Naphthalene Benzene 800 — 790 — 780 770 760 750 — 740 — 730 I I I I I I I I I I I I I I I I I I I I I I 720 1994 1996 1998 2000 2002 2004. 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE Toluene * * Naphthalene Ethylbenzene x Groundwater Elevation Xylenes NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marithon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for MW51 Project No. 31829547 East Side ES33 ES34 PMWO9 1000000 - 100000 — Concentration (ug/L) 10000 - 1000 - 100 10 0.1 ES33 800 — 790 - 780 770 760 750 — 740 — 730 TIII 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 I 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES33 Project No. 31829547 ES34 1000000 100000 - Concentration (ug/L) 10000 = 1000 — 800 — 790 — 780 — 770 — 760 100 — 10 0.1 750 — 740 - 730 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene • o MTBE Toluene * * Naphthalene Ethylbenzene Groundwater Elevation Xylenes NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marithon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES34 Project No. 31829547 1000000 _ PMWO9 100000 - Concentration (ug/L) 10000 1000 - = 13f0.113eezene Xylenes 100 — 10 — = Naphthalene 0.1 Benzene 800 — 790 — 780 — 770 — 760 750 - 740 — 730 I I I I I I I I 1 1 1 1 I I����� 1 1 1 720 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 • LEGEND Benzene Toluene Ethylbenzene Xylenes * * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marithon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for PMWO9 Project No. 31829547 Central/Downgradient DWO2 DWO3 ES38 1000000 DWO2 100000 - Concentration (ug/L) 10000 - 1000 - Toluene Ethylbenzene 100 Xylenes MTBE 10 — = Naphthalene 1 0.1 Benzene I I I I I I I I I I I I I I 1 800 — 790 — 780 770 760 750 - 740 - 730 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 Benzene ■ ❑ Toluene LEGEND Ethylbenzene : e Xylenes MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for DWO2 Project No. 31829547 DWO3 800 790 780 770 760 750 740 730 720 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene Toluene Ethylbenzene Xylenes * MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others Groundwater Elevation (feet) URS Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for DWO3 Project No. 31829547 ES38 1000000 _ 800 100000 = Concentration (ug/L) 10000 1000 = = Toluene Ethylbenzene 100 — Xylenes MTBE 10 — = Naphthalene 0.1 Benzene — - 790 780 770 — 760 750 — 740 - 730 1994 1996 1998 2000 2002 2004 2006 2008 2010 2012 2014 2016 LEGEND Benzene Toluene Ethylbenzene Xylenes • 0 MTBE Naphthalene Groundwater Elevation NC 2L Groundwater Standard Note: Open symbols represent detection limit for nondetect results. Data prior to January 2007 has been taken from documents prepared and submitted to NCDENR by others 720 Groundwater Elevation (feet) uRs Marathon Charlotte East Terminal 7401 Old Mount Holly Road Charlotte, North Carolina Appendix D Time -Trend Graph of Analytical Results and Groundwater Elevations for ES38 Project No. 31829547 Appendix E Historical Isoconcentration Maps Benzene MTBE Naphthalene 1,2-Dichloroethane 2015 - 8:53 AM September 21, \Jobs4\ Pro iects\Marathon <Fmr BP 4762)\5,0 Deliverables\5,3 Reports\June 2015\figures \1-Benzene,dwg / DECEMBER 2013 JUNE 2014 • DECEMBER 2014 I LV.3 _dw JUNE 2015 0 350 Legend Property Line DWo1 • Groundwater Monitoring Well Abandoned Monitoring Well 1 Benzene Isoconcentration Contour (ug/I) SCALE AS SHOWN DESIGNED BY DATE CDNFIIENTIAL-ALL RIGHTS RESERVED -PROPERTY OF DRAWN BY TSH CHECKED BY AB DATE 01SEP15 DATE 01SEP15 APPROVED BY DATE MN 01SEP15 Historical Benzene Isoconcentration Maps Marathon Charlotte East Terminal CONTRACT NO. 60393333 DRAWING ND. 1—BENZENE REV. 0 rn W N Q v/ I N 3 7 to > )%tj" �,9, II I •: w. f;, i i �,. - • t —t_ J, a Z29_._,•P;ERy JUNE 2013**`.; • t • n .. :.. .. '. _.. �` �'� 1 , \ •i - ;r• -----_._ w;• ,1 fit; rr', •:°^/f�. ••��-1,--• i 1, �' , •u **• DECEMBER 2013 —_ • . _ - \.1 �, \fr-. ..-2, _ �� _ -- • _ _ • : / • '• • • )I,�� � �� V�,i (r = • -- '� '";9 ��.lY`*'. - -- - ` � d• ,.• _ _ JUNE 2014 ------ ; . • l I�[; • •W .. ,\ \ _ — , �. • • \' �`y• ��� _-—_.._,' ,- DECEMBER 2014 \ e_: \ \s \£ • 1 "�� \ y�." _i " •MI _ -a � \L•b _ — ---_ ` _ �3• — \• I I I I I • = s°\ •� • • • / : N. lei $ • ' I i _ _ • • ,. \;. -• � _" — — -- _ \ ",., . _ \ 0 350 Legend in a few of during the plume better — — DW01 • 20 — Property Groundwater Abandoned Line Monitoring Well Monitoring Well ContourR- of 1/1/2010) Contour been observed of the elongated wells were sampled making the MTBE Isoconcentration (ug/I) (As MTBE Isoconcentration :: . �� .), • -- _w_,>• JUNE 2015 • -' _ - r_ (ug/I) (8/2009) ** Elevated concentrations of MTBE have the wells within the 2013 and 2014 depiction plume dating back to 1999. Additional 3 and 2014 sampling events; therefore, def defined. SCALE AS SHOWN DESIGNED BY DATE Historical MTBE Isoconcentration Maps Marathon Charlotte East Terminal CTNTIIENTIAL-ALL RIGHTS RESERVED -PROPERTY OF UltS RDU. NORTH CAROUNA 27560 DRAWN BY TSH DATE 01 SEP15 CHECKED BY AB DATE 01 SEP15 CONTRACT NO. 60393333 DRAWING N0. 2—MTBE REV. 0 APPROVED BY MN DATE 01 S E P 15 I I r_ O i I � Cll -74 rIV U) ru o- L + O _E 6 L `J N u O1 0 0 0 1 Q_ 2015 - 8:45 AM L' JUNE 2013 DECEMBER 2013 JUNE 2014 • DECEMBER 2014 JUNE 2015 0 350 Legend Property Line DWOI• Groundwater Monitoring Well ;I Abandoned Monitoring Well - 21 Naphthalene Isoconcentration Contour (ug/I) 6 Naphthalene Isoconcentration Contour (ug/I) (As of 1/1/2010) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF URS RDU, NORTH CAROLRN 27550 DRAWN BY TSH DATE 01 SEP15 CHECKED BY AB DATE 01 SEP15 Historical Naphthalene Isoconcentration Maps Marathon Charlotte East Terminal APPROVED BY MN DATE 01 SEP15 CONTRACT NO. 60393333 DRAWING N0. 3—NAPH REV. 0 2015 - 8:46 AM September 21, i d;• JUNE 2013 DECEMBER 2013 • JUNE 2014 • DECEMBER 2014 JUNE 2015 • 0 DW01 • 350 0.38 0.40 Legend Property Line Groundwater Monitoring Well Abandoned Monitoring Well 1,2-Dichloroethane lsoconcentration Contour (ug/I) 1,2-Dichloroethane lsoconcentration Contour (ug/I) (As of 1/1/2010) SCALE AS SHOWN DESIGNED BY DATE CONFIDENTIAL -ALL RIGHTS RESERVED -PROPERTY OF URS RDU. NORTH CAROUNA 27560 DRAWN BY TS H DATE O1SEP15 CHECKED BY AB DATE O1SEP15 Historical 1,2—Dichloroethane Isoconcentration Maps Marathon Charlotte East Terminal APPROVED BY MN DATE O1SEP15 CONTRACT NO. 60393333 DRAWING NO. 4-1,2—DCA REV. 0 NORM CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES NOTIFICATION OF INTENT TO CONSTRUCT QR OPERATE INJECTION WELLS The following are "Permitted by rule" and do not require an individual permit when constructed in accordance with the rules Tof15A NCA C 02C .0200. This form shall be submitted at least 2 weeks prior to injection. AQUIFER TEST WELLS (15A NCAC 02C :0220) These wells are used to inject uncontaminated fluid into an aquifer to deterinine aquifer hydraulic characteristics., iNS/TUREMfEDIATION (I5A NCAC 02C .0225) or TRACER WELLS (15A &CAC 02C .0229):. 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods. 2) Small -Scale Injection Operations .— Injection wells:located within, a: land sinfaceUrea not to, exceed 10,000 square feetfor the purpose of soil orgroundwater remediation or tracer:tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation,. and where the surface area of the injection zone wells:are locatedwithin:an area thatdoes nOt exceed -five -Percent of the:land surface above the known extent of groundWater contamination. An individual permit shall* required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE , 20 PERMIT NO, A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection (2) Aquifer Test Weli.. ............ ... (3) Passive Injection. System—. (4) Small -Scale Injection Operation.., (5) Pilot Test. . , . .. .. Tracer Injection ........ B. STATUS OF WILL OWNER: fhoow (to be filled in by DWR) sections BF, K, N sections B-F, K, N Complete sections B-F, 1-1ANT Complete sections 13-N Complete sections. B-N ............. ...Complete sections B-N C. WELL OWNER — State name of entity and name 'of person ,delegated authorityto sign on behalf of the business or agency: Name: 14 1rIA"IA01,,,. 1):&41-0 1-€4(wt.. Com'r Lr 01P,, , Mailing Address: \fit/1 Ce/EAVII4 City: 1 IMIT00/10, State: Zip Code: L14.7.:$&4 County:',Mt(T01".. Day Tele No.: 3 I/ 11 - 13-7-4 Cell No.: EMAIL Address: Fax No.: UIC/In Situ Remed. Notification (Revised3/2/20i5) Page 1 E. PROJECT CONTACT - Person who can answer technical questions about the proposed injection project, Name: r=tk N 145 (a00 oo City: ov rtsvif (z, State: too Zip Code: V7S-(va County: •1-ke, Ce11 No.: EMAIL Address: Fax No.: D. PROPERTY OWNER (if different than well owner) Name: Mailing Address: City: State: Zip Code: County: Day Tele No.: Ce11 No.: EMAIL Address: Fax No.: Mailing Address: DayTeleNo.: (vq) 11(01-1-1("2-- F. PHYSICAL LOCATION OF WELL SITE (1) Physical Address: � c old MA - County: City: C State: NC Zip Code: 'VOA (2) Geographic Coordinates:. Latitude**: ° " or ° Longitude**: ° " or ° Reference Datum: Accuracy: Method of Collection: **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: square feet Land surfacearea of inj. well network: square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be < 5% of plume for pilot test injections) H. INJECTION ZONE MAPS — Attach the following to the. notification. (1) Contaminant plume map(s) with isoconcentration lines that 'show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and•existing and proposed injection wells; and (2) .Cross-section(s) to the known or projected' ,depth of contamination that show the: horizontal, .and vertical extent of the contaminant -.plume, in soil and groundwater, changes in lithology, existing. and proposed monitoring wells, and existing and proposed'injection wells. (3) Potentiometric surface :map(s) indicating the rate and direction of groundwater .movement, plus existing and proposed wells. UICIInSitu Remed. Notification (Revised 3/2/2015) Page 2 I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES — Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. J. INJECTANTS — Provide a MSDS and the following for each injectant. Attach additional sheets if necessary. NOTE: Approved injectants (tracers and remediation additives) can be found online at http://portal.ncdenr.org/web/wq/aps/gwpro. All other substances must be reviewed by the Division of Public Health, Department of Health and Human Services. Contact the UIC Program for more info (919-807-6496). Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: K. WELL CONSTRUCTION DATA (1) Number of injection wells: 26 Proposed 1 Existing (2) Provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following: (a) well type as permanent, direct -push, or subsurface distribution system (infiltration gallery) (b) depth below land surface of grout, screen, and casing intervals (c) well contractor name and certification number UICln Situ Reined. Notification (Revised 3/2/2015) Page 3 L. SCHEDULES— Briefly describe the schedule for well construction and injection' activities. M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER, APPLICANT: '1 hereby certify,under penalty of law, that fain familiar with the information submitted in this document and all attachments thereto and that based on my inquiry of those individuals immediately responsible for obtaining said ittf rmation, I believe that the information is true, accurate and complete dam aware that there are significant penalties, including; the possibility of fines and imprisonment, for submitting false information I agree to construct, operate, maintain, repair, and if applicable; abandon the injection well and all related appurtenances in accordance with the I5A NCAC 02C 0200 Rules." Brett G, Schaefer, PE Signatate of Applicant, Print or Type Full Name PROPERTY OWNER (if the property is not owned by the permit applicant): "As owner of the property on which the injection well(S) areto be constructed and operated; I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction. Standards (ISA NCAC 02C .0200). " "Owned' means any yccsoa. who holds the fee or .other property rightsin the well being constructed. A well is real property and its construction on land shallbe deemed to vest ownership in the land owner; in t in writing.. the absence of contrary agr S1gnature* of Prop2rtyOwner (if different from applicant) ilk 4 ILe. / 4J//24 f/i Print or Type Full Name An access agreement between the applicant' and property owner may be submitted inner' of a signature on this form. Submit: the completed notification package to: DWR UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 YIIGIn Situ Remed. Notification (Revised 3/2/2015) Page 4 0 Y.c Pining Rid \CAD\ H9ign\4.4 [heign $➢e \Aids\T G:\Ooto\200\MPC\Remediotian S 0W100 ES07 ` 0 OW05 �... ,�r -1 S3� ESIO i ) RWO3 `' i / 1",. i � i � MW48—,._�,=—@fESO�: 1_JMw27 AW20 MW21 t((-' _ ;,� (- -�. 1 /` / BS16. YBS24 — ' VE04 MW% z7 0 MW26 BS15• SVE11 BS23 • ESOEDR ESO5SR 0 / SVE10 SVE9Q SVES • BS14 BS13 _ �Q ; ES11 0 / 1_'1 BS12 0 Q I BS11 0 OFFICE #5 l; ID( �1 1,dW43� .1Z_c7'"�,n -BS27 Q :�ri S EJ In •SVEE6 BS26 SVES rsp� 0S 5 REMEDUtii0 'x24'1 COVERED LOADING RACK 1 0 VE07 6 f _ I(L_ i4iULTIPLE Plp g c_ L_ `_ R 02< � 4 ,NS06 BS22.\ 1n-#8 ct,, )sI !UWOB{ BS21 TO ) sal / 1Igj'1-70 I UW/0'Bs1a DP101��> ' 1 \suwo2t' v�UW11 C. ES30 ES26 J/ MW42 MW4 0 1 SVE4Q o I B ® •BS9 SVE3 _ RW0212 E2 MW3�: 0 MW3 eseQ` 411 ° Q 0 BM7 Qt SVE1 MW 41 / S CBS_ " APPioxlMnrE ®rF5 BS'F 3 —�j nR_ i ROPER7Y LIN E : 2' } - ,Q ? : , ? ..8 $19_ 0.^r 12' —t----__NitiL`__----_..__ c. ES28 _IIII ES37 D ®)2 EQUIPMENT BUILDING n TC Legend Treeline Fence Line Property Line Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Groundwater Monitoring Well Proposed Blosparge Well (BS3) 0 Proposed SVE Well (SVE2) Gravel Area FT NOTES: 1. Shallow groundwater flow is towards the SSW. 2. A lane must he open at all times to allow traffic flow on paved portions of the work site unless otherwise discussed during kickoff meeting. 3. Contractor will convert existing VE04 into SVEI2 and AS06 into AS22. 0 60 N0. DATE BY REVISION WELL LAYOUT PLAN MARATHON PETROLEUM COMPANY CHARLOTTE, NC DRAWN BGS CHECKED MN DATE 5/16/14 SCALE 1 "=60' FIGURE SIZE B FIGURE 1 12" x 12" WELL VAULT INTERIOR 1"xd" REDUCER 2"x1" THREADED REDUCER 2"x2"x1" GAL THREADED . REDUCING TEE 2" GAL PIPE 2" PVC TO GAL ADAPTER 2" PVC WELL CASING PLAN VIEW BIOSPARGE WELL CROSS—SECTION 1" COMPRESSED AIR RATED HOPE PIPE FROM EQUIPMENT COMPOUND SAMPLE PORT FOR AIR FLOW/PRESSURE MONITORING 1" GAL 90' 1" BRASS BALL VALVE 1" GAL PIPE 1" HDPE TO GAL ADAPTER TYPICAL BIOSPARGE WELLHEAD CONSTRUCTION DETAILS --T� 1" COMPRESSED AIR RATED HDPE PIPE FROM EQUIPMENT COMPOUND Contractor: S&ME, Inc. Driller Name: Tom Whitehead Well Contractor Cert.#: 2907-A NOTES: TO BIOSPARGE WELLHEAD 24' 12' APPROXIMATELY 40' BELOW GROUND SURFACE 24" TYPICAL BIOSPARGE WELL CONSTRUCTION DETAILS CEMENT—BENTONITE GROUT TO 36" BELOW GRADE (TRENCH DEPTH) HYDRATED BENTONITE PELLET SEAL 20/40 SAND 2in.OD 40um SCHUMASOIL HIGH DENSITY POROUS POLYETHYLENE WELL SCREEN APPROX. 8—INCH BOREHOLE 1. WELL INSTALLATION WILL BE PERFORMED BY OTHERS. CONTRACTOR TO CONSTRUCT VAULT AND CONNECT PIPING. 2. HDPE TO GALVANIZED AND PVC TO GALVANIZED ADAPTERS SHALL BE SINGLE MOLDED TRANSITION FITTINGS. 3. WELL COMPLETION DETAIL IN CONCRETE IS TO BE UTILIZED FOR WELL VAULTS LOCATED IN BOTH ASPHALTIC CONCRETE AND PORTLAND CEMENT BASED CONCRETE AREAS OF THE TERMINAL. COMPLETE JOINT PER GSTD-0123-01-C NOT TO SCALE POURED FIBER REINFORCED CONCRETE PAD EXISTING NEW GRAVEL CONCRETE BEDDING 12' X t2' BIOSPARGE WELL TRAFFIC RATED STEEL WELL VAULT 1Y _ (1YP) PEA GRAVEL TYPICAL WELL SURFACE COMPLETION DETAIL IN GRAVEL PATH (BS-18 THROUGH BS-24, AND BS-27) POURED FIBER REINFORCED CONCRETE PAD EXISRNG NEW CONCRETE CONCRETE BEDDING 6' BIOSPARGE WELL TRAFFIC RATED STEEL WELL VAULT PEA GRAVEL TYPICAL WELL SURFACE COMPLETION DETAIL IN CONCRETE (B5-7 THROUGH DS-17, BS-23, BS-25, BS-26) 36' MIN CONCRETE EXTENSION PER GBTD-0123-02-C FT BIOSPARGE WELL VAULT DETAILS MARATHON PETROLEUM COMPANY CHARLOTTE, NC DRAWN BGS DATE SCALE FIGURE SIZE FIGURE CHECKED MN 5/19/14 N.T.S. B 2 RECEIVED/NCDENR/DWR MAY 1 8 2015 MOORESVILLWQROS E REGIONAL OFFICE May 15, 2015 Aquifer Protection Section North Carolina DENR — DWQ Mooresville Regional Office 610 East Center Avenue Mooresville, North Carolina 28115 RE: Monitoring Well Construction Permit Marathon Petroleum Company, LP (MPC) 7401 Old Mt Holly Road, Charlotte, Mecklenburg County, NC NCDENR Incident Nos.: 06771, 15159, 15618, 17002, 17263, 17264, and 20622 Program Manager: Please find enclosed a well application for biosparge and soil vapor extraction wells planned for installation in June 2015 at the above referenced site. Well installation is part of an approved Corrective Action Plan. Mecklenburg County is also being notified of proposed wells. If you have any questions or concerns, please do not hesitate to contact me at (919) 461-1423 or margaret.ness@aecom.com. Sincerely, URS Corporation — Nor Margaret Ness, PG Project Manager Attachments cc: Project File FILE SUBJECT — im-44 NUS n1 /1S-{ tia a (-" MIA) c1?() DATE URS Corporation — North Carolina 1600 Perimeter Park Drive, Suite 400 Morrisville, NC 27560 Tel: 919-461-1100 Fax: 919-46-1415 f, 7�rd ,a-V G)oviWr (e,. ?i rig gut" Ktlitl V LIJ/NUUtNhOD11111111111 MAY 1 8 2015 NORTH CAROLINA DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES WQROS DIVISION OF WATER RESOURCES - AQUIFER PROTECTION SECTION MOORESVILLE REGIONAL OFFI APPLICATION FOR PERMIT TO CONSTRUCT A MONITORING OR RECOVERY WELL SYSTEM 1. 2. 3. 4. PLEASE TYPE OR PRINT CLEARLY In accordance with the provisions of Article 7, Chapter 87, General Statutes of North Carolina and regulations pursuant thereto, application is hereby made for a permit to construct monitoring or recovery wells. Date: 5/13/15 County: Mecklenburg FOR OFFICE USE ONLY PERMIT NO. ISSUED DATE What type of well areyou applying for? (monitoringor recovery):biosparging and soil vapor extraction YP Applicant: Marathon Petroleum Company, LP (MPC) Telephone: 317-871-7824 Applicants Mailing Address: 8902 Vincennes Circle, Suite D, Indianapolis, IN 46268 Applicant's Email Address (if available): 5. Contact Person (if different than Applicant): Margaret Ness Telephone: Contact Person's Mailing Address: URS (AECOM), 1600 Perimeter Park Dr., Suite 400, Morrisville, NC 27560 margaret.ness@aecom.com Contact Person's Email Address (if available): 6. Property Owner (if different than Applicant): Mark W. Ehrman Telephone: 317-871-7824 Property Owner's Mailing Address: 8902 Vincennes Circle, Suite D, Indianapolis, IN 46268 Property Owner's Email Address (if available): 7. Property Physical Address (including zip code) and PIN Number 7401 Old Mt Holly Road, Charlotte, NC; 05724302 8. Reason for Well(s): Remediation (ex: non -discharge permit requirements, suspected contamination, assessment, groundwater contamination, remediation, etc.) 9. Type of facility or site for which the well(s) is(are) needed: Petroleum Distribution Terminal (ex: non -discharge facility, waste disposal site, landfill, UST, etc.) 10. Are there any current water quality permits or incidents associated with this facility or site? If so, list permit and/or incident no(s). Yes; NCDENR GW Incidents: 06771, 15159, 15618, 17002, 17263, 17264, and 20622 919-461-1423 11. Type of contaminants being monitored or recovered: Petroleum Hydrocarbons (ex: organics, nutrients, heavy metals, etc.) 12. Are there any existing wells associated with the proposed well(s)? If yes, how many? yes; 66 monitoring wells Existing Monitoring or Recovery Well Construction Permit No(s).: 50000061, 10000062 13. Distance from proposed well(s) to nearest known waste or pollution source (in feet): 0; within source area 14. Are there any water supply wells located less than 500 feet from the proposed well(s)? no If yes, give distance(s): 15. Well Contractor: S&ME; Thomas Whitehead Certification No.: 2907-A Well Contractor Address: 100 Kirk Ave SE, Roanoke, VA, 24011 PROPOSED WELL CONSTRUCTION INFORMATION 1. As required by 15A NCAC 02C .0105(f)(7), attach a well construction diagram of each well showing the following: a. Borehole and well diameter e. Type of casing material and thickness b. Estimated well depth f. Grout horizons c. Screen intervals g. Well head completion details d. Sand/gravel pack intervals Continued on Reverse •s PROPOSED WELL CONSTRUCTION INFORMATION (Continued) 2. Number of wells to be constructed in unconsolidated 5. How will the well(s) be secured? Locking well cap & material: 36 sealed vault 3. Number of wells to be constructed in bedrock: 0 6. Estimated beginning construction date: 6/1/15 4. Total Number of wells to be constructed: 36 7. Estimated construction completion date: 6/30/15 (add answers from 2 and 3) 1. ADDITIONAL INFORMATION As required by 15A NCAC 02C .0105(f)(5), attach a scaled map of the site showing the locations of the following: a. All property boundaries, at least one of which is referenced to a minimum of two landmarks such as identified roads, intersections, streams, or lakes within 500 feet of the proposed well or well system. b. All existing wells, identified by type of use, within 500 feet of the proposed well or well system. c. The proposed well or well system. d. Any test borings within 500 feet of proposed well or well system. e. All sources of known or potential groundwater contamination (such as septic tank systems, pesticide, chemical or fuel storage areas, animal feedlots as defined in G.S. 143-215.106(5), landfills, or other waste disposal areas) within 500 feet of the proposed well or well system. SIGNATURES The Applicant hereby agrees that the proposed well(s) will be constructed in accordance with approved specifications and conditions of this Well Construction Permit as regulated under the Well Construction Standards (Title 15A of the North Carolina Administrative Code, Subchapter 2C) and accepts full responsibility for compliance with these rules o A ) Applicant or Signature pp *Agent Margaret Ness Printed name of Applicant or *Agent Project Manager Title of Applicant or *Agent * If signing as Agent, attach authorization agreement stating that you have the authority to act as the Agent. If the property is owned by someone other than the applicant, the property owner hereby consents to allow the applicant to construct wells as outlined in this W Construction Permit application and that it shall be the responsibility of the applicant to ensure that the conform to ell Construction Standards (Title 15A of the North Carolina Administrative Codes, Subchapter 2C). Signature of Property Owner (if different than Applicant) Printed name of Property Owner (if different than Applicant) DIRECTIONS Please send the completed application to the appropriate Division of Water Resources's Aquifer Protection Section Regional Office: Asheville Regional Office 2090 U.S. Highway 70 Swannanoa, NC 28778 Phone: (828) 296-4500 Fax: (828) 299-7043 Fayetteville Regional Office 225 Green Street, Suite 714 Fayetteville, NC 28301-5094 Phone: (910) 433-3300 Fax: (910) 486-0707 Mooresville Regional Office 610 East Center Avenue Mooresville, NC 28115 Phone: (704) 663-1699 Fax: (704) 663=6040 Raleigh Regional Office 3800 Barrett Drive Raleigh, NC 27609 Phone: (919) 791-4200 Fax: (919) 571-4718 Washington Regional Office 943 Washington Square Mall Washington, NC 27889 Phone: (252) 946-6481 Fax: (252) 975-3716 '� $ ahv Ile rY Moor. sv4jle/ (Win%ron'5aleri T _ ':.� rin {on 1.4 Wilmington Regional Office 127 Cardinal Drive Extension Wilmington, NC 28405 Phone: (910) 796-7215 Fax: (910) 350-2004 Winston-Salem Regional Office 585 Waughtown Street Winston-Salem, NC 27107 Phone: (336) 771-5000 Fax: (336) 771-4630 yeti vine cL f rWiir ngton GW-22MR (Rev. 8/13) a N) 0 0 N rfl 0 0 DW1 0 ES13 ES07 ES 10 DWO5 ono, COVERED LOADING RACK ES12 e OFFICE #1 UW DPEWW02. ASO6• BS22 #7 #8 LI El 1I 1UW08 BS21 •,PTO 0 -BS20 • DWO1A e BS19• •' T01 UW 0 BS18 DWO1 -UW02 %' ' OUW1 BS17 • MW20 MW21 VE02 BS16• BS24 VE04 v. MW e MW2 6 BS15• SVE11 oI BS23 • OFFICE #4 ES3 eESO MW48 e ES37 DWO2 ❑ #6 MW43 �f14�® - -BS27 o 1.1 a WAREHOUSE IELL T BS26 MW51 gSV6 ES05DR ESO5SR SVE10O • ti e • SVE9 0 SVE8 - BS14 BS13 • ES11 0 SVE5 BS12 . • III BS11 '% BS25 MW42 MW44,, - SVE4O oli • BSs SVE3 BS10 •. . JMW46 OFFICE MW3 SVE2 RW02 MW3►\MW50 #5 o A • S05 BSS5 ES 1 :,, BS8 BST J. _3• —_-_.J MW36 SVE1 APPROXIMATE PROPERTY LINE — o MW41 M .4: BS4 ASO BS6 • BS3 M ny 4. BS2— • si BS1 — — REMEDIATION—_ EQUIPMENT BUILDING 'x24') MW-55 TC TANK 115 DWO1® DR FT Legend Treeline Fence Line - Property Line Fire Hydrant Lamp Post Protective Steel Bollard Power Pole Groundwater Monitoring Well • Proposed Biosparge Well (BS3) o Proposed SVE Well (SVE2) Gravel Area NOTES: 1. Shallow groundwater flow is towards the SSW. 2. A lane must be open at all times to allow traffic flow on paved portions of the work site unless otherwise discussed during kickoff meeting. 3. Contractor will convert existing VE04 into SVE12 and AS06 into BS22. 0 60 NO. DATE BY REVISION WELL LAYOUT PLAN M MARATHON MARATHON PETROLEUM COMPANY CHARLOTTE, NC DRAWN BGS CHECKED MN DATE 5/18/14 SCALE FIGURE SIZE B FIGURE 1 12" x 12" WELL VAULT --\INTERIOR PLAN VIEW 1 "x4" REDUCER 2"x1" THREADED REDUCER 1" COMPRESSED AIR RATED HDPE PIPE FROM EQUIPMENT COMPOUND SAMPLE PORT FOR AIR FLOW/PRESSURE MONITORING 2"x2"x1" GAL THREADED 1" GAL 90' REDUCING TEE 2" GAL PIPE 2" PVC TO GAL ADAPTER 2" PVC WELL CASING BIOSPARGE WELL CROSS-SECTION 1" BRASS BALL VALVE 1" GAL PIPE 1" HDPE TO GAL ADAPTER TYPICAL BIOSPARGE WELLHEAD CONSTRUCTION DETAILS 1" COMPRESSED AIR RATED HDPE PIPE FROM EQUIPMENT COMPOUND Contractor: S&ME, Inc. Driller Name: Tom Whitehead Well Contractor Cert.#: 2907-A NOTES: APPROXIMATELY 40' BELOW GROUND SURFACE TO BIOSPARGE WELLHEAD 24" MIN 12" 24" ;rr CEMENT—BENTONITE GROUT TO 36" BELOW GRADE (TRENCH DEPTH) HYDRATED BENTONITE PELLET SEAL 20/40 SAND 2in.OD 40um SCHUMASOIL HIGH DENSITY POROUS 77-- POLYETHYLENE WELL SCREEN TYPICAL BIOSPARGE WELL CONSTRUCTION DETAILS APPROX. 8—INCH BOREHOLE 1. WELL INSTALLATION WILL BE PERFORMED BY OTHERS. CONTRACTOR TO CONSTRUCT VAULT AND CONNECT PIPING. 2. HDPE TO GALVANIZED AND PVC TO GALVANIZED ADAPTERS SHALL BE SINGLE MOLDED TRANSITION FITTINGS. 3. WELL COMPLETION DETAIL IN CONCRETE IS TO BE UTILIZED FOR WELL VAULTS LOCATED IN BOTH ASPHALTIC CONCRETE AND PORTLAND CEMENT BASED CONCRETE AREAS OF THE TERMINAL. COMPLETE JOINT PER GSTD-0123-01-C NOT TO SCALE POURED FIBER REINFORCED CONCRETE PAD EXISTING NEW GRAVEL CONCRETE BEDDING ; 12' X 12' 2' TRAFFIC RATED STEEL WELL VAULT 12' (T'P) fy �/. PEA GRAVEL BIOSPARGE WELL TYPICAL WELL SURFACE COMPLETION DETAIL IN GRAVEL PATH (BS-18 THROUGH BS-24, AND BS-27) POURED FIBER REINFORCED CONCRETE PAD EXISTING NEW CONCRETE CONCRETE BEDDING 6' 12' X 12' 2' BIOSPARGE WELL TRAFFIC RATED STEEL WELL VAULT 36" (MIN) PEA GRAVEL TYPICAL WELL SURFACE COMPLETION DETAIL IN CONCRETE (BS-7 THROUGH BS-17, BS-23, BS-25, BS-26) 36' MIN CONCRETE EXTENSION PER GSTD-0123-02-C AFT BIOSPARGE WELL VAULT DETAILS MARATHON PETROLEUM COMPANY CHARLOTTE, NC DRAWN BGS DATE SCALE FIGURE SIZE FIGURE CHECKED MN 5/19/14 N.T.S. B 2 t 12" x 12" THREADED PVC WELL VAULT WELL CAP INTERIOR 3" SCH40 PVC SVE LINE 1/4" LIQUID FILLED 0-100"H20 PRESSURE GAUGE PVC REDUCING TEE (4" x 4" x 3") PLAN VIEW SVE WELL CROSS—SECTION TO EQUIPMENT COMPOUND 1/4" NPT LIQUID FILLED 0-100"H20 VACUUM GAUGE THREADED PVC WELL CAP 4" PVC RISER 3" SCH40 PVC SVE LINE TO EQUIPMENT COMPOUND TYPICAL SOIL VAPOR EXTRACTION WELLHEAD CONSTRUCTION DETAILS APPROXIMATELY 10' BELOW GROUND SURFACE TO SVE WELLHEAD ss, 12" MIN 6" 6' nz. CEMENT—BENTONITE GROUT TO 36" BELOW GRADE (TRENCH DEPTH) HYDRATED BENTONITE PELLET SEAL 4—INCH PVC CONTINUOUS WRAP 0.020—INCH SLOT WELL SCREEN APPROX. 10—INCH BOREHOLE TYPICAL SOIL VAPOR EXTRACTION WELL CONSTRUCTION DETAILS COMPLETE JOINT PER GSTD-0123-01—C POURED FIBER REINFORCED CONCRETE PAD EXISTING NEW CONCRETE CONCRETE BEDDING 6" NOT TO SCALE 12" X 12" TRAFFIC RATED STEEL WELL VAULT 36" (MIN) //\ i\\/ pacT,%`�� PEA GRAVEL TYPICAL WELL SURFACE COMPLETION DETAIL (SVE-1 THROUGH SVE-12) 36" MIN CONCRETE EXTENSION PER GSTD-0123-02—C J RAFT SVE WELL VAULT DETAIL M MARATHON MARATHON PETROLEUM COMPANY CHARLOTTE, NC DRAWN BGS DATE SCALE FIGURE SIZE FIGURE CHECKED MN 5/19/14 N.T.S. B 3