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HomeMy WebLinkAboutWQ0014248_Residual Annual Report 2020_20210225Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* Annual Report Year* Permit Number (IR)* Applicant/Permittee Email Notifications ........................................................................................................................................................................ Does this need review by the hydrogeologist?* Regional Office CO Reviewer Admin Reviewer * Annual Report * Residual Annual Report r Additional Information r Other 2020 WQ0014248 Town of Cheraw r Yes c No Submittal Form Project Contact Information Rease provide information on the person to be contacted by N B Staff regarding electibnittal, confirmation of receipt, other .......................................................... electronic surece, aner correspondence. _ - Name * Sherry Turner Email Address* stolson@cheraw.com Project Information ........ ......... .......................................................................................................................................... Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 8435378440 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 IT Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0014248 Fbs Current Existing perm number Applicant/Permittee Address * 1 Roddy Street PO Box 219 Cheraw, SC 29520 Facility Name * Town of Cheraw DCAR Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form} Engineering Rans, Specifications, Calculations, Bc.) Town of Cheraw Biosolids 2020.pdf 2.8MB Upload only 1 RFdocurrent (less than 250 fv8). Miltiple documents rust be combined into one RJFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/25/2021 Town of Cheraw Public Utility Department February 23, 2021 Me. Sonia Gregory NCDENR/DWQ/1Vater Quality Section Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Dear Ms. Gregory: Enclosed is the annual Biosolids marketing and distribution report. Please contact me if you have any questions or comments_ Sincerely, Sherry Turner Town of Cheraw Post Office Box 219 1 Cheraw, South Carolina 29520 i 843-537-8440 F: 843-537-8442 1 www.cheraw.com rx"11 %Jt%Ju 1..tlir1, AArr1A%-A I WIN LER 1 iHUATION FORM Permit#: WQ0014248 County: Chesterfield Year: 2020 Facility Name (as shown on permit): Town of Cheraw - Land Land Application Operator: Phone:__ Land application of residual solids as allowed by the permit occurred during the past calender year? ® Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A: Total number of application fields in permit: Total number of fields land application occurred during the year:-2 Total amount of dry tons applied during the year for all application sites: 51 Total number of acres land application occurred during the year. $0 Part B: Facility was compliant during calendar year _ 2020 with all conditions of the land application permit (including but not Iimited to items 1.12 below) issued by the Division of Water Quality. ® Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. I. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and time was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed in accordance with the crop management plan. 11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 12. All buffer requirements as specified on the permit were maintained during each application of residuals. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sherry Turner/Operator-of-Record 2 L3 Z Permittee Name and Title (type or print) Signa a of Permittee ate Signature of Preparer* Date Signiture of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) " Preparer is defined in 40 CFR Part 503.9 (r) Author Daryl D. Merritt DENR FORM ACF (7/2002) ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM PERMIT #: WQ0014248 FACILITY NAME: Town of Cheraw PHONE: (843) 537-8440 COUNTY: Chesterfield OPERATOR: FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) ® Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? ® Yes ❑No No If No skip parts A, B, C and certify form below Part A*: Par Sources(s) (include NPDES # if Volume (dry tons) Recipient I Month AdmendmenU applicable) Residual In Product Out Name(s) Vol Bulking Agent January Vernon Dye 38 February No Residuals Vernon Dye 12 March produced during 2020, April but distribution of May residuals from 2018 June took lace July October Novemb Annual (dry tons nt(s) u u 51 t B*: nformation ume (dry tons) Intended use(s) .4 deer plots .8 deer plots .2 * If more space than given is required, please attach additional information sheet(s). ❑ Check box if additional sheets) are attached Part C: Facility was compliant during calendar year 2020 with all conditions of the permit (including but not limited to items 1-3 below) issued by the Division of Water Quality. ® Yes ❑ No If No, please provide a written description why the facility was not compliant. 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, trite, accurate and complete. I am aware that there are significant penalties for submitting false informatton, including the possibility of fines and imprisonment for knowing violations." -A " 2, iignat a of Permittee Date Signature of Preparer** Date (if different from Permittee) **Preparer is defined in 40 CFR Part 5039(r) Author Daryl D. Merritt DENR FORM DMSDF (7/2002) * If more space than given is required, please attach additional information sheet(s). ❑ Check box if additional sheets) are attached Part C: Facility was compliant during calendar year 2020 with all conditions of the permit (including but not limited to items 1-3 below) issued by the Division of Water Quality. ® Yes ❑ No If No, please provide a written description why the facility was not compliant. 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, trite, accurate and complete. I am aware that there are significant penalties for submitting false informatton, including the possibility of fines and imprisonment for knowing violations." -A " 2, iignat a of Permittee Date Signature of Preparer** Date (if different from Permittee) **Preparer is defined in 40 CFR Part 5039(r) Author Daryl D. Merritt DENR FORM DMSDF (7/2002) TOWN OF CHERAW WASTEWATER TREATMENT FACILITY BIOSOLIDS REPORT 2020 Month Press I-Irs. Dry Cake Solids Ton Tons Lime Used % Lime Total Dry Product Lime ±/Ton Produced Poly $/Ton Cake Lbs Poly/ Ton Cake Lbs Poly Used .JANUARY 230.0 79.21 4.87 2.09 165.0 FEBRUARY 221.0 66.25 6.81 2.91 192.5 MARCH 241.0 68.70 5.62 2.40 165.0 APRIL 211.0 40.88 9.45 4.04 165.0 MAY 201.0 2696 14.32 6.12 165.0 JUNE 260.0 35.85 10.76 4.60 165.0 JULY 252.0 52.59 13.17 5.75 302.5 AUGUST 238.0 60.25 13.58 5.93 357.5 SEPTEMBER 267.0 60.65 15.57 6.80 412.5 OCTOBER 291.0 37.02 11.91 5.20 192.5 NOVEMBER 229.0 33.76 18.66 8.15 275.0 DECEMBER 290.0 52.68 9.57 4.18 220.0 TOTAL 2931.0 614.80 134.29 58.16 2777.5 AVERAGE 244.3 51.23 11.19 4.85 231.5 MINIMUM 201.0 79.21 4.87 2.08 165.0 MAXIMUM 291.0 26.96 18.66 8.15 412.5 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0014248 Laboratory: 1) Davis & Brown Labs Facility Name: Town of Cheraw 2) Clemson University NPDES # or 3) WQ#: SC0020249 4) WWTP Name: Town of Cheraw WWTP 5) Residual Analysis Data Sample or Composite Date 1 /15/20 1 1 /15/20 3/18/20 3/18/20 5/20/20 5/20/20 7/15/20 7/15/20 Percent Solids 64.6 59.6 56.5 56.7 65.7 65.5 67.0 65.3 Arsenic 2.71 4.991 2.12 .995 Cadmium 4.493 .4.496 .989 .995 Chromium 47.2 40.4 56.0 53.0 ,.� Co er 27.8 22.7 31.5 38.1 Lead .493 t.496 989 -c.995 Mercury .055 -e-.020 .044 Mol bdenum 3.94 3.96 -3.95 .047 1.09 Nickel 16.5 12.4 19.8 18.8 Selenium 4.975 4.991 4.989 < .995 Zinc 222.96 205 233 234 .� TKN 7239 27281 6473 6769 monia-Nitro e 0 0 0 306.3 rNitrateand Nitrite 458 318 30 41 tal Phosphorus 9621 11911 2748 9617 9/16/20 63.7 9/16/2011/24/2 58.3 1/24/20 71.1 3.00 3.74 <.994 47.4 30.2 1.13 t.172 <3.97 17.6 '.994 201 c.960 7845 222.9 82 13280 58.1 41.8 2.02 .141 <3-.84 22.8 <.960 292 7909 140.6 232 1107 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signatur of Preparer Date Author Daryl D. Merrill DENR FORM RSSF (7/2002) Vernon Dye / Pegues Cir 34 ° 47' 38"N 60 acres '850 �- -� ° ' " 795516W ^ 34.7 dmt '� 7. i ✓/~ F 2S6Y f! I n ` _ LZZ -- (;— • / r � ~ /��( ✓, Q /rJ _ _lam tit .• �,``1, '\�`{ -'r � � � r _ _ - � _- � / 1 _ C r� "`• .� �_� r f 73947 l \\�\ \ r �\i' --\` ��.J n��, •%rr, 1 `� (1 �_ _ . ` CAI j 1�1 r\ ,� ` J, -- yx = i_ =�ri �hJ`,,�•`"% 640000 FEET 3646000m N. l�7?4� 55' 2330000 FEET (S.C.) .J 34p45' p !1 6g20a0rE, CHERAW 6 mt y 79 52'3Q �,LE ROAD CLASSIFICATION .0 Primary highway, Light -duty road, hard or hard surface improved surfacec'F� Secondary highway, hard surface Unimproved road v Interstate Roue '77 U S. Route State Route rl C 9UAGRA ISLE LOCATiO4 M ORVEN E SST, N.C.—S.C. N 445--W7952.5/7.5 1971 xF�l_ 5053 IV SW —SERIES V842 ANNUAL METALS 141ELll LUADINCi bUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Town of Cheraw Total Dry Tons Applied (Annual): 38.4 W00020248 Cation Exchange Capacity (non 503 only): _ Vernon Dye 60 Acres Permitted: Owner: Site #: Pegues Cir Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent #): REM Total Phos- phorus�EWEEEEEEEEEE Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total Phos- �_phorus.EMEEEEEEEEEEE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations" Signature of Land Applier Author DaNi D. Merritt Date DENR FORM MFLSF (7/2002) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "NIA" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WWQ0014248 Annual Dry Tons Applied:' 38.4 Owner: Operator: _ Vernon Dye Cation Exchange Capacity (non 503): Site #: Pegues Circle Field #: Acres Utilized: 60 Acres Permitted: Specify Totals n Solids Dry Residual Site Cond. Inches Appli- Voli- Miner- Ammo Ni- Gat . CuNd. Q Per As Tons Sources Dry, Preci p cation tila- ala- TKN nia- trate- Report Totals Acre Deci- Per (Summarize) Wets Past 24 Meth- zation zation Ni- Ni- Gal. Acre Hrs. rs. od** Rate* Rate trogen trogen 11 Moist Jan N/A N/A1 .646 1 0.64 1 1 1 S 1 0.5 1 1 7239 0 458 PAN I I PAN 2 Must Select Crop 1 or Crop 2 Crop I I Crop 2 TOTALS: As Cd Cr I Cu Pb Hg I Mo Ni Se I Zn P PAN I PAN 2 Lime A lied Annuallbs/acre .0054 .0010 .0935 .0551 .0010 .0001 .0078 .0327 .0019 .4418 20.66 Date Ibs/ac Current Cumulative lbs/acre .0054 .0010 .0935 .0551 .0010 .0001 .0078 .0327 .0019 .4418 Prior Years Cumulative lbs/acre . 0 Permitted C. P. L. R.*** ?ermit PAN Limit lst/2r `I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system lesigned to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �C' ►� _ . Application Method: 5 -Surface, IN -Injection, INC -Incorporation ier Date **Volitilization Rate: Surface - 0.5, Injection/Incorpora(ion -1.0 Signature of Land Appl ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merrilt DENR FORM FSF (7/2002) ANNUAL METALS HELD WAVINU SUMMARY kORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Town of Cheraw Total Dry Tons Applied (Annual): 12.8 wnnm A 2AA _ Cation Exchange Capacity (non 503 only): Vernon Dye 20 Acres Permitted: Owner: Vernon Dye Site #: Dye Hoare Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent #): Total Phos- phorusEENEENNEEMEN Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total Phos- "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, includin the possibility of fines and imprisonment for knowing violations" Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL LAND APPLICATION FIE LD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. Facility Name: Town of Cheraw Owner: Vernon Dye Site #: Dye Horne Field #: PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Permit #: WQ0014248 Annual Dry Tons Applied;' 12.8 Operator: Vernon Dye _ _ _ Cation Exchange Capacity (non 503): Acres Utilized: 20 Acres Permitted: Specify Totals Per Acre ° Solids As Deci- mal Dry Tans Acre Residual Sources (Summarize) Site e Cond. Dry, Wet, Moist Inches Precip. Hrs. Appli- cation od** Voli- [ila- Rate* Miner- ala- Rate TKN Ammo nia- trogen Ni- trate- trogen PAN i PAN 2 Must Select Crop 1 Cro p or P 2 Gal. Cu.Yd. Totals in Gal. Crop 1 Crop 2 Feb N/A N/A .646 0.64 S 0.5 7239 0 458 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P I PAN 1 PAN 2 LimeA.3plied Annual lbs/acre .0054 .0010 .0935 .0551 .0010 .0001 1.0078 .0327 .0019 .4418 120.66 1 1Date lbs/ac Current Cumulative lbs/acre .0151 .0040 .2463' .1880 .0154 .0062 :0199 .1073 .0049 11.184 .0097 .0030 .1528 .1329 1.0144 .0001 .0121 1.0746 1 .0030 .7424 Prior Years Cumulative lbs/acre Permitted C. P. L. R.*** Permit PAN Limit lst/2nd Crop `I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system Designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier Date **Volitilizalion Rate: Surface - 0.5, Injection/Incorporation -1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DFNR FORM FSF (7/2002) d 1 Imo^ t Yfelsan tirava un \ T 1 . 1' 1 \ ^� �f` -�,_- �tf?'� �( `� �?�'eavtslch _'�� 1�: � ♦ —�== .'� � -- ✓ � Ji� J r acc�2.%' OZ Vernon Dye- y 0 U Dye Home 34050' 10"N 20 acres — 79°49' 21 "W 11.6 dmt ` _ r •l;' - Fla a.:.� f.;F: _.� ..1.- -- - s - V o�.�a,;„''�� - .s�Stnh.� # ��- ►ate �_`' _ �aa� �. -� t ti -' ao 0 TH CAIOLFti.'A - - '--=,- CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: January 15, 2020 Biosolids Maximum Maximum Maximum Maximum Metal Allowable Allowable Application Application Content, Metal App. Rate, Rate, Rate, METALS ppm Content, ppm #lAerelNr OT1Acre/Yr WT+AcreNr Arsenic, Total 2.81 41.00 1.80 190.59 319.73 Cadmium, Total 0.51 39.00 1.70 989,47 1659.90 Chromium, Total 49.03 1200.00 134.00 814.63 1366.60 Copper, Total 28.88 1500.00 67.00 691.56 1160.14 Lead, Total 0.51 300.00 13.00 7566.51 12693.36 Mercury, Total 0.06 17.00 0.75 3912.89 6564.15 Molybdenum, Total 4.09 ' 18.00 0.80 58,26 97.74 Nickel, Total 17.14 420.00 1 B.70 32520 545,55 Selenium, Total 1.01 36.00 4.50 132436 2221.71 PCB BRL 1,60 'Actual metal content less than amount indicated 890501ids Bicsolids Maximum Maximum Nutrient Nutrient Crop1S61 Application Application Content, Content, Requirement, Rate. Rate. ppm .a #/Acre -- DT-AcrelYr WT:Acre/Yr. Ammonium Nitrogen 0.00 0.00 Organic Nitrogen 4315.00 0.43 Incorporated Available Nitrogen 3025.00 0.30 120.00 11.82 1983 Surface Available Nitrogen 3025.00 0.30 120.00 11.82 19.83 Phosphorus as P205 5735.00 0.57 80.00 416 6.97 Potassium as K20 645.00 0.06 50.00 23.10 38.76 Calcium, Total 176260.00 17.63 Calcium as CaO 246792.00 24.68 Calcium as CaCO3 (CCE) 2915 0o 0.29 2000.00 204.49 343.05 Magnesium, Total 1910,00 0.19 Manganese 70.00 0.01 Sodium 205.00 0.02 Percent Moisture 40.39 "These are typical values and must be adjusted based upon specific site conditions OT Is Dry Tons of Biosolids. WT is Wet Tons of Btosolids. CERTIFICATION; This biosolid product has been produced by the Town of Cherav/s Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide) The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 4C. CFR Part 503 for a 'Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE; This biosolid is intneded to be used as a sod amendment The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop groom and site sal characteristics The user should contact the Clemson Extension Service (843.623.2134) andlor the Soil Conservation Service (843.623.2187) for assistance In determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular N475 tilled 'Ume and Fertilizer Recommendations.' THIS PRODUCT IS H GHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN, AVOID CONTACT W;TH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOL,D PRODUCT lily ,.ohm 0. Wwe, Public Utility Director P 0 Box 219; Cheraw, SC 29520 Telephone 843-537.8440 FAX: 843-537-8442 PRODUCT USER NAME. ADDRESS NTENDED USE: LMATZ-R-t1R U$k. OIIANT-TY R£CE VED- RECEIVED BY- Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 17-Jan-20 Client #: 168 Report Date: 31-Jan-20 Sample Date: 15-Jan-20 Approved By: SDG #: SDG-135273 Lab Sample ID: LSID-298265 Scott Fields Sample m: BIOSOLIDS 1-15-20-500 Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Acid Digestion (Solids) YES EPA 200.2 1/20/2020 10.45 JR Selenium, Total <0.975 0.975 mgfkg EPA 701016010 [122/2020 16:30 JR Percent Moisture 35.4 0.1 wt% S11-846 3540 1/20/2020 14:37 INiL Aluminum, Total 4960 19.7 mgAg SW846 6010D 1/29/2020 11:11 JR Arsenic, Total 2.71 0.975 mglkg SW846 601OD 1/22/2020 16:30 JR Cadmium, Total <0.493 0.493 mg/kg SW846 6010D 1/21/2020 12:15 AE Chromium, Total 47.2 0.493 mg/kg SW846 6010D 1/21/2020 12:I5 AE Copper, Total 27.8 0.493 mg/kg SW846 6010D 1/21/2020 12:15 AE Lead, Total c0.493 0.493 mg/kg SW846 6010D l/21/2020 12.15 AE Molybdenum, Total <3.94 3.94 mglkg SW846 6010D 1/20/2020 19:54 JR Nickel, Total 16.5 0.493 mg ft SW846 601OD 1/21/2020 12.15 AE Mercury, Total 0.055 0.02i mglkg SW846 7470A 1/22/2020 12:30 CG PCB BRL mg/kg SW8468082A S11A IY2812020 12:55 UH Page l ACass ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis &- Brovvn P.O. Box 1503E Quinby SC 29506 ATTENTION Scott Fields PROJECTID 298265 LABORATORY REPORT NUMBER ?001 K33 DATE January 29, 2020 Primary Data Review By Secondary Data Rev ievv B% Ashley Amick Chris Pafford Project Nlanager, Access Analytical Project Manager, AES aamick ci aes-inc.com PLEASE NOTE: - Unless olhervvise noted, all analysis on this report performed at Analytical Environmental Services Inc. ( \ES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDI IEC certified laboratory q 98t11(i, NCDENR certified lab 9562, G 1 certified [ab 9 F L-E875,92, AEI, AP certified laboratory 9 E87582 - AIII-%-LAP,LLC Laboratory I D:100671 for Industrial Ilygiene samples (Organics, Metals, PCN1 Isbestns, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental -Microbiology (Fungal) Direct Examination. Local support services for this project are pro%ided by Access Analytical. Inc. Access. lnalytical is a representative orAES serving client in the SC NC/GA areas. All questions regarding this report should ;)e directed to your local Access Analytical representative at 803.781.4243 or tall tee at 833.315.4243 Paqe 1 of 5 ® DAVIS & BROWN REGULATORY: YES NG 6 SMIR E ID I DATE 299)21,0(T tligk r.&�C- zL)-0- 4p,.) 124W.McIver Road PH: 842-865.6748 Florence, SC 29501 PAX., 842-866.2208 CHAIN OF CUSTODY RECORD SAMPLE ANALYSIS REGUE5'ED PAGE q -OF_ TURNAROUND 1141E ^pL STANDARD RUSH --�P2 USE COPES TO 1NCCrATE fF SAMPLE WAS CRPRESERVED A r HNC Prsearvel"L IFILTERED 8-HCL D -Nsc, FoFLLTRATION C•NACH E+NA,S60, 0-2INCACETATE 289GAAM ARFA: D. DRINKING WATER o :GROUNDWATER Q�GROUNDWATSR 9=SOLID SL•SLUDGE U.C) U. W O-OTHER O ,a PLEASE B Y ,L o Q. o SHADED AREAS FOR LAB USE ONLY a NOTES LAB ID J I ( I Flli In the Number aiContelnen for EACH T431 sr k L --rEL.- FLOW INFO I I !CE No PACK REOEB'7 TEMP: c R¢ingagnad A' Ualr: Tlma: Ra4rqu•et� C� Rndvad by e 171e Date: T!mo: Rscalvad Lr, Cuy Tina: P?,ye2f5 Y' Analytical Environmental Services, Inc Date: 29-Jan-20 Client: Davis & Bromm Client Sample 11): 298263 Project Name: 298263 Collection Date: 1/1312020 9:40:00 A41 Lab ID: 2001K38-001 Matrix: Solid Analvses Result Reporting Qual Limit L nits BatchlD Dilution Factor DateAnalyxed Analyst POLl'CiILORI,NiATED BIPIIE\I'LS S%N8082A (SNN3550C) Aroclor 101b BRL 53 tqhu•drn 291416 1 C-1 28,2010 1133 Uff Aroclor 1221 BRL 53 nghg-dn 291496 1 01 28,2020 12 55 Ull kroclor 1232 BRL 53 tle-' 4-dry 291486 1 01 29,2020 11 55 Ull Aroclor 1242 BRL 53 itetig-dr,, 291436 1 01'23i2020 12 55 Ull Aroclor 1243 BRL 53 oche -dry 291436 1 01,28)2020 12 55 Ulf Aroclor1254 BRL 33 ugl._�-thy 291456 1 0123r20201253 Ulf Aroclor 1260 BRL 53 uL-Kpiln 29143o 1 01 23i2020 12 55 Ulf Sum Decuchlorobipheny 1 35 3 43 7-141, 'dREC 291436 1 01 2312020 12 55 Ulf Sum Tetrachforo-m-xylenc 52 = 43 3-12h I.REC 291436 1 01 23,2020 12 55 Uli PERCEtNT,NIOISTL RE D2216 Percent Moisture 3'.y 9 w{'• Ra;n&.)3 I Of _x 20'_409:C0 lt4 QqA wtY Slue "ceeds:nirmum conummant IeLal BaL Bcluw rcperuag hmn If 11olden3 urre4 for prepay mn or ana!ysts areecded N ,IMIl to net %FL.kC cen:fed B knalyte detected in the associated mrthed bank I Greater than Result value E Esama:ed iva:ne above gwn1:Tauun nngcl S Spike Rxovm omstde im:ts Jue to matrix ti arr Sec au nwrit. c F Via, -cd ,n E.e ,h,.ahich -s i de•.ta»on Prom the n:cthcd Less than Resn!t va:ue 1 £sttmated .a.aaJewcred'elnw Reporting Gmn Pane 3 of 5 axurnc.%L E.Ex%j .r:1l .c. SAMPLE/COOLER RECEIPT CHECKLIST AF.S SFR57CER, I�iC. i. client Name: Access Analytical, Inc. 2. Carrier: FedExC UPS❑ USPSEll Client El Couder0 Othm AES Work Orde- Number, 20OIK38 Yee N. NIA ri—a. f Save as r —I. Shipping container/cooler received in good condition? • damaged `1 leaking t - other❑ Custody seals present an shipping container? • Custody seals intact on shipping container? • Temperature blanks present? • Cooler temperatute(s) within limits of 00V (See item 13 and 14 for temperature recordings.) O O O Cooling initiated for recently collected sampler / ic, present �'! Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? no Sampler name and/or signature on CCC7 • Were all samples received within holding time? • TAT marked on the CDC? • If no TAT radiated, proceeded wnh standard TATrTerms &Conditions. 13. Cooler 1 Temperature 1.4 •C 14, Cooler 5 Temperature •C 15, Comments: 16. 17 18 19. 20. 21. 22. 23, 24, 25. 26. Cooler 2 Temperature •C Cooler 3 Temperature aC Cao6r4 Temperature *' Cooler 6Temperature •C Cooler7Temperature eC Cooler 8 Temperature �C I certify that I have completed sections 1.15 (dated initials( NU 112' V.. fan NIA ..tail. [.cements Ware sample containers Intact upon mocipt? • Custody teals present on sample containers? • Custody teals intact on sample containers? 0- Dosample container labels match the COC? O O 0 in,ompete nfo ❑ illegible = no.abel ❑ other ❑ Are analyses requested indicated an the CDC? • all of the samples listed on the CDC received? O O O samp les received but not listed on COC ElWere samples 5sted an CDC not received ❑ Was the sample collection dateltime noted? • Did we receive sufficient sample volume for Indicated analyses? • Were samples received in appropriate containers? • Were VCA samples received without headspace jc 114' bubble;? Were trip blanks submitted? • listed on CDC I not „sted a, C:,C 27 Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated Initials). OR 1/23/20 checked at Sample Receipt. Yes No N/A Details Comments 28 Have containers reading chemica; preservation been checked? • • 29. Ccntainers meet presemat.en guidetnes? we 30 1was pH adjusted at Sample Receipt? + • Note: Cahn analyaea require chemical pinaNaaarl but must be checked in the laboratory and not upon Sample Receipt such as Coklomw, VOCs and CW & GreaaaRPH I certify that I have completed sections 2S-30 (dated initials). OR 1/23/20 Checklist 6.9.17 Rev 2 Locher! Page 4 of 5 End of Report Paae 5 of 5 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S South Carolina Lab Certification Number: 23101 S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 A cultural Service Laboratory Clemson University S7 South Carolina Lab Certification Number: 36001 S8 Lab sam les were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 10 South Carolina Lab Certification Number: 84009 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016 Note: S 11 A indicates AES Laboratory; S 11 G indicates GCAL Laboratory S12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S15 S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S25 Sample was analyzed by Microsee s, Inc Laboratory S26 North Carolina Lab Certification Number: 21 Wilson Division NC00120 S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 Revision 05113 Dalaqual (SubLabs) _wpd DAVIS & BROWN r21 W. McWcrRo,-ld PH, 843-665.8746 PAGE # % OF Porence.uC 296ar FAX. 343-08.2209 2�3 RECUL?CRY: vo CHAIN OF CUSTODY RECORD '[VAHA D rg'I . — pl _ �ApI A:SH p3 CL1E4T: f 1 C4-14tt:..f S.sGpL3 A:rALYS�G RCS': ES c. K C L'SE CCCc3-G ?�rIC i.7 T_ r"N'fFf.3 !!Av F!i3Qe. CR?PEie-•gibs-- AsHNCs 9aHCL 0+rli50i Fa FILTRATION C a NACH E- NAS;Ci G a ZINCACSTATE �resarmh+a I I C V rn C� Z � Z a J = y� dOCRESS: PO iRGJt Zt riL -!:iPAti+aPEa; D. DRINIONGYYAscR G a GRDUMT WATER S a SOLID SL. SLUM' W • WASTEWATER O.CTNER PLEASE PPINT LEGIBLY PHCHE; FAX: SAMPLE ID DA: — I TIME NCT°S - ' 'O 19+eSau fs zo Fill In theNLMberorCGrlamemfcr:.ACH -m I I I I I II I III 1 1 I I I I i T SAMPLER SIGNATURE � aa F! CSY+NFO iG'c E, NO PACK 34 eG RtlltlgsnahL'�1 Cate. Tme- Re'N etl t:Y 1- 7 C e. ra R=drguehed by' Calm tme: - Re by, Calm••2d r�o Tmc. I i a=crave: tY Oa'a Tsnc. Gor'smenh: ,J cei �...��,} .y SLfL�r1i „L ,..�l1�,Gm iwGJr�'[�II�TL �i.�r l�iS)MMiII ..+,l 7L i�b Nii/ww/ L.S.'CX1L�r L�-�c, .�iyba2GL4.«�r /YLGhii� /•�L.7LC.0 J A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 10071 Clemson University TURNER, SHERRY Po BOX 219 CHERAW SC 29520 ACCOUNT COMRLBR DATE 01/23/2020 STOLSON@CHERAW.COM SAMPLE NO. 01152050 MANURE; OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED ANALYST p7 pi p3 dw/sa dw/sa dw/sa dw/sa dw/sa BASIS---------------------- lbs/ton Ammonium Nitrogen 0.00 % 0.00 Organic Nitrogen 0.43 % 8.63 Nitrate Nitrogen 273.04 ppm 0.55 ---------------------------------------------------------------- INCORPORATED AVAILABLE NITROGEN ESTIMATE 6.05 SURFACE AVAILABLE NITROGEN ESTIMATE 6.05 --------------------------------------------------------------- Phosphorus as P2O5 0.57 % 11.47 Potassium as K2O 0.06 % 1.29 Calcium 17.63 % 352.56 Magnesium 0.19 % 3.82 Sulfur 0.13 % 2.62 Zinc 222.96 ppm 0.45 Copper 32.79 ppm 0.07 Manganese 69.15 ppm 0.14 Sodium 203.88 ppm 0.41 Moisturc 40.39 % Calcium Carbonate Equivalency 0.29 % 5.83 ------------------------------------------------------------------------------- INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and IM of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 40.39 59.61 1192.2 596100 % ppm lbs/ton % ppm lbs/ton as-sam led as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0 0 0 0 0 0 Organic Nitrogen 0.4315 4315 8.63 0.723872 7238.718 14.47744 Nitrate Nitrogen 0.027304 273.04 0.54608 0.045804 458.044 0,916088 Incorporated Available Nitrogen Estimate 0.3025 3025 6.05 0.507465 5074.652 10.1493 Surface Available Nitrogen Estimate 0.3025 3025 6.05 0.507465 5074.652 10.1493 Phosphorus as P205 0.5735 5735 11.47 0.962087 9620.869 19.24174 Potassium as K20 0.0645 645 1.29 0.108203 1082.033 2.164066 Calcium 17.628 176280 352.56 29.57222 295722.2 591.4444 Magnesium 0.191 1910 3.82 0.320416 3204.16 6.408321 Sulfur 0.131 1310 2.62 0,219762 2197,618 4,395236 Zinc 0.022296 222.96 0.44592 0.037403 374.0312 0,748062 Copper 0.003279 32.79 0.06558 0,005501 55.00755 0,110015 Manganese 0.006915 69.15 0.1383 0.0116 116.004 0.232008 Sodium 0.020388 203.88 0.40776 0.034202 342.0232 0.684046 Calcium Carbonate Equivalency 0.2915 2915 5.83 0.489012 4890.119 9.780238 January 2020 CHERAW ALKALINE BIOSOLIDS S01L AMENDMENT CHEMICAL CHARACTERISTFCS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: March 18, 2020 Biosolids Maximum Maximum Max mum Max mum Metal Allcwable Allowable Application Application Content, Metal App Rate, Rate Rate, METALS ppm Content, ppm #lAcreNr. DTlAcrelYr. WTrAcrelyr Arsenic Total 1.18 41 00 1 80 43336 76471 Cadmium Total 059 ' 3900 1 70 81774 144299 Chromium, Total 47.98 120000 134.00 791.36 1396.43 Copper. Total 26,96 150000 67.00 704,20 1242.64 Lead. Total 0-59 300.00 1300 625332 1103463 Mercury Total 0.02 - 1700 075 694706 15788.00 Molybdenum. Total 4,70 18.00 0.80 4820 85.05 Nickel Total 1473 420.00 1870 35981 63492 Selenium, Total 1.18 ' 36-00 450 108340 1911 77 Zinc, Total 24346 1525,00 12500 14548 256.72 PCB BRL 1.60 Actual metal content --ess than amount indicated Biosolids Nutrient Content, ppm Blosolids Nutrient Content. % CroplSoil Requirement, #/Acre " Maximum Application Rate DTlAcrelYr Maximum Application Rate WTIAcre/Yr Ammonium Nitrogen 0-00 000 Organic Nitrogen 15460.00 1 55 Incorporated Available Nitrogen 9565.00 096 12000 3.55 627 Surface Available Nitrogen 9565.00 096 12000 355 627 Phosphorus as P205 6750,00 068 8000 336 593 Potassium as K2O 1910,00 019 5000 742 1309 Calcium, Total 179975 00 1800 Calcium as CaO 251965 00 2520 Calcium as CaCO3 (CCE) 267500 0,27 200000 21 185 37383 Magnesium, Total 1870.00 019 Manganese 80.00 0,01 Sodium 1210.00 012 Percent Moisture 4333 These are typical values and must be adjusted based upon specific site conditions OT is Dry Tons of Biosolids WT s Wet Tons of Biosolids. CERTIFICATION This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual so ids using high temperature and lime (Calcium oxide) The Town of Cheraw certifies that th is biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above DIRECTIONS FOR USE This biosolid is inineded to be used as a so I amendment The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above The application rate for nitrogen. phosphorus, potassium and calcium is dependent upon the crop grown and site soil characteristics The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843.623.2187) for assistance in determining the proper application rate for each crap and site 'n no case shall the and application rate exceed the agronomic rate for the crop grown User should also refer to the Clemson Extension Service Circular #476 Oiled'Llme and Fertilizer Recommendations' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY AVOID PROLONGED CONTACT WITH THE SKIN AVOID CONTACT WITH THE EYES THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF TH S BIOSOLID PRODUCT ;1r. John D Stowe, Public UBSty Director P 0 Box 219; Cheraw SC 29520 Telephone 843-537-8440 FAX 843.537-8442 PRODUCT USER_ NAME. ADDRESS — -- INTENOED USE OC TI N 159—USE I�UANfITY REC�)1/E�— - - - R�C`E11/E� BY Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 19-Mar-20 Client #: 168 Report Date: 03-Apr-20 Sample Date: 18-Mar-20 SDG #: SDG-136278 Parameter Result LSID-300519 3-17-20-001INF Biochemical Oxygen Demand 296 Approved By: Scott Fields Lab Director Reporting Limit Unit Method Flag Date Time Analyst 2 mg/L SM 5210B LSID-300520 3-18-20-0011NF Biochemical Oxygen Demand 268 2 mg/L SM 52[OB LSID-300521 3-18-20-002 EFF Biochemical Oxygen Demand 10.7 2 mg/L SM 52108 319.2020 10:30 AE 3.19.2020 10:30 AE 3 : 19.2020 10:30 AE LSID-300522 3-18-20-0400 Acid Digestion (Solids) YES EPA 200.2 3/23/2020 9.30 AE Selenium, Total <0.991 0.991 mg/kg EPA 7010 r' 6010D 3/23/2020 11:08 JR Percent Moisture 43.5 0.1 wt%a SW846 3540 3/20/2020 15:34 141 Aluminum, Total 4600 19.8 mg/kg SW846 6010D 3/23/2020 10:30 JR Arsenic, Total <0.991 0.991 mg/kg SW846 6010D 3/24/2020 11:08 JR Cadmium, Total <0.496 0.496 mg/kg SW846 6010D 3/23/2020 16:45 AE Chromium, Total 40.4 0.496 mg/kg SW846 601OD 3/23/2020 16:45 AE Copper, Total 22.7 0.496 mg/kg SW846 6010D 3/23/2020 16:45 AC Lead, Total <0.496 0.496 mg/kg SW846 6010D 3/23/2020 16:45 AE Molybdenum, Total <3.96 3.96 mg/kg SW846 6010D 3/23/2020 10:30 JR Page I Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-I444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNTER Receipt Date: 19-Mar-20 Client #: 168 Report Date: 03-Apr-20 Sample Date: 18-I1ar-20 SDG #: SDG-136278 Approved By: :►• Scott Fields Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Nickel, Total 12.4 0 496 mgfkg SW846 6010D 3.23;2020 16:45 AE Zinc, Total 205 0.991 mgAg SW946 6010D 3,30;2020 11:55 AE Mercury, Total <0.020 0.02 m&Ig SW846 7470A 3:23:2020 12:45 CG PCB BRL mWIcg SW8468082A SIlA!D 3'20,2020 16:16 UH Page 2 AccEss ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 300522 LABORATORY REPORT NUMBER 20031,85 DATE March 24, 2020 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com - unless otherwise noted, all analysis on this report performed at Analytical Lnvironmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, Grp 30340. AES is SCDIIEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIIiA-LAP,LLC Laboratory IDA00671 ror Industrial Ilygiene samples (Organics, Metals, PC%I Asbestos, G ravi met ric), Environmental Lead (Paint, Soil, Dust 1N ipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical. Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll Fee at 883,315.4243 Page 1 of 5 Ai-l'PSS (AI-] �.0 lk- 7—'v—fir r 1 L. ;,G0 �L5' 3Cr R ® D A V I S & BROWN PAGE K OF Flaronaa, ac 501 APHI U3456.97aa aran e, z9sa� FAX.- aaa-ess•zzae � REOULtiTORY: YES .140 CHAIN OF CUSTODY RECORD ' PN"0CND nvF-. ST?4]AFJ R Srf PZ CL:E4i: SA.MFLE AYAL!S19 aECLES L;Ut C.^. 3TO NCIC7A-E 1'3MAPL ArA3 PtafmaCw I I i '-'=RW CRP.SEsERVt-:s7 A • HNC, -9 a HCL 0. P.S0f F x=:LTgATiCfi AQCttES9: v C -MACH E - N.l 3A O • tNtACE'iAT2 %9CGAAAl1PEA . 0 - ORMICNG'NAM C: G-QML4CWA..R S-SOL:II SL-SLJCOE 4 Q C " N a 71AS-UNATER C-OTHER PHCNS. FAX; PLIA29 MUT LEGIBLY W = SHADED AREAS FOR LA8 USE ONLY MA z_Z_ In CATE I rue XMAL I V07"cS L1 C Witpc, 1 � ! Ffl n the Number a! Csri 1rers 4t'cs3CH's�t cc G L_ ,� G l � I1 J I I IT I t � t --- I I I _2. 1 9A:.tFLEs"l SttiHATURE PLOW IN-0 10E YES No PACK RECEEFT TEMP-C R+Ar.S:ifn sae: ira: Ha a sY Oale-. oSr / (("w Rot"m Cr CaleTmw Fowr,G-m,aof ^irn..oc.kl-f\ Sec-iveq ry Cr0. rA_ q. C:rr..entr. :55i:E0: ACVH9ER701Y F�oiwf� Analytical Environmental Services, Inc Date: 24-Nlar--20 Client: Davis & Brown Client Sample ID: 300522 Project Name: 300522 Cnllectiun Date: 3/18/2020 10:40:00 AtIM Lab ID: 20031.85-001 Matrix: Solid Analyses Result Qual deporting Limit Units RalchlD Factortor Fa Date Analyzed Analyst POLYCHLORINATED DIPHENYLS SW8082A (SNN-3550C) Aroclor 1016 BRL 51 tigKg-dry 294300 1 03/20/2020 16 16 UH Aroclor 1221 BRL 51 ugKg-day 294300 1 03/20/2020 16 16 UH Aroclor 1232 BRL 51 kig Kg -dry 294300 1 03/20/2020 16 16 UH Aroclor 12.42 BRL 51 tigKg-dry 294300 1 03/20/2020 16 16 UH Aroclor 12.48 BRL 51 ligKg-dry 294300 1 03/20/2020 16 16 UH Aroclor 1254 BRL 51 ULL Kg -dry 294300 1 030-OJ2020 16 16 UH Aroclor 1260 BRL 51 ugKpdry 294300 1 03/2012020 16 16 UH Surr: Decachlorobiphenyl 636 45 7-140 °oREC 294300 1 03120l2020 1616 UH Surr: Tetrachloro-m-xylcne 71 4 45 3-126 IbREC 294300 1 03/20/2020 1616 U41 PERCENT MOISTURE D2216 Percent Moisture 35 -1 0 wt^a R321368 l 03I2312020 00 00 J W Qualifiers; Value exceeds maximum contaminant level BRL Below reporting limn II Holding limes for preparation or analystsexceeded N Analyte not NELAC certified B Analyze detected in the associated method blank > Greater than Result value E Esuntatedlvalueabove quanntationrange) S Spike Recovery outside limns due to matrix Siam See case narranle F Analyzed in the lab which is a deviation from the meihnd Less than Result value J Estimated value detected below Reporting Limit Page 3 of dES!1 �.ti.t'nc%. qX E\'VIACYNa11-VT.t1, SAMPLE/COOLER RECEIPT CHECKLIST +Sexwcts,t. C. 1. Client Name: Access Analytical, Inc. 2. Carrier. Fed Ex J trp$ J USPS::] C11ent::] Courier athel yes No N/A Details 3 4. 5. 6. 7. g. 9. lD. ll. 12 Clear AE5 WarkCrderNumber, 2003LOS Save as Shipping container; cooler received in good condition? damaged eak ng ' other' - Custody seals present on shipping container? Custody seals intact on shipping container? • Temperature blanks present? Cooler temperatures; within limits of GOO [See tern 13 and 1a tar temperature recordings., I O Cavling nit.ated'cr rexertiy capered samples / ice presentGain ofCustody ICCIQ present? Gain of Custody signed, dated, and timed when relinquished and received?Sampler name and/or signature an CDC? Were all samples eeceived within holding time? TAT marked an the COC7 IF no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Gaoler 1 Temperature 0 5 °C Cooler 2 Temperature sC Cooler 3 Temperature °C Cooler 4 Temperature °C 14, Cooler 5 Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature 'C Cooler ilTemperature °C 15. Comments: 16, 17, 16. 19, 20. 21. 22. 23. I4, 25. 26. I certify that I have completed sections 1-1S (dated Initials). gH 3/20120 Were sample containers Intact upon receipt? • Custody seals present an sample containers? • Custody teals intact on sample containers? • Do sample container labels match the CDC? O• O O incomplete info illegble _• no label other _ Are analyses requested Indicated on the CCIC? •Tr Were all of the samples listed on the CDC received? O O O samples received but not listed on CDC f] samples listed an CDC not received _ Was the sample collection date/time noted? • Did we receive sufficient sample volume far Indicated analyses? • Were samples received In appropriate containers? • I Were VOA samples received without headspace I� 1/4' bubbte►? Were trip blanks submitted? listed on CDC --I not listed an CDC vv 27. Commemw This section only applies to samples where pH can be I certify that I have completed sections 16.27 (dated initials). LM 3/20/10 waµa neceip4 Yes No N/A Details Comments Have containers needing chemical preservation been checked? • • Containers meet preservation guidelines? • Was all adjusted at Sample Receipt? • damyses ragu,re vtemseai presarvanan out must oe eneCited in me lacora:ory and not upon Sample Recopl such as Colllorms. VOCs and Oil a Gmase/TPH. I cenlly that I have completed sections 26.10 [dated Initlalsl. LA4 3/20120 Checklist 6.9.17 Rev 2 Locked Page 4d5 End of Report Page 5 of 5 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S South Carolina Lab Certification Number: 23 101 S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson Universi S7 South Carolina Lab Certification Number: 36001 S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 10 South Carolina Lab Certification Number: 84009 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016 Note: S 11 A indicates AES Laboratory; S 11 G indicates GCAL Laborato S 12 AASHTO RI Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S15 S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S25 Sample was analyzed by Microsee s, Inc Laboratory S26 North Carolina Lab Certification Number: 21(Wilson Division NCOOi20) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 Revision 45I13 Dalaqua1(Sub(.jbs) ,wpd DAVIS & BROWN R `SC 2lsc1 FAX. a s-ssas� PAGE # OF 13tp Z -i8 REGULATORY: YES ND CHAIN OF .CUSTODY RECORD TURNAROUND RUSH —_p2 CLIENT: • , O n 4w SAMPLE ANALYSIS REOURSTED aa' USE CODES TO INOICrATE rt SA14eLE WAS FILTEREDORPRESERVEO A•HMO, B.HCL D-". F. FILTRATION C•NAOH E+NA.S.O, G•HNCACETATE Preaenrathe L� It ty U ° W ADDRESS: PROGRAM AREA; D a ORINKWO WATER G.GROUNDWATER B■SOLID SL•StUDGE W.WASTEWATER O-OTMM PLEASE PRINT LEGIBLY PHDHE FAX: SAMPLE ID DATE TIME INITIAL NOTES LAB IO 3- -r•a -�o i 3-18 0-752 As Fill In the Number of Cwtalrembr EACH Tent vJ SOM T�nF wos2a • 9 -.-J sooszt 3-18-ao-o�a� •)LZ IcAo As C 1 ti Ls 300szz SAMPLER SIONATTIRE geld IgCsflriA, N MaiS$IL!!f 'K%� Se, AkA 3,Cd,Cr, CL., 4b,mo,h�i,Zn�rNS FLOWINPO ICE NO PACK npr YEW 5-7-o C R bK Data: Tyne: ' Rd. aU try Dale: Tlnw R6W4u ahN W: Daw: Time; R Dan: TYna: pT ale: Time Re""d aT Den: Time: amments: I9!uen: Nvvw m "12 A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 30468 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC 29520 ACCCUNT COCHSFL DATE 04/15/2020 STOLSON@CHERAW.COM SAMPLE NO. 03182050 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton pi Ammonium Nitrogen 0,00 % 0.00 pi Organic Nitrogen 1.55 30.92 pi Nitrate Nitrogen --------------------------------------------------------------- 180.20 ppm 0.36 INCORPORATED AVAILABLE NITROGEN ESTIMATE 19.13 SURFACE AVAILABLE --------------------------------------------------------------- NITROGEN ESTIMATE 19.13 dw/sa Phosphorus as P205 0.67 % 13.50 dw/sa Potassium as K20 0.19 % 3.82 dw/sa Calcium 18.30 % 359.95 dw/sa Magnesium 0.19 % 3.74 dw/sa Sulfur 0.16 % 3.17 Zinc 257.27 ppm 0.51 Copper 37.40 ppm 0.07 Manganese 78.77 ppm 0.16 Sodium 1208.14 ppm 2,42 Moisture 43.33 % Calcium Carbonate Equivalency 0.27 % 5.35 ------------------------------------------------------------------------------- INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application, Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, sail type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of moisture % solids lbs. solids/ton lbs. solids/500 tons 43.33 56.67 1133.4 566700 % ppm lbs/ton % ppm lbs/ton as-sam led as-sam led as-sam pled d ton dry ton dry Ammonium Nitrogen 0 0 0 0 0 0 Organic Nitrogen 1.546 15460 30.92 2.728075 27280.75 54.5615 Nitrate Nitrogen 0.018020 180.2 0.3604 0.031798 317.9813 0.635963 Incorporated Available Nitrogen Estimate 0.9565 9565 19.13 1.687842 16878.42 33.75684 Surface Available Nitrogen Estimate 0.9565 9565 19.13 1.687842 16878.42 33.75684 Phosphorus as P2O5 0.675 6750 13.5 1.191106 11911.06 23.82213 Potassium as K2O 0.191 1910 3.82 0.337039 3370.39 6.74078 Calcium 17.9975 179975 359.95 31.75843 317584.3 635.1685 Magnesium 0.187 1870 3.74 0.329981 3299.806 6.599612 Sulfur 0.1585 1585 3.17 0.279689 2796.894 5.593789 Zinc 0.025727 257.27 0.51454 0.045398 453.9792 0.907958 Copper 0.00374 37.4 0.0748 0.0066 65.99612 0.131992 Manganese 0.007877 78.77 0.15754 0.0139 138.9977 0.277995 Sodium 0.120814 1208.14 2.41628 0.213189 2131.886 4.263773 Calcium Carbonate Equivalency 0.2675 2675 5.35 0.472031 4720.311 9.440621 March 2020 CHERAW ALKALINE B OSOLICS SOIL AMEN-_MENT CHEM CAL CHARACTERISTICS AND LAND A--PLICAT'ON RATES BIOSOUDS SAMPLE DATE: May 20, 2020 METALS Biosolids Metal Content, ppm 6laximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate Rate ftlAcrerYr DT Acre,Yr Maximum Application Rate WT/AcreNr Arsenic, Total 2-17 41,00 1 80 27226 41567 Cadmium, Total 1.01 3900 1 70 551 20 B41 52 Chromium, Totai 57.19 1200,00 I J4 00 76731 1171 47 Capper Total 32-17 1506 00 6700 68205 1041 30 Lead Total 1.01 300.00 13.00 421504 6435 17 Mercury, Total 004 1700 075 546591 834491 Molybdenum. Total 4 03 ' la c0 0 60 6495 99 15 Nickel Total 2022 42000 1870 30285 462,37 Selenium. Total 1.01 36,00 450 1459 :5 2227 56 Zinc, Twat 237.96 152500 12500 172 03 262,64 PCB BRL 1,60 • Actual metal content -ess than amount indicated B1CSOWS Nutrient Content. ppm Biosclids Nutrient Content, %*Acre CrcprSoil Requirement, Maximum Application Rate OT AcrerYr Maximum Application Rate WT'AcrerYr Ammonium Nitrogen 000 000 Organic Nitrogen 424000 042 Incorporated Available Nitrogen 257500 026 12000 t5 26 2330 Surface Available Nitrogen 257500 025 12000 t5 26 2330 Phosphorus as P205 180000 0 18 8000 1456 22 22 Potassium as K20 71000 007 50 00 23 06 3521 Calcium, Total 4283500 429 Calcium as CaO 5996900 600 Calcium as CaCO3 (CCEI 313500 031 2000 CO 20893 318 98 Magnesium, Total 59000 006 Manganese 25 c0 000 Sodium 155.06 002 Percent Moisture 34 50 These are typical values and must be adjusted based upon specific site conditions DT s Dry Tons of B osolids 4VT is Wet Tons of B cso,ids CERTIFICATION This biosolid prsduct has teen produced by the Town of : heravls bVastewater Treatment Plant by a treatment process that pasteurized plant res.dual so (is using sigh temperaure and lime icalcium ox de'. The Tcvm of Cheraw certifies that INN bioselid complies w th the Environmental Protection Agency regulat.ons 40 CFR Pan 503 for a'Class A" product and has a meta. and nutrient content as presented above. DIRECTIONS FOR USE This biasel,d ,s inlneded to be used as a sod amendment The bicsclid land application rate shall not exceed the most restrictive tilax:mum Application Rate as indicated n the table above The application rate for nitrogen phosphorus potassium and calcium is dependent upon the crop grown and site so characteristics The user should contact the Clemson Extension Service (843-623-21341 and or the Soil Conservation Service (843-623.2187) for assistance m determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown User should also refer to the Clemson Exlens= Service Circular #476 titled "L me and Fertilizer Recommendations' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY AVOID PROLONGED CONTACT WITH THE SKIN- AVOID CONTACT WITH THE EYES THE TOWN OF CHERAW S NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF TH,S BIOSOLID PRODUCT hlr John D Stowe, Public Utility Director P 0 Box 219 Cheraw, SC 29520 Telephone. 843-537-8440 FAX. 843-537-8442 PRODUCT USER NAME INiEl1�E0LSE - LbCA IO�E — - QUANTitY RECE_VED RECEIVED BY - Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O. BOX 219 CHIERAW, SC 29320 Contact: SHERRY TURNER Receipt Date: 2 t-.May-20 Client #: 168 Report Date: 05-Jun-20 Sample Date: 21-11ay-20 SDG #: SDG-137213 A roved B PP Y ��a,, Scott Fields Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-302657 5-20-20-001IYF Biochemical Oxygen Demand 280 2 rn�L SNI 5210E C 321 2020 10:57 AE LSID-302658 5-20-20-002 EFF Biochemical Oxygen Demand 80,0 2 m_ L SN1 5210E C 5l2UNN 10:57 AE LSID-302659 5-20-20-0400 BIO Ignitability �180 0 Deg. F. D93 : 1010A SI IA 5/26/2020 0:00 SK TCLP Extraction (Solids) YES EPA 1311 S I I A Acid Digestion (Solids) YES EPA 200.2 5/25/2020 9:00 AE Selenium, Total <0,989 0.989 mz'kg EPA 7010. 6010D 3/26/2020 10:04 AE TCLP PASS Pf SW-846 SIIA 6/3/2020 10:33 WSF Percent Moisture 34.3 0.1 wt°-, SW846 3540 5/21/2020 15:37 NIL Aluminum, Total 5770 19.8 mgAg SW846 601OD 5/27/2020 1046 JR Arsenic, Total 2.12 0.989 mg,kg SW846 601OD 5/26/2020 10.04 AE Cadmium, Total <0989 0.989 mgkg SW846 601OD 5/25/2020 15:51 AE Chromium, Total 56.0 0.989 mg/kg SW846 601OD 925/2020 15:51 AE Copper, Total 31.5 0,989 mglkg SW846 601 OD 5/25/2020 13:51 AE Lead, Total -f0,989 0989 mg/kn SW846 601OD 5/25/2020 15:51 AE Molybdenum, Total <3.95 3.95 mgrkg SW846 6010D 5/27/2020 10:46 JR Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWS OF South Carolina Certification Number: 21117 P.O.BOX 2l9 CHERAW, SC 29520 Contact: SHERRY TMNER Receipt Date: 21-May-20 Client R: 168 Report Date: 05-Jun-20 Sample Date: 20-,1ay-20 �--. SDG #: SDG-137213 Approved By: Scott Fields Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Nickel, Total 19.3 0.999 mzkg SVV3.45 6010D 525 2020 15:51 AE Zinc, Total 233 0 939 me ka SWS46 6010D 5 23 2020 15:51 AE Mercury, Total 0.044 0.02 mzka SWS 46 7 470A 6.3 2020 11;45 CG PCB BRL ma k- SWS46 8092A S l lA 5 23.2020 23:16 UH Reactivity, Cyanide <0.971 0.971 mLt. k_ SWS46 9010 9012 S 1 lA 5 26.2020 13:15 BW Reactivity, Sulfide <100 100 m2 k1! SW346 9030, 903.4 S 1 l A 3 272020 13.33 BW LSID-302660 SOURCE WATER Total Organic Carbon 3.7 0.5 mg L S%l 53IOB-201 1 525 2020 3.25 AF LSID-302661 FINISHED `PATER Total Organic Carbon 2.6 0.5 mg L SM 531OB-201 l 525 2020 3:23 AE Page 2 ACCESS ANALYTICAL., INC. AINALYTICAL REPORT CLIENT Davis & Brown 124 W. titclver Road Florence SC 29501 ATTENTION Scott Fields PROJECT ID 302659 LABORATORY REPORT NUMBER 2005037 DATE June 02, 2020 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick,'a axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (,US Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDE`R certified lab # 562, GA certified lab # FL-E87582, N'ELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Org.tnics, Metals, PCNI Asbestos, Gmvimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC1`C, GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 ,at[,--tllciW-]AfJN ;0- 'sFual 'uaill :�It[t Afi Panlrla/F 'alq� I iW[ I Aq Panla:lail —. Aq p-nolcln1w;all 17rro f M1411l. :&IB(l r .Aq Flan Rim[. -Kqn MF Imil81fibipipF[ (Z g) 'nIMF ':Ills *1 FI lint 1d13038 AIa a3 — - -inn i V wm; )131c NOW ON S3A 331 Isal FIO1f3 .lol sJoulaluop to JogwnN oql uI 111d (11 fivi SALON .r' n m ' t I %-P o I n n rn DU uJ r'D U m 'IVIIINI 7wll. 31vo 11I 1 IcILNVS AWO 3Sn GV7 UOJ SV3UV 030VHS A7E1937J.N1gd3SV37d SS3L Zl11I10=0 !l31vM315vM=M 210an1S =1S MIUS = S lIH1V1UlONn021 J - 7 N31VM ONINNIHU = U 3lv133v3NIZ = o 10`S'VN = 3 IIOVN = 3 NORV8111A = 3 los'lI = Q 1011 = 9 'ONI1 = V G:?AH= ^3!!d 2VO 03U-71114 SVA4 37c1J'YV.+ 3131 V-i01ONt Ol 3300. 35n - n ��� UN eAIIUAJ EOJd o=11 ScInr)38 SISAIVNV -;? IdWVS -//�/0/1�p1 l� :3W11 QNftOlJVNl11?1 [it VVV OO /� ia77 /✓ 7 der fT7✓ `Q®`s no J0 p IWO ON s3A :Aao3.vinJ]a 9017,1999-cry -'xV1 l osrz os 'aall-oll p/► p� ;9 xi S p p V Jo # a9vd 91'L9-999-Ff y =1lcl PVOJ�nn1OL11 M 1:7.6 JIYY ®� "� a� i! / R V LW5W2 �r,IL 1-115 zo-Dv Analytical Environmental Services, Inc Dam 2-Jun-20 Client: Davis & Brow-n Project: 302659 Case Narrative Lab Ip: 2005037 Mercury Analysis by Method 7470A-1311: LCS-297777 recovery for mercury was outside control limits biased hi=h. Target analyte was not detected in the analytical samples and data is reportable with high bias. Analytical Environmental Services, Inc Date: 2-Jun-20 Client: Davis & Brown Client Sample ID: 302659 Project Name: 302659 Collection Date: 5 20.2020 11:58:00 AM Lab ID: 2005037-001 Matrix: Solid Analyses y Result Reporting Limit Qua1 Units Batchip Dilution Factor pate Analyzed Analyst N'OLATILES, TCLP SW1311/8260D (SW503013) 1,1-Dichlorocthene BRL 0.10 mg L 297-9 20 03 23,2020 la 26 IT 1,2-Dichloroethane BRL 0.10 mg L 2977-9 20 05 2812020 14 26 IT 2-Butanone BRL 0.20 mg L 29-779 20 05 23r2020 14.26 IT Benzene BRL 0.10 mg L 29'7-9 20 05 23,2020 1426 IT Carbon tetrachloride BRL 0.10 mg L 297779 20 05 2&2020 la 26 IT Chlorobenzene BRL 0.10 mg L 247-"9 220 05.23,2020 1426 IT Chloroform BRL 0 10 mg L 297779 20 03 23.2020 la 26 IT Tetrachloroethene BRL O.lfl mg L 297--9 20 05 28,2020 14.26 IT Trichloroethene BRL 0 l0 mg L 2917-9 20 05 23; 2020 14.26 IT Vinyl chloride BRL 0 040 tng L 29 --- 9 20 03 23, 2020 1426 IT Surr: 4-13romofluorobenzene 94.2 63 1.120 ',REC 29-7-9 20 05 23.202r 1426 IT Surr: Dibromofluoromethane 104 1?0 1.12t) ',REC 29'--9 20 03 23,202C 14-26 IT Surr: Toluene-dS 94.6 75 3-119 ',REC 29-7'9 20 05 2S.2020 1426 IT Sulfide, Reactive SNV846-7.3 (SNN7.3.4.2) Sulfide, Reactive BRL [CO r_g Kg 29763' 1 05 272020 13 35 HU, SENIIVOLATILES ORG.VNICS, UP SW131118270E (SW3310C1 1,4-Dichlorobettzene BRL 0.10 mg L 297462 1 03 27 2020 19 06 YH 2,4,5-Trichlorophenol BRL 0.10 mg L 297462 I 0527 2020 19.06 YH 2,4,6-Trichlorophenol BRL 0.10 mg L 297462 I 05 27 2020 t9 06 YH 2,4-Dinitrotoluene BRL 0.10 mgL 297462 1 05f27 2020 19.06 'I'll Hexachlorobenzene BRL 0.10 mg L 297462 1 05127 2020 19 06 21-11 Hexachlorobutadiene BRL 0.10 mg L 297462 1 0327 2020 19.015 YH Hexachloroethane BRL 0.10 mg L 297462 1 03r27 2020 19.0u Y`H m,p-Cresol BRL 0.10 mg L 297462 1 03127 2020 19:06 YH Nitrobenzene BRL 0.10 mg L 297462 1 03r272020 19:06 YH a -Cresol BRL 0.10 mg L 297462 1 05,27 2020 19:06 YH Pentachlorophenol BRL 0.50 mg L 297462 1 0327 2020 19.06 Y1l Pyridine BRL O't0 mg L 297462 1 0527 2020 19:06 YH Cresols, Total BRL 0.10 mg L 297462 t 05i27i2020 19.06 YH Surr:2,4,6-Tribromophenol 93.4 51.6-135 'AEC 297462 1 O3i27r202019.06 YH Surr: 2-Fluorobiphenyl 63.6 43.7-132 '.,REC 297462 1 03:27 2020 19.06 Y13 Stun: 2-Fluorophenol 69.8 42.1-124 '.aREC 297462 1 05.,27 2020 19.06 1['l3 Surr: 4-Terphenvl-d14 64 53.2-132 'AEC 297462 1 05;27 2020 19.06 YH Star: Nitrobenzene-0 79 30.7-130 'iREC 297462 1 05:27 2020 1906 Y11 Surr: Phenol-d5 63.8 43.6-121 ',REC 297462 I 03.27 2020 1906 YH POLYCHLORTNATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 53 UE,Kg-dry 297752 t 03�2312020 23:16 UH Aroclor 1221 BRL 53 ugKg-dry 297752 1 05128.202023.16 UH Aroclor 1232 BRL 33 ugkg-dry 297732 1 0512S12020 23 16 UH Aroclor 1242 BRL 33 ugKg-dry 297752 1 032Sr202023.16 UH Aroclor 1248 BRL 53 ugKg-dry 297752 1 05128,202023-16 Ull Aroclor 1234 BRL 53 ugKg-dr:' 297752 1 05129 202023.16 UH Qoatlnen: . Va.n::u-6 n:.1.C:Morn Ctlr::ff.^LlY^.t :[ :I } I-i ^ 1:C i 01.L: 1'I'S: yLi.';I 1::C f ra .) BRL Be:uw rgor-ng lim-1 5 Sgu: R:eov .- :u 'itr.:!s Su: to m.,'_.x H Hol"I ng t mo for pr ,arvi ott ar araiysis :ac::d:d tip. 5¢::asc rara:!se N Anj;yte art `ELAC cvnCad } ,L+a:yr:d to the ;aa ;s i I. t• m th.-.cL%cd a wlyic dctucied to the issnclat.d n:Cthcd Yank L_sa aun R:suA v:i,u: > Greater that ResO va:ue I F_.anated va:u. !e :et:d belo.v R.rar int[ Limit Analytical Environmental Services, Inc Date: 2-Jun-20 Client: Davis & Brown Client Sample ID: 302659 Project Name: 302659 Collection Date: 5-20/2020 11:58:00 A4I Lab 1D: 2005037-001 Matrix: Solid Reporting Dilution Analyses y Result Qual Units BatchID Date Analyzed Analyst Limit Factor POLYCHLORINATED BIPHENYLS SW8082A (SNV3550C) Aroclor 1260 BRL 53 ug Kg -dry 297732 1 05:28; 2020 23:16 U11 Surr: Decachlorobiphenyl 75.3 45.7-140 INREC 297752 1 05:28i2020 23:16 Ull Surr: Tetrachloro-m-xylene 80.5 43.3-126 ?6RE•C 297752 1 05.28.2020 23:16 UI-I MERCURY, TCLP SW1311/7470A (SW7470A) Mercury BRL 0.00400 mg L 297333 1 06.01.2020 20:26 AJ lgnitability / Flashpoint SW1010A Ignitabiiity 180 0 a 'F R42Q-73 1 05.26; 2020 00:00 SK ICP,NIETALS, TCLP SW1311/6010D (SNN'3010A) Arsenic BRL 0.250 Mgt 297639 1 05 272020 1724 KB Barium BRL 0.500 Mgt 297639 1 05.27 2020 1724 K.4 Cadmium BRL 0.0250 mg L 297639 1 05r27-2020 17:24 KB Chromium BRL 0.0500 mg L 297639 1 05:27 20210 17.24 KB Lead BRL 0.0500 mg L. 297639 1 05.27 2020 17.24 KB Selenium BRL 0.100 Mgt 297639 1 05-27202017:24 KB Silver BRL 0.0250 Mgt 297639 1 05 27 2020 1724 KB Cyanide, Reactive SW846-7.3 (SW7.3.3.2) Cyanide, Reactive BRL 0.971 mg Kg 2974,51 1 05.26;2020 13:15 BW PERCENT MOISTURE D2216 Percent 'Moisture 3" 3 f+ Wis.. R426240 1 05 26:2020 00 00 JW Qualilicn: Value exceeds maximum contammant level E Esuma:cd iva:ue above gcartiiai= range) BRL Below r-poning lirmt S Spike Recovery outside limits Sue to matrix H Holding times for preparation or analysts exceeded tiasr See casc narncvc Analyte not N'ELAC ccrliflcd F Analyzed .n the lab which is a deviation From the method B Analyic detected in the associated method blank < Less than Rcsult value > Grmicr than Result value J Estimated value detected below R.-porting Limit 301 A NA IXI'I LS11- E-NVIRONlttlO` I -All. AI- St_RVICls, INC. I. client Name; Access Analytical, Inc. Carrier: Ft. f rr_f UPS U USPSU Client{ CourierLj Other 3. 1. i. S. 1. 1. L. SAMPLE/COOLER RECEIPT CHECKLIST Yes No NIA notails AFS Work Order Number 2005037 Clear Save'aal r—me..t. Shipping container/cooler received In good condition? damaged L kr4king IL other{ j Custody seals present on shipping container? I • Custody seals intact on shipping container? • Temperature blanks present? + Cooler temperature(s) within limits of 00C? lSee item 13 and 14 for temperature recordings.) O Q Q Cooling iNtklled for recently collected samples / Ice present Chain of Cu study (COC) present? 0- Chain of Custudy signed, dated, and timed when relinquished and received? name and/or signature on COC?•Were I altsamples received within holding tune? TAT marked on the COC? +Sampler If no TAT indicated, proceeded with standard TAT per Ternis Le+ Conditions. 1011 t. Cooler 1 'Ternpe(ature 1.8 °C Cooler 2 Temperature 1, Couler 5-Temperature "C Cooler G Temperature i. Cenunents: °C Cooler 3'remperature 1 c Coulee 4 Temperature e'C "C Cooler 7 retnperatute IV Cooler li Teniperatute 1,C I certify that I have completed sections 1-15 (dated initials). t M W _/20 Yes No N/A Details rnmmentc Were sample r.untainers intact upon receipt? e Custody seals present on Sample containers' • F. Custody seals mtaCt un sample Containers' Do sarnpie f:nntainer labels rnarr:h tree COC? 0 O 0 ineamµlete inru I e Illrglilre ! I , no label ?ether ! Are analyses requested indicated on the COC? • Were ❑II rrl the saln pll'S listed On FIIe COC received?7 O © O samples receiver) but not listed on Cf1f; samples listed on COC not received Was the sainple Collection date/tinte Voted? + Did we receive sulticient sample volume for indicated analyses? Were samples received in appfopriaw containers? r Were VOA sanifites received without headspace (C 1/4" bubble)? r Were trip blanks submitted? • listed on COC I j k not Lsted on CUC Comments: This section only applies to samples where pH can be I certify that I have completed sections 16.27 (dated initials). I M 5/22/20 checked at Sample Receipt. Yes No N/A Details Comments Have Containers needing chemical preservation been checked? ' Containers meet preservation guidelines? • Was ptI adjusted dt Sample Receipt?0 -0 lo Nole: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms. VOCs and Oil & GreaselTPH 1 certify that I have completed sections 28-30 (dated initials). LM 5/22/20 hecklist v.9 ] 7 kry 7 Locked P-tm- r• of A Analytical Environmental Services, Inc Date: 2-Jun-20 Client: Davis & Brown Project Name: 302659 Dates Report Lab Order: 2005037 Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date 2005037-O01A 302659 5/2012020 11:58:00AM Solid VOLATILES, TCLP Leached 05127/2020 512812020 8:03:OOAM 05/28/2020 2005037-001B 302659 5120/2020 11:58:00AM Solid IGNITABILITY 05126/2020 2005037-001B 302659 5120/2020 11:58:OOAM Solid TCLP SEMIVOLATILES ORGANICS 0512612020 5/2712020 8:45:OOAM 05/27/2020 2005037-OOIB 302659 5/20/2020 11:58:OOAM Solid MERCURY, TCLP Leached 05126/2020 611/2020 2-54.00PM 06/01/2020 2005037-001 B 302659 5120/2020 11:58:OOAM Solid ICP METALS, TCLP Leached 05126/2020 512712020 12.57.00PM 05/27/2020 2005037-001 B 302659 5/2012020 11:58:OOAM Solid Cyanide, Reactive 5126/2020 7:50:OOAM 05126/2020 2005037-001B 302659 5/2012020 11:58:OOAM Solid Sulfide, Reactive 5127/2020 9.15.00AM 05/27/2020 2005037-001C 302659 5/20/2020 11:58:OOAM Solid POLYCHLORINATED BIPHENYLS 5128/2020 10:00:OOAM 05128/2020 2005037-001C 302659 5/20/2020 11'58'OOAM Solid PERCENT MOISTURE 05/26/2020 n �refs 7 !`f 11 End of Report DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S South Carolina Lab Certification Number: 23101 S1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratoa Clemson University S7 South Carolina Lab Certification Number: 36001 S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 10 South Carolina Lab Certification Number: 84009 Sl 1 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016 Note: S 11 A indicates AES Laborato ; S 11 G indicates GCAL Laboratory S12 AASHTO R18 Certified S13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S15�***** S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S25 Sample was analyzed by Microsee s, Inc Laboratory S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 South Carolina Lab Certification Number. 32571 S28 Revision 03 13 Dataquai {subLabs} _wpd DAVIS & BROWN "124 W. Alclvf~rRoad PH. S4.7-665-6746 Florence, SC 29501 rn.Y: 843-656-22011 REGULATORY: YE� NO CHAIN OF CUSTODY RECORD SAMPLE AMALYSIS IlrQUESTEU ^ �` +� (, u V Preservalivo ESS: U) t:t in z -E U FAX: " U a ;e SAMPLE ID DATE Trwr- [u ❑- 1:,1111,kcdl .: F l Gfr- D.� W57 F C - 1 1 bio -o4o o 1 G 4 Lo G R SIGNATURr hud by L[al[ C Iqn� Q V val ill Ills: M !"juber GI Conlaintets for LAUi l test FI.OtV 1PtF0 PAGE it OF Lj +2 ` i TORNANUUND r1A7E Pi STANDARD RIJS"l PZ USE CODES TO IAtDICTATF. 1F S.Ip.fPLE' 6VAS FILTERED OR PR£SFRVED A = HNO3 13 = HGL D = H.50a F m FILTRATION C = HAOH E NA,S,D, G = ZINCACC-TATE r'' OG17.4A1 R 'l ' D = DRINKMG WATER ,r G = GROUNDWATER S = SOLID SL _ SLUDGE W=17ASTELVATER 02OTlIC•R PLEASE PRINT LEGIBLY E^ O ROT1:S LAB ID 3024g-q 50 5 I untl• I{L'ha:'.jutylieCj hY Uwe- rIFF1. I�e.hN!�I '�Ily LJiIC T[me ,:r 'cn Ly ' ' _ i [nr Hecrurll II' IC[ VES NO PACK rtl� r. �-1Pr Tfr fly 5-d-- c Ih4 7/20/2020 Mips frpsaweb.clemson.edu/aglab/AgSvcLab/Lab ResultslCOCHSFLTURNER, SHERRY2006091338141.htm A N I M A L W A S T E A N A L Y S I S R E P O R T Agricultural Service Laboratory LAB No. 60615 Clemson University TURNER, SHERRY ACCOUNT COCHSFL PO BOX 219 DATE 06/09/2020 CHERAW SC 29520 STOLSON@CHERAW.COIN SAMPLE NO. 05202040 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton A Ammonium Nitrogen 0.00 % 0.00 A Organic Nitrogen 0.42 % 8.48 pi Nitrate Nitrogen --------------------------------------------------------------- 19.65 ppm 0.04 INCORPORATED AVAILABLE NITROGEN ESTIMATE 5.15 SURFACE AVAILABLE NITROGEN ESTIMATE 5.15 dw/sa --------------------------------------------------------------- Phosphorus as P205 0.18 % 3.60 dw/sa Potassium as K20 0.07 % 1.42 dw/sa Calcium 4.28 % 85.67 dw/sa Magnesium 0.06 % 1.18 dw/sa Sulfur 0.07 % 1.31 Zinc 67.46 ppm 0.13 Copper 18.99 ppm 0.04 Manganese 22.92 ppm 0.05 Sodium 155.23 Qom 0.31 Moisture 34.50 % Calcium Carbonate Equivalency 0.31 % 6.27 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - SH of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of acrLmonium-AI, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of application. The Agricultural Service Laboratory is a public service of Clemson University, an affirmative action and equal opportunity educational institution. xx http://www.clemson.edu/agsrvlb *S % moisture 34.5 % solids 65.5 lbs. solids/ton 1310 lbs. solids/500 tons 655000 °a ppm lbs/ton °o ppm lbs/ton Ammonium Nitrogen as -sampled as -sampled as -sampled dry ton dry ton d ry Organic Nitrogen 0 0.424 0 4240 0 8.48 0 0.647328 0 6473.282 0 12.94656 Nitrate Nitrogen 0.001965 19.65 0.0393 0.003000 30 0.06 Incorporated Available Nitrogen Estimate 0.2575 2575 5.15 0.39313 3931.298 7.862595 Surface Available Nitrogen Estimate 0.2575 2575 5.15 0.39313 3931.298 7.862595 Phosphorus as P205 Potassium as K20 0.18 1800 3.6 0.274809 2748.092 5.496183 Calcium 0.071 710 1.42 0.108397 1083.969 2.167939 Magnesium 4.2835 42835 85.67 6,539695 65396.95 130.7939 Sulfur 0.059 590 1.18 0.090076 900.7634 1.801527 Zinc 0.0655 655 1.31 0.1 1000 2 Copper 0.006746 67.46 0.13492 0.010299 102.9924 0.205985 Manganese 0.001899 18.99 0.03798 0,002899 28.99237 0.057985 Sodium 0,002292 22.92 0.04584 0.003499 34.99237 0.069985 Calcium Carbonate Equivalency 0,015523 155.23 0.31046 0.023699 236.9924 0.473985 0.3135 3135 6.27 0.478626 4786.26 9.572519 May 2020 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES SIOSOLIOS SAMPLE DATE. July 15, 2020 Biosolids Maximum Maximum Maximum Maximum Metal Allowable Allowable Application Application Content, Metal METALS App Rate, Rate, Rate ppm ppm ppm Content. ppm rtlAcre+Yr. DTrAcrerYr YF AcreeYr 33 329 Arsenic, Toter t.00 41.00 Cadmium, Total 1.90 58977 903 17 0,995 099648507 1.00 3900 Chromium, Total 5308 t200 00 1 70 13400 557 01 a24 26 85300 0,995 099648507 Copper, Total 38.16 1500 00 6700 57330 1262.21 97795 53 53 0791045 Lead. Total 1 M WO 00 13.00 425947 6522 93 381 38 1568657 Mercury Total 0 05 17 00 0.75 520234 7966 93 0.995 0 99fi48S07 Molybdenum Total 1,09 18.00 0.90 23928 36643 0.047 004707015 Nickel Total Ia.83 420.00 18 70 32425 49660 1.09 10gi62687 Selenium. Total Ito ' 3600 450 147443 225794 18.8 18 8280597 Zinc, Total 23435 152500 12500 174 15 26670 0.995 995 0 95648507 8507 PCB BRL 160 234 349254 ' Actual metal content Bess than amount indicated. Blosolids Bicsoltds Maximum t'laximum Nutrient Content, Nutnent Content, CroplSe:l Requirement Apptication Rate Applicaticn ppm 2 ppm @ ppm FFm % *Acre " OT AcrefYr Rate. 4YT AcrerYr % ibs Acin 34.70 moisture moisture 34 70 moisture Ammonium Nitrogen 200 c0 (102 Organic Nitrogen 422000 042 002 0.40 200 220 Incorporated Available Nitrogen 2735.00 0 27 120 CO 1433 21 94 0 2735 2735 Surface Available Nitrogen 267500 027 12 0 Otl 14 65 22 43 735 02735 5.47 5.47 2735 2735 Phosphorus as P205 629000 0.63 80 00 4 16 637 0.2675 5.35 2675 2675 Potassium as K20 94500 009 50 00 1729 2646 0.628 00945 12.56 6290 6280 Calcium. Total t 7 37EO 00 1738 1.89 945 945 Calcium as CaO 243264 00 24.33 t7 376 347.52 173760 173760 Calcium as CaCO3 (CCE) 302000 0.30 2000 00 21623 331 13 0 0 302 6.04 0 Q Magnesium. Total 163000 D 16 3020 3020 Manganese 70 00 0.01 0 163 3.28 1630 1630 Sodium 200 Q 03 0 C07 0,14 70 70 Percent moisture 3 470 0 027 0.54 270 270 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons or B oso ids. N!f Is Wet Tcns of Bicselids CERTIFICAT'ON: This biosoiid product has been produced by the Town Of Cheraw's Wastewaler Treatment Plant by a treatment process that pasteurized plant residual se;ids using high temperature and lime :cafcium oxide). The Town of Cheraw certifies that this biosolld complies rnth the Environmental Protect Agency regualions 40 CFR Part 503 for a'Class A" product and has a metal and nutrient content as presented above D RECTIONS FOR USE: This biosolid 's ntneded to be used as a soil amendment The bicsand and application rate shaA not exceed the mast restrictive Maximum App; cat -on Rate as ndicated n the table above The appl cation rate for nitrogen, phosphorus, potassium and calcium s dependent upon the crap grown and site sail characteristics, The user should contact the Clemson Extension Service :943-623.2134) andlor the Soil Conservation Service (843-623.2la7; for assistance n determining the proper application rate for each crap and site. In no case shall the and application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extens:cn Service Cfrcular 9476 titled "L-me and Fervizer Recommendations' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD eE HANDLED ACCOROINGtY AVOID PROLONGED CONTACT WITH THE SK-N. AVOID CONTACT VATH THE EYES THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING CF THiS BIOSOOO PRODUCT, Mr John 0. Slowe Public uh ly D:reclor P 0 Box 219 Cheraw SC 29520 Telephone_ 043-537.8440 FAX, B43-537-8442 PRODUCT USER NANAIE' ADD E - `--- - - - - - - - - IN1'E-Nff9D USE - - - -- - - GU -;C�;AT�10N OF U'� Davis & Brown PO Box 15038 Quinhy, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 16-Jul-20 Client #: 168 Report Date: 24-Jul-20 Sample Date: 16-Jul-20 SDG #: SDG-138148 Parameter Result LSID-304761 7-15-20-001 Biochemical Oxygen Demand 386 Approved By: Scott Fields Lab Director Reporting Limit Unit Method Flag Date Time Analyst 2 mglL SM 521OB LSID-304762 7-15-20-002 -- - Biochemical Oxygen Demand <2.6 2 mgiL SM 5210E LSID-304763 Acid Digestion (Solids) Selenium, Total Percent Moisture Aluminum, Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Molybdenum, Total Nickel, Total Zinc, Total Mercury, Total 7-15-20-0400 BIOSOLIDS YES EPA 200.2 <0.995 0.995 mg/kg EPA 7010 - 601 OD 33.0 0.1 w't°u SW8463340 5330 19.9 mglkg SW846 6010D <0.995 0995 mglkg SW846 6010D <0.995 0.995 mg/kg SW846 6010D 53.0 0.995 mg/kg SW846 601OD 38.1 0.995 mglkg SW846 6010D <0.995 0.995 mg/kg SW846 601OD 1.09 0.796 mglkg SW846 601OD 18.8 0.995 mg/kg SW846 601OD 234 0.995 mg -kg SW346 6010D 0.047 0.028 mg/kg SW846 7470A 716.2020 10:44 AE SDF 7. 16 2020 10:44 AE 7/20/2020 7122/2020 7/17/2020 7/20/2020 7/22/2020 7/20/2020 7/20/2020 7/20/2020 7/20/2020 7/20/2020 7/20/2020 7/20/2020 7/22/2020 9:00 AE 13:46 AE 15:25 ML 16:41 JR 13:46 JR 9:36 AE 9:36 AE 9:36 AE 9:36 AE 16:13 JR 9:36 AE 9:36 AE 12:30 CG Page l Davis & Brown PO Box 15438 Quinby, SC 29506 (843) 665-6746 F;%...X: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHER.kV , SC 29520 Contact: SHERRY" TURNER Receipt Date: 16-Jul-20 Client #: 168 Report Date: 24-Jul-20 Sample Date: 15-Jul-20 .1 SDG 9: SDG438148 approved Bti: Scott Fields Lab Director Reporting Parameter Result limit Lnit Method Flag Date Time analyst PCB BRL e a k SW846 8032:\ S 1 I A. D " 21 '0,?1 17.46 LIH Page ACCEss ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown 124 W. McIver Road Florence SC 29501 ATTENTION Scott Fields PROJECT ID 304763 LABORATORY REPORT NUMBER 2007109 DATE July 22, 2020 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamickct ass-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES Is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified Iaboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, i CM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC. VGGA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 DAVIS & BROWN 124 W. McIver Road PH: 843.6611-6746 PAGE it OF_ Florence, SC 29501 FAX: 843-656.2268 REGULATORY; YES NO CHAIN OF CUSTODY RECORD rulrntAROuTTIME:_Pt STANDARD RUSH P2 NT: (Uvx� SAMPLE ANALYSIS REOL1l b'I E D w p USE CODES 770 WDICIATE IF SAMPLE WAS FILTERED OR PRESERVED A = HNO, I3=HCL D-H=SO4 Fa FILTRATION C = NAOH E - NAAOy O n 21NCACETATE Preaarvetive in r U S3 r�L N lr C! 'G K LL a 1— (,{�i iESS- PROGRAMAREA: D- DRINKING WATER O a GROUNDWATER S-SOLID $L - SLUDGE W = WASTEWATER O=OTHER PLEASE PRINT LEGIBLY SHADRD AREAS FOR LAB USE ONLY 4E: FAY: SAMPLF ID DATE TIME NOTES LAB ID FIII In this Number of Contalnera far EACH Tast 5 LEH SIGsNA-I UItE: FLOW INFO ICE Yeg No PACK RECEIPT MUP: aC l�he 13ate, Time JCL It 7 f I (. (G "J Rolingwshdd Ly Dala: rtkna RdH,l+ru shod oy Unla: Time nC IV, Data- 1 lrnu LIL Rer.LIvEd Irk Dale' Trua Fta:-aivud by Dala Time. brdy: Pane 2 nt 5 Analytical Environmental Services, Inc Date: 22-Jul-20 Client: Davis & Brown Client Sample ID: 304763 Project Name: 304763 Collection Date: 7:15, 2020 9:28:00 AM Lab ID: 2007I09-001 Matrix: Solid Analyses Result Reporting Qual [snits BatchlD Dilution Date Analyzed Analyst Limit Factor POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BELL 48 ugdig-dry 300219 1 07'21 2020 17:06 UH Aroclor 1221 BRL 48 ug'Kg-dry 300219 1 07 21-2020 17:06 UII Aroclor 1232 BELL 48 ug�Kg-dry 300219 1 0721"2020 17:06 Ulf Aroclor 1242 BELL. 48 ugKg-dry 300219 1 07.21:2020 17:06 UH Aroclor 1248 BELL. 48 ug'Kg-dry 300219 1 07 21'2020 17:06 UH Aroclor 1.254 BELL 48 ug`Kg-dry 300219 1 07 21'2020 17:06 UH Aroclor 1260 BELL 48 ugKg-dry 300219 1 07 21'2020 17:06 UF1 Surr: Decachlorobiphenyl 51.9 45.7-140 "DREG 300219 1 07 21'2020 17:06 UH Surr: Tetrachloro-m-xylcne 71.8 45.3-126 'aREC 300219 I 07:21 2020 17:06 UH PERCENT MOISTURE D2216 Percent Moisture 30.5 0 wt', 1243045i> 1 07 20r2020 00:00 AV Quallllers: Value exceeds maximtun catraminam level BRL Below reporting omit H Holding times for preparation or analysis exceeded ti Awiyte not NELAC certified B Analyle detected in the associated method blank > Greaur thart Result value E Estimatcd (value above quantilation range) S Spike Rzcovery outside limits due to matrix Narr See cast nar'attve F analyzed in the lab wbirh is a deviation from the method < Less than Resu:t value J Estimated value detected below Reporting Limn fr ANALY11CAL 11���JJ JENVIRONMENJI-All. AES Sii1tVlCliS, INC. 1. Client Name: Access Analytical, Inc. 2. Cartier: FrdEx r UPS USPS U Client Courier_ Other 3. 4. 5. 6. 7. S. 9. -O. .1. .2. 3. Cooler 1 Temperature 2.1 °C Cooler 2 Temperature 4, Cooler 5 Temperature °C Cooler 6 Temperature 5. f Ornmcntw. G. 7. 8. 9. O. 1. 2. 3. 4, 5. 6. SAMPLE/COOLER RECEIPT CHECKLIST Yes No N/A AES Work Order Number: 2007109 Details Clear GAVe as Comments Shipping container/cooler received In good condition? • damaged i. ! leaking I ! otheti Custody seals present on shipping container? • Custody seals Intact on shipping container? ` Temperature blanks present? • Cooler temperature(s) within limits of O-EVC? ISee item 13 and 14 for temperature recordings.] Cooling initiated for recently collected samples / tee present 1 Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? + Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms & Conditions. Lj °C Cooler 3 Temperature °C Cooler 4 Temperature °C " C Cooler 7 Temperature °C Cooler 8 Temperature "C I certify that I have completed sections 1-15 (dated initials). LM 7/17/20 Yes No N/A Details Comments Were sample containers intact upon receipt? • Custody seals present on sample containers? • Custody seals intact on sample containers? • Do sample container labels match the CDC? Q © © incomplete info I illegible no label Other i Are analyses requested indicated on the COC? • Were ail of the samples listed on the COC received? © O samptes received but not listed on COT*ed? f ) samples fisted on CDC not received I Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? t Were trip blanks submitted? 0-• • listed on COC not listed on (.(X ! 1 7, Comments: This section only applies to samples where pH can be 1 certify that I have completed sections 16-27 (dated initials). LM 7/17/20 checked at Sample Receipt. Yes No N/A Details Comments Have containers needing chemical preservation been checked? • • Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? • Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Calilorms. VOCs and Oil & GreaselTPH. I certify that I have completed sections 28-30 (dated initials). LM 7/17/20 Checklist 6.9,17 Rev 2 Locked End of Report DAMS & BROW- Data Qualifiers Within the attached report, some analytical data may be r_portcd as Qualified Data is indicated by a data quad ier or a Flag next to the result This table summarizes the possible Data Qualifiers that may be associated with this report. A SOD result showed toxic (endencies. B The SOD data is suspect due to a failed qualu_r ccvrul check iGGAI- C The SOD data is suspect due to a failed quAty cr.ntr.d check i$'anks). D Results at: reported on a dry weight basis H Sample was analyzed beyond the accepted hu ding time 1 Estimated value Presence t: f the compound was confumed nut !css than the re.nrted detecacn lima L Results based on colony counts outside the ac=ptable ranee Tat ideal range fur Lhc fecal co:iforat t.st ii 20 -60 colonies SIS Sample matrix spike percent rccouerywas vuts.dc the acc: pud range. O Sampled, but analysis lost or not per. rmed P Sample was not properly preserved upon receipt. G LCS or NIS excecds the control limits. S Samp[c was analyzed by another 5C ccrtidcd Lab SC Sced Correction outside the accepted range of 0.50 - 1.4 mg L. (BOD) Seed Correction outside the acecptcd range of 0.60 - 1.4 mz L (CBOD) SD Results reported are derived from suspect data. 55 SOD results derived from supersaturated D O. va!ues. Sample(i) were aerated per the ,uper;aturatien prcccdure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg L, or the sample dilutions did not meet the requirement of DO residual of at least 1.0 tngi.. Davii & Brown is reporting these results ai valid data. T Storage Condition: Temperature above 6° C due to power outage V Analyte detected in the associated method blank. Notc: the value in the blank Shall not be subtracted from the sample result. Revisiun 04. 17 W SF Dataqual.wpd DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S, South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S l l South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S l 1A indicates AES Laboratory (98016); S 11 G indicates Pace Gulf Coast (73006); S I 1 P indicates Pace Analytical (96042001); S I 1 TS indicates Test America Savannah (98001) S I 1 TP indicates Test America Pittsbur (89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 F4vis4nOt'20 D4L4qw[[5ubLahs)p2.wpd A U � � & B R � � � a2•I W. flclvcr Rolrt1 PH: tI.13•rss-f7af pAO� tE OF In Florence, SC 29501 FAX. 043-656-2200 {r,��( � f � 1 CHA/A( OF CUSTODY RECORD TURNASTANDARDRUSH UND E `P9 REGULATORY: YES NO P2 IT: SAMPLE ANALYSIS REUUrs1L•L) ELSE CODES TO INOICTAT±: IF SAMPLE WAS F'fESeN.ltivc 1 y FILTFRFOORPRf:!;ERI'F.O A=HNO� B = HCL D = II;SOj F = FILTRATION C = NAOH E = NAsS,O, G = ZIIICACETATE E55; Q w _ PROr AMARFA: D=DRINKING WATER (= F G = GROUNDPIATER S = SOLID SL = SLUDGE U O Q1N=1'VASTEWATER O=OTHER PLEASE PRINT LEGIBLY 4 ae � r y Q 1E: FAX: a l—� SAMPLE ID RATE TIME INITIAL FIEII[is LAO II] I III m the Number OI ConlainurS f9! LAGI'I I ent L( 2 FF I LER SfGNATUIiE FLOWINFO I" ICE YE) NO PACK r ��• RECEIPT n TEAIP `j. �° C U13hed by: Gale: 11111 :' I�el411i{IlISIIjt'' by QaIL• 11111U: I(uW(j"%Ld I)w Daw 11riae r JL1 yDade: Tune: c luk by , Dalu fllfle. krti:Llve:ll,q Lfale 1i1m: ci -Sf "AL �vtoi }�•t ljlll�'.1 L..[11 La� 1�1,. �I-. r1lf) /�I `1-� a I 1 t I 1 1 1 I 1 i ) E-� � -L I-t• 1� =0: [•I1.:)VEI1Hbd(uuQ 10/26/2020 https:llpsaweb.clemson.edu/aglab/AgSvcLab,+Lab Results/0000000TURNER, SHERRY2008261543351.htm A N I M A L W A S T E A N A L Y S I S R E P 0 R T Agricultural Service Laboratory LAB No. 70762 Clemson University TURNER, SHERRY ACCOUNT 0000000 PO BOX 219 DATE 08/04/202C CHERAW SC 29520 STOLSON@CHERAW.COM PREPAID SAMPLE NO, 07152040 MANZURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS --------------- ANALYST lbs/ton pi Ammonium Nitrogen 0.02 0.40 pi Organic Nitrogen 0.42 8.44 pi Nitrate Nitrogen 26.77 ppm 0.05 INCORPORATED AVAILABLE NITROGEN ESTIMATE 5.47 SURFACE AVAILABLE ---------------------------------------------------------------- NITROGEN ESTIMATE 5.35 dw/sa Phosphorus as P205 0.63 % 12.56 dw/sa Potassium as K20 0.09 % 1.89 dw/sa Calcium 17.33 % 347.52 dw/sa Magnesium 0.16 % 3.26 dw/sa Sulfur 0.15 % 3.00 Zinc 242.91 oom 0.49 Copper 43.75 Dom 0.09 Manganese 68.56 ppm 0.14 Sodium 271.64 Dom 0.54 Moisture 34.70 Calcium Carbonate Equivalency 0.30 6.04 INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. % moisture 34.7 % solids 65.3 lbs. solids/ton 1306 lbs. solids1500 tons 653000 ppm Ibsiton °a ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.02 200 0.4 0.030628 306.2787 0.612557 Organic Nitrogen 0.422 4220 8.44 0.646248 6462.481 12.92496 Nitrate Nitrogen 0.002677 26.77 0.05354 0.004100 40.99541 0.081991 Incorporated Available Nitrogen Estimate 0.2735 2735 5.47 0.418836 4188.361 8.376723 Surface Available Nitrogen Estimate 0.2675 2675 5.35 0.409648 4096.478 8.192956 Phosphorus as P205 0.628 6280 12.56 0.961715 9617,152 19.2343 Potassium as K20 0.0945 945 1.89 0.144717 1447.167 2.894334 Calcium 17.376 173760 347.52 26,60949 266094.9 532.1899 Magnesium 0.163 1630 3.26 0,249617 2496.172 4,992343 Sulfur 0.15 1500 3 0.229709 2297.09 4.594181 Zinc 0.024291 242.91 0.48582 0.037199 371.9908 0,743982 Copper 0.004375 43.75 0.0875 0.0067 66.99847 0,133997 Manganese 0.006856 68.56 0.13712 0,010499 104.9923 0.209985 Sodium 0.027164 271.64 0,54328 0.041599 415.9877 0.831975 Calcium Carbonate Equivalency 0,302 3020 6.04 0.462481 4624.809 9.249617 July 2020 CHERAW ALKALINE B10SOLQS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIO$OLIDS SAMPLE DATE: September 16, 2020 Biosolids Maximum Maximum Maximum Maximum Metal Allowable Allowable Application Application Content, Metal App. Rate. Rate, Rate, ppm 9 ppm METALS ppm Content, ppm #,'AcrelYr. OTlACrerYr, YVTrAcreiYr 36.3 32,9 Arsenic Total 3.16 4100 1.BO 16609 284 8O 3 3 16012559 Cadmium, Total 1.05 ' 3900 1,70 47344 811.80 0.994 104705495 Chromium, Total 49.93 120000 t 34 00 782 58 1341.38 47.4 49 9299843 Copper, Total 31.81 150000 67,00 614.15 105306 30.2 318119309 Lead, Total 1.19 30000 13OO 3184.7t 5460-74 1,13 119031397 Morcury Twat 018 17,00 0.75 1207,C8 206976 0.172 0 18118053 Molybdenum, Total 4,18 18,00 080 5573 9565 3,97 4 1 a I a9953 Nickel, Total 1854 42000 18.70 294 13 504.33 17.6 18 5394035 Selenium Total 1.05 ' 36A0 4 50 125323 2148.88 0.994 104705495 7inc, Total 21 t.73 1525.00 12500 172.15 295 19 201 2 t 1 7284 t4 PCB BRL 1.60 0 'Actual metal conlem Tess than amount indicated. Biosolids Biosolids Maximum M1ax!mum Nutrient Nutrient CroplSod Applicalicn Application ppm m ppm ppm Content, Content, Requirement, Rate, Rate, 41.68 4168 ppm 'k #!Acre " OTrAcroYf lt/T AcrerYr tea Ibs icon moisture moisture moisture Ammonium Nitrogen 13000 0 01 0 013 0.28 130 130 Organic Nitrogen 444500 044 0 4445 8.89 4445 4445 incorporated Available Nitrogen 284500 028 120_CO t 2 30 210 02945 5.69 2845 2845 Surface Available Nitrogen 280500 028 120-00 T2 47 21 39 02905 5.61 2805 2805 Phosphorus as P205 774500 0.77 8000 301 5 16 07745 15.49 7745 7745 Potassium as K20 154500 0.15 50 CO 944 tfi to 0 1545 3.09 1545 1545 Caldum, Total 17484500 17,48 T74845 349.69 174645 174845 Calcium as CaO 244783 00 2448 0 0 0 Calcium as CaCO31CCEj 323000 0,32 200000 18056 30950 0 323 e.45 3230 3230 Magnesium, Total 210000 0 21 0 21 4.2 2100 21 CO Manganese 90,00 001 0009 0.1B 90 90 Sodium 395.00 0,04 0.0395 0.79 395 395 Percent Moisture 41,68 " These are typical values and must be adjusted based upon speciFc site conditions DT is Dry Tons -of Biosolids WT is Viet Tons of Biosolids CERTIFICATION This bresolld product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and time (calcium oxide) The Town of Cheraw cercfes that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a'Class A" product and has a metal and nutrient content as presented above DIRECTIONS FOR USE This brosoiid is intneded to be used as a soil amendment- The tiosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above The application rate for nitrogen phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics The user should contact the Clemson Extension Service (843-623-2134) andfor the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown, User should also refer to the Clemson Extension Service Circular #476 tilled "Lime and Ferri izor Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKM AVOID CONTACT `PATH THE EYES THE TOWN OF CHERAW IS NOT RESPONS BLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT Mr. John D. Stowe, Public Utility Director P. 0. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX. 843.537-8442 PRODUCT USER NAME: ADDRESS: INTENDED USE: LOCATION OF USE: UANT4 -Y RE IVED: RE EIV D BY, Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number; 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 17-Sep-20 SDG #: SDG-139161 Parameter Result LSID-306997 9-16-20-0011YF Biochemical Oxygen Demand 480 Receipt Date: 17-Sep-20 Report Date: 19-Oct-20 r� Approved By: Scott Fields Lab Director Reporting Limit unit Method 2 mg/L Sit 5210E LSID-306998 9-16-20-0400 BIOSOLIDS Acid Digestion (Solids) YES Selenium, Total <0.994 0.994 Percent Moisture 36.3 0.1 Aluminum, Total 5120 19.9 Arsenic, Total 3.00 0.994 Cadmium, Total <0.994 0.994 Chromium, Total 47.4 0.994 Copper, Total 30.2 0.994 Lead, Total 1.13 0.994 Molybdenum, Total <3.97 3.97 Nickel, Total 17.6 0.994 Zinc, Total 201 0994 Mercury, Total <0.172 0.172 PCB BRL LSID-306999 9-16-20-002 EFF mg/kg wto'o mgAg mg/kg mglkg mglkg mg/kg mglkg mg/k.- 0 mg/kg mpg mg/kg mg/kg Flag Date Time Analyst 9 172020 10:39 AE EPA 200.2 9/21/2020 1030 JR EPA 7010 6010D 9/22/2020 10:56 JR SW846 3540 9/18/2020 13,34 ML SW846 601 OD 9/21/2020 12;27 JR SW846 601 OD 9/22;2020 10:52 JR SW846 601 OD 9/21/2020 1 l -23 JR SW846 6010D 9/21/2020 11:23 JR SW846 601 OD 9/21/2020 12-25 JR SW846 6010D 9/21/2020 12.25 JR SW846 6010D 9/21/2020 12:27 JR SW846 6010D 9/21/2020 11.23 JR SW846 6010D 9/21/2020 11.23 JR SW846 7470A - S SI IA)`D 9/29/2020 19:33 SK SW8468082A SIIA/D 10/14/2020 21:03 UH Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O. BOX 219 CHERAW, SC 29510 Contact: SHERRY TURNER Client ##: 163 Sample Date: 17-Sep-20 SDG#: SDG-13916E Reporting Parameter Result Limit Unit Biochemical Oxygen Demand <:2.,, '_ South Carolina Certification Number: 21117 Receipt Date: 17-Sep-20 Report Date: 19-Oct-20 Approved By: Scott Fields Lab Director Method Flag Date Time :analyst SM 32 1 OB 9 172020 10:39 AE Page 2 ACCE55 ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown 124 NV. Nfelver Road Florence SC 29501 ATTENTION Scott Fields PROJECT ID 306998 LABORATORY REPORT NUMBER 2009P35 DATE October 02, 2020 Primary Data Review By Secondary Data Review By / < Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamickgaxs-inc.com PLEASE NOTE: - Unless otherwise noted, ail analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDIIEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, N'ELAP certified laboratory # E87582 - A]HA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC; GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803 781.4243 or toll fee at 883.315.4243 es /� � U q rt03s DAVIS A � Y `I S & BROWN 121 4V- Alclver Road PH., 843-665.6746 PAGE # OF El �7 BROWN Florence, SC 29501 FAX: 843-856.2208 2O-6- tiZ REGULATORY: YES rJa CHAIN OF CUSTODY RECORD TLlRNJiROUNO PAYE: _p1 STANDARD Rush P2 '17 "AMPLE ANALYSIS REGUES FED USE COVES TO INDiCIATE IF 5+1IdPLE KAS Preservative D Q`�L� ey&,)o EIL,TF-REnORPRESERVEl) A=HNO, R=lICL D=HISO, F,FILTRATION N ESS, r C = NAOH E = NA2:i=❑3 G = ZINCACETATE n_ y[ l 2!ffl)C-A—A6FA: D = D14INKING WATER — 4- ,r G L GHOUNDWATER S - SOLID SL - SLUDGE U n W WASTEWATER O-OTHER a v (9 LL 0 :M 1 PL€ASEPRINT LEGIBLY _- FAX: Cd � o SHADED AREAS FOR LAB USE ONLY SAMPLE ID DATE TIME INIDAL r r MOTES L.AU 10 I Fill In We Number of Containers for EACH -I'es! 30cP 9 9 a how ova- I-T ER 51GNAtUFiL PLOWINFO ICE YE No PACK RECEIPT i TEMP: °C ` sha y �e:e l!t Ke@tlyulsled 7V Clair I uuu I(rkI :julyl orf 6v L1n:a lIlhtl 1 1' Oa flme. Reaeved icy Dam, Limn li.:rolvnd toy Page 2 of 5 Analytical Environmental Services, Inc date: 2-Oct-20 Client: Davis & Brown Client Sample ID: 306998 Project Name: 306998 Collection Date: 9 1.612020 10:17:00 AM Lab ID: 2009P35-00t Matrix- Solid Reporting Dilution Analyses Result Limit Qual Units 13atchID Factor Date Analyzed analyst Total Mercury by SW7473 (S'*N'7473) Mercury RRi. n.112 -mg Kg -itrs 103442 1 0912912020 19:33 SK PERCENT MOISTURE D2216 Percent'IDisture 419 n w " R433935 I 10r01202000:00 AV QwILIfeTT: Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyze not NTLAC c-rtiriicd H Analytc detected in the associated methad blank n GrCltrr Q= ResuN value E Estimated (value above quantitation rang:) S Spike Recovery eutside limits due to mattim Parr See case narrative F Analyzed in the lab whtch is a deviation from the method < Less than Result value J Estimated value detected below Reporting Limit A NA IX1-1 CAI. I ]EN V I RONA100-AI. AE.S SI:RVICII.S, INC. 1. Client Name: Access Analytical, Inc. 2. Carrier. FedEx U UPS U USPS[J Cllent[J CourlerF-1 Othei 3. 4. 5. 6. 7. 8. 9. .0. .1. .2. SAMPLE/COOLER RECEIPT CHECKLIST Yes No N/A AES Work Order Number: 2009P35 Details Clear Save t31s Comments Shipping container/cooler received in good condition? • n damaged i leaking othe4 ' Custody seals present on shipping container? • Custody seals intact on shipping container? ` Temperature blanks present? • Cooler temperature(s) within limits of O-6'C? [See item 13 and 14 for temperature recordings.] e 0 ® Cooling initiated for recently collected samples f ice present i Chain of Custody (COC) present? U. Chain of Custody signed, dated, and timed when relinquished and received? 0 Sampler name and/or signature on COC? • Were all samples received within holding time? TAT marked on the CDC? • If no TAT Indicated, proceeded with standard TAT per Terms & Conditions. Li .3• Cooler 1 Temperature 3.1 °C Cooler 2 Temperature "C Cooler 3 Temperature "C Cooler 4 Temperature °C .4. Cooler 5 Temperature °C Cooler 6 Temperature "C Cooler 7 Temperature "C Cooler 8 Temperature "C .5. Comment%- I certify that I have completed sections 1 15 (dated initials]. AftS J/23/20 Yes No N/A Details Comments Were sample 4untainers intact upon receipt' • Custody seals present on sample containers? • Custody seals intact on sample containers? • ❑o sample container labels match the COC? e O 0 incomplete into illegible no label other i Are analyses requested indicated on the COC? • Were all of the samples fisted on the CDC received? Q O samples received but trot listed un UX samples listed on COC not received Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? • Were VOA samples received without headspace (< 1/4" bubble[? i Were trip blanks submitted? listed on CDC not listed on CDC 17 Comments; This section only applies to samples where pH can be 1 certify that I have completed sections 16-27 (dated Initials]. 8H 9/24/20 checked at Sample Receipt. Yes No N/A Details Comments Have containers needing chemical preservation been checked?' • Containers meet preservation guldelmes? • Was pH adjusted at Sample Receipt? 4191-0-1 ' Note: Cedairi analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs. and Oil S GreaserrPH. Tltts also excludes metals by EPA 200.7, 200.8 and 245.1 which will be verified betwuon 16 and 24 hours alter preservalinn. I certify that I have completed sections 28-30 (dated initials}, fjH 9/24/20 Locked fheckltst i `) lr] Revd P-wrr 4 of End of Report ACC>;S5 ANAL)TICAL, INC. ANALYTICAL REPORT CLIENT Dais & Brow-n 124 tip". McIver Road Florence SC 29501 ATTENTION Scott Field; PROJECT ID 306993 LABORATORY REPORT NUMBER 20lfi7t6 DATE Oca.-ber 16, 2020 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project'Manager, Access Analytical aamickg axs-inc.com Unless othernvise noted, all analysis an this report performed at Analytical Environmental Services Inc. (aES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, N CDENi2 certified lab # 362, GA certified lab # FL-E87582, NELAV certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbloingry (Fungal) Direct Examination. Local support services for this project are provided by _access Analytical, Inc. Access Analytical is a representative ofAES serving client in the SC NC GA areas. All questions retarding this report should be directed to your local Access _analytical representative at S03.731.1243 or toll fee at 883.315.4243 2o- 6- 17 Z,009103S In DAVIS & BROWN O w A ! 124 W. McIver Road PH. 843_05-6746 PAGE # OF ,V Flarene_e, SC 29601 FAX_ 843-655,2208 REGULATORY: YES NO CHAIN OF CUSTODY RECORD rUNND Pi -STANDARD RUSH P2 j-� SAMPLE ANALYSIS REQUEST FO (y rz o a USE GOVES fO 1AWICTATE IP SAMPLE WAS MLTEREOORPRESERVED A- HNO3 R- HCL D= H:50+ F n FILTRATION C = NAOH E n NA,5103 G - ZINCACETATL P[eaervallve a, N o U a r' cn yv `L � i Q �� - :E$S: PIMORAM A : D = DRINKING WATER G- GROUN13WATER S - 50LID SL = SLUDGE W- WASTEWATER O=OTHER PLEASE PRIN-r LEGIBLY SHADED AREAS FOR LA B USE ONLY IF: FAX: SAMPLE ID DATE TIME INITIAL NOTES LAB ID Ail In the Number of Containers for EACH Test LER SIGNATURE FLOWINFO ICE S NO PACK YE RECEIPT TEMP: C xsh y inle. Tirt 2z12.1 Hewlqu.she+i by Datn: T:nte. llur,qutsndd hy: Dale Tillie au { Lc Da •. TIME: 2lLv102L Heaelvel by : atn Time: HilcOunn lq Du'e e'71fi D- NOVEMBER 2012 -- Page 2 of 6 Analytical Environmental Services, Inc Dutc; 16-Oct-20 Client: Davis & Brown Project: 306998 Case Narrative Lab ID: 2010716 At the request of Angela Martin via email 10-07-20 sample 2009P35-001 was analyzed far total PCB;. PCB Analysis by Method 8082. Matrix spike an&rr matrix spike duplicate analyses were not pert,,.rmed with Batch 3N193 due to insufficient sample volume. Analytical Environmental Services, Inc Date: 16-Oct-20 Client: Davis & Brown Client Sample ID: 306998 Project ,Name: 306998 Collection Date: 9.16/2020 10:17:00 A.hi Lab ID: 2010716-001 Matrix: Soil Analyses Result Reporting Qual Units BatchlD Dilution Date Analyzed Analyst Limit Factor POLYCHLORINATED SIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 57 ug. Kg.dry 304193 l 10.14/2020 21:03 Ulf Aroclor1221 BRL 57 ugKg-dry 304193 l 10+14i20202L03 UH Aroclor 1232 BRL 57 ug Kg -dry 304193 1 10.14/2020 21:03 UH Aroclor 1242 BRL 57 ug/Kg-dry 304193 l 10i 1412020 21:03 UH Aroclor 1248 BRL 57 ug Kg -dry 304193 l 10: I4120M 2I:03 UH Aroclor 1234 BRL 57 ug Kg -dry 304193 1 10.14/2020 21:03 UH Aroclor 1260 BRL 57 ug/Kg-&f 304193 1 10.:14/2020 21:03 UH Suer. Decachlorobiphenyl 5 0 45.7-140 °nREC 304193 l 1014i2020 21:03 UH Surr: Tetraehloro-m-xylene 03 45.3426 °6REC 304193 l 10r 1412020 21:03 UH PERCENT MOISTURE D2216 Percent Moisture 419 0 wrl. R436674 l 10;09.'2020 00:00 JW Quallllers: Value exceeds maximum contaminant level nRL Below reporting limit H Holding lima fur preparation or analysis exceeded N lnalyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estanxed(valueabove gvu:utatianrange: 5 Sp:kc Recovery eulstde Lmits due Lo mmx Nair See case namlive F Anaiymd in the lab which is a deviation from the method < Less than Result value I Estimated value detected below Rcporung Lima (SIA.mm.rricAI. ENvtRONNI I:NC111. AES Sauvicm.INC. 1. LrLent N,,,,t.. Access Analytical, Inc. 2 Carries fedfx ■! u!'S 1 USN$ Christ Olivier' 43hr1 SAMPLE/COOLER RECEIPT CHECKLIST Yes No WA 1Ar� L �t`a1.Yo1y,{xrdrr Nultlhrr� ��g�� �/��/�j Slupp,ng u.utainer/cuoler received to band corid,tiun/ • damaged Peaking t,rltel Custody steals present on shipping container? Cllslndy y als intact on Shipping tantaliser?Tuitirwr rtire Idallks prese•rlt?Cuuler tenijlvrature(s) Withal III [1115 [lt -li'C? �SCe Ileltr D anti 1-ItUr rucardinep I O O Co4hnW inlVilled Ire IBCBlltly I.11 Wt 11'II 4JI1 �dL , f Iilemperatule Chain ul Custudy [LOCI present? +Chainm tit Lustudy Signed, dated, and unied when relinquished and receiyed71;t re n COO Sapler oame and/or signatuti Were all samples received within holdin ngtune./]AT marked othe COCI II unTATafdiralvd, prucerded witil standard IA1 per brats & Conditions. II- CL,aler ' Irniljerature 1 14 Cutllef l IrFnl7er•t[ull•_ 1 '. Q,+lnfernls. °L ruuler 7 lemperatiut• I(- Con el "I1011lfeldtufr "( L`uulet 11 lrrnprrd{u,r 0(' '{ {tiUlel lilL•lI,I]elittllllr tlNdel "r !e'RIIIrL$IHC_ "l. ti,Hle't }t Iefllpr_ldtlNr ._ •� •'C 1 Lertily Oil -at I have ulmpleted sectium 1 15 (dated Initialsl Yes Nil N/A rt..t.uh I ........ Wei sample t tirllalners MULL tlpolf fefelpt' t IealS presrrft ulr yalifp)r CA1jj(aLJ W}I tarstady st'als intact ton ample cunralnt:N: • Nu serrplr uutd(nthr Idhrl: hatch the riiCr O O t',L CftIK�ICIr 11110 dirgdlh• Iln Llbul t7tllel Ara: aildipus I eLiLluSted ind,Cafea oil the C UC 1 • Wt-r,• .dl .it Ihr• s.141011[re listed till ttw C oc recem-0 Q O O Samples re•eetvrd but not Ilztrd Lill (.U(- sdmple .. Irstf:d nit COC clot w. t.1vi•d WiS Itle Sarlplr Loliechurl Batt±/tlnly nolydr • Old We It•: ViVe •.ultIUVI,l S.Irttliie Vnhinir[nl 1luucated drtalpes • WeI IT S,th,llie, re( BiVell Iit apldulit late LUlltdlrlrl Sl • Welt V0A--im des zeculved wilhout tfeadspace i> 114" INihl,lti'I? r Were IfIp blaliks stihnlitted • listed on LOC i ,nit Iisted kill LOC 17 (n,lir eWtL This seojon tidy applies to samples where pH can bu I rertily 11411 1 have Lunipleled saclium 16-27 (dated initials). h1i 1024120 rheci od at Sample receipt. Yes Nn N/A n..t..aa IS 29 :if). Have conWutw&. needing chefmc.fl preservation been cilecked? 0 1 0 1 • Luinainers riteet pfeSefVktirlf Q 1• Was pH adlw,iud al Sample Itecugrt+ NOW L.Uflaul dndfyse8 requae eualtllcar preservntlon nil must ha chuckatl in mu latirlsalo+y ats!l nil upon E;ampke Ilecrtpt such t1s r,()ptprins. V VGs and Oil E Gfease,l PH , INS dl.+x , -011dLitl ntelals by CPA W0 1. $W A and 245. 1 which will be veuhed duty doe 1 tit .t:111 : •1 u.nns :dike 1urstfrl,lhtd, I certify that I have completed sections 2It 30 {dated Initials) bH 41/24/20 Page 5 of 6 End of Report DAVIS & BROtiti N Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flan next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A ROD result ihowcd toxic tendencies. B The 130D data is suspect due to a failed quality comrol check (GG.%). C The BOD data is suspect due to a failed qualir� contra check (Blanks). D Results are repurted on a dry weight basis. H Sample was analyzed beyond the accepted holding time 1 Estimated value. Presence of the compound wa; confirmed but less than the r-ror.:d 4et.cticn limit. L Results based on colony counts outside the acecpraEc range -Mc ideal range for the (--cal colobrm t:st is 20 - 60 colonies .MS Sample matrix spike percent recovery was outside the accepted ran;_. 0 Sampltd, but analysis lost or not performed P Samplc was not properly preserved upon receipt G LCS or NIS exceeds the control limits. S Sample was analyzed by another SC terrified Lab SC Seed Correction outside the accepted range of 0 60 - , d mgL (BODr Seed Correction outside the accepted rang: of 0 60 - I d mg L CBOD i SD Results reported are derived from suspect data. SS ROD results derived from supersaturated D.0 values Sample(i) were aerat:d per the iuperiamrarion procedure in Standard Methods 52l .B SDF Sample Dilutions did not meet the requirement of DO depiction of at least 2 (; mz L, ar the samptc diluiiori did not meet the requirement of DO residual of at least 1.0 mg-L. Divis & Brown is reparttng these results is valid data. T Storage Condition: Temperature aboyc 60C due to power autagc. V Analyte detected in the associated method blank. \,)to- the value in the blink shall not be iubtracted from the Sample result. Rc%ision 04 1- WSF Dataqual xpd DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 S2 South Carolina Lab Certification Number: 93013 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 S5 South Carolina Lab Certification Number: 84002 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 S9 Lab samples were subcontracted. See attached documentation. South Carolina Lab Certification Number: 94014001; 94014002 S 1 I South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 1 IA indicates AES Laboratory (98016); S 11 G indicates Pace Gulf Coast (73006); S 11 P indicates Pace Analytical (96042001); S 11 TS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg (89014) S12 AASHTO R18 Certified S 13 S 14 South Carolina Lab Certification Number: 96012 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 S21 South Carolina Lab Certification Number: 96027001 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 S26 South Carolina Lab Certification Number: 82014001 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 S31 Galbraith Laboratories, Inc. Knoxville TN South Carolina Lab Certification Number: 32576 Rcveon6',.20 Dmaq%uI(5ub[a6e'ip2 wpd D p O `�` 124 W. McIver Road PH. 943-665-6746 PAGE It% OF H & YY N Florence, SC 29501 FAX: 843-656-2208 In CHAIN OF CUSTODY RECORD Tl1RNAROU D TIME: Pi TIME. ~P2 REGULATORY: E NO AND RUSH 4T: SAMPLE ANALYSIS REQUESTED USE CODES TO INDICTATE IF SAMPLE WAS Preservative 0 FILTERED OR PRESERVED: A - HNOj N -o n frQ C.✓ H = HCL D - H=SO, F = FILTRATION C = NAOH E = NA,S=O, G - ZINCACETATE :ESS: PROGRAMAREA. D=DRINKINGWATER a ¢ E U z G = GROUNDWATER S = SOLID SL = SLUDGE t7 � W =WASTEWATER O=OTHER C PLEASE PRINT LEGIBLY le: FAX. a SAMPLE ID DATE TIME INITIAL NOTES LAB ID ::r,4 Fill In the Number of Containers for EACH Test 1 -� -00} -l7-2� �Fs! �- 5 C ,3D�9q -)to •�O^oYcDO - rp•ao /U11 S err- f-Z S _ER SIGNATURE FLOW INFO I ICE „n YES NO PACK - ......,._ RECEIPT TEMP - 20 oC lashed by: Date: Time: Relinquished by Dale: Time: Relinquished by: Date: Tema: q-1� aL) 0 qoa _ _ !oz<s by: Date: Time: 6 y Date: Time: Received by_ Date. Time: p ��j�17�_> L/aIt� ants: 10/26/2020 https:llpsaweb,clemson.edu/aglab/AgSvcLab/Lab Results/0000000TURNER, SHERRY2010161003311.htm A N I M A L W A S T E A N A L Y S I S R E P 0 R T Agricultural Service Laboratory LAB No. 101016 Clemson Universitv TURNER, SHERRY ACCOUNT 0000000 PO BOX 219 DATE 10/15/2020 CHERAW SC 29520 STOLSON@CHERArd.COM PREPAID SAMPLE NO. 09152050 MANURE: OTHER STORAGE; COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS --------------- ANALYST lbs/tan pi Ammonium Nitrogen 0.01 0.26 ❑j Organic Nitrogen 0.44 8.89 pi nitrate Nitrogen --------------------------------------------------------------- 47.82 ppm 0.10 INCORPORATED AVAILABLE NITROGEN ESTIMATE 5.69 SURFACE AVAILABLE NITROGEN ESTIMATE 5.61 dw/sa Phosphorus as P205 0,77 ---------------- % 15.49 dw/sa Potassium as K20 0,15 % 3.09 dw/sa Calcium 17.48 % 349.69 dw/sa Magnesium 0.21 % 4.20 dw/sa Sulfur 0.15 % 2.92 Zinc 249.61 ppm 0.50 Copper 63.57 ppm 0.13 Manganese 91.56 Dom 0.18 Sodium 393.66 Dom 0.79 Moisture 41.68 Calcium Carbonate Equivalency 0.32 1 6.46 ----------------------------------------------------------------------- INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80'« of ammonium-N, 60�- of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. % moisture 41.68 % solids 58.32 lbs. solids/ton 1166.4 lbs. solids/500 tons 583200 °o ppm Ibs:'ton °o ppm lbs/ton Ammonium Nitrogen as-sam led as -sampled as -sampled dry ton d ton d ry Organic Nitrogen 0.013 130 0.26 0,022291 222.9081 0.445816 Nitrate Nitrogen 0.4445 4445 8.89 0.762174 7621.742 15,24348 Incorporated Available Nitrogen Estimate 0.004782 0.2845 47.82 0.09564 0.008200 81.99588 0.163992 Surface Available Nitrogen Estimate 0.2805 2845 5.69 0.487826 4878,258 9.756516 Phosphorus as P205 2805 5.61 0.480967 4809,671 9.619342 Potassium as K20 0.7745 7745 15.49 1.328018 13280.18 26.56036 Calcium 0.1545 1545 3.09 0.264918 2649.177 5,298354 Magnesium 17.4845 174845 349.69 29,98028 299802.8 599.6056 Sulfur 0.21 2100 4.2 0.360082 3600.823 7,201646 Zinc 0.146 1460 2.92 0.250343 2503.429 5.006859 Copper 0,024961 249.61 0.49922 0.0428 428.0007 0,856001 Manganese 0.006357 63.57 0.12714 0.0109 109.0021 0.218004 Sodium 0.009156 91.56 0.18312 0.0157 156.9959 0.313992 0.039366 393.66 0.78732 0.0675 675 1.35 Calcium Carbonate Equivalency- 0.323 3230 6.46 0.553841 5538.409 11.07682 September 2020 CHERAW ALKALINE 8 OSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE, November 24, 2020 Biosolids Maximum Maximum Max mum Maximum Metal Allowable Allowable Application App1 cation Content, Metal App Rate Rate Rate, METALS ppm - Content ppm #,AcreNr DT AcrerYr '.W.AcreiYr Arsenio, Total 0.90 41-00 180 70749 994 7a Cadmium Total 0.90 39 CO 1 70 668 19 93952 Chromium Total 54.75 12GO CO 13400 87026 122365 Copper, Total 3939 t 500 00 67 00 6C4 31 85041 Lead, Total 1,90 3120 00 1300 2428 35 34144.1 Mercury Total 0 13 17,00 075 2CO7 06 282208 Molybdenum Total 3.62 ' 18.00 030 7861 11053 Nickel, Total 21.49 42000 la 70 30948 435 15 Selenium Total 0.90 3600 450 Ina 73 243696 Zinc, Total 275 19 152500 12500 161 53 227 12 PCB BRL 1.60 ' Actual metal content less than amount indicated Biosoiids Nutrient Content, ppm Biosoiids Nutnent Content, % CrcplSoil Requirement, #,Acre - Maximum Application Rate DT AcrefYr Maximum Application Rate Va Acrelrr Ammonium Nitrogen 10000 001 Organic Nitrogen 552500 055 Incorporated Available Nitrogen 266000 037 12000 1166 16.39 Surface Available Nitrogen 3630.00 036 t20 00 11 76 1653 Phosphorus as P205 830500 083 eo ao 343 482 Potassium as K20 2655.00 027 50 00 670 9 42 Calcium, Total 220535 00 22.G5 Calcium as CaO 3CS749 00 3087 Calcium as CaCO3 ;CCE- 475000 0 43 200000 tag 73 21053 Magnesium, Total 2490 CO 025 Manganese 95C0 001 Sodium 48500 00 Percent Moisture 2888 These are typical values and must to adjusted based up::n specific site candihons DT is Dry Tons of Biosands WT s Wet Tans cf Biesc ids CERTIF CATION: This biasoljd product has been produced by the Town of Cheraw s V.astowater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxldej The Town of Cheraw cerufes that this b oso d complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a `Crass W product and r,as a metal and nutrient content as presented above DIRECTIONS FOR USE This bwsolid .s ntneded to be used as a sc- amendmem The biosolid land application rate shall not exceed the Masi restrictive Nlaximum Application Pale as indicated in the table above The apptication rate for nitrogen phosphorus potassium and calcium is dependent upon the crop grown and sale soil characteristics The user should contact the Clemson Extension Service (843-623.2134: andlar the Soil Conservation Service ias3-623-21aTi for assistance n determining the proper application rate for each crap and site In no case shag the land app cat cn rate exceed the agronomic rate for the crop grown User should also refer to the vternscn Extension Service Circular #476 titled'L me and Fertilizer Recommendations' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORD NGLY AVOID PROLONGED CONTACT WITH THE SK N AVOID CCNTACT V'IITH THE EYE THE TOV`&I OF CHERAW IS NO- RESPONS-BLE FOR NIPRDPER USE OR HANDLING OF THIS BIOSOLID PRODUCT Nit Jahn O Stowe Public-0-billy Director P 0 Box 2t9 Cheraw SC 29520 Telephone 843-537-8440 FAX 843-537-8442 PRODUCT USER NAME ADDRE S — - - — - INTEN�ED u�`aE — LOCATIO�I OF VSE QUANTITY RECEIVEL? RCE,VEO BY -' Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification -Number: 21117 P.O. BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNNER Receipt Date: 24-Nov-20 Client #: 168 Report Date: I I-Dec-20 Sample Date: 24-Nov-20 1. SDG #: SDG-140255 Approved By: � �11-1 +� Scott Fields Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-309597 BIOSOLFDS 11-24-20-005 Acid Digestion (Solids) YES EPA 200.2 11-30.2020 8:30 JR Selenium, Total <0.960 0.96 mgkg EPA 7010/601 OD 12A.2020 14:54 JR Arsenic, Total 3.74 0.96 mgkg SW846 6010D 12.:8;2020 14:54 JR Cadmium, Total <0.960 0.96 mgdkg SW846 6010D 11/30:2020 11:39 JR Chromium, Total 58.1 0.96 mg kg SW846 6010D 11/30 2020 11:39 JR Copper, Total 41.8 0.96 mg kg SW846 6010D 11130 2020 11:39 JR Lead, Total 2.02 0.96 mg kg SW846 601OD 11/30/2020 11:39 JR Molybdenum, Total <3.84 3.84 mVkg SW846 601 OD 12/9/2020 17:19 JR Nickel, Total 22.8 0.96 mg kg SW846 601OD 11/30/2020 11:39 JR Zinc, Total 292 0.96 mg kg SW846 60IOD 11/30/2020 11:39 JR Mercury, Total 0.141 0.131 mgikg SW846 7470A S S I 1 D 12/1/2020 18:40 SK PCB BRL mp,•'kg SW846 8082A S1 I D 12/3/2020 2-02 UH Paint Filter PASS P f SW846 9095B 11/25/2020 9:00 NIL LSID-309598 11-23-20-001 INF Biochemical Oxygen Demand 486 2 mgl. SN15210B 11/24/2020 13:19 AE LSID-309599 11-23-20-002 EFF Biochemical Oxygen Demand <2.0 2 me-L SM 521OB 1124:2020 13:19 AE Page I ACass ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown 124 W Melver Road Florence SC 29501 ATTENTION Scott Fields PROJECT ID 309597 LABORATORY REPORT NUMBER 2011T03 DATE December 03, 2020 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project MManager, Access Analytical aamick .axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 93016, NCDENR certified lab # 562, CA certified lab # FL-£87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID;100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc Access Analytical is a representative ofAES serving client in the SC-�lClGA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.791.4243 or toll fee at 883.315.4243 Atte&s i)us P - 0 ,,P�r 21- 0 - 20 u-10 3 DAVIS & BROWN 124 W. Mclvur Hood PIP s47-665-67,16 PAGE; e . , , ■ 1=lorencu, SC 29501 FAX: 843-G56-2209 REGULATORY: YES NO CHAIN OF CUSTODY RECORD TURNAROUNO TIME: P1 5TANI]ARo RUSH P2 CLIENT. L < SAMPLL AHALYSI8111=4U1_S11 Al 111111 ¢ O.. USE CODES To ININGTATE IF SAMPLE WAS FkTERE-DO1?1,R `SFf2VED: A« IINOI B - IICL D = H250, F - FILTRATION C a NAOH E= NAzS20, G-7JNCAGETATE Preservattva a i U C7 'a W, 'L � L) I :a! `� -+;-. CSU Q— CL Q) o C) ADDRESS:— P1iOGRAMARFA : A = DRINKING WATER G -, GROUNDWATER S o SOLID EL -SLUDGE Y! - WASTEWATEF2 OFOTHER co Italp_-ft5&ffl=(;fAs SHADED AREAS FOR LAS USE ONLY f lIONE: FAX: SANIPLE tD DATE TIME INITIAL NOTES L.AB ID 1kj?qb0 Fill In Ilia Number of Containers for EACH Test FFF SAMI'LL-H SIGNATURE FLOWINFO ICE NO PACK 7EW: 0. l oC Raanqu by nit I lute: _ [t ?J [oc7v i 4arIul;hed by u�lz hlv.- Ite:fnqu!shed by 001t 11mu: Rae y Time F= S'� Rees ved by e3.iSe Tinwx Itecelund by iMde: no. Curfner•ny rssr n.n �If]LCAM]l.0 time Page 2 of 5 Analytical Environmental Services, Inc Date: 3-Dcc-20 Client: Davis & Brown Project Name: 309597 Lab ED: 2011T03-001 Client Sample ID: 309597 Collection Date: 11/24/2020 8:13:00 AM Matrix: Solid Analyses Y Result Reporting Qual Units BatchlD Dilution Date Analyzed Analyst Limit Factor Total Mercury by SW7473 (SW7473) Mercury 0.141 0.131 TrgKg-Lh'e 306693 i 1210U202c, 18:40 SK POLYCHLORINATED BIPHEitiYLS SW8081A (SW3550C) Aroclor 1015 Ham- as ug]Cg-dry 306751 1 12.4V202002:02 UH Aroclor 1221 Hitt -N ugKg-dY 306751 1 12iO3/202002:02 UFl Aroclor 1232 BRi- 34 ugKg-dry 306751 1 1-10312020 02:02 UH Aroclor 1242 BRL 44 ugxg-dry 306751 1 12,03/202002:02 UH Aroclor 1248 BRL 44 ur Kg-dr9 306751 1 12/03/2020 02:02 UH Aroclor 1254 BRL ad ugKg-dry 306751 1 12/03l202002:02 UH Aroclor 1260 BRL 44 igKg-dry 306751 t 12iO3'202002:02 UH Surr; Decachlorobiphcnyl 75.6 45.7-140 °aREC 306751 t 12031202402:02 UFl Surr: Tetrachloro-m-xylene 83.7 45.3.126 16REC 306751 12 0312020 02:02 UH PERCENT MOISTURE D2216 Percent Moisture 23.4 0 R4408_D 1 it. 2W2020 00:il0 AV Onaltren! Value exceeds maximum contaminant level BU Below reporting Grant H Holding times fer preparation ar analysis exceeded V Analyse not NELAC ceniGed B Analyse detected in the associated meshed blank > Greater than Result value E Estimated (value shave guanatroan range) S Spike Recovery outside limits Jul ro matrix Vat: See Gnfe narrative F Analy7ed in the lab Axii is a deviation Fom the mcOwd Less thorn Result value ! Estimated value detected belaw Repotting Limn t( Ar�NALVI•ICAl. >E.NVIRON1%1IWI-A1. A F=S SERVICES, INC. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2. Carrier: FedEx On UPS ❑ USPS ❑ Client ❑ Courier0 Othei 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Cooler 1 Temperature 0.9 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19, 20. 21. 22. 23. 24, 25. 26. Yes No NIA 1]etalls AES Work Order Number: 2011T03 Clear Save as Shipping container/cooler received in good condition? damaged El leaking U other[] Custody seals present on shipping container? Custody seals intact on shipping container? R)on •Temperature blanks present? Cooler temperatures) within limits of 0-6'C? (See item 13 and 14 for temperature recordings.) O Cooling initiated for recently collected samples / ice present I I Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? Sampler name and/or signature on COC7 • Were ail samples received within holding time? I TAT marked on the COC? • I Q If no TAT Indicated, proceeded with standard TAT per Terms & Conditions. °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1.25 (dated Initials). Ml 11/25/20 Yes No NIA nat2u. r_�_. .._ Were sample containers intact upon receipt? • ------------- Custody seals present on sample containers? Custody seals intact on sample containers? Q 0 1• Do sample container labels match the COC? O O O incomplete Info illegible no label I other Are analyses requested indicated on the COC? • Were all of the samples listed on the CDC received? O O O samples received but not listed on COC samples listed on COC not received Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? Were samples received in appropriate containers? Were VOA samples received without headspace {c 1/4" bubble)?Were g_o__l trip blanks submitted?• listed on COC not listed on CDC 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 {dated initials). M1 11/25/20 checked at Sample Receipt. Yes No N/A Details r,.,..,.. *, 28. Have containers needing chemical preservation been checked? ' • 29. Containers meet preservation guidelines? - 30. Was pH adjusted at Sample Receipt? • - ivote: uenain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Colilorms, VOCs and Oil & Greaso/TPH. This also excludes metals by EPA 200.7, 200.E and 245.1 which will be verified between 16 and 24 hours after preservation. I certify that I have completed sections 28-30 (dated Initials). MJ 11/25/20 Checklist 7.9.20 Rev 3 Locked Page 4 of 5 End of Report DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier 'IS"' indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S South Carolina Lab Certification Number: 23101 S1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratoa Clemson University S7 South Carolina Lab Certification Number: 3600I S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S10 South Carolina Lab Certification Number: 84009 S 11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 980I6 Note: S 11 A indicates AES Laboratory; S 11 G indicates GCAL Laboratory S 12 AASHTO R18 Certified S13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S15 S 16 South Carolina Lab Certification Number: 84004 S17 South Carolina Lab Certification Number: 96037001 S l8 South Carolina Lab Certification Number: 95005 S19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 I South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S25 Sample was analyzed by Microsee s, Inc Laboratory 926 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 Revision 03. l3 Dataqual (SubLabs).wpd DAVIS & BROWN 72.1 NJ. Mclver Hoar! PH: 343-665•G7.1fr 0orerfcc, SC 29501 FAY. 11.13-656-2201J REGULATORY: CHAIN OF CUSTODY RECORD :LlENT. i, ` _ ,+11F'Li:l+F1ALY515 R_gIJESTC•U i'resclvalivc DDRESS! C% Lfl S lh LL R HONE' FAX: it o -, a r_ L SAt.1PLE fD DATE TIME IJJITIRL � } t Fill in the Nimstur of Containers for i AGH i est It-Z3- 7.� --apt ��J�" rt-z�-�• 7ti�s ,,.� [, r f TURNAROUND TIME I' 1 _L,'6TANrJARD RUSH P2 USr CODES TOWD1CTATE IF S.A;,1PLt WA FIL TERED+')R PRESFRtxD A = KNO, B = HCL D = Il,SO, F = FILTRATIOrl C = NADII C = NA,S,O, G = ZJNCACETATE PROG.RALL.41?i A: D = DRINKING WATER t G = GROUNDWATER S = SOLID SL = SLUDGE W=WASTEWATER O=OTHER •Y PLEASE PRINT LEGIBLY cl NlJ i L=5 I LAB It) ,s ue I boa L7, al;a IPLER SIGNATURE p F1.I7tV1NF0 ICE ICE YES NO PACK L�f RECEIP TV, L° C lmyuuhed u%' Dafe: Time: by �i D< a limb Fttlia, msheq Ir .,',me � TP7 D ceivcd/ Y. '�v►" ��` Dale �.S !! Z zio TI `ie' �Vl ivied by n .a ,[e i urx" I�rceweq t>• . mnn,�:: �[y A r, e� r Gi l rlct C.• ,, 13 f k . 1 l 1 LIED- Fit _e11� - A N I M A L `r1 A S T E A N A L Y S I S R E P O R T Agricultural Service Laboratory LAB No. 121230 Clemson University TURNER, SHERRY ACCOUNT 0000000 PO BOX 219 DATE 12/17/2020 CHERAW SC 29520 STOLSON@CHERAW.COM PREPAID SAMPLE NO. 11242005 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLES BASIS --------------- ANALYST 1bs/ton A Ammonium Nitrogen 0.01 % 0.20 A Organic Nitrogen 0.55 11.05 A Nitrate Nitrogen --------------------------------------------------------------- 164.99 ppm 0.33 INCORPORATED AVAILABLE NITROGEN ESTIMATE 7.32 SURFACE AVAILABLE NITROGEN ESTIMATE 7.26 dw/sa Phosphorus as P205 0.83 ------------------ 1 16.61 dw/sa Potassium as K20 0.27 ? 5.31 dw/sa Calcium 22.05 441.07 dw/sa Magnesium 0.25 4.98 dw/sa Sulfur 0.22 4,41 Zinc 293.01 ppm 0.59 Copper 64.72 ppm 0.13 Manganese 93.88 npm 0.19 Sodium 462.89 ppm 0.97 Moisture 28.88 Calcium Carbonate Equivalency 0.47 9.50 ----------------------------------------------------------------------- INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 601 of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100& of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. % moisture 28.88 % solids 71.12 lbs, solids/ton 1422.4 lbs. solids/500 tons 711200 °a ppm lbs/ton °,a ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.01 100 0.2 0.014061 140.6074 0.281215 Organic Nitrogen 0.5525 5525 11.05 0.776856 7768.56 15.53712 Nitrate Nitrogen 0.016499 164.99 0.32998 0.023199 231.9882 0,463976 Incorporated Available Nitrogen Estimate 0.366 3660 7.32 0.514623 5146.232 10.29246 Surface Available Nitrogen Estimate 0.363 3630 7.26 0.510405 5104.049 10.2081 Phosphorus as P205 0.8305 8305 16.61 1.167745 11677.45 23.35489 Potassium as K20 0.2655 2655 5.31 0.373313 3733.127 7.466254 Calcium 22.0535 220535 441.07 31,00886 310088.6 620.1772 Magnesium 0.249 2490 4.98 0,350112 3501.125 7.00225 Sulfur 0.2205 2205 4.41 0,310039 3100.394 6.200787 Zinc 0.029301 293.01 0.58602 0,041199 411.9938 0.823988 Copper 0.006472 64.72 0.12944 0.0091 91.00112 0.182002 Manganese 0.009388 93.88 0.18776 0.0132 132.0022 0.264004 Sodium 0.048289 482.89 0.96578 0.067898 678.9792 1.357958 Calcium Carbonate Equivalency 0.475 4750 9.5 0.667885 6678.853 13.35771 November 2020 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM Facility Name: Permit Number: WQ0014248 WWTP Name: Town of Cheraw WWTP NPDES Number: SCO020249 Monitoring Period: From 01 /01 /20 To 12/31 /20 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Town of Cheraw Class A: Alternative 1 ❑ Alternative 2 ❑ Alternative 3 ❑ Alternative 40 Alternative 5 ® Alternative 6 ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray [31 Gamma Ray ❑ Pasteurization Class B: I Alternative I ❑ Alternative 2 ❑ 1 Alternative 3 ❑ If applicable to alternative performed (CIass B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Level in Qhiringa Pathogen Density Number o Excee- Frequency of Analysis Sample Type Analytical Tech-nique Minimurr Geo. Mean aximu Units Fecal Coliform 2 x 10 to the 6th power MPN per gram of total solids or 2 x 10 to the 6th power CFU per gram of 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Option 1 ❑ Option 2 ❑ 1 Option 3 ❑ 1 Option 4 ❑ Option 5 ❑ Option 6 ® Option 7 ❑ 1 Option 8 ❑ 10ption 9 ❑ 10ption 10 ❑ No vector attraction reduction were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ® "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Sherry Turner/Operator of Record Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) Signal re of Preparer Date Signature of Land Applier (if applicable) Author Daryl D. Merritt DENR FORM RF (7/2002) Date FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10-' dilution / 10 ml sample 10-' dilution / 1.0 ml sample — r- Single Strength 10'Z dilution / 1.0 ml sample Single Strength 10''- dilution / 0.1 ml sample Date/Time Test Set -Up: I— IS ao 11 iaa Date/ Time Test Read: Time Placed in Incubator: Incubator Temp: 3513s �-- Time Transferred to Water Bath: I L41-7 Operator /45 % Solids _ 4:)qI to Ck - Water Bath Temp: 4 r G Media Lot # : l U 6I ko 11 CA Sample# "�5'a0 —0L)O MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results 0 Biosolids Collection: Date — 5 ` Time Op. AS 35,TC 3� 1 a r�, . A-- cf 0. 5'C- FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids = A - B x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # �I — { `5 :p—U-4()0 0 Weight of dried residue + dish: Duplicate weight of dried residue + dish Weight of empty dish Weight of wet sample + dish 4 —7,DLI % Total Solids = � _ 5 9 .,(o /o Lo FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10'dilution 110 ml sample 10'dilution 1 1.0 ml sample Single Strength 10'2dilution; 1.0 ml sample Single Strength 10-2 dilution / 0.1 ml sample Date/Time Test Set -Up: 2, Time Placed in Incubator: Time Transferred to Water Bath: 3 �5 Operator : , ,'-wJ rs �- % Solids I 0�ll� Date/ Time Test Read: —,20 Incubator Temp: _ 3 , ` C- - Water Bath Temp: " C Media Lot # : C214 'a, Sample # - 9 -P,0 _04 D O MPN Fecal Coliform = 10 x MPN Index / 100 ml = 0 per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 9 - '�O Time Cg,;' s Op. _ A_�& FORMULA: Where: CALCULATION FOR TOTAL SOLIDS N BIOSOLIDS SAMPLE % Total Solids (A-B)x 100 C -B A Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C - Weight of wet sample + dish (mg) Sample # : ') -19 Weight of dried residue + dish: Duplicate weight of dried residue + dish : Weight of empty dish Weight of wet sample + dish : r2����3 a,Og5 �D -::�d.gL'-9.2- - % Total Solids = a , a� -�° X00 Mad FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-' dilution / 10 ml sample Single Strength 10-' dilution . 1.0 nil sample Single Strength 10-2 dilution / 1.0 ml sample Single Strength 10''- dilution ` 0.1 nil sample r r r, Date/Time Test Set -Up: 3 -I �- a2y / 1'100 Date/ Time Test Read: 11334- Time Placed in Incubator: I Ll Uc.) Incubator Temp: 35. a' C Time Transferred to Water Bath: -J C] Water Bath Temp: �C Operator G. Media Lot # : Qi % Solids , - D Sample # 3 - � � � . q 00 MPN Fecal Coliform = 10 x MPN Index / 100 nil - per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results . - C - ), Biosolids Collection: Date-_0-.X) Time JD JQ pp, _ 4_5 FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE °fo Total Solids = LA_-B)s 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : - 12 - - Q 4 Weight of dried residue + dish: Duplicate weight of dried residue + dish Weight of empty dish Weight of wet sample + dish : (Q % Total Solids = 5(v , 9 % J FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution/ 10 ml sample 10'' dilution ' 1.0 ml sample r r Single Strength 10'= dilution / I.0 ml sample Single Strength 10-2 dilution:-'O. I ml sample i Date/Time Test Set -Up: J S - - l t( Date! Time Test Read:- _1 is a al / gLf0. Time Placed in Incubator: LlIncubator Temp:. o C r O Time Transferred to Water Bath: j. Water Bath Temp: Ll< < S OperatorEA-1.c — Media Lot # I (C 0 (�gi % Solids CC), Lr� °A) Sample # q- 15 'o�C�- () NIPN Fecal Coliform - 10 x MPN Index / 100 ml = 0 per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results BiosolidsCollection: Date -15 -9C Time f 9- pp. J 5 FORMULA: Where: CALCULATION FOR TOTAL SOLIDS N BIOSOLIDS S_AN PLE % Total Solids (A-B)x100 C B A = NVeiaht of dried residue + dish (n2) B = Weight of empty- dish (mg) C = Weight of wet sample + dish (mg) Sample # :� 5 �_ L�`i✓'C� Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : %Total Solids = '--') 4 -7�� L� W 40 ,- Dp L 7C a7x FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution / 10 ml sample 10'1 dilution! 1.0 ml sample Single Strength Single Strength 10 dilution / 1 A ml sample 10'2 dilution 0.1 ml sample Date/Time Test Set-Up:S- -,-�D a, Date' Time Test Read: :5 -,2- 1 Time Placed in Incubator: � a Incubator Temp: 3 5, O Time Transferred to Water Bath: i $ Water Bath Temp: t-i L[ , 3 ' C Operator ] ,� Ie� S Media Lot # i CU O LI "?, % Solids G ��o Sample # : j- - c7 - L) MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date IS -,Ii-v1Q Time FORNTULA: Where: CALCULATION FOR TOTAL SOLIDS N BIOSOLIDS SAMPLE °,s Total Solids f A- B l x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample I : 5' 2U —ao _ C-> 0 C) Weight of dried residue + dish: Duplicate weight of dried residue dish: Weight of empty- dish Weight of wet sample + loch % Total Solids = � I . �, 0% a2 I • 7 .2- Y i a 7a-Lt v 7 i� G J FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10'1 dilution / 10 ml sample 10'dilution ' 1.0 ml sample Single Strength 10'2 dilution ,' 1.0 ml sample Single Strength I V dilution 10. I ml sample Date/Time Test Set -Up: & 17 -.2a / i I �{ Time Placed in Incubator: Time Transferred to Water Bath: I Ll ; 3r Operator P w l S % Solids Date/ Time Test Read: L, - I --'2G / 1 i -2 5 Incubator Temp: 3 5 . 3 OL Water Bath Temp: L[ 1-1 1 � GC - Media Lot # cc, / CIy a Li 6 L+ 2 Sample # G - 1-7 -)-C) ` u LID() TMTN Fecal Coliform = 10 x MPN Index / 100 ml - per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date , - - U Time C) �' ,�� Op. _ _ t V'�s FORbvfnA: Where: CALCULATION FOR TOTAL SOLIDS I\r SIOSOLIDS SAMPLE °ro Total Solids - ( A - B) s l00 C -B A = Weight of dried residue + dish (ma) B = Weight of empty- dish (mg) C = Weight of wet sample + dish (ma) Sample I : � — 1-7 _ ) v — U L! � . Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : `1 1 �� 9j 3 3 �;� % Total Solids = f �� ` _ _ 4), 0 FECAL COLIFORI&I FOR MUNICIPAL B[OSOLIDS A- I Medium Double Strength Single Strength 10" dilution 1 10 n-1 sample 10` dilution 1.0 ml sample 1 r Single Strength I 0''- dilution; 1.0 ml sample Single Strength 10'= dilution ! 0.1 ml sample Date/Time Test Set-Up:'7-! 5'��'� Time Placed in Incubator: _C i 5 Time Transferred to Water Bath: 15u Operator % Solids Date' Time Test Read: 7-1 !, lo to Incubator Temp: Water Bath Temp: Z-1 ``I Media Lot C) co Sample MPN Fecal Coli%rm = 10 x MPN Index / 100 ml per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results t Biosolids Collection: Date - { Time tJ pp. f FORMULA: Where: CALCULATION FOR TOTAL SOLIDS N B[OSOLIDS SAMPLE % Total Solids (A-B )x 100 C B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (me) Sample 4i - ^7 ` 15 `;�c) - U'# (DO Weight of dried residue T dish: Duplicate Weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish % Total Solids 3LI, 33;S �' 6 P KZ jg�- ri�ERIC lk S C (lr c c F C �C t f Z S k (2,C) FECAL COLIFORNI FOR MUNICIPAL BIOSOLIDS A- I Medium Double Strength 10"1 dilution ; 10 ml sample Single Strength 10-' dilution ' 1.0 ml sample 1 — r Single Strength Single Strength 10-2 dilution / 1.0 ml sample 10-2 dilution 0.1 ml sample Date/Time Test Set-Up:3-1 .go L3 Time Placed in Incubator: 3 3 Time Transferred to Water Bath: 3 Operator °fo Solids MPN Fecal Coliform per Gram Total Solids Date.' Time Test Read: S - � -,20 / 13.23 Incubator Temp: 3 s . 3 `'C Water Bath Temp: Media Lot # ')uYYV� a Sample#-a-Dy()J 7�-- 10 x NIPN Index- / 100 mI = y Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date Time Op. _ 5 FORNMA: Where: _ s CALCULATION FOR TOTAL SOLIDS FN B10SOL[DS SAMPLE °oTotal Solids = (A-B)xl°; C -B A = N'Veight of dried residue -- dish �mg) B= Weight Of emptti- dish (MI-1) C = Weight of wet sample - di:h (mg') Sampler :- 19 - g(�-- 0 y Weizht of dried residue - dish: I 1 G Duplicate weight of dried residue - dish: � L Weight of empty dish' U 5 Weiaht of vet sample + dish �.4 Total Solids f�--3cu)ce ]Cyan �C�1 Z•5 1�L� 0 FECAL COLIFORM FOR MUNICIPAL. BIOSOLIDS A-1 Medium Double Strength Single Strength 10'' dilution ! 10 ml sample 10-' dilution 1.0 ml sample Single Strength 10-2 dilution / 1.0 ml sample Sin0e Strength 10'2 dilution 0.1 m1 sample Date., -'Time Test Set -Up q-k- jj I t7 Time Placed in Incubator: �I � Q J Date.: Time Test Read:la �1p Incubator Temp: » ; 5 Time Transferred to Water Bath: JA 3 - Water Bath Temp: q 9.5,7 C, Operator : Media Lot # 1 M CUe3 55 %Solids 53,Lo u/v Sample 0 ,- NIPN Fecal Coliform — 10 x MPN Index / 100 nil = per Gram Total Solids Largest Volume x % Dry Solids NOTE: - indicates positive results; -indicates negative results r r. _ Biosolids Collection: Date Time C)�_9D Op. �C �� C. Tr . L[L{,5'(— 0 FORMULA: Where: CALCUL.-kTION FOR TOTAL SOLIDS Ili BIOSOLIDS S AMPLE ° n Total Solids = 4 A - B ) x 100 C -B A = Weicht of dried resido_ — (mg dish (mg f B = Weight of empty dish (wig) C = Weight of wet sample — dL-h (mg) Sampler: 99LS7D-0If�� 'F p, Weight of dried residue - dish: r ! t' Duplicate weight of dried residue — dish: Weight of empty dish Weight of wet sample -�- dish % Total Solids c. 'i�1. C� r .� C r a C CLc'1 �C ° �1� C f �I 1 +•-� Q� t m .. FECAL COLIFORM FOR 1NVICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10'r dilution 1 10 m1 sample I0-' dilution 1.0 - sample Single Strength 10'= dilution 1.0 ml sample r Date/Time Test Set -Up: It)- I �Itao Time Placed in Incubator: _LL,a&} Time Transferred to G�'ater Bath: 1 L f ,Z C, Single Strength 1 V dilution 0.1 tnl sample r Dateei Time Test Read: L _d_L-2�1101 Incubator Temp: 3 :;, 4' C Water Bath Temp: L I Ll , 5L Operator w Media Lot n Solids _ [V L- , 3 %u Sample L MPN Fecal Coliform - 10 x IVIPN Index / 100 ml V per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date Time Op. 2 -- 5,1 LIB{. 5'�- CALCUL:,,TIONi FOR TOTAL SO DS rN BIOSOLIDS S -%-NIPLB FORMULA: ° o Total Solids -- A- B 1 N 101) C -B Where: - Weight of dried residue - dvh ? M! ) B - Weight of empty dish (mg) C = �'eiaht of vvet sample - dish I nu i Sample-.-': - D- L) Weizht of dried residue - dish: Duplicate wei-ght of dried residue . dish: Weight of empty dish Weight of,,vet sample - dish 4o Total Solids y 7C'03 pC'f'-7Ul.}3 cD C CL r-) 1 U Y lid 4 l Z-SA Q-0 yfi [a] FECAL COLIFORNI FOR NfU,\rTCIP_kL 1310SOLIDS A-1 Medium Date.gime Test Set -Up: I - J $ -2C� Date.' Time Test Read: 1 Time PIaced in Incubator: I j v L incubator Temp: Time Transferred to Water Bath: i (a Water Bath Temp: L1 LI , S" C_ Operator `� ,� 1 tSlS __ Media Lot # Cv 1 6 3 L155 Rio SolldS Sample T - 1& -?G - tl (�G NIPN Fecal Coliform = 10 x MPN Index i 100 mI = per Gram Total Solids Largest Volume x ONO Dry Solids NOTE: indicates positive results ; - indicates negative results 0 Biosoiids Collection: Date I I - is- Time 12 17 .�► � is _ Op. �2 ..x , 3rc.- n L4 L1, 5 0 FORMULA: Where: CALCULATION FOR TOTAL SOLIDS EN B10S01 iDS SAMPLE o Total Solids �A -BIxUK C -B A = Weight of dried residue — dish (mg) B 1,Veiaht of empty dish (Mal C W-eight of wet sample — d-i:h (mg) fr i i C �J - G LI Sample Oc� v Weitrht of dried residue - dish: Duplicate weight of dried residue -;- dish: Weiahht of emptti- dish weiaht of tivet sample . dish : % Total Solids = � 5 � ;� �5 LI cj a)e c�ber1 ��C�i� C E `� 'y Q nT-e C �� z-SA l LLB Ll S FECAL COLIFORM FOR 1MILIIICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilutioa 10 ml sample 10'' dilution LO ml sample Single Strength I0 2 dilution 1.0 m1 sample Single Strength 10" dilution 0.1 ml sample Date Time Test Set -Up: 11-1L�) 13C)l Date Time Test Read: 1 -17 -,2LJ / 131c-) Time Placed in Incubator: ( 0 ( Incubator Temp:�C- Time Transferred to Water Bath: 0 Water Bath Temp: '--f Li C'6' Operator V'�YS NMedia Lot A I7 ' .L' R 6 �r � 5 5` % Solids �, o •���, /� � Sampler MPN Fecal Coliform 10 x l IPN Index / 100 rnl per Gram Total Solids Largest Volume x °o Dry, Solids NOTE: � indicates positive results; -indicates negative results Biosolids Collection: Date 19") L- --le— � Tune I2c i S pp, �c ' 35. 1 1 A 1 1,f a A Or CUCL"LATI0 FOR TOT.-kL. SOLIDS i\4 BIOSOLIDS SAMPLE FORMULA: 0 o Total Solids = ! '. - B) 1+_�� C -B A = "Weight of dried resid-l_ - dija (u1_�) B -'Weight of eM 0 , dish (mg. C = iejRht of wet s,,-uple -- dish (r-L7I mpler : Lf �:- Sa Nt, 62ht of dried residue - dish: Duplicate v e iaht of dried residue + dish Weight of empty dish .� eisht of wtt sample + dish j C) G� % Total Solids