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HomeMy WebLinkAboutWQ0002712_Residual Annual Report 2020_20210222Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* W00002712 Applicant/Permittee City of Lincolnton Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office Mooresville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00002712 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * City of Lincolnton RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for City of Lincolnton, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Lincolnton NC 2020 Annual Report FINAL.pdf 32.62MB Upload only 1 FCFdocurrent (less than 250 fvB). Miltiple documents rust be contained into one F7Ffile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/22/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 22, 2021 NCDEQ Division of Water Resoures Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0002712 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the City of Lincolnton, NC. If you have any questions or need additional information, please do not hesitate to contact Robert Pearson at (704) 736-8940 or Alex Fox at (336) 703-8681. Sincerely, oe"i& Shuuc" ,es Derrick Shivar Environmental Compliance Manager Enclosures cc: Robert Pearson, City of Lincolnton Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF LINCOLNTON, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0002712 2020 ANNUAL REPORT City of Lincolnton, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00002712 County Lincoln Year 2020 Facility Name (as shown on permit) City of Lincolnton WWTP and WTP NPDES No. NC0025496 & 0085588 Land Application Operator Synagrro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to PartC. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 33 Total number of fields utilized for land application during the year: 15 Total amount of dry tons applied during the year for all application sites: 666.34 Total number of acres utilized for land application during the year: 360.38 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. if. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Robert Pearson, Water Services Director Permittee Name and Title (type or print) ign tune of Permittee Date Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 LINCOLNTON, NC LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS January 2020 204,600.00 G 17.66 D 16.02 February 2020 204,600.00 G 17.66 D 16.02 March 2020 210,800.00 G 18.20 D 16.50 April 2020 688,200.00 G 82.08 D 74.44 May 2020 452,600.00 G 53.98 D 48.96 June 2020 551,800.00 G 65.81 D 59.69 July 2020 427,800.00 G 92.05 D 83.49 August 2020 198,400.00 G 42.69 D 38.72 September 2020 706,800.00 G 152.08 D 137.94 October 2020 235,600.00 G 25.74 D 23.35 November 2020 644,800.00 G 70.45 D 63.90 TOTAL 4,526,000.00 G 638.39 D 579.02 LINCOLNTON, NC WATER PLANT LIQUID MONTH/YEAR July 2020 1r•1r_111111 AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 117,800.00 G 27.95 D 25.35 117,800.00 G 27.95 D 25.35 Report Date: 2/2/2021 8:43:24 AM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00002712 Facility Name: LINCOLNTON, NC Residual Source WQ # or NPDES#: NCO025496 WWTP Name: LINCOLNTON WWTP Laboratory: PACE ANALYTICAL; Waypoint Analytical Virginia Inc. Residual Analysis Data Product Type LIQ LIQ LIQ LIQ Sample or Composite Date 01/07/20 04/01/20 07/01/20 10/01/20 Parameter (mg/kg dry weight) Ceiling Cone. Limit Percent Solids (%) NA 2.07 2.86 5.16 2.62 Arsenic 75 <23.8 7.7 4.4 7.9 Cadmium 85 <4.76 <0.73 <0.4 <0.79 Copper 4300 263 230 160 390 Chromium NA 51.4 61 37 81 Lead 840 <14.3 11 8.2 20 Mercury 57 <0.705 <0.68 <0.36 <0.75 Molybdenum 75 <11.9 7.3 3.7 8 Nickel 420 <11.9 15 7.9 20 Selenium 100 <23.8 6.1 3.7 11 Zinc 7500 269 230 150 370 Total Phosphorus NA 27300 15000 10000 22000 TKN NA 80500 33000 42000 60000 Ammonia -Nitrogen NA 35400 13000 7900 22000 Nitrate and Nitrite NA 714 525 48.1 175 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personn r perly gathered evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possi ity o fnes and im r' on ent for knowing violations." Signature of Preparer' Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 2/1/2021 10:36:58 AM For: 2161 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: W00002712 Laboratory: Facility Name: LINCOLNTON, NC PACE ANALYTICAL; Waypoint Analytical Virginia Residual Source Inc. NPDES # or WQ#: NCO025496 WWTP Name: LINCOLNTON WWTP Residual Analysis Data Product Type LIQ LIQ LIQ LIQ Sample or Composite Date 01/07/20 04/01/20 07/01/20 10/01/20 Parameters (mg/kg dry weight) Aluminium 10800 15000 7200 19000 Calcium 11800 9400 5800 13000 Magnesium 5140 4500 2600 6200 pH (s.u.) 7.50 6.70 6.80 7.00 Potassium 10100 7800 3500 7900 Sodium 4300 3400 720 2600 PAN 27414 11025 10818 18775 SAR (Ratio) 1.1921 1.2162 0.4468 0.7576 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personn r perl thered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possib' y o fine a imprisonm or knowing violations." Signature of Preparer Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2/1/2021 10:41:03 AM For: 2161 01 DENR FORM RSSF-B (12/2006) Waypointo ANALYTICAL 1 / 16/2020 Synagro Central LLC/ Lincolnton Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-008-0011 Project Description: Lincolnton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/8/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 5 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-008-0011 Client Project Description: Lincolnton WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 70114 Lincolnton WWTP Solids 01/07/2020 13:45 01/08/2020 SM-4500-NH3C WP MTN 9045D WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN SM-2540G WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 5 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46467 Synagro Central LLC/ Lincolnton Mary Brewer Project Lincolnton WWTP Report Date : 01/16/2020 284 Boger Road Information : Received : 01/08/2020 Mocksville , NC 27028 Pam« mL 60wr Pauric McGroary Report Number : 20-008-0011 REPORT OFANALYSIS Agronomist Lab No : 70114 Matrix: Solids Sample ID : Lincolnton WWTP Sampled: 1/7/2020 13:45 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 97.9 % 0.010 1 01/12/2013:29 ADM SM-2540G Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 35400 mg/Kg - dry 4760 1 01/15/20 14:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N 714 mg/Kg - dry 231 1 01/14/20 14:53 ZBD 4500NO3F-2011 Organic N 45000 mg/Kg - dry 11900 1 01/15/20 10:00 CALCULATION pH 7.5 S.U. 1 01/14/20 05:41 JSL 9045D Total Solids 2.07 % 0.010 1 01/12/20 13:29 ADM SM-2540G Total Kjeldahl Nitrogen 80500 mg/Kg - dry 11900 1 01/15/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 27300 mg/Kg - dry 238 1 01/11/20 02:17 KKM 6010D Aluminum 10800 mg/Kg - dry 238 1 01/11/20 02:17 KKM 6010D Arsenic <23.8 mg/Kg - dry 23.8 1 01/11/20 02:17 KKM 6010D Calcium 11800 mg/Kg - dry 1190 1 01/13/20 18:58 BKN 6010D Cadmium <4.76 mg/Kg - dry 4.76 1 01/11/20 02:17 KKM 6010D Chromium 51.4 mg/Kg - dry 11.9 1 01/11/20 02:17 KKM 6010D Copper 263 mg/Kg - dry 11.9 1 01/11/20 02:17 KKM 6010D Iron 10500 mg/Kg - dry 238 1 01/11/20 02:17 KKM 6010D Lead <14.3 mg/Kg - dry 14.3 1 01/11/20 02:17 KKM 6010D Magnesium 5140 mg/Kg - dry 238 1 01/11/20 02:17 KKM 6010D Manganese 274 mg/Kg - dry 23.8 1 01/11/20 02:17 KKM 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 5 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46467 Synagro Central LLC/ Lincolnton Mary Brewer Project Lincolnton WWTP Report Date : 01/16/2020 284 Boger Road Information : Received : 01/08/2020 Mocksville , NC 27028 Pam« mL 60wr Pauric McGroary Report Number : 20-008-0011 REPORT OFANALYSIS Agronomist Lab No : 70114 Matrix: Solids Sample ID : Lincolnton WWTP Sampled: 1/7/2020 13:45 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Mercury <0.705 mg/Kg - dry 0.705 1 01/10/20 15:02 TJS SW-7471B Molybdenum <11.9 mg/Kg - dry 11.9 1 01/11/20 02:17 KKM 6010D Nickel <11.9 mg/Kg - dry 11.9 1 01/11/20 02:17 KKM 6010D Potassium 10100 mg/Kg - dry 238 1 01/14/20 18:47 BKN 6010D Selenium <23.8 mg/Kg - dry 23.8 1 01/11/20 02:17 KKM 6010D Sodium 4300 mg/Kg - dry 1190 1 01/11/20 02:17 KKM 6010D Zinc 269 mg/Kg - dry 59.5 1 01/11/20 02:17 KKM 6010D Sulfur 8860 mg/Kg - dry 238 1 01/11/20 02:17 KKM 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 5 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46467 Customer Name: Synagro Central LLC/ Lincolnton Report Number: 20-008-0011 Shipping Method ® Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/08/2020 13:52:49 Page 5 of 5 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton VWVfP Lot Number:VD02102 Date Completed:04/13/2020 MIM�� Mr� 04/15/2020 4:43 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VD02102 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids sample -001 was weighed out at 3 times the normal amount. The LOQ has been adjusted to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VD02102-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:04/01/2020 0945 % Solids: 2.86 04/08/2020 0043 Date Received:04/02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (% Solids) SM 2540G 1 04/08/2020 0043 MOM 50147 1 350.1 (Ammonia - N ) 350.1 10 04/06/2020 1338 DMA 50065 1 (Nitrate - N ) 9056A 1 04/08/2020 1713 HKL 50477 1 (Nitrite - N ) 9056A 1 04/08/2020 1713 HKL 50478 1 (Phosphorus) 365.1 10 04/06/2020 1620 DMA 04/06/2020 1221 50071 1 (Soil pH meas) 9045D 1 04/07/2020 1940 SRB 50256 1 351.4 (TKN) 351.2 1 04/07/2020 1525 DMA 04/07/2020 0952 50060 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.86 % 2 Ammonia - N (gas diffusion) 350.1 13000 350 180 mg/kg 1 Nitrate - N (soluble) 9056A 35 18 0.86 mg/kg 1 Nitrite - N (soluble) 9056A 490 7.0 0.67 mg/kg 1 Phosphorus 7723-14-0 365.1 15000 1800 350 mg/kg 1 Soil pH measured in water @ 21.9 ° C 9045D 6.7 su 1 TKN 351.2 33000 880 880 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 04/07/2020 1109 KSH2 04/07/2020 0517 50143 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.8 0.68 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601 OD 1 04/07/2020 0849 LLL 04/04/2020 1320 49964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 15000 230 87 mg/kg 1 Arsenic 7440-38-2 6010D 7.7 J 8.7 2.9 mg/kg 1 Cadmium 7440-43-9 6010D ND 2.9 0.73 mg/kg 1 Calcium 7440-70-2 6010D 9400 2900 360 mg/kg 1 Chromium 7440-47-3 6010D 61 5.8 1.5 mg/kg 1 Copper 7440-50-8 6010D 230 5.8 2.6 mg/kg 1 Iron 7439-89-6 6010D 14000 58 26 mg/kg 1 Lead 7439-92-1 6010D 11 5.8 2.6 mg/kg 1 Magnesium 7439-95-4 6010D 4500 2900 360 mg/kg 1 Manganese 7439-96-5 6010D 220 8.7 3.4 mg/kg 1 Molybdenum 7439-98-7 6010D 7.3 J 23 5.8 mg/kg 1 Nickel 7440-02-0 6010D 15 J 23 6.1 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VD02102-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:04/01/2020 0945 % Solids: 2.86 04/08/2020 0043 Date Received:04/02/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/07/2020 0849 LLL 04/04/2020 1320 49964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 7800 2900 360 mg/kg 1 Selenium 7782-49-2 6010D 6.1 J 12 4.7 mg/kg 1 Sodium 7440-23-5 6010D 3400 2900 360 mg/kg 1 Zinc 7440-66-6 6010D 230 29 7.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC t I � Sim Kb CF n h= v CA 13 A E m A S€Os GO Ff CJ COW C -�tlun A ti c 2 2 m Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC 511wly1-r.virmnr..nnI5l`Nle,%.lnc, 7gC 1LPL Sample Receipt Cheddiist (SRC) Chert= cooler lwgnocr d by/date- ynu: i C41fM2U-0 Lott VM102 VVM3 of receipt: BEST Utient [l UR 0 FedT'�c paler; Yes �J No 1- wvr4 4u stod>s^eals p�cssee7= on tha uaoJrr'f Yes N� hDrl 2. Jfcustcd 'seals xere rc�cn� �s'!:� [key i]tt21c# aLtd uuranol<rrL7 PHShip ID; NA Chlorkic SLrip f3); ETA Tested by ttiA. 4iglrl131 #MmpQ'aWM anon raceiPl. i DL:-D',nd (CfiirecWd) tempea-D(Ltri-, upon- raxi-3- "Insalid $nap -GULP ]0! l904 .23 5.0 }S,Q CC KA jNA °C NA ; NA `C TEA INA ¢G _ Mclbod- LlTempeintore Blank f 1Agatst Bottles- IR C Gan ID- 5 IR UrL C ormc-tion Factor, 1) DO Mebod nfcoolant' _ 0 Vdot Ire I] Jce Packs 0 D' Tut: © Norke — [� U'�s ❑ Ho ONA, a. Iftcltlperaturp of any cooJer excr�;;ed6.0°C. wea project Mat�6TrNotifled? PLYL Viko Notified by-! pltame ennui] ? faoo-tea-fact (circle one)- fYcs ❑ No 0 h1.4 4, is the rnr-Imeroial euuricr'€ pErking Ap atrachM la this tbrm? ® ' ❑ No 5- Were p:xaPer UkISt0 dy P+ DWdlarJ;s (J+:Jinquisrwx_ ilreoei sc1) followed? - ® 1`es 0 6. Were saJe ]Ds Iistcd on the C:r}C,r m Ycs [J No 7. rrc surer* ]Ds lisred on al] wrnpk contairre� � ® �'cs ❑ Tti O 8, leas C01 lection 4DW & tirne J i shed cn the COC? Yes -No: 9, WascoJlecaan date&. tb),e li.;torun all 4amplccon:a'Dem'r ® y& ❑ Ja 10- Did all oant"er label info r nAaion (II), date, Lima) agivu with the CD 9 71Yes El Nu 11. G'CrC tests Eo aL: p�f;}ltn ]rstnd ay the Co(~? ® Yes ❑ No 12. Did dI sampJea arrive 2r, r)e proper Containers fo- eacal test �Wftr in gOfA cnnd'tion {unbroie,l, '.its 0r4 etc.)" ® Ycs 1]aL 13_ Was adNuale sample .xdvrne i1vailftblc? Yes Two 14. Were i41J sale ir4 rmxL�Lved within'Athe 101ding time or 4B _you.- wh[Chaver conics tinst2 'es ONo 15. V.'ere any Narrlprex containers inizin cxucss (circle mc`j sar,E iln Nor listed on COG'? ❑ 'es Q ND ®NA 16, Frx VOA and RSK-175 sam.pk.s, were' Ubr0]c5 presell' Ea-siza: (a"or 6ront iEzdiarneL In any of the VOA vials? f y Na NA 17- Were all rDRCOkmlid-sir lltrient se,slplcs receives Ftt a pH of r 27 ❑ Ycs ❑ No ® NA I S. W4�rc ail cyanide, sans A res ree6vcd ar a I -I � 12 aid so le sain res re"ived at a pH > 9? ❑ 1'es ❑ Na 60Nrl 13, 1Nere all apt; JL IcN a?1KNiGy31n� e ; erloUb25 ( O.Sm1;{L}sanip es free nFre�i ❑ 20. Wire crigryt rClttar]C u+rc�u� 9tg (i.e- tegaestcd di Yes lLILittrls, L4'SNISD desifmatians, etc, Q Two � N � carcrly trii ed C]Y7�, Illc U01C tt1Lu the CDrrri It 5=1011 in LIMS? J Yes Nn 1,erdli59Was (ha QUOtC nitmierIIsted on Un4c mtainerlahel? If ves, Quota 4 NA ;xmlrle. [ MIe rvatiors (Must be eamplotcd€a'21iiy Aample(s) nticornx[ly preserved o-wid7 h ad.pauL, j «1r'+t;t5) L �2L_ u r4' rrxoived inmrently prc-oervcd and werb adjusted arzu4iniinagly szrtpic rcceiving with NA rnL of circle ona: I-D-804, NNU3, I -ICI, Nita li usilig SR # i+rA Inc of pres*rvanion MA If mode than one prescrvativo isne.Qak�d, pk_me nolr. hittecoltLurrrus below. nplEs(s} L4 were rceoia;d tv ith bubb:os >6 m m in dJ3lneter. mpJei(s) NA were trreivad kvith 7'KC > 0-: Mg!� (If* 19 iq ua } and were LEsted aCC ndingJy in sairpJe rare Iving will, sn.dium thiosul fate Fa,S p) w=tri 5kr ly II?: NA barco&- lobcls applimi *_ T WC'r Lal([; 044.2 MD C;13111IMMis; Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:VG02032 Date Completed:07/13/2020 NIM�� Mr� 07/13/2020 5:00 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VG02032 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids, sample -001 was weighed out 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VG02032-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:07/01/2020 0845 % Solids: 5.16 07/06/2020 2227 Date Received:07/02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 07/06/2020 2227 MOM 59064 1 350.1 (Ammonia - N ) 350.1 10 07/08/2020 1434 DMA 59280 1 (Nitrate - N ) 9056A 1 07/08/2020 1523 AMR 59434 1 (Nitrite - N ) 9056A 1 07/08/2020 1523 AMR 59435 1 (Phosphorus) 365.1 25 07/10/2020 1312 DMA 07/10/2020 0837 59501 1 (Soil pH meas) 9045D 1 07/07/2020 1900 SRB 59210 1 351.4 (TKN) 351.2 1 07/10/2020 1449 DMA 07/10/2020 0934 59571 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 5.16 % 1 Ammonia - N (gas diffusion) 350.1 7900 190 100 mg/kg 1 Nitrate - N (soluble) 9056A 40 9.7 0.48 mg/kg 1 Nitrite - N (soluble) 9056A 8.1 3.9 0.37 mg/kg 1 Phosphorus 7723-14-0 365.1 10000 2400 480 mg/kg 1 Soil pH measured in water @ 21.2 ° C 9045D 6.8 su 1 TKN 351.2 42000 480 480 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/07/2020 1950 JMH 07/07/2020 1244 58922 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 1.5 0.36 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 07/08/2020 1832 KSH2 07/07/2020 1514 58921 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 7200 130 48 mg/kg 1 Arsenic 7440-38-2 6010D 4.4 J 4.8 1.6 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.6 0.40 mg/kg 1 Calcium 7440-70-2 6010D 5800 1600 200 mg/kg 1 Chromium 7440-47-3 6010D 37 3.2 0.80 mg/kg 1 Copper 7440-50-8 6010D 160 3.2 1.4 mg/kg 1 Iron 7439-89-6 6010D 8500 32 15 mg/kg 1 Lead 7439-92-1 6010D 8.2 3.2 1.4 mg/kg 1 Magnesium 7439-95-4 6010D 2600 1600 200 mg/kg 1 Manganese 7439-96-5 6010D 160 4.8 1.9 mg/kg 1 Molybdenum 7439-98-7 6010D 3.7 J 13 3.2 mg/kg 1 Nickel 7440-02-0 6010D 7.9 J 13 3.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VG02032-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:07/01/2020 0845 % Solids: 5.16 07/06/2020 2227 Date Received:07/02/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 07/08/2020 1832 KSH2 07/07/2020 1514 58921 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 3500 1600 200 mg/kg 1 Selenium 7782-49-2 6010D 3.7 J 6.4 2.6 mg/kg 1 Sodium 7440-23-5 6010D 720 J 1600 200 mg/kg 1 Zinc 7440-66-6 6010D 150 16 4.0 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC L z z z LO X.w A o_ m C A L d G. Wtv J 7 'w E 8 y �c{ 0 � o v � � - a Tr a i di N } � O c SrSA �lle41DVV � y r WI o z m X 1 2;� a G m � �, � � Ki C3 ❑ � C �j y0 S j[ +f bi a n 4a 45} e -Zip 3 � t- E. o C: h4+1 /{ Q x � FgP�J :E` ) m u� � IP, •a as C ,�.. G, �5 c ,� s 4- Cr rT , 1E m C a � x t j Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC Slice l+' EwhommuWa: 5-mites, Irv. hiL%o t of t Grcu meat FJc-dbyr' 3.1P90] eC-l-1 Crxceve 6xi ,• 9,'2+:61 S Sample Receipt Chccklist ( RQ C tierlt. v C 't [a3_ 1 T--) Y'r, 1— I-,OA.+ram r1,Wd11)j- ' --? 1 1 r u _ t Mcans of recafpP 0 S Client M UPS © );edix OffiL . — ❑ Ye;3 _ 0 ..[I 1, Were c.ustod sea!! mscat o11 the 0001erfi Yt ; LlT+Ttr -Irk 2. If uwsWdy seals were MEent,weTe they intaclt and . nLralcea? $trip TD; IV rc� A— Chlorine Strip ID, �', - Te&l±d by:�ry f inol telleraSuRe trptm receipt I Derived {Conec#ed} teixperatur upon rec$ipc 'J6Suliti Snap -cup JD}i1 Method; OT�mperature Blank ❑Agiinst Bottles IlR Gttn ID; IR Gun C&Tarli[n Yngror; oC Method o: coolant: IaVet lot ❑ Ict; PCtcks ❑ D Ice Q Ntma U Ycs j Ikla ,p" A 3, If Wmperdture of amy cooler exceeded fi (rQ was Plaject tma tagur Nlot fled? PM maw TWuti tied by: ple J e>ua i[ racro-to-face (rircl a onay 4, B tilt commercial calxr[Ws packi rig slip attached to d1is furor? n 1Ym ! 0 No [DNA EF-Yes E] Na 5. Were pTDper a -rtody rooedwas nli�yuishcd(receitred) followod? 6- Were FiSMP14 M8 jig" on the C50 ? e Na i`es ❑ 7- Wero sample Ws listed on all sate to containers',` ❑`Yes ❑ Nu 8. Was wHoctian date & lime lisird to, Ibis (M? Yet o 9. Was collectian d®te & time hstcd.m all samnla cuatainaS? © YOS 0 Nt} 10. Did A cturtatnt:r lsl;6l itllfb!' 6fttiou (II]: date, Lunt) agree with the CC)('? es ❑ NO 11. W= Costs to be perfx,rimnd li:Acd nn the C�DG7 Q" ,x Ll No 12. Did :{l1 Z,ampWS ttrrivo ut the pro -per cantsin(zs far each ttzi andiur in goad condition (nrabroftn, lids on, etc.}? 0-ys9 Zj No 13. Was adequato sample vo1 unte imihib.11 7 7 7cs ❑ No 14_ Were pie simples received witbip'ri the how litrto ar 48 hours, whichever coquet fr.;[? Yes NO � 1 �. Were an satnplvs arntain�s mis9iipt� ens {circle t7nr snot les 7+ltal ]ix[crt an t�OC? Yes [� No riIA I16, For VOA and R9FC-175 samples, w�ete IAibbLi present:}°`Cea-Sind' C/�"or 6trim in diameter] Itt arty of tho VOA vials? ❑ Yt!s LJ No LJ NA 117, Were al I DR(}Jmetaa3slamrient yptn plus received at d VH iDf < 2? El 1(e� 1 o V QNA 18. Nettie W1 cyanide mmvleS rectyvcd at a pii > 17 and sulfide bum Its received at a } g ❑ ❑Na Ycs 19, ere all applitatbioN 3lTKN?cvap p anol,662 { o,5m 11� samples cc a rtsealu�l L3'N A _ chlorine? © Yes El No Wero cikU =arks lrcg sm (i,a rogttested-Muiiuns, MSe MSD dettigriaxio�lw, etc...) c wredly llunstaibedfrom the COC' intp the commcat 9ock-0n in LAMS? 121 Ll Y� - Vhl� alit quotc number limcd on the container Jabal? If YES. Quolc M NA S;imp1e.PreAcl-,f,Ation (Must be. Gotnpluk%d foT any mmllle(a) iacorreWy prescrycd or meth head9pace,} - sample(s) I� lVc1' fCC1:3'Qd II440t1OCtly' pre t rvad artcl u r adjusted ati}tarclinly in -sample rw:t+MnZ with _ mL of circle ors I12SO4, HNW, HC4 Na0H using M # r + . rime Opreservation 12t_ _, If m�rre thkH onetrs perwativc i� neeried, pleasena� in fet-�anments lat below. arnple(s) - were ircco ved with bubbles >6 mm in d1amcter- ampl*s) _ W WC Mc3eived �u [th TRC > 4,5 ,mg,'I, (7f # l9 is >'to ) wed Were 4115tad acconlill�ly in Ample ]'eceiving with sodium th ioaulfm (Nax5203) with Sealy ID. )t barcada Labels appIkd by. Iv�} Z_ Dote, ) 11Pjti tUI . i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:VJ03016 Date Completed:10/12/2020 NIM�� Mr� 10/13/2020 4:01 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VJ03016 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low % solids, the initial amount used for sample -001 deviated from the standard procedure. The LOQ has been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VJ03016-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:10/01/2020 0900 % Solids: 2.62 10/05/2020 2313 Date Received:10/02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (% Solids) SM 2540G 1 10/05/2020 2313 MOM 68892 1 350.1 (Ammonia - N ) 350.1 25 10/09/2020 1544 DRD 69087 1 (Nitrate - N ) 9056A 1 10/10/2020 0235 AMR 69482 1 (Nitrite - N ) 9056A 1 10/10/2020 0235 AMR 69483 1 (Phosphorus) 365.1 25 10/08/2020 1622 DMA 10/07/2020 1133 69153 1 (Soil pH meas) 9045D 1 10/06/2020 2235 SRB 69036 1 351.4 (TKN) 351.2 1 10/07/2020 0942 DMA 10/06/2020 1406 68936 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.62 % 2 Ammonia - N (gas diffusion) 350.1 22000 950 500 mg/kg 1 Nitrate - N (soluble) 9056A 130 19 3.8 mg/kg 1 Nitrite - N (soluble) 9056A 45 7.6 3.8 mg/kg 1 Phosphorus 7723-14-0 365.1 22000 4800 950 mg/kg 1 Soil pH measured in water @ 20.3 ° C 9045D 7.0 su 1 TKN 351.2 60000 950 950 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 10/05/2020 1345 JAB2 10/05/2020 0938 68766 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.1 0.75 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 10/08/2020 1406 KSH2 10/07/2020 0847 68742 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 19000 250 94 mg/kg 1 Arsenic 7440-38-2 6010D 7.9 J 9.4 3.1 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.1 0.79 mg/kg 1 Calcium 7440-70-2 6010D 13000 3100 390 mg/kg 1 Chromium 7440-47-3 6010D 81 6.2 1.6 mg/kg 1 Copper 7440-50-8 6010D 390 6.2 2.8 mg/kg 1 Iron 7439-89-6 6010D 20000 62 28 mg/kg 1 Lead 7439-92-1 6010D 20 6.2 2.8 mg/kg 1 Magnesium 7439-95-4 6010D 6200 3100 390 mg/kg 1 Manganese 7439-96-5 6010D 380 9.4 3.7 mg/kg 1 Molybdenum 7439-98-7 6010D 8.0 J 25 6.2 mg/kg 1 Nickel 7440-02-0 6010D 20 J 25 6.5 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VJ03016-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:10/01/2020 0900 % Solids: 2.62 10/05/2020 2313 Date Received:10/02/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 10/08/2020 1406 KSH2 10/07/2020 0847 68742 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Potassium 7440-09-7 6010D 7900 3100 390 mg/kg 1 Selenium 7782-49-2 6010D 11 J 12 5.1 mg/kg 1 Sodium 7440-23-5 6010D 2600 J 3100 390 mg/kg 1 Zinc 7440-66-6 6010D 370 31 7.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC IM"ri = MK1- y; � % r;atimru �". I•f JWO EUWjUn LESrpr�M 1 Y - } !I.WJdgl w S•i z 1 l' � 1�5'�•�: Iniplinnirr kwL f myu 4 '41ti 9p!14S},x;a.la��eol x ' � �� AJ-l9M • IAN `5 -2 O 13 4' "} s r C] P, �i J,rT F L} k= J �Irz1pra"as'a W4l,Al' ELM, gd'lu Oti.6 K --- I ---- 'Iery'pD'a iv-131 ul�ts Iv•ta n i:no � t f.?' '' Rd �B16n 3A1L �� E � �� '�:i.' .�kr �, F lalllt� � a a 5' zi � - I 6 � ,e s ; wOriO}"f�4�Ya11J:.EFIaTNS ° V' � �k IL i[ w O O B F y{ W 4Y w 5 I � i �� ' latirra o��:ol �d•kL37a'M:'8 ti+ S � � � iy�'�Hfi'•w�4 iIIIY.}i6kiL7�i N� ;L_ Fsi 1 ..jn a � { +F EIL f 41 c e c7 L c Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC Samples Re c6pt Checklist (SRC) i MEOOISC-15) P ceAr�a!MCal Issu ing Authority: Pace EN:' - WOOL Sample Receipt Checklist (SRC) C::icnt: S%fNAGRO Cooler Inspectcd {dke: 1dot 0; VL'WksOfreceiPt: RaCA Am, LJTJPS J FedEx od=: QyfY�'Sl ONL'I 1. Were umJody seals oil tho molt:O Lj Yefi No l A 2- If custody Sea18 Were preSGRI, Wt:M the Y :IltUt Ud un'334343k n} .l:1lStrip ID: WA -._ C.h1orinc91ripID- NA _ Tested by:AA CkigirkaItcmperolurc upon receipt! E:tcwjvrd, (Corrected)1rmp-rat NuFtln Tmt!;IJl S'6 Im Rat fl.9 +0.9 cC NA {ALA WA INA ziC NA 121.7 L)c Wank J❑A �attlos I R Gutt ID � 1R Uun C:r,rsalion T h ffiosi ❑Teanpc- hmc in st � � M-ethad cf coolant; ❑ Wet its Ice Neics 2a lee ❑ Non.- y(c; ❑1ti ©111 3. If =nperaituro of ary ooalel' emeaded 6.0'C, was Project Managed' I ❑ 13M was lNotiFied bo! phabe! einail J fac 40- ace (circle one}. Yes a No Di( KA 4. Is the CwmTnwc: uj cx,w-ier's pac-L4 slip atrwhar to this torus? Yesi Ll No 5_ 'Nero pm[ er cu9" procedure3 (rc1ing0s1xdfieaeived) follow-od? , ej Y'es; El ' l'3 6. W.;rc sample IT?M Bated cal the COC? MY-831 ❑ No 7. WarasarnpTe lDs 3i3ted on alJ 38mp1cam xiuCi_,? ,r Ycs LANd R. was eoliectitan date & tim: listed on No COC? 0 y v5 No 9. Was 4:gihxAi�u dzie &. time HsW m a:] sample cantaittcrs'' F Yam - ! 111. 10. Did all container label infxxm Liwi (ID, dx-le, time) agree witli the-f �I Y., N, 1i.Ocrc iust4 to be -jerfarined listed w the-COC) Revised ;9J291 %net] Rage 1 of ! WOR16 4CurlD- M-2W6 l Lctor.4 °O ;]Aires]? ❑ Yes ❑ No 12- Did all samples mTim j the puxl}wa' covairxe:T far each test aridlar in goad condition (11phrrALm, li hi oil. eM-):`," V E -1 13, Was adequffiesampic volume ltvallab!0 n J` y I INO 14,'K!re R1I carnple!� received wkNn'A the holding tiSnn or49 hours, Aic,hovor owns fiFA*- IDyu Ld No 15. WerC =y EM les cor~tai„xTS m isyio exce5; (circle ale) sauy-Dl(;s N i)t 1 isted on C:iwC ? , Yes ❑W.0 mNA 16. Far VOA andRSK-175 sample;, viprebubblcs xwrnl.,t--sai're":('!4°'orGnuu in diamete=) in any of the VOA vials'' i rl Yee Lj No NA 17_ Were a] I DRCYrr eta Autriugl; Kant es recetvad at a T>F1 of < 24 i Q Yos No NHS 18, VA�re all cy auide sarrl les rem.- i vi_d Mt a p14> 12 wid sulfide salnp]CS S`' aivEd Al. a 1 I I > 9'? L— 19- Wert al I asp tca�,?Tj-',Nr`cyar�id�+phetlaLrb25.Vzb.3 {C 1 5TI(W.) :satn[Pler free o ❑'rus LJtK13 2NA ru3idual €hloritle$ _ A 20. War-.cliunt r-,.= rks,'riegoe�ts (i.e-1-eqLested dilations, M'3eMSD designations, o.c,..) El Yes n `' ONemraull transcribed from Ilu: COC into the cotnment s:.ctiM ]n LIMB 't!' J TI Lr 12 I, Wa: the cuct3 numbur Jiatcd cm the awWaer 1nbel7 IfvD ot: l� Sample w.w.rvation (MLL=t he cwnplctad fo-r my mmpie(s) iucna' w ly pre3umd or with h and pace.; Samples} were rx;ccived ina3r_eotly prescrrcd and 'orc adjust accorCKRZY ,in swmpie receMiftg with NA nrla oCc:rdt ore_ i2904, HNO3, Ii(,l, NaOJF using SR 0 )4' I Tlrne of preservatton NA if inm-, than 4txe prese-va-irxs is nesr.derl, rl�ease nt3ta in the mipni lts below. Samples) MA were received with bubbles >b min is d:alnem'. Saniples(s) New were r--cc irod with TRC = 0.5 mg,'L (if # 19 is Ku) and veer.- tvlju rtei aorcrrdtn;i}' i]S salrlple ldlrivin with .sodium tllioRulfaoc (Itiu'Ss0.1 +w'ia] Shealy ID= '� i _-•— SR bamude :ahoy S licd AHL) lr.- ro+;rarnit pP b}'� - - Cr4rflnlrntS: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00002712 Laboratory: Facility Name: LINCOLNTON, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: 01-55-010 WWTP Name: LINCOLNTON WTP Residual Analysis Data Product Type Sample or Composite Date WPL 06/22/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 5.69 Arsenic 75 7.9 Cadmium 85 <0.37 Copper 4300 890 Chromium NA 77 Lead 840 14 Mercury 57 <0.33 Molybdenum 75 <2.9 Nickel 420 19 Selenium 100 2.8 Zinc 7500 80 Total Phosphorus NA 6100 TKN NA 7900 Ammonia -Nitrogen NA 840 Nitrate and Nitrite NA 14.7 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, u er penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personn pr perly gathered and e u ed the information submitted. I am aware that there are significant penalties for submitting false information, including the possibi ty o fines and impr' onm nt fo knowing violations." 2 ail zl Signature of Preparers Date `Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 2/1/2021 10:39:02 AM For: 2161 02 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: WQ0002712 LINCOLNTON, NC 01-55-010 LINCOLNTON WTP Residual Analysis Data Product Type WPL Sample or Composite Date 06/22/20 Parameters (mg/kg dry weight) Aluminium 96000 Calcium 1100 Magnesium 870 pH (s.u.) 7.10 Potassium 850 Sodium 1500 PAN 3259 SAR (Ratio) 1.9484 Laboratory: PACE ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possib' ' f fines and imprisonme for knowing violations." 2 z� Signe of Preparer Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 2/1/2021 10:41:47 AM For: 2161 02 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton WTP Lot Number:VF23014 Date Completed:07/02/2020 Revision Date: 07/06/2020 07/06/2020 1:11 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VF23014 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low % solids the initial amount of sample was 3 times the standard procedure amount. The LOQ has been adjusted accordingly. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 PACE ANALYTICAL SERVICES, LLC Sample Summary Synagro Lot Number: VF23014 Sample Number Sample ID Matrix Date Sampled Date Received 001 Lincolnton WTP Solid 06/22/2020 1330 06/23/2020 (1 sample) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 PACE ANALYTICAL SERVICES, LLC Detection Summary Synagro Lot Number: VF23014 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 Lincolnton WTP Solid Ammonia - N (gas 350.1 840 mg/kg 5 001 Lincolnton WTP Solid Nitrate - N (soluble) 9056A 13 mg/kg 5 001 Lincolnton WTP Solid Nitrite - N (soluble) 9056A 1.7 J mg/kg 5 001 Lincolnton WTP Solid Phosphorus 365.1 6100 mg/kg 5 001 Lincolnton WTP Solid TKN 351.2 7900 mg/kg 5 001 Lincolnton WTP Solid Aluminum 6010D 96000 mg/kg 5 001 Lincolnton WTP Solid Arsenic 6010D 7.9 mg/kg 5 001 Lincolnton WTP Solid Calcium 6010D 1100 J mg/kg 5 001 Lincolnton WTP Solid Chromium 6010D 77 mg/kg 5 001 Lincolnton WTP Solid Copper 6010D 890 mg/kg 6 001 Lincolnton WTP Solid Iron 6010D 32000 mg/kg 6 001 Lincolnton WTP Solid Lead 6010D 14 mg/kg 6 001 Lincolnton WTP Solid Magnesium 6010D 870 J mg/kg 6 001 Lincolnton WTP Solid Manganese 6010D 1100 mg/kg 6 001 Lincolnton WTP Solid Nickel 6010D 19 mg/kg 6 001 Lincolnton WTP Solid Potassium 6010D 850 J mg/kg 6 001 Lincolnton WTP Solid Selenium 6010D 2.8 J mg/kg 6 001 Lincolnton WTP Solid Sodium 6010D 1500 mg/kg 6 001 Lincolnton WTP Solid Zinc 6010D 80 mg/kg 6 (19 detections) Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client:Synagro Laboratory ID:VF23014-001 Description: Lincolnton WTP Matrix: Solid Date Sampled:06/22/2020 1330 % Solids: 5.69 06/25/2020 0122 Date Received:06/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 350.1 (Ammonia - N ) 350.1 2 06/30/2020 1224 DMA 58435 1 (Nitrate - N ) 9056A 1 06/25/2020 2341 AMR 58189 1 (Nitrite - N ) 9056A 1 06/25/2020 2341 AMR 58188 1 (Phosphorus) 365.1 10 06/26/2020 1120 HKL 06/25/2020 1059 58049 1 (Soil pH meas) 9045D 1 06/24/2020 2055 SRB 57996 1 351.4 (TKN) 351.2 1 07/01/2020 1703 DMA 07/01/2020 1002 58652 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ammonia - N (gas diffusion) 350.1 840 35 18 mg/kg 1 Nitrate - N (soluble) 9056A 13 8.8 0.43 mg/kg 1 Nitrite - N (soluble) 9056A 1.7 J 3.5 0.34 mg/kg 1 Phosphorus 7723-14-0 365.1 6100 880 180 mg/kg 1 Soil pH measured in water @ 20.8 ° C 9045D 7.1 su 1 TKN 351.2 7900 440 440 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 06/26/2020 0946 JMH 06/25/2020 1257 57821 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 1.4 0.33 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 06/27/2020 1817 KSH2 06/23/2020 1459 57823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 96000 120 44 mg/kg 1 Arsenic 7440-38-2 6010D 7.9 4.4 1.5 mg/kg 1 Cadmium 7440-43-9 6010D ND 1.5 0.37 mg/kg 1 Calcium 7440-70-2 6010D 1100 J 1500 180 mg/kg 1 Chromium 7440-47-3 6010D 77 2.9 0.73 mg/kg 1 Copper 7440-50-8 6010D 890 2.9 1.3 mg/kg 1 Iron 7439-89-6 6010D 32000 29 13 mg/kg 1 Lead 7439-92-1 6010D 14 2.9 1.3 mg/kg 1 Magnesium 7439-95-4 6010D 870 J 1500 180 mg/kg 1 Manganese 7439-96-5 6010D 1100 4.4 1.7 mg/kg 1 Molybdenum 7439-98-7 6010D ND 12 2.9 mg/kg 1 Nickel 7440-02-0 6010D 19 12 3.1 mg/kg 1 Potassium 7440-09-7 6010D 850 J 1500 180 mg/kg 1 Selenium 7782-49-2 6010D 2.8 J 5.8 2.4 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client:Synagro Laboratory ID:VF23014-001 Description: Lincolnton WTP Matrix: Solid Date Sampled:06/22/2020 1330 % Solids: 5.69 06/25/2020 0122 Date Received:06/23/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 06/27/2020 1817 KSH2 06/23/2020 1459 57823 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Sodium 7440-23-5 6010D 1500 1500 180 mg/kg 1 Zinc 7440-66-6 6010D 80 15 3.7 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES. LLC z _ 5 0 It P. I �. m 42 _ 4 � E £Wf L S G LIP C _ t � P1 � 'n - D 2 a+ 141 SEAS m b r3 L - E10azaj E ,fig r C 133 4 CDNH ' r. t j' or E3 !!�� @ E 9 4 E a} if Gnt9n } p w a I~ x ; m ca y a °4 s r w 1D a 1D LM e' 0 9 3 Q ,C ` m 0 ra ? < In .. ` r Y m 10 ' �L r " IL 1.74 CIS Id gr it J1I gI L Gs Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 PACE ANALYTICAL SERVICES, LLC Sltulk ruxirunmeoln %ricer Tnr.. N2r I of l I]acuma;lL ti wnlwr MIND] NC -I S lilli*cti�.ie talc ROM. I it Reecip# Checklist (SRC) [jean: SYNAGRO Cooler Inspected h JdaGa N= r 6'2312420 ] r VF24014 lvtcans of eeceipt! ❑ ST:�T [_lieu{ 0 UPS Q T�cdE �Cither, - a Yes ®No I, 3Vcrc cusmdy seals preon[ on ft cooler? f cs N a NA 2. it custody AeaTs were Eresejjwrrc! Lhuy ir,tsr:t aTul unbroken? L pH Scrip Tr); NA Chlorine Strip TD, NA J u-,cd NA Original iwperriim upon rece,4pt r Dwiwd ( L cad) temllwatwo upon receip', %Scffld Snail -nip 1D: M-302 3 a. 13.7 2C NA INA ce WA }NA Ef, TVA }NA. me — Method: EjTew ralurc Blank mAgahitit Rottles III Gun 1D: 5 _ IR Gun Corroc#ion Fact: 0 Lr' MAthod or`uoolam; ® Wet lee 11 [cc t aMks 0 D ICI: ❑ None ❑ No ®NA 3. !° te7lperalure of any txrolcr t xcaedcd 6-brC ,was Project lwibrl�gr ,o4i Fled? ❑ Ye4y JI PM wars No-% -d h 'aunc i emaiI 1 fa:- l n-liar Yes NA A. is the cornmercied cotiriew's p3eking slip attaukcd tc th:s R)MI? ® Yr.5 Q N-DI S_ Wcr� proper custody ures (rrIii {uimbLx1'-ece:ved) followed'? f Yas El Nu 6. Wera Ram pic ri.]S Rsteed on the GOC? Ytis �] No 7. Were swT,PIc ll)s listed on all Damp-6 c3wi Ww.rs? 0 Y% ❑ No S. War, cnllect[Cn_dzte & tuuc Iisiml on tlue Cpa--? ❑ §'rs %Vns colle b—on date & time listed on al I sampkL contautats" ® Yes ❑ No 10- Did Ml exintaincr label inforrtincioit (ID, date, (imc) agTee jvitls ibe ® Y es ❑ 1+Ta IL WLj a leit� m be Pelf' rmed liste;;i an the CCC? 12- Did all .9amples arrive in the Proper con tohiors fDr ewAm Se5[ dlLYcjr in d ti goonrLdjdnrl cs Q � (Unbroken, .ids on, etc.)? VJ Yes ❑ No 13, %Va� Ledcrluate samplevolumc nvaiIable? Yr..s ❑ No. :4. Wcrc all samples rre fdwd withjtl 7s [hc i1L7101Gtimeor 98 hours, wtti hcvVcr comes tir414 Ej Yes 66 nil 15. WOM any samples c[LaTtr. -Im rr-issin excess (ch-ety unu) sam pies Nei' IisW on COC? ❑ Ye-9 ❑ No O NA 16. For VOA ttnd KSK-175 tamplcs, were buhbks present>"pe�siac" (Wor 6rmn in diamet an any oftlle VOA vials? Q Yes LJ Nol Lfj NAJ I ;- Wt rr aIJ DR01PI"l.lnutriemt e.am pjcs received al p ph of < 22 [f Yt* No � NA 18, Were all a M idc samples =eivcd at a H > 12 and sulfide samples recei vcd tat a pH � 9? Nu ] NA 19' WuE! a anplicmb a• Nm tT&N,'ryanidvphenol M5 ( .5jrrgJTj sHmplas6i a or-s ua[ © Yes - ❑ Yes ❑ Na O NA 20. Wen: cliont rznTa6wr>rquc3rs (Le- requcstod brut:Or1S. MSdUlSD desij,ratious- etc--- j corfecdy Iranyrribed from Cho CQC into the canunen' SeCtion in LIMS? Q Yes NO 21. Was tho quote nuroba listed on Ihta c jnt,ainer 1pl,Lu17 J fves. Uuota #! NA LLII}IC l'reserVAtlori (Moat 1tc it�mpleted for any sample s} inCOYr ctly preSC[VYd or with brad5p�t o Lliple,LSJ tva Wtrareceived inLxwroctlypt'es and and were adja4rp.d according Sawple Fereivingwhh NA mLofcircJPonL H2S(K HNO3, HCI,TraOH usjnc, SR �.' NA m ofprt:verymfion NA If oxore than one plaqerV'41iv1; is needed, please note i11 [[> e-D lnM t5 below, ample(5) NA were r+eceivod wittt bubbiw >6 mm in di. Tnketcr SaLnples(s) NA. — were rxcjvzd u-ith TRC 1 1S MP)L (i€9 is Ho ) and were adjrstt2l accordingly lu .ample rt;meivi% tvhh *O&Um thiasulfatc (Nays W with Shcally JD; NA SR harogde'abais �pp;iax[ by: TwT C. Date; 0&23LWt% Crxnmearts= - Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 SECTION 3 FACILITY NAME: LINCOLNTON, NC LANDOWNER: INVESTMENTS GROUP FOUR OPERATOR: INVESTMENTS GROUP FOUR CROP 1 NAME: SOYBEANS (SB) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) % Month Solids Amount UOM 7/1/2020 148,800.00 (G) 5.160 7/2/2020 161,200.00 (G) 5.160 Jul-20 310,000.00 (G) ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-CA-00024-0-0009- ANNUAL DRY TONS APPLIED: 66.70 SITE #: NC CA 00024 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 160 CROP 2 NAME: Page: 1 ACRES UTILIZED: 17.7 ACRES PERMITTED: 17.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Site Name of Crop Type Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Crop 1 1 Crop 2 Crop 1 Crop 2 DryTons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg 1.811 LIL DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 39.182 SB 1.962 LIL DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 42.447 SB T 1_1 a1 ago n nnn Total 3.773 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penal of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are si cant �� submitting false information, including the possibility of fines and i7.74 nent for knowing violations." Ar --r—( SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation ***' C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ****` See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1 /2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: TURBYFILL PROPERTIES OPERATOR: ELMORE JEFFERY CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W ) Month Amount UOM /23/2020 204,600.00 (G) Jan-20 204,600.00 (G) ------------ inual Ibs/acre Applied Applied o� Solids Dry Tons/Ac 2.070 1.784 ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-CA-00035-0-0002-C ANNUAL DRY TONS APPLIED: 17.66 SITE #: NC CA 00035 PREDOMINANT SOIL SERIES: LOYD CROP 1 MAX. PAN: 132 CROP 2 NAME: Page: 1 ACRES UTILIZED: 9.9 ACRES PERMITTED: 9.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Site Name of Crop Type Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg LIL MOIST "0-<1/2" SUR 1 0.5 0.20T801500 .00 35,400.00 714.00 97.809 n nnn FSP Total 1.784 AS CD CU CR PB HG I MO NI SE ZN 0.085 0.017 0.938 0,183 1 0.051 0.003 1 0.042 1 0.042 1 0.085 0.960 0.253 0.072 8.819 3.139 0.418 0.014 0.282 0.605 I 0.242 I 10.885 P I Lime 97.402 �— Date 132 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre) 36 6 34 8 1 339 0 267.9 1 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of laJ.nalt hathis document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifi offing false information, including the possibility of fines and imprisomnent for knowing violations." 2 -z SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0-1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge 0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/ 1 /2021 FACILITY NAME: LINCOLNTON, NC LANDOWNER: TURBYFILL PROPERTIES OPERATOR: ELMORE JEFFERY CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W ) Month Amount UOM 8/27/2020 31,000.00 (G) 8/28/2020 167,400.00 (G) Aug-20 198,400.00 (G) 9/3/2020 161,200.00 (G) 9/4/2020 49,600.00 (G) Sep-20 210,800.00 (G) ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-CA-00035-0-0003-A ANNUAL DRY TONS APPLIED: 88.05 SITE #: NC CA 00035 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 162 CROP 2 NAME: Page: 1 ACRES UTILIZED: 41.6 ACRES PERMITTED: 41.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Site Name of Crop Type Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual % Residual Dry, Wet, Past 24 Firs. Application lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 Solids DryTons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg 5.160 0.160 LIL DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 3.469 FSP 5.160 0.866 LIL DRY 1'0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 18.734 FSP 0.834 LIL MOIST "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 18.040 FSP 5.160 5.160 0.257 LIL DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 T_a 5.551 AK 7UA n nnn FSP Total 2.117 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific p alties for su`t •=nformation, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF AND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation `*** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 **`"* See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1 /2021 FACILITY NAME: LINCOLNTON, NC LANDOWNER: TURBYFILL PROPERTIES OPERATOR: ELMORE JEFFERY CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-CA-00035-0-0003-B ANNUAL DRY TONS APPLIED: 34.69 SITE #: NC CA 00035 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 162 CROP 2 NAME: Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) % Residual Month Solids Dry Tons/Ac Source Amount UOM 9/3/2020 24,800.00 (G) 5.160 0.606 LIL 9/4/2020 136,400.00 (G) 5.160 3.335 LIL Sep-20 161,200.00 (G) Page: 1 ACRES UTILIZED: 8.8 ACRES PERMITTED: 8.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Site Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 Moist Inches Method* Rate** Rate— mg/kg mg/kg mg/kg MOIST 1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 13.120 FSP DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 72.160 FSP I otai s.av-i AS CD CU CR PB HG MO NI SE ZN Ibs/acre Applied 0.035 0.003 1.261 0.292 0.065 0.003 0.029 0.062 0.029 1.182 Total 85.280 0.000 Lime Applied Pd 831 Date Lbs/Ac ....* .*. Cumulative Ibs/acre Applied 0.237 0.060 21.928 3.330 1 0.535 1 0.019 0.254 0.763 I 0.189 I 11.307 I I I - 162 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre) 36 6 34 8 1 339 0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifi enalties for subm g false information, including the possibility of fines and imprisonment for knowing violations." ul". -,? - z/ SIG9A7URE OF LAND APPLIER DATE NR = Not Reported or Not Required Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 `*"** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/ 1 /2021 FACILITY NAME: LINCOLNTON, NC LANDOWNER: MIKE DAVIS OPERATOR: MIKE DAVIS CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-CA-00048-0-0004- ANNUAL DRY TONS APPLIED: 72.04 SITE #: NC CA 00048 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 17.6 ACRES PERMITTED: 17.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Residual Source Site Cond. Dry, Wet, Moist Precip Past 24 Hrs. Inches Application Method* Volati- lization Rate** Mineral- ization Rate*** TKN mg/kg Ammonia Nitrogen mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Date or Month Gallons (G) or Cubic Yards (Y) or Wet Tons (W) % Solids DryTons/Ac Crop 2 Crop 1 Crop 2 Amount UOM 2.047 2.047 LIL LIL DRY DRY "0-<1/2" "0-<1/2" SUR SUR 0.5 0.5 0.20 0.20 42,000.00 42,000.00 7,900.00 7,900.00 48.10 48.10 Tn4a1 F44.280 88.560 0.000 FSH FSH 9/8/2020 9/9/2020 Sep-20 167,400.00 167,400.00 334,800.00 (G) (G) (G) 5.160 5.160 I otai 4.U%14 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Ibs/acre Applied 0.036 0.003 1 1.310 0.303 0.067 1 0,003 0,030 0.065 0.030 1.22 1 81.863 1 Date L Cumulative Ibs/acre Applied 0.036 0.003 1.310 0.303 0.067 1 0.003 0.030 0.065 I 0.030 I 1.228 _ 216 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre)**** 36.6 34.8 1 1,339.0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe Iti for sub false information, including the possibility of fines and imprisonment for knowing violations! 2fm _q _-tl IGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1 /2021 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: LINCOLNTON, NC WQ PERMIT #: WQ0002712 FIELD#: NC-CA-00048-0-0010- ACRES UTILIZED: 18.0 LAND OWNER: MIKE DAVIS ANNUAL DRY TONS APPLIED: 24.08 SITE #: NC CA 00048 ACRES PERMITTED: 18.0 OPERATOR: MIKE DAVIS PREDOMINANT SOIL SERIES: CECIL CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: RYE SILAGE (RYSI) CROP 1 MAX. PAN: 120 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) % Month Solids Dry Tons/Ac Amount UOM 2/28/2020 105,400.00 (G) 2.070 0.505 2/29/2020 99,200.00 (G) 2.070 0.476 Feb-20 204,600.00 (G) 3/2/2020 74,400.00 (G) 2.070 0.357 Mar-20 74,400.00 (G) Site Cond. Dry, Wet, Moist Precip Past 24 Hrs. Inches Application Method* Volati- lization Rate** Mineral- ization Rate*** TKN mg/kg Ammonia Nitrogen mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Residual Source Crop 1 Crop 2 Crop 1 Crop 2 MOIST MOIST "0-<1/2" 0-<1/2" SUR SUR 0.5 0.5 0.20 0.20 80,500.00 80,500.00 35,400.00 35,400.00 714.00 714.00 27.713 26.082 RYSI RYSI LIL LIL LIL MOIST "0-<1/2" SUR 0.5 0.20 80,500.00 35,400.00 714.00 19.562 0 000 RYSI Total 1.338 Total 73.357 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.064 0.013 0.704 0.138 0.038 0.002 0.032 0.032 0.064 0.720 73.052 Date Lbs/Ac Cumulative Ibs/acre Applied 0.064 0.013 0.704 0.138 0.038 0.002 0.032 0.032 0.064 0.720 120 Permit PAN Limit (Ibs/acre) 1st Crop Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500 0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID in a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am "I certify, under penalty of law, that this document was prepared under my direction or supervision accordance with aware that there are significant An lties for submi 'ng false information, including the possibility of fines and imprisomnent for knowing violations." SIGNAT RE OF LAND APPLIER DATE *'* Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 NR = Not Reported or Not Required * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation **`* C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1 /2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: CHUCK WATERS OPERATOR: CHUCK WATERS CROP 1 NAME: SUDAN HAY (SNH) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) % Month Solids Amount UOM 5/4/2020 86,800.00 (G) 2.860 5/5/2020 68,200.00 (G) 2.860 5/6/2020 142,600.00 (G) 2.860 5/7/2020 62,000.00 (G) 2.860 May-20 359,600.00 (G) F7/812(0,20 117,800.00 (G) 5.690 0 117,800.00 (G) ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-LT-00019-0-0001- ANNUAL DRY TONS APPLIED: 70.84 SITE #: NC LT 00019 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 276 CROP 2 NAME: Page: 1 ACRES UTILIZED: 41.8 ACRES PERMITTED: 41.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Site Name of Crop Type Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 DryTons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg LIL DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 5.461 SNH 0.248 0.195 LIL DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 4.291 SNH 0.407 LIL DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 8.971 SNH 0.177 LIL MOIST "0-<112" SUR 0.5 0.20 33,000.00 13,000.00 525.00 3.901 SNH 0.669 _ LNVPL DRY "0-<1/2" SUR 0.5 0.40 7,900.00 1 840.00 14.70 4.358 nc noo n nnn SNH Total 1.696 Annual Ibs/acre Applied AS 0.026 CD 0.002 CU CR 1.662 0.228 PB 0.041 HG I 0.002 MO NI 0.019 0.056 SE 0.016 ZN P Lime Applied 0.579 38.938 Date L Cumulative Ibs/acre Applied 0.216 0.079 16.176 7.814 0.836 0.034 0.480 1.056 0.194 15.493 276 Permit PAN Limit (Ibs/acre) 1st Crop' Federal C.RLR. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID LIW PL = LINCOLNTON, NC WATER PLANT LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pcles for sub�ttiag€aise information, including the possibility of fines and imprisomnent for knowing violations." 2 - r_( IGNATURE OF ND APPLIER DATE NR = Not Reported or Not Required **` Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge 0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **'* C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/ 1 /2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: CHUCK WATERS OPERATOR: CHUCK WATERS CROP 1 NAME: SUDAN HAY (SNH) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) Month Solids Dry Tons/Ac Amount UOM /2412 220 105,400.00 (G) 2.860 0.952 Jun-20 105,400.00 (G) 7/6/2020 117,800.06 (G) 5.160 1.920 1ul-20 117,800.00 (G) ANNUAL LAND APPLICATION FIELD SUMMARY FORM W Q PERMIT #: W Q0002712 FIELD#: NC-LT-00019-0-0003- ANNUAL DRY TONS APPLIED: 37.92 SITE #: NC LT 00019 PREDOMINANT SOIL SERIES: RIVERVIEW LOAM CROP 1 MAX. PAN: 208 CROP 2 NAME: Page: 1 ACRES UTILIZED: 13.2 ACRES PERMITTED: 13.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Site Cond. Dry, Wet, Moist Precip Past 24 Hrs. Inches Application Method* Volati- lization Rate** Mineral- ization Rate*** TKN mg/kg Ammonia Nitrogen mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Residual Source Crop 1 Crop 2 Crop 1 Crop 2 DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 20.998 SNH LIL DRY "0-<1/2" SUR 0.5 0.20 42,000.00 7,900.00 48.10 1-1 41.547 C9 CAR n nnn SNH LIL Total 2.872 AS CD CU I CR PB HG MO 0 028 ZN P 1 014 66.9i Lime Applied Date Lbs/Ac Annual Ibs/acre Applied 0.032 0.003 1.053 0.258 0.052 10.003 -•--- ***** Cumulative Ibs/acre Applied 0.168 0.068 11.007 6.281 0.742 0.033 0.431 0,805 0.192 14.773 208 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre) 36 6 34 8 17 0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified persomiel properly gathered and evaluated the information submitted. I am aware that there are significant lties for sub. formation, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 «*** * Application Method: SUR -Surface, ]NJ -Injection, SURIN -Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1 /2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: RANDY LEATHERMAN OPERATOR: RANDY LEATHERMAN CROP 1 NAME: RYE SILAGE (RYSI) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-LT-00047-0-0002- ANNUAL DRY TONS APPLIED: 36.16 SITE #: NC LT 00047 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 120 CROP 2 NAME: Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) Month Solids Dry Tons/Ac Amount UOM 3/2/2020 37,200.00 (G) 2.070 0.093 3/3/2020 18,600.00 (G) 2.070 0.047 3/7/2020 80,600.00 (G) 2.070 0.202 Mar-20 136,400.00 (G) 11/9/2020 93,000.00 (G) 2.620 0.295 11/10/2020 130,200.00 (G) 2.620 0.413 Nov-20 223,200.00 (G) i otai Luau AS CD Ibs/acre Applied 0.027 1 0.00 Cond. Precip Volati- Mineral - Residual Dry, Wet, Past 24 Hrs. Application lization ization Source Moist Inches Method* Rate** Rate*`* LIL MOIST 1,0-<112" SUR 0.5 0.20 LIL DRY "0-<1/2" SUR 0.5 0.20 LIL MOIST "0-<1/2" SUR 0.5 0.20 Page: 1 ACRES UTILIZED: 34.5 ACRES PERMITTED: 34.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Ammonia Nitrate PAN Applied Receiving Residual TKN Nitrogen and Nitrite (Ibs/acre) Application mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 80,500.00 35,400.00 714.00 5.109 RYSI 80,500.00 35,400.00 714.00 2.555 RYSI 80,500.00 35,400.00 714.00 11,070 RYSI LIL LIL DRY DRY "0-<1/2" "0-<1/2" SUR SUR 0.5 0.5 0.20 0.20 60,000.00 60,000.00 22,000.00 22,000.00 175.00 175.00 Total 11.072 15.500 45.306 0.000 RYSI RYSI CU CR PB HG MO NI SE ZN P Lime Ar 0.732 0.150 0.038 0.002 0.019 0.036 0.032 0.707 49.792 Date Cumulative Ibs/acre Applied 0.027 0.004 1 0.732 0 150 0.038 0.002 0.019 0.036 0.032 0.707 20 Permit PAN Limit (Ibs/acre) 1st Crop _ _ - - 120 2nd Crop Federal C P L R (Ibs/acre)**** 36.6 34 8 1 339 0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was pre ared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe3V;f1GNATURE r su f se information, including the possibility offines and imprisonment for knowingviolations." 7'q_2< 44 OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge 0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/6l2021 ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: LINCOLNTON, NC WQ PERMIT #: WQ0002712 FIELD#: NC-LT-00047-0-0004- ACRES UTILIZED: 31.2 LAND OWNER: FLORENCE CRIMAN ANNUAL DRY TONS APPLIED: 62.11 SITE #: NG LT 00047 ACRES PERMITTED: 31.2 PREDOMINANT SOIL SERIES: CECIL CATION EXCHANGE CAPACITY (NON-503): OPERATOR: RANDY LEATHERMAN CROP 2 MAX. PAN: CROP 1 NAME: SOYBEANS (SB) CROP 1 MAX. PAN: 185 CROP 2 NAME: RESIDUAL SOURCE(S): * See list at bottom of report Name of Crop Type Gallons (G) Site Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual or Cubic Yards (Y) Cond. Precip ization TKN Nitrogen and Nitrite (Ibs/acre) Application Date or or Wet Tons (W) °� Residual Dr Wet, y' Past 24 Hrs. Application lization Crop 2 Crop 1 Crop UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Month Amount LIL DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 15.677 SB 4/2/2020 186,000.00 (G) 2.860 0.711 "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 15.155 SB 4/3/2020 179,800.00 (G) 2.860 0.687 LIL DRY SB 2.860 0.592 LIL DRY "0-<1J2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 13.064 4/6/2020 155,000.00 (G) Apr-20 520,800.00 (G) Total 43.896 0.000 Total 1.990 CU CR PB HG MO NI SE ZN P Lime Applied AS 0.031 �O�CD 0.916 0.243 0.044 0.003 0,029 0.060 0.024 0.916 59.723 Date Lbs/Ac ,nnual Ibs/acre Applied ***** ;umulativ9 Ibs/acre Applied 0.031 0.003 0.916 0.243 0.044 0.003 0.029 0.060 0.024 0.916 185 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre) 36 6 I 34 8 1,339.0 267 9 15 0 375 0 89 0 2 500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific t nalties f r�suU UA409II� ormation, including the possibility of fines and imprisonment for knowing violations." -Z ter - z � SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required '** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 *.* * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** See Site pH & Li Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 *"*** me Application Records Section of Report DENR FORM FSF (12/2006) Printed: 211 /2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: SUE GILBERT OPERATOR: RANDY LEATHERMAN CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-LT-00047-0-0005- ANNUAL DRY TONS APPLIED: 42.00 SITE #: NC LT 00047 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) % Month Solids Dry Tons/Ac Amount UOM 10/27/2020 173,600.00 (G) 2.620 0.713 10/28/2020 62,000.00 (G) 2.620 0.255 Oct-20 235,600.00 (G) 11/4/2020 130,200.00 (G) 2.620 0.535 11/5/2020 18,600.00 (G) 2.620 0.076 Nov-20 148,800.00 (G) Site Cond. Precip Volati- Mineral - Residual Dry, Wet, Past 24 Hrs. Application lization ization Source Moist Inches Method* Rate** Rate*** LIL MOIST "0-<1/2" SUR 0.5 0.20 LIL MOIST "0-<1/2" SUR 0.5 0.20 LIL MOIST "0-<1/2" SUR I 0.5 I 0.20 LIL DRY "0-<1/2" SUR 0.5 0.20 Page: 1 ACRES UTILIZED: 26.6 ACRES PERMITTED: 26.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Ammonia Nitrate PAN Applied Receiving Residual TKN Nitrogen and Nitrite (Ibs/acre) Application mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 60,000.00 22,000.00 175.00 26.774 FSH 60,000.00 22,000.00 175.00 9.562 FSH 60,000.00 1 22,000.00 1 175.00 1 20.081 1 1 I-Jh 60,000.00 22,000.00 175.00 2.869 FSH Total 1.579 Total 59.286 0.000 AS CEJ_CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.025 0.003 1.232 0.256 0.063 0.002 0.025 0.063 0.035 1.168 69.469 Date Lbs/Ac Cumulative Ibs/acre Applied 0.025 0.003 1.232 0.256 0.063 0.002 0.025 0.063 0.035 1.168 209 Permit PAN Limit (Ibs/acre) 1st Crop', Federal C P L R (Ibs/acre)**** 36 6 34 8 1 339 0 267.9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe It s for submi se information, including the possibility of fines and imprisonment for knowing violations." _ ?r SIGNATURE OF LAND APPLIER NR = Not Reported or Not Required * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 DATE *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge 0.4 * ** C.P.L.R.: Cumulative Pollutant Loading Rate `***` See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/6/2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: MIKE DAVIS OPERATOR: MIKE DAVIS CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00002712 FIELD#: NC-LT-00048-0-0005- ANNUAL DRY TONS APPLIED: 31.06 SITE #: NC LT 00048 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 157 CROP 2 NAME: Gallons (G) Site or Cubic Yards (Y) Cond. Date or or Wet Tons (W) % Residual Dry, Wet, Month Solids DryTons/Ac Source Moist Amount UOM 4/29/2020 167,400.00 (G) 2.860 0.774 LIL DRY Apr-20 167,400.00 (G) 5/4/2020 93,000.00 (G) 2.860 0.430 LIL DRY May-20 93,000.00 (G) Precip Volati- Mineral - Past 24 Hrs. Application lization ization Inches Method* Rate** Rate*** ,0-<1/2" SUR 0.5 0.20 I Oral -1.4v% AS CD CU CR PB bs/acre Applied 0.019 1 0.002 0.554 0.147 1 0.02 Ibs/acre Applied 0.019 1 0.002 1 0.554 0.147 0.026 0.5 HG MO NI 0.002 0.018 0.0: Page: 1 ACRES UTILIZED: 25.8 ACRES PERMITTED: 25.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: TKN mg/kg Ammonia Nitrogen mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 33,000.00 13,000.00 525.00 17.063 FSP 33,000.00 13,000.00 525.00 Total 9.479 26.542 0.000 FSP SE 0.015 1 ZN 0.554 P 36.111 Lime Applied I Date I Lbs/Ac 6.018 1 0.036 1 0,015 157 Permit PAN Limit (Ibs/acre) 1st Crop _ _ _ — — — _ 157 2nd Crop Federal C P L R (Ibs/acre) 36 6 34 8 1 339 0 267.9 15.0 375.0 89.0 1 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penal s r submitting false information, including the possibility of fines and imprisomnent for Icnowing violations." SI NATURE OF LAND APPLIER DATE '** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 NR =Not Reported or Not Required * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** SeeC.PSiteR. Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH &Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/6/2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: MIKE DAVIS OPERATOR: MIKE DAVIS CROP 1 NAME: FESCUE (FS) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W) Month Amount UOM 11/5/2020 74,400.00 (G) 11/6/2020 148,800.00 (G) 11/9/2020 49,600.00 (G) Nov-20 272,800.00 (G) Annual Ibs/acre Applied Applied ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0002712 FIELD#: NC-LT-00048-0-0008- ANNUAL DRY TONS APPLIED: 29.80 SITE #: NC LT 00048 PREDOMINANT SOIL SERIES: MADISON CROP 1 MAX. PAN: 126 CROP 2 NAME: Site Cond. Precip Volati- Mineral- % Residual Dry, Wet, Past 24 Hrs. Application lization ization Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** DRY "0-<1/2" SUR 0.5 0.20 2.620 0.328 LIL 2.620 0.656 LIL DRY "0-<1/2" SUR 0.5 0.20 2.620 0.219 LIL DRY "0-<1/2" SUR 0.5 0.20 Total 1.203 AS CD CU CR PB HG MO 6.619 0.002 1 0.937 1 0.195 0.048 0.002 0.01 0.019 0.002 0.937 0.195 1 0.048 0.002 0.01 NI 0.048 Page: 1 ACRES UTILIZED: 24.8 ACRES PERMITTED: 24.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Ammonia Nitrate PAN Applied Receiving Residual TKN Nitrogen and Nitrite (Ibs/acre) Application mg/kg mg/kg mg/kg Crop 2 Crop 1 Crop 60,000.00 22,000.00 175.00 f8.2 FS 60,000.00 22,000.00 175.00 FS 60,000.00 22,000.00 175.00 FS 0.048 1 0.026 Total 45.127 0.000 ZN P I Lime Applied 889 1 52.879 1 1 Date 1 L 126 Permit PAN Limit (Ibs/acre) 1st Crop Federal C P L R (Ibs/acre) 36 6 34 8 1 339 0 267 9 15.0 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of lawthat this docurnent was prepared under my direction or supervision in accordance with a system designed to assure that qualified persomiel properly gathered and evaluated the information submitted. I am aware that there are signi!t%S bmittin rmation, including the possibility of fines and imprisonment for knowing violations.' ATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 **.* * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1/2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: MICHAEL N TERESA WESSON OPERATOR: MICHAEL N TERESA WESSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W ) Month Amount UOh 6/25/2020 117,800.00 (G) 6/26/2020 80,600.00 (G) 6/30/2020 43,400.00 (G) Jun-20 241,800.00 (G) Annual Ibs/acre Applied Limit(lbs/acre) 1st ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0002712 FIELD#: NC-LT-00049-0-0001- ANNUAL DRY TONS APPLIED: 28.84 SITE #: NC LT 00049 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: Residual Solids DryTons/Ac Source 2.860 0.956 LIL 2.860 0.654 LIL 2.860 0.352 LIL Total 1.962 ]EAS jCDj�j CU 0.902 0.030 0.003 4, 0.902 1,339.0 Page: 1 ACRES UTILIZED: 14.7 ACRES PERMITTED: 14.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Site Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Dry, Wet, Past24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 21.074 FSH MOIST "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 14.419 FSH DRY "0-<1/2" SUR 0.5 0.20 33,000.00 13,000.00 525.00 7.764 — i A Ann FSH CR u'_ PB HG MO NI SE ZN P L 0.239 0.043 0.003 i 0.029 I 0.059 R 0.024 0.902 58,852 Date E 0.902 0.239 P 0.043 0.003 0.029 �I 0.059 0.024 P 209 1 267.9 1 15.0 3375.0 89.0 2,500.0 LIL = LINCOLNTON, NC W WTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, th t this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe ,I s for sub tion, including the possibility of fines and imprisonment for knowing violations" SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * ..** Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation C.P.L.R.: Cumulative Pollutant Loading Rate ** ***** See Site & Lime Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 P H Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1/2021 FACILITY NAME: LINCOLNTON, NC LAND OWNER: MICHAEL N TERESA W ESSON OPERATOR: MICHAEL N TERESA WESSON CROP 1 NAME: FESCUE (FS) RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) or Cubic Yards (Y) Date or or Wet Tons (W ) Month Amount UOP 6/30/2020 I 130,200.001 (G) J1 204,600.00 (G) al Ibs/acre Applied dative Ibs/acre Applied ANNUAL LAND APPLICATION FIELD SUMMARY FORM W Q PERMIT #: W Q0002712 FIELD#: NC-LT-00049-0-0002- ANNUAL DRY TONS APPLIED: 24.40 SITE #: NC LT 00049 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 209 CROP 2 NAME: Cond. % Residual Dry, Wet, Solids Dry Tons/Ac Source Moist 2.860 0.259 LIL MOIST 2.860 0.454 LIL DRY Page: 1 ACRES UTILIZED: 34.2 ACRES PERMITTED: 34.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Name of Crop Type Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Crop 1 Crop 2 Crop 1 Crop 2 Inches Method* Rate** Rate— mg/kg mg/kg mg/kg SUR 0.5 0.20 33,000.00 13,000.00 525.00 5.721 FS SUR 0.5 0.20 33,000.00 13,000.00 525.00 10.011 n nnn FS Total 0.713 PB HG MO NI CD CU CR 0.016 <0.001 0.010 0.021 0.009 0.328 21.404 EASE 0.001 0.328 0.087 0.328 0.087 0.016 <0.001 0.010 0.021 1 0.009 0.328 0.011 1 0.001 �Vv 209 1stCrop 36.6 34.8 1,339.0 267.9 1 15.0 _ 375.0 89.0 2,500.0 LIL = LINCOLNTON, NC WWTP ANAEROB. DIGESTED LIQUID "I certify, under penalty of law, that thus document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific nalties for submitting fals ormation, including the possibility of fines and imprisonment for knowing violations." �- q_z( SIGNATURE OF LAND APPLIER DATE *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 NR =Not Reported or Not Required * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** See SiteR. Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH &Lime Application Records Section of Report DENR FORM FSF (12/2006) Printed: 2/1/2021 SECTION 4 SUMM111 Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOL0C4r;S,INC Cuyahoga Falls, Ohio44223 Arraly0ca1 Laboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com January 31, 2020 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Lincolnton WWTP Dear Alex Fox: Order No.: 20010314 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/8/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington C891 Page 1 of 34 mm' y Summit Environmental Technologies, Inc. Case Narrative su3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 20010314 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/31/2020 CLIENT: Synagro Project: Lincolnton WWTP WorkOrder Narrative: 20010314: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 20010314-OOIA F1ashPt_NPW-20OF(1010): Z = Method deviation, due to instrument limitations could not stir to 250 RPM as required by the method. 20010314-OOIA pH NPW(4500-H+B) 22nd Ed.: pH is an EPA field recommended parameter. Per 40 CFR 136.3, hold time is 15 minutes from collection. Analytical Sequence QC Notes: CCV-108161 VOC-MSTR_NPW(8260): The VOC CCV (Batch R10861) exhibited high recovery for Styrene and Method -Specified CCC Vinyl chloride; All samples were ND for Vinyl chloride. All other Method -Specified CCCs and SPCCs exhibited control. LCS-R108281 F1ashPt S(1010): Z = Method deviation, due to instrument limitations could not stir to Original Page 2 of 34 mm' y Summit Environmental Technologies, Inc. Case Narrative su3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 20010314 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/31/2020 CLIENT: Synagro Project: Lincolnton WWTP 250 RPM as required by the method. LCS TCLP-SVOC-Herb_TCLP(8151): LCS exhibited high recovery, associated samples are ND for all analytes of interest. Original Page 3 of 34 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 20010314 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 1/31/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 4 of 34 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMM@NtaLTECHNp4,1ULES,1NC. Cuyahoga Falls, Ohio44223 Analytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Lincolnton WWTP Lab SampleID Client Sample ID 20010314-001 Lincolnton WWTP Tag No Date Collected 1/7/2020 1:45:00 PM Workorder Sample Summary WO#: 20010314 3l Jan-20 Date Received Matrix 1/8/2020 10:20:00 AM Non -Potable Water Page 5 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES R PORT ENVIRONMENTALTECHN❑L0G1ES,11+1C Cuyahoga Falls, Ohio44223 WO#: 20010314 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20010314-OOIA Lincolnton WWTP 1/7/2020 1:45:00 PM Non -Potable Water Flashpoint 200°F (EPA 1010) 1/21/2020 1:16:03 PM pH (SM4500-H+B) 1/17/2020 2:56:00 PM Reactive Cyanide (9014/7.3.3.2)-Liqui 1/9/2020 1:29:00 PM Reactive Sulfide (EPA 9034) 1/9/2020 1:29:00 PM TCLP Herbicides by EPA 8321B 1/9/2020 5:00:00 PM 1/23/2020 11:49:00 PM TCLP Mercury Analysis (SW1311/7471/9/2020 5:00:00 PM 1/14/2020 9:30:00 AM 1/21/2020 12:33:00 PM TCLP Metals Analysis (SW1311/6010:1/9/2020 5:00:00 PM 1/13/2020 9:40:00 AM 1/16/2020 4:53:00 PM TCLP Pesticides Analysis (SW1311/8(1/9/2020 5:00:00 PM 1/14/2020 10:45:00 AM 1/18/2020 3:45:00 AM TCLP Semi-Volatiles Analysis 1/9/2020 5:00:00 PM 1/13/2020 9:45:00 AM 1/15/2020 6:42:00 PM (SW1311/8270) TCLP Volatiles Analysis 1/9/2020 5:00:00 PM 1/18/2020 8:07:00 PM Original Page 6 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010314 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: NON -POTABLE WATER Collection Date: 1/7/2020 1:45:00 PM Lab ID: 20010314-OOIA Project: Lincolnton WWTP Client Sample ID Lincolnton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW131117470) TCLP Mercury ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND TCLP Barium(Ba) ND TCLP Cadmium(Cd) ND TCLP Chromium(Cr) ND TCLP Lead(Pb) ND TCLP Selenium(Se) ND TCLP Silver(Ag) ND RCI FLASHPOINT 200°F (EPA 1010) Flashpoint (200oF) >200 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW131118270) 1,4-Dichlorobenzene ND 2,4,5-Trichlorophenol ND 2,4,6-Trichlorophenol ND 2,4-Dinitrotoluene ND Cresols, Total ND Hexachloro-1,3-butadiene ND Hexachlorobenzene ND Hexachloroethane ND Nitrobenzene ND Pentachlorophenol ND Pyridine ND Surr: 2-Fluorophenol 63.1 Surr: Phenol-d6 60.4 Surr: Nitrobenzene-d5 67.2 SW7470A SW7470A Analyst: MJM 0.00200 mg/L 1 1/21/2020 12:33:00 PM SW6010D SW3010A Analyst: EAM 0.500 mg/L 1 1/16/2020 4:53:00 PM 5.00 mg/L 1 1/16/2020 4:53:00 PM 0.100 mg/L 1 1/16/2020 4:53:00 PM 0.200 mg/L 1 1/16/2020 4:53:00 PM 0.500 mg/L 1 1/16/2020 4:53:00 PM 0.0500 mg/L 1 1/16/2020 4:53:00 PM 0.500 mg/L 1 1/16/2020 4:53:00 PM SW1010 Analyst: TAH Z °F 1 1/21/2020 1:16:03 PM SW8270 SW3510C Analyst: SFG 0.200 mg/L 2 1/15/2020 6:42:00 PM 0.500 mg/L 2 1/15/2020 6:42:00 PM 0.500 mg/L 2 1/15/2020 6:42:00 PM 0.100 mg/L 2 1/15/2020 6:42:00 PM 10.0 mg/L 2 1/15/2020 6:42:00 PM 0.0400 mg/L 2 1/15/2020 6:42:00 PM 0.100 mg/L 2 1/15/2020 6:42:00 PM 0.200 mg/L 2 1/15/2020 6:42:00 PM 0.200 mg/L 2 1/15/2020 6:42:00 PM 0.500 mg/L 2 1/15/2020 6:42:00 PM 0.500 mg/L 2 1/15/2020 6:42:00 PM 10 - 109 %Rec 2 1/15/2020 6:42:00 PM 10 - 109 m %Rec 2 1/15/2020 6:42:00 PM 19 - 120 %Rec 2 1/15/2020 6:42:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 7 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010314 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: NON -POTABLE WATER Collection Date: 1/7/2020 1:45:00 PM Lab ID: 20010314-OOIA Project: Lincolnton WWTP Client Sample ID Lincolnton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW131118270) Surr: 2,4,6-Tribromophenol 89.2 Surr: 2-Fluorobiphenyl 67.1 Surr: p-Terphenyl-d14 93.3 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW131118081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 16.3 Surr: DCB 15.1 TCLP HERBICIDES BY EPA 8321B 2,4-D ND 2,4,5-TP ND Surr: 2,4-Dichlorophenylacetic aci 76.2 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1, 2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8270 SW3510C Analyst: SFG 10 - 120 %Rec 2 1/15/2020 6:42:00 PM 22 - 117 %Rec 2 1/15/2020 6:42:00 PM 34 - 116 %Rec 2 1/15/2020 6:42:00 PM SW8081 SW3510C Analyst: SEK 0.125 mg/L 5 1/18/2020 3:45:00 AM 0.250 mg/L 5 1/18/2020 3:45:00 AM 0.0125 d mg/L 5 1/18/2020 3:45:00 AM 0.0125 mg/L 5 1/18/2020 3:45:00 AM 0.0125 d mg/L 5 1/18/2020 3:45:00 AM 0.0125 d mg/L 5 1/18/2020 3:45:00 AM 0.0125 d mg/L 5 1/18/2020 3:45:00 AM 10 - 119 %Rec 5 1/18/2020 3:45:00 AM 10 - 119 %Rec 5 1/18/2020 3:45:00 AM SW8321A SW1311M Analyst: BJH 0.500 mg/L 50 1/23/2020 11:49:00 PM 0.500 mg/L 50 1/23/2020 11:49:00 PM 70 - 130 %Rec 50 1/23/2020 11:49:00 PM SW8260 SW1311M Analyst: RMT 0.250 mg/L 50 1/18/2020 8:07:00 PM 0.250 mg/L 50 1/18/2020 8:07:00 PM 5.00 mg/L 50 1/18/2020 8:07:00 PM 0.250 mg/L 50 1/18/2020 8:07:00 PM 0.250 mg/L 50 1/18/2020 8:07:00 PM 2.50 mg/L 50 1/18/2020 8:07:00 PM 0.250 mg/L 50 1/18/2020 8:07:00 PM 0.250 mg/L 50 1/18/2020 8:07:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 8 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20010314 Date Reported: 1/31/2020 CLIENT: Synagro Tag Number: Matrix: NON -POTABLE WATER Collection Date: 1/7/2020 1:45:00 PM Lab ID: 20010314-OOIA Project: Lincolnton WWTP Client Sample ID Lincolnton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: RMT TCLP VOLATILES ANALYSIS Trichloroethene ND 0.250 mg/L 50 1/18/2020 8:07:00 PM Vinyl chloride ND 0.100 QC+ mg/L 50 1/18/2020 8:07:00 PM Surr: 4-Bromofluorobenzene 96.3 70 - 130 %Rec 50 1/18/2020 8:07:00 PM Surr: Di brom ofl uorom ethane 100 70 - 130 %Rec 50 1/18/2020 8:07:00 PM Surr: Toluene-d8 101 70 - 130 %Rec 50 1/18/2020 8:07:00 PM RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-LIQUID Cyanide, Reactive ND 0.476 mg/L 1 1/9/2020 1:29:00 PM PH (SM4500-H+ B) A4500-H+B Analyst: DHC pH 6.8 H s.u.@21.3C 1 NOTES: pH is an EPA field recommended parameter. Per 40 CFR 136.3, hold time is 15 minutes from collection. RCI SW9034 REACTIVE SULFIDE (EPA 9034) Sulfide, Reactive ND 25.0 mg/L 1 Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit 1/17/2020 2:56:00 PM Analyst: MS 1/9/2020 1:29:00 PM E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 9 of 34 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report ENVAONMEuTAL TECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20010314 Wehsite: http://www.settek.com 31Jan-20 Client: Synagro State: NW Project: Lincolnton WWTP Program Name: NC WW_SCM Sample ID Matrix Test Name Analyte Status 20010314-OOIA Non -Potable Water Flashpoint 2007 (EPA 1010) Flashpoint (2007) A Non -Potable Water pH (SM4500-H+ B) Hydrogen Ion (pH) A Non -Potable Water Reactive Cyanide (9014/7.3.3.2)-Liquid Cyanide, Reactive U Non -Potable Water Reactive Sulfide (EPA 9034) Sulfide, Reactive U Non -Potable Water TCLP Herbicides by EPA 8321B 2,4,5-TP A Non -Potable Water TCLP Herbicides by EPA 8321B 2,4-D A Non -Potable Water TCLP Mercury Analysis (SW1311/7470) Mercury A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Arsenic A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Barium A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Cadmium A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Chromium A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Lead A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Selenium A Non -Potable Water TCLP Metals Analysis (SW1311/6010) Silver A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Endrin A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Non -Potable Water TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Non -Potable Water TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Original #1 Page 10 of 34 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report ENVIRONMENTAL YECHNOWGIES, INC, Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20010314 Wehsite: http://www.settek.com 31Jan-20 Client: Synagro State: NW Project: Lincolnton WWTP Program Name: NC WW_SCM Sample ID Matrix Test Name Analyte Status 20010314-OOIA Non -Potable Water TCLP Volatiles Analysis 1, 1 -Dichloroethene A Non -Potable Water TCLP Volatiles Analysis 1,2-Dichloroethane A Non -Potable Water TCLP Volatiles Analysis 2-Butanone A Non -Potable Water TCLP Volatiles Analysis Benzene A Non -Potable Water TCLP Volatiles Analysis Carbon tetrachloride A Non -Potable Water TCLP Volatiles Analysis Chlorobenzene A Non -Potable Water TCLP Volatiles Analysis Chloroform A Non -Potable Water TCLP Volatiles Analysis Tetrachloroethene A Non -Potable Water TCLP Volatiles Analysis Trichloroethene A Non -Potable Water TCLP Volatiles Analysis Vinyl chloride A Original #1 Page 11 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010314 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: 41416 Sample ID: MB-41416 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 1/9/2020 RunNo: 108161 Client ID: PBS Batch ID: 41416 TestNo: SW8260 SW1311M Analysis Date: 1/18/2020 SegNo: 2565165 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.0500 1,2-Dichloroethane ND 0.0500 MEK ND 1.00 Benzene ND 0.0500 Carbon tetrachloride ND 0.0500 Chlorobenzene ND 0.500 Chloroform ND 0.0500 Tetrachloroethene ND 0.0500 Trichloroethene ND 0.0500 Vinyl chloride ND 0.0200 Surr: 4-Bromofluorobenzene 492 Surr: Dibromofluoromethane 500 Surr: Toluene-d8 495 500.0 98.4 70 130 500.0 100 70 130 500.0 99.0 70 130 QC+ Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 34 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: 41436 Sample ID: 20010299-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/13/2020 RunNo: 108178 Client ID: Batch= Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/16/2020 SegNo: 2565505 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.72 0.500 2.000 0 86.0 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.9484 59.0 70 130 S TCLP Cadmium(Cd) 1.52 0.100 2.000 0.001993 76.1 70 130 TCLP Chromium(Cr) 1.36 0.200 2.000 0 67.8 70 130 S TCLP Lead(Pb) 1.53 0.500 2.000 0 76.3 70 130 TCLP Selenium(Se) 1.79 0.0500 2.000 0 89.4 70 130 TCLP Silver(Ag) 1.66 0.500 2.000 0 83.0 70 130 Sample ID: 20010299-001AMSD SampType: MSD TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/13/2020 RunNo: 108178 Client ID: Batch= Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/16/2020 SegNo: 2565506 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.69 0.500 2.000 0 84.3 70 130 1.720 2.00 20 TCLP Barium(Ba) ND 5.00 2.000 0.9484 49.3 70 130 0 0 20 S TCLP Cadmium(Cd) 1.47 0.100 2.000 0.001993 73.5 70 130 1.524 3.47 20 TCLP Chromium(Cr) 1.27 0.200 2.000 0 63.5 70 130 1.355 6.48 20 S TCLP Lead(Pb) 1.48 0.500 2.000 0 73.8 70 130 1.526 3.40 20 TCLP Selenium(Se) 1.78 0.0500 2.000 0 89.0 70 130 1.788 0.392 20 TCLP Silver(Ag) 1.55 0.500 2.000 0 77.7 70 130 1.660 6.66 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010314 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: 41436 Sample ID: MB-41436 SampType: MBLK TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/13/2020 RunNo: 108172 Client ID: PBS Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/16/2020 SegNo: 2565377 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-41436 SampType: LCS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/13/2020 RunNo: 108172 Client ID: LCSS Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/16/2020 SegNo: 2565378 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.04 0.500 2.000 0 102 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 109 80 120 TCLP Cadmium(Cd) 2.08 0.100 2.000 0 104 80 120 TCLP Chromium(Cr) 2.09 0.200 2.000 0 104 80 120 TCLP Lead(Pb) 2.18 0.500 2.000 0 109 80 120 TCLP Selenium(Se) 2.02 0.0500 2.000 0 101 80 120 TCLP Silver(Ag) 2.32 0.500 2.000 0 116 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010314 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: 41436 Sample ID: MB-41436 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/13/2020 RunNo: 108068 Client ID: PBS Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/13/2020 SegNo: 2563279 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-41436 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 1/13/2020 RunNo: 108068 Client ID: LCSS Batch ID: 41436 TestNo: SW6010D SW3010A Analysis Date: 1/13/2020 SegNo: 2563280 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.99 0.500 2.000 0 99.4 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 104 80 120 TCLP Cadmium(Cd) 2.03 0.100 2.000 0 102 80 120 TCLP Chromium(Cr) 2.11 0.200 2.000 0 105 80 120 TCLP Lead(Pb) 2.12 0.500 2.000 0 106 80 120 TCLP Selenium(Se) 2.10 0.0500 2.000 0 105 80 120 TCLP Silver(Ag) 2.20 0.500 2.000 0 110 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: MB-41456 SampType: MBLK TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 lient ID: PBS Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566517 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.559 Surr: Phenol-d6 0.525 Surr: Nitrobenzene-d5 0.572 Surr: 2,4,6-Tribromophenol 0.751 Surr: 2-Fluorobiphenyl 0.579 Surr: p-Terphenyl-d14 0.806 1.000 55.9 10 109 1.000 52.5 10 109 1.000 57.2 19 120 1.000 75.1 10 120 1.000 57.9 22 117 1.000 80.6 34 116 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: LCS-41456 SampType: LCS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: LCSS Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566521 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.428 0.100 0.8000 0 53.5 36.4 130 2,4,5-Trichlorophenol 0.736 0.250 0.8000 0 92.0 31.7 132 2,4,6-Trichlorophenol 0.789 0.250 0.8000 0 98.7 31.1 133 2,4-Dinitrotoluene 0.879 0.0500 0.8000 0 110 43.3 130 o-Cresol 0.592 0.250 0.8000 0 74.0 32.9 130 Cresols, Total ND 5.00 1.600 0 75.5 31.7 130 Hexachloro-1,3-butadiene 0.458 0.0200 0.8000 0 57.3 31.4 130 Hexachlorobenzene 0.673 0.0500 0.8000 0 84.2 43.1 130 Hexachloroethane 0.397 0.100 0.8000 0 49.6 36.5 130 Nitrobenzene 0.550 0.100 0.8000 0 68.8 39.5 130 Pentachlorophenol 0.817 0.250 0.8000 0 102 34 130 Pyridine 0.342 0.250 0.8000 0 42.8 10 130 Surr: 2-Fluorophenol 0.660 1.000 66.0 17.1 130 Surr: Phenol-d6 0.677 1.000 67.7 10 130 Surr: Nitrobenzene-d5 0.684 1.000 68.4 32.6 130 Surr:2,4,6-Tribromophenol 1.03 1.000 103 4.43 130 Surr:2-Fluorobiphenyl 0.684 1.000 68.4 41.8 130 Surr: p-Terphenyl-d14 0.948 1.000 94.8 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: 20010310-001AMS SampType: MS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: Batch= Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566524 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.417 0.200 0.8000 0 52.2 15.2 124 2,4,5-Trichlorophenol 0.706 0.500 0.8000 0 88.2 30.6 152 2,4,6-Trichlorophenol 0.712 0.500 0.8000 0 89.1 27.6 150 2,4-Dinitrotoluene 0.920 0.100 0.8000 0 115 58 141 o-Cresol 0.537 0.500 0.8000 0 67.2 26.9 132 Cresols, Total ND 10.0 1.600 0 68.5 27.6 132 Hexachloro-1,3-butadiene 0.427 0.0400 0.8000 0 53.4 -5.3 156 Hexachlorobenzene 0.694 0.100 0.8000 0 86.8 54.3 142 Hexachloroethane 0.382 0.200 0.8000 0 47.8 1.92 131 Nitrobenzene 0.516 0.200 0.8000 0 64.5 21 135 Pentachlorophenol 0.969 0.500 0.8000 0 121 47.4 134 Pyridine ND 0.500 0.8000 0 34.4 -10.3 64.2 Surr:2-Fluorophenol 0.570 1.000 57.0 9.77 146 Surr: Phenol-d6 0.606 1.000 60.6 20.7 130 Surr: Nitrobenzene-d5 0.614 1.000 61.4 13.9 156 Surr:2,4,6-Tribromophenol 1.05 1.000 105 27.3 183 Surr:2-Fluorobiphenyl 0.624 1.000 62.4 21.4 153 Surr: p-Terphenyl-d14 0.970 1.000 97.0 54.8 154 mQMR Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: 20010310-001AMSD SampType: MSD TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: Batch= Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566527 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.343 0.200 0.8000 0 42.8 15.2 124 0.4172 19.6 30 2,4,5-Trichlorophenol 0.598 0.500 0.8000 0 74.8 30.6 152 0.7060 16.6 30 2,4,6-Trichlorophenol 0.622 0.500 0.8000 0 77.8 27.6 150 0.7124 13.5 30 2,4-Dinitrotoluene 0.724 0.100 0.8000 0 90.4 58 141 0.9204 23.9 30 o-Cresol ND 0.500 0.8000 0 59.5 26.9 132 0.5372 200 30 Cresols, Total ND 10.0 1.600 0 59.2 27.6 132 0 0 30 Hexachloro-1,3-butadiene 0.331 0.0400 0.8000 0 41.4 -5.3 156 0.4268 25.2 30 Hexachlorobenzene 0.602 0.100 0.8000 0 75.3 54.3 142 0.6944 14.2 30 Hexachloroethane 0.300 0.200 0.8000 0 37.6 1.92 131 0.3820 23.9 30 Nitrobenzene 0.469 0.200 0.8000 0 58.6 21 135 0.5160 9.59 30 Pentachlorophenol 0.807 0.500 0.8000 0 101 47.4 134 0.9688 18.2 30 Pyridine ND 0.500 0.8000 0 23.7 -10.3 64.2 0 0 30 Surr:2-Fluorophenol 0.519 1.000 51.9 9.77 146 0 Surr: Phenol-d6 0.534 1.000 53.4 20.7 130 0 Surr: Nitrobenzene-d5 0.576 1.000 57.6 13.9 156 0 Surr:2,4,6-Tribromophenol 0.903 1.000 90.3 27.3 183 0 Surr:2-Fluorobiphenyl 0.626 1.000 62.6 21.4 153 0 Surr: p-Terphenyl-d14 0.826 1.000 82.6 54.8 154 0 Rm Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: MB-41456 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 lient ID: PBS Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566479 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.559 Surr: Phenol-d6 0.525 Surr: Nitrobenzene-d5 0.572 Surr: 2,4,6-Tribromophenol 0.751 Surr: 2-Fluorobiphenyl 0.579 Surr: p-Terphenyl-d14 0.806 1.000 55.9 10 109 1.000 52.5 10 109 1.000 57.2 19 120 1.000 75.1 10 120 1.000 57.9 22 117 1.000 80.6 34 116 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: LCS-41456 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: LCSS Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566480 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.428 0.100 0.8000 0 53.5 36.4 130 2,4,5-Trichlorophenol 0.736 0.250 0.8000 0 92.0 31.7 132 2,4,6-Trichlorophenol 0.789 0.250 0.8000 0 98.7 31.1 133 2,4-Dinitrotoluene 0.879 0.0500 0.8000 0 110 43.3 130 o-Cresol 0.592 0.250 0.8000 0 74.0 32.9 130 Cresols, Total ND 5.00 1.600 0 75.5 31.7 130 Hexachloro-1,3-butadiene 0.458 0.0200 0.8000 0 57.3 31.4 130 Hexachlorobenzene 0.673 0.0500 0.8000 0 84.2 43.1 130 Hexachloroethane 0.397 0.100 0.8000 0 49.6 36.5 130 Nitrobenzene 0.550 0.100 0.8000 0 68.8 39.5 130 Pentachlorophenol 0.817 0.250 0.8000 0 102 34 130 Pyridine 0.342 0.250 0.8000 0 42.8 10 130 Surr: 2-Fluorophenol 0.660 1.000 66.0 17.1 130 Surr: Phenol-d6 0.677 1.000 67.7 10 130 Surr: Nitrobenzene-d5 0.684 1.000 68.4 32.6 130 Surr:2,4,6-Tribromophenol 1.03 1.000 103 4.43 130 Surr:2-Fluorobiphenyl 0.684 1.000 68.4 41.8 130 Surr: p-Terphenyl-d14 0.948 1.000 94.8 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 21 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: 20010310-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: Batch= Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566485 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.417 0.200 0.8000 0 52.2 33.8 126 2,4,5-Trichlorophenol 0.706 0.500 0.8000 0 88.2 28.7 144 2,4,6-Trichlorophenol 0.712 0.500 0.8000 0 89.1 12.8 153 2,4-Dinitrotoluene 0.920 0.100 0.8000 0 115 20.4 155 o-Cresol 0.537 0.500 0.8000 0 67.2 10 148 Cresols, Total ND 10.0 1.600 0 68.5 10 148 Hexachloro-1,3-butadiene 0.427 0.0400 0.8000 0 53.4 29 126 Hexachlorobenzene 0.694 0.100 0.8000 0 86.8 33.7 134 Hexachloroethane 0.382 0.200 0.8000 0 47.8 32.8 132 Nitrobenzene 0.516 0.200 0.8000 0 64.5 20 158 Pentachlorophenol 0.969 0.500 0.8000 0 121 10 176 Pyridine ND 0.500 0.8000 0 34.4 10 130 Surr:2-Fluorophenol 0.570 1.000 57.0 3.39 130 Surr: Phenol-d6 0.606 1.000 60.6 5 130 Surr: Nitrobenzene-d5 0.614 1.000 61.4 14.5 154 Surr: 2,4,6-Tribromophenol 1.05 1.000 105 19.5 130 Surr:2-Fluorobiphenyl 0.624 1.000 62.4 34.4 130 Surr: p-Terphenyl-d14 0.970 1.000 97.0 8.86 156 mQMR Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41456 WO#: 20010314 31-Jan-20 Sample ID: 20010310-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/13/2020 RunNo: 108215 Dient ID: Batch= Batch ID: 41456 TestNo: SW8270 SW3510C Analysis Date: 1/15/2020 SegNo: 2566486 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.343 0.200 0.8000 0 42.8 33.8 126 0.4172 19.6 30 2,4,5-Trichlorophenol 0.598 0.500 0.8000 0 74.8 28.7 144 0.7060 16.6 30 2,4,6-Trichlorophenol 0.622 0.500 0.8000 0 77.8 12.8 153 0.7124 13.5 30 2,4-Dinitrotoluene 0.724 0.100 0.8000 0 90.4 20.4 155 0.9204 23.9 30 o-Cresol ND 0.500 0.8000 0 59.5 10 148 0.5372 200 30 Cresols, Total ND 10.0 1.600 0 59.2 10 148 0 0 30 Hexachloro-1,3-butadiene 0.331 0.0400 0.8000 0 41.4 29 126 0.4268 25.2 30 Hexachlorobenzene 0.602 0.100 0.8000 0 75.3 33.7 134 0.6944 14.2 30 Hexachloroethane 0.300 0.200 0.8000 0 37.6 32.8 132 0.3820 23.9 30 Nitrobenzene 0.469 0.200 0.8000 0 58.6 20 158 0.5160 9.59 30 Pentachlorophenol 0.807 0.500 0.8000 0 101 10 176 0.9688 18.2 30 Pyridine ND 0.500 0.8000 0 23.7 10 130 0 0 30 Surr:2-Fluorophenol 0.519 1.000 51.9 3.39 130 0 Surr: Phenol-d6 0.534 1.000 53.4 10 130 0 Surr: Nitrobenzene-d5 0.576 1.000 57.6 14.5 154 0 Surr: 2,4,6-Tribromophenol 0.903 1.000 90.3 19.5 130 0 Surr:2-Fluorobiphenyl 0.626 1.000 62.6 34.4 130 0 Surr: p-Terphenyl-d14 0.826 1.000 82.6 8.86 156 0 Rm Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 34 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: 41521 TCLP Mercury ND 0.00200 TCLP Mercury 0.00393 0.00200 0.00400 0 98.2 80 120 TCLP Mercury 0.00431 0.00200 0.00400 0 108 75 125 Sample ID: 20010299-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/14/2020 RunNo: 108219 Client ID: Batch= Batch ID: 41521 TestNo: SW7470A SW7470A Analysis Date: 1/21/2020 SegNo: 2566750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00422 0.00200 0.00400 0 106 75 125 0.00431 2.11 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 24 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Lincolnton WWTP BatchID: 41521 WO#: 20010314 31-Jan-20 Sample ID: 20010299-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/14/2020 RunNo: 108219 Dient ID: Batch= Batch ID: 41521 TestNo: SW7470A SW7470A Analysis Date: 1/21/2020 SegNo: 2566750 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 34 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: R107965 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4630 25.0 4800 0 96.5 85 115 Sulfide, Reactive 4710 25.0 4800 0 98.1 75 125 W Sample ID: 20010217-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 107965 Client ID: Batch= Batch ID: R107965 TestNo: SW9034 Analysis Date: 1/9/2020 SegNo: 2559844 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4720 25.0 4800 0 98.3 75 125 4710 0.212 30 W Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com QC SUMMARY REPORT WO#: 20010314 3l Tan-20 Client: Synagro Project: Lincolnton WWTP Batchll): R107965 Sample ID: 20010217-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 107965 client ID: BatchQC Batch ID: R107965 TestNo: SW9034 Analysis Date: 1/9/2020 SegNo: 2559844 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal} J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 34 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: R107967 Cyanide, Reactive ND 0.490 Cyanide, Reactive 9.75 0.495 10.00 0 97.5 85 115 Cyanide, Reactive ND 0.481 0.5000 0 86.3 50 150 Sample ID: 20010217-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 107967 Client ID: Batch= Batch ID: R107967 TestNo: SW9014 Analysis Date: 1/9/2020 SegNo: 2559904 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.28 0.481 10.00 0 92.8 81.3 118 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 34 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: R107967 Sample ID: 20010217-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 107967 Client ID: Batch= Batch ID: R107967 TestNo: SW9014 Analysis Date: 1/9/2020 SegNo: 2559904 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20010217-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 107967 Client ID: Batch= Batch ID: R107967 TestNo: SW9014 Analysis Date: 1/9/2020 SegNo: 2559905 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.47 0.500 10.00 0 94.7 81.3 118 9.276 2.04 5 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 29 of 34 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20010314 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: R108314 pH 7.0 7.0 0 100 90 110 pH 4.6 0 0 4.6 0 10 pH 7.0 7.0 0 99.6 90 110 Sample ID: CHECK 7 SampType: LCS TestCode: PH_0IL(9045 Units: sm.@21.1C Prep Date: RunNo: 108314 Client ID: LCSW Batch ID: R108314 TestNo: A4500-H+B Analysis Date: 1/17/2020 SegNo: 2572540 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 30 of 34 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com QC SUMMARY REPORT WO#: 20010314 3l Tan-20 Client: Synagro Project: Lincolnton WWTP Batchll): R108314 Sample ID: CHECK SampType: LCS TestCode: PH_OIL(9045 Units: s.u.@21.lC Prep Date: RunNo: 108314 Client ID: LCSW Batch ID: R108314 TestNo: A4500-H+B Analysis Date: 1/17/2020 SegNo: 2572540 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal} J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 31 of 34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20010314 31-Jan-20 Client: Synagro Project: Lincolnton WWTP BatchID: R108314 Sample ID: 20010312-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@20.4C Prep Date: RunNo: 108314 lient ID: BatchQC Batch ID: R108314 TestNo: A4500-H+B Analysis Date: 1/17/2020 SegNo: 2572434 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.8 6.9 0.6 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 32 of 34 � e k 2 � k � 2 � � � menu @ j�h� qjrIJ,j ¥. m ,ry = @lam Iq ,o� = 7n4',= qui9 ❑ � � 15 �} PC � � ❑ - - � - � / § \ tr � � 7- \ t / ( jz = G Q c = ) � � � 2 � � i Page 33 of34 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 20010314 RcptNo: 1 Logged by: Jesseca E. Westfall 1/8/2020 10:20:00 AM A4,�G Completed By: Jesseca E. Westfall 1/8/2020 4:04:32 PM Reviewed By: Jennifer Woolf 1/9/2020 11:22:05 AM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes V No ❑ 15. Is it clear what analyses were requested? Yes ❑ No W 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes V No ❑ NA ❑ Person Notified: Nate/Alex Date: j1/8/2020 By Whom: jJennifer Woolf Via: ❑d eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Itests Client Instructions: Ifull TCLP includina P&H & RCI 18. Additional remarks: tests not complete on COC Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 11.9 Goodl Not Present Page 34 of 34 SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Lincolnton Lot Number:U106072 Date Completed:09/26/2019 09/26/2019 4:56 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q pCCRFO TNN acca� " Eoi B !1 BOo0o eLna The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vwvw.shealylab.com Page 1 of 13 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: U106072 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP The initial sample amount used for the following sample deviated from the standard procedure: U106072- 001. Due to a low amount of % solids, the initial amount of the samples were weighed out to about 3.0 g instead of 1.0g. The LOQ has been adjusted accordingly. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvww.shealylab.com Page 2 of 13 Client:Synagro Laboratory ID:U106072-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 1.39 09/07/2019 0416 Date Received:09/06/2019 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 09/07/2019 0416 MDD 28205 1 350.1 (Ammonia - N ) 350.1 20 09/13/2019 1525 DFR 28582 1 (Ignitability) 1010A 1 09/26/2019 1200 SLC 30162 1 (Nitrate - N ) 9056A 1 09/17/2019 1644 GMH 29171 1 (Nitrite - N ) 9056A 1 09/17/2019 1644 GMH 29240 1 (pH) 9045D 1 09/09/2019 2034 HET 28337 1 (Phosphorus) 365.1 5 09/17/2019 1411 DMA 09/16/2019 0926 29064 1 (Reactive Cya) 7.3.3 1 09/11/2019 2054 MSG 09/09/2019 0934 1 (Reactive Sul) 7.3.4 1 09/10/2019 1655 HET 09/09/2019 0934 1 351.4 (TKN) 351.2 1 09/12/2019 1037 DMA 09/11/2019 1806 28644 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 1.39 % 1 Ammonia - N (gas diffusion) 350.1 41000 1400 750 mg/kg 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Nitrate - N (soluble) 9056A 52 36 1.8 mg/kg 1 Nitrite - N (soluble) 9056A 65 14 1.4 mg/kg 1 Soil pH measured in water @ 22.3 ° C 9045D 7.0 su 1 Phosphorus 7723-14-0 365.1 12000 1800 360 mg/kg 1 Reactive Cyanide 7.3.3 ND 50 mg/kg 1 Reactive Sulfide 7.3.4 ND 50 mg/kg 1 TKN 351.2 70000 1800 1800 mg/kg 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 09/14/2019 0316 JTH 28924 09/12/2019 1814 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D ND 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3of13 Client:Synagro Laboratory ID:U106072-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 1.39 09/07/2019 0416 Date Received:09/06/2019 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 106 70-130 1,2-Dichloroethane-d4 117 70-130 Toluene-d8 118 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 09/16/2019 1606 JCG 09/13/2019 1657 28844 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 63 37-129 2-Fluorophenol 34 24-127 Nitrobenzene-d5 54 38-127 Phenol-d5 44 28-128 Terphenyl-d14 102 10-148 2,4,6-Tribromophenol 56 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 09/17/2019 0031 DAL1 09/15/2019 1406 28961 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 60 50-112 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4of13 Client:Synagro Laboratory ID:U106072-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 1.39 09/07/2019 0416 Date Received:09/06/2019 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081 B 1 09/18/2019 0509 DAL1 09/15/2019 1543 28959 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081 B 0.00040 J 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 80 20-131 Tetrachloro-m-xylene 76 26-132 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 09/10/2019 0953 KSH2 09/09/2019 1520 28269 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 5.5 1.3 mg/kg 1 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 09/12/2019 0254 LLL 09/11/2019 1726 28648 09/10/2019 2043 1 1311/7470A 7470A 1 09/13/2019 1317 KSH2 09/12/2019 1455 28691 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.070 J 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5of13 Client:Synagro Laboratory ID:U106072-001 Description: Lincolnton WWTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 1.39 09/07/2019 0416 Date Received:09/06/2019 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 09/13/2019 1205 LLL 09/12/2019 0834 28607 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 12000 480 180 mg/kg 1 Arsenic 7440-38-2 6010D 6.3 J 18 5.9 mg/kg 1 Cadmium 7440-43-9 6010D ND 5.9 1.5 mg/kg 1 Calcium 7440-70-2 6010D 9500 5900 740 mg/kg 1 Chromium 7440-47-3 6010D 47 12 3.0 mg/kg 1 Copper 7440-50-8 6010D 210 12 5.3 mg/kg 1 Iron 7439-89-6 6010D 12000 120 54 mg/kg 1 Lead 7439-92-1 6010D 12 12 5.3 mg/kg 1 Magnesium 7439-95-4 6010D 5500 J 5900 740 mg/kg 1 Manganese 7439-96-5 6010D 250 18 7.0 mg/kg 1 Molybdenum 7439-98-7 6010D ND 48 12 mg/kg 1 Nickel 7440-02-0 6010D 13 J 48 12 mg/kg 1 Potassium 7440-09-7 6010D 12000 5900 740 mg/kg 1 Selenium 7782-49-2 6010D 9.7 J 24 9.7 mg/kg 1 Sodium 7440-23-5 6010D 3600 J 5900 740 mg/kg 1 Zinc 7440-66-6 6010D 250 59 15 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6of13 Client:Synagro Laboratory ID:U106072-002 Description: Lincolnton WTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 3.03 09/07/2019 0416 Date Received:09/06/2019 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 09/07/2019 0416 MDD 28205 1 (Ignitability) 1010A 1 09/26/2019 1330 SLC 30162 1 (Paint Filter) 9095B 1 09/15/2019 1540 HET 1 (pH) 9045D 1 09/09/2019 2037 HET 28337 1 (Reactive Cya) 7.3.3 1 09/11/2019 2056 MSG 09/09/2019 0934 1 (Reactive Sul) 7.3.4 1 09/10/2019 1655 HET 09/09/2019 0934 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 3.03 % 1 Ignitability (Pensky-Martens Closed -Cup) 1010A >140 140 0 o F 1 Paint Filter Test 9095B Fail H* pass/fail 1 Soil pH measured in water @ 22 o C 9045D 6.6 su 1 Reactive Cyanide 7.3.3 ND 50 mg/kg 1 Reactive Sulfide 7.3.4 100 50 nrl 1 TCLP Volatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/5030B 8260D 10 09/14/2019 0340 JTH 28924 09/12/2019 1814 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Benzene 71-43-2 8260D ND 0.050 0.0040 mg/L 1 2-Butanone (MEK) 78-93-3 8260D ND 0.10 0.020 mg/L 1 Carbon tetrachloride 56-23-5 8260D ND 0.050 0.0040 mg/L 1 Chlorobenzene 108-90-7 8260D ND 0.050 0.0040 mg/L 1 Chloroform 67-66-3 8260D ND 0.050 0.0040 mg/L 1 1,2-Dichloroethane 107-06-2 8260D ND 0.050 0.0040 mg/L 1 1,1-Dichloroethene 75-35-4 8260D ND 0.050 0.0040 mg/L 1 Tetrachloroethene 127-18-4 8260D ND 0.050 0.0040 mg/L 1 Trichloroethene 79-01-6 8260D ND 0.050 0.0040 mg/L 1 Vinyl chloride 75-01-4 8260D ND 0.010 0.0040 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Bromofluorobenzene 110 70-130 1,2-Dichloroethane-d4 115 70-130 Toluene-d8 120 70-130 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 09/16/2019 1631 JCG 09/13/2019 1657 28844 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7of13 Client:Synagro Laboratory ID:U106072-002 Description: Lincolnton WTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 3.03 09/07/2019 0416 Date Received:09/06/2019 TCLP Semivolatiles Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8270E 1 09/16/2019 1631 JCG 09/13/2019 1657 28844 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dichlorobenzene 106-46-7 8270E ND 0.040 0.0050 mg/L 1 2,4-Dinitrotoluene 121-14-2 8270E ND 0.080 0.0050 mg/L 1 Hexachlorobenzene 118-74-1 8270E ND 0.040 0.0050 mg/L 1 Hexachlorobutadiene 87-68-3 8270E ND 0.040 0.0050 mg/L 1 Hexachloroethane 67-72-1 8270E ND 0.040 0.010 mg/L 1 2-Methylphenol 95-48-7 8270E ND 0.040 0.010 mg/L 1 3+4-Methylphenol 106-44-5 8270E ND 0.040 0.015 mg/L 1 Nitrobenzene 98-95-3 8270E ND 0.040 0.015 mg/L 1 Pentachlorophenol 87-86-5 8270E ND 0.20 0.020 mg/L 1 Pyridine 110-86-1 8270E ND 0.040 0.0050 mg/L 1 2,4,5-Trichlorophenol 95-95-4 8270E ND 0.040 0.0050 mg/L 1 2,4,6-Trichlorophenol 88-06-2 8270E ND 0.040 0.0050 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 2-Fluorobiphenyl 60 37-129 2-Fluorophenol 34 24-127 Nitrobenzene-d5 50 38-127 Phenol-d5 44 28-128 Terphenyl-d 14 99 10-148 2,4,6-Tribromophenol 51 41-144 TCLP Herbicides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/8151A 8151A 1 09/17/2019 0054 DAL1 09/15/2019 1406 28961 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 2,4-D 94-75-7 8151A ND 0.020 0.0050 mg/L 1 2,4,5-TP (Silvex) 93-72-1 8151A ND 0.0050 0.0013 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits DCAA 62 50-112 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081 B 1 09/18/2019 0523 DAL1 09/15/2019 1543 28959 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run gamma-BHC (Lindane) 58-89-9 8081B ND 0.00040 0.00017 mg/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8of13 Client:Synagro Laboratory ID:U106072-002 Description: Lincolnton WTP Matrix: Solid Date Sampled:09/05/2019 % Solids: 3.03 09/07/2019 0416 Date Received:09/06/2019 TCLP Pesticides Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3520C 8081 B 1 09/18/2019 0523 DAL1 09/15/2019 1543 28959 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chlordane 57-74-9 8081B ND 0.0040 0.0015 mg/L 1 Endrin 72-20-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor 76-44-8 8081B ND 0.00040 0.00015 mg/L 1 Heptachlor epoxide 1024-57-3 8081 B ND 0.00040 0.00016 mg/L 1 Methoxychlor 72-43-5 8081B ND 0.0016 0.00021 mg/L 1 Toxaphene 8001-35-2 8081B ND 0.0080 0.0030 mg/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits Decachlorobiphenyl 77 20-131 Tetrachloro-m-xylene 72 26-132 TCLP Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date 1 1311/3010A 6010D 1 09/12/2019 0259 LLL 09/11/2019 1726 28648 09/10/2019 2043 1 1311/7470A 7470A 1 09/13/2019 1320 KSH2 09/12/2019 1455 28691 09/10/2019 2043 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Arsenic 7440-38-2 6010D ND 0.15 0.025 mg/L 1 Barium 7440-39-3 6010D 0.097 J 0.25 0.031 mg/L 1 Cadmium 7440-43-9 6010D ND 0.050 0.0060 mg/L 1 Chromium 7440-47-3 6010D ND 0.10 0.013 mg/L 1 Lead 7439-92-1 6010D ND 0.10 0.047 mg/L 1 Mercury 7439-97-6 7470A ND 0.0020 0.00091 mg/L 1 Selenium 7782-49-2 6010D ND 0.20 0.085 mg/L 1 Silver 7440-22-4 6010D ND 0.10 0.021 mg/L 1 Footnote(s): 'Paint Filter: 64mL collected; LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9of13 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 13 SHEALY ENVIRONMENTAL SERVICES, INC. z C � Cw 1 r- ❑ � � E S L] L6. 4 E 4 MLIS O w r � � t db 9 C - a z 'S' m Of 131 3 — F 1- F F F. i= y r °P E 17 o!1rt IWO QQ1 4 = U Ys U c Z� a �saa:�pco 114 Jeal!j JU!ad ;n {u�nJaS m m a � W'$hf 4Jfi�Jil� and HC X c eplsg�ed -r1w1 lla= 5i5lJ' '. ... L u g F L H o sr FD tj� CL m Q G 0 0 0 1 2 1113.IIr� a m J C 1 t . _ L. d dD N rs z Z c 1 Fr" p'zt a31 m m E Ll p n m ,u m C 25 5 _ N iw Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 13 SHEALY ENVIRONMENTAL SERVICES, INC. o �r�. C3� O a� ln� CM I Q4 1 1 F E Li c� ,Q 3DD V .- ❑❑ 0 a ? a� 4--n Puce no, z 0 m a Ja;lld ItgQd �} YPdN a�@Ilu 4g rC .r Lj �y'y ODd GS 0 c a x Z = 1= E .0 J ,r s {% Li = rr in HU 3 E } m CL Ir n�6 ill 54 ci 4 LLI v r apl!41aF1 �pl�]saddlDllF'� `- [+ Cn 3 i` o �r fj � J9Lij[� }� a � �• ❑M u]" to E E E *" O CL IT s LL .yy LL 12 2 Ld `6 8 m YL E R 3 T€] � � � � � a � qg�� to ❑ 8 C � � rc�q 3 ID b 4L z p Y y 2 EL a 5 qu mELL R Z o ¢ {4 A] p) L 4 LQ q as R' _U J3 - 73 }aJ C = aa.. G7ILI C C j-- o. ® - F fY PJ y Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 13 SHEALY ENVIRONMENTAL SERVICES, INC. Shealy Eii�li iiiml:iI 4,r.nviceg, [nti L?oewncrd Nuroher: 61Riaif mil= :,Jgd 1 nr1 Sample Receipt Checklist (SRErre e Cuenr: Synagro C{nllcr h specied dmc: EmN 1 9r6}1 I.o[ = 11106072 Means ofreceipt: SES1 ❑ C.IJent Z UPS 0 F dF:a€ Otlxr j� Yes No I_ �Wc,re cu-md xals resent On the cooler? — Yes No NA 2_ If c:hslod • seals were eser{ ,�•s,7s d7e intact and unbrokcth'f pA Strip 1D: 7w.4 Chloflno Strip JD: NA Tested b , NA Origin%l temperature upon receipt i Oerived (Convcted) temparat"re upgn receipt %Solid Srtap-Cup IT]_ 19-1616 ► letlioul: ❑ Tcmperawm Blank JZ] Agaill5t BcvTes fR Gun IA. S ITS GLrn GarrL•ctiQn Paf tvr: aC cthodot'eoolant. _ 0 'i4ct Ice Q Ice Fackh ❑ Dry lot 2 None Yes ❑ NA rO ❑ AfA ,f tciuperatum of any cooler exceeded 1i.01C, wew Project marhager NOLifWd7 PM vas Notifod by, p1lenc f emai facz_to-fiwte (circle aneX YQ5 No ❑NA d_ Is thecvrnmeirialcow-fer'slwkingsli aaachodto>iliisfiwm,, s_ Wr.re. }srolxr cusWdy proccdurC.g (-1:Hnquishedfrrncivcd) folluwcd? b, Were somplc IDs listed on the i C7 'T Were sampic JDs liswd on all sample contaiiiws?' EYHEE11 8_ Was collm-ton date k time listed an the 9. Was cNkction date & iane listed on all &-Lmplo contain10Did alT corniabwr rabid intomiflcm (1D, dtrGc, time) writ with the Cx{ I I- Were tcbts t4 be Perfumed lisled on the COO ❑ Yes 0 No 12. bid all sumpJes atrivc in the prvpirr containers for each test andlpr in good enrid bear 1(ujj1bnjkcEL. lids ism, etc.)? thu r es i__! NtolqA 13. was adequ fft� sample volume available° WJ 'es Elmo 14, 'Were all santptex received wirhin Vz the hold big tine or 4E liourg, whichever 00mes fiRV9 Ycs J13, J rc arty sgm les C4ntuarers rnis5i¢rgr'exeesS l.circle ore) sa its Not listed on COC? ❑ Yes ❑ N16_ Iff V0A and RSK-175 samples, were bubbles present �`pr,-,vsize' (W'or 6mm in diamet in an�r of the VGA vials? ❑ Yes N17. 'Were all DR t?hnrstalf t urtrieu[ samples receircd at a pp of � 2? Yes ❑ ?U v ®NA i 8, Were a1T cyaenide sumplca received a[ a H > ] 2 and stdfide s�rrrples received at a H > y7 ❑ Yes [� No N l9' Were all app [c le hIH c}anidc tlsenOl. 5 (•. q.5mg.L) Same es + e ❑Fresidual ❑ Yes ❑ Na 20, Wero client remarksfrequests (Le. requested dilutions, 1�1WMSJD dell DNA 9hations, etc,.,) correctly transojihcd from the C intth the ceirurlm secdm in LIM? Yeas No 21 _ Was the quQte awnlvr lisped an tfte coutRinc:r label? if yes_ OuWr. ar NA inple ��rtiou (.MLtst be completed fur any AL110e[8) inc.pll �V pr�scTved r,r with lr lypace.) rnp]c}(s) N NA wee IW6vcA incorrectly prase, vLcf and were adjus&d ace saurplt! receiving will) LNA _ mI, of circle cmc= ICS04, HNO3, RC.I. Na0H [isimg 9'R # NA att~ Qf present atim lVr1 ff more ih ane preservative is needed, please note in the comments hel ow. NA vrm received with bu bbles >b olio Ln ctf srr[erer. '''p � " _,Prcre received with TKC > (a_S n L (11-k 19 is to) and wc, accordingly in salty pile race iviN xlth sodium ihitrsulfate (NaA03) with Shraly TD: NA baju)Lk labels applied by: DM. N C OtrIMMIS' "I J 13CiJ_I_tphl' battle frrr N&M G]i loded in cooler_ Date, 9}6fl 9 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 13 SECTION 5 Facility Name: WWTP Name: ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) of Lincolnton W WTP Lincolnton WWTP WQ Permit Number: NPDES Number: WQ 0002712 NC 0025496 Monitoring Period: From 01/01/20 To 03/31/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion m _ �i..a,. �1,., r,.11.....:.... ... nitnr:no data• If a licable to alternative errormea - Allowable Level in Sludge ass A of l aSS y com wac eaaa .vuo...,. -------- Pathogen Density No. of Frequency Sample Analytical Parameter Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal WO to the 6th MPN MPN/g Coliform power per gram of total solids 19 368 1041 CFU/g 0 Quarterly Grab CFU SM SM 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) X (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification in ing fine an imprisonment Robert Pearson Water Resources Director APrrer'Narne and Ti type or print) Land pplier Name and Title (if applicable) (type or print) tie_re of Prepare ate Signature of Land Applies (if applicable) Date *Prepares is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) v%A 11 IICH I , SM 2540 B-2011, 2540 D -2011 NCO025496 wudl LUI I y eal p 74-120 z a All weighings are done in grams NMI` RN'T MR ---------- Time Collected 0 0" el 19 Date Collected Z-0 Date i Time In Date / Time Out Total Wet Wgt f3, 9/ tO Dish V41 g.3 2.3 Wet Sludge Wgt D-41 (I 03-105'C) Dried wgt 6 J-1 2.), Dish (01 (,oyY, z3.3 6 Ll !?3 Dry Solids Wgt 4 5-* % Solids AVG % Solids C) ovz) Time In/Out (103-105'C) Dried Wgt 2- 550°C Wt I D 4/� Volatile Solids Wgt % Volatile Solids e2 7— V Yo 2— AVG % Volatile Solids % TS DAF % TS Sludge OX3- -VS -bjkP = y,0 % VS Sludge = ?3. 3 % Total Solids = My Solids Wgt -X 100 Wet Solids Wgt % Volatile Solids = (Volatile Solids Wgt) -X 100 Dried Solids Wgt % Reduction e (VS DAF - VS Sludge) x 100 VS DAF - (VS DAF)(VS Sludge) ***See Effluent Fecal Coliform Setup for QA Data o Method: 9222D SM 21 st ed Temperatures are in C Collection Water Bath Colony Calculate % Reportable Setup < 8 hours after Grab Read 24 +/- 2 hours Count Colonies Colonies TOTAL Colonies ml Date Time By Setup Removal per per per SOLIDS per Time In By Temp Time Out By Temp Used Filter 100 mUFilter 100 mL/Filter g A B C D CID L)D 4�-<t'�, 0.01e CFU i 0.1 aa V ; L P f 5 ,�- q T.5 f a 68/;z ? CFU 30�0 0.1��� -- o � � qC % '�% � CFU p Z aZ oe0 ez 9 aO U CFU 0.1 D Z,u9 /0 00 l i 3L) t1 � � 0 �j°�� ,�... � ('s 444. ti .,� o � l � � � CFU � � 07 �0�� `'(��5 I�ZV .9it� (�� -e"r+ �� © % CFU —8H 1.01 � /0 d.s SOD 1z CFU 0.1 v Technician lx- " SM 2540 G-1997, 2540 D -1997 Quarter / Year All weighings are done in grams j 5%zaz D Time Collected / d O / a © y, Date Collected �.(�� 2-0Z0 ZDZD / , Z6 Zf7 1—r'�-Zo2i3 �•ls" Z49i;-0 j—ZZ_- Ze�)zcv Date/ In r'��-Z0Z d 1,4 ��Z07-'C� l r � �r �ZpLiS .1S-ZDZ-b ZZ ZoLD Time 0 Zi 0 5 3a pp 02� Date/ Time Out 1�'l-Zo0(� C-Z4�0 3 f lo-Z-02-9 6 �Lo �� j-/�-2vz0 p (o O t7 1J`Jr-' -rzp Q Y �-a.'Z.02-� 1) rra 0 ca � M ,v Total (, Jog A!, ad 7 713 ► ?4 // /11,`774t0 �� 9a • 3sf� ll D , 9�q`f lvr. i3$7 Wet Wgt Dish 'fi`f. g3� �(�, ►a`f�.2 ��, 2(e3�( ,��'i� ����% q(o.a& ;Lg4,9 gq'��°lZ �`�r�a/o A`iA�/ Lh-.2.33� �1,.2 6e Wet Sludge Vgt ,�%�� 3��� ���i4`��o �(,(g?�1� �� �127 ��r�z "I�►�/�� ��� 5�. ��Z� �B�S� •_ {103-105°C) SZ� �`�,rl`tZ� 5(,�i0o3 �5 ,��G� ��) l �rlWfp �q,�bb �%, d��� 'w' �rz 7).Z306 5 C1, ZZSS° Dried Wgt qq ` o Dish`f quo 'G1c-j&* qq,1$b( ��•2 �.(..2`f(ofl / �, ale Y'�. ��1 �'�' "��Y� Z33t r6,2-6�a� Dry gtids �, j,�� � a�l_� 3,Z�f a• �% 3,30� a.�3�ff t', C�, tG3r�� % Solids f , 3 I l ' S' 3,) �� (] l [ �1 (r ! Ct c V i v Average %Solids ! .1 �� -i f -l• / l / D RPD All I % Total Solids = Dry Solids Vogt X 100 Wet Solids Wgt ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WWTP Name: Lincolnton WWTP NPDES Number: Monitoring Period: From 04/01/20 To 06/30/2020 WQ 0002712 NC 0025496 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion ni_..., n� .. ..1oto fl.n f..11nwino mnnifnrina data' If a licable to aiternanve perrormeu l l'dSS Allowable Level in Sludge H Ul \ itlab li wua .cw ... .o.. ..-•------------- Pathogen Density No. of Frequency Sample Analytical Parameter Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2xl0 to the 6'h MPN MPN/g Coliform power per gram of total solids 53 248 877 CFU/g 0 Quarterly Grab 9222D CFU SM 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 (VS reduction) X Option/Alt.2 (40-day bench) Option/Alt. 3 (30-day bench) Option/Alt.4 (Spec. 02 uptake) Option/Alt. 5 (14-Day Aerobic) Option/Alt. 6 (Alk Stabilization) Option/Alt. 7 (Drying — Stable) Option/Alt. 8 (Drying — Unstable) Option/Alt. 9 (Injection) Option/Alt. 10 (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the athogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification in ding fine and imprisonment." Robert Pearson Water Resources Director l a, I ss C Pre er Name and Title (typ r print) Land p lier Name and Title (if applicable) (type or print) Signature of Preparer* Date Signature o and Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) I echnician�' SM 2..,40 8-2011. 2540 D -2011 NCO025496 uuarter / Year c-�I- ry L) All weiahincis are done in grams '. y/'�. tY t jl 5®4 .� t {{ %. )t: 5 k.�.11 {��. 5; F% •' J$t ` ,pf "��Tb. .p+� 4 F 2 .�f�' k � � ' r� � .'L � /e� � .yQf�y� SM5`�„-.1- =/ _ Time Collected Date Collected Date / Time In Date / Time Out Total Wet Wgt Dish Wet Sludge Wgt 4�9 J YO (103-1 Dried Wgt Dish Dry Solids Wgt % Solids c ) 6 0 �l) AVG % Solids Time In/Out (103-105°C) Dried Wgt U �/ ( D 1�' ! 550°C Wt 1 f Volatile Solids Wgt � � / 3 / / % Volatile Solids 0 AVG % Volatile Solids I �2, /( C l J s� c 30 % TS DAF = % TS Slud e = % VS DAF = L' VS Sludge = 9 1,3 % Total Solids = Dry Solids Wgt x 100 Wet Solids Wgt Volatile Solids ( /o ° Volatile Solids Wgt) X 100 = Dried Solids Wgt % Reduction ® (VS DAF - VS Sludge) x 100 VS DAF - (VS DAF)(VS Sludge) �r q"3 pay' m �gy SLUDGE Pedal C®iif®rms ***See Effluent Fecal Coliform Setup for QA Data Method: 9222D SM 21st ed Temperatures are in °C Collection Water Bath Colony Calculate % Reportable Setup < S hours after Grab Read 24 +/- 2 hours Count Colonies Colonies TOTAL Colonies Date Time By Setup Removal ml per per per SOLIDS per Time In By Temp Time Out By Temp Used Filter 100 mL/Filter 100 mL/Filter .9 A B C D C/D lE% LC! CFU pt ,10 R � CFU { L4 L,°'w #"�" [i�i� •�" /` C (� 3 f `,- CFU �l / Lid . f 7 f i CFU t CFU !I �p 4�,.' &� ✓" P, 4'w s ;:; 6b` r ✓ CFU f GJ "i 6�&1 f1 51i CFU ✓U°,Tt✓ �%�-`,�� �'� Technician` SM 2540 G-1 997, 2540 D -1997 Quarter / Year 0 All weighings are done in grams Time Collected Z. 0 Date 3, 2—L g�z Collected Date Time In zt- ZZ) Lk 24 - L-C Date "LA jj Time Out Total j qq jq 5 3.03 Wetwgt Dish 2- C 3 oc'31 A0 lq�, Wet Sludgel�p GY L Wgt (103-105°C) 01. LE -S q4, q3 Lo Dried Wgt Dish q q 2- YL-JL') V6_36(j litqi;vk) iLt 3f2-3 Dry Solids Wgt 2-Z, % Solids 3,3 3,3 f Average % Solids tj Lit t, % Total Solids = Dry Solids Wgt —X 100 Wet Solids Wgt ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WQ 0002712 WWTP Name: Lincolnton WWTP NPDES Number: Monitoring Period: From 07/01/20 To 09/30/2020 NC 0025496 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion -a ini...... A ,.,. /''1..�� Rl ....mol-a +he in l folowg manitnrinu data: it a ncanie to alternative eriuruicu Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 (VS reduction) X Option/Alt. 2 (40-day bench) Option/Alt. 3 (30-day bench) Option/Alt.4 (Spec. 02 uptake) Option/Alt. 5 (14-Day Aerobic) option/Alt. 6 (Alk Stabilization) Option/Alt. 7 (Drying — Stable) Option/Alt. 8 (Drying — Unstable) Option/Alt. 9 (Inj ection) Option/Alt. 10 (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the athogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification inc ding fine and imprisonment." �1 r Robert Pearson Water Resources Director F�O- J Pr rer Name a itl type or print) C^`'/�-[- 2 Land p lier Name and applicable) (type or print) 2A 7il T Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) SM 2540 $-2011.2540 D -2011 NCO025496 All weinhings are done in grams 43d`�'}{�, }'s 'c vt v^Jf .r�nJ �j �i ` ,{-[`4�JF' 'r`y .,/�i. .'�, a/...a_..- .+-s...�� f..� P Time Collected `ry Date Collected ` -` z V Date / Time In r . - ` Date / Time Out Total Wet Wgt n V? Z c 1 c Dish�- Wet Sludge Wgt (103-105°C) Dried W9t L r '� C i3 .� 9107 &• ,--zeta Dish 11 L(, 7j Dry Solids Wgt C l l �- 1 % Solidsf 2 c AVG % Solids 3 1 Time In/Out (103-105°C) Dried Wgt ` c,: � e 550°C Wf ' 2 Oat Volatile Solids Wgt L Volatile Solids C 7 s AVG %Volatile Solids %Volatile Solids T� Le % TS DAF % TS Sludge = G % VS DAF = r % VS Sludge -- % Total Solids = Dry Solids Wgt 00 Wet Solids Wgt % Volatile Solids = (Volatile Solids Wgt) X 100 Dried Solids Wgt % Reduction = (VS DAF - VS Sludge) X ,100 VS DAF - (VS DAF)(VS Sludge) 3 rs 3$<b � yj1 SLUDGE Fecal Coliforms ***1 � nnn�rl QNA ')I �+ —4 See Effluent Fecal Coliform Setuo for QA Data Temoeratures are in OC Collection Date Time By Water Bath Setup < 8 hours after Grab Read 24 +/- 2 hours Setup Removal V Colony Count per Calculate Colonies per Colonies per % TOTAL SOLIDS Reportable Colonies per ml Time In By Temp Time Out By Temp Used Filter 100 mL/Filter 100 mL/Filter 9 A B C D C/D 0.01 jA CFU 0. pt)o CFU 0.1 C) r 0, 60 CFU 0.01 CFU 0.1 15, 0.01 CFU 0.1 lG 0.01 -0 t 0 CFU 0.1 0.01 CFU C' Technician Quarter I Years Cy SM 2540 G-1997, 2540 D -1997 All +weighings are done in grams ..,. .... •.:. ....d :. �- 0^ ,v l rity .nsSM1. 'i ,, . ..,� , �a..F�-''r . 5+,+ �...:. n• ... .r ,; ... Sr .. a.H.s„ r::.�,....,.. � �x�%cs� kexq, a 3 .. , .k :, : +'. �i. (r .. .. � E. ... ., y;�, ram. ,�� rt" s,. ;fix §,%f' v's:v,u '�.. �' "9v ,.,.. :S .r ... ....�". �"�:';:��:'± :n: 'F:, ,..� P'J.'C i.Y ...:r ,, >�: �. +_n,�.. v>�. i, a G . , a., .c t 1.r f• ,. � ��i. x£ 1,) ,..� +0.`s; aa! .l s^ "S�i1�'CI � M .. ,� n,.u. ,: -.ten ...� . �'i ':r r t. .. ,+rd, r„ �n-. � iL, Z.nt,..v ••d,... i,,�F n ,•5�.. , � � , %r;^�':� . re*..��h . m�... #'- k�' ,x..... ,. , . , : ' u . », trlY l.:�,.^^=i.. r:._. uv.x ...-.:,. F}s..�.,' x ... :.:.. M, �- T ...� d . ,� :& ( � 4,.• �S � �P .w•`.e y „{+tr.:?, .,�.�.WLid d "!''. �5?h Time Collected t r� µ33 t C/ ` C� y= (ice y �% t ? t��� LL ' ate Co ected ' / ' Z L� " `�. v Z - (` 2 - _ r ` G - 7-v - 7 Date Time In 'jpt�, �✓ ` !pc} Qf Date ! Time Out � � c� r C? �q� f ri ?ate C 7 � ��► 7 `j��. io Total t Wet Wg � 1 . �f 'j' � � IN i �� ��. �`'`3� ��� �5 ��` C��' � ��'3�� 11, Dish ��� 3oa5- y, 2zaS, g6,z!l6, r � �y +��� 3t�Ef �G{. q, 2 j C v3 Q 14 WetWg{dge DFc>°�wOi° 'C3 0�� 0 (103-1050C) Dried Wgt ClE)3 (� r� ��+ ��lt<J L�") * 171 / 7?�/7tr; �1�i°� / ��3 I "t tZ� '"• / ) �� �i�`at� Dish q`j60 - ,t `t•l`c& `i64 fa4 �'It31 Dry Solids W % Solids J• U 3,5 Average % Solids C� L7 t 36 RPD % Total Solids = Dry Solids Wgt X 100 Wet Solids Wgt ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Lincolnton WWTP WQ Permit Number: WQ 0002712 WWTP Name: Lincolnton WWTP NPDES Number: NC 0025496 Monitoring Period: From 10/01/20 To 12/31/20 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion o� Con, Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 4 (Spec. 02 uptake) Option/Alt. 8 (Drying — Unstable) Option/Alt. 1 Option/Alt. 2 (VS reduction) X (40-day bench) option/Alt. 5 Option/Alt. 6 (14-Day Aerobic) (Alk Stabilization) Option/Alt. 9 (Inj ection) Option/Alt. 10 (Incorporation) CERTIFICATION STATEMENT (please check the appropriate statement) Option/Alt. 3 (30-day bench) option/Alt. 7 (Drying — Stable) No vector attraction reduction alternatives were performed "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification in uding fine and�pprisonment."_`C Robert Pearson Water Resources Director A'� `� �+ Pr re, Name and Title (t or print) Land Name and Title (if applicable) (type or print) 7 At Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) uuarrer t Year [echniclan SM 2540 B-2011, 2540 D -2011 NC0025496 All weighings; are done in grams Time Collected (qc2 zz d Date Collected Date / Time In Date / Time Out 10 -13 - Total Wet Wgt rt L2 - 0 10 Dish d7 Wet Sludge Wgt (103-105°C) Dried A, Wgt 3 Dish 2-o Dry Solids Wgt ✓ 23 % Solids 2 LA V G L-%/.S o fri d s Time In/Out 2,:3 b (103-105°C) Dried Wgt 550°C Wt x /,5— q�, Volatile Solids Wgt -3 7 % Volatile Solids AVG %Volatile Solids --------------- % VS DAF % TS DAF = % TS Sludge = % VS Sludge % Total Solids Dry Solids Wgt ..---x 100 Wet Solids Wgt % Volatile Solids = (Volatile Solids Wgt) x 100 Dried Solids Wgt % Reduction (VS DAF - VS Sludge) x 100 VS DAF - (VS DAF)(VS Sludge) 0/1 SLUDGE Fecal Coliforms ***See Effluent Fecal Coliform Setup for QA Data lL.tk A 071)17r1 cnn Oi9 +cry Temperatures are in °C Collection Water Bath Setup < 8 hours after Grab Read 24 +/- 2 hours v Colony Count v Calculate Colonies Colonies % TOTAL Reportable Colonies ml Used Date Time By Setup Removal Time In By Temp Time Out By Temp per Filter per 100 mL/Filter per 100 mL/Filter SOLIDS per 9 A B C D C/D C 1 j CFU Ga�,n `� -C3 - �� p� % / 'f'�`5 C ✓ f� GAS •,�-. t5 '�`C �9-�99 `�iJFrit lJ L1 'ter' �2 L 3133 CFU �% /� lU fJ`Y% �i /� �J g3 ` CFU i OL)4cy` � l� t l') `° L lt�% ✓is`—�,� `{ s to �� rr;; / �) ✓� CFU .� CFU 1333 �723� Y ZJ � � $-e z - /� l ' y � ' CFU _ �9-f' CFU Technician SM 2540 G-1997, 2540 0 -1997 Quarter / Year 1-14 All weighings are done in grams ,., c. ,. �;,. .�- w -- . ...,.. vim, -:s:,. "L ,,�..Q„_+:• ,. +,� _.;. c- ,. 1.:r —:. .. t.,>_. -A' .c� Y +n i ..�:': ;..:. - .... k'. .: . � .. R . �*' .<.�. , . v::: s.. -:.: - .a .. ..r.- 1:. .. r � v -.:;.7 .. •.xo S ... . .;>. i., 3� Y -_ '\ - ;bx %+' -,.�_ 4 • ,. was.. ... ..; , a J--we- � .. =44, x�h-�x'++• t C: Time Collected {�� l� 0L ) OC / Cj O v �1 ( !V 0 ✓ `y Date _ z-'� � .�� 3 -- L i� � �- � � _ z- � � -r s - � �> % � - ,� � - z� " 2- c3 � � - Collected � � ! z �, Date/ 1 u- /Z. Z'v ia_�3— 2.3 � C3 j�.-l`fY �,�®15"_� /.i-�'C�- /!�� Z- L, 2. 2 0 �-(- Time In Z L zoo Date I d C 3 - `l _ 2- L >, l �-`� ` ;j ! (s - 2 u' - 2 l - L c { z z - c, Time Out �> 7 `j i Ga `J ` � ��� I� .; / 0 (; � � Total t-' �r�;3' l U � 3% "� �`( (� � l� ' Wet Wgt �J �. r 1 I � Dish;3 V6 7 , 3 WetSludge a��y,L�` � b i7 /,.j v�U�' .-,+������tti-�(' ^.}�L����D ����� '�ipq y.��, _L 2(I�,iy�`0� �4"�,6) .�`�� � G l (103-105°C)`��?C� •� 1 1 �" t ' � Il i 7�` i.� t�l i�`D "l ;ia .�j1 � .d:� � l,�y,`% i�.j,.`J L 6 Dried Wgt 4 ,�`l .� -7f " 1 Dish j i � ` 3 J t� � 1�� O iv �w - a� t r� � � `�. b i i/`f �^, WI) / 4,�, .7 , .JI c Dry Solids `� asp-(` L W� cr'�t�►�' �7►l� %Solids Average, �r > 4 ✓' L a '� % Solids % "Total Solids = Dry Solids Wgt X 100 Wet Solids Wgt SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Lincolnton Field (state -county -site -field) So"F-11 pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied NC-CA-35-2C 6.3 O.OT/Ac. NC-CA-48-10 5.6 1.OT/Ac. 1 Ton 03/20/20 NC-LT-47-2 5.1 1.0 T/AC 1 Ton 03/20/20 NC-LT-47-4 5.8 3.OT/Ac. 1 Ton 03/20/20 NC-LT-48-5 6.7 O.OT/Ac. NC-LT-19-1 6.0 O.OT/Ac. NC-LT-19-3 5.9 O.OT/Ac. NC-LT-49-1 5.4 .50T/Ac. 1 Ton NC-LT-49-2 5.8 O.OT/Ac. NC-CA-24-9 6.6 O.OT/Ac. NC-CA-48-4 6.2 0.50T/Ac. 1 Ton 09/20/20 NC-CA-35A 6.9 O.OT/Ac. NC-CA-35B 6.9 O.OT/Ac. NC-LT-47-5 6.0 O.OT/Ac. NC-LT-48-8 6.1 O.OT/Ac. SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002565 �5{i �141..tiL Client: Synagro Advisor: Predictive ;• Synagro r. 284 Boger Rd. r, Soil Report Mehlich-3 Extraction Mocksville, NC27028 Links to Helpful Information Sampled County: Catawba Client ID: 503079 Advisor ID: Sampled: 07/25/2020 Received: 08/19/2020 Completed: 08/26/2020 Farm: ch-24 (Mike Davis) Sample ID: 9 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.0 0 50 50 0 0 pH$ 0 0 0 Note: 3 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.32 1.07 6.6 91 0.6 6.6 38 47 63 24 103 105 65 106 106 201 0.1 2 Noah Carolina FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002565 Synagro Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL003744 �5{i �141..tiL Client: Sidney Turbyfill Advisor: Synagro Predictive 4300 Biggerstaff Rd Synagro ;• Maiden, NC 28650 284 Boger Rd. +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Catawba Links to Helpful Information Client ID: 285863 Advisor ID: 503079 Sampled: 09/01/2020 Received: 09/08/2020 Completed: 09/16/2020 Farm: ca-35 Sample ID: 3a Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 10 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.18 1.02 13.5 97 0.4 6.9 127 73 81 14 64 487 296 195 195 143 0.1 1 Sample ID: 3b Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 50 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.13 1.06 8.3 96 0.3 6.9 82 42 83 11 51 370 225 101 101 156 0.1 1 Noah Carolina i� fdtaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL003744 Sidney Turbyfill Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 20-042-0576 Account No: 46476 Advisor: Synagro Central LLC/ Newton Mary Brewer 284 Boger Road Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Turbyfill Poperties Newton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: CA-35 Date Received: 02/11/2020 Date of Report: 02/13/2020 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 22000 2C 2C MIN 6.3 0.9 56 72 33 69 108 108 110 8.6 89 70 14 0.8 0.1 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Mn-AI Zn Cu B Mg Last Crop 1- Fescue Hay lb/acre 0.0 150 15 10 20 0 54 0 0 0 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005775 �5{i �141..tiL Client: Alex Fox Advisor: Alex Fox Predictive Synagro Synagro ;• 284 Boger Rd 284 Boger Rd $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County: Catawba Client ID: 501947 Advisor ID: 501947 Sampled: 09/15/2020 Received: 09/24/2020 completed: 10/02/2020 Farm: CA-48-4( Mike Davis) Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 80 60 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.22 1.00 6.9 88 0.8 6.2 24 39 61 24 227 72 57 121 121 129 0.1 1 Noah Carolina FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL005775 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 20-071-0689 Account No: 46467 Advisor: Synagro Central LLC/ Lincolnton Mary Brewer 284 Boger Road Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Mike Davis Lincolnton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: CA-48 Date Received: 03/11/2020 Date of Report: 03/12/2020 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 14960 10a MIN 1.2 5.8 0.7 160 42 21 81 130 130 255 3.8 82 58 18 0.9 0 Crop Recommendations: 1- Corn Rec Uom lb/acre Lime (Vacre) 0.5 N 160 P205 0 K20 55 S 20 Mn 0 Mn-AI 69 Zn 0 Cu 0 B 1.4 Mg 0 Last Crop 14961 10b MIN 2.5 5.6 1.2 123 69 35 81 158 158 350 5.2 78 53 18 0.7 0 Crop Recommendations: 1- Corn Rec Uom lb/acre Lime (Vacre) 0.5 N 160 P205 0 K20 10 S 20 Mn 0 Mn-AI 72 Zn 0 Cu 0 B 1.2 Mg 0 Last Crop Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031455 �5{i �141..tiL Client: Chuck Waters Advisor: Alex Fox Predictive 3529 Killian Road Synagro ;• Lincolnton, NC 28092 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Client ID: 409870 Advisor ID: 501947 Sampled: 05/08/2020 Received: 05/29/2020 Completed: 06/05/2020 Farm: LT-1 9-1 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.46 1.10 8.7 84 1.4 6.0 183 33 57 25 47 731 456 371 371 271 0.1 1 Noah Carolina i� Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO31455 Chuck Waters Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/v weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032840 �5{i �141..tiL Client: Chuck Waters Advisor: Alex Fox Predictive 3529 Killian Road Synagro ;• Lincolnton, NC 28092 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Client ID: 409870 Advisor ID: 501947 Sampled: 06/24/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: Lt-19 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 70 90 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.41 0.92 6.9 85 1.0 5.9 28 25 52 31 67 339 220 83 83 192 0.1 1 Noah Carolina fdtaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32840 Chuck Waters Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/v weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 21-004-0520 Account No: 12259 Advisor: Synagro/Columbus NC Mary Brewer 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Randy Leatherman 2020 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: LT-47 CA-47 Date Received:01/04/2021 Date of Report: 01/05/2021 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na 109910 2 MIN 1.9 5.7 1.1 70 51 64 88 74 0 130 130 210 5.1 78 53 19 1.1 0.1 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.5 N 150 P205 0 K20 40 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop 09911 6 MIN 1.9 6.6 0.8 564 54 12 188 121 0 433 433 200 13.9 94 84 7 0.8 0.1 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.0 N 150 P205 0 K20 40 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop 09912 7 MIN 1.6 5.7 1.4 164 35 12 288 194 0 128 128 95 6.6 78 63 12 0.7 0 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.5 N 150 P205 0 K20 68 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002564 �5{i �141..tiL Client: Randy Leatherman Advisor: Synagro Predictive 3322 Dansbury Ln Synagro ;• Vale, NC 28168 284 Boger Rd. +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Client ID: 502961 Advisor ID: 503079 Sampled: 07/25/2020 Received: 08/19/2020 Completed: 08/26/2020 Farm: LT-47 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 0.3 0 140 60 0 0 0 6 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.09 0.96 4.6 77 1.0 5.8 4 40 42 31 326 28 27 23 23 55 0.1 2 Noah Carolina i� Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002564 Randy Leatherman Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 20-071-0690 Account No: 46467 Advisor: Synagro Central LLC/ Lincolnton Mary Brewer 284 Boger Road Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Randy Leatherman Lincolnton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: LT-47 Date Received: 03/11/2020 Date of Report: 03/12/2020 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 14962 2 MIN 2.6 5.1 1.6 47 48 121 63 78 78 180 4.2 61 41 15 0.6 0 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Mn-AI Zn Cu B Mg Last Crop 1- Soybeans lb/acre 1.0 0 31 40 20 0 61 0 0 0 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011126 �5{i �141..tiL Client: Randy Leatherman Advisor: Synagro Predictive 3322 Dansbury Ln Synagro ;• Vale, NC 28168 284 Boger Rd. +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Client ID: 502961 Advisor ID: 503079 Sampled: 10/23/2020 Received: 10/28/2020 Completed: 11/12/2020 Farm: LT-47 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 20 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.51 1.07 8.4 88 1.0 6.0 95 64 65 19 48 188 129 246 246 221 0.1 1 Noah Carolina Futaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011126 Randy Leatherman Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031450 �5{i �141..tiL Client: Mike Davis Advisor: Alex Fox Predictive 284 Bogar Road Synagro ;• Mocksville, NC 27028 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Lincoln Links to Helpful Information Client ID: 508842 Advisor ID: 501947 Sampled: Received: 05/29/2020 Completed: 06/05/2020 Farm: LT-48 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.27 0.97 11.8 96 0.5 6.7 261 128 67 24 48 295 183 639 639 433 0.1 1 Noah Carolina fdtaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO31450 Mike Davis Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 21-004-0519 Account No: 12259 Advisor: Synagro/Columbus NC Mary Brewer 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Mike Lewis 2020 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: Lt-48 Date Received:01/04/2021 Date of Report: 01/05/2021 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na 109909 8 MIN 3.0 6.1 1.4 124 139 23 175 120 0 333 333 225 10.3 87 55 24 0.6 0.1 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Zn Cu B Mg Last Crop 1- Fescue Hay Ib/acre 0.5 150 0 0 20 0 0 0 0 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032835 �5{i �141..tiL Client: Alex Fox Advisor: Alex Fox Predictive Synagro Synagro ;• 284 Boger Rd 284 Boger Rd $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County: Lincoln Client ID: 501947 Advisor ID: 501947 Sampled: Received: 06/30/2020 Completed: 07/09/2020 Farm: It-49/wesson Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.6 120-200 110 80 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.02 4.6 76 1.1 5.4 14 27 49 24 165 97 75 52 52 70 0.1 2 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 50 70 0 0 0 0 0 0 Note: 12 2- 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.27 1.03 5.1 83 0.9 5.8 36 32 55 24 104 92 72 104 104 139 0.1 2 Noah Carolina i� fdtaw frum Fund Ciwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32835 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm