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HomeMy WebLinkAboutWQ0004609_Residual Annual Report 2020_20210224Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0004609 Applicant/Permittee Wayne Farms LLC Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00004609 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * Wayne Farms RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for Wayne Farms, LLC - Dobson, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Wayne Farms NC 2020 Annual Report FINAL.pdf 6.89MB Upload only 1 FFdocurrent (less than 250 fvB). Miltiple documents rust be combined into one FJFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/24/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 24, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0004609 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Wayne Farms, L.L.C.-Dobson, NC. If you have any questions or need additional information, please do not hesitate to contact Paul Nordin at (336) 386-8151 or Alex Fox at (336) 703-8681. Sincerely, W�1 01_ I t Derrick Shivar Environmental Compliance Manager Enclosures cc: Paul Nordin, Wayne Farms, L.L.C.-Dobson Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD WAYNE FARMS, L.L.C. , NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0004609 2020 ANNUAL REPORT Wayne Farms, L.L.C. - Dobson, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form & Annual Operations Summary 2. Annual Residual Sampling Summary Forms 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Control of Possible Nuisance Conditions 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit 4: W 0004609 County 5AM Year 2020 Facility Name (as shown on permit) Wayne Farms NPDES No. NC0006548 Land Application Operator S na o Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. if NO, skip Part A. and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summarv: Total number of application fields in the permit: 26 Total number offields utilized for land application during the year: 6 Total amount of dry tons applied during the year for all application sites: 180.89 Total number of acres utilized for land application during the year: 130.10 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality -YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. I , Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. S. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 027 .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T . l 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1 1 1 I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop managemcnt was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface watcrs has occurred. 13, All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Matthew Wooten Complex Mana3Zcr Permittee Name and Title (type or print) tture of Permittee Date -��-z� Signature of Preparer* Date ' �Srignature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparcr) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 WAYNE FARMS, L.L.C., NC WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID MONTH/YEAR January 2020 March 2020 October 2020 November 2020 TOTAL AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 62,000.00 G 7.73 D 7.01 613,800.00 G 76.53 D 69.41 613,800.00 G 76.53 D 69.41 161,200.00 G 20.10 D 18.23 1,450,800.00 G 180.89 D 164.07 Report Date: 2/11/2021 4:18:14 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0004609 Laboratory: Facility Name: WAYNE FARMS, L.L.C., NC Waypo[nt Analytical Virginia Inc. Residual Source WQ # or NPDES#: N00006548 WWTP Name: WAYNE FARMS L.L.C. Residual Analysis Data Product Type FPLIQ Sample or Composite date 01/23/20 Parameter (mgfkg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 2.99 Arsenic 75 <16.7 Cadmium 85 <3.33 Copper 4300 530 Chromium NA 23.7 Lead 840 <10 Mercury 57 <0.487 Molybdenum 75 8.33 Nickel 420 24.2 Selenium 100 <16.7 Zinc 7500 1040 Total Phosphorus NA 11200 TKN NA 66000 Ammonia -Nitrogen NA 13400 Nitrate and Nitrite NA <W3 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the Individual permit for metals limits. "I certify, under penalty of law, [hat this document was prepared under my difeclion or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibi[it fines and imprisonment for knowing violations." Signature of Preparer* Hate 'Preparer is defined in 40 CFR Part 503.8(r) and 15 A NCAC 2T.1102(26) bFNR FORM RSSF-B (12l2006) Printed: 2/1112021 4:18:64 PM For. 206101 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0004609 Facility Name: WAYNE FARMS, L.L.C., NC Residual Source NPDES # or WQ#. NC0006548 WWTP Name. WAYNE FARMS L.L.C. Residual Analysis Data Product Type FPLIQ Sample or Composite Date 01/23/20 Parameters (mg/kg dry weight) Aluminium 6830 Calcium 72300 Magnesium 8670 pH (s.u.) 8.50 Potassium 3470 Sodium 4400 PAN 22673 SAR (Ratio) 0.7103 Laboratory: Waypo€nt Analytical Virginia Inc. "I certify, under penalty of law, that this document ryas prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the passibility of fines and imprisonment for knowing violations." 1k;; a_ad-ac Signaturo of Preparer Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2111/2021 4:19:22 PM For: 206101 DENR FORM RSSF.B (1212006) Waypointo ANALYTICAL 1 /31 /2020 Synagro Central LLC/ Wayne Farm Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-024-0011 Project Description: Wayne Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/24/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 Waypoint ANALYTICAL Report Number: 20-024-0011 Client Project Description: Wayne Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Sample Summary Table Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 SM-2540G WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 SW-7471B WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 SM-4500-NH3C-TKN WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 4500NO3F-2011 WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 6010D WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 SM-4500-NH3C WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 9045D WP MTN 70265 Wayne Farms Solids 01/23/2020 13:30 01/24/2020 AOAC 955.01 WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 i Waypoint. ANALYTICAL 46499 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Synagro Central LLC/ Wayne Farm Alex Fox Mary Brewer Project Wayne Farms Report Date : 01/31/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Report Number : 20-024-0011 REPORT OFANALYSIS Pauric Agronomist McGry Lab No : 70265 Matrix: Solids Sample ID : Wayne Farms Sampled: 1/23/2020 13:30 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 97.0 % 0.010 1 01/29/2017:05 ADM SM-2540G Calcium Carbonate Equivalent 20.2 % - dry 0.1 1 01/29/20 09:25 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 13400 mg/Kg - dry 3330 1 01/30/20 14:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N <163 mg/Kg - dry 163 1 01/29/20 13:31 ZBD 4500NO3F-2011 Organic N 52700 mg/Kg - dry 8330 1 01/30/20 10:00 CALCULATION pH 8.5 S.U. 1 01/30/20 06:12 JSL 9045D Total Solids 2.99 % 0.010 1 01/29/20 17:05 ADM SM-2540G Total Kjeldahl Nitrogen 66000 mg/Kg - dry 8330 1 01/30/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 11200 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Aluminum 6830 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Arsenic <16.7 mg/Kg - dry 16.7 1 01/29/20 16:42 JTR 6010D Calcium 72300 mg/Kg - dry 833 1 01/29/20 16:42 JTR 6010D Cadmium <3.33 mg/Kg - dry 3.33 1 01/29/20 16:42 JTR 6010D Chromium 23.7 mg/Kg - dry 8.33 1 01/29/20 16:42 JTR 6010D Copper 530 mg/Kg - dry 8.33 1 01/29/20 16:42 JTR 6010D Iron 12300 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Lead <10.0 mg/Kg - dry 10.0 1 01/29/20 16:42 JTR 6010D Magnesium 8670 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46499 Synagro Central LLC/ Wayne Farm Alex Fox Mary Brewer Project Wayne Farms Report Date : 01/31/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Pauric ry Report Number : 20-024-0011 REPORT OFANALYSIS Agronomist Lab No : 70265 Matrix: Solids Sample ID : Wayne Farms Sampled: 1/23/2020 13:30 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Manganese 467 mg/Kg - dry 16.7 1 01/29/20 16:42 JTR 6010D Mercury <0.487 mg/Kg - dry 0.487 1 01/29/20 12:02 TJS SW-7471B Molybdenum <8.33 mg/Kg - dry 8.33 1 01/29/20 16:42 JTR 6010D Nickel 24.2 mg/Kg - dry 8.33 1 01/29/20 16:42 JTR 6010D Potassium 3470 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Selenium <16.7 mg/Kg - dry 16.7 1 01/29/20 16:42 JTR 6010D Sodium 4400 mg/Kg - dry 833 1 01/29/20 16:42 JTR 6010D Zinc 1040 mg/Kg - dry 41.7 1 01/29/20 16:42 JTR 6010D Sulfur 9670 mg/Kg - dry 167 1 01/29/20 16:42 JTR 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 6 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46499 Customer Name: Synagro Central LLC/ Wayne Farm Report Number: 20-024-0011 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/24/2020 13:01:28 Page 5 of 6 SAMPLING LOG # CUSTOMER: SYNAGRO PROJECT MANAGER: ---"IL ) x Phone: �7p } 70 3 `66� A & L CUSTOMER SAMPLING LAB # SAMPLE 1.13. LOCATION 111 r■ Relinquished by Sampler: Relinquished by: Relinquished by: SPECIAL INSTRUCTIONS: 02( "for monitoring purposes. r � I llllll lull llll llr1lll lLl 1111111111111111Wavne �1E10111111111111 ? 0' �� � ® CUSTODY - Wavne Farms RECORD field sampling procedures were Cdd rin fion of these samples. SAMPLER SAMPLE # OF SAMPLING METHOD METHOD TYPE CONTAINERS DATE TIME PRESERVED SHIPPEC co l L-L7 ] C� JOT Date Time �3 If : r� Date Time D to ,me - I riLt I U Recleved by: Recieved by: ,16T5 P❑#: REMARKS: SAMPLE ANALYSIS REQUEST LD. SL1 SL.2 ' iVH -N a I Na7 _N a jorganiu �i Cd Ce Ni Pb As ; ig 5e pH Caco, equiv. Volatile Solids Mo - Cl N❑ N 2 Ljf n L 1,40 1.40 Pr f0 100 1000' 100 le -ow L006, g� low 9090 1409 { 9400, Y4re� SLI: Total Solids �Moisturej, Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SLI plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc Page 6 of 6 SECTION 3 FACILITY NAME: WAYNE FARMS, L.L.C., NC LANDOWNER: JAMES WALTER JOHNSON OPERATOR: JAMES WALTER JOHNSON CROP 1 NAME: WHEAT (WH) RESIDUAL SOURCE(S): ' See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT H: W00004609 FIELD#: NC-SU-00013-0-ONM- ANNUAL DRY TONS APPLIED: 9,28 SITE #: NC SU 00013 PREDOMINANT SOIL SERIES: WOOLW INE-FAIRVIEW CROP 1 MAX. PAN: 68 CROP 2 NAME: Page: 1 ACRES UTILIZED: 9.9 ACRES PERMITTED: 9.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Y Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- M'neral- Ammonia Nitrate PAN Applied Receiving Residual Dale or or Wet Tons (W) % Residual Dry, Wet, Pas124 Hrs. Application lization Izalion TIW Nitrogen and Nitrite (lbslac(e) Application Month Solids DryTcnslAC Source Moist Inches Method' Rate" Rate— mglkg mglkg mglkg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 1116/2020 74,400.00 (G) 2.990 0.937 WFFPL DRY "0- 1/2" SUR 0.5 0.30 66,000.00 13,400.00 163.00 42,490 WH I- Nov-20 74,400.00 (G) Total 0.937 10141 42,48U u.uuu WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law th t this document was prepared under my direction or supervision in accordance With a system designed to assure that qualified personnel properly gathered and evaluated Cite information submitted. I am aware that there are significan Ities f sing false information, including the possibility of fines and imhrisormiennt7-L t for knowing +violations." L! Zj SIGNATURE Of LAND APPLIER DATE NR = Not Repotted or Not Required "' Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge•0.4 ' Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation '"` C-P.L.R.: Cumulative Pollutant Loading Rate Volatilization Rate: Surface 0.5, Injectionllncorporation 1.0 ""' See Site pH & Lime Application Records Section of Report Printed: 2/112021 DEN FORM FSF (12/2006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Wayne Farms, L.L.C., NC Total Dry Tons Applied (Annual): WQ0004609 Walter Johnson Owner: 9.9 Acres Permitted: Cation Exchange Capacity (non 503 only): Walter Johnson Predominant Soil Series: 9.9 Site #: NC SU 00013 Field #: 9.28 Fairview SU 00013 0004 Residual Analysis Data (Heavy Metals and Total Phosphorus use mullzu. % Solids nco Raw P,-rrPnt ;Q)- Sample or Com- posite Date 1 1/23/20 21 [-31 LAT5 6 7 8 v 9 10 11 12 % Solids 2.99 Arsenic 16.7 Cadmium 3.33 Copper 530 Chromium 23.7 Lead 10 Mercury 0.487 Molyb- denum 8.33 Nickel 24.2 Selenium 16.7 Zinc 1040 Total Phos- hones 11200 .[Vutluai neavy ivieLat rtetu it oautnLys tt-aicuiarea in ins/acrei: Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ y o App. m Event 0.94 Arsenic 0.031 0.000 0.0oo 0.000 0.000 o.00o 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.993 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.993 Chromium 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Lead 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- denum 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.0I6 Nickel 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 o.000 0.000 0.000 0.000 0.045 Selenium 0.031 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Zinc 1.949 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.949 Total Phos- 20.989 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 20.989 hones i cerniy, uuuer Penalty of Law, roar tors uocumenr was prepares unaer my airection or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". ,L --2- - Signature of Land Applier Date FACILITY NAME: WAYNE FARMS, L.L.C., NC LANDOWNER: JAMES WALTER JOHNSON OPERATOR: JAMES WALTER JOHNSON CROP 1 NAME: WHEAT (WH) RFSIDUAL SOURCE(S): " See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0004609 FIELD#: NC-SU-00013.0-0006- ANNUAL DRY TONS APPLIED: 19.33 SITE #: NC SU 00013 PREDOMINANT SOIL SERIES: BRADDOCK CROP 1 MAX. PAN: 137 CROP 2 NAME: Page: 1 ACRES UTILIZED: 30.4 ACRES PERMITTED: 30.4 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs, Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids Dry TonslAc Source Moist Inches Method* Rate— Rate""'"' mglkg mg/kg mglkg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 3111/2020 130,200.00 (G) 2.990 0.534 WFFPL DRY "0- 112" SUR 0.5 0.30 66,000,00 13,400.00 163.00 24.215 WH 3/12/2020 24,800.00 (G) 2.990 0.102 WFFPL DRY "0-<112" SUR 0.5 0.30 66,000.00 13,400,00 163.00 4.612 WH Mar-20 155,000.00 (G) Total 0.636 iaLai co.ocr V.VVV AS CD CU CR PB HG MO NI 5E ZN P Lime Applied Annual Ibslacre Applied 0,021 0.004 0.674 0.030 0.013 <0.001 0.011 0.031 0.021 1.322 14.240 Date Lbs1Ac Cumulative Ibslacre Applied 0.051 0.021 3,079 0,232 0.072 0.005 0,077 0.183 0.068 8.211 Permit PAN Limit (Ibslacre) 1st Crap 137 Federal C.P.L.R. (Ibslacre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law, that t is document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penal or submitting false inforniation, including the possibility of Fines and imprisonment for knowing violations." -2z-z� SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *'* Mineralization Rates: Compost-G. 1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injectionllncorporation 1.0 **" See Site pH & Lime Application Records Section of Report Printed: 2/112021 DENR FORM FSF (12/2006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farins, L.L.C., NC Total Dry Tons Applied (Annual): Permit #: WQ0004609 Cation Exchange Capacity (non 503 only): Operator: Acres Used: Walter Johnson Owner: Walter Johnson Predominant Soil Series 30.4 Acres Permitted 30.4 Site #: NC SU 00013 Field #: 19.33 Braddock SU 00013 0006 Aesinual Analysis Data (Heavy Metals and 'Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or L 1 2 3 4 5 6 7 S 9 t0 11 12 Com- posite Date 1123I20 % Solids 2,99 Arsenic 16.7 Cadmium 3.33 Copper 530 Chromium 23.7 Lead 10 Mercury 0.487 Molyb- 8.33 denum Nickel 24.2 Selenium 16.7 Zinc 1040 Total Phos- 11200 horLIS Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ D App, w_ Event 0.64 Arsenic 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.021 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.674 0.000 0.000 0.000 0.D00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.674 Chromium 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Lead 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- denum 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Nickel 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Selenium 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Zinc 1.323 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.323 Total Phos- 14,246 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.246 hors "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and impriso ment for knowing violations". - 2- Signature of Land Applier Date FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OWNER: JOANN DUNBAR OPERATOR: WALTER JOHNSON CROP 1 NAME: FESCUE (FS) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0004609 FIELD#: NC-SU-00013-0-0010- ANNUAL DRY TONS APPLIED: 87.35 SITE #: NC SU 00013 PREDOMINANT SOIL SERIES: FAIRVIEW CROP 1 MAX. PAN: 188 CROP 2 NAME: Page: 1 ACRES UTILIZED: 42.9 ACRES PERMITTED: 42.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) %v Residual Dry, Wet, Past24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids Dry Ton51Ac Source Moist inches Method" Rate** Rate- mglkg mg/kg mg1k9 Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 10/5/2020 12,400.00 (G) 2.990 0,036 WFFPL DRY "0-<112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 1.634 FS 10/612020 37,200.00 (G) 2.990 0.108 WFFPL DRY "0-1112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 4.903 FS 10l712020 86.800.00 (G) 2.990 0.252 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000,00 13,400.00 163.00 11.440 FS 10/8/2020 12,400.00 (G) 2.990 0.036 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 1.634 FS 10/9/2020 55,800.00 (G) 2.990 0.162 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 7,354 FS 10119/2020 18,600.00 (G) 2.990 0.054 WFFPL I DRY 0-<112" SUR 0.5 0.30 66.000.00 13,400.00 163.00 2,451 FS 10/2112020 117,800.00 (G) 2.990 0.342 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 15,525 FS 10/2212020 117.800.00 (G) 2.990 0.342 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000-00 13,400.00 163.00 15.525 FS 10123/2020 155,000.00 (G) 2.990 0.450 WFFPL DRY 0-<112" SUR 0.5 0.30 66,000.00 13,400.00 163.00 20.428 FS Oct-20 613,800.00 (G) 12020 86,800.00 (G) 2.990 0.252 WFFPL DRY 0-<112" SUR 0.5 0.34 66,000.00 13,400.00 163.00 11.440v-20 FN, 86,800.00 (G) Total 2.034 " .. I-- AS CD CU CR PB KG MO NI SE ZN P Lime Applied Ibslacre Applied 0.068 0,014 2,158 0.097 0.041 0.002 0.034 0.099 0.068 4.235 45.611 Date Lbs1A Cumulative Ibslacre Applied 0.098 0.028 4.404 1 0.373 0.095 0.005 0.098 1 0.268 1 0.111 1 10.115 Permit PAN Limit (Ibslacre) 1st Crop 188 Federal C.P.L.R. (Ibslacre)"""""' 36.6 34.8 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 WFFPL= WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law, tha this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pen ti for sub mitf information, including the possibility of fines and imprisonment for knowing violations." _ z.z-Z NATURE OF LA IER DATE NR = Not Reported or Not Required '*+ Mineralization Rates: Compost-0.1, Anaeropically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 " Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P. L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5. Injectionllncorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/112021 DENR FORM FSF (1212006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Residual Analy Sample or 9 Com- posite Date l/23/20 % Solids Arsenic Cadmium Lead Mercury Molyb- Nickel Selenium Zinc Total Phos- Annual H Total DT/Ac./ App. Event Arsenic Cadmium Copper Lead Mercury Motyb- 2.99 16.7 3.33 530 23.7 10 0.487 8.33 24.2 16.7 1040 11200 2.03 0.068 0.014 2.156 0.096 0.041 0.002 Wayne Farms, L.L.C., NC Total Dry Tons Applied (Annual): 87.35 WQ0004609 Walter Johnson Owner: 42.9 Acres Permitted: Cation Exchange Capacity (non 503 only): Joann Dubar Predominant Soil Series: Fairview 42.9 Site #: NC SU 00013 Field #: SU 00013 0010 is Data (Heavy Metals and Total Phosphorus use Metal Field Loadings (Calculated in lbslacre): % Solids use Raw Percent #): I II 1 111 l l 1 11 1 11 !11 ! 111 1 11 ll 1 111NEENEENEEMEN 1 1 Ill 1 !11 !Ill 111 1 1! 1 II l 1! 1 Ill 1 !1 1!! l Ill I 1 1 111 1 111 1 111 Ill l !11 11i1 11! l 111 © l 111 ! 111 ! III ! 111 1 1 1 1 I11 1 1 11!! ! 11 I I11 1 111 1 11! 1 1 111 111 lilt 111 1111 1111 lill 111 1111 Il! llll I! 1 11 1 III 1 1 1 1 111 1 Ill 1 Ill 11 l 11 1 111 l l I 1 111 I Il 0.034 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.000 1 0.034 Nickel 1 0.098 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.098 Selenium 0.068 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.068 Zinc 4.231 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.231 Total Phos- 45.562 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 45.562 hOrr1S "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and impriso L for knowing violations". Signature of Land Applier Date ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: WAYNE FARMS, L.L.C., NC WQ PERMIT P WQ0004609 FIELD#: NC-SU-00021-0-0001- ACRES UTILIZED: 20.4 LANDOWNER: RUBEN GOLDING ANNUAL DRY TONS APPLIED: 7.73 SITE* NC SU 00021 ACRES PERMITTED: 20.4 OPERATOR: RUBEN & MITZI GOLDING PREDOMINANT SOIL SERIES: CLIFFORD CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE HAY (FSH) CROP 1 MAX. PAN: 209 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Date or Month Gallons (G) or Cubic Yards (Y) or Wet Tons (W) Amount UOM % Solids Dry TonslAc Residual Source Site Cond. Dry, Wet, Moist Precip Past 24 Hrs. Inches Application Method* Volati- lization Rate** Mineral- ization Rate*** TKN mglkg Ammonia Nitrogen mglkg Nitrate and Nitrite mglkg PAN Applied (Ibslacre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/912020 49,600.00 (G) 2.990 0.303 WFFPL DRY "0-a112" SUR 0.5 0.30 66,000.00 13,400,00 163.00 13.747 FSH 3/1212020 12,400.00 (G) 2.990 0.076 WFPPL DRY "o-1I2" SUR 0.5 0,30 66,000.00 13,400.00 163,00 3.437 FSH Mar-20 62,000.00 (G) Total 0.379 Total 17.184 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibslacre Applied 0.013 0.003 0.4D2 0.018 0.008 �0.001 0.006 0.018 D.013 0.788 8.488 Date LbslAc Cumulative Ibslacre Applied 0.013 0.003 1 0A02 1 0.018 0,008 <0.001 0.006 1 0.018 0.013 J 0.788 Permit PAN Limit (lbs/acre) 1st Crop 209 Federal C.P.L.R. (Ibslacre)**** 36.6 34.8 1 1,339.0 267.9 15.0 375.0 1 89.0 1 2,500.0 W FFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID 7 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pen i s for suUmittin Ise information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - injection, SURIN - Incorporation *** C.P.L.R.: Cumulative Pollutant Loading Rate '* Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***" See Site pH & Lime Application Records Section of Report Printed: 2I1412021 DENR FORM FSF (1212006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, L.L.C., NC Total Dry Tons Applied (Annual): 7.73 Permit #: WQ0004609 Cation Exchange Capacity (non 503 only): Operator: Ruben Golding Owner: Ruben Golding Predominant Soil Series: Clifford Acres Used: 20.4 Acres Permitted: 20.4 Site #: NC SU 00021 Field #: SU 00021 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or 1 Com- posite Date 1/23/20 % Solids 2.99 Arsenic 16.7 Cadmium 3.33 Copper 530 Chromium 23.7 Lead 10 Mercury 0.487 Molyb- 8.33 denuin Nickel 1 24.2 Selenium 16.7 Zinc 1040 Total Phos- 11200 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 1 L2 3 4 5 6 7 8 9 10 11 12 y DT/Ac./ m App Event 0.37 Arsenic 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.392 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.392 Chromium0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 o.000 0.000 .0.000 0.000 0.018 Lead 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.00o o.000 0.000 0.000 0.006 denum Nickel 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Selenium 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Zinc 0.770 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.770 Total Phos- 8.288 0.000 O.D00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.288 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisoninent for knowing violations". Signature of Land Applier Date FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OWNER: BEN WATSON OPERATOR: BEN WATSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT#: WQ0004609 FIELD#: NC-SU-00022-0-0001- ANNUAL DRY TONS APPLIED: 27.83 SITE #: NC SU 00022 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 151 CROP 2 NAME: Page: 1 ACRES UTILIZED: 12.8 ACRES PERMITTED: 12.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids Dry Tons1Ac Source Moist Inches Method" Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crap 1 Crop 2 Crop 1 Crop 2 1/2/2020 62.000.00 (G) 2.990 0.604 WFFPL MOIST "0-<1l2" SUR 0.5 0.30 66,000.00 13,400.00 163.00 27.386 FSH Jan-20 62,000.00 (G) 302020 161,200.00 (G) 2.990 1.570 WFFPL MOIST "0-<1/2" SUR 6.5 0.30 66,000.00 13,400.00 163.00 71.203 FSH Mar-20 1 161,200.00 (G) i alai c.-i f % Total 98.589 0.000 AS CD CU CR PB FIG MO NI SE ZN P Lime Applied Annual Ibslacre Applied 0.073 1 0.014 2.305 0.103 0.043 0.002 0.036 1 0.105 0.073 4.522 48.701 1 1 Date I LbslAc Applied 0.073 1 0.014 1 2.305 1 0.103 1 0.043 1 0.002 1 0.036 1 0,105 1 0.073 1 4.522 Permit PAN Limit (Ibslacre) 1st Crop .... 151 Federal C.P.L.R. (Ibslacre)**** 36.6 34.8 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, tinder penalty of law, that Allis document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. i am aware that there are significant pena ' for sub i ' se r ation, including the possibility of fines and imp ri ment nowing violations." _2( SI NATURE OF LAND APPLIER DATE NR = Not Reported or Not Required **' Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobfcally digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation '*** C.P.L.R.: Cumulative Pollutant Loading Rate '* Volatilization Rate: Surface 0.5, Injectionlincorporation 1.0 **** See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DENR FORM FSF (1212006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, L.L.C., NC Total Dry Tons Applied (Annual): Permit #: WQ0004609 Cation Exchange Capacity (non 503 only): Operator: Ben Watson Owner: Acres Used: 12.8 Acres Permitted: Ben Watson Predominant Soil Series: 12.8 Site #: NC SU 00022 Field #: 27.83 Clifford SU 00022 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg. % Solids use Raw Prrrent 4)- Sample or L2J L 3 j L4 5 6 7 8 9 7 i1 1 12 Com- posite Date 1 /23/20 % Solids 2.99 Arsenic 16.7 Cadmium 3.33 Copper 530 Chromium 23.7 Lead 10 Mercury 0.487 Molyb- 8.33 denum Nickel 24.2 Selenium 16.7 Zinc 1040 Total Phos- 11200 horus Annuai Heavy Metal yield Loadings (Ualculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9j 10 11 12 DT/Ac.l 0 App. a' Event 2.17 Arsenic 0.073 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.073 Cadmium 0.014 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Copper 2.304 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.304 Chromiurn 0.103 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.103 Lead 0.043 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.043 Mercury O M2 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- denum 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Nickel 0.105 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.105 Selenium 0.073 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.073 Zinc 4.522 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.522 Total Phos- 48.698 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 48.698 Moms "I certify, under penalty of law, that this document was prepared under my direction or supervision in arrnrrlanrP with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and impriso ent for knowing violations". Signature of Land Applier Date FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OW NER: MAX & PEGGY W ALL OPERATOR: MAX WALL CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: W Q0004609 FIELD#: NC-SU-00023-0-0001- ANNUAL DRY TONS APPLIED: 29.38 SITE #: NC SU 00023 PREDOMINANT SOIL SERIES: BRADDOCK CROP 1 MAX. PAN: 247 CROP 2 NAME: Page: 1 ACRES UTILIZED: 13.7 ACRES PERMITTED: 13.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbslacre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate"* Rate'*' mglkg mglkg mg/kg Amount I UOM Crop 1 Crop 2 Crop 1 Crop 2 3/5/2020 148,800.00 (G) 2.990 1.354 WFFPL MOIST 1 "0_<112" SUR 0.5 0.30 66.000.00 13,400.00 163.00 61.408 FSP 3/912020 86,800.00 (G) 2.990 0.79C WFFPL MOIST "0-<112" SUR 0.5 0.30 66,000,00 13.400.00 163.00 35.822 FSP Mar-20 235,600.00 (G) Total 2A44 • •,•"• _. •--- -•"-- AS I CD CU CR PB HG MO NI SE ZN P L lbslacre Applied 0.072 1 0.014 2.273 0.102 0,043 0,002 0,036 0.104 10.072 4.460 46.030 Date Cumulative Ibs/acre Applied 0.072 0.014 2.273 0.102 0.043 0.002 0.036 0.104 0.072 4,460 Permit PAN Limit (lbslacre) 1st Crop 247 Federal C.P.L.R. (lbslacre)**" 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 W FFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law, that t is ocument repared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.) am aware that there are significant penal s or sub ittin false inf anon, including the possibility of fines and imprisonment for knowing violations." 2 -z z --z SI ATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *'* Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **`* C.P.L.R.: Cumulative Pollutant Loading Rate '* Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 See Site pH & Lime Application Records Section of Report Printed: 2/1/2021 DFNR FORM FSF (12/2006) Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Wayne Farms, L.L.C., NC Total Dry Tons Applied (Annual): 29.38 Permit #: WQ0004609 Cation Exchange Capacity (non 503 only): Operator: Max Wall Owner: Max Wall Predominant Soil Series: Braddock Acres Used: 13.7 Acres Permitted: 13.7 Site #: NC SU 00023 Field #: SU 00023 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg. % Solids use Raw Percent #): Sample or L 11 L2]3 4 5 j L6 7 L9 1p 11 12 Com- posite Date 1/23/20 % Solids 2.99 Arsenic 16.7 Cadmium 3.33 Copper 530 Chromium 23.7 Lead 10 Mercury 0.487 Molyb- 8.33 denum Nickel 24.2 Selenium 16.7 Zinc 1040 Total Phos- 11200 hones Annual Heavy Metal Field Loadings (Calculated in lbslacre): Tota] 1 11 L2 3 [__4_F 5 6 7 8 9 9 Q 1 12 DT/Ac.l -i 0 App. °r Event 2.14 Arsenic 0.072 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.072 Cadmium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.014 Copper 2.273 0.000 0.000 0-000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.273 Chromium 0.102 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.102 Lead 0.043 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.043 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- denum 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 Nickel 0.104 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.104 Selenium 0.072 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.072 Zinc 4.460 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 4.460 Total Phos- 48.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 48.026 horus r-T 1 ceruiy, under penaity of iaw, tnat tors document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". ar ',;Z-z_ 97,_ - �J, Signature of Land Applier Date SECTION 4 SUMM111 ENVIRONMENTAL TECHNOLOMZ3. INC ArrzrJy0ca1 Laboralorfas August 21, 2019 Nate Roth Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Wayne Farms Dear Nate Roth: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com Order No.: 19071834 Summit Environmental Technologies, Inc. received 1 sample(s) on 7/26/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAT CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH00923201 1 -1, Virginia VELAP 9456, Washington C891 Page 1 of 36 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL rEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 Wo#: 19071834 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 8/21/2019 CLIENT: Synagro Project: Wayne Farms WorkOrder Narrative: 19071834: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 19071834-OOIA TCLP-SVOC_8270E: Surrogate recovery was outside of the laboratory established acceptance criteria for: p-Terphenyl-dl4. All other surrogates exhibited recoveries within the acceptance cntena. Original Page 2 of 36 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S Ekiwlt OMM@N-rALTECHN❑LOG{r,S,INC Cuyahoga Falls, Ohio442� WO#: 19071834 ArralyUcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-446 Wehsite: httn:11www.settek.co, Date: 8/21/2019 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low () or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low () or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low () or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low () or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIROMM@NtaL YECHNO ijULES.INC. Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Wayne Farms Lab SampleID Client Sample ID 19071834-001 Wayne Farms Tag No Date Collected 7/25/2019 9:00:00 AM Workorder Sample Summary WO#: 19071834 2l Aug-l9 Date Received Matrix 7/26/2019 9:50:00 AM Sludge Page 4 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES "PORT ENVIRON M ENTAL 1 ECHNO L0G1E5,1rJG Cuyahoga Falls, Ohio 44223 WO#: 19071834 ArWyft cal tai5oralonas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 21Aug-19 Client: Synagro Project: Wayne Farms Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19071834-OOIA Wayne Farms 7/25/2019 9:00:00 AM Sludge Flashpoint Determination (1010) 7/31/2019 12:01:41 PM pH (SW9045D) 7/29/2019 3:21:02 PM Reactive Cyanide (9014/7.3.32)-Solid 7/31/2019 12:26:00 PM Reactive Sulfide (9034)/7.3.42 7/31/2019 12:26:00 PM TCLP Herbicides Analysis (SW1311/8 8/7/2019 12:15:00 PM 8/13/2019 5:34:00 PM solid TCLP Mercury Analysis (SW1311/74 i 8/1/2019 5:00:00 PM 8/2/2019 2:40:00 PM 8/2/2019 5:29:00 PM TCLP Metals Analysis (SW1311/6010 8/1/2019 5:00:00 PM 8/5/2019 9:30:00 AM 8/5/2019 6:03:12 PM TCLP Pesticides Analysis (SW1311/8(8/l/2019 5:00:00 PM 8/6/2019 11:10:00 AM 8/6/2019 4:13:00 PM TCLP Semi-Volatiles Analysis 8/1/2019 5:00:00 PM 8/5/2019 1:00:00 PM 8/6/2019 6:13:00 PM (SW1311/8270) TCLP Volatiles Analysis 8/5/2019 2:00:00 PM TCLP Volatiles Analysis 8/1/2019 5:00:00 PM 8/5/2019 2:00:00 PM Original Page 5 of 36 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19071834 Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND TCLP Barium(Ba) ND TCLP Cadmium(Cd) ND TCLP Chromium(Cr) ND TCLP Lead(Pb) ND TCLP Selenium(Se) ND TCLP Silver(Ag) ND FLASHPOINT DETERMINATION (1010) Flashpoint (140°F) ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 2,4,5-Trichlorophenol ND 2,4,6-Trichlorophenol ND 2,4-Dinitrotoluene ND Cresols, Total ND Hexachloro-1,3-butadiene ND Hexachlorobenzene ND Hexachloroethane ND Nitrobenzene ND Pentachlorophenol ND Pyridine ND Surr: 2-Fluorophenol 20.7 Surr: Phenol-d6 26.9 Surr: Nitrobenzene-d5 24.2 SW7470A SW7470A Analyst: DNS 0.00500 mg/L 1 8/2/2019 5:29:00 PM SW6010D SW301OA Analyst: EAM 0.500 mg/L 1 8/5/2019 6:03:12 PM 5.00 mg/L 1 8/5/2019 6:03:12 PM 0.100 mg/L 1 8/5/2019 6:03:12 PM 0.200 mg/L 1 8/5/2019 6:03:12 PM 0.500 mg/L 1 8/5/2019 6:03:12 PM 0.0500 mg/L 1 8/5/2019 6:03:12 PM 0.500 mg/L 1 8/5/2019 6:03:12 PM SW1010 Analyst: TAH °F 1 7/31/201912:01:41 PM SW8270 SW351OC Analyst: BJH 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.100 mg/L 2 8/6/2019 6:13:00 PM 10.0 mg/L 2 8/6/2019 6:13:00 PM 0.0400 mg/L 2 8/6/2019 6:13:00 PM 0.100 mg/L 2 8/6/2019 6:13:00 PM 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 10 - 109 %Rec 2 8/6/2019 6:13:00 PM 10 - 109 %Rec 2 8/6/2019 6:13:00 PM 19 - 120 %Rec 2 8/6/2019 6:13:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CalcVal <MDL Page 6 of 36 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVITtONMENTALTECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19071834 Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: 2,4,6-Tribromophenol 27.0 10 - 120 %Rec Surr: 2-Fluorobiphenyl 24.7 22 - 117 %Rec Surr: p-Terphenyl-d14 25.9 34 - 116 S %Rec TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 47.1 Surr: DCB 50.1 SW8270 SW351OC Analyst: BJH 2 8/6/2019 6:13:00 PM 2 8/6/2019 6:13:00 PM 2 8/6/2019 6:13:00 PM SW8081 SW351OC Analyst: MES 0.0250 mg/L 10 8/6/20194:13:00 PM 0.0500 mg/L 10 8/6/20194:13:00 PM 0.00500 mg/L 10 8/6/20194:13:00 PM 0.00500 mg/L 10 8/6/20194:13:00 PM 0.00500 mg/L 10 8/6/20194:13:00 PM 0.00500 d mg/L 10 8/6/20194:13:00 PM 0.00500 d mg/L 10 8/6/20194:13:00 PM 10 - 119 %Rec 10 8/6/2019 4:13:00 PM 10 - 119 %Rec 10 8/6/2019 4:13:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP HERBICIDES ANALYSIS (SW1311/8151)-SOLID 2,4-D ND 0.0100 2,4,5-TP ND 0.00500 Surr: DCAA 99.9 20 - 140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1,2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8151A SW8151A Analyst: MES d mg/L 1 8/13/2019 5:34:00 PM mg/L 1 8/13/2019 5:34:00 PM %Rec 1 8/13/2019 5:34:00 PM SW8260 Analyst: CTB 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 5.00 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 2.50 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CalcVal <MDL Page 7 of 36 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.com Analytical Report (base report) WO#: 19071834 Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: CTB TCLP VOLATILES ANALYSIS Trichloroethene ND 0.250 mg/L 50 8/5/2019 2:00:00 PM Vinyl chloride ND 0.100 mg/L 50 8/5/2019 2:00:00 PM Surr: 4-Bromofluorobenzene 93.9 70 - 130 %Rec 50 8/5/2019 2:00:00 PM Surr: Dibromofluoromethane 97.3 70 - 130 %Rec 50 8/5/2019 2:00:00 PM Surr: Toluene-d8 97.0 70 - 130 %Rec 50 8/5/2019 2:00:00 PM RCISOLID-W/ IGNITABILITY1030 SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.490 mg/Kg 1 7/31/2019 12:26:00 PM RCISOLID-W/ IGNITABILITY1030 SW9045D Analyst: VVK PH (SW9045D) pH 6.7 s.u.@20.00 1 7/29/2019 3:21:02 PM RCISOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 7/31/2019 12:26:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CalcVal <MDL Page 8 of 36 Summit Environmental Technologies, Inc. Accreditation Program fr 3310 Win St. summlmr Anal tes Report Y ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 Y Arralytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19071834 Wehsite: http://www.settek.com 21Aug-l9 Client: Synagro State: NW Project: Wayne Farms Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 19071834-OOIA Sludge Flashpoint Determination (1010) Flashpoint (140°F) A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.32)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.42 Sulfide, Reactive U Sludge TCLP Herbicides Analysis (SW1311/8151)-solid 2,4,5-TP A Sludge TCLP Herbicides Analysis (SW1311/8151)-solid 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Version #2 Page 9 of 36 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal tes Report Y EMOROMMEWAL YECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19071834 Wehsite: http://www.settek.com 21Aug-l9 Client: Synagro State: NW Project: Wayne Farms Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 19071834-OOIA Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Version #2 Page 10 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38679 Sample ID MB-38679 SampType: MBLK TestCode: TCLP-voc-M Units: %Rec Prep Date: 8/1/2019 RunNo: 101545 Client ID: PBS Batch ID: 38679 TestNo: SW8260 SW1311M Analysis Date: 8/2/2019 SegNo: 2253693 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr:4-Bromofluorobenzene 509 500.0 102 70 130 Surr: Dibromofluoromethane 500 500.0 100 70 130 Surr: Toluene-d8 498 500.0 99.6 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38692 TCLP Mercury ND 0.00200 TCLP Mercury 0.00403 0.00200 0.00400 0 101 80 120 TCLP Mercury ND 0.00200 Sample ID 19071918-002AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254325 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00258 0.00200 0.00400 0 64.5 75 125 S Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38692 Sample ID 19071918-002AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254325 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID 19071918-002AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254328 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual FCLP Mercury 0.00214 0.00200 0.00400 0 53.5 75 125 0.00258 18.6 20 S Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 13 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38702 Sample ID MB-38702 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: PBS Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257435 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-38702 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: LCSS Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257436 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.89 0.500 2.000 0 94.7 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 101 80 120 TCLP Cadmium(Cd) 1.77 0.100 2.000 0 88.5 80 120 TCLP Chromium(Cr) 2.01 0.200 2.000 0 100 80 120 TCLP Lead(Pb) 2.02 0.500 2.000 0 101 80 120 TCLP Selenium(Se) 1.89 0.0500 2.000 0 94.3 80 120 TCLP Silver(Ag) 2.08 0.500 2.000 0 104 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38702 Sample ID 19072115-004AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: Batch= Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257448 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.32 0.500 2.000 0 116 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2739 102 70 130 TCLP Cadmium(Cd) 2.03 0.100 2.000 0 102 70 130 TCLP Chromium(Cr) 2.10 0.200 2.000 0.0009437 105 70 130 TCLP Lead(Pb) 2.16 0.500 2.000 0 108 70 130 TCLP Selenium(Se) 2.43 0.0500 2.000 0 122 70 130 TCLP Silver(Ag) 2.32 0.500 2.000 0 116 70 130 Sample ID 19072115-004AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: Batch= Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257449 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.28 0.500 2.000 0 114 70 130 2.315 1.47 20 TCLP Barium(Ba) ND 5.00 2.000 0.2739 99.2 70 130 0 0 20 TCLP Cadmium(Cd) 1.98 0.100 2.000 0 99.0 70 130 2.032 2.63 20 TCLP Chromium(Cr) 2.04 0.200 2.000 0.0009437 102 70 130 2.096 2.53 20 TCLP Lead(Pb) 2.13 0.500 2.000 0 106 70 130 2.159 1.51 20 TCLP Selenium(Se) 2.40 0.0500 2.000 0 120 70 130 2.430 1.36 20 TCLP Silver(Ag) 2.26 0.500 2.000 0 113 70 130 2.317 2.45 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID mb-38719 SampType: MBLK TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 client ID: PBS Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2258308 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0.100 2,4,6-Trichlorophenol ND 0.100 2,4-Dinitrotoluene ND 0.0200 o-Cresol ND 0.100 Cresols, Total ND 2.00 Hexachloro-1,3-butadiene ND 0.00800 Hexachlorobenzene ND 0.0200 Hexachloroethane ND 0.0400 Nitrobenzene ND 0.0400 Pentachlorophenol ND 0.100 Pyridine ND 0.100 Surr: 2-Fluorophenol 0.395 Surr: Phenol-d6 0.430 Surr: Nitrobenzene-d5 0.400 Surr: 2,4,6-Tribromophenol 0.456 Surr: 2-Fluorobiphenyl 0.362 Surr: p-Terphenyl-d14 0.518 1.000 39.5 10 109 1.000 43.0 10 109 1.000 40.0 19 120 1.000 45.6 10 120 1.000 36.2 22 117 1.000 51.8 34 116 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID Ics-38719 SampType: LCS TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: LCSS Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2258309 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.423 0.0400 0.8000 0 52.9 36.4 130 2,4,5-Trichlorophenol 0.523 0.100 0.8000 0 65.3 31.7 132 2,4,6-Trichlorophenol 0.500 0.100 0.8000 0 62.5 31.1 133 2,4-Dinitrotoluene 0.532 0.0200 0.8000 0 66.5 43.3 130 o-Cresol 0.532 0.100 0.8000 0 66.5 32.9 130 Cresols, Total ND 2.00 1.600 0 66.7 31.7 130 Hexachloro-1,3-butadiene 0.421 0.00800 0.8000 0 52.6 31.4 130 Hexachlorobenzene 0.435 0.0200 0.8000 0 54.4 43.1 130 Hexachloroethane 0.423 0.0400 0.8000 0 52.9 36.5 130 Nitrobenzene 0.541 0.0400 0.8000 0 67.7 39.5 130 Pentachlorophenol 0.528 0.100 0.8000 0 66.0 34 130 Pyridine 0.349 0.100 0.8000 0 43.6 10 130 Surr: 2-Fluorophenol 0.556 1.000 55.6 17.1 130 Surr: Phenol-d6 0.640 1.000 64.0 10 130 Surr: Nitrobenzene-d5 0.616 1.000 61.6 32.6 130 Sum 2,4,6-Tribromophenol 0.632 1.000 63.2 4.43 130 Sum 2-Fluorobiphenyl 0.544 1.000 54.4 41.8 130 Surr: p-Terphenyl-d14 0.572 1.000 57.2 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID 19072156-001ams SampType: MS TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: Batch= Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2261123 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.546 0.0800 0.8000 0 68.2 33.8 126 2,4,5-Trichlorophenol 0.643 0.200 0.8000 0 80.4 28.7 144 2,4,6-Trichlorophenol 0.598 0.200 0.8000 0 74.7 12.8 153 2,4-Dinitrotoluene 0.658 0.0400 0.8000 0 82.2 20.4 155 o-Cresol 0.681 0.200 0.8000 0 85.2 10 148 Cresols, Total ND 4.00 1.600 0 86.4 10 148 Hexachloro-1,3-butadiene 0.528 0.0160 0.8000 0 66.1 29 126 Hexachlorobenzene 0.500 0.0400 0.8000 0 62.4 33.7 134 Hexachloroethane 0.560 0.0800 0.8000 0 70.0 32.8 132 Nitrobenzene 0.696 0.0800 0.8000 0 87.0 20 158 Pentachlorophenol 0.693 0.200 0.8000 0 86.7 10 176 Pyridine 0.430 0.200 0.8000 0 53.7 10 130 Surr: 2-Fluorophenol 0.741 1.000 74.1 3.39 130 Surr: Phenol-d6 0.816 1.000 81.6 5 130 Surr: Nitrobenzene-d5 0.791 1.000 79.1 14.5 154 Surr: 2,4,6-Tribromophenol 0.752 1.000 75.2 19.5 130 Sum 2-Fluorobiphenyl 0.665 1.000 66.5 34.4 130 Surr: p-Terphenyl-d14 0.751 1.000 75.1 8.86 156 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID 19072156-001amsd SampType: MSD TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: Batch= Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2261124 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.547 0.0800 0.8000 0 68.4 33.8 126 0.5460 0.220 30 2,4,5-Trichlorophenol 0.686 0.200 0.8000 0 85.7 28.7 144 0.6432 6.38 30 2,4,6-Trichlorophenol 0.643 0.200 0.8000 0 80.4 12.8 153 0.5976 7.29 30 2,4-Dinitrotoluene 0.648 0.0400 0.8000 0 81.0 20.4 155 0.6580 1.59 30 o-Cresol 0.684 0.200 0.8000 0 85.6 10 148 0.6812 0.469 30 Cresols, Total ND 4.00 1.600 0 86.2 10 148 0 0 30 Hexachloro-1,3-butadiene 0.559 0.0160 0.8000 0 69.8 29 126 0.5284 5.59 30 Hexachlorobenzene 0.536 0.0400 0.8000 0 67.0 33.7 134 0.4996 7.10 30 Hexachloroethane 0.532 0.0800 0.8000 0 66.5 32.8 132 0.5600 5.20 30 Nitrobenzene 0.712 0.0800 0.8000 0 89.0 20 158 0.6956 2.27 30 Pentachlorophenol 0.765 0.200 0.8000 0 95.7 10 176 0.6932 9.87 30 Pyridine 0.542 0.200 0.8000 0 67.8 10 130 0.4296 23.2 30 Sum 2-Fluorophenol 0.740 1.000 74.0 3.39 130 0 Surr: Phenol-d6 0.830 1.000 83.0 10 130 0 Surr: Nitrobenzene-d5 0.776 1.000 77.6 14.5 154 0 Surr: 2,4,6-Tribromophenol 0.745 1.000 74.5 19.5 130 0 Sum 2-Fluorobiphenyl 0.690 1.000 69.0 34.4 130 0 Surr: p-Terphenyl-d14 0.756 1.000 75.6 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38740 Sample ID 19080252-001ams SampType: MS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: Batch= Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260684 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00544 0.00500 0.0100 0 54.4 10 224 gamma-BHC ND 0.00500 0.0100 0 45.1 10 192 Heptachlor ND 0.00500 0.0100 0 0 10 197 S Heptachlor epoxide ND 0.00500 0.0100 0 42.8 10 208 Methoxychlor ND 0.00500 0.0100 0 32.1 10 251 Surr: TCMX 7.01 20.00 35.1 10 157 Surr: DCB 9.22 20.00 46.1 10 194 Sample ID 19080252-001amsd SampType: MSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: Batch= Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260686 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00741 0.00500 0.0100 0 74.1 10 224 0.00544 30.6 gamma-BHC 0.00618 0.00500 0.0100 0 61.8 10 192 0.00451 31.2 Heptachlor ND 0.00500 0.0100 0 0 10 197 0 0 Heptachlor epoxide 0.00630 0.00500 0.0100 0 63.0 10 208 0.00428 38.0 Methoxychlor ND 0.00500 0.0100 0 49.7 10 251 0 0 Surr: TCMX 9.48 20.00 47.4 10 157 0 Surr: DCB 12.5 20.00 62.5 10 194 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco 30 R 30 R 30 S 30 R 30 R Original Page 20 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38740 Sample ID mb-38740 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: PBS Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260868 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 d gamma-BHC ND 0.000500 d Heptachlor ND 0.000500 d Heptachlor epoxide ND 0.000500 d Methoxychlor ND 0.000500 d Surr: TCMX 10.3 20.00 51.7 10 119 Surr: DCB 10.5 20.00 52.3 10 119 Sample ID Ics-38740 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: LCSS Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260869 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00395 0.000500 0.0100 0 39.5 20 216 gamma-BHC 0.00268 0.000500 0.0100 0 26.8 20 197 Heptachlor 0.00243 0.000500 0.0100 0 24.3 20 200 Heptachlor epoxide 0.00348 0.000500 0.0100 0 34.8 20 200 Methoxychlor 0.00330 0.000500 0.0100 0 33.0 20 227 Surr: TCMX 5.46 20.00 27.3 20 143 Surr: DCB 5.57 20.00 27.9 20 151 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response P Second column confirmation exceeds RL Reporting Detection Limit H Holding times for preparation or anal, MC Value is below Minimum Compound PL Permit Limit S Spike Recovery outside accepted reco Original Page 21 of 36 SUMM' Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMENTALTECHNOWgiiES,INC Cuyahoga Falls, Ohio44223 WO#: 19071834 Anjiyt�caf iaboraforlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38780 2,4-D ND 0.0100 0 0 2,4,5-TP ND 0.00500 0 0 Surr: DCAA 409 500.0 81.8 20 140 m 2,4-D 0.419 0.0100 0.500 0 83.9 43.8 130 2,4,5-TP 0.355 0.00500 0.500 0 71.0 51.5 ill Surr: DCAA 472 500.0 94.3 34.2 150 Sample ID LCSD-38780 SampType: LCSD TestCode: tclp-svoc-her Units: mg/L Prep Date: 817/2019 RunNo: 101987 Client ID: LCSS02 Batch ID: 38780 TestNo: SW8151A SW8151A Analysis Date: 8/13/2019 SegNo: 2274711 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.477 0.0100 0.500 0 95.5 43.8 130 0.419 12.9 30 2,4,5-TP 0.344 0.00500 0.500 0 68.8 51.5 130 0.355 3.11 30 Surr: DCAA 463 500.0 92.6 34.2 150 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@21.2 Prep Date: RunNo: 101322 Client ID: LCSS Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241818 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID LCS-R101322 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@20.6C Prep Date: RunNo: 101322 Client ID: LCSW Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241117 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 90 110 Sample ID CHECK 7 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@20.6C Prep Date: RunNo: 101322 Client ID: LCSW Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241138 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 24 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID 19071527-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@20.6C Prep Date: RunNo: 101322 client ID: BatchQC Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241137 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 11.9 0.5 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101417 Sample ID LCS-R101417 SampType: LCS TestCode: FlashPt_S(10 Units: °F Prep Date: RunNo: 101417 Client ID: LCSS Batch ID: R101417 TestNo: SW1010 Analysis Date: 7/31/2019 SegNo: 2246281 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Flashpoint (140°F) 136 135.4 0 100 98 102 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101441 Cyanide, Reactive ND 0.495 Cyanide, Reactive 9.25 0.490 10.00 0 92.5 85 110 Cyanide, Reactive 9.43 0.490 10.00 0 94.3 81.6 122 Sample ID 19071654-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 101441 Client ID: Batch= Batch ID: R101441 TestNo: SW9014 Analysis Date: 7/31/2019 SegNo: 2247614 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.41 0.490 10.00 0 94.1 81.6 122 9.427 0.208 5 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101441 Sample ID 19071654-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 101441 -Iient ID: Batch= Batch ID: R101441 TestNo: SW9014 Analysis Date: 7/31/2019 SegNo: 2247614 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101444 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4780 25.0 4800 0 99.6 85 115 Sulfide, Reactive 4670 25.0 4800 0 97.3 80 120 Sample ID 19071654-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 101444 Client ID: Batch= Batch ID: R101444 TestNo: SW9034 Analysis Date: 7/31/2019 SegNo: 2247640 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4640 25.0 4800 0 96.7 80 120 4670 0.644 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 29 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101444 Sample ID 19071654-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 101444 -Iient ID: Batch= Batch ID: R101444 TestNo: SW9034 Analysis Date: 7/31/2019 SegNo: 2247640 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 30 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID LCS-101627 SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: LCSW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284872 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.0196 0.00500 0.0200 0 98.0 70 138 1,2-Dichloroethane 0.0194 0.00500 0.0200 0 96.9 70 130 MEK 0.0951 0.0250 0.100 0 95.1 70 130 Benzene 0.0190 0.00500 0.0200 0 95.1 70 132 Carbon tetrachloride 0.0187 0.00500 0.0200 0 93.3 70 130 Chlorobenzene 0.0197 0.00500 0.0200 0 98.4 10 255 Chloroform 0.0185 0.00500 0.0200 0 92.5 47.7 141 Tetrachloroethene 0.0193 0.00500 0.0200 0 96.7 10 130 Trichloroethene 0.0197 0.00500 0.0200 0 98.5 70 130 Vinyl chloride 0.0175 0.00200 0.0200 0 87.6 70 130 Surr: 4-Bromofluorobenzene 50.6 50.00 101 70 130 Surr: Dibromofluoromethane 49.7 50.00 99.4 70 130 Surr: Toluene-d8 50.0 50.00 99.9 70 130 Sample ID MBLK-101627 SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: PBW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284873 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 31 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID MBLK-101627 SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: PBW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284873 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Bromofluorobenzene 47.4 Surr: Dibromofluoromethane 48.0 Surr: Toluene-d8 49.2 50.00 94.8 70 130 50.00 96.1 70 130 50.00 98.3 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 32 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID 19072156-00laMS SampType: MS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272450 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.184 0.0500 0.200 0 92.0 39.9 160 1,2-Dichloroethane 0.197 0.0500 0.200 0 98.4 42.5 157 MEK ND 1.00 1.00 0 95.4 16.6 227 Benzene 0.182 0.0500 0.200 0 90.9 38.1 155 Carbon tetrachloride 0.153 0.0500 0.200 0 76.5 40.8 162 Chlorobenzene ND 0.500 0.200 0 94.8 35.7 168 Chloroform 0.180 0.0500 0.200 0 90.2 18.3 199 Tetrachloroethene 0.162 0.0500 0.200 0 80.8 10 261 Trichloroethene 0.175 0.0500 0.200 0 87.6 23.8 175 Vinyl chloride 0.157 0.0200 0.200 0 78.6 10 165 Surr:4-Bromofluorobenzene 512 500.0 102 84.6 130 Surr: Dibromofluoromethane 494 500.0 98.8 71.4 127 Surr: Toluene-d8 508 500.0 102 74.6 127 Sample ID 19072156-00laMSD SampType: MSD TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272451 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.182 0.0500 0.200 0 91.0 39.9 160 0.184 1.04 25 1,2-Dichloroethane 0.208 0.0500 0.200 0 104 42.5 157 0.197 5.54 25 MEK ND 1.00 1.00 0 97.2 16.6 227 0 0 25 Benzene 0.187 0.0500 0.200 0 93.6 38.1 155 0.182 2.93 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 33 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID 19072156-00laMSD SampType: MSD TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272451 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.148 0.0500 0.200 0 73.8 40.8 162 0.153 3.53 25 Chlorobenzene ND 0.500 0.200 0 97.8 35.7 168 0 0 25 Chloroform 0.192 0.0500 0.200 0 96.1 18.3 199 0.180 6.28 25 Tetrachloroethene 0.164 0.0500 0.200 0 82.0 10 261 0.162 1.54 25 Trichloroethene 0.180 0.0500 0.200 0 90.2 23.8 175 0.175 2.81 25 Vinyl chloride 0.150 0.0200 0.200 0 74.8 10 165 0.157 4.95 25 Surr:4-Bromofluorobenzene 486 500.0 97.1 84.6 130 0 25 Surr: Dibromofluoromethane 506 500.0 101 71.4 127 0 25 Surr: Toluene-d8 509 500.0 102 74.6 127 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 34 of 36 S■.umrmit Environmental Technologies, Inc. Analysis Request/Chain of Custody ffl 33 10 Win Street Pnr Suluttiit Enviammenta! TeUhnologies, CLryahoga Faik. Ohio 44223 Tel: 330.253.8211 Fax: 330.253,4489 Puge_ of - A . P1 P ntl ['-ajcci game Analyfica P�rgrneters and Methods Company Name i mouse n Company Prujerl .4drE .Rti Clicnl Phonc Nc% i r1� I �� xepnfl W Clicni F.i� Ni. f'Iensr ► J i'(}ii it ar Cliern 1i:muil R r c is 1 su i tf t}uOz No. �I q i y���Ir��ilt*� C�1h a VC-el-l�` W Cl}RliF1'S PLrufn V A , a 41 C'herk if Ohio VALP samples 1 :: = Snmplcd h3 Sri t Date rn titimPSr i1JE'I11ifIC110MI Cniire[tKl {'nlicrtsd C7 0. RUCOwd by: t hair Reccirrd i l�hy-�DUI�CII'Nnie must hc;ippnnvd Rush Reiaursted By: by W nunaM ]a[e �r k1`hilr and xlY m P �re .lwuld liii'[1FS}pafty' h lFn Y1YC5 W 1}u' intl NIHf11Y'. L U J hirte%ji:umnienu _ State of Sample Origin- r ( Check if FOR COMPLIANCE he dienl regains Ihr P111k Putµ. 126392 PnriP 1 of l �� � � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRONMENTALTECHNOLOGiES.lftC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafyacal Laboralnrlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.com Client Name: SYN-NC-27028 Work Order Number: 19071834 RcptNo: 1 Logged by: John A.Semenik Completed By: Jacqueline Rasile Reviewed By: Jennifer Woolf 7/26/2019 9:50:00 AM 7/26/2019 11:18:05 PM 7/29/2019 2:54:58 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? FedEx Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes 0 No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 14.5 Goodl Not Present Page 36 of 36 SECTION 5 Wayne Farms Land Application Program Permit #WQ0004609 Calendar Year 2020 Animal processing wastewater residuals were land applied in two events in the year 2020. The biosolids have been sampled for nutrients and metals concentrations on an annual basis per permit requirements. The biosolids land applied in 2020 had sufficient lime added to raise the pH of the uniform mixture to a pH of 10 for thirty minutes prior to being surface land applied. This was performed to control possible nuisance conditions (see Section II, Item 7 in permit #WQ0004609). CLASS 13fVSRP pH LOG SHEET Using a pH Meter with Two -Point Standardization and Automatic Temperature Compensation (ATC) Probe Analysis Method: SW-846 Method 9045D, Soil And Waste pH MONT01YEAR: Oc�, r 1010 FACILITY/LOCATION: SAMPLING LOCATION 10•S•� Initial PH �: 12.0 S.U. : �xHoua PH ? 12.0 S.U. .2h r Hoag pH >11.5 S.U. 24 Hr pHlsu a Temp/ C Adjusted 24-Hr PH*/su - v° '5'004-� mrn W b Ra -St3 Initial pI4/su Temp/°C aa. Adjusted 3 Initial u 11,up b� � -° I:JW.� dw w 3 y a. , 2- ib 3 Dir: rZ Rr p1I*/su Ternp!°C y ;ko-(O Adjusted 2-Hr pFi"/su a N ro x c N En T ro Q w PO • q �' d N rk Pgtuvalernt pI-1 value at 25°C; CmT Comments: .., . �—,J — �• Vj JJrx u u b = Measumci pl-1 +/- the CIe. -23- SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Wayne farms Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied SU-13-6 6.6 O.OT/Ac. SU-20-1 5.7 0.0 T/AC SU-22-1 6.4 O.OT/Ac. SU-22-2 6.0 O.OT/Ac. SU-21-1 6.6 O.OT/Ac. SU-23-1 5.6 O.OT/Ac. SU-13-4 6.2 O.OT/Ac. SU-13-10 7.2 O.OT/Ac. SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011129 Client: Synagro Advisor: Synagro vo- Predictive Synagro Synagro 284 Boger Rd. 284 Boger Rd. :...,$� Soil Report Mehlich-3 Extraction Mocksville, NC27028 Mocksville, NC27028 Links to Helpful Information Sampled County : Surry Client ID: 503079 Advisor ID: 503079 Sampled: 10/08/2020 Received: 10/28/2020 completed: 11/12/2020 Farm: SQ-13/ WALTER JOHNSON Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 90 60 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.76 0.97 8.3 88 1.0 6.4 21 37 63 23 33 139 88 382 382 226 0.1 1 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 30 80 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.81 1.06 7.7 85 1.2 6.2 50 31 64 19 37 118 78 589 589 ill 0.1 1 Sample ID: 10 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 30 80 0 0 pH$ 0 0 0 Note: 3 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.41 1.03 8.8 97 0.3 7.2 45 30 67 28 37 97 51 343 343 167 0.1 1 North Carolina r Tobww Trust Fw►d C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011129 Synagro Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL029571 �5{i �141..tiL Client: Alex Fox Advisor: Predictive ;• Synagro r. 284 Boger Rd r, Soil Report Mehlich-3 Extraction Mocksville, NC27028 Links to Helpful Information Sampled County : Surry Client ID: 501947 Advisor ID: Sampled: 03/17/2020 Received: 04/13/2020 completed: 04/22/2020 Farm: SU-133 (Walter Johnson) Sample ID: 6 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.0 120 - 160 0 10 0 0 pH$ 0 0 0 Note: 3 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.27 1.11 8.9 88 1.0 6.6 143 70 63 22 33 182 117 420 420 152 0.1 1 Noah Carolina Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO29571 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032833 �5{i �141..tiL Client: Alex Fox Advisor: Alex Fox Predictive Synagro Synagro ;• 284 Boger Rd 284 Boger Rd $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County : Surry Client ID: 501947 Advisor ID: 501947 Sampled: Received: 06/30/2020 Completed: 07/09/2020 Farm: su-13/walter Sample ID: 13 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 0 90 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.22 1.03 6.8 89 0.8 6.4 67 24 57 30 40 1385 836 153 153 154 0.1 1 Noah Carolina fdtaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32833 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL029574 �5{i �141..tiL Client: Alex Fox Advisor: Predictive ;• Synagro r. 284 Boger Rd r, Soil Report Mehlich-3 Extraction Mocksville, NC27028 Links to Helpful Information Sampled County : Surry Client ID: 501947 Advisor ID: Sampled: 03/01/2020 Received: 04/13/2020 completed: 04/22/2020 Farm: SU-21 (Ruben Golding) Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 20 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.02 8.3 88 1.0 6.6 83 68 58 27 30 130 86 408 408 78 0.1 1 Noah Carolina Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO29574 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 20-022-9619 Account No: 46431 Advisor: Synagro Central LLC Marshal Puryear 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Ben Watson Wayne Farms 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: 56-22 Date Received:01/22/2020 Date of Report: 02/13/2020 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 04066 56-22-1 MIN 2.0 6.4 0.7 138 165 27 113 233 233 100 8.3 92 60 21 0.8 0.1 Crop Recommendations: 1- Pasture Rec Uom lb/acre Lime (Vacre) 0.0 N 50 P205 0 K20 0 S 16 Mn 2 Mn-AI 79 Zn 0 Cu 0 B 0 Mg 0 Last Crop 04067 56-22-2 MIN 1.8 6.9 0.2 52 45 44 106 4533 4533 180 14.8 99 57 40 0.3 0 Crop Recommendations: 1- Pasture Rec Uom lb/acre Lime (Vacre) 0.0 N 50 P205 30 K20 99 S 7 Mn 2 Mn-AI 67 Zn 0 Cu 0 B 0.5 Mg 0 Last Crop Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032839 �5{i �141..tiL Client: Ben Watson Advisor: Alex Fox Predictive 331 Kirby Bowman Rd Synagro ;• Siloam, NC 27047 284 Boger Rd Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Surry Links to Helpful Information Client ID: 494545 Advisor ID: 501947 Sampled: 06/23/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: su-22 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 110 30 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.22 0.89 6.5 86 0.9 6.0 15 57 52 30 120 96 74 135 135 64 0.1 2 Noah Carolina FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32839 Ben Watson Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/v weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL029575 �5{i �141..tiL Client: Alex Fox Advisor: Predictive ;• Synagro r. 284 Boger Rd r, Soil Report Mehlich-3 Extraction Mocksville, NC27028 Links to Helpful Information Sampled County : Surry Client ID: 501947 Advisor ID: Sampled: 03/10/2020 Received: 04/13/2020 Completed: 04/22/2020 Farm: SU-23 (Max Wall) Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.6 120-200 0 70 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.19 6.2 74 1.6 5.6 275 33 58 14 32 138 100 280 280 341 0.1 2 Noah Carolina Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO29575 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm