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HomeMy WebLinkAboutWI0800546_Permit (Issuance)_20210224CES Ni February 9, 2021 C Michael Rogers DWR — UIC Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 RE: CES of NC, PLLC 5104 Reagan Drive, Suite 7 Charlotte, North Carolina 28206 980.819.9333 [office] 540.343.6259 [facsimile] -.,ECE$VED— FEB 11 '2021 NC DEQ/DWR Central Office Notification of Intent to Operate Injection Wells GPM 3181 (Scotchman #3181) 5200 Carolina Beach Road Wilmington, New Hanover County, North Carolina NCDEQ UST Incident No.: 22460 Dear Mr. Rogers: On behalf of the responsible party/applicant GPM Southeast, LLC, CES of NC, PLLC is submitting the enclosed Notification of Intent to Operate Injection Wells. The document details "deemed permitted" passive injection activities utilizing existing monitoring wells for the purpose of groundwater remediation associated with the referenced incident number. Following review should you have any questions or require additional information, please do not hesitate to contact me by phone at (980) 819-9333 or email at astreams@crawfordenvironmental. Sincerely, CES of NC, PLLC Allison Streams Project Manager Enclosure CES@NM February 9, 2021 Michael Rogers DWR — UIC Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 RE: Notification of Intent to Operate Injection Wells GPM 3181 (Scotchman #3181) 5200 Carolina Beach Road Wilmington, New Hanover County, North Carolina NCDEQ UST Incident No.: 22460 Dear Mr. Rogers: CES of NC, PLLC 5104 Reagan Drive, Suite 7 Charlotte, North Carolina 28206 980.819.9333 [office] 540.343.6259 [facsimile] On behalf of the responsible party/applicant GPM Southeast, LLC, CES of NC, PLLC is submitting the enclosed Notification of Intent to Operate Injection Wells. The document details "deemed permitted" passive injection activities utilizing existing monitoring wells for the purpose of groundwater remediation associated with the referenced incident number. Following review should you have any questions or require additional information, please do not hesitate to contact me by phone at (980) 819-9333 or email at astreams@crawfordenvironmental. Sincerely, CES of NC, PLLC Allison Streams Project Manager Enclosure NC Department of Environmental Quality — Division of Water Resources (DWR) NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are `permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS (15A NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells is located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. 5) In -Situ Thermal Wells (IST) — Used to `heat' contaminated groundwater to enhance remediation. DATE: 2/9 Print Clearly or Type Information. Illegible Submittals Will Be Returned as Incomplete. , 2021 PERMIT NO. W I0800546 (to be filled in by DWR) NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g., different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the previously assigned permit tracking number and any needed relevant information to assess and approve injection: A. B. Permit No. WI Issued Date: WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well Complete sections B through F, J, M (2) Aquifer Test Well Complete sections B through F, J, M (3) X Passive Injection System .. Complete sections B through F, H-M (4) Small -Scale Injection Operation Complete sections B through M (5) Pilot Test Complete sections B through M (6) Tracer Injection Well Complete sections B through M (7) In -Situ Thermal (IST) Well Complete sections B through M STATUS OF WELL OWNER: Business/Organization Deemed Permitted GW Remediation NOI Rev. 2-17-2020 Page 1 C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): GPM Southeast, LLC — Rolfe Lann, VP of Environmental Mailing Address: 8565 Magellan Parkway, Suite 400 City: Richmond State: VA Zip Code: 23227 County: Richmond Day Tele No.: (804) 730-1568 Ce11 No.: EMAIL Address:rlann@gpminvestments.com Fax No.: (804) 417-1041 D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: Kyle Campbell VP, SR Legal Council, Risk Mgr. Company Name:RILP NC2 LP Mailing Address: 11995 El Camino Real City: San Diego State: _CA Day Tele No.: N/A EMAIL Address: N/A Zip Code: 92130 County: San Diego Ce11 No.: N/A Fax No.: N/A E. PROJECT CONTACT (Typically Environmental Consulting/Engineering Firm) Name and Title: Allison Streams, Project Manager F. Company Name Mailing Address: CES of NC, PLLC 5104 Reagan Drive, Suite 7 City: Charlotte Day Tele No.: (980) 819-9333 EMAIL Address: astreams@crawfordenvironmental.com PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: Scotchman 3181 (GPM 3181) State: NC 5302 Carolina Beach Road Zip Code: 28206 County: Mecklenburg Cell No.: Fax No.: (540) 343-6529 City: Wilmington County: New Hanover Zip Code: 28403 (2) Geographic Coordinates: Latitude**: 34 ° 8 ' 32.98 " or 34°.140448 N Longitude**: 77 ° 53 ' 46.71 " or 77°.892780 W Reference Datum: WGS84 Accuracy:2 meters Method of Collection: Google Earth **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: square feet Land surface area of inj. well network: square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: (must be < 5% of plume for pilot test injections) Deemed Permitted GW Remediation NOI Rev. 2-17-2020 Page 2 H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE — Provide a brief narrative regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity: Application of passive injection groundwater remediation cylinder socks within three monitoring wells (MW- 12, MW-13, and RW-1) impacted with petroleum hydrocarbons from UST system leak. Socks will be deployed as a source and barrier application to prevent further plume migration and assist with remediation of groundwater to below 2L Standards. J. WELL CONSTRUCTION DATA (1) No. of injection wells: Proposed 3 Existing (provide NC Well Construction Record (GW-1) for each well) (2) Appx. injection depths (BLS): 13' (3) For Proposed wells or Existing wells not having GW-1s, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number K. INJECTION SUMMARY NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http ://deq.nc. gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHSprior to use. Contact the UIC Program for more info if you wish to get approval for a different additive. However, please note it may take 3 months or longer. If no injectants are to be used use N/A. Injectant: Carus RemOx SR+ Na2S2O8 Total Amt. to be injected (gal)/event:1.5 Injectant: Carus RemOx SR+ KMnO4 Total Amt. to be injected (gal)/event:1.5 Injectant: Injectant: Deemed Permitted GW Remediation NOI Rev. 2-17-2020 Total Amt. to be injected (gal)/event: Total Amt. to be injected (gal)/event: Page 3 Injectant: Total Amt. to be injected (gal)/event: Total Amt. to be injected (gal/event): 3.0 No. of separate injection events:1 Total Amt. to be injected (gal): 3.00 Source of Water (if applicable): N/A L. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. Baseline groundwater monitoring has been performed prior to injectant deployment. Subsequent monitoring events are proposed on a semi-annual basis concurrent with injectant cylinder removal/replacement. Groundwater samples will be submitted for laboratory analysis of the NCDEQ UST section required list of target analytes of volatile organic compounds by Standard Methods 6200B. See NCDEQ UST Incident Number22460. M. SIGNATURE OF APPLICANT AND PROPERTY OWNER ApprQ,redAsTQForm tosolDeportneAl i i hi[GI�laa Well Owner/Applicant: "7 hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the 15A NCAC 02C 0200 Rules." / 9 Lt Rolfe Lann VP of Environmental ignature of Applicant Print or Type Full Name and Title Property Owner (if the property is not owned by the Well Owner/Applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200)." "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. Kyle Campbell, VP, SR. Legal Counsel, Risk Mgr. Signature* of Property Owner (if different from applicant) Print or Type Full Name and Title *An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form. Please send 1 (one) hard color copy of this NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 707-9000 Deemed Permitted GW Remediation NOI Rev. 2-17-2020 Page 4 2631 - 3181 (NC) NOI Signature Page Final Audit Report 2021-02-02 Created: 2021-02-02 By: Matt McClellan (mmcclellan@realtyincome.com) Status: Signed Transaction ID: CBJCHBCAABAAEKPP8EgDga43g_AXKhoCtjsnQgieciQO "2631 - 3181 (NC) NOI Signature Page" History t Document created by Matt McClellan (mmcclellan@realtyincome.com) 2021-02-02 - 9:08:44 PM GMT- IP address: 162.250.160.202 Document emailed to Kyle Campbell (kcampbell@realtyincome.com) for signature 2021-02-02 - 9:10:14 PM GMT 5 Email viewed by Kyle Campbell (kcampbell@realtyincome.com) 2021-02-02 - 10:02:36 PM GMT- IP address: 104.143.198.130 Document e-signed by Kyle Campbell (kcampbell@realtyincome.com) Signature Date: 2021-02-02 - 10:05:47 PM GMT - Time Source: server- IP address: 70.181.210.104 Agreement completed. 2021-02-02 - 10:05:47 PM GMT j Adobe Sign LEDGEj10 ONIR NEW REAR SET • E I R EXISTING IRON FOUND CI CONCRETE MONUMENT , M GONGIETE CONThcL KMNENT SET a TELEPHONE PAD ® ELECTRICAL PAD ---Q-- UTILIN POLE —W-- FENCE (type noted) E — OVERHEAD ELECTRICAL LINES a CATCH BASIN MONITORING WELL Gi TELESCOPING WELL • UST CAP WATER METER/VALVE PROPANE TANK - Soil Boring Location Notes: 1) Soil samples were also collected from the boreholes of monitoring wells SMMW-5, SMMW-6, and SMMW-8. RESIDENTIAL r9N NAIL IN PP 100. 00 ASSUMED US HWY 421 esio, .sB-s 3 eNN I11D f �rELE Pen SCALE 1"=50' SHOPPING CENTER E �_ s-2! ®sMMW-5 3) sB-, t1N 12 MN 13 O straw 1 i • + •SMMW-7 ASB--- �-SB- ®SMMWB OSMMW-8 OPW 9 j { I SB-6 GRASS 4, Sit& 2 SMM1 E E _ 0 alb,A wweowwetklet e. DEC. 14, 2001 REVISED JAN. 12. 2002 0 25 50 100 Delta Environmental Consultants, Inc. 3205 Randall Parkway Suite 104 Wilmington, North Carolina 28403 PROJECT NO. XONC-026 PROJECT MANAGER S.LATZ DATE 4/5/02 FIGURE 5 CLIENT/LOCATION Worsley Companies, Inc. Scotchman #181 Wilmington, North Carolina DRAWING DESCRIPTION Soil Boring Location Map TABLE 4 SUMMARY OF ANALYTICAL RESULTS FOR SOIL - COMPREHENSIVE SITE ASSESSMENT SCOTCHMAN 8181 WILMINGTON, NORTH CAROLINA DELTA PROJECT NO. XONC-026 Benzene Toluene Ethylbenzene Total Xylenes 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene MTBE 0.0054 0.020 0.010 0.054 0.0057 0.025 0.016 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.010 <0.005 <0.010 0.0056 7 0.24 5 7 8 0.92 NOTES: •Analytical results presented in mg/kg. •All values exceeding MSCCs are in bold type. 1) MSCC denotes maximum soil contaminant concentrations. PROPERTY 177/ � / GRASS/BRUSH Legend SMMW-1 a Monitoring Well (Type II) SMDW-1 ® Monitoring Well (Type III) co' Utility/Power Pole v Sanitary/Storm Sewer Manhole — OHE— Overhead Electric Line — OHC- Overhead Communication Line — OHT— Overhead Traffic Control Stormwater Ditch Benzene Concentration Contour Line Benzene Concentration in ug/L (4/29/2020) Free Product Not Sampled (3.3) (FP) (NS) CON RUOL BOXH MW-15 (<0.50) 77 //It S\• 0 7 O�MW-3 // (NS) (<0.50) MW-1 1 D Z MW-1 1 e ASPHALT (<0.50) _o Airs KEROSENE DISPEN Benzene 2L Standard: 1 ug/L CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 4 GPM 3181 Benzene Concentration (04/29/2020) Extent Exceeding 2L Standards Groundwater Monitoring Report SMMW-8 (NS) CON/ ( BMW-1Q NS) �\ \ (3\\STE — 3 \ \e e osmm / MW-9 \(<0.51 (NS) \ M ReT( ��,25)� \(43) / vS't—1SMNS)5 \, • (NS) SMMW-6 (NS) SMMW-4 ASPHALT (NS) Project Manager: DJF Drawn By: RAR Checked By: GRASS 0 20' 40' SMMW-1 (NS) SMMW-2 (NS) 80' 1 inch equals 40 feet CES N Ca 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) GRAVEL Project No: 9.0610 Date: 6/18/20 Revision: 0 PROPERTY uNE\, / ff / • GRASS/BRUSH (NS) MW-2 usr VENT PIPE KEROSENE DISPEN Legend SMMW-1 a Monitoring Well (Type II) SMDW-1 ® Monitoring Well (Type III) co' Utility/Power Pole Sanitary/Storm Sewer Manhole — OHE— Overhead Electric Line — OHC- Overhead Communication Line — OHT— Overhead Traffic Control — — Stormwater Ditch Toluene Concentration Contour Line (7,000) Toluene Concentration in ug/L (4/29/2020) (FP) Free Product (Ns) Not Sampled 600 Toluene 2L Standard: 600 ug/L CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 5 GPM 3181 Toluene Concentration (04/29/2020) Extent Exceeding 2L Standards Groundwater Monitoring Report • ox / o<\. ?sue\o `y 9�y 7 \ STORMWAIER INLET /� X� Oki 0 Nk coNtROL BO 1)09 COMMUNICATION BOXN `• ��.� 2) _, 41110 MW-15 e (<0.50) 7 SMMW 9 It.\ (NS) /7 PIPES •R/VAO /0*e MW-3 77 (NS) (<0.50) MW-1 1 D: 0/MW-11� Usr BASIN\ \ ASPNALr (<0.50) (NS) d /• /��J MW-14\ S MPS '\ \a, SMMW-8 r / • \ GRASS CONTTE (NS) / BMW —1 �(NS)\ 1.1) \ EN 600 • „Iv10-3 Project Manager: DJF Drawn By: RAR Checked By: \e e osk4MW— MW-9 N(<0.50 (NS) MW-10 y(NS) OHC GRASS 0 20' "R — (00)\ (7,0 ® SMMW-5\ u SMDW 1 (NS) (NS) SMMW-6 (NS) 40' ASPHALT SMMW-1 (NS) SMMW-4 (NS) � SMMW-2 (NS) OHC- 80' mm 1 1 inch equals 40 feet CES NCa 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) GRAVEL Project No: 9.0610 Date: 6/18/20 Revision: 0 CONTROL BOX M (<0.50) 77 SMMW 9 \ • \ (NS) RiREs Ac '. MW-10 /' 0 (NS) �� MW-3 (NS) (<0.50) / MW-11D� Off\ / / MW-11� usrBAVN\ ASPHALT (0.45 J) (NS) cw�ss Aodrs /�^J A e 14\ / �'� KEROSENE S MGS/ �\ \ \ DISPEN.� SMMW-8 �/ \ \ GRASS / coNC. NS MW— / ( ) CONTTE (1 0� 600 (NS) usr ` / \ 0 • . SERS \ \ —3 \ \ M (NS) \ /ii5 $SMMW 7 MW-2 UST VENT • \ MW-9 (16) PIPE ^\/ (NS) R —T(1 400) GRASS/BRUSH Legend SMMW-1 a Monitoring Well (Type II) SMDW-1 ® Monitoring Well (Type III) co' Utility/Power Pole v Sanitary/Storm Sewer Manhole — OHE— Overhead Electric Line — OHC- Overhead Communication Line — OHT— Overhead Traffic Control Stormwater Ditch Ethylbenzene Concentration Contour Line Ethyl benzene Concentration in ug/L (4/29/2020) Free Product Not Sampled 600 (2,400) (FP) (NS) Ethylbenzene 2L Standard: 600 ug/L CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 6 GPM 3181 Ethylbenzene Concentration (04/29/2020) Extent Exceeding 2L Standards Groundwater Monitoring Report \ M \ VA (2,40r MMW-5 v SMD^— (NS) O (NS) \ SMMW-6 (NS) SMMW-4 ASPHALT (NS) Project Manager: DJF Drawn By: RAR Checked By: GRASS 0 20' 40' SMMW-1 (NS) SMMW-2 (NS) 80' 1 inch equals 40 feet CES N Ca 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) GRAVEL Project No: 9.0610 Date: 6/18/20 Revision: 0 PROPERTY 177\ / SMMW-1 e SMDW-1 c02 — OHE- - OHC- GRASS/BRUSH Legend Monitoring Well (Type II) Monitoring Well (Type III) Utility/Power Pole Sanitary/Storm Sewer Manhole Overhead Electric Line Overhead Communication Line KEROSENE DISPEN — OHT— Overhead Traffic Control — — Stormwater Ditch 0o Xylenes Concentration Contour Line (12,500) Xylenes Concentration in ug/L (4/29/2020) (FP) Free Product (NS) Not Sampled Xylenes 2L Standard: 500 ug/L CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 7 GPM 3181 Xylenes Concentration (04/29/2020) Extent Exceeding 2L Standards Groundwater Monitoring Report CON RUOL BOXH MW-15 (<1.0) SMMW-8 (NS) Project Manager: DJF Drawn By: RAR Checked By: GRASS 0 20' M (12,50 v SMI„-1 (NS) SMMW-6 (NS) 40' SMMW-1 (NS) MMW-5 (NS) SMMW-4 (NS) SMMW-2 (NS) 80' MM I 1 inch equals 40 feet CES N Ca 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) GRAVEL Project No: 9.0610 Date: 6/18/20 Revision: 0 PROPERTY 177/ GRASS/BRUSH Legend SMMW-1 a Monitoring Well (Type II) SMDW-1 ® Monitoring Well (Type III) co' Utility/Power Pole < Sanitary/Storm Sewer Manhole — OHE— Overhead Electric Line — OHC- Overhead Communication Line — OHT— Overhead Traffic Control Stormwater Ditch Naphthalene Concentration Contour Line Naphthalene Concentration in ug/L (7/20/2018) Free Product Not Sampled (28) (FP) (NS) KEROSENE DISPEN Naphthalene 2L Standard: 6 ug/L CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 8 GPM 3181 Naphthalene Concentration (04/29/2020) Extent Exceeding 2L Standards Groundwater Monitoring Report CON RUOL BOXH MW-15 (<0.50) SMMW-8 (NS) Project Manager: DJF Drawn By: RAR Checked By: GRASS 0 20' (NS) SMMW-6 (NS) SMMW-1 � (NS) 40' 80' 1 inch equals 40 feet CES N Ca 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) GRAVEL Project No: 9.0610 Date: 6/18/20 Revision: 0 A 100 95 90 85 80 75 70 65 „SI05M,I„ CD 1: 1 1t m Ne, IN oa as asswm 0 4: US HWY 421 910m114 00 0¢p 081114,50 i .0 ii JL sm.o,,,. ,,,. ralYISS A' srm 1 1 ♦ 1 ♦ / % 1,000 ug2� / i'111 /I I 11 • 1/II'1 500 ug/L_ - / 1111 • 1 1 1 1` I;1 lugL 1 N LEGEND: A Silty Sand (SM) Clayey Sand (SC) Sandy Clay (CL) Free Product Horizontal Scale: 1" = 25' Vertical Scale: 1" = 5' ♦ Water Table Elevation Notes: 1) 2) 3) SMMW-1 SMMW-2 SMMW-3 SMMW-4 SMMW-5 SMMW-6 SMMW-7 SMMW-8 SMMW-9 MW-3 MW-9 MW-10 MW-12 MW-13 MW-14 MW-15 MW-11D SMDW-1 WELL 1D BENZENE CONCENTRATION (ug2) <0.5 <0.5 528 <0.5 148 567 1,090 <0.5 <0.5 <0.5 <0.5 0.7 710 Free Product <0.5 <0.5 <0.5 <0.5 Groundwater elevation is approximated based on data obtained from monitoring wells MW-3, MW-10, and MW-12 on November 16, 2001, SMMW-1 through SMMW-9, MW-9, MW-11D, MW-14, and MW-15 on March 18, 2002, and MW-13 on April 3, 2002 . Monitoring well MW-11D analytical results are below laboratory detection limits; however, the well is not shown on the cross-section due to effect the monitoring well depth has on the scale. Boring logs for monitoring wells associated with Crown release (MW-10, MW-12, and MW-13) are not available. Delta Environmental Consultants, Inc. 3205 Randall Parkway Suite 104 . Wilmington, North Carolina 28403 PROJECT NO. CLIENT/LOCATION XONC-026 Worsley Companies, Inc. PROJECT MANAGER Scotchman # 181 Wilmington, North Carolina S. LATZ DATE 4/9/02 FIGURE NO. 13 DRAWING DESCRIPTION A -A' Estimated Vertical Extent of Dissolved Benzene Concentrations in Groundwater A 100 95 90 85 80 75 70 65 RCS IINVOINS. . �. 00 �I,n A ANTOINETTE DR. • US STY 421 00 CA [-Mammy. aaMYw. °"" I• I I _m*ow...Lea A' 11 • ra /��+r —r'r ug/L • LEGEND: A Silty Sand (SM) Clayey Sand (SC) Sandy Clay (CL) <intzzl, Free Product Horizontal Scale: 1" = 25' Vertical Scale: 1" = 5' ♦ Water Table Elevation Notes: 1) 2) 3) WELL ID SMMW-1 SMMW-2 SMMW-3 SMMW-4 SMMW-5 SMMW-6 SMMW-7 SMMW-8 SMMW-9 MW-3 MW-9 MW-10 MW-12 MW-13 MW-14 MW-15 MW-11D SMDW-1 MTBE CONCENTRATION u <10 <10 218 <10 <100 <500 839 <10 <10 <10 <10 150 170 Free Product <10. <10 <10 <10 Groundwater elevation is approximated based on data obtained from monitoring wells MW-3, MW-10, and MW-12 on November 16, 2001, SMMW-1 through SMMW-9, MW-9, MW-11D, MW-14, and MW-15 on March 18, 2002, and MW-13 on April 3, 2002 . Monitoring well MW-11D analytical results are below laboratory detection limits; however, the well is not shown on the cross-section due to effect the monitoring well depth has on the scale. Boring logs for monitoring wells associated with Crown release (MW-10, MW-12, and MW-13) are not available. Delta Environmental Consultants, Inc. 3205 Randall Parkway Suite 104 Wilmington, North Carolina 28403 PROJECT NO. CLIENT/LOCATION XONC-026 Worsley Companies, Inc. PROJECT MANAGER S. LATZ Scotchman #181 Wilmington, North Carolina DATE 4/9/02 FIGURE NO. 14 DRAWING DESCRIPTION A -A' Estimated Vertical Extent of Dissolved MTBE Concentrations in Groundwater B 100 95 90 85 80 75 70 65 00 1 1 1 1 1 1 1 ` Estimated Vertical _Extent of Benzene Ono - OOP • 1 1 1 1 1 1 R131 VENT B' US HTY 421 X,V .. T SaJTC.~ vat. 11,fir Pre LEGEND: *113,.t,0 CENTER ss Silty Sand (SM) Clayey Sand (SC) Sandy Clay (CL) Free Product Horizontal Scale: 1" = 25' Vertical Scale: 1"= 5' ♦ Water Table Elevation Notes: 1) 2) 3) WELL ID SMMW-1 SMMW-2 SMMW-3 SMMW-4 SMMW-5 SMMW-6 SMMW-7 SMMW-8 SMMW-9 MW-3 MW-9 MW-10 MW-12 MW-13 MW-14 MW-15 MW-11D SMDW-1 BENZENE CONCENTRATION u <0.5 <0.5 528 <0.5 148 567 1,090 <0.5 <0.5 <0.5 <0.5 0.7 710 Free Product <0.5 <0.5 <0.5 <0.5 Groundwater elevation is approximated based on data obtained from monitoring wells MW-3, MW-10, and MW-12 on November 16, 2001, SMMW-1 through SMMW-9, MW-9, MW-11D, MW-14, and MW-15 on March 18, 2002, and MW-13 on April 3, 2002 . Monitoring well MW-1ID analytical results are below laboratory detection limits; however, the well is not shown on the cross-section due to effect the monitoring well depth has on the scale. Boring logs for monitoring wells associated with Crown release (MW-9 and MW-13) are not available. Delta Environmental Consultants, Inc. 3205 Randall Parkway Suite 104 Wilmington, North Carolina 28403 PROJECT NO. XONC-026 PROJECT MANAGER S. LATZ CLIENT/LOCATION Worsley Companies, Inc. Scotchman # 181 Wilmington, North Carolina DATE 4/9/02 FIGURE NO. 15 DRAWING DESCRIPTION B-B' Estimated Vertical Extent of Dissolved Benzene Concentrations in Groundwater B 100 95 90. 85 80 75 70 65 NI Riga I _ •_ ill • ♦ ------Ei = I Estimated Vertical • Extent of MTBE C B' US HPIy 421 1�i ^wre'I1L /M Yo rtA• ea... f I1II QAM„ i LEGEND: II II IE 1111111 111111t Silty Sand (SM) Clayey Sand (SC) Sandy Clay (CL) ® Free Product Horizontal Scale: 1" = 25' Vertical Scale: 1" = 5' ♦ Water Table Elevation WELL ID MTBE CONCENTRATION (ug/L) SMMW-1 <10 SMMW-2 <10 SMMW-3 218 SMMW-4 <10 SMMW-5 <100 SMMW-6 <500 SMMW-7 839 SMMW-8 <10 SMMW-9 <10 MW-3 <10 MW-9 <10 MW-10 150 MW-12 170 MW-13 Free Product MW-14 <10 MW-15 <10 MW-11D <10 SMDW-1 <10 Notes: 1) Groundwater elevation is approximated based on data obtained from monitoring wells MW-3, MW-10, and MW-12 on November 16, 2001, SMMW-1 through SMMW-9, MW-9, MW-11D, MW-14, and MW-15 on March 18, 2002, and MW-13 on April 3, 2002 . 2) Monitoring well MW-11D analytical results are below laboratory detection limits; however, the well is not shown on the cross-section due to effect the monitoring well depth has on the scale. 3) Boring logs for monitoring wells associated with Crown release (MW-9 and MW-13) are not available. Delta Environmental Consultants, Inc. 3205 Randall Parkway Suite 104 Wilmington, North Carolina 28403 PROJECT NO. XONC-026 PROJECT MANAGER S. LATZ CLIENT/LOCATION Worsley Companies, Inc. Scotchman # 181 Wilmington, North Carolina DATE 4/9/02 FIGURE NO. 16 DRAWING DESCRIPTION B-B' Estimated Vertical Extent of Dissolved MTBE Concentrations in Groundwater PROPERTY LINE„ , / / MW-2 PIUK VENT • GRASS/BRUSH o' Legend SMMW-1 a Monitoring Well (Type II) SMDW-1 ® Monitoring Well (Type III) co' Utility/Power Pole Sanitary/Storm Sewer Manhole — OHE— Overhead Electric Line — OHC- Overhead Communication Line — OHT— Overhead Traffic Control — — Stormwater Ditch -93.801— Groundwater Contour Line (93.38) Groundwater Elevation (feet) Groundwater Flow Direction • / / KEROSENE DISPEN ox\ , ox\ p\°'‚7, 'PO 9�J STORMWATER INLET Ok/t CONTROL COMMUNICATION CONTROL BOX MW-15 (NA) ��, AC PIPES ♦ R/VAC MW-1 0 e 7 MW-3 (93.38) MW-1 1 De MW-1 1 e ASPHALT (NA) UST \ airs 0 SMMW-8 93.80 CONC EIE BO SMMW 9 BASIN \ MW-14 / \ \ \ CRASS W-1`Q (9 ENSERS \SM —3 • sMMW-7 \ MW-9 (93.90) (NA) MW— 0. 3� R _1\ \ \ (94.00)) SMMW-5 SMDW-1 SMMW-6 oHC' GRASS ASPHALT SMMW-1 / / 0 20' 40' O SMMW-4 \ F\ SMMW-2 OHC — 80' 1 inch equals 40 feet GRAVEL CLIENT: GPM Southeast, LLC LOCATION: 5302 Carolina Beach Road Wilmington, North Carolina Figure 3 Project Manager: DJF GPM 3181 Water Table Elevation Map (04/29/2020) Drawn By: RAR Checked By: CESN CJ a Project No: 9.0610 Date: 06/18/20 Groundwater Monitoring Report 5104 Reagan Drive, Suite 7 Charlotte, NC 28206 540-343-6256 (phone) 540-343-6259 (fax) Revision: 0 TABLE 4 SUMMARY OF WELL CONSTRUCTION DATA GPM 3181 (Scotchman #3181) Wilmington, New Hanover County, North Carolina Well ID Boring Depth (ft, bgs) Well Screen Interval (ft, bgs) Well Diameter (inches) Top of Casing Elevation (ft) Installation Date Well Status/Comments MW-1 NA NA NA 102.15 NA Not Located, data not available MW-2 12 2 - 12 2 99.32 8/7/1991 Current, installed by AES MW-3 12 2 - 12 2 97.65 8/7/1991 Current, installed by AES MW-4 NA NA NA 100.69 1991 Destroyed prior to 2000, installed by AES MW-5 NA NA NA 97.89 1992 Destroyed/removed prior to 2000 MW-6 15 2.5 - 15 2 99.83 6/9/1992 Not Located, data not available MW-7 NA NA NA 99.60 1992 Destroyed/removed prior to 2000 MW-8 NA NA NA NA NA Not Located, data not available MW-9 13 3 - 13 2 98.69 2/18/2000 Current, installed by Agra MW-10 13 3 - 13 2 98.01 2/18/2000 Current, installed by Agra MW-11 12 2-12 2 NA 3/7/2018 Current, installed by Regional Probing MW-11D 40 30 - 40 2 97.73 2/18-19/2000 Current, installed by Agra MW-12 13 3 - 13 2 97.94 10/11/2000 Current, installed by Agra MW-13 13 3 - 13 2 98.09 10/11/2000 Current, installed by Agra MW-14 13 3 - 13 2 98.21 10/11/2000 Current, installed by Agra MW-15 13 3 - 13 2 NA 10/11/2000 Current, installed by Agra SMMW-1 12 2 - 12 2 99.71 7/25/2001 Current, installed by Delta SMMW-2 12 2 - 12 2 99.05 7/25/2001 Current, installed by Delta SMMW-3 10 2 - 10 2 97.93 7/25/2001 Current, installed by Delta SMMW-4 12 2 - 12 2 98.82 3/14/2002 Current, installed by Delta SMMW-5 12 2 - 12 2 98.13 3/14/2002 Current, installed by Delta SMMW-6 12 2 - 12 2 98.80 3/14/2002 Current, installed by Delta SMMW-7 12 2 - 12 2 98.56 3/14/2002 Current, installed by Delta SMMW-8 12 2 - 12 2 98.38 3/14/2002 Current, installed by Delta SMMW-9 12 2 - 12 2 98.00 3/14/2002 Current, installed by Delta SMDW-1 25 20 - 25 2 98.91 7/25/2001 Current, installed by Delta RW-1 NA NA 4 NA NA Current, data not available AS-1 22 20 - 22 2 NA NA Current, installed by Delta SVE-1 NA NA 2 NA NA Current, horizontal well installed by Delta OB-1 15 1 - 15 2 NA 9/2002 Current, installed by Delta Notes: - ft,bgs denotes feet, below ground surface - NA indicates that this information is not available - Delta (Delta Environmental Consultants, Inc.) - Agra (Agra Environmental, Inc.) - AES (Applied Environmental Sciences, Inc.) '. NORTH CAROLNA pNl?!+,E,NT Or NATLRAL rlirlpURCEll AND COMIAJNITY oevactit lerrr DIYISIO�t;QF'ciY 04- ORouIgWATEfi 8E0110N P.Q. 114.0761.11.C,27e11,PHONE(e10033-MI rorli TriucTIO 4 nECOnD • Mw4I? w I1.Ln o COrt rnAoTOn LEf I'f.LEf t I1E013 rf 1A71011 ttUMUEll ' 1, WELL LOCA11QN: (S iopr otetCh pr She 4o,Ca�lop below) Nearest Town: w26 N G 0/1/ (flood, Community, or.SubdlvIslon and Lot No.) 2. OWNER C%ZOL) ' ADDRESS 'reel or oil—uje No, City or Town Slate Zip Code 13. DA1E DRILLED /Q_ USE OF WELL Via/_ -zaLe s. TOTAL DEPTH —.DZ.___, CUTTINGSEl No : COLLECTED ❑Yea 15. DOES WELL REPLACE.E.XISTING.Y.iELL7 ❑ Yes GB NQ 8, STATIC WATER LEVEL FT. D above 1& C] below TOP OF CASING TOP OF CASING, --__ FT. ABOVE LAND. SURFACE. ,7, YIELD (gpm): —__ METHOD OF TEST 3. WATER ZONES (depth): 1CHLORINATION: Type Amount 0. CASING: Depth Wall Thickness Diameter or Weight/Ft. Material From To Ft From To Ft. From To 111. FL GROUT: From From 2. SCREEN: ' DlPM Diameter Slot Size From. Material To.' }. Ft,- In. •(7O In, _.t(L ' From,:.Tg_,r�-rP1.-- IR-__-In. From Tq-- fl In. In. L GRAVEL PACK: I Depttl She Materiel From _ /1 _ _. TQ..�_ .1.1rP c—.� w. __ f /..c'. 'REMARKS.---•.FrarirTe.r-- �-f,lr --- Depth Material Method T.o / FL_�f—N �iyLc nr.2 1, P.- FLall�c,,otir-'7.-n= FOR OFFICE DSE.DNLY Quad, No.Serlal No. Lat. Long. Minor Basin Pc - Basin Code Iloader F.nl ___.---- GW-I En1.. 9IATF. Y1lFILL (OE!•i'IT1UC ION rum". NUI:ft3[t1: County: /t/ Depth URII.LIN(3 LOG From To Formolion Description 1-4 NBC r r,Jit/T> If additional space Is needad use back of form. LOCATION K Try (Show direction and dletance from at least two Slate Roads, or other map reference points) 1 4 y rst o v pvciro I DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C, WELL CONSTRUCTION ' STANDARDS, AND THAT A COPY OF THIS RECORD K S PROVIDED TO THE WELL OWNER. r SIGNATURE • / - - dui Y-1 Revved 6/80 CONTRACTOR OR AGENT DATE Subm11 original to Division of Environmental Management and copy to well owner. 1 .FOR OFFICE USE ONLY I NORTH CAROL INA 01/1ARflsa CO WAN. Agotwola AID oOs tilrTY avgLoroorT miaow OF l trvIROi.xrM'women' - oRO(AgWAIVI NOTION pm, Dog !plot-N.IJIGIUIQ. 17e11, h KM (9 te)7N-9et1 wail. CONt}TflU4:1'IOPI fl !COfE IM4✓ 413. t11;tI.lR!13 CQ ltRACTOR �9ZD5 1)(19.1.411 Itr_plr't' 1A11G11 tIUMUE11 %-? 3 0 Quad. No. feria No. Lot. Long. Pc Nihror Saeln Bengt Code _ IIo•dor F.:It.-_- OW-1 Elul.___. SIA'IF. WF,I.I. COI 1 711Ur1'H.1E1 I F11h1I'I' I!UI 10F1l: 1. WELL LOCATION: (Stay!, sketch of10* Woollen below) Nooioot Town: 11)2 C. 2-,v Grp", County: // Con% �ii/v v� I CARQ (Iload, Community, or Subdivision and Lot No.) Depth onfLLINO L00 L'tw9 p CsC(/ Rd, 2. OWNER Cgr.)LO r✓ ZWC. F� S Formation Descr n MbII/Hire_ a,D j r n 7-/I .•V Ve r fi/t/n O / 3 D [-ACL< 1 i4r- f/i✓rD ADDRESS (Stress or eels o.) City or, Town Slats Zip Cods 113. DATE DRILLED /0 -// PO use OF WELL "v11 awrrC<Z 1. TOTAL DEPTH / 3' CUTTINGS COLLECTED ❑Yes ©No S. DOES WELL REPLACE EXISTING®' G WELL? ❑ Yes No 116. STATIC WATER LEVEL:„ FT. Sabove TOP Of CASINO, TOP OF CASING 18 B babes FT ABOVE LAND SURFACE. 17. YIELD (gpmk METHOD OF TEST !, WATER ZONES (depth) I. CHLORINATION: Type Amount ---� 0. CASINO: From From Prim D. GROUT lhickness Oeoth Diameter orlweight/Ft. Materiel To Ft. To .Ft. To FL DeoN Mafiosi Method From To/ Ft._Jl.V7T.t�t�[ 2r],./2 From /--- To.—` FL rvr+r c r + c,.r- 1. SCREEN: IDept Dlametsr Slot Sits Materiel From ���.To }, FI. 1 • t From lit FL litin, ry 1, £ v From.. —_ To-.._. FL h. it3 6 GRAVEL. PACK: d ( LP I a D�Pth Size Yrgl9al U From ' To c7- Ft. cQZ ,i 2 �C From To:, _ Ft. »�. REMARKS: 100 HERESY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 16 NCAC 2C, WELL CON1TRUCTION STA/DARDB. AND THAT A COPY OF THIS RECCAO H 41 -X MOILED TO THE WELL OWNER II addIIIonal space Is needed use back of form. LOCATION sx try (Show dkection and distance from at least two Slate Roads, or other map reference points) Soo_fk (re.1.. S} • i i o"►rw J��.c l-,E) r-1 pooled aka A1n I oCk. ,N- SIMATLIRE' • • TOR OR AGENT Submit original b Division of Environmental Management and DATE riopY 10 !reef owner, roe J / -a 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions SAFETY DATA SHEET RemOx® SR+ ISCO Reagent None. In situ and ex situ chemical oxidation of contaminants and compounds of concern for environmental remediation applications. Use in accordance with supplier's recommendations. Manufacturer/Importer/Supplier/Distributor information Company name Address Telephone E-mail Website Contact person Emergency Telephone 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Signal word Hazard statement CARUS CORPORATION 315 Fifth Street, Peru, IL 61354, USA +1 815 223-1500 - All other non -emergency inquiries about the product should be directed to the company salesmkt@caruscorporation.com www.caruscorporation.com Dr. Chithambarathanu Pillai For Hazardous Materials [or Dangerous Goods] Incidents ONLY (spill, leak, fire, exposure or accident), call CHEMTREC at CHEMTREC®, USA: 001 (800) 424-9300 CHEMTREC®, Mexico (Toll -Free - must be dialed from within country): 01-800-681-9531 CHEMTREC®, Other countries: 001 (703) 527-3887 Oxidizing solids Acute toxicity, oral Skin corrosion/irritation Sensitization, respiratory Sensitization, skin Specific target organ toxicity, single exposure Specific target organ toxicity, repeated exposure Hazardous to the aquatic environment, acute hazard Hazardous to the aquatic environment, long-term hazard Not classified. Category 3 Category 4 Category 1 B Category 1 Category 1 Category 1 (Respiratory system) Category 1 (Central Nervous System, Respiratory system) Category 1 Category 1 Danger May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Causes damage to organs (Respiratory system). Causes damage to organs (Central Nervous System, Respiratory system) through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. RemOx® SR+ ISCO Reagent SDS US 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 1/9 Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Keep away from heat. Keep/Store away from clothing//combustible materials. Do not breathe dust. Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Take any precaution to avoid mixing with combustibles. [In case of inadequate ventilation] wear respiratory protection. Contaminated work clothing must not be allowed out of the workplace. Avoid release to the environment. In case of fire: Use water for extinction. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If experiencing respiratory symptoms: Call a poison center/doctor. Take off immediately all contaminated clothing and wash it before reuse. If exposed or concerned: Call a poison center/doctor. Immediately call a poison center/doctor. Collect spillage. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number % Potassium permanganate 7722-64-7 20 - 40 Sodium persulfate 7775-27-1 20 - 40 Composition comments 4. First -aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire -fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Remove victim to fresh air and keep at rest in a position comfortable for breathing. For breathing difficulties, oxygen may be necessary. Get medical attention immediately. Remove contaminated clothing and shoes. Wash contaminated clothing before reuse. Get medical attention immediately. Contact with skin may leave a brown stain of insoluble manganese dioxide. This can be easily removed by washing with a mixture of equal volume of household vinegar and 3% hydrogen peroxide, followed by washing with soap and water. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart. Continue rinsing. Get medical attention immediately. Immediately rinse mouth and drink plenty of water. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical attention immediately. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. Symptoms may be delayed. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Flood with water from a distance, water spray or fog. Dry chemical. Foam. Carbon dioxide (CO2). Halogenated materials. Oxidizing agent, may cause spontaneous ignition of combustible materials. By heating and fire, corrosive vapors/gases may be formed. RemOx® SR+ ISCO Reagent SDS US 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 2/9 Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Selection of respiratory protection for firefighting: follow the general fire precautions indicated in the workplace. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. Dike fire control water for later disposal. Water runoff can cause environmental damage. The product is not flammable. May intensify fire; oxidizer. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Environmental precautions 7. Handling and storage Precautions for safe handling Keep unnecessary personnel away. Avoid inhalation of dust and contact with skin and eyes. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Wear protective clothing as described in Section 8 of this safety data sheet. Local authorities should be advised if significant spillages cannot be contained. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into the environment. This product is miscible in water. Stop leak if possible without any risk. Dike the spilled material, where this is possible. Never return spills in original containers for re -use. For waste disposal, see Section 13 of the SDS. Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage to drain/aquatic environment. Take any precaution to avoid mixing with combustibles. Keep away from clothing and other combustible materials. Do not get this material in your eyes, on your skin, or on your clothing. Do not breathe dust or mist or vapor of the solution. If clothing becomes contaminated, remove and wash off immediately. When using, do not eat, drink or smoke. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Avoid release to the environment. Do not expose to sparks, heat, open flames, or hot surfaces. It is important that smoking is not allowed in proximity to RemOx® SR. Do not cut RemOx® SR ISCO Reagent with any cutting tool which could produce friction (i.e. hand saws, circular saws, reciprocal saws, etc.) as it may cause ignition of the material. Conditions for safe storage, Store locked up. Keep container tightly closed and in a well -ventilated place. Store in a cool, dry including any incompatibilities place. Store away from incompatible materials (See Section 10). Follow applicable local/national/international recommendations on storage of oxidizers. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Potassium permanganate Ceiling 5 mg/m3 (CAS 7722-64-7) US. ACGIH Threshold Limit Values Components Type Value Form Potassium permanganate (CAS 7722-64-7) Sodium persulfate (CAS 7775-27-1) US. NIOSH: Pocket Guide to Chemical Hazards TWA Components TWA 0.1 mg/m3 Inhalable fraction. 0.02 mg/m3 0.1 mg/m3 Type Value Respirable fraction. Form Potassium permanganate (CAS 7722-64-7) STEL TWA 3 mg/m3 Fume. 1 mg/m3 Fume. Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines Follow standard monitoring procedures. RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date: - Issue date: 04 -April-2015 SDS US 3/9 Appropriate engineering controls Individual protection measures, Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Provide adequate general and local exhaust ventilation. An eye wash and safety shower must be available in the immediate work area. such as personal protective equipment Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes. Use protective gloves made of: Rubber or plastic. Suitable gloves can be recommended by the glove supplier. Wear chemical -resistant, impervious gloves. In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter. In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134. Wear appropriate thermal protective clothing, when necessary. When using, do not eat, drink or smoke. Keep from contact with clothing and other combustible materials. Remove and wash contaminated clothing promptly. Wash hands before breaks and immediately after handling the product. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Appearance White solid. Physical state Solid. Form Solid. Color White. Odor Paraffinic. Odor threshold Not applicable. pH Not applicable. Melting point/freezing point 130 °F (54.44 °C) Not applicable. Initial boiling point and boiling range Flash point Evaporation rate Not applicable. Not applicable. Flammability (solid, gas) Non flammable. Upper/lower flammability or explosive limits Flammability limit - lower Not applicable. (%) Flammability limit - upper Not applicable. (%) Explosive limit - lower (%) Not applicable. Explosive limit - upper (%) Not applicable. Vapor pressure Not applicable. Vapor density Not applicable. Relative density 1.18 (25 °C) Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto -ignition temperature Decomposition temperature Viscosity Other information Explosive properties Oxidizing properties 10. Stability and reactivity Reactivity Not available. Not applicable. Not available. Not available. Not applicable. Not explosive. Can explode in contact with sulfuric acid, peroxides and metal powders. Oxidizer. The product is stable and non -reactive under normal conditions of use, storage and transport. RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date: - Issue date: 04 -April-2015 SDS US 4/9 Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable at normal conditions. Contact with combustible material may cause fire. Contact with combustibles. Acids. Peroxides. Reducing agents. Combustible material. Metal powders. Contact with hydrochloric acid liberates chlorine gas. By heating and fire, corrosive vapors/gases may be formed. 11. Toxicological information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Components Harmful if swallowed. Species May cause irritation to the respiratory system. Causes severe skin burns. Causes serious eye damage. Harmful if swallowed. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. Test Results Potassium permanganate (CAS 7722-64-7) Acute Dermal LD50 Rat Oral LD50 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Rat Causes severe skin bums. Causes serious eye damage. 2000 mg/kg 2000 mg/kg May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause allergic skin reaction. Test data conclusive but not sufficient for classification. Test data conclusive but not sufficient for classification. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Ecotoxicity Test data conclusive but not sufficient for classification. Causes damage to organs (respiratory system). Causes damage to organs (respiratory system, central nervous system) through prolonged or repeated exposure. Based on available data, the classification criteria are not met. May cause damage to respiratory system. Prolonged exposure, usually over many years, to manganese oxide fume/dust can lead to chronic manganese poisoning, chiefly affecting the central nervous system. No other specific acute or chronic health impact noted. Very toxic to aquatic life with long lasting effects. RemOx® SR+ ISCO Reagent SDS US 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 5/9 Components Species Test Results Potassium permanganate (CAS 7722-64-7) Aquatic Fish LC50 Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects Bluegill (Lepomis macrochirus) Carp (Cyprinus carpio) 2.7 mg/I, 96 hours static 2.3 mg/I, 96 hours flow through 2.3 mg/I, 96 hours 1.8 - 5.6 mg/I 3.16 - 3.77 mg/I, 96 hours 2.97 - 3.11 mg/I, 96 hours 3.3 - 3.93 mg/I, 96 hours static > 1.4 mg/I, 96 hours 1.8 mg/I, 96 hours 1.08 - 1.38 mg/I, 96 hours 0.77 - 1.27 mg/I, 96 hours Expected to be readily converted by oxidizable materials to insoluble manganese oxide. Potential to bioaccumulate is low. Not available. The product is water soluble and may spread in water systems. None known. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant Special precautions for user Special provisions Packaging exceptions Packaging non bulk Packaging bulk IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Goldfish (Carassius auratus) Milkfish, salmon -herring (Chanos chanos) Rainbow trout (Oncorhynchus mykiss) Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. D001: Ignitable waste The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all applicable regulations. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. U N 1479 Oxidizing solid, n.o.s. (Sodium persulfate, Potassium permanganate) 5.1 5.1 I I Yes Read safety instructions, SDS and emergency procedures before handling. 62, IB5, IP1 None 211 242 U N 1479 Oxidizing solid, n.o.s. (Sodium persulfate, Potassium permanganate) 5.1 RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date: - Issue date: 04 -April-2015 SDS US 6/9 Label(s) Packing group Environmental hazards ERG Code Special precautions for user IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Label(s) Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations 5.1 I I Yes 5L Read safety instructions, SDS and emergency procedures before handling. U N 1479 OXIDIZING SOLID, N.O.S. (Sodium persulfate, Potassium permanganate) 5.1 5.1 I I Yes F-A, S-Q Read safety instructions, SDS and emergency procedures before handling. Not applicable. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Potassium permanganate (CAS 7722-64-7) LISTED Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Chemical name CAS number % by wt. Potassium permanganate 7722-64-7 20 - 40 Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Potassium permanganate (CAS 7722-64-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Potassium permanganate (CAS 7722-64-7) 6579 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Potassium permanganate (CAS 7722-64-7) 15 %WT RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 SDS US 7/9 DEA Exempt Chemical Mixtures Code Number Potassium permanganate (CAS 7722-64-7) 6579 US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Potassium permanganate (CAS 7722-64-7) US. New Jersey Worker and Community Right -to -Know Act Potassium permanganate (CAS 7722-64-7) Sodium persulfate (CAS 7775-27-1) US. Pennsylvania Worker and Community Right -to -Know Law Potassium permanganate (CAS 7722-64-7) US. Rhode Island RTK Potassium permanganate (CAS 7722-64-7) US. California Proposition 65 Not Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) Yes United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Revision date Version # NFPA ratings List of abbreviations References 01-December-2014 01 LD50: Lethal Dose, 50%. LC50: Lethal Concentration, 50%. Chemical safety report. ECHA registered substances database RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 SDS US 8/9 Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user of the product. RemOx® is a registered trademark of Carus Corporation. RemOx® SR+ ISCO Reagent 923162cp Version#: 01 Revision date:- Issue date: 04 -April-2015 SDS US 9/9