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HomeMy WebLinkAboutWI0300065_Regional Office Historical File Pre 2018• Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Coleen Sullins, Director Division of Water Quality January 11, 2008 Mr. Forrest Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 RE: Issuance of Injection Well Permit WI0300065 Dear Mr. Stevenson: TECEOWE uI JAN 3 0 2008 NC DENR MRO DWQ - Aquifer Protection In accordance with the application submitted on August 6, 2007, we are forwarding permit number WI0300065. This permit is for the injection of RegenOxTM and ORC AdvancedTM to remediate groundwater contaminated with petroleum hydrocarbons at the Virginia Avenue Auto and Wrecker at 201 W. Virginia Avenue, Bessemer City, Gaston County, North Carolina. This permit shall be effective from the date of issuance until January 31, 2010, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS. Please note that some of the monitoring requirements have changed from your application. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. If you have any questions regarding your permit please feel free to contact me at (919) 715-6935. Sincerely, Cg C-07 Qu Qi, P.G. Underground Injection Control Program Manager cc: Suzanne Bailey — Marshall Miller & Associates eoresvilllle °egional office CO-UIC files Enclosures NorthCarolina Naturally Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Phone (919) 733-3221 Customer Service Internet: http://h2o.enr.state.nc.us 2728 Capital Boulevard Raleigh, NC 27604 Fax (919) 715-0588 1-877-623-6748 Fax (919)715-6048 An Equal Opportunity/Affirmative Action Employer— 50% Recycled/10% Post Consumer Paper '...: 8cgg 0 i4AL NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION F L In accordance v ith tie provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other- apLaw plicable,s Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Norfolk Southern Railway Company FOR THE CONSTRUCTION AND OPERATION OF TYPE 51 INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject RegenOx and ORC Advanced, to remediate groundwater contaminated with petroleum hydrocarbons. These injection wells/points will be located at 201 W. Virginia Avenue, Bessemer City, Gaston County, North Carolina, and will be operated in accordance with the application submitted August 6, 2007, which is filed with the Department of Environment and Natural Resources and is considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until January 31, 2010, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. vikkr— Permit issued this the day of ,, r trA ,ok.c J. uSt21-S Coleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission. , 2008. Permit No. WI0300065 PAGE 1 ver.8/07 AP/UIC-6 e PART I - WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. This permit is valid only for construction of the number of injection wells described in the application and other supporting data. Construction of additional injection wells must be approved in advance by the Aquifer Protection Section. 4. Each injection well shall not hydraulically connect separate aquifers. 5. Each injection well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 6. Each injection well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes and the entrance to each well must be secured with a locking cap. 7. Each injection well shall be afforded reasonable protection against damage during construction and use. 8. Each injection well shall have permanently affixed an identification plate. 9. Within 30 days of completion of well construction, a completed Well Construction Record (Form GW-1) must be submitted for each injection well to: Aquifer Protection Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART II - WELL CONSTRUCTION SPECIAL CONDITIONS 1. At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office staff, telephone number (919) 715-6935 and the Mooresville Regional Office Aquifer Protection Section Staff, telephone number 704-663-1699. Permit No. WI0300065 PAGE 2 ver.8/07 AP/UIC-6 PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate of injection, and number of injection wells as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV - PERFORMANCE STANDARDS 1. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 2. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V - OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned physical alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central Office staff, telephone number (919) 715-6935. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. Permit No. WI0300065 PAGE 3 ver.8/07 AP/UIC-6 PART VI - INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect anyproperty, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS 1. The following monitoring plan shall be followed. A new down -gradient monitoring well should be installed twenty to thirty feet away from the proposed injection area; an one -inch geo-probe well is acceptable. New well and MW-1, MW-2, MW-3, and MW-4 will be sampled before injection and one (1) month after the third injection and three months after the fourth injection followed by semi-annual sampling until the monitoring data demonstrates that the chemical reaction is complete and geochemical conditions returned to the pre - injection state. The monitoring wells shall be sampled for the following parameters: a) Volatile and semi -volatile Organic Compounds (EPA Method 8260 and 8270); b) RCRA metal (will only be sampled for three times: pre -injection, one month after the third injection, and. final sampling event); c) Temperature; d) Dissolved oxygen; e) Oxidation-reduction potential; f) pH; g) Specific conductivity; h) Sulfate; i) Sodium, total and dissolved iron. 2. All sample results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office and the Raleigh Central Office. Any monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to insure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. 3. The Permittee shall submit an Injection Event Record within 30 days of completing each injection. 4. The Permittee shall produce a final project evaluation within 9 months after completing all Permit No. WI0300065 PAGE 4 ver.8/07 AP/UIC-6 injection -related activity associated with this permit or produce a project interim evaluation before submitting a renewal application for this permit. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plumemaps and potentiometric surface maps. 5. The monitoring results and the final project evaluation shall be submitted to: and to: Aquifer Protection Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 Aquifer Protection Section DENR-DWQ Mooresville Regional Office 610 East Center. Avenue Mooresville, NC 28115 6. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Mooresville Regional Office, telephone number 704-663-1699, any of the following: (A) Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 7. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 8. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. PART VIII - PERMIT RENEWAL In order to continue uninterrupted legal use of the injection facility for the stated purpose, the Permittee must submit an application to renew the permit 120 days prior to its expiration date. PART IX - CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned Permit No. WI0300065 PAGE 5 ver.8/07 AP/UIC-6 4 according to 15A NCAC 2C .0113, Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C..0113(b), including but not limited to the following: (A) All casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D) Drilled wells shall be completely filled with cement grout, or bentonite grout which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment. 3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Staff_ DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with the product proposed to be used are as follows: exposure can cause severe irritation and possibly burns to the skin, eyes, nose, throat, lungs, and gastrointestinal tract. 2. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. Permit No. WI0300065 PAGE 6 ver.8/07 AP/UIC-6 3..Persons working with these products should at least wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 4. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. 6. Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. 7. Efforts should be made to prevent contamination of existing or future wells and surface waters that may be located near the application area. Permit No. WI0300065 PAGE 7 ver.8/07 AP/UIC-6 nilvarrivM bJo AI!!enbJagennou•nwm :;auJe4u! 94 L8Z ON 'a!!!nsaJooW L08 ages 'enueny Jagua3 gse3 069 euiiozepu o'N O1709-£99 (170L) :xe3 6691-£99 (170L) :auoyd ao!JO leu0!69b a!!!Aseloo!N / uogoas uo!4oa}ad Je4!nby / Amen° Ja),eM;o uo!s!n!Q ouo AQUIFER PROTECTION ' : L STAFF REPORT 011E Date: August 31, 2007 To: Aquifer Protection Central Office Central Office Reviewer: Peter Pozzo Regional Login No: L GENERAL INFORMATION 1. This application is (check all that apply): ❑ New ® Renewal ❑ Minor Modification ® Major Modification County: Mecklenburg Permittee: Norfolk Southern Jed Name: Virginia Ave Auto Wrecker Application No.: WI0300065 ❑ Surface Irrigation n Reuse n Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment B included ❑ 503 regulated ❑ 503 exempt n Distribution of Residuals n Surface Disposal n Closed -loop Groundwater Remediation ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? ❑ Yes or ® No. a. Date of site visit: b. Person contacted and contact information: c. Site visit conducted by: d. Inspection Report Attached: ❑ Yes or /1 No. 2. Is the following information entered into the BIMS record for this application correct? n Yes or ® No. If no, please complete the following or indicate that it is correct on the current application. For Treatment Facilities: a. b. c. d. Location: Driving Directions: USGS Quadrangle Map name and number: Latitude: Longitude: e. Regulated Activities / Type of Wastes (e.g., subdivision, food processing, municipal wastewater): For Disposal and Injection Sites: (If multiple sites either indicate which sites the information applies to, copy and paste a new section into the document for each site, or attach additional pages for each site) a. Location(s): ok b. Driving Directions: From Mooresville, I77 south to 185 south to exit #13 for Bessemer City, go north on Edgewood, continue onto Athenia Pl, then left (west) onto Alabama Ave. Go right (north) onto 13th and the site is just through the tunnel under the railroad and on the left. c. USGS Quadrangle Map name and number: Bessemer City d. Latitude: ok Longitude: ok (men° JateM;o uo!s!n!Q JotoanQ 'su!!InS 'H ua9103 seanosej lejngeN pue guewua!nu3;o guewpedea eu!!oJe3 g1JON kimonos -Jr sso d .9 we!!!!M Jowano I eLLse3 laeyo!Vt FOW10300106 staff report Norfolk Southern Virginia Ave renewal 8-07 AQUIFER PROTECTION REGIONAL STAFF REPORT II. & III. - deleted IV. INJECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description Of Well(S) And Facilities — New, Renewal, And Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QM/5QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (5L/"Non-Discharge") ❑ Other (Specify: 2. Does system use same well for water source and injection? n Yes ® No 3. Are there any potential pollution sources that may affect injection? a Yes ❑ No What is/are the pollution source(s)? This injection is for remediation at a UST site into the plume. What is the distance of the injection well(s) from the pollution source(s)? 0 ft. 4. What is the minimum distance of proposed injection wells from the property boundary? —25 ft. 5. Quality of drainage at site: ® Good ❑ Adequate ❑ Poor 6. Flooding potential of site: ® Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ® Yes ❑ No. Attach map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater monitoring program: 8. Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow. Injection Well Permit Renewal And Modification Only: 1. For heat pump systems, are there any abnormalities in heat pump or injection well operation (e.g. turbid water, failure to assimilate injected fluid, poor heating/cooling)? ❑ Yes ❑ No. If yes, explain: 2. For closed -loop heat pump systems, has system lost pressure or required make-up fluid since permit issuance or last inspection? n Yes n No. If yes, explain: 3. For renewal or modification of groundwater remediation permits (of any type), will continued/additional/modified injections have an adverse impact on migration of the plume or management of the contamination incident? n Yes ® No. If yes, explain: FORM: WI0300106 staff report Norfolk Southern Virginia Ave renewal 8-07 2 AQUIFER PROTECTION REGIONAL STAFF REPORT 4. Drilling contractor: Name: Address: Certification number: 5. Complete and attach Well Construction Data Sheet. V. EVAL UATIONAND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the application.: Regional evaluation was conducted in the office and consisted of review of the pollution incident file for this site, the UIC file, and discussion with the current project manager with DWM-UST. Based on information reviewed, the proposed renewal represents a major modification to the injection strategy, as the old method was simply use of ORC socks. This application proposes numerous ORC injection points in an effort to reduce benzene to levels below the GCLs in order to get risk -based site closure from DWM. There are no water supply wells or sensitive receptors in the vicinity. Based on the maps in the application that depict shallow flow, there are no monitoring wells downgradient of the area of MW2, which is the single well that has contamination over the GCLs and is the area for the injection. However, given the localized area of concern, the limited area for the injection, and the clay -rich materials, this is not anticipated to be a significant problem as transport will be limited. The DWM case manager supports the injection effort. 2. Attach Well Construction Data Sheet - if needed information is available 3. Do you foresee any problems with issuance/renewal of this permit? ❑ Yes ® No. If yes, please explain briefly. 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason Hydraulic capacity information (L.5., page 8 of their application report) The application simply refers to assumed values. There should be slug test data available in the CSA or such tests are easily conducted to better approximate needs for the injection. FORM: WI0300106 staff report Norfolk Southern Virginia Ave renewal 8-07 3 AQUIFER PROTECTION REGIONAL STAFF REPORT 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: Condition Reason 6. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; ® Issue upon receipt of needed additional information; ❑ Issue; n Deny. If deny, please state reasons: 8. Signature of report preparer(s): Andrew Pitner Signature of APS regional supervisor: Andrew Pitner Date: August 31, 2007 ADDITIONAL REGIONAL STAFF REVIEW ITEMS FORM: WI03 00106 staff report Norfolk Southern Virginia Ave renewal 8-07 4 AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: August 10, 2007 To: ❑ Landon Davidson, ARO-APS ❑ Art Barnhardt, FRO-APS ® Andrew Pitner, MRO-APS ❑ Jay Zimmerman, RRO-APS From: Peter Pozzo , Groundwater Protection Unit Telephone: (919) 715-6164 E-Mail: peter.pozzo@ncmail.net ❑ David May, WaRO-APS ❑ Charlie Stehman, WiRO-APS ❑ Sherri Knight, WSRO-APS Fax: (919) 715-05 ECEOWE AUG 1 3 2007 A. Permit Number: WI0300065 B. Owner: Norfolk Southern Railway Company C. Facility/Operation: Virgina Avenue Auto & Wrecker ❑ Proposed ® Existing NC DENR MRO DWQ -Aquifer Protection ❑ Facility ❑ Operation D. Application: 1. Permit Type: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle ❑ I/E Lagoon ❑ GW Remediation (ND) (5I) in -situ groundwater remediation REGENOX, ORC For Residuals: ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: ❑ New ❑ Major Mod. ❑ .Minor Mod. ❑ Renewal ® Renewal w/ Mod. E. Comments/Other Information: n I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: ® Return a Completed Form APSSRR. ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO*. * Remember that you will be responsible for coordinating site visits, reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 02/06 Page 1 of 1 Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources August 9, 2007 FORREST STEVENSON NORFOLK SOUTHERN RAILWAY COMPANY 110 FRANKLIN ROAD, SE BOX 13 ROANOKE VA 24042-0013 Dear Mr. Stevenson: C j� LC, �CD, sinp AUG 1 3 2007 NC DENR MRO DWQ - A uifer Protection Subject: Acknowledgement of Application No. WI0300065 Virginia Avenue Auto & Wrecker Injection In situ Groundwater Remediation Well (5I) Gaston County The Aquifer Protection Section of the Division of Water Quality (the Division) acknowledges receipt of your permit application and supporting materials on August 6, 2007. This application package has been assigned the number listed above and will be reviewed by Peter Pozzo. The reviewer will perform a detailed review and contact you with a'request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Peter Pozzo by phone at (919) 715-6164 or by email at Pete.Pozzo@ncmail.net. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart, go to http://h2o.enr.state.nc.us/documents/dwq orgchart.pdf. PLEASE REFER TO '1HE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. For Debra J. Watts Supervisor cc: oresville Regional C?fI"ice, lurfel� I'rrct�ction Section • pplication Ile WI0300065 Suzanne Bailey, Marshall Miller & Associates, 8371 Melrose Drive, Lenexa, KS 66214 ermit Aquifer Protection Section 1636 Mail Service Center Internet: www.ncwaterqualitv.org Location: 2728 Capital Boulevard An Equal Opportunity/Affirmative Action Employer— 50% Recycled/10% Post Consumer Paper 'rector uality North Carolina Naturally Raleigh, NC 27699-1636 Telephone: (919) 733-3221 Raleigh, NC 27604 Fax 1: (919) 715-0588 Fax 2: (919) 715-6048 Customer Service: (877) 623-6748 State of North Carolina Department of Environment and Natural Resoui Division of Water Quality APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A ECIodED AUG 1 3 2007 NC DENR MRO if Type 51 Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated groundwater. • Submit TWO copies of the completed application and all attachments to the address on the last page of this form. • Any changes made to this form will result in the application package being returned. Application Number (to be completed by DWQ): I. GENERAL INFORMATION: RECEIVED / DENR / DWQ AQUIFFR'PRnTF(:TInN SECTION AUG 0 6 2007 1. Applicant's Name (generally the responsible party): NORFOLK SOUTHERN RAILWAY COMPANY 2. Signing Official's Name: FORREST W. STEVENSON Title: ENGINEER 3. Mailing address of applicant: 110 FRANKLIN ROAD, SE, BOX 13 City: ROANOKE State: VA Zip: 24042-0013 Telephone number: 540 981-4236 Fax number: 540 981-5069 4. Property Owner's Name (if different from Applicant): 5. Property Owner's mailing address: City: State: Zip: 6. Name and address of contact person who can answer questions about the proposed injection project: Name: SUZANNE BAILEY Title: BRANCH MANAGER Company: MARSHALL MILLER & ASSOCIATES Address: 8371 MELROSE DRIVE City: LENEXA State: KS Zip: 66214 Telephone number: 913 648-4424 Email Address: SUZANNE_BAILEY@MMAI.COM H. PERMIT INFORMATION: Fax number: 913 648-4763 1. Project is: L1 New VI Modification of existing permit ❑ Renewal of existing permit without modification 2. If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number WI0300065 and the issuance date 12/6/04 For renewalwithout modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). UIC-5I/5T ver. 12-05 Page 1 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type ST Wells — Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION I . Facility name: VIRGINIA AVENUE AUTO & WRECKER 2. Complete physical address of the facility: 201 W. VIRGINIA AVENUE City: BESSEMER CITY County: GASTON State: NC Zip:28016 B. INCIDENT DESCRIPTION 1. Describe the source of the contamination: Five gasoline underground storage tanks (USTs) and one kerosene UST were located at the Site, but were removed in September 1998 and January 1999. Approximately 277 tons of petroleum hydrocarbon impacted soil associated with the USTs was removed and the excavation pits were backfilled with clean material. Impacted' soils remain at the site and may act as a source of petroleum contaminants during high groundwater levels. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): GASOLINE (BTEX) 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ❑ Yes If yes, list maximum measured separate phase thickness: feet No If no, list maximum concentration of total VOCs observed at site: 91210 ppb 4. Agency managing the contamination incident: UST Section ❑ Superfimd Section (including REC Program and DSCA sites) L7 DWQ Aquifer Protection Section ❑ Solid Waste Section ❑Hazardous Waste Section El Other: 5. Incident number or other site number assigned by the agency managing the contamination incident: Pollution Incident No. 19216 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: NONE 2. DWQ Non -Discharge or NPDES permits: NONE 3. County or DEH subsurface wastewater disposal permits: NONE 4. Other environmental permits required by state or federal law: NONE UIC-5I/5T ver. 12-05 Page 2 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — In. Situ Groundwater Remediation / Type 5T Wells — 'Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA 1. List all proposed injectants. NOTE: Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the Occupational and Environmental Epidemiology Section (OEES) of the Division of Public Health, Department of Health and Human Services. Review the list of apvroved injectants or contact the UIC Program to determine if the injectants you are proposing have been reviewed by OEES. Injectant: REGEN OX (by Regenesis Co.) Concentration at point of injection: 5.1% (1620 Ibs RegenOx in 1725 gal of water) Injectant: ORC ADVANCED (by Regenesis Co.) Concentration at point of injection: 30% solids (575 Ibs ORC Adv. in 161 gal water) Inj ectant: Concentration at point of injection- Injectant: Concentration at point of injection: Inj ectant: Concentration at point of injection: 2. Source of fluids used to dilute or chase the injectants listed above: ❑None VI Municipal water supply ❑ Groundwater from private well or any well within'/4 mile of injection site ❑ Air ❑ Other: 3. If groundwater from a private well or any well within'/4 mile of injection site is to be used as the fluid source, supply the following information: a. Location/ID number of source well: N/A b. Depth of source: N/A c. Formation: N/A d. Rock/Sediment type: N/A e. In Attachment B, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE: If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit application form. You must apply for a closed -loop groundwater remediation permit using application form GWRS. UIC-5I/5T ver. 12-05 Page 3 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJE CTION Type 5I Wells In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Maximum number of separate injection events: 4 Expected duration of each injection event: 1 DAY Expected duration between events (if more than one event): 2-4 WEEKS 2. Injection rate per well: UP TO 5 gallons per minute (gpm) 3. Total Injection volume: 1725 gallons per day (gpd); 1725 gallons per event (if separate events) 4. Injection pressure: < 1500 pounds/square inch (psi) 5. Temperature at point of injection: 70 (ambient) °F 6. Briefly describe how the above parameters will be measured and controlled: Injection rates and pressures will be metered and/or pumping pressure and liquid volume measurements will be continuously measured to calculate the injection rates. 7. Estimated hydraulic capacity of the well: 5 gpm C. INJECTION WFI,I, CONSTRITCTTON DATA 1. Injection will be via: ❑ Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. O Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: VIRONEX NC Well Contractor Certification number: 3027 3. Date to be constructed: OCT- 01 W-tom ' 0•7 Number of borings: 9 Approximate depth of each boring (feet): 21 4. Screened interval/Injection interval of injection wells: Depth: 9 to 21 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: ❑ PVC ❑ Stainless steel VA Other: N/A (INJECTION THROUGH DPT RODS) Casing depth: to ft. 6. Grout (N/A if injection is through direct push rods): Type: ❑ Cement ❑ Bentonite Grout depth: to ft. ❑ Other: NIA (INJECTION THROUGH DPT RODS' UIC-5I/5T ver. 12-05 Page 4 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJE CTION Type St Wells -- In Situ Groundwater Remediation / Type ST Wells — Tracer Injection V. ATTACHMENTS Provide the following items as attachments with the given headings: A. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) the regional geologic setting; (2) significant changes in Ethology; (3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and (4) the depth to the mean seasonal high water table. NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the penforrnance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or her. B. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within '/a mile of the injection site is used as the source well, include chemical analysis of source fluid here. C. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) goals of the injection project; (2) a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. D. INJECTION PROCFDTJRF, AND F.QIJIPMF.NT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: (1) construction plans and materials; (2) operation procedures; (3) a detailed diagram of the surface and subsurface portions of the system; and (4) a planned injection schedule. E. MONITORING PLAN Provide a plan for monitoring the results of the injection, including: (1) a list of existing and proposed monitoring wells to be used; (2) a list of monitoring parameters and analytical methods to be used; and (3) a schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by- products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target contaminants as well as secondary or intermediate contaminants which may result from the injection and other parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated reactions and rate of transport of the injectants and contaminants. UIC-5I/5T ver. 12-05 Page 5 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJE CTION Type SI Wells — In Situ Groundwater Remediation / Type ST Wells .. Tracer Injection F. WELL DATA Provide a tabulation of data on all existing or abandoned wells within 'A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open borehole depth interval, and well construction or abandonment record, if available. G. MAPS Attach the follotiving scaled, site -specific maps: (1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site. (2) Site map including: a. all property boundaries; b. all buildings within the property boundary; c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within'/4 mile of the injection well or well system; e. all surface water bodies within '/ mile of the injection well or well system; and f. all existing or abandoned wells within 'A mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells_ (3) Potentiometric surface map(s) including: a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant plume, including isoconcentration lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross-section(s) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology UIC-5I/5T ver. 12-05 Page 6 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — Di Situ Groundwater Remediation / Type 5T Wells — Tracer Injection VI. CERTIFICATION I, FORREST W. STEVEN.SON,in .:; a.ai , hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. 1 am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature• �' _. Date:4440Sr `Lt Z . Title: ENGINEER If authorized agent is acting on behalf of the applicant, supply a letter signed by the applicant authorizing the above agent. VII. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrail agreement in writing.) I, i ,c:a na=sic Cif nron�I•,., as owner of the property on which the injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title I5A NCAC 2C .0200) Signature: Title: Date - Submit TWO copies of the completed application package, including all attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 715-6935 UIC-5I/5T ver.09-06 Page 7 of 7 UIC PERMIT NO. WI0300065 INJECTION PERMIT MODIFICATION APPLICATION CLASS 5I WELL Norfolk Southern Railway Company Virginia Avenue Auto & Wrecker 201 W. Virginia Avenue Bessemer City, Gaston County, North Carolina Latitude: 35° 17' 5" North Longitude: 81° 17' 2" West August 2007 Prepared For: RECEIVED / DENR / DWQ AQUIFFR'PRnTFr..TInN SECTION AUG 0 6 2007 NORFOLK SOUTHERN RAILWAY COMPANY Mr. Forrest W. Stevenson 110 Franklin Road, SE, Box 13 Roanoke, Virginia 24042-0013 Norfolk Southern File No. 1-9-NC-BSMR-UT98.133-002 Prepared By: MARSHALL MILLER & ASSOCIATES, INC. 8371 Melrose Drive Lenexa, Kansas 66214 (913) 648-4424 MM&A Project No. NS1411 Norfolk Southern File No. 1--9-NC-BS 4R-UTQ . 13 -002 CERTIFICATION " I hereby certify, under penalty of law, that I have personally examined and am familiar with the information. submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the infoiuuation is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting, false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit' Forrest W. Stevensor. Engineer Environmental Remediation \torfolk Southern Railway Com.nia.nv Signature of Well Owner or Authorized Agent) TABLE OF CONTENTS PAGE A. PERMIT APPLICANT 1 B. PROPERTY OWNER 1 C. STATUS OF APPLICANT 1 D. FACILITY (SITE) DATA 1 E. DECRIPTION OF INJECTION ACTIVITIES 1 F. DESCRIPTION OF SITE 2 G. HYDROGEOLOGIC DESCRIPTION 4 1. REGIONAL GEOLOGIC SETTING 5 2. SIGNIFICANT CHANGES IN LITHOLOGY 5 3. HYDRAULIC CONDUCTIVITY 5 4. DEPTH TO MEAN SEASONAL HIGH WATER TABLE 5 5. TRANSMISSIVITY / SPECIFIC YIELD 5 H. MONITORING PROCEDURE 6 I. WELL USE 7 J. CONSTRUCTION DATA 7 K. OTHER WELL DATA 7 L. PROPOSED OPERATING DATA 7 1. INJECTION RATE: 7 2. INJECTION VOLUME: 7 3. INJECTION PRESSURE: 8 4. INJECTION TEMPERATURE: 8 5. HYDRAULIC CAPACITY OF THE WELL 8 6. EXPECTED LIFETIME OF THE INJECTION FACILITY 9 7. DESCRIPTION OF MEASUREMENTS/CONTROLS 9 M. INJECTION RELATED EQUIPMENT 9 N. LOCATION OF WELL(S) 9 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 TABLE OF CONTENTS (Continued) PAGE O. INJECTION FLUID DATA 9 1. FLUID SOURCE 10 2. CHEMICAL, PHYSICAL, BIOLOGICAL, AND RADIOLOGICAL CHARACTERISTICS OF INJECTION FLUID. 10 P. PERMIT LIST 10 Q. REFERENCES 10 FIGURES AND TABLES APPENDICES APPLICATION FOR MODIFICATION TO UIC PERMIT NO. WI0300065 TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Class 5I Wells This permit modification application was prepared in accordance with the provisions of NCAC Title 15A: 02C.0200. The following sections provide a detailed description of all planned activities relating to the proposed four injections of oxygen release compounds (ORC) which constitute a change and/or present additional information not included in the UIC Permit No. WI0300065. MM&A proposes three injections of Regenesis brand RegenOx® in -situ oxidant and one injection of Advanced Formula Oxygen Release Compound® (ORC Advanced') into the subsurface surrounding monitoring well MW-2 to reduce the hydrocarbon levels in soils and ground water at the former UST Site. A. PERMIT APPLICANT No Change. B. PROPERTY OWNER No change. C. STATUS OF APPLICANT No change. D. FACILITY (SITE) DATA No change. E. DECRIPTION OF INJECTION ACTIVITIES The proposed work consists of four injection events: three injections of Regenesis brand RegenOx® in -situ oxidant into the subsurface surrounding monitoring well MW-2 and then 1 INNEJ la? Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC° Remediation Bessemer City, NC August 2007 one final injection of ORC Advanced® into the same vicinity. The injection area includes approximately 400 square feet with a vertical thickness of 12 feet (9 to 21 feet below ground surface (bgs) (Figure 2). A total of nine injection points spaced on approximate 8 foot centers will be used for the injection events (Figure 3). The oxidant material will be injected through direct push borings on one -foot intervals from the bottom up starting at 21 feet below grade and terminating at nine feet bgs. A copy of manufacturer's Regenox® and ORC Advanced® information, MSDS, and installation procedures is provided as Appendix A of this permit modification application. The Regenox® injection events will be conducted at least two to three weeks apart. To effectively distribute the material within the subsurface, the injection point locations will be offset a few feet horizontally between injection events. In addition to baseline sampling to be conducted in August 2007, confirmation sampling of ground water in monitoring wells will be completed after the second injection event to determine the RegenOx® effectiveness and whether a third injection of this material is required to achieve remedial goals. A final injection event of ORC Advanced® will take place six weeks after the completion of the last RegenOx® injection event. In order to assess the effectiveness of RegenOx® and ORC Advanced®, two ground water monitoring events will be conducted following the last injection event. It is anticipated that the two final ground water monitoring events will be conducted in June and December 2008. Pending this permit modification approval, the initial injection event is planned for the Fall of 2007. Four semi-annual ground water monitoring events (August 2007, December 2007, June 2008, and December 2008) will provide before and after results of the injections. F. DESCRIPTION OF SITE This section provides updated information of the Site. The Site has been assigned Pollution Incident No. 19216 by NCDENR. According to Mr. Brad Newton of the North Carolina Department of Environment and Natural Resource (NCDENR), if benzene levels can be 2 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 brought below the NCAC 15A 2L GCL standards (5000 µg/L) in ground water, the Site may be considered for closure. Five gasoline underground storage tanks (USTs) and one kerosene UST were located at the Site, but were removed in September 1998 and January 1999 by Earth Tech, Inc. (Earth Tech). Earth Tech removed approximately 277 tons of petroleum hydrocarbon impacted soil associated with the USTs. The excavation pits were backfilled with clean material. Between 1999 and 2001, seven monitoring wells were installed to evaluate ground water impacts. Data from the last four gauging events indicate the ground water typically flows to the southwest (Figures 4-7). Volatile organic compounds (VOCs) present in the ground water include benzene, toluene, ethylbenzene, total xylenes (BTEX), and naphthalene. Currently, benzene is the most prevalent. Figure 8 shows the most current benzene isoconcentration contours at the Site. Figures 9-12 show the most current isoconcentration contours at the Site for toluene, ethylbenzene, total xylenes, and naphthalene, respectively. A Comprehensive Site Assessment (CSA) was completed by Burns & McDonnell Consultants, Inc. (Burns & McDonnell) and submitted in May 2000. A Corrective Action Plan (CAP), completed by Burns & McDonnell, was submitted in October 2000, which recommended monitored natural attenuation as the most cost effective treatment option. Prior to approving the CAP, NCDENR requested the installation of two monitoring wells (MW-6 and MW-7) south of the railroad trestle down gradient from the Site, to further evaluate the extent of impacted ground water. Burns & McDonnell installed two monitoring wells (MW-6 and MW-7) in January 2001, and submitted a summary report to NCDENR in June 2001. Based on the results from the newly installed monitoring wells, NCDENR approved the CAP in a letter dated July 17, 2001. In November 2002, NSRC contracted MM&A to continue semi-annual ground water monitoring at the Site, in accordance with the approved CAP. In the November 2003 monitoring report, MM&A recommended enhancing the natural biodegradation process by 3 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 installing Regenesis brand Oxygen Release Compound (ORC®) socks in MW-2 and MW-4 and extending the semi-annual monitoring program for additional two years. MM&A submitted an injection permit to the NCDENR Division of Water Quality (DWQ) on November 1, 2004. NCDENR DWQ approved the permit on December 7, 2004 (permit no. WI0300065). This permit expires on December 1, 2007. The first set of ORC® socks were installed in January 2005; the second in June 2005; and the third set in December 2005. MM&A conducted semi-annual ground water monitoring in June and December of 2005. The ORC® socks were removed in June 2006 following the sampling event. The January 2007 sampling event established ground water quality post treatment of ORC® socks. Results indicated that the ORC® was effective in lowering the benzene levels (range of results over treatment period, 6400 — 11000 µg/L); however, ORC® treatment in the wells alone was insufficient to overcome the influence of remaining impacted soils. The objective of the remediation at this Site using RegenOx® and ORC Advanced® injections is to effectively and permanently lower benzene levels in the ground water below the GCL (5000 µg/L) so that NCDENR will reclassify the Site as low risk and grant closure. G. HYDROGEOLOGIC DESCRIPTION The following section includes updated information and revisions to support permit modification application and was prepared in accordance with G.S. 89E-13 and has been approved by a licensed geologist. 4 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 1. REGIONAL GEOLOGIC SETTING No change. 2. SIGNIFICANT CHANGES IN LITHOL O GY This section includes revised cross -sections of the Site. Subsurface materials encountered in soil borings and excavations at the Site consist of fill, clay, and clayey sand. Fill material (subgrade composed of clay, sand, and gravel) is prevalent across the Site to a depth of approximately two feet beneath the asphalt pavement. This fill is underlain by approximately 10 feet of native soil composed of low plasticity clay with some sand. Additional fill material comprised primarily of clay with some sand is also present within the former UST excavation to an average depth of 10 feet bgs. Based on the well MW-2 boring log, native soil consisting of low plasticity clay is present beneath the UST excavation to a depth of approximately 25 feet. Based on boring logs for MW-4 and MW-5, clayey sand was observed between approximately 10 and 20 feet bgs. This is the principal water bearing unit at the Site and is underlain by at least five feet of clay. Figure 13 shows the location of cross sections A -A' (Figure 14) and B-B' (Figure 15) which illustrate the relationship of subsurface units and approximate extent of petroleum impacted ground water at the Site. 3. HYDRAULIC CONDUCTIVITY No change. 4. DEPTH TO MEAN SEASONAL HIGH WATER TABLE This section includes updated Table 1. Based on historical data, the mean seasonal high water table is typically 10 feet bgs. Historic ground water elevations and field measurement data can be found in Table 1. 5. TRANSMISSIVITY/SPECIFIC YIELD No change. 5 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 H. MONITORING PROCEDURE This section has been revised to reflect additional monitoring requirements for the permit modification. A monitoring well network consisting of seven wells already exists at the Site and is shown on Figure 2. Historical ground water monitoring has included quarterly and semi-annual sampling from seven shallow monitoring wells (MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, and MW-7) for VOCs (USEPA Method 8260) and polynuclear aromatic hydrocarbons (PAHs, USEPA Method 8270). Four semi-annual ground water monitoring events are proposed to monitor effectiveness of RegenOx® and ORC Advanced® injections. The first of four semi-annual ground water monitoring events will be performed in July/August 2007 before the first injection event. The semi-annual sampling event for December 2007 will be completed between the second and third injection event, and two additional, post -injection semi-annual ground water monitoring events will be performed in June 2008 and December 2008. Ground water samples will be collected and sent to an off -site laboratory to be analyzed for: • VOCs including isopropyl ether (IPE), methyl tertiary butyl ether (MTBE), and ethylene dibromide (EDB) following USEPA Method 8260, • PAHs following USEPA Method 8270, • Biological oxygen demand, and • Chemical oxygen demand. Field parameters to be measured during sampling will include: • pH, • Water temperature, • Specific conductivity, • Dissolved oxygen, • Oxidation reduction potential, and • Ferrous Iron (Hach test method using field kit). 6 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 Well construction diagrams are included with the respective boring logs for the Site and have been provided in UIC Permit No. WI0300065. I. WELL USE This section has been revised to reflect additional monitoring requirements for the permit modification. All Site wells are monitoring wells designed for ground water sampling to monitor the natural attenuation of dissolved gasoline constituents in ground water. None of these wells will be used for injection purposes and none of the Site monitoring wells is used for potable water. Ground water samples will be collected from all Site monitoring wells on a semi-annual schedule for two years as described in Section H of this permit application. J. CONSTRUCTION DATA No change. K. OTHER WELL DATA No change. L. PROPOSED OPERATING DATA This section has been revised to reflect requirements for the permit modification. 1. INJECTION RATE The injection rate for RegenOx and ORC Advanced® will not exceed five gallons per minute (gpm) using bottom -up direct push placement in one -foot treatment intervals. 2. INJECTION VOLUME During each event, injection will be conducted at nine locations (borings). In each boring, injecting will start at approximately 21 feet below grade and will proceed upward on one -foot intervals until the depth of nine feet is reached. This means that there will be 12 injection points for each boring (108 for the entire Site per event). 7 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 For each RegenOx® application, approximately 1620 lbs of RegenOx® and 1,725 gallons of water will be mixed at the Site. The injection of this mixture will consist of approximately 17.5 gallons per foot at depth intervals described above. This equates to a total of approximately 191.6 gallons per location (boring). Approximately 575 lbs of ORC Advanced® will be mixed at the Site with approximately 161 gallons of water. The injection of this mixture will be 1.5 gallons per foot at depth intervals described above. This equates to approximately 17.9 gallons per location (boring). 3. INJECTION PRESSURE The RegenOx® and ORC Advanced® will be injected under pressure of less than 1500 PSI. It is anticipated; however, that actual pressures will be much lower to avoid soil fracturing. 4. INJECTION TEMPERATURE The RegenOx® and ORC Advanced® will be injected at ambient air temperature. S. HYDRAULIC CAPACITY OF THE WELL Relatively low yielding materials underlie the Site. Although pumping tests have not been conducted to determine the hydraulic capacities of the Site wells, based on typical hydraulic capacities of low yield materials (clays, silty clays) the well capacity is estimated to be less than five gpm. Because RegenOx® and ORC Advanced® will be injected using temporary boreholes, the hydraulic capacity of the borings is assumed to be similar to that of on -site monitoring wells. The in -situ remedial compounds will be injected at rates which will not fracture or damage the subsurface materials. Injection rates will be determined in the field and it is anticipated that the rates will not exceed five gpm. 8 \\' ' \\ '� Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 6. EXPECTED LIFETIME OF THE INJECTION FACILITY Existing monitoring wells are expected to be viable for an estimated 10 years or more. 7. DESCRIPTION OF MEASUREMENTS/CONTROLS The rate of oxygen released to the aquifer is an estimate. Actual rates of the oxygen release will vary depending on the geochemical and biological conditions of the aquifer. Based on manufacturer's (Regenesis) claims, RegenOx® and ORC Advanced® are typically depleted within six months after injection into the subsurface. M. INJECTION RELATED EQUIPMENT This section has been revised to reflect requirements for the permit modification. A Geoprobe® 6600 or similar equipment will be used for the direct push injection events. An associated Mobile Injection System (MIS) comprised of an integrated mixing and pumping (diaphragm, piston and progressive cavity) that can achieve injection rates up to 100 gpm and pressures up to 1500 psi will be used for injections. The injection tooling will consist of a top -down and bottom -up injection tooling which allows for the injection of remedial compounds at specific target depths (each foot from the depths of 9 to 21 feet below grade). N. LOCATION OF WELL(S) This section has been revised to reflect requirements for the permit modification. A Site vicinity map is shown in Figure 1 and includes topographic contours. The proposed injection area points and monitoring wells are shown on Figure 2 along with the required elements described in Section N of the permit. All monitoring wells are located on Norfolk Southern Railway Company property. A topographic map of Gaston County (Appendix C) obtained from the county website (www.co.gaston.nc.us) shows five-foot contour intervals. A tax map (Appendix B) illustrates the NSRC right of way which encompasses the Site. O. INJECTION FLUID DATA This section has been revised to reflect requirements for the permit modification. 9 Norfolk Southern Railway Company Injection Well Permit Modification for RegenOx® and ORC® Remediation Bessemer City, NC August 2007 1. FLUID SOURCE Both RegenOx® and ORC Advanced® are produced by the Regenesis Company. Information on these products are located in Appendix A. 2. CHEMICAL, PHYSICAL, BIOLOGICAL, AND RADIOLOGICAL CHARACTERISTICS OF INJECTION FLUID. The proposed injection materials, RegenOx® and ORC Advanced®, information provided by the manufacturer, is included in Appendix A. P. PERMIT LIST No change. Q. REFERENCES No change. 10 ►► 'J'�►►JSi3� FIGURES AND TABLES Prepared by: ARSHALL ► 1,ILLE SOCI _TES NS1499 09 /06/07 USGS 7.5' BESSEMER CITY, NC QUADRANGLE - 1973 CONTOUR INTERVAL = 20' NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NORTH CAROLINA 2,000' 0 2,000' SCALE 1:24,000 FIGURE 1 VICINITY MAP NORTH CAROLINA QUADRANGLE LOCATION 4 MW-7 50' Q� VIRGINIA AVENUE AUTO FIBER OPTIC CABLE — RAILROAD BRIDGE MW-6 4 PENNSYLVANIA AVE. 0 50' 1"=50' WRC/N,A NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. A STORM `®SEWER MW-1 AUTG- fl 4 MW-2 ,MW-4 PROPOSED INJEC11ON AREA 4)- MW-5 } MW-3 MW-1 LEGEND MONITORING WELL FIGURE 2 SITE MAP WITH PROPOSED INJECTION AREA NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: 4127107 SCALE: 1" = 50' DESIGNED: JB DRAWN: JGS Prepared by: NS1411•INJECTION.dwg A L� , ® MW_2 a/ a, IN e� ®. LEGEND 4 4 MW-1 - MONITORING WELL NO $ 1 _4, • - 1ST INJECTION EVENT A - 3RD INJECTION EVENT NOTE: The location and dimensions of features shown on this map have 0 - 2ND INJECTION EVENT * - 4TH INJECTION EVENT been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no GROUND WATER FLOW claim is made as to the degree of accuracy of this drawing. 11=1114SCALE: Prepared 6y: DATE: 7125/07 FIGURE 3 n 1"=4' PROPOSED INJECTION AREA NORFOLK SOUTHERN \ \ \ L• DESIGNED: JB EMI 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DRAWN: JGS - NS1411-INJECTION.dwg MW-7 881.64 50' IlRCryVfA STORM _�/-SEWER MW-1 VIRGINIA 884.48 40. ay, co AVENUE N'Oc 5 AUTO \ / / / / '882.54 FIBER OPTIC CABI 883 RAILROAD BRIDGE MW-6 PENNSYI VANIA AVE. 880.17 o •MW-3 88 .61 sixiastatsataatasi/ am" 0 50' 1 = 50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. LEGEND MW-1 — 880 — MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1 FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON JUNE 14, 2005 FIGURE 4 GROUND WATER CONTOUR MAP JUNE 2005 r NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CRY, NC DATE: 07/09/05 SCALE: 1" = 50' DESIGNED: JB DRAWN: BAG Prepared by: LARSHALL 1ILLE NS1411 JUNE 2005.dwg MW-7 876.02 co cb 50' 8>> 1 jRGIN/q VIRGINIA AVENUE AUTO 8>8 FIBER..^T. SABLE RAILROAD BRIDGE MW-6 PENNSYLVANIA AVE. 875.25 0 50' 1" = 50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. STORM —SEWER MW-1 879.27 - MW-5 *87.93 MW-3 MW-2 87 .27 877.86 w r MW-1 t) LEGEND MONITORING WELL — 876 — GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1 FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON DECEMBER 13, 2005 FIGURE 5 GROUND WATER CONTOUR MAP DECEMBER 2005 v�r NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CffY, NC DATE: 01/03106 SCALE: 1" = 50' DESIGNED: JB DRAWN: RDF Prepared by: ARSHALL k kILLE MILSICEITHEINIM NS1411 DEC 2005.dwg MW-7 NM 50' VIRGINIA AVENUE AUTO FIBER OPTIC CABLE RAILROAD BRIDGE MW-6 PENNSYLVANIA AVE. 875 0 50' 1"=50 OR GgyIA Atie NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. MW-1 879.734_ STORM � - SEWER MW-4 878.54 fl MW-1 878 NM *MW W1-3 87 .92 LEGEND MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOT MEASURED NOTES: 1. GROUNDWATER ELEVATIONS IN FEET ABOVE MEAN SEA LEVEL. 2. GROUNDWATER ELEVATIONS OBTAINED JUNE 8, 2006 FIGURE 6 GROUND WATER CONTOUR MAP JUNE 2006 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JUNE 2006 SCALE: 1" = 50' DESIGNED: JB DRAWN: PM Prepared ►►►► NS1411-June 2006.dwg 1 MW-7 DRY 50' Q_ VIRGINIA AVENUE AUTO FIBER OPTIC CABLE - RAILROAD BRIDGE MW-6 DRY PENNSYLVANIA AVE. 0 50' 1', = So, 14RGIN/A AVf NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. STORM �MW� 876.79 MW-4 r—� w ce 878.2233 ao r co MW 1 878 LEGEND MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1. GROUNDWATER ELEVATIONS IN FEET ABOVE MEAN SEA LEVEL. 2. GROUNDWATER ELEVATIONS OBTAINED JANUARY 3, 2007 FIGURE 7 GROUND WATER CONTOUR MAP JANUARY 2007 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY 2007 SCALE: 1"= 50' DESIGNED: JB DRAWN: RDF Prepare� f ►►' ►► NS1411June 2006.dwg MW-7 NS 50' , VIRGINIA AVENUE AUTO `4RG/N/A FIBER OPTIC CABLE — RAILROAD BRIDGE MW-6 NS PENNSYLVANIA AVE. 0 50' 1"=50' Av STORM SEWER NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. 130 5000 MW-5 *1550 500 MW-4� 310 LEGEND MW-1 ND NOT DETECTED NS NOT SAMPLED — 5000 — BENZENE ISOCONCENTRATION CONTOUR MONITORING WELL EXCEEDS NCDENR GROSS CONTAMINATION LEVEL (5000 Ng/L) NOTES: 1: G a UNU WATER SA ' LES COLLECTED N JANUARY 03, 2007 2. ALL RESULTS IN -OGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR BENZENE = 1 Ng/L FIGURE 8 BENZENE ISOCONCENTRATION MAP JANUARY 2007 tier NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY 2007 SCALE: 1"= 50' DESIGNED: JB DRAWN: RDF Prepared by: _ ►► ►► NS1411-June 2006.dwg r I MW-7 NS 50' C� _ ` VIRGIIVIq t/E STORM ®SEWER VIRGINIA AVENUE AUTO FIBER OPTIC CABLE RAILROAD BRIDGE PENNSYLVANIA AVE. 0 MW-6 50' 1"=50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. MW-1 690 • fl MW-5 {591l0 MW 3 8500 6600 MW-4 45700 r_ 14.1 oho LEGEND MONITORING WELL ND NOT DETECTED NS NOT SAMPLED J ESTIMATED VALUE —1000— TOLUENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON JANUARY 3, 2007 2: ALL RESULTS IN MICROGRAMS PER LITER (Ng/L) 3: NCDENR GROUND WATER STANDARD FOR TOLUENE = 1000 pg/L FIGURE 9 TOLUENE ISOCONCENTRATION MAP JANUARY 2007 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY 2007 SCALE: 1"= 50' DESIGNED: JB DRAWN: RDF ► .► NS1411-June 2006.dwg 1 MW-7 NS 50' C VIRGINIA AVENUE AUTO FIBER OPTIC CABLE PENNSYLVANIA AVE. s 0 RAILROAD BRIDGE MW-6 50' 1"= 50' ERG/NI/4 A f STORM _ _ ��SEWER MW-1- 70 NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. AVM 5 2800 ,MW 3 930 4O� j0 LEGEND MW-1 MONITORING WELL ND NOT DETECTED NS NOT SAMPLED —1000— ETHYLBENZENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON JANUARY 3, 2007 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR ETHYLBENZENE = 29 Ng/L FIGURE 10 ETHYLBENZENE ISOCONCENTRATION MAP JANUARY 2007 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY 2007 SCALE: 1" = 50' DESIGNED: JB DRAWN: RDF Prepared y: �.�v�llllll' ►!a\'b1:1c\�lk \IIMMEZKEITHEMI \J� NS1411June 2006.dwg 1 MW-7 NS so' — WI? G/NiA VIRGINIA AVENUE AUTO FIBER OPTIC CABLE -- RAILROAD BRIDGE MW-6 NS PENNSYLVANIA AVE. 0 50' 1" = 50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. AVE STORM ®SEWER fl MW-5 4100 5000 , MW-2 I 4300-M5300 I 1--.MW-4 W _AOOGCt IL 3500 I 0) r M LEGEND MW-1 MONITORING WELL ND NOT DETECTED NS NOT SAMPLED —5000— XYLENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON JANUARY 3, 2007 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR XYLENES = 530 Ng/L FIGURE 11 TOTAL XYLENES ISOCONCENTRATION MAP JANUARY 2007 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY 2007 SCALE: 1" = 50' DESIGNED: JB DRAWN: RDF Prepare NS1411-June 2006.dwg MW-7 NS 50' G l?RGINIA AVe STORM _®/ SEWER El VIRGINIA AVENUE MW\5 AUTO 4- 1 L' MW-3 200 FIBER OPTIC CABLE — RAILROAD BRIDGE MW-6 NS PENNSYLVANIA AVE. s 0 50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. LEGEND MW-1 MONITORING WELL ND NOT DETECTED NS NOT SAMPLED —500— NAPHTHALENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON JANUARY 3, 2007 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR NAPHTHALENE = 21 Ng/L FIGURE 12 NAPHTHALENE ISOCONCENTRATION MAP JANUARY 2007 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JANUARY2007 SCALE: 1" = 50' DESIGNED: JB DRAWN: RDF NS1411June 2006.dwg MW-7 50' �RGINIA A •STORM � ` SEWER VIRGINIA AVENUE AUTO FIBER OPTIC CABLE RAILROAD BRIDGE PENNSYLVANIA AVE. A uw_ 0 50' 1"=50' 5 3 LEGEND MW-1 MONITORING WELL - RAILROAD TRACKS NOTE: The location and dimensions of features shown on this map have A A' CROSS SECTION LINE been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. 0 - RAILROAD RIGHT-OF-WAY PROPERTY BOUNDARY (APPROXIMATE) FIGURE 13 SITE MAP SHOWING CROSS SECTION LINES � ry NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JUNE 2007 SCALE: 1"= 50' DESIGNED: SB DRAWN: JGS Prepared by: ►►' ►► NS1411.dwg SOUTH MW-6 CLAY - - SS-1 - SS-2 - SS-3 TD=20.8 FT. NOTE: The location and dimensions of features shown on this mop hove been derived from various sources and supplemented by fleld measurements. Though sufficient for Its intended purpose, no claim la made as to the degree of accuracy of thls drawing. MW-6 WAS DRY JANUARY 2006 20 10 0 APPROXIMATE HIGH WATER TABLE MAY 2003 APPROXIMATE LOW WATER TABLE NOVEMBER 2001 PROFILE SCALE HORIZONTAL 1 "=20' VERTICAL 1"=10' VERTICAL EXAGGERATION 2X RAILROAD EMBANKMENT MW-2 1/3/07 GROUND WATER RESULTS BENZENE TOLUENE ETHYLBENZENE XYLENES NAPHTHALENE 6400*E 8500 E 440 4300 260 APPROXIMATE GROUND SURFACE MIN--4 1/3/07 GROUND WATER RESULTS BENZENE TOLUENE ETHYLBENZENE XYLENES NAPHTHALENE 490 8400 E 970 5800 260 20 40 s CLAYEY SAND SANDY CLAY DISSOLVED IMPACTS ( CLAYEY SAND ABOVE NCDENR GROUND WATER STANDARDS (APPROXIMATE) M W-4 MW-2 NORTH MW-5 1/3/07 GROUND WATER RESULTS BENZENE TOLUENE ETHYLBENZENE XYLENES NAPHTHALENE 550 590 2800 4100 180 ASPHALT PAVEMENT - MW-5 - _SS-2 - UST EXCAVA'ION CLAY - } SS-1 _ CLAYEY -SS3 D-SS4 - SS-5 FILL -• CLAY — SAND - SANDY CLAY - _ - ) _ _ - -- - _ — ---- , TD=25 0 FT, TD WELL=25.0 FT. - - — ---TD=25.0 FT. TD SOIL BORING=27.0 FT. LEGEND SCREEN APPROXIMATE HIGH GROUND WATER ELEVATION (FT. MSL) MAY 2003 APPROXIMATE LOW GROUND WATER ELEVATION (FT. MSL) NOVEMBER 2001 1.) BOLD VALUES EXCEED NCDENR SOIL -TO -GROUNDWATER MCLs OR GROUND WATER STANDARDS. 2.) GROUND WATER DATA IN MICROGRAMS PER LITER (pG/L) 3.) E=CONCENTRATIONS EXCEEDS THE CALIBRATION RANGE OF THE INSTRUMENT 4.) *=EXCEEDS NDCENR GROSS CONTAMINATE LEVELS (GCLs) smmme SOU TH�ERN 130 11 O I❑ 1 >- z z M CC Z LU U a� �¢iz z0 z0z cc cno� YJ N W Lt.w = CO 0 z CROSS -SECTIONAL VIEW A -A' FIGU RE 14 EAST MW-3 zw J wl ma MW-2 ASPHALT PAVEMENT WEST APPROXIMATE MW-1 GROUND SURFACE CLAY - \\ v r 1 UST EXCAVATION ]- SS-1 SS-2 usr EXCAVATION L APPROXIMATE HIG WATER TABLE MAY 2003 -I 1- SS-1 TD=31.5 F. SURFACE CASING CLAY - i SS3 APPROXIMATE LOW WATER TABLE NOVEMBER 2001 SS-4 SS-5 TD WELL=25.0 FT. TD SOIL BORING=27.0 FT. MW-3 1/3/07 GROUND WATER RESULTS BENZENE 600 TOLUENE 6600 E ETHYLBENZENE 930 XYLENES 5300 E NAPHTHALENE 200 NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for Its intended purpose, no dorm Is made as to the degree of accuracy of this drawing. 0 DISSOLVED IMPACTS ABOVE NCDENR GROUND WATER STANDARDS (APPROXIMATE) PROFILE SCALE HORIZONTAL 1"=10' VERTICAL 1"=10' 10 20 s CLAY - SS-2 SS-3 TD WELL=25.0 FT.r �S � -SS-6 TD SOIL BORING=42.0 FT j LEGEND SCREEN APPROXIMATE HIGH GROUND WATER ELEVATION (FT. MSL) MAY 2003 APPROXIMATE LOW GROUND WATER ELEVATION (FT. MSL) NOVEMBER 2001 MW-1 1/3/07 GROUND WATER RESULTS BENZENE TOLUENE ETHYLBENZENE XYLENES NAPHTHALENE 130 690 70 790 56 MW-2 1/3/07 GROUND WATER RESULTS BENZENE 6400*E TOLUENE 8500 E ETHYLBENZENE 440 XYLENES 4300 NAPHTHALENE 260 1.) BOLD VALUES EXCEED NCDENR SOIL -TO -GROUND WATER MCLs • OR GROUND WATER STANDARDS. 2.) GROUND WATER DATA IN MICROGRAMS PER LITER (pG/L) 3.) E=CONCENTRATIONS EXCEEDS THE CALIBRATION RANGE OF THE INSTRUMENT 4.) *=EXCEEDS NDCENR GROSS CONTAMINATE LEVELS (GCLs) NORFOLK SOUTHERN m ❑0 00 ■o 1 A 4 EA 1 C A a NORFOLK SOUTHERN RAILWAY COMPANY Z W o Q w U < g cc zZ ct • 5 o W N W fn W CROSS -SECTIONAL VIEW B-B' FIGURE 15 TABLE 1 GROUND WATER ELEVATION AND FIELD MEASUREMENT DATA Norfolk Southern Railway Company Bessemer City, North Carolina GROUND WATER ELEVATION DATA FIELD MEASUREMENT DATA Monitoring Well Number Date Measured Ground Surface Elevation (MSL) Top of Casing Elevation (ft MSL) Depth to Water (ft TOC) Groundwater Elevation (ft MSL) Temperature o ( Celsius) pH Specific Conductivity (uS/cm) Dissolved Oxygen (mg/i) MW-1 12/07/99 895.49 894.72 15.77 878.95 NA NA NA NA 03/16/00 895.49 894.72 12.59 882.13 NA NA NA NA 03/18/00 895.49 894.72 12.61 882.11 NA NA NA NA 09/14/00 895.49 894.72 16.30 878.42 NA NA NA NA 04/04/01 895.49 894.72 12.32 882.40 NA NA NA NA 08/22/01 895.49 894.72 17.76 876.96 19.5 4.48 1390 0.26 11/29/01 895.49 894.72 19.52 875.20 19.2 4.41 1430 0.21 03/04/02 895.49 894.72 16.60 878.12 20.0 4.91 1160 0.39 06/12/02 895.49 894.72 17.41 877.31 19.5 4.58 42* 0.12 11/26/02 895.49 894.72 18.35 876.37 17.9 5.13 1410 1.47 05/14/03 895.49 894.72 8.22 886.50 19.6 5.97 1360 0.5 11/10/03 895.49 894.72 11.33 883.39 18.4 6.78 1290 NM 11/17/04 895.49 894.72 12.33 882.39 20.1 4.9 1410 1.11 06/14/05 895.49 894.72 10.24 884.48 19.1 6.87 _ 85.5 NM 12/13/05 895.49 894.72 15.45 879.27 18.6 5.32 67 NM 06/08/06 895.49 894.72 14.99 879.73 21.5 5.13 71 NM 01/03/07 895.49 894.72 14.50 880.22 17.92 4.73 147 1 # MW-2 12/07/99 894.77 894.30 15.57 878.73 NA NA NA NA 03/16/00 894.77 894.30 12.93 881.37 NA NA NA NA 08/22/01 894.77 894.30 17.19 877.11 19.2 5.30 1150 0.20 11/29/01 894.77 894.30 18.96 875.34 20.0 5.86 1450 0.18 03/04/02 894.77 894.30 16.90 877.40 20.0 5.60 1100 0.92 06/12/02 894.77 894.30 17.63 876.67 19.4 5.58 103* NA 11/26/02 894.77 894.30 19.37 874.93 20.3 6.13 1480 1.7 05/14/03 894.77 894.30 10.40 883.90 21.8 6.05 1370 0.8 11/10/03 894.77 894.30 10.90 883.40 17.0 9.9 1670 NM 11/17/04 894.77 894.30 13.20 881.10 21.2 5.18 1270 NM 06/14/05 894.77 894.30 12.12 882.18 19.7 8.51 391.5 NM 12/13/05 894.77 894.30 16.44 877.86 19.9 8.66 388 NM 06/08/06 894.77 894.30 15.60 878.70 23.1 8.83 353 NM 01/03/07 894.77 894.30 15.75 878.55 18.2 6.91 600 3.7 # Attach4-Tablel.xls Page 1 of 4 \\' !NMI ��; SOCI; ES TABLE 1 GROUND WATER ELEVATION AND FIELD MEASUREMENT DATA Norfolk Southern Railway Company Bessemer City, North Carolina GROUND WATER ELEVATION DATA FIELD MEASUREMENT DATA Monitoring Well Number Date Measured Ground Surface Elevation (MSL) Top of Casing Elevation (ft MSL) Depth to Water (ft TOC) Groundwater Elevation (ft MSL) Temperature P o ( Celsius) pH Specific Conductivity (uS/cm) Dissolved Oxygen (mg/1) MW-3 12/07/99 894.07 893.84 15.60 878.24 NA NA NA NA 03/16/00 894.07 893.84 12.59 881.25 NA NA NA NA 03/18/00 894.07 893.84 12.63 881.21 NA NA NA NA 09/14/00 894.07 893.84 14.84 879.00 NA NA NA NA 04/04/01 894.07 893.84 12.20 881.64 NA NA NA NA 08/22/01 894.07 893.84 15.51 878.33 21.3 5.10 2000 0.54 11/29/01 894.07 893.84 17.79 876.05 20.4 4.89 2220 2.08 03/04/02 894.07 893.84 16.86 876.98 20.9 5.69 2000 0.87 06/12/02 894.07 893.84 17.39 876.45 19.8 5.50 155* 0.80 11/26/02 894.07 893.84 19.03 874.81 18.2 5.29 1440 2.64 05/14/03 894.07 893.84 10.73 883.11 21.8 5.03 2080 0.60 11/10/03 894.07 893.84 11.85 881.99 16.9 10.08 1420 NM 11/17/04 894.07 893.84 15.79 878.05 20.5 5.15 1830 NM 06/14/05 894.07 893.84 12.23 881.61 19.8 7.02 186 NM 12/13/05 894.07 893.84 16.57 877.27 19.6 5.91 111 NM 06/08/06 894.07 893.84 15.92 877.92 24.6 5.62 114 NM 01/03/07 894.07 893.84 17.05 876.79 18.6 4.85 181 3.7 # MW-4 12/07/99 894.84 894.33 16.00 878.33 NA NA NA NA 03/16/00 894.84 894.33 13.20 881.13 NA NA NA NA 03/18/00 894.84 894.33 13.23 881.10 NA NA NA NA 09/14/00 894.84 894.33 16.89 877.44 NA NA NA NA 04/04/01 894.84 894.33 13.42 880.91 NA NA NA NA 08/22/01 894.84 894.33 18.34 875.99 18.5 4.70 770 0.30 11/29/01 894.84 894.33 19.92 874.41 19.2 4.97 870 0.34 03/04/02 894.84 894.33 17.37 876.96 18.7 5.09 800 0.25 06/12/02 894.84 894.33 18.25 876.08 18.4 5.02 61* 0.34 11/26/02 894.84 894.33 19.92 874.41 17.6 5.13 961 2.08 05/14/03 894.84 894.33 7.37 886.96 21.4 5.84 1680 1.3 11/10/03 894.84 894.33 9.05 885.28 17.1 9.87 1420 NM 11/17/04 894.84 894.33 12.76 881.57 19.18 4.69 780 0.81 06/14/05 894.84 894.33 10.83 883.50 18.7 7.1 225 NM 12/13/05 894.84 894.33 16.79 877.54 18.1 8.4 469 NM 06/08/06 894.84 894.33 15.79 878.54 23.1 9.34 344 NM 01/03/07 894.84 894.33 16.10 878.23 16.16 5.19 114 5 # Attach4-Tablel .xls Page 2 of 4 TABLE 1 GROUND WATER ELEVATION AND FIELD MEASUREMENT DATA Norfolk Southern Railway Company Bessemer City, North Carolina GROUND WATER ELEVATION DATA FIELD MEASUREMENT DATA Monitoring Well Number Date Measured Ground Surface Elevation (MSL) Top of Casing Elevation (ft MSL) Depth to Water (ft TOC) Groundwater Elevation (ft MSL) Temperature o ( Celsius) pH Specific Conductivity (uS/cm) Dissolved Oxygen (mg/1) MW-5 12/07/99 894.49 894.18 15.09 879.09 NA NA NA NA 03/16/00 894.49 894.18 12.50 881.68 NA NA NA NA 03/18/00 894.49 894.18 12.52 881.66 NA NA NA NA 09/14/00 894.49 894.18 14.89 879.29 NA NA NA NA 04/04/01 894.49 894.18 12.18 882.00 NA NA NA NA 08/22/01 894.49 894.18 16.08 878.10 20.1 4.26 1430 0.20 11/29/01 894.49 894.18 17.86 876.32 21.0 4.20 1510 0.77 03/04/02 894.49 894.18 16.33 877.85 20.6 4.67 1270 0.37 06/12/02 894.49 894.18 17.29 876.89 20.0 4.53 237* 0.34 11/26/02 894.49 894.18 18.66 875.52 17.9 5.28 1350 1.68 05/14/03 894.49 894.18 9.92 884.26 24.4 5.86 1770 1.3 11/10/03 894.49 894.18 12.25 881.93 19.4 9.91 1580 NM 11/17/04 894.49 894.18 13.43 880.75 20.9 4.58 1310 0.89 06/14/05 894.49 894.18 11.64 882.54 19.8 8.76 153 NM 12/13/05 894.49 894.18 16.25 877.93 19.7 5.1 69 NM 06/08/06 894.49 894.18 15.57 878.61 22.5 4.79 84 NM 01/03/07 894.49 894.18 15.50 878.68 18.9 4.37 190 1.5 # MW-6 12/07/99 893.58 893.26 NA NA NA NA NA NA 03/16/00 893.58 893.26 NA NA NA NA NA NA 03/18/00 893.58 893.26 NA NA NA NA NA NA 09/14/00 893.58 893.26 NA NA NA NA NA NA 04/04/01 893.58 893.26 15.45 877.81 NA NA NA NA 08/22/01 893.58 893.26 19.73 873.53 13.7 NA NA 2.74 11/29/01 893.58 893.26 19.81 873.45 NA NA NA NA 03/04/02 893.58 893.26 19.08 874.18 17.3 4.54 1520 4.90 06/12/02 893.58 893.26 19.76 873.50 NA NA NA NA 11/26/02 893.58 893.26 Dry NA NA NA NA NA 05/14/03 893.58 893.26 10.84 882.42 18.4 5.54 1850 11.6 11/10/03 893.58 893.26 13.21 880.05 16.7 6.31 1910 NM 11/17/04 893.58 893.26 15.10 878.16 19.35 4.5 2170 3.15 06/14/05 893.58 893.26 13.09 880.17 18.7 7.12 211.5 NM 12/13/05 893.58 893.26 18.01 875.25 18.9 4.98 132 NM 06/08/06 893.58 893.26 17.57 875.69 22.5 4.34 119 NM 01/03/07 893.58 893.26 Dry NA NM NM NM NM Attach4-Tablel.xls Page 3 of 4 TABLE 1 GROUND WATER ELEVATION AND FIELD MEASUREMENT DATA Norfolk Southern Railway Company Bessemer City, North Carolina GROUND WATER ELEVATION DATA FIELD MEASUREMENT DATA Ground Top of Depth Groundwater Specific Dissolved Monitoring Date Surface Casing to Water Elevation Temperature pH Conductivity Oxygen Well Number Measured Elevation (MSL) Elevation (ft MSL) (ft TOC) (ft MSL) Celsius) (uS/cm) (mi/1) MW-7 12/07/99 896.02 895.81 NA NA NA NA NA NA 03/16/00 896.02 895.81 NA NA NA NA NA NA 03/18/00 896.02 895.81 NA NA NA NA NA NA 09/14/00 896.02 895.81 NA NA NA NA NA NA 04/04/01 896.02 895.81 18.40 877.41 NA NA NA NA 08/22/01 896.02 895.81 19.80 876.01 18.1 NA NA 5.23 11/29/01 896.02 895.81 Dry NA NA NA NA NA 03/04/02 896.02 895.81 Dry NA NA NA NA NA 06/12/02 896.02 895.81 Dry NA NA NA NA NA 11/26/02 896.02 895.81 Dry NA NA NA NA NA 05/14/03 896.02 895.81 12.12 883.69 18.1 5.52 1420 10.9 11/10/03 896.02 895.81 15.06 880.75 16.3 6.19 1310 NM 11/17/04 896.02 895.81 16.70 879.11 18.7 5.08 1810 3.15 06/14/05 896.02 895.81 14.17 881.64 17.5 7.09 166.5 NM 12/13/05 896.02 895.81 19.79 876.02 NM NM NM NM 06/08/06 896.02 895.81 19.71 876.10 NM NM NM NM 01/03/07 896.02 895.81 Dry NA NM NM NM NM Notes: Elevations are in reference to feet above mean sea level (MSL). ft - Feet uS/cm - Micro -Siemens per centimeter mg/1 - Milligrams per liter TOC - Top of casing NA - Not Available • - Units are in micro -ohms per centimeter NM - Not Measured Attach4-Table 1.xls Page 4 of 4 # - Estimated conversion from % DO to Mg/L APPENDIX A REGENESIS, REGENOX® and ORC ADVANCED® INFORMATION ORC "The Evolution of Controlled Release Oxygen" ORC Advanced" is the state-of-the-art technology for stimulating aerobic bioremediation. It offers unparalleled, maximum oxygen release for periods up to 12 months on a single injection and is specifically designed to minimize oxygen waste while maximizing contaminated site remediation. HOW IT WORKS Oxygen has been shown to be the limiting factor for microbes capable of aerobically degrading contaminants such as petroleum hydrocarbons. Without adequate oxygen, contaminant degradation will either cease or may proceed by much slower anaerobic (oxygen -free) processes. When hydrated, ORC Advanced is designed to release its full amount of oxygen (17% by weight) over a 12 month period. Upon injection into the subsurface, ORC Advanced utilizes its patented Controlled Release Technology (CRT') to deliver its oxygen consistently over an extended period of time, avoiding excessive foaming and oxygen loss seen with commodity chemicals. This enables aerobic microbes to significantly accelerate rates of natural attenuation over long periods of time. PRODUCT FEATURES AND BENEFITS Highest Available Oxygen Content More active oxygen (17%) plus Regenesis' patented CRT' saves time and money by increasing degradation rates and improving remediation performance by providing more oxygen on a single injection. It is particularly effective at higher demand sites where oxygen may be limited and scavenged by competing carbon sources. Patented Controlled Release Technology (CRT") Based on the same proven technology employed in the industry standard Oxygen Release Compound (ORC®), CRT allows for an efficient, long-term release of oxygen providing the optimal conditions for sustained aerobic biodegradation. This can save time and money by reducing the potential need for multiple applications. Also, oxygen release "lock -up" is avoided — an unfortunate problem experienced with commodity chemicals. (See Details of CRT in Figure 1). In -Situ Application Remediation with ORC Advanced is typically more cost-effective than ex -situ treatments. With the use of ORC Advanced there is minimal site disturbance with no above -ground piping or mechanical equipment, no operations and maintenance costs and no hazardous materials handling or disposal. Free Technical Design and Support from Regenesis Regenesis has been designing and evaluating in -situ accelerated bioremediation projects for over 10 years. This "free of charge" service offers the user the highest level of information available on stimulating natural attenuation and ensures a high level of project success. REGENESIS Leaders in Accelerated Natural Attenuation 1011 Calle Sombra / San Clemente / California 92673-6244 / Tel: 949/366-8000 / Fax: 949/366-8090 / www.regenesis.com 02004 Regenesis DEFINING THE SCIENCE BEHIND CONTROLLED RELEASE TECHNOLOGY (CRTTM) Early on, Regenesis researchers noted that in order to optimally stimulate the natural attenuation of aerobically degradable contaminants, biologically usable oxygen was best supplied in low but constant concentrations. Big bursts of oxygen are wasteful and simply "bubble off", often generating undesirable foaming and producing unwanted preferential flow paths in the subsurface. Regenesis sought to solve this problem by controlling the rate of oxygen release from solid oxygen sources. The answer was provided by the development of CRT. The CRT process involves intercalating (embedding) phosphates into the crystal structure of solid peroxygen molecules. This patented feature, now available in the ORC Advanced"' formulation, slows the reaction that yields oxygen within the crystal, minimizing "bubble off" which can waste the majority of oxygen available in common solid peroxygen chemicals. CRT"' provides "balance" — it slows down the rate of oxygen release while at the same time preventing "lock -up" Commodity solid peroxygen chemicals, when in contact with water, will produce an initial rapid and uncontrolled release of oxygen. Then, as hydroxides form, a significant portion of the oxygen deeper in the crystal is made unavailable or becomes"locked up." This undesirable effect is ineffiecient and costly. CRT prevents lock up and controls the rate of oxygen release, representing the state- of-the-art technology in passive oxygen delivery. CRT Specifics Uniformly embedded within the crystalline structure of the peroxygen are phosphate ions. These ions do two important things: 1. they slow the rate of hydration that liberates oxygen thereby creating the CRT effect and 2. they form exit pathways for the oxygen in an otherwise tightly packed crystal that can become even more "locked -up" when hydroxides begin to form as a reaction by-product following oxygen liberation. This patented process optimizes peroxygen performance and is only available in the Regenesis line of products. HOSPFHATE. tesGROUP': lntercafa" and Disrupt: rysiel'Ar(ay) For more information or a free :project evaluation contact Regenesis at (9,49) 366-8000 or visit our website at www.regenesis.com GENESIS ,Leaders'in.Accelerated Natural Attenuation Oxygen Release Compound — Advanced (ORC AdvancedrM) MATERIAL SAFETY DATA SHEET (MSDS) Last Revised: March 13, 2007 Section 1 - Material Identification Supplier: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Phone: 949.366.8000 Fax: 949.366.8090 E-mail: info(a,regenesis.com Chemical A mixture of Calcium OxyHydroxide [CaO(OH)2] and Description: Calcium Hydroxide [Ca(OH)2]. Chemical Family: Inorganic Chemical Advanced Formula Oxygen Release Compound Trade Name: (ORC Advancedrm) Chemical Synonyms Calcium Hydroxide Oxide; Calcium Oxide Peroxide Product Use: Used to remediate contaminated soil and groundwater (environmental applications) Section 2 — Composition CAS No. Chemical 682334-66-3 Calcium Hydroxide Oxide [CaO(OH)2] 1305-62-0 Calcium Hydroxide [Ca(OH)2] 7758-11-4 Dipotassium Phosphate (HK2O4P) 7778-77-0 Monopotassium Phosphate (H2K04P) Regenesis - ORC Advanced MSDS Section 3 — Physical Data Form: Powder Color: White to Pale Yellow Odor: Odorless Melting Point: 527 °F (275 °C) — Decomposes Boiling Point: Not Applicable (NA) Flammability/Flash NA Point: Auto- Flammability: NA Vapor Pressure: NA Self -Ignition NA Temperature: Thermal Decomposition: 527 °F (275 °C) — Decomposes Bulk Density: 0.5 — 0.65 g/ml (Loose Method) Solubility: 1.65 g/L @ 68° F (20° C) for calcium hydroxide. Viscosity: NA pH: 11-13 (saturated solution) Explosion Limits % by Volume: Hazardous Decomposition Products: Hazardous Reactions: Non -explosive Oxygen, Hydrogen Peroxide, Steam, and Heat None Regenesis - ORC Advanced MSDS Section 4 — Reactivity Data Stability: Conditions to Avoid: Incompatibility: Hazardous Polymerization: Stable under certain conditions (see below). Heat and moisture. Acids, bases, salts of heavy metals, reducing agents, and flammable substances. Does not occur. Section 5 — Regulations TSCA Inventory Listed List: CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: No Unlisted Substance: Yes Reportable Quantity (RQ): Characteristic(s): RCRA Number: Waste 100 pounds Ignitibility D001 SARA, Title III, Sections 302/303 (40 CFR Part 355 — Emergency Planning and Notification) Extremely Hazardous Substance: No SARA, Title HI, Sections 311/312 (40 CFR Part 370 — Hazardous Chemical Reporting: Community Right -To -Know Hazard Category: Immediate Health Hazard Fire Hazard Threshold Planning 10,000 pounds Quantity: Regenesis - ORC Advanced MSDS Section 5 — Regulations (cont) SARA, Title III, Section 313 (40 CFR Part 372 — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous Substance: WIIMIS Classification: No C D Canadian Domestic Not Listed Substance List: Oxidizing Material Poisonous and Infectious Material Material Causing Other Toxic Effects — Eye and Skin Irritant Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Handling: Keep in tightly closed container. Store in dry area, protected from heat sources and direct sunlight. Clean and dry processing pipes and equipment before operation. Never return unused product to the storage container. Keep away from incompatible products. Containers and equipment used to handle this product should be used exclusively for this material. Avoid contact with water or humidity. Regenesis - ORC Advanced MSDS Section 6 — Protective Measures, Storage and Handling (cont) Personal Protective Equipment (PPE) Engineering Controls: Respiratory Protection: Hand Protection: Eye Protection: Skin Protection: Other: Industrial Hygiene: Protection Against Fire & Explosion: Calcium Hydroxide ACGIH® TLV® (2000) 5 mg/m3 TWA OSHA PEL Total dust-15 mg/m3 TWA Respirable fraction- 5 mg/m3 TWA NIOSH REL (1994) 5 mg/m3 For many conditions, no respiratory protection however, in dusty or unknown atmospheres approved dust respirator. Impervious protective gloves made of nitrile, or neoprene. Use chemical safety goggles (dust proof). may be needed; use a NIOSH natural rubbber For brief contact, few precautions other than clean clothing are needed. Full body clothing impervious to this material should be used during prolonged exposure. Safety shower and eyewash stations should be present. Consultation with an industrial hygienist or safety manager for the selection of PPE suitable for working conditions is suggested. Avoid contact with skin and eyes. NA Section 7 — Hazards Identification Emergency Overview: Potential Health Effects: Oxidizer — Contact with combustibles may cause a fire. This material decomposes and releases oxygen in a fire. The additional oxygen may intensify the fire. Irritating to the mucous membrane and eyes. If the product splashes in ones face and eyes, treat the eyes first. Do not dry soiled clothing close to an open flame or heat source. Any Regenesis - ORC Advanced MSDS clothing that has been contaminated with this product should be submerged in water prior to drying. Inhalation: Eye Contact: Skin Contact: Ingestion: High concentrations may cause slight nose and throat irritation with a cough. There is risk of sore throat and nose bleeds if one is exposed to this material for an extended period of time. Severe eye irritation with watering and redness. There is also the risk of serious and/or permanent eye lesions. Irritation may occur if one is exposed to this material for extended periods. Irritation of the mouth and throat with nausea and vomiting. Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage/Gas Leakage: Extinguishing Media: Suitable: Further Information: First Aid: Collect in suitable containers. Wash remainder with copious quantities of water. See next. Large quantities of water or water spray. In case of fire in close proximity, all means of extinguishing are acceptable. Self contained breathing apparatus or approved gas mask should be worn due to small particle size. Use extinguishing media appropriate for surrounding fire. Apply cooling water to sides of transport or storage vessels that are exposed to flames until the fire is extinguished. Do not approach hot vessels that contain this product. After contact with skin, wash immediately with plenty of water and soap. In case of contact with eyes, rinse immediately with plenty of water and seek medical attention. Consult an opthalmologist in all cases. Section 8 — Measures in Case of Accidents and Fire Eye Contact: Inhalation: Flush eyes with running water for 15 minutes, while keeping the eyelids wide open. Consult with an ophthalmologist in all cases. Remove subject from dusty environment. Consult with a physician in case of respiratory symptoms. Regenesis - ORC Advanced MSDS Ingestion: Skin Contact: Special Precautions: Specific Hazards: If the victim is conscious, rinse mouth and admnister fresh water. DO NOT induce vomiting. Consult a physician in all cases. Wash affected skin with running water. Remove and clean clothing. Consult with a physician in case of persistent pain or redness. Evacuate all non -essential personnel. Intervention should only be done by capable personnel that are trained and aware of the hazards associated with this product. When it is safe, unaffected product should be moved to safe area. Oxidizing substance. Oxygen released on exothermic decomposition may support combustion. Confined spaces and/or containers may be subject to increased pressure. If product comes into contact with flammables, fire or explosion may occur. Section 9 — Accidental Release Measures Precautions: Observe the protection methods cited in Section 3. Avoid materials and products that are incompatible with product. Immediately notify the appropriate authorities in case of reportable discharge (> 100 lbs). Collect the product with a suitable means of avoiding dust formation. All receiving equipment should be clean, vented, dry, labeled and made of material that this product is Cleanup Methods: compatible with. Because of the contamination risk, the collected material should be kept in a safe isolated place. Use large quantities of water to clean the impacted area. See Section 12 for disposal methods. Section 10 — Information on Toxicology Toxicity Data Acute Toxicity: Irritation: Oral Route, LD50, rat, > 2,000 mg/kg (powder 50%) Dermal Route, LD50, rat, > 2,000 mg/kg (powder 50%) Inhalation, LD50, rat, > 5,000 mg/m3 (powder 35%) Rabbit (eyes), severe irritant Regenesis - ORC Advanced MSDS Sensitization: No data Chronic Toxicity: In vitro, no mutagenic effect (Powder 50%) Target Effects: Organ Eyes and respiratory passages. Section 11— Information on Ecology Ecology Data 10 mg Ca(OH)2/L: pH = 9.0 100 mg Ca(OH)2/L: pH = 10.6 Acute Exotoxicity: Fishes, Cyprinus carpio, LC50, 48 hrs, 160 mg/L Crustaceans, Daphnia sp., EC50, 24 hours, 25.6 mg/L (Powder 16%) Mobility: Low Solubility and Mobility Water — Slow Hydrolysis. Degradation Products: Calcium Hydroxide Abiotic Degradation: Water/soil — complexation/precipitation. Carbonates/sulfates present at environmental concentrations. Degradation products: carbonates/sulfates sparingly soluble Biotic Degradation: NA (inorganic compound) Potential for NA (ionizable inorganic compound) Bioaccumulation: Section 11— Information on Ecology (cont) Comments: Observed effects are related to alkaline properties of the product. Hazard for the environment is limited due to the product properties of: • No bioaccumulation • Weak solubility and precipatation as carbonate or sulfate in an aquatic environment. Diluted product is rapidly neutralized at environmental pH. Further Information: NA Regenesis - ORC Advanced MSDS Section 12 — Disposal Considerations Waste Disposal Consult current federal, state and local regulations regarding Method: the proper disposal of this material and its emptied containers. Section 13 — Shipping/Transport Information D.O.T Shipping Oxidizing Solid, N.O.S [A mixture of Calcium OxyHydroxide Name: [CaO(OH)2] and Calcium Hydroxide [Ca(OH)2]. UN Number: 1479 Hazard Class: 5.1 Label(s): 5.1 (Oxidizer) Packaging Group: II STCC Number: 4918717 Section 14 — Other Information HIVES® Rating Health — 2 Flammability — 0 Reactivity — 1 PPE - Required HMIS® is a registered trademark of the National Painting and Coating Association. Health — 2 Reactivity —1 NFPA® Rating Flammability — 0 OX NFPA® is a registered trademark of the National Fire Protection Association. Reason for Issue: Update toxicological and ecological data Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. Regen Ox TM CHEMICAL OXIDATION REDEFINED... RegenOxr" is an advanced in situ chemical oxidation technology* designed to treat organic contaminants including high concentration source areas in the saturated and vadose zones PRODUCT FEATURES: Rapid and sustained oxidation of target compounds • Easily applied with readily available equipment Destroys a broad range of contaminants • More efficient than other solid oxidants • Enhances subsequent bioremediation 4g Avoids detrimental impacts to groundwater aquifers RegenOx product application HOW IT WORKS: RegenOx maximizes in situ performance using a solid alkaline oxidant that employs a sodium percarbonate complex with a multi -part catalytic formula. The product is delivered as two parts that are combined and injected into the subsurface using common drilling or direct -push equipment. Once in the subsurface, the combined product produces an effective oxidation reaction comparable to that of Fenton's Reagent without a violent exothermic reaction. RegenOx safely, effectively and rapidly destroys a wide range of contaminants in both soil and groundwater (Table 1). ACHIEVES RAPID OXIDATION VIA A NUMBER OF MECHANISMS RegenOx directly oxidizes contaminants while its unique catalytic complex generates a suite of highly charged, oxidative free radicals that are responsible for the rapid destruction of contaminants. The mechanisms by which RegenOx operates are: • Surface- Mediated Oxidation: (see Figure 1 and description below) Direct Oxidation: C2CL, + 2 Na,CO3 • 3 H20, + 2 H2O "—► 2CO3 + 4 NaCI + 4 H2O + 2 H,CO3 a Free Radical Oxidation: — Perhydroxyl Radical (H02.) — Hydroxyl Radical (OH-) — Superoxide Radical (02') Figure 1. Surface -Mediated Oxidation is responsible for the majority of RegenOx contaminant destruction. This process takes place in two stages. First, the RegenOx activator complex coats the subsurface. Second, the oxidizer complex and contaminant react with the activator complex surface destroying the contaminant. * Patent applied for Figure 1. RegenOx'' Surface -Mediated Oxidation From Mass Reduction to Bioremediation: RegenOx`" is an effective and rapid contaminant mass reduction technology. A single injection will remove significant amounts of target contaminants from the subsurface. Strategies employing multiple Regenox injections coupled with follow-on accelerated bioremediation can be used to treat highly contaminated sites to regulatory closure. In fact, RegenOx was designed specifically to allow for a seamless transition to low-cost accelerated bioremediation using any of Regenesis controlled release compounds. Significant Longevity: RegenOx has been shown to destroy contaminants for periods of up to one month. Product Application Made Safe and Easy: RegenOx produces minimal heat and as with all oxidants proper health and safety procedures must be followed. The necessary safety guidance accompanies all shipments of RegenOx and additional resources are available on request. Through the use of readily available, highly mobile, direct -push equipment and an array of pumps, RegenOx has been designed to be as easy to install as other Regenesis products like ORC® and HRC®. Effective on a Wide Range of Contaminants: RegenOx has been rigorously tested in both the laboratory and the field on petroleum hydrocarbons (aliphatics and aromatics), gasoline oxygenates (e.g., MTBE and TAME), polyaromatic hydrocarbons (e.g., naphthalene and phenanthrene) and chlorinated hydrocarbons (e.g., PCE, TCE, TCA). Oxidant Effectiveness vs. Contaminant Type: Contaminant RegenOx" Tablet Fenton's Reagent Permanganate Persulfate Activated Persulfate Ozone Petroleum Hydrocarbons A A B B B A Benzene A A D B B A MTBE A B B C B 3 Phenols 1 A A B C B A Chlorinated Ethenes (PCE, TCE, DCE, VC) A A A B A A Chlorinated Ethanes (TCA, DCA) A B C D C B Polycyclic Aromatic Hydrocarbons (PAHs) A A B B A A Polychlorinated Biphenyls (PCBs) B C D D D 13 Explosives (RDX, HMX) A A A A A A Based on laboratory kinetic data, thermodynamic calculations, and literature reports. Oxidant Effectiveness Key: A = Short half life, low free energy (most energetically favored), most complete B = Intermediate half life, low free energy, intermediate degree of completion C = Intermediate half life, intermediate free energy, low degree of completion D = Long half life, high free energy (least favored), very low degree of completion REGENESIS Advanced Technologies for Groundwater Resources 1011 Calle Sombra i San Clemente !California 92673-6244 Tel: 9491366-8000 1 Fax: 949/366-8090 i www.regenesis.com Regen OX — Part A (Oxidizer Complex) Material Safety Data Sheet (MSDS) Last Revised: November 7, 2005 Section 1— Supplier Information and Material Identification Supplier: REGENES1S 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Chemical Description: Chemical Family: Trade Name: Product Use: A mixture of sodium percarbonate [2Na2CO3.3H2O2], sodium carbonate [Na2CO3], sodium silicate and silica gel. Inorganic Chemicals Regen Ox — Part A (Oxidizer Complex) Used to remediate contaminated soil and groundwater (environmental applications) Section 2 — Chemical Information/Other Designations CAS No. 15630-89-4 5968-11-6 1344-09-8 63231-67-4 Chemical Sodium Percarbonate Sodium Carbonate Monohydrate Silicic Acid, Sodium Salt, Sodium Silicate Silica Gel Section 3 — Physical Data Form: Color: Odor: Melting Point: Boiling Point: Powder White Odorless NA NA RegenOx — Part A Section 3 — Physical Data (cont) Flammability/Flash Point: Vapor Pressure: Bulk Density: Solubility: Viscosity: pH (3% solution): Decomposition Temperature: NA NA 0.9 — 1.2 g/cm3 Min 14.5g/100g water @ 20 °C NA " 10.5 Self -accelerating decomposition with oxygen release starts at 50 °C. Section 4 — Reactivity Data Stability: Conditions to Avoid/Incompatibility: Hazardous Decomposition Products: Stable under normal conditions Acids, bases, salts of heavy metals, reducing agents, and flammable substances Oxygen. Contamination with many substances will cause decomposition. The rate of decomposition increases with increasing temperature and may be very vigorous with rapid generation of oxygen and steam. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: Unlisted Substance: No Yes SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: WHMIS Classification: Canadian Domestic Substance List: C, D2B Appears J:\Operations\MSDS\Regenox Page 2 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Handling: Oxidizer. Store in a cool, well ventilated area away from all sources of ignition and out of the direct sunlight. Store in a dry location away from heat and in temperatures less than 40'C. Keep away from incompatible materials and keep lids tightly closed. Do not store in improperly labeled containers. Protect from moisture. Do not store near combustible materials. Keep containers well sealed. Store separately from reducing materials. Avoid contamination which may lead to decomposition. Avoid contact with eyes, skin and clothing. Use with adequate ventilation. Do not swallow. Avoid breathing vapors, mists or dust. Do not eat, drink or smoke in the work area. Label containers and keep them tightly closed when not in use. Wash hands thoroughly after handling. Personal Protective Equipment (PPE) Engineering Controls: Respiratory Protection: Hand Protection: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Avoid creating dust or mists. Maintain adequate ventilation at all times. Do not use in confined areas. Keep levels below recommended exposure limits. To determine actual exposure limits, monitoring should be performed on a routine basis. For many conditions, no respiratory protection is necessary; however, in dusty or unknown conditions or when exposures exceed limit values a NIOSH approved respirator should be used. Wear chemical resistant gloves (neoprene, rubber, or PVC). J:\Operations\MSDS\Regenox Page 3 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling (cont) Eye Protection: Skin Protection: Other: Protection Against Fire & Explosion: Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Try to avoid skin contact with this product. Chemical resistant gloves (neoprene, PVC or rubber) and protective clothing should be worn during use. Eye wash station. Product is non -explosive. In case of fire, evacuate all non- essential personnel, wear protective clothing and a self- contained breathing apparatus, stay upwind of fire, and use water to spray cool fire -exposed containers. Section 7 — Hazards Identification Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Eye Contact: Causes irritation, redness and pain. Skin Contact: Causes slight irritation. Ingestion: May be harmful if swallowed (vomiting and diarrhea). Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage: Eliminate all ignition sources. Evacuate unprotected personnel and never exceed any occupational exposure limit. Shovel or sweep spilt material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to the inventory. Extinguishing Media: First Aid Eye Contact: Water Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Inhalation: Remove affected person to fresh air. Seek medical attention if the effects persist. Ingestion: If the individual is conscious and not convulsing, give two- four cups of water to dilute the chemical and seek medical attention immediately. Do Not induce vomiting. J:\Operations\MSDS\Regenox Page 4 RegenOx — Part A Section 8 — Measures in Case of Accidents and Fire (cont) Skin Contact: Wash affected areas with soap and a mild detergent and large amounts of water. Section 9 — Accidental Release Measures Precautions: Cleanup Methods: Shovel or sweep spilt material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to the inventory. Section 10 — Information on Toxicology Toxicity Data LD50 Oral (rat): LD50 Dermal (rabbit): LD50 Inhalation (rat): 2,400 mg/kg Min 2,000 mg/kg Min 4,580 mg/kg Section 11— Information on Ecology Ecology Data Ecotoxicological Information: NA Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Package (Pail) Treatment: Dispose of in an approved waste facility operated by an authorized contactor in compliance with local regulations. The empty and clean containers are to be recycled or disposed of in conformity with local regulations. J:\Operations\MSDS\Regenox Page 5 RegenOx — Part A Section 13 — Shipping/Transport Information D.O.T. Shipping Name: Oxidizing Solid, N.O.S. [A mixture of sodium percarbonate [2Na2CO3.3H2O2], sodium carbonate [Na2CO3], sodium silicate and silica gel.] UN Number: 1479 Hazard Class: 5.1 Labels: 5.1 (Oxidizer) Packaging Group: III Section 14 — Other Information HMIS® Rating Health —1 (slight) Reactivity —1 (slight) Flammability — 0 (none) Lab PPE — goggles, gloves, and lab coat HMIS" is a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. J:\Operations\MSDS\Regenox Page 6 Regen OX — Part B (Activator Complex) Material Safety Data Sheet (MSDS) Last Revised: November 7, 2005 Section 1— Supplier Information and Material Identification Supplier: REGENES1S 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Chemical Description: Chemical Family: Trade Name: Product Use: A mixture of sodium silicate solution, silica gel and ferrous sulfate Inorganic Chemicals Regen Ox — Part B (Activator Complex) Used for environmental remediation of contaminated soils and groundwater Section 2 — Chemical Information/Other Designations CAS No. 1344-09-8 63231-67-4 7720-78-7 7732-18-5 Chemical Silicic Acid, Sodium Salt, Sodium Silicate Silica Gel Ferrous Sulfate Water Section 3 — Physical Data Form: Color: Odor: Melting Point: Boiling Point: Flammability/Flash Point: Vapor Pressure: Liquid Blue/Green Odorless NA NA NA NA RegenOx — Part B Section 3 — Physical Data (cont) Specific Gravity 1.39 g/cm3 Solubility: Miscible Viscosity: NA pH (3% solution): 11 Hazardous Decomposition Oxides of carbon and silicon may be formed when Products: heated to decomposition. Section 4 — Reactivity Data Stability: Stable under normal conditions. Conditions to Avoid: None. Incompatibility: Avoid hydrogen fluoride, fluorine, oxygen difluoride, chlorine trifluoride, strong acids, strong bases, oxidizers, aluminum, fiberglass, copper, brass, zinc, and galvanized containers. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: No Unlisted Substance: Yes SARA, Title III, Sections 302/303 (40 CFR Part 355) — Emergency Planning and Notification Extremely Hazardous No Substance: SARA, Title III, Sections 311/312 (40 CFR Part 370) — Hazardous Chemical Reporting: Community Right -To -Know Hazard Category: Acute SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: Page 2 RegenOx — Part B Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Keep in a tightly closed container (steel or plastic) and store in a cool, well ventilated area away from all incompatible materials (acids, reactive metals, and ammonium salts). Store in a dry location away from heat and in temperatures less than 24 ?C. Do not store in aluminum, fiberglass, copper, brass, zinc or galvanized containers. Handling: Avoid contact with eyes, skin and clothing. Avoid breathing spray mist. Use with adequate ventilation. Do not use product if it is brownish -yellow in color. Personal Protective Equipment (PPE) Engineering Controls: Respiratory Protection: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Safety shower and eyewash station should be within direct access. Use NIOSH-approved dust and mist respirator where spray mist exists. Respirators should be used in accordance with 29 CFR 1910.134. Hand Protection: Wear chemical resistant gloves. Eye Protection: Skin Protection: Other: Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Try to avoid skin contact with this product. Gloves and protective clothing should be worn during use. Protection Against Fire & Product is non -explosive and non-combustible. Explosion: Page 3 RegenOx — Part B Section 7 — Hazards Identification Potential Health Effects Inhalation: Eye Contact: Skin Contact: Ingestion: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Causes irritation, redness and pain. Causes irritation. Symptoms include redness, itching and pain. May cause irritation to mouth, esophagus, and stomach. Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage (small): After Spillage/Leakage (large): Extinguishing Media: Further Information: First Aid Eye Contact: Inhalation: Ingestion: Skin Contact: Mop up and neutralize liquid, then discharge to sewer in accordance with local, state and federal regulations. Keep unnecessary personnel away; isolate hazard area and do not allow entrance into the affected area. Do not touch or walk through spilled material. Stop leak if possible without risking injury. Prevent runoff from entering into storm sewers and ditches that lead to natural waterways. Isolate the material if at all possible. Sand or earth may be used to contain the spill. If containment is not possible, neutralize the contaminated area and flush with large quantities of water. Material is compatible with all extinguishing media. Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Remove affected person to fresh air. Give artificial respiration if individual is not breathing. If breathing is difficult, give oxygen. Seek medical attention if the effects persist. If the individual is conscious and not convulsing, give two-four cups of water to dilute the chemical and seek medical attention immediately. DO NOT induce vomiting. Wash affected areas with soap and a mild detergent and large amounts of water. Remove contaminated clothing and shoes. Page 4 RegenOx — Part B Section 9 — Accidental Release Measures Precautions: PPE: Environmental Hazards: Cleanup Methods: Wear chemical goggles, body -covering protective clothing, chemical resistant gloves, and rubber boots (see Section 6). Sinks and mixes with water. High pH of this material may be harmful to aquatic life. Only water will evaporate from a spill of this material. Pick-up and place in an appropriate container for reclamation or disposal. US regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. Section 10 — Information on Toxicology Toxicity Data Sodium Silicate: When tested for primary eye irritation potential according to OECD Guidelines, Section 405, a similar sodium silicate solution produced corneal, iridal and conjunctival irritation. Some eye irritation was still present 14 days after treatment, although the average primary irritation score has declined from 29.7 after 1 day to 4.0 after 14 days. When tested for primary skin irritation potential, a similar sodium silicate solution produced irritation with a primary irritation index of 3 to abraded skin and 0 to intact skin. Human experience confirms that irritation occurs when sodium silicates get on clothes at the collar, cuffs, or other areas where abrasion may exist. The acute oral toxicity of this product has not been tested. Ferrous Sulfate: LD50 Oral (rat): 319 mg/kg not a suspected carcinogen. Page 5 RegenOx — Part B Section 11— Information on Ecology Ecology Data Ecotoxicological Based on 100% solid sodium silicate, a 96 hour median Information: tolerance for fish of 2,320 mg/1; a 96 hour median tolerance for water fleas of 247 mg/L; a 96 hour median tolerance for snail eggs of 632 mg/L; and a 96 hour median tolerance for Amphipoda of 160 mg/L. Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Package (Pail) Treatment: Neutralize and landfill solids in an approved waste facility operated by an authorized contactor in compliance with local regulations. The empty and clean containers are to be recycled or disposed of in conformity with local regulations. Section 13 — Shipping/Transport Information D.O.T. This product is not regulated as a hazardous material so there are no restrictions. Section 14 — Other Information HMIS Rating Health — 2 (moderate) Reactivity — 0 (none) Flammability — 0 (none) Lab PPE — goggles, Contact —1 (slight) gloves, and lab coat HMISis a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Page 6 RegenOx — Part B Page 7 APPENDIX B GASTON COUNTY MAPS Map Output Disclaimer: The information provided is not to be considered as a L Gaston County does not guarantee the accuracy of thi: Page 1 of 1 http://public_gis.co.gaston.nc.us/website/ParcelDai 10/19/2004 Map Output Disclaimer: The information provided is not to be considered as a Gaston County does not guarantee the accuracy of th Page 1 of 1 http://public_gis.co.gaston.nc.us/website/Parcela 10/25/2004 Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Coleen H. Sullins Director Division of Water Quality July 11, 2007 Forrest W. Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 CERTIFIED MAIL RETURN RECEIPT REQUESTED 7006 2150 0003 5466 3174 Subject: Notice of Expiration UIC Permit No. WI0300065 Virginia Avenue Auto & Wrecker Gaston County Dear Mr. Stevenson: The Underground Injection Control (UIC) Program of the North Carolina Division of Water Quality is responsible for regulating injection well construction and operation activities within the state. Our records show that the injection well permit referenced above will expire on December 1, 2007. This permit was issued on December 6, 2004 for the injection system located at 201 West Virginia Avenue in Bessemer City, North Carolina. Please submit the enclosed form, STATUS OF INJECTION WELL SYSTEM (form GW/UIC-68) to indicate the current status of this injection well system within 30 calendar days of the receipt of this letter. If you intend to conduct additional injections or pursue any injection -related activities that are beyond the scope of the permit referenced above, you must submit a letter requesting a renewal and/or amendment of the permit that describes in detail the procedure, locations, volume, and frequency of injected material, and any other pertinent information regarding the proposed activity. In addition, our records indicate that a final project evaluation is due within 9 months after completion of the injection operation. If the injection project has been completed, please submit the required final project evaluation as indicated in your permit in PART VII — MONITORING AND REPORTING REQUIREMENTS. If any injection well is no longer being used for any purpose, it must be permanently abandoned according to the regulatory requirements specified in the North Carolina Administrative Code Title 15A Subchapter 2C Section .0214. If any injection well is to be permanently abandoned, well abandonment records must be submitted to our office to ensure proper abandonment. Aquifer Protection Section 1636 Mail Service Center Internet: www.ncwaterqualitv.org Location: 2728 Capital Boulevard An Equal Opportunity/Affirmative Action Employer— 50% Recycled/10% Post Consumer Paper NorthCarolina Naturally Raleigh, NC 27699-1636 Telephone: (919) 733-3221 Raleigh, NC 27604 Fax 1: (919) 715-0588 Fax 2: (919) 715-6048 Customer Service: (877) 623-6748 Please call Qu Qi at (919) 715-6935, or email him at qu.gi@ncmail.net if you have any questions regarding this correspondence, your permit, or the enclosed form. Sincerely, W Jesse Wiseman Aquifer Protection Section Enclosure cc: Suzanne Bailey, MM&A _ fo_oresville.Regional-Office._APS w/o -enclosure_ 1 APS Central Files - Permit No. WI0300065 w/o enclosure MEMORANDUM To: From: Re: DIVISION OF WATER QUALITY AQUIFER PROTECTION SECTION December 7, 2004 !Andrew-P-itner, Aquifer Protection Supervisor Mooresville Regional Office Mike Ranck/t Central Office Issuance of injection well permit type 5I (in -situ groundwater remediation well) Permit Number WI0300065 Norfolk Southern Railway Company Permit Number WI0300065 is for the injection of Oxygen Release Compound® to enhance bioremediation of the dissolved phase hydrocarbon contamination at this site. These injection wells will be located at 201 W. Virginia Avenue, Bessemer City, North Carolina, Gaston County. Please retain the application paper work and permit copy for the MRO-UIC files. The UIC group appreciates the MRO's inspection and review tasks concerning this permit application. If you have any questions regarding this permit or the UIC program, please contact me at (919) 715-6164 or Evan Kane at (919) 715-6182. cc: CO-UIC Files Enclosures Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Alan W. Klimek, P.E. Director Division of Water Quality December 7, 2004 Mr. Forrest W. Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 Dear Mr. Stevenson: In accordance with your application received on August 25, 2004, we are forwarding Permit No. WI0300065 for the operation of Type 5I injection wells at 201 W. Virginia Avenue, Bessemer City, North Carolina. This permit shall be effective from the date of issuance until December 1, 2007, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII—MONITORING AND REPORTING REQUIREMENTS. Please note that the permit requires additional sampling and analysis beyond what is proposed in the original application. These additions are listed in Part VII-1 of the permit. You will also need to notify this office by telephone 48 hours prior to initiation of injection at this facility. In order to continue uninterrupted legal use of this injectant for the stated purpose, you should submit an application to renew the permit three months prior to its expiration date. If you have any questions regarding your permit please contact me at (919) 715-6164 or Evan Kane at (919) 715-6182. Sincerely, /. &Wed ilt/4„. J. Michael Ranck Hydrogeologist Groundwater Protection Unit cc: Andrew Pitner, MRO CO-UIC file Suzanne Bailey, MM&A Enclosures No One Carolina aurally Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Internet: http://h2o.enr.state.nc.us 2728 Capital Boulevard Raleigh, NC 27604 An Equal Opportunity/Affirmative Action Employer-50% Recycled/10% Post Consumer Paper Phone (919) 733-3221 Customer Service Fax (919) 715-0588 1-877-623-6748 Fax (919)715-6048 NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF WELLS FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Norfolk Southern Railway Company FOR THE CONSTRUCTION AND OPERATION OF TYPE 5I INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), for use to inject Oxygen Release Compound® for enhanced bioremediation of dissolved petroleum hydrocarbons. These injection wells will be located at 201 West Virginia Avenue, Bessemer City, North Carolina, and will be operated in accordance with the application submitted August 25, 2004 and in conformity with the specifications and supporting data submitted November 1, 2004, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until December 1, 2007, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. Permit issued this the (n day of reC*nkrt ( , 2004. (05\c,- 'Ted L. Bush, Jr., Chief Aquifer Protection Section Division of Water Quality By Authority of the Environmental Management Commission. Permit No. WI0300065 PAGE 1 OF 6 ver.7/04 AP/UIC-6 PART I - WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this peiniit, the approved plans and specifications, and other supporting data. 3. This permit is valid only for construction of the number of injection wells described in the application and other supporting data. Construction of additional injection wells must be approved in advance by the Aquifer Protection Section. 4. Each injection well shall not hydraulically connect separate aquifers. 5. Each injection well shall be constructed in such a manner that water from land surface cannot migrate into the gravel pack or well screen. 6. Each injection well shall be secured to reasonably insure against unauthorized access and use. Each well shall be permanently labeled with a warning that it is for injection purposes and the entrance to each well must be secured with a locking cap. 7. Each injection well shall be afforded reasonable protection against damage during construction and use. 8. Each injection well shall have permanently affixed an identification plate. 9. A completed Well Construction Record (Form GW-1) must be submitted for each injection well to DENR-Division of Water Quality, Aquifer Protection Section — UIC Program, 1636 Mail Service Center, Raleigh, NC 27699-1636, within 30 days of completion of well construction. PART II - WELL CONSTRUCTION SPECIAL CONDITIONS 1. At least forty-eight (48) hours prior to constructing each injection well, the Permittee shall notify the Aquifer Protection Section -Underground Injection Control (UIC) Central Office staff, telephone number (919) 715-6164 and the Mooresville Regional Office Aquifer Protection Section Staff, telephone number (704) 663-1699. PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate of injection, and number of injection wells as described in the application and other supporting data. Permit No. WI0300065 PAGE 2 OF 6 ver.7/04 AP/UIC-6 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes, rules, regulations, or ordinances which maybe imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV - PERFORMANCE STANDARDS 1. The injection facility shall be effectively maintained and operated at all times so that there is no contamination of groundwater which will render it unsatisfactory for normal use. In the event that the facility fails to perform satisfactorily, including the creation of nuisance conditions or failure of the injection zone to adequately assimilate the injected fluid, the Permittee shall take immediate corrective actions including those actions that may be required by the Division of Water Quality such as the repair, modification, or abandonment of the injection facility. 2. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. PART V - OPERATION AND MAINTENANCE REQUIREMENTS 1. The injection facility shall be properly maintained and operated at all times. 2. The Permittee must notify the Division and receive prior written approval from the Director of any planned physical alterations or additions in the permitted facility or activity not specifically authorized by the permit. 3. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section - Underground Injection Control (UIC), Central Office staff, telephone number (919) 715- 6164. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. PART VI - INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on Permit No. WI0300065 PAGE 3 OF 6 ver.7/04 AP/UIC-6 or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS 1. The proposed monitor plan included in the application shall be followed. In addition to the monitor plan in the application, all samples shall be analyzed for ferrous iron, oxidation- reduction potential, biological oxygen demand, and chemical oxygen demand. Additionally, samples shall be collected and analyzed from MW-1 on the same schedule as MW-3, MW-6, and MW-7. All sample results shall be submitted to the Aquifer Protection Section's Mooresville Regional Office and the Raleigh Central Office (see VII-3 for addresses). Any monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to insure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. 2. The Permittee shall produce a final project evaluation within 9 months after completing all injection -related activity associated with the permit application. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plume maps and potentiometric surface maps. 3. The final project evaluation shall be submitted to the Underground Injection Control Program, Aquifer Protection Section, NC DENR-Division of Water Quality, 1636 Mail Service Center, Raleigh, NC 27699-1636 and to the Aquifer Protection Section, Mooresville Regional Office, 610 East Center Avenue, Suite 301, Mooresville, NC 28115. 4. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Mooresville Regional Office, telephone number (704) 663-1699, any of the following: (A)Any occurrence at the injection facility which results in any unusual operating circumstances; (B) Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 5. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Permit No. WI0300065 PAGE 4 OF 6 ver.7/04 AP/UIC-6 Director by the Permittee. 6. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. PART VIII - PERMIT RENEWAL The Permittee shall, at least three (3) months prior to the expiration of this permit, request an extension. PART IX - CHANGE OF WELL STATUS 1. The Permittee shall provide written notification within 15 days of any change of status of an injection well. Such a change would include the discontinued use of a well for injection. If a well is taken completely out of service temporarily, the Permittee must install a sanitary seal. If a well is not to be used for any purpose that well must be permanently abandoned according to 15A NCAC 2C .0113, Well Construction Standards. 2. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that injection well in accordance with the procedures specified in 15A NCAC 2C .0113(b), including but not limited to the following: (A) All casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B) The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. (C) The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D)Drilled wells shall be completely filled with cement grout, or bentonite grout which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel -packed wells in which the casing and screens have not been removed, neat -cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. Permit No. WI0300065 PAGE 5 OF 6 ver.7/04 AP/UIC-6 (G) The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment. 3. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Staff DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 PART X — WORKER PRECAUTIONS DURING APPLICATION 1. Exposure can cause irritation of skin, eyes, nose, and throat. 2. Contents within the product proposed for use may ignite combustibles (wood, paper and oil). In addition, contents within the product react violently with reducing agents, hydrocarbons such as fuels, and strong acids which can lead to a fire hazard. 3. If the products are released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then it is imperative that proper personal protective equipment be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. 4. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 5. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 6. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 7. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. 8. Access to the area of application should be limited to the workers applying the product. In order to minimize exposure to unprotected individuals, measure should be taken to prevent access to the area of application. Permit No. WI0300065 PAGE 6 OF 6 ver.7/04 AP/UIC-6 October 28, 2004 Mr. Michael Ranck Groundwater Protection Unit NCDENR-DWQ 1636 Mail Service Center Raleigh, North Carolina 27699-1637 Re: Addendum to Application for Permit, Class 5I Wells Virginia Avenue Auto & Wrecker Site Bessemer City, Gaston County, North Carolina Pollution Incident #19216 Norfolk Southern File No. 1-9-NC-BSMR-UT98.133-002 MM&A Project # NS1411 Dear Mr. Ranck: Marshall Miller & Associates, Inc. (MM&A), on behalf of Norfolk Southern Railway Company (NSRC), is submitting the enclosed information as an addendum to the Class 5I Well Permit Application, per your letter dated September 24, 2004. Following are numbered responses corresponding to your comments in the September 24, 2004 letter. A copy of your letter is enclosed for reference in Attachment 1. 1. Per our telephone conversation on October 5, 2004, MM&A has enclosed copies of the groundwater potentiometric maps from the last three sampling events at the site (Attachment 2). Monitoring wells MW-3, MW-6, and MW-7 are down gradient from the proposed ORC treatment wells (MW-2 and MW-4). The 2003 groundwater elevations at MW-3, MW-6, and MW-7 are lower than those of MW-2 and MW-4. In June 2002, groundwater elevations were lower overall, reflecting regional drought conditions. During that time, groundwater elevations at MW-6 and MW-7 were lower than MW-2 and MW-4, while the groundwater elevation at MW-3 was similar to MW-2 and MW-4. Table 1 (Attachment 3) summarizes monitoring well depths, screening intervals, and historical groundwater elevation data. MW-3, MW-6, and MW-7 will be used to monitor the effects of oxygen injection at the site. 2. The topographic and tax maps in Attachment 4 were obtained from the Gaston County website (www.co.gaston.nc.us). The topographic map has a five-foot contour interval and the tax map illustrates the NSRC right of way which encompasses the site at 201 W. Virginia Avenue. In Attachment 5, MM&A has included a site map showing the approximate NSRC right of way property 8371 Melrose Drive / Lenexa, KS 66214 / Tel 913.648.4424 / Fax 913.648.4763 Web Site — http://www.mmal.com • E-mail — Ienexa@mmal.com ranch Offices in Bluefield, VA / Richmond, VA / Kingsport, TN / Charleston, WV / Morgantown, WV / Lexington, KY / Raleigh, NC / Harrisburgh, PA Mr. Michael Ranck NCDENR-DWQ October 28, 2004 Page 2 boundaries, November 2003 isoconcentration maps for all detected chemicals in groundwater, and cross sections for the site. Cross sections has been included showing the approximate vertical extent of the dissolved plume at the site. 3. The cross sections A -A' and B-B' in Attachment 5 illustrate the approximate depth of petroleum impacts at the site. Soil data have been provided, where available. Groundwater analytical data for the November 2003 sampling event have also been included on the cross sections. 4. Attachment 6 includes the drilling logs with well construction diagrams for all monitoring wells at the site. In addition, the well depth and screen intervals for each well are listed on Table 1 (Attachment 3). MM&A appreciates the opportunity to provide this additional information to your depai Intent. If you have any questions or comments, please call me at (913) 648-4424. Sincerely, M�IZSHALL MILLER & ASSOCIA' §1 INC. iste Suzfiiine E. Bailey, Branch Manager Enclosures cc: Forrest W. Stevenson, NSRC File NS1411 \► HALL\\LLE Attachment 1 NCDENR Letter — September 24, 2004 o' WA1 Q� RECEIVED OCT 0 4 1UU4 Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Alan W. Klimek, P.E. Director Division of Water Quality September 24, 2004 Mr. Forrest Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 Subject: Type 5I Injection Well Permit Application Virginia Avenue Auto & Wrecker Site, Bessemer City, NC Dear Mr. Stevenson: Norfolk Southern Railway Company's application for a permit to use wells for the injection of ORC® at the subject site is currently under review. Applications for injection must adhere to the North Carolina Administrative Code (NCAC), Title 15A, Subchapter 2C. In this regard, we have found your application incomplete. In order for our staff to complete their review of your permit application, please address the following issues: 1. Submit a revised monitoring procedure that includes a monitor well array downgradient from the injection locations in accordance with 15A NCAC 2C .0213(c)(2)(D). Injection wells (e.g. MW-2, MW-4) should not be used as monitor wells. 15A NCAC 2C .0213(c)(2)(D) requires that monitoring wells shall be located in such a fashion as to detect any movement of injection fluids, process by-products, or formation fluids outside the injection area or zone. 2. Submit a site map including all property boundaries, contour intervals not exceeding two feet, and the horizontal and vertical extent of the contaminant plume (including plume cross sections), in accordance with 15A NCAC 2C .0211(d)(1)(D) and (d)(3)(B). 3. Submit a cross section of the subsurface to a depth that includes the known or projected depth of contamination, as required by 15A NCAC 2C .0211(d)(3)(D). • 4. Submit plans for the proposed location and construction details of the groundwater monitoring well network, in accordance with 15A NCAC 2C .0211(d)(3)(G). N"os,�e Carolina ,Naturally Aquifer Protection Section Internet: http://h2o.enr.state.nc.us 1636 Mail Service Center Raleigh, NC 27699-1636 Phone (919) 733-3221 Customer Service 2728 Capital Boulevard Raleigh, NC 27604 Fax (919) 715-0588 1-877-623-6748 Fax (919) 715-6048 An Equal Opportunity/Affirmative Action Employer — 50% Recycled/10% Post Consumer Paper Mr. Forrest Stevenson September 24, 2004 Page 2 You are requested to submit this additional information within 30 days of receipt of this letter, otherwise your application will be returned. If you have any questions regarding this letter or your permit application, please contact Michael Ranck at (919) 715-6164. Sincerely, Debra J. Watts Supervisor Groundwater Protection Unit cc: Suzanne Bailey, Marshall Miller & Associates APS-Mooresville Regional Office UIC UIC Central Office File Attachment 2 Groundwater Potentiometric Maps MW-7 880.75 50' 881 yR-"A Alt STORM VIRGINIA AVENUE AUTO FIBER OPTIC CABLE RAILROAD BRIDGE 882 MW—B PENNSYLVANIA AVE. 880.05 0 50' 1"=50 NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. MW-1 883.39 885. 8 883.40� t' M ` —2 MW1 880.05 N 881.99 5 3 1 LEGEND MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON NOVEMBER 10, 2003 FIGURE 3 GROUND WATER CONTOUR MAP NOVEMBER 2003 NORFOLK SOUTHERN • 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1"=50' DESIGNED: SB DRAWN: BFW MW-1 876 LEGEND MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION 883.69 MW-7 VIRGINIA AVENUE AUTO G11y1A Alt MW-1 STORM SEWER 883.90 MW-2 8 86 .96 //FIBER OPTIC CABLE Nil\0q ch PENNSYLVANIA AVE. RAILROAD BRIDGE 882.42 40* MW-6 NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON MAY 14, 2003 5 884.26 *W 3 883.11 1 50' 0 50' 1"=50' FIGURE 3 SHOWING: GROUND WATER CONTOURS-05/03 BESSEMER CITY, NC Designed: Drawn: SB D Checked. SB Project Number. N51411 Date: JUL Y, 2003 Scale: = 50' File Name: F70-3. dwg Map Number. WELL # NORTHING EASTING GROUND ELEV. TOP OF CASING ELEV. W. L. 06/12/02 GW ELEV. MW-1 566543.66 1317774.06 895.49 894.72 17.41 877.31 MW-2 566541.05 1317790.01 894.77 894.30 17.63 876.67 MW-3 566513.84 1317811.44 894.07 893.84 17.39 876.45 MW-4 ' 566489.85 1317773.66 894.84 894.33 18.25 876.08 MW-5 5665432.72 1317810.50 894.49 894.18 17.29 876.89 MW-6 566349.02 1317710.90 893.58 893.26 19.76 873.50 MW-7 566359.57 1317639.10 896.02 895.81 DRY NA LEGEND • MONITORING WELL MW-1 876.00 GROUNDWATER CONTOUR CONTOUR INTERVAL = 1.0 FT. NA NOT APPLICABLE NA MW-7 875.00 874.00 t/RGINIA A VIRGINIA AVENUE AUT0877. 876.00 FIBER 0P11C CABLE RAILROAD BRIDGE 873.50 MW- PENNSYLVANIA AVE. NOTE: GROUNDWATER MEASUREMENTS COLLECTED ON JUNE 12, 2002 MW-1 877`31* • STORM SEWER 874.00 50 5 89 3 .45 875.00 0 877.p0 50 100 SCALE IN FEET Bu rns& McDon nell SIIICE 1898 Figure 2 GROUNDWATER POTENTIOMETRIC SURFACE MAP NORFOLK SOUTHERN RAILWAY COMPANY BESSEMER CITY, NC Attachment 3 Table SOCI: ES Ground Water Elevation and ca co co L 4E' .0 d E 0 • Z al d • V 2 `m E G7 Gf LL N N d m FIELD MEASUREMENT DATA �I ^i T bI QF.ZZZZZO Q d Q Q Q N N M .N. V OOO,.OzZZZZZOOOZ-.OZZZZZZCNOON Q Q Q Q Q N Q l-: ao d Q Q Q Q 7); O o�0 21 53 'Z OZZZZZZOOCON".z Q Q Q Q Q g M N M 8,1 Specific Conductivity (uS/cm) d Q d d Q 00 0 80 N 00 00 N ZZZZZ . V Q d d Q Q 0 00 O O 00 00 00 ZZZZZ.~-.,.,,.,. ,..ZZZZZNNN-. Q d 0 0 0 O N O vll O v l Coo). Q d Q Q Q P. F2 O -. l0 c. 7 ZZZZZr0oVC) Gq G QddQd�crChV1,.ch°r°ddddd,)oco ZZZZZvvvvvito; voZZZZZviv;v;vilcldo;ZZZzzv;vv;v;v,v;OZZZZZvvv;v;viv,rn VDv°O�oQ QdQdd��s�No�Qddddg�o00-00000 e y i EV ' Q d d d d vl N O vl b V Z Z Z Z Z O 0' s. 0' Q Q Q d Q N O O '7 rn W O Z Z Z Z Z- N N- N N _ Q d Z d M V 0\ 00 N W T ZZ Z Z Z ry O O ry vl N r" V 7 -• d Z d d Z Z Z Z Z oo O+ o0 00 h N -,-:• GROUND WATER ELEVATION DATA Groundwater Elevation (ft MSL) vl M .-. N O \0 O N .-. I, O T Q. -- -. V V ch N„ M M vl M 00 N N 00 N 6 vl 00 N- r- 0O 00 00 00 00 00 00 00 0 00 00 00 00 00 00 a0 00 00 00 00 00 00 00 00 00 00 en n CO VD 1, -• 7 O r- on O O r, M o l or, vl .. M 7 40 Q. 01 <t W 00 .. 00 -. lZ N N N N 00 0 00 00 00 00 00 00 00 00 00 00 00 00 co 00 00 00 00 00 00 00 00 00 co 00 `7 vl -. O V' M vl 00 vl .-+ -. CA Cl N N O V0 on O O1 V' 00 -. 0\ Do 00 -. 01 0. W �0 �0 �O N 00 00 00 00 00 00 00 00 00 00 00 00 00 00 co 00 00 W co 00 00 00 00 00 00 00 rn M O '7 .• 0\ .-. V0 00 -. V0 00 M .--. .-. d' T Ol 7 0\ co V cp N 00 .. -. lZ O up V �0 00 7 00 vl 00 00 00 00 00 00 00 00 00 00 00 00 co 00 co 00 co 00 00 00 OO 00 00 00 Depth to Water (ft TOC) r- 00 .-. co N b N co vl 00 l- vl V0 on rh N vl VD 47 '+l N onvl 00 N N 6 N l4 00 6 N 00 W .-. r- 00 N V 00 01 VD O 00 r- O O 01 0\ O1 V- -. 0\ CN VD en V' Ol vl N N vl N N 00 6 lz Ol O O O 01 00 V' O -. 00 \0 00 00 00 vl VDvl VD 0o N vl l- 00 on O l— co) V"i N N V N vl lZ b N 0; O -. CD O 00 00 Cl V' N N vl N O N N 00 7 M T of N 00 M O 6 rri r.l b 00 00 00 N 00 01 0\ Top of Casing Elevation (ft MSL) N N N N N N N N N N N N N N N N N N n N r V- N n 00 00 00 0 00 00 0 00 00 00 7 00 00 00 00 O\ 00 0l 0, 0l 00 00 00 00 00 00 00 00 00 00 00 00 00 00 00 CO O O O O O O O O O O O O M on r•1 en r+l rrl r+l r+l M M rrl M 00 00 00 00 00 00 R 00 00 V 00 00 0A COCr,01 00 00 0. 00 00 0Cr+0 ON 0l 00 00 00 00 00 00 W 00 00 00 00 00 00 V V' V '7 '7 '7 V' V' V <! '7 '7 00 00 00 00 00 00 00 00 00 00 00 00 M M 00 00 00 rri 00 00 00 00 rrl r.l 00 00 00 00 0A 00 0\ 01 00 00 00 01 00 00 00 00 00 00 00 00 00 00 Oo oo 00 rrl 00 r+l rn 00 rn rrl 00 00 00 00 en on on on r+l rn M rn r.'1 rrl M on 00 00 00 0 00 00 00 00 00 00 V V 00 O, CNN 0A 0l 01 0\ 0\ 00 0l 01 0A 00 oo 00 oo oo 0000 00 00 CO 00 oo Ground Surface Elevation (ft MSL) 01 ON 0\ O. ON CI 0l 00 00 00 00 Ch V V V V V V '7 '7 '7 7 7 7 vl vl vl vh v00 l vl vl l Cr,00 00 0l 01 0l 0l 00 00 00 0001 01 00Ol 00 00 00 00 00 0o ao co 00 00 00 CO r, c- N F- N N- N N N N S [., N N N n n r N N r N N v Ni 00 Ni Ni v Ni 00 00 00 00 00 01 0i 0` 00 00 00 00 00 0 00 00 00 CO 00 00 CO 00 00 00 0o 00 00 00 00 r- N 0 N t 0- N N N r- r- o o O O O O O O O o 0 0 v 00 00 00 Ni 00 00 00 00 00 00 v 00000001 00COCO00 00 01 0000 00 00 00 00 00 00 00 00 00 00 00 00 v v v v v v v v v v v v 00 00 00 CO 00 00 00 00 CO 00 00 00 00 00 v 00 Ni 00 00 00 00 00 004 00 00Cl 0000 CO00 00 00 00 0001 00 00 CO 00 00 00 00 00 00 00 00 00 Date Measured 00 C. O O N N N 00 00 CA-.„ 0 0 0 0 0 0 0 0 0 0 0 N b 00 Yr R N 00 V' N VO 7 O C^ ". -. O rl N O -. r, .. .. N 00 00 00 'V' 00 .-. 00 00 00 -.\N. .-. O O O O O .. O O -. O ". 0\ O O O N N N 00 00 0, O CO O O O O O O O O O n l0 00 Yr Y7 N Cl R N VD V O O .-. -. O N N O -. N o... 00 00 00 R 00 -. 00 VD .. Vl ". O O O O O -. O O .. O -. 00 0 0 0 N N N 00 00 rT 0 0 0 0 0 0 0 0 CO O O t- b 00 7 'V N 00 V' N l0 V O O .., ". -. O N N O .-. r4.... � 00 00 00 V 00 .-. 00 00 -. Vl .--. O O O O O .-. O O -. O -. ON O 0 0 -+ -. -. N N Cl 00 rrl 0, O O O O O O Co O O O O N b 00 V R N T C N l0 -,. O O ,. -. -. O N N O -. N � 00 00 00 '7 00 -- it l0 .. 0 .. O O O O O .. O O -• o -• Screened Interval (ft bgs) Un N O V N O vl b N h N O Total Depth (ft bgs) vl N vl N 41 In 00 N Monitoring Well Number 2 00 Table 1 Ground Water Elevation and Field Measurement Data Bessemer City, North Carolina GROUND WATER ELEVATION DATA FIELD MEASUREMENT DATA Monitoring Total Screened Ground Top of Depth Groundwater Specific Dissolved Well Number Depth Interval Date Surface Casing to Water Elevation Temperature p13 Conductivity Oxygen (ft bgs) (ft bgs) Measured Elevation (ft MSL) Elevation (ft MSL) (ft TOC) (ft MSL) (°Celsius) (uS/cm) (mg/1) MW-5 25 10-25 12/07/99 894.49 894.18 15.09 879.09 NA NA NA NA 03/16/00 894.49 894.18 12.50 881.68 NA NA NA NA 03/18/00 894.49 894.18 12.52 881.66 NA NA NA NA 09/14/00 894.49 894.18 14.89 879.29 NA NA NA NA 04/04/01 894.49 894.18 12.18 882.00 NA NA NA NA 08/22/01 894.49 894.18 16.08 878.10 20.1 4.26 1430 0.20 11/29/01 894.49 894.18 17.86 876.32 21.0 4.20 1510 0.77 03/04/02 894.49 894.18 16.33 877.85 20.6 4.67 1270 0.37 06/12/02 894.49 - 894.18 17.29 876.89 20.0 4.53 237* 0.34 11/26/02 894.49 894.18 18.66 875.52 17.9 5.28 1350 1.68 05/14/03 894.49 894.18 9.92 884.26 24.4 5.86 1770 1.3 11/10/03 894.49 894.18 12.25 881.93 19.4 9.91 1580 NM MW-6 20.8 5-20 12/07/99 893.58 893.26 NA NA NA NA NA NA 03/16/00 893.58 893.26 NA NA NA NA NA NA 03/18/00 893.58 893.26 NA NA NA NA NA NA 09/14/00 893.58 893.26 NA NA NA NA NA NA 04/04/01 893.58 893.26 15.45 877.81 NA NA NA NA 08/22/01 893.58 893.26 19.73 873.53 13.7 NA NA 2.74 11/29/01 893.58 893.26 19.81 873.45 NA NA NA NA 03/04/02 893.58 893.26 19.08 874.18 17.3 4.54 1520 4.90 06/12/02 893.58 893.26 19.76 873.50 NA NA NA NA 11/26/02 893.58 893.26 Dry <873.48 NA NA NA NA 05/14/03 893.58 893.26 10.84 882.42 18.4 5.54 1850 11.6 11/10/03 893.58 893.26 13.21 880.05 16.7 6.31 1910 NM MW-7 20.3 5-20 12/07/99 896.02 895.81 NA NA zzzzz:zzzz� d d d d d d d d d d V zzzzzzzzzzvi,g5 NA NA 03/16/00 896.02 895.81 NA NA NA NA 03/18/00 896.02 895.81 NA NA NA NA 09/14/00 896.02 895.81 NA NA NA NA 04/04/01 896.02 895.81 18.40 877.41 NA NA 08/22/01 896.02 895.81 19.80 876.01 NA 5.23 11/29/01 896.02 895.81 Dry NA NA NA 03/04/02 896.02 895.81 Dry NA NA NA 06/12/02 896.02 895.81 Dry NA NA NA 11/26/02 896.02 895.81 Dry <875.90 NA NA 05/14/03 896.02 895.81 12.12 883.69 1420 10.9 11/10/03 896.02 895.81 15.06 880.75 1310 NM Notes: Elevations are in reference to feet above mean sea level (MSL). bgs - below ground surface ft - Feet TOC - Top of casing uS/cm - Micro-siemen per centimeter NA - Not Available mg I - Milligrams per liter • - Units are in micro -ohms per centimeter NM- Not Measured Table 1 Page 2 of 2 Attachment 4 Topographic and Tax Maps • SOCI • ES Map Output Page 1 of 1 201 W. Virginia Avenue 4, !" Legend Major Roads AtioupSpcx3d35m I Aweritp Spejed45sndi Aserxp Cwvrl 55 CH41 Roads 'Parcel Lines Topo Annotation Easements Paws Raid Tdgiticettl Stricture Footprints ADDITION ®UUSSTLYG G NE YEW Qll T)ONAALE Lases, Streams Edge Tope (Contour Lines 5° Intenrai) Lidr.Cai .xr!1Y] of corky Lin, f./ STATE_tine Disclaimer: The information provided is not to be considered as a Legal Document or Description. The Map and Parcel Data is believed to be accurate, but Gaston County does not guarantee the accuracy of this information. http://public gis.co.gaston.nc.us/website/ParcelDataSite/MapFrame.htm 10/19/2004 Map Output Page 1 of 1 Print Scale 1:16096 or 1" = 1258' 201 W. Virginia Avenue :t�; . .,, $'.Ei 1't� teaall' _''•'► . PIP .- g' ila rAli‘F, AAMAS# Q.#,.f I1FslP,e'4i, l7kir t- W, k''' # R 1 11 11 j. i k III. # # 2 Lr:l19, ' „^--���A a FbiiItr -; # -, * w Legend Major.Roads `/ hMa9?ob135edl A9xsaga S .u145 mCta h.Sraed5ni0 Parboi Lines /1 STATE Erne .i 4, OrAi.i ¢ ,,, �; �p�r �1Vl�`�[iu_j:d4V __., d` C,. .L4.t' l �, _,: ; 111#' J Ogij Vk. 4,, '� YR it Rtti *. * }it...}r ; ffl#I# rMr* it + L ;'* * * E.[1,i �4y8 - - # � NA **#+r r.ilv ` ' USW 41111iP 42 At i'lLtQL;(1-D Yi_lit C.) r� 1 ¢, r # ail I+ ..1, i r ,--0. JON 4 f ; 4V4g ' ifr 1%''-: Mfg - -'11 .D9 aleIlk PA ' 1/4,,, ...,,,,, _. i. stay 14 so lier tog. isionryi+ MA- " - Aril $. iv Air +a` TE +ire) •'a A illgiela :lari County, INC��t , V OP witife,--t-Nre.,,,,, a. 411, "_F Sri moo Arilibr -2-II!" "Ilan" .�4V5 * 104 at lints a " v 1-1 iir { ill , i yr AlIO'' ki11 mite* Disclaimer: The information provided is not to be considered as a Legal Document or Description. The Map and Parcel Data is believed to be accurate, but Gaston County does not guarantee the accuracy of this information. http://publicgis. co.gaston.nc.us/website/ParcelDataSite/MapFrame.htm 10/25/2004 Attachment 5 Site Map, Cross Sections, and Isoconcentration Maps MW-7 VIRGINIA AVENUE AUTO FIBER OPTIC CABLE PENNSYLVANIA AVE. A RAILROAD BRIDGE 50' 0 50' = 50' yRGll ylq STORM SEWER -1 5 3 LEGEND MW-1 W MONITORING WELL I I I I I I I RAILROAD TRACKS NOTE: The location and dimensions of features shown on this map have A A' CROSS SECTION LINE been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. 0 — RAILROAD RIGHT-OF-WAY PROPERTY BOUNDARY (APPROXIMATE) FIGURE 2 SITE MAP MySNORFOLK SOUTHERN 0 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1' = 50' DESIGNED: SB DRAWN: BFW NS1411.dwg � a SOUTH MW-6 CLAY - ALL GROUND WATER RESULTS FOR MW-6 WERE NON -DETECTABLE 11-10-03 1 -SS-1 - SS-2 • SS-3 TD=20.8 FT. NOTE: The location and dimensions of features shown on this map have been derived from venous sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. Source map and date 20 10 0 APPROXIMATE WATER TABLE 11-10-03 PROFILE SCALE HORIZONTAL 1 "=20' VERTICAL 1"=10' VERTICAL EXAGGERATION 2X RAILROAD EMBANKMENT. MW-2 11/10/03 GROUND WATER RESULTS BENZENE 12000 TOLUENE 36000 ETHYLBENZENE 2700 XYLENES 17000 NAPHTHALENE 950 2-METHYLNAPHTHALENE 180 APPROXIMATE GROUND SURFACE MW-4 11/10/03 GROUND WATER RESULTS BENZENE 2200 TOLUENE 24000 ETHYLBENZENE 1800 XYLENES 11000 NAPHTHALENE 370 2- METHYLENAPHTHALEN E 59 20 40 CLAYEY SAND SANDY CLAY DISSOLVED IMPACTS ( CLAYEY SAND - ABOVE NCDENR GROUND WATER STANDARDS (APPROXIMATE) �---� (SANDY CLAY LH,'GH,WD SCREEN MW-4 1 NORTH MW-5 11/10/03 GROUND WATER RESULTS BENZENE 260 TOLUENE 5500 ETHYLBENZENE 1500 XYLENES 8400 NAPHTHALENE 380 2-METHYLNAPHTHALENE 62 ASPHALT PAVEMENT MW-2 .MW-5 -- = EXCAVATION CLAY - 3SS-1 - - _ -SS-2 CLAYEY -SS-3 FILL - CLAY , SAND - _ - 1 - _ 1 _ , - ' - - -} - SS-4 SANDY CLAY - SS 5 / I TD=25 0 FT., TD WELL=25.0 FT.- _ --TD=25.0 FT, L GROUND WATER ELEVATION (FT. MSL) 11-10-03 1.) BOLD VALUES EXCEED NCDENR SOIL -TO -GROUND WATER MCLs OR GROUND WATER STANDARDS. 2.) SOIL DATA IN MILLIGRAMS PER KILOGRAM (MG/KG). 3.) GROUND WATER DATA IN MICROGRAMS PER LITER (uG/L) TD SOIL BORING=27.0 FT. MW-2 SOIL RESULTS SS-1 SS-2 SS-3 SS-4 SS-5 5-7 10-12 15-17 20-22 25-27 NAPHTHALENE 18.62 105.1 403.9 34.35 30.49 N-PROPYLBENZENE 13.77 70.15 232.2 23.38 20.62 1,2,4-TRIMETHYLBENZENE 109.4 764.7 586.E 235.1 213.9 1,3,5-TRIMETHYLBENZENE 31.67 219.1 536.2 52.99 47.08 XYLENES 213.9 1,482 3,934 420.1 336.1 BENZENE 1.812 25.29 63.16 9.545 4.028 ETHYLBENZENE 37.97 251.5 710.5 75.32 59.51 ISOPROPYLBENZENE 2464 13.75 44.74 4.935 4.167 STYRENE 3.623 24.49 67.11 6.039 4.722 TOLUENE 82.61 565.4 530.3 187.0 121.5 4-ISOPROPYLTOLUENE ND 5.294 17.11 5.13 1.597 VPH C5-C8 ALIPHATICS 29.6 7,500 6,360 1,870 238 VPH C9-C12ALIPHATICS 16.5 3,530 3,080 1,350 135 VPH C9-C10 AROMATICS 19.3 3,530 2,950 1,640 179 ❑❑ Y ; 5 �{g ❑ ❑ xg t A d PROJECT NO.: N51411 F. 2 z a.. • ¢ • z J aw¢ U a� ¢rr u-zO zz USE F? U O�w `1J N W O W 0 C° z CROSS -SECTIONAL VIEW A -A' EAST MW-3 zw - J W CC CO 0_ MW-2 ASPHALT PAVEMENT WEST MW-1 APPROXIMATE GROUND SURFACE L _ ICLAY- \ 1' / / / / / / / / / / / / / / / / / / / / TD=31.5 FT. UST EXCAVATION SURFACE CASIN CLAY ]- SS-1 I SS-2 UST EXCAVATION L APPROXIMATE WATER TABLE 11-10-03 SS-3 SS-4 - SS-5 TD WELL=25.0 FT. / TD SOIL BORING=27.0 FT. MW-3 11/10/03 GROUND WATER RESULTS BENZENE TOLUENE ETHYLBENZENE XYLENES NAPHTHALENE 1400 18000 1800 10000: 390 `t%%tI ei1gt���,r •,,,,to NOTE: The location and dimensions of features shown on this mop hove been derived from various sources and supplemented by field measurements. Though sufficient for Its Intended purpose, no claim is made as to the degree of accuracy of this drawing. Source map and date 2 1 0 PROFILE SCALE HORIZONTAL 1"=10' VERTICAL 1"=10' 10 20 DISSOLVED IMPACTS ABOVE NCDENR GROUND WATER STANDARDS (APPROXIMATE) CLAY - SS-1 • SS-2 ss-3 - - - TD WELL=25.0 FT.�SS 4 SSS -SS.6' TD SOIL BOR NG=42.0 FT LEGEND SCREEN s GROUND WATER ELEVATION (FT. MSL) 11-10-03 1.) BOLD VALUES EXCEED NCDENR SOIL -TO -GROUND WATER MCLs OR GROUND WATER STANDARDS. 2.) SOIL DATA IN MILLIGRAMS PER KILOGRAM (MG/KG). 3.) GROUND WATER DATA IN MICROGRAMS PER LITER (uG/L) MW-1 11/10/03 GROUND WATER RESULTS ETHYLBENZENE XYLENES NAPHTHALENE 2-METHYLNAPHTHALENE 35 600 38 22 MW-2 11/10/03 GROUND WATER RESULTS BENZENE 12000 TOLUENE 36000 ETHYLBENZENE 2700 XYLENES 17000 NAPHTHALENE 950 2-METHYL NAPHTHALENE 180 MW-1 SOIL RESULTS SS-1 10-12 SS-2 15-17 SS-3 20-22 SS-4 20-22 SS-5 25-27 SS-6 40-42 NAPHTHALENE .0062 .3732 .0176 ND .0038 zzzzzzzzz 000000000 N-PROPYLBENZENE ND .5070 ND ND ND 1,2,4-TRIMETHYLENZENE ND 4.246 .1085 .0168 .0414 1,3,5-TRIMETHYLBENZENE ND 1:444 .0331 .0046 .0095 XYLENES ND 1.937 .0324 ND .0135 VPH C5-C8 ALIPHATICS ND 62.3 9.80 7.31 8.23 VPH C9-C12ALIPHATICS ND 11.6 ND ND ND VPH C9-C10 AROMATICS ND 11.4 ND ND ND EPH C9-C18 ALI PHATICS ND 29.0 ND ND ND SS-1 SS-2 SS-3 SS-4 SS-5 MW-2 SOIL RESULTS 5-7 10-12 15-17 20-22 25-27 NAPHTHALENE 18.62 105.11 403.9 34.35 30.49 N-PROPYLBENZENE 13.77 70.15 232.2 23.38 20.62 1, 2,4-TR I M ETHYLBENZEN E 109.4 764.7 586.8 235.1 213.9 1,3,5-TRIMETHYLBENZENE 31.67 219.1 536.2 52.99 47.08 XYLENES 213.9 1,482 3,934 420.1 336.1 BENZENE 1.812 25.29 63.16 9.545 4.028 ETHYLBENZENE 37.97 251.5 710.5 75.32 59.51 ISOPROPLYBENZENE 2.464 13.75 44.74 4.935 4.167 STYRENE 3.623 24.49 67.11 6.039 4.722 TOLUENE 82.61 565.4 530.3 187 121.5 4-ISOPROPYLTOLUENE ND 5.294 17.11 5,13 1.597 VPH C5-C8 ALIPHATICS 29.6 7,500 6,360 1,870 238 VPH C9-C12 ALIPHATICS 16.5 3,530 3,080 1,350 135 VPH C9-C10 AROMATICS 19.3 3,630 2,950 1,640 , 179 d z a a z >- ct 0-- z 2 z O 0 U W cc < w O a1- cc z z aim �� > U ,_ to 2 Y N cnu JJo w Ix CO 0 z CROSS -SECTIONAL VIEW B-B' •~ Ayr: STORM MW-1 VIRGINIA ND AVENUE 26 AUTO 4 FIBER OPTIC C LE RAILRO BRIDGE MW-6 PENNSYLVANIA AVE ND NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. FIGURE 4 BENZENE IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003 LEGEND MONITORING WELL ND NOT DETECTED —1,000 — BENZENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR BENZENE=1 ug/L NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CRY, NC DATE: JAN.2004 SCALE 1' = 50' DESIGNED: BB DRAWN: BFW yRGfNfA A it STORM MW-1 VIRGINIA ND AVENUE AUTO FIBER OPTIC CAB RAILROAD BRIDGE PENNSYLVANIA AVE. NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its Intended purpose, no claim is made as to the degree of accuracy of this drawing. FIGURE 5 TOLUENE IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003 LEGEND MVW1 MONITORING WELL ND NOT DETECTED -1,000 - TOLUENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (Ng/L) 3: NCDENR GROUND WATER STANDARD FOR TOLUENE=1,000 pg/L NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE 1' = 50' DESIGNED: SB DRAWN: BFW • MW-7 ND 50' VIRGINIA AVENUE AUTO FIBER OPTIC C RAILROAD BRIDGE MW-6 PENNSYLVANIA AVE ND 0 50' 1°=sa �RG/N1 NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. A A� STORM MW-1 5 3 LEGEND MONITORING WELL ND NOT DETECTED —1,000— ETHYLBENZENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR ETHYLBENZENE=29 Jg/L FIGURE 6 ETHYLBENZENE IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1" = 50' DESIGNED: SB DRAWN: BFW VIRGINIA AVENUE AUTO MW-7 ND MW-6 PENNSYLVANIA AVE. ND 50' 0 50' 1"= 50' NOTE The location and dimensions of features shown on this nap have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. LEGEND MW-1 MONITORING WELL ND NOT DETECTED —5,000— XYLENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) 3: NCDENR GROUND WATER STANDARD FOR XYLENES=530 pg/L FIGURE 7 XYLIENE IN GROUND WATER ISO CONCENTRATION MAP NOVEMBER 2003 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1" = 50' DESIGNED: SB DRAWN: BFW MW-7 ND _ ` 46'C1NlA A►t: STORM �/SEWER VIRGINIA AVENUE AUTO FIBER OPTIC CA RAILROAD BRIDGE MW-6 PENNSYLVANIA AVE ND 50' 0 50' 1"=50 NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. MW1 LEGEND MONITORING WELL ND NOT DETECTED -500 NAPHTHALENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (Ng/L) 3: NCDENR GROUND WATER STANDARD FOR NAPHTHALENE=21 Ng/L FIGURE 8 NAPHTHALENE IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003 NORFOLIC SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN.2004 SCALE 1"=50' DESIGNED: SB DRAWN: BFW Attachment 6 Well Drilling Logs and Construction Diagrams ►►E ' ►► ��; SOCI; ES Drilling Lo Protect Name Nogfclit Protect Number q5?-S?0-y-aoy-ol Boring Number' r1 t- - / Ground Elevation Location 0'0) Iv. 1/I �u.; A A v e $�5.-'M P/ C;// Pape / o f 1/ Air Monitoring Equipment p Total Footage , , _ Drilling Type Hole Size Overburden Footage Bedrock Footage No. 0f Samples No. 0f Core Boxes h1-5.4 /0,51/ a,o A/g- //4 Drilling Company ?lcAbL R(p71.1,,e(s 271,6 . 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Potential pollution source Potential pollution source COPY Pat Y/'(t'r L%: nco (J L4:Id/✓ North Carolina Department of Environment and Natural Resources Division of Water Quality Aquifer Protection Section PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT -FORM A INJECTION WELL PERMIT NO. WI DATE NAME OF OWNER Nor' / l Sot4erg'► ,1i1/14+ Cn ADDRESS OF OWNER fj l 101 /^fran/ J4i Il d f St"; j Yox I on h o l VA z 9-04Z — nO /3 )4751/ /t'1Y, For/ eS7- Sfe✓enson (Street/ road or lot and subdivision, county, town) Zp —O(f-- LOCATION OF PROPOSED INJECTION'�^,/WELLJ(and source fwell(s), if applicable) /Ll®ri,fait ,lri9 �e/k /114 —� 6aA Ar t � , /h l^Oh�7 LU1/diYi/ lJit s: e. o1• Gro v, B si 13 f�, S�r>°e✓ (Street/ road or lot and subdivision , county, town, if different than owner's address, plus description of location on site) /t1po:7or,^), Lie/ Distance from well (' /'L w - z Distance from well Potential pollution source Distance from well Minimum distance of proposed wellfrom property boundary Quality of drainage at site a060/ Flooding potential of site 2d1-1/ (good,adequate,poor) (high,moderate,low) DRAW SKETCH OF SITE (Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow.) /11q/5 CC: /t -/Ps f,hles e. GW/UIC-1 July 28, 2.004 Page 2 of 2 PRECONSTRUCTION INJECTION FACILITY INSPECTION REPORT - FORM A (cont.) GPS Data: 3S17/ Z' d'gl�17�10 7r Latitude: D% `T� At Longitude: a S� 2SS �/t/ COMMENTS J � e RP fr o,100SS eo4,re D/ C soc in?- �n /41„1//7z6r/no i/e A 7c e i7 P Lt/c l�1BA/ °/H9 r/ v7 Y�L�AY e J/ /Urvr P 7 , ��� ✓Pr �1 F_ ‘-e-///Stoke d CO /fie► %— re.v,gin Sn 7fie+7L / e 1i1S7 J/ Sec7�i, <a�(A 5� oT c0 Sqs / z'/c°Aie w P/15--;Ar. t e. Lncssiit s are lewQroattvrr��. 74 7i�2 INSPECTOR /311ic c r ArfAr `— Office R.O WITNESS Address WITNESS Address GW/UIC-1 July 28, 2004 Norfolk Southern UIC - Bessemer City From USGS 1993 Bessemer City Topographic Map til•l! 0 162.5 325 650 Feet Norfolk Southern UIC -Bessemer City From 1998 DOQQ 0 95 190 380 Feet :MapQuest: Maps: print El Send To Printer Back to Map 201 W Virginia Ave Bessemer City NC 28016-2374 US - Notes: W91f9 4ve rf Of 4-1 U• _Floride A{ ye:. `---i JAW y6• (.. extg r �.-- . i `fcv 0 300si 900td ; r� `Bog:CO d .�2004:Mlap[luestco'm;'tn ;;.0-2004'_NAVTEQ` All rights reserved. Use Subiect to License/Copyright 1 Map Legend NYIVTEO OWN E.oFto This map is informational only. No representation is made or warranty given as to its content. User assumes all risk of use: MapQuest and its suppliersassume no responsibility for any loss or delay resulting from such use. Privacy Policy & Legal Notices © 2004 MapQuest.com, Inc: All rights reserved. http://www.mapquest. com/maps/print.adp?mapdata=Qg5DZU1XQC9Aw2 WzkwMzbigUU... 9/16/2004 NW-7 880.75 881 VIRGINIA AVENUE AUTO MW-6 PENNSYLVANIA AVE 88"5 0 sa 1"=5Q . NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. LEGEND M1 MONITORING WELL 880.05 GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON NOVEMBER 10, 2003 FIGURE 3 GROUND WATER CONTOUR MAP NOVEMBER 2003 NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE JAN. 2004 SCALE. 1' = 50' DESIGNED: SB DRAWN: BFW PfC�JB�� ►►• ►► NS1411.dwg . • •• 4- MW-7 ND 50 C4 -- AtZ STORM VIRGINIA . AVENUE, AUTO FIBER RAILRO BRIDGE MW-6 PENNSYLVANIA AVE ND , 0 50' LEG -END MONITORING WELL ND NOT DETECTED —1,000 — BENZENE ISOCONCENTRATION CONTOUR • NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (pg/L) • NOTE The location and dimensions of features shown on this map have . . been derived from various sources and supplemented by field . • • measurements. Though sufficient fof its intended purccee, no - 3: . NCDENR GROUND WATER STANDARD FOR BENZENE=1 ug/L claim is made as to the degree of accuracy of this drawing • , - . , FIGURE 4 BENZENE:IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003- • NOsornFOHleRN • 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE 1" = 50' DESIGNE):- S8 DRAWN:- BFW Pmpared by: i:iJ NS1411.thira Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Alan W. Klimek, P.E. Director Division of Water Quality September 24, 2004 Mr. Forrest Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 REC•EIVF[)zz 3EP 2 9 2004` NO DE r"1151Wit:MdiENT r� AND NATURAL klt:..-Oct �. l. M'OORE:S Y ll-S:le REGIONAL OFF CE Subject: Type 5I Injection Well Permit Application Virginia Avenue Auto & Wrecker Site, Bessemer City, NC Dear Mr. Stevenson: Norfolk Southern Railway Company's application for a permit to use wells for the injection of ORC® at the subject site is currently under review. Applications for injection must adhere to the North Carolina Administrative Code (NCAC), Title 15A, Subchapter 2C. In this regard, we have found your application incomplete. In order for our staff to complete their review of your permit application, please address the following issues: 1. Submit a revised monitoring procedure that includes a monitor well array downgradient from the injection locations in accordance with 15A NCAC 2C .0213(c)(2)(D). Injection wells (e.g. MW-2, MW-4) should not be used as monitor wells. 15A NCAC 2C .0213(c)(2)(D) requires that monitoring wells shall be located in such a fashion as to detect any movement of injection fluids, process by-products, or formation fluids outside the injection area or zone. 2. Submit a site map including all property boundaries, contour intervals not exceeding two feet, and the horizontal and vertical extent of the contaminant plume (including plume cross sections), in accordance with 15A NCAC 2C .0211(d)(1)(D) and (d)(3)(B). 3. Submit a cross section of the subsurface to a depth that includes the known or projected depth of contamination, as required by 15A NCAC 2C .0211(d)(3)(D). 4. Submit plans for the proposed location and construction details of the groundwater monitoring well network, in accordance with 15A NCAC 2C .0211(d)(3)(G). Aquifer Protection Section Internet: http://h2o.enr.state.nc.us f r Caro ina ,Naturally 1636 Mail Service Center Raleigh, NC 27699-1636 Phone (919) 733-3221 Customer Service 2728 Capital Boulevard Raleigh, NC 27604 Fax (919) 715-0588 1-877-623-6748 Fax (919)715-6048 An Equal Opportunity/Affirmative Action Employer — 50% Recycled/10% Post Consumer Paper Mr. Forrest Stevenson September 24, 2004 Page 2 You are requested to submit this additional information within 30 days of receipt of this letter, otherwise your application will be returned. If you have any questions regarding this letter or your permit application, please contact Michael Ranck at (919) 715-6164. Sincerely, E a . Debra J. Watts Supervisor Groundwater Protection Unit cc: Suzanne Bailey, Marshall Miller & Associates TAPS -Mooresville Region-alO ffice_UIC) UIC Central Office File DIVISION OF WATER QUALITY AQUIFER PROTECTION SECTION August 26, 2004 MEMORANDUM _ _ Aridrew Pitney, Aquifer Protection Supervisor Aquifer Protection Section Mooresville Regional Office From: Mike Ranck Central Office NC DEPT. OF ENVIRONMENT AND NATURAL RESOURCES RECEIVED -AUG 3 I= 2004- IOORESVILLE'REGIONAL OFFICE DWQ-GROUNDWATER SECTION Re: Request for review of an injection well application, type 5I injection well (groundwater remediation), submitted by Norfolk Southern Railway Company, to construct and use injection wells for injection of ORC® socks to remediate dissolved petroleum hydrocarbons at their site in Bessemer City, North Carolina. 1. Please review the application and submit any comments to CO-UIC group. Retain the application for your UIC file. 2. Please inspect the injection well site to verify that the location and construction plans submitted in the application are accurate and that the NCAC Title 15A 2C.0200 standards are being complied with, using the enclosed Preconstruction Injection Facility Inspection Report (Form A) as appropriate. You are requested to return The Review Comments and the completed Preconstruction Injection Facility Inspection Report (Form A) to the CO-UIC by September 27, 2004. If the inspection and review cannot be accomplished by this date, please let me know. The UIC group appreciates your assistance with this review. If you have any questions regarding this review or the UIC program, please contact me at (919) 715-6164. cc: CO-UIC Files Enclosures oc.WA T9 Michael F. Easley, Governor Q William G. Ross Jr., Secretary \O. QG North Carolina Department of Environment and Natural Resources Cq r Alan W. Klimek, P. E. Director j —i Division of Water Quality 0 Coleen H. Sullins, Deputy Director Division of Water Quality August 26, 2004 Mr. Forrest Stevenson Norfolk Southern Railway Company 110 Franklin Road, SE, Box 13 Roanoke, VA 24042-0013 Subject: Type 5I injection well permit application Virginia Avenue Auto & Wrecker Site, Bessemer City, NC Dear Mr. Stevenson: Norfolk Southern Railway Company's application for a permit to construct and use wells for injection of ORC® socks at.the subject site in Bessemer City, North Carolina has been received and is currently under review. A member of the Groundwater Section's Mooresville Regional Office staff will be contacting you to arrange an inspection of the injection well site as part of the review. If you have any questions regarding your permit application or the Underground Injection Control program please contact me at (919) 715-6164 or Evan Kane at (919) 715-6182. Sincerely, / laud .//6"eit J. Michael Ranck Hydrogeologist Groundwater Protection Unit cc: Andr ew Pitner,:Mooresville-R egional"Office' CO-UIC files Suzanne Bailey, Marshall Miller & Associates N. C. Division of Water Quality / Aquifer Protection Section 1636 Mail Service Center Raleigh, N.C. 27699-1636 Phone: (919) 733-3221 Fax: (919) 715-0588 Internet: http://gw.ehnr.state.nc.us Customer Service 1-877-623-6748 Norfolk Southern File No. 1-9-NC-BSMR-UT98.133-002 CERTIFICATION " I hereby certify, under penalty of law, that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the approved specifications and conditions of the Permit." 90sitabl W Forrest W. Stevenson Engineer Environmental Remediation Norfolk Southern Railway Company (Signature of Well Owner or Authorized Agent) APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION, Class 5I Wells This permit application was generated in accordance with the provisions of NCAC Title 15A: 02C.0200. The following sections provide a detailed description of all planned activities relating to the proposed placement of Regenesis brand Oxygen Release Compound® (ORC®) socks into two existing monitoring wells to aid with biodegradation of petroleum hydrocarbons. kt illA. PERMIT APPLICANT /'V\ Y rS Norfolk Southern Railway Company C �'. ��°�� 110 Franklin Road, SE, Box 13 �`��7 1 '1A Roanoke, Virginia 24042-0013 Contact: Mr. Forrest W. Stevenson, Engineer Environmental Remediation da'�S �e r6d4 Contact Phone: 540-981-4236 1- /4V,1 rygle B. PROPERTY OWNER Norfolk Southern Railway Company 110 Franklin Road, S.E., Box 13 Roanoke, Virginia 24042-0013 Contact: Mr. Forrest W. Stevenson, Engineer Environmental Remediation Contact Phone: 540-981-4236 C. STATUS OF APPLICANT yi A Ics • vim r 1U.r ;2$ ii-elgi zp, W. Norfolk Southern Railway Company (NSRC) is a private transportation organization. D. FACILITY (SITE) DATA Virginia Avenue Auto & Wrecker 201 W. Virginia Ave. Bessemer City, North Carolina ►►' ' ,, •4 Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 2 of 12 Gaston, County Contact: Mr. Forrest W. Stevenson (NSRC) The Site location is shown on an excerpt from the United States Geological Survey (USGS) 7.5- minute series Bessemer City topographic quadrangle (Figure 1). E. INJECTION PROCEDURE Provide a detailed description of all planned activities relating to the proposed injection facility including but not limited to: 1. construction plans and materials; 2. operation procedures; and 3. a planned injection schedule The proposed underground injection consists of installing Regenesis brand ORC socks in existing monitoring wells MW-2 and MW-4 and conducting semi-annual ground water monitoring for two years. MW-2 and MW-4 were selected for treatment because of the presence of gasoline range petroleum hydrocarbons in ground water at concentrations that exceed the North Carolina ground water standards. ORC® socks contain a proprietary solid form of magnesium peroxide that, when placed in a well, react with the ground water to promote the timed release of molecular oxygen to the aquifer. The release of additional molecular oxygen aids the aerobic degradation of dissolved petroleum hydrocarbons in ground water. Once the ORC® socks are installed, they must remain undisturbed in the wells for at least six months to promote affective treatment. A copy of ORC® information and installation procedures is provided as Appendix A. The ORC® sock installation could occur during the next semi-annual sampling event (currently scheduled for November 2004). During the May 2005 sampling event, the ORC® socks would be removed, the wells sampled, and new ORC® socks would be placed in the wells. In total, three sets of ORC® socks will be installed over the two-year semi-annual sampling schedule. At the end of the two year monitoring schedule, future actions for the Site will be evaluated. Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 3 of 12 According to Mr. Brad Newton of the North Carolina Department of Environment and Natural Resource (NCDENR), if benzene levels can be brought below the NCAC 15A 2L GCL standards (5000 µg/L) in ground water, the Site may be considered for closure. F. DESCRIPTION OF SITE The Site has been assigned Pollution Incident No. 19216 by NCDENR. Five gasoline underground storage tanks (USTs) and one kerosene UST were located at the Site, but were removed in September 1998 and January 1999 by Earth Tech, Inc. (Earth Tech). Earth Tech removed approximately 277 tons of petroleum hydrocarbon impacted soil associated with the USTs. The excavation pits were backfilled with clean material. Between 1999 and 2001, seven monitoring wells were installed to evaluate ground water impacts. The ground water typically flows to the southwest (Figure 3). Volatile organic compounds (VOCs) present in the ground water include benzene, toluene, ethylbenzene, total xylenes (BTEX), and naphthalene. Currently, benzene is the most prevalent. Figure 4 shows the benzene isoconcentration contours at the Site. A Comprehensive Site Assessment (CSA) was completed by Burns & McDonnell Consultants, Inc. (Burns & McDonnell) and submitted in May 2000. A Corrective Action Plan (CAP), completed by Burns & McDonnell, was submitted in October 2000, which recommended monitored natural attenuation as the most cost effective treatment option. Prior to approving the CAP, NCDENR requested the installation of two monitoring wells (MW-6 and MW-7) south of the railroad trestle down gradient from the Site, to further evaluate the extent of impacted ground water. Burns & McDonnell installed two monitoring wells (MW-6 and MW- 7) in January 2001, and submitted a summary report to NCDENR in June 2001. Based on the results from the newly installed monitoring wells, NCDENR approved the CAP in a letter dated July 17, 2001. In November 2002, NSRC contracted MM&A to continue semi-annual ground water monitoring at the Site, in accordance with the approved CAP. As part of the previous CAP submittals, periodic ground water monitoring events have been conducted, with the most recent sampling event occurring on November 10, 2003. 3 ►► ► ��; SOCI. ES Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 4 of 12 G. HYDROGEOLOGIC DESCRIPTION The following section was prepared in accordance with G.S. 89E-13 and has been approved by a licensed `��pd� �. '� %bii 0 �iraeaaaa��►� Suzanne E. Bailey, L.G. 1778 1. REGIONAL GEOLOGIC SETTING The Site is at an elevation of approximately 894 feet above mean sea level (MSL) and is located in the southern portion of the Kings Mountain Belt Physiographic Province of North Carolina. According to the geologic map of North Carolina (North Carolina Geological Survey, 1985), the uppermost bedrock in the Site vicinity is the Battleground Formation, which contains quartz- sericite schist with metavolcanic rock, quartz -pebble metaconglomerate, kyanite-sillimanite quartzite, and garnet -quartz rock. Bedrock has not been encountered in soil borings at the Site. 2. SIGNIFICANT CHANGES IN LITHOLOGY Subsurface materials encountered in soil borings and excavations at the Site consist of fill, clay, and clayey sand. Fill material (subgrade composed of clay, sand, and gravel) is prevalent across the Site to a depth of approximately two feet below grade (bg) beneath the asphalt cover. This fill is underlain by approximately 10 feet of native soil composed of low plasticity clay with some sand. Fill material (primarily clay with some sand) is also present within the former UST excavation to an average depth of 10 feet bg. Native soil consisting of low plasticity clay is present beneath the UST excavation to a depth of 25 feet according to the boring log for MW-2. Clayey sand, observed between approximately 10 and 20 feet bg, is the principle water bearing 4 ►' ►v ��; SOCI. ES Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 5 of 12 unit at the Site and is underlain by at least five feet of clay according to boring logs for MW-4 and MW-5. 3. HYDRAULIC CONDUCTIVITY The CSA reports an average hydraulic conductivity of 3.77 x 10-2 ft/day or 1.33 x 10 -5 cm/sec based on the results of slug tests performed in wells MW-4 and MW-5. This value is consistent with typical hydraulic conductivity values for sandy clay and clayey sand. 4. DEPTH TO MEAN SEASONAL HIGH WATER TABLE Based on historical data, the mean seasonal high water table is typically 10 feet bg. 5. TRANSMISSIVITY/SPECIFIC YIELD Using data from the CSA Report, the transmissivity (T) across the zone of proposed ORC® installation at the Site was calculated using the average hydraulic conductivity value (K=3.77 x 10-2 ft/day) and the thickness of the saturated zone that will be treated (b=15 ft, based on the screened interval in MW-2 and MW-4 from 10 ft bg to 25 ft bg). Therefore, the transmissivity is T=bK, or approximately 0.5655 ft2/day. The specific yield of the saturated zone cannot be determined from available Site data, but can be inferred based on the subsurface materials observed in soil borings. According to Fetter (1994), clay and sandy clay have a specific yield averaging 2%, but this value can range from 0 to 5%. H. MONITORING PROCEDURE A monitoring well network already exists at the Site as shown on Figure 2. Ground water monitoring has included quarterly and semi-annual sampling from seven shallow wells for VOCs (USEPA Method 8260) and polynuclear aromatic hydrocarbons (PAHs, USEPA Method 8270). Two years of semi-annual ground water monitoring is proposed during ORC® treatment. The first of four semi-annual ground water monitoring events will be performed in November 2004 before installing the ORC® socks. ORC® socks will be installed in monitoring wells MW- 5 ��; SOCI. ES Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 6 of 12 2 and MW-4 immediately following ground water sampling in November 2004. Three additional semi-annual ground water monitoring events will be performed in May 2005, November 2005 and May 2006. The ORC® socks will then be replaced in May 2005 and again in November 2005. Ground water samples will be analyzed for VOCs, including isopropyl ether (IPE), methyl tertiary butyl ether (MTBE), and ethylene dibromide (EDB) using USEPA Method 8260; and PAHs using USEPA Method 8270. Field parameters monitored for will include: pH, water temperature, specific conductivity, and dissolved oxygen. Well construction diagrams on the respective boring logs for MW-2 and MW-4 are provided in Appendix B. I. WELL USE Monitoring wells MW-2 and MW-4 are proposed to undergo treatment with ORC® socks. These and all other Site wells are monitoring wells designed to allow access for ground water sampling to monitor the natural attenuation of dissolved gasoline constituents in ground water. None of the Site monitoring wells is used for potable water. Monitoring wells MW-2 and MW- 4 will have three sets of ORC® socks installed at six-month intervals over the two-year monitoring and treatment period. Ground water samples will also be collected from all Site monitoring wells on a semi-annual schedule for two years. J. CONSTRUCTION DATA Both MW-2 and MW-4 have a total depth of 25 feet bg and are constructed with two-inch diameter schedule 40 PVC. Each well has 15 feet of 0.01-inch slotted screen and 10 feet of PVC riser. Number 2 filter pack sand was installed through the augers to at least two feet above the top of the screen. Each well has at least two feet of seal above the screen composed of hydrated bentonite chips. Both wells were completed with cement to ground surface and finished with flush mount well covers and vaults. Well construction information for MW-2 and MW-4 are provided on the last page of the boring logs in Appendix B. 6 ►®' ' ►► ��; SOCI. ES Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 7 of 12 K. OTHER WELL DATA The CSA Report indicates that the Bessemer City has a city ordinance requiring all residences and businesses within the city limits to use the municipal water supply. The Site and surrounding area within 1/4 mile are all within the city limits. The CSA Report indicates that no private water wells exist within 1,500 feet of the Site and that all residences and businesses within this radius use the municipal water supply. Bessemer City obtains its municipal water supply from two reservoirs, Webber Lake and Arrowood Lake. Public water is available at the Site from water lines along W. Virginia Avenue and 13th Street. L. PROPOSED OPERATING DATA 1. INJECTION RATE: Each ORC"' sock releases molecular oxygen at an estimated rate of 0.2 grams per day. Each monitoring well will have 15 ORC® socks installed at a time. Therefore, the estimated rate of molecular oxygen release per well is 3 grams per day, assuming a constant rate of release. 2. INJECTION VOLUME: Given the rate of molecular oxygen release of 3 grams/day per well, the volume of oxygen released from the ORC® socks over six months is estimated to be 540 grams per well or a total of 1080 grams. Three six-month treatment periods with ORC® socks would release an estimated 3240 grams of molecular oxygen. 3. INJECTION PRESSURE: The oxygen will be released passively from the ORC® socks under ambient pressure. 4. INJECTION TEMPERATURE: The oxygen will be released from the ORC® at the ambient air temperature. Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 8 of 12 S. HYDRAULIC CAPACITY OF THE WELL Because oxygen will be released passively, versus injected under pressure, the hydraulic capacity of the wells is not of concern. 6. EXPECTED LIFETIME OF THE INJECTION FACILITY Existing monitoring wells are expected to be viable for an estimated 10 years or more. 7. DESCRIPTION OF MEASUREMENTS/CONTROLS The rate of oxygen released to the aquifer is an estimate. Actual rates of the oxygen release will vary depending on the geochemical and biological conditions of the aquifer. ORC® socks are typically depleted six months after installation in water. M. INJECTION RELATED EQUIPMENT The program consists of installing ORCsocks within existing monitoring wells. Equipment consists of ORC® socks and polypropylene rope. A diagram showing the configuration of a typical ORC® sock installation is included in Appendix A. N. LOCATION OF WELL(S) A Site vicinity map is shown in Figure 1 and includes topographic contours. The proposed ORC® sock installation points are monitoring wells shown on Figure 2 along with the required elements described in section N of the permit. All monitoring wells are located on Norfolk Southern Railway Company property. O. INJECTION FLUID DATA 1. FLUID SOURCE No fluids will be injected into the subsurface. 8 =M. SOCI. ES Norfolk Southern Railway Company Injection Well Permit for ORC® Remediation 8/24/2004 Page 9 of 12 2. CHEMICAL, PHYSICAL, BIOLOGICAL, AND RADIOLOGICAL CHARACTERISTICS OF INJECTION FLUID. No fluid will be injected; however, the characteristics of ORC®, the proposed injection material provided by the manufacturer, are included in Appendix A. P. PERMIT LIST No additional permits or construction approvals are known to be required outside of this permit. Q. REFERENCES Fetter, C. W., Applied Hydrogeology, 3rd Edition. (New York: Macmillan College Publishing Company, Inc., 1994). 9 \► nF LL\\ SOCI. ES FIGURES SOLI. ES Prepared by: \\M \\ SOCI ES NS1411 01/06/04 jugNORFOLK SOUTHERN USGS 7.5' BESSEMER CITY, NC QUADRANGLE -1973 CONTOUR INTERVAL = 20' 201 W. VIRGINIA AVENUE BESSEMER CITY, NORTH CAROLINA 2,000' 0 2,00a SCALE 1:24,000 FIGURE 1 VICINITY MAP NORTH CAROLINA QUADRANGLE LOCATION MW-7 880.75 50' 881 "RG/Nlq A tz VIRGINIA AVENUE AUTO FIBER OPT1C CABLE RAILROAD BRIDGE 882 • MW-6 PENNSYLVANIA AVE 880.05 0 883 50' 1"=50' NOTE: The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. FIGURE 3 GROUND WATER CONTOUR MAP NOVEMBER 2003 MW-1 2tgl3 3r, 885.28 805 8 STORM ��SEMcR MWi 880.05 5 3 LEGEND MONITORING WELL GROUND WATER ELEVATION CONTOUR (CONTOUR INTERVAL=1FOOT) APPROXIMATE GROUND WATER FLOW DIRECTION NOTES: 1: GROUND WATER ELEVATION IN FEET ABOVE MEAN SEA LEVEL 2: GROUND WATER ELEVATIONS OBTAINED ON NOVEMBER 10, 2003 NORF©PK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1" = 50' DESIGNED: SB DRAWN: BFW MW-7 ND 50' V/RC1NlA Atr STORM VIRGINIA AVENUE AUTO FIBER OPTIC CABLE RAILROAD BRIDGE • MW-6 PENNSYLVANIA AVE ND 0 sa 1"=50. NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. FIGURE 4 BENZENE IN GROUND WATER ISOCONCENTRATION MAP NOVEMBER 2003 MW-1 3 LEGEND MONITORING WELL ND NOT DETECTED - BENZENE ISOCONCENTRATION CONTOUR NOTES: 1: GROUND WATER SAMPLES COLLECTED ON NOVEMBER 10, 2003 2: ALL RESULTS IN MICROGRAMS PER LITER (Ng/L) 3: NCDENR GROUND WATER STANDARD FOR BENZENE=1 ug/L NOREOEK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CRY, NC DATE: JAN.2004 SCALE: 1" = 50' DESIGNED: SB DRAWN: BFW MW-7 Q•••••:: VIRGIN AVENUE AUTO STORM ��SEWER MW-1 IA40- FIBER OPTIC ,CABLE PENNSYLVANIA AVE. RAILROAD BRIDGE MW-6 50' 0 50' 1" = 50 NOTE The location and dimensions of features shown on this map have been derived from various sources and supplemented by field measurements. Though sufficient for its intended purpose, no claim is made as to the degree of accuracy of this drawing. MW 5 *PAW 3 MW-2 ,MW-4 MW1 LEGEND MONITORING WELL FIGURE 2 SITE MAP • NORFOLK SOUTHERN 201 W. VIRGINIA AVENUE BESSEMER CITY, NC DATE: JAN. 2004 SCALE: 1" = 50' DESIGNED: SB DRAWN: BFW „I RJI'II LL„ INEMINCEN NS1411.dwg APPENDIX A REGENESIS, OXYGEN RELEASE COMPOUND (ORC®) INFORMATION SOCI. ES - Products - ORC® - Overview http://www.regenesis.com/products/orc/ Leaders in Accelerated Natural Attenuation • Search I Contact Us I Ordor REGENESIS , 6 Product PRODUCTS OVERVIEW SOLUTIONS Ii RESOURGEBi a' ABOUT US i ?WORLDWIDE;, ORC is a proprietary formulation of phosphate -intercalated magnesium peroxide that time releases oxygen when hydrated. Purpose To supply oxygen to accelerate the rate of naturally occurring aerobic contaminant biodegradation in groundwater and saturated soils. Functionality ORC is typically applied using direct -injection techniques. This process requires ORC to be mixed with water to form an injectable slurry which is then pressure injected (using a pump), into the zone of contamination. Once in the aquifer, ORC particles will sorb to or reside in the soil matrix and slowly release oxygen for periods of up to 1 year. ORC is also available in 2", 4" and 6" filter socks that can be emplaced in wells and removed when exhausted. Upon removal the old socks can be replaced with new ones to rejuvenate the oxygen supply and maintain aerobic biodegradation as needed. Product Specifications • A powdery material less than 10 microns in diameter • Composition - Magnesium Peroxide (Mg02) • Non -hazardous, food grade product • Intercalated design allows for slow -release of oxygen without "lock -up" • Releases 10% of its weight as oxygen when hydrated • Packaged and delivered in 30 Ib. PVC buckets By -Products • "Milk of magnesia" or Mg(OH)2 a common antacid formula Field Applications • Straight powder application in excavations • ORC and water mixture (slurry) application in excavations • Replaceable filter socks for single well and barrier applications • Directly -injectable slurry (most common) for source area and permeable reactive barrier applications Benefits of Use • Slow -release of molecular oxygen to support aerobic microbial activity • Long-term source of oxygen to the subsurface (up to 12 months) • Clean, low-cost, non -disruptive application (direct -push or socks) • Direct Injection not limited by presence of surface structures • No Operations and Maintenance • Faster and often lower cost than drawn out natural attenuation approaches • Complimentary product application design and site analysis from Regenesis Application Considerations • Contaminant mass • Groundwater Flow Rates • Distribution of oxygen in the aquifer • Longevity (C)2004 Regenesis, All Rights Reserved re, LEARN MORE Have a Regenesis Expert Answer Your Questions SITE EVALUATION Request a Free Evaluation of the Use of ORC, HRC or HRC-X at Your Site Brochures: o ORC Brochure (PDF) - Products - ORC® - How It Works http://www.regenesis.com/products/orc/howitworks.aspx Leaders In Accelerated Natural Attenuation REGENESIS PRODUCTSt,I soLUTlo How it Works? RESOURCES _l._, ABOUT,_ Soarch I Contact Us I Order oftirDWA'pElq HOW IT WORKS Oxygen is often the limiting factor for aerobic microbes capable of biologically degrading contaminants such as petroleum hydrocarbons. Without adequate oxygen, contaminant degradation will either cease or may proceed by much slower anaerobic (oxygen -free) processes. ORC is designed to release oxygen, into the subsurface, for up to one year depending on site conditions. In the presence of this long-lasting oxygen source, aerobic microbes flourish accelerating natural attenuation of gasoline and fuel additives (BTEX and MTBE), diesel, kerosene, jet fuel, gas condensates, fuel oils, lubricants, bunker oil, PAHs, certain metals (arsenic), certain pesticides/herbicides and certain industrial solvents (alcohols and ketones). Critical Timed Release ORC is intercalated with food -grade phosphate, this gives it the time -release properties that are critical in a passive, low-cost oxygen application system. The term "intercalation" is used here to describe the permeation of phosphates into the crystalline structure of magnesium peroxide (Fiqure 1). This feature slows the reaction that yields oxygen thus facilitating the extended release. Phosphate intercalation also prevents a process known as "oxygen lock -up." When water reacts with an un-intercalated magnesium peroxide, a cement -like coating of magnesium hydroxide forms which prevents water from penetrating deeper into the crystal to release all of the available oxygen. ORC's phosphate intercalation keeps the crystal "open," preventing this problem and continuing the release of oxygen. Figure 1: ORC Intercalation O nd C r PHOSPHATE GROUP " ("intercalates" and Disrupts Crystal Array) ORC CRYSTAL OXYGEN co (9Q Figure 1 (Click to Enlarge) Product Applications ORC is typically applied in the subsurface via direct push injection, borehole backfill or filter socks. When using direct push and/or borehole backfill, ORC powder is mixed with water to form an injectable slurry. The slurry is then pumped into the groundwater where it disperses into the aquifer via diffusive and advective forces. In filter sock form, ORC is placed into monitoring wells where the compound reacts when contacted with water. Upon exhaustion, which can take up to 1 year, filter socks can be removed and replaced to replenish the oxygen supply and continue , treatment. Special canisters are available with filter socks to avoid lodging them in deeper wells (> 40 ft.). Additionally ORC can be applied into excavated areas either in its native powder form or by broadcasting the slurry mixture. Excavation treatments take advantage of fluctuating groundwater levels and percolation from the surface to activate the oxygen releasing capabilities of ORC. (C)2004 Regenesis, All Rights Reserved LEARN MORE Have a Regenesis Expert Answer Your Questions SITE EVALUATION Request a Free Evaluation of the Use of ORC, HRC or HRC-X at Your Site Brochures: ❑ ORC Brochure (PDF) ei? REGENESIS Oxygen Release Compound (ORC®) Installation Instructions (Replaceable Filter -Sock Application) ORC Filter Socks are used to enhance bioremediation of petroleum hydrocarbons in groundwater. The filter sock contains ORC and an inert carrier matrix. The socks come in one foot sections. They are laced together to span the vertical polluted saturated zone in monitoring type wells. Once the socks are laced together and lowered into the wells, they become hydrated and begin releasing oxygen. The following instructions are vital to proper installation and subsequent removal of the socks. SAFETY PRECAUTIONS: • ORC is completely non -toxic, but is composed of ultra -fine particles. • Wear dust masks and goggles to prevent soft tissue irritation • Reference the Material Safety Data Sheet for specific technical and physical information. CONDITION OF SOURCE WELL: • Test for well deviation and smoothness before ORC installation. • For the test, use a 5 foot section of pipe with an outside diameter 1/2 inch smaller than the source well's inside diameter. KEY REQUIREMENTS FOR INSTALLATION: • SOCKS MUST BE INSTALLED WITH BLACK GROMMETS ON TOP • Wrap Socks as independent units (see page 3, figure 5) • A maximum of 20 ea. 2-inch socks per section. • A maximum of 8 ea. 4-inch socks per section. • A maximum of 6 ea. 6-inch socks per section. • Make sure each sock is properly shaped (cylindrical and without bends) to facilitate ease of installation and removal. HELPFUL HINTS: • ORC matrix hardens into a cement once hydrated • Minimize slack between each sock, by periodically pulling up slack while lacing • Tie off ORC retrieval lines to the well cap. Regenesis recommends the use of a 3/8" diameter x 6" long eyebolt. 1 • The ORC Socks should be wetted to prevent excessive dusting prior to installation • Make sure your work area is clean to avoid oil and dirt deposits on the socks. FILTER -SOCK REMOVAL: • ORC Socks will be approximately 20% heavier after water saturation • Static friction from screened casing may cause difficulty in removal • A winch and stanchion (or comparable equipment) may be necessary to help remove the socks due to increased weight, friction, etc. LACING DIAGRAMS FOR SOCK INSTALLATION: 4 INCH AND 6 INCH SOCK LACING DIAGRAM: WHITE GROMMETS CENTER OF ROPE BLACK GROMMETS BLACK GROMMETS -441:1111iN N. r ..i%4III.II WHITE 4 � , �::04SI: 4,A.A i es• III N GROMMETS ""�'•••'" E i�III •II//I/I��N ..IIII i :/ WHITE GROMMETS CENTER OF ROPE BLACK GROMMET: 1. Find the center of the rope. Begin lacing the ORC Socks by threading the two ends of the installation rope through the black grommets and then through the white grommets at the bottom of the same side of the bottom sock 2. Pull the rope through the bottom sock, making sure the center of the rope is between the black grommets. Cross the ropes over each other. 3. Loop the ends of the rope around the back of the sock and cross them. Repeat this step once again, so the rope is wrapped around the sock with two full turns. 2 WHITE BLACK GROMMETS GROMMETS 1 1 FRONT VIEW BACK VIEW WHITE GROMMETS y WHITE GROMMETS BLACK GROMMETS 4. Bring the ends of the rope around from the back, cross them, and thread them into the black grommets. The rope ends should be inserted into the black grommets diagonally from the white ones they started from. Threading the black grommets will be tight only on the bottom sock due to the unique lacing pattern. 5. To avoid the ORC Sock slipping past each other, the socks must be laced with the grommet flaps of the bottom sock and second sock butting against each other (as shown) 6. The remaining socks on the rope section are laced up according to Figure 6. Make sure that the rope is turned around the sock two full turns, with the grommets of each sock butting up against the next sock as shown in Figure 5. 7. Lace each subsequent ORC Sock exactly the same as in Figure 5 and 6. IMPORTANT: Do not exceed the maximum number of socks per section (see "Key Requirements D & E" on page 1). Minimize the slack between the socks 3 TOP SE CIION TIE KNOT-^ `�*- OOTTOJA SECTION CENTER OF ROPE WHITE GROMMET 8. If you need to install more ORC Socks than the maximum allowed per well size (see "Key Requirements D & E on page 1), then multiple sections must be installed. Each section is laced exactly the same, but they should be tied off to each other. Tie the end of the rope from the lower section to the bottom sock of the upper section; this allows each section to be installed and removed independently (see well diagram) 2 INCH SOCK LACING DIAGRAM: 2" SOCK,„..„..." 1 BLACK GROMMET Well Diagram 9. Find the center of the rope. Begin lacing the ORC Socks by threading one end of the installation rope through the white grommet. Make sure that the center of the rope is pulled through to the center of the white grommet on the bottom sock. 4 2" SOCK CENTER OF ROPE WHITE GROMMET WHITE;- GROMMET S 1 •,`.� BLACK GROMMET 1o. Wrap each end of the BLACK installation rope around the sock GROMMET twice and then cross them through the black grommet. 11. Lace each subsequent sock using the same method ad describe in Figure 2 above. IMPORTANT: Do not exceed the maximum number of socks per section (see "Key requirements B" on Page 1) Minimize the slack between socks For direct assistance or answers to any questions you may have regarding these instructions, contact Regenesis Technical Services at 949-366-8000. REGENESIS, 2002 www.regenesis.com 5 - Products - ORC® - MSDS http://www.regenesis.com/products/orc/msds.aspx Leaders in Accelerated Natural Attenuation REGENESIS r RpDUCTt ' ;,`zt� t< i� « �, �- ��—4s-°,� �u v.r-•� � a.��ys; ,�' f r ,��, ��' � a� �� iLUTIONS [ RESOURCES + ] ABOUTUS a ] WORLDWIDE a MATERIAL SAFETY DATA SHEET A printable PDF version of the MSDS is available here. Last Revised: February 10, 2004 Section 1 - Material Identification Soarch I Contact Us I Order Supplier: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Phone: 949.366.8000 Fax: 949.366.8090 Email: infoaregenesis.com Chemical Description: A mixture of Magnesium Peroxide (Mg02), Magnesium Oxide (MgO), and Magnesium Hydroxide [Mg(OH)2] Chemical Family: Inorganic Chemical Trade Name: Oxygen Release Compound (ORC®) Product Use: Used to remediate contaminated soil and groundwater (environmental applications). CAS # 14452-57-4 1309-48-4 1309-42-8 Assay: Melting Point: Boiling Point: Section 2 - Chemical Identification Chemical Magnesium Peroxide (MgO2) Magnesium Oxide (MgO) Magnesium Hydroxide [Mg(OH)22] 25-35% Magnesium Peroxide (MgO2) Section 3 - Physical Data Not Determined (ND) ND Flash Point: Not Applicable (NA) Self -Ignition Temperature NA Thermal Decomposition: Spontaneous Combustion possible at —150°C Density: 0.6-0.8 g/cc Solubility: Reacts with water pH: Approximately 10 in saturated solution Appearance: White powder Odor: None Vapor Pressure: None Hazardous Decomposition Products: Not Known Hazardous Reactions: Hazardous Polymerization will not occur Further Information: Non-combustible, but will support combustion Section 4 - Reactivity Data • LEARN MORE Have a Regenesis Expert Answer Your Questions SITE EVALUATION Request a Free Evaluation of the Use of ORC, HRC or HRC-X at Your Site Brochures: ❑ ORC Brochure (PDF) APPENDIX B SOIL BORING LOGS WITH WELL CONSRUCTION DIAGRAMS ►►, ' ►► '4 Drilling Log Project Name nvoFcGA- Project Number 4q -9 - y ooy -o ( Boring Number A k,-7. Ground Elevation Location mac) In". V)r5,A-1/1 4ve'5e4>C ; 6i, Page i of 3 i Mr Nonitoring Equipment 1Z n Total Footage Drilling Type Hole Size Overburden Footage Bedrock Footage No. 0f Samples No. 0f Core Boxes 4 '/ _ 1 I o. S 017)1 ?-7 o NA- 5 ,v 4 Drilling Company /,i 6.6/4 L L 5✓ 04 46,✓ S D(ialer Is) Ken, /`') c.p0n-4 Id Don. Totiti.5 o�. 10 i✓v,r✓7kPrvh IL Drilling Rig Gel 4 r(4 �7—yso Tpe of Sampler SML%,1 . J/10O/1" Date 6/-���o ! 1 To 6/�6�9� / Field Observer(5) R Qil.1,rs Depth (feet) Description Description Class Blow Count Recov. Run/ Time SamplePID Desig. (ppm) Remarks/ Water Levels BZ BH S BZ BH 0 2- 3- 4- 5 = 6 - = 8 - 9- 10 -- -' 11- 12 - _ 13- 14 - Ayve ,A- Otiy5 o SYS &y;,�1ic, S.,o,e' SS -I 043� San '' 7 — — -= —, 2 - — _ - -+ 7 - G 6 r/sone c1.0ve( a-S%j�Y/e cv4(5e GLI7 k-i I''�/ �4 S:fh, f-r•Xt' 51-4-veli51%Ff)✓t-c).. j,14S/le/ ICYPl. e) o o� v6 rl TOP- `�°�� rp:v -1f3S .__ o9iv PD=yo • pt7 �/ �7 5 ��C SS �' - --- ,462 j oVis voc% )"Tl iqr v9it BZ=Breathing Zone BH=Bore Hole S=Sanpie Bums 8 McDonnell Waste Consultants, Inc uriiiing Log continuation Boring Number /AN, _?-- Pro)ect Name /VofFo1/ Page �. of 3 Project Number ��I -� b - li -Goy O/ Date .6./ 9`f Depth (feet) Description Class Blom Count Recov. Run/ Time Sample Deslg. PID (PM)J Remarks/ BZ BH S Water Levels 6 5 Gu — - / 7 2_ JJ U — = I — _ - 22 44i/ 50,c Go7 c-i-- Si / 11141' - Fi t.e ,.d vrl, yc'i(c—r5I' ---),A -,-. 1 �ppplelUri°r/11mr oRW 2T ,-7- .15 A--o" t s7-. c( F!/ t) - h,e 4 -- 20--- -3, / Do�p �l -T�' ll— cY�s - - ��3� - e, cal, 0955 - 5'5 T A-12)41/ tinZJ/ A ..s r 3r►F J 5 0�� 5S 3 VcCS vv/ pJ'D=`735 pzp= 3� .. _ . 0995 • c vLcs ,41vA? �9.Yyo air • '3 ) 7 6-774`45yTn v� 5 VPI� J y 'ip = a7 (D ' S,�-�;i- Sac � BZ=Breathing Zone BH=Bore Hole S=Sample EMI Wute Consult n!J 1 Drilling Log Continuation Project Name Project Number Depth (feet) qq-9�(1-q-coy-01 Description Class Blow Count Recov. Run/ Time Sample Desig. Boring Number r/w — Pa9e 3 of 3 Date 6/36/iY PID (ppm) - 10 o7'p: _ (eA)5e{ n a Gc> ve $%Hon of 4ve i-L 4-) asicA Fee 4- B 6 5 A/ T To e-4 t E- BZ 1 BH I S Remarks/ Water Levels (29SS _ 0..c/c Sty4 .v i/ 541 r v,;f4, 4t ip : 148, 10,07' w)spl Ihrx � JS.cF? CF ` Ft.k'f 70F s - P5v qyy) 7r0' /YY-J(4,tJ - kk-,:1' pt ' t �. C9b/iys) 1 co T,44 i( coiure J? phi) Wrtb F6v5i) Mov vl— p ✓e( /5.20 BZ=Breathing Zone BH=Bore Hole S=Sample MGMWaste Drilling Log ,lect Name Alag fD �\ /�/ I,0,ect Nun4Der-Zv-y- QDy-O Z >und Elevation 1Locatlon ✓ ; Monitoring Equipment ,/ /J ^ J [� 6� /T2 Drilling Type I Overburden Footage I Bedrock Footage No. Of Samples -7, I 2‘ d '. I /V / - Drllef (S) /rJ,,,e f7L••-rr/ Type of ( Sampler 1 f %, f J d �1 / Lr� Field Ooserver (s) e+/o7 Cuff 7, 0-.7 Hole Size Ss/4- Company icclhf1 L✓e // D/r /11.1 filing Rig d Zoo G G ite /Z /3 /ycl ITo /Z /3 / epth feet) Description 1 _ C/47, Jo?'1G ✓L/y 4'n2 J/c/hlL/1- JG�tO� re� (2 .s %Q 572) 2- Ca^ r sue, 4C� 4/;J�ic,s4 )<•4f wo o l Ti"" 3- 4- 5- 6- Sti�,,�.7 c/47i rz� y/')w/;�, Sw - S,,: f d to4:1-z SG,raQiJ o 7- rd 1 Cet. A-c/c ,,,,,,/)Gf& % ▪ /0o5e./ ma. -,m do f t- g- Ca4f %s ^c7) 0G N,/ 9- 10_ 11= 12 ; 13- Class CL Blow Count Recov. Run/ Time Boring Number ./vi tv— Page of 2— Total Footage C O Sample Desig. PID (ppm) No. Of Core Boxes 35-/ C/ 7`7 f4 / rep( CZIr Y, r/ /c dL / Shh4I' gok v 1LA) ci0%r^.: 44- Sc_ Z /j Z 2 otis 2 BZ I BH I S O O 0 = 2/•FI, O 0 G /.•7 a 8.1 ci Z I LAG= a50 2 1 02_2/.7., /5.9 Remarks/ Water Levels 14 - R?=Rreathina Zone EH=Bore Hole 5=Sample Waste Consultant_. Drilling Log Continuation ^, Boring Number _yY/ (�/ — L7/ n Project Name / / F',/—L �� f Page Z of Protect Number � —y — — 6/0 G71— p Z Date / Z. / S Cf Depth (feet) Class Blow Recov. Run/ Sample PID (ppm) Remarks/ r� Description Count Time Desig. BZ BH S dater Levels _ _ c i``1``f-,��' i r v-- `� ra, well 5';citci, SC- Z SS /O.b 27,173_, )V:Zo.f - _ _ 17 yrrt,}J goi,^+,1a-14- z SS-9 6Zv 11 = Clay r4 -7, / 4.1 e j— 7 2 d33, 5:fg ; ' / - jlooj2 ,4h�yy/-4-,zd. 1H44-+ •-,14r- l✓6/l9-4d�i / 7u4 ?Z 4.4a4e,,;etif T l .�1-9 `7Z7 i�6 7Z.Z �S S� . } _ • - S.,vy G /4/ J fd (/ U\ 1 i / ,1 C L ? ,,- / -. • ,r« =, t i +� '� .': -'- •i .-.. . ) c: i :::.,.).1::- •.,.. 2 _ - zy= ., iy (/4 Jkc, // $ - - (6)4f;/S "7 rno•; 4 (,,,Ld" / ? 3_ - Z c3?f� ;;_ li �Z� $ 3C? •,-):-. ,,),(5- > - ;''� - 91s �y-er5) 04' Ds Z,q2k ei I S i Icy SJ lZ W20 Ati.hd ,,,,,,,,,e ,L.:o,a,k c l-,p i 1 tk�_ck- J - -- _ ���,�, off— �1a16 = 21,O' Sz. well G� ZS,o' ri.,-, d.c_ •._ 0 0 - ;; . ✓fzx• g.:' : /ice.; j_ - — ell:. r i(: i J - �.� J - A 4 i. ,"3.•L ,i j — 1--4 �i1+W r ., _ _ I — '° —� To -_ - 2-5 S C ,�j L � BZ=Breathing Zone BH=Bore Hole S=Sampie Waste