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HomeMy WebLinkAboutNC0021369_Permit Issuance_19981026NPDES DOCUHENT SCANNING COVER SHEET Permit: NC0021369 Columbus WWTP NPDES Document Type: Permit Issuance ) Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Engineering Alternatives (EAA) Correspondence Instream Assessment (67b) Speculative Limits Environmental Assessment (EA) Document Date: October 26, 1998 This document is printed on reuse paper - ignore any content on the reYerse side State of North Carolina Department of Environment and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Wayne McDevitt, Secretary A. Preston Howard, Jr., P.E., Director Mr. David Lane Town of Columbus P.O.Box 146 Columbus, North Carolina 28722 Dear Mr. Lane: vt;47c1rA ,,21F/E• NCDENR October 26, 1998 Subject: NPDES Permit Issuance Permit No. NC0021369 Town of Columbus WWTP Polk County In accordance with the application for a discharge permit received on April 8, 1998, the Division is forwarding herewith the subject state - NPDES permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated December 6, 1983. Please note the following changes incorporated into this NPDES permit: • The WWTP was re -rated from a Class III to a Class II facility, therefore monitoring frequencies were adjusted for a Class II ranking. • Effluent limits and monitoring requirements for chromium and nickel were deleted from the permit. • Effluent limits for lead, cyanide, and mercury were removed from the permit, and the monitoring frequency was changed from weekly to monthly. • Monitoring frequency for copper and zinc was changed from 2/month to monthly. • The permit expiration date was changed from November 30, 1998 to July 31, 2003. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the office of Administrative Hearings, Post Office Drawer 27447, Raleigh, North Carolina 27611-7447. Unless such a demand is made, this permit shall be final and binding. Please take notice that this permit is not transferable. Part II, E.4. addresses the requirements to be followed in case of change in ownership or control of this discharge. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act, or any other Federal or Local governmental permits may be required. 1 P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper Page 2 Mr. David Lane Town of Columbus October 26, 1998 If you have any questions or need additional information, please contact Mr. Tom Belnick, telephone number (919) 733-5083, extension 543. Sincerely, Original Signed By David A. Goodrich A. Preston Howard, Jr., P.E. cc: Central Files U.S.EPA, Roosevelt Childress NPDES Unit, Permit File Asheville Regional Office, Water Quality Point Source Compliance/Enforcement Unit Aquatic Tox Permit No. NC0021369 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards arid regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Town of Columbus is hereby authorized to discharge wastewater from a facility located at Town of Columbus WWTP Levi Road extension Columbus, North Carolina Polk County to receiving :waters designated as an unnamed tributary to Whiteoak Creek in the Broad River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. This permit shall become effective December 1, 1998. This permit and authorization to discharge shall expire at midnight on July 31, 2003. Signed this day October 26, 1998. Original Signed By David A. Goodrich A. Preston Howard, Jr., P.E., Director Division of Water Quality By Authority of the Environmental -Management Commission 1 J Permit No. NC0021369 SUPPLEMENT TO PERMIT COVER SHEET Town of Columbus is hereby authorized to: 1. Continue to operate the existing 0.80 MGD activated sludge wastewater treatment facility with effluent disinfection located at the Town of Columbus WWTP, Levi Road Extension, Columbus, Polk County (See Part IIIA of this permit), and 2. Discharge wastewater (via Outfall 001) from said treatment works at the location specified on the attached map into an unnamed tributary to Whiteoak Creek, which is classified C waters in the Broad River Basin. in( . i O Latitude: 351513 Longitude: 820956 N USGS Quad #: F10SW River Basin #: 030802 Broad Receiving Stream: UT White Oak Cr Stream Class: C Town of Columbus WWTP NC 0021369 Polk County A (1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS - FINAL Permit No. NC0021369 During the period beginning on the effective date of the permit and lasting until expiration, the Permittee is authorized to discharge from outfall serial number 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT CHARACTERISTICS LIMITS MONITORING REQUIREMENTS Monthly Average Weekly Average Daily Maximum Measurement. Frequency Sample Type Sample Location1 Flow 0.80 MGD Continuous Recording I or E BOD, 5 day, 20°C 2 30.0 mg/I 45.0 mg/I Weekly Composite E, I Total Suspended Residue2 30.0 mg/I 45.0 mg/I Weekly Composite E, I NH3 as N 2/Month Composite E Fecal Coliform (geometric mean) 200 / 100 ml 400 / 100 ml Weekly Grab E Total Residual Chlorine 2/Week Grab E Temperature Weekly Grab E pH3 Weekly Grab E Total Nitrogen (NO2 + NO3 + TKN) 2/Year Composite E Total Phosphorus 2/Year Composite E Cadmium 5.4 ug/I 2/Month Composite E Lead Monthly Composite E Cyanide Monthly Grab E Mercury Monthly Composite E Copper Monthly Composite E Zinc Monthly Composite E Silver Monthly Composite E Chronic Toxicity4 Quarterly Composite E Notes: 1. Sample locations: E - Effluent, I — Influent 2. The monthly average effluent BOD5 and Total Suspended Residue concentrations shall not exceed 15% of the respective influent value (85% removal). 3. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units. 4. Chronic Toxicity.(Ceriodaphnia) P/F at 37%; September, December, March, and June; See Special Condition A(2). There shall be no discharge of floating solids or visible foam in other than trace amounts. Permit No. NC0021369 SUPPLEMENT TO EFFLUENT LIIVIITATIONS AND MONITORING REQUIREMENTS SPECIAL CONDITIONS A (2). CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised November 1995, or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 37.0% (defined as treatment two in the procedure document). The permit holder shall perform quarterly monitoring using this procedure to establish compliance with the permit condition. The tests will be performed during the months of March, June, September, and December. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DWQ Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Road Raleigh, North Carolina 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) testorm indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test j requirement will revert to quarterly in the months specified above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the 'months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include altemate'rnonitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. SEP-10 98 10:1S FROMI:TRYCN DAILY BULLETIN 828-859-5575 TO:919 733 9919 PAGE:01/01 PUBLIC NOTICE STATE OF NORTI1 CAROLINA EN VC ROM ENTAL MANAGEMENT COMM ISSION POST OFFICE BOX 29535 RALEIGTI, NC 27626-0535 NOTIFICATION OF INTEN'r'I'U ISSUE A'I'ATE NPDES PERMIT On the basis of thorough Sluff review and application uIArticic 2l of Chapter 143, General Statutes of North Carolina, Public Law 92-500 and other lawful 5lundards and regu- lations, the North Carolina Environ- mental Management Commission proposes to issue a permit to dis- charge to the persons listed below effective 10/26/98 and subject to special conditions. Persons wishing to CCmment upon or object to the pmposcd determina- tions are invited 1u submit same in writing to the above address no later than 10/09/98, All comments re- ceived prior to that elate will be considered in the formulation of'fi- nal determinations regarding the: proposed permit. A public meeting may be held where the Director of the Di vision ofEnvironmental Man- agemenl finds a significant dcgrceof public interest in the proposed per- mit. A copy of the draft permit is available by writing; or calling the Division of Environmental Manage- ment, PO Box 2953 5, Raleigh, North Carolina 27626-0535; (919) 733- 7015. The application and other infor- mation may be inspected at these lacationsduringnorrnal office hours, Copics of the information on file arc available upon request and payment of the costs a Preproduction. A it such comments or requests regarding a proposed permit should make refer- ence to the NPDES permit number listed below. September 1, 1998 David A. Goodrich A. Preston Howard lr., P.E., Director Division of environmental Management Public notice of intent to issue a State NPDES permit to the follow- ing: 1. NPDES No, NC0021369. Town of Columbus, PO Box 146, Columbus, NC 28722 has applied for permit renewal for a facility located at Town of' Columbus WWTP, ot1 NCSR 153., cast of Colutbus, Polk County. The facil- ity discharges 0.80 MGD of treated domestic wastewater from one out - fall into an unnamed tributary to Whiteoak Creek, a Class C stream in the Broad River Basin which has a 7Q 10 flow oft. 10 cfs. Some param- eters are water quality limited. 'This mayaffect future water-qual ity based effluent limitations for additional dischargers within this portion of the watershed. 2. NPDES No. NC0004464. Stonet:utter Milk Corporation, Dal- las Street, Spinclulc, NC 28160 has applied fix a permit renewal for a tacihty Incatcd at the Mill Spring 'pinning Plant, NC Highway 108, Mill Spring, Polk County. The facil- itydisehurbus 0,015 MGD of treated domestic w:islewalor from one out- let' into the South Branch River, u Class C stream in the Bread River Basin which has a 7Q 10 flow of0,_ti5 cis. For some parameters, the avail- able load capacity of the immediate receiving water will be consumed. This inay affect future water quality based effluent limitations for addi- tional dischargers within this por- tion id* the watershed. ;idv.9/ 1 1 Ix 13 FAX TO: KIM MURPHY AT 919-733-9919 This is Your PROOF AD From Tryon Daily Bulletin As Requested Please Review Immediately! Please proof for typos only. Text changes or ad redesign may incura minimal graphic arts charge. Thank you, The Tryon Daily Bulletin Phone: 828-859-9151 OR Fax: 828-859-5575 ❑ Faxed By: CD n`► --0 CD LEGALS - page 33 DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0021369 Facility Information Facility Name Town of Columbus Permitted Flow: 0.80 MGD _ Facility Class: II (recentl reranke 1 from Ill to 11 by ARO) (-P 0 to . ' (7 ,-,-! - Facility/Permit Status: (i.e. New, Modification, Existing or Renewal) Renewal 4 re rate- C -13 -'%5 County: Polk Stream Characteristics Receiving Stream: UT to Whiteoak Creek Stream Classification: C Subbasin: 030802 (Broad River Basin) Drainage Area (mi2): 4.5 Summer 7Q10 (cfs) 2.1 (use for permit renewal) 0.96 (updated USGS data; use for any future expansion) Winter 7Q10 (cfs): NA 30Q2 (cfs): NA Average Flow (cfs): 6.8 I WC (%): 37% (use 56% for any future expansion) Miscellaneous Regional Office: Asheville USGS 'Fopo Quad: F 1 OS W Changes Incorporated into Permit Renewal Proposed Changes Parameters Affected Basis for change(s) Change facility class from III to II, and adjust monitoring frequencies accordingly. Toxicants (with limits) will get 2/month sample — frequency. Toxicants (without limits) will get monthly sample frequency. ,, Toxicants. Monitoring frequency for all other parameters already reflects Class II requirements Facility recently re -rated by ARO, per Staff report submitted 5/18/98. Toxicant monitoring requirements for Class II facility based on NPDES Supplemental Monitoring Fact Sheet. Remove from permit (currently only a monthly monitoring requirement) Chromium Detected in 1 of 28 samples from 1996-97; reeonable potential analysis (RPA) does not indicate a toxicity concern. Remove from permit ✓ (currently an effluent limit and weekly monitoring requirement) Nickel Detected in 2 of 103 samples from 1996-97; RPA does not indicate a toxicity concern. Remove effluent limit, and change monitoring requirement from weekly to monthly V Lead Detected in 18 of 103 samples from 1996-97; predicted max eff conc. represents 93% of allowable eff conc. Remove effluent limit, and change monitoring requirement from weekly to monthly L Cyanide Detected in 7 of 103 samples from 1996-97; predicted max eff conc represents 46% of allowable eff conc. Remove effluent limit, and change monitoring requirement from weekly to monthly ,/ Mercury Detected in 1 of 103 samples, but detection limit exceeds allowable eff.conc. RPA indicates potential toxicity concern due to detection limit. Change monitoring requirement from 2/month to monthly Copper, Zinc, Silver RPA indicates potential exceedance of action levels; therefore retain monitoring requirement but modify monitoring frequency per Supplemental Monitoring Fact Sheet for Class II Toxicants (w/o limits) .� 6'1*er ioaS aJ/-zady elarjed ,. -f.-0,, D-� PP, -tfl ,on'emy on pea . 30 I y q 4 - - �t•NPDES See rev i sed ge+-r'�' • NC0021369 Summary Previously this minor municipal WWTP (0.8 MGD) received its majority of flow from a single industry (Hatch Mill, a dyeing and finishing operation), which closed its operations in Spring 1994. Currently, the Town receives only domestic sewage plus septage from commercial haulers. The Town's pretreatment program has been inactivated since 1994. The current permit was modified in December 1994 for two metals (chromium and silver), after the industrial source was removed. ARO is currently requesting additional modifications to the metals limits and/or monitoring requirements. Proposed Permit Changes. Facility Class changed from III to II, with associated changes in monitoring frequency for toxicants. A Reasonable Potential Analysis (RPA) was conducted using data for the last 24 months (1996-1997 calendar years). Limits and monitoring requirements were deleted for chromium and nickel, and modified for other metals. DMR Data. Facility appears to be compliant for the 1996-1997 calendar years. Of 9 quarterly chronic toxicity test results submitted between 1996-97, there was only one reported test failure. Staff Report. ARO submitted a staff report on 5/18/98. ARO recommends permit renewal, with modification of metals limits and/or monitoring frequencies. Specifically, ARO recommends that chromium, nickel, silver, and mercury be removed from new permit due to limited detections. ARO also recommends only quarterly monitoring with no limits for the following detected metals (cyanide, cadmium, copper, lead, and zinc). WLA/Receiving Stream. The facility discharges to an UT to Whiteoak Creek, which is classified C waters (classified 9/1/74, Index No. 9-29-46). Downstream uses include fish and wildlife habitat and propagation. The receiving stream is not listed in the 1998 303(d) listing, and available data indicate the water meets its uses. There are no instream monitoring requirements in the current permit for this facility. The current permit limits were based on a 1993 WLA which used a 7Q10 = 2.1 cfs. It was indicated (1994 memo) that the USGS flow data was being revised, and a 7Q10 = 0.96 cfs would be more appropriate for this discharge outfall. Since it is NPDES policy not to change flow values unless there is an expansion, the old 7Q10 = 2.1 cfs was used for this permit renewal and reasonable potential analysis. Upon any future expansion, a 7Q10 of 0.96 cfs should be used in the updated WLA/R.PA. Based on last WLA, ammonia limits (summer and winter) would be appropriate to protect for potential instream toxicity; however, it appears that facility has elected to replace ammonia limits with quarterly chronic WET toxicity testing. DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES No. NC0021369 (Continued) Proposed Schedule for Permit Issuance Draft Permit to Public Notice: 09/09/98 Permit Scheduled to Issue: 10/26/98 State Contact If you have any questions on any of the above information or on the attached permit, please contact Tom Belnick at (919) 733-5038, extension 543. Copies of the following are attached to provide further information on the permit development: • Reasonable Potential Analysis (majors only) • Existing permit effluent sheets with changes noted (existing facilities only) • Draft Permit NPDES Recommendation by: Date: 730 - qS Regional Office Comments This space is used by the Regional office personnel to identify specific concerns in reference to issuance of the subject permit. (rrr) vemdzo ow/ • 'Ae /1-04t4;4,3ed ty ercl earya , C9liu- 4//)17;,,toatt,7 Regional Recommendation b Reviewed By: Regional Supervisor: NPDES Unit: ate: SOC priority: yes _x_no TO: STATE ENGINEERING & REVIEW GROUP FAX: 919-733-0719 ATTN: TOM BELNICK FROM: WATER QUALITY SECTION ASHEVILLE REGIONAL OFFICE WANDA P. FRAZIER DATE: MAY 18, 1998 NPDES STAFF REPORT AND RECOMMENDATION PART I - GENERAL INFORMATION 1. Facility name: County: Permit number: Name: Address: Phone: 2. Date of Inspection: 3. Inspector/Report By: 4. Persons Contacted: Telephone Number: 5. Directions to Site: Town of Columbus P. 0. Box 146 Columbus, North Carolina 28722 Polk NC0021369 David Lane, Town Administrator PO Box 146; Columbus, NC 28722 828-894-8236 May 12, 1998 Wanda P. Frazier Bob Barwell, ORC 828-894-3055 The facility is located on NCSR 1531 east of Columbus, NC 6. Discharge Point: Latitude: 35° 15' 13" Longitude: 82° 09' 56" Note: Attached is a USGS map extract, indicating the facility site and discharge point(s) on the map using USGS Quad No.: F10 SW USGS Quad Name: Mill Spring, NC 7. Is the site size and expansion area consistent with application? not applicable 8. Topography (relationship to flood plain included): slightly rolling 9. Location of nearest dwelling: >100 feet -1- 10. Receiving stream or affected surface waters: UT to Whiteoak Creek a. Classification: C b. River Basin & subbasin no: Brd 03-08-02 c. Describe receiving stream features and pertinent downstream uses: fish and wildlife and habitat and propagation PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. a. What is the volume of wastewater to be permitted in MGD (Ultimate Design Capacity)? 0.800 MGD b. What is the current permitted capacity of the Wastewater Treatment facility? 0.800 MGD c. What is the actual treatment capacity of the current facility (current design capacity)? 0.800 MGD d. What is/are the date(s) and construction activities allowed by previous Authorizations to Construct issued in the previous two years? n/a; an A to C has NOT been issued within the past two years. e. Provide a description of existing or substantially constructed wastewater treatment facilities. Existing 0.8 MGD extended aeration activated sludge basins, clarifier, chemical addition, with effluent disinfection. f. Provide a description of proposed wastewater treatment facilities. n/a; no facilities proposed. g What are the possible toxic impacts to surface waters? None, other than chlorine. There are no industrial discharges at this time, only septage from commercial haulers and a small contribution from commercial establishments. A small quantity of "Epfloc" polymer is used to assist with coagulation and settling. h. Is there a pretreatment program (POTWs only)? in development should be required approved _x_not needed 2. Residuals handling and utilization/disposal scheme: -2- a. Are residuals being land applied? Yes Permit Number: WQ002645 Residuals Contractor: n/a (Town of Columbus) Telephone Number: n/a b. Residuals stabilization: x PSRP PFRP OTHER c. Landfill: none d. Other disposal/utilization scheme: none 3. Treatment plant classification: Class II (48 points) Note: Previous ratings classified facility as Class III. See attached completed rating sheet. 4. SIC Codes(s): 4952 Wastewater code(s) - Primary: - Secondary: Main Treatment Unit Code: 312-3 01 none PART III - OTHER PERTINENT INFORMATION 1. Is this facility (municipals only) being constructed with Construction Grant Funds or are any public monies involved? n/a 2. Special monitoring or limitations (including toxicity) requests: No special monitoring requirements at this time. 3. Important SOC, JOC, or Compliance Schedule dates: n/a Dates: Submission of Plans and Specifications: n/a Begin Construction: n/a Complete Construction: n/a PART IV - EVALUATION AND RECOMMENDATIONS 1. Compliance: The facility's operation has demonstrated compliance for the past year (see attached compliance evaluation analysis). 2. Pretreatment: The pretreatment program has been inactivated due to the discontinuation of Milliken's discharge in the spring of 1994. 3. Metals: The current permit was revised 12-30-94 for chromium; the limit was removed and monitoring frequency -3- changed from weekly to monthly. Also, the monitoring frequency was changed from twice a month to monthly for silver. See attached letter date August 31, 1994 from McGill Associates (consulting engineers) requesting removal of listed metals from the permit. According to the compliance evaluation nalysis port: There have been no "hits" for chromium, nickel, silver, and mercury. ARO recommends that these parameters be removed from the new permit. There have been "hits" for cyanide, cadmium, copper, lead and zinc. ARO recommends that these parameters should be monitored quarterly with no permit limits. 4. Recommendations: The Asheville Regional Office recommends renewal of NPDES permit # NC0021369 with modifications and/ or removal of limits and/or monitoring frequencies for metals mentioned above (Part IV #3). This facility was rated a Class III, it is now a Class II. Please change monitoring requirements accordingly. 2a:270/a i . - a Signature of Report parer ater Quality Regional Supervisor I 7 a Date -4- Facility Name = Columbus VVVVTP arameter = NPDES # = NC0021369 Standard = Qw (MGD) = 0.8 Qw (cfs) = 1.23776 7Q10s (cfs)= 2.1 n !WC (%) = 37.13 FINAL RESULTS FOD I- Oil Cadmium Max. Pred Cw Luti } 111.0 5/103 _ Allowable Cw 5.4 Chromium Max. Pred Cw gewswe 19.8 1/28 Allowable Cw 134.7 Nickel Max. Pred Cw Rl M 04 t 6.6 2/103 Allowable Cw 237.0 Lead Max. Pred Cw (NA t-Ji r 62.5 18/103 Allowable Cw 67.3 Cyanide Max. Pred Cw Mo* 1 6.250 7/103 Allowable Cw 13.468 Mercury Max. Pred Cw Mo ki IV 0.5 1/103 Allowable Cw 0.032 copper (AO Max. Pred Cw 50/50 Allowable Cw 18.855 Zinc (AO Max. Pred Cw '11toHi 412.8 50/50 Allowable Cw 134.7 Silver (AC} Max. Pred Cw 11.8 2/25 Allowable Cw o,W 0.16 6,tha NoDFS 7-z9-48 J WLtftAir- TomcoT ,3AT?4 --= Cadmium l 2 pg/I DL=1/2DL tual Data RESULTS 1.2 Std Dev. 5.379653 3 Mean 1.710769 26 C.V. 3.144581 21 n=101 30 0.5 <1 Mult Facto 3.7 0.5 Max. Valu 30 pg/I 0.5 Max. Pred 111 pg/I 0.5 Allowable 5.4 pg/I 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 . 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Parameter = Chromium Standard = 50 pg/I n DL=1/2DL ctual DataRESULTS 1 9 Std Dev. 1.131371 2 1 <2 Mean 1.16 3 1 C.V. 0.97532 4 1 n=50 5 1 6 1 Mult Facto 2.2 7 1 Max. Valu 9 8 1 Max. Pred 19.8 9 1 Allowable C 134.7 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 1 29 1 30 1 31 1 32 1 33 1 34 1 35 1 36 1 37 1 38 1 39 1 40 1 41 1 42 1 43 1 44 1 45 1 46 1 47 1 48 1 49 1 50 1 rameter = Nickel tandard = 88 pg/I n DL=1 /2DL ctual Dat ESULTS 1 6 Std Dev. 0.198 2 6 Mean 5.04 3 5 <10 C.V. 0.039 4 5 n=50 5 5 6 5 Mult Factor 1.1 7 5 Max. Value 6 8 5 Max. Pred C 6.6 9 5 Allowable C 237.0 10 5 11 5 12 5 13 5 14 5 15 5 16 5 17 5 18 5 19 5 20 5 21 5 22 5 23 5 24 5 25 5 26 5 27 5 28 5 29 5 30 5 31 5 32 5 33 5 34 5 35 5 36 5 37 5 38 5 39 5 40 5 41 5 42 5 43 5 44 5 45 5 46 5 47 5 48 5 49 5 50 5 rameter = Lead tandard = 25 pg/I n DL=1/2DLtual Data RESULTS 1 2.3 Std Dev. 4.29 2 4.9 Mean 2.64 3 6 C.V. 1.625 4 3.1 n=65 5 6.6 6 2.7 Mult Factor 2.5 7 2.9 Max. Value 25 8 2 Max. Pred C 62.5 9 7 Allowable C 67.3 10 6.7 11 2.5 12 2 13 2.6 14 17 15 11 16 25 17 17 18 3.3 19 1 <2 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 1 29 1 30 1 31 1 32 1 33 1 34 1 35 1 36 1 37 1 38 1 39 1 40 1 41 1 42 1 43 1 44 1 45 1 46 1 47 1 48 1 49 1 50 1 51 1 52 1 53 1 54 1 55 1 56 1 57 1 58 1 59 1 60 1 61 1 62 1 63 1 64 1 65 1 66 rameter = Cyanide tandard = 5 pg/I n DL=1/2DLtual Data RESULTS 1 6 Std Dev. 3.671 2 28 Mean 2.5 3 17 C.V. 1.468 4 5 n=65 5 6 6 5 Mutt Factor 2.5 7 6 Max. Value 2.5 8 2.5 <5 Max. Pred C6.250 9 2.5 Allowable C114/4*# 10 2.5 11 2.5 12 2.5 13 2.5 14 2.5 15 2.5 16 2.5 17 2.5 18 2.5 19 2.5 20 2.5 21 2.5 22 2.5 23 2.5 24 2.5 25 2.5 26 2.5 27 2.5 28 2.5 29 2.5 30 2.5 31 2.5 32 2.5 33 2.5 34 2.5 35 2.5 36 2.5 37 2.5 38 2.5 39 2.5 40 2.5 41 2.5 42 2.5 43 2.5 44 2.5 45 2.5 46 2.5 47 2.5 48 2.5 49 2.5 50 2.5 51 2.5 52 2.5 53 2.5 54 2.5 55 2.5 56 2.5 57 2.5 58 2.5 59 2.5 60 2.5 61 2.5 62 2.5 63 2.5 64 2.5 65 2.5 rameter = Mercury PE tandard = 0.012 pg/I n DL=1/2DLtual Data RESULTS 1 0.4 Std Dev. 0.037 2 0.1 <0.2 Mean 0.105 3 0.1 C.V. 0.356 4 0.1 n=65 5 0.1 6 0.1 Mulf Factor 1.35 7 0.1 Max. Value 0.4 Ng/ 8 0.1 Max. Pred C 0.54 Ng/ 9 0.1 Allowable C 0.03 Ng/ 10 0.1 11 0.1 12 0.1 13 0.1 14 0.1 15 0.1 16 0.1 17 0.1 18 0.1 19 0.1 20 0.1 21 0.1 22 0.1 23 0.1 24 0.1 25 0.1 26 0.1 27 0.1 28 0.1 29 0.1 30 0.1 31 0.1 32 0.1 33 0.1 34 0.1 35 0.1 36 0.1 37 0.1 38 0.1 39 0.1 40 0.1 41 0.1 42 0.1 43 0.1 44 0.1 45 0.1 46 0.1 47 0.1 48 0.1 49 0.1 50 0.1 51 0.1 52 0.1 53 0.1 54 0.1 55 0.1 56 0.1 57 0.1 58 0.1 59 0.1 60 0.1 61 0.1 62 0.1 63 0.1 64 0.1 65 0.1 rameter = copper tandard = 7 pg/I (AL) n DL=1/2DL ctual DataRESULTS 1 13 Std Dev. 8.961 2 20 Mean 16.24 3 9 C.V. 0.552 4 8 n=50 5 18 6 7 Mult Factor 1.65 7 12 Max. Value 50 8 10 Max. Pred C 82.5 9 10 Allowable C 18.9 10 10 11 13 12 9.9 13 10 14 16 15 8 16 16 17 10 18 13 19 12 20 18 21 18 22 15 23 14 24 14 25 26 26 19 27 12 28 16 29 18 30 16 31 21 32 29 33 22 34 50 35 21 36 14 37 43 38 17 39 12 40 12 41 6 42 8 43 8 44 9 45 39 46 31 47 13 48 12 49 18 50 16 51 rameter = Zinc tandard = 50 Ng/I ,(AL) n DL=1/2DL ctual Dat ESULTS 1 96 Std Dev. 51.17 2 159 Mean 101.5 3 51 C.V. 0.504 4 91 n=50 5 116 6 67 Mult Factor 1.6 7 98 Max. Value 258 8 55 Max. Pred C 412.8 9 97 Allowable C 134.7 10 52 11 90 12 81 13 104 14 63 15 103 16 36 17 142 18 63 19 96 20 101 21 79 22 57 23 143 24 140 25 79 26 90 27 64 28 141 29 69 30 123 31 123 32 59 33 87 34 73 35 109 36 212 37 133 38 12 39 181 40 245 41 168 42 92 43 68 44 76 45 183 46 258 47 37 48 72 49 78 50 63 51 Parameter = Silver Standard = 0.06 pg/I (AL) n BDL=1/2DL Actual Data RESULTS 1 5.6 Std Dev. 0.9338094 2 3 Mean 1.6 3 1.5 < C.V. 0.58363088 4 1.5 n=26 5 1.5 6 1.5 Mult Factor 2.1 7 1.5 Max. Value 5.6 8 1.5 Max. 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