WQ0038835_Residual Annual Report 2020_20210226

Initial Review
Reviewer Thornburg, Nathaniel
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application what is the submittal type?* r Annual Report
r Residual Annual Report
r Additional Information
r Other
Annual Report Year* 2020
Permit Number (IR)* WQ0038835
Applicant/Permittee Terra Renewal Services, Inc
Email Notifications
Does this need review by the hydrogeologist?* 0 Yes r No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Rease provide information on the person to be contacted by N B Staff regarding electibnittal, confirmation of receipt, other
.......................................................... electronic surece, aner correspondence.
_ -
Name * Terra Renewal Services
Email Address*
david.coyle@terrarenewa I. com
Project Information
........ ......... ............................................................................................................................... .
Application/Document Type* r New (Fee Req ui red)
r Modification - Major (Fee Required)
r Renewal with Major Modification (Fee
Required)
r Annual Report
r Additional Information
r Other
Phone Number*
4797478192
O Modification - Minor
C Renewal
C GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
IT Residual Annual Report
r Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* r Wastewater Irrigation r High -Rate Infiltration
r Other Wastewater r Reclaimed Water
r Closed -Loop Recycle r Residuals
r Single -Family Residence Wastewater r Other
Irrigation
Permit Number:* WQ0038835
Fbs Current Existing pernit number
Applicant/Permittee Address* P.O. Box1746 Watkinsville, GA30677
Facility Name * Terra Renewal Services - Washington Region RLAP
Please provide comments/notes on your current submittal below.
This is the 2020 Annual Report for permit # WQ0038835 with land sites in Gates and Lenoir
County. This relates to a land application event from a lagoon cleanout at the Valley Proteins
rendering facility in Emporia, VA with 1.5 MG gallons of residuals applied to permitted sites in
Gates County. No hard copy will be submitted. If there are any complications or requests for
additional information, please contact David Coyle @ 479-747-8192 or
[e-mail].
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form Engineering Rans, Specifications, Calculations, Rc.)
NC—WQ0038835—Terra Renewal Annual Report_2020.pdf 6.96MB
Upload only 1 RDFdocurrent (less than 250 W). IvL@iple documents rust be combined into one RDFfile unless file is larger than
upload lirrit.
* W By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order
and made payable to the North Carolina Department of Environmental Quality
(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617

Signature
Submission Date 2/26/2021

M
fV
TERRA
renal
PO BOX 399 • DARDANELLE • ARKANSAS • 72834
479.747.8192
terrarenewal.com
2020 ANNUAL REPORT
for NC Land Application Permit Number:
WQ0038835
(Class B Residuals)
Permittee / Submitted By:
Terra Renewal Services
P.O. Box 399
Dardanelle, AR 72834
Attention:
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section
Non -Discharge Permitting Unit
512 N. Salisbury Street; 6t" Floor
Raleigh, NC 27604

TERRA
renewal
February 26, 2021
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permit Section
Non -Discharge Permitting Unit
Information Processing Unit
6th Floor
512 N. Salisbury Street
Raleigh, NC 27699
East Region Environmental Office
P.O. Box 1746
Watkinsville, GA 30677
phone [phone]
RE: 2020 Annual Report for Land Application Permit No. WQ0038835
Permittee: Terra Renewal Services, Inc
Dear Sir or Madam,
The enclosed documentation is intended to serve as the annual report for the land application of residuals
sources related to the above referenced permit in Lenoir County.
The following information is provided:
PPrmittPP-
Terra Renewal Services, Inc.
P.O. Box 399
Dardanelle, AR 72834
Preparer & Contact:
Terra Renewal Services, Inc
David C. Coyle; Environmental Manager
P.O. Box 1746
Watkinsville, GA 30677
phone: [phone]
email: david.coyleCcDterrarenewal.com
These items are included with the report (in order):
1) The Annual Land Application Certification Form (ACF)
2) The Annual Residuals Sampling Summary Form (RSSF) and Annual Residuals Sampling
Summary Form — B (RSSF-B) for each residuals source
3) The Annual Metals Field Loading Summary Form (MFLSF), Annual Land Application Field
Summary Form (FSF), and Annual Land Application Field Summary Form Supplement (FSF-
SUPP)
4) Lab Analyses for Residuals:
— Nutrients, Metals, TCLP, Other
— Fecal Density (Seven Set)
— Vector Attraction Reduction Data (30 Day Bench)
5) Annual Pathogen and Vector Attraction Reduction Form for NCAC 2T Rules (PVRF 2T)
6) Soil Test Reports (for fields applied in 2020)

Page 2
2020 Annual Report
WQ0038835
Residuals were land applied and incorporated per the conditions of the permit. PAN application rates
were established based on a spring corn crop in 2021. These fields were planted in small grains within
five days of conclusion of the land application event (mid -December), intended as a cover crop for the
purpose of site stability and to assimilate any nitrate mobilized during winter months. The cover crop will
be "burned down" and incorporated prior to planting corn in spring of 2021.
On the Annual Land Application Certification Form (ACF), the option "No" is selected under Part B —
Annual Compliance Statement for the statement "Facility was compliant during calendar year 2020 with
all conditions of the land application permit issued by the Division of Water Resources". The reasons for
this are as follows:
Item-2 — "Soil pH was adjusted as specified in the permit and lime was applied (if needed) to
achieve a soil pH of at least 6.0 or the limit specified in the permit. "
— Soil samples were collected at the time of the application event. Results for both fields
applied showed soil pH < 6.0. This project concluded in early December 2020. Following
application, the information regarding the need for pH adjustment was provided to the
farmer. Field conditions were too wet in late December 2020 through February 2021 to
allow for lime application. Lime application at the rates recommended by the Agronomist
is planned for both fields prior to planting corn in spring 2021. Records of the application
(lime tonnage tickets and dates) will be provided to the Division as an addendum to this
report once complete.
All other conditions listed under the Compliance Statement on Form ACF were met.
If additional information is required or there are any questions regarding this annual report, please contact
David Coyle via the information listed above. Thank you for your cooperation and attention to this matter.
Sincerely,
David C. Coyle
Environmental Manager
NC LSS #1315

1
ANNUAL LAND APPLICATION CERTIFICATION FORM (ACF)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0038835 County: Gates Year:
Facility Name (as shown on permit):
Land Application Operator:
Terra Renewal Services, Inc
2020
Terra Renewal Services, Inc Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
r❑ Yes ❑ No - If No, slip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit:
15
Total number of fields utilized for land application during the year:
2
Total amount of dry tons applied during the year for all application sites:
90
Total number of acres utilizes for land application during the year:
72
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2020 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. ❑ Yes r❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T . I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
David C. Coyle; Environmental Manager
Permittee Name and Title (type or print)
2/26/2021
Signature of Permittee
Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
DENR FORM ACF (12/2006)

2
ANNUAL RESIDUALS SAMPLING SUMMARY FORM (RSSF)
ANNUAL RESIDUALS SAMPLING SUMMARY FORM - B (RSSF-B)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0038835 Laboratory: 1)
Facility Name: Terra Renewal Services, Inc 2)
Residual Source WQ # or WQ0034380 3)
NPDES #: 4)
WWTP Name: Valley Proteins -Emporia, VA 5)
Residual Analysis Data
Pace Analytical Services, LLC
Parameter
(mg/kg)
Cone.
Limit
(m /lc )a
Sample or Composite Date
11/4/20
Percent Solids (%)
NA
1.47
Arsenic
75
25
Cadmium
85
< 5.7
Copper
4,300
67
Chromium
NA
Lead
840
43
Mercury
57
< 5.3
Molybdenum
75
< 45
Nickel
420
< 45
Selenium
100
< 23
Zinc
7,500
300
Total Phosphorus
NA
4400
TKN
NA
31000
Ammonia -Nitrogen
NA
3500
Nitrate and Nitrite
NA
50
'For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
2/26/2021
Date
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0038087
Facility Name: Terra Renewal Services, Inc
Residual Source WQ0034380
NPDES # or WQ#:
WWTP Name: Sanderson Farms - Kinston
Residual Analvsis Data
Laboratory: 1) Pace Analytical Services, LLC
2)
3)
4)
5)
Parameter
Sample or • • • - Date
SAR (no units)
------------
------------
------------
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
2/26/2021
Date
DENR FORM RSSF - B (12/2006)

3
ANNUAL METALS FIELD LOADING SUMMARY FORM (MFLSF)
ANNUAL LAND APPLICATION FIELD SUMMARY FORM (FSF)
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
SUPPLEMENT (FSF-SUPP)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038835
Terra Renewal Services Owner:
43 Acres Permitted:
Cation Exchange Capacity (non 503 only):
RE Miller & Sons, Inc Predominant Soil Series:
46.8 Site #: NC-GT-EM-05 Field #:
48.89
4.0
Noboco
NC-GT-EM-05
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample
or Com-
posite
Date
1
11/4/20
2
3
4
5
6
7
8
9
10
11
12
% Solids
1.47
Arsenic
25
Cadmium
5.7
Copper
67
Chromium
Lead
43
Mercury
5.3
Molyb-
denum
45
Nickel
45
Selenium
23
Zinc
300
Total
Phos-
horus
4400
Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre):
Total
1j
L2j3
4
5J
6
7
8
9
10
11J
12
DT/Ac./
App.
14
Event
1.14
Arsenic
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.057
Cadmium
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Copper
0.152
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.152
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.098
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.098
Mercury
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Molyb-
0.102
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.102
denum
Nickel
0.102
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.102
Selenium
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Zinc
0.682
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.682
Total
Phos-
10.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
10.006
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/26/2021
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038835 Field #: NC-GT-EM-05 Acres Utilized: 43
Land Owner: Robert E Miller Jr & Sons Inc Annual Dry Tons Applied: 48.9166 Site #: NC-GT-EM-05 Acres Permitted: 46.8
Operator: Terra Renewal Services, Inc Predominant Soil Series: Noboco Cation Exchange Capacity (non 503): 4.0
Crop 1 Name: Sm Grains to Corn Crop 1 Max. PAN: 131 Crop 2 Name: Crop 2 Max. PAN:
0 p
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Moist)
Precip.
past 24
Hrs.
inches
y
o
°o
*Z
o
?
rn
*
°�
,aa,
*
*
fKN
mg/kg
Z a
�t �
o
�.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/2
36000
1.47
0.051
Out of State
D
0
INC
1
0.3
1 31000
3500
1 50
1.211
NA
SG/Corn
11/3
150000
1.47
0.214
Out of State
D
0
INC
1
0.3
31000
3500
50
5.046
NA
SG/Corn
11/4
156000
1.47
0.222
Out of State
D
0
INC
1
0.3
31000
3500
50
5.248
NA
SG/Corn
1115
150000
1.47
0.214
Out of State
D
0
INC
1
0.3
31000
3500
50
5.046
NA
SG/Corn
11/6
156000
1.47
0.222
Out of State
D
0
INC
1
0.3
31000
3500
50
5.248
NA
SG/Corn
11/7
108000
1.47
0.154
Out of State
D
0
INC
1
0.3
31000
3500
50
3.633
NA
SG/Corn
11/9
42000
1.47
0.060
Out of State
D
0
INC
1
0.3
31000
3500
50
1.413
NA
SG/Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
01
798000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
26.847
0.000
Lime Applied
Annuallbs/acre
0.057
0.013
0.152
0.000
0.098
0.012
0.102
0.102
0.052
0.682
10.006
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.057
0.013
0.152
0.000
0.098
0.012
0.102
0.102
0.052
0.682
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1 st/2nd Crop
1 131
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the uossibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/26/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038835
Terra Renewal Services Owner:
29 Acres Permitted:
Cation Exchange Capacity (non 503 only):
RE Miller & Sons, Inc Predominant Soil Series:
36.5 Site #: NC-GT-EM-06 Field #:
41.47
5.6
Goldsboro
NC-GT-EM-06
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Sample
or Com-
posite
Date
1
11/4/20
2
3
4
5
6
7
8
9
10 j
12
% Solids
1.47
Arsenic
25
Cadmium
5.7
Copper
67
Chromium
Lead
43
Mercury
5.3
Molyb-
denum
45
Nickel
45
Selenium
23
Zinc
300
Total
Phos-
horus
4400
Annual Heavy Metal Field Loadings (Ualculated in Ibs/acre):
Total
1j
L2j3
4
5J
6
7
8
9
10
11J
12
DT/Ac./
App.
14
Event
1.43
Arsenic
0.072
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.072
Cadmium
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
0.192
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.192
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.123
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.123
Mercury
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Molyb-
0.129
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.129
denum
Nickel
0.129
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.129
Selenium
0.066
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
Zinc
0.858
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.858
Total
Phos-
12.584
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.584
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
2/26/2021
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0038835 Field #: NC-GT-EM-06 Acres Utilized: 29
Land Owner: Robert E Miller Jr & Sons Inc Annual Dry Tons Applied: 41.5607 Site #: NC-GT-EM-06 Acres Permitted: 36.5
Operator: Terra Renewal Services, Inc Predominant Soil Series: Goldsboro Cation Exchange Capacity (non 503): 5.6
Crop 1 Name: Sm Grains to Corn Crop 1 Max. PAN: 131 Crop 2 Name: Crop 2 Max. PAN:
0 p
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Moist)
Precip.
past 24
Hrs.
inches
y
o
°o
*Z
o
?
rn
*
°�
,aa,
*
*
fKN
mg/kg
Z a
�t �
o
�.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
11/9
90000
1.47
0.190
Out of State
D
0
INC
1
0.3
1 31000
3500
1 50
4.490
NA
SG/Corn
11/10
150000
1.47
0.317
Out of State
D
0
INC
1
0.3
31000
3500
50
7.483
NA
SG/Corn
11/11
120000
1.47
0.254
Out of State
D
0
INC
1
0.3
31000
3500
50
5.986
NA
SG/Corn
12/1
102000
1.47
0.216
Out of State
M
0
INC
1
0.3
31000
3500
50
5.088
NA
SG/Corn
12/2
156000
1.47
0.330
Out of State
D
0
INC
1
0.3
31000
3500
50
7.782
NA
SG/Corn
12/3
60000
1.47
0.127
Out of State
D
0
INC
1
0.3
31000
3500
50
2.993
NA
SG/Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
01
678000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
33.822
0.000
Lime Applied
Annuallbs/acre
0.057
0.013
0.152
0.000
0.098
0.012
0.102
0.102
0.052
0.682
10.006
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.057
0.013
0.152
0.000
0.098
0.012
0.102
0.102
0.052
0.682
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit I st/2nd Crop
F 131
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
2/26/2021 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date * * * Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

4
LABORATORY ANALYSES:
- Nutrients, Metals, TCLP, Other

0p
0
PaceAnalyfical
Report of Analysis
Terra Renewal Services, Inc.
PO Box 3036
Russellville, AR 72811
Attention: David Coyle
Project Name: VP -Emporia
Lot Number:VK07060
Date Completed:12/01/2020
NIM�I�Mr�
12/02/2020 2:33 PM
Approved and released by:
Project Manager II: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 12

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: VK07060
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W'
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low % solids the initial amount of these samples was 3 times the standard procedure amount per
PM's request. The LOQ has been adjusted accordingly.
% Volatile Solids
The following sample was analyzed outside of analytical holding time due to the test having been added
after the sample's expiration: VK07060-001.
Paint Filter
Samle -001 has been qualified with an "H", however, there is not a method defined hold time for this
parameter.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 12

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: VK07060
Sample Number Sample ID Matrix Date Sampled Date Received
001 VP -EMPORIA Solid 11/04/20201430 11/06/2020
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of12

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: VK07060
Sample Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
VP -EMPORIA
Solid
% Volatile Solids
SM 2540G-
28 H
%
5
001
VP -EMPORIA
Solid
Ammonia - N (gas
350.1
3500
mg/kg
5
001
VP -EMPORIA
Solid
Ignitability (Pensky-Martens
1010A
>140
° F
5
001
VP -EMPORIA
Solid
Nitrate -Nitrite - N (soluble)
353.2
50
mg/kg
5
001
VP -EMPORIA
Solid
Paint Filter Test
9095B
Fail H'
pass/fail
5
001
VP -EMPORIA
Solid
Phosphorus
365.1
4400
mg/kg
5
001
VP -EMPORIA
Solid
TKN
351.2
31000
mg/kg
5
001
VP -EMPORIA
Solid
Aluminum
6010D
39000
mg/kg
8
001
VP -EMPORIA
Solid
Arsenic
6010D
25
mg/kg
8
001
VP -EMPORIA
Solid
Calcium
6010D
10000
mg/kg
8
001
VP -EMPORIA
Solid
Copper
6010D
67
mg/kg
8
001
VP -EMPORIA
Solid
Lead
6010D
43
mg/kg
8
001
VP -EMPORIA
Solid
Zinc
6010D
300
mg/kg
8
(13 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4of12

Client: Terra Renewal Services, Inc. Laboratory ID:VK07060-001
Description: VP -EMPORIA Matrix: Solid
Date Sampled:11/04/2020 1430 % Solids: 1.47 11/07/2020 2016
Date Received:11/06/2020
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
11/25/2020 0153 MOM
74558
1 350.1
(Ammonia - N ) 350.1
5
11/25/2020 1212 CAG2
74610
1
(Ignitability) 1010A
1
11/16/2020 0844 KMC
73655
1
(Nitrate-Nitr) 353.2
1
11/24/2020 1428 AMR
74802
1
(Paint Filter) 9095B
1
11/16/2020 1114 KMC
1
(Phosphorus) 365.1
2
11/25/2020 1135 DMA
11/24/2020 2011 74700
1
(Reactive Cya) 7.3.3
1
11/17/2020 1846 KFE
11/13/2020 1957
1
(Reactive Sul) 7.3.4
1
11/13/2020 2305 SRB
11/13/2020 1957
1
(Soil pH meas) 9045D
1
11/12/2020 2338 AAB
73363
1 351.4
(TKN) 351.2
1
11/23/2020 0953 DMA
11/21/2020 1044 74362
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
28
H
%
1
Ammonia - N (gas diffusion)
350.1
3500
3400
mg/kg
1
Ignitability (Pensky-Martens Closed -Cup)
1010A
>140
140
o F
1
Nitrate -Nitrite - N (soluble)
353.2
50
14
mg/kg
1
Paint Filter Test
9095B
Fail
H"
pass/fail
1
Phosphorus
7723-14-0
365.1
4400
680
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 19.7 ° C
9045D
6.8
su
1
TKN
351.2
31000
1700
mg/kg
1
TCLP
Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 11/13/20201846
TML
73449 11/10/20201710
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
Units
Run
Benzene
71-43-2
8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3
8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5
8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7
8260D
ND
0.050
mg/L
1
Chloroform
67-66-3
8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2
8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4
8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4
8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6
8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4
8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5of12

Client: Terra Renewal Services, Inc. Laboratory ID:VK07060-001
Description: VP -EMPORIA Matrix: Solid
Date Sampled:11/04/2020 1430 % Solids: 1.47 11/07/2020 2016
)ate Received:11/06/2020
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
89 70-130
1,2-Dichloroethane-d4
95 70-130
Toluene-d8
100 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 11/22/2020 0120 SCD
11/12/2020 1800 73337 11/10/2020 2130
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
69 37-129
2-Fluorophenol
38 24-127
Nitrobenzene-d5
75 38-127
Phenol-d5
50 28-128
Terphenyl-d14
72 10-148
2,4,6-Tribromophenol
75 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 11/16/2020 1255 DAL1
11/12/2020 0205 73175 11/10/2020 2130
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
101 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time
W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6of12

Client: Terra Renewal Services, Inc. Laboratory ID:VK07060-001
Description: VP -EMPORIA Matrix: Solid
Date Sampled:11/04/2020 1430 % Solids: 1.47 11/07/2020 2016
Date Received:11/06/2020
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 11/25/2020 1651 DAL1 11/24/2020 1020 74581
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
1100
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
1100
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
1100
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
1100
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
1100
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
1100
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
1100
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
83 41-132
Tetrachloro-m-xylene
79 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 11/16/20201426 DAL1 11/12/20201600 73299 11/10/20202130
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC(Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
102 20-131
Tetrachloro-m-xylene
88 26-132
CVAA
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7471B 7471B 1 11/24/2020 0830 JAB2 11/24/2020 0540 74570
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury 7439-97-6 7471B ND 5.3 mg/kg 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7of12

Client: Terra Renewal Services, Inc. Laboratory ID:VK07060-001
Description: VP -EMPORIA Matrix: Solid
Date Sampled:11/04/2020 1430 % Solids: 1.47 11/07/2020 2016
Date Received:11/06/2020
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
6010D
1 11/12/2020 2123 KSH2
11/12/2020 0921 73147 11/10/2020 2130
1 1311/7470A
7470A
1 11/13/2020 1011 JAB2
11/13/2020 0405 73383 11/10/2020 2130
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
mg/L
1
Barium
7440-39-3 6010D
ND
0.25
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 11/25/2020 1805 JMH
11/24/2020 0457 74429
2 3050B
601OD
1 11/30/2020 1603 JMH
11/24/2020 0457 74429
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
39000
450
mg/kg
1
Arsenic
7440-38-2 6010D
25
17
mg/kg
1
Cadmium
7440-43-9 6010D
ND
5.7
mg/kg
1
Calcium
7440-70-2 6010D
10000
5700
mg/kg
1
Copper
7440-50-8 6010D
67
11
mg/kg
1
Lead
7439-92-1 6010D
43
11
mg/kg
1
Magnesium
7439-95-4 601OD
ND
5700
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
45
mg/kg
1
Nickel
7440-02-0 6010D
ND
45
mg/kg
1
Potassium
7440-09-7 6010D
ND
5700
mg/kg
1
Selenium
7782-49-2 6010D
ND
23
mg/kg
1
Sodium
7440-23-5 601OD
ND
5700
mg/kg
2
Zinc
7440-66-6 6010D
300
57
mg/kg
1
Footnote(s): 'Paint Filter: 82mL collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8of12

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9of12

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Ana' ais f
ach Ilstif
more
apaw i--ne*drd)
PV,7a
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qr
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AR
12p Code
71�94
1
K07060
Ran'ark&IC Marl.-Marl.
Oloo' Kama: YFO-E Oh
raJac' Number
R.0 No_
Caruic:Vany3Cdburn
pate IL15�
�,
No of owiRiners n �
J'n=�erwaliwe l' le
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unless other a rrerl amen:a Ere mode-
AFsW-Ff%Nl v
lccY 1 -Lv on Icc (Glicuh) �;y p;7r'k
Fiacelpi 13 * i `C
DoCJm6rYtHumb,a ME402OIhr'-01
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C�
rn
r^

PACE ANALYTICAL SERVICES, LLC
North Carolina Permit Parameters
2_ IbeSiduals s6al: 6� anHIy-wLcI r¢ 4CIDCvnStMJC tljEX
re e� s urce comervation
and Rccoviy Act (1tL'R.)_ The aara esrrnes'nryiy, ig,n;la�laili#y, re.kc#ivi and #oxgei
characterlstic l tx#Jg protedura ,(TMi 3 t�que�7cy pe iGed in
xi4 iwhrmrat A, and the Pexlnittee shall tuatataW thew results for 8 Tninirnum of five years. Any
exc ptinas fromfmmtw, requinis in tbi - noaditlon s1lmll be suecified in Atuick ent A
ul
Z
The TCI;P analysis slaalI inside the l'ol awing pamwe#ais (the rMulatary lt:v& in milligrams per liter
; in parantaeses):
Aiiric (5A)
Badum (100.0)
Benzene (0.5)
Cadmium (t _D)
Carbon t,e 4cblorsde (0,5)
Chlordaw (0.43)
Clal-oroberizene (100_1)
1,1c1MlQxobenze�� ('7,5)
1,2-DkW=et:hane (0.5)
1,l-i]i�lllc�roe€t:��lcnc (Q.?}
2.4-Dinihrotahitne (0.13)
Eudrin (0.02)
Huxarllorobenzene (0,13)
Heptachlor (and its, hydroxi4e)
f0_00Rl
itrobem (2.0)
Pail $=blorophonol (100.0)
PyrWjw (5-0)
Selenium (I A)
'FetMChLoro+otixylono
Texapheue (0-5)
i
Cfhlorafbrm {5A)
Hesxaeh'M'0-133-butadiene (0-5)
'rFi610 ,)pthylcno (0.5j
Chromium (5.D)
� ITffxad*vof-thane CIO)
7,,4,5-TridAor0p1icn1D1(400_G)
era-G�Frsol (?.00,0)
Load (.5.0)
2,4,6-Trioh1orophona1 (2.0)
o-Cresol (200.4)
p-Cresol 00,0)
Undane {0.4)
2,A,5-T? (Salve.) (1,0)
Mu=y (0,2)
Vinyl wolf& 0-2)
aesol (200.0)
Kethaxxchlor (10,0)
2A-D (10.U) " --
- - M,-thyl ethyl jAcMeeU{t_U
3. An .ana=ysis sL7a1 be condsctcd an xesiduaIs franc each source gemViag Acility at the fiWuenoy
specified in. AMdment A, and the Foirr ttee shall M' dataiu the results fo-- a r-iini mien of fwe years_
Tht aoalysiF shall ivavdo the following pnrameterr,
Aipmiffu ll.
Mercury
}�C�iSS1U'n
Ammonte-NitroM=
Molybdeuum
'Mckell
S elonllmn
— -- - Sodium
Arsenic
C;adarium
Nitrate-Nimte Nitrogc n
I
nlCiudc
Percem:t Total Bauch
'iKN
Copper
PH
Zino
Bead
M-.-IR lesixlm
Volatile 80.1ids
P 9'S
TERRA RENEWAL SERVICES
479-747-8192
wcwmims Vgrei, n 1 n Sheil Version_ 14C-2 :0 pace R of L2
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 12

PACE ANALYTICAL SERVICES, LLC
SN Mplet Receipt Cheoidlst (SRC) (ME0GIV—I5j Rf wAwd:91,2V2020
�r rhr: lyhC,r' Issuing Authority- Pace ENV WML page = of 1
Sample Receipt Checklist (Ski')
ciimt= :'LLKRARL:NL'WAL Cooler lrspecwby+date- VS(; } L1rMOM L I9, VK07060
MtiJW of rece- 0 Pace
Clint J UPS Othnr,
—
z`r
- N(3
L- Vdnre mstoc+r seals present an the cooleO
0
yc Na
_ ETA
3- IfGUSIVd S��L;� ti rc L�sg[r� were 1115y irlwtand anbrdcm'%
p[ [ Sttip ID: Ltik Chlorine St'ip ID, NA Tnmd,' by: NA
{ .-Oinxl Wirpe.-attire tivon itnecip; i DtTived (Correa) vanperature upon mceipl. %Solid SrMp-(.Up LD: U-1431
+S.S oC NA INA u(. NA )NFL ar NA INA
eLhad: MTe✓I?lpe_�.urC k3luk zaiLlst E4t[]e9 IR Gun 1L): 5 Llt GLD CIDMCl,'iflp T11"01. 0 �C
Mchod otooalart: d wut lcc O Ice Plick.3 ❑ Dry lc ❑ Nan. —
❑ Yr.S LINo ETI.4'. IfteLrpmw e uf any coolerexcea&e h.0°C, was Project Mwia&rs:rNo i z-.d'?
PM was Notified by, phone i cntai l l face-to-fatc 1a -cle otle).
No NA 4- Is the urmimcrciaI coLu'iei%piwking slip atEached to 7,is frwrn?
Yzs o 15. Were FLP[Xi 4-j5[ody pr•-coedurm (relinquishodri'eceived) follovrcd?
Y
No
16. Wel�SvmPic Ms listed on theOOC?
;. crx:sxmplp IDS listed an alLrumpleo0Irteillm
J 'cs
Nu
Ycs
No
S, Wars CU3ocLion date & time HaNd on the CDC^
1), Was CQI 1160fi7I] &te & time I I8Ltt1 on A sample 0"1 Aron-- ?
10- Did all container label irlforrnatron (lD, date, Lirn* 4g ,,vids the CQQ
O -yCS
Na
71 ifaa
❑No
f yce,
No
11. W(Te wscs to be i5; r%rrmtcd listed on the COC?
12.- Did all sumplo arriv3 ;r the prayer cnnrAiners Cor earth i�st an(Vor In good vmditipn
(LinhrrLkcr., ]ids ar, eic-)?
Yes
No
13. lip 35 pLleyuatz sampje volume available?
+M Yes
'No
14. Were al, sd[llples reeaive:i wishin % I -la holding tkng, or 48 homs, Whichever cam�g tlist,
Ycs
,/ No
15- Wer-O any seLLlp h--4 uminHersmissinW excess (circle one},3Lnrles Not listed Dii CL ,
16- For VOA and RSK••175 swnples, w= bubbles 1#Iesdlt `pea-si te" (Vi"Or 6mrn in dia1Y1aler)
1
El Yes
❑No
PINA
Im
any oftlle Y()A vials?
Ym
U No
MNAJ
17. Riem al DRCVmOW1s/nUrient Fare ltts roMeived a[ a p14 of d 27
U Y_0
t o
riEr4
i R. Were al l cvxn idp sarLrples reecIved at a pH � 12 and 5u liLdo sam Lei mrr, d- at a i-I > 9"
❑ Yes
LINO
❑J NA
19. Wcra all applicable , TKh4'cyansde anol625,11J < 0.SmWL, saa,pl free if
residh.Lal chlorinc"
❑Ycs
El No
[Z]NA
20. Were clientternarks 1+eque�ts (i,e, rcgiarsted diIIL[ions, M&MS€3de,yaguatisins: etc---)
curnaly transcribed front the COC ilma the tinmmmnt section in UMS"t
Yrs
N
21- Was ale, von number limd an the coritadicr Ialro39 If yvi, [hinter #
PreservaUnu (MUM be tOmpleted for any sampk(s) iororrertly proserved ar w;[h lit adspace.)
MMPLVkS) -^ WWU reoeiued i'1:c011tOly PrBSBLroed 04d w[:TC adjusned accarditt&ly
n ramp'¢ receivIng with —iul. nrcirrle; one: H28C)4, FW0 3,1TC1, NaOff using SR # -4A _
'irrle Of preser Aiun NA L= Tf mara thai one pi+e~ r utivc is needed, plewo note in the [a7ir]rnc[118 bel rrx-
tample{s) vA wcra received wifh }nibbles>6 mm in diamamr.
�s? "" _ _ were. itilxived Witb �I�C � i�,5 m�+�. Alt: # l9 is nn) and were
alovardinp)y ires rrLplorereivirg Mill: wdiurusninsuIFite (N%$7rOa) wihShealy] a, NA
ba.-Code Iahc is f lied b ' KRS
cmmeti Ls.
Date; [ I r7i242 D
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 12

LABORATORY ANALYSES:
- Seven Set Fecal Coliform Data

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 11/04/2020
Reported: 11 /06/2020
For: VP -Emporia Class B
Comments: GEOMETRIC MEAN <889 MPN/G
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
201104-27-01
Fecal Coliforms
F1
<847
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-01
Percent Solids
F1
2.36
%
SM2540B-2011
11/04/2020
WC
201104-27-02
Fecal Coliforms
F2
<995
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-02
Percent Solids
F2
2.01
%
SM2540B-2011
11/04/2020
WC
201104-27-03
Fecal Coliforms
F3
<962
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-03
Percent Solids
F3
2.08
%
SM2540B-2011
11/04/2020
WC
201104-27-04
Fecal Coliforms
F4
<858
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-04
Percent Solids
F4
2.33
%
SM2540B-2011
11/04/2020
WC
201104-27-05
Fecal Coliforms
F5
<905
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-05
Percent Solids
F5
2.21
%
SM2540B-2011
11/04/2020
WC
201104-27-06
Fecal Coliforms
F6
<844
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-06
Percent Solids
F6
2.37
%
SM2540B-2011
11/04/2020
WC
201104-27-07
Fecal Coliforms
F7
<826
MPN/g
SM92210E-2006
11/05/2020
WC
201104-27-07
Percent Solids
F7
2.42
%
SM2540B-2011
11/04/2020
WC
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 2

Client:
t-IAL. I WRTE�2
�WTiO,.iS
`+T'SVILLF
' r�P� MLYTICAL
122 Court Strcct • P.O. BOX 228
.` States,ille, NC 28687
(704> 872 4697
Chain of
" Custody Record
Address: 33�aS E2+.t r Avg
A
l LL-E- A 2 -7Z FA Z
Contact Person: Phone # FAX#
� n e,>Y �i-7g-7w�_sr�-2
PO # Requisitioned by: (7irne Date)
Customer
Sample ID#
Lab -ID #
Time Sampled
(Grab Only)
Date Sampled
(Grab Only)
a
'
Maax
Parameters requested ror analysis
sa,dge
w
ww
/�FL �
v • N
(;ouFo2•'I MNnr or cw
rl F2
•0
/l: 2'7Ar1
4
r t+S
7,9
2Sn
!r: R
�r
Ooo
rr �y
2 6
Il: -3I An
't
r
rr F6
21 W-
/1: 3rHn
"
✓
" F7
-37 An
Relinquished by: 1 q [fy
Time 2 am pm ate
Sampled by:. I
Received by:
Time qq2 apDate k/
?
Transported by:
Relinquished by:
Time am, pm Date / �_—
Holding times met:
Received by:
Time am, pm Date /
Compliance work:
Composite
Time begin am, pm Date T/ /_
Non-compliance work:
Time end am, pm Date I_I__
Lab Comments:
Samples Transported On Ice:
Composite Sampling #2:
Time begin am, pm Date. _ t
Time end am, pm Date I_
lnilials:
W
N
N
X
O
m
0
a

LABORATORY ANALYSES:
-Vector Attraction Reduction Data

;cal) Report Sleet
Project: VP - Emporia
30 Day Benchtop Test
CTS Proj_
002-051
Client: Denali Water Solutions
{EPA 6 5[R-921013, Appendix D)
Regulatory
Sampled
Received
Due
Ref, Methods
Std. Meth 191' ed.
By D. Coyle
By C,. Cameron
2540 G - TS
Date GVM20
Dare
02105120
Date
Requested Analysis
2540 G - VS
'type
Crab
Matrix
Sludge
Sample ID
Lab ID
TS *!a)
You (°)
A ate
Analyst
2002-H1-01
Stark (ti 2` )
1.79%
18.5
02foliz0
1.60%
18.3%
2114420
FVSR (ra.b.)
11.14%
1.67%
18.5%
NW213
FVSR (m.b)
7,03%
1.499%
28.4%
2r27120
r VSR (m.b.)
-27.72%
End (+ 30)
1.72%
18.5%
03106120
FVSR (rn_b.)
3.75%
Final Results
FVSR (rn.b.) 3.7 %
Pass, a 15%
Project Manager Date:
Notes: Sample starled at TS s 2%
Page 1

219 S. ate Sir.
Cameron Testing Services, Inc
Ftairt of Custody
Sarr►a.u. NC 27330
MM" 91!�-2384240 HC WnWGWCed 9P&54 NC PHFtS Lest 9 �7794 U$ EPA NCO1913 Page s
o i
O%TG A4 + 6-6xn wa, I'Emsrt:
..: . c►► . d .b is w.
CTS lab use
Contact_
hone:
—
;' n ple Temp CD
Addrrss(C.4y, QF &,-, siC
Fax:
i[?f a
` .�Sit`L•.r4a�C C•
t441e9;
Permit(Y�w)
ProjBCC V f Mirc 4-44
Rugh (YJN) i'llra
Sample
Gw C�61R: IYAll7a: 9"
y'4 4rAO IT k.E
+,+.JF• 3hM�:
✓
Sample Iniotyn orl
Nam tier Of bakties + e
uired TestinglAoalysis
Client Sample
w � -0
{Q
on CL ,� a 2
Pres�ervaUvea: (V)npreservvd, Hic-11,
t}, H{NP3.�TI51041k�iEC,
T
Sample
I}
J
C2I ! r
1D
14WC)H. 4PjftasFhneic.Other kXj,ledirate
14
.1f r4f 446 Fl-�7
-70
- -
TS
-
Reli. uished.
-
Received:
�y } j D�telTitr4e
-
Check -in
Rush work will require p of approval. Addiiional charges will apply

5
Annual Pathogen & Vector Attraction Reduction Form for NCAC 2T Rules
(FORM PVRF 2T)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc.
WWTP Name: Valley Proteins -Emporia, VA
Monitoring Period: From l/l/2020 To
WQ Permit Number: WQ0038835
NPDES Number: Out of State
12/31 /2020
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
Alt B (Alk Treatment)❑
Alt. C (Prior Testing)❑
A1t.D (No Prior Test)
1 Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑
Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
Gamma Ray ❑
Pasteurization ❑
Class B:
jAlt. (1) Fecal Density p
Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
Air Drying ❑
1 Composting ❑
jAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable Level
in Sludge
Pathogen Density
g ty
Number o
Excee-
dences
Frequency
ofAnalysis
Sample
Type
Analytical
Tech -
niciue
Minimum
Geo. Mean
Maximum
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
826
889
995
MPN/g
0
1/yr
Grab
92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt.I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
I Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) 0
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
'❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Environmental Manager
Preparer Name and Title (type or print)
,�- 5- ---
2/26/2021
Land Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

6
2020 SOIL TEST REPORTS

NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomi/
Report No.
FY21-SL013390
�5{i �141..tiL
Client:
David Coyle
Advisor:
Predictive
;•
Terra Renewal
r.
P.O. Box 1746
r, Soil Report Mehlich-3Extraction
Watkinsville, GA 30677
Links to Helpful Information
Sampled County : Gates
Client ID: 401799
Advisor ID:
Sampled: Received: 11/12/2020 Completed: 12/03/2020
Farm:
Sample ID: EM-5
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu
B
Information
Lime History:
1 -Corn, grain 0.7
120 - 160 0
50
25 0
0
0
0
0
Note: 3
2 -Small Grain (SG) 0.0
80-100 0
50
$ 0
0
0
0
0
Note: 3 Note:
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I Na
ESP
SS-1 NO3-N
0.51 1.31 4.0 67 1.3 5.4 103 47
51 9
36
85
68 61
73
73
116 0.1
3
Sample ID: EM-6
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O
Mg S
Mn
Zn
Cu
B
Information
Lime History:
1 -Corn, grain 0.5
120 - 160 0
50
0 0
0
0
0
0
Note: 3
2 -Small Grain (SG) 0.0
80-100 0
50
0 0
0
0
0
0
Note: 3
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2
Zn-I
Zn-AI
Cu-I Na
ESP
SS-1 NO3-N
1.14 1.25 5.6 73 1.5 5.7 124 43
60 9
69
56
51 44
564
564
212 0.1
2
Noah Carolina
i
I Awl'
fotciW frum fuWCurnml5skm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY21-SLO13390
David Coyle
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS%
% CEC occupied by basic cations
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg%
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
only on reports for greenhouse soil or problem samples.
Mn-All
Mn-availability index for crop 1
Mn-Al2
Mn-availability index for crop 2
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
Mn-
mineral -organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagr.gov/agronomi/pubs.htm.
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
P205
phosphate
S-1
sulfur index
Test Results
SS-1
soluble salt index
W/V
weight per volume
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-AI
zinc availability index
Zn-1
zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel
available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm