WQ0002883_2020 Residual Annual Report_20210226

Initial Review
Reviewer Thornburg, Nathaniel
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application what is the submittal type?* r Annual Report
r Residual Annual Report
r Additional Information
r Other
Annual Report Year* 2020
Permit Number (IR)* WQ0002883
Applicant/Permittee City of Elizabeth City
Email Notifications
Does this need review by the hydrogeologist?* 0 Yes r No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Rease provide information on the person to be contacted by N B Staff regarding electronic receipt, another correspondence. ittal, confirmation of iptd othd
.......................................................... ronc su_ -
Name * Drew Matthews
Email Address*
[e-mail]
Project Information
........ .................................................................................................................................................. .
Application/Document Type* r New (Fee Req ui red)
r Modification - Major (Fee Required)
r Renewal with Major Modification (Fee
Required)
r Annual Report
r Additional Information
r Other
Phone Number*
2528839301
O Modification - Minor
C Renewal
C GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
IT Residual Annual Report
r Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* r Wastewater Irrigation r High -Rate Infiltration
r Other Wastewater r Reclaimed Water
r Closed -Loop Recycle r Residuals
r Single -Family Residence Wastewater r Other
Irrigation
Permit Number:* WQ0002883
Fbs Current Existing permt number
Applicant/Permittee Address* PO Box347 Elizabeth City, NC 27907
Facility Name * City of Elizabeth City RLAP
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form Engineering Rans, Specifications, Calculations, Bc.)
2020 Elizabeth City Annual Report.pdf 16AMB
Upload only 1 PCFdocurrent (less than 250 MB). Multiple documents rust be contained into one FDFfile unless file is larger than
upload limit.
* V By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order
and made payable to the North Carolina Department of Environmental Quality
(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
a�f� (M&A"
Submission Date 2/26/2021

CITY OF ELIZABETH CITY
2020 ANNUAL LAND APPLICATION OF
RESIDUAL BIOSOLIDS REPORT
CLASS B PROGRAM
WQ0002883
Submitted by:
Soil Plus
PO Box 1396
Oxford, NC 27565
February 25, 2021
SOIL PLUS

SOIL PLUS
February 25, 2021
NCDEQ-DWR
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2020 LAND APPLICATION ANNUAL REPORT
Elizabeth City "Class B" Program
NC Permit No.: WQ002883
Soil Plus Project No. 200704.A10
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for the City of Elizabeth City on behalf of Atlantic
OBX, Inc. Soil Plus compiled this report using data gathered during the compliance year.
This data includes (1) certification form, (2) residual sampling, (3) field loading calculations,
(4) pathogen and vector attraction reduction documentation, (5) standard soil fertility
nutrient analysis.
The City of Elizabeth City conducted application events on permitted fields in Pasquotank
County during 2020. A total of 245.60 dry tons or 1,202,000 gallons of permitted residual
biosolids from the City's WWTP were land applied to permitted fields in WQ002883. An
additional 535.46 dry tons or 2,515,500 gallons were land applied under Atlantic OBX's
Class B permit WQ0000974. A total of 781.06 dry tons or 3,717,500 gallons were
generated by the City of Elizabeth City's WWTP in 2020.
A total of 401.65 dry tons or 568,000 gallons of permitted residuals from the City's WTP
were land applied as a Class B product to permitted fields in WQ002883. An additional
1,433.20 dry tons or 1,956,500 gallons of WTP residuals were distributed as a Class A
product under Atlantic OBX's Class A permit WQ0040622. A total of 1,834.85 dry tons or
2,524,500 gallons were generated by the City of Elizabeth City's WTP in 2020.
If there is any further information required or questions regarding this annual report, please
do not hesitate to contact me or the City of Elizabeth City (252-337-6626) for further
assistance.
Respectfully,
PO Box 1396
Drew Matthews, Soil Plus
Oxford, NC 27565
[phone]
Andrew Edwards, City of Elizabeth City
dmatthewsgsoapius.net
Raymond Staten, City of Elizabeth City
www.soilplus.net
J. Bryan Smith, Atlantic OBX

City of Elizabeth
City 2020 Annual
Land Application of
Residual Biosoilds
Report
WQ0002883
Elizabeth City, NC
ANNUAL
CERTIFICATION FORM
Source Summary
Field Loading Summary
RESIDUAL SAMPLING
SUMMARY FORMS
Elizabeth City WWTP
Elizabeth City WTP
FIELD SUMMARY
FORMS
PATHOGEN & VECTOR
REDUCTION FORMS
Elizabeth City WWTP
SOIL SAMPLES

City of Elizabeth City
2020 Class B Annual Report
WQ Permit# WQ0002883
Annual Certification Form
Source Summary
Field Loading Summary

ANNUAL LAND APPLICATION CERTIFICATION FORM
PermitNumber FacilityName Land Application Operator County Phone Number
WQ0002883 City of Elizabeth City
Year: 2020
Atlantic OBX Pasquotank [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Yes No
Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how ❑� A
the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: 162
Total number of fields utilized for land application during the year: 5
Total amount of dry tons applied during the year for all application sites: 647.26
Total number of acres utilized for land application during the year: 101.15
Part B - Annual Compliance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water (duality ❑d
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least G
3. annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
certified laboratory results are attached
G.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements as specified in the Land application Permit were complied with (applicable to 40 CFR Part 503 regulated
facilities).
8. all monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated
facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water (duality
10. No contravention of Ground Water (duality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
I � 6vjcll Aa Omtr,� av M�(-
Permitteyg..Name and Titl (type or print): '{ /
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
Thursday, February 11, 2021
k4o-
Sig#ore of Permittee Date
/4—C. 2/11 /2021
Signature of Land Applier Date
(if different from Permittee)

Source Summary Report
WWTP VolumeApplied Total
Elizabeth City WTP 568,000 401.65
Elizabeth City WW I'P 1,202,000 245.60
Total 1,770,000 647.26
Thursday, February 11, 2021 Page 1 of 1

Site# LL
YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED
CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
33
22.37
507,000
166.21 82.82
88.49
Wheat, Grain
111
74.6%
34
19.88
273,000
55.78 81.23
85.30
Wheat, Grain
111
73.2%
35
20.26
418,000
146.74 66.63
71.60
Wheat, Grain
111
60.0%
36
20.31
260,000
53.13 75.72
79.52
Wheat, Grain
111
68.2%
37
18.33
312,000
225.41 42.65
48.15
Wheat, Grain
111
38.4%
Total 1,770,000
Thursday, February 11, 2021
Page 1 of 1

City of Elizabeth City
2020 Class B Annual Report
WQ Permit# WQ0002883
Residual Sampling Summary Forms
Elizabeth City W fP
Elizabeth City WTP
Field Loading Calculations
2020 Analytical
2020 TCLP

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0002883 Facility Name City of Elizabeth City Source Permit No. NC0025011 Source Name Elizabeth City W WTP
Laboratory 1
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) Class A Class B
Pace An*fical
Pace Analytical
Pace Analytical
Pace Analytical
2/28/2020
5/?12/2020
8/7/2020
11/3/2020
Aluminum
N/A
N/A
12100
13,100
29,900
15,800
Ammonia Nitrogen
N/A
N/A
1,020
5,060
20,100
2,450
Arsenic
41
75
15.8
15.9
3
9.5
Cadmium
39
85
1.7
1.6
1.1
2
Calcium
N/A
N/A
110po
96,400
9,770
161,000
Copper
1,500
4,300
185
231
421
192
Lead
300
840
10.4
14.6
14.5
16.1
Magnesium
N/A
N/A
4,270
5,130
3,600
6,260
Mercury
17
57
0.22
0.24
0.016
0.046
Molybdenum
N/A
75
7.9
7.9
4.2
4.7
Nickel
420
420
9.5
9.9
17.7
10.2
Nitrate -Nitrite Nitrogen
N/A
N/A
80
73
90
53
Percent Solids
N/A
N/A
4.90
5.40
4.40
7.30
pH (no units)
N/A
N/A
Phosphorus
N/A
N/A
15,200
16,700
16,100
14,500
Potassium
N/A
N/A
7,920
7,930
3,180
4,730
PAN (Inj./Inc.)
N/A
N/A
14,984
17,475
29,460
9,208
PAN (Surface)
N/A
N/A
14,474
14,945
19,410
7,983
Selenium
100
100
15.8
13.9
5.5
9.5
Sodium
N/A
N/A
7,920
7,930
475
4,730
SAR
N/A
N/A
1.41
1.56
OM
0.85
TKN
N/A
N/A
47,300
46,200
51,000
24,800
Zinc
2,800
7,500
643
773
1100
775
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations"
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC Zr .1102 (26)

FIELD LOADING ESTIMATES
Facility Elizabeth City WWTP
Sampling Date 2/28/2020
Solids 4.9
Mineralization Rate 0.3
Gallons per DT 4,894.04
pH
Sodium Absorpotion 1.41 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 47,300 lbs./1,000 gal 19.33
Ammonia Nitrogen (mg/Kg) 1,020.00 lbs./1,000 gal 0.42
Nitrate -Nitrite (mg/Kg) 80.30 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 14,474 lbs./1,000 gal 5.92
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 14,984 lbs./1,000 gal 6.12
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.24
Phosphorus lbs./1,000 gal 6.21
Calcium lbs./1,000 gal 44.95
Magnesium lbs./1,000 gal 1.74
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
15.80
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
185.00
Copper lbs./1,000 gal
0.08
Lead (mg/Kg)
10.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.22
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
9.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
15.80
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
643.00
Zinc lbs./1,000 gal
0.26
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
47,300
14,474 28.95
32,826
47,300
14,984 29.97
32,316
32,826
4,924 9.85
27,902
32,316
4,847 9.69
27,468
27,902
2,093 4.19
25,809
27,468
2,060 4.12
25,408
25,809
968 1.94
24,841
25,408
953 1.91
24,455
24,841
466 0.93
24,376
24,455
459 0.92
23,997
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 22,924 45.85
Total 23,303 46.61

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 13, 2020
Rececca Miller
Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
Dear Rececca Miller:
Enclosed are the analytical results for sample(s) received by the laboratory on February 28, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Andrew Edwards, City of Elizabeth City
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 17

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
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Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92467277001 SLUDGE EPA6010D
SH1
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
NAL
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJH1
3
PASI-A
EPA 365.1 Rev 2.0 1993
KDF1
1
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
EPA9056
JDM
1
PASI-O
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
Sample: SLUDGE
Lab ID: 92467277001 Collected:
02/28/20 10:15 Received: 02/28/20 13:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture,
sample size and any dilutions.
Parameters
Results Units Report Limit
DF Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
12100 mg/kg
158
1 03/09/20 09:25
03/12/20 20:43
7429-90-5 M1
Arsenic
ND mg/kg
15.8
1 03/09/20 09:25
03/12/20 20:43
7440-38-2
Cadmium
1.7 mg/kg
1.6
1 03/09/20 09:25
03/12/20 20:43
7440-43-9
Calcium
110000 mg/kg
158
1 03/09/20 09:25
03/12/20 20:43
7440-70-2 M1
Chromium
20.9 mg/kg
7.9
1 03/09/20 09:25
03/12/20 20:43
7440-47-3
Copper
185 mg/kg
7.9
1 03/09/20 09:25
03/12/20 20:43
7440-50-8
Lead
10.4 mg/kg
7.9
1 03/09/20 09:25
03/12/20 20:43
7439-92-1
Magnesium
4270 mg/kg
158
1 03/09/20 09:25
03/12/20 20:43
7439-95-4
Molybdenum
ND mg/kg
7.9
1 03/09/20 09:25
03/12/20 20:43
7439-98-7
Nickel
9.5 mg/kg
7.9
1 03/09/20 09:25
03/12/20 20:43
7440-02-0
Potassium
ND mg/kg
7920
1 03/09/20 09:25
03/13/20 13:37
7440-09-7
Selenium
ND mg/kg
15.8
1 03/09/20 09:25
03/12/20 20:43
7782-49-2
Sodium
ND mg/kg
7920
1 03/09/20 09:25
03/13/20 13:37
7440-23-5
Zinc
643 mg/kg
15.8
1 03/09/20 09:25
03/12/20 20:43
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
0.22 mg/kg
0.038
1 03/10/2013:49
03/11/2018:33
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Total Solids
4.9 %
0.10
1
03/02/20 15:21
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
95.1 %
0.10
1
03/02/20 15:12
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Nitrogen, Ammonia
1020 mg/kg
191
1 03/04/20 11:00
03/04/20 22:23
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
47300 mg/kg
4610
5 03/03/20 12:53
03/04/20 05:29
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
80.3
1 02/29/20 14:28
02/29/20 16:26
Nitrogen, Nitrate
ND mg/kg
80.3
1 02/29/20 14:28
02/29/20 16:26
14797-55-8
Nitrogen, Nitrite
ND mg/kg
80.3
1 02/29/20 14:28
02/29/20 16:26
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
15200 mg/kg
304
15 03/04/2010:18
03/04/2013:40
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
3740 mg/kg
195
1 03/03/2010:48
03/03/2014:02
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056 Preparation Method: EPA 9056
Sulfate
ND mg/kg
1010
1 03/06/2012:00
03/06/2019:05
14808-79-8
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014
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 529229
Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471B
Analysis Description: 7471 Mercury
Associated Lab Samples: 92467277001
METHOD BLANK: 2826551
Matrix: Solid
Associated Lab Samples: 92467277001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0060
03/11/2017:45
LABORATORY CONTROL SAMPLE: 2826552
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.083 0.088
105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2826553 2826554
MS MSD
92467158001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/kg ND
0.047 0.047 0.049
0.056 104 118 75-125 13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 529214 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Associated Lab Samples: 92467277001
METHOD BLANK: 2826492
Associated Lab Samples: 92467277001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
03/12/20 20:37
Arsenic
mg/kg
ND
1.0
03/12/20 20:37
Cadmium
mg/kg
ND
0.10
03/12/20 20:37
Calcium
mg/kg
ND
10.0
03/12/20 20:37
Chromium
mg/kg
ND
0.50
03/12/20 20:37
Copper
mg/kg
ND
0.50
03/12/20 20:37
Lead
mg/kg
ND
0.50
03/12/20 20:37
Magnesium
mg/kg
ND
10.0
03/12/20 20:37
Molybdenum
mg/kg
ND
0.50
03/12/20 20:37
Nickel
mg/kg
ND
0.50
03/12/20 20:37
Potassium
mg/kg
ND
500
03/13/2013:30
Selenium
mg/kg
ND
1.0
03/12/20 20:37
Sodium
mg/kg
ND
500
03/13/2013:30
Zinc
mg/kg
ND
1.0
03/12/20 20:37
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2826493
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
500
506
101
80-120
Arsenic
mg/kg
50
45.6
91
80-120
Cadmium
mg/kg
50
48.2
96
80-120
Calcium
mg/kg
500
502
100
80-120
Chromium
mg/kg
50
49.9
100
80-120
Copper
mg/kg
50
51.2
102
80-120
Lead
mg/kg
50
49.5
99
80-120
Magnesium
mg/kg
500
480
96
80-120
Molybdenum
mg/kg
50
47.4
95
80-120
Nickel
mg/kg
50
50.2
100
80-120
Potassium
mg/kg
500
ND
97
80-120
Selenium
mg/kg
50
44.0
88
80-120
Sodium
mg/kg
500
489J
98
80-120
Zinc
mg/kg
50
47.3
95
80-120
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Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2826494 2826495
MS MSD
92467277001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Aluminum mg/kg 12100 7930 7930 22900 22400 137 131 75-125 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2826494
2826495
MS
MSD
92467277001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/kg
ND
793
793
762
720
95
89
75-125
6
Cadmium
mg/kg
1.7
793
793
783
742
99
93
75-125
5
Calcium
mg/kg
110000
7930
7930
122000
122000
162
160
75-125
0 M1
Chromium
mg/kg
20.9
793
793
838
795
103
98
75-125
5
Copper
mg/kg
185
793
793
1040
993
109
102
75-125
5
Lead
mg/kg
10.4
793
793
809
768
101
96
75-125
5
Magnesium
mg/kg
4270
7930
7930
12500
12100
104
99
75-125
3
Molybdenum
mg/kg
ND
793
793
781
739
98
93
75-125
6
Nickel
mg/kg
9.5
793
793
817
770
102
96
75-125
6
Potassium
mg/kg
ND
7930
7930
13100
12900
107
104
75-125
2
Selenium
mg/kg
ND
793
793
720
695
91
88
75-125
3
Sodium
mg/kg
ND
7930
7930
9990
9510
107
101
75-125
5
Zinc
mg/kg
643
793
793
1440
1400
100
95
75-125
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 528016 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92467277001
SAMPLE DUPLICATE: 2820772
92467337001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 15.3 15.2 0
SAMPLE DUPLICATE: 2820773
92467448010 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 16.1 17.5 9
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Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 528380
Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod.
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92467277001
METHOD BLANK: 2822256
Matrix: Solid
Associated Lab Samples: 92467277001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/kg
ND 8.9
03/04/20 21:50
LABORATORY CONTROL SAMPLE: 2822257
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg
385
389
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2822258
2822259
MS
MSD
92466125001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/kg 268
1530
1620 1650
1980 90 106
90-110 18 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2822260
2822261
MS
MSD
92466924002
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/kg 29.9
571
571 608
611 101 102
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 528080
Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Associated Lab Samples: 92467277001
METHOD BLANK: 2820995
Matrix: Solid
Associated Lab Samples: 92467277001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
ND 50.0
03/04/20 04:33
LABORATORY CONTROL SAMPLE: 2820996
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
1000
1020
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2820997
2820998
MS
MSD
92466125001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg ND
2790
3170 2540
3090 88 95
90-110 20 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2820999
2821000
MS
MSD
92467299001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 21400
4090
4800 22500
23200 26 38
90-110 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 527834
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite
Associated Lab Samples: 92467277001
METHOD BLANK: 2819972
Matrix: Solid
Associated Lab Samples: 92467277001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
02/29/20 16:24
Nitrogen, Nitrite
mg/kg
ND 4.0
02/29/20 16:24
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
02/29/20 16:24
LABORATORY CONTROL SAMPLE: 2819973
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/kg
15 15.4
102 90-110
Nitrogen, Nitrite
mg/kg
10 10.1
101 90-110
Nitrogen, NO2 plus NO3
mg/kg
25 25.5
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2819974 2819975
MS MSD
92467277001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/kg
ND
300 300 329
329 110 110
90-110 0
Nitrogen, Nitrite mg/kg
ND
199 199 227
227 105 105
90-110 0
Nitrogen, NO2 plus NO3 mg/kg
ND
499 499 555
556 107 107
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 528191
Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92467277001
METHOD BLANK: 2821467
Matrix: Solid
Associated Lab Samples: 92467277001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Phosphorus mg/kg
ND 1.0
03/04/2013:25
LABORATORY CONTROL SAMPLE: 2821468
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Phosphorus mg/kg
50
50.2
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2821469
2821470
MS
MSD
92466575001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Phosphorus mg/kg 75.5
87.3
94 223
231 169 165
90-110 3 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2821471
2821472
MS
MSD
92466656001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Phosphorus mg/kg 10.5
45.6
49.1 50.4
53.2 88 87
90-110 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 528116
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Associated Lab Samples: 92467277001
METHOD BLANK: 2821077
Matrix: Solid
Associated Lab Samples: 92467277001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Chloride mg/kg
ND 9.8
03/03/2013:38
LABORATORY CONTROL SAMPLE: 2821078
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Chloride mg/kg
198
206
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2821079
2821080
MS
MSD
92466690006
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/kg 48.3
111
112 161
163 101
102
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2821081
2821082
MS
MSD
92466690007
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/kg 212
115
113 344
337 115
110
90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
QC Batch: 615742
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92467277001
METHOD BLANK: 3346427
Matrix: Solid
Associated Lab Samples: 92467277001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Sulfate
mg/kg
ND 49.6
03/06/2014:13
LABORATORY CONTROL SAMPLE: 3346428
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Sulfate
mg/kg
499 474
95
80-120
MATRIX SPIKE SAMPLE: 3346430
35534263010 Spike
MS
MS % Rec
Parameter
Units
Result Conc.
Result
% Rec Limits Qualifiers
Sulfate
mg/kg
25.71-1 514
625
118 80-120
SAMPLE DUPLICATE: 3346429
35534263010 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Sulfate
mg/kg
25.71-1 ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALIFIERS
Project: QUARTERLY SLUDGE
Pace Project No.: 92467277
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
Pace Analytical Services, LLC
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TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
QUARTERLY SLUDGE
92467277
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92467277001
SLUDGE
EPA 3050B
529214
EPA 6010D
529325
92467277001
SLUDGE
EPA 7471 B
529229
EPA 7471 B
529569
92467277001
SLUDGE
SM 2540G-2011
528462
92467277001
SLUDGE
ASTM D2974-87
528016
92467277001
SLUDGE
EPA 350.1 Rev 2.0 1993
528380
EPA 350.1 Rev 2.0 1993
528431
Mod.
Mod.
92467277001
SLUDGE
EPA 351.2 Rev 2.0 1993
528080
EPA 351.2 Rev 2.0 1993
528336
92467277001
SLUDGE
EPA 353.2 Rev 2.0 1993
527834
EPA 353.2 Rev 2.0 1993
527836
92467277001
SLUDGE
EPA 365.1 Rev 2.0 1993
528191
EPA 365.1 Rev 2.0 1993
528426
92467277001
SLUDGE
SM 4500-CI-E-2011
528116
SM 4500-CI-E-2011
528165
92467277001
SLUDGE
EPA 9056
615742
EPA 9056
615756
Date: 03/13/2020 04:56 PM
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Rebevca Miller
rmiller(s cityofec.com
•• Preservmfivelyuts:(11 nitric a rid, l7}ruBvhc add.[31 hydrod,✓or id,[4)N fi,m hvd.eaida,isSxiKacraee,
I61 methanol,[7) sodlum K Here,(a)setllum*I*wlfaM,(9)homer:(Ar acerbic acid. (B) anurronium aullate,
aedwardsQbtvofec.cam
Site Collection Info/Address:
ICJ amrtwniumhydrnide, (a)TSP, [nF Unprest—t (0) other
Orrarterly W WTP Residuals
Elizabeth City. NC 27909
Afta?ysu
an".im •
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Cc7tod SGu3"C3l;lA`,=Y
s
N,
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252-339-3331 -Site/Facility
I
]DO;
Compliance Monitoring?
I 1 Yes [ ] No
li Fri
Purchase Order 0:
DW PINS ID
n�
e#
DW Location Cade:
:.
m
-
r'
S e ce
llect ByIIsfg u l:
7umaround Date Requlsed:
Immediately Pac ked
�,
on Ice:
Yes
kl
a
_
-'
t�.L
S, Is'
Tolcaeseas approw,afe [ I Rctum
Rush:
[ ] Same Day I I Next Day
Field Flhered (Rapp ume}:
I 1 Yes [ 1 No
e+ive.
j ]20ay I 13Day I 140ay 1 ]50ay
IL
7.--
eG
I lliyr
}Expedue [homes Apply)
Analysis:
-
O
•Matrix Codes(lnsen In Matrix box belewl:Drinking
Water(DW), Ground Water(GW], Wastewater(WW),
Producr (P), 5oiV5oRd (SL}, CIII (OL), Wipe (WP), Air [ARI. Tmsue (lS1. Bloassay (B), Vapor M, Other (OTi
, ,
"�.
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t�,S M' .aCC CAIIrS[[+'
} ASS �:Y�. _'��
Rernqulsh
W � parts Signature]
Date �
Received /Co Si nature}
Date�me;
.r,MT1CSrvlei[L56igN �
- '� '?�y
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Rerrlved by/Company: (Signature)
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elinquished by/Company: ISlgnatum)
Date/time:Received
by/Company: (Signature}
Date/i1mC:
I!r.
N
(D

FIELD LOADING ESTIMATES
Facility Elizabeth City WWTP
Sampling Date 5/22/2020
Solids 5.4
Mineralization Rate 0.3
Gallons per DT 4,440.89
pH
Sodium Absorpotion 1.56 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 46,200 lbs./1,000 gal 20.81
Ammonia Nitrogen (mg/Kg) 5,060.00 lbs./1,000 gal 2.28
Nitrate -Nitrite (mg/Kg) 72.70 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 14,945 lbs./1,000 gal 6.73
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 17,475 lbs./1,000 gal 7.87
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.57
Phosphorus lbs./1,000 gal 7.52
Calcium lbs./1,000 gal 43.41
Magnesium lbs./1,000 gal 2.31
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
15.90
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.60
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
231.00
Copper lbs./1,000 gal
0.10
Lead (mg/Kg)
14.60
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.24
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
8.90
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
15.90
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
773.00
Zinc lbs./1,000 gal
0.35
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
46,200
14,945 29.89
31,255
46,200
17,475 34.95
28,725
31,255
4,688 9.38
26,567
28,725
4,309 8.62
24,417
26,567
1,993 3.99
24,574
24,417
1,831 3.66
22,585
24,574
922 1.84
23,653
22,585
847 1.69
21,738
23,653
443 0.89
23,209
21,738
408 0.82
21,331
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 22,991 45.98
Total 24,869 49.74

(�Ia'ne Analytical
www.pacolahs.com
June 08, 2020
Rececca Miller
Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Dear Rececca Miller:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on May 22, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,f
/ ' Q_
Clayton McCrickard for
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Andrew Edwards, City of Elizabeth City
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 19

(�Ia'ne Analytical
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SAMPLE ANALYTE COUNT
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92478803001 Sludge EPA 6010D
IDS
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
CJH1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJH1
3
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
EPA9056
CMB
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 19

(�Ia'ne Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge Lab ID: 92478803001 Collected: 05/22/20 09:44 Received: 05/22/20 13:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
15100 mg/kg
159
1 05/27/20 07:55
06/01/20 12:27
7429-90-5
Arsenic
ND mg/kg
15.9
1 05/27/20 07:55
06/01/20 12:27
7440-38-2
Cadmium
ND mg/kg
1.6
1 05/27/20 07:55
06/01/20 12:27
7440-43-9
Calcium
96400 mg/kg
159
1 05/27/20 07:55
06/01/20 12:27
7440-70-2
Chromium
19.0 mg/kg
7.9
1 05/27/20 07:55
06/01/20 12:27
7440-47-3
Copper
231 mg/kg
7.9
1 05/27/20 07:55
06/01/20 12:27
7440-50-8
Lead
14.6 mg/kg
7.9
1 05/27/20 07:55
06/01/20 12:27
7439-92-1
Magnesium
5130 mg/kg
159
1 05/27/20 07:55
06/01/20 12:27
7439-95-4
Molybdenum
ND mg/kg
7.9
1 05/27/20 07:55
06/01/20 12:27
7439-98-7
Nickel
8.9 mg/kg
7.9
1 05/27/20 07:55
06/01/20 12:27
7440-02-0
Potassium
ND mg/kg
7930
1 05/27/20 07:55
06/01/20 12:27
7440-09-7
Selenium
ND mg/kg
15.9
1 05/27/20 07:55
06/01/20 12:27
7782-49-2
Sodium
ND mg/kg
7930
1 05/27/20 07:55
06/01/20 12:27
7440-23-5
Zinc
773 mg/kg
15.9
1 05/27/20 07:55
06/01/20 12:27
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation
Method:
EPA 7471 B
Pace Analytical Services - Asheville
Mercury
0.24 mg/kg
0.045
1 05/27/2013:17
05/28/2014:17
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
5.4 %
0.10
1
05/26/20 16:40
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
94.6 %
0.10
1
05/26/20 16:27
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
5060 mg/kg
180
1 06/06/20 11:50
06/06/20 13:33
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
46200 mg/kg
2710
5 05/29/20 13:41
05/30/20 07:35
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
72.7
1 05/23/20 14:45
05/23/20 16:56
Nitrogen, Nitrate
ND mg/kg
72.7
1 05/23/20 14:45
05/23/20 16:56
14797-55-8
Nitrogen, Nitrite
ND mg/kg
72.7
1 05/23/20 14:45
05/23/20 16:56
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
16700 mg/kg
329
20 05/26/2019:21
05/27/2019:06
7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/08/2020 08:49 AM
without the written consent of Pace Analytical
Services, LLC.
Page 4 of 19

(�Ia'ne Analytical
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ANALYTICAL RESULTS
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge Lab ID: 92478803001 Collected: 05/22/20 09:44 Received: 05/22/20 13:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 3330 mg/kg 181 1 05/28/20 15:24 05/28/20 20:05 16887-00-6
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 79.7 mg/kg 49.8 1 05/28/2017:45 05/29/2016:31 14808-79-8
Date: 06/08/2020 08:49 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 19

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543684 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2895547
Associated Lab Samples: 92478803001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 2895548
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0060 05/27/2015:37
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.083 0.075 90 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2895549 2895550
MS MSD
92478874004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.049 0.053 0.05 0.087 0.080 72 63 75-125 9 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/08/2020 08:49 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 19

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543576 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2895076
Associated Lab Samples: 92478803001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
06/01/2011:52
Arsenic
mg/kg
ND
1.0
06/01/2011:52
Cadmium
mg/kg
ND
0.10
06/01/2011:52
Calcium
mg/kg
ND
10.0
06/01/2011:52
Chromium
mg/kg
ND
0.50
06/01/2011:52
Copper
mg/kg
ND
0.50
06/01/2011:52
Lead
mg/kg
ND
0.50
06/01/2011:52
Magnesium
mg/kg
ND
10.0
06/01/2011:52
Molybdenum
mg/kg
ND
0.50
06/01/2011:52
Nickel
mg/kg
ND
0.50
06/01/2011:52
Potassium
mg/kg
ND
500
06/01/2011:52
Selenium
mg/kg
ND
1.0
06/01/2011:52
Sodium
mg/kg
ND
500
06/01/2011:52
Zinc
mg/kg
ND
1.0
06/01/2011:52
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2895077
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
500
507
101
80-120
Arsenic
mg/kg
50
49.4
99
80-120
Cadmium
mg/kg
50
49.7
99
80-120
Calcium
mg/kg
500
506
101
80-120
Chromium
mg/kg
50
51.5
103
80-120
Copper
mg/kg
50
51.8
104
80-120
Lead
mg/kg
50
50.8
102
80-120
Magnesium
mg/kg
500
490
98
80-120
Molybdenum
mg/kg
50
53.6
107
80-120
Nickel
mg/kg
50
51.4
103
80-120
Potassium
mg/kg
500
ND
100
80-120
Selenium
mg/kg
50
47.6
95
80-120
Sodium
mg/kg
500
507
101
80-120
Zinc
mg/kg
50
48.8
98
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/08/2020 08:49 AM without the written consent of Pace Analytical Services, LLC.
Page 7 of 19

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2895078
2895079
MS
MSD
92477099005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
9550
426
446
14400
14500
1140
1100
75-125
0 M1
Arsenic
mg/kg
9.3
42.6
44.6
45.8
49.7
86
91
75-125
8
Cadmium
mg/kg
0.0811
42.6
44.6
40.3
42.9
94
96
75-125
6
Calcium
mg/kg
127
426
446
544
551
98
95
75-125
1
Chromium
mg/kg
13.7
42.6
44.6
59.2
61.3
107
107
75-125
4
Copper
mg/kg
4.0
42.6
44.6
47.7
50.4
103
104
75-125
6
Lead
mg/kg
11.2
42.6
44.6
49.2
52.5
89
93
75-125
7
Magnesium
mg/kg
312
426
446
865
872
130
126
75-125
1 M1
Molybdenum
mg/kg
0.35J
42.6
44.6
38.1
41.5
89
92
75-125
8
Nickel
mg/kg
2.9
42.6
44.6
45.4
47.9
100
101
75-125
5
Potassium
mg/kg
ND
426
446
816
825
136
132
75-125
1 M1
Selenium
mg/kg
1.1
42.6
44.6
36.6
38.8
83
85
75-125
6
Sodium
mg/kg
ND
426
446
469
453
108
99
75-125
3
Zinc
mg/kg
36.0
42.6
44.6
72.4
74.3
86
86
75-125
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543455 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92478803001
SAMPLE DUPLICATE: 2894685
2631868003 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 77.5 77.3 0
SAMPLE DUPLICATE: 2894913
92478803001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 94.6 94.5 0
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 545665 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2905370
Associated Lab Samples: 92478803001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 2905371
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 06/06/20 13:28
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 488 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2905372 2905373
MS MSD
92478803001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 5060 9020 9020 14400 14300 103 102 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 544098 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2897586
Associated Lab Samples: 92478803001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 2897587
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 05/30/20 06:21
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 1010 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2897588 2897589
MS MSD
92477874001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 350 287 20 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543285 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2893938
Matrix: Solid
Associated Lab Samples: 92478803001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
05/23/20 16:54
Nitrogen, Nitrite
mg/kg
ND 4.0
05/23/20 16:54
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
05/23/20 16:54
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 2893939
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.7 105 90-110
Nitrogen, Nitrite mg/kg 10 10 100 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.7 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2893940
2893941
MS
MSD
92478803001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
259
274
271
289
104
106
90-110 6
Nitrogen, Nitrite
mg/kg
ND
173
182
189
197
101
101
90-110 4
Nitrogen, NO2 plus NO3
mg/kg
ND
432
456
460
486
104
105
90-110 6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543496 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2894865
Associated Lab Samples: 92478803001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 2894866
Parameter Units
Phosphorus mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.86 05/27/2019:00
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
43.1 43.8 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2894867 2894868
MS MSD
92478556001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 125 80.5 85.2 302 283 220 185 90-110 7 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2894869 2894870
MS MSD
92478556002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 184 98 83.5 305 243 124 71 90-110 22 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
QC Batch: 543970 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92478803001
METHOD BLANK: 2896989
Associated Lab Samples: 92478803001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 2896990
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 05/28/20 20:03
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 202 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2896991 2896992
MS MSD
92478803001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 3330 1800 1820 5180 5160 103 100 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 636482 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92478803001
METHOD BLANK: 3460884
Associated Lab Samples: 92478803001
Parameter
Units
Sulfate
mg/kg
LABORATORY CONTROL SAMPLE:
3460885
Parameter
Units
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
3460887
Parameter
Units
Sulfate
mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 49.9 05/29/2012:24
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
499 473 95 80-120
2632016001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
4940 2470 7800 115 80-120 E
SAMPLE DUPLICATE: 3460886
2632016001 Dup
Parameter Units Result Result
Sulfate mg/kg 4940 4940
RPD Qualifiers
0 E
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALIFIERS
Project: Quarterly Sludge Sample 5/22
Pace Project No.: 92478803
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Quarterly Sludge Sample 5/22
92478803
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92478803001
Sludge
EPA 3050B
543576
EPA 6010D
543698
92478803001
Sludge
EPA 7471B
543684
EPA 7471B
543725
92478803001
Sludge
SM 2540G-2011
543666
92478803001
Sludge
ASTM D2974-87
543455
92478803001
Sludge
EPA 350.1 Rev 2.0 1993
545665
EPA 350.1 Rev 2.0 1993
545694
Mod.
Mod.
92478803001
Sludge
EPA 351.2 Rev 2.0 1993
544098
EPA 351.2 Rev 2.0 1993
544266
92478803001
Sludge
EPA 353.2 Rev 2.0 1993
543285
EPA 353.2 Rev 2.0 1993
543288
92478803001
Sludge
EPA 365.1 Rev 2.0 1993
543496
EPA 365.1 Rev 2.0 1993
543527
92478803001
Sludge
SM 4500-CI-E-2011
543970
SM 4500-CI-E-2011
543983
92478803001
Sludge
EPA 9056
636482
EPA 9056
636558
Date: 06/08/2020 08:49 AM
REPORT OF LABORATORY ANALYSIS
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Page 17 of 19

WO#:92478503
N

Document Name:
Document Issued: Marco 14, 2019
Battle Identiffeatlon Form (81F)
Page 1 of i
Document No.:
lssuing Authority:
�,,,,p�
F-CAR-CS-043-Rev.00
Pace Carolinas QuP14 Office
'Check marls top half of box if pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Eaeptloas: VOA, Coliform, TOC, oil and Grease, DAO/8015 (waterl DOC, LLHg
*•Bottom half of box is to list number of bottle
Project N
on
means
■
MOOSE
'a
pH Adjustment log for Preserved Samples
Sample ID
Type of Preservative
pH upon tecalpt
Date preservation adjusted
Time preserwtfon
adjusted
Amount of Preservrtiva
added
Lot
Note: Whenever0tre is a discrepancy atrecung nortn Ldfaana—Pnsn- smr-p-�.,u�wr�••••-•• •••••--•-••••-•••-
Out of hold, Incorre[t preservative, out of temp, Incorraet Contalnem.
Page 19 of 19

FIELD LOADING ESTIMATES
Facility Elizabeth City WWTP
Sampling Date 8/7/2020
Solids 4.4
Mineralization Rate 0.3
Gallons per DT 5,450.19
pH
Sodium Absorpotion 0.22 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 51,000 lbs./1,000 gal 18.71
Ammonia Nitrogen (mg/Kg) 20,100.00 lbs./1,000 gal 7.38
Nitrate -Nitrite (mg/Kg) 90.30 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 19,410 lbs./1,000 gal 7.12
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 29,460 lbs./1,000 gal 10.81
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 1.17
Phosphorus lbs./1,000 gal 5.91
Calcium lbs./1,000 gal 3.59
Magnesium lbs./1,000 gal 1.32
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.10
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
421.00
Copper lbs./1,000 gal
0.15
Lead (mg/Kg)
14.50
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.02
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
17.70
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
5.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
1100.00
Zinc lbs./1,000 gal
0.40
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
51,000
19,410 38.82
31,590
51,000
29,460 58.92
21,540
31,590
4,738 9.48
26,851
21,540
3,231 6.46
18,309
26,851
2,014 4.03
24,837
18,309
1,373 2.75
16,936
24,837
931 1.86
23,906
16,936
635 1.27
16,301
23,906
448 0.90
23,458
16,301
306 0.61
15,995
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 27,542 55.08
Total 35,005 70.01

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 24, 2020
Rececca Miller
Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: PLANT SLUDGE
Pace Project No.: 92489767
Dear Rececca Miller:
Enclosed are the analytical results for sample(s) received by the laboratory on August 07, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Andrew Edwards, City of Elizabeth City
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
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Page 1 of 18

014
aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: PLANT SLUDGE
Pace Project No.: 92489767
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
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SAMPLE ANALYTE COUNT
Project: PLANT SLUDGE
Pace Project No.: 92489767
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92489767001 WW PLANT SLUDGE EPA6010D
DS
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
92489767002 WW PLANT SLUDGE SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
3
PASI-A
EPA 365.1 Rev 2.0 1993
DMN
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
EPA9056
YMP
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: PLANT SLUDGE
Pace Project No.: 92489767
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW PLANT SLUDGE Lab ID: 92489767001 Collected: 08/07/20 09:00 Received: 08/07/20 13:48 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical
Services - Asheville
Aluminum
29900
mg/kg
65.8
10
08/10/20 20:13
08/11/20 18:34
7429-90-5
Arsenic
3.0
mg/kg
0.66
1
08/10/20 20:13
08/11/20 16:27
7440-38-2
Cadmium
1.1
mg/kg
0.066
1
08/10/20 20:13
08/11/20 16:27
7440-43-9
Calcium
9770
mg/kg
65.8
10
08/10/20 20:13
08/11/20 18:34
7440-70-2
Chromium
23.4
mg/kg
0.33
1
08/10/20 20:13
08/11/20 16:27
7440-47-3
Copper
421
mg/kg
0.33
1
08/10/20 20:13
08/11/20 16:27
7440-50-8
Lead
14.5
mg/kg
0.33
1
08/10/20 20:13
08/11/20 16:27
7439-92-1
Magnesium
3600
mg/kg
6.6
1
08/10/20 20:13
08/11/20 16:27
7439-95-4
Molybdenum
4.2
mg/kg
0.33
1
08/10/20 20:13
08/11/20 16:27
7439-98-7
Nickel
17.7
mg/kg
0.33
1
08/10/20 20:13
08/11/20 16:27
7440-02-0
Potassium
3180
mg/kg
329
1
08/10/20 20:13
08/11/20 16:27
7440-09-7
Selenium
5.5
mg/kg
0.66
1
08/10/20 20:13
08/11/20 16:27
7782-49-2
Sodium
475
mg/kg
329
1
08/10/20 20:13
08/11/20 16:27
7440-23-5
Zinc
1100
mg/kg
6.6
10
08/10/20 20:13
08/11/20 18:34
7440-66-6
7471 Mercury
Analytical Method:
EPA 7471 B Preparation Method:
EPA 7471 B
Pace Analytical
Services - Asheville
Mercury
0.016
mg/kg
0.0041
1
08/10/20 20:20
08/11/20 16:38
7439-97-6
Sample: WW PLANT SLUDGE Lab ID: 92489767002 Collected: 08/07/20 09:00 Received: 08/07/20 13:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
4.4 % 0.10
1 08/10/20 15:54
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
95.6 % 0.10
1 08/10/20 15:41
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method: EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
20100 mg/kg 211
1 08/11/20 07:33 08/11/20 11:15 7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
51000 mg/kg 4380
5 08/18/20 13:50 08/19/20 05:33 7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg 90.3
1 08/08/20 12:11 08/08/20 13:12
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: PLANT SLUDGE
Pace Project No.: 92489767
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW PLANT SLUDGE Lab ID: 92489767002 Collected: 08/07/20 09:00 Received: 08/07/20 13:48 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
ND mg/kg 90.3 1 08/08/20 12:11 08/08/20 13:12 14797-55-8
Nitrogen, Nitrite
ND mg/kg 90.3 1 08/08/20 12:11 08/08/20 13:12 14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
16100 mg/kg 328 15 08/10/2015:57 08/11/2010:21 7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
3470 mg/kg 226 1 08/10/20 21:49 08/11/20 00:25 16887-00-6
9056 IC Anions
Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate
1150 mg/kg 1130 1 08/11/20 15:00 08/12/20 20:54 14808-79-8
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 559034 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767001
METHOD BLANK: 2966258
Associated Lab Samples: 92489767001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 2966259
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0060 08/11 /20 16:19
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.083 0.087 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2966260 2966261
MS MSD
92489694001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.012 0.078 0.082 0.091 0.10 99 106 75-125 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 559033 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767001
METHOD BLANK: 2966254
Associated Lab Samples: 92489767001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
08/11/2015:38
Arsenic
mg/kg
ND
1.0
08/11/2015:38
Cadmium
mg/kg
ND
0.10
08/11/2015:38
Calcium
mg/kg
ND
10.0
08/11/2015:38
Chromium
mg/kg
ND
0.50
08/11/2015:38
Copper
mg/kg
ND
0.50
08/11/2015:38
Lead
mg/kg
ND
0.50
08/11/2015:38
Magnesium
mg/kg
ND
10.0
08/11/2015:38
Molybdenum
mg/kg
ND
0.50
08/11/2015:38
Nickel
mg/kg
ND
0.50
08/11/2015:38
Potassium
mg/kg
ND
500
08/11/2015:38
Selenium
mg/kg
ND
1.0
08/11/2015:38
Sodium
mg/kg
ND
500
08/11/2015:38
Zinc
mg/kg
ND
1.0
08/11/2015:38
LABORATORY CONTROL SAMPLE:
2966255
Parameter
Units
Aluminum
mg/kg
Arsenic
mg/kg
Cadmium
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Lead
mg/kg
Magnesium
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Selenium
mg/kg
Sodium
mg/kg
Zinc
mg/kg
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
500
493
99
80-120
50
49.5
99
80-120
50
48.7
97
80-120
500
478
96
80-120
50
49.7
99
80-120
50
51.8
104
80-120
50
49.6
99
80-120
500
479
96
80-120
50
50.8
102
80-120
50
50.3
101
80-120
500
ND
98
80-120
50
46.4
93
80-120
500
498J
100
80-120
50
46.9
94
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: PLANT SLUDGE
Pace Project No.: 92489767
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2966256
2966257
MS
MSD
92489015002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
34000
530
540
51600
44600
3320
1960
75-125
15 E,M1
Arsenic
mg/kg
6.9
53
54
51.2
51.8
84
83
75-125
1
Cadmium
mg/kg
0.092J
53
54
47.1
48.8
89
90
75-125
3
Calcium
mg/kg
1160
530
540
1680
1540
98
69
75-125
9 M1
Chromium
mg/kg
33.8
53
54
85.7
80.4
98
86
75-125
6
Copper
mg/kg
20.5
53
54
82.7
80.0
117
110
75-125
3
Lead
mg/kg
13.9
53
54
59.3
58.3
86
82
75-125
2
Magnesium
mg/kg
1400
530
540
2530
2350
213
175
75-125
8 M1
Molybdenum
mg/kg
1.2
53
54
42.6
44.7
78
81
75-125
5
Nickel
mg/kg
10.9
53
54
63.5
62.7
99
96
75-125
1
Potassium
mg/kg
1620
530
540
2830
2780
229
215
75-125
2 M1
Selenium
mg/kg
1.4
53
54
42.9
43.5
78
78
75-125
1
Sodium
mg/kg
ND
530
540
637
628
96
92
75-125
1
Zinc
mg/kg
37.4
53
54
107
101
130
118
75-125
6 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 558995 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92489767002
SAMPLE DUPLICATE: 2966077
92489845001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 21.6 18.8 14
SAMPLE DUPLICATE: 2966078
92489910001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 18.1 19.1 5
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 558962 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767002
METHOD BLANK: 2965907
Associated Lab Samples: 92489767002
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 2965908
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.3 08/11 /20 10:47
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
490 492 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965909 2965910
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg ND 4890 5670 4870 5590 99 99 90-110 14 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965911 2965912
MS MSD
92488344001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 5590 3090 2980 9110 9570 114 133 90-110 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 560527 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767002
METHOD BLANK: 2973941
Associated Lab Samples: 92489767002
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 2973942
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 08/19/20 04:33
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 998 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2973943 2973944
MS MSD
92489568001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 1730 1800 1860 3550 3580 101 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 558759 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767002
METHOD BLANK: 2965156
Matrix: Solid
Associated Lab Samples: 92489767002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
08/08/20 13:10
Nitrogen, Nitrite
mg/kg
ND 4.0
08/08/20 13:10
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
08/08/20 13:10
LABORATORY CONTROL SAMPLE: 2965157
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 16.4 109 90-110
Nitrogen, Nitrite mg/kg 10 9.8 98 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 26.2 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2965158
2965159
MS
MSD
92489767002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
330
339
342
355
104
105
90-110 4
Nitrogen, Nitrite
mg/kg
ND
221
225
228
215
103
94
90-110 6
Nitrogen, NO2 plus NO3
mg/kg
ND
551
567
570
570
104
101
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 558912 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767002
METHOD BLANK: 2965711
Associated Lab Samples: 92489767002
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 2965712
Parameter Units
Phosphorus mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.88 08/11/2010:11
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
48.1 48.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965713 2965714
MS MSD
92488344001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 7010 327 346 7110 7080 30 20 90-110 0 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
QC Batch: 559042 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92489767002
METHOD BLANK: 2966303
Associated Lab Samples: 92489767002
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 2966304
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 08/11/20 00:18
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 203 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2966305 2966306
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 413 1100 1100 1550 1560 103 104 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: PLANT SLUDGE
Pace Project No.: 92489767
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 655990 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92489767002
METHOD BLANK: 3566758
Associated Lab Samples: 92489767002
Parameter Units
Sulfate mg/kg
LABORATORY CONTROL SAMPLE: 3566759
Parameter Units
Sulfate mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.2 08/12/2017:14
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
502 537 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3566761 3566760
MS MSD
35569123001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/kg 145 573 568 716 725 100 102 80-120 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC.
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QUALIFIERS
Project: PLANT SLUDGE
Pace Project No.: 92489767
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/24/2020 10:58 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 18

aceAnalytical
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
PLANT SLUDGE
92489767
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92489767001
WW PLANT SLUDGE
EPA 3050B
559033
EPA 6010D
559066
92489767001
WW PLANT SLUDGE
EPA 7471 B
559034
EPA 7471 B
559049
92489767002
WW PLANT SLUDGE
SM 2540G-2011
559181
92489767002
WW PLANT SLUDGE
ASTM D2974-87
558995
92489767002
WW PLANT SLUDGE
EPA 350.1 Rev 2.0 1993
558962
EPA 350.1 Rev 2.0 1993
559088
Mod.
Mod.
92489767002
WW PLANT SLUDGE
EPA 351.2 Rev 2.0 1993
560527
EPA 351.2 Rev 2.0 1993
560845
92489767002
WW PLANT SLUDGE
EPA 353.2 Rev 2.0 1993
558759
EPA 353.2 Rev 2.0 1993
558767
92489767002
WW PLANT SLUDGE
EPA 365.1 Rev 2.0 1993
558912
EPA 365.1 Rev 2.0 1993
559014
92489767002
WW PLANT SLUDGE
SM 4500-CI-E-2011
559042
SM 4500-CI-E-2011
559050
92489767002
WW PLANT SLUDGE
EPA 9056
655990
EPA 9056
656098
Date: 08/24/2020 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 18

CHAIN -OF -CUSTODY Analytical Request Document
aceAnalytica!`
Chain-af-Custody N a LEGAL DOCUMENT- Complete all relevent fields
'ity of Elizabeth City Billing Informatior:
450 Knobbs Creek
Yasheka Brothers Email To:
Rebecca Miller [Site Collection Info/Address:
Quarterly Sludge IElizabeth Chy, NC 27909
Site/Facility ID #:
Compliance Mnn itoring?
252]337-3331
[ ] Yes [ ] No
C I e y (prin
Purchase Order#:
DW PWS ID M
quote#:
❑W Location Code:
Turnafound Date Required:
edlately Packed on Ice:
[ Yes [ ] No
S pl isp l:
Rush:
Feld filtered (if applicable):
[ I Dispose -appropriate [ ] Return
[ ] Same Day [ ] Next Day
L 1 Yes [ ]NO
[ I Archive:
[ ] 2 Day [ 13 Day [ ] 4 Day [ ] S Day
[ )Hold:
(Expedite CharMAppfy}
Analysls:
• Matrix Codes (Insert in Matrix box below): Drinking Water(DW), Ground Water (GM, Wastewater
Product (P), Soil/Solid (SL), Oil (OL), Wipe [WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V], Other (OT)
Comp /
Collected for
Res
# of
Customer Sample ID
Matrix
Grab
Compositestart)
Composite End
Cl
Ctrs
Date I
Time
Date
Time
WW PLANT SLUDGE
SL
-7
CAIEAL-51(ID
1
8
AIAY,Cd,Ca,Cr,Cu,Pb,Mg,M0,NI,K,Se,Na,Zn & Hg
R&dqul It d / rfiraliY: (Signature)
Re mquished by/Company: (Sign
N
rD
wog 92489767
X
92489767
i(illli� U�i'
ice'
Container Preservative Type `•N
r `
_
as
0. U
UINNU
? , 6 T5%1M,,aw
Preservative Types: (1) nAfic add,121 sulfuric acid, (3) hydrochloric arid, (4) sodium hydroxide, (5) zinc acetate,
methanol, (7) sodium Bisulfate, (8) sodium thiosutfate, (9) hexane, (A) ascorbic acid, [B) ammonium suttatc,
ammonium
hydroxide,
(D) TSP, (D( Dnpreserved, {D) Dther
Analyses
III
?,
.I'!E•
ask
! ,
LU
O91111
i
&I
X
M
X
Mal
x
.
ar
RJOINNEWINOWN
:.,9Kr,MM n7—r0 53
R u�i U?Mu
R (v y/Com rV-.(signature) Date/Time;
Received by/ ampany: (Signature) Date/Time:
____ -- -.

FIELD LOADING ESTIMATES
Facility Elizabeth City WWTP
Sampling Date 11/3/2020
Solids 7.3
Mineralization Rate 0.3
Gallons per DT 3,285.04
pH
Sodium Absorpotion 0.85 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 24,800 lbs./1,000 gal 15.10
Ammonia Nitrogen (mg/Kg) 2,450.00 lbs./1,000 gal 1.49
Nitrate -Nitrite (mg/Kg) 53.30 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 7,983 lbs./1,000 gal 4.86
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 9,208 lbs./1,000 gal 5.61
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.88
Phosphorus lbs./1,000 gal 8.83
Calcium lbs./1,000 gal 98.02
Magnesium lbs./1,000 gal 3.81
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
9.50
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
2.00
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
192.00
Copper lbs./1,000 gal
0.12
Lead (mg/Kg)
16.10
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.05
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
10.20
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
9.50
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
775.00
Zinc lbs./1,000 gal
0.47
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
24,800
7,983 15.97
16,817
24,800
9,208 18.42
15,592
16,817
2,523 5.05
14,294
15,592
2,339 4.68
13,253
14,294
1,072 2.14
13,222
13,253
994 1.99
12,259
13,222
496 0.99
12,726
12,259
460 0.92
11,799
12,726
239 0.48
12,488
11,799
221 0.44
11,578
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 12,312 24.62
Total 13,222 26.44

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 12, 2020
Andrew Edwards
City of Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Dear Andrew Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

014
aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92503758001 WW PLANT SLUDGE EPA6010D
BG2, SH1
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
3
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
EPA9056
NMT
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW PLANT SLUDGE Lab ID: 92503758001 Collected: 11/03/20 11:12 Received: 11/04/20 10:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
15800 mg/kg
94.6
1 11/08/2014:50
11/09/2014:53
7429-90-5
Arsenic
ND mg/kg
9.5
1 11/08/2014:50
11/09/2014:53
7440-38-2
Cadmium
2.0 mg/kg
0.95
1 11/08/2014:50
11/09/2014:53
7440-43-9
Calcium
161000 mg/kg
473
5 11/08/20 14:50
11/09/20 20:18
7440-70-2
Chromium
22.1 mg/kg
4.7
1 11/08/2014:50
11/09/2014:53
7440-47-3
Copper
192 mg/kg
4.7
1 11 /08/20 14:50
11 /09/20 14:53
7440-50-8
Lead
16.1 mg/kg
4.7
1 11 /08/20 14:50
11 /09/20 14:53
7439-92-1
Magnesium
6260 mg/kg
94.6
1 11/08/2014:50
11/09/2014:53
7439-95-4
Molybdenum
ND mg/kg
4.7
1 11/08/2014:50
11/09/2014:53
7439-98-7
Nickel
10.2 mg/kg
4.7
1 11 /08/20 14:50
11 /09/20 14:53
7440-02-0
Potassium
ND mg/kg
4730
1 11/08/2014:50
11/09/2014:53
7440-09-7
Selenium
ND mg/kg
9.5
1 11/08/2014:50
11/09/2014:53
7782-49-2
Sodium
ND mg/kg
4730
1 11/08/2014:50
11/09/2014:53
7440-23-5
Zinc
775 mg/kg
9.5
1 11/08/2014:50
11/09/2014:53
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation
Method:
EPA 7471 B
Pace Analytical Services - Asheville
Mercury
0.046 mg/kg
0.045
1 11/06/2010:20
11/06/2015:14
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
7.3 %
0.10
1
11/05/20 14:33
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
92.7 %
0.10
1
11/05/20 14:12
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
2450 mg/kg
102
1 11/11/20 13:32
11/12/20 08:09
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
24800 mg/kg
3240
5 11/11/20 11:30
11/12/20 06:49
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
53.3
1 11/04/20 19:48
11/04/20 21:17
Nitrogen, Nitrate
ND mg/kg
53.3
1 11/04/20 19:48
11/04/20 21:17
14797-55-8
Nitrogen, Nitrite
ND mg/kg
53.3
1 11/04/20 19:48
11/04/20 21:17
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
14500 mg/kg
248
20 11/05/20 22:33
11/06/20 18:10
7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /12/2020 02:45 PM
without the written consent of Pace Analytical
Services, LLC.
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ANALYTICAL RESULTS
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW PLANT SLUDGE Lab ID: 92503758001 Collected: 11/03/20 11:12 Received: 11/04/20 10:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 3170 mg/kg 136 1 11/09/20 21:28 11/10/20 00:35 16887-00-6
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 1670 mg/kg 682 1 11/06/20 10:05 11/06/20 20:32 14808-79-8
Date: 11/12/2020 02:45 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 578365 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3060038
Associated Lab Samples: 92503758001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 3060039
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0060 11 /06/20 14:26
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.083 0.088 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3060040 3060041
MS MSD
92504016001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.078 0.086 0.084 0.19 0.17 123 107 75-125 9
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /12/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 578778 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3062344
Associated Lab Samples: 92503758001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
11/09/2015:50
Arsenic
mg/kg
ND
1.0
11/09/2015:50
Cadmium
mg/kg
ND
0.10
11/09/2015:50
Calcium
mg/kg
ND
10.0
11/09/2015:50
Chromium
mg/kg
ND
0.50
11/09/2015:50
Copper
mg/kg
ND
0.50
11/09/2015:50
Lead
mg/kg
ND
0.50
11/09/2015:50
Magnesium
mg/kg
ND
10.0
11/09/2015:50
Molybdenum
mg/kg
ND
0.50
11/09/2015:50
Nickel
mg/kg
ND
0.50
11/09/2015:50
Potassium
mg/kg
ND
500
11/09/2015:50
Selenium
mg/kg
ND
1.0
11/09/2015:50
Sodium
mg/kg
ND
500
11/09/2015:50
Zinc
mg/kg
ND
1.0
11/09/2015:50
LABORATORY CONTROL SAMPLE:
3062345
Parameter
Units
Aluminum
mg/kg
Arsenic
mg/kg
Cadmium
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Lead
mg/kg
Magnesium
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Selenium
mg/kg
Sodium
mg/kg
Zinc
mg/kg
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
500
479
96
80-120
50
48.6
97
80-120
50
49.7
99
80-120
500
495
99
80-120
50
48.9
98
80-120
50
49.8
100
80-120
50
48.9
98
80-120
500
467
93
80-120
50
50.7
101
80-120
50
50.2
100
80-120
500
ND
95
80-120
50
46.4
93
80-120
500
474J
95
80-120
50
48.5
97
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3062346
3062347
MS
MSD
92502983001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
15300
469
469
19300
16500
857
259
75-125
16 M1
Arsenic
mg/kg
2.6
46.9
46.9
42.7
43.6
86
87
75-125
2
Cadmium
mg/kg
1.5
46.9
46.9
40.9
41.6
84
86
75-125
2
Calcium
mg/kg
14200
469
469
17700
14600
758
97
75-125
19 M1
Chromium
mg/kg
22.5
46.9
46.9
62.0
62.6
84
85
75-125
1
Copper
mg/kg
443
46.9
46.9
511
508
144
139
75-125
0 M1
Lead
mg/kg
17.2
46.9
46.9
57.4
57.5
86
86
75-125
0
Magnesium
mg/kg
2820
469
469
3350
3330
112
109
75-125
0
Molybdenum
mg/kg
4.9
46.9
46.9
45.6
46.3
87
88
75-125
2
Nickel
mg/kg
16.1
46.9
46.9
56.5
57.0
86
87
75-125
1
Potassium
mg/kg
3510
469
469
4010
4000
107
105
75-125
0
Selenium
mg/kg
3.1
46.9
46.9
42.6
43.6
84
86
75-125
2
Sodium
mg/kg
1090
469
469
1540
1540
96
97
75-125
0
Zinc
mg/kg
829
46.9
46.9
877
881
103
111
75-125
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 578302 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92503758001
SAMPLE DUPLICATE: 3059647
92503930003
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
20.0
19.1 4
SAMPLE DUPLICATE: 3059648
92503777003
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
15.3
13.8 10
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 579530 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3065752
Associated Lab Samples: 92503758001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 3065753
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.4 11/12/20 08:00
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
481 480 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065756 3065757
MS MSD
92502983001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 683 523 544 1180 1230 95 101 90-110 4
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3066170 3066171
MS MSD
92503758001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 2450 6810 6810 8950 8980 95 96 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /12/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 579432 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3065367
Associated Lab Samples: 92503758001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 3065368
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 11 /12/20 04:24
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 1030 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065369 3065370
MS MSD
92504198001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 194 1320 1450 1460 1570 96 95 90-110 7 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /12/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 578067 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3058463
Matrix: Solid
Associated Lab Samples: 92503758001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
11/04/20 21:14
Nitrogen, Nitrite
mg/kg
ND 4.0
11/04/20 21:14
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
11/04/20 21:14
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 3058464
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.3 102 90-110
Nitrogen, Nitrite mg/kg 10 10 100 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.3 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3058465
3058466
MS
MSD
92503758001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
199
199
238
238
119
119
90-110 0
Nitrogen, Nitrite
mg/kg
ND
134
134
148
148
104
103
90-110 0
Nitrogen, NO2 plus NO3
mg/kg
ND
332
332
386
386
106
106
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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014
aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 578343 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3059927
Associated Lab Samples: 92503758001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 3059928
Parameter Units
Phosphorus mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.96 11/06/2018:05
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
46.3 46.6 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3059929 3059930
MS MSD
92502983001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 14000 52.3 54.4 15000 15000 1950 1930 90-110 0 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /12/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
QC Batch: 579056 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92503758001
METHOD BLANK: 3063602
Associated Lab Samples: 92503758001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 3063603
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 11/10/20 00:13
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 210 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063604 3063605
MS MSD
92504652001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 18500 131 131 20400 20200 1430 1300 90-110 1 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /12/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 679802 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92503758001
METHOD BLANK: 3699359
Associated Lab Samples: 92503758001
Parameter Units
Sulfate mg/kg
LABORATORY CONTROL SAMPLE: 3699360
Parameter Units
Sulfate mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 49.9 11 /06/20 18:00
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
502 495 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3699362 3699361
MS MSD
35589928001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/kg 55.7J 593 591 621 620 95 95 80-120 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: QUARTERLY SLUDGE (11/3)
Pace Project No.: 92503758
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
QUARTERLY SLUDGE (11/3)
92503758
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92503758001
WW PLANT SLUDGE
EPA 3050B
578778
EPA 6010D
578796
92503758001
WW PLANT SLUDGE
EPA 7471 B
578365
EPA 7471 B
578527
92503758001
WW PLANT SLUDGE
SM 2540G-2011
578591
92503758001
WW PLANT SLUDGE
ASTM D2974-87
578302
92503758001
WW PLANT SLUDGE
EPA 350.1 Rev 2.0 1993
579530
EPA 350.1 Rev 2.0 1993
579625
Mod.
Mod.
92503758001
WW PLANT SLUDGE
EPA 351.2 Rev 2.0 1993
579432
EPA 351.2 Rev 2.0 1993
579787
92503758001
WW PLANT SLUDGE
EPA 353.2 Rev 2.0 1993
578067
EPA 353.2 Rev 2.0 1993
578074
92503758001
WW PLANT SLUDGE
EPA 365.1 Rev 2.0 1993
578343
EPA 365.1 Rev 2.0 1993
578663
92503758001
WW PLANT SLUDGE
SM 4500-CI-E-2011
579056
SM 4500-CI-E-2011
579078
92503758001
WW PLANT SLUDGE
EPA 9056
679802
EPA 9056
680068
Date: 11/12/2020 02:45 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 19

Iffix
RAAB -1[]V�
ytical Request Ddcument
CHAIN-OF-CGkO OAnal 'YNV
aceAwlyticafo­ NO#:92503758
Chain -of -Custody is a LEGAL DOCUM ENT - Complete A relevant fields
Cjty of Elizabeth City Billing Inforr n*low.
450i,ntjlibs creek
92! )3758
Efiuv To D) IrWro6kK-ac4 (4) -crwm hydroudli, zkric!Oetlte;-
ash"
Pmervative
Aa)
(U) UnVf6i"�,
be
L
aparterly Sludge. Eftabetb City, NC 27909
V7
KENN . . . . . . .
site[Facifty ID S.
Compliance MoNnowing?
[phone].
Yes ]No
Purchase Order V:
Purchase
.
DW PWS ID #;
*-W #-.
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Turnaround Date Required: I -d on ice: z
5 atu Ijmediately Packed
0
Yes NO
pie i.spapsaLt Hush:
Fiekl'Fvttcred (if apphmble),
I I Dispose as approWate Retum
] Same Day I Next Day
I 3yes ]No
I Ardiive:
I 12Day [ ]3Day 1 4 Day 5 Day
I
CEXpedlteawg-Apply)
lAnalysis.
Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GVk% Wastewater (WW1,
0cli
z
LU
Product (P), Sod/Sand (5Q, Oil (OL),
Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
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CD Relinquished by/company: (Signature)
Date/Ttme:
Received by/Company: ( ature
Date/Time:

Document Name:
Condition Upon Rec
Document No.:
*Check mark top half of box if pH anti/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Caliform, TOC, oil and Grease, DAO/8015 (Plater) DOC, LLHg
**Bottom half of box Is to list number of bottle
{)etument Revised: February 7, 2018
t(SCUP) Page 1 of 2
issuingAuthoritY:
pace CafalinasQuality office
ProjE W0# : 92503758
PM: KPD Due Date: 11/13/20
CLIENT: 92—Elizabeth
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pH Adjustment Log for Preserved Samples
tU Type of Preservative pH span receipt Qate preservation adjusted Tlmea � tion
Note: Whenever there lsa tllsuepancy alit:LLMe lvUJ411 —•••r
out of hold, Incorrect preservative, out of temp, incorrect contalners•
Amount of Pre,
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Page 19 of 19

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 23, 2020
Andrew Edwards
City of Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Dear Andrew Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on October 23, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Greensburg
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 1 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Pace Analytical Services Pennsylvania
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Florida: Cert E871149 SEKS WET
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
CERTIFICATIONS
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TN I Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Pace Analytical Services National
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Mold Certification #: LABO152
Texas Certification #: T 104704245-17-14
USDA Soil Permit #: P330-15-00234
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Utah Certification #: TN00003
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: VT2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21LA 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 35

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92501955001 TCLPSludge-(Herb-submssv2-Pac EPA8151A
TAB
3
PAN
EPA 8081 B
SEM
9
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA6010D
SH1
7
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8270E
PKS
18
PASI-C
EPA 8260D
SAS
14
PASI-C
EPA 1010
DRK
1
PASI-PA
EPA 9012B
JER
1
PAN
EPA 9030B
LDT
1
PAN
EPA9045C
AJM
1
PASI-PA
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-PA = Pace Analytical Services - Greensburg
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 4 of 35

aceAnalytical
www.paeelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Sample: TCLP Sludge -(Herb- Lab ID: 92501955001 Collected: 10/23/20 07:27 Received: 10/23/20 10:25 Matrix: Solid
submssv2-Pac
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical Method: EPA8151A Preparation Method: 8151A
Leachate Method/Date: 1311; 10/29/20 13:30 Initial pH: 10.27; Final pH:
5.56
Pace National - Mt. Juliet
2,4,5-TP (Silvex)
ND mg/L 0.00200 1 11/03/20 08:00
11/03/20 22:26
93-72-1
2,4-D
ND mg/L 0.00200 1 11/03/20 08:00
11/03/20 22:26
94-75-7
Surrogates
2,4-DCAA (S)
78.6 % 14.0-158 1 11/03/20 08:00
11/03/20 22:26
19719-28-9
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081B Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 10/27/20 15:27 Initial pH: ; Final pH:
5
Pace Analytical Services - Charlotte
gamma-BHC (Lindane)
ND ug/L 0.50 1 11/03/20 08:24
11/04/20 15:25
58-89-9
Chlordane (Technical)
ND ug/L 3.0 1 11/03/20 08:24
11/04/20 15:25
57-74-9
Endrin
ND ug/L 0.50 1 11/03/20 08:24
11/04/20 15:25
72-20-8
Heptachlor
ND ug/L 0.50 1 11/03/20 08:24
11/04/20 15:25
76-44-8
Heptachlor epoxide
ND ug/L 0.50 1 11/03/20 08:24
11/04/20 15:25
1024-57-3
Methoxychlor
ND ug/L 1000 1 11/03/20 08:24
11/04/20 15:25
72-43-5
Toxaphene
ND ug/L 3.0 1 11/03/20 08:24
11/04/20 15:25
8001-35-2
Surrogates
Decachlorobiphenyl (S)
124 % 10-154 1 11/03/20 08:24
11/04/20 15:25
2051-24-3
Tetrachloro-m-xylene (S)
65 % 10-184 1 11/03/20 08:24
11/04/20 15:25
877-09-8
8082 TCLP PCBs RVE
Analytical Method: EPA8082A Preparation Method: EPA3510C
Leachate Method/Date: EPA 1311; 10/27/20 15:27 Initial pH: ; Final pH:
5
Pace Analytical Services - Charlotte
PCB-1016 (Aroclor 1016)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
12674-11-2
PCB-1221 (Aroclor 1221)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
11104-28-2
PCB-1232 (Aroclor 1232)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
11141-16-5
PCB-1242 (Aroclor 1242)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
53469-21-9
PCB-1248 (Aroclor 1248)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
11097-69-1
PCB-1260 (Aroclor 1260)
ND ug/L 1000 1 10/29/20 06:59
10/30/20 18:43
11096-82-5
Surrogates
Decachlorobiphenyl (S)
35 % 10-181 1 10/29/20 06:59
10/30/20 18:43
2051-24-3
6010 MET ICP, TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 10/27/20 15:05 Initial pH: ; Final pH:
2
Pace Analytical Services - Asheville
Arsenic
ND mg/L 0.050 1 10/29/20 02:13
10/29/20 23:00
7440-38-2
Barium
ND mg/L 0.25 1 10/29/20 02:13
10/29/20 23:00
7440-39-3
Cadmium
ND mg/L 0.0050 1 10/29/20 02:13
10/29/20 23:00
7440-43-9
Chromium
ND mg/L 0.050 1 10/29/20 02:13
10/29/20 23:00
7440-47-3
Lead
ND mg/L 0.025 1 10/29/20 02:13
10/29/20 23:00
7439-92-1
Selenium
ND mg/L 0.10 1 10/29/20 02:13
10/29/20 23:00
7782-49-2
Silver
ND mg/L 0.025 1 10/29/20 02:13
10/29/20 23:00
7440-22-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM
without the written consent of Pace Analytical Services, LLC.
Page 5 of 35

aceAnalytical
www.paeelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Sample: TCLP Sludge -(Herb- Lab ID: 92501955001 Collected: 10/23/20 07:27 Received: 10/23/20 10:25 Matrix: Solid
submssv2-Pac
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
7470 Mercury, TCLP
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 10/27/20 15:05
Initial
pH: ; Final pH:
2
Pace Analytical
Services - Asheville
Mercury
ND
mg/L
0.00020
1
10/29/2010:13
10/29/2013:33
7439-97-6
8270E TCLP RVE
Analytical Method:
EPA 8270E Preparation
Method:
EPA3510C
Leachate Method/Date: EPA 1311; 10/27/20 15:27
Initial
pH: ; Final pH:
5
Pace Analytical
Services - Charlotte
1,4-Dichlorobenzene
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
87-68-3
Hexachlorobenzene
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
118-74-1
Hexachloroethane
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
67-72-1
2-Methyl phenol(o-Cresol)
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
95-48-7
3&4-Methylphenol (m&p Cresol)
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
15831-10-4
Nitrobenzene
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
98-95-3
Pentachlorophenol
ND
ug/L
100
1
10/28/20 14:04
10/29/20 15:40
87-86-5
Pyridine
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
110-86-1
2,4,5-Trichlorophenol
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
50.0
1
10/28/20 14:04
10/29/20 15:40
88-06-2
Surrogates
Nitrobenzene-d5 (S)
76
%
10-144
1
10/28/20 14:04
10/29/20 15:40
4165-60-0
2-Fluorobiphenyl (S)
48
%
10-130
1
10/28/20 14:04
10/29/20 15:40
321-60-8
Terphenyl-d14 (S)
115
%
34-163
1
10/28/20 14:04
10/29/20 15:40
1718-51-0
Phenol-d6 (S)
35
%
10-130
1
10/28/20 14:04
10/29/20 15:40
13127-88-3
2-Fluorophenol (S)
44
%
10-130
1
10/28/20 14:04
10/29/20 15:40
367-12-4
2,4,6-Tribromophenol (S)
83
%
10-144
1
10/28/20 14:04
10/29/20 15:40
118-79-6
8260D MSV TCLP
Analytical Method:
EPA8260D Leachate Method/Date: EPA 1311; 11/02/20 11:27
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
100
20
11/03/20 14:58
71-43-2
2-Butanone (MEK)
ND
ug/L
200
20
11/03/20 14:58
78-93-3
Carbon tetrachloride
ND
ug/L
100
20
11/03/20 14:58
56-23-5
Chlorobenzene
ND
ug/L
100
20
11/03/20 14:58
108-90-7
Chloroform
ND
ug/L
100
20
11/03/20 14:58
67-66-3
1,4-Dichlorobenzene
ND
ug/L
100
20
11/03/20 14:58
106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
11/03/20 14:58
107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
11/03/20 14:58
75-35-4
Tetrachloroethene
ND
ug/L
100
20
11/03/20 14:58
127-18-4
Trichloroethene
ND
ug/L
100
20
11/03/20 14:58
79-01-6
Vinyl chloride
ND
ug/L
100
20
11/03/20 14:58
75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
70-130
20
11/03/20 14:58
17060-07-0
Toluene-d8(S)
103
%
67-135
20
11/03/20 14:58
2037-26-5
4-Bromofluorobenzene (S)
100
%
70-130
20
11/03/20 14:58
460-00-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 35

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
Sample: TCLP Sludge -(Herb-
Lab ID: 92501955001 Collected: 10/23/20 07:27 Received: 10/23/20 10:25 Matrix: Solid
submssv2-Pac
Results reported on a "wet -weight" basis
Parameters
Results Units Report Limit DF Prepared
Analyzed CAS No. Qual
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010
Pace Analytical Services - Greensburg
Flashpoint
>200 deg F 60.0 1
10/29/20 19:00
Wet Chemistry 9012 B
Analytical Method: EPA 9012B Preparation Method: 9012B
Pace National - Mt. Juliet
Cyanide, Reactive
ND mg/kg 0.250 1 11/02/20 15:01
11/02/20 17:23 ML
Wet Chemistry 9034-9030B
Analytical Method: EPA 9030B Preparation Method: 9034-9030B
Pace National - Mt. Juliet
Sulfide, Reactive
ND mg/kg 25.0 1 10/30/20 22:00
10/30/20 22:00
9045 pH Soil
Analytical Method: EPA9045C
Pace Analytical Services - Greensburg
pH in water at 25 degrees C
11.9 Std. Units 2.0 1
10/26/20 21:56 H3
REPORT OF LABORATORY ANALYSIS
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Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 1569429 Analysis Method: EPA8151A
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151A
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92501955001
METHOD BLANK: R3589101-1
Matrix:
Solid
Associated Lab Samples: 92501955001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4-D
mg/L
ND
0.00200
11/03/2019:19
2,4,5-TP (Silvex)
mg/L
ND
0.00200
11/03/20 19:19
2,4-DCAA (S)
%
67.2
14.0-158
11 /03/20 19:19
LABORATORY CONTROL SAMPLE:
R3589101-2
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
2,4,5-TP (Silvex)
mg/L
0.0500
0.0377
75.4 50.0-125
2,4-D
mg/L
0.0500
0.0351
70.2 50.0-120
2,4-DCAA (S)
%
68.6 14.0-158
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
R3589101-3
R3589101-4
MS
MSD
L1278817-03
Spike
Spike
MS MSD
MS
MSD % Rec
Parameter
Units
Result
Conc.
Conc.
Result Result
% Rec
% Rec Limits RPD Qual
2,4,5-TP (Silvex)
mg/L
ND
0.0500
0.0500
0.0396 0.0399
79.2
79.8 50.0-125 0.755
2,4-D
mg/L
ND
0.0500
0.0500
0.0379 0.0378
75.8
75.6 50.0-120 0.264
2,4-DCAA (S)
%
80.2
83.4 14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 576524 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury TCLP
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92501955001
METHOD BLANK: 3049163
Associated Lab Samples: 92501955001
Parameter Units
Mercury mg/L
LABORATORY CONTROL SAMPLE: 3051237
Parameter Units
Mercury mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.00020 10/29/20 13:12
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.0025 0.0027 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3051238 3051239
MS MSD
92502079001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/L ND 0.0025 0.0025 0.0024 0.0024 95 95 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 576523 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92501955001
METHOD BLANK: 3049163
Matrix:
Water
Associated Lab Samples: 92501955001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
10/29/20 21:42
Barium
mg/L
ND
0.25
10/29/20 21:42
Cadmium
mg/L
ND
0.0050
10/29/20 21:42
Chromium
mg/L
ND
0.050
10/29/20 21:42
Lead
mg/L
ND
0.025
10/29/20 21:42
Selenium
mg/L
ND
0.10
10/29/20 21:42
Silver
mg/L
ND
0.025
10/29/20 21:42
LABORATORY CONTROL SAMPLE:
3051234
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Spike
LCS
LCS
% Rec
Conc.
Result
% Rec
Limits Qualifiers
2.5
2.4
97
80-120
2.5
2.4
96
80-120
2.5
2.3
94
80-120
2.5
2.3
93
80-120
2.5
2.3
93
80-120
2.5
2.5
101
80-120
1.2
1.2
96
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3051235
3051236
MS
MSD
92501413001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
0.049J
2.5
2.5
2.4
2.5
96
99
75-125
3
Barium
mg/L
0.059J
2.5
2.5
2.5
2.5
96
99
75-125
3
Cadmium
mg/L
ND
2.5
2.5
2.3
2.4
92
96
75-125
4
Chromium
mg/L
ND
2.5
2.5
2.3
2.4
93
96
75-125
4
Lead
mg/L
ND
2.5
2.5
2.3
2.4
92
96
75-125
4
Selenium
mg/L
ND
2.5
2.5
2.5
2.6
101
104
75-125
3
Silver
mg/L
ND
1.2
1.2
1.2
1.2
94
98
75-125
4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 577564 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92501955001
METHOD BLANK: 3055782
Associated Lab Samples: 92501955001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
11/03/20 11:44
1,2-Dichloroethane
ug/L
ND
5.0
11/03/20 11:44
1,4-Dichlorobenzene
ug/L
ND
5.0
11/03/20 11:44
2-Butanone (MEK)
ug/L
ND
10.0
11/03/20 11:44
Benzene
ug/L
ND
5.0
11/03/20 11:44
Carbon tetrachloride
ug/L
ND
5.0
11/03/20 11:44
Chlorobenzene
ug/L
ND
5.0
11/03/20 11:44
Chloroform
ug/L
ND
5.0
11/03/20 11:44
Tetrachloroethene
ug/L
ND
5.0
11/03/20 11:44
Trichloroethene
ug/L
ND
5.0
11/03/20 11:44
Vinyl chloride
ug/L
ND
5.0
11/03/20 11:44
1,2-Dichloroethane-d4 (S)
%
97
70-130
11/03/20 11:44
4-Bromofluorobenzene (S)
%
100
70-130
11/03/20 11:44
Toluene-d8 (S)
%
102
67-135
11/03/20 11:44
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3055781
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
57.3
115
70-132
1,2-Dichloroethane
ug/L
50
47.6
95
70-130
1,4-Dichlorobenzene
ug/L
50
51.2
102
70-130
2-Butanone (MEK)
ug/L
100
98.3
98
70-133
Benzene
ug/L
50
54.1
108
70-130
Carbon tetrachloride
ug/L
50
54.6
109
70-130
Chlorobenzene
ug/L
50
52.8
106
70-130
Chloroform
ug/L
50
50.8
102
70-130
Tetrachloroethene
ug/L
50
54.7
109
70-130
Trichloroethene
ug/L
50
58.1
116
70-130
Vinyl chloride
ug/L
50
44.7
89
59-142
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
98
67-135
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3055783
3055784
MS
MSD
92502830001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,1-Dichloroethene
ug/L
ND
400
400
395
372
99
93
70-158
6
1,2-Dichloroethane
ug/L
ND
400
400
345
308
85
76
67-138
11
1,4-Dichlorobenzene
ug/L
ND
400
400
342
339
85
85
70-133
1
2-Butanone (MEK)
ug/L
ND
800
800
743
636
86
73
61-147
15
Benzene
ug/L
ND
400
400
377
341
94
85
67-150
10
Carbon tetrachloride
ug/L
ND
400
400
408
361
102
90
70-147
12
Chlorobenzene
ug/L
ND
400
400
370
346
92
86
70-137
7
Chloroform
ug/L
ND
400
400
363
313
91
78
70-144
15
Tetrachloroethene
ug/L
ND
400
400
379
358
95
89
70-139
6
Trichloroethene
ug/L
ND
400
400
405
365
101
91
70-149
11
Vinyl chloride
ug/L
ND
400
400
308
287
77
72
55-172
7
1,2-Dichloroethane-d4 (S)
%
98
98
70-130
4-Bromofluorobenzene (S)
%
98
101
70-130
Toluene-d8(S)
%
99
100
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 577506 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92501955001
METHOD BLANK: 3055629
Matrix:
Water
Associated Lab Samples: 92501955001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
11/04/20 15:58
Endrin
ug/L
ND
0.50
11/04/20 15:58
gamma-BHC (Lindane)
ug/L
ND
0.50
11/04/20 15:58
Heptachlor
ug/L
ND
0.50
11/04/20 15:58
Heptachlor epoxide
ug/L
ND
0.50
11/04/20 15:58
Methoxychlor
ug/L
ND
1000
11/04/20 15:58
Toxaphene
ug/L
ND
3.0
11/04/20 15:58
Decachlorobiphenyl (S)
%
122
10-154
11/04/20 15:58
Tetrachloro-m-xylene (S)
%
99
10-184
11/04/20 15:58
LABORATORY CONTROL SAMPLE:
Parameter
3055630
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Endrin
ug/L
1.2
1.5
123
41-155
gamma-BHC (Lindane)
ug/L
1.2
1.2
100
42-146
Heptachlor
ug/L
1.2
1.1
92
23-135
Heptachlor epoxide
ug/L
1.2
1.4
109
39-142
Methoxychlor
ug/L
3.8
5.5J
147
55-173
Decachlorobiphenyl (S)
%
138
10-154
Tetrachloro-m-xylene (S)
%
86
10-184
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3055631
3055632
MS
MSD
92502171001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.5
1.6
119
128
23-171
7
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.2
1.4
97
112
29-157
15
Heptachlor
ug/L
ND
1.2
1.2
1.1
1.4
90
108
11-149
18
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.3
1.5
104
118
21-157
12
Methoxychlor
ug/L
ND
3.8
3.8
5.2J
5AJ
139
145
33-193
Decachlorobiphenyl (S)
%
120
135
10-154
Tetrachloro-m-xylene (S)
%
71
133
10-184
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 576550 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 TCLP PCB RV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92501955001
METHOD BLANK: 3049166
Associated Lab Samples: 92501955001
Parameter
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Decachlorobiphenyl (S)
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
ug/L
ND
1000
10/30/2019:29
%
37
10-181
10/30/20 19:29
Qualifiers
LABORATORY CONTROL SAMPLE: 3051276
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 25 ND 62 41-137
PCB-1260 (Aroclor 1260) ug/L 25 ND 64 42-156
Decachlorobiphenyl (S) % 61 10-181
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3051277
3051278
MS
MSD
92501955001 Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
ND 25
25 ND
ND
79
93
22-145
PCB-1260 (Aroclor 1260)
ug/L
ND 25
25 ND
ND
89
101
10-167
Decachlorobiphenyl (S)
%
79
89
10-181
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 576392 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92501955001
METHOD BLANK: 3049166
Associated Lab Samples: 92501955001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
10/29/20 12:15
2,4,5-Trichlorophenol
ug/L
ND
50.0
10/29/20 12:15
2,4,6-Trichlorophenol
ug/L
ND
50.0
10/29/20 12:15
2,4-Dinitrotoluene
ug/L
ND
50.0
10/29/20 12:15
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
10/29/20 12:15
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
50.0
10/29/20 12:15
Hexachloro-1,3-butadiene
ug/L
ND
50.0
10/29/20 12:15
Hexachlorobenzene
ug/L
ND
50.0
10/29/20 12:15
Hexachloroethane
ug/L
ND
50.0
10/29/20 12:15
Nitrobenzene
ug/L
ND
50.0
10/29/20 12:15
Pentachlorophenol
ug/L
ND
100
10/29/20 12:15
Pyridine
ug/L
ND
50.0
10/29/20 12:15
2,4,6-Tribromophenol (S)
%
71
10-144
10/29/20 12:15
2-Fluorobiphenyl (S)
%
63
10-130
10/29/20 12:15
2-Fluorophenol (S)
%
48
10-130
10/29/20 12:15
Nitrobenzene-d5 (S)
%
78
10-144
10/29/20 12:15
Phenol-d6 (S)
%
38
10-130
10/29/20 12:15
Terphenyl-d14 (S)
%
99
34-163
10/29/20 12:15
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3050290
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
120
24
18-130
2,4,5-Trichlorophenol
ug/L
500
408
82
35-130
2,4,6-Trichlorophenol
ug/L
500
416
83
31-130
2,4-Dinitrotoluene
ug/L
500
461
92
37-136
2-Methyl phenol(o-Cresol)
ug/L
500
338
68
35-130
3&4-Methyl phenol (m&p Cresol)
ug/L
500
325
65
34-130
Hexachloro-1,3-butadiene
ug/L
500
175
35
11-130
Hexachlorobenzene
ug/L
500
432
86
38-130
Hexachloroethane
ug/L
500
107
21
14-130
Nitrobenzene
ug/L
500
389
78
36-130
Pentachlorophenol
ug/L
1000
913
91
23-149
Pyridine
ug/L
500
147
29
10-130
2,4,6-Tribromophenol (S)
%
87
10-144
2-Fluorobiphenyl (S)
%
61
10-130
2-Fluorophenol (S)
%
46
10-130
Nitrobenzene-d5 (S)
%
78
10-144
Phenol-d6 (S)
%
38
10-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
LABORATORY CONTROL SAMPLE:
3050290
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Terphenyl-d14 (S)
%
101
34-163
MATRIX SPIKE SAMPLE:
3050291
92501413001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
ND
500
177J
35
10-130
2,4,5-Trichlorophenol
ug/L
ND
500
384
77
10-143
2,4,6-Trichlorophenol
ug/L
ND
500
312
62
10-147
2,4-Dinitrotoluene
ug/L
ND
500
373
75
29-148
2-Methyl phenol(o-Cresol)
ug/L
38400
500
50100
2350
20-130 M1
3&4-Methyl phenol (m&p Cresol)
ug/L
21000
500
27700
1340
16-130 M1
Hexachloro-1,3-butadiene
ug/L
ND
500
184J
37
10-130
Hexachlorobenzene
ug/L
ND
500
390
78
29-130
Hexachloroethane
ug/L
ND
500
169J
34
10-130
Nitrobenzene
ug/L
ND
500
2020
403
25-130 M1
Pentachlorophenol
ug/L
ND
1000
383J
38
10-175
Pyridine
ug/L
1890
500
2290
81
10-130
2,4,6-Tribromophenol (S)
%
75
10-144
2-Fluorobiphenyl (S)
%
59
10-130
2-Fluorophenol (S)
%
43
10-130
Nitrobenzene-d5 (S)
%
79
10-144 D3
Phenol-d6 (S)
%
42
10-130
Terphenyl-d14 (S)
%
90
34-163
SAMPLE DUPLICATE: 3050292
92502324002
Dup
Parameter
Units
Result
Result RPD Qualifiers
1,4-Dichlorobenzene
ug/L
ND
ND
2,4,5-Trichlorophenol
ug/L
ND
ND
2,4,6-Trichlorophenol
ug/L
ND
ND
2,4-Dinitrotoluene
ug/L
ND
ND
2-Methyl phenol(o-Cresol)
ug/L
ND
22.3J
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
ND
Hexachloro-1,3-butadiene
ug/L
ND
ND
Hexachlorobenzene
ug/L
ND
ND
Hexachloroethane
ug/L
ND
ND
Nitrobenzene
ug/L
ND
ND
Pentachlorophenol
ug/L
ND
ND
Pyridine
ug/L
ND
ND
2,4,6-Tribromophenol (S)
%
88
53
2-Fluorobiphenyl (S)
%
49
34
2-Fluorophenol (S)
%
49
33
Nitrobenzene-d5 (S)
%
80
54
Phenol-d6 (S)
%
39
26
Results presented on this page are in the units
indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
SAMPLE DUPLICATE: 3050292
92502324002 Dup
Parameter Units Result Result RPD Qualifiers
Terphenyl-d14 (S) % 118 98
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 420855 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Laboratory: Pace Analytical Services - Greensburg
Associated Lab Samples: 92501955001
METHOD BLANK: 2034111
Associated Lab Samples: 92501955001
Parameter Units
Flashpoint deg F
SAMPLE DUPLICATE: 2034112
Parameter Units
Flashpoint deg F
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
>200 60.0 10/29/2014:57
30389741001 Dup
Result Result
>200 >200
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 1569350 Analysis Method: EPA 9012B
QC Batch Method: 9012B Analysis Description: Wet Chemistry 9012 B
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92501955001
METHOD BLANK: R3588504-1
Associated Lab Samples: 92501955001
Parameter Units
Cyanide, Reactive mg/kg
LABORATORY CONTROL SAMPLE: R3588504-2
Parameter Units
Cyanide, Reactive mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
0.527 0.250 11 /02/20 17:12
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
2.50 2.36 94.5 85.0-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3588504-3 R3588504-4
MS MSD
92501955001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide, Reactive mg/kg ND 1.67 1.67 1.10 1.04 52.0 48.8 75.0-125 4.96 MIL
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3588504-6 R3588504-7
MS MSD
L1277677-02 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide, Reactive mg/kg ND 1.67 1.67 1.17 1.23 61.9 65.5 75.0-125 5.06 MIL
SAMPLE DUPLICATE: R3588504-8
L1277699-01 Dup
Parameter Units Result Result RPD Qualifiers
Cyanide, Reactive mg/kg ND ND 0.00
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 35

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 1568052 Analysis Method: EPA 9030B
QC Batch Method: 9034-9030B Analysis Description: Wet Chemistry 9034-9030B
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92501955001
METHOD BLANK: R3587777-1
Matrix: Solid
Associated Lab Samples: 92501955001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND 25.0
10/30/20 22:00
LABORATORY CONTROL SAMPLE:
R3587777-2
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
100
84.1
84.1 70.0-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3587777-5
R3587777-6
MS
MSD
L1278905-06
Spike
Spike MS
MSD MS MSD % Rec
Parameter
Units Result
Conc.
Conc. Result
Result % Rec % Rec Limits RPD Qual
Sulfide, Reactive
mg/kg ND
100
100 95.6
95.6 95.6 95.6 70.0-130 0.050
SAMPLE DUPLICATE: R3587777-3
L1277476-02 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg ND ND 0.00
SAMPLE DUPLICATE: R3587777-4
L1277677-02 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg ND ND 0.00
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 35

aceAnalytical
www.pacelabs.eom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
QC Batch: 420281 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Laboratory: Pace Analytical Services - Greensburg
Associated Lab Samples: 92501955001
SAMPLE DUPLICATE: 2031657
Parameter
pH in water at 25 degrees C
30389227001 Dup
Units Result Result RPD Qualifiers
Std. Units 8.9 8.9 0 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 35

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: TCLP Sludge+RCI
Pace Project No.: 92501955
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
POL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
WORKORDER QUALIFIERS
WO: 92501955
Ill All Reactive Cyanide results reported in the attached report were determined as totals using method 9012B.
Ill All Reactive Sulfide results reported in the attached report were determined as totals using method 9034/9030B.
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased
low.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /23/2020 01:47 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 35

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
TCLP Sludge+RCI
92501955
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92501955001
TCLPSludge-(Herb-submssv2-
8151A
1569429
EPA8151A
1569429
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 3510C
577506
EPA 8081 B
577795
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 3510C
576550
EPA 8082A
576717
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 3010A
576523
EPA 6010D
576548
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 7470A
576524
EPA 7470A
576648
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 3510C
576392
EPA 8270E
576630
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 8260D
577564
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 1010
420855
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
9012B
1569350
EPA 9012B
1569350
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
9034-9030B
1568052
EPA 9030B
1568052
Pac
92501955001
TCLP Sludge-(Herb-submssv2-
EPA 9045C
420281
Pac
Date: 11/23/2020 01:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 35

CHAIN -OF -CUSTODY Analytical Request Documen#
W0# : 92501955 der Number
aceAnafytical
�
or
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields
�� � III I III II II
II III III
CITY OF ELlZABETH CITY
Billing information:
92501955
450 KNORBS CREEK
iLY
REBECCA MILLER
rmiller cit ofec.com
Container Preservative Type..
Loh Project Manager
�f _ ° (r
brothers Cl ofec.com
" Preservauve7ypes:
(1) nitric acid, (2) sulfuric add, (3) hydrochloric
acid, (4) sodium hydroxide, (5) tint acetate,
Site Collection Info/Address:
16) methanol,
V) sodium btsuitate, (8) sodium
thlosulfate, M hexane,
(A) ascorbic acid, (B) ammonium sulfate,
(C) ammonium
hydroxide, (d) YSP, (U} Unreserved, (D) other
TCLP 5LUDGE+RCI
State: County/City: Time Zone Collected:
Analyses
Lab Profile/Une:
Phone:
/ [ ]PT ( )MT [ jCT j ]ET
Lab Sampio Receipt Checklist:
Site/Facility ID #: Compliance Monitoring.
\
Custody Seals Present/intact Y N NA
Email:
�
Custod Signatures Present Y N NA
y' ig.'
C Ile-cte¢ By (print):
[ J Yes I I No
d
Collector Signature Present Y N NA
Purchase Order # : DW PWS ID #;
Dottlas intact Y N NA
DW Location Code:
ID
\
Correct Bottles' - Y N NA'
lie ed (si natur
1� $
Tum4round Date Required: Immediately Packed on Ice:
m
Sufficient Volume. Y N NA
Samples Received am Ice Y N_ NA
Samp1C-DiSp bl:
']Yes [ ]No
�
J
CO
�
VDA - aescspace Acceptable Y N NA
I ]Disposeasappropriate
Rush: fie d Fihered (if applicable]:
It
Q
w
�_
' 9
USDA Regulated Soils ... _ Y N NA
Samples in.Holding -NtiA
( ]Return
I )Same Day ) J NeM Day 1 ] Yes [ J No
Z
Time Y -
J )Archive:
[ ) i Day [ ) 3 Day [ 14 Day I ] 5 Day
g
z
(]
U
Residtidl-Chlorine Present Y N NA
cl Strips:
(Expedite Charges Apply) Analysis:
. }
j O W
U
Sample pH Acceptable Y. N NA
' Matrix Codes (Insert in Matrix box below): Drinking water (0W), Ground Water {GW), Wastewater (WW),
V
pH strips: ;
Product (P), Soil/Solid (SLJ, Oil (OL), Wipe [WP), Air (RR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
j
>
Q C
U]
O. m
Sulfide Present - Y N' NA
Lead Acetate Strips;
Comp J Collected {or Res # of
H
op
CD co co
0
Z co
'
Customer Sample ID
Matrix • Composite End
Grab Composite Start}
(]
ix
d
LAB USE ONLY: _
Cl Ctns
J
�
J d 4 _j
d
Lab Sample - I / [omnents:
Date Time Date Time
00
C)
F
0
SLUDGE 8
X
X
X X X. X
X X
Type of Ice Used: Wet Blue Dry None
SHORT HOLDS PRESENT (<72 hours) : Y N N/A
LAB Sample Temperature Info:
Packing Material Used:
Lab Tracking #
Temp Blank Received: Y N NA
-
-
_
Therm IDI: -
-
--
Cooler Temp -Upon Receipt: oC
Radchemsample(s)screened (<SWcpm): Y N NA
-
- Samples n-ceived via:
-
Cooler '1 -Therm .Corr. Factor, aC
-
FEDEX
UPS', Client Courier PaceCouder
Cooler 1'Corrected Temp: oc
e n fished y/Ca pang: lgna
?
�) Da a ime: _
Recely Company: {S]rr ature)
Date/Tlme: 1� t S
MTIL LAB USE ONLY
comments;
' - . - -
R nish d by ompany:
Signature)
Date ime: Received by Compan . (Signature)
Date/Time:
Acctnum:
Trip Blank Received: Y N. NA
Template:
HCL '_MeOH •T5P Other
Relinquished by/Company: [Signature) Date/Timer Received y: (Signature)
by/Company:
Date ime:
/i
Prelogln: l , !{
�] vJr�7! �U
0/
PM: S.% I
Non Conformance(s): Page:
I
P9:
YES / NO of:
LO
M
O
N
N
m
m
a

aceAnalytical a ANALYTICAL REPORT
National Center for Testing & Innovation November 04, 2020
Pace Analytical - Eden, NC
Sample Delivery Group: L12776O4
Samples Received
Project Number:
Description:
Site:
Report To:
10/24/2020
TCLP Sludge + RCI
001
Kristi Prater
205 East Meadow Rd
Suite A
Eden, NC 27288
Entire Report Reviewed By
Christl M Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
JEl
Page 25 of 35
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical - Eden, NC 92501955 L1277604 11/04/20 19:48 1 of 11
Ad

TABLE OF CONTENTS ONE LAB. NATIONWIDE. *
Cp: Cover Page
1
FP
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
FS
SLUDGE L1277604-01
5
Fn
Qc: Quality Control Summary
Wet Chemistry by Method 9012 B
6
Fr
Wet Chemistry by Method 9034-9030B
7
Chlorinated Acid Herbicides (GC) by Method 8151A
8
FC
GI: Glossary of Terms
9
F
Al: Accreditations & Locations
10
Sc: Sample Chain of Custody
11
[Al
RC
ACCOUNT:
Pace Analytical - Eden, NC
PROJECT: SDG: DATE/TIME:
92 501955 L1277604 11/04/2 0 19:48
Page 26 of 35
PAGE:
2 of 11

SAMPLE SUMMARY ONE LAB. NATIONWIDE.
Collected by Collected date/time Received date/time
SLUDGE L1277604-01 Solid 10/23/2007:27 10/24/2009:00 , C
P
Method
Batch
Dilution Preparation
Analysis
Analyst
date/time
date/time
Preparation by Method 1311
WG1567683
1 10/29/2013:30
10/29/2013:30
TDW
Wet Chemistry by Method 9012 B
WG1569350
1 11/02/2015:01
11/02/2017:23
JER
Wet Chemistry by Method 9034-9030B
WG1568052
1 10/30/20 22:00
10/30/20 22:00
LDT
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1569429
1 11/03/20 08:00
11/03/20 22:26
TAB
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Pace Analytical - Eden, NC
92501955
L1277604
11/04/20
19:48
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Fr
FC
�GI
SAI
RC
Page 27 of 35
PAGE:
3 of 11

CASE NARRATIVE
ONE LAB. NATIONWIDE. *
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
6
. QC
�GI
Christl M Wagner F
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034/9030B.
ACCOUNT:
Pace Analytical - Eden, NC
PROJECT: SDG: DATE/TIME:
92 501955 L1277604 11/04/2 0 19:48
Page 28 of 35
PAGE:
4of11

SLUDGE
Collected date/time: 10/23/20 07:27
Preparation by Method 1311
SAMPLE RESULTS - 01
L1277604
Result Qualifier
Prep
Batch
Analyte
date / time
TCLP Extraction -
10/29/2020130:45 PM
WG1567683
Fluid 1
10/29/2020130:45 PM
WG1567683
Initial pH 10.27
10/29/2020130:45 PM
WG1567683
Final pH 5.56
10/29/2020130:45 PM
WG1567683
Wet Chemistry by Method 9012 B
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/kg mg/kg date / time
Reactive Cyanide ND J6 0.250 1 11/02/202017:23 WG1569352
Wet Chemistry by Method 9034-9030B
Result Qualifier RDL Dilution Analysis Batch
Analyte mg/kg mg/kg date / time
Reactive Sulfide ND 25.0 1 10/30/2020 22:00 WG1568052
Chlorinated Acid Herbicides (GC) by Method 8151A
Result Qualifier RDL Limit
Analyte mg/I mg/I mg/I
2,4,5-TP (Silvex) ND 0.00200 1
2,4-D ND 0.00200 10
(S) Z4-Dichlorophenyl Acetic Acid 78.6 14.0-158
Dilution Analysis
Batch
date / time
1 11/03/2020 22:26
WG1569429
1 11/03/2020 22:26
WG1569429
1110312020 22.26
WG1569429
ONE LAB. NATIONWIDE. *
Fp
Fc
FS
Fn
U
Fc
�GI
SAI
Rc
ACCOUNT:
Pace Analytical - Eden, NC
PROJECT: SDG: DATE/TIME:
92 501955 L1277604 11/04/2 0 19:48
Page 29 of 35
PAGE:
5of11

WG1569350
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R3533504-1 11/02/201712
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
Reactive Cyanide 0.527 0.0390 0.250
L1277699-01 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1277604-01
(OS) L1277699-01 11/02/2017:31 • (DUP) R3533504-3 11/02/2017:32
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg %_
Reactive Cyanide ND ND 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3533504-2 11/02/20 1713
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.36 94.5 85.0-115
L1277604-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1277604-01 11/02/20 17:23 • (MS) R3533504-3 11/02/20 17:24 • (MSD) R3533504-4 11/02/2017:25
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.10 1.04 52.0 48.8 1 75.0-125 J6 J6 4.96
L1277677-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1277677-02 11/02/20 17:23 • (MS) R3533504-6 11/02/20 17:29 • (MSD) R3533504-7 11/02/20 17:30
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 ND 1.17 1.23 61.9 65.5 1 75.0-125 J6 J6 5.06
ONE LAB. NATIONWIDE. *
F—P
ITC]
FS-1
[Cn]
Fr
�GI
1711
Fc
RPD Limits
20
RPD Limits
20
ACCOUNT:
Pace Analytical - Eden, NC
PROJECT: SDG: DATE/TIME:
92 501955 L1277604 11/04/2 0 19:43
Page 30 of 35
PAGE:
6 of 11

WG1568052
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R3537777-1 10/30/20 22:00
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
Reactive Sulfide U 7.63 25.0
L1277476-02 Original Sample (OS) • Duplicate (DUP)
QUALITY CONTROL SUMMARY
L1277604-01
(OS) L1277476-02 10/30/20 22:00 • (DUP) R3537777-3 10/30/20 22:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg %_
Reactive Sulfide ND ND 1 0.000 20
L1277677-02 Original Sample (OS) • Duplicate (DUP)
(OS) L1277677-02 10/30/20 22:00 • (DUP) R3537777-4 10/30/20 22:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte mg/kg mg/kg
Reactive Sulfide ND ND 1 0.000 20
Laboratory Control Sample (LCS)
(LCS) R3587777-2 10/30/20 22:00
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Sulfide 100 84.1 84.1
Rec. Limits LCS Qualifier
70.0-130
L1278905-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
ONE LAB. NATIONWIDE. *
(OS) L1273905-06 10/30/20 22:00 • (MS) R3537777-5 10/30/20 22:00 • (MSD) R3537777-6 10/30/20 22:00
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Sulfide 100 ND 95.6 95.6 95.6 95.6 1 70.0-130 0.0502 20
Page 31 of 35
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical - Eden, NC 92501955 L1277604 11/04/20 19:43 7 of 11

WG1569429
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3539101-1 11/03/2019:19
MB Result
Analyte mg/I
2,4-D U
2,4,5-TP (Silvex) U
(S)Z4-Dichlorophenyl Acetic 672
Acid
QUALITY CONTROL SUMMARY
L1277604-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3539101-2 11/03/20 19:34
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I
2,4,5-TP (Silvex) 0.0500 0.0377 75.4 50.0-125
2,4-D 0.0500 0.0351 70.2 50.0-120
(S) Z4-Dichlorophenyl Acetic 68.6 14. 0-158
Acid
L1278817-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
ONE LAB. NATIONWIDE. *
(OS) L1273317-03 11/03/20 2123 • (MS) R3539101-3 11/03/20 2143 • (MSD) R3539101-4 11/03/20 2157
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
2,4,5-TP (Silvex) 0.0500
ND
0.0396
0.0399 79.2
79.8
1 50.0-125
0.755
20
2,4-D 0.0500
ND
0.0379
0.0378 75.8
75.6
1 50.0-120
0.264
20
(S)Z4-Dichlorophenyl Acetic
80.2
83.4
14.0-158
Acid
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Pace Analytical - Eden, NC
92501955
L1277604
11/04/20 19:43
Page 32 of 35
PAGE:
3of11

GLOSSARY OF TERMS
ONE LAB. NATIONWIDE. *
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
Rec.
Recovery.
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
Fp
Fc
FS
Fn
Fr
Fc
SAI
Rc
ACCOUNT:
Pace Analytical - Eden, NC
PROJECT: SDG: DATE/TIME:
92 501955 L1277604 11/04/2 0 19:48
Page 33 of 35
PAGE:
9of11

ACCREDITATIONS
& LOCATIONS
ONE LAB. NATIONWIDE.
Pace National is the only environmental laboratory accredited/certified to support your work nationwide
from one location. One phone call, one point of contact,
one laboratory. No other lab is as
accessible or prepared to handle your needs throughout the country. Our capacity and capability from our
single location laboratory is comparable to the collective
totals of the network
laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory
campus. The model is conducive to accelerated
productivity, decreasing
Cp
turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium
quality and prompt service allows us to be YOUR
LAB OF CHOICE.
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace
National.
Fc
State Accreditations
Alabama 40660
Nebraska
NE-OS-15-05
FS
Alaska 17-026
Nevada
TN-03-2002-34
Arizona AZ0612
New Hampshire
2975
Arkansas 88-0469
New Jersey—NELAP
TNO02
Fn
California 2932
New Mexico
n/a
Colorado TN00003
New York
11742
Connecticut PH-0197
North Carolina
Env375
Fr
Florida E87487
North Carolina'
DW21704
Georgia NELAP
North Carolina 3
41
Georgia' 923
North Dakota
R-140
Fc
Idaho TN00003
Ohio—VAP
CL0069
Illinois 200008
Oklahoma
9915
7G1
Indiana C-TN-01 f
Oregon
TN200002
Iowa 364
Pennsylvania
68-02979
Kansas E-10277
Rhode Island
LA000356
Kentucky' 6 90010
South Carolina
84004
Kentucky 2 16
South Dakota
n/a
Louisiana A130792
Tennessee'"
2006
Louisiana' LA180010
Texas
T104704245-18-15
Rc
Maine TN0002
Texas 5
LABO152
Maryland 324
Utah
TN00003
Massachusetts M-TNO03
Vermont
VT2006
Michigan 9958
Virginia
460132
Minnesota 047-999-395
Washington
C847
Mississippi TN00003
West Virginia
233
Missouri 340
Wisconsin
9980939910
Montana CERT0086
Wyoming
A2 LA
Third Party Federal Accreditations
A2LA— ISO17025 1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5 1461.02
DOD
1461.01
Canada 1461.01
USDA
P330-15-00234
EPA—Crypto TN00003
' Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold
6 Wastewater n/a Accreditation not applicable
Our Locations
Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact
our main office. Pace National performs all testing at our central laboratory.
WA
MT ND
OR
ID SD
VWY
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KS
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AK
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ACCOUNT: V PROJECT:
Pace Analytical - Eden, NC 92501955
MN
WVI NY
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Mo IL 141110KY WV
N * r�
AR
Ms AL GA
LA
FL
SDG: DATE/TIME:
L1277604 11/04/20 19:48
ME
Page 34 of 35
PAGE:
10 of 11

Internal Transfer Chain of Custody _ aceAnalyficale
Samples Pre -Logged into eCOC State Of Origin: NC
Cert. Needed: n Yes No
Workorder: 92501955 Workorder Name: TCLP Sludae+RCI Owner Received Date: 10/23/2020 Results Reauested Rv: 11IF;12rton
Report To Subcontract To
Requested Analysis
Kristi Prater Pace Analytical National
Pace Analytical Eden 12065 Lebanon Rd
205 East Meadow Road Nit Juliet, TN 37122
Suite A Phone [phone]
Eden, NC 27288
Phone [phone]
a
;u
Preserved Containers
>
Sample
Coilect
Item
Sample lD
Type
DaterTime
Lab ID
Matrbc
j
LAB USE ONLY
1
sludge
PS
10r2WWO 07:27
92501955001
Solid
x21<61
2
3
4
5
com"WIt4
Transfers
Ftele ,Wdy
DaterTime
Received By
DatelTime
-
(�
2
,
3
G
j
Cooler`T'�m erature On Receipt 'C Cust Seat or N Receiv on Ice Y or N Samples Intact Y or N
—in order to maintain client confidentiality, location/name of the sampling site, samplet's name and signature may not be provided on this COC document.
This chain of custody is considered complete as is since this information is available in the owner laboratory.
C 11J4 G t he kiis*
rz p eLTJ If Fpplicai la Il
r inza=�: �Y{-� Zero Headapa�e: =�
COC Seal pre9el+- �S N VCR+
CSC Signs 'Accurate. iJ Pres.C,rrectiCheck: Pt
ttles acriVe intact: - YN
-�N
Cerr®clume sent:
r' Sufficxent vo
SE rN" <115 mRA
BAD Screen <_.5 mR'hr: y N
Friday, October 23, 2020 2721:47 PM FMT-ALL-C-002rev.o0 24March2009 Page 1 of 1
Page 35 of 35

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0002883 Facility Name City of Elizabeth City Source Permit No. 04-70-010 Source Name Elizabeth City WTP
Laboratory 1
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) Class A Class B
Pace Anal6cal
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analvtica]
1/15/2020
3/11/2020
5/7/2020
7/27/2020
9/9/2020
11/19/2020
Aluminum
N/A
N/A
6,190
7,080
10,100
93
1,080
42,600
Ammonia Nitrogen
N/A
N/A
8
35
28
109
67
473
Arsenic
41
75
4.5
3.5
2.8
9.3
6.1
34.8
Cadmium
39
85
a45
0.35
028
0.93
0.61
35
Calcium
N/A
N/A
129,mo
132,000
258,000
93
19,600
363,000
Copper
1,500
4,300
2.3
1.7
1.4
4.7
3.1
17.4
Lead
300
840
2.3
1.7
1.4
4.7
3.1
17.4
Magnesium
N/A
N/A
7,150
5,810
8,370
93
1,140
35,000
Mercury
17
57
0.04
0.0072
0.0065
0.068
02
Molybdenum
N/A
75
2.3
1.7
1.4
4.7
3.1
17.4
Nickel
420
420
2.3
1.7
1.4
4.7
3.1
17.4
Nitrate -Nitrite Nitrogen
N/A
N/A
32
15
14
45
27
197
Percent Solids
N/A
N/A
12.60
2620
2920
8.80
13.80
200
pH (no units)
N/A
N/A
Phosphorus
N/A
N/A
202
189
132
221
225
1,220
Potassium
N/A
N/A
2,260
1,730
11400
4,650
3,060
171400
PAN (Inj./Inc.)
N/A
N/A
39
50
41
154
94
672
PAN (Surface)
N/A
N/A
35
32
27
99
60
433
Selenium
100
100
4.5
3.5
2.8
9.3
6.1
34.8
Sodium
N/A
N/A
2,260
1,730
1,400
4,650
3,060
17,400
SAR
N/A
N/A
o59
0.61
0.40
24.09
2.13
1.04
TKN
N/A
N/A
319
153
157
540
301
2,350
Zinc
2,800
7,500
45
35
3.1
9.3
6.1
34.8
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
-2,5 -,.2
APrepoler* - Date
is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 1/15/2020
Solids 12.6
Mineralization Rate 0
Gallons per DT 1,903.24
pH
Sodium Absorpotion 0.59 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 319 lbs./1,000 gal 0.34
Ammonia Nitrogen (mg/Kg) 7.90 lbs./1,000 gal 0.01
Nitrate -Nitrite (mg/Kg) 31.50 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 35 lbs./1,000 gal 0.04
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 39 lbs./1,000 gal 0.04
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.37
Phosphorus lbs./1,000 gal 0.21
Calcium lbs./1,000 gal 135.56
Magnesium lbs./1,000 gal 7.51
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
4.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.45
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
2.30
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
2.30
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.04
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
2.30
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
4.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
4.50
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
319
35 0.07
284
319
39 0.08
280
284
0 0.00
284
280
0 0.00
280
284
0 0.00
284
280
0 0.00
280
284
0 0.00
284
280
0 0.00
280
284
0 0.00
284
280
0 0.00
280
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 35 0.07
Total 39 0.08

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
January 31, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Dear RAYMOND STATEN:
Enclosed are the analytical results for sample(s) received by the laboratory on January 16, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 39

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services Atlanta
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Pace Analytical Services Pennsylvania
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Florida: Cert E871149 SEKS WET
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TN I Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 39

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services National
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification M LA000356
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LABO152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 9980939910
Wyoming UST Certification #: via A21LA 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 39

(�Ia'ne Analytical
www.pacelabs.cem
SAMPLE ANALYTE COUNT
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92460983001 WTPSLUDGE EPA8151
MTJ
11
PAN
EPA 8081 B
PKS
9
PASI-C
EPA 601OD
SH1
14
PASI-A
EPA 601OD
DS
7
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 7471 B
SOO
1
PASI-A
EPA 8270E
BPJ
18
PASI-C
EPA 8260D
SAS
14
PASI-C
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 1010A
SMK
1
PASI-A
SM 2540G
KBC
1
PAN
EPA9045D
SMK
1
PASI-A
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
3
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
EPA9056A
MWB
1
PASI-GA
92460983002 WTP SLUDGE RCI EPA 1010
RTB
1
PASI-PA
EPA9045C
AJM
1
PASI-PA
EPA 9014
PAS
1
PASI-PA
SM 4500S2F-2011
PAS
1
PASI-PA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 39

(�Ia'ne Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Sample: WTP SLUDGE
Lab ID: 92460983001 Collected: 01/15/20 12:05
Received: 01/16/20 09:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted
for percent moisture, sample size and any dilutions.
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical Method: EPA8151
Preparation Method:
8151A
2,4-D
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
94-75-7
Dalapon
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
127-20-8
2,4-DB
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
94-82-6
Dicamba
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
1918-00-9
Dichloroprop
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
15165-67-0
Dinoseb
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
88-85-7
MCPA
ND
mg/kg
32.5
1
01/21/2013:18
01/22/2014:15
94-74-6 LO
MCPP
ND
mg/kg
32.5
1
01/21/2013:18
01/22/2014:15
7085-19-0 LO
2,4,5-T
ND
mg/kg
0.350
1
01/21/2013:18
01/22/2014:15
93-76-5
2,4,5-TP (Silvex)
ND
mg/kg
0.350
1
01/21/20 13:18
01/22/20 14:15
93-72-1
Surrogates
2,4-DCAA(S)
41.1
%
22.0-132
1
01/21/2013:18
01/22/2014:15
19719-28-9
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081B Preparation Method:
EPA 3510C
Leachate Method/Date: EPA 1311; 01/22/20 14:52
Initial pH: ; Final pH:
4
gamma-BHC (Lindane)
ND
ug/L
0.50
1
01/23/20 15:55
01/27/20 12:41
58-89-9
Chlordane (Technical)
ND
ug/L
3.0
1
01/23/20 15:55
01/27/20 12:41
57-74-9
Endrin
ND
ug/L
0.50
1
01/23/20 15:55
01/27/20 12:41
72-20-8
Heptachlor
ND
ug/L
0.50
1
01/23/20 15:55
01/27/20 12:41
76-44-8
Heptachlor epoxide
ND
ug/L
0.50
1
01/23/20 15:55
01/27/20 12:41
1024-57-3
Methoxychlor
ND
ug/L
1000
1
01/23/20 15:55
01/27/20 12:41
72-43-5
Toxaphene
ND
ug/L
3.0
1
01/23/20 15:55
01/27/20 12:41
8001-35-2
Surrogates
Decachlorobiphenyl (S)
121
%
10-138
1
01/23/20 15:55
01/27/20 12:41
2051-24-3
Tetrachloro-m-xylene (S)
85
%
10-110
1
01/23/20 15:55
01/27/20 12:41
877-09-8
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
6190
mg/kg
45.3
1
01/21/20 10:38
01/23/20 20:27
7429-90-5
Arsenic
ND
mg/kg
4.5
1
01/21/20 10:38
01/23/20 20:27
7440-38-2
Cadmium
ND
mg/kg
0.45
1
01/21/20 10:38
01/23/20 20:27
7440-43-9
Calcium
129000
mg/kg
226
5
01/21/20 10:38
01/24/2011:57
7440-70-2
Chromium
ND
mg/kg
2.3
1
01/21/20 10:38
01/23/20 20:27
7440-47-3
Copper
ND
mg/kg
2.3
1
01/21/20 10:38
01/23/20 20:27
7440-50-8
Lead
ND
mg/kg
2.3
1
01/21/20 10:38
01/23/20 20:27
7439-92-1
Magnesium
7150
mg/kg
45.3
1
01/21/20 10:38
01/23/20 20:27
7439-95-4
Molybdenum
ND
mg/kg
2.3
1
01/21/20 10:38
01/23/20 20:27
7439-98-7
Nickel
ND
mg/kg
2.3
1
01/21/20 10:38
01/23/20 20:27
7440-02-0
Potassium
ND
mg/kg
2260
1
01/21/20 10:38
01/23/20 20:27
7440-09-7
Selenium
ND
mg/kg
4.5
1
01/21/20 10:38
01/23/20 20:27
7782-49-2
Sodium
ND
mg/kg
2260
1
01/21/20 10:38
01/23/20 20:27
7440-23-5
Zinc
ND
mg/kg
4.5
1
01/21/20 10:38
01/23/20 20:27
7440-66-6
6010 MET ICP, TCLP
Analytical Method:
EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date:
EPA 1311; 01/27/20 15:30
Initial
pH: 9.74; Final
pH: 3
Arsenic
ND
mg/L
0.050
1
01/28/2011:18
01/28/2016:34
7440-38-2
Barium
ND
mg/L
0.25
1
01/28/2011:18
01/28/2016:34
7440-39-3
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Sample: WTP SLUDGE Lab ID: 92460983001 Collected: 01/15/20 12:05 Received: 01/16/20 09:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP, TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/27/20 15:30 Initial pH: 9.74; Final
pH: 3
Cadmium
ND mg/L 0.0050 1 01/28/2011:18
01/28/2016:34
7440-43-9
Chromium
ND mg/L 0.050 1 01/28/2011:18
01/28/2016:34
7440-47-3
Lead
ND mg/L 0.025 1 01/28/2011:18
01/28/2016:34
7439-92-1
Selenium
ND mg/L 0.10 1 01/28/2011:18
01/28/2016:34
7782-49-2
Silver
ND mg/L 0.025 1 01/28/2011:18
01/28/2016:34
7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/27/20 15:30 Initial pH: 9.74; Final
pH: 3
Mercury
0.00020 mg/L 0.00020 1 01/28/2012:07
01/29/2015:12
7439-97-6
7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
Mercury
ND
mg/kg
0.040
1
01/23/20 13:30
01/27/20 09:52
7439-97-6 R1
8270E MSSV TCLP Sep Funnel
Analytical Method:
EPA 8270E Preparation Method:
EPA 3510C
1,4-Dichlorobenzene
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
87-68-3
Hexachlorobenzene
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
118-74-1
Hexachloroethane
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
67-72-1
2-Methyl phenol(o-Cresol)
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
95-48-7
3&4-Methylphenol (m&p Cresol)
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
15831-10-4
Nitrobenzene
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
98-95-3
Pentachlorophenol
ND
ug/L
100
1
01/23/20 12:51
01/27/20 10:46
87-86-5
Pyridine
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
110-86-1
2,4,5-Trichlorophenol
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
50.0
1
01/23/20 12:51
01/27/20 10:46
88-06-2
Surrogates
Nitrobenzene-d5 (S)
82
%
12-102
1
01/23/20 12:51
01/27/20 10:46
4165-60-0
2-Fluorobiphenyl (S)
80
%
13-107
1
01/23/20 12:51
01/27/20 10:46
321-60-8
Terphenyl-d14 (S)
76
%
21-132
1
01/23/20 12:51
01/27/20 10:46
1718-51-0
Phenol-d6 (S)
25
%
10-110
1
01/23/20 12:51
01/27/20 10:46
13127-88-3
2-Fluorophenol (S)
39
%
10-110
1
01/23/20 12:51
01/27/20 10:46
367-12-4
2,4,6-Tribromophenol (S)
64
%
27-108
1
01/23/20 12:51
01/27/20 10:46
118-79-6
8260D MSV TCLP
Analytical Method:
EPA8260D
Benzene
ND
ug/L
100
20
01/28/20 01:51
71-43-2
2-Butanone (MEK)
ND
ug/L
200
20
01/28/20 01:51
78-93-3
Carbon tetrachloride
ND
ug/L
100
20
01/28/20 01:51
56-23-5
Chlorobenzene
ND
ug/L
100
20
01/28/20 01:51
108-90-7
Chloroform
ND
ug/L
100
20
01/28/20 01:51
67-66-3
1,4-Dichlorobenzene
ND
ug/L
100
20
01/28/20 01:51
106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
01/28/20 01:51
107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
01/28/20 01:51
75-35-4
Tetrachloroethene
ND
ug/L
100
20
01/28/20 01:51
127-18-4
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 39

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ANALYTICAL RESULTS
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE Lab ID: 92460983001 Collected: 01/15/20 12:05 Received: 01/16/20 09:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV TCLP
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
1010 Flashpoint,Closed Cup
Flashpoint
Total Solids 2540 G-2011
Total Solids
9045 pH Soil
pH at 25 Degrees C
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 01 /31 /2020 09:34 AM
Analytical Method: EPA8260D
ND ug/L 100
20
01/28/20 01:51
79-01-6
ND ug/L 100
20
01/28/20 01:51
75-01-4
86 % 70-130
20
01/28/20 01:51
17060-07-0
103 % 67-135
20
01/28/20 01:51
2037-26-5
99 % 70-130
20
01/28/20 01:51
460-00-4
Analytical Method: SM 2540G-2011
12.6 % 0.10
1
01/17/2016:08
Analytical Method: ASTM D2974-87
87.4 % 0.10
1
01/17/2015:59
Analytical Method: EPA 1010A
151.00 deg F 70.0
1
01/28/20 12:12
D6
Analytical Method: SM 2540G Preparation Method: SM 2540 G
20.0 %
1 01/21/2018:53
01/21/2019:15
Analytical Method: EPA9045D
7.9 Std. Units 0.10
1
01/20/20 15:02
H3
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
ND mg/kg 7.9
1 01 /21 /20 10:38
01 /21 /20 14:24
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
ND mg/kg 319
1 01/28/20 05:22
01/29/20 07:21
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
ND mg/kg 31.5
1 01/17/2010:52
01/17/2011:56
M1
ND mg/kg 31.5
1 01/17/2010:52
01/17/2011:56
14797-55-8
ND mg/kg 31.5
1 01/17/2010:52
01/17/2011:56
14797-65-0
M1
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
202 mg/kg 7.8
1 01/19/2019:24
01/20/2018:23
7723-14-0
Analytical Method: SM 4500-CI-E-2011 Preparation
Method: SM 4500-CI-E-2011
301 mg/kg 78.1
1 01/30/20 07:28
01/30/20 09:56
16887-00-6
Analytical Method: EPA9056A Preparation Method: EPA9056A
ND mg/kg 49.3
1 01/22/20 18:00
01/24/20 05:20
14808-79-8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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(�Ia'ne Analytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Sample: WTP SLUDGE RCI
Lab ID: 92460983002 Collected:
01/15/20 12:05 Received: 01/16/20 09:20 Matrix: Solid
Results reported on a "wet -weight"
basis
Parameters
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010
Flashpoint
>200 deg F
60.0 1 01/21/20 21:16
9045 pH Soil
Analytical Method: EPA9045C
pH in water at 25 degrees C
9.2 Std. Units
2.0 1 01/17/20 19:54 H3
733C S Reactive Cyanide
Analytical Method: EPA9014 Preparation
Method: SW-846 7.3.3.2
Cyanide, Reactive
ND mg/kg
1.0 1 01/17/20 19:15 01/17/20 19:54
734S Reactive Sulfide
Analytical Method: SM 4500S2F-2011
Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive
ND mg/kg
10.0 1 01/17/20 19:15 01/17/20 19:19
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 1413898 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Associated Lab Samples: 92460983001
METHOD BLANK: R3493345-1
Associated Lab Samples: 92460983001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed Qualifiers
2,4-D
mg/kg
ND
0.0700
01/22/2012:03
Dalapon
mg/kg
ND
0.0700
01/22/2012:03
2,4-DB
mg/kg
ND
0.0700
01/22/2012:03
Dicamba
mg/kg
ND
0.0700
01/22/2012:03
Dichloroprop
mg/kg
ND
0.0700
01/22/2012:03
Dinoseb
mg/kg
ND
0.0700
01/22/2012:03
MCPA
mg/kg
ND
6.50
01/22/2012:03
MCPP
mg/kg
ND
6.50
01/22/2012:03
2,4,5-T
mg/kg
ND
0.0700
01/22/2012:03
2,4,5-TP (Silvex)
mg/kg
ND
0.0700
01/22/20 12:03
2,4-DCAA(S)
%
47.9
22.0-132
01/22/2012:03
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
R3493345-2
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,4-D
mg/kg
0.167
0.0891
53.4
40.0-120
Dalapon
mg/kg
0.167
0.0683
40.9
15.0-120
2,4-DB
mg/kg
0.167
0.0983
58.9
25.0-143
Dicamba
mg/kg
0.167
0.0833
49.9
43.0-120
Dichloroprop
mg/kg
0.167
0.104
62.3
32.0-129
Dinoseb
mg/kg
0.167
0.0729
43.7
10.0-120
MCPA
mg/kg
1.67
2.38
143
31.0-121 LO
MCPP
mg/kg
1.67
5.26
315
28.0-133 E,LO
2,4,5-T
mg/kg
0.167
0.0996
59.6
41.0-120
2,4,5-TP (Silvex)
mg/kg
0.167
0.0905
54.2
42.0-120
2,4-DCAA (S)
%
45.4
22.0-132
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
R3493345-3
R3493345-4
MS
MSD
L1180905-01
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
2,4-D
mg/kg
ND
0.193
0.192
0.0949
0.0833
49.2
43.5
10.0-160
13.0
Dalapon
mg/kg
ND
0.193
0.192
ND
ND
0.00
0.00
10.0-121
0.00 ML
2,4-DB
mg/kg
ND
0.193
0.192
0.116
0.105
60.2
54.9
10.0-160
9.86
Dicamba
mg/kg
ND
0.193
0.192
0.0659
0.0599
34.2
31.3
10.0-154
9.42
Dichloroprop
mg/kg
ND
0.193
0.192
0.116
0.109
60.1
56.6
10.0-158
6.53
Dinoseb
mg/kg
ND
0.193
0.192
0.0673
0.0698
34.9
36.4
10.0-120
3.73
MCPA
mg/kg
ND
1.93
1.92
4.22
3.23
219
168
10.0-160
26.5 E,MH
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 39

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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
R3493345-3
R3493345-4
MS
MSD
L1180905-01
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
MCPP
mg/kg
ND
1.93
1.92
9.03
5.53
468
288
10.0-160
48.0 E,MH,P9,
R1
2,4,5-T
mg/kg
ND
0.193
0.192
0.0963
0.0886
49.9
46.2
10.0-157
8.29
2,4,5-TP (Silvex)
mg/kg
ND
0.193
0.192
0.102
0.0961
53.0
50.1
10.0-156
6.21
2,4-DCAA (S)
%
47.7
45.6
22.0-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 39

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521782
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92460983001
METHOD BLANK: 2789820
Matrix: Water
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/L
ND 0.00020
01/29/2015:31
METHOD BLANK: 2790229
Matrix: Water
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/L
ND 0.00020
01/29/2015:07
LABORATORY CONTROL SAMPLE: 2791282
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/L
0.0025 0.0028
111 80-120
LABORATORY CONTROL SAMPLE: 2791283
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/L
0.0025 0.0028
110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2791284 2791285
MS MSD
92460983001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/L 0.00020
0.0025 0.0025 0.0025
0.0029 91 106 75-125 14
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520938
Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B
Analysis Description: 7471 Mercury
Associated Lab Samples: 92460983001
METHOD BLANK: 2787180
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0060
01/27/20 09:50
LABORATORY CONTROL SAMPLE: 2787181
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.083 0.086
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2787182 2787183
MS MSD
92460983001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/kg ND
0.43 0.35 0.46
0.36 105 103 75-125 24 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520448 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Associated Lab Samples: 92460983001
METHOD BLANK: 2784871
Associated Lab Samples: 92460983001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
01/23/20 20:03
Arsenic
mg/kg
ND
1.0
01/23/20 20:03
Cadmium
mg/kg
ND
0.10
01/23/20 20:03
Calcium
mg/kg
ND
10.0
01/23/20 20:03
Chromium
mg/kg
ND
0.50
01/23/20 20:03
Copper
mg/kg
ND
0.50
01/23/20 20:03
Lead
mg/kg
ND
0.50
01/24/2011:54
Magnesium
mg/kg
ND
10.0
01/23/20 20:03
Molybdenum
mg/kg
ND
0.50
01/23/20 20:03
Nickel
mg/kg
ND
0.50
01/23/20 20:03
Potassium
mg/kg
ND
500
01/23/20 20:03
Selenium
mg/kg
ND
1.0
01/24/2011:54
Sodium
mg/kg
ND
500
01/23/20 20:03
Zinc
mg/kg
ND
1.0
01/23/20 20:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2784872
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
500
510
102
80-120
Arsenic
mg/kg
50
48.1
96
80-120
Cadmium
mg/kg
50
50.6
101
80-120
Calcium
mg/kg
500
523
105
80-120
Chromium
mg/kg
50
52.5
105
80-120
Copper
mg/kg
50
53.5
107
80-120
Lead
mg/kg
50
51.3
103
80-120
Magnesium
mg/kg
500
502
100
80-120
Molybdenum
mg/kg
50
49.3
99
80-120
Nickel
mg/kg
50
51.8
104
80-120
Potassium
mg/kg
500
513
103
80-120
Selenium
mg/kg
50
46.6
93
80-120
Sodium
mg/kg
500
542
108
80-120
Zinc
mg/kg
50
49.5
99
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2784873 2784874
MS MSD
92461401001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Aluminum mg/kg 2600 276 280 4290 4510 611 683 75-125 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 39

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
BiMonthly Residual Sludge+TCLP
92460983
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2784873
2784874
MS
MSD
92461401001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/kg
ND
27.6
28
25.1
26.2
90
93
75-125
4
Cadmium
mg/kg
ND
27.6
28
26.6
27.4
96
98
75-125
3
Calcium
mg/kg
49.6
276
280
339
391
105
122
75-125
14
Chromium
mg/kg
2.8
27.6
28
30.8
31.7
101
103
75-125
3
Copper
mg/kg
0.80
27.6
28
30.3
31.4
107
110
75-125
4
Lead
mg/kg
3.4
27.6
28
28.5
29.6
91
94
75-125
4
Magnesium
mg/kg
97.2
276
280
443
463
125
131
75-125
4 M1
Molybdenum
mg/kg
0.20J
27.6
28
25.1
25.8
90
92
75-125
3
Nickel
mg/kg
1.1
27.6
28
28.6
29.6
100
102
75-125
3
Potassium
mg/kg
ND
276
280
406
418
126
129
75-125
3 M1
Selenium
mg/kg
ND
27.6
28
23.8
24.8
86
89
75-125
4
Sodium
mg/kg
ND
276
280
298
304
102
103
75-125
2
Zinc
mg/kg
3.9
27.6
28
31.4
32.4
99
102
75-125
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 39

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521769 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92460983001
METHOD BLANK: 2789820
Matrix:
Water
Associated Lab Samples: 92460983001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
01/28/2016:21
Barium
mg/L
ND
0.25
01/28/2016:21
Cadmium
mg/L
ND
0.0050
01/28/2016:21
Chromium
mg/L
ND
0.050
01/28/2016:21
Lead
mg/L
ND
0.025
01/28/2016:21
Selenium
mg/L
ND
0.10
01/28/2016:21
Silver
mg/L
ND
0.025
01/28/2016:21
METHOD BLANK: 2790229
Matrix:
Water
Associated Lab Samples: 92460983001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
01/28/2016:27
Barium
mg/L
ND
0.25
01/28/2016:27
Cadmium
mg/L
ND
0.0050
01/28/2016:27
Chromium
mg/L
ND
0.050
01/28/2016:27
Lead
mg/L
ND
0.025
01/28/2016:27
Selenium
mg/L
ND
0.10
01/28/2016:27
Silver
mg/L
ND
0.025
01/28/2016:27
LABORATORY CONTROL SAMPLE:
2791140
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike
LCS
LCS
% Rec
Conc.
Result
% Rec
Limits Qualifiers
2.5
2.3
94
80-120
2.5
2.4
97
80-120
2.5
2.4
95
80-120
2.5
2.3
94
80-120
2.5
2.3
93
80-120
2.5
2.4
98
80-120
1.2
1.2
96
80-120
LABORATORY CONTROL SAMPLE: 2791141
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.4 95 80-120
Barium mg/L 2.5 2.5 100 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2791141
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Cadmium
mg/L
2.5
2.4
97
80-120
Chromium
mg/L
2.5
2.4
97
80-120
Lead
mg/L
2.5
2.4
96
80-120
Selenium
mg/L
2.5
2.6
103
80-120
Silver
mg/L
1.2
1.2
98
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2791142
2791143
MS
MSD
92460983001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.4
2.4
95
96
75-125
1
Barium
mg/L
ND
2.5
2.5
2.6
2.6
98
99
75-125
1
Cadmium
mg/L
ND
2.5
2.5
2.5
2.5
98
99
75-125
1
Chromium
mg/L
ND
2.5
2.5
2.4
2.4
96
98
75-125
2
Lead
mg/L
ND
2.5
2.5
2.4
2.4
95
96
75-125
1
Selenium
mg/L
ND
2.5
2.5
2.6
2.6
103
103
75-125
1
Silver
mg/L
ND
1.2
1.2
1.2
1.2
99
100
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521608 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Associated Lab Samples: 92460983001
METHOD BLANK: 2790462
Associated Lab Samples: 92460983001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
01/27/20 23:46
1,2-Dichloroethane
ug/L
ND
5.0
01/27/20 23:46
1,4-Dichlorobenzene
ug/L
ND
5.0
01/27/20 23:46
2-Butanone (MEK)
ug/L
ND
10.0
01/27/20 23:46
Benzene
ug/L
ND
5.0
01/27/20 23:46
Carbon tetrachloride
ug/L
ND
5.0
01/27/20 23:46
Chlorobenzene
ug/L
38.6
5.0
01/27/20 23:46
Chloroform
ug/L
ND
5.0
01/27/20 23:46
Tetrachloroethene
ug/L
ND
5.0
01/27/20 23:46
Trichloroethene
ug/L
ND
5.0
01/27/20 23:46
Vinyl chloride
ug/L
ND
5.0
01/27/20 23:46
1,2-Dichloroethane-d4 (S)
%
85
70-130
01/27/20 23:46
4-Bromofluorobenzene (S)
%
96
70-130
01/27/20 23:46
Toluene-d8 (S)
%
104
67-135
01/27/20 23:46
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2790461
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
48.1
96
70-130
1,2-Dichloroethane
ug/L
50
48.3
97
70-130
1,4-Dichlorobenzene
ug/L
50
56.2
112
70-130
2-Butanone (MEK)
ug/L
100
88.7
89
64-135
Benzene
ug/L
50
53.6
107
70-130
Carbon tetrachloride
ug/L
50
53.8
108
70-130
Chlorobenzene
ug/L
50
54.1
108
70-130
Chloroform
ug/L
50
51.2
102
70-130
Tetrachloroethene
ug/L
50
56.8
114
69-130
Trichloroethene
ug/L
50
59.3
119
70-130
Vinyl chloride
ug/L
50
42.7
85
70-131
1,2-Dichloroethane-d4 (S)
%
86
70-130
4-Bromofluorobenzene (S)
%
95
70-130
Toluene-d8 (S)
%
95
67-135
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790463 2790464
MS MSD
92460870004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene ug/L ND 400 400 412 403 103 101 70-154 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC.
Page 17 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2790463
2790464
MS
MSD
92460870004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
372
386
93
97
70-137
4
1,4-Dichlorobenzene
ug/L
ND
400
400
421
432
105
108
70-133
3
2-Butanone (MEK)
ug/L
ND
800
800
619
659
77
82
60-139
6
Benzene
ug/L
ND
400
400
437
437
109
109
70-151
0
Carbon tetrachloride
ug/L
ND
400
400
446
450
112
112
70-143
1
Chlorobenzene
ug/L
ND
400
400
461
471
115
118
70-138
2
Chloroform
ug/L
ND
400
400
409
417
102
104
70-139
2
Tetrachloroethene
ug/L
ND
400
400
458
464
115
116
59-143
1
Trichloroethene
ug/L
ND
400
400
473
488
118
122
70-147
3
Vinyl chloride
ug/L
ND
400
400
369
359
92
90
70-156
3
1,2-Dichloroethane-d4 (S)
%
92
94
70-130
4-Bromofluorobenzene (S)
%
96
97
70-130
Toluene-d8(S)
%
97
95
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 39

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521019 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92460983001
METHOD BLANK: 2786421
Matrix:
Water
Associated Lab Samples: 92460983001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
01/27/20 13:55
Endrin
ug/L
ND
0.50
01/27/20 13:55
gamma-BHC (Lindane)
ug/L
ND
0.50
01/27/20 13:55
Heptachlor
ug/L
ND
0.50
01/27/20 13:55
Heptachlor epoxide
ug/L
ND
0.50
01/27/20 13:55
Methoxychlor
ug/L
ND
1000
01/27/20 13:55
Toxaphene
ug/L
ND
3.0
01/27/20 13:55
Decachlorobiphenyl (S)
%
115
10-138
01/27/20 13:55
Tetrachloro-m-xylene (S)
%
88
10-110
01/27/20 13:55
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
2787567
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Endrin
ug/L
1.2
1.1
90
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.1
90
20-118
Heptachlor
ug/L
1.2
0.97
78
20-142
Heptachlor epoxide
ug/L
1.2
1.2
93
22-133
Methoxychlor
ug/L
3.8
3.6J
97
44-150
Decachlorobiphenyl (S)
%
94
10-138
Tetrachloro-m-xylene (S)
%
82
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2787568
2787569
MS
MSD
92460983001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.1
1.2
85
94
21-133
10
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.0
1.1
82
90
24-119
10
Heptachlor
ug/L
ND
1.2
1.2
0.89
0.97
71
77
16-128
9
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.1
1.2
86
95
50-150
10
Methoxychlor
ug/L
ND
3.8
3.8
3.7J
4J
98
106
50-150
Decachlorobiphenyl (S)
%
118
119
10-138
Tetrachloro-m-xylene (S)
%
75
79
10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 39

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520953 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Associated Lab Samples: 92460983001
METHOD BLANK: 2786421
Associated Lab Samples: 92460983001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
01/23/20 16:01
2,4,5-Trichlorophenol
ug/L
ND
50.0
01/23/20 16:01
2,4,6-Trichlorophenol
ug/L
ND
50.0
01/23/20 16:01
2,4-Dinitrotoluene
ug/L
ND
50.0
01/23/20 16:01
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
01/23/20 16:01
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
50.0
01/23/20 16:01
Hexachloro-1,3-butadiene
ug/L
ND
50.0
01/23/20 16:01
Hexachlorobenzene
ug/L
ND
50.0
01/23/20 16:01
Hexachloroethane
ug/L
ND
50.0
01/23/20 16:01
Nitrobenzene
ug/L
ND
50.0
01/23/20 16:01
Pentachlorophenol
ug/L
ND
100
01/23/20 16:01
Pyridine
ug/L
ND
50.0
01/23/20 16:01
2,4,6-Tribromophenol (S)
%
49
27-108
01/23/20 16:01
2-Fluorobiphenyl (S)
%
50
13-107
01/23/20 16:01
2-Fluorophenol (S)
%
35
10-110
01/23/20 16:01
Nitrobenzene-d5 (S)
%
56
12-102
01/23/20 16:01
Phenol-d6 (S)
%
24
10-110
01/23/20 16:01
Terphenyl-d14 (S)
%
64
21-132
01/23/20 16:01
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2787236
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
358
72
10-110
2,4,5-Trichlorophenol
ug/L
500
342
68
39-108
2,4,6-Trichlorophenol
ug/L
500
356
71
40-104
2,4-Dinitrotoluene
ug/L
500
419
84
42-109
2-Methyl phenol(o-Cresol)
ug/L
500
372
74
31-110
3&4-Methyl phenol (m&p Cresol)
ug/L
500
360
72
30-110
Hexachloro-1,3-butadiene
ug/L
500
311
62
10-110
Hexachlorobenzene
ug/L
500
386
77
39-121
Hexachloroethane
ug/L
500
368
74
10-110
Nitrobenzene
ug/L
500
405
81
32-101
Pentachlorophenol
ug/L
1000
744
74
18-108
Pyridine
ug/L
500
201
40
10-110
2,4,6-Tribromophenol (S)
%
92
27-108
2-Fluorobiphenyl (S)
%
72
13-107
2-Fluorophenol (S)
%
53
10-110
Nitrobenzene-d5 (S)
%
80
12-102
Phenol-d6 (S)
%
37
10-110
Terphenyl-d14 (S)
%
86
21-132
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2787234
2787235
MS
MSD
92460826001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
181
159
36
32
30-150
13
2,4,5-Trichlorophenol
ug/L
ND
500
500
184
173
37
35
30-150
6
2,4,6-Trichlorophenol
ug/L
ND
500
500
185
167
37
33
30-150
10
2,4-Dinitrotoluene
ug/L
ND
500
500
240
246
48
49
30-150
2
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
142
128
28
26
30-150
10 M1
3&4-Methylphenol (m&p
ug/L
ND
500
500
142
124
26
23
30-150
13 M1
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
142
120
28
24
30-150
16 M1
Hexachlorobenzene
ug/L
ND
500
500
222
221
44
44
30-150
0
Hexachloroethane
ug/L
ND
500
500
176
150
35
30
30-150
16
Nitrobenzene
ug/L
ND
500
500
201
170
40
34
30-150
16
Pentachlorophenol
ug/L
ND
1000
1000
422
429
42
43
30-150
2
Pyridine
ug/L
ND
500
500
87.1
86.1
17
17
30-150
1 M1
2,4,6-Tribromophenol (S)
%
57
51
27-108
2-Fluorobiphenyl (S)
%
40
32
13-107
2-Fluorophenol (S)
%
23
19
10-110
Nitrobenzene-d5 (S)
%
44
35
12-102
Phenol-d6 (S)
%
15
12
10-110
Terphenyl-d14 (S)
%
49
43
21-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520039 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92460983001
SAMPLE DUPLICATE: 2782891
92459602005 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 95.6 95.6 0
SAMPLE DUPLICATE: 2783101
92461292001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 25.7 25.3 2
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 380462 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92460983002
METHOD BLANK: 1844534 Matrix: Water
Associated Lab Samples: 92460983002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Flashpoint deg F >200 60.0 01/21/20 20:56
SAMPLE DUPLICATE: 1844535
30346045001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521732 Analysis Method: EPA 1010A
QC Batch Method: EPA 1010A Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92460983001
SAMPLE DUPLICATE: 2791004
92460983001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F 151.00 189.00 D6
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 1414491
Analysis Method:
SM 2540G
QC Batch Method: SM 2540 G
Analysis Description:
Total Solids 2540 G-2011
Associated Lab Samples: 92460983001
METHOD BLANK: R3492967-1
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Solids
%
0.00400
01/21/20 19:15
LABORATORY CONTROL SAMPLE: R3492967-2
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Solids
%
50.0 50.1
100 85.0-115
SAMPLE DUPLICATE: R3492967-3
L1180561-04 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Solids
%
76.1 76.4 0.356
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 380007 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Associated Lab Samples: 92460983002
SAMPLE DUPLICATE: 1842390
Parameter
pH in water at 25 degrees C
30345551001 Dup
Units Result Result RPD Qualifiers
Std. Units 6.8 6.8 0 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520147 Analysis Method: EPA 9045D
QC Batch Method: EPA 9045D Analysis Description: 9045 pH
Associated Lab Samples: 92460983001
SAMPLE DUPLICATE: 2783524
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 2783525
Parameter
pH at 25 Degrees C
92460408001 Dup
Units Result Result RPD Qualifiers
Std. Units 5.6 5.6 0 H3
92460460001 Dup
Units Result Result RPD Qualifiers
Std. Units 4.7 4.6 2 D6.1-13
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520287
Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod.
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92460983001
METHOD BLANK: 2784091
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/kg
ND 0.99
01/21/20 14:05
LABORATORY CONTROL SAMPLE: 2784092
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg
49.7 50.0
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2784093 2784094
MS MSD
92460129001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 3800
58.8 58.8 6830
6360 3990 3180 90-110 7 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 521598
Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Associated Lab Samples: 92460983001
METHOD BLANK: 2790415
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
ND 50.0
01/29/20 07:12
LABORATORY CONTROL SAMPLE: 2790416
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
1000 938
94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790417 2790418
MS MSD
92460903001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 15600
3220 3990 26600
23000 340 184 90-110 14 M6, R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 519956
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite
Associated Lab Samples: 92460983001
METHOD BLANK: 2782410
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/kg
ND 3.9
01/17/20 11:59
Nitrogen, Nitrite mg/kg
ND 3.9
01/17/20 11:59
Nitrogen, NO2 plus NO3 mg/kg
ND 3.9
01/17/20 11:59
LABORATORY CONTROL SAMPLE: 2782411
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg
14.9 14.7
99 90-110
Nitrogen, Nitrite mg/kg
9.9 10
100 90-110
Nitrogen, NO2 plus NO3 mg/kg
24.9 24.7
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2782412 2782413
MS MSD
92460983001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/kg ND
119 119 150
149 126 126
90-110 1
Nitrogen, Nitrite mg/kg ND
79.7 78.9 92.1
91.2 116 116
90-110 1 M1
Nitrogen, NO2 plus NO3 mg/kg ND
199 198 242
240 119 119
90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 520163
Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92460983001
METHOD BLANK: 2783610
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phosphorus mg/kg
ND 0.93
01/20/2018:08
LABORATORY CONTROL SAMPLE: 2783611
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Phosphorus mg/kg
50 53.7
107 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2783612 2783613
MS MSD
92460453001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 799
222 246 959
1020 72 90 90-110 6 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 522083
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Associated Lab Samples: 92460983001
METHOD BLANK: 2792612
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/kg
ND 10.0
01/30/20 09:54
LABORATORY CONTROL SAMPLE: 2792613
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/kg
200 195
98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2792614 2792615
MS MSD
92460983001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 301
795 787 1070
1060 97 96 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 379781
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92460983002
METHOD BLANK: 1841187
Matrix: Solid
Associated Lab Samples: 92460983002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND 0.99 01/17/20 19:41
LABORATORY CONTROL SAMPLE: 1841188
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
99.9 ND
0 0-8
SAMPLE DUPLICATE: 1841189
30345183001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 379780
Analysis Method:
SM 4500S2F-2011
QC Batch Method: SW-846 7.3.4.2
Analysis Description:
734S Reactive Sulfide
Associated Lab Samples: 92460983002
METHOD BLANK: 1841183
Matrix: Solid
Associated Lab Samples: 92460983002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND
9.9 01/17/20 19:19
LABORATORY CONTROL SAMPLE: 1841184
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
200 36.0
18 0-52
SAMPLE DUPLICATE: 1841185
30345183001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Sulfide, Reactive
mg/kg
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
QC Batch: 42357
Analysis Method: EPA 9056A
QC Batch Method: EPA 9056A
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92460983001
METHOD BLANK: 193166
Matrix: Solid
Associated Lab Samples: 92460983001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/kg
ND 47.8
01/24/20 04:34
LABORATORY CONTROL SAMPLE: 193167
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Sulfate mg/kg
94.3 93.2
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 193168
193169
MS MSD
92460983001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Sulfate mg/kg ND
99.2 99.5 107
106 105 103 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
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RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PAN
Pace Analytical National
PASI-A
Pace Analytical Services - Asheville
PASI-C
Pace Analytical Services - Charlotte
PASI-GA
Pace Analytical Services - Atlanta, GA
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H3 Sample was received or analysis requested beyond the recognized method holding time.
LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
MH Matrix spike recovery and/or matrix spike duplicate recovery was above laboratory control limits. Result may be biased
high.
ML Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased
low.
P9 RPD between the primary and confirmatory analysis exceeded 40%.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 39

Pace Analytical Services, LLC
(�Ia'neAnalytical ® 9800 neyAve. Suite 100
Huntersville, NC 28078
www.pacelabs.cem [phone]
QUALIFIERS
Project: BiMonthly Residual Sludge+TCLP
Pace Project No.: 92460983
ANALYTE QUALIFIERS
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 01 /31 /2020 09:34 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 39

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
BiMonthly Residual Sludge+TCLP
92460983
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92460983001
WTPSLUDGE
8151A
1413898
EPA8151
1413898
92460983001
WTPSLUDGE
EPA 3510C
521019
EPA 8081 B
521337
92460983001
WTPSLUDGE
EPA 3050B
520448
EPA 6010D
520583
92460983001
WTPSLUDGE
EPA 3010A
521769
EPA 6010D
521799
92460983001
WTPSLUDGE
EPA 7470A
521782
EPA 7470A
521814
92460983001
WTPSLUDGE
EPA 7471 B
520938
EPA 7471 B
521040
92460983001
WTPSLUDGE
EPA 3510C
520953
EPA 8270E
521043
92460983001
WTPSLUDGE
EPA8260D
521608
92460983001
WTPSLUDGE
SM 2540G-2011
520498
92460983001
WTPSLUDGE
ASTM D2974-87
520039
92460983001
WTPSLUDGE
EPA 1010A
521732
92460983002
WTP SLUDGE RCI
EPA 1010
380462
92460983001
WTPSLUDGE
SM 2540 G
1414491
SM 2540G
1414491
92460983001
WTPSLUDGE
EPA9045D
520147
92460983002
WTP SLUDGE RCI
EPA9045C
380007
92460983001
WTPSLUDGE
EPA 350.1 Rev 2.0 1993
520287
EPA 350.1 Rev 2.0 1993
520485
Mod.
Mod.
92460983001
WTPSLUDGE
EPA 351.2 Rev 2.0 1993
521598
EPA 351.2 Rev 2.0 1993
521966
92460983001
WTPSLUDGE
EPA 353.2 Rev 2.0 1993
519956
EPA 353.2 Rev 2.0 1993
519967
92460983001
WTPSLUDGE
EPA 365.1 Rev 2.0 1993
520163
EPA 365.1 Rev 2.0 1993
520245
92460983001
WTPSLUDGE
SM 4500-CI-E-2011
522083
SM 4500-CI-E-2011
522227
92460983002
WTP SLUDGE RCI
SW-846 7.3.3.2
379781
EPA 9014
380011
92460983002
WTP SLUDGE RCI
SW-846 7.3.4.2
379780
SM 4500S2F-2011
380010
92460983001
WTPSLUDGE
EPA 9056A
42357
EPA 9056A
42396
Date: 01 /31 /2020 09:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 38 of 39

ace Analytical CHAIN -OF -CUSTODY Analytical Request Document
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields
Company: Billing Information:
4—;il-
Address, f r
Report I o:
Email To:
Copy To: L
Site Collection Info/Address;
Customer Project Name/Number. //^ �j
State:County/City: Time Zone Collected:
PT
! /�1[/�
[ ] MT [ ] CT �4ET
Phone: �Sz ti( 4
Site/Facility ID #;
Compliance Monitoring?
Email: ,rs
rr+
[ ] Yes [ ] No
lected By (prin ): r
54L.(C,
gdt�j
Purchase Order #:
Quote #:
OW PWS ID #:
OW Location Code:
CXIIZsig6,e):
Turnaround Date Required:
Imme late y Pac a on Ice:
[ ] Yes [ ]NO
Sample Disposal:
Rush:
Field Filtered (if applicable]:
[ ] Dispose as appropriate [ ] Return
[ ] Same Day [ ) Next Day
[ ] Yes [ } No
( j Archive:
[ ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
[ ] Hold:
(Expedite Charges Apply)
Analysis:
" Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other JOT)
Comp /
Collected (or
Res
# of
Customer Sample ID
Matrix "
Grab
Composite Start)
Composite End
Cl
Ctns
Date
I Time
I Date
Time
Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: )am' Blue Dry None
Packing Material Used:
Radchem sample(s) screened (<Soo cpm): Y N VA
Relinquished by/Company: (Signature] Date/Time: Rece' d by/Company: (Signal e)
IS5�Zo 30 -?\ f I AAMJ -,
ished by/Company: (Signature) I Date/T[me: ceive /Company:
Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature
W
LAB USE ONLY WO# : 92460983
AL IIIIIIIIIIll4lllllllll
92460983
Container Presti. __ new o. .+ R■
or
Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) Hint acetate,
{6) methanol, (7) sodium bisulfate, (9) sodium thiosulfate, (9) hexane, (A)ascorbic acid, (B) ammonium sulfate,
(C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other _
Custody Seals Present/,Intact Y N XIC
CusLody Signatures Present
Y N
Collector Signature Present
-YN NA
Bottles Intact
k—N NA
Correct Bottles
X-N NA
Sufficient Volume
-T'N NA
Samples Received on ice
—Y N NA
VOA - Headspace Acceptable
Y N JM
USDA Regulated Soils
Y N NK
Samples in Holding Time
X N NA
Residual Chlorine Prey nt
Y ➢i'NA
Cl SLrivs:
Samole pH Acceptable
_
Y N ytr-
pH Strips:
Sulfide Present
Y N NA,
Lead Acetate Strips:
LAB USE ONLY;
Lab Sample # / Comments:
SHORT HOLDS PRESENT (<72 hours): , Y Ar N/A
Lab Tracking #;
mples received via:
FE,B X UPS Client
Courier Pace Courier
Date/T e:
MTJL LAB USE ONLY
I� �Q z V
Acttnum:
Prelo�giin-
PM: 1 �i j ! �iJ •,
Lab Sample Temperature Info:
Temp Blank Receivad• Y N
11A—
Therm ID#: L
Cooler 1 Temp Upon Receipt: - h oC
Cooler 1 Therm Corr, Factor: 1. oC
Cooler 1 Corrected Temp: vC
Comments:
Trip Blank Received: Y N 1%1:4'
HCL McOH TSP Other
Non Conformance(s): Page:
YES / NO of: —J`

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 3/11/2020
Solids 26.2
Mineralization Rate 0
Gallons per DT 915.30
pH
Sodium Absorpotion 0.61 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 153 lbs./1,000 gal 0.33
Ammonia Nitrogen (mg/Kg) 34.70 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 14.90 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 32 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 50 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.78
Phosphorus lbs./1,000 gal 0.41
Calcium lbs./1,000 gal 332.13
Magnesium lbs./1,000 gal 12.70
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.50
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.35
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.70
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.70
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.70
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.50
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.50
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
153
32 0.06
121
153
50 0.10
103
121
0 0.00
121
103
0 0.00
103
121
0 0.00
121
103
0 0.00
103
121
0 0.00
121
103
0 0.00
103
121
0 0.00
121
103
0 0.00
103
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 32 0.06
Total 50 0.10

(�Ia'ne Analytical
www.pacelabs.com
March 30, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Dear RAYMOND STATEN:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 12, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Clayton McCrickard for
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: SCOTT OSBORNE, ELIZABETH CITY
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 40

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services Pennsylvania
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Florida: Cert E871149 SEKS WET
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
CERTIFICATIONS
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TN I Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
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Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
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Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
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Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
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Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 40

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
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Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
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Louisiana DW Certification #: LA180010
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Michigan Certification #: 9958
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Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
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North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
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CERTIFICATIONS
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New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
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North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
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Texas Mold Certification #: LABO152
Texas Certification #: T 104704245-17-14
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
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AIHA-LAP/LLC EMLAP Certification #:100789
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 40

(�Ia'ne Analytical
www.pacelabs.cem
SAMPLE ANALYTE COUNT
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92469224001 WTPSLUDGE EPA8151
LEL
11
PAN
EPA 8081 B
SEM
9
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA 601OD
SH1
14
PASI-A
EPA 601OD
SH1
7
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 7471 B
SOO
1
PASI-A
EPA 8270E
PKS
18
PASI-C
EPA 8260D
CL
14
PASI-C
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 1010
RTB
1
PASI-PA
EPA 1010A
SMK
1
PASI-A
SM 2540G
MMF
1
PAN
EPA9045C
AJM
1
PASI-PA
EPA9045D
SMK
1
PASI-A
EPA 350.1 Rev 2.0 1993 Mod.
NAL
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
EPA 9014
PAS
1
PASI-PA
SM 4500S2F-2011
PAS
1
PASI-PA
EPA9056
JDM
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 40

(�Ia'ne Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Sample: WTP SLUDGE
Lab ID: 92469224001 Collected: 03/11/20 06:50
Received: 03/12/20 11:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed
CAS No.
Qual
Chlorinated Herb. (GC) 8151
Analytical Method:
EPA8151
Preparation Method:
8151A
2,4-D
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
94-75-7
Dalapon
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
127-20-8
2,4-DB
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
94-82-6
Dicamba
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
1918-00-9
Dichloroprop
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
15165-67-0
Dinoseb
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
88-85-7
LO
MCPA
ND
mg/kg
59.7
1
03/17/20 21:27
03/18/20 23:04
94-74-6
LO
MCPP
ND
mg/kg
59.7
1
03/17/20 21:27
03/18/20 23:04
7085-19-0
LO
2,4,5-T
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
93-76-5
2,4,5-TP (Silvex)
ND
mg/kg
0.643
1
03/17/20 21:27
03/18/20 23:04
93-72-1
Surrogates
2,4-DCAA (S)
54.4
%
22.0-132
1
03/17/20 21:27
03/18/20 23:04
19719-28-9
8081 TCLP Pesticides RVE
Analytical Method:
EPA 8081B Preparation Method:
EPA 3510C
Leachate Method/Date:
EPA 1311; 03/16/20 17:12
Initial pH: 5.78; Final
pH: 5
gamma-BHC (Lindane)
ND
ug/L
0.50
1
03/20/20 13:00
03/27/20 17:34
58-89-9
Chlordane (Technical)
ND
ug/L
3.0
1
03/20/20 13:00
03/27/20 17:34
57-74-9
Endrin
ND
ug/L
0.50
1
03/20/20 13:00
03/27/20 17:34
72-20-8
Heptachlor
ND
ug/L
0.50
1
03/20/20 13:00
03/27/20 17:34
76-44-8
Heptachlor epoxide
ND
ug/L
0.50
1
03/20/20 13:00
03/27/20 17:34
1024-57-3
Methoxychlor
ND
ug/L
1000
1
03/20/20 13:00
03/27/20 17:34
72-43-5
Toxaphene
ND
ug/L
3.0
1
03/20/20 13:00
03/27/20 17:34
8001-35-2
Surrogates
Decachlorobiphenyl (S)
131
%
10-138
1
03/20/20 13:00
03/27/20 17:34
2051-24-3
Tetrachloro-m-xylene (S)
75
%
10-110
1
03/20/20 13:00
03/27/20 17:34
877-09-8
8082 TCLP PCBs RVE
Analytical Method:
EPA8082A Preparation Method:
EPA3510C
Leachate Method/Date:
EPA 1311; 03/16/20 17:12
Initial pH: 5.78; Final
pH: 5
PCB-1016 (Aroclor 1016)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
12674-11-2
L1
PCB-1221 (Aroclor 1221)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
1000
1
03/18/20 12:08
03/24/20 05:42
11096-82-5
L1
Surrogates
Decachlorobiphenyl (S)
136
%
10-132
1
03/18/20 12:08
03/24/20 05:42
2051-24-3
S3
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
7080
mg/kg
34.7
1
03/19/20 10:15
03/20/20 22:03
7429-90-5
Arsenic
ND
mg/kg
3.5
1
03/19/20 10:15
03/20/20 22:03
7440-38-2
Cadmium
ND
mg/kg
0.35
1
03/19/20 10:15
03/20/20 22:03
7440-43-9
Calcium
152000
mg/kg
347
10
03/19/20 10:15
03/21/2014:16
7440-70-2
Chromium
ND
mg/kg
1.7
1
03/19/20 10:15
03/20/20 22:03
7440-47-3
Copper
ND
mg/kg
1.7
1
03/19/20 10:15
03/20/20 22:03
7440-50-8
Lead
ND
mg/kg
1.7
1
03/19/20 10:15
03/20/20 22:03
7439-92-1
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Sample: WTP SLUDGE Lab ID: 92469224001 Collected: 03/11/20 06:50 Received: 03/12/20 11:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3050B
Magnesium
5810
mg/kg
34.7
1
03/19/20 10:15
03/20/20 22:03
7439-95-4
Molybdenum
ND
mg/kg
1.7
1
03/19/20 10:15
03/20/20 22:03
7439-98-7
Nickel
ND
mg/kg
1.7
1
03/19/20 10:15
03/20/20 22:03
7440-02-0
Potassium
ND
mg/kg
1730
1
03/19/20 10:15
03/20/20 22:03
7440-09-7
Selenium
ND
mg/kg
3.5
1
03/19/20 10:15
03/20/20 22:03
7782-49-2
Sodium
ND
mg/kg
1730
1
03/19/20 10:15
03/20/20 22:03
7440-23-5
Zinc
ND
mg/kg
3.5
1
03/19/20 10:15
03/20/20 22:03
7440-66-6
6010 MET ICP, TCLP
Analytical Method:
EPA 6010D
Preparation Method: EPA 3010A
Leachate Method/Date:
EPA 1311; 03/19/20 14:30
Initial
pH: 9.03; Final
pH: 4.5
Arsenic
ND
mg/L
0.050
1
03/20/20 10:58
03/20/20 23:44
7440-38-2
Barium
ND
mg/L
0.25
1
03/20/20 10:58
03/20/20 23:44
7440-39-3
Cadmium
ND
mg/L
0.0050
1
03/20/20 10:58
03/20/20 23:44
7440-43-9
Chromium
ND
mg/L
0.050
1
03/20/20 10:58
03/20/20 23:44
7440-47-3
Lead
ND
mg/L
0.025
1
03/20/20 10:58
03/20/20 23:44
7439-92-1
Selenium
ND
mg/L
0.10
1
03/20/20 10:58
03/20/20 23:44
7782-49-2
Silver
ND
mg/L
0.025
1
03/20/20 10:58
03/20/20 23:44
7440-22-4
7470 Mercury, TCLP
Analytical Method:
EPA 7470A
Preparation Method: EPA 7470A
Leachate Method/Date:
EPA 1311; 03/19/20 14:30
Initial
pH: 9.03; Final
pH: 4.5
Mercury
ND
mg/L
0.00020
1
03/20/2011:10
03/21/2012:35
7439-97-6
7471 Mercury
Analytical Method:
EPA 7471 B
Preparation Method:
EPA 7471 B
Mercury
ND
mg/kg
0.0072
1
03/19/2013:30
03/19/2017:44
7439-97-6
8270E TCLP RVE
Analytical Method:
EPA 8270E
Preparation Method:
EPA3510C
1,4-Dichlorobenzene
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
87-68-3
Hexachlorobenzene
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
118-74-1
Hexachloroethane
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
67-72-1
2-Methyl phenol(o-Cresol)
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
95-48-7
3&4-Methylphenol (m&p Cresol)
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
15831-10-4
Nitrobenzene
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
98-95-3
Pentachlorophenol
ND
ug/L
100
1
03/18/20 10:58
03/19/20 15:29
87-86-5
Pyridine
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
110-86-1
2,4,5-Trichlorophenol
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
95-95-4
2,4,6-Trichlorophenol
ND
ug/L
50.0
1
03/18/20 10:58
03/19/20 15:29
88-06-2
Surrogates
Nitrobenzene-d5 (S)
83
%
12-102
1
03/18/20 10:58
03/19/20 15:29
4165-60-0
2-Fluorobiphenyl (S)
69
%
13-107
1
03/18/20 10:58
03/19/20 15:29
321-60-8
Terphenyl-d14 (S)
87
%
21-132
1
03/18/20 10:58
03/19/20 15:29
1718-51-0
Phenol-d6 (S)
37
%
10-110
1
03/18/20 10:58
03/19/20 15:29
13127-88-3
2-Fluorophenol (S)
55
%
10-110
1
03/18/20 10:58
03/19/20 15:29
367-12-4
2,4,6-Tribromophenol (S)
87
%
27-108
1
03/18/20 10:58
03/19/20 15:29
118-79-6
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 40

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ANALYTICAL RESULTS
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE Lab ID: 92469224001 Collected: 03/11/20 06:50 Received: 03/12/20 11:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
1010 Flashpoint,Closed Cup
Flashpoint
Flashpoint
Total Solids 2540 G-2011
Total Solids
9045 pH Soil
pH in water at 25 degrees C
pH at 25 Degrees C
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
Date: 03/30/2020 04:59 PM
Analytical Method: EPA8260D
ND ug/L
100
20
03/23/2013:18
71-43-2
ND ug/L
200
20
03/23/2013:18
78-93-3
ND ug/L
100
20
03/23/2013:18
56-23-5
ND ug/L
100
20
03/23/2013:18
108-90-7
ND ug/L
100
20
03/23/2013:18
67-66-3
ND ug/L
100
20
03/23/2013:18
106-46-7
ND ug/L
100
20
03/23/2013:18
107-06-2
ND ug/L
100
20
03/23/2013:18
75-35-4
ND ug/L
100
20
03/23/2013:18
127-18-4
ND ug/L
100
20
03/23/2013:18
79-01-6
ND ug/L
100
20
03/23/2013:18
75-01-4
100 %
70-130
20
03/23/2013:18
17060-07-0
98 %
67-135
20
03/23/2013:18
2037-26-5
100 %
70-130
20
03/23/2013:18
460-00-4
Analytical Method: SM 2540G-2011
26.2 %
0.10
1
03/13/2017:47
Analytical Method: ASTM D2974-87
73.8 %
0.10
1
03/13/2017:34
Analytical Method: EPA 1010
>200 deg F
60.0
1
03/16/20 18:50
199.00 deg F
70.0
1
03/23/20 11:52
Analytical Method: SM 2540G Preparation
Method: 2540 G
10.9 %
1 03/18/2010:50
03/18/2011:14
Analytical Method: EPA9045C
9.6 Std. Units
2.0
1
03/16/20 23:22
H3
9.0 Std. Units
0.10
1
03/18/20 13:36
H3
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
ND mg/kg
34.7
1 03/15/2016:14
03/16/2014:25
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
ND mg/kg
153
1 03/17/20 01:18
03/17/20 08:06
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
ND mg/kg
14.9
1 03/13/20 23:00
03/14/20 00:28
H1,H2
ND mg/kg
14.9
1 03/13/20 23:00
03/14/20 00:28
14797-55-8
ND mg/kg
14.9
1 03/13/20 23:00
03/14/20 00:28
14797-65-0
H1,H2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 40

(�Ia'ne Analytical
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ANALYTICAL RESULTS
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE Lab ID: 92469224001 Collected: 03/11/20 06:50 Received: 03/12/20 11:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
189 mg/kg 3.2 1 03/19/20 17:46 03/19/20 21:46 7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Chloride
491 mg/kg 37.1 1 03/18/2016:20 03/18/2018:18 16887-00-6
733C S Reactive Cyanide
Analytical Method: EPA9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive
ND mg/kg 3.8 1 03/17/20 16:08 03/18/20 20:45
734S Reactive Sulfide
Analytical Method: SM 4500S2F-2011 Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive
ND mg/kg 37.9 1 03/17/20 16:08 03/17/20 16:11
9056 IC Anions
Analytical Method: EPA 9056 Preparation Method: EPA 9056
Sulfate
457 mg/kg 191 1 03/20/20 07:00 03/20/20 15:36 14808-79-8
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 1445661 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Associated Lab Samples: 92469224001
METHOD BLANK: R3510127-1
Associated Lab Samples: 92469224001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed Qualifiers
2,4-D
mg/kg
ND
0.0700
03/18/20 18:32
Dalapon
mg/kg
ND
0.0700
03/18/20 18:32
2,4-DB
mg/kg
ND
0.0700
03/18/20 18:32
Dicamba
mg/kg
ND
0.0700
03/18/20 18:32
Dichloroprop
mg/kg
ND
0.0700
03/18/20 18:32
Dinoseb
mg/kg
ND
0.0700
03/18/20 18:32
MCPA
mg/kg
ND
6.50
03/18/20 18:32
MCPP
mg/kg
ND
6.50
03/18/20 18:32
2,4,5-T
mg/kg
ND
0.0700
03/18/20 18:32
2,4,5-TP (Silvex)
mg/kg
ND
0.0700
03/18/20 18:32
2,4-DCAA (S)
%
62.5
22.0-132
03/18/20 18:32
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
R3510127-2
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,4-D
mg/kg
0.154
0.110
71.4
40.0-120
Dalapon
mg/kg
0.154
0.0722
46.9
15.0-120
2,4-DB
mg/kg
0.154
0.110
71.4
25.0-143
Dicamba
mg/kg
0.154
0.0946
61.4
43.0-120
Dichloroprop
mg/kg
0.154
0.102
66.2
32.0-129
Dinoseb
mg/kg
0.154
0.0126
8.18
10.0-120 LO
MCPA
mg/kg
1.54
2.30
149
31.0-121 LO
MCPP
mg/kg
1.54
5.02
326
28.0-133 E,LO
2,4,5-T
mg/kg
0.154
0.109
70.8
41.0-120
2,4,5-TP (Silvex)
mg/kg
0.154
0.0972
63.1
42.0-120
2,4-DCAA (S)
%
59.0
22.0-132
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
R3510127-3
R3510127-4
MS
MSD
L1198880-01
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
2,4-D
mg/kg
ND
0.183
0.181
0.132
0.140
72.2
77.5
10.0-160
5.81
Dalapon
mg/kg
ND
0.183
0.181
0.0950
0.105
52.0
58.3
10.0-121
10.3
2,4-DB
mg/kg
ND
0.183
0.181
0.130
0.137
71.0
75.6
10.0-160
5.08
Dicamba
mg/kg
ND
0.183
0.181
0.118
0.126
64.8
70.0
10.0-154
6.45
Dichloroprop
mg/kg
ND
0.183
0.181
0.118
0.124
64.8
68.8
10.0-158
4.65
Dinoseb
mg/kg
ND
0.183
0.181
0.0468
0.0293
25.6
16.3
10.0-120
45.9 R1
MCPA
mg/kg
ND
1.83
1.81
2.47
2.12
135
118
10.0-160
15.2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
R3510127-3
R3510127-4
MS
MSD
L1198880-01
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
MCPP
mg/kg
ND
1.83
1.81
4.07
3.71
223
206
10.0-160
9.28 E,MH
2,4,5-T
mg/kg
ND
0.183
0.181
0.131
0.137
71.6
75.6
10.0-157
4.22
2,4,5-TP (Silvex)
mg/kg
ND
0.183
0.181
0.114
0.121
62.3
66.9
10.0-156
5.77
2,4-DCAA (S)
%
59.3
67.5
22.0-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531646
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92469224001
METHOD BLANK: 2837184
Matrix: Water
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
03/21/2011:57
METHOD BLANK: 2837441
Matrix: Water
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
03/21/2012:02
LABORATORY CONTROL SAMPLE: 2838347
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0026
105 80-120
LABORATORY CONTROL SAMPLE: 2838348
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0028
110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2838349 2838350
MS MSD
92467783001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/L
ND
0.0025 0.0025 0.0026
0.0026 104 103 75-125 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531409
Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B
Analysis Description: 7471 Mercury
Associated Lab Samples: 92469224001
METHOD BLANK: 2837205
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury mg/kg
ND 0.0060
03/19/2015:07
LABORATORY CONTROL SAMPLE: 2837206
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Mercury mg/kg
0.083 0.090
108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2837207 2837208
MS MSD
92469560004
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.0042
0.046 0.045 0.045
0.041 88 80 75-125 10
ug/g
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531376 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Associated Lab Samples: 92469224001
METHOD BLANK: 2837060
Associated Lab Samples: 92469224001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
03/20/2012:10
Arsenic
mg/kg
ND
1.0
03/20/2012:10
Cadmium
mg/kg
ND
0.10
03/20/2012:10
Calcium
mg/kg
ND
10.0
03/20/2012:10
Chromium
mg/kg
ND
0.50
03/20/2012:10
Copper
mg/kg
ND
0.50
03/20/2012:10
Lead
mg/kg
ND
0.50
03/20/2012:10
Magnesium
mg/kg
ND
10.0
03/20/2012:10
Molybdenum
mg/kg
ND
0.50
03/20/2012:10
Nickel
mg/kg
ND
0.50
03/20/2012:10
Potassium
mg/kg
ND
500
03/20/2012:10
Selenium
mg/kg
ND
1.0
03/20/2012:10
Sodium
mg/kg
ND
500
03/20/2012:10
Zinc
mg/kg
ND
1.0
03/20/2012:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2837061
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
500
518
104
80-120
Arsenic
mg/kg
50
46.5
93
80-120
Cadmium
mg/kg
50
48.5
97
80-120
Calcium
mg/kg
500
507
101
80-120
Chromium
mg/kg
50
52.8
106
80-120
Copper
mg/kg
50
53.9
108
80-120
Lead
mg/kg
50
50.8
102
80-120
Magnesium
mg/kg
500
497
99
80-120
Molybdenum
mg/kg
50
49.7
99
80-120
Nickel
mg/kg
50
50.3
101
80-120
Potassium
mg/kg
500
ND
99
80-120
Selenium
mg/kg
50
45.1
90
80-120
Sodium
mg/kg
500
510
102
80-120
Zinc
mg/kg
50
46.8
94
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2837062 2837063
MS MSD
92468696001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Aluminum mg/kg 15.8 373 373 399 400 103 103 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 40

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Bi-Monthly Sludge
92469224
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2837062
2837063
MS
MSD
92468696001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/kg
ND
37.3
37.3
34.2
34.3
92
92
75-125
0
Cadmium
mg/kg
35.6
37.3
37.3
71.4
69.1
96
90
75-125
3
Calcium
mg/kg
28.3
373
373
403
402
100
100
75-125
0
Chromium
mg/kg
ND
37.3
37.3
39.1
39.1
105
105
75-125
0
Copper
mg/kg
13.6
37.3
37.3
53.5
53.0
107
105
75-125
1
Lead
mg/kg
1.3
37.3
37.3
38.4
38.6
99
100
75-125
1
Magnesium
mg/kg
17.1
373
373
380
379
97
97
75-125
0
Molybdenum
mg/kg
ND
37.3
37.3
36.7
36.7
98
98
75-125
0
Nickel
mg/kg
ND
37.3
37.3
36.7
36.6
98
98
75-125
0
Potassium
mg/kg
ND
373
373
376
375
98
97
75-125
0
Selenium
mg/kg
ND
37.3
37.3
33.3
33.1
89
89
75-125
1
Sodium
mg/kg
1490
373
373
1870
1780
102
78
75-125
5
Zinc
mg/kg
11.6
37.3
37.3
45.9
45.1
92
90
75-125
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 40

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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531644 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92469224001
METHOD BLANK: 2837184
Matrix:
Water
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
03/20/20 22:37
Barium
mg/L
ND
0.25
03/20/20 22:37
Cadmium
mg/L
ND
0.0050
03/20/20 22:37
Chromium
mg/L
ND
0.050
03/20/20 22:37
Lead
mg/L
ND
0.025
03/20/20 22:37
Selenium
mg/L
ND
0.10
03/20/20 22:37
Silver
mg/L
ND
0.025
03/20/20 22:37
METHOD BLANK: 2837441
Matrix:
Water
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
mg/L
ND
0.050
03/20/20 22:44
Barium
mg/L
ND
0.25
03/20/20 22:44
Cadmium
mg/L
ND
0.0050
03/20/20 22:44
Chromium
mg/L
ND
0.050
03/20/20 22:44
Lead
mg/L
ND
0.025
03/20/20 22:44
Selenium
mg/L
ND
0.10
03/20/20 22:44
Silver
mg/L
ND
0.025
03/20/20 22:44
LABORATORY CONTROL SAMPLE:
2838339
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike
LCS
LCS
% Rec
Conc.
Result
% Rec
Limits Qualifiers
2.5
2.5
101
80-120
2.5
2.5
102
80-120
2.5
2.5
100
80-120
2.5
2.5
101
80-120
2.5
2.4
95
80-120
2.5
2.6
103
80-120
1.2
1.2
100
80-120
LABORATORY CONTROL SAMPLE: 2838340
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.5 99 80-120
Barium mg/L 2.5 2.6 102 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 40

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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2838340
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Cadmium
mg/L
2.5
2.6
102
80-120
Chromium
mg/L
2.5
2.6
103
80-120
Lead
mg/L
2.5
2.5
101
80-120
Selenium
mg/L
2.5
2.7
108
80-120
Silver
mg/L
1.2
1.3
101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2838341
2838342
MS
MSD
92467783001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.5
2.5
100
99
75-125
0
Barium
mg/L
0.84
2.5
2.5
3.3
3.3
99
98
75-125
1
Cadmium
mg/L
0.047
2.5
2.5
2.6
2.6
102
102
75-125
1
Chromium
mg/L
ND
2.5
2.5
2.5
2.5
100
99
75-125
1
Lead
mg/L
ND
2.5
2.5
2.4
2.3
94
93
75-125
1
Selenium
mg/L
ND
2.5
2.5
2.7
2.6
105
104
75-125
1
Silver
mg/L
ND
1.2
1.2
1.3
1.3
101
101
75-125
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531914 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Associated Lab Samples: 92469224001
METHOD BLANK: 2840284
Associated Lab Samples: 92469224001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
03/23/20 10:53
1,2-Dichloroethane
ug/L
ND
5.0
03/23/20 10:53
1,4-Dichlorobenzene
ug/L
ND
5.0
03/23/20 10:53
2-Butanone (MEK)
ug/L
ND
10.0
03/23/20 10:53
Benzene
ug/L
ND
5.0
03/23/20 10:53
Carbon tetrachloride
ug/L
ND
5.0
03/23/20 10:53
Chlorobenzene
ug/L
ND
5.0
03/23/20 10:53
Chloroform
ug/L
ND
5.0
03/23/20 10:53
Tetrachloroethene
ug/L
ND
5.0
03/23/20 10:53
Trichloroethene
ug/L
ND
5.0
03/23/20 10:53
Vinyl chloride
ug/L
ND
5.0
03/23/20 10:53
1,2-Dichloroethane-d4 (S)
%
100
70-130
03/23/20 10:53
4-Bromofluorobenzene (S)
%
100
70-130
03/23/20 10:53
Toluene-d8 (S)
%
96
67-135
03/23/20 10:53
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2839711
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
41.3
83
70-130
1,2-Dichloroethane
ug/L
50
40.9
82
70-130
1,4-Dichlorobenzene
ug/L
50
54.2
108
70-130
2-Butanone (MEK)
ug/L
100
81.8
82
64-135
Benzene
ug/L
50
44.9
90
70-130
Carbon tetrachloride
ug/L
50
44.1
88
70-130
Chlorobenzene
ug/L
50
50.7
101
70-130
Chloroform
ug/L
50
43.5
87
70-130
Tetrachloroethene
ug/L
50
48.9
98
69-130
Trichloroethene
ug/L
50
45.4
91
70-130
Vinyl chloride
ug/L
50
42.9
86
70-131
1,2-Dichloroethane-d4 (S)
%
87
70-130
4-Bromofluorobenzene (S)
%
94
70-130
Toluene-d8 (S)
%
97
67-135
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2839713 2839714
MS MSD
92469553001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene ug/L ND 400 400 395 409 99 102 70-154 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 40

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2839713
2839714
MS
MSD
92469553001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
376
372
94
93
70-137
1
1,4-Dichlorobenzene
ug/L
ND
400
400
440
471
110
118
70-133
7
2-Butanone (MEK)
ug/L
ND
800
800
699
720
87
90
60-139
3
Benzene
ug/L
ND
400
400
403
415
101
104
70-151
3
Carbon tetrachloride
ug/L
ND
400
400
421
420
105
105
70-143
0
Chlorobenzene
ug/L
ND
400
400
445
450
111
113
70-138
1
Chloroform
ug/L
ND
400
400
401
411
100
103
70-139
3
Tetrachloroethene
ug/L
ND
400
400
431
444
108
111
59-143
3
Trichloroethene
ug/L
ND
400
400
417
405
104
101
70-147
3
Vinyl chloride
ug/L
ND
400
400
414
404
104
101
70-156
3
1,2-Dichloroethane-d4 (S)
%
100
91
70-130
4-Bromofluorobenzene (S)
%
99
96
70-130
Toluene-d8(S)
%
97
95
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531334
Analysis Method:
EPA 8081 B
QC Batch Method: EPA 3510C
Analysis Description:
8081 TCLP Pesticides RV
Associated Lab Samples: 92469224001
METHOD BLANK: 2834140
Matrix: Water
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
03/27/20 19:31
Endrin
ug/L
ND
0.50
03/27/20 19:31
gamma-BHC (Lindane)
ug/L
ND
0.50
03/27/20 19:31
Heptachlor
ug/L
ND
0.50
03/27/20 19:31
Heptachlor epoxide
ug/L
ND
0.50
03/27/20 19:31
Methoxychlor
ug/L
ND
1000
03/27/20 19:31
Toxaphene
ug/L
ND
3.0
03/27/20 19:31
Decachlorobiphenyl (S)
%
121
10-138
03/27/20 19:31
Tetrachloro-m-xylene (S)
%
96
10-110
03/27/20 19:31
LABORATORY CONTROL SAMPLE:
2836938
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Endrin
ug/L
1.2
1.5
117
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.2
100
20-118
Heptachlor
ug/L
1.2
0.94
76
20-142
Heptachlor epoxide
ug/L
1.2
1.3
104
22-133
Methoxychlor
ug/L
3.8
4.3J
116
44-150
Decachlorobiphenyl (S)
%
103
10-138
Tetrachloro-m-xylene (S)
%
71
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2836939
2836940
MS
MSD
92469455001
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.8
1.8
146 147
21-133
0 M1
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.6
1.4
130 114
24-119
14 M1
Heptachlor
ug/L
ND
1.2
1.2
1.1
1.2
88 97
16-128
10
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.7
1.7
133 132
50-150
0
Methoxychlor
ug/L
ND
3.8
3.8
5.7J
5.8J
151 156
50-150
M1
Decachlorobiphenyl (S)
%
101 100
10-138
Tetrachloro-m-xylene (S)
%
95 78
10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 40

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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531065 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 TCLP PCB RV
Associated Lab Samples: 92469224001
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 2834140
Matrix:
Water
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
1000
03/24/20 06:40
PCB-1221 (Aroclor 1221)
ug/L
ND
1000
03/24/20 06:40
PCB-1232 (Aroclor 1232)
ug/L
ND
1000
03/24/20 06:40
PCB-1242 (Aroclor 1242)
ug/L
ND
1000
03/24/20 06:40
PCB-1248 (Aroclor 1248)
ug/L
ND
1000
03/24/20 06:40
PCB-1254 (Aroclor 1254)
ug/L
ND
1000
03/24/20 06:40
PCB-1260 (Aroclor 1260)
ug/L
ND
1000
03/24/20 06:40
Decachlorobiphenyl (S)
%
109
10-132
03/24/20 06:40
LABORATORY CONTROL SAMPLE:
2835558
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
25
ND
124 38-113 L1
PCB-1260 (Aroclor 1260)
ug/L
25
ND
129 35-120 L1
Decachlorobiphenyl (S)
%
138 10-132 S3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2835559
2835560
MS
MSD
92469224001 Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc. Result
Result
% Rec
% Rec
Limits RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
ND 25
25 ND
ND
119
127
19-142
PCB-1260 (Aroclor 1260)
ug/L
ND 25
25 ND
ND
122
132
19-142
Decachlorobiphenyl (S)
%
126
139
10-132 S3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 40

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 530878 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Associated Lab Samples: 92469224001
METHOD BLANK: 2834140
Associated Lab Samples: 92469224001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
03/17/20 16:52
2,4,5-Trichlorophenol
ug/L
ND
50.0
03/17/20 16:52
2,4,6-Trichlorophenol
ug/L
ND
50.0
03/17/20 16:52
2,4-Dinitrotoluene
ug/L
ND
50.0
03/17/20 16:52
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
03/17/20 16:52
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
50.0
03/17/20 16:52
Hexachloro-1,3-butadiene
ug/L
ND
50.0
03/17/20 16:52
Hexachlorobenzene
ug/L
ND
50.0
03/17/20 16:52
Hexachloroethane
ug/L
ND
50.0
03/17/20 16:52
Nitrobenzene
ug/L
ND
50.0
03/17/20 16:52
Pentachlorophenol
ug/L
ND
100
03/17/20 16:52
Pyridine
ug/L
ND
50.0
03/17/20 16:52
2,4,6-Tribromophenol (S)
%
76
27-108
03/17/20 16:52
2-Fluorobiphenyl (S)
%
78
13-107
03/17/20 16:52
2-Fluorophenol (S)
%
64
10-110
03/17/20 16:52
Nitrobenzene-d5 (S)
%
105
12-102
03/17/20 16:52 S3
Phenol-d6 (S)
%
41
10-110
03/17/20 16:52
Terphenyl-d14 (S)
%
86
21-132
03/17/20 16:52
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2834582
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
384
77
30-130
2,4,5-Trichlorophenol
ug/L
500
416
83
40-130
2,4,6-Trichlorophenol
ug/L
500
376
75
40-130
2,4-Dinitrotoluene
ug/L
500
423
85
49-130
2-Methyl phenol(o-Cresol)
ug/L
500
419
84
30-130
3&4-Methyl phenol (m&p Cresol)
ug/L
500
455
91
20-130
Hexachloro-1,3-butadiene
ug/L
500
380
76
10-130
Hexachlorobenzene
ug/L
500
399
80
30-130
Hexachloroethane
ug/L
500
361
72
10-130
Nitrobenzene
ug/L
500
442
88
20-130
Pentachlorophenol
ug/L
1000
875
87
10-140
Pyridine
ug/L
500
161
32
10-130
2,4,6-Tribromophenol (S)
%
84
27-108
2-Fluorobiphenyl (S)
%
75
13-107
2-Fluorophenol (S)
%
66
10-110
Nitrobenzene-d5 (S)
%
81
12-102
Phenol-d6 (S)
%
52
10-110
Terphenyl-d14 (S)
%
71
21-132
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2834584
2834585
MS
MSD
2629855004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
321
331
64
66
30-130
3
2,4,5-Trichlorophenol
ug/L
ND
500
500
389
540
78
108
40-130
33 R1
2,4,6-Trichlorophenol
ug/L
ND
500
500
221
431
44
86
40-130
65 R1
2,4-Dinitrotoluene
ug/L
ND
500
500
427
516
85
103
49-130
19
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
380
437
76
87
30-130
14
3&4-Methylphenol (m&p
ug/L
ND
500
500
326
423
65
85
20-130
26
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
303
307
61
61
10-130
1
Hexachlorobenzene
ug/L
ND
500
500
395
446
79
89
30-130
12
Hexachloroethane
ug/L
ND
500
500
289
295
58
59
10-130
2
Nitrobenzene
ug/L
ND
500
500
436
497
87
99
20-130
13
Pentachlorophenol
ug/L
ND
1000
1000
209
1050
21
105
10-140
133 R1
Pyridine
ug/L
ND
500
500
294
300
59
60
10-130
2
2,4,6-Tribromophenol (S)
%
74
106
27-108
2-Fluorobiphenyl (S)
%
76
81
13-107
2-Fluorophenol (S)
%
44
66
10-110
Nitrobenzene-d5 (S)
%
89
93
12-102
Phenol-d6 (S)
%
48
54
10-110
Terphenyl-d14 (S)
%
76
88
21-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 40

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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 530470 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92469224001
SAMPLE DUPLICATE: 2833020
92469230001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 16.2 16.6 2
SAMPLE DUPLICATE: 2833021
92469347001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 87.0 87.6 1
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 388185 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92469224001
METHOD BLANK: 1880468 Matrix: Water
Associated Lab Samples: 92469224001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Flashpoint deg F >200 60.0 03/16/20 15:50
SAMPLE DUPLICATE: 1880469
30354477001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531840 Analysis Method: EPA 1010A
QC Batch Method: EPA 1010A Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92469224001
SAMPLE DUPLICATE: 2839545
92469455002 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
SAMPLE DUPLICATE: 2839553
35536536001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 1445459
Analysis Method:
SM 2540G
QC Batch Method: 2540 G
Analysis Description:
Total Solids 2540 G-2011
Associated Lab Samples: 92469224001
METHOD BLANK: R3510481-1
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Solids
%
ND
03/18/20 11:14
LABORATORY CONTROL SAMPLE: R3510481-2
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Total Solids
%
50.0 50.0
100 85.0-115
SAMPLE DUPLICATE: R3510481-3
L1199598-01 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Solids
%
2.34 2.33
0.428
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 388251 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Associated Lab Samples: 92469224001
SAMPLE DUPLICATE: 1880778
Parameter
pH in water at 25 degrees C
30354667001 Dup
Units Result Result RPD Qualifiers
Std. Units 12.0 12.1 0 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531100 Analysis Method: EPA 9045D
QC Batch Method: EPA 9045D Analysis Description: 9045 pH
Associated Lab Samples: 92469224001
SAMPLE DUPLICATE: 2835663
Parameter
pH at 25 Degrees C
92469224001 Dup
Units Result Result RPD Qualifiers
Std. Units 9.0 9.0 0 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 40

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 530585
Analysis Method: EPA
350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod.
Analysis Description: 350.1
Ammonia
Associated Lab Samples: 92469224001
METHOD BLANK: 2833292
Matrix: Solid
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/kg
ND 9.1
03/16/20 13:56
LABORATORY CONTROL SAMPLE: 2833293
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/kg
463
464
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2833294
2833295
MS
MSD
2629849001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/kg 3270
3050
2880 5760
5300 82 70
90-110 8 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2833296
2833297
MS
MSD
92468646001
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Ammonia mg/kg 443
1280
1500 1750
1780 103 89
90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 530749
Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Associated Lab Samples: 92469224001
METHOD BLANK: 2834156
Matrix: Solid
Associated Lab Samples: 92469224001
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
ND 50.0
03/17/20 07:41
LABORATORY CONTROL SAMPLE: 2834157
Spike
LCS
LCS % Rec
Parameter Units
Conc.
Result
% Rec Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/kg
1000
1050
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834158
2834159
MS
MSD
92468237002
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 16300
1400
1050 17900
17600 116
126
90-110 2 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834160
2834161
MS
MSD
92468237003
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 21000
15800
15800 40800
42700 125
137
90-110 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 30 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 530489
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite
Associated Lab Samples: 92469224001
METHOD BLANK: 2833042
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
03/14/20 00:23
Nitrogen, Nitrite
mg/kg
ND 4.0
03/14/20 00:23
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
03/14/20 00:23
LABORATORY CONTROL SAMPLE: 2833043
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/kg
15 14.7
98 90-110
Nitrogen, Nitrite
mg/kg
10 10.2
102 90-110
Nitrogen, NO2 plus NO3
mg/kg
25 24.9
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2833044 2833045
MS MSD
92469468001
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units
Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/kg
ND
18.1 18.2 18.2
16.6 100 91
90-110 10
Nitrogen, Nitrite mg/kg
ND
12.2 12.2 11.6
11.5 96 94
90-110 1
Nitrogen, NO2 plus NO3 mg/kg
ND
30.3 30.5 29.8
28.1 97 90
90-110 6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 40

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531493 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92469224001
METHOD BLANK: 2837771 Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/kg ND 0.82 03/19/20 21:10
LABORATORY CONTROL SAMPLE: 2837772
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/kg 38.5 39.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2837773 2837774
MS MSD
92469468001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 25.0 55.3 57.5 71.2 69.4 83 77 90-110 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
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(�Ia'ne Analytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 531234
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Associated Lab Samples: 92469224001
METHOD BLANK: 2836364
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride mg/kg
ND 10.0
03/18/2018:13
LABORATORY CONTROL SAMPLE: 2836365
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chloride mg/kg
200 200
100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2836366 2836367
MS MSD
92467783001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 1100
145 142 1650
1460 377 250 90-110 12 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/30/2020 04:59 PM without the written consent of Pace Analytical Services, LLC.
Page 33 of 40

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 388255
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92469224001
METHOD BLANK: 1880790
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND
1.0 03/18/20 20:41
LABORATORY CONTROL SAMPLE: 1880791
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
99.3 ND
0 0-8
SAMPLE DUPLICATE: 1880792
30354764001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
1.0 U
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 388254
Analysis Method:
SM 4500S2F-2011
QC Batch Method: SW-846 7.3.4.2
Analysis Description:
734S Reactive Sulfide
Associated Lab Samples: 92469224001
METHOD BLANK: 1880787
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND
10.0 03/17/20 16:11
LABORATORY CONTROL SAMPLE: 1880788
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
199 35.8
18 0-52
SAMPLE DUPLICATE: 1880789
30354764001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Sulfide, Reactive
mg/kg
10.0 U
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
QC Batch: 619501
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92469224001
METHOD BLANK: 3367509
Matrix: Solid
Associated Lab Samples: 92469224001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Sulfate
mg/kg
ND 49.8
03/20/20 09:46
LABORATORY CONTROL SAMPLE: 3367510
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Sulfate
mg/kg
496 465
94
80-120
MATRIX SPIKE SAMPLE: 3367574
92469468001 Spike
MS
MS % Rec
Parameter
Units
Result Conc.
Result
% Rec Limits Qualifiers
Sulfate
mg/kg
ND 616
553
87 80-120
SAMPLE DUPLICATE: 3367573
92469468001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Sulfate
mg/kg
ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
POL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PAN
Pace Analytical National
PASI-A
Pace Analytical Services - Asheville
PASI-C
Pace Analytical Services - Charlotte
PASI-O
Pace Analytical Services - Ormond Beach
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
MH Matrix spike recovery and/or matrix spike duplicate recovery was above laboratory control limits. Result may be biased
high.
REPORT OF LABORATORY ANALYSIS
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(�Ia'ne Analytical
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QUALIFIERS
Project: Bi-Monthly Sludge
Pace Project No.: 92469224
ANALYTE QUALIFIERS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
R1 RPD value was outside control limits.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
REPORT OF LABORATORY ANALYSIS
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(�Ia'ne Analytical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Bi-Monthly Sludge
92469224
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92469224001
WTPSLUDGE
8151A
1445661
EPA8151
1445661
92469224001
WTPSLUDGE
EPA 3510C
531334
EPA 8081 B
531871
92469224001
WTPSLUDGE
EPA 3510C
531065
EPA 8082A
531872
92469224001
WTPSLUDGE
EPA 3050B
531376
EPA 6010D
531485
92469224001
WTPSLUDGE
EPA 3010A
531644
EPA 6010D
531661
92469224001
WTPSLUDGE
EPA 7470A
531646
EPA 7470A
531668
92469224001
WTPSLUDGE
EPA 7471 B
531409
EPA 7471 B
531456
92469224001
WTPSLUDGE
EPA 3510C
530878
EPA 8270E
530990
92469224001
WTPSLUDGE
EPA8260D
531914
92469224001
WTPSLUDGE
SM 2540G-2011
530913
92469224001
WTPSLUDGE
ASTM D2974-87
530470
92469224001
WTPSLUDGE
EPA 1010
388185
92469224001
WTPSLUDGE
EPA 1010A
531840
92469224001
WTPSLUDGE
2540 G
1445459
SM 2540G
1445459
92469224001
WTPSLUDGE
EPA9045C
388251
92469224001
WTPSLUDGE
EPA9045D
531100
92469224001
WTPSLUDGE
EPA 350.1 Rev 2.0 1993
530585
EPA 350.1 Rev 2.0 1993
530611
Mod.
Mod.
92469224001
WTPSLUDGE
EPA 351.2 Rev 2.0 1993
530749
EPA 351.2 Rev 2.0 1993
530830
92469224001
WTPSLUDGE
EPA 353.2 Rev 2.0 1993
530489
EPA 353.2 Rev 2.0 1993
530495
92469224001
WTPSLUDGE
EPA 365.1 Rev 2.0 1993
531493
EPA 365.1 Rev 2.0 1993
531539
92469224001
WTP SLUDGE
SM 4500-CI-E-2011
531234
SM 4500-CI-E-2011
531246
92469224001
WTP SLUDGE
SW-846 7.3.3.2
388255
EPA 9014
388451
92469224001
WTPSLUDGE
SW-846 7.3.4.2
388254
SM 4500S2F-2011
388452
92469224001
WTPSLUDGE
EPA 9056
619501
EPA 9056
619519
Date: 03/30/2020 04:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 40

CHAIN -OF -CUSTODY Analytical Request Document
LAB USE ONLY- Affix Workorder/Login Label Here or List Pace Workorder Number or
M
MTJL Lag -in Number HereWD#
11�7accAnalXical
- Chain -of -Custody is a LEGAL DOCUMENT- Complete all rel event fields
92469224
Company:
Billing Information:
ALL SHADED ARI
Container PreservativeT a ** II
1�
IIII
Addres :
S
�II II II II ��I
{) () [) 92411692241111 11
'" Preservative T es: 1 nitric acid, 2 sulfuric acid, 3
Types:
Report To:
Email To:
✓^
lr. M C . C rf_—
(6[ methanol, (7) sodium bisulfate, (8) sodium thiosulfatt
(C) ammonium hydroxide, (D) TSP, (U] Unpreserved, (CI) Other
Copy To: �Ld 1 r
Site Collection Info/Address:
T} 5
Analyses
Lab Profile/Line:
Customer Project Name/Number:
State: County/City: Time Zane Collected:
/ �<<zp�� [ , �T [ , MT [ cr
Lab Sample Receipt Checklist:
Ak R4 , Er
Custody Seals Present/Intact Y N DK
Custody Signatures present Y N Wr'
Phone:(Z5 Z)335- fq (.I,
Site/Facility ID #:
C mpliance Monitoring?
Finail:
`
CO—
[ ] Yes [ ] No
Collector Signature Present ,.)KN NA
Bottles intact .Y-N NA
Correct Bottles A� N NA
Cg�lected By (print):
Purchase Order#:
DW PWS ID #:
=fsl�
Quote #:
DW Location Code:
Sufficient Volume ,Y-N NA
Samples Received on Ice --Y N NA
VOA - Headspace Acceptable Y N �
Coll ted B (signatu ):
Turnaround Date Required:
Immediately Pace on Ice:
[ ] Yes [ ]No
USDA Regulated Soils Y N N<'
Samples in Holding Time -'1r N NA
Residual chlorine Present Y N NA
S ple Disposal:
Rush:
Field Filtered (if applicable):
] pispose as appropriate [ ] Return
[ ] Same Day [ ] Next Day
[ ] Yes [ ] No
Cl Strips:
I I Archive:
[ ] 2 Day ] ) 3 Day [ , 4 Day ( ] 5 Day
Sample pH Acceptable Y N NK
[ ]Hold:
(Expedite Charges Apply)
Analysis:
pH Strips:
sulfide Present Y N NA'
Lead Acetate strips:
* Matrix Codes {Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
LAB USE ONLY:
Lab Sample # / Comments:
Comp /
Collected (or
Composite End
Res
# of
Customer Sample ID
Matrix *
Grab
Composite Start[
Cl
Ctns
Date
Time
Date
Time
GJTP S(4c{
L
C
3-{(-Zc
2
L
[_
G
r
L
(Q
LIZ-
f
Customer Remarks / Special Conditions / Possible Hazards:
Type of Ice Used: t Blue Dry None
SHORT HOLDS PRESENT 1<72 hours): . Y N/A
Lab Sample Temperature Info:
Temp Blank Received: Y N NA
�>
Packing Material Used:
Lab Tracking#:
Therm IDM
l
Cooler 1 Temp Upon Receipt:. • oC
Radchem samples) screened (c500 cpm): Y N N
Samples received via: ` `
Cooler 1 Therm Corr. Factory - C
r
F X UPS Client Courier P rier
Cooler 1 Corrected Temp: FoC
Comments:
Relinquished by/Company: (Signature)
Date/Time:
Recei d by/Company: (Signat re)
Date;/Time
1 /
MTJL LAB USE ONLY
I
Table#:
Acctnum:
eli wished b Co
q y/ pany: (Signature)
Date/Time:
ceived by/Company: (Sig ture)
Date/Time:
CD
Template:
Trip Blank Received: Y N yP�
PreIQ I'
HCL McOH TSP Other
4 3inquished by/Company: (Signature)
Date/Time:
ived by/Company: (Signature)
Date/Time:
o
Tce
PM:
Non Conformance{s):
Page:
PB:
YES

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 5/7/2020
Solids 29.2
Mineralization Rate 0
Gallons per DT 821.26
pH
Sodium Absorpotion 0.40 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 157 lbs./1,000 gal 0.38
Ammonia Nitrogen (mg/Kg) 27.60 lbs./1,000 gal 0.07
Nitrate -Nitrite (mg/Kg) 13.60 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 27 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 41 lbs./1,000 gal 0.10
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.41
Phosphorus lbs./1,000 gal 0.32
Calcium lbs./1,000 gal 628.30
Magnesium lbs./1,000 gal 20.38
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.80
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.28
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.40
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.40
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
2.80
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.10
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
157
27 0.05
130
157
41 0.08
116
130
0 0.00
130
116
0 0.00
116
130
0 0.00
130
116
0 0.00
116
130
0 0.00
130
116
0 0.00
116
130
0 0.00
130
116
0 0.00
116
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 27 0.05
Total 41 0.08

(�Ia'ne Analytical
www.pacelabs.com
May 18, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Dear RAYMOND STATEN:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on May 08, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
Project logged under wrong Elizabeth City profile. Report has been revised to reflect correct profile identification. KIP 5/18
If you have any questions concerning this report, please feel free to contact me.
Sincerely, r
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: SCOTT OSBORNE, ELIZABETH CITY
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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(�Ia'ne Analytical
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SAMPLE ANALYTE COUNT
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92476849001 Sludge 1-9 EPA6010D
IDS, RDT
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
3
PASI-A
EPA 365.1 Rev 2.0 1993
CJH1
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
EPA9056
NMT
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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(�Ia'ne Analytical
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ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge 1-9 Lab ID: 92476849001 Collected: 05/07/20 13:10 Received: 05/08/20 11:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
10100 mg/kg
28.1
1 05/11/20 08:23
05/13/20 15:15
7429-90-5
Arsenic
ND mg/kg
2.8
1 05/11/20 08:23
05/13/20 15:15
7440-38-2
Cadmium
ND mg/kg
0.28
1 05/11/20 08:23
05/13/20 15:15
7440-43-9
Calcium
258000 mg/kg
281
10 05/11/20 08:23
05/14/20 14:51
7440-70-2
Chromium
ND mg/kg
1.4
1 05/11/20 08:23
05/13/20 15:15
7440-47-3
Copper
ND mg/kg
1.4
1 05/11/20 08:23
05/13/20 15:15
7440-50-8
Lead
ND mg/kg
1.4
1 05/11/20 08:23
05/13/20 15:15
7439-92-1
Magnesium
8370 mg/kg
28.1
1 05/11/20 08:23
05/13/20 15:15
7439-95-4
Molybdenum
ND mg/kg
1.4
1 05/11/20 08:23
05/13/20 15:15
7439-98-7
Nickel
ND mg/kg
1.4
1 05/11/20 08:23
05/13/20 15:15
7440-02-0
Potassium
ND mg/kg
1400
1 05/11/20 08:23
05/13/20 15:15
7440-09-7
Selenium
ND mg/kg
2.8
1 05/11/20 08:23
05/13/20 15:15
7782-49-2
Sodium
ND mg/kg
1400
1 05/11/20 08:23
05/13/20 15:15
7440-23-5
Zinc
3.1 mg/kg
2.8
1 05/11/20 08:23
05/13/20 15:15
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Pace Analytical Services - Asheville
Mercury
ND mg/kg
0.0065
1 05/12/2016:10
05/13/2012:32
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
29.2 %
0.10
1
05/11/20 17:12
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
70.8 %
0.10
1
05/11/20 16:56
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/kg
27.6
1 05/12/20 17:34
05/13/20 13:48
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
157 mg/kg
79.7
1 05/13/20 13:40
05/14/20 06:04
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
13.6
1 05/08/20 22:48
05/09/20 00:48
Nitrogen, Nitrate
ND mg/kg
13.6
1 05/08/20 22:48
05/09/20 00:48
14797-55-8
Nitrogen, Nitrite
ND mg/kg
13.6
1 05/08/20 22:48
05/09/20 00:48
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
132 mg/kg
3.0
1 05/08/2019:44
05/10/2011:04
7723-14-0
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge 1-9 Lab ID: 92476849001 Collected: 05/07/20 13:10 Received: 05/08/20 11:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 260 mg/kg 34.1 1 05/13/20 17:50 05/13/20 20:32 16887-00-6
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 475 mg/kg 171 1 05/12/2010:11 05/12/2018:19 14808-79-8
Date: 05/18/2020 12:58 PM
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 541054 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2883526
Associated Lab Samples: 92476849001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 2883527
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0060 05/13/2011:30
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.083 0.087 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2883528 2883529
MS MSD
92476815001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.0049 0.033 0.033 0.036 0.035 96 94 75-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 540741 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2882083
Associated Lab Samples: 92476849001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
05/13/2014:03
Arsenic
mg/kg
ND
1.0
05/13/2014:03
Cadmium
mg/kg
ND
0.10
05/13/2014:03
Calcium
mg/kg
ND
10.0
05/13/2014:03
Chromium
mg/kg
ND
0.50
05/13/2014:03
Copper
mg/kg
ND
0.50
05/13/2014:03
Lead
mg/kg
ND
0.50
05/13/2014:03
Magnesium
mg/kg
ND
10.0
05/13/2014:03
Molybdenum
mg/kg
ND
0.50
05/13/2014:03
Nickel
mg/kg
ND
0.50
05/13/2014:03
Potassium
mg/kg
ND
500
05/13/2014:03
Selenium
mg/kg
ND
1.0
05/13/2014:03
Sodium
mg/kg
ND
500
05/13/2014:03
Zinc
mg/kg
ND
1.0
05/13/2014:03
LABORATORY CONTROL SAMPLE:
2882084
Parameter
Units
Aluminum
mg/kg
Arsenic
mg/kg
Cadmium
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Lead
mg/kg
Magnesium
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Selenium
mg/kg
Sodium
mg/kg
Zinc
mg/kg
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
500
496
99
80-120
50
48.6
97
80-120
50
49.0
98
80-120
500
501
100
80-120
50
49.8
100
80-120
50
51.1
102
80-120
50
49.2
98
80-120
500
475
95
80-120
50
52.1
104
80-120
50
49.7
99
80-120
500
ND
95
80-120
50
45.3
91
80-120
500
492J
98
80-120
50
48.4
97
80-120
Pace Analytical Services, LLC
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Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
Bi-Monthly Residuals
92476849
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2882085
2882086
MS
MSD
92476117001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
22300
1450
1430
28000
28100
393
405
75-125
0 M1
Arsenic
mg/kg
6.3
145
143
141
141
93
94
75-125
1
Cadmium
mg/kg
1.3
145
143
138
136
94
94
75-125
2
Calcium
mg/kg
21000
1450
1430
22200
22100
87
78
75-125
1
Chromium
mg/kg
31.4
145
143
172
170
97
97
75-125
1
Copper
mg/kg
208
145
143
365
356
108
103
75-125
2
Lead
mg/kg
19.2
145
143
155
151
94
92
75-125
3
Magnesium
mg/kg
2720
1450
1430
4270
4220
107
105
75-125
1
Molybdenum
mg/kg
5.0
145
143
150
146
100
98
75-125
3
Nickel
mg/kg
18.7
145
143
162
158
99
97
75-125
3
Potassium
mg/kg
ND
1450
1430
3040
3030
120
121
75-125
1
Selenium
mg/kg
3.9
145
143
133
130
89
88
75-125
2
Sodium
mg/kg
ND
1450
1430
1780
1750
99
99
75-125
2
Zinc
mg/kg
735
145
143
870
865
92
91
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 540839 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92476849001
SAMPLE DUPLICATE: 2882605
92475703001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 23.6 25.3 7
SAMPLE DUPLICATE: 2882929
92477107001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 3.8 3.8 1
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 541140 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2883920
Associated Lab Samples: 92476849001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 2883921
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.8 05/13/2013:24
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 514 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2883922 2883923
MS MSD
92476117001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 6790 1930 1540 8910 8250 110 94 90-110 8
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 541199 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2884202
Associated Lab Samples: 92476849001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 2884203
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 34.5 05/14/20 05:49
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 963 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2884204 2884205
MS MSD
92476348001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 34700 2930 2380 39700 36000 171 55 90-110 10 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2884629 2884630
MS MSD
92477121002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 7000 1870 1810 8100 6650 59 -19 90-110 20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 540607 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2881617
Matrix: Solid
Associated Lab Samples: 92476849001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
05/09/20 00:53
Nitrogen, Nitrite
mg/kg
ND 4.0
05/09/20 00:53
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
05/09/20 00:53
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
LABORATORY CONTROL SAMPLE: 2881618
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.3 102 90-110
Nitrogen, Nitrite mg/kg 10 10.3 103 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2881619
2881620
MS
MSD
92476849001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
51.1
50.4
52.6
53.3
103
106
90-110 1
Nitrogen, Nitrite
mg/kg
ND
33.9
33.6
36.2
34.9
100
97
90-110 4
Nitrogen, NO2 plus NO3
mg/kg
ND
85
84.3
88.9
88.3
102
102
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 540547 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2881186
Associated Lab Samples: 92476849001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 2881187
Parameter Units
Phosphorus mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.86 05/10/2010:54
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
49 50.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2881188 2881189
MS MSD
92476045001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 1210 291 280 2390 2360 406 412 90-110 1 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
QC Batch: 541396 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92476849001
METHOD BLANK: 2885025
Associated Lab Samples: 92476849001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 2885026
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 05/13/2019:52
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 201 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2885027 2885028
MS MSD
92476849001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 260 339 339 580 579 94 94 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 632138 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92476849001
METHOD BLANK: 3436869
Associated Lab Samples: 92476849001
Parameter
Units
Sulfate
mg/kg
LABORATORY CONTROL SAMPLE:
3436870
Parameter
Units
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
3436872
Parameter
Units
Sulfate
mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 49.9 05/12/2015:02
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 519 104 80-120
35548411001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
31.3J 536 615 109 80-120
SAMPLE DUPLICATE: 3436871
35548411001 Dup
Parameter Units Result Result
Sulfate mg/kg 31.3J 43J
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALIFIERS
Project: Bi-Monthly Residuals
Pace Project No.: 92476849
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
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RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Bi-Monthly Residuals
92476849
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92476849001
Sludge 1-9
EPA 3050B
540741
EPA 6010D
540844
92476849001
Sludge 1-9
EPA 7471 B
541054
EPA 7471 B
541152
92476849001
Sludge 1-9
SM 2540G-2011
540813
92476849001
Sludge 1-9
ASTM D2974-87
540839
92476849001
Sludge 1-9
EPA 350.1 Rev 2.0 1993
541140
EPA 350.1 Rev 2.0 1993
541157
Mod.
Mod.
92476849001
Sludge 1-9
EPA 351.2 Rev 2.0 1993
541199
EPA 351.2 Rev 2.0 1993
541486
92476849001
Sludge 1-9
EPA 353.2 Rev 2.0 1993
540607
EPA 353.2 Rev 2.0 1993
540608
92476849001
Sludge 1-9
EPA 365.1 Rev 2.0 1993
540547
EPA 365.1 Rev 2.0 1993
540597
92476849001
Sludge 1-9
SM 4500-CI-E-2011
541396
SM 4500-CI-E-2011
541444
92476849001
Sludge 1-9
EPA 9056
632138
EPA 9056
632641
Date: 05/18/2020 12:58 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 19

WO# : 92476849
CHAIN -OF -CUSTODY Analytical Request Document
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92475$49
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RSTATEN CITYOFEC.COM
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Site Collection Info/Address:
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Page 19 of 19

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 7/27/2020
Solids 8.8
Mineralization Rate 0
Gallons per DT 2,725.09
pH
Sodium Absorpotion 24.09 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 540 lbs./1,000 gal 0.40
Ammonia Nitrogen (mg/Kg) 109.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 44.90 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 99 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 154 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.41
Phosphorus lbs./1,000 gal 0.16
Calcium lbs./1,000 gal 0.07
Magnesium lbs./1,000 gal 0.07
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
9.30
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.93
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
4.70
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
4.70
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.07
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
4.70
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
9.30
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
9.30
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
540
99 0.20
441
540
154 0.31
386
441
0 0.00
441
386
0 0.00
386
441
0 0.00
441
386
0 0.00
386
441
0 0.00
441
386
0 0.00
386
441
0 0.00
441
386
0 0.00
386
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 99 0.20
Total 154 0.31

(�Ia'ne Analytical
www.pacelabs.com
August 11, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Dear RAYMOND STATEN:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on July 28, 2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: SCOTT OSBORNE, ELIZABETH CITY
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 18

(�Ia'ne Analytical
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SAMPLE ANALYTE COUNT
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92487990001 Water Plant Sludge EPA 6010D
SH1
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
3
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
EPA9056
YMP
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 18

(�Ia'ne Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Sample: Water Plant Sludge
Lab ID: 92487990001 Collected:
07/27/20 08:00
Received: 07/28/20 10:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
ND mg/kg
93.0
1
07/30/20 08:33
07/31/20 12:30
7429-90-5
Arsenic
ND mg/kg
9.3
1
07/30/20 08:33
07/31/20 12:30
7440-38-2
Cadmium
ND mg/kg
0.93
1
07/30/20 08:33
07/31/20 12:30
7440-43-9
Calcium
ND mg/kg
93.0
1
07/30/20 08:33
07/31/20 12:30
7440-70-2
Chromium
ND mg/kg
4.7
1
07/30/20 08:33
07/31/20 12:30
7440-47-3
Copper
ND mg/kg
4.7
1
07/30/20 08:33
07/31/20 12:30
7440-50-8
Lead
ND mg/kg
4.7
1
07/30/20 08:33
07/31/20 12:30
7439-92-1
Magnesium
ND mg/kg
93.0
1
07/30/20 08:33
07/31/20 12:30
7439-95-4
Molybdenum
ND mg/kg
4.7
1
07/30/20 08:33
07/31/20 12:30
7439-98-7
Nickel
ND mg/kg
4.7
1
07/30/20 08:33
07/31/20 12:30
7440-02-0
Potassium
ND mg/kg
4650
1
07/30/20 08:33
07/31/20 12:30
7440-09-7
Selenium
ND mg/kg
9.3
1
07/30/20 08:33
07/31/20 12:30
7782-49-2
Sodium
ND mg/kg
4650
1
07/30/20 08:33
07/31/20 12:30
7440-23-5
Zinc
ND mg/kg
9.3
1
07/30/20 08:33
07/31/20 12:30
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Pace Analytical Services - Asheville
Mercury
ND mg/kg
0.068
1
07/31/2013:23
07/31/2014:40
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
8.8 %
0.10
1
07/29/20 14:28
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
91.2 %
0.10
1
07/29/20 14:20
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation
Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/kg
109
1
08/11/20 07:33
08/11/20 10:50
7664-41-7 R1
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
ND mg/kg
540
1
08/11/20 00:53
08/11/20 07:45
7727-37-9 R1
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
44.9
1
07/28/20 20:31
07/28/20 22:31
R1
Nitrogen, Nitrate
ND mg/kg
44.9
1
07/28/20 20:31
07/28/20 22:31
14797-55-8
Nitrogen, Nitrite
ND mg/kg
44.9
1
07/28/20 20:31
07/28/20 22:31
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
221 mg/kg
8.2
1
07/29/20 20:36
07/30/20 18:34
7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 18

(�Ia'ne Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92487990001 Collected: 07/27/20 08:00 Received: 07/28/20 10:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 413 mg/kg 113 1 08/10/20 21:49 08/11/20 00:20 16887-00-6
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 1750 mg/kg 567 1 08/03/20 12:00 08/05/20 20:39 14808-79-8
Date: 08/11/2020 12:09 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 18

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 557138 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2957458
Associated Lab Samples: 92487990001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 2957459
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0060 07/31 /20 14:26
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.083 0.092 110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2957460 2957461
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg ND 0.3 0.3 0.28 0.28 89 89 75-125 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 18

(�Ia'ne Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 556775 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2955897
Associated Lab Samples: 92487990001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
07/31/2012:01
Arsenic
mg/kg
ND
1.0
07/31/2012:01
Cadmium
mg/kg
ND
0.10
07/31/2012:01
Calcium
mg/kg
ND
10.0
07/31/2012:01
Chromium
mg/kg
ND
0.50
07/31/2012:01
Copper
mg/kg
ND
0.50
07/31/2012:01
Lead
mg/kg
ND
0.50
07/31/2012:01
Magnesium
mg/kg
ND
10.0
07/31/2012:01
Molybdenum
mg/kg
ND
0.50
07/31/2012:01
Nickel
mg/kg
ND
0.50
07/31/2012:01
Potassium
mg/kg
ND
500
07/31/2012:01
Selenium
mg/kg
ND
1.0
07/31/2012:01
Sodium
mg/kg
ND
500
07/31/2012:01
Zinc
mg/kg
ND
1.0
07/31/2012:01
LABORATORY CONTROL SAMPLE:
2955898
Parameter
Units
Aluminum
mg/kg
Arsenic
mg/kg
Cadmium
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Lead
mg/kg
Magnesium
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Selenium
mg/kg
Sodium
mg/kg
Zinc
mg/kg
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
500
472
94
80-120
50
46.0
92
80-120
50
47.7
95
80-120
500
473
95
80-120
50
48.0
96
80-120
50
48.9
98
80-120
50
47.5
95
80-120
500
455
91
80-120
50
48.4
97
80-120
50
48.8
98
80-120
500
ND
90
80-120
50
44.6
89
80-120
500
460J
92
80-120
50
46.3
93
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2955899
2955900
MS
MSD
92487994001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
187
679
729
1480
1110
190
127
75-125
28 M1,R1
Arsenic
mg/kg
ND
67.9
72.9
65.3
70.0
96
96
75-125
7
Cadmium
mg/kg
ND
67.9
72.9
67.1
72.3
99
99
75-125
7
Calcium
mg/kg
1650
679
729
2560
3940
135
315
75-125
42 M1,R1
Chromium
mg/kg
0.77
67.9
72.9
66.7
72.3
97
98
75-125
8
Copper
mg/kg
1.3
67.9
72.9
72.1
79.3
104
107
75-125
10
Lead
mg/kg
ND
67.9
72.9
66.5
71.8
98
99
75-125
8
Magnesium
mg/kg
418
679
729
1080
1120
98
96
75-125
3
Molybdenum
mg/kg
ND
67.9
72.9
68.6
74.8
101
103
75-125
9
Nickel
mg/kg
ND
67.9
72.9
68.5
74.6
100
102
75-125
8
Potassium
mg/kg
1390
679
729
2000
1960
90
79
75-125
2
Selenium
mg/kg
ND
67.9
72.9
65.4
71.2
96
98
75-125
9
Sodium
mg/kg
ND
679
729
661J
721J
95
97
75-125
Zinc
mg/kg
9.1
67.9
72.9
74.1
79.5
96
97
75-125
7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 556600 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92487990001
SAMPLE DUPLICATE: 2955095
92488076001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
18.1
18.0 1
SAMPLE DUPLICATE: 2955112
92488232001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
2.7
3.1 16
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 558962 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2965907
Associated Lab Samples: 92487990001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 2965908
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.3 08/11 /20 10:47
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
490 492 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965909 2965910
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg ND 4890 5670 4870 5590 99 99 90-110 14 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965911 2965912
MS MSD
92488344001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 5590 3090 2980 9110 9570 114 133 90-110 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 558745 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2965043
Associated Lab Samples: 92487990001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 2965044
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 08/11 /20 07:43
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 951 95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2965045 2965047
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg ND 9080 10300 8940 10200 94 95 90-110 13 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 556393 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2954286
Matrix: Solid
Associated Lab Samples: 92487990001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
07/28/20 22:29
Nitrogen, Nitrite
mg/kg
ND 4.0
07/28/20 22:29
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
07/28/20 22:29
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 2954287
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.6 104 90-110
Nitrogen, Nitrite mg/kg 10 10.0 100 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.6 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2954288
2954289
MS
MSD
92487990001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
169
169
218
178
128
105
90-110 20
Nitrogen, Nitrite
mg/kg
ND
113
113
108
110
95
98
90-110 3
Nitrogen, NO2 plus NO3
mg/kg
ND
283
283
325
288
110
97
90-110 12 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC.
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(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 556657 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2955382
Associated Lab Samples: 92487990001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 2955383
Parameter Units
Phosphorus mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.96 07/30/2018:30
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
44.6 44.4 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2955384 2955385
MS MSD
92487994001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 122 77 70.3 230 226 140 147 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 18

(�Ia'ne Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
QC Batch: 559042 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92487990001
METHOD BLANK: 2966303
Associated Lab Samples: 92487990001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 2966304
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 08/11/20 00:18
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 203 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2966305 2966306
MS MSD
92487990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 413 1100 1100 1550 1560 103 104 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 18

(�Ia'ne Analytical
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QUALIFIERS
Project: Bi-Monthly Residual Sludge Jul
Pace Project No.: 92487990
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 08/11 /2020 12:09 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Bi-Monthly Residual Sludge Jul
92487990
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92487990001
Water Plant Sludge
EPA 3050B
556775
EPA 6010D
556999
92487990001
Water Plant Sludge
EPA 7471 B
557138
EPA 7471 B
557232
92487990001
Water Plant Sludge
SM 2540G-2011
557185
92487990001
Water Plant Sludge
ASTM D2974-87
556600
92487990001
Water Plant Sludge
EPA 350.1 Rev 2.0 1993
558962
EPA 350.1 Rev 2.0 1993
559088
Mod.
Mod.
92487990001
Water Plant Sludge
EPA 351.2 Rev 2.0 1993
558745
EPA 351.2 Rev 2.0 1993
559079
92487990001
Water Plant Sludge
EPA 353.2 Rev 2.0 1993
556393
EPA 353.2 Rev 2.0 1993
556399
92487990001
Water Plant Sludge
EPA 365.1 Rev 2.0 1993
556657
EPA 365.1 Rev 2.0 1993
556957
92487990001
Water Plant Sludge
SM 4500-CI-E-2011
559042
SM 4500-CI-E-2011
559050
92487990001
Water Plant Sludge
EPA 9056
653519
EPA 9056
654541
Date: 08/11/2020 12:09 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 16 of 18

WO#:92487990
QJ

Document Name: Document Revised, February7, 2018
+ Sample Condition U an Recelpt(SCUR Page 1 of 2
26ArWocar Document No.: IssuingAuthorltyl:
c_rea_rc_naa.D— na Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Prol W AZMO gg�
verified and within the acceptance range forpreservation o� g
samples. PM. KPD Due Date: 08/11/20
Exceptlons; VOA, Collform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: 92_E 1 i zabeth
**Bottom half of box is to list number of.bottle
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pH Adjustment Log for Preserved Samples; .
Sample ID
Type of Preservative •
' PH upon receipt
Gate preservation, adjusted
Time piljusted'irvatlon
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Amount of Preservative
added
lot
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of ims roan wmresenc to me svnrcn t-aroona uennn Lei cu n.diwn V u— ti.C.
out of hold, Incorrect preservative, out of temp, Incorrect containers.
Page 18 of 18

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 9/9/2020
Solids 13.8
Mineralization Rate 0
Gallons per DT 1,737.74
pH
Sodium Absorpotion 2.13 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 301 lbs./1,000 gal 0.35
Ammonia Nitrogen (mg/Kg) 67.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 26.80 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 60 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 94 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.52
Phosphorus lbs./1,000 gal 0.26
Calcium lbs./1,000 gal 22.56
Magnesium lbs./1,000 gal 1.31
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
6.10
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.61
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
3.10
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
3.10
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
Mercury lbs./1,000 gal
Nickel (mg/Kg)
3.10
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
6.10
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
6.10
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
301
60 0.12
241
301
94 0.19
207
241
0 0.00
241
207
0 0.00
207
241
0 0.00
241
207
0 0.00
207
241
0 0.00
241
207
0 0.00
207
241
0 0.00
241
207
0 0.00
207
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 60 0.12
Total 94 0.19

(�Ia'ne Analytical
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September 23, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Dear RAYMOND STATEN:
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on September 10, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
REVISED REPORT. ORIGINAL REPORT LOGGED UNDER WRONG NAME. KIP 9/23
If you have any questions concerning this report, please feel free to contact me.
Sincerely, r
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: SCOTT OSBORNE, ELIZABETH CITY
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

014
aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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(�Ia'cie Analytical
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SAMPLE ANALYTE COUNT
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92494782001 Sludge Sample EPA 6010D
SH1
14
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
DMN
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
3
PASI-A
EPA 365.1 Rev 2.0 1993
NAL
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
EPA9056
YMP
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
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(�Ia'cie Analytical
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ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge Sample Lab ID: 92494782001 Collected: 09/09/20 08:30 Received: 09/10/20 12:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
1080 mg/kg
61.3
1 09/17/20 14:23
09/18/20 23:17
7429-90-5
Arsenic
ND mg/kg
6.1
1 09/17/20 14:23
09/18/20 23:17
7440-38-2
Cadmium
ND mg/kg
0.61
1 09/17/20 14:23
09/18/20 23:17
7440-43-9
Calcium
19600 mg/kg
61.3
1 09/17/20 14:23
09/18/20 23:17
7440-70-2
Chromium
ND mg/kg
3.1
1 09/17/20 14:23
09/18/20 23:17
7440-47-3
Copper
ND mg/kg
3.1
1 09/17/20 14:23
09/18/20 23:17
7440-50-8
Lead
ND mg/kg
3.1
1 09/17/20 14:23
09/18/20 23:17
7439-92-1
Magnesium
1140 mg/kg
61.3
1 09/17/20 14:23
09/18/20 23:17
7439-95-4
Molybdenum
ND mg/kg
3.1
1 09/17/20 14:23
09/18/20 23:17
7439-98-7
Nickel
ND mg/kg
3.1
1 09/17/20 14:23
09/18/20 23:17
7440-02-0
Potassium
ND mg/kg
3060
1 09/17/20 14:23
09/18/20 23:17
7440-09-7
Selenium
ND mg/kg
6.1
1 09/17/20 14:23
09/18/20 23:17
7782-49-2
Sodium
ND mg/kg
3060
1 09/17/20 14:23
09/18/20 23:17
7440-23-5
Zinc
ND mg/kg
6.1
1 09/17/20 14:23
09/18/20 23:17
7440-66-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
13.8 %
0.10
1
09/11/20 17:14
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
86.2 %
0.10
1
09/11/20 17:05
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/kg
67.0
1 09/13/20 09:18
09/14/20 10:13
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
ND mg/kg
301
1 09/16/20 05:32
09/17/20 04:30
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
26.8
1 09/10/20 22:15
09/11/20 00:39
Nitrogen, Nitrate
ND mg/kg
26.8
1 09/10/20 22:15
09/11/20 00:39
14797-55-8
Nitrogen, Nitrite
ND mg/kg
26.8
1 09/10/20 22:15
09/11/20 00:39
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
225 mg/kg
5.7
1 09/14/2016:03
09/15/2013:11
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
264 mg/kg
72.2
1 09/21/20 19:16
09/21/20 20:53
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,
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Date: 09/23/2020 09:46 AM
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Services, LLC.
Page 4 of 18

(�Ia'cie Analytical
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ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Sludge Sample Lab ID: 92494782001 Collected: 09/09/20 08:30 Received: 09/10/20 12:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 1090 mg/kg 360 1 09/16/20 12:00 09/16/20 20:53 14808-79-8
REPORT OF LABORATORY ANALYSIS
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Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
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(�Ia'cie Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 567075 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 3004823
Associated Lab Samples: 92494782001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
09/19/20 20:32
Arsenic
mg/kg
ND
1.0
09/19/20 20:32
Cadmium
mg/kg
ND
0.10
09/19/20 20:32
Calcium
mg/kg
ND
10.0
09/19/20 20:32
Chromium
mg/kg
ND
0.50
09/19/20 20:32
Copper
mg/kg
ND
0.50
09/19/20 20:32
Lead
mg/kg
ND
0.50
09/19/20 20:32
Magnesium
mg/kg
ND
10.0
09/19/20 20:32
Molybdenum
mg/kg
ND
0.50
09/19/20 20:32
Nickel
mg/kg
ND
0.50
09/19/20 20:32
Potassium
mg/kg
ND
500
09/19/20 20:32
Selenium
mg/kg
ND
1.0
09/19/20 20:32
Sodium
mg/kg
ND
500
09/19/20 20:32
Zinc
mg/kg
ND
1.0
09/19/20 20:32
LABORATORY CONTROL SAMPLE:
3004824
Parameter
Units
Aluminum
mg/kg
Arsenic
mg/kg
Cadmium
mg/kg
Calcium
mg/kg
Chromium
mg/kg
Copper
mg/kg
Lead
mg/kg
Magnesium
mg/kg
Molybdenum
mg/kg
Nickel
mg/kg
Potassium
mg/kg
Selenium
mg/kg
Sodium
mg/kg
Zinc
mg/kg
Qualifiers
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
500
490
98
80-120
50
47.6
95
80-120
50
47.0
94
80-120
500
487
97
80-120
50
49.7
99
80-120
50
49.7
99
80-120
50
48.1
96
80-120
500
481
96
80-120
50
50.1
100
80-120
50
48.7
97
80-120
500
ND
99
80-120
50
44.6
89
80-120
500
499J
100
80-120
50
46.2
92
80-120
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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(�Ia'cie Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3004825
3004826
MS
MSD
92494166001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
10600
545
559
10400
11600
-20
183
75-125
10 M1,M6
Arsenic
mg/kg
15.3
54.5
55.9
67.2
70.8
95
99
75-125
5
Cadmium
mg/kg
1.2
54.5
55.9
55.1
57.1
99
100
75-125
4
Calcium
mg/kg
350000
545
559
314000
371000
-6690
3700
75-125
17 M6
Chromium
mg/kg
11.9
54.5
55.9
57.4
59.5
84
85
75-125
4
Copper
mg/kg
43.9
54.5
55.9
94.7
98.8
93
98
75-125
4
Lead
mg/kg
9.6
54.5
55.9
53.6
55.4
81
82
75-125
3
Magnesium
mg/kg
10700
545
559
15000
14400
791
666
75-125
4 M6
Molybdenum
mg/kg
5.3
54.5
55.9
56.0
57.6
93
93
75-125
3
Nickel
mg/kg
31.7
54.5
55.9
75.7
79.3
81
85
75-125
5
Potassium
mg/kg
3680
545
559
4100
4400
77
128
75-125
7 M1
Selenium
mg/kg
2.4
54.5
55.9
52.3
54.0
92
92
75-125
3
Sodium
mg/kg
935
545
559
1360
1470
77
96
75-125
8
Zinc
mg/kg
73.9
54.5
55.9
128
124
99
90
75-125
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 565966 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92494782001
SAMPLE DUPLICATE: 2999600
92494550001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 17.8 18.4 3
SAMPLE DUPLICATE: 2999601
92494782001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 86.2 86.7 1
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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(�Ia'cie Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 566038 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 3000057
Associated Lab Samples: 92494782001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 3000058
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 09/14/20 09:54
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 501 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3000059 3000060
MS MSD
92493491001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 4820 2330 2150 6550 5800 74 45 90-110 12 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 566623 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 3002865
Associated Lab Samples: 92494782001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 3002866
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 50.0 09/17/20 04:22
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
1000 1060 106 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3002867 3002868
MS MSD
92494673001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg 85.7 1270 1090 1290 1120 95 95 90-110 15 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 565723 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 2998338
Matrix: Solid
Associated Lab Samples: 92494782001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
09/11/20 00:23
Nitrogen, Nitrite
mg/kg
ND 4.0
09/11/20 00:23
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
09/11/20 00:23
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 2998339
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 15.2 102 90-110
Nitrogen, Nitrite mg/kg 10 9.8 98 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 25.0 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2998340
2998341
MS
MSD
92494747001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
16.9
16.9
17.7
17.5
105
104
90-110 1
Nitrogen, Nitrite
mg/kg
ND
11.3
11.3
11.3
11.3
100
100
90-110 0
Nitrogen, NO2 plus NO3
mg/kg
ND
28.1
28.1
29.0
28.8
102
101
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 566117 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 3000336
Associated Lab Samples: 92494782001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 3000337
Parameter Units
Phosphorus mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.98 09/15/2012:57
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
44.6 44.3 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3000338 3000339
MS MSD
92494315001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 98.3 74.8 95.6 206 302 144 213 90-110 38 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3000340 3000341
MS MSD
92494315002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 108 57 80.8 136 133 49 31 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

(�Ia'cie Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
QC Batch: 567867 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92494782001
METHOD BLANK: 3009174
Associated Lab Samples: 92494782001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 3009175
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 09/21 /20 20:51
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 203 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3009176 3009177
MS MSD
92494782001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 264 722 722 993 998 101 102 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
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(�Ia'cie Analytical
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QUALITY CONTROL DATA
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 665748 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92494782001
METHOD BLANK: 3620896
Associated Lab Samples: 92494782001
Parameter Units
Sulfate mg/kg
LABORATORY CONTROL SAMPLE: 3620897
Parameter Units
Sulfate mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 49.8 09/16/2019:25
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
498 513 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3620899 3620898
MS MSD
92494782001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/kg 1090 3590 3620 4530 4550 96 96 80-120 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC.
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(�Ia'cie Analytical
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QUALIFIERS
Project: Bi-Monthly Residuals
Pace Project No.: 92494782
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 09/23/2020 09:46 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 18

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Bi-Monthly Residuals
92494782
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92494782001
Sludge Sample
EPA 3050B
567075
EPA 6010D
567287
92494782001
Sludge Sample
SM 2540G-2011
566204
92494782001
Sludge Sample
ASTM D2974-87
565966
92494782001
Sludge Sample
EPA 350.1 Rev 2.0 1993
566038
EPA 350.1 Rev 2.0 1993
566069
Mod.
Mod.
92494782001
Sludge Sample
EPA 351.2 Rev 2.0 1993
566623
EPA 351.2 Rev 2.0 1993
567018
92494782001
Sludge Sample
EPA 353.2 Rev 2.0 1993
565723
EPA 353.2 Rev 2.0 1993
565727
92494782001
Sludge Sample
EPA 365.1 Rev 2.0 1993
566117
EPA 365.1 Rev 2.0 1993
566294
92494782001
Sludge Sample
SM 4500-CI-E-2011
567867
SM 4500-CI-E-2011
567935
92494782001
Sludge Sample
EPA 9056
665748
EPA 9056
666242
Date: 09/23/2020 09:46 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 18

aceAtaalylical m
City of Elizabeth City
1 Wilson St
Elizabeth City, NC 27909
Sept.: Bi-Monthly Residuals
WO# : 92494782
rkorderNtirtrberar
CHAIN -OF -CUSTODY Analytical Request Document
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Chain -of -Custody is a LEGAL DOCUMENT- Complete all relevent fields
ti~r
-
Billing Information:
'^+
92494782
Container Preservative Type "
lat}os�yN,.9..a�rra�ge� sac
Preservatiwe Types_ (t) nitric acid, (Z) sulfuricacid, 13) hydrochloric acid, (4) sodium hydnixlde, (5) zinc acetate,
Site COIIeGtIOn Info/Address:
{6} methanal. (7) sodium bksulfatc, (a) sod)am thlmulfa % 19) hexane,
(A) ascorbic ac1d, tB) ammonium sulfate,
IC) anunaniurn hydroxide, (D) TSP, (u) Unpresowed, (0) Other
Analyses
{ab,PY&fiile/L[ne
252 337-6626 Site/Facility Q ta: / Com nce Monitoring?
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[ Yes [ ]No g 4 e 54u ba J' v
C ed B rint : Purchase Order ri : x k f` 3'4 yL °� �` f
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Quote IS: flW Location Code: ��'- � d �`-• ^x_ r�i; �aZ 5i��c� o��'�t0 V�Sa:�ti,
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Col( ign ure Turnaround Date Required. Imm ately Packed on Ice: �k5�tea fa wr r rz _ kr
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(Expedrre Charges Apply) Analysis:; C'] ., <�} [] <{ .' sz Ha. pstxar-
` Matrix Code, (Insert In M'atrbr box below): Drinking Water (DW), Ground Water (GW1, Wastewater (WW), O
Produd (P), SoillSol'ld SL , 4i1 OL , W e WP ,Air AR ,Tissue 75 , Bioassa (B), Vapor tn' '
[ ) ( ) P ( ) ( ) ( ) Y (V), Other JOT) h ' � O U z i e s3x ggt7d oak r
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Customer Sample ID Matrix Grab Composite Start) Ci Ctns #1Y Z Jh } I Y' ✓ F,
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Document Name:
Sam le Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.06
Issuing Authority:
Pace Carolinas Quality Office
*Check.mark top half of box if pH and/or dechlorination Is Project #
verifled.and within the acceptance range for preservation:
samples. .
Exceptions: VOA, Coliferm, TOC, Oil and Grease, DRO/8015'(water) DOC; LLHg
*'Bottom half of box is to list number of bottle
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Sample I❑ Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preseruative Lat #
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Note: Whenever there ia'a discrepancy affecting North Carolina compliance samples, a Copy of this form wl11 be sent to the North Carolina DEHlR Certlflcatlon Office (Le.
Out of hold, Incorrect preseivadve, out of temp, incorrect containers.
Page 18 of 18

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 11/19/2020
Solids 2
Mineralization Rate 0
Gallons per DT 11,990.41
pH
Sodium Absorpotion 1.04 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 2,350 lbs./1,000 gal 0.39
Ammonia Nitrogen (mg/Kg) 475.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 197.00 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 435 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 672 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.90
Phosphorus lbs./1,000 gal 0.20
Calcium lbs./1,000 gal 60.55
Magnesium lbs./1,000 gal 5.84
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
34.80
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
3.50
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
17.40
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
17.40
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.20
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
17.40
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
34.80
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
34.80
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
2,350
435 0.87
1,916
2,350
672 1.34
1,678
1,916
0 0.00
1,916
1,678
0 0.00
1,678
1,916
0 0.00
1,916
1,678
0 0.00
1,678
1,916
0 0.00
1,916
1,678
0 0.00
1,678
1,916
0 0.00
1,916
1,678
0 0.00
1,678
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 435 0.87
Total 672 1.34

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 17, 2020
RAYMOND STATEN
CITY OF ELIZABETH CITY
1 WILSON ST.
Elizabeth City, NC 27909
RE: Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Dear RAYMOND STATEN:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: SCOTT OSBORNE, ELIZABETH CITY
Accounts Payable, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

014
aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Ohio DEP 87780
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92507544001 SLUDGE EPA6010D
BG2, SH1
14
PASI-A
EPA 7471 B
SOO
1
PASI-A
SM 2540G-2011
KDF
1
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 350.1 Rev 2.0 1993 Mod.
KDF1
1
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
JKG
3
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
EPA 9056
EDC
1
PASI-O
PASI-A = Pace Analytical Services -Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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(�Ia'ne Analytical
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ANALYTICAL RESULTS
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE Lab ID: 92507544001 Collected: 11/19/20 11:20 Received: 11/20/20 14:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Pace Analytical Services - Asheville
Aluminum
42600 mg/kg
348
1 11/29/2012:08
11/30/2016:43
7429-90-5
Arsenic
ND mg/kg
34.8
1 11/29/2012:08
11/30/2016:43
7440-38-2
Cadmium
ND mg/kg
3.5
1 11/29/2012:08
11/30/2016:43
7440-43-9
Calcium
363000 mg/kg
4350
5 11/29/2012:08
12/01/2014:09
7440-70-2
Chromium
ND mg/kg
17.4
1 11/29/2012:08
11/30/2016:43
7440-47-3
Copper
ND mg/kg
17.4
1 11/29/2012:08
11/30/2016:43
7440-50-8
Lead
ND mg/kg
17.4
1 11/29/2012:08
11/30/2016:43
7439-92-1
Magnesium
35000 mg/kg
348
1 11/29/2012:08
11/30/2016:43
7439-95-4
Molybdenum
ND mg/kg
17.4
1 11/29/2012:08
11/30/2016:43
7439-98-7
Nickel
ND mg/kg
17.4
1 11/29/2012:08
11/30/2016:43
7440-02-0
Potassium
ND mg/kg
17400
1 11/29/2012:08
11/30/2016:43
7440-09-7
Selenium
ND mg/kg
34.8
1 11/29/2012:08
11/30/2016:43
7782-49-2
Sodium
ND mg/kg
17400
1 11/29/2012:08
11/30/2016:43
7440-23-5
Zinc
ND mg/kg
34.8
1 11/29/2012:08
11/30/2016:43
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation
Method: EPA 7471 B
Pace Analytical Services - Asheville
Mercury
ND mg/kg
0.20
1 11/30/2014:00
12/02/2010:45
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 2540G-2011
Pace Analytical Services - Charlotte
Total Solids
2.0 %
0.10
1
11/24/20 17:44
Percent Moisture
Analytical Method: ASTM D2974-87
Pace Analytical Services - Charlotte
Percent Moisture
98.0 %
0.10
1
11/24/20 17:38
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0 1993 Mod.
Pace Analytical Services - Asheville
Nitrogen, Ammonia
ND mg/kg
475
1 11/24/20 09:31
11/24/20 13:24
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Kjeldahl, Total
ND mg/kg
2350
1 12/02/20 12:22
12/03/20 03:18
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, NO2 plus NO3
ND mg/kg
197
1 11/21/20 12:37
11/21/20 14:00
Nitrogen, Nitrate
ND mg/kg
197
1 11/21/20 12:37
11/21/20 14:00
14797-55-8
Nitrogen, Nitrite
ND mg/kg
197
1 11/21/20 12:37
11/21/20 14:00
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
1220 mg/kg
39.2
1 11/30/20 22:19
12/01/20 19:55
7723-14-0
REPORT OF LABORATORY ANALYSIS
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M1,R1
H1,H2
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ANALYTICAL RESULTS
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE Lab ID: 92507544001 Collected: 11/19/20 11:20 Received: 11/20/20 14:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 1890 mg/kg 479 1 11/23/20 20:49 11/24/20 02:35 16887-00-6
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Pace Analytical Services - Ormond Beach
Sulfate 7140 mg/kg 2470 1 12/16/20 12:00 12/17/20 07:43 14808-79-8
Date: 12/17/2020 05:30 PM
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 583163 Analysis Method: EPA 7471 B
QC Batch Method: EPA 7471 B Analysis Description: 7471 Mercury
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3083571
Associated Lab Samples: 92507544001
Parameter Units
Mercury mg/kg
LABORATORY CONTROL SAMPLE: 3083572
Parameter Units
Mercury mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0036 12/02/2010:33
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.05 0.054 108 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3083573 3083574
MS MSD
92507727006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury mg/kg 0.014 0.1 0.097 0.13 0.12 108 107 75-125 9
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 583161 Analysis Method: EPA 6010D
QC Batch Method: EPA 3050B Analysis Description: 6010 MET
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3083563
Associated Lab Samples: 92507544001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
Aluminum
mg/kg
ND
10.0
11/30/2016:14
Arsenic
mg/kg
ND
1.0
11/30/2016:14
Cadmium
mg/kg
ND
0.10
11/30/2016:14
Calcium
mg/kg
ND
25.0
11/30/2016:14
Chromium
mg/kg
ND
0.50
11/30/2016:14
Copper
mg/kg
ND
0.50
11/30/2016:14
Lead
mg/kg
ND
0.50
11/30/2016:14
Magnesium
mg/kg
ND
10.0
11/30/2016:14
Molybdenum
mg/kg
ND
0.50
11/30/2016:14
Nickel
mg/kg
ND
0.50
11/30/2016:14
Potassium
mg/kg
ND
500
11/30/2016:14
Selenium
mg/kg
ND
1.0
11/30/2016:14
Sodium
mg/kg
ND
500
11/30/2016:14
Zinc
mg/kg
ND
1.0
11/30/2016:14
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3083564
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Aluminum
mg/kg
250
258
103
80-120
Arsenic
mg/kg
25
24.3
97
80-120
Cadmium
mg/kg
25
24.2
97
80-120
Calcium
mg/kg
250
252
101
80-120
Chromium
mg/kg
25
25.0
100
80-120
Copper
mg/kg
25
25.5
102
80-120
Lead
mg/kg
25
25.0
100
80-120
Magnesium
mg/kg
250
240
96
80-120
Molybdenum
mg/kg
25
26.0
104
80-120
Nickel
mg/kg
25
25.4
102
80-120
Potassium
mg/kg
250
ND
101
80-120
Selenium
mg/kg
25
23.1
92
80-120
Sodium
mg/kg
250
ND
98
80-120
Zinc
mg/kg
25
23.9
96
80-120
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Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3083565
3083566
MS
MSD
92507727006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Aluminum
mg/kg
27200
277
274
31800
31700
1650
1640
75-125
0 E,M1
Arsenic
mg/kg
1.9
27.7
27.4
27.0
27.1
90
92
75-125
0
Cadmium
mg/kg
ND
27.7
27.4
25.9
24.7
93
90
75-125
5
Calcium
mg/kg
254
277
274
503
507
90
93
75-125
1
Chromium
mg/kg
4.7
27.7
27.4
32.7
31.3
101
97
75-125
4
Copper
mg/kg
12.7
27.7
27.4
41.9
41.1
105
104
75-125
2
Lead
mg/kg
9.2
27.7
27.4
33.9
32.7
89
86
75-125
4
Magnesium
mg/kg
1560
277
274
1850
1910
103
130
75-125
4 M1
Molybdenum
mg/kg
0.84
27.7
27.4
26.5
25.1
93
89
75-125
6
Nickel
mg/kg
2.6
27.7
27.4
28.6
27.0
94
89
75-125
6
Potassium
mg/kg
1490
277
274
1790
1810
109
119
75-125
1
Selenium
mg/kg
ND
27.7
27.4
23.4
22.8
85
83
75-125
3
Sodium
mg/kg
ND
277
274
293J
277J
98
94
75-125
Zinc
mg/kg
32.6
27.7
27.4
58.9
58.4
95
95
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 582790 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92507544001
SAMPLE DUPLICATE: 3082037
92508124001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 16.2 15.1 7
SAMPLE DUPLICATE: 3082043
92508107003 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 21.3 23.1 8
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 582538 Analysis Method: EPA 350.1 Rev 2.0 1993 Mod.
QC Batch Method: EPA 350.1 Rev 2.0 1993 Mod. Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3080481
Associated Lab Samples: 92507544001
Parameter Units
Nitrogen, Ammonia mg/kg
LABORATORY CONTROL SAMPLE: 3080482
Parameter Units
Nitrogen, Ammonia mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.4 11 /24/20 13:16
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
472 459 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080483 3080484
MS MSD
92505102002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/kg 3470 446 455 3750 3720 62 55 90-110 1 M6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 583903 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3086829
Associated Lab Samples: 92507544001
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
LABORATORY CONTROL SAMPLE: 3086830
Parameter Units
Nitrogen, Kjeldahl, Total mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 31.2 12/03/20 03:16
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
690 643 93 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3086831 3086832
MS MSD
92507544001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/kg ND 43000 43000 32800 40100 75 92 90-110 20 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 582145 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3078851
Matrix: Solid
Associated Lab Samples: 92507544001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/kg
ND 4.0
11/21/20 14:04
Nitrogen, Nitrite
mg/kg
ND 4.0
11/21/20 14:04
Nitrogen, NO2 plus NO3
mg/kg
ND 4.0
11/21/20 14:04
LABORATORY CONTROL SAMPLE: 3078852
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/kg 15 14.6 97 90-110
Nitrogen, Nitrite mg/kg 10 10.3 103 90-110
Nitrogen, NO2 plus NO3 mg/kg 25 24.9 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3078853
3078854
MS
MSD
92507544001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Nitrate
mg/kg
ND
741
741
728
718
98
97
90-110 1
Nitrogen, Nitrite
mg/kg
ND
494
494
501
506
102
102
90-110 1 H1
Nitrogen, NO2 plus NO3
mg/kg
ND
1240
1240
1230
1220
98
97
90-110 0 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 583402 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3084804
Associated Lab Samples: 92507544001
Parameter Units
Phosphorus mg/kg
LABORATORY CONTROL SAMPLE: 3084805
Parameter Units
Phosphorus mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 12/01 /20 18:30
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
45.5 45.0 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3084806 3084807
MS MSD
92507524001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/kg 91.6 59.3 62.7 122 129 52 59 90-110 5 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
QC Batch: 582491 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92507544001
METHOD BLANK: 3080368
Associated Lab Samples: 92507544001
Parameter Units
Chloride mg/kg
LABORATORY CONTROL SAMPLE: 3080369
Parameter Units
Chloride mg/kg
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10.0 11 /24/20 02:33
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
200 208 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080370 3080371
MS MSD
92507544001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/kg 1890 4790 4790 6770 6830 102 103 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 690043 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92507544001
METHOD BLANK: 3757605
Associated Lab Samples: 92507544001
Parameter Units
Sulfate mg/kg
LABORATORY CONTROL SAMPLE: 3757606
Parameter Units
Sulfate mg/kg
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 49.9 12/17/20 06:58
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
502 484 96 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3757608 3757607
MS MSD
92507544001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/kg 7140 24700 24800 29100 29100 89 89 80-120 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: SLUDGE-NOVEMBER
Pace Project No.: 92507544
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
POL - Practical Quantitation Limit.
Pace Analytical Services, LLC
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RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
H1 Analysis conducted outside the EPA method holding time.
H2 Extraction or preparation conducted outside EPA method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
SLUDGE-NOVEMBER
92507544
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92507544001
SLUDGE
EPA 3050B
583161
EPA 6010D
583178
92507544001
SLUDGE
EPA 7471 B
583163
EPA 7471 B
583354
92507544001
SLUDGE
SM 2540G-2011
583013
92507544001
SLUDGE
ASTM D2974-87
582790
92507544001
SLUDGE
EPA 350.1 Rev 2.0 1993
582538
EPA 350.1 Rev 2.0 1993
582599
Mod.
Mod.
92507544001
SLUDGE
EPA 351.2 Rev 2.0 1993
583903
EPA 351.2 Rev 2.0 1993
584139
92507544001
SLUDGE
EPA 353.2 Rev 2.0 1993
582145
EPA 353.2 Rev 2.0 1993
582150
92507544001
SLUDGE
EPA 365.1 Rev 2.0 1993
583402
EPA 365.1 Rev 2.0 1993
583714
92507544001
SLUDGE
SM 4500-CI-E-2011
582491
SM 4500-CI-E-2011
582497
92507544001
SLUDGE
EPA 9056
690043
EPA 9056
690544
Date: 12/17/2020 05:30 PM
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Document Name:
Document Revised: October 28, 2020
8A1131ytIC�l +
Sample Condition !lean Recelpt(SCUR
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.D7
Face Carolinas Quality Office
laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville ❑ RalelghN Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name: praject wog : 92507544
I Upon Receiptr
01 j
Courier: ❑Fed 6x ❑UPS ❑USP5 ❑Client
❑ Commercial Pace ❑Other: 92507544
Custody Seal Present? ❑Yes &No seals intact? Des RJNo
Date/initials Person Examining Contents:�LU
Packing Material: []Bubble Wrap MBBubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: IP1 .❑Yes ❑No RIN/A
❑ III Gun ID: &f [ M '-') Typo of Ice. ,c'iwet ❑Blue ❑None
5.Correction Factor:
CooierTemp: Add/Subtract ('C) IV • Temp should he above freezing to 6'C
+� ❑Samples out of temp criteria. Samples on Ice,'cooling process
Cooler Temp Corrected ('C): 5.3 has begun
USDA Regulated Sall (LRN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign saurce {Internationally,
Comments/Discrepancy: u
Chain of Custody Present?
Yes
❑Na
ONIA
1.
Samples Arrived within Hold Time?
NYas
[]No
N/A
2.
Short Hold Time Analysis (<72 hr.)?
fRYel
El No
N/A
3,
Rush Turn Around Time Requested?
QYes
Jallo
N/A
4.
Sufficient volume?
Yes
❑No
❑N/A
5.
Correct Containers Used?
Pace Containers Used?
(Yes
MYes
❑Na
No
❑N/A
❑N/a
6.
Containers Intact?
Yes
ONo
QNIA
7.
Dissolved analysis; Samples Field Filtered?
Des
Eho
/A
8.
9.
Sample Labels Match COCZ # JkYes []No❑N/A
-Includes Date/11me/ID/Analysis Matrix: L
Headspace in VOA Vials (55-6mm)?
QYes
No
N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
EjYes
[]No
❑No
A�N/A
N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted; Date/Time:
Project Manager SCURF Review: 1y
Project Manager SRF Review: '
Field. Data Required? []Yes ❑No
Lot ID of spilt containers:
Date:
Date:
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Page 18 of 20

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Document Name:
:andition Upon Recel
Document No.:
F-CAR-CS-033-Rev,07
*Check mark top half of box If pH and/or dechlorination is Proj
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Off and Grease, DRO/8015 (water) DOC, LLHg
*'"Bottom half of box is to fist number of bottles
Document Reused: October 29, 2020
Page 2 of 2
issuing Authority:
WO#:92507544
PM: KFD Due Date: 12/03/20
CLIENT: 92-Elizabeth
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservatlun adjusted
Time preservatlon
adjusted
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added
Lot#
Note: whenever there fs a discrepancy affecting North Caronna compllance samples, a copy ortnfs rorm v+in ne sent to the North Laroiina or MNH Lertirecation Umee ii.e.
out of hold, incorrect preservative, uutof temp, Incorrect contalners.
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Page 20 of 20

City of Elizabeth City
2020 Class B Annual Report
WQ Permit# WQ0002883
Land Application Field Summary Forms

PernutNumber WQ0002883
Facility Name City of Elizabeth City
LandOwner Lawrence Larabee
Operator
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Site# LL County Pasquotank Crop 1 Wheat, Grain
Field Name 33 SoilSeries Pettigrew Crop 1 Pan 111
Acres Permited 22.37 Soil Abbrevation: Crop 2
Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied
% Solids Used DT/Ac. Tons
Source
Condition Precip
Method
P Volatilization Mineralization
TKN Ammonia -Nitrite PAN
PAN Crop
01/02/2020 Gallons 312,000
4.90 22.37 2.85 63.75
Elizabeth City WWTP
Moist < 0.5"
Surface
86.64 0.50 0.3
47,300 1,020.00 80.30 82.50
Crop 1
01/03/2020 Gallons 195,000
12.60 22.37 4.58 102.46
Elizabeth City WTP
Moist < 0.5"
Surface
1.85 0.50 0
319 7.90 31.50 0.32
Crop 1
Total Volume Applied
507,000
Total Dry Tons 166.21
Sum Total P 88.49
Total 82.82
Total
Reported in Gallons
Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel
Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.131
0.014
1.076 0.140
0.080
0.002
0.066
0.075
0.131
3.706
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.128
0.023
2.597 0.087
0.284
0.005
0.095
0.158
0.113
8.127
Cumulative Total
0.259
0.037
3.673 0.227
0.365
0.007
0.161
0.233
0.244
11.833
Permitted CPLR
36
34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-11-2021 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 34 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 19.88 Soil Abbrevation: Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip
Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
01/02/2020 Gallons 273,000 4.90
19.88 2.81 55.78
Elizabeth
City WWTP
Moist < 0.5"
Surface
85.30
0.50
0.3 47,300
1,020.00 8030 81.23
Crop 1
Total Volume Applied 273,000
Total Dry Tons 55.78
Sum Total P
85.30
Total 81.23
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.089 0.010
1.038 0.117
0.058
0.001
0.044
0.053
0.089
3.608
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 0.140 0.025
2.697 0.104
0.296
0.006
0.101
0.172
0.125
8.436
Cumulative Total 0.229 0.034
3.735 0.221
0.354
0.007
0.145
0.225
0.213
12.044
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-11-2021 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermitNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 35 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 20.26 Soil Abbrevation: Crop 2
Operator Crop 2 Pan
Volume
Acres
Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used
DT/Ac. Tons
Source
Condition Precip
Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
02/02/2020 Gallons
227,000 4.90
20.26
2.29 46.38
Elizabeth City WWTP
Moist < 0.5"
Surface
69.60
0.50
0.3 47,300
1,020.00 8030
66.27
Crop 1
02/03/2020 Gallons
191,000 12.60
20.26
4.95 100.36
Elizabeth City WTP
Moist < 0.5"
Surface
2.00
0.50
0 319
7.90 31.50
0.35
Crop 1
Total Volume Applied
418,000
Total Dry Tons 146.74
Sum Total P
71.60
Total
66.63
Total
Reported in Gallons Arsenic Cadmium
Copper
Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.117 0.012
0.870
0.118
0.070 0.001
0.059
0.066
0.117
2.989
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.131 0.025
2.872
0.108
0.303 0.006
0.096
0.166
0.115
9.026
Cumulative Total
0.248 0.037
3.741
0.227
0.374 0.007
0.155
0.232
0.232
12.015
Permitted CPLR
36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-11-2021 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 36 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 20.31 Soil Abbrevation: Crop 2
Operator Crop 2 Pan
Volume
Acres
Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used
DT/Ac. Tons
Source
Condition Precip
Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
03/02/2020 Gallons 260,000 4.90
20.31
2.62 53.13
Elizabeth
City WWTP
Moist < 0.5"
Surface
79.52
0.50
0.3 47,300
1,020.00 8030 75.72
Crop 1
Total Volume Applied 260,000
Total Dry Tons 53.13
Sum Total P
79.52
Total 75.72
Total
Reported in Gallons Arsenic Cadmium
Copper
Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.083 0.009
0.968
0.109
0.054
0.001
0.041
0.050
0.083
3.364
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 0.121 0.025
3.169
0.120
0.318
0.006
0.091
0.161
0.103
10.025
Cumulative Total 0.204 0.034
4.137
0.230
0.373
0.007
0.133
0.211
0.185
13.389
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-11-2021 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 37 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 18.33 Soil Abbrevation: Crop 2
Operator Crop 2 Pan
Volume
Acres
Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used
DT/Ac. Tons
Source
Condition Precip
Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
03/02/2020 Gallons
130,000 4.90
18.33
1.45 26.56
Elizabeth City WWTP
Moist < 0.5"
Surface
44.05
0.50
0.3 47,300
1,020.00 80.30
41.95
Crop 1
03/03/2020 Gallons
182,000 26.20
18.33
10.85 198.84
Elizabeth City WTP
Moist < 0.5"
Surface
4.10
0.50
0 153
34.70 14.90
0.70
Crop 1
Total Volume Applied
312,000
Total Dry Tons 225.41
Sum Total P
48.15
Total
42.65
Total
Reported in Gallons Arsenic Cadmium
Copper
Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.122 0.013
0.573
0.097
0.067 0.001
0.060
0.064
0.122
1.940
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.119 0.025
3.085
0.113
0.312 0.006
0.090
0.157
0.101
9.750
Cumulative Total
0.240 0.037
3.658
0.210
0.379 0.006
0.150
0.222
0.222
11.690
Permitted CPLR
36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-11-2021 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

City of Elizabeth City
2020 Class B Annual Report
WQ Permit# WQ0002883
Pathogen & Vector Attraction Reduction Forms
Elizabeth City W WP
Lime Stabilization Records

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number: NCO025011
Monitoring Period: 01/01/2020 to 03/31/2020
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry 0 0 Continuous Grab Samples
Weight)
Analytical Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
❑ requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Andrew Edwards, Chief Operator J. Bryan Smith, President
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
�
0�? �
�� a .+f.�. 2/11 /2021
I
Signature of Preparer* Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Thursday, February 11, 2021

City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates: January 2020
NPDES Permit # NCO025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit # NCO025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.00)
Temp (°c)
Shipped
to SST
#lor2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(2 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#1
JM
1/5/2020
0800
12.74
-0.24
12.50
16.9°
1M
1/5/2020
1000
12.70
-0.21
12.49
17.90
#1
1M
1/6/2020
0800
12.19
-0.24
11.95
17.80
20000
#1
RT
1/5/2020
1900
12.89
-0.27
12.62
16.90
RT
1/5/2020
2100
12.90
-0.31
12.60
15.70
#1
RT
1/6/2020
1900
12.44
-0.24
12.20
17.40
20000
#1
DR
1/8/2020
0300
12.30
-0.27
12.03
16.40
DR
1/8/2020
0500
12.27
-0.27
12.00
16.10
#1
DR
1/9/2020
0300
12.10
-0.27
11.83
15.70
20000
#2
SC
1/10/2020
18001
12.64
-0.211
12.43
17.70
SC
1/10/20201
2000
12.68
-0.21
12.47
17.50
#2
RT
1/11/20201
1500
12.35
-0.15
12.20
20.40
20000
#1
RT
1/11/2020
2100
12.29
-0.15
12.14
20.10
QS
1/12/2020
2320
12.24
-0.15
12.09
20.20
#1
DE
1/16/20201
1346
12.20
-0.21
11.99
18.10
20000
#2
SC
1/12/2020
1200
12.46
-0.15
12.31
20.30
SC
1/12/2020
1420
12.44
-0.12
12.32
20.50
#2
1M
1/13/20201
1200
12.36
-0.15
12.21
20.80
20000
#1
QS
1/13/2020
0315
12.50
-0.18
12.32
19.80
QS
1/13/2020
0520
12.47
-0.15
12.32
20.10
#2
SC
1/14/2020
0325
12.46
-0.15
12.31
20.40
20000
#2
RT
1/14/2020
1800
12.62
-0.15
12.42
20.40
RT
1/14/2020
2000
12.60
-0.15
12.42
20.30
#2
RT
1/15/2020
1800
12.50
-0.24
12.26
17.70
20000
#1
SC
1/15/2020
0925
12.61
-0.21
12.40
18.10
SC
1/15/2020
1930
12.54
-0.15
12.39
20.20
#2
SC
1/16/2020
0925
12.42
-0.24
12.18
16.50
20000
#2
DR
1/15/2020
2300
12.53
-0.21
12.32
17.6°
DR
1/16/2020
0100
12.49
-0.24
12.25
17.90
#2
DR
1/16/2020
2300
12.56
-0.21
12.35
17.70
20000
#1
SC
1 1/16/2020
1130
12.61
-0.18
12.43
19.4°
SC
1/16/2020
1348
12.58
-0.18
12.40
19.40
#2
1 SC
1/17/2020
1200
12.55
-0.30
12.25
14.90
20000
#2
DR
1/17/2020
01001
12.37
-0.241
12.13
17.1°
DR
1/17/20201
0300
12.32
-0.24
12.08
16.90
#1
DR
1/18/2020
0100
12.25
-0.27
11.981
16.20
20000
#1
SC
1/17/2020
1100
12.68
-0.27
12.41
16.4°
SC
1/17/2020
1330
12.60
-0.24
12.36
16.90
#1
JM
1 1/18/2020
1100
12.62
-0.27
12.40
16.10
20000
#2
JM
1/18/2020
0800
12.62
-0.30
12.32
15.2°
1M
1/18/2020
1000
12.57
-0.27
12.30
16.40
#1
QS
1/19/2020
0820
12.49
-0.24
12.25
17.80
20000
#2
QS
1/21/2020
0200
12.51
-0.33
12.18
14.3°
QS
1/21/2020
0400
12.50
-0.33
12.17
14.30
#1
QS
1/22/2020
0215
12.51
-0.33
12.18
14.30
20000
#1
RT
1/22/2020
1800
12.50
-0.36
12.14
13.5°
RT
1/22/2020
2000
12.46
-0.33
12.13
14.40
#1
RT
1/23/2020
1800
12.48
-0.33
12.15
14.70
20000
#2
DR
1/25/2020
0430
12.71
-0.24
12.47
16.9°
DR
1/25/2020
0630
12.64
-0.24
12.40
16.70
#2
DR
1/26/2020
0530
12.52
-0.30
12.22
15.10
20000
#1
QS
1/26/2020
2045
12.80
-0.30
12.50
15.6°
QS
1/26/2020
2245
12.72
-0.301
12.42
15.80
#1
RT
1/27/2020
2045
12.18
-0.30
11.88
15.10
20000
#2
DR
1 1/29/20201
0100
12.71
-0.27
12.44
15.8°
DR
1/29/2020
0300
12.37
-0.30
12.67
15.50
#2
QS
1/30/2020
0115
12.60
-0.36
12.24
13.60
20000
#1
QS
1/29/2020
2350
12.71
-0.33
12.38
14.8°
QS
1/30/2020
0200
12.611
-0.33
12.35
14.30
#1
QS
1/31/2020
0120
12.56
-0.36
12.20
13.4°
20000
#2
SC
1/31/2020
1016
12.52
-0.27
12.25
16.3°
SC
1/31/2020
1352
12.45
-0.24
12.21
17.30
#1
JM
2/1/2020
1025
12.63
-0.24
12.39
17.3°
20000
#1
DR
1/31/2020
2030
12.70
-0.30
12.40
15.40
DR
1/31/2020
2230
12.61
-0.30
12.31
15.20
#1
DR
2/1/20201
20301
12.29
-0.301
11.99
15.2-1
20000
Sheet Total (Gallons):
1 440000
* LST#1 was shipped early by SC and when a 24hr pH was grabbed from SST#1 was taken
it didn't meet the 11.50 limit so several batches of lime are being added to SST#1 to bring pH up.

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Partner Electrode pH Probe - SN 59001-34
Dates: February 2020 Oakton Temperature Probe -SN 35613-13
NPDES Permit# NC0025011
Residuals Permit p WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit# NC0025011
Residuals Permit p WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.00)
Temp (°c)
Shipped
to SST
#Ior2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(211.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#2
DR
2/4/2020
0130
12.69
-0.27
12.42
16.4°
DR
2/4/2020
0330
12.62
-0.27
12.35
16.2°
#2
DR
2/5/2020
0130
12.24
-0.24
12.00
17.3°
20000
#1
QS
2/4/2020
1140
12.77
-0.24
12.53
17.9°
QS
2/4/2020
1340
12.69
-0.21
12.48
18.01
#2
QS
2/5/2020
1210
12.52
-0.24
12.32
17.2°
20000
#2
SC
2/4/2020
2000
12.69
-0.21
12.48
17.9°
SC
2/4/2020
2200
12.65
-0.21
12.44
17.5'1
#2
RT
2/5/2020
2000
12.62
-0.30
12.30
15.11
20000
#1
QS
2/5/2020
12501
12.71
-0.21
12.50
18.7'1
QS
1 2/5/2020
1450
12.72
-0.211
12.51
18.3°
#2
1M
1 2/6/2020
1250
12.51
-0.241
12.27
17.2°
20000
#2
DR
2/6/2020
0100
12.65
-0.24
12.41
17.4°
DR
2/6/2020
0300
12.59
-0.24
12.35
17.1°
#2
QS
2/7/2020
0100
12.49
-0.18
12.31
19.3°
20000
#1
JM
2/6/2020
1215
12.70
-0.21
12.49
18.4°
DE
2/6/2020
1419
12.68
-0.18
12.50
18.91
#2
1M
2/7/2020
1230
12.49
-0.21
12.28
18.6°
20000
#1
QS
2/7/2020
0420
12.72
-0.24
12.48
17.5°
QS
2/7/2020
0620
12.67
-0.24
12.43
17.7°
#1
QS
2/8/2020
0420
12.67
-0.30
12.37
15.3°
20000
#2
RT
2/7/2020
1830
12.61
-0.24
12.40
17.3°
QS
2/7/2020
2056
12.59
-0.30
12.29
15.51
#2
QS
2/8/2020
18311
12.53
-0.27
12.26
16.8°
20000
#2
QS
2/12/2020
0705
12.67
-0.24
12.43
17.9°
QS
2/12/2020
0920
12.70
-0.18
12.52
18.01
#2
QS
2/13/2020
0705
12.47
-0.18
12.30
19.51
20000
#1
RT
2/12/2020
2000
12.29
-0.30
12.00
15.7°
RT
2/12/2020
2200
12.22
-0.27
12.00
16.3°
#1
RT
2/13/2020
2000
11.60
-0.24
11.40
17.4°
20000
#2
DR
2/14/2020
0100
12.63
-0.21
12.42
18.11
DR
2/14/2020
0300
12.60
-0.21
12.39
17.9'1
#2
QS
2/15/2020
0100
12.50
-0.24
12.26
17.1°
20000
#1
1 CS
1 2/15/2020
00101
12.65
-0.30
12.35
15.6'1
QS
1 2/15/2020
0210
12.64
-0.271
12.37
16.1°
#1
QS
1 2/16/2020
0100
12.46
-0.271
12.19
16.8°
20000
#2
SC
2/18/2020
1000
12.70
-0.21
12.49
17.6°
SC
2/18/2020
1200
12.66
-0.21
12.45
17.7°
#1
SC
2/19/2020
1020
12.63
-0.21
12.42
18.11
20000
#1
DR
2/19/2020
0415
12.67
-0.21
12.46
17.7°
DR
2/19/2020
0615
12.62
-0.24
12.38
17.4°
#1
DR
2/20/2020
0415
12.51
-0.30
12.21
15.2°
20000
#2
DR
2/20/2020
1130
12.66
-0.33
12.33
14.0°
DR
2/21/2020
0130
12.60
-0.33
12.27
13.6°
#2
QS
2/21/2020
2340
12.67
-0.33
12.34
14.6°
20000
#1
RT
2/21/2020
1700
12.64
-0.39
12.30
12.6°
RT
2/21/2020
1900
12.94
-0.39
12.60
12.2°
#1
RT
2/22/2020
17001
12.79
-0.33
12.50
14.5°
20000
#2
DR
2/25/2020
0200
12.76
-0.27
12.49
15.9°
DR
2/25/2020
0400
12.68
-0.27
12.41
16.1°
#2
DR
2/26/2020
0200
12.52
-0.27
12.25
16.2°
20000
#1
RT
2/25/2020
1900
12.79
-0.241
12.55
17.5°
RT
2/25/20201
2100
12.79
-0.24
12.55
17.0°
#1
QS
2/26/2020
1900
12.66
-0.27
12.39
16.7°
20000
#2
SC
2/27/2020
1130
12.49
-0.24
12.25
17.4°
SC
2/27/20201
1330
12.42
-0.21
12.211
17.50
#1
SC
2/28/2020
1230
12.21
-0.21
12.00
17.7°
20000
#1
1 CS
1 2/27/2020
2030
12.79
-0.30
12.49
15.1°
QS
2/27/2020
2230
12.80
-0.30
12.50
15.20
#1
RT
2/28/2020
2000
12.68
-0.27
12.41
16.4°
20000
#2
DR
2/29/2020
0600
12.62
-0.30
12.32
14.9°
SC
2/29/2020
1000
12.66
-0.27
12.39
16.2°
#2
DR
3/1/2020
0600
12.67
-0.36
12.31
13.1°
20000
#1
1 RT
1 2/29/20201
20301
12.69
-0.39
12.30
12.6-1
RT
1 2/29/20201
22301
12.66
-0.301
12.36
15.4°
#2
1 RT
1 3/1/2020
2000
12.43
-0.271
12.16
16.1°
20000
Sheet Total
(Gallons):
440000

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Parmer Electrode pH Probe - SN 59001-34
Dates: March 2020 Oakton Temperatu re Probe -SN 35613-13
NPDES Permit# NC0025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit# NC0025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.00)
Temp (°c)
Shipped
to SST
#lor2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#2
QS
3/2/2020
2345
12.63
-0.24
12.39
17.3°
QS
3/3/2020
0145
12.60
-0.24
12.40
17.40
#2
DR
3/3/2020
2345
12.55
-0.27
12.28
15.70
20000
#1
SC
3/4/2020
0940
12.60
-0.21
12.39
18.20
SC
3/4/2020
1140
12.52
-0.21
12.31
18.10
#2
SC
3/5/2020
0950
12.22
-0.24
11.98
16.70
20000
#2
DR
3/6/2020
0345
12.71
-0.27
12.44
16.50
DR
3/6/2020
0545
12.66
-0.27
12.39
16.30
#2
DR
3/7/2020
0345
12.57
-0.27
12.30
15.70
20000
#1
QS
3/6/2020
15301
12.66
-0.24
12.42
17.40
QS
1 3/6/2020
1745
12.61
-0.221
12.34
16.90
#1
RT
1 3/7/2020
1530
12.49
-0.241
12.25
17.40
20000
#1
RT
3/9/2020
1700
12.42
-0.18
12.24
19.70
RT
3/9/2020
1900
12.51
-0.24
12.27
17.90
#2
RT
3/10/2020
1700
12.15
-0.18
11.97
19.50
20000
#2
QS
3/10/2020
0650
12.64
-0.24
12.40
17.20
SC
3/10/2020
0919
12.59
-0.21
12.38
17.80
#2
QS
3/11/2020
0650
12.43
-0.24
12.19
17.70
20000
#2
DR
3/13/2020
0003
12.19
-0.18
12.01
19.10
DR
3/13/2020
0230
12.17
-0.18
11.99
18.80
#2
DR
3/14/2020
0030
12.13
-0.18
11.95
19.50
20000
#1
SC
3/13/2020
1130
12.22
-0.15
12.07
20.20
SC
3/13/2020
13301
12.12
-0.15
11.97
19.80
#1
QS
3/14/2020
14001
11.70
-0.15
11.55
20.90
20000
#1
QS
3/15/2020
0745
12.42
-0.21
12.21
18.30
QS
3/15/2020
09451
12.34
-0.21
12.13
18.10
#2
SC
3/16/2020
0726
12.37
-0.33
12.04
14.30
20000
#2
QS
3/15/2020
1430
12.64
-0.24
12.40
17.40
RT
3/15/2020
1630
12.55
-0.24
12.31
17.30
#2
RT
3/16/2020
1500
12.29
-0.24
12.05
17.60
20000
#1
JM
3/17/2020
1015
12.10
-0.21
11.89
18.10
JM
3/17/2020
1215
12.02
-0.24
11.78
17.40
#1
JM
3/18/2020
1030
11.70
-0.15
11.55
19.50
20000
#2
QS
1 3/18/2020
02501
12.44
-0.21
12.23
18.80
QS
1 3/18/2020
0450
12.35
-0.151
12.20
19.2°
#2
QS
1 3/19/2020
0300
12.16
-0.181
11.98
19.10
20000
#2
DR
3/20/2020
0130
12.41
-0.15
12.26
20.40
DR
3/20/2020
0330
12.24
-0.15
12.09
20.20
#1
DR
3/21/2020
0130
12.05
-0.09
11.96
22.10
20000
#1
RT
3/20/2020
2000
12.64
-0.12
12.52
21.50
RT
3/20/2020
2200
12.63
-0.12
12.75
21.30
#1
QS
3/21/2020
2000
12.49
-0.15
12.34
20.30
20000
#2
DR
3/24/2020
0430
12.44
-0.24
12.20
17.50
DR
3/24/2020
0630
12.40
-0.24
12.16
17.40
#1
DR
3/25/2020
0430
12.01
-0.21
11.80
17.80
20000
#2
RT
3/24/2020
1500
12.14
-0.21
11.93
18.70
RT
3/24/2020
1700
12.09
-0.24
11.85
17.80
#1
RT
3/25/20201
1500
11.85
-0.21
11.64
18.60
20000
#1
RT
3/25/2020
1900
12.62
-0.24
12.38
17.20
RT
3/25/20201
21001
12.60
-0.27
12.33
16.70
#2
RT
3/26/20201
1900
12.12
-0.15
11.97
20.10
20000
#2
SC
3/26/2020
0830
12.40
-0.24
12.16
16.80
JM
3/26/2020
1030
12.32
-0.21
12.11
17.80
#1
SC
3/27/2020
0830
12.19
-0.15
12.04
19.60
20000
#1
RT
3/27/2020
1800
12.09
-0.15
11.94
20.20
RT
3/2
2000
12.00
-0.18
11.82
19.30
#1
RT
3/28/2020
1800
11.53
-0.15
11.38
20.30
20000
#2
QS
3/28/2022
1215
12.39
-0.09
12.30
22.9°
QS
/2020
3/28/2020
1325
12.30
-0.03
12.27
24.7°
#2
QS
3/29/2020
1215
12.13
-0.03
12.10
24.40
20000
#2
DR
3/31/2020
6600
12.56
-0.15
12.41
19.6°
QS
3/31/2020
0800
12.52
-0.18
12.34
19.30
#1
QS
4/1/2020
1345
12.24
-0.18
12.06
19.20
20000
Sheet Total
(Gallons):
420000

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number: N00025011
Monitoring Period: 04/01/2020 to 06/30/2020
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry o
0 Continuous Grab Samples
Weight)
Analytical Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization
°GI certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Andrew Edwards, Chief Operator
Preparer Name and Title (type or print)
IMS /
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
2/11 /2021
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Thursday, February 11, 2021

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Partner Electrode pH Probe - SN 59001-34
Dates: April 2020 Oakton Temperature Probe -SN 35613-13
NPDES Permit# NC0025011
Residuals Permit p WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit# NC0025011
Residuals Permit p WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.20)
Temp ("c)
Analyst
Date
Tim,
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.00)
Temp (°c)
Shipped
to SST
itlor2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(211.50)
Temp (°c)
Stabilization
Amount
(Gallons)
fit
DR
4/2/2020
0400
12.55
-0.21
12.34
17.7°
DR
4/2/2020
0600
12.53
-0.21
12.32
17.6°
fit
DE
4/3/2020
0720
12.28
-0.24
12.04
16.6°
20000
#1
RT
4/2/2020
1700
12.49
-0.18
12.31
19.11
RT
4/2/2020
1900
12.58
-0.21
12.37
18.30
fit
RT
4/3/2020
1700
12.34
-0.15
12.19
20.3°
20000
Al
DR
4/8/2020
0430
12.46
-0.15
12.31
20.3°
DR
4/8/2020
0630
12.44
-0.15
12.29
20.00
#2
QS
4/9/2020
0445
12.21
-0.18
12.03
21.9-1
20000
fit
SC
4/9/2020
14201
12.27
-0.06
12.21
23.1°
SC
4/10/2020
0845
11.98
-0.12
11.86
20.5°
#2
SC
1 4/10/2020
1400
11.97
-0.091
11.88
22.0°
20000
Al
QS
4/10/2020
0005
12.57
-0.18
12.39
19.3°
QS
4/10/2020
0205
12.64
-0.24
12.40
17.2°
#2
JM
4/11/2020
0010
12.18
-0.15
12.03
20.0°
20000
#1
QS
4/13/2020
0115
12.36
-0.15
12.21
20.1°
QS
4/13/2020
0315
12.29
-0.15
12.14
20.5°
#2
QS
4/14/2020
0120
11.95
-0.18
11.77
21.0°
20000
A2
QS
4/14/2020
0145
12.62
-0.18
12.44
21.3°
QS
4/14/2020
0355
12.60
-0.18
12.42
21.0°
#2
QS
4/15/2020
0145
12.50
-0.15
12.35
20.6°
20000
#1
JM
4/14/2020
2000
12.42
-0.15
12.27
20.1°
JM
4/14/2020
2200
12.40
-0.15
12.25
19.7°
#2
JM
4/15/2020
20001
12.15
-0.21
11.94
17.8°
20000
Al
DR
4/19/2020
1200
12.52
-0.15
12.37
19.7°
DR
4/19/2020
1400
12.49
-0.15
12.34
20.0°
#1
DR
4/20/2020
1200
12.40
-0.15
12.25
19.11
20000
fit
QS
4/20/2020
0230
12.33
-0.15
12.18
20.4°
QS
4/20/2020
0500
12.25
-0.18
12.07
21.2°
#2
QS
4/21/2020
0230
12.02
-0.15
11.80
19.11
20000
A2
QS
4/22/2020
0000
12.43
-0.151
12.28
20.4°
QS
4/22/2020
02001
12.38
-0.151
12.23
20.1'1
#2
QS
4/23/2020
0000
12.28
-0.15
12.13
19.5'1
20000
#1
1 1M
1 4/22/20201
17301
12.36
-0.12
12.24
21.2°
JM
4/22/2020
19301
12.19
-0.121
12.07
20.6°
#2
JM
4/23/2020
1730
11.63
-0.121
11.51
21.0°
20000
Al
1 DR
4/29/2020
0900
12.13
-0.12
12.01
21.2°
SC
4/29/2020
1110
11.97
-0.09
11.88
21.6°
Back SST
SC
4/29/2020
0900
11.79
-0.09
11.70
22.2°
20000
fit
RT
4/29/2020
1840
12.29
-0.09
12.20
22.2°
RT
4/29/2020
2040
12.30
-0.12
12.18
21.5°
7f2
JM
4/30/2020
1840
12.02
-0.06
11.96
22.6°
20000
Al
1 QS
1 4/29/20201
23301
12.45
-0.12
12.33
21.3°
QS
5/1/20201
01401
12.44
-0.121
12.32
21.1°
#1
SC
5/1/2020
2340
12.35
-0.12
12.23
21.7°
20000
Sheet Total (Gallons):
300000

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Parmer Electrode pH Probe - SN 59001-34
Dates: Mav 2020 Oakton Temperature Probe - SN 35613-13
NPDES Permit p NC0025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit p NC0025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.00)
Temp (°c)
Shipped
to SST
#Ior2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#2
DE
5/1/2020
1028
12.36
-0.06
12.30
22.6°
DE
5/1/2020
1315
12.35
-0.12
12.23
21.3°
#2
JM
5/2/2020
1030
11.63
-0.09
11.54
22.3°
20000
#2
RT
5/4/2020
1940
12.23
-0.09
12.14
22.3°
RT
5/4/2020
2140
12.22
-0.12
12.10
21.7°
#2
RT
5/5/2020
1940
11.97
-0.12
11.85
21.4°
20000
#I
SC
5/5/2020
1010
12.32
-0.12
12.20
21.4°
SC
5/5/2020
1210
12.29
-0.12
12.17
21.4'1
#2
SC
5/6/2020
1010
12.07
-0.09
11.98
21.7'l
20000
#2
QS
5/6/2020
23451
12.42
-0.121
12.30
21.1°
QS
5/7/20201
0200
12.39
-0.15
12.24
20.8°
#2
Qs
5/7/20201
2345
11.83
-0.12
11.81
21.3°
20000
#I
DR
5/7/2020
1330
12.46
-0.12
12.34
21.0°
RT
5/7/2020
1530
12.26
-0.09
12.17
22.3°
#2
SC
5/8/20201
1400
12.24
-0.09
12.15
22.1°
20000
#2
JM
5/8/2020
2200
12.36
-0.12
12.24
21.2°
QS
5/9/2020
0000
12.38
-0.12
12.26
21.0°
#2
JM
5/9/2020
2200
12.21
-0.12
12.09
20.9°
20000
#I
DR
5/9/2020
0930
12.37
-0.15
12.22
20.4°
DR
5/9/2020
1130
12.36
-0.15
12.21
20.5°
#2
JM
5/10/2020
0930
12.15
-0.12
12.03
21.2°
20000
#I
Qs
5/10/2020
2350
12.45
-0.15
12.30
20.0°
QS
5/11/2020
0158
12.37
-0.15
12.22
20.9°
#2
SC
5/12/2020
0215
12.39
-0.15
12.24
20.2°
20000
#2
DE
5/11/2020
1412
12.30
-0.06
12.24
22.7°
RT
5/11/2020
1612
12.27
-0.09
12.18
22.8°
#2
DR
5/12/2020
1412
12.09
-0.06
12.03
22.9°
20000
#I
JM
5/13/2020
0000
12.47
-0.15
12.32
19.70
JM
5/13/2020
0200
12.45
-0.15
12.30
20.3°
#2
JM
5/14/2020
0000
12.35
-0.12
12.23
21.3°
20000
#2
SC
1 5/13/2020
1130
12.52
-0.09
12.43
22.2°
SC
5/13/2020
1330
12.46
-0.06
12.40
22.8°
#1
SC
5/14/2020
1230
12.32
-0.06
12.26
23.3°
20000
#I
Qs
5/15/2020
01301
12.35
-0.151
12.20
22.0°
QS
5/15/20201
0335
12.31
-0.09
12.22
22.1°
#1
SC
5/15/2020
1320
12.27
-0.03
12.24
23.7°
20000
#2
RT
5/15/2020
1720
12.27
-0.06
12.21
23.9°
RT
5/15/2020
1920
12.23
-0.06
12.17
23.1°
#2
JM
5/16/2020
1725
11.89
0.00
11.89
25.1°
20000
#I
DR
5/16/2020
0730
12.31
-0.06
12.25
22.80
DR
5/16/2020
0930
12.27
-0.06
12.21
23.0°
#2
SC
5/17/2020
0730
12.11
-0.03
12.08
23.9°
20000
#2
SC
5/17/2020
1400
12.22
0.03
12.25
25.70
JM
5/17/2020
1600
12.21
0.03
12.24
25.6°
#2
SC
5/18/2020
1430
12.20
-0.03
12.17
24.3°
20000
#I
QS
5/18/2020
0420
12.37
-0.06
12.31
23.40
QS
5/18/2020
0620
12.35
-0.06
12.29
23.5°
#1
Qs
5/19/2020
0500
12.29
-0.09
12.20
22.3°
20000
#I
DR
5/23/2020
1200
12.36
-0.06
12.30
23.3°
DR
5/23/2020
1400
12.33
-0.03
12.30
23.8°
#2
DR
5/24/2020
1230
12.25
-0.03
12.22
24.2°
20000
#2
QS
5/24/2020
0205
12.28
-0.15
12.13
22.8°
QS
5/24/2020
0410
12.28
-0.061
12.22
23.0°
#2
Qs
5/25/2020
0235
12.24
-0.09
12.15
22.2°
20000
#2
1 Qs
1 5/27/20201
0340
12.35
-0.15
12.20
22.3°
QS
5/27/2020
0540
12.30
-0.091
12.21
22.4°
#2
1 Qs
1 5/28/2020
03451
12.15
-0.03
12.12
24.20
20000
#I
RT
5/27/2020
21001
12.04
-0.03
12.01
24.0°
QS
5/27/20201
23101
11.99
-0.03
11.96
24.1°
#2
1 RT
1 5/28/20201
24001
11.651
0.00
11.65
25.70
20000
#2
JM
5/28/2020
2340
12.29
-0.03
12.26
24.0°
JM
5/29/2020
0145
12.26
-0.03
12.23
24.3°
7f2
1M
5/29/2020
2340
12.18
0.00
12.18
25.3°
20000
7f1
RT
1
5/29/2020
2100
12.02
-0.03
11.99
24.1°
JM
5/29/2020
2300
12.00
0.00
12.00
24.5°
#2
RT
5/30/2020
2100
11.731
0.00
11.73
25.6°
20000
#2
QS
1 5/31/2020
2451
12.31
-0.03
12.28
24.1°
QS
5/31/20201
5451
12.29
-0.03
12.26
24.3°
#2
1 Qs
1 6/1/20201
03451
12.28
-0.09
12.19
21.4°
20000
Sheet Total
(Gallons):
460000

Alternative 2 PSRP
Class B Biosolids
Dates: June 2020
City of Elizabeth City W Wf P
Monitoring Sheet for Lime Stabilization
Oakton pH 2700 - SN 2407052 NPDES Permit p NC0025011
Cole Partner Electrode pH Probe - SN 59001-34 Residuals Permit p WQ0002883
Oakton Temperature Probe - SN 35613-13 40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
NPDES Permit p NC0025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
PH(su)
Correction
Factor
pH(su)
after
Correction
>_ 12.20
Temp(°c)
Analyst
Date
Time
PH(su)
Correction
Factor
pH(su)
after
Correction
>_ 12.00
Temp(°c)r#1
Analyst
Date
Time
PH(su)
Correction
Factor
pH(su)
after
Correction
>_ 11.50
Temp(°c)
Stabilization
Amount
(Gallons)
p2
1M
6/2/2020
2200
12.28
-0.03
12.25
23.6°
QS
6/3/2020
0000
12.34
-0.03
12.31
23.6°
QS
6/3/2020
2300
12.22
0.00
12.22
25.30
20000
#1
CIS
6/5/2020
0005
12.27
0.00
12.27
25.60
QS
6/5/2020
0215
12.29
0.00
12.29
25.50
1M
6/6/2020
0005
12.15
(+)0.06
12.21
26.90
20000
p2
RT
6/5/2020
1500
12.24
(+)0.03
12.27
26.40
RT
6/5/2020
1700
12.18
(+)0.03
12.21
26.40
RT
6/6/2020
1500
11.73
(+)0.09
11.82
28.00
20000
#1
DR
6/9/2020
10001
12.22
0.001
12.22
25.60
DR
6/9/20201
1200
12.21
(+)0.03
12.24
26.00
#1
DR
6/10/2020
10001
12.13
(+)0.061
12.19
27.30
20000
p2
CIS
6/10/2020
0145
12.22
0.00
12.22
25.90
QS
6/10/2020
0345
12.22
0.00
12.22
25.50
p2
QS
6/11/2020
0215
11.93
(+)0.06
11.99
26.80
20000
#1
1M
6/11/2020
1030
12.29
(+)0.03
12.32
26.00
JM
6/11/2020
1230
12.24
(+)0.03
12.27
26.30
#1
1M
6/12/2020
1030
12.25
(+)0.06
12.31
26.80
20000
p2
CIS
6/12/2020
0005
12.26
(+)0.03
12.29
26.00
QS
6/12/2020
0225
12.24
0.00
12.24
25.90
#1
CIS
6/12/2020
2345
12.01
(+)0.06
12.07
26.60
20000
#1
QS
6/13/2020
0055
12.34
-0.03
12.31
24.70
QS
6/13/2020
0255
12.33
-0.03
12.30
24.60
#1
1M
6/14/2020
0055
12.16
(+)0.03
12.19
26.00
20000
p2
RT
6/13/2020
1800
12.36
-0.06
12.30
23.00
RT
6/13/2020
2000
12.31
-0.09
12.22
22.70
p2
RT
6/14/2020
1800
11.61
0.00
11.61
25.10
20000
#1
SC
6/15/2020
0330
12.35
-0.03
12.32
23.50
SC
6/15/2020
0530
12.33
-0.03
12.30
23.60
p2
QS
6/16/2020
0330
12.24
-0.06
12.18
23.90
20000
p2
RT
6/15/2020
1500
12.24
-0.06
12.18
23.70
RT
6/15/2020
1700
12.36
-0.06
12.30
23.90
p2
RT
6/16/2020
1600
12.13
-0.06
12.04
22.70
20000
#1
DR
6/17/2020
1400
12.28
0.00
12.28
25.30
1M
6/17/2020
1600
12.27
0.00
12.27
25.40
p2
1M
6/18/2020
1540
12.19
(+)0.06
12.25
26.60
20000
p2
QS
6/18/2020
0650
12.35
0.00
12.35
25.60
1M
6/18/2020
1540
12.24
(+)0.03
12.27
25.90
p2
CIS
6/19/2020
0650
12.20
0.00
12.20
25.90
20000
p2
RT
6/24/2020
1800
12.39
(+)0.03
12.42
26.70
RT
6/24/2020
2000
12.37
(+)0.03
12.40
26.30
#1
1M
6/25/2020
1800
12.27
(+)0.09
12.60
28.10
20000
#1
RT
6/27/2020
1930
12.05
(+)0.12
12.17
29.80
RT
6/27/2020
2130
12.06
(+)0.12
12.18
29.70
#1
RT
6/28/2020
1930
11.95
(+)0.15
12.10
30.8°
20006
p2
RT
6/28/2020
1700
12.16
(+)0.09
12.25
28.40
RT
6/28/2020
1900
12.05
(+)0.09
12.14
28.00
#1
RT
6/29/2020
1700
11.73
(+)0.12
11.85
29.8°
20000
#1
1M
6/30/2020
0200
12.34
(+)0.06
12.40
27.00
1M
6/30/2020
0400
12.31
(+)0.06
12.37
27.40
#1
1M
7/1/2020
0200
12.16
(+)0.12
12.28
29.0°1
20000
p2
RT
6/30/2020
1530
12.09
(+)0.09
12.18
28.40
RT
6/30/2020
1730
12.30
(+)0.06
12.36
27.90
#1
RT
7/1/2020
1530
12.08
(+)0.09
12.17
28.50
20000
Sheet Total (Gallons):
360000

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number: NCO025011
Monitoring Period: 07/01/2020 to 09/30/2020
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry 0 0 Continuous Grab Samples
Weight)
Analytical Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Andrew Edwards, Chief Operator
Preparer Name and Title (type or print)
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
2/11 /2021
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Thursday, February 11, 2021

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Parmer Electrode pH Probe - SN 59001-34
Dates: July 2020 Oakton Temperature Probe - SN 35613-13
NPDES Permit p NC0025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit # NC0025011
Residuals Permit# WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.00)
Temp (°c)
Shipped
to SST
#Ior2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#1
QS
7/2/2020
0130
12.18
(+)0.03
12.21
26.8°
QS
7/2/2020
0330
12.10
(+)0.06
12.16
27.90
#2
QS
7/3/2020
0140
12.01
(+)0.12
12.13
29.10
20000
#2
QS
7/3/2020
0400
12.39
(+)0.06
12.45
27.30
QS
7/3/2020
0600
12.28
(+)0.06
12.34
27.20
#1
SC
7/4/2020
0400
12.29
(+)0.12
12.41
29.00
20000
#1
DR
7/7/2020
1130
12.27
(+)0.12
12.39
29.20
DR
7/7/2020
1330
12.26
(+)0.15
12.41
30.00
#1
DR
7/8/2020
1130
12.20
(+)0.12
12.32
29.20
20000
#2
JM
7/8/2020
02301
12.09
(+)0.121
12.21
28.70
JM
7/8/20201
0430
12.00
(+)0.12
12.12
28.70
#1
JM
7/9/2020
0230
11.57
(+)0.15
11.72
29.60
20000
#1
DR
7/9/2020
1100
12.07
(+)0.12
12.19
28.50
DR
7/9/2020
1300
12.06
(+)0.12
12.18
28.70
#1
DR
7/10/2020
1245
12.00
(+)0.12
12.12
29.40
20000
#2
DR
7/10/2020
1300
12.35
(+)0.12
12.47
29.4°
DR
7/10/2020
1500
12.32
(+)0.12
12.44
29.50
#1
DR
7/11/2020
1300
12.28
(+)0.12
12.40
29.30
20000
#2
SC
7/13/2020
1350
12.13
(+)0.21
12.34
31.8°
RT
7/13/2020
1651
12.43
0.00
12.43
25.30
#1
SC
7/14/2020
1355
12.41
(+)0.03
12.44
25.80
20000
#1
SC
7/14/2020
0900
12.63
0.00
12.63
25.0°
SC
7/14/2020
1115
12.61
0.00
12.61
25.10
#1
DR
7/15/2020
1200
12.29
(+)0.06
12.35
26.70
20000
#1
DR
7/17/2020
1145
12.68
(+)0.03
12.71
25.50
DR
7/17/2020
1345
12.28
(+)0.06
12.34
26.50
#1
DR
7/18/2020
1300
12.06
(+)0.06
12.12
27.20
20000
#2
RT
7/17/2020
2130
12.31
(+)0.03
12.34
26.10
QS
7/17/2020
2330
12.23
(+)0.06
12.29
26.30
#2
QS
7/18/2020
2150
11.92
(+)0.06
11.98
26.90
20000
#1
DE
1 7/22/2020
0852
12.17
(+)0.06
12.23
27.10
DE
7/22/2020
1052
12.121
(+)0.06
12.18
26.90
#1
1 DR
7/23/20201
0852
12.08
0.00
12.08
25.20
20000
#2
QS
7/23/2020
0045
12.16
(+)0.06
12.22
27.60
QS
7/23/2020
0245
12.11
(+)0.06
12.17
26.70
#1LDR
7/24/2020
0050
12.02
(+)0.09
12.11
28.30
20000
#1
JM
7/25/2020
0400
12.25
(+)0.06
12.31
26.50
JM
7/25/2020
0400
12.27
-0.03
12.24
24.30
1
7/26/2020
0715
12.09
0.00
12.09
24.90
20000
#2
QS
7/25/2020
1955
12.00
0.00
12.00
25.00
QS
7/25/2020
2200
11.91
(+)0.06
11.97
26.40
#17/26/2020
2100
11.62
(+)0.06
11.68
26.8°
20000
#2
QS
7/28/2020
0645
12.13
0.00
12.13
25.8°
DR
7/28/2020
0845
12.05
(+)0.03
12.05
25.7°
#17/29/2020
0715
11.84
(+)0.06
11.90
26.7°
20000
#1
QS
7/29/2020
0240
12.15
0.00
12.15
25.8°
QS
7/29/2020
0450
12.12
(+)0.03
12.12
26.2°
#17/30/2020
0545
12.02
(+)0.03
12.05
26.4°
20000
Sheet Total (Gallons):
320000

City of Elizabeth City W WTP City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization Monitoring Sheet for Li me Stabilization
Alternative 2 PSRP Oakton PH 2700- SN 2407052 NPDES Permit 11 NC0025011 NPDES Permit 11 NC0025011
Class B Biosolids Cole Parmer Electrode PH Probe - SN 59001-34 Residuals Permit 11 WQ0002883 Residuals Permit Jt WQ0002883
Dates: Aueust 2020 Oakton Temperature Probe - SN 35613-13 40 CFR Part 503 Subpart D 503.30-503.33 40 CFR Part 503 Suhoart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
PH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.20)
Temp (°c)
Analyst
Date
Time
PH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.00)
Temp (°c)
Shipped
to SST
Jtlor2
Analyst
Date
Time
PH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#1
RT
8/1/2020
1853
12.28
(+)0.03
12.31
26.4°
RT
8/1/2020
2053
12.11
(+)0.06
12.17
27.0°
#1
RT
8/2/2020
1900
12.16
(+)0.06
12.22
27.6°
20000
#2
JM
8/2/2020
0230
12.21
(+)0.03
12.24
25.9°
Jim
8/2/2020
0430
12.18
(+)0.03
12.21
25.9°
#1
QS
8/3/2020
2000
11.17
(+)0.06
11.23
26.6°
20000
#2
DE
8/5/2020
1116
12.26
(+)0.03
12.29
26.4°
DE
8/5/2020
1318
12.16
(+)0.09
12.25
27.8°
#1
DE
8/6/2020
1128
12.05
(+)0.06
12.11
27.1°
20000
#1
1 JM
8/5/2020
22001
12.67
(+)0.031
12.70
25.6°
QS
8/5/2020
00101
12.13
(+)0.031
12.16
25.5'1
#1
1 RT
8/6/2020
2200
11.92
(+)0.06
11.98
27.1°
20000
#1
SC
8/11/2020
1130
12.18
(+)0.06
12.24
27.0'1
SC
1 8/11/2020
1330
12.16
(+)0.06
12.22
27.0°
#2
SC
8/12/20201
1400
12.12
(+)0.06
12.18
27.3°
20000
#2
QS
8/12/2020
0210
12.13
(+)0.03
12.16
26.4°
QS
8/12/2020
0410
12.11
(+)0.03
12.14
26.3°
#1
QS
8/13/2020
0215
11.97
(+)0.06
12.03
27.0°
20000
#1
SC
8/13/2020
1130
12.20
(+)0.06
12.26
27.1°
SC
8/13/2020
1430
12.16
(+)0.03
12.19
26.2°
#1
JM
8/14/2020
1130
12.02
(+)0.06
12.08
27.4°
20000
#2
QS
8/14/2020
0110
12.22
(+)0.03
12.25
25.8°
QS
8/14/2020
0310
12.23
(+)0.03
12.26
26.2°
#1
QS
8/15/2020
0110
12.17
(+)0.03
12.20
25.3
20000
#1
QS
8/16/2020
0405
12.21
(+)0.03
12.24
25.7°
QS
8/16/2020
0605
12.22
0.00
12.22
25.4°
#1
JM
8/17/2020
0405
12.14
(+)0.03
12.17
25.9°
20000
#2
SC
8/17/2020
0820
12.41
0.00
12.41
24.9°
SC
8/17/2020
1120
12.38
(+)0.03
12.41
26.3°
#1
SC
8/18/2020
1030
12.18
(+)0.09
12.27
27.5°
20000
#1
DE
8/18/2020
1914
12.08
(+)0.06
12.14
26.7°
DE
8/18/2020
2119
12.14
0.00
12.14
25.3°
#1
DE
8/19/2020
1914
12.05
(+)0.06
12.11
26.9°
20000
#2
QS
8/19/2020
0230
12.14
0.00
12.14
25.0°
QS
8/19/2020
0430
12.30
0.00
12.30
25.1°
#1
1 QS
8/20/2020
0600
12.20
(+)0.03
12.23
25 8'1
20000
#2
SC
8/26/2020
0930
12.32
(+)0.06
12.38
26.7°
SC
8/26/2020
1130
12.24
(+)0.06
12.30
27.3°
ttl
SC
8/26/2020
1330
12.23
(+)0.06
12.29
27.3°
20000
ttl
(IS
8/26/2020
2330
12.26
(+)0.06
12.32
26.5°
QS
8/27/2020
0135
12.31
(+)0.03
12.34
26.2°
Jtl
QS
8/28/2020
0100
1206.
(+)0.03
12.09
26.1°
20000
ttl
DE
8/31/2020
0816
12.24
(+)0.03
12.27
25.6°
DE
8/31/2020
1037
12.16
(+)0.03
12.19
26.3°
#1
SC
9/1/2020
0930
12.12
(+)0.03
12.15
25.7°
20000
Sheet Total
(Gallons):
300000

City of Elizabeth City WWTP City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oakton pH 2700 -SN 2407052 NPDES Permit # NC0025011 NPDES Permit # NC0025011
Class B Biosolids Cole Farmer Electrode pH Probe - SN 59001-34 Residuals Permit # WQ0002883 Residuals Permit # WQ0002883
Dates: September 2020 Oakton Temoerature Probe - SN 35613-13 40 CFR Part 503 Suboart D 503.30-503.33 40 CFR Part 503 Suboart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 12.00)
Temp (°c)
Shipped
to SST
#1or2
Analyst
Date
Tirne
pH (su)
Correction
Factor
pH (su)
after
Correction
(>_ 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#2
QS
9/1/2020
0125
12.16
0.00
12.16
25.4°
QS
9/1/2020
0325
12.13
0.00
12.13
25.1°
#1
Jim
9/2/2020
0130
11.88
(+)0.06
11.94
26.9°
20000
#2
DE
9/9/2020
0957
12.39
(+)0.03
12.42
26.1°
SC
9/9/2020
1200
12.67
(+)0.06
12.73
26.70
#1
SC
9/10/2020
1130
12.67
0.00
12.67
25.1°
20006
#1
JM
9/11/2020
0145
12.73
0.00
12.73
25.40
Jim
9/11/2020
0345
12.72
(+)0.03
12.75
25.70
#1
SC
9/12/2020
1430
12.67
(+)0.06
12.73
27.1°
20000
#2
SC
9/11/2020
1409
12.80
(+)0.03
12.83
26.40
RT
9/11/2020
1608
12.53
0.00
12.53
28.00
#1
CIS
9/14/20201
0530
12.52
-0.03
12.49
24.3°
20000
#2
Jim
9/15/2020
1130
12.75
0.00
12.75
25.3°
1M
9/15/2020
1330
12.74
0.00
12.74
21.4°
#1
JM
9/16/2020
1130
12.68
0.00
12.68
25.3°
20000
#1
QS
9/16/2020
0320
12.70
0.00
12.70
24.6°
QS
9/16/2020
0530
12.72
-0.03
12.69
24.3°
#1
QS
9/17/2020
0340
12.63
0.00
12.63
25.3°
20000
#1
1M
9/23/2020
0800
12.54
-0.06
12.48
22.70
1M
9/23/2020
1000
12.53
-0.06
12.47
23.20
#1
1M
9/24/2020
0800
12.46
-0.03
12.43
23.8°
20006
#2
RT
9/23/2020
1600
12.38
-0.06
12.32
23.90
RT
9/23/2020
1800
12.38
-0.03
12.35
24.90
#1
RT
9/24/2020
1600
12.19
-0.03
12.06
24.3°
20000
Sheet Total
(Gallons):
160000

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number: NCO025011
Monitoring Period: 10/01/2020 to 12/31/2020
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stabllization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry 0 0 Continuous Grab Samples
Weight)
Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Andrew Edwards, Chief Operator
Preparer Name and Title (type or print)
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
2/11 /2021
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Thursday, February 11, 2021

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP Oa kton pH 2700 - SN 2407052
Class B Biosolids Cole Parmer Electrode pH Probe - SN 59001-34
Dates: October 2020 Oakton Temperature Probe - SN 35613-13
NPDES Permit# NC0025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
NPDES Permit# NC0025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(212.00)
Temp (°c)
Shipped
to SST
#1or2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(2 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#1
RT
10/1/2020
1900
12.00
(+)0.03
12.03
26.7°
RT
10/1/2020
2100
12.14
-0.03
12.11
24.70
#1
RT
10/2/2020
1900
11.84
-0.09
11.75
22.00
20000
#2
AE
10/2/2020
0810
12.41
-0.06
12.35
22.80
1M
10/2/2020
1030
12.41
-0.03
12.38
24.30
#1
SC
10/3/2020
1030
12.42
-0.06
12.36
22.70
20000
#1
QS
10/3/20201
0255
12.65
-0.06
12.59
23.00
QS
10/3/2020
0500
12.53
-0.09
12.44
22.30
#1
JM
10/4/2020
0300
12.49
-0.03
12.46
23.70
20000
#2
JM
10/4/2020
05451
12.64
-0.09
12.55
22.4°
SC
10/4/2020
07451
12.67
-0.12
12.55
21.00
#1
QS
10/5/2020
0600
12.55
-0.09
12.46
22.00
20000
#1
QS
10/5/2020
0030
12.47
-0.06
12.41
22.80
QS
10/5/2020
0300
12.50
-0.09
12.41
21.90
#1
QS
10/6/2020
0030
12.39
-0.06
12.33
22.80
20000
#2
RT
10/6/2020
1800
12.47
-0.06
12.41
23.70
RT
10/6/2020
2000
12.48
-0.06
12.42
23.10
#1
JM
10/7/2020
1800
12.24
0.00
12.24
25.20
20000
#1
JM
10/7/2020
1900
12.36
-0.03
12.33
24.40
1M
10/7/2020
2100
12.35
-0.03
12.32
24.20
#1
JM
10/8/2020
1900
12.27
0.00
12.27
24.90
20000
#1
JM
10/10/2020
0830
12.21
-0.03
12.18
23.80
1M
10/10/2020
1035
12.08
-0.03
12.05
24.20
#1
SC
10/11/2020
1130
11.84
-0.03
11.81
24.10
20000
#2
AE
10/12/2020
1400
12.22
-0.03
12.19
24.10
AE
10/12/2020
1634
12.14
0.00
12.14
25.30
#1
SC
10/13/2020
1400
12.17
0.00
12.17
25.30
20000
#1
SC
10/13/2020
1400
12.20
-0.03
12.17
23.50
RT
10/14/2020
1600
12.25
-0.06
12.19
23.10
#1
SC
10/15/20201
1400
12.15
0.00
12.15
25.10
20000
#2
1 JM
10/15/20201
2200
12.29
-0.031
12.261
24.00
QS
10/16/2020
0000
12.23
-0.06
12.17
23.20
#1
1M
10/16/2020
2200
12.33
-0.09
12.22
22.20
20000
#1
JM
10/16/2020
1800
12.34
-0.06
12.28
23.4°
JM
10/16/2020
2000
12.30
-0.06
RT
10/17/2020
1800
12.24
-0.03
12.21
23.9°
20000
#1
AE
10/27/2020
1249
12.19
-0.03
12.16
23.6°
AE
10/27/2020
1449
12.17
-0.03
L122,...24La#,#1
AE
10/28/2020
1249
11.96
0.0011.96
24.9°
20000
#2
QS
10/28/2020
0200
12.23
-0.09
12.14
22.3°
QS
10/28/2020
0410
12.27
-0.06
#1
1 RT
1 10/29/20201
02001
12.11
-0.031
12.08
23.80
20000
Sheet Total
(Gallons):
280000

Alternative 2 PSRP
Class B Biosolids
Dates: November 2020
City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Cakton pH 2700- SN 2407052 NPDES Permit # NCO025011
Cole Farmer Electrode pH Probe - SN 59001-34 Residuals Permit # WQ0002883
Cakton Temperature Probe - SN 35613-13 40 CFR Part 503 Subpart D 503.30-503.33
City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(> 12.20)
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(> 12.00)
Temp (°c)
Shipped
to SST
#1or2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
(> 11.50)
Temp (°c)
Stabilization
Amount
(Gallons)
#2
AE
11/5/2020
1104
12.31
-0.09
12.22
22.30
AE
11/5/2020
1348
12.38
-0.06
12.32
23.2°
71
AE
11/6/2020
1125
12.47
-0.061
12.41
23.1°
2000
#1
AE
11/6/2020
0917
12.35
-0.06
12.29
23.2°
AE
11/6/2020
1128
12.44
-0.06
12.38
23.3°
#1
AE
11/7/2020
1201
12.25
-0.03
12.22
23.90
20000
#2
1M
11/9/2020
0000
12.42
-0.09
12.33
22.4°
QS
11/9/2020
0200
12.25
-0.09
12.16
22.2°
#1
CIS
11/10/2020
0000
12.17
-0.06
12.11
22.70
20000
#1
AE
11/9/2020
1040
12.35
-0.06
12.29
23.1°
AE
11/9/2020
1413
12.26
-0.03
12.23
24.0°
#1
1M
11/10/2020
1100
12.28
0.00
12.28
25.00
2000
Sheet Total
(Gallons):
80000

City of Elizabeth City W WTP City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization Monitoring Sheet for Li me Stabilization
Alternative 2 PSRP Oakton PH 2700- SN 2407052 NPDES Permit# NC0025011 NPDES Permit# NC0025011
Class B Biosolids Cole Parmer Electrode PH Probe - SN 59001-34 Residuals Permit# WQ0002883 Residuals Permit # WQ0002883
Dates: December 2020 Oakton Temperature Probe - SN 35613-13 40 CFR Part 503 Subpart D 503.30-503.33 40 CFR Part 503 Subpart D 503.30-503.33
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
-
-------
-------
-
-------
-
Sheet Total
(Gallons):

City of Elizabeth City
2020 Class B Annual Report
WQ Permit# WQ0002883
Soil Samples

Page 1 of 1
Report No: 20-364-0731
Account No: 04596
Advisor: Soil Plus, LLC
Joyce Barrette
P.O. Box 1396
Oxford NC 27565
Waypoint"'o
ANALYTICAL
Client: Granville Farms Inc
2850 Daisy Lane, Wilson, NC 27896
Main 252-206-1721 ° Fax [phone]
www.waypointanalytical.com
Farm: L. Larabee
Date Received: 12/29/2020
Date of Report: 12/30/2020
Lab No Field ID
Sample ID
Soil Class HM% W/V pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-1
CEC BS%
Ca%
Mg%
ESP
Na
121305
33
MIN
2.4
6.0
1.5
98
23
40
63
55
0
140
140
50
6.1
75
59
12
2.1
0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.5
N
160
P205
0
K2
93
S
0
Mn
0
Zn
0
Cu
0
B
0
Mg
0
Last Crop
21306
34
MIN
1.0
6.2
1.6
98
25
31
63
52
0
145
145
55
6.6
76
60
12
1.6
0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.0
N
160
P205
0
K2
89
S
0
Mn
0
Zn
0
Cu
0
B
0
Mg
0
Last Crop
21308
35
MIN
1.1
6.2
1.6
111
26
35
81
62
0
185
185
65
7.0
78
62
12
2.4
0.2
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.0
N
160
P205
0
K2
86
S
0
Mn
0
Zn
0
Cu
0
B
0
Mg
0
Last Crop
21309
36
MIN
1.2
6.1
1.6
98
26
37
63
53
0
135
135
65
6.3
75
57
13
2.6
0.2
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.5
N
160
P205
0
K2
86
S
0
Mn
0
Zn
0
Cu
0
B
0
Mg
0
Last Crop
21310
37
MIN
1.1
6.2
1.6
108
27
25
50
44
0
145
145
65
6.5
76
60
13
1.5
0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.0
N
160
P205
0
K20
84
S
0
Mn
0
Zn
0
Cu
0
B
0
Mg
0
Last Crop
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Carolina, Inc.