WQ0004797_Groundwater Monitoring Report November 2020_20210108

Anchor QEA of North Carolina, PLLC ANCHOR
231 Haywood Street ' QEA
Asheville, North Carolina 28801
828.281.3350
December 11, 2020
Tracy Wolfe
Lassonde Pappas & Co., Inc.
125 Industrial Park Road
i
Hendersonville, North Carolina 28792
Re: November 2020 Groundwater Sampling Event �i ?C�,
Clement Pappas NC, LLC
Dear Ms. Wolfe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the November 2020 water quality
monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site), located at
485 Brookside Camp Road in Hendersonville, North Carolina. The company that operates the facility
rebranded to Lassonde Pappas & Company in 2016. However, for permitting purposes, the
Hendersonville facility retains the Clement Pappas NC LLC name that is designated on the property deed.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the subject facility (the Site) on
November 6, 2020. A Site location map is included in Figure 1. The groundwater sampling event was
performed in accordance with North Carolina Department of Environmental Quality (DEQ) wastewater
irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed May 15, 2020
(referred to as the permit in this letter; effective September 1, 2020, and expires July 31, 2026).
Anchor QEA used low -flow methods to purge and collect groundwater samples from six monitoring
wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed April 14,
2015, to replace the previously damaged monitoring well MW-2R. Monitoring well MW-5 is an
upgradient (background) monitoring well. The locations of the monitoring wells are shown in Figure 2.
Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a
North Carolina -certified laboratory, for analysis of the parameters specified in the permit, as follows:
• Total organic carbon • Total nitrate
• Chloride • Phosphorous
• Fecal coliform . Total dissolved solids
• Total ammonia • Volatile organic compounds (VOCs) by 6200
Groundwater Elevation
Table 1 summarizes current and historical groundwater elevations from May 2018 to November 2020.
Except for monitoring well MW-9, all monitoring well concrete pads and top -of -well casing elevations
\\ashevillel\Asheville\Projects\Clement Pappas\Reports\2020\November\Files for review\20201211_November 2020 Groundwater Sampling Event Clement Pappas NC, LLC.docx

December 11, 2020
Page 2
were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well MW-9 was
surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed top -of -casing elevations are
indicated in Table 1.
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from May 2018 to
November 2020. During the current sampling event, the parameters analyzed were within the
groundwater standards provided in the permit,' except as follows:
• The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R (13.0 mg/L) but has
decreased significantly from the previous sampling event.
The Title 15A, North Carolina Administrative Code [NCAC], Subchapter 2L, Section .0202 standard
(21- standard) for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mQ. There is
not a specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform. The following summarizes fecal coliform results from the groundwater monitoring wells:
• Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring
wells MW-5 (8.0 CFU/100 mQ, MW-6 (3.0 CFU/100 mQ, MW-8 (14.0 CFU/100 mQ, and MW-9
(16.0 CFU/100 mQ.
• Fecal coliform was not detected at or above laboratory detection limits in the samples
collected from monitoring wells MW-4 and MW-71R.
The pH of the samples collected from MW-4 (5.30 standard units [SU]), MW-5 (5.65 SU), MW-6 (5.23
SU), MW-7R (5.54 SU), and MW-9 (4.93 SU) were below the groundwater standard range of 6.5 to 8.5
SU. The sample collected from the background monitoring well, MW-5, has a pH that is similar to the
other groundwater monitoring wells.
Volatile Organic Compounds
Analytical results for VOCs, analyzed by U.S. Environmental Protection Agency Standard Method
620013, are presented in Table 2. In accordance with permit requirements, samples are analyzed for
VOCs annually in November. No VOCs were detected at concentrations above the method detection
limits in monitoring wells MW-4, MW-6, MW-7R, MW-8, or MW-9. VOC concentrations detected in
MW-5 (the background monitoring well for the Site) are summarized as follows:
• Two VOCs (tetrachloroethene and trichloroethene) were detected in monitoring well MW-5.
— Tetrachloroethene was detected at a concentration of 0.80 microgram per liter (Ng/L),
which exceeds its 2L standard (0.70 pg/L).
Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.

December 11, 2020
Page 3
— Trichloroethene was detected at a concentration of 1.0 pg/L, which is below the permit
groundwater standard (3.0 pg/L).
— Concentrations of historically detected VOCs decreased during this sampling event to
the lowest level since sampling began.
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in
May 2020 and effective September 2020 requires semiannual sampling of the surface water
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the
November 2020 sampling event, no parameters were detected at concentrations above the
associated 15A NCAC 2B surface water standards (2B standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The fall 2020
sampling showed a similar relationship: upstream sample SW-1 showed a concentration of
0.71 mg/L, and downstream sample SW-2 showed 0.70 mg/L. The results for total organic carbon,
chloride, total dissolved solids (TDS), ammonia, and total phosphorus were also similar for upstream
and downstream samples, indicating the unlikelihood that the Site is impacting Mud Creek. The fecal
coliform concentration was higher in the upstream sample SW-1 (145 CFU/100mL) than the
downstream sample SW-2 (97 CFU/100mL).
The Site irrigation fields have experienced significant flood events since over the last several years.
The regular flooding of Mud Creek and its nutrient loading associated with runoff from agricultural
fields upstream of the facility is suspected to have impacts on Site groundwater.
Discussion
Taking a proactive approach, in 2016 Clement Pappas contracted Nutter and Associates to analyze
the overall health and performance of the land application system to determine ways to improve the
longevity of the system while reducing the likelihood of impacts on groundwater. Based on this work,
Clement Pappas has implemented the following activities:
• To avoid introducing additional nitrogen into soils at the subject facility, Clement Pappas has
implemented the practice of baling harvested fescue and removing it from the irrigation fields,
instead of mowing it and allowing it to decompose.
— Removing the harvested fescue should result in improved vegetative growth, which will
allow the fescue to uptake additional available nitrogen.

December 11, 2020
Page 4
— Additionally, it is expected that removing the harvested fescue will result in greater
assimilation of nitrogen into facility soils and reduce the potential for nitrogen leaching.
All of the samples collected during the November 2020 sampling event were below the permit
standard for nitrate except for MW-7R; however, the nitrate concentration in MW-7R has decreased
significantly since the last monitoring event.
In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the
following to the DEQ by December 31, 2020 (on or before the last working day of the month
following the sampling month):
• Laboratory analytical reports and chain -of -custody forms (Attachment 1)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 2)
• DEQ GW-59A — Compliance Report Form (Attachment 3)
• DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 4)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in May 2021.
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] [e-mail].
Sincerely,
Jennifer Verde
Managing Engineer
Attachments
Table 1
Current and Historical Groundwater Elevation Measurements
Table 2
Current and Historical Groundwater Analytical Results
Table 3
Current and Historical Surface Water Analytical Results
Figure 1
Site Location Map
Figure 2
Site Plan Map
Attachment 1
Laboratory Analytical Reports and Chain -of -Custody Forms
Attachment 2
Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 3
DEQ GW-59A — Compliance Report Form
Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
M W -4
Screened
Interval
(ft bgs)
Date Measured
Depth to
Groundwater
Top -of-
Casing
Elevation
Top -of -Casing
Height Above
Ground Surface
Groundwater
Elevation
5.0 - 15.0
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2055.77
05/21/2019
8.49
2055.28
11/14/2019
8.82
2054.95
05/06/2020
7.98
2055.79
11/06/2020
8.02
2055.75
MW-5
9.0 - 19.0
05/02/2018
8.47
2085.60
3.00
1
2077.13
11/02/2018
8.23
2077.37
05/21/2019
8.57
2077.03
11/14/2019
8.90
2076.70
05/06/2020
8.28
2077.32
11/06/2020
8.90
2076.70
MW-6
5.0 - 10.0
05/02/2018
5.36
2061.17
3.00
2055.81
11/02/2018
5.03
2056.14
05/21/2019
5.53
2055.64
11/14/2019
5.59
2055.58
05/06/2020
5.41
2055.76
11/06/2020
5.33
2055.84
MW 7R
5.0 15.0
05/02/2018
10.99
2062.86
3.00
1
2051.87
11/02/2018
10.33
2052.53
05/21/2019
10.88
2051.98
11/14/2019
11.33
2051.53
05/06/2020
10.11
2052.75
11/06/2020
10.05
2052.81
MW-8
3.0 - 13.0
05/02/2018
9.39
2060.80
1
3.00
2051.41
11/02/2018
US
2051.95
05/21/2019
9.38
2051.42
11/14/2019
9.75
2051.05
05/06/2020
8.54
2052.26
11/06/2020
8.37
2052.43
MW-9
3.0 - 13.0
05/02/2018
5.07
2060.23
1.44
2055.16
11/02/2018
4.55
2055.68
05/21/2019
4.89
2055.34
11/14/2019
5.15
2055.08
05/06/2020
4.30
2055.93
11/06/2020
4.10
2056.13
November 2020 Groundwater Sampling Event Pagel of 2
Clement Pappas, Hendersonville, North Carolina December 2020

Table 1
Current and Historical Groundwater Elevation Measurements
Notes:
Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based upon a survey by Hill and Associates
Surveyors, dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based upon
differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -
casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -
casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying.
ft bgs: feet below ground surface
Monitoring is performed in accordance with Permit No. W00004797 issued to Clement Pappas on May 15, 2020 and effective
on September 1, 2020.
November 2020 Groundwater Sampling Event Page 2 of 2
Clement Pappas, Hendersonville, North Carolina December 2020

Table 2
Current and Historical Groundwater Analytical Results
Sample
Name
Sample Date
e
V
A
0 c
° v
v
o
U
F
C
w
v
d
z
e
w
& Ai
�
_
o
v
o o
r
m
c
E
E
N
i'
°
L
N
a
9
°
d
W
N
O
s
°i
N
L
a+
N
o
N
r4
.= C
N V
- v
d
°
c L
A V
` v
M
L
°
v
C
d
C
L
G
L
°
v
(SU)
(mg/L)
(mg/L)
(CFUs per
100 mL)
(mg/L)
(m L)
(m /L)
(m /L)
(mg/L)
(p /L)
(pg/L)
(p /L)
I (pg/L)
(pg/L)
(pg/L)
2L Groundwater Standards
6.5 - 8.5
10
250
1
NL
S00
500
7.5
NL
0.7
3
70
700
1 0.03
7
Groundwater Standards Provided in Permit No. W00004797
6.5 - 8.5
10
250
NL
10
250
S00
1.5
NL
3
70
700
0.03
7
05/02/2018
5.86
3.0
10.0
<1.0
2.1
NA
167
<0.020
0.11
-0.7.
NR
11/02/2018
5.47
3.6
9.0
<10.0
0.48
NA
137
<0.10
0.070
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW 4
05/21/2019
5.81
3.0
11.3
<1.0
3.3
NA
170
<0.050
0.044 J
NR
11/14/2019
5.82
3.7
11
<1.0
0.42
NA
190
<0.10
<O.OSO
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/06/2020
5.70
2.3
7.6
<1.0
3.7
172
<0.10
<0.050
NR
11/06/2020
5.30
2.8
6.9
<1.0
0.73
148
<0.10
<0.050
< O.SO < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.69
5.7
16.1
2.0
0.0
NA
90
<0.10
0.097
NR
11/02/2018
5.53
5.1
23.9
<10.0
<0.020
NA
86
<0.10
0.08S
39.1 6.0 6.7 1 < 0.50 < 1.0 < 0.50
MW-5
05/21/2019
5.68
9.4
26.8
7.0
0.1
NA
91
<0.050
0.120
NR
11/14/2019
5.59
6.0
20.1
7.0
0.055
NA
202
<0.10
0.081
22.4 4.4 5.0 1 < 0.50 < 1.0 < 0.50
05/06/2020
5.90
6.9
7.3
8.0
<0.040
116
<0.10
0.083
NR
11/06/2020
5.65
4.6
6.9
8.0
< 0.040
61.0
<0.10
0.060
0.80 1.0 < 0.50 I < 0.50 < 1.0 < 0.50
05/02/2018
5.28
2.3
9.4
1.0
0.1
NA
81
<0.10
0.097
NR
11/02/2018
5.02
2.5
10.1
69.0
0.6
NA
88
<0.10
0.057
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW-6
05/21/2019
5.46
3.3
11.3
23.0
0.4
NA
78
<0.050
0.068
NR
11/14/2019
5.30
2.9
9.3
44.0
0.56
NA
342
<0.10
0.052
< 0.50 < 0.50 < 0.50 1 < 0.50
05/06/2020
5.38
2.0
9.7
3.0
1.1
96.0
<0.10
<0.050
NR
11/06/2020
5.23
2.6
12.5
3.0
3.2
139
<0.10
<0.050
< 0.50 < 0.50 < O.SO I < 0.50 < 1.0 < 0.50
05/02/2018
5.41
3.2
22.6
<2.0
15.5
NA
207
<0.10
0.320
NR
11/02/2018
5.48
5.3
20.2
<10.0
15.7
NA
243
<0.10
0.170
< 0.50 < 0.50 < O.SO I < 0.50 < 1.0 < 0.50
MW-7R
05/21/2019
5.58
3.0
29.0
<2.0
20.2
NA
234
<0.050
0.130
NR
11/14/2019
6.42
3.0
22.7
<2.0
17.1
NA
73
<0.10
0.084
< 0.50 < 0.50 < O.SO I < 0.50 < 1.0 < 0.50
05/06/2020
5.20
1.2
20.9
<1.0
21.5
219
219
<0.10
<0.050
NR
11/06/2020
5.54
1.7
17.8
<1.0
13.0
205
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
6.74
10.8
12.9
<2.0
14.4
NA
548
<0.10
0.190
NR
11/02/2018
6.52
9.5
8.0
19.0
6.8
NA
351
<0.10
0.250
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW 8
05/21/2019
6.89
7.9
7.3
<10.0
6.2
NA
249
<0.050
0.290
NR
11/14/2019
6.71
7.7
7.2
2.0
1.2
NA
51
<0.10
0.10
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/06/2020
6.41
2.7
2.8
<1.0
3.6
139
<0.10
<0.050
NR
11/06/2020
6.34
2.8
2.3
14.0
2.4
127
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.52
4.6
4.9
<2.0
0.6
NA
69
<0.10
0.370
NR
11/02/2018
5.11
8.4
5.8
<10.0
0.6
NA
88
<0.10
0.470
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW 9
05/21/2019
5.64
7.2
4.6
<10.0
0.2
NA
80
<0.050
0.230
NR
11/14/2019
5.57
6.1
5.4
<1.0
0.89
1 NA
56
<0.10
0.076
< 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50
05/06/2020
5.52
5.9
1.8
<1.0
<0.040
68.0
<0.10
0.099
NR
11/06/2020
4.93
4.5
1.4
16.0
0.043
1
88.0
<0.10
0.095
1 < 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
Notes:
2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Total organic carbon and nitrate standards are set in
Wastewater Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform."
Bolded values indicate a concentration above the respective permit groundwater standard or outside the permit groundwater standard range,
pH is analyzed by Anchor QEA of North Carolina, PLLC; NC lab certification number 5445
Monitorinq is performed in accordance with Permit No. W00004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
< indicates that the constituent concentration was not detected above the method detection limit
pg/L: micrograms per liter
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliter
NL: No 2L standard exists.
NR: not reported
SU: standard unit
November 2020 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina December 2020

Table 3
Current and Historical Surface Water Analytical Results
c.
V CC
•01 'G
O u
•�
.O
_
f0 :=
U. U
r
i
Z
_ N
10 H .a
G �n
•!
0
£
Q
VI
O
_ OMaa+
�0 N
t°- a
(CFUs per
Sample Name
Sample Date
(SU)
(mg/L)
(mg/L)
100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
28 Standard
6.5 - 8.5
NL
230
200
NL
NL
NL
NL
5/2/2018
6.88
1.5
4.8
53.0
0.74
54.0
<0.10
0.044 J
11/2/2018
6.28
2.9
5.1
780
0.72
54.0
<0.10
0.077
5/21/2019
7.02
1.6
5.0
98.0
0.75
42.0
<0.050
0.067
SW-1
11/14/2019
6.76
1.9
5.3
118
0.83
57.0
<0.10
0.1
(Upstream)
5/6/2020
7.20
1.6
4.6
290
0.76
49.0
<0.10
0.092
11/6/2020
5.83
1.6
4.4
145
0.71
56.0
<0.10
< 0.050
5/2/2018
6.98
1.4
4.4
118.0
0.72
51.0
0.052 J
0.045 J
11/2/2018
7.08
2.9
4.6
940.0
0.75
53.0
0.099 J
0.076
5/21/2019
6.99
1.6
4.9
200.0
0.76
47.0
<0.050
1 0.068
SW-2
11/14/2019
7.01
1.9
5.4
127
0.82
83.0
<0.10
0.089
(Downstream)
5/6/2020
6.67
1.7
4.2
420
0.72
53.0
<0.10
<0.050
11/6/2020
6.19
1.6
4.4
97.0
0.70
59.0
<0.10
<0.050
Notes:
2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and
Wetland Standards (last amended in September 2017), or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended Water Quality
Criteria for Aquatic Life and Human Health.
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
< indicates that the constituent concentration was not detected above the laboratory reporting limit
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
CFU: coliform -form i ng unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliters
NL: No NC2L standard exists
SU: standard unit
November 2020 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina December 2020

Figures

LEGEND: SOURCES:
Basemap: USGS Topographic Maps, Fruitland and Hendersonville 0 2,000
[3 Site Location Quadrangles, 1997
Parcel: Henderson County GIS 2016 0 Feet
P"I th Late [C•16: o� -t' 1136 i- JM U—' cuute
Filepath. P VClement Pappas\FigwesVGIS\Figure 1
kzANCHOR Figure 1
(SEA w Site Location Map
November 2020 Groundwater Sampling Event
Clement Pappas, Hendersonville, North Carolina

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AnchorQEA of •Carolina,
• �• Haywood231 Street ANCHOR
•
Asheville, North Carolina
801
828.281.3350
1 •
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DRAWN BY: S. STAVINOHA k
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• �. 1 1/ 111
• • :• �•• 1 1 1: •
• • .• • .• D•TE: SCALE IN FEET••• 1 �: 1 1

Attachment 1
Laboratory Analytical Reports and
Chain -of -Custody Forms

aceAnalyfical ",
www.pscNsbs.cm
November 16, 2020
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas
Pace Project No.: 92504561
Dear Jennifer Verde:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
Al _
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 48

aceAnalytical "'
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Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 48

aceAnalytical
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i
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
Lassonde Pappas
92504561
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92504561001
MW-4
SM 6200B
SAS
63
PASI-C
SM 254OC-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561002
MW-5
SM 6200B
SAS
63
PASI-C
SM 254OC-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561003
MW-6
SM 6200B
SAS
63
PASI-C
SM 254OC-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561004
MW-7R
SM 6200B
SAS
63
PASI-C
SM 254OC-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561005
MW-8
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 48

aceAnalytical
www.putlabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Lassonde Pappas
Pace Project No.:
92504561
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561006
MW-9
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561007
SW-1
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561008
SW-2
SM 6200E
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 48

aceAnalytical "'
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 00:42
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 00:42
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 00:42
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 00:42
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 00:42
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 00:42
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
135-98-8
tert- Butyl benzene
ND
ug/L
0.50
1
11/11/20 00:42
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 00:42
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 00:42
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 00:42
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 00:42
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 00:42
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 00:42
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 00:42
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 00:42
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 00:42
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 00:42
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 00:42
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 00:42
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 00:42
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 00:42
75-35-4
cis- 1, 2-Dich loroethene
ND
ug/L
0.50
1
11/11/20 00:42
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 00:42
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 00:42
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 00:42
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 00:42
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 00:42
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 00:42
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 00:42
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 00:42
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 00:42
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 00:42
79-34-5
REPORT
OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 11/16/2020 01:39 PM
without the written consent of Pace Analytical Services, LLC.
Page 5 of 48

1�;a'cie Analytical QD
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 00:42
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 00:42
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 00:42
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 00:42
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 00:42
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 00:42
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 00:42
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 00:42
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 00:42
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 00:42
95-63-6
1,3,5-Trimethyl benzene
ND ug/L
0.50
1
11/11/20 00:42
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 00:42
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 00:42
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 00:42
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
96 %
70-130
1
11/11/20 00:42
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/11/20 00:42
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 00:42
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
Total Dissolved Solids
148 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:35
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
0.73 mg/L
0.040
1
11/07/20 03:03
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:12
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
6.9 mg/L
1.0
1
11/09/20 23:41
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 48

Pace Analytical Services, LLC
a
aceAnalXical 2225 Riverside
Asheville, NC 2880404
www.pscelabs.com [phone]
I
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC Analytical Method: SM 531 OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 2.8 mg/L 1.0 1 11/12/20 17:07 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 48

11�;a'cieAnalXicalo
www.pacNsbs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:00
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:00
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:00
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:00
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:00
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:00
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:00
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:00
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:00
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:00
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:00
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:00
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:00
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:00
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:00
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:00
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:00
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:00
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:00
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:00
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:00
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:00
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:00
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:00
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:00
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:00
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:00
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:00
79-34-5
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/16/2020 01:39 PM
without the written consent of Pace Analytical Services, LLC.
Page 8 of 48

aceAnalytical
www.pscolabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
0.80 ug/L
0.50
1
11/11/20 01:00
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:00
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:00
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:00
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:00
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:00
79-00-5
Trichloroethene
1.0 ug/L
0.50
1
11/11/20 01:00
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:00
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:00
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:00
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:00
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:00
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:00
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:00
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
98 %
70-130
1
11/11/20 01:00
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/11/20 01:00
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 01:00
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
61.0 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
8.0 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:40
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
ND mg/L
0.040
1
11/07/20 03:00
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
0.060 mg/L
0.050
1
11/09/20 19:00 11/10/20 21:16
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
6.9 mg/L
1.0
1
11/09/20 23:42
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 48

aceAnalXical
www.pecNabs.com
i
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 4.6 mg/L 1.0 1 11/12/20 17:31 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 48

aceAnalytical
www.pealabs.com
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis- 1, 3-Dichloropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
0.50
1
11/11/20 01:18
71-43-2
0.50
1
11/11/20 01:18
108-86-1
0.50
1
11/11/20 01:18
74-97-5
0.50
1
11/11/20 01:18
75-27-4
0.50
1
11/11/20 01:18
75-25-2
5.0
1
11/11/20 01:18
74-83-9
0.50
1
11/11/20 01:18
104-51-8
0.50
1
11/11/20 01:18
135-98-8
0.50
1
11/11/20 01:18
98-06-6
0.50
1
11/11/20 01:18
56-23-5
0.50
1
11/11/20 01:18
108-90-7
1.0
1
11/11/20 01:18
75-00-3
0.50
1
11/11/20 01:18
67-66-3
1.0
1
11/11/20 01:18
74-87-3
0.50
1
11/11/20 01:18
95-49-8
0.50
1
11/11/20 01:18
106-43-4
1.0
1
11/11/20 01:18
96-12-8
0.50
1
11/11/20 01:18
124-48-1
0.50
1
11/11/20 01:18
106-93-4
0.50
1
11/11/20 01:18
74-95-3
0.50
1
11/11/20 01:18
95-50-1
0.50
1
11/11/20 01:18
541-73-1
0.50
1
11/11/20 01:18
106-46-7
0.50
1
11/11/20 01:18
75-71-8
0.50
1
11/11/20 01:18
75-34-3
0.50
1
11/11/20 01:18
107-06-2
0.50
1
11/11/20 01:18
75-35-4
0.50
1
11/11/20 01:18
156-59-2
0.50
1
11/11/20 01:18
156-60-5
0.50
1
11/11/20 01:18
78-87-5
0.50
1
11/11/20 01:18
142-28-9
0.50
1
11/11/20 01:18
594-20-7
0.50
1
11/11/20 01:18
563-58-6
0.50
1
11/11/20 01:18
10061-01-5
0.50
1
11/11/20 01:18
10061-02-6
0.50
1
11/11/20 01:18
108-20-3
0.50
1
11/11/20 01:18
100-41-4
2.0
1
11/11/20 01:18
87-68-3
0.50
1
11/11/20 01:18
98-82-8
2.0
1
11/11/20 01:18
75-09-2
0.50
1
11/11/20 01:18
1634-04-4
2.0
1
11/11/20 01:18
91-20-3
0.50
1
11/11/20 01:18
103-65-1
0.50
1
11/11/20 01:18
100-42-5
0.50
1
11/11/20 01:18
630-20-6
0.50
1
11/11/20 01:18
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 48

aceAnalytical .
rww.Pacelabston
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 01:18
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:18
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:18
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:18
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:18
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:18
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 01:18
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:18
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:18
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:18
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:18
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:18
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:18
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:18
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
11/11/20 01:18
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/11/20 01:18
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 01:18
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
Total Dissolved Solids
139 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006
Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
3.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:47
7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
3.2 mg/L
0.040
1
11/07/20 02:58
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:18
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
12.5 mg/L
1.0
1
11/09/20 23:43
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 48

a�
aceAnalytical
www.pacNabs cm
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 2.6 mg/L 1.0 1 11/12/20 18:44 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 48

OD
aceAnalytical
www.pacNabs.cwa
i
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:35
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:35
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:35
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:35
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:35
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:35
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:35
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:35
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:35
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:35
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:35
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:35
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:35
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:35
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:35
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:35
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:35
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:35
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:35
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:35
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:35
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:35
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:35
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:35
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:35
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:35
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 48

�,-;a'cie Analytical
www.pscolabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200E MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3, 5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
Date: 11/16/2020 01:39 PM
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
ND ug/L
0.50
1
11/11/20 01:35
127-18-4
ND ug/L
0.50
1
11/11/20 01:35
108-88-3
ND ug/L
2.0
1
11/11/20 01:35
87-61-6
ND ug/L
2.0
1
11/11/20 01:35
120-82-1
ND ug/L
0.50
1
11/11/20 01:35
71-55-6
ND ug/L
0.50
1
11/11/20 01:35
79-00-5
ND ug/L
0.50
1
11/11/20 01:35
79-01-6
ND ug/L
1.0
1
11/11/20 01:35
75-69-4
ND ug/L
0.50
1
11/11/20 01:35
96-18-4
ND ug/L
0.50
1
11/11/20 01:35
95-63-6
ND ug/L
0.50
1
11/11/20 01:35
108-67-8
ND ug/L
1.0
1
11/11/20 01:35
75-01-4
ND ug/L
1.0
1
11/11/20 01:35
179601-23-1
ND ug/L
0.50
1
11/11/20 01:35
95-47-6
99 %
70-130
1
11/11/20 01:35
17060-07-0
98 %
70-130
1
11/11/20 01:35
460-00-4
102 %
70-130
1
11/11/20 01:35
2037-26-5
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
205 mg/L
25.0
1
11/08/2011:43
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
ND CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L
0.10
1
11/10/2012:52
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
13.0 mg/L
0.40
10
11/07/20 03:19
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:18
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
17.8 mg/L
1.0
1
11/09/20 23:44
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 48

aceAnalytical
www.pacdabs.con
I
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 1.7 mg/L 1.0 1 11/12/20 20:09 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 48

aceAnalytical
www.paeNabs.eoe
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-8
Parameters
6200B MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis- 1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1, 3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Date: 11/16/2020 01:39 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92504561005 Collected: 11/06/20 09:27 Received: 11/06/20 14:55 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
0.50
1
11/11/20 01:53
71-43-2
0.50
1
11/11/20 01:53
108-86-1
0.50
1
11/11/20 01:53
74-97-5
0.50
1
11/11/20 01:53
75-27-4
0.50
1
11/11/20 01:53
75-25-2
5.0
1
11/11/20 01:53
74-83-9
0.50
1
11/11/20 01:53
104-51-8
0.50
1
11/11/20 01:53
135-98-8
0.50
1
11/11/20 01:53
98-06-6
0.50
1
11/11/20 01:53
56-23-5
0.50
1
11/11/20 01:53
108-90-7
1.0
1
11/11/20 01:53
75-00-3
0.50
1
11/11/20 01:53
67-66-3
1.0
1
11/11/20 01:53
74-87-3
0.50
1
11/11/20 01:53
95-49-8
0.50
1
11/11/20 01:53
106-43-4
1.0
1
11/11/20 01:53
96-12-8
0.50
1
11/11/20 01:53
124-48-1
0.50
1
11/11/20 01:53
106-93-4
0.50
1
11/11/20 01:53
74-95-3
0.50
1
11/11/20 01:53
95-50-1
0.50
1
11/11/20 01:53
541-73-1
0.50
1
11/11/20 01:53
106-46-7
0.50
1
11/11/20 01:53
75-71-8
0.50
1
11/11/20 01:53
75-34-3
0.50
1
11/11/20 01:53
107-06-2
0.50
1
11/11/20 01:53
75-35-4
0.50
1
11/11/20 01:53
156-59-2
0.50
1
11/11/20 01:53
156-60-5
0.50
1
11/11/20 01:53
78-87-5
0.50
1
11/11/20 01:53
142-28-9
0.50
1
11/11/20 01:53
594-20-7
0.50
1
11/11/20 01:53
563-58-6
0.50
1
11/11/20 01:53
10061-01-5
0.50
1
11/11/20 01:53
10061-02-6
0.50
1
11/11/20 01:53
108-20-3
0.50
1
11/11/20 01:53
100-41-4
2.0
1
11/11/20 01:53
87-68-3
0.50
1
11/11/20 01:53
98-82-8
2.0
1
11/11/20 01:53
75-09-2
0.50
1
11/11/20 01:53
1634-04-4
2.0
1
11/11/20 01:53
91-20-3
0.50
1
11/11/20 01:53
103-65-1
0.50
1
11/11/20 01:53
100-42-5
0.50
1
11/11/20 01:53
630-20-6
0.50
1
11/11/20 01:53
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 48

I
nde Pappas
561
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID: 92504561005 Collected:
11/06/20 09:27
Received: 11/06/20 14:55 Matrix:
Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
ND ug/L
0.50
1
11/11/20 01:53
127-18-4
ND ug/L
0.50
1
11/11/20 01:53
108-88-3
ND ug/L
2.0
1
11/11/20 01:53
87-61-6
ND ug/L
2.0
1
11/11/20 01:53
120-82-1
ND ug/L
0.50
1
11/11/20 01:53
71-55-6
ND ug/L
0.50
1
11/11/20 01:53
79-00-5
ND ug/L
0.50
1
11/11/20 01:53
79-01-6
ND ug/L
1.0
1
11/11/20 01:53
75-69-4
ND ug/L
0.50
1
11/11/20 01:53
96-18-4
ND ug/L
0.50
1
11/11/20 01:53
95-63-6
ND ug/L
0.50
1
11/11/20 01:53
108-67-8
ND ug/L
1.0
1
11/11/20 01:53
75-01-4
ND ug/L
1.0
1
11/11/20 01:53
179601-23-1
ND ug/L
0.50
1
11/11/20 01:53
95-47-6
100 %
70-130
1
11/11/20 01:53
17060-07-0
96 %
70-130
1
11/11/20 01:53
460-00-4
100 %
70-130
1
11/11/20 01:53
2037-26-5
lids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
127 mg/L
25.0
1
11/08/2011:44
m AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
14.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L
0.10
1
1111012012:53
7664-41-7
unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
2.4 mg/L
0.040
1
11/07/20 02:55
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:19
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
2.3 mg/L
1.0
1
11/09/20 23:45
16887-00-6
aceAnalytical
www.pudobs.com
Project: Lasso
Pace Project No.: 92504
Sample: MW-8
Parameters
6200E MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
2540C Total Dissolved So
Total Dissolved Solids
MBIO 9222D Fecal Colifor
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, N021NO3
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 48

1�2ceAnalyfical'
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-8 Lab ID: 92504561005 Collected: 11/06/20 09:27 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310E TOC
Total Organic Carbon
Date: 11/16/2020 01:39 PM
Analytical Method: SM 531OB-2011
Pace Analytical Services - Asheville
2.8 mg/L 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
11/12/20 20:33 7440-44-0
Page 19 of 48

acmnalytical
www.pacNabs.com
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-9
Parameters
6200E MSV
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dich loroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1, 3-Dich loropropene
trans-1,3-Dichloropropene
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
Methylene Chloride
Methyl-tert-butyl ether
Naphthalene
n-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Date: 11/16/2020 01:39 PM
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
0.50
1
11/11/20 02:11
71-43-2
0.50
1
11/11/20 02:11
108-86-1
0.50
1
11/11/20 02:11
74-97-5
0.50
1
11/11/20 02:11
75-27-4
0.50
1
11/11/20 02:11
75-25-2
5.0
1
11/11/20 02:11
74-83-9
0.50
1
11/11/20 02:11
104-51-8
0.50
1
11/11/20 02:11
135-98-8
0.50
1
11/11/20 02:11
98-06-6
0.50
1
11/11/20 02:11
56-23-5
0.50
1
11/11/20 02:11
108-90-7
1.0
1
11/11/20 02:11
75-00-3
0.50
1
11/11/20 02:11
67-66-3
1.0
1
11/11/20 02:11
74-87-3
0.50
1
11/11/20 02:11
95-49-8
0.50
1
11/11/20 02:11
106-43-4
1.0
1
11/11/20 02:11
96-12-8
0.50
1
11/11/20 02:11
124-48-1
0.50
1
11/11/20 02:11
106-93-4
0.50
1
11/11/20 02:11
74-95-3
0.50
1
11/11/20 02:11
95-50-1
0.50
1
11/11/20 02:11
541-73-1
0.50
1
11/11/20 02:11
106-46-7
0.50
1
11/11/20 02:11
75-71-8
0.50
1
11/11/20 02:11
75-34-3
0.50
1
11/11/20 02:11
107-06-2
0.50
1
11/11/20 02:11
75-35-4
0.50
1
11/11/20 02:11
156-59-2
0.50
1
11/11/20 02:11
156-60-5
0.50
1
11/11/20 02:11
78-87-5
0.50
1
11/11/20 02:11
142-28-9
0.50
1
11/11/20 02:11
594-20-7
0.50
1
11/11/20 02:11
563-58-6
0.50
1
11/11/20 02:11
10061-01-5
0.50
1
11/11/20 02:11
10061-02-6
0.50
1
11/11/20 02:11
108-20-3
0.50
1
11/11/20 02:11
100-41-4
2.0
1
11/11/20 02:11
87-68-3
0.50
1
11/11/20 02:11
98-82-8
2.0
1
11/11/20 02:11
75-09-2
0.50
1
11/11/20 02:11
1634-04-4
2.0
1
11/11/20 02:11
91-20-3
0.50
1
11/11/20 02:11
103-65-1
0.50
1
11/11/20 02:11
100-42-5
0.50
1
11/11/20 02:11
630-20-6
0.50
1
11/11/20 02:11
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 48

w
aceAnalytical
wrrtir.Pacalabs.coo
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-9 Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 02:11
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 02:11
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:11
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:11
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:11
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:11
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 02:11
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 02:11
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 02:11
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:11
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:11
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 02:11
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 02:11
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 02:11
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
11/11/20 02:11
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/11/20 02:11
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 02:11
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
Total Dissolved Solids
88.0 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006
Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
16.0 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:54
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.043 mg/L
0.040
1
11/07/20 02:59
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
0.095 mg/L
0.050
1
11/09/20 19:00 11/10/20 21:20
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1.4 mg/L
1.0
1
11/09/2023:47
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 48

Pace Analytical Services, LLC
�CGAnal�'na' 2225 Riverside 04
tiG HI I (r Asheville, NC 28804
www.pialobs.com [phone]
I
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-9 Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 4.5 mg/L 1.0 1 11/12/20 20:58 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 48

aceAnalytical
www.pactiabs.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-1 Lab ID: 92504561007 Collected: 11/06/20 14:00 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 02:29
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 02:29
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 02:29
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 02:29
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 02:29
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 02:29
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 02:29
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 02:29
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 02:29
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 02:29
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:29
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:29
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 02:29
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 02:29
124-48-1
1,2-Dibromoethane(EDB)
ND
ug/L
0.50
1
11/11/20 02:29
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 02:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 02:29
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:29
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:29
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
563-58-6
cis- 1, 3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
10061-01-5
trans- 1, 3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 02:29
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 02:29
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 02:29
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 02:29
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 02:29
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 02:29
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 02:29
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:29
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:29
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 48

ID
aceAnalytical
www.yaedabs.em
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: SW-1
Parameters
Lab ID: 92504561007 Collected: 11/06/20 14:00
Results Units Report Limit DF
Received: 11/06/20 14:55 Matrix: Water
Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 02:29
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 02:29
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:29
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:29
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:29
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:29
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 02:29
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 02:29
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 02:29
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:29
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:29
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 02:29
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 02:29
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 02:29
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
11/11/20 02:29
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/11/20 02:29
460-00-4
Toluene-d8 (S)
100 %
70-130
1
11/11/20 02:29
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
56.0 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation
Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
145 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:56
7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
0.71 mg/L
0.040
1
11/07/20 03:07
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:20
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
4.4 mg/L
1.0
1
11/09/20 23:48
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 48

Pace Analytical Services, LLC
aceAnalytical 2225 Riverside
Asheville, NC 2880404
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-1 Lab ID: 92504561007 Collected: 11/06/20 14:00 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531 OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 11/12/20 21:28 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 48

aceAnalytical
www.paNlbs.coe
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
7
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 02:47
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 02:47
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 02:47
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 02:47
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 02:47
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 02:47
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 02:47
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 02:47
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 02:47
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 02:47
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:47
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:47
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 02:47
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 02:47
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 02:47
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 02:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 02:47
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:47
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:47
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
10061-01-5
trans- 1, 3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 02:47
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 02:47
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 02:47
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 02:47
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 02:47
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 02:47
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 02:47
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:47
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:47
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 26 of 48

aceAnalytical
www.pacelaba.cm
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Tetrachloroethene
Toluene
1,2,3-Trichlorobe nzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trich lorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethyl benzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
Date: 11/16/2020 01:39 PM
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
ND ug/L
0.50
1
11/11/20 02:47
127-18-4
ND ug/L
0.50
1
11/11/20 02:47
108-88-3
ND ug/L
2.0
1
11/11/20 02:47
87-61-6
ND ug/L
2.0
1
11/11/20 02:47
120-82-1
ND ug/L
0.50
1
11/11/20 02:47
71-55-6
ND ug/L
0.50
1
11/11/20 02:47
79-00-5
ND ug/L
0.50
1
11/11/20 02:47
79-01-6
ND ug/L
1.0
1
11/11/20 02:47
75-69-4
ND ug/L
0.50
1
11/11/20 02:47
96-18-4
ND ug/L
0.50
1
11/11/20 02:47
95-63-6
ND ug/L
0.50
1
11/11/20 02:47
108-67-8
ND ug/L
1.0
1
11/11/20 02:47
75-01-4
ND ug/L
1.0
1
11/11/20 02:47
179601-23-1
ND ug/L
0.50
1
11/11/20 02:47
95-47-6
101 %
70-130
1
11/11/20 02:47
17060-07-0
97 %
70-130
1
11/11/20 02:47
460-00-4
101 %
70-130
1
11/11/20 02:47
2037-26-5
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
59.0 mg/L
25.0
1
11/08/2011:44
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services - Asheville
97.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L
0.10
1
11/10/2012:57
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
0.70 mg/L
0.040
1
11/07/20 02:56
14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:21
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
4.4 mg/L
1.0
1
11/09/20 23:50
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 48

Pace Analytical Services, LLC
1�;a'neAnalyfical Ashevihevi ® Riverside lle, NC 2880404
www.pacNsbs.com [phone]
I
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 11/12/20 22:04 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 48

w
aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 579267 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3064425 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,1-Trichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,2-Trichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/11/20 00:06
1,2,3-Trichloropropane
ug/L
ND
0.50
11/11/20 00:06
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/11/20 00:06
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/11/20 00:06
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/11/20 00:06
1,2-Dibromoethane (EDB)
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichloropropane
ug/L
ND
0,50
11/11/20 00:06
1,3,5-Trimethyl benzene
ug/L
ND
0.50
11/11/20 00:06
1,3-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
1,3-Dichloropropane
ug/L
ND
0.50
11/11/20 00:06
1,4-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
2,2-Dichloropropane
ug/L
ND
0.50
11/11/20 00:06
2-Chlorotoluene
ug/L
ND
0.50
11/11/20 00:06
4-Chlorotoluene
ug/L
ND
0.50
11/11/20 00:06
Benzene
ug/L
ND
0.50
11/11/20 00:06
Bromobenzene
ug/L
ND
0.50
11/11/20 00:06
Bromochloromethane
ug/L
ND
0.50
11/11/20 00:06
Bromodichloromethane
ug/L
ND
0.50
11/11/20 00:06
Bromoform
ug/L
ND
0.50
11/11/20 00:06
Bromomethane
ug/L
ND
5.0
11/11/20 00:06
Carbon tetrachloride
ug/L
ND
0.50
11/11/20 00:06
Chlorobenzene
ug/L
ND
0.50
11/11/20 00:06
Chloroethane
ug/L
ND
1.0
11/11/20 00:06
Chloroform
ug/L
ND
0.50
11/11/20 00:06
Chloromethane
ug/L
ND
1.0
11/11/20 00:06
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
Dibromochloromethane
ug/L
ND
0.50
11/11/20 00:06
Dibromomethane
ug/L
ND
0.50
11/11/20 00:06
Dichlorodifluoromethane
ug/L
ND
0.50
11/11/20 00:06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 48

a
�-;ane Analytical
www.psalsbs.000
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
METHOD BLANK: 3064425 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Diisopropyl ether
ug/L
ND
0.50
11/11/20 00:06
Ethylbenzene
ug/L
ND
0.50
11/11/20 00:06
Hexachloro-1,3-butadiene
ug/L
ND
2.0
11/11/20 00:06
Isopropylbenzene (Cumene)
ug/L
ND
0.50
11/11/20 00:06
m&p-Xylene
ug/L
ND
1.0
11/11/20 00:06
Methyl-tert-butyl ether
ug/L
ND
0.50
11/11/20 00:06
Methylene Chloride
ug/L
ND
2.0
11/11/20 00:06
n-Butylbenzene
ug/L
ND
0.50
11/11/20 00:06
n-Propylbenzene
ug/L
ND
0.50
11/11/20 00:06
Naphthalene
ug/L
ND
2.0
11/11/20 00:06
o-Xylene
ug/L
ND
0.50
11/11/20 00:06
sec-Butylbenzene
ug/L
ND
0.50
11/11/20 00:06
Styrene
ug/L
ND
0.50
11/11/20 00:06
tert-Butylbenzene
ug/L
ND
0.50
11/11/20 00:06
Tetrachloroethene
ug/L
ND
0.50
11/11/20 00:06
Toluene
ug/L
ND
0.50
11/11/20 00:06
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
trans-1,3-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
Trichloroethene
ug/L
ND
0.50
11/11/20 00:06
Trichlorofluoromethane
ug/L
ND
1.0
11/11/20 00:06
Vinyl chloride
ug/L
ND
1.0
11/11/20 00:06
1,2-Dichloroethane-d4 (S)
%
96
70-130
11/11/20 00:06
4-Bromofluorobenzene (S)
%
96
70-130
11/11/20 00:06
Toluene-d8 (S)
%
100
70-130
11/11/20 00:06
LABORATORY CONTROL SAMPLE:
Parameter
3064426
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.7
105
60-140
1, 1, 1 -Trichloroethane
ug/L
50
49.5
99
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
50.9
102
60-140
1, 1, 2-Trichloroethane
ug/L
50
50.0
100
60-140
1,1-Dichloroethane
ug/L
50
49.2
98
60-140
1,1-Dichloroethene
ug/L
50
50.7
101
60-140
1,1-Dichloropropene
ug/L
50
48.9
98
60-140
1,2,3-Trichlorobenzene
ug/L
50
52.9
106
60-140
1,2,3-Trichloropropane
ug/L
50
49.2
98
60-140
1,2,4-Trichlorobenzene
ug/L
50
55.4
111
60-140
1,2,4-Trimethylbenzene
ug/L
50
52.1
104
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
54.7
109
60-140
1,2-Dibromoethane (EDB)
ug/L
50
51.4
103
60-140
1,2-Dichlorobenzene
ug/L
50
53.9
108
60-140
1,2-Dichloroethane
ug/L
50
44.7
89
60-140
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48

aceAnalytical
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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
LABORATORY CONTROL SAMPLE:
Parameter
3064426
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloropropane
ug/L
50
50.3
101
60-140
1,3,5-Trimethylbenzene
ug/L
50
51.8
104
60-140
1,3-Dichlorobenzene
ug/L
50
53.7
107
60-140
1,3-Dichloropropane
ug/L
50
52.0
104
60-140
1,4-Dichlorobenzene
ug/L
50
53.7
107
60-140
2,2-Dichloropropane
ug/L
50
47.8
96
60-140
2-Chlorotoluene
ug/L
50
52.8
106
60-140
4-Chlorotoluene
ug/L
50
50.7
101
60-140
Benzene
ug/L
50
50.1
100
60-140
Bromobenzene
ug/L
50
50.2
100
60-140
Bromochloromethane
ug/L
50
49.1
98
60-140
Bromodichloromethane
ug/L
50
49.6
99
60-140
Bromoform
ug/L
50
50.6
101
60-140
Bromomethane
ug/L
50
56.1
112
60-140
Carbon tetrachloride
ug/L
50
46.8
94
60-140
Chlorobenzene
ug/L
50
51.1
102
60-140
Chloroethane
ug/L
50
39.1
78
60-140
Chloroform
ug/L
50
51.3
103
60-140
Chloromethane
ug/L
50
41.6
83
60-140
cis-1,2-Dichloroethene
ug/L
50
48.5
97
60-140
cis- 1, 3-Dichloropropene
ug/L
50
52.1
104
60-140
Dibromochloromethane
ug/L
50
54.2
108
60-140
Dibromomethane
ug/L
50
52.4
105
60-140
Dichlorodifluoromethane
ug/L
50
37.3
75
60-140
Diisopropyl ether
ug/L
50
47.7
95
60-140
Ethylbenzene
ug/L
50
50.0
100
60-140
Hexachloro-1,3-butadiene
ug/L
50
49.4
99
60-140
Isopropylbenzene (Cumene)
ug/L
50
53.1
106
60-140
m&p-Xylene
ug/L
100
102
102
60-140
Methyl-tert-butyl ether
ug/L
50
49.4
99
60-140
Methylene Chloride
ug/L
50
46.6
93
60-140
n-Butylbenzene
ug/L
50
53.1
106
60-140
n-Propylbenzene
ug/L
50
51.2
102
60-140
Naphthalene
ug/L
50
55.8
112
60-140
o-Xylene
ug/L
50
51.0
102
60-140
sec-Butylbenzene
ug/L
50
50.7
101
60-140
Styrene
ug/L
50
52.7
105
60-140
tert-Butylbenzene
ug/L
50
44.3
89
60-140
Tetrachloroethene
ug/L
50
50.4
101
60-140
Toluene
ug/L
50
49.2
98
60-140
trans-1,2-Dichloroethene
ug/L
50
48.8
98
60-140
trans- 1, 3-Dichloropropene
ug/L
50
51.0
102
60-140
Trichloroethene
ug/L
50
50.6
101
60-140
Trichlorofluoromethane
ug/L
50
39.3
79
60-140
Vinyl chloride
ug/L
50
42.4
85
60-140
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 48

aceAnalytical
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I
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
LABORATORY CONTROL SAMPLE: 3064426
Spike LCS
Parameter Units Conc. Result
Toluene-d8 (S) %
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,1-Dichloropropene
1,2, 3-Trichlorobenzene
1,2,3-Trichloropropane
1,2,4-Trichlorobenzene
1,2,4-Trimethylbenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1, 3,5-Trimethylbenzene
1,3-Dichlorobenzene
1,3-Dichloropropane
II A-Dichlorobenzene
2,2-Dichloropropane
2-Chlorotoluene
4-Chlorotoluene
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1, 3-Dichloropropene
Dibromochloromethane
Dibromomethane
Dichlorodifluoromethane
3064427
MS
92504571003 Spike
Units Result Conc.
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L 1180 4000
ug/L ND 4000
ug/L 358 4000
ug/L ND 4000
ug/L 177 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L 4730 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
ug/L ND 4000
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LCS % Rec
% Rec Limits Qualifiers
98 70-130
MSD
Spike
Conc.
3064428
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
4000
4320
4180
108
104
60-140
3
4000
4300
4290
108
107
60-140
0
4000
3920
3900
98
97
60-140
0
4000
4170
4070
104
102
60-140
2
4000
4080
4150
102
104
60-140
2
4000
4590
4630
115
116
60-140
1
4000
4290
4300
107
108
60-140
0
4000
4060
4170
102
104
60-140
3
4000
3890
3920
97
98
60-140
1
4000
4270
4270
107
107
60-140
0
4000
5580
5540
110
109
60-140
1
4000
3960
3960
99
99
60-140
0
4000
4550
4510
105
104
60-140
1
4000
4310
4290
108
107
60-140
0
4000
3810
3850
91
92
60-140
1
4000
4270
4300
107
107
60-140
1
4000
4750
4740
119
118
60-140
0
4000
4380
4380
109
109
60-140
0
4000
4170
4180
104
104
60-140
0
4000
4350
4340
109
109
60-140
0
4000
3440
3470
86
87
60-140
1
4000
4420
4370
111
109
60-140
1
4000
4280
4320
107
108
60-140
1
4000
8930
9240
105
113
60-140
3
4000
4230
4160
106
104
60-140
2
4000
4060
4020
102
101
60-140
1
4000
4070
4040
102
101
60-140
1
4000
3710
3740
93
93
60-140
1
4000
4930
5050
123
126
60-140
2
4000
4170
4300
104
107
60-140
3
4000
4260
4230
107
106
60-140
1
4000
3860
4020
97
101
60-140
4
4000
4300
4040
107
101
60-140
6
4000
3510
3680
88
92
60-140
5
4000
4160
4120
104
103
60-140
1
4000
4040
4090
101
102
60-140
1
4000
4240
4110
106
103
60-140
3
4000
4190
4250
105
106
60-140
1
4000
3740
3720
94
93
60-140
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Qua[
Page 32 of 48

a�
aceAnalytical
www.pacelabs.coo
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3064427
Parameter
Diisopropyl ether
Ethylbenzene
Hexachloro-1,3-butadiene
Isopropylbenzene (Cumene)
m&p-Xylene
Methyl-tert-butyl ether
Methylene Chloride
n-Butylbenzene
n-Propylbenzene
Naphthalene
o-Xylene
sec-Butylbenzene
Styrene
tert-Butylbenzene
Tetrachloroethene
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
MS
92504571003
Spike
Units
Result
Conc.
ug/L
ND
4000
ug/L
1140
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
5010
8000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
3010
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
21100
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
ug/L
ND
4000
3064428
MSD
Spike MS MSD
Conc. Result Result
4000 3870 3950
4000 5420 5410
4000 4100 4020
4000 4550 4560
8000 13600 13900
4000 3980 3910
4000 3760 3850
4000 4300 4380
4000 4630 4590
4000 4340 4420
4000 7380 7480
4000 4380 4390
4000 4320 4290
4000 3840 3840
4000 4310 4320
4000 25000 26300
4000 4210 4300
4000 3950 3960
4000 4340 4270
4000 3980 4030
4000 3780 3840
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MS
MSD
% Rec
% Rec
% Rec
Limits
RPD Qual
96
98
60-140
2
107
107
60-140
0
102
101
60-140
2
114
114
60-140
0
107
111
60-140
2
100
98
60-140
2
94
96
60-140
2
108
110
60-140
2
116
115
60-140
1
104
105
60-140
2
109
112
60-140
1
110
110
60-140
0
108
107
60-140
1
96
96
60-140
0
108
108
60-140
0
98
131
60-140
5
105
107
60-140
2
99
99
60-140
0
109
107
60-140
2
100
101
60-140
1
94
96
60-140
2
98
101
70-130
99
98
70-130
98
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
www.pacolabs.com
I
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 578777 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3062340 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/08/20 11:41
LABORATORY CONTROL SAMPLE: 3062341
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 248 99 90-110
SAMPLE DUPLICATE: 3062342
92504334001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 106000 ug/L 116 9
SAMPLE DUPLICATE: 3062343
92504561002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 61.0 60.0 2
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 578682 Analysis Method: SM 9222D-2006
QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) - AVL
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3061988 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/07/20 15:33
SAMPLE DUPLICATE: 3061989
92504561004 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 35 of 48

aceAnalytical
wtv pacelabs etm
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579004
QC Batch Method: EPA 350.1 Rev 2.0 1993
Associated Lab Samples: 92504561001
METHOD BLANK: 3063400
Associated Lab Samples: 92504561001
Parameter Units
Nitrogen, Ammonia mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 11/10/2011:53
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3063401
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.8 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063402 3063403
MS MSD
92503866004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 1.1 5 5 5.8 5.8 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063404 3063405
MS MSD
92503881001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 29.8 5 5 34.7 34.0 97 84 90-110 2 M1
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 48

aceAnalytical
www.pacelabs.com
r
I
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 579005 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007, 92504561008
METHOD BLANK: 3063406 Matrix: Water
Associated Lab Samples: 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007, 92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 11/10/20 12:37
LABORATORY CONTROL SAMPLE: 3063407
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.8 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063408 3063409
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 95 95 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063410 3063411
MS MSD
92504561003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.7 4.7 94 94 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 48

aceAnaIXical
www.pndabs.com
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 578705 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3062116 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 11/07/20 02:43
LABORATORY CONTROL SAMPLE: 3062117
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3062118 3062119
MS MSD
92504561004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 13.0 1.5 1.5 15.1 14.2 142 84 90-110 6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3062120 3062121
MS MSD
92504561001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.73 1.5 1.5 2.2 2.2 98 97 90-110 1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 578977 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3063304 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/10/20 21:11
LABORATORY CONTROL SAMPLE: 3063305
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063306 3063307
MS MSD
92504561001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.5 2.5 98 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063308 3063309
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.060 2.5 2.5 2.6 2.6 100 101 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579054 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
METHOD BLANK: 3063590
Matrix:
Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
11/09/20 23:19
LABORATORY CONTROL SAMPLE:
3063591
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.6
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063627 3063628
MS MSD
92503890002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 54.6 10 10 65.6 63.7 110 91 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063629 3063630
MS MSD
92503896001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 6.7 10 10 16.7 16.6 100 99 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 48

aceAnalytical
www.pacelabs.com
i
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579055 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561006, 92504561007, 92504561008
METHOD BLANK: 3063596 Matrix: Water
Associated Lab Samples: 92504561006, 92504561007, 92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 11/09/20 23:45
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3063597
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063631 3063632
MS MSD
92504093001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 9.6 10 10 19.1 19.0 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063633 3063634
MS MSD
92504093006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua]
Chloride mg/L 1.7 10 10 12.1 11.9 103 102 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 41 of 48

�-;acie Analytical
www.pacNsbs.cee
I
I
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QC Batch: 579489 Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3065625 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/11/20 23:33
LABORATORY CONTROL SAMPLE: 3065626
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065627 3065628
MS MSD
92502998001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 25.7 25.8 99 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065629 3065630
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 4.6 25 25 29.2 29.3 99 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11/16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 48

aceAnalytical
www.psealsbs.eoe
QUALIFIERS
Project: Lassonde Pappas
Pace Project No.: 92504561
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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�-;aclel Analytical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
Lassonde Pappas
92504561
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92504561001
MW-4
SM 6200B
579267
92504561002
MW-5
SM 6200B
579267
92504561003
MW-6
SM 6200B
579267
92504561004
MW-7R
SM 6200B
579267
92504561005
MW-8
SM 6200B
579267
92504561006
MW-9
SM 6200B
579267
92504561007
SW-1
SM 6200E
579267
92504561008
SW-2
SM 6200B
579267
92504561001
MW-4
SM 2540C-2011
578777
92504561002
MW-5
SM 2540C-2011
578777
92504561003
MW-6
SM 2540C-2011
578777
92504561004
MW-7R
SM 254OC-2011
578777
92504561005
MW-8
SM 2540C-2011
578777
92504561006
MW-9
SM 254OC-2011
578777
92504561007
SW-1
SM 2540C-2011
578777
92504561008
SW-2
SM 2540C-2011
578777
92504561001
MW-4
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561002
MW-5
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561003
MW-6
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561004
MW-7R
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561005
MW-8
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561006
MW-9
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561007
SW-1
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561008
SW-2
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561001
MW-4
EPA 350.1 Rev 2.0 1993
579004
92504561002
MW-5
EPA 350.1 Rev 2.0 1993
579005
92504561003
MW-6
EPA 350.1 Rev 2.0 1993
579005
92504561004
MW-7R
EPA 350.1 Rev 2.0 1993
579005
92504561005
MW-8
EPA 350.1 Rev 2.0 1993
579005
92504561006
MW-9
EPA 350.1 Rev 2.0 1993
579005
92504561007
SW-1
EPA 350.1 Rev 2.0 1993
579005
92504561008
SW-2
EPA 350.1 Rev 2.0 1993
579005
92504561001
MW-4
EPA 353.2 Rev 2.0 1993
578705
92504561002
MW-5
EPA 353.2 Rev 2.0 1993
578705
92504561003
MW-6
EPA 353.2 Rev 2.0 1993
578705
92504561004
MW-7R
EPA 353.2 Rev 2.0 1993
578705
92504561005
MW-8
EPA 353.2 Rev 2.0 1993
578705
92504561006
MW-9
EPA 353.2 Rev 2.0 1993
578705
92504561007
SW-1
EPA 353.2 Rev 2.0 1993
578705
92504561008
SW-2
EPA 353.2 Rev 2.0 1993
578705
92504561001
MW-4
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561002
MW-5
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561003
MW-6
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561004
MW-7R
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561005
MW-8
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561006
MW-9
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39
PM
without the written consent of Pace Analytical Services, LLC.
Page 44 of 48

aceAnalytical
www.pacelabs.com
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas
Pace Project No.: 92504561
Lab ID Sample ID QC Batch Method QC Batch
92504561007
SW-1
EPA 365.1 Rev 2.0 1993
578977
92504561008
SW-2
EPA 365.1 Rev 2.0 1993
578977
92504561001
MW-4
SM
4500-CI-E-2011
579054
92504561002
MW-5
SM
4500-CI-E-2011
579054
92504561003
MW-6
SM
4500-CI-E-2011
579054
92504561004
MW-7R
SM
4500-CI-E-2011
579054
92504561005
MW-8
SM
4500-CI-E-2011
579054
92504561006
MW-9
SM
4500-CI-E-2011
579055
92504561007
SW-1
SM
4500-CI-E-2011
579055
92504561008
SW-2
SM
4500-CI-E-2011
579055
92504561001
MW-4
SM
531OB-2011
579489
92504561002
MW-5
SM
531OB-2011
579489
92504561003
MW-6
SM
531OB-2011
579489
92504561004
MW-7R
SM
531OB-2011
579489
92504561005
MW-8
SM
531OB-2011
579489
92504561006
MW-9
SM
531OB-2011
579489
92504561007
SW-1
SM
5310E-2011
579489
92504561008
SW-2
SM
5310E-2011
579489
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Analytical Method
EPA 365.1 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
Analytical
Batch
579311
579311
Page 45 of 48

Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: October 28, 2020
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.07
Issuing Authority:
Pace Carolinas Quality Office
aceAnalyfical
Laboratory re eiving samples:
Asheville IF-' Eden[—] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta[] Kernersville❑
Client
Sample Condition me:
Upon Receipt
CA/ Project ff:
Courier: ❑Fed Ex ❑UPS ❑USPS 211ent
❑ Commercial ❑Pace ❑Other:
Custody Seal Present? ❑Yes to Seals Intact? ❑Yes
Packing Material: ❑Bubble Wrap PTBubble Bags ❑None ❑ Other
Thermometer:
/" IR Gun 10: (/ ❑Vet ❑Blue
Type of Ice:
/ / Q Correction Factor:
Cooler Temp: J • r J Add/Subtract ('C) [)
Cooler Temp Corrected (°C):
USDA Regulated Soil ( ZrN/A, water sample)
Did samoles oriainate in a ouarantine zone within the United States: CA. NY, or SC (check maps)?
W0f1 : 92504561
IIIII�1111111111111111
Date/Initials Person Examining Contents: ` A
lno
Biologica1Tissue Frozen?
❑Yes ONO J�rN/A
❑None
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
hasbegun
Did samples originate from a foreign source (internationally,
❑Yes [:]No
includingHawaii and Puerto Rico)! IJyes u1vV
Comments/Discrepancy:
Chain of Custody Present?
E 1res
❑No
N/A
1.
Samples Arrived within Hold Time?
es
❑No
❑NIA
2.
Short Hold Time Analysis (02 hr.)?
[]Yes
o
❑N/A
3.
Rush Turn Around Time Requested?
[]Yes
o
[]NIA
4.
Sufficient Volume?
es
[]No
N/A
5.
Correct Containers Used?
-Pace Containers Used?
E!r7es
J21es
[]No
❑No
❑N/A
❑N/A
6.
Containers Intact?
es
[]No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
/A
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
,2fes
❑No
❑NIA
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
[-]No
JKIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
[)NO
❑No
/A
A
11.
COMMENTS/SAMPLE DISCREPANCY
Field Data Required? ❑Yes ❑No
A.�
Lot ID ofsplit containers:
CLIENT NOTIFICATION/RESOLUTION
1
Person contacted: �' , i ;
1 i� ! ��L
/
Date/Time:
Project Manager SCURF Review:
-
Date:
Project Manager SRF Review:
Date:
Page 46 of 48

Document Name:
Document Revised: October 28, 2020
2ceAnai(Sle
ampCondition Upon Receipt(SCUR)
Page 2 of 2
Document No.:
F-CAR-CS-033-Rev.07
Issuing Authority:
Pace Carolinas Quality Office
'�tICc3�
7
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS
"Bottom half of box is to list number of bottles
Project # WO# : 92504561
PM: UP Due Date: 11/13/20
CLIENT: 93—ALTAMONT
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot N
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will to sent 0 the North Carolina DEHNN Lertrncanon Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 47 of 48

• "AnalyV al '
Section A
Section 8
Required Client NHorn sidom.
Required Project IMormadw:
Company: ANCHOR OEA OF NC, PLLC
Report To:
Address: 231 Haywood Street
Copy To:Vul 6101
Asheville, NC 28801
Email r 6%n Lt
Purchase Order /f
Phone' (828)7075M7 Fax
f
Project Name: Lassonde
guested Due Date Project k
a
s
MATRM CODE
3
v
COLL'!
Do—q Wale, Dw
wager wr
v
3
V
W-1. w.- ww
3
Produe P
s
„
SAMPLE ID S.Ivr.w 5L
's
START
One Character per box. W.Pe WP
wppop
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(A-Z. 0.91 . an. Or
#
Sample Ids must be unique T— TS
J
a
a
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DATE
TIME
C'
2
C��vppbw"
3
IVY
4
5
1 VQ-
AAW.,
6
7
W-
8
Uv a^
9
10
11
00
V
0
CHAIN -OF -CUSTODY / Analytical Request Document a
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. a)
m
d
Section C
Invoice Information: Page : _ Of
.-. / " n.. 1 Allenl,on. _
Pace Profile #: 8114
o
_
_
__
J
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END
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ADDITIONAL COMMENTS REL INCUISHED 8Y I AFFILIATION I DATE I TIME ' ACCEPTED BY IAFF11UAT1oN I DATE I TIMEII 1 SAMPLE CONDITIONS I
? I/ i'1'IA1rIil/li;(iA1.f?i(1' Itlln�in lbiq� � LT7 �CC /�'% ���/SJ c fi,PI -r I �J I � I
PLER NAME AND SIGNATURE
PRINT Name of SAMPLE
SIGNATURE of SAMPLER:
Signed: L(I(./?S--)
U
0
c m
1- 3 Y V Y y Y

Attachment 2
Well Sampling Logs and Instrument
Calibration Data Sheet

tZANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number:
C01482-01.01 t 02
Location:
Hendersonville, NC
Date:
1 (� 1
Sampling Personnel
p' A11-.
Weather.
W5
Well ID:
MW4
Arrive at Well:
Screen Interval:
5_15
ft bgs
StartTime:
Depth to Water.
0 ��—
ft
Sample Time:
13
Measuring Point
TOC
Finish Sample Time:
3
II
Depth of Pump Intake:
11.5
ft
Leave Well:
J
Drawdown Set
110
_
ft
Well Diameter.
—_� in
Pump Used (circle):
Perisleftic
Bladder
Other(describe):
Commenm
�d�{
Purge Rate:
Tagged bottom at �'
99 � ft
No 3
1 .1 y
Time: _�
Total Volume Purged:
Pum rr�
PumpSpeed:j�-
pH (S.U.)
Time
Um (het)
Temp Cn
DO (mg/L)
Sp@MC Cond. (p% report to 0.1 S.U. oRp (MV)
Turbtdily (MM
1 fi
I
0 3'1s1
I
�o i
1
�`5:
3
a,
aL
4_
lt.,
1lz___
�Iqq
1`13 C
t��,a-
i q
Lc
a.
3. a2
J
.�
-1- ---
'I --
1
$�
LID
l - ----
-- -
�°
A- -1-
'� - --1 _
?a
-- --
Sampling Personnel Signaeure:
/
Deem
Notes:
Stabilization (3 sucoessive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
16 micro-Siemen mV: millivolt
'C: degrees Celsius NTU: nephelometric turbidity units
bgs below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U. standard units
mg/L: milligrams per Gter toc top of casing
Method Reference:
Temperature: SM 2550 B-2010
DO. SM 4500 0 G-2011
Specific conductivity. EPA Method 1201, Rev. 1982
pH. SM 4500-H' B-201 1
NCDEQ Wastewater
Irrigation System Permit
Number:
W00004797
Page 1 of 1

kZANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number:
C01482-01.01 t 02
Location: Hendersonville, NC
Date:
(` ]-.,
� f�'l=Vn�'l
P
Sampling ersonnel• ��.
Weather.
_ _
�s
Well ID: MW-5
Arrive at Weik
OQ_
Screen Interval: 9.19
ft bgs
Start Trme:
T1
Depth to Water.
ft
Sample Time:
Measuring Point TOC
finish Sample Time:
Depth of Pump Intake: 14
ft
Leave Well:
Drawdown Set A
ft
Well Diameter.
in
Pump Used (circle): Peristakic Bladder
Other (describe):
Comments:
Purge Rate:
Total Volume Purged:
Tagged bottom at } �: W ft
Time: ✓
Pump Speed: ` i f� l�
pH (S.U.)
Tone
DTw (fee" Tamp CQ)
DO (mg/L)
Specific Cond. (I.M
'*P*11 to Mi S.U.
ORP (MV)
Turbidity (NTU)
g
-_[iaa
'_Q
(o
_ li!
Lei.,
li
?7.
O
5.53
it,a.
-
] lblor
61 T, X
K. 3
i
IG
- 1i [_ - -
-_
5-�
?
%
Sampling parecnnel Signature:
_
Data: i
I (o�
Notes:
Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity; +/- O.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flaw (Minimal Dmwdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
yS: micro-Sierren
mV: millivolt
-C degrees Celsius
NTU: nephelometric turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U.: standard units
mg/L: milligrams per liter
toc top of casing
Method Reference:
Temperature: SM 2550 3-2010
DO: SM 4500 O G-2011
Specific conductivity: EPA Method 120.1• Rev. 1982
pH: SM 4500-H' B-2011
NCDEQ Wastewater
Irrigation System Permit
Number:
WQOOO4797
Page 1 of 1

ANCHOR
Q EA ` 4`�
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number:
C01482-01.01 t 02
Location:
Hendersonville, NC
Date:
1 6 V v
Sampling Personnel:
Iy.V-- _
Weather.
Well ID:
MW-6
Arrive at Well:
Screen Interval:
5-10
ft bgs
Start Time:
"10
Depth to Water.
5. 3 3
ft
Sample Time:
Measuring Point:
TOC
Finish Sample Time:
Depth of Pump Intake:
7.5
ft
Leave Well:
ld CJ O
Drawdown Set:
(,1 La 0
ft
Well Diameter.
in
Pump Used (circle):
Peristaltic
Bladder Other (describe):
Comments:
Purge Rate:
Total Volume Purged:
Tagged bottom at: - b
(x-_ ft Time: _l� -7
Pump Speed: s 1 L _
pH (S.UJ
Time
DTW (fwQ
Temp CC) DO (mg/L)
Specific Cond. (pS)
^>�t to 0.1 xU ORP (mV) Turbidity (PfTU)
ID
5•
I�. �1--
3
to _
D
5 Q
t
5.3 at 3
fit•
a,-
_1D10
=to
o
W110
_.� �.
-� .�---
� -
fwb
i
Sampling Personnel Signature
Date: l t (.( n
Notes:
Stabilization (3 successive readings, e.�utes &pert): within +/- 10% DO and turbidity. +/- 3% Conductivity. +/- 0.1 PH unit 4/- 10 mV for ORP
from EPA - Low -Flow 04inunal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
p5: micro-Siemen
mV: millivolt
'C: degrees Celsius
NTU: nephelometdc turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U.: standard units
mgA: milligrams per liter
toc top of casing
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 O G-2011
Specific conductivity EPA Method 120.1, Rev. 1982
PH: SM 4500-H' B-2D11
NCDEQ Wastewater
Irrigation System Permit
Number:
WQ0004797
Page 1 of 1

111ZANCHOR
QEA 4L­4­4i
Low -Flow Sampling Log
Project Name: Lassonde Pappas Groundwater Sampling
Location. Hendersonville, NC
Sampling Personnel 1•lC`
Well ID. MW-7R
Screen Interval: 5-15
It bgs
Depth to Water. O O
ft
Measuring Point TOC
Depth of Pump Intake: 12
ft
Drawdown Set I p d -)
ft
r
Pump Used (circle): Peristaltic Bladder
Other (describe):
Com ments:
Tagged bottom at _tg 3 ft Time: I)qd 11
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Number:
CO1482-01.01 It 02
Date:
+ t 7 70
Weather.
Arrive at Well:
Start Time:
Sample Time:1
Finish Sample Time:
1
Lei
Leave Well:
f 05
Well Diameter.
it%
Purge Rate:
Total Volume Purged:
Pump Speed: ��.A_
Time
DTW (fast)
Tamp (*Q
DO (mg/L)
I
Spaciflc Cord. (pp
PH (S.UJ
report to Q.7 S.U.
ORP (mV)
TurlaWhy (NU)
,r
3, U
oQ 31
10r It 1
y�
�tL, .�?
5•�i
i�� 7
(.D
j�
3
At
�.G,y
i
Liq
i .5q
Q
tL�O�
l
-7I?
C<1A q
tC.� I
t-I
Ilk, L
S
f
I
Sampling PwsomN Signnure:
''�
Date: J )
Notes:
Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity. 4/- 0.1 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
mv: millivolt
•C: degrees Celsius1�
NTU: nephelometric turbidity units
bgs: below ground surface
1r
ORP oxidation reduction potential
DO: dissolved oxygen )
S.U.: standard units
mg/L milligrams per liter �i
toc: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DO:SM 45M O G-2011
pH:SM 4500-H' B-2011
NCDEQ Wastewater
Irrigation System Permit
Number:
WQ0004797
Page 1 of 1

kzANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number.
C0102-01.01 t 02
Location.
Hendersonville, NC
Date:
it 1 L'
Sampling Personnel:
(lkv--
Weather.
40S
Well ID:
MW-8
Arrive at Well:
it
Screen Interval:
3-13
it bgs
Start Time:
O
Depth to Water.
3 1�
7
ft
Sample Time:
Measuring Point
TOC
Finish Sample Time:
f j
Depth of Pump Intake:
10.5
ft
Leave Well:
V +_Z�
Drawdown Set.
8 Lk�
ft
Well Diameter
�]
in
Pump Used (circle):
Peristaltic
Bladder
Other (describer
�r _
Comments:
I (� �'rJ
Purge Rate:
Total Volume Purged:
Tagged bottom at _t L1 it
Time: l Lt f
Pump Speed: i. Lei j1 "
PH (S.U.)
Time
DTW (f-Q
Temp CQ
DO (nWL)
Specific Cond. (pS)
nePeK to A S-U.
ORP (mV)
Turbidity (NTU)
U�li
ti .
13 L/
33-3
"["�3.
� �.?
I ��t�,
Ito,
i;ri 11�
N� I
I
LU
ILA
Sampling Personnel Signature:
fie: 't
1✓ v
Notes
Stabilization (3 successive readings, 3 min �-O-wiMin +/- 10% DO and rurbidil)r +/- 3% Conductivity,- +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minima( Dmwdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Sierren mv: millivoft
°C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg/L: milligrams per liter toc: top of casing
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 45000 G-2011
Specific conductivity: EPA Method 1201, Rev. 1982
PH: SM 4500-H' B-2011
NCDEQ Wastewater
Irrigation System Permit
Number:
WQ0004797
Page 1 of 1

ANCHOR
OE
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling Project Number: Co14a2.01.01 t 02
Location: Hendersonville, NC Date: tl 6
Sampling Personnel: � �
Weather. y�
Well ID: MW-9
Screen Interval: ynknoWr
Arrive at Well: LiN3
ft bgs Start Time: tt��
Depth to Water. L-lt lL r 1
ft Sample Time: a
_
Measuring Point: TOC
Finish Sample Time: a 3
Depth of Pump Intake: ]S �-
k�� Leave Well: o 7
Drawdown Set:
la
ft Well Diameter: in
Pump Used (circle): Peristakic
Bladder Other (describe):
Comments:
Purge Rate: _--- --___--
Total Volume Purged:
Tagged bottom at: tD«J ft Time: ►a 31? _ Pump Speed: 3 .el?4--a'
PH (S.U.)
Time DTW (fw Q
Tway CQ DO (mg/L) SpsdRc Cond. 46) report to 0.1 £U. ORPP (mN) Turbidity (NM
777
_ .
-&d-�
i -kec LCA-
- - -
ur -
��
- ----- --tfnD
5
= . S
0.0 _ 3
LtA- - 3`4_ - -
_ 2_
1
Samp&V Person« SlytnWrc
Dow I /(,
Notes.
Stabilization (3 successive readings, Via, r apart): within +/- 10% DO and turbidity, +/- 3% Conductivity. +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - tow -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
'C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 0 G-2011
mV: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
S.U.: standard units
toc: top of casing
Specific conductivity. EPA Method 120.1, Rev. 1982
PH: SM 4500-H' B-2011
41 NCDEQ Wastewater
Irrigation System Permit
Number:
WQ0004797
Page 1 of 1

kzANCHOR
QEA 4..4..4--,
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling Date: 1
Project Number C01482-01.01 t 02
-ol S.-
Weather. RAAaAn�4idol
Sampling Personnet 1.7�
J
Sample Name: SW-1
Comments: upstream of site !
"5tYe/(1M--VF
kVkAC—
Sample Method: i" Grab
Syringe
Pump Bailer-Disp. Other.
Dissolved
Specific Cond.
pN (S.U.)
Oxkhdlon
Reduction
Twbldity
Time Temp (•C) Oxygen (mg/L)
(PS/cm)
report to 0.1 S.U.
Potential (mv)
(MM
comments
(� 96%
( `
SampUng container
Number of ConfaYwrs
Requested Anelysls
500 mL Plastic
250 mL Plastic
125 mL Plastic--
UQ
40 mL Glass
1 L Glass
Other
Vegetation:
Access: -�va'
Sampling Personnel Signature: ly, Date: (�
em.mb.
Samples are analyzed immediately upon collection.
'C: degrees Celsius
y5/cm: micro-Siemen per cubic centimeter
mg/L• milligrams per liner
mv: miFivolt
NTU: nephelometric turbidity units
S.U.: standard units
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
NCDEQ Wastewater
Irrigation System Permit
Number:
WQ0004797
Page 1 of 1

ANCHOR
Surface Water Sampling Log
Anchor QFA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Date: II W v -)
Project Number. C01482.01.01 t 02
Weather
ALI �O S
Sampling Personnel: hA
Sample Name: sW2
Comments: Downstream ofsi6e
1
Sample Method: Grab /-"
Syringe Pump
Bailer-Disp. Other.
Dissolved
Specific Cond.
pH (S.U.)
Reduction
Turbidy►
Time Tamp (-C)
Oxygen (nWL)
(NS/nrt)
report to a I S.U.
Potential (mv)
0M
eo111meMf
Sampling container
Nundw of containers
Requested Anabolls
S00 mL Plastic
1
250 mL Plastic-
125 mL Plastic
__
Z
— --
40 mL Glass
t✓ -
-
1 L Glass
—
Other —
Vegetation: SrbVYW Access: 0Y,_ -ice/\ Lt 51Aj ofvi-ve4'r
Samping Personnel Signature: - Dap:
Notes:
Samples are analyzed immediately upon co8ection.
'C: degrees Celsius
NS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
m%t. milivoft
NTU: nephelometric turbidity units
S.U.: standard units
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity. EPA Method 120.1, Rev. 1982
DCP. SM 4500 O C-2011
pH: SM 4500-H' B-2011
NCDEQ Wastewater
Irrigation System Permit
Number:
W Q0004797
Page 1 of 1

kzANCHOR
Q EA
Equipment Documentation and Instrument Calibration Data Sheet
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
CALIBRATION DOCUMENTATION y�
Project Name: 11 t 61nll Yyp k � Person Conducting Calibration:
Project Number. Date of Calibration: J\ %d
Project Location: Date of Field Measurements: ,lJ L I7C7
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Select Turbidimeter Hach 21000 (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Instrument Reading
Inshument Reading
(Hach 21001
(HF Scientific MicroTPW)
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
0.02 NTU
Calibration Expiration
ii 11
l 3!
tit a1
III )
Date:
Cal-
Cal:
Cal:
Cal:
Cal:
Cal:
Time:
Time
Time:
Time:
Time:
Time:
Calibration
'Pre-Analysis
Meals: rr
Time:
U�ZT
'Pre -Analysis
Meas:
7me:
Verification:
Check (10 NTU):
Check (10 fill
"Post -Analysis
Meal
Time:
'Post -Analysis
Meas:
Time:
Check (10 NTU):
S O
Check (10 NTU):
YSI Professional Plus Multipwanketer Meter (s/n 188101802)
Instrunten Readings
Calibration Lot No.
8t Expiration Date
Dissolved Oxygen
Initial: �1
&61 7.
Cal:
CA CJ 610
mmHg:
)
Temperature CQ:
1 3
Time: �/
n [b
,U
v (
pH 7 S.U.
Initial
`� pHmV:
Cal:
pHmV:Time-
t O
a�
report to 0.1 S.U.
U O
PH 4 S.U.
�, `
Initial: 1k,4
pHmV:
Cal: ; (_, �
✓L
pHmV:
'�
Time:
� �`� y
` V
report to 0.1 S.U.
prt 10 S.U.
Initial:I- �
61 (/�
pHmV:
Cal:
1 a
pHmV-
Time: (
�-7 !L
V�
report m 0.1 S.U.
'
-�`
'
v l 1
QC' pH 7 S.U. report
AM Time:n
o
Mil
�j
Mid Day Time:
Check
PM Time:
C�� .
to 0.1 S.U.
U '
Spec Cond.
Initial:
Cal:j
Time:
070
6
W 6 0 pstcr,
)030
QC':
073
AM Time:
Meas:
Mid Day Time:
Check:
PM Time:
i4 of
Check:
Ps/cn
u
% Recove =
�, c?r1� mV
ORP Uvv
Initial: G
�3. ✓
Cal-
1�- t c Z�
Temperatures (oQ:
��, f
Ilime
lJ`l 0 V
V�jC��
Signature: ; ��— Date: h'
Notes:
Revision 3, 04/30/20, MHF
1. Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, OC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated
S. • QC check must be performed prior to sampling and following completion of sampling, at a minimum.
6. % Recovery = (Value Obtained, µ5/cm + True Value, yS/cm) z 100
Method Reference: Temp: SM 2550 8-2010 1 Conductivity EPA Method 720.7 1 DO SM 4500 0 G-2011 I pH: SM 4500-H+8.2071 I Turbidity. SM 2730 8-2011
NCDEQ Wastewater
�ry Irrigation System Permit
tnJ Number:
W00004797
Page 1 of 1

ENVIRO-EQUIPMENT, INC.
YSI PRO+ CALIBRATION DATA SHEET
Serial Number: Date:10U Inspectot`T6P-A-__
Calibration Check (Performed At Lab Room Temperature)
Solution/Value
Manufacturer
Lot Number Expiration
Reading-
Accuracy
pH 4.00
AquaPhoenix
C(COW_
Cra
t0.2
pH 7.00
AquaPhoenix
, ✓ ( L�
-1 • d 2-
t0.2
pH 10.00
AquaPhoenix
2'Z
�G Q I
t0.2
Conductivity
1000 µS/cm
AquaPhoenix
FLS�CIlI t 1
.SolutionlValue
Manufacturer
Lot Number Expiration
Reading
Accurac•I
ORP 200 mV
AquaPhoenix
CrA--eY�}•OmV
t20111V
Solution/Value
Calibration Type
Temperature Barometer Reading
Reading
Accuracy
Dissolved Oxygen
Saturated Air
°C ► 4., J
c
2010
Date of last D.O. membrane cap replacement: j0 Z$
ZG
Dissolved oxygen accuracy:
0 - 200% air saturation: f2% of reading or 2% air saturation
200% to 500%
air saturation: +6% of reading
"Note all standard solution values are at 25°C. **
Temperature Check
Testo 925
(NIST Traceable) °C t0.5°C
YSI Pro+ �� °C f0.2 °C
Inspector's Maintenance Notes
FEI PRO+ CAL FORM
NCDEQ Wastewater
Irrigation System Permit
Number:
W00004797

CHAIN -OF -CUSTODY l Analytical Request Document
r
.rs.nnu.r.wa The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section 8 Section C
Required Client Information: Required Project Information: Invoice Information: Poi 1 Of 1
Company ANCHOR QEA OF NC, PLLC Report To: a e j a Attentwsn
Address: 231 Haywood Street Copy To: N _ Comoanv Nan -
Asheville, NC 28801
dress:
tie A'
Emeit
Purchase Order#: r f -
Pare Quole:
Phorla' (828)707.6R27 Fax
Project Name: Lassonde P a
Pace Project Manager: lorri.pattonapecelabaxorn,
/
Requested Due Date:
Project #:
Pace Profile #: 8114
iMPilfhilid
MATRIX CODE
3
$
'
a
0
`i
COLLECTED
z
0
Preservatives
i<
5.,
22
g
DriWngw"'DW
WT
Wx.Vv w WW
B
Q
W
SAMPLE ID ��"�ai0
8
cti
START
END
One Character per box. Wme AARR
is
.T
W
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$
(A-7- (1-91. OT
Sample Ida must be unique 71— Ts
$
K
m
D
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yXm
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a
ce
D
W
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=
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DATE
TIME
DATE
TIME
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• ADOrTIONAL COMMENTS
RFUNCPJWWD BY I AFFIUATION
DATE
.TIME
ACCOPWUIBY AAFKJl\i10N
DATE
TIME
a11MPLt CONDITIONS
S S
V,
y
tJ
SAMPLER NAME AND VISMIATURE
U
PRINT Name of SAMPLER: M•
j
'm 8
SIGNATURE of SAMPLER:
DATE Signed: f 1 ^']�.�

Attachment 3
DEQ GW-59A — Compliance Report Form

GW-59A COMPLIANCE REPORT FORM Permit # WQ0004797
(Submif one each monitoring period with GIY-59 fur nc.)
I
Enter date monitoring results were due. (12/31/202o) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
X
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or- missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? ff the answer is "Yes ", contact the Regional Office for guidance.
X
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
Nitrate (21, = 10 mg/L): MW-7R® 13.0 mg/L
Fecal Coliform (Total Coliform 2L standard = 1.0 CFU/100mL): MW-50 8.0 CFU/100ML, MW-6® 3.0 CFU/100mL, MW-8® 14.0 and
MW-90 16.0
5
For the constituents identified In question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) In the last two years?
X
If the answer to question 5 Is "NO", skip to section 8.
if the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
Nitrate Fecal Coliform Fecal Coliform Fecal Coliform Fecal Coliform
MW-7R (mg/L) KW-5 (CFU/100mL) MW-6 (CFU/100mL) MW-8 (CFU/100mL) MW-9 (CFU/100mL)
05/21/19: 20.2 05/21/19; 7.0 05/21/19: 23.0 05/21/19: <10.0 05/21/19:
:10.0
11/14/19: 17.1 11/14/19: 7.0 11/14/19: 44.0 11/14/19; 2.0 11/14/19: 1.0
05/06/20: 21.5 05/06/20: 8.0 05/06/20: 3.0 05/06/20: �1.0 05/06/20: <1.0
11/06/20: 13.0 11/06/20: 8.0 11/06/20: 3.0 11/06/20: 14.0 11/06/20: 16.0
6
Are the monitoring wells listed In section 6 located at or beyond the review boundary?
YES
X
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer Is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
X
If the answer to question 7 is 'YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may sublect the permittee to a Notice of Violattgm
fines, and/or penalties.
Fecal coliform should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud
Creek has found high levels of fecal coliform. The surface water sample collected in Mud Creek upstream of the site
had higher fecal coliform concentrations than the sample collected downstream of the site.
High nitrate concentrations may be attributable to the frequent flooding of Mud Creek. As a proactive approach to
avoid introducing additional nitrogen into soils at the facility, Clement Pappas has implemented the practice of
baling harvested fescue and removing it from the irrigation fields, instead of mowing it and allowing it to decompose.
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the Information submitted In this
report (Compliance Report GW-69A) Is true and complete to the best of my knowledge.
Signatufe of Permittee (or Authorized Agent) Date
G%V-59A 12/8/2003

Attachment 4
DEQ GW-59 — Groundwater Quality
Monitoring: Compliance Report Forms

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
, , ,
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
161T MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 / 31 / 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
® Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 828 - 3 2 9 - 6 64 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW - 4
Date sample collected: 11 / 0 6 / 2 0 2 0 FIELD ANALYSES:
WAS
Well Depth: 18 2 pft.
Well Diameter: 2 in.
pH ooaoo: 5 . 30 units Temp. 000lo: 18 . 1 °C
DRY at
_
Depth to Water Level azsas: 8 - 02 ft. below measuring point Screened Interval: _ift. to
1 r, ft. Spec. Cond. 000sa: 230.4 µMhos
time ofsampling,
Measuring Point is 2 . 43 ft. above land surface
Relative M.P. Elevation: 2063.77 ft.
Odor00085: none
check
Volume of water pumped/bailed before sampling: 0 - 4 0 gallons screened interval is relative to land
surface Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved
and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 < 1 . 0 /100mL
Nitrate (NO3) as N 00620 0.73
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 < 0 - 0 5
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 148 mg/L
Al - Aluminum oil o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 2 .8 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 6. 9 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only • • •
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENT 3 NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
�
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
12 Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW- 5
Date sample collected: 11 / 0 6 / 2
0 FIELD ANALYSES:
WAS
Well Depth: 18 _ , p ft.
Well Diameter: 2 in.
pH 00400: 5 . 65 units Temp. 000lo: 18.2 °C
DRY at
Depth to Water Level 82546: 8 . 9 0 ft. below measuring
point Screened Interval: 9 * ft. to
19 * ft. Spec. Cond. 00094: 64.5 µMhos
time of
sampling,
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2085.60 ft.
Odor 00085: none
check
* screened interval is relative to land
Volume of water pumped/bailed before sampling: 0.36 gallons
surface
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 8.0 /100mL
Nitrate (NO3) as N 00620 < 0 . 04 0mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 0 . 06 0 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 61.0 mg/L
Al - Aluminum 01105
mg/L Tetrachloroethene - 0.80 pg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L Trichloroethene - 1.0 pg/L
TOC 00680 4.6 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 6.9 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only Total • _ • •
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
_lac' oof_AlvaE M AIVA✓ �,
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Perrnittee (or Authorized Agent) (Date)
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENT 3 NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 3 1 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
IS Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION MW- 6
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11
/ 0 6 / 2 0 2 0
FIELD ANALYSES:
WAS
Well Depth: 11 • 58 ft.
Well Diameter: 2
in.
pH 00400: 5 • 23 units Temp. 00010: 16 . 4 °C
DRY at
Depth to Water Level 82546: 5 . 3 3 ft. below measuring point Screened Interval: 5 * ft. to 10 *
ft. Spec. Cond. 00094: 202.6 µMhos
time of
sampling,
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2061.17
ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling: 0.70 gallonSscreened interval is relative to land surfaceAppearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead olo51 ug/L
Coliform: MF Fecal 31616 3.0 /100mL
Nitrate (NO3) as N 00620
3.2 mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
< 0 . 0 5 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 139 mg/L
Al - Aluminum oil o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 2.6 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 12.5 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
�P E v'D �s� �✓ rA c-rA Z
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.8/2013

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 3 1 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside
Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
® Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation
Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
MW - 7R
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 0 6 / 2
0 FIELD ANALYSES:
WAS
Well Depth: 17 j 7 ft.
Well Diameter: 2 in.
pH 00400: 5 . 54 units Temp. 000lo: 14 .3 °C
DRY at
_
Depth to Water Level 82546: 10 . 0 5ft. below measuring point Screened Interval: 5 ft.* to
15 ft* Spec. Cond. 00094: 311.6 µMhos
time of
sampling,
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2062.86 ft.
Odor 00085: none
check
Volume of water pumped/bailed before sampling:
* screened interval is relative to land
0.47 gallons
surface
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 < 1 . 0
/100mL
Nitrate (NO3) as N 00620 13.0
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665 < 0 . 0 5
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
lissolved Solids:Total 70300 205
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680 1.7
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 17.8
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only • • •
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
V4 pt: A k�oY ks,) �✓ � 4 &-r-" /-' A
Permittee (or Authorized Agent) Name and Title - Please print or type
Signature of Permittee (or Authorized Agent) (Date)
GW-59 Rev.8/2013

6UtiM1 I FOKM UN YtLLUW F Al tK UNLY
GROUNDWATER QUALITY MONITORING:
COMPLIANCE REPORT FORM
117An11 ITV 1\111T^M&AA"^L1 Please Print Clearlv or
acility Name: Clement Pappas
ermit Name (if different):
acility Address: 485 Brookside Camp Road
Hendersonville NC 28792 County Henderson
act Person: Mrs. Tracy Wolfe Telephone#:[phone]
Location/Site Name: Irrigation area No. of wells to be sampled: 6
iEPARTMENT OF ENVIRONMENT 3 NATURAL RESOURCES
iIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
RMIT Number: Expiration Date:
n-Discharge WQ0004797 UIC
PDES Other
YPE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump ❑ Other:
ILL ID NUMBER (from Permit): MW- 8 Date sample collected: 11 / 0 6 / 2 0 FIELD ANALYSES:
I Depth: 13 _ 9-Ift. Well Diameter: 2 in. pH 00400: 6 . 34 units
ith to Water Level 82546: 8 - 3 7 ft. below measuring point Screened Interval: 3 ft* to 13 ft* Spec. Cond. 00094:
isuring Point is 3 . 00 ft. above land surface Relative M.P. Elevation: 2060. 80 ft. Odor 00085: none
lme of water pumped/bailed before sampling: 0.60 gallonS screened interval is relative to land surfaceAppearance
sales for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO
)ate sample' analyzed varies; see analytical report LaboratoryName: Pace Analytical Services
1ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L
Coliform: MF Fecal 31616
14.0
/100ml-
Nitrate (NO3) as N 00620
2.4 mg/L
Coliform: MF Total 31504
/100ml-
Phosphorus: Total as P 00665
<0 . 05 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
issolved Solids:Total 70300
127
mg/L
Al - Aluminum oilo5
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680
2.8
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
2.3
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L
Phenol 32730
ug/L
Fe - Iron 01045
ug/L
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L
pecific Conductance 00095
µMhos
K - Potassium 00937
mg/L
Total Ammonia 00610
< 0 - 10
mg/L
Mg - Magnesium 00927
mg/L
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L
Temp.00010: 14.5 °C
229.0 µMhos
Certification No. 3 7 712
Pb - Lead olo51 ug/L
Zn - Zinc 01092 mg/L
Other (Specify Compounds and Concentration Units):
ORGANICS: (by GC, GC/MS, HPLC)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached? ® Yes (1) ❑ No (0)
method #
method #
method #
method #
For Remediation Systems Only Total• • •
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
orz-gsd
/
Permittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Agent) D.
GW-59 Rev. 8/2013
If WELL
WAS
DRY at
time of
sampling,
here: ❑

SUBMIT FORM ON YELLOW PAPER ONLY
MEMEMIDEPARTMENT
OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW - 9
Date sample collected: 11 / 0 6 / 2 0 FIELD ANALYSES:
WAS
Well Depth: 1 g-L
Well Diameter: 2 in.
pH ooaoo: 4 - 93 units Temp. 00010: 18 .4 C
DRY atft.
Depth to Water Level 82546: 4 . 10 ft. below measuring point Screened Interval: 3 ft* to
13 ft* Spec. Cond. 000sa: 55 . 4 µMhos
time of
sampling,
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor 00085: none
check
* screened interval is relative to land surface
Volume of water pumped/bailed before sampling: 0.30 gallons Appearance
here: ❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 16.0 /100mL
Nitrate (NO3) as N 00620 0.043
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 0.095
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 88. 0 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 4.5 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 1.4 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
pecific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remedlation Systems Only Total•Total• •
I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
DE 6,VD6��6, tE Lrne l LAA V ,2-lr61C_
Permittee (or Authorized Agent) Name and Title - Please print or type
Permittee (or Authorized
(Date)
GW-59 Rev.8/2013