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WQ0014885_Residual Annual Report 2020_20210223
Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0014885 Applicant/Permittee Harnett County Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office Fayetteville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00014885 Has Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * Harnett County DCAR Please provide comments/notes on your current submittal below. 2020 Annual Report for Harnett County WTP NC for Class A Residuals At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Harnett Co WTP 2020 Annual Report FINAL.pdf 4.66MB Upload only 1 FCFdocurrent (less than 250 fvB). Multiple documents rust be combined into one F7Ffile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/23/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 23, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0014885 Dear NCDEQ: SYNAGRO Enclosed is one electronic copy of the above referenced report on behalf of Harnett WTP Class A Residuals under Permit No. WQ0014885. If you have any questions or comments, please contact Steve Ward at (910) 893-7575 or Chris Wynne at (336) 909-8627. Sincerely, oe"i& Shuuc" ,es Derrick Shivar Environmental Compliance Manager Enclosures cc: Steve Ward, Harnett County Chris Wynne, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD HARNETT COUNTY WTP, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0014885 2020 ANNUAL REPORT Harnett County WTP, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WQ0014885 County Harnett Year 2020 Facility Name (as shown on permit) Harnett County Utilities Regional WTP PWS ID No. 00-076-84 Land Application Operator Synagro Phone# (330 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: N/A Total number of fields utilized for land application during the year: 1 Total amount of dry tons applied during the year for all application sites: 463.12 Total number of acres utilized for land application during the year: 42.2 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. S. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T . i I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality, 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. if. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, includ' the possibility of fines and imprisonment for knowing violations." jJ Steve Ward Director of Public Utilities Permittee Name and Title (type or print) Signature of Preparer* Date Signaure oTLand ApMer . (if different from Permittee) (if different from Permittee and Preparer) 1.2 ~ +(- V *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 HARNETT CO. UTILITIES, NC HARNETT CO. UTIL., NC COH REGIONAL WTP LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS January 2020 1,054,000.00 G 92.30 D 83.71 February 2020 694,400.00 G 60.81 D 55.15 March 2020 626,200.00 G 54.84 D 49.74 April 2020 266,600.00 G 23.35 D 21.17 September 2020 731,600.00 G 64.07 D 58.11 October 2020 1,915,800.00 G 167.77 D 152.16 TOTAL 5,288,600.00 G 463.12 D 420.05 Report Date: 2/7/2021 1:17:22 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0014885 Laboratory: Facility Name: HARNETT CO. UTILITIES, NC PACE ANALYTICAL; PACE ANALYTICAL Residual Source WQ # or SERVICE INC. NPDES#: NC0007684 WWTP Name: COH REGIONAL WTP Residual Analysis Data Product Type WPL WPC WPL WPC WPC Sample or Composite Date 02/05/20 04/21/20 04/21/20 09/29/20 10/22/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 2.10 25.90 25.90 24.80 25.80 Arsenic 75 12 10 10 17 14 Cadmium 85 <0.97 <0.16 <0.16 <0.082 <0.076 Copper 4300 480 150 150 120 230 Chromium NA 46 32 32 19 22 Lead 840 17 13 13 15 <0.27 Mercury 57 <0.84 <0.074 <0.074 <0.077 <0.34 Molybdenum 75 10 7.3 7.3 18 14 Nickel 420 21 16 16 9 12 Selenium 100 <6.3 <1 <1 6.4 <4.9 Zinc 7500 86 62 62 77 84 Total Phosphorus NA 2600 1600 1600 2300 2100 TKN NA 9800 7100 7100 8600 8900 Ammonia -Nitrogen NA 99 15 15 4 35 Nitrate and Nitrite NA 28 3.77 3.77 2.74 5.06 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel proper► athere nd evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fin dim nment for knowing violations." Signature of Preparer* Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2TA 102(26) DENR FORM RSSF-B (12/2006) Printed: 2/10/2021 10:47:04 AM For: 2037 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0014885 Laboratory: Facility Name: HARNETT CO. UTILITIES, NC PACE ANALYTICAL; PACE ANALYTICAL Residual Source SERVICE INC. NPDES # or WQ#: NC0007684 WWTP Name: COH REGIONAL WTP Residual Analysis Data Product Type WPL WPC WPL WPC WPC Sample or Composite Date 02/05/20 04/21/20 04/21/20 09/29/20 10/22/20 Parameters (mglkg dry weight) Aluminium 190000 130000 130000 150000 <9 Calcium 1100 610 610 530 820 Magnesium 2300 1400 1400 860 940 pH (s.u.) 5.40 5.30 5.30 5.90 5.80 Potassium 1700 810 810 630 670 Sodium 880 60 60 130 190 PAN 2018 11 1428 5 8900 SAR (Ratio) 0.4993 0.1548 0.1548 0.4018 0.5432 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imp ' onment for knowing violations." 1 fg Signature of Pr'eparer" Date Treparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2/10/2021 10:45:57 AM For: 2037 01 DENR FORM RSSF-B (12/2006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Melinda Boyd Project Name: Harnett County WTP Lot Number:VB11019 Date Completed:02/21/2020 NIM�� Mr� 02/24/2020 4:19 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VB11019 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low % solids, the initial mas for sample -001 was 3 times the standard procedure amount. The LOQ has been adjusted accordingly. Paint Filter Sample -001 has been qualified with an "H", however, there is not a method defined hold time for this parameter. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 02/11/2020 2239 MDD 44610 1 (Ignitability) 1010A 1 02/17/2020 1302 SLC 45230 1 (Paint Filter) 9095B 1 02/20/2020 0855 SLC 1 (Reactive Cya) 7.3.3 1 02/17/2020 1716 MSG 02/13/2020 1106 1 (Reactive Sul) 7.3.4 1 02/17/2020 1623 HET 02/13/2020 1106 1 (Soil pH meas) 9045D 1 02/13/2020 2010 SRB 44964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.72 % 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Paint Filter Test 9095B Fail H* pass/fail 1 Reactive Cyanide 7.3.3 ND 50 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 50 mg/kg 1 Soil pH measured in water @ 19.9 o C 9045D 5.3 su 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 02/19/2020 1130 TML 45473 02/17/2020 2010 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D 0.0090 J 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 103 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 02/17/2020 1258 JCG 02/13/2020 1404 44836 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 02/17/2020 1258 JCG 02/13/2020 1404 44836 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 74 37-129 2-Fluorophenol 59 24-127 Nitrobenzene-d5 69 38-127 Phenol-d5 73 28-128 Terphenyl-d14 109 10-148 2,4,6-Tribromophenol 79 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 02/19/2020 1456 DAL1 02/16/2020 2002 45138 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 80 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 02/17/2020 1155 DAL1 02/13/2020 1404 44834 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 02/17/2020 1155 DAL1 02/13/2020 1404 44834 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 35 20-131 Tetrachloro-m-xylene 83 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 02/14/2020 1240 LLL 02/13/2020 0004 44776 02/11/2020 1949 1 1311/7470A 7470A 1 02/17/2020 1640 JMH 02/17/2020 1024 44810 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.043 J 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 Footnote(s): 'Paint Filter: 97mL collected; LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 10 Client:Synagro Laboratory ID:VB11019-002 Description: Harnett WTP 1 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.10 02/11/2020 2239 Date Received: 02/11/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 02/11/2020 2239 MDD 44610 1 350.1 (Ammonia - N ) 350.1 1 02/19/2020 1252 SLC 45301 1 (Nitrate - N ) 9056A 1 02/15/2020 1840 HKL 45243 1 (Nitrite - N ) 9056A 1 02/15/2020 1840 HKL 45244 1 (Phosphorus) 365.1 2 02/14/2020 1442 DMA 02/14/2020 1008 44986 1 (Soil pH meas) 9045D 1 02/11/2020 2105 SRB 44620 1 351.4 (TKN) 351.2 1 02/21/2020 1315 DMA 02/19/2020 0951 45417 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.10 % 1 Ammonia - N (gas diffusion) 350.1 99 48 25 mg/kg 1 Nitrate - N (soluble) 9056A 28 24 1.2 mg/kg 1 Nitrite - N (soluble) 9056A ND 9.5 0.92 mg/kg 1 Phosphorus 7723-14-0 365.1 2600 480 95 mg/kg 1 Soil pH measured in water @ 21.3 ° C 9045D 5.4 su 1 TKN 351.2 9800 1200 1200 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 02/15/2020 1030 KSH2 02/14/2020 1327 45001 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.5 0.84 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 02/15/2020 1022 LLL 02/12/2020 0908 44593 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 190000 310 120 mg/kg 1 Arsenic 7440-38-2 6010D 12 12 3.9 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.9 0.97 mg/kg 1 Calcium 7440-70-2 6010D 1100 J 3900 480 mg/kg 1 Chromium 7440-47-3 6010D 46 7.7 1.9 mg/kg 1 Copper 7440-50-8 6010D 480 7.7 3.5 mg/kg 1 Iron 7439-89-6 6010D 47000 77 35 mg/kg 1 Lead 7439-92-1 6010D 17 7.7 3.5 mg/kg 1 Magnesium 7439-95-4 6010D 2300 J 3900 480 mg/kg 1 Manganese 7439-96-5 6010D 1700 12 4.6 mg/kg 1 Molybdenum 7439-98-7 6010D 10 J 31 7.7 mg/kg 1 Nickel 7440-02-0 6010D 21 J 31 8.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 10 Client:Synagro Laboratory ID:VB11019-002 Description: Harnett WTP 1 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.10 02/11/2020 2239 Date Received:02/11/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 02/15/2020 1022 LLL 02/12/2020 0908 44593 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 1700 J 3900 480 mg/kg 1 Selenium 7782-49-2 6010D ND 15 6.3 mg/kg 1 Sodium 7440-23-5 6010D 880 J 3900 480 mg/kg 1 Zinc 7440-66-6 6010D 86 39 9.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 10 PACE ANALYTICAL SERVICES, LLC iew y G1?airr of efistody ROcarroR Ackfrt-ss '18�1 " al} Sbko 2g5Gad2 Almpxrilie ?Iq 2N2s PrsJ�l hie'ne 1'rowa rauma9r 5au s� Irl / Ce!Chpr,-.n IGml4ners br each svrrlrp mar be c Mt&, ti on" Irie) &r .R+Wg410Thu RrsurW;W—I� pp malppm I U RWILI %O-9F iFlJ :3elr4LIAu bieM..nL-- Shealy Envfronmerlltul SeMoes, Inc_ I W Ventage pow Drive Wiest Co.utnbia, RGu[I7 CaF0.11 u 2,fH e2 Cr TvfEph ,, ly4_ (6C-3) T91-9700 Fax N4_ (aO2) 7Fj-#` awuzredl!ii.�u� �� � C:nl �; tiAli.; _! iA- jPnnGeu rriauj +n4 rIOG I faA "a. f anw 45�td1 r E L T04-T 1 i1hp{ Onpim amc� 7.MY.D A 2P'..'§r`u2anrtk#xC}ff2fia . rL I 1.o 6 k9Thn n Ourrbar sI t5 fi Mabx 7CLP !C [1 # III r}Gre 5H FM L6'9' F9� P.ilrt bll GYd F '. end r �F CErr Tiiw & "I" ;ser F IUU RwW if �541 raa A1od1k1') barnCIeLhpDEe; OCraquraae�� 7r &Y!, Per Luca% pr+im <9 L&H Di:, .J ty Lgh NC-ryhQlioh 1. } img 1 i REL*iwtd �Y ^� 2 RSMNh d kr 5 --h,TU—eai ay+ NiObe: Ap S�rrlpYesare e� igGd for sfa Weeks trnir� Fnadit Trna arrangrrnents ark �+ueei�k H��d Id4nlirrz7�n II rj hkr.-Ham Fhmrr.3al9 I• •I PN%cr UiknK.wi .r 3 ail aC� Y ®r_ UMn k . Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 10 PACE ANALYTICAL SERVICES, LLC wYmaly Fn%,Wmmcilal 4crrvicm bn& %ic t nil Dxmn,er-tNtrnbw. MEO'11w-,14 Clrccrire f}aru EiV2016 Sample Receipt Checklist (SRC Ciicnt: Synexo C0,1-r lncqlresut hylrlste' 13WG ! cu)1122M Lr+t II: VB1101�; ears of wfCipt. E] 5E51 T_iLcni ❑ UPS ® FedF,s ❑ Ot41,ar C) Yes ON.1)1 11. W,, rr. mid nely seals 7 L'eL on the coolvfr ❑ Yes lIu 1 2.:CtiusLuJ} 5c813 w'c1'c )resent. tiwrm tll intact and unbroken? pH Strj G M. NA Chlorinz Strip I.U: NA Tested by- NA OAF,inel ferry.taLurc uprm neocipli Dc vcd (Qaraakx3) lempembue upon receipt %Solid Snap -Cup iD: 19-2313 1,8 11.8 aC NA --NA -C NA (NA or- NA 1NA_ -C Method, ❑T'emperattrrr, Rlank Z.AIrmiml-B15iilvs IR Gua ID: b TR Gun Col-unolt Factor: MMI'adafovo[arrC 0 Wdhe ❑ lee Pacl. s ❑ ()TY Ice ❑ NU-M CA Yes El t io ®AlA 3, If tcmperature of MY coaler actcasdad L,U"�;, �aa L'mject VLm3gerN'o- fkO PM was Not'-fied by: p wnc f email f fbCe to-fFa{e tc.rcle anc), Yes ❑ No U NA 4, is the rrymmr,.rrii:l rnuricr'u parking slip athadmd to this form? Yns ❑ No S, WtT,, prope' er svC y pmnederrs 1,Tu1fngLri 4fim11rmtivCLI) ful(uwed? Ty—. ❑ rNo b. VrFere sanple Ms listed an tho CUC' Yes ❑ No ?. ctxl sample: MEL lister) an all sample conraincrs'l ® Yes 0s -No it.- WH:� coilraalion du5c & tilde l isted on tlM ('0('? `f,: ' gg No 9. Was wilcoLicn date ak time l isted as al I aurnplt; ounlruoere ® Yew Cj No 14. I)id all wnt+�nrr Iabel inliarnkal103r (11), chic, um;.) agnx with fha COO? [Z! yes ❑Flo 1 :. Vle nb Lums to he perfbunud listed on the CO C? �'i e ❑ Iel 12. U_d all l 6arnplel: arriue in the pruper (Dmtahicls foi- r-wh test anClvr in goad -cone ilion (unbmkctl, lids or4 yesi No 11.3. Was adeyuuie swople v;,lunw mailable yes No 14. Were all sarqles deceived within !4 the holding time rar49 l,r)uvi. whicaarver Cucnes 1—s-1 'ar No 15, %Ycrc any samples cantuiurs misriexcess (circle cuus) sainpl"'Not IiFteri ml COC? ❑ Yes ❑ No IkA 16. Po- VOA and L{SFA- 5 sanlpics, w= bubb[ea pr sent ('%"or Gahm in diaitictcr) in any of dk VOA vial3? 0 Yea it o NA 17. Were fill DR. mersll$/ne-rrierit same Irs P-_LmivcJ ui a �,II Ui r 27 Ej Yus 0 Ku 0 NA 18- Were. all cyanide samples rrrrivrA nt a r.T-T ;- =2 rtnei sulfide saruplGs i��ciYed 81[ a > $? Yew � I� 41' Er�r-77J yy L`+1A19. rrc a app Icuk a NI I3?TKN?;yUrjiJeplrett:oUG 5 (C O.Sit;rg l,15an1P1�5 free ofTcxi dual ehiamncry ❑ C5 I—[ ❑ 14i NA121 20, we m e1if njlt T Mdicsheqursu (i.e_ -egllested di(udona, b�MSIMSD dcsigna#ions, et';_._j cC rc�ctly banrcnbed frem the COC; into the =nlcn! scCtion in I'JW � U 'cs NO - Was the crucite rualliBr lIsred on dw eonfainor labrl? 117ym, Quixc it NA hwnple Preservation (Mils; be ecmplcird for any samplu(s) incuTTeetty pretenved orwith lmdspaca,) 3mpie(s) NA -w= CpCWvcd inorwm[tly prcNcrmd uud w=ad.justod aocoidngly hi sa_uplo raaciving with ETA mT of circle ; ne: FTLS04, UND3, 11CL NIOE UkM 5lt # NA _ utx of presrrvariml N if rn7r than one LrrWSCn 8liVe is nccdod, pleaasc rrotC jn the oa1:7--1cr�ty Belo ti+. ulnplc(N,1 NA Wr.t-A rOroivaul With �uUllICK>6 mn in diameter, a�Twks(s) N --- -- -�- wuc. received avitlr TRC 5- 0-5 niy/L (11'419 is rro) and tsar~. djvslcdaccordinoyinsemlpiomccivingwillisndiumLhicwllllfln(Na,,58O3)wiIL910.3lyM, NA 5Tt barzode labels applk;d by: RMC, l7aac: 02r`11M2A commonts: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 10 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Nate Roth Project Name: Harnett Lot Number:VD23024 Date Completed:04/30/2020 MIM�� Mr� 04/30/2020 3:57 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VD23024 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids, sample -001 was weighed out 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VD23024-001 Description: Harnett WTP Cake Matrix: Solid Date Sampled:04/21/2020 1130 % Solids: 25.9 04/23/2020 2207 Date Received: 04/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 04/23/2020 2207 HET 51982 1 350.1 (Ammonia - N ) 350.1 1 04/28/2020 1526 SLC 52271 1 (Nitrate - N ) 9056A 1 04/26/2020 0129 HKL 52210 1 (Nitrite - N ) 9056A 1 04/26/2020 0129 HKL 52211 1 (Phosphorus) 365.1 10 04/28/2020 1639 DMA 04/28/2020 1146 52263 1 (Soil pH meas) 9045D 1 04/23/2020 1925 SRB 51981 1 351.4 (TKN) 351.2 1 04/29/2020 1508 DMA 04/29/2020 0934 52375 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 25.9 % 1 Ammonia - N (gas diffusion) 350.1 15 3.9 2.0 mg/kg 1 Nitrate - N (soluble) 9056A 3.4 1.9 0.095 mg/kg 1 Nitrite - N (soluble) 9056A 0.37 J 0.77 0.074 mg/kg 1 Phosphorus 7723-14-0 365.1 1600 190 39 mg/kg 1 Soil pH measured in water @ 18.3 ° C 9045D 5.3 su 1 TKN 351.2 7100 97 97 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 04/27/2020 2326 JMH 04/27/2020 0317 51971 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.31 0.074 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 04/27/2020 1957 LLL 04/25/2020 1414 51966 2 3050B 601OD 2 04/28/2020 0620 LLL 04/25/2020 1414 51966 3 3050B 6010D 10 04/28/2020 0631 LLL 04/25/2020 1414 51966 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 130000 260 96 mg/kg 3 Arsenic 7440-38-2 6010D 10 1.9 0.64 mg/kg 2 Cadmium 7440-43-9 6010D ND 0.64 0.16 mg/kg 2 Calcium 7440-70-2 6010D 610 320 40 mg/kg 1 Chromium 7440-47-3 6010D 32 0.64 0.16 mg/kg 1 Copper 7440-50-8 6010D 150 0.64 0.29 mg/kg 1 Iron 7439-89-6 6010D 35000 13 5.8 mg/kg 2 Lead 7439-92-1 6010D 13 6.4 2.9 mg/kg 3 Magnesium 7439-95-4 6010D 1400 320 40 mg/kg 1 Manganese 7439-96-5 6010D 700 0.96 0.38 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VD23024-001 Description: Harnett WTP Cake Matrix: Solid Date Sampled:04/21/2020 1130 % Solids: 25.9 04/23/2020 2207 Date Received:04/23/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/27/2020 1957 LLL 04/25/2020 1414 51966 2 3050B 601 OD 2 04/28/2020 0620 LLL 04/25/2020 1414 51966 3 3050B 601OD 10 04/28/2020 0631 LLL 04/25/2020 1414 51966 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Molybdenum 7439-98-7 6010D 7.3 2.6 0.64 mg/kg 1 Nickel 7440-02-0 6010D 16 5.1 1.3 mg/kg 2 Potassium 7440-09-7 6010D 810 320 40 mg/kg 1 Selenium 7782-49-2 6010D ND 2.6 1.0 mg/kg 2 Sodium 7440-23-5 6010D 60 J 320 40 mg/kg 1 Zinc 7440-66-6 6010D 62 3.2 0.80 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC L cu M 9 C d LIT -77 }} E~ 1r I r aq WO 004 rtw a.7 IQ pue rK 1e911� �u!g�l (uatag TJ'$ V 'J., k-W 7; Hdl I I l I I i 1 I "I IRiaH ' a:'usoj 4f1D.L Lail 513 �>�1•J+S f s .�dUICS ?C q 0_ 0 6 . 4! E gym' � 4 E V D Y s o � i] {! CL a L — L4 M •I CL i7. r t LL x . F w a S � v n 7 d0 �' 1 � � v k lYLF ^' b• i� .4 Q LL' F'� d t z ii W Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC SiVt Dwiro11111ewul 4urviwo, Ina EK%Um UNu;nLC_': MMWIz1 -,q rage 1 01 Sample Receipt Clieckliq (SMC) Eulfw 3'�r201� C:ie_3': `x)na�•ro Coo [or hs ecLed bvldate- line; ;' iW3.�Ot'r 1313024 Lor P, _ cans of rc-..eip#; ❑ SE I ❑ 01lent O UPS T"edEx ❑ Ulhc* [ Yes No _ 1 . eae aas[ady fe21S premr_r ooi th4 ao0W_ �'�: N NA12 Ifouspodv seals wwre scut, were the il> vteu� u�broketk? 13PI Snip [I): NA _ Ghlodne Strip W. NA Toted bye- NA original LcmE eratwr upon rE 0e:pt 1 Derit+ed (C ortvected) M31per4ture LLpm7 re: ri�j %S0lid Sna-j-Cxn 3I)- 19-2J 5-a i S,$ ' _- T NA 1`LNA T NA ?NA cC NA r1tiA QC -- elIKO_ ElTernperamre 61auk [OAgainst B,)u3m IR Gun II}_ 6 a {;an rwamxtion F�iaor a °C Metl7nal rsf 0003arit; ®IVU rce ❑ lee Eyck& ❑ Dry Ito 0 NcIno �] y3s ❑ NO 14Nq 3. JflcrnpersturcOfa�iy cUOltrexeee�lydG.0°C, 'vas Project klaiuz rtNotified? P.M wus Ntrdriad by: pliurle 1 email ? faCe-.tp-fucG (tira12 one). ' ❑ No ❑ T ,d 4, Is the coofy,r1crpaJ rDuriar's packing s[ip attachzd W [h[% Crirrl? Vern ❑ hJe 5. 14err r0 ercu�t0[ly pra[COLII S (rnkingU'she rrRel�t k FOUID r'ed? ® Yes [_70 6. %Vere sample IT)% risrad on '.I Lc C[)C? ® Ye_; ❑ Nol 7, Were.5ample IDS listed or, all sarnpiccantainers? Yes ❑ V0 J3, MIS kolJectyan date & Limo 'iatej an the CGC-r 9. Wm C0Iie0Li1J1-% KIPW & timG listed an al: saenplo contains rNO : `fcs Q NO 10. Did i11 cor.rairker IabeJ ir*Ymivriai (TD, dape, Limn) a�.r$G with 1-t COO? Yrm* ❑ Nu 11. Were tests to be pnRonned I_.ked an *-, COCF •— Yes ❑ No 12_ Did all sarrn*31-s arrivk in the prcwper con[a.incn t; r rash te_SL and/or in goad condition [unbrukc n, 'idm on, etc.)F _ Yer ❑NEr I3.LVasa13�equuIQsamplevolunieavuilable? Y �'es ❑ No 14_ Wm all samples .1ec)eived l iftn A the holding turn or 49 Eu,rn-', wh k&:_ er —comes firsr? 14n 15. rc n '.w l 71pIE5 oonlaimN mjs5l` _,a f-:—Je une) samples Clot ]istcd on CC)C. ❑ Ye6 ❑ No 21 NA 16. E'4r �'O 1 and R IC-] 75 samples, wwrE bubbles presenf >"p�Y."0r 6mni itr dia[neter) in any of the VOA vials? ❑ Yes No 1�A 17, VJer� rll C>RQ!nrcl�Js'nrttryGlLt szn� ice; rcc�ived ata II uI � 27 Yes ❑ Va f 7vA I8, Ware alr cya,liLk seonple.s -owiye j at a pil > E? and suiFdc sarr. JCS -,wefverl at a I = +9'T ❑ Y ❑ No N 14_ Were all �Ipp i�alxle _ H lCNfa} at�ideJktcnu r'b25 { 0.3*r�r, , sarnp:cs Lice aYYCsi L a[ ❑ Yesl ❑ _ t;hl�rine? O NA 20' WerE eliont urrimrksh+eq wp ,t5 {i,e_ ragaested C llt'ions, Jb4SYMSD a mjgnatiais,,-,w � eUTLTcdy trrnscrihnj r'rant the COC Entothe cartlmoDt mctiun in LIIW ? ?]. WOS [hc uote rumhe: Ji tEd on the ccllloincr label? Ifyes, Limtc # NA Pie Preservation (lust be comb Wad For any ya:npla(s} [moon-eerly pmwr cd o:- with heddspaCL) A-.f-.1 �''Er5 received in,onoutly pfeSrnvxl m1d 4hwc adjvsicd aocoydiEIgly En 0ruple receiving %[6 NA mL of oircle one: H C 4, Oga I ICi, 'JaDFI rsing 5R 4 NA Time of preycruation NA� If Mom than one PreserVUt[vc is rnmctied, pletSc note :r_ the C0krirncr.ts bel4wr_ 5alttp2c4s1 NA _wCTe receiwd with I AtAes >6 mm in dlRmeter_ San,pkcs(s} NA � W-O received with T[tC> 0_5 E VIL {ff 410 [s na) and ivul. acljuytcsd amotdin.9- do samlrla r aivi,�gwii� sodium thij)Mu[fatc•{1ra,S.0) with Shealy 1TJ; HA -01-00de IaLbcls applied by: 5MC - Gore en[s`. Date: 0412312020 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Chris Wynne Project Name: North Harnett WTP Lot Number:V130016 Date Completed:10/08/2020 NIM�� Mr� 10/09/2020 1:49 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: V130016 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids, the sample was weighed out at 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VI30016-001 Description: North Harnett WTP Matrix: Solid Date Sampled:09/29/2020 1300 % Solids: 24.8 10/01/2020 0128 Date Received:09/30/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 10/01/2020 0128 MOM 68450 1 350.1 (Ammonia - N ) 350.1 1 10/02/2020 1316 DRD 68540 1 (Nitrate - N ) 9056A 1 10/02/2020 1536 AMR 68670 2 (Nitrite - N ) 9056A 1 10/03/2020 0640 AMR 68728 1 (Phosphorus) 365.1 10 10/02/2020 1638 DMA 10/01/2020 1025 67605 1 (Soil pH meas) 9045D 1 10/01/2020 1456 AAB 68542 2 351.4 (TKN) 351.2 1 10/07/2020 1046 DMA 10/06/2020 1406 68936 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 24.8 % 1 Ammonia - N (gas diffusion) 350.1 4.0 4.0 2.1 mg/kg 1 Nitrate - N (soluble) 9056A 2.3 2.0 0.40 mg/kg 1 Nitrite - N (soluble) 9056A 0.44 J 0.81 0.40 mg/kg 2 Phosphorus 7723-14-0 365.1 2300 200 40 mg/kg 1 Soil pH measured in water @ 20.2 ° C 9045D 5.9 su 1 TKN 351.2 8600 100 100 mg/kg 2 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 10/05/2020 1220 JAB2 10/05/2020 0800 68617 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.32 0.077 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 10/05/2020 1949 KSH2 10/03/2020 1537 68645 2 3050B 601OD 10 10/07/2020 1714 KSH2 10/03/2020 1537 68645 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 150000 260 98 mg/kg 2 Arsenic 7440-38-2 6010D 17 0.98 0.33 mg/kg 1 Cadmium 7440-43-9 6010D ND 0.33 0.082 mg/kg 1 Calcium 7440-70-2 6010D 530 330 41 mg/kg 1 Chromium 7440-47-3 6010D 19 0.65 0.16 mg/kg 1 Copper 7440-50-8 6010D 120 0.65 0.29 mg/kg 1 Iron 7439-89-6 6010D 25000 65 30 mg/kg 2 Lead 7439-92-1 6010D 15 6.5 2.9 mg/kg 2 Magnesium 7439-95-4 6010D 860 J 3300 410 mg/kg 2 Manganese 7439-96-5 6010D 1000 9.8 3.9 mg/kg 2 Molybdenum 7439-98-7 6010D 18 2.6 0.65 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VI30016-001 Description: North Harnett WTP Matrix: Solid Date Sampled:09/29/2020 1300 % Solids: 24.8 10/01/2020 0128 Date Received:09/30/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 10/05/2020 1949 KSH2 10/03/2020 1537 68645 2 3050B 6010D 10 10/07/2020 1714 KSH2 10/03/2020 1537 68645 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 9.0 2.6 0.68 mg/kg 1 Potassium 7440-09-7 6010D 630 330 41 mg/kg 1 Selenium 7782-49-2 6010D 6.4 J 13 5.3 mg/kg 2 Sodium 7440-23-5 6010D 130 J 330 41 mg/kg 1 Zinc 7440-66-6 6010D 77 3.3 0.81 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC eli 4 i a { O L O I i3 ML a E 4 E I e9Rii WD70 --- a aS ' 133 0 bED ox E j-D Imo) IB3e_=l DN _ I- - .....-... W V I �` O �, 4'S I 2 UPP93*0 d'131 IIM=],+ ri U WOO � 2 F. L k t rz e i w ' O J m ^� q5 I p 4 G T _�3 j .+ � e�2 i ° s Ea IIYY F, � ' o F Li Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC Samples Keceil,t CherkFsr [SR{'} {MR018C.-15j Ax ylr 2i Issui!nG Authority_ Pare Eh V - WOOL Sample Receipt Cheddist (SRC') Uallt: ACAii`Ll CoL1:rr Itlapv;ml r fdax:ites ! I - % - X Lw; 1i; RFVlSPF=9!?gf71170 PegeicFI hirmins-ofro aipt= SEESI ❑ C.liert ❑ 1<PS aTedEx 0 Other; n yt*1 1. LVerc-uslady scars prirsca on thv caalcO Yes, ? . NOI l A 2- If cus seals acre -.i-e-gCnt„ were they incest and unbroken? p1; Strip ll}: r4A C:hIO dn� Istrip ID" -J cstcd'iy. - - � {Cl�riginal�� e�raEi i retpnco�rl De�ri{ed ['8rfrected tern��� upon lsiccipk %5ofid Sntlp-C,rp ID-. OV- I'-IW lfeth,Do ,,] Temperature S] nlc Jrpiinst accl_es Ili Guh Mr - -- 19 0wi Coff cctioa FmAur=. +'et:etlLj uC-4)01ar.E: VUL Ice i� lot P-,Ck.R ❑ ar •ice � None - - - Ye�To—I ❑ � NO: ti'�JA _3. if temperature of alty cooler exceeced G.U°C, war, Pnajec.K hU-r-a�r NL)fiFx ? PM was Notified by: phone f ettl ai t i fare -tin -:ace (.circle one). Yet Np 7 NA 4, Is the oanunercial courier's packing slip attached -�a 1his fffrm? 'ey ❑ No' ]. W fe proper cllsoody prozedum (relinquishcr.lnn rivied) rollowed? yCS No n. Were sample las listed on Ilia C:OU? I= ❑ Nu 7. Were Sain-3le lds listed on all sample cortainw? ZJ Cb ❑ l�to 8. Was c;,llwdon date & tme listed on tine HOC? YCs L o 9. Was eDiketion &c & time iistzc un all 5ampl0 Wrlt6n XS` O-Yes © No 10. Did ali ctintainer label infarmatim {ID, date-, ti-n*--) wilh the ( ;7 1 1- Vkrere test; to be perfDrmed Listed on the COO [ 'Yes ❑ No Ycy ❑ 12.. Did all ;nmpltA arrive in the proper contabers fbr ezch test andlor In pao& tnndidan {unbroken, lids on, cte.) f i 1'es ❑ No l3- Was adequate sample volume available? s No'4, )Were all sample.; received wh`kin `r the hotdin Ilrre cr A hours. whichever comes Ilrst? U Yes a :3- Wa.Fe any samplas contabiers missingleX0655 (circle OLe} samples Not listed on COC? Y 16. Por VOA and K. IK-17$ samples, wire huEil3lcxpaM�nL>"pva-sizes"{'./,"nrOnm in Jlarnct[r) in any of the VOA Vials? Yens U No LkNA J7. WM all DkO*oae [&'nntriea- sanlp'es reoeiv€d at a ply of ¢ 2 � La }` �s No [a -NA 18. Wefe all cyanide smrnpl:s rvLcivt!J aL a I!I-I l_' a:icl sLJfide Salllples received at a pH> 9? ❑ Yes Q '� aTe a npp ice e = cyani ePk- no , r U'3 k< D in +i j s rrlple oc o residual ch lori r c? 0 Y-s ©No L7 NA 20. W� re tlio)t remarl:slregLH!SU (Le- requeswd dilutions, 81IMSU clesig rtions, etc,..) cxFrrectly In uiscrbcd froul 6t! COC into the colu_nont section in LIMS? ll yes 219 'Nag the uat;: number :i5Led on tale container Iabe17 If yes, Quote R Sample Presrrvotlon (Must be completed for any sera pie(s) hlcf7eCsiy preserved or witl1 liead.space-) 5 tngle�(Sj vie-.t received hinormctiy prescrvcd our rc adjuved Utordingly iH sample recGit-in,, with raL oCckcle one: 1 i3S0.4, 11NQ3, 1-ICI, NPOF'. using $k a Time of presertration P, If ell ore Char- one presto-Vild W is mcdod.. pl mb= n ote ill the Comments bClm sample(E) trcre received with bubbles >6 mnl in d;xmeter- satnlx3es{5) wc= received wkt 'FRC:> U-S LngfL (If # 19 is Ate ) and -kvwm adjusted acmAing:y Jn sairl.pie recciy:ng wiihAsoditiM Mirsuli„OW kh':tzS30a) with Shealy lll: SR barcode labels appli-ni hy: KZ F?aLe: Iwuln.-amis; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Chris Wynne Project Name: Harnett Lot Number:VJ23014 Date Completed:11/02/2020 11/03/2020 3:08 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VJ23014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to the matrix and low percent solids, the initial sample amount used was 3X the standard procedure for the following sample: VJ23014-001. The LOQ has been adjusted accordingly. Nutrients The method blank for analytical batch 71002 contained total phosphorus greater than the method acceptance criteria. The continuing calibration blanks (CCB's) analyzed on the instrument did not show contamination. Due to the large dilutions associated with these samples on the instrument, any contamination from prep was diluted out and the sample results are not impacted. The data has been reported. The method blank for analytical batch 71626 contained the analyte ammonia greater than the acceptance criteria. The associated samples contained detections for this analyte at concentrations greater than 1 OX the value found in the method blank; therefore sample results are not impacted. The data has been reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VJ23014-001 Description: Harnett WTP Matrix: Solid Date Sampled:10/22/2020 1100 % Solids: 25.8 10/26/2020 2236 Date Received:10/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 10/26/2020 2236 MOM 71210 1 350.1 (Ammonia - N ) 350.1 1 10/29/2020 1511 DRD 71626 1 (Nitrate - N ) 9056A 1 10/29/2020 1756 AMR 71640 1 (Nitrite - N ) 9056A 1 10/30/2020 0923 AMR 71750 1 (Phosphorus) 365.1 25 10/27/2020 1653 DMA 10/26/2020 1224 70769 1 (Soil pH meas) 9045D 1 10/24/2020 1826 AAB 71058 1 351.4 (TKN) 351.2 2 10/30/2020 0949 DMA 10/29/2020 1059 71581 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 25.8 % 1 Ammonia - N (gas diffusion) 350.1 35 3.9 2.0 mg/kg 1 Nitrate - N (soluble) 9056A 4.6 1.9 0.39 mg/kg 1 Nitrite - N (soluble) 9056A 0.46 J 0.78 0.39 mg/kg 1 Phosphorus 7723-14-0 365.1 2100 480 97 mg/kg 1 Soil pH measured in water @ 20.6 o C 9045D 5.8 su 1 TKN 351.2 8900 190 190 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 5 11/02/20201212 JAB2 11/02/2020 1014 71918 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 1.4 0.34 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 10/29/2020 1353 KSH2 10/28/2020 1432 71297 2 3050B 601OD 10 10/29/2020 1731 KSH2 10/28/2020 1432 71297 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 601OD ND 24 9.0 mg/kg 1 Arsenic 7440-38-2 6010D 14 0.90 0.30 mg/kg 1 Cadmium 7440-43-9 6010D ND 0.30 0.076 mg/kg 1 Calcium 7440-70-2 6010D 820 300 38 mg/kg 1 Chromium 7440-47-3 6010D 22 0.60 0.15 mg/kg 1 Copper 7440-50-8 6010D 230 0.60 0.27 mg/kg 1 Iron 7439-89-6 6010D 22000 60 27 mg/kg 2 Lead 7439-92-1 6010D ND 0.60 0.27 mg/kg 1 Magnesium 7439-95-4 6010D 940 300 38 mg/kg 1 Manganese 7439-96-5 6010D 1800 9.0 3.6 mg/kg 2 Molybdenum 7439-98-7 6010D 14 2.4 0.60 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VJ23014-001 Description: Harnett WTP Matrix: Solid Date Sampled:10/22/2020 1100 % Solids: 25.8 10/26/2020 2236 Date Received:10/23/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 10/29/2020 1353 KSH2 10/28/2020 1432 71297 2 3050B 6010D 10 10/29/2020 1731 KSH2 10/28/2020 1432 71297 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 12 2.4 0.63 mg/kg 1 Potassium 7440-09-7 6010D 670 300 38 mg/kg 1 Selenium 7782-49-2 6010D ND 12 4.9 mg/kg 2 Sodium 7440-23-5 6010D 190 J 300 38 mg/kg 1 Zinc 7440-66-6 6010D 84 3.0 0.75 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC 0 L a s *tea A -2 111 1". 13 Q E! 0 0 0 001 fa "mmr3 full* 3.r') m z w r r 601:1 CP Eff LLon O f.3 u 1L ? eprmslkd dl.IN or ORA] 1 ;51 LLI 4D E:. co 1K U-4j r= F oil CL LZ z 2, 0 LZ C3 F L> 4p --Z sH :93 - YL U 73 -Z' 2 0 z Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803)791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC Samples ReceiprtChecklrst(SRC)(ME007SC-15) �E �I�1i1111lEIYl, 3f29f2020 � � H 155uirig Authority, Pace ENV- WOOL VJ23014 age Iof 1 aTilpiC Receipt ilEr� t client Coalor 17soeotcd bvidato; ! � Lot �❑ VIRV 4 of rece pr ace I 1C.1jent UPS Bllradzx Ocher _ CS YCR 4 N 9d, 1. WCFC cu5t4dy SCAB prcunt 41t tho roof i 13 custody sealp A-ae regent, were it7—y iniacr and i10L-Fulu ? _..--- _. .., pH grip IV: ChlvrinvStripID:...__......._ Testeylbv_ 4 r- — 7, Ori nal to pergp rre upon rCCCI / Dcrivvd (Corrcclod) tcmprcr=rc upon receipt 9G.Sfl1 iJ Sr a � •{ tp it )_ ' ' c7 � 4 ,( o NA IMA QC TIA INA MA 1NA cC ,leCtrugCFkrturl' 1i14 ElAgaillst kiottles ]]i Gun IIJ: IR Gun Cnlracrrorl Tactnr i °C' CGiod 4f coolant; L kYe:lce El Ice Packs El Pa Ice ❑ Nome ❑ Yos -(.qrs ©�lo DNo ENA 1*IA 3' If tInperaturc of any cooler exoee€led 6.0°C, wa-5 Proj- c4%M mf� x NWiflUd? FM was NoEifed by, plane f eniail 1 (oircic ujx). 4, b theoommercial c=ier:spackftsiip atmched 7othig fbrm? Yv DNO 5, Were proper custody procedures (relinquisl3tdfrarxiwed) f111frXca17 Rryes LJ No 6, WeTe sanaple ID3 listed of the COM ra ❑ No 17. Were sompk I1)s listed on all sample vantaincm? Yrs No 8. W;1-5 cvllccaon date & Sme listed on the COC? 'Yek LJ.qo 4. W uN crrlloudan Auto & dme Listed on al i sr, ]e ConMjr xS? cs Flo 10. Did all oc¢1Wncr label information (ID, dre, time) agree w ffh the COC? 217yar EINO l I. 14'ere LLMA to be Tlcrgnrrn r.d ) istrd on the. COC? L3Y L. ❑ Nv _ 12. I}id nl; 15unplcs arrive in the proper oontailners for each lest aed}.�r 41 pud wrA tiQu (unbroken, lids tsn, etc.)? Flo 13. Was adequate swnple volume available? Yes n 14- Reese all FAMVWPOCOvad wilt ii 'A- the Lioldin time Qr 48 hours, whichever mmcs first? Yee} a 9 15, �4 om any mm m corrtuinm Mis5in foxccss {circle ono) sampler, Not listed on C (X 9 [ Y,;s ❑Flo 1+1.4 16, Fur VOA land RSY-l75 samples, were 3ubblet pre-senL >`�ert�SizG" ('!zor 6mm in diameter) :u uny rrfthc VOA witlls? Yr.cc Yes n Flo LN . IT %Im-ft all DRO.Imetalsintltr[ent swn ks r> 6,md at ai pH of < 2? L29ALI I K. W we aff cyanide simples recei+,+ved at a pH > 12 rand sulfidr ss:npics recekved ar a pi 1 > 97 ❑ �'- ❑ o '- [!r I M a upa ca a hlia!']'KNlcyanidelpheuol{625.116 8 .� C mp -ee Lamp es q I Sldlk3� C11�U�'ISrG f yisLjN �01 [T _ Wtwc client n;markLr�nuests (i.e. requesre>d dilutions, MSlIt+1SD d:signadom, CSC...0 wnr.dly Lranvribrd ftum the COC• Irm the COt1712 eat SCC&m ill L1MS? Yes 21. l�'�s Ti7� otc lllunl]er listed an die %�or31ailler'auWl? If }ta rote Pj am plc FYeseripaiiian (Must be uusnpitAed fi,r Hny 4arf pWs) incorrectly preserved ar wilb head4pacc.) Samples) NA were ruwival Ln+xurectly preserved and were adjusted SocoMingly :n sample rewLvin-with NA mL of circle one= H2SO4, WKO3, M, NVOH using SH 5me a Omit matiori NA _.. If niore than or,e proWvWvc ie ncodA, pkoase note in the can=emis bolavr. Sample(g) NIL __ y vrem receivtad w16 bubbIrN - 66 Film in riia-ptifel-, arriples(s) MA were mmi%red with TRO > 0.5 mprL (lf f.1 I1 is vo) and were nisted arcordirlgly in sample receiving with (sodium tMosulfate (Na2SiO,) Mini Shealy ID- i R W�^ rGusie labels app]ied Icy: Date,- 10 Comments; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: HARNETT CO. UTILITIES, NC WQ PERMIT#: WQ001 4885 FIELD#: NC-HA-OOX43-0-0001- ACRES UTILIZED: 39.3 LAND OWNER: HARNETT COUNTY ANNUAL DRYTONS APPLIED: 463.12 SITE #,, NC HA 0OX43 ACRES PERMITTED: 39.3 OPERATOR: HARNETT COUNTY PREDOMINANT SOIL SERIES: LAKELAND CATION EXCHANGE CAPACITY (NON-603): CROP I NAME: BERMUDAGRASS, COMMON - CROP I MAX PAN: 147 CROP 2 NAME: CROP 2 MAX. PAN: wAVfPr1r)w1 RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond . Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24Hrs. Application 8 lization ization TKN Nitrogen and Nitrite (lbstacre) Application --Er-o-pl -Er-.-p -2 -7Er-.-pj Ma ' Month Amount UOM Solids Dry Tons/Ac Source MoistryL Inches Method* Rate- Rate*** mg/kg mglkg mg/kg Crop 11812020 � 0 130,200.00 (G) 100 6290 HCUCOHWPL SUR 0.5 0.20 �-9*8'00 -'00 9.800.00 99.00 28.00 1A71 BCOH 1/912020 179,800.00 (G) 2.100 0.401 HCUCOHWPL SUR 0.5 0.20 1 9,800.00 99.00 28.00 1.617 BCOH 1/1012020 130,200.00 (G) 2.100 0.290 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.171 SCOH 1/11/2020 210,800.001 (G) 2.100 0.470 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.895 BCOH 1/23/2020 6,200.001 (G) 2.100 0,014 HCUCOHWPL SUR gg 0.5 0.20 9,800.00 99.00 28.00 0.056 BCOH 1/24/2020 148,800.00J (G) 2.100 0.332 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1338 BCOH 1/27/2020 111,600.00 (G) 2.100 0,249 HCUCOHWPL SUR 0 9,800m 99.00 28.00 tl 1.003 BCOH 1/28/2020 136,400.00 (G) 2.100 0.304 iHCUCOHWPL SUR 0.5 --- 9,800.00 99.00 28.00 1.226 BCOH Jan-20 1,054,000.00 (G) 0/2020 148,800.00 (G) .100 0.3R IHCUCOHWPL'i SUR 0.5 7.+'800.00 020 99.00 28.00 1.338 BCOH 2112/2020 68,200.00 (G) 2.100 0.152 HCUCOHWPL: SUR 0.5 0.20 9,800.00 99.00 28.00 0.613 BCOH 212412020 i 124,000.00 (G) 2.100 0.276 HCUCOHWPL: SUR 0.5 0.20 9,800.00 99.00 28.00 1.115 BCOH 2127/2020 186,000.00 (G) 2.100 0.414 ii HCUCOHWPL" SUR 0.5 0.20 9,800.00 99.00 28.00 1.672 BCOH 2t2812020 167,400.00 (G) 2,100 0.373 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.505 BCOH Feb-20 694,400.00 (G) -(G) -HCUCOHWPL -SUR -39/202-0 -117,800.00 21-00 02-62 0-5 0.20 9,800.0-0 99.00 S 1.059 BCOH 3/1012020 124,000.00 (G) 2.100 0.276 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.115 BCOH 3111/2020 155,000.00 (G) 2.100 0.345 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 ¢ 28.00 1.394 BCOH 3/12/2020 99,200.00 (G) 2.100 0.221 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 0.892 BCOH 3/26/2020 130,200.00 (G) 2.100 0.290 HCUCOHWPL SUR 1 0.5 0.20 9,800.00 99.00 28.00 1.171 i BCOH Mar-20 626,200.001 (G) -T/2-/2020 --T3-072-0000 (G) 2.100 0.290 HCUCOHWPL SUR 0.5 0.20 0. 20: 9,800.00 99.00 2&00 1.171 H BCOH 4/3/2020 136,400.00 (G) 2.100 0.304 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.226 BCOH Apr-20 , 266,600.00 (G) --T -355 9/22f2020 161,200.00 (G) T 2.100 0.33-5 HCUCOHWPL SUR 0.5 0 0.20 9,800.00 99.66 28.66 1 �COH 9/23/2020 99,200.001 (G) 2100 0.206 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1 0.831 BCOH 9/24/2020 130,200.00 (G) 2.100 0.270 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1 1.090 BCOH 9/28/2020 192,200.00 (G) 2.100 0.399 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1 1.609 BCOH 9/30/2020 148,800.00 (G) 2.100 0.309 HCUCOHWPL SUR 0.5 020 9,800.00 99.00 28.00 1.246 BCOH Sep-20 731,600.00 (G) ANNUAL LAND APPLICATION FIELD SUMMARY FORM 10/1/2020 14880000� (G) 2.100 4 0.309 ) HCUCOHWPL ° SUR 0.5 020 9,80000 99.00 28.00 1246 BCOH 10/212020 $ 13020000 (G) i, 2100 0.270 HCUCOHWPL i SUR 0.5 0.20 9,80000 4 99.00 28.00 1.090 BCOH 101512020 14260000 (G) 2100 0.296 � HCUCOHWPL ° SUR 0.5 0.20 ! 9,80000 99.00 28.00 1.194 BCOH 10/612020 142600001 (G) 2.100 0.296 i HCUCOHWPL SUR 0.5 � 0.20 € t 9,800.00 99.00 28.00 1,194 f BCOH 1017/2020 14880000 (G) 2.100 0.309 HCUCOHWPL s SUR 0.5 0.20 9,800.00 r 99.00 28.00 1.246 BCOH 10/8/2020 11160000j (G) 2.100 y 0.232 HCUCOHWPL SUR I 0.5 I 0.20 9,800.00 i 99.00 28.00 0.935 j BCOH 10113/2020 186,000.00 (G) } 2.100 0.386 HCUCOHWPL SUR 0.5 0.20 ) t@ 9,800.00 99.00 28A0 1.558 ; BCOH 10/1412020 ? 111,600.00 (G) 2.100 0.232 r HCUCOHWPL I SUR 0.5 I 0.20 ( 9,800.00 99.00 28.00 0.935 ? SCOH 10/1512020 204,600.00V (G) 2A00 0.425 � HCUCOHWP0 SUR 0.5 y' 0.20 9,800.00 99.00 28.00 1.713 ? BCOH 10/19/2020 155,000.00 (G) 2.100 0.322 HCUCOHWPL SUR 0.5 020 9,800.00 99.00 28.00 1298 BCOH 10/20/2020 93,000.00 (G) 2.100 0.193 HCUCOHWPL SUR 0.5 0.20 1 9,800.00 99.00 s 28.00 0.779 BCOH 10/21/2020 142,600.00) (G) 2.100 P 0.296 F HCUCOHWPL } SUR i 0.5 0.20 9,800.00 99.00 r 28.00 1.194 BCOH 10/22/2020 148,800.00 (G) 2,100 0.309 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 1.246 BCOH 10123/2020 49,600.00 (G) 2.100 0.103 HCUCOHWPL SUR 0.5 0.20 9,800.00 99.00 28.00 0.415 i SCOH Oct-20 � 1,915,800.00 {G} Total 11.382 Total 45.917 0.000 Page: 1 HCUCOHWPL = HARNETT CO. UTIL., NC COH REGIONAL WTP LIQUID 'Z certify, under penalty of law, that this ocument was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penal[ r b g Is infomtation including the possibility of fines and impr sonment f kno g violations." 1© Zo Z IG TURE OF LAND APPLIER ATE NR = Not Reported or Not uired *" Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/712021 DENR FORM FSF (12/2006) SECTION 4 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Melinda Boyd Project Name: Harnett County WTP Lot Number:VB11019 Date Completed:02/21/2020 NIM�� Mr� 02/24/2020 4:19 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 10 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VB11019 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low % solids, the initial mas for sample -001 was 3 times the standard procedure amount. The LOQ has been adjusted accordingly. Paint Filter Sample -001 has been qualified with an "H", however, there is not a method defined hold time for this parameter. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 02/11/2020 2239 MDD 44610 1 (Ignitability) 1010A 1 02/17/2020 1302 SLC 45230 1 (Paint Filter) 9095B 1 02/20/2020 0855 SLC 1 (Reactive Cya) 7.3.3 1 02/17/2020 1716 MSG 02/13/2020 1106 1 (Reactive Sul) 7.3.4 1 02/17/2020 1623 HET 02/13/2020 1106 1 (Soil pH meas) 9045D 1 02/13/2020 2010 SRB 44964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.72 % 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Paint Filter Test 9095B Fail H* pass/fail 1 Reactive Cyanide 7.3.3 ND 50 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 50 mg/kg 1 Soil pH measured in water @ 19.9 o C 9045D 5.3 su 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 02/19/2020 1130 TML 45473 02/17/2020 2010 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D 0.0090 J 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 107 70-130 Toluene-d8 103 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 02/17/2020 1258 JCG 02/13/2020 1404 44836 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3of10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 02/17/2020 1258 JCG 02/13/2020 1404 44836 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 74 37-129 2-Fluorophenol 59 24-127 Nitrobenzene-d5 69 38-127 Phenol-d5 73 28-128 Terphenyl-d14 109 10-148 2,4,6-Tribromophenol 79 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 02/19/2020 1456 DAL1 02/16/2020 2002 45138 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 80 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 02/17/2020 1155 DAL1 02/13/2020 1404 44834 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 10 Client:Synagro Laboratory ID:VB11019-001 Description: Harnett WTP 2020 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.72 02/11/2020 2239 Date Received: 02/11/2020 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081B 1 02/17/2020 1155 DAL1 02/13/2020 1404 44834 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 35 20-131 Tetrachloro-m-xylene 83 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 02/14/2020 1240 LLL 02/13/2020 0004 44776 02/11/2020 1949 1 1311/7470A 7470A 1 02/17/2020 1640 JMH 02/17/2020 1024 44810 02/11/2020 1949 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.043 J 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 Footnote(s): 'Paint Filter: 97mL collected; LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 10 Client:Synagro Laboratory ID:VB11019-002 Description: Harnett WTP 1 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.10 02/11/2020 2239 Date Received: 02/11/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 02/11/2020 2239 MDD 44610 1 350.1 (Ammonia - N ) 350.1 1 02/19/2020 1252 SLC 45301 1 (Nitrate - N ) 9056A 1 02/15/2020 1840 HKL 45243 1 (Nitrite - N ) 9056A 1 02/15/2020 1840 HKL 45244 1 (Phosphorus) 365.1 2 02/14/2020 1442 DMA 02/14/2020 1008 44986 1 (Soil pH meas) 9045D 1 02/11/2020 2105 SRB 44620 1 351.4 (TKN) 351.2 1 02/21/2020 1315 DMA 02/19/2020 0951 45417 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.10 % 1 Ammonia - N (gas diffusion) 350.1 99 48 25 mg/kg 1 Nitrate - N (soluble) 9056A 28 24 1.2 mg/kg 1 Nitrite - N (soluble) 9056A ND 9.5 0.92 mg/kg 1 Phosphorus 7723-14-0 365.1 2600 480 95 mg/kg 1 Soil pH measured in water @ 21.3 ° C 9045D 5.4 su 1 TKN 351.2 9800 1200 1200 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 02/15/2020 1030 KSH2 02/14/2020 1327 45001 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.5 0.84 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 02/15/2020 1022 LLL 02/12/2020 0908 44593 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 190000 310 120 mg/kg 1 Arsenic 7440-38-2 6010D 12 12 3.9 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.9 0.97 mg/kg 1 Calcium 7440-70-2 6010D 1100 J 3900 480 mg/kg 1 Chromium 7440-47-3 6010D 46 7.7 1.9 mg/kg 1 Copper 7440-50-8 6010D 480 7.7 3.5 mg/kg 1 Iron 7439-89-6 6010D 47000 77 35 mg/kg 1 Lead 7439-92-1 6010D 17 7.7 3.5 mg/kg 1 Magnesium 7439-95-4 6010D 2300 J 3900 480 mg/kg 1 Manganese 7439-96-5 6010D 1700 12 4.6 mg/kg 1 Molybdenum 7439-98-7 6010D 10 J 31 7.7 mg/kg 1 Nickel 7440-02-0 6010D 21 J 31 8.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 10 Client:Synagro Laboratory ID:VB11019-002 Description: Harnett WTP 1 Matrix: Solid Date Sampled:02/05/2020 1630 % Solids: 2.10 02/11/2020 2239 Date Received:02/11/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 02/15/2020 1022 LLL 02/12/2020 0908 44593 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 1700 J 3900 480 mg/kg 1 Selenium 7782-49-2 6010D ND 15 6.3 mg/kg 1 Sodium 7440-23-5 6010D 880 J 3900 480 mg/kg 1 Zinc 7440-66-6 6010D 86 39 9.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 10 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 10 PACE ANALYTICAL SERVICES, LLC iew y G1?airr of efistody ROcarroR Ackfrt-ss '18�1 " al} Sbko 2g5Gad2 Almpxrilie ?Iq 2N2s PrsJ�l hie'ne 1'rowa rauma9r 5au s� Irl / Ce!Chpr,-.n IGml4ners br each svrrlrp mar be c Mt&, ti on" Irie) &r .R+Wg410Thu RrsurW;W—I� pp malppm I U RWILI %O-9F iFlJ :3elr4LIAu bieM..nL-- Shealy Envfronmerlltul SeMoes, Inc_ I W Ventage pow Drive Wiest Co.utnbia, RGu[I7 CaF0.11 u 2,fH e2 Cr TvfEph ,, ly4_ (6C-3) T91-9700 Fax N4_ (aO2) 7Fj-#` awuzredl!ii.�u� �� � C:nl �; tiAli.; _! iA- jPnnGeu rriauj +n4 rIOG I faA "a. f anw 45�td1 r E L 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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 10 PACE ANALYTICAL SERVICES, LLC wYmaly Fn%,Wmmcilal 4crrvicm bn& %ic t nil Dxmn,er-tNtrnbw. MEO'11w-,14 Clrccrire f}aru EiV2016 Sample Receipt Checklist (SRC Ciicnt: Synexo C0,1-r lncqlresut hylrlste' 13WG ! cu)1122M Lr+t II: VB1101�; ears of wfCipt. E] 5E51 T_iLcni ❑ UPS ® FedF,s ❑ Ot41,ar C) Yes ON.1)1 11. W,, rr. mid nely seals 7 L'eL on the coolvfr ❑ Yes lIu 1 2.:CtiusLuJ} 5c813 w'c1'c )resent. tiwrm tll intact and unbroken? pH Strj G M. NA Chlorinz Strip I.U: NA Tested by- NA OAF,inel ferry.taLurc uprm neocipli Dc vcd (Qaraakx3) lempembue upon receipt %Solid Snap -Cup iD: 19-2313 1,8 11.8 aC NA --NA -C NA (NA or- NA 1NA_ -C Method, ❑T'emperattrrr, Rlank Z.AIrmiml-B15iilvs IR Gua ID: b TR Gun Col-unolt Factor: MMI'adafovo[arrC 0 Wdhe ❑ lee Pacl. s ❑ ()TY Ice ❑ NU-M CA Yes El t io ®AlA 3, If tcmperature of MY coaler actcasdad L,U"�;, �aa L'mject VLm3gerN'o- fkO PM was Not'-fied by: p wnc f email f fbCe to-fFa{e tc.rcle anc), Yes ❑ No U NA 4, is the rrymmr,.rrii:l rnuricr'u parking slip athadmd to this form? Yns ❑ No S, WtT,, prope' er svC y pmnederrs 1,Tu1fngLri 4fim11rmtivCLI) ful(uwed? Ty—. ❑ rNo b. VrFere sanple Ms listed an tho CUC' Yes ❑ No ?. ctxl sample: MEL lister) an all sample conraincrs'l ® Yes 0s -No it.- WH:� coilraalion du5c & tilde l isted on tlM ('0('? `f,: ' gg No 9. Was wilcoLicn date ak time l isted as al I aurnplt; ounlruoere ® Yew Cj No 14. I)id all wnt+�nrr Iabel inliarnkal103r (11), chic, um;.) agnx with fha COO? [Z! yes ❑Flo 1 :. Vle nb Lums to he perfbunud listed on the CO C? �'i e ❑ Iel 12. U_d all l 6arnplel: arriue in the pruper (Dmtahicls foi- r-wh test anClvr in goad -cone ilion (unbmkctl, lids or4 yesi No 11.3. Was adeyuuie swople v;,lunw mailable yes No 14. Were all sarqles deceived within !4 the holding time rar49 l,r)uvi. whicaarver Cucnes 1—s-1 'ar No 15, %Ycrc any samples cantuiurs misriexcess (circle cuus) sainpl"'Not IiFteri ml COC? ❑ Yes ❑ No IkA 16. Po- VOA and L{SFA- 5 sanlpics, w= bubb[ea pr sent ('%"or Gahm in diaitictcr) in any of dk VOA vial3? 0 Yea it o NA 17. Were fill DR. mersll$/ne-rrierit same Irs P-_LmivcJ ui a �,II Ui r 27 Ej Yus 0 Ku 0 NA 18- Were. all cyanide samples rrrrivrA nt a r.T-T ;- =2 rtnei sulfide saruplGs i��ciYed 81[ a > $? Yew � I� 41' Er�r-77J yy L`+1A19. rrc a app Icuk a NI I3?TKN?;yUrjiJeplrett:oUG 5 (C O.Sit;rg l,15an1P1�5 free ofTcxi dual ehiamncry ❑ C5 I—[ ❑ 14i NA121 20, we m e1if njlt T Mdicsheqursu (i.e_ -egllested di(udona, b�MSIMSD dcsigna#ions, et';_._j cC rc�ctly banrcnbed frem the COC; into the =nlcn! scCtion in I'JW � U 'cs NO - Was the crucite rualliBr lIsred on dw eonfainor labrl? 117ym, Quixc it NA hwnple Preservation (Mils; be ecmplcird for any samplu(s) incuTTeetty pretenved orwith lmdspaca,) 3mpie(s) NA -w= CpCWvcd inorwm[tly prcNcrmd uud w=ad.justod aocoidngly hi sa_uplo raaciving with ETA mT of circle ; ne: FTLS04, UND3, 11CL NIOE UkM 5lt # NA _ utx of presrrvariml N if rn7r than one LrrWSCn 8liVe is nccdod, pleaasc rrotC jn the oa1:7--1cr�ty Belo ti+. ulnplc(N,1 NA Wr.t-A rOroivaul With �uUllICK>6 mn in diameter, a�Twks(s) N --- -- -�- wuc. received avitlr TRC 5- 0-5 niy/L (11'419 is rro) and tsar~. djvslcdaccordinoyinsemlpiomccivingwillisndiumLhicwllllfln(Na,,58O3)wiIL910.3lyM, NA 5Tt barzode labels applk;d by: RMC, l7aac: 02r`11M2A commonts: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 10 of 10