NC0003719_NPDES Permit Renewal_20060619

MEMORANDUM
TO:
FROM:
THROUGH:
SUBJECT:
DIVISION OF WATER QUALITY
- June 19, 2006
Carolyn.Bryant
Point Source Branch
Dale Lopez, Environmental Specialist
Belinda = S. Henson, Regional ,Sup
Renewal of NPDES Permit
,DAK Americas LLC
NPDES No. NC0003719
Cumberland County
Please find encloseda staff report and recommendations from the Fayetteville Regional
Office concerning the'renewal of subject new NPDES Permit. '
If you have any questions or.require any further information, please advise.
DL/RM-S
Enclosures

SOC PRIORITY PROJECT: YES_ NO X
If Yes, SOC No.
To: Permits and Engineering Unit
Water Quality Section
Attention: Carolyn Bryant
Date: June 19 2006.
NPDES STAFF REPORT AND RECOMMENDATION
COUNTY: Cumberland
Permit No. NC0003719
PART I - GENERAL INFORMATION
1. Facility and Address: DAK Americas LLC
3468 Cedar Creek Road
Fayetteville, NC 28312
2. Date of Investigation: June 8, 2006
3. Report Prepared by: Dale Lopez, Environmental Specialist FRO
4. Persons Contacted and Telephone Number: Donald Allbright, ORC
[phone]
5. Directions to Site: From Fayetteville travel NC 53 East. The plant is located 8 miles from
Fayetteville, NC
6. Discharge Point(s), List for all discharge points:
Latitude: 34 deg. 58'8" Longitude: 78 deg. 46' 58"
Latitude: Longitude:
Attach a U.S.G.S. map extract and indicate treatment facility site and discharge point on map.
U.S.G.S.Quad No. H23'NE'
U.S.G.S. Quad Name: Cedar Creek, NC
7. Site size and expansion area consistent with application?
X Yes No (If no, explain)
8. Topography (relationship to flood plain): The wastewater treatment plant is on bluff between the plant
(manufacturing part) and the Cape Fear River. The site is not within the 100-year
flood plain.
Location of nearest dwelling: None within 1,000 feet

10. Receiving stream or affected surface waters:
a. Classification: Lower Little River Class C
b. River Basin and Subbasin No:: Cape Fear River Basin 03-06-15
c. Describe'receiying stream features and pertinent downstream uses: -
At this location the Cape Fear River is approxiinately;100 yards wide, 8-10;f_eet
d,eepwell^. mixed. It is classified as Class C.waters in'this location;' which
.promotes aquatic life propagation and'survival, fishing, wildlife, secondary
recreation, and agriculture. - -
PART 1T - DESCRIPTION OF WASTES AND TREATMENT WORKS
1. a. Volume of wastewater to be permitted:, 1.25 MGD (Ultimate Design Capacity) ,
b. What is the current permitted capacity of the Wastewater Treatment facility? " - 0.5 MGD
c. Actual treatment capacity of the current facility (current design capacity). 1.25 MGD
d. Date(s) and construction activities allowed by previous Authorizations to Construct issued
in the previous two (2) years. None
e. Please provide a description of existing, or substantially constructed wastewater treatment
facilities:
(See attached A). '
Please provide `a description of proposed wastewater treatment facilities: N/A
Possible toxic impacts to -surface waters: Waste, contains several toxic substances. To
date, treatment levels have effluent passing toxicity requirements. There were two (2)
'aquatic toxicity failures .at this facility since January 1999 for pimephales promelas:
August .1999 and May 2003: The reasons for the failures were not determined.
. Pretreatment Program (POTWs only):
In development Approved
Should be required Not needed X ,
2. Residuals handling and utilizing/disposal scheme:

a. If residuals are being land applied, please specify DWQ Permit No.
Residual Contractor:
Telephone:
b. Residuals stabilization: PSRP PFRP Other
c. Landfill: Solids from the drying beds are sent to Sampson County Landfill
d. Other disposal/utilization scheme (specify):
3. Treatment plant classification (attach completed rating sheet):
. SIC Code (s):
Main Treatment Unit Code:
PART III — OTHER PERTINENT INFORMATION
1. Is this facility being constructed with Construdtion Grant Funds (municipals only)?
N/A
2. Special monitoring or limitations (including toxicity) requests: N/A
3. Important SOC, JOC or Compliance Schedule dates (please indicate): NA
Date
Submission of Plans and Specifications N/A
Begin Construction .N/A
Complete Construction N/A
4. Alternative Analysis Evaluation: Has the facility evaluated all of the non -discharge options
available? Please provide regional perspective for each option evaluated.
Spray Irrigation: N/A
Connection to Regional Sewer System: Is currently available to send wastewater to PWC
Rockfish WWTP with an approved pretreatment permit IUP# 2116RF
Subsurface: N/A
Other disposal options: N/A

5. Other Special Items: DAK is presently a member of the Cape Fear River Assembly and instream
Cape Fear River monitoring•is;performed by this group, thus upstream, and downstream
monitoring by the company should not be'a permit requirement.
PART. IV - EVALUATION AND RECOMMENDATIONS
The wastewater treatment adequately treats the wastewater generated from DAK Resins Plant and the
Dupont Teijin Film Plant. There is a small increase in production projected for 2007indicated in the
application package. ;
Based on our June 8, 20site inspection, it is recommended that the DAK NPDES Permit be issued for
an additional 5-year06 term: The two °outfalls to be included in the permit are 002 (process water lines from
all sources) and 001,-which is DAK's storm -water discharge that is combined with non -contact cooling
water from the DAK Resins Plant. A questionnaire will be sent to DAK from FRO concerning the
stormwater permit NCS00038,9 request to modify the NPDES permit to include an additional outfall:
outfall 003 as the stormwater runoff from the DAK Resins Plant (See Attachment B).
Signature of Report Preparer
Water Quality Regional Suso
Date

/(/ 7HC11/v/C/v-
Present Operating Status
The wastewater collection and treatment network consists of the following key sys-
tems: Outfall 001 for stormwater and Outfall 002 for effluent frorri the biotreatment sys-
tem. The two are segregated until the flows reach the Outfall box at the river, they then
mix together and are discharged to the river via the same pipe. These systems are de-
scribed below.
The wastewater treatment system of DAK's Cedar Creek site is an activated sludge
treatment system that consists of equalization, pH adjustment and nutrient addition, aera-
tion, clarification, and sludge digestion and disposal. The waste treatment system treats
industrial and sanitary_ discharges from the DAK Americas Resin Plant and the DuPont
Teijin Film Plant. This wastewater must be treated prior to its discharge to the Cape Fear
River.
The wastewater treatment method used is a biological process that is divided into
five steps:
1. Collection andequalization of raw wastewater
The wastewater from the DAK Resins Plant and the DuPont Teijin Film Plant travel
through separate lines into either of two Equalization (EQ) Tanks. These Equaliza-
tionTanks have a capacity of 660,500' gallons each' or a combined storage of
1,300,000 gallons. The combined flow is then metered into the pH control pit. The
Chem -Lift station collects chemical waste flows from the DAK utilities sump but by-
passes EQ tanks for the pH Control Pit. The only other wastewater treated is domes-
tic sewers from the DAK Services Complex that directly enter the biological aeration
basin.
2. Adjustment of pH and addition of nutrients
The pH control pit is divided into two chambers for nutrient and rough pH adjustment
followed by oil and grease removal along with final pH adjustment. Caustic is added
in the first chamber to adjust the pH. Uran and phosphoric acid are also added in the
first chamber as nutrients. Defoaming chemicals can also be added at this point as
needed. The capacity of the pH control pit is 120,000 gallons.
3. Aeration
Activated sludge is used by the biotreatment system to process wastes. The'raw
wastewater is combined with air and microorganisms and the soluble wastes are oxi-
dized through biochemical reactions. This reduces the `oxygen demand' of the water
so it can be safely discharged. There are two aeration basins; however, during normal
operation, only one is in service. Aerators provide oxygen as needed. Aeration Basin
1 has a capacity of- 3,500,000 gallons and Aeration Basin 2 has a capacity of

1;200,000. OCCasionally activated Lcarbon is added 'tb the aeration basin' as a seed for
the coagulation of solids prior tO clarifiCation.
4. Clarification
After several days of detention time, this.qctivcite,d sludge is then settled in a clarifi-
cation process to remove -suspended solids from the treated Water, Sometimes the
solids do not settle very well, therefore polymers, Klaraid,PC1224 and TO i 72, are
added at the distribution box where the flow is leaving Aeration Basin 2 and entering
the clarifer tO aid in coagulation. This allows for improVed settling Of solids and less
solids in the effluent strewn, This clarified effluent is discharged into the Cape Fear
River. 'The concentrated solids are recycled back into the aeration basins in order to
Maintain a 'steady state' waste treatment operation. This is called return activated
sludge (RAS) However, hecanse the microbes are feeding on the wastewater chemi-
cals, their biomass is growTherefore a waste activated sludge (WAS) stream is
diverted from the RAS for further treatment. The diameter of the clarifier is 90 feet •
and it has a Capacity' of 100,000 gallons. Chlorine tablets are added to the clarifier to
prevent algae growth.
•
5.. Aerobic:sludge digestion and disposal
Excess biomass is oxidized, or digested, by aerating the waste activated sludge in ba-
sins without influent feed. This reduces/the amount of solids that have to be dis-
posed. A digester is available to treat the wasted activated sludge. The capacity Of
the digester is 550,000 gallons. After several weeks of detention time, thesludge is
pumped to a sludge storage basin. The sludge storage basin has a capacity of , •
1,000,000 gallons. After settling; the sludge is pumped to sludge drying beds for de -
watering. There are three sand -drying beds with a Capacity of100;000 gallons each.
All decanted water from the storage basin and beds is returned: to the Aeration Basin
2. The solids from the drying beds are sent to the Sampson County Landfill.

Figure i . DAK Americas Cedar Creek Site Wastewater Treatment System
DAK Resins, •LLC
3216 Cedar Creek Road
Fayetteville, NC
Cumberland County
NPDES Permit No. NC0003T19
DAK Resins
Influent from process
Dupont Teijin Fiirn
Equalization Tanks
Non -contact cooling water
Non -contact
cooling water
to stormwater
Outfall 001
Stormwater
Outfall 001
Spill Basin
Outfall 002
• To Cape Fear River
Effluent from wastewater
treatment plant
pH pit
Sanitary
Sewer
AB2
Digesters
To sludge storage
April 26, 2006

.039
-.002-mgd
.112 mgd
.228 mgd
PWC .431 mgd
.02 MGD
:003 mgd ,
BLOWDOWN:.033 MGD
• .0026 MGD
.021 MGD
.062 mgd
SANITARY :006 mgd
BLOWDOWN :0004 MGD
BLOWDOWN .010 mad
:001 MGD
SLOWDOWN .044 mgd
Waste Sludge• .013 MGD
STEAM
.039 MGD
STORMWATER OUTFALL 001
.116 mgd •
.012 mgd t
ATMOSPHERE
OUTFALL 002
.208 mgd
♦ _ -
TO RIVER

Table I. DAK Americas LLC Cedar Creek Site
Outfall Locations
Outfall
Latitude
Longitude
Description
Receiving Water
. Dry Weather Flow
001
34°58"08'
78°46"58'
Stormwater from developed and undeveloped land throughout the plant
property including the plant process areas and cooling tower
blowdown..
Cape Fear River
Yes
002
34° 58"08'
78°46"58'
Sanitary waste, treated process waste from the utility wastewater,
cooling tower blowdown, boiler blowdown, steam condensate and
sanitary and treated process waste from DuPont Teijin Fi1msTM
Cape Fear River
-Yes
003
.
34° 59"02'
78°47"26'
Stormwater runoff from the DAK resins plant. This outfall is currently
permitted under NCS000389. DAK Americas requests that DENR add
this outfall to the new permit and, if added to the new permit, then to
revoke NCS000389. This would consolidate all stormwater outfalls
and process wastewater outfalls into one permit.
Cape Fear River
No
A
34°59"02'
78°46"40'
Stormwater runoff from the parking lot and paved areas where the
Monsanto facility formerly stood. The outfall discharges onto a
vegetative strip prior to entering the waterway. The outfall discharges
onto a vegetative strip prior to entering the waterway.
Cape Fear River
Small amount of
groundwater infiltration
B1
34°58"58'
78°46"39' =
Stormwater from the paved roadway usedfor in -plant transportation..
The outfall discharges onto a vegetative strip prior to entering the
waterway.
Cape Fear River
- No _
B2
34°58"56
78°46"38'
Stormwater from the paved roadway used for in -plant transportation.
The outfall discharges onto "a vegetative strip prior to entering the
waterway.
Cape Fear River
Small amount of
groundwater infiltration
B3
34°58"55'
78°46"38'
Stormwater from the paved roadway used for in -plant transportation. •
The outfall discharges onto a vegetative strip prior to entering the
waterway.
Cape Fear River
No
-
C
34°58"54'
78°46"39'
Stormwater from the railroad spurs used to transport materials. No
unloading activities occur in this area. Sheet flow only through a
vegetated strip
Cape Fear River
No

Outfall
! •Latitude
'Longitude
Description
: Receiving Water
. Dry Weather Flow •
. D
34°58"54' -
78°46"42' •
Stornwater from railroad spurs used to transportmaterials. No
unloading activities occur in this area. Sheet. flowonly through a°
vegetated strip
Cape Fear River -
• No
E
34°58"49'
-78°46"42'
No industrial activity in this area.- Area drains a small paved area." The .
outfall discharges onto a vegetative strip prior to entering the •
waterway._ ;
Cape Fear River -
-
-No
F
34°58"42'
78°46"50' -
Stormwater from developed and undeveloped land throughout the plant
- property including process areas. Overflow from•SW001. The outfall
discharges onto a vegetative strip prior to entering the waterway.
.Cape Fear River
• • Small amount of
overflow from SW001
-
G
34°58'41' •
' 78°46"50' ,
Stormwater froin activities_ associated with wastewater treatment basins,
fuel. oil storage and -paved roadways used for in -plant transportation
' The, outfall discharges onto a vegetative strip prior to entering the
waterway.
- Cape Fear River
No
H
34658"45'
78°47"05' -
Stormwater from activities associated with the wastewater treatment
plant: Outfall discharges onto:a vegetative strip prior to .entering the
- waterway. •> - .
Cape Fear River
- .- -
- -
No
Extensive sampling: was conducted for all'-outfalls and submitted with the permit renewal application in 1992: Outfalls A -through G indicated'low levels or less
- than detectable amounts of pollutants. Based on this documentation, the State decided -that stormwater sampling would only be required.from Outfall 001. For
ease of accessibility, this sample is taken from the manhole designated SW-1, which is immediately upstream from Outfall 001. • -

17 7 7//C fingeN T
Requested Permit Modification
Outfall 003: discharges stormwater runoff froMTthe DAKresins_ plant. This outfall is cur-
rently permitted under NCS000389, a separate stonnwater permit.. DAK Americas re-
quests that DENR add this outfall to the new permit:and; if added to the new permit, then
to revoke NCS000389. This would consolidate all stormwater outfalls and process
wastewater outfalls into one permit.

WATER:POII:.UTION, _CUN'1'KUL Y"l,m yr;i.
CERTIFICATION:_ COMMISSION
. CLASSIFICATION: ;-:
.
HEET
RATING S . .:- ; 'P; -
FOR WATER POLLUTION CONTROL SYSTEMS.
CONTACT PERSON: JA LP' '/9 1 1 G: TEELEPHONE:.:
PERMIT NO: / V C OD 3 :.7/ y : Check One: NC
RATING INFORMATION: (Before completing this section, please refer to pages'2-4)
PERMITTED FLOW: O,`. MG
CHECK CLASSIFICATION: WASTEWATER:
COLLECTION: 1
URFACE LAND APPLICATION._
PHYSICAL/CHEMICAL GRADE I . GRADE II
REGION:. /i(� DATE: 4
REGIONAL OFFICE TELEPHONE NUMBER:. (Q/D ). V 3— 33/4.k E

North Carolina Departmentof Envronment•and Natural Resources
Michael F. Easley, Governor
June 8, 2006
` Mr.:Anthony-Hudson
Safety, Health,, and Environment Manager
PO Box 1690
Fayetteville, NC 28312,
SUBJECT: Compliance Evaluation Inspection Report (June 8, 2006)
. DAK Resins LLC = Fayetteville
NC0003719
Cumberland County
Dear Mr.. Hudson,
William G. Ross Jr., Secretary
Alan W. Klimek, P.E., Director
Coleeh H. Sullins, Deputy Director
Division of Water Quality
Enclosed you will find a copy of the Report for the Compliance Evaluation Inspection
conducted on June 8, 2006. As part of the inspection a tour of the Wastewater Treatment Plant
was conducted. • All observations are in Section D. Summary of Findings/Comments of this
inspection report. This facility was found to be in Compliance with permit NC0003719. The
cooperation of Mr. Donald Allbright, ORC, was greatly appreciated.
Dale Lopez
Environmental Specialist
Enclosures: EPA Water Compliance Inspection Report
Check List for Field Parameters
cc: Donald Ray Allbright, ORC
225 Green Street — Suite 714, Fayetteville, North Carolina 28301-5043
Phone: [phone] \ FAX: [phone] \ Internet: www.enr.state.nc.us/ENR/
An Equal Opportunity / Affirmative Action Employer - 50 % Recycled \ 10 % Post Consumer Paper
NorthCarolina
Naturally

. . • '
United States Environmental Protection Agency
_
Washington, D.C... 20460
EPA ., - . • - •.,.‘,:- . ,
•
Water Compliance Inspection Report
For rh A0proved. - • , '
QME3.No,.2040-0057.
Approval expires 8-317981
•• Section A: NatiOnal.bata Sysiem-COding (i:6., PCS) • '
. Transaction Code • NPDES yr/rno/day 'Inspection
1'IN1 '' 2 1 51' 31 NC0003719 . ' ili. 12[ 06/6/08 1 17 -
Type ' Inspector ''. , Fac tyPe
181 ci ,19111 . 201
L1.4
, ,
. . , - •
I-1 11 1'1 Ill I II I 116e
- •
- Remarks
211 I -II I I ILI" Ill I I 1111 I 11111111 II I I
• Inspection Work Dys Facility Self -Monitoring Evaluation Rating B1 QA
• 671'. 1.:0 1 69 ,, . 701 31 , :,
1 .1 71U . . .72INI
t--J
- . Reseryed-------7----=
781 I 1.74. 751 :1 I I I - I I ,I 80
- - N., . . . . Section.13: Facility Data ' ,
,.
Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include '
POTW name and NPDES permit Nprnber)
,
Cedar Creek Site.' ,. . . • ,
• :-• .•
•
3468 Cedar Creek Rd. ' • .•• . . _. - .
E Fayetteville NC 28301
. . ,•.10:30
. .
Entry Time/Date
98:30 AM -06/06108
Permit Effective Date
• 03/04/01
Exit Time/Dete . ; . ,-
AM 06/06/08
.
'permit Expiration Date
• i
• 06/10/31
Name(s) of Onsite RepreSentative(s)/Titles(s)/Phone and Fax Number(s) •Other
1 // • i:. ' ' ,-
- .
Donald Ray Allbright/ORC/910-433-8227/ • , ,
.
Facility Data : . . .
• '
. .
• . -
,
. • • . ' .
• ,
Name; Address of Responsible Official/Title/Phone and FaxNumber . • '• • '
..,,... , .
Coritacted
Anthony Hudson, P.O: Box 1690 28302//910-433-8338/ .
•No
. . , ..
- • ' • Section C: Areas Evaluated During InspeCtion (Check only those areas evaluated) ' •
• Permit .- . Flow Measurement' •Operations & Maintenance' Records/Reports ' .
-I Facility Site Review •Effluent/ReceivingWaters '• • . .• .
'Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary)
. .. . .
, • . . . , .
. - . .
(See attachment summary)' • ,
, .
. •
. - •
• . . -
• . ..
. . • . , - . .
Name(s) Signature(s) of Inspector(s) . ' . Agency/Office/Phone and Fax Numbers • Date • : •
•
Dale Lopez . • FRO_WQ//910,486-1541 Ext.712/ • .
. , .
• , '
. .
. ,
Signature of Management Q A Reviewer . , • . Agency/Office/Phone and Fax Numbers • • ' Date -
EPA Form 3560-3 (Rev 9-94). Previous editions are obsolete.
Page # 1

NPDES
NC0003719
111 121
yr/mo/day
06/06/08
117
, Inspection Type
18
1
Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary)
DAK appeared to be in compliance with the NPDES permit. The quality of record keeping and process
control is excellent.
Page # 2

Permit: "NC0003719 'Owner - Facility: , Cedar Creek Site
Inspection Date: 06/08/2006 Inspection Type: Compliance Evaluation
Operations & Maintenance
. Is the plant generally clean with acceptable housekeeping? ' ' 1. n n 0
Does the facility analyze: process control. parameters, for ex: MLSS, •MCRT, Settleable Solids; pH; DO, Sludge. • ,n ❑ n
Judge, and other that -are applicable? .
Comment: .
Permit Yes No NA NE
. (If the present permit expires in 6 months or less). Has the permittee submitted a new application? II n n n
Is the facility as described in the permit? N 0 0- n
#Are'there a,ny` special. conditions for the permit? ` II'n Q 0 •
Is access to the plant site restricted to the general public? ■ n n n
Is the inspector granted access to all areas for inspection? ' a ,:n n n
Comment:
Equalization Basins
Is the basin aerated?.
Is the basin free of bypass lines or structures to the natural environment?
Is the basin free ofexcessive grease?
Are all pumps present?
Are all pumps operable?
Are float controls operable?
Are audible and visual alarms operable?
# Is basin size/volume adequate?
Comment: .
Secondary Clarifier .
Is the clarifier free of black and odorous wastewater?
• Is the site free of excessive buildup of solids in center well of circular clarifier?
Are weirs level?
Is the site free ofweir blockage?
Is the site free of evidence of short-circuiting?
Is scum removal adequate?
Is the'site free of excessive floating sludge?
Is the drive unit operational?
Yes No NA NE,
Yes No NA NE
n 'n■n
. nnn
o nnm
n n■ri
O 0m0
IInnn
■ nnn:
• nnn
Yes No NA NE
■ n n °
•000
■ n, n, rn
O 000
li, n. n n
■ nnn'
�.nnn
o no
Page # 3

Permit: NC0003719 Owner - Facility: Cedar Creek Site
Inspection Date: 06/08/2006 Inspection Type: Compliance Evaluation
Secondary Clarifier
Is the retum rate acceptable (low turbulence)?
Is the overflow clear of excessive solids/pin floc?
Is the sludge blanket level acceptable? (Approximately'/ of the sidewall depth)
Comment:
Aeration Basins
Mode of operation
Type of aeration system
Is the -basin free of dead spots?
Are surface aerators and mixers operational?
Are the diffusers operational?
Is the foam the proper color for the treatment process?
Does the foam cover less than 25% of the basin's surface?
Is the DO level acceptable?
Is the DO level acceptable?(1.0 to.3.0 mg/I)
Comment:
Laboratory
Are field parameters performed by certified personnel or laboratory?
Are all other parameters(excluding field parameters) performed by a certified lab?
# Is the facility using a contract lab?
Is proper temperature set for sample storage (kept at 1.0 to 4.4 degrees Celsius)?
Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees?
Incubator (BOD) set to 20.0 degrees Celsius +/-,1.0 degrees?
Comment:
Flow Measurement - Effluent
# Is flow meter used for reporting?
Is flow meter calibrated annually?
Is the flow meter operational?
(If units are separated) Does the chart recorder match the flow meter?
Comment:
Record Keping
Yes No NA NE
• 000
■ n❑n
• 000
Yes No NA NE
Ext. Air
Surface
■ ❑nn
• 000
■ nnn
■ n❑❑
■ nnn
■ ❑ ❑ ❑
■ n.n❑
Yes No NA NE
■ ❑❑n
■ nnn
■ nnn
n ❑n■
o nio
n n■❑
Yes No NA NE
• 000
■nn❑
■ nnn
n n■n
Yes No NA NE
Page # 4

Permit: NC0003719
Inspection Date:06/08/2006 Inspection Type: Compliance Evaluation
Owner - Facility: Cedar Creek Site
Record Keeping
Arerecords kept and maintained as required by the permit?
Is all required information readily available, complete and current?
Are all records maintained for 3 years (lab. reg. required 5 years)?
Are analytical results consistent withdata reported on DMRs?
Is the chain -of -custody complete?
Dates, times and location of sampling
Name of individual performing the sampling
'Results of analysis and calibration
Dates of analysis
Name of person performing analyses
Transported COCs
Are DMRs complete: do they include all permit parameters?
Has the facility submitted its annual compliance report to users and DWQ?
(If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift?
Is the ORC visitation log available ,and current?
Is the ORC certified at grade equalto or, higher than,the'facility classification?
Is the backup operator certified at one grade less or greater than the facility classification?
Is a copy of the current NPDES permit available on site?
Facility has copy of:previous year's Annual Report on file for review?
Comment: 0
Yes No -NA NE
:non.
■r0.:QQ..
i`000-
00'0•
Q 0 0 •
n•
■ QQQ'
n.n■n
■ '.n-n.n
■00Q
▪ nn
u=n n n
n n n
. nn•■n.
Page # 5

Name of site to be Inspected:
Field certification # (if applicable):
1. Circle the parameter or parameters performed at this Site.- -
4W
Settleable Solids Conductivit
II. Instrumentation:
A Does the facility have the equipment necessary to analyze field parameters as circled above?
,
1. A pH meter C %Clui/ L4 No ,
. ,
• 2. A Residual Chlorine meter
3. DO meter :5- C
4. A Cone' for settleable solids
5. A thermometer or meter that measures temperature.
6. Conductivity meter Yes No
III. CalibrationlAnal sis: !
1. Is the pH rrieter:calibrated with a Uffers- and
checked with - • • ffer each day of xi Se? .
• .
2. For Total Resi,/ al Chlorine, is a check:standard
analyzed each day Of us
LO,
3. Is the air calibration of e DO meter performed
each day of use?
4. For Settleable SOlid§, is 1 literof Sample_ ,
settled for 1 hour?
5. Is the temperature measuring device calibrated
annually against a certified thermometer?
6. For Conductivity, is a calibration standard •
analyzed each day of use?
• Yes
es
•Yes
Yes
No
No
No
No
No
No
No
No
Or'

8. For Temperature;` is' the annual'calibration'°0
the:measuring ;device docurriented? •s
. Comments:. .
Please' submit a copy of this completed form _tothe Laborato
DWQ Lab .Certification
Chemistry Lab .
Courier # 52-01-01
FIELD INSPECTOR CHECKLIST REV. 04/23/2002
Certification Program.

#entloxicity Testing Self -Monitoring Summary,
1-FACILITY REQUIREMENT
May 16, 2006
YEAR JAN FED MAR APR MAY JUN JUL AUG SEP OCT NOV DEC
Cooksln GW Remediatlon System Chr. Lim: 90%
NC0088081/001 Begin:10/12005 Frequency: Q Jan Apr Jul Oct
County: Anson, Region: FRO Subbasin: YADIO
PF: 0.10 Special
7Q10: NA .IWC(%) 100 order.
Ceri7dPF 2002 -
+ NonComp: 2003 -
2004 --
2005 --
2006 NR/Pass
Come, Dept Of (McCain Hospital-001) chr lim: 67%
NC0035904/001 Begin:9/12004 Frequency: Q Jan Apr Jul Oct
County: HokeRegion: FRO Subbasin: LUM51
PF: 0.20 Special
7Q10: 0.15 IWC(%) 67.4 Order:
Ceri7dPF 2002 Pass - - Pass Pass - - Pass
+ NonComp:Single 2003 Pass - - Pass - - Pass - - Pass
2004 Pass - - Pass - - Pass - - Pass
2005 Pass - - Pass Pass - Pass
I 2006 Pass - - Pass
CP&L-Wtatherspoan/001 . 24 hr LC50 ac manit epis'flhd
NC0005363/001 Begin:11/1/2004 Frequency:5 OWD/A
County: Robeson. Region: FRO Subbasire LUM5l
PF: NA Special
7Q10: 122 . IWC(%) NA order.
Fthd24Ac t 2002 - - - - H
NonComp: 2003 - - -. -- - H
2004 =- - - - - H
2005 _- - - - - H
2006 - - -
DAK Americas, LLC = Cedar Creek Site r ' 24hr p/f ac lim: 90% tlhd (combined outfall) , Fthd24PF . Y 2002 - Pass - Pass - - - Pass - - Pass
NC0003719/002 Begim 1/1/1996 Frequency: Q P/F + Feb May Aug Nov NonComp:Single 2003 -- Pass - Fail Pass - Pass - Pass
County: Cumberland Region: FRO Subbasin: CPFI5 - 2004 - Pass - - Pass - - Pass - - Pass
PF: 1.3 Special 2005 - Pass - Pass - - Pass - Pass
7Q10: 791.0 IWC(%)0.25 order: - 2006 Pass
Dunn/Bluckrlvcr W WTP chr lim: I % Ceri7dPF 2002 -
NC0043176/001 Begin:7/l/2002 Frequency: Q Mar Jun Sep Dec + NonComp:Single 2003 - . -
County: Harnett Region: FRO Subbasin: CPF07 2004 Late Pass
PF: 3.75 Special 2005 >100(P)
7Q10: 586.6 IWC(%) 1.0 Order 2006 -
-
Pass - - Pass - - Pass - - Pass
Pass - - Pass - Pass - - Late
Pass -- - Pass - - Pass - - Pass
Pass >4(P) - Pass,>4.0(P) - - Pass >4.0(P) - - Pass
Pass
Dupont -.Fayetteville Works chr lim: 3.3%
NC0003573/001 Begin:2/1/2004 Frequency: Q , Feb May Aug Nov
County: Bladen Region: FRO Subbasin: CPF16
PF: 17 Special '
7Q10: 791.0 IWC(%) 3.3 Order
Ceri7dPF 2002 - Pass - - Pass - - Pass - Pass
+ NonComp:Single 2003 - Pass - - Pass - - Pass - Pass
2004 - Pass - Pass - - Pass - - Pass
2005 - Pass - Pass - - Pass - - Pass
2006 - Pass -
Dynapar Corp/004(comb 01,02,03) 24hr ac p/f lim: 90% tthd
NC0001121/004' Begin:1/1/2003 Frequency Q P/F + Mar Jun Sep Dec
County: Bladen Region: FRO Subbasin: CPFI6
PF: NA Special
7Q10: 812.5 IWC(%) NA Orders
Fthd24PF 2002 -- - Pass - -- Pass - Pass - - Pass
NonComp:Single 2003 - - Pass -- - Pass - Pass - - Pass
2004 - - Pass - - Pass - - Pass - _- Pass
2005 - - Pass - Pass - - Fail Fail Pass Pass
2006 - - Pass
Elizabethtown Power, LLC 241v ac p/flim: 90%
NC0058297/003 Begin:11/1/2002 Frequency: Q P/F + Mar Jun Sep Dec
County: Bladen Region: FRO Subbasin: CPF16
•
PF: NA Special
7QI0: 740.0 IWC(%) 0.03 Order:
Fthd24PF 2002 - - Pass - - Pass - Pass - - Pass
NonComp:Single 2003 - - Pass - Pass - - Pass - - Pass
_ 2004 -- - Pass - Pass - - Pass - - Pass
2005 - - Pass - - H - Pass H - -- Pass
2006 - - H
Elizabethtown WWTP chr lim: 4.6% Ceri7dPF 2002 -
NC0026671/001 Begin:1/1/2004 Frequency: Q Mar Jun Sep Dec + NonComp:Single 2003 -
County: Bladen Region: FRO. Subbasin: CPF16 2004 -
PF: 1.225 Special 2005 -
7Q10:815 IWC(%)4.6 outer. , 2006 --
- Pass . - - Pass - - Pass - - Pass
- Late Pass - Pass - - Pass - - Pass
- Pass - - Pass - Pass - - Pass
- Pass>9.2(P) - Pass>9.2(P) - - Pass>9.2(P) - - Pass>9.2(P)
- Pass
Ellerbe WWTP chr lim: 61% Ceri7dPF 2002 Fail >100 >100 Fail,>100 -- <15.25 Pass - - Fail 69.9 69.9
NC0021784/001 Begin:3/1/1999 Frequency:Q Jan Apr Jul Oct + NonComp:Single 2003 Pass - -- Pass - - Pass - Pass -- -
County: Richmond Region: FRO Subbasin: YADIO 2004 Pass - - Pass - - Pass - - Pass -
-
PF: 0.18 Special 2005 Fell >100 >100 Fail >100 >100 Pass - - Pass -
_
7Q10: 0.18 IWC(%) 61.0 Order. 2006 Pass - --
ErwinWWTP chr lim: 0.32% - Ceri7dPF 2002 70.5
NC0064521/001 Begin:4/1/2002 Frequency: Q + Jan Apr Jul Oct NonComp:Single 2003 Pass
County: Harnett Region: FRO Subbasin: CPF07 2004 Late
PF: 1.2 Special 2005 Pass>t(P)
7Q10: 586 IWC(%) 0.32 Order. 2006 Pass
Pa- ss
Pass - Pass
- Pass - - Pass
- Pass - - Pass
- Late Pass>1(P) - NR/Paest
- - Late Pass
- Pass -
- Pass -
- Pass >1(P), -
Y Pre 2002 Data Available
LEGEND: .
PERM = Permit Requirement LET = Administrative Letter- Target Frequency = Monitoring frequency: Q- Quarterly; M- Monthly; BM- Bimonthly; SA- Semiannually; A- Annually; OWD- Only when discharging; D- Discontinued monitoring requirement
Begin = First month required 7Q10 = Receiving stream low flow criterion (efs) += quarterly monitoring increases to monthly upon failure or NR Months that testing must occur - ex. Jan, Apr, Jul, Oct NonComp = Current Compliance Requirement
PF = Permitted flow (MGD) IWC% = lnstream waste concentration P/F = Pass/Fail test AC = Acute. CHR= Chronic
Data Notation:f- Fathead Minnow; • - Ceriodaphnia sp.; my - Mysid shrimp; ChV - Chronic value; P - Mortality of stated percentage at highest concentration; at - Performed by DWQ Aquatic Tox Unit; bt - Bad test
Reporting Notation: --= Data not required; NR - Not reported Facility Activity Status: 1- Inactive, N -Newly Issued(To construct); H - Active but not discharging; f-More data available for month in question; = ORC signature needed
2

January 16, 2003
YEAR JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC
Whole Effluent Toxicity Testing Self -Monitoring Summary
FACILITY REQUIREMENT
BayettevIlls-Rochlish WWTP - ' ' chr lim:. 3.5%
NC0050105/001 degin:11/1/2002' FrequencY: Q ' * • - Jen Apo Jul Oct
County: Cumberland ' Region: FRO Subbasin: CP1,15
PR 16.0 ', - - : specid.'
7Q10: 675.0 IWC(%) 3.5 - Order:
y 1999 Pass '
H&C-amp:Single • , 2000 Pass
2001 Pass ' -.-
2002 pass
2003
Pass - ••• '
' Pass
Pass 7
Pass
•
`Piss
Pass
Pass
Fall
Pass
- - Pass
Pass
>14 >14 • Lata
Pass
-
Fort Bragg WWTP/001 chr lim: 26%'
NC0003964/001 Begin:8/1/2001 Frequency: Q . Ian Apr Jul Oct,
County: Cumberland: Region: FRO ' Subbasin: CPF14
' PF: 8.0.: " Spacial. . ' : . -
' 1Q10:,35.8 • - IWC(%)26 Order: . -
. . -
Hamlet WWIH. ".. , chr lira: 38% "
NC0047562/001 . Begin:7/1/1999 Frequency: Q P/F . + Jan Apr Jul Oct
County: Richmond Region: FRO Subliasin: YAD16
PF: 1.0 , .- , . Special
7Q10: 2.5 • ': . TWC(%) 38.27 . Ord.: ..
+ NonComp:Single
• 1999 Pass
2000 Pass,
2001 Pass
' 2002 ' pass
2003
•
• Pass
Pass
NR
Pass
Pass
Pass
Pass
- .
Pass
Pass
Pass
•
+ NonComp:Single
1999 Pass "
- 2000 Late
-
2001 Pais
2002 pass
2003
Pass
• ' Pass '
Pass •`
Pass
Pass
PaissIg- "
- Pass
- Paps
- - PaSs
Pass,
Pass
Indusirlallic Agilcultural Chentleals • 48HRLC50 AC MONIT'CERIO'OR DAPH (GRAB) STORM
NC0000236/001 Begin:21.1/1994 Frequency: 2/YR: : Semiannual . . NonComp:
County; Robeson - ' Region: -FRO Subbasin: LU1v152
PF: VAR Special • '
.7Q10:- 0. IWC(%) NA Orden
J.P. Stevens-Wagram . chr lim: 9%
NC0005762/001 Begin:1/1/2001 Frequency: Q Feb May Aug Nov + NonComp:Siugle
County: Scotland • Region: FRO Subbasin: LUMSI
_
PF: 7.0 .. ,..... .. , _ -
7Q10: 117 ' . TWC(35) 9.0 . Orde+, - • ,
LattrInburg Maxton Alrpori•Laurel H111 du lim: 1.5%
. • NC00054791001 Begin:12/l/1999 Frequency: Q P/F Mar`lim Sep Dee
,.
Comity: Scotland - Region; FRO Subbasin: LUM55-
PF: 0.3 - Special
7Q10: 31.0 IWC(%) 1.5 • ' Ot'dm •
1999 --
2000
2001 --
20D2
2003
<12.5'
<3.125
. • -
_ 9.15 _ .
11.3 - NR
y 1999
2001 -
2002 -
2003
Pass _ L.
Fall
Pass
, Pass .
Pass
Pass
Fail
Pass
Pass
25.5
• -. Pass
25.5 ' Pass .
... , Pass
-- Pass
'Pass
Pass
Pass
Pass
+ NonCompsS in gl c
y 1999 --
2002 .-
2003"
Pass
- Pass
Pass'
Bt
Pass
Pass
_Pass
et '
Pass
Pass- -
Pass -
'Pass ' Pass
Pass
Pass
LaurInburg VVWTP. - . chr line: 31% .
NO3020656/001 'Begin:3/1/2001 Frequency: Q - Feb MayAug Nov 4" NonComp:Single
County:Scolland Region: FRO Subbasin: LUM55
PF: 4.0 - . Special
7Q10: 13.8 IWC(%) 31 Orden:
. -
1999 -- ,
2000 --
2001 --
2002"
2003 : •
Peg.
>so
Pass
Pass
tate
Pass
- . Pass
Pass
Pass
- Fall
Bt. -
- -. Pass
- Pass
Fall
Pass
Pass ' Pass
Pass
- - Pass
Pass
..
Latirinburg•Maxion Airport clu lim: 1.3%; if pf 2MGD chr lim 2.6%
NC0044725/001 Begin:3/1/2000 Frequency: Q Mar Jun Sep Dec + NonComp:Single
County: Scotland . . , Region: FRO ' Subbasin: LUMSI
PF: 1.0 - Special - .:
7Q10: 111.0 IWC(%) 1.38 . Order: - t
1999
2001 ,
2002
2003.
- Pass 7- •
Pass
Fall 1.94 3.68
91
Pass
Pass'
- Pass
• .
---
,_
Pass '
Pais
-
Pass
Pass
Pass
Pass
' Libbey-Owens Ford Co. ' . 24 hr p/f ac Ian: 90% fthd (grab) - -
NC0049514/001 Begin:12/1/1999 Frequency: Q P/F + Jan Apr Jul Oct . + NonComp:Siugle
County: Scotland - Region: FRO Subbasin: LUM55
PF: VAR ' • . . Special .
7Q10: 0.0 . IWC(%) 100 , Order:
1999 - '
2000 Late
2001 Pass
2002 H
2003
Pass
Pass
. _ •
, Pass
•Pass
Pass
Pass
. .• ' Pass
- Pass
14
Pass
Pass
14
Pass
Pass
- •
Lumberton WWTP., clic lint.21% , . " ' • .
' . HC0024571/001 Begin:1/1/2001 Frequency Q , Feb May Aug Nciv 7 + NonComp:Siogle"
•:' Comty:.Ttobesori. , Region: FRO Subbasin: LUMSI ,
Special
' .• .. ', 7Q10.„120,.,: ..-..IWC(%) 21 ' - Orden_
y 1999
2000
2001
2002 .-
2003
„Pass
Pass -
Pass
Pass
Pass
Pass • Pass
- - Pass
. . ... -
, - i',', MonsaMO/001,002 ".:`,;•.2,?...,.".
.• ' 241t/f-tieli9,6%-illid(cOmbined.Ohtfall) .
NC0003719/002 Begin: 1/1/1996' Frequency: QP/F -li Feb May Aug Nov NonComp:Single -
-..- ' ' . • ConntylCuMbrIruid ' Regain: FRO Subbasin: CPF15
''''• ' ' ' • Bawls! "
•• . ' 70.0: 791.0 - .., f IWC(%)13.2.5. • Ord,,: -
•
y 1999 -
2000 --
2001 --
2002 -
2003
Pass,
Pass
Pass -
Pass - •••
Late
- Pass
Pass
.Pass
Pass
Pass
Fa. '
• . Pass
Pass
Pass
PassPass
Pass
Pass
Pass"
Pass
Pass
Pass
Pass
Pass
• •
8 Pre 1999. Bata Available •
. -
. .
• ,, - , • .
. .
. .
' • LEGEND:., • - - .. _ . . . .
PERM w Pain* Requirement ..- LET w Administrative Letter - Target . ' Frequency •• Monitonng frequency: Q- Quarterly; M- Misnthly; BM- Bimonthly; SA- Semianniially, A. Annually; OWD- Only when discharging; D- Discontinued' monitoring requircuient .
Begin - First month requJrc4 '-:7Q10 = Receiving stream low. flow criterion (cfs) + •• quarterly monitoring increases to monthly upon failure or NR Months that testing must occur - ex. Jan, Apr, Jul, Oct . - - NonComp w Current Compliance Requirement
PF - Permitted flow GDy:' IWC%- lost:ream 'waste concentration, '. - - P/F w pais/Fail test . • ' ..: AC Acute, • CHR - Chronic .
Data Notation: f Fathead-MinnoW;•:--Ceriodaphniiesg.; My. Mysid shrimp; ChV - Chronic value ; P - Mortality of stated percentage at highest concentration; at - Performed by DWQ Aquatic Tox Unit; bt - Bad test
Repelling Notation: - - Data not required; NR . Not reported Facility Activity Status:1 - Inactive. N'.• Newly Issued(To construct); H - Active but not discharging; l•-More data available for inonth in question; • .- ORC signature needed
. 3

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
OUTFALL: 002
EFFLUENT
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 13 OF 22
00010
deg c
.Temperature,
Water Deg.
Centigrade -
00300
mg/1
DO, Oxygen,
Dissolved
00310
lbs/day
SOD, 5-Day (20
Deg. C)
00340
lbs/day
COD, Oxygen
Demand, Chem.
(High Level)
00400
su
pH
00530
lbs/day
Solids, Total
Suspended
00600
mg/1
Nitrogen, Total
(as N)
00610
lbs/day
Nitrogen,
Ammonia Total
(as N)
43.4
72.5
70
1 -05
16.375
9.05
2.9
90.95
6.7 - 8.1
8.9
2.3
43.4
72.5
70
2-05
17.7
9.375
3.325
55.225
7.5 - 7.8
6.1
1.2
0
43.4
72.5
70
3-05
17.6
8.58
4.02
77.16
6.8 - 7.9
9.92
1.266
43.4
72.5
35
4-05
20.725
8.725
8.625
136.35
7.3 - 7.4
17.45
0
43.4
72.5
35
5-04
25.325
7.1
5.275
65.525
8.1 - 8.3
16.65
2
1.185
43.4
72.5
35 •
6-04
27.4
7.64
9.3
153.04
8.1 - 8.3
15.32
4.88
•
43.4
72.5
35
7-04
-
29
6.95
11.8
131.425
8.1 - 8.3
26.8
0.85
43.4
72.5
35
8-04
27.6
7.575
7.96
132.06
8 - 8.3
30.2
38.8
0
43.4
72.5
35
9-04
23.88
8.32
8.75
121.1
7.6 - 8
10.925
0.4675
43.4
72.5
35
10-04
21.075
8.25
2.975
8 - 8.2 .
4.575
1.235
43.4
72.5
70
11-04
19.25
8.825
9.86
96.54
7.5 - 8.1
6.48
2.7
3.904
43.4
72.5
70
12-04
16.2
9.42
2.475
93.825
7.1 - 8.1
7.275
3.435

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site CITY: E Fayetteville
COUNTY: Cumberland
. PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 14 OF 22
00665'
ing/1
Phosphorus,
Total (as P)
00720
lbs/day
Cyanide, Total
(as Cn)
01034`
lbs/day -
Chromium, Total
(as_r) . - _
C
01042
1bs/day
,Copper, Total
(as
_
01051
lbs/day
Lead, Total (as
Pb)
01067,
lbs/day
Nickel, Total
(as Ni) •
01092 -
lbs/day
Zinc, Total. (as
Zn) ,
31616
.#/100m1
Coliform, Fecal
MF, M-FC
Broth, 44.5C
1 - 05
•
0.763
2.017
2.625
0. ?82
3.071
-
1
2-05
0.203
0.763
2.017
-
2.635
0.582
-
3.071
4.212866
. 3-05
0.763 ..
2.017 •
2.635-
=
a 582 '
3,071 -
1.9'33182
• -4-05
0.763-
-
2.017 - -
2.635
0.582 - -
3.071 .,
. 21.041422
5-04.
1
0.763 -- .
0
2.017 -
0 -
2.635
0•
0,582
0
3.071
0.006
0.01
1.565085
6-04
0.763
2..017 ' - .
2.635
.
0.582 '
3.071
.
7.004617
7-04
. 0.763
2.01'7- •
' 2.635 - '
0.582 r
3.071
1.86121
'8-04
0.2
0.763
2.017 -.
2.635
0.582
-
3.071 ,
-
-
4.728708
9-- 04
0.763
-2.017
2:635
0.582 - -
3.071 '
-
. -
13.429397
10-04
.0.763
2.017
.
2.635
-
0.582 . .
3.071 -
5.243611
-.11 - 04
0
0.763
2.017
-
2.635
-
6.582
-
3.071
-
0.
12-04
0.763
2.017
2.635
0.582
-
3.071
7.832804 ' -

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 15 OF 22
32102
lbs/day
Carbon
Tetrachloride
32103
lbs/day
1,2-dichloroetha
ne
32106
lbs/day
Chloroform
34010
lbs/day
Toluene
34030
lbs/day
Benzene
34200
lbs/day
Acenaphthylene
34205
lbs/day
Acenaphthene
34215
lbs/day
Acrylonitrile
1 -05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
•
2-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
3-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
4-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
5.- 04
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0,174
6-04
0.033
0.124 .
0.038
0.047 .
0.067
0.04
0.04
0.174
7-04
0.033
0.124
0.038
0.047
0.067
0.04
0.04 -
0.174
8-04
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
9-04
0.033
.
0.124
0.038
0.047
0.067
0.04
0.04
0.174
10-04
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
11 -04
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
12-04
0.033
0.124
0.036
0.047
0.067
0.04
0.04
0.174

PERMIT NUMBER: NC0003719
• FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY:. EFayetteVillc
COUNTY:. Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 16 OF 22 -
.....
: .
34220
lbs/day • :
Anthracene
. - -
.
34242
lbstday '
Benzo(K)fluorant
hene
.
34247
lbs/day
-Benzo(A)pyrene.,
34301
lbs/day. ,
'Chlorobenzene ,
39311
lbs/day -',
TChlcroethane
.
:
34320
lbs/day
Chrl;sene
-
_
.
34336
lbs/day
Diethyl •
Phthalate' '
:
39341
lbs/day
Dimethyl'
- Phthalate
'
.
'
- 1
- 95
0- . ,04 -
0.04
0,042
;_
- -
0.027
•
0.189
. . '
'
0.04
''
--0.147
0,035 ,
•
2
- 05
0.04 "
• 0.04 -
0.042 .
0.027
'.
0.189
0,04
•
.
.
0.147
.
- 0.035 . -
3
- 05
0.04 . •
0.04 -.
0.042 . ,
0.027
-
0.189 .
.•
0.04
-
.0.147 ..
,
.
0,035
.
. •
.
4
- 05
. ,
0,04
0.04 .
0.042. "
-
0.027 _
0.189
:.
0.04
-
,
.
0.147
. .
...•
0.035
,
..
5
04 •
0.04
- _
0.04- . ,
.
0.042 ,
-.
_,
,0.027
0,189
0.04
0.147 .
0.035 . - --.'
6
_
- 04 -
0.04 .
.
0.04 .
.
0:042 -
.
0.027
: 0.169 .
-
0.04
.
0.147
• .
0.035
7
- 04
0.04 . -
0.04
0.042
0.027
•.
- 0'1 . ,9
' .
,
0.04 :
_
..
0.147
-,
-
•. ,
.0.035 -
• "
• 8
- o4
0,04
0.04 • -
0.042
0.027
0.189
.
0.04
'
0.147
- -
0.035
9
- 04
0.04 -.- . .
0.04 •
.
0.042 .
-. ,"
0.027
.
0,189
,
. 0.04 '
,
•- •
0.14-7 .
-
-,
0,035 '
,
.
•
. 10
- 04
0.04
- .
0.04 . •
0.0:42 --.
'
0.027
.
.
0.189
0.04
'
0.147
'
0.035
.
11
- 04
0.04 ,
- . .
0.04 '
.
" 0.042
04)27
.. ,
0.189 ,
-
:
- 0.04 -
t
' 0447
.
" 0.035
12
- 04
0.04 -
0.04
. 0.042
0.027
0.1 89
. _
• 0,04
..
-
0.147
. '
0.035
.
.

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 17 OF 22
34371
lbs/day
Ethylbenzene
34376
lbs/day
'Fluoranthene
34381
lbs/day
Fluorene
34396
lbs/day
Hexachloroethane
34418
lbs/day
Methyl Chloride
(chloromethane )
34423
lbs/day
Methylene
Chloride
(dichloromethane
chlhoride)ylene
dimet
34447
lbs/day
Nitrobenzene
34461
lbs/day
Phenanthrene
1-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
• 0.04 -
2-05
0,058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
- 3-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
4-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
5-04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
6-04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
7-04
0.058
0.045
0.04
0.033
0.156
0.073 - -
0.049
0.04
8-04
0.058
0.045
0,04
0.038
0.156
0.073
0.049
0.04
9-04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
10-04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
11 -04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
12-04
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0,04

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC -Cedar Creek Site
CITY: EFayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR .12 Month Calculated
• PAGE 18 OF 22
-
34469
lbs/day -
Pyrene
34475
lbs/day
Tetrachloroethyl
ene -
34496
lbs/day
1,1-dichloroetha.
ne
-
34501
lbs/day
1,1-dichloroethy
lene
34506
lbs/day
1,1,1-trichloro-
ethane '_
_"
34511
lbs/day
•1,1-,2-trichloro-
ethane
34526
lbs/day
Benzo(A)anthrace
ne
34536
lbs/day
1,2-dichlorobenz
ene -
(ortho-dichlorob
enzene;
1,2-DCB)
1 -05
0.045
.0.04'
0.04- -
0:029
0.038
0.038
•
J
0.04
0,14
2-05
0.045
0.04
0.04 .
0.029 .
.
0.038
0.038
0.04
0.14
3-05
0.045 -
0.04
0.04 " . -
0.029
0.038 ..
" 0.038
-
0.04
0 14
4-05
0.045
0.04
0.04
0.029
0.038
0.038
0.04 '
0.14
5104
0.045 -
0.04
. 0.04
' 0.029
0.038
0.038
0.04'
. 0.14
6-04
0.045 -
• 0.04
0.04
0.029
" 0.038 •0.038
•
0.04
0,14
-7_04.
- 0,045
-.
0.04
0, 04
0:029
• • 0.038
0.038
,
0.04
0.14
8-04
0.045
•
0.04
0,04
0.029
•
0.0'98
0.038
- -
0.04
0.14"
.9-04
0.045
0.04
0.04
0.029
- 0.038
0.038
-
0.04
0.14 - .
10-04
0.045
• -
0.04
0.04
0.029
0.038
0.038
0.04
0.14
.11-04
0.045
0.04
0.04
.0.029
0.038 -
0.038
•
-0.04 .
0,14
12-04
0.045
0.04
0-04
0,029
0.038
0.038
-
0.04
0.14

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: EFayettev'lle
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 19 OF 22
39591
1bs/day
1,2-dichloroprop
ane
34546
lbs/day
1,2-trans-dichlo
ro- ethylene
39551
lbs/day
1,2,4-trichloro-
benzene
34566
lbs/day
1,3-dichlorobenz
ene
(meta-dichlorobe
nzene;
-1,3-DCB)
34571
lbs/day
1,4-dichlorobenz
ene
(pars-dichlorobe
nzene;
1,4-DCB)
39586
lbs/day
2-chlorophenol
34591
lbs/day
2 -ni trophenol
34601
lbs/day
2,4-dichlorophen
of
1 -05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
2-05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
3-05
0.278
0.038
0.12.4
0.056
0.027
0.056
0.07,E
0.071
4-05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
5-04
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
6-04
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
7-04
0.278
0.038 -
0.124
0.056
0.027 -
0.056 - -
0.075--
0.071
8-04
0.278
0.038
0.124
0. 056
0,027
0.056
0.075
0.071
9-04
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
10-04
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
11 -04
0.278
0.038
0.124
0,056
0.027
0.056
0.075
0.071
12-04
0.278
0.038
0.124
0.056
0.0.27
0.056
0.075
0.071

PERMIT NUMBER: NC0003719
:FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: EFayetteville
COUNTY: Cumberland --
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 20 OF22
34606
lbs/day
,2,4-dimethylphen
of
34611
lbs/day
2,4-dinitr_otolue
ne, -
34616
lbs/day,
2,4-dinitropheno
1 .
34626 ,
lbs/day ,
2;6-dinitrotolue
ne
34646
lbs/day -
4-nitrophenol
-
34657
lbs/day •
4,6-dinitro-o-cr
esol
34694
lbs/day
Phenol,' Single
,Compound''
34696, ,
lbs/day
Naphthalene
•
1 - 05 •
0.033
0.205
0.129
0.463
0.131 ,
0.142
0.027 .
0.04
2-05
0.033
0.205
0.129
0.463
0.13.1
.0.142.
0.027
,
0.04
-3-05
0.033
0.205
0.129
0.463
0.131
0.142
;.
0.027
. 0.04
4-05'
0.033
0.205
0.129
0.463
0.131
0.142
-0.027
0.04
5-04
. 0,033
0.205 ,
0.129
0.463 "
0.-131
0.142
0.027
"
0.04
6-04
0.033
0.205
0:129
0.463
0.131
0.142
-
0.027
0.04
7-04
0.033
0.205
0.129
0.463'
0.131
0.142
.
0.027
0.04
8-04
0.033
0.205
0.129
-
0.463
0.131
0.142
0,027
0.04
-
9 04
0.033 - - :
0.205
0.,129
0.463 . -
0.131
,
_ 0.142
0.027
.
0.04 .
10-04
0.033
•
0.205 '
0.129
.
0.463
0.131
0.142
0.027
:0.04
11 04
0,033 -
0.205
- 0.129
0.463
0.131
_0.142
.
-.
DMR 12 Month Calcul
12-04
' 0.033
0.205 -.
PERMIT NUMBER: NC0003719 Cedar Creek Site
or.ILITY NAME: DAY.Americas, LLC
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
39702
39941
mg/1
ated
PAGE.21 Ur,22
50050
mgd
Flow, in -thru
or _
39'700

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 21 OF 22
39100
lbs/day
Bis
(2-Ethylhexyl)
Phthalate
(di(2-ethylhexyl
)phthalate)
39110
lbs/day
Di-n-Butyl
Phthalate
39175
lbs/day
Vinyl Chloride
39180
lbs/day
Trichloroethylen
e
39700
ug/1
Hexachlorobenzen
e
39702
lbs/day
Hexachlorobutadi
ene
39941
mg/1
Roundup
50050
mgd
Flow, in
conduit or thru
treatment plant
0,187 --
0.099
0.189
0.038
0.036
0.5
1 -05
0.19271
0.187
0.049
0.189
0.038
0.036
0.5
2-05
0.182786
0.187
0.049
0.189
0.038
0.036
0.5
3-05
0.181129
0.187
0.049
0.189
0.038
0.036
0.5
4-05
0.172533
0.187
0.049
0.189
0.038
0.036
0.5
5-04
0.193032
0.187
0.049
0.189
0.038
0.036
0.5
6-04
-
0.300867
0.187
0.049
-0.189 -
0.038
0.036 -
- -
- 0.5
7-04
0.303774
0.187
0.049
0.189
0.038
0.036
0.5
8-04
0.333
0.187
0.049
0.189
0.038
0.036
0.5
9-04
0.3568
0.187
0.049
0.189
0.038
0.036
0.5
10-04
0.2024
0.187
0.049
0.189
0.038
0.036
0.5
11-04
0.190233
0.187
0.049
0.189
0.038
0.036
0.5
12-04
0.178767

PERMIT NUMBER: NC00037-19
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
. CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2005 DMR 12 Month Calculated
PAGE 22 OF 22
50060
ug/L
Chlorine, Total
Residual •
77163
lbs/day
1,3
-dichloropropene '
79531
lbs/day
3,4 ,'
Ben'zofluoran-The
ne
TGE6C
pass/fail
P/F STAT 24hr
Acu Pimephales ,
1-05
0.053
0.042
- 2-05
0.053 -
0.042
1
•3,-05
•
0.053
_- •
, 0.042
-
4-05
0 .
0.053
0.042 •.
.
•
- 5-04-
0.053
0:042 -
6-04
0
0.053
0.042 .
7-04
.0,053
0.042 •
...
8-- 04
.0, 053
0:042
1
9.-04
0.052
0.053 -
-
0.042
"--
.
10-04
0.053
.
0.042 .
11 -04
0
•
-0.053 -
0-042
1
.12-04
0
0.053 -
0.042
-
REGION: Fayetteville

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
OUTFALL: 002
EFFLUENT
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 13 OF 22
00010
deg c
Temperature,
Water Deg.
Centigrade
00300
mg/1
DO, Oxygen,
Dissolved
00310
lbs/day
BOD, 5-Day (20
Deg. C)
00340
lbs/day
COD, Oxygen
Demand, Chem.
(High Level)
00400
su
pH
00530
lbs/day
Solids, Total
Suspended
00600
mg/1
Nitrogen, Total
(as N)
00610
lbs/day
Nittro9en,
Ammonia Total
(as N)
43.4
72.5
70
1 -06
•
18.7
9.05
6.56
94.84
6.4 - 7.1
19.96
0
43.4
72.5
70
2-06
16.75
9.4
2.025
6.4 - 7.2
6.55
6.2
0
43.4
72.5
70
3-06
18.88
9.14
2.9
102.05
6.7 - 7.5
13.175
0
43.4
72.5
35
4-06
20.875
•8.45
0
56.1
7 - 7.7
4.85
0.78
43.4
72.5
35
5-05
19.7
8.566667
7.075
123.25
6.6 - 7.9
25.35
2.2
0.5125
43.4
72.5
35
6-05
23.64
7.94
8.9
134.05
6.5 - 7.4 •
20
0.335
43.4
72.5
35
7-05
•
28.05
7.75
0.875
132.75
6.1 - 7.1
7.45
0
43.4
72.5
35
8-05
26.7
7.74
4.12
86.78
6.9 - 7.4
8.6
1.8
0.92
43.4
72.5
35
9-05.
25.1
7.875
2.325
82
6.6 - 7.6
3.825
4.3575
43.4
72.5
35
10-05
20.975
8.475
.3.625
76.8
6.2 - 6.9
7.075
0
43.4
72.5
70
11-05
21.14
8.62
2.84
66.48
6.04 - 7.2
5.98
13.6
2.95
12 05
43.4
72.5
70
17.575
9.675
3.3
91.35
6.6 - 7.4
11.2
0

PERMIT NUMBER: NC0003719
FACILITY NAME: "DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated,'
PAGE 14 OF22
00665
mg/1
Phosphorus,
Total (as P)
00720 •
lbs/day
Cyanide, Total
(as Cn)
01034
-lbs/day
Chromium,
(as Cr)-
Total
01042
lbs/day -
Copper, Total
(as Cu)
-01051
lbs/day
,Lead, Total (as
Pb)
01067
lbs%day
Nickel,
(as Ni)
Total
01092
1bs/day
Zinc, Total
Zn)
(as
31616
#/100m1
Conform, Fecal
MF, M-FC
Broth,44.5C
1-06
0.763 -
• _
2.017
2:635
0.582
3.071
-
..
2.59002
2-06
0.2
0.763
0
2.017
0
2.635 '
0 -
0.562
0 .
3.071-
0
.
0.036
2
' 2.828427
3-06
0.763
2.017
•
2.635
2.592013
4-06
.
0.763
2.017
2.635 -
0.582
=
-
4.391731
5-05
2.9 ,
0.763- -
0
2.017
0
2.635
'0 -
0.582
0
, 3.071
0
-
0.026 -
."13.869536
6-05
0.763 •
2.017
2.635
0.582
3.071
17.630696
7-05_
0.763
2.017
"
2.635 -
0.582
3.071
-
=
-
7.613508
8-05
- .
-
2.5 - -
0.763
-
0. -
2.017
0, .
2.635
0.009 - -
0.582
0
3.071
0
- .
-
0.049
8.338811
9' .05
'0.763
2,017.
__
2.635
0.582
3.071
."' .
5.346327
•
10-05
0.763
2.017
2.635
0.582
3.071
-
27.243313
11-05
1.4
0.763
0
2.017
0
2.635
0
0.582
0
3.071
0.009
'
0.039
-
2.459509
12=05
- 0.763
2.017
, 2.635
" 0.582
' 3.071
.
5.711306

PERMIT NUMBER: NC0003719
FACILITY NAME: •DAK Americas, LLC - Cedar Creek Site
CITY: EFayettev'lle
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 15 OF 22
32102
lbs/day
Carbon
Tetrachloride
32103
lbs/day
1,2-dichloroetha
ne
32106
lbs/day
Chloroform
•
34010
lbs/day
Toluene
34030
lbs/day
Benzene
34200
lbs/day
Acenaphthylene
34205
lbs/day
Acenaphthene
34215
lbs/day
Acrylonitrile
1 - 06
0,033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
2-06
0.033
0.124
0.038
0.047
0.067
0,04
0.04
0.174
3-06
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
4-06
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
5-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
6-05
0.033
0.124
0.038
0.047
0.067
0.04
0,04
0.174
7-05
0,033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
8-05
0.033
0
0.124
0
0.038
0
0.047
0
0.067
0
0.04
0•
0.04
0
0.174
0
9'-05
0.033
0. 124
0.038
0.047
0.067
0.04
0.04
0.174
10-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174
11 -05
0.033
0.124
0.038
0.047
6.067
0.04
0.04
0.174
12-05
0.033
0.124
0.038
0.047
0.067
0.04
0.04
0.174

. PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E fayetteVille
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 MonthCalculated
PAGE 16' OF 22
.
.34220
lbs/day
Anthracene
.
..
34242
lbs/day
Benzo(K)fluorant
hene
34247
lbs/day .
Benzo(A)pyrene
.
34301
1bs/5Iay
Chlorobenzene.
.
.
,
34311 ..
lbs/day ' -
Chloroethane
•
34320 ' .
lbs/day
Chrysene
• . '
•
- .
34336
lbs/day
Diethyl
Phthalate .
34341
lbs/day
Dimethyl
Phthalate
-
1 - 06
0.04
.
0.04
0.042 ' .,
0.027
'
.
0.189 ,
- -..• _
0.04
,
_ •
..
0.147 -
0.035
-
•
2 - 06
0.04
•
.
0.04
.
.....
' 0,042
0.027
.
0.189
.
0.04 •
0.147
0.035
-
-06
0.04
•
'
.
'
0.04-
-
..
0.042
0.027
.'
0,189 .
0.04
0.147
0.035
4 - 06
0.04
0.04 •
0.042
0.027
-
0.189
0.04
,
_
...
0.147
0.035
• •
5 2'05
0.04
.-' •
0.04 . .
' ,
0.042
_
0.027
.
•
0.189
-
0.04
.
0.147
.
0.035
6 - 05.
0.04
-
. .
0.04,•
.
,
0.042 .
0.027
,
0.189.
0.04
.
0.147 ,
.
0.0.35:
-
- - 7 - 05
0.04
•
•
'
, .
.-.
004
,
•
•
0.04,2 .
0.189 . -
0.04
0147
-
0 .035
-
805
0.04
_
0
0.04
.
.
0.042
0
0.027
Q
'
0.189 '
0 ,
0.04
0.147
0
0.035
0
'
• 9 - 05
_ .. _ •
0.04
• - .
.
. 0.04
. .
0.042
_ .
0.027
.
. _
.
0.189
.
.. .
0.04 -..
- 0,147 =
_
0.035 . ..
.
..
_
.
-10 - 05 '
.0.04
..
.
0.04
.--
0.042
0.027
0.189
0.04
_
0.147
0.035
.
.--
0.04
. ,
• -
:
.
0.04
.
0.042
0.027
,
-
0.189 . -
0.04 ;
_
,
-
• 0.147
.0.035 . - .‘
12 - 05
.
.
: 0,04 .
-
0.042
0.027
•
0.189
0.04
0.147 . .
0.035

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 17 OF 22
•
34371
1bs/day
Ethylbenzene•
34376
1bs/day
Fluoranthene
34381
lbs/day
Fluorene
34396
lbs/day
Hexachloroethane
34418
lbs/day
Methyl Chloride
(chloromethane )
34423
lbs/day
Methylene
Chloride
(dichloromethane
methylene
dichloride) -
34447
lbs/day -
Nitrobenzene
34461
lbs/day
Phenanthrene
1 -'06
0.058
0.045
0.04
0.038
0,156
0.073 .
0.049
0.04
2-06
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
3-06
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
4-06
0.058
•
.0.045
0.04
0.038
0.156
0.073
0.049
0.04
5 - 05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
6-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
'
7-05
0.058 -
0.045
0.04 -
- 0.038
0.156 -
0.073
0.049--
0.04
8-05
'0
0.058
0.045
0
0,04
0.
0.038
0
0.156
0
0.073
0
0.049
0
0.04
0
9-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
10-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04
11-05
0.058
0.045
0.04
0.038
0.156
•
0.073
0.049
0.04
12-05
0.058
0.045
0.04
0.038
0.156
0.073
0.049
0.04

• PERMIT NUMBER: NC0003719
FACILITY NAME: 'DMZ. Americas, ELC - Cedar.Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 18 OF 22
-
34469
lbs/day
Pyrene
-
.
. . .
34475
lbs/day
Tetrachloroethyl
ene
•
'
.
34496
lbs/day
1,1-dichloroetha
ne- -
_ _
34501
lbs/day ..
1,1-dichloroethy
-lene - .-..
,
34506
lbs/day
1,1,1-trichloro-
ethane
• • ,
.
34511
lbs/day
-1,1,2trichloro-
ethane . _
,
..
.
.
34526
lbs/day
Benzo(A)anthrace
ne ' _ - - -
-
34536 `--
lbs/day
‘1,2-dichlorobenz
ene
(ortho-clichlorob
•enzene;
1,2-DCB)
_
.
6
1 - 0•
0.045
.
0.04
0.04
. 0.029
.
0.038
0.038
.
•
0.04
• 0.14
2 - 06
0.045
_ •
0.04 .
•
0.04
.
.. . •
,
10.029
_
. ...
" 0.038
- '
0.088 •
..
-
0:04
0.14
3 - 06
0.045
.
0.04
_ ._
0,04
_
0.029
,.:.
'
'
0.:038
0.038 •
'
0.04 - -
. 0.14
4 - 06
0.045
'
0.04
0.04
0.029
0.038
0.038
0.04
0.14
.
5 --05
0.045
0.04
,
.
0.04
0.029
.
0.038
.
0.038
.
0.04 • .
0.14
6 - 05
0.045
.•
0,04
-
..
' .
_ 0.04
•-0.029
,
.
0.038
0.038
• -
0,04 -
.
0.14
.
7 - 05
0.045:=
. .
0.04 -
._
-
_,. •
0 04
..
•
-
0.029
•
;
0.038 '
0.038 -
..,
0.04
. .
0.14
8 - 05
--0.045
• •
• -
. •
'0.04
0
..
.
. •
0.04
- 029
0.
-
-..
0.038
•
0.038
•
0.04 '
.0.14
9 05
0.045
•
0.04-
0.04
.
,
' 0,029
• .
. '
0.038
.:
•
0.038
..
0.04 .
0.14
10 - 05
• 0,045
•
0.04
''' .
0.04
0.029
.
0.038
0.038
0.04
0.14
.
11 :05
0.045
0.04
0.04
0.029
•
0.038
0.038
.
0.04
0.14
12 - 05
. ....,
0,045
•
..
,•-
0.04
.
0.04
0.029
•
.
0.038
0.038
-0.04
0.14

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 19 OF 22
34541
lbs/day
1,2-dichloroprop
ane
34546
lbs/day
1,2-trans-dichlo
ro- ethylene
34551
lbs/day
1,2,4-trichloro-
benzene
34566
lbs/day
1,3-dichlorobenz
ene
(meta-dichlorobe
nzene;
1,3-DCB)
34571
lbs/day
1,4-dichlorobenz
ene
(para-dichlorobe
nzene;
1,4-DCB)-
.34586
lbs/day
2-chlorophenol
34591
lbs/day
2-nitrophenol.
34601
lbs/day
2,4-dichlorophen
of
1-06
0.278
0.038
0.124
0,056
0.027
0.056
0.075.
•0.071
2-06
0.278
0.038
0.124
,
0.056
0.027
0.056
0.075
0.071
3-06
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
4-06
0,278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
5-05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
6-05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
0.071
7-05
0.278
0.038 -
0.124-
0.056 -
0.027
0.056 .
0.075
0.071
8-05
0.278
0
0.038
0
0.124
0
0.056
0
0.027
0
0.056
0
0.075
0
0.071
0
9-05
0.278
0.038
0.124
0.056
0.027
.
0.056
0.075
0.071
10-05
0.278
0.038
0,124
0.056
0.027
0.056
0.075
0.071
11 -05
0.278
0.038
0.124
0.056
0.027
0.056
0.075
•
0,071
12-05
0.278
0.038
0.124
0,056
0.027
0.056
0.075
0.071

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Americas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 20 OF 22
-
34606
lbs/day
2,4-dimethylphen
of
34611
lbs/day
2,4-dinitrotolue
ne
34616
lbs/day -
2,4'-dinitropheno
1 : -
34626 -
lbs/day
2,6-dinitrotolue
-ne - _
34646
lbs/day
4-nitrophenol
,.
34657 • .
lbs/day
4,6-dinitro-o-cr
esol
34694
lbs/day
Phenol, Single
Compound .- -
34696
lbs/day
Naphthalene'-
1 -06
. 0.033
0.205 ,
0.129
-
0.463
0.131
0.142
0.027
0.04
2-06
0.033
0.205
0.129
0.463
0.131
0.142
0.027
'
0.04
3-06
0.033
0.20.5
0.129
. 0.463
0.131
0.142
0.027
0.04
•
4.- 06
0.033
0.205 -
. 0.129
0.463
0.131
0.142
0.027 •
-
0.04
5-05
0.033
. -
0.205
-
0.129
0.463
0.131
0.142
'0.027
-.
.0.04
6.-05
0.033
0.205
0.129 '
0.463 -
0.131
0.142
.
' .
0.027
0.04
7-05
0,033
0.205
'0.129 '
0.463
-
0.131 -
0.142
.
-'
0.027
•- •
0.04 -
8-05
0.033
0 -
0.205
0-
0.129 _
0
0.463
-0
0.131
0
0.142
0
-
0.027
0
0.04
0 -_
9 -= 05
0.033 -
0.205
' 02129 -
0.463
0.131 _
'
0.142
0.027
0.04
10-05
0.033
0.205
0.129 -
0.463
0.131
•0.142
0.027
0.04
11-05
0.033 •
0.205 :
0.129
0.463
0.131
0.142
.-'0.027
0.04
12-05
0.033
0,205
0.129
0.463
0.131
0.142
.0.027
0.04

PERMIT NUMBER: NC0003719
FACILITY NAME: DAK Ame icas, LLC - Cedar Creek Site
CITY: E Fayetteville
COUNTY: Cumberland
PERIOD ENDING MONTH: 4 - 2006
REGION: Fayetteville
DMR 12 Month Calculated
PAGE 21 OF 22
39100
lbs/day
Bis
(2-Ethylhexyl)
Phthalate
(di(2-ethylhexyl
)phthalate)
39110
lbs/day
Di-n-Butyl
Phthalate
39175
lbs/day
Vinyl Chloride
39160
lbs/day
Trichloroethylen
e
39700
lbs/day
Hexachlorobenzen
e
39700
ug/1
Hexachlorobenzen
e
39702
lbs/day
Hexachlorobutadi
ene
39941
mg/1
Roundup
0.187
0.049
0.189
0.038
0.036
1 - 06
0.187
0.049
0.189
0.038
0.036
2-06
.
0.187
0.049
0.189
0.038
0.036
3-06
0
0.187
0.049
0.189
0.038
0,036
4-06
0.187
0.049
0.189
0.038
0.036
5-05
0.187
0.049
0.189
0.038
0.0366
6-05
.
0.187 -
/
0.049
0.189 -
0.038
0.036
7-05
0.187
0.049
0,189
0.038
0.036
8-05
0
0
0 .
0
0
0
0.187
0.049
0.189
0.038
'
0.036
9-05
0.187
0.049 -
0.189
0.038
0.036
10-05
'
0.187
•
0.049
0.189
0.038
0.036
11-05
0.187
0.049
0.189
0,038
0.036
12-05

PERMIT NUMBER:NC0003719
-' FACILITY NAME: DAK'Americas, LLC - Cedar Creek Site
- CITY: E Fayetteville
COUNTY: Cumberland,
50050
mgd
Flow, -in
conduit or thru.
treatment plant
-77163--
_1bs/day
1,3 •-
dichloropropene
- --
79531 1:TGE6C
lbs/day
3; 4 -
Benzofluoran-The
,ne
pass/fail
P/FT STAT 24hr ,
Acu Pimepha-les.
- -
. 0.5
0.053 .
- 0.042
1-06
.
0.216903 -
0.5
0.053
0.042
2-06
'
0.219393
- -
1
0.5. - -
0.053
0.042
3-06
-
-
'
.0.1.72161 -
-
• 0.5 - -
0.053
0.042
4-06
-
-
0.161433
. -
0.5
0.053
0.042
-5.-05
.
,
10.1046-45
:
1
0.5
- 0:053
-
0,042
-' .
6-05
- -
-
0.2081
.
0.5
0.053 :1
- -
0.042
- 7 - 05
_, -
.
-�
.
-
0.300258
0.5
0.053
0.042
- •-
8-05
-
,. 0.257613
: 0 ..
0
1
9-05
0,5
0,053.
.. .
0.042.
-
:,
0.189733.
0.5
.0.053
0.042
'
•10-.05
-
0.225097 -
-
-
0.5 ,
0.053
0.042
11 =05
0:2381
-
-
-1
0.5 -
0.053
. -
0.042
12-05
0.264484
.
PERIOD ENDING MONTH: 4 - 2006
REGION:'"Fayetteville
DM1R..12 Month Calculated
PAGE 22 OF 22