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HomeMy WebLinkAboutWI0300127_Regional Office Historical File Pre 2018ATA NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary March 23, 2009 Mr. John W. Kirby NCDOT Roadside Environmental Unit 4809 Beryl Road Raleigh, NC 27606 Ref: Issuance of Injection Permit WI0300127 NCDOT — Roadside Environmental Unit Former NCDOT Asphalt Testing Laboratory #35 Rockwell, North Carolina. Dear Mr. Kirby: 0 9 7.009 1i In accordance with the application received on November 12, 2008, and the supporting data submitted December 5, 2008, and March 17, 2009, we are forwarding permit number WI0300127. This permit is for a pilot study to inject EOS® solution plus 1000 gallons of potable "chase water" to remediate groundwater contaminated with chlorinated solvents at the former NCDOT Asphalt Testing Laboratory #35 facility located in Rockwell, Rowan County, North Carolina. This permit shall be effective from the date of issuance until February 28, 2011, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS. Please note that during a site inspection by the Mooresville Regional Office (MRO), two monitoring wells (35MW-1 and 35DW-1) were partially covered by road construction materials and possibly damaged and do not meet well construction requirements per Title 15A NCAC 2C .0100. If the wells are damaged beyond repair and need to be replaced, a permit will need to be obtained from the MRO. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at 919-715-6166 or Michael.Rogers@ncmail.net if you have any questions about your permit. cc: Anci w _tue es i�lde„ i a1�(�7ffG Robert Bost, BOSTCO tEEC Jessica Dehart, Solutions-IES WI0300127 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 Phone: 919-733-32211 FAX 1: 919-715-0588; FAX 2: 919-715-6048 l Customer Service: 1-877-623-6748 Internet: www.ncwaterquality.orq An Equal Opportunity 1 Affirmative Action Employer Best Regards, Michael Rogers Environmental Specialist Aquifer Protection Section. NorthCarolina Naturally NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO NCDOT - Roadside Environmental Unit FOR THE CONSTRUCTION AND OPERATION OF 6 TYPE 5I INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject EOS 598, to stimulate bioremediation of chlorinated ethenes. These injection wells/points will be located at the NCDOT Former Asphalt Testing Laboratory Site #35, 500 Industrial Drive, Rockwell, Rowan County, North Carolina, and will be operated in accordance with the application submitted November 12, 2008, and in conformity with the specifications and supporting data submitted December 5, 2008, and March 17, 2009, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Actor any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until February 28, 2011, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the day of 11'`e\N — , 2009. f Coleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission. Permit No. WI0300127 PAGE 1 OF 6 ver.8/07 AP/UIC-6 shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment. 3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with short-term exposure to chemicals in the product proposed to be used include eye, skin, nose, and throat irritation. Significant inhalation exposure can cause coughing, wheezing, and shortness of breath. The chemicals may cause a skin allergy where very low exposures can cause itching and skin rash. 2. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 3. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 4. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 5. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 6. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. Permit No. WI0300127 PAGE 6 OF 6 ver.8/07 AP/UIC-6 AQUIFER PROTECTION REGIONAL STAFF REPORT Date: 12/17/08 To: Aquifer Protection Central Office Central Office Reviewer: Thomas Slusser Regional Login No: County: Rowan Permittee: NCDOT Project Name: NCDOT Asphalt Site #35 Application No.: WI0300127 L GENERAL INFORMATION 1. This application is (check all that apply): ® New ❑ Renewal ❑ Minor Modification ❑ Major Modification n Surface Irrigation ❑ Reuse n Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon n Land Application of Residuals n Distribution of Residuals ❑ Attachment B included ❑ Surface Disposal n Closed -loop Groundwater Remediation ❑ 503 regulated ❑ 503 exempt ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? N Yes or ❑ No. a. Date of site visit: 12/09/08 b. Person contacted and contact information: onsite fellow working with Bost Construction (current site owner is Bostco LLC) c. Site visit conducted by: Andrew Pitner & Maria Schutte d. Inspection Report Attached: n Yes or ® No. 2. Is the following information entered into the BIMS record for this application correct? ® Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. For Treatment Facilities: info in BIMS for the facility was updated by MRO a. Location: b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: e. Regulated Activities / Type of Wastes (e.g., subdivision, food processing, municipal wastewater): For Disposal and Injection Sites: info in BIMS for the facility was updated by MRO (If multiple sites either indicate which sites the information applies to, copy and paste a new section into the document for each site, or attach additional pages for each site) a. Location(s): see above b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: II. NEW AND MAJOR MODIFICATION APPLICATIONS (this section not needed for renewals or minor modifications, skip to next section) Section II is not applicable to this project. FORM: APRSR040929-UIC review NCDOT Asphalt #35 1 AQUIFER PROTECTION REGIONAL STAFF REPORT III. RENEWAL AND MODIFICATION APPLICATIONS (use previous section for new or major modification systems) Section III is not applicable to this project. IV. INJECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description Of Well(S) And Facilities — New, Renewal, And Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QM/5QW) ® In situ remediation (5I) n Closed -loop groundwater remediation effluent injection (5L/"Non-Discharge") ❑ Other (Specify: ) 2. Does system use same well for water source and injection? ❑ Yes0 No 3. Are there any potential pollution sources that may affect injection? ® Yes ❑ No What is/are the pollution source(s)? The injection is designed to treat groundwater contamination associated with previous use of chlorinated solvents at the site by a DOT lab. The former lab location is now partly occupied by several fuel ASTs and their containment structure. The injection wells are proposed to be installed about 60 feet from the ASTs. There is no data at this point that suggests that the ASTs are a significant source of pollution, though some very minor staining was observed in their vicinity. What is the distance of the injection well(s) from the pollution source(s)? Roughly 60 ft from the former lab.. 4. What is the minimum distance of proposed injection wells from the property boundary? —225ft. 5. Quality of drainage at site: n Good Adequate ❑ Poor 6. Flooding potential of site: // Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ® Yes n No. Attach map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater -monitoring program: 8. Does the map presented represent the actual site (property lines, wells, surface drainage)? ❑ Yes or ® No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow. Maps provided don't do a very good job of illustrating property lines, but do adequately show significant site features in the vicinity of the injection area. If the CO wants a map from MRO's GIS, let us know and we'll send one. FORM: APRSR040929-UIC review NCDOT Asphalt #35 2 AQUIFER PROTECTION REGIONAL STAFF REPORT Injection Well Permit Renewal And Modification Only: This section not applicable to this project. Y. EVAL UATIONAND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the application: This is a small-scale injection intended to remediate a small plume of dissolved chlorinated solvents from a DOT asphalt testing lab. In terms of potential receptors, there is one water supply well about 1500 feet away that is not likely to be impacted by any injection activities. The facility and adjacent businesses are connected to municipal water supply. Unnamed tributaries to Second Creek can be found to the south and east sides of the property; the closest to the injection is to the east about 250 feet and it is also unlikely to be impacted by the injection given the volume of injectant, distance and conductivity of the regolith. One issue is that the key monitoring wells, 35MW-1 and 35DW-1, have been partially covered by gravel & asphalt due to activities at the site. After scraping briefly with a shovel, one of the well covers was visible and part of the pad of the other well was visible. These wells need maintenance as they are in a traffic area — likely reconstruction of the protective covers and pads — but it is possible they might need to be replaced if the wells have been damaged beyond repair. If replacement were necessary, then a permit would be required from the MRO. Otherwise, the MRO sees no significant issues with this proposal and recommends that it be permitted. 2. Attach Well Construction Data Sheet - if needed information is available 3. Do you foresee any problems with issuance/renewal of this permit? n Yes ® No. If yes, please explain briefly. 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: Condition Reason 6. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason 1. Maintenance / repair to 35MW-1 and 35DW-1. 1. These MWs have been partially covered by gravel/asphalt. FORM: APRSR040929-UIC review NCDOT Asphalt #35 3 AQUIFER PROTECTION REGIONAL STAFF REPORT 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; n Issue upon receipt of needed additional information; Issue; ❑ Deny. If deny, please state reasons: 8. Signature of report preparer(s): Andrew HPitner Signature of APS regional supervisor: Andrew HPitner Date: December 17, 2008 ADDITIONAL REGIONAL STAFF REVIEW ITEMS FORM: APRSR040929-UIC review NCDOT Asphalt #35 4 TABLE 1 Summary of Groundwater Analytical Data for Target Compounds NCDOT Former Asphalt Laboratory Site #35 Rockwell, North Carolina NCDOT WBS #36413.1.49 Well ID Sampled by Sample Date 1,1,1- TCA 1,1,2- TCA 1,1- DCA 1,2- DCA 1,1- DCE Chloroethane PCE TCE cis-1,2- DCE trans DCE Chloroform Vinyl Chloride NC 2L Standard 200 NE 70 0.38 7 2,800 0.7 2.8 70 100 70 0.015 SHALLOW MONITORING WELLS 35MW-1 G&M 12/13/1996 120 <25 <25 <25 ,170::: <25 <25 ,410;. <25 <25 <25 <25 G&M 12/13/1996* 120 <50 <50 <50 a220 ' <50 <50 500 `_ <50 <50 <50 <50 Solutions-IES 2/21/2006 35 <0.5 4.8 <0.5 120 <0.5 ;`18 .. 1300: 2.9 - <0.5 3.0 <0.5 Solutions-IES 8/8/2006 63 <25 <25 <25 ``:240:._ <25 <25 ;1800.!; <25 <25 <25 <25 35MW-2 G&M 11/22/1996 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35MW-3 G&M 12/13/1996 <1 <1 <1 <1 <1 <1 <1 <1 <I <1 <1 <1 G&M 12/13/1996* <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 - <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35MW-4 G&M 11/22/1996 <1 <1 <I <1 <I <I <1 <1 <1 <1 6 <1 G&M 11/22/1996* <1 <1 <1 <1 <1 <l <I <1 <1 <1 5 - <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 <0.5• <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 - <0.5 35MW 5 G&M 11/22/1996 . <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35MW-6 G&M 4/3/1997 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 • <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35MW-7 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 En ull DEC - 9 2003 119 -1TC DrhlR iVIRO DWQ - Ac infer Protection Page 1 of 2 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS — IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS F. MONITORING PLAN F.1 Monitoring Wells The following wells will be used for post -injection monitoring: • 35MW-1 • 35MW-4 • 35DMW-1 • 35DMW-2 • 35DMW-7 RECEIVED / DENR / DWQ AQUIFFRPR(1TFCTION SECT NC DENR MRO DWQ - A. uifer Protection Table 3 provides a summary of the well construction for existing monitoring wells and proposed temporary injection wells. F.2 MONITORING PARAMETERS AND ANALYTICAL METHODS During each sampling event, a set of site -wide water level measurements will be collected from all monitoring wells. Each well to be sampled will then be purged and DO, ORP, specific conductance, pH, and temperature measurements will be taken. Groundwater samples will then be collected and submitted to a certified laboratory for analysis of VOCs (Method 8260 B), Total Organic Carbon (Method 5310B), Nitrate (Method 353.2), Sulfate (Method 375.4). F.3 MONITORING SCHEDULE A groundwater monitoring event will be conducted prior to injection activities to act as a baseline for evaluation of groundwater data. Post -injection monitoring will be completed at 1-month and 3-months following injection at the wells indicated in Section F.1. At approximately 6-month post injection, groundwater monitoring will be conducted at all on -site monitoring wells. G. WELL DATA Well construction data for the existing monitoring well network and the proposed temporary injection wells are presented in Table 3. A receptor survey conducted in 2004 by Hart & Hickman did not identify any water supply wells within 1500 feet of the site. 11 • 0 0 0 Z W 0] r W� 0 ›- OD ❑ W 0 U W U m p 0 0 W 0 W J a 125) RIgC 11J8. 35MW-2 35MW-7 35MW-3 4-1 C7 35DW-6 <0.5 35DW-1 310 2.8 351\m-1 tl 335DW-2 2.820 35MW-6 35DW-4 <0.5 35DW-3 <0.5 35MW-5 1So1utions -IES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. RECEIVED / DENR / DWQ AQUIFFR'PROTECTION SECTION DEC 052008 ---- 2.8 LEGEND 35 MW-5 SHALLOW MONITORING WELL 35 DW-1 DEEP MONITORING WELL TCE CONCENTRATION (ug/L) ESTIMATED EXTENT OF TCE ABOVE 2L STANDARD 0 50 100 SCALE IN FEET FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA TCE ISOCONCENTRATION MAP DEEP AQUIFER AUGUST 2006 FIGURE: 7 >- Q] ❑ o 0 U W 0 U 35MW-3 <0.5 0 co W a 0 s LL 35DW-6 LJ 35MW-6 <0.5 L. 35DW-4 1800 2.8 35DW-3 35MW-5 <0.5 AQU! FR PROD FCT ON/SFCQ DEC p 5 r�o� 2008 LEGEND 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL TCE CONCENTRATION (ug/L) ESTIMATED EXTENT OF TCE ABOVE 2L STANDARD 0 50 100 SCALE IN FEET Solutions -JES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA TCE ISOCONCENTRATION MAP ,SHALLOW AQUIFER AUGUST 2006 FIGURE: 6 AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: November 19, 2008 To: ❑ Landon Davidson, ARO-APS ❑ David May, WaRO-APS ❑ Art Barnhardt, FRO-APS ❑ Charlie Stehman, WiRO-APS ►.� . n t�ew �',�ttner. O+wA1PS 111 Sherri Knight, WSRO-APS ❑ Jay Zimmerman, RRO-APS From: Thomas Slusser , Groundwater Protection Unit Telephone: (919) 715-6164 E-Mail: thomas.slusser@ncmail.net A. Permit Number: 0VII`[+16iU;)112it7es B. Owner: NCDOT ROADSIDE ENVIRON. UNIT Fax: (919) 71 C. Facility/Operation: FORMER ASPHALT TESTING FACILITY ® Proposed ❑ Existing ❑ Facility SQ• I� 1 =C1 IVVy?E "' -NOV 2 1 2008 NC.DENR MRO C'' DWQ`- A. uiter Protection ® Operation D. Application: 1. Permit Type: ❑ Animal N Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle N I/E Lagoon ❑ GW Remediation (ND) UIC - (5I) in -situ groundwater remediation For Residuals: ❑ Land App. ❑ D&M N S• urface Disposal ❑ 503 ❑ 503 Exempt N A• nimal 2. Project Type: ® New ❑ Major Mod. ❑ Minor Mod. ❑ Renewal ❑ Renewal w/ Mod. E. Comments/Other Information: N I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 5 0 iznzlarflays; please take the following actions: ,E) Return a Completed Form APSSRR. ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO*. * Remember that you will be responsible for coordinating site visits, reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 02/06 Page 1 of 1 Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Coleen H. Sullins Director Division of Water Quality November 18, 2008 Mr. John W. Kirby NCDOT-Roadside Environmental Unit 4809 Beryl Road, CEP 880-1911 Raleigh, NC 27606 Subject: Acknowledgement of Application No. WI0300127 NCDOT Former Asphalt Testing Laboratory Site # 35 Injection In situ Groundwater Remediation Well (5I) Rowan Dear Mr. Kirby: EHE NOV 2 1 2008 NC DENR MRO DWQ -A uifer Protection The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on November 12, 2008. This application package has been assigned the number listed above and will be reviewed by Thomas Slusser. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Thomas Slusser at 919-71.5-6164 or via e-mail at thomas.slusser@ncmail.net. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart, go to http://h2o.enr.state.nc.us/documents/dwq orgchart.pdf. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sine 1y, j for Debra atts Supervisor cc: Maoresa��id ebiona ff Aqui+f Prottecfiori bion Solutions-IES (Jessica L. Dehart, 1101 Nowell Rd., Raleigh, NC 27607) Permit Application File WI0300127 NorthCarolina Naturally Aquifer Protection Section 1636 Mail Service Center Internet: www.ncwaterquality.orq Location: 2728 Capital Boulevard An Equal Opportunity/Affirmative Action Employer- 50% Recycled/10% Post Consumer Paper Raleigh, NC 27699-1636 Telephone: (919) 733-3221 Raleigh, NC 27604 Fax 1: (919) 715-0588 Fax 2: (919) 715-6048 Customer Service: (877) 623-6748 State of North Carolina Department of Environment and Natural Resources Division of Water Quality APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated groundwater. • Submit TWO copies of the completed application and all attachments to the address on the last page of this form. • Any changes made to this form will result in the application package being returned. Application Number (to be completed by DWQ): I. GENERAL INFORMATION: 1. Applicant's Name (generally the responsible party): NCDOT - Roadside Environmental Unit 2. Signing Official's Name: Mr. John W. Kirby Title: Project Manager 3. Mailing address of applicant: 4809 Beryl Road City: Raleigh Telephone number: 919-835-8481 State: NC Zip: 27606 Fax number: 919-715-0679 4. Property Owner's Name (if different from Applicant): BOSTCO, LLC. 5. Property Owner's mailing address: 500 Industrial Drive City: Rockwell State: NC Zip: 28138 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Jessica L. Dehart Company: Solutions-IES Address: 1101 Nowell Road Title: Project Hydrogeologist City: Raleigh State: NC Zip: 27607 Telephone number: 919-873-1060 Fax number: 919-873-1074 Email Address: jdehart@solutions-ies.com PERMIT INFORMATION: Project 2. if this applic existing perr, For renewal form, and o For all rene date. Revised 8/07 New 0 Modification of existing permit ❑ Renewal of existing permit without modification Renewal of existing permit with modification or er ii : u t d. r s or modification to an existing permit, provide: 1and the issuance date t t modifications, fill of �e miler& si a ou must submit a statu NC DENR MRO DWQ - Aquifer Protection t lions I & II only, sign the certification on the last page of this re to indicate consent (if the applicant is not the owner). report including monitoring results of all injection activities to RECEIVED / DENR / DWQ IC-51/5T Aquifer Protection Section NOV 12 2008 Page 1 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION 1. Facility name: NCDOT Former Asphalt Testing Laboratory Site #35 2. Complete physical address of the facility: 500 Industrial Drive City: Rockwell County: Rowan State: NC Zip: 28138 B. INCIDENT DESCRIPTION 1. Describe the source of the contamination: The site formerly housed an NCDOT asphalt testing laboratory facility. NCDOT conducted on -site testing of asphalt using ASTM Method D2172-88. The method required the use of a solvent (such as TCE, 1,1,1-TCA, or CT) to extract petroleum binder from the aggregate. Solvents stored, spilled or disposed of on -site near operating Tabs resulted in releases of chlorinated solvents to the environment. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Chlorinated ethenes 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ❑ Yes If yes, list maximum measured separate phase thickness feet El No If no, list maximum concentration of total VOCs observed at site: 2,103 ppb 4. Agency managing the contamination incident: ❑ UST Section ❑ Superfund Section (including REC Program and DSCA sites) ❑ DWQ Aquifer Protection Section ❑ Solid Waste Section ❑ Hazardous Waste Section i Other: IHSB (formerly DWQ Aquifer Protection Section 5. Incident managers name Unknown (not assigned) and phone number 919-508-8400 6. Incident number or other site number assigned by the agency managing the contamination incident: NONCD0002166 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: NA 2. DWQ Non -Discharge or NPDES permits: NA 3. County or DEH subsurface wastewater disposal permits: NA 4. Other environmental permits required by state or federal law: NA Revised 8/07 UIC-5I/5T Page 2 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA 1. List all proposed injectants. NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the Occupational and Environmental Epidemiology Section (OEES) of the Division of Public Health, Department of Health and Human Services. Review the list of approved injectantsT or contact the UIC Program to determine if the injectants you are proposing have been reviewed by OEES. Injectant: EOS 598 (emulsified vegetable oil 60%, aqueous solution 40%) Concentration at point of injection: 10% solution Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Source of fluids used to dilute or chase the injectants listed above: ❑ None N Municipal water supply ❑ Groundwater from private well or any well within 'A mile of injection site ❑ Air ❑ Other: 3. If any well within'/4 mile of injection site, a private well, or surface water is to be used as the fluid source, supply the following information: a. Location/ID number of source: NA b. Depth of source: c. Formation: d. Rock/Sediment type: e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit application form. You must apply for a closed -loop groundwater remediation permit using application form GPM'. Revised 8/07 UIC-51/5T Page 3 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Maximum number of separate injection events: 1 Expected duration of each injection event: 3-5 days Expected duration between events (if more than one event): 2. Injection rate per well: 2 gallons per minute (gpm) 3. Total Injection volume: 3,030 gallons per day (gpd); gallons per event (if separate events) 4. Injection pressure: <10 psi pounds/square inch (psi) 5. Temperature at point of injection: ambient °F 6. Briefly describe how the above parameters will be measured and controlled: Flow distribution manifold with flow meters, gate valves, and pressure gauges. 7. Estimated hydraulic capacity of the well: 2 gpm gpm C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: ❑ Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. El Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: Solutions-IES (Brian Reber); Parratt Wolff, Inc. NC Well Contractor Certification number: SIES: 3061-B Parratt Wolff: 2487 3. Date to be constructed: November 2008 Number of borings: 6 Approximate depth of each boring (feet): 3 @ 20 ft bgs; 3 @ 50 ft bgs 4. Screened interval/Injection interval of injection wells: Depth: 10 to 60 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: ® PVC ❑ Stainless steel ❑ Other: Casing depth: 0 to ft. shallow 0-10ft; deep 0-50 6. Grout (N/A if injection is through direct push rods): Type: I Cement ❑ Bentonite ❑ Other: Grout depth: 0 to 7 ft. shallow. Deep 0-45 ft. Revised 8/07 UIC-5I/5T Page 4 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection V. ATTACHMENTS Provide the following items as attachments with the given headings: A. SITE HISTORY Provide a brief description of the site history including: (1) site usage historically and present, (2) origin of the contamination, (3) previous remedial action(s). NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or her. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) the regional geologic setting; (2) significant changes in lithology; (3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and (4) the depth to the mean seasonal high water table. C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within A mile of the injection site is used as the source well, include chemical analysis of source fluid here. D. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) goals of the injection project; (2) a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: (1) (2) (3) (4) construction plans and materials; operation procedures; a detailed diagram of the surface and subsurface portions of the system; and a planned injection schedule. F. MONITORING PLAN Provide a plan for monitoring the results of the injection, including: (1) a list of existing and proposed monitoring wells to be used; (2) a list of monitoring parameters and analytical methods to be used; and (3) a schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by- products, or formation fluids outside the injection area or zone. The monitoringparameters should include the target contaminants as well as secondary or intermediate contaminants which may result from the injection and other parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and Revised 8/07 UIC-5I/5T Page 5 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated reactions and rate of transport of the injectants and contaminants. G. WELL DATA Provide a tabulation of data on all existing or abandoned wells within' 'A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open borehole depth interval, and well construction or abandonment record, if available. H. MAPS Attach the following scaled, site -specific maps: (1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site. (2) Site map including: a. all property boundaries; b. all buildings within the property boundary; c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within' 'A mile of the injection well or well system; e. all surface water bodies within'/a mile of the injection well or well system; and f. all existing or abandoned wells within'/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. (3) Potentiometric surface map(s) including: a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant plume, including isoconcentration lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross-section(s) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology Revised 8/07 UIC-51/5T Page 6 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection VI. CERTIFICATION I, t-TO a-/4 ... VV . K t i - )1,V , hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature: Title: N'ti' 0 T- i4GC: Date: l eV i S eUa If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the above agent. VII. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. I, BOSTCO, LLC. , as owner of the property on which the injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200) Signature: t�• Title: PD d-4— rlt.'- Date: U(1 /es s Submit TWO copies of the completed application package, including all attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 Revised 8/07 UIC-5I/5T RECEIVED / DENR / DWQ Aquifer Protertinrn Qantion NOV 12 2008 Page 7 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells - In Situ Groundwater Remediation/Type 5T Wells — Tracer Injection This work has been prepared under my direct supervision as per G. all drawings, reports, or documents involving geologic work which approved by a licensed geologist or a subordinate under his or her by him or her. Jessica L. Dehart, P.G. Printed Name S. 89E-131twhich requires that shall have been prepared or direction be singed ancije i,,a® �. • ��GE Pl O•�2 v i SEAL irt rn : 2169 if — a �"Se N 14amest®®�® RECEIVED / DENR / DWQ Aquifer Protection Section NOV 12 2008 t 't ATTACHMENTS APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS —IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS A. SITE HISTORY A.1 BACKGROUND Site #35 is located on approximately 10.75 acres about one mile northwest of downtown Rockwell, North Carolina at 500 Industrial Drive. Figure 1 shows the approximate location of the site, and Figure 2 depicts the approximate site layout. The site formerly housed an NCDOT asphalt testing facility and was an active asphalt plant until the early 1990s. The property is currently owned by Bostco, LLC and is used as a vehicle maintenance facility with a small adjacent aboveground storage tank (AST) farm containing fuel for the construction vehicles. Historical information on the years of laboratory operation and solvent types and usage at this location is not available. However, other NCDOT testing facilities in North Carolina generally ceased operations in the early 1990s. NCDOT conducted on -site testing of asphalt at many asphalt -producing facilities using American Society for Testing and Materials (ASTM) Method D 2172-88. The ASTM test method required the use of a solvent such as trichloroethene (TCE), 1,1,1-trichloroethane (1,1,1-TCA) or carbon tetrachloride (CT) to extract the petroleum binder from the aggregate. The aggregate was then subject to a particle size gradation test. According to NCDOT, on -site laboratories primarily used TCE and 1,1,1-TCA in progression when the laboratory was in operation. The solvents were usually purchased new, and were reused until they were no longer effective. Recycled solvents possibly containing impurities were also used. Solvents stored, spilled or disposed of onsite near operating laboratories, resulted in releases of chlorinated solvents to the environment. The NCDOT entered into a memorandum of agreement with the North Carolina Department of Environment and Natural Resources (NCDENR) Division of Water Quality's (DWQ) Groundwater Section in 1999 outlining the objectives and procedures to be used in evaluating the potential environmental impacts at former asphalt testing laboratories. Since that time, the NCDENR has undergone a reorganization and the asphalt sites are currently under the jurisdiction of the Inactive Hazardous Sites Branch (IHSB). 1 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS -IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS A.1.2 Environmental Assessments and Remedial Actions An initial site screening conducted by NCDOT in 1989 indicated the presence of TCA and TCE in a soil sample collected at an unspecified location. A comprehensive site assessment (CSA) was conducted by Geraghty & Miller in 1996 and early 1997 which included a soil vapor survey, soil and groundwater sample collection and analysis, installation of 10 monitor wells, surveying, water level measurements, and aquifer testing. Results of the CSA indicated the possible presence of target chlorinated solvents in the soil vapor samples in the vicinity of the former asphalt testing laboratory. The Geoprobe® groundwater investigation identified the presence of TCE, TCA, and 1,1-dichloroethene (1,1-DCE) at concentrations above the 15 NCAC 2L.0202 groundwater standards (NC 2L standards) in one groundwater sample collected in the vicinity of the former asphalt testing laboratory. The CSA concluded that the extent of TCE-impacted soils was horizontally delineated, but not vertically delineated. In addition, the lateral extent of target chlorinated solvents had been adequately defined for the shallow groundwater plume; however, the vertical extent of target chlorinated solvents had not been fully defined. In a letter dated July 1, 1997, the NCDENR issued written comments on the CSA submitted in May 1997. The letter agreed with the CSA that the vertical extent of target chlorinated solvents in soil and groundwater had not been adequately delineated. The letter recommended additional soil sampling at the location of SS-3 to define the vertical extent of soil contamination, additional monitor wells adjacent to or downgradient of SS-3 (the presumed source area), and an additional deep monitor well to the east of 35MW-3 to define the horizontal extent of deep groundwater contamination. Solutions-IES conducted soil and groundwater sampling in August 2006 to complete the delineation activities. An additional shallow monitoring well was installed in the presumed source area. Soil samples were collected during well installation activities to define the extent of soil contamination remaining in this area. In addition, two deep monitoring wells were installed with the intent of delineating the horizontal extent of groundwater contamination in the western portion of the site (35-DW6) and the vertical extent of contamination in the current groundwater plume area (35-DW7). APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS —IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS B. HYDROGEOLOGIC DESCRIPTION B.1 REGIONAL GEOLOGIC SETTING The town of Rockwell is situated within the Carolina Slate Belt, part of the Piedmont physiographic province. Bedrock within the Carolina Slate Belt is predominantly composed of low grade metavolcanic rocks. The site is located in an area described as being underlain by metavolcanic rock of interbedded mafic to felsic tuffs on the 1985 Geologic Map of North Carolina (North Carolina Geologic Survey). The mafic rocks are described as medium grayish green to dark green to black, fine -to medium -grained andesitic to basaltic tuffs and flows. The typical Piedmont aquifer system is divided into three zones. These zones include the unconsolidated saturated soil zone, the underlying saprolite and weathered bedrock. All three zones are interconnected and act as a single aquifer system, although each zone varies in its ability to transmit water (permeability). The base of the Piedmont bedrock aquifer is indistinct and occurs where the fracture system is no longer effective in transmitting flow. The number of fractures decreases with increasing depth, and often fractures are non -water bearing below a depth of approximately 300 feet (Heath, 1980). The site is specifically underlain by the Cecil Loam soil unit (CeB2) (NRCS Web Soil Survey 2.0). This soil type is described as: "sandy clay loam". B.2 SIGNIFICANT CHANGES IN LITHOLOGY The characteristics of the subsurface materials at the site were evaluated from the description of onsite borings completed by Geraghty & Miller, as well as information obtained during the installation of new monitor wells in July 2006 by Solutions-IES. Figure 3 shows the location of cross sections across the site generated from historical and recent boring information. Figures 4 and 5 are cross sections showing the site lithology. Based on the boring logs, the subsurface materials generally consist of 1 to 2 feet of fill material overlaying interbedded clays and silts to a depth of approximately 15 feet and sandy silts to the top of a saprolite layer. The bedrock at this site was encountered at approximately 50 ft bgs and was overlain by 1 to 5 feet of saprolite. Numerous fractured zones were identified during the drilling of borings for the deep monitor wells. 3 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS -IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS At the site, the shallow aquifer includes surficial sediments and saprolite and has been delineated during previous work at the site as land surface to approximately 50 ft bgs. The deep aquifer lies below the 50 ft bgs depth and consists of a highly fractured zone to a depth of approximately 60 ft bgs under which lies competent bedrock with few fractures. B.2.1 Current Site Conditions Only one well (35MW-1) screened in the shallow groundwater monitoring zone contained concentrations of target compounds above the NC 2L standards during the February and August 2006 sampling events. TCE concentrations in 35MW-1 have been detected in concentrations ranging from 1300 µg/L in February 2006, to 1800 µg/L in August 2006, while 1,1-DCE has been detected at concentrations of 120 µg/L and 240 µg/L in February and August 2006 respectively. Target compounds detected above the NC 2L standards in monitoring wells screened in the deep aquifer include 1,1-DCE and TCE. Concentrations of 1,1-DCE have been detected in 35DW-1 at concentrations ranging from 57 µg/L to 41 µg/L in February and August 2006 respectively. TCE has historically been detected in 35DW-1 at concentrations as high as 820 µg/L, but has most recently been detected at 310 µg/L in both the February and August 2006 events. In well 35DW- 2, concentrations of TCE appear to be decreasing, with the most recent concentrations being 21 µg/L and 20 µg/L, in February and August 2006 respectively. Table 1 provides a summary of historical groundwater analytical data. In summary, TCE and 1,1-DCE are the main target compounds presently detected in groundwater at Site #35 at concentrations above the NC 2L standards. Target compounds were detected above the NC 2L standards in monitor wells 35MW-1, 35DW-1, and 35DW-2 (Figures 6 and 7). Of these wells, the most favorable conditions for reductive dechlorination were detected in 35DW-2. Generally reducing conditions were also detected in 35DW-1. Based on current conditions, there is some indication of natural biodegradation of TCE to cis-1,2-DCE in 35DW-1; however, in 35MW-1 and 35DW-2 there has been little change (or increase in TCE) with no appearance of daughter products. In fact, the current TCE concentration in 35MW-1 is more than double the 1996 concentration. Conversely, in all three wells with target compounds, the concentration of 4 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS — IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS 1,1,1-TCA has decreased appreciably since 1996 with the accompanying presence of 1,1-DCE, which is an abiotic breakdown product of 1,1,1-TCA. B.2.2 Lithology of the Injection Area Based on the boring logs, the subsurface materials generally consist of 1 to 2 feet of fill material overlaying interbedded clays and silts to a depth of approximately 15 feet and sandy silts to the top of a saprolite layer. The bedrock at this site was encountered at approximately 50 ft bgs and was overlain by 1 to 5 feet of saprolite. Numerous fractured zones were identified during the drilling of borings for the deep monitor wells. At the site, the shallow aquifer includes surficial sediments and saprolite and has been delineated during previous work at the site as land surface to approximately 50 ft bgs. The deep aquifer lies below the 50 ft bgs depth and consists of a highly fractured zone to a depth of approximately 60 ft bgs under which lies competent bedrock with few fractures. B.3 HYDROGEOLOGIC PARAMETERS USED FOR DESIGN Groundwater at the site flows in a south to southeasterly direction in both the shallow and the deep aquifer toward the unnamed creek located along the southeastern border of the property. The water -level elevation data collected during the August 2006 sampling event were used to create a potentiometric surface map of the shallow aquifer (Figure 8). The overall groundwater gradient was estimated from the August 2006 water level data to be approximately 0.03 ft/ft in the shallow aquifer and 0.007 ft/ft in the deep aquifer. Geraghty & Miller estimated that the average hydraulic conductivity for the shallow aquifer was 0.79 ft/day and 25.54 ft/day in the bedrock aquifer. The average groundwater velocity at this site was estimated to be 27 ft/year. Using a geometric mean hydraulic conductivity of 0.79 ft/day, an average hydraulic gradient of 0.03 ft/ft between 35MW-2 and 35MW-4, and an estimate of 30 percent for porosity, the site -wide groundwater flow velocity is estimated as: K Ah 0.79ft/day x0.03ft/ft=0.079ft/day 0.30 5 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS -IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS where K is the hydraulic conductivity, Ne is the effective porosity, and Ah/Al is the slope of the water table; which is appropriate for contaminant transport calculations downgradient of the source area. B.4 DEPTH TO MEAN SEASONAL HIGH WATER TABLE During the most recent groundwater sampling event in August 2006 by Solutions-IES, the water levels in the shallow aquifer ranged from 18.87 ft below top of casing (btoc); (elevation of 724.0 ft above mean sea level (amsl)) in MW-4 to 13.98 ft btoc (elevation of 731.17 ft amsl) in MW-7. The water levels in the deep aquifer ranged from 17.69 ft btoc (elevations of 724.44 ft asml) in monitoring well DW-4 to 16.28 ft btoc (elevation of 726.63 ft amsl) in DW-6. These values are consistent with historical water levels recorded at the site. Table 2 provides a summary of the historical water levels at this site. C. INJECTION FLUB) COMPOSITION The injection fluid is a stable emulsified -oil concentrate (EOS®) composed of food -grade soybean oil, surfactants, amino acids, and vitamins blended to maintain a non -separated phase concentrate. The concentrate will be diluted in the field with potable water to assist in distribution into the aquifer. The emulsified liquid contains oil droplets in the 0.7 to 1.5 micron size range which allow for ease of dilution, simplicity of injection and optimal subsurface distribution. The EOS® will be handled according to the manufacturer's recommendations and in accordance with the site's Health & Safety Plan. All materials used in the process are Generally Recognized As Safe (GRAS) food -grade materials (21 CFR 184.1400). A Material Safety Data Sheet for EOS® is included in Appendix A. The water source will be from a potable water supply obtained from the City of Salisbury, which provides potable water to this area. D. INJECTION RATIONALE D.1 GOALS OF THE INJECTION PROJECT The remediation goal for groundwater is to return it to its most beneficial use (which is drinking water). The NC 2L Standards are proposed as the cleanup goals for groundwater. The goal of this injection is to introduce a biodegradable organic substrate into portions of the aquifer with high VOC concentrations to stimulate microbial activity and enhance reductive dechlorination of 6 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS — IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS dissolved chlorinated ethene contaminants present in groundwater at the site. Six injection wells will be utilized for the injection of EOS®, chase water and Vitamin B-12. The well configuration provides for two treatment zones with three injection wells per zone: one zone in the shallow aquifer and one zone in the deep aquifer. The locations of the six proposed injection wells are shown on Figure 9. D.2 INJECTANT/CONTAMINANT REACTIONS This project injects a biodegradable organic substrate into a contaminated aquifer. The technology involves a one-time injection of slowly biodegradable, emulsified oil substrate (EOS®). EOS® is a water miscible emulsion with an engineered droplet size that is prepared using food -grade edible oils, surfactants, macro- and micronutrients. The EOS® process is patented by Solutions-IES (U.S. Patent #US RE40,448E). The emulsion is injected and distributed throughout the treatment zone using conventional injection wells. The vegetable oil becomes trapped within the sediment grain pores leaving a residual oil phase to support long-term anaerobic biodegradation of the target contaminants. As the oil slowly biodegrades, it provides a continuous source of dissolved organic carbon to the native microbial community to stimulate microbiological consumption of oxygen and production of hydrogen. This reaction is illustrated generically in Equation 1: (Eq. 1) C18H3202 (linoleic acid) + 34 H2O --Bacteria--> 18 CO2 + 50 H2 The organic substrate is the electron donor in this sequence of reaction. The hydrogen itself then drives the desired anaerobic biological metabolism of the target contaminants by a second, more specialized, group of microorganisms. These metabolic biotransfonnations are illustrated in Equations 2 through 5 where hydrogen is used sequentially to replace each chlorine atom: (Eq. 2) C2C14 (PCE) + H, -- Bacteria --> C,HC13 (TCE) + Cl + H (Eq. 3) C2HC13 (TCE) + H, -- Bacteria --> C2H2C1, (DCE) + Cl + H+ (Eq. 4) C,H2C12 (cis%trans-DCE) + H2 -- Bacteria --> C2H3C1(VC) + Cl + H+ (Eq. 5) C2H3C1 (VC) + H2 -- Bacteria --> C2H4 (ethene) + CI + H+ APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS - IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS Overall, four hydrogen molecules (4H2) are needed to completely dechlorinate the PCE molecule to chloride. D.3 MODELING AND TESTING RESULTS Reductive dechlorination of chlorinated ethenes using a carbon source electron donor is a proven groundwater remediation methodology. The amount of EOS® injected into the subsurface is determined based on the concentrations of the target compounds (TCE and 1,1-DCE), the concentrations of competing electron acceptors (i.e., dissolved oxygen, nitrate, sulfate, manganese dioxide and ferric iron) and hydrogeologic conditions (i.e., subsurface lithology and heterogeneity, hydraulic conductivity and effective porosity of the treatment zone). The available site -specific information obtained from the Comprehensive Site Assessment (Geraghty & Miller, 1997) and testing by Solutions-IES in August 2006, were entered into the design spreadsheet provided by EOS Remediation of Raleigh, NC. The design indicated that 5 drums (approximately 1,300 lbs) of EOS® would be required to treat both injection zones. The design life for this amount of substrate is approximately 3 to 5 years. To optimize the injection process, the injection was designed to involve diluting the concentrate 10-fold as it is injected until all the EOS® has been placed in the aquifer. Then the EOS® is further distributed away from each injection point using potable chase water. EOS® has been thoroughly tested and is manufactured from food grade soybean oil, emulsifying agents, micronutrients, vitamin B-12 and water. EOS® was used in a source area treatment project at the Tarheel Army Missile Plant (TAMP) in Burlington, NC. In 2004, Solutions-IES injected 13,000 pounds of EOS® concentrate into the 100 x 100 ft (30.5m X 30.5m) zone believed to be the primary source area for the TCE plume. The EOS® treatment quickly stimulated anaerobic conditions as evidenced by decreased dissolved oxygen, oxidation-reduction potential, and sulfate concentrations and increasing ferrous iron, and methane. TCE was gone and only degradation products were evident within one year of treatment. The regular monitoring program confirmed the effectiveness of the selected treatment technology. Suitable conditions were established for the contaminants to be reduced to non -chlorinated end -products. 8 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS - IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS E. INJECTION PROCEDURE AND EQUIPMENT E.1 CONSTRUCTION PLANS AND MATERIALS A total of six temporary injection wells will be installed to treat both the shallow and deep treatment zones. Three shallow borings will be advanced drilled using Geoprobe® direct push drilling techniques. The borings will be advanced to approximately 20 feet below ground surface (ft bgs). The shallow injection wells will be constructed as 1-inch diameter PVC with 10 feet of 0.020-slot screen. An appropriately sized sand pack will be placed around the screen to approximately 2 feet above the top of the screen. The remaining annular space will be backfilled with bentonite pellets (periodically hydrated as they are added to the annular space) to within 3 feet of land surface. The last 3 feet of annular space shall be completed with a bentonite grout cement mix. In addition, three deep borings will be advanced using air -rotary drilling techniques. The borings will be advanced to approximately 60 ft bgs. A temporary surface casing will be set during well construction to prevent caving of the overburden. The deep injection wells will be constructed as 2-inch diameter PVC with 10 feet of 0.020-slot screen. An appropriately sized sand pack will be placed around the screen to approximately 2 feet above the top of the screen. The remaining annular space will be backfilled with bentonite pellets (periodically hydrated as they are added to the annular space) to within 3 feet of land surface. The last 3 feet of annular space shall be completed with a bentonite grout cement mix. After injection activities are completed, all of the temporary injection wells will be abandoned. Injection activities will be conducted in two phases, one phase will inject into the shallow aquifer and the other phase will inject into the deep aquifer. For each phase of the injection process, the wells will be manifolded together, but will have individual flow meters, gate valves and pressure gauges. The Dosatron® diluter (or transfer pump) will be plumbed into a splitter that will allow individual wells to be shut off from the injection process as needed. This will allow for the control of pressure and flow rates of injection at each well. The manifold will be plumbed to a Dosatron® with a potable water source (City of Salisbury) to provide dilution of the EOS® concentrate. The Dosatron® will only allow a maximum total flow of 7 gpm. Therefore, to inject three wells simultaneously the injection rate will be limited to 2 gpm per well. 9 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS - IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS E.2 OPERATING PROCEDURES Implementation of the process involves on -site blending of the EOS® concentrate with potable water utilizing a Dosatron® water -powered proportional dosing pump. A Dosatron® will be set up on a drum of EOS® via a flexible hose. Water from a fire hydrant will go through a City supplied flow meter, then into the Dosatron® for use in diluting the EOS® to the proper 10:1 concentration (10 parts water to 1 part EOS®). If the Dosatron® proportional dosing pump is unable to achieve the design flow rate, alternative mixing and pumping approaches will be implemented. Alternative designs may include using dilution tanks, chemical feed and transfer pumps to conduct the injection. The mixture will then be piped to the splitter where the injectant will be directed into flexible hoses going to each well head manifold. Each braided hose line will have a flow meter to determine the total volume of injectant going into each well. A gate valve and pressure valve at each well manifold will allow field personnel to monitor and adjust flow rates and fluid pressures during the injection process. E.3 SYSTEM DESIGN The EOS® solution will be injected into 6 temporary injection wells located down gradient of the source area (Figure 9). The injection process will be performed during one mobilization in several steps. EOS® concentrate will be diluted with potable water to a 10% concentration using an in -line metering system. Approximately 505 gallons of dilute EOS® will be injected into each of the 6 wells via the EOS® Metering System. Afterwards, approximately 1,000 additional gallons of potable water will be injected to move the emulsion out into the formation away from each well. If an injection rate of one gpm is achievable, then the injection should be completed within approximately three days. However, if injection rates are significantly less, then additional time in the field will be required. Figure 10 shows a schematic of the injection process. E.4 INJECTION SCHEDULE The injection is anticipated to occur during the Fall of 2008. The injection well installation activities will commence within one month of receiving an approved UIC permit. The actual injection of EOS® will occur within two weeks of the completion of the injection wells. 10 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 5I WELLS —IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS F. MONITORING PLAN F.1 Monitoring Wells The following wells will be used for post -injection monitoring: • 35MW-1 • 35MW-4 • 35DMW-1 • 35DMW-2 • 35DMW-7 Table 3 provides a summary of the well construction for existing monitoring wells and proposed temporary injection wells. F.2 MONITORING PARAMETERS AND ANALYTICAL METHODS During each sampling event, a set of site -wide water level measurements will be collected from all monitoring wells. Each well to be sampled will then be purged and DO, ORP, specific conductance, pH, and temperature measurements will be taken. Groundwater samples will then be collected and submitted to a certified laboratory for analysis of VOCs (Method 8260 B), Total Organic Carbon (Method 5310B), Nitrate (Method 353.2), Sulfate (Method 375.4). F.3 MONITORING SCHEDULE A groundwater monitoring event will be conducted prior to injection activities to act as a baseline for evaluation of groundwater data. Post -injection monitoring will be completed at 1-month and 3-months following injection at the wells indicated in Section F.1. At approximately 6-month post injection, groundwater monitoring will be conducted at all on -site monitoring wells. G. WELL DATA Well construction data for the existing monitoring well network and the proposed:temperry, injection wells are presented in Table 3. A receptor survey conducted'in xxx by xxx did nod identify any water supply wells within 1500 feet of the site. 11 APPLICATION FOR PERMIT To CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION TYPE 51 WELLS - IN SITU GROUNDWATER REMEDIATION SECTION V. ATTACHMENTS H. MAPS The following maps are attached: Figure 1 Figure 2 Figure 3 Figure 4 Figure 5 Figure 6 Figure 7 Figure 8 Figure 9 Figure 10 REFERENCES Site Location/Topographic Map Site Layout Cross Section Trace Geologic Cross Section A -A' Geologic Cross Section B-B' Shallow Groundwater TCE Isoconcentration Map — August 2006 Deep Groundwater TCE Isoconcentration Map — August 2006 Shallow Groundwater Potentiometric Surface Map — August 2006 Proposed Injection Locations Injection Schematic Geraghty & Miller, 1997. Comprehensive Site Assessment, May 1997. Heath, R.C. 1980. Ground -Water Regions of the United States. United States Geological Survey Water Supply Paper 2232. LeGrand, H.E., Sr. 1967. Ground Water of the Piedmont and Blue Ridge Province in the Southeastern United States. United States Geological Survey Circular 538. 12 TABLES TABLE 1 Summary of Groundwater Analytical Data for Target Compounds NCDOT Former Asphalt Laboratory Site #35 Rockwell, North Carolina NCDOT WBS #36413.1.49 Well ID Sampled bySample p Date 1,1,1- TCA 1,1,2- TCA . 1,1- DCA 1,2- DCA 1,1- DCE Chloroethane PCE TCE cis-1,2- DCE trans-1,2 DCE Chloroform Vinyl Chloride NC 2L Standard 200 NE 70 0.38 7 2,800 0.7 2.8 70 100 70 0.015 DEEP MONITORING WELLS 35DW-1 G&M 12/13/1996 :'430= <100 <100 <100 .180 <100 <100 . 820 <100 <100 <100 <100 G&M 1/21/1997 s:260 <1 <1 1 : ,150J; <1 1 °' 520 <1 <1 <1 <1 G&M 1/21/1997* -.=370e-, <1 <1 1 140; : <1 ; 1 660 <1 <1 <1 <1 G&M 4/3/1997 430`. <1 <1 2 160 <1 2 `:. 780 <1 <1 <1 <1 G&M 4/3/1997* 420 <1 <1 2 150 <1 1 , =:750 <1 <1 <1 <1 Solutions-IES 2/21/2006 37 <0.5 1.4 <0.5 57- <0.5 ``0 77 :310,=; 3.7 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 23 <5 <5 <5 41 ': <5 <5 310' <5 <5 <5 <5 35DW-2 G&M 4/3/1997 18 <1 <1 <1 7t,- : <1 <1 ` 33 : „ <1 <1 <1 <1 G&M 4/16/1997 19 <1 <1 <1 °' 7° . ' <1 <1 35.: - <1 <I <1 <1 G&M 4/16/1997* 19 <1 <1 <1 6 <1 <1 ..:-35 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 1.8 <0.5 3 <0.5 <0.5 21., ` <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 1.1 <0.5 <0.5 <0.5 2 <0.5 <0.5 ;-20..;° <0.5 <0.5 <0.5 <0.5 35DW-3 G&M 4/3/1997 1 <1 <1 <1 <1 <1 <1 "" 3. " <1 <1 <1 <1 G&M 4/16/1997 11 <1 <1 <1 3 <1 <1 ; `18 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-4 G&M 4/3/1997 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-6 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-7 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 1.2 <0.5 <0.5 10 <0.5 <0.5 <0.5 <0.5 Notes: All concentrations reported in pg/L (ppb). NC 2L Standards are the 15A NCAC 2L.0200 groundwater standards. Shaded concentrations exceed the NC 2L groundwater standards. NE denotes not established. * denotes duplicate sample. Page 2 of 2 TABLE 1 Summary of Groundwater Analytical Data for Target Compounds NCDOT Former Asphalt Laboratory Site #35 Rockwell, North Carolina NCDOT WBS #36413.1.49 Well ID Sampled by Sample Date 1,1,1- TCA 1,1,2- TCA 1,1- DCA 1,2- DCA 1,1- DCE Chloroethane PCE TCE cis-1,2- DCE trans-1,2 DCE Chloroform V1nyl Chloride NC 2L Standard 200 NE 70 0.38 7 2,800 0.7 2.8 70 100 70 0.015 DEEP MONITORING WELLS 35DW-1 G&M 12/13/1996 , 430 <100 <100 <100 180 <100 <100 ,;; 820 <100 <100 <100 <100 G&M 1/21/1997 .260_... <1 <1 1 150J <1 ;°1 0'_" <1 <1 <1 <1. G&M 1/21/1997* 370':,: <1 <1 1 ,.. 140 <1 1 •:''660 <1 <1 <1 <1 G&M 4/3/1997 430 <1 <1 2'160e, <1`:�`2 780 <1 <1 <1 <1 G&M 4/3/1997* 420'> <1 <1 -2 , .. 150 <1 1 '�750 > _< <1 <1 <1 <1 Solutions-IES 2/21/2006 37 <0.5 1.4 <0.5 57 ..n <0.5 0.77 " 310 3.7 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 23 <5 <5 <5 41, <5 <5 ':`310= <5 <5 <5 <5 35DW-2 G&M 4/3/1997 18 <1 <1 <I ,; 7 ;. <1 . <1 33`t <1 <1 <1 <1 G&M 4/16/1997 19 <1 <1 <1 7 .;s <1 <1 -35; ' <1 <1 <1 <1 G&M 4/16/1997* 19 <1 <1 <1 6 <1 <1 35,F <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 1.8 <0.5 3 <0.5 <0.5 21 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/8/2006 1.1 <0.5 <0.5 <0.5 2 <0.5 <0.5 ` 20 <0.5 <0.5 <0.5 <0.5 35DW-3 G&M 4/3/1997 1 <1 <1 <1 <1 <1 <1 3 <1 <1 <1 <1 G&M 4/16/1997 11 <1 <1 <1 3 <1 <1 18 `; <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-4 G&M 4/3/1997 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Solutions-IES 2/21/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 Solutions-IES 8/9/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-6 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 35DW-7 Solutions-IES 8/8/2006 <0.5 <0.5 <0.5 <0.5 1.2 <0.5 <0.5 : ` 10 .'„ <0.5 <0.5 <0.5 <0.5 Notes: All concentrations reported in µg/L (ppb). NC 2L Standards are the 15A NCAC 2L.0200 groundwater standards. Shaded concentrations exceed the NC 2L groundwater standards. NE denotes not established. * denotes duplicate sample. Page 2 of 2 TABLE 2 Summary of Groundwater Elevation Data NCDOT Former Asphalt Laboratory Site #35 Rockwell, North Carolina NCDOT WBS #36413.1.49 Monitoring Well Well Depth t (ft bgs) Screened Interval (feet) Top of Casing Elevation (feet) Measurement Date Depth to Water (ft BTOC)2 Groundwater Elevation (feet) SHALLOW MONITORING WELLS 35MW-1 20 10-20 743.7 11/22/1996 14.40 729.30 4/3/1997 13.92 729.78 5/2/1997 13.57 730.13 2/21/2006 15.76 727.94 8/8/2006 16.99 726.71 35MW-2 20 10-20 744.02 11/22/1996 10.50 733.52 4/3/1997 10.32 733.70 5/2/1997 8.90 735.12 2/21/2006 11.27 732.75 8/8/2006 12.99 731.03 35MW-3 20 10-20 744.21 11/22/1996 13.60 730.61 5/2/1997 12.69 731.52 2/21/2006 14.83 729.38 8/8/2006 16.17 728.04 35MW-4 20 10-20 742.87 11/22/1996 16.42 726.45 4/3/1997 15.23 727.64 5/2/1997 15.62 727.25 2/21/2006 17.87 725.00 8/8/2006 18.87 724.00 35MW-5 20 10-20 739.97 11/22/1996 13.10 726.87 5/2/1997 12.47 727.50 8/8/2006 15.85 724.12 35MW-6 20 10-20 738.25 4/3/1997 5.36 732.89 5/2/1997 5.03 733.22 2/21/2006 7.11 731.14 8/8/2006 8.63 729.62 35MW-7 30 20-30 745.15 8/8/2006 13.98 731.17 DEEP MONITORING WELLS 35DW-1 60 50-60 743.71 11/22/1996 14.87 728.84 1/21/1997 14.55 729.16 4/3/1997 14.27 729.44 5/2/1997 14.06 729.65 2/21/2006 16.40 727.31 8/8/2006 17.53 726.18 35DW-2 100 89-99 743.93 4/3/1997 13.48 730.45 4/16/1997 15.05 728.88 5/2/1997 14.86 729.07 2/21/2006 17.23 726.70 8/8/2006 18.15 725.78 35DW-3 60 50-60 737.01 4/3/1997 8.48 728.53 4/16/1997 8.52 728.49 5/2/1997 8.20 728.81 2/21/2006 10.50 726.51 8/8/2006 11.47 725.54 35DW-4 60 48.5-58.5 742.13 4/3/1997 14.62 727.51 5/2/1997 14.47 727.66 2/21/2006 16.61 725.52 8/8/2006 17.69 724.44 35DW-6 60 50-60 742.91 8/8/2006 16.28 726.63 35DW-7 150 130-150 743.33 8/8/2006 17.55 725.78 Notes: 1. ft bgs denotes feet below ground surface. 2. ft BTOC denotes feet below top of casing. TABLE 3 Well Construction Data NCDOT Former Asphalt Laboratory Site #35 Rockwell, North Carolina NCDOT WBS #36413.1.49 Monitoring Well Well Type Well Depth (ft bgs)1 Screened Interval (feet) Top of Casing Elevation (feet) SHALLOW WELLS 35MW-1 Monitoring 20 10-20 743.7 35MW-2 Monitoring 20 10-20 744.02 35MW-3 Monitoring 20 10-20 744.21 35MW-4 Monitoring 20 10-20 742.87 35MW-5 Monitoring 20 10-20 739.97 35MW-6 Monitoring 20 10-20 738.25 35MW-7 Monitoring 30 20-30 745.15 351W-1 Temporary Injection 20 20-30 NA 35IW-2 Temporary Injection 20 20-30 NA 35IW-3 Temporary Injection 20 20-30 NA DEEP WELLS 35DW-1 Monitoring 60 50-60 743.71 35DW-2 Monitoring 100 89-99 743.93 35DW-3 Monitoring 60 50-60 737.01 35DW-4 Monitoring 60 48.5-58.5 742.13 35DW-6 Monitoring 60 50-60 742.91 35DW-7 Monitoring 150 130-150 743.33 35IW-4 Temporary Injection 60 50-60 NA 35IW-5 Temporary Injection 60 50-60 NA 35IW-6 Temporary Injection 60 50-60 NA Notes: 1. ft bgs denotes feet below ground surface. 2. ft BTOC denotes feet below top of casing. 3. NA = not applicable. Page 1 of 1 FIGURES •. -N. ,;•0 •••, • I ) - • Jt.%,•- shw • tt P • • ... • a \ If • .1.4"•-• I 111. pl • • T, • 12/ I.! •V a R.. ).10 62,11 I 'w _ fa • ' • ( ah, 1 10 If 6 21:1!11 I - ••••,, •6'11.s tij .1 RY • •-• 1 : 10,000 SITE LOCATION MAP FORMER NCDOT ASPHALT LABORATORY SITE # 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA -.1•••ar :71 .1 a re • REFERENCE: USGS 7.5 MINUTE TOPOGRAPHIC MAP- ROCKWELL, NC, 1962, Photorevised 1987. (DRG digital map from N.C. Geological Survey, 1997) , Solutions -TES Industrial & Environmental Services 1101 Nowell Road, Raleigh, NC 27606 Phone (919) 873-1060, Fax (919) 873-1074 Created by: KBB Checked by: CZ File: Figure 1.mxd Software: ESRI ArcMap 9.1 Project: 7060.08A3.NCDO Date: JULY 2008 FIGURE 1 0 0 U Z m W Q CO 0 20 7 Z r U W 0 a 00 W W 0 U CO 0 ›- a. 0 A� iv/AC F 35MW-2 - .:,- x`, A-;_. l..� .'s ..'{oF 35MW-7 AST (TYPICAL) CONCRETE BERM 35MW-3 35DW-6 35DW-1 35MW-1 G1 l'! 35DW-2 35DW-7 35MW-6 t7 35DW-4 35DW-3 4- 35v1 W-5 G1 LEGEND 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL 0 50 100 SCALE IN FEET sijaSolutions -IES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA SITE LAYOUT FIGURE: 2 l 35MW-2 - 0 0 0 Z w Qm m 2p 7 c0 Z p 0 w 0 cc CC 2 w w o LL 0 } 0 0 w 0 U w U w z U w U cc a co p O co w 0 w J_ LL 35MW-3 35DW-6 35DW-2 35DW-7 35MW-6 35DW-4 35DW-3 4) 35MW-5 1 LEGEND 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL A A' CROSS SECTION TRACE 0 50 100 SCALE IN FEET 11 Solutions -IES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA CROSS SECTION TRACE FIGURE: 3 J Cross Section.dwg w LL ELEV (ft msl) 750- 740- 730- 720- 710- 700- 690- 680- 670- 660- 650- 640- 630 — 620 — 610 — 600 — 590 — 35PMV--2 <0.5 <0.5 A A;L rb CL <0 ML 35M W-7 <0.5 <0.5 SAPROLITE / WEATHERED BEDROCK CL 2, A r5 r5('D nD� 1800 240 j . 35DW-1 310 41 — ML 35DW-2 20 2 CL 35DW-7 10 1.2 A' CL 35MMNV-4 — <0.5 — <0.5 — GROUNDWATER ELEVATION AUGUST 2006 SAPROLITE ML WEATHERED BEDROCK 35DW-4 <0.5 <0.5 CL ML 35DW-4 <0.5 <0.5 LEGEND CLAY SILT SCREENED INTERVAL MONITORING WELL ID TCE CONCENTRATION 1,1-DCE CONCENTRATION ESTIMATED EXTENT OF TCE ABOVE 2L STANDARDS 60 HORIZONTAL SCALE 1"=60' 120 So1utions -TES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1. CROSS-SECTION BASED ON PREVIOUS WORK BY GERAGHTY & MILLER, INC. 2. WELL LOCATIONS ARE RELATIVE TO TRACE OF CROSS-SECTION FORMER NCDOT ASPHALT LABORATORY SITE #35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA GEOLOGIC CROSS SECTION A -A' FIGURE: 4 1 o W� 0 } m 0 0 W 0 U x 0 uJ 0 0 z o 0 W 0 0 a Cross Section.dwg ELEV B *;5 (ft msl) rS°� 740- 730— — 720- 710- 700- 690- 680- 35ATN-3 <0.5 <0.5 CL ML SAPROLITE WEATHERED BEDROCK 35DW-1 310 41 rgo rb CL GROUNDWATER ELEVAT AUGUST 2006 SAPROLITE WEATHERED BEDROCK 3510W-6 <0.5 <0.5 35DW-3 <0.5 <0.5 B' CL ML 35DW-4 <0.5 <0.5 LEGEND CLAY SILT SCREENED INTERVAL MONITORING WELL ID TCE CONCENTRATION 1,1-DCE CONCENTRATION ESTIMATED EXTENT OF TCE ABOVE 2L STANDARDS HORIZONTAL SCALE 1"=60' W J 0 to b J < II U W 7 Solutions -IFS Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1. CROSS-SECTION BASED ON PREVIOUS WORK BY GERAGHTY & MILLER, INC. 2. WELL LOCATIONS ARE RELATIVE TO TRACE OF CROSS-SECTION FORMER NCDOT ASPHALT LABORATORY SITE #35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA GEOLOGIC CROSS SECTION B-B' FIGURE: 5 0 0 Z W co 0. o z� Z W 0 a CO 0 0 CO W 0 a L cn J LL l S.NA vR1AC vE 35MW-7 AST (TYPICAL) CONCRETE BERM 35MW-3 611 35DW-6 35MW-1 35DW-1 l'l 35DW-2 35MW-6 r1 35DW-4 35DW-3 35MW-5 LEGEND 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL 1800 TCE CONCENTRATION (ug/L) 2.8 ESTIMATED EXTENT OF TCE ABOVE 2L STANDARD 0 50 100 SCALE IN FEET Solutions -IES Industrial & Environmental Sen-ices 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA TCE ISOCONCENTRATION MAP SHALLOW AQUIFER AUGUST 2006 FIGURE: 6 l t m 2 w ❑ r 0 ❑ >- m❑ ❑ W V W 2 O m 0 0 0 W w J LL 35MW-2 U A , 1OF 35MW-7 AST (TYPICAL) CONCRETE BERM 35DW-6 35MW-3 35MW-1 35DW-1 41 35DW-2 350W-7 35MW-6 35DW-4 35DW-3 4- 35MW-5 w LEGEND 35 MW-5 SHALLOW MONITORING WELL 35 DW-1 DEEP MONITORING WELL TCE CONCENTRATION (ug/L) 2.8 ESTIMATED EXTENT OF TCE ABOVE 2L STANDARD 0 50 100 SCALE IN FEET • 11 Solutions —TES • Industrial 4 Environmental Services NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA TCE ISOCONCENTRATION MAP DEEP AQUIFER AUGUST 2006 FIGURE: 7 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 J E- LL O } p 0 W 0 W U 35MW-3 728.04 op p 0 m W 1- 0 35MW-4 724.00 �j 35DW-3 35MW-6 29.62 350W-4 724.12 v 1-5 724.12 LEGEND 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL WATER TABLE ELEVATION 728 WATER TABLE CONTOUR IMPLIED DIRECTION OF GROUNDWATER FLOW 0 50 100 SCALE IN FEET FIGURE: 111 Solut• ions -TES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TFi • ia14i R73-1060 FAX.: (9191 873-1074 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA POTENTIOMETRIC SURFACE MAP SHALLOW AQUIFER AUGUST 2006 0 U mo 2D co Z cc W a. >- m0 0' W 0 W 0 0 CD 0 co W 0 a LL 4- 35MW-3 Solutions -IES Industrial & Environmental Services 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX.: (919) 873-1074 35DW-6 APPROXIMATE LOCATION OF FORMER ASPHALT LAB 35MW-1 NOTES: 1) BASEMAP REFERENCE, "SITE MAP, NC DEPARTMENT OF TRANSPORTATION, SITE NO. 35", GERAGHTY & MILLER ENVIRONMENTAL SERVICES, DATED 4/17/97. 35DW-2 r1 LEGEND PROPOSED DEEP INJECTION WELL PROPOSED SHALLOW INJECTION WELL 35MW-5 SHALLOW MONITORING WELL 35DW-4 DEEP MONITORING WELL 35MW-4 0 20 40 SCALE IN FEET 35DW-7 FORMER NCDOT ASPHALT TESTING LABORATORY SITE NO. 35 500 INDUSTRIAL DRIVE ROCKWELL, ROWAN COUNTY, NORTH CAROLINA PROPOSED INJECTION WELL LOCATIONS FIGURE: 9 1 0 0 0 Z W Q 0 CO p 2 o Z 0 w O 0 W m 2 o -3 w 0 U W 0 w w 0 z 0 w 0 0 0 w w m 2 co W w w 0 FIGURE 10.pdf HYDRANT EMULSION DILUTION BACKFLOW PREVENTER NOTE: FOR WATER CHASE LINE, INLINE DILUTER IS REMOVED & REPLACED WITH BLANK PIPE SECTION ® E► INUNE DILUTER DOSATRON® OR EQUIIVALENT A EOS® CONCENTRATE EMULSION INJECTION INJECTION LINE TEMPORARY INJECTION WELL ® ® TO ADDITIONAL ® 0 0 INJECTION WELLS ua ► ra ua BENTONITE SEAL WELL SCREEN m EOS®INJECTION SEQUENCE DEPENDS ON SITE CONDITIONS LEGEND PRESSURE GAGE FLOW METER VALVE - GATE VALVE - BALL QUICK -CONNECT UNION AIR RELEASE VALVE 0 —} 1So1utions -JES lnc�n tri.11& kn.ircinnlrntal 5rrvicrs 1101 NOWELL ROAD RALEIGH, NORTH CAROLINA 27607 TEL.: (919) 873-1060 FAX (919) 873-1074 FORMER NCDOT ASPHALT TESTING LABORATORY SITE #35 500 INDUSTRIAL DRIVE ROCKWELL. ROWAN COUNTY. NORTH CAROLINA INJECTION SCHEMATIC FIGURE: 10 7 APPENDIX A EOS®MSDS MATERIAL SAFETY DATA SHEET EMULSIFIED EDIBLE OIL SUBSTRATE D.O.T. HAZARD CLASSIFICATION: NONE MANUFACTURER'S NAME EOS Remediation, LLC 1101 Nowell Road Raleigh, NC 27607 www.EOSRemediation.com DATE OF PREPARATION 01-24-03, Rev. 04-19-05 HEALTH FLAMMABILITY REACTIVITY PERSONAL PROTECTION INFORMATION TELEPHONE NO. 919-873-2204 SECTION I - PRODUCT IDENTIFICATION PRODUCT NAME PRODUCT CLASS CAS NUMBER EOS®CONCENTRATE 598B42 VEGETABLE OIL BASED EMULSION MIXTURE SECTION II - HAZARDOUS INGREDIENTS COMPONENT(S) EXPOSURE LIMIT THIS PRODUCT IS A MIXTURE OF EDIBLE FOOD GRADE ADDITIVES AND CONTAINS NO HAZARDOUS INGREDIENTS. SECTION III - PHYSICAL DATA BOILING POINT: SPECIFIC GRAVITY: VAPOR PRESSURE: PERCENT VOLATILE BY VOLUME (%): VAPOR DENSITY: EVAPORATION RATE: SOLUBILITY IN WATER: APPEARANCE AND ODOR: 212°F 0.97; .92 (pure oil phase) NOT ESTABLISHED 24 (AS WATER) HEAVIER THAN AIR NOT ESTABLISHED SOLUBLE OFF WHITE LIQUID WITH VEGETABLE OIL ODOR EMULSIFIED EDIBLE OIL SUBSTRATE SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: FLAMMABLE LIMITS: EXTINGUISHING MEDIA: UNUSUAL FIRE AND EXPLOSION HAZARDS: SPECIAL FIRE FIGHTING PROCEDURES: >300°F NOT ESTABLISHED CO2, FOAM, DRY CHEMICAL NOTE: WATER, FOG, AND FOAM MAY CAUSE FROTHING AND SPATTERING. BURNING WILL CAUSE OXIDES OF CARBON. WEAR SELF CONTAINED BREATHING APPARATUS AND CHEMICAL RESISTANT CLOTHING. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. SECTION V - PHYSICAL HAZARDS STABILITY: CONDITIONS TO AVOID: STABLE NONE INCOMPATIBILITY: STRONG ACIDS AND OXIDIZERS. HAZARDOUS DECOMPOSITION THERMAL DECOMPOSITION MAY PRODUCE OXIDES PRODUCTS: OF CARBON. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR SECTION VI - HEALTH HAZARDS SIGNS AND SYMPTOMS OF EXPOSURE: 1. Acute Overexposure - NONE 2. Chronic Overexposure - NONE MEDICAL CONDITIONS GENERALLY NONE KNOWN AGGRAVATED BY EXPOSURE: CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN: N.T.P. - NO I.A.R.C. - NO OSHA- NO EMERGENCY AND 1.) Inhalation- 2.) Eyes- 3.) Skin- 4.) Ingestion - FIRST AID PROCEDURES: REMOVE TO FRESH AIR. FLUSH WITH WATER FOR 15 MINUTES, IF IRRITATION PERSISTS SEE PHYSICIAN. WASH WITH MILD SOAP AND WATER. PRODUCT IS NON -TOXIC. IF NAUSEA OCCURS, INDUCE VOMITING AND SEEK MEDICAL ATTENTION. 4 EMULSIFIED EDIBLE OIL SUBSTRATE SECTION VII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: VENTILATION: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE CLOTHING OR EQUIPMENT: NOT NORMALLY REQUIRED LOCAL EXHAUST NOT NORMALLY REQUIRED NOT NORMALLY REQUIRED NONE SECTION VIII - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: OTHER PRECAUTIONS: STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED: WASTE DISPOSAL METHODS: DO NOT STORE NEAR EXCESSIVE HEAT OR OXIDIZERS. NONE SOAK UP WITH DRY ABSORBENT AND FLUSH AREA WITH LARGE AMOUNTS OF WATER. DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS. SECTION IX - ADDITIONAL REGULATORY INFORMATION SARA TITLE III UNDER THE PROVISIONS OF TITLE 111, SECTION 311/312 OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATIONS ACT, THIS PRODUCT IS CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: NONE THIS PRODUCT DOES NOT CONTAIN SECTION 313 REPORTABLE INGREDIENTS. THE INFORMATION CONTAINED HEREIN IS BASED ON AVAILABLE DATA AND IS BELIEVED TO BE CORRECT. HOWEVER, EOS REMEDIATION, INC. MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED THEREOF. THIS INFORMATION AND PRODUCT ARE FURNISHED ON THE CONDITION THAT THE PERSON RECEIVING THEM SHALL MAKE HIS/HER OWN DETERMINATION AS TO THE SUITABILITY OF THE PRODUCT FOR HIS/HER PARTICULAR PURPOSE.