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WQ0000020 Aville Arpt GW Monitoring Nov 2009-Apr 2015
DUKE ant ENERGY GarrneralManager ® Plant General PROGRESS Asheville Steam Electric Plant Duke Energy Progress ASVL PLT 1200 CP&L Dt Arden,NC 28704 o: 828-687-5201 F, 828.687-5204 Certified Mail:7012 1640 0000 6844 4658 garry.whisnant@duke-energy.com File Pt.: 12520-Q July 7,2015 Mr. G.Landon Davidson NCDENR/Asheville Regional Office 2090 U.S.70.Highway Swannanoa,NC 28778 RE: Duke Energy Progress Asheville Steam Electric Plant April 2015 Groundwater Monitoring Sampling and Analysis Results Airport Fills Dear Mr.Davidson: Attached are the results from the most recent semi-annual groundwater monitoring sampling event conducted in April 2015 for the wells near the Area I, III and IV structural fills at the Asheville Regional Airport. The results from these sampling events are included on the GW59CCR forms normally used for groundwater monitoring results around ash basins per a recommendation from Jon Risgaard, NC DENR. As these structural fill sampling events are not part of an NPDES permit; this form was slightly modified and is not signed. Please note that the groundwater sample collected at well MW-9 —A4 in April did not reach the lab. As such, this well was resampled on May 13, 2015 and the results from this resample are included. NC DENR personnel did split samples with DEP at this well in April. DEP would appreciate it if NCDENR will send us the results from the state lab regarding these split samples at the Asheville Airport fills. Per our letter to Mr. Brett Laverty, NC DENR, dated March 2, 2105, DEP contacted the MSD Industrial Waste Section and asked that they contact Mr. Laverty such that Mr. Laverty could retrieve information directly from MSD regarding leachate quantity and quality for Area III and Area IV leachate discharges. If this arrangement has proved unsuitable, please advise Mr. John Toepfer at 919-546-7863 or Ms.Teresa Williams at 828-687-5240. Sincerely; Garry A.Whisnant RECEIVED Asheville Plant Manager Division of Water Resources Attachments JUL 9 2015 Water Quality Regional OperatlanS Asheville Regional Office www.duke-energy.com GROUNDWATER QUALITY MONITORING: DEP(fiMENtD�ENVIHDNMEN7&NATLIRAtREsaa(scEs r a COMPLIANCE REPORT FORM LHvaS1oNAFiIrArEaY>ttAuiY INFpR)YIAhoNPROtE�S)NGUNI ' i SS1X5A141L5ER�iCE„1`ENTEB,ItAL�WH WC',27G49�S677,Phene'`z{91h�"�33.3221:`<,ks `,„.,',. FACILITY INFORMATION Please Print Clearly or Type Facility Name: - Asheville Regional Airport - Permit Type: DORS Expiration Date: 2/28/2015 Permit Name(if different): ;Duke Energy Progress,Inc.. . PERMIT Number:1 WQ0000020 Facility Address: 61 Tuminal.Drive (Street) TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill 'Fletcher _ NC' `28732 County - ,..Buncombe - (City) (State) (zip) Contact Person: `Teresa Williams Telephonelf 919-417-6417 Well Location/Site Name: Structural Fill Area]` No.of wells to be sampled: I 4' (fmm Permit) n�f .. x ara a; :wMan ito i Welt Co recto I rma on r_u.,.+�....,a: 3��,?,�..t ti;., �, �1a a�•�,b ,?,.rc.�-a*. i}„a..fi.,.a.=v�.rr�,. .. a;,,a,.."4-�, �.„� r.:,'a.,,," Well ID Number(From Permit) Units MW1A-Al MW2A-Al MW4A-Al- MWS-Al hi MW MW- MW- MW- MW- MW MW- MW- MW- MW- MW- MW- MW- Well Depth(ft below land surface) ft 20.00 15.00 45.00 57.00 Measuring Point(toc)[it above land surface] ft 2.72 3.56 -0.17 3.08 Well Diameter '.... in 2.0 20 2.0 2.0 Screen To [ft below land surface] ft 5.00 5.00 30.00 42.00 Screen Bottom[ft below land surface) ft 20.00 15.00 45.00 57.00 Relative Measurin Peim Elevation - ft 2100.40 2102.71 2151.55 2153.86 - ,'J:x Sta Y ,.n x• .« , a", a�~w° .�«Gt 4 sa ,.a.W .am„�. }..�v `r. CHECK IF DRY WELL AT TIME OF SAMPLING ❑DRY ❑DRY e❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY ❑DRY x ❑DRY 15A•2L Units MW1A-Al MW2A-AS MW4A-Al* MWS-A3 Sample Date "" ' '... 04/06/2015 04/06/2015 04/07/2015 04/06/2015 Water Level[ft below measuring t.](82546) ", It - 7.29 0.69 19.44 37.76 Volume of Water pumped/bailed i gal 0.25 0.50 0.50 2.50 Temperature(00020) de.0 13.0 12.0 15,0 16.0 Odor(00085) - _ None None None None Appearance Clear Clear Clear Clear Turbid' (82078) NTU 3.3 0.7 1.4 10.0 Dissolved Oxygen(00300) mg/L - 5.6 3.41 0.3 5.4 Oxidation Reduction Potential(00090) mV 379 354 121 389 Specific Cond-ffeld(00094) umhos/cm 45 361 64 21 H-field(00400) G.S.8.5 SU 1 5.61 5.11 5.0 5.0 .._.. hY^` ✓'kd. „�.✓ . n: ,v. ' ,u uBbOtatOP1 ID10fH Laboratory Name Pace Analytical Services Certification NCDENR040 Samples for metals were collected unfiltered: ❑+ Yes ❑ No Sample Analysis Date April 8-13,2015 1 and field addiHed: 0 Yes ❑ No 15A-21. Units MW1A•At MW2A•Al MW4A•Al- MWS-Al Sb-Antimo2y(01097) 1 ug/I <0.5 <0.5 <0.5 <0.5 As-Arsenic(01002) 10 u I <0.5 <0.5 <0.5 <0.5 Ba-Barium(01007) 700 ug/I 18.7 16.5 25.9 20.9 B-Boron(01022) 700 ug/I <50 <50 <50 <50 Cd-Cadmium(02027) 2 ug/I 0.74 0.11 0.39 0.1 CI-Chloride(00940) 250 mg/1 1.2 2 1.7 1.2 Cr-Chromium(01034) 10 ug/1 <5 <5 <5 <5 Cu-Copper(01042) 1 fall <0.005 <0.005 <0.005 <0.005 ' Fe-hon(01045) 300 1 ug/I 1551 <50 32001 263 Pb-Lead(01051) 15 ug/I 0.28 <0.1 0.24 0.5 l Mn•Manganese(01055) 50 ug/I 11.4 <5 841 59.8 Hg-Mercu (71900) 1 ug/I <0.2 <0.2 <0.2 <0.2 Ni-Nickel(01067) 100 ug/I <5 <5 <5 <5 Nitrate(NOJ as N(00620) 10 mg/I 0.91 0.32 <0.02 0.93 Se-Selenium(01147) 20 ug/I <0.5 <0.5 <0,5 <0.5 SO,-Sulfate(00945) 250 mgtl <2 <2 4.6 <2 TI-Thallium(01059) 0.2 ug/I <0.1 <0.1 0.36 <0.1 TDS-Total Diss.Solids(70300) 500 mg/I 25 <25 <25 <25 Zn-Zinc(01092) 1 mg/I <0.01 <0.01 <0.01 0.028 AI-Aluminum(01105 u I N/A N/A N/A N/A _ Turbidity is fiddanalyred for nto..ti.nuseonly. 60LD vaiuesequal exceed ih car,esPdf!drng]L stand"Po�.�t_.,-_. _.--,,_,�. .. ,_„_ �Mu.�� Notes: 1 certify that,to the mformationr including the - - - - data -d usmg approved methodsDWQ-certifled laboratory, there are significant penalties for subruttimig false possiblity of lines and imp6suresent for kn.YAng violations, 1 1 Ix Permittee(or Authorizedgent)t4ame and Title-Please print or type Signature of Permi ee(or Authorized Agent) Date GW-59CCR-Voluntary ••Denotes Background Well (B)-Laboratory"B"flag GROUNDWATER QUALITY MONITORING: 136ARTiMENtoFeM4iRoNrnEENi&NATURaL„RrssoURtEs COMPLIANCE REPORT FORMUNIT' e m DIVISION OF WATER:QUALITY a INFORMATION PHOCESSINLt 1617 MAIL SERVICECENTER;RALEIGH NC 27699.3617 P,honesa919}7333221x;� FACILITY INFORMATION Please Print Clearly orType Facility Name: -' " Asheville Regional Airport PermitType:I DORS Expiration Date: 2/28/2015 Permit Name(if different): Duke Energy Progress,Inc. PERMIT Number: WQ0000020 Facility Address: - 61 Terminal Drive (Street) - TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill Fletcher - NC 28732 County Buncombe (City) (state) (zip) Contact Person: Teresa Williams Telephonep 828-687-5240 Well Location/Site Name: Structural FIII Areas III&IV No.of wells to be sampled: 14 (from Permit) , 7. n „ ,. »�. ,, . : � � norgWellConsrficion 1n TmatloD Well ID Number(From Permit) Units MW-IA • MW-1-A3 MW-2-A3 MW-3-AL MW-4-A3 MW-5-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-5-A4 MW-SD-A4 MW-6-A4 MW-7'-A4E2069.01 -A4 MW- MW- MW- WeII Depth[ft below land surface] ft .84.50 53.50 63.00 65.00 34.00 63.00 68.00 67.00... .30:00 25.00 71.50 30.00 30.000 Measuring Point(toc)[ft above land surface] ft 2.01 2.11 2.29 2.59 1.70 1.77 1.41 2.88 .3.01 2.49 4.51 3.59 2.638 Well Diameter in 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Screen To [ft below land surface] ft 76.51 38.50 .47.90 49.70 23.70 47.40 51.70 52.50 10.00 10.00 61.50 15.00 15.008 Screen Bottom[ft below land surface] k 86.51 57.50 62.90 64.70 33.70 62.40 66.70 67.50 30.00. 25.00 71.50 30.00 30.008 Relative MeasuringPoint Elevation ft 2133.65 2162.42 2147.13 2140.98 2117.64 2123.16 2130A4 2121.54 2076.56 2068.31 2071.47 2074.01 2071.37 7. ": 7,77 r 77 7,77 Sampling itdortnatioo and FleIHiAnalysis- '- - ,. ,• CHECK IF DRY WELLATTIME OF SAMPLING ❑DRY ❑a. ❑:DRY ❑DxY - „- w --„ �„ - „ _ 6 -❑DRY ❑�o0.Y ❑DRY ❑DRY ❑DRY ❑O0.Y - :❑DRY ❑DRY ❑DRY ❑,DRY ❑.pRY ❑DRY ��❑o0.Y ❑.pRY 1SA-2L Units MW-1A • MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-5-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-S-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sample Date. .. 04/09/2015 04/08/2015 04/08/2015 04/08/2015 04/08/2015 04/07/201S .04/07/2015 04/07/2015. 04/09/2015 04/09/2015 04/09/2015 04/09/2015 04/09/201S 05/13/2015 Water Level[k below measuring t.](825461 k 30.44 32.84 22.40 30.33 19.04 24.12 32.11 25.69 15.46 8.61 13.64 16.80 19.48 20.90 Volume of Water pumped/bailed gal 1.50 3.00 0.50 4.50 1.00 0.50 0.75 0.50 0.50 0.50 0.50 0.25 0.25 0.50 Temperature(00010 deg.C 15.0 16.0 17.0 '15.0 14.0 16.0 16.0 15.0 16.0 15.0 17.0 17.0 18.0 18.0 Odor(00085)... .. None None None None None None None None None .,None None None None None .Appearance .` Normal Normal Normal Normal Normai . Normal . Normal Normal. Normal Normal Normal Normal Normal Normal Turbidity(82078) - NTU 6.8 14.4 6.2 9.7 9.0 4.2 9.7 7.2 1.7 - 3.2 4.9 1.1 1.0 2.2 Dissoved Oxygen(00300) _ mg/L 4.9 5.7 6.9 7.5 1.6 5.7 5.6 511 3.6 0.5 4.4 2.4 3.8 3.4 Oxidation Reduction Potential(00090) - mV 341 311 398 400 318 401 407 397 373 360 353 386 390 65 Specific Cond-fiold(00094) umhos/cm 57 40 22 14 52 18 17 21 50 200 77 43 23 .76 H-field 00400 6.5-8.5 SU 1 5.51 . < . .5.3 5.5 5.5 5.6 5.3 .5.5 5.3 5.1 4.9 5.9 5.3 4.6 6.1 , _ . '" �', `- ,s alaboratorylnformat]on .LaboratoryName :"" -"Pace Anal "'Analytical services :.. Certification it Samples for metals were collected unfiltered: � Yes ❑ No Sample Analysis Date Aril 9.23,2015&May 15-19,2015 NC DENRg40 P Y P and field acidified: [] Yes ❑ No 15A-21. Units MWAA • MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-5-A3 MW-6-A3 li A3 li-A4 MW-5-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sh-Antimony(01097) 1 ug/I <0.5 cl <3 <3 <S <1 <3 <3 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 As-Arsenic(01G02) 10 ugli <0.5 <1 Q <3 <1 <3.. <1 <3 <0.5 1 <0.5 <0.5 <0.5 <0.5 <0.5 Ba•Barium(01007) 700 ug/I 22.3 33 6 13 14 9 12 11 25.6 167 23.4 28.9 52.4 6.5 B-Barren(01022)- 700 ug/I : <50 <50 <50 <SO <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 Cd-Cadmium(01027) 2 ug/1 <0.08 <1 <1 <1 <1 <1 <1 el 0.22 <0.08 <0.08 0.16 0.46 <0.08 CI-Chloride(00940) 250 mg/1 1.3 1.4 0.88 0.46 0.95 0.6 0.41 0.83 8.2 20.9 <1 2.1 1.6 <1 Cr-Chromium(01034) 10 ull 6.7' 6 <5 6 <5 <5 .<5 <5 <5 <5 1 <5 es <5 ' <5 Cu-Copper(01042) 1 mg/I <0.005 <0.005 <0.005 <0.005 <0.005 <O.005 <0.005 <0.005 <0.005 <0.005 <0.005 <O.00S <0.005 <0.005 Fe-Iran(01045) 300 ug/I 1 236 969 IS91 471 1110 125 2081 335 <50 68.11 116 <50 <50 67.8 Pb-Lead(02051) 15 ug/I 0:16 <1 <1 <1 <1 <1 <1 <1 0.1 <0.1 <0.1 e0.1 0.11 <0.1 Mn-Manganese(01055) S0 ug/I' 30.1 129 99 75 287 50 :10 .. 74 21.9 90.5 <5 <5 7.6 <5 Hg-Mercury(71900) 1 ug/I <0.2 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Ni-Nickel(01067) 100 -ug/I <5 <5 <5 <5 <5 - <5 <5 - <5 <5 <S <5 es <5 <5 Nitrate(NO.)as N(00620) 10 mg/I 3.9 0.89 0.1 <0.023 0.08 0.04 <0.023 '0.06 0.038 7.6 0.89 0.32 <0.02 0.91 Se-Selenium(01147) 20 ug/1 <0.5 <1 el <1 <1 <1 <1 <3 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 SO4-SUlfate(00945) 250 mg/1 <2 1.1 1.1 0.3 <0.1 0.25 0.24 0.12 <2 17.9 <2 <2 <2 <2 TI-Thallium(01059) 0.2 ug/I <0.1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.1 <0.1 <0.1 '' <0.1 <0.1 <0.1 TDS-Total Diss.Solids(70300) 500 mg/I 61 29 <25 :::-- <25 42 <25 - <25 ---<25 : - 39 147 72 --- 36 <25 70 Zn-Zinc(01092) 1 mg/I 0.013 0.026 <0.005 0.0141 <0.005 <0.005 0.01 0.006 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 AI-Aluminum(01105) - 1 ugti NAI NAI NA -.NA NA NA NA NA I NA NA NA " NA NA NA -b'dity ufeldanalyzetl(ar informatlan use only. BOLD luef q I exceed th _p2L t d dw NMer Permittee(or Authorized A ent)Name and Title-Please print ortype Signature f Permittee(or Authorized Agent) - Date GW-59CCR-Voluntary •-Denotes Shared Background Well for Areaslll&IV - (B)-Laboratory"B"flag �z 6-4'�- County: BUNCOMBE O�WA7-R Sample ID: AC18156 River Basin O� Q� PO Number# 15GO109 Report To ARID Date Received: 04/08/2016 ? 7H. Time Received: 08:00 Collector: B LAVERTY f3711 Region: ARO Labworks LoginlD TASCENZ01 Sample Matrix: GROUNDWATER Final Report Date: 5/4/15 Loc.Type: Monitoring Well Final Report Report Print Date: 08/17/2015 Emergency Yes/No _ VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 1:MONITORING WELL-MW1A Location ID: 1P11MW1A Collect Date: 04/06/2015 Collect Time: 12:35 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalYte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 1.1 °C 4/8115 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 4/20/15 ESTAFFORD1 7429-90-5 Al by ICP 50 120 ug/L EPA200.7 4117/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 4122/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 20 ug/L EPA200.7 4/15/15 ESTAFFORD1 7440-41-7 Be by ICP .5.0 5.0 U ug/L EPA200.7 4/17/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.70 ug/L EPA 200.8 4/20/15 ESTAFFORD1 744048-4 Cobalt by ICP 50 50 U ug/L EPA200.7 4/17/15 ESTAFFORDI 744047-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 4/20/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 7.9 ug/L EPA 200.8 4/20/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 140 ug/L EPA200.7 4/17/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 4/14/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 2.0 mg/L EPA200.7 4/15115 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA 200.7 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 4/22/15 ESTAFFORD1 7440-23-5 Na by ICP 0.10 2.6 mg/L EPA200.7 4115115 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 4/20/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 4/20/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 33 ug/L EPA 200.8 4/22/15 ESTAFFORDI 7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA 200.8 4122/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA 200.8 4/20115 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to hap,(/ �i_o.�Nger og4�,oPo,aAab/staHneu/rechaGsi t#opw..gy�iiF.er_cpae<htpL Forat.oc�E•nr ora/Web(w4lmbhraxneo/Egch�_p Page 1 of 1 North Carolina Division of Water Resources Y�s>tlA :a Tay Lab Use 0 1�/ Water Sample Collection&Submittal Form Central Laboratory(Water Sciences Section) °(apEtonat) lQ. L46oratory I Sample Number. Coca#ron°Descrrpfion: Asheville Airport Area 1;Monitoring Well-MW 1 A tocation Code. 1 P 11 M W 1 A Date Received:p county.,- Buncombe collector: Brett Laverty Prror�ty: Watermatrim � Locettori7ype DWR,'Regtont. r Time Received: DWR 1Ce' ASheVllle ❑Ambient River/Stream Lake sedon"county; (orvge Fypamej ❑Surface ❑Estuary ❑Canal Rereaved'By. River$ast% Date. 4/6/2015 El Routine ❑Stormwater r OComliance ✓ State Courier p ❑Ground ❑Monitoring Well ❑Water Supply Notes: fine 12:35 PM Delivery Method:° ❑Hand Delivery n,` ❑COC ❑Waste ❑Effluent ❑Influent �' "� ❑Other: Somp tag ❑� Grab Composite [:]Field Blank ❑Chlorinated ❑De-chlorinated in Field Emergency ❑Blank ❑Trip Blank Method.— Other: [-]Filter Blank Temperature(°C) ❑Filtered in Field Dissolved analysis:Enter"DIS" onArnvatf:'. in check-boxes for parameters Splt7pUeptlt ' ❑QA ❑Solution ❑Other: Collectors Comments: EE Microblologarameters:, 1 ,r.F �, `u MBAS(surfactants) mg/L MetalsParame�rs:,, _, ��•;> nf, Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100m1 Residue:Volatile/Fixed,Suspended mg/L X I Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L Orgal►la�Parameter; Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides they Parameters: X Lead(Pb) µg/L Organophosphorus Pesticides ,Wet'ChemiStoParameters pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients Parameters: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters{optional): WaterTemp(°C): I pHAs7u.j: Dissolved oxygen(ppm):. Conductivity(µmhos/cm); Salinity(pptj: Revision:2/06/2015 I County: BUNCOMBE OF w 7E Sample ID: AC18155 River Basin PO Number# 15GO108 Report To ARO r�r`j Date Received: 04108/2015 -I Time Received: 08:00 Collector: B LAVERTY d Region: ARO Labworks LoginlD TASCENZ01 Sample Matrix: GROUNDWATER Final Report Date: 514/15 Loc.Type: Monitoring Well Final Repoli Report Print Date: 08/17/2015 Emergency Yes/No Visit]D COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT AREA 1:MONITORING WELL-MW2A Location ID: 1P11MW2A Collect Date: 04/06/2015 Collect Time: 11:47 Sample Depth If this report is labeled preliminary report the results have not been validated. Do not use for Regulatory purposes. CAS# AnalYte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 1.1 °C 4/8/15 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 4117/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 4122/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 4120/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 18 ug/L EPA200.7 4/15/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 4/17/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 4/17/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4/20/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 4117/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/14/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.3 mg/L EPA200.7 4/15/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA200.7 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 IOU ug/L EPA200.8 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 2.0 mg/L EPA200.7 4/15/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.3 4/20115 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 29 ug/L EPA200.8 4/22115 ESTAFFORDI 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA200.8 4/22/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 4/17115 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 IOU Ug/L EPA200.8 4/20/15 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to}ytg/J po ai.�cdec.or,,,( wa/mbhtaenHo/cechacsfstuoata qu-01er cude'chtp.IZpsrtn�n-_n...o.IR(w,eblva/tan(staHnfiu Page 1 of 1 North Carolina Division of Water Resources Y,Is�tID Tog Water Sample Collection&.Submittal Form Central Laboratory(Water Sciences Section) (optiana ID, laboratory. sample Nomber. Location Descidiptions Asheville Airport Area 1;Monitoring Well-MW2A Locaddn-Code: 1 P11 MW2A s . pate Received:` County Buncombe Collector: I Brett Laverty Priority Water LocationTyLre n Tlt`e'Received.•' DWR,Re ion: OWR.O ice: ❑River/Stream Lake , based on�un (ora enure Asheville ❑Ambient ❑ ry ( tyJ° g ) ❑Surface Estua ]Canal ❑Routine ❑Stormwater RecQ►vedey; River Basin: < Date 4/6/2015 ❑� Compliance ❑� Ground ❑Monitoring Well ❑WaterSupplyba State Courier Delivery Method: _State Delivery Notes: time 11:47 AM ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: sampling ❑� Grab Composite ❑Field Blank ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank []Trip Blank Meihvd` °1 ❑Other: ❑Filter Blank Telnperatare C'10 Dissolved analysis:Enter"DIS" on Arrival: ❑Filtered in Field in check-boxes for parameters FS17;);De"pth ❑QA ❑Solution ❑Other: Collectors Comments: MicrobiologyParametters: MBAS(surfactants) mg/L Metals°Parameters: Tin(Sri) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L CBOD:Carbonaceous BOD,5-day me/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100m[ TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters;. Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other Parameters:' X Lead Pb( ) µg/L Organophosphorus Pesticides UVetChemistryParameterS: pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L. Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Wittrients Parameters: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADM] C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L. Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg X Sodium(Na) mg/L p Biological,"; gym, Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L ir—TOrthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: ° m Field Parameters(opdonai): Water Temp(°C): pH(s.u.): Dissolved Oxygen(ppm): Conductivity(µmhos/cm): Salinity(ppt): Revision:2/06/2015 _. County: BUNCOMBE OF W'A7FR Sample ID: AC18218 River Basin �� QG PO Number# 16GO115 Report To ARO trj r Date Received: 04/09/2015 y Time Received: 08:05 Collector: B LAVERTY O 'r Region: ARO Labworks LoginlD TASCENZ01 Sample Matrix: GROUNDWATER Final Report Date: 5/4/15 Loc.Type: Monitoring Well Final Report Report Print Date: 08/17/2015 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW4A Location ID: 1 P11MW4A Collect Date: 04/07/2016 Collect Time: 09:25 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 2.4 °C' 4/9/15 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7429-90-5 Al by ICP 50 65 ug/L EPA200.7 4117/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 4/22/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.E 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 28 ug/L EPA200.7 4/15115 ESTAFFORDI 7440-41-7 Be by ICP 5.0 6.0 U ug/L EPA200.7 4/17/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7440-4B4 Cobalt by ICP 50 50 U ug/L EPA200.7 4/17115 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4/20/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 4/20/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 3700 ug/L EPA200.7 4117/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.26 mg/L EPA200.7 4115115 ESTAFFORD1 7439-96-5 Mn by ICP 10 940 ug/L EPA200.7 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 4/22115 ESTAFFORDI 7440-23-5 Na by ICP 0.10 9.3 mg/L EPA200.7 4/15/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 4120/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA200.8 4/20115 ESTAFFORD1 7440-28-0 Thallium (TI)ICPMS 2.0 2.0 U ug/L EPA200.8 4/22/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 4117115 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 IOU Ug/L EPA200.8 4120/15 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to tt�:J,MorarZ �n..,.orQ[we@LX9LL@ljqy.4fioLt�hRa,#Data CLYA!Lic{_co,ges chtp;[/vo*p(.,ncpenr prpigenjvq/!,ap�staSr_(Ljtechassisv Page 1 of 1 North Carolina Division of Water Resources =Viqit1D: Ta LGE3 USe C)pl�i:Water Sample Collection&Submittal Form seCentral Laboratory(Water Sciences Section) Laboratory ` ""• Sample Number: Locotinn�Des'ctiptions Asheville Airport-Monitoring Well MW4A Lbcation Coder 1 P11 MW4A t `Dote Received: J County. Buncombe Collector Brett Laverty Priority WaterMatr/x. =`Location Type: DINR,,Regron:,, DWR Office: rrrie Received: � Asheville ❑Ambient ❑River/Stream Lake R (bused oncouuty} � (oragencyname}` ❑Surface ❑Estuary [ canal w served ey , ❑Routine ❑Stormwater Re I River Basin: Dote 4/7/2015 state Courier t ❑Compliance QGround ❑MonitoringWell ❑Water Supply Delivery Method:_ ❑Hand Delivery Notes: Time., z, 9:25 AM ❑COC []Waste ❑Effluent ❑Influent ❑Other: 5amp/ink ° QGrab Composite ❑Field Blank " ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method El Other: ❑Filter Blank Temperature(,_ Dissolved analysis:Enter"DIS" on Arrival: ❑Filtered in Field Samn leDepth: ❑QA ❑Solution ❑Other: in check-boxes for parameters a Colectolr s f.'Anunears: Miclobiology'Paramelters:',; MBAS(surfactants) mg/L Metals Parameters: Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/7- Oil and Grease,HEM,Total Recoverable mg/L X I Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters: Y Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other Paramat&s::° X Lead(Pb) µg/L Organophosphorus Pesticides Wet,ChemiStryParameters.. `_, pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients Parameters: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L plologieal."` k= Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L F.,Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Fieid'Parameters(opHonatl Water Temp(°C):° pH(s.u.): D4ssolved Oxygen(ppm): " Conductivity(µmhos/cm)c Salinity(plat): Revision:2/06/2015 County: BUNCOMBE OF` Ar9 Sample ID: AC18157 River Basin QG . , PO Number# 15GO110 Report To ARO CO Date Received: 0410812016 Collector: B LAVERTY a y Time Received: 08:00 Labworks LoginlD TASCENZ01 Region: ARO Final Report Date: 5(4(15 Sample Matrix: GROUNDWATER Report Print Date: 08/17/2015 Loc.Type: Monitoring Well Final Repolt Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 1:MONITORING WELL-MW5 Location ID: 1P11MW5 Collect Date: 0 4/0 612 0 1 5 Collect Time: 15:22 Sample Depth If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 1.1 °C 4/8/15 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 4/20/15 ESTAFFORDI 7429-90-5 Al by ICP 50 360 ug(L EPA200.7 4117/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug(L EPA 200.8 4/22/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 22 ug/L EPA200.7 4115115 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 4/17/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 4/17/15 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4/20115 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2,2 ug/L EPA200.8 4/20/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 220 ug/L EPA200.7 4/17/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.95 mg/L EPA200.7 4/15/15 ESTAFFORDI 7439-96-5 Mn by ICP 10 57 ug/L EPA200.7 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 4122/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.2 mg/L EPA200.7 4/15/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4120/15 ESTAFFORD1 778249-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 4/20/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 IOU ug/L EPA200.8 4120/15 ESTAFFORD1 7440-28-0 Thallium(TI) ICPMS 2.0 2.0 U ug/L EPA200.8 4/22/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 4/17115 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 25 ug/L EPA200.8 4/20/15 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to.hep;[[,,po�i.�ede�r orp[wenJWq/lab/,tafin$o(techasis[kDa[aQualifiet Code,<h JL.port�t;nccenrgrp�-b[Wgllab[tufin„(1o/te6-ig, Page 1 of 1 Acib Use North Carolina Division of Water Resource VisitIl - �� tabaratary Qp�J/ Water Sample Collection&Submittal Form Central LaboratoryWater Sciences Section (p tonal @ Sample Number: tacationVeseriptions Asheville Airport Area 1;Monitoring Well-MW5 Ldcation Code:, 1 P11 MW5 ' - aye Gate Received: County Buncombe Collector. Brett Laverty Priarrty: Water Matrix: Location Type � - _ �$ DVEIRRegron „ DWR°Offlee: �❑River/Stream -❑LakeTirneReceiverl; Asheville River/Stream❑ [-]canal 9 (based an county) (orogencynamej El Surface Estuary Received By: ❑Routine ❑Stormwater River Basln: Dater 4/6/2015 ❑✓ Com fiance ✓ ✓ g p State Courier p ❑Ground ❑Monitorin Well ❑Water Su ply Notes: Time • 3:22 PM Delivery Method: El Delivery ❑coc ❑Waste ❑Effluent ❑Influent ❑Other: 5vihpling °'' ❑Grab Composite ❑Field Blank "° ❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method ❑Other: ❑Fitter Blank Temperatyre('"CJ_ Dissolved analysis:Enter^DIS" on Arrival:" El in Field in check-boxes for parameters Sampte Depths,;; ❑QA ❑Solution ❑Other: Coltector's Commentsr lYlicrobiologyfiararjleters: '' ` " MBAS(surfactants) mg/L Metals Parameters:` Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(5b) µg/L X Vanadium(V) µg/L Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100m[ Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters:, , Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides OthedParameters `" `" T X Lead(Pb) µg/L Organophosphorus Pesticides WethemistryParameters *,. pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients Parameteis: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg X Sodium(Na) mg/L Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Meld Paremeters(dptionalj: WaterTemp(°Q: pH(s.u.): - Dissolved Oxygen'jppim): Conductivity{µmhosJcm): Salinity(ppt): Revision:2/06/2015 /q40Z &if 3 AC18248 North Carolina D ion of Water Resources Water Science -ction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW1 Sample ID: AC18248 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO123 Region: ARO Report To ARO Location ID: 1P11MW1 Date Received: 04/10/2015 River Basin Collect Date: 04/08/2015 Priority Time Received: 08_00 Emergency Collect Time: 16_10 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4/15 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 1.3 °C 4/10/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7429-90-5 Al by ICP 50 980 ug/L EPA 200.7 Rev4.4 4117/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 34 ug/L EPA 200.7 Rev4.4 4/15115 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4122/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4120/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 920 ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 1.5 mg/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORDI 7439-96-5 Mn by ICP 10 120 ug/L EPA 200.7 Rev4.4 4117/15 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 2.4 mg/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORDI .7440-02-0 Ni by ICPMS 2.0 2.0 ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 30 ug/L EPA 200.8 Rev5.4 4120/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 23 ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources Vi3�tID>� Tugp1 Water Sample Collection&Submittal Form -- - --- --- Central Laboratory(Water Sciences Section) (opttonafJ 1[? iI'llaf�orat " i Sample lltum#q: LocotionxDescriptions Asheville Airport-Monitoring well MW 1 Location Code: 1 Pi MW 1 Date Received;` County. Buncombe CoUectar. Brett Laverty Priority. Water Matrix: tocattonType oWRRegton. ; �, owtOTe ❑ ❑River/Stream ❑Lake �1FrrreRecefvd basedon caant (oragencyname� Asheville Ambient ( y) � 1°, ❑Surface ❑Estuary [:]canal Recetved By:; 3 ❑Routine ❑Stormwater River Basin: � � Date 4/8/2015 0 State Courier ❑Compliance QGround OMonitoringWell ❑Water Supply Notes: Ame.," 4:10 PM Delivery Method: El Hand Delivery ❑COC ❑Waste []Effluent ❑Influent ❑Other: Satnpll ,!'j ❑✓ Grab Composite [-]Field Blank ❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank Trip Blank Metlt0d j ❑Other: ❑Filter Blank Temperature('C), Dissolved analysis:Enter"DIS" 'onAmval:; ❑Filtered in Field in check-boxes for parameters S€rmple.Depth:11 ❑QA ❑Solution ❑Other: Collector's Corrtmentsr, Micto6iologyParameters. % r MBAS(surfactants) mg/L Metals'Pararneters: Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L ft*cs Parameters:, Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other`Par�itnetersi X Lead(Pb) µg/L Organophosphorus Pesticides "�IAfetChelhistry;Pafameters ,.p�,L pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L l4utrients;Parameter s: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA). Color:ADM[ C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological.. Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: , �., (Pp) .Fiield Parameters(optlonatJ: 'VVaterTemp(°C): pH(s u): ) Dissolved Okygen(ppm): Conductivity(µmh'os/cm): Salinityt: Revision:2/06/2015 � A2EA 3 AC18249 North Carolina D ion of Water Resources Water Scienct -Iction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW2 Sample ID: AC18249 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15G0124 Region: ARO Report To ARO Location ID: 1P11MW2 Date Received: 04/10/2015 River Basin Collect Date: 04/08/2015 Priority Time Received: 08_00 Emergency Collect Time: 12_28 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4115 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 1.3 °C 4/10/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7429-90-5 Al by ICP 50 160 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 10 U ug/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/22115 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 110 ug/L EPA200.7 Rev4.4 4117/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 Rev3 4114/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 0.31 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7439-96-5 Mn by ICP 10 89 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 3.0 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20115 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI WSS Chemistry Laboratory»1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or U'does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources Visit ID: Tad LOb Ilse Qnly4 Water Sample Collection&Submittal Form _ Central Laboratory(Water Sciences Section) (opttonal) ) ID Lafioratory r Sor»pleflfuniber`� LocatiomDescriptfvnr- Asheville Airport-Monitoring well MW2 Location Coders 1 P11 MW2 e r,� �, Date Received.• , County Buncombe Collector Brett Laverty Rriorrty Water Matrix LocadanType v :DWR'Region: ? DWR Office Time Receiveed Asheville ❑River/Stream Lake - (or agency namet, ❑Ambient (bosedoacauriryJ, ❑Surface ❑Estuary []canal Received ey. �'� ❑Routine ❑stormwater River Basin ;,°n ,Dote 4/8/2015 OCompliance ❑✓ Ground OMonitoring Well ❑Water Supply 4 State Courier Notes: k Time., 12:28 PM Coc Dehi�eryMethod° ❑Hand Delivery ❑ ❑Waste ❑Effluent ❑Influent 5. ❑Other: ,Sa►ttpling �� QGrab Composite ❑Field Blank ❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method: ❑Other. ❑Filter Blank Temperature(cl Dissolved analysis:Enter"DIS° am eDepthb ❑CA ❑Solution o!IArrival El Filtered in Field pt. l! ❑Other: in check-boxes for parameters S Collectors Comments:, Micirobiology,Paramete,� .�; `: r, �_ ,,; •„ MBAS(surfactants) mg/L ,` Metals Parameters: --. •:; Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters: Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides OtherPaameters, X Lead(Pb) µg/L Organophosphorus Pesticides Wet Chemistry Parameters:,; pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L. Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Ntitrients`Paraineters:' X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.u. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological: ; Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Pa'rameters(o`pttonaJJ: 'Water Temp(°C)z`;I Pf1(s u.).` Dissolyed.;•Oxygen{ppmj:: ,� `Conductivity'(µmhos/cm} Salinity(ppt)::. Revision:2/06/2015 Ait Elf 3 AC18250 North Carolina D_ _ .on of Water Resources Water Science- -,yction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW3 Sample ID: AC18250 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO125 Region: ARO Report To ARO Location ID: 1P11MW3 Date Received: 04/10/2015 River Basin Collect Date: 04/08/2016 Priority Time Received: 08_00 Emergency Collect Time: 11_19 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4/15 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 1.3 'C 4110/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7429-90-5 Al by ICP 50 160 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22115 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 13 ug/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 744043-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4120/15 . ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 110 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.70 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7439-96-5 Mn by ICP 10 89 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22115 ESTAFFORD1 7440-23-5 Na by ICP 0.10 0.78 mg/L EPA200.7 Rev4.4 4115/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20115 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5A 4/20/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA 200.8 Rev5A 4/20/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 12 ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources ViWiIW Tags ,g Ltdbi st--.0 Central Laboratory Water Sample Collection&Submittal Form �, ( Labarara`ry ry(Water Sciences Section e d[op'ttortat fD� Lf 1 11, -_ Sample Numhgr. tocation=Description; Asheville Airport-Monitoring well MW3 Location CodQ: 1 Pi MW3 II Date Qecefved County Buncombe Collector ,., Brett Laverty Priority:, W,aterMatrixc Location.Type ,p i f Y Q Time 6ecerved DWR'RegJOn:' DWIIO Ce,° ❑River/Stream ❑Lake �. based on¢oun �' orag'en name, Asheville ❑Ambient ❑ ry ❑ tYl. cy j� ❑Surface Estua Canal ❑Routine ❑Stormwater Re cetvedBy', t River Basin: Date =._ 4/8/2015 ❑Compliance ❑✓ Ground ❑� Monitoring Well [—]water Supply State Courier Notes: me` 11:19 AM DeliveryMethod: ❑Hand Delivery ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: Sampllrrg QGrab Composite ❑Field Blank ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank ►�' ❑Other: ❑Filter Blank Temperature lq) Dissolved analysis:Enter"DIS" onArrfval ❑Filtered in Field in check-boxes for parameters Sample Depthi ❑QA ❑Solution ❑Other: CpllectoraCom►rRents i1�iCiabiolOgy:Patamete`rs,° w * MBAS(surfactants) mg/L � Metals Parameters 7 : Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L n Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /loom[ Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Para mete, Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides 0 e-r Parameters X Lead(Pb) µg/L Organophosphorus Pesticides YVet_Char ij$ryFarameters „, n pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients Raiardeters �':,� s X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters(optron. .. WaterTem r(°C):° pH(s u) p Dissolved dxygen(ppmJ: ° Conductivity(µmhos/cm): Salinity(ppt):a Revision:2/06/2015 AC18251 North Carolina D ion of Water Resources Water Science -,ction Laboratory Results Loc.Descr.: ASHEVILLEAIRPORT-MONITORING WELL MW4 Sample ID: AC18251 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO126 Region: ARO Report To ARO , Location ID: 1P11MW4 Date Received: 04/10/2015 River Basin Collect Date: 04/08/2016. Priority Time Received: 08_00 Emergency Collect Time: 09_35 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 514115 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 1.3 °C 4/10/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7429-90-5 Al by ICP 50 87 ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 14 ug/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDi 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 ReAA 4/17/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 950 ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 2.0 mg/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 250 ug/L EPA 200.7 ReAA 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.6 mg/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4120/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 39 ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources Vfslt ID: Ya �LGE3 UsBOt�ly:'' Water Sample Collection&Submittal Form -- ------ ---- --- Central Laboratory(Water Sciences Section) ;,=(op'tionat)` ID" Loboratory ! ` " Sarr`►pteNrrmber Location pescriptfon. Asheville Airport-Monitoring well MW4 Loca#fon code 1 P11 MW4 P 9 p Daie Received County .I Buncombe cotiector Brett Laverty Prror+ty WaterMatrvr: Location Type DWR'Region-, " 9 DWRO�Ce` �❑River/Stream° ❑Lake rmeReterved ° Asheville ❑Ambient = �(bvsedon county) `� (orog�ncynae)- ❑Surface ❑Estuary ❑Canal Received By. ❑Routine ❑Stormwater Rrver 8asrn '' Bute 4/8/2015 OComliance State Courier p QGround OMonitoringWell ❑Water Supply Notes: TYrrie 9:35 AM Delrvery Method: El Hand Delivery ❑COC ❑Waste []Effluent ❑Influent ❑Other: 3� p ,pg 4.•_ 0 Grab Composite ❑Field Blank ❑ Chlorinated ❑De-chlorinated in Field fi ❑Emergency ❑Blank —]Trip Blank ' Method., ❑ether: ❑Filter Blank Temperature('C) Dissolved analysis:Enter"DIS" El Filtered Arrival i' ° Filtered in Field in check-boxes for parameters Shcnple Depth:: ❑ ❑QA Solution El Other: f collettor's Comments: ,� ,_` E> MBAS Naicrabiolog -Varameters ,:,. �� -0 , �x (surfactants) mg/L Metals Parameters: ,°°"�.r �_ �n Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters:' Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides ;AttrerParameters:.., ,E P, 4 X Lead(Pb) µg/L Organophosphorus Pesticides P . lAlet_t:hernisLryParameters , Fm :; „"°,_. f pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L ,1Vatrierrts,;Farametrs: X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological. Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS Fie'ld�Parameters(opttonaT): WaterTemp(°C): P (s u): Dissolved Oxygen(ppm}u Conductivity(µmhos/cm}i Salinity(Pet)•i° - a Revision:2/06/2015 RAE-A 3 AC18221 North Carolina D on of Water Resources Water Scienct xtion Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MON ITORING WELL MW5 Sample ID: AC18221 County: BUNCOMBE Collector: BLAVERTY VisitlD PO Number# 15G0118 Region: ARO Report To ARO Location ID: 1P11MW5 Date Received: 04/09/2015 River Basin Collect Date: 04/07/2015 Priority GROUNDWATER Time Received: 08_05. Emergency Collect Time: 13_27. Sample Matrix: GROUNDWATER Labworks LoginlD TASCENZO1 CDC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 6/4116 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Units Method Analysis CAS# Analyte Name PQL Qualifier Reference Date Validated by LAB Sample temperature at receipt by lab 2.4 °C 4/9/15 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7429-90-5 Al by ICP 50 180 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4117/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20115 ESTAFFORDI 7439-89-6 Fe by ICP 50 120 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.87 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 48 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22/15 ESTAFFORD1 7440-23-5 Na by ICP 0.10 1.1 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-28-0 Thallium(TI) ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/22115 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources "vsrtID. 'Tag, Lab�/Se�Drt/Y. " Water Sample Collection&Submittal Form -- ------ ---- --- ---- Central Laboratory(Water Sciences Section) (optionatj ID'- Laboratory, Sample Numbi4r: Location Descrlprion, Asheville Airport-Monitoring Well MW5 Locattan Code;: 1 P11 MW5 g 111 Date Received:• o� County `y,,1 Buncombe Collector Brett Laverty Prrar�tlr Ultaterllrlatrix: LocatlonType tl DWR o (Ce'" River Stream " Lake n!ne Received: DWRRegrori: a, Asheville ❑Ambient ❑ ry ❑ (based'oncduntyJ (rdger2cynarne/° ❑Surface Estua Canal RiverBasrn bate 4/7/2015 ❑Routine ❑stormwater Received°By ` ❑comliance 3 i State Courier p QGround OMonitoringWell ❑Water Supply DeliveryllRethvd ' ❑Hand Delivery Notes: Time 1:27 PM ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: ❑� ❑Chlorinated ❑De-chlorinated in Field Sampling Grab LjComposite� [:]Emergency ❑ ❑Field BlankBlank ❑Trip Blank Method ❑Other: ❑Filter Blank Temperature(,'C) El Filtered in Field IeDepth ❑ ❑ p ❑Other. m Dissolved analysis:Enter"DIS• Sam ., QA Solution onAval._ in check-boxes for parameters 1t k Collectors Comments.•, Microbiology Parameterwa,"' < ,_ "4 MBAS(surfactants) mg/L Metals parameters:., -s �„ . Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(5b) µg/L X Vanadium(V) µg/L Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total5olids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /loom[ Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100m1 Silica mg/L X Chromium(Cr),Total µg/L Organics Parafneters: _' Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organon[trogen Pesticides Other Parameters:;, X Lead(Pb) µg/L Organophosphorus Pesticides n , WethemistiyParameters , % - pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L ,Nutrients Par,ameters. ., �: " X Molybdenum(Mo)' µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) X mg/L Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Paramefers(opaana't): Water Temp(°C): pH(s u) Dissolved Oxygen(ppm)➢ ' Conductivity(µmhos/crri}: Sat[rity(ppt}: • „ Revision:2/06/2015 Aiz r-A 3 AC18220 North Carolina D ion of Water Resources Water Scienct action Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW6 Sample ID: AC18220 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 16GO117 Region: ARO Report To ARO Location ID: 1P11MW6 Date Received: 04/09/2016 River Basin Collect Date: 04/07/2015 Priority GROUNDWATER Time Received: 08_05 Emergency Collect Time: 12_24 Sample Matrix: GROUNDWATER Labworks LoginlD TASCENZO1 COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 514/15 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Units Method Analysis CAS# Analyte Name PQL Qualifier Reference Date Validated by LAB Sample temperature at receipt by lab 2.4 °C 4/9/15 CGREEN MET 7440-22-4 Ag by ICPMS •1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7429-90-5 AI by ICP 50 360 ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/15/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 140 ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 Rev3 4/14/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.84 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 0.89 mg/L EPA 200.7Rev4.4 4/15/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/22115 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 13 ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources li3sltlD: Tag Cab e--,VI IY t' Water Sample Collection&Submittal Form o ttanat ID"` ---- ---------- Central Laboratory(Water Sciences Section) f P J Ltiboratdry Ldcatian•Dexerlpton; Asheville Airport-Monitoring Well MW6 Location Code• 1 P11 MW6 lveg; I Date Rece it. " Zl t Buncombe Collector ,".R Brett Laverty -Priority:v Wote_rMatrix ,t., taiat✓onTye rrne Received: DWRRegtor%` D€A/R�O�ce.°q River/Stream ❑Lake T * 1 Asheville ❑Ambient. �❑ ❑ �(brrsedoncountyj (oragencyrtame) El Surface EstuaryCanal �° ❑ ' Routine ❑Stormwater Received 8y: River eosin �� Date' 4/7/2015 " ❑✓ Compliance QGround ❑✓ Monitoring Well ❑Water Supply } State Courier Notes: Time 12:24 PM Delivery Method., El Hand Delivery ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: Spmpling ,1 QGrab Composite ❑ ❑ [—]Field Blank ❑Chlorinated ❑De-chlorinated in Field Emergency Blank ❑Trip Blank Method ., El Other: [—]Filter Blank Temperature(`Q Dissolved analysis:Enter"DIS" onArrftral: El Filtered in Field in check-boxes for parameters 'SGmpleDepth; ❑GA ❑Solution ❑Other: Collector sComments:.— �iVllcrobioloryParametets. �t '`�- MBAS(surfactants) mg/L MetaieParameters:, - f„ Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100m1 Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters: Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides OtherParameters:y-- s X Lead(Pb) µg/L Organophosphorus Pesticides WetChernistryParamefets:, ;�; pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L• X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L "'NutrientiParameterss. ''_ X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L -Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: r Field Parameters(opdonal) Water Temp(°C}: ;pN(s u} Dissolved Oxygen(ppm)`: Conductivity{µmhos/cm):. ' Salinity{apt): a Revision":2/06/2015 AILOJ AC18219 North Carolina D ion of Water Resources Water Science. action Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW7 Sample ID: AC18219 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15G0116 Region: ARO Report To ARO Location ID: 1P11MW7 Date Received: 04/09/2016 River Basin Collect Date: 0 4/0 712 0 1 6 Priority GROUNDWATER Time Received: 08_05 Emergency Collect Time: 10_31 Sample Matrix: GROUNDWATER Labworks LoginlD TASCENZ01 CDC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 614116 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.4 °C 4/9/15 CGREEN MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7429-90-5 - AI by ICP 50 390 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/22115 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 11 ug/L EPA200.7 Rev4.4 4/15/15. ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA200.7 Rev4A 4/17/15 ESTAFFORDI 7440A7-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5A 4/20/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20115 ESTAFFORD1 7439-89-6 Fe by ICP 50 230 ug/L EPA 200.7 Rev4.4 4/17/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/14115 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 1.1 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORDI 7439-96-5 Mn by ICP 10 67 ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/22/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.1 mg/L EPA200.7 Rev4.4 4/15/15 ESTAFFORD1 7440-02-0 ' Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/20/15 ESTAFFORDI 7440-28-0 Thallium(TI)ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/22115 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/17/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/20/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources VisitFD TO 7, Lah Use on/y Water Sample Collection&Submittal Form ---^ ---- ------------`=-----`- Central Laboratory(Water Sciences Section) (opttanaiJ iD laboratory r, Sample Number: tocation tfon Asheville Airport-Monitoring Well MW7 locdtiori Cade: 1 P11 MW7 Yt 11 Date Recdv6d County Buncombe Co�%ctor Brett Laverty uPr16rity° �� WatexMatrix:, «� Location DWR��Re io ice:e�( ❑ / ream Lake Time Received DWRO/ .° Asheville ❑ambient River st(trosedon, -tyJ, {orvgencynomeJ ❑Surface Estuary ❑Canal Received°By ° ❑Routine ❑Stormwater River oasis: 'Date 4/7/2015 ❑✓ Compliance ❑✓ ❑� M [:]Water onitoring Well Water Supply State Courier � DeliveryMethod:r El Hand Delivery Notes: Time 10:31 AM ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: Sompiiirg I Q Grab LjComposite ❑Field Blank ❑Chlorinated ❑De-chlorinated in Field ❑Emergency []Blank [:]Trip Blank ❑ M2thodi�` ❑Other: Filter Blank Temperature(CJ� anAnfval<°p.; Dissolved analysis:Enter"DIS" ElFiltered in Field ❑Other: In check-boxes for parameters Saipple Dep#h: ❑C!A ❑Solution Collectors Coramerits: Microbiology'Parameters: _ MBAS(surfactants) mg/L Mewls Parameters: r _x Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L Boo:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics`Parameb rsi. ` Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Cc) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides 'Other l?4ameters' X Lead(Pb) µg/L Organophosphorus Pesticides Wet Chemistry`Parameters:' 7 7, 7, 7 pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients"Paramete>s:"" X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-1\1) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.u. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological: Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L r4Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters(optrono!)3 WaterTemp(°C): pt (s u) Dissolved Oxygen,(ppm)o Conductivity(µmhos/cm). Salinity(Opt): Revision:2/06/2015 )q a64 Y AC18339 North Carolina D ;on of Water Resources Water Sciencl -Iction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW1A Sample ID: AC18339 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO136 Region: ARO Report To ARO Location ID: 1P11MW1A Date Received: 0 4/1 512 0 1 5 River Basin Collect Date: 04/09/2016. Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 10_10 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4/15 Report Print Date: 05l04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7429-90-5 AI by ICP 50 120 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 19 ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4122/15 ESTAFF0RD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFF0RD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFF0RD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 85 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/28/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.9 mg/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 22 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 2.7 mg/L EPA 200.7 ReAA 4/21/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFF0RD1 7440-24-6 Sr by ICPMS 10 31 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/22/15 ESTAFF0RD1 7440-66-6 Zn by ICPMS 10 16 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFF0RD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources Yisat II) e gQ 6b Water Sample Collection&Submittal Form ----` Central Laboratory(Water Sciences Section) (oponat) !D s Laboratory zearitpte Numbers Location Descnpt or Asheville Airport-Monitoring well MW 1 A tocca run Cade.I MW 1 A w Date Received County Buncombe Collector,, Brett Laverty ,Pnarrty Wate Matrix. OCA0on,Type . � �-�--y � .� i Torte Received DWR_ReglOn b61!RO; ce., Asheville ❑Ambient lJRiver/Stream Lake (6AsedOgcountyj (oragencynamep ❑Surface ❑Estuary ❑Canal ❑Routine ❑Stormwater Recerved8y , .Over Basal Date, ;, 4/9/2015 , A State Courier ❑Compliance ❑� Ground ❑� Monitoring Well -]water Supply Notes: CCB Area 4rt71e ° ;� 10:10 AM Delivery Method`° ❑Hand Delivery ❑COC ❑Waste ❑Effluent ❑Influent ❑Other: Sompling,r� QGrab Composite ❑Field Blank r' ' ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank g t. Methods ' ❑Other: ❑Filter Blank Temperature{ C Dissolved analysis:Enter^DIS" k on 4rrrvai ❑Filtered in Field in check-boxes for parameters >5amp/e L38pths- ❑QA ❑Solution ❑Other. ° "icollectvr's Camrraertts:°"l MiErobiotogyarartfdters. <�„ .:: MBAS(surfactants) mg/L �" `Metai5Param"etr?rs:° �_ °1 Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(6),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L. Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L °' Organics Parameters:'° Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other Parhmeters.3 r _ `_ ��,�� X Lead(Pb) µg/L Organophosphorus Pesticides �x WettfiemistryPararekers ° .: ; S.U. Lithium{U) µg/L PCBs(polychlorinated bi hen Is )pH Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L .m_ Nutnsrtts,Parametiers; X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) _ mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L aeiologlcal:' ` a Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae 4 Hexavalent Chromium(Cr6+) mg/L IF70rthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters(aprldnagj: °`Water temp(,C): ` N Hl(s u). <- r Dissolved Oxygen(ppm): a; Conductivity{µ nhos(cm):` Salinity(Pp Revision:2/06/2015 A2EA K AC18341 North Carolina D. _ .on of Water Resources Water Sciew -lction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW2 Sample ID: AC18341 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO137 Region: ARO Report To ARO Location ID: 1P11MW2 Date Received: 04/15/2015 River Basin Collect Date: 0410912016 Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 12_16 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT CDC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 514/15 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Units Method Analysis CAS# Analyte Name PQL Qualifier Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7429-90-5 AI by ICP 50 73 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 26 ug/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 ReAA 4/22/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/28/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.8 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 21 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 4.3 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4123115 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 13 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 12 ug/L EPA200.8 Rev5.4 4123/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources Visit ID. _ ITai, Q7 Sample Collection&Submittal Form ------ Water - -- " `-- Central Laboratory(Water Sciences Section) (OttandlY ' 1D° La4oratory� y. � 5ampleNamber:_ tocatlan Descrrptron: Asheville Airport-Monitoring well MW2 toca#ion Code 1 P11 MW2 ' ` � � _ Dofe Received County w° .,r Buncombe Collector. Brett Laverty Priority,. INoterMatrix: docatron„Type i River/ DWR-Reglom.. D!t)/R Office: _❑` Tfine Recerverrl Asheville ❑Ambient am La ke (based oncaunty)� . « (or age El ❑ Surface Estuary ❑ Canal Received ey. ❑Routine ❑Stormwater River Basins a ,.Date., 4/9/2015 Compliance QGround OMonitoring Well ❑Water Supply q State Courier Notes: CCB Area 4 Time 12:15 PM DeilveryMethod: ❑Hand Delivery ❑COC [:]Waste ❑Effluent [-]Influent ❑Other: Spitrptfog ❑✓ Grab Composite Emergency ❑Blank ❑Field Blank [-]Trip Blank ❑Chlorinated ❑De-chlorinated in Field ;Methad „ ❑ ❑ Temperature- "C ❑Other: Filter Blank ) ElFiltered in Field Dissolved analysis:Enter"DIS" Sample ❑QA ❑Solution anArrrval in check-boxes for parameters ❑Other; !?epthr 61mctor's Comments: Microbiology Parameters: L Al.'A' 4 MBAS(surfactants) mg/L Metals Parameters: w Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L CBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100mll Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Okgaiiild 12ar46e46s: _ Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other Parameters: X Lead(Pb) µg/L Organophosphorus Pesticides Wet Chemistry;Parameters: pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) �� Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients'Parameters: ri :i' X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L kX Sodium(Na) mg/L 'elological: ' Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/LStrontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/LThallium(TI) µg/L LAB COMMENTS: field Paratneters(optionoo 'Water Temp(°C)i-I pH(s u): , Dissolved Oxygen{ppm Conductivity(µmhos/cim):a T= Sa{ir ity(ppt):,a; Revision:2/06/2015 AC18343 North Carolina Diyj.sion of Water Resources Water Sciencl__ -,ction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MWS Sample ID: AC18343 County: BUNCOMBE , Collector: B LAVERTY VisitlD PO Number# 15GO139 Region: ARID Report To ARO Location ID: 1P71MW5 Date Received: 04/15/2015 River Basin Collect Date: 04/09/2016 Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 13_47 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT CDC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4116 Report Print Date: 0 6/0 412 01 8 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name - PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7429-90-5 Al by ICP 50 65 ug/L EPA200.7 Rev4.4 4/22115 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5A 4/23/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 170 ug/L EPA200.7 Rev4.4 4/21/15 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L, EPA200.7 Rev4.4 4/22115 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/28/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 4.8 mg/L EPA200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 91 ug/L EPA200.7 Rev4.4 4/22115 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 10 mg/L EPA200.7 Rev4.4 4/21/15 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5A 4/23/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 67 ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-28-0 Thallium (TI)ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 276994623 (919)733-3908 "Not Detected"or"U'does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources a Y1AtID: .• Ta� � Lab O67l41 -- --- '- '- '--- Central Laboratory(Water Sciences Section) Water Sample Collection&Submittal Form (opttarlaO� 113 Cafioratory, Sample Number:: Location Descriptfon:i Asheville Airport-Monitoring well MW5 Location Code 1 P11 MW5 ` to rved Pa Rece County ti Buncombe ff'Collector p Brett Laverty Priority Water Matrix Location 7ype Time Received.- DWRRegiOti: DWROjffice ❑River/Stream Lake Asheville ❑Ambient (fiased on county) .. (Orag,aocxname) ❑Surface ❑Estuary ❑Canal Received By: ' $ ]Routine ❑Stormwater River Basin:.w, .Date 4/9/2015 OCompliance ❑✓ Ground ❑✓ Monitoring Well ❑Water Supply LJ State Courier Notes: CCB Area 4 41me 1:47 PM DeliWeryMethodb ❑Hand Delivery ❑COC ❑Waste [_]Effluent ❑Influent ❑Other: Sampling= QQ Grab Composite ❑Field Blank z _ ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank McH►od. "^ ❑Other: ❑Filter Blank Temperature:{°CT Dissolved analysis:Enter"DIS" j onArrlval: ,. ❑Filtered in Field in check-boxes for parameters 5ampte Depth: ❑QA ❑Solution ❑Other. I ( e011ectorsC0MMents• 1=:IVlicrobiolagylParameters , MBAS(surfactants) mg/L .„ „Metals Parameters; Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L I Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Otiipies Parametdrsi Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides otherlFarnmeters._ X Lead(Pb) µg/L Organophosphorus Pesticides Wet:Chemistry Parameters.« pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutdents:Parameterss. X Molybdenum(Mo) lig/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI c.u. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological:" Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: 61eldFarameters(opt7ona(1: "WaterTemp(°C):`= z "PH(su): Dissolvedroxyge6'(ppm).' Conductivity(µmhosJcm)" _ .'Salinity(ppt)aE Revision:2/06/2015 A n6-(A L/ AC18342 North Carolina Division of Water Resources Water Science_ ._action Laboratory Results Loc.Descr.: AHEVILLE AIRPORT-MONITORING WELL MW5D Sample ID: AC18342 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO138 Region: ARO Report To ARO Location ID: 1P11MW5D Date Received: 04/16/2015 River Basin Collect Date: 04/09/2016 Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 12_68 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4115 Report Print Date: 05/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Units Method Analysis CAS# Analyte Name PQL Qualifier Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7429-90-5 AI by ICP 50 61 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5A 4/23115 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23115 ESTAFFORD1 7440-38-3 Ba by ICP 10 24 ug/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 62 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 Rev3 4/28/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.8 mg/L EPA 200.7 Rev4.4 4121/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-23-5 Na by ICP 0.10 6.3 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23115 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 89 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23115 ESTAFFORD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources LQ'�7 tlSe_Dl?JJf:•' a,t Water Sample Collection&Submittal Form h --- -- Central Laboratory(Water Sciences Section) (o�itlonat� 1D Cabortitory " s g sohiple Number. Ldratl:' "A 9�crll}tiot, Asheville Airport-Monitoring well MW51D Location Code;, 1 Pi MW51D � III gw �. Date Received,, County ;_ 4 ;;,� Buncombe Collector Brett Laverty °Pr,for�tyaw, WoterlMafri�G tocattoriT,y�e 666 " TtM Fecelved 0 R' egion: DWROf¢iee..°' ❑River/Stream ❑Lake ° Asheville []Ambient , Q (bdsed'bncaur?0) (o�agencynameJ ❑ []Estuary Estuary ❑Canal � � Received By:° r ❑❑Routine Stormwater River i6hi , Date 4/9/2015 ❑✓ Compliance OGround OMonitoring Well ❑Water Supply al State Courier Notes: CCB Area 4 Ume ,°�° 12:58 PM Delveryli�ethod$ ❑Hand Delivery ❑COC ❑Waste ❑Effluent ❑Influent Other: salro g QGrab Composite ❑Field Blank ❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank " G f Method Pwr ❑Other: ❑Filter Blank Temperrrturer tj Dissolved analysis:Enter"DIS" onArnvol El Filtered in Field sampleDgpth: in check-boxes for parameters l ;� ❑C!A ❑Solution ❑Other: v 111111 Collectors commenty.1, Micro6iology,'Parametrs ,� ,;; ,n° �° MBAS(surfactants) mg/L Metals Parameters:,= -, Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(Al) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L. Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters:" Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Capper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides MQtHec�Parameters;,,, % X Lead(Pb) µg/L Organophosphorus Pesticides Wet ChemisttyParaineters ° `- ,' : , �m pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X I Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L NutrientsParameterso , X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L. 181ologitali l Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(5r) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field parameters(optional Water,Tem (°C p! (s u) ° Dissolves Orygen(ppm):y Conductivity(µmhos/cm) Salinity{pptp' P r) , Revision:2/06/2015 AnE?q. � AC18337 North Carolina Division of Water Resources Water Science action Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW6 Sample ID: AC18337 County: BUNCOMBE Collector: B LAVERTY VisitID PO Number# 15G0133 Region: ARO Report To ARO Location ID: 1P11MW6 Date Received: 04/15/2015 River Basin Collect Date: 04/09/2015 Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 03_28. Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 514/16 Report Print Date: 06/04/2018 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7429-90-5 Al by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4122/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-38-3 Ba by ICP 10 29 ug/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA 200.7 Rev4A 4/22/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4128/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.3 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA 200.7 Rev4A 4/22/15 ESTAFFORD1 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-23-5 Na by ICP 0.10 2.9 mg/L EPA 200.7 Rev4A 4121/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-24-6 Sr by ICPMS 10 30 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-28-0 Thallium(TI) ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4122/15 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23115 ESTAFFORD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources V sttID To Lc�b t7S4:0 ly. Water Sample Collection&Submittal Form Central Laboratory(Water Sciences Section) (gAtivna!) -� lQ, `Laboratary Sample Ntirnber . tjocptfon Description: Asheville Airport-Monitoring well MW6 Locat►on Bode: 1 P11 MW6 y 333333 i Date Recelved N a County,., » °° Buncombe Ca/lector': Brett Laverty Prrorfty: Water Matrix., a Locatioo=Type tDWRReyron:) II DWRO ,y ❑River/Stream-�-❑Lake TimeReceivcd hasedpn aue ora encynume Asheville ❑Ambient ❑ ry El Surface Estua ❑Canal °Recerved By: VerBastlt Date "` .4/9/2015 ❑Routine ❑Stormwater ❑� Compliance ❑� Ground ❑Monitoring Well ❑Water Supply : . State Courier DeNveryMetfrod ❑Hand Delivery Notes: CCB Area 4 7me 3:28 PM ❑coc ❑Waste ❑Other: ❑Effluent —Influent ;om'pf lil ° EGrab Composite ❑Field Blank ` ❑ Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method El Other: Filter Blank Temperature]"Cj ❑ ' Dissolved analysis:Enter"DIS" aiaArrival ❑Filtered in Field Sample Depth: ❑QA ❑Solution ❑Other: in check-boxes for parameters 11 C611eciorYCoinnients: Nlicrohiology Parameters: MBAS(surfactants) mg/L Metals Parameters: Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /10oml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parametersr Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides OtherParameters:° � ` a X Lead Pb( ) µg/L Organophosphorus Pesticides WetChemistrvParameters: pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients Parameters X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological: '° Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters(opdcnotl: WaterTemp(°C). p,H(s u);; Dissolved Oxygen(ppm)r; Conductivity(µmhos/cm).' Salinity(ppt): Revision:2/06/2015 fi Orl � AC18338 North Carolina Division of Water Resources Water Science_ _action Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MONITORING WELL MW7 Sample ID: AC18338 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 15GO134 Region: ARO Report To ARO Location ID: 1P11MW7 Date Received: 04/15/2015 River Basin Collect Date: 04/09/2016 Priority GROUNDWATER Time Received: 08_00 Emergency Collect Time: 02_45 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4/15 Report Print Date: 05/04/2018 Final Regort If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15/15 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7429-90-5 Al by ICP 50 110 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 53 ug/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 ReAA 4/22/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 ReAA 4/22/15 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5A 4/23/15 ESTAFFORDI 7439-89-6 Fe by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 Rev3 4/28/15 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.73 mg/L EPA 200.7 ReAA 4/21115 ESTAFFORDI 7439-96-5 Mn by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.3 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-28-0 Thallium (TI) ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources YisitID." To Water Sample Collection&Submittal Form Central Laboratory(Water Sciences Section) (apttanaEj @ Laborptary "Sample Nun tocatidmDescriodonr Asheville Airport-Monitoring well MW7 Loc ation Coder 1 P11 MW7 a. Dote fiecerved: County Buncombe Collector Brett Laverty Priority 5 Water Matrix; Location Type Tnrie Recetded:� 1 OWR�Regipnrg I7WR Office:. ❑River/Stream Lake 4 ( � .:,, Asheville ❑Ambient ❑ ❑ 6ased;onsaun (orogencynamek ❑Surface EstuaryCanal Recenred� ❑Routine ❑Stormwater River Basin: Date 4/9/2015 LJ OCompliance QGround Monitoring Well ❑Water Supply State Courier Notes: CCB Area 4 � Time 2:45 PM DellveryMethod:l ❑Hand Delivery ❑COC ❑Waste ❑Effluent ❑Influent ❑Other 5oi»pling DGrab Llcomposite ❑Field Blank ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method .,:` ❑Other: ❑Filter Blank Teniperaturg Dissolved analysis:Enter"DIS"in check-boxes for parameters onArrivol c ❑Filtered in Field Somp1eDepth ❑QA ❑Solution ❑other. S Collectorfs.Comments:.;'„ Mic[obiologyj?arameters: _ a MBAS(surfactants) mg/L Metals Parameters:., ,; ="r e ,._,p Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical Oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100m1 Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /100ml TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters'. Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides ether Pa[anieter5,,," X Lead(Pb) µg/L Organophosphorus Pesticides Wet Chemistry:Paraineters..z s. M ,...: ti F. ° pH S.U. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/1- X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L Nutrients'PaYameters. X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological; Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L Orthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: ,Field Parameters' y WaterTemp(°C): pH(s u),f, . Dissolved Oxygen(ppm). Conductivity(µmhos/cm):,,, Salinity(ppt); Revision:2/06/2015 �12&4 y AC18340 North Carolina Division of Water Resources Water Science_ .__,ction Laboratory Results Loc.Descr.: ASHEVILLE AIRPORT-MON ITORING WELL MW9 Sample ID: AC18340 County: BUNCOMBE Collector: B LAVERTY VisitlD PO Number# 16GO136 Region: ARO Report To ARO Location ID: 1P11MW9 Date Received: 04/15/2016 River Basin Collect Date: 04/09/2016 Priority GROUNDWATER Time Received: 08:00' Emergency Collect Time: 11_21 Sample Matrix: GROUNDWATER Labworks LoginlD MSWIFT COC Yes/No Sample Depth Loc.Type: Monitoring Well Delivery Method NC Courier Final Report Date: 5/4/15 Report Print Date: 0 510 4/2 01 8 Final Report If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Units Method Analysis CAS# Analyte Name PQL Qualifier Reference Date Validated by LAB Sample temperature at receipt by lab 2.7 °C 4/15115 MSWIFT MET 7440-22-4 Ag by ICPMS 1.0 1.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7429-90-5 AI by ICP 50 53 ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-38-3 Ba by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORDI 7440-41-7 Be by ICP 5.0 5.0 U ug/L EPA 200.7 Rev4.4 4122/15 ESTAFFORDI 7440-43-9 Cd by ICPMS 0.50 0.50 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-48-4 Cobalt by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4122/15 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 Rev3 4/28/15 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.8 mg/L EPA 200.7 Rev4.4 4/21/15 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7439-98-7 Mo by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-23-5 Na by ICP 0.10 7.1 mg/L EPA 200.7 ReAA 4/21/15 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5A 4/23/15 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-24-6 Sr by ICPMS 10 64 ug/L EPA 200.8 Rev5.4 4/23/15 ESTAFFORD1 7440-28-0 Thallium (TI)ICPMS 2.0 2.0 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORDI 7440-62-2 V by ICP 25 25 U ug/L EPA 200.7 Rev4.4 4/22/15 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 Rev5.4 4/23/15 ESTAFFORD1 WSS Chemistry Laboratory>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 "Not Detected"or"U"does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL. Page 1 of 1 North Carolina Division of Water Resources =(:Istlillll� Water Sample Collection&Submittal FormCentral Laboratory(Water Sciences Section) i0 ( toboiotoryh+ ` , n Sample&UMbek.. Eocatrondlescripfion:, Asheville Airport-Monitoring well MW9 Coca�ion Code,j 1 P11 MW9 E Date Received•. County °` Buncombe collector Brett Laverty Prtorityi Wafer Matrix: i&ationT pe ° t DINd?Region::: DW.R Q�ce•14 "River/Stream Time Received. Ambient Lake Asheville ❑ (boseiloncountyJ: (oragencpnaMe ❑Surface ❑Estuary ❑Canal r " Routine ,ReceivedBy fterBa3rn Date 4/9/2015 ❑ ❑Stormwater Ocomliance ✓ ✓ Lj State Courier p ❑Ground ❑Monitoring Well ❑Water Supply s ' Notes: CCB Area 4 Time 11:21 AM DetiveryMethod: Hand Delivery ❑COC ❑Waste Effluent ❑Influent[:]Effluent &whpiing� OGrab Composite —]Field Blank r �~ ❑Chlorinated ❑De-chlorinated in Field ❑Emergency ❑Blank ❑Trip Blank Method ,°. ❑Other. ❑Filter Blank Temperatuie"i Cj' Dissolved analysis:Enter"DIS" an Amvad: ' El Filtered in Field Sample Depth`� ❑QA ❑Solution ❑Other: in check-boxes for parameters Coddector's Comments: Microbiology Parameters: MBAS(surfactants) mg/L Metals Parameters. Tin(Sn) µg/L Acidity,as CaCO3,to pH 4.5/8.3 mg/L Oil and Grease,HEM,Total Recoverable mg/L X Aluminum(AI) µg/L Titanium(Ti) µg/L Alkalinity,as CaCO3,to pH 4.5/8.3 mg/L Phenols,Total Recoverable µg/L X Antimony(Sb) µg/L X Vanadium(V) µg/L BOD:Biochemical oxygen Demand,5-day mg/L Residue:Total(Total Solids) mg/L X Arsenic(As) µg/L X Zinc(Zn) µg/L cBOD:Carbonaceous BOD,5-day mg/L Residue:Volatile/Fixed,Total mg/L X Barium(Ba) µg/L Coliform:Fecal MF /100ml Residue:Suspended(Suspended Solids) mg/L X Beryllium(Be) µg/L Boron(B),Total µg/L Coliform:Total MF /100ml Residue:Volatile/Fixed,Suspended mg/L X Cadmium(Cd) µg/L Mercury 1631,low-level ng/L Coliform:Tube Fecal /10om1 TDS-Total Dissolved Solids mg/L Calcium(Ca) mg/L Coliform:Tube Total /100ml Silica mg/L X Chromium(Cr),Total µg/L Organics Parameters; = Specific Conductance,at 25°C umhos/cm Sulfide mg/L X Cobalt(Co) µg/L Acid Herbicides TOC-Total Organic Carbon mg/L Tannin&Lignin mg/L X Copper(Cu) µg/L Organochlorine Pesticides Turbidity NTU X Iron(Fe) µg/L Organonitrogen Pesticides Other Parameters:1 F X Lead(Pb) µg/L Organophosphorus Pesticides W04'ChemistryParam@'tars pH s.u. Lithium(Li) µg/L PCBs(polychlorinated biphenyls) Bromide mg/L Hardness,Total as CaCO3-by titration mg/L X Magnesium(Mg) mg/L Chloride mg/L X Manganese(Mn) µg/L Semi-Volatile Organics(BNAs) Fluoride mg/L X Mercury(Hg) µg/L TPH Diesel Range Sulfate mg/L ,NutrientsParameters. X Molybdenum(Mo) µg/L Chlorophyll a µg/L Ammonia as N(NH3-N) mg/L X Nickel(Ni) - µg/L Volatile Organics(VOA) Color:ADMI C.U. Nitrate-Nitrite as N(NO3+NO2-N) mg/L Potassium(K) mg/L. Color:Platinum Cobalt C.U. Total Kjeldahl Nitrogen as N(TKN) mg/L X Selenium(Se) µg/L TPH Gasoline Range COD:Chemical Oxygen Demand mg/L Total Phosphorus as P(TP) mg/L X Silver(Ag) µg/L Cyanide,Total mg/L Nitrite as N(NO2-N) mg/L X Sodium(Na) mg/L Biological., Formaldehyde mg/L Nitrate as N(NO3-N calculated) mg/L X Strontium(Sr) µg/L Phytoplankton/Algae Hexavalent Chromium(Cr6+) mg/L HOrthophosphate as P(PO4) mg/L X Thallium(TI) µg/L LAB COMMENTS: Field Parameters(opt/onatJ: WaterTemp(°C):r;� pH Ss u) n ` Dissolved Oirygen(ppm}.`w^„ Conductivity(µmhosJcm)r Salinity(PPt) r , Revision:2/06/2015 1. DUKE Duke Energy Progress ASVL PLT 1 200 CP&L Dr ENERGY® Arden, NC 28704 PROGRESS Certified Mail: 7011 1570 0003 3848 4271 File Pt.: 12520-Q January 15, 2015 Mr. G.Landon Davidson EIVE® NCDENR/DWR Aquifer Protection Section Division of lNater Resources 2090 U.S. 70 Highway Swannanoa,NC 28778 JAN 20 2015 RE: Duke Energy Progress Asheville Steam Electric Plant Asheville Airport Areas I,IV, and III Fill Projects Water ouaRty Regional operations November 2014 Groundwater Monitoring Results Asheville Regional ofrice Dear Mr. Davidson: Attached are the results from the most recent semi-annual groundwater monitoring sampling event conducted in November 2014 for the wells near the Areas I, IV, and III of the Asheville Regional Airport coal ash structural fills. The results from these sampling events are included on the GW59CCR forms normally used for groundwater monitoring results around ash basins per the recommendation from Jon Risgaard of the Non-Discharge Permitting Unit. As these structural fill sampling events are not part of an NPDES permit, this form was slightly modified and is not signed. Please note that MW-9 within Area IV was not accessible during the sampling event and therefore was not sampled. The inaccessibility was due to a 9.86-foot extension of the top-of-casing on the well, a result of the ongoing construction at the site whereby overburden has been removed. Also attached are groundwater contour maps as prepared by SynTerra Corporation for these sampling events. The volume of leachate discharged to the Metropolitan Sewerage District(MSD) of Buncombe County,North Carolina since June 2014 through November 2014 from Area IV and Area III fill projects is as follows: Area IV,Phase 2- 4.1046 MG Area III- 7.5824 MG All leachate monitoring results were in compliance with the respective permits with one exception of a high pH reading in July for Area III Permit G-0363. This value was determined to be the result of a faulty instrument. The instrument was repaired on the same day. Attached are the Industrial Self-Monitoring Reports for June 2014 through November 2014 that were submitted to the MSD. There has been no leachate removed via pump and haul. Please contact Ms.Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. Sincerely, Garry A.Whisnant Attachments Asheville Plant Manager www.duke-energy.com I GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT&NATURALRESOUBCES z , ., COMPLIANCE REPORT FORM DIVISIONOFWATER;QUALITY 1NFORMQ'FIONPROCESSINGUNi1=' M1-6117 MdICSERVICE C NTEB,RAtE1GH NC27.6981617'Phone(919)733 322 FACILITY INFORMATION Please Print Clearly orType Facility Name: Asheville Regional Airport ;. Permit Type: DORS Expiration!Date: F 2/2E/2015 Permit Name(if different): Duke Energy Progress,Inc. PERMIT Nurnber:1 WQ0000020 Facility Address: 61 Terminal Drive " (Street) TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill Fletcher IN 28732 County Buncombe (City) (State) (zip) Contact Person: Laurie Moorhead Telephone# 828-687-5240 Well Location/Site Name: • Structural Fill Area I "' No.of wells to be sampled: . 4 ` (from Permit) Well ID Number(From Permit) Units MW1A-Al MW2A-A3 MW4A-Al* MWS-Al MW- MW- MW- MW- MW- MW- MW- MW- MW- MW- MW- MW- MW- MW- Well Depth [ft below land surface] ft 20.00 15.00 45.00 57.00 Measuring Point(toc)[ft above land surface] ft 2.72 3.56 -0.17 3.08 Well Diameter r in 2.0 2.0 2.0 2.0 Screen Top[ft below land surface] G "qu ft 5.00 5.00 30.00 42.00 Screen Bottom [ft below land surface] ft 20.00 15.00 45.00 57.00 Relative Measuring Point Elevation ft 2100.40 2102.71 2151.55 2153.86 ,a.:. _< :-: � _ m bn _ alto ,a el .,, , ,, ,. � ..: ..,.. _,_. �_,. _ _ „ . ,Sa. Inform n nd, i_d n sis _ ,�.. _, __-sue___ _ � ._ ,� ,� _,:_ ��, :.. P. !i, E Y �<..... .y,.. _ �..�.. .._<„nR� Fa'W', �FSAFs -- � CHECK IF DRY WELL AT TIME OF SAMPLING ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY 1SA-2L Units MW1A-Al MW2A-A3 MW4A-Al* MWS-AS Sample Date - 11/05/2014 11/05/2014 11/05/2014 11/05/2014 - Water Level[ft below measuring pt.](82546) ft` 7.37 0.82 19.76 37.63 Volume of Water pumped/bailed gal 0.50 0.60 0.50 2.50 Temperature(00010) deg.C 15.0 15.0 16.0 17.0 Odor(00085) None None None None Appearance Normal Normal Normal Normal Turbidity(8207B) NTU 1.4 1.1 0.8 25.3 Dissoved Oxygen(00300) mg/L 6.1 3.8 0.4 6.2 Oxidation Reduction Potential(00090) mV 272 289 150 309 - Specific Cond field(00094) ' umhos/cm 47.0 36.4 84.0 22.6 PH-field(00400) fi.S-8.5 SU 5.3 5.2 4.8 4.9 n WOO Laboratory Name Pace Analytical Services Certification# NC DENR ff 40 Samples for metals were collected unfiltered: Yes ❑ No SampleAnalysis.Date November fi-iS,z01a ,and field acidified: Yes ❑ No 1SA-21. Units MW1A-Al MW2A-Al MW4A-A3* MWS-Al I Sb-Antimony(01097) 1 ug/I <0.5 <0.5 <0.5 <0.5 As-Arsenic(01002) 10 ug/I <5 <5 <5 <5 Ba-Barium(01007) 700 ug/I 15.6 15.3 26.4 21.8 B-Baran(01022) 700 ug/I <50 <50 <50 <50 Cd-Cadmium(01027) 2 ug/I <1 <1 <1 <1 Cl-Chloride(00940) 250 mg/I 1.7 .2.5 2.2 1.8 - Cr-Chromium(01034) 10 ug/I <51 <5 <5 <5 Cu-Copper(01042) - 1 mg/I <0.005 <0.005 <0.005 <0.005 " Fe-Iron(01045) 300 ug/I <50 <50 3320 413 Pb-Lead(01051) 15 ug/I <5 <5 <5 <5 Mn-Manganese(01055) s0 ug/I <5 <5 864 49 Fig-Mercury(71900) 1 ug/I <0.2 <0.2 <0.2 <0.2 4 Ni-Nickel(01067) 100 ug/I <5 <5 <5 <5 Nitrate(NOj as N(00620) 10 mg/I 0.82 0.25 <0.021 0.78 Se-Selenium(61147) 20 ug/I <10 <10 <10 <10 SO*-Sulfate(00945) 250 mg/I <2 <2 5 <2 TI-Thallium(03059) 0.2 ug/I <0.1 <0.1 <0.1 <0.1 TDS-Total Diss.Solids(70300) Soo mg/I 26 <25 30 <25 Zn-Zinc(01092) 1 mg/I <0.01 <0.01 <0.01 <0.01 AI-Aluminum(01305) ug/I N/A N/A N/A N/A I Turbidity is field analyzed for Information use only. Notea: I certify that,to the best of my knowledge and belief,the information submitted in this report is true,accurate,and complete,and that the laboratory analytical data was,produced using approved methods of analysis by a DWQ-certified laboratory, I am aware that there are significant pena Ftes for subi-nitUng false information,including the I possibility of fines andjmprisonment for knowing violations, Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) Date GW-59CCR-Voluntary *-Denotes Background Well (B)-Laboratory"B"flag i i y a GROUNDWATER QUALITY MONITORING: DEPARTMENT OF ENVIRONMENT&'NATURAL RE56URCES COMPLIANCE REPORT FORM DIVISION OF WATER QUALITY,,-INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER;RALEIGH NC 27699-1617 vPhone:(919)733-3221 'a FACILITY INFORMATION Please Print Clearly or Type Facility Name: Asheville Regional Airport Permit Type: DORS Expiration Date: 2/28/2D15 Permit Name(if different): Duke Energy Progress,Inc. PERMIT Number: WQ0000020 Facility Address: 61 Terminal Drive (Street) TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill Fletcher NC 28732 County Buncombe (City) (State) (Zip) Contact Person: Laurie Moorhead Telephone# 828-687-5240 Well Location/Site Name: Structural Fill Areas III&IV No.of wells to be sampled: 14 (from Permit) _ Monitoring Well Constructionlnformation _ Well ID Number(From Permit) Units MW-3A ' MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-S-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-S-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 MW- MW- MW- Well Depth [ftbelow land surface] ft 84.50 58.00 63.00 65.00 34.00 63.00 68.00 67.00 30.00 25.00 71.50 30.00 30.00 95.00 Measuring Point(toc)[ft above land surface] ft 2.01 2.11 2.29 2.59 1.70 1.77 1.41 2.88 3.01 2.49 4.51 3.59 2.63 2.38 Well Diameter in 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Screen Top Ift below land surface] It 74.50 42.50 47.90 49.70 23.70 47.40 51.70 52.50 10.00 10.00 61.50 15.00 15.00 85.00 Screen Bottom [ft below land surface] ft 84.50 57.50 62.90 64.70 33.70 62.40 66.70 67.50 30.00 25.00 71.50 30.00 30.00 95.OD Relative Measuring Point Elevation - ft 2136.19 2169.35 2147.13 2140.98 2117.64 2123.16 2130.44 2121.54 2076.56 2068.31 2071.47 2074.01 2071.37 2059.15 pling Information and'Field Anal Sis,.,f.,,,,�.,., _ y -r CHECK IF DRY WELL AT TIME OF SAMPLING ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRV ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY 1SA-2L Units MW-1A ' MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-S-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-S-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sample Date 11/06/2014 11/06/2014 11/06/2014 11/06/2014 11/06/2014 11/06/2014 11/05/2014 11/05/2014 11/06/2014 11/07/2014 11/06/2014 11/07/2014 11/07/2014 NS'• Water Level[ft below measuring pt.](82546) ft 32.18 39.60 23.95 30.02 19.06 23.40 30.76 24.14 16.58 8.69 14.14 17.25 19.68 NS•• Volume of Water pumped/bailed gal 1.5 2.3 0.5 2.25 1.5 0.25 2.5 1.3 0.5 0.5 0.5 0.5 0.25 NS Temperature(00010) deg.C 16 16 15 15 14 14 15 15 16 14 15 14 12 NS•• Odor(0008S) None None None None None None None None None None None None None NS•• Appearance7 Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal NS"• Turbidity(82078) - NTU 39.9 68.7 4.071 42.5 8.98 8.06 9.31 8.13 4.11 2.61 4.29 2.66 1.14 NS*• Dissoved Oxygen(00300) - mg/L 4.5 5.9 7.0 7.2 2.0 6.5 6.5 5.5 3.4 0.6 4.4 2.2 5.5 NS** Oxidation Reduction Potential(00090) mV 245 251 266 241 232 277 277 261 331 299 282 269 345 N5** Specific Cond-field(00094) umhos/cm 59.2 45.4 28.31 18.3 55.6 29.2 21.8 33.1 57.4 125.2 67.9 45 24 NS" pH-field(00400) 6.5-8.5 SU 5.3 S.2 5.21 S.3 S.S 4.8 5.1 S.0 4.8 5.1 5.7 5.3 4.6 NS'• _'La oratory,ln ormation Laboratory Name Pace Analytical Services Certification# NC DENR#40 Samples for metals were collected unfiltered: (] Yes ❑ No Sample Analysis Date November 6-18,2014 1 and field acidified: 0 Yes ❑ No 1SA-2L Units MW-3A • MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-S-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-5-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sb-Antimony(01097) 1 ug/I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 NS•* As-Arsenic(01002) 30 ug/I <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 NS Ba-Barium(01007) 700 ug/I 28.5 49 5.2 23 12.1 8.4 6.1 10.8 27.5 97.1 22.5 26.3 40.9 NS"* B-Boron(01022) 700 ug/I <50 <50 <50 <50 <50 <50 <50 59.9 <50 <50 <50 <50 <50 NS** Cd-Cadmium(01027) 2 ug/I <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS** Cl-Chloride(00940) 250 mg/I <1 1.9 1.5 <1 1.6 <1 <1 1.8 9.9 4-.8 <1 1.5 1.3 NS•• Cr-Chromium(01034) 10 ug/I 60.1 30.4 <51 59.8 <5 <5 <5 <5 <5 <5 <5 <5 <5 NS** Cu-Copper(01042) 1 mg/1 <0.005 <0.005 <0.005 0.007 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 NS•* Fe-Iron(0304S) 300 ug/I 1300 2930 183 1900 753 211 144 202 64.6 245 207 166 76.5 NS'• Pb-Lead(01051) 15 ug/I <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 NS*• Mn-Manganese(010S5) so ug/I 107 204 81.3 144 225 60.8 8.4 70.8 19.1 53.7 5.3 <5 7.2 NS** Hg-Mercury(71900) 1 ug/I <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NS** Ni-Nickel(01067) 100 ug/I 34.7 17.2 <5 32.4 <5 <5 <5 <5 <5 <5 <51 <5 <5 NS** Nitrate(NO3)as N(00620) 30 mg/I 3.8 0.93 0.091 <0.021 0.099 0.63 <0.02 0.12 <M02 2 0.89 0.39 <0.02 NS Se-Selenium(01147) 20 ug/l <10 <10 <10 <101 <10 <10 <10 <10 <10 <10 <10 <10 <10 NS*" SO4-Sulfate(00945) 2s0 mg/I <2 2.1 2.3 <2 <2 <2 <2 <2 <2 19.4 <2 <2 <2 NS•• TI-Thallium(01059) 0.2 ug/I <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 NS•• TDS-Total Diss.Solids(70300) Soo mg/I 46 89 54 42 56 <25 <25 <25 29 71 48 31 <25 NS** Zn-Zinc(01092) 1 mg/I 0.021 0.015 <0.01 0.016 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 NS** Al-Aluminum(01105) --- ug/I NA NA NA NA NA NA NA NA NA NA NA NA NA NA ..___-__.. _,- ._,,,_.__„_,___...___..._..___.,._.._,.- _-__,..__.___..._..__._ Turbidity is field analyzed for Information use only. ;BOLD values equal c r exceed the corresponding 2L standard _ ,._......_._ Notes: !Icertifytha t6the best of my knowledge and belief,the iriformiatiomsubmitted in'this�report is true,accurate,and complete,and'rthat the laboratory analytical date was produde Using approved metridds of analysis by 6 DYVQ-certified laboratory. I�am aware that th6re are significant pen Ities,for submitting false information,including tl,� Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) Date GW-59CCR-Voluntary •-Denotes Shared Background Well for Areas III&IV (B)-Laboratory"B"flag NS**-MW-9 not accessable YIN W Hoitldng -yEAm} TnE7o;flan'I ` O} s r J M-1A Cilia-S: 94 90102 217.Q1B z A[fh 1 'axaaTa( seluma3 7r3. v , rx .Ai ! 2 Ce+Ba8 Y8 ^1] 21011 "^ v ' ,S ", '�1F " I 1.7 0.hl-3 USX4&Sa- -11337N 21W.83 � y a♦� �rx jb '' t °nH'..� I 1�'+ ^ t. '0.TV8 'C3ml.67 9a22327 21Z'16 1'. Off♦ .5 ♦ ( a L .Al;-T e�zz�a 9alsz�t .rr.y, s� `a�ii�!F� �+"� 44 `"a ^{.'. t '•,_�1 •I ",, r 09 68 r ro g ip ♦ y, c + ia 107 R r♦ � � ♦.11 1 a r QI *qP 1 ♦ ��� ( ♦�N��� � emu✓-�^�.a't� " I e , s p0 a:- .J ;�.'y c ♦ ��i'6+;'r�` AREA 3 COAL d w> �� ,� fi'# ��u 3,C.*s�p _ a ■ ry ) '- '^tq a 7` �� PRODUCT LtM1T5 !� �' '"`. �"P" f . �' - �� ♦"`� a ^.M -3 ;� { ro1 (APPROXIMA'f� 5 '& mL �` '+1 x .. ��s n! 1,♦ �' } .. t� � t a ter^•� ASHEVILLE =�� w lY ' :-''' \ ti, e w., ry �,I �. ♦ �u REGIONAL 2123.18♦ � AIRPORyTAIX ♦ k -21 a N w y r 1z' Al G"' ♦. vn s .. 47 4r:.i\\''� AS LEGEND a, -;-' 't-�0 MONITORING WELL(SAMPLED)D 2129.75 ♦ I . 2097.40 WATER LEVEL IN FEET(msl.) , ♦ Sl S MW--B MONITORING WELL(NOT SAMPLED) j1, w WATER LEVEL CONTOUR IN FEET(msl) 5FT CONTOUR INTERVAL) ) } •1 " ■wti wd COAL COMBUSTION PRODUCT LIMITS ♦ t ! a s REVIEW BOUNDARY COMPLIANCE BOUNDARY °a fir-�• 1� , ' --- PROPERTY LINE(APPROXIMATE) eI } '*VL%y SOURCES: ♦+y+ `" e 20MAERW.PHOTOGRAPH OBTAINED FROM NRCS GEOSPTIAL DATA GATEWAYAT:MW/dabFAteaaY.nr-, Sda.gov/ ALLWEl15SURYEYED EXCEPT MW3 BY WNCPAOFESSIDNAL ENGINEERS& SURVEYORS ON 4PRIL 19:2012. - °COMPLIANCE BOUNDARY.REVIEW BOUNDARY.AND UMRS OFCCBFILL BASED: 4 ON ORAWFNG BYFRAMMUNS.CRAIG.P.E.OF GCSTONIA NORTH CAROUNA TBIEDARA-ARFA3 ENGINEERED FILL DESIGN.SHEET3F3.DATED JANUARY. 13. 28,20 . .. .. .. GRAPHIC SCALE . .: 250 0 .250::.. 500 FIGURE 2.. :.. INFEET DUKE ENERGY PROGRESS 148 GREENERETSOUTHSUITEROLIN STRUCTURAL FILL-AREA 3 GREENVILLE;SOUTH CAROLINA 29601 PHONES 442t-9999 WATER LEVEL MAP NOVEMBER 2014 w wterracolv-con ASHEVILLE REGIONAL AIRPORT synTero ORAWNBY.NAGERHASTAW DAlEf2/M)/2114 FLETCHER,NORTH CAROLINA DRAWN BY.R OHN C NATAI KTBB IAYGUi:IVATER LEVELMIIP ' 1208 149:48 AM P\Ouire Ene .10 O2.A.�i11EVILLE IT.201a Nt515am An3a39n1atu21 FallDV.Sw91MIf.TMAL FHI3-WLMA0.201411. qw S F 1 - + r � tr r a: 't ��[e la�*`�'� r✓ �wm MW 2A y. + a'Yt��?SS, t 5, 4�y�C��'k �m�`t � � 'fl( t' `4. MW 1A # "� t% 'r = �� (2097 03 1� � �� E Y � 4 + xq t '� ,!E' �•4 'tr � !-.iT +� f ) l+f'4 'x'•f,,t, ` `y r t� ..i .• $ ,9�� `f t-.: t'f t ` A !C 'x` �et�, t . ���i7 !r e''.s !` �1\1 F '/..�! `sYur r.i ✓# t •E - 1 v ,{r-Uk rpm . r �o d . I•.: Y' r EM xi Ewe e271833 L1 t 1 kk ! r' a / \ •+ n •'�t 1° ._ \t' \rd\ j/ ///. - - .j 'y"r �1 :"+'� i ♦ pry; 3�. � s } � \\y\;\\`\ ! !Y� � ` i� a �� -S\ � "F r, s(f ' A r -rti tN...♦'�., .. !�.�, t `a" ."` 6 r \h \Z!\CC ,i! y� i •fi' r•'x a'I h-;�. I } Toyofcowni '�L�� r . �r r t +, IQl ID. .. Northing. �.. ElewOon- u M o1 s.w a zlm.aD MAJ . ;-:;`i �! _...�, 1 . 1 1 - \i\\� /i. t: =` 41 t}a`a � t,r ' x`€ ,s.t' LEGEND MW4A MONITORING WELL M1.' `,t J 2132.79 WATER ELEVATION INFEEijmsty. ,� '• F j \- \\\,�/ •. - ,ter _ WATER LEVEL CONTOUR IN FEET(msL) f ' 1 T ��• �' �. •' (2FT CON TOUR INTERVAL) ,'� ., \ ��t\♦ '/� _ "t'A c,� f t .......... COAL COMBUSTION PRODUCT LIMITS " p lr i Y y. REVIEW BOUNDARY A Y } `�'•,\. '� ♦ ; L ` t 2—� COMPLIANCE BOUNDARY PROPERTY LINE(APPROXIMATE) . 4MW-0A ., ^'y� .l w1 '� 60DACE8: `)i�T3f F',w 4>�,: p1iiLPALF@IpD@.vN hA50D(a:hFDfA(YA;GLMC$GFDSi41ULWryWMWAYAT iiil A. ;(( .!. k- �. 1 {K` nrDsvA.'•A/�va.ws aw.. WELL L=Mh&fru0WMT*%PACOLC5 LaMF VDCl:1MiA D x r -+ '� �. pmttw Lrern.TDun rAALHrTroa ssFetwAw:re TrilD•rsm�ncmnv'FLox TIUME f} .'} �' r - S \ ',.,i J. . ,1 N+PST.UCNaunu•.ntfm lDlE2410, DUKE ENERGY PROGRESS } S STRUCTURAL FILL-AREAI - T+fY'Mr4FA1 P WATER LEVEL MA NOVEMBER 5,2014 ASHEVILLE REGIONAL AIRPORT �, a 5yi'1 end ,9. "" ARDEN,NORTN CAROLINA LlciJ ID NertNnA EaArr9 ,E3e e.4n t T L� sak plv, 4qq+ �° " °,"k'{ •-$'"'F x ' !-1A Ciltt$2 3:'961 OZ 2t�.19 4YEE+ a` ka�f^•. - ,s;.. di-2 L52"51'.b` 9.3G1E 5D 953 -.. 1 J V yL'YL ."h"+s 6'tiY 5 M39,a9 St44t'+ a �1&4 31 w ..j a l ryT t18S ' rar-m C93mas. 9:cs Z5 aTT147 4 y'*`r 1 . S E 'A I d - ' ._ASHEV �E GION L RP RTI�, rar.T Bmaaw xtlB^ . ter a' °s ` '� 1T t t '1" q-�s is G �*'aT P G P2 amm 3�s5i..t2 80&401 >q ", t.1 i R$*• Y b Y Y '± l AT A �4, era+ Asa g� 'a + �. 4 5 g r ib Y � R 1 a - rr MW-f�4t8,1 ,i Q*a t '3 a..�;■"�'" snt�G£ o ' ��'iE'� c\ �, ,�" s � �- � : "�� ; tl .x ;� � 4-�� ,{� ■ "` +x�, FrNtt\H° ,`��"" `. Ilk a a �Iy'"� 7 ''3�+0q�," ��� I �''`� 6� 0 �♦ ,''a "., 4 c '.? k 45 '�, s e »P+ ,r 'A r�p �/ �: � � ♦ p a k� 'A�`r dY.,+ f i'_.i `� r� r i ?Q�s�y�``�"�C®,�f�,�:.'1A `"M�e` 'a�O9 ♦ s.'. Y.l"v .`° _ � r '� a♦ r�■k;d � y" $°y�4;W�cayv f„sue ,.ems` `,.���tk�,,,'�l-p 6 By�.� • g3N A tp� .,s COMBUSTIONL j� ♦ a 1, p°? 4 � ,.COM ` a 2059.98 0 r • s ♦ ":PRODUCT LIMITS SE i COAL ; r y ■ a APPROXIMATE J I ( 1 , # COMBUSTION PRODUCT �`, . A !�J ', .`�"�t•r ds �ss, ,r .:�,�. ,� �,. o i :iffi �:° ,^'"�,. ^" .',�"-•t� r—^` s r r x�e ° ♦, 11ibby a WESTERN NORTH CARdLINA 4• p>'t"`, °gyp' 2059 62 2057.33 ` ;q#" �?fit, ,1-s� AGRICULTURAL CENTER — f a. ,"'�"ENTR �'1"` !. O�'4 ♦ a ..k .tea°'i I y t 4 x ANCEwr,. t� ♦ ,� x S"' l �. v„ 1 F pk?r 2056 76 � sa►! ♦ �, ■ 'r ?O�n�' .' � y`S. ♦ 9�. �p,'.;'� 1:� � "• "�„ t*�t � .a x +, T - ,. .. �tao `$: „ ■ 1a 2 0 t5i 6!9 41 �, rr } ✓T°Xr 'y�,y. ,'"' ?a1��x �,SS. ♦« e 1 a' � .. .. , ■ � �� MW 8r�,�i�`•t r�t tt �T ;'/� S C#�`� 7 .%��, �M+a ru d •y. 'y `Ida � .YX A`�� � � �*� i�". � �: LEGEND ss x'• /s' 1 � 'R . IMW-7_1 MONITORING WELL(SAMPLED) z 2051.69 WATER LEVEL IN FEET(msi) s�O r F e MW-a MONITORING WELL(NOT SAMPLED) v1 x WATER LEVEL CONTOUR IN FEET(mSQ SOURCES (5FT CONTOUR INTERVAL 2012 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPIR DATA GATEWAY AT httpV/datagateway.nrc wdag p `§ e ASHEWLLE �, -I .COAL COMBUSTION PRODUCT LIMITS ALL WELLS SURVEYED FJ(CEPTMWd BY PROFESSION ENGINEERS& � � q REGIONAL SURVEYORS ONAPRIL19.2017 f AIRPORT e s■ REVIEW BOUNDARY l r , COMPLIANCE BOUNDARY,REVIEWS. R BOUNDARY,AST LIMITSNIA,N OTHCARGUMASED COMPLIANCE BOUNDARY ON DRAWING 4FULPHAS$.ENGINEEOFGLDESINNORMEA,DATE PROPERTY LINE APPROXIMATE TITLE AREA UNE302011 ALL PHASES ENGINEERED FILL DESIGN,SHEET E3,DATED GRAPHIC SCALE 300 0 300 600 DUKE ENERGY PROGRESS INFEST 1Ywwrsynterracorp.co 148 RIVER STREET,SURE 220 STRUCTURAL FILL-.AREA 4 GREENVILI-MOUTH CAROLINA 29601 WATER LEVEL MAP-NOVEMBER 2014 PHONES64-02 p:co m ASHEVILLE REGIONAL AIRPORT O Y:B HN C N Terra DRAWN HASTAIN DATE 12/09{2014. AR®EN, NORTH CAROLINA syn1 DROWN BY. AGE RAMY WEHB. LAYOUT-WATER LEVEL MAP 12/09!2014950 AM P:\pnkr Ene Rn ress102G102ASHEVALE PfANF\8214 Wei S..n lin Area 451ni mlFili-X''TRrICRINa FILL 4ML MAR2014-11d 7/18/2014 MSD-Industrial Self-Monitoring Report '4 Metropolitan sewerage District Industrial Self-Monitoring Report Industrial Waste Division �• ' - Phone:(828)225-8230 June 2014 r } Fax:(828)232-5546 Co.Name:Charah Inc_02 Permit#:G-0362 Day 4Flow gpm pH TSS Cd Cr Cu Pb Ni Ag Sn Zn CN Hg MEK ample md)01 0.025737 17.90 7.30 1 Grab 02 0.02781519.30 7.40 1 Grab 03 0.029181 20.30 7.40 Grab 04 0.029217 20.30 7.30 Grab 05 0.029186 20.30 7.30 Grab 06 0.028456 19.80 7.20 Grab 07 0.024676 17.10 7.20 Grab 08 0.024491 17.00 7.20 Grab 09 0.023889 16.60 7.20 Grab 10 0.024140 16.80 7.20<2.5 <0.001<0.005<0.005<0.005<0.005<0.001 0.028<0.010 0.060 0.000001 <0.0010 Comp 11 0.014728 10.20 7.20 Grab 12 0.015054 10.50 7.20 Grab 13 0.015941 11.10 7.20 1 Grab 14 0.018357 12.70 7.20 Grab 15 0.020583 14.30 7.10 Grab 16 0.006858 4.80 7.10 Grab 17 0.008784 6.10 7.10 1 Grab 18 0.0124318.60 17.10 1 Grab 19 0.019515 13.60 7.10 Grab 20 0.02018714.00 7.20 1 Grab 21 0.01806312.50 7.20 Grab 22 0.017893 12.40 7.20 Grab 23 0.019336 13.40 7.20 Grab 24 0.011313 7.90 7.10 Grab 25 0.01838412.80 7.10 1 Grab 26 0.016082 11.20 7.10 Grab 27 0.014632 10.20 7.10 Grab 28 0.014080 9.80 7.10 Grab 29 0.015531 10.80 7.10 Grab 30 0.028063 19.50 7.10 Grab Day Flow gpm pH TSS Cd Cr Cu Pb NI Ag Sn Zn CN Hg MEK Sample Type * All monitoring data and sampling frequencies meet permit requirements. All monitoring data and sampling frequencies DO NOT meet permit requirements. If the facilityis non-compliant,please commenton corrective actions being taken in respectto equipment,operation,maintenance,etc.,and a time table for improvements to be made. Ag = Beryllium 1 Sn = Selenium I CN = Arsenic I MEK = Barium Hg = LLMg in mg/L as required by permit. I certify under penalty of law that this tvbnthly Self-fvbnitoring Report and all attachments w ere prepared Comments: under ny direction or supervision in accordance w Ith a system designed to assure that quarrfied personnel property gather and evaluate the information submitted.Based on my inquiry of the person or persons w ho manage the system or those people directly responsible for gathering the information,the information submitted is,to the best of my know ledge and belief,true,accurate,and complete.I am aw are that there are significant penalities for submitting false information,including the possibility of fines and imprisonment for know ing violations. Name&Date:lNorman Divers, 7/18/2014i {;Digitally signed by Norman Divers Signature g DN:cn=Norman Divers,o=Charah,ou=E- -0- 1E,email=ndivers@charah.com,c=US Date:2014.07.1812:12:12-04'00' httpJ/www.rnsdbc.orgfiwr(ncMraste entry_module.php?month id=34&company_id=29&printable=1&editable=0 1/2 7/18/2014 MSD-Industrial Self-Monitoring Report Copyright©2012 Metropolitan Sewerage District.All Rights Reserved. httpJAmwv.msdbc.orgAwrfinc/waste_entry_module.php?month_id=34&company_id=29&printable=1&editable=0 2t2 8/7/2014 MSD-Industrial Self-Monitoring Report a A F yD Metropolitan Sewerage District Industrial Self-Monitoring Report Industrial Waste Division Phone:(828)225-8230 July 2014 c+ Fax:(828)232-5546 y fi� n 9 Y� Co.Name:Charah Inc_02 Permit#:G-0362 Day Flow gpm pH TSS Cd Cr Cu Pb Ni Ag Sn Zn CN Hg Ib1SK S,aammple 01 0.029303 20.35 7.10 1 1 Grab 02 0.028979 20.12 7.10 1 Grab 03 0.02864619.89 T10 Grab 04 0.02550017.717.10 Grab 05 0.023029 15.99 7.10 Grab 06 0.02579717.917.10 Grab 07 0.028740 19.96 7.10 1 Grab 08 0.028940 20.10 7.10 Grab 09 0.027672 19.22 7.10 Grab 10 0.025531 17.73 7.10<2.5 <0.001 <0.005<0.005<0.005<0.005<0.001 0.011<0.010 0.080 0.000001 0.0804 Comp 11 0.024241 16.83 7.10 Grab 12 0.023784 16.52 7.10 Grab 13 0.026295 18.26 7.10 Grab 14 0.028271 19.63 7.10 1 Grab 15 0.029170 20.26 7.10 Grab 16 0.028488 19.78 7.10 Grab 17 0.024651 17.12 7.10 6.7 <0.001 <0.005<0.005<0.005<0.005<0.001�0.042<0.010 0.111 0.000001 0.0680 Comp 18 0.023101 16.04 7.10 Grab 19 0.024098 16.73 7.00 Grab 20 0.024993 17.36 7.00 Grab 21 0.024947 17.32 7.10 1 Grab 22 0.024564 17.06 7.10 Grab 23 0.02571717.86 7.10 Grab 24 0.028507 19.80 7.10 Grab 25 0.025954 18.02 7.10 Grab 26 0.025952 18.02 7.10 Grab 27 0.026956 18.72 7.10 Grab 28 0.028061119.4917.101 1 1 Grab 29 0.02609218.12 7.00 1 rim Grab 30 0.024084116.7317.101 1 1 1 1 Grab 31 0.023901116.6017.101 1 1 1 Grab Day Flow gpm pH TSS Cd Cr Cu Pb Ni Ag Sn Zn CN Hg MEK Sample Type C�3 Al monitoring data and sampling frequencies meet permit requirements. 0 Al monitoring data and sampling frequencies DO NOT meet permit requirements. If the facilityis non-compliant,please comment on corrective actions being taken in respectto equipment,operation,maintenance,etc.,and a time table for improvements to be made. Ag= Beryllium i Sn = Selenium I CN = Arsenic i MEK = Barium Hg = Low Level Mercury in mg/L as required by permit 1, I certify under penalty of law that this Nbnthly Self-Monitoring Report and all attachments were prepared Comments: under my direction or supervision in accordance w Rh a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry of the person or persons who manage the system or those people directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant penalities for subrr tUng false information,including the possibility of fines and imprisonment for know ing violations. A Name&Date: lNorman Divers, 8/15/201 Signature httpJ/www.msdbc.orgAwrriincMraste entry_module.php?month id=35&company_id=29&printable=1&editable=0 1/2 BU12014 MSD-Industrial Self-Monitoring Report Copyright©2012 Metropolitan Sewerage District.All Rights Reserved. http://w m.msdbc.orgCwrfinc/waste entry_module.php?rrwnth id=35&company_id=29&printable=1&editable=0 212 9/18/2014 MSD-Industrial Self-Monitoring Repor6 Metropolitan sewerage District Industrial Self-Monitoring Report r# � Industrial Waste Division P Phone: (828)225-8230 August 2014 + Fax: (828)232-5546 Co.Name:Charah Inc_02 Permit#:G-0362 Day Flow gpm pH TSS Cd Cr Cu Pb Ni Ag Sn Zn ON Hg MEK Sam�plle 01 0.025108 17.44 7.10 Grab 02 0.025319 17.58 7.10 Grab 03 0.025114 17.44 7.10 Grab 04 0.025686 17.84 7.10 Grab 05 0.025918 18.00 7.10 Grab 06 0.026013 18.06 7.10 7.7 <0.001 <0.005<0.005<0.005<0.005<0.001 <0.010<0.010 0.136<0.000001 0.0876 Com 07 0.026054 18.09 7.10 1 1 Grab 08 0.024288 16.87 7.10 Grab 09 0.024518 17.03 7.10 Grab 10 0.023134 16.07 7.10 Grab 11 0.024382 16.93 7.10 Grab 12 0.027108 18.83 7.10 Grab 13 0.024877 17.28 7.10 Grab 14 0.023216 16.12 7.10 1 1 1 Grab 15 0.023377 16.23 7.10 Grab 16 0.023482 16.31 7.10 Grab 17 0.024297 16.87 7.10 Grab 18 0.026386 18.32 7.10 Grab 19 0.026663 18.52 7.10 Grab 20 0.023948 16.63 7.10 Grab 21 0.021592 14.99 7.10 1 Grab 22 0.023198 16.11 7.00 1 Grab 23 0.024890 17.28 7.00 Grab 24 0.023731 16.48 7.00 Grab 25 0.023729 16.48 7.00 Grab 26 0.023652 16.43 7.00<5.9 <0.001 <0.005<0.005<0.005<0.005<0.001 <0.010<0.010 0.079 0.000002 0.0777 Com 27 0.023605 16.39 7.00 Grab 28 0.023550116.3517.001 1 1 Grab 29 0.023500116.3217.001 1 Grab 30 0.023450 16.28 7.00 Grab 31 omwoT1602517.001 I Grab Day Flaw gpm pH TSS Cd Cr Cu Pb Ni Ag Sn Zn ON Mg MEK Sample Type All monitoring data and sampling frequencies meet permit requirements. 0 All monitoring data and sampling frequencies DO NOT meet permit requirements. If the facility is non-compliant,please comment on corrective actions being taken in respect to equipment,operation,maintenance,etc.,and a time table for improvements to be made. Ag = Beryllium I Sn = Selenium I CN = Arsenic I MEK = Barium Hg = Low Level Mercury in mg/L as required by permit I certify under penalty of law that this Monthly Self-Monitoring Report and all attachments were prepared under my Comments: direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry of the person or persons who manage the system,or those people directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete.I am aware that there are significant penalities for submitting false information,including the possibility of fines and imprisonment for knowing violations. Name&Date: I Norman Divers, 9/19/2014 Signature Copyright©2012 Metropolitan Sewerage District.All Rights Reserved. http://www.msdbc.org/iwr/inc/waste_entry_module.php?month_id=36&company_id=29&printable=1&editable=0 1/1 i011622014 MSD-IndustriaiSet oniiioring.Repor Metropolitan SewerageDishict Industr-ia'l,Self-l►tlC7?A"'n- Report Industrial Waste Division s ', Phanpi (see)225ez Q Septiemher2014 ,(828)232-5546 Co Name;'Charah hr c_152 ParmR tt;.�-�i+3fa Day F low, (rrigd) gprn pal TSS: Cd Cr Cu P13 tli Ag Sri 2n CH JIg MEK 'Type Ie' 61 .01=2409 J62 _00 Grab .021857 5:18 10 Grab 03 :023128 6JO6 AID Grab 04 .021265 4.77 _00 Grab 05 J.021275 4.77 _10 Grab 06 .022919 5.92 AO Grab 07 :033979 .60 .80 Grab D8 A33568 ,31 ".70 Grab 09 .0220231530 90 Grab 10' .0221 ST ISAI .10 Grab 11 .023369 6.23 .10 Grab 12 .022584 5.68 .10 Grab 13, .020873 4.50 .10 Graft 14. TI5887 11.03 .10 Grab 15 .019825 13.77 .90 Grab 16 :0 25962 18.03 _90 Grab 17 .028098 1951 _00 g2.5 0.001 <0J005 0.G05 .005 0.022 0:001 A10 .013 . .011 JD1J4002 .0838 Com 18 .023918 16.61 .00 Grab 19 .020783 4.43 .00 Grab 20 .020507 424 TM Grab 21 .023547 635 7.00 Grab 22 .023196 6.11 00 Grab 23 :019899 13.82 100 .6" gO.001 OJD05 0.005 0D5 0.005 0.001 .DZ9 D.010 .068 GJOD0301 .0708 Com 24 .021038' 4.61 7.00 Grab 25 :023240 1614 .00 Grab 26 .024003 6-67 :00 Grab 27 .023800 6.53 .10 Grab 28 J.023995 16S66 .10 Grab 29 .025624 17.79 .10 Grab 30 .025460 17.68 .00 Grab D-ay, Flow ggrri p0 TSS Cd Cr Cu Pb Ni Ag Sn ?n CM Hg MEK Sarnple Type 0 AJ 1 m onitoririg data and'sa m piing freWer)des m e et pe m d reguirem tints. A I m onitoreng dafta and sampling freapsencies DO MPT meet perm it requiremerds., ifthefaoilrcyisnorit¢aipliant,pleasecorrLrrianoncameuroveaixiorisbedtakenirirespecttiex;ulgtr i taperatlan,'mairetenarace,etc.,andatime�hrztarirrpro5ementsto be made. Cg = Ser ylliuo I Sn Selenium j CK =Arsenic i MEK = Barium rg= l I F in WL as required Llg perait. ICe r[Ilf x i de r pe rarV W M b atti 19 UOk U IjJ eU-Mlk 40riig Re pd It"aid 393ttdx:9 iti We re p k pa red II,C FMV Comments die c1k,'i or,t rpe mirbi h`aaurdai Ce rilil'a sgst desigied,b ass r re tlatgsatm persoi i e I p ropz rifga3e rand t7Lan of a tie iniomiama stlim m d.lased o�my OQi rSgr6t ti e•"pe 60 Y or peraors 176 maiage tie.Syalm.axU Se people drectlrresporsbe93"rgatlerlig tie lI, .7,rr.'A*lrAmalknarb Md19,m tie MCI orMyYiaxrk Bid be Ilel,to e.axi Kati.aid tom pie le.I'an ZVJM Here are s yi Mar tperaMs Liar tm lMk g Talre 1r9)1matbr,lie kdSagfifepw4bllbrof%esandtapitwimerttrkioviIg'LE s_, tame Date: �rman Divers, .l0 20�2014 SI riatUl'B 1 L3lblyHgwl6yrxamnda g [atm�+mun Cerar,ce�Zash.w_eE�, r'fi"' ;rair..i=r.3wr*�drolr3hcccgd¢� ,' a��ion is=oo�n-rem tapygrL 7 2Dit kcUm�ul:Len.S:h+:mje t>itircL3�1 Rgnis(Y_x±xQ." fifip;Jit�urwti+.msdbc.or nUrac{uaste:_entrp_madale_php7month_€tl=378corr,panyjd=298tirirrtalle=1&editatile=O 1J1 1UM2014 MSD-Irdustrid Self-Ma iior'ing Resort Metropolitan Sewerage District itidustr-ia1.Se1f7Monit6rih0 Report Industrial Waste Division Phone:•(828)225-3230 October2014 Fax: (828)232-54b '�e:a •' C...Narner,Oiarah dnc 02 Pwn it#-. G-0362 Day CFm9i iciim gprn pH TSS Cd Cr Cu Pia Ili Ag Sn 2n CH Hg &E.K Vale 01 .024f2716.75 _DO Grab 02 .0 21 396 14.86 .00 Grab 03, .02316716.09 .DO Grab 04 .02752919.12 _DD Grab 05. ].0252GS 7.51 .00 Grab 06 .023778 6.51 _00 Grab 07 .023003 15,97 .00 Grab 02 ].02287715.89 .00 Grab 09., ].021478 4.92 .00 Grab 10 .022952 15.94 _00 Grab 11. ].023813 6S4 A0 Grab 12 ].02233115.51 _00 Grab 13 .021821 5.15 _00 Grab 14 .024631 7.10 .00 -Grab 15 .022372 5.54 .00 Grab 16 .022972 15,95 .00 Grab 17 .020833 4.47 00 Grab 18 .021539 4.96 _00 Grab 19 .017558 12.19 .00 Grab 20 .018108 12.58 .00 Grab 21 ].020353 14.13 .00 2'.5 0.001 0.005 0.005 OA05 0.005 0.001 OJ010 0.01D .059 M0005 .0769 Como 22 .018395 2.77 .00 - Grab 23 .018439 2.,80 .00 Grab 24 ].019047 323 .DO Grab 25 ].019640 3.64 .00 Grab 26 .020515 1425 .00 Grab 27 .018874 3.11 DO Grab 28 ].017914 2.44 .00 4.2 0.041 0.005<0.005 0.005 0.005 0.001 O.010 eWD10 J.066 .000D02 .0798 C.om 29 .019563 13.S9 .00 Grab 30 .019936 3.84 .00 Grab 31 .02222005.43VF-001 Grab Day Flow gptn pH TSS Cd Cr Cu Pb Hi Ag Sri Fn CH Hg ME STypeample @4'AJI monitoring data and sampling frequencies meet permit requirements. ID All monitoring data and sampling frequencies DO NOT meet perm.it requiremerd& Ifthe boilityisnon-ownpliarit,please"nunentom corrective"acdo6sbeirrgtal%n in r+espedVa egaiprrent,operation,rnain5±nance,Etc:,and a timetable brirrprowmentsm be made. €g = Beryllium I sn selenium I OR _Arsenic_ i MEK = Barium 1 = r.LV iri W/L as required by permit. Icertlf Ride rpeia[yo7bauxlattlBIAoiiiijeF-uo%a hg,ReFortald'ar[aC�rspearuerepceparedtWeray Comments_ dtemi oratE-imtiin hawordaice•rrn aofato desyredtoavar re tiatgzMdpenoti`elprope.rVgatteraid euaimv tie IArmami atbm tea,Batedo i mphqup of tie pe raoi orpersota®ib maIa_*tie WVM,orticxe peopb drect¢reipo2zb&tor[ptierligtie'lifomiattn,tie LiomiaiA sIbmt@d I,btie bestoYmyKkc led aid be Iiat trie,aca gam,au3 complete.]am awaietkattie re are ai7iMmitpeiamz:brattrn Illfi Braise lif0rrllaW1,1tGridhg13ep .b19f0f111esaidtsp1tanme1t1orki0rr1kgu10ratdu. Name.&Date:jx5rran ivers, r7 RC1Y�gAd6YNxrmthtxxas Signature � �" ,,",.E.aasl�dt•as•9d�aaF:cm1c�15 ���""+//' ,"Oalai2014.17,T?6R423�{50m Lawy-yK a ZUZ1H1e1wrafta-5ewa#nge Vet.:cL All Rgriz Res_red., WAwvnr.msdbr-.crg fireluva,-te_errtry_modrle,php?morth ici=388cmip ry_id=29&priniab1e=1&editaUe=O 1A 12115MI4 MSD-lr&rstrial Self-M oniton rg Report t Metropolitan Sewera a Distri€t p � Industr-ia[ Self.-I+lonitorirlg Report Industrial Waste Division. .1 Phone; ($28)225-8230 �i November 2014 Fax: (828)232-554 Co.Name: Charah Inc 02 Perm it#. G-O'1a62 Bay low gprri pH TSS Cal Cr Cu Pb M Ag Sn Zn CH Hg hEK Sample Type 01 .023103 6.04 .10 1 Grab 02 .01637811_37 A 0 Grab 03. 7.014998 0.42 .1ID Grab 04 .01742-1 12.10 .10 Grab 05 7.018276 12.69 .00 Grab 06 .023155 16JD9 .00 Grab 07 .021749 5.10 .10 Grab 08 7.020858 4.48 .10 Grab 09 J.020831 4.47 10 Grab 10 .019187 3.32 .10 Grrab 11. 7.019411 3.48 _10 Grab 12 ].019411 3.48. .10 Grab 13 .019038 322 .10 Grab 14 .017984 12.49 .10 Grab 1� .015694 10.90 .10 Grab 16 .018001 12.50 .10 Grab 17 .024882 728 .170 Grab 18 .019887 3.M .10 Grab 19 .01,6599 11 ri .10 Grab 20 .019124 3.28 .10 Grab 21 ].015702 10.90 .10 A ,0.001 : 0.005,0.005 0.005 0A05 A'.001 -DA10 0.010 .061 .000002 .0716 Cvm 22 015228 i0.58 .10 Grab 23 A2026514 07 .10 Grab 24 .026148 8.16 .10 Grab 25• .032030 24 .10 10.1 ,0.001 0.005 0.005 0.005 0.1005 0.001 J.013 40.0100.072 .0000 .0787 Comp 26 .019968 3.87 .10 Grab 27 .018834 13.08 20 Grab 28 J.015714 10.91 =10 Grab 29 .017403 2iM 20 Grab 30 .016898 1.73 20 Grab Day Flow gpm pH TSS Cd Cr Cu Pb Hj Ag Sn Zn C11 Hg MEK Sample Type 1] 'all monitoring data and sampling Ireauendes"meet permk.reiMrements, A]monitoring data and sampling lYequendes DO NOT meet permit requirem erds. Ifthe.facilltV is noncompliant,ple ase cormtertt on co rrectiiie actions Ding token in re sp ecttd egtdpment,o peratio n,rrokmff ance,etc.,and a time tale br impro•wmeritsta be made. Cg = s rylIium I sn= Selenium I CH = Arsenic I t9EK =Barium M = LLHg in 691L as required by permit loan'frtderpetaivo7twtrattllslaoiukesar-uoi6r3tg.He Pei rtarq'a¢attwaei-zwereprepa red rtderap Comments: orecrur;orsipe rutm baceordaice rim a ufatm desyredto xsr re tiatq'92MdpeNON i'elplope rvgattelaid emitat tie Abmia.Mi sibmLtd.Based ONmybrittireTue peuok orpersotsotumaiage tie systm,ornme peopp dtecttr respoisbb lei gate erbg tie Itfdmiatbi,tie womiatut siem and t,b tie bestoimVktora Qd3e aid belleY,trre,aoaiat,aid complete.lam awaQ tiatTere are snrrMartpetaMfbrartrn Imr9 t31se 1tYorm atbr,b didbg Be possb 1ty oYnr es a td'In piEwmei to r A rora bg u b atbts. Narne:8 Date- zman ;vans:, u .3 3 by Ntaosn 6ta3 S igrlature i�� ,u,:m�«n,�n�.•��ah6��, "Q,��nuru.t¢tssray.�w Carxp-gM @ Mi Met-agnMa-5ewa,age M31-;:t_All rignrs R2 ,vad, t> fYw�vrf.msdk�c.art r7irr lrs+ �te_endry_yiodlephp?month id=3Mcompany id=29RFrirdable=I,&edtable=0 1A MOM -lndc�alrld SNP�dcalhodll�Report NdhWeibin Mmw■pa VMrkk Industrial Self Monitoring Report InductrfalWadaD7vblan .1 Phan■:(M)225-SM. .June 2614 w g Fam Z82r554� G.O.O.Fila( �hrr8�h gf G Permit#.G-03 DW 9lm pH TES Od Cy Cu Pb N1 PQ En 2ae G;N HS UEK 01 .80 UUM I I Gab 02 11 ho 1 q�3 04 as t GMb 09 A0 Hamm I I Gmb as GMb a� 09 0A321Z8 t GMb 10 SA Ml 40M 0.M2 OL147Como 17 5 < 12 13 M GMb 14 M a I GMb 15 1 .00GMb iB 7 17 .10 G ffib 1H B M GMb 19 Grab 20 21 22 DJ03B1 50 A1g GMb 23 1 1 GMb 24 25 AD 28 8 .001 LMMICOAN:L<DDDS-gDMaASgMO31DLi4lOLLWDMDM A 27 1 1 1 1 tmb 213 0J08h31 a40 29 30 1 emb Al uni dda wW aempltig fragwmi+a mad parrn0 rligllll+wnwt. GAM mpd►7 ft daft end earnpikV fregcpr in IDO,NOT m*t pwmit WF*wrada. �wfidllgrk norrcamplsrL p1•asa comrrt�atan marracl�acibns br3np>.bwn In!wP�fo�palAm�rik op�nfon cntlrrinrarw�,,�bF,and afm t�bl�tar knprapsrn�nY b bibunA. g- pexyllivm I'lm- 9eienitu E CH-Araanim - Farina Qg— Ling in mg/L as rtniirsd Tay paaait., rcrr�iry rwww+iar.on�cw s arr�tarlprcrea�au�a serww.n.ar.vr«s Cammerib: u�r y sro�,or Ytn n roeordt>it•x fa r sJairre 6rY�wd fo rr�rss�t gnlirw P��Pub p��rd�ttw�irtfam�naobifbd�on�r�rer�.p.ea�Q v+rsae wh*ff&MP tr _M a N.w wQo1r rws+awbb far sl >tx tta rrCbn.fir. !t<,a®aon MfntEud Y,�1A�o7aitLf ny Y►xrYdp�tl iris(.trr��oolrnl4�tl ear�trl�Iar11. �a96�ifl�ern p�'is hRruts�giic�i�rn� dpe•��J d NEW&Daft; Orman Divers, 7j 21�201 atmett�m.ms�hril.eumL t•mus(zdt.s@#mh,aw.cin. .,�2J'Gf►1H 1'aSD14fOC' . nrJ�iel�enlry mrxlthr�rlhJd-94doar>pa�Jd�lB�trtd?[�18�edtehie�0 1� BI+RZi?i4 A -JMAMMd 504hdWrlo RWod + .� oifan sue.oft Industilil Self 1►0"nitdring ko&t.. Indu6t'rbl Waa#a[3hrkioh � 4 lb i4 f&z(828)-281,5516 `r 4r C&Iiamz CINra11MILM Parriilt#."303 My ppm pH TSS Cd Cr Cu Fb R@ Ag En 2e, GN Ila El 11K 07 1 Gtab 02 7 iab 04 1 7dt Gwb 05 7.5473D Gmb 08 Grab 07 Q8 T OB 1 8 Grab iQ 0lQ8BQ� 907A845.0 AN 40.01M 4MM 40.001 1l.02 al7 ANC 11 12 AD 18 4 Grab 14 QM1 87 Grab f0 17 1.6$ A .Q01 cMW 0MI a 9 0MMWWW .1 i8 ? Grab -79 F Grab 26 6 21 22 Glub 23 0A93B1 7� (dab 24 7 IEQ 28 26 921 42 ?Bd Gmb 27 1 Gn;b 29 1tA941 7� 29 30 1 18. 130 C3�b M ja C�r� U M maritb"dad end awp1hp ffoq uml6s mod permit MqiMMra L PJ mcNbrttlg dda and aOmpOrg Awmnctss DO NOT mad pwmft IaqL*mwtL V#w1l#ci1ly4 nancon4illoK P%pw 4�mn*ng4e vwred*oxftr F buku f9i*n In Mop Mtb*wlamwIL gpervom erelrkrrar", e2t1 w fte title#kT lFvMmsrft IP bomada.. 8nryllim 1 $n- Selenium I CH Arsenic- 1 !� Barium E* Leval?rAmmczry 34:mq/L na raigaired 1sy.'permi! pS rt&<q'oa'.,7f21114 szeraid6G ]9 "it Liat— 83 rsedicg. it dui:tea a malfunction of OR"i twat ras xstia ked an aaanr' tes9yrid�pe�raft�f�t@iibr�r��.11vo�l7Hepgfadd�tl�ii�epeepted �00'Ifl'I�Il�K: tamrw-M11Of10fWRY F.1lIt4i0fd�lo�1!<i�t plldMlRMdiDM6Us1<it4MfM� IA'�'Q�11'prlaroelaYainirUlainl'm>'lattue IWa4�M1I>I� cr[tipano?gr. pe�me+rlo rnrspiba�wtfa�peopr d+d!eeepa��iQ fr H�tetlfmn.fta t[faMrl MWAM MM,IsffiatxdiafoVMnarhcjaadb",bv%amraftamas gift I= r+r:seft9nrw an sl�fsa�tparilrs for auers�t[att lirorna�tna�pt4apasrEatStaP �rdLprYoR�iis ims>npv�a r NOMA1)po! D7arman Divers; :875 201. •`p EVt* byNomnn13ms ;ac�EEamY�3wa9diar*m7t ::,v` []OrY20ti�7S 7&2259-0SCO Itcde�k u9#"iarlhl ' #wl6 dw o -0 112 Sf Islit014 USD-)ndumW SaMml ing Repo Nedrop6nm sawimmpa olowct Diduaria[ Self-Mon,it6rin$Report Industrial iEbsbc Oivlslon My gm �"'_f PBnit1E�:C�G3 pH M Cd Ce -Cu Pb IS- ?A CM HOC D! .M 2473 30 Grab Dar .0m9s so Grob 03. X381 84 Grab 0I5 1 .70 Grob 05 .053137 .70 7 .001 OMS d0j=*rD .DD3 40M 40.010 .070 aBDO D2 0.1070 Om 07 .am= 1s M Grab 1* .04sm AQ Grab 10 .DS6=39.t# AO Grab i 7 A0 Gmb 12- .080M41.94 A0 Gmb 73 .0T .8QGmb 1d .p77 $ .8q Grab 15 .0mm .90 Grob 1s .043444 17 .TO Grob 17 .031014 € .T0 Grab 19 .040M .70 fln� 30 Mull .70 Gr®b 21, .0a4M 80 Grab 22 M47 7.1Q .50 . 23 24 .01947413� .B0 Grab 25 . .7D .80 Grob 28, D3831 .t10 .1 .001 � i mS .0 = .33d 4 .101 .118D Cain 27 .0223T0 m Crab 8 .023D84 s 84 .50 Grab 29 .019887 3 A0 Grob 30. .000040 71 .50 Grab 31 .009Y91 80 pH TW Cd Cr Ou Pb N AM En a CN ma mmEK, tea Al mmft t�daft end aaiin km fsaquendaa meet pam ltiaqukmnmta NI mar�Kming dam end mmO1nU f*'mndea 0.NOT moat pernit r9WkanmntL fthrfiol�rhnmaaetlNl�rdPE oona�rt�oerta�r�oKottsb�Gapealrnk�niP+ollor wnL :atm.mid aifrlds6[arknpmnn alm be mrpo% As - Baryillem I sn- Sala L= i CH-Armnic i MK -Barn- Ng ■ Law LWAd lrarcury in tip[. at-rmpdrad pormit IiMtYlalMfWn�4'diairlMtiYi�Mi�pt&�is�O1fOR�VuIaMa��11t1�MSRMrrrlelim[� �iGPnmEnl� drywaQevii®ki dodo tD i tfrqvndPm-mdFWffty ftW-d eat Nei > '9•���k:�iyr�lr�:��p.��aai�fhr�Q� w000 dW*rO9mmMrow aaama ei.irarr or�a�.raamrar n.0 a i a rrer� �. 1zr�GYU,i�u4ardbcvnplM�1 wxr��ttnw w�1nMuriEpw�rfaa�Wtfrq t� 1e�lart�Alm,kKi�q�a�l�Y d�a sid�tihrkainpvfd�as I1laliif!dtQRI6= Fbr an I?i.vers, 9f1912014 asmr-o�,... P�4?r.•��( Ftltpal�ww ncAwasb_d��stodub-PhP4rt "Q86avamperty.}d�1&peir�bie�7d�edHieb[a�+D 7!1 I On 612014' M SO-Industrial Sett-Monrtonn'g R epor ► a McEropoli#anetverage District Industrial Self.-honitoririg Report r' r Industrial Waste Division . . M.nei.(sea)225-82311 September 2014 S5g F..: (t2a)232-5546 y r !tc hlame: diarah Inc_U3 PR:rink u;G-r Day (FFn.gd)low gpm pH TSS Cd Cr Cu Pb Hi Ag Sn Zn CH Hg FAEK Sample bi .000000 .00 _30 Grab 02 .033925 .56 .30 Grab 03 .031017 54 .50 Grab 04 .033928 _56 _50 Grab 05 7.035865 s4-92 50 Grab 06 .017483 2.14 30 Grab 6� .031935 .18 _20 Grab 08 .071070 .35 .50 Grab 09 ].077235 .64 .60 Grab 10• .068323 7.45 .30 Grab 11: .089373 -06 _40 Grab 12 .077585 .88 .30 Grab 13 .075819 J65 .40 Grab 14 .056939 .54 .60 Grab 15 ].059715 1.47 .60 Grab 16 .055889 .81 .404.1 0.001 0.005 0.005 -0.005 0.005 0:001 546 _011 .097 .000002 .1560 Comp 17 :048079 _39 .60 Grab 18 :049486 .37 .60 Grab 19, -046740 .46 .70 Grab 20 .041347 .71 .60 Grab 21 7.024024 6J68 .40 Grab 22 .032442 .53 .80 Grab 23 .000529 .37 .50 -.1 :0.001 0.005 0.005 .005 0.005 0.001 _506 0.010 .088 .000002 _1300 Comp 24 .000000 .00 _60 Grab 25 .000000 .00 .40 Grab 26 .000000 _00 .30 Grab 27 .000000 AD _30 Grab 28 J.000000 .00 70 Grab 29 .000000 _00 .50 Grab 30 .000000 A0 30 1 1 1 Grab Day. Flow gpm pH TSS Cd Cr Cu Pb Ri Ag Sn Zn CH Hg MEK Sample Type 0 Alm onitoring dda and,sampling frequencies.meet permit requirem erns. PJI'monitoring data and,sampling frequencies DO NOT meetpermit.reguiremeits. Ifthefacilityi nan-cmrpliaht,please comriekonoorreadveacsionsbei atakeninrespecttoequipment.operation,neintumice.etc.,and atfrne table 9orirrproverrientsm be made. r€ Be'ryllium I sa= selenium I CH = Arsenic I r9EK = Barium lig = LLHg in cg/L as required by permit lcennfiider iaaro7brrtiattYKlAoitikseG�rataeeitig,Rep7rcaitlaltattac3�eitxierepk�redrlder®q CommentS- d1F croo i o r s ipe utxbi 6 accoNai ce arti a ayxtz�desy ted b ass i re tiatgta&W person i e I p n-pg rkr ga1S a raad e uali ate I tke iiYomiami zabm m d.Rased o u ny bqi uvottl a Pe¢o i or persois ulo manage tie evn2m.grtaaae people d1e09jtespoiab&Argarierliq tie lifomozMe.the ht inab-Do ii6mlt8d trjotie bestoimykicoaeO aid [an aaeatnaftbere are syiMcaitpeaa sfiirxibrnImigtalse b i)rm atbi,lic kMg ate prima b lik oY tli es aid iapEboame it b r K ioW Y g u bt cans. Name&Date:I Plorman.Diversi 10-20-2014 signature , °cgayba3p°"'N0f"°n g L7EaxikmnnL7rar:i�'ar3�au�E, . mtc�aaio5ca,�sa-arav capyign}J 2Biz meuapal;on$--Ynvagc MwkLAE Rynls rd-x-vad.. hRp:fi�v va.msdbc.orghmAnclvvde,.entry mocUe.php?month fd= 7&aornpa6y_id=31"table=l&,editable7-0 1!1 11t17dd714 a1SD-lndustriN Sdf,-Moriitoring Report "o sea Pletropolitan Sewer ageDistrict IndL'st-iaf Se1f7MOnit6rih0Deport Industrial Waste Division r• Phonei (828)225-8230 October 20i4 ^yj jt Far;, (828)232 S34b ' Co.Marne: Charah Inc Q3 Permit#: C,-D363 Day mod) gprn pH TSS Cd Cr Cu Pb Ili Ag Sn Zii CH Hg MEK STD e 01 .000000 _00 730 Grab 02 .000000 .00 7.20 Grab 03 .000000 .00 7.70 Grab 04 .000000 .00 7.10 Grab 05 J.000000 _00 _10 Grab 06 .000000 _00 T.90 Grab 07 .021791 S +D .40 Grab 08 .030190 .97 .10 Grab 09 .021321 4.89 .10 Grab 1& .047575 04 00 Grab 11. .015029 0.44 _10 Grab 12, .003043 _11 .20 Grab. 13 .068782 7.77 .130 Grab: 14 .099714 25 .10 Grab 1 _10026-1 _64 .80 Grab 16 .095313 A _70 Grab 17 .093479 .92 _80 Grab 18 .089781 .35'SO Grab 19. .085448 .347.10 Grab 20 .082904 .577.20 Grab 21 .026591 8.47 TAO 2.7 0.001 OA05 0.005 0.005 0.005 0'.001 .06 {0.010 :012 .000001 .0203 Comp 22 7.023777 6.51 .60 Grab 23 .016360 1.3±6 .90 Grab: 24 .010144 .04 .70 Grab 25• J.000613 .43 .00 Graf 26 .000569 .40 .70 -Grab 27 .002682 1.86 JO0 Grab 28 J.001451 .01 .10 Grab 29 .001427 _99 .10 Grab 30 .017488 2.14 .50 Grab 31 .045716 .75 .50. 3.5 '0.001 OA05,0.005 0.005 0.005 0.001 10.789TJ3.012 10.172 JO.000001 -089 71 Comp Day Flaw gpm pl-1 US Cd Cr Cu Pb Hi Ag Sn Zn CH Hg VEK Sarnple Type 0*Al monitoring data and sampling freglaencies meet permit,requirements. ;,411 monitoring deteand sampling teaiuericies DO NOT met permit requiremerds. Ifthe boilityis non-compl iant,ple ase cammert on co rtective actions being to ke n in re sr ectto egtdpment,o peratio 6.rrairrienance,etc:,and a time table ibr improvements to be made. Ag = Beryllium I sn = selenium I Ch --'Arsenic i dent = Barium t?g= CLlig in mgrL as required by pert. isertofrr(jzrpeiatfwuutiattii5witik,%I-mibr3rgPOOrtalG'allattki®e bit vie reprepa red tide ray Comments: dtecwr ornperutin haoeorda)CA 9Jlll a pirkra deal4yedto asarre tiatgtandperaoi ieip rope rygatielaid euauale tie persoi orpersonaVhomalade tie sysiem,artiose peop e d to cqr re'spooatrk for gati a rlig tie lgomeaan,tie"liTo.n atw s ibm tkd k.b tie be stoimy ki ow Nge aid belief,trie,aeca said Complex.lam aware tiattlen are agi himitpeiamsbrsitm Itllig 1alce hTormabot,Itdidhg ne posabik oTflies aid iDPtMmei t'dr k ioa lig ubtrtbra_ Name.&Date: Norman Divers 1IAW014. Si nature res�dinurron❑wcs g � ;.at�sa+urrono,urxc a,u�ha� ,:�'�r.�t-rsw.r_a,aurricar�cus ���fff'��� -: ❑sm=aman i Qa+aan>�ar terYlgm©ZUZHeL�rncten rerx-ege Dst-cL All RgnLs It r bcfl., Nw.msdk�c.arg�4ai�linch ^te_erhry modrlehla.rmorth id=388,00mpary 1i1 12115M14 M SO-l ndir,tri t:l;Self M or itoring Report MetropolitanSewerageDiktict Industrial Self7MonitoringReport 5 Industrial Waste'Dl�ision Ph one.; 225-8230 November,2014 f' Fas: (828)232-5545 Co.Narne:•dharah Inc 03 Perm it u• G-0363, Day (F��} gprri pH TSS Cd Cr Cu Pb f4i Ag Sn Zn CH Hg N Ef; Sample Type 49 .073165 .81 _10 Grab 02 .036275 19 AD Grab 03 .021353 5.18 M Grab 04 .003041 .11 AD Grab 05 J.004213 _93 .10 Grab 06 .000081 _06 .20 Grab 07 .000000 .00 .30 Grab. 06 .000000 _00 .30 Grab 09 .000000 .00 30 Grab 10 .000000 _00 AD Grab 11 .000000 .00 _40 Grab 12, .037828 27 _30 Grab 13 .090468 83 .10 Grab 14 .099191 _88 30 Grab 15 .096554 .05 AD Grab 16 .091136 .29 .40 Grab 17 .101933 .79 .20 Grab 18 J 06785 $_16 .30 Grab 19, .082610 37 .30 •Grab 20 .082742 _46 .20 Grab 21 J.087891 _04 .20 5.0 0.001 4.005 0.005-4GM5 40.005 i�0'.001 3.434 eO.010 D.100 0.000002 1.0944 Com 22 .088973 .79 _20 Grab 23 .082136 A3 .70 Grab 24 .081931 .90 .90 Grab: 25• .083705 .13 .90 5.0 0.001 0.005 0.005 0.005 0.005 0.001 3257 eO.01OR 073 .000002 _1040 Corn 26 .084030 .35 .90 Grab 27 .084873" .94 -90 - Grab 28 J.083767 .17 .00 Grab 29 .080519 .92 _10 Grab 30 .076464 _10 _10 Grab Day. Flow gprrr pH TSS Cd Cr Cu Pb Ni Ag Sn Zn CH Hn r&,=K Sample Type 0 P11 moniforing data and sampling ttequerfdes`me-et peraig,re"rements, 0 Al moniforittg data and sampling frequenrdes DO NOT meet permit requirements. Ifthe facility"ss noncompliant,please courrnant on or rrective actions being to ken i h re sp ectm egrgpment,o peratio n,rraisenance,etc.,and a time table br improvements to be made. Cg = Beryllium I Sn= selenium I Qt = Arsenic i MK Barium t = LLHg in rC/L as required by permit IcertlfnderpeiakotHratiattilttlo'inkrser-witarrLg.RepogakIaalrai:ticaoeiiwerepreparekltrdercay Comments dtoC.Wiaratp. nrMtiaceard iceVmadgS4Geesyredtoartiretiatgca€T@mpeuo�ieIprcperygatteiaW euauat lie hf amatoisebm[td,Batetiokmyo41-tpoTtia pertoi or ' motso6omaLade tie ajratirt,005oae peopt•dtecgrreapomabkforgatierlig tie ItToaaattas,tlehfomiatlrot1timtsdt,btie eIttofmYktowQd aid bellat,trre,aomiat.aid complete.Iam araale t attien are thii6s1tpeiaM5brsr1)m Imig vise bfirm atlas;Ii clydbg Fie port b IDf aYTIr et a ttl mptnwme i tYa r k rbu Ug u 6 6tD�. Narne&Date_ �=, 12/16/2014 SIg nat4e f a�sis�a>�bY ti rtnnIX�srs -R�aaNamnoirorJ w2art►orF6- . E "oid,a:.s �� j RY&2a1312.1616:53:11-06gP capyiym p 26I2191dwp3Cyn Sewerage Ph4ct_linRynLs Roelerd., f ltvw�tstmsdbc.agJ5asfincl te_�rtry modrlephp?morth id= mpc�ny_id=a'1£tEcir bie=1& dtabl�0 11i DUKE h. '' ' Duke Energy Progress ASVL PLT 1 200 CP&L Dr ENERGY® Arden, NC 28704 PROGRESS Certified Mail: 7011 1570 0003 3848 3991 File Pt.: 12620-Q June 24,2014 Mr.G.Landon Davidson ' NCDENR/DWQ Aquifer Protection Section 2090 U.S.70 Highway Swannanoa;NC 28778 RE: Duke Energy Progress Asheville Steam Electric Plant Asheville Airport Areas I,N and III Fill Projects April 2014 Groundwater Monitoring Results Dear Mr. Davidson: Attached are the results from the most recent semi-annual groundwater monitoring sampling event conducted in April 2014 for the wells near the Areas I, IV and III of the Asheville Regional Airport coal ash structural fills. The results from these sampling events are included on the GW59CCR forms normally used for groundwater monitoring results around ash basins per the recommendation from Jon Risgaard of the Non-Discharge Permitting Unit. As these structural fill sampling events are not part of an NPDES permit,this form was slightly modified and is not signed. Also attached are groundwater contour maps as prepared by SynTerra Corporation for these sampling events. The volume of leachate discharged to the Metropolitan Sewerage District(MSD)of Buncombe County,North Carolina since February 2014 through May 2014 from Area IV and Area III fill projects is as follows: Area W,Phase I/IA—0.37 MG Area N,Phase 2—3.94 MG Area III—2.73 MG Please note that Area III began direct discharge into the sewer system in March 2014 when the fill project began receiving ash. No leachate from Area IV fill area has been removed via pump and haul since connection to the MSD in late December 2013 as previously reported on February 18, 2014. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. Sincerely, 4 � TT`���.-;;= ;-~_ Gay A. Whisnant Vivision o'WPLt r Resomo' Asheville Plant Manager Attachment .IUN 2 5 2 Water oualit, ti�ni. ?{Q��+r24fOt1S www.duke-energy.com J GROUNDWATER QUALITY MONITORING: DEPARTMENT OF.ENVIRONMENT&NATURAL RESOURCES " Coal Ash Structural Fill Voluntary Report Form DNISION:OF WATER RESOURCES 2090 U.S HIGHWAY-70,SWANNANOA,'NC28778 FACILITY INFORMATION Please Print Clearly or Type Facility Name: Asheville Regional Airport Permit Type: DORS Expiration Date: 2/28/2015 Permit Name(if different): Duke Energy Progress,Inc. PERMIT Number: WQ0000020 Facility Address: 61 Terminal Drive (Street) TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill Fletcher NC 28732 j County Buncombe (City) (State) (Zip) Contact Person: Laurie Moorhead Telephone# 828-687-5240 Ed Well Location/Site Name: Structural Fill Area I No.of wells to be sampled: 4 (from Permit) Monitorin Well'Construction Information: Well ID Number(From Permit) Units MW1A-A3 MW2A-A1 MW4A-A1* MWS-Ai Well Depth [ft below land surface] ft 20.00 15.00 45.00 57.00 Measuring Point(toc)[ft above land surface] ft 2.72 3.56 0.17 3.08 Well Diameter in 2.0 2.0 2.0 2.0 Screen Top [ft below land surface] ft 5.00 5.00 30.00 42.00 Screen Bottom [ft below land surface] ft 20.00 15.00 45.00 57.00 Relative Measuring Point Elevation ft 2100.40 2102.71 2151.55 2153.86 ........... ....... ;=Sampling'Ipformatlon,a»d Field:Analysis ' CHECK IF DRY WELL AT TIME OF SAMPLING ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY 15A-2L Units MW1A-Al MW2A-Al MW4A-Al* MWS-Al Sample Date 04/09/2014 04/09/2014 04/09/2014 04/09/2014 Water Level[ft below measuring pt.](82546) ft 6.92 0.51 19.18 36.79 Volume of Water pumped/bailed gal 0.25 0.20 0.25 3.00 Temperature(00010) deg.C 13 12 151 15 Odor(00085) None None None None Appearance Normal Normal Normal Normal Specific Cond-field(00094) umhos/cm 41 33 681 22 pH-field(00400) 1 6.5-8.5 SU 5.2 5.2 4.81 4.7 ` Laboratory Information Laboratory Name Pace Analytical Certification q Samples for metals were collected unfiltered: 0 Yes ❑ No Sample Analysis Date April 10-22,2014 530 and field acidified: 0 Yes ❑ No 15A-21. Units MW1A-Al MW2A-Al MW4A-A1* MW5-Al Sb-Antimony(01097) 1 ug/I <0.5 <0.5 <0.5 <0.5 As-Arsenic(01002) 30 ug/I <5 <5 <5 <5 Ba-Barium(01007) 700 ug/I 16.6 15.1 27.1 27.5 B-Boron(01022) 700 ug/I <50 <50 <50 <50 Cd-Cadmium(01027) 2 ug/I <1 <1 <1 <1 CI-Chloride(00940) 250 mg/I <1 2 1.8 <1 Cr-Chromium(01034) 10 ug/I <5 <5 <5 <5 Cu-Copper(01042) " 1 mg/I <0.005 <0.005 <0.005 <0.005 Fe-Iron(01045) 300 ug/I 98.2 <50 2070 464 Pb-Lead(01051) 15 ug/I <5 <5 <5 <5 Mn-Manganese(01055) 50 ug/I 8.6 <5 904 52.8 Hg-Mercury(71900) 1 ug/1 <0.2 <0.2 <0.2 <0.2 Ni-Nickel(01067) 100 ug/I <5 <5 <5 <5 Nitrate(NO3)as N(00620) 10' mg/I 0.72 0.37(B) 0.069(B) 0.92 Se-Selenium(01147) 20 ug/I <10 <10 <10 <10 SO4-Sulfate(b0945) 250 mg/I <2 <2 6.6 2.1 TI-Thallium(01059) 0.2 ug/I <0.1 <0.1 <0.1 <0.1 TDS-Total Diss.Solids(70300) 500 mg/I <33.3 <25 34 <25 Zn-Zinc(01092) 1 mg/I <0.01 0.0167 <0.01 0.0201 Al-Aluminum(01105) ug/I N/A N/A N/A N/A ;BOLD values equal or exceed the corresponding 21.standard • - •- s • -•e- • •- - • • e -• -•• - - • • • - - 2A#tX2t tXQ 1244atory analytical,dataproduced •approved methods• • A -• . e • - -are significant enalfies for subi-nitting false inf6rmation,including flye possibility offine�and imprisonment for knowirig Violations. Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) Date GW-59CCR-Voluntary *-Denotes Background Well (B)-Laboratory"B"flag i r IC GROUNDWATER QUALITY MONITORING: • DEPARThAENTOF'ENVIRONMENT&NATURALatESOURCES ,.. Coal Ash Structural Fill Voluntary Report Form •• DIVISION OF WATER RESOURCES 2090�U,S HIGHWAY 70,SIiVAr NANOA,NC.28778 FACILITY INFORMATION Please Print Clearly or Type Facility Name: Asheville Regional Airport Permit Type: DORS Expiration Date: 2/28/2015 Permit Name(if different): Duke Energy Progress,Inc. PERMIT Number:1 WQ0000020 Facility Address: 61Terminal Drive (Street) TYPE OF PERMITTED OPERATION BEING MONITORED Coal Ash Structural Fill Fletcher NC 28732 County Buncombe (City) (State) (zip) Contact Person: Laurie Moorhead Telephone# 828-687-5240 Well Location/Site Name: Structural Fill Areas III&IV No.of wells to be sampled: 14 (from Permit) a. ..r , , ♦. .. - - .. ` w-.Monitorin ;Vi►elhConstructlon`(n orrnat�an Well ID Number(From Permit) Units MW-1A * MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-5-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-5-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Well Depth [ft below land surface] ft 84.50 57.50 62.90 64.70 33.70 62.40 66.70 67.50 30.00 25.00 71.50 30.00 30.00 95.00 Measuring Point(toc)[ft above land surface] ft 2.01 2.11 2.29 2.59 1.70 1.77 1.41 2.88 3.01 2.49 4.51 3.59 2.63 2.38 Well Diameter in 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Screen Top [ft below land surface] ft 74.50 42.50 47.90 49.70 23.70 47.40 51.70 52.50 10.00 10.00 61.50 15.00 15.00 85.00 Screen Bottom [ft below land surface] ft 84.50 57.50 62.90 64.70 33.70 62.40 66.70 67.50 30.00 25.00 71.50 30.00 30.00 95.00 Relative Measuring Point Elevation ft 2136.19 2169.35 2147.13 2140.98 2117.64 2123.16 2130.44 2121.54 2076.56 2068.31 2071.47 2074.01 2071.37 2059.15 I liri a to`marl "n`and Fie d^Anal's)s . - P g n r o y CHECK IF DRY WELL AT TIME OF SAMPLING ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY ❑ DRY 15A-2L Units MW-1A * MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-5-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-5-A4 MW-SD-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sample Date 04/10/2014 04/09/2014 04/09/2014 04/09/2014 04/10/2014 04/10/2014 04/10/2014 04/10/2014 04/11/2014 04/11/2014 04/11/2014 04/11/2014 04/11/2014 04/11/2014 Water Level[ft below measuring pt.](82546) i ft 30.94 39.80 20.80 29.66 18.55 22.82 29.19 22.24 15.05 7.53 13.06 15.86 19.36 8.97 Volume of Water pumped/bailed gal 1.00 4.00 0.20 2.00 0.50 0.50 2.25 0.50 0.25 0.50 0.25 0.25 0.25 0.50 Temperature(00010) deg.0 15 16 14 14 14 15 16 161 12 11 13 16 16 16 Odor(00085) None None None None None None None None None None None None None None Appearance Normal Normal Normal Normal Normal Normal Normal Normal Normal Normal Normall Normal Normal Normal Specific Cond-field(00094) umhos/cm 52 37 36 19 49 53 21 21 67 99 631 39 15 79 pH-field(00400) 1 6.5-8.51 SU 5.2 5.2 5.3 5.2 5.4 6.0 5.2 4.9 4.7 5.1 5.81 5.1 4.4 5.9 v . Laboraiko �Informat)on ry. Laboratory Name Pace Analytical Certification# 530 Samples for metals were collected unfiltered: p Yes ❑ No Sample Analysis Date April 10-24,2014 F and field acidified: 0 Yes ❑ No 15A-21. Units MW-1A * MW-1-A3 MW-2-A3 MW-3-A3 MW-4-A3 MW-5-A3 MW-6-A3 MW-7-A3 MW-2-A4 MW-5-A4 MW-51)-A4 MW-6-A4 MW-7-A4 MW-9-A4 Sb-Antimony(01097) 1 ug/I <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 As-Arsenic(01002) 30 ug/1 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Ba-Barium(01007) 700 ug/I 14.8 34.4 5.7 11.5 10.5 10.1 26.3 9.5 32.1 68.6 19.6 23.7 25 6.9 B-Boron(01022) 700 ug/1 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 <50 Cd-Cadmium(01027) 2 ug/l <11 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 CI,Chloride(00940) 250 mg/I <1 1.5 1.1 <1 1 <1 <1 <1 13.3 5.5 <1 1.3 1.4 <1 Cr-Chromium(01034) 30 ug/I <5 8.1 <5 5.4 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Cu-'Copper(01042) 1 mg/I <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 Fe-Iron(03045) 300 ug/I <50 1390 91.4 226 502 149 503 <50 <50 <50 <50 <50 <50 59.1 Pb-Lead(01051) 15 ug/I <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Mn-Manganese(01055) 50 ug/I 16.6 236 71.9 - 100 166 280 54.4 91.5 27 13.6 <51 <5 <5 9.2 Hg-Mercury(71900) 1 ug/I <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Ni-Nickel(01067) 100 ug/1 <5 5.8 <5 8.4 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 Nitrate(NO3)as N(00620) . 10' mg/I 3.5 0.65 0.19(B) 0.11(B) 0.33(B) 0.19(B) 0.064(B) 0.12(B) 0.33(B) 3 1.1 0.52(B) 0.11(B) 1.1 Se-Selenium(01147) 20 ug/I <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 SO4-Sulfate(00945) 250 mg/I. <2 2.8 4.4 2.8 <2 2.2 <2 <2 <2 11.3 <2 <2 <2 <2 TI-Thallium(01059) 0.2 ug/I <0!1 0.11 <0.1 <0.1 <0.1 <0.1 0.13 <0.1 <0.1 <0'A <0.1 <0.1 <0.1 <0.1 TDS-Total Diss.Solids(70300) 500 mg/I, 29 <25 35 <25 61 49 <25 43 56 72 74 45 <25 85 Zn-Zinc(01092) 1 mg/I <0.01 0.0156 <0.01 0.0144 0.0226 <0.01 0.018 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 <0.01 Al-Aluminum(01105) ug/I N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A (BOLD values,equal or exceed the corresponding 2L9tandard - • - •- • • -•s- • •- - - o • • -e -•• - • • •- - • .eo • •, • •• -• a .•• • -• - •• • • ! � - -o .o• m - - Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) Date GW-59CCR-Voluntary *-Denotes Shared Background Well for Areas III&IV (B)-Laboratory"B"flag A _ ,_x t r�:,e i �w�ilTinrGos`' MW-2A -� 2102.20 °°' \": •.,, ,; i r •�,s. Ye 4s '��2093.48 _ , s ���� r + f" �' s i a `"'� ■..L!• `'+`' k �t��,g � .��lC' '� -.=r,..�s.J a4:' ,s ..;, e� 9�\ �e MW-5 18'RCP ' -41 I r1\\ ! !•/, i e' j :'�e Top of Casing \• \ • \ • 4? WellID Northing Easting �`, ,L, ■\ \\ '! ! / Elevation MW-01A 636559.6E 944943.83 2100.40 •\\, \\ ! ! e ti _ 0 '4 MW-02A 636617.12 945291.16 210271 '� MW-04A 635188.59 944975.13 2151.55 MW-D5 636320.32 944677.45 2153.86 t 1 `\ LEGEND r• '. • \\ • • ••'` 3. MWAA MONITORING WELL \ \ ! � P'A'�� ��s _. 1�. 2132.37 WATER ELEVATION IN FEET(msl.) ± • \ \/ • .pry ''` WATER LEVEL CONTOUR IN FEET(msl.) ®a o e® a• I (2FT CONTOUR INTERVAL) a ;'. ;'+' �O�\-�/�_ •� 4 +� �'." .......... COAL COMBUSTION PRODUCT LIMITS ————— REVIEW BOUNDARY •R - r . r.0 15r \ COMPLIANCE BOUNDARY r✓ 1 —--— PROPERTY LINE(APPROXIMATE) Fmw` 12132.374A u✓ ' �` SOURCES: ' _ �''�. S 2012 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAY AT 000 _ MtpY1dafagafaway.=s.usdagov1 WELL LOCATIONS COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND COMPUANCEBOUNDARY TAKEN FROM S&ME DRAWING TITLED'GROUNDWATER FLOW MAP STRUCTURAL FILL',DATED 12-16-2010. GRAPHIC SCALE 100 o H ,Oo 200 DUKE ENERGY PROGRESS w ' ` 146RNER6TREET,EU17E220 STRUCTURAL FILL-AREAI OHONESLLE60U6dd239999 CAROUNA29601 WATER LEVEL MAP-APRIL 2014 (' 9 PHONE B • �M +r 1 �ena ems P o Q�a U AS E REGIONAL AIRPORT o ARDENRDEN NORTH CAROLINA 4 5w.wwesrm,�,�w.oru.nu.av�«.w�oiao<.e. 1 Wei lA tlodhirg Ea3irtg TpP.oiC5sr4g 1 1.TN-1A 637462.82 84.19D1.02 213e.19 cmi 634J3784 942845.89 21e335 , �Afi1-2 E3444&88 953Em.52 214713 8.N1J 635548.38 94333734 214098 MW-4 6"1+40 943105.17 211764 NNV6 83B531.67 94323427 21=16 O� flwIe 639'T34.G' 9432671D 2130.44 t\ 4 '111.7 WMM38 94312a53 21Z1,5d n1 "• 2099.30 t- t MW-6 2101.25 MW-5 2100.34 MW-4 • ��.+.d�l- 2099.09 ; ' • ^00 +y 4 AREA 3 COAL ry � COMBUSTION' �17" PRODUCT LIMITS MW-3 (APPROXIMATE) Aov1 ��. a4 2111.32 O ASHEVILLE ^ry MW-2 REGIONAL 2126.33 AIRPORT 3 r '11w ram""' ' �,_ 2, , • �' LEGEND MW-1 •�P MW-7 MONITORING WELL(SAMPLED) 2129.55 2052.01 WATER LEVEL IN FEET(msl.) Mw-8 MONITORING WELL(NOT SAMPLED) j• _ WATER LEVEL CONTOUR IN FEET(msl.) ` .. NTOUR INTERVAL) COAL COMBUSTION PRODUCT LIMITS • ® � REVIEW BOUNDARY COMPLIANCE BOUNDARY ---- PROPERTY LINE(APPROXIMATE) SOURCES: 2012 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPTIAL DATA GATEWAY AT http://datagateway.nms.usda.gov/ALL WELLS SURVEYED INCEPT MW-3 BY WNC PROFESSIONAL ENGINEERS& SURVEYORS ON APRIL 19,2012. COMPLIANCE BOUNDARY,REVIEW BOUNDARY,AND LIMITS OFCCB FILL BASED t :P ON DRAWING BY FRANKLIN S.CRAIG,P.E.OF GASTONIA,NORTH CAROLINA { hd TITLED ARAA-AREA 3 ENGINEERED FILL DESIGN,SHEET 3-E1,DATED JANUARY 28,2013. 250 GRAPHIC SCALE O 50 500 FIGURE 2 IN FEEr DUKE ENERGY PROGRESS VIP 148 RIVER STREET,SUITE 220 STRUCTURAL FILL-AREA 3 GREENVPHONE8I64-421999AROLINA29601 WATER LEVEL MAP-APRIL 2014 www.synterracorp.com ASHEVILLE REGIONAL AIRPORT synTerra PROJECT S.MANAGER: KATHYDATE:04/25/2014 FLETCHER, NORTH CAROLINA PROTECT MANAGER:KA WEBB LAYOUT:WATER LEVEL MAP 0505201412:24PM PAProrjess Ener .302602ASHEVILLE PLA 17.2014 Well Samlin Area 3 Suuaural FIIDWGDUKEASHEVILLE STRUCTURAL FILL 3-WL MAP-2014.04.dw DUKE ENERGY® Duke Energy Progress,Inc. PROGRESS 410 S.Wilmington Street/NC14 Raleigh,NC 27601 March 20,2014 Mr. Brett Laverty RECEIVED Civision of water Resourm NC DENR Asheville Regional Office 2090 U.S.70 Highway . . Swannanoa, NC 28778 MAR 2 4 2014 RE: Asheville Airport Structural Fill Area III WRWouardyRegtonatOpewiffanS Pre-Coal Ash Placement Groundwater Monitoring Results Asheville Regional Office Dear Mr. Laverty: We completed a pre-coal ash placement groundwater:monitoring event for the seven review-boundary wells for:Area III coal ash structural fill located at the Asheville Regional Airport in December.2013. Note the background well for Area III fill will be the same background well that is in use for Area IV fill. As this background well for-Area IV fill was sampled in November, it was not sampled again in December. The table below summarizes parameters detected above groundwater quality standards. Parameter/Well ... 2L Limit MW-1. MW-2 MW-3 MW-4 MW-S : MW-6 MW-7 pH 6.5:=8.5 5.7 5.7 5.9 5.5 5.8 6 5.6 S.U: . . Iron 300 ug/I =--. . 301 --- --- --- 772 --- Manganese 50.ug/I 353 79.3 1 162 1 173 92.8 --- 92.8 The attached summary report prepared by Geotrack Technologies, Inc. includes the boring log and well construction record (form GW-1b) for each of the seven review boundary wells for Area III fill. Also attached are the groundwater sampling field notes from each review boundary well. The next sampling event for all three airport fill areas-will be in April 2014. This will- be the first post-ash placement monitoring event for Area III fill. A groundwater contour map will be submitted with the results from the April 2014 sampling event for each airport fill area. Please contact me at 919-546-7863 if you have any questions on the enclosed information. SinRToep J Fer Lead Engineer JT:I rt Attachments DENR Laverty Letter March 20,2014 Ashe le kAif.0o t Area:Il4Pre-Ash Placement Groundwater Sampling Event December 2013 for the Seven Review Boundary Wells Parameter :0202Ltmit i�flW-1 MW-2 MW-3 MW-4 MW-5 MIPV-6 MW-7 PQL Antimony(ug/1) 1 <5 <5 <5 <5 <5 <5 <5 5 k10 <10 <10 <10 <10 <10 <10 10 .Barium(ug/I)_r r'• •700, l22.5 10.1 8.6 13 8.3 17.1 10.2 5 Boron(ug/1) 700 <50 <50 <50 <50 <50 <50 <50 50 Cadmium(ug(I) 2 <1 <1 <1 <1 <1 <1 <1 1 Chloride(mg/1) 256 1.7 1.2 1.1 <i <1 <1 <S 1 Chromium(ug/I) 10 <5 <5 <5 <5 <5 <5 <5 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.005 Iron(ug/1) 300 227 .301 207 107 91.1 772 71.5 50 j Lead(ug/1) 15 <5 <5 <5 <5 <5 <5 <5 5 Manganese(ug/1) 50 353 79.3 162 173 92.8 35.9 92.8 5 Mercury(ug/1) 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 Nickel(ug/l) 100 <5 <5 <5 <5 <5 <5 <5 5 Nitrate-(as N)(mg/1) 10 0.6 <0.02 <0.02 0.066 <0.02 <0.02 <0.02 0.02 Selenium(ug/1) 20 <10 <10 QO <10 <16 <10 <ld 10 Sulfate(mg/1) 250 2.3 2.7 <2 <2 <2 <2 <2 2 -Thallium(ug/1) 0.2 <0.1 <0.1 <0:1. <0.1 <0.1 <0.1 <0:1 0.1 I Zine(mg/1) 1 0.012 <0.01 <0.01 <0.01 <0.01 0A155 <0:01 0.01 I TDS(mg/1) 5U0 31 58 <25 33 <25 58 <25 25 r PH(S.U.) 6.5-8.5 5.7 5.7 5.9 5.5 5.8 6.0 5.6 N/A water Level(ft.) N/A 39.77 21.23 29.77 18.42 22.65 30.08 -47.00 N/A Temperature(`C) N/A 14.4 11.9 13.7 14.1 13.6 11.4 13.5 N/A 1 SpecificCond. N/A 42 32 26 28 31 24 22 N/A i (umhos/cm) Turbidity(NTU) N/A 8 56 19 18 9 330 6 N/A j Date Sampled 1. N/A 1 12/10/201312/19/201312/10/2013 12/19/2013 12/11/2013 12/19/201312/1112013 N/A !115ANCACO2L.0202GroundwaterQualityStandards E PPQL-Practical Quantitation Limit ug/l- rams p g !u Imicro per liter __- jmg/I-_milligrams per liter iS.U.-.Standard Units j - 1---- r i----- j 'N U NephelometricTuibidity Unit _ _ j LT_T___' 2 RECEIVE® DUKE Duke Energy Progress AS ENERGY® DECVL PLT C 0DEC1 6 2013 t 3 Ardenn,, N NC 287 28704 PROGRESS Asheville Regional Office Aquifer Protection 4 Certified Mail: 7012 1640 0000 6844 4559 File Pt.: 12520-Q December 13,2013 Mr.G.Landon Davidson NCDENR/DWR Water Quality Regional Operations Section 2090 U.S.70 Highway Swannanoa,NC 28778 RE: Duke Energy Progress Asheville Steam Electric Plant Asheville Airport Area I&IV Fill Projects November 2013 Groundwater Monitoring Results Dear Mr.Davidson: Attached are results from the most recent semi-annual groundwater monitoring sampling event, conducted on November 4,2013, of wells near the Area I Asheville Regional Airport coal ash structural fill project. Also attached is a groundwater contour map as prepared by SynTerra Corporation for this sampling event. Sampled were down-gradient wells MW-lA,MW-2A and MW-5 along with up-gradient well MW-4A(for reflecting ambient conditions). The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Iron Manganese Groundwater 6.5—8.5 300 50 Quality Standard (u /1) MW-IA 5.2 --- --- MW-2A 4.8 --- --- MW-4A 4.6 976 935 MW-5 5.2 2,360 96.8 Results and a groundwater contour map from the most recent semi-annual groundwater monitoring sampling event, conducted on November 4 and 5,2013, of wells near the Area N Asheville Regional Airport coal ash structural fill project are also attached. Down-gradient wells MW-2,MW-5,MW-5D,MW-6,MW-7 and MW-9 along with up-gradient well MW-lA(for reflecting ambient conditions)were sampled. The table below summarizes parameters detected above groundwater quality standards. www.duke-energy.com DENR Davidson Letter December 13,2013 Well/Parameter PH Chromium Iron Groundwater 6.5—8.5 10 300 Quality Standard (ug/1) MW-lA 5.5 23.3 369 MW-2 4.9 --- --- MW-5 5.3 --- --- MW-5D 5.9 --- --- MW-6 5.2 --- --- MW-7 4.4 --- --- MW-9 6 --- --- All results from this sampling event are summarized on the following pages. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions regarding the results. Note that next sampling event for the Area I and Area IV coal ash structural fill is scheduled for April 2014. Sincerely, arry A. Chisnant Asheville Plant Manager Attachments 2 DENR Davidson Letter December 13,2013 Results from Sampling Event on November 4,2013 - Area I Structural Fill i Parameter .0202 Limit Well MWAA Well MW-2A Well MW-4A Well MW-5 PQL Antimony(ug/I) 1 <0.5 <0.5 <0.5 <0.5 0.5 Arsenic(ug/I) 10 <5 <5 <5 <5 5 1 Barium(ug/1) 700 15.9 15.5 27.5 67.4 5 Boron(ug,+'l) 700 <510 <50 <50 <50 50 cadmium(ug/1) 2 <1 <1 <1 <1 1 Chloride(mg/1) 250 1.2 2.1 2 1.5 1 Chromium(ug/1) 10 <5 <5 <5 6.1 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 0.005 Iron(ug/1) 300 51.6 67.4 976 2360 50 Lead(ug/1) 15 <5 <5 <5 7.1 5 Manganese(ug/1) 50 <5 <5 935 96.8 5 Mercury(ug/1) 1 <0.2 <0.2 <0.2 <0.2 0.2 Nickel(ug/1) 100 <5 <5 <5 5.1 5 Nitrate(as N)(mg/1) 10 0.55 0.16 <0.02 0.73 0.02 Selenium(ug/I) 20 <10 <10 <10 <10 10 Sulfate(mg/1) 250 <2 <2 7.8 <2 2 Thallium(ug/1) 0.2 <0.1 <0.1 <0.1 <0.1 0.1 i Zinc(mg/1) 1 <0.010 <0.010 <0.010 0.0244 0.01 TDS(nig/I) 500 34 29 44 116 25 pH(S.U.) 6.5-8.5 5.2 4.8 4.6 5.2 N/A Water Level(ft.) N/A 7.15 0.88 19.58 45.113 N/A Temperature('C) N/A 1.5 14 15 16 N/A Specific Cond. N/A 41 32 76 30 N/A (umhos/cm) Turbidity(NTU) N/A 2.1 1.7 4.2 183 N/A Date Sampled N/A 11/4/20,13 11/412013 11/4/2013 11/4/2013 N/A 15A NCAC 02L.0202 Groundwater-Quality-Standards PQL-Practical Quantitation Limit - ug/l--micrograms per liter - - - - mg/l-milligrams per liter ----- - - - - - - ;S.U.-Standard Units r - NTU-Nephelometric Turbidity Unit 3 _• JJJ ' c - .� � t ;.�, --rim• Exisnrvc S� _ � r' .. . ws.•,' �;�1?'.t�dj.•r,oo a1.2101.83 2093.25L4 "fte , ♦+ �i��18 RCP f ' 21086� �4 ♦��y •:'z� /9*'I � ,. '. \zS*• `r'♦ ♦h `♦ ■� 9)�! /- • •+{�a \ .ter 1+c,' '- t: • , ,t .3 * �,�. ` � ♦` `.sue/ y • ••• A 'Fib i} S }, �.. �i� �� �r ys..��fa'r ' S . 1 / ; y{I ii4 I ;�' ; �` ♦` // / \' ♦ DTI i ti WeII ID" Northing Fasting . Devadon i I '-� '; 4� ♦ - /. /. • ♦♦ M W-01A 636559..68 9443.83 2100 40 •\ 9291.16 210_ • MW-D2A 63661712 712 x i ; 1s M W-04A 635188.59 944975.13 2151.55 ! ■ I ,�- • ■ q ` ' z M W 05 636320.32 944677.45 2153.86 LEGEND t / " . ' .I ■ ♦ / r• •y.••' MW-4A MONITORING WELL I. + ` t •% dl�f ��'I� 0 2131.97 WATER ELEVATION IN FEET(msl.) • .�sA''I ,r WATER LEVEL CONTOUR IN FEET(msl.) ; • i"r"%" (2FP CONTOUR NMRVAL) 1; , 1 ` '���• %o, �•.�� '' ` •••••••••• COAL COMBUSTION PRODUCT LIMITS �. ————— REVIEW BOUNDARY �•r •. '� r. tit ' ,. ` • —.-� ,,� � � r_ COMPLIANCE BOUNDARY ,2� ' �' ,'_ —__— PROPERTY LINE(APPROXIMATE) a ` .tl i 2 3�9 s�'� , a4 S SOURCES: �'a-. �� 'R �C 2012 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATLAL DATA GATEWAY AT ♦ P '$ '` �; ' ti i'4 s htfpY1dafagatemynms.usda.gov1' }: ��• y 1 I,;� a WELL LOCATIONS,COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND COMPLIANCE BOUNDARYTAKEN FROM S&ME DRAWING TITLED"GROUNDWATER FLOW ,:F+,. r.. 1, •+ r r": - �, T } '.":-^9i' „♦,- � • it -A. i '�t7- -- � - GRAPHIC SCALE MAP STRU CTURAL FILL°,DATED 12-16-2010. 0 100 200 DUKE ENERGY PROGRESS 4 ` 148 RIVER STREET.SURE=0 STRUCTURAL FILL-AREA GREENVILLE SOUTH MOUNA 29601 WATER LEVEL MAP-NOVEMBER 2013 PHON `64-0o��9m ASHEVILLE REGIONAL AIRPORT 14 ARDEN,NORTH CAROLINA synTerra aaroa� s all �a DENR Davidson Letter December 13,2013 Results from Sampling Event on November 4 & 5,2013 - Area IV Structural Fill Parameter .0202Limit MWAA MW-2 MW-5 MW-5D MW-6 MW-7 MW-9 PQL Antimony(ug/1) 1 €0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 0.5 Arsenic(ug/1) 10 <5 <5 <5 <5 <5 <5 <5 5 j Barium(ug/1) 700 19.3 44.3 49.2 22 24.3 25 7.3 5 Boron(ug/1) 700 <50 <50 <50 <50 <50 <50 <50 50 Cadmium(ug/1) 2 <1 <1 <1 <1 <1 <1 <1 1 Chloride(mg/1) 250 1.3 16.1 5 <1 1.4 1.7 <1 1 Chromium(ug/1) 10 23.3 <5 <5 <5 <5 <5 <5 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 <0.005 <0,005 1 <0.005 0.005 Iron(ug/1) 300 369 51.3 78.8 126 75.3 122 72.7 50 Lead(ug/1) 15 <5 <5 <5 <5 <5 <5 <5 5 Manganese(ug/1) 50 39.6 28.7 9.5 <5 <5 5.5 11.4 5 Mercury(ug/1) 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 Nickel(ug/I) 100 13.7 <5 <5 <5 <5 <5 <5 5 Nitrate(as N)(mg/1) 10 3.5 0.035 0.98 0.91 0.31 <0.02 0.93 0.02 Selenium(ug/1) 20 <10 <10 <10 <10 <10 <10 <10 10 Sulfate(mg/1) 250 <2 <2 2.9 <2 <2 <2 <2 2 Thallium(ug/1) 0.2 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 <0.1 0.1 Zinc(mg/I) 1 0.011 0.0119 <0.010 <0.010 <0.010 0.023 <0.010 0.01 TDS(mg/1) 500 44 49 39 63 28 <25 71 25 PH(S.U.) 6.5-8.5 5.5 4.9 5.3 5.9 5.2 4.4 6 N/A Water Level(ft.) N/A 30.47 15.47 8.45 14.09 17.21 20.62 10.79 N/A Temperature('C) N/A 15 15 16 14 14 15 14 N/A SpecificCond. N/A 54 72 57 76 36 15 82 N/A (umhos/cm) Turbidity(NTU) N/A 12 3 3.7 8.7 2.8 4.4 6 N/A Date Sampled N/A 11/4/2013 11/4/2013 11/5/2013 11/5/2013 11/4/2013 11/5/2013 11/5/2013 N/A '15A NCACO2L.0202 Groundwater Quality Standards i PQL-Practical Quantitation Limit ug/I-micrograms per liter I mg/I-milligrams per liter - 'S.U.-Standard Units r - !NTU-Nephelometric Turbidity Unit', 4 ti r Well ID Northing Fa Topot Casingsting Elevation MW-1A 631462.82 944901.02 2136.19 i.q 1• - it( t " . MW-2 629920.28 944436.90 2076.56 MW-5 629395.45 944832.59 2068.31 Mw-sD 629386.39 94484205 2071.47 ASHEVILLE REGIONAL AIRPORT l 6t , `• MW-6 628967.08 94520285 2074.01 MW-7 628489.87 94551201 2071.37 ,�\ ` S"S r: tp t . ,"F �,• MW 9 _ 627830.E 93212 2059.1� •E_ y�.�.1, 2 r ` L7y yi.,#/ t f'ti1F. f '};t.1� °9 t `?7 ♦ r" pt ,� }/r° � �,� ?O s s r�`I1 '�S�} ♦♦�`i 1�, ' - y�� - y ' 11„r� 9 r 2.�J;��f •L , � f ��r'�t F NNNGgatO=� � I1 i +.f# r - O° X ■ �" ♦ 1 :tip 'x' s l rs;,. '�+ ��r•1�� ,' �O ,fi� % �f"t�I.`�♦�'� � � �. �1 �,/!' �f�F .J' r fie' \ ,'..�.�R d�, , ..« ss�:�r ,1 +` ® �.. moo♦ � , - 'r •� ",f • s.i"' F .B .J ` `47• '' ..' S t +a 1, { �•-, ?os0r f` • � .� � `may� � ■ ; \ 1, h 5^ MW-2 ?O8 PHASE II COAL s ■ } t el + 2061.09 �cOMBUSTION If ,;,,.. � ' ♦ (:PRODUCT LIMITS ! �\ 1 PHASE I COAL. t 1 v r^i9 ♦` (APPROXIMATE �• COMBUSTION ,• '� I ,^"-^""`s-; a:ra' ,� ♦ r'-- `7 ',�•_ `� r PRODUCT LIMITS I ♦` '✓�r ♦ * APPROXIMATMW r a^,• r`r•�� � ♦ '/✓ rj+ `-�7�° I� ..R. � � 1 C1e}) ��,.�- � ,' � It ,- f �MW 5D % 44 ♦, \ L °'WESTERN NORTH CAROLINA 2057 38 AGRICULTURAL CENTER / ENTRANCE " ���♦` �l� �` ! % • ` ` rY ft �r ra r � 2055 80 1 � " t yy 0000 ey :.i�,.*s .( � ^c � r. ` � � R■ l{11. t► '-y. � sF' I I ', - ,� ow 2050.75 '' O?►> ` i t t�111 i.� }•- 901 , .�" RO . *{�` !! AA�MW 8 �S •� � � �1 I #i«r.y :y, MW-9 .. y 2048.36 ti • `ate _ � "�� e� ,`�,� �;.;�rJ'"�-'�.• I y v �v,�> �k�,n r'''�M1. ��it� LEGEND + *�!t MW-7 I MONITORING WELL(SAMPLED) 012050.75 WATER LEVEL IN FEET(msl.) & ,� ,�t ti�� .' e0rt5 .e1�'";�`y l' ► " ±,'�,' � ,. 9 MW-8 MONITORING WELL(NOT SAMPLED) JI`+ WATER LEVEL CONTOUR IN FEET(msl.) SOURCES: m 1— 2012 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPHAL DATA GATEWAY M!' ) AT http:/(2FT CONTOUR INTERVAL /datagateway.nrrs.usda.gov/ s ` •t ASHEVILLE { } i mmmm. COAL COMBUSTION PRODUCT LIMITS ALL WELLS SURVEYED EXCEPT MW-3 BY WNC PROFESSIONAL ENGINEERS& REGIONAL SURVEYORS ON APRIL 19,2012. r AIRPORT ♦ �� REVIEW BOUNDARY J " COMPLIANCE BOUNDARY,REVIEW BOUNDARY,AND LIMITS OF CCB FILL BASED l• -r 1tJ r Z.'!t"Twyr{e!t! o COMPLIANCE BOUNDARY ON DRAWING BY FRANKLIN S.CRAIG,P.E.OF GASTONIA,NORTH CAROLINA �•• -r'� ,s „�,p'"*., i, TITLED AREA#4-ALL PHASES ENGINEERED FILL DESIGN,SHEET E-1,DATED ---- PROPERTY LINE(APPROXIMATE) JUNE30,2011. GRAPHIC SCALE 300 0 300 600 DUKE ENERGY PROGRESS IN FEET148 RIVER STREET SUITE 220 STRUCTURAL FILL-AREA 4 GREENVILE,SOUTH CAROLINA 29601 WATER LEVEL MAP- NOVEMBER 2013 PHONE86rracor9999 ASHEVILLE REGIONAL AIRPORT ' WATER m synTerra DRAWN DATE:11/15/2013 ARDEN, NORTH CAROLINA PROJECT MANAGER:EL MA WEBB LAYOUT:WATER LEVEL MAP 11/27/20138:57 AM P:\Prag,..Energy.1026\02.ASHEVILLE P'LANT\12.2013 Well Sampling Area 4\DWG\PE ASHEVILLE STRUCTURAL FILL 4WL MAP.2013.ii.dwg I RECEIVE® kL'W- ress Pro 9 Energy Asheville Regional Office Certified Mail: 70113500 0003 6728 6223 Aquifer Protection File Pt.: 12520-Q May 1,2013 Mr.G.Landon Davidson NCDENR/DWQ Aquifer Protection Section 2090 U.S.70 Highway Swannanoa,NC 28778 RE: Progress Energy Carolinas Asheville Steam Electric Plant Asheville Airport Area I&IV Fill Projects April 2013 Groundwater Monitoring Results Dear Mr.Davidson: Attached are results from the most recent semi-annual groundwater monitoring sampling event, conducted on April 1, 2013, of wells near the Area I Asheville Regional Airport coal ash structural fill project. Also attached is a groundwater contour map as prepared by SynTerra Corporation for this sampling event. Sampled were down-gradient wells MW-1A,MW-2A and MW-5 along with up-gradient well MW-4A(for reflecting ambient conditions). The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Iron Manganese Groundwater 6.5—8.5 300 50 Quality Standard (u 1) MW-1A 5.2 --- --- MW-2A 5.3 --- --- MW-4A 4.3 432 1500 MW-5 4.6 --- 77 Results and a groundwater contour map from the third semi-annual groundwater monitoring sampling event, conducted on April 1 and 2,2013, of wells near the Area IV Asheville Regional Airport coal ash structural fill project are also attached. Down-gradient wells MW-2,MW-5, MW-5D,MW-6, MW-7 and MW-9 along with up-gradient well MW-lA(for reflecting ambient conditions)were sampled. The table below summarizes parameters detected above groundwater quality standards. Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter May 1,2013 Well/Parameter pH Chromium Iron Groundwater 6.5—8.5 10 300 Quality Standard (ug/1) MW-lA 5.2 14 --- MW-2 6 --- --- MW-5 6.3 --- --- MW-5D --- --- I --- MW-6 6.2 --- 452 MW-7 5.6 --- --- MW-9 --- --- --- All results from this sampling event are summarized on the following pages. Please contact Ms.Laurie Moorhead at 828-687-5240 if you have any questions regarding the results. Note that next sampling event for the Area I and Area IV coal ash structural fill is scheduled for November 2013. Sincerely,X4 '%' A Garry A. Whisnant Asheville Plant Manager Attachments 2 DENR Davidson Letter May 1,2013 Results from Sampling Event on April 1,2013 -Area I Structural Fill Parameter .0202 Limit MW-1A MW-2A MW-4A MW-5 PQL Date Sampled N/A 4/1/13 4/1/13 4/1/13 4/1/13 Antimony (ug/1) 1 <1 <1 <1 <1 1 Arsenic (ug/1) 10 <1 <1 <1 <1 1 Barium (ug/1) 700 20 14 40 25 5 Boron(ug/1) 700 <50 <50 <50 <50 50 Cadmium (ug/1) 2 <1 <1 <1 <1 1 Chloride (mg/1) 250 0.96 1.7 1.4 1.3 0.1 Chromium (ug/1) 10 <5 <5 <5 7 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 0.005 Iron(ug/1) 300 267 12 432 153 10 Lead (ug/1) 15 <1 <1 <1 <1 1 Manganese (ug/1) 50 16 <5 1500 77 5 Mercury (ug/1) 1 <0.05 <0.05 <0.05 <0.05 0.05 Nickel (ug/1) 100 <5 <5 <5 5 5 Nitrate (as N)(mg/L) 10 0.54 0.12 0.05 1.3 0.023 Selenium (ug/1) 20 <1 <1 <1 <1 1 Sulfate (mg/1) 250 <0.1 0.18 2.7 0.22 0.1 Thallium (ug/1) 0.2 <0.2 <0.2 <0.2 <0.2 0.2 Zinc(mg/1) 1 <0.005 0.005 0.017 0.02 0.005 TDS (mg/1) 500 30 26 22 14 10 pH(S.U.) 6.5 -8.5 5.2 5.3 4.3 4.6 N/A Water Level (ft.) N/A 7.1 0.72 20.18 45.4 N/A Temperature (°C) N/A 14.3 14.3 15.6 16.3 N/A Specific Cond. N/A 38 33 42 25 N/A (umhos/zu) Turbidity N/A 15.4 0.9 4.38 13.1 N/A 15A NCAC 0.2L.0202 Groundwater quality standards PQL-Pratical Quantitation Limit ug/L-micrograms per liter mg/l -milligrams per liter S.U. -Standard Units NTU-Nephelometric Turbidity Unit 3 !L ASHEVILLE REGIONAL All RPORTn. � 1r I ON - it l _ • 2104.51 , � •� ,�.y,4. r �. ,t VW j. 15 Y S? MW-1 gw %,4 ♦ � ' .�f�F1 �'�` r v- v �I. �•,� p 7-.• •� � �♦ %"�, � �� i'u' , tl -,tom a;,� ���� v.. It `rYr r ;PHASE II COAL I o y+ • ♦' _ i •is ktiS"r' 1_ �r-----�-r------- 2062.13 COMBUSTION ♦ i S,•�•. r -'1 ` PRODUCT LIMITS �'', ♦ I PHASE I COAL♦ (APPROXIMATE) r �• i 'l COMBUSTION + „ '..'�!rr , v - I PRODUCT LIMITS ,,�• _ ,..�.� - r •Y ;�� ♦ ` .�-'., j i" ♦"' ` 1 (APPROXIMATE) 11 S �, ;iR I �•�, I; ' 'J +r�+r j �ei-�f � ♦ -� �ao�� 61 .` l `i ��' c;,r ;� -_ F� it - �', !� rl•# ,92060.7 ���a?�♦' '1 , , • II � - ' NORTH r NA AGRICULTURAL CENTER ENTRA ` � _ �2058.19 k T r AT; 2)57.90 r r Ilk W-7Oil r M ° ♦ ® R , r, Mw81'i7eb, - RJG� — ,.'l 2049.62 ~ 'F � '``•..!` ,��"".'-+-�'f^ -� f ��q Y.X.-v ti•rj �{ 1��� �'�,' LEGEND cl(Mw--s �- - ` MW-7 MONITORING WELL(SAMPLED) *1r Y•� + ''�I``�} y NNE` t + ��"�4 " 2051.72 WATER LEVEL IN FEET(msl.) ;�^ ?� '♦'"'' o -� � X' s�� �*�1' �� a���_..,- ,I ;., •\ „+'r t+r���, s Mw-8 MONITORING WELL(NOT SAMPLED) tirR•r+� y J `•-� t-* 1 �' r y :r WATER LEVEL CONTOUR IN FEET(msl.) souRces. i1, '/ R ^+� •I�,: e * rl 111W11111 2012 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPTIAL DATA GATEWAY 2FT CONTOUR INTERVAL / 1 ( ) AT http://datagateway.nres.usda.gov/ ��r•�� COAL COMBUSTION PRODUCT LIMITS ALL WELLS SURVEYED EXCEPT MW-3 BY WNC PROFESSIONAL ENGINEERS& ASHEVILLE �•j'ry REGIONAL SURVEYORS ON APRIL 19,2012. ; AIRPORT REVIEW BOUNDARY COMPLIANCE BOUNDARY,REVIEW BOUNDARY,AND LIMITS OF CCB FILL BASED \, r_ COMPLIANCE BOUNDARY ON DRAWING BY FRANKLIN S.CRAIG,P.E.OF GASTONIA,NORTH CAROLINA wJ TITLED AREA N4-ALL PHASES ENGINEERED FILL DESIGN,SHEET E-1,DATED .,.,...•F a 1 •tS'Y. •� —--— PROPERTY LINE(APPROXIMATE) JUNE 30,2011. } ` GRAPHIC SCALE 300 0 300 600 PROGRESS ENERGY IN FEET STRUCTURAL FILL -AREA 4 148 RIVER STREET,SUITE 220 GREENVILLE,SOUTH CAROLINA 29601 WATER LEVEL MAP-APRIL 20'13 461, PHONE864ra2 ASHEVILLE REGIONAL AIRPORT rp.com www.synterra co rp.c o syrlTerra DRAWN MANAGER: DATE:04/19/2013 ARDEN, NORTH CAROLINA PROTECT MANAGER:HATHY WEBS LAYOUT:WATER LEVEL MAP O4/24/20132:38PM PAProgrez Ener .1026 02ASHEVILLE PLA 12.2013 Well Sampling Area 4 WG PE ASHEVILLE STRUCTURAL FILL 441.MAP-2012-ilAw DENR Davidson Letter May 1,2013 Results from Sampling Event on April 1 &2,2013 -Area IV Structural Fill Parameter .0202 Limit MW-1A MW-2 MW-5 MW-5D MW-6 MW-7 MW-9 PQL Date Sampled N/A 4/1/13 4/2/13 4/2/13 4/2/13 4/2/13 4/2/13 4/2/13 Antimony(ug/1) 1 <1 <1 <1 <1 <I <1 <1 1 Arsenic(ug/1) 10 <1 <1 <1 <1 <1 <1 <1 1 Barium(ug/1) 700 19 48 52 21 29 23 9 5 Boron(ug/1) 700 <50 <50 <50 <50 <50 <50 <50 50 Cadmium(ug/1) 2 <1 <1 <1 <1 <1 <1 <1 1 Chloride(mg/1) 250 1 16 4.1 0.65 1.1 1.2 0.74 0.1 Chromium(ug/1) 10 14 <5 <5 <5 <5 <5 <5 5 Copper(mg/I) 1 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 0.005 Iron(ug/l) 300 287 99 44 35 452 <10 256 10 Lead(ug/1) 15 <1 <1 <1 <1 <I <1 <1 1 Manganese(ug/1) 50 41 33 10 <5 15 <5 24 5 Mercury(ug/1) 1 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 0.05 Nickel (ug/1) 100 10 <5 <5 <5 <5 <5 <5 5 Nitrate(as N)(mg/L) 10 3.4 <0.023 1.3 0.89 0.3 <0.023 0.9 0.023 Selenium(ug/1) 20 <1 <1 <1 <1 <1 <1 <1 1 Sulfate(mg/1) 250 <0.1 0.36 3.3 0.15 0.37 <0.1 0.4 0.1 Thallium (ug/1) 0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.2 Zinc(mg/1) 1 0.018 0.013 <0.005 <0.005 0.006 <0.005 0.007 0.005 TDS(mg/1) 500 46 51 46 70 33 11 75 10 pH(S.U.) 6.5-8.5 5.2 6 6.3 6.9 6.2 5.6 6.9 N/A Water Level (ft.) N/A 31.68 14.43 7.52 13.28 16.11 19.65 9.53 N/A Temperature(°C) N/A 15 12.4 10.2 12 14.2 14.1 13.6 N/A Specific Cond. N/A 53 81 57 82 36 14 81 N/A (umhos/cm) Turbidity(NTU) N/A 7.72 3.78 5.87 1.79 6.53 1.73 9.74 N/A 15A NCAC 0.2L.0202 Groundwater quality standards PQL-Pratical Quantitation Limit ug/L-micrograms per liter mg/I-milligrams per liter S.U.-Standard Units NTU-Nephelometric Turbidity Unit 4 �,X h +i ��. CULVERT #; - r, _ s � µ .. •. EXISTING - S� '►1it ' w !� !� f� �, ti Ip K 'YI�I cur-aye wr' .#- «► ; 2093 30 � w f r A. io !v t r ♦ 18"RCP { Z u , I{' 2108.46 ♦, ,% _.�`_.; ,+.e - •� ® yam. ''�\ < Try 3 AA y, 40e r ID r , \ *, �. ■ All -44 t g`� e t:.y '.,{ y ` / r '•. � ♦ r vet. O 10 oo r j ` f 1 / �••� LEGEND ■ cl ••. MW-4A MONITORING WELL ■ •• t ` ; ` 0 /�/ a•• 2131.37 WATER ELEVATION IN FEET(msl.) i ': : ,"1►, � � WATER LEVEL CONTOUR IN FEET(msl.) a e� j.-� �� ..� (2F"CONTOUR INTERVAL) 11y �� s •••* ; . s`{N ■n.......■ COAL COMBUSTION PRODUCT LIMITS REVIEW BOUNDARY b \ O ♦I �,� P .� , �. COMPLIANCE BOUNDARY go® • ., TT00 PROPERTY LINE(APPROXIMATE) a! y MW-4A SOURCES: �2131.37 2012 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAY AT !a 4 http://datagateway.nres.usda.gov/ .r S WELL LOCATIONS,COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND COMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING TITLED"GROUNDWATER FLOW p MAP STRUCTURAL FILL",DATED 12-16-2010. CL' 4 + ;e. ire', GRAPHIC SCALE )? ? * 100 0 100 200 PROGRESS ENERGY IN FEET 148 RIVER STREET,SUITE 220 STRUCTURAL FILL -AREA 44 GREENVILLE,SOUTH CAROLINA 29601 WATER LEVEL MAP -APRIL 2013 PHONE 864-421-9999 www.synterracorp.com ASHEVILLE REGIONAL AIRPORT . # 'r -',� _ ynTe �� DRAWN BY:C.NEWELL DATE 4/19/2013 „ '.,. _ 1 - _ so PROJECT MANAGER:KATHY WEBS ARDEN NORTH CAROLINA .t' LAYOUT.WL MAP APRIL 2013 ¢ + .� t " 4/19/20131:55 PM P:\Pro ess Ener .3026\02ASHEVILLE PLANT\11.2013 Well Sampling Area 1\DWG\PE STRUCTURAL FILL AREA 1-Wl--MAP.2013-04.dvig n FEE to� Pro ress Ener J gY ON 032619 Asheville Regier4 i Certified Mail: 70113500 0003 6728 5714 n tl �t; l�i'J7:r'^1 i File Pt.: 12520-Q January 2,2013 Mr.G.Landon Davidson NC DENR/DWQ Aquifer Protection Section 2090 U.S.70 Highway Swannanoa,NC 28778 RE: Progress Energy Carolinas Asheville Steam Electric Plant Asheville Airport Area I&IV Fill Projects November 2012 Groundwater Monitoring Results Dear Mr.Davidson: Attached are results from the seventh semi-annual groundwater monitoring sampling event, conducted on November 13,2012, of wells near the Area I Asheville Regional Airport coal ash structural fill project. Also attached is a groundwater contour map as prepared by SynTerra Corporation for this sampling event. Sampled were down-gradient wells MW-IA,MW-2A and MW-5 along with up-gradient well MW-4A(for reflecting ambient conditions). All of these wells are located within the compliance boundary around the Area I ash fill project. The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Chromium Iron Manganese Groundwater 6.5—8.5 10 300 50 Quality Standard (u 1) MW-lA 5.5 --- --- --- MW-2A 5.5 --- --- --- MW-4A 4.9 --- 643 978 MW-5 4.8 10.5 --- 72 Results and a groundwater contour map from the second semi-annual groundwater monitoring sampling event, conducted on November 13 and 14, 2012, of wells near the Area IV Asheville Regional Airport coal ash structural fill project are also attached. Down-gradient wells MW-2, MW-5, MW-5D, MW-6,MW-7 and MW-9 along with up-gradient well MW-IA(for reflecting ambient conditions)were sampled. Nitrate was detected in the field blank for the Area IV fill project. Therefore,the nitrate data with concentrations less than 5 times the field blank concentrations are qualified with a`13' flag. The table below summarizes parameters detected above groundwater quality standards. Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 November 2012 Asheville AirpOIL vv✓Results January 2,2013 Well/Parameter PH Chromium Iron Manganese Groundwater 6.5—8.5 10 300 50 Quality Standard (u /1) MWAA 5.4 33.9 543 66.6 MW-2 5 --- --- --- MW-5 5.3 --- --- --- MW-5D 6 --- 994 --- MW-6 5.3 --- --- --- MW-7 4.8 --- --- --- MW-9 6.1 --- --- --- All results from this sampling event are summarized on the following pages. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions regarding the results. Note that next sampling event for the Area I and Area IV ash fills is scheduled for April 2013. Sincerely, 4Garr�. �W' hlsnant Asheville Plant Manager Attachments 2 November 2012 Asheville Airpal L.,YJ Results January 2,2013 Results from Sampling Event on November 13, 2012-Area I Structural Fill Parameter .0202 Limit Well N7lt A A 'W'19e11 MW-2A Well MW 4A 194b'ell MW-5 PQL Date Sampled N/A 11/13/12 11/13/12 11/13/12 1JL/JL3/12 N/A Antimony(sug/1) 1 <0.5 <0.5 <0.5 <0.5 0.5 Arsenic(ug/1) lei <5 <5 -05 <5 5 Barium(ung/1) 700 15.7 15.6 27.5 24.8 5 Boron(eg/1) 700, <50 <5-0 <50 <50 50 Cadmium(ug/1) 2 <0.08 <0.'08 <0.08 <0.08 0.08 Chloride(mg/1) 2.50, 1.2 2 2.2 <1 1 Chromium(ug/1) 10 <5 <5 <5 10.5 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 0.005 Iron(uag,11) 300, 93.5 71.3 643 247 50 Lead(uaglljI 15 <5 <5 <5 <5 5 Manganese(aug 1) 50 5.9 <5 978 72 5 Mercury(ug/Q 1 <0.2 <0.2 <0.2 <0.2 0.2 Nickel(ug/Q 100 <5 <5 C5 6.2 5 Nitrate(as N)(mg/1) 10 0.63 0.085 <0.02 1.3 0.02 SeleniEucm jug/I) 20 <10 <11b <10 <10 10 Sulfate(mg/1) 250 <2 <2 12.3 <2 2 Thallium(ug/I) 0.2 <0.1 <0.1 <0.1 <01.1 0.1 Zinc(mg/1) 1 <0.010 0.0169 <0.'010 0.0172 0.01 TDS(cmg,Q 500 35 <25 57 <25 25 pH(S.U.) 6.5-8.5 5.5 5.5 4.9 4.9 N/A VWater Level(ft.) N/A 7.60 1.28 22.60' 45.70 N/A Temperature('C) N/A 15.18 13.54 14.93 15.6 N/A Specific Cond. /A 41 33 87 26 N/A (u mhos/ccm) Turbidity(NTU) N/A 3.95 1.97 9.86 6.87 N/A I :15A N C-AC 02L.0,202 Groundwater Quality Standards PQL-Practical Quantitation Limit - ug/I-micrograms per later - - nmg/I-milligrams per liter S.U.-Standard Units, NTU-Nephelocmetric Turbidity unit 3 _ .:�",�: r1�„�•irrP6�p --� -t' p Y�'r y5 p'p +se ir' ''} ,�,'[' � JX ,r �a ,.';C f -ter_— � � IS \t �'"• `i" 'iv;m"� Y, r r•I ; 1, I`.?�.j)1, - S T x"� ,C_7 _ p� y t� '',, + s� '` AX ra< r'--�.- � '�.-!1"� 'C! ,t• a a. 1 \ 1 L t Ex16TING Fiat ,,�. ®" �: wETUNOs r MW 2A �'�t- �'„ _t zy •�'4- 210143 +4�5 — . �� _ �`�.- •® r'T �; r„�ay, t� >. f _ _ ♦ mow' I MW 1A r�it ^'t..,� '1+�Iq.i See/ ri..ram, '} •T. .. 'Yr�'- t ,, >,y.c,C,•�, �•3 I ti. °.• ,,,r ' ^.`, 2092 80 'r//�. !�%, tr ✓3 r 7 * 'd. s ' y \. -17 �-' � �`.- ', .Ir, � , `! �7`.♦} /F / /•�•l• -+r \� e:}• ` �f6 � ks u., w"'��F _'.-,.e � �-`..,g,+ 'sr '�.. .J � MW 5 ri7 e`RcvJ`'/ l t! '/./ ' i ON- 4 ` '' +, , ♦ X~♦♦ ♦ `�' • L��/- /FENCE - ' '` `o, ' m - ') •: PIP lit �TE �. — ♦ t r, n. o •, e r LEGEND a 1f: '' Q ." ���,i/ t i.•••�_ 4 1 ' /. MW-4A MONITORING WELL } 4`� 1 ; ♦ ?z. r^ ® 2128.95 WATER ELEVATION IN FEET(msl.) •„I �" It I • ♦ /" • '„r!+= s WATER LEVEL CONTOUR IN FEET(msl.) ► �. , E,�+"° z` y ' (2FT CONTOUR INTERVAL) ' �t 1 y!I .. ` ®�, ♦tee;a/-. ��•.••'0 I� .� ? j ; ® T ' � .......... COAL COMBUSTION PRODUCT LIM ITS } `� M1 _ - ♦ /^ O ` - �' —®——— REVIEW BOUNDARY COMPLIANCE BOUNDARY PROPERTY LINE APPROXIMATE 2128 95 SOURCES: % ' y® '� \'h „� - 2012 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAY AT � ® ® ® Tt� -.. i• hffpl/delegelewaYnrrs.usda.gov/ { ` _ _ _ ® ® - •.w £ WELL LOCATIONS,COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARYAND COMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING TITLED'GROUNDWATER FLOW MAP STRUCTURAL FILL',DATED I2-16-2010. GRAPHICSCALE r } c IGG o I00 200 PROGRESS ENERGY "~ • �T yy S 1n6RrvwsrnEEr.surcE zo STRUCTURAL FILL-AREA I �� GREENNLLE.SOUTHCAROLINA2 601 WATER LEVEL MAP-NOVEMBER,2012 • ,;� PHONE16-21A9l synTerl^ds lerraaurP.Pm a o.Ta ASHEVILLE REGIONAL AIRPORT ARDEN,NORTH CAROLINA Jt `"''�C��i`.sT � ' •'�tl�. Li t�"�4 '' J�i311' �� N"A ASHEVILLE REGIONAL AIRPORT 2102 43 . :..C+�, `• 9S " I y �,^ O �.F�.'il� � 1't I^_ -����+�'3"`',.r 1'I� •.�-{V'c��.,,:,'� �'. TON .tea t ' v i � y l COAL COMBUSTION 4 � PRODUCT LIMITS "�',� i d ' `! ��v� vI� MATE) .� �. t j I ` PPROXI # M W 1 �. ♦1 r t r! `PtpGE RD OFFICE�! •.� .\ - `�I'- FP At- T11* fj f r hWMW 44 „rSMALL CREEKS , AMAIN ENTRANCE �e': S : ` y .'• ;`.}.•, r"r` r �� 2058.88 �. / �6�RAY, 2 MYMW-5 �j. 2059.61 ' MW-5D -'WESTERN NORTH CAROLINA 2057 08 ' 11 AGRICULTURAL CENTER � � ✓s l;�r� t �t ✓ .r} r �+F' \� �� 11 � 'I. . \ � 1, -�:.y, - {;` t }�_�t 11 Y . rr. 1 + , MW-6 ,; `.`'r `i ray 2056 54 ' ,fit' -?OS. '� ( { , kt arr' d "� y_,� p•. Sit �.9��g�� ` R� r) ,i. I 5.%r' AWN � -�r��t � � °' t`a ��• �� �; ( i( 1 ' �;'�. 9 e�POJ d, s �(.. MW-9 air rP,fr _ k Fx •� , +a"" 2048.17 S f F - ..f'P• n. s5`1 I' r 7 4't yy. M F 4 r �+ �,,�• ��a r7s�3 F�F^ � T�5 f ,..� 'Y F .,�i�`x'Y '� ,- r;..✓ =-,ir t,y r;`', i. -i tZ'�.: *. y'l•. � ' � ��,(.,r trl'tt*��: '4 / �NN.pf1 �_�_��, �--�i r.J.r ` �'`�'!�'�,.R; a s, LEGEND MW-7 MONITORING WELL(SAMPLED) 2052.25 WATER LEVEL IN FEET(msl.) MW--8 MONITORING WELL(NOT SAMPLED) f �TE . SOURCES: ' 7r r� � S �?-w,� t� T:yam tr��.,j'lx 2012 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPATIAL DATA GATEWAY a r`^ + AT http://datagateway.nres.usda.gov/ - ALL WELLS SURVEYED EXCEPT MW-3 BYWNC PROFESSIONAL ENGINEERS& SURVEYORS ON APRIL 19,2012. GRAPHIC SCALE 300 0 300 600 PROGRESS ENERGY IN FELT STRUCTURAL FILL-AREA 4 VIP 148 RIVER STREET,SUITE 220 GREENVILLE,SOUTH CAROLINA 29601 WATER LEVEL MAP- NOVEMBER, 2012 PHONES64-421 wwwsynterracorp.com ASHEVILLE REGIONAL AIRPORT .com Terra DRAWN BY:JOHNCHASTAIN DATE:05/14/2012 ARDEN, NORTH CAROLINA PROJECT MANAGER:KATHY WEBS LAYOUT:WATER LEVEL MAP 12/10/201210:14AM P:\Progress Ener .102602.ASHEVILLE PIA 07.2012 Well sampling Structural Fill-Area 4 DWG PE ASHEVILLE STRUCTURAL FILL 4-WL MAP-201211.dw z rn C: m Ln C M. M m P aa cu L2r c m ro 0 m CL cu n. 42 m CD fu 0- CL fD . . . . . . . . . . . In Pa ro- CL Q. Ln Ln No m CP m C cLa e aQp- m Ln pr W Un Lj CD A A 171 Ln CA p P:- Ln I- a LU w cm Nj CD CL 1- iA Ln Z A A PA po PA < r-n Ln Kl N3 NI r13 Co Ln CD CD A -1 C:) LO C-P P�j Ln LA I_n Lu rr, Fn CO > .m cl PA PA PA !IJ LO 0 A EW " CD CD 0 00 �Q Ln L9 :M A A A A Uj Zjj V A A PA & n C-n CD ih 4 CDVt NJ w A A tQ A PA Cn a A Ln w Ln 0 r1a C:) -t Ln w A - Ln �o �a Na ca J CJt Fs a Un 00 rj Ln P Cn Fn Vi $- Ln w ul :�7 3;7 1� NJ ou County: BUNCOMBE e� 4 WAi? �r' Sample ID: AB89880 River Basin PONumber# 12GO998 a Report To AROAP ' i» Date Received: 11/15/2012 y� Time Received: 08:30 Collector: B LAVERTY u Labworks LoginlD HMORGAN Region: ARO r Final Report Date: 12/14/12 Sample Matrix: GROUNDWATER Loc.Type: MONITORING WELL Rhal Report Report Print Date: 12/20/2012 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT I Location ID: 1P11ASHEVILLEAIRPORTMWIA Collect Date: 11/13/2012 Collect Time: 12:14 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.8 C 11/15/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 50 U ug/L EPA'200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-38-3 Ba by ICP 10 17 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 2.8 mg/L EPA200.7 11/26/12 ESTAFFORD1 74,40-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11129/12 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/16/12 ESTAFFORDI 7440-09-7 KbyICP 0.10 0.82 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.8 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 IOU ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-23-5 Na by ICP 0.10 2.3 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium (TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed tlescriplion of the qualifier egtles refer to h<p ,ona ncd�nr orelwe6LwanagLfi�,,f./�ecn_ss�seiro_:r.�qu�i�flcr tones<nco:/Lpona..�_ncgen.,9.rg[.n�niwo/i, :_firm L:nassisn Page 1 of 2 ArC(I)WQ Ga6oratory Section Resufts Location ID: 1P11ASHEVILLEAIRPORTMW1A Sample ID: AB89880 Collect Date: 11/13/2012 Collect Time:: 12:14 MET CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments Metals,Thallium,J2 Qualifier, LFB Recovery'54%, LFM Recovery 41%. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp1LLr,Lncdenr,oralµeb/vygtWbf_caWa/ wst# 'ta qualifier Cotles<h:oa1 .grt,@,.ncdenr_ogfweh/v{g/la6fsiafnno/tcchassisb Page 2 of 2 County: BUNCOMBE WATtc Sample ID: AB89838 River Basin . r� PO Number# ARO Report To AROAP Date Received: 11/14/2012 F' Time Received: 09:10 Collector: 9 LAVERTY s Labworks LoginlD KJIMISON Region: ARO Final Report Date: 11/19/12 Sample Matrix: GROUNDWATER t t Loc.Type: MONITORING WELL FIn 1I Repolt" Report Print Date: 12/20/2012 Emergency,Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW1A Collect Date: 11/13/2012 Collect Time: 12:14 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalVte Name PQL Result/ Units Method AnalVsiS Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 0.2 °C 11/14/12 RBYRD Turbidity 1 1 U NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For adetailed-desen lion of the qualifier codes refer to ht //oor�l.ncdenco weblw,ll,h,.,f nh techass�stpD:rca tluafiftr C Aes�hto:// rtal dent o lr/ Ian s•finfto to h b ' P 9 —P` --��_.._a._a..L•-:,.__�s1__ _ Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW1A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 2 Date Received Time: Lat. Long. ❑ Other- Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 12:14 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.,o °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW1A Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L X Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cord.95 pMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X I Cr-Chromium 46559 u /L WAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L JcNi-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P1 1 AshevilleairportMW1 A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. El ElEmergency 2 Date Received Time: Lat. Long. El Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 12:14 PM Baseline, Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW1A Appearance DO, mg/L. ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) - BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /10oml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L IMBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L I Boron DOC Fe-Iron 46563 u /L I Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L I TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE V1 T Sample ID: AB89879 River Basin fr} PO Number# 12GO997 t7 G Report To AROAP Date Received: 11/15/2012 I Time Received: 08:30 Collector: B LAVERTY .+ Labworks LoginlD HMORGAN Region: ARID Sample Matrix: GROUNDWATER Final Report Date: 12/14/12 Loc.Type: MONITORING WELL Final Rep01't" '� Report Print Date: 1 212 0/2 0 1 2 Emergency Yes/No VisitlD CDC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW2A Collect Date: 11/13/2012 Collect Time: 13:18 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalVte Name PQL Result/ Units Method Anal sis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.8 °c 11/15/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-38-3 Ba by ICP 10 17 ug/L EPA200.7 11/26/12 ESTAFFORDI 7440-70-2 Ca by ICP 0.10 2.3 mg/L EPA200.7 1'1/26/12 ESTAFFORDI 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 68 ug/L EPA200.7 11/27/12 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/16/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 0.73 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.1 mg/L EPA200.7 11/26/12 ESTAFFORDI 7439-96-5 Mn by ICP 10 IOU ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.8 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium(TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp;((s:onal.ncdenrar(web(wgtiah[raf.n„Fg[techassl3 nort_qualifi.-:r Co,A.e,;<ncg:/!portal.n derv. veb�wglWb[rifinfe/mcy 1, Page 1 of 2 AV DWQ Laboratory Section ResuCts Location ID: 1P11ASHEVILLEAIRPORTMW2A Sample ID: AB89879 Collect Date: 11/13/2012 Collect Time:: 13:18 MET Result/ Method Analysis Validated by CAS# Analyte Name PQL Qualifier Units Reference Date Sample Comments Metals,Thallium,J2 Qualifier LFB Recovery 54%, LFM Recovery 41% I Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes,fe(ef l0 h2g;li.,�,orwl.n:denr aortal.n cenr.org/we&wgjlap[,rafi�figLcech_ssisD Page 2 of 2 County: BUNCOMBE Sample ID: UVAT,6 l A889839 River Basin O 4 3 PO Number# ARO Report To AROAP ' Date Received: 11/14/2012 Time Received: 09:10 Collector: B LAVERTY "C Region: LabworksLoginlD KJIMISON ARO t' t e Final Report Date: 11/19/12 Sample Matrix: GROUNDWATER Report Print Date: 12/20/2012 Loc.Type: MONITORING WELL .....RhAl lie ort Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW2A Collect Date: 11/13/2012 Collect Time: 13:18 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 0.2 °C 11/14/12 RBYRD Turbidity 1 1 U NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp:j[port;a,n denr. eblwolfab/aafinfio techassict#orta qualifi-r Codes<h g/(pona„L,n..cd..,nr,,orgy,bfw...q/.la..h[@, finnojc..�ehassian Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW2A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 3 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 1:18 PM Baseline, Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airpottcircleone) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW2A Appearance DO, mg/L ORP, mV - Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L X Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 946 mg/L X Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L X Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L xSe-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 cU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P1lAshevilleairportMW2A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe X Water(Ground Water) Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 3 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 1:18 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circleone) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.10 °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW2A Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitro en Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/1 Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fedron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46566 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH,as N 610 mg/L Na-Sodium 46556 m /L I TPH-Gasoline Range Bicarbonate 440 mg/L I TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L I NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE Sample ID: AB89878 River Basin PO Number# 12GO996 Report To AROAP � Date Received: 11/16/2012 Time Received: 08:30 Collector: B LAVERTY O Labworks LoginlD HMORGAN Region: ARO Sample Matrix: GROUNDWATER Final Report Date: 12/14/12 Loc.Type: MONITORING WELL ...... . Fihal'Report Report Print Date: 12/20/2012 Emergency Yes/No VisitlD COC Yes/No Loc.Deser.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW4A Collect Date: 11/13/2012 Collect Time: 14:38 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.8 °C 11/15/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 6.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 95 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-38-3 Ba by ICP 10 29 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 0.33 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11129/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-89-6 Fe by ICP 50 540 ug/L EPA200.7 11/27/12 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/16/12 ESTAFFORDI 7440-09-7 K by'ICP 0.10 0.97 mg/L EPA200.7 11/26/12 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.29 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 960 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 16 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium JI)ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ht.;....ort�I;n^denrar MetL1 flab�•afinfiohechassis,[aD.-,te ualifie cones<hm:/ orWl,ncdenco ',g6Iv lab aafinno[echassist> P 9 ......vll a. .- a._ s_L_ .._4-.'--..-......_-1e_..._.--�L__._aL�_=1.__..........-._. Pagel of 2 9VC(DWQQ La6oratory Section Results Location ID: 1P71ASHEVILLEAIRPORTMW4A Sample ID: AB89878 Collect Date: 11/13/2012 Collect Time:: 14:38 MET CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments J2 QUALIFIER USED DUE TO HCL INTERFERENCE DURING DIGESTION PROCESS. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp1 7orr�l.n^.derv,.rg(_w„e¢[v_�/g 1�6[::.�fiq@.oj;echa_s�stitoata Q,�,allfirr C,oAes<_h_q.//oortal.ncd;.nr.ore/webl'kq/lah(s<,.fmfl.�[I,chassisb Page 2 of 2 County: BUNCOMBE bg'MA Sample ID: AB89840 River Basin a `'� ' PO Number# ARO Report To AROAP aj Date Received: 11/14/2012 d Time Received: 09:10 Collector: B LAVERTY Region: ARID 4 _. Labworks LoginlD KJIMISON Final Report Date: - 11/19/12 Sample Matrix: GROUNDWATER _ r Loc.Type: MONITORING WELL ' Flna� RepOrt�r", Report Print Date: 12/20/2012 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW4A Collect Date: 11/1 312 0 1 2 Collect Time: 14:38 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis Validated by CAS# Analyte Name PQL Qualifier Units Reference Date Others Sample temperature at receipt by lab 0.2 °c 11/14/12 RBYRD Turbidity 1 1.5 NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to hto://=W.n.ncdPnr or e LmAakil.z- chassst#Data gnaliher Codes<hcoa/nortal.nceenuorettveb/wa/lanisiaFnflo/techassisn Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW4A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 4 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 2:38 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW4A Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOO 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /loom) Phenols 32730 ug/I xCa-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 - mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L xNi-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L X Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 cU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW4A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe X Water(Ground Water) DO Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 4 Date Received Time: Lat. Long. ❑ Other Redd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 2:38 PM Baseline, Complaint, Compliance,LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW4A Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /l ooml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L I Boron DOC Fe-Iron 46563 u /L I Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L I TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L INitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival (°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. 14 z�a 7on�cl County: BUNCOMBE WA7 � Sample ID: AB89881 River Basin r t PO Number# 12GO999 Report To AROAP ra q Date Received: 11/16/2012 4 ' I Time Received: 08:30 Collector: B LAVERTYed i 'r 7 S a Labworks LoginlD HMORGAN Region: ARO T g Final Report[late: 12/17/12 Sample Matrix: GROUNDWATER ` .e Report Print Date: 12/20/2012 Loc.Type:' MONITORING WELL Flhaf RepOPt Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW5 Collect Date: 11/13/2012 Collect Time: 10:60 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.8 °C 11/15/12 HMORGAN MET 7440-22=4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 AI by ICP 50 140 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 27 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 0.47 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 13 ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 190 ug/L EPA200.7 11/27/12 ESTAFFORD4 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 11/16/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 0.68 mg/L EPA 200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.0 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 69 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-23-5 Na by ICP 0.10 1.3 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 6.9 ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-28-0 Thallium (TI)ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 21 ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp;(f�ortal,;,n,"-de.- -b pab,t FnF,:gJtechassist#Data 4ualifier Co,A„es„<htp:(�por 1-denra, ek,Nia/1abLr�fin o[fechae;sb Page 1 of 2 NC DWQ Laboratory Section Wsults Location ID: 1P11ASHE%ALLEAIRPORTMW5 Sample ID: AB89881 Collect Date: 11/13/2012 Collect Time:: 10:50 MET Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by Sample Comments Metals, Thallium,J2 Qualifier, LFB Recovery 54%, LFM Recovery 41%. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to neR:[[.porn!.deter.or�k.�e[.,.g[ianlrtaflniro/cecnass�scueac,�c,minor codes Mp_/[.p.prt.—,d nr.o.e/.wenlwq/ian[r Fn3a[mms51sh Page 2 of 2 County: BUNCOMBE 04yq� � Sample ID: AB89837 River Basin ,, ' Q PO Number# ARO Report To AROAP .° Date Received: 11/14/2012 Time Received: 09:10 Collector: B LAVERTY Labworks LoginlD KJIMISON Region: ARO Final Report Date: 11/19/12 Sample Matrix: GROUNDWATERzw Loc.Type: MONITORING WELL n6 j F:t ort Report Print Date: 12/20/2012 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW6 Collect Date: 11/13/2012 Collect Time: 10:50 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 0.2 °C 11/14/12 RBYRD Turbidity 1 2.1 NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description ofthe qualifier caries referto htp;11 arty'_ncdenrJor; b/wgAabl3?afi.nflltechassscacrta.Cii,alificr cones<nxo:i.onal.n:denr. v_eg[w.gLah[st figsoL=cnassisn. Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P1 1 AshevilleairportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe I� Water(Ground Water) Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat. Long. ❑ Other (D Redd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier; Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 10:50 AM Baseline, Complaint, Comoliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.10 °C Odor Description of sampling point:Area 1 structural fill—monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: Monsoon pump Sample Interval Field Analysis By: _ Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 535 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle 1 Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range — Bicarbonate 440 mg/L TKN as N 625 mg/L X Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/ NH4-ammonium Silica Temperature on arrival(IC): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS'in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1P11AshevilleairportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe DC Water(Ground Water) X Routine Lab Number El Soil El Emergency Quad No Serial No. Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 10:50 AM Baseline, Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 251C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo IC Odor Description of sampling point:Area 1 structural fill—monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: Monsoon pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335- mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 Mooml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/1 Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE d �pA � Sample ID: AB89973 River Basin PO Number# 12GIO17 Report To AROAP 3c Date Received: 11/16/2012 "1 Time Received: 08:00 Collector. J STEPP P <' Region: ARO _ i Labworks LoginlD HMORGAN ` Final Report Date: 12/14/12 Sample Matrix: GROUNDWATER :x Report Print Date: 01/15/2013 Loc.Type: MONITORING WELL Final Report Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: IP11ASHEMLLEAIRPORTMWlA Collect Date: 11/1 412 01 2 Collect Time: 10:01 Sample Depth if this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 2.1 C 11/16/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 630 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 22 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 3.7 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 45 ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-89-6 Fe by ICP 50 580 ug/L EPA200.7 11/27/12 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/28/12 ESTAFFORDI 7440-09-7 KbyICP 0.10 1.7 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 2.1 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 74 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 2.8 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 23 ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium (TI)ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 13 ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htoi/!cortal.ncde.nr.ore/weh blstafinfio/tec„hasslstkD-iT Qualifier Codes ahto://aortal.ncdencore/web/wu/Wb/staBnfio/tech�ssisb Page 1 of 2 NC D WQ Laboratory Section Res its LocationlD: 1P11ASHEVILLEAIRPORTMWlA Sample ID: AB89973 Collect Date: 11/14/2012 Collect Time:: 10:01 MET CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments Metals,Thallium, J2 Qualifier, LFM Recovery 54%, LFB 41%. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to hto://oor�al.ncdPnr,.or,�(wen/w.4lian(siabnflo as��stpDna ouatirer.Conga.<nso://norcal—de—or wen/w/Wn nafinfllrncn Ls a Page 2 of 2 r-, County: BUNCOMBE tflFATF sample ID: AB89899 River Basin �O . QG PO Number# ARO Report To AROAP ; Date Received: 11/15/2012 y Time Received: 09:00 Collector: J STEPP Labworks LoginlD KJIMISON Region: ARO Final Report Date: 11/19/12 Sample Matrix: GROUNDWATER Loc.Type: MONITORING WELL Final Report Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONALAIRPORT Location ID: 1P11ASHEVILLEAIRPORTMWlA Collect Date: 11/14/2012 Collect Time: 10:01 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalVte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date Others Sample temperature at receipt by lab 4.0 °C 11/15/12 RBYRD Turbidity 1 11 NTU APHA213013-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp://ooftaLncdenr.orgLiveb�Lb(„„�ra$nfi�Lechassstl(para�ugLflp,Coal h-./portaLncdenr.orvJweh/w flah soiflnfiojtec„hessisb. Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1P11AshevilleAirport_MW1A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe �I Water(Ground Water) DO Routine q Lab Number Quad No Serial No. ❑ Soil ❑ Emergency I Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., El Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Jonathon Stepp Date: 11/14/2012 Time: 10:01 AM Baseline, Complaint, Compliance,11-ISle e, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Regional Airport pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point: Area 4 structural fill—monitoring well MW1A Appearance DO, mg/L ORP, mV Sampling Method: peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46561 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46568 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L XNi-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 •mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X n-Zinc 46567 uci/L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE � � Sample ID: AB89877 River Basin * PO Number# 12GO996 Report To AROAP Date Received: 11/16/2012 I ; Time Received: 08:30 Collector: B LAVERTY Labworks LoginlD HMORGAN Region: ARO Final Report Date: 12/14/12 Sample Matrix: GROUNDWATER Report Print Date: 01/15/2013 Loc.Type: MONITORING WELL Fin"-a� Report Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW2 Collect Date: 11/13/2012 Collect Time: 15:48 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalVte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.8 'C 11/15/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 Al by ICP 50 70 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 15 ug/L EPA200.7 11/26/12 ESTAFFORDI 7440-70-2 Ca by ICP 0.10 0.89 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/16/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 0.90 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.2 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 IOU ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 2.4 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-28-0 Thallium (TI)ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htpj. orb�wcbjwyian/siafinfiohech,�ssstae=.ca quaiirer co�?es.,<n;.a;[(�ortai nc_denr.ora/wenivrq/lao s.afl�no/cecnassjsn Page 1 of 2 NC(D WQ Laboratory Section W§sufts Location ID: 11311ASHEVILLEAIRPORTMW2 Sample ID: AB89877 Collect Date: 11/1 312 0 1 2 Collect Time:: 16:48 MET Result/ Method Anal sis Validated by CAS# Analyte Name PQL Qualifier Units Reference Date Sample Comments J2 QUALIFIER USED DUE TO HCL INTERFERENCE DURING DIGESTION PROCESS. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ntp,[[_p_orrolncd„Gnr,.or, web/w_gLap/^afinfio/techapvs[noa?a Qualifier Codes<hio:J[portahn^dery Drab+reb/wo/lab/ttafinno�te<hassiso Page 2 of 2 12CilDWO Laboratory Section Wes,.. y County: BUNCOMBE bPV+lp17FA Sample ID: AB89841 { River Basin O QG PO Number# ARO Report To AROAP t7' �' Date Received: 11/14/2012 r: 1 Collector: B LAVERTY f3 Time Received: 09:10 Labworks LoginlD KJIMISON Region: ARO i Final Report Date: 11/19/12 Sample Matrix: GROUNDWATER Report Print Date: 01/15/2013 Lac.Type: MONITORING WELL Finai'Re06rt Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW2 Collect Date: 11/13/2012 Collect Time: 15:48 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 0,2 °c 11/14/12 RBYRD Turbidity 1 1.0 NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description ofthe qualifiercodes referto n:p:!{norcaisp4enr.orz/web ls.dab sngnglSe�hass @Dn,Quaiiesr codes<n�p ponai.ncde L! iab tt=�,o/recnass�sn Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW2 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 5 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed. Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 3:48 PM Baseline, Complaint, Compliance( LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 4 structural fill—monitoring well MW2 Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46666 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ugh X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X n-Zinc 46567 u /L Color:True 80 cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival (°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW2 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water Ground Water Routine I� ( ) � Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 5 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 3:48 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.10 eC Odor Description of sampling point:Area 4 structural fill—monitoring well MW2 Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /loom[ Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100m[ Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC I Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. ,n County: BUNCOMBEAT� Sample ID: AB89876 River Basin �Q PO Number# 12G0994 Report To AROAP ?; Date Received: 11/15/2012 B LAVERTY Collector. C3 { Time Received: 08:30 Labworks LoginlD HMORGAN Region: ARO R Sample Matrix: GROUNDWATER Final Report Date: 12/14/12 V Report Print Date: 01/1'5/2013 Loc.Type: MONITORING WELL � FInB� Re�Ort`�.' ' Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW5 Collect Date: 11/1 312 01 2 Collect Time: 17:02 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis_ Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.8 °C 11/15/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 742940-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 69 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 3.9 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 66 ug/L EPA200.7 11/27/12 ESTAFFORD1 - 7439-97-6 Hg 245.1 0.2 0..20 U ug/L EPA245.1 11/16/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 1.7 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.4 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 15 ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-23-5 Na by ICP 0.10 3.9 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-28-0 Thallium (TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to h�L,orc,nodenrpr A b../y{yla afinfioLtech�ssrstnDzca Qualifier Cotles<hco://�ortaln_denr.org(w�b wf�i llablsu finfio(techassisb Page 1 of 2 NC O WQ Laboratory Section Wysufts Location ID: 1P11ASHEVILLEAIRPORTMW6 Sample ID: AB89876 Collect Date: 11/13/2012 Collect Time:: 17:02 MET CAS# AnalVte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments Sample qualified because HCL interferance from digestion process. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ham://corL,Lrdenr.orz/:vebl_q!lab[.afinf o�_hassisteo�,t„a..gga„I„ifi..r C,o„nes<n*. p.rW,.-do-Tr„. (w.eL y/l, s afi�na[recnassjsn Page 2 of 2 Lai6oratorySectim County: BUNCOMBE IVATi� Sample ID: ABB9842 River Basin �� QG PO Number# ARO Report To AROAP r Date Received: 11/14/2012 y _ s Time Received: 09:10 Collector: B LAVERTY Region: ARO Labworks LoginlD KJIMISON Sample Matrix: GROUNDWATER Final Report Date: 11/19/12 Loc.Type: MONITORING WELL Final Report Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW5 Collect Date: 11/1 312 01 2 Collect Time: 17:02 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# AnalYte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 0.2 °c 11/14/12 RBYRD Turbidity 1 1 U NTU APHA21308-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp,[[_poM].ncd„gnLrz/web/wc1lab/,nafinfiyLha_stgD atp„_gualifi=r cotles<h-11�ortai.ncee.�;re/web/�/lan(_c af[af..9 recnass�on Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1P11AshevilleairportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 6 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To: ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 5:02 PM Baseline, Complaint, Co LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport kullulu one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.10 IC Odor Description of sampling point:Area 4 structural fill—monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L X Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm x Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X n-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code:1 P11AshevilleairportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Do Water(Ground Water) DC Routine Lab Number El Soil El Emergency Quad No Serial No. Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., El of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 11/13/2012 Time: 5:02 PM Baseline, Complaint, Comjpliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner:Asheville Regional Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point:Area 4 structural fill—monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: Peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46568 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L X Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments - GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. - Laboratory- County: BUNCOMBE V4/bT�� Sample ID: AB89975 River Basin O QG PO Number# 12G1019 Report To AROAP Date Received: 11/16/2012 I' Time Received: 08:00 Collector: J STEPP '< Labworks LoginlD HMORGAN Region: ARID Sample Matrix: GROUNDWATER Final Report Date: 12/14/12 Loc.Type: MONITORING WELL Final-Report Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT MWSD Location ID: 1P11ASHEVILLEAIRPORTMW5D Collect Date: 1111 4/2 01 2 Collect Time: 12:28 Sample Depth if this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 2.1 °C 11/16/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 690 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5. B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-38-3 Ba by ICP 10 32 ug/L EPA200.7 11/26/12 ESTAFFORDI 7440-70-2 Ca by ICP 0.10 6.8 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.3 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-89-6 Fe by ICP 50 840 ug/L EPA200.7 11/27/12 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/28/12 ESTAFFORDI 7440-09-7 K by ICP 0.10 1.9 mg/L EPA200.7 11/26/12 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 1.9 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 21 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 6.5 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium (TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 '11/29/12 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codas refer to htp1!_l:oa- , _. �iass� p a Qualifie eodes<tLnderareeb[�I�h/tfinno/ehassisoJa Page 1 of 2 NC(DWWQ Gafioratory Section Results Location ID: 1P11ASHEVILLEAIRPORTMWSD Sample ID: AB89976 Collect Date: 11/14/2012 Collect Time:: 12:28 MET CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments Metals,Thallium, J2 Qualifier, LFB Recovery 54%, LFM Recovery 41%. a Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp:/I nortai.n;denr.ore/web/wnAablra8nfio/rechass¢tNgata_�acfier codes<h—//norcai.ncderr.ore/web/wnAah/c:afingahecha9slsb Page 2 of 2 County: BUNCOMBE VA Sample ID: A1389900 River Basin d �? PO Number# ARID Report To AROAP -O r Date Received: 11/15/2012 Collector: J STEPP a "i Time Received: 09:00 Region: ARO Labworks LoginlD KJIMISON Sample Matrix: GROUNDWATER Final Report Date: 11/19/12 Loc.Type: MONITORING WELL Final R@pOft Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT Location ID: 1P11ASHEVILLEAIRPORTMW5D Collect Date: 11/14/2012 Collect Time: 12:28 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analvte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date Others Sample temperature at receipt by lab 4.0 °C 11/15/12 RBYRD Turbidity 1 11 NTU APHA2130B-20th 11/15/12 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed desorption of the qualifier codes refer to ht: onei.oceeor.ore/menLym iagL afi re?h_,csistgpsca Qualifier[oAes<htoa/portaLncdenr.ere/we g/I,a„A(ttafi�fip techazsisb Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1 P11AshevilleAirport—MW5D SAMPLE TYPE SAMPLE PRIORITY County: Buncombe X Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 3 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Jonathon Stepp Date: 11/14/2012 Time: 12:28 PM Baseline, Complaint, Compliance(,.LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Regional Airport role pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.10 °C Odor Description of sampling point: Area 4 structural fill—monitoring well MW5D Appearance DO, mg/L ORP, mV Sampling Method: peristaltic pump Sample Interval Field Analysis By: Remarks _ LABORATORY ANALYSES (Pumping time,air temp.,eta.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum,46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I X.Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L XSe-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments Please add antimony and thallium , GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. 3 y } (DWO Laboratory Section . _�' County: BUNCOMBE ` tY ;� �ryxq � a Sample ID: AB89977 River Basin , Q PO Number# 12GI021 Report To AROAP Date Received: 11/16/2012 Time Received: 08:00 Collector: J STEPP C3 Region: ARIDa { Labworks LoginlD HMORGAN r ` cAR' Final Report Date: 12/14/12 Sample Matrix: GROUNDWATER Loc.Type: MONITORING WELL - "FI11a� Rep01 Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASH EVILLE REGIONAL AIRPORT MW6 Location ID`. 1P11ASHEVILLEAIRPORT_MW6 Collect Date: 11/14/2012 Collect Time: 15:04 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date Validated by LAB Sample temperature at receipt by lab 2.1 °C 11/16/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 Al by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-36-0 Antimony by ICPMS 10 10 U ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 25 ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 2.5 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/28/12 ESTAFFORD1 7440-09-7 KbyICP 0.10 0.98 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.1 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 10 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-23-5 Na by ICP 0.10 2.9 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-28-0 Thallium(TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 '10 U ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 Fora detailed description ofthe qualifier codes refer to ht orwLdenr,.qrg[weblyrg/IanLifinFa(„tech,issjstftat_Qualifier Codes<h>.n:/[portal_ncden-!FLeb/ ilhp'gtafin.2G_c giksb Page 1 of 2' NC DWQ Ga6oratorySection Results Location ID: 1P71ASHEVILLEAIRPORT_MW6 Sample ID: AB89977 Collect Date: 11/14/2012 Collect Time:: 16:04 MET CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Sample Comments Metals,Thallium,J2 Qualifer, LFB Recovery 54%, LFB Recovery 54% Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ht;j/norr�i._n d,�r.ore/weti�wo/Ian/ss�nnfioRechas5istgData..qualifier codes<hro://o;naL cdp_re/—b(wa/lab[ttaflnngL<has„sjso Page 2 of 2 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1P11AshevilleAirport—MW6 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 5 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Jonathon Stepp Date: 11/14/2012 Time: 3:04 PM Baseline, Complaint, Compliance(�iL�USle e, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Regional Airport pH aoo Spec. Cond,94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.,to °C Odor Description of sampling point: Area 4 structural fill—monitoring well MW6 Appearance DO, mg/L ORP, mV Sampling Method: peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitro en Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L x Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /1 ooml Phenols 32730 ug/I X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L X Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L xPb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments::5 Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE r � Ar s Sample ID: AB89976 River Basin a ? E PONumber# 12G1020 Report To AROAP v s2, 3' 't Date Received: 11/16/2012 Collector. J STEPP "1 Time Received: 08:00 Labworks LoginlD HMORGAN Region: ARO Sample Matrix: GROUNDWATER r'r Final Report Date: 12/14/12 Loc.Type: MONITORING WELL FIf13� Report Report Print Date: 01/15/2013 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT MW7 Location ID: 1P11ASHEVILLEAIRPORT MW7 Collect Date: 11/14/2012 Collect Time: 14:01 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analvte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 2.1 °C 11/16/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 Al by ICP 50 82 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORD1 7440-38-3 Ba by ICP 10 26 ug/L EPA200.7 11/26/12 ESTAFFORDI 7440-70-2 Ca by ICP 0.10 0.10 U mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/28/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 0.51 mg/L EPA200.7 11/26/12 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 0.35 mg/L EPA200.7 11/26/12 ESTAFFORD1 7439-96-5 Mn by ICP 10 IOU ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 0.86 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-28-0 Thallium(TI) ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORD1 7440-66-6 Zn by ICPMS 1.0 IOU ug/L EPA200.8 11/29/12 ESTAFFORD1 Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ht:H o.ft,,l cdenn jyjb/v,.yllab[raFntijtecbassstno a q aiifier eoaes<h;o:U oorcal.ncdenr.ora/web ,Lsufinno i-,chassiso Page 1 of 2 5VC D WQQ Laboratory Section Results Location ID: 1P11ASHEVILLEAIRPORT_MW7 Sample ID: AB89976 Collect Date: 11/14/2012, Collect Time:: 14:01 MET Result/ Method Analysis Validated by CAS# Analyte Name PQL Qualifier Units Reference Date Sample Comments Metals,Thallium,J2 Qualifier, LFB Recovery'54%, LFM Recovery 41%. Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 Fora detailed description of the qualifier codes refer to„htp.././..nsrr,,n-denr.otz/webl. JA b/^;»nf;o tecnass�st qte,,.g�ati@er cods«h:olQporta�.nmenrarp,Liv=nn/wgL,stafinn'oftecha_o Page 2 of 2 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1 P11AshevilleAirport—MW7 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe X Water(Ground Water) Routine Lab Number El soil El Emergency Quad No Serial No. Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., El Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Jonathon Stepp Date: 11/14/2012 Time: 2:01 PM Baseline, Complaint, Compliance,,,LUo e, Pesticide Study, Federal Trust, Other: FIELD ANALYSES _ Owner: Asheville Regional Airport pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point: Area 4 structural fill—monitoring well MW7 Appearance DO, mg/L ORP, mV Sampling Method: peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L X Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /loom] Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /loom] Phenols 32730 ug/I X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L X Boron DOC X Fedron 46563 u /L Semivo]atile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH,as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L xPb-Lead 46564 u /L Chloride 940 mg/L P:-Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3as N)620 mg/L xZn-Zinc46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg NH4-ammonium Silica Temperature on arrival(IC): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE Sample ID: AB89974 River Basin �� {} PO Number# 12G1018 Report To AROAP Date Received: 11/1 612 0 1 2 a ,R Time Received: 08:00 Collector: J STEPP 6=a Labworks LoginlD HMORGAN Region: ARO Final Report Date: 12/14/12 Sample Matrix: GROUNDWATER �' s Report Print Date: 01/15/2013 Loc.Type: MONITORING WELL FI118� Reg01t Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE REGIONAL AIRPORT MW9 Location ID: 1P11ASHEVILLEAIRPORT MW9 Collect Date: 11/14/2012 Collect Time: 11:13 Sample Depth If this report is labeled preliminary report,the results have not been validated. Do not use for Regulatory purposes. CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 2.1 °c 11/16/12 HMORGAN MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7429-90-5 AI by ICP 50 110 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-36-0 Antimony by ICPMS 10 IOU ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7429-90-5 B by ICP 50 50 U ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-38-3 Ba by ICP 10 IOU ug/L EPA200.7 11/26/12 ESTAFFORD1 7440-70-2 Ca by ICP 0.10 7,0 mg/L EPA200.7 11/26/12 ESTAFFORDI 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-47-3 Cr by.ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7439-89-6 Fe by ICP 50 110 ug/L EPA200.7 11/27/12 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 11/28/12 ESTAFFORD1 7440-09-7 K by ICP 0.10 1.7 mg/L EPA 200.7 11/26/12 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 2.2 mg/L EPA200.7 11/26/12 ESTAFFORDI 7439-96-6 Mn by ICP 10 21 ug/L EPA200.7 11/27/12 ESTAFFORDI 7440-23-5 Na by ICP 0.10 6.9 mg/L EPA200.7 11/26/12 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 11/29/12 ESTAFFORD1 7782-49-2 Se by ICPMS 5.0 5.0 U, ug/L EPA200.8 11/29/12 ESTAFFORD1 7440-28-0 Thallium (TI)ICPMS 10 10 U J2 ug/L EPA200.8 11/28/12 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 11/29/12 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description or the qualifier codes refer to htpj[_ort _den,rog(web/wgLab suNinfiLahassi;jNp,.,(_a_,,,Qualificr Codes<hm://aortal.ncdenr�ore[wehivq/IahL:*_fnfi L�,ch�ssi5b Page 1 of 2 NC(DrWQ,La6oratory Section W§sufts Location ID: 1P11ASHEVILLEAIRPORT_MW9 Sample ID: AB89974 Collect Date: 11/14/2012 Collect Time:: 11:13 MET Result/ Method Analysis CAS# Analyte Name PQL Qualifier Units Reference Date validated by Sample Comments Metals,Thallium,J2 Qualifier, LFB Recovery 54%, LFB Recovery 41% Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description oft he qualifier codes refer to_hta .�grt_I;ncde_ wetiA4q(�ab'stafinF.q(tech,Tssjstao�ta gualifi=r Codes<htoa/port_a,1,ncdenr_arpj„w,,,rb(�_vg/„latr(s-afi Lchassisb Page 2 of 2 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1P11AshevilleAirport—MW9 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe I%J Water(Ground Water) OC Routine Lab Number El Soil El Emergency Quad No Serial No. 2 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Jonathon Stepp Date: 11/14/2012 Time: 11:13 AM Baseline, Complaint, Compliance r�i LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Regional Airport pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher, NC Temp.lo °C Odor Description of sampling point: Area 4 structural fill—monitoring well MW9 Appearance DO, mg/L ORP, mV Sampling Method: peristaltic pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 336 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I X Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L IMBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L X Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units X K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 666 mg/L X Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(eC): Lab Comments:::f Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS°in block. � C IVE 23 2 ����' 2012 Progress Energy Certified Mail: 7007 2680 0000 1189 3031 Asheville Regional Office ui$eC Ps'®dG922 File Pt.: 12520-Q May 22,2012 Mr.G.Landon Davidson NC DENR/DWQ Aquifer Protection Section 2090 U.S. 70 Highway Swannanoa,NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Area I Fill Project April 2012 Groundwater Monitoring Results Dear Mr.Davidson: Attached are results from the sixth semi-annual groundwater monitoring sampling event, conducted on April 11, 2012, of wells near the Area I coal ash structural fill at the Asheville Regional Airport. Also attached is a groundwater contour map as prepared by SynTerra Corp. for this sampling event. Sampled were down-gradient wells MW-lA,MW-2A and MW-5 along with up-gradient well MW-4A(for reflecting ambient conditions). All of these wells are located within the compliance boundary around the Area I ash fill project. The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Iron Manganese Groundwater 6.5—8.5 300 50 Quality Standard (u l) MW-1A 5.7 --- --- MW-2A 5.9 --- --- MW-4A 5.1 349 1,070 MW-5 1 5.0 311 64.8 All results from this sampling event are summarized on the following page. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. Note that the next sampling event is scheduled for November 2012. Sincerely, y � Garry A. Whisnant Asheville Plant Manager Attachments Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 � � ospR Davidson Letter - May 22,2012 Results from Sampling Event nu April ll,2Ol2 Parameter .0202 Limit Well MWAA Well MW-2A ,Well MW-4A Well MW-5 PQL - - ' — 154NC4CO2L.0202 Groun.d»voter Quality-Standards _ . _ ___ PDL- PracUcaKOuantitationLj/nit � | :ug'| . ��mg/ _�n8| per|iter___- S.[L-Standard Units 'NTU' Nar he|omne �trcTurbi� Unit _ --_--_ ' 2 w. M a� � to , MW 1A �s � �+�"Y"'����x�'`�� /, o— 77 �"+���� > �� �- �i £:,'� � ..Z:.. �,'� � ��y< , •wt '� � ._. � # ~1 -,-,., t /a �I � k/ a♦� l $ "ft y e� >3s .' or i. .w- ^�„� �.." ���t /� 1/� �p`♦� 5•�. - • �!'�� ..,E q� r , C `:I �`. "^a"°'S i ^.�.- - .pi ♦♦I ° - 8"'l �.4'.. ,'"., 4 :.,..-•;'t ,,,r a t .y �210888�` F�! �`�` ��\ r�� !� /d �'� i e• �\ \N �Y_jq h�2 / s - "•A h I 2 ® y4 ~ .ter t •.r f Y.I, r v ; , , —_'���ryo �' ♦: t; It � e .-_ '"Iy �" a ,:� '♦ �o`� !�'•I tiw •'fir ��r $ �x �� �y �,, � + _` � �,`�'�• �` I � I e -.'♦ - O � 11 �.� �` r- ,�;,y`; Fri o Ilk .- � - ■♦ "i �,- i i ®: ��r\ t, � r, 13`� try'"-`^� k - t f i 1 a� ,t o / - • ,� °. n z,v ` TL ��3 : '„4''. u - t r.,' •` 1 ., /, • _ s LEGEND 1 > `45 �, `� ! �• • i ))\`� s :5 MW-4A MONITORING WELL • ee f •e � � � � ® 2129.53 WATER ELEVATION IN FEET FEE `` ! .• by WATER LEVEL CONTOUR IN FEET(msl.) (2FT CONTOUR INTERVAL) y ; 4 `fie ♦♦ � _--- .......... COAL COMBUSTION PRODUCT LIMITS t � ,� "`• !_,�..,.-- �- .-"' ,�,, ;/?} fin. � �3„�'*. REVIEW BOUNDARY -,i COMPLIANCE BOUNDARY PROPERTY LINE(APPROXIMATE) I ( MW 4A _ ,�, r, Y soueces: 4 �'� • 2129 53 ;' ® 1 y ,�,1 ty;,'�'f°`•+ 2010 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAY AT •0.Yi httpl/datagetawaynrcs.usda gov/ ¢ �� 1 } #� i,� Oi�. Jk{�"� Y1 \ t ('��• WELL LOCATIONS,COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARYAND COMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING TITLED'GROUNDWATER FLOW �w t t �' i t , �tJ� i•— �� �—;� - ,i MAPSTRUCTURAL FILL",DATED I2-16-2010. GRAPHIC SCALE oU o OO zoo PROGRESS ENERGY } / 4 tW may N FEET G48RwEa STREET SUITE 22o STRUCTURAL FILL-AREA REENVIUE SOUTH CAROUNA29601 WATER LEVEL MAP-APRIL 11,2012 14�� PHONE 8644219999 iMy �esY°ePa=°,P=°m °. ASHEVILLE REGIONAL AIRPORT IN na M } ° °n° ARDEN,NORTH CAROLINA ` - R ECEIVED Progress Energy Y �0 26 � [AshevilleRegional Ofeicc, Certified Mail: 7010 0780 0000 6613 2474 Protection File Pt.: 12520-Q May 29, 2012 Mr. G. Landon Davidson NC DENR/DWQ Aquifer Protection Section 2090 U.S. 70 Highway Swannanoa,NC 28778 RE: Asheville Steam Electric Plant Asheville Airport Area IV Fill Project April 2012 Groundwater Monitoring Results Dear Mr. Davidson: Attached are results from the first semi-annual groundwater sampling event, conducted on April 19, 2012, of wells near the Area IV coal ash structural fill at the Asheville Regional Airport. All of these wells are located within the compliance boundary around the Area IV ash fill. Also attached is a groundwater contour map as prepared by SynTerra Corp. for this sampling event. Sampled were down-gradient wells MW-2, MW-5, MW-5D, MW-6, MW-7 and MW-9 along with up-gradient well MW-lA (for reflecting ambient conditions). The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Chromium Iron Manganese Groundwater 6.5 —8.5 10 300 50 Quality Standard (ug/1) MW-lA 5.8 --- --- 117 MW-2 5.4 --- 745 --- MW-5 5.3 --- --- --- MW-5D 6 --- --- --- MW-6 5.6 --- 341 --- MW-7 5.2 --- --- --- MW-9 1 6.3 17.7 376 176 Also included in this report are the boring logs and well construction records (DENR Form GW-lb) for the wells around the Area IV structural fill. The table below includes the surveying information for these wells. Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter May 29,2012 Top of PVC Ground Well Northing Easting Casing Elevation Well Location Elevation (ft) ft MW-lA 631,462.82 944,901.02 2,136.19 2,134.19 Background MW-2 629,920.28 944,436.90 2,076.56 2,074.46 Review Boundary MW-5 (Formerly 629,395.45 944 832.59 2,068.31 2,066.18 Review Known as Boundary PZ-4) MW-51) 629,386.39 944,842.05 2,069.75 2,067.13 Review Boundary MW-6 628,967.08 945,202.85 2,074.01 2,070.69 Review Boundary MW-7 6285489.87 945,512.01 2,071.37 2,069.20 Review Boundary MW-9 627,830.32 945,932.12 2,059.15 2,057.15 Review Boundary Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. The next sampling event for Area IV ash fill is scheduled for November 2012. Sincerely, AL-0- /j /�- Garry A. Whisnant Asheville Plant Manager Attachments 2 r DENR Davidson Letter May 29,2012 Results from Sampling Event on April 19, 2012-Area IV Structural Fill Parameter .0202 Limit MW-IA MW-2 MW-5 MW-51) MW-6 MW-7 Mlh!-9 PQL Antimony(ug/1) 1 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <:0.5 0.5 Arsenic(ug/1) 10 <5 <5 <5 <5 <5 <5 <5 5 Barium (ug/1) 700 1S.2 21.6 120 20.1 25.1 24 8.8 5 Boron(ug/1) 700 <50 <50 <50 -50 <50 <50 <50 50 Cadmium (ug/1) 2 <:0.08 <0.08 <0.08 <:0.08 <0.08 <0.08 <0.08 0.08 Chloride(mg/1) 250 <5 <5 26.9 <5 <5 <5 <5 5 Chromium(ug/1) 10 <5 <5 <5 <5 <5 <5 17.7 5 Copper(mg/1) 1 <:0.005 <0.005 <0.005 <0.005 <0;005 <0.005 <.-0.005 0.005 Van (ug/1) 300 263 745 1"11 221 341 72 376 .50 Lead (ug/1) 15 <_5 <5 l5 <5 <5 <5 <5 5 Manganese(ug/1) 50 117 11.5 19.8 36 6.5 6.5 176 5 Mercury(ug/'l) 1 <0.2 <:0.2 <0.2 <0.2 <0.2 <0.2 <:0.2 0.2 Nickel(ug/1) 1.00 <5 <5 <5 <5 <5 <5 26.3 5 Nitrate(as N)(mg/1) 10 3.7 <:0.2 1.1 0.96 <0.2 <0.2 0.73 0.2 Selenium (ug/I) 20 <.10 <:10 <10 <:10 <:10 <:10 <:10 10 Sulfate(mg/1) 250 <5 <5 8.8 <5 <5 <5 <5 5 Thallium(ug/1) 0.2 <0.1 <.0.1 <O.1 <0.1 <0.1 <0.1 <0.1 0.1 Zinc(mg/1) 1 <0.010 0.0111 <:0.010 <0.010 <0.010 <:0.010 <:0.010 0.01 TDS(mg/1) 500 40 <25 73 36 26 <25 77 25 pH(S.U.) 6.5-8..5 5.8 .5.4 5.3 6.0 5.6 5.2 6.:3 N/A .eater Level(ft.) N/A 33.08 1.5.27 6.31 10.00 15.45 19.12 5.73 N/A Temperature(°C) N/A 14.60 14.07 15.43 17.30 15.68 15.66 16.04 N/A Specific Cond. N/A 58 32 130 73 36 15 93 N/A (umhos/cm) Turbidity(NTU) N/A 8.97 24.4 8.59 4.06 9.9 2.87 7.71 NfA 15A NCAC 02L.0202 Ground:Jater Quality Standards PQL-Practical Quantitation Limit ug/I-micrograms per liter mg/I-milligrams per liter S.U.-Standard Units NTU-Nephelometric Turbidity Unit 3 � , �4� K y t4ty��i••i,'�.tC 1Yl t, � � i1V .' t i r ` \ ASHEVILLE REGIONAL AIRPORT r } MW-1A 2103.11 9 1 y fill COAL COMBUSTION I 7 ♦� S, w '` \ ♦ PRODUCTLIMITS , ♦ �' ♦ /'(APPROXIMATE) °Bp MW-1® l♦ - `\t �/ it OFFICE r'� _SMALL CREEK � itlA' 7 �A.`: \ 1,�,• ,,i, ; I � k: r,. MAIN ENTRANCE � +IM ',ti♦ ♦ - ,b—�!r - II 0 2061.29 e�♦ ��` I ` I� _. 'IV-WAY r S I'I - MW-5 - F 2062.00 i a i'' 1 �: I, ® MW-5D ¢ `)WESTERN NORTH CAROLINA AGRICULTURAL CENTER )`�� j ct•� "�' � }1 '- ,I- _• . .i ter• •� I w. MW-6 e�+O,90 4:, MW-8r •7. °�ys '1\ �� r k r iw 1, ��• >' ya2 2050.42 41 LEGEND 4a� fit♦ ` `� goy`sj°�;rt FM -7 MONITORING WELL(SAMPLED) 4a 2052.25 WATER LEVEL IN FEET(msl.) w ;� _ �r '�,� �• � ,„• C��, " �) I� MW-8 MONITORING WELL(NOT SAMPLED) y �" t "p J,, .,tR •: - tp `r ;�' SOURCES: 2010 AERIAL PHOTOGRAPH OBTAINED FROM NRCS GEOSPTIAL DATA GATEWAY AT ^y► httpy/date gateway.nresusdagov/ }�O Y yK � `• n ti �,ryi. ,fix, ALL WELLS SURVEYED EXCEPT MW-3 BY WNC PROFESSIONAL ENGINEERS& ?x +r {y, '` C z+f'�4 SURVEYORS ON APRIL 19,2012. .Qd..+:' 1 >.)� .� }'. j.:,l "'sK ,1, •- .��kC`X' 2 GRAPHIC SCALE 300 0 300 600 PROGRESS ENERGY IN FEET STRUCTURAL FILL -AREA 4 148 RIVER STREET,SUITE 220 GREENVILLE,SOUTH CAROLINA 29601 WATER LEVEL MAP-APRIL 19, 2012 PHONES64421-9999 www.synterracorp.com ASHEVILLE REGIONAL AIRPORT synTerra ORAWNBY IOHNCHASTAIN DATE 05/14/2012 ARDEN, NORTH CAROLINA PROJECT MANAGER:KATHY WEBB LAYOUT:WATER LEVEL MAP 05/15/201211:17AM P:Pro —Ener .102602.ASHEVILLE PIA 07.2012 Well Sampling Structural Fill-Area 4 DWG PE ASHEVILLE AIRPORTSTRUCTURAL FILL 4.dw BORING RECORD EOTRACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING No. MIN-`IA Asheville, NC GeoTrack Project No. 10-2626A-N Boring Location: N 631463.03; E 944900.7 Date Drilled: 3/21/12 Ground Elevation: 2134.2 ft Notes: Drilling Method: HSA Hammer Type: Gravity Top of Casing Elev=2136.24 Water Level: 32.5 ft ATD Boring Diameter: 8 in g t u m y STD,PENETRATION TEST DATA o✓ MATERIAL DESCRIPTION CL o E t (blows/ft) ul 0.0 O co z V 10: M Z 5 10 20 40 70 Dense Light Brown Micaceous Silty Flne Sand-Residual 2129.2 8.5 2124.2 SS-1 17 18 20 38 2119.2 15.0 Partially Weathered Rock-Sampled as Gray and Brown Micaceous Silty Fine to Coarse Sand(Very Dense Saprolite) ° ° SS-2 40 50/.3 100+ 2114.2 e ° 4 ° 2109.2 25.0 0 Very Firm Gray and Brown Micaceous Silty Fine to Coarse Sand 28.5 2104.2 SS-3 8 10 13 23 Sz 2099.2 35.0 M Partially Weathered Rock-Sampled as °Ho Gray and Brown Micaceous Silty Fine to oCoarse Sand(Very Dense Saprolite) 38.5 2094 2- SS-4 45 501.3 100+ 0 1L �e C7 ° (V m 2089.2 °• e x i LA L/7 •p A 48.5 0 ° SS-5 J 26 50/.3 i100+1 », S LEGEND Continued Next Page � SAMPLER TYPE DRILLING METHOD z SS -Split Spoon NQ-Rock Core, 1-7/8" HSA- Hollow Stem Auger RW -Rotary Wash a ST Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC - Rock Core m AWG- Rock Core, 1-1/8" CT-Continuous Tube DC -Driving Casing BORING RECORD DEOTPACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING NO. MW-1 A Asheville, NC GeoTrack Project No. 10-2626A-N Boring Location: N 631463.031 E 944900.7 Date Drilled: 3/21/12 Ground Elevation: 2134.2 ft Notes: Drilling Method: HSA Hammer Type: Gravity Top of Casing Elev=2136.24 Water Level, 32,5 ft ATD Boring Diameter: 8 in g g v m m a) STD.PENETRATION TEST DATA a��i MATERIAL DESCRIPTION o E � '� Q m-1 m m t to 00 > (blows/ft) �Z in c N M Z 5 10 20. 40 70 •° e 2079.2 e' ° d ° 2074,2 e' ° Q��e- 2069.2 n' ° "d e "e d .2064.2 2059.2- ° d e ° d ° 2054.2 ° d 84.5 N 2049.2 - Auger Refusal at 84.5 feet a 0 2044.2 LU a t� N " 2039.2 �n N 0 o LEGEND U zW SAMPLER TYPE DRILLING METHOD SS -Split Spoon NQ-Rock Core, 1-7/8" HSA-Hollow Stem Auger RW Rotary Wash o ST -Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC - Rock Core m AWG-Rock Core,1-1/8° CT-Continuous Tube DC -Drivinq Casing Well name changE, �-o MW-5 BORING LOG / WELL CONSTRUCTION REPORT 0 SS Drill Rig: Ingersoll Rand Date Drilled: 12/08/2009 Logged By: Silar Sv"iirs Inc. Boring Dia: 8 Inches Boring Number: PZ-04 Bryan Sladky Undefined Completion Depth E Lithology Description M Undefined Feet rn Topsoil and brown SILT 7—. Light brown silty fine-medium SAND,low-medium moist. 5 10 As-above,wet at 13 ft bgs. X 15 .......... 20 25 30 35 Completion Notes: Site: -well finished with a locked, above-ground steel security casing. Asheville Airport Asheville, NC Project No.: Page 1 BORING RECORD REOTRACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING No. MW-6D Asheville,NC GeoTrack Project No.10-2626A-N Boring Location: N 629386.57; E 944842.06 Date Drilled: 4/2/12 Ground Elevation: 2066.9 ft Notes: Drilling Method: HSA Hammer Type: Gravity Top of Casing Elev=2069.53 Water Level: 9.3 ft ATD Boring Diameter: 8 in 0 STD.PENETRATION TEST DATA ca MATERIAL DESCRIPTION o E C _ (blows/ft) w 0 �-� ink M d io m 0.0 Z V N M Z 5 10 20 40 70 Loose Yellowish Brown Silty Fine to Medium Sand-Residual 2061.9 8.5 2056.9 SS-1 4 5 5 10 2051.9 15.0 Firm Gray and Yellowish Brown Very Micaceous Silty Fine Sand 18.5 2046.9 SS-2 4 6 6 12 2041.9 25.0 Firm Gray and Brown Micaceous Fine Sandy Silt 28.5 2036.9- SS-3 6 7 10 17 33.5 �� 2031.9 35,0 SS-7 26 20 23 43 Very Dense White and tight Gray a Micaceous Silty Fine Sand r? 38.5 � 40,0_ SS-4 17 28 35 63 2026.9 Partially Weathered Rock-Sampled as W Gray and Brown Micaceous Silty Fine Sand (Very Dense Saprolite) [V V 2021.9 0 N ° ° 48.5 o ° SS-5 35 50/.5 100+ ? :>>, 0 LEGEND 0 Continued Next Page LU SAMPLER TYPE DRILLING METHOD SS Split Spoon NQ-Rock Core, 1-7/8" HSA-Hollow Stem Auger RW -Rotary Wash ST Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC -Rock Core m AWG-Rock Core, 1-1/8" CT-Continuous Tube DC -Driving Casing BORING RECORD DEOTRACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING No. MW-5D Asheville,NC GeoTrack Project No.10-2626A-N Boring Location: N 629386.57; E 944842.06 Date Drilled: 4/2/12 Ground Elevation: 2066.9 ft Notes: Top of Casing Elev=2069.53 Drilling Method: HSA Hammer Type: Gravity Water Level: 9.3 ft ATD =BoringDiameter; 8 in G Y9 m z m m a) STD.PENETRATION TEST DATA o MATERIAL DESCRIPTION CoIC E Ug Eta _ m (blows/ft) m M io jo w CD W� Wiz° 0 z N M 5 10 20 40 70 •e 2011.9 n' ° e' e ° r 58.5 2006.9 e ° SS-6 38 50/A 100+ >? •°•ffc ele 2001.9 Q ID •° e n ° 1996.9 e' e 71.5 Auger Refusal at 71,5 feet 1991.9 1986.9 1981:9 of v X 1976.9 _ 0 w (V V 1971.9 N G: LEGEND iW SAMPLER TYPE DRILLING METHOD SS -Split Spoon NQ-Rock Core,1-7/8" HSA- Hollow Stem Auger RW -Rotary Wash ST -Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC -Rock Core o AWG-Rock Core. 1-1/8" CT-Continuous Tube DC -Driving Casin m BORING LOG Drill Rig: Geoprobe Date Drilled: July 2,2010 Logged By: Boring Dia: 8 Inches Boring Number: MW-6 Tim Silar Blow Completion Depth Lithology Description E M Counts Feet W Bm-rd brn sit w1tr clay,tr mica ..16, 5 Brn w/sm grysh bm sit,tr of gr sd 10 Bm and tan sit w/tr mica,tr clay,wet @ 151 15 Brn f-vf gr sd,saturated @ 18' 20 AA 25 AA Completion Notes: Site: Asheville Airport Area 4 FProject No.: Page 1 ' BORING LOG Drill Rig: Geoprobe Date Drilled: July 2,2010 Logged By: 1 Boring Dia: 8 Inches Boring Number: MW-7 Tim Silar Blow pth E Counts Completion Feet Lithology Description Brn-rd brn sit w/tr clay,tr mica 5 .:a •u:� I i I� Brn w/sm grysh brn sit,tr of gr sd yes•. ai•. � f 10 ' Brn and tan sit w/tr mica,tr clay,saturated @ 15' 15 1 I f Brn f-vf gr sd 20 AA 25 AA Completion Notes: Site: Asheville Airport Area 4 j Project No.: Page 1 BORING RECORD ® O RACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING No. lad W-9 Asheville,NC GeoTrack Project No. 10-2626A-N Boring Location: N 627830.48; E 945932.19 Date Drilled: 3/29112 Ground Elevation: 2067.1 ft Notes: Drilling Method: HSA Hammer Type: Gravity Top of Casing Elev=2059.14 Water Level: 14.2 ft ATD Boring Diameter: 8 in g g (D L a� 0 STD.PENETRATION TEST DATA o$ MATERIAL DESCRIPTION (blows/ft) w (9 in fa COO ifl o io > 0.0 Z N M Z 5 10 20 40 70 Firm Yellowish Brown and Gray Micaceous Silty Fine Sand,-Residual 2052.1 8.5 2047.1 SS-1 8 9 11 20 Sz 2042,1 15.0 - Firm to Dense Gray and Brown Micaceous Silty Fine Sand 18.5 2037.1 SS-2 9 20 22 42 2032.1 28.5 20271 SS-3 •15 18 22 40 N 2022.1 - F_ � 3t3.5 2017.1 SS-4 8 8 11 19 V2012.1 04 N � ...LEGEND Continued Next Page zw SAMPLER.TYPE DRILLING METHOD SS -Split Spoon NQ- Rock Core, 1-7/8" HSA- Hollow Stem Auger RW -Rotary Wash o ST -Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC - Rock Core m AWG- Rock Core, 1-1/8" CT-Continuous Tube DC -Driving Casing BORING RECORD ®EOTRACK TECHNOLOGIES, INC. Asheville Airport Area 4 BORING No. MW-9 Asheville,NC GeoTrack Project No.10-2626A-N Boring Location: N 627830.48; E 945932.19 Date Drilled: 3/29/12 Ground Elevation:2057.1 ft Notes: Drilling Method: HSA Hammer Type: Gravity Top of Casing Elev=2059.14 Water Level: 14.2 ft ATD Boring Diameter: 8 in c a STD.PENETRATION TEST DATA > MATERIAL DESCRIPTION m o m, E C (blows/ft) Wf� J O in 6 f0 D to Z N (o Z 5 10 20 40 70 2002.1 55.0 Partially Weathered Rock-Sampled as ; . .N: Gray and White Micaceous Silty Fine Sand (Very Dense Saprolite) 58.5 1997 1 a• a SS-5 18 35 50/A 100+ ;»' ° n ° a 1992.1 a ° d ° 1987.1 a ° ,Q• a •° a 1982.1 a' ° a• ° a' ° 78.5 1977 1 ° SS 6 01.4 100+ >> e . p 1 e i N 1972.1 ° q v ° a � a (9 n Y 1967A a• a 0 UJ °• e a' N CQ 1962.1 n• e 0 96.0 Auger Refusal at 96 feet N O g LEGEND ie SAMPLER TYPE DRILLING METHOD z SS -Split Spoon NQ-Rock Core,1-7/8" HSA- Hollow Stem Auger RW -Rotary Wash o ST Shelby Tube CU-Cuttings CFA-Continuous Flight Augers RC -Rock Core m AWG- Rock Core,1-1/8" CT-Continuous Tube DC -Driving Casing r �pn 5TnrF'Q`,� 1 !r ONRESIDENTM WELL CONSTRUCTION RECORD North Carolina Department of Environment and Natural Resources-Division of Water Quality WELL CONTRACTOR CERTIFICATION# 2288 1.WELL CONTRACTOR: :d. TOP OF CASING IS 2.02 FT.Above Land Surface" Mr. Robert Frye "Top of casing terminated at/or below land surface may require Well Contractor(Individual)Name a variance in accordance with 15A NCAC 2C.0118. c/o GeoTrack Technoloaies Well Contractor Company Name e. YIELD(gpm): METHOD OF TEST 3620 Pelham Road PMB 292 f. DISINFECTION:Type Amount Street Address :g. WATER ZONES(depth): Greenville SC 29615 :'Top_Bottom Top Bottom City or Town State Zip Code :Top Bottom Top Bottom 8( 64 ) 329-0013 :Top Bottom Top Bottom Area code Phone number Thickness/ 2.WELL INFORMATION: :7. CASING: Depth Diameter Weight Material WELL CONSTRUCTION PERMIT#WM0100291 :Top 0 Bottom 74.5 Ft. 2" S 40 PVC OTHER ASSOCIATED PERMIT#(if applicable) Top Bottom Ft. SITE WELL ID#(if applicable)MW-1 A Top Bottom Ft. 3.WELL USE(Check One Box)Monitoring t(Municipal/Public❑ 8. GROUT: Depth Material Method Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑ :Top 0 Bottom 73 Ft. Cement/Bent. Tremie Irrigation❑ Other❑ (list use) :Top Bottom Ft. DATE DRILLED 3/21/12 ;Top Bottom Ft. 4.WELL LOCATION: :9. SCREEN: Depth Diameter Slot Size Material Asheville Reaional Airport Area 4 ;Top 74.5 Bottom 84.5 Ft. 2" in. 0.010 in. PVC (Street Name,Numbers,Community,Subdivision,Lot No.,Parcel,Zip Code) Top Bottom Ft. in. in. CITY: Asheville COUNTY Buncombe :Top Bottom Ft, in, in. TOPOGRAPHIC/LAND SETTING: (check appropriate box) ❑Slope ❑Valley ❑Flat ZRidge ❑Other •10.SAND/GRAVEL PACK: LATITUDE 35 0 25 58.0000 "DMS OR DD Depth Size Material LONGITUDE 82 0 32 35.0000 ;Top Bottom 84.5 Ft. 20-40 Fine Silica Sand "DMS OR DD 73;Top Bottom Ft. Latitude/longitude source: I]GPS JgTopographic map :Top Bottom Ft. (location.of well must be shown on a USGS topo map andattached to this form if not using GPS) :11. DRILLING LOG 5.FACILITY(Name of the business where the well is located,) Top Bottom Formation Description Asheville Reaional Airnnrt 0 / 15 _Lt.Brown Silty Fine Sand Facility Name Facility ID#(if applicable) 15 / 25 Gray and Brn Silty F-Cs Sand 61 Terminal Drive 25 / 35 _Gray and Brn. Silty F-Cs Sand Street Address/ 84.5 Gray and Brn.Silty F-Cc Sand Fletcher NG 2am / City or Town State Zip Code / (See Boring Record) _Mr. M. Reisman / Contact Name / Mailing Address / City or Town State Zip Code 12.REMARKS: �1 �� Area Phone number -Mea n-b ��y� S.WELL DETAILS: :I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15A NCAC 2C,WELL CONSTRUCTION STANDARDS,AND THAT A COPY OF THIS a. TOTAL DEPTH: 84.5 RECORD HAS BEEN PROVIDED TO THE WELL OWNER. b. DOES WELL REPLACE EXISTING WELL? YES❑ NO q/ :SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing:_32.8 FT. :-Robert Frye (Use"+"if Above Top of Casing) :PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to:Division of Water Quality- Information-Processing, Form Rev.2/09 b 09 1617 Mail Service Center,Raleigh,NC 27699-161,Phone:(919)807-6300 5r+r� NONRESIDENTIAL ONRESIDE.NTIAL WELL CONSTRUCTION RECORD i North Carolina Department of Environment and Natural Resources.Division of Water Quality WELL CONTRACTOR CERTIFICATION# 2580 1.WELL CONTRACTOR: d. TOP OF CASING IS 2.0 FT.Above Land Surface' JASON MANTAK "Top of casing terminated at/or below land surface may require Well Contractor(Individual)Name a variance in accordance with I SA NCAC 2C.0118, GEOLOGIC EXPLORATION,INC. e. YIELD(gpm): N/A METHOD OF TEST NIA Well Contractor Company Name f. DISINFECTION:Type N/A Amount NIA STREET ADDRESS 176 COMMERCE BLVD g. WATER ZONES(depth): STATESVILLE NC 28625 From__To From To City or Town State Zip Code From,—To From To 70( 4 ). 872-7.686 From —.To Frwr1 To Area code- Phone number 6. CASING: eett Thickness/ 2.WELL INFORMATION: 0.0 Depth10.0 2 INCHef SePhl PM I ial SITE WELL ID#(if applicable) MW-2 From —To Ft. C STATE WELLPERMIT#(if applicable) From _TO Ft. DWQ or OTHER PERMIT#(if applicable) From - To Ft. WELL USE(Check Applicable Box)Monitoring® Municipal/Public`I 7. GROUT: Depth Material Method Industrial/Commercial❑ Agricultural❑ Recovery❑Injection❑ From 0'0 -To 4.0 Ft Portland bentonite SLURRY Irrigation❑ Other❑ (list use) From _To Ft. DATE DRILLED - 12/08/09 From To Ft. TIME COMPLETED AM❑ PM❑ 8. SCREEN: Depth Diameter Slot Size Material From 10.0 To 30.0 Ft.2.0 in, .010 in. PVC 3.WELL LOCATION: From _To—Ft. in. in. CITY: ASHEVILLE COUNTY BUNCOMBE From To Ft. in. in. WRIGHT BROTHERS WAY 28732 9. SANDIGRAVEL PACK: (Street Name,Numbers,Community,Subdivision,Lot No.,Parcel Zip Code) Depth Size Material i TOPOGRAPHIC/LAND SETTING: From 8.0 To 30.0 Ft. 20-40 FINE SILICA SAND QSlope []Valley ❑Flat DRidge El Other (check appropriate box) From To Ft. I11Tr7uDE May be in degrees, From To. FI. — minutes,seconds or 10.DRILLING LOG LONGITUDE _ _ in a decimal ibrnra: From To Formation Description Latitudeflongitude source: ❑GPS ❑Topographic map 0.0 15.0 _ BROWN SILTY CLAY (location of well must be shown on a USGS topo map and 15.0 30.0 _ GRAY SILTY CLAY attached to this form if not using GPS) 4.FACILITY-is the name or the business where the well is located —_ FACILITY ID#(if applicable) NAME OF FACILITY ASHEVILLE AIRPORT -- STREET ADDRESS WRIGHT BROTHERS WAY -- ASHEVILLE NC 28732 City or Town State Zip Code CONTACT PERSON ASHEVILLE REGIONAL AIRPORT MAILING ADDRESS 61 TERMINAL DRIVE --- FLETCHER NC 28732 11.REMARKS; City or Town State Zip Code BENTONITE SEAL FROM 4.0 TO 8.0 FEET Area code- Phone number — 6.WELLDETAILS: 'CO RE9YCERTIfYTHTTHI WAS CONSTRUCTED IN ACCORDANCE WITFi 1 Sq C 2C,WEL R N STANDARDS.AND THAT A COPY OF THIS 30.0 FEET RE BEEN I E WELL OWNER. a. TOTAL DEPTH: 12/10/09 b. DOES WELL REPLACE EXISTING WELL? YES❑ NO❑ S_1_JtATURE OF CERTIFIED WELL CONTRACTOR DATE C. WATER LEVEL Below Top of Casing: 14.0 FT JASON MA 4TAK (Use"+"if Above Top of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit the original to the Division of Water Quality within 30 days. Attn: Information Mgt., Form GW-1b 1617 Mail Service Center-Raleigh,NC 27699-1617 Phone No,(919)733-7016 ext 568. Rev.7105 Well named changed to MW-5 slArr r ! *. p NON.RESIDENTIAL WELL CONSTRUCTION RECORD North Carolina.Department of Environment and Natural Resources-Division of Water Quality r r WELL CONTRACTOR CERTIFICATION# 2580 1.WELL CONTRACTOR: d. TOP OF CASING IS 2.0 FT.Above Land Surface- JASON MANTAK 'Top of casing terminated attor below land surface may require Well Contractor(Individual)Name a variance in accordance with 15A NCAC 2C.011 B. GEOLOGIC EXPLORATION,INC. e. YIELD(gpm) NIA METHOD OF TEST NIA Well Contractor Company Name I. DISINFECTION:Type N/A Amount NIA STREET ADDRESS 176 COMMERCE BLVD g. WATER ZONES(depth): STATESVILLE NC 28625 From--To From To City or Town State Zip Code - From—_To From To 70( 4 )- 872-7686 From__To From To Area code Phone number 6. CASING: Thickness/ 2.WELL INFORMATION: Depth Diametter fth$ Material at al SITE WELL ID#(inapplicable) PZ-4 From 0.0 _To 10-0 Fl 2 INPVC STATE WELL PERMIT#(it applicable) From _To Ft. From A. DWp or OTHER PERMIT#(if applicable) ""- i o WELL USE(Check Applicable Box)Monitoring® Municipat/Public t_ 7. GROUT: Depth Material Method Industriat/Commercial❑ Agricultural❑ Recovery❑Injection G From 0.0 _To 4.0 Ft Portland bentonite SLURRY Irrigation❑ Other❑ (list use) From _To Ft. DATE DRILLED 1210B/09 From — To. Ft. 8. SCREEN: Depth Diameter Slot Size Material TIME COMPLETED AM(] PM❑ 10.0 r 25.0 2.0 .010 3.WELL LOCATION: From o Ft. in. in. PVC From 70 Ft. in. in. CITY' ASHEVILLE COUNTY BUNCOMBE From �To—Ft. in_ in. WRIGHT BROTHERS WAY 28732 (Street Name,Numbers,Community,Subdivision,Lot No. Parcel.Zip Code) 9. SANDIG PACK: Depth Size Material ,i TOPOGRAPHIC/LAND SETTING: From 8.0 ro 25.0 Ft. 20-40 FINE SILICA SAND ❑Slope ❑Valley DFlat ❑Ridge ❑Other From fo Fl. (check appropriate box) LATITUDE May be in degrees. From _ro A. minutes,seconds or 10,DRILLING LOG LONGITUDE _ in a decimal format From To Formation Description Latitude/longitude source: ❑GPS ❑Topographic Wrap 0.0 250 BROWN SILTY CLAY (location of we#must be shown on a USGS topo map and attached to this lwm if not using GPS) 4.FACILITY.is The name or the business where the wets is Inca,ea. FACILITY ID#(if applicable) —_ NAME OF FACILITY ASHEVILLE AIRPORT STREET ADDRESS WRIGHT BROTHERS WAY —'— ASHEVILLE NC 28732 City or Town State Zip Code CONTACT PERSON ASHEVILLE REGIONAL AIRPORT MAILING ADDRESS 61 TERMINAL DRIVE FLETCHER NC 28732 11.REMARKS: City or Town State Zip Code BENTONITE SEAL FROM 4.0 TO8.0 FEET Area code- Phone number _ 100 HEREBY CERIIFY-HATrHIS WELL W CONSTRUCTED I10 ACCORDANCE WITH S.WELL DETAILS: ISA NC 2C,WELL CUNST CTI N DARDS,AND THAT COPY OF THIS a. TOTAL DEPTH: 25.0 FEET RECo AS BEEN P D E WELL OWNER. 12110/09 b. DOES WELL REPLACE EXISTING WELL? YES❑ NO EJ SIG URE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing: 5•0 FT. #SON 14ANTAK } (Use"+"if Above Top of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit the original to the Division of Water Quality within 30 days. Attn:Information Mgt., Form GW-1b 1617 Mail Service Center—Raleigh,NC 27699-1617 Phone No.(919)733-7015 ext 568. Rev.7/05 NoNREsiDENT 4L wi;Ll.CoivsTRUC'r10N RECORD �4t 4 b_f North Carolina Department of Environment and Natural Resources-Division of Water Quality WELL CONTRACTOR CERTIFICATION 4 2288 1.WELL CONTRACTOR: d. TOP OF CASING IS 2.61 FT.Above Land Surface*Mr. Robert Frye `Top of casing terminated at/or below land surface may require Well Contractor(Individual)Name a variance in accordance with 15A NCAC 2C.0118. C/o GeoTrack Technologies :e. YIELD(gpm): METHOD OF TEST Well Contractor Company Name 3620 Pelham Road, PMB 292 f, DISINFECTION:Type Amount Street Address ;g. WATER ZONES(depth): Greenville SC 29615 :Top Bottom Top Bottom City or Town State Zip Code :Top Bottom Top Bottom 8( 64 ) 329-0013 :Top Bottom Top Bottom Area code Phone number Thickness/ 2.WELL INFORMATION: 7. CASING: Depth Diameter Weight Material WELL CONSTRUCTION PERMIT#WM0100291 Top 0 Bottom 61.5 Ft. 2" S 40 PVC OTHER ASSOCIATED PERMIT#(if applicable) :Top Bottom Ft. SITE WELL ID*(if applicable)MW-5D Top Bottom Ft. 3.WELL USE(Check One Box)Monitoring R(Municipal/Public❑ :8. GROUT: Depth Material Method Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑ :Top 0 Bottom 58 Ft. Cement/Bent. Tremie Irrigation❑ Other❑ (list use) :Top Bottom Ft. DATE DRILLED 4/2/12 ;Top Bottom Ft, 4.WELL LOCATION: :9. SCREEN: Depth Diameter Slot Size Material Asheville Regional Airport Area 4 :Top 61.5 Bottom 71.5 Ft. 2" in. 0.010 in. PVC (Street Name,Numbers,Community,Subdivision,Lot No.,Parcel,Zip Code) :Top Bottom Ft. in. in. CITY: Asheville COUNTY Buncombe :Top Bottom Ft. in. in. TOPOGRAPHIC/LAND SETTING: (check appropriate box) []Slope ❑Valley ❑Flat ZRidge ❑Other : 10.SAND/GRAVEL PACK: LATITUDE 35 25 39.0000 DMS OR DD Depth Size Material LONGITUDE 82 3z 35.0000 :Top 58 Bottom 71.5 Ft. 20-40 Fine Silica Sand "DMS OR DID :Top Bottom Ft. Latitude/longitude source: E]GPS Topographic map :Top Bottom Ft. (location of well must be shown on a USGS topo map andattached to this form if not using GPS) :11. DRILLING LOG 5.FACILITY(Name of the business where the well is located.) : Top Bottom Formation Description Asheville Reainnal Airnort 0 / 15 Y. Brown Silty Fine Sand Facility Name Facility ID#(if applicable) 15 / 25 Gray and Y. Brn Silty F Sand 61 Terminal Drive 25 / 35 Gray and Brn F Sandy Gilt Street Address 35 / 40 White and Gray Silty Fine Sand FletehPr NC 28732 40 / 71.5 Gray and Brn.Silty F-Cs Sand City or Town State Zip Code / Mr. M_ Reisman / (See Boring Record) Contact Name / / Mailing Address / City or Town State Zip Code 12.REMARKS: Are cog de Phone number Measured SPS b0s---- i 6.WELL DETAILS: ;I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH I 15A NCAC 2C,WELL CONSTRUCTION STANDARDS,AND THAT A COPY OF THIS a. TOTAL DEPTH: 71.5 RECORD HAS BEEN PROVIDED TO THE WELL OWNER. b. DOES WELL REPLACE EXISTING WELL? YES❑ NO qI :SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing:_ 11.89 FT. : Robert Frye (Use"+"if Above Top of Casing) :PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to: Division of Water Quality- Information-Processing, Form GWA b Rev,2/09 1617 Mail Service Center, Raleigh,NC 27699-161,Phone:(919)807-6300 J r Z = NONRESIDENTIAL WELL CONSTRUCTION RECORD y Noah Carolina Department of Environment and Natural Resources-Division of Water Quality `:... � WELL CONTRACTOR CERTIFICATION 4 3098 —�, 1.WELL CONTRACTOR: d. TOP OF CASING IS 3.0 FT.Above Land Surface' JOHNNY BURR 'Top of casing terminated attor below land surface may require a variance in a.cordance with 15A NCAC 2C.0118. Well Contractor(Individual)Name GEOLOGIC EXPLORATION,INC. e. YIELD(gpm): N/A METHOD OF TEST N/A f. DISINFECTION:Type WA Amount N/A Well Contractor Company Name STREET ADDRESS 176 COMMERCE BLVD — g. WATER ZONES tdepth): From—To From To STATESVILLE NC 28625 _ From_ To From To City or Town State Zip Code - From _ To Fran To 70( 4 1. 872-7686 Area code- Phone number 6. CASING: Thickness! Deoth Diameter W t hb Material 2.WELL INFORMATION: 15.0 2 INCH S�r�a PVC SITE WELL ID*(if applicable) MW-6 From 0.0 To Ft. _ F`an-__T o STATE WELL PERMIT#(if applicable) Ft. - From To Ft. DWQ or OTHER PERMIT#(if applicable) 7. GROUT: Dtspth Material Method WELL USE(Check Applicable Box)Monitoring 9) Municipaf/Public 71 Industrial/Commercial❑ Agricultural❑ Recovery El Injection Injection From 0�0 _To 10'0 Ft Portland benlonile SLURRY Irrigation[--) Other❑ pist use) From To Ft. Frorrl To Ft. DATE DRILLED 07/01/10-07/02/10 8. SCREEN: Depth Diameter Slot Size Material TIME COMPLETED AM❑ PM❑ 15.0 30.0 2.0 .010 PVC Frcm To Ft. in. in. 3.WELL LOCATION: From To Ft. in. in. CITY. ASHEVILLE COUNTY BUNCOMBE From Ftin. in. WRIGHT BROTHERS WAY 28732 9. SAND/GRAVEL PACK: } (Street Name,Numbers,Community,Subdivision,Lot No..Parcel,Zip Code; Depth Size Material TOPOGRAPHIC/LAND SETTING: From 13.0 0 30.0 Ft_ 20-40 FINE SILICA SAND ❑Slope []Valley ❑Flat p Ridge ❑Other — From_ o Ft- (check appropriate box) May be rn degree; From_"—~•o_ Ft. LATITUDE -`—' -— minu[cs.yconds ar 10,DRILLING LOG LONGITUDE _ _ in a decimal Furm:tt From To Formation Description Latitude/longitude source: ❑GPS ❑Topod aphic map -0 3.0 _ ORANGE ROCKY SANDY CLAY (location of well must be Shown on a USGS topo map and 3.0 10.0 TAN/ORANGE SILTY CLAY attached to this form tl not using GPS) 10.0 30.0 _ TAN/BROWN SANDY CLAY 4.FACILITY-is the name of the business where the well is located FACILITY ID#(if applicable) — — NAME OF FACILITY ASHEVILLE AIRPORT STREET ADDRESS WRIGHT BROTHERS WAY ASHEVILLE NC 28732 City or Town State Zip Code CONTACT PERSON ASHEVILLE REGIONAL AIRPORT — MAILING ADDRESS 61 TERMINAL DRIVE ------— PLETCHER NC 28732 11•REMARKS: City or Town Stale Zip Code BENTONITE SEAL FROM 10.0 TO 13.0 FT Area code- Phone number I DO HERFaY CERTIFY"HAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 5.WELL DETAILS: t5A NCA.0-C,W-LL CaNSTRUCTIDN ST ARDS,AND THAT A COPY OF THIS 30.0 FEET RE C• ¢ �VfDG C 7E t}CLOWNER. a. TOTAL DEPTH: 0T/07/10 b. DOES WELL REPLACE EXISTING WELL? YES C NO�i 'SIGNATURE CERTIFIED '„ CD 7 A DATE c. WATER LEVEL Below Top of Casing: 15.0 FT. JOHNNY BURR (Use"+"if Above Top of Casing) PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit the original to the Division of Water Quality within 30 days. Attn:Information Mgt., Form GWAb 1617 Mail Service Center—Raleigh,NC 27699-1617 Phone No.(919)733-7015 exi 668. Rev.7/05 �•:� 1 Y'ONRESIDENTDAL WELL CONSTRUCTION RECORD `='•Al North Carolina Department of Em ironmrnt and Natural Resources-Diviiirin of Water Quality 1;1 WELL CONTRACTOR CERTIFICATION# 3098 1.WELL CONTRACTOR: d. TOP OF CASING IS 3.0 FT.Above Land Surface' JOHNNY BURR 'Top of casing terminated at/or below land surface may require a variance in ac cordance with 15A NCAC 2C.0118. Well Contractor(Individual)Name e. YIELD{gpm}: N/A METHOD OF TEST N/A GEOLOGIC EXPLORATION.INC. Well Contractor Company Name f. DISINFECTIOIC Type NIA Amount N/A STREET ADDRESS 176 COMMERCE BLVD _ g. WATER ZONES(depth): From To From To STATESVILLE NC 28625 - Fran To From To City or Town State Zip Code From 7o From 7a 70( 4 ). 872-7686 Area code- Phone number 6. CASING: Thickness/ 2.WELL INFORMATION: Depth i5.0 Ft 2 1N etef ls�i�a& Material SITE WELL ID#(ir applicable) MW- Fran_0_0 STATE WELL PERMIT#(if applicable) From To Ft. - From_ To Fl. DWQ or OTHER PERMIT#(if applicable) 7. GROUT: Depth Material Method WELL USE(Check Applicable Box)Monitoring M Municipal/Public C. Indus trial/Commercial El Agricultural❑ Recovery p Injection� From- To To 10.0 Ft Portland bentomle SLURRY From_ To A Imgation❑ Other❑ (list use) From To Ft. DATE DRILLED 07101/4 0-07/02/10 8. SCREEN: Depth Diameter Slot Size Material TIME COMPLETED AM O PM O 15.D 30.0 2.0 .010 PVC From To Ft. in. in. 3.WELL LOCATION: From To Ft. in. in. CITY' ASHEVILLE COUNTY BUNCOMBE Fran 7u FL-in- in. WRIGHT BROTHERS WAY 28732 9. SAND/GRAVEL PACK: (Street Name,Numbers,Community.Subdivision,Lot No..Pareel Zip Code) Depth Size Material i TOPOGRAPHIC/LAND SETTING: From_13.0`70 30.0 Ft, 20-40 FINE SILICA SAND ❑Slope ❑Valley ❑flat ❑Ridge p Other - From To Ft. (check appropriate box) - May be in degrees From-_,T o Ft. LATITUDE - - minutes,seconds er 10.DRILLING LOG LONGITUDE _ in a decimal forma: From To Formation Description Latitudellongitude source: pGPS EiTopographic map 0.0 3.0 - ORANGE ROCKY SANDY CLAY (location of well must be shown on a USGS topo map and 3.0 10.0 - TANIORANGE SILTY CLAY attached t0 this form if not using GPS) 10 0 30.0 - TANIBROWN SANDY CLAY 4.FACILITY-is the name or the business where the well is located. _ - FACILITY ID#(if applicable) - - NAME OF FACILITY ASHEVILLE AIRPORT _ - STREET ADDRESS WRIGHT BROTHERS WAY -" ASHEVILLE NC 28732 _ City or Town State Zip Code CONTACT PERSON ASHEVILLE REGIONAL AIRPORT MAILING ADDRESS 61 TERMINAL DRIVE - -- ------ - FLETCHER NC 28732 11.REMARKS: City or Town State Zip Code BENTONITE SEAL FROM 10.0 TO 13.0 FT U-Area code- Phone number 100 HEREBY CE RTIF Y T-IAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 5.WELL DETAILS: 15A N , 2C.YVELL CO 4STRUCTION STA RDS.AND THAT A COPY OF THIS a. TOTALDEPTH: 30.OFEET FtEC D A EENpRU EDTOTHEOWNER. - 07/07/10 b. DOES WELL REPLACE EXISTING WELL? YES❑ NO E SIG1lATUREIOF CERTIFIED VVIReE Co TRAC ON DATE c. WATER LEVEL Below Top of Casing: 15.0 FT. JOHNNY BURR } (Use"+"if Above Top of Casing) PRINTED NAME 01:PERSON CONSTRUCTING THE WELL Submit the original to the Division of Water Quality Within 30 days. Attn: Information Mgt., Form GW-lb 1617 Mail Service Center-Raleigh,NC 27699-1617 Phone No.(919)733-7016 ext 568. Rev.7105 r, .NONRESIDENTIAL WELL CONSTRUCTION RECORD 4;1 North Carolina Department of Environment and Natural Resources-Division of Water Quality WELL CONTRACTOR CERTIFICATION# 2288 1.WELL CONTRACTOR: :d. TOP OF CASING IS_2.00 FT.Above Land Surface* _Mr. Robert Frye *Top of casing terminated at/or below land surface may require Well Contractor(Individual)Name a variance in accordance with 15A NCAC 2C.0118. c/o GeoTrack Technologies 'e. YIELD(gpm): METHOD OF TEST Well Contractor Company Name 3620 Pelham Road. PMB 292 f. DISINFECTION:Type Amount Street Address ;g. WATER ZONES(depth): Greenville SC 29615 :Top Bottom Top Bottom City or Town State Zip Code :Top Bottom Top Bottom 8( 64 ) 329-0013 Top Bottom Top Bottom Area code Phone number Thickness/ 2.WELL INFORMATION: 7. CASING: Depth Diameter Weight Material WELL CONSTRUCTION PERMIT#WM0100291 :Top-0- Bottom 85 Ft. 2" S 40 PVC OTHER ASSOCIATED PERMIT#(if applicable) :Top Bottom Ft. SITE WELL ID#(if applicable)MW-9 Top Bottom Ft. 3.WELL USE(Check One Box)Monitoring N(Municipal/Public❑ :8. GROUT: Depth Material Method Industrial/Commercial❑ Agricultural❑ Recovery❑ Injection❑ Top 0 Bottom 82 Ft. Cement/Bent. Trentie Irrigation❑ Other❑ (list use) :Top Bottom Ft. DATE DRILLED 3/29/12 :Top Bottom Ft. 4.WELL LOCATION: 9. SCREEN: Depth Diameter Slot Size Material Asheville Regional Airport Area 4 Top 85 Bottom 95 Ft. 2" in, 0.010in. PVC (Street Name,Numbers,Community,Subdivision,Lot No.,Parcel,Zip Code) Top Bottom Ft, in. in. CITY: Asheville COUNTY Buncombe :'Top Bottom Ft. in. In. TOPOGRAPHIC/LAND SETTING: (check appropriate box) ❑Slope ❑Valley []Flat ZRIdge []Other 10.SAND/GRAVEL PACK: LATITUDE 35 *25 25.0000 DMS OR DD Depth Size Material LONGITUDE 82 * 32 20.0000 :Top 82 Bottom 95 Ft. 2 -40 Fine Silica Sand "DMS OR DD ;Top Bottom Ft. Latitude/longitude source: pGPS 0-opographic map :Top Bottom Ft. (location of well must be shown on a USGS topo map andattached to this form if not using GPS) : 11. DRILLING LOG 5.FACILITY(Name of the business where the well is located.) Top Bottom Formation Description Asheville ReainnM Airnclrt 0 / 15 Y. Brn.and Gray Silty Fine Sand Facility Name Facility ID#(if applicable) 15 / 55 _Gray and Brn.Silky Fine Sand 61 Terminal Drive 55-1_95 _Gray and White Silty Fine Sand Street Address Fletrher NG 28739 I (See Boring Record) City or Town State Zip Code / Mr_ M_ RAISman / Contact Name / Mailing Address / City or Town State Zip Code _ :12.REMARKS: Are code de Phone number Dg- 6.WELL DETAILS: :I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE-WITH 15A NCAC 2C,WELL CONSTRUCTION STANDARDS,AND THAT A COPY OF THIS a. TOTAL DEPTH:_95 RECORD HAS BEEN PROVIDED TO THE WELL OWNER. b. DOES WELL REPLACE EXISTING WELL? YES❑ NO q/ :SIGNATURE OF CERTIFIED WELL CONTRACTOR DATE c. WATER LEVEL Below Top of Casing:- 16.15 FT. (Use"+"if Above Top of Casing) '-Robert Frye PRINTED NAME OF PERSON CONSTRUCTING THE WELL Submit within 30 days of completion to: Division of Water Quality- Information Processing, Form GW-1b 1617 Mail Service Center,Raleigh,NC 27699-161,Phone:(919)807-6300 Rev.2/09 I� A a C� Progress Energy 4 �°�� 0 5 z��� t®� 9 9Y Certified Mail: 7010 0780 0000 6615 2335'. File Pt.: 12520-Q -- -January 4,2012 Mr.G.Landon Davidson NC DENR/DWQ Aquifer Protection Section 2090 U.S. 70 Highway Swannanoa,NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Area I Fill Project November 2011 Groundwater Monitoring Results Dear Mr. Davidson: Attached are results from the fifth semi-annual groundwater monitoring sampling event, conducted on November 9, 2011, of wells near the Area I coal ash structural fill at the Asheville Regional Airport. Also attached is a groundwater contour map as prepared by SynTerra Corp. for this sampling event. Sampled were down-gradient wells MW-IA,MW-2A and MW-5 along with up-gradient well MW-4A(for reflecting ambient conditions). The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Chromium Iron Manganese Groundwater 6.5—8.5 10 300 50 Quality Standard (u 1) MW-lA 5.7 --- --- --- MW-2A 5.64 --- --- --- MW-4A 5.11 --- --- 1,240 MW-5 5.07 12.4 372 70.4 All results from this sampling event are summarized on the following page. Note that total dissolved solids(TDS)were detected in the field blank. Therefore,the TDS data with concentrations less than 5 times the field blank concentration are qualified with a `B' flag. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. The next sampling event is scheduled for April 2012. Sincerely, /��O G-&�- Garry A. Whisnant Asheville Plant Manager Attachments Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter January 4,2012 Parameter .0202 Limit Well MW-1A Well MW-2A Well MW-4A Well MW-5 PQL Antimony(ug/1) 1 <0.5 <0.5 <0.5 <0.5 0.5 Arsenic(ug/1) 10 <5 <5 <5 <5 5 Barium(ug/1) 700 13.2 14.9 30 22.4 5 Boron(ug/1) 700 <50 <50 <50 <50 50 Cadmium(ug/1) 2 <0.08 <0.08 0.091 0.092 0.08 Chloride(mg/1) 250 <5 <5 <5 <5 5 Chromium(ug/1) 10 <5 <5 <5 12.4 5 Copper(mg/1) 1 <0.005 <0.005 <0.005 <0.005 0.005 iron(ug/1) 300 <50 56.1 <50 372 50 Lead(ug/1) 15 <5 <5 <5 <5 5 Manganese(udl) 50 <5 <5 1240 70.4 5 Mercury(ug/1) 1 <0.2 <0.2 <0.2 <0.2 0.2 Nickel(ug/1) 100 <5 <5 <5 8.9 5 Nitrate(as N) (mg/l) 10 0.32 <0.2 <0.2 1.2 0.2 Selenium(ug/1) 20 <10 <10 <10 <10 10 Sulfate(mg/1) 250 <5 <5 13.5 <5 5 Thallium(ug/1) 0.2 <0.1 <0.1 <0.1 <0.1 0.1 Zinc(mg/1) 1 <0.010 <0.010 0.0106 0.0168 0.01 TDS(mg/1) 500 114 B 28 B 59 B 328 25 pH(S.U.) 6.5-8.5 5.7 5.64 5.11 5.07 N/A Water Level (ft.) N/A 7.90 1.52 23.97 45.23 N/A Temperature('C) N/A 15.28 14.82 15.14 19.8 N/A Specific Cond. N/A 36 32 96 22 N/A (umhos/cm) Turbidity(NTU) N/A 1.21 1.53 1.22 9.6 N/A 15A NCAC 02L.0202 Groundwater Quality Standards _-- PQL-Practical Quantitation Limit -- ug/I-micrograms per liter mg/l milligrams per liter -- --- ---- - -- - - S.U.-Standard Units NTU_NephelometricTurbidity Unit -- ---- --- -�-- -- - ---- - - -� 2 a7uk r .>q I A. gA 13 .,•t P i$. P M W-2A.,. . . � •..�-._.. •vt- - ,.. '. -. : Y, r�,' [ 7 � f• �:'.i--'-" d ta+M ,� An, W 1A ; ,'q � Y4, �\ w �-Eay w"�+•� I`� -n^*._, ^-y .-_ ,1 r ., -, '' '.r� -_• Tim , �'-♦ i / ,,,r�s/� � ,� • 3r }y MW-S rp �♦ ♦ 6 RCP,I�'I / `/ / r/r = +C °s �`t' tr c` p r 42108.63 �"+ ♦. ♦ - ®r/ y� / `�/ -e :N� t� • }N 9- `:� ' 4' ♦ ° ♦ �` ♦` Y=,,� Zj` i ,,,;-(..•, t - - '.,r�`1l, ` , ..:, �. • -:_. •' si / : r sN moist 'L..., Ct,`11�t,,, • ,'_•� ;}�^ld®� ��♦� ♦ ��.i >:/ �°•/ i rrr\= s sti :"m � ; "� �� } Af 41 ®{ s. .. f {'_ q: .I* I `♦•♦ ��i� / /• • ° A c dv O • I. - tr� w �- o � r }1 a 5f,i� ♦� / • i '• a 4�1 .o S � •r \ � `.� �, • s`� �-/-�� .~ _ 1 m +• ♦ o-- o/ • • °- r, 1.1 �. ' LEGEND - 1 i:' ♦ •`I ' e •c+!. - t� ' a , fr; ® MW4A MONITORING WELL ' • • c c 't +' :. 2127.58 WATER ELEVATION IN FEET(msl.) Al y ♦ a } d ® a` , ___ WATER LEVEL CONTOUR IN FEET(msl.) ♦ -`' : ®as :{i p} * (2FT CONTOUR INTERVAL) 7.�.� .A .......... COAL COMBUSTION PRODUCT LIMITS a `� ®�o o REVIEW BOUNDARY t O o COMPLIANCE BOUNDARY d 'f PROPERTY LINE(APPROXIMATE) ;iS —MW-4A! !! CyVa SOURCES: 12127.58I 2010 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE ARCS GEOSPATIAL DATA GATEWAY AT httpY1datagateway.n=.mda.goW `'�' J� ' �II` WELL LOCATIONS,COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND �r r COMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING TITLED'GROUNDWATER FLOW +,s..` F y ,>a,3 �',1 .I', ; _ a -�,or, _ -•Y-,r' _ y ,, MAP STRUCTURAL FILL%DATED 12-16-2010. 'V" t "g�' >fi4 - r ' i�� �_ •t 70o GRAPHIC SCALE 200 IN EE PROGRESS ENERGY 4, 148 RIVER STREET.SUITE 220 STRUCTURAL FILL-AREA I - GREENVILE SOUTH CAROONA29601 WATER LEVEL MAP-NOVEMBER 9,2011 PHONE 8644219999 - �w..mt n ASHEVILLE REGIONAL AIRPORT a , sO,SnTe °"T"'/'°�°' ARDEN,NORTH CAROLINA * _" +� E%ISTING Y Y ; 9.'3S �` •t z 'OasW..�—�:` MW-2A �5s V 'yi• �.d". } '�' A Maq l � �T i q ea� "2101.19 t t11 � 1 t° , Ss sL y} �r°♦ mw r+u + �2108 63 �♦_�♦o�o s� ♦!♦`yry''`e�. ���0�/ , . } +o `t �`'`��..:,� +' �t1 AI 5 S` } ♦ a i. t � to dl ♦ cl . bj$ - _ ♦ ♦ yyy a � 1 - - t �,- y r 4 � /a a i o �I _ � � �L S� r'r�d :�' t tt3.± �� •e 3 / A. .' l A I ��i i ♦ / 0 e i �r �'' l LEGEND Y +' , MW4A MONITORING WELL ':.\ Q t Ir.1 t•a ♦' �/ I �. a�oo!. t� r J i '" a ° � �,� �<�g+„ � �•-�. 2127.58 WATER ELEVATION IN FEET(msl.) it`� ♦ / t! ® j :, ` WATER LEVEL CONTOUR IN FEET(msl.) ' r yq '• �, 1 O`/ ��� / t 4 (2FT CONTOUR INTERVAL) e7 yA g' t •••••.•••• COAL COMBUSTION PRODUCT LIMITS —®®m m REVIEW BOUNDARY r; - i t O ':� ✓ �® y s"'"" 1 COMPLIANCE BOUNDARY } PROPERTY LINE(APPROXIMATE) I , MW 4AA� _ 'S e SOURCES: ® 2127.55 ' 'Y{'i ® 4#, } '.. ' y 2010 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAY AT �! hftp.Y/data9afewaYnrcs.usda.9ov/ t. WELL LOCATIONS COAL COMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND y COMPLIANCE BO NDARY TAKEN FROM S&ME DRAWING TITLED%ROUNDWATER FLOW ;' . t _ 1. ` +' !,� — ,-�• -•T MAP STRUCTURAL FILL",DATED 12-16-2010. �� , (1 fL•. GRAPHIC SCALE �+. o0 o iao zoo PROGRESSENERGY Ly' STRUCTURAL FILL-AREA I l 1., 148 RIVER STREET.SUITE fHONE 220 '� PREENVI-F,SOU9T9H9C ROLINA29601 WATER LEVEL MAP-NOVEMBER 9,2011 A Y� P SHEVILLE REGIONAL AIRPORT st I �£ /C1Tef'�d °^ °"°° ARDEN,NORTH CAROLINA �7 % TING I,s MW A-TS 2j'j2Tirj' M I 2W A r _ray A ki —4f 40p-' 'A. 118'RcP:AW -IMW5 tMO 6 3 Iv- st V, Z7 % V, It A ov N j. of, :7 V A" 'v o, 40' ok ool Aj f ZQ r ; ; LEGEND %\ I I MVV-4A MONITORING WELL .1 o;v e It 2127.68 WATER ELEVATION IN FEET(msl.) WATER LEVEL CONTOUR IN FEET(msl.) (2FT CONTOUR INTERVAL) .......... COAL COMBUSTION PRODUCT LIMITS 1 REVIEW BOUNDARY oll vio COMPLIANCE BOUNDARY PROPERTY LINE(APPROXIMATE) W-4K 7 15 SOURCES: 127 2010 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPAT1AL DATA GATEWAYAT t 2,11 htIpY1daIagateway—uscfa.gov1 I, k WELL LOCATIONS,COALCOMBUSTION PRODUCTS LIMITS,REVIEW BOUNDARY AND COMPLIANCE BOUNDARY TAKEN FROM S&ME DRAWING TITLED'GROUNDWATER FLOW MAP STRUCTURAL FILL",DATED 12-16-2010. GRAPHIC SCALE o loo 2oo PROGRESS ENERGY ma STRUCTURAL FILL-AREA I 145 RIVER STREET.SUITE 220 GREENVILLE SOUTH CAROUNA 29601 WATER LEVEL MAP-NOVEMBER 9,2011 Wn PHONE864d219999 ASHEVILLE REGIONAL AIRPORT ena ARDEN,NORTH CAROLINA JVFc-D C� Progress Energy q Certified Mail: 7009 0080 0001 2486 2412 V Asheville Regional Office File Pt.: 12520-Q May 17, 2011 Aguifer Protection Mr. G. Landon Davidson NC DENR/DWQ-Aquifer Protection Section 2090 U.S. 70 Highway Swannanoa,NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Area I Fill Project April 2011 Groundwater Monitoring Results Dear Mr. Davidson: Attached are results from the fourth semi-annual groundwater monitoring sampling event, conducted on April 11, 2011, of wells near the Area I coal ash structural fill at the Asheville Regional Airport. Included in this sampling event were down-gradient wells MW-IA, MW-2A and MW-5 along with up-gradient well MW-4A (for reflecting ambient conditions). All of these wells are located within the compliance boundary around the Area I ash fill project. The table below summarizes parameters detected above groundwater quality standards. Well/Parameter pH Chromium Iron Manganese Mercury Groundwater 6.5—8.5 10 300 50 1 Quality Standard (ug/1) MW-lA 5.59 --- --- --- --- MW-2A 5.68 --- 609 --- --- MW-4A 4.96 --- 381 2,340 1.5 MW-5 4.97 10.2 353 74.5 --- All results from this sampling event are summarized on the following page. A groundwater contour map as prepared by SynTerra Corp. for this sampling event is attached as well. Our next sampling event is scheduled for November 2011. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. Sincerely, 4Gn3 A. Whisnant Asheville Plant Manager Attachments Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter May 17,2011 (--Date Parameter ' .0202 Limit Well MWIA Well MW2A Well MW4A Well MW5 PQL 411112011 Arsenic (u ll) 10 <5 <5 <5 <5 5 j 411112011 Barium u ll 700 10.8 18.5 40.5 22.6 5 _ j 411112011 Boron u /I 700 <50 <50 <50 <50 50 j 4/1112011 Cadmium u /I 2 <0.08 <0.08 0.39 <0.08 0.08 1411112011 Chromium u 1l 10 <5 <5 <5 10.2 5 j 4/11/2011 Copper m /I 1 <0.005 <0.005 <0.005 0.0214 0.005 4/1112011 Iron u ll 300 136 609 381 353 50 4/11/2011 Lead u /I 15 <5 <5 <5 <5 5 j 4/11/2011 Manganese u 11 50 8.6 11.7 2340 74.5 5 I 4/11/2011 Mercury u /I 1 <0.2 <0.2 1.5 <0.2 0.2 j 4/1112011 Nickel u /I 100 <5 <5 <5 7.2 5 j 411112011 Nitrate as N (m l) 10 <0.1 <0.1 <0.1 1.5 0.1 j 411112011 Nitrite as N m /l 1 <0.1 <0.1 <0.1 <0.1 0.1 j 411112011 Selenium u /I 20 <10 <10 <10 <10 10 _ j 4/11/2011 Silver u /I 20 <5 <5 <5 <5 5 j 4/1112011 Sulfate m /l 250 <5 <5 6.9 <5 5 j 4/1112011 Zinc m /I 1 <0.010 <0.010 <0.010 0.0486 0.01 I 4/11/2011 TDS m 11 500 28 69 60 <25 25 j 4/11/2011 TOC m /l NIA 1.6 12 8.2 <1 1 4/11/2011 pH S.0 6.5-8.5 5.59 6.68 4.96 4.97 NIA j 4/11/2011 Water Level ft. N/A 8.00 1.58 21.88 39.21 NIA j 4111/2011 Tern C N/A 16.65 17.63 19.23 20.96 NIA j 4/11/2011 Specific Cond. N/A 27 40 56 26 N/A umhos/cm I 4/11/2011 Turbidity NTU N/A 3.68 15.3 12.1 9.92 NIA _ 1 j �'15A NCAC 02L.0202 Groundwater Quality Standards TDS=Total Dissolved Solids- _ TOC=Total Organic Carbon j N/A= Not Applicable _ PQL=Practical Quantitation Limit as provided by Pace Analytical Services,inc. As of January 1,2010,following changes went into effect: 12L Groundwater Interim Maximum Allowable Conc. I(MACS: j Arsenic standard went from 0.05 mgll to 0.01 Mg/l Antimony_1 ug/I Established August 1,2010) rBarium standard went from 2 mg/I to 0.7 mg/I IThallium- 0.2 ug/l Established October 1, 2010) Boron standard went from 0.316 mg/l to 0.7 mgll Chromium_standard went from 0.06 mg/1 to 0.01 mg/I Selel m standard ,vent from 0.05 mg/I to 0.02 mg/1 2 F♦ T ♦ CULVERT{ �. T 1 Y .�`� � %weinw"u°osp�MW 2A A +. \♦;., F -a _:.r.� _ r MW 1A 1 �rl�J 1 �T i_ ■4)=3:4' 1 .. ' g i I2092.401 r •''�/ ill ...... !. -`y 1 k •• -a .. y x gcP(i 21 �MW14.651 1 �1 1�� � �- • • / • \ \�'�,, u . yr . j 1 / 1 1, 1��.-\., .zToo ♦ I�/ /i � T,` �\ - • .;� _ �; I + v yl Z1y4'�t w,lt�l`5 ! , \�-.1�\ \ � ���� o.�f � ,e� \ `S3r Rs' �' •- - _., Y_ -" - 66 is 1 ♦ I . ■ <; 1 •2120 LEGEND Cf i i..►�'� r S t` J MW-4A MONITORING WELL E --- • .:R , « I T -� 0 2129.67 WATER ELEVATION IN FEET(msl.) is .,,'- 'Ix WATER LEVEL CONTOUR IN FEET(msl.) 1 e _ i s r '+: a •1J :$. /�■ i ----- (2FT CONTOUR INTERVAL) ow •........• COAL COMBUSTION PRODUCT LIMITS • � 1 -- -' -`` r- �'' �^:�a s _, s 1' {� ����� REVIEW BOUNDARY O- / � w•g Rwx -•� COMPLIANCE BOUNDARY ♦ ~Y y3 PROPERTY LINE(APPROXIMATE) •I ® MW;4A vY 'r% SOURCES: 2129.67 _ '-1 ♦- .�4� 2010 AERIAL PHOTOGRAPH WAS OBTAINED FROM THE NRCS GEOSPATIAL DATA GATEWAYAT a® I hUpl/dafagale ynra.usda.gov1 • 1 x!. WELL LOCATIONS.COAL COMBUSTION PRODUCTS LIMITS.TTLEO GBOUNDARYAND * COMPLIANCE BOUNDA,RY TAKENDATED 1 FROM S&ME DRAWING TRLED'GROUNDWATER FLOW MAP STRUCTURAL FILL°,DATED 12-16-2010. GRAPHIC SCALE 1•, I00 0 10o 200 PROGRESS ` RGY STRUCTURAL ILL-AREA 14S RIVER STREET,SURE 220 GRE—ILLE.SOUTH C ROTIIJA29601 a � - WATER LEVEL MAP-APRIL 11,2011 yy PHONE864d21-9999 �+ wr•Ta�a�m.�m ASHEVILLE REGIONAL AIRPORT •" Til' Syr1TeY1�d ARDEN,NORTH CAROLINA rx County: BUNCOMBE Sample ID: AB70289 River Basin �04 LVATip4. PO Number# 11G0270 Report To AROAP F Date Received: 0411312011 r C >_ Time Received: 08:30 Collector: B LAVERTY =i. Region: ARO Labworks LoginlD DLEAVITT Sample Matrix: GROUNDWATER Report Generated: 5/4/11 Loc.Type: MONITORING WELL Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: IC11ASHEVILLEAIRPORTMWIA Collect Date: 04/11/2011 Collect Time: 16:34 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.9 'C 4/13/11 DLEAVITT MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7429-90-5 Al by ICP 50 100 ug/L EPA 200.7 4/15/11 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-38-3 Ba by ICP 10 12 ug/L EPA200.7 4/15/11 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15111 ESTAFFORDI 7439-89-6 Fe by ICP 50 85 ug/L EPA200.7 4/15/11 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/19111 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 1.3 mg/L EPA200.7 4/15/11 ESTAFFORDI 7439-96-5 Mn by ICP 10 IOU ug/L EPA200.7 4/15/11, ESTAFFORDI 7440-23-5 Na by ICP 0.10 1.7 mg/L EPA200.7 4/15/11 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-36-0 Sb by ICPMS 10 10 U ug/L EPA200.8 4/15/11 ESTAFFORDI 778249-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-28-0 Thallium(TI)ICPMS 10 10 U J2 ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 4/15/11 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to tgpILimgo yPcaenr,Qp,(tvet.(�,yylap/�fa�n Le,ha;lttgpaea_gux+finer togef<hFe;/lusdal,ero?__xL�4l.•N_:L�ahLstannp:./feo-a_isn Page 1 of 1 County: BUNCOMBE Sample ID: AB70230 River Basin �QF LVa,T�,�, PO Number# ARO Report To AROAP �O q Date Received: 0 411 2/2 011 °- Time Received: 08:00 Collector: B LAVERTY "`I' Labworks LoginiD KJIMISON Region: ARO Report Generated: 5/11/11 Sample Matrix: GROUNDWATER L Date Reported: 1 2/2 812 0 11 oc.Type: MONITORING WELL Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 61 TERMINAL DRIVE FLETCHER,NC Location ID: IC11ASHEVILLEAIRPORTMWIA Collect Date: 04/11/2011 Collect Time: 16:34 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 1.3 °C 4/12111 DLEAVITT Turbidity 1 3.4 NTU APHA2130B-20th 4/13111 CGREEN Residue—Suspended In liquid 6.2 8 mg/L APHA2540D-20th 4/18/11 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed desedplion orthe qualifier codes refer to�taa[_[ponaLnmi...j,.mr or°/w—e—mm iLtJga:ffnfio/�e,hP, L*�goata_ga!M9T,co.Pns 5h!p.Y poraLaOwnr.ozwNiehl•:wLl?1z gdl!Pcbassi:r.• Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW1A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number El soil El Emergency Quad No Serial No. Other Date Received Time: er Lat. Long. Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 4:34 PM Baseline, Complaint, Co�lia� LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport circle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.lo °C Odor Description of sampling point: Monitoring well MW1A Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Y Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /loom] Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /looml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L _ Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L X Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW1A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe X Water(Ground Water) Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 4 Date Received Time: Lat. Long. ElOther Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus,Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 4:34 PM Baseline, Complaint, Co-m lia�nce LUST, Pesticide Study, Federal Trust, Other: f FIELD ANALYSES Owner: Asheville Airport `circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.lo °C Odor Description of sampling point: Monitoring well MW1A Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /loom[ Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 • mg/L Ni-Nickel u /L I TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write°DIS°in block. County: BUNCOMBE Sample ID: AB70288 River Basin PO Number# 11G0269 Report To AROAP �O� QG Date Received: 04/13/2011 y Time Received: 08:30 Collector: B LAVERTY Y Region: ARO Labworks LoginlD DLEAVITT Sample Matrix: GROUNDWATER Report Generated: 5!4/11 D Loc.Type: MONITORING WELL ate Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1C11ASHEVILLEAIRPORTMW2A Collect Date: 04/11/2011 Collect Time: 16:26 Sample Depth CAS# Analvte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB' Sample temperature at receipt by lab 0.9 °c 4113/11 DLEAVITT MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 4115/11 ESTAFFORDI 7429-90-5 Al by ICP 50 1000 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-38-3 Ba by ICP 10 16 ug/L EPA200.7 4/15/11 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4115111 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7439-89-6 Fe by ICP 50 560 ug/L EPA200.7 4/15/11 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/19/11 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 1.4 mg/L EPA200.7 4/15/11 ESTAFFORDI 7439-96-5 Mn by ICP 10 12 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-23-5 Na by ICP 0.10 4.9 mg/L EPA200.7 4/15/11 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-36-0 Sb by ICPMS 10 IOU ug/L EPA200.8 4/15/11 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15111 ESTAFFORDI 7440-28-0 Thallium(TI)ICPMS 10 10 U J2 ug/L EPA200.8 4/15111 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 10 ug/L EPA200.8 4/15/11 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to h5e/L.P.arta;,ncdenr,,q;pfjv_gb/y�yflabJstaf7,nflo(te_h;3sltnDafa C�,ua':Ifier coaez<nep;((_porcz),n5;�lenr;o.;Jyt b�Aanq hyafinfio/jgchasq�:r._ Page 1 of 1 County: BUNCOMBE Sample ID: AB70229 River Basin O4 WATER PO Number# ARO Report To AROAP `Oa Q Date Received: 0 411 2/2 011 r Collector: B LAVERTY Time Received: 08:00 �i 'C Labworks LoginlD KJIMISON Region: ARO Report Generated: 5/11/11 Sample Matrix: GROUNDWATER Loc.Type: MONITORING WELL Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 61 TERMINAL DRIVE FLETCHER,NC Location ID: 1C11ASHEVILLEAIRPORTMW2A Collect Date: 04/11/2011 Collect Time: 15:26 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 1.3 oc 4/12111 DLEAVITT Turbidity 1 20 NTU APHA2130B-20th 4/13/11 CGREEN Residue—Suspended in liquid 6.2 24 mg/L APHA254oD-20th 4/18/11 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to bpx.j_yoda!,Pcdenr.,qrp,(wetJy�uflabfstafinNo/terhasslstF¢a,Sa_gqa' er,_Co�g$<htp;//y>octal.ncdent,otq[yie}[wojla7[sfafipfioj!ecryassisT, Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW2A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) I%I Routine Lab Number Quad No Serial No. ElSoil ElEmergency 3 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus,Courier, Hand Del.,Other: Purpose: Collector(s): Brett Laverty Date: 0 4/1 112 0 1 1 Time: 3:25 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport circle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.lo °C Odor Description of sampling point: Monitoring well MW2A Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /1oom1 Hardness(non-Garb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /1 ooml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond:95 NMhos/cm Y Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L WAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X. Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46566_ m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X n-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW2A SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 3 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus,Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 3:25 PM Baseline, Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport �circleone) pH 400 Spec. Cond.s4 at 250C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.,o °C Odor Description of sampling point: Monitoring well MW2A Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /loom] Phenols 32730 ug/l Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3as N)620 mg/L Zn-Zinc46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 72o mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE Sample ID: A670286 River Basin 0 WArfi9 PO Number# 11G0267 Report To AROAP � gO� QG. Date Received: 04/13/2011 Time Received: 08:30 Collector: B LAVERTY Region: ARO Labworks LoginlD DLEAVITT Sample Matrix: GROUNDWATER Report Generated: 5/4/11 Loc.Type: MONITORING WELL Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Deser.: ASHEVILLE AIRPORT Location ID: 1C11ASHEVILLEAIRPORTMW4 Collect Date: 04/11/2011 Collect Time: 12:07 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.9 °C 4/13/11 DLEAVITT MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7429-90-5 Al by ICP 50 100 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-38-3 Ba by ICP 10 44 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-43-9 Cd by ICPMS 1.0 1.0 ug/L EPA200.8 4/15111 ESTAFFORD1 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 4115/11 ESTAFFORDI 7439-89-6 Fe by ICP 50 140 ug/L EPA200.7 4115/11 ESTAFFORDI 7439-97-6 Hg 245.1 0.2 1.4 ug/L EPA245.1 4/26/11 ESTAFFORD1 7439-95-4 Mg by ICP 0.10 0.60 mg/L EPA200.7 4115/11 ESTAFFORD1 7439-96-5 Mn by ICP 10 2400 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-23-5 Na by ICP 0.10 6.7 mg/L EPA200.7 4/15/11 ESTAFFORD1 7440-02-0 Ni by ICPMS 2.0 3.9 ug/L EPA200.8 4/15/11 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-36-0 Sb by ICPMS 10 IOU ug/L EPA200.8 4/15/11 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-28-0 Thallium(TI) ICPMS 10 10 U J2 ug/L EPA200.8 4/15/11 ESTAFFORD1 7440-66-6 Zn by ICPMS 10 15 ug/L EPA200.8 4/15/11 ESTAFFORDI Laboratory Section 1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 Fora detailed description of the qualifier codes rererto htn://uonatncdenf.°'Pf¢. o/eecnassista, sa Qua'Ifie gdap:)/o.rtaLncdenLgrq(yieb ab staflSfioftechassisp Page 1 of 1 a County: BUNCOMBE Sample ID: A670227 River Basin wA ,fii4R PO Number# ARO Report To AROAP `4 G Date Received: 04/12/2011 }Collector: B LAVERTY Time Received: 08:00 a ,� , Region: ARO Labworks LoginlD KJIMISON Sample Matrix: GROUNDWATER Report Generated: 5/11/11 Date Reported: 12/28/2011 Loc.Type: MONITORING WELL Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 61 TERMINAL DRIVE FLETCHER,NC Location ID: 1C11ASHEVILLEAIRPORTMW4 Collect Date: 04/11/2011 Collect Time: 12:07 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated,by Qualifier Reference Date Others Sample temperature at receipt by lab 1.3 °C 4/12111 DLEAVITT Turbidity 1 3.0 NTU APHA2130B-20th 4/13/11 CGREEN Residue—Suspended in liquid 6.2 6.2 U mg/L APHA2540D-20th 4/18111 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to hcn;((.,oral.ncaenco;y,(w.et/;gnag[spaFnno[eecrassistanata.,.us;tner„c�sez<hep:[/-ortL'smdgnr,or;,N bL NbAta,[,.nN.-IL%tms l t Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW4 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) DO Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus,Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 12:07PM Baseline,Complaint, Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport circle one) pH 400 Spec. Cond.94 at 25eC Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.io eC Odor Description of sampling point: Monitoring well MW4 Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Organochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 M oom1 Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 n1 /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46562 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46566 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L X Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L X Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW4 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) ICI Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat. Long. ElOther Rec'd By: From:Bus, Courier, Hand Del., IL ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 12:07PM Baseline, Complaint, Com liance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport —('circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher, NC 28732 Temp.to °C Odor Description of sampling point: Monitoring well MW4 Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L �( Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAS Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range - Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. DWO Laboratory �'�,__A County: BUNCOMBE Sample ID: AB70287 River Basin 0 ,WAT , Q PO Number# 11G0268 Report To AROAP CCU Gy Date Received: 0411312011 t_ Time Received: 08:30 Collector. B LAVERTY � `i Labworks LoginlD DLEAVITT Region: ARO Sample Matrix: GROUNDWATER Report Generated: 5/4/11 Loc.Type: MONITORING WELL Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1CIIASHEVILLEAIRPORTMW6 Collect Date: 04/11/2011 Collect Time: 13:39 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.9 °C 4/13/11 DLEAVITT MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7429-90-5 Al by ICP 50 340 ug/L EPA200.7 4/15/11 ESTAFFORDI 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA 200.8 4115/11 ESTAFFORD1 7440-38-3 Ba by ICP 10 27 ug/L EPA200.7 4115/11 ESTAFFORD1 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA 200.8 4/15/11 ESTAFFORDI 7440-47-3 Cr by ICPMS 10 26 ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-50-8 Cu by ICPMS 2.0 29 ug/L EPA200.8 4/15/11 ESTAFFORD1 7439-89-6 Fe by ICP 50 690 ug/L EPA200.7 4/15/11 ESTAFFORD1 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 4/19111 ESTAFFORDI 7439-95-4 Mg by ICP 0.10 1.3 mg/L EPA200.7 4/15/11 ESTAFFORDI 7439-96-5 Mn by ICP 10 83 ug/L EPA200.7 4115/11 ESTAFFORDI 7440-23-5 Na by ICP 0.10 0.83 mg/L EPA200.7 4/15/11 ESTAFFORDI 7440-02-0 Ni by ICPMS 2.0 17 ug/L EPA200.8 4/15/11 ESTAFFORDI 7439-92-1 Pb by ICPMS 2.0 2.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-36-0 Sb by ICPMS 10 10 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7782-49-2 Se by ICPMS 5.0 6.0 U ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-28-0 Thallium(TI)ICPMS 10 10 U J2 ug/L EPA200.8 4/15/11 ESTAFFORDI 7440-66-6 Zn by ICPMS 10 63 ug/L EPA200.8 4/15/11 ESTAFFORDI Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to nio:I/aonal.nmenso„p,(.>J4'tWlaagop�e�ryasststapata�ua�(fier CodeS�pleJ1_nerezlnreien�or�ieb/•.vq(iak(staAy:fj.-chassi:r.• Page 1 of 1 2EA -I- a6oratory.Yection Wu' County: BUNCOMBE Sample ID: AB70228 River Basin adF PO Number# ARO Report To AROAP Date Received: 04H212011 Collector: B LAVERTY > -1, Time Received: 08:00 Q "C Labworks LoginlD KJIMISON Region: ARO Sample Matrix: GROUNDWATER Report Generated: 5/11/11 Date Reported: 12/28/2011 Loc.Type: MONITORING WELL - Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT 61 TERMINAL DRIVE FLETCHER,NC Location ID: 1C11ASHEVILLEAIRPORTMW6 Collect Date: 04/11/2011 Collect Time: 13:39 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date Others Sample temperature at receipt by lab 1.3 °C 4/12/11 DLEAVITT Turbidity 1 8,6 NTU APHA21308-20th 4/13/11 CGREEN Residue—Suspended in liquid 6.2 13 mg/L APHA2540D-20th 4/18111 CGREEN Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to CEnl!_eonai,ncae�r.,;_rg(wepls!s!?1s3?fl�9.:lSssn�git�g�?aca__quz!tFler cqe„y_.rt2JLP-_a4 Ln21ear.sr.aLviWws n/sea fir no to ,asss1sn Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location codes 1C11AshevilleAirportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe I� Water(Ground Water) 04 Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 2 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus,Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 1:39 PM Baseline,Complaint,Compliance LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport tcircle one) pH 400 Spec. Cond.94 at 250C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.lo °C Odor Description of sampling point: Monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L X As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /loom) Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/l Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L X Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L X Cu-Copper 46552 u /L Boron DOC X Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L X Mg-Magnesium 46554 m /L _ Alkalinity to pH 8.3 415 mg/L PO4 as P X Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L X Na Sodium 46556 m L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L X Zn-Zinc 46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(IC): Lab Comments Please add antimony and thallium GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code: 1C11AshevilleAirportMW5 SAMPLE TYPE SAMPLE PRIORITY County: Buncombe Water(Ground Water) X Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency 2 Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑ Chain of Custody Other: Report To:ARO, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO, Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus, Courier, Hand Del., Other: Purpose: Collector(s): Brett Laverty Date: 04/11/2011 Time: 1:39 PM Baseline, Complaint, Compliance, LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner: Asheville Airport circle one) pH 400 Spec. Cond.94 at 25°C Location or Site: 61 Terminal Drive Fletcher,NC 28732 Temp.lo °C Odor Description of sampling point: Monitoring well MW5 Appearance DO, mg/L ORP, mV Sampling Method: external pump Sample Interval Field Analysis By: Remarks LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlodne Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug[l Ca-Calcium 46552 m /L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L X Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L MBAs Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Boron DOC Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 m /L Alkalinity to pH 4.5 410 mg/L Mg-Magnesium 46554 m /L _ Alkalinity to pH 8.3 415 mg/L PO4 as P Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L I Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 uglL Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 u /L Color:True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L NH4-ammonium Silica Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. FIB HECEW c Energy Progress a 9 gY o e zU 1l Certified Mail: 7009 0080 0001 2486 2153 Asheville Regional Office A uifer Proleclion File Pt.: 12520-Q January 5,2011 Mr. G.Landon Davidson NC DENR/DWQ-Aquifer Protection Section 2090 U.S. 70 Highway SWannanoa,NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Area I Fill Project Fall 2010 Groundwater Monitoring Results Dear Mr.Davidson: Attached are results from the third semi-annual groundwater monitoring sampling event of wells near the Area I coal ash structural fill at the Asheville Regional Airport. On November 19,2010 down-gradient wells MW-1A,MW-2A and MW-5 along with up-gradient well MW-4A were sampled. Summarized below are parameters detected above groundwater quality standards. Well/Parameter pH Iron Manganese Groundwater 6.5—8.5 300 50 Quality Standard (ug/1) MW-lA 5.48 --- --- MW-2A 5.45 374 --- MW-4A 4.99 1,020 3,010 MW-5 4.74 771 1 90.6 The following table summarizes all results from this sampling event. All of these wells are located within the compliance boundary around the Area I ash fill project. Also attached are two copies of the report prepared by S&ME, Inc.which include a summary of the sampling event, a groundwater contour map and the laboratory results. The next sampling event is scheduled for spring 2011. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions regarding sampling results. Sincerely, Adto GAL Garry A. Whisnant Asheville Plant Manager Attachments Progress Energy Carolinas,Inc. Asheville Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter January 5,2011 Date Parameter .0202 Limit Well 1u1WIA Well MVd2A Well lit]W4A Well 1dW5 PQL --- -, 11/1912010 Arsenic(u 11) 10 <5 <5 <5 <5 5 1111912010 Barium (u 1l) 700 14.3 19.3 38.6 29.3 5 1111912010 Boron(u II) a l70 <50 <50 <50 <50 50 -� 1111912010 Cadmium(ucjjll. 2 4.08 ,,0,035 0.12 <0.08 0.08 _ 1111912010 Chromium(u II 10 <5 <5 <5 <5 5 1 Ill 912010 Copper(m 1l) 1 <0.005 <0.005 <0.005 <0.005 0.005 l 1111912010 Iron fu fl 300 209 374 1020 771 50 - 11I1912010 Lead u 11) 15 <5 <5 <5 <5 5 1111912010 . Manganese(u 11', 50 10.6 10.6 3010 90.6 5 - l 1111912010 Mercury u 11) 1 <0.2 <0.2 0.39 <0.2 0.2 - 1 1111912010 Nickel u ill) 100 <5 <5 <5 <5 5 1 111 9120 1 0 Nitrate(as N)(m !1, 10 0.1 <0.1 0.16 1.7 0.1 __ I 11I1912010 Nitrite(as N)(m lR 1 <0.1 <0.1 <0.1 <0.1 0.1 11119,1'2010 Selenium(u 1l) 20 <10 <10 <10 <10 10 1111912010 Silver(u 1() 20 <5 <5 <5 <5 5 1 111 9120 1 0 Sulfate(m 11) 250 <5 <5 <5 <5 5 1111912010 Zinc(m II) 1 <0.01 <0.01 <0_010 0.0134 0.01 - ---- 1111912010 TDS(m 11) 500 28 37 43 <25 25 1111912010 TOG(m fl) NIA 1.4 14.5 3.1 1.2 1 1111912010 H S_U, 6.5-8.5 5.48 5.45 4.99 4.74 NIA 1111912010 Water Level ft. NIA 6.59 2.10 23.98 40.92 NIA 1 111 912 0 1 0 Temp G) NIA 14.27 13.80 14.59 13.24 NIA _ ^� Specific Cond. 11/1912010 umhoslcm) NIA 23 27 40 20 N/A 1 111 9/20 1 0 Turbidity NTU' NIA NS** NS** NS- 9.19 N1A 2L.0202 Groundwater Quality Standards � � j- T_DS=Total Dissolved Solids I TOG=Total Organic Carbon k* Do to an instrument malfunction,turbidity readings were not collected. NA=Not!.faplicable PQL=Practical Quantitation Limit as provided by Pace Analytical Services, Inca As ofJanuary�1,2010,following changes went into effect_ 2L Groundwater Interim Maximum Allowable Conc. (INIACIC-1 Arsenic standard went from 0.05 mg/1 to 0.01 mgll Antimony-1 ugll (Established August 1,20101, 1 Barium standard went from 2 mgll to 0.7 mg Thallium-0.2 ug11 (Established October 1,2010k Boron standard went from 0.315 mg/1 to 0.7 mgdl i Chromium standard went from 0.05 mg f7 to 0.01 mgll Selenium standard went from 0.05 mgll to 0.02 mgll ._ 2 , 1 c� APR 0 8 26@ Progress Energy E Asheville Regional Office Certified Mail: 7009 0080 00012486 2009 A t8ifAr P6 rq.,=Ct,e%, File Pt.: 12520-Q April 7,2010 Mr.G. Landon Davidson NC DENR/DWQ-Aquifer Protection Section 2090'U.S.70 Highway Swannanoa, NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Fill Project Spring 2010 Groundwater Monitoring Results Dear Mr. Davidson: Attached are results from the second semi-annual groundwater monitoring sampling event of wells near the coal ash structural fill at the Asheville Regional Airport. On March 9, 2010 down-gradient wells MW- 1A, MW-2A, and MW-5 along with up-gradient well MW-4A were sampled. During the sampling process,turbid water was encountered in wells.MW-4A and,MW-5. We have notified the contractor responsible for well installation of the need to develop all 4 wells to remove sediment from the well casings. This activity will be completed prior to the fall 2010 sampling event. While the collected data from both the fall 2009 and spring 2010 sampling events are suspect, please find below a summarization of detected parameters that exceed groundwater quality standards from this recent sampling event. Well/Parameter Iron Manganese Groundwater 0.3 0.05 Quality Standard (mg/1) M W-1A 0.783 --- MW-2A 0.301 --- M W-4A 2.03 8.06 MW-5 1.41 0.166 The table on the following page summarizes all results from this sampling event. All of these wells are located within the compliance boundary around the ash fill project. Our next sampling event is scheduled for fall 2010. Please contact Ms. Laurie Moorhead at 828-687-5240 if you have any questions on the sampling results. Sincerely, Garry A.Whisnant Asheville Plant Manager Progress Energy Carolinas,Inc. Asheville Steam Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter April 7,2010 fJIW-1A MW-2A MWAA -- PAW-5 PQL - Date Parameter m /1* m 11 m 11 m 11 m /l m /I 319/2010 Arsenic 0.01 <0.005 <0.005 <0.005 <0.005 0.005 3/9/2010 Barium 0.7 0.0223 0.0215 0.053 0.0487 0.005 3/9/2010 Boron 0.7 0.0681 0.0714 0.0671 0.0665 0.05 { 3/9/2010 Cadmium 0.00175 <0.001 <0.001 <0-001 <0.001 0.001 i 3/912010 Chromium 0.01 <0.005 <0.005 <0.005 <0.005 0.005 3/9/2010 Copper 1 <0.005 <0.005 <0.005 <0.005 0.005 3/912010 Iron 0.3 0.783 0.301 2.03 1.41 0.05 31912010 Lead 0.015 <0.005 <0.005 <0.005 <0.005 0.005 3/9/2010 Manganese 0.05 0.0327 0.0203 8.06 OA 66 0.005 3/9/2010 Mercury 0.00105 0.00000134 <0.0000005 0.000145 0.00000856 0.0000005 3/9/2010 Nickel 0.1 <0.005 <OA05 0.005 <0.005 0.005 3/9/2010 Nitrate as N 10 <0.1 <0.1 0.36 3 0.1 31912010 Nitrite(as N) 1 <0.1 <0.1 <0.1 <0.1 0.1 C 3/9/2010 Selenium 0.02 <0.01 <0.01 <0.01 <0.01 0.01 31912010 Silver 0.0175 <0.005 <0.005 <0.005 <0.005 0.005 3/9/2010 Sulfate 250 <5.0 <5.0 <5.0 <5.0 5 j 3/912010 Zinc 1-05 <0.01 0.0125 0-0173 0.0219 0.01 3/9/2010 pH (S_U) 6-5-8-5 5.71 5.6 5 07 4.77 NIA 3/9/2010 Tem ( NIA 55.94 53.96 6026 60.8 N/A 319/2010 Water Level(ft.) N/A 5.73 1.13 20.68 36.93 N/A Specific Cond. 3/9/2010 (umhos/cm) NIA 27.8 33.3 53.3 37.8 NIA 3/9/2010 TOG N/A 5.6 <1.0 2 <1.0 1 31912010 TDS N/A 54 40 50 38 20 '15A NCAC 02L_0202 Groundwater Quality Standards TDS=Total Dissolved Solids j TOC=Total____Organic Carbon --� _ NlA=Not Applicable PQL=Practical Quantitation Limit as provided by Pace Analytical Services, Inc. j As of January 1,2010 fallo+rring changes went into effect: - __I__ Arsenic standard went from 0.05 m011 to 0_01 mg/I L_ Barium standard went from 2 mg11 to 0.7 niC l Boron standard went from 0-315 mg11 to 0.7 mg/1 Chromium standard?;vent from 0.05 mg11 to 0.01 m /1g � Selenium standard went from 0-05 mg/l to 0.02 mg/I 2 County: BUNCOMBE , Sample ID: AB55840 River Basin pF W'4TF PO Number# 10GO124 Report To AROAP Q QG Date Received: 03/11/2010 Collector. B LAVERTY Time Received: 08:30 Labworks LoginlD SMATHIS Region: ARO 9 Sample Matrix: GROUNDWATER _ Report Generated: 4/1/10 .. Date Reported: 12/28/2011 Loc.Type: MONITORING WELL Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 11311MW1ATOTAL Collect Date: 03/09/2010 Collect Time: 10:56 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 AI by ICP 50 340 ug/L EPA200.7 3/16110 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10 18 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 2.1 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L -EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 370 ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP 0.10 0.84 mg/L EPA 200.7 3/26/10 ESTAFFORD 7439-954 Mg by ICP 0.10 1.5 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 27 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 2.5 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 778249-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section 1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed tlescription of the qualifier codes refer to ncp;(/port;,l1Ecd nr.o eLy 4§j5Lgfl_n..f o cec ass.�sca�-M guaiifler[odes<h- o ral.ncdancor w ni iafi r fiono r.na sn Page 1 of 1 County: BUNCOMBE Sample ID: AB55841 WATER River Basin E PO Number# 10G0125 Report To AROAP �{?+ %7 Date Received: 03/11/2010 Collector: B LAVERTY ,3 4 v Time Received: 08:30 � `-( � i a Labworks LoginlD SMATHIS Region: ARO Report Generated: 4/1/10 Sample Matrix: GROUNDWATER Date Reported: 12/28/2011 Loc.Type: MONITORING WELL `FM Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P71MW1ADISSOLVED Collect Date: 03/09/2010 Collect Time:- 11:05 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 AI by ICP 50 270 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2,5 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10. 12 ug/L EPA200.7 8/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 2.1 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA 200.8 3/16110 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 190 ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 3/15110 ESTAFFORD 7440-09-7 K by ICP 0.10 0.74 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 1.4 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 12 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 2,6 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to'htp:/f�or4_!.ncd„enr_G,r7[µm„b[w.q!„ia„nl.tafinEorteckmisthoata Ouslifier Codes ehco�orwi.mc r EL e„Wwq hh'st fin5ojtnchassisn Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code 1 e0)I M 1&11/�iO7t A = SAMPLE TYPE SAMPLE PRIORITY County R.,TI C C,M l Water 129 Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat. Long. ❑Other Rec'd By: From:Bus, Courier, Hand Del., El Chain of Custody Other: Report To.ARO FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston Fq rust, Central Off., Other: Date Reported: Shipped by: BusCCouder.Aand Del.,Other. Purpose: Collector(s):_B i_A%j Gt2 L' Date Time I :IF.)� Baseline, Complaint,Compliance LUST, Pesticide Study, Federal Trust,Other. FIELD ANALYSES Owner A si-k eut LLe A 1 Q Dri(Lf- ("rue°"a) pH 40o Spec. Cond.ga at 25°C Location or Site NJI G Eat iA r)A L L&N a t OAF C- -. Temp., °C Odor Description of sampling point M W I_A Appearance Sampling Method P;;&A ra) r;c 1> 4 Sample Interval Field Analysis B : 'T�mo. ai er,ec. Y Y Remarks —ro-r�a� ,�n Ewa c LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOO 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 ug/L Organochiorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 ug/L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 ug/L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 ug/L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/l Ca-Calcium 46552 mg/L PCBs TOC 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 ug/L Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 ug/L Residue,Total Suspended 530 mg/L Sulfide 745 mg/L u-Copper 46562 ug/L e Iron 46563 ug/L Semiwlatile Organics Oil and Grease mg/L Hg-Mercury 71900 ug/L TPH-Diesel Range pH 403 units K-Potassium 46555 mg/L Alkalinityto pH 4.5 410 mg/L g-Magnesium 46554 m qJL Alkalinityto pH 8.3 415 mg/L Mn-Manganese 46565 ug/L Volatile Or anics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 mg/L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel ug/L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NOZ+NO,,as N 630 mg/L Pb-Lead 46564 u - Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium ug/L Chromium:Hex 1032 ug/L Nitrate(NO,,as N)620 mg/L n-Zinc 46567 ug/L Color.True 80 CU Nitrite(NO Z as N)615 mg/L LA8 USE ONLY Cyanide 720 mg/L Temperature on arrival(°C): Lab Comments GW-54 REV.7103 For Dissolved Analysis-submit filtered sample and write"DIS"In block. GROUNDWATER FIELD/LAB FORM North Carolina Department of Environment and Natural Resources Location code i P i i :'M In!t A Di ��I ►i—r DIVISION OF WATER QUALITY-GROUNDWATER SECTION SAMPLE TYPE SAMPLE PRIORITY County_ Water I Routine. Quad No Serial No. ❑ Soil Lab Number Emergency Lat. Long. ❑ Other Date Received Time: Rec'd By: From:Bus, Courier, ;and Del., 9 Report To: RO FRO, MRO, RRO,WaRO,WiRO, Chain of Custody Other: WSRO, Kinston Fed.Trust, Central Off.,Other: Data Entry By: Ck: Shipped by: Bus, Hand Del.,Other. Date Reported: Collector : `r3az�<< Purpose: �s� I—A� -t Date 3 i C9 Time t I',65 Baseline FIELD ANALYSES , Complain, ompliance-%LUST, Pesticide Study, Federal Trust,Other: ' Owner ('role one) p Spec. Cond.94 at 25°C Location or Site N 0 rr rl t c a A i A S EI p(Z 0 I Temp.10 °C Odor Description sampling �� ' Appearance P p g point s��a f t .4 Field Analysis By: Sampling Method PG.A c ra 'r, 11, um ps Sample Interval LABORATORY ANALYSES Remarks_ �; c r E,� M -ro , BOD 310 (Pumping time,air temp.,etc.) mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 COD High 340 m /L u /L Or anochlorine Pesticides 9 Fluoride 951 mg/L AI-Aluminum 46557 COD Low335 u /L Or ano hos horns Pesticides mg/L Hardness:Total 900 mg/L As-Arsenic 46551 Coliform:MF Fecal 31616 /100m1 Hardness non cart 902 u Nitr en Pesticides ( ) mg/L Ba-Barium 46558 Coliform:MF Total 31504 /loom[ Phenols 32730 u /L Acid Herbicides ugA Ca-Calcium 46552 TOC 680 mg/L Specific Cond.95 NMhos/cm 6/ Cd Cadmium 46559 m IL PCBs Turbidity76 NTU u IL Sulfate 945 mg/L v' Cr-Chromium 46559 Residue,Total Suspended 530 mg/L ug/L 9 Sulfide 745 mg/L u-Copper 46562 u /L Fe-Iron 46563 u /L Semivolatile Organics pH 403 units Oil and Grease mg/L H g-Mercury 71900 u /L TPH-Diesel Ran e K-Potassium Alkafinityto pH 4.5 410 mg/L 46565 in L Alkalinity to pH 8.3 415 mg/L _Mg-Magnesium 46554 m L g Carbonate 445 mg/L NH as N 610 Mn=Manganese 46565 u /L Volatile Or anics(VOA bottle,, mg/L Na-Sodium 46556 Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel m IL TPH-Gasoline Ran e Carbon dioxide 405 mg/L NOZ+NO3 as N 630. mg/L PP-Lead 46564 u n- TPH-BTEX Gasoline Range Chloride 940 mg/L P:Total as P 665 u /L mg/L Se-Selenium u 2 Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 m /L 9 Zn Zinc 46567 Color: u IL Cyanide 720 mg/L True 80 CU Nitrite(NOZ as N)615 mg/L LAB USE ONLY Z Temperature on arrival(°C): Lab Comments , t - : . ,-- t ti F t r GW-54 REV.7103 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE f Sample ID: AB55842 River Basin t �y�IWAT�cR PO Number# 10G0126 Report To AROAP QG Date Received: 03/11/2010 t Collector. B LAVERTY v y -` Time Received: 08:30 r.. Labworks LoginlD SMATHIS Region: ARO Sample Matrix: GROUNDWATER Report Generated: 4/7/10 Loc.Type: MONITORING WELL Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P11MW2ATOTAL Collect Date: 0 310 9/2 0 1 0 Collect Time: 12:00 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11110 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 Al by ICP 50 110 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by furnace 2.0 2.0 U ug/L EPA200.9 3/26/10 ESTAFFORD 7440-38-3 Ba by ICP 10 21 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 3.0 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 -10 U ug/L EPA200.8 3/16110 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8• 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 220 ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP 0.10 0.78 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 1.4 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 19 ug/L EPA200.8 3/16110 ESTAFFORD 7440-23-5 Na by ICP 0:10 1.6 mg/L EPA200.7 3/26110 ESTAFFORD 7440-02-0 Ni by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to ht 11 o°rtatncdenr.orehvebiw ian:;afinF°techaeslstFDzta ualifisr codes hpzli a°rtai.ncaenr.or'wenrw/I..maiiailtc ha o Page 1 of 1 County: BUNCOMBE Sample ID: AB55843 River Basin I QF WATFR PO Number# 10GO127 ReportTo AROAP Q� Q y Date Received: 03/11/2010 } � ,-� Time Received: 08:30 Collector. B LAVERTY P "C Labworks LoginlD SMATHIS Region: ARO Sample Matrix: GROUNDWATER Report Generated: 4/1/10 Loc.Type: MONITORING WELL -_ Date Reported: 12/28/2011 Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLEAIRPORT Location ID: 1P71MW2ADISSOLVED Collect Date: 03/09/2010 Collect Time: 12:10 Sample Depth Result/ Method Analysis Validated by CAS# Analyte Name PQL Qualifier Units Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 Al by ICP 50 98 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2.3 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10 21 ug/L EPA200.7 3/16110 ESTAFFORD 7440-70-2 Ca by ICP 0.10 3.1 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 2/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 72 ug/L EPA200.7 3/16110 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 KbyICP 0.10 0.79 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 1.4 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 18 ug/L EPA200.8 3/16110 ESTAFFORD 7440-23-5 Na by ICP 0.10 1.7 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to btogl rortai:hxdenr or°/w°b[wqIlan/nflnfioJ..te<h�ssist#Ma oualftr Codex<hm:q.�o„rgal ncd /webIwo/lah/S:afiafio/mch,,xs'15n Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code 1 P i( M W 2A-TOT&i SAMPLE TYPE SAMPLE PRIORITY County 1 fl C(9 M�— %Water Z Routine Lab Number Quad No Serial No. ❑ Soil ElEmergency S —Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑Chain of Custody Other: Report T :ARO,fRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kins on Fq�.Trust, Central Off.,Other: Date Reported: Shipped by: Bus, uri Hand Del.,Other. Purpose: Collector(s): BPF--r,--r 1_4x(E ilay Dat 00 Time ia: Op Baseline, Complaint, ompliance UST, Pesticide Study, Federal Trust,Other: FIELD ANALYSES Owner A 5"�v l 1 i-au A,aDr, tprtone) - pH 40o Spec. Cond.94 at 250C Location or Site o -ri-t Al As( R p hn 1 a GT Temp.lo °C Odor Description of sampling point M W;P.}{ Appearance Sampling Method De2 r Tic o. ai er.ec.iTP Sample Interval Field Analysis By: Remarks 'Tc, CAL nn _—r pry um LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOO 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 ug/L Or anochlodne Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 ug/L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 ug/L Nitrogen Pesticides Coliform:MF Fecal 31616 /loom) Hardness(non-carb)902 mg/L —ea-Barium 46558 ug/L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/l Ca-Calcium 46552 mg/L PCBs TO 680 mg/L Specific Cond.95 pMhos/cm "Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L v Cr-Chromium 46559 ug/L Residue,Total Suspended 530 mg/L Sulfide 745 mg/L 1/ Cu-Copper 46562 ug/L Fe-Iron 46563 ug/L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 ug/L TPH-Diesel Range pH 403 units K-Potassium 46555 mg/L Alkalinityto pH 4.5 410 mg/L Mg-Magnesium 46554 mg/L Alkalinity to pH 8.3415 mg/L L/ Mn-Manganese 46565 ug/L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 mg/L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 626 mg/L Ni-Nickel ug/L TPH-BTEX Gasoline Range Carbon diopde 405 mg/L NO2+NO3 as N 6.30 mg/L Pb-Lead 46564 ug/L Chloride 940 mg/L P:Total as P 665 mg/L e-Selenium u/L Chromium:Hex 1032 ug/L Nitrate(NO3as N)620 mg/L n-Zinc46567 ug/L Color.True 80 Cu Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L Temperature on arrival(°C): Lab Comments GW-54 REV.7103 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code 1 M SAMPLE TYPE SAMPLE PRIORITY County A0t'l C,fh M n 1= Z Water Routine Lab Number Quad No Serial No. El Soil Emergency Date Received Time: Lat. Long. O Other Rec'd By: From:Bus,Courier, Hand Del., ❑Chain of Custody Other: Report T :ARO iFRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FCQ'Fe�-�rust, Central Off.,Other: Date Reported: Shipped by: Bus, Cowrie and Del.,Other. Purpose: Collector(s):_ t<e-r-r L-A Jr.t2%, Date 31qJ10 Time la.' 10 Baseline, Complaint,Qompll�ance�LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner crdeone) �S H73y o LI A t�2 Den PH 400 Spec. Cond.94 at 250C Location or Site_ . til 1,2-TN Co ,L Ac N P c7 t c-T Temp.lo °C Odor Description of sampling point_ IA W 2_A " Appearance Sampling Method 0 u n �m°T 'f'�-c 120 n;a Sample Interval Field Analysis By: Remarks 1J i 5 S o 1 r Xei.e� LABORATORY ANALYSES (Pumping time,air temp.,etc.) SOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46666 ug/L Or anochlodne Pesticides COD High 340 mg/L Fluoride 951 mg/L V AI-Aluminum 46557 ug/L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 ug/L Nitrogen Pesticides Coliform:MF Fecal 31616 Moorn[ Hardness(non-carb)902 mg/L Ba-Barium 46558 ug/L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ugA Ca-Calcium 46552 mg/L PCBs TOC 680 mg/L Specific Cord.95 FlMhos/cm Cd-Cadmium 46559 u Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 ug/L Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 ug/L Fe Iron 46563 ug/L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 ug/L TPH-Diesel Range pH 403 units K-Potassium 46555 m fL Alkalinity to pH 4.5 410 mg/L g-Magnesium 46554 m [L Alkalinityto pH 8.3 415 mg/L Mn-Manganese 46565 ug/L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610' mglL Na-Sodium 46556 mg/L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Nickel ug/L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L b-Lead 46564 ug/L Chloride 940 mg/L P:Total as P 665 mg/L e-Selenium ug/L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L n-Zinc 46567 ug/L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide720 mg/L Temperature on arrival(°C): Lab Comments E 11,$4 -1 15 M t c-ft n k j, �' I A Z-2 P 6A G.e GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE Sample ID: AB55846 River Basin OF VWAT�9 �r PO Number# 10GO130 Report To AROAP �O� QG Date Received: 0 311112 01 0 Vj Time Received: 08:30 Collector: B LAVERTY i 0 'C Labworks LoginlD SMATHIS Region: ARID Report Generated: 4/1/10 Sample Matrix: GROUNDWATER + Date Reported: 12/28/2011 Loc.Type: MONITORING WELL - ---- -- =' Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P11MW4ATOTAL Collect Date: 03/09/2010 Collect Time: 14:37 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 Al by ICP 50 2900 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10 50 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 0.43 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA 200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 6.9 ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 7600 ug/L EPA 200.7 3116/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP - 0.10 2.1 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 1.1 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 5400 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 0.84 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 10,U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 %u ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 20 ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htp://ponzl.ncdeneor/web/wa/lablrafinfi/techaz ist#Data 4ualifler Codes<htav//portal-de...re/web/wa/lablxaflnn`o/techassisra Page 1 of 1 County: BUNCOMBE Sample ID: AB55847 River Basin �pF WArE�Q PO Number# 10GO131 Report To AROAP Date Received: 0 3/1112 01 0 r_ Time Received: 08:30 Collector. B LAVERTY 1 O Region: ARO Labworks LoginlD SMATHIS Report Generated: 4/1/10 Sample Matrix: GROUNDWATER Date Reported: 12/28/2011 Loc.Type: MONITORING WELL Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P11MW4ADISSOLVED Collect Date: 03/09/2010 Collect Time: 14:46 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 AI by ICP 50 1200 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 4.2 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10 57 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 0.88 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3116/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 3.6 ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 3000 ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA 245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP 0.10 2.6 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 1.3 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 8000 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 1.4 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 21 ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to htod/oortal.ncdenram/weblwo/lab/st Fnflo/techaseatttoata Cmal'fier Codes°h-//aortal ncdenr orelweblwallabistafingo/tcchassisb Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code__.-Q 11 AJl UH T©TA l- SAMPLE TYPE SAMPLE PRIORITY County 1`pp�,) I( n r�- Water A Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat. Long. ❑Other Rec'd By: From:Bus, Courier, Hand Del., ❑Chain of Custody Other: Report T :ARO FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO Fed.Trust, Central Off., Other: Date Reported: Shipped by: Bus Court Hand Del.,Other. Purpose: Collector(s):_Rrz -r LAi/�,r21- Date U Time a -37 Baseline, Complaint, Com lia ��UST, Pesticide Study, Federal Trust,Other. FIELD ANALYSES �— Owner A s N&-v t L-L- A •t_2 D,, PH 400 Spec. Cond.94 at 25°C Location or Site Wr)2-ri-1 coA'i A C H i�2d t E UT, Temp.lo °C Odor Description of sampling point M W L4 A 1.1 Appearance Sampling Method Pa2TA t LI lr 3 ALL 1-2 v 1 Sample Interval Y Y Remartcs Field Analysis B : umo. ai er.e-ro--ram L nn�-r a LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 ug/L Organochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L tL AI-Aluminum 46557 u Or ano hos horus'Pesticides COD Low 335 mg/l- Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 1100ml Hardness(non-cart)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /loom1 Phenols 32730 ugR Ca-Calcium 46552 mg/L PCBs TOC 680 mg/L Specific Cond.95 PMhos/cm Cd-Cadmium 46559 u Turbidity76 NTU Sulfate 945 mg/L 1/ Cr-Chromium 46559 u /L Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 mg/L Alkalinityto pH 4.5 410 mg/L Mg-Magnesium 46554 mg/L Alkalinity to pH 8.3 415 mg/L Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 mg/L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioAde 405 mg/L NOz+NO3 as N 630 mg/L Pb-Lead 46564 ug/L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc46567 u /L Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L Temperature on arrival(°C): Lab Comments GW-54 REV.7103 For Dissolved Analysis-submit filtered sample and write°DIS°in block North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code_( P' 1 SAMPLETYPE SAMPLE PRIORITY County, 1_)U N Gc1^A (-�t= 0 Water X Routine Lab Number Quad No Serial No. 0 Soil El Emergency Date Received Time: Lat. Long. 13 Other Rec'd By: From:Bus, Courier, Hand Del., El Chain of Custody Other: Report To(�Bb, FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO Trust, Central Off.,Other: Date Reported: Shipped by: Bus, off, Hand Del.,Other. Purpose: Collector(s): R(Z —, 1 1 A>,f F�� Date Time A: �-1 (o B seline,-Complai C�1!ian ! LUST, Pesticide Study, Federal Trust,Other: FIELD ANALYSES Owner H - , — crcl ane) pH 40c Spec. Cond.ga at 250C Location or Site Temp.lo IC Odor Description of sampling point M lA 1 y A Appearance Sampling Method "l L_ P Sample Interval Field Analysis By: Remarks 01 ss n `. LABORATORY ANALYSES `t (Pumping time,air temp„etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 qgvL Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L AI-Aluminum 46557 u /L Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 u /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100m1 Hardness(non-carb)902 mg/L a-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ugn Ca-Calcium 46552 mg/L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u 2 Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units K-Potassium 46555 mg/L Alkalinity to pH 4.5 410 mg/L g-Magnesium 46554 mg/L Alkalinity to pH 8.3 415 mg/L Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 mg/L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L b-Lead 46564 ugA Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc46567 ug/ Color:True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L Temperature on arrival(°C): Lab Comments 15, iiEsLED U 1TY1 AA t r a 14 F_ A GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. County: BUNCOMBE Sample ID: AB55844 River Basin �QF VVATRQ PO Number# 10G0128 Report To AROAP �O Gy Date Received: 03/11l2010 r Time Received: 08:30 Collector. B LAVERTY l O Y Labworks LoginlD SMATHIS Region: ARO Sample Matrix: GROUNDWATER Report Generated: 4/1/10 Date Reported: 12/28/2011 Loc.Type: MONITORING WELL Emergency Yes/No ViisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P11MW5TOTAL Collect Date: 03/09/2010 Collect Time: 13:23 Sample Depth CAS# AnalVte Name PQL Result/ Units Method Analysis Validated by Qualifier. Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 Al by ICP 50 160 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-38-3 Ba by ICP 10 44 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 0.78 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.3 ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 110 ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP 0.10 0.89 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 2.0 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 130 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 1.7 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 IOU ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 18 ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section>>1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes refer to he: oml.ncdeor.ore/webL.-vb�sc>Fnfyltechawbt#Data Dvallfier Codes<hro:r/non l.ncdenr.ore/;veb/wo/IabR.,,afb Jt�chazsisb Page 1 of 1 ,;+-_/m County: BUNCOMBE = Sample ID: AB55845 River Basin ��F NIATF iO PO Number# 10GO129 Report To AROAP �O Gy Date Received: 03/11/2010 i Time me Received: 08:30 Collector. B LAVERTY yO -�•; Labworks LoginlD SMATHIS Region: ARO Sample Matrix: GROUNDWATER r Report Generated: 4/1/10 Date Reported: 12/28/2011 Loc.Type: MONITORING WELL - -- --- Emergency Yes/No VisitlD COC Yes/No Loc.Descr.: ASHEVILLE AIRPORT Location ID: 1P11MWSDISSOLVED Collect Date: 03/09/2010 Collect Time: 13:27 Sample Depth CAS# Analyte Name PQL Result/ Units Method Analysis Validated by Qualifier Reference Date LAB Sample temperature at receipt by lab 0.4 °C 3/11/10 SMATHIS MET 7440-22-4 Ag by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7429-90-5 Al by ICP 50 82 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-38-2 As by ICPMS 2.0 2.0 U ug/L EPA200.8 3/16/10 ESTAFFORD' 7440-38-3 Ba by ICP 10 42 ug/L EPA200.7 3/16/10 ESTAFFORD 7440-70-2 Ca by ICP 0.10 0.87 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-43-9 Cd by ICPMS 1.0 1.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-47-3 Cr by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-50-8 Cu by ICPMS 2.0 2.1 ug/L EPA200.8 3/16/10 ESTAFFORD 7439-89-6 Fe by ICP 50 50 U ug/L EPA200.7 3/16/10 ESTAFFORD 7439-97-6 Hg 245.1 0.2 0.20 U ug/L EPA245.1 3/15/10 ESTAFFORD 7440-09-7 K by ICP 0.10 0.89 mg/L EPA200.7 3/26/10 ESTAFFORD 7439-95-4 Mg by ICP 0.10 2.0 mg/L EPA200.7 3/16/10 ESTAFFORD 7439-96-5 Mn by ICPMS 10 120 ug/L EPA200.8 3/16/10 ESTAFFORD 7440-23-5 Na by ICP 0.10 1.8 mg/L EPA200.7 3/26/10 ESTAFFORD 7440-02-0 Ni by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7439-92-1 Pb by ICPMS 10 10 U ug/L EPA200.8 3/16/10 ESTAFFORD 7782-49-2 Se by ICPMS 5.0 5.0 U ug/L EPA200.8 3/16/10 ESTAFFORD 7440-66-6 Zn by ICPMS 10 19 ug/L EPA200.8 3/16/10 ESTAFFORD Laboratory Section-1623 Mail Service Center,Raleigh,NC 27699-1623 (919)733-3908 For a detailed description of the qualifier codes referto hto://con l.ncdenr.ore/web/wanabJraansw/te Qualifier Codes<hto://oortal.ocdenrarelweb/wo/lab/mfinn"o/techassisb Page 1 of 1 North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code 1 f w�i I P)`T A l_ SAMPLE TYPE SAMPLE PRIORITY County v w C-U P l E= Water Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency Date Received Time: Lat Long. ❑Other .15 Rec'd By: From:Bus, Courier, Hand Del., ❑Chain of Custody Other: Report T :AR , FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO d.Trust, Central Off., Other: Date Reported: Shipped by: Bu , ourier Hand Del.,Other. Purpose: Collector(s):'R2E-r-r L.A�t F_.? Date 319 i Time_ i`. "', Baseline, Complain, m ffpnce�LUST, Pesticide Study, Federal Trust, Other: FIELD ANALYSES Owner A S H F_�v t l A (d"I'"e) PH aoo Spec. Cond.ga at 25eC Location or Site fro 2TN Cn A' R. I-t 4>TLc j izr -r Temp.lo eC Odor Description of sampling point NA\A t Appearance Sampling Method w Sample Interval Field Analysis By: Remarks_ Tv-ra-i_ M Ta��°"°tea'e`•e`• LABORATORY ANALYSES (Pumping time,airtemp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L Ag-Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L r/AI-Aluminum 46557 upill. Or ano hos horus Pesticides COD Low 335 mg/L Hardness:Total 900 mgfL As-Arsenic 46551 u /L Nitro en Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100m1 Phenols 32730 ugll Ca-Calcium 46552 mg/L PCBs TOG 680 mg/L Specific Cond.95 pMhos/cm Cd-Cadmium 46559 u /L Turbidity76 NTU Sulfate 945 mg/L r/ Cr-Chromium 46559 u 2 Residue,Total Suspended 530 mg/L Sulfide 745 mg/L 'Cu-Copper 46562 u /L Fe-Iron 46563 u /L Semiwlatile Organics Oil and Grease mg/L Hg Mercury 71900 u /L TPH-Diesel Range pH 403 units K Potassium 46555 mg/L Alkalinity to pH 4.5 410 mg/L g-Magnesium 46554 mg/L Alkalinity to pH 8.3 415 mg/L Mn-Manganese 46565 u /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L "Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 4.05 mg/L NO2+NO3 as N 630 mg/L Li Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L C/ Se-Selenium u/L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L ✓Zn-Zinc 46567 u 2 Color.True 80 CU Nitrite(N%as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L Temperature on arrival(°C): Lab Comments GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write"DIS"in block. North Carolina GROUNDWATER FIELD/LAB FORM Department of Environment and Natural Resources DIVISION OF WATER QUALITY-GROUNDWATER SECTION Location code 1 P i I M'1A!E)i>15,Sn i j ED SAMPLE TYPE SAMPLE PRIORITY County I t)NI(In /A2;r 0Water 9 Routine Lab Number Quad No Serial No. ❑ Soil ❑ Emergency _ Date Received Time: Lat. Long. ❑ Other Rec'd By: From:Bus, Courier, Hand Del., ❑Chain of Custody Other. Report To ARO FRO, MRO, RRO,WaRO,WiRO, Data Entry By: Ck: WSRO, Kinston FO Fed.Trust, Central Off.,Other: Date Reported: Shipped by: Bus, Courier Hand Del.,Other. Purpose: Collector(.,):_rL3 E r-r L.,-,\fF 9=zTq Date-37 Time t a"7 .Baseline, Complaint, Complianc LUST, Pesticide Study, Federal Trust,Other: FIELD ANALYSES Owner 0 � r Q D�ar --* PH 40o Spec. Cond.94 at 250C Location or Site f3 o 2 Ti-1 c-6 A t A c 0 P fzn 1 eCT Temp.lo eC Odor Description of sampling point IV1 M S Appearance Sampling Method P Ll. P�tAA(J Sample Interval Field Analysis By: Remarks i S n 1 I�r M E Ado. LABORATORY ANALYSES (Pumping time,air temp.,etc.) BOD 310 mg/L Diss.Solids 70300 mg/L g Silver 46566 u /L Or anochlorine Pesticides COD High 340 mg/L Fluoride 951 mg/L 7j7 AI-Aluminum 46557 u /L Or ano hos horns Pesticides COD Low 335 mg/L Hardness:Total 900 mg/L As-Arsenic 46551 /L Nitrogen Pesticides Coliform:MF Fecal 31616 /100ml Hardness(non-carb)902 mg/L Ba-Barium 46558 u /L Acid Herbicides Coliform:MF Total 31504 /100ml Phenols 32730 ug/I Ca-Calcium 46552 mg/L PCBs TOC 680 mg/L Specific Cond.95 NMhos/cm Cd-Cadmium 46559 u /L Turbidity 76 NTU Sulfate 945 mg/L Cr-Chromium 46559 u /L Residue,Total Suspended 530 mg/L Sulfide 745 mg/L Cu-Copper 46562 u /L Fe-Iron 46563 u /L Semivolatile Organics Oil and Grease mg/L ✓ Hg-Mercury 71900 u /L TPH-Diesel Range pH 403 units I K-Potassium 46555 mg/L Alkalinityto pH 4.5410 mg/L Mg-Magnesium 46554 m IL Alkalinity to pH 8.3 415 mg/L Mn-Manganese 46565 /L Volatile Organics(VOA bottle Carbonate 445 mg/L NH3 as N 610 mg/L Na-Sodium 46556 m /L TPH-Gasoline Range Bicarbonate 440 mg/L TKN as N 625 mg/L Ni-Nickel u /L TPH-BTEX Gasoline Range Carbon dioxide 405 mg/L NO2+NO3 as N 630 mg/L Pb-Lead 46564 u /L Chloride 940 mg/L P:Total as P 665 mg/L Se-Selenium u /L Chromium:Hex 1032 ug/L Nitrate(NO3 as N)620 mg/L Zn-Zinc 46567 ug/L Color.True 80 CU Nitrite(NO2 as N)615 mg/L LAB USE ONLY Cyanide 720 mg/L Temperature on arrival CC): Lab Comments-„46QG.n wt'ft-1 LIS MtGQGv E, I+tlt_ 4ez-- GW-54 REV.7/03 For Dissolved Analysis-submit filtered sample and write°DIS"in block. ` &41 7Regional Progress Energy [Ashevill.efice Certified Mail:7006 0100 0003 6098 5940 January 11;20T �F9 File Point: 12520-Q Mr.G. Landon Davidson NC DENR/DWQ-Aquifer Protection Section 2090 U.S.70 Highway Swannanoa, NC 28778 RE: Progress Energy Asheville Steam Electric Plant Asheville Airport Fill Project Fall 2009 G.roundwater Monitoring Results Dear Mr. Davidson: Attached are results for the initial sampling event of wells near the coal ash structural fill at the Asheville Regional Airport. On November 30, 2009 down-gradient wells MW-1A, MW-2A and MW-5 along with up-gradient well MW-4A were sampled. The table below summarizes parameters detected above groundwater quality standards. Well/Parameter Iron Lead Manganese Groundwater 0.3 0.015 0.05 Quality Standard (mg/1) MW-1A 20.8 0.0371 1.01 MW-2A 2.21 --- 0.0778 MW-4A 0.667 0.0178 8.08 MW-5 1.22 --- 0.27 Complete results from the November 30, 2009 sampling event are presented in the attached table. All of these wells are located within the compliance boundary around the ash fill project. Our next sampling event is scheduled for spring 2010. Soil boring logs and well construction records for all wells installed at the Asheville Airport site are also attached. Three wells (MW-2, MW-3 and MW-4) have been abandoned and their well abandonment records are also included here. Please contact Ms. Laurie Moorhead at 828_-687- 5240 if you have any questions on the sampling results. Sincerely, arA.Whisnant Asheville Plant Manager Attachments Progress Energy Carolinas,Inc. Asheville Steam Plant 200 CP&L Drive Arden,NC 28704 DENR Davidson Letter January 11,2010 .0202 Limit 6AW-1A FAW-ZA tu3W 4A fl,9W 5 PQL Date Parameter m /f' m 1! m 11 m /1 m 11 nn /1 j 1113012009 Arsenic 0.05 0.0069 <U05 <0.005 <0-005 0.005 ( 11/30/2009 Barium 2 0-296 0-0395 0.0334 0.0657 0-005 ( lV3012009 Boron 0.315 <0.05 <0.05 <0.05 <0.05 0.06 i 11/30/2009 Cadmium 0.00175 <0.001 <0-001 <0.001 <0.001 0-001 ( 11/30/2009 Chromium 0-05 0.0191 <0.005 <0-005 <0.005 0.005 ( 11/3012009 Copper 1 0-0491 <0-005 0.15 <0-005 0.006 ( 11/30/2009 Iron 0.3 20-8 2.21 0.667 1.22 0.05 ( 11/30/2009 Lead 0.015 0.0371 <0.005 0.0178 <0.005 0.005 11130/2009 Manganese 0.05 1-01 0.0778 8.08 0.27 0-00.5 11130/2009 Mercury 0.00105 0.0000233 0.00000238 0-00000297 0-0000307 0.0000002 1 113 0/20 0 9 Nickel 0.1 0.0154 <0-005 0.0053 <0.005 0.005 ( 11/30/2009 Nitrate(as N) 10 <0.1 <0.1 0.22 4-7 0.1 11/30/2009 Nitrite(as N) 1 0.84 <0-1 <0-1 <0-1 0.1 11/30/2009 Selenium 0.05 <0-01 <0.01 <0-01 <0.01 0.01 ( 1113012009 Silver 0.0175 <0.005 <0-005 <0.005 <0-005 0-006 J 11/30/2009 Sulfate 250 33-1 <5.0 <5.0 <5-0 5 ( 11/30/2009 Zinc 1-05 0.113 0.0224 0.0181 0.0233 0.01 11/30/2009 pH (S.U) 6-5-8.5 5.67 526 5.45 4-67 N/A { 11/30/2009 Tern (F) N/A 58-1 57.74 59.72 57.92 N/A 111130/2009 Water Level ft. N/A 7.99 1.42 25.23 40.41 NIA Specific Cond_ 11/3012009 (umhos/cm) N/A 56 43 71 53 NIA 1 113 0/2 0 0 9 TOC N/A 1-8 22.4 4-7 1-6 1 11/30/2009 TDS NIA 122 34 38 32 720 1 i `15A PJCAC 02L.0202 Groundtivater Quality Standards TDS=Total Dissolved Solids 1. _ ------------- TOC=Total Organic Carbon -� i _ lJ/A Not Applicable PQL=Practical Quantitation Limit as provided by Pace Analical Services,_Inc- Top of PVC Ground Well Northing Easting Casing Well Status Elevation Elevation MW-1 636,742.78 945,061.99 2,098.94 -2,096.5 Inactive MW-2 636,506.39 945,538.68 2,117.70 -2,115.5 Abandoned MW-3 636,009.17 945,710.52 2,147.76 -2,145.5 Abandoned MW-4 635,470.96 945,343.76 2,143.73 "2,141.5 Abandoned MW-1A 636,559.68 944,943.83 2,100.40 ^2,097.7 Active MW-2A 636,617.12 945,291.16 2,102.71 -2,099.9 Active MW-4A 635,188.59 944,975.13 2,151.55 ^2,152.0 Active MW-5 '636,320.32 944,677.45 2,153.86 ^2,152.0 Active 2 U . S&ME neVD 1N 0 b 2G 11 ' Asheville Regional Office A uifer Protection I GROUNDWATER MONITORING REPORT NOVEMBER 2010 SAMPLING EVENT ASHEVILLE AIRPORT AREA 1 STRUCTURAL PILL REVIEW NETWORK ARDEN, NORTH CAROLINA h � S&ME Project No. 1584-10-055 t , Prepared For: Progress Energy Carolina's,Inc. { r Prepared By: S&ME, Inc. 3718 Old Battleground Road _ Greensboro,North Carolina 27410 December 20,2010 f-' SE;�� 1216 Edmund,Q.B. Henriques, L.G. Scott A. Spinner, L.G. { Environmental Department Manager Project Geologist r� �I If I_ SWE,INC./3718 Old Battleground Road/Greensboro, NC 27410/p 336.288.7180 IF 336.288.8980/www.smeinc.com i TABLE OF CONTENTS Paqe 1. EXECUTIVE SUMMARY.......................................................................................1 2. INTRODUCTION.....................................................................................................2 3. SCOPE OF WORK...................................................................................................2 4. METHODS EMPLOYED.........................................................................................2 4.1 Monitoring Well Sampling.................................................................................2 5. RESULTS...................... t_ 5.1 Groundwater Analytical Results.........................................................................4 5.2 Groundwater Flow Direction..............................................................................4 5.3 Quality Assurance...............................................................................................4 6. REFERENCES..........................................................................................................5 TABLES..............................................................................................................................I FIGURES..........................................................................................................................II APPENDIXI...................................................................................................................III APPENDIXII..................................................................................................................IV - TABLES Table 1: Groundwater Analytical Results Table 2: Well Construction Details and Groundwater Elevation Data r`r FIGURES IJFigure 1: Groundwater Flow Map APPENDICES Appendix I: Groundwater Sampling Field Data Sheets - Appendix II: Laboratory Analytical Reports LJ i 7 i r" Y I ` r-� i t Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 1. EXECUTIVE SUMMARY Progress Energy Carolina's, Inc. (PEC) operates the Asheville steam electric plant located in Arden,North Carolina. As part of an expansion project at the adjacent Asheville Regional Airport, ash was removed from the ash basin at the plant and placed as structural fill in Area I. The wells MW-lA,MW-2A, MW-4A, and MW-5 comprise the groundwater monitoring network for the Area I structural fill project at the Asheville Regional Airport. Monitoring well MW-4A serves as a background water quality well, and wells MW-lA,MW-2A, and MW-5 are point of review wells. These four monitoring wells were sampled on November 19, 2010. Sampling was conducted using "low-flow" sampling methods and the samples were analyzed by a North Carolina certified laboratory. The following summarizes the analytical results from this monitoring event. o Total barium, cadmium, iron,manganese,mercury, zinc;plus nitrate, TDS, and TOC were reported at concentrations above the practical quantitation limit in one or more wells monitored. • The field pH levels measured at the review boundary wells MW-IA,MW-2A, MW-5 and background well MW-4A were below the NCAC 2L specified range of 6.5- 8.5 standard units. Given the low pH reading at background well MW-4A,the pH recorded at the review boundary wells could reflect naturally occurring conditions. • Total iron was detected at all four well locations; however, only the concentrations detected at wells MW-2A,MW-4A, and MW-5 exceed the NCAC 2L groundwater standard of 300 µg/L. The total iron concentration detected at background water, quality well MW-4A is greater than the concentrations detected in the review boundary monitoring wells. Iron is a naturally occurring metal. • Manganese was detected at all four well locations; however, only the concentrations detected at wells MW-4A and.MW-5 exceed the NCAC 2L groundwater standard of 50 µg/L. The total manganese concentration detected at background water quality well MW-4A is greater than the concentrations detected in the review boundary monitoring wells. Manganese is a naturally occurring metal. • No other targeted constituents were detected at concentrations that exceed the published NCAC 2L groundwater quality standards. In accordance with 15A NCAC 02L .0202 (b) (3) "Where naturally occurring substances exceed the established standard, the standard will be the naturally occurring concentration as determined by the director. " Iron and manganese are naturally occurring metals in the earths crust, as such natural variations in their distribution and concentrations in the vadose zone and saturated zone influence the range of �— concentrations present in the groundwater system. Therefore, it may be premature to i ! assume that the concentrations detected in background water quality well MW-4A,reflect the full range of natural background concentrations across the site. ` ' 1 Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 2. INTRODUCTION PEC operates the Asheville steam electric plant located at 200 CP&L Drive, in Arden, North Carolina. As part of an expansion project at the adjacent Asheville Regional Airport, ash was removed from the ash basin at the plant and placed as structural fill in Area I. The wells MW-1A,MW-2A,MW-4A, and MW-5 comprise the groundwater monitoring network for the Area I structural fill project at the Asheville Regional Airport. Monitoring well MW-4A serves as a background water quality well, and wells MW-lA, MW-2A, and MW-5 are point of review wells. S&ME, Inc. (S&ME)was contracted by the PEC to complete this groundwater monitoring event for the structural fill review boundary well network,which was installed during October 2009. Figure 1 depicts the location of the structural fill,the review and compliance boundaries for the structural fill and the associated review boundary monitor well locations. This report discusses the field procedures, summarizes the field measurements and analytical results for the November 19, 2010 water quality monitoring event. 3. SCOPE OF WORK To complete the scope of work, S&ME completed the following tasks: • Sampled four monitoring wells at the Structural Fill. • Obtained field values for pH,temperature,turbidity, and conductivity at each sample location. • Depth to water measurements were collected during well purging to monitor drawdown. • Groundwater samples were analyzed by a North Carolina certified laboratory, using State approved methods. • Calculated groundwater flow directions for the monitored area. • Prepared and submitted this Groundwater Monitoring Report 4. METHODS EMPLOYED i 4.1 Monitoring Well Sampling Groundwater monitoring well sampling took place on November 19,2010. The monitoring well locations are shown on Figure 1. Prior to sampling, each well was visually inspected for well integrity and well security. Appendix I contains the "Groundwater Sampling Field Data"forms completed for each well,to document the observations. Each well was opened and the static water level was measured from the top edge of the PVC casing in wells. Total well depth and depth to water were used to determine the volume of water in each well. Each well was purged and sampled using either a submersible pump or a peristaltic pump,with the intake for the pump placed near the mid-point of the saturated well screen. Well sampling was conducted using"low-flow" 2 Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 sampling methods. For the purpose of this discussion,we refer to"low-flow"in the _ context of the velocity with which water enters the pump and evokes flow from the formation in the immediate vicinity of the well. The objective of low-flow sampling is to pump in a manner that minimizes the stress on the aquifer system,to the extent possible. Current literature defines typical flow rates ranging from 0.1 to 0.5 Liter/minute. The purge rate and the drawdown of the water table were monitored as an indicator of how much stress the purging placed on the aquifer. The purge rates were calculated by recording the time required to fill a graduated cylinder. The purging flow rates varied but typically ranged from approximately 250 to 300 milliliters/minute (nil/min.). During purging,the depth to water was periodically monitored and recorded on the "Groundwater Sampling Field Data"forms. It is our opinion that the observed drawdowns were generally minor during purging; therefore,the stresses placed on the aquifer should have been minor. The observed drawdown data also suggests that the purging rates should have been low enough such that recharge water should not have been overly agitated,reducing the potential for colloids to be drawn into the well bore. During purging activities, measurements for pH,temperature, conductivity, and turbidity were typically taken at 5 to 10 minute intervals. Stabilization of field parameters was used to indicate that conditions are suitable for sampling to begin. In general pH, temperature, and conductivity were deemed stabilized after three consecutive intervals with readings within plus or minus 5 to 10%. For turbidity,less than or equal to a measure of 10 Nephelometric Turbidity Units (NTUs)was targeted as the minimum stabilization criteria. During the purging of monitor wells MW-lA and MW-4A,the turbidity meter was malfunctioning. Following the stabilization of pH, temperature, and conductivity,these two wells were purged until free of visible fines. The field data collected during sampling was recorded on the "Groundwater Sampling Field Data forms contained in Appendix I. Groundwater samples were collected directly from the tubing at each of the pumped wells. Immediately upon collection, each sample was placed in laboratory supplied containers,packed on ice, and placed under chain-of custody. The sampling technician wore nitrile gloves that were changed between wells to reduce the possibility of cross contamination. The samples were transported and delivered directly to PACE Analytical, PEC's contract laboratory for this project. All monitoring well samples were analyzed for total arsenic,barium,boron, cadmium, chromium, copper, iron, lead, manganese,mercury,nickel, selenium, silver, and zinc; plus nitrate,nitrite, sulfate,total dissolved solids (TDS) and total organic carbon(TOC). Analyses were conducted by PACE Analytical, a North Carolina certified laboratory. Laboratory analytical data is attached in Appendix II. 3 1� I ` Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 � i 50 RESULTS j 5.1 Groundwater Analytical Results Table 1 provides a summary of the laboratory analytical results and provides the applicable groundwater quality standards as a reference. The complete laboratory report is included in Appendix B. The following summarizes the groundwater sample analyses. • Total barium, cadmium, iron,manganese, mercury, zinc; plus nitrate, TDS, and TOC were reported at concentrations above the practical quantitation limit in one or more wells monitored. • The field pH levels measured at the review boundary wells MW-1A,MW-2A, MW-5 and background well MW-4A were below the NCAC 2L specified range of 6.5- 8.5 standard units. Given the low pH reading at background well MW-4A,the pH recorded at the review boundary wells could reflect naturally occurring conditions. • Total iron was detected at all four well locations; however, only the concentrations detected at wells MW-2A, MW-4A, and MW-5 exceed the NCAC 2L groundwater standard of 300 µg/L. The total iron concentration detected at background water quality well MW-4A is greater than the concentrations detected in the review boundary monitoring wells. Iron is a naturally occurring metal. • Manganese was detected at all four well locations; however, only the concentrations detected at wells MW-4A and MW-5 exceed the NCAC 21,groundwater standard of 50 µg/L. The total manganese concentration detected at background water quality well MW-4A is greater than the concentrations detected in the review boundary monitoring wells. Manganese is a naturally occurring metal. • No other targeted constituents were detected at concentrations that exceed the j published NCAC 21, groundwater quality standards. 5.2 Groundwater Flow Direction The static water levels in the four monitoring wells were measured on November 19, `J 2010. The depth to the water table ranged from 2.10 to 40.92 feet below the top of well -, casing on this date. Table 2 contains well construction details, depths to groundwater, I and calculated groundwater elevation data. A groundwater contour map constructed using the data collected during this monitoring event is presented as Figure 1. The groundwater elevation data collected during this monitoring event indicates that the groundwater beneath the structural fill generally flows toward the north and northeast. 5.3 Quality Assurance One Field Blank sample (Field Blank-2)was prepared in the field using de-ionized water and accompanied the sample bottles on their return to the laboratory. The Field Blank-2 was analyzed for the same suite of constituents as the groundwater monitoring wells.No 1 target constituents were present in the Field Blank sample at detectable levels. One duplicate sample (Duplicate-2)was collected during the sampling of review boundary -' well MW-5 and analyzed for all constituents included in this sampling event. The analytical results for the duplicate sample are very similar to those reported for sample ^} 4 � I ' Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 r Asheville Airport,Arden, North Carolina December 20,2010 MW-5. The results of the laboratory QA/QC sample analyses are included in Appendix 17 II. -' S. REFERENCES North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Environmental Management, Subchapter 2L, Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, Sections .0100, .0200, and .0300 (November 8, 1993); from the Environmental �._ Management Commission Raleigh,North Carolina. l l 5 Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 TABLES I TABLE 1 GROUNDWATER ANALYTICAL RESULTS . ASHEVILLE AIRPORT.AREA 1-STRUCTURAL FILL ARDEN,NORTH CAROLINA Sc&ME PROJECT NO. 1584-10-055 GW Standard(eff.1/1/2010,•`81112010) "a afPM r 7at1( h 74t1 2 ,U W SODS m w? a;''��.'50 w v� 1 3tf0e Units u /1 u 6/I u /I u /I u /1 m /I u /I u /I u /I u /I u /1 Parameter Arsenic Barium Boron Cadmium Chromium Copper Iron Lead Manganese Mercury Nickel Method Well Well relative tation.. Sample o Collection Name. Compliance Date Boundary(CB) MW-1A RB 11/19/2010 <5 14.3 <50 <0.08 <5 <0.005 209 <5 10.8 <0.2 <5 MW-2A RB' 11/19/2010 <5 19.3 <50 0.085 .<6 <0.005 �374.','� <5 10.6 <0.2 <5 MW-4A Background 11/19/2010 -<5 38.6 <50 0.12 <5 <0.005 10Z0` ; <5 =w 3010.E 0.39 <5 MW-5 RB " 11/19/2010: <5 29.3' <50 <0.08"� <5 <0.005 .77,1 '` <5 a, ,90"6 rn.f% <0.2 <5 GW.Standard(eff.1/1/2010,"8/1/2010) M204,4 i �a�ON L e 24 b txj Units m /I m /I u /I u /I m /I m /I m /I m /I SU C umhos/cm Parameter Nitrate Nitrite Selenium Silver Sulfate Zinc TOS TOC H Temp: Cond. Method WeIL.Location Well relative to Sample Name,, Compliance Collection Boundary(CB) Date. MW-1A .... RB 11/19/2010, 0.1 <0.1 <10 <5 <5 <0.010 28 1.4 Tr' 548.,'. 14,27 23 MW-2A RB 11/19/2010 <0.1 <0.1 <10 <5 <5 <0.010 37 14.5 13.80 27 MW74A Background 11/19/2010 0.16 <0..1 <10 :<5. <5 <0.010 43: 3.1 14.59 40. r:MW-5 RB 11/19 /2010: 1.7 . <0.1 <10, <5 <5 0.0134 <25 1 2 " 4 74,r'�� 13:24 20 Concentrations in cells shaded green,exceed the corres ondin NCAC 2L roundwater ualit standard; however,may be natural) occurrin 9 p, 9 9 Q Y Y Y 9 TABLE 2 WELL CONSTRUCTION DETAILS AND GROUNDWATER ELEVATION DATA REVIEW BOUNDARY WELL NETWORK ASHEVILLE AIRPORT AREA 1 - STRUCTURAL FILL ARDEN, NORTH CAROLINA S&ME PROJECT NO. 1584-10-055 Total Well Screen Date Well Top of Casing Depth to Groundwater Well ID Position Use Depth Interval Installed Northing Easting Elevation Groundwater Elevation 1111912010 11/19/2010 feet b feet b (NAVD 88) feet feet MW-1A Down-gradient Review 20 5-20 10/6/2009 636559.68 944943.83 2100.40 8.59 2091.81 MW-2A Down-gradient Review 15 5- 15 10/6/2009 636617.12 945291.16 2102.71 2.10 2100.61 MW-4A Up-gradient Background 45 30-45 10/7/2009 635188.59 944975.13 2151.55 23.98 2127.57 MW-5 Down-gradient Review 57 42-57 10/7/2009 636320.32 944677.45 2153.86 40.92 2112.94 Progress Energy provided the well coordinates and top of casing elevations. feet bg =feet below grade Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20,2010 FIGURES I I o /o er O 1 I ( la it Yr T t. g N D ,r Tir1 q T d j ti ti I ti j Iti ti ti tt a' tih N N 1 f I g, �I I III dl t[ i I 'Ix _1 t r� lL I � p �-�g� � I T zTf t 1 iti I I u T t t��t :,/� •l1t?1 /l v 1 .W D p It 1 ti� J I _., rw ` y w '" \ r w!�� i I i A :.+1+1{ �p { r/ Yl\\\ `! 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I n! t •I11>wvlf 1b % ! + �l l \ <: 0 � f' I Or�yr '.\ [[ \ rw e[b. t. i il. t t � \+l '`-\` `\.i Ir, JIB♦�\ / i S `row;\\.0 \ w$roA® 4Ji 11 1 q J 1 L t' 14 Owl 1 I I 7 i in 1 i c kit t[r,S '1__• ♦ Oe®" \\\' + \i7 T' T T a l L T r T Ii�\I I Ply + rn D 4 i 1p p \o \ I t I I ! 1 / ♦ / \\ \+ It .{ t ��4 1 , I T I i I I-. t s,�y J I 1 �I.I t Ilt [ { �„—� � i ♦♦� ��..1 ., , t1 \ \ � I+,� t l I f II} I 't i�, I I 1 1+ Jil} I J �t I I t �I. i t 1 S 4 l �1t J ' 1 1 1 i\ ; / i/ m�®�'•� \ �t l�'� I I tr� r l o ' i i 1 ; I f; `@a:,®v ®wmm ♦r► s' I Ir,fl 1? 1Stkl S 1 tJsl , tJts}IatJ - 7 Q A v "� � ���':: / ` i+^ \ '..+� ♦o�•.I T\r -T.. � r�`� -��- i ; �—I's �1 N mw�vrr /� -." —. 8 [, � � � � ,{._�� S;° /� \ cc! 9--. � \ ♦e , I i \r\t t T , f:a� : ,,tmr�rr % '✓ ,,--' 1 � � g ,ii I \♦\i\\`�i\ , e® �i��\ ® � � Y I �....h cyp�i pg r� ' ♦• '1\ 1,` 0♦Y%l {rl I Q t7'�\ o 1 loo 14 ',• 8 B b GROUNDWATER FLOW MAP 8 u € m STRUCTURAL FILL .. _. .. - *S&ME umoi. wa.w0.0 em, ru(c°cie°1°eei mug ASHEVILLE PLANT WWW.SMEINC.COM ARDEN, NC Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport,Arden, North Carolina December 20, 2010 APPENDIX I Groundwater Sampling Field Data Sheets ul GROUNDWATER SAMPLING FIELD DATA Location: -51e K N k r O✓ Purge Date: It `1 fC� `t o c- 1 Project No.: — Purge Time: ioLf/f0. - � Source Well: Sample Date: Sample Time: Locked?: Yes: V No; Weather: 1 /1 Sampled By: Z/ Y=VUIS A-S Air Temp: Condition of well Tag,easing,�d condr€ee pad: b Water Level&Well Data C� Depth to water from measuring point: { feet Depth to well bottom from measuring point: Z O feet Height of water column: y, feet Measuring point Well Purging&Sample Collection Purge Method p2Ec,5 i•='i t 4 Purge Time Sample Method I I Start h 0'{O Stop �!• �� Purge Rate 05-ID ml/min Sample Collection Time. Control Settings On: sec. Start . ;o Off:Za A A s Pressure: Volume of water In well 2"well: 7 height:'9.d , x.163 Volume of water removed gallons I liters Was well purged dry Yes No x _ Field Analyses 'Stabilization Parameters Time DTW Temp H Conductivity 'Turbidity i o. da Final Readings GROUNDWATER SAMPLING FIELD DATA Location: /� r`1 i— Purge Date: Project No.: j S-1 i-{--10 �Qt S"-nr— Purge Time: Source Well: /►AX"-2. Sample Date: Sample Time: f Locked?: Yes: No: Weather. C rz� ( LZ�' Sampled By: ?l G k."i 'S A S Air Temp: Condition of well'tag,casing,cap and con rcn ete pad: v�'Lo Glt C v M W .a, 1 Water Level&Well Data 1 Depth to water from measuring point: L 1 �!! feel Depth to well bottom from measuring point: O Meet Height of water column: �� feet Measuring point: �- Well Purging&Sample Collection Purge Method YS`r'�r {, �`��^{� Purge Time Sample Method t Start ()q tq 0 Stop Purge Rate 70 V ml/min Sample Collection Time Control Settings On: sec. Start 0 Off.. sec. /U/A Pressure: psi Volume of water in well 2"well: � r G height: +j 6"5', x.163= Volume of water removed , gallons _ liters Was well purged dry Yes No Field Analyses 'Stabilization Parameters Time DTW Temp R Conductivity *Turbidity z r 3. 1 V 13,Cr t r7 0r 03- 17 fa`o O Q Final Readings GROUNDWATER SAMPLING FIELD DATA Location: �, rPDt Purge Date: 1f1`lG) r[ Project No.: f. Purge Time: / h� 35—MJ S Source Well: bidSample Date: d �r Sample Time: Locked?: Yesr�n !� �' l No: Weather. eACM 9 Sampled By: S yV Air Temp: Condition of well tag,casing,cap and concrete pad: k Water Level&Well Data Depth to water from measuring point: J feet Depth to well bottom from measuring point: feet Height of water column: 1 19 3 feet Measuring point: • / o Well Purging&Sample Colle ton `/J� Purge Method L"J r Poo Purge Time u ry Sample Method I start Stop Slop ! R Purge Rate ml/min Sample Collection Time Control Settings On: see. Start d L-3 Stop Off: sec. Pressure:3-0 psi Volume of water in well 2"well: I� C height: R I) V r x.163= ° �a( �`•J Volume of water removed �^ gallons �. liters Was well purged dry Yes No Field Analyses 'Stabilization Parameters �'� Time D_TW Temp H Conductivity *Turbidity � 1 , 9 S b .�" _ • i � , S ►I5l f �-t I t o °Sb 6-3 as Q. n O, i � 1 S , f , C3I w4 i 0.5:1)k iM 1rr , i :I i Final Readings GROUNDWATER SAMPLING FIELD DATA Location: e'�;�{�Q Froi i t ^,' Purge Date: Project No.: Purge Time: A r /0,-Yn,5 Source Well: ""� Sample Date: r f t Cf f G Sample Time: r a r Looked?: Yes: ! No: Weather: C e (or Sampled By: `5�S f f7�'/J Air Temp: Condition of well tag,casing,caj 6d cone pad: Water Level&Well Data r Depth to water from measuring point: �-,V feet Depth to well bottom from measuring point: 4:2 1 . feet Height of water column: 0<3t, feet Measuring point: f CS Du p 'e-7— 7— Well Purging&Sample Collection `�r} (<< v Purge Method r$tJ�G`f� �L'MI jy_ Purge Time Sample Method �� l f Start s 1'it' Stop Purge Rate 7r mVmin Sample Coile¢ti n Time Control Settings On: t sec. Start. Stop Off 15 sec. Pressure: Q psi Volume of water in well 2`well: r € height:,2f)r3t x.163= a Volume of water removed gallons 8 liters Was well purged dry Yes No Field Analyses "Stabilization Parameters Time DTW Temp H Conductivity 'Turbidity 0 R 1,AG I 1 1,9. 'l I '14A 6 ,5111 ; 5 `19 I t ! •`�c� r t o I p r� i36 T7 q.-3 0, 1)a0 . Final Readings Water Quality Monitoring Report—Structural Fill S&ME Project No. 1584-10-055 Asheville Airport Arden North Carolina December 20,2010 APPENDIX 11 Laboratory Analytical Report Iv Q,, /© Pace Analytical Services,Inca a Pace Analytical Services,Inc aL'e/�11a')/f1L'a! 2225 Riverside Dr. 9800 Kincey Ave. Suite 100. www.pacelabs.com Asheville,NC 28804 Hunteisville,NC 28078 (828)254-7176 (704)875-9092 December 15, 2010 Mr. John Toepfer Progress Energy 410 S.Wilmington Street/PEB4 Raleigh, NC 27601 RE: Project: Asheville Airport Fill Project Pace Project No.: 9282583 Dear Mr.Toepfer: Enclosed are the analytical results for sample(s) received,by the laboratory on November 19, 2010.. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, � — Lord Patton lorri.patton@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS Page 1 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. HrAa Cpq v^i Pace Analytical Services,Inc. Pace Analytical Services,Inc. aeeAnalytieal® 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 CERTIFICATIONS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Minnesota Certification IDs 1700 Elm Street SE Suite 200,Minneapolis,MN 55414 Montana Certification#:MT CERT-0092 Alaska Certification#:UST--078 Nebraska Certification#:Pace Alaska Certification#MN00064 Nevada Certification#:MN 00064 Arizona Certification#:AZ-0014 New Jersey Certification#:MN-002 Arkansas Certification M 88-0680 New Mexico Certification M Pace California Certification#:01155CA New York Certification#:11647 EPA Region 8 Certification#:Pace North Carolina Certification#;530 Florida/NELAP Certification#:E87605 North Dakota Certification#:R-036 Georgia Certification#:959 North Dakota Certification#:Rr036A Idaho Certification#:MN00064 Ohio VAP Certification M CL1.01 Illinois Certification#:200011 Oklahoma Certification#:D9921 Iowa Certification M 368 Oklahoma Certification M 9507 Kansas Certification#:E-10167 Oregon Certification#:MN200001 Louisiana Certification#:03086 Pennsylvania Certification#:68-00563 Louisiana Certification#:LA080009 Puerto Rico Certification Maine Certification#:2007029 Tennessee Certification M 02818 Maryland Certification M 322 Texas Certification#:T104704192 Michigan DEQ Certification#:9909 Washington Certification#:C754 Minnesota Certification#:027-053-137 Wisconsin Certification M 999407970 Mississippi Certification M Pace Ormond Beach Certification IDs 8 East-Tower Circle,Ormond Beach,FL 32174 Michigan Certification M 9911. Alabama Certification M 41320 Mississippi Certification:FL NELAC Reciprocity Arizona Certification#:AZ0735 Montana Certification#:Cert 0074 Colorado Certification:FL NELAC Reciprocity Nevada Certification:FL NELAC Reciprocity Connecticut Certification#:PH 0216 New Hampshire Certification#:2958 Florida Certification#:E83079 New Jersey Certification#:FL765 Georgia Certification#:955 New York Certification M 11.e08 Guam Certification:FL NELAC Reciprocity North Carolina Environmental Certificate#:667 Hawaii Certification:FL NELAC Reciprocity North Carolina Certification#:12710 Kansas Certification#;E-10383 Pennsylvania Certification#:68-547 Kentucky Certification M 90050 Puerto Rico Certification#:FLO1264 Louisiana Certification#:LA090012 Tennessee Certification M TN02974 Louisiana Environmental Certificate#:05007 Texas Certification:FL NELAC Reciprocity Maine Certification#:FL1264 Virginia Certification M 00432 Massachusetts Certification#:M-FL1264 Wyoming Certification:FL NELAC Reciprocity Asheville Certification IDs 2225 Riverside Dr.,Asheville,NC 28804 North Carolina Wastewater Certification#:40 Connecticut Certification#:PH-0106 Pennsylvania Certification#:68-03578 Florida/NELAP Certification#:E87648 South Carolina Bioassay Certification#:99030002 Massachusetts Certification#:M6NC030 South Carolina Certification#:99030001 New Jersey Certification#:NC011 Virginia Certification#:00072 - North Carolina Bioassay Certification-#:9 West Virginia Certification#:356 North Carolina Drinking Water Certification#:37712 REPORT OF LABORATORY ANALYSIS Page 2 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. ////N....���•c COg..O//�..��`` V��V s. /�,, ® Pace Analytical Services,Inca Pace Analytical Sery Ices,Inc. aceAna�ytiCa� 2225 Riverside Dr. 9800 KinceyAve. Suite 100. www.pa'celabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT Project-. Asheville Airport Fill Project Pace Project No.: 9282583. Analytes Lab ID Sample ID Method Analysts Reported Laboratory 9282583001 MW-1A EPA200.7 SHB 12 PASI-A EPA200.8 TO 1 PASI-M EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA 300.0 HEM. 1 PASI-O EPA353.2 DMN 2 PASI-A SM 5310B RAB 1 PASI-A 9282583002 MW-2A EPA200.7 SHB 12 PASI-A EPA200.8 TL1 1 PASI=M EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA300.0 HEM 1 PASI-O EPA353.2 DMN 2 PASI-A SM 5310121 RAB 1 PASI-A 9282683003 MW-4A EPA200.7 SHB 12 PASI-A EPA200.8 TL1, 1 PASI-M EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA300.0 HEM 1 PASI-O EPA353.2 DMN 2 PASI-A SM 5310B RAB 1 PASI-A 9282583004 MW-5 EPA200.7 SHB 12 PASI-A EPA200.8 TL1 1 PASI-M EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA300.0 HEM 1 PASI-O EPA353.2 DMN 2 PASI-A SM 5310B RAB 1 PASI-A 9282683005 Field Blank-2 EPA200.7 SHB 12 PASkA EPA200.8 TL1 1 PASI-M EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA300.0 HEM 1 PASI-O EPA353.2 DMN 2 PASI-A SM 5310B RAB 1 PASI-A 9282683006 Duplicate-2 EPA200.7 SHB 12 PASI-A EPA200.8 TL1 1 PASI-M REPORT OF LABORATORY ANALYSIS Page 3 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. „�CCCq Geia i. /© Pace Analytical Services,Inc. Pace Analytical Services,Inc." aL'eAna�f��L'a! 2225 Riverside Dr. 9800 Kincey Ave. Suite 100. J`•,www.pai:ela6s.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT " Project: Asheville Airport Fill Project Pace Project No.: 9282583 Analytes Lab iD. Sample ID Method Analysts Reported Laboratory EPA245.1 JMW 1 PASI-A SM 2540C MLM 1 PASI-A EPA300.b HEM 1 PASI-O EPA853.2 DMN 2 PASI-A SM 5310B RAB 1 PASI-A 'q. REPORT OF LABORATORY ANALYSIS Page 4 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. AO :i re act, �I //��,,,, // o Pace Analytical Services,Inc: Pace Analytical Services,Inc. ann illal �L+al 2225 Riverside Dr. 9800 KinceyAve..Suite 100 www.pacelabs.com Asheville,NC 28804 Muntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project -- Pace Project No.: 9282583 Sample: MWAA Lab ID: 9282583001 Collected: 11/19/10 12:00 Received: 11119/1015:45 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA200.7 Preparation Method:EPA200.7 Arsenic ND ug/L 5.0 1 11/23/10 10:3.0 12/02/10 06:25 7440-38-2 Barium 14.3 ug/L 5.0 1 11/23/10 1.0:30 12/02/10 06:25 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:25 7440-42-8 Chromium ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:25 7440-47-3 Copper ND ug/L 5.0 1 11/23/10 10:30 12/02110 06:25 7440-50-8 Iron 209 ug/L 50.0 1 11/23/10 10:30 12/02/10 06:25 7439-89-6 Lead ND ug/L 5.0 1 11/23110 10:30 12/02/10 06:25 7439-92-1 Manganese 10.8 ug/L 6.0 1 11/23/10 10:30 12/02/10 06:25 7439-96-5 Nickel ND ug/L 5.0 1 11123/10 10:30 12/02/-10 06:25 7440-02-0 Selenium ND ug/L 10.0 1 11/23/10 10:30 12/02/10 06:25 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:25 7440-22-4 Zinc ND ug/L 10.0 1 11/23/10 1'0:30 12/02/10 06:25 7440-66-6 200.8 MET ICPMS Analytical Method:EPA 200.8 Cadmium ND ug/L 0.080 1 11/23/10 13:22 11/29/10 01:03 7440-43-9 245.1 Mercury Analytical Method:EPA245.1 Preparation Method:EPA245.1 Mercury ND ug/L 0.20 1 12/02/1016:25 12106/1013:18 7439-97-6 2640C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids 28.0 mg/L 25.0 1 11/23/10 14:18 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 12/13/10 17:22 1'4808 79-8 353.2 Nitrogeni N021NO3 unpres Analytical Method:EPA353.2 Nitrogen,Nitrate 0.10 mg/L 0.10 1 11/19/10 18:15 Nitrogen,Nitrite ND mg/L 0.10 1 11/19/10 18:15 531 OB TOC Analytical Method:SM 5310B Total Organic Carbon 1.4 mg/L 1.0 1 11/24/10 00:27 7440644-0 Date:12/15/2010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 5 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. lo h cc oft n / ® Analytical Services,Inc. Pace Analytical Services,Inc. 1Pace eA�aljd cal .2225 Riverside Dr. 9800 KinceyAve. Suite 100 wwwpacela6s.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Sample: MW-2A Lab ID: 9282683002- Collected: 11/19/10 10:15 Received: 11/19/10 15.45 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7 - Arsenic ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:32 7440-38-2 Barium 19.3 ug/L 5.0 1 11/23/lb 10:30 12/02/10 06:32 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:32 7440-42-8 Chromium ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:32 7440-47-3 Copper ND ug/L 5.0 1 11/23/W 1:0:30 12/02/10 06:32 7440-50-8 Iron 374 ug/L 50.0 1 11/23/10 10:30 12/02/10 06:32 7439-89-6 Lead ND ug/L 5.0 1 11/23/10 10:30 12/02110 06:32 7439-92-1. Manganese 10.6 ug/L 5.0 1 11/23/10 10:30 12/02/10 06:32 7439-96-5 Nickel ND ug/L 5.0 1 11/23/10 10:30 12/02110 06:32 7440-02-0 Selenium ND ug/L 10.0 1 11/23/1'0 10:30 12/02/10 06:32 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 1.0:30 12102110 06:32 7440-22-4 Zinc ND ug/L 10.0 1 11/23/10 1-0:30 12/02/10 06:32 7440-66-6 200.8 MET ICPMS Analytical Method:EPA 200.8 Cadmium 0.085 ug/L 0.080 1 11/23/1-0 13:22 11/29/10 01:06 7440-43-9 245.1 Mercury. Analytical Method:EPA245.1 Preparation Method:EPA245.1 Mercury ND ug/L 0.20 1 12/02/10 16:25 12/0611013:33 7439-97-6 2540C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids 37.0 mg/L 25.0 1 11/23/10 14:1'8 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 12113/1017:34 14808-79-8 353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Nitrogen,Nitrate ND mg/L 0.1.0 1 11/1.9M0 18:14 Nitrogen,Nitrite ND mg/L 0.10 1 14/19/10 18:14 531OB TOO Analytical Method:SM 531 OB Total Organic Carbon 14.5 mg/L 1.0 1 11124/10 00:52 7440-44-0 Date:12/15/2010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 6 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. Q., ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. aeeMalX cal 2225 Riverside Dr. 9800 KinceyAve. Suite 100. www.pacelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Sample: MW-4A Lab ID: 9282583003 Collected: 11/19/10 14:30 Received: 11/19/10 15:45 Matrix:Water Parameters Results Units Report Limit DF ' Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7 Arsenic ND ug/L 5.0 1 11/23/10 10:30 12102/10 06:35 7440-38-2 Barium 38.6 ug/L 5.0 1 11/23/10 1.0:30 12/02/10 06:35 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:35 7440-42-8 Chromium ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:35 7440-47-3 Copper ND ug/L 5.0 1 11/23/110,40:30 12/02/10 06:35 7440-50-8 Iron 1020 ug/L 50.0 1 11/23/10 10:30 12/02/10 06:35 7439-89-6 Lead ND ug/L 5.0. 1 11/23/10 10:30 12/02/10 06:35 7439-92-1 Manganese 3010 ug/L 5.0 1 11/23/10 10:30 12/02/10 06:35 7439-96-5 Nickel ND ug/L 5.0 1 11/23/1D 1.0:30 12/02/10 06:35 7440-02-0 Selenium ND ug/L 10.0 1 11/23/10 10:30 12/02/10 06:35 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:35 7440-224 Zinc ND ug/L 10.0 1 11/23/10 10:30 12/02/10 06:35 7440-66-6 200.8 MET ICPMS Analytical Method:EPA200.8 Cadmium 0.12 ug/L 0.080 1 11/23/10 13:22 11/29/10 01:10 7440-43-9 246.1 Mercury Analytical Method:EPA245.1 Preparation Method:EPA245.1 Mercury 0.39 ug/L 0.20 1 12/02110 16:25 12/06/10 13:36 7439-97-6 2640C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids 43.0 mg/L 25.0. 1 11/23/10 14:18 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 12/1311017:46 14808-79-8 353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA353.2 Nitrogen,Nitrate 0.16 mg/L 0.10 1 11/19/10 18:16 Nitrogen,Nitrite ND mg/L 0.10 1 11/19/1018:16 5310B TOC Analytical Method:SM 5310B Total Organic Carbon 3.1 mg/L 1.0 1 11/24/10 15:11 7440-44-0 Date:12/15/201'0 10:13 AM REPORT OF LABORATORY ANALYSIS Page 7 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. co, dieli Pace Analytical Services,Inc.. Pace Analytical Services,Inc. aL'elilla' �L'a'_. 2225 Riverside Dr. 9800 I(inceyAve..;Suite 100 •www.pai:ela6s.cnm Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Sample: MW-5 - Lab ID: 9282583004 Collected: 11/19/10 08:50 Received: 11/19/1015:45 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA200.7 Preparation Method:EPA200.7 Arsenic. ND ug/L 5.0 1 11/23/10 10:30 12/02/1006.49 7440-38-2 Barium 29.3 ug/L 5.0 1 11/23/W 10:30 12/02/10 06:49 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 1210VID 06:49 7440-42-8 Chromium ND ug/L 5.0 1 11/23/1'0 10:30 12/02/10 06:49 7440-47-3 Copper ND ug/L 5.0 1 11/23/10 1.0:30 12/02/10 06:49 7440-50-8 Iron 771 ug/L 50.0 1 -11/23/10-1.0:30 12/0211006:49 7439-89-6 Lead ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:49 7439-92-1 Manganese 90.6 ug/L 5.0 1 11/23/10 10:30 12/02/10 06:49 7439.96-5 Nickel ND ug/L 5.0 1 1112311'0 10:30' 12/02/10 06.49 7440-0260 Selenium ND ug/L 10.0 1 11123110 10:30 12/02%10 06:49 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:49 7440-22-4 Zinc 13.4 ug/L 10.0 1 11/23/10 10:30 12/02/10 06:49 7440-66-6 200.8 MET ICRMS Analytical Method:EPA 200.8 Cadmium ND ug/L 0.080 1 11/23/10 13:22 11/29/10 01:13 7440-43-9 246.1 Mercury Analytical Method:EPA245.1 Preparation Method:EPA245.1 Mercury ND ug/L 0.20 1 12/02/10 16:25 12106/1013:38 7439-97-6 2640C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids ND rng/L 25.0 1 11/23/10 14:18 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 1211311017:58 14808-79-8 353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Nitrogen,Nitrate 1.7 mg/L 0.10 1 11/19/10 18:08 Nitrogen,Nitrite ND rng/L 0.10 1 11/19/1018:08 5310B TOC Analytical Method:SM 5310B Total Organic Carbon 1.2 mg/L 1.0 1 11/24/10 01:34 7440-44-0 Date:12/15/2010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 8 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. /� / ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. a�i+eMa(1�oal 2225 Riverside Dr. 98001(incey.Ave..Suite 100. www.pabelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Sample: Field Blank-2 Lab ID: 9282583005 Collected: 11/19/10 09:00 Received: 11/19/10 15:45 Matrix:Water Parameters Results-' Units Report Limit DF Prepared Analyzed CAS No. Quaff 260.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7 Arsenic ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:52 7440-38-2 Barium ND ug/L 5.o 1 11/23/10 10:30 12/02/10 06:52 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:52 7440-42-8 Chromium ND ug/L 5.0 1 11/23110 10:30 12/02/10 06:52 7440-47-3 Copper ND ag/L 5.0 1. 11/23/10 10:30 12/02/10 06:52 7440-50-8 Iron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:52 7439=89-6 Lead ND ug/L 5.0 1 11/23/10 10:30 12102/10 06:52 7439-92-1 Manganese ND ug/L 5.0_ 1 11/23/10 10:30 12/02/10 06:52 7439-96-5 Nickel ND ug/L 5.0 1 11/23/10.10:30 12/02/10 06:52 7440-02-0 Selenium ND ug/L 10.0 1 11/23/10 16:30 12/02/10 06:52 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:52 7440-22-4 Zinc ND ug/L 10.0 1 11/23/10 10:30 12/02/10 06:52 7440-66-6 200.8 MET ICPMS Analytical Method:EPA 200.8 Cadmium ND ug/L 0.080 1 11/23/10 13:22 11/29/10 01;16 7440-43-9 245.1 Mercury Analytical Method:EPA 245.1 Preparation Method:EPA 245.1 Mercury ND ug/L 0.20 1 12/02/10 16:25 12/06/10 13:41 7439-97-6 2640C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids ND rng/L - 25.0 1 11/23/1'0 14:19 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 12/13/10 18:11 14808-79-8 353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2 Nitrogen,Nitrate ND mg/L 0.10 1 11/19/10 18:13 Nitrogen,Nitrite ND mg/L 0.10 1 11/19/10 18:13 - 5310B TOG Analytical Method:SM 5310B Total Organic Carbon ND mg/L 1.0 1 11/24/10 01:44 7440-44-0 Date:12/15/2010 10:13AM REPORT OF LABORATORY ANALYSIS Page 9 of 20 This report shall not be reproduced,except in full, without the written consent of Race Analytical Services,Inc.. µ ACCy�o' V�VYM©i /�., ® Pace Analytical Services,Inc. Pace Analytical Services,Inc: aeeMaIX cal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wwwpacela6s.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Asheville Airport Fill Project Pace Project No.: 9282583 Sample: Duplicate-2 Lab ID: 9282583006 Collected: 11/19/10 00:00 Received: 11/19/10 15:45 Matrix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7: Arsenic ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:56 7440-38-2 Barium 27.6 ug/L 5.0 1 11/23/10 10:30 12/02/10 06:56 7440-39-3 Boron ND ug/L 50.0 1 11/23/10 10:30 12/02/10 06:56 7440-42-8 Chromium ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:56 7440-47-3 Copper ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:56 7440-50-8 Iron 570 ug/L 50.0 1 11/23/10 10:30 12/02/10 06:56 7439-89-6 Lead ND ug/L 5.0 1 11/23/10 1.0:30 12/02/10 06:56 7439-92-1 Manganese 83.0 ug/L 5.0 1 11/23/10 10:30 12/02110 06:56 7439-96-5 Nickel ND ug/L 5.0 1 11/23/10 10:30' 12/02/10 06:56 7440-02-0 Selenium ND ug/L 10.0 1 11/23110 10:30 12/02/10 06:56 7782-49-2 Silver ND ug/L 5.0 1 11/23/10 10:30 12/02/10 06:56 7440-22-4 Zinc 12.6 ug/L 10.0 1 11/23/10 10:30 12/02/10 06:56 7440-66-6 200.8 MET ICPMS Analytical Method:EPA 200.8 Cadmium ND ug/L 0.080 1 11/23/10 13:22 11/29/10 01:20 7440-43-9 245.1 Mercury Analytical Method:EPA245.1 Preparation Method:EPA245.1 Mercury ND ug/L 0.20 1 12/02/10 16:25 12/06/1'0 13:44 7439-97-6 2540C Total Dissolved Solids Analytical Method:SM 2540C Total Dissolved Solids ND rng/L 25.0 1 11/23/10 14:19 300.0 IC Anions 28 Days Analytical Method:EPA 300.0 Sulfate ND mg/L 5.0 1 12/13/10 19:11 14808-79-8 363.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA353.2 Nitrogen,Nitrate 1.0 mg/L 0.10 1 11/19/10 18:07 Nitrogen,Nitrite ND mg/L 0.10 1 11/19/10 18:07 5310B TOO Analytical Method:SM 5310B Total Organic Carbon 13.2 mg/L 1.0 1 11/24/10 01:57 7440-44-0 Date:12/15/2010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 10 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. X•CCOp /�,, ® Pace Analytical Services,Inc. -Pace Analytical Services,Inc. aG'e/`II Ia1 �L'al .2225 Riverside Dr. 9800 Kinsey Ave. Suite 106 www.pa6elabs.com Asheville,NC 28804 Huntersvilie,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 QC Batch: MPRP17482 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 METHOD BLANK: 532080 Matrix: Water Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,92825830D5,9282583006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic. ug/L ND 5.0 12/01/1'0 22:41 Barium ug/L ND 5.0 12/01/10 22:41 Boron ug/L ND 50.0 12/01/10 22:41 Chromium uglL ND 5.0 12/01/10 22:41 Copper ug/L ND 5.0 12/01/10 22:41 Iron ug/L ND 50.0 12/61/10 22:41 Lead ug/L ND 5.0 12/01/10 22:41 Manganese ug/L ND 5.0 12/01/10 22:41 Nickel ug/L ND 5.0 12/01/10 22:41 Selenium ug/L ND 10.0 12/01/10 22:41 Silver ug/L ND 5.0 12/01/10 22:41 Zinc ug/L ND 10.0 12/01/10 22:41 LABORATORY CONTROL SAMPLE: 532081 Spike LCS LCS %Res Parameter Units' Cone. Result %Rec Limits Qualifiers Arsenic ug/L 500 507 101 85-115 Barium ug/L 500 506 1'01 85-115 Boron ug/L 500 504 101 85-115 Chromium ug/L 500 521 1.04 85-115 Copper ug/L 500 510 102 85-115 Iron ug/L 5000 5000 100 85-115 Lead ug/L 500 515 103 85-115 Manganese ug/L 500 513 103 85-115 Nickel ug/L 500 516 103 85-115 Selenium ug/L 500- 503 101 85-115 Silver ug/L 250 236 94 85-115 Zinc ug/L 500 504 101 85-115 MATRIX SPIKE SAMPLE: 532082 9282494001 Spike MS MS %Res Parameter Units Result Cone. Result %Res Limits Qualifiers Arsenic ug/L ND 500 511 102 70-130 Barium ug/L 7.2 500 496 98 70-130 Boron ug/L 758 500 1300 107 70-130 Chromium ug/L ND 500 512 102 70-130 Copper ug/L 7.1 500 510 101 70-130 Iron ug/L 765 5000 5620 97 70-130 Lead ug/L ND 500 494 99 70-130 Manganese ug/L 67.0 500 564 99 70-130 Date:12/1512010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 11 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. �o :4L _e, /�., ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. aL'e/'illa'I t'cal 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacefabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 MATRIX SPIKE SAMPLE: 532082 9282494001 Spike MS MS %Ree Parameter Units Result Cone. Result %Ree Limits Qualifiers Nickel ug/L ND 500 502 100 70-130 Selenium ug/L ND 500 503 100 70-130 Silver ug/L ND 250 234 94 70-130 Zinc ug/L 22.9 500 526 101 70-130 MATRIX SPIKE SAMPLE: 532084 9282433012 Spike MS MS %Rec Parameter Units Result Cone. Result %Ree Limits Qualifiers Arsenic ug/L ND 500 473 94 70-130 Barium ug/L 217 500 635 84 70-130 Boron ug/L 972 500 1420 89 70-130 Chromium ug/L ND 500 445 89 70-130 Copper ug/L ND 500 452 90 70-130 Iron ug/L 64.6 5000 4280 84 70-130 Lead ug/L ND 500 436 87 70-130 Manganese ug/L 579 500 987 82 70-130 Nickel ug/L ND 500 433 87 70-130 Selenium ug/L 25.0 5.00 484 92 70-130 Silver ug/L ND 250 212 85 70-130 Zinc ug/L ND 500 453 90 70-130 SAMPLE DUPLICATE: 532083 928249600/ Dup Parameter Units Result Result RPD Qualifiers Arsenic ug/L ND ND Barium ug/L 15.2 15,4 1 Boron ug/L ND 24.7J Chromium ug/L. ND .45J Copper ug/L 10.9 10.9 0 Iron ug/L 293 296 1 Lead ug/L ND ND Manganese ug/L 30.3 30.7 1 Nickel ug/L ND ND Selenium ug/L ND ND Silver ug/L ND ND Zinc ug/L ND 6.4J SAMPLE DUPLICATE: 532085 9282583001 Dup Parameter Units Result Result RPD Qualifiers Arsenic ug/L ND ND Barium ug/L 14.3 14.2 1 Boron ug/L ND 21.1J Chromium ug/L ND 1.2J Date:12/1512010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 12 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. Accoq �+n/( // o :. Pace Analytical Services,Inc. Pace Analytical Services,Inc. alrli/inalfilia/ 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacelab&com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 SAMPLE DUPLICATE: 532085 9282583001 Dup Parameter Units Result Result RPD Qualifiers Copper ug/L ND ND Iron ug/L 209 212 1 Lead ug/L ND ND Manganese ug/L 10.8 10.8 0 Nickel ug/L ND ND Selenium ug/L ND ND Silver ug/L ND ND Zinc ug/L ND 3.51 Date:12/1'5/2010 10:13 AM REPORT OF LABORATORY ANALYSIS Page 13 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. si le = . ® Pace Analytical Services,Inc. Pace Analytical,Sery Ices,Inc : lambalidical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 wwwpabefa6s.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project j Asheville Airport Fill Protect Pace Project No.: 9282583 QC Batch: ICPM/23688 Analysis Method: EPA200.8 QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET Associated Lab-Samples: 9262583001,9282583002,9282583003,9282563004,9282583005,9282583006 METHOD BLANK: 896834 Matrix: Water AssociatedLab Samples: 9282583001,9282583002,9282563003,9282583004.9282563005,9282583006 Blank - Reporting - Parameter Units Result Limit Analyzed .Qualifiers Cadmium ug/L ND 0.080 11/28/10 23:32 LABORATORY CONTROL SAMPLE: 896835 Spike LCS - LCS_ %Rec Parameter Units Cone. Result %Ree Limits Qualifiers Cadmium ug/L 80 78.5 98 85-1115 MATRIX SPIKE SAMPLE: 896838 9282433009 Spike MS MS %Ree Parameter Units Result Cone. Result %.Ree Limits .Qualifiers Cadmium ug/L ND. 80 77.5 97 70-130 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 897088 891689 MS MSD 6089434002 Spike Spike MS MSD MS MSD %Ree Parameter Units Result Cone. Cone. Result Result %Rec. %Ree Limits RPD Qual Cadmium ug/L ND - 80 80 _ 78.6 78.5 981 98 70-130 .06 Date:12115/2010 40:13AM REPORT OF LABORATORY ANALYSIS Page 14 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical.Services,Inc.. Pace Analytical q,, o Services,Inc. Pace Analytical Services,Inc. acef 11Ia')/ical 2225 Riverside Dr. 9800 KinceyAve. Suite 100 wwwpacelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 QC Batch: MERP/3163 Analysis Method: EPA245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 .METHOD BLANK: 534631 Matrix: Water Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 12/06/1'012:22 LABORATORY CONTROL SAMPLE: 534632 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Mercury ug/L 2.5 2.5 100 85-115 MATRIX SPIKE SAMPLE: 534633 9282465001 Spike MS MS %Ree Parameter Units Result Cone. Result %Rec Limits Qualifiers Mercury ug/L ND 2.5 1.8 68 70-130 MO MATRIX SPIKE SAMPLE: 534635 9282433010 Spike MS MS %Ree Parameter Units Result Cone. Result %Rec Limits Qualifiers Mercury ug/L ND 2.5 1.9 74 70-130 SAMPLE DUPLICATE: 534634 9282490001 -Dup Parameter Units Result Result RPD Qualifiers Mercury ug/L ND ND SAMPLE DUPLICATE: 534636 9282433011 Dup Parameter Units Result Result RPD Qualifiers Mercury ug/L ND ND Date:12/15/2010 W:13 AM REPORT OF LABORATORY ANALYSIS Page 15 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. 4 ACCo# L / ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. aL'4]AnaFl/fiL'al 2225 Riverside Dr. 9800 KinceyAve. Suite 100 www.pacelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 QC Batch: WET/14555 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids .. Associated Lab_Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 METHOD BLANK: 532300 Matrix: Water Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/23/10 14:12 LABORATORY CONTROL SAMPLE: 532301 Spike LCS LCS %Roo Parameter Units Coric. Result %Rec Limits Qualifiers Total Dissolved Solids mg/L 250 257 103 80-120 SAMPLE DUPLICATE: 532302 9282294004 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 563 566 1 Date:12/15/201010:13AM REPORT OF LABORATORY ANALYSIS Page 16 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. H ACCpgo, ``�'frh�ie�aca= ® Pace Analytical Services,Inc.., Pace Analytical Servces,Inc..: 225 Riverside Dr. 9800 KinceyAve. Suite 100LeqaIJtiCaI a - wwwpacelabs.com Asheville;NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project- Pace Project No.: 9282583 - QC Batch: WETA/7681 Analysis-Method: EPA300'.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 METHOD BLANK: 150288 Matrix: Water Associated Lab Samples: 9282583001,9282583002;9282583003,9282583004,-9282583005,.9282583006 Blank Reporting Parameter Units Result: Limit Analyzed Qualifiers Sulfate mg/L ND 5.0 12113/1.013:07 LABORATORY CONTROL SAMPLE: 150289- Spike LCS. LCS %Re-c Parameter Units Cone. Result %Ree Limits Qualifiers Sulfate mg/L 50 48.1.. 96 906110 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: -1'50290 150291 MS MSD 9281794012 -Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Sulfate mg/L 4.11 50 50 50.3 50.3 92 92 90=110 .05 MATRIX SPIKE&MATRIX SPIKE DUPLICATE:: 150292 150293 - MS: MSD 9282583005 Spike Spike MS MSD MS MSD %Rec Parameter Units Result 'Cone. Cone. Result Result %Ree %Ree Limits RPD Qual Sulfate mg/L ND 50 50 45.6 45.7 91 91 90-110 .1 Date:12/151201O 1'0:13AM REPORT OF LABORATORY ANALYSIS Page 17 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. . 1 COgOq V ©i /�., /m Pace Analytical Services,Inc._ Pace Analytical Services,Inc. aCe/'illalXicaI 2225 Riverside Dr. _ 9800 KinceyAve. Suite 100 Wwwpace/abs.tom Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project Pace Project No.: 9282583 QC Batch: WETA/8634 Analysis Method: EPA353.2 QC Batch Method: EPA 353.2 Analysis Description:. 353.2 Nitrate+Nitrite,Unpres. Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 METHOD BLANK: 531171 Matrix: Water Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen,Nitrate mg/L ND 0.10 11/19/10 17:42 Nitrogen,Nitrite mg/L ND 0.10 11/19/10 17:42 LABORATORY CONTROL SAMPLE: 531172 Spike LCS LCS %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Nitrogen,Nitrate mg/L 5 4.9 98 90-110 Nitrogen,Nitrite mg/L 1 1.0 105 90-11'0 MATRIX SPIKE SAMPLE: 531173 - 9282433006 Spike MS MS %Ree Parameter Units Result Cone. Result %Ree Limits Qualifiers Nitrogen,Nitrate mg/L 0.36 5 4.9 91 90-110 Nitrogen,Nitrite mg/L ND 1: 0.99 98 90-110 MATRIX SPIKE SAMPLE: 531175 9282433007 Spike MS MS %Ree Parameter Units Result Cone. Result %Ree Limits Qualifiers Nitrogen,Nitrate mg/L 1.9 5 6.5 93 90-110 Nitrogen,Nitrite mg/L ND 1 1.1 110 90-110 .SAMPLE DUPLICATE_: 531174 9282433006 Dup Parameter Units Result Result RPD Qualifiers Nitrogen,Nitrate mg/L 0.36 0.26 30 D6 Nitrogen,Nitrite mg/L ND ND SAMPLE DUPLICATE: 531.176 9282433007 Dup Parameter Units Result Result RPD Qualifiers Nitrogen,Nitrate mg/L 1.9 1.9. 1 Nitrogen,Nitrite mg/L ND ND Date:12/15/2010 10:13AM REPORT OF LABORATORY ANALYSIS Page 18 of20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. �qo ® Pace Analytical Services,Inc.. Pace Analytical Services,Inc. aeeMalXical 2225 Riverside Dr. 9800 Kincey Ave.,Suite 100. www.pacelabs.com Asheville,NC 28804 Huntersville,NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: Asheville Airport Fill Project' Pace Project No.: 9282583 QC Batch: WETA/8655 Analysis Method: SM 5310B QC Batch Method: SM 5310B Analysis Description: 531 OB TOC Associated Lab Samples: 9282583001,92825.83002,9282583003,9282583004,9282583005,9282583006 METHOD BLANK: 532064 Matrix: Water Associated Lab Samples: 9282583001,9282583002,9282583003,9282583004,9282583005,9282583006 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 11123/1:0 22:19 LABORATORY CONTROL SAMPLE: 532065 Spike LCS LCS. %Rec Parameter Units Cone. Result %Rec Limits Qualifiers Total Organic Carbon mg/L 25 25.1 101 90-110 MATRIX SPIKE SAMPLE: 532066 9282433011 Spike MS MS %Rec Parameter Units Result Cone. Result %Ree Limits Qualifiers Total Organic Carbon mg/L 1.2 25 27.4 105 75-125 MATRIX SPIKE SAMPLE: 532067 9282433012 Spike MS MS %Rec Parameter Units Result Cone. Result %Rec Limits Qualifiers Total Organic Carbon mg/L ND 25 27.0 165 75-125 SAMPLE DUPLICATE: 532068 9282583001 Dup Parameter Units Result Result RPD Qualifiers Total Organic Carbon mg/L 1.4 1.4 0 SAMPLE DUPLICATE: 532069 9282583002 Dup Parameter Units Result Result RPD Qualifiers Total Organic Carbon mg/L 14.5 14.4 0 Date:12/15/2010 1'0:13AM REPORT OF LABORATORY ANALYSIS Page 19 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc.. N A_COq �`°i�ielae1= ® :Race Analytical Services,Inc.. Pace Analyticai:Services,Inc.- ,. aceAnalytical. 2225 Riverside Dr.. 9800 KinceyAve. Suite 100 Asheville,NC 28804 Hunters w iIle NC.28076 www.pacetabs.com (828j254-7176 (704)875-9092 QUALIFIERS Project: Asheville Airport Fill Project. i Pace Project No.: 9282583 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes In sample:preparation,.dilution of _the sample aliquot,or moisture content. ND-NoWeteeted at.or above adjusted reporting.limit. J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. S-Surrogate 1,2-Diphenylhydraz!no(8210 listed-analyte)decomposes to Azobenzene. Consistent with EPA guidelines,unround'ed data_are displayed and have been used to.calculate%recovery and RPD values. . LCS(D)-Laboratory Control Sample:(Duplicate) MS(D) Matrix Spike(Duplicate) or DUP+.Sample Duplicate RPD-Relative.Percent Difference. NC-Not_Caleulable. .: U-Indicates the compound was analyzed for,but not detected. N=Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for-. each analyte Is a combined concentration. Pace Analytical Is NELAP accredited.Contact your Pace PM for the current list of accredited analytes. LABORATORIES PAS1-A Pace Analytical Services-Asheville" PASI:-M Pace Analytical Services-Minneapolis PASI-O Pace Analytical Services-Ormond Beach , ANALYTE QUALIFIERS - D8 The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory control limits. Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. Date:12/15/2010 1'0:13 AM REPORT OF LABORATORY ANALYSIS Page 20 of 20 This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,Inc..- un c'k- CHAIN-OF-GUSTO'DY I Analytical Request Document ��aceAnalXica!- The Chalmol Custody Is a LEGAL DOCUMENT.AN relevant fields must-be completed accurately. www.paCNacz.cmn Section Section 8 Section C f Required Cfient Information: Required Project Information: Invoice information: Pag • e• of 1 . company.=, Progress Energy Report To:John Toepfer Attenrbn: 1 Address: 8�1SuttonSiearnRlantRd. CopyTc: -Rob&, Hovrard 6ompanyNarrrgi; R AC Y�•' ; i 1,astii ItGi]L4►CO ...;� �IkC C- NPDES r GROUND WATER r DRINKING WATER' .._. .. ... Pap�uol UST EmaOTe ... ._ .. - :....._. PurcheseOrtlarNo.: " OTHER - r j' RC,RA " (- Phone: Fax. Project Name Asheville Alrimft Fill Project Pae•ProJ�ce Lorri`Patton SI(e LoGat16'n - Ma ', .. Regaa's'ted Due Dat AT: ..... .. Project Numtior.'. .. .....PapnaPmN.'Y: .. ...... -. NC E :���,k•3,;�Reque3ted A7tatysla,'�Flltbred•'(�'/IJ)ram,'%:� Section Valid'NatrlxCodes ? ~Ff _ wh a.Rwr.d,cranrtnfomutbn his CAE a °� COLLECTED PreserTrahves Wa GWATM Y0 :...... .;. _... .. 0 ... .. ... ,..._. '£fir .. TER .. WASTEWATER WW 8 COMPONTE COMPOSRE CF.I �yk+`'� O-.O :. lV .. PRODUCT P 'q START ENDGM W �3` p .0 - Z > F! orsan i . PL SAMPLE ID' W w �? < Z (A•Z,D•9'/,-) OTHER oT I�Ej U 'o O ' ''MUST . O cryp m .ZSamk lD TuE Ts U. Z ,N Y, Z N O iT g LL d - « DATE natE . DATE TIME v, �.2 x _ Z Z � ;O .yr. m- T �, z . Race ProjectNoJ Lab I.D. i MW 1A WT -c JO ::DO g x x .x x x 'x x x x.' -2A WT c / x x x x x x x x X 2 MW s..; Nj 1.. MW-4A wT G 0. ... x x .x x. x .X x .x x. ... w_5 wr G x x X. x x x x x x 5 1=.`Bl 1t WT. c a.60 x x x" x x x' x x x �- s _ k wr G. h x x X. x_ x x. .x x x 01 10 t F . i ,. -., .. ', :.. i; ... ,� rz �. .. :,..:,.. �v-..ac�a��,., d v;.,4..� ,.}. v f - �.x.y.. ,�.Hy 9:VEi •..:•y�... .. a 4 ADD (1IU;C Mt:IRss aI � FNr.'nSMe1d�REL1N tll BY �F Ck s�q] ..s�dA�E MAC DflUA7ibN, 2� A Y '� TWB,F .S%fMRLECON DITIONS .:':•: -.. t 3 �:,-:_ � :•.•...,�.�:..,�:6�y.;�:.:�' .�w4: Q�ti ;�,.:tw "i,^, �. .;�+�._.•?I�sg .@,''A�-,:,ta+:P aVii RIM�r i� �t7MF.. :i:.,i'E�Fi%P•:�fe;a.Sx�W'il ;i •J+`An.�.; er:,_ S,-.nrwra���A�„d�E`�A�b`iI��AR�N� ��'. .�f�N!��:}.:+�t'�,�t��f:�i k�t. ��•�A"� '"•'i�rs' ,'�#l. t� ;7;: ;� o.-. 7� :: PRINT Name ofSAMPLER: E 'DATE Sica c 'SIGNATURE of SAM►L.ER: MMIDD ned YY I 'Imporh'd Not•:BY nViny Wa form yowat:aeppling Papa NET 30 day paymmtIlarm WW apra ft'lorlats cliaryaaof 1.5%Paemnnth for anyW.01ca nor-paid,wthln 30 days. F-ALL-0-020rev.08,72-0'Cf-2007. . Sample Condition UponReceipt CeAnaR1cal Cient Name: pd Project # ate Where Received:- ❑ Huntersville Imo.Asheville . ❑ Eder Courier: ❑.Fed Ex.❑ UPS ❑USPS Bent ❑Commercial --❑ Pace Other O boreal Custody Seal on Cooler/Box Present: , 'yes _❑ no Seals intact:. _-wE yes ❑- no P .Du e e Date: roj. Name: Packing Material: -Bubble Wrap u ble Bags' ❑None ❑Other Thermometer Used: 14-648-44 Type of Ic<Lw;l Blue None les on ice,cooling process has.begun 'Temp Correction Factor: Add:/ btract C Corrected Cooler Temp.: Biological-Tissue ical:Tissue is Frozen: Yes 'No Date and Initials o perso xa ining 1 1 C g contents: Temp should be above freezing to 6°C. Comments- Chain of Custody Present: . dyes QNo DWA -.1. Chain of Custody Filled Out: ZYes ONo EIN/A Chain of.Custody Relinquished: es ONo DIVA '3. Sampler Name&Signature on COC: ' .es ONo: DN/A 4. Samples Arrived:within Hold Time: IE,Tres DNo DIVA, 5. Short Hold Time Analysis 42hr): -Yes DNo E INiA i6. !v' Rush Turn_Around Time Re uested: DYes E7wA y. Sufficient Volume: es ON, 0N/A 8. :Correct Containers Used: as ONo DN/A 9. -Pace Containers Used,* es ON. EINia Containers Intact: es DNo ON/A ;10. Filtered volume received for Dissolved tests <UYes DNo OwA 11. Sample Labels match COC: � YesDNDNo ON/A '12. -Includes date/time/ID/Analysis Matrix: `^'n kil containers needing preservation Have been checked. Yes DNo DIVA 13. :. All containers needing preservation are found to be in yes ONo DwA compliance with EPA reco .dation. �' exceptions: VOAb.coliform,T &G;WI-DRO twaterf .-�Yes DNo _W ialwhen completed. Samples checked for chlorination: OYes DNo A:`:14. Heads:ace in VOA Vials(>6mm) es DNo OwA: 15. :Trip Blank Present: Dyes ONo Pf< 16. Trip Blank Custody Seals Present Oyes ONo WA, !Pace Trip Blank Lot#(if purchased): Client Notificationf Resolution: Field.Data Required? Y / N Person Contacted: Date/Time:: Comments/Resolution: SCURF Review:. Date: I h I I I'ft I SRF Review Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DEHNR Certification Office(Le out of hold,incorrect preservative,out of temp,Incorrect containers) F-ASV-CS-03-Rev.02