WQ0008778_Residual Annual Report 2020_20210223

Initial Review
Reviewer Thornburg, Nathaniel
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application what is the submittal type?* r Annual Report
r Residual Annual Report
r Additional Information
r Other
Annual Report Year* 2020
Permit Number (IR)* W00008778
Applicant/Permittee Town of Farmville
Email Notifications
Does this need review by the hydrogeologist?* 0 Yes r No
Regional Office Washington
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide infornation on the person to be contacted by N B Staff
Name * Lysa Finnerty
Email Address*
[e-mail]
electronic subnittal, confirmation of receipt, and other correspondence.
Project Information
........ ......... ....................................................................................................................................... .
Application/Document Type* r New (Fee Req ui red)
r Modification - Major (Fee Required)
r Renewal with Major Modification (Fee
Required)
r Annual Report
r Additional Information
r Other
Phone Number*
14105376150
O Modification - Minor
C Renewal
C GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
r Residual Annual Report
r Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* r Wastewater Irrigation r High -Rate Infiltration
r Other Wastewater r Reclaimed Water
r Closed -Loop Recycle r Residuals
r Single -Family Residence Wastewater r Other
Irrigation
Permit Number:* W00008778
Fbs Current Existing perrrit number
Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220
Facility Name * Town of Farmville RLAP
Please provide comments/notes on your current submittal below.
2020 Annual Report for Town of Farmville NC
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form Engineering Fans, Specifications, Calculations, Bc.)
Farmville NC 2020 Annual Report FINAL.pdf 6.11MB
Upload only 1 FCFdocurrent (less than 2501vB). Miltiple docurrents mist be corrbined into one F7Ffile unless file is larger than
upload limit.
* V By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order
and made payable to the North Carolina Department of Environmental Quality
(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 2/23/2021

435 Williams Court, Suite 100
Baltimore, MD 21220
www.synagro.com
FEBRUARY 23, 2021
NCDEQ
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2020 Annual Report for Permit No. WQ0008778
Dear NCDEQ:
SYNAGRO
Synagro is submitting one electronic copy of the above referenced report on behalf of the Town
of Farmville, NC.
If you have any questions or need additional information, please do not hesitate to contact
James Shoulders at [phone] or Chris Wynne at [phone].
Sincerely,
oe"i& Shuuc" ,es
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: James Shoulders
Chris Wynne, Synagro
YOUR PARTNER FORA CLEANER, GREENERWORLD

TOWN OF FARMVILLE, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0008778
2020 ANNUAL REPORT

Town of Farmville, NC
Residuals Land Application Program
2020 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms and Residuals
Analyses
3. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen Reduction/Vector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analyses

SECTION 1

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit #: WQ0008778 County Pitt Year 2020
Facility Name (as shown on permit) Farmville WWTP NPDES No. NC0029572
Land Application Operator Synagro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A — Residuals Anplication Summa
Total number of application fields in the permit: 7
Total number of fields utilized for land application during the year: 3
Total amount of dry tons applied during the year for all application sites: 59.02
Total number of acres utilized for land application during the year: 54.30
Part B — Annual Compliance Statement:
Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items
1-13 below) issued by the Division of Water Quality X YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C — Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. l
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations." 1
David P. Hodgkins, Town Manager
Permittee N and,T% itl (type or print) r�
J�4 ! L y�
Signature of Prepare Date
(if different from Permittee)
J-� f l z!cx
Signature ofPermittee bate
I
Sign o Date
(if different from e r and Pr er)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA
ALL COUNTIES - ALL SITES
DATE RANGE: 1/1/2020 - 12/31/2020
FARMVILLE, NC
FARMVILLE, NC AEROBICALLY DIGESTED LIQUID
MONTH/YEAR
January 2020
June 2020
TOTAL
AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS
210,800.00 G 14.06 D 12.76
390,600.00 G 44.95 D 40.77
601,400.00 G 59.02 D
53.53
Report Date: 2/2/2021 3:57:39 PM

SECTION 2

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0008778 Laboratory:
Facility Name: FARMVILLE, NC PACE ANALYTICAL
Residual Source WQ # or
NPDES#: NCO029572
WWTP Name: FARMVILLE
Residual Analysis Data
Product Type
AEDLIQ
Sample or Composite Date
02/27/20
Parameter (mg/kg dry weight)
Ceiling Conc.
Limit
Percent Solids (%)
NA
2.76
Arsenic
75
4.4
Cadmium
85
1.1
Copper
4300
330
Chromium
NA
26
Lead
840
23
Mercury
57
<0.66
Molybdenum
75
6.3
Nickel
420
17
Selenium
100
5.8
Zinc
7500
670
Total Phosphorus
NA
16000
TKN
NA
43000
Ammonia -Nitrogen
NA
1000
Nitrate and Nitrite
NA
70.4
For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment rf knowing violations."
Signature of Preparer' Date
Treparer is defined in 40 CFR Part503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (1212006)
Printed: 2/2/2021 4:02:01 PM For: 2015 01

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0008778
Facility Name:
FARIVIVILLE, NC
Residual Source
NPDES # or WQ#:
NCO029572
VVVVTP Name:
FARIVIVILLE
Residual Analysis Data
Product Type
AEDLIQ
Sample or Composite Date
02/27/20
Parameters (mg/kg dry weight)
Aluminium
10000
Calcium
8900
Magnesium
2500
pH (s.u.)
6.20
Potassium
4000
Sodium
1600
PAN
13170
SAR (Ratio)
0.6394
Laboratory:
PACE ANALYTICAL
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified
personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and impr 4onm 4efor knowing violations."
-11 &
Signature of Preparer Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1 102(26)
Printed: 2/2/20214:01:01 PM For: 2015 01 DENR FORM RSSF-B (12/2006)

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Nate Roth
Project Name: Farmville
Lot Number:VC03017
Date Completed:03/18/2020
MIM�� Mr�
03/18/2020 2:19 PM
Approved and released by:
Lab Director - Greenville: Lucas Odom
Q PCCRBp��
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ANSI NdmlAccre00- Board
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A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: VC03017
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance
Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to
the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W'
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low percent solids, sample -001 was weighed out at 3 times the normal weight. The LOQ has been
elevated to reflect the dilution.
Paint Filter
This analysis has been qualified with an "H", however, there is not a method defined hold time for this
analysis.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received: 03/03/2020
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
(% Solids) SM 2540G
1
03/03/2020 2237 MDD
46788
1
(Ignitability) 1010A
1
03/09/2020 1348 SLC
47298
1
(Paint Filter) 9095B
1
03/10/2020 1443 SLC
1
(Reactive Cya) 7.3.3
1
03/10/2020 0000 KFE 03/10/2020 1046
1
(Reactive Sul) 7.3.4
1
03/10/2020 1925 HET 03/10/2020 1046
1
(Soil pH meas) 9045D
1
03/05/2020 2159 SRB
47065
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
1.65
%
1
Ignitability (Pensky-Martens Closed -Cup)
1010A
>140
140
0
o F
1
Paint Filter Test
9095B
Fail H"
pass/fail
1
Reactive Cyanide
7.3.3
ND
50
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
50
mg/kg
1
Soil pH measured in water @ 21 ° C
9045D
6.1
su
1
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/5030B 8260D
10 03/13/2020 0350 JTH
47756
03/11/2020 2110
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Benzene
71-43-2 8260D
ND
0.050
0.0040
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
0.020
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
0.0040
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
0.0040
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
0.0040
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
0.0040
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
0.0040
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
0.0040
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
0.0040
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
0.0040
mg/L
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
100 70-130
1,2-Dichloroethane-d4
97 70-130
Toluene-d8
105 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 03/12/2020 1340 SCD 03/10/2020 1710
47402 03/08/2020 2357
CAS Analytical
Parameter
Number Method Result Q
LOQ DL Units Run
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL
= Detection Limit
ND = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J =
Estimated result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received:03/03/2020
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8270E
1 03/12/2020 1340 SCD
03/10/2020 1710 47402
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
0.0050
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
0.0050
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
0.0050
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
0.0050
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
0.010
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
0.010
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
0.015
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
0.015
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
0.020
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
0.0050
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
0.0050
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
67 37-129
2-Fluorophenol
37 24-127
Nitrobenzene-d5
68 38-127
Phenol-d5
61 28-128
Terphenyl-d 14
83 10-148
2,4,6-Tribromophenol
72 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/8151A
8151A
1 03/16/2020 1738 JJG
03/12/2020 1747 47726
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
0.0050
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
0.0013
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
70 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8081B
1 03/13/20201519 DAL1
03/11/20201452 47527
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
gamma-BHC (Lindane)
58-89-9 8081B
ND
0.00040
0.00017
mg/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
ND = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result
< LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received:03/03/2020
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8081B
1 03/13/20201519 DAL1
03/11/20201452
47527
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Chlordane
57-74-9 8081B
ND
0.0040
0.0015
mg/L
1
Endrin
72-20-8 8081B
ND
0.00040
0.00015
mg/L
1
Heptachlor
76-44-8 8081B
ND
0.00040
0.00015
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
0.00016
mg/L
1
Methoxychlor
72-43-5 8081B
ND
0.0016
0.00021
mg/L
1
Toxaphene
8001-35-2 8081B
ND
0.0080
0.0030
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
84 20-131
Tetrachloro-m-xylene
86 26-132
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3010A
6010D
1 03/10/2020 0412 LLL
03/09/2020 2018 47306
03/08/2020 2357
1 1311/7470A
7470A
1 03/10/2020 1512 KSH2
03/10/2020 0941 47316
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
0.025
mg/L
1
Barium
7440-39-3 6010D
0.35
0.25
0.031
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
0.0060
mg/L
1
Chromium
7440-47-3 6010D
ND
0.10
0.013
mg/L
1
Lead
7439-92-1 6010D
ND
0.10
0.047
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
0.00091
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
0.085
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
0.021
mg/L
1
Footnote(s): 'Paint Filter: 40mL collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client:Synagro Laboratory ID:VC03017-002
Description: FV Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 2.76 03/03/2020 2237
Date Received: 03/03/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 03/03/2020 2237 MDD
46788
1 350.1
(Ammonia - N ) 350.1
1 03/09/2020 1406 SLC
46871
2
(Nitrate - N ) 9056A
1 03/17/2020 1156 AMR
48204
1
(Nitrite - N ) 9056A
1 03/11/2020 1643 AMR
47697
1
(Phosphorus) 365.1
10 03/06/2020 1343 DMA
03/06/2020 0937
47087
1
(Soil pH meas) 9045D
1 03/05/2020 2201 SRB
47065
1 351.4
(TKN) 351.2
1 03/04/2020 1544 DMA
03/04/2020 1002
46808
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
2.76
%
1
Ammonia - N (gas diffusion)
350.1
1000
36
19
mg/kg
1
Nitrate - N (soluble)
9056A
65
18
0.89
mg/kg
2
Nitrite - N (soluble)
9056A
5.4 J
7.2
0.69
mg/kg
1
Phosphorus
7723-14-0 365.1
16000
1800
360
mg/kg
1
Soil pH measured in water @
21 ° C
9045D
6.2
su
1
TKN
351.2
43000
900
900
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 03/04/2020 1630 KSH2
03/04/2020 1230
46714
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471B
ND
2.7
0.66
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 03/09/2020 1918 LLL
03/06/2020 1452
46709
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
10000
240
89
mg/kg
1
Arsenic
7440-38-2 6010D
4.4 J
8.9
3.0
mg/kg
1
Cadmium
7440-43-9 6010D
1.1 J
3.0
0.75
mg/kg
1
Calcium
7440-70-2 6010D
8900
3000
370
mg/kg
1
Chromium
7440-47-3 6010D
26
5.9
1.5
mg/kg
1
Copper
7440-50-8 6010D
330
5.9
2.7
mg/kg
1
Iron
7439-89-6 6010D
22000
59
27
mg/kg
1
Lead
7439-92-1 6010D
23
5.9
2.7
mg/kg
1
Magnesium
7439-95-4 6010D
2500 J
3000
370
mg/kg
1
Manganese
7439-96-5 6010D
290
8.9
3.5
mg/kg
1
Molybdenum
7439-98-7 6010D
6.3 J
24
5.9
mg/kg
1
Nickel
7440-02-0 6010D
17 J
24
6.2
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client:Synagro Laboratory ID:VC03017-002
Description: FV Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 2.76 03/03/2020 2237
Date Received:03/03/2020
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D 1 03/09/2020 1918 LLL
03/06/2020 1452
46709
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Potassium
7440-09-7 6010D
4000
3000
370
mg/kg
1
Selenium
7782-49-2 6010D
5.8 J
12
4.8
mg/kg
1
Sodium
7440-23-5 6010D
1600 J
3000
370
mg/kg
1
Zinc
7440-66-6 6010D
670
30
7.4
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES. LLC
Sheed
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
Shmry rrl'iwi nOurul 3ta ;m, Inc. '
EotumcmNL,lNcr:_41�3+xr:tiL'-ta �iT:���,:•:�� r:e:^�6,7:�]:�
Sample Receipt Checklist (SRQ
C-liett[' Sy:tagro — T Cooler inspeeLed by/date: l3mG J DM3.2021) Lot i1: VC43417
McattsoUTctcipt; 0 SESL ©{;[iCnt UPS ® 1FedEx O1hcr. _
d Yes 91 NQL. I. Were cusi seals presets' cc tlu; eooIV,
�'fcs hia NA 2_ If c u sr0dy seaL� wrrL M. ,grmt, were tlsey intact and unbroken"
-ip 10: T*iA Chlorttle Strip ID, CIA Tested by- NA
Jri-Mir7al tcrnuetature up vn rcccipt J3erived (COTm 4 tenLiler4urti upon moeiirt Solid soap -dap IJ�: i9-2:,1 #
-4.f. i4.2 flC NA iNA °C NA O'JN4 hC NA 4NA d{;
ja tBotles 11Z Gun ID: TR - Gun Gormcdcn Faz;wr; 10 °C
�+Tetlirxl; W`1'c3m[1ei'aturcT )auk ❑A
Method of molant; 0 duet Ice Elft,,: Packs ❑ Icn t] None-
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❑ Y �a No 0NA 3- if tempomfure of any roofer Lnxeedej 6,01C, was Project Managar Nat'sfieri?
1 M �•a3 Notified :)y_ pltae l email i %oe-Waec keirrJ,e one).
Yes 0 h'o ❑NA 4, is fl c comrrercial COuricCS packin .G] ip aMehed to psis farm?
Yes 0 No 3, ct+c rcrper rustodv i octxtunm (L-ulinquisltad�r eived) followed?
2 't' �s Nrr 6_ Wrrn sample IDs I:sLrA an the COC? -
Yee ❑ N
Yeg ❑ N
7, Wury sample [Ds I:sted on all sirtplC conlaincry
ll_ Was collection &rav k. Lim listed an tlra COC? -
9- Was collective date & tims ]iMd on aJl salnple untainurs?
10. Did all container Calm-1 icifurrnation 01133 dins rime) agree With thr.
11. We,- LrAs Lo be nerfi)rned listed on the COO?
�,rs ❑ No 1
12. Did all samplcs arrive in Ow prtaper cnaM1ners For each test EuILUor in good condition
tunbrvlwn, lids on, etc.r
V1 PF ❑ No
=eso
_ Y -S 1- a
EJ Yes ❑ bTv
t—r Ycx L.-7N-
[] Yes, ❑ No
❑ ZI r No
i3. Was Nkqualc %irnpic +roluule avdi'.eblt;? -
14_VIW8ft all samplesre�ct�%dwith'n'rzlheholdingtifitaor ShoL.es_whichevr.Tcoiuesfuse
15_ W= arry ssrtLp]es Crrnlzij)= miss iu }+excess (rimte ojie) 9araples Not lisit:d un CUU?
NA J6. For VOA and UK-1 ;5 sampl er., wcire bubbles preskl3t >-pea-qi;,, " ('la"ar Gtnrn in diarnaLcr)
it nny of ]te VOA vial3i
14 NA 17, Wvm ail DROr me4Lls nutrient :, mlcs rccri-vcd Es a pH of < 2? —
VJ NA 18. Wore a]I cyanide samples rereiwii ut a plI > 12 and s11[fide 3arnrc=ived at a pH > 99
®h A 19_ WC re 0111 HPPJ Lcablc N.l�,(l K llcyan ifller'pMti 62_S (< 0_.5mgiQ samples rep ofresidual
❑ Yes CJ No '20. Were ell ienLrcninrksdrequests [.a. regne!�ted dllutians, iwlMASD 1csiguatials, cte,,,j
icurrealy nuscribcd from the COC into d7e eornment foctimi in LIM ?
:J yC5 Nir' 12 lisied on the container 19W? lfwe5, -)uoteAL NA
roplePresstvatiod (Must becomplei,a:1.oranysampte(s)IroneudyprT,ycdorwith hcadsp e_)
5amp[c(s� TyA wemir=Nod in-carrect]y preserverl wi.I wr-r-n adjusted atcordingly
in .%Arnpie t*res:v r a with INA m G of Gircie vrtc: E12SO4, I fNO3, HCI, NaDI4 using SR 4 NA
7'ime ofpmkrvasiott NA Ifinorc thus onr pres}ervativg is needmi, pka3e na'e in tltc oommetsts buknv.
S rrplo(s) NA LL xerereeoivcdwith hii1: ,: 6 men inll=ame�r_
Sarnples(s) NA _ %Vre reet:ived wit),'17iC> J)_5 mgr'i.. (Y919 is an) and we;,
L ustcd accunlinvly in sample receiving wiLh sodium thimilfatc (Ma,;,lam with Reidy ID: NA
SR harcode Ia7eb applied try: 6MG rjyt$; 4310312024
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

SECTION 3

FACILITY NAME: FARMVILLE, NC
LAND OWNER: HAROLD FLANAGAN
OPERATOR: HAROLD FLANAGAN
CROPINAME:BERMUDAGRASS,COASTAL-
DACTI IA lPr'D\
RESIDUAL SOURCE(S): * See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WQ PERMIT #: WQ0008778 FIELD#: NC-PI-00001-0-0001-
ANNUAL DRY TONS APPLIED: 20.69 SITE #: NC PI 00001
PREDOMINANT SOIL SERIES: EXUM
CROP 1 MAX. PAN: 201 CROP 2 NAME:
Page: 1
ACRES UTILIZED: 5.8
ACRES PERMITTED: 11.8
CATION EXCHANGE CAPACITY (NON-503):
CROP 2 MAX. PAN:
Gallons (G)
Site
Name of Crop Type
or Cubic Yards (Y)
Cond.
Precip
Volab- Mineral-
Ammonia Nitrate
PAN Applied
Receiving Residual
Date or
or Wet Tons (W)
%
Residual
Dry, Wet,
Past 24 Hrs.
Application
lization ization
TKN Nitrogen and Nitrite
(Ibs/acre)
Application
Month
Solids Dry Tons/Ac
Source
Moist
Inches
Method*
Rate** Rate***
mg/kg mg/kg mg/kg
Amount
UOM
Crop 1
Crop 2
Crop 1 Crop 2
6/8/2020
124,000.00
(G)
2.760 2.461
FARAEDL
DRY
1'0-<1/2"
SUR
0.5 0.30
43,000.00 1,000.00 70.40
64.814
BCP
6/9/2020
55,800.00
(G)
2.760 1.107
FARAEDL
DRY
"0-<1/2"
SUR
0.5 0.30
43,000.00 1,000.00 70.40
29.166
BCP
Jun-20
179,800.00
(G)
Total 3.668 Total 93.980 0.000
AS CD CU CR PB HG MO NI SE ZN P Lime Applied
Annual Ibs/acre Applied 0.031 0.008 2.355 0.186 0.164 0.005 0.045 0.121 0.041 4.781 114.171 Date Lbs/Ac
Cumulative Ibs/acre ADDlled 0.172 0.131 52,390 3.874 2.306 0.04B 0.625 1.812 0.158 34.055
Permit PAN Limit (Ibs/acre) 1st
(Federal C.P.L.R. (Ibs/acre)**** 36.6 ! 34.8 1 1,339.0 1 16 267.9 1 15.0 1 1 375.0 ( 89.0 1 2,500.0 ! 1 1
FARAEDL = FARMVILLE, NC AEROBICALLY DIGESTED LIQUID
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties f su 'tting f Ise infonnation, including the possibility of fines and imprison gent or knowing violations."
SIGNATUR LAND APPLIER PATE
NR = Not Reported or Not Required — Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4
* Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **** See Site pH & Lime Application Records Section of Report
Printed: 2/1/2021 DENR FORM FSF (12/2006)

FACILITY NAME: FARMVILLE, NC
LANDOWNER: HAROLD FLANAGAN
OPERATOR: HAROLD FLANAGAN
CROP 1 NAME: SOYBEANS (SB)
RESIDUAL SOURCE(S): * See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WQ PERMIT #: W00008778 FIELD#: NC-PI-00001-0-0002-A
ANNUAL DRY TONS APPLIED: 24.26 SITE #: NC PI 00001
PREDOMINANT SOIL SERIES: EXUM
CROP 1 MAX. PAN: 188 CROP 2 NAME:
Page: 1
ACRES UTILIZED: 15.8
ACRES PERMITTED: 15.8
CATION EXCHANGE CAPACITY (NON-503):
CROP 2 MAX. PAN:
Gallons (G)
Site
Name of Crop Type
or Cubic Yards (Y)
Cond.
Precip
Volati- Mineral-
Ammonia
Nitrate
PAN Applied
Receiving Residual
Date or
or Wet Tons (W)
%
Residual
Dry, Wet,
Past 24 Hrs.
Application
lization ization
TKN Nitrogen
and Nitrite
(Ibs/acre)
Application
Month
Solids Dry Tons/Ac
Source
Moist
Inches
Method*
Rate** Rate—
mg/kg mg/kg
mg/kg
Amount
UOM
Crop 1
Crop 2
Crop 1 Crop 2
6/9/2020
111,600.00
(G)
2.760 0.813
FARAEDL
DRY
"0-<1!2"
SUR
0.5 0.30
43,000.00 1,000.00
70.40
21.413
SB
6/10/2020
99,200.00
(G)
2.760 0.723
FARAEDL
DRY
110-<1/2"
SUR
0.5 0.30
43,000.00 1,000.00
70.40
19.034
SB
Jun-20
210,800.00
(G)
Total 1.636 Total 40.447 0.000
AS CD CU GR PB HG MO Ni SE ZN P Lime Applied
Annual Ibs/acre Applied 0.014 1 0.003 1 1.013 1 0.080 1 0.071 0.002 1 0.019 1 0.052 0.018 1 2.058 1 49.137 Date Lbs/Ac
Cumulative Ibs/acre Applied 0.323 0.219 1 87.506 6 7.719 1 3.871 I 0.086 ! 0.745 ! 4.333 I 0.220 I 56.101 { I I I
Permit PAN Limit (Ibs/acre) 1st Crop I 9 1 I I 6 ( i 188 1 R
Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1 1,339.0 267.9 15.0 375.0 89.0 1 2,50,
FARAEDL= FARMVILLE, NC AEROBICALLY DIGESTED LIQUID
"I certify, under penalty of law, that this document was repared under my direction or supervision in accordance with a sys em designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties f mittin false information, including the possibility of fines and imprisagnmyt fo knowing violations."
G !
SIGNATU E F LAND APPLIER I D E
NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4
* Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report
Printed: 2/1/2021 DENR FORM FSF (12/2006)

FACILITY NAME: FARMVILLE, NC
LANDOWNER: HAROLD FLANAGAN
OPERATOR: HAROLD FLANAGAN
CROP 1NAME: BERMUDAGRASS,COMMON -
DACTI Mr lPf r)P\
RESIDUAL SOURCE(S): * See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
WQ PERMIT #: WQ0008778 FIELD#: NC-PI-00001-0-0006-
ANNUAL DRY TONS APPLIED: 14.07 SITE* NC PI 00001
PREDOMINANT SOIL SERIES: GOLDSBORO
CROP 1 MAX. PAN: 172 CROP 2 NAME:
Page: 1
ACRES UTILIZED: 32.7
ACRES PERMITTED: 32.7
CATION EXCHANGE CAPACITY (NON-503):
CROP 2 MAX. PAN:
Gallons (G)
Site
Name of Crop Type
or Cubic Yards (Y)
Cond.
Precip
Volati-
Mineral-
Ammonia
Nitrate
PAN Applied Receiving Residual
Date or
or Wet Tons (W)
%
Residual Dry, Wet,
Past 24 Hrs.
Application
lization
ization
TKN
Nitrogen
and Nitrite
(Ibs/acre) Application
Month
Solids
Dry Tons/Ac
Source Moist
Inches
Method*
Rate**
Rate***
mg/kg
mg/kg
mg/kg
Amount UOM
Crop 1
Crop 2 Crop 1 Crop 2
1/23/2020
93,000.00 (G)
1.600
0.190
FARAEDL DRY
110-<1/2"
SUR
0.5
0.30
69,400.00
16,300.00
616.00
9.372
BCOP
1/24/2020
117,800.00 (G)
1.600
0.240
FARAEDL DRY
110-<1/2"
SUR
0.5
0.30
69,400.00
16,300.00
616.00
11.872
BCOP
Jan-20
210,800.00 (G)
Total 0.430 Total 21.244 0.000
AS CD CU CR PB HG MO NI SE ZN P Lime Applied
�Annuaflbs/acre Applied 0.004 0.001 0.315 1 0.030 1 0.021 <0.001 1 0,005 1 0.019 0.004 1 0.707 19.613 Date Lbs/Ac
0.020 1 0.007 1 1.678 E 0.185 1 0.110 1 0.002 E 0.025 1 0.105 9 0.022 1 3.136
Permit PAN Limit (Ibs/acre) 1 st Crop 11Z
Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0
FARAEDL = FARMVILLE, NC AEROBICALLY DIGESTED LIQUID
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant pen att fo su ling false information, including the possibility of fines and impriso ent r knowing violations."
Z 15 Z-
SIGN T RE OF LAND APPLIER I qATE
NR = Not Reported or Not Requ d *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4
* Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate
** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report
Printed: 2/1/2021 DENR FORM FSF (12/2006)

SECTION 4

0p
0
PaceAnalyfical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Nate Roth
Project Name: Farmville
Lot Number:VC03017
Date Completed:03/18/2020
MIM�� Mr�
03/18/2020 2:19 PM
Approved and released by:
Lab Director - Greenville: Lucas Odom
Q PCCRBp��
AAW
'ye I
ANSI NdmlAccre00- Board
eORft
Al
A C C R E D I T E D
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: VC03017
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance
Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to
the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W'
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Metals by ICP
Due to low percent solids, sample -001 was weighed out at 3 times the normal weight. The LOQ has been
elevated to reflect the dilution.
Paint Filter
This analysis has been qualified with an "H", however, there is not a method defined hold time for this
analysis.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received: 03/03/2020
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
(% Solids) SM 2540G
1
03/03/2020 2237 MDD
46788
1
(Ignitability) 1010A
1
03/09/2020 1348 SLC
47298
1
(Paint Filter) 9095B
1
03/10/2020 1443 SLC
1
(Reactive Cya) 7.3.3
1
03/10/2020 0000 KFE 03/10/2020 1046
1
(Reactive Sul) 7.3.4
1
03/10/2020 1925 HET 03/10/2020 1046
1
(Soil pH meas) 9045D
1
03/05/2020 2159 SRB
47065
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
1.65
%
1
Ignitability (Pensky-Martens Closed -Cup)
1010A
>140
140
0
o F
1
Paint Filter Test
9095B
Fail H"
pass/fail
1
Reactive Cyanide
7.3.3
ND
50
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
50
mg/kg
1
Soil pH measured in water @ 21 ° C
9045D
6.1
su
1
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/5030B 8260D
10 03/13/2020 0350 JTH
47756
03/11/2020 2110
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Benzene
71-43-2 8260D
ND
0.050
0.0040
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
0.020
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
0.0040
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
0.0040
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
0.0040
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
0.0040
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
0.0040
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
0.0040
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
0.0040
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
0.0040
mg/L
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Bromofluorobenzene
100 70-130
1,2-Dichloroethane-d4
97 70-130
Toluene-d8
105 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 03/12/2020 1340 SCD 03/10/2020 1710
47402 03/08/2020 2357
CAS Analytical
Parameter
Number Method Result Q
LOQ DL Units Run
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL
= Detection Limit
ND = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J =
Estimated result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3of10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received:03/03/2020
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8270E
1 03/12/2020 1340 SCD
03/10/2020 1710 47402
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
0.0050
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
0.0050
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
0.0050
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
0.0050
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
0.010
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
0.010
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
0.015
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
0.015
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
0.020
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
0.0050
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
0.0050
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
67 37-129
2-Fluorophenol
37 24-127
Nitrobenzene-d5
68 38-127
Phenol-d5
61 28-128
Terphenyl-d 14
83 10-148
2,4,6-Tribromophenol
72 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/8151A
8151A
1 03/16/2020 1738 JJG
03/12/2020 1747 47726
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
0.0050
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
0.0013
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
70 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8081B
1 03/13/20201519 DAL1
03/11/20201452 47527
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
gamma-BHC (Lindane)
58-89-9 8081B
ND
0.00040
0.00017
mg/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
ND = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result
< LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Client:Synagro Laboratory ID:VC03017-001
Description: FV20 Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 1.65 03/03/2020 2237
Date Received:03/03/2020
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8081B
1 03/13/20201519 DAL1
03/11/20201452
47527
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Chlordane
57-74-9 8081B
ND
0.0040
0.0015
mg/L
1
Endrin
72-20-8 8081B
ND
0.00040
0.00015
mg/L
1
Heptachlor
76-44-8 8081B
ND
0.00040
0.00015
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND
0.00040
0.00016
mg/L
1
Methoxychlor
72-43-5 8081B
ND
0.0016
0.00021
mg/L
1
Toxaphene
8001-35-2 8081B
ND
0.0080
0.0030
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
84 20-131
Tetrachloro-m-xylene
86 26-132
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3010A
6010D
1 03/10/2020 0412 LLL
03/09/2020 2018 47306
03/08/2020 2357
1 1311/7470A
7470A
1 03/10/2020 1512 KSH2
03/10/2020 0941 47316
03/08/2020 2357
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Arsenic
7440-38-2 6010D
ND
0.15
0.025
mg/L
1
Barium
7440-39-3 6010D
0.35
0.25
0.031
mg/L
1
Cadmium
7440-43-9 6010D
ND
0.050
0.0060
mg/L
1
Chromium
7440-47-3 6010D
ND
0.10
0.013
mg/L
1
Lead
7439-92-1 6010D
ND
0.10
0.047
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
0.00091
mg/L
1
Selenium
7782-49-2 6010D
ND
0.20
0.085
mg/L
1
Silver
7440-22-4 6010D
ND
0.10
0.021
mg/L
1
Footnote(s): 'Paint Filter: 40mL collected;
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 10

Client:Synagro Laboratory ID:VC03017-002
Description: FV Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 2.76 03/03/2020 2237
Date Received: 03/03/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 03/03/2020 2237 MDD
46788
1 350.1
(Ammonia - N ) 350.1
1 03/09/2020 1406 SLC
46871
2
(Nitrate - N ) 9056A
1 03/17/2020 1156 AMR
48204
1
(Nitrite - N ) 9056A
1 03/11/2020 1643 AMR
47697
1
(Phosphorus) 365.1
10 03/06/2020 1343 DMA
03/06/2020 0937
47087
1
(Soil pH meas) 9045D
1 03/05/2020 2201 SRB
47065
1 351.4
(TKN) 351.2
1 03/04/2020 1544 DMA
03/04/2020 1002
46808
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
2.76
%
1
Ammonia - N (gas diffusion)
350.1
1000
36
19
mg/kg
1
Nitrate - N (soluble)
9056A
65
18
0.89
mg/kg
2
Nitrite - N (soluble)
9056A
5.4 J
7.2
0.69
mg/kg
1
Phosphorus
7723-14-0 365.1
16000
1800
360
mg/kg
1
Soil pH measured in water @
21 ° C
9045D
6.2
su
1
TKN
351.2
43000
900
900
mg/kg
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 03/04/2020 1630 KSH2
03/04/2020 1230
46714
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7471B
ND
2.7
0.66
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 03/09/2020 1918 LLL
03/06/2020 1452
46709
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6010D
10000
240
89
mg/kg
1
Arsenic
7440-38-2 6010D
4.4 J
8.9
3.0
mg/kg
1
Cadmium
7440-43-9 6010D
1.1 J
3.0
0.75
mg/kg
1
Calcium
7440-70-2 6010D
8900
3000
370
mg/kg
1
Chromium
7440-47-3 6010D
26
5.9
1.5
mg/kg
1
Copper
7440-50-8 6010D
330
5.9
2.7
mg/kg
1
Iron
7439-89-6 6010D
22000
59
27
mg/kg
1
Lead
7439-92-1 6010D
23
5.9
2.7
mg/kg
1
Magnesium
7439-95-4 6010D
2500 J
3000
370
mg/kg
1
Manganese
7439-96-5 6010D
290
8.9
3.5
mg/kg
1
Molybdenum
7439-98-7 6010D
6.3 J
24
5.9
mg/kg
1
Nickel
7440-02-0 6010D
17 J
24
6.2
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 10

Client:Synagro Laboratory ID:VC03017-002
Description: FV Matrix: Solid
Date Sampled:02/27/2020 1000 % Solids: 2.76 03/03/2020 2237
Date Received:03/03/2020
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
6010D 1 03/09/2020 1918 LLL
03/06/2020 1452
46709
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Potassium
7440-09-7 6010D
4000
3000
370
mg/kg
1
Selenium
7782-49-2 6010D
5.8 J
12
4.8
mg/kg
1
Sodium
7440-23-5 6010D
1600 J
3000
370
mg/kg
1
Zinc
7440-66-6 6010D
670
30
7.4
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES. LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES, LLC
Shmry rrl'iwi nOurul 3ta ;m, Inc. '
EotumcmNL,lNcr:_41�3+xr:tiL'-ta �iT:���,:•:�� r:e:^�6,7:�]:�
Sample Receipt Checklist (SRQ
C-liett[' Sy:tagro — T Cooler inspeeLed by/date: l3mG J DM3.2021) Lot i1: VC43417
McattsoUTctcipt; 0 SESL ©{;[iCnt UPS ® 1FedEx O1hcr. _
d Yes 91 NQL. I. Were cusi seals presets' cc tlu; eooIV,
�'fcs hia NA 2_ If c u sr0dy seaL� wrrL M. ,grmt, were tlsey intact and unbroken"
-ip 10: T*iA Chlorttle Strip ID, CIA Tested by- NA
Jri-Mir7al tcrnuetature up vn rcccipt J3erived (COTm 4 tenLiler4urti upon moeiirt Solid soap -dap IJ�: i9-2:,1 #
-4.f. i4.2 flC NA iNA °C NA O'JN4 hC NA 4NA d{;
ja tBotles 11Z Gun ID: TR - Gun Gormcdcn Faz;wr; 10 °C
�+Tetlirxl; W`1'c3m[1ei'aturcT )auk ❑A
Method of molant; 0 duet Ice Elft,,: Packs ❑ Icn t] None-
0 — -' -
❑ Y �a No 0NA 3- if tempomfure of any roofer Lnxeedej 6,01C, was Project Managar Nat'sfieri?
1 M �•a3 Notified :)y_ pltae l email i %oe-Waec keirrJ,e one).
Yes 0 h'o ❑NA 4, is fl c comrrercial COuricCS packin .G] ip aMehed to psis farm?
Yes 0 No 3, ct+c rcrper rustodv i octxtunm (L-ulinquisltad�r eived) followed?
2 't' �s Nrr 6_ Wrrn sample IDs I:sLrA an the COC? -
Yee ❑ N
Yeg ❑ N
7, Wury sample [Ds I:sted on all sirtplC conlaincry
ll_ Was collection &rav k. Lim listed an tlra COC? -
9- Was collective date & tims ]iMd on aJl salnple untainurs?
10. Did all container Calm-1 icifurrnation 01133 dins rime) agree With thr.
11. We,- LrAs Lo be nerfi)rned listed on the COO?
�,rs ❑ No 1
12. Did all samplcs arrive in Ow prtaper cnaM1ners For each test EuILUor in good condition
tunbrvlwn, lids on, etc.r
V1 PF ❑ No
=eso
_ Y -S 1- a
EJ Yes ❑ bTv
t—r Ycx L.-7N-
[] Yes, ❑ No
❑ ZI r No
i3. Was Nkqualc %irnpic +roluule avdi'.eblt;? -
14_VIW8ft all samplesre�ct�%dwith'n'rzlheholdingtifitaor ShoL.es_whichevr.Tcoiuesfuse
15_ W= arry ssrtLp]es Crrnlzij)= miss iu }+excess (rimte ojie) 9araples Not lisit:d un CUU?
NA J6. For VOA and UK-1 ;5 sampl er., wcire bubbles preskl3t >-pea-qi;,, " ('la"ar Gtnrn in diarnaLcr)
it nny of ]te VOA vial3i
14 NA 17, Wvm ail DROr me4Lls nutrient :, mlcs rccri-vcd Es a pH of < 2? —
VJ NA 18. Wore a]I cyanide samples rereiwii ut a plI > 12 and s11[fide 3arnrc=ived at a pH > 99
®h A 19_ WC re 0111 HPPJ Lcablc N.l�,(l K llcyan ifller'pMti 62_S (< 0_.5mgiQ samples rep ofresidual
❑ Yes CJ No '20. Were ell ienLrcninrksdrequests [.a. regne!�ted dllutians, iwlMASD 1csiguatials, cte,,,j
icurrealy nuscribcd from the COC into d7e eornment foctimi in LIM ?
:J yC5 Nir' 12 lisied on the container 19W? lfwe5, -)uoteAL NA
roplePresstvatiod (Must becomplei,a:1.oranysampte(s)IroneudyprT,ycdorwith hcadsp e_)
5amp[c(s� TyA wemir=Nod in-carrect]y preserverl wi.I wr-r-n adjusted atcordingly
in .%Arnpie t*res:v r a with INA m G of Gircie vrtc: E12SO4, I fNO3, HCI, NaDI4 using SR 4 NA
7'ime ofpmkrvasiott NA Ifinorc thus onr pres}ervativg is needmi, pka3e na'e in tltc oommetsts buknv.
S rrplo(s) NA LL xerereeoivcdwith hii1: ,: 6 men inll=ame�r_
Sarnples(s) NA _ %Vre reet:ived wit),'17iC> J)_5 mgr'i.. (Y919 is an) and we;,
L ustcd accunlinvly in sample receiving wiLh sodium thimilfatc (Ma,;,lam with Reidy ID: NA
SR harcode Ia7eb applied try: 6MG rjyt$; 4310312024
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

SECTION 5

Facility Name:
WWTP Name:
ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Town of Farmville
Town of Farmville WWTP
Monitoring Period: From 01/01/20
r Basin
To 12/31/20
WQ Permit Number: WQ0008778
NPDES Number: NCO029572
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 2/I3 (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying Composting Aerobic Digestion
Anaerobic Digestion
Tf --- 1 —hla to alternation nerfnrmed tclace A nr C lnee Rl rmmnlete the fnlinwino mnnitarino data:
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
dences
Analysis
Fecal
2x10to the 6t'
MPN
MPN/g
Coliform
power per gram
of total solids
<40200
44900
81200
CFU/g
0
Annually
Grab
SM9222D
CFU
1000 MPN per gram of
MPN/g
total solids (dreight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed:
Option/Alt. 1
Option/Alt. 2
Option/Alt. 3 Option/Alt. 4
(VS reduction)
(40-day bench)
(30-day bench) X (Spec. 02 uptake)
Option/Alt. 5
Option/Alt. 6
Option/Alt. 7 Option/Alt. 8
(14-Day Aerobic)
(Alk Stabilization)
(Drying — Stable) (Drying — Unstable)
Option/Alt. 9
Option/Alt. 10
(Injection)
(Incorporation)
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
been met. I am aware that there are significant penalties for false certification including fine and imprisonment."
David Hodgkins Town Manager
Preparer r
e d Titlei(iy or print)
R
Sign tore of Preparer* Date
Land Applier Name and Title (if applicable) (type or print)
Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Cameron Testing Services, Inc. Laboratory Report
NC DENR #W
NC PHHS #37799
W EPAMC01918
Client:
Synagro CTS Prof. 2002-106
Project.,
Farmvilte WWTP Regulatory
Yet,
Sample Information
Sampled
Pub Y.1
Date 02112120 Received
E. Puckett Data
02112120
Analyses and Results
- Lab 10
"rapto to
Anslyto Rosult
ttly
SM Matho4s
0
Reference
2002-106 1
FV1
aludoc ck FColiform-S 81200
cPvt 40600
02/1 =0 RL
92220 - MF
2
FV2
<40800
crwg 40111O
3
FV3
<40200
cfutj; 40200
4
FV4
<40800
CFU4 40800
5
FV5
<40700
CFU1q 40700
6
FV6
<40800
C" 40800
7
FV7
<40700
rFu,,,% 40700
Goo mean 44WO
2002-106 1
FV1
UAV Gt Ts N Z47%
% 00'
02112/2D RL
2540 0 JS
2
FV2
Z45%
% oot
3
FV3
2.49%
% 0.01
4
FV4
2,46%
% o-et
5
FV5
2.46%
'A oot
6
FV6
Z45%
00i
7
FV7
2,46%
00t
Report f
Review 4=41e
bits
219 S Swck Sir. 919-2M-4240
Sanford NC 27330 ChriseLoanwontes t ingsom

Ssnfard,14C 27330
phor 5bt-�,i 4C, (aaV C��;, NCPH*iS Cvri 1'h'$ �,"
.... .. ,.. ....
€�A t��:i�ir � � ..�.". ,�...».�.�.
yii
' ..
C
�*
a.
Sample Tefty
1c) R p 2
Add t, Boger R
FAX
t
Mocksville, NC 27028
"y Nj
ct, t c
Pulb (YIN) Olt*
i Vanv di
x ri tar#"
at baftses
Requested Amlysis
? 912
yet
ID
sample ID
-
P3
ri ua
Ike +fix), WKWOW
TVT
Rush wowill require picot approval Additional cbarqes will a

Sample Preservation
Chock -In Sheet
Project # _
Date;
Checked In By:
Temp 4.7 oC Time:
Route:
I'},
TS
Sampled
CTS
Pickup
USM
Fedex
General
Courier
UPS
Sample
No
Analysis
Requested
Matrix
Comp/
Grab
Container
Preservative
None
None
HCL
HCL
H2SO4
H2SO4
HNO3
T-TNO3
NaOH
NaOFT
Thio
Thio
Other
d
C f
G
Other
C /
,P
/ G
Na a
HCL
H2SO4
HNO3
NaOTI
Thin
Other
C /
P
/ G
N e
HCL
H2SO4
HI;I03
hFaOH
Thin
Other
Nana
FTCL
H2SO4
11NO3
Naotl
Thin
Other
C i
/ G
one
HCL
132SO4
HNO3
NaOH
Thio
Other
C %
/ G
one
HCL
H2SO4
HNO3
NaOH
Thin
Other
G
ne
HCL
t i2SO4
HNO3
NaOH
Thio
Other
C / G
P / G
None
HCL
H2SO4
HNO3
NaOH
Thio
Other
C / G
P / G
None
HCL
H2SG4
HNO3
NaQH
TWO
Other
C / G
P / G
None
HCL
H2SO4
HNO3
NaOH
Thio
Other
C / G
P / G
None
HCL
H2SO4
HNO3
NaOH
Thio
Other
C / G
P l G
None
HCL
H2SO4
HNO3
Na014
Thin
Other
C / G
P / G
None
HCL
H2SO4
HNO3
NaOH
Thio
Other
C / G
P / G
Nane
HCL
H2SO4
HNO3
Na0t3
Thio
Other
C / G
P / G
None
HCWH2S0411NO3
NaOFT
Thio
Other
C / G
P / \3
Nane
HC
NaOH
Thio
Other
C / G
P / G
None
HCL
NaOH
Thio
otherC/G
P/G
Nona
HCL
NaOH
Thio
Other
COMWENTS:

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Ryan Copeland Report Date: 4/22/2020
Client: Synagro
284 Boger Road Project: Farmville WWTP
Mocksville, NC 27028 Date Sample Rcvd: 3/19/2020
Vector Attraction Reduction / Aerobically Digested Sludge 30 Day Test
Meritech Work Order # 03192035 Sample: Farmville WWTP Composite 3/19/20
Total Solids Volatile Solids % Volatile Solids
Week 1 0.910 0.660 0.726
Week 2
0.790
0.590
0.754
Week 3
0.740
0.560
0.749
Week 4
0.700
0.490
0.697
Week 5
0.540
0.390
0.718
Van Kleeck Reduction (%): 4.11
I hereby certify that I have reviewed and approve these data. Ama u a Trw )
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

8/9n8 Chain of Custody Record (COC)
NPDES#:
Client: 5a Phone:. ��_,��� Yv3-Y3Z4
Address: Fax:
Email: Yu F) s'��lo ,4r-0 �.
Project:
P.O.#:
Turn Around Time*
Attention: /moo;
*RUSH work needs prior approval,
How would you like your report sent? Char es ADDIV
Circle all that a I Email(pre d), Fax, Mail Std 1 a s) 3-5 Da s 2�rs
pp Y' ❑J
MERITECH INC.
ti ENVIRONMENTAL LABORATORIES
i 642 Tamco Rd. Phone: [phone]
• Reidsville NC 27320 Fax: [phone]
Email: [e-mail]
www.meritechlabs.com
Sample Location and/or ID #
Sampling Dates & Times
Person Taking Sample (Sign/Print):
Lab Use Only
Start
End
Comp?
Grab?
#of
Cont,
Test(s) Required
Yeflee?
s No
pH OK?
CI OK?
Date
Time
Date
Time
L11 I -
Temperature Upon
Receipt: - \& C.
S.J
Method of
Shipment:
*** Dechlorination
(<0.5 p m) of Ammonia, Cyanide, Phenol and TKN samples must be done in the field prior to preservation.
Comments:
�ZrF<�'r� • "'
Com p ositor#
Ll UPS
Jug #
❑ Fed Ex
Are these results for regulatory purposes? Yes No ❑
Report results in: mg/L ❑ mg/kg ❑ ug/L ❑
and Delivery
d b .
RelinquisheDate: Time:
1 3 z J
Received by: Date: Time:
❑, Other
Relinquished by: Date: Time:
Received by: Date: Time:
.t
Relinquished by: Date: Time:
R ed by Lab:
C�

SECTION 6

Agricultural Lime Application Log
2020
Farmville, NC
Field
(state -county -site -field)
Soil
pH
Lime Requirement
(tons/acre)
Tons/Acre
Applied
Date Applied
NC-PI-1-1
6.1
0.0
0.0
NC-PI-1-2A
5.8
0.3
0.0
NC-PI-1-6
6.1
0.0
0.0
Lime application will proceed when field conditions improve*

SECTION 7

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY20-SL031967
�5{i �141..tiL
Client:
Harold Flanigan
Advisor: Chris Wynne
Predictive
3625 Arch Flanigan Rd / 200 Arch
483 Bogar Road
;•
Flanigan Rd
Mocksville, NC 27028
$. Soil Report Mehlich-3 Extraction
}
Farmville, NC27828
Links to Helpful Information
Sampled County : Pitt
Client ID: 418924
Advisor ID: 509090
Sampled: 06/04/2020 Received: 06/09/2020 Completed: 06/16/2020 Farm: PI-01
Sample ID: 1
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1-Bermuda hay/past., E 0.0 60-80 0
30
0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg%
S-1
Mn-I
Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS -I NO3-N
0.41 1.10 8.4 87 1.1 6.1 508 59 72 11
35
55
49 1126 1126
470 0.1 1
Sample ID: 2A
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1-Soybean 0.3 0 0
40
0 0 0 0
0 0
Note: 3
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg%
S-1
Mn-I
Mn-All Mn-AI2 Zn-I Zn-AI
Cu-I Na ESP SS -I NO3-N
0.71 1.28 6.9 82 1.3 5.8 424 49 70 8
37
45
37 355 355
365 0.1 1
Noah Carolina
i�
Futaw frum Fund Ciwn1nl55km
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Aqriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY20-SLO31967
Harold Flanigan
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS%
% CEC occupied by basic cations
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg%
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
only on reports for greenhouse soil or problem samples.
Mn-All
Mn-availability index for crop 1
Mn-Al2
Mn-availability index for crop 2
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
Mn-
mineral -organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagr.gov/agronomi/pubs.htm.
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
P205
phosphate
S-1
sulfur index
Test Results
SS-1
soluble salt index
W/V
weight per volume
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-AI
zinc availability index
Zn-1
zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel
available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY21-SL013100
�5{i �141..tiL
Client: Harold Flanagan
Advisor: Chris Wynne
Predictive
3625 Arch Flanagan Rd
Synagro LLC
;•
Farmville, NC 27828
284 Boger Road
+_ Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County: Pitt
Links to Helpful Information
Client ID: 463740
Advisor ID: 509090
Sampled: 11/05/2020 Received: 11/09/2020 Completed: 12/01/2020 Farm: PI-1
Sample ID: 6
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O Mg S Mn Zn
Cu B
Information
Lime History:
1-Bermuda hay/past., M 0.0 180-220 0
50 0 0 0 0
0 0
Note: 12
2 - 0.0
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS -I NO3-N
1.61 1.17 11.8 86 1.6 6.1 419 85 63 19
77 68 56 1475 1475
329 0.1 1
Noah Carolina
i�
Futaw frum Fund Ciwn1nl55km
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Aqriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY21-SLO13100
Harold Flanagan
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS%
% CEC occupied by basic cations
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu-I
copper index
ESP
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg%
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
manganese
only on reports for greenhouse soil or problem samples.
Mn-All
Mn-availability index for crop 1
Mn-Al2
Mn-availability index for crop 2
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
Mn-
mineral -organic soil class
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagr.gov/agronomi/pubs.htm.
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that
P-1
phosphorus index
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
P205
phosphate
S-1
sulfur index
Test Results
SS-1
soluble salt index
W/V
weight per volume
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-AI
zinc availability index
Zn-1
zinc index
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel
available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm