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WQ0031725_Residual Annual Report 2020_20210225
Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* W00031725 Applicant/Permittee Baxter Healthcare Corporation Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office Asheville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Rease provide information on the person to be contacted by N B Staff regarding electibnittal, confirmation of receipt, other .......................................................... electronic surece, aner correspondence. _ - Name * Corey Carpentier Email Address* corey_carpentier@baxter.com Project Information ........ ......... ............................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 8287566636 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 IT Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0031725 Has Current Existing perm number Applicant/Permittee Address* 65 Pitts Station Road Facility Name * Baxter Healthcare Corporation RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for Land Application of WWTP Sludge Residuals At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Rans, Specifications, Calculations, Rc.) 2020 Annual Sludge Report WQ0031725.pdf 1.35MB Upload only 1 FLFdocurrent (less than 250 fvt3). Miltiple documents rust be contained into one FDFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Cot'e� ca�Pe�►ret' Submission Date 2/25/2021 2020 Baxter Healthcare Corporation 2020 Annual Report Land Application Program Permit No. WQ0031725 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0031725 County: McDowell Year: 2020 Facility Name (as shown on permit): Baxter Healthcare Corporation Land Application Operator: US Biosolids, Inc. Phone: 336-957-7871 Land application of residuals as allowed by the permit occurred during the past calendar year? a Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals ADDHC860n Summarr. Total number of application fields in thepermit: 10 Total number of fields utilized for land application during the year: 9 Total amount of dry tons applied during the year for all application sites: 149.68 Total number of acres utilizes for land application during the year: 68.8 Part B - Annual Compiance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Resources. © Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .l 105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T .1 1 I 1 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the pen -nit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. l 1) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "1 certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." -J Go 17 J ` Vv E2t3Cct; /�srr- �A-Ec l or?— Permittee Name and Title (type or print) Sianatuof 267-fi Signature of Pe ittee Date 2-let � Zi 8, 1 , T Date 5 gnature of _and Applier I -as Date (if different from Penmittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and I SA NCAC 02T .1102 (26) DENR FORM ACF (12t2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0031725 Laboratory: 1) Facility Name: Baxter Healthcare Corporation 2) Residual Source WQ # or WQ0031725 3) NPDES #: 4) WWTP Name: Baxter Healthcare Corporation 5) Residual Analvsis Data Statesville Analytical Parameter Conc. Limit m a Sample or C mposite Date 1-23-20 Percent Solids (%) NA 12.7 Arsenic 75 3.7 Cadmium 85 0.54 Copper 4,300 80.6 Chromium NA NA Lead 840 3.071 Mercury 57 0.126 Molybdenum 75 5.04 Nickel 420 11.18 Selenium 100 3.7 Zinc 7,500 8 4. 3) Total Phosphorus NA 2677 TKN NA 86866 Ammonia -Nitrogen NA 20107 Nitrate and Nitrite NA 66.9 "For surface disposal facilities the ceiling concentration limits listed in this form are not applicable Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." J i¢nature Pren r * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26) DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0031725 Facility Name: Baxter Healthcare Corporation Residual Source WQ0031725 NPDES # or WQV: WWTP Name: Baxter Healthcare Corporation Residual Analvsis Data Laboratory: 1) Statesville Analytical 2) 3) 4) 5) Parameter Sample or Composite Date ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature 6f Prepare" *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26) Date DENR FORM RSSF - B (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 10.70 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Acres Used: 5.5 Acres Permitted: 5.5 Site #: Predominant Soil Series: FCC2 DP Field #: 1A Residugl Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Annual Heavy Metal Field Loadings (Calculated in Ibslacre): Total Annual Heavy Metal Field Loadings (Calculated in Ibslacre): Total 11 - 2 3t 41 5 6 7 8 91 10 11I 12 tl U!"Ac. App. v Event 1.95 Arsenic 0,014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.314 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.314 Chromium #4#### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 denum Nickel 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 0.328 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.328 Total Phos- 10.419 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.419 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 1-f h_ Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "NIA" 1N A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation Land Owner. Douglas Poplin Operator: Douglas Poplin Crop I Name: Fescue WQ Permit #: WQ0031725 Annual Dry Tons Applied: 10.7020 Predominant Soil Series: FeC2 Field #: 1A Acres Utilized: 5.5 Site #: DP Acres Permitted: 5.5 Cation Exchange Capacity (non 503): Crop 1 Max. PAN: 158 Crop 2 Name: Crop 2 Max. PAN: = ca c � VL.olume applied ( eater one) Solids/ Liquid Cu. Yds Gallons o /o Solids Volume A tied r PP ie per Acre (Dry TansrAc) Residual Sources (NP0F.S C H Q#. Fert.. Animal Waste, etc) Soil Cond. (Dry. wet. Moist) Precip past 24 Hrs. inches � �• z E � j• a = rt W K - o. 3 n ;, L ti . ,� 1'K'�i -P9 z a o 2 ,ro m mgr+�9 Nitrate and Nitrite m91k9 PAN Applied t lWacre) Name of Crop TyPC ReceivingResidual Application Crop 1 Crop 2 Crap 1 Crop 2 8-2020 100.06 12.7 1.946 W00031725 dry 0 1 s 0.5 0.3 1 86W 20107 1 66.9 117 326 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 100.061 0 As Cd Cu Cr Pb Hg Mo Ni Se I Zn P 117.326 0.000 Lime Aimlied Annuallbs/acre 0.014 0.002 0.314 4#114### 0.012 0.000 0.020 0.044 0.014 0.328 10.419 Date lbs/ac Prior Years Cumulative lbs/ac 0.199 0.055 3.259 2.384 0.064 0.011 0.15 0.787 0.128 4.959 0 Current Cumulative lbs/ac 0.213 0.057 3.573 ####### 0.076 0.011 0.170 0.831 0 142 5.287 Permitted C. P. L. R.**** 36 1 34 1 1338 1 NA 267 15 NA 374 89 2498 Permit PAN Limit Ist/2nd Crop 158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 *** Mineralization Rates: Compost -0.1, anserobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation _Total Dry Tons Applied (Annual): 3.12 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 Acres Used: 1.6 Acres Permitted: 1.6 Site #: DP Field #: 1B Residual Analysis Data (Heavy Metals and Total Phosphorus use mgtkg, % Solids use Raw Percent #): 4amnle or . 2 3 4 5J 6 7 8 9 10 11 12 Com- posite Date 1 `23 :20 0o Solids 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 1.'hrorniurn NA Lead 3.071 Mercury 0.126 Molyb- 504 denum Nickel 11.18 Selenium 3.7 zinc 84.3 Total Phos- 2677 A.,.,. A Hanary Matal l ipid Il -na.linae !C'alenlated in Ihslacrel: Total 1 2 3 4 5 6 7 8 9 1t} 11 12 DT Ac.l ° App. w 14 Event 1.95 Arsenic 1 0.014 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.315 0.000 0.000 0A00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.315 Chromium 4##### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4##### Lead 0.012 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.012 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 enunt Nickel 0.044 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 0.329 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.329 Total Phos- 10.451 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.451 horus 1.1 certify, under penalty of taw, teat tn13 document was preparea under my alrectlon or supervision In accoraance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "NIA" 1N A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit #: WQ0031725 Field #: Land Owner: Douglas Poplin Annual Dry Tons Applied: 3.1231 Site Operator: Douglas Poplin Crop I Name: Fescue Predominant Soil Series: FcC2 Crop 1 Max. PAN: 158 Crop 2 dame: I Acres Utilized: DP Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 1:.6 1.6 Volume applied Volume Residual Sources Soil Preci p• a ¢ �' -Z > - 3 Nitrate PAN Applied Name of Crop Type (enter one) Solids/ % Applied per (NPDES #. WQ#, Fond Past 24 R ' z = R TKN +3 3 and (Ibslacre} Recervmg Residual o Liquid Solids Acre Fert.. Animal (Dq. Wet.inches lirs. P. R Nitrite Application Crop I Crop 2 Cmp I Crop 2 Cu. Yds Gallons (Dry TonslAc) Waste, etc) Moist) ' `_ mglkg mgrkg mgncg 5-2020 29.2 12.7 1.952 WQ0031725 dry 0 s 05 03 86866 20107 669 117.695 NA Fescue 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 o.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 Residuals Applications totals on FORM FSF supp { attach FORM FSF supp to this form): TOTALS 2921 0 As Cd Cu Cr Pb H& Mo Ni Se Zn I P 117.6951 0.000 Lime Applied Annual Ibs/acre 0.014 0 002 0.315 ####### 0.012 0.000 0.020 0.044 0.014 0.329 10.451 Date lbs/ac Prior Years Cumulative lbs/ac 0.196 0.053 3.106 2.245 0.265 0.01 l 0.143 0.742 0.124 4.631 0 Current Cumulative Ibs/ac 0.210 0.055 3.421 ####### 0.277 0.011 0.163 0.786 0,139 4.960 Permitted C. P. L. R.**** 36 34 1338 NA 267 l5 NA 374 89 2498 Permit PAN Limit IsU2nd Crop 158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1-.74-.;N1 f -Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loadine Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 5.83 Permit If: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 Acres Used: 3 Acres Permitted: 3 Site #: DP I Field #: IC Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date 1 `23.20 % Solids 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 Chromiur6 NA Lead 3.071 Mercury 0.126 Molyb- 5.04 num Nickel 11.18 Selenium 3.7 Zinc 84.3 Total Phos- 1 2677 Annual Heavy Metal Total DT!Ac J App Event 1.94 Field Loadings (Calculated 2' 3 45� in lbs/acre): 6 7 8 9! 10 11 12 0 as Arsenic 0.014 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.313 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.313 Chromium ###### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 denum Nickel 0.043 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.043 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 line 0.328 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.328 Total 1 Phos- 10.403 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.403 "l certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". t Si naure of Land A tier �. PP Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit #: WQ0031725 Field #: IC Land Owner: Douglas Poplin Annual Dry Tons Applied: 5.829E Site #: DP Acres Utilized: 3 Acres Permitted: 3 Operator: Douglas Poplin Predominant Soil Series: FcC2 Cation Exchange Capacity (non 503): Crop 1 Name: Fescue Crop I Max. PAN: 158 Crop 2 Name: Crop 2 Max. PAN: Volume applied Volume Residual Sources Soil Preci p > o 9 ? .- Nitrate , PAN Applied Name ol'Crop f 5pe = {toter one) Solids/ o �u Applied per (NPI)ES N. N4Q#. Cond. Past 24 z i` m = m n m'_ TKN o3 a fm and ( Ibslacre) Receiving Residual V Liquid Solids Acre Fen.. Animal t1)r3`• n' m ry ; = w -L _ a s iv NilClle Application Cu Yds Gallons (Dry TenwAc) Waste. etch Wet,Hrs. Moist) inches . 3 mgtkg mg/kg mglkg Crap 1 Crop 2 Crop I Crop 2 5-2020 453 12.7 1.615 WQ0031725 dry 0 0.5 03 86866 20107 66..9 97.381 NA Fescue 6-2020 9.2 12.7 0.328 WQ0031725 dry 0 r 0.5 0.3 86866 20107 66.9 19.777 NA Fescue 0.000 0 000 0 000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0 000 0.000 Residuals Applications totals on FORM FSF supp { attack FORM FSF supp to this form): TOTALS: >4.5 0 As Cd Cu Cr Pb H Mo Ni Se Zn P 117.158 0.000 Lime A lied Annual Ibslacre 0.014 0.002 0 313 ####### 0,012 0 000 0.020 0.043 0.014 0.329 10.403 Date Ibslac Prior Years Cumulative ibs/ac 0.778 0.067 3.79 2.634 0.317 0.013 0.168 0.887 0.144 6.057 12-2020 1000 Current Cumulative lbs/ac 0.792 0.069 4.103 ####### 0.329 0.013 o.188 0.930 0 158 6.385 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 374 1 89 2499 Permit PAN Limit Ist/2nd Crop 158 "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a Sy'lehhh Ur-a,gncu .,, a0001 � •••a• qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation i�•�� S **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, annerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 17.86 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 Acres Used: 9.6 Acres Permitted: 9.6 Site #: DP Field #: 1D Residual Analvsis Data (Heave Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite rotal Phos- phorusMENEENEENEEN Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1.1 _2j 3 4 5j 6 7 8 9 t0 �t 12 APp• y Event 1.86 ' Arsenic 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.300 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.300 Chromium ######1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.019 0.000 0.000 0.000 0-000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 denum Nickel 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 0.314 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.314 Total Phos- 9.958 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9.958 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". -7 Signature of Lan Applier Date DENR FORM MFLSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: Baxter Healthcare Corporation Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name. Fescue PLACE A "NIA" 1N A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0031725 Field #: 1D Annual Dry Tons Applied: 17.9584 Site #: DIP Predominant Soil Series: FeC2 Crop 1 Max. PAN: 158 Crop 2 Name: Acres Utilized: 9.6 Acres Permitted: 9.6 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: G Y o 0 Volume applied (enter one) Solids/ liquid Cu. Yds Gallons % Solids Volume Applied prr Acn (Dry ronsift) Residual Sources (NPI)F.S #. WQ#- I crl.. Animal Wasfe. etc) Soil Cond. (Dry, Wei Moisl) Precip. Pasi 24 Hrs. inches > �' a 3 n 'a c C °= „ J > x n " :� R > TKN n)Wkg z 3 o ' ry 3 p mglkg Nitrate and Nitrite mglkg PAN Applied ( lbs/acre) Name ofCroP rYPc Receivina Residual Applicaron Crop 1 Crop 2 : rop l Crop 2 5-2020 66.41 12.7 0.740 WQ0031725 dry 0 s 0.5 03 96966 20107 66.9 44.613 NA fescue 8-2020 100.56 12.7 1.120 WQ0031725 dr% 0 s 0.5 0.3 86966 20107 66.9 67 554 NA Fescue 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp (attach FORM FSF supp to this form): TOTALS 16697 o As Cd Cu Cr Pb N Mo Ni Se Zn P 112 166 0,000 Lime Applied Annual lbs/acre 0.014 0 002 0.300 ####### 0.011 0.000 0 019 0 042 0 014 0.314 9.958 Date Ibs/ac Prior Years Cumulative lbs/ac 0.192 0.051 3.041 2.209 0.284 0.009 0.139 0.714 0,108 4.394 12-2020 2000 Current Cumulative lbslac 0.206 0,053 3.341 ####### 0.295 0.009 0.158 0756 0.122 4.708 Permitted C. P. L. R.**** 36 34 1338 1 NA 267 15 NA 374 89 2498 Permit PAN Limit Ist/2nd Crop F 158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, 1N - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, injection/Incorporation - 1.0 Signature of Land Applier Date **" Mineralization Rates: Compost -0.1, anserobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ""C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 20.76 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 Acres Used: 5.887 Acres Permitted: 5.887 Site #: DP Field #: 3-Corn Residual Analysis Data (Heavy Metals and Total Phosphorus use mgtkg, % Solids use Raw Percent #): Sample or 1 2 3 4 5 6 7 8 9 10 11 12 Com- posite Date 1!21`20 % Solids 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 Chromium NA Lead 3.071 Mercury 0.126 Molyb- 5.04 enum Nickel 11.18 Selenium 3.7 Zinc 84.3 Total Phos- 2677 Annual Heavy Metal Field Loadings (Calculated in Ibslacre): Total 1 2 3 4 5 6 S 9 10 11 12 D'r/Ac . 0 m A pp Event 3.53 Arsenic 0.026 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.026 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.569 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.569 Chromium ######1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00o 0.000 0.000 0.000 ###### j Lead 0.022 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 den -um Nickel 0.079 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.079 Selenium 1 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Z.tnc 0.595 0 000 0.000 0.000 0.000 0.000 0.000 0.o00 0.000 0.000 0.000 0.000 0.595 Total Phos- 18.884 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0ao 18.s84 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". .w• Sig mature of Land Appiier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" 1N A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit #: WQ0031725 Field #: 3-Corn Acres Utilized: 5.887 Land Owner: Douglas Poplin Annual Dry Tons Applied: 20.7634 Site #: DP Acres Permitted: 5.887 Operator: Douglas Poplin Predominant Soil Series: FCB2 Cation Exchange Capacity (non 503): Crop I Name: Corn Crop I Max. PAN: 214 Crop 2 Name: Crop 2 Max. PAN: `o Volume applied Volume Residual Sources Soil Cond. Precip• > < _ K z - Nitratc PAN Applied PP Name ofCrop 'fype Rccerving Residual (enter one} Solids! o/, Applied per (NPDES tt, WQ#, (Dn. i'tisE 24 = 51 � �+ _= a °�_- i'KN "0 and ( Ibs/acrL) Application y «- o 0 1.i uid A Solids Acre 1 c rt., Animal Wet' Firs. o F ' + V = 3. Nitrite PP Cu. Yds Gallons (DryTons/Ac) Waste. etc) Moist) '�h� o mgikg kg mglkg Crop 1 Crop 2 Crop 1 Crop 2 3-2020 194.13 12.7 3.527 WQ0031725 dr) 0 s 0.5 03 86M6 20107 1 669 212.664 NA Corn 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 i 0 000 0.000 0 000 0.000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0,000 0 000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 :T Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this formy At.S. 194.13 0 As Cd Cu Cr Pb H Mo Ni Se Zn P 212.664 0.000 Lime A lied Annual lbs/acre 0.026 0.004 0.569 0090 0.022 0.001 0.036 0.079 0.026 0.595 18,884 1 Date lbs/ac Prior Years Cumulative Ibs/ac 0.456 0.133 2.236 5.43 0.657 0.023 0.311 1.644 0.602 13.848 12-2020 1000 Current Cumulative lbs/ac 0.482 0.137 2.805 #000 0.679 0.024 0.347 1.723 0.628 14.443 Permitted C. P. L. R.**** 36 34 1 1338 NA 1 267 15 NA 374 1 89 2498 Permit PAN Limit 1 st/2nd Crop 214 " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC- Incorporation 1 ;6-P I **Volatilization Rate: Surface - 0.5, Injection/incorporation - 1.0 rrr *** Mineralization Rates; Compost -0.1, anserobially digested -0.2, Signature of Land Applier Date aerobically digested -0.3, raw sludge -0.4 ""*"C.P.L.R.: Cumulative Pollutant Loadine Rate DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 21.75 Permit #: W00031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: Fc82 Acres Used- 6.983 Acres Permitted: 6.983 Site #: DP Field #: 3-Grass Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent): Sample or 1 2j 1 3 4 5 61 11 8 9 10 11 12 Com- posite Date 1123/20 % Solids 1 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 Chromiuml NA Lead 3.071 Mercury 0.126 Molyb- 5.04 num Nickel 11.18 Selenium 3.7 Zinc 84.3 Total Phos- 2677 horus Annual Heavy Metal Field Loadings (Calculated in Ibslacre): Total 1 2 3 4 ; 53 6 7 $ , 91 Lo 11 12 UrAc. r m App w Event 3.12 Arsenic 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 0.502 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.502 Chromiurn #4#### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 1 0.001 Molyb- 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 enum Nicke; 1 0.070 0.000 1 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0,000 0.070 Selenium 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.023 Zinc 0.525 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0-000 0.000 1 0.525 Total Phos- 16.678 0.000 0.000 o.o00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 16.678 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit #: WQ0031725 Field #: 3-Grass Land Owner: Douglas Poplin Annual Dry Tons Applied: 21.7527 Site #: DP Operator: Douglas Poplin Crop 1 Name: Fescue Predominant Soil Series: FcB2 Crop l Max. PAN: 194 Crop 2 Name: Acres Utilized: 6.983 Acres Permitted: 6.983 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: � _ C Volume applied (enter one) Solids/ Liquid Cu. Yds. Gallons Cu. % Solids Volume Applied per Acre {DryTonslAc) Residual Sources (NPDES #. WQ#. Fert.. Animal Waste. inc) Soil Cond. (Dry Wet- Moist} Pircip Past 24 Hrs. > r � c _ * ' t m = `3 3 x R ; ° TKN mglkg Z D .� � r o o U' niWkg Nitrate and Nitrite �9 PAN Applied (1b aL } Name of Crop Type Receiving Residual Application Crop I P Crop 2 P Crop 1 P Crop 2 P 2-2020 106.6 12.7 1.633 WQ0031725 di) 0 s 0.5 0.3 86866 20107 66.9 98.449 NA Fescue 3-2020 26.13 12.7 0.400 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 24.132 NA Fescue 11-2020 70.65 12.7 1.082 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 65.248 NA Fescue 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0.000 O.000 0.000 0 000 0.000 0.000 0 000 0.000 0.000 0.000 0 000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0 000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS 20= 0 As Cd Cu I Cr Pb Hg Mo Ni Se Zn P 187.8281 0.000 Lime Applied Annual Ibs/acre 0.023 0.003 0.502 ####### 0.019 0.001 0,031 0 070 0 023 0.525 16.678 Date Ibs/ac Prior Years Cumulative lbs/ac 0.451 0.138 7.668 5.441 0.657 0.023 0.323 1.656 0.617 13.91 0 Current Cumulative lbs/ac 0.474 0.141 8.170 ####### 0A76 0.024 0.354 1.726 0.640 14.435 Permitted C. P. L. R.**** 36 1 34 1338 NA 267 15 NA 374 89 2498 Permit PAN Limit 1st/2nd Crop F 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation a-1bi**Volatilization Rate: Surface-0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DEN FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 19.86 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcB2 Acres Used: 8.7 Acres Permitted: 8.7 Site #: DP Field #: 4 Recidwgl Analvsic Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date BIT 1 . Phos- 1 1 rusiMEMENNEENEEN Annual Heavv Metal Field Loadings (Calculated in Ibslacre): Total 2 _3j 4 v 5 _6j 7j 8 __9,1 10 ill 12 DT/Ac.' App. m Event 2.28 Arsenic 0.017 0.000 0.000 0.000 1 0.000 0.000 0.000 0-000 0.000 0.000 0.000 0.000 1 0.017 Cadmium 0.002 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.368 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.368 Chromium ###### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Moiyb- 0.023 0.000 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0.023 denum Nickel 1 0.051 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.051 Selenium 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Zinc 0.385 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.385 "iota i Phos- 12.223 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 12.223 horus "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Ladd Applier Date DENR FORM MFLSF (1212006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OFTHIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit #: WQ0031725 Field #: 4 Land Owner: Douglas Poplin Annual Dry Tons Applied: 19.8617 Site #: DP Operator: Douglas Poplin Crop I Name: Fescue Predominant Soil Series: FcB2 Crop 1 Max. PAN: 194 Crop 2 Name: Acres Utilized: 8.7 Acres Permitted: 8.7 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: o f .2 o Q Volume applied enter one Solids! ( ) . liquid Cu. Yds Gallons /o Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #. WQ#. I�ert.. Animal Waste. etc) Sad Cond. (Dry. Wet Moist) 11recip. Nast 24 11rs. Ino es a 9 b n � k- as ^ x ' t= _ �, 3 9 R � :.,^ TKN mg*g z o 3 �? � - mglkg Nitrate and Nitrite nv'kg PAN Applied ( Ibs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crap 1 Crop 2 1-2020 51.3 12.7 0.631 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 38.027 NA Fescue 2-2020 81.6 12.7 1.003 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 60.488 NA Fescue 9-2020 52.8 12.7 0.649 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 39.139 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 .000 0.000 .000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): a TOTALS 185.7 0 As Cd Cu Cr Pb H Mo Ni Se Zn P .000 Lime Applied Annual Ibs/acre 0.017 0.344 0.361 36 0.002 0.1 0.102 34 0.368 5.579 5.947 k 133$ ####### 4.083 ####### 1 NA 0 014 0.469 0.483 267 0.001 0-017 0.019 15 0.023 0.238 0.261 NA 0 051 1.335 1.386 1 374 0.017 0.179 0.196 89 0 385 10.096 10.481 1 2498 12.223 Date Ibs/ac Prior Years Cumulative Ibs/ac 0 Current Cumulative Ibs/ac Permitted C. P. L. R.**** Permit PAN Limit lst/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation .�•)p 2 j **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loadine Rate DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 31.01 Permit 4: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 Acres Used: 15.9 Acres Permitted: 15.9 Site #t: DP Field #: 5 Residual Analysis Data (Heavy Metals and Total Phosphorus use mglkg, % Solids use Raw Percent #}: a Q 10 11 12 Corm polite Date 1.23 20 °o Solids 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 :hromiurn NA Lead 3.071 Mercury 0.126 Molyb- 5.04 denurn Mickel 11.18 Selenium 3.7 Zinc 84.3 Total Pros- 2677 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total I 1 2 3 4 5_ 6 7 8 9 10 11 12 DT-Ac.. e App. Event 1.95 Arsenic 0.014 1 0.000 1 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0-000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.002 Copper 0.314 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.314 Chromic ##00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 wall Lead 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.012 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 enu � Nickel 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 O.o00 0.000 0.044 Selenium 0.014 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 zinc 0.329 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.329 Total 1 Phos- 10.440 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.440 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 401%.• ' ---- _ j. }j•170 01 Si azure of Land -Applier-ierr Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON Facility Name: Baxter Healthcare Corporation Land Owner: Douglas Poplin Operator: Douglas Popl in Crop I Name: Fescue PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. WQ Permit #: WQ0031725 Field #: 5 Annual Dry Tons Applied: 31.0076 Site IN: DP Predominant Soil Series: FcC2 Crop I Max. PAN: 158 Crop 2 Name: Acres Utilized: 15.9 Acres Permitted: 15.9 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: c 0 a 4-2020 Volume applied (enter one) Solids,' Liquid Cu Yds Gallons 118.32 qo l ds 12.7 Volume Applied per Acre (Dry 7onsrAcl 0.796 Residual Sources (NPDIS #- WQ#. Fort.. Animal Wash. rtc l WQ0031725 Soil C and (Dn. Wet.c Moist) dr) Preeip Past 24 Hrs. � 0 > 3 3 � - * ' s c R � .>_ 0.5 K rt � �' * 3 0.3 TKN mglkg 96866 z 3 r c � m• mglkg 20107 Nstrate and Nitrite mglkg 66.9 PAN Applied t Ibs/acPe) Name of Crop 1'%.pe Receiving Residual App'ication ( rup I 47.991 Crop 2 NA Crop t Fescue Crop 2 7-2020 74.3 12.7 0.500 WQ0031725 dry 0 4 0.5 0.3 86866 20107 66.9 30.136 NA Fescue 11-202P 97.29 12.7 0.654 W00031725 dr) 0 , 0.5 0.3 86866 20107 66.9 39.461 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0-000 0.000 0.000 0.000 0.000 0.000 0 000 0.000 0.000 0 000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTAI % 289.91 0 As Cd Cu I Cr Pb Hg Mo Ni Se Zn P 1175871 0.000 Lime Applied Annuallbs/acre 0.014 0.002 0.314 ####### 0.012 0.000 0.020 0.044 0014 0.329 10.440 Date lbs/ac Prior Years Cumulative lbs/ac 0.289 0.083 4.589 3.222 0.405 0.015 0.195 1.097 0.135 8.499 12-2020 1000 Current Cumulative lbs/ac 0.302 0.095 4.903 ####### 0.417 0.015 0.215 1 141 0.149 8.829 Permitted C. P. L. R.**** 36 34 1338 NA 1 267 1 15 1 NA 374 1 89 2498 Permit PAN Limit I st/2nd Crop 158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier -'4L Date *Application Method: S - Surface, IN - Injection, INC - Incorporation **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 •** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, taw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 10.76 Permit #: WQ0031725 Cation Exchange Capacity (non 503 only): Operator: Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 Acres Used: 5.5 Acres Permitted: 5.5 Site #: DP Field #: 6 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or 2� 3 4 11 5! 6; 7 8 9 10 12 Com- posite Date 1123120 "o Solids 12.7 Arsenic 3.7 Cadmium 0.54 Copper 80.6 Chromium NA Lead 3.071 Mercury 0.126 Molyb. 5.04 denurn Mickel 11.18 Selenium 3.7 zinc 84.3 Total Phos- 2677 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Total 1 2 3 4 5 6 7 8 8 10 11 12 DT/Ac., App. Event 1.96 Arsenic 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 a.oa0 0.000 0.000 0.014 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.315 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.315 Chromium 4##### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.012 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.012 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 denum Nickel 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 0.330 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.330 Total Phos- 10.472 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 10.472 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "NIA" 1N A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation WQ Permit M WQ0031725 Field #: 6 Land Owner: Douglas Poplin Annual Dry Tons Applied: 10.7598 Site #: DP Operator: Douglas Poplin Crop 1 Name: Fescue Predominant Soil Series: FcC2 Crop 1 Max. PAN: 158 Crop 2 Name: Acres Utilized: 5.5 Acres Permitted: 5.5 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: ` 0 o o QLiquid Volume applied (enter one) Solids/ Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (Np[-)I:ti #. 1b'()#. Fert.. Animal Waste. etc) Soil Cond. (Dry. Wet Moist) Prrcip. Past 24 Hrs inches D = ^'. f y 3 o d °» g N I sa :3 1'KN z a o 3 rro 0 a �• ^�k9 Nitrate and Nitrite 9 PAN Applied ( lbs/acre) Name ol'Crop Type Receiving Residual Application Crop I I Crop 2 Cn)p 1 Crop 2 12-2020 100.6 12.7 1.956 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 117.9591 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS tOO.6 0 As Cd Cu Cr Pb H Mo Ni Se Zn P ! 17.959 0.000 Lime A lied Annual ibs/acre 0.014 0.002 0.315 ####### 0.012 0.000 0.020 0 044 0.014 0.330 10.472 Date Ibs/ac Prior Years Cumulative lbs/ac 0.383 0.11 6.222 4.506 0.566 0.017 0.253 1.26 0 153 11.627 0 Current Cumulative Ibs/ac 0.397 0.112 6.537 ####### 0.578 0.017 0.273 1.304 0.167 1 11.957 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 374 i 89 2498 Permit PAN Limit lst/2nd Crop I1513 " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Land Applier *Application Method: S - Surface, 1N - Injection, INC - Incorporation -74-20al **Volatilization Rate: Surface -0.5, Injection/Incorporation- 1.0 Date *** Mineralization Rates: Compost -0.1, snserobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Baxter Healthcare Corporation Total Dry Tons Applied (Annual): 8.02 WQ0031725 Cation Exchange Capacity (non 503 only): Douglas Poplin Owner: Douglas Poplin Predominant Soil Series: FcC2 4.4 Acres Permitted: 4.4 Site #: DP Field #: 7 Metalsand Total Phosphorus use inWka, % Solids use Raw Percent it): Com- posite WIN ®phorus_00MENNINEEMEM ----------- Total Phos- Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 8 4 v 5- 6 7 8 9 10 11 12 D'r ,Ac App. m y Event 1.82 Arsenic 0.013 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.013 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.294 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.294 Chromium ###### 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ###### Lead 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.011 Mercury 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 denurn Nickel 0.041 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.041 Selenium 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Zinc 0.307 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.307 Total Phos- 9.760 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9.760 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Slgttatttre of Land Appl+er Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "NIA" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Baxter Healthcare Corporation Land Owner: Douglas Poplin Operator: Douglas Poplin Crop 1 Name: Fescue WQ Permit #: WQ0031725 Field #: 7 Acres Utilized: 4.4 Annual Dry Tons Applied: 8.0228 Site #: DIP Acres Permitted: 4.4 Predominant Soil Series: FcC2 Crop 1 Max. PAN: 158 Crop 2 Name: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: L p w aU C Volumes lied PP (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (l]ryronsrAcl Residual Sources (NPDFS #. WQ#_ Fcrt.. Animal Waste. etc) S"'I Cond. ( Dry. s Moist) W Preel R• Past 24 IIr,. ;,,fig a S ? s �' 0 w " a c _ = r, -- + ;Z. � x R x+ � ` o TKN TngAg ? .. 3 S B "9t `_ 3 mg/kg Nitrate and Nitrite m9fk8 PAN Applied pP ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 10-2020 49.91 12.7 1.213 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 73.153 NA Fescue 12-2020 25.1 12.7 0.610 WQ0031725 dry 0 s 0.5 0.3 86866 20107 66.9 36.789 NA Fescue 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TUTAI.S. 75.011 0 As Cd Ctt Cr Pb I Hg Mo Ni Se Zn P 109,941 0.000 Lime Ai3viied Annuallbs/acre 0.013 0.002 0.294 ####### 0.011 0.000 0.018 0.041 0.013 0.307 9.760 Date Ibs/ac Prior Years Cumulative Ibs/ac 0.328 0.088 5.074 3.629 0.452 0.017 0.216 1.228 0.153 9.127 12-2020 1000 Current Cumulative lbs/ac 0.341 i 0.090 5.368 ####### 0.463 0.017 0.234 1.269 0.166 9.434 Permitted C. P. L. R.**** 36 34 1338 NA 267 15 NA 3-74 1 89 2498 Permit PAN Limit Ist/2nd Crop F 158 "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." I - of Land Applier *Application Method: S - Surface, IN - Injection, INC - Incorporation ;- a6il "Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3. raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loadin¢ Rate DENR FORM FSF (1212006) ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Baxter Healthcare Corporation WQ Permit Number: W00031725 WWTP Name: Baxter Healthcare Corporation NPDES Number: NC0006564 Monitoring Period: From Ul 2020 To 12/3112020 Pathogen Reduction (15A NCAC 02T .1106) -Please indicate level achieved and alternative performed: Class A: Alt. A (ttmeltem) ❑ Alt B (Alk Treatment)❑ Alt. C (Prior Testin )❑ Alt.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If a livable to alternative performed (Class A only) Indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ I Gainina Ray [1-1 Pasteurization ❑ Class B: Alt. (l} Fecal Density 21 Alt. (2) Process to Significantly Reduce Patho7ens ❑ If applicable to alternative performed (glass B onh•) indicate "Process to Significantly Reduce Path ens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ jAerobic Digestion ❑ Anaerobic Di estior. ❑ If applicable to alternative performed Class A or Class B) complete the followiI monitorin data: Aliowable Level Pathogen Density um er requency Sample Ana ytu Parameter Excee-f Analysis T a Tech - in Sludge Minimu Geo. Mean Maximu Units de YPniaue 2 x 10 to the MPN 1769 6th power per gram of Fecal Coliform total solids cFU I000 mpn per gram of total solid (dry Salmonella bacteria 3 MPN per 4 grams (in lieu of fecal total solid (dry coliform wei ht VnrFrnr Affenotinn Rminetinn t15A 1843.8 1 1949 1 MPN/g 1 0 7 1 grab I sm9221 ' 02T .11071 - Please indicate alternative performed: AIt.I (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) El Alt. 4 (Spec. O, uptake) Li Alt. 5 (14-Day Aerobic) Tit. 9 (Injection) ❑ ❑ Alt. 6 (Alk. Stabilization ❑ Alt. 10 (Incorporation) ❑ Alt 7 (Drying - Stable) ❑ Alt. 8 (Drying - Unstable) No vector attraction reduction alternatives were performed ❑ ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 21 "1 certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T. 1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." Li "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Dennis Key US Biosolids, Inc. Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) - � -11�- -NY 1 Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .I 102 (26) DENR FORM PVRF 02T (1212006) Analytical Results Southern Soil Builders 958 Hoots Road Roaring River, NC 28669 Receive Date: 01/23/2020 Reported: 03/02/2020 For: BAXTER Comments: STATESVILLE ANALYTICAL �, Sample Number (Parameter Sample ID Result Unit Method Analyzed Analyst 200123-31-01 Ammonia Nitrogen BAXTER 20107.1 mg/kg 6m"w"" 38r-1 ? 01/28/2020 WE 200123-31-01 Arsenic - Solid BAXTER <3.70 mg/kg SM31138.2004 02/03/2020 MT 200123-31-01 Calcium BAXTER 9750 mg/kg EPA 20D 7 01/3012020 MD 200123-31-01 Copper BAXTER 80.6 mg/kg EPA2D0.7 01/29/2020 MD 200123-31-01 Conosivity BAXTER See Attached sw-UG 01/24/2020 PACE 200123-31-01 Ignitability BAXTER See Attached 1010M 01/2412020 PACE 200123-31-01 Lead -Solid BAXTER 3.071 mg/kg SM3113B 01/31/2020 MD 200123-31-01 Magnesium BAXTER 2940 mg/kg EPA206.7 01/30/2020 MD 200123-31-01 Mercury Solid BAXTER 0.126 mg/kg sM3112&2011 02/05/2020 MD 200123-31-01 Nitrate/Nitrite - BAXTER 66.9291 mg/kg 5M4WQF1A 01/23/2020 CL Solids 200123-31-01 Percent Solids BAXTER 127 % SM25408.2077 01/27/2020 MD 200123-31-01 pH BAXTER 791 Std Units swwms-2011 01/23/2020 CL 200123-31-01 Potassium - Solid BAXTER 2420 mglkg EPAM.7 02/0312020 MT 200123-31-01 Reactivity BAXTER See Attached sw-s 01/2412020 PACE 200123-31-01 Selenium BAXTER <370 mg/kg EPA200.7 02/03/2020 MT 200123-31-01 Sodium - Solid BAXTER 222835 mg/kg SM 31118 01/29/2020 MD 200123-31-01 T. Phosphorus Solid BAXTER 2677 mg/kg SM45DWE-2011 01/31/2020 CL 200123-31-01 TCLP BAXTER See Attached iN01ed 01/24/2020 PACE 200123-31-01 TKN BAXTER 86866 1 mg/kg s'"''4S00'' n 8-201' 01129/2020 CL 200123-31-01 Total Solids BAXTER 154833 mg1L SiA 540.1"7 01/27/2020 MD 200123-31-01 Zinc BAXTER 843 mg/kg VAMI 01/29/2020 MD PO Box 228 • Statesville, NC 28687 •704/872/4697 Page 1 of 2 Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200123-31-01 Aluminum BAXTER 1130 rng/kg EPA 2W.? FWAA H" b1/30/2020 MD 200123-31-01 Cadmium ICP BAXTER 0.54 mg/kg EPA 2W7 01/30/2020 MD 200123-31-01 Molybdenum BAXTER 5.04 mg/kg EPA2W.i 01/30/2020 MD 200123-31-01 Nickel - Solid BAXTER 11.18 mg/kg SM313 a 01/29/2020 MD Respectfully submitted, :1. Y : rR- 0'. 1) .-)41 Dena Myers NC Cer# #440, NCDW Cert #37755, EPA #NC00909 P4 Box 228 it Statesville, NC 28687.704/872/4697 Pape 2 of 2 SAR Sodium Absorption Ratio Na: Sodium (MgIL) Equivalent weight: 23 Ca : Calcium (MgIL) Equivalent weight: 20 Mg : Magnesium (MgIL) Equivalent weight: 12 Milli Equivalent = MgIL / Equivalent weight Na M IL Ca M IL M M I 283 1 1238.25 1 373.38 Na (ME) 12 30435 Ca (MEI Mg (ME 31.115 61.9125 SAR= Na Milli Equivalent/(0.5 X (Ca Milli Equivalent + Mg Milli equivalent)]0 5 power SAR = 1.80413 (From MgIL entered above) SAR= 1.80376 (From ME entered below) Na (ME) Ca (ME) MgME, 123 61.9 31.1 The amour amount of e Permitting PAN Mineralization as decimal ITotal dry ton ear lAcres. Awlied on Rate 0.3 TKN 86866.1 NH3 201071 NO3 NO2 66.9291 0 % Solids 0.127 PAN Surface 30148.17911 mg/kgmgLkg 60.29636 lbs/dry ton 0 1 Ibs total PAN #DIVlO! jibs PAN/acre PAN Injection 40201.72911 mglkg 80.40346 lbs/dry, ton 0 1 Ibs total PAN #DIVIO! jibs PAN/acre Dry Tonsf1000 gal. 0.52959 1st year PAN Surface lbs. 0 1st year PAN In ected Ibs. 0 IbsJacre Surface #DIV/0! Ibs.lacre Injected #DIV/0- MR(TKN-NH3)+ + .5(NH3)+NO3+NO2 =mg/kg mglkg x .002=lbsldry ton MR(TKN-NH3) + 1(NH3)+NO3+NO2 =mg/kg mg/kg x .002=lbs/dry ton 1000 X 8 34 X %solids X sip cravi y "=dry tons/1000gal." 2000 Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River, NC 28669 Receive Date: 01/23/2020 Reported: 05/08/2020 For: BAXTER Comments: Sample Number Parameter Sample IA Result Unit Method Analyzed Analyst 200123-32-01 Fecal Coliforms 61 loll MPN1g SM92210E-2006 01124/2020 WC 200123-32-01 Percent Solids B1 12.7 % SM25AOB-20" 01/24/2020 WC 200123-32-02 Fecal Coliforms 62 1870 MPNIg SM92210E-2006 01/2412020 WC 200123-32-02 Percent Solids B2 12.3 % SM254oB-201 01/24/2020 WC 200123-32-03 Fecal Coliforms 133 1769 MPN1g s1092210E-M6 01/24/2020 WC 200123-32-03 Percent Solids 83 13 % 5M25400.2011 01/24/2020 WC 200123-32-04 Fecal Coliforms B4 1797 MPNIg SM92210E-2000 01/24/2020 WC 200123-32-04 Percent Solids 84 12.8 % sM2540B.2011 01/24/2020 WC 200123-32-05 Fecal Coliforms B5 1949 MPN,g SM92210E-2006 01/2412020 WC 200123-32-05 Percent Solids 85 11.8 % SM25408.2011 01/24/2020 WC 200123-32-06 Fecal Coliforms B6 1917 MPN?g 51A92210E-2W6 01/24/2020 WC 200123-32-06 Percent Solids B6 12 % SM25400-2011 01/24/2020 WC 200123-32-07 Fecal Coliforms 87 1825 MPNrg SM9221cE-2M 01124/2020 WC 200123-32-07 Percent Solids B7 126 % SM25408.2011 01124/2020 WC Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 a 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200123-32-01 Temp on Arrival 6.0 Parameter Schedule. Percent Solids Received on Ice Parameter Schedule- Fecal Coliforms Sodium Thiosulfate Received on Ice Chemica s in containers, lab Sample Number 200123-32-02 Temp on Arrival: 6.0 Parameter Schedule Percent Solids Received on Ice Parameter Schedule. Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals n containers, lab Sample Number 200123-32-03 Temp on Arrival: 6.0 Parameter Schedule Percent Solids Received on Ice Parameter Schedule Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200123-32-04 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200123-32-05 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice p0 Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200123-32-06 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200123-32-07 Temp on Arrival: 6.0 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 lJv:ayr.Z� .. srAMVIMEARALY[ICAL Adds: Rd I zz Cour srsa ro. t na Slsaville,NC 2NIt7 ,. cm+, azzrear contact Person: I � B il uc- qs 1- V�1)1 Fnx+l Chain of Par Y�c Requtsmoned dy •� I r Custody Record GlfWflr Sarror IDM L,aA10f MrlagaT(1�I Grab DMa5amDrau YkRbC,*N1 ^ _ r w Panwn,retigwnaFfaadysis k IL Relinquished py: — Time 3111 am, Date Sampled by 1 1_ I Received t]y V �4 L��� "' Time 5 am, m��Dale �2J�W Transported by: 1 Relinquished hy:— _ _ Time am, Pm Date Holding times met: / i Received by-._ Time arrt pm Date �l—J Compliance work: ite — Time begin am, pm Date _/ r __ luon•eompuance work: Time end _ am. Pm Date -�—r— ! tab C..,r*at: c4mmite Umpling $2, sarrQws Tramponwl on ke. j a 1 Time begin _ am. pm Dale Time end — _am, pm Data —j r, rn tD N O r� v 0 m o a rl 00 Co N u z a; a x 00 rNr rV x 0 Co 0 Q. i t PacgmNniceY F /'!�p L1 /�"� !n'j A� Sate 100 - �yG, r �r4Qf Humerlville. NC 2bo76 vissaeolfte" (704)876-ON2 ANALYTICAL RESULTS Project BAXTER Pace Prored No : 92462233 Sample: Samples-200123.31.01 Lab lD• 92462233001 Collected: 01r23120 13:30 Pwaived 01124/20 14:55 Matrix- Solid Results reported on a "dry weight' basis and are adjusted tar percent moisture. sample adze and any dilutions. Parameters Results Units Report Limit OF Prepared Analyiatl CAS No. Qua: Chlorinated Herb. (4C) 81E1A Analytrcal McJvd. EPA 815t A Preparalion MethpH- 8151A Leachate MdhoUlDale: 1311. 01r"20 20.25 Initial pH: 7 12: Final pH. 5.06 2A.5-TP ($ilvax) NO mgll 0.00200 1 02/03/20 07:10 02/03120 20:08 93.72.1 24.0 NO m911- 0.00200 1 02103120 0TI O 02M3120 20:06 94.75-7 Surrogates 2 44)CAA (5) 690 % 140.158 1 02/03/20 07:10 02M3120 20:08 19719-28-9 8081 TCLP Pestletdas RYE Analytcal Method: EPA 80816 Preparation Method. EPA 3510C L ea(Aa:e Me01od47ate- EPA 1311. 0128120 15:49 In Ile! pH: 7.69- Final pH. 4 gamma-BHC (Lindane} NO ug/L 0.50 1 012920 11.34 01r30120 17 32 58-89-9 CNordsne (Tedm,ceq NO ugA. 30 1 0112912011.34 010=0 17,32 57-74.9 Enonn NJ ug4 0-50 1 01r29f2011.34 01-30201732 72.20-8 Heptachlor NO ug11- 0.50 1 01129/20 1134 0IM12017 32 76.44.8 Heptachlor epoxide ND uglL 0.50 1 0t12920 11,34 OIfd020 17 32 1024.57.3 Meltwxyctdor NO ug& WOO 1 01129120It34 011=017:32 72.43.5 Toxephene NO ug/L 3.0 1 0112912011,34 01r3012017-32 8001.35.2 Surrogates Decachoroblpnenyl(S) 102 % 10.138 1 nV29r2011:34 OVA7017:32 2051.24.3 Tetrachloro-rtrxylene (S) 75 % 10.110 1 01129M 11.34 0IM70 17.32 877-09-8 8082 GCS PCe Analytical Method: EPA8082A Preparation Method: EPA 3546 PCB-1016 (kodor 10161 ND ug*9 232 1 0t12720 It 32 01128120 23-55 12674.11.2 PCB-1221 1Arodor 12211 NO ugikg 232 1 Ot27/2011-32 OWOM 23:55 11104.28-2 PCB-1232 01wodor 12321 NO ugikg 232 1 OV27120 1t 32 OM8120 23:55 11141.16-5 PCB-1242 (Arodor 1242) ND ugikg 232 1 01 27120 11 32 01'28120 23755 53469-21.9 PCB.1248 (Arodor 1248) NO ugikg 232 1 0112720 11 32 012820 2155 12672-29.0 PCB-1254 (Araclor 1254) NO ugikg 232 1 01271201132 01128/20 23'55 11097.690 PCB-1260 (Aratlor 1260t NO ugikg 232 1 01272011 32 Ot/28120 23:55 11096.82-5 Sulrooales Decachlorobiphenyl(S► 45 % 10-130 1 01727/20 1132 Ov2&20 23.55 2051-24-3 $092 TCLP Pees RVE Analytical Method- EPA 8082A Preparation McOtod, EPA 3510C Leachate Melhod(Date EPA 1311 01f28t20 15:49 Initial pH- 7,69 Final pH 4 PCB-1016 (Arodor 1016) No uplL 1000 1 0112912011 34 01/30/20 15 06 12674-11.2 PCB 1221 (Arodor 1221) NO ugrl 1000 1 01129/'2011 34 0113002016:06 11104-28-2 PCB-1232(A(odor 1232) NO ug1L 1030 1 01/29/2011 34 0113012015.06 11W-16.5 PC8 1242 (Arodor 1242) NO ug1L 1000 1 01129/20 1134 01r4W() 15:06 53469-21.9 PCB.1248 (Arodor 1248) NO ugll 1000 1 01IM2011 34 01/30120 15:06 12672-29-6 PC13•1254 (Arodor 1254) NO ug)L 1000 1 011MO 11 34 01130120 15:06 1t097$9.1 PCS-1260 (Arodor 1260) NO ug1L 1000 1 01r29120 11 34 01/30120 15,06 11096-82.5 Surrogates Oecad+loi bq) anN (5) 99 % 10-132 1 01129f20 11 34 01130/20 15:06 2051.24.3 6010 MET ICP, TCLP Anatyllcal Method: EPA 601OD Preparation Method, EPA 30I0A I.eachole MelhodlDate, EPA 1311. 0210WO 17 10 What pH 9 23- Final pH 4 5 Arsenic NO mg/L 0 050 1 02;04/20 12 00 021052016:32 7440.38.2 Barium 0.26 mglL 0.25 1 02104120IZ00 02IM2011132 7440.39-3 REPORT OF LABORATORY ANALYSIS 7fns report ahax not be reprodLmW except m ha Dale 0210712020 04-49 PM *WwM Owe iltcn cons"t of FwaAnayccal Sereices LLC Page 5 of 26 PO Sox 228 a Statesville, NC 28687 a 704187214697 Page 21 of 42 aceAna! a 11)! rrrrul.tM�sae ANALYTICAL RESULTS Pace Analytical Services, LLC 99001tarceyAve Suite+OD HoVitrsvee NC 28078 (704AM9092 Project BAXTER Pace Protect No. 92462233 Semple,. Samples.200123.31.01 Lab 10: 92462233001 Collected 0123t20 13 30 Re"nred- 01124120 14 55 Malnx• Solid Resulfs rep~ on a 'dry wftht' frasls and are adjusted ila patent moisture, sample sire and any dltudons. Parameters Results Un is Report Lim-1 OF Prepared Analyzed CAS No. QLW 6010 MET 1CR TCLP Analytical Method EPA 60100 Preparation Method, EPA 3010A Leachate MelhodlDale EPA 1311 02103/20 17 10 Initial pH 9 23 Final pH 4.5 Cadmium NO mg1L ; :}150 1 02104120 12 00 021 WID 16.32 744043-9 Chromium NO mg-1- 0 050 1 02-0420 12 00 02105120 16:32 7440.47 3 Lead NO mg.-L 0 925 1 02104120 12-00 021MO 15.32 7439.92.1 Selenium NO mg1L 0.10 1 02M4120 12 00 02M5120 16:32 7782.49-2 Silver NO mgR 0025 1 02*4201200 02M5i2016:32 7440.22.4 7470 Mercury, TCLP Analytical Method EPA 7470A Preparation Method: EPA 7470A Leachate Mefhod/Date- EPA 1311 02/03120 17 10 India pH 9.23: Rnal P►+ 4.5 Mercury ND Ing/L. 00002D 1 02r042013.30 02MW O12.07 7439-97.6 8270E MSSV TCLP Sep Funnel Anstytkal Method EPA 8270E preparation Melhod EPA 3510C 14-81chlorobenzene NO u21L 50.0 1 02r04120 OS-07 02MS12011:58 106-46-7 2.4d3fiitrolo-uene NO --91L 50-0 1 02104:2008:07 02105J2011.58 121.14.2 Hexachbro-1 3-butaduene NO uWL 50.0 1 07+0420 06.07 02W20 11 58 87-66-3 Henachlaaben=ene NO ugr. $0.0 1 02*$20 08:07 0210512011.68 118-74 1 Hexachlowelhane NO u]rL 50.0 1 0210420 05.07 02105120 11 58 67.72-1 2-Mathylphend(o-Creso) NO tg!L 50.0 1 02(04)20 08:07 02105/20 11 58 95.46-7 3d4-Methylphenol(m9p Creso i NO i.gk 50.0 1 02r0420 08.07 02/OS120 11 58 15831.104 Nitrobenzene ND ugA 50.0 1 02M4120 06:07 021144M 11 58 98.95-3 Perdachlorophend NO 1911 Ma 1 02104/20 OS.07 02r0520 11 58 87-8&5 Pyridine NO ..g2 50.0 1 0210420 D5.07 021tiWN 11 58 110-86.1 2,4 5-Tnchlorophenol NO ug1L 50.0 1 02*470 08 07 02/05120 1158 95.95.4 2.4,6-TrkNoraphenol NO ug1L 50.0 1 02fO4FA08'07 02/051201v55 88.06.2 Sw"gates Nllrobenzene-0 ($1 41 % 12-102 1 02/04120 O8 07 02105/20 1158 4165.60-0 2-Fluorobiphenyl (S) 40 % 13.107 1 021`04120 08:07 02IM20 1158 321.)0-S Terph rnyl-d14 (S) 55 % 21 132 1 07JO41200807 02/05120 1158 1718.51-0 Phenol-d6 (S) 13 % 10-110 1 0204420 06.07 02/05/20 11 58 13127-88.3 2-Fluorophanol(S) 19 % 10.110 1 0210412006.07 0210520It58 367-12-4 2.4,8 Tribromophenol (S) 38 % 27-108 1 02/04120 08.07 02105/2011 58 116-79.8 82600 MSY TCLP Analytical Method EPA 82WD Benzene NO ugk 100 20 021062019:51 71.43-2 2-Butanone (MEK) NO ug1L 200 20 02MMO 19,51 78-93-3 Carbon tevachlo!" NO ug1L 100 20 0210620 19:51 56.23-5 Chlorobenzene NO ug1L 1D0 20 02/062019:51 10$-90.7 Chloroform NO ug1L 100 20 02/W2019:51 67.66-3 1,4-Dichlorobenzene NO ug1L 100 20 02/062019:51 106-46.7 1.2-Dichioroethane NO ug1L 100 20 02M&201951 107-M-2 11-Dichlomathene NO ugx 100 20 0210612019,51 75-35-4 Tatrachlotoelhene NO ugiL 100 20 02/OW2019:61 127-184 Tnehloroo hens NO ugil. 100 20 07JO6120 19.51 79.01.8 Vinyl rhkK!de NO OWL 100 20 02r06120 19:51 75-01-4 Surrogates 1,2-D,chloroethane-d4 (S) 99 % 70.130 20 02106/20 19:51 17ON-07-0 REPORT OF LABORATORY ANALYSIS This repon shall net be rapadi led. artapl in hati. Date- 02/0712020 04:49 PM without ills MriaM consent of Pace Arelytcat Services, LLC Page S of 25 PO Box 228 a Statesville, NC 28687 a 704/972/4697 Page 22 of 42 =A aiOc it k ANALYTICAL RESULTS Pace An0y11aa Sarvkaa- LLC 9a00KkX"AV0 Slxtel[[ Hunterevq NC 2000 (704)675.9092 Protect BAXTER Pace Project No. 92462233 Sample: Samples-200123.31.01 Lab ID: 92462233001 Collected- 01,23120 13.30 Received- 01124r20 14 55 Matrix Sold Aesutts reported on a "dry wNpht' basis and are adjusted for percent mmsturs, sample size and any dilutions. Parameters Results units Report Limit OF Prepared Analyzed CAS No 4ual a290D MSV TCLP Analytical Method FPA8260D Surropatas Toluene.0(S) 104 % 67.135 20 OM'20 19,51 2037.26 5 4-Bromofluorobanzene (S) 97 % 70.130 20 02.'0612019 51 460-00.4 Percent MolMure Analytical Method ASTM 02974.87 Percent Moisture 85.7 % 010 t 01f24f20 16.41 1010 Flashpotot,Closed Cup Analytical Method* EPA 1010A FlashpoiM 3-200 deg F 70.0 1 02/03/20 12-35 904S pH $oil Analylicsi trlelhod: EPA 90450 pH at 25 Degrees C 7.7 Sid Units OA0 1 01/2712015.24 H3 NOS Paint Filter Liquid Test Analytical Method, EPA 9095E Free Liquids Pass 1.0 1 01131!YO 18 27 733C S Reactive cyanide Anayt(cal Method EPA 9014 Preparation Method SW-846 7 ] 3.2 Cyanide. Reactive ND mglkg 7.0 1 01i29120 15:57 01129120 16,36 7343 Reactive Sulfide Analytical Method, SM 4500521'-201t Preparaiion Method. SW-846 7,34.2 Sulfide, Reactive NO m911(9 69.8 1 Ot129R015:57 O1f2912016-00 REPORT OF LABORATORY ANALYSIS This spat shah real tie reproduced, except n hie Data 02M?!2020 04:49 PM wi9qut d» mitim com"I of Pen Analybc Service{- LLC Page 7 of 26 PO Box 228 a Statesville, NC 28687 a 704/872/4697 Page 23 of 42 a ct 0 '►trr� MTE$VR RANALVWAL 122 Can Snow .0. oft 228 &IwVH*' NC 20587 (ce) 9724497 Chidn of Custody Record Add rsw: S _� RA •,AL aq FA}ca canted Perear y Phone ` 33L- s.)- Isni Pot if Re" aitioned by: } culoww ew Labs bd ole*w name o" Wrwaen'"n'mhuA�rW1rr& w 1' 3e yr, TCL rra ea...i�•, Relinquished by: % Time 3: h am. {� Deba JJ' jRD ,ampw by: Z f'`�_ Recehod by Time ✓l �7 am. �n Ike � � -w ed by-. Re"ulshed br. Time am, pm pate J / HW1ng times mom: f Recei ood br. Time am, pm Date JJ Compiler" Work Time bagm am. pm Data �� _. Non-compliance worm Time end -am, pm Data Le6 Ca mnnre: SWOM TratropoMd On roe: Time begin am, pm Date :JJ Time end am, pm Data Irit<els: Go t0 N U Z of aJ go N N O C. Analytical Results U.S. Biosolids Inc 958 Hoots Road Roaring River_ NC 28669 Receive Date: 03/19/2020 Reported: 04/27/2020 For. BAXTER Comments: STATESVILLE ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200319-21-01 30 Day Benchscale BAXTER Respectfully submitted, 'Op ,�A..)n, �C, I Dena Myers NC Cart #440, NCDW Cert #37755. EPA #NC00909 <1 % EPAWS-R-M 03/19/2020 WC PO Box 228.Statesville, NC 28687.704/872/4697 Page 1 of 3 30 Day Bench Worksheet Sample ID # ?) Qa 31 q 21 WFFK t Samples Total Solids Volatile Solids % Volatile Fraction I 2 2 I 1• 05 3 I 1. I 02`7-7 Average: —Al ' WEEK 2 Sam les Total Solids Volatile Solids % Volatile Fraction 1 1 2 - 3 ; L4 . a U: Averse_ I • -7 0 C1 2 24 WEEK 3 Samples 1 2 3 Average: WEEK 4 Total Solids Volatile Solids latle /o Voi Samples Total Solids Volatile Solids % Volatile Fraction 1 -- --- 2 O 1 3 I 5� Avers e: 1. ."1 5 M A-M Total Solids Vo 1 2_.. 3 15 WEEK 6 Solids 1 % Volatile Fraction 101 Samples Total Solids I, 4U Volatile Solid LZ-jL--.—Mft25 % VolatileFra-ction I 2 1. t4112 I f 3 . -7 Avers e: 1 Van Kleeck Reduction: a/ Vol. FLa . Final % Val. EM . X 100 = % rutial % Vo[. C. - ( Initial % Vol. Frac. X Final % Vol. Frac.) FINAL RESU % Condition of Receipt Sample Number 200319-21-01 Temp on Arrival. Parameter Schedule; =7M— I M-1 PO Box 228 • Statesville, NC 29687.7041872/4697 Page 2 of 3 V S 8:03e14� Znc Pic, 80 14C ;TATFSVIIIIF ANALY71:AL �, c ass � o +� 122CLunSim • P.o.aokUS ;IPerson, Ph'"0 336.9 :S ! FAX:of 286di r�a,srt,6gr nRecf" PdWU* f wmd by. lnm• o:e.1 Custody Tip aae �npay IDa Data Senpq i r ww Paraan MQWM LANs �. h.:, L Relinqunhed by Time ! Sams by; 7IQ am, pm Date i 1 h! a i� Time 1(OLD am, pm Date f 7/ TmnsPorlecl by ? , k, —7 "✓ � Relinquleh: ed by-, — Time am, pm Date /� _ H Holding times met: Received by- lime am, pm Date / / — - -- Carnp6ance work: Time begin am, pm Date /_ 1� MamXimpliance Time end am, pm Date --/ 1 commwra sulw4a irttlrporla0 on !a: Time begin am, pm Date Time end am. pm Dare Mffi�a: NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomil Report No. FY21-SLO13784 " ' Predictive Client: Doug Poplin 594 Austin Little Mtn Rd Advisor: Zach Key Southern Sod Builders Mehlich- 3 Extraction Soil Report Ronda, NC 28670 958 Hoots Rd Roaring R ver, NC 28669 - Sampled County � Wilkes �' "• " 610M to Helpful Information Client ID: 160157 AdvisorlD: 231531 Sampled- Received: 11/13/2020 Compieted. 12109/2020 Farm. Sample ID: DP1A Recommendations: Lime Nutrients (lblacre) More Crop (tonslacre) N P20S K20 Mg S Mn Zn Cu B information Lime History: 1-FescuelOGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 I 2- 0.0 Test Results [units - WN in glcrr?; CEC and Na In meg1100 cm3; NO3-N in mgldrti): Soil Class: Mineral HM% WN CEC BS% Ac PH P-1 K4 Ca% Mg% S4 Mn-1 Mn-All Mn Al2 Zn-I Zn-AI Cu-1 Na ESP SS4 NO3-N 0.51 0.94 10.0 85 1.5 6.1 196 131 55 23 42 181 125 315 315 934 0.1 1 Sample ID: DP18 Recommendations: Lime Nutrients (lb/acre) More Crop (tonsfacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1- FescuelOGrasslTim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - WN In glcrr?; CEC and Na in meg1100 cars; NO3-N in mgldlrf ): Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K4 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn4 Zn AI Cu-1 Na ESP SS4 NO3-N 0.60 0.95 12.6 88 1.5 6.2 305 140 61 22 51 133 93 657 657 1613 0.2 2 Sample ID: DP1C Recommendations: Lime Nutrients (lb/acre) More Crop (tonstacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/TIm, M 0.3 120-200 0 0 0 0 0 0 0 0 Note 12 2- 0.0 I Test Results [units - WN in glcrf?: CEC and Na in mag1100 cm3; NO3-N in mgldm ): Soil Class: Mineral HM% WN CEC SS11/6 Ac pH P-1 Kd Ca% Mg% S4 Mn-1 Mn-All Mn-AI2 Zn4 Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.51 0.93 11.4 84 1.8 5.9 203 145 56 21 45 205 140 773 773 1310 0.2 2 North Carolina Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler. Commissioner of Avriculture NCDABCS Agronomic Division Phone: (919) 733-2655 �Website: www.ncagr.govlagronomil Report No. FY21-SLO13784 Doug Pop.in Page 2 of 4 Sample ID: DP1D Recommendations: Lime Nutrients (lb/acre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/Tim, M 1.2 120-200 0 10 0 0 0 0 0 0 Note: 1 2- 0.0 Test Results [units - WN in glcd; CEC and Na in meg1100 cm3: NO3-N In mgldni): Soil Class: Mineral HM%o WN CEC BS% Ac pH P4 K4 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn4 Zn AI Cu-I Na ESP SS-1 NO3-N 0.71 0.98 7.4 70 2.2 5.3 126 73 47 18 46 V0 83 403 403 450 0.1 1 Sample ID: DP2 Recommendations: Lime Nutrients (Iblacre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1-SGlCom silage 00 80- 100 0 30 0 0 pH$ 0 0 0 Note: 3 Notet 2- 0.0 Test Results [units - WN in glcm3; CEC and Na in meg1100 cm3; NO3-N In mgldrr?]: Soil Class: Mineral HM% WN CEC BS% Ac pH P4 K4 Ca% Mg% S4 Mn-1 Mn-Alt Mn-Al2 Zn4 Zn-Al Cu-I Na ESP SS-1 NO3-N 0.36 0.99 10.0 91 0.9 6.7 203 91 57 29 73 146 88 685 685 791 0.2 2 Sample ID: DP3C Recommendations: Lime Nutrients (Iblacre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1-FescuelOGrass(Tim, M 1.0 120-200 0 20 0 0 0 0 0 0 Note. 12 2- 0.0 Test Results [units - WN in g/cm3; CEC and Na in meg1100 cm3; NO3-N in mgldnr): Soil Class: Mineral HM% WN CEC US% Ac pH P-1 K4 Ca% Mg% S-1 Mn-I Mn-Ali Mn-Al2 Zn4 Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.89 8.6 75 2.2 5.5 345 65 48 23 90 90 71 629 629 664 0.2 2 Sample ID: DP3G Recommendations: Lime Nutrients (lb/acre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu S Information Lime History: 1- SG/Corn silage 0.0 80-100 0 150 0 0 0 0 0 0 Note 3 2- 0.0 Test Results [units - WN in glcd- CEC and Na in meg1100 cm13; NO3-N in mgldrvt): Soil Class: Mineral HM%. WN CEC BS% Ac pH P-1 K4 Ca% Mg% S4 Mn-I Mn-All Mn-Al2 Zn4 Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.51 0.87 10.4 85 16 6.1 136 26 53 31 57 72 52 546 546 356 0.2 2 NCDA&CS Agronomic Division Phone: (919) 733-2655 i Website: www.neagr.gov/agronomi/ Report No. FY21-SL013784 Doug Poplin Page 3 of 4 Sample ID: DP4 Recommendations: Lime Nutrients (Iblacre) More Crop (tonslacre) N P205 KzO Mg S Mn Zn Cu B Information Lime History: 1-FescuelOGrass[Tim, M 0.0 120-200 0 10 0 0 PH$ 0 0 0 Note: 12 Note: S 2- 0.0 Test Results [units - W1V in glans; CEC. and Na in meg1100 cm3, NO3-N in mgldrrtt]: Soil Class: Mineral HM% WN CEC BS°% Ac PH P4 K-1 Ca% Mg% S-1 Mn-i Mn-All Mn-AI2 Zn4 Zn-Al Cu-I Na ESP SS-1 NO3-N 0,56 0.94 12.1 91 1.1 6.6 151 72 54 35 60 227 144 626 626 748 0.2 2 Sample ID: DP5 Recommendations: Lime Nutrients (lb/acre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu 8 Information Lime History: 1-FescuelOGrassfrim, M 0.3 120-200 0 0 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - WN in g1cd; CEC and Na in meg1100 cart; NO3-N in mgldrrl3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-I Ca% Mg% S4 Mn-I Mn All Mn-Al2 Zn-I Zn-AI Cu4 Na ESP 33-1 NO3-N 0.66 0.83 11.4 83 1.9 5.9 161 108 51 27 52 112 84 857 857 554 0.2 2 Sample ID: DP6 Recommendations: Lime Nutrients (lb/acre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1- FescuelOGrassMm, M 0.0 120-200 0 0 D 0 pHS 0 0 0 Note: 12 Nole: 2- 0.0 Test Results [units - WN in glcrr?; CEC and Na in meg1100 cm3; NO3-N in mgldnrj: Soil Class: Mineral HM% WN CEC 135 % Ac pH P-1 K4 Ca% Mg% S-1 Mn4 Mn-AI1 Mn-Al2 Zn4 Zn-AI Cu-I Na ESP SS-1 NO3-N 0.60 0.97 11.5 91 11 6.5 93 93 54 32 48 102 70 607 607 515 0.1 1 Sample 1D: DP7 Recommendations. Lime Nutrients (lb/acre) More Crop (tonslacre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrassffim, M 08 120-200 0 70 0 0 0 0 0 0 Note. 12 2- 0.0 Test Results [units -WN in g/crr?,, CEC and Na in meg1100 cm3; NO3-N in mgldnl3]: Soil Class: Mineral HM% WN CEC OS°% Ac pH P4 K-1 Ca% Mg% S-1 Mn-I Mn-Ali Mn-Al2 Zn4 Zn-AI cu-i Na ESP SS-1 NO3-N 0.56 0.94 9.4 78 20 5.6 228 32 54 23 57 134 97 563 563 929 0.1 1 NCDABCS Agronomic Division Phone: (919) 733.2655 Website: www.ncagr.gov/agranomi/ - Report No. FY21-SLO13784 Doug Poplin Page 4 of 4 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime If testing finds that soil pH is too low for the crop(s) indicated, a time recommendation will be given in units of either ton/acre or Ib11000 sq ft. For best results, mix the lime into the top 6 to S inches of soil several months before planting. For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at time, even if the report recommends more. You can apply the rest in similar increments every six months until the full r is applied. If MG is recommended and lime is needed, use dolomitric lime_ Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutHent levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to ote_ Secondaly_Nutriepts and Micn)nutnents. In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncaqr.qov/aqronomi/pubs.htm. i Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find the exact fertilizer grade recommended on the report, visit www.ncaar.vovlaaronomilobow14.htn end information that may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer Test Results The first seven values ]soil class, HM%, WN, CEC, B5%, Ac and pH] describe the soil and its degree of acidity. The remaining 16 [P-I, K-1, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn AI, CA. S-I, SS-1, Na. ESP, SS -I, NO3-N (not routinell available)] indicate levels of plant nutrents or other fertility measurement. Vis.t wwwncear.aov/agronomiluvrsthim Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K4 potassium index K20 potash Mg% % CEC occupied by magnesium MIN mineral soil class Mn manganese Mn All Mn-availability index for crop 1 MnAl2 Mn-availability index for crop 2 Mn-I manganese index M-0 mineral -organic soil class N nitrogen Na sodium NO3-N nitrate nitrogen ORG organic soil class pH current soil pH P-1 phosphorus index P205 phosphate S-1 sulfur index SS-1 soluble salt index WN weight per volume Zn-AI zinc availability index Zn4 zinc index