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WQ0001800_Residual Annual Report 2020_20210222
Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0001800 Applicant/Permittee Town of Yadkinville Email Notifications Does this need review by the hydrogeologist?* 0 Yes r No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* WQ0001800 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * Town of Yadkinville RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for Town of Yadkinville NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Rans, Specifications, Calculations, Bc.) Yadkinville NC 2020 Annual Report FINAL.pdf 7.6MB Upload only 1 RCFdocurrent (less than 2501v8). Miltiple docurrents rust be confined into one RJFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/22/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 22, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0001800 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Yadkinville, NC. If you have any questions or need additional information, please do not hesitate to contact Perry Williams at (336) 679-8732 or Alex Fox at (336) 703-8681. Sincerely, oe"i& Shuuc" ,es Derrick Shivar Environmental Compliance Manager Enclosures cc: Perry Williams — Town of Yadkinville Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF YADKINVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0001800 2020 ANNUAL REPORT Town of Yadkinville, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms & Metal Field Loading Summary Forms 4. TCLP Analyses 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION! CERTIFICATION FORM WQPerrnitif: W00001800 County Yadkin Year2020 Facility Name (as shown on permit) Town ofYadkinville WWTP & WTP NPDES No. NC0020338,44e667� i7eIt Land Application Operator Svnauo Phone# (3361999-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES ^NO. 1f NO, skip Part A, and Part B and proceed to Pait C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary Total number of application fields in the permit: l9 Total number of fields utilized for land application during the year: 5 Total amount of dry tons applied during the year for all application sites: 117.51 Total number of acres utilized for land application during the year: 46.2 Part B—Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. l . Only residuals approved for this permit were applied to the permitted sites. 2. Soil p1-1 was adjusted as specified in the permit and time was applied (if needed) to achieve a soil pH of at least 6.0 or the litnit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T . i 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the T.and Application Permit were complied with (applicable to 40 Cl7R Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. It. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C —Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Jacob Swaim Director of Public Works Pen ee Name and Title (type or print) Si a f Permittee Bat Signature ofPreparer* Date Signature of LandApplier Bate (if different from Pennittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T . t 102 (26) DBNR FORM A.CF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 YADKINVILLE, NC YADKINVILLE, NC WWTP LIQUID MONTH/YEAR May 2020 June 2020 November 2020 TOTAL YADKINVILLE, NC WTP LIQUID AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 204,000.00 G 13.44 D 12.19 180,000.00 G 11.86 D 10.76 204,600.00 G 13.48 D 12.23 588,600.00 G 38.78 D 35.17 MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS January 2020 63,000.00 G 16.29 D 14.77 April 2020 31,500.00 G 8.14 D 7.39 May 2020 24,500.00 G 6.33 D 5.75 July 2020 56,000.00 G 14.48 D 13.13 September 2020 45,500.00 G 11.76 D 10.67 November 2020 84,000.00 G 21.72 D 19.70 TOTAL 304,500.00 G 78.73 D 71.40 Report Date: 2/7/2021 4:24:52 PM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00001800 Laboratory: Facility Name: YADKINVILLE, NC PACE ANALYTICAL Residual Source WO # or NPDES#: NCO020338 WWTP Name: YA€]KINVILLE WWTP Residual Analysis Data Product Type Sample or Composite Date LIQ 03/10/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 1.58 Arsenic 75 6.1 Cadmium 85 1.3 Copper 4300 670 Chromium NA 61 Lead 840 29 Mercury 57 3.1 Molybdenum 75 <10 Nickel 420 59 Selenium 100 <8.5 Zinc 7600 2300 Total Phosphorus NA 32000 TKN NA 63000 Ammonia -Nitrogen NA 7200 Nitrate and Nitrite NA 97.2 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. 9 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the Information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer" Bate "Preparer is defined In 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (1212006) Printed: 2/7/2021 4:43:40 PM For. 2056 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WO Permit Number: WQ0001800 Laboratory: Facility Name: YADKINVILLE, NC PACE ANALYTICAL Residual Source NPDES # or WQ#: NCO020338 WWTP Name: YADKINVILLE WWTP Residual Analysis Data Product Type LIQ Sample or Composite Date 03/10/20 Parameters (mg/kg dry weight) Aluminium 51000 Calcium 14000 Magnesium 3500 pH (s.u,) 7.30 Potassium 4800 Sodium 5200 PAN 20437 SAR (Ratio) 1.2763 " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assura that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are s'sgnifcant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer' Date 'Preparer is defined in 40 CFR Past 503.9(r) and 15 A NCAC 2T.1102(2fi) Printed: 2a/2021 4.40:56 PM For. 2056 01 DENR FORM RSSF-B (1212006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Yadkinville VWVFP Lot Number:VC11049 Date Completed:03/18/2020 NIM�� Mr� 03/20/2020 11:07 AM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VC11049 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids sample -001 was weighed out at 3 times the normal weight. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VC11049-001 Description: Yadkinville WWTP Matrix: Solid Date Sampled:03/10/2020 1145 % Solids: 1.58 03/11/2020 2312 Date Received: 03/11/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 03/11/2020 2312 MDD 47600 1 350.1 (Ammonia - N ) 350.1 5 03/17/2020 1527 DRD 48003 1 (Nitrate - N ) 9056A 1 03/17/2020 1428 AMR 48204 1 (Nitrite - N ) 9056A 1 03/17/2020 1428 AMR 48208 1 (Phosphorus) 365.1 25 03/17/2020 1528 DMA 03/17/2020 1050 48045 1 (Soil pH meas) 9045D 1 03/11/2020 2343 SRB 47607 1 351.4 (TKN) 351.2 1 03/13/2020 1313 MSG 03/12/2020 1158 47641 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 1.58 % 1 Ammonia - N (gas diffusion) 350.1 7200 320 160 mg/kg 1 Nitrate - N (soluble) 9056A 89 32 1.6 mg/kg 1 Nitrite - N (soluble) 9056A 8.2 J 13 1.2 mg/kg 1 Phosphorus 7723-14-0 365.1 32000 7900 1600 mg/kg 1 Soil pH measured in water @ 21.6 o C 9045D 7.3 su 1 TKN 351.2 63000 1600 1600 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 03/17/2020 1005 JMH 03/16/2020 1904 47825 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B 3.1 J 5.0 1.2 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 03/14/2020 1202 KSH2 03/12/2020 1558 47692 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 51000 420 160 mg/kg 1 Arsenic 7440-38-2 6010D 6.1 J 16 5.2 mg/kg 1 Cadmium 7440-43-9 6010D 1.3 J 5.2 1.3 mg/kg 1 Calcium 7440-70-2 6010D 14000 5200 660 mg/kg 1 Chromium 7440-47-3 6010D 61 10 2.6 mg/kg 1 Copper 7440-50-8 6010D 670 10 4.7 mg/kg 1 Iron 7439-89-6 6010D 25000 100 48 mg/kg 1 Lead 7439-92-1 6010D 29 10 4.7 mg/kg 1 Magnesium 7439-95-4 6010D 3500 J 5200 660 mg/kg 1 Manganese 7439-96-5 6010D 4800 16 6.2 mg/kg 1 Molybdenum 7439-98-7 6010D ND 42 10 mg/kg 1 Nickel 7440-02-0 6010D 59 42 11 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VC11049-001 Description: Yadkinville WWTP Matrix: Solid Date Sampled:03/10/2020 1145 % Solids: 1.58 03/11/2020 2312 Date Received:03/11/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 03/14/2020 1202 KSH2 03/12/2020 1558 47692 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 4800 J 5200 660 mg/kg 1 Selenium 7782-49-2 6010D ND 21 8.5 mg/kg 1 Sodium 7440-23-5 6010D 5200 5200 660 mg/kg 1 Zinc 7440-66-6 6010D 2300 52 13 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC zfr v E IF � 1= � F H � t:_ L5 .j f: h ti� ❑ C m rt � a i I I .� Ell 5 m - - LJ to' Yb d} C`J ad i3 m � 1 z n i� ❑ � 0�} � C G} � r" r" I�1I C c m r Ql o a W L I � x a SOh # L 74 o SC7fl Z i `a/ E 0 yS T kTIU6i I N 6l]aflN a E � BUuon=v c of B R ?J }5 �e to ❑ Lr " L B r 4 +4] ❑ Al Tip I © $ a 4 1 $ k CC CC Y {} {] 0. ti T Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC skeely Cnrinxm=lai Servlcm in[- Page i o I Qcemmx�t'�wntse,- MGC013ti-.@ Owe dY11if}18 Sample Receipt Checklist (SRC) C K"rit: Sync CoaJer lm,;ue -tcd Ir•ldutc::'W- 1 DM IMM Lor Pr: VC1 1049 Ivl�nsareeipt; SpS[ € Jient ®UPS =] =edEX 011arer: ❑ Ye_fi No 1. Were onsiody 5=6 -piLscnl on the cooler? EI 'e M D NA1 7. 1 Otrst4 r&aL,%y mmint. ' era d)re i lA2a .end uabrok 1i? aH Strip ID' NA ChIt)r:rrC Snit 10: 1tiA Toswd by; NA Original rem pe-ature i_pnn m-cmipe i Derived (Corrcctcd) 1 mperanre upon receipt %Solid Snap -Cup ID: 19- 231311 � 5.7 a 5.7 oC NA r'1~A �C NA INA -C irk NA eC M zrhod- ❑ Tmpumare Blank io A rrpiii~t 3otrles IR Gun LD; IR Ciun Correctio:r Factor- 0 °C Mz:ffiod of e0c31anr ❑ Wet R❑ Ice Packs ❑ Dry I" ❑ None — © Yes ❑ Tea m NA 3. Ifrcmperature of any cooler excee�l�(b,0°G, was :'inject Managw Nora iFied? PM was NctifeA by. phom l email f thcL 1e�bu a (cirrJe one). Yes ❑ No n Tti.� d, 15 lie L�oriiulercia] ccttlrie�s 3tkietio slip attached to i$iN fpr-n'? Yca ❑ 7tio 5- Wine pro')eT euslody praccdlmes ire1ingt3iAFtd}rcceiwedl foil ovM11? ® Yes ON 6- wcru s mPk IDS Iis ul an the COC? V1 Yes 0 No 7- Werr. Rffple IDS 1iKed im srll sritn Je containem? Yes ❑ No 8- V4WEo collection date & tirnr listed on Cie DOC? 9. MIrus Lm lectiar- data °e thm ] isfed oil all sarrtplc sxmWners4 - y0o5 ® No - 0 YG-ml ❑ No 10- i)id all container label information (ID, d=, time) Kjee with rtre C? 0 Yr-ij 0 No I L bi um ks-is _tobepeMi.,mcd listed on dit: COC: ,i,e- 0 No 13- Did all t,rnlrl s an'=ve in Hit prep.-r coctainem fir e0.01-r test audlor in goad conditim (unbr ton, lids on, ere-)? Yes Q Nc, 13. Vdas adequate 94MPIC vot4ine availabb? 'es =No 14. sainoles rcccivcd withari A the lioldi!ig Linct vr48 hours, �-4hichev" G*rn s first? 15. r!r6 auy samples cantalllers miss_.; r'"veas {circle one) Sam ]95 Not Ji ted on C ? 't'eS No Ll Ycs ❑ No 1Z NA 16' For V(DA and RSIC-175 sampler,, were bubbles ptesedt �-1 pca-s:7,e:' (3VYw (jMni in diarinetev) in py o"(hu VOA vials? l7.'Ncmall TIRCli,'anctalsluutrimiitsalllplcsmceivecata pH Hof<2'� 1 S. We,,. a) l ayar ide Sam [)It!,, re_xci ved a- 8 1-1 > 12 and sLdfide sarn lo-i rocs' rd ar a 11 9? 19- Were rll Hpplicable NI-ItrTKN!ey�tii plienoli625 (<U,5mWL) samp'es f:Cc a real cal ❑Yes U No VJ NA ❑ Ye5 - i�lo ® i�d A 13 YesEl Mc� ®NA Chlorin~? 74, 1Wet oliont-cmzrks?reclrehis (i.e. roquestedd4jtions, hISIMSDde i �riorls, at�...l El Y ] Nr ®1 A cnrrecfy transcribed from twee 00C into the coiiurlcr,Jscution in L1h1S? 21. Was' the tale tiUtrlber lisaed oil tiro COoi�ain[� l bcl? I:' 'e% NA El YesNr Sam ple r -sip.Li nation (Mlia4 ac completed for any samples) iueorrectty pircyurvvd or win heac,iacr,.) Saruple(S) .NA Wtn'C rerae;rv^d inc Urrertly pMerved 9nG were adjusted dc*ordiagly in Earnple r�L;eivirig with NA ii L vrcirckc one: I• SO4, HNO;, HC1, NaOK using SR # NA i Time of preLEfawdDii r`aA ,, ifmnre dlau one preservative is needed. pi=sc natc in the ormire."ts bolotiw. aMpl=(s) NA were received witl', bubbles >6 giln in diarte!Hr. SampJas(s) NA were received xvirir TRC > 0-5 TIC A , (if f ip is tru ),11W '.vorr aditis-ed aozordinly i:j sririplc meeiving w0b sodium thiasulfaLin (Nu, 5,%)%0ffi Shealy ID: NA Sly L�LI o[rJe ]ah41R ri itIeci �y" IVIG Datc: par U20210 Cairiruents- Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - 8 WO Permit plumber: Laboratory: Facility Name: YADKINVILLE, NC Waypoint Analytical Virginia Inc. Residual Source WQ # or NPDES#: WQOOD1800 VVWT"P Name: YADKINVILLE WTP Residual Analysis Data Product Type Sample or Composite Date WPL 01/23120 Parameter (mglkg dry weight) Ceiling Conc. Limit Percent Solids {%) NA 6.20 Arsenic 75 <8.06 Cadmium 85 <1.61 Copper 4300 06.3 Chromium NA 28.5 Lead 840 17.6 Mercury 57 <0.245 Molybdenum 75 <4.03 Nickel 420 11.3 Selenium 100 <8.06 Zinc 7500 142 Total Phosphorus NA 579 TKN NA 7470 Ammonia-Nitroger¢ NA 1610 Nitrate and Nitrite NA <76.1 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify. under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." f go-L Signatur f Pr are ` Date 'Preparer is defined in 40 CFR Part 543.9(r) and 15 A NCAC 2T.1102(26) QENR FORM RSSF-6 (1212006) Printed: 2/712021 4:44:16 PM For: 2056 02 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed_ WQ Permit Number: Facility Name: YADKINVILLE, NC Residual Source NPDES # or WQ#: VVQ00018DO WWTP Name: YADKINVILLE WTP Residual Analysis Data Product Type WPL Sample or Composite Date 01/23/20 Parameters (mglkg dry weight) Aluminium 93900 Calcium 2310 Magnesium 1280 pN (s.u.) 13.50 Potassium 856 Sodium 25&000 PAN 3221 SAR (Ratio) 265.0106 Laboratory: Waypoint Ana€ytical Virginia Inc. 11 certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." aj 110 Sig re o rep r Date .Preparer is defined in 40 CFR Par! 503.9(r) and 15 A NCAC 2TA 102(26) Printed: 217/2021 4:44:53 PM For: 2056 02 DENR FORM RSSF-B (12/2006) Waypointo ANALYTICAL 2/3/2020 Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-024-0016 Project Description: Yadkinville WTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/24/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 6 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-024-0016 Client Project Description: Yadkinville WTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 70270 Yadkinville WTP Solids 01/23/2020 11:30 01/24/2020 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46507 Synagro Central LLC/ Yadkinville Alex Fox Mary Brewer Project Yadkinville WTP Report Date : 02/03/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Pauric ry Report Number : 20-024-0016 REPORT OFANALYSIS Agronomist Lab No : 70270 Matrix: Solids Sample ID: Yadkinville WTP Sampled: 1/23/2020 11:30 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 93.8 % 0.010 1 01/29/2017:05 ADM SM-2540G Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 1610 mg/Kg - dry 1610 1 01/31/20 12:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N <76.1 mg/Kg - dry 76.1 1 01/29/20 13:36 ZBD 4500NO3F-2011 Organic N 5850 mg/Kg - dry 4030 1 01/31/20 10:00 CALCULATION pH 13.5 S.U. 1 01/30/20 06:12 JSL 9045D Total Solids 6.20 % 0.010 1 01/29/20 17:05 ADM SM-2540G Total Kjeldahl Nitrogen 7470 mg/Kg - dry 4030 1 01/31/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 579 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Aluminum 93900 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Arsenic <8.06 mg/Kg - dry 8.06 1 01/29/20 17:16 JTR 6010D Calcium 2310 mg/Kg - dry 403 1 01/29/20 17:16 JTR 6010D Cadmium <1.61 mg/Kg - dry 1.61 1 01/29/20 17:16 JTR 6010D Chromium 28.5 mg/Kg - dry 4.03 1 01/29/20 17:16 JTR 6010D Copper 96.3 mg/Kg - dry 4.03 1 01/29/20 17:16 JTR 6010D Iron 24200 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Lead 17.6 mg/Kg - dry 4.84 1 01/29/20 17:16 JTR 6010D Magnesium 1280 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Manganese 10000 mg/Kg - dry 80.6 10 01/30/20 15:56 JTR 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 6 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46507 Synagro Central LLC/ Yadkinville Alex Fox Mary Brewer Project Yadkinville WTP Report Date : 02/03/2020 284 Boger Road Information : Received : 01/24/2020 Mocksville , NC 27028 Pam« mL 60wr Submitted By : Alex Fox Pauric ry Report Number : 20-024-0016 REPORT OFANALYSIS Agronomist Lab No : 70270 Matrix: Solids Sample ID: Yadkinville WTP Sampled: 1/23/2020 11:30 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury <0.245 mg/Kg - dry 0.245 1 01/29/20 12:09 TJS SW-7471B Molybdenum <4.03 mg/Kg - dry 4.03 1 01/29/20 17:16 JTR 6010D Nickel 11.3 mg/Kg - dry 4.03 1 01/29/20 17:16 JTR 6010D Potassium 856 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Selenium <8.06 mg/Kg - dry 8.06 1 01/29/20 17:16 JTR 6010D Sodium 260000 mg/Kg - dry 4030 10 01/30/20 15:56 JTR 6010D Zinc 142 mg/Kg - dry 20.2 1 01/29/20 17:16 JTR 6010D Sulfur 1920 mg/Kg - dry 80.6 1 01/29/20 17:16 JTR 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 6 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46507 Customer Name: Synagro Central LLC/ Yadkinville Report Number: 20-024-0016 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/24/2020 13:36:20 Page 5 of 6 SAMPLING LOG # cuS T 0mlER: SY1qAG rj,(, PRC)cJyCT MANAGER: �x Phone: (s3 ) 7v3�� A & L GUSTOMEfi LAS # SAMPLE J.D. SAMPLING LOCATION S Relinquished by S8,npler,/ x RellnquIshed by; t ! Ck Relinquished by: SPECIAL INSTRUCTIONS. ?air monitoring purposes. a 4-aazs Svnaaro Central LLCI Yadkinville 4-2020 Yadkinville VVTP 13:35:33 SAMPLE TYPE 4 Datel ime n�+� OF cus-raay RECORD attest that the proper field Sam lin s d aLrrfn P S Procedures 4 coon of tfrese samples. SAIMIPLER 0I SANiPLING CONTAINERS PATE F4E iHOE] TIME PRESERdEC M1hECHp❑ � _ SHIPPED Rsdeved by: RE<'+LARKS: Recieved by.1— vit'ujuvea py: ,)A PLE ANALYSIS REQUEST J SLI SL2 jNH4-N NO3-N ❑r nic Cd Cr j Ni Pb As Hg 5e AEI CaCO3 Volatile) equly, Solids `°. Cl NQ� �d S l : Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iran, Aluminum, Manganese, Copper and Zinc SECTION 3 FACILITY NAME: YADKINVILLE, NC LANDOWNER: TOWN OFYADKINVILLE OPERATOR: TOWN OFYADKINV€LLE CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): ' See list of bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W000018CO FIELD#: NC-YK-00029-0-0001- ANNUAL DRY TONS APPLIED: 78.72 SITE #: NC YK 00029 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 11.5 ACRES PERMITTED: 11.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids DryTonslAc Source Moist Inches Method* Rate"* Rate- mglkg mglkg mglkg Amount UOM Crap 1 Crop 2 Crop 1 Crop 2 V912020 31,600.00 (G) 6,200 0.708 YWPL MOIST 0-<112" SUR 0.5 0.40 7,470.00 1,610.00 76.10 4,562 FSH 111012D20 31,500.00 (G) 6.200 0.708 YWPL MOIST 0-<112" SUR 0.5 0.40 7,470.00 1,610.00 76,10 4.562 FSH Jan-20 63,000.00 {G} 4129/2020 31,500.00 (G) 6.200 0.708 YWPL MOIST "0-<112" SUR 0.5 0.40 7,470.00 1,610.00 76.10 4.562 FSH Apr-20 31,500.00 (G) 5/412020 24,500.00 (0) 6.2CO 0.551 YWPL MOIST 0-<1I2" SUR 0.5 0.40 7,470.00 1,610.00 76.10 3.548 FSH May-20 24,500.00 (G) 711512D20 24,500.00 (G) 6.200 0.551 YWPL DRY 0-<112" SUR 0.5 0,40 7,470.00 1,610.00 76.10 3.548 FSH 71161202D 31,500.00 (G) 6.200 0.708 YWPL DRY 0-<112" SUR 0.5 0,40 7,470.00 1,610.00 76.10 4.562 FSH Jul-20 56,000.00 (G) 9/312020 21,000.00 (G) 6.200 0.472 YWPL DRY 0-<112" SUR 0.5 0.40 7,470.00 1,610.00 76.10 3.041 FSH 9/4/2020 24,500.00 (G) 6.200 0.551 YWPL DRY 0-<112" SUR 0.5 0.40 7,470.00 1,610.OD 76,10 3,548 FSH Sep-20 45,500.00 (G) 11/19/2020 35,000.00 (G) 6.200 0.787 YWPL DRY C-<112" SUR 0.5 0.40 7,470.00 1,610.00 76.10 5.069 FSH 11/20/2020 49,000.00 (G) 6.200 1.102 YWPL DRY D-a112" SUR 0.5 0.40 7,470.00 1,610.00 76.10 7.097 FSH Nov-20 84,000.00 (G) Total 6.846 AS CD CU CR PB HG MO NI SE ZN Annual Ibslacre A pplied 4.110 0.022 1,318 0.390 0.241 0.003 0.055 0.155 0.110 1.94 Cumulative Ibslacre Applied 0.136 0.044 1.764 0.557 0.441 0.004 0.072 0.238 0.126 3.24 Permit PAN Limit (Ibslacre) 1st Crop' 2nd Crop; Federal C.P.L.R. (Ibslacre)"'* 36.6 34.8 1,339.0 267.9 15.0 375.01 89.0 2,501 YWPL = YADKINVIL.LE, NC WTP LIQUID Total 44.099 0.000 P 216 216 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 "I certify, under penalty o la , that this document wa prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are sign penalties f u mini a false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-D.2, Aerobicaily digested-0.3, Raw Sludge-0.4 * Application Method: SUR _ Surface, [NJ - Injection, SURIN - Incorporation *'** C.P.L.R.: Cumulative Pollutant Loading Rate Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 '" * See Site pH & Lime Application Records Section of Report Printed: 2/7/2021 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Yadkinville, NC WQ0001800 Town of Yadkinville Owner: 11.5 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): Town of Yadkinville Predominant Soil Series: 11.5 78.72 Clifford Site #: NC YIC 00029 Field #: YK 00029 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): -Sample or Com- posite Date Non �Miiiiiiiiiii Total Phos- Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4j 51 6 /1 81 91 10 11 12 y DT/Ac./ 0 App. Event 6.85 .. Arsenic 0.119 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.118 Cadmium 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Copper 1.319 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 1.319 Chromiuiii 0.390 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.390 Lead 0.241 0.000 0.000 1 0.000 0.000 0.000 1 0,000 0.000 0.000 0.000 0.000 0.000 0.241 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.055 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.055 denum Nickel 0.155 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.155 Selenium 0.110 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.110 Zinc 1.944 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.944 Total Phos- 7.928 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 7.928 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and iinprisonft;ejAt for lcatowing violations". Signature f Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LANDOWNER: KENNETH GRAY HOBSON OPERATOR: JAMES HOBSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): ' See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT ##: WQ0001800 FIELDS: NC-YK-00033-0-0001- ANNUAL DRY TONS APPLIED: 5.93 SITE #: NO YK 00033 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 215 CROP 2 NAME: Page: 1 ACRES UTILIZED: 7.6 ACRES PERMITTED: 7.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Vclati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) °/ Residual Dry, Wet, Past24 Hrs. Application lizatton ization TKN Nitrogen and Nitrite (lbslacre) Application Month Solids DryTonslAc Source Moist Inches Method` Rate— Rate— mg/kg mglkg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 611/2020 36,000.00 (G) 1.580 0.312 YL MOIST "0-1112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 12.757 FSH 6/212020 54,000.00 (G) 1,580 0.468 YL DRY "0-1112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 19.135 FSH Jun-20 90,000.00 (G) Annual fbslacre Applied Total 0.780 Total 31.892 0.000 0.030 1 0.006 1 4.970 1 0.333 0.161 1 0.007 1 0.039 1 0.320 1 0.034 Lime Federal C.P.L.R. (lbslacre)**** 36.6 34.8 1 1,339.0 267.9 1 15.0 375.0 89.0 1 2,500.0 YL = YADKINVILLE, NO WWTP LIQUID "T certify, under penalty of Iwat this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gathered and evaluated the information submittedI am aware that there are signiS tie, alse information, including the possibility of fines and imprisonment for knowing violations." Z.� SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation * * C.P.L.R.: Cumulative Pollutant Loading Rate Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **"*' See Site pH & Lime Application Records Section of Report Printed: 2/7/2021 DENR FORM FSF (12/2003) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Yadkinville, NC Total Dry Tons Applied (Annual): 5.93 WQ0001800 Cation Exchange Capacity (non 503 only): Tames Hobson Owner: Kenneth Hobson Predominant Soil Series: Clifford 7.6 Acres Permitted: 7.6 Site #: NC YK 00033 Field #: YK 00033 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Total Phos- phoruSMENNEEMENEEN. Annual Heavy Metal Field Loadings (Calculated in lbslacrc): Total 1 2 3 4 5 h 7 8 9 16 11 12 DT/Ac./ 0 App. y Event 0.78 Arsenic 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 1.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.045 Cbromiuir 0.095 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.095 Lead 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.045 Mercury 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.005 Molyb- 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0A00 0.000 0.000 0.000 0.000 0.016 denum Nickel 0.092 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.092 Selenium 0.0 H 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Zinc 3.588 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.588 Total Phos- 49.920 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.920 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NO LANDOWNER: KENNETH GRAY HOBSON OPERATOR: JAMES HOBSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): ` See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W Q0001800 FIELD#: NC-YK-00033-0-0002- ANNUAL DRY TONS APPLIED: 12.87 SITE 4: NC YK 00033 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN; 2C2 CROP 2 NAME: Page: 1 ACRES UTILIZED: 6.4 ACRES PERMITTED: 6.4 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past24 Hrs. App€ization lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids DryTonslAc Source Moist Inches Method* Rate`* Rate— mg/kg mglkg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 6/1/2020 90,000.00 (G) 1.580 0.927 YL MOIST .0.<112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 37.871 FSH Jun-20 1 90,000.00 (G) 111912D20 93,000.00 (0) 1.580 0,957 YL DRY 0-<112' SUR 0.5 0.30 63,000.0C 7,200.CC 97.20 39.133 FSH 1111012C20 12,400.00 {G) 1.58C 0.128 YL MOIST "0 <112" SUR C.5 0.30 63,000.00 7,200.00 97.20 5.215 FSH Nov-20 t05,400.00 {G) Total 2,012 Total 82.222 0,000 AS CD CU CR Pe HG MO NI SE ZN P Lime Applied 0.025 0.005 2.696 0,245 C.117 0.012 0.040 0.237 0.034 9.253 128.741 Date Lbs1Ac 24,758 0.058 0.012 9.138 0.636 0.307 0.016 0.079 0.611 0.068 1st Crop;::r 202 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500,0 YL = YADKINVILLE, NC W WTP LIQUID "1 certify, under penalty of law, hat this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information subrnittcd. t am aware that there are significant n Ides fo g false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobicaliy digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation **"* C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injectionllncorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/712021 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Yadkinville, NC Total Dry Tons Applied (Annual): 12.87 WQ0001800 Cation Exchange Capacity (non 503 only): James Hobson Owner: Kenneth Hobson Predominant Soil Series: Clifford 6.4 Acres permitted: 6.4 Site #: NC YK 00033 Field #: YK 00033 0002 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date On FRIMI Total Phos- Pliorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 2 3 4 5 6 7 8 9 10 1 12 y DTIAc./ App. Event 2.01 Arsenic 0.025 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.025 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 2.696 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 2.696 hromiui 0.245 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.245 Lead 0.117 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.117 Mercury 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.012 Molyb- 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 denum Nickel 0.237 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.237 Selenium 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Zinc 9.255 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9.255 Total Phos- 128.768 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0,000 0.000 ###{### liorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LANDOWNER: JAMES K HOBSON OPERATOR: JAMES K HOBSON CROP 1 NAME: WHEAT (WH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LANE] APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0001800 FIELD#: NC-YK-00033-0-0003- ANNUAL DRY TONS APPLIED: 6.54 SITE #: NO YK 00033 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 111 CROP 2 NAME: Page: 1 ACRES UTILIZED: 8.5 ACRES PERMITTED: 8.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volatl- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbslacre) Application Month Solids DryTons/Ac Source Moist inches Method* Rate" Rate`** mglkg mglkg mglkg Amount UOM Crap 1 Crop 2 Crop 1 Crop 2 11110120M 99,200.00 (G) 1.580 0.769 YL MOIST "0-<112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 31.429 W H Nov-20 99,200.00 (G) Applied Cumulative Ibs/acre Applied Total 0.769 Total 31.429 0.000 1 0 YL = YADKINVILLE, NO WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p !al �sfor submitti a information, including the possibility of fines and imprisomnent for knowing vioIations." 'SIC NATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation *"** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ""*** See Site pH & Lime Application Records Section of Report Printed: 2/7/2021 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Yadkinville, NC WQ0001800 James Hobson Owner: 8.5 Acres Permitted: Total Dry Tons Applied (Annual): 6.54 Cation Exchange Capacity (non 503 only): .lathes Hobson Predominant Soil Series: Clifford 8.5 Site #: NC YK 00033 Field 4: YID 00033 0003 Residual Analysis Data(Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): �Miiiiiiiiiii Total Phos- Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 b 7 8 9 1 0 lij 12 y DT/Ac./ App. Event 0.77 Arsenic 0.009 1 0.000 0.000 0.000 1 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 1.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0M00 0.000 0.000 1.030 Chrorniinr 0.094 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.094 Lead 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.045 Mercury 0.005 0,000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molyb- 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 denture Nickel 0.091 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.091 Selenium 0.013 0.000 0.000 0.000 0M00 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Zinc 3.537 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.537 Total Phos- 49.216 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.216 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and unpriso meat for lutowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LANDOWNER: ROGER FRANK DAVIS OPERATOR: ROGER FRANK DAVIS CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM W Q PERMIT #: W Q0001800 FIELD#: NC-YK-00035-0-0001- ANNUAL DRY TONS APPLIED: 13.44 SITE #: NC YK 00035 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 12.2 ACRES PERMITTED: 12.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Corid. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or W at Tons (W) % Residual Dry, wet, Past 24 Hrs. Application lization lzation TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids DryTonslAc Source Moist Inches Method* Rate** Rate— mg/kg mg/kg mglkg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 5/15/2020 84,000.00 (G) 1.580 0.454 YL DRY 0- 112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 18.542 FSH 5/18/2020 120,000.00 (G) 1.580 0.648 YL DRY 0-a112" SUR 0.5 0.30 63,000.00 7,200.00 97.20 26.489 FSH May-20 204,000.00 (G) Permit PAN Limit (Ibslacre) st Total 1.102 Total 45.031 0.000 0.022 1 0.130 1 0.019 1 5.068 {Federal C.P.LR. (Ibslacre) ** 36.6 { 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 YL = YADKINVILLE, NC W WTP L€QUID "I certify. under penalty of law, t] t this document was prepared tinder my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p I s for submi a se 7nsr cation, including the possibility of fines and imprisonment for knowing/violations." ®�_� --Z —/ /Z SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation '"** C.P.L.R.: CumLI]ative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 *"*** See Site pH & Lime Application Records Section of Report Printed:2/712021 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMAIARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Yadlsinville, NC Total Dry Tons Applied (Annual): Permit #: WQ0001800 Cation Exchange Capacity (non 503 only): Operator: Roger Frank Davis Owner: Roger Frank Davis Predominant Soil Series: Acres Used: 12.2 Acres Permitted: 12.2 Site #: NC YK 00035 Field #: 13.44 Clifford YK 00035 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft Sample or Com- posite Date 1 1 3/10/20 2 J 3 4 5 6 7 J 8 9j 10 11 12 % Solids 1.58 Arsenic 6.1 Cadmium 1.3 Copper 670 Chromium 61 Lead 29 Mercury 3.1 Molyb- denum 10 Nickel 59 Selenium 8.5 Zinc 2300 Total Phos- horus 32000 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2j 3j 4j 5j 6 7j 8j 9 1 d 11 12 DT/Ac./ 0 App. Event 1.10 Arsenic 0,013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 1.477 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.477 Chromium 0.134 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.134 Lead 0.064 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0,000 0.000 0.064 Mercury 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Moly6 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 denum Nickel 0.130 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.130 Selenium 0.019 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.019 Zinc 5.069 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.069 Total Phos- 70.528 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 70.528 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprison n for knowing violations". ,Signature of Land Applier Date DLNR FORM MFLSF (1212006) SECTION 4 SUMM111 Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOL0C4r;S,INC Cuyahoga Falls, Ohio44223 Arraly0ca1 Laboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com January 31, 2020 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Yadkinville WWTP Dear Alex Fox: Order No.: 20010822 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/15/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington C891 Page 1 of 30 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 20010822 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/31/2020 CLIENT: Synagro Project: Yadkinville WWTP WorkOrder Narrative: 20010822: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 20010822-OOIA TCLP-SVOC-CPEST(8081B): Bracketing CCVs were out of range for some analytes. All samples within the sequence are non -detect for all analytes. 20010822-OOIA TCLP-SVOC_8270E: Possible low bias for 1,4-Dichlorobenzene and Hexachloroethane due to low recovery in LCS-41607. 20010822-OOIA Sulfide,Reactive_NPW(9034): The sample was analyzed outside of hold time. 20010822-OOIA pH NPW(4500-H+B) 22nd Ed.: pH is an EPA field recommended parameter. Per 40 CFR 136.3, hold time is 15 minutes from collection. Analytical Sequence QC Notes: LCS-41611 TCLP-SVOC-CPEST_TCLP(8081): LCS-41611 demonstrated high recovery for analyte Original Page 2 of 30 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„NQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 20010822 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/31/2020 CLIENT: Synagro Project: Yadkinville WWTP Endrin, suggesting a potential high bias for recovery of this analyte. All samples in this batch are non - detect for Endrin. LCS-41607 SVOC-BNA_TCLP(8270): LCS-41607 exhibited low responses to 1,4-Dichlorobenzene and Hexachloroethane. Possible low bias in associated samples for these analytes. 20010822-001AMSD TCLP-SVOC_8270E: High RPD due to suspected sample inhomogeneity. LCS TCLP-SVOC-Herb_TCLP(8151): LCS exhibited high recovery, associated samples are ND for all analytes of interest. Original Page 3 of 30 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 20010822 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 1/31/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 4 of 30 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL TECHNp4,1 ULES,1NC. Cuyahoga Falls, Ohio 44223 Analytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Yadkinville WWTP Lab SamplelD Client Sample ID 20010822-001 Yadkinville WWTP Tag No Date Collected 1/14/2020 2:15:00 PM Workorder Sample Summary WO#: 20010822 3l Jan-20 Date Received Matrix 1/15/2020 10:20:00 AM Sludge Page 5 of 30 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES R PORT ENVIRONMENTALTECHN❑L0G1ES,11+1C Cuyahoga Falls, Ohio44223 WO#: 20010822 ArWyft cal taboralonag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20010822-OOIA Yadkinville WWTP 1/14/2020 2:15:00 PM Sludge pH (SM4500-H+B) 1/29/2020 12:15:53 PM Reactive Cyanide (9014/7.3.3.2)-Liqui 1/27/2020 1:47:00 PM Reactive Sulfide (EPA 9034) 1/27/2020 1:47:00 PM TCLP Herbicides by EPA 8321B 1/19/2020 3:00:00 PM 1/24/2020 2:27:00 AM TCLP Mercury Analysis (SW1311/7471/19/2020 3:00:00 PM 1/21/2020 5:20:00 PM 1/24/2020 1:34:00 PM TCLP Metals Analysis (SW1311/6010:1/19/2020 3:00:00 PM 1/21/2020 12:55:00 PM 1/22/2020 10:12:02 PM TCLP Pesticides Analysis (SW1311/8(1/19/2020 3:00:00 PM 1/20/2020 3:30:00 PM 1/24/2020 1:25:00 AM TCLP Semi-Volatiles Analysis 1/19/2020 3:00:00 PM 1/21/2020 3:30:00 PM 1/24/2020 6:40:00 PM (SW1311/8270) TCLP Volatiles Analysis 1/19/2020 3:00:00 PM 1/23/2020 5:37:00 PM Original Page 6 of 30 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010822 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/14/2020 2:15:00 PM Lab ID: 20010822-OOIA Project: Yadkinville WWTP Client Sample ID Yadkinville WWTP Analyses Result RL Qual Units DF Date Analyzed RCI SW1010 Analyst: TAH FLASHPOINT 200°F (EPA 1010) Flashpoint (200oF) >140 °F 1 1/16/20204:00:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: MJM TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00200 mg/L 1 1/24/2020 1:34:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW301OA Analyst: EAM TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/22/2020 10:12:02 PM TCLP Barium(Ba) ND 5.00 mg/L 1 1/22/2020 10:12:02 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/22/2020 10:12:02 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/22/2020 10:12:02 PM TCLP Lead(Pb) ND 0.500 mg/L 1 1/22/2020 10:12:02 PM TCLP Selenium(Se) 0.0568 0.0500 mg/L 1 1/22/2020 10:12:02 PM TCLP Silver(Ag) ND 0.500 mg/L 1 1/22/2020 10:12:02 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: SFG TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.200QL-QMRmg/L 2 1/24/2020 6:40:00 PM 2,4,5-Trichlorophenol ND 0.500 mg/L 2 1/24/2020 6:40:00 PM 2,4,6-Trichlorophenol ND 0.500 mg/L 2 1/24/2020 6:40:00 PM 2,4-Dinitrotoluene ND 0.100 mg/L 2 1/24/2020 6:40:00 PM Cresols, Total ND 10.0 mg/L 2 1/24/2020 6:40:00 PM Hexachloro-1,3-butadiene ND 0.0400 QMR mg/L 2 1/24/2020 6:40:00 PM Hexachlorobenzene ND 0.100 mg/L 2 1/24/2020 6:40:00 PM Hexachloroethane ND 0.200QL-QMRmg/L 2 1/24/2020 6:40:00 PM Nitrobenzene ND 0.200 mg/L 2 1/24/2020 6:40:00 PM Pentachlorophenol ND 0.500 mg/L 2 1/24/2020 6:40:00 PM Pyridine ND 0.500 mg/L 2 1/24/2020 6:40:00 PM Surr: 2-Fluorophenol 65.0 10 - 109 %Rec 2 1/24/2020 6:40:00 PM Surr: Phenol-d6 63.2 10 - 109 %Rec 2 1/24/2020 6:40:00 PM Surr: Nitrobenzene-d5 75.5 19 - 120 %Rec 2 1/24/2020 6:40:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CaleVal < MDL Page 7 of 30 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010822 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/14/2020 2:15:00 PM Lab ID: 20010822-OOIA Project: Yadkinville WWTP Client Sample ID Yadkinville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: 2,4,6-Tribromophenol 91.0 10 - 120 %Rec 2 Surr: 2-Fluorobiphenyl 83.2 22 - 117 %Rec 2 Surr: p-Terphenyl-d14 96.4 34 - 116 %Rec 2 NOTES: Possible low bias for 1,4-Dichlorobenzene and Hexachloroethane due to low recovery in LCS-41607. TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 90.2 Surr: DCB 108 TCLP HERBICIDES BY EPA 8321B SW8081 SW351OC Analyst: SFG 1/24/2020 6:40:00 PM 1/24/2020 6:40:00 PM 1/24/2020 6:40:00 PM Analyst: SEK 0.125 mg/L 5 1/24/2020 1:25:00 AM 0.250 mg/L 5 1/24/2020 1:25:00 AM 0.0125iQC+(QDmg/L 5 1/24/2020 1:25:00 AM 0.0125 dQC+ mg/L 5 1/24/2020 1:25:00 AM 0.0125 dQC+ mg/L 5 1/24/2020 1:25:00 AM 0.0125 dQC+ mg/L 5 1/24/2020 1:25:00 AM 0.0125 dQC+ mg/L 5 1/24/2020 1:25:00 AM 10 - 119 %Rec 5 1/24/2020 1:25:00 AM 10 - 119 %Rec 5 1/24/2020 1:25:00 AM SW8321A SW1311M Analyst: BJH 2,4-D ND 0.500 mg/L 50 1/24/2020 2:27:00 AM 2,4,5-TP ND 0.500 mg/L 50 1/24/2020 2:27:00 AM Surr: 2,4-Dichlorophenylacetic aci 70.7 70 - 130 %Rec 50 1/24/2020 2:27:00 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: RMT TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.250 mg/L 50 1/23/2020 5:37:00 PM 1,2-Dichloroethane ND 0.250 mg/L 50 1/23/2020 5:37:00 PM MEK ND 5.00 mg/L 50 1/23/2020 5:37:00 PM Benzene ND 0.250 mg/L 50 1/23/2020 5:37:00 PM Carbon tetrachloride ND 0.250 mg/L 50 1/23/2020 5:37:00 PM Chlorobenzene ND 2.50 mg/L 50 1/23/2020 5:37:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original RL Reporting Detection Limit U Samples with CaleVal < MDL Page 8 of 30 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010822 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 1/14/2020 2:15:00 PM Lab ID: 20010822-OOIA Project: Yadkinville WWTP Client Sample ID Yadkinville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS SW8260 SW1311M Analyst: RMT Chloroform ND 0.250 mg/L 50 Tetrachloroethene ND 0.250 mg/L 50 Trichloroethene ND 0.250 mg/L 50 Vinyl chloride ND 0.100 mg/L 50 Surr: 4-Bromofluorobenzene 100 70 - 130 %Rec 50 Surr: Di brom ofl uorom ethane 100 70 - 130 %Rec 50 Surr: Toluene-d8 95.1 70 - 130 %Rec 50 RCI SW9014 REACTIVE CYANIDE (9014/7.3.3.2)-LIQUID Cyanide, Reactive ND 0.490 mg/L 1 PH (SM4500-H+ B) A4500-H+B pH 7.1 H s.u.@21.lC 1 NOTES: pH is an EPA field recommended parameter. Per 40 CFR 136.3, hold time is 15 minutes from collection. RCI SW9034 REACTIVE SULFIDE (EPA 9034) Sulfide, Reactive ND 25.0 H mg/L 1 NOTES: The sample was analyzed outside of hold time. Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM 1/23/2020 5:37:00 PM Analyst: MS 1/27/2020 1:47:00 PM Analyst: VVK 1/29/2020 12:15:53 PM Analyst: MS 1/27/2020 1:47:00 PM E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 9 of 30 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20010822 Wehsite: http://www.settek.com 31Jan-20 Client: Synagro State: NW Project: Yadkinville WWTP Program Name: NC WW_SCM Sample ID Matrix Test Name Analyte Status 20010822-OOlA Sludge Flashpoint 2007 (EPA 1010) Flashpoint (2007) A Sludge pH (SM4500-H+ B) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Liquid Cyanide, Reactive U Sludge Reactive Sulfide (EPA 9034) Sulfide, Reactive U Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A Sludge TCLP Herbicides by EPA 8321B 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Original #1 Page 10 of 30 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report ENVIROMMEWAL IrECHHOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20010822 Wehsite: http://www.settek.com 31Jan-20 Client: Synagro State: NW Project: Yadkinville WWTP Program Name: NC WW_SCM Sample ID Matrix Test Name Analyte Status 20010822-001A Sludge TCLP Volatiles Analysis 1, 1 -Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A Original #1 Page 11 of 30 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: 41570B Sample ID: MB-41570 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 108443 Client ID: PBS Batch ID: 41570B TestNo: SW8081 Analysis Date: 1/23/2020 SegNo: 2581728 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 dQC+ gamma-BHC ND 0.000500 dQC+ Heptachlor ND 0.000500 dQC+ Heptachlor epoxide ND 0.000500 dQC+ Methoxychlor ND 0.000500 dQC+ Surr: TCMX 601 1000 60.1 10 119 Surr: DCB 1030 1000 103 10 119 Sample ID: LCS-41570 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 108443 Client ID: LCSS Batch ID: 41570B TestNo: SW8081 Analysis Date: 1/23/2020 SegNo: 2581729 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.790 0.000500 0.500 0 158 10 130 SmQC- gamma-BHC 0.482 0.000500 0.500 0 96.5 10 130 QC+ Heptachlor 0.516 0.000500 0.500 0 103 10 130 mQC+ Heptachlor epoxide 0.576 0.000500 0.500 0 115 10 130 QC+ Methoxychlor 0.789 0.000500 0.500 0 158 10 178 mQC+ Surr: TCMX 793 1000 79.3 10 130 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 12 of 30 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: 41572 TCLP Mercury ND 0.00200 TCLP Mercury 0.00402 0.00200 0.00400 0 101 80 120 TCLP Mercury ND 0.00200 Sample ID: TCLP BLANK 1-20-2 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/21/2020 RunNo: 108442 Client ID: PBS Batch ID: 41572 TestNo: SW7470A SW7470A Analysis Date: 1/24/2020 SegNo: 2581507 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 30 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: 41572 TCLP Mercury 0.00466 0.00200 0.00400 0 116 75 125 Sample ID: 20011053-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/21/2020 RunNo: 108442 Client ID: Batch= Batch ID: 41572 TestNo: SW7470A SW7470A Analysis Date: 1/24/2020 SegNo: 2581516 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00455 0.00200 0.00400 0 114 75 125 0.00466 2.39 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 14 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010822 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: 41581 Sample ID: 20011053-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/21/2020 RunNo: 108350 Client ID: Batch= Batch ID: 41581 TestNo: SW6010D SW3010A Analysis Date: 1/22/2020 SegNo: 2575555 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.19 0.500 2.000 0 109 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2056 92.4 70 130 TCLP Cadmium(Cd) 2.14 0.100 2.000 0.001431 107 70 130 TCLP Chromium(Cr) 1.87 0.200 2.000 0.002186 93.3 70 130 TCLP Lead(Pb) 1.75 0.500 2.000 0 87.5 70 130 TCLP Selenium(Se) 2.43 0.0500 2.000 0.02499 120 70 130 TCLP Silver(Ag) 2.31 0.500 2.000 0 116 70 130 Sample ID: 20011053-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/21/2020 RunNo: 108350 Client ID: Batch= Batch ID: 41581 TestNo: SW6010D SW3010A Analysis Date: 1/22/2020 SegNo: 2575556 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.27 0.500 2.000 0 114 70 130 2.188 3.77 20 TCLP Barium(Ba) ND 5.00 2.000 0.2056 93.7 70 130 0 0 20 TCLP Cadmium(Cd) 2.19 0.100 2.000 0.001431 110 70 130 2.140 2.36 20 TCLP Chromium(Cr) 1.89 0.200 2.000 0.002186 94.6 70 130 1.869 1.32 20 TCLP Lead(Pb) 1.79 0.500 2.000 0 89.3 70 130 1.750 2.09 20 TCLP Selenium(Se) 2.62 0.0500 2.000 0.02499 130 70 130 2.430 7.36 20 TCLP Silver(Ag) 2.38 0.500 2.000 0 119 70 130 2.314 2.64 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010822 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: 41581 Sample ID: MB-41581 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/21/2020 RunNo: 108247 Client ID: PBS Batch ID: 41581 TestNo: SW6010D SW3010A Analysis Date: 1/21/2020 SegNo: 2575079 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-41581 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/21/2020 RunNo: 108247 Client ID: LCSS Batch ID: 41581 TestNo: SW6010D SW3010A Analysis Date: 1/21/2020 SegNo: 2575080 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.82 0.500 2.000 0 91.2 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 92.4 80 120 TCLP Cadmium(Cd) 1.80 0.100 2.000 0 90.2 80 120 TCLP Chromium(Cr) 1.85 0.200 2.000 0 92.7 80 120 TCLP Lead(Pb) 1.88 0.500 2.000 0 94.1 80 120 TCLP Selenium(Se) 1.92 0.0500 2.000 0 96.1 80 120 TCLP Silver(Ag) 2.00 0.500 2.000 0 100 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville WWTP BatchID: 41607 WO#: 20010822 31-Jan-20 Sample ID: 20010822-001AMS SampType: MS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/21/2020 RunNo: 108448 lient ID: Yadkinville WWTP Batch ID: 41607 TestNo: SW8270 SW3510C Analysis Date: 1/24/2020 SegNo: 2586256 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.259 0.200 0.8000 0 32.4 15.2 124 QMR 2,4,5-Trichlorophenol 0.681 0.500 0.8000 0 85.2 30.6 152 2,4,6-Trichlorophenol 0.662 0.500 0.8000 0 82.7 27.6 150 2,4-Dinitrotoluene 0.893 0.100 0.8000 0 112 58 141 o-Cresol ND 0.500 0.8000 0 61.6 26.9 132 Cresols, Total ND 10.0 1.600 0 62.4 27.6 132 Hexachloro-1,3-butadiene 0.278 0.0400 0.8000 0 34.7 -5.3 156 QMR Hexachlorobenzene 0.657 0.100 0.8000 0 82.1 54.3 142 Hexachloroethane 0.227 0.200 0.8000 0 28.4 1.92 131 QMR Nitrobenzene 0.483 0.200 0.8000 0 60.4 21 135 Pentachlorophenol 0.899 0.500 0.8000 0 112 47.4 134 Pyridine ND 0.500 0.8000 0 41.8 -10.3 64.2 m Surr:2-Fluorophenol 0.489 1.000 48.9 9.77 146 Surr: Phenol-d6 0.525 1.000 52.5 20.7 130 Surr: Nitrobenzene-d5 0.581 1.000 58.1 13.9 156 Surr:2,4,6-Tribromophenol 0.942 1.000 94.2 27.3 183 Surr:2-Fluorobiphenyl 0.622 1.000 62.2 21.4 153 Surr: p-Terphenyl-d14 1.02 1.000 102 54.8 154 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville WWTP BatchID: 41607 WO#: 20010822 31-Jan-20 Sample ID: 20010822-001AMSD SampType: MSD TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/21/2020 RunNo: 108448 lient ID: Yadkinville WWTP Batch ID: 41607 TestNo: SW8270 SW3510C Analysis Date: 1/24/2020 SegNo: 2586257 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.397 0.200 0.8000 0 49.6 15.2 124 0.2588 42.2 30 R 2,4,5-Trichlorophenol 0.741 0.500 0.8000 0 92.6 30.6 152 0.6812 8.38 30 2,4,6-Trichlorophenol 0.793 0.500 0.8000 0 99.2 27.6 150 0.6616 18.1 30 2,4-Dinitrotoluene 0.944 0.100 0.8000 0 118 58 141 0.8932 5.57 30 o-Cresol 0.613 0.500 0.8000 0 76.7 26.9 132 0.4924 21.9 30 Cresols, Total ND 10.0 1.600 0 76.6 27.6 132 0 0 30 Hexachloro-1,3-butadiene 0.470 0.0400 0.8000 0 58.7 -5.3 156 0.2776 51.4 30 R Hexachlorobenzene 0.728 0.100 0.8000 0 91.0 54.3 142 0.6568 10.3 30 Hexachloroethane 0.378 0.200 0.8000 0 47.2 1.92 131 0.2272 49.7 30 R Nitrobenzene 0.584 0.200 0.8000 0 73.0 21 135 0.4832 18.8 30 Pentachlorophenol 0.984 0.500 0.8000 0 123 47.4 134 0.8992 9.01 30 Pyridine ND 0.500 0.8000 0 44.7 -10.3 64.2 0 0 30 m Surr: 2-Fluorophenol 0.581 1.000 58.1 9.77 146 0 Surr: Phenol-d6 0.650 1.000 65.0 20.7 130 0 Surr: Nitrobenzene-d5 0.682 1.000 68.2 13.9 156 0 Surr:2,4,6-Tribromophenol 1.02 1.000 102 27.3 183 0 Surr:2-Fluorobiphenyl 0.755 1.000 75.5 21.4 153 0 Surr: p-Terphenyl-d14 1.07 1.000 107 54.8 154 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville WWTP BatchID: 41607 WO#: 20010822 31-Jan-20 Sample ID: MB-41607 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/21/2020 RunNo: 108448 lient ID: PBS Batch ID: 41607 TestNo: SW8270 SW3510C Analysis Date: 1/24/2020 SegNo: 2581886 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.383 Surr: Phenol-d6 0.386 Surr: Nitrobenzene-d5 0.373 Surr: 2,4,6-Tribromophenol 0.640 Surr: 2-Fluorobiphenyl 0.375 Surr: p-Terphenyl-d14 0.859 1.000 38.3 10 109 1.000 38.6 10 109 1.000 37.3 19 120 1.000 64.0 10 120 1.000 37.5 22 117 1.000 85.9 34 116 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville WWTP BatchID: 41607 WO#: 20010822 31-Jan-20 Sample ID: LCS-41607 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/21/2020 RunNo: 108448 lient ID: LCSS Batch ID: 41607 TestNo: SW8270 SW3510C Analysis Date: 1/24/2020 SegNo: 2581887 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.213 0.100 0.8000 0 26.7 36.4 130 S 2,4,5-Trichlorophenol 0.610 0.250 0.8000 0 76.3 31.7 132 2,4,6-Trichlorophenol 0.642 0.250 0.8000 0 80.2 31.1 133 2,4-Dinitrotoluene 0.822 0.0500 0.8000 0 103 43.3 130 o-Cresol 0.448 0.250 0.8000 0 56.0 32.9 130 Cresols, Total ND 5.00 1.600 0 58.1 31.7 130 Hexachloro-1,3-butadiene 0.263 0.0200 0.8000 0 32.9 31.4 130 Hexachlorobenzene 0.597 0.0500 0.8000 0 74.7 43.1 130 Hexachloroethane 0.188 0.100 0.8000 0 23.5 36.5 130 S Nitrobenzene 0.438 0.100 0.8000 0 54.7 39.5 130 Pentachlorophenol 0.705 0.250 0.8000 0 88.1 34 130 Pyridine 0.255 0.250 0.8000 0 31.9 10 130 Surr: 2-Fluorophenol 0.434 1.000 43.4 17.1 130 Surr: Phenol-d6 0.482 1.000 48.2 10 130 Surr: Nitrobenzene-d5 0.506 1.000 50.6 32.6 130 Surr: 2,4,6-Tribromophenol 0.831 1.000 83.1 4.43 130 Surr: 2-Fluorobiphenyl 0.521 1.000 52.1 41.8 130 Surr: p-Terphenyl-d14 0.834 1.000 83.4 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 30 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108275 Sample ID: LCS-R108275 SampType: LCS TestCode: FlashPt_Oil(1 Units: °F Prep Date: RunNo: 108275 Client ID: LCSW Batch ID: R108275 TestNo: SW1010 Analysis Date: 1/16/2020 SegNo: 2570505 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Flashpoint (200oF) 137 135.4 0 101 98 102 Sample ID: LCSD-R108275 SampType: LCSD TestCode: FlashPt_Oil(1 Units: °F Prep Date: RunNo: 108275 Client ID: LCSS02 Batch ID: R108275 TestNo: SW1010 Analysis Date: 1/16/2020 SegNo: 2570506 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Flashpoint (200oF) 137 135.4 0 101 98 102 137.0 0 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 21 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010822 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108275 Sample ID: 20010790-007ADUP SampType: DUP TestCode: FlashPt_NP Units: °F Prep Date: RunNo: 108275 lient ID: BatchQC Batch ID: R108275 TestNo: SW1010 Analysis Date: 1/16/2020 SegNo: 2570557 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Flashpoint (200oF) 186.0 1.07 10 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 30 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108542 Cyanide, Reactive ND 0.485 Cyanide, Reactive 9.68 0.490 10.00 0 96.8 85 115 Cyanide, Reactive ND 0.490 0.5000 0 78.9 50 150 Sample ID: 20010820-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 108542 Client ID: Batch= Batch ID: R108542 TestNo: SW9014 Analysis Date: 1/27/2020 SegNo: 2587805 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.28 0.490 10.00 0 92.8 81.3 118 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 30 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108542 Sample ID: 20010820-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 108542 Client ID: Batch= Batch ID: R108542 TestNo: SW9014 Analysis Date: 1/27/2020 SegNo: 2587805 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20010820-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 108542 Client ID: Batch= Batch ID: R108542 TestNo: SW9014 Analysis Date: 1/27/2020 SegNo: 2587806 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.37 0.485 10.00 0 93.7 81.3 118 9.285 0.905 5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 24 of 30 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108543 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4510 25.0 4800 0 94.0 85 115 Sulfide, Reactive 4580 25.0 4800 0 95.4 75 125 H NOTES: The sample was analyzed outside of hold time. Sample ID: 20010820-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 108543 Client ID: Batch= Batch ID: R108543 TestNo: SW9034 Analysis Date: 1/27/2020 SegNo: 2587818 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 30 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108543 Sample ID: 20010820-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 108543 Client ID: Batch= Batch ID: R108543 TestNo: SW9034 Analysis Date: 1/27/2020 SegNo: 2587818 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4640 NOTES: The sample was analyzed outside of hold time. Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits 25.0 4800 0 96.7 75 125 4580 1.30 30 H E Value above quantitation range M Manual Integration used to determine area response P Second column confirmation exceeds RL Reporting Detection Limit H Holding times for preparation or anal MC Value is below Minimum Compound PL Permit Limit S Spike Recovery outside accepted reco Original Page 26 of 30 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010822 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108624 Sample ID: LCS-R108624 SampType: LCS TestCode: pH_Oil(9045D Units: s.u.@20.9C Prep Date: RunNo: 108624 Client ID: LCSW Batch ID: R108624 TestNo: A4500-H+B Analysis Date: 1/29/2020 SegNo: 2592160 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 90 110 Sample ID: CHECK 7 SampType: LCS TestCode: pH_Oil(9045D Units: sm.@21.1C Prep Date: RunNo: 108624 Client ID: LCSW Batch ID: R108624 TestNo: A4500-H+B Analysis Date: 1/29/2020 SegNo: 2592362 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 90 110 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 27 of 30 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010822 31-Jan-20 Client: Synagro Project: Yadkinville WWTP BatchID: R108624 Sample ID: 20010820-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@20.2C Prep Date: RunNo: 108624 lient ID: BatchQC Batch ID: R108624 TestNo: A4500-H+B Analysis Date: 1/29/2020 SegNo: 2592172 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.8 NOTES: pH is an EPA field recommended parameter. Per 40 CFR 136.3, hold time is 15 minutes from collection. 6.8 0.3 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 30 CD [V CO O w O DBPix Evaluation ° ie - �. ?alysis Request/Chain of Custody 3�"`�Witk Street For Summit Environmental Technologies, Inc, use only toga FaUs, Ohio 44LIJ let. a]U.E7J.aLi i ran. of- - SET No. :vn�pany [3amt iPledse Prins] i'raject Name ethtYds uDmfpa,ny AsidIrets Project Rddress y ! iL� *ref 41o'f4 .41C' Va I i-Ale— +3,0 client Pbone Ne. +x 7 f y 703 - Us i�- V Client Fax No_ Y as Results PO# y '" PleaseBMW QUGW No- CileRC EFIlit /% ' I[ y TLCe7 i ontaci Persau d JI Sampled by oe- Check if ()hio VAY samples d ❑ t � to g C'�► 1 '^YSample [70 Identi#3cation [�lested Col[eeted :D ran I.z rp 1 e[[n uished VL R e'tv n lab by: I?Ate 15me Received by,— Date 'Time 14aicslComments: 1O Stale 6I Sample 0riyin _ FORCOMPLIANU YES NO CERTIFICATION REQUIRED YES NO RE FORT TO STATE (DW ON LY) YES NO 1v1us[ he a If yts, Piece provide I'W5 STU, & MP Rate Time Rash Requested BY: �-- pprovd co •�tt�oi npt l.•, sI r, i>�. n� simppns,rx.4d ❑eSe by lab manager a wlltml repoei UW a'auln uruxa White and yellow pages should amompany samples [o the lahorawry. Tho client retains the Piak past. 121478 www.an aL0M Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 20010822 RcptNo: 1 Logged by: Jesseca E. Westfall 1/15/2020 10:20:00 AM A4,�G Completed By: Jesseca E. Westfall 1/29/2020 9:34:01 AM Reviewed By: Jennifer Woolf - 2 1/31/2020 3:08:05 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes ❑ No ❑d NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes 0 No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 11.2 Goodl Not Present Page 30 of 30 TCLP data is not included in the 2020 Annual Report for Yadkinville WTP. A TCLP sample was taken in 2019 and is only required to be taken once per permit cycle. SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Yadkinville WQ Permit Number: W 00001800 WWTP Name: Yadkinvilie WWTP NPDES Humber: 3A9B{r19&G'� 1�1� 00 20 33 MonitoringPeriod: From 01/0112020 To 12/31/20 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed: Class A: Alt. l/A (tin€eltemp) Alt, 21B (Alk Treatment) Alt. 31C (Prior Testing) Alt. 41D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Ifeat Drying; Heat Treatntea€t Therniophilic Beta Ray Ganuna Ray Pasteurization Class i3: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) Indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestio€t Hnnnlieahle to niternotiva nPrfarmerl fr1-w,4 A nr Class R1 enrnnlete the follnwinir monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excce- of Type Technique Minimum Creo, Mean Maximum Units dences Analysis Fecal 2x10 to the 61 MPN 2899 4608 7407 MPN/g 0 Annual Grab Sm9221C Colifornn power per gram E of total solids CFU/g CFU 1000 MPN per gram of il4PN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lien of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: option/Alt, 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) X (40-day bench) (30-clay bench) (Spec. 02 uptake) Option/Alt_ 5 Option/Alt, 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying-- Stable) (Drying— Unstable) Option/Alt. 9 Option/Alt. 10 (Infection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32115A NCAC 02T. l 106 and the vector attraction X reduction requirement in 40 CFR 50333/15ANCAC 02T.1107 have been met." "1 certify, under penalty of lave, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in, 40 CFR 503.33115A NCAC 02T.1107 have not been met." (Please note if you check this statement attach au explanation why you have not met one or both of the requirements.) "This delen-nination has been made under my direction and supervision in accordance with the system designed to ensure that qunkfned personnel properly gather and evaluate the information used to determine that the hogen and vector attraction reduction requirements have been met, t am aware that there are significant peyalties for false certification in u g fine and imprisonment." Grant Trivette Plant Manager W� r Pre ar r Name nd Title (type ar print) Land App 'cr Name and title (if applicable) (type or print) - Signature of Preparcr* .Date Signature of Land Applier (if applicable) Date *Preparcr is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results Town of Yadkinville PO Box 816 Yadkinville, NC 27055 Receive Date: 02/27/2020 Reported: 02/28/2020 For: Holding Tank Fecals Comments: GM 4,314 MPN/g STATESVILLE ANALYTICAL Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 200227- 15-01 Fecal Coliforms 1 5755 MPNIg SM92210E-2006 02/27/2020 WC 200227-15-01 Percent Solids 1 1.39 ova SM2540B-2011 02/27/2020 WC 200227-15-02 Fecal Coliforms 2 3030 MPN/g SM92210E-2006 02/27/202C WC 200227-15-02 Percent Solids 2 1.32 % SM254OB-2011 02/27/2020 WC 200227-15-03 Fecal Coliforms 3 2899 MPNIg SM92210E-2005 02/27/2020 WC 200227-15-03 Percent Solids 3 1.38 % SM25408-2011 02/27/2020 WC 200227-15-04 Fecal Coliforms 4 6299 MPN/g SM92210E-2006 02/27/2020 WC 200227-15-04 Percent Solids 4 1.27 % SM25408-2011 02/27/2020 WC 200227-15-05 Fecal Coliforms 5 3390 MPN/g SM92210E-2006 02/27/2020 WC 200227-15-05 Percent Solids 5 1 18 % SM2540B-2011 02/27/2020 WC 200227-15-06 Fecal Coliforms 6 3478 MPN/g SM92210E-2006 02/27/2020 WC 200227-15-06 Percent Solids 6 1.15 % SM254oe-2011 02/27/2020 WC 200227-15-07 Fecal Coliforms 7 7407 MPNIg 6M92210E-2006 02/27/2020 WC 200227-15-07 Percent Solids 7 1.08 % SM25408-2011 02/27/2020 WC Respectfully submitted, rU� *'O" ` `' Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 Condition of Receipt Sample Number 200227-15-01 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-02 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-03 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-04 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-05 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 2 of 4 Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-06 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab Sample Number 200227-15-07 Temp on Arrival: 3.2 Parameter Schedule: Percent Solids Received on Ice Parameter Schedule: Fecal Coliforms Sodium Thiosulfate Received on Ice Chemicals in containers, lab PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 3 of 4 N 1 05 --.33G 6r rSit -d50- Phone � 21 FAx lPsraan.�i2A.�— r RequWW*d by: tic ors I ro tiamrHal DNS 9�npNd pM1M laWO0 Relinquished by: l Received by: Relinquished by: Received by: Compgoite Sampling art; . Time begin am, pm Date —l_I_ Time and am, pm Date Composite SwWlln9 02: Time begin am, pm Date Time end am, pm Date _ /_J— STATESVILI.k:ANALVIII AI. 122 l',wn Sow • PO ikn 22B %Wksv lk. NC 29667 (714)972 /697 Chain of Custody Record PA�a+ nrrynleJ rw rul f y+ _ Time 10 Pm Date ? l l�Q Sampled by: N z 111G � Time Ic 21 6pm Date _/�, Transported by: BA/ Time am, pm Date _!�/_ Holding times met: Time am, pm Date Compliance work: Non-compliance work: Lab COMTOW Samosa Ttwm* W On 10 lnWds: rn w rV O r- V 0 11 O t` 00 1" lV U z 4J 05 ,n 00 fV f'V X O Co Q a Daw in 103405 olieli _ �T� l a _ _ _ DMe In §fit use: � 1,2 , c rage in 103405 aver: [ 4 q c - _ To* In SM Ammme: �. .I�-- Ta Ott 103-105 Time OLd 550 UUM: — WL 1 2-A 0 vm sanoe vol. L r XXW C4,�) USE INITIAL AND FINAL AVERAGES OF YOUR % VOLATILE FRACTION TO CALCULATE THE PERCENT REDUCTION (USE THE VAN KLEECK FORMULA) van %% etwo !ram 96 dol. frac. -Final 96 fnmw % Vol- frac, - vol. €rac. X 100 % dctim (irttti� % v+ol, frac x Final % vol. ftac.) minus fl [7 tithes Do MU�ication inside K )] before you subtract 3 bttract o bottom of equation, r O�7641— C 76 SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Yadkinville WWTP Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied YK-35-1 5.4 1.1 T/Ac. 1.1 06/20/20 YK-33-2 6.9 O.OT/Ac. YK-33-3 6.3 0.0 T/AC YK-33-1 5.8 0.5T/Ac. *Lime will be applied when conditions improve. SECTION 7 Page 1 of 1 Report No: 21-004-0517 Account No: 12259 Advisor: Synagro/Columbus NC Mary Brewer 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: James Hobson 2020 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: 4K-33-1 Date Received:01/04/2021 Date of Report: 01/05/2021 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na 109907 1 MIN 1.7 5.8 0.9 27 15 81 63 58 0 195 195 110 4.8 82 57 22 1.3 0.1 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Zn Cu B Mg Last Crop 1- Fescue Hay Ib/acre 0.5 150 74 111 20 0 0 0 0 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032838 Client: James Hobson Advisor: Predictive 3541 Apperson Rd East Bend, NC 27018 Mehlich-3 Extraction Soil Report Sampled County: Yadkin Links to Helpful Information Client ID: 493738 Advisor ID: Sampled: 06/01/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: yk-33 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.5 120-200 0 100 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.22 1.14 5.5 76 1.3 5.6 96 20 50 25 70 102 78 251 251 166 0.1 2 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.4 120-200 90 120 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.22 1.01 4.5 77 1.0 5.6 22 13 55 20 150 54 49 117 117 94 0.1 2 Noah Carolina i� Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32838 James Hobson Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031452 �5{i �141..tiL Client: Roger Davis Advisor: Alex Fox Predictive 284 Boger Road Synagro ;• Mocksville, NC 27028 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Yadkin Links to Helpful Information Client ID: 508843 Advisor ID: 501947 Sampled: Received: 05/29/2020 Completed: 06/05/2020 Farm: YK-35 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.1 120-200 0 0 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.71 0.95 8.6 74 2.2 5.4 139 103 43 25 69 198 136 546 546 177 0.1 1 Noah Carolina fdtaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO31452 Roger Davis Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005777 �5{i �141..tiL Client: Alex Fox Advisor: Alex Fox Predictive Synagro Synagro ;• 284 Boger Rd 284 Boger Rd $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County: Yadkin Client ID: 501947 Advisor ID: 501947 Sampled: 09/21/2020 Received: 09/24/2020 Completed: 10/02/2020 Farm: YK-29 ( Town of Yadk Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 130 50 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.09 1.02 6.7 87 0.8 6.1 7 44 51 34 41 337 218 65 65 45 0.1 1 Noah Carolina i� FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005777 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm