WI0300111_Regional Office Historical File Pre 2018

North Cart lina Depa
w`~`i [iant , Ross Jr., Secretary
nvirnnment anti Natural Resources
COI H. Sullins, Director
Division of Water Quality
Scott Bortz
Sunset Southstar, LLC `/„ Tribek Properties
200 Providence Road. Suite 106
Charlotte, NC 28207
Subject:
June 18, 2008
Rescission of 51 Injection Well Permit No. W10300111
Beatties Ford Rd. & Sunset Rd. (Proposed Walgreen Store)
Mecklenburg County
Dear Mr. Bortz:
Reference is made to your request for rescission of the subject 5I injection well permit. Staff from the
Mooresville Regional Office have confirmed that this permit is no longer required. Therefore, in
accordance with your request, Permit Number W1.0300111 is rescinded effective immediately.
If, in the future, you wish again to conduct injection operations you must first apply ftor and receive a new
injection well permit. Operating an injection well without a valid permit could result in a civil penalty of
up to $25,000 per day.
Please contact the Mooresville Regional Office at [phone] or Debra atts ofthe Groundwater.
Protection Unit at [phone] if you have any questions.
oleen H. Sullins
CHS:tjs
cc: Andrew Pitner— Mooresville Regional Office
APS CO Files
One
N, thCa�rolinn
,,Vatu ahllf
Division of Water Quality 1617 Mal] Setwiee
Internet: sr.vw.ncrvteratttataiv.aar 512 N, Salisbury 5:
Center
Raleigh, NC 27699-1617 Phone
Raleigh, NC 27604 Fax
An Equal Opportunity/Affirmative Action Employer — 50% Recycle dfl0 Pot onsumer Paper
9
-7015 Customer Sc
-2496 1-877-625_,

March 13, 2007
Attn: Aquifer Protection Section Staff
NCDENR
Division of Water Quality
Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue, Ste 301
Mooresville, North Carolina 28115
Project No, 99006-0 6118
Subject: Sodium Persulfate Pilot Study Report February 27, 2007
Site of Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road, Charlotte, North Carolina
UIC Permit No.: WI0300111
DeAquifer Protection Section Staff:
Enclosed please find a copy of the above referenced report for the above referenced subject
property.. As discussed in the attached report, the pilot study conducted at the referenced site is
complete, If you have questions, please contact me at 919 960-6289,
Sincerely,.
Bureau Verity North America, Inc,
David Wagner
Senior Consultant
Tampa Regional Office
cc: Aquifer Protection Section — UIC Staff, Raleigh, NC office
Mr. Randy Nance, PIN Construction Consulting
Mr. Scott Bartz, Sunset Southstar, LLC
hments
Bureau Verltas North America, Inc.
094*

Sodium Persulfate Pilot Study Report
Proposed Wa!green Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, North Carolina
Bureau Veritas Project No. 99006-006118
FEBRUARY 27, 2007
Prepared for:
Mr. Scott Bortz
SUNSET SOUTHSTAR, LLC
200 Providence Road, Suite 106
Charlotte, North Carolina 28207
Prepared by:
Bureau Veritas North America, Inc.
3710 Corporex Park Drive, Suite 220
Tampa, Florida 33619
vvww.us.bureauveritas.com

February 28, 2007
Mr. Scott Bartz
SUNSET SOUTHSTAR, LLC
200 Providence Road, Suite 106
Charlotte, North Carolina 28207
BU R EAU
VERITAS
Bureau Veritas Project No. 99006-005118
Subject: Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, North Carolina
Dear Mr. Bortz:
Attached is the Bureau Veritas North America, Inc. (Bureau Veritas), (formerly Clayton Group
Services, Inc., a Bureau Veritas Company) Pilot Study report for the above -referenced property.
This report is certified to Wafgreen Co.
If you have questions or comments, please contact the Chicago Regional office at [phone].
Sincerely,
Bureau Veritas North America, inc.
Health, Safety and Environmental Services
David Wagner
Senior Consultant
Environmental Services
Tampa Regional Office
Dave Matz
Project Manager
Environmental Services
Chicago Regional Office
Bureau Veritas North America, Inc.
3140 Finie7 Road
Downers Grove,11. 60515
30(6._
Richard E. Carman
Division Manager
Environmental Services
Tampa Regional Office
Main: [phone]
Fax [phone]
www.us.bureauvesitas.corn reauve ,tas.com

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
TABLE OF CONTENTS
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
1.0 INTRODUCTION & BACKGROUND 1
2.0 SCOPE OF WORK 3
3.0 FINDINGS 4
3.1 Persulfate Solution Injection and Distribution 4
3.2 Pre- and Post -Injection Analytical Results 4
4.0 CONCLUSIONS & RECOMMENDATIONS 5
Figures
1 Site Vicinity Map
2 Site Map Showing Recognized Environmental Conditions and Pilot Study Location
Table
1 Summary of Groundwater Analytical Results for Pilot Study Monitoring Well PMW-1
Appendices
A injection Permit
B Redox Tech, LLC Pilot Study Report
C Laboratory Analytical Reports & Chain -of -Custody Records
SAW& gree^sTropGs1II51181P6ot Study11427.-p43-2Bfe1507.tloc
Project Number 99006-006118

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store Si 0275
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
1.0 INTRODUCTION & BACKGROUND
Sunset Southstar, LLC (c/o Tribek Properties) retained Bureau Veritas North America, Inc. (Bureau
Veritas) to conduct a sodium persulfate pilot study (Pilot Study) at the site of proposed Walgreen
Store # 10275 located at the southeast comer of Beatties Ford Road and Sunset Road in Charlotte,
North Carolina (the "subject property"). The Pilot Study was conducted in accordance with Bureau
Veritas' proposal No. 0711.06.1241 dated July 14, 2006 and Change Order No. 3 to this proposal
dated September 19, 2006. A site location map is provided as Figure 1. As of the date of this report,
the subject property is being redeveloped for use as a Walgreen Retail Drug Store.
The primary objective of the Pilot Study was to evaluate if a base -activated sodium persulfate solution
(persulfate solution) could feasibly be used to reduce to below applicable standards the concentrations of
petroleum -related contaminants present in soil and groundwater associated with the documented Old
Store Leaking Underground Storage Tank (LUST) Incident at the subject property. The results of the Pilot
Study were then used to evaluate the efficacy of using a persulfate solution to remediate (i.e., reduce the
concentrations to below applicable standards) the impacted soils and groundwater associated with the
LUST Incident, and to obtain design parameters for a full-scale remediation system.
During January 2006, Sunset Southstar, LLC retained Bureau Veritas to conduct a Limited
Subsurface Investigation (SI) at the subject property. The Limited S1 was conducted in two phases.
The first phase is referred to as the Limited SI and the second phase is referred to as the
Supplemental Limited SI. The Supplemental Limited SI was conducted to further evaluate the extent
of impacted soil and groundwater detected at the subject property during the Limited SI. The Limited
SI investigation is summarized in Bureau Veritas' report entitled, "Limited Subsurface Investigation,
Proposed Walgreen Store #10275, SEC of Beatties Ford Road and Sunset Road, Charlotte, NC'
dated February 20, 2006. The Supplemental Limited SI is summarized in Bureau Veritas' report
entitled, "Limited Subsurface investigation —Supplemental Report, Proposed Walgreen Store#10275,
SEC of Beatties Ford Road and Sunset Road, Charlotte, NC" dated February 9, 2007. The purpose
of the Limited SI scope of work was to evaluate the recognized environmental conditions (RECs) that
were identified during the performance of a Phase I Environmental Site Assessment (ESA) that was
conducted at the subject property by Bureau Veritas during Fall 2005 (Bureau Veritas Project
Number 16-06118, report dated October 27, 2005). The three referenced reports were previously
submitted to Sunset Southstar, LLC and Walgreen Company and include summaries of the history of
these RECs, investigations performed to evaluate potential Impacts to soil and groundwater
associated with these RECs, and the regulatory status of these RECs (particularly the Old Store
LUST Incident).
One of the RECs investigated was the previously referenced Old Store LUST Incident. Based on the
results of the Limited Sis conducted to date, evidence of subsurface impact from this REC was
observed on the subject property. Impacted soil and groundwater are present at concentrations
exceeding the North Carolina Department of Environmental and Natural Resources (NCDENR)
Residential Soil Cleanup Levels (SCLs) and Gross Contamination Levels (GCLs), respectively. In
addition, based on detected petroleum -related constituents near the subject property boundaries, it is
likely that impacted soil and groundwater are present off -site. However, the on -site extent of
impacted soil and groundwater associated with this REC has been adequately defined and Is limited
to the northwest comer of the subject property. It is to be noted that the goal of any remedial effort at
the subject property would be to reduce contaminant levels to below the SCLs and GCLs.
Based on the results of the Limited Sls conducted to date, the geology observed in the area of the Old Store
LUST incident generally consists of dark brown to light brown clayey silt to silty clay. The static water table is
generally encountered at a depth of approximately 17 ft bgs in this same area. The apparent groundwater
flow direction in the area of the Old Store LUST incident is to the southwest.
S:lWalprearwtproie ts1061181.Pilot StudyH0275-ph3.281eb77.60c
1 Project Number99006-006118

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
SEC of 'Seethes Ford and Sunset Roads
Charlotte, North Carolina
Assuming closure of the Old Store LUST incident is not going to be pursued in the near future by
Sunset Southstar, LLC, the following was previously recommended by Bureau Veritas, which is in
addition to that required and recommended by the NCDENR (regardless of whether or not closure is
pursued — see both the Limited SI and Limited SI — Supplemental Reports):
• In conjunction with site redevelopment, the subsurface portion only of a soil and groundwater
remediation system should be considered for installation in the area of the Old Store LUST
incident on -site Impact. Therefore, if remediation is voluntarily decided to be pursued at a
later date by Sunset Southstar, LLC or others, or needed to be pursued by the NCDENR,
after the site has been redeveloped, the subsurface portion of the remediation system could
be readily joined to the corresponding above ground portion of the system (to be installed at a
later date, if needed) with minimal site disturbance and disruption to store operations. The
installation of the subsurface portion only of a remedial system was recommended to be
installed in conjunction with site redevelopment so as to minimize the chance of any
significant disturbance to future Walgreen Company store operations. Although there are
several proven methods available for the remediation of the type of petroleum impacts
observed at the Old Store LUST incident site, given the type of geology present a the site,
which includes relatively low permeability silty clays to clayey silts, it was recommended that a
pilot study be conducted to evaluate one of these methods prior to the installation of a full-
scale system.
One of the proven methods for the remediation of the petroleum -impacted soil and groundwater is air
sparging and soil vapor extraction (ASISVE). AS!SVE was also considered by Bureau Veritas for
evaluation through the use of a pilot study. However, based on the type of geology present at the
subject property it was concluded that an AS/SVE pilot study would not be the most optimal method to
evaluate at this time. Instead, it was decided that the injection of a chemical oxidant under relatively
high pressure should be evaluated through the use of a pilot study.
Redox Tech, LLC (Redox) of Cary, North Carolina was chosen to conduct the injection Pilot Study.
Redox is an environmental remediation firm that specializes in in -situ remediation of soil and
groundwater, providing state of the art services in delivery and formulation. Redox specializes in in -
situ chemical oxidation (ISCO), chemical reduction, both aerobic and anaerobic bioremediation, and
metals stabilization. Sodium persulfate was selected by Redox as the injectant due to its proven
ability to oxidize the types of petroleum -related (more specifically gasoline -related) contaminates
detected at the site including amongst other compounds Benzene, 1,2-Dibromoethane (EDB), and
1,2-Dichloroethane (DCA). The following information was provided by Redox.
The persulfate anion is the most powerful oxidant of the peroxygen family of compounds. When given
energy (i.e., heat, light, etc.), the persulfate forms sulfate radicals which in turn produce energy and
can easily oxidize many compounds including benzene, EDB and DCA, which are present at the
subject property. The chemical oxidation process converts hazardous contaminants to non-
hazardous or less toxic compounds that are more stable, Tess mobile, and/or inert. The end products
of the oxidation of benzene, EDB, and DCA are water, carbon dioxide (CO2), chloride, bromide, and
sulfate ions. As a side benefit to the reaction, aerobic biodegradation of contaminants can benefit
from the presence of oxygen (02) released during the persulfate decomposition. Also, the sulfate that
results from the reaction of persulfate will be an electron acceptor via sulfate reduction. That is, the
sulfate will be consumed for bioconversion of petroleum compounds (i.e., benzene) after the
persulfate chemical oxidation mechanism ceases. Depending upon site -specific conditions (i.e.,
geochemistry, hydrogeology, contaminant types and concentrations, etc) and the quantity and
concentration of a persulfate solution injected into the subsurface at a given site, the persulfate
solution typically persists in the subsurface from anywhere from two to three weeks to two to three
months.
5:1WalsreonV.Proje s4D61181Pi1d Siudy51C275-ph.328teb67.doe
2 Project Number 99006-006118

Sodium Persulfate Pilot Study Report
Proposed Wa!green Store#i0275
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
The remainder of this report documents the procedures used to implement, and the results of the
Pilot Study. Recommendations based on the results of the Pilot Study are also presented.
2.0 SCOPE OF WORK
Prior to the implementation of the Pilot. Study, an "Application for Permit to Construct andlor Use a
Well(s) for Injection" (Permit Application) was prepared by Bureau Veritas and submitted to
NCDENR's Division of Water Quality (DWQ), Aquifer Protection Section (APS), Underground
Injection Control (UJC) Program in Raleigh, North Carolina on August 17, 2006. Approval of the
Permit Application was received from the NCDENR on October 11, 2006. A copy of the Permit
Application and approval letter, along with other relevant correspondence (including "Modified
Attachments E & F" dated September 19, 2006) is provided in Appendix A.
A copy of a report entitled, "Pilot Test at Beatties Ford Road and Sunset Road, Charlotte, NC" dated
February 8, 2007, prepared by Redox is provided in Appendix B. This report details the quantity and
location of the Pilot Study points and provides the general procedures used to install the Pilot Study
points, inject the persulfate solution, and monitor the distribution of the persulfate solution. In
addition, this report also summarizes the quantity of persulfate solution injected along with injection
pressures and rates. Furthermore, the Redox report also provides a summary of the apparent
distribution in the subsurface of the persulfate solution. in general, the Pilot Study Involved the
installation of three injection points (shallow, medium, and deep) and one monitoring well and the
injection of a total of approximately 900 gallons of persulfate solution into the three injection points.
The results of pre- and post -injection groundwater monitoring are discussed in the next section.
The Pilot Study was conducted in general accordance with the procedures outlined in the Permit
Application and the compliance requirements outlined in the October 11, 2006 NCDENR approval
letter. For a detailed discussion of these procedures and requirements, refer to the documents
provided in Appendices A and S. The Pilot Study target zone was from 15 to 30 feet below ground
surface (bgs) which included most of the saturated zone. Relatively significant exceptions to the
procedures outlined in the Permit Application are noted below:
■ The Pilot Study was originally planned to be performed adjacent to the location of soil boring
SB-1, where a combination of both significantly high soil and groundwater impacts had been
previously observed_ ,Flowever, it was later decided that it would be more effective to perform
the Pilot Study in an area were the most significant groundwater -only impact had been
observed, therefore the Pilot Study was performed adjacent to soil boring SB-2.
• The actual injection well screen lengths and depth intervals were slightly adjusted to provide
adequate coverage across the saturated zone.
One post -injection groundwater monitoring event was added at one week and the first post -
injection quarterly sampling event was actually performed at two months.
• Injection pressures, rates and volumes varied slightly from those estimated in the Permit
Application.
Following receipt of the Permit Application approval, the Pilot Study injection points (including shallow,
medium and deep points) were installed on October 23, 2006 and the injection of the persulfate
solution occurred on October 24, 2006. As outlined in the Permit Application, Bureau Veritas
collected pre- and post -injection groundwater samples from pilot study monitoring well (PMW-1). The
pre -injection sample was collected on October 24, 2006 just prior to the injection of the persulfate
solution. Five post -injection samples were collected at approximately 24-hours (October 25), one
week (October 30), two weeks (November 10), one month (November 21) and two months
WWalareersiPro ect 611 BSPibt SUlykl0275-2112-28ta„.07.dx
3 Project Number 99006-006118

Sodium Persulfate Pilot Study Report
Proposed Waigreen Store #10275
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
(December 27) after the injection of the persulfate solution. The procedures used to collect the
samples are outlined in the Permit Application. The groundwater samples were submitted to Pace
Analytical of Huntersville, North Carolina, which is an NCDENR-certified laboratory. The samples
were analyzed in accordance with United States Environmental Protection Agency (USEPA) SW-846
and NCDENR methods for the parameters summarized in the Permit Application. The laboratory
analytical reports and chain of custody records are provided in Appendix C. The analytical results are
summarized in Table 1.
3.0 FINDINGS
3.1 Persulfate Solution injection and Distribution
As presented in further detail in the attached Redox report (see Appendix B), in summary
approximately 900 gallons of persulfate solution (which included approximately 1,705 pounds of
sodium persulfate and 30 gallons of 25 percent by weight sodium hydroxide mixed with water) were
injected into the subsurface, with the majority of this material being injected into the deep injection
well (25 to 30 feet bgs). Due to the occurrence of daylighting', minimal quantities (approximately 90
gallons) of persulfate solution were able to be injected in the shallow (15 10 20 feet bgs) and medium
(20 to 25 feet bgs) injection points and these points were no longer able to be used for injection
because of the daylighting. Approximately 810 gallons of persulfate solution were injected into the
deep well, with an estimated 50 gallons lost to daylighting.
As discussed in greater detail in the Redox report, based on qualitative field measurements (including
starch iodide test kits and electrical conductivity measurements) performed during and immediately
(within 24 hours) after the injections were completed, it appeared that the persulfate solution was
successfully distributed throughout a significant portion of the targeted zone. Based on these field
results, it appeared that the persulfate solution was distributed radially around the injection points to a
distance of at least five feet and possibly further.
Based on these observations alone, Redox concluded that for a full-scale system application, a
minimum 15 foot well spacing could be used to successfully inject the persulfate solution into the
impacted zone and that well screen intervals of five to seven feet should be used for each injection
well. The positioning of the screened intervals would depend on the location of the water table and
the thickness of the impacted zone to be treated and that multiple vertical injection points would likely
be needed for a full-scale system. Note that Redox's conclusions do not take into account the results
of the post -injection groundwater monitoring analytical results discussed below.
3.2 Pre- and Post-lnjection Analytical Results
As shown on Table 1,17 gasoline -related volatile organic compounds (VOCs) were detected in groundwater
sample PMW-1 during the pre -injection monitoring event. Eleven of these VOCs were detected at
concentrations exceeding NCDENR's Groundwater Quality Standards (GWQSs), while three of these VOCs
were detected at concentrations exceeding both the GWQSs and the GCLs. These three gasoline -related
VOCs included Benzene, EDB and DCA and were detected in the pre -injection groundwater sample at
concentrations of 17.0, 0.59 and 2.20 milligrams per liter (mg/I), respectively. As stated previously, the goal of
any remedial effort at the subject property would be to reduce contaminant levels to below the GCLs. The
Daylighting is the observance of an injectant at the ground surface and occurs when the injectant enters a flow
path (Le., channel, fissure, etc) that is connected directly 10 the ground surface. Daylighting is not desirable
because a significant quantity of injectant does not get delivered to its intended location in the subsurface. In
addition, once daylighting starts at a given injection well location it typically cannot be stopped and the efficiency
of the injection well becomes significantly reduced.
S:1WafgraenslPrajvtis1Di11 &Pilot StuOy110275-ph3-2Br0;rD7.doc
4 Project Number 99006-006118

Sodium Persulfate Pilot Study Report
Proposed Wa!green Store f110275
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
three referenced VOCs are herein collectively referred to as the "Target Compounds" since they are the
contaminants that exceed the GCL.
As shown on Table 1, after two months of groundwater monitoring, total VOC concentrations decreased
slightly from 80.8 mg/l to 72.3 mg/i. However, the concentrations of the Target Compounds remained
generally the same after two months compared to the pre -injection results and in fact increased slightly for two
of the three compounds. The number of VOCs detected during groundwater monitoring after two months
increased to 19.
Sulfate was not detected at or above the method detection limit in any of the groundwater samples collected to
monitor the results of the Pilot Study. Based on the results of the starch iodide field tests, the sodium
persulfate appeared to have persisted in the groundwater in the area of well PMW-1 for at least two weeks
after the injections were complete, but was apparently no longer present after one month. As discussed in
Section 1.D, this is consistent with the information provided by Redox regarding the typical length of time that a
persulfate solution will persist in the subsurface.
The results of other analysis including metals and field measurements are summarized in Table 1. Four
metals including chromium, iron, sodium and copper were detected in the pre -injection groundwater sample.
Chromium and copper were not detected in any of the post -injection samples while iron and sodium continued
to be detected in the post -injection samples. The concentrations of the iron and sodium detected in the post -
injection samples were less than that detected in the pre -injection sample. This, along with the fact that
chromium and copper were not detected in any of the post -injection samples, is likely a result of the pre -
injection sample being more turbid (since it was collected just after the well was installed) than the subsequent
post -injection samples. Note that mercurywas also detected during one of the post -injection sampling events
at a relatively low concentration. As shown on Table 1, the concentrations of the field parameters remained
relatively stable throughout the Pilot Study and varied little when compared to the pre -injection results.
4.0 CONCLUSIONS & RECOMMENDATIONS
The following conclusions and recommendations are based on the observations and data from
Bureau Veritas' Pilot Study conducted at the subject property:
• Based on the qualitative field measurements at the time of the injections, it appeared that the
persulfate solution was successfully distributed throughout a significant portion of the
targeted saturated zone. However, based on the pre -and post -injection groundwater
monitoring analytical results, the concentrations of the Target Compounds remained relatively
unchanged and total VOC concentrations reduced only slightly after a two month period after
the injections were complete.
• Based on the analytical results, it appears that the concentration and/or quantity of the
persulfate solution injected was not sufficient enough to adequately reduce the Target
Compound concentrations and/or the persulfate solution was, in actuality, not adequately
distributed throughout the formation, particularly the saturated zone In the area of PMW-1.
This in spite of the evaluation of the qualitative field measurements made at the time of the
injections, which apparently indicated that the persulfate solution was adequately distributed.
Based on the observations of dayllghting at the three injection point locations, it is likely that a
significant amount of the persulfate solution ended up in the unsaturated zone in the area of
the injection points. The daylighting observed is in large part due to the type of geology (silty
clay to clayey silt) present at the subject property, which because of its relatively low
permeability can be problematic for this and other types of remedial methods. In addition, the
field measurements taken at the time of the injections were qualitative and not quantitative so
it cannot be determined based on these types of measurements the actual quantity of
persulfate solution at any given location.
S:lWalDreenslPro 5Y151181P11ot Swdy11G275-ph3-28rebD7.dac
5 Project Number 99006-006118

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
SEC of Beatties Ford and Sunset Roads
Charlotte. North Carolina
• Based on the analytical results, the Pilot Study as implemented was not successful at
reducing Target Compound concentrations. In addition, the installation and operation (if
needed) of a full-scale system involving the use of the injection of a persulfate solution (even
at greater concentrations compared to that injected during the Pilot Study) may not produce,
in a feasible manner, the desired results of reducing soil and groundwater concentrations to
below SCLs and GCLs, respectively. Furthermore, it is estimated that the installation of the
subsurface only portion of a full-scale injection system (or other types of systems such as
AS/SVE) would cost well over $50,000 and the operation of this system at a later date (if
warranted) would easily exceed Si 00,000 and could even exceed $200,000.
Based on the above conclusions, Bureau Veritas does not recommend the installation of the
subsurface only portion of a remedial system at this time, including any associated piping systems
and concrete pads. This recommendation is further bolstered by the following observations:
• Impacted soil and groundwater associated with the Old Store LUST incident REC apparently
does not extend beneath the footprint of the proposed Walgreen Store building; therefore the
threat of vapor intrusion into the building is minimal. Regardless, the NCDENR-
recommended vapor barrier beneath the building should still be Installed. It is our
understanding that Sunset Southstar, LLC does plan on installing a vapor ban-ier.
• Impacted soil and groundwater associated with the Old Store LUST incident REC at
concentrations exceeding the SCLs and the GCLs, respectively is apparently limited to the
landscaped area at the northwest comer of the subject property_ Therefore any remedial
activities decided to be undertaken at a future date would be limited to this landscaped area
only, and would result in minimal, if any, disruption to the daily operations of the future
Walgreen Store.
• As per the NCDENR, the current or future owner of the subject will not become the
Responsible Party and will not be required to undertake any remedial activities associated
with this REC. However, remedial activities can be conducted on a voluntary basis. .
• Also as per the NCDENR, since the identified nearby receptors (i.e., residential potable wells)
in the area of the Old Store LUST incident have apparently not been impacted by the release
of gasoline from the former underground storage tank system releases, the NCDENR has no
immediate plans to conduct remedial activities at the subject property.
• Based on Bureau Veritas' experience with the NCDENR and given the nature of this site,
Bureau Veritas finds it highly unlikely that the NCDENR will undertake remedial activities at
the subject property. However, in the unlikely event that they do decide to undertake
remedial activities, they have stated that they will highly consider the future operations at the
subject property and will minimize any disruptions to daily operations. Therefore, given the
remote possibility that the NCDENR ever decides pursue the closure of the Old Store LUST
Incident, it is Bureau Veritas' opinion that they will likely choose monitored natural
attenuation. This type of remedial method is considered passive and would cause minimal to
no disruption to the daily operations of the future Walgreen Store.
In lieu of the installation of the subsurface only portion of a remedial system, Bureau Veritas
recommends that three shallow, permanent groundwater monitoring wells be installed in the area of
the Old Store LUST incident. Groundwater samples should be collected from these wells on a
periodic basis and analyzed for select parameters. These wells would be used to monitor the
impacted groundwater and to evaluate the natural attenuation of the impacted groundwater. Note that
as part of the NCDENR requirements for this site, existing well MW-2 would likely have to be
decommissioned and replaced. Therefore, the replacement of monitoring well MW-2 would be
included as one of the three recommended monitoring wells.
SAWalgreensPrgeas1C51181Piiot Stud 0.1027512h3.28febOT.d e
6 Project Number 99006-006118

Sodium Persuifate Pilot Study Report
Proposed Wa'green Store #10275
The following is also recommended by Bureau Veritas:
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
• A Notice of Residual Petroleum (i.e., deed restriction) will have to be placed on groundwater
use and soil contamination for the subject property (this recommendation was made
previously in other reports), and
• Although not required, it is highly recommended that this Pilot Study report be submitted to
Ms. Ghiold of the NCDENR's UST Section Trust Fund Branch, Federal -Lead Program, for
their records.
Also note that the Pilot Study injection points (including PMW-1) must be decommissioned and the
results of the Pilot Study must be submitted to the NCDENR's DWQ, APS, U1C Program in order to
officially close out the Permit Application.
SAWaigreels'.Pto;eas5D61181Plo', sruy110275-p,3.2efea07.doc
7 Project Number 99005-00611 B

1993 USGS Topographic Map
N
Proposed tiValgreen Store #I0275
SEC of Beanies Ford Road and
Sunset Road
Quadrangle: Derita,
North Carolina
Figure
1
Site Vicinity
Viv
*
Charlotte, North Carolina
Map
Client: Sunset Southstar, LLC
Scale: I:24,000
Project No: 99006-006118

M
LEGEND
SOIL BORING
SURFACE SAMPLE
SOIL STOCKPILE SAMPLE
MONITORING WELL
---- SUBJECT PROPERTY
BOUNDARY
(5040 BEATTIES FORD
ROAD)
APPROXIMATE SCALE
3 0 3 6 90
Figure 2
Site Map Showing Recognized Environmental
Conditions and Pilot Study Location
SS-
Ogg
SS-6, ...•�}
5B/t9.
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S Proposed Wa1 en Snore #10275
TSEC ofBeattiea Ford Road and Sunset Road
Charlotte, North Carolina
Project) . 99006.0061IR
Fthracry a.aom

TABLE 1
SUMMMARY OF GROUNDWATER ANALYTICAL RESULTS FOR PILOT STUDY MONITORING WELL PMW-1
Proposed Waigreels Store tL)0275
SEC of Beatties Ford Road nod Sunset Road
Charlotte, North Grolius
Bureau Verdes Project No.: 99006.006118
PARAMETERS/METHOD
NORTH CAROLINA
2LGROUNDWATER
QUALITY
ST( VjVDQAItDS
NORTD CACA.ROLINA
GROSS
CONTAMINATION
LEVELS (GCLM)
D
t.,
a. m
i
POST -INJECTION
24 ilr
1 Week
2 Wte&
1 Month
2 Month
SampleCalketio.Data
-
-
10/24/2006
10/25/2006
10/30/2006
11/10/2006
11/21/2006
12/27/2006
WWI /8260
-
-
-
-
-
-
•
Acetone
0.7
700
3.90
2.60
290
3.10
6.10
4.40
Benzene
0.001
5
:::14113:•:
:::: ]9:or:•
-:•::20,[l::::::::Y9J0.:.:•
•::,:tt0:::•:::•:•isis.:•:-
2-Butnnone(MEX)
0.17
L70
3.90
4,60
4.60
5-50
6.30
4.90
n-Batylbenttrm
0.07
6.9
0.037
ND
ND
0.012
ND
0.016
Cblaroethane
2.6
no standard established
ND
ND
ND
ND
ND
0,002
2-Chltuotoiueae
0.14
oo slaadard established
ND
ND
N D
ND
}..:::0X3-:::::::::4.S3:•}:•
ND
0,19
1,2•Dibsomorthaie(EDB)
00000004
005
0.59?:;'I74P
::::II.•>:::0:52:::•:'.::Pt.:
12-Dithloroethane
0,00038
0.38
•:::2,20:•:::
, ::•,:,4D:::{,'-::.:2;10::::::::::1:$0:::::
•::•:2.70-:•:
:: •::3.5Q::::•
1,2•Dithionnxopanz
0.00056
0.56
ND
ND
ND
ND
ND
0.004
Diisopeopyl ether •
0.07
70
0.60
0.62
0.58
0.78
0.68
0.81
Ethylbenzene
0.55
84.5
3.40
3.30
1.80
2.30
2.10
3.0
Isopropyl benzene
0.07
25
0.17
0.14
0.065
0.090
ND
0.13
p•lsopropyltohuee
no standard established
no standard established
0.053
ND
ND
ND
ND
ND
Methyl -tan -butyl ether
0.20
200
0.084
0.060
0.058
0.066
ND
0.077
_
Nnplrtfwlm.
0.021
- 15.5
0.08
0.25
0.24
021
0-66
0.26
n-Prnpylbesaenn
0.07
30
037
034
0.14
0.20
ND
0.17
Toluene
1.0
257.5
31.0
34.0
31.0
30.0
23.0
24.0
L,2,4-Trimethylbenzatc
6.35
283
1.90
1.80
0.78
1.10
0.87
1.50
I.35-Trimctylbcnzene
. 0.35
25
0.50
0.47
020
0.26
0.20
0.32
Xyienes (mixed)
0.53
87.5
I5.0
15.0
8.2
9.9
9.6
12.0
Other VOCs
sec individual compounds
see individual compounds
ND
ND
ND
ND
ND
ND
Total VOCs
-
80.8
85.3
73.1
75.8
68.5
723
Sulfate/ 375.4
no standard established
no standard established
ND
ND
ND
NA
ND
ND
Metals / 3030C
-
-
-
•
-
-
•
-
Arsesis
0.01
no standard established
ND
ND
ND
NA
ND
ND
Cadmium
0.005
no standard established
ND
ND
ND
NA
ND
ND
ChrtaMuna
0.05
50
0,DD8
ND
ND
. NA
ND
ND
Iron
03
no standmd established_
SA036
0.40
NA -
1.10
0.68
M .
0.0011
no standard established
ND
ND
0,00922
NA
ND
ND
Sodium
no standard csmblisbod
no sren6ard established
5.60
5.10
4.50 _
NA
430
4.00
Lead
D.015
13
ND
ND
ND
NA
ND
ND
Copper
1
no standard established
0.019
ND
ND
NA
ND
ND
Silver
0.018
18
ND
ND
ND
NA
ND
ND
Pkld Measurements /Parameters a
-
-
-
-
Sodium Petsnlfa t PPrsem'1)
no standard established
no standard established
no
yes
yes
yes
no
DO
Depth to Orotundwtater (ft bps)
nor applicable
not spplisabie
16.3
15,7
163
16.5
nos measured
15.7
pH (ttanderi touts)
6.5 - B.5
no s ondan/ established
6.1
63
6.5
NA
63
62
Osidztion-Reduraioa Potential (mV)
no sea dm . established
no standard established
277
246
228
NA
156
190
Temperance (eC)
no standard established
no standard established
16.0
18.I
20.5
NA
15.9
16.1
Dissolved Oxygen
no standard established
no aandmd established
8.5
8.9
7.7
NA
B.0
8,0
Conductivity (ms/00)
no nandard estab&sbed
no standard established
D.0
0,0
0.0
NA
0.0 _
0.0
Notes:
The not Study igieedea +vas conducted on Oembsr 24, 2006.
All results are is legl, unless otherwise noted.
(1) The depth to groundwater lined was that measured priertn well purging and the Sell pama set= listed were than measured after stabilization of readings was obtained.
(2) Results based on the use ea Starch Iodide Seld test lot
The above samples were collected by Bureau Veotu and were analyzed by Pace Analytical.
Bold cell equals concea scion above the CWQS
Boa/ and shaded cell equals concentration above **cra-
ft hos.- feet below. Pzound engem
ors/©• mDRsientens pm- coMenetet
mV • milliyottc
ND - not detected at err above the method detection Bath
NS want sampled
NA • not =mired
VOCsn volatile organic compounds

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
SEC of Beatlies Ford and Sunset Roads
Charlotte, North Carolina
APPENDIX A
INJECTION PERMIT
S:1Walgreens1Pro e=s10611 BSPisot sndy1.10275-ph32Bfei07.doc
Project Number 99Q06-006118

3380 Chastain Meadows Parkway
Suite 300 Air C1a�/ ton
Kennesaw, GA 30144
...TTT
770.499.7500 GROUP SERVICES
Fax [phone]
August 17, 2006
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1638 Mall Service Center
Raleigh, NC 27699-1636
Clayton Project No. 99006-00611 B
Subject: Submittal of "Application for Permit to Construct anchor Use a
Well(s) for Injection"
Old Store LUST Incident #8789
5040 Beatties Ford Road
Site of Proposed,Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road, Charlotte, North Carolina
Dear UIC Program Official:
Enclosed please find two copies of an "Application for Permit to Construct and/or Use a
Well(s) for Injection' for the above referenced site. The attached application for permit
includes the implementation of a field pilot study to evaluate the use of sodium persulfate
as a remedial method. Clayton will retain the services of Redox Tech, LLC of Cary,
North Carolina to conduct the pilot study and inject the sodium persulfate. Redox Tech
has many years of experience in the chemical oxidation and injection business.
Based on information provided by Ms. Sharon Ghiold of NCDENR, there is currently no
responsible party (RP) for the referenced Old Store LUST Incident, since the original
owner of the former USTs has long been deceased and his estate dissolved. Therefore,
the Old Store LUST Incident site is currently being overseen by NCDENR's UST Section
Trust Fund Branch, Federal -Lead Program. The site has been classified as a "high tisk°
due to on -site groundwater contamination exceeding NCDENR standards and the
presence of off -site receptors within 1,000 feet of the property line. However, according
to Ms. Ghiold, the UST Section has no immediate plans for additional work at this site,
since the nearby receptors are not impacted by the LUST incident and there are limited
funds available for such activities.
According to Ms. Ghiold, the UST Section will not require the current property owner
(which is Sunset Southstar, LLC c/o Tribak Properties (Sunset Southstar)) to conduct a
soil and groundwater investigation' and/or remediation in order to develop the subject
property or after development, even though soil and groundwater concentrations are
present above applicable standards. Furthermore, Ms. Ghiold stated that the current
t As part of the real estate transaction for this property, a Limited Subsurface Investigation was conducted
by Clayton, the results of which are presented in the application for permit.
v+nvw.claytortgrp.com
Environmental Services • Occupational Heahh and Safety • Laboratory Services

Submittal of Application for UIC Permit
Old Store LUST Incident
Charlotte, NC
Clayton
property owner will not become the RP and would not be made responsible for any
monitoring or remediatlon costs. However, Ms. Ghiold also indicated that site closure
could not be granted as long as concentrations remain above, the applicable standards
and there remain of site receptors, and that any activities related to achieving closure
could be undertaken and financed by the existing property owner on a voluntary basis.
Sunset Southstar will be redeveloping the subject property and does not plan on
obtaining closure of the Old Store LUST Incident at this time. However, in good faith and
to minimize the possibility of significant disturbance to the subject property after it has
been redeveloped, Sunset Southstar has elected to install the subsurface portion only of
a full-scale remediation system, which could be activated in the future (if needed) to
address impacted soil and groundwater associated with the Old Store LUST Incident.
The subsurface portion (i.e., wells and piping network) of the full-scale system will be
installed in conjunction with site redevelopment activities and will be covered over by
landscaped areas and pavement. A piping manifold will be located above ground for
future access (if needed) to the subsurface system. The subsurface system could be
activated at a later date if so desired by either NCDENR or the subject property owner.
The results of the sodium persulfate pilot study will be used to design the subsurface
portion of the full-scale system.
Clayton, on behalf of Sunset Southstar, would greatlY appreciate your quick approval of
this application so that the redevelopment of this property can proceed without delay. In
the interim, if you have questions, please contact me at 919 960-6289.
Sincerely,
Clayton Group Services, Inc.
A Bureau Vedas Company
David Wagner
Senior Consultant
Atlanta Regional Office
cc: Mr. Randy Nance, Sunset Southstar
attachmanie
Page 2

State of North Carolina
Department of Environment and Natural Resources
Division of Water Quality
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells— In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
• Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated groundwater.
• Submit TWO copies of the completed application and all attachments to the address on the last page of this form.
• Any changes made to this form will result in the application package being returned.
Application Number (to be completed by DWQ):
L GENERAL INFORMATION:
3ua*ft f1w716'fp-
I. Applicant's Name (generally the responsible ): etnowr8LLC cdo Tribek Properties
2. SigningOfficial'sName: -S En -1. 4'* .Ale: ceYibe
3. Mailing address of applicant: 200 Providence'Road. Suite 106
City: Charlotte State: NC ZIp: 28207
Telephone number. 704-333-8484 Fax number: 704-333-.8485
4. Property Owner's Name (if different from Applicant): 5,41g e'
5. Property Owner's mailing address:
City: State: Zip:
6. Name and address of contact person who can answer questions about the proposed injection project:
Name: David Wagner Title: Senior Consultant
Company: Clayton Group Services
Address: 297 Highview Drive
City: Chapel Hill State: NC Zip; 27517
Telephone number 919 960 6289 Fax number: 919 960 6289
Email Address:davld.wagnertus.bureauveritas.com
II. PERMIT INFORMATION:
1. Project is: Z New O Modification of existing permit 0 Renewal of existing permit without modification
2. If this application is being submitted for renewal or modification to an existing permit, provide:
existing permit number and the issuance dale
For renewal without modifications, Fill out sections I & II only, sign the certification on the last page of this
form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner).
I.i1C-51/5T ver. 12-05 Page 1 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJE CTION
Type 51 Wells — in Situ Groundwater Remediation / Type ST Wells — Tracer injection
Ill. INCIDENT & FACILITY DATA
A. FACILJTY INFORMATION
1. Facility name: Proposed Waigreen Store #10275, SEC of Beattles Ford Road and Sunset Road
2. Complete physical address of the facility: 504QBeatties Ford Road
City: Charlotte
County: Mecklenburg State: NC Zip:28216
B. INCIDENT DESCRIPTION
I. Describe the source of the contamination.
From approximately the mid 1950s up t7 approximately 1990, the 5040 Beatties Ford Road property was a
gasoline retail station. During UST removal in 1990. soil and groundwater contamination was confirmed
Additional LISTS were discovered during a road widening project in February 2000. Some of the Impacted soils
were excavated and disposed of off -site. However, petroleum -related compounds remain in the soil and
groundwater at concentrations exceeding NCDENR standards.
2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g.,
gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticideslherbicides, etc):
gasoline -related compounds - See attached tables for most recent results.
3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)?
0 Yes If yes, list maximum measured separate phase thickness: feet
l No If no, list maximum concentration of total VOCs observed at site: 2,323,000 (see SB-7 soil) ppb
4. Agency managing the contamination incident:
® UST Section
❑DWQ Aquifer Protection Section
DHazardous Waste Section
❑ Superfund Section (including REC Program and DSCA sites)
0 Solid Waste Section
I i ogler; Federal Trust Fund program
5. Incident number or other site number assigned by the agency managing the contamination incident:
8789
C. PERMITS
List all permits or construction approvals that have been issued for the facility or incident, including those not
directly related to the proposed injection operation:
1. Hazardous Waste Management program permits under RCRA:
2. DWQ Non -Discharge or NPDES permits:
3. County or DEH subsurface wastewater disposal permits:
4. Other environmental permits required by state or federal law:
UIC-5U5T ver. 12-05 Page 2 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 51 Wells —In Situ Groundwater Remediation / Type ST Wells— Tracer Injection
W. INJECTION DATA
A. INJECTION FLUID DATA
1. List all proposed injectants.
NOTE: Any substance to be injected as a tracer or to promote in situ remediation mast be reviewed by the
Occupational and Environmental Epidemiology Section {PEES) of the Division of Public Health, Department of
Health and Human Services. Review the list gfapproved inrjectunrs or contact the UIC Program to determine if
the injeetants you are proposing have been reviewed by GEES
Injectant:sodium persulfate
Concentration at point ofinjection:20 percent by weight
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
Injectant
Concentration at point of injection:
2. Source of fluids used to dilute or chase the injectants listed above:
®None
❑ Municipal water supply
0 Groundwater from private well or any well within 'A mile of injection site
❑ Air
❑ Other:
3. if groundwater from a private well or any well within'/4 mile of injection site is to be used as the fluid source,
supply the following information:
a. Location/JD number of source well: not applicable
b. Depth of source:
c. Formation:
d. Rock/Sediment type:
e. In Attachment B, provide a current, complete chemical analysis of the water from the source well, including
analyses for all contaminants suspected or historically recognized in soil or groundwater on the site.
NOTE: If contaminated groundwater is to be used as the dilution or chase fluic4 this is not the proper permit
application form_ You must apply for a Nosed -loop groundwater remediation permit using applirntlnn Prar
GWRS.
UIC-5I/5T ver.12-05 Page 3 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJE CTION
Type SI Wells — In Situ Groundwater Rem edietion / Type 5T Wells — Tracer Injection
B. PROPOSED OPERA'3TNO PARAMEfERS
1. Duration of Injection:
Maximum number of separate injection events: one
Expected duration of each injection event: Approx 2 - 9 hrs
Expected duration between events (if more than one event):
. 2. Injection rate per well: Aoarox 2 - 10 gallons per minute (gpm)
3. Total Injection volume: 1,000 gallons per day (gpd); gallons per event (if separate events)
4. Injection pressure: 50 - 125 pounds/square inch (psi)
5. Temperature at point of injection: ambient °F
6. Briefly describe how the above parameters will be measured and controlled:
via valves, regulators, and gauges
7. Estimated hydraulic capacity of the well: less than 5
gpm
C. INIFCTION WPT,I, CONSTRUCTION DATA
1. injection will be via:
O Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of
your knowledge.
® Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as
proposed construction specifications.
2. Well Drilling Contractor's Name: Redox Tech, LLC
NC Well Contractor Certification number. 3380
3_ Date to be constructed: daft /fp,s.T Yb'tu1ber of borings: 3
Approximate depth, of each boring (feet): 19, 24, & 30
4. Screened interval/Injection interval of injection wells:
Depth: 14 to 30 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth).
5. Well casing (N/A if injection is through direct push rods):
Type: l7 PVC D Stainless steel 0 Other:
Casing depth: 14 to 25 ft,
6. Grout (N/A if injection is through direct push rods):
Type: RI Cement ® Bentonite 0 Other:_
Grout depth: 12 to 23 ft.
UIC-5I/ST ver. 12-05 Page 4 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 51 Wells — In Situ Groundwater Remediation 1 Type 51' Wells — Tracer injection
V. ATTACHMENTS
Provide the following items as attachments with the given headings:
A. HYDROGEOLOGIC DESCJIPTION
Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the
known or projected depth of contamination. The hydrogeologic description shall include:
(1) the regional geologic setting;
(2) significant changes in lithology;
(3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a
description oldie test(s) used to determine these parameters; and
(4) the depth to the mean seasonal high water table.
NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the
public welfare or safeguarding cf the environment be prepared by a licensed geologist or subordinate under his or her
direction. G.S. 89E-13 requires that alidrawings, reports, or documents involving geologic work which shall have been
prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or
her.
B. INJECTION FLUID COMPOSITION
Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety
Data Sheet (MSDS) for each injectant. If a private well or a well within 'A mile of the injection site is used as the source
well, include chemical analysis of source fluid here.
C. INJECTION RATIONALE
Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including:
(I) goals of the injection project;
(2) a description of the reactions between the injectants and tJie contaminants present including specific breakdown
products or intermediate compounds that may be formed by the injection; and
(3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change
(biological, chemical or physical) in the subsurface.
D. INIECTION PROCEDURF. AND EQI IHPMFNT
Provide a detailed description of all planned activities related to the proposed injection including but not limited to:
(1) construction plans and materials;
(2) operation procedures;
(3) a detailed diagram of the surface and subsurface portions of the system; and
(4) a planned injection schedule.
E. MON1TORING PLAN
Provide a plan for monitoring the results of the injection, including:
(1) a list of existing and proposed monitoring welts to be used;
(2) a list of monitoring parameters and analytical methods to be used; and
(3) a schedule for sampling to monitor the proposed injection.
NOTE: The selected monitoring wells must be located so as to detect any movement of iiectlon fluids, process by-
products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target
contaminants as well as secondary or intermediate contaminants which may result from the injection and other
parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved arygen, and
other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated
reactions and rate of transport of the injectants and contaminants.
UIC-51/5T vet. 12-B5 Page 5 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type SI Wells— In Situ Groundwater Remediation / Type ST Wells — Tracer Injection
F. WELL DATA
Provide a tabulation of data on all existing or abandoned wells within '/. mile of the injection wells) which penetrate the
proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells.
Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open
borehole depth interval, and well construction or abandonment record, if available.
G. MAPS
Attach the following scaled, site -specific maps:
(1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1.24,000 and
showing the location of the proposed injection site.
(2) Site map including;
a_ all property boundaries;
b. all buildings within the property boundary;
c. existing and proposed injection wells or well field(s)
d. any existing sources of potential or known groundwater contamination, including waste storage,
treatment or disposal systems within '/. mile of the injection well or well system;
e. all surface water bodies within '/. mile of the injection well or well system; and
f. all existing or abandoned wells within 'A mile of the injection well(s) which penetrate the proposed
injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection
wells.
(3) Potentionietric surface map(s) including.
a. direction of groundwater movement
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(4) Contaminant plume map(s) including:
a. the horizontal extent of the contaminant plume, including isoconcentration lines
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(5) Cross-section(s) to the known or projected depth of contamination, includIng:
a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines
b_ major changes in lithology
UIC-51/5T ver. 12-05 Page 6 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR tN:TE CTION
Type 51 Wells — In Situ Groundwater Remediation / Type ST Wells — Tracer Injection
VL CERTIFICA 70N
I, ,S'W j-��: �G�ti.• . , hereby certify under penalty of law that
I have personally examined and am familiar with the information submitted in this document and all attachments
thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information,
I believe that the information is true, accurate and complete. I am aware that there are significant penalties,
including the possibility of fines and imprisonment, for submitting false information. I agree to construct,
operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in
accordance with the approved specifications and conditions of the Permit.
Signature. OC4fr C 4 Date• l i 166
Title. 121.wLlr[r
If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the
above agent.
YII. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant)
("Owner" means any person who holds the fee or other property rights in the well being constructed ,4 well is
real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of
contrary agreement in writing.)
, as owner of the property on which the
injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each
injection well as outlined in this application and agree that it shall be the responsibility oftbe applicant to ensure
that the injection well(s) conform to the Well Construction Standards (Title 1 5A NCAC 2C .0200)
Signature:
Title:
hoc
/1¢w�
Date. 1a Vhi
Submit TWO copies of the completed application package, including all attachments, to:
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone [phone]
UIC-5V5T ver. 12-05 Page 7 of 7

A FACHMENTS — SECTION V
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)
FOR INJECTION
Type aI Wells — In Situ Groundwater Remediation
Old Store LUST Incident (#8789)
5040 Beatties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, North Carolina
August 17, 2006
Clayton Project Number 99006-006118
A. Hydrogeologic Description
The subject property is located in the Southern Piedmont Physiographic Region of North
Carolina. The subject property is underlain by the Charlotte Belt, which is generally
composed of metamorphic and intrusive rock from the late -Proterozoic to mid -Paleozoic
age. Depth to bedrock is greater than 30 ft bgs. The general area is characterized by
broad, gently rolling interstream areas with steeper slopes along drainage ways. The
Catawba River and its tributaries drain three -fourths of Mecklenburg County and the
Rocky River and its tributaries drain the remaining eastern portion. The closest water
body appears to be McIntyre Creek, located approximately 5,000 feet to the north and
several small, unnamed ponds located approximately 2,000 feet to the southwest.
Topographic gradient around the subject property trends to the south to southwest, while
the subject property is generally flat. Elevations at and around the subject property range
from 820 to 830 ft above mean sea level (USGS Topographic Map Derita, NC, 1993).
According to files obtained from NCDENR, approximately 15 private water wells are
located within a 1,000-foot radius of the subject property (see Section F for further
details).
Based on borings drilled at the subject property by Clayton, the native soil at the subject
property generally consists of a dark brown to light brown clayey silt to silty clay (see
attached boring locations and boring logs). The native soil in the immediate vicinity of
the Old Store LUST incident consists mostly of clayey silt. Fill was encountered in the
area of the former Old Store USTs to depths as great as 17 ft bgs. As shown on the logs,
this fill also consists of a clayey silt. In addition, fill in the form of fine to coarse slag,
covers the majority of the site. No significant changes in lithology were observed.
The depth to groundwater measured in the vicinity of the Old Store LUST incident (at
boring locations SB-1, SB-2, SB-4, SB-6, and MW-2) ranged from 17.7 ft bgs to 18.7 ft
bgs. Based on the depth to water measurements and relative elevations measured by
Clayton, the apparent groundwater flow direction in the area of the Old Store LUST

Attachment 5 -- Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Wa!green Store 410275
Charlotte, NC
WA yd
incident is to the southwest This apparent direction of groundwater flow`�,���� i��.*"'
with that measured in the past (circa January 1997) during earlier investigatioo nitt
Old Store LUST incident (see attached figures).
The hydraulic conductivity (K) and the specific yield (Sy) of the saturated zone in the
vicinity of the Old Store Lust incident was estimated from published literature at I0-2
gal/day/ft. (Freeze and Cherry, 1979) and 10-15 percent (Driscoll, 1989), respectively.
The transmissivity (T) of the saturated zone in the vicinity of the Old Store Lust incident
was estimated using the referenced K value and a saturated zone thickness (b) of 10 ft.
Using the formula: T = Kb, the estimated value of T is I0-1 gal/day/ft.
B. Injection Fluid Composition
An MSDS sheet for sodium persulfate is attached.
The pilot test will encompass an area of approximately 115 square feet, targeting depths
from 14 to 30 feet bgs (unsaturated and saturated soils). Using a total oxidant demand
(TOD) value of 9.9g/kg, approximately 1,705 pounds of sodium persu[fate will be
required to treat the target zone. The TOD value is the highest reported value from
laboratory testing conducted on site -specific soil and groundwater samples. The sodium
persulfate will be mixed at a 20% solution by weight, resulting in approximately 1,000
gallons of solution that will be injected.
Sodium hydroxide will be added to the solution in order to catalyze the persulfate. A
total of approximately 20 gallons of a 25 percent by weight solution of sodium hydroxide
will be used.
C. Injection Rationale
Sodium persulfate is being injected into the subsurface as part of a pilot study. The
objective of the pilot study is to evaluate the efficacy of using sodium persulfate to
remediate impacted soil and groundwater and to obtain necessary parameters for the
design of a full-scale system including well construction, well spacing, injection volumes,
loading rates, etc. Sodium persulfate was selected due to its proven ability to oxidize the
types of gasoline -related contaminates detected at the site including benzene, 1,2-
Dibromoethane (EDB), and 1,2-Dichloroethane (DCA) (see attached tables).
In recent years, sodium persulfate has been recognized as a very effective oxidant in
treating volatile organic compounds (VOCs). Some of the advantages of sodium
persulfate over other treatment alternatives are provided below:
1) Safer to handle compared to other widely used oxidants.
2) High solubility in water compared to potassium permanganate. Comparable
solubility to hydrogen peroxide, but much safer at higher concentrations. This
means more oxidant per gallon of solution injected.
Page 2

Attac3une ts—SectionV
Application for Injection Pilot Study
Oid Store LUST Incident
Proposed Walgreen Store 410275
Charlotte, NC
3) Is effective over a wide range of pH conditions and is less affectekty
groundwater geochemistry than Fenton's chemistry.
4) When steam -catalyzed, persulfate is the most robust (works on most n �+ t toe
organic contaminants) oxidant on the market. When catalyzed by iron or acid, it
has a higher oxidation potential than permanganate, and comparable to Fenton's
chemistry.
5) The solution is colorless and odorless.
6) The sulfate produced during the consumption of persulfate inhibits the conversion
of dichloroethene (DCE) to vinyl chloride (VC). The sulfate can also serve as an
electron acceptor for anaerobic•oxidation of petroleum compounds_
7) Works on mixtures of petroleum and chlorinated solvents. Permanganate
typically is used for chlorinated alkenes. There is safety issues associated with
aggressive Fenton's chemistry on petroleum.
The persulfate anion is the most powerful oxidant of the peroxygen family of compounds.
When given energy (i.e., heat, light, etc.), the persulfate forms sulfate radicals which in
turn have lots of energy and can easily oxidize many compounds including benzene, EDB
and DCA, which are present at the site. Under alkaline conditions, the reaction of
persulfate follows this equation:
S,082OH' 4HSO4 +S0ti2+1/202
The chemical oxidation process converts hazardous contaminants to non -hazardous or
less toxic compounds that are more stable, less mobile, and/or inert. The end products of
the oxidation of benzene, EDB, and DCA are water, CO2, • chloride, bromide, and sulfate
ions. Asa side benefit to the reaction, aerobic biodegradation of contaminants can benefit
from the presence of 02 released during the persulfate decomposition. Also, the sulfate
that results from the reaction of persulfate will be an electron acceptor via sulfate
reduction. That is, the sulfate will be consumed for bioconversion of petroleum
compounds (i.e., benzene) after the persulfate chemical oxidation mechanism ceases.
D. Injection Procedure and Equipment
The scope of the pilot test will involve the installation of one nested set of semi-
permanent injection points targeting both soil and groundwater at a depth of 14 to 30 feet
bgs, and the installation of a single monitoring well located approximately 6 feet from the
injection points. The injection points will be used to deliver a base activated sodium
persulfate solution. The purpose of using semi -permanent injection points is to mimic
and test the proposed approach for use in a full-scale system. The pilot study will be
performed within native soils (as opposed to the former tank pit fill areas) at the
approximate location shown on the attached figures. Note that the existing building will
need to be demolished prior to the pilot study. However, the exact location where the
pilot study wells will be field determined.
Assuming a radius of influence of 6 feet, the pilot test will encompass an area of
approximately 115 square feet. At a distance of 6 feet from the injection wells, a single
Page 3

Attachments —Section V
Application for Injection Pilot Study
Old Stave LUST Incident
Proposed Walgreen Store *10275
Charlotte, NC
��. LAR "
e-3c:4154" 4r's
Irs
OF
iffis
al.t 5
iNAG-• `'
•
but 00
3/-inch diameter monitoring well will be installed with a screened interval that extends
across the saturated target zone, from approximately 20 to 30 feet bgs. This monitoring
well will be used to assess the effects of sodium persulfate on contaminant concentrations
detected in the groundwater. -The- nested set of injection wells will target both the
unsaturated and saturated soils. Screens will be positioned from approximately 14 to 19,
20 to 24, and 25 to 30 feet bgs. The purpose of nested injection points is to ensure that
proper vertical distribution of sodium persulfate solution occurs. The nested injection
points and the monitoring well will be installed with a Geoprobe® direct push drill rig
and completed as stickups with no protective casing. Each injection point and the
monitoring well will be constructed of % inch diameter PVC screens and risers. The
injection point will be constructed with a sand pack around the screened interval, and
sealed with a foot of granular bentonite and a cement grout to surface (see attached
schematic).
Based on an area of approximately 115 square feet, a target interval from 14 to 30 feet
bgs (unsaturated and saturated soils), and a total oxidant demand (TOD) value of 9.9g/kg,
approximately 1,705 pounds of sodium persulfate will be required to treat the target zone.
Mixed at- a 20% solution by weight, approximately 1,000 gallons of solution will be
injected. The TOD value of 9.9g/kg was based on the highest TOD value reported from
analysis on site -specific soil samples collected during January 2006.
The attached figure shows a schematic of the injection setup. The sodium persulfate
solution will be injected using a trailer equipped with a Sandpiper double diaphragm
pump. The Sandpiper will pump the persulfate solution from a 500-gallon mixing tank to
the injection well through a series of hoses and valves. The valves are used to shut off or
restrict flow if required. The Sandpiper pump is operated with an air compressor and
controlled with an air regulator, which is mounted to the trailer. This allows the field
crew to control the injection pressure. The solution is injected at approximately 2 to 10
gpm, utilizing an injection pressure that may range from approximately 50 to 125 psi
(this will be field determined). The mixing tank is graduated and therefore flow rates can
be calculated by measuring the volume of solution over time, if required. The 1,000
gallons of solution will likely be equally distributed amongst the three injection wells and
based on the injection rate (2 —10 gpm, to be field determined), the injection will take up
to approximately 8 - 9 hrs to complete.
E. Monitoring Plan
Prior to injection of persulfate, an electrical conductivity probe will be used to acquire
background levels of electrical conductivity through the target zone (Le. from 14 to 30
feet bgs). This testing will be conducted at the injection location, prior to installation of
the injection wells. Once the injections have been completed, the vertical and lateral
distribution of the persulfate using the conductivity probe will be assessed. The electrical
conductivity measurements, in the presence of persulfate, will be elevated significantly
from background readings and therefore conductivity measurements vertically and
laterally will provide information on the radius of influence and the vertical distribution
of the persulfate.
Page 4

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Wa!green Store # 1027S
Charlotte, NC
In addition to electrical conductivity testing, starch iodide test kits will be used to test
groundwater within the monitoring well. The starch iodide test is a quick and reliable
visual field technique to test for the presence of persulfate. Upon contact with persulfate,
the starch iodide solution will turn bright blue.
Also prior to the injection, a groundwater sample will be collected from the newly
installed monitoring well for analysis of VOCs (using USEPA Method 8260 and a North
Carolina certified Iaboratory); sulfate, and dissolved iron. In addition field parameters
including depth to groundwater, pH, oxidation-reduction potential (ORP), temperature,
dissolved oxygen (DO), and conductivity will also be measured. - Post -injection
groundwater monitoring will be conducted approximately 24 hours and three weeks after
the injection is complete. During the 24-hr post -injection monitoring event, the
groundwater will be analyzed for sulfate, dissolved iron, depth to groundwater, pH, ORP,
temperature, DO, conductivity, and persulfate (using a starch iodide test kit). Since the
persulfate reaction is generally relatively slow it is not necessary to analyze the 24 hr
post -injection sample for VOCs, since it is likely that little to no reduction in
concentrations will have occurred by that time. The three week post -injection
groundwater sample will be analyzed for the same parameters as the 24-hr sample plus
VOCs.
F. Well Data
See attached information regarding wells located within the general area of the Old Store
LUST incident. As noted there are approximately 15 private water wells within
approximately 1,000 — 1,500 feet of the subject property. It is our understanding that
none of these private wells have been reported to be impacted by petroleum -related
compounds, and none of these private wells are located within or adjacent to the Old
Store LUST incident groundwater plume. In addition, the vast majority of these wells are
upgradient to crossgradient relative to the subject property. Specific information other
than what is attached regarding these private wells is not currently available.
One monitoring well, designated as MW-2, currently exists on the subject property. 'It is
believed that this well was installed as part of the initial investigation of the LUST
incident back in the early 1990's. It is constructed of 1-inch PVC and is approximately
l 9.5 feet deep. The depth of the screened interval is unknown. During January 2006, the
depth to water in this well was measured at 18.6 feet below the top of the casing, with
approximately one foot of water in the well. Apparently, this well was not installed deep
enough to adequately monitor the water table, therefore its use as a reliable and adequate
monitoring point is questionable. 4. yk CRR0 .
G. Maps 4 .3%.4,
See attached.
r
Page 5
1998
3 Q GeOLOG�.�'� 4 ti

Attachments — Section V
Application for injection Pilot Study
Old Store LUST Incident
Proposcd Walgry n Store 410275
Charlotte, NC
SUMMARY OF SOIL AND GROUNDWATER ANALYTICAL RESULTS

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SUMMARY OF GROUNDWATERANALYTICAL RESULTS
Proposed Waimea, Slurp N10273
SEC of Beattie; Ford Road and Sunset Road
Charlotte, North Caroline
Clayton Project No.; 99006.096118
PARAMETERS1
ME
NORTH CAROLINA
11, GROUNDWATER
QUALITY
STANDARDS
(C Q
NORTH CAROLiNA
GROSS
CONTAMINATION
LEVELS (GCLa)
Ou-SlteOld Snare LUST incident (5040 Beattie, Ford Road)
OnSitt Mendel Historical
llialntasauce and Repair
Operotlaae(5040Drastic.
Ford Road)
Oo-Site Septic
System (5006and
SO40Rea Niko
r'ord Raul)
d AutomotiTe
Repair
(
Ford
513.16
Fatal y
Heating
Road)
915-17
roundel
Ghlorloaled
Solvent
GroundwaterTILOD
coetamioation
8.1 -19
SD-1
SD-1
51i-4
58-6
SD.-7
SD-11
MW-2
913•10
SH-IT
S13.12
S13-13
50-14
VOCa 15260
-
-
-
-
-
-
-
-
-
-
-
Benzene
0.001
5
;::::M::`;.
•:•10..; :
0.0i8
; 11k
1.3
ND
3,9
ND
ND
ND
ND
ND
0.14
ND
ND
n•Dutylbooreus
0.07
6.9
ND
0.054
0.016
ND
0.014
ND
0.1i
ND
ND
ND
ND
ND
ND
ND
ND
tat-Dnlylbeezeae
0.07
15
ND
0.21
ND
ND
ND
ND
0.38
ND
ND
ND
ND
ND
ND
__ND
ND
Chloroform
9.00000019
0.19
ND
ND
0.014
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NT)
1,2•Dli rora tbaati(EDH)
0.0000004
0.05
•-8;.n,6
'=0t 3:�
ND
:::` [;D::,
ND
ND
:41'1
ND
ND
ND
ND_
ND
ND_
ND
ND
1,2-Dtchlaraedtane
0.00038
0.98
,t;: rj,:
41;r;?:
ND
,:'.3;1t:;::.
ND
ND
0,13
ND
ND
ND
ND
ND
ND
ND
ND
Dlisagmgtyl ether
0.07
70 _
12
0.27
ND
"0.%
ND
ND
ND
ND
ND
ND
ND
ND
0.012
ND
ND
E00rlbautae
0.029
29
23
2.9
0.019
2.5
3.0
ND
3.4
ND
N1)
ND
ND
ND
ND
ND
ND
Isopropyl benzene
0,07
23
0.10
slat]
0.029
01141
0.076
ND
0.20
0.002
ND
ND -
ND
ND
0.018
ND
ND
p-laoperpylb ltlee
po standard established
no standard establlehed
ND
ND
0.011
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
McUOdtaeChloride
0.003
3
ND
ND
ND
ND
ND
ND
0.22
ND
ND
ND
ND
ND
ND
ND
ND
Meth l-test-but letter
0.20
200
ND
ND
ND
ND
0,05
ND
ND
ND
ND
ND
ND
ND
1.7;
ND
'ND
Naphthalene
0.021
15.5
033
0.25
0.018
0.55
053
ND
0.24
ND
ND
ND .
ND
ND
0.028
0.002
Tor
u•Pri pyIb nzeno
0.07
30
0.11
0.18
0,046
0.18
0.14
ND
0.41
ND
ND
ND
ND
NO
ND
ND
ND
Styr ten
0.0001
100
ND
ND
ND
ND
0.012
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Toluene
1.0
257.5
10
33.
0.064
28
9.1
ND
13
ND
ND
ND
ND
ND
ND
ND
ND
1,2,4-Trimelhy1bmzene
0.35
28.5
13
1.5
0.20
1.1
1.3
ND
2.7
ND
ND
ND
ND
NO
ND
ND
ND
1,3,5-Trimcth)dbtnnna
0.35
25
0.21
0.34
0.15
0.24
0,17
ND
3.0
ND
ND
ND
ND
ND
ND
ND
ND
Xylmes (sauced)
0.33
87.5
11
13
0.22
11
13
ND
17
ND
ND
ND
ND
ND
0.014
ND
ND
OlberVOCS
emtndrwidtalcompamds
eeeludirddualmmpowda
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NI)
ND
NA
Total VON
-
•
55
74
0.8
66
29
ND
45
0.002
ND
ND
ND
ND
1.9
0.002
ND
TPH-DRO/8015
no sUmdardmrsblished
no standard established
11
14
0.58
0,}
6.0
ND
N$
02"
0.34
0.27
ND
ND
1,3
ND
Lnd131130C
0.01S
IS
NA
ND
NA
NA
NA
0.0088
_
NS
ND
NA
NA
NA
NA
NA
1{A
_NA
NA
PC& 18082
me hArldrvl carfamds
as indvlded compoonda
NA
NA
NA
NA
NA
NA
NA
ND
ND
ND
NA
NA
NA,
NA
NA
Nutn:
An resuhr are inmgll, unless otherwise noted
Die Acme .ampl . were ct4I,, led by Clayton from Amory 1.6 through lama) le, 2006 and wme analyzed by Pau Antlyllcat
Bold tell equals conoenoouon above thnCAWS
Bold and shaded cell equals eamermehcn above the OCL
ND -rat detected at or above the method dchroloo b,,,Tt
NS - not sampled due to Insufficient ample gosnlity
NA. ma anTlied
V OCs - volatile organic compounds
TPI I - PRO -total pEratalm ludroearba n- diacl rams organics
PCBs - polychlorinated biphenyl

Attachments — Section V
Application for injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store # 10275
Char' ex, NC
FIGURES AND SCHEMATIC

PORTION OF 7.5—MINUTE SERIES (TOPOGRAPHIC) MAP
UNITED STATES DEPARTMENT OF THE INTERIOR
GEOLOGICAL SURVEY
DERITA, NORTH CAROLINA
DATE: 1993
FIGURE A-1
SITE
LOCATION MAP
aYtiCel
utOO► ft.YiCii
PROPOSED WALGREEN STORE
SEC OF BEATTIES FORD AND SUNSET ROAD
CHARLOTTE, NORTH CAROUNA
CLAYTON PROJECT NO:
16--06118.00
SBBH DEVELOPMENT, LLG
c/o TRI9EK PROPERTIES, INC.

M :2
0-6 SB-
gosoo
LEGEND
4_ SOIL BORING
MONITORING WELL
-- GEOLOGIC
CROSS-SECTION
LOCATION
_. - SUBJECT PROPERTY
BOUNDARY
APPRDXIIVIATE SCALE
30 0 6 0
Figure 2
Site Map Showing Approximate
Location of Sodium Persulfate
Pilot: Study
SBA
0, o� S`19 `
Len
imam Qzftoo CranvSerrira
WOW'
IMr.r Iir2m Crw/..e.
C
SBBH Development, LLC
daTribekProperties
T
Proposed Walgreen Store#10275
TSEC of Beanies Ford Road and Sunse: Road
Charlotte, North Carolina
Pmjeq No. W106006J 19 I
11n11..
•vrvvt22006

.ram fr-•`
de' •t
i
.Sa-4
1 1 Sop;gz- N)
-•, �a�- I -10 • Foe' - —
/ ill +) td 1 i 'N ,I,:,\. ,
I \ : 5 G SB-I 1 +
errk�B-7 i"g4` �0 SB-13 ���'
\ \ .41, '.\ Y. - _,O. -12
•
\ \t‘‘ �A.f e = 54'140.1
'- �, --�--- --�
/
6F. "5-4- ept`
,.\ .
SB-17
SB-14
4- SOIL BORING
it MONITORING WELL
LEGEND
---- SUBJECT PROPERTY
BOUNDARY
--- — ESTIMATED TOTAL
—^ - ESTIMATED EXTENT OF EXTENT OF
GASOLINE -IMPACTED GASOLINE -IMPACTED
SOIL WHERE ONE OR SOIL, BASED ON FIELD
MORE VOCS EXCEED OBSERVATIONS AND
NCDENR's RESIDENTIAL ANALYTICAL RESULTS
SOIL CLEANUP LEVELS
APPROXIMATE SCALE
3
Figure 3
Estimated. Extent of
Gasoline -Impacted Soil
max=U ymn Group Serrim
Ifl.vl..a. p.5..,
C
• SBBII Development, LLC
• der Tribek Properties
T
S Proposed Walgreen Store #10275
TSEC of Beanies Ford Road and Sunset Rand
g Charlotte, North Carolina
Pmleallo. roo -A J61 r+
[u cnas
,Giver 1,2.O 4

f- _ ;__ . ;.I -�
s ▪ -�
/_i-' 'S.-B-3 ; + ` t`
.l IT, SBA ie 01$) SB 19
S SB- ' SH.1O 4019 A -`�
,ti 'r
4:55� �` �7
—r
fp
.• `
v.it0;\
1
SB-13
+SB-14
i I
LEGEND
SOIL BORING
MONITORING WELL
--- SUBJECT PROPERTY
BOUNDARY
--- ESTIMATED TOTAL
----- ESTIMATED EXTENT OF EXTENT OF
GASOLINE -IMPACTED GASOLINE -IMPACTED
GROUNDWATER GROUNDWATER, BASED
WHERE ONE OR. MORE ON FIELD OBSERVATIONS
VOCs EXCEED AND ANALYTICAL
NCDENR's GROSS RESULTS
CONTAMINATION
LEVELS
APPROXIMATE SCALE
30 d
.
ti
y �
•
Figure 4
Estimated Extent of
Gasoline -Impacted Groundwater
EMMEN magmem JOJM� Services1
c
SBBH Development, LLC
cio Tribek Properties
T
• Proposed Walgtacn Store #I 0275
TSEC of Beatties Ford Rout and Sunset Road
• Charlotte, North Cnro3-tnn
Pmjed Na.9900-406t111 1
Lau R..am
Ave.. S. 1n06

NORTFI
A
820-
SUNSET
ROAD
♦ + + •
• + + + • + + + ♦ + • + ♦ ♦ a • ♦ • + f 1 + 4 ♦ + 1 ♦ •
• , + +. • 4 4 • ♦ • • • • • • + • • ♦ f + + 4 4 + f 1
115- • +. 4 ♦ • • + • + + ♦ + 4 ♦ • ♦ ♦ 4 + • + + + + + + + + • -_ - - _ _ - — — _
+ • • + • + + • t + + • • 4 • 4 4 + .♦ • i + • + + + t — _ _ _ _ _ -
+ a + + + + + .♦ I, + • • • a • 4 a + a + + • + + • + ♦ - - - - - - - -
• -
♦ f • • • ♦ + + + ♦ + + + 4 4 • • + 4 + • +' • • • + — _----- ��••����— --
810- i•+ + + +• ♦• • • • 4 • • • + ♦ a + + ♦•
• + • + 4 + + • + . _ _ _rti.....::_r.�-:;_::
4 • + • 4 • • + + 1 4 4 • + + ♦ ♦ 4 a 4 + + 4 ♦ • r — — — — — — — _—_
•
2 103-.._•- - - • + • • t + ♦ ♦ • a --- — — — - - - - - - -
• f • ♦ • • ♦ 4 • •
• +..1_•2-.+ -7ss riffrt.
•
b ] 1 J6 zo 14 ' .ts ' ix ' ss da ` 419 52 #c 10 ' gri /2 ' 716 k 2+ >bi !rx do a Jba Lb8 i lx 1a 120 J a 128 112
LEGEND
1 BORINGTERMD1AT10N
GROUNDWATER ELEVATION
▪ (APPROXIMATE)
— ESTIMATED EXTENT OP GASOLINE -IMPACTED
GROUNDWATER WHERE ONE OR MDRE VGa
IIXCEEDNCDBNR's GROSS CONTAMINATION LEVELS
© FU.L MATERIAL
M SILTY CLAY
Q CLAYEY SR.T
CHECK BY KW
DRAWN BY GB
DATE 08-02-06
SCALE AS SHOWN
CAD NO.
PROJ NO. 99006-006118
N=
I. CROSSSEC ION SCALE:
HORIZONTAL SCALE 1• -16'
VERTICAL SCALE I"- 16'
VERTICAL EXAGGERATION = 0
2. THE OROUNDSURFACB ELEVATIONS WERE APPROXIMATDBASROON
"DEMOIJHON PUN" PROVIDED BY PM PNGINEERBNG. INC. DATED MAY 1. 2006.
3. STATIC WATER LEVELS APPROXIMATED.
4. S85 FIGURE 2 FOR CROSS•SRCTION LOCATION.
5. CROSS RBCDONIS BASED ON Am PROFESSIONAL JUDGMENT USING AVAILABLE
DATA. 11B 000LOOY FRE81AT2ED IN THIS CROSS SECTION WAS CENERALI250 TO
ILLUSTRATE TlIE MA7OR LITHOLOGIC mars AT THE FITS TUB TTIICI24E.SSAND
EXTENT OFTHE LITHOL001C UNITS ARE APPROXIMATED AND GEOLOGIC
CONTACTS BETWEEN BORING LOCATIONS ARE INFERRED.
GEOLOGIC CROSS-SECTION
PROPOSED WAL GR£EN STORE #L0275
SEC OF BEA L i TES FORD ROAD AND SUNSET ROAD
CHARLOTTE, NORTH CAROLINA
SOUTH
A'
Clayton Group Services
.4 LruKIu ✓rrItal Company
I401/11E
5
H.17:H :F'..A.1 1

FOMER OAS STATION
rWs
LEGEND
MW-1
. 6 (902)
Ini-2
6 (9025) / z
/
40 )1
/ //
/ 0 /
• r
40
�• � 04)
REAT11 S FORD ROAD
•
.1 r
amum amisia simkarmaval.
(9025) C,YiOIlOWATE1 ELEVATION
— — alicuiDWAIER UOOONTOLU LIFE
GEO--ENVIRONMENTAL
CONSULTANTS, INC.
cLoTEPKWAVOIVIRCIMIDITIU. £N J IR$ ; SG0111519
I17w HEAMES ROAD. CHARLOTTE. NC MOO-71137
mow( 004159a-a7Eia FAa (7wlsaa-177o
OMt. IMO/
1'RO1CT O.IIs
palm YTs , KAi
soul 1' . JO'
0 0
OLD STORE
5040 B1 ATTIEB FORD ROAD
CHARLOTTE, NORTH CAROLINA
ORAYN lit [AS
MAIL 1 w.■30 (III Gli0UIMATBi coNiollI MAP
ROME
2

EIRENERTN TO COreNEC1 WELL
CA OTC TD DUE COON NOSE
r
OEHroF 1t5
.1 EY. ADOVI
r �
r. 2'tar
r . }- HEDIx.TkA MHO;
AE1UrIR To TMK
f CAo & C00.4 1106E CONNECTORS
TRUE UHION mimic
OUTLFT CONNFCTtOH DETML
II�WJ[CIRjN
a FT. SCREEN
MnOBlwe RIME ore �+
ItlltCNCH HOSE
SEE OUTLET CONNECTOR SETIL
!/�!J }• rMA8R EC r nJ9lr PIO
PRESSURE AELE7 NOSE
f
\ `t TRIFA Mgao J \ r 1.0401
r Sw. YAWL
H01Ei ALI.
RPEE to L an sac 80 PYC I1NLESS
OIS
E11NP1 U T UOUNTCS ON TRAILER
ti
WIzRG6libi
Mho
rnwle uomtaq courtert STSSITIMILI { ,WRuaY TT. loos.["" ROT To stiles
'loan MK
REDOx TECH, 11C
1008A tIORRISYILLE PARKWAY
MORRISYluE. NC 27500

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store 1/ 10275
Charlotte, NC
SOIL BORING LOGS

Date installed : 1117/06
Logged By : David Wagner
Dulling Company : Regional Probing
MPG Methods : Geoprobe
Through Surfacer : pone stag
Borehdo Diameter : 2-Inches
Boring Terminated al : 264
Sampling Point :1" PVC
Casing Interval : DAB feet
Screened Inlerral : 16-26 feed
Date Measured 1/18/06
TOD Elevation : S4.1
Ground Elevation : S3.8
Dept' to Groundwater :17.7
Depth to NAPL : NA
NAPL Thickness : HA
Weather while DrAtlng : Partly sunny. 85 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Appe ble
: Below Ground Surface
: Not Sampled
: P1D did not detect organic
:vapors
Depot 3
In
Feet
r»
a
ii
0
DESCRI PT1ON
U
z
0
12-
14-
20-
22-
24-
28--
28
NS
2
B
20
200
250
650
sso
1200
1100
860
NS
NS
Fine gravel (slag) with silt and sand.
Light brown to brown silt with Tittle clay, moist
Very slight gasoline -like odor
S5ght to moderate gaasoiina-like odor.
Moderate gasoline-Edce odor
Moist to wet, moderate gasoline -like odor
Wet, moderate gasoline -Ill a odor
Fitt
ML
24-28 ft No recovery of sample.
End ofboring at 28 ft bgs.
LOG OF BORING SB-1
(Page 1 of 1)
Proposed Watgrean Store #10275
SEC of Beauties Ford Road and Sunset Roar}
Charlotte, NC

Date Installed
Logged By
Lang Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing interval
Screened Interval
: 1117/06
: David Wegner
: Regional Probing
Geop obe
: Fine Slag
2-Inches
: 20
: 1' PVC
: 0-17 feet
: 17-27 feet
Date Measured : 1,10/00
TOC Elevation : 04.2
Ground Elevation ; 83.5
Depth to Groundwater : 17.0
Depth to NAPL : NA
NAPL Ttickness : NA
Weather while L1nl1irrg : Partly sonny. 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: NalAppllcahle
: Blow Ground Surface
: Not Sampled
P1D did not detect organic
: vapors
b
2
to
Fed
E
a
a
3
1=
DESCRIPTION
a
6
2-
4--
8-
8—
J
10--
12-
14-
167
18-
7
20
22
24;
28:
a
28
NS
3
3
7
a
34
20
13
75
40
1100
1400
500
140
NS
NS
Fine gravel (slag) with silt and sand.
Light brown sift with trace day, moist.
Very slight gasorme-like odor
Slight gasofirre4tke odor
Light brawn to fight gray silt with little to some day,
moist to wet; moderato gasoline -like odor.
•
Moderate gasoline-Igre odor.
ML
24-28 ft. No recovery of sample.
End of boring at 28 ft bgs.
Casing interval
Screened Interval
LOG OF BORING SB-2
(Page 1 of 1)
Proposed Walgreen Stare #10275
SEC of Beattie* Ford Road and Sunset Road
Charlotte. NC

Date Installed : 1117106
Logged By : David Wagner
Th fing Company : Regional Prong
Wiring Methods : Geeprobe
Through Surface : Fine slap
Borehole Diameter : 2-Inter
Boring Terminated at : 26'
Sanding Point : NA
Casing Interval : NA
Screened bttarval : NA
Dale Measured : NA
TOG Elevation : NR
Ground Elevation ! NA
Depth to Groun water : Not measured
Depth to NAPL : NA
NAM_ Thickness : NA '
Weather wile Drilling : Partly sunny, ES degrees
Abbreviation Key
NR : Not Recorded
NA : No:Applcable
bga : Below Ground Surface
NS : Not Sampled
ND : HD rid not detect organic
: vapors
in
Feet
la
E,R
c
c-
E
DESCRIPTION
ron
D.
C.,
0
-
.•
z-
7
7.
4
ill—,
6=
10-
12
14i,E1
18-
18-E
-
ND
p0
ND
7
'la
7
850
550
650
450
'
-
Light brawn to brown slit with Gale day and trace
medium gravel, moist 1 - 2 inches of fine slag at
surface.
Grades to brown with trace clay, little fine to coarse
sand. Larne of fine to medium slag also present at
approximately 4 feet.
Grades to some clay with trace fine to coarse sand and
trace fine to medium gravel. very slight gasoline -like
odor.
FELL
Light brown to brown at with little day, moist, slight to
moderate gasoline -trice odor,
End of boring at 20 ft. bgs.
—
ML
20
_
ir 1,,,
LOG OF BORING SB-3
(Page 1 of 1)
Proposed We/green Store 610275
SEC of Beanies Ford Road and Sunset Road
Charlotte, NC
lolieltiml

Date hastened
Logged By
Drilling Company
Dn18ng Methods
Thigh Surface
Borehole Diameter
Baring Terminated at
Sampling Point
Casing Interval
Screened Interval
:1I 7R08
: David Wagner
: Regional! Probing
: Geoprohe
: Furs slag
: 2-irxhes
: 28
: 1' PVC
: 0-18 feet
: 18-28 feet
Date Measured, :1/18/08
TOC Elevation : 84.6
Grain Elevat n : 84.1
Depth to Groundwater : 18.0
Depth to NAPL : NA
NAPLThidcncn :NA
Weather while Driiling : Partly sunny, 55 degrees
AbbrevlsOoo Kay
NR
NA
bgy
NS
ND
: Not Recorded
: Nat AppEcable
: Below Ground Surface
: Nol Sampled
PJD did natdeteot organic
: vapors
Depth
to
Foal
co
E
0
8
F
DESCRIPTION
a
2—
4—
8-
8—
10.
12-
14_
18—
1B-
20-
22-
24 —
26 —
28
NS
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
,Fine gravel (slag) with silt and sand.
Light brown to brown silt with tittle clay, moist
Light brown to light gray.
Trace clay
Light brown to beige with little day and moist to weL
Light brown to fight gray, moist
End of boring at 28 ft. bgs.
FILL
?AL
Casing Interval
Screened Interval
LOG OF BORING SB-4
(Page 1 of 1 )
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte. NC

Data hateged
Logged By
Dnlrmg Company -
Drilling Methods
Through Surface
BorehofeDi meter
Boring Terminated at
Sampling Point
Casing Interval
Scaeened Intervie
Depth
Feet
tn
E
: 1117J09
: David Wegner
: Regional Probing
: Grceen:be
: Fine slag
:2-Inches
:2a
:NA
:NA
:NA
se
m
8
F
Date Measured : NA
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : Not measured
Depth to NAPL : NA
NAPL Thickness : NA
Wcatherwhits DNting : Partly surety, 55 degrees
DESCRIPTION
0,
Abluevfe5cn Key
NR
NA
bag
NS
NO
0
r
2�
4-
6=
a-
10-
12-
14-
1ti-
18�
20
NS
5
a
152
43
SS5
1260.
1416
1475
1200
1020
Light brown to dark brown silt with Me to some gravel
and silt, and little fiche to coarse sated, moist. 1 - 2
Inches of fete slag at surface.
FILL
Light brown to brown silt with soma day. moist, slight
gasoline Ike odor.
Lithe clay, slight to moderate gasoline -De odor.
Modererte gaso0ne-flio3 odor.
End of baring at 20 ft bgs.
tstIL
LOG OF BORING SB-5
(Page 1 of 1)
: Not Recorded
NotApplizeble
: Below Ground Surface
Not Sampled
: PND did not date.; organic
vapors
Proposed Walgreen Store #10275
SEC of Beattie& Fond Road and Sunset Road
Charlotte, NC

Date installed
Logged By
Drtlhng Company
Dri#mg Methods
Through Surface
Borahala Diameter
5oring Terminated at
Sampling Point
Casing lntervei
Screened interval
:1l17108
David Wagner
: Regional Probing
: Geoprobe
: Fine slag
: 2-inctiea
: 25'
: 1' PVC
: 0-17 feet
:17-27 feet
Data Measured :1116/05
TOC Elevation : 95.2
Ground Elevation : 94.6
Depth to Groundwater : 1 s.7
Depth to NAPL : NA
NAPL Thickness : NA
Weather vale Drilling : Pally sunny, 65 degrees
Abbreviated Kay
NR
NA
NS
ND
: Not Recorded
: Not Appacat Ie
: Below Ground Surface
: Not Semp1N1
: P9D did not detect organic
: 'spars
Depth
in RI -
Feet gJ
II
-a
a
•
a
DESCRIPTION
3
v
0
2—
,4:
aJ
10-
12—'
157
18-
20--
22:
24-
26-
28
NS
S
30
70
15
220
550
1300
1300
1100
500
NS
NS
NS
NS
Light brown to dark brown clay with little to some gravel
and silt, and little fine to coarse sand, moist 1 - 2
Inches of fine slag at the surface.
ALL
Light brown to brown sift with some clay, moist, slight
gasoline -like odor.
Little clay, slight to moderate gasoline -like odor.
Moderate gasoline -toe odor.
Moderate gaso0nefii oe odor.
Moderate gaso5ne-rice odor_
NIL
20-28 ftbgs No recovery
End of baring at 28 ft bgs.
Casing Interval
Screened Interval
LOG OF BORING SB-6
(Page 1 of 1)
Proposed Walgreen Store #10276
SEC of Beetties Ford Road and Sunset Road
Charlotte, NC

Date Instated
Legged By
Doling Company
Miring Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened interval
: 1117108
: David Wagner
Regianal Probing
Geoprobe
: Fine slag
; 24rrrkres
: 2Er
: t' PVC
: 0-1 6 feet
: 16-25 feet
Date Measured :1118/05
TCC Erman ; NR
Ground Elevation : NR
Depth to Groundwater : 15.0
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Dr1ting : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
NS
ND
: Not Recorded
Not Applicable
: Wow Ground Surface
: Not Sampled
PID did not detect organic
: vaxaa
Depth
in
Feet
1)
N
E
0
DESCRIPTION
c
U
m
0
2--
4-
6—
a
8-
10-
12-
18-
20-
22-
24:1
28-
28
1
4
10
121
61
eon
350
570
520
340
550
820
700
700
Ught brown to dark brown day with Iittls to some gravel
and silt, and little twee to coarse sand, moist. 1 - 2
Inches of line slag at the surface.
FILL
Ught brown to brown slltwhh some clay, moist, slight
gasoline -like odor.
Little to some clay.
ML
Ught brown to fight gray day with some sill, moist, slight
to moderate gasoline -like odor.
CL
Light brown to light gray silt with tittle day_
to wet and moderato gasoline -like odor.
Slight to moderato gasoline -like odor.
Wet
Wet to saturated and slight to moderate gasoline -late
odor.
End of boring at 28 ft. bgs.
ML
LOG OF BORING SB-7
(Page 1 of 1)
•
Casing Interval
Screened Interval
Proposed Walgreen Store 010275
SEC of wattles Ford Road and Sunset Road
Charlotte, NC

Date Installed
Io8ged BY
Drain Company
Drilling Methods
Through Sonata
Scrrje* Diameter
Bering Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1117f0+5
: David Wagner
: Regional Probing
: °copra=
Fine slag
: 2-incites
: 24'
PVC
: 0-14 feet
: 14,24 feet
Date measured
T0C Elevation
Groused Elevation
: 111 BtO6
:NR
:NR
Depth to Groundwater : 5.6
Depth tD NAPL : NA
NAPL Thickness : NA
Weatherw4dle Dining : Pally sunny, 55 degrees
Abbreviation Key
NR
NA
b
NS
ND
: Not Recorded
: Not Applicable
Betow Ground Siatace
: Not Sampled
PID did not detect organic
: vapors
Depth
to a
Feel m
0.
0.
C.
T1m® Collected
DESCRIPTION
z
2--
a
4-
8-
8-
10--
18-
20—
22—
24
NS
ND
Fib
ND
ND
ND
ND
NO
ND
ND
ND
ND
Light brown to dark brown day with lithe to some gravel
and silt, and little fine to coarse sand, moist 1- 2
undies of fine stag at the surface.
FILL
Light brawn silt with little to some stay, moist
Linte coy.
i}tde to some clay.
L.ttde day.
Most to wet
End of boring at 24 ft. bgs.
ML.
Casing Interval
Screened Interval
LOG OF BORING SB-8
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

Date InstaSSad
Lagged Dy
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated et
Sampling Point
Casing interval
: 28r+ed interval
1l I5!09
: David Wagner
: Regional Probing
: Geaprabe
: Fine stag
: 2-Inures
213
: 1" PVC
: 0.15 feet
: 15-25 feet
Date Measured :1l1Bt08
IOC Eevation : NR
Ground Elevation : NR
Depth to Groundwater : 15,7
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny. 50 degrees
Abb►eviatxun Key
NR
NA
NS
ND
: Not Recorded
: Not Applicable
:Heim Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
Depth
in
Feet
E
E
a
0
Time Collected
DESCRIPTION
0,
0
2
0
2-
4-
6-
8�
12-
14-
16-
18-
20-
22-
24-
26-
28
C7
NS
ND
ND
ND
ND
a
4
0,5
1
5
0.5
0,5
o.5
0.5
1,F1ne gravel (slag) with sift and sand.
Brown clay with little to soma silt. moist,.
FILL
Ct.
Ur
Light brown to light gray silt with trace to tittle clay,
moist, slight gasoline -like odor.
VerysGgllt gasoline -like odor.
Some Clay.
Trace okay.
Trace to little clay and very slight gasoline like odor,
MOM.
Some day and wet to saturated.
End of boring at 2811. bgs.
ML
Casing interval
Screened Interval
LOG OF BORING SB-10
(Page 1 of 1)
Proposed Walgteeft Store #10275
SEC of 8eatlies Ford Road and Sunset Road
Charlotte. NC

Date installed :1NWV0e
Logged Ey : David Wagner
Drug company : Regional Probing
Drilling Methods : Oeoproba
Through Surface : Fine slag
Borehole Diameter : 24nchea
Boring Terminated at : 27'
Swaging Point :1' PVC
Casing interval : 0-17 feet
Screened interval :17-27 feet
Data Measured ' 1f1tV06
TOC Elevation : NR
Grand Elevation : NR
Deter to Groundwater :12.9
Depth to NAPI. : NA
NAPL Ttddtness : NA
Weather white Drlihng : Panty sunny. SO degrees
Abbreviation Key
NR : Not Recorded
NA : NotAppk fe
bgs : Below Ground Surface
NS : Not Sampled
ND : Pie drd not detect organic
: V2pare
In
Feet
E
0
a.
DESCRIPTION
8
Q
0
1-
2-
3_
4-
5-
5-
7--
B-
0-
10-
11-
12-
13-
14-
15-
18-
17-
18-
1Q-
20-
21-
22—
23-
24-
25-
25-
27
rn
NS
ND
It)
1+�
ND
ND
ND -
Are
ND
NNS
ND
ND
ND
ND
,.Fine gravel (slag) with sill end sand.
Brawn to dark brown clay with soma silt, moist.
Light brown.
Light brown to light grey, slit with trace clay, moist
Mast to wet
End of boring at 27 ft. bgs.
ti
1-
a
M1.
Casing interval
Screened Interval
LOG OF BORING SB-11.
(Page 1 of 1)
Proposed Weigreen Store #10275
SEC of Beadles Ford Road and Sunset Road
Charlotte, NC

Data installed :1/17iQe
Logged By : David Wagner
Drilling Company : Regional Probing
Mang Methods : lgeapaobe
Through Surface : Fine slag
Borehats Diameter : 2-inches
Baring Terminated at : 24
Sempring Pont :1' PVC
Casing 1ntrrval : 0-14 feet
Screened Interval :14-24 fed
date Measured :1fiB100
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 4.6
Depth la NAPL : NA
NAPL Thickness : NA
Weather while Duffing : Partly sunny. 55 degrees
Abbreviation Key
NR
NA
NS
ND
: Not Remrded
: Not Applicable
: Below {around Surface
: Not 5arrotazi
:PID del not detect organic
: vapors
s
DePth
in
Feel
a
a
DESCRIPTION
0
a
2
4
NS
Fine gravel' (slag) with slit and sand.
FILL
T
Light brown to brown silt with e to some clay, moist.
Me
NO
NO
Light brown and very slight petroleum -like odor.
Light brown to light gray and some clay.
50
tics
n
Little flay.
5
ML
5
Wet to saturated
00
Moist to wet.
Little to some clay and wet to saturated.
30
ID
End of boring at 24 tt bps.
10
__
8-
10
12
14
16
18
20
22
24
1nrornr M=I `um uemm3:
Casing Interval
Screened Interval
EITZEIDDI
LOG OF BORING SB-12
(Page's of 1)
Proposed Wasgreen Store 610275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

Date Installed : 1l1ed0e
Logged By : David Wagner
Drilling Company : Regional Probing
Drilling Methods . Geoprobc
Through Surface : Coarse slag
Borehole Diameter : 2-inches
Boring Terminated mt :10'
Sampling Point : 1° PVC
Casing Interval : NA
Screened Interval : NA
Date Measured : 1110/05
TOO Elevation : NR
Ground Elevation : NR
Depth to Groundwater :10.3
Depth to NAPL : NA
NAPLThiekness :NA
Weather while Drilling : Partly sunny, 50 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Betow Ground Sleaze
: Not Sampled
: PID did not detect organic
: vapors
Depth
in .
Feet 5
rn
E
o.
o.
DESCRIPTION
0
U
r
a
0
0
1-
2-
3--
4-
5-�
63
'7-
ti
15—
16-
19-
NS
NS
ND.
ND
ND
ND
NO
ND
ND
Fine to coarse gravei and cobbles (slag) with at and
sand.
Brown clay with some silt. moist
Little to some sill
Wet
Light brown to light gray, saturated.
fM1oi5L
Some silt and moist to wet.
Light brown to brawn silt with liit@e clay, moist.
End of boring at 19 ft. bgs.
FILL
CL
ML
Casing Interval
Screened Interval
LOG OF BORING SB-13
(Page 1 oft}
Proposed Welgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte. NC

Date instilled
Logged By
DrnTmg Company
Drifting Methods
Through Surfaoe
Borehole Diameter
Boring Terminated et
Sampling Pa1nt
Casing Interval
Screened Interval
:1118/05
: David Wagner
: Regional Prating
Geoprobe
: Dirt parking area
: 2-loches
: 24'
:1' PVC
0-14 feet
:14-24 feet
Date Measured
TOC Eovarron
Ground Elevation
:1 r1970s
: NR
:NR
Depth to Groundwater : 14.1
Depth to NAPS. : HA
NAPL Thickness : NA
Weather while Orftting : Partly sunny. 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
Not Recorded
: Not Applicable
: Below bround Surface
: Not Sampled
: PID did not detect organic
:vapors
Depth
In
Feet
E
rA
E
a
D.
m
j
DESCRI P'FION
co
LJ
rn
0
NS
No
Brown silt with frttig to some clay. moist
ND
Little clay.
ND
MI
No
Light brown to brown.
ND
ML
NO
Light brown and moist to wet
ND
Wet
-
NND
20-24 ft bgs. Not sampled.
NS
-
End of boring at 24 ft bgs.
-
Ns
2-
4
S
8
4' 10
.12
14
10
18
20
22
24
110221110124
LOG OF BORING SB-14
(Page 1 of 1)
Casing Interval
Screened Interval
Proposed Walgreen Store #k10275
SEC of Beatties Ford Road and Sunset Road
Charlotte. NC

Date installed : 1h8r05
Logged 8y : David Wagner
Drifting Ccrmparry : Regional Probing
Drilling Methods : Deoplabe
Through Surface : Dirt armess road
Borehole Diameter : 2-Inches
BolfngTe dot : 24'
iris Paint : 1' PVC
Casing interval : 0-14feet
Screened Interval 14-24 feet
Depth
Feet
E
a
n
a.
i�
F
-T
Date Measured : 1113i0&
TOC Elawdon : NR
Ground Elevation ; NR
Depth to Groundwater : 13.3
Depth to NAP_ : NA
NAPL Thickness • : NA
Ylfeather while Dritlbrg : Pasty sunny, 55 degrees
Abbredi>dim Key
NR
NA
bga
NS
ND
: Not Recorded
: Not AppE g
: Below Grotext Surface
: Not Sampled
: P113 rid not detect edged:
DESCRIPTION
0
0
2-
4-
6-
6—
h0-
12-
14-
16—I
1t8-
20-
22-
24
CI
NS
2
3
2
4
2
2
4
25
3
NS
Ns
% Darts brown to brown silt, sand and gravel,
Light brown to light gray day with Tittle to soma sit,
moist, very slight petroleum and goof', e-liKe odor.
Some sib.
Light brown to fight gray silt with untrue to some clay.
moist
Light brown and trace to little clay.
Light brown to tight gray and little day, Very slight
gasoline -like odor.
Moist to wet and very sight gasoline -like odor.
20-24 ft bgs. Not sampled.
End of boxing at 24 it bgs.
FILL
CL
Mb.
LL
LOG OF BORING SB-1 6
(Page 1oil)
s
MliM W I1nl Mu1 HI nlp1 nl-fluilInnl nnunm
Casing Interval
Screened interval
Proposed Walgreen Store tkl0275
SEC of Beatfies Ford Road and Sunset Road
Charlotte. NC

Dale Mstai1 d
Logged By
DrtTng Company
Ming Methods
Through Surface
Bo a role Diameter
BoiingTermineted at
Sampling Point
Casing Interval
Screened Interval
:1118/05
: David Wagner
: Regional Probing
: Geoprobe
: Dirt excess road
: 2-Inches
: 24'
:1" PVC
: 0-14 Feet
14-24 feet
Date Measured
TOC Elevation
Ground Elevation
: 1118) 8
:NR
:NR
Depth to Groundwater : 9.0
Depth to NAPL : NA
NAPL Thickness : NA
Wea herwlvle Dr9rtng : Panty sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not AppSke
: Bdo'w Gintmd Surface
Not Sampled
: Pia did nat detect organic
: vapors
Depth m
fn E
Feet a
E
rs.
DESCRIPTION
w
0
a
l7
0
2:
10-
12-
14-
16-
187
20:
22—
24
NS
ND
ND
1
NO
ND
Dark brown to brown silt, Sand and gravel.
Light brown to right gray clay with little to soma sdt,
moist.
Some sift
FILL
;'"
CL
Light brown to fight gray silt with tittle clay, moist.
ND Little to some clay.
NA
N Wet to saturated and tittle clay.
ND
ND
I5
NS
ML
20-24 ft. bgs. Not sampled.
End of boring at 24 ft bgs.
1II]YYig[p[7 r1mmo
Casing Interval
Screened interval
1151112113211
LOG OF BORING SS-17
(Paget of 1)
Proposed Walgreen Store #10275
SEC of Beauties Ford Road and Sunset Road
Charlotte, NC

Dale installed : 1118l06
Logged By : David Wegner
Drilling Company : Regional Probing
DriBrig Methods : Geoprobe
Through Surface : Coarse stag
Borehole Diameter : 24nrhea
Boring Terminated at : 21Y
Sampling Point : 1" PVC
Casing Mime] : 0-14 feat
Screened interval : 14-18 feet
Date Measured : lll&/08
TDC Elevation : NR
Ground Elevation : NR
Depth to Groundwater :4.7
Depth to NAM : NA
NAPL Thisdness : NA
Weather white Onlli ig : Partly slimy, 50 degrees
Abbreviation Key
NR
NA
bSts
NS
ND
: Nat Recorded
: Not Applicable
: Behave Ground Surraoo
: Not Sampled
: PID Old not detectorganic
vapors
Depth
In
Feet
is
1/3
E
a
Time Co rBdad
DESCRIPTION
V
so
0
2-'
4=
s-
s=
10�
14i
1B-
J
18-
20
Ns
NO
ND
ND
ND
ND
ND
ND
ND
ND
NS
Fine to coarse gravel and cobbles (slag) with slit and '
sand
Fire
Brown day with Rite to some silt moist
Light brown to brown.
Little sNt
Light brown to light gray and little to soma silt_
Wet.
Some silt and saturated.
`End of boring at 20 ft bgs.
CL
Casing Interval
Screened Interval
LOG OF BORING SB-19
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Seethes Ford Road and Sunset Road
Charlotte. NC

Attachments — Section V
Application fir Injection Pilot Study
- Old Store LUST Incident
Proposed Walgrcen Store 010275
Charlotte, NC
MSDS FOR SODIUM PERSULFATE

MATERIAL SAFETY DATA SHEET
Sodium Persulfate •
FMC
MSDS Re[ No.; 7775-27-1
Date Approved: 02f2212005
Revision No.: 11
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the rsirada Workplace Hazardous Materials Information System (WHMIS)
and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Sodium Persulfate
SYNONYMS: Sodium Peroxydisulfaee; Disodium Peroxydisu1fate
GENERAL USE: Polymerization initiator. Etchant and cleaner in manufacture of
printed circuit boards, Booster in hair bleaching formulations in
cosmetics. Secondary oil recovery systems as a polymerization
initiator and a gel breaker.
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION
Active Oxidants Division
1735 Market Street
Philadelphia, PA 19103
[phone] (General Information)
[phone] (CHEMTREC -U.S.)
[phone] (Medical - Call Collect)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW :
• White, odorless, crystals
• Oxidizer.
• Decomposes in storage under conditions of moisture (water/water vapor) and/or excessive heat causing
release of oxides of sulfur and oxygen that supports combustion. Decomposition could form a high
temperature melt See Section 10 ("Stability and Reactivity").
POTENTIAL HEALTH EFFECTS: Airborne persulfate dust may be irritating to eyes,
nos; lungs, throat and skin upon contact. Exposure to high levels of persulfate dust may cause difficulty in
breathing in sensitive persons.
Page 1 of 9

Sodium Persulfate (7775-27-1)
Date: 02/22/2005
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS#
Wt%
EC No.
EC Class
Sodium Persulfste
7775-27-1
>99
231-892-1
Not classified as hazardous
4. FIRST AID MEASURES
S
EYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Rinse-moutb with water. Dilute by giving 1 or 2 glasses of water. Do not induce
vomiting_ Never give anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists,
contact a medical doctor.
NOTES TO MEDICAL DOCTOR: This product has low oral toxicity and is not irritating to
the eyes and skin. Flooding of exposed areas with water is suggested, but gastric Iavage or emesis
induction for ingestions must consider possible aggravation of esophageal injury and the expected absence
of system effects. Treatment is controlled removal of exposure followed by symptomatic and supportive
cart. .
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Deluge witb water.
FIRE / EXPLOSION HAZARDS: Product is non-combustible. On decomposition releases
oxygen which may intensify fire. Presence of water accelerates decomposition.
FIRE FIGHTING PROCEDURES: Do not use carbon dioxide or other gas Pilled fire
extinguishers; tbsy will have no effect on decomposing persutfates. Wear full protective clothing and self-
contained breathing apparatus.
FLAMMABLE LIMITS: Non-combustible
SENSITIVITY TO IMPACT: No data available
Page 2of9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
SENSITIVITY TO STATIC DISCHARGE: Not available
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Spilled material should be collected and put in approved DOT container and
isolated for disposal. Isolated material should be monitored for signs of decomposition (fuming/smoking).
If spilled material is wet, dissolve with Iarge quantity of water and dispose as a hazardous waste. All
disposals should be carried out according to regulatory agencies procedures.
7. HANDLING AND STORAGE
HANDLING: Use adequate ventilation when transferring product from bags or drums. Wear
respiratory protection if ventilation is inadequate or not available. Use eye and skin protection. Use clean
plastic or stainless steel scoops only.
- STORAGE: Store (unopened) in a cool, clean, dry place away from point sources of heat, e.g.
radiant beaters or steam pipes. Use fast in, fast out storage system. Avoid contamination of opened
product. In case of fire or decomposition (fuming/smoldng) deluge with plenty of water to control
decomposition. For storage, refer to NFPA Bulletin 430 on storage of liquid and solid oxidizing materials.
COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to
prevent release of dust into work environment. Spills should be collected into suitable containers to prevent
dispersion into the air.
S. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name
ACGIH
OSHA
Supplier
Sodium Persulfate
0.1 mg/m3 (TWA)
ENGINEERING CONTROLS: Provide mechanical local general room ventilation to
prevent release of dust into the work environment. Remove contaminated clothing immediately and wash
before reuse.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Use cup type ctemical goggles. Full face shield may be used.
RESPIRATORY: Use approved dust respirator when airborne dust is expected.
Page 3 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
PROTECTIVE CLOTHING: Normal work clothes. Rubber or neoprene footwear.
GLOVES: Rubber or neoprene gloves. Thoroughly wash the outside of gloves with soap and
water prior to removal. Inspect regularly for leaks.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR:
APPEARANCE:
AUTOIGNITION TEMPERATURE:
BOILING POINT:
COEFFICIENT OF OIL 1 WATER:
DENSITY 1 WEIGHT PER VOLUME:
EVAPORATION RATE:
FLASH POINT:
MELTING POINT:
ODOR THRESHOLD:
OXIDIZING PROPERTIES:
PERCENT VOLATILE:
pH:
• SOLUBILITY IN WATER:
SPECIP7C GRAVITY:
VAPOR DENSITY:
VAPOR PRIf!SSURE:
None
White crystals
Not applicable. No evidence of combustion up to 800°C.
Decomposition will occur upon heating.
Not applicable
Not applicable
Not available
Not applicable (Butyl Acetate = 1)
Non-combustible
Decomposes
Not applicable
Oxidizer
Not applicable
typically 5.0 - 7.0 @ 25 °C (1% solution)
73 % @ 25 °C (by wt.)
2_6 (H1O=I)
Not applicable (Air =1)
Not applicable
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID:
STABILITY:
POLYMERIZATION:
INCOMPATIBLE MATERIALS:
Page 4 of 9
Heat, moisture and contamination.
Stable (becomes unstable in presence of heat,
moisture and/or contamination)_
Will not occur
Acids, alkalis, halides (fluorides, chlorides,
bromides and iodides), combustible materials, most
metals and heavy metals, oxidizable materials,
other oxidizers, reducing agents, cleaners, and
organic or carbon containing compounds. Contact

Sodium Persulfate (7775-27-1) Date: 02/2212005
with incompatible materials can result in a material
decomposition or other uncontrolled reactions.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen that supports combustion and oxides of
sulfur.
COMMENTS: PRECAUTIONARY STATEMENT: Use ofpersulfates in chemical reactions
requires appropriate precautions and design considerations for pressure and thermal relief.
Decomposing persulfates will evolve large. volumes of gas and/or vapor, can accelerate exponentially with
heat generation, and create significant and hazardous pressures if contained and not properly controlled or
mitigated.
Use with alcohols in the presence of water has been demonstrated to generate conditions that require
rigorous adherence to process safety methods and standards to prevent escalation to an uncontrolled
reaction.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Nan -irritating (rabbit) [FMC Study Number ICG/T-79.029]
SKIN EFFECTS: Non -irritating (rabbit) [FMC StudyNutnber. ICG/T-79.029]
DERMAL LD50: > 10 g/1rg [FMC Study Number: ICG1r-79.029]
ORAL L050: 895 mg/kg (rat) [FMC Study Number. ICG/I'-79.029]
INHALATION LC50: 5.1 mg/1 (rat) [FMC 195 2017]
SENSITIZATION: May be sensitizing to allergic persons. [FMC Study Number:ICG/T 79.029]
TARGET ORGANS: Eyes, skin, respiratory passages
ACUTE EFFECTS FROM OVEREXPOSURE: Dust may be harmful and irritating.
Maybe harmful if swallowed.
CHRONIC E+ tt CTS FROM OVEREXPOSURE: Sensitive persons may develop
dermatitis and asthma [Respiration 38:144,1979). Groups of male and female rats were fed 0, 300 or 3000
ppm sodium persulfate in the diet for 13 weeks, followed by 5000 ppm for 5 weeks. Microscopic
examination of tissues revealed some injury to the gastrointestinal tract at the high dose (3000 ppm) only.
This effect is not unexpected for an oxidizer at high concentrations. [Ref. FMC 190-1151, Toxicologist
1:149, 1981).
Page 5 of 9

Sodium Persulfate (7175-27-1) , Date: 02/22/2005
CARCINOGENICITY:
NTP: Not listed
IARC: Not listed
OSHA: Not listed
OTHER ACG1H: Not listed
12. ECOLOGICAL INFORIVIATION
ECOTOXICOLOGICAL INFORMATION:
Bluegsll sunfish, 96-hour LC50= 771 mg/L [FMC Study 192-1250]
Rainbow trout, 96--hour LCso =163 mg/L [FMC Study 192-125I ]
Daphnia, 4B-hour LC5a=133 mg/L [FMC Study 192-1252]
Grass shrimp, 96-hour LC50= 519 mg/L [FMC Study 192-1253]
CHEMICAL FATE INFORMATION: Biodegradability does not apply to inorganic
substances.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose as a hazardous waste in accordance with local, state and federal
regulatory agencies.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
PROPER SHIPPING NAME: Sodium Persulfate
PRIMARY HAZARD CLASS / DIVISION: 5.1 (Oxidizer)
UN/NA NUMBER:' UN 1505
PACKING GROUP: III
LABEL(S): 5.1 (Oxidizer)
PLACARD(S): 5.1 (Oxidizer)
MARK1NG(S): Sodium Persulfate, UN 1505
ADDITIONAL INFORMATION: Hazardous Substance/RQ: Not applicable
Page 6of9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
49 STCC Number: 4918733
This material is shipped in 225 lb. fiber
drums, 55 lb. poly bags and 1000 - 22001b. -
IBC's (supersacis).
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
PROPER SHIPPING NAME: Sodium Persulfate
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
PROPER SHIPPING NAME: Sodium Persulfate
OTHER INFORMATION:
Protect from physical damage. Do not store near acids, moisture or heat
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not applicable
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Fire Hazard, Immediate (Acute) Health Hazard
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
Not listed
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Unlisted, RQ = 100 lbs., limitability
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA INVENTORY STATUS (40 CFR 710):
Pagel of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
Listed
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261):
Waste Number: D001
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM);
Product Identification Number: 1505
Hazard Classification / Division: Class C (Oxidizer), Class D, Div. 2, Subdiv. B. (Toxic)
Ingredient Disclosure List: Listed
INTERNATIONAL LISTINGS
Sodium persulfate:
Australia (AICS): Listed
China: Listed
Japan (ENCS): (1)-1131
Korea: K&12369
Philippines (PICCS): Listed
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
EC Symbols: (Not classified as hazardous)
EC Risk Phrases: (Not classified as hazardous)
EC Safety Phrases: (Not classified as hazardous)
16. OTHER INFORMATION
HMIS
Health
1
Flammability
0
Physical Hazard
I
Personal Protection (PPE)
J
Protection = J (Safety goggles, gloves, apron & combination dust vapor reap
HMIS = Hazardous Materials Identification System
Degree of Hazard Code:
4 — Severe
Page 8 of 9

Sodium Persulfate (7775-27-1) Date: 02/2212005
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
NFFA
Health
Flammability
Reactivity
0
1
Special
ox
SPECIAL a OX (Oxidizer)
NFPA = National Fire Protection Association
Degree of Hazard Code;
4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant
REVISION SUMMARY:
This MSDS replaces Revision #10, dated October 05, 2004.
Changes in information are as follows:
Section 1 (Product and Company Identification)
Section 16 (Other Information)
FMC Logo - FMC Corporation Trademark
© 2005 FMC Corporation. All Rights Reserved,
FMC Corporation believes that the information and recommendations contained herein [including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance an such information.
Page 9 of 9

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store #I0275
Charlotte, NC
ADJACENT PROPERTY RECEPTOR SURVEY RESULTS

AM1•
NA
Brownly
:11144-.: ,. .. . TA9i E 1
ti r r. .
'A D3ACENT'.PROPERTYOW NI RPOTENTIAI:.RECEPTORSURVEY
ADDRESS • .--4.1'CITY• WATER!3B!1S13,1F3�7T SUPPLY W COMMENTS
=;sue - - 7-. Fit -DATA
:w � � — DEPTH
5226 !kettles Ford Rd
4837 Beanies Ford Rd
NA
NA
NA
DIAMETER
NA
Rezones
Temple
4919 Beanies Ford Rd
Barnes
Amen
No
Yes
5300 Beanies Ford Rd— Yes
5041 Beanies Ford fed
Cummings
Pena
Sunset Comers Plaza
5308 Beanies Ford Rd
5309 Beattie Ford Rd
Yes
Ycs
No
No
NA
Resident nor home - well
house observed
NA Resident uses supply well
1No supply well
NA
No
No
NA
NA
NA
NA
NA
NA
Kappa Alpha
Psi
5400 Beanies Ford Rd
5408 Beanies Ford Rd
No
Yes
No
Yes
NA
NA
NA
NA
No
Yes
No
NA
NA
NA
NA
NA
5409 Beauties Ford Rd
Rapp:
5009 Beanies Ford Rd
NA
NA
NA
2"
Well house observed
No supply well
Nine stores on city water
Resident uses supply well
Resident not home
Resident uses supply well
Resident net home - well
house and water meter
observed
Resident not ho0me -,yell
sure ooservc
Yes
Yes
NA
NA
Resident not home - well
house and water meter
observed •
NA
Russell
Lytle pals
NA
Liam than
HamilrOn
4040 Hamilton Dr
443 6 Eeenies Ford Rd
4901 $entries Ford Rd
4909 Beanies Ford Res
4912 Beanies Ford Rd
4952 Beanies Ford Rd
Ycs
Yes
Hamilton
Commercial
Courier
Express
Butler
Blackman
4924 Beanies Ford Rd
No
Yes
Yes
Yes
Yes
Yes
No
No
NA
No
No
No
NA
1
_N
NA
90'
NA
ReSldent nal home - well
house and inter meter
observed
NA 'Resident uses supply well
• No supnls'tircU
NA
Resident not home
No supply well
- No supply well
2' Resi\4'ede Lindicated no looser
n.SC
5006 Beanies Ford Rd
4900 Beauties Ford Rd
4924 Kerr Lane
No
No
NA
6'
Business uses supply well
Nash
Ttan
Boyznate5
5000 Kerr lone
4314 lobo}' or
4322 Sunset Rd
No
No
Yes
Yes
Yes
No
No
Yes
No
No
NA
NA
NA
NA
Chambers
Rivers
NA
Mbungu
Ford
4951 Hamilton Cir
4947 Hamilton Cir
4944 Hamilton Cir
4939 Hamilton Cir
4928 Hamilton Or
Yes
No
NA
Yes
No
NA
NA
NA
Resident uses supply well
Resident uses supply well
No supply well
No
supply well
,No supply wolf
NA Rrstnnr indichaied °,wash+;ars
and noose worn well Mallet
NA
NA
No
Na
Yes
Yes
NA
40'
NA
2"
lirsidcnt hes supply wet!
Resident not home - well
house and wailer meter
observed
Resldeni uses supply well
Resident uses supply will
NA Resident(s) not available on four occasions for interview or did not know answers.
• - Determined by „ester meter and/or interview.
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Table 1:
Receptor Survey Summary
K1ker Property, incident# 21451
5100 Wattles Ford Road
Charlotte, Mecktenlrurs County
S611IE Project 0135+03-509
Lanai >L a :.> i albs*.ate
867;4116--P Oc roJE e 0-031 `s
r 1 ge-2 7130errr /, LoCirEQ NvirrJJ -
,s-va ter. perre D' a,-- -ri r ape- slim 9 Bruit 211.
li
i -::a� ��� ' i-�=� .w
.... ..�¢i' ...i.
-.h ff � �..}��i S k
x.. ":,.. .�. A +t-,
n �..f5 i. ti.!V I s
.4..,.-
{ 5 ,i
_.l:.ni-� r
11 �4- e l
..:
1
5100 Beanies Ford Road {site)
RMP Sunset, LLP
10700 Sikes Place, r7100
Charlotte, NC
0
Well abandoned January 2001
.12
5100 Beatties Ford Road (Site)
RMP Sunset, LLP
10700 Sikes Plate' COO
Charlotte, NC
0
• Well abandoned January 2002
3
5Z00 8eattles Ford Road
James H. Richardson, Jr.
17511 Paradise Cove Court
Cornelius, NC 28031
'
0 - 250
Property Is vacant, no well observed, MCDEP
database does not indicate well on Property
4
4232 Kitty Drive
Robert A. & Melinda B. Dabbs14232
Kitty Drive •
Charlotte, NC 28216
750 -1,000
Wellhouse observed; no one home, MCDEP
database Indicates well an property
4216 Kitty Drive
•5
tyndi J. Boone
4216 Kitty Drive
Charlotte, NC 28216
750 -1,000
No wellhouse observed, access to property
restricted, MCDEP database indicates Well on
nroperty
6
4208 Kitty Drive
Charles D. Webb
4208 Kitty Drive . •
Charlotte, NC 28216
750 - 7,➢00
Observed welt, no one home, MCDEP database
•
Indicates welt an property
7
4126 Kitty Drive
Ronald B. Griffin, Sr.
16732 Leeward Lane
tfuntersville, NC 28076
750 -1,000
Wetihouse observed, access tO property
restricted, MCDEP database indicates well on
mmnerty
8
•
5233 Mettles Fond Road
Devrey W. a Carolyn H. Craig
es Ford Hoed
5233 charlBeatotte.
Charlotta. HC 28216
750 -1,000
Spoke to owner, well used for potable water
9
5308 kettles Ford Road
Ronald Lee Cunmings
5308 Beott}es Ford Road
Charlotte. NC 28216
750 - 1,000
•
Spoke to owner, well used for potable water
10
5300 Beatties Ford Road
Adam Barnes, Jr.
5309 Hearties Ford Road
Charlotte, NC 28216
750 -1,000
Connected to municipal water, well used for
irrigation purposes
11
4028 Sunset Road
Sunset Road Associates TWO,
LLC
10737 Independence Pointe
Parkway, Suite 103
Matthews, NC II1105.2745
250.500
Weilhouse observed, property unoccupied,
MCDEP database does not indltate welt on
P►trpeay
12
1
5040 Berates Ford Road
•
•
Estate o! J.C. 8rooksirir�e
P.O. Sox 668123
Charlotte, NCI826645173
0 - 250
_
Otd Store Site - WeRhausa not observed,
occupant stated, that building usesmunlclpat
water, MCDEP database Indicates well an
_roae►ty

Table 1:
Receptor Survey Summary
Riker Property, Incident 9 21451
5100 Beattles Ford Road
Charlotte, Mecklenburg County
• SEX Project # 1354.03.509
1111
IC/
131 4209 Kitty Drive
3006 Beattles Ford Road ,
4924 Beanies Ford Road
5009 Sentties Ford Read
5309 Beanies Ford Road
4117 Kitty Drive
4201 Kitty Drive
Mfchaef R. 8: 0ufeda C.
Bradley
13825 Scotties Ford Road
Charlotte, NC 2B07e
6010 Windy Knoll We
Charlotte, HC 2P217-938Z
Roo! Martin Rappe
WR Enterprises, LLC
Estate of Mites A. Hilton
Daniel L-'Et Kimberly M.
Ballard
5D49 Beatties Ford Road'
Charlotte, NC 28216
Sherry T. Jones
3024 Colvard Parkway
Charlotte, NC 28269.8637
3906 Tam 0 granter Road
Kemersvilie, NC 27284
4201 Kitty Drive
Charlotte, NC 75216
cltra
250 - 500
500 - 750
250.500
4223 Kitty Dave
Charlotte, NC 28216
•`780 • taoo
.750 -1,000
occupant states that bulldin8 uses municipal
Water, no well observed on property
Wellhouse observed, no one home, MCDEP
database does not Indicate well on property.
Wellhouse observed, no one Now; MCDEP
database does not indicate welt on property
750 -1,000
750'-1,00D
tip wellhousevbserred, no one home, MCDEP
indicates well on property
Wellhouse observed, no one home, MCDEP
database indicates well on property
No welthouse observed, no one home, MCDEP
trtdicates well on property
Property is vacant MCDEP Indicates -well on
property • .

Michael F. Easley, Governor
Wdliarn G. Ross Jr., Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E. Director
Division of Water Quality
August 21, 2006
Scott Bortz
200 Providence Road, Suite 106
Charlotte, NC 28207
Subject: Acknowledgement of Application No. W10300111
Injection in Situ Groundwater Reniediation Well (5I)
Mecklenburg
Dear Mr. Bortz:
The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit
application and supporting materials on August 18, 2006. This application package has been assigned the number
listed above and will be reviewed by Qu Qi.
The reviewer will perform a detailed review and contact you with a request for additional information if necessary.
To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in
providing a timely and complete response to any additional information requests.
Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final
action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days
after receipt of a complete application.
If you have any questions, please contact Qu Qi at 919-715-6935, or via e-mail at qu.gi(Jncmail.net. If the reviewer
is unavailable, you may leave a message, and they will respond promptly. Also note That the Division has
reorganized. To review our new organizational chart, go to http:l/h2o.enr.state.nc.us/documents/dwq orgchartod£
PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS
PROJECT.
Sincerely,
for Debra J. Watts
Supervisor
cc:
Regional Office, Aquifer Protection Section
David Wagner, Senior Consultant - CIayton Group Seivices
Permit Application File W10300111
l Carolina
Aquifer Protection Section 1636 Mall Service Center Raleigh, NC 27699-1636 Telephone: [phone]
Internet: www,ncwatencua[ty.or9 Location: 2728 Capital Boulevard Raleigh, NC 27604 Fax 1: [phone]
Fax 2: [phone]
An EqualOpportuniylAtfirrnativaAdicnEmployer-5D%Retycledf10%PostConsurnerFacer Customer Service: [phone]

Manta F. Easley, Governor
William G. Rasa Jr., Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Xlimek, P.E. Director
Division of Water Quality
September 11, 2006
Mr. Scott Bort
Sunset Southstar
200 Providence Road, Suite 106
Charlotte, NC 28207
Subject: Injection Well Permit Application
Site of Proposed Walgreen Store 410275 — LUST Incident # 8789
5040 Beatties Ford Road, Charlotte
Mecklenburg County, North Carolina
Permit Number: WI030011 I
Dear Mr. Bort:
We have reviewed your Injection Well Permit Application for the subject site, and
determined that additional information is needed before we can finish our review. Please provide
additional information listed below:
1) The proposed monitoring plan is not sufficient. The proposed injection fluid has the
potential to react with the underground utility and/or soil and release metals to the
groundwater. The purpose of the groundwater monitoring is not only to evaluate the
effectiveness of the proposed rernediation plan, but also to monitor potential impact on the
groundwater quality. Traditionally, for sites where strong oxidants are injected, we require
the following parameters be analyzed: Field parameters:: pH, temperature, conductivity,
oxidation-reduction potential (ORP), dissolved oxygen; Laboratory analyses: Metals 3030C
(As, Cd, Cr, Fe, Hg, Na, Pb, Cu, and Ag), sulfate, VOCs by EPA Methods 6260. Sampling
frequency: baseline sampling before injection, one month after injection, quarterly sampling
thereafter until the sampling results show that the reactions are complete and geochemical
conditions return to the pre -injection state. Please provide a modified monitoring plan.
2) Provide an updated water supply well survey report. For the pilot injection test, a five
hundred (500) feet radius water supply well survey should be conducted and results
submitted to us. For the full-scale injection, a water supply well survey within one thousand
five hundred (1,500) feet radius should be conducted.
iu lri
Cain
Aquifer Protection Section 1636 Mail SerYice Center Raleigh, NC 27699-1636 Phone [phone] Customer Service
Internet httpl/h2o.enrstate.ue.us 2728 Capital Boulevard Raleigh, NC 27604 - Fax [phone] •
Fax [phone] Antt �� 1
Equal Opperluntiy/Atiurnatnie Aeon Employer— 50% Recycled/10% Past CarsumetPaper t rs W ‘ t 3re�

WI0300111
Page 2 of 2
09/11/200s
We appreciate your effort and cooperation on this project. Please do not hesitate to call me if
you have any questions about this letter.
Sincerely,
QuQi,PG
UIC Program Manager
cc: Mooresville Regional Office
David Wagner — Clayton, 297 Highview Dr., Chapel Hill, NC 27517
Permit Application File WI0300111

3380.Chastain Meadows Parkway
Suite 300
Kennesaw, GA 30744
770.499.7500
Fax 770.499,7511
September 19, 2006
Atttn: Mr_ Qu Qi, PG
Program Manager
UIC Program
Aquifer Protection Section
North Carotma DENR-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
Ckiyton
.. GROUP SERVICES
Clayton Project No, 99008-006118
Subject Submittal of "Modified Attachments E & P for the szApplication for
Permit to Construct and/or Use a Wells} for Injection"
Old Store LUST Incident #8789
5040 Bealties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beanies Ford Road and Sunset Road, Charlotte. North Carolina
Dear Mr. Qi:
As per your latter dated September 11, 2008, enclosed please find two copies of
'Modified Attachments E 8 i = for the 'Application for Permit to Construct and/or Use a
Well(s) for Injection' for the above referenced site. The application for permit includes
the Implement of a field pilot study to evaluate the use of sodium persulfate as a
remedial method.
Clayton, on behalf of Sunset Southstar, would greatly appreciate your quick approval of
this application so that the redevelopment of this property can proceed without delay. In
the interim, if you have questions, please contact me at 919 960-6289.
Sincerely,
Clayton Group Services, inc.
A Bureau Yentas Company
David Wagner
Senior Consultant
Atlanta Regional Office
cm Mr. Randy Hance. Sunset Souther
attachment
www.daytongrp.com
Environmental Services • Occupational Health and Safety • Laboratory Services

MODIFIED ATTACHMENTS E & F' — SECTION V
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)
FOR INJECIION
Type 51 Wells —In Sim Groundwater Remediation
Old Store LUST Incident (#8789)
5040 Beatties Ford Road
Site of Prinposed Walgreen Store #10275
SEC of Wattles Ford Road and Sunset Road
Cbsur1otte, North Carolina
September 19, 2006
Clayton Project Number 9900E-0U6118
E. Monitoring Plan
Prior to injection of persuIfate, an electrical conductivity probe will be used to acquire
background levels of electrical conductivity through the target zone (i.e. from 14 to 30
feet bgs). This testing will be conducted at the infection location, prior to installation of
the injection wells. Once the injections have been completed, the vertical and lateral
distribution of the peisnlfate using the conductivity probe will be assessed. The electrical
conductivity measurements, in the presence of persuulfate, will be elevated significantly
from background readings and therefore conductivity measurements vertically and
laterally will provide information on the radius of influence and the vertical clistribution
oldie persulfate.
In addition to electrical conductivity testing, starch iodide test kits will be used to test
groundwater within the monitoring well. The starch iodide test is a quick and reliable
visual field technique to indirectly test for the presence of persulfate. Upon contact with
per, the starch iodide solution will turn bright blue.
Also prior to the injection, a groundwater sample will be collected from the newly
installed monitoring well for analysis of VOCs (using USEPA Method 8260), sulfate, and
Metals inchiding As, Cd, Cr, Fe, Hg, Na, Pb, Cu, and Ag (using Method 3030C). A
North Carolina -certified laboratory will perform the analysis. In addition, field
parameters including depth to groundwater, pH, oxidation-reduction potential (ORP),
temperaivae, dissolved oxygen (DO), and conductivity will also be measured during the
pre -injection sampling event. Post -injection groundwater monitoring will be conducted
approximately 24 hours, two weeks, and one month after the injection is complete, then
quarterly thereafter until sampling results show that the reactions are complete and
geachenical conditions return to the pre -injection state. The post -injection analysis will
Modifications to Attachments E a$ F per letter from NCDENR's Aquifer Protection Section dated
September I1, 2006.

Moll ed Attachments E dtF— Section V
Application fur Injection Pilot Study
Old Stoic LUST incident
Proposed Walgeen Stare #10275
Charlotte, NC
be the same as the pre -injection analysis, including the in -direct measurement o£
per.
F. Wef Data
A 500 ft-radius water well survey was completed during week ending September 22,
2006. This survey included contacting (via f mile and through the infant) the
Charlotte / Mecklenburg County Utilities Authority, New Services Department and the
Mecklenburg County Environmental Health Department to evaluate if the properties
within a 500-ft radius of the subject property are on city -supplied water or have registered
wells, respectively. The information obtained from these two departments indicated that
the properties surrounding the subject property (within a 500 ft radius) are on city -
supplied water and that these are no wells currently registered within this area. The area
searched is shown on the attached map.
One rnonitoaing well, designated as MW-2, currently exists on the subject property. It is
believed that this well was -installed as part of the initial investigation of the 5040 Beanies
Ford Road Old Store LUST incident back in the early 1990's. It is ronstmcted of 1-inch
PVC and is approximately 19.5 feet deep. The depth of the screened interval is unknown.
During January 2006, the depth to water in this well was measured at 18.6 feet below the
top of the casing, with approximately one foot of water in the well. Apparently, this well
was not installed deep enough to adequately monitor the water table, therefore its use as a
reliable and adequate monitoring pointi •'�-=}t''040
is questionable. ```+ '�� CAr

•
•
• •
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. • . .
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•
. •

Michael P. Easley. Governor
Willman o. Ross Jr.. Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E. Directed
Division of Water Quality
October 11, 2006
Mr. Scott Bortz
Sunset Southstar, LLC c/o Tribek Properties
200 Providence Road
Spite 106
Charlotte, NC 28207
RE: Issuance of Injection Well Permit WI0300111
Dear Mr. Bortz:
In accordance with the application submitted on August 18, 2009, we are forwarding permit
number WI0300111. This permit is for the injection of sodium persulfate for petroleum
hydrocarbon oxidation at the Proposed Walgreen Store #10275 at 5040 Beatties Ford Road in
Charlotte, NC.
This permit shall be effective from the date of issuance until September 30, 2008, and shall be
subject to the conditions and limitations stated therein, including the requirement to submit a
final project evaluation as stated in PART VII — MONITORING AND REPORTING
REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance
requirements of the permit. You will need to notify this office by telephone 48 hours prior to
initiation of operation of the facility. In order to continue uninterrupted legal use of the injection
facility for the stated purpose, you must submit an application to renew the permit 120 days prior
to its expiration date.
If you have any questions regarding your permit please feel free to contact me at [phone].
Sincerely,
Peter Pozzo
Hydrogeologist
cc:
IIMMINPRINIMGroup Services
Andrew Pitner, Mooresville Regional Office
Sharon Ghiold, UST FIT
CO-UIC files
Enclosure
Aquifer Protection Section 1636 Mail Servite Center Raleigh, NC27699-1636
1ntanet: wwvt newstteauaritv.orR Location: 2728 Capital Boulevard Raleigh, NC 27604
An Equal OppomrtJt /Affmni 1tve Ac6la, Employer- SO% Rerial:00% Post Consumer Paper
Telephone: [phone]
Fax 1: [phone]
Fax 2: [phone]
Customer service: [phone]

NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
RALEIGH, NORTH CAROLINA
PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION
In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and
other applicable Laws, Rules, and Regulations
PERMISSION IS HEREBY GRANTED TO
Sunset Southstar, LLC c/o Tribec Properties
FOR THE CONSTRUCTION AND OPERATION OF TYPE 51 INJECTION WELLS, defined
in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject sodium persulfate,
for oxidation of petroleum hydrocarbon contamination as a pilot study. These injection
wells/points will be located at the Proposed Walgreen Store #10275 at 5040 Beatties Ford Road,
Charlotte, Mecklenburg County, North Carolina, and will be operated in accordance with the
application submitted August 17, 2006, and in conformity with the specifications and supporting
data submitted, all of which are filed with the Department of Environment and Natural Resources -
and are considered a part of this permit.
This permit is for Construction and Operation only, and does not waive any provisions of the
Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an
injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C
.0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and
use.
This permit shall be effective, unless revoked, from the date of its issuance until September 30,
2008, and Gball be subject to the specified conditions and limitations set forth in Parts I through
X hereof.
Permit issued this the I / t day of QG pit! 2006.
cc4,
Alan W. Klimek, Director
Division of Water Quality
By Authority of the Environmental Management Commission.
Permit No. W10300111
ver_4105 AP/t fC-6
PAGE 1 OF 7

PART I - WELL CONSTRUCTION GENERAL CONDITIONS
1. The Permittee must comply with all conditions of this permit and with the standards and
criteria specified in Criteria and Standards Applicable to inj ection Wells (1 SA NCAC 2C
.0200). Any noncompliance with conditions of this permit constitutes a violation of the
North Carolina Well Construction Act and is grounds for enforcement action as provided for
in N.C.G.S. 87-94.
2. This permit shall become voidable unless the facility is constructed in accordance with the
conditions of this permit, the approved plans and specifications, and other supporting data
3. This permit is valid only for construction of the number of injection wells described in the
application and other supporting data. Construction of additional injection wells mast be
approved in advance by the Aquifer Protection Section.
4. Each injection well shall not hydraulically connect separate aquifers.
5. Each injection well shall be constructed in such a manner that water from land surface cannot
migrate into the gravel pack or well screen.
6. Each injection well shall be secured to reasonably insure against iinaiithorized access and use.
Each well shall be permanently labeled with a warning that it is for injection purposes and the
entrance to each well must be secured with a locking cap.
7. Each injection well shall be afforded reasonable protection against damage during
construction and use.
8. Each injection well shall have permanently affixed an identification plate.
9. Within 30 days of completion of well construction, a completed Well Construction Record
(Form GW-1) must be submitted for each injection well to:
Aquifer Protection S ection UIC Staff
DENR Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
PART II - WELL CONSTRUCTION SPECIAL CONDITIONS
1. At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall
notify the Aquifer Protection Section -Underground Injection Control (MC) Central Office
staff, telephone number [phone] and the Mooresville Regional Office Aquifer
Protection Section Staff, telephone number [phone].
CAW,Pl c r �,s3,.� It71lY�D� .1.CUtr/il -4ALikle-e
4 r-�
140fla
�.a eFor LAO—/ Offf v1 i [ f /err Als .
_ .A;'
Permit No. W10300 111 PAGE 2 OF 7
rror.4/05 AP/UIC-5

PART III - OPERATION AND USE GENERAL CONDITIONS
1. This permit is effective only with respect to the nature, volume of materials, rate of injection,
and number of injection wells as described in the application and other supporting data.
2. This permit is not transferable without prior notice to, and approval by, the Director of the
Division of Water Quality (Director). In the event there is a desire for the facility to change
ownership, or there is a name change of the Permittee, a formal permit amendment request
must be submitted to the Director, including any supporting materials as maybe appropriate,
at least 30 days prior to the date of the change.
3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying
with any and all statutes, rules, regulations, or ordinances which may be imposed by other
local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this
permit does not imply that all regulatory requirements have been met.
PART IV - PERFORMANCE STANDARDS
1. The injection facility shall be effectively maintained and operated at all times so that there is
no contamination of groundwater which will render it unsatisfactory for normal use. In the
event that the facility fails to perform satisfactorily, including the creation of nuisance
conditions or failure of the injection zone to adequately assimilate the injected fluid, the
Permittee shall take immediate corrective actions including those actions that may be
required by the Division of Water Quality such as the repair, modification, or abandonment
of the injection facility.
2. The Permittee shall be required to comply with the terms and conditions of this permit even if
compliance requires a reduction or elimination of the permitted activity.
3. The issuance of this permit shall not relieve the Pem ittee of the responsibility for damages to
surface or groundwater resulting from the operation of this facility.
PART V - OPERATION AND MAINTENANCE REQUIREMENTS
1. The injection facility shall be properly maintained and operated at all times.
2. The Permittee must notify the Division and receive prior written approval from the Director
of any planned physical alterations or additions in the permitted facility or activity not
specifically authorized by the permit.
3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for
injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central
Office staff, telephone number [phone]. Notification is required so that Division staff
can inspect or otherwise review the injection facility and determine if it is in compliance with
permit conditions.
Permit No. WI0300111 PAGE 3 O1 7
ver.4/05 AP/UIC-6

PART VI - INSPECTIONS
1. Any duly authorized officer, employee, or representative cif the Division of Water Quality
may, upon presentation of credentials, enter and inspect any property, premises, or place on
or related to the injection facility at any reasonable time for the purpose of determining
compliance with this permit, may inspect or copy any records that must be maintained under
the terms and conditions of this permit, and may obtain samples of groundwater, surface
water, or injection fluids.
2. Department representatives shall have reasonable access for purposes of inspection,
observation, and sampling associated with injection and any related facilities as provided for
in N.C.G.S. 87-90.
3. Provisions shall be made for collecting any necessary and appropriate samples associated
with the injection facility activities.
PART VII - MONITORING AND REPORTING REQUIREMENTS
1. The proposed monitoring plan included in the application shall be followed. All sample
results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office
and the Raleigh Central Office. Any monitoring (including groundwater, surface water, or
soil sampling) deemed necessary by the Division of Water Quality to insure surface and
ground water protection, will be established and an acceptable sampling reporting schedule
shall be followed.
2. The Permittee shall produce a final project evaluation within 9 months after completing all
injection -related activity associated with the permit application. This document shall assess
the injection projects finding in a written summary. The final project evaluation shall also
contain monitoring well sampling data, contaminant plume maps and potentiometric surface
maps.
3. The monitoring results and the final project evaluation shall be submitted to:
Aquifer Protection Section-UIC Staff
DENR-Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
and to:
Aquifer Protection Section
DENR-DWQ Mooresville Regional Office
610 East Central Ave.
Mooresville, NC 28115
Permit No. W10300111 PAGE 4 OF 7
ver.4/05 AP/UIC

4. The Permittee chalk report by telephone, within 4S hours of the occurrence or first knowledge
of the occurrence, to the Mooresville Regional Office, telephone number [phone], any
of the following:
(A) Any occurrence at the injection facility which results in any unusual operating
circumstances,
(B) Any failure clue to known or unknown reasons, that renders the facility incapable of
proper injection operations, such as mechanical or electrical failures.
5. Where the Permittee becomes aware of an omission of any relevant facts in a permit
application, or of any incorrect information submitted in said application or in any report to
the Director, the relevant and correct facts or information shall be promptly submitted to the
Director by the Permittee.
6. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take
such immediate action as may be required by the Director.
PART VIII - PERMIT RENEWAL
In order to continue uninterrupted legal use of the injection facility for the stated purpose, the
Permittee must submit an application to renew the permit 120 days prior to its expiration date.
PART IX - CHANGE OF WELL STATUS
1. The Permittee shall provide written notification within 15 days of any change of status of an
injection well. Such a change would include the discontinued use of a well for injection. If a
well is taken completely out of service temporarily, the Permittee must install a sanitary seal.
If a well is not to be used for any purpose that well must be permanently abandoned ;
according to 15A NCAC 2C .0113, Well Construction Standards. -
_�—
2. When operations have ceased at the facility and a well will no longer be used foiiy ;-- -
puzpose, the Permittee shall abandon that injection well in accordance with the procedures
specified in 15A NCAC 2C .0113(b), including but not limited to the following:
(A) All casing and screen materials may be removed prior to initiation of abandonment
procedures if such removal will not cause or contribute to contamination of the
groundwaters.
(B) The entire depth of each well shall be sounded before it is sealed to insure freedom
from obstructions that may interfere with sealing operations.
(C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines
that failure to do so could lead to the contamination of an underground source of
drinking water.
Permit No. WI0300111 PAGE 5 OF 7
ver.4/05 AP/UIC-6

(D) Drilled wells shall be completely filled with cement grout, or bentonite grout which
shall be introduced into the well through a pipe which extends to the bottom of the
well and is raised as the well is filled.
(E) In the case of gravel -packed wells in which the casing and screens have not been
removed, neat -cement, or bentonite grout shall be injected into the well completely
filling it from the bottom of the casing to the top.
(F) In those cases when, as a result of the injection operations, a subsurface cavity has
been created, each well shall be abandoned in such a manner that will prevent the
movement of fluids into or between underground sources of drinking water and in
accordance with the terms and conditions of the permit.
(G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified
in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment.
3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to:
Aquifer Protection Section-UIC Staff
DENR Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
PART X — WORKER PRECAV'ITONS DURING APPLICATXON
1. Some effects reported to be associated with exposure to the proposed chemicals are as
follows: Exposure can cause severe irritation and burning of eyes, skin, nose and throat.
Inhalation exposure can cause coughing, wheezing, and/or shortness of breath including
asthma-Iike allergy. Future exposure can cause asthma attacks with shortness of breath,
wheezing, cough, and/or chest tightness. Inhalation exposure can cause severe respiratory
irritation and inflammation leading to shock, coma, and seizures. •
2. Chemicals proposed for use may ignite combustibles such as wood, paper, oil, etc. The
chemicals proposed for use must be stored separately from hydrazine and organic
monomers since violent reactions can occur. The chemicals proposed for use are not
compatible with reducing agents; powdered metals; strong bases such as sodium
hydroxide and potassium hydroxide; alcohols; and hydrocarbon fuels.
3. Store in tightly closed containers in a cool, well -ventilated area away from moist air and
combustibles. Containers may explode when heated, Runoff may create fire or explosion
hazard. Chemicals proposed for use heat up spontaneously when decomposing and could
start fires.
4. If the products are released into the environment in a way that could result in a suspension
of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing),
then pmper.personal protective equipment should be used. The application process
should be reviewed by an industrial hygienist to (1) ensure that the injection process is
done in a safe manner, and (2) ensure that the most appropriate personal protective
equipment is used.
Permit No. W10300111 PAGE 6 OF 7
ver.4/05 AP/UIC-6

S. Persons working with these products should wear goggles or a face shield, gloves, and
protective clothing. Face and body protection should be used for anticipated splashes or
sprays.
6. Rating, drinking, smoking, handling contact lenses, and applying cosmetics should not be
permitted in the application area during or immediately following application.
7. Safety controls should be in place to ensure that the check valve and the pressure delivery
systems are working properly.
S. The Material Safety Data Sheets should be followed to prevent incompatible or adverse
reactions and injuries.
9. Access to the area of application should be limited to workers applying the product. In
order to minimize exposure to unprotected individuals, measures should be taken to
prevent access to the area of application.
Permit No. WI030O 111 PAGE 7 OF 7
ver.4/05 AP/UIC-6

Sodium Persulfate Pilot Study Report
Proposed Wa!green Store #10275
APPENDIX B
SEC of Beattles Ford and Sunset Roads
Charlotte, North Carolina
REDOX TECH, LLC PILOT STUDY REPORT
S:IWaSpreerglPmje iWeel l B Pilot Swoy510275-pf3-2atea07. oc
Project Number 99006-006118

Redox Tech; LLC
Providfrag Innovative Soil and finer Solution
February 8, 2007
Via email
David Wagner
Bureau Veritas North America, Inc.
Phone/Fax:[phone]
email: david.wagner us.bureauveritas.com
RE: Pilot Test at Beatties Ford Road and Sunset Road, Charlotte, NC
Dear Mr. Wagner: - This report provides a summary of the field activities for the pilot test conducted at the
• F •above referenced site during the week of October 23, 2006. Included in this document are
•
- ' - recommendations for full-scale application based on the pilot test findings. The purpose of
the pilot test was to assess the ability of base catalyzed sodium persulfate to treat the
contaminants, of concern (COCs), specifically benzene and ],2-Dichloroethane, which
persist at the site. Analytical results that will be used to help further evaluate the
effectiveness of the pilot study will be summarized when available. The pilot test also
provided information that will be used in full-scale design and implementation.
Well Installation
One nested set of semi -permanent injection points were installed targeting a zone from 15
to 30 feet bgs. These injections points were installed using a Geoprobe direct push drill rig
and constructed with %-inch diameter PVC materials. Screens were set from 15 to 20 (IP-
S), 20 to 25 (IP-M), and 25 to 30 (IP-D) feet bgs, respectively. A sand pack was installed
around each well screen and sealed to surface using a portland cement grout. These wells
were spaced approximately 1.5 feet apart and were used to deliver the base activated
sodium persnlfato to the target zone(s).
One monitoring well was installed at a distance of 6 feet from the injection points (PM-
1). This well was constructed of 1-inch diameter PVC screen and riser, and installed using
a Geoprobe direct push drill rig. A sand pack was placed around the well screen, extending
approximately 1-foot above the top of the well screen, and sealed to ground surface using a
portland cement grout. The screen was positioned across the saturated zone, from
approximately 20 to 30 feet bgs. Figure 1 shows the relative layout of the wells at the site.
In addition, copies of the Non Residential Well Construction Records are provided, which
were submitted to the North Carolina Department of Environmental and Natural
Resources.
Sodium Persulfatee Iniections
900 gallons of solution consisting of 1,705 pounds of sodium persulfate and 30 gallons of
25 percent by weight sodium hydroxide solution was injected into the three injection
points. The volume of solution injected into each well is summarized in Table 1 and also
on the injection log sheets provided. The total mass of persulfate used was based on a total
1441 BRANDING LANE, STATE 100. DOWNERS GROVE. IL 60515 TEL 630.5I5.1810 FAX [phone]
WWW.REDOX-TECFLCOM E-MAIL A+ fARK.ESIC@REDOX TECH.COM

February 8, 2007
Pilot Test Repot, Cherlone, NC
Page 2of6
oxidant demand (TOD) value of 9.9g/kg. This TOD value was the highest TOD value
reported from analysis of site -specific soil samples sent to Redox Tech in January 2006. A
copy of this report is provided.
At the higher pressure and flow rates, fluid was observed to come up around the injection
well. This is also referred to as "blow -by". By reducing the injection pressure and flow
rate the blow -by was controlled..
Injection of persulfate solution into IP-S and IP-M resulted in daylighting of fluids to
ground surface at various locations within approximately 5 to 6 feet of these two injection
points. Injection into IP-S was performed initially with daylighting occurring after 50
gallons was injected. Subsequent injections at lower pressures also resulted in daylighting
at the same location. Daylighting of fluid while injecting into IP-M occurred in the same
location as IP-S, indicating that the two flow paths intersected. Daylighting occurred after
25 gallons of solution was injected into IP-M.
Daylighting also occurred during injection into IP-D after approximately 650 gallons had
been injected. It is estimated that a total of approximately 50 gallons of solution was lost at
surface due to the daylighting while injection into IP-D. The injection volumes are
summarized in Table 1.
Persulfate Distribution
Two qualitative techniques were used to assess the distribution of the sodium persuflate
within the subsurface. The first method involved testing the groundwater within
monitoring well PMW-1 for the presence of sodium peasulfate. This was performed using
a starch iodide test kit. In the presence of persulfate, the starch iodide solution rapidly
turns dark blue. Results from this screening indicated that persulfate was present in the
monitoring well, located approximately 6 feet from the injection points. This suggests that
a radius of influence of 6 feet is possible with the injection pressures and volumes used
during the pilot study. Temporary monitoring wells were also installed at locations PI4
and PI5 (Figure 1). Groundwater sampled from these wells also tested positive for sodium
persulfate, indicating that the persulfate solution was dispersed radially from the injection
point a minimum of 5 to 6 feet.
An electrical conductivity (EC) probe was also used to assess the distribution of sodium
persulfate. Electrical conductivity measurements, in the presence of persulfate, are
elevated with respect to background Levels, and therefore provide evidence of persnIfstt
distribution both vertically and horizontally from the injection points. The EC probe was
advanced during monitoring well construction at locations CGS1 (at PMW-1) and CGS2
(at IP-D) (Figure 1), and provided background readings. Subsequent to the persulfate
injections, the EC probe was advanced at locations immediately beside the injection points
(PI1), and at various distances and directions from the injection points (PI2 through P15).
PI2 was advanced immediately adjacent to PMW-1.
All EC plots are attached to this report. Background EC plots from locations CGSI and
CGS2 are fairly consistent with one another, showing stable conductivity values from
Redas Tech LLC

February 8, 2007
Pilot Tcst Rcpart, Charlotte, NC
Page 3 of 6
ground surface to approximately 16 feet below ground surface, and from approximately 21
to 28 feet below ground surface. Significant spikes are observed in the 16 to 21 foot range
at both locations. In addition, both plats show an increase in conductivity near the bottom
of the boring at approximately 28 feet.
Post injection EC plots at locations IP-D and PMW-1 (identified as PI1 and P12,
respectively) show significant increases in conductivity across the entire soil column. Near
injection location LP D, EC readings in excess of 10,000 mSlm are observed at
approximately 4, 14, and 29 ft bgs. Significantly elevated readings are observed
throughout the soil column in zones 15 to 20, 20 to 25, and 25 to 30 ft bgs. This is
consistent with the screened intervals of the injection points and suggests that the injections
were successful at vertically distributing the persulfate through the soil column. EC
readings adjacent to PMW-I show vertical distribution of persclfate as indicated by the
elevated EC readings within the upper 5 ft, at the 10-foot zone, and from 15 through 20
feet bgs. Elevated readings in the upper 5-foot zone are consistent with the daylighting
observations that were made during injections.
EC measurements collected at location P13 show a significant rise in conductivity in the
zone from 30 to 35 feet bgs. Although these elevated readings may indicate the presence
of persulfate, there were no background readings collected at these depths to confirm that
this is the case.
During advancement of the EC probe at location PI5, it was discovered that the probe line
was cut, therefore providing erroneous data. It is also possible that this line was damaged
during the advancement at location PI4 and was simply not identified. Therefore, these
two data sets were not used in assessing the persulfate distribution, but instead as
mentioned previously, starch iodide tests at these two locations indicated the presence of
sodium persulfate.

February 8, 2007
Pilot Test Report, Charlotte, NC
Page 4 of 6
Beanies Ford Rd.
Sunset
■ 4-$- ' w ,i IP 1
A IP-DLG3521/11
CORM '
`@ (Sat 0'Temp
3D'a�ithlD'
IFSA
•PI5 (EC Plate Lila Cut — Set 'l:"PYC
Tema Wall 24' with 5' semaa)
• Mee erreeViroII(1-11ianettsPYC).
Iajxri'a Paints (3—ShaIIey,15 to 2D ft b7)
(111—brt 22 to 25 ft bp)
(D —Dcep; 25 to'2€18 bss)
IIeesazlCoMactivrty bansc9atPilthcmcltPl5
Pe fate test Its ux3 e2 PrI,PI4aodPIS
N at to Stale
Conclusions
The data collected during the pilot test injections indicates that persulfate was apparently
successfully distributed within the target zone, radially from the injection points.
Daylighting was observed to occur during the injection process, but may be controlled by
reducing pressures and flow rates. Since the formation is inherently heterogeneous, these
occurrences may or may not occur in other locations at the site.
Based on the pilot test injection results, Redox Tech concludes that a minimum injection
well spacing of 15 feet would be adequate to properly distribute the chemical amendment
at the site.
In addition, well screen lengths of no more than 5 to 7 feet should be used and positioned
to maximize the vertical distribution of the amendment The positioning of the wells
screens should be determined based on the location of the water table. The static water
table in this area of the site has been observed at approximately 16 to 18 ft bgs. Therefore,
it is concluded that multiple injection points could be used to properly disperse the solution
vertically across the target zone.
Installation of the injection wells can be done "sing a Geoprobe drill rig similar to the pilot
test approach. A bentonite grout should be used to seal the injection points to minimize the
chance of "blow by" from occurring.
Redox Tech, LW c

February 8, 2007
Pilot Test RepChary NC
page 5 of 6
Please feel to contact me with any questions or concerns relating to material presented in
this report.
Regards,
Steve Markesic

2/14/24D7
Pilot Tcst Report, Chedottc, NC
Page 6 of 6
Injection Location
Screen Depth
(ft bgs2
Injection
Pressure'` (psi)
Flow Rate
(gpm)
Injected Volume
(gallons)
'Comments
IP-S
A
15 to 20
50
1.67
50
Daylighting approx. 5
feet from injection
point
40
2.1
15
Daylightcd at same
location
IP-M
20 to 25
40
N/A
25
Daylightcd at same
location as IP-S
IP-D
25 to 30
60
5
35
Blow -by around IP-D
20
2.5
365
at —35 gallons
40
2.5
100
40
3.6
110
40
3.6
200
Began daylighting at
approximately 650
gallons _
"Actual injection pressure is twice the value meatd on the injection lag sheets
Redax Tech, LLC

APPENDIX A
Injection Log Sheets and Non Residential Well Construction Records

Redox Tech, LLC Data Coilection Sheet (oxidant)
Date:
10/24/2006
Data Taker:
JC
Page 3 of 3
Client:
CGS
Site Name:
°softies Ford Rd
Location: Charlotte, NC
lig.Trailer
Columbia
Rig,type:
6610
Int Tool:
PVC well
Pipe Diam:
3/4"
Point name:
IP-S
Point toe;
Ref. Point
Fluid Iniected:
Sodium Persulfate
Fluid Conc.:
16 bags/400_gal
Location
Steam Unit Serial #:
15 gal NaOH ,
Date/Time
Point/Depth (ft bgs)
Flow rate (gpm
or strokes/min).
Injection Pressure
(pst)/Temp (deg)
Notes (flow change, etc.)
1230
20'
15/20
1300
screened 151-20'
1.67.gpm
DL —5' away OD 50 gal Injected
1504
20/40
1511
2.1 gpm
DI_ 15 gal injected
55 gel injected total
galroPaxliiiPt0Z241
•
noose drop oll or r.ant to 1006A MOirisinhe Parkway, MorniANTIC

Redox Tech, LLC Data Collection Sheet (oxida
Date:
101241200E
Data Taker:
JC
Page 2 of 3
Client:
CGS
Site Name:
Besides Ford Rd
Location: Charlotte, NC
Inj.Trailer:
Columbia
Rig type:
0610
In]. Tool:
PVC well
Pipe Diem:
3/4"
.
Point name:
IP-M
Point lac:
Ref. Point
Fluid Injected:
Sodium PersulFate
Fluid Conc.:
18 bags1400 gal
Location
Steam Unit Serial #:
15 gal. NaOH
Date/Time
Poinl/Depth (ft bps)
Flow rate (gpm
or strokes/min)
Injection Pressure
(psi)1Temp (deg)
Notes (flow change, etc.)
1316
25'
20/15
daylight same as IP-S
1410
screened 20'-25'
25 gal Injected
1417
15
try again and daylight
1418
•
25 gal injected total injected
Please drop off or sendi'v 100BA Morrisville ParkvWT ornsvilie,
4C-27580 or fax 919..4 O-0211

Redox Tech, LLC Data Collection Sheet (oxidant)
,
Date:
10/24/2006
Data Taker:
JC
Pace 1 of 3 ,
Client:
CGS
Site Name:
Beatties Ford Rd
Location: Charlotte, NC
Inj.Trallor:
Columbia
Rig type:
8610
.
lnJ. Tool:
PVC well
Pipe Dlam:
3/4"
Point name:
IP-D
Point loc:
Ref. Point
Fluid Injected:
Sodium Persulfate
Fluid Conc.:
15 bapa1500 gal
Location
Steam Unit Serial #:
1ga1 NaOH
*
Date/Timo
Point/Depth fft bgs)
Flow rate {gpm
or strokes/min)
Injection Pressure
. (psi)/Temp (deg)
Notes (flow changee, etc.)
915
30'
30/30
922
screened 25-30'
5 gpm
Stop- Newby around IP-D (approx 35 pal ,
929
10/15 to 20
injected)
_
1230
resume injection@, low pressure
1422
20/20 ,
400 sal injected
1501
2.5 gpm
_
100.gaI injected
1513
20/25
1544
3.66 gpm
-110gal injected
1616
20/25
started -1645 but kept pumping
1715
200 gal injected
lost -50 gal to daylighting
5&
Please +rop °Ifo-t aend toifbOOA Morrisville Parkway. Morrisviili
qC 27560 or ax 01-9
2Ti

0.1
NONRESIDENTIAL wru. CONSTRUCTION RECORD
Noah h Oxon= DepartmeniQf Boveronrosat read Natured Beacon- Division of Water Quaky
WELL CONTRACTOR CERTIFICATION 0 3379
1. WELL cO lTRACTO
Jason Ctvotazz1
Wei Contractor ( Tune
RedocTech, LLC.
Wee Orrerezior Company Nome
Sffc:tl AtIDRESS 103 Vera Rd
Lea
SC 29072
Oily ix Tom Stale 4PCode
303 } 205-0360
Amu code- Phoneourrma
2 WELL INFORMATION:
sue%lei ID Cgarctta>Ie) PMW-1
STATE WELL PERM Tv3[tl
OYVC or OTHER PSibilTT d(if ePE f1 W10 99111
WELL 1isE (CheckArnalcaide likeO Morvmring 1D Mera oi>aiIPIC ❑
indeedrieleCorrencesial C Amioadl cal ❑ Recovery 0 Woe= 0
Int7lOmE1 Orrr us* far Oat study
DATE DIU.L.EO 1 012iA6
T E COMPLETED 1:00 AM a] PAf �+
3.Wa3.. LOCAfl01t:
crr Charlotte o Ti hilecklartbUrg
5040 Scathes Ford Raad
pact tiun., awmmR Cammmtl: Lee No. Pomal. Zp Code)
TOPOGRAPHIC/LAND sE TTh 3
139•p dY ORkios 0 Other
wort ageropdale bad
LA-1-mm 35 1 B.2994
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seceolsor
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Lstiludeiineg 1ude sou rcew-,PS DTopographie reap
¢ ow=daver usthedrawnona115GStaxxmapand
stfachfsrl fire loan Trull r+saeg GPS)
4. FACI1JtY-- is >a® nano d s+e I aerer. Where MO Witt 4 ranee.
FACILITY a114 appliieabfe)
Nokia of FPCUJ Y Proposed Walgroen Siore#10275
STREET ADDREss 5040 Beattie s Ford Raad
chrbbe NC 28218
city orTorn Stale $Cods
CONTACT CT PERSON David Wagner PaYtort Group Sam)
MAILING ADDRESS 297 H09hvieve Drive
Chapel Kin NC
CeyorTown Stsm
{ 919 }. 9130-6289
Area code - Ptrxra mjtha
6. WELL DETAILS:
a. TOTAL DEPiit 31?-0"
27517
2rp Cada
b. DOES VIEl.L1L REPLACE E70811N6 WEILT YES ❑ NO t7
a WATER LEVEL. BeimTCp d Cssi 35 FT.
{alss't-tfAN:wetTapoft shgl
d. TOP of CASING Is 0 FT. Above lard Strtecer
'Top r# casing tamed Leta below land nerfice may metre
rradon= in =on:C noe awn 15A NCAC 2C .0113.
e. YIELD tgpm) METHOD 07 TEST
1. COSiti7ECTIOte Typo Armrest
p. WATER ZONES *Oka
Fine 15 ra 30 From To
Fran TO From To
From To Ftar , To
6: CASING:
SeMint
� O °Too"_' ' A.
1 r n To FL
Fran To FL
r. GROUT: Deep Material
pun 0 To-16 Pt. carman!
From To Ft
FAR To FL
& SCE: Depth Dlaoreler Ski Size Materiel
From -20 To -32FL1' is_ 10 In. PVC
From To FL In. ln_
From To _ Pt 0. Err.
B. SANDIGR .VEL PACK:
Depth Shoe. feral
Fri 19 __To IT. #2 sand
Flan' To Ft
From To Ft-
10. DRILLINGS LOG
From To
Verde
11. REMARKS:
Formation De :Motion
see attached tog for SB-2
thated approximately 5 from PMW-1
on 1/17/06
W Scols RUCTEP N ACCORIIVICS vNRI+
STANDARDS, AMDTHAT ACC YOFTi6
IWIEW LLe NEIR.
fOF
1
CONWACMR TE
C /8 .19Z,Z!
PRINTED NAME OF PERSON CONSTRUCTING TIE WELL
Submit tut original to the Division of Water Quality within 30 days. Alin: lnforrehtion Mgt,
11117 Mall Ssrvd= Center Roleigh, NC 27699.1817 Pharr a No. [phone] 4-e:t669.
Farm OW -lb
Rev. 7fd5

NONRESIDENT/AL WELL CONSTRUCTION RECORD
North Cara= Oman of Environment end Natturl Resources -Division of Weisz Quality
WELL CONTRACTOR CERTIFICATION # 3370
I.WELL CONTRACTOW
J s [ want
WU Cmtraolor tiodiduay Name
Redox Tech, LLC.
WeI Contractor Company Nora
STD ADDRESS 103 Vera Rd
Lexington SC 29072
Cliyr ccTOes Stale ZIP Code
r 803 }. 205-0380
Ansucode- Reno number
2. WELL R1RRJRATIOIt
SITE WEIR. to (r>.pcomtI.D i4�S
STATE WELL PEES Ta•{i c iaj
DWG orOTHER I TSiE LW10.TE1D111
WELL USE (Che:lcAp66et hJoltl antra ❑ hluiIpzlPPUic 0
tremsfatilICoromardal4Awlvalmal RYD Irtecron El
trrtal:eII 040<fsta mjacbon
DATE DRILLED 1 0231110�r
TINE COMPLETED 200 Alin PIE
3. WELLLOCAT7Qit
CITY: Charlotte aouNTY Mecklenburg
5040 Beatles Ford Road
{Sisal Ni m Wat>r& Coned rts. Stun. La PAX. Paroa.
TOPOGRAPHIC fIANDSEI (ice
09tcDe ARA plate 0 Olba
tcheacuppoperestet
LATITUDE ,i5_ 18.2994
Lotion AE 80 6/.4807
Nat tom
le a &erred Forma
LaG ell sout='ASS IZIToPograPhicmap
[taaion or>innd be shown on e ZJ S two MVP end
aemdtad to !Ws fom Inot L 19 6PS7
4. FACILITY ssers•rsdie lawkan obsnIe%moisbow.
FACC. r1Y !D *Of appliestrat
NAMEOF p.comu Y Proposed Welgreen SW5110275
STFIEET ASS 5040 Beaches Ford Road
Charlotte WC 28218
Z1N ea' Then State 7p Gam
COl1TAOT PERSON devil Warner {Cle1ton Group Servlp )
toxiLitiaADDRESS 297 ffegtnrlenr Drive
Chapel MI NC 27517
CrlyorTomo State
{ 919 .. 950-5289
AteaWde-.. number
5. anal. DETAILS:
e. TOTALnEPTN: 20.0'
ZIP Code
b. DOES WELL REPLACE MISTING WELL? YES C NQ k7
r- WATER LEVEL 13do s Top of Casba 15 FT:
(Use't rAbomTop ofCasing)
d. TOP OF cASJWG JS t] FT. Above 1st Slate ''
'Top rimming twilled baba laud surfaces may rngIie
6 sabot* hi accordmoevels f5A NCAC 20 .D115.
e. YIELD ism]: WETHOD QPTIST
L D SI F8T)0I TyJ ksnoemt D. WATER ZONES (deplht
FRcm 15 To 30 From To
Fran__ To From To
From To Fiont_TO
L CASI G: TidcbI1
Rum 15 R1
Frop___` To FL
F _To
7: GROUT: note aittaial Method
From_To____
T 12 camera
Fran To FL
From To Ft.
& SCREEPA Dept )gamer Ski Toe Wart
From'15 To 20 R.314' b, 14 In. PVC
Ram
From To FL in_ 6t
a SAIlORrlitAVEL PACIL
Doan Sly hCanna
From -14 To pr. #2 SEMI
Fran To F7.
ROM To FL
1o. ofnumG LOG
From To Farmalion DesortGan
,See attached log for S$-2
same s from IP-S on 1#17105
11. REMARKS:
15A
snrY
it N►9
worpO Ci MAcocrecurZEWIIR
trc-un .t.OWNER-
CONTRACTOR
.Si�1S (t {DPI
PRINTED NAME OF PERSON OOSTRUCTING THE WELL
3Cc:,
•
Submit the original to the Dlvesiol of Water Qua* within 30 [kris. Alin: lnfor naiwn Mgt,
1617 Wall Servil* Canter — Raleigh, NC 27629-1617 Mow Mo. [phone] cod 665.
FismGIN•1b
Rmr_7/05

NON RESIDENTIAL WELL c ONS RJcrfoly RECORD
Wert. C colinau uvflmvuonaurmmdNatise1 Raoeuces-DivisicoofWaifs Quality
WELL CONTRACTOR CERTIFICATION A 3378
I. WELL C fRACTDR:
Jason Ch
WeCar rscmt{btd6814 Nam
Red x TBCI7, 13.C.
WA Cad or Coaaprsir Name
Si Face ADDRESS 103 Vera Rd
Lndraglon SC
29072
C+gaToot State Zp Coda
{ 296-9360
Area DateMote molter
2. WELL INPORMATIOM
SfiEWELL EDIV Epplootont IP-M
STATE WaL PERMITiVomi5GEOIO.
DWQQOTHER PERMIT Rif opoircrElm WI0300111
TIME LISE (Chock apt n tD Municiparublt ❑
telitstraCommereelO Alb ❑ Recanarn L-tackst n
latafccup OIMIX(Est USH anlrCtiaci
DATE swum 40123,05
TIME COMP!-TED 30D AM n PM El
3.WE[L LOCATla*
cffy: Ctasiotle mom Met denburr
5840 Beatles Ford Road
pact maim r+ccioroyt l.St BMi141tNrs.P Cam)
TOPOGRAPHIC !LAND SETTING:
LATITUDE _L5 182994
LONGITUDE 80 51,4807
Mr/ in clegroes,
racuLs„ =comsat
in a dxrraf forma
Latita&ilangitado sots ='{5PS crropographia map
a corian of osirrarst be shown our a USGS topo map and
at schedm Cris farm footeraieQGPM
s FACILITY-b.ee,amem.eGeaics'miretoweddtamm
FACIUTY m t{1
gum OF FACtuTY Proposed Waigraen Store#10275
.E TEEET ADDREss 5940 Beardes Fond Road
Char otter NC 2821
City or Tam Sala Zip Cori:
CONTACT PERSON David Wagnrt (tlaylaa Grpup Sesvica)
IAALLNG ADDRESS 29T Hirtiview Drive
Chapel Hill NC
C y or Tom star
1919 7- 9E4-6289
Aratt code- Phase motes
22517
Zip Code
5.1NELL DETAILS:
a TOTAL DEFILE 25•0'
6. DOES 1r1EU. REPLACE EXXT0 G WELL? YES Ei NO ED
c WATER LEVEL Below Top or CtssInF 15 Fr.
(Llse'4' Ef About Top d Coming)
d. TOP OF CAS= IS D FT. Atc ue Lard Surfaor
'Top of Ong t nat d ati r below laird aufa a afar win
a %radonvs In eCCCIrdieed2 Mal 15A NCAC 2C .4111i
a. YIELD �R METHOD Of TEST
L DISSNFECTIOli_ Typo Arrmutm
WATER ZONES flex
Roam 15 To 30 Fran To
Fran To From To
Prom To From To
6 CASIMG: "yirhti�cldd oI
RPM 0 Ta' R al Apg PYC
Fsar t To FL
Frain To FL
7. GROUT: DermaMittoriol
From 0 To -17 R. Carnal
tie m e
Fran To Ft.
From To Pt
9. SCREE* Dap% DamSid Size WNW
Fran •20 To 25 FL314" to 70 in. PVC
From To FL in_ In.
From To FL in. in.
9. SAIIOEGrRAVE L PACK:
Depth S® Material
From 19 To -25 Ft. #2 sand
Pram To Fr_
Fran To FL
i0. DRILLING LOG
From To
t1. REMARKS:
Formation criptiora
hae Rttached Incittr 58-2
driled appradmrotrt! 5' tram a? -titan 1r17436
Subrstt the original 6o tha Division of Water sty within 30 days, Aura: information MgL.
1617 Wail Stiry ca Contra --Raleigh. NC 27CBS.1617 Phase RN (NB) 7334018 Bard 568.
Form GW-16
Rau 7l05

SQl1 we
qi-M9 (W0
'8-S9 Pre SIOL-£FZ (S1& 'aN ouo>ic! L1.94-669L3 3N 'tibcolo2i —JotmO *!is LI.BL
15iO uoPt1110P :Il Y miell OE 14401DJM UO1el1Ua ela O IU!3P0 pia mui inS
T❑M 3HL
N052l3d AO 3iWN 0
LrOLIVI3LNO3
•
7:17IAPOTOM
SHL AdCOYSYW,OnV im4VG25YJ3
RUM =ifloaa=Oso N m` I!.1400 $51A1
90414 are Iuo1I sANNIErczalm pin*
z-es x41 PBVzusse oss
utoc0=sea uess uraj
pues
ICI
ORd
mraiiliveld
O.L Ward
sal COMM 131
73 d! Luoij
of 11+a1�
Lacul
3
:NOVA lEIMMOIEUIVS 'g
.up •UI 7d a1 insrA
'ai 0 L �A 4l61d 4E' es1 Sy_
=IS IqS ;ell [ MetiO > 5 g
1d nL
7d o�
luewes H ZZ- al 0 1113
RAM :.SIQU9 1.
1:1 o/ coma
aa�� a1. eueu
'
Ie41e�Y7 Neigt s�vamoi 0
Iss.r 11l. :WSW
oL UEJ$ ai 9�3
oL u3 a1 uay
a1 unaj 06 a1 SL u>CLIs
*OM Sal40211301s S
PntotJY •114.41 1193-IK2S10
ISM. 30G CON 11dd J TEIA -
1t11:7z3 3NbSI.IRKc BPr>ccewgsIselma
Lbw lls a awitinspL 111opq 6(4 J cal.
antis purl Y Jd 0 SI EIKISI 9 30 d0.L 13
S1 di:PiM*13M 1 MUM
GI ON CF 53.t ITEM 9[IIL97C3 3oV1dBa rEwl woe 'R
.0-0E 'H144O 30301 'R
:swam 'TEMA
zmursueerram -spas eery
69Z3096
epo3 rt2 c35 1aeol10 40
L19LZ ON LEH IsdetIO
emia M IM16U4 L6Z SS3i30C3tl 9NCI VW
(seotMos time utittEro)1auEBM pica NOS233d 1Q . NOO
4003 d z wet3 Malvin
IRi6Z ON elialle440
P° I see 0009 L a
sap FPS uGJEIBM pasockud AU13Yd AO OWN
9 RaWido AmJJn19tl3
virwol R oge itO lm tveRi ill P ownt rrop q jS tnI d 1'
(SAS 6tfxn;4xq two/ sreff atPagrzefis
pue data sssn a uo amp Q7 07ui11m/a
41310 0E0513296210 SdE/ a511-12130PP1igL
smug irgaPQP sm
1:1'1FTN. An
r _
Losing LS 08 2001112401
y86Z84 cr en
fotiq cffixiciaide zpl>ul
suaa c3 a4PILIO WOK tiacsn❑ arias
:SN11139ONY7lOIHd1 JOdO1
(ti200 d! limand 'TN Fl txdsioupois laasow103 'aloeisurT1 mas)
Peold Pio3 saIIlgag 0005
Nair Q1 TWAT
13 fvd C] 1M4' 00:E O3Jx1dsitra 3YO1
°, Ol -7,101 O311RlC1
uor he Om 1104410 1111 1r1
IE13204 ❑ llsocao'ti 0 P¢rx1l>g11 ❑
Qofflirrasdrfirvi ❑ SuPormIn One ldctt%oe113) 3'Sl T13M
t 1.1.00s0610, Onewid23100 1}J3d see- LO 33 two
i�14 1tk11111V?}ad TI3M 21,VLS
o-dI 1ll4 of ISM MIS
RozireWMO f ► z
,mu=auoe,d -eaoollg14r
09E0-90Z •t-
woo da sinis arnaJ. ko
ZL06Z OS uelbui ai
Rti 1A E0i SSEIZIOov14 14
auieA{Assiut) isPsiloo0 PM
linl91sa1>p& ADIC100
•o-ri 'tineiltaPav
euEN.Outi pull xcluitoo 'rem
Prail:islO timer
4019Y211S07 TWA -c
141011.1131.411.3130 "HOLIVILLMOO TWA
Agallb sin 3o 1 0-mmosaa p txia iszanK10113301roarind2C1Railam0
axw xo any TI M mauraryieioN

3
1
6
8
Date tnwaSed
Wire Company
BY
Dram Methods
Through Surface
Berdr ie Dfemeter
Boring Trim at
Swaying Pcitit
Screened inter
1r17/0B
: Dartd Wear
: Regicerd Probing
:FmeSlag
:2inches
2a
:1•PVC
:0-17feet
1r27feet
Date Measured :1718106
TOG Elevation : 942
Ground Elevation : 03.B
Depth to Groundwater :17.0
Depth to N APL : NA
NAPL Tut : NA
Weather write Dri : Partly canny. 55 degrees
.4hi>,eviction Kay
MR
bOs
KS
ND
: Not Recorded
: NotAppiabe
: Woe Gruad Surfer*
: Not Sampled
: PlD dld net detect organic
: vapors
0
Tim. Colfocted.
DESCRIPTION
n
x
0
2-.-
4—
$-,
s-
J
1�- n
12
14-J
16-�
7
182j DJ
24=
22—'
24
26-
Zg.
1
NS
3
3
7
6
54.
20
13
75
40
1100
1400
500
140
NS
NS
Fma sand
Light blown (stag)with
daffy. mist
Very agbigascarreQce Od3T
SWIdgesOlme-aatodor
Light brown to Tight gray sit with Vida to some day,
most to wet, moderate gaso0ne-titre odor.
Moderate gasoline: Moe odor.
MI_
24-28 R. No recovery of sample.
End of boring at 2.811 tags.
Casing interval
Screened Interval
Proposed Watgreen Stone #1=275
LOG OF BORING SB-2 SEC of Beall/es Ford Road and Sunset Road
• Chartotte, NC
(Page 1 of 1)

10
0
10
15
s
r
25
CGS Charlotte Background
Electrical Conductivity (mSfm!
100 1000
10000
rS1 -Background
"CGS2 - Background

10
0
5
10
15
t 20
p
25
30
40
Cis Ct3 Otte (Pii]
Electrical Conductivity (mSim)
100 1000
10000
--1,CGS1 -Background
�CG52 • Background
P11

10
0
5
10
15
20
25
30
35
40
CGS Charlotte [PIA
EJK61ea1 Conduc*Mty (m51m)
100 1000
10000
�Cfi51 -Background
��CG52 - Background
—}E—Pf2

10 •
0
10
15
r
25
40
CGS Charlotte [P13]
Electrical Conductivity (mslm)
100 1000
10000
-CGSi -Background
�CG52 - Background
--91F-PI3

10
0
5
10
15
20
30
35
40
CGS Charlotte [P141
Electricril Conductivity (cranny
100 1000
10000
1iim'CGS1-Badground
.CGS2 - Background
II-PE4

10
CGS Charlie [P15]
Electrical Conductivity (mS1m)
100 1000
10000
0
1 t
—
5
14
i.
'r.
15
20
25
30
en
II
. i
r�CGS1-8ac cgroand
w•CGS2 - Background
1--P15

10
0a
10
15
CGS Charlotte Total
Electrical Conductivity (mSln)
100 1000
10000
a
i'm'CG S1 -Background
CG52 - Background
PI1
—3(F--P12
TPl3
-PI4
�— P15

{
Redox Tech LI;C
Providing Innovative Soil a d Water Solutions
TOD SAMPLE ANALYSES
Clayton
DATE TITRATED: January 23, 2006
DATE PREPARED: January 19, 2006
SAMPLES RECEIVED: January 19, 2006
OXIDANTS: Sodium Persulfate (50 g/kg dose)
Sample ID Oxidant
98-1 Sodium persulfate
98-2 Sodium persulfate
SB-6 Sodium persulfate
Oxidant Demand
(glkg)
9.0
9.9
7.5
TOD is reported in grams of oxidant per kilogram of saturated sediment material.
TOD preparation and treatment procedure for persulfate is completed per Haselow et al.,
2003. Estimating the Total Oxidant Demand for In Situ Chemical Oxidation Design,
Remediation, Autumn, 2003. Post -treatment titrations for persulfate are completed per
away procedures in FMC Persulfates Technical Information bulletin. Persulfate samples
were catalyzed with sodium hydroxide dose at approximately 8A g/kg.
1006A MORRISVII.LE PKWY. MORRISVLLLE, NC 27560 TEL 9I9.460.0330 FAX [phone]
WWW.REDOX-TECH.COM E-MAIL.: [e-mail]

Sodium Persulfate Pilot Study Report
Proposed Walgreen Store #10275
APPENDIX C
SEC of Beatties Ford and Sunset Roads
Charlotte, North Carolina
LABORATORY ANALYTICAL REPORTS & CHAIN -OF -CUSTODY RECORDS
S'1WalgreeneProjeds1.061191Piloi SNdy110275-ph3-29fe507,doc
Project Number 99006-006118

Pace Analytical Services, inc.
9800 KncsyAvenue, Suite 100
Huntersvill8, NC28078
Phone:[phone]
Far 704.875.9097
November 09, 2006
1r. David Wegner
Clayton Group Services
297 Highvier Drive
Chapel Hill, 1C 27517
RE:" Lab Project ±ai*er3 921307/6
Client Project IDs Walgreene Beettiee Ford Ed
Dear Mr. Wagner:
Enclosed are the analytical remelts for nemple(e) received by the laboratory on October 25, 2005. Results
reported hernia eoaferd to t:Ae met current NELAC standards, where applicable, unless otherwise narrated in the
body of the report.
Inorganic Wet Chemistry and Metals Enalyses were performed at our Paco Asheville laboratory and Organic testing
was performed at our Pace Charlotte laboratory unless otherwise footnoted.
if you have any geeations concerning this report please feel free to content me.
Sincerely,
VI971.111.41Wit
Bonnie McKee
bonaie.mcteeepecelebo.com
[phone] ex:. 234
Project manager
Enclosures
hevilia CertifiCd110a IDS
NC Wastewater 4D
NC Driniin0 Water 37712
SC Envlronmeolat 93330
FL NELAP E117648
REPORT OF LABORATORY ANALYSIS
7h:s report shah eat 0a repro&cr1. mein In t11,
*hoot ttre written consent of Pace Ana i J Santis, Int
Char1otte Certification IDs
NCWasleu aw 12
NC Drinking Water 3T7D6
SC 99006
FL 11ELAP ES7527
F

aeAI1IYflcar
... paodabscom
Pace Analyileal Sernfres, Inc.
98001GnceyAvenue, Suite 100
Huntersville, NC 28078
Phone_ 704.875.9092
Fax [phone]
Lah Project Number: 92136716
Client Project ID: s7algreen8 Beattiee Ford Rd
Lab Semple No: 927597211
Client Sample ID: PMW-1 PRS IN,78CTION
paxametere
Metals
3030C Metals, ICP, Trace
Arsenic, 3030C
Cadmium, 3030C
Chromium, 3030C
Copper, 303DC
Iron, 3030C
Lead, 3030C
Silver, 3030C
Sodium, 3030C
Date Digested
Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Sulfate,Turbidimetric
Sulfate
GC/MS Volatilee
GC/MS VOCS by 8260, low level
Acetone
Benzene
Bromobenzene
Bromochloromethaae
Bromodichloromethane
Bronofarm
Bromomethane
2-eutenene ICE)
n-Butylbenzene
see-Buty1benzaae
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethene
Chloroform
Chloromethane
2-Chlorotuluene
4-Chlorotolueae
pate: 11/os/as
Results
Prep/Method:
ND
ND
8.1
19.
500D
ND
LTD
5600
10/26/06 11:00
Method: EPA 245.1
ND ug/1
Method: EPA 375.4
ND mg/1
Project Sample Number: 92130716-001 Date Collected: 10/24/06 D8:50
Matrix: Water
Date Received: 10/25/06 14:05
Unite Report Limit Analyzed By CAS No. goal ReoLnt
3M 3030C / EPA 200.7
ug/1 5.0
ug/1 1.0
ug/1 5.0
ug/1 5.0
ug/1 50.
ug/1 5.0
ug/1 5-0
ug/1 1000
11/01/06
11/01/06
11/01/06
11/01/06
11/01/06
11/01/06
11/01/06
11/01/06
10/26/06
22:36 EWS
22:36 FRS
22:36 3115
22:36 BWS
22:36 EWS
22:36E15
22:36 i24S
22:36 ENS
11:00
744D-38-2
744D-43-9
744D-47-3
7440-50-8
7439-89-6
7439-92-1
7440-22-4
7440-23-5
0.2D 11/03/06 14:29 ALV 7439-97-6
5.D 10/31/06 07:21 TWR
Method: EPA 8260
3900 ug/1 25. 10/20/06 1D:45
17000 1g/1 500 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:48
ND ug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/D6 10:45
ND ug/1 1.D 10/28/D6 10:45
ND ug/1 1.D 10/28/06 10:45
3900 u8/1 2500 10/28/06 10:45
37. ug/1 1.0 10/28/06 10:45
ND 11g/1 1.0 10/28/06 10:45
3D ug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:45
SD ug/1 1.0 10/28/06 10:45
NDug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:45
ND ug/1 1.0 10/28/06 10:45
Asheville CPr1 ireatioNA5
NC WanLt.raler 40
NC Drinking Water 37712
SC Environmental 99930
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report chat re be rcproduoed, esep b toil,
wipout the vmften camera o0Pace Meal Samna. hrc.
MSF
MSF
3SF
MSP
MSP
MSS
NSF
MSF
MSP
MSP
M5F
MSF
NSF
MOP
!OF
MEP
NSF
LISP
67-64-1
71-43-2
108-86-1
74-97-5
75-27-4
75-25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
0hadotte CerBTratinn IN
LICWas3rt ter 12
NC Drinking Stater 37706
SC 99006
FL NELAP 1E87S21
Page: 1 of 22
9

aceAna!yticar
www peceleb&. m
Pace Analytical Services, Inc.
9800 ;gooey Avenue, Sole T00
Nunt8rsvtlle, NC28078
Phone:: [phone]
Fax [phone]
Lab Project Number: 92130715
Client Project ID: Walgreene Seatties Ford Rd
Lab Sample Not 927597221 Project Sample Number: 92130716-001 Date Collected: 10/24/06 08:50
Client Sample ID: PMW-1 PRE INJECTION Matrix: Water
Date Received: 10/25/06 14:05
parametere Reeulte Unite _ Jeoort Limit Analyzed Ev CAS 11o. Qua ReT t
1,2-Dibramo-3-chloropropane ND ug/1 1.0 10/28/06 10:45 MSF 96-12-8
Dibromochloromethaee ND ug/1 1.D 10/28/D5 10:45 MSF 124-48-1
1,2-Dibramoethaae {MOH) 590 ug/1 500 10/28/06 10:45 MSF 106-93-4
Dibromometharae ND ug/1 1.9 10/28/D6 10:43 MSF 74-95-3
1,2-Dicblorobeazene ND ug/1 1.0 10/28/06 10:45 M5F 95-50-1
1,3-Dichlorobenzene ND ug/1 1.0 1D/28/06 10:45 MSF 541-73-1
1,4-Dichlorobeazene ND ug/1 1.0 10/28/06 10:45 MSF 105-46-7
Dichlorodifluoromethane ND ug/1 1.0 20/28/06 10:45 24512 75-71-8
l,1-Dichloroethane ND ug/1 1.0 1D/28/05 10:45 MSF 75-34-3
1,2-Dichloroethane 2200 ug/1 SOD 10/28/05 10:45 NSF 107-06-2
1,2-Dichloroethene (Total) ND us/1 1.0 10/28/D6 10:45 MSF 540-59-0
1,1-Dichloroethene ND ug/1 1.0 10/28/06 10:45 NSF 75-35-4
ciu-1,2-Dichloroethene ND ug/1 1.0 1D/28/06 10:45 M5F 156-59-2
trans-1,2-Dichlorcethene ND ug/1 1.0 10/28/06 10:45 NSF 155-60-5
1,2-Dichloroprapane ND ug/1 1.0 10/28/06 10:45 NSF 78-87-5
1,3-Dichloropropane ND ug/1 1.0 10/28/06 10:45 MOP 142-28-9
2,2-Dichloroprapane ND ug/1 1.0 1D/28/06 10:45 MSF 594-20-7
1,1-Dichloropropene ND ug/1 1.0 10/28/06 10:45 MSF 563-58-6
Diiaopropyl ether 600 ug/1 500 10/28/06 10:45 NSF 108-20-3
Etbylbenteme 3400 ug/1 500 10/28/06 10:45 MSF 100-41-4
Hexachle:ro-1,3-butadiene ND ug/1 1.0 I0/28/06 10:45 MSF _87-68-3
Isopropylbenzeae (Cumene) 17D ug/1 1.0 1D/28/06 10:45 NSF 98-82-8
p-Ienprepyltolueno 53. ug/1 1.0 10/28/06 10:45 MSF 99.87-6
Methylene chloride ND ug/1 2.0 10/28/06 10:45 NSF 75-09-2
Methyl -tart -butyl ether 84. ug/1 1.0 10/21/06 10:45 M5F 1634-04-4
Naphthalene 80. ug/1 1.0 10/21/D6 10:45 MET 91-20-3
a-Propylbeazene 37D ug/1 1.0 10/28/06 10:45 NSF 103-65-1 1
Styrene ND ug/1 1.0 10/28/06 10:45 1d9F 100-42-5
1,1,1,2-Tetrechloroethane ND ug/1 1.0 10/28/96 10:45 MSF 630-20-6
1,1,2,2-Tetrechloroethene ND mg/1 1.0 10/28/05 10:45 NSF 79-34-5 get'.
Tetrachloroetbene ND ug/1 1.0 10/28/06 10:45 M5F 127-18-4
Toluene 31000 ug/l 500 10/28/06 10:45 MBF 108-88-3
1,2,3-Trichlorabensene ND mg/1 1.0 10/28/06 10:45 MSF 87-61-6
1,2,4-Trichlorobenrene RD mg/1 1.0 10/28/06 10:45 MSF 120-82-1
1,1,1-Triehloroethane ND ug/l 1.0 10/28/06 10:45 MSF 71-55-6
1,1,2-Trichlaraethaae ND ug/1 1.0 10/28/06 10:45 MSF 79-00-5
Trichloroethene ND ug/1 1.0 10/28/06 10:45 MSF 79-01-6
TrichloroEluoromethane ND i /1 1.0 10/28/06 10:45 NSF 75-69-4
1,2,3-Trichlorapropaae ND ug/1 1.0 10/28/06 10:45 NSF 96-18-4
Da:e: 11/09/06 Pages 2 o! 22
AshENN CeIdiratans0;:
NC Weslewatss 40
NC Drinking Water 37712
SC Eovconmental 99030
FL NEU F E8764B
REPORT OF LABORATORY ANALYSIS
This resort shah rot be rei::duce; eaep: ka
without the written corset of Pace AselytmE Services, inc.
yharlvtte Certification IDS
NC Westete xr 12
SC Drinking Water 3770E
SC 99006
!l `4
FL NEW E87827

/2eAnJyticar
tn�wu! paoelabs.ccm
Pace Afalytkal SerWces, lac.
9600 X1ncoy Avenue, Suits 700
Hunfersville, NC28078
Phone: 704,875.9092
Far 704.875.9091
Lab Project Hhtmber: 92130715
Client Project ID: Wa1green9 Beattice Ford Rd
Lab Sample No: 927597211
Client Sample ID_ PMW-1 PRE INJECTION
parameters
1,2,4-Trimethylbearene
1,3,5-Trimethylbensene
Vinyl chloride
3:ylene (Total)
m&p-2ylene
o-Xylene
Toluene-d8 (S)
4-Sromofluorobenzene (5)
Dibrwnofluoramethane (S)
1,2-Dichloroethene-d4 (S)
Date, 11/09/06
Project Sample Number: 92130716-00I
Matrix: Water
Results Units peoort Limit Analysed By
1900 ug/1 500 10/28/06 10:45 MS?
500 up/1 500 10/28/06 10:45 MSP
ND ug/1 1.D 10/28/06 10:45 MSF
150D0 u3/1 500 10/28/06 10:45 MSP
10000 ug/1 1000 10/28/06 10:45 MS?
5000 ug/1 500 10/28/06 10:45 MSF
43 % 10/28/06 10:45 MSP
115 % 10/2a/06 10:45 MSF
110 % 10/28/06 10:45 MSF
436 1 10/26/06 10:45 NSF
Asherrlle Certifreetipn ins
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 95030
FL NELAP E87646
REPORT OF LABORATORY ANALYSIS
This report shall np be repmdured, except In fun,
einhaet the written consent of Pau Aneyties1 SnM nn, Inc.
itiefath
Date Collected: 10/24/06 08:50
Date Received: 10/25/06 14:05
CAS No. Dual jtegLntit
95-63-6
108-67-8
75-01-4
1330-20-7
95-47-6
2037-26-5 2
460-00-4
1868-53-7
17060-07-0 3
2adntte Ceotatiei 11%
NO Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E87627
Pogo: 3 of 22

t2eAnaIj4icar
www.pe>ralahscam
Pace Analytical Services. Inc. f
98001GnneyAvenue, Suits 109
Huntersville, NC2807B
Phone: [phone]
• Far 7154.875.9091
Lab Project ?Amber: 92130716
Client Project ID: Walgreens 3eattie8 Ford Rd
Lab Sample No: 927597229 Project Sample Number: 92130716-002 Date Collected: 10/25/06 11:00
Client Sample ID: PMW-1 POST INJECTION 24AR
Matrix: Water Date Received: 10/25/06 14:05
Parameters Results Anita jlenort Limit Analyzed By CAS No, Dual� ReoLmt
Metals
3030C Metale, ICP, Trace Prep/Method: OM 3030C / EPA 200.7
Arsenic, 3030C ND ug/1 5.0 11/01/06 22:40 EWS 7440-38-2
Cadtium, 3030C ND ug/1 1.0 11/01/06 22:40 EWS 7440-43-9
Chromium, 3030C ND ug/1 5.0 11/01/06 22:40 EWS 7440-47-3
Copper, 3030C ND ug/1 5.0 11/01/06 22:40 EWS 7440-50-8
Iron, 3030C 360 ug/1 50. 11/01/06 22:40 EWS 7439-89-6
Lead, 3030C ND ug/1 5.0 11/01/06 22:40 EWS 7439-92-1
Silver, 3030C ND ug/1 5.0 11/01/06 22:40 EWS 7440-22-4
Sodium, 3030C 5100 ug/1 1000 11/01/06 22:40 EWS 7440-23-5
Date Digested 10/26/06 11:00 10/26/06 11:00
Mercury, CVAAS, in Water
Mercury
Method: EPA 245.1
ND ug/1
0.20 11/03/06 14:43 ALV 7439-97-6
Wet Chemistry
Sulfate,2urbi5imetric Method: EPA 375.4
Sulfate ND mg/1 5.0 10/31/06 07:24 TMR
GC/MS Volatilea
GC/MS VDCo by 8260. low level Method: EPA 8260
Acetone 2B00 ug/1 1200 10/31/06 D2:29 MSF 67-64-1
Benzene 19000 ug/1 250 10/31/06 02:29 MSF 71-43-2
Bromoben:ene ND ug/1 50. 10/31/06 D2:29 MSP 108-86-1
Bromochloramethane ND ug/1 50. 10/31/06 02:29 MS? 74-97-5
Bramodichloromethane ND ug/1 50. 10/31/06 02:29 MSF 75-27-4
Bramoform ND ug/1 50. 10/31/D6 02:29 NSF 75-25-2
Brcmemethane ND ug/1 50. 10/31/06 02:29 MSF 74-83-9
2-3utanoae (1L4R) 4600 u9/1 250 10/31/D6 02:29 MS? 78-93-3
n-Eutylbanzeaa ND ng/1 50. 10/31/06 02:29 MSF 104-51-8
sec-Eutylbenzene ND ug/1 50. 10/31/06 02:29 MSP 135-98-8
tert-Butylbenzene ND ug/1 50. 10/31/06 02:29 MSF 98-06-6
Carbon tetrachloride ND ug/1 50. 10/31/06 02:29 MSF 56-23-5
Chlorobenzene ND ug/1 50. 10/31/06 02:29 MSF 10B-90-7
Chloroethane ND ug/1 50. 10/31/06 02:29 MS? 75-00-3
Chloroform ND ug/1 50. 10/31/06 02:29 M58 67-66-3
Chlorometbane ND ug/1 50. 10/31/06 02:29 MSP 74-87-3
2-Chlorotoluene ND ug/1 50. 10/31/06 02:29 MSF 95-49-8
4-chlorotoluene ND ug/1 50. 10/31/06 02:29 MS? 106-43-4
Data: 11/09/05 Page, 4 of 22
AaIrt i!le Certification tD
NC Waciewal:r 40
NC Drinking Wafer 37712
SC Environmental 931)30
FLNELW E137648
REPORT OF LABORATORY ANALYSIS
This repent Shall nd he reproiuurd. es ept IR tu0.
witotn the written consent of PmeAnu)yEical Serv6Cec, Inc.
Dharloutfr&Sjfcatie RJ D5
N0 Wzstewaler 12
NC Drinking Water 37706
SC 99008
FL NELAP E87627

(aeAnical"
o wimpecelabs_cam
PaceAnalrticrl Services, loc.
9800 KrnceyAvenue, Suite 100
Hunters ille, NO 28078
Phone. [phone]
Fair: 704.875.9091
Lab Project Humbert 92130715
Client Project ID: Welgreena Seattle:: Ford Rd
Lab Sample No: 927597229 Project Sample Number: 92130716-002 Date Collected: 10/25/06 11:00
Client Sample ID: PMW-1 POST IN38CTIDN 24MR Matrix: Water Date Received: 10/25/D6 14:05
Parameters Results UUnita Fenort Limit Analysed 89' ChS No. Coal JteoLml
1,2-Dibromo-3-chloropropane ND ug/1 50. 10/31/06 02:29 MSF 96-12-8
Dibromochloromethano ND ug/1 50. 10/31/06 02:29 MSF 124-48-1
1,2-Dibromoetheae (RD8) 620 ug/1 50. 10/31/06 02:29 MSF 106-93-4
Dibromoaethene ND ug/1 50. 10/31/06 02:29 NSF 74-95-3
1,2-Dichlorobensene ND ug/1 50. 10/31/06 02:29 MSF 95-50-1
1,3-Dichlorobensene ND ug/1 50. 10/31/06 02:29 MSF 541-73-1
1,4-Dichlorobensene ND ug/1 50. 10/31/D6 02:29 NSF 106-46-7
Dichloradifluotamstbane ND ug/1 50. 10/31/06 D2:29 808E 75-71-8
1,1-Dicbloroethane t9D ug/1 50. 10/31/06 02:29 M5P 75-34-3
1,2-Dichloroethane 2300 ug/1 50. 10/31/06 02:29 MSF 107-06-2
1,2-Dichloroetheae (Total) ND ug/1 50. 10/31/06 02:29 MSF 540-59-0
1,1-Dichloroathene ND ug/1 50. 10/31/06 02:29 MSF 75-35-4
cis-1,2-Diehloroetheno ND ug/1 50. 10/31/06 02:29 MSF 156-55-2 ..•r.
trans-1,2-Dichioreethema ND ug/1 50. 10/31/06 02:29 MSF 156-60-5
1,2-Dichloropropene ND ug/1 SD, 10/31/05 02:29 MSF 78-87-5
1,3-Dichloropropane ND ug/l 50. 10/31/06 02:29 NSF 142-28-9
2,2-Diehlarepropane ND ug/1 5D. 10/31/06 02:29 MSF 594-20-7
1,1-nichloropropene ND ug/1 5D. 10/31/05 02:29 MSF 563-58-6
Diieopropyl ether 620 ug/1 5D. 10/31/06 02:29 MSF 108-20-3
Ethylbensene 3300 ug/1 50. 10/31/06 02:29 MSF 100-41-4
Mexachloro-1,3-butadiane ND ug/1 50. 10/31/06 02:29 MSF 87-68-3
Isopropylbensene (Cunene) 140 ug/1 50. 10/32/05 02:29 MSF 98-82-8
p-Isopropyltoluene ND ug/1 50. 10/31/06 02:29 MSF 99-87-6
Methylene cblorids MD ug/1 100 10/31/06 02:29 NSF 75-09-2
Methyl -tart -butyl ether 60. ug/1 50. 10/31/06 02:29 NSF 1634-04-4
Naphthalene 250 ug/1 50. 10/31/06 02:29 MSF 91-20-3
n-Propylbensene 340 ug/1 50. 10/31/06 02:29 MSF 103-65-1
Styrene ND ug/1 50. 10/31/06 02:29 MSF 100-42-5
1,1,1,2-Tetrachloroethane ND ug/1 50. 10/31/06 02:29 MSF 630-20-6
1,1,2,2-Tetrachloroethane ND ug/1 S0. 10/31/06 02:29 MSF 79-34-5
Tetrachloroethene ND ug/1 50. 10/31/06 02:29 MSF 127-18-4
Toluene 34000 ug/1 250 10/21/D6 02:29 MSF 108-88-3
1,2,3-Trichlorobensene 3D ug/1 50. 10/31/06 02:29 MSF 87-61-6
1,2,4-Trichlorobenaene ND ug/l 50. 1D/31/06 02:29 MSF 120-82-1
1,1,1-Trichloraethene ND ug/1 50. 10/31/06 02:29 MSF 71-55-6
1,1,2-Trichloroothaue ND ug/1 50. 10/31/06 02:29 MSF 79-00-5
Trichloroethene ND ug/1 50. 10/31/06 02:29 MSF 79-01-6
Trichlorofluoromethane ND ug/1 50. 10/21/06 02:29 MSF 75-69-4
1,2,3-Trichloropropane ND ug/1 50. 10/31/06 02:29 MSF 95-18-4
Data: 11/09/D6 Pap! 5 of 22
Asheville C4rt$icatwn Ids
NC Wastenter 40
NC Drinking Water 37712
5C Environmental 99030
FL 8ELAP E87648
REPORT OF LABORATORY ANALYSIS
TFrs'sport shall rer he evpradad, eft in MI,
w3hact the written cv tan! of Pace An:lylial Services, Inc.
thekiC6
chartnte Ceal+lcation IDS
NC Wastewater 12
NC Drinking Water 37705
5C 99005
FL NELAP E57627
f

aceAnalyt ca!
1vww.pate1absc»m
Pate Analytical Services, km.
9800 KJnceyAvenue, SuJ)e 100
Nuntersville, NC 28078
Phone: [phone]
Fax: 704.875,9091
Lab Project Number: 92130715
Client Project ID: Walgraena Beattie Ford Rd
Lab Sample No: 927597229
Client Sample ID: PMw-1 POST IN,TEJ:TION 24MR
Parameters
1,2,4-Trimethylbenzeae
1,3,5-Trimethylbenxeae
vinyl chloride
Xylem: (Total)
mop-Rylens
o-Rylene
Toluene-d8 (5)
4-Bromofluorobenxene (6)
nibromofluorometbaae (S)
1,2-Dichloroathane-d4 (5)
Data: 11/Ds/D6
Results 17aits
1800 ug/1
470 ug/1
ND ug/1
15000 ug/1
10000 ug/1
5000 ug/1
99
1D4
96
96 9J
Ashville Co tine honi Dg
NC Wastewater CO
NC Drinking Water 37712
SC Environmental 99033
FL NELJP E57548
Project Sample Number: 92130716-002 Ante Collected: 10/25/06 11:00
Matrix: Mater Date Received: 10/25/06 14:05
Report Limit Analyzed 8y CAS No. Oual Reg3ia
50.
50.
50.
50.
100
50.
10/31/06 02:29
10/31/06 02:29
10/31/06 02:29
10/31/06 02:29
10/31/06 02:29
1D/31/05 02:25
10/31/06 02:29
10/31/D6 02:29
10/31/06 02:29
10/31/D6 02:29
REPORT OF LABORATORY ANALYSIS
Thla report shaft nag be rePmduczd. ec{n m iol,
witout the rrtitlm centre D1 Paw Aaalylioal Services, Inc.
MSF 95-63-6
NSF 108-67-8
NSF 75-01-4
NSF 1330-2D-7
NSF
MSF 95-47-6
MSF 2037-26-5
MSF 460-00-4
MSF 1868-53-7
MSF 17060-07-0
Aar1Dtte Cmtrrrilkm IO5
NC Wastewat r 12
NC Drinking Water 37706
SC 99006
FLNELAP EE7627
Page: 6 o2 22
F

aeAnaij4icar
�Aaa�IIs.*a0m
Pace Analytical Samtes, Inc.
9800 Kinney Avenue, Suite 100
Etuntcrsvliis, NC28078
Phone: [phone]
Fax [phone]
Lab Project Number: 9213071E
Client Project ID: Walgreens Rennie■ Ford Rd
PARAMETER FOOTNOTES
Method 9071B modified to use ASB.
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending an the moisture content the PRLe care be elevated for all soil samples reported on a dry weight beiie.
2-chloroet.hyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
11C Not Calculable
Estimated concentration above the adjusted method detection limit and below the edjusted reporting limit
MDL Adjusted Method Detection Limit
(9) Surrogate
[1) Compound concentration exceeds the calibration ratan of the instrument (CLP B-Flag).
[2] Low surrogate recovery was confirmed as a matrix effect by a second analysis.
[3] High surrogate recovery was confirmed as a matrix effect by a second analysis.
•
Cates 11/09/06 Pager 7 of 22
AsirerFre Ida
NC WWSlewatet 40
VG Grinking Water 37712
SC Environmental 9301)
R. NaAP E57848
REPORT OP LABORATORY ANALYSIS
This recoil shall not he reproduces!, exrxpl in 1u0,
nttto2tthewrt notrseMoTParaAnalyticaIService,Ina
yharlotte Certitkxtion IQI
NE Wastewater 12
NC Drinking Water 37706
SC 9900'n
FI NEAP E67627

(/2
www paCetabs oom
Pace AAalytfear Services, Inc.
9800 Klneey Avenue, Suite 100
Nuntersvitle, NC28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Kalgreens Beattie::: Ford 8d
QC Batch: 171415
QC Batch Method: EPA 8260
Associated Lab Sample®:
927597211
Analysis Method: En 9260
Analysis Description: GC/MS VOCs by 8260, lox level
I4ETBOD BLANK: 927608125
Associated Lab Samples: 927597211
Blank Reporting
Parameter units Result Licit Footnotes
Acetone ug/1 ND 25.
Benzene ug/1 ND 1.0
Bromobenzene ug/1 ND 1.0
Bromoehlorometbaae ug/1 ND 1.0
Bromodichloromethane ug/1 ND 1.0
Bromaform ug/1 ND 1.0
Bromomethane ug/1 ND 1.0
2-Butaaone (MEE) ug/1 ND 5.0
n-13utylbearene ug/1 ND 1.0
sec-Butylbeneeae ug/1 ND 1.0
tert-Butylbenzeae ug/1 ND I.0
Carbon tetrachloride ug/I ND 1.0
Chlorobenzene us/1 ND 1.0
Chloroethane ug/1 ltD 1.0
Chloroform ug/1 ND 1.0
Chioromethane ug/1 ND 1.0
2-Chloxotolueae ug/1 ND 1.0
4-Chlorotoluena ug/1 ND 1.0
1,2-Dibrotmo-3-ebloropropane ug/1 ND 1.0
Dibromochloramethane ug/1 RID 1.0
1,2-Dihroethane (EDB) ug/1 'ND 1.0
Dibromomethane ug/1 ND 1.0
1,2-Dichlorohenzene ug/1 ND 1.0
1,3-Dichlorobenzene ug/1 ND 1.0
1,4-Dichlorabenzene ug/1 ND 1.0
Dichlorodifluoromethaae ug/1 ND 1.0
1,1-Dichloroethane ug/1 ND 1.D
1,2-Dichloroethene ug/1 bD 1.0
1,2-Dichloroathene (Total) ug/1 ND 1.0
1,1-Dichloroethene ng/1 ND 1.0
cis-1,2-Dichloroethene ug/1 ND 1.0
Vac 22/D9/86 P g•e 8 of 22
psheArte Centlicalion IDg
NC Wastewater 40
NC Drinking Wafer 37712
SC Emrironmental 09330
FL KELP E876EB
REPORT OF LABORATORY ANALYSIS
Tie9 repon shoo not bo reproduced, ettepl In fun,
viittbut the written consort of Pace Analytical Services, Ice.
1,halotte CertfraliDn iO4
NC Wastewater 12
NC Ddnkiog Water 97/05
SG 99035
R NELAP E87627
F

aceArelyticar
m nstperagabs.com
Pace Analyllral Services, inc.
9800MnceyAvenue, Suite WO
Huniersville, NC 28078
Phone: 704,875.9092
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Walgreens Beatties Ford Rd
t ate0D BLANK: 927608125
Associated Lab Samples: 927397211
Blank Reporting
Parameter Unity Result Limit Footnotes
trans-1,2-Dichloroethene ug/1 ND 1.0
1,2-Diehloroprapane ug/1 ND 1.0
1,3-Dichlaropropane ug/1 ND 1.0
2,2-Dichloropropane ug/1 ND 1.0
I,1-Dichloropropena ug/1 ND 1.0
Diiaopropyl ether ug/1 ND 1.0
Ethylbensene ug/1 ND 1.0
Hexechloro-1,3-butadiene ug/1 ND 2.0
Isopropylbenzene (Cmrene) ug/1 ND 1.0
p-Isopropyltoluene ug/1 ND 1.0
Methylene chloride ug/1 ND 2.0
Methyl -tart -butyl ether ug/1 ND 1.0
Naphthalene ug/1 ND 1.0
n-Propylbenzene ug/1 ND 1.0
Styrene ug/1 ND 1.0
1,1,1,2-Tetrachloroet ene ug/1 ND 1.0
1,1,2,2-Tetrachloroetbane ug/1 ND 1.D
Tetrachloroethene ug/1 ND 1.0
Toluene ug/1 ND 1.D
1,2,3-Trichlorobben:sae vg/1 ND 1.0
1.2,4-Trichlorobenzene ug/1 ND 1.D
1,1,1-Trichloroethane ug/1 ND 1.D
1,I,2-Trichloroethene u9/1 ND 1.D
Trichloroethene ug/1 ND 1.D
Trichlorofluoramethana ug/1 ND 14
1,2,3-Trichloropropane ug/1 1D 1.0
1,2,4-Trimethylbenzane ug/1 ND 1.0
1,3,5-Trimethylbensene ug/1 DID 1.0
Vinyl chloride ug/1 ND 1.0
%yleae (Total) ug/1 ND 1.0
msp-Xylene ug/1 ND 2.0
o-Xylena ug/1 ND 1.0
Toluene-d8 (5) $ 100
4-3romofluorobenzene (9) 'k 100
Dibromofluoramethane (S) 4 97
1,2-Dichloroethene-d4 (S) % 95
Data: 11/D9/24 Page: 9 o2 22
Asit,ltfertiftcation FD$
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL HEIR? E3754$
REPORT OF LABORATORY ANALYSIS
Tr c rep r1 star not be repoeored, =etc in ful,
withuutthe wrtten consent of Pace Analytical Services, Inc.
in ti
NC Wastewater 12
NC Drinking Water 37700
SC 99006
FL NELAP E87627
F

aceAnalyticar
www pace abscom
Pate Airarylkal Services, Inc.
9800kinceyAvenue, Suite 100
Huntersvi le, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Wa1greens Beettiea Yard Rd
LABORATORY CONTROL SAMPLE: 927608133
Spike LCS LCS
Parameter Unite Conc. Result k Rec Footnotes
Acetone ug/1 100.00 84.04 84
Beneene ug/1 50.00 51.19 102
Bromobenzene ug/1 50.00 51.27 103
13romochloromethhne ug/1 50.00 49.33 99
Bromodichloro:nethane ug/1 50.00 53.97 108
Bromoform 11g/1 50.00 45.79 92
Bromoaeethnne ug/1 50.00 57.97 116
2-Butanone WEE) ug/1 100.00 91.97 92
n-Butylben:eae ug/1 50.00 49.10 98
see-Butylbenzene ug/1 50.00 53.64 107
tart-3utylbenzene ug/1 50.00 53.58 107
Carbon tetrachloride ug/1 50.00 55.25 111
Ch1orobenzsns ug/1 50.00 51.49 103
Chloroethane ug/1 50.00 54.64 109
Chloroform ug/1 50.00 51.98 104
Chloromathane ug/1 50.00 50.21 100
2-Clalorotolueae ug/1 50.00 51.97 104
4-Chlorotoluene ug/1 50.00 51.69 103
1,2-Dibrctmo-3-chloropropane ug/1 50.00 43.58 97
Dibromoohloromethano ug/1 50.00 46.38 93
1,2-Dibremoethane (BDB) ug/1 50.00 53.57 107
Dibramomethans ug/l. 50.00 50.93 102
1,2-Dichlorobenzeno ug/1 50.00 52.17 104
1,3-Dichlorobenzeae ug/1 50.00 51.94 104
1,4-Dichlorobemenne ug/1 50.00 50.2D 100
Dich1orodifluoromethaae ug/1 50.00 54.89 110
1,1-Dichloroethane ug/1 50.00 53.85 108
1,2-Dichlorosthaae ug/1 50.00 48.79 58
1,2-Dichloroethene (Total) ug/1 100.00 113.1 113
1,1-Diohlorcathene ug/1 50.00 59.18 118
cis-1,2-Dichloroethene ug/1 50.00 55.70 111
trams-1,2-Dichloroethene ug/1 50.00 57.40 115
1,2-Dichloropropane ug/1 50.00 52.23 104
1.3-Dichlaropropana ug/1 50.00 51.88 104
2,2-Dichloropropane ug/1 50.00 46.66 93
1,1-Dichlaroprapene ug/1 50.00 54.20 108
Diieopropyl ether ug/1 50.00 51.31 103
Date: II/09/06 Page: 1D o! 17
jshaviiit C+ tficaticn 1D5
NC Wastewater 40
ND Drinking Water 37712
SC Ervironnental 99C30
FL HELP E87648
REPORT OF LABORATORY ANALYSIS
This +rro-t stall rat h: reproduced. except Ma
without the erdien COnterd el Pace Aneiylcal Sarvloes, Inc,
Charlotte Certification Ipg
NC Wastewater 12
NC Drinking Water 377D8
5C 99006
FL NELAP f87627

aceAnaayticar
www.p celabxoorn
Pace Arralnkal Services, inc. F
9800Moo Avenue, Suite 100
Huntersville, NC 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130715
Client Project I0: Walgreeae Beatties Ford Rd
LABORATORY CONTROL SAmPLB: 92760B133
Spike LCS LCS
parameter " Unite Conc. Result l Rec Footnotes
Ethylbenzene ug/1 50.00 51.14 102
Hexachloro-1,3-butadiene ug/1 50.00 55.52 111
Isoprapylbenzene (Cumeae) ug/1 50.00 54.55 109
p-I9opropyltoluane ug/1 50.00 49.76 100
methylene chloride ug/1 50.00 50.0E 100
Methyl -tart -butyl ether ug/1 50.00 48.93 9B
Naphthalene ug/1 50.00 44.87 90
a-Prapylbeazene ug/1 5D.00 53.21 106
Styreaa ug/1 50.00 54.73 109
1,1,1,2-Tetrachloroetbana ug/1 50.00 56.07 112
1,1,2,2-Tetrachloroethane ug/1 50.00 34.40 109
Tetrachloroetheae ug/1 50.00 51.79 104
Toluene ug/1 50.00 48.00 96
1,2,3-Trichlorobenzene ug/1 50.00 53.19 106
1,2,4-Trichlarobenzene ug/1 50.00 53.25 106
1,I,.1-Trich1oroothane ug/1 50.0D 54.64 110
1,1,2-Trichloroetbaae ug/1 50.00 46.96 98
Txichloroetheno ug/1 50.00 49.53 99
Trichlorofluarcmethaae ug/1 50.00 56.57 113
1,2.3-Trichloropropane ug/1 50.00 47.22 94
1,2,4-Trimethylbenzene ug/1 50.00 48.02 96
1,3,5-Trimethylbeazeae ug/1 50.00 48.34 97
Vinyl chloride ug/1 50.00 52.65 105
Iyleae (Total) ug/1 150.00 156.4 104
map-Eylene ug/1 100.00 104.1 104
o-Xylene ug/1 50.00 52.31 105
Toluene -dB (S) 99
4-Bromofluorabenzeae (5) 101
Dibromofluoromathene (S) 98
1,2-Dichloroethaae-d4 (5) 57
MATRIX SPIES & MATRIX SPIKE DUPLICATE: 927608174 9276118182
Parameter
Benzene
927592972 Spike MS MSD ii9 !LSD
Units xelault Conc. Result Result % Rea % Rea An Footnotes
ug/1 0.3976 50.00 66.77 56.61 133 112 16
Datat 11/03/06 Paps 11 a 22
Asheville Cel11N66nn 1015
NC Wastewater 40
NC Drinking Water 37712
Se Envinanmental 99030
FL NEAP E137648
REPORT OF LABORATORY ANALYSIS
ibis upon ;WI not be reprvdeed. except In 1oA,
Mime the wren meant of Pace Analytical SrMo , loe
trielaCi
Charfehe Cerliftailor! 1D5
NC Wastewater 12
NC Drinking Water 37706
SC MOM
FL NELAP €87627

aceAnalyttical
wrvw. sbstnm
Pace Anafrtks: Services, Inc. F
9800 gncay Avenue, Suite 100
Huntersville, NC 28078
Phwre:704.875.9092
Fare 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92130715
Client Project ID: walgreana Beattiee Ford Rd
MATRIX SPIKE & MATRIX SPIRT: ➢UPLICATE: 927608174 927600162
927592972 Spike MS MSD MS MSD
Parameter Unite Result Conc. Result Result 4 Roc % Roc RPD Footnotes
Chlorobencene ug/1 0.4437 50.00 55.04 55.04 109 109 0
1,1-Dichloroetbene ug/1 0 50.00 49.52 48.96 99 95 1
Toluene ug/1 D 50.00 87.94 61.36 176 123 36 1,2
Trichloroethene ug/1 0 50.00 50.89 50.41 102 101 1
Toluene -dB {g} 98 100
4-Bromofluorobenmene (5) 106 104
Dibromofluororaetheae (8) 32 97
1,2-Dichloroethane-d4 (S) 85 91
Data[ 11/55/46 Pops 12 of 22
AstieNtrit Certification ID
NC Wastewater 40
NC Drinking Wafer 37112
SC Environmental 93030
FLtt9-AP E87648
REPORT BF LABORATORY ANALYSES
This marl shag net to repro1uwtl, owl N tugt,
without thetsrilon cased, of Peer Analy2kat Services, Inc.
Lharble CervtiaUon Ir135
NC V1'aslewater 12
NC Drinking Water 37706
SC 89005
R NELAP EB7627

aceAnalytica!"
w:envpaceWs.l vn
Pace Analytical Services, tor. F
9800K1nteyAvenue, Saite 100
h'srnfersville, NC 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Numher: 92130116
Client Project ID: Walgreene Hearties Ford Rd
QC Batch: 271589
QC Batch Method: 3PA 8260
Associated Lab Sample!:
927597229
Analysis method: EPA 8260
Analysis Description: DC/MS VDCa by 8260, low level
METHOD BLANK: 927616086
Associated Lab Samples: 927597229
Blank Reporting
Parameter IIni,ts Result Limit Footnotes
Acetone ug/1 1W 25.
Benzene ug/1 ND 1.0
sromobensene 141/1 ND 1.0
Bramochlerom:ethaae ug/1 ND 1.0
Bromodichloronethene ug/1 ND 1.0
Bromoform ug/1 BD 1.D
Bromomethmse vg/l -ND 1.0
2-Butanone (MSLC) mg/1 ND 5.0
12-Butylben2ene ug/1 ND 1.0
see-Butylbeazone vg/1 ND 1.D
tert-Butylbenzene ug/1 ND 1.D
Carbon tetrachloride ug/1 ND 1.D
Chlorobenzeae vg/l ND 1.0
Chloroethane 14/1 ND 1.0
Chloroform ug/1 ND 1.D
Chloromethane ug/I ND 1.0
2-Cblorotoluene ug/1 ND 1.D
4-Chlorotoluana ug/1 - ND 1.D
1,2-Dibromo-3-chloroprapane ug/1 ND 1.0
Dibromochloramethane ug/1 ND 1.0
1,2-Dibromoethano (EDB) ug/1 ND 1.0
Dibromonethena ug/1 ND 1.0
1,2-Di ehlorobensene ug/1 ND 1.D
1,3-Dichlorobenzene ug/1 ND 1.0
1,4-Dichlorobanzene mg/1 ND 1.0
Dichlorodifluorom<ethana ug/1 ND 1.0
1,1-Dichloroethane ug/1 ND 1.0
1,2-Dichloroethane vg/1 AID 1.0
1,2-Dichloroethens (Total) ug/1 ND 1.0
1,1-Diahloroetbene ug/1 ND 1.0
cis-1,2-Dichloroethene ug/1 DID 1.0
Date: 11109106
Muni& OrnSiDallan IDg
NCWasterraiar a0
NC Drinking Water 37712
SC Environmental 98630
FL NELAP E07648
REPORT OF LABORATORY ANALYSIS
Ns report shall nrl be repredumd, Mani SnfuD,
without thawriten consent of Pace Analytical SeMxs, lnc.
£iiarkr:te Galin:Aire me
NC Wastewater 12
NC Drinking water 37706
SC 99006
FL NELAP E87627
Page: 13 of 22

(eAnaYtical"
www.paaarabs.com
Paea Analylfcaf Sarvic s, lae. f
9800 KnceyAvenue, Suite 100
Nurrlarsw1ie, NC 28078
Phone: [phone]
Far 704.875.4091
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Walgreens $oattiea Ford kd
Manson BLANK: 927616086
Associated Lab Samples: 927597229
Blank Reporting
parameter Units Result Limit Footnotes
trans-1,2-Dichloroethene ug/1 ND 1.0
1,2-Dicbloropropane 11g/1 ND 1.0
1,3-Dichloropro?ene ug/1 ND 1.0
2,2-Diehloroprapene ug/1 ND 1.0
1,1-Dichloropropene ug/1 ND 1.0
Diinapropyl ether ug/1 ND 1.0
8thylbentene ug/1 ND 1.0
Hexaehloro-1,3-butadiene ug/1 ND 1.0
Ieopropylbeasene (Ctimeae) tg/1 ND 1.0
p-Isopropyltoluene 12g/1 ND 1.0
Methylene chloride ug/1 ND 2.0
Methyl -test -butyl ether ug/1 ND 1.0
Naphthalene ug/1 ND 1.0
n-Propylbenze ug/1_ ND 1.0
Styrene ug/1 ND 1.0
1.1,1,2-2otrachloroetheae ug/1 ND 1.0
1,1,2,2-Tetrachloroethane ug/1 ND 1.0
Tetrachloroethene UV/1 ND 1.0
Toluene ug/1 ND 1.0
1,2,3-Trichlorobenrene ug/1 ND 1.0
1,2,4-Trichlorobenzene ug/1 ND 1.0
1,1,1-Trichloroetha a ug/1 ND 1.0
1,1,2-Trichloroethane ug/1 ND 1.0
Trichloroethene ug/1 ND 1.0
Trichlorofluoromethene ug/1 ND 1.D
1,2,3-Txichloroprapane ug/1 ND 1.D
1,2,4-Trimethylbenzene 119/1 ND 1.D
1,3,5-Trimethylbeazene ug/1 ND 1.D
Vinyl chloride ug/1 ND 1.D
xylene (Total) ug/1 MD 1.0
mfp-Xylene ug/1 ND 2.0
o-Xylene 115/1 MD 1.D
Toluene -dB (S) % 1D0
4-eromofiuorobenzene (S) % 1D4
Dibrcnofluoromethane (S) % 92
1,2-Dichloroethane-d4 (S) % 87
Drees 11/09/06 Page: 14 of 22
psheviige Certifirx' . 1r15
NC Wastewater 40
NC Drinking Water 37712
S& Erreironmentz1 99030
FL NELAP E8760
REPORT OF LABORATORY ANALYSIS
Trds report slal toot ba reproduced, me% In toll,
Whoa the written consent of Pau MathMafitiral Services. In.
prartiTre Cerbli lion ID4
N£ Wastewater 12
NC Drinking Water 37766
SC 99606
F- NILAP t87527

aceAnalyticar
Pace AnalyticalServicss, Inc.
9800 Kinney Avenue, Suite 100
Nuntersvllla, NC 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project tnr Wa1greens Beattiee Ford Rd
LABORATORY CONTROL SA1PLE: 927615094
Spike /C9 LCS
Fax -meter Units Conc. _ Result Rec Footnotes
Acetone ug/1 100.00 81.57 82
Benzene ug/1 50.00 45.54 91
Bromobenzene ug/1 50.00 43.33 87
Bromochloromethane ug/1 50.00 42.71 85
Bromodichloromethene ug/1 50.00 47.04 94
Hromoform ug/1 50.00 44.34 89
Bramcmethane ug/1 50.00 34.41 69
2-Eutanone (0658) ug/1 100.00 82.62 83
n-eutylbeazens ug/1 50.00 49.85 100
sec-Butylbenzone ug/1 50.00 55.79 112
tart-Hutylbenzune 11g/1 50.00 52.27 105
Carbon tetrachloride ug/1 50.00 49.66 99
Chlorobenzena ug/1 50.00 45.97 92
Chloroethaste u9/1 50.00 44.38 89
Chloroform ug/1 50.00 42.82 66
Chloramethane ug/1 50.00 41.59 83
2-Chlorotolueno ug/1 50.00 45.64 91
4-Chloratoluene ug/1 50.00 45.19 90
1,2-Dibromo-3-chloropropaae ug/1 50.00 36.12 72
Dlhromoohloremetbaua ug/1 50.00 42.25 84
1,Z-Dibr000ethane (EDB) ug/1 50.00 48.50 97
Dibromomethane ug/1 50.00 47.51 95
1,2-Dichlorobonzeae ug/1 •50.00 46.51 93
1,3-Dichlorobenzene ug/1 50.00 47.92 96
1,4-Dichlorobenzeme ug/1 50.00 44.79 90
Dichlorodifluoramethane ug/1 50.00 46.15 92
1.1-Diehloroothane 119/1 50.00 44.55 89
1,2-Dichloroethane ug/1 50.00 39.61 79
1,2-Dichloroethene (Total) ug/1 100.00 52.75 93
1,1-Dichloroet:hene u9/1 50.00 47.62 96
cis-1,2-Diohloroetheae ug/1 50.00 44.90 90
trans-1,2-Diohloroethene ug/I 50.00 47.85 96
1,2-Dichloropropana ug/1 50.00 45.86 92
1,3-Dichloropropene ug/1 50.00 46.55 91
2,2-Dichloropropane ug/1 50.00 46.71 93
1,1-Dichloropropene ug/1 50.00 44.84 90
Diisopropyl ether ug/1 50.00 45.65 91
nate: 1109/06 Pages 15 of 22
Ass rflieCertifrcatienrDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NEIAP E8754B
REPORT OF LABORATORY ANALYSIS
This report shall not ba reproduced, e>,cant
w>thordthe twiner! corset! of Pace Analytip4 Serbian, In.
l' 4
:
partner Cerrifentinn Irke
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP EB7627
f

ceAnalydca!'
w , paaelabs ciom
Pace Anelyllcal Services, lac.
9800 Kiocey Avenue, Suite 199
Nuntersville, NC28078
Phone [phone]
Far 704.875.9991
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Walgreens B4attiea Ford Rd
LABORATORY CONTROL 5A18LE: 927615094
Spike LCS LCS
Parameter Units CDAC. Result i Rec Footnotes
Bthylbensene ug/1 50.00 46.55 93
Bexachloro-1,3-butadieae ug/1 50.00 59.59 119
Isopropylbeazene (Cumeae) ug/1 50.00 52.85 106
p-IOopropyltoluene ug/1 50.00 51.45 103
Methylene chloride ug/1 50.00 43.53 87
Methyl -text -butyl ether ug/1 50.00 44.28 89
Naphthalene ug/1 50.0D 32.18 64
a-Fropylbensene ug/1 50.00 49.71 99
Styrene ug/1 50.00 49.66 99
1,1,1,2-Tetrachloroethane ug/1 50.00 50.87 102
1,1,2,2-Tetrachloroethane ug/1 50.00 49.65 99
Tetrachlorooehene ug/1 50.00 49.63 99
Toluene ug/1 50.00 44.31 89
1,2,3-Trichlorobenzeae ug/1 50.04 32.80 66
1,2,4-Trichlarobeazene ug/1 50.00 39.17 7B
1,1,1-Trichloroothane ug/1 50.00 45.55 91
1,1,2-Trichloroethane ug/1 50.00 44.68 89
Trichloroethene ug/1 50.00 45.34 91
2richlnrcfluoromethane ug/1 50.00 45.88 92
1,2,3-TriChloropropaee ug/1 50.00 45.12 90
1,2,4-Trimethylbeazeno ug/1 50.00 43.31 87
1,3,5-Trimethylheazene ug/1 50.00 45.15 9D
Vinyl Chloride ug/1 50.00 43.79 88
Xylene (Total) ug/1 150.00 144.5 96
m&p-lylene ug/1 100.00 95.79 96
o-Xyleue ug/1 50.60 48.69 97
Toluene -dB (S) 100
4-Bromoflucrobenrene (S) 108
Dibromoflueromethane (S) 92
1,2-Dichlaroethane-d4 (S) 91
MATRIX SPIXB s MATRIX SPIER DUPLICATE: 927616482 927616440
Parameter
Benzene
927615419 Spike !LS M5u M5 MSD
Unita Result Conc. Reen]t Result % Rec %-E2B 2EPD• F_o_otnotea
ug/1 • 0 50.00 47.75 48.03 96 96 1
Date: 11/09/06 Pape 15 of 22
A frevilie C•¢rtifieetion !4g
NGWastrattor 40
NC Drinking Water 37712
SC Environmental 99030
R tioLAP E87648
REPORT OF LABORATORY ANALYSIS
ihfs repot shall riot b6 reprDCu." 4, e R t fug.
without the ortitten carsent of Pate Analytkol Somas, Inc
harfolte Cerjliset0 i 105
NC 4hstewatar 12
NC Drinking Water 37706
SC 99005
FL ((FLAP E87627
F

aeAnacar
wwwPaCeIRDS.Caet
Pace Analytical Services, Inc.
9800 MceyAvenue, Suite 100
Huntersvtlte, NO 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lek Project N tuber: 92130716
Client Project ID: Walgreeae Seattiee Ford Rd
MATRIX SPIKE & 3BTRIX SPITE DDPL1CATE; 527616482 927616490
927615415 Spike MS •MSD MS XSD
Ferameter U its Resul Cant• Result Result $ Rec % Rec 11.2 Footnotes
Chlorabenzene ug/1 0 50.00 47.97 48.36 96 97 1
1.1-Die]xloroethene ug/1 0 50.00 46.71 48.36 97 97 1
Toluene ug/1 0 50.00 45.25 45.37 90 91 0
Trichloroethene ug/1 0 50.00 45.82 45.72 92 91 0
Toluene-d8 (S) 100 100
4-Sromofluarobanzene (S) 103 104
Dibromofluoromathaaa (S} 96 97
1.2-Dichloroethaae-d4 (S) 91 92
Date, 11/0/e6 Pagel 17 of 22
Ashegple Certification IN
NC Wastewater 40
NC Drinking Water 37712
SC Emlronn,eMBl 99030
FL NET.AP E87645
REPORT OF LABORATORY ANALYSIS
This report ShaII not t e tepmdurge, wept in Tut
wit 0in the vale) cmaent of Pace Analytical Services, Inc.
Dilations Certification lOs
NC Wastewater 12
NC Drinking Water 37708
SC 99006
ANNELAP E87827
F

ceAnalytica!"
amtw.paceiabs vOm
Pace Analytksf $emres, 11w.
9800 KncayAvenue Suite 100
Nuntersvife, NC 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID; Walgreens Seattiee Pord Rd
QC Batch: 172041
QC Batch Method: EPA 245.1
Associated Lab Samples:
Analysis Method: SPA 245.1
Analysis Description: Mercury. CVAAS, in Water
927597211 927597229
METBOD BLANK: 927634592
Associated Lab Samples: 927597211 927597229
Blank Reporting
Parameter Units Result Limit Footnotes
Mercury ug/1 ND 0.20
LABORATORY CONTROL SAMPLE: 927634600
Pester
Mercury
Spike WS LCS
Unite Coat,Result Footnotes
ug/1 2.500 2.500 100
MATRIX SPIKE: 927634518
Parameter
Mercury
927597211 Spike M5 M3
Unite Result Conc. Retyylt k Res footnotes
ug/1 0.1140 2.500 3.71D 144 1
SAMPLE DUPLICATE: 927634626
parameter
Mercury
927537229 DVP
Unite keeult Result RPA Footnotes
ug/1 ND ID NC
Date: 11/09/D6 Papas 16 of 22
kshwilie Certdratan IN
NC Wastewater 40
NC Drinking Water 97712
SC Enmta:mental 99030
FL riaAP E67648
REPORT OF LABORATORY ANALYSIS
This wort shall not be reprauzed, except in full,
wflhaul the written cauenf of Pate Aneyk6 al Seniors, lne.
0harlotte Certification 105
NC Wastewater 12
NC Drinking Water 37705
S± 99636
R HELP E87627

aceAnralyticar
www.pacetabs.cnm
Pace Analytical Services, lac.
9800 Kincey Avenue, Sulfa 100
Huntersv111e, NC 28078
Phone: [phone]
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Walgreene 8eattiea Ford Rd
QC Hatch: 171256
QC Batch Method: SM 3030C
Associated Lab Samples:
Analysis Method: 22k 200.7
Analysis Description: 3030C Metals, ICP, Trace
927597211 927597229
14R'HOD BLAME: 927599332
Associated Lab Samples: 927597211 927597229
Blank Reporting
Parameter Brits Result Limit goottotee
Lead, 303DC ug/1 VD 5.0
LABORATORY CONTROL SAMPLE: 927599340
Spike LCS LCS
Parameter Units Cone. Result $ Ell Footnotes
Arsenic, 3030C ug/1 500.00 572.0 114
Cadmium, 3030C us/1 500.00 581.D 116
Chromium, 3030C _ us/1 500.00 532.0 106
Copper, 3030C us/1 500,00 534.0 107
Iron. 3030C us/1 5000.00 5319 106
Lea5. 3030C ug/1 500.00 561.0 112
Silver, 3030C ug/1 250.00 273.0 109
Sodium, 3030C us/1 5000.00 5860 117
MATRIX SPIKE: 927599357
927597211 Spike MS MS
Parameter Omits Result Conc. Result % Rec Footnotes
Arsenic, 3030C us/1 0.6030 500.00 563.0 112
Cadmium, 3030C us/1 0.6540 500.00 560.0 112
Chromium, 3030C ugfl 8.100 500.00 531.0 105
Copper, 3030C 129/1 18.70 500.00 554.0 107
Iron, 3030C ug/1 5049 5000.00 10430 108
Lead, 3030C 11g/1 2.810 500.00 541.0 108
Silver, 3030C ug/1 0.5940 250.00 48.10 19
Sodium, 303DC 119/1 5576 5000.00 10950 . 108
Data: 21/09/06
Asheville CertRtetion IDS
NC Wastnaht 40
NC Drinking Wa1r 37712
5C Environmental 99030
FL NELAP E87646
REPORT OF LABORATORY ANALYSIS
itis mat :hal as be reproducer!. except In fun,
sand inn writ', casent of Pax Analyti al Union, Inc.
Lnarlatte Certification 105
NC Wastewater 12
NC Drinking Water 37706
SC 99206
FL NELAP 287627
PeQar 19 of 22
F

aceAnalyttical
ww wpacelaDs com
Pica 1nalpilcat Services, Inc.
98001Gncey Avenue, Suite 100
Huniersville, NC 28078
Pharre: 704.875.9092
Fax 704, 875.9991
QUALITY CONTROL DATA
Lab Project Number: 92130716
Client Project ID: Walgroena Beatties Ford 8d
SAMPLE DOPLICATB: 927599365
927597229 D P
Parameter Pnits Result Result 222 Footnotes
Axcemic, 3D30C ug/1 ND ND NC
Cadmium, 3030C ug/1 ND ND NC
Chromium, 3030C u5/1 ND ND NC
Copper, 3030C ug/1 ND ND NC
Iron, 3030C ug/1 360.0 360.0 2
Lead, 3030C ug/1 ND ND NC
Silver, 3030C ug/1 ND ND NC
Sodium, 3030C ug/1 5100 4900 2
Pete: 11/02/06
dewurgie Certlficaslon 101 REPORT OF LABORATORY ANALYSIS Charlotte Certifkxlion IDS
NC YVa51CN21er 40 This rapt shad nee be reproduced, except 41141, NC 14asrtawater 12
NC Drinking Water 37712 Atka the r. consent e1 Pace pnet1tiral Seaiees, lne. NC Drlr'. Nlaler 37706
SC Ermronmental 90030 50 99006
FL NELAP E07648 ? L ? FL NEW' E07627
P0901 20 of 22
1

ceMalytfcal'
wwr! paoelatts.00m
Paces Anlytical Services, Inc. f
9800 Kincey Avenue, Soils 100
Nuniersville, NC 28078
Phone: [phone]
Fax.' 704.875.9091
QUALITY CONTROL DATA
Lab Project N:mlber: 92130716
Client Project ID: Walgreets Beatties Ford Rd
QC Retch: 171623
QC Batch Method: 13PA 375.4
Associated Lab Samples:
Analysis Method: EPA 375.4
Analysis Description: Sulfate,lurbidimetric
927597211 927597229
METHOD BLAH&: 927616904
Associated Lab Samples: 927597211 927597229
Blank Reporting
Parameter Units Result Limit Footnotes,
Sulfate mg/1 ND 5.D
LABORATORY CONTROL SAMPLE: 927616912
Spike LCS LCS
Faramete= units Conc. Result $ Roc Footnotes
Sulfate mg/1 20.00 19.12 96
MATRIX SPIXR: 927616920
parameter
Sulfate
927597211 Spike MS MS
Daita Result conc. Result % Ree FOytnatee
mg/1 1.991 20.00 21.02 95
SAMPLE D➢PLICAT; 92761593E
Parameter
Sulfate
927597229 DUP
Gaits Result Result ppn Footnotes
mg/1 ND ND NC
Doto. 11/P9/es ?age: 21 GE 22
AshavIfl Certif4elionj05
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP EB7646
REPORT OF LABORATORY ANALYSIS
The report shoe not be reproduced, except in ful,
without tin written natant ottPert Ansfylleal Servant. Inc.
cTiP9�!
t
Charlotte Certtl;atieniDI
NC Wastewater 12
NC Drinking Water 37706
5C 99w5
FL ti AP EB7627

(aeAnaMicaf'
wma.com
Pace Arral'lleal Sarriees, Ins.
9800 'Gncey Avenue, Suite 100
Nentersville, NC 28078
Phone: [phone]
Far 704.8759091
Lab Project Number: S2130716
Client Project ID: S7algreens Deattiee Ford Rd
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with SPA guidelines, unrounded concentrations are displayed end have been used to calculate 941 Rec and RPD values.
LC2(D) Laboratory Control Sample (Duplicate)
M5(D) Matrix Spike (Duplicate)
DDP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
3 Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
3IDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(5) Surrogate
111 The spike recovery was outside acceptance limits for the MS and /or MSD due to matrix interference. The LC5
and/or Gc5D were within acceptance 1imits showing that the laboratory ie in control and the data ie
acceptable.
121 The RPD value for the sample duplicate or MS/MSD was outside of QC acceptance limits due to matrix
interference. QC batch accepted based on LCS and/or LCSD recovery and/or RPD values.
Ditto: 21/09/26
Astsoll a Cerrifrcatmn IDg
NC Wastewater 40
NC Drinking Water 37712
SC Enrironrnertta1 94030
FL NELAP EB7649
REPORT OF LABORATORY ANALYSIS
This report shall nvl ire reproduced, except in len,
iebout the nntkn mama of Pace Awayucal So n. em tn
atetac
Chartolle Certi atton 1%
NC Wastewater 12
NC Drinking Water 37706
SC 99000
F1. NELAP EE7627
Pagel 22 of 22
f

(2eAnaIJ4icar
wwwpacelaes.cam
November 09, 2006
Mr. David Wagner
Clayton Croup Services
297 eighviev Drive
Chapel Hill, NC 27517
RS: lab Project Slumber: 92131564
Client Project ID: Nelgreeas SPR
Dear Mr. Wagner:
Paco Analytical Services, let. F
98001GnceyAvenue, Suite 100
HuatersvJlle NC 28078
Phone: [phone]
Far 704.875.9091
Hnclosed are the analytical results for sample(s) re:eland by the laboratory on October 30, 2006. Restate
reported herein conform to the most currant =LAC standards, where applieabl■, unless otherwise narrated in the
body of the report.
Inorganic Wet Chemistry and Metals Analyaee were performed et our Pace Asheville laboratory and Organic testing
was performed at our Pace Charlotte Laboratory unless otherwise Footnoted.
If you have any question concerning this report please feel free to contact ma.
sincerely,
I
Elvin Herring
kevLn.herringepacelabs.com
Project Manager
Enclosorea
for
• Asheville C^rtrfrcation IDS
Wastewater 40
NC Drinking Water 37712
SC Ertviroarnental 99030
FLNELA? E27648
REPORT OF LABORATORY ANALYSIS
Tlis report shall nce be repsadre3, csrpt m rat,
ivthost the eeinen cameo et Pact Antlyikni Savior, lne.
Chade to Genii rat,en Im
NC wastewater 12
NC Driridrrg Warr 37706
SC S9006
FL NELAP ES7627

aeAflalYticar
:nf,7v �elabscarr
Pace Raaiyticai Services, inc.
9800 Kin cey Avenue, Sulto 100
Hurrtersviile, NC28078
Phone: [phone]
Far 704.875.9091
Lab Project Number: 92131584
Client Project ID: Walgreeae BFR
Lab Sample No: 927616474
Client Sample ID: P!4W-1 1 WERE
Pnram@SDr.s
Metals
3030C Metals, 1Cp, Trace
Arsenic, 3030C
Cadmium, 3030C
Chromium, 3030C
Copper, 30300
Iron, 3030C
Lead, 3030C
Silver, 3030C
Sodium, 3030C
Date Digested
Mercury, CVAAS, is Water
Mercury
Wet Chemistry
Sulfate,Turbidizeetric
Sulfate
GC/MS Volatiles
GC/MS VDCB by 8260, lox level
Acetone
Benzene
Bramoben:ens
Bromochloramethane
Bromodichlormethane
sremoferm
Bramomethane
2-Butenone (Z0310
a-Butylben:ens
Dec-Butylba:none
tart-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethame
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Date: 11/09/C6
Project Sample Number: 92131584-001 Date Collected: 10/30/06 00:00
Results Units Renart Limit'
Prep/Method:
ND
ND
ND
ND
400
ND
ND
4500
10/31/06 11:15
SM 3030C / EPA
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
Method: SPA 7470
0.22 us/1
Method: EPA 375.4
ND ng/1
200.7
5.0
1.0
5.0
5.0
50.
5.0
5.0
1000
Matrix: Water
Date Received: 10/30/06 15:37
Analysed av CAS No. Qual MeoLmt
11/01/06
11/01/D6
11/01/06
11/01/06
11/01/D6
11/01/D6
11/01/06
11/01/06
10/31/06
23:06
23:06
23:D6
23:06
23:06
23:06
23:06
23:06
11:15
7440-38-2
744D-43-9
7440-47-3
7440-50-8
7439-89-6
7439-92-1
7446-22-4
7446-23-5
0.2D 11/07/06 11:20 ALV 7439-97-6
5.0 11/03/06 11:41 TER
Method: EPA 8260
2900 ug/1 1200 10/31/06 19:38
20000 ug/1 200 10/31/05 19:38
ND 149/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
4600 ug/1 250 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 14:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/D6 19:38
ND ug/1 50. 10/31/06 19:38
ND ug/1 50. 10/31/06 19:38
Asher -Fe Certification kill
NC Wastewater 40
NC Drin1dng Water 37712
SC Environmental 93030
FL NEAP E8764B
REPORT OF LABORATORY ANALYSIS
its :epn,t shall no: 0e reproduced. meet In full,
v iflnt0 the verb, consent cif Fax
Anal}2pl Services, kn
MSF
NSF
MSF
NSF
MSF
145F
NSF
MSF
M0F
MSF
MSF
MSF
NSF
HSF
NSF
MSF
MSF
MSF
67-64-1
71-43-2
108-86-1
74-97-5
75-27-4
75.25-2
74-83-9
78-93-3
104-51-8
135-98-8
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
Snar atte Certification IDl
NC Wastewater 12
NC Drinking Warr 37705
SC 99005
FL NELAP E87627
Pago: 1 of 14
f

ceAnalydca!"
WNW-
Pace Analytical Services, inc
9800 Kincey Avenue, Suite 100
Huntersvilie, NC28078
Phone: [phone]
Fax: 704.875,9091
Lab Project Number: 92131564
Client Project ID: 1Palgreens BFR
Lab Sample No: 927616474 Project Sample Number: 92131564-001 Date Collected: 10/30/06 DD:00
Client Sample ID: PMW-1 1 WRIAX Matrix: Water Date Received: 10/30/06 15:37
Parameters _ Results Vnits Report Limit Analyzed 8y CAS No. Qi Re Lm
1,2-Dibromo-3-chloropropane ND ug/l 50. 10/31/06 19:38 MSF 96-12-8
Dibromoehloromethane ND ug/1 50. 10/31/06 19:38 MSF 124-48-1
1,2-Dibromcethane f6DB) 520 ug/1 50. 10/31/06 19:38 MSF 106-93-4
Dibromamethane ND ug/1 50. 10/31/06 19:38 NSF 74-95-3
1,2-Dichlorcbeazene ND ug/1 50. 10/31/05 19:38 MSF 95-5D-1
1,3-Diehlorobenzene ND ug/1 50. 10/31/06 19:38 NSF 541-73-1
1,4-Dichlorobenzene ND ug/1 50. 10/31/06 19:38 MS? 106-46-7
Dichlorodiflucromethane ND ug/1 50. 10/31/06 19:38 NSF 75-71-8
1,1-Dichloroethane ND ug/1 50. 10/31/06 19:38 NSF 75-34-3
1,2-Dichloroethane 2000 ug/1 50. 10/31/06 19:38 NSF 107-06-2
1,2-Dichlaroethene (Total) ND ug/1 . 50. 10/31/06 19:38 MSF 540-59-0
1,1-Dichloroethene ND ug/1 50. 10/31/06 19:38 NSF 75-35-4
cis-1,2-Dichloroethene ND ug/1 50. 10/31/06 19:38 MSF 156-59-2
trans-1,2-Diehloroethene ND ug/l 50. 10/31/06 19:38 MSF 156-60-5
1,2-Dicticropropane ND ug/1 50. 10/31/06 19:38 MSF 78-87-5
1,3-Dichloropropane ND ug/1 50. 10/31/06 19:38 NSF 142-28-9
2,2-Dichloropropene ND ug/1 50. 10/31/06 19:38 NSF 594-20-7
1,1-Dichlorapropene ND ng/1 50. 10/31/06 19:38 NSF 563-58-6
Dilsoprcpyl ether 580 ug/1 50. 10/31/06 19:38 NSF 108-20-3
Ethylbenzene 1BDO ug/1 50. 10/31/06 19:38 N3F 100-41-4
Hexachloro-1,3-butadiene ND ug/1 50. 10/31/06 19:38 NSF 87-68-3
Isopropylbenzene (Cunene) 65. ug/1 50. 10/31/06 19:38 MSF 98-82-8
p-Isopropyltoluene ND ug/1 50. 10/31/06 19:38 NSF 99-87-6
Methylene chloride ND ug/1 100 10/31/06 19:36 NSF 75-09-2
Methyl-tert-butyl ether 58. ug/1 50. /0/31/06 19:38 NSF 1634-04-4
Naphthalene 240 ug/1 50. 10/31/06 19:38 NSF 91-20-3
n-Propylbeazene 140 ug/1 50. 10/31/D6 19:38 NSF 103-65-1
Styrene ND ug/1 50. 10/31/06 19:38 NSF 100-42-5
1,1,1.2-Tetrachloroethane ND ug/1 50. 10/31/06 19:36 NSF 630-20-6
1,1,2,2-Tetraehloroethaae ND ug/1 50. 10/31/06 19:38 MSF 79-34-5
Tetrachloroethene ND _ ug/1 50. 10/31/06 19:38 145F 127-16-4
Toluene 31000 0g/1 200 10/31/06 19:38 MSP 108-88-3
1,2,3-Trichlorobensene ND ug/1 50. 10/32/06 19:38 MSF 87-61-5
1,2,4-Trichlorobenseae ND ug/1 S0. 1D/31/06 19:36 MSF 120-82-1
1,1,1-Trichloroethane ND ug/1 50. 1D/31/06 19:38 MSF 71-55-6
1,1,2-Trichloroethane ND ug/1 - 50. 1D/31/06 19:38 MSF 79-00-5
Trichloroethene ND ug/1 5D. 10/31/D6 19:38 MSF 79-01-6
Trichlorofluoromethaae ND ug/1 5D. 10/31/06 19:38 MSF 75-69-4
1,2,3-Trichloropropene ND ug/1 5D. 10/31/06 19:38 NSF 96-18-4
Date: 11/89/06 Pagel 2 o0 14
As0Bvllte Cerlificatian rDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NEL FiP EB7848
REPORT OF LABORATORY ANALYSIS
71 s report shall na he reprodued. e:capt in tutu,
without the wriLLer tersem & Pace Analytical Services, Inc.
Chartone Cartacasion I01
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP EB7627

aeAnaVtiCar
tatfnr. pa0t11abs_mrr:
Pace Analytfce Services, Inc
9800 Kinsey Avenue, Suite 100
Huntersville, NC28078
Phone: [phone]
Far 704.875 9091
Lab Project Number: 52131584
Client Project ID: Walgreene BFR
Lab Sample 1io: 927616474 Project sample Number: 92131584-001 Data Collected: 10/30/46 00:00
Client Sample ID: PMW-1 1 MEK! Matrix: Water Data Received: 10/30/06 15:37
Parameters Results Unite Report Limit Analyzed 0y CAS No. Oual ReaLmt
1,2,4-Trimetbyl.benzene 780 ug/1 50. 10/31/06 19:38 MSF 95-63-6
1,3,5-Trimethylbenzene 200 ug/1 50. 10/31/06 19:38 MSF 10S-67-8
Vinyl chloride ND ug/1 50. 10/31/06 19:38 MSF 75-01-4
Iylene (Total) 8200 ug/1 100 10/31/06 19:36 MSF 1330-20-7
nep-Xylene 5400 ug/1 1D0 10/31/06 19:38 MSF
o-Xylene 2900 ug/1 50. 10/31/06 19:38 MSF 95-47-6
Toluene -dB (S) 93 % 10/31/06 19:36 MSF 2037-26-5
4-8romofluarobenzene (S) 104 5 10/31/06 19:38 146F 460-00-4
Dibromnfluoromethane (s) 94 % 10/31/Di 19:38 MS7 186E-53-7
1,2-Dichloroethas:e-d4 (3) 92 % 10/31/06 19:38 1451, 17060-07-0
Date[ 11/0S 6
Ammilli Cerllficafion ID4
NC Wastwrater 40
NG Drinking Water 37712
SO Environmental 93030
fL NELAP E67640
REPORT OF LABORATORY ANALYSIS
This report shall re: be reproduced, excep1 iul.
Milani the wthle i ooresm of Pace Artyli:al Services, Inc.
fehdi
Charlotte CertiriCation !D4
NC Wastewater 12
NC Drinking Water 37705
50 99068
FL NELAP E67S27
Page: 3 of 14
F

aceAnalytical"
www paoEslabs oorn
Pare Malytiral Services, law. f
9800 navy Avenue, Sulk 100
Nurrtersvllle, NC 28078
Phone: [phone]
Fax [phone]
Lab Project Number: 92131584
Client Project ID: Walgreeme BFR
PARAMETER FOOTNOTES
Method 90718 modified to use Ass.
All pH, Free Chlorine, Total Chlorine and Ferrous Iron analyaos conducted outside of EPA recomsended da:mediate
hold tine.
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
2-Cbloroethyl vinyl other has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
Date: 11/64/06 Pager 1 of 14
Asheville CEficatinn lA;
NO Wastewater 40
NC Drtlrig Water 37712
SC Enviranmen121 29030
FLNELAP E8764B
REPORT OF LABORATORY ANALYSIS
ih''s repaid shall rotbe rep o:fixed, ercepl to fult
*alma the mitten comp/ of Pau Analytical SeMtr .tgk
ha.
Gharlotte Certltitat ei ID
NO Wasteardter 12
NC Drinking Water 37105
5C 99905
FL NELAP E87627

aceAnalyt%al'
wrvw.pac>°IaLscnm
Face Analyllcal Services, Inc. F
98r00!Olney Avenue, Suite 100
Hurrlersvilie, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131564
Client Project ID: Walgreens HPR
QC Hatch: 171658
QC Batch Method: EPA 8260
Associated Lab Samples:
927616474
Analysis Method: EPA B260
Analysis Description: OC/KS VDCs by 8260, low level
METHOD BLANK: 927618017
Associated Lab Samples: 927616474
Blank Reporting
Parameter Dilitc Result Limit Footnotes
Acetone ug/1 ND 25.
Benzene ug/1 ND 1.0
Bromobenzene ug/1 ND 1.0
Bromochloromethaae ug/1 ND 1.0
Brcmodichloromcthanc ug/1 ND 1.0
2rorofozm ug/1 ND 1.0
Bromomethane ug/1 ND 1.0
2-8utanone (MER) 11g/1 ND 3.0
n-Eutylbenzene ug/1 ND 2.0
sec-Eutylbenzene ug/1 ND .1.0
test-Butylbenzene ug/1 ND 1.D
Carbon tetrachloride ng/1 ND 1.0
Chlorabanzen° 12g/1 ND 1.0
Chloroethane ug/l ND 1.D
Chloroform ug/1 ND 1.D
Chlorcmethane ug/1 ND 1.0
2-Chlorotoluene ug/1 ND 1.0
4-Cblorotoluene ug/1 ND 1.0
1,2-Dibromo-3-chloropropane ug/1 ND 1.D
Dibramochlaromathaoe ug/1 DP 1.D
1,2-Dibromoethase (BB) ug/1 ND 1.D
Dibromomathana ug/1 ND 1.0
1,2-Lichlorobenzeno ug/1 ND 1.0
1,3-Dichlorobanzene ug/1 ND 1.0
1,4-Dichlorobenzene ug/1 ND 1.0
Dicblorodifluoromethane ug/1 ND 1.0
1,1-Dichloroethane ug/1 ND 1.0
1,2-Dichlaroethane ug/1 ND 1_0
1,2-Dichloroethene (Total) ug/1 ND 1.0
1,1-Dichloroethene ug/1 ND 1.0
cis-1,2-Dichloroethene ug/1 ND 1.0
Dater 1149/e6 Pogar 3 of 14
AsrreuIlle Certification ID4
NC Wastewater 40
NCDrinklnp Water 37712
SC EnvironraerY,al 99330
R NELAP E87648
REPORT OF LABORATORY ANALYSIS
ihla mart hall nd ht reproduced, poops fn fu9,
vdthout the writers Cur .1af Pace Arralylaal Strvim, Inc.
Charlotte Certnicallon f06
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL UGLAP 647627

/.2eAnaIyticar
rev OSCEdaCs corn
Pace Ambit:al Services, Inc.
9800 Krncey Avenue Suitt 700
Huntersville, IOC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131584
Client Project ID: Walgreens EFR
METHOD ELANE: 927618017
Associated I,ab samples: 927616474
Blank Reporting
parameter gaits Reoult Limit Footnotes
trans-1,2-Dichloroethene ug/1 ND 1.0
1,2-Dichloroprapane ug/1 ND 1.0
1,3-Dich10 opropaae 11g/1 ND 1.0
2,2-Dichloropropane ug/1 ND 1.0
1,1-Dichloropropene ug/1 .ND 1.0
Diisopropyl ether ug/1 ND 1.D
Ethylbe1zene ug/1 ND 1.0
Hexaehltsra-1,3-butadiene ug/1 ND 1.0
Isopropylbeazeae (Cunene) ug/1 AID 1.0
p-Isopropyltolueae ug/1 ND 1.0
Methylene chloride 12g/1 AID 2.0
Methyl -tart -butyl ether ug/1 ND 1.0
Naphthalene ug/1 ND 1.0
a-Propylbeneene ug/1 ND 1.0
Styrene ' 41g/1 ND 1.0
1,1,1,2-Tetrachloroethene ug/1 ND. 1.0
1,1,2,2- Tetra chloroethane ug/1 ND 1.0
Totrachloroethane ug/1 ND. 1.0
Toluene ug/1 ND 1.0
1,2,3-Trichlorobenzene ug/1 MD 1.0
1,2,4-Trichlorobenzene ug/1 ND 1.0
1,1,1-Trichloroetheae ug/1 ND 1.0
1,1,2-Trichloroethane ug/1 ND 1.0
T;ic]tloreetheae ug/1 ND 1.0
Trichlosofluoromethane ug/1 ND 1.0
1,2,3-Trichloropropane ug/1 ND 1.0
1,2,4-Trimethylbenzene ug/1 3D 1.0
1,3,5-Trimethylhenuene ug/1 Np 1.0
Vinyl chloride ug/1 ND 1.0
%ylene (Total) ug/l ND 2.D
m+rp-8ylene ug/1 ND 2.0
o-Tylene ug/1 ND 1.0
Toluene-d8 (S) % 99
4-Dromafluorobenzeae (S) % 104
Dibromofluoromethaue (S) 9t 92
I,2-Dichloroethene-d4 (S) 1r 85
Date: 11/09/e5 ?ago: 5 of 14
Asheville Certification I65
NC Wastewater 40
NC Drink% Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report hall nffi he repioface4. etoot In Ni
without the written coeae+rl of Pace Analytical Servtee. Inc.
gharlohe Certlfita1IDn ID5
NC Wastewater 12
NC Drinking Water 37706
SG 99406
FL NELAP E87627

aceAnalyticar
riww.pacelabs com
Pace Analytical Services, lac.
9800 Kincey Avenue, Surle 100
Nuntersville, NC 28078
Phone: [phone]
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92131584
Client Project ID: Walgreen8 BFR
LABORATORY CONTROL SAMPLE: 927618025
Spike LCS LCS
parameter Chits Conc. Result Rea gootnoten
Acetone ug/1 100.00 83,8D 84
Benzene ug/1 50.00 44.6D B9
Bromabenzene ug/1 50.00 42.77 86
3romochlorcmethene ug/1 50.00 42.03 84
Bromodichloromethane ug/1 50.00 47.14 54
Bremoform ug/1 50.00 44.71 89
Bromamethane ug/1 50.00 35.32 71
2-Butanone (MSK) ug/1 100.00 85.54 86
n-Butylbenrene ug/1 50.00 53.18 106
sec-Butylbenzene ug/1 50.00 55.72 111
tart-Butylbenzene us/1 50.00 52.58 105
Carbon tetrachloride ug/1 50.00 49.77 100
Chlorobenzene ug/1 50.00 45.52 91
Ckloroethane ug/1 50.00 42.7D 85
Chloroform ug/1 50.00 42.54 85
Chloromethane ug/1 50.00 38.20 76
2•Chlorotoluene ug/1 50.00 45.63 91
4-Chlorotoluene ug/1 50.00 45.33 91
1,2-Dibromo-3-chlorapropane ug/1 50.00 36.32 73
Dibromochloromethena ug/1 50.00 42.76 86
1,2-D7 romoethane (EDB) ug/1 50.00 47.95 96
Dibramomethane ug/1 50.0D 46.60 93
1,2-Dichlorobenzene ug/1 50.00 46.41 93
1,3-Dichlorobenzene ug/l 50.00 47.51 95
1,4-Dichlorobenzene ug/1 50.00 45.67 9I
Dichlorodiiluo:omethane ug/1 50.00 38.31 77
1.1-Dichloroethane ug/1 50.00 43.52 87
1,2-Dichloraethane ug/1 50.00 38.49 77
1,2-Diehloroethene (Total) ug/1 100.00 100.7 101
1,1-nichloroatheoe vg/1 50.00 47.01 94
cis-1,2-Dichloraethene ug/1 5D.00 53.84 108
trans-1,2-Dichloroathene ug/1 50.00 46.86 94
lr2-Dichloropropane ug/1 50.00 45.82 92
1,3-Dichloropropane ug/1 50.00 46.05 92
2,2-Dichloropropene ug/1 50.00 48.63 97
1,1-Dichloropropene ug/1 5D.00 43.98 88
Diisopropyl ether ug/1 50.00 44.98 90
Date i 11/09/06 Papa; 7 of 14
Asheville CBild:.1,m 4D5
NC Wastewater 40
NC Drinking Water 37712
SC Errrironrnental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report shall not 9e reproduced, tzcapl in 1v4
without The wri3^en D issent of Fax Analytiml Senices, Ins.
Y c'J J3dLlha'.
gharlotte Certilira1Eon PD1
NC Wastewater 12
NC Drinking Water 37706
SC 69006
FL NRAP E67627
f

(..eAnaIYtica
wimpacelobs con
Pace Analytical Services. Inc.
9800 KinceyAvenue, Suiie 100
FFunfersville, NC28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab project Number: 92132564
Client Project ID: walgreens BFR
LABORATORY CONTROL SA1@L8: 927618025
Spike LCS LCS
Parameter Units Cone. Result % Rec Footnotes
Ethylbenzeae ug/1 50.00 46.01 92
Mexachloro-1,3-butadiene ug/1 50.00 62.04 124
Tsopropylbenzene (Cunene) ug/1 50.00 52.61 105
p-Isopropyltoluene US/1 50.00 51.79 104
Methylene chloride ug/1 50.00 41.81 84
Methyl-tert-butyl ether ug/1 50.00 43.31 87
Naphthalene ug/1 50.00 30.97 62
n-Propylbenzeno ug/1 50.00 49.29 99
Styrene ug/1 50.00 49.27 98
1,1,1,2-Tetrachloroathane ug/1 50.00 50.40 101
1,1,2,2-Tetrachloroetbane ug/1 50.00 49.37 99
Tetrachloroethene ug/1 50.00 49.13 98
Toluene ug/1 50.00 42.90 86
1,2,3-Trichlorobenzeae ug/1 50.00 40.23 80
I,2.4-Trichlorebenzene ug/1 50.00 48.69 97
1,1,1-Trichloroethane ug/1 - - 50.00 45.31 91
1,1,2-Trichloroethane ug/1 50.00 44.34 89
Trichloroethene ug/1 50.00 44.36 89
Trichlorofluoronethene ug/1 50.00 44.88 90
1,2,3-Tric,hlcroprnpeae ug/1 50.00 43.47 87
1.2.4-Trimethylbenzene ug/1 50.00 44.05 BB
1,3,5-Trimethylbenzene 1.1g/1 50.00 45.18 90
Vinyl chloride vg/1 50.00 39.83 80
Xylene (Total) ug/1 150.00 142.9 95
m&p-Xylene u2/1 100.00 94.73 95
o-xylene ug/1 50.00 48.15 96
Toluene -de (S) 100
4-Bromoflucrabenzene (S) 10B
Dibromoflueromethano (S) 92
1,2-Dichloroethane-d4 (S) 90
MATRIX SPIER & MATRIX SPIKE DUPLICATE! 927620260 927620278
Parameter
Benzene
Date: 11/09/06
927611608 Spike MS M5D MS M5D
Unita Result Conc. Result Result % Rec % Rao RPD Footnotes
u9/1 0.3731 50.00 47.95 53.83 95 107 12
Asheville Certification 104
NC Wastewater 40
NC Drinking Water 37712
5C Erwironmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
Th}e report stoat not be reproduced. except in 'EA
without tha written consent of Pace pca1 cal Setvlxs, Inc.
,Gtnllntie Certification IQS
NC Wastewater 12
NC Drinking Water 37706
SG 99006
FL NELAP E67627
page: a of 14
F

aceAnalytical
wwwpateLabs.Com
Pace Analytical Sondrs, Inc~
9800 Klncey Avenue, Suite 100
Huntersvllle, NC 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131584
Client Project ID: Walgreene SFR
I91TRIX SPIKE & MATRIX SPIKE DUPLICATE: 927620260 927620278
927611608 Spike !IS MSD MS MED
Parameter Units Result Conc. Result Result ��� % Rea REP. Footnotes
Chlorobeusene u9/1 0 50.00 49.55 54.70 99 109 10
1,1-Dichloroetheae ug/1 0 5D.00 47.40 54.17 95 1D8 13
Toluene ug/1 0.7281 50.00 46.09 51.99 91 102 12
Trichloroethene ug/1 0 5D.00 47.40 51.04 95 102 7
Toluene -dB (5) 99 98
4-Sramolluoroben e.o (9) 104 100
Dibramafluoromethane (S) 92 97
1,2-bichloroethane-d4 (S) 86 99 1,1
Date: 11/09/0fi Page: 9 of 14
Asheville CertiToation IDS
NC Wastewater 40
NC Chinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This report Shall not 6e reproo re4, except In M.
witrout LN WT 00I1 carseal of Pace Analyii l SeM n Inc.
);harlotte Ce t tic0Si0n It o
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NELAP E67627

/2eAnayllcar
www.pecelebs.com
Pace Analyilral Services, loc.
98001GnceyAvenue, Suite 100
Nurrfersville, NC 28078
Phone: [phone]
Fax.: [phone]
QUALITY CONTROL DATA
Lab Project Number: 42131584
Client Project ID: Walgreens BFR
QC Batch: 172266
QC Batch Method: SPA 7470
Associated Lab Samples:
927616474
Analysis Method: EPA 7470
Analysis Description: Mercury, CVAAS, in Water
METHOD BLANK: 927645234
Associated Lab Samples: 927616474
Parameter
Mercury
Blank Reporting
baits Result Limit 7ooaotes
ug/1 ND 0.20
LABORATORY CONTROL SAMPLE: 927645242
Parameter
Mercury
Spike LCS LCS
UAitP Cone. Result % Rec Footnotes
ug/1 2.500 2.500 100
MATRIX SPIXE: 927645259
Parameter
Mercury
927616474 Spike MS HS
Gaits Result Result k Rea Footnotes
ug/1 0.2170 2.500 1.960 70 2
SAMPLE DOPLICAT$: 927645267
Parameter
Mercury
927644823 D7P
Pai,¢p Result Result 77PD Pootnotea
ug/1 ND ND NC
Meta: 11/09/06 Pages 10 of 14
Asheville Genf it tiara IDo
NC Wastewater 40
NC Dtirddng Water 37712
SC Environmental 99030
R. MAP E87648
REPORT OF LABORATORY ANALYSIS
The report shall rat be iterodused, errant in fu9,
with0el CIE wri0:.n c.c ent d Para Mayikkat Swims, IPG.
Charlotte Certnitatlee log
NO Wastewater 12
NC Drinking Water 37708
5C 99008
FL NELAP 887527
F

(i
aceAnalyticar
wumfommebbs.c0M
Pare Analytical Services, Inc.
9850May Avenue, Suite 100
liuntersviile, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131584
Client Project ID: Walgreens BFR
QC Batch: 171629
QC Batch Method: SM 3030C
Associated Lab Samples:
927616474
Analysis Method: SPA 200.7
Analysis Description:-3030C Metals, ICP, Trace
0TBOD BLANK: 927617100
Associated Lab Samples: 927616474
Slack Reporting
parameter Units Result Limit poataotes
Arsenic, 3030C ug/1 ND 5.0
Cadmium, 3030C ug/1 ND 1.0
Chromium, 3030C ug/1 ND 5.0
Copper, 3D3DC ug/1 ND 5.0
Iran, 3030C ug/1 ND 50.
Lead, 303DC u9/1 ND 5.0
Silver, 3D3DC - ug/1 ND 5.0
Sodium, 3D30C ug/1 ND 1000
LABORATORY CONTROL SAJ16: 927617118
Spike LCS LC3
garpmeter Units Cone. Result Rae Footnotes
Arsenic, 3030C ug/1 500.00 557.0 111
Cadmium, 3030C u9/1 500.00 566.0 113
Chromium, 3030C ug/1 500.00 521.D 104
Copper, 3030C ug/1 5E10.00 516.0 104
Iron, 3030C ug/1 5000.00 5325 107
Lead, 3030c ug/1 5D0.00 547.D 109
Silver, 3030C ug/1 250.00 272.D 109
Sodium, 303DC ug/1 5000.00 5764 115
MATRIX SPIKE: 927617126
927616456 spike MS HS '
ponamater unite Result anc Result 6 Rep pootnoten
Arsenic, 3030C ug/L 2.060 500.00 525.0 105
Cadmium, 3030C ug/1 0.8870 500.00 508.0 101
Chrrffiiwa, 3030C ug/1 4.500 500.00 464.9 96
Data: 11/09/06 Page: 11 of 14
Asheville CerlIfitaSon_}A5
NC Wastewater 40
NC -Drinking Water 37712
SC Emrironmerdal 99330
FL NELAP E87648
REPORT OF LABORATORY ANALYSES
Thls croon shin nix 6e rcy+nd,ce cams M WI,
vienut thavridsn cavern of PaoArdytical Servcp, In .
Plaviptte Certifi:ation 195
NGWastewatar •12
NC Drinkn0 Water 37706
SC 99005
FL NEAP 667627
F

aceAnalyticar
wwwpsoe3abs.aom
Pare Amigo! Ser,Jres, inc.
9800Kfrn yAvenue, Suite 100
Huntersville, NC 28078
Phone: 704.875,9092
Fax 704.875,9091
Qi7ALITY CONTROL DATA
Lab Project Nr,mber: 92131584
Client Project ID: Walgreens RFR
MATRIX SPIKE: 927617126
927616458 Spike MS MS
Parameter Unite Result Conc. Result % Rea Footnotee
Copper. 3030C ug/1 17.00 500.00 514.0 99
Iron, 3030C ug/1 6532 5000.00 12520 120
Lead, 3030C ug/1 0.6420 500.00 489.0 98
Silver, 3030C u9/1 3.080 250.00 256.0 101
Sodium, 3030C ug/1 43950 5000.00 48100 83
9AMPLR DIM/CATS: 927617234
927616466 DUP -
pagame er Omits Result Result gk 7 otnotes
Arsenic, 3030C ug/1 ND ND NC
Cadmium, 3030C ug/1 ND ND NC
Chromium, 3D3DC ug/1 6.400 ND NC
Copper, 303DC ug/1 12.00 12.00 8
Iron, 3030C ug/1 — 7500 830D 6
Lead, 3030C ug/1 ND ND NC
Silver, 3030C ug/1 ND ND NC
Sodium, 3030C ug/1 21000 2200D 1
Data: 11/69/6G Page. 12 of 11
Asheville Cetlitieatinn 106
NG Wastewater 40
NC Drinkive Water 37712
SC Eattlronmeniel 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
'Mb repovt shaft rad be repmdvced, except In tun,
vithrnn the wriorncement or Pox Arvlyi215eMots, inc.
pharioefs;BUjuniion 1D5
NO Wastewater 12
IC Drinkhe Wafer 37706
SC 99006
FL !OAP 567627
F

(.eAI1aticarPae
arsve.Faoetrsmm
AnalyticalWO KincyAvenuo. Suite WO Hunie sville, NC28078
Phone: [phone]
fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131584
Client Project ID: Walgreena SFR
QC Batch: 171996
QC Batch Method: EPA 375.4
Associated Lab Samples: 927516474
Analysia Method: SPA 375.4
Analyaie Description: 5ulfate,Tu'bidimetric
MOOD BLANK: 927633347
Aaeociated Lab Samples: 927616474
Parameter Units
Blank Reporting
Result Limit Footnotes
Sulfate mg/1
,
ND 5.0
LABORATORY CONTROL SAMPLE: 927633354
Parameter Units
Spike LCs LCS
Conc. Result % Rec gootnotes
Sulfate mg/1
20.00 18.58 93
MATRIX SPIKE: 927633362
Parameter Units
927616474 Spike MS M8
Result Conc. Result % Res Footnotes
Sulfate mg/1
1.160 20.00 19.06 90
SAMPLE DUPLICATE: 927634147
Parameter units
927629717 DoP
Rn331t Revolt ggp Footnotes
2ege: 13 o: 24
Sulfate mg/1
Pate: 17./09/05
Asheville Certification 1114
ND ND NC
REPORT OF LABORATORY ANALYSIS Dharlotte Certlflcatian 112,2
NC Wastewater 40
NC Drinking Water 37712
SC Environmental P2030
FL SEiAP E87648
net report saeP not be reproduced, except in NIL NC 16estnrvaler 12
4ei4mutthe wnitttal sent o<pece Analytical Seamy, Inc. NC Drinking Water 37706
~ SC MOOS
% FL Na AP E8762c7

(2eAnatitcar
www.paoelaes.com
Pace Analytical Services, The. F
9800 KlnceyAvenue, Suite 100
Nuntersv111e, NC 28078
Phone: [phone]
Fax [phone]
Lab Project Number: 92111584
Client Project ID: Walgreena BPR
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with SPA guidelines, uarounded eoacestrations are displayed and have been used to calculate % 2ec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
ES(D) Matrix Spike (Duplicate)
DDP Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
(1] Sample was received by the laboratory without acid preservation as recommended by the CB EPA.
(2] The spike recovery was outside acceptance limits for the MS and /or MSD dna to matrix interference. The LCS
and/or LCSD were within acceptance limits showing that the laboratory is in control and the data le
acceptable.
Deter 11/09/01 Dagor 14 oe 14
*OWN Carjiricdtien leg
NC Phstewatee 40
NGDrinkin!Water 37712
SC Ei emnmental 99033
RNELAP E87648
REPORT OF LABORATORY ANALYSIS
Thlc report shall rat 6s reproduced, oseft in fat
uAttroto the villein consent d Pea Analytical Services, toe.
Lhar1o11 Certification IDs
NC Wastewater 12
NC Drinldn; Water 37706
SC 93036
FL NELAP 667627

(2eAnaIYt/caI
wvempacetabs coals
Novotber 15, 2006
Mr. David Wagner
Clayton Group Services
297 Highview Drive
Chapel Hill, NC 27517
RBI. Lab Project Vumberl 92131916
client Project IDt BPS. PILOT STUDY
Dear Mr. Wagner:
Pace Analytical Services. Inc.
980D Oro eyAvenue, Suite 100
Hentersvtle, NC28078
Phone. [phone]
Fax [phone]
3aeloaod are the analytical results for samples) received by the laboratory on November 10, 2006. Results
reported herein conform to the most current NLLI.0 standard', where applicable, unless otherwise narrated in she
body of the report.
Inorganic wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory atd Organic testing
yea performed at our Pace Charlotte laboratory unless ottL�rise footnoted.
If you hello any questions concerning this report please feel free to contact me.
Sinceyr]e�l�y, %y//n/
]Sevin Herring
kevin.herriag0pacelabs.com
Project Manager
Enclosures
for
Asheville Certification 11)5 REPORT OF LABORATORY ANALYSIS Charlotte Certifl 8tIOD 105
NC Wastewater 40 The reppi alien not he reproduced. eneptie full. NC Wastewater 12
NC Drinking Water 37712 within; the meiaen consent el Pace Analytical SeMxs, Inc. NC Drinking Water 37706
SCEs ircnm ttat 99030 SC 89D05
R NEiAP E67640 c k :y%. FLeELAP 687627
4
1

aceArralyticar
l'AvirPacelabs.com
Pace Analyih7tlServices; Inc.
9800XJnceyAvenue, Sane 100
Nuntersvrlle, NC28078
Phone: 704,875.9092
Far 704.875.9091
Lab Project Number: 92131918
Client Project ID: MR MOT STUDY
Lab Sample No: 927667261
Client Sample ID: PMW-1 2W2SB
parameters
GC/MS Volatiles
OC/M8 VOCa by 8260, for level
Acetone
Benzene
Brcmobenzono
Sromochloromethene
mromodichloramethane
Srcmmoform
9ramamethane
2-Butanone (Mag)
a-Butylbon:ene
sec-Butylhenzene
tert-Bntylbensene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluone
4-Chlorotolueae
1,2-Dibromo-3-chloroproptsno
Dibromochloramethane
1,2-Dibroxoethane (EDS)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichloroben:ene
Dichlorodifluoremethane
1,I-Dichloroetbane
1,2-Dichloroethane
1,2-Dichloroathnne (Total}
1,1-Diehloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroetbaae
1,2-Dichloroprcpane
1,3-Dichloropropane
2,2-Dicbloropropana
1,2-Diehloropropene
Diisopropyl ether
DUCO: 11J15/0S
Project Sample Number: 92131918-001 Date Collected: 11/10/06 11:45
Matrix: Water
Date Received: 11/10/06 15:20
Results Whits Report Limit Analyzed By CAS No. Qual_ Aea1 t
Method: SPA
3100
19000
ND
ND
ND
ND
ND
5500
12.
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
770
1D
ND
ND
ND
ND
ND
2500
ND
ND
ND
ND
ND
ND
ND
ND
780
NC Wastewater 40
NC Drinking Water 37712
SC Emlronmental 99030
FL N2LAP 1987648
8260
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
u9/1
ug/1
ug/1
ug/1
u9/1
u9/1
ug/1
ug/1
250 11/14/06 21:25 MSF 67-64-1
250 11/14/06 21:25 NSF 71-43-2
10. 11/14/06 21:25 MSF 108-86-1
10_ 11/14/06 21:25 MSF 74-97-5
10. 11/14/06 21:25 MSF 75-27-4
10. 11/14/06 21:25 MSF 75-25-2
10. 11/14/06 21:25 MSF 74-83-9
50. 11/14/06 21:25 MSF 78-93-3 1
10. 11/14/06 21:25 3558 104-51-8
10. 11/14/06 21:25 MSF 135-98-8
10. 11/14/06 21:25 MSF 38-06-6
10. 11/14/06 21:25 MSF 56-23-5
20. 11/14/06 21:25 MSF 108-90-7
10. 11/14/06 21:25 MSF 75-00-3
10. 11/14/06 21:25 MSF 67-66-3
10. 11/14/06 21:25 NSF 74-87-3
10. 11/14/66 21:25 MSF 95-49-8
10. 11/14/06 21:25 MSF 106-43-4
10. 11/14/06 21125 MSF 96-12-8
10. 11/14/06 21:25 3558 124-48-1
10. 11/14/06 21:25 MSF 106-93-4
10. 11/14/06 21:25 MSF 74-95-3
10. 11/14/66 21:25 MSF 95-50-1
10. 11/14/06 21:25 MSF 541-73-1
10. 11/14/06 21:25 MSF 106-46-7
10. 11/14/06 21:25 3558 75-71-8
10. 11/14/D6 21:25 353E 75-34-3
250 11/14/06 21:25 MSF 107-06-2
10. 11/14/06 21:25 MSF 540-59-0
10. 11/14/06 21:25 3528 75-35-4
10. 11/14/06 21:25 52F 155-59-2
10. 11/14/06 21:25 355E 156-60-5
10, 11/14/06 21:25 MSF 78-87-5
10. 11/14/06 21:25 MSF 142-26-9
10. 11/14/06 21:25 352E 594-20-7
10. 11/14/06 21:25 155F 563-58-6
10. 11/14/06 21:25 NSF 108-20-3
REPORT OF LABORATORY ANALYSIS
TMs report shall rme be reproduced, except h fu4
wtlhcmthe wri en consent of Pax Mt19tira] 5ervbes, ]ne
harloflectt aktil1i0g
NC Wastewater 12
NCDrinkboWater 37706
SC 99006
FINELAP E97627
Page 1 of 5
1

aeAnacar
oruror.pdCefaDS.COar1
Pare Analytical Senvlces, Inc.
9800 Kincey Avenue, Suite WO
ffunlersvilla, NO 28078
Phone: [phone]
Far 704, 875.9091
Lab Project Number: 92131918
Client Project ID: 8FR PILOT STUDY
Lab Sample Na: 927667261 Project Semple Number: 52131918-001 Date Collected: 11/10/06 11:45
Client Sample ID: PMW-1 2WSSf Mntriz: 14ater Date Received: 11/10/06 15:20
Parameters Reeulte Unite Report Lim1; Analyzed My CAA No. Qu4I BegInt
Ethylbenzene 2300 ug/1 250 11/14/06 21:25 MSF 100-41-4
Hexachloro-1,3-butediene ND ug/1 10. 11rl4/D6 21:25 MSF 87-68-3
Isopropylbeazene (Cunene) 90. ug/1 10. 11/14/D6 21:25 MSF 58-82-8
p-Isopropyltoluene ND ug/1 1D. 11/14/06 21:25 MSF 99-87-6
Methylene chloride ND ug/1 2D. 11/14/D6 21:25 MSF 75-09-2
Methyl-tert-butyl ether 66. ug/1 10. 11/14/06 21:25 MSF 1634-04-4
Naphthalene 210 ug/1 10. 11/1U80 21:25 M58f- 91-20-3
n-Propylbenzene 2D0 u9/1 10. 11/14/06 21:25 MSF 103-65-1
Styrene ND ug/1 10. 11/14/06 21:25 MSF 100-42-5
1,1,1,2-Tatrachloroethame ND ug/1 10. 11/14/06 21:25 MSF 630-20-6
1,1,2,2-Tetra0h1oroathaae ND ug/1 10. 11/14/06 21:25 MSF 79-34-5
Tetrechloroethane ND ug/1 10. 11/14/06 21:25 MSF 127-18-4
Toluene 30000 -a3$h 250 11/14/06 21:25 MSF 108-88-3
1,2,3-Trichlornbenzeme ND ug/1 10. 11/14/DS 21:25 MSF 87-61-6
1,2,4-Tricblorobenzene ND ug/1 10. 11/14/D6 21:25 MSF 120-82-1
1,1,1-Trichlorcethane ND ug/1 10. 11/14/06 21:25 MSF 71-55-6
1,1,2-Trichloroethane ND ug/1 10. 11/14/06 21:25 MSF 79-00-5
Trichloroethene 5D u9/1 1D. 11/14/06 21:25 MSF 79-01-6
Trichlorofiuorometbann ND ug/1 10. 11/14/06 21:25 MSF 75-69-4
1,2,3-Trichloropropane ND ug/1 10. 11/14/06 21:25 MSF 96-18-4
1,2,4-Trimetbylbenzene 13D0 ug/1 10. 11/14/06 21:25 MSF 95-63-6
1,3,5-Trimethylbe.D:emo 260 ug/1 10. 11/14/06 21:25 MSF 108-67-8
Vinyl chloride ND ug/1 10. 11/14/06 2I:25 MSF 75-01-4
Zylene (Total) 9900 ug/1 500 11/14/06 21:25 MSF 1330-20-7
mop-Zylene 6600 ug/1 50D 11/14/06 21:25 MSF
o-Zylene 3300 ug/1 250 11/14/06 2I:25 143F 95-47-6
Toluene-d8 (S) - 94 % 11/14/06 21:25 MSF 2037-26-5
4-8rcmofluorobeaaeae (5) 101 6 11/14/06 21:25 MSF 460-D0-4
Dibramofluoromethano (S) 103 % 11/14/06 21:25 MSF 1868-53-7
1,2-Dichloroethane-d4 (6) 91 *e 11/14/06 21:25 MS? 17060-07-0
Date: 11/15/96 Pagn: 2 e6 9
Ashey0e Certificaan 1fl
NC Wastewater 40
15C Drinking Water 37 712
SC E wirenreereat 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
lids tom stab not bs reproduced. except in M,
without the nnitM consult of Pace Anilylbel Sends. Inc.
t. CA
Charlotte Corfifioation 105
NC Wastewater 12
AS Drinking Water 37706
SC 90006
FL NELAP E87627

/eAnaIyticar
mvw.paoeJabs.ctom
Pare An fytfcalSoMacs, Inc.
9800 KfncoyAvenue, Suite 100
Nuntersvi le, NC 28078
Phone: [phone]
Fax [phone]
Lab Project Number: 3213191B
Client Project ID: SFR PILOT STUDY
PARAMETER FOOTNOTES
Method 9071H modified to use ARR.
All pH. Free Chlorine. Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending on the moisture content the PRLs can be elevated for all soil samples reported on a dry weight basis.
2-Chloroethyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(s) Surrogate
(1] Compound concentration extends the calibration range of the inetruMent (CLP E-Flag).
Data: 11/1S/06 Paw 3 of 9
Asp.Eville Certification IDS
NC Wastewater 40
NC Drinking Water 377712
SC Erfrironmentat 99030
FLNELAP E07649
REPORT OF LABORATORY ANALYSIS
This report stall at Le reproduced, except in tug.
'annul the written consort afPace Analytical Services, iris.
ft�a
(2tarlotte Cut fisetion ID:
NC Wastewater 12
NC Drini isg Water 37706
SC 99026
R NELAP E67627

/2eAnaIj4icar
nrempale.'abs.com
Pare Anarytical Services, Inc.
9600 KnceyAvenue, Suite 100
Hunterslr/11e, 1VC28078
Phone: [phone]
Fax. [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131918
Client Project ID: BPR PILOT BTUDY
QC Batch: 172858
QC Batch Method: EPA 8260
Associated Lab Samples:
927667261
Analysis Method: EPA 8260
Analysis Description: GC/MS VOCs by 8260, low level
METBOD BLAME: 927674952
Associated Lab Samples: 927667261
Blank Reporting
Parameter Unite Result Limit Footnotes
Acetone ug/1 ND 25.
Benzene ug/1 ND 1.0
Bromobeazene ug/1 ND 1.0
Bromochloronstbane ug/1 ND 1.0
Bromodichloromethane ug/1 ND 1.0
Bromofora 113/1 ND 1.0
Bromonetbane ug/1 ND 1.0
2-Butanone (MEg) ug/1 DID 5.0
a-Butylbeazeae ug/1 ND 1.0
sec-Butylbanzene ug/1 ND '1.0
tert-Butylbenzene up/1 ND 1.0
Carbon tetrachloride ug/1 ND 1.0
Chlorobenzene ug/1 ND 1.0
Chloroethane ug/1 ND 1.0
Chloroform ug/1 ND 1.0
Chloromlethane ug/1 ND 1.0
2-Chlorotoluene ug/1 ND 1.0
4-Cbloroteluene ug/1 ND 1.0
1,2-Dibramo-3-chloropropane ug/1 ND 1.0
Dibramochloromethane ug/1 ND 1.0
1,2-Dibromoethane (RD3) ug/1 ND 1.0
Dibromcmethane ug/1 ND 1.0
1,2-Dichlorobaazene ug/1 ND 1.0
1,3-Dichlorobenzeae ug/1 ND 1.0
1,4-Dicblorobenzene ug/1 ND 1.0
Dicblorodifluoromethane ug/1 ND 1.0
1,1-Dichloroethana ug/1 ND 1.0
1,2-Dichlorosthane ug/1 ND 1.0
1,2-Dichloroethene (Total) ug/1 ND 1.0
1,1-Dichloroethene ug/1 ND 1.0
cis-1,2-Dichloroethene ug/1 ND 1.0
linter 11/15/06 Page: 4 of 9
Asheville Certification IDg
NC Wastewater A0
NC Drinking Water 37712
5C Environmental 9A030
FL NELAP E8764
REPORT OF LABORATORY ANALYSIS
TVs report chae rwt be reproduce. except in Lull,
without 1h: written consent of Pau Analytical SenArxs, Inc.
3�3
Charlotte Certification Ilia
NC Wastewater 12
NC Drinking Water 37706
SC 99006
R NELAP E87627

aceAnalyiical
Kivivpamiatitcom
Pace Aralytliel Services, lac. F
9800 !array Avenue, Suite 100
Nurtiersville, NO28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131910
Client Project ID: ERR PILOT STUDY
METHOD BLAHS: 927674952
Associated Lab Samples: 927667261
Blank Reporting
parameter Onus Result __Limit Footnotes
trans-1,2-Dichloroethene ug/1 ND 1.0
1,2-Dichloropropane ug/1 ND 1.0
1,3-Dichlaropropane ug/1 ND 1.0
2,2-Dichloropropane ug/1 ND 1.0
1,1-Dichlosopropene ug/1 ND 1.0
Diisopzopyl ether ug/1 ND 1.0
Ethylbenzene ug/1 ND 1.0
eezachlora-1,3-butadiene ug/1 Nn 1.0
Isopropylbenzeae (Cunene} ug/1 ND 1.0
p-Iaopropyltolueae ug/1 ND 1.0
Methylene chloride ug/1 ND 2.0
Methyl -tart -butyl ether ug/1 ND 1.0
Naphthalene ug/1 -ND 1.0
n-Propylbeazene ug/1 ND 1.0
Styrene ug/1 ND 1.0
1,1,1,2-Tetrachloroethane ug/1 ND 1.0
1,1,2,2-Tetrachloreethane ug/1 ND 1.0
Tetrachlnroetheno mg/1 ND 1.0
-Toluene ug/1 ND 1.0
R - 1,2,3-Trichlorobe3zene ug/1 NM 1.0
1,2,4-Trichlorobenzene ug/1 ND 1.0
1,1,1-Tricblornethau• ug/1 ND 1.0
1,1,2-Trichloreethaae ug/1 ND 1.0
Trichloroethene ug/1 ND 1.0
Trichlorofluoranethans ug/1 ND 1.0
1,2,3-Trichlaropropane ug/1 ND 1.0
1,2,4-Trimethylbenzene ug/1 Nn 1.0
1,3,5-Trimethylbenzene ug/1 ND 1.D
Vinyl chloride ug/1 ND 1.0
Xyleie _(Total) - ug/1 ND 2.0
m&p-Xylene ug/1 ND 2.D
'�' o-xylene ug/1 ND 1.0
Toluene -dB (9) 6 99
4-Bronofluorobenzena (S) % 100
Dibrcmnflucroanethane (S} % 99
1,2-Dichloroethane-d4 (S) % 98
Gates 11/15/06 Page, 3 of 9
pShe ills Cert9metian I1l6
NC Wasltwatar 40
NC DrinkTnp 19atcr 37712
SC Environmental 49030
FLFIELAP E876eB
REPORT OF LABORATORY ANALYSES
This report shoe nwr be reproducer!. emcee In full,
wallet the whim souent of Pesr k etytaal ServI¢s. Ire.
Charlotte Certtcation 1DI
NC Wastewater 12
NC Drinking Water 37706 -
SD 99006
FL MAP- 07627

Pare Analgicaf Servtees, Inc. F
9800 KnreyAvenue, Suitt 100
Huntersvife, NG 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92131918
Client Project TD: SFR PILOT STUDY
LABORATORY CONTROL MIME: 527674960
Spike LCS LCS
parameter Unita Cone. Result Re Footnotes
Acetone 129/1 100.00 109.8 110
Benzene ug/1 50.00 53.15 106
Bromobenzene ug/1 50.00 50.57 101
Bramochloromethane ug/1 50.00 50.44 101
Bromodichloromethane ug/1 50.00 52.77 106
Bromoform 1)9/1 50.00 48.17 96
Bromomethane u9/1 50.00 61.57 123
2-Butanoae (HEM) ug/1 100.00 110.3 110
a-Butylhennone ug/1 50.00 47.11 94
sec-Butylbenzene ug/1 50.00 51.83 104
tent-Butylbeazene ug/1 50.00 50.47 101
Carbon tetrachloride ug/1 50.00 53.13 106
Chlorobesrese ug/1 50.00 51.71 103
Chloroethane ug/1 50.00 49.26 98
Chloroform ug/1 50.00 53.92 108
Chioromethane ug/1 50.00 49.70 99
2-Chlorotolueue ug/1 50.00 49.91 100
4-Chlorotoluene ug/1 50.00 50.27 101
1,2-Dibromo-3-cbloroprapane ug/1 50.00 44.30 89
Dibromochloromethane ug/1 50.00 47.65 95
1,2-Dibromoethane (1'sD3) ug/1 50.00 54.58 109
Dibramomethaxse ug/1 50.0D 53.27 107
1,2-Dichlorobenzene ug/1 50.00 49.90 100
1,3-D1chloroheazene ug/1 50.00 49.28 99
1,4-D1chlarebennene ug/1 50.00 49.14 98
Dichlorodifluorotaethane 12g/1 50.00 45.39 51
1,I-Dich1oroethane ug/1 50.00 55.13 110
1,2-Dichloroethnaa ug/1 50.00 50.15 100
1,2-Dichloroethene (Total) ug/1 100.00 112.2 112
1,1-Dichloroethene ug/1 50.00 61.04 122
cis-1,2-Diahloroethams u9/1 50.00 53.53 I06
trans-1,2-Dichloroethene vg/1 50.00 58_25 117
1,2-Dich1oropropane ug/1 50.00 54.71 109
1,3-Dichloropropaae 11g/1 50.00 51.94 104
2,2-Dichloroprcpeae ug/1 50.00 50.07 100
1,1-Dicbloroprapeue vg/1 50.00 54.53 109
Diioopropyl ether ug/1 50.00 52.74 105
Pats: 11/15/05 Pogo: 6 of 9
Asheville Certification i05
NC Wastewater 40
AiC Drinking Water 37712
SC Environmental 99030
FL NEU& 187640
REPORT OF LABORATORY ANALYSIS
The report rhaA sot be reproduced, exupl In full,
Aka
2,J •C
;bubble 5ertificallon_lDl
ND Wtsreviater 12
NC Drinking Water 37706
SC 99005
R. NERAP 687627

/2eAnaIy1icaI
wwtxpacelabs.com
•
Pace Analytical88nfces, Inc.
9800AinceyAvenue, Suite 100 •
Huntersville,11C 28078
Phan; 704,875.9092
Fax 704,875.9091
QUALXTY CONTROL DATA
Lab Project Number: 92131918
Client Project ID: BPR PILOT STUDY
LABORATORY CONTROL SAMPLE: 927674960
Spike LCS LCS
parameter Plaits Conc. Result sec 7ootaotee
Ethylbenzene ug/L 50.00 50.79 102
8exaohloro-1,3-butediene ug/1 50.00 51.64 103
Ieoprapylbenzene (Cunene) ug/1 50.00 53.40 107
p-Isopropyltoluene ug/1 50.00 46.98 94
Methylene chloride ug/1 50.00 47.92 96
Kethyl-tert-hutyl ether ug/1 50.00 51.00 1D2
Naphthalene ug/1 50.00 34.27 68
a-Propylbentene ug/1 50.00 51.14 102
Styrene ug/1 50.00 56.40 113
1,1,1.2-Totrachloroethaae ug/1 50.00 54.14 108
1,1,2,2-Tetrachloroethane ug/1 50.00 52.16 104
Tetrachloroethene ug/1 50.00 52.22 104
Toluene ugfl 50.00 51.50 103
1,2,3-Trichlorobenzene ug/1 50.00 52.18 104
1,2,4-Tricblorobenzene ug/1 50.00 52.42 105
1,1,1-Trichloroethane ug/1 50.00 55.54 111
1,1,2-Trichloroethane ug/1 50.00 50.97 102
Trichloroethene ug/1 50.00 53.04 106
Tricblorofluoromethaae ug/1 50.00 37.42 115
1,2,3-Trichloropropane ug/1 50.00 50.17 100
1,2,4-Trimethylbenzeae ug/1 50.00 46.22 92
1,3,5-Trimethy1. enzene .ug/1 50,0 46.51 93
Vinyl chloride ug/1 50.00 48.47 97
Xylene (Total) ug/1 150.00 156.3 104
n&p-Eylene ug/1 100.00 104.4 104
a-Xylsne ug/1 50.00 51.94 104
Toluene-d8 (S) 100
4-Bromofluorobenzone (S) 101
Dihro®ofluoromsthane (8) 100
1,2-P3chloroethene-d4 (Si 104
1O TRIK SPIN & MATRIX SPIXS DUPLICATE: 927674978 927674966
Paremeter
Benzene
927672634 Spike MS MSD MS MSD
pnj,ts Result Conc. Result Result 4 Rec % Rem RFD Footnotes
ug/1 0 50.00 58.04 56.61 116 114 2
Data: 11,15/7f Page: 7 c0 9
(_pteIIeCert icrio41I15
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 991130
FL NELAP E876e6
REPORT OF LABORATORY ANALYSIS
-this epod shall not be reproduced. suisadd In lul,
vmhoot tie vrtiten consent of Pace nnssuraJ services, ten
f.! a ac
.s
Charlotte Certification ID
NC Wastewater 12
NC Drinking Water 37706
5C 93006
FL PELAP 287627

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Pau Analytical Semites, lne. f
9800 VCmceyAv4nue, Suite WO
Nuatersville, NC 28078
Phone: [phone]
Far 704,875.9091
Lab Project Number: 9213191E
client Project TD: APR MOT STUDY
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent with EPA guidelines, unreunded concentrations are displayed and have been used to calculate 1 Rea
and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix $pike (Duplicate)
DUP Sample Duplicate
an Not detected at or above adjusted reporting limit
NC Not Calculable
Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
pate; 11/15/06 Pagai 9 of 9
Asheville Certilicafoo I
.11
NC Wastewater 40
NC DrinklnQ Water 37712
SG Environmental 99330
FL NELAP 117645
REPORT OF LABQRATORY ANALYSIS
This mart shall not be reproduwd. except In Nrt6.
without the Writhes consent o1 Pap Analytical Services. Inc.
Gharlots Denigration IDS
ND Wastewater 12
NC Drinking Wrier 3770G
SC °3006
FL N LAP E87627

/eAnaJyticar
wwr�:paoeta8s.00frl
November 77, 2006
Nr. David Wagner
Clayton Group Services
297 Righviev Drive
Chapel Hill, NC 2751.7
RE: Lab Project Number: 92132592
Client Project ib: Walgreems $FR
Dear Mr. Nasser:
Para Anai"Waa1 Ssmeas, inc.
9300 know Avenue, Suite WO
Hunfersvilfe, MC 28078
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results :or aerple(s) received by the laboratory on November 21, 2005. Results
reported herein conform to the most current raw C standards, where applicable, unless otherwise narrated is the
body of the report.
inorganic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing
vas performed at our Pace Charlotte laboratory unless ot`aesviae footnoted.
if you have any quearione concerning this report please feel free to content me.
Sincerely,
Kevin Herring
tevia_herringmpecelsba.cmn
Project Imager
Eau loaurea
for
Ate Pe rl ficativn 101
NC Wastewater as
NG Drinking Water 37712
SC Environmental 99030
FL NELAP EE7648
REPORT OF LABORATORY ANALYSIS
Th report shalt nW Pe reproduced were in full,
witrou1 the bitten canned el Pate Maryriter Scrvccs. lnc
Charlotte Certification CA
NC Wastewater 12
NC Drinking Water 37706
SC 99006
FL NEAP E87627
f

aceMaytica!"
Praw.pacelabscom
Pace Analytical Services, Inc.
9800 KrnceyAvenue, Suite 100
Kuntersviile, NC 28078
Phone: [phone]
FalC 704.875 9091
Lab Project Number: 92132592
Client Project ID: Walgreens B77
Leh Sample No: 927707653 Project Simple Number: 92132592-001 Date Collected: 11/21/06 11:45
Client Semple ID: PM96-1 1 MOM Matrix: Water Date Received: 11/21/06 12:15
parameters
Results yrzite Report Limit Ana2vzed By CAS No. Baal Reglmt
Metals
3030C Metals, SCP, Trace Prep/method: SM 3030C / SPA 200.7
Arsenic, 3030C DID ug/1 5.0 11/25/06 21:27 JDA1 744D-38-2
Cadmium, 3030C ND ug/1 1.0 11/25/06 21:27 JDA1 7440-43-9
Chromium, 3030C ND ug/1 5.0 11/25/06 21:27 JDA1 7440-47-3
Copper, 3030C ND ug/1 5.0 21/25/06 21:27 JDA1 7440-50-B
Iron, 3D30C 1100 u9/1 50. 11/25/06 21:27 JDA1 7439-89-6
Lend, 3030C ND ug/1 5.0 11/25/06 21:27 JDA1 7439-92-1
Silver, 3030C ND ug/1 5.0 11/25/D6 21:27 JDA1 7440-22-4
Sodium, 303DC 4300 ug/1 1000 11/25/06 21:27 JDA1 7440-23-5
Date Digested. 11/22/06 09:45 11/22/06 09:45
Mercury, CVAAS, in water Method: EPA 7470
Mercury
rD us/1
0.20 11/22/D6 11:27 ALV 7439-97-6
Wet Chemistry
Sulfate,Rurbidimetric Method: EPA 375.4
Sulfate ND mg/1 5.D 11/25/06 15:47 SAJ
GC/MS Valet/lea
GC/06S VOCs by 8260, 3.ov lerel Method: EPA 6260
Acetone 6100 ug/1 5000 11/26/06 14:46 MCK 67-54-1
Benzene 16000 ug/1 200 11/26/06 14:46 MCK 71-43-2
eramobenzene ND ug/1 200 11/26/06 14:46 MCA 108-86-1
BranochloronethAtta ND ug/1 200 11/26/06 14:46 MCK 74-97-5
Bramodichloromethane ND ug/1 200 11/26/06 14:46 MCX 75-27-4
Bramoferm ND ug/1 200 11/26/06 14:46 Mc9 75-25-2
Eromomethane ND ug/1 200 11/26/06 14:46 MCK 74-83-9
2-3utaaone (MBE) 6100 ug/1 100D 11/26/06 14:46 =X 78-93-3
n-Butylhenaene ND 129/1 200 11/26/D6 14:46 16CK 104-51-8
sec-8utylbenzene ND ug/1 200 11/26/06 14:46 MCK 135-98-8
tert-Butylbenzene ND ug/1 20D 11/26/06 14:46 MCK 98-06-6
Carbon tetrachloride ND ug/1 200 11/26/06 14:46 Mar( 56-23-5
Chlorobenzene ND ug/1 200 11/26/06 14:46 MCA 108-90-7
chloroetbane ND ug/1 200 11/26/06 14:46 NCK 75-00-3
Chloroform ND ug/1 200 11/26/06 14:46 MCK 67-66-3
Chlaromethane ND ug/1 20D 11/26/06 14:46 1= 74-87-3
2-ehlorotoluene ND ug/1 200 11/26/06 14:46 MCR 95-49-8
4-Chlorotoluana ND ug/1 200 11/26/06 14:46 t6CK 106-43-4
Date, 11(27/D6
AslurvirleCerIllicarion ID4
NC Wastewater 40
NC Drinking Water 37712
SC Environments! 95030
R. NELOP E67648
REPORT OF LABORATORY ANALYSIS
This report ilia not es reproduced. Meg 3 kik
witrein the written tmsent of Pace Anelyllen Services, M
e
C1arlefle Certtrication Its
NG Wastewater 12
NC Drinking Waler 37706
SC 99008
FL NELAP E67627
Page: 1 of 14
F

aceAnalyticar
rm etnacelabs caul
Pace Analytical Services, Inc.
9800 Kincey Avenue, Suite 100
Nuniersvitle, NC 28078
Phone: 704,875.9092
Far 704.875.9091
Lab Project Number: 92132592
Client Project ID: Walgreens 9FR
Lab Sample No: 927707553 Project Sample Number: 92132592-001 Date Collected: 11/21/06 11:45
Client Semple ID: PNW-1 1 MONTH
Matrix: Water Date Received: 11/21/06 12:15
Parameters Results Unite Report Limit Analyzed By CAS No. Qual Rea*
1,2-Dibromo-3-chlnropropane ND ug/1 200 11/26/06 14:46 MCK 96-12-8
Dibromoohloromethaae ND ug/1 200 11/26/06 14:46 MCK 124-48-1
1,2-Dibromoetbane (3D3) 530 ug/1 200 11/26/06 14:46 MCK 106-93-4
Dibromoaethaae 3D ug/1 20D 11/26/06 14:46 MCK 74-95-3
1,2-Dichlorobenzene 1m ug/1 200 11/26/06 14:46 MCK 95-50-1
1,3-Dichlorobeazeno ND u9/1 200 21/26/06 14:46 MCK 541-73-1
1,4-Dichlorobea:ene ND u3/1 200 12/26/06 14:46 MCK 106-46-7
Dichlorodifluoroanethane DID u2/1 200 11/26/06 14:46 MCK 75-71-8
1,1-Dichloroethane ND ug/1 200 11/26/06 14:46 MCE 75-34-3
1,2-Dichloroathaae 2700 ug/1 20D 11/26/06 14:46 MCK 107-06-2
1,1-Diehloroethene ED ug/1 200 11/26/06 14:46 MCE 75-35-4
cis-1,2-Dichloroethene ND ug/1 200 11/26/06 14:46 MCK 156-59-2
trans-1,2-Diehloroetheno ND ug/1 200 11/26/06 14:46 ME 156-60-5
1,2-Dichioropropane ND ug/1 200 11/26/05 14:46 MCE 78-87-5
1,3-Dichloropropane ND ug/1 200 11/26/06 14:46 MCE 142-28-9
2,2-Dichloropropaoe ND ug/1 200 11/26/06 14:46 NCK 594-20-7
1,1-Dichloropropeao ND ug/1 200 11/26/06 14:46 MCI 563.58.6
Diisopropyl ether 680 ug/1 200 11/26/06 14:46 NCS 108-20-3
Ethylbeuzene 2100 ug/1 200 11/26/06 14:46 MCI 100-41-4
8oxachloro-1,3-butadiene ND 4/1 200 11/26/06 14:46 NCI 87-68-3
Ieopropylbenzene (Cunene) ND ug/1 200 11/26/06 14:46 NCI 98-82-8
p-Iaopropyltoluene ND ug/1 200 11/26/06 14:46 NCI 99-87-6
Methylene chloride DID ug/1 400 11/26/06 14:46 MCE 75-09-2
Methyl -tort -butyl ether ND ug/1 200 11/26/06 14:46 NCK 1634-04-4
Naphthalene 660 ug/1 200 11/26/06 14:46 NCK 91-20-3
a-Propylbeaseue ND ng/1 200 11/26/06 14:46 MCI 103-65-1
Styrene 3D ug/1 200 11/26/06 14:46 NCI 100-42-5
1,1,1,2-Tetrachloroethane ND ug/1 200 11/26/06 14:46 24CE 630-20-6
1,1,2,2-Tetrachloroethane ED ug/1 200 11/26/06 14:46 MCI 79-34-5
Tetrachloroethene ND ug/1 200 11/26/06 14:46 NCE 127-18-4
Toluene 21000 ug/1 200 11/26/05 14:46 MCK 108-88-3
1,2,3-Trichlorobeazeae ND ug/1 200 11/26/06 14:46 NCK 87-61-6
1,2,4-Trlehlorobenzene ND ug/1 200 11/26/06 14:46 MCI 120-82-1
1,1,1-Trichloroethane ND ug/1 200 11/26/06 14:46 ]4CK 71-55-6
1.1,2-Trichloroothano ND ug/1 200 11/26/06 14:46 34CK 79-00-5
Trichloroethene ND ug/1 200 11/26/06 14:45 14CE 79-01-6
Trichiorofluoromethane ND ug/1 200 21/26/06 14:46 210E 75-69-4
1,2,3-Triehioropropane ND ug/1 200 11/25/06 14:46 MCI 96-18-4
I,2,4-Trimethylbenzene 870 ug/1 200 11/26/06 14:46 MCI 95-63-6
•
palm 11/27/04 prior 2 a= 14
psnevil's Cei'rfirati0n 1D6
NC WastCwater . 40
NC Drinkino Water 37712
SC Erwiruom n l 99033
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This rope 0 shag but he reproduced, mere in fug,
without 0e errtnencase„sd of?ace,Analytiral S r s. Ins
1
Qh:Ioha CertINC01100IQ5
NC Wastewater 12
NC Drinking Water 37705
SC 99006
FL NELAP E87527

aceAnalyticar
wwwpa0eiabs_OOra
Pate Analytical Semites. loc.
9800 lance Arenue, Suite 100
Ntrntersville, NC 28078
Phone: [phone]
Far 704.875.9091
Lab Project Number: 92132592
Client Project ID: Walgreeaa BPR
Lab Sample No: 927707653 Project Sample Number: 92132392-001 Date Collected: 11/21/06 11:45
Client Sample ID: PNW-1 1 MONTH
Matrix: Water Date Received: 11/21/06 12:15
Earametera Results Unite Report Limit Analysed By CAS No. _ Dual Kealaat;
1,3,5-Trimethylbenseae 200 ug/1 200 11/25/06 14:46 MCZ 108-67-8
Vinyl chloride ND ug/1 200 11/26/06 14:46 MCI 75-01-4
m&p-Xylene 6309 ug/1 400 11/26/06 14:46 MCI
o-xylene 3300 ug/1 200 11/26/06 14:46 MCI 95-47-6
Toluene-d8 (S) 99 4 11/24/06 14:46 MCI 2037-26-5
4-Bromofluarobermeae (S) 111 t 11/26/06 14:46 Mtlg 460-00-4
Dibronotluoromethene (6) 95 % 11/25/06 14:46 MCI 1858-53-7
1,2-Dichlaroathane-d4 (S) 97 'L 11/26/06 14:46 MCI 17060-07-0
Data: 11/27/DE Papa: 3 of 14
AshD'Ilie Cetlifiation 103
NC Wastwratar 40
NGDrinkinp Water 3TM2
SG Emiwnrnerrtal 93030
FL NEAP E87646
REPORT OF LABORATORY ANALYSIS
Thk col WWI ne16! reproduced. except I tul,
without the written marmot at Pace Nratettml Sent s.ficad
lnc.
plalane Cerlitication 164
NCWaarewater 12
NC Drinking Water 37706
50 99006
FL ?CLAP f87627
i

ce,gralylica►_
www.pooeslabs.com
Pace AmiyUcaf Services, Inc. f
9800KincayAvenue, Strife WO
HuntersviAe, NC 28078
Phone: [phone]
Fax' 704 875.9991
Lab Project Number: 42132592
Client Project ID: Walgreene BFR
PARAMETER FOOTNOTES
Method 9071E modified to use ASE.
All pE, Frea Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside o£ EPA recommended mediate
held time.
Depending on the moisture content the PBLs can be elevated for all Boil samples reported on a dry weight basis.
2-Cbloroethyl vinyl ether has been shown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
(S) Surrogate
Dates 11/27/0b Pager 4 of 14
Asheville Gettificalion 1Dg
NC Wastewaler 40
NC DrirJdng Water 37712
SC Environmental 991130
FL NEIAP E87648
REPORT OF LABORATORY ANALYSIS
This rum shall nprtle reproduce, euerl In full,
wOodtheu menoounttePutArsalyrsarSen7rtt,Inc.
Chartotle Certification IN
NU Wastewater 12
NC Drinking Water 37706
SC 99D06
FL NELAP E87627

aceAnalyticar
we wpaoefabs corn
PaceAastylinl Services, Inc.
9800 Kim ',4 efwe, Suite 10D
Huntersvgle, h1C28078
Pone: 704875,9092
Far 704.875.9091
QUALITY CONTROL DATA
Leh Project Number: 92132592
Client Project ID: Walgreens BPR
QC Batch: 173812
QC Batch Method: EPA 8260
Associated Lab Samples:
927707653
Analysis Method: EPA 8260
Analysis Description: GC/MS VOCs by 8260, low level
METHOD BLANK: 927717934
Associated Lab Samples: 927707653
Blank Reporting
Parameter ti.ita Result Limit___ footnotes
Acetone ug/1 ND 25.
Benzene ug/1 ND 1.0
Bromobenzene ugJ1 ND - 1.0
Brcmochloromothane ug/1 ND 1.0
Bromodichloromethane ug/1 ND 1.0
Bromoform ug/1 ND 1.0
Bromametbane ug/1 ND 1.0
2-8utanone (NEK) ug/1 ND 5.0
n-Butylbenzene ug/1 ND 1.D
sec-Butylbenseae ug/1 ND 1.0
test-Butylbenzene ug/1 ND 1.0
Carbon tetrachloride ug/1 ND 1.0
Chlorobenzene ug/1 ND 1.0
Chloroetha>ae ug/l ND 1.0
Chloroform ug/1 ND 1.0
Chien:methane ug/1 ND 1.0
2-Cblorotoluene ug/1 ND 1.0
4-Chlorotoluene ug/1 ND 1.0
1,2-Dibroo0-3-chloropropane ug/1 ND 1.0
Dibrc ochloramethane ug/1 ND 1.0
1,2-Dibromoethane (EBB) ug/1 ND 1.0
Dibromomethaae ug/L ND L.0
1,2-Dichlorobenzene ug/L ND 1.0
1,3-Dichlorobenzene ug/L ND 1.0
1,4-Dichicrobenzene ug/1 HD 1.0
Dichlorodifluorcoethane ug/1 . ND 1.0
1,1-Dichloroethaae ug/1 ND 1.0
1,2-Dichlosoethane ug/1 ND 1.D
1,1-Dichlcroethens ug/1 ND 1.0
cis-1,2-Dichloroetheae ug/1 ND 1.0
trans-1,2-Dichlaroethene ug/1 ND 1.0
Rate: 11/27/06 Pays: 5 of 14
Asheville Certitieation ip1
NC Wastewater 40
NC Drinking Water 377t2
SC Environmental 9902.0
FL NELAP F87648
REPORT OF LABORATORY ANALYSIS
TN; report s1e2 rot be reproduced. oaz76 in Ne,
Y4th0d the rerifla edrsam of Piz Araty'.iat Service. Inc
Charlotte C@ttDo
NC wastaw>ter 12
&C Drinking Water 37706
SC 99006
FL NUJ? E87627
F

(2eAnIiicr
i i paperabs.cam
PaceAna!ytlCal Services, MC.
9800 KinceyAvehile, Suite 100
Huntersvitte, NC28078
Phone: 704,8759092
Far 704.875 9091
QUTALITY CONTROL DATA
Lab Project Number: 92132592
Client Project ID: walgreens SFR
METHOD BLANK: 927717934
Associated Lab Samples: 927707653
Blank Reporting
EAremetet Dnita Result Uimit Footnotes
1,2-Dichloropropane ug/1 ND I.D
1,3-Diehloropropane ug/1 ND 1.0
2,2-Dichlnropropane ug/1 ND 1.D
1,1-Dichloropropene ug/1 ND 1.D
Diisopropyl ether ug/I ND 1.0
Rthylbenzene ug/1 ND 1.0
Hexachloro-1,3-butadiene ug/1 ND 1.0
Ieopropylbeazene (Cunene) ug/1 ND 1.0
p-IsopropyLtoluene ug/1 ND 1.0
Methylene chloride ug/1 ND 2.0
Methyl -tent -butyl ether ug/1 ND 1.0
Naphthalene ug/1 ND 1.0
n-Propylbenzene ug/1 ND 1.0
Styrene ug/1 ND 1.0
1,1,1,2-Tetrachleroethane ug/1 ND 1.0
I,1,2,2-Tetrachloroethaan ug/1 em 1.D
Tetrachloroethene ug/1 ND 1.0
Toluene ug/1 ND 1.0
1,2,3-Trichlorobenzene ug/1 ND 1.0
1,2,4-Trichlorobenzene ug/1 ND 1.0
1,1,1-Trichloroethane ug/1 ND 1.0
1,1,2-Trichloroethane ug/1 ND 1.0
Trichloroethene ug/1 ND 1.0
Trichlorofluoramethane ug/1 ND 1.0
1,2,3-Trfehloropropane ug/1 ND 1.0
1,2,4-Trimethylbeasene ug/1 ND 1.0
1,3,5-Trimethylbeazene ug/1 ND 1.0
Vinyl chloride ug/1 ND 1.0
map-Eyleno ug/1 ND 2.0
o-xylene ug/1 ND 1.0
Toluene -dB (S) % 99
4-Bromofluorobenzene (S) % 111
Dibromofluoronetbane (S) % 96
1,2-Dicluloroethane-d4 (S) % 94
Eats': 21/27/D6
Ashevil1e Ci;illficati7nJR5
NC Wastewater 40
NC DrinOrw; Water 37712
SC EzM ccunertal 99030
FL NELAP E137648
REPORT OF LABORATORY ANALYSIS
itss report shag not 62 epnduaed, escepl In M.
wi licutthe w fl tamed of Pace AnaMi.1 So Mats. inc.
Chkrytie Certification ID1
NC Wastewater 12
NC ()Orden Water 37705
SC 29003
FL NUM E67E27
Page, 6 of 24

CieA aI car
www.paoeiabs.aorn
Pace Anal 1i a ScrOtas, lnc.
9800 law Avenue, 5ahe ?OD
Hunterav17e, NC28078
Phone: [phone]
Far 704.875.9497
QUALITY CONTROL DATA
Lab Project Number: 92132592
Client Project ID: Wa3greena BFR
LABORATORY CONTROL SANPLB: 927717942
Spike LCS LCS
parameter POite Conc. Result it Rec 12221piatps
Acetone ug/1 100.00 105.4 105
Benzene ug/1 50.00 53.64 107
Bronobenzene ug/1 50.00 49.78 100
Bronochlorometbane ug/1 50.00 52.62 105
BromodichIoramethane ug/1 50.00 54.38 109
Sromoforn ug/1 50.DD 55.32 111
BromoDethane ug/1 50.00 53.52 107
2-Dutanone CMEK) ug/1 100.00 103.4 103
n-Butylbenzene ug/1 50.00 47.59 95
sea-Butylbenzene ug/1 50.00 52.29 105
tert-Butylbenzena ug/1 50.00 51.98 104
Carbon tetrachloride ug/1 50.00 56.00 112
Chlorobeaxene ug/1 50.00 55.56 111
Chloroethane ug/1 50.00 46.74 94
Chloroform ug/1 50.00 52.97 106
Chloransthaae ug/1 50.00 51.08 102
2-Chlorotoluene ug/1 50.00 50.05 100
4-Chlorotolueae ug/1 50.00 50.54 101
1,2-Dibro o-3-chloropropane ng/1 50.00 46.02 92
Dibromochlorcmethane ug/1 5D.00 52.30 105
1,2-Dibromoethate (BOB) ng/1 50.00 58.93 118
Dibremomethaae 115/1 50.00 58.43 117
1,2-Dichlorobensene ug/1 50.00 52.56 105
1,3-Dichlarobenseae ug/1 '50.00 52.88 106
1,4-Dichlorobenrene ug/1 50.00 51.34 103
Dichlorodifluoromethane ug/1 50.00 45.06 90
1,1-Dichloroethaae ug/1 50.00 54.22 108
1,2-Dichloroethene ug/1 50.00 46.99 94
1,1-Dichloroethene ug/1 50.00 50.10 120
cis-1,2-Dichlaroethene ug/1 50.00 55.52 111
trena-1,2-Dichloroethene ug/1 50.00 57.56 115
1,2-Diabloropropene ug/1 50.00 56.32 113
1,3-Dichloropropane ug/1 50.00 54.04 108
2,2-Dichloropropane ug/1 50.00 53.53 107
1,1-Diehloropropene ug/1 50.00 53.57 107
Diiaopropyl ether ug/1 50.00 52.02 104
Ethylbeasenia ug/1 50.00 53.73 107
Date: IV27/Ofi ?saw 7 a if
9shevala Oenn casipn i05
NC Wasiewatar 40
NC 6rinkirg Water 37712
SC Environmental 99030
FLNELAP E87648
REPORT OF LABORATORY ANALYSIS
Pik rap:m shah nd be repraduxd, except in1utl,
wtlhpiR>ha Y115 , wrnent cd Pox Ntsy[ical Selwiuf,
"3
ChaitRhe Certdlratlon IDS
NCWastewater 12
NC Drinldnp Waur 37706
SG 89008
FLNEAP E87627

aceAnalytical
warw.paaelabs.mm
Pace Analytical Services, Inc.
9800lancnyAvenue, Suite 100
Nu77tersville, NC 28078
Phone: [phone]
Fax [phone]
QUUALITY CONTROL DATA
Lab Project Humber: 92132592
Client Project ID: Walgreens SYR
LABORATORY CONTROL SAMPLE: 927717942
Spike LCS LCS
p resister Units Canc. Reenit: L Res Footnotes
Hexachloro-1,3-butadiene ug/1 50.00 54.19 108
Iaopropylbenzene (Cunene) ug/1 50.00 56.95 114
p-Isoprcpyltolueae ug/1 50.00 46.87 98
Methylene chloride ug/1 50.00 45.26 90
Methyl -test -butyl ether ug/1 50.00 51.09 102
Naphthalene ug/1 50.00 49.92 100
n-Propy3bensene ug/1 50.00 51.13 102
Styrene ug/1 50.00 59.73 119
1,1,1,2-Tetrachloroethane ug/1 50.00 60.78 122
1,1,2,2-Tetrachloroathane ug/1 50.00 53.74 107
Tetrachloroetbene ug/1 50.00 57.95 116
Toluene ug/1 50.00 51.20 102
1,2,3-Trichlorobenzene ug/1 50.00 58.64 117
1,2,4-Trichlorobenzene ug/1 50.00 57.67 115
I,1,1-Trichloroethane ug/1 50.00 55.26 111
1,1,2-Triohlaroethane ug/1 50.00 51.99 104
Trichloroethene ug/1 50.00 56.28 113
Triehlorofluoromethane ug/1 50.00 57.07 114
1,2,3-Trichlaropropane ug/1 50.00 54.55 109
1,2,4-Trimethylbenzene ug/1 50.00 47.25 94
1,3,5-Trimethylbenzeae ug/1 50.00 47.39 95
Vinyl chloride ug/1 50.00 50.48 101
nOp-lylene ug/1 100.00 110.0 110
o-Xyieste ug/1 50.00 54.76 110
Toluene -dB (S) 101
4-8rorofluorobenzeno (S) 115 1
Dibrxno£luaramethane (S) 99
1,2-Dichloroathene-d4 (S) 65
MATRIX SPIRE a MATRIX SPIRR DCPLICATE: 927717959 927717967
927704862 Spike MS MSD MS MSD
Parameter Anita Result Cora. Result Result ec %.eg BE Footnotes
Benzene ug/1 0 50.00 48.73 48.38 98 37 1
Chlorobenseae ug/1 0 50.00 53.26 52.95 106 106 1
1,1-Dichloroethene ug/1 0 50.00 46.00 44.60 92 89 3
Dote: 11/27/06
0ss+eviTie Certification IDe
NC Wastewater 40
140 Drinking Water 37712
SC Envimnrncrr1i 99030
R N_LAP E87648
REPORT OF LABORATORY ANALYSIS
Th report sf ll rwt be reproduce. erupt in ful.
xithT.4 ibe ef&n mrset d Pace Anelyt Serims, 0
K yy,
0ariotte Certification IDa
NC Wastewaer 12
NC Drinking Water 37706
SC 99005
FL HELM' 687527
Pap: 8 of 14
F

aecar
wwwpaoaiaDs.com
Pace Analytical Services, Ins.
9800 K1ncey Avenue, Suite 100
HurdersvilIe, NC28078
Phone: [phone]
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92132592
Client Project ID: Walgreens SFR
MATRIX SPIKE S MATRIX SPIKE DUPLICATE: 927717959 927717967
927704882 spike • MS MSD 113 MSD
Parameter Units Result Conc. Result Result % Rec ec RED gooinotea
Toluene ug/1 0 50.00 47.62 46.65 95 93 2
Trichloraethene ug/1 0 50.00 51,45 50.64 103 101 2
Toluene-d8 (S) 98 99
4-Bromofluorobeazene (5) 111 1.10
Dibromoiluoromethaae (5) 97 96
1,2-Dichlosoethune-d4 (5) 94 92
Dater 11/27204 Pager 9 of 14
ASfievilk Certifioatfon }Da
0C W'aSiewoltr 40
NC Drinkin0 Water 3;712
SC Environmental 99030
FL NE1AP E87648
REPORT OF LABORATORY ANALYSIS
Rh report stun rd be reproduced, tarcepl In fun,
without the mine, =sem of Pax Matytizl Service, brc.
Dtarintte_Curtifiuttinn Ifls
NC Wastewater 12
NCDrinkl 9 Water 37705
50 44005
FI NELAP E87627
F

aceArralytica!'
w+w.pdctleeswm fvwwpacelab4com
Pate Analytical Services, Inc.
9800 Klncey Avenue, Stele 100
N(mtersville, NC 28078
Phone.' 704.873.9092
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92132392
Client Project ID: Walgreeas BPR
QC Batch: 173647
QC Batch Method: EPA 7470
Associated Lab Samples:
927707653
Analysis Method: EPA 7470
Analysis Description: Mercury, CV7tAL in Kater
METHOD BLANK: 927711978
Associated Lab Samples: 927707653
Parameter
Mercury
Blank Reporting
Units Result Limit footnotes
vg/1 ND 0.20
LABORATORY CONTROL SAMPLE: 927711585
Spike LCS LCS
Parameter Unite Conc. Result % Rec Pootnotes
Mercury 11g/1 2.500 2.700 108
MATRIX SPIKE a MAT81X SPIKE DUPLICATE: 927711994 927712060
Parameter
Mercury
natal 11/27/e6
927707653 Spike MS MSD 10 M5D
Units Result Conc. Result Result % Rec st Rec REF Footnotes
ug/1 0.03000 2.500 2.740 2.800 108 111 2
Ashnv111n Ckrlificalion 1D4
NC Was1?weter 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP 587648
REPORT OP LABORATORY ANALYSIS Cnaintfe Cartinjllen IDA
Ms wort =4 net 6e rspm7u:BG. exCV, In tul.
NC Waste-v.it r 12
vrsRrat khs wrI5 n GUM nl of Pax Analytical Strikes. Ins. NC Drinking Water 37705
SG 99005
- FL NEL14P E87627
Paget 1a of 14
F

/eAnayticar
Frrsys;t:Dm
Pace Analytical Services, Inc.
9800 KinceyAvenue, SOD 100
Huetersvilla, N028078
Phone: [phone]
Fax 704.875.909 f
QUALITY CONTROL DATA
Lab Project Numbers 92132592
Client Project ID: Walgreeue BFR
QC Hatch: 173654
QC Batch Method: SIC 3030C
Associated Lab Samples:
927707653
Analysis Method: 8PA 200.7
Analysis Description: 3030c Metals, ICI", Trace
METHOD BLANK: 927712190
Associated Lab Samples: 927707653
Blank Reporting
Parameter Units Result Limit Footnotes
Arsenic, 3030C ug/1 ND 5.0
Cadmium, 3030C ug/1 VD 1.0
Chromium, 3030C ug/1 ND 5.0
Capper, 3030C ug/1 BD 5.D
iron, 3030C ng/1 ND 50.
Lead, 3030C ng/1 ND 5.D
Silver, 3030C ug/1 ND 5.D
Sodium, 3030C ug/1 ND 1000
LABORATORY CONTROL SAMPLE: 927712208
Spike LCS LCS
parameter units Conc. Result % Rec Footnotes
Arsenic, 3030C ug/1 500.00 543.0 109
Cadmium, 3030C ug/1 500.00 558.0 112
Chromium, 3030C ug/1 500.00 560.0 112
Copper, 30300 ug/1 500.00 514.0 103
Iron, 3030C ug/1 5000.00 5773 115
Lead, 3030C ug/1 500.00 558.0 112
Silver, 3030C ug/1 250.00 259.0 104
Sodium, 3030C ug/1 5000.00 5209 104
MATRIX SPIKE E MATRIX SPIRE DUPLICATE: 927712216 927712224
927707653 Spike MS MHD MS NSD
Parameter Unite Result Cone. Result Reeulk % Ree %Res up Foataoteo
Arsenic, 3030C u9/1 1.210 500.0D ' 553.0 537.0 110 107 3
cadmium, 3030C ug/1 0.2250 500.0D 559.0 541.0 112 108 3
Chromium, 3030C ug/1 1.020 500.00 564.0 545.0 113 109 3
Date: 11/27/06 Page: 11 of 14
Asheville certifeatipn ID2 REPORT OF LABORATORY ANALYSIS Fnartotte Certlfl a1Ion IDg
NC Wastewater 40 7 ie wart seas nolDe repro4uced 0ixtpt M roe. NC Wastewater 12
NC Dsinta Q Water 37712 vdt eta tna x n ce t at r ece Axo1 ica 5ertiims i NC Drinking Water 37705
SC Emironmentai 99030 �.� 5C 99005
FL NELAP E87648 is°;:; } FL NELAP E87627

Pare Analytical Services, inc.
9800 Klncey Avenue, Stilts 100
lirrntersville, NC 28078
Phone: 704,8759092
Far 704.875.9091
QUALITY CONTROL DATA
LBb. inj9et-8>rmhar; 92132592
leliec6,,sFroject: Sdi Walgreena SFR
MATRIX SPIKE E MATRIX SPIXB DUPLICATE: 927712216 927712224
927707653 Spike MS MSD 5S MSD
"ammeter Mite Result Conc. Result Result 4 Rec IL.Reg RE2 7ootnoten
Capper, 3030C ug/1 1.990 500.00 525.0 510.0 105 102 3
Iron., 303DC ug/1 1104 5000.00 7013 6841 118 115 2
Lead, 303DC ug/1 0.7980 500.00 554.0 538.0 111 107 3
Silver, 3030C ug/1 0.4310 250.00 11.20 10.70 4 4 5 2
Sodium, 3030C ug/1 4260 5000.00 9996 9590 115 107 4
Dntor 11/27/06
Asheville Cerlitinatitrn 1Ds REPORT OF LABORATORY ANALYSIS Ghatlotte Certification 1Ds
NC Weslewater 4 This report chsl not be wisdom!, except intuit, NC Wastewater 12
NC Drinking Water 37712 wdhmethe written rnosere of Paw Anstytiml s, Inc. NC Drink11 Water 37706
SC E v 1cnmtstal 38030 SC 99006
FL HELAP E8MVPA: FL NEAP 57627
Pogo' 12 of 24
F

aCeAnalj,tical l
www.paad8Ds corn
Pace Analyfkal Services, inc. F
9800*rosy Avenue, SuUte 100
Hurtersvltle, NC 28078
Phone: [phone]
Fax: [phone]
QUALITY CONTROL DATA
Lab Project Number: 92132592
Client Project ID: Walgreens BFR
QC Batch: 173801
QC Batch Method; EPA 375.4
Associated Lab Samples;:
927707653
Analysis Method: EPA 375.4
Analysis Description: Sulfate,Turbidimetric
METHOD SLANX: 9277175B7
Associated Lab Samples: 927707653
Parameter
Sulfate
Blank Reporting
Units Result Sinn Footnotes
mg/1 ND 5.0
LABORATORY CONTROL SAMPLE: 927717595
parameter
Sulfate
Spike LCS LCS
Units Conc. Result % Rec Footnotes
mg/1 20.00 18.37 52
MATRIX SPI30: 927717603
parameter
Sulfate
927707653 Spike MS M5
Units Result Come. Result 7r Roc Footnotes
mg/1 0.3288 20.0D 21.28 105
SAMPLE DDPLICATE: 927717611
527679241 L8P
Parameter Units Result Result RPD Footnotes
Sulfate mg/1 . ND Hn NC
Data: 11/27/ME
AShureie Cenifemen fl35
NC.. Wasttw ter 40
NC, Odell* Water 37712
SC Environmerrbl 99330
FL NELAP E87848
REPORT OF LABORATORY ANALYSIS
This :epos see; not tut rep rei um&, accept In MI,
mhos the tun= eonsent of Pate Anallheat Services, Int.
chartMtte Certtrearion 7Os
NC1Nastewaser 12
NC Drinking Water 37T05
SC 95005
FL NELAP 887827
?agar L3 of 1A

/2eAnaIyticar
w w.pacelabs cnm
PaceAnalytkal Stinker, Inc.
9800XGnceyAvenue, Suite 100
Huntersvrfle, NC28078
Phone. [phone]
Fax [phone]
Lab Project Number: 92132592
Client Project ID: Walgreens SFR
QUALITY CONTROL DATA PARAMETER FOOTNOTES
Consistent e th EPA guidelines, unrounded concentrations are displayod and have been used to calculate k 2ec and RPD value..
LCS(D) Laboratory Control Sample (Duplicate)
MS(D) Matrix Spike (Duplicate)
DDT Sample Duplicate
ND Not detected at or above adjusted reporting limit
NC Not Calculable
d Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
MDL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
I1) The surrogate and/or spike recovery was outside acceptance limits.
121 The spike recovery was outside acceptance limits for the KS end /or MSD due to matrix interference. The LCS
and/or LCSD were within acceptance limits showing that the laboratory is in control and the data is
acceptable.
Dais: 11/27/06 Page: 14 of 14
Asn�rorecertii tion IDs
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 9030
FLNELAP E97648
REPORT OF LABORATORY ANALYSIS
Th"S repel steJn rwe b cepredirad. oral%1n tul,
withou1 the =tem cma_nt al Pere An [Oka! Seaters, let
iliebtl
CtarlonE Cerlttirglbbrl FDg
NC x'zsferner 12
NC Drinking Water 37706
SC 99006
FL NEELAP f87627
f

ceAnalytical n
w pacaiabs on
January 08, 2067
Mr. David Wagger
Clayyton Croup Services
297 Highview Drive
Chapel Hill, NC 27517
R£: Lab Project Numbers 92134848
Client Project 7D: walgream, 8satties Ford Road
Dear air. Wagner:
Face Analytical' services, loc.
9800 KitceyAvenue, Suite 100
Huntersvtlte, NC28078
Phone: [phone]
Far 704.875.9091
Enclosed ere the analytical results for samples} received by the laboratory on December 27, 2005. Results
reported herein conform to the most current RELIC standards, where applicable, unless otbarwiao narrated in the
body of the report.
Inorganic Wet chemistry and Metals Analyses were performed at our Paca Asheville laboratory and Organic testing
was performed at our Paco Charlotte laboratory unless otherwise footnoted.
If you have say questions eonceroiag tbia report please Ee4,1 frea to contact ma.
sincerely,
Kevin Herring
kevia.herriag®paceleba.eom
Project Xanager
loc1oanrea
for
Ashevllls Certification 13
NC Wattreater 40
NC brin15ng Water 37712
SC Environmental 99030
R. NELAP 667648
REPORT OF LABORATORY ANALYSIS
Tho repel ,all ire be repot! eeu it tul.
atthaul the armen cement of Pr Ane}yti at Seniors, Inc.
charlotte Certification Ws
NC Wastewater 12
NC Drinking Water 37709
5C 99006
FL N:LAP E07627

Pace Anarytical Services, Inc. f
9800 Kincey Avenue, Suite 100
Hunfersvilk, NC 28078
Phone [phone]
Far 704.875.9091
Lab Project Number: 92134616
Client Project ID: Walgreen, Beatties Ford Road
Lab Sample No: 927635066
Client Sample lb: PMW-1 2 MONTH
Parameters
Metals
3030C Metals, ICP, Trace
Arsenic, 3030C
Cadmium, 3030C
Chromium, 3030C
Copper, 3030C
Iron, 3030C
Lead, 3030C
Silver, 3030C
Sodium, 3030C
Date Digested
Mercury, CVAAS, in Water
Mercury
Wet Chemistry
Sulfate,Turbidisetric
Sulfate
GC/NS Volatiles
PC/MS VOCS by B260, law level
Acetone
Benzene
Bromobenzeone
Bramochloromethane
Bromodich1oromethaae
Br®oform
Bromomethene
2-Butanone (Maa)
a-Butylbenzene
sec-sutylbeazene
tert-Butylbenzena
Carbon tetrachloride
Cblorabenzene
chloroethone
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dates 01/D8/07
Results
Project Sample Number: 92134846-D0I Date Collected: 12/27/06 11:55
Matrix: Water
Date Received: 12/27/06 12:15
Vnita Report Limit Analyzed By CAS No. Dual ReoLmt
Prep/Method: SM 3030C / EPA 200.7
ND ug/1 5.0 12/28/D5
ND ug/1 1.0 12/28/05
ND ug/1 5.0 12/28/D5
ND ug/1 5.0 12/28/05
680 ng/1 50. 12/28/D6
ND ug/1 5.0 12/28/05
ND ug/1 5.D 12/28/05
4000 ug/1 1000 12/28/D6
12/2B/05 00:30 12/28/06
Method: EPA 245.1
ND ug/I
Method: EPA 375.4
ND 03/1
Method: EPA 626D
4400 ug/1
15000
ND
ND
ND
ND
ND
6900
16.
ND
ND
ND
ND
1.6
ND
ND
190
ND
Asecvllle tertifiralion 105
NO Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
71 NEAP E87048
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
ug/1
15:36 ENS
15:35 EWS
15:36 ENS
15:36 ENS
15:36 EMS
15:36 ENS
15:36 EMS
15:36 EW9
08:30
744D-38-2
7440-43-9
744D-47-3
7440-50-8
7439-89-6
7439-92-1
744D-22-4
7440-23-5
0.20 01/05/07 12:31 ALV 7439-97-6
5.0 12/30/D5 12:06 JDA1
1200
1600
1.0
1.0
1.0
1.0
1.0
250
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
12/30/D5
12/30/06
12/30/05
12/30/06
12/30/06
12/30/05
12/30/06
12/30/06
12/30/05
12/30/06
12/30/06
12/30/05
12/30/05
12/30/06
12/30/05
12/30/06
12/30/06
12/30/06
REPORT OF LABORATORY ANALYSIS
tet report stun rut he reproduce. eocro u ful
willoui !M. unitteri eirseet
c(NceMr3yl:alServ¢,s,Inc.
04:35 MCR
04:35 MCK
04:35 MOE
04:35 MCK
04:35 MCK
04:35 MCK
04:35 MCK
04:35 MCK
04:35 MCK
04:35 MCA
04:35 mot
04:35 8C8
04:35 MCK
04:35 MCA
04:35 MCK
04:35 MCK
04:35 MCA
04:35 MCS
67-64-1
71-43-2
108-85-1
74-97-5
75-27-4
75-25-2
74-83-9
79-93-3
104-51-8
135-98-6
98-06-6
56-23-5
108-90-7
75-00-3
67-66-3
74-87-3
95-49-8
106-43-4
5oar1one DertlfbaBon IDS
NC Wastewater 12
NC Main Water 37708
SC 94006
FL NEL P E67627
Pape 1 of 14

aceAnalyticaf
wan, paceiats mm
Pace Analytical Services, lac.
9800 gray Avenue, Suite 100
Huntersvi0B, NC28078
Phone: [phone]
Fax [phone]
Lab Project Number: 92134848
Client Project ID: Walgreen, Seatties Ford Road
Lab Sample No: 927835066 Project sample )cumber: 92134848401 Date Collected: 12/27/06 11:55
Client Sample ID: PNV-1 2 MONTH Matrix: Water Date Received: 12/27/06 12:15
Parameters Results suite Report Limit Analysed Rv CAS lig. Ouel Regret
1,2-Dibreaao-3-chloropropane ND ug/1 1.0 12/30/06 04:35 MCK 96-12-8
Dibromochloromethane ND ug/1 2.0 12/30/06 04:35 MCK 124-48-1
1,2-Dibrostoethane'(sDB) 650 ug/1 50. 12/30/06 04:35 MCI[ 106-93-4
Dibromomethane ND ug/1 1.0 12/30/06 04:35 MCK 74-93-3
1,2-Dfchlorobenzene ND ug/1 1.0' 12/30/06 04:35 MCK 95-50-1
1,3-Diehlorobeazene ND ug/1 1.0 12/30/06 04:35 KM 541-73-1
1,4-Dichlorobenaeae ND ug/1 1.0 12/3D/06 04:35 MCA 106-46-7
Dichlorodifluaromethane ND ug/1 1.D 12/30/06 04:35 MCA 75-71-8
1,1-Dichloroethane ND ug/1 1.0 12/30/D6 04:35 MCA 75-34-3
1,2-Dichloroetbaae 3500 ug/1 50. 12/30/06 04:35 MCA 107-06-2
1,1-Dichloroethene ND ug/1 1.0 12/30/06 04:35 MCA 75-35-4
cis-1,2-Dichloroetheao ND ug/1 1.0 12/3D/06 04:35 MCA 156-59-2
trans-1,2-Dicbloroethene ND ug/1 1.0 12/30/06 04:35 MCA 156-60-5
1,2-Dichloropropane 4.0 ug/L 1.D 12/30/06 04:35 MCK 7B-87-5
1,3-Dichioropropana ND ug/1 1.0 12/30/06 04:35 MCA 142-28-9
2,2-Dichloropropane ND ug/L 1.0 12/30/06 D4:35 MCA 594-20-7
1,I-Dichloropropene ND ug/1 1.0 12/30/06 04:35 MCK 563-58-6
Diieopropyl ether B10 ug/L 50. 12/30/05 D4:35 MCA 108-20-3
Sthylbenzeae 3200 ug/1 50. 12/30/06 04:35 MCK 100-41-4
Herachloro-1,3-butadione ND ug/1 1.D 12/30/06 04:35 MCK 87-6B-3
Isopropylbemzene (Cunene) 130 ug/1 1.0 12/3D/06 D4:35 MCA 98-82-8
p-Icopropyltoluene ND ug/1 1.0 12/30/06 04:35 MCA 99-87-6
Methylene chloride ND ug/1 2.D 12/30/06 04:35 MCA 75-09-2
Methyl -test -butyl ether 77. ug/1 1.D 12/30/06 04:35 MCA 1634-04-4
Naphthalene 280 ug/1 50. 12/3D/06 04:35 MCA 91-20-3
n-Propylbenzene 170 ug/1 1.0 12/30/06 04:35 MCA 103-65-1
Styrene ND . ug/1 1.0 12/30/06 04:35 MCI 100-42-5
1,1,1,2-Totrachloroethene ND ug/1 1.0 12/30/06 04:35 MCI 630-20-6
1,1,2,2-Tetrachloroethene ND ug/1 1.0 12/30/06 04:35 MCI 79-34-5
Tetraehloroethene ND ug/1 1.0 12/30/06 04:35 MCI 127-18-4
Toluene 24800 ug/1 1000 12/50/06 04235 MCA 108-88-3
1,2,3-Trichlorobearene ND ug/1 1.0 12/30/06 04:35 MCI 87-61-6
1,2,4-Trichlorobeazene up ug/1 1.D 12/30/06 04:35 MCA 120-82-1
1,1,1-Trichloroethane ND ug/1 1.0 12/30/06 04:35 MCA 71-55-6
1,1,2-Trichloroethane ND ug/1 1.0 12/30/06 04:35 MCA 79-00-5
Trichloroethane ND ug/1 1.0 12/30/06 04:35 MCK 79-01-6
Trichlorofluoroethane ND ug/1 1.0 12/30/06 04:35 MCI 75-69-4
1,2,3-Trichloropropane ND ug/1 1.0 12/30/06 04:35 MCA 96-18-4
1,2,4-Trimetbylbeazene 1500 ug/1 5D. 12/30/05 04:35•MCI 95-63-6
a:a: D1/Da/07 Page: 2 et 14
Ashede CeRifir lion IDS
NC Wastewater 40
90C Drinking Water 37712
SC EevironRlental 89030
R NELAP E87648
REPORT OF LABORATORY ANALYSIS
This repot [ha runt he reproduced. carted in full.
withoi/ the mro•n ma„rt ofPate AIeM �l Serums, Inn.
`,1JG
s fat
charlotte Geritiiostinn]45
N6 Wastewater 12
NC Drinking Water 37705
SC 99006
Ft. NELAP E87627
f

aceAnalytical'
.patelaba. n
Pace Analytical Services, rnc. f
9800 Krncey Avenue, Suite 100
Hunfersvilfe, NC 28078
Phone: [phone]
Far. 704.875.9091
Lab Project Number: 92134846
Client Project ID: Walgreen, Beattien Pord Road
Lab Sample No: 927835066
Client Sample ID: PMW-1 2 MONTH
Project Sample Number: 92134848-001 Data Collected: 12/27/05 11:55
Matrix: Water Date Received: 12/27/06 12:15
Parameters Reaulte Anita Report Limit Analyzed By CAS No. Qual lteeLirj
1,3,5-Trimethylbencene 32D 1g/1 50. 12/30/06 04:35 KCK 108-67-8
Vinyl chloride ND ug/1 1.D 12/30/06 04:35 NCR 75-01-4
m&p-Aylene 11000 ug/1 100 12/3D/06 04:35 MCK
o-xylene 540D ug/l 50. 12/30/06 04:35 MCK 95-47-5
Toluene-d8 (S) 62 % 12/3D/06 D4:35 MCK 2037-26-5
4-9romofluoroben:ene (9) 108 % 12/30/06 D4:35 MCK 460-0D-4
Dibromofluoromethane (S) 77 6 12/30/06 04:35 MCK 1868-53-7 1
1.2-Dicbloroethane-d4 (5) 90 % 12/30/D6 D4:35 MCK 1706D-07-0
Data: e1/DB/o7 Page 3 of 14
Ashevif:0ertili abon 1.131
NC Wastewater 40
NC Orielen2 War 37712
SC EnvIromental 99330
FLNELAP E87648
REPORT OF LABORATORY ANALYSIS
!vs report snail not be i prodvae4. except in fuB.
without the mitten moral of pace Aralytcal Services. tnc.
�.lF4
Charlotte GennicationtRa
NCWestevater 12
NC Rrinkinp Water 37706
SC 99006
FL PE -LAP F87627

/eAnaIyticar
ttnvimpaoaia&Lown
Pace Araly&iI Services, lac.
98001<nceyAvenue, Suite 100
Nurrte+svife, NG 28078
Phone: [phone]
Far 701.875.9091
Lab Project Number: 9213484E
Client Project ID: Walgreon, 8eatties Ford Road
PARAMETER FOOTNOTES
Method 9D713. modified to use A58.
All pH, Freo Chlorine, Total Chlorine and Ferrous Iron analyses conducted outside of EPA recommended immediate
hold time.
Depending on the moisture content the PELe can be elevated for all soil samples reported on a dry weight basis.
2-Cbloroethyl vinyl ether hae been ehown to degrade in the presence of acid.
ND Not detected at or above adjusted reporting limit
NC Not Calculable
J Estimated concentration above tbo adjusted method detection limit and below the adjusted reporting limit
NDL Adjusted Method Detection Limit
(S) Surrogate
[1] Low surrogate recovery was confirmed an a matrix effect by a second analysis.
Date: 01/48/D7 Page: 4 of 14
Ashevf? Certiticatien IDs
NCWaslewalai 40
NC Drinking Water 37712
SC Emrimnmental 02030
FL NELAP E87&49
REPORT OF LABORATORY ANALYSIS
The; repot slave not be repmduped, meet Intel
without the writhe consent of Par_ AneMi 1 Santee, Inc.
Cna!tot+r Cerratien ll�
NC Wastewater 12
NC Drinlliap Water 37705
SC 99006
R NELAP E87627
f

/eAna1yticar
:v►►7nparxlsbs.oam
Pate Analyiksr Services, Inc.
9800KnceyAvenue, Suite 100
Huntersviiie, NC 28078
Phone; 704.875.9092
Fax [phone]
QUALITY CONTROL DATA
Lab Project Ntmber: 92124848
Client Project ID: Walgreen, Beattiee Ford Road
QC Batch: 176798
QC Hatch Method: BPA 8260
Associated Lab Samples:
927835066
Analysis Method: BPA 8260
Analysis Description: 6C/NS V Ca by 8260, low level
METHOD BLANK: 927845172
Associated Lab Samples: 927835066
Blank Reporting
Parameter Units Reeult Limit pootnotes
Benzene ug/1 ND 1.0
Bramobenzene ug/1 ND 1.0
Brecochlnromathaae ug/1 ND 1.0
Bramodichloromathaae ug/1 ND 1.0
Bromoform ug/1 ND 1.0
Bromometbane ug/1 ND 1.0
a-Butylbenzene ug/1 ND 1.0
Cec=Butylbensene ug/1 ND 1.0
tert-Butylbenzene ug/1 ND 1.0
Carbon tetrachloride ug/1 ND 1.0
Chlorobenzene ug/1 ND 1.0
Chloroethaae ug/1 ND 1.0
Chloroform ng/1 ND 1.0
Chloromethane ug/1 ND 1.0
2-Chlorotoluene ug/1 ND 1.0
4-Chlorotolueao og/1 ND 1.0
1,2-Dibramo-3-cbloropropene ug/1 la 1.0
Dibromochloronetbane ug/1 ND 1.0
1.2-Dibromoethane (RDB) ug/1 ND 1.0
Dibr®ometbaua ug/1 ND 1.0
1,2-Dichlorobenzene ug/1 ND 1.0
1,3-Dicblorobenzeae ug/1 ND 1.0
1,4-Dichlorobenzene ug/1 ND 1.0
Dichlorodifluoromethane ug/1 ND 1.0
1,1-Dichloroethane .ug/1 ND 1.0
1,2-Dichloroethene ug/1 ND 1.0
1,1-Dichloroethene ug/1 ND 1.0
cis-1,2-Dichlaroethene ug/1 ND 1.0
trans-1,2-Dicbloroethene ug/1 DID 1.0
1,2-Dich1oropropane ug/1 •.7) 1.0
1,3-Dichloropropane ug/1 ND 1.0
Dater 01/oe/07 Page: 5 a! 14
Ashev0[a Certlicaion tog
NC Wastewater 40
NC Drinkap Water 37712
SC Emitonmental 99030
FL NELAP E87648
REPORT OF LABORATORY Af1ALYSJS
This mod shall not be reproduced, except in Id,
vtdwut the a rl0e.i wasentt oft Amlyttai Srn1 e . tie.
. llltidl.t
Ghadotte Certification las
NC Wastewater 12
NC Drinking Water 37706
SC 90306
FL NELAP c67527

aceAnalyticar
►nve:pacelaCSADttt
Pace Analytical Swaim, Inc.
9800KInceyAvenue, Suite 10D
Nuntersville, NC 28078
Pima 784.875.9092
Far 704.8759091
QUALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: Walgreeu, 8eattiea Ford Road
=MOP 9LANX: 927845172
Associated Leh Samples: 9271135006
8Iank Reporting
Parameter Units Result Limit Footnotes
2,2-Dichlaroprapane ug/1 ND 1.0
1,1-Dichloropropeue ug/1 ND 1.0
Diieopropyl ether ug/1 17D 1.0
Ethylbenzene mg/1 ND 1.0
8exachloro-1,3-butadiene ug/1 ND 1.0
Isopropylbenzene (Cumene) ug/1 ND 1.0
p-Iaopropyltoluese mg/1 ND 1.0
Methylene chloride ug/1 ND 2.0
Methyl-tert-butyl ether ug/1 ND 1.0
Naphthalene 117/1 HD 1.0
n-Propylbenzene ug/1 ND 1.0
Styrene mg/1 ND 1.0
1,1,1,2-Tetrachloroethaae ug/1 ND 1.0
1.I,2.2-Tetrachloroethane ug/1 ND 1.0
Tetrachloroethene ug/1 ND 1.0
Toluene ug/1 HD 1.0
1,2,3-Trichlorobeazene ug/l ND 1.0
1,2,4-Trichlorobenzene ug/1 ND 1.0
1,1,1-Trichloraethene mg/1 DID 1.0
1,1,2-Trichloroethene mg/1 ND 1.0
Triohlcroetbene ug/1 ND 1.0
Trichlorofluoroeethane ug/1 ND 1.0
1,2,3-Trichloropropa>ae ug/1 ND 1.0
1,2,4-Trimethylbenzene ug/1 DID 1.0
1,3,5-Trimethylbenzene ug/1 HD 1.0
Vinyl chloride mg/1 DID 1.0
m&p-Xylene mg/1 ND 2.0
o-xylene mg/1 ND 1.0
Toluene -Mt (S) % 100
4-eramotluorobenrene (S) % 108
Dibranofluarcmethane (3) % 94
1,2-Dichloroethane-d4 (S) % 86
Dater 01/08/e7 Page: 6 of 14
AshmriNCarrifmMionM11 REPORT OF LABORATORY ANALYSIS Dnarlotte CeitlGtxtioniDB
NE (NasNmratet CG This report suit not be reprpaced. e�ept hilt
NC Wastewater t2
N0 Drinking Water 37712 %emu! the rslMei rareoot of Pace Analykal Services, Inc. NC Drinkilp Water 37706
SC Environmental 99030 SC 99006
FL NELAP EB7548 " FL NELAP 87627
inciam

2eAIk?Iytica
A Av.pac„abs.mm
Pace Anti, Oral Services, Inc.
9800 KtnceyAvenue, 5u8e 100
Nuntersvlfle, NC 28078
Mane: 704.875.9092
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: walgreen, Boattieo Ford Road
LABORATORY CONTROL SAMPLE: 927845180
Spike LCS LCS
Paramexer Unite Conc. Result % Rea Footnotes
Acetone ug/1 100.00 109.3 109
Benzene ug/1 50.00 56.43 113
Bromobearene ug/1 50.00 51.54 103
Bromochloromethane ug/1 50.0D 47.98 96
sromodiahloromethane ug/1 50.00 55.71 111
Bremoform ug/1 50.0D 58.D0 116
Bromon there ug/1 50.00 57.02 114
2-Butanone (MER) ug/1 100.00 104.3 104
a-Butylbenzene ug/1 50.00 49.72 99
sec-Butylbenzene ug/1 50.00 55.58 111
tert-Butylbenzene ug/1 50.00 5D.98 102
Carbon tetrachloride ug/1 50.00 57.34 115
Chlorobenzene mg/1 50.00 55.76 112
Chloroetheae mg/1 50.0D 51.03 ID2
Chloroform mg/1 50.00 52.80 106
Chlaromethane ng/1 - 50.00 44.05 88
2-Chlorotoluene mg/1 50.00 51.77 104
4-Chlorotoluene ug/1 50.00 52.25 104
1,2-Dibromo-3-chloropropane ug/1 50.0D 51.60 103
mibronochloromethane ug/1 50.00 53.73 107
1,2-Dibronoethane (EDS) ug/1 50.00 53.01 106
3ibranomethana ug/1 50.00 60.75 121
1,2-Dichlorobeszsae ug/1 50.00 52.37 105
1,3-Dichlorobenzene ug/1 50.00 53.76 108
1,4-Dichlorobenzeoe ug/1 50.00 53.53 107
bichlorodifluoromethsae vg/1 50.00 37.30 75
1,1-Dichloroethane ug/1 50.00 54.47 109
1,2-Dichloroetheno ug/1 50.00 51.16 102
1,1-Dichlaroatheme ug/1 50.00 59.42 119
cie-1,2-Dichloroathana ug/1 50.00 55.69 111
trans-1,2-Dichloroethene ug/1 50.00 56.72 113
1,2-Dichloropropana ug/1 50.00 57.72 115
1,3-Dichlaropro3ama ug/1 50.00 53.93 108
2,2-Dichlorapropana ug/1 50.00 47.16 94
1,1-Dichloropropene ug/1 50.00 54.65 109
Diisopropyl ether ug/1 50.00 52.65 105
Ethylbenzene ug/1 50.00 55.72 111
Distal O1/013/07 Raga: 7 of 14
Asheville Cerliftation 104
NC Wastewater 40
NC Drinking Water 37712
5C Environmental 99030
FL NELAP 887648
REPORT OF LABORATORY ANALYSIS
This moll shalt ref be rep+eduxl, erupt o1 fist,
veil/Kate airi n ur6en: d Pax MaAyli:ai Scrviots, Inc.
0hariotfie Cerlilitoi1on514
NCWasteuoter 12
Nf DriddI10 Water 37706
SC 99000
FL NEW E67627
f

eAnalytical'
wwu:pacatabscom
PaceknaljtC8l &Men Inc. - F
9800gamy Avenue, Suite 100
Huntersvi ie. NC28078
Phone. [phone]
Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Humber: 9213484E
Client Project ID: Walgreen, Beatties Fnrd Road
LABORATORY CONTROL SAKPLE1 927845180
Spike LCS LCS
Parameter 'Units Cone. Result % Rec Footnotes
Sesachloro-1,3-butadiene ng/1 50.00 56.08 132
Isopropylbemzene (c ene) ug/1 50.00 57.74 115
p-[sopropyltoluene vg/1 50.00 50.96 102
Methylene chloride ug/1 50.00 50.94 102
Mathyl-tert-butyl ether ug/1 50.00 49.42 99
Naphthalene ug/1 50.00 47.56 95
n-Propylbensene ug/1 50.00 54.46 209
Styrene ug/1 50.00 59.07 116
1,1,1,2-Tetrachlaroethane ug/1 50,00 55.47 111
1,1,2,2-Tetraehloroethaue ug/1 50.00 49.68 99
Tetrachlotoethene ng/1 50.00 58.59 117
Toluene ug/1 50.00 55.53 111
1,2,3-Trichlorobenzeae ug/1 50.00 56.37 114
1,2,4-Trichlorobeezene ug/1 50.00 56.94 114
1,1,1-Trichloroethane ug/1 50.00 54.68 106
1,14-Trichloroethaae u9/1 -50:00 -52:70 105
Trichloroethene ug/1 50.00 61.40 Z23
Trichlorofluoromethane ug/1 50.00 53.14 106
1,2,3-Trichloropropane ug/1 50.00 53.64 107
1,2,4-TrimethYlboAsuse ug/1 50.00 48.09 96
1,3,5-Trimethylbeazsene ug/1 50.00 48.09 56
Vinyl chloride ug/1 50.00 50.114 102
ms,p-Eylene ug/1 100.00 115. D 115
o-Xylene ug/1 50.00 55.27 111
Toluene-d8 (33 99
4-8ramofluorobeamene (9) 107
Dibroutofluoromethane (8) 93
1,2-Dichloroethane-d4 (5) 95
MATRIX SPIKE & MRTRIE SPIRE Di7FLSCATET 927847418 927847426
927831205 Spike MS PSSD MS 3651)
Parameter Units Result Coal,Result Result iii Rec 1SaQC. 7PD gootnotee
8enzeAe u9/1 5.257 50.00 48.28 50.56 86 91 5
Chlorobenzens ug/1 0 50.00 47.33 51.43 95 103 8
1,1-Dichloroethene u9/1 0 50.00 61.96 53.50 124 127 2
Dater 01/06/07 Page.:a of 14
Ashevl8e Ceniscatian ins
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87845
REPORT OF LABORATORY ANALYSES
report stun not be reproduced, incept in full,
Ivithout the written cement of Pact Aralytiwl Servius, be.
r•,
flItSaa
Charlotte Certification IDs
NC Wastewater 12
NC Drinking Water 37706
SD 99006
FL NElAP E87827

Pare litudyfical Services, its.
9800 Kincey Avenue, Suite 100
Nuntersvitle, NO 28078
Phone: [phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: Walgreen, Beatties Ford Road
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 927847418 927847426
927831305 Spike • MS MSD MS MSD
Parameter Uni,xy Ewalt Conc. Result Result % h_geg. EER poatnotes
Toluene ug/1 12.27 50.00 44.05 47.13 64 70 7
- Tricbloroethens vg/1 0 50.00 47.28 49.94 95 100 5
Toluene-d8 (S) 9B 97
4-9rozofluorobeasene (S) 102 102
Dibronofluoromethane (3) 107 103
1,2-Diehloroethane-d4 (S) 99 95 1,2,2,3
Dater 43/04/D7 Paget 9 of 14
Asheville Certification 114
ND Westeaater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP 887649
REPORT OF LABORATORY ANALYSIS
itt moan chat nor be reproduced, emegt kt lul.
without the written consent ofe Pe k:Wm, Scv¢xs. Inc
Pflerat
Chart ten rxrtlfieatinn Ir e
NCWaslevret r 12
. NC Drinkirg Water 37706
SO 99006
FL NELAP E87627

aceAnalytical
w+vw:paa�abscrorn
Pace Analytical Sanity:, inc
9800 lencey Avenue, Suite 100
Hantersvrlle, 111C2807B
Phone:[phone]
Fax [phone]
QUALITY CONTROL DATA
Lab Project Eturber: 92134848
Client Project ID: Walgreen, 3eatties Ford Road
QC Batch: 177153
QC Batch Method: EPA 245.1
Associated Lab samples:
527835066
Analyaie Method: SPA 245.1
Analysis' Description: Mercury, CVAAS, in Water
METHOD BLANK: 927860916
Associated Lab samples: 927835066
Parameter
Mercury
Blank Reporting
Units Result Limit Footnotes
ug/1 AID 0.20
LABORATORY CONTROL SAMPLE: 927860924
Parameter
Mercury
Spike LCS LCS
Unita Conc. Result ILIgS Footnotes
ug/1 2.50D 2.370 95
MATRIX SPIKE: 927860932
7arametor
Mercury
977835066 Spike NS MS
Unite Result Conc. Result % Agg Footnotes
ug/1 0.0500D 2.50D 1.90D 70
SAMPLE DUPLICATE: 927860940
Parameter
Mercury
927859041 DUFF
Units Result Result RFD Footnotes
ug/1 ND ND NC
Data: 01/116/07 l'a•ge: 10 of 14
Asheviflo Certification iPs
NC Wastewater 4D
NC Drirkin0 Water 37712
SC Environmental 99630
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
ilia magi earl nd 6e reproduced, Email!) fufl,
witaut tin mitten wr>scat of Pact kalyfiral SeMata, Inc.
JLEN
Charlotte Certilicalion 105
NC Wastewater 12
NG Drinking Water 37705
SC 39005
R.SIELAP E87627

Pare AnafyVcal Semres, lne.
98001Gnri'yAvenue, Suite 100
4 c /�,,, lyt , /� Huntersville, NC28078
s►t,/`illCil�7�/ f Phane:704.875.9092
www.paoelsbs.cam Far 704.875.9091
QUALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: Nalgreen, Beatties Ford Road
QC Batch: 176559
QC Batch Method: SM 3030C
Associated Lab Samples:
927635066
Analysis Method: EPA 200.7
Analysis Description: 3030C Metals, ICP, Trace
1 Er'aOD BLANK: 927837294
Associated Lab Samples: 927835066
Blank Reporting
Parameter unite Result Limit Footnotes
Arsenic, 3030C ug/1 ND 5.0
Cadmium, 3030C ug/1 ND 1.0
Chromium, 3030C ug/1 ND 5.0
Copper, 3030C ug/1 ND 5.0
Iran, 3030C ug/1 ND 50.
Lead, 3030C ug/1 ND 5.D
Silver, 3030C ug/1 an 5.0
Sodium, 3036C ug/1 ND 1000
LABORATORY CONTROL SAMPLE: 927837302
Spike LCS LCS
Parameter units Gone Result ec 7ootaotes
Arsenic, 3030C ug/1 500.00 508.0 102
Cadmium, 3030C ug/1 500.00 522.0 102
Chromium, 3030C ug/1 500.00 481.0 96
Copper, 3030C ug/1 500.00 474.0 95
Iron, 3030C ug/1 5000.00 5346 107
Lead, 303DC ug/1 500.00 500.D 100
Silver, 3030C ug/1 250.00 264.0 106
Sodium, 3D30C ug/1 5000.00 5439 109
MATRIX SPTAB: 927837310
927835066 Spike MS MS
Parameter Units Result onc. Result % Rea Footnotes
Arsen4c, 3030C ug/1 0.2350 500.00 512.0 102
Cadmium, 3030C ug/1 0.3020 500.00 504.0 101
Chromium, 3030C ug/1 0.7890 500.00 480.0 96
Data: 01/08/D7
Asheville Cuttfication VDT
NC Wastewater 40
NC 0rinldnp Water 37712
SO Envlmnarental 93030
fifiELAP E87648
REPORT OF LABORATORY ANALYSIS
Thu report shall n9: be reproduced. eapltn full.
Witted the mrde.i consent of Pace Analytical 5eTim Inc,
Charlotte Certification IDL
NO Wastewater 12
NC Drinking Water 37706
SC 99008
FL PEA? E87627
Yap. 11 al 14
f

eceAna!yticaf
w,srw.pacexabs.com
Pace Anolyfl ait Services, Inc.
9800 Kincey Avenue. Suite 10U
Hunlersville, NC28078
Phone: [phone]
fax [phone]
QUALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: Welgreen, Beattie Ford Road
MATRIX SPIKE: 927837310
927835066 Spike !CS 14S
parameter Qaite Result Conc. R!Bult__ % Rec poostnetee
Copper, 3030C ug/1 3.130 500.00 480.0 95
Iron, 3030C ug/1 660.0 5000.00 5689 100
Lead, 3030C ug/1 0.8550 500.00 490.0 96
Silver, 3030C ug/1 0.4480 250.00 199.0 79
Sodium, 3030C ug/1 3969 5000.00 9786 116
SAMPLE DUPLICATE: 927831328
927836734 DDT,
parameter Units Result Result RPD Pootnotto
-Arsenic, 30300 ug/1 ND ND NC
Cadmium, 3030C ug/1 1.300 1.40D 7
Chromium, 3030C ug/1 92.00 94.00 2
Copper, 3030C ug/1 6.000 6.200 3
Iron, 3030C ug/1 12000 11000 2
Lead, 3030C ug/1 ND 5.400 0
Silver, 303DC ug/l ND ND NC
Sodium, 303DC ug/1 28000 28000 3
Bata: D1/02/27 ?agog 12 0! 14
4sirevl11eCerlifcation 0?5
NC Wastewater 40
NGDrinking Water 37712
5C Environmental 99030
FLNELAP E0764B
IEPORT OF LABORATORY AP ALYSIS
This report sha nd be reproduced. except in 1u4
witleul the written cornet of Pace Analytical Services. Inc.
Charlotte Certification ID1
NCWaslewater 12
NC Drinking Water 3T708
SC 89008
FL NELAP E87627
f

aceAnalyticar
www.pacelabs.com
Face Analytfcal Sewises. Inc. 1
9600 Kincey Avenue, Suite WO
Huntersville, NC 28073
Fhnne: 704.875 9092
' Fax: [phone]
QTALITY CONTROL DATA
Lab Project Number: 92134848
Client Project ID: Walgzeen, Beatties Pord Road
QC Batch: 176830
QC Batch Method: EPA 375.4
Associated Lab Samples: 927835066
Analysis Method: EPA 375.4
Analysis Description: Sulfete,Turbidimetrie
METHOD BLAN&: 927B47004
Associated Lab Samples: 927835056
Zarameter baits
Blank Reporting
Result Limit Footnotes
Sulfate mg/1
ND 5.0
LABORATORY CONTROL SAMPLE: 927847012
Parameter Anita
Spike LCS LCS
Cone_ Result % Rec Foo otas
Sulfate mS/1
20.00 20.12 101
MATRIX SPIRE: 927647020
Parameter Units
927819763 Spike MS 31S
Result Conc. Result % Rec Footnotes
Sulfate mg/1
11.78 20.00 30.80 95
SAMPLE DUPLICATE: 927647038
Parameter Units
927819771 DUP
Result Result 7PD Footnotes
Page_ 13 of 14
Sulfate mg/1
Data: el/Ds/07
bshev1te C r1RFcation IDg
NC Wastewater 40
NC Drinking Water 37712
SC Environmental 0903D
FL NEL/iP E87648
ND ND NC
REPORT OF LABORATORY AJi AIYSIS Chd1C11e CertiFrcatio-a 1D5
rrd, men shag not be reproduced, extept hi 1u1, NC Wastewater 12
without the written consent of Face Amlgteal Services, Inc, NC DrInking Water 377D6
SC 99066
r i wr FL IJELAP EB7627

Paco Mslytkal Services. las.
9800 kincey Avenue, Suite 100
Monterey" lle; NC28078
Phone_ 704.875 9092
Fax [phone]
Lab Project Number: 92134848
Client Project ID: Walgreea, Scotties Ford Road
QUALITY CONTROL DATA PARA3 TER FOOTNOTES
Consistent with EPA guidelines. uarounded concentrations are displayed and have been used to calculate % Rec and RPD values.
LCS(D) Laboratory Control Sample (Duplicate)
NS(D) Matrix Spike (Duplicate)
BOP Sample Duplicate
ND Not detected et or above adjusted reporting limit
NC Not Calculable
d Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit
LWL Adjusted Method Detection Limit
RPD Relative Percent Difference
(S) Surrogate
[1] Reported MSJMSD injected outside of method recommended tune time.
[2] Insufficient sample availahle for re -analysis.
[31 trS/]dSDwas injected outside of method recommended tune time.
Data! e1/eS/47 Paw 14 of 14
Asheville CertifiCalipo ID5
NCWastewater 40
NC Drinking Water 37712
SC Environmental 99030
FL NELAP E87648
REPORT OF LABORATORY ANALYSIS
This regal snarl not he remittal, ®teeth run,
without the irate sunent of Pas AneMi al Services, Inc.
,,1s
Marina Cemncailon log
NC Wastewater 12
NC Drinking Water 37705
SC ' 99905
R 4UELAP E57627

CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody Is a LEGAL DOCUMENT. All relevant fields must ba completed accurately.
/ aceHnaryacar
Page: of J
(Section A Section B Section C
Roadbed Meat lefarmafIon: Required Project Information: Invoice Information:
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/Section A
Requited Client Information:
Section 13
Remold Project Infonnellan:
CHAIN-OF-CUSTODY/AnalyticalRequestDocument
The Cheln-nt-Custody is a LEGAL DOCUMENT. All relevant Nelda must be completed accurately.
Section C
Irivoteo Into /nation;
Page: of /
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Section B
Requited Project Information:
Repo
CHAlW0E-CUSTODYI Analytical Request Document
The Chaltot-Custody is a LEGAL DOCUMENT. All relevant fields must be completed acc
•
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Inver* Intel/Wien:
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Address:
!r.47J nu 3/G, (
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CHAIN -OF -CUSTODY 1 Analytical Request Document
The ChaIn-of-Custody Is a LEGAL DOCUMENT: Alt relevant fields must be completed accurately.
> r a vnrrdryttuat
•
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Required ClcantlAfOresatloc Required ProJadt InfatmaElen; Invoice Information:
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Section A
Required Client Information;
Comps
Add
Section B
Required Project Intonation:
!Zopo.
•dt. /4 at /-✓
Copy To:
-?•i
CHAIN -OF -CUSTODY ! Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
T '
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•
Section C •
vai+
Iace lnlormaliaa: " • r
Company Naim:
Address:
Emar,a,
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Purchase Order No.:
pa t m �� . Pr ✓ i r dra-rit,
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BPIIISOLUT SL
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DEERavurtse olDe Fon maw -norm
Pace Quote Reference.
Pace PrajnntWiesen
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COLLECTED
❑ NPDES
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REGULATORY AGENCY
Para Pre1B t Number
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SAMPLER NAME AND SIGNATURE
PRINT Nveyi SAMPLER:
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Michael F. Easley., Governor
vi11i rm G. Ross Jr, Secretary
North Carolina .Department of Environment and Natural Resources
Alan W. Klirn P.E, Director
Division of Water Quality
September 11, 2006
Mr. Scott. Bort
Sunset Southstar
200 Providence Road, Suite 106
Charlotte, NC 28207
Subject: Injection Well Permit Application
Site of Proposed Walgreen Store #10275 ® LUST Incident # 8789
5040 Beatties Ford Road, Charlotte
Mecklenburg County, North Carolina
Permit Number: W10300111
Dear Mr. Bort:
We have reviewed your Injection Well Permit Application for the subject site, and
determined that additional information is needed before we can finish our review. Please provide
additional information listed below:
1) The proposed monitoring plan is not sufficient. The proposed injection fluid has the
potential to react with the underground utility and/or soil and release metals to the
groundwater. The purpose of the groundwater monitoring is not only to evaluate the
effectiveness of the proposed remediation plan, but also to monitor potential impact on the
groundwater quality. Traditionally, for sites where strong oxidants are injected, we require
the following parameters be analyzed: Field parameters: pH, temperature, conductivity,
oxidation-reduction potential (ORP), dissolved oxygen; Laboratory analyses: Metals 3030C
(As, Cd, Cr, Fe, Hg, Na, Pb, Cu, and Ag), sulfate, VOCs by EPA Methods 6260. Sampling
frequency: baseline sampling before injection, one month after injection, quarterly sampling
thereafter until the sampling results show that the reactions are complete and geochemical
conditions return to the pre -injection state. Please provide a modified monitoring plan.
2) Provide an updated water supply well survey report. For the pilot injection test, a five
hundred (500) feet radius water supply well survey should be conducted and results
submitted to us. For the full-scale injection, a water supply well survey within one thousand.
five hundred (1,500) feet radius should be conducted.
Aquifer Protection Section
Internet: httpa'th2o.enr.state.nc.0
1636 Mail Service Center Raleigh; NC 2°7Ci99-1636
2728 Capital Boulevard Raleigh, NC 27604
Phone (919)
Fax (919)
Fax (919) 7
Customer Service
I-877-623-6748
An. Equal Opportunity/Affirmative Action Employer 50% Recyded110% P©sl Consumer Paper

W10300111
Page 2 of 2
09/ 11 /2006
eAppreciate your' 'fort and cooperation on this project. Please do not hesitate to call me if
�quet%vns.at tis letter.
Sincerely,.
Qu Qi, PG
UK Program Manager
cc: Mooresville Regional Office
David Wagner — Clayton, 297 Highview Dr., Chapel Hill, NC 27517
Peiinit Application File W10300111

DIVISION OF WATER QUALITY
AQUIFER PROTECTION SECTION
October 11 „ 2006
MEMORANDUM
TO: Andrew Pittner
Mooresville Regional Office
FROM: Peter Pozzo, Underground. Injection Control Program
RE: Issuance of injection well permit #WI030011 1
Permit number has been issued to Sunset Southstar, LLC c/o Tribec Properties for the injection of
sodium persulfate for petroleum hydrocarbon oxidation at the Proposed Walgreen Store #10275 at
5040 Beatties Ford Road in. Charlotte, NC. A copy of this permit is enclosed for your files. The
VIC Program appreciates your staff's assistance with the review of this permit. If you have any
questions regarding this permit or the MC Program, please call me at (919) 715-61.64.
cc: l_JIC--CO files
Enclosures

Michael F. Easley, Governor
William G. Ross Jr., Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E. Director
Division of Water Quality
October 11, 2006
Mr. Scott Bortz
Sunset Southstar, LLC c/o Tribek Properties
200 Providence Road
Suite 106
Charlotte, NC 28207
RE: Issuance of Injection Well Permit WI0300111
Dear Mr. Bortz:
In accordance with the application submitted on August 18, 2009, we are forwarding permit
number WI0300111. This permit is for the injection of sodium persulfate for petroleum
hydrocarbon oxidation at the Proposed Walgreen Store #10275 at 5040 Beatties Ford Road in
Charlotte, NC.
This permit shall be effective from the date of issuance until September 30, 2008, and shall be
subject to the conditions and limitations stated therein, including the requirement to submit a
final project evaluation as stated hi PART VII — MONITORING AND REPORTING
REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance
requirements of the permit. You will need to notify this office by telephone 48 hours prior to
initiation of operation of the facility. In order to continue uninterrupted legal use of the injection
facility for the stated purpose, you must submit an application to renew the permit 120 days prior
to its expiration date.
If you have any questions regarding your permit please feel free to contact me at [phone].
Sincerely,
Peter Pozzo
Hydrogeologist
cc: David Wagner, Clayton Group Services
Andrew Pitner, Mooresville Regional Office
Sharon Ghiold, UST FIE
CO-UIC files
Enclosure
NNaCarolina
turally
Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: [phone]
Internet: www,ncwaterqualitv.org Location: 2728 Capital Boulevard Raleigh, NC 27604 Fax 1: [phone]
Fax 2: [phone]
An Equal Opportunity/Affirmative Action Employer-50°A Recycled/10% Post Consumer Paper Customer Service: [phone]

NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
RALEIGH, NORTH CAROLINA
PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION
In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and
other applicable Laws, Rules, and Regulations
PERMISSION IS HEREBY GRANTED TO
Sunset Southstar, LLC c/o Tribec Properties
FOR THE CONSTRUCTION AND OPERATION OF TYPE 5I INJECTION WELLS, defined
in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject sodium persulfate,
for oxidation of petroleum hydrocarbon contamination as a pilot study. These injection
wells/points will be located at the Proposed Walgreen Store #10275 at 5040 Beatties Ford Road,
Charlotte, Mecklenburg County, North Carolina, and will be operated in accordance with the
application submitted August 17, 2006, and in conformity with the specifications and supporting
data submitted, all of which are filed with the Department of Environment and Natural Resources
and are considered a part of this permit.
This permit is for Construction and Operation only, and does not waive any provisions of the
Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an
injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C
.0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and
use.
This permit shall be effective, unless revoked, from the date of its issuance until September 30,
2008, and shall be subject to the specified conditions and limitations set forth in Parts I through
X hereof.
Permit issued this the I / day of G ��- ; 2006.
Alan W. Klimek, Director
Division of Water Quality
By Authority of the Environmental Management Commission.
Permit No. WI0300111 PAGE 1 OF 7
ver.4/05 AP/UIC-6

PART I - WELL CONSTRUCTION GENERAL CONDITIONS
1. The Permittee must comply with all conditions of this permit and with the standards and
criteria specified in Criteria and Standards Applicable to Injection Wells (1SA NCAC 2C
.0200). Any noncompliance with conditions of this permit constitutes a violation of the
North Carolina Well Construction Act and is grounds for enforcement action as provided for
in N.C.G.S. 87-94.
2. This permit shall become voidable unless the facility is constructed in accordance with the
conditions of this permit, the approved plans and specifications, and other supporting data.
3. This permit is valid only for construction of the number of injection wells described in the
application and other supporting data. Construction of additional injection wells must be
approved in advance by the Aquifer Protection Section.
4. Each injection well shall not hydraulically connect separate aquifers.
5. Each injection well shall be constructed in such a manner that water from land surface cannot
migrate into the gravel pack or well screen.
6. Each injection well shall be secured to reasonably insure against unauthorized access and use.
Each well shall be permanently Iabeled with a warning that it is for injection purposes and the
entrance to each well must be secured with a locking cap.
7. Each injection well shall be afforded reasonable protection against damage during
construction and use.
8. Each injection well shall have permanently affixed an identification plate.
9. Within 30 days of completion of well construction, a completed Well Construction Record
(Form GW-1) must be submitted for each injection well to:
Aquifer Protection Section-UIC Staff
DENR-Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
PART II - WELL CONSTRUCTION SPECIAL CONDITIONS
1. At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall
notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office
staff, telephone number [phone] and the Mooresville Regional Office Aquifer
Protection Section Staff, telephone number [phone].
Permit No. WI0300111 PAGE 2 OF 7
ver.4/05 APIUIC-6

PART III - OPERATION AND USE GENERAL CONDITIONS
1. This permit is effective only with respect to the nature, volume of materials, rate of injection,
and number of injection wells as described in the application and other supporting data.
2. This permit is not transferable without prior notice to, and approval by, the Director of the
Division of Water Quality (Director). In the event there is a desire for the facility to change
ownership, or there is a name change of the Permittee, a formal permit amendment request
must be submitted to the Director, including any supporting materials as may be appropriate,
at least 30 days prior to the date of the change.
3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying
with any and all statutes, rules, regulations, or ordinances which may be imposed by other
local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this
permit does not imply that all regulatory requirements have been met.
PART IV - PERFORMANCE STANDARDS
1. The injection facility shall be effectively maintained and operated at all times so that there is
no contamination of groundwater which will render it unsatisfactory for normal use. In the
event that the facility fails to perform satisfactorily, including the creation of nuisance
conditions or failure of the injection zone to adequately assimilate the injected fluid, the
Permittee shall take immediate corrective actions including those actions that may be
required by the Division of Water Quality such as the repair, modification, or abandonment
of the injection facility.
2. The Permittee shall be required to comply with the terms and conditions of this permit even if
compliance requires a reduction or elimination of the permitted activity.
3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to
surface or groundwater resulting from the operation of this facility.
PART V - OPERATION AND MAINTENANCE REQUIREMENTS
1. The injection facility shall be properly maintained and operated at all times.
2. The Permittee must notify the Division and receive prior written approval from the Director
of any planned physical alterations or additions in the permitted facility or activity not
specifically authorized by the permit.
3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for
injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central
Office staff, telephone number [phone]. Notification is required so that Division staff
can inspect or otherwise review the injection facility and determine if it is in compliance with
permit conditions.
Permit No. WI030011.1 PAGE 3 OF 7
ver.4/05 APIUIC-6

PART VI - INSPECTIONS
1. Any duly authorized officer, employee, or representative of the Division of Water Quality
may, upon presentation of credentials, enter and inspect any property, premises, or place on
or related to the injection facility at any reasonable time for the purpose of determining
compliance with this permit, may inspect or copy any records that must be maintained under
the terms and conditions of this permit, and may obtain samples of groundwater, surface
water, or injection fluids.
2. Department representatives shall have reasonable access for purposes of inspection,
observation, and sampling associated with injection and any related facilities as provided for
in N.C.G.S. 87-90.
3. Provisions shall be made for collecting any necessary and appropriate samples associated
with the injection facility activities.
PART VII - MONITORING AND REPORTING REQUIREMENTS
1. The proposed monitoring plan included in the application shall be followed. All sample
results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office
and the Raleigh Central Office. Any monitoring (including groundwater, surface water, or
soil sampling) deemed necessary by the Division of Water Quality to insure surface and
ground water protection, will be established and an acceptable sampling reporting schedule
shall be followed.
2. The Permittee shall produce a final project evaluation within 9 months after completing all
injection -related activity associated with the permit application. This document shall assess
the injection projects findings in a written summary. The final project evaluation shall also
contain monitoring well sampling data, contaminant plume maps and potentiometric surface
maps.
3. The monitoring results and the final project evaluation shall be submitted to:
and to:
Aquifer Protection Section-UIC Staff
DENR-Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
Aquifer Protection Section
DENR-DWQ Mooresville Regional Office
610 East Central Ave.
Mooresville, NC 28115
Permit No. WI0300111 PAGE 4 OF 7
ver.4/05 AP/UIC-6

4. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge
of the occurrence, to the Mooresville Regional Office, telephone number [phone], any
of the following:
(A) Any occurrence at the injection facility which results in any unusual operating
circumstances;
(B) Any failure due to known or unknown reasons, that renders the facility incapable of
proper injection operations, such as mechanical or electrical failures.
5. Where the Permittee becomes aware of an omission of any relevant facts in a permit
application, or of any incorrect information submitted in said application or in any report to
the Director, the relevant and correct facts or information shall be promptly submitted to the
Director by the Permittee.
6. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take
such immediate action as may be required by the Director.
PART VIII - PERMIT RENEWAL
In order to continue uninterrupted legal use of the injection facility for the stated purpose, the
Permittee must submit an application to renew the permit 120 days prior to its expiration date.
PART IX - CHANGE OF WELL STATUS
1. The Permittee shall provide written notification within 15 days of any change of status of an
injection well. Such a change would include the discontinued use of a well for injection. If a
well is taken completely out of service temporarily, the Permittee must install a sanitary seal.
If a well is not to be used for any purpose that well must be permanently abandoned
according to 15A NCAC 2C .0113, Well Construction Standards.
2. When operations have ceased at the facility and a well will no Ionger be used for any
purpose, the Permittee shall abandon that injection well in accordance with the procedures
specified in 15A NCAC 2C .0113(b), including but not limited to the following:
(A)All casing and screen materials may be removed prior to initiation of abandonment
procedures if such removal will not cause or contribute to contamination of the
groundwaters.
(B) The entire depth of each well shall be sounded before it is sealed to insure freedom
from obstructions that may interfere with sealing operations.
(C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines
that failure to do so could lead to the contamination of an underground source of
drinking water.
Permit No. W10300111 PAGE 5 OF 7
ver.4105 AP/UIC-6

(D) Drilled wells shall be completely filled with cement grout, or bentonite grout which
shall be introduced into the well through a pipe which extends to the bottom of the
well and is raised as the well is filled.
(E) In the case of gravel -packed wells in which the casing and screens have not been
removed, neat -cement, or bentonite grout shall be injected into the well completely
filling it from the bottom of the casing to the top.
(F) In those cases when, as a result of the injection operations, a subsurface cavity has
been created, each well shall be abandoned in such a manner that will prevent the
movement of fluids into or between underground sources of drinking water and in
accordance with the terms and conditions of the permit.
(G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified
in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment.
3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to:
Aquifer Protection Section-UIC Staff
DENR-Division of Water Quality
1636 Mail Service Center
Raleigh, NC 27699-1636
PART X — WORKER PRECAUTIONS DURING APPLICATION
1. Some effects reported to be associated with exposure to the proposed chemicals are as
follows: Exposure can cause severe irritation and burning of eyes, skin, nose and throat.
Inhalation exposure can cause coughing, wheezing, and/or shortness of breath including
asthma -like allergy. Future exposure can cause asthma attacks with shortness of breath,
wheezing, cough, and/or chest tightness. Inhalation exposure can cause severe respiratory
irritation and inflammation leading to shock, coma, and seizures.
2. Chemicals proposed for use may ignite combustibles such as wood, paper, oil, etc. The
chemicals proposed for use must be stored separately from hydrazine and organic
monomers since violent reactions can occur. The chemicals proposed for use are not
compatible with reducing agents; powdered metals; strong bases such as sodium
hydroxide and potassium hydroxide; alcohols; and hydrocarbon fuels.
3. Store in tightly closed containers in a cool, well -ventilated area away from moist air and
combustibles. Containers may explode when heated. Runoff may create fire or explosion
hazard. Chemicals proposed for use heat up spontaneously when decomposing and could
start fires.
4. If the products are released into the environment in a way that could result in a suspension
of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing),
then proper.personal protective equipment should be used. The application process
should be reviewed by an industrial hygienist to (1) ensure that the injection process is
done in a safe manner, and (2) ensure that the most appropriate personal protective
equipment is used.
Permit No. WI0300 111 PAGE 6 OF 7
ver.4/05 AP/UIC-6

5. Persons working with these products should wear goggles or a face shield, gloves, and
protective clothing. Face and body protection should be used for anticipated splashes or
sprays.
6. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be
permitted in the application area during or immediately following application.
7. Safety controls should be in place to ensure that the check valve and the pressure delivery
systems are working properly.
8. The Material Safety Data Sheets should be followed to prevent incompatible or adverse
reactions and injuries.
9. Access to the area of application should be limited to workers applying the product. In
order to minimize exposure to unprotected individuals, measures should be taken to
prevent access to the area of application.
Permit No. WI0300111 PAGE 7 OF 7
ver.4/05 AP/UIC-6

DIVISION OF WATER QUALITY
AQUIFER PROTECTION SECTION
September 21, 2006
MEMORANDUM
TO: Andrew Pitner
Mooresville Regional Office
FROM: Peter .Pozzo, Underground Injection Control Program
Additional information injection well permit application #W I03©0
Enclosed is a copy of the additional information you requested. The LAIC Program appreciates your
staffs assistance with the review of this permit. If you have any questions regarding this permit or
the UIC Program, please call me at (91.9) 715-6164.
cc: UIC-CO tiles
Enclosures

3380 Chastain Meadows Parkway
Suite 300
Kennesaw, GA 30144
7 7Q.499,7500
fax 770.499,7511
September 19, 2006
Atttn: Mr. Qu Qi, PG
Program Manager
UIC Program
Aquifer Protection Section
North Carolina DENR-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
off
R O U P SERVICE S
RECENEC I DENR i
AQUIFFR'FRfTFCTION SECTION
SEP 2 0 2006
Clayton Project No, 99006-006118
Subject; Submittal of "Modified Attach rr ents E & F" for the "Application for
Permit to Construct and/or Use a Well(s) for Injection"
Old Store LUST Incident #8789
5040 Beatties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beattles Ford Road and Sunset Road, Charlottes North Carolina
Dear Mr. Qi:
As per your letter dated September 11, 2006, enclosed please find two copies of
"Modified Attachments E & F" for the "Application for Permit to Construct and/or Use a
Well(s) for Injection" for the above referenced site. The application for permit includes
the implementation of a field pilot study to evaluate the use of sodium persulfate as a
remedial method,
Clayton, on behalf of Sunset Southstar, would greatly appreciate your quick approval of
this application so that the redevelopment of this property can proceed without delay. In
the interim, if you have questions, please contact me at 919 960-6289.
Sincerely,
Clayton Group Services, inc.
A Bureau Verdes Company
David Wagner
Senior Consultant
Atlanta Regional Office
Mr, Randy Nance, Sunset Southstar
attachment
www.claytongrp.com
.Environmental Services • Occupational Health and Safety • Laboratory Services

MODIFIED ATTACHMENTS E & Fl — SECTION V
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)
I FOR INJECTION
Type 51 Wells in Situ Groundwater Remediation
Old Store LUST Incident (#8789)
5040 Beatties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, North Carolina
September 19, 2006
Clayton Project Number 99006-006118
0
' 'g1.�„ AG �'`'
E. Monitoring Plan
Prior to injection of persulfate, an electrical conductivity probe will be used to acquire
background levels of electrical conductivity through the target zone (i.e. from 14 to 30
feet bgs). This testing will be conducted at the injection location, prior to installation of
the injection wells. Once the injections have been completed, the vertical and lateral
distribution of the persulfate using the conductivity probe will be assessed. The electrical
conductivity measurements, in the presence of persulfate, will be elevated significantly
from background readings and therefore conductivity measurements vertically and
laterally will provide information on the radius of influence and the vertical distribution
of the persulfate.
In addition to electrical conductivity testing, starch iodide test kits will be used to test
groundwater within the monitoring well. The starch iodide test is a quick and reliable
visual field technique to indirectly test for the presence of persulfate. Upon contact with
persulfate, the starch iodide solution will turn bright blue.
Also prior to the injection, a groundwater sample will be collected from the newly
installed monitoring well for analysis of VOCs (using USEPA Method 8260), sulfate, and
Metals including As, Cd, Cr, Fe, Hg, Na, Pb, Cu, and Ag (using Method 3030C). A
North Carolina -certified laboratory will perform the analysis. In addition, field
parameters including depth to groundwater, pH, oxidation-reduction potential (ORP),
temperature, dissolved oxygen (DO), and conductivity will also be measured during the
pre -injection sampling event. Post -injection groundwater monitoring will be conducted
approximately 24 hours, two weeks, and one month after the injection is complete, then
quarterly thereafter until sampling results show that the reactions are complete and
geochemical conditions return to the pre -injection state. The post -injection analysis will
z Modifications to Attachments E and F per letter from NCDENR's Aquifer Protection Section dated
September 11, 2006.

Modified Attachments E & F — Section V
Application for Injection Pilot Study
r OW Store LUST Incident
Proposed Walgreen Store#10275
Charlotte, NC
be the same as the pre -injection analysis, including the in -direct measurement of
persulfate.
F. Well Data
A 500 ft-radius water well survey was completed during week ending September 22,
2006. This survey included contacting (via facsimile and through the internet) the
Charlotte / Mecklenburg County' Utilities Authority, New Services Department and the
Mecklenburg County Environmental Health Department to evaluate if the properties
within a 500-ft radius of the subject property are on city -supplied water or have registered
wells, respectively. The information obtained from these two departments indicated that
the properties surrounding the subject property (within a 500 ft radius) are on city -
supplied water and that there are ino wells currently registered within this area. The area
searched is shown on the attached map.
One monitoring well, designated as MW-2, currently exists on the subject property. It is
believed that this well was installed as part of the initial investigation of the 5040 Beatties
Ford Road Old Store LUST incident back in the early 1990's. It is constructed of 1-inch
PVC and is approximately 19.5 feet deep. The depth of the screened interval is unknown.
During January 2006, the depth to water in this well was measured at 18.6 feet below the
top of the casing, with approximately one foot of water in the well. Apparently, this well
was not installed deep enough to adequately monitor the water table, therefore its use as a
reliable and adequate monitoring point is questionable. q�oa C �,`7o‘®
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AQUIFER PROTECTION REGIONAL STAFF REPORT
Dat25/06 ,r
To: A�`i otection Central ©fice
Central Office Reviewer:
Regional Login No:
I. GENERAL .INFORMATION,
1. This application is (check an that apply): New Rene
Minor Modification ( Micar Modification
Sur
Land Application of Residuals
Distribution of Residuals
Closed -loop Groundwater Rernediation J Other lnjectio
Was a site visit conducted in order to prepare this report
Project Na
0
County: Mecklenburg
Perittee: Sunset Southstar
pplication No.:
Reuse LJ Recycle LJ High Rate lnfiltratiott Li l:vapnration/tnfiltration Lagoon
� Attachment B included [1 50.3 regulated D 503 exempt
© Surface Disposal
N
including in ,siiei renaediation)
a. Date of site visit: n/a, but familiar +friththis location from recent previous work nearby.
b. Person contacted and contact information: Contacts include Sharon Ghiold & Alan Schiff, UST Section
c. Site visit conducted by:
d. Inspection Report Attached: Yes or No..
Is the following information entered into the BIMS record for this application correct?
® Yes or No. If no, please complete the .following or indicate that it is correct on the current application.
For Treatment Facilities:
a. Location: The actual site is located at ft40 Heatties Ford Road, Charlotte„ NC 28216. It appears that the
mailing address is currently listed in BIAS as the facility location.
b. Driving .Directions: 1-77 south from Mooresville to the Sunset Rd, exit (6 o ri ht west about 0.5
intersection with Beatties Ford. Site is at SE corner of that intersection. Look for the parking lot of the new
Walgreens.
c. USGS Quadrangle Map name and nut be Deritaa
d. Latitude: 35 18' .I8" Longitude: 80 51' 28"
e. Regulated Activities / Type of Wastes (e.g., subdivision, food processing, municipal wastewater): ok
For Disposal and Injection Sites:
(If multiple sites either indicate which, sites the information applies to, copy and pastes. dew secti.ot�t into the
document for each site, or attach additional pages for each site)
a. Location(s):
b. Driving Directions:
c. USGS Quadrangle Map name and number:
d. Latitude: Longitude:
II. NEW AND MAJOR MODIFICATION APPLICATIONS ('this senot needed,,/` r° renewers or minor
modifications, skip to next section)
Section deleted — NA to this permit.
FORM: APRSR04O929-UIC Review Old Store UST site Meck

AQUIFER PROTECTION REGIONAL STAFF REPORT
II1. RENEWAL AND MODIFICATION APPLICATIONS (use previous section for new or major modification
systems)
Section deleted —NA to this permit.
IV. INJECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection
wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat
pump injection wells.)
Description Of Well(S) And Facilities — New., Renewal, And Modification
Type of injection system:
❑ Heating/cooling water return flow (5A7)
E Closed -loop heat pump system (5QM/5QW)
® In situ remediation (51)
❑ Closed -loop groundwater remediation effluent injection (5LP'Non-Discharge")
❑ Other (Specify:
2. Does system use same well for water source and injection? E Yes ® No
3. Are there any potential pollution sources that may affect injection? ® Yes E No
What is/are the pollution source(s)? Former UST systems contaminated soil and groundwater at the site with
petroleum products. This system is designed to treat the contamination. What is the distance of the injection
wells) from the pollution source(s)? 0 ft.
4. What is the minimum distance of proposed injection wells from the property boundary? Approx 20 ft.
5. Quality of drainage at site: E Good
6. Flooding potential of site: ® Low
® Adequate
❑ Moderate
❑ Poor
❑ High
7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program
(number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ® Yes ❑ No. Attach
map of existing monitoring well network if applicable. If No, explain and recommend any changes to the
groundwater monitoring program: The proposed monitoring is generally adequate for the pilot test. Note that
the proposal indicates that the exact location of the injection wells will be determined based on field conditions,
which include tearing down the old station building. However, it is not clear that a full-scale system will have
adequate injection and monitoring locations as the contaminated soil and groundwater extend under a newly -
widened & heavily traveled intersection. The extent of the existing contamination does not appear to be fully
defined. Note that the MRO UST Section no longer has the incident file for this site — it is now in Raleigh.
8. Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If
no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution
sources, roads, approximate scale, and north arrow.
Iniection Well Permit Renewal And Modification Only:
Section deleted — NA to this permit.
FORM: AFRSR040929-UIC Review Old Store UST site Meck 2

AQUIFER PROTECTION REGIONAL STAFF REPORT
V. EVALUATION AND RECOMMENDATIONS
1. Provide any additional narrative regarding your review of the application:
2. Attach Well Construction Data Sheet - if needed information is available
3. Do you foresee any problems with issuance/renewal of this permit? ❑ Yes ® No. If yes, please explain
briefly.
4. List any items that you would Iike APS Central Office to obtain through an additional information request.
Make sure that you provide a reason for each item:
Item
Reason
Updated supply well survey
Well survey in application consists of 1997 map
& table from previous consultant's work at this
site and a 2003 survey table w/o keyed map by
another consultant at a nearby site. Need to
clarify the status of possible supply wells in the
immediate vicinity (-500 ft) for the purposes of
this pilot test. Recommend updated 1500' survey
if system will be up scaled.
5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure
that you provide a reason for each condition:
Condition
Reason
6. List specific special conditions or compliance schedules that you recommend to be included in the permit when
issued. Make sure that you provide a reason for each special condition:
Condition
Reason
Copies of this permit application and all system
This work is not considered directed or being
installation & monitoring reports and diagrams
required by UST staff even though this is
must also be submitted to Sharon Ghiold of the
considered a high -risk site. In order to better
UST FTF Group.
manage the site, UST needs to be in the
information loop, but they apparently cannot
require that this information be submitted to
them. Should legislative changes mandate future
FORM: APRSR040929-UIC Review Old Store UST site Meck
3

AQUIFER PROTECTION REGIONAL STAFF REPORT
work at the site, they need to know about
existing infrastructure and impacts of associated
injections.
7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; n Hold,
pending review of draft permit by regional office; ® Issue upon receipt of needed additional information; ❑
Issue; ❑ Deny. If deny, please state reasons:
8. Signature of report preparer(s): Andrew H. Pitner
9. Signature of APS regional supervisor: Andrew H. Pitner
Date: 8/25/06
ADDITIONAL REGIONAL STAFF REVIEW ITEMS
Also, please include "Old Store UST#8789 somewhere in BIMS so that it is clear which incident site this injection
is attempting to address.
FORM: APRSR040929-UIC Review OId Store UST site Meek 4

AQUIFER PROTECTION SECTION
APPLICATION REVIEW REQUEST FORM
Date: August °'' , 2.00
o:
C
Landon Davidson, ARC?-APS
Art Barnhardt, FRO-APS
Andrew Pitner, MRO-APS
Jay Zimmerman, R.RO-A.PS
From : Qu Qi , Ciroa ;n water Protcctio
Telephone: [phone]
.F.-Mail: qu.gi
030011'1
hs
y/Operatics : Proposed Walt stem Store # 1.0275
D. Appiicati
1. Perm
it Type:
El Proposed
For Residuals..
Animal
Recycle
fisting
David May, WaRO-LIPS
_ Charlie Stehnban, WiRO-APS
I— Sherri Knight, WSRO-APS
Fax: L9J9) 715-0
lity ri Operation
Rcttse Ej ip-R infiltration
gratin CON Rernedia
IJ1C - (51) in -situ groundwater retnediation
Ej Land App.
503
2. Project Type: New [l Major 1
Co., '.eats/Otherllr forma
II
D&M
503 Exempt
od. I Minor Mod. 1 1 Renewal
ike
rnpany you on a s
(ND)
face 1*)isposal
nal
Renewal w, Mod.
Attached, you will find all information snbrnittcd in support of the above -referenced application for your
re eww, eomme.nt, and/or. action, Within 30 calendar days, please take the following actions:
Z Return a Completed honn APSSRR.
Attach Well Construction Data Sheet.
E. Attach Attach.rent B for Certification by the LA.PCIU.
11 Issue an Attachment B Certification from the RO*.
Remember that you will be responsible for coordinatitu site visits, re iewadditi.ot al
information requests with other RO-APS representatives in carder to prepare a cornplete Attaeh rent B for
certification. Refer to the RPP SOP for additional drtsil.
When you receive this request form, please write your name and dates in the spaces below, make a copy
of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person
listed above.
RO-APS Reviewer:
e:
,APSARR 02/06 Page 1 of 1

Michael F. Easley, Governor
William G. Ross Jr.„ Secretary
North Carolina Department of Environment and Natural Resources
Alan W. Klimek, P.E. Director
Division of Water Quality
Auaust 2l, 2006
Scott Bortz
200 Providence Road, Suite 106
Charlotte. NC 28207
Subject: Acknowledgement of Application No, W103001 1 1
ln)ection in Situ. Groundwater Rernedia.tiun Well (51)
Mecklenburg
Dear Mr. Bortz:
The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit
application and supporting materials on August 18, 2006, This application package has been assigned the number
listed above and will be reviewed by Qu Qi.
The reviewer will perform a, detailed revct you with a request for additional information it necessary.
To ensure the urrr irtlartrt e. aciencv in processing permit Applications, the Division requests your assistance in
providing a timely and complete response to any additional itrtorniation requests.
Please be aware 'that the Division's Regional Office, copied below, must provide recommendations prior to flu.
action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days
after receipt of a complete application,
if you have any questions, please contact Qu Qi at 919-715-693,5, or via e-mail at qu.gi@nemaiLnet. 1f the reviewer
is crrtavailable, you may leave a message, and they will respond promptly. Also note that the Division has
reorganized, To review,' our new organizational chart, ao to lttt `'h2o lrr.state,nc.usldoeumentsidwq p,rgchart,.pdf:
PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS
PROJECT.
Supervise
cc:
Regional Office, Aquifer Protection Section
David Wagner, Senior Consultant - Clayton Group Services
Permit Application File W10300l 11
Aquifer Protection Section 1636 Mail Service Center
Internet: www.ncwaterquahty.orq Location: 2728 Capital Boulevard
An Equal Opportunity/Affirmative Action Employer- 50% Recycled/10`Y° Post Consumer Paper
Raleigh„ NC 27699-1636 Telephone: [phone]
Raleigh, NC 2,7604 Fax 1: [phone]
Fax 2,: [phone]
Customer Service: [phone]

t�.arkw �4
Kennesw:c,•v, t,\ 30144
.70.499? 5iil)
'Fax 770.4 9,?5G1
August 17, 2006
UIC Program
Aquifer Protection Section
North Carolina DENR-DVWQ
1636 Mail Service Centert.--
Raleigh, NC 27699-1636
RECEIVED / DENR I DWQ
AQUIFER `PROTECTION SECTION
AUG x $ 200E
Clayton Project No. 99006-006118
Subject: Submittal of "Application for Permit to Construct andlor Use a
Well(s) for Injection"
Old Store LUST Incident #8789
5040 Beatties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road, Charlotte, North Carolina
Dear UIC Program Official:
Enclosed please find two copies of an "Application for Permit to Construct and/or Use a
Well(s) for Injection" for the above referenced site. The attached application for permit
includes the implementation of a field pilot study to evaluate the use of sodium persulfate
as a remedial method. Clayton will retain the services of Redox Tech, LLC of Cary,
North Carolina to conduct the pilot study and inject the sodium persulfate. Redox Tech
has many years of experience in the chemical oxidation and injection business.
Based on information provided by Ms. Sharon Ghiold of NCDENR, there is currently no
responsible party (RP) for the referenced Old Store LUST Incident, since the original
owner of the former USTs has long been deceased and his estate dissolved. Therefore,
the Old Store LUST Incident site is currently being overseen by NCDENR's UST Section
Trust Fund Branch, Federal -Lead Program. The site has been classified as a "high risk"
due to on -site groundwater contamination exceeding NCDENR standards and the
presence of off -site receptors within 1,000 feet of the property line, However, according
to Ms. Ghiold, the UST Section has no immediate plans for additional work at this site,
since the nearby receptors are not impacted by the LUST incident and there are limited
funds available for such activities.
According to Ms. Ghiold, the UST Section will not require the current property owner
(which is Sunset Southstar, LLC c/o Tribek Properties (Sunset Southstar)) to conduct a
soil and groundwater investigation' and/or remediation in order to develop the subject
property or after development, even though soil and groundwater concentrations are
present above applicable standards. Furthermore, Ms. Ghiold stated that the current
As part of the real estate transaction for this property, a Limited Subsurface Invest' gatton vas conducted
by Clayton, the results of which are presented in the application for pernit.
te:sn s Fr.z n
::s.�taa tins' al Flaltk.i atf7t

Submittal of Application for UIC Permit
Old Store LUST Incident
Charlotte, NC
c�Claytori
property owner will not become the RP and would not be made responsible for any
monitoring or remediation costs. However, Ms. Ghiold also indicated that site closure
could not be granted as long as concentrations remain above the applicable standards
and there remain off -site receptors, and that any activities related to achieving closure
could be undertaken and financed by the existing property owner on a voluntary basis.
Sunset Southstar will be redeveloping the subject property and does not plan on
obtaining closure of the Old Store LUST Incident at this time. However, in good faith and
to minimize the possibility of significant disturbance to the subject property after it has
been redeveloped, Sunset Southstar has elected to install the subsurface portion only of
a full-scale remediation system, which could be activated in the future (if needed) to
address impacted soil and groundwater associated with the Old Store LUST Incident.
The subsurface portion (Le., wells and piping network) of the full-scale system will be
installed in conjunction with site redevelopment activities and will be covered over by
landscaped areas and pavement. A piping manifold will be located above ground for
future access (if needed) to the subsurface system. The subsurface system could be
activated at a later date if so desired by either NCDENR or the subject property owner.
The results of the sodium persulfate pilot study will be used to design the subsurface
portion of the full-scale system_
Clayton, on behalf of Sunset Southstar, would greatly appreciate your quick approval of
this application so that the redevelopment of this property can proceed without delay. In
the interim, if you have questions, please contact me at 919 960-6289.
Sincerely,
Clayton Group Services, Inc.
A Bureau Veritas Company
David Wagner
Senior Consultant
Atlanta Regional Office
cc: Mr. Randy Nance, Sunset Southstar
attachments
Page 2

State of North Carolina
Departmertt of Environment and Natural Resources
Division of Water Quality
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A "l'l'EI L(S) Ft
Type 51 Wells — In Situ Groundwater Remediation / Type 5T Wells — Trace
• Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinjec
• Submit TWO copies of the completed application and all attachments to the address on the last page of th
• Any changes made to this form will result in the application package being returned.
Application Number (to he completed by.DWQ):
GENERAL INFORMATION:
1. Applicant's Name (generally the responsible p
2. Signing Official's Name:=_;
3. Mailing address of applicant:::20Q Providence'Road, Suite
City: Charlotte
Telephone slumber:r704-333-8484
RECEIVED / DENR / CWQ
AQUIFER 'PROTECTION SECT
AUG 18 2806
a T k. Properties
State: NC Zip: 28207
Fax number: 704-333-8485
4. Property Owner's Name (if different from Applicant): 5 ��
5. Property Owner's mailing address:
City:
6. Name and address of contact person
Name:, David Wagner
Company: Clayton Group Services
Address: 297 Highview Drive
City: Chapel Hill
Telephone number: 919 960 6289
ho can ans
State:
Email Address: dovid.wagner [e-mail]
11. PERMIT INFORMATION:
stions about the proposed injection proje
Title: Senior Consultn"
State: NC Zip: 27517
Fax number: 919 960 6289
Project is: 1New [1 Modification of existing permit Li Renewal of existing pe It without modification
If this application is being submitted for renewal or modification to an existing perrrtit, provide:
existing permit number and the issuance date
For renewal without modifications, fill out sections]. & II ony, sign the certification on the last page of this
form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner).
MC-fit/5T ver. 12-05 Page p of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
III. INCIDENT & FACILITY DATA
A. FACILITY INFORMATION
I. Facility name: Proposed Walgreen Store #10275, SEC of Beatties Ford Road and Sunset Road
2. Complete physical address of the facility: 5040 Beatties Ford Road
City: Charlotte County: Mecklenburg State: NC Zip: 28216
B. INCIDENT DESCRIPTION
1. Describe the source of the contamination:
From approximately the mid 1960s up to approximately 1990, the 5040 Beatties Ford Road property was a
gasoline retail station. During UST removal in 1990, soil and groundwater contamination was confirmed.
Additional USTs were discovered during a road widening project in February 2000. Some of the impacted soils
were excavated and disposed of off -site. However, petroleum -related compounds remain in the soil and
groundwater at concentrations exceeding NCDENR standards.
2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g.,
gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc):
gasoline -related compounds - See attached tables for most recent results.
3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)?
❑ Yes If yes, list maximum measured separate phase thickness: feet
lNo If no, list maximum concentration of total VOCs observed at site: 2,323,000 (see SB-7 soil) ppb
4. Agency managing the contamination incident:
OUST Section ❑ Superfund Section (including REC Program and DSCA sites)
❑ DWQ Aquifer Protection Section ❑ Solid Waste Section
❑ Hazardous Waste Section 0 Other: Federal Trust Fund program
5. Incident number or other site number assigned by the agency managing the contamination incident:
8789
C. PERMITS
List all permits or construction approvals that have been issued for the facility or incident, including those not
directly related to the proposed injection operation:
I. Hazardous Waste Management program permits under RCRA:
2. DWQ Non -Discharge or NPDES permits:
3. County or DEH subsurface wastewater disposal permits:
4. Other environmental permits required by state or federal law:
UIC-5115T ver. 12-05 Page 2 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells— Tracer Injection
IV. INJECTION DATA
A. INJECTION FLUID DATA
1. List all proposed injectants.
NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the
Occupational and Environmental Epidemiology Section (GEES) of the Division of Public Health, Department of
Health and Human Services. Review the list of approved iniectants or contact the UIC Program to determine if
the injectants you are proposing have been reviewed by OEES.
Injectant:sodium persulfate
Concentration at point of injection:20 percent by weight
Injectant
Concentration at point of injection:
Inj ectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
Injectant:
Concentration at point of injection:
2. Source of fluids used to dilute or chase the injectants listed above:
® None
❑ Municipal water supply
❑ Groundwater from private well or any well within % mile of injection site
❑ Air
❑ Other:
3. If groundwater from a private well or any well within 'A mile of injection site is to be used as the fluid source,
supply the following information:
a_ Location/ID number of source well: not applicable
b_ Depth of source:
c. Formation:
d. Rock/Sediment type:
e. In Attachment B, provide a current, complete chemical analysis of the water from the source well, including
analyses for all contaminants suspected or historically recognized in soil or groundwater on the site.
NOTE: If contaminated groundwater is to be used as the dilution or chase, fluid, this is not the proper permit
application form. You must apply for a closed -loop groundwater remediation permit using application fnr;ri
G JVRS.
UIC-51/5T ver. 12-05 Page 3 of 7

APPLICATIION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
B. PROPOSED OPERATING PARAMETERS
1. Duration of Injection:
Maximum number of separate injection events: one
Expected duration of each injection event: Approx 2 - 9 hrs
Expected duration between events (if more than one event):
2. Injection rate per well: Approx 2 - 10 gallons per minute (gpm)
3. Total Injection volume: 1,000 gallons per day (gpd); gallons per event (if separate events)
4. Injection pressure: 50 - 125 pounds/square inch (psi)
5. Temperature at point of injection: ambient °F
6. Briefly describe how the above parameters will be measured and controlled:
via valves, regulators, and gauges
7. Estimated hydraulic capacity of the well: less than 5
gpm
C. INJECTION WELT. CONSTRUCTION DATA
1. Injection will be via:
❑ Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of
your knowledge.
O Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as
proposed construction specifications.
2. Well Drilling Contractor's Name: Redox Tech, LLC
NC Well Contractor Certification number: 3380
3. Date to be constructed:4Pffr ft''`'1 iTA▪ let4(61(li&ber of borings: 3
Approximate depth of each boring (feet): 19, 24, & 30
4. Screened interval/Injection interval of injection wells:
Depth: 14 to 30 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth).
5. Well casing (N/A if injection is through direct push rods):
Type: ® PVC ❑ Stainless steel ❑ Other:
Casing depth: 14 to 25 ft.
6. Grout (N/A if injection is through direct push rods):
Type: ® Cement ® Bentonite ❑ Other:_
Grout depth: 12 to 23 ft.
UIC-5I/5T ver. 12-05 Page 4 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
V. ATTACHMENTS
Provide the following items as attachments with the given headings:
A. HYDROGEOLOGIC DESCRIPTION
Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the
known or projected depth of contamination. The hydrogeologic description shall include:
(1) the regional geologic setting;
(2) significant changes in lithology;
(3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a
description of the test(s) used to determine these parameters; and
(4) the depth to the mean seasonal high water table.
NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the
public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her
direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been
prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or
her.
B. INJECTION FLUID COMPOSITION
Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety
Data Sheet (MSDS) for each injectant. If a private well or a well within 1 mile of the injection site is used as the source
well, include chemical analysis of source fluid here.
C. INJECTION RATIONALE
Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including:
(1) goals of the injection project;
(2) a description of the reactions between the injectants and the contaminants present including specific breakdown
products or intermediate compounds that may be formed by the injection; and
(3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change
(biological, chemical or physical) in the subsurface.
D. INJECTION PROCFDI ERE AND EQUIPMENT
Provide a detailed description of all planned activities related to the proposed injection including but not limited to:
(1) construction plans and materials;
(2) operation procedures;
(3) a detailed diagram of the surface and subsurface portions of the system; and
(4) a planned injection schedule.
E. MONITORING PLAN
Provide a plan for monitoring the results of the injection, including:
(1) a list of existing and proposed monitoring wells to be used;
(2) a list of monitoring parameters and analytical methods to be used; and
(3) a schedule for sampling to monitor the proposed injection.
NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by-
products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target
contaminants as well as secondary or intermediate contaminants which may result from the injection and other
parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and
other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated
reactions and rate of transport of the injectants and contaminants.
UIC-51/5T ver. 12-05 Page 5 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection
F. WELL DATA
Provide a tabulation of data on all existing or abandoned wells within '/a mile of the injection well(s) which penetrate the
proposed injection zone, including, but not Limited to, monitoring wells and wells proposed for use as injection wells.
Such data shaII include a description of each welI's use (water supply, monitoring, etc), total depth, screened or open
borehole depth interval, and well construction or abandonment record, if available.
G. MAPS
Attach the following scaled, site -specific maps:
(1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and
showing the location of the proposed injection site.
(2) Site map including:
a. all property boundaries;
b. all buildings within the property boundary;
c. existing and proposed injection wells or well field(s)
d. any existing sources of potential or known groundwater contamination, including waste storage,
treatment or disposal systems within 'A mile of the injection well or well system;
e. all surface water bodies within' mile of the injection well or well system; and
f. all existing or abandoned wells within ''A mile of the injection well(s) which penetrate the proposed
injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection
wells.
(3) Potentiometric surface map(s) including:
a. direction of groundwater movement
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(4) Contaminant plume map(s) including:
a. the horizontal extent of the contaminant plume, including isoconcentration lines
b. existing and proposed monitoring wells
c. existing and proposed injection wells
(5) Cross-section(s) to the known or projected depth of contamination, including:
a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines
b. major changes in lithology
UIC-5115T ver. 12-05 Page 6 of 7

APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELLS) FOR IN`JE CTION
Type 5I Wells — In Situ Groundwater Remediation / Type 5T We ll:t — Tracer Injection
VI. CERTIFICATION
I, -f te7 C.BQtta , hereby certify under penalty of law that
I have personally examined and am familiar with the information submitted in this document and all attachments
thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information,
I believe that the information is true, accurate and complete. I am aware that there are significant penalties,
including the possibility of fines and imprisonment, for submitting false information. I agree to construct,
operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in
accordance with the approved specifications and conditions of the Permit,
Signature:�
Title: /11444(+—
Date:
If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the
above agent.
VIL CONSENT OF PROPERTY OWNER (if le property is not owned by the applicant)
("Owner" means any person who i?olds Melee or other property rights in the well being constructed. A well is
real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of
contrary agreement in writing)
I, a�z as owner of the property on which the
injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each
injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure
that the injection well(s) conform to the Well Construction Standards (Title 15.A NCAC 2C .0200)
SignatureW w Date: fr
Title:. I� ,
Submit TWO copies of the completed application package, including all attachments,. to:
UIC-51.15T ver. 12-05
ULC Program
Aquifer Protection Section
North Carolina DENI4-DWQ
1636 Mail Service Center
Raleigh, NC 27699-1636
RECEIVED l INN
AQUIFERPROTECTI( N
Telephone [phone] AUG 18 2005
Page 7 of` 7

ATTACHMENTS — SECTION V
APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S)
FOR INJECTION
Type 5I Wells — In Situ Groundwater Remediation
Old Store LUST Incident (#8789)
5040 Beatties Ford Road
Site of Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
. Charlotte, North Carolina
August 17, 2006
Clayton Project Number 99006-006118
A. Hydrogeologic Description
The subject property is located in the Southern Piedmont Physiographic Region of North
Carolina. The subject property is underlain by the Charlotte Belt, which is generally
composed of metamorphic and intrusive rock from the late -Proterozoic to mid -Paleozoic
age. Depth to bedrock is greater than 30 ft bgs. The general area is characterized by
broad, gently rolling interstream areas with steeper slopes along drainage ways. The
Catawba River and its tributaries drain three -fourths of Mecklenburg County and the
Rocky River and its tributaries drain the remaining eastern portion. The closest water
body appears to be McIntyre Creek, located approximately 5,000 feet to the north and
several small, unnamed ponds located approximately 2,000 feet to the southwest.
Topographic gradient around the subject property trends to the south to southwest, while
the subject property is generally flat. Elevations at and around the subject property range
from 820 to 830 ft above mean sea level (USGS Topographic Map Derita, NC, 1993).
According to files obtained from NCDENR, approximately 15 private water wells are
located within a 1,000-foot radius of the subject property (see Section F for further
details).
Based on borings drilled at the subject property by Clayton, the native soil at the subject
property generally consists of a dark brown to light brown clayey silt to silty clay (see
attached boring locations and boring logs). The native soil in the immediate vicinity of
the Old Store LUST incident consists mostly of clayey silt. Fill was encountered in the
area of the former Old Store USTs to depths as great as 17 ft bgs. As shown on the logs,
this fill also consists of a clayey silt. In addition, fill in the form of fine to coarse slag,
covers the majority of the site. No significant changes in lithology were observed.
The depth to groundwater measured in the vicinity of the Old Store LUST incident (at
boring locations SB-1, SB-2, SB-4, SB-6, and MW-2) ranged from 17.7 ft bgs to 18.7 ft
bgs. Based on the depth to water measurements and relative elevations measured by
Clayton, the apparent groundwater flow direction in the area of the Old Store LUST

�,���aeaco?caadr�a
Attachments — Section V
Application for Injection Pilot Study a °
Old Store LUST Incident /..—..."
_Proposed Walgreen Store #10275
Charlotte, NC :' \5. 4l�
@v�ss d4 a�; OLd�'' Ny Joao
incident is to the southwest. This apparent direction of groundwater flow` k�6fasito®+°
with that measured in the past (circa January 1997) during earlier investigatiol'1 +tfftlPM
Old Store LUST incident (see attached figures).
The hydraulic conductivity (K) and the specific yield (Sy) of the saturated zone in the
vicinity of the Old Store Lust incident was estimated from published literature at 10'2
gallday/f (Freeze and Cherry, 1979) and 10-15 percent (Driscoll, 1989), respectively.
The transmissivity (T) of the saturated zone in the vicinity of the Old Store Lust incident
was estimated using the referenced K value and a saturated zone thickness (b) of 10 ft.
Using the formula: T = Kb, the estimated value of T is 104 gal/day/ft.
B. Injection Fluid Composition
An MSDS sheet for sodium persulfate is attached.
The pilot test will encompass an area of approximately 115 square feet, targeting depths
from 14 to 30 feet bgs (unsaturated and saturated soils). Using a total oxidant demand
(TOD) value of 9.9g/kg, approximately 1,705 pounds of sodium persulfate will be
required to treat the target zone. The TOD value is the highest reported value from
laboratory testing conducted on site -specific soil and groundwater samples. The sodium
persulfate will be mixed at a 20% solution by weight, resulting in approximately 1,000
gallons of solution that will be injected.
Sodium hydroxide will be added to the solution in order to catalyze the persulfate. A
total of approximately 20 gallons of a 25 percent by weight solution of sodium hydroxide
will be used.
C. Injection Rationale
Sodium persulfate is being injected into the subsurface as part of a pilot study. The
objective of the pilot study is to evaluate the efficacy of using sodium persulfate to
remediate impacted soil and groundwater and to obtain necessary parameters for the
design of a full-scale system including well construction, well spacing, injection volumes,
loading rates, etc. Sodium persulfate was selected due to its proven ability to oxidize the
types of gasoline -related contaminates detected at the site including benzene, 1,2-
Dibromoethane (EDB), and 1,2-Dichloroethane (DCA) (see attached tables).
In recent years, sodium persulfate has been recognized as a very effective oxidant in
treating volatile organic compounds (VOCs). Some of the advantages of sodium
persulfate over other treatment alternatives are provided below:
1) Safer to handle compared to other widely used oxidants.
2) High solubility in water compared to potassium permanganate. Comparable
solubility to hydrogen peroxide, but much safer at higher concentrations. This
means more oxidant per gallon of solution injected.
Page 2

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store # 10275
Charlotte, NC
1995 t
3) Is effective over a wide range of pH conditions and is less affectekby eep14�o
groundwater geochemistry than Fenton's chemistry. '•,y�9y'j"y*I�ts* 4e�
4) When steam -catalyzed, persulfate is the most robust (works on most n `joa+°
organic contaminants) oxidant on the market. When catalyzed by iron or acid, it
has a higher oxidation potential than permanganate, and comparable to Fenton's
chemistry.
5) The solution is colorless and odorless.
6) The sulfate produced during the consumption of persulfate inhibits the conversion
of dichloroethene (DCE) to vinyl chloride (VC). The sulfate can also serve as an
electron acceptor for anaerobic oxidation of petroleum compounds.
7) Works on mixtures of petroleum and chlorinated solvents. Permanganate
typically is used for chlorinated alkenes. There is safety issues associated with
aggressive Fenton's chemistry on petroleum.
The persulfate anion is the most powerful oxidant of the peroxygen family of compounds.
When given energy (i.e., heat, light, etc.), the persulfate forms sulfate radicals which in
turn have Tots of energy and can easily oxidize many compounds including benzene, EDB
and DCA, which are present at the site. Under alkaline conditions, the reaction of
persulfate follows this equation:
5208"2 + OFF - HSO4` + SO4 2 + 1/2 02
The chemical oxidation process converts hazardous contaminants to non -hazardous or
less toxic compounds that are more stable, less mobile, and/or inert. The end products of
the oxidation of benzene, EDB, and DCA are water, CO2, chloride, bromide, and sulfate
ions. As a side benefit to the reaction, aerobic biodegradation of contaminants can benefit
from the presence of 02 released during the persulfate decomposition. Also, the sulfate
that results from the reaction of persulfate will be an electron acceptor via sulfate
reduction. That is, the sulfate will be consumed for bioconversion of petroleum
compounds (i.e., benzene) after the persulfate chemical oxidation mechanism ceases.
D. Injection Procedure and Equipment
The scope of the pilot test will involve the installation of one nested set of semi-
permanent injection points targeting both soil and groundwater at a depth of 14 to 30 feet
bgs, and the installation of a single monitoring well located approximately 6 feet from the
injection points. The injection points will be used to deliver a base activated sodium
persulfate solution. The purpose of using semi -permanent injection points is to mimic
and test the proposed approach for use in a full-scale system. The pilot study will be
performed within native soils (as opposed to the former tank pit fill areas) at the
approximate location shown on the attached figures. Note that the existing building will
need to be demolished prior to the pilot study. However, the exact location where the
pilot study wells will be field determined.
Assuming a radius of influence of 6 feet, the pilot test will encompass an area of
approximately 115 square feet. At a distance of 6 feet from the injection wells, a single
Page 3

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store #10275
Charlotte, NC
Nep
dIII 111 %1
3/4-inch diameter monitoring well will be installed with a screened interval that extends
across the saturated target zone, from approximately 20 to 30 feet bgs. This monitoring
well will be used to assess the effects of sodium persulfate on contaminant concentrations
detected in the groundwater. The nested set of injection wells will target both the
unsaturated and saturated soils. Screens will be positioned from approximately 14 to 19,
20 to 24, and 25 to 30 feet bgs. The purpose of nested injection points is to ensure that
proper vertical distribution of sodium persulfate solution occurs. The nested injection
points and the monitoring well will be installed with a Geoprobe® direct push drill rig
and completed as stickups with no protective casing. Each injection point and the
monitoring well will be constructed of 3/4 inch diameter PVC screens and risers. The
injection point will be constructed with a sand pack around the screened interval, and
sealed with a foot of granular bentonite and a cement grout to surface (see attached
schematic).
Based on an area of approximately 115 square feet, a target interval from 14 to 30 feet
bgs (unsaturated and saturated soils), and a total oxidant demand (TOD) value of 9.9g/kg,
approximately 1,705 pounds of sodium persulfate will be required to treat the target zone.
Mixed at a 20% solution by weight, approximately 1,000 gallons of solution will be
injected. The TOD value of 9.9g/kg was based on the highest TOD value reported from
analysis on site -specific soil samples collected during January 2006.
The attached figure shows a schematic of the injection setup. The sodium persulfate
solution will be injected using a trailer equipped with a Sandpiper double diaphragm
pump. The Sandpiper will pump the persulfate solution from a 500-gallon mixing tank to
the injection well through a series of hoses and valves. The valves are used to shut off or
restrict flow if required. The Sandpiper pump is operated with an air compressor and
controlled with an air regulator, which is mounted to the trailer. This allows the field
crew to control the injection pressure. The solution is injected at approximately 2 to 10
gpm, utilizing an injection pressure that may range from approximately 50 to 125 psi
(this will be field determined). The mixing tank is graduated and therefore flow rates can
be calculated by measuring the volume of solution over time, if required. The 1,000
gallons of solution will likely be equally distributed amongst the three injection wells and
based on the injection rate (2 — 10 gpm, to be field determined), the injection will take up
to approximately 8 - 9 hrs to complete.
E. Monitoring Plan
Prior to injection of persulfate, an electrical conductivity probe will be used to acquire
background levels of electrical conductivity through the target zone (i.e. from 14 to 30
feet bgs). This testing will be conducted at the injection location, prior to installation of
the injection wells. Once the injections have been completed, the vertical and lateral
distribution of the persulfate using the conductivity probe will be assessed. The electrical
conductivity measurements, in the presence of persulfate, will be elevated significantly
from background readings and therefore conductivity measurements vertically and
laterally will provide information on the radius of influence and the vertical distribution
of the persulfate.
Page 4

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store # 10275
Charlotte, NC
In addition to electrical conductivity testing, starch iodide test kits will be used to test
groundwater within the monitoring well. The starch iodide test is a quick and reliable
visual field technique to test for the presence of persulfate. Upon contact with persulfate,
the starch iodide solution will turn bright blue.
Also prior to the injection, a groundwater sample will be collected from the newly
installed monitoring well for analysis of VOCs (using USEPA Method 8260 and a North
Carolina certified laboratory), sulfate, and dissolved iron. In addition field parameters
including depth to groundwater, pH, oxidation-reduction potential (ORP), temperature,
dissolved oxygen (DO), and conductivity will also be measured. Post -injection
groundwater monitoring will be conducted approximately 24 hours and three weeks after
the injection is complete. During the 24-hr post -injection monitoring event, the
groundwater will be analyzed for sulfate, dissolved iron, depth to groundwater, pH, ORP,
temperature, DO, conductivity, and persulfate (using a starch iodide test kit)_ Since the
persulfate reaction is generally relatively slow it is not necessary to analyze the 24 hr
post -injection sample for VOCs, since it is likely that little to no reduction in
concentrations will have occurred by that time. The three week post -injection
groundwater sample will be analyzed for the same parameters as the 24-hr sample plus
VOCs.
F. Well Data
See attached information regarding wells located within the general area of the Old Store
LUST incident. As noted there are approximately 15 private water wells within
approximately 1,000 — 1,500 feet of the subject property. It is our understanding that
none of these private wells have been reported to be impacted by petroleum -related
compounds, and none of these private wells are located within or adjacent to the Old
Store LUST incident groundwater plume. In addition, the vast majority of these wells are
upgradient to crossgradient relative to the subject property. Specific information other
than what is attached regarding these private wells is not currently available.
One monitoring well, designated as MW-2, currently exists on the subject property. It is
believed that this well was installed as part of the initial investigation of the LUST
incident back in the early 1990's. It is constructed of 1-inch PVC and is approximately
19.5 feet deep. The depth of the screened interval is unknown. During January 2006, the
depth to water in this well was measured at 18.6 feet below the top of the casing, with
approximately one foot of water in the well. Apparently, this well was not installed deep
enough to adequately monitor the water table, therefore its use as a reliable and adequate
monitoring point is questionable. co�,p �ancepie°aaa
§o 0 ('ADO
en® Qyaa.aa d ��
G. Maps 143:-. 14473°°°�ij' o{
See attached.
Page 5
998 n i•
i 4
G d O
eaeaaattasa��':

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store #10275
Charlotte, NC
SUMMARY OF SOIL AND GROUNDWATER ANALYTICAL RESULTS

•
PARAMETERS /
METHOD
NORTH
CAROLINA
RESIDENTIAL
SOIL CLEANUP
LEVELS (SCLs)
NORTH
CAROLINA SOIL -
TO -
GROUNDWATER
MSCC
On -Site Old Store LUS"
SR-1
(16 ft)
SB-2
(10 ft)
SB-2
(18 ft)
VOCs / 8260
-
-
-
-
-
Acetone
1,564
3.0
ND
ND
ND
Brotssomethaue
no standard established
no standard established
ND
ND
ND
Methylene Chloride
85
0.02 '
ND
ND
ND
Benzene
22
0,0056
1:.:.:$1::.:.:.
ND
19
n-Buylbenzene
156
4.0
ND
ND
ND
sec-Butylbenzene
156
3.0
16
ND
10
Ethylbenzene
1,560
0.24
240
ND
150
Isopropyl benzene
1,564
2.0
'29
ND
21
Methyl-tert-buyl ether
156
0.92
ND
ND
ND
P-Isopropyltoluene
no standard established
no standard established
26
ND
19
Naphthalene
63
0.58
43
ND
28
n-Propylbenzene
156
2.0
95
ND
67
Toluene
3,200
7.0
260
ND
160 I
1,2,4-Trimethylbenzene
782
8.0
200
ND
210
1,3,5-Trimethylbenzene
782
7.0
120
ND
80
Xylenes (mixed)
32,000
5.0
510
ND
450
Other VOCs
see individual eanpcimds
see individual compounds
ND
ND
ND
Total VOCs
-
-
1,590
ND
1,214
TPH - DRO /8015
40 (used as an initial screening level)
1,800
ND
430
SVOCs / 8270
-
-
-
-
-
1-Methylnaphthaiene
no standard established
no standard established
NA
NA
NA
2-Methylnaphthalene
63
3
NA
NA
NA
Naphthalene
63
0.58
NA
NA
NA
Other SVOCs
see individual cravens
see individual compounds
NA
NA
NA
PCBs / 8082
we individual cm¢p ands
see individual compounds
NA
NA
NA
Notes:
All results are in mg/kg, unless otherwise noted
The above samples were collected by Clayton from January 16 through Januar/ 19, 2006 and were analyzed by
MSCC = Maximum Soil Contaminant Concentration
Bold cell equals concentration above the MSCC
Bold and shaded sell equals concentration above either the SCLs or the TPH - DRO initial sc veining level
ND = not detected et or above the method detection limit
NA = not analyzed
VOCs = volatile organic compounds
SVOCsasemi VOCs
TPH - DRO = total petroleum hydrocarbons - diesel range organics
PCBs = polychlorinated biphenyls

SUMMARY OF GROUNDWATER ANALYTICAL RESULTS
Proposed Wit green ^tare #10275
SEC of Beattles Ford Road and Sunset Road
Charlotte, North Carolina
Clayton Project No.: 99006-006118
PARAMETERS!
METHOD
VOCs! 8260
Benzene
n-Butylbenzene
tert-Butylbenzene
Chloroform
1,2-Dibromoethane (EDB)
1,2-Dichloroethane
Diisopropyl ether
Ethylbenzene
Isopropyl benzene
p-Isopmpyltoluene
Methylene Chloride
Methyl -text -butyl ether
Naphthalene
n-Propylbenzene
Styrene
Toluene
1,2,4-Trimethylbenzene
1,3, 5-Trimethylbenzene
Xylenes (mixed)
Other VOCs
Total VOCs
TPH - DRO / 8015
Lead / 3030C
PCBs 18082
NORTH CAROLINA NORTH CAROLINA
2L GROUNDWATER GROSS
QUALITY CONTAMINATION
STANDARDS LEVELS (GCLs)
(GWQS)
0,001
0.07
0.07
0.00000019
0.0000004
0.00038
0.07
0,029
0.07
no standard established
0.005
0.20
0.021
0.07
0.0001
1.0
0.35
0.35
0.53
sec individual compounds
no standard established
0.015
see individual compounds
5
6.9
15
0.19
0.05
0.38
70
29
25
no standard established
5
200
15.5
30
100
257.5
28,5
25
87.5
see individual compounds
no standard established
15
see individual compounds
On -Site Old Stare LUST Incident (5040 Beatties Ford Road)
SB-1
ND
ND
ND
I.2
23
0.10
ND
ND
ND
0.33
0.21
ND
18
13
0.27
11
ND
55
11
NA
NA
SB-2
0.054
0.21
ND
0.27
2.9
0.12
ND
ND
ND
0.25
0.28
ND
33
1.5
0.34
13
ND
74
14
ND
_ NA
SB-4
0.018
0.016
ND
0.014
ND
ND
ND
0.019
0.029
0.011
ND
ND
0.018
0.046
ND
0.064
0.20
0.15
0.22
ND
0.8
0.58
NA
NA
SB-6
ND
ND
ND
0.56
2.5
0.09I
ND
ND
ND
0.55
0.18
ND
28
1.1
0.24
11
ND
66
8.3
NA
NA
Notes:
All results are in mgfl, unless otherwise nosed.
The above samples were collected by Clayton from January 16 through January 18, 2006 and were analyzed by Pace Analytical.
Bold cell equals concentration above the GWQS
Bold and shaded cell equals concentration above the GCL
ND = not detected at or above the method detection limit
NS = not sampled due to insufficient sample quantity
NA = not analyzed
VOCs = volatile organic compounds
TPH - DRO =total petroleum hydrocarbons - diesel range organics
PCBs = polychlorinated bipheayls
SB7
13
0.014
ND
ND
ND
ND
ND
3.0
0.076
ND
ND
0.05
0.58
0.14
0.012
9.1
1.5
0,17
I3
ND
29
6.0
NA
NA
SB-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0088
NA
MW-2
3.9
0.11
0.38
ND
0.13
ND
3.4
0.20
ND
0.22
ND
0.24
0.41
ND
13
2.7
3.0
17
ND
45
NS
NS
NA
On -Site Potential Historical
Maintenance and Repair
Operations (5040 Beanies
Ford Road)
SB-I0
ND
ND
ND
ND
ND
ND
ND
ND
0.002
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.002
0.32
ND
ND
SB-11
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NI)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.34
NA
ND
SB-12
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.27
NA
ND
On -Site Septic
System (5006 and
5040 Scotties
Ford Road)
SB-13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
NA
SB-I4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
NA
Adjacent
Automotive
Repair Facility
(5006 Beanies
Ford Road)
SB-16
0.I4
ND
ND
ND
ND
ND
0.012
ND
0.018
ND
ND
1.7
0.028
ND
ND
ND
ND
ND
0.014
ND
1.9
I.3
NA
NA
5B-17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.002
ND
ND
ND
ND
ND
ND
ND
0.002
ND
NA
NA
Potential
Chlorinated
Solvent
Groundwater
Contamination
SB-19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NA
NA
NA

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store # 10275
Charlotte, NC
FIGURES AND SCHEMATIC

PORTION OF 7.5—MINUTE SERIES (TOPOGRAPHIC) MAP
UNITED STATES DEPARTMENT OF THE INTERIOR
GEOLOGICAL SURVEY
DERITA. NORTH CAROLINA
DATE: 1993
FIGURE A-1
SITE
LOCATION MAP
GROUP SERVICES
PROPOSED WALGREEN STORE
SEC OF BEATTIES FORD AND SUNSET ROAD
CHARLOTTE, NORTH CAROLINA
1
CLAYTON PROJECT NO:
1 6--061 18.00
SBBH DEVELOPMENT, LLC
c/o TRIBEK PROPERTIES, INC.

C7%
SB-
LEGEND
SOIL BORING
MONITORING WELL
{ GEOLOGIC
CROSS-SECTION
LOCATION
SUBJECT PROPERTY
BOUNDARY
APPROXIMATE SCALE
30 0 30 60
9D
Figure 2
Site Map Showing Approximate
Location of Sodium Persulfate
Pilot Study
01
'S�LOCA
SB-10
SB-I 1
SB-12
K�
i
',
caN�
��q,sk_p\SBf 1910
SB-13
+SB-1
�IO2.
ESEMEM Clayton Group Services
.I 11"' I'ptius Ca+Ym.r
c
E
N
T
SB-16
SBBH Development, LLC
c/o Tribek Properties
Proposed Walgreen Store #10275
TSEC of Beatties Ford Road and Sunset Road
E Charlotte, North Carolina
Project Na. 99,305-00611S
Last Rorisiort
Aupsf 2,2006

2
�SS
il5SB-11
SB 8
tvp
\ 976
\
5i: b esis�o
•SB-13
diSB-1 4,.
Qo
41,0,0
LEGEND
-t SOIL BORING
MONITORING WELL.
----- ESTIMATED EXTENT OF
GASOLINE -IMPACTED
SOIL WHERE ONE OR
MORE VOCs EXCEED
NCDENR's RESIDENTIAL
SOIL CLEANUP LEVELS
----- SUBJECT PROPERTY
BOUNDARY
— ESTIMATED TOTAL
EXTENT OF
GASOLINE -IMPACTED
SOIL, BASED ON FIELD
OBSERVATIONS AND
ANALYTICAL RESULTS
APPROXIMATE SCALE
30 _ OE 30 60
0
t�
SB/19
400
AQS SGQy
of
t 00199Qom.
O1r
L
SB-17
Figure 3Proposed
Estimated Extent of
Gasoline -Impacted Soil
c �U Yfq
H
='unif
l o
Clayton Group Services
C
I SBBH Development, LLC
E clo Tribek Properties
14
T
S Walgreen Store #1027S
T SEC of Beatties Ford Road and Sunset Road
E Charlotte, North Carolina
Emu=
I rsur.,= 1
Project No. 99006-D06118Last Revision
Aug.. 1,2 06
airs. Cwurygr

SB-
• 014
\ IsIlleadiPD \\,613-7
„so „,;,.+.
\1,
\(1) \ `�
tSB 8
LEGEND
4_ SOIL BORING
MONITORING WELL
----- ESTIMATED EXTENT OF
GASOLINE -IMPACTED
GROUNDWATER
WHERE ONE OR MORE
VOCs EXCEED
NCDENR's GROSS
CONTAMINATION
LEVELS
---- SUBJECT PROPERTY
BOUNDARY
--- ESTIMATED TOTAL
EXTENT OF
GASOLINE -IMPACTED
GROUNDWATER, BASED
ON FIELD OBSERVATIONS
AND ANALYTICAL
RESULTS
APPROXIMATE SCALE
30 0 30 60
90
oP
.OES
SB-17
cP 4
A-161'(S15t;-°
Fl e 4
Estimated Extent of
Gasoline -Impacted Groundwater
P
uV
v�1
ED
T
+6:u REJLu1,
Clayton Group Services
Y p
-[ru..�+'.,umc y
L
E
N
r
SBBH Development, LLC
c/o Tribek Properties
S
Proposed \Valgrcen Store #10275
T SEC ofBeatties Ford Road and Sunset Road
E Charlotte, North Carolina
Project No. 99006006118 fast Revitiaa
Avert 1,1006

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— 795
1' 4 1I2 116 ' 210 , 214 218
312 , 316 , 410 , 412 414
418
512
516 60 614 51a 712 716 810
84 818
92 916
160 164 168 112 116 120 114 1ZB 132 790
LEGEND
▪ BORING TERMINATION
z
GROUNDWATER ELEVATION
(APPROXIMATE)
®� ESTIMATED EXTENT OF GASOLINE -IMPACTED
GROUNDWATER WHERE ONE OR MORE VOCs
EXCEED NCDENR's GROSS CONTAMINATION LEVELS
FILL MATERIAL
SILTY CLAY
CLAYEY SILT
NOTES:
1. CROSS-SECTION SCALE:
HORIZONTAL SCALE 1" - 16'
VERTICAL SCALE 1" = 16'
VERTICAL EXAGGERATION = 0
2. THE GROUND SURFACE ELEVATIONS WERE APPROXIMATE BASED ON
"DEMOLITION PLAN' PROVIDED BY PM ENGINEERING, INC. DATED MAY 1, 2006.
3. STATIC WATER LEVELS APPROXIMATED.
4. SEE FIGURE 2 FOR CROSS-SECTION LOCATION.
5. CROSS SECTION IS BASED ON BEST PROFESSIONAL JUDGMENT USING AVAILABLE
DATA. THE GEOLOGY PRESENTED IN THIS CROSS SECTION WAS GENERALIZED TO
ILLUSTRATE THE MAJOR LITHOLOGIC UNITS AT THE SITE, THE THICKNESS AND
EXTENT OF THE LITHOLOGIC UNITS ARE APPROXIMATED AND GEOLOGIC
CONTACTS BETWEEN BORING LOCATIONS ARE INFERRED.
Clayton Group Services
Bureau Veritas Company
CHECK BY KW
DRAWN BY GB
DATE 08-02-06
SCALE AS SHOWN
CAD NO.
GEOLOGIC CROSS-SECTION
PROPOSED WALGREEN STORE #10275
SEC OF BEATTIES FORD ROAD AND SUNSET ROAD
CHARLOTTE, NORTH CAROLINA
dBrfU,.R E'AfU
1133311112131
FIGURE
5
PROJ NO. 99006-006118

IS s 1 LLOW OR01H]WATST 11CH1CMOI WELL
(90.25) GROUNDWATER ELEVATION
0
cc
rn
FOliMER GAS STATION
I
I.IW_1
(902)
MW-2
(90.25)
/
/
® 04)
/
BEATT1ES FORD ROAD
LEGEND .�
— C3ROLNDWAT I ISOCONTOUR LIE
0
SCALE- 1 = 30'
0
15
30
GEO—ENVIRONMENTAL
CONSULTANTS, INC.
GEOTECHNICAL/ENY1R011L1ENTAL ENGINEERS & SCIENTISTS
11704 REAMES ROAD. CHARLOTTE. NC 28269-7637
PHONE [phone] FAX [phone]
PROJECT J: 95662
OAIE: I/9/97
PRG.(C1 MGR: D.A.S.
DESIGN OY:
DRAM 8: K.A.S.
OLD STORE
5040 BEATIIES FORD ROAD
CHARLOTTE, NORTH CAROLINA
SCALE: I IN.p30 FEEL
GRO(JNDWATIai CONTOUR MAP
RGUFE
2

TO INJECTION POINT -
EXTENSION TO CONNECT WELL
CASING TO INJECTION HOSE
1
GROUT
TO GROUND]
SURFACE
BENTONITE
1 FT. ABOVE SAN ACK
SAND PACX
1 FT. ABOVE SCREEN
x 2' >t 2' TEE
2' v r REDUCING BUSHING
RETURN TO TANK
i" CAM & GROOVE HOSE CONNECTORS
i TRUE UNION BALL VALVE
OUTLET CONNECTION DETAIL
5 FT. SCREEN
INJECTION WELL
}' NYLOB E FLEXIBLE PVC
INJECTION HOSE
SEE OUTLET CONNECTION OETAI
/I
N. TRAILER BED J
NYLOBRADE FL£NIBLE PVC
PRESSURE RELIEF HOSE
50O GALLON
POLYPROPYLENE
TANK
NOTE: ALL PIPE FITTINGS ME NPT SCH. 80 PVC UNLESS
OTHERWISE SPECIFIED.
EQUIPMENT MOUNTED ON TRAILER
/
INJECTION EQUIPMENT SCHEMATIC
REDOX TECH, LLC
1006A MORRISVILLE PARKWAY
MORRISVILLE, NC 27560
JANUARY 17. 2008
IsrALE
NOT TO SCALE

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store # 10275
Charlotte, NC
SOIL BORING LOGS

02.10.2005 S:tOlficeAATLEMS12006 FY1Projects116-06118.00A11 Walgreen, Charlotte, NC\Phase laboring Iogs1S9-1.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened !Menial
: 1/17/06
: David Wagner
: Regional Probing
: Geoprobe
: Fine slag
: 2-Inches
: 28'
: 1" PVC
: 0-18 feet
: 18-28 feet
Date Measured : 1/18106
TOC Elevation : 94.1
Ground Elevation : 93.6
Depth to Groundwater : 17.7
Depth to NAPL : NA
NAPLThickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PO did not detect organic
: vapors
Depth
in
Feet
a)
E
m
E
a
a
Time Collected
DESCRIPTION
co
0
U
o-
0
2-
4-
6--
8-
10-
12-
14—
NS
2
1
8
20
290
200
250
16—n 650
20—
_
22--
24 —
26 —
28
550
1200
1100
850
NS
Ns
Fine gravel (slag) with silt and sand.
FILL
Light brown to brown silt with little clay, moist.
Very slight gasoline -like odor
Slight to moderate gasoline -like odor.
Moderate gasoline -like odor
Moist to wet, moderate gasoline -like odor
Wet, moderate gasoline -like odor
ML
24-28 ft No recovery of sample.
End of boring at 28 ft bgs.
diE11 JII III Iliiillll III III W IlilitEll li! LIE ILE Ili TIE III III III III 11!!f 111 hit III
Casing Interval
Screened Interval
IVECEEICIal
LOG OF BORING SB-1
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1016ce&ATLEMS12005 FY1Projectsli6-06118.00.011 Watgreen, Charlotte, NC1Phase lilbaring iogs\SB-2.bor
Date installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened interval
: 1/17/06
: David Wagner
: Regional Probing
: Geoprobe
: Fine Slag
: 2-inches
: 28'
: 1" PVC
: 0-17 feet
: 17-27 feet
Date Measured
TOC Elevation
Ground Elevation
: 1/18/06
94.2
: 93.6
Depth to Groundwater :17.8
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: P1D did not detect organic
: vapors
Depth
in
Feet
a
E
rn
E
D.
o.
Time Collected
DESCRIPTION
U
0
2-
4-
6-
8-
10-
12-
14-
16-
18-
20 —
22 ---
24-
26--
28
NS
3
3
7
8
34
20
13
75
40
1109
1400
5013
140
NS
NS
Fine gravel (slag) with silt and sand.
Light brown silt with trace clay, moist.
Very slight gasoline -like odor
Slight gasoline -like odor
Light brown to light gray silt with little to some day,
moist to wet, moderate gasoline -like odor.
Moderate gasoline -like odor.
ML
24-28 ft. No recovery of sample.
End of boring at 28 ft bgs.
Casing Interval
Screened Interval
LOG OF BORING SB-2
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02.1 D-2006 S:1OfcelATLEMS.2006 FY\Prajecls\16-06116.00.011 Walgreen, Charlotte, NClPhase ilkhadng Iogs1SB-3,bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1/17/06
: David Wagner
: Regional Probing
Geoprobe
: Fine slag
: 2-inches
: 20'
: NA
: NA
:NA
Date Measured
TOC Elevation
Ground Elevation
Depth to Groundwater
Depth to NAPL
NAPL Thickness
Weather while Drilling
: NA
:NR
:NR
: Not measured
: NA
:NA
: Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
Depth
in
Feet
E
n
0.
Time Collected
DESCRIPTION
1
12
14
16
18
20
=
..
=
?—
3
l—
=
=
i=
8=
=
=
-
NS
ND
ND
ND
7
10
7
Light brown to brown silt with little clay and trace
medium gravel, moist 1 _ 2 inches of fine slag at
surface.
Grades to brown with trace clay, little fine to coarse
sand, Lense of fine to medium slag also present at
approximately 4 feet
Grades to some clay with trace fine to coarse sand and
trace fine to medium gravel, very slight gasoline -like
odor.
FILL
Light brown to brown silt with little clay, moist, slight to
moderate gasoline -like odor.
0
850
_
550
ML
650
-
450
End of boring at 20 ft. bgs.
LOG OF BORING SB-3
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1O16ce1ATLEMS12006 PAProjects116-06118.00,011 Walgreen, Charlotte, NCPPhase I1lbaring logs4SB-4,hor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
1/17/06
: David Wagner
: Regional Probing
: Geoprobe
: Fine slag
: 2-inches
: 28'
: 1" PVC
: 0-18 feet
: 18-28 feet
Date Measured : 1/18/06
TOC Elevation : B4.6
Ground Elevation : 94.1
Depth to Groundwater : 18.0
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
: Vapors
Depth
in
Feet
E
m
07
E
0.
0
0
Time Collected
DESCRIPTION
0
co
0
2-
4-
6-
8-
14-
16-
20 —
22 —
24 —
26 ---
28
NS
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
ND
\Fine gravel (slag) with silt and sand.
Light brown to brown silt with little clay, moist.
Light brown to light gray.
Trace clay
Light brown to beige with little clay and moist to wet.
Light brown to light gray, moist
End of boring at 28 ft. bgs.
FILL
ML
JLuI lu l]ETEI IIl rn[111Fr RI TUI
Casing Interval
Screened Interval
LOG OF BORING SB-4
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2008 5:1Dibce'ATLEM512006 FY\Projecls116-06118.00.011 Walgreen, Charlotte, NC\Phase laming logsl$B-5,bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1/17100
: David Wagner
: Regional Probing
: Geoprobe
: Fine slag
: 2-inches
: 20'
:NA
:NA
:NA
Date Measured : NA
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : Not measured
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PIO did not detect organic
: vapors
Depth
in
Feet
E
d
a
0-
Time Collected
DESCRIPTION
U
co
0
2-
4-
6-
8-
10�
12-
14
16-
20
1❑
NS
5
8
152
43
695
1260
1415
1475
1200
1020
Light brown to dark b
and silt, and little fine
inches of fine slag at
rown silt with little to some gravel
to coarse sand, moist. 1 - 2
surface.
FILL
Light brown to brown
gasoline -like odor.
silt with some clay, moist, slight
Little clay, slight to moderate gasoline -like odor.
Moderate gasoline -like odor.
End of boring at 20 ft. bgs.
ML
MIZIGEMLEI
LOG OF BORING SB-5
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:IOffrca4ATLEMS42006 FYIProlects116-06118.00.011 Walgreen, Charlotte, NC4Phase II\boring Iogs4SB-6.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1/17/06
: David Wagner
: Regional Probing
Geoprobe
: Fine slag
: 2-inches
: 28'
: 1" PVC
: 0-17 feet
: 17-27 feet
Date Measured : 1/18/06
TOC Elevation : 95.2
Ground Elevation : 94.6
Depth to Groundwater : 18.7
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny. 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
Depth
in
Feet
w
E
m
to
E
a
a
Time Collected
DESCRIPTION
U
❑
❑
0
2-
4-
6-
8-
10-
12-
14-
16-
18-
20 —
22 —
24-
26-
28
0
NS
5
30
70
15
220
550
1300
800
1100
500
NS
NS
NS
NS
Light brown to dark brown clay with little to some gravel
and silt, and little fine to coarse sand, moist. 1 - 2
inches of fine slag at the surface.
FILL
Light brown to brown silt with some clay, moist, slight
gasoline -like odor.
Little clay, slight to moderate gasoline -like odor.
Moderate gasoline -like odor.
Moderate gasoline -like odor.
Moderate gasoline -like odor.
ML
20-28 ft bgs No recovery
End of boring at 28 ft. bgs.
l! I I I r D rl m m I rfl T
Casing Interval
Screened Interval
LOG OF BORING SB-6
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2005 S:10ffice1ATLEMS12006 PAProjecls116-06116.00.011 Walgreen, Charlotte, NC\Phase Illboring logs\SB-7.bor
Date Installed :1/17/06
Logged By : David Wagner
Drilling Company : Regional Probing
Drilling Methods : Geoprobe
Through Surface : Fine slag
Borehole Diameter : 2-inches
Boring Terminated at : 28'
Sampling Point : 1" PVC
Casing interval : 0-16 feet
Screened Interval : 16-26 feet
Date Measured : 1/18/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 18.9
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR : Not Recorded
NA : Not Applicable
bgs : Below Ground Surface
NS : Not Sampled
ND : PID did not detect organic
: vapors
Depth
in
Feet
E
R
Time Collected
DESCRIPTION
rn
0
to
0
2-
4-
6-
6-
10-
12-
14-
16-
18-
20-
22 —
24 —
26-
28
NS
4
10
121
61
200
350
570
520
340
550
820
700
700
Light brown to dark brown clay with little to some gravel
and silt, and little fine to coarse sand, moist. 1 - 2
inches of fine slag at the surface.
FILL
Light brown to brown silt with some clay, moist, slight
gasoline -like odor.
Little to some clay.
Light brown to light gray clay with some silt, moist, slight
to moderate gasoline -like odor.
Light brown to light gray silt with little Gay.
Moist to wet and moderate gasoline -like odor.
Slight to moderate gasoline -like odor.
Wet
Wet to saturated and slight to moderate gasoline -like
odor.
End of boring at 28 ft. bgs.
ML
CL
ML
Casing Interval
Screened Interval
LOG OF BORING SB-7
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1Ofilc6\ATLEMS12006 FYtiProjectsIt6-06118.03,011 Walgreen, Charlotte, NCIPhase fRboring Iogs1S13-8.bor
Date Installed : 1/17/06
Logged By : David Wagner
Drilling Company : Regional Probing
Drilling Methods : Geoprobe
Through Surface : Fine slag
Borehole Diameter : 2-Inches
Boring Terminated at : 24'
Sampling Point : 1" PVC
Casing Interval : 0-14 feet
Screened Interval : 14-24 feet
Date Measured : 1/18/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 8,6
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR : Not Recorded
NA : Not Applicable
bgs : Below Ground Surface
NS : Not Sampled
ND : PIO did nal detect organic
: vapors
Depth
In
Feet
E
4
0
4.
Time Collected
DESCRIPTION
U
cn
D
0
2-
4-
6-
8-
14-
16-
18-
20 —
22 —
24
T
NS
ND
ND
ND
ND
NO
ND
ND
ND
ND
ND
ND
ND
Light brown to dark brown clay with little to some gravel
and silt, and little fine to coarse sand, moist. 1 - 2
inches of fine slag at the surface.
FILL
Light brown silt with little to some clay, moist.
Little clay.
Little to some clay.
Little clay.
Moist to wet.
End of boring at 24 ft. bgs.
ML
Casing Interval
Screened Interval
LOG OF BORING SB-8
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
1/16/05
David Wagner
Regional Probing
Geoprobe
Fine slag
2-Inches
28'
1" PVC
0-15 feet
15-25 feet
Date Measured : 1/18/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 15.7
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 50 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Nat Recorded
: Not Applicable
;Below Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
02-10-2006 5:1Offlce ATLEMS12006 FY1Prnjeds116-06118.00.011 Walgreen, Charlotte, NCSPhase II horing CogsLSB-10.bcr
Depth
in
Feet
E
0.
0
0
Time Collected
DESCRIPTION
co
0
N
U
0
0
2_
4--
6--
8-
14-
16-
18-
20 —
22 —
24--
26-
28
NS
ND
ND
ND
ND
8
4
0.5
4
5
0.5
1
0,5
0.5
sFine gravel (slag) with silt and sand.
Brown clay with little to some silt, moist,.
Light brown to light gray silt with trace to little clay,
moist, slight gasoline -like odor.
Very slight gasoline -like odor.
Some Clay.
Trace clay.
Trace to little clay and very slight gasoline -like odor,
moist.
Some clay and wet to saturated.
0.5 End of boring at 28 ft bgs.
FILL
•
CL
ML
i
Casing Interval
Screened Interval
LOG OF BORING SB-10
(Page 1 of 1)
Proposed Walgreen Stare #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1Office1ATLEMSL2006 FYYPrajects116-06118.00.011 Welgreen. Cherla c, NCIPhase 01baring Iogs1SB-11.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1115106
: David Wagner
: Regional Probing
: Geoprobe
: Fine slag
: 2-Inches
: 27'
: 1" PVC
: 0-17 feet
: 17-27 feet
Date Measured
TOG Elevation
Ground Elevation
: 1/1B106
:NR
:NR
Depth to Groundwater : 12.9
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 50 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: AID did not detect organic
: vapors .
Depth
in
Feet
E
a.
4
0
Time Collected
DESCRIPTION
0)
U
0
1-
2-
3-
4-
5-
6-
7-
8-
9-
20 —
21-
22-
23-
24-
25-
26�-
27
NS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
\Fine gravel (slag) with silt and sand.
Brown to dark brown clay with some silt, moist.
Light brown.
Light brown to light gray silt with trace clay, moist.
Moist to wet.
End of boring at 27 ft. bgs.
FILL
CL
ML
Casing Interval
Screened Interval
LOG OF BORING SBA 1
(Page 1 of 1)
Proposed Waigreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:10Rce\ATLEMS12006 FY\PrcJeats116-06118,00,011 We}green, Charlotte, MC1Phase IIlharing Iags1SB-12.bar
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
1/17/06
David Wagner
Regional Probing
Geoprobe
Fine slag
2-inches
24'
1" PVC
0-14 feet
14-24 feet
Date Measured
TOC Elevation
Ground Elevation
: 1/18/06
:NR
:NR
Depth to Groundwater : 4.6
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
Not Sampled
PID did not detect organic
: vapors
Depth
In
Feet
5)
w
d
E
ro
07
E
4
Q.
0
Time Collected
DESCRIPTION
0
kn
D
0
2-
4-
6-
8-
10-
12-
14-
16-
18-
20 —
22---
24
0
NS
ND
ND
9
50
110
5
5
90
20
30
10
10
Fine gravel (slag) with silt and sand.
FILL
Light brown to brown silt with little to some clay, moist.
Light brown and very slight petroleum-fike odor.
Light brown to light gray and some clay.
Little clay.
Wet to saturated
Moist to wet
Little to some clay and wet to saturated.
End of boring at 24 ft bgs.
ML
5i LEIIII,I IIIIIII !i!!illlRIIII!iELLIL.L!!'i LI Et!I} Ill Ll Li it Id In LE„r
Casing Interval
Screened Interval
LOG OF BORING SB-12
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02.1D-2006 S:1OfflcelAThEMS12006 FYYProJectsl16-06118.00.011 Wargreen, Charlotte. rlC4Phase Illbcring Iogs1SB-13.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1116106
: David Wagner
: Regional Probing
: Geoprobe
: Coarse slag
: 2-inches
:19'
: 1" PVC
:NA
:NA
Date Measured : 1/10/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 10.3
Depth to NAPL : NA
NAPLThickness : NA
Weather while Drilling : Partly sunny, 50 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
Depth
In a
Feet
to
E
a
O
0
Time Collected
DESCRIPTION
2
0
0
1—
2-
3-
4-
5-
6--
a
7-
8—
9-
10�n
11-
12--
13-
14-
15:
16-
17-
18-
19 "
NS
NS
ND
ND
ND
ND
ND
ND
ND
ND
Fine to coarse gravel and cobbles (slag) with silt and
sand.
FILL
Brown clay with some silt, moist.
Little to some silt.
Wet
Light brown to light gray, saturated.
Moist.
Some silt and moist to wet.
Light brown to brown silt with tittle clay, moist..
End of boring at 19 ft. bgs.
CL
ML
Casing Interval
Screened Interval
LOG OF BORING SB-13
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:IOSice1ATLEMSI2006 FYFPro;edsll6-06118.0D,011 Walgreen, Charlotte, NCIPhase Ellbodng I1405B-14.bo4
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1l18l06
: David Wagner
: Regional Probing
Geoprobe
: Dirt parking area
: 2-inches
: 24'
: 1" PVC
: 0-14 feet
: 14-24 feet
Date Measured : 1l18/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 14.1
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
Below Ground Surface
: Not Sampled
PID did not detect organic
vapors
Depth
In
Feet
E
0.
Time Collected
DESCREPTION
U
rn
0
2-
4-
6-
8--
10-
12-
14-
16-
18-
20-
22 —
24
f
NS
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NS
NS
Brown silt with little to some clay, moist.
Little clay.
Light brown to brown.
Light brown and moist to wet.
Wet.
ML
20-24 ft bgs. Not sampled.
End of boring at 24 ft bgs.
ill IIIIli I H III III Itl i l l IIRII HI II! IIr1II 111 Ill IIIlII IIrfII III 111111111111 II ID II! IIIIIIII
Casing Interval
Screened Interval
LOG OF BORING SB-14
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

e
0
m
9
0
co
N
2
t
m
c
0
0
0
QwQ
e
.
N
0
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Intervat
Screened Interval
: 1/18/06
: David Wagner
: Regional Probing
: Geoprobe
: Dirt access mad
: 24nches
: 24'
: 1" PVC
: 0-14 feet
: 14-24 feet
Date Measured : 1/18/06
TOC Elevation : NR
Ground Elevation : NR
Depth to Groundwater : 13.3
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny. 55 degrees
Abbreviation key
NR : Not Recorded
NA : Not Applicable
bgs ; : Below Ground Surface
NS ' : Not Sampled
NO : PID did not detect organic
: vapors
Depth
in
Feet
0
2-
4-
6-
8-
10-
12-
14-
16-
16
20 —
22-
24
0
t11
E
m
rn
uJ
E
a
a
n
a
NS
2
3
2
4
e
2
2
4
25
3
NS
NS
Time Collected
DESCRIPTION
Dark brown to brown sift, sand and gravel.
Light brown to light gray day with little to some silt,
moist, very slight petroleum and gaotine-like odor.
Some silL
Light brown to light gray silt with little to some clay,
moist.
Light brown and trace to little clay.
Light brown to light gray and little day, very slight
gasoline -like odor.
Moist to wet and very slight gasoline -like odor.
U
T
0,
0
co
FILL
CL
ML
20-24 ft bgs. Not sampled.
End of boring at 24 ft bgs.
LOG OF BORING SB-16
(Page 1 of 1)
Z
Casing interval
Screened Interval
Proposed Walgreen Store #10275
SEC of Beanies Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1Office1ATLEMSti2006 FriPrajects116-06116.01011 Wafgreen, CharIon, NCLPhase Illboring Iogs1S13-17.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened Interval
: 1N 8106
: David Wagner
: Regional Probing
: Geoprobe
: Dirt access road
: 2-inches
: 24'
1" PVC
: 0-14 feet
: 14-24 feet
Date Measured : 1118106
TOC Elevation : NR
Ground Elevation ; NR
Depth to Groundwater : 9.0
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny. 55 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
vapors
Depth
In
Feet
4
a
a
Time Collected
DESCRIPTION
0)
U_
1
0
2-
4-
6— n
8-
10-
12--
14-
16-
18-
20 —
22—
24�-
NS
ND
ND
1
ND
ND
ND
ND
ND
ND
ND
NS
NS
Dark brown to brown silt, sand and gravel.
Light brown to light gray clay with little to some silt,
moist.
Some silt.
Light brown to light gray silt with little clay, moist.
Little to some clay.
Wet to saturated and little clay.
FILL
CL
ML
20-24 ft. bgs. Not sampled.
End of boring at 24 ft bgs.
]f III Irr ID IIT71110 II111l 01 Lr II4 al III 1!IWITT
Casing Interval
Screened Interval
LOG OF BORING SB-17
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

02-10-2006 S:1Ofc&ATLEM512006 FYtiP u1ects116-06118 00.011 Walgreon, Charlotte, NC1Phese II%bodng Iogs\SB-19.bor
Date Installed
Logged By
Drilling Company
Drilling Methods
Through Surface
Borehole Diameter
Boring Terminated at
Sampling Point
Casing Interval
Screened interval
: 1/16/06
: David Wagner
: Regional Probing
: Geoprobe
: Coarse slag
: 2-Inches
: 20'
: 1" PVC
: 0-14 feet
: 14-1 B feet
Date Measured
IOC Elevation
Ground Elevation
: 1/18106
:NR
:NR
Depth to Groundwater :4.7
Depth to NAPL : NA
NAPL Thickness : NA
Weather while Drilling : Partly sunny, 50 degrees
Abbreviation Key
NR
NA
bgs
NS
ND
: Not Recorded
: Not Applicable
: Below Ground Surface
: Not Sampled
: PID did not detect organic
: vapors
Depth
in
Feet
aaii
E
as
E
0
Time Collected
DESCRIPTION
to
U
0
S
0
2—
4-
8�
10-
12-
14—
16-
18J
20
NS
ND
ND
ND
ND
ND
ND
ND
ND
ND
NS
Fine to coarse gravel and cobbles (slag) with silt and
sand.
FILL
Brown Gay with little to some silt, moist.
Light brown to brown.
Little silt
Light brown to light gray and little to some silt.
Wet
Some silt and saturated.
End of boring at 20 ft. bgs.
CL
Z
Casing Interval
Screened Interval
LOG OF BORING SB-19
(Page 1 of 1)
Proposed Walgreen Store #10275
SEC of Beatties Ford Road and Sunset Road
Charlotte, NC

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store #10275
Charlotte, NC
MSDS FOR SODIUM PERSULFATE

MATERIAL SAFETY DATA SHEET
Sodium Persulfate
MSDS Ref. No.: 7775-27-1
Date Approved: 02/22/2005
Revision No.: 11
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CPR 1910.1200; the Canada's Workplace Hazardous Materials Information System (WHMIS)
and, the EC Directive, 2001/58/EC.
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME:
SYNONYMS:
GENERAL USE:
MANUFACTURER
FMC CORPORATION
Active Oxidants Division
1735 Market Street
Philadelphia, PA 19103
[phone] (General Information)
Sodium Persulfate
Sodium Peroxydisulfate; Disodium Peroxydisulfate
Polymerization initiator. Etchant and cleaner in manufacture of
printed circuit boards. Booster in hair bleaching formulations in
cosmetics. Secondary oil recovery systems as a polymerization
initiator and a gel breaker.
EMERGENCY TELEPHONE NUMBERS
[phone] (CHEMTREC - U.S.)
[phone] (Medical - Call Collect)
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
• White, odorless, crystals
• Oxidizer.
• Decomposes in storage under conditions of moisture (water/water vapor) and/or excessive heat causing
release of oxides of sulfur and oxygen that supports combustion. Decomposition could form a high
temperature melt. See Section 10 ("Stability and Reactivity").
POTENTIAL HEALTH EFFECTS: Airborne persulfate dust may be irritating to eyes,
nose, lungs, throat and skin upon contact. Exposure to high levels of persulfate dust may cause difficulty in
breathing in sensitive persons.
Page 1 of 9

Sodium Persulfate (7775-27-1)
Date: 02/22/2005
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS#
Wt.%
EC No.
EC Class
Sodium Persulfate
7775-27-1
>99
231-892-1
Not classified as hazardous
4. FIRST AID MEASURES
EYES: Flush with plenty of water. Get medical attention if irritation occurs and persists.
SKIN: Wash with plenty of soap and water. Get medical attention if irritation occurs and persists.
INGESTION: Rinse mouth with water. Dilute by giving 1 or 2 glasses of water. Do not induce
vomiting. Never give anything by mouth to an unconscious person. See a medical doctor immediately.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists,
contact a medical doctor.
NOTES TO MEDICAL DOCTOR: This product has low oral toxicity and is not irritating to
the eyes and skin. Flooding of exposed areas with water is suggested, but gastric lavage or emesis
induction for ingestions must consider possible aggravation of esophageal injury and the expected absence
of system effects. Treatment is controlled removal of exposure followed by symptomatic and supportive
care.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Deluge with water.
FIRE / EXPLOSION HAZARDS: Product is non-combustible. On decomposition releases
oxygen which may intensify fire. Presence of water accelerates decomposition.
FIRE FIGHTING PROCEDURES: Do not use carbon dioxide or other gas filled fire
extinguishers; they will have no effect on decomposing persulfates. Wear full protective clothing and self-
contained breathing apparatus.
FLAMMABLE LIMITS: Non-combustible
SENSITIVITY TO IMPACT: No data available
Page 2 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
SENSITIVITY TO STATIC DISCHARGE: No't available
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: spilled material should be collected and put in approved DOT container and
isolated for disposal. Isolated material should be monitored for signs of decomposition (fuming/smoking).
If spilled material is wet, dissolve with large quantity of water and dispose as a hazardous waste. All
disposals should be carried out according to regulatory agencies procedures.
7. HANDLING AND STORAGE
HANDLING: Use adequate ventilation when transferring product from bags or drums. Wear
respiratory protection if ventilation is inadequate or not available. Use eye and skin protection. Use clean
plastic or stainless steel scoops only.
STORAGE: Store (unopened) in a cool, clean, dry place away from point sources of heat, e.g.
radiant heaters or steam pipes. Use first in, first out storage system. Avoid contamination of opened
product. In case of fire or decomposition (fuming/smoking) deluge with plenty of water to control
decomposition. For storage, refer to NFPA Bulletin 430 on storage of liquid and solid oxidizing materials.
COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to
prevent release of dust into work environment. Spills should be collected into suitable containers to prevent
dispersion into the air.
S. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name
ACGIII
OSHA
Supplier
Sodium Persulfate
0.1 mg/m3 (TWA)
ENGINEERING CONTROLS: Provide mechanical local general room ventilation to
prevent release of dust into the work environment. Remove contaminated clothing immediately and wash
before reuse.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Use cup type chemical goggles. Full face shield may be used.
RESPIRATORY: Use approved dust respirator when airborne dust is expected.
Page 3 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
PROTECTIVE CLOTHING: Normal work clothes. Rubber or neoprene footwear.
GLOVES: Rubber or neoprene gloves. Thoroughly wash the outside of gloves with soap and
water prior to removal. Inspect regularly for leaks.
9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: None
APPEARANCE: White crystals
AUTOIGNITION TEMPERATURE: Not applicable. No evidence of combustion up to 800°C.
Decomposition will occur upon heating.
BOILING POINT: Not applicable
COEFFICIENT OF OIL / WATER: Not applicable
DENSITY / WEIGHT PER VOLUME: Not available
EVAPORATION RATE: Not applicable (Butyl Acetate = I)
FLASH POINT: Non-combustible
MELTING POINT: Decomposes
ODOR THRESHOLD: Not applicable
OXIIDIZING PROPERTIES: Oxidizer
PERCENT VOLATILE: Not applicable
pH: typically 5.0 - 7.0 @ 25 °C (1% solution)
SOLUBILITY IN WATER: 73 % @ 25 °C (by wt.)
SPECIFIC GRAVITY: 2.6 (H20=1)
VAPOR DENSITY: Not applicable (Air = I)
VAPOR PRESSURE: Not applicable
10. STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Heat, moisture and contamination.
STABILITY:
Stable (becomes unstable in presence of heat,
moisture and/or contamination).
POLYMERIZATION: Will not occur
INCOMPATIBLE MATERIALS:
Page 4 of 9
Acids, alkalis, halides (fluorides, chlorides,
bromides and iodides), combustible materials, most
metals and heavy metals, oxidizable materials,
other oxidizers, reducing agents, cleaners, and
organic or carbon containing compounds. Contact

Sodium Persulfate (7775-27-1) Date: 02/22/2005
with incompatible materials can result in a material
decomposition or other uncontrolled reactions.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen that supports combustion and oxides of
sulfur.
COMMENTS: PRECAUTIONARY STATEMENT: Use of persulfates in chemical reactions
requires appropriate precautions and`deigti considerations for pressure and thermal relief.
Decomposing persulfates will evolve large volumes of gas and/or vapor, can accelerate exponentially with
heat generation, and create significant and hazardous pressures if contained and not properly controlled or
mitigated.
Use with alcohols in the presence of water has been demonstrated to generate conditions that require
rigorous adherence to process safety methods and standards to prevent escalation to an uncontrolled
reaction.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Non -irritating (rabbit) [FMC Study Number: ICG/T-79.029]
SKIN EFFECTS: Non -irritating (rabbit) [FMC Study Number: ICG/T-79.029]
DERMAL LD50: > 10 g/kg [FMC Study Number: ICG/T-79.029]
ORAL LD50: 895 mg/kg (rat) [FMC Study Number: ICG/T-79.029]
INHALATION LC50: 5.1 mg/I (rat) [FMC I95-2017]
SENSITIZATION: May be sensitizing to allergic persons. [FMC Study Number: ICG/T-79.029]
TARGET ORGANS: Eyes, skin, respiratory passages
ACUTE EFFECTS FROM OVEREXPOSURE: Dust may be harmful and irritating.
May be harmful if swallowed.
CHRONIC EFFECTS FROM OVEREXPOSURE: Sensitive persons may develop
dermatitis and asthma [Respiration 38:144, 1979]. Groups of male and female rats were fed 0, 300 or 3000
ppm sodium persulfate in the diet for 13 weeks, followed by 5000 ppm for 5 weeks. Microscopic
examination of tissues revealed some injury to the gastrointestinal tract at the high dose (3000 ppm) only.
This effect is not unexpected for an oxidizer at high concentrations. [Ref. FMC I90-1151, Toxicologist
1:149, 1981].
Page 5 of

Sodium Persulfate (7775-27-1) Date: 02/22/2005
CARCINOGENICITY:
NTP: Not listed
IARC: Not listed
OSHA: Not listed
OTHER: ACGIH: Not lis"ted--
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION:
Bluegill sunfish, 96-hour LC50 = 771 mg/L [FMC Study I92-1250]
Rainbow trout, 96-hour LC50 = 163 mg/L [FMC Study I92-1251]
Daphnia, 48-hour LC50 — 133 mg/L [FMC Study I92-1252]
Grass shrimp, 96-hour LC50= 519 mg/L [FMC Study I92-1253]
CHEMICAL FATE INFORMATION: Biodegradability does not apply to inorganic
substances.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Dispose as a hazardous waste in accordance with local, state and federal
regulatory agencies.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
PROPER SHIPPING NAME: Sodium Persulfate
PRIMARY HAZARD CLASS / DIVISION: 5.1 (Oxidizer)
UNINA NUMBER: UN 1505
PACKING GROUP: III
LABEL(S): 5.1 (Oxidizer)
PLACARD(S): 5.1 (Oxidizer)
MARKING(S): Sodium Persulfate, UN 1505
ADDITIONAL INFORMATION: Hazardous Substance/RQ: Not applicable
Page 6 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
49 STCC Number: 4918733
This material is shipped in 2251b. fiber
drums, 55 lb. poly bags and 1 000 - 22001b.
IBC'; (supersacks).
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
PROPER SHIPPING NAME: Sodium Persulfate
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
PROPER SHIPPING NAME: Sodium Persulfate
OTHER INFORMATION:
Protect from physical damage. Do not store near acids, moisture or heat.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not applicable
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Fire Hazard, Immediate (Acute) Health Hazard
SECTION 3I2 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
Not listed
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Unlisted, RQ = 100 lbs., Ignitability
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA INVENTORY STATUS (40 CFR 710):
Page 7 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
Listed
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261):
Waste Number: DOOI
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
Product Identification Number: 1505
Hazard Classification / Division: Class C (Oxidizer), Class D, Div. 2, Subdiv. B. (Toxic)
Ingredient Disclosure List: Listed
INTERNATIONAL LISTINGS
Sodium persulfate:
Australia (AICS): Listed
China: Listed
Japan (ENCS): (1)-1131
Korea: KE-12369
Philippines (PICCS): Listed
HAZARD, RISK AND SAI+ETY PHRASE DESCRIPTIONS:
EC Symbols: (Not classified as hazardous)
EC Risk Phrases: (Not classified as hazardous)
EC Safety Phrases: (Not classified as hazardous)
16. OTHER INFORMATION
HMIS
Health
1
Flammability
_ 0
Physical Hazard
1
Personal Protection (PPE)
J
Protection = J (Safety goggles, gloves, apron & combination dust & vapor respirator)
HMIS = Hazardous Materials Identification System
Degree of Hazard Code:
4 = Severe
Page 8 of 9

Sodium Persulfate (7775-27-1) Date: 02/22/2005
3 = Serious
2 = Moderate
1 = Slight
0 = Minimal
NFPA
Health
Flammability
Reactivity
Special
0
1
OX
SPECIAL = OX (Oxidizer)
NFPA = National Fire Protection Association
Degree of Hazard Code:
4 = Extreme
3 = High
2 = Moderate
1 = Slight
0 = Insignificant
REVISION SUMMARY:
This MSDS replaces Revision #10, dated October 05, 2004.
Changes in information are as follows:
Section 1 (Product and Company Identification)
Section 16 (Other Information)
FMC Logo - FMC Corporation Trademark
© 2005 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance on such information.
Page 9 of 9

Attachments — Section V
Application for Injection Pilot Study
Old Store LUST Incident
Proposed Walgreen Store #10275
Charlotte, NC
ADJACENT PROPERTY RECEPTOR SURVEY RESULTS

wNAME
7
AD7ACE I';PROPERTY OWNER POTEN77ALRECEPTOR'SURVEY -
• :ADDRESS - y CI`IY"WATER"• BASEMENT •SUPPLY WELL DATA COMMENTS
•.-7 DEPTH DIAMETER
NA 5226 Beatties Ford Rd NA
Brownly 4837 Beatties Ford Rd
Rmneses
Temple 4919 Beatties Ford Rd
Barnes 5300 Beatties Ford Rd
Auten 5041 Beatties Ford Rd
Sunset Corners Plaza
Cummings 5308 Beanies Ford Rd
Pettis 5309 Beatties Ford Rd
NA 5400 Beatties Ford Rd
NA 5408 Beatties Ford Rd
Kappa Alpha
Psi 5409 Beanies Ford Rd
Rappe 5009 Beatties Ford Rd
NA
Russell
Little Oaks
NA
Hamilton
Hamilton
Hamilton
Commercial
Courier 5006 Beatties Ford Rd
Express
4040 Hamilton Dr
4838 Beatties Ford Rd
4901 Beanies Ford Rd
4909 Beanies Ford Rd
4912 Beanies Ford Rd
4952 Beatties Ford Rd
4924 Beatties Ford Rd
Butler 4900 Beatties Ford Rd
Blackman 4924 Kerr Lane
Nash 5000 Kerr Lane
Tran 4314 Johov Dr
Yes
Yes
Yes
No
Yes
No
No
Yes
Yes
Yes
Yes
Yes
NA NA NA
NA
No
No
No
Ycs
No
No
No
• NA
No
No
No
No
Bojangles 4322 Sunset Rd
Yes N No supply well
NA
NA
NA'
NA
NA
NA
NA
NA
NA
NA
•
Resident not home - well
house observed
Resident uses supply well
No supply well
Well house observed
No supply well
Nine stores on city water
Resident uses supply well
Resident nor home
Resident uses supply well
Resident not home - well
house and water meter
observed
ResidResident not home - well
ent o serve
Resident not home -well
house and water meter
observed •
Resident not home - well
house and water meter
observed
Resident uses supply well
No supply well
Resident not home
No supply well
No supply well
Resident, indicated "no longer
use well
Business uses supply well
Resident uses supply well
Resident uses supply well
No supply well
No supply well
Chambers 4951 Hamilton Cir Yes No NA
NA Resident indi aced "wash gars 4947 Hamilton Cir and house Scat well water
Yes No NA NA Resident has supply well
NA 4944 Hamilton Cir Resident not home - well
Yes NA NA NA house and wafer meter
Mbun,u No Y
4939 Hamilton Cir observed
Yes NA NA Resident uses supply well
Ford 4928 Hamilton Cir No
Yes 40' 7" Resident uses supply well
NA Resident(s) not available on four occasions for interview or did not know answers.
' - Determined by water meter and/or interview.
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Table 1:
Receptor Survey Summary
Kiker Property, incident # 21451
5100 Beatties Ford Road
Charlotte, Mecklenburg County
SEME Project # 1354-03-509
2w7L.111II
_
41 g Ocrolle-R 4.0-D]
—114 gt ge/2 71,Ayerryi zoe-ATT-ED /vaturi.i
_51/0 prO2v77-7 -rip( Grp 5-1 0-e V rep.
M• 61ATPIWg1
Jar 'ilk. astY-1 -u
' -''''. girrtYce '''r
41%r nit_Ltielititleff
•r,
o " , .
1
5100 Beatles Ford Road (Site)
RMP Sunset, LLP
10700 Sikes Place, #200
Chariotte, NC
0 .
- - - - -Well abandoned January 2002
2
5100 Beatties Ford Road (Site)
RMP Sunset, LLP
'
10700 Sikes Place, #200
Charlotte, NC
0
Welt abandoned Januiry 2002
3
5200 Beatties Ford Road
James H. Richardson, Jr.
17511 Paradise Cove Court
Cornelius, NC 28031
0 - 250
Property is vacant, no well observed, MCDEP
database does not indicate well on property
4
4232 Kitty Drive
Robert A. Ft Melinda B. Dabbs
4232 Kitty Drive - .
Charlotte, NC 28216
750 - 1,000
Wellhouse observed, no one home, MCDEP
database indicates welt on property
5
4216 Kitty Drive
•
Lyndi J. Boone
4216 Kitty Drive
Charlotte, NC 28216
750 - 1,000
No welthouse observed, access to property
restricted, MCDEP database indicates well on
property
6
4208 Kitty Drive
•
Charles D. Webb
4208 Kitty Drive
Charlotte, NC 28216
750 - 1,000
Observed well, no one home, MCDEP database
•
indicates well an property
7
4126 Kitty Drive
Ronald B. Griffin, Sr.
16232 Leeward Lane
Huntersville, NC 28078
750 - 1,000
..,
Wellhouse observed, access to property
restricted, MCDEP database indicates well on
property
8
5233 Beatties Ford Road
Dewey W. a Carolyn H. Craig
5233 Beatties Ford Road
Charlotte, NC 28216
750 - 1,000
Spoke to owner, welt used for potabte water
9
5308 Beatties Ford Road
Ronald Lee Cummings •
5308 Beatties Ford Road
.
Charlotte, NC 28216
750 - 1,000
Spoke to owner, well used for potable water
10
5300 Beatties Ford Road .
Adam Bames, Jr.
5300 Beatles Ford Road
Charlotte, NC 28216
750 - 1,000
Connected to municipal water, well used for
irrigation purposes r
11
4028 Sunset Road
Sunset Road Associates Two,
LLC
.
10737 independence Pointe
Parkway, Suite 103 '
Matthews, NC 28105-2745
250 - 500
Wellhouse observed, property unoccupied,
MCDEP database does not indicate well on
property
12
5040 Beatties Ford Road
•
.
Estate of J.C. Brookshire
P.O. Box 668123
Charlotte, NC28266-8123
•
0- 250
Old Store Site - Weilhouse•not observed,
occupant stated.that building uses municipal.
water, MCDEP database Indicates welt on
property

Table 1:
Receptor Survey Summary
Kiker Property, incident # 21451
5100 Beatles Ford Road
Chariotte, Mecklenburg County
• SEtME Project # 1354-03-509
, ,
itID d
, -re,,,,:s0VSAV.;?,'M
, foaciatttrasb „...,,,,
7-1W-4SVAP4.1.A jrr
: _ lope . wirgz, 4
Sit' ' 70-741 • •
.4,4, 11 ir 4 4nunhes .,
tb !WV,
a 01104
13
5006 Beatties Ford Road
.
Michael R. Et Ouieda C.
Bradley
13825 Beatties Ford Road
Chadoite, NC 28078
250 _ 500
Occupant states that building uses municipal
. Water, no well observed on property
14
4924 Beattles Ford Road
.
Minnie M. Hamilton
.
6010 Windy Knoll Lane
Charlotte, NC 28227-9382
500 - 750 •
Wellhouse observed, no one home, MCDEP
database does not indicate well on property.
15
_
_
5009 Beatties Ford Road
5309 Beatties Ford Road
•
•
Roy Martin Rappe
WR Enterprises, LLC
5009 Beatties Ford Road •
Charlotte, NC 28216
3024 Colvard Parkway
Charlotte, NC 28269-8637
! •
250 - 500
,
'. 750 - ,OGO
f
Wellhouse observed, no one home; MCDEP -
-- ,
wed on property
database does not indicate-
. .• .- .
No wellhouse observed, no one home, MCDEP
. indicates.well on property
16
17
4117 Kitty Drive
Estate of Miles A. Hilton
•
3906 Tam 0 5hanter Road
Kemersville, NC 27284
.750 - 1,000
Wellhouse observed, no one home, MCDEP
database indicates well on property
18
4201 Kitty Drive
Daniel L.-Et Kimberly M,
Ballard
.
4201 Kitty Drive
Charlotte, NC 28216
.
750- 1,000
No wellhouse observed, no one home, MCDEP
- indicates well on property
19
4209 Kitty Drive
SherT. Jones
ry .
4225 Kitty Drive
.
Charlotte, NC 28216
1
750 - 000
,
Property is vacant, MCDEP IndicatesWell on
, . property • .
•
, .