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WQ0006017_Residual Annual Report 2020_20210224
Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* W00006017 Applicant/Permittee Town of Beaufort Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Wilmington CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00006017 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * Town of Beaufort RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for Town of Beaufort NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Beaufort NC 2020 Annual Report FINAL.pdf 5.58MB Upload only 1 FCFdocurrent (less than 250 fvB). Miltiple documents rust be contained into one F7Ffile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/24/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 24, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0006017 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Beaufort, NC. If you have any questions or need additional information, please do not hesitate to contact Donovan Willis at (252) 728-7166 or Chris Wynne at 336-909-8627. Sincerely, W�1 01_ I t Derrick Shivar Environmental Compliance Manager Enclosures cc: Donovan Willis — Town of Beaufort Chris Wynne, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF BEAUFORT, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0006017 2020 ANNUAL REPORT Town of Beaufort, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Form 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analysis SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM Permit Number W00006017 County Carteret Year 2020 Facility Name (as shown on permit) Beaufort W WTP NPDES No. NCO021831 Land Application Operator S�nagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year X YES NO, If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summa *Total number of application fields in permit. 2 *Total number of fields utilized for land application during the year. 1 *Total amount of dry tons applied during the year for all application sites. 82.12 *Total number of acres utilized for land application during the year. 40.00 Part B — Annual Compliance Statement Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. I. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .l 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. it. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Donovan Willis, Public Utilities Director Permittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) f � Siw1a �Ofie Sigioture of Land Ap er Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 BEAUFORT,NC BEAUFORT, NC AEROBICALLY DIGESTED CAKE MONTH/YEAR May 2020 IEel f1I AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 500.00 Y 82.12 D 74.48 500.00 Y 82.12 D 74.48 Report Date: 2/2/2021 8:42:31 AM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0006017 Laboratory: Facility Name: BEAUFORT, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: NCO021831 WWTP Name: BEAUFORT Residual Analysis Data Product Type Sample or Composite Date AEDCAK 02/26/20 Parameter (mg1kg dry weight) Ceiling Conc. Limit Percent Solids (°lo) NA 19.50 Arsenic 75 20 Cadmium 85 2.8 Copper 4300 1100 Chromium NA 38 Lead 840 45 Mercury 57 1.8 Molybdenum 75 9 Nickel 420 21 Selenium 100 11 Zinc 7500 2000 Total Phosphorus NA 25000 TKN NA 48000 Ammonia -Nitrogen NA 1000 Nitrate and Nitrite NA 696 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." C Signature of Preparer* Date *Preparer is defined in 40 CFR Part503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 2/112021 10:38:13 AM For: 2226 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM -B Report all sampling analysis results for parameters not listed mFORM nSaFthat are part ofthe VVOpermit nrwere analyzed for over the past calendar year. Use additional forms as needed. xvoPermit Number: vvu0006017 Facility Name: BEAUpnFT,wt Residual Source wPDEo#u,xvc#: won021831 mooTpmumo: osAupnnT Residual Analysis Data Product Type xsooAx Sample n,Composite Date 02/26/20 Parameters (mglkgdry weight) Aluminium 13000 Calcium 48000 Magnesium r000 nn(au.) s.*n Potassium 2400 Sodium rroo p4m 15296 S4R(mauo) aocrn Laboratory: PACE ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accomiancewith u system designed to assure that qualified personnel properly gatheredarmnm|uateduxommnnouonuubmitted.|amawanemmthnmaremOnmoan penalties for submitting false information, inmmunome possibility of fines and imprisonment for knowing violations." c , Signature mprepare ^ Dam 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Nate Roth Project Name: Beaufort WWTP Lot Number:VC03018 Date Completed:03/17/2020 MIM�� Mr� 03/17/2020 3:50 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VC03018 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. ICP Metals Due to low percent solids sample -001 was weighed out 3 times the normal weight. The LOQ has been elevated to reflect the dilution. Nitrate The continuing calibration blank for analytical batch 47694 contained Nitrate greater than the acceptance criteria. The associated sample, VC03018-002, contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received: 03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 03/03/2020 2237 MDD 46788 1 (Ignitability) 1010A 1 03/09/2020 1546 SLC 47298 1 (Paint Filter) 9095B 1 03/12/2020 1035 SLC 1 (Reactive Cya) 7.3.3 1 03/10/2020 0000 KFE 03/10/2020 1046 1 (Reactive Sul) 7.3.4 1 03/10/2020 1925 HET 03/10/2020 1046 1 (Soil pH meas) 9045D 1 03/05/2020 2203 SRB 47065 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 19.1 % 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Paint Filter Test 9095B Pass pass/fail 1 Reactive Cyanide 7.3.3 ND 50 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 50 mg/kg 1 Soil pH measured in water @ 20.9 o C 9045D 6.5 su 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 03/13/2020 0417 JTH 47756 03/11/2020 2110 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D 0.0060 J 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 103 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 67 37-129 2-Fluorophenol 40 24-127 Nitrobenzene-d5 74 38-127 Phenol-d5 81 28-128 Terphenyl-d14 85 10-148 2,4,6-Tribromophenol 74 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 03/16/2020 1801 JJG 03/12/2020 1747 47726 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 75 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 77 20-131 Tetrachloro-m-xylene 83 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 03/10/2020 1028 LLL 03/09/2020 2018 47306 03/08/2020 2357 1 1311/7470A 7470A 1 03/10/2020 1520 KSH2 03/10/2020 0941 47316 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.41 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 10 Client:Synagro Laboratory ID:VC03018-002 Description: B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.5 03/03/2020 2237 Date Received: 03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 03/03/2020 2237 MDD 46788 1 350.1 (Ammonia - N ) 350.1 5 03/09/2020 1322 SLC 46871 1 (Nitrate - N ) 9056A 5 03/11/2020 1758 AMR 47694 1 (Nitrite - N ) 9056A 5 03/11/2020 1758 AMR 47697 1 (Phosphorus) 365.1 250 03/06/2020 1456 DMA 03/06/2020 0937 47087 1 (Soil pH meas) 9045D 1 03/05/2020 2205 SRB 47065 1 351.4 (TKN) 351.2 5 03/04/2020 1550 DMA 03/04/2020 1002 46808 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 19.5 % 1 Ammonia - N (gas diffusion) 350.1 1000 26 13 mg/kg 1 Nitrate - N (soluble) 9056A 680 13 0.63 mg/kg 1 Nitrite - N (soluble) 9056A 16 5.1 0.49 mg/kg 1 Phosphorus 7723-14-0 365.1 25000 6400 1300 mg/kg 1 Soil pH measured in water @ 20.9 ° C 9045D 6.4 su 1 TKN 351.2 48000 640 640 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 10 03/04/2020 1632 KSH2 03/04/2020 1230 46714 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 1.8 J 3.6 0.88 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 601 OD 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 13000 30 11 mg/kg 1 Arsenic 7440-38-2 6010D 20 2.3 0.76 mg/kg 2 Cadmium 7440-43-9 6010D 2.8 0.76 0.19 mg/kg 2 Calcium 7440-70-2 6010D 48000 760 95 mg/kg 2 Chromium 7440-47-3 6010D 38 0.76 0.19 mg/kg 1 Copper 7440-50-8 6010D 1100 1.5 0.68 mg/kg 2 Iron 7439-89-6 6010D 45000 15 6.9 mg/kg 2 Lead 7439-92-1 6010D 45 1.5 0.68 mg/kg 2 Magnesium 7439-95-4 6010D 7000 380 47 mg/kg 1 Manganese 7439-96-5 6010D 900 1.1 0.45 mg/kg 1 Molybdenum 7439-98-7 6010D 9.0 3.0 0.76 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 10 Client:Synagro Laboratory ID:VC03018-002 Description: B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.5 03/03/2020 2237 Date Received:03/03/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 6010D 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 21 6.1 1.6 mg/kg 2 Potassium 7440-09-7 6010D 2400 380 47 mg/kg 1 Selenium 7782-49-2 6010D 11 3.0 1.2 mg/kg 2 Sodium 7440-23-5 6010D 7700 380 47 mg/kg 1 Zinc 7440-66-6 6010D 2000 3.8 0.95 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 10 PACE ANALYTICAL SERVICES, LLC I -6 E41 i I 2j 51 42 m hP F c � ° YF I • i TJ � { — c11a�3 11 V = O � ti5 d � 93F°JJ�i �U� 90 l4 Ems) Enad ah' Ln Uo He X 111 r �,I�L x OC _ .a r aOpImP4 .9F•rA.gis, E d IEnj Cr .r 1:7L1�[1 sr• j 2 :.) L :7 L h o 3 J � i4 U C m f _ r1� CCC� 4W. rip ea LA d _' J ice' y.i '4 n I � IL 7i -0 p a ppI� i Mr 7IF 53 � rr y, fD w O i1 " fY r; o Lj � gy w d c +• z _ Q ar " i 2 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 10 PACE ANALYTICAL SERVICES, LLC Slimly GrvirpnmmAl ci�iu�� Inc. L'aeumeneNur.,cr; -09)U;at-l9 liairriwr0me 62'TCIB amp(c Receipt Checklist (SRC C~1ie;n[: S}+ysnro Cools l:nspectad byid'Qw- [mac { s7 }03l2420 Lour VC03018 Mcausofreceipt: ❑ SESI ❑ CIic-it © UPSO Foci& 0 OUT: ❑ Y'es ®NO 1. Were cuero Seals preserrc on ft coo'eff ja Yas N❑ NL A2. If cmrodv stalH wept OMBEFC, were Lhl!y ntwc a.nd unhu-nkan'? Fri [ ';[rip r(). NA Chlorine Strip ID- NA Tested bu- NA ! Odginsi temperature U0011 rot;rapt { Dgrived (C[�mmod) tellr_pnral.ure upor. re iPt 4.a {4, f1C NA jNA vC NA lNA fiC NIA YNA -- Method; ®Trar[pernture 131snk L:]Aga'nst Hordes JR Gun ID' ii IR Gres Corructian Vactor, 0 "C lldi,t[~od ofcaul;rnt; 0 VkIe[ lac ❑ Ice PfV. s 0 I)ry Ice F] None ❑ Yc-y D NO ONA 3_ ICtarnperature of any ennlar exceeded 6d1`I , was Project Vlaneger N tified7 P61 wus Notifi!d by, phone f einail i frvr_-to-faca (circie Rio}. Ym No nNA 4. Is the Commeraiel unurim— s cki Slip attached to [his Firm? Jz Yes [ Nv ' 3, Were or oustcdV JAX3QUdU.TCS (relinqu irhesjJrear.eiuvd) fol1uwcd7 'es Nn {r_ %Vcrf OM131a IDs on toe COCs? 14 Yet ❑ LNG 7_ WC, 0 sample IDS ]isw on all =110[C mltaiacm? Yes 0 No R_ Was collection dais Rr. tirl$ fisted Qr9 COCOC7 [J Yes C%] N 9_ Was r.,,llection dUe & dmc listed on al[ Sample containers? ff Ye.3 Q No 10, Did a IJ container label inform ari[ial OD, date, time) agrr- w ixil the QQC^ — a Yes ❑ Nn ' I. 1,1rrlr- tests to be performed I:sted on the CAC? c; L 7 12. DJd A samules arrive in tPrc proper conluirrrs (breach lei andlar _In goad cxmditian (unbroken, ]idg on, h41 � es LJ No El ] 3. 14ras adC uatc sa u,,ie w�llrmg avai[ab'e? Ye~ ® Nr~ 114. Weir, a[i samples rr:Givcd wittin i5 the holding time or48 hours. 4wlkirL.hr}ter antes first;% 71 YCS 115.lVdiroany san [-e£Coraauter£,rlissin 'cxoes.(elrcletne)sairples NX listed on C OC? I& For VDA and RSK-] 7s sum pies, were Wobles present sizcR ('fa"or Gistm In +Jirrrn ter) ❑ Yes ❑ w 0 NA in any of tltie VOA vials" ❑ Yes 11kn YJ NA 17- Wtiv va [ DRO/meta[s/nutrierr sam [cs v- c ivod at a pH of < r — ❑ Yes Q No Z A~ 1$. wcro alJ cyanide Sam [es received at a FJII > 12 and str,fide sa„rples rc{XiVOd at a PTJ> 9F i9, 14ere all app ace a NIdA F [4�ysnide+fl,tno 25 (< 0_.Srie1) samples ('rcr ❑ residua] �] Yes � No � N.� ❑ves L2NoV]NA20_We.�raclient rernarksfn�uests(i.e.rrqunteridiIUEIOIL9.IMiSASDdesignadous,etc uxrvdly timscribed Cram the COC into the commem wedon irl I.I?VT9 C -yQ NO: 21. Was the uU;i: number I icterl nn the contain er libel'( lf yes, Qum j NA sampt2 l'r cmfttiian (Mwt 1,C rrm-plated For any saruple(S) inctwrmrly pvmrmf vT with headspacc.) mpJe(s) NA werarecei�red inccxrcctJy PMiMrVQd acid WereadjurJ g s[eccorc{Jngly sarl,pie=rcceivingwith NA mLufi hill;one:112$Q4.HNO3,IICJ„-NaOHirsuIgSRJ~ NA ne of t,n e-yra*ion NA_. . If mlxe thar one presmative is netMe;i, please ruAc in 1-3 car nmr5 below- NA Ieere rCMived wide bubbJcs>6lnrn Sri diameter_ [s] NA hand ere -eceived with TRC> 0.5 mgf1. (If 919 is lro) awctz acoordh gly i_r %Lunpin remMilg with sodium, thiosulfate {Nay 31Q;) kti i [h Shealy Ell NA balrcodv labeis applied M}= BWO Da[OM3MH Colulllerrly; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 10 SECTION 3 FACILITY NAME: BEAUFORT, NC LANDOWNER: WALTER WETHERINGTON OPERATOR: ROBERT RIGGS CROP 1 NAME: CORN (C) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M WQ0006017 FIELD* NC-CR-00007-0-0003-B ANNUAL DRY TONS APPLIED: 82.12 SITE* NC CR 00007 PREDOMINANT SOIL SERIES: NORFOLK CROP 1 MAX. PAN: 131 CROP 2 NAME: Page: 1 ACRES UTILIZED: 40.0 ACRES PERMITTED: 40.0 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crap Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 514/20, 500.00 (Y) 19.500 2.053 BAEDC DRY "0-<1/2" SURIN 1.0 0.30 48,000.00 1,000.00 696.00 64.856 C May-20 500.00 (Y) i Total 2.053 Total 64.856 0.000 AS CD CU CR PB HG MO NI SE ZN P I ILime Applied Annual lbs/acre Applied 0.082 1 0.012 4.516 1 0.156 1 0.185 0.007 1 0.037 1 0.086 0.045 1 8.212 1 102,646 1 1 Data I Lbs/Ac Cumulative Ibs/acre Applied 0.939 0.387 77.239 I 22.578 5.508 0.327 I 1.012 E 9.704 R 0.552 116.765 i I Permit PAN Limit (Ibs/acre) 1st Crop, 131 I Federal C.P.L.R. (Ibs/acre)"'** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 BAEDC = BEAUFORT, NC AEROBICALLY DIGESTED CAKE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalti o ub g false information, including the possibility of fines and impriso 7 nt or knowing violations Z zl SIGN U E OF LAND APPLIER ATE NR = Not Reported or Not Requi d **" Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/112021 DENR FORM FSF (1212006) SECTION 4 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Nate Roth Project Name: Beaufort WWTP Lot Number:VC03018 Date Completed:03/17/2020 MIM�� Mr� 03/17/2020 3:50 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VC03018 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. ICP Metals Due to low percent solids sample -001 was weighed out 3 times the normal weight. The LOQ has been elevated to reflect the dilution. Nitrate The continuing calibration blank for analytical batch 47694 contained Nitrate greater than the acceptance criteria. The associated sample, VC03018-002, contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received: 03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 03/03/2020 2237 MDD 46788 1 (Ignitability) 1010A 1 03/09/2020 1546 SLC 47298 1 (Paint Filter) 9095B 1 03/12/2020 1035 SLC 1 (Reactive Cya) 7.3.3 1 03/10/2020 0000 KFE 03/10/2020 1046 1 (Reactive Sul) 7.3.4 1 03/10/2020 1925 HET 03/10/2020 1046 1 (Soil pH meas) 9045D 1 03/05/2020 2203 SRB 47065 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 19.1 % 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Paint Filter Test 9095B Pass pass/fail 1 Reactive Cyanide 7.3.3 ND 50 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 50 mg/kg 1 Soil pH measured in water @ 20.9 o C 9045D 6.5 su 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 03/13/2020 0417 JTH 47756 03/11/2020 2110 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D 0.0060 J 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 98 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 103 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 03/12/2020 1632 SCD 03/10/2020 1710 47402 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 67 37-129 2-Fluorophenol 40 24-127 Nitrobenzene-d5 74 38-127 Phenol-d5 81 28-128 Terphenyl-d14 85 10-148 2,4,6-Tribromophenol 74 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 03/16/2020 1801 JJG 03/12/2020 1747 47726 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 75 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 10 Client:Synagro Laboratory ID:VC03018-001 Description: Beaufort 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.1 03/03/2020 2237 Date Received:03/03/2020 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 03/13/20201606 DAL1 03/11/20201452 47527 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 77 20-131 Tetrachloro-m-xylene 83 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 03/10/2020 1028 LLL 03/09/2020 2018 47306 03/08/2020 2357 1 1311/7470A 7470A 1 03/10/2020 1520 KSH2 03/10/2020 0941 47316 03/08/2020 2357 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.41 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 10 Client:Synagro Laboratory ID:VC03018-002 Description: B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.5 03/03/2020 2237 Date Received: 03/03/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 03/03/2020 2237 MDD 46788 1 350.1 (Ammonia - N ) 350.1 5 03/09/2020 1322 SLC 46871 1 (Nitrate - N ) 9056A 5 03/11/2020 1758 AMR 47694 1 (Nitrite - N ) 9056A 5 03/11/2020 1758 AMR 47697 1 (Phosphorus) 365.1 250 03/06/2020 1456 DMA 03/06/2020 0937 47087 1 (Soil pH meas) 9045D 1 03/05/2020 2205 SRB 47065 1 351.4 (TKN) 351.2 5 03/04/2020 1550 DMA 03/04/2020 1002 46808 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 19.5 % 1 Ammonia - N (gas diffusion) 350.1 1000 26 13 mg/kg 1 Nitrate - N (soluble) 9056A 680 13 0.63 mg/kg 1 Nitrite - N (soluble) 9056A 16 5.1 0.49 mg/kg 1 Phosphorus 7723-14-0 365.1 25000 6400 1300 mg/kg 1 Soil pH measured in water @ 20.9 ° C 9045D 6.4 su 1 TKN 351.2 48000 640 640 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 10 03/04/2020 1632 KSH2 03/04/2020 1230 46714 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 1.8 J 3.6 0.88 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 601 OD 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 13000 30 11 mg/kg 1 Arsenic 7440-38-2 6010D 20 2.3 0.76 mg/kg 2 Cadmium 7440-43-9 6010D 2.8 0.76 0.19 mg/kg 2 Calcium 7440-70-2 6010D 48000 760 95 mg/kg 2 Chromium 7440-47-3 6010D 38 0.76 0.19 mg/kg 1 Copper 7440-50-8 6010D 1100 1.5 0.68 mg/kg 2 Iron 7439-89-6 6010D 45000 15 6.9 mg/kg 2 Lead 7439-92-1 6010D 45 1.5 0.68 mg/kg 2 Magnesium 7439-95-4 6010D 7000 380 47 mg/kg 1 Manganese 7439-96-5 6010D 900 1.1 0.45 mg/kg 1 Molybdenum 7439-98-7 6010D 9.0 3.0 0.76 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 10 Client:Synagro Laboratory ID:VC03018-002 Description: B 2020 Matrix: Solid Date Sampled:02/26/2020 1100 % Solids: 19.5 03/03/2020 2237 Date Received:03/03/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/09/2020 1924 LLL 03/06/2020 1452 46709 2 3050B 6010D 2 03/09/2020 2241 LLL 03/06/2020 1452 46709 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 21 6.1 1.6 mg/kg 2 Potassium 7440-09-7 6010D 2400 380 47 mg/kg 1 Selenium 7782-49-2 6010D 11 3.0 1.2 mg/kg 2 Sodium 7440-23-5 6010D 7700 380 47 mg/kg 1 Zinc 7440-66-6 6010D 2000 3.8 0.95 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 10 PACE ANALYTICAL SERVICES, LLC I -6 E41 i I 2j 51 42 m hP F c � ° YF I • i TJ � { — c11a�3 11 V = O � ti5 d � 93F°JJ�i �U� 90 l4 Ems) Enad ah' Ln Uo He X 111 r �,I�L x OC _ .a r aOpImP4 .9F•rA.gis, E d IEnj Cr .r 1:7L1�[1 sr• j 2 :.) L :7 L h o 3 J � i4 U C m f _ r1� CCC� 4W. rip ea LA d _' J ice' y.i '4 n I � IL 7i -0 p a ppI� i Mr 7IF 53 � rr y, fD w O i1 " fY r; o Lj � gy w d c +• z _ Q ar " i 2 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 10 PACE ANALYTICAL SERVICES, LLC Slimly GrvirpnmmAl ci�iu�� Inc. L'aeumeneNur.,cr; -09)U;at-l9 liairriwr0me 62'TCIB amp(c Receipt Checklist (SRC C~1ie;n[: S}+ysnro Cools l:nspectad byid'Qw- [mac { s7 }03l2420 Lour VC03018 Mcausofreceipt: ❑ SESI ❑ CIic-it © UPSO Foci& 0 OUT: ❑ Y'es ®NO 1. Were cuero Seals preserrc on ft coo'eff ja Yas N❑ NL A2. If cmrodv stalH wept OMBEFC, were Lhl!y ntwc a.nd unhu-nkan'? Fri [ ';[rip r(). NA Chlorine Strip ID- NA Tested bu- NA ! Odginsi temperature U0011 rot;rapt { Dgrived (C[�mmod) tellr_pnral.ure upor. re iPt 4.a {4, f1C NA jNA vC NA lNA fiC NIA YNA -- Method; ®Trar[pernture 131snk L:]Aga'nst Hordes JR Gun ID' ii IR Gres Corructian Vactor, 0 "C lldi,t[~od ofcaul;rnt; 0 VkIe[ lac ❑ Ice PfV. s 0 I)ry Ice F] None ❑ Yc-y D NO ONA 3_ ICtarnperature of any ennlar exceeded 6d1`I , was Project Vlaneger N tified7 P61 wus Notifi!d by, phone f einail i frvr_-to-faca (circie Rio}. Ym No nNA 4. Is the Commeraiel unurim— s cki Slip attached to [his Firm? Jz Yes [ Nv ' 3, Were or oustcdV JAX3QUdU.TCS (relinqu irhesjJrear.eiuvd) fol1uwcd7 'es Nn {r_ %Vcrf OM131a IDs on toe COCs? 14 Yet ❑ LNG 7_ WC, 0 sample IDS ]isw on all =110[C mltaiacm? Yes 0 No R_ Was collection dais Rr. tirl$ fisted Qr9 COCOC7 [J Yes C%] N 9_ Was r.,,llection dUe & dmc listed on al[ Sample containers? ff Ye.3 Q No 10, Did a IJ container label inform ari[ial OD, date, time) agrr- w ixil the QQC^ — a Yes ❑ Nn ' I. 1,1rrlr- tests to be performed I:sted on the CAC? c; L 7 12. DJd A samules arrive in tPrc proper conluirrrs (breach lei andlar _In goad cxmditian (unbroken, ]idg on, h41 � es LJ No El ] 3. 14ras adC uatc sa u,,ie w�llrmg avai[ab'e? Ye~ ® Nr~ 114. Weir, a[i samples rr:Givcd wittin i5 the holding time or48 hours. 4wlkirL.hr}ter antes first;% 71 YCS 115.lVdiroany san [-e£Coraauter£,rlissin 'cxoes.(elrcletne)sairples NX listed on C OC? I& For VDA and RSK-] 7s sum pies, were Wobles present sizcR ('fa"or Gistm In +Jirrrn ter) ❑ Yes ❑ w 0 NA in any of tltie VOA vials" ❑ Yes 11kn YJ NA 17- Wtiv va [ DRO/meta[s/nutrierr sam [cs v- c ivod at a pH of < r — ❑ Yes Q No Z A~ 1$. wcro alJ cyanide Sam [es received at a FJII > 12 and str,fide sa„rples rc{XiVOd at a PTJ> 9F i9, 14ere all app ace a NIdA F [4�ysnide+fl,tno 25 (< 0_.Srie1) samples ('rcr ❑ residua] �] Yes � No � N.� ❑ves L2NoV]NA20_We.�raclient rernarksfn�uests(i.e.rrqunteridiIUEIOIL9.IMiSASDdesignadous,etc uxrvdly timscribed Cram the COC into the commem wedon irl I.I?VT9 C -yQ NO: 21. Was the uU;i: number I icterl nn the contain er libel'( lf yes, Qum j NA sampt2 l'r cmfttiian (Mwt 1,C rrm-plated For any saruple(S) inctwrmrly pvmrmf vT with headspacc.) mpJe(s) NA werarecei�red inccxrcctJy PMiMrVQd acid WereadjurJ g s[eccorc{Jngly sarl,pie=rcceivingwith NA mLufi hill;one:112$Q4.HNO3,IICJ„-NaOHirsuIgSRJ~ NA ne of t,n e-yra*ion NA_. . If mlxe thar one presmative is netMe;i, please ruAc in 1-3 car nmr5 below- NA Ieere rCMived wide bubbJcs>6lnrn Sri diameter_ [s] NA hand ere -eceived with TRC> 0.5 mgf1. (If 919 is lro) awctz acoordh gly i_r %Lunpin remMilg with sodium, thiosulfate {Nay 31Q;) kti i [h Shealy Ell NA balrcodv labeis applied M}= BWO Da[OM3MH Colulllerrly; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 10 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Beaufort WQ Permit Number: W00006017 WWTP Name: Town of Beaufort WWTP NPDES Number: NCO021831 Monitoring Period: From 01/01/2020 _ To 12/31/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlieahle to alternative nerformed (Class A or Class M comalete the followinu monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Gen. Mean Maximum Units dences Analysis Fecal 2xl0to the 61 MPN MPN/g Coliform power per gram of total solids <5690 <5840 <6170 CFU/g 0 Annually Grab SM9222D CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0ption/Alt. I Option/Alt. 2 (VS reduction) (40-day bench) _ Option/Alt. 5 Option/Alt. 6 (14-Day Aerobic) (Alk Stabilization) _ Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) X CERTIFICATION STATEMENT (please check the appropriate statement) Option/Alt. 3 Option/Alt. 4 (30-day bench) (Spec. 02 uptake) Option/Alt. 7 Option/Alt. 8 (Drying — Stable) (Drying — Unstable) No vector attraction reduction alternatives were performed "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Donavan Willis, Director of Public Works Preparer Name and Title (type or print) Signature of Preparer* Date Todd Larson, Operations. Director Land Applier Nam n t it1 ^ if applied 1 or print) -4 Signature f pplier ( pplicable) ater *Preparer is defined in 40 CFR Part 503.9(r) and 15ANCAC 2T.1102 (26) Cameron Testing Services, Inc. Laboratory Report Client: Synagro CTS Prof, 2003-053 Project: Beaufort Regulatory Yes Sample Information Sampled N. Roth Date 03105/20 Raceived M. Sims Date 03105120 Analyses and Results Lab 10 Sample 10 j E Aftalyte Result Reference 2003�053 1 skdof of Fee, Coliform-S <5890 cFuV 5890 OWOSM RL 9222D - MF 2 <5890 cfutq 5890 3 <5700 m4 6700 4 <5090 CFUV 5690 <5690 cFuv 5690 <5880 CFU'V 5880 7 <6170 CMV 6170 C*omean <5840 2003-053 01 1 3UV or TSM 17.01/a 0.01 GIT&W RL 2540 G -TS 2 1T0% 001 3 IT6% 001 4 17,6% 001 5 17,6% 40t 6 17.0% 001 7 16.2% 001 Report Review Lat, Director Daw 21195 stocle%tr 9194A)8-42240 Swford NC 27330 dwWOCatnoont"ling,com III-AA4-&t kk� 1111A Cameron Testing Services, Inc Chain of Custody pwoe 919-ZO44240 NC,G , #,654NOfWHSC&A#3tMUSEPA NCO1918 page of COMWOY: I* 405yn OYIJ 4, C 11 CTS lair use contact. phonef Sa"Ve Ttmv Pr i' I v' �. Far # (M Ater ' Rush C"Y N) Sample "•q�r: 3�C�;: rah; Isamele Information Nvm er of beftl I*e ve AreTe i nat i Client ste r d.1 t r eie h-i Project � Date, Checked in B 'OIL ra cr. I t ` Delivered ���I ed CTS isus il General Courier UPS Checked for Pmervative by pH Check t {1? W C $ G j f p!P/ psi .e *VS(A��{#��pt'IQ3 y �[{ NaOH m d%l�OHDW#`WW#S _ } p yaq�y7 � TGN q;� +F .#'�fi i'R.:, �ififi.+F'� 1-F s€ W/W I Cilia PIG MC 04 NaOH W I WW / I G P rat Ham- Phos NWOH < MW [' WW d A:.t' G V # Nam HCL .. .. H#+a7'k.T f hWO3 Z'hin FY$F4�Y8 C { DW I WW / / / Now Pis f DW f WW S g+.yt� / G G igO«�N. g bh Fg�L��-.r+ �y L 3 ph S$O < 1 $ WW 1 S Ili 'P _ i�� / G qt N .. HC .y04 2SSO4 3 'R .•m N#OH W/ WW :/ / G E" / G Nm HCL Ii2mg HNO3 P WIS t+f" - DW P W T P f Wes` I I C/ G i F SiteNow P/ G None HCL eS H2SO4NW .HNO3 S.jI4 NaGif C { e I COMMENTS- SECTION 6 Agricultural Lime Application Log Year: 2020 Beaufort, NC *Lime will be spread when conditions improve SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031973 �5{i �141..tiL Client: Robert B (Bobby) Riggs Advisor: Chris Wynne Predictive 483 Wetherington Landing Rd 483 Bogar Road ;• Stella, NC 28582 Mocksville, NC 27028 +;. Soil Report Mehlich-3 Extraction Sampled County: Craven Links to Helpful Information Client ID: 238686 Advisor ID: 509090 Sampled: 05/01/2020 Received: 06/09/2020 Completed: 06/16/2020 Farm: CR-07 Sample ID: 3B Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Corn, grain 0.5 120 - 160 0 70 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.66 1.26 4.4 72 1.2 5.5 285 35 57 11 42 68 58 339 339 349 0.1 2 Noah Carolina i� Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO31973 Robert B (Bobby) Riggs Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm