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WQ0003902_Residual Annual Report 2020_20210222
Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* r Annual Report r Residual Annual Report r Additional Information r Other Annual Report Year* 2020 Permit Number (IR)* WQ0003902 Applicant/Permittee City of Newton Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office Mooresville CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide inforration on the person to be contacted by N B Staff Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ....................................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 14105376150 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00003902 Fbs Current Existing perrrit number Applicant/Permittee Address* 435 Williams Court, Suite 100, Baltimore, MD 21220 Facility Name * City of Newton RLAP Please provide comments/notes on your current submittal below. 2020 Annual Report for City of Newton NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Fans, Specifications, Calculations, Bc.) Newton NC 2020 Annual Report FINAL.pdf 19.46MB Upload only 1 FFdocurrent (less than 250 fvB). Miltiple documents rust be contained into one FJFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/22/2021 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 22, 2021 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2020 Annual Report for Permit No. WQ0003902 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the City of Newton, NC. If you have any questions or need additional information, please do not hesitate to contact Eric Jones at (828) 695-4345 or Alex Fox at (336) 703-8681. Sincerely, oe"i& Shuuc" ,es Derrick Shivar Environmental Compliance Manager Enclosures cc: Eric Jones — City of Newton Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD CITY OF NEWTON, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0003902 2020 ANNUAL REPORT City of Newton, NC Residuals Land Application Program 2020 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WQ0003902 County Catawba Year 2020 Facility Name (as shown on permit) City of Newton, Clark Creek WWTP NPDES No. NCO036196 Land Application Operator Synagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 44 Total number of fields utilized for land application during the year: 13 Total amount of dry tons applied during the year for all application sites: 1,212.99 Total number of acres utilized for land application during the year: 253.50 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2020 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." James Wentz: Public Works Director Permittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) /� ti", z-s -JJ ignature of Pe ittee Date Signature of Land Applier Date (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2020 - 12/31/2020 NEWTON, NC NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS January 2020 516,000.00 G 164.61 D 149.30 February 2020 42,000.00 G 13.40 D 12.15 April 2020 516,000.00 G 202.26 D 183.45 June 2020 558,000.00 G 218.72 D 198.38 August 2020 522,000.00 G 272.09 D 246.79 October 2020 618,000.00 G 194.57 D 176.47 December 2020 468,000.00 G 147.34 D 133.64 TOTAL 3,240,000.00 G 1,212.99 D 1,100.19 Report Date: 1/30/2021 9:20:07 AM SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0003902 Laboratory: Facility Name: NEWTON, NC PACE ANALYTICAL; Waypoint Analytical Virginia Residual Source WQ # or Inc. NPDES#: NCO036196 WWTP Name: CLARK CREEK Residual Analysis Data Product Type Sample or Composite Date LSLIQ 01/07/20 LSLIQ 04/01/20 LSLIQ 07/27/20 LSLIQ 10/01/20 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 7.65 9.40 12.50 7.55 Arsenic 75 <6.49 2.3 1.9 3.7 Cadmium 85 <1.3 0.72 0.51 0.42 Copper 4300 191 220 160 200 Chromium NA 28.6 32 23 42 Lead 840 15.8 18 18 18 Mercury 57 0.21 <0.2 <0.16 <0.23 Molybdenum 75 4.66 5.5 3.3 4.6 Nickel 420 19.7 16 12 20 Selenium 100 <6.49 1.5 1.2 3 Zinc 7500 721 790 510 710 Total Phosphorus NA 10200 8200 7500 4600 TKN NA 21700 6800 15000 12000 Ammonia -Nitrogen NA 5380 3300 2400 3000 Nitrate and Nitrite NA 116 42 13.5 21.3 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines an imprisonment for knowing violations." Signature of Pr arer* Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF-B (12/2006) Printed: 1/30/2021 9:04.39 AM For: 2025 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0003902 Facility Name: NEWTON, NC Residual Source NPDES # or WQ#: NCO036196 WWTP Name: CLARK CREEK Residual Analysis Data Product Type Sample or Composite Date Parameters (mg/kg dry weight) Aluminium Calcium Magnesium pH (s.u.) Potassium Sodium PAN SAR (Ratio) Laboratory: PACE ANALYTICAL; Waypoint Analytical Virginia Inc. LSLIQ LSLIQ LSLIQ LSLIQ 01/07/20 04/01/20 07/27/20 10/01/20 20600 23000 16000 36000 191000 200000 160000 250000 5180 6000 4500 7900 6.90 11.20 11.20 10.90 1140 1300 900 1700 819 970 420 800 7726 2742 4994 4221 0.1394 0.1785 0.0998 0.1178 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." L 2 -S - 2-1 Signature Preparer " Date *Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 1/30/2021 9:04:24 AM For: 2025 01 DENR FORM RSSF-B (12/2006) Waypointo ANALYTICAL 1 /17/2020 Synagro Central LLC/ Newton Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 20-008-0012 Project Description: Newton WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 1/8/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, �a f• c•—r Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 5 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-008-0012 Client Project Description: Newton WWTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 70115 Newton WWTP Solids 01/07/2020 14:20 01/08/2020 SM-2540G WP MTN SW-7471B WP MTN SM-4500-NH3C-TKN WP MTN 4500NO3F-2011 WP MTN 6010D WP MTN SM-4500-NH3C WP MTN 9045D WP MTN AOAC 955.01 WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 5 i Waypoint. ANALYTICAL 46476 Synagro Central LLC/ Newton 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Mary Brewer Project Newton WWTP Report Date : 01/17/2020 284 Boger Road Information : Received : 01/08/2020 Mocksville , NC 27028 Pam« mL 60wr Report Number : 20-008-0012 REPORT OFANALYSIS Pauric McGroary Agronomist Lab No : 70115 Matrix: Solids Sample ID: Newton WWTP Sampled: 1/7/2020 14:20 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 92.3 % 0.010 1 01/13/2016:39 ADM SM-2540G Calcium Carbonate Equivalent 18.9 % - dry 0.1 1 11/16/19 12:43 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 5380 mg/Kg - dry 1300 1 01/15/20 14:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N 116 mg/Kg - dry 61.3 1 01/14/20 14:53 ZBD 4500NO3F-2011 Organic N 16400 mg/Kg - dry 3250 1 01/15/20 10:00 CALCULATION pH 6.9 S.U. 1 01/14/20 05:41 JSL 9045D Total Solids 7.65 % 0.010 1 01/13/20 16:39 ADM SM-2540G Total Kjeldahl Nitrogen 21700 mg/Kg - dry 3250 1 01/15/20 10:00 JPJ ;M-4500-NH3C-TKl` Phosphorus 10200 mg/Kg - dry 64.9 1 01/11/20 02:22 KKM 6010D Aluminum 20600 mg/Kg - dry 64.9 1 01/11/20 02:22 KKM 6010D Arsenic <6.49 mg/Kg - dry 6.49 1 01/11/20 02:22 KKM 6010D Calcium 191000 mg/Kg - dry 1620 5 01/13/20 19:09 BKN 6010D Cadmium <1.30 mg/Kg - dry 1.30 1 01/11/20 02:22 KKM 6010D Chromium 28.6 mg/Kg - dry 3.25 1 01/11/20 02:22 KKM 6010D Copper 191 mg/Kg - dry 3.25 1 01/11/20 02:22 KKM 6010D Iron 13000 mg/Kg - dry 64.9 1 01/11/20 02:22 KKM 6010D Lead 15.8 mg/Kg - dry 3.90 1 01/11/20 02:22 KKM 6010D Magnesium 5180 mg/Kg - dry 64.9 1 01/11/20 02:22 KKM 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 5 i Waypoint.: 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 46476 Synagro Central LLC/ Newton Mary Brewer Project Newton WWTP Report Date : 01/17/2020 284 Boger Road Information : Received : 01/08/2020 Mocksville , NC 27028 Pam« mL 60wr Pauric McGroary Report Number : 20-008-0012 REPORT OFANALYSIS Agronomist Lab No : 70115 Matrix: Solids Sample ID: Newton WWTP Sampled: 1/7/2020 14:20 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Manganese 539 mg/Kg - dry 6.49 1 01/11/20 02:22 KKM 6010D Mercury 0.210 mg/Kg - dry 0.203 1 01/10/20 15:03 TJS SW-7471B Molybdenum 4.66 mg/Kg - dry 3.25 1 01/11/20 02:22 KKM 6010D Nickel 19.7 mg/Kg - dry 3.25 1 01/11/20 02:22 KKM 6010D Potassium 1140 mg/Kg - dry 64.9 1 01/14/20 18:52 BKN 6010D Selenium <6.49 mg/Kg - dry 6.49 1 01/11/20 02:22 KKM 6010D Sodium 819 mg/Kg - dry 325 1 01/11/20 02:22 KKM 6010D Zinc 721 mg/Kg - dry 16.2 1 01/11/20 02:22 KKM 6010D Sulfur 4910 mg/Kg - dry 64.9 1 01/11/20 02:22 KKM 6010D Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 5 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 2-4237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 46476 Customer Name: Synagro Central LLC/ Newton Report Number: 20-008-0012 Shipping Method ® Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 01/08/2020 13:54:36 Page 5 of 5 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Newton VWVFP Lot Number:VD02104 Date Completed:04/10/2020 MIM�� Mr� 04/15/2020 4:44 PM Approved and released by: Lab Director - Greenville: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VD02104 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low percent solids sample -001 was weighed out at 3 times the normal amount. The LOQ has been adjusted to reflect the dilution. pH Sample VD02104-001 had a pH that excedes the constraints of the pH daily calibration. When a pH buffer of 12 SU was run along side the batch, the buffer failed to recover within acceptance criteria. Results will be reported. Subcontracted Analysis The analysis for CCE has been submitted to Waypoint Analytical. This data can be found on a separate subcontract report. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VD02104-001 Description: Newton WWTP Matrix: Solid Date Sampled:04/01/2020 0900 % Solids: 9.40 04/02/2020 2253 Date Received: 04/02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 04/02/2020 2253 HET 49869 1 350.1 (Ammonia - N ) 350.1 10 04/06/2020 1340 DMA 50065 1 (Nitrate - N ) 9056A 1 04/08/2020 1735 HKL 50477 1 (Nitrite - N ) 9056A 1 04/08/2020 1735 HKL 50478 1 (Phosphorus) 365.1 25 04/06/2020 1620 DMA 04/06/2020 1221 50071 1 (Soil pH meas) 9045D 1 04/07/2020 1941 SRB 50256 1 351.4 (TKN) 351.2 1 04/07/2020 1525 DMA 04/07/2020 0952 50060 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 9.40 % 1 Ammonia - N (gas diffusion) 350.1 3300 110 55 mg/kg 1 Nitrate - N (soluble) 9056A 18 5.3 0.26 mg/kg 1 Nitrite - N (soluble) 9056A 24 2.1 0.20 mg/kg 1 Phosphorus 7723-14-0 365.1 8200 1300 270 mg/kg 1 Soil pH measured in water @ 21.8 ° C 9045D 11.2 su 1 TKN 351.2 6800 270 270 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 04/07/2020 1111 KSH2 04/07/2020 0517 50143 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.85 0.20 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 04/07/2020 0854 LLL 04/04/2020 1320 49964 2 3050B 601OD 3 04/07/2020 1037 LLL 04/04/2020 1320 49964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 23000 70 26 mg/kg 1 Arsenic 7440-38-2 6010D 2.3 J 2.6 0.88 mg/kg 1 Cadmium 7440-43-9 6010D 0.72 J 0.88 0.22 mg/kg 1 Calcium 7440-70-2 6010D 200000 2600 330 mg/kg 2 Chromium 7440-47-3 6010D 32 1.8 0.44 mg/kg 1 Copper 7440-50-8 6010D 220 5.3 2.4 mg/kg 2 Iron 7439-89-6 6010D 14000 18 8.0 mg/kg 1 Lead 7439-92-1 6010D 18 1.8 0.79 mg/kg 1 Magnesium 7439-95-4 6010D 6000 880 110 mg/kg 1 Manganese 7439-96-5 6010D 460 2.6 1.0 mg/kg 1 Molybdenum 7439-98-7 6010D 5.5 J 7.0 1.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VD02104-001 Description: Newton WWTP Matrix: Solid Date Sampled:04/01/2020 0900 % Solids: 9.40 04/02/2020 2253 Date Received:04/02/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 04/07/2020 0854 LLL 04/04/2020 1320 49964 2 3050B 6010D 3 04/07/2020 1037 LLL 04/04/2020 1320 49964 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 16 7.0 1.9 mg/kg 1 Potassium 7440-09-7 6010D 1300 880 110 mg/kg 1 Selenium 7782-49-2 6010D 1.5 J 3.5 1.4 mg/kg 1 Sodium 7440-23-5 6010D 970 880 110 mg/kg 1 Zinc 7440-66-6 6010D 790 8.8 2.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC o to I W F: ;3 �C O n OE E t M Z - d J Z yy L Y 7 1 0 {yll`jF u -2 .20 ~ i Ej 91 - x [fj U Li ID = -MGM - } } � £4NH G o O O' C r r 2' 21 snaen y £ 0 F h -uvH ra + 0M 3 13 { w � �i�4 ys� yc 41b g ?! ell`-eGu�:x=J Jrr��s Lain ❑ IJ k m ? G t - k F F E s 4 a 0 10 o ++ [ t Cr o R � Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC Slrealfliwirairwnial Sarrico, Inc. P L oFl Wa:nkcm T#urn6cr. MLaa I W-kf, L-k7ecl:Ve Sample Rccicipt Checldi9t (SRC Cl[—rm SvIkax ro C'ooltr i,1s ected b-Odales= &MCJ � 04,'0212020 1 ALL 9: VD02104 Mrxns of racaipv- M Y'2 hto Yas M No I Q SPSj D CI ient ❑ UPS 0 CM17 Other; — — — 1,'Wore cLL9tod y 3eal E rmiyc--nI oo L1L cu<iler? 777q U1 MAI 2. ll-rusLod wals 1uCTe reser_r~ were thcy kxiL L LLTIJ unt1:0_{e_n? pH Suip ]D; VA C;nkrinrr SLrip ID: LNd Tested by_N.A CeLgir al t&lrlNimfurs upon recLipt f Dcrivud (CCurreued) relnlmrahlre lipim receipt ftSa:id Srap,Cl=p ID: I' iU l3 5.0 15.0 °G NA fNrA -' ?tire r-NA °L NA MA r er$crd, ❑Teulpcmturc T)Ia k 2]Aga:r!,T Bottics 1K Gun ID' _5 LR Gnm Corrcdion Cactor; 4cthud of t,W!LLmt: ® Wet Ict% ❑ [c4 l ,tikes ❑ D Lce ❑ Fuptn El yea M No ®h A 3, ] f w,-RpLvwun of any aaolu ewco&k d 6,0°C, was Project hdanupT Mitiriod? T M was Notified bp: phone ! tarW1 r' ftre-tn-face (cirri le one). Z Yes ❑ ❑ NA 4. Is the vumrremie1 courier`s parking Aip mlached up this tariuT S_ 'Ware proper cunDdy proccdurw (mlin uishedfreceivpd) followed? -6_ Were Sample 116 lisled rbn The C OC 7 ;_ Were sample 1N Ii8iixl Lqk all 99111ple MTtP.iners? s, Was collcctiou da1to & time I is�d an the C(Kt ? 0 Y-us ® Yes _No ❑ Nu ❑ Nu 'es ❑ Nc QZ Yes ❑ No Yes ONO 9. WaS collec#[on date &- [ime listed Oil all sa3np!s c3LNlitiTIM7 10. Did a]I containu labs! in:u1-mu(ia1(ID, date, ti_n.M) agree wltb the COC? ] ] , Were tiests to bo pwrformed listed on tfLe C OC'7 ditio 12. Did all sarrplcs wrivc iu the proper cont9iners FoT roof, last and?or in good corrk (unh vken, ]iLiL oin, dtC )? ._ II Was adcgumwsum pie volume availably' 14. Were all samples reaeivnd w1thin 'A tine holding time Dr 4S hour}, whicJlever comes hr5t? ' S. Were oily samplCB-;HirLLu!7ieet mimi nplexcess (Clrule onel5arr>: Ies Not Iistw) un C }C'7 J6' Fvr VOA and RSK-175samples, were bvbbia3 p-mrm. �`pckt SIz^_" i"Or6mrr in diAmclur) klk Lu1y or Me VOA vials'? Yes EJ No Z Yes ❑ No Y No 1'es 0Ye6 ❑Lilo ❑TAD 77 YCS ®ND ❑ Yrs El No DNA ❑ l Ko NA ]?, Wvru all DRD/1uela]SVrUtrJaill SARI ]ct5 rcrc,Mivcll A. a P1I Of < 2'1 L] YL-, No O A la, Were crarkide samples mmrivedPI a pl:i> 12and sulfidr sstnj laq received at pH> 9? ❑ Yes ❑ No ❑ hA 19. Were al I appl!citble lwj� TX ilcyzinide.+ph ano11625 (< 0_SmWL) saul pies Evc of resi duril uhkrrirLe? .. I El yes" Na a[J11JA4 VJr,,e client iwu9rks/rcqur5t6 (i.e_ recumted dilutions, i�-S iMSD desi4mtions, ex...j nxaL L1v W—flSCC_bed ZYDnl the COO :rlA dia C17Lriment scdian in LIMS? Q Yc5l 61.No � I, Wtm ihu m)w rLur I is-.ed a n tlic CoMairier I ni }el? If"S, QuOle Sample Pr•ewrvation (lvlusL lac L Ur11]}1dR d Far ah, s�Lmple(s) inL nrre tly prea�n�d a� with hwpds ,) 4 sample(J) NA WEIE J%eCPiied incorrott]y preserved and we=zidjusuxiacowdiWy ' in 5zr1p]c ree�ivirke Wi(:n NA In ofcirrie DTiT; H2SO?-, 1-ING3, T-JCI, NsOli usiklgt SR P MA _ 1'1n1S of pDc5cp,%jj0n NA Ifmore Iharl ono preserl xdkre =5 tleedec� pJease now irl 01Ls UD1t1rklt-ilt5 below. Sarnplr:,(s) NA WdjFC =L,,iveti ►y fh Wbbies :-b mtn in diameter. mpleS(5 NA wem t-9ceived with '1'irC: � Fi_5 FngL (1 t19 is rru) wla 1xM adjusted acobrdir>;g[y it sample receiving with sodium thiosulfuue (Na�S,0,) with Shaa]y 0D: NA 1k bamadL: lihchi appliW by: ]3hlG — Du[e- 04fCY2J2920 Cornmrncs: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Newton Lot Number:VG27035 Date Completed:08/05/2020 NIM�� Mr� 08/06/2020 3:34 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VG27035 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Pace policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W' qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to the low % solids value, sample -001 was weighed out 3 times the normal amount. The LOQ has been elevated to reflect the dilution. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VG27035-001 Description: Newton Matrix: Solid Date Sampled:07/27/2020 0845 % Solids: 12.5 07/28/2020 0012 Date Received:07/27/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 07/28/2020 0012 MOM 61416 1 350.1 (Ammonia - N ) 350.1 10 07/28/2020 1325 DMA 61436 1 (Nitrate - N ) 9056A 1 07/29/2020 2009 AMR 61679 1 (Nitrite - N ) 9056A 1 07/29/2020 2009 AMR 61744 1 (Phosphorus) 365.1 25 07/28/2020 1354 DMA 07/28/2020 0935 61432 1 (Soil pH meas) 9045D 1 08/04/2020 2253 SRB 62360 1 351.4 (TKN) 351.2 1 07/28/2020 1501 DMA 07/28/2020 1002 61429 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 12.5 % 1 Ammonia - N (gas diffusion) 350.1 2400 80 42 mg/kg 1 Nitrate - N (soluble) 9056A 12 4.0 0.80 mg/kg 1 Nitrite - N (soluble) 9056A 1.5 J 1.6 0.80 mg/kg 1 Phosphorus 7723-14-0 365.1 7500 1000 200 mg/kg 1 Soil pH measured in water @ 21.2 ° C 9045D 11.2 su 1 TKN 351.2 15000 200 200 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 07/29/2020 1452 JAB2 07/29/2020 1025 61550 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.66 0.16 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 07/30/2020 1421 KSH2 07/29/2020 1428 61551 2 3050B 601OD 3 07/30/2020 1910 KSH2 07/29/2020 1428 61551 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 16000 51 19 mg/kg 1 Arsenic 7440-38-2 6010D 1.9 1.9 0.64 mg/kg 1 Cadmium 7440-43-9 6010D 0.51 J 0.64 0.16 mg/kg 1 Calcium 7440-70-2 6010D 160000 1900 240 mg/kg 2 Chromium 7440-47-3 6010D 23 1.3 0.32 mg/kg 1 Copper 7440-50-8 6010D 160 3.9 1.7 mg/kg 2 Iron 7439-89-6 6010D 11000 13 5.8 mg/kg 1 Lead 7439-92-1 6010D 18 1.3 0.58 mg/kg 1 Magnesium 7439-95-4 6010D 4500 640 80 mg/kg 1 Manganese 7439-96-5 6010D 360 1.9 0.76 mg/kg 1 Molybdenum 7439-98-7 6010D 3.3 J 5.1 1.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VG27035-001 Description: Newton Matrix: Solid Date Sampled:07/27/2020 0845 % Solids: 12.5 07/28/2020 0012 Date Received:07/27/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 07/30/2020 1421 KSH2 07/29/2020 1428 61551 2 3050B 6010D 3 07/30/2020 1910 KSH2 07/29/2020 1428 61551 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 12 5.1 1.3 mg/kg 1 Potassium 7440-09-7 6010D 900 640 80 mg/kg 1 Selenium 7782-49-2 6010D 1.2 J 2.6 1.0 mg/kg 1 Sodium 7440-23-5 6010D 420 J 640 80 mg/kg 1 Zinc 7440-66-6 6010D 510 6.4 1.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC n, 13 i EJ et rr. a ao- -u m — E E a `� ai do G $~A -�. a 4 a C5 � F 1 y ❑ �111 e m W } {�'} 3 I Q V Q ¢m {fj 6i t i b IL 47 U 10 E F' d N I 0 _ 4.? cCi } I m ai N 0 97 E1=E] � 1 0 at CJ � r4 .7 Ll Ztf 4 C 001 m ` M LL � �] 10 I] a W r C fy 9`. {a �3 lu n d} EO N a 4 � tv +� le ri 2,61 a 15 a F u L 0= CC it Ejof Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC 81kcelY t'rri=.' I'Mimni NIIMlit. W 9gr41{{fi, Jj: . MUM IfftJ4 1 SainP]e Receipt C lei` Elf[ 711eR )ist (5 C) CEient: CColvr 1,1s: mArd krvldate: CIW 1 7'2712020 i.at ij: VGrr 035 Meant a raceipl- ❑ SE-SI O Bilt ❑ UF'S ❑ VrdEX Othcr; Yes No I . Wens rus_ody seals pre-scn. an the cr3oler, T�j 171 NFL 2, If Custody sk; 4[5 wcrC RJ eSent, wCre they i Yes 1t&--I and iuiJ okeu? - PH Strip NA ChIQr[ne Strip ID;Nit 4P:r14C1AJV TrstcGriZingl upon receipt i Uar[ved (r_k;UQ temperature on receip: %S lid 'in.�,cp p Ile; 20-302 I 2.5 ? 29� �C NA lNJA QC NL A /NA 0C NA INN °�' Vi.1m; 0'1'empcl'a1',Iro Blank ❑Against 13ottles JR Gun ID: 5 IR Gun 00rrcctlon Factor, U IN-- 011-13d at %Xxr'irnt= V1 We.[ Ice C1 fee Packs ❑ uEz lee ❑ Mac ❑ Yr.-, 3, It 12mpera[ure 4f any cooler =ceded ci ❑ Rio �ITIA f', was Project MuTr�ger Notified? E'M>nras Norlfiod by: phune Iwoviil l fa trr-I`amr (circle ones. In Yes 70 No ®NA 4. Is the ewnmcMal courier's packing slip d torched to 9tis form? 4'es ❑ NO 1j. Wcrc plopar custody promdums (rnlinqu shCCV1VLCiv'CX[) fcilp: wed? YtsIf I No 145. Were: S=121C IDS Ii ited I m the COC9 Yes :�I No 7. Were;arnple [Ds listudon a:l 33-np[a conuilner,0 Y es, ❑ NO S_ Wa5 041 lcetion date & tuna listed orn Lhrt . C? © yesl NO 9. Was ml[ettion date& tinnic lisped ou;njI s p1e contaiurel ® Yes i ❑ No 10. 0 id a] I coritai uer lialy.] infcinnatinn (ID, te, tiuw) a,g -ea with the c '— �❑ ATo Yes 1 :. Were teats to Ise rrFortucd listed or4 the COC:? m �❑ No 12- DkI ail y�Tmples urivc in tho proffer Con—COD-f iriers; fur each tut and!j r in good onndition i (unbroken, l ids -on, otc.)T — YL's I❑ N4 13, Was ll&quafr,samplevolunic akailbhle2 Ycs No 14. Were all sumplzs rmelv&xt vw'itlAn K Lhe ldtug time ar 48 hour, whichever rcmeS first? ess (63C[e c3n0 Sani tes'lrt fisted ibn e()U7 1610 pre4ent im" (V"or 6mn) M illamctl - Y": Nor No ❑NA 15. Were any Samples eQntuiner3 missing' 16- for VOA and RSK-i 75 samples, were bi. 's'es in any cif the VDA viola'? ❑ Yes Na WJ NA 17, WrFO all DRQ?Inela'Vnatrient szmpll eivcd Etta Pj J of4P.? > 12 a11d ,;rr]titftl sFTrr4e-1 i 00 p]-i > 9;' Er —yes ❑ 740 V-fNA 19. iNerr. all SW idc samples r$oclvcci ai ❑ Yes El ND 10 NA tiff app gable , .r ] KN(�rnnjd p olfG2 {� O.S,n 7.) E�rple� e v refirduT41 toile' nee No U NA 20. Weir clkml rmarks+requests (Le- macs ❑ yes 3 dixtiT7rls, 1ASlMrD di;s1 ta6urti, atc-..) j comcLly trnnscr[bed from the OOC into the Inrnort Scction in LIMS? ❑ Yes Nor 121. Was the quorr slumber lisped (m the coma (Must 1U� enrnpleded for any mrnple(s) Irlrrrec ncr Iabe0 I' ote # CIA v presurved nrwith head-5puw.) Vcorreotiy Sample pr�eservnflon Saitip[e(s) litsaJnple { ri wee JL�Ccivpd i with NA rr.L ufpjrelo gee: Ji2SO4, fNO3„ HC1, pres3ezi H,Td wexe ac3uSted �cc4rdinf Turirn�g NaDli tlking SR f Time of 1 x c n-mion NA = If mare tEtan gti4 p. csc^wati ve is ue A _NA r [, phase nptC in the coffir.lunits bel;,w, Samples) _ r,c rccLived wil'T btlbbles'-6 nirr. in dltl-irleup- w id I TRC i v7,5 nip IL (Tf A 19 as 11) and were amples(sj NA _ worn received justed .L'i ordilloil}' i11 .sslmple re: Vjving widl 30613m th'osulfotc (� Ia�.S, ) with Shelly ID!! NA I SR 1:w-pcodJ 1l6e1S applied l'ry: CMS2 []:rtc= �J"27I 02U C`A)mnients:l ge 1 0l'1 U1241 i Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Newton VWVFP Lot Number:VJ03017 Date Completed:10/12/2020 NIM�� Mr� 10/13/2020 4:01 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: VJ03017 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" qualifier If you have any questions regarding this report please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Metals by ICP Due to low % solids, the initial amount used for sample -001 deviated from the standard procedure. The LOQ has been adjusted accordingly. Sample VJ03017-001 had a pH that excedes the constraints of the pH daily calibration. When a pH buffer of 12 SU was run along side the batch, the buffer failed to recover within acceptance criteria. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:VJ03017-001 Description: NEWTON WWTP Matrix: Solid Date Sampled:10/01/2020 0830 % Solids: 7.55 10/05/2020 2313 Date Received:10/02/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 (% Solids) SM 2540G 1 10/05/2020 2313 MOM 68892 1 350.1 (Ammonia - N ) 350.1 10 10/09/2020 1546 DRD 69087 1 (Nitrate - N ) 9056A 1 10/10/2020 0253 AMR 69482 1 (Nitrite - N ) 9056A 1 10/10/2020 0253 AMR 69483 1 (Phosphorus) 365.1 10 10/08/2020 1627 DMA 10/07/2020 1133 69153 1 (Soil pH meas) 9045D 1 10/06/2020 2239 SRB 69036 1 351.4 (TKN) 351.2 1 10/07/2020 1016 DMA 10/06/2020 1406 68936 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 7.55 % 2 Ammonia - N (gas diffusion) 350.1 3000 130 69 mg/kg 1 Nitrate - N (soluble) 9056A 18 6.6 1.3 mg/kg 1 Nitrite - N (soluble) 9056A 3.3 2.6 1.3 mg/kg 1 Phosphorus 7723-14-0 365.1 4600 660 130 mg/kg 1 Soil pH measured in water @ 20 ° C 9045D 10.9 su 1 TKN 351.2 12000 330 330 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 10/05/2020 1348 JAB2 10/05/2020 0938 68766 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 0.94 0.23 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 10/08/2020 1409 KSH2 10/07/2020 0847 68742 2 3050B 601OD 5 10/08/2020 1637 KSH2 10/07/2020 0847 68742 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 36000 88 33 mg/kg 1 Arsenic 7440-38-2 6010D 3.7 3.3 1.1 mg/kg 1 Cadmium 7440-43-9 6010D 0.42 J 1.1 0.28 mg/kg 1 Calcium 7440-70-2 6010D 250000 5500 690 mg/kg 2 Chromium 7440-47-3 6010D 42 2.2 0.55 mg/kg 1 Copper 7440-50-8 6010D 200 11 5.0 mg/kg 2 Iron 7439-89-6 6010D 24000 22 10 mg/kg 1 Lead 7439-92-1 6010D 18 2.2 0.99 mg/kg 1 Magnesium 7439-95-4 6010D 7900 1100 140 mg/kg 1 Manganese 7439-96-5 6010D 780 3.3 1.3 mg/kg 1 Molybdenum 7439-98-7 6010D 4.6 J 8.8 2.2 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:VJ03017-001 Description: NEWTON WWTP Matrix: Solid Date Sampled:10/01/2020 0830 % Solids: 7.55 10/05/2020 2313 Date Received:10/02/2020 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 10/08/2020 1409 KSH2 10/07/2020 0847 68742 2 3050B 6010D 5 10/08/2020 1637 KSH2 10/07/2020 0847 68742 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 20 8.8 2.3 mg/kg 1 Potassium 7440-09-7 6010D 1700 1100 140 mg/kg 1 Selenium 7782-49-2 6010D 3.0 J 4.4 1.8 mg/kg 1 Sodium 7440-23-5 6010D 800 J 1100 140 mg/kg 1 Zinc 7440-66-6 6010D 710 11 2.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC E 6D 4q ri 8. (WA ml PL U J2 LLJ 5 . F --. F i ii-T I Vplr-Vw-uald two-k NM2 �3' F,i fij L- L UZ'UN t6')g oats 4 71 M 'm 'evi qd 'no - 0,, Dj. HCMP Oil No A IH[11=0211p dral ff-dAVE <; LLF 1dWYD-U aWAOrU 3d)1iL1dW1; L4i tax N ' Ow CA Ob P-� I Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803)791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC samples Receipt Checklist (SR) (I IEDOIK-15) Bvlsed: Jzo o /)WZ r.4*V171 Issuing AuthDrltp; Pace ENV -WCOL I Page I of I amplo Rpeeipt C.lheekilst ( tx1-') ic»t: SYNAM Cooler Inspc�ted b lclr : : C , rt�ra.'2020 LLA 4i: VJWU17 Mec-nnofrecedpt Pace Client Lj UPS FA FcdEx 0 O(bc: YYes ,e' Nol I I _ WrL're Lusiudy 'r-.r_N TNrsmil orr like cooler" Yes i [}:o I LJNA12. If custody s=als tme present, wrm they intad,t Hnd ur broken? pH Strip [D; NA C1111uri M, 5013 JD; NA Tesred by, "A1 rigiaal temperacu'e uponreceipt,' Derived(Cmtutod)tvmp.7alury upon �sxia; 1M.UliJ;r up1T�_ 2t�a5E t1.9 fU-9 °r NA INA cr NA INA c�C NA 1VA aC Mvffiod; ❑Tcmpomiurc Bkmk dK inst BoW3 Ili Gun ID: 1P, Gun Qormct[on actor, °C Vlr.rhrld6Frmol:ml- 1771wet. Tee ffJc.,-packt ❑T]r ice ❑ Nnne 171 Yes ❑ -N D Q NA 3_ If tenperature, of any mo ler exce>aded 6-WC, was Pmject Manager 11Motified? PIVI was Notjfbed')y: prone 1 entail J face-to-faca (cinch~ one), Yes I F_. Nu d NA 4-, Is the commercial courier's pact Ong slip artac had to thi5 form? � F71 Yes I LjND S. Were prupercuskidy pruutxiure.�i ('nl:ryuislwWrtx; ived) Fall owofp. d Yes I Li No 1'�= sample Ms :ismd on the COC? � Yes N6 +6. + . Wc..rr.`!mm]-.1c 1 N '10M cn Hal-Wdnplu f_'imN inprs? Yes ND S. Was culloction dote & tare IisWd on the CM d Yes N u 4, Was caliocrion date & rinta listed on all sample corta{ncrs? f:/7 Yes ❑ Nn 10. Did ell container label i6un ration (ID, dal.c, tirr•_c) agck with thti OOC7 ,r Yes U.-gL' 11. Were testa :o be performed listed on the COC2 ❑ Yea ❑ N a 12_ Did all Su,li pie, :u, :ve ju the pruprr Lxastaiuers for Pool i test aji&or Irr guLA co__r:i4ioo (unhvAen. UN im, etc.)? L9rJ Yn NO I _ 11 n adequam sample volume available? wlyeti ENO 114. Were all samples received v Allin -, the :kolding time or 4H hrrurs, wlt'_cliever comeq tirg_7 Yes kJ No 11 kVerc any samples coutaincrs missing+excess (ciicse ale) samples dot :isti on COC? Yes ❑❑TJn ❑1Y.4 16-''nr\10A Mid RSK-J7� 5aMplts> Wert birhbie8 PFt:WQ( >'POK-.si7e';('/"or pmm is EWTICte_�) in -any of ChoV0A vials? FI Yes Ej N u J NA 17. Were all DROrineralshiutrieut samples received at a pH of < 2� Yc Nu l NA IS_ Were all cyanide sc-niples revaived at a O_hl > l2 aitd sulFidt: �Wrtlales re P;ved of a fH '. 4" ❑ Y n No �NA 19. Were all applicably N11�eTK eyaiiiWph-cno1f�25.116U.3 (C G_3m_WLj samples ffse oi- - resi�ival chl«rine" ❑ Yes ❑ N o R]NA 20. Were client rtmarks'rec{uests (i.e. regvcmd dilutions. MSiMS D dc�i2ri tiors, etc., . ) correct=y trimaribod From tho COC bno the cominertt smWi in LIMS'" Yes No !I. was Lire quote mnnber IL ed Dn the conmi;rer IaW7 1= 'es, Q;:ote 5$m filp Prt9C� 4'�t[oi1 (Most be completed for any Sanaple(s) incd rmctly preset ved or WTI 'ieacsrace_) :Sanlplcfs} r'� _—__vrer�rrPoei�recl Irurarla;Cdly ilr�fyervednr.r_ wrrr. �iiljusted pia:rr,:;ri_ly -in wrruple recaiving m ith NA mL of cirde ane: T J2_90 4, 111403. T ICI, -NaOl I nsina SR A 11; A Mime of preservation NA If mare tian vice prcgervative is nee -der., p-e a npie In lh� r.(A'a nanm. brlow, :�Qmple(5) NA __._.... wvn recPiird with bubbi s>h mn in diameter. were received w1th TRC > 9.5 rng(L ([ 4uEtcd accord'.p4y in tttiusa1W (N 2 iv1Lh Shoal}' Ili; NA 019 is Pic) and wen. �R baroade labels applied by; AHD Date; 11i31 Q C C0!nmenCS: Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 FACILITY NAME: NEWTON, NC LAND OWNER: BRUCE HUNSUCKER OPERATOR: GORDY GOINS CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00018-0-0001- ANNUAL DRY TONS APPLIED: 179.97 SITE M NC CA 00018 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 151 CROP 2 NAME: Page: 1 ACRES UTILIZED: 30.4 ACRES PERMITTED: 30.4 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 4/7/2020 156,000.00 (G) 9.400 2.011 NCCLSL DRY 1'0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 11.031 FSP 4/8/2020 48,000.00 (G) 9.400 0.619 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 3.394 FSP 4/10/2020 72,000.00 (G) 9.400 0.928 NCCLSL DRY 1'0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 5.091 FSP Apr-20 276,000.00 (G) 10/15/2020 102,000.00 (G) 7.550 1.056 NCCLSL MOIST 1'0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 8.918 FSP 10/16/2020 114,000.00 (G) 7.550 1.181 NCCLSL DRY 1'0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 9.968 FSP 10/17/2020 12,000.00 (G) 7.550 0.124 NCCLSL DRY 110-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 1.049 FSP Oct-20 228,000.00 (G) Total 5.919 Total 39.451 0.000 AS Annual Ibs/acre Applied 0.034 CD CU CR PB HG MO NI SE ZN P Lime Applied 0.007 2.510 0.426 0.213 0.003 0.061 0.208 0.025 8.976 80.087 Date Lbs/Ac Cumulative Ibs/acre Applied 0.257 0.138 15.333 3.334 1.358 0.041 0.425 1.671 0.259 58.117 ***** ***** Permit PAN Limit (Ibs/acre) 1st Crop 151 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 1 375.0 1 89.0 1 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware at there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation * ** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***"* See Site pH & Lime Application Records Section of Report Printed: 2/4/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: BRUCE HUNSUCKER OPERATOR: GORDY GOINS CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00018-0-0003- ANNUAL DRY TONS APPLIED: 83.86 SITE #: NC CA 00018 PREDOMINANT SOIL SERIES: CECIL CROP 1 MAX. PAN: 162 CROP 2 NAME: Page: 1 ACRES UTILIZED: 7.1 ACRES PERMITTED: 7.1 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount7 UOM Crop 1 Crop 2 Crop 1 Crop 2 4/8/2020 12,000.00 (G) 9.400 0.663 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 3,633 FSP 4/10/2020 120,000.00 (G) 9.400 6.625 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 36.332 FSP Apr-20 132,000.00 (G) 10/17/2020 102,000.00 (G) 7.550 4.523 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 38.186 FSP Oct-20 102,000.00 (G) Total 11.811 Total 78.161 0.000 Annual Ibs/acre Applied AS CD CU CR PB HG MO NI SE ZN P Lime Applied 0.067 0.014 5.016 0.846 0.425 0.005 0.122 0.414 0.049 17.937 161.127 ±_ Date Lbs/Ac Cumulative Ibs/acre Applied 0.287 0.141 16.452 3.095 1.243 0.033 0.427 1.684 0.250 65.673 1 1***** ***** Permit PAN Limit (Ibs/acre) 1st Crop I I I I I I 162 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 375.0 1 89.0 1 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am awa that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/4/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: BRUCE HUNSUCKER OPERATOR: GORDY GOINS CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT#: WQ0003902 FIELD#: NC-CA-00018-0-0004- ANNUAL DRY TONS APPLIED: 80.11 SITE #: NC CA 00018 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 162 CROP 2 NAME: Page: 1 ACRES UTILIZED: 15.0 ACRES PERMITTED: 15.0 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 4/7/2020 6,000.00 (G) 9.400 0.157 NCCLSL DRY 0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 0.860 FSP 4/8/2020 102,000.00 (G) 9.400 2.665 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 14.617 FSP Apr-20 108,000.00 (G) 10/16/2020 84,000.00 (G) 7.550 1.763 NCCLSL DRY 0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 14.885 FSP 10/17/2020 36,000.00 (G) 7.550 0.756 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 6.379 FSP Oct-20 120,000.00 (G) Total 5.341 Total 36.741 0.000 AS Annual Ibs/acre Applied 0.032 CD CU CR PB HG MO NI SE ZN P Lime Applied 0.006 2.249 0.392 0.192 0.002 0.054 0.191 0.024 8.036 69.457 Date Lbs/Ac Cumulative Ibs/acre Applied 0.211 0.087 12.494 2.469 0.925 0.027 0.338 1.323 0.198 49.496 ***** ***** 'ermit PAN Limit (Ibs/acre) 1st Crop I I I I I I I I I I 162 =ederal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 1 267.9 1 15.0 1 375.0 1 89.0 1 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aw e at there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 2/4/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: HAROLD SHERRILL OPERATOR: WALLY SAINE CROP 1 NAME: FESCUE (FS) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00020-0-0003- ANNUAL DRY TONS APPLIED: 178.00 SITE #: NC CA 00020 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 151 CROP 2 NAME: Page: 1 ACRES UTILIZED: 41.7 ACRES PERMITTED: 41.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 1/27/2020 60,000.00 (G) 7.650 0.459 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 21,700.00 5,380.00 116.00 7.092 FS 1/29/2020 174,000.00 (G) 7.650 1.331 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 21,700.00 5,380.00 116.00 20.568 FS 1/30/2020 180,000.00 (G) 7.650 1.377 NCCLSL DRY 110-<1/2" SUR 0.5 0.30 21,700.00 5,380.00 116.00 21.277 FS 1/31/2020 102,000.00 (G) 7.650 0.780 NCCLSL DRY 110-<1/2" SUR 0.5 0.30 21,700.00 5,380.00 116.00 12.057 FS Jan-20 516,000.00 (G) 2/4/2020 42,000.00 (G) 7.650 0.321 NCCLSL MOIST "0-<1/2" SUR 0.5 0.30 21,700.00 5,380.00 116.00 4.965 FS Feb-20 42,000.00 (G) Total 4.268 Total 66.959 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.055 0.011 1.631 0.244 0.135 0.002 0.040 0.168 0.055 6.155 87.081 Date Lbs/Ac Cumulative Ibs/acre Applied 0.201 I 0.095 I 11.031 1.876 0.746 I 0.022 I 0.268 I 1.221 I 0.268 I 47.713 Permit PAN Limit (Ibs/acre) 1st Crop; I I 151 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1,339.0 267.9 15.0 375.0 89.0 21500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty 1 w, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there arc sign t pcualf mitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LANDOWNER: HAROLD SHERRILL OPERATOR: TIM WOODRIFF CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M WQ0003902 FIELD#: NC-CA-00020-0-0008- ANNUAL DRY TONS APPLIED: 77.61 SITE #: NC CA 00020 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 22.0 ACRES PERMITTED: 22.0 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate— mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 6/23/2020 198,000.00 (G) 9.400 3.528 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 19.347 FSP Jun-20 198,000.00 (G) Total 3.528 Total 19.347 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.016 0.005 1.552 0.226 0.127 0.001 0.039 0.113 0.011 5.574 57.856 Date Lbs/Ac Cumulative lbs/acre AoDlied 0.130 0.060 8.617 1.463 0.581 0.015 0.245 0.705 0.142 31.849 Permit PAN Limit (Ibs/acre) 1st Crop; 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 I 34.8 I 1,339.0 ' 267.9 9 15.0 I 375.0 1 89.0 1 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penal law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are s' 'cant pe submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LANDOWNER: THOMAS WARLICK OPERATOR: TIM WOODRIFF CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00021-0-0001- ANNUAL DRY TONS APPLIED: 64.23 SITE #: NC CA 00021 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 27.5 ACRES PERMITTED: 27.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site I Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 12/29/2020 30,000.00 (G) 7.550 0.343 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 2.900 FSH 12/30/2020 174,000.00 (G) 7.550 1.992 NCCLSL MOIST "0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 16.818 FSH Dec-20 204,000.00 (G) Total 2.335 Total 19.718 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.017 0.002 0.934 0.196 0.084 0.001 0.021 0.093 0.014 3.316 21.487 Date Lbs/Ac Cumulative Ibs/acre Applied 0.099 I 0.040 I 6.293 I 1.502 0.427 I 0.015 I 0.160 I 0.577 I 0.099 I 23.157 Permit PAN Limit (Ibs/acre) 1st Crop 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 ! 267.9 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penal o ]aw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the infonmation submitted. I am aware that there are si i cant p ubmitting false information, including the possibility of fines and imprisonment for knowing violations." 2_157Z/ SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 **** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: GARY DELLINGER OPERATOR: GARY DELLINGER CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00025-0-0001- ANNUAL DRY TONS APPLIED: 272.09 SITE #: NC CA 00025 PREDOMINANT SOIL SERIES: FAIRVIEW CROP 1 MAX. PAN: 183 CROP 2 NAME: Page: 1 ACRES UTILIZED: 40.8 ACRES PERMITTED: 40.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Date or Month Gallons (G) or Cubic Yards (Y) or Wet Tons (W) % Solids Dry Tons/Ac Residual Source Site Cond. Dry, Wet, Moist Precip Past 24 Hrs. Inches Application Method* Volati- lization Rate** Mineral- ization Rate*** TKN mg/kg Ammonia Nitrogen mg/kg Nitrate and Nitrite mg/kg PAN Applied (Ibs/acre) Name of Crop Type Receiving Residual Application Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 8/13/2020 120,000.00 (G) 12.500 1.533 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 15,000.00 2,400.00 13.50 15.311 FSH 8/19/2020 156,000.00 (G) 12.500 1.993 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 15,000.00 2,400.00 13.50 19.904 FSH 8/20/2020 132,000.00 (G) 12.500 1.686 NCCLSL MOIST "0-<1/2" SUR 0.5 0.30 15,000.00 2,400.00 13.50 16.842 FSH 8/21/2020 30,000.00 (G) 12.500 0.383 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 15,000.00 2,400.00 13.50 3.828 FSH 8/27/2020 84,000.00 (G) 12.500 1.073 NCCLSL DRY 110-<1/2" SUR 0.5 0.30 15,000.00 2,400.00 13.50 10.718 FSH Aug-20 522,000.00 (G) Total 6.668 Total 66.603 0.000 AS CD CU CR PB FIG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.025 0.007 1 2.134 0.307 0.240 0.002 0.044 0.160 0.016 6.802 100.034 Date I Lbs/Ac Cumulativelbs/acre Applied 0.025 ( 0.007 I 2.134 I 0.307 I 0.240 f 0.002 I 0.044 0.160 I 0.016 6.802 Permit PAN Limit (Ibs/acre) 1st Crop I I 183 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penal flaw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are si cant p ies in false information, including the possibility of fines and im onment for knowing violations." S NATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *`** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: JASON LITTLE OPERATOR: JASON LITTLE CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M WQ0003902 FIELD* NC-CA-00027-0-0001- ANNUAL DRY TONS APPLIED: 16.46 SITE* NC CA 00027 PREDOMINANT SOIL SERIES: FAIRVIEW CROP 1 MAX. PAN: 216 CROP 2 NAME: Page: 1 ACRES UTILIZED: 7.5 ACRES PERMITTED: 7.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids DryTons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount 3 UOM Crop 1 Crop 2 Crop 1 Crop 2 6/15/2020 42,000.00 (G) 9.400 2.195 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 12.038 FSH Jun-20 42,000.00 (G) Total 2.195 Total 12.038 0.000 AS CD CU CR PB HG MO NI SE ZN ! P Lime Applied Annual Ibs/acre Applied 0.010 0.003 0.966 0.140 0.079 <0.001 0.024 0.070 0.007 3.468 E 35.999 Date Lbs/Ac Cumulative Ibs/acre Applied 0.010 I 0.003 0.966 0.140 I 0.079 I <0.001 0.024 I 0.070 I 0.007 I 3.468 I j Permit PAN Limit (Ibs/acre) 1st Crop I i 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 's 267.9 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty oIa , that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signi t penatt g false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 *"*** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: JASON LITTLE OPERATOR: JASON LITTLE CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00027-0-0002- ANNUAL DRY TONS APPLIED: 61.15 SITE M NC CA 00027 PREDOMINANT SOIL SERIES: FAIRVIEW CROP 1 MAX. PAN: 194 CROP 2 NAME: Page: 1 ACRES UTILIZED: 22.8 ACRES PERMITTED: 22.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 6/12/2020 114,000.00 (G) 9.400 1.960 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 10.748 FSH 6/15/2020 42,000.00 (G) 9.400 0.722 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 3.960 FSH Jun-20 1 156,000.00 (G) Total 2.682 Total 14.708 0.000 AS CD a CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.012 0.004 1.180 0.172 0.097 0.001 0.030 0.086 0.008 4.238 ! 43.984 Date Lbs/Ac Cumulativelbs/acre Applied 0.012 0.004 1.180 0.172 ; 0.097 I 0.001 0.030 0.086 0.008 4.238 i Permit PAN Limit (Ibs/acre) 1st Cropl 194 Federal C.P.L.R. (Ibs/acre)*"*` 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 I NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalW o law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are pena ' tting false information, including the possibility of fines and imprisonment for knowing violations." tilant 2-s=,� SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required ** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LANDOWNER: RONNIE SIGMON OPERATOR: RONNIE SIGMON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00032-0-0001- ANNUAL DRY TONS APPLIED: 52.89 SITE #: NC CA 00032 PREDOMINANT SOIL SERIES: APPLING CROP 1 MAX. PAN: 237 CROP 2 NAME: Page: 1 ACRES UTILIZED: 12.2 ACRES PERMITTED: 12.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate— mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 = Crop 2 10/19/2020 168,000.00 (G) 7.550 4.335 NCCLSL DRY 110-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 36.602 FSH Oct-20 168,000.00 (G) Total 4.335 Total 36.602 U.00u AS CD CU CR PB HG MO NI SE ZN P I Lime Applied Annual Ibs/acre Applied 0.032 0.004 1.734 0.364 0.156 0.002 0.040 0.173 0.026 6.156 39.886 Date Lbs/Ac Cumulative lbs/acre Aoolied 0.107 0.050 7.037 1.359 0.528 0.007 0.144 j 0.705 0.182 25.030 Permit PAN Limit (Ibs/acre) 1st Crop 237 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under pe IV of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there ar si 'ficant p ubmitting false information, including the possibility of fines and imprisonment for knowing violations." i 00r, SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (1212006) FACILITY NAME: NEWTON, NC LAND OWNER: RANDY LEATHERMAN OPERATOR: SHARON RHONEY CROP 1 NAME: WHEAT (WH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0003902 FIELD#: NC-CA-00047-0-0006- ANNUAL DRY TONS APPLIED: 49.11 SITE #: NC CA 00047 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 98 CROP 2 NAME: Page: 1 ACRES UTILIZED: 9.6 ACRES PERMITTED: 9.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids DryTons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 12/11/2020 48,000.00 (G) 7.550 1.574 NCCLSL MOIST "0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 13.290 WH 12/12/2020 108,000.00 (G) 7.550 3.542 NCCLSL DRY "0-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 29.903 WH Dec-20 166,000.00 (G) Total 5.116 Total 43.193 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.038 0.004 2.046 0.430 0.184 0.002 0.047 0.205 0.031 7.265 47.068 Date Lbs/Ac Cumulative Ibs/acre Applied 0.038 I 0.004 I 2.046 I 0.430 I 0.184 I 0.002 I 0.047 I 0.205 I 0.031 I 7.265 I I I I Permit PAN Limit (Ibs/acre) 1st Crop, 98 I Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty 1 w, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are sign' c t penalties fo=btt' false information, including the possibility of fines and imprisonment for knowing violations." J 'C;, SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: RANDY LEATHERMAN OPERATOR: SHARON RHONEY CROP 1 NAME: WHEAT (WH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M WQ0003902 FIELD#: NC-CA-00047-0-0007- ANNUAL DRY TONS APPLIED: 34.00 SITE M NC CA 00047 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 98 CROP 2 NAME: Page: 1 ACRES UTILIZED: 6.6 ACRES PERMITTED: 6.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application III lization ization TKN Nitrogen and Nitrite (lbs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate— mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 12/11/2020 108,000.00 (G) 7.550 5.152 NCCLSL MOIST 110-<1/2" SUR 0.5 0.30 12,000.00 3,000.00 21.30 43.495 WH Dec-20 1 108,000.00 (G) Total 5.152 Total 43.495 0.uuu NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty of w that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signifi penaltie false information, including the possibility of fines and imprisonment for knowing violations." 2 �-� / SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation '** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) FACILITY NAME: NEWTON, NC LAND OWNER: GORDY GOINS OPERATOR: GORDY GOINS CROP 1 NAME: SUDAN HAY (SNH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00003902 FIELD#: NC-LT-00119-0-0005- ANNUAL DRY TONS APPLIED: 63.50 SITE* NC LT 00119 PREDOMINANT SOIL SERIES: LLOYD CROP 1 MAX. PAN: 276 CROP 2 NAME: Page: 1 ACRES UTILIZED: 10.3 ACRES PERMITTED: 13.9 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 6/22/2020 162,000.00 (G) 9.400 6.165 NCCLSL MOIST 0-<1/2" SUR 0.5 0.30 6,800.00 3,300.00 42.00 33.810 SNH Jun-20 162,000.00 (G) Total 6.165 Total 33.810 0.000 AS CD CU CR PB HG MO NI SE ZN I P Lime Applied Annual Ibs/acre Applied 0.028 0.009 2.713 0.395 0.222 0.002 0.068 0.197 0.019 9.741 101.108 Date Lbs/Ac Cumulative Ibs/acre Applied 0.028 0.009 2.713 0.395 0.222 0.002 0.068 I 0.197 0.019 9.741 Permit PAN Limit (Ibs/acre) 1st Crop; 276 Federal C.P.L.R. (Ibs/acre)**"* 36.6 34.8 1,339.0 ; 267.9 15.0 375.0 89.0 2,500.0 NCCLSL = NEWTON, NC CLARK CREEK LIME STABILIZED LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p�n 'es for submitting false information, including the possibility of fines and imprisonments for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, ]NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/30/2021 DENR FORM FSF (12/2006) SECTION 4 SUMM111 Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOL0C4r;S,INC Cuyahoga Falls, Ohio44223 Arraly0ca1 Laboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com April 21, 2020 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Newton WWTP Dear Alex Fox: Order No.: 20040157 Summit Environmental Technologies, Inc. received 1 sample(s) on 4/2/2020 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada OH009232020-1, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 2019-155, Oregon OH2O0001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah OH009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 28 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 20040157 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 4/21/2020 CLIENT: Synagro Project: Newton WWTP WorkOrder Narrative: 20040157: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence QC Notes: PEST 250PPB ccv SVOC-CPEST_NPW(8081): CCV exhibits high recovery for batch specific analyte Endrin. Reported samples are ND Original Page 2 of 28 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 20040157 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: htm:11www.settek.co Date: 4/21/2020 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 28 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL reCHNO ijULES. INC. Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Newton WWTP Lab SamplelD Client Sample ID 20040157-001 Newton WWTP Tag No Date Collected 4/1/2020 9:00:00 AM Workorder Sample Summary WO#: 20040157 21 Apr-20 Date Received Matrix 4/2/2020 10:20:00 AM Sludge Page 4 of 28 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES REPORT ENVIRONMENTALTECHN❑L0G1ES,11+1C Cuyahoga Falls, Ohio44223 WO#: 20040157 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 20040157-OOIA Newton WWTP 4/1/2020 9:00:00 AM Sludge Flashpoint Determination (1010) 4/10/2020 5:04:05 PM pH (SW9045D) 4/6/2020 3:01:16 PM Reactive Cyanide (9014/7.3.3.2)-Solid 4/6/2020 9:00:00 AM Reactive Sulfide (9034)/7.3.4.2 4/6/2020 9:00:00 AM TCLP Herbicides by EPA 8321B 4/8/2020 3:00:00 PM 4/16/2020 7:49:00 AM TCLP Mercury Analysis (SW1311/7474/8/2020 3:00:00 PM 4/10/2020 9:30:00 AM 4/10/2020 1:55:00 PM TCLP Metals Analysis (SW1311/6010:4/8/2020 3:00:00 PM 4/9/2020 1:00:00 PM 4/10/2020 10:59:01 AM TCLP Pesticides Analysis (SW1311/8(4/8/2020 3:00:00 PM 4/10/2020 12:30:00 PM 4/13/2020 9:50:00 PM TCLP Semi-Volatiles Analysis 4/8/2020 3:00:00 PM 4/9/2020 12:00:00 PM 4/14/2020 5:07:00 PM (SW1311/8270) TCLP Semi-Volatiles Analysis 4/8/2020 3:00:00 PM 4/9/2020 12:00:00 PM 4/13/2020 6:35:00 PM (SW1311/8270) TCLP Volatiles Analysis 4/9/2020 4:00:00 PM 4/10/2020 5:37:00 PM Original Page 5 of 28 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20040157 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 9:00:00 AM Lab ID: 20040157-OOIA Project: Newton WWTP Client Sample ID Newton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND TCLP Barium(Ba) ND TCLP Cadmium(Cd) ND TCLP Chromium(Cr) ND TCLP Lead(Pb) ND TCLP Selenium(Se) ND TCLP Silver(Ag) ND RCI FLASHPOINT DETERMINATION (1010) Flashpoint (140°F) >140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 2,4,5-Trichlorophenol ND 2,4,6-Trichlorophenol ND 2,4-Dinitrotoluene ND Cresols, Total ND Hexachloro-1,3-butadiene ND Hexachlorobenzene ND Hexachloroethane ND Nitrobenzene ND Pentachlorophenol ND Pyridine ND Surr: 2-Fluorophenol 73.4 Surr: Phenol-d6 75.8 Surr: Nitrobenzene-d5 62.0 SW7470A SW7470A Analyst: MJM 0.00200 mg/L 1 4/10/2020 1:55:00 PM SW6010D SW301OA Analyst: EAM 0.500 mg/L 1 4/10/2020 10:59:01 AM 5.00 mg/L 1 4/10/2020 10:59:01 AM 0.100 mg/L 1 4/10/2020 10:59:01 AM 0.200 mg/L 1 4/10/2020 10:59:01 AM 0.500 mg/L 1 4/10/2020 10:59:01 AM 0.0500 mg/L 1 4/10/2020 10:59:01 AM 0.500 mg/L 1 4/10/2020 10:59:01 AM SW1010 Analyst: TAH °F 1 4/10/2020 5:04:05 PM SW8270 SW351OC Analyst: SFG 0.200 mg/L 2 4/13/2020 6:35:00 PM 0.500 mg/L 2 4/13/2020 6:35:00 PM 0.500 mg/L 2 4/13/2020 6:35:00 PM 0.100 mg/L 2 4/14/2020 5:07:00 PM 10.0 mg/L 2 4/13/2020 6:35:00 PM 0.0400 mg/L 2 4/13/2020 6:35:00 PM 0.100 mg/L 2 4/14/2020 5:07:00 PM 0.200 mg/L 2 4/13/2020 6:35:00 PM 0.200 mg/L 2 4/13/2020 6:35:00 PM 0.500 mg/L 2 4/14/2020 5:07:00 PM 0.500 mg/L 2 4/13/2020 6:35:00 PM 10 - 109 %Rec 2 4/13/2020 6:35:00 PM 10 - 109 %Rec 2 4/13/2020 6:35:00 PM 19 - 120 %Rec 2 4/14/2020 5:07:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 6 of 28 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20040157 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 9:00:00 AM Lab ID: 20040157-OOIA Project: Newton WWTP Client Sample ID Newton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: SFG TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: 2,4,6-Tribromophenol 108 10 - 120 %Rec 2 4/13/2020 6:35:00 PM Surr: 2-Fluorobiphenyl 72.3 22 - 117 %Rec 2 4/14/2020 5:07:00 PM Surr: p-Terphenyl-d14 99.8 34 - 116 %Rec 2 4/13/2020 6:35:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 Analyst: MES TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.0125 mg/L 5 4/13/2020 9:50:00 PM Toxaphene ND 0.0250 mg/L 5 4/13/2020 9:50:00 PM Endrin ND 0.00250 QC+ mg/L 5 4/13/2020 9:50:00 PM gamma-BHC ND 0.00250 mg/L 5 4/13/2020 9:50:00 PM Heptachlor ND 0.00250 mg/L 5 4/13/2020 9:50:00 PM Heptachlor epoxide ND 0.00250 mg/L 5 4/13/2020 9:50:00 PM Methoxychlor ND 0.00250 mg/L 5 4/13/2020 9:50:00 PM Surr: TCMX 62.7 10 - 119 %Rec 5 4/13/2020 9:50:00 PM Surr: DCB 81.1 10 - 119 %Rec 5 4/13/2020 9:50:00 PM TCLP HERBICIDES BY EPA 8321B 2,4-D ND 2,4,5-TP ND Surr: 2,4-Dichlorophenylacetic aci 120 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1, 2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8321A SW1311M Analyst: BJH 0.500 mg/L 50 4/16/2020 7:49:00 AM 0.500 mg/L 50 4/16/2020 7:49:00 AM 70 - 130 %Rec 50 4/16/2020 7:49:00 AM SW8260 SW1311M Analyst: RMT 0.500 mg/L 100 4/10/2020 5:37:00 PM 0.500 mg/L 100 4/10/2020 5:37:00 PM 10.0 mg/L 100 4/10/2020 5:37:00 PM 0.500 mg/L 100 4/10/2020 5:37:00 PM 0.500 mg/L 100 4/10/2020 5:37:00 PM 5.00 mg/L 100 4/10/2020 5:37:00 PM 0.500 mg/L 100 4/10/2020 5:37:00 PM 0.500 mg/L 100 4/10/2020 5:37:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 7 of 28 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.coin Analytical Report (base report) WO#: 20040157 Date Reported: 4/21/2020 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 4/l/2020 9:00:00 AM Lab ID: 20040157-OOIA Project: Newton WWTP Client Sample ID Newton WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: RMT TCLP VOLATILES ANALYSIS Trichloroethene ND 0.500 mg/L 100 4/10/2020 5:37:00 PM Vinyl chloride ND 0.200 mg/L 100 4/10/2020 5:37:00 PM Surr: 4-Bromofluorobenzene 94.8 70 - 130 %Rec 100 4/10/2020 5:37:00 PM Surr: Dibromofluoromethane 104 70 - 130 %Rec 100 4/10/2020 5:37:00 PM Surr: Toluene-d8 105 70 - 130 %Rec 100 4/10/2020 5:37:00 PM RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.495 mg/Kg 1 4/6/2020 9:00:00 AM RCI SW9045D Analyst: VVK PH (SW9045D) pH 11.6 s.u.@20.3C 1 4/6/2020 3:01:16 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 4/6/2020 9:00:00 AM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 8 of 28 Summit Environmental Technologies, Inc. Accreditation Program fr 3310 Win St. SUMMIEF Anal�7n tes Report ENOROMMEWAL IrECHNOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20040157 Wehsite: http://www.settek.com 21Apr-20 Client: Synagro State: NW Project: Newton WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20040157-OOIA Sludge Flashpoint Determination (1010) Flashpoint (1407) A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive N Sludge Reactive Sulfide (9034Y7.3.4.2 Sulfide, Reactive N Sludge TCLP Herbicides by EPA 8321B 2,4,5-TP A Sludge TCLP Herbicides by EPA 8321B 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM N Not Accredited Original #1 Page 9 of 28 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Anal�7n tes Report ENVIROMMEWAL IrECHHOL.OG{r,S, INC, Cuyahoga Falls, Ohio 44223 J Y ArralyVcal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 20040157 Wehsite: http://www.settek.com 21Apr-20 Client: Synagro State: NW Project: Newton WWTP Program Name: NC—WW—SCM Sample ID Matrix Test Name Analyte Status 20040157-OOIA Sludge TCLP Volatiles Analysis 1, 1 -Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM N Not Accredited Original #1 Page 10 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42926 WO#: 20040157 21 Apr-20 Sample ID: MB-42926 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 lient ID: PBS Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/9/2020 SegNo: 2724283 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.100 2,4,5-Trichlorophenol ND 0.250 2,4,6-Trichlorophenol ND 0.250 2,4-Dinitrotoluene ND 0.0500 o-Cresol ND 0.250 Cresols, Total ND 5.00 Hexachloro-1,3-butadiene ND 0.0200 Hexachlorobenzene ND 0.0500 Hexachloroethane ND 0.100 Nitrobenzene ND 0.100 Pentachlorophenol ND 0.250 Pyridine ND 0.250 Surr: 2-Fluorophenol 0.784 Surr: Phenol-d6 0.764 Surr: Nitrobenzene-d5 0.581 Surr: 2,4,6-Tribromophenol 1.13 Surr: 2-Fluorobiphenyl 0.696 Surr: p-Terphenyl-d14 1.17 1.000 78.4 10 109 1.000 76.4 10 109 1.000 58.1 19 120 1.000 113 10 120 1.000 69.6 22 117 1.000 117 34 116 S Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42926 WO#: 20040157 21 Apr-20 Sample ID: LCS-42926 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: LCSS Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/9/2020 SegNo: 2724284 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.460 0.100 0.8000 0 57.6 36.4 130 2,4,5-Trichlorophenol 0.886 0.250 0.8000 0 ill 31.7 132 2,4,6-Trichlorophenol 0.880 0.250 0.8000 0 110 31.1 133 2,4-Dinitrotoluene 0.858 0.0500 0.8000 0 107 43.3 130 o-Cresol 0.680 0.250 0.8000 0 85.0 32.9 130 Cresols, Total ND 5.00 1.600 0 85.0 31.7 130 Hexachloro-1,3-butadiene 0.466 0.0200 0.8000 0 58.3 31.4 130 Hexachlorobenzene 0.804 0.0500 0.8000 0 101 43.1 130 Hexachloroethane 0.438 0.100 0.8000 0 54.7 36.5 130 Nitrobenzene 0.565 0.100 0.8000 0 70.6 39.5 130 Pentachlorophenol 0.816 0.250 0.8000 0 102 34 130 Pyridine 0.324 0.250 0.8000 0 40.5 10 130 Surr: 2-Fluorophenol 0.816 1.000 81.6 17.1 130 Surr: Phenol-d6 0.839 1.000 83.9 10 130 Surr: Nitrobenzene-d5 0.629 1.000 62.9 32.6 130 Surr:2,4,6-Tribromophenol 1.22 1.000 122 4.43 130 Surr: 2-Fluorobiphenyl 0.791 1.000 79.1 41.8 130 Surr: p-Terphenyl-dl4 1.16 1.000 116 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42926 WO#: 20040157 21 Apr-20 Sample ID: 20031698-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: Batch= Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/10/2020 SegNo: 2724309 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.489 0.200 0.8000 0 61.1 33.8 126 2,4,5-Trichlorophenol 0.909 0.500 0.8000 0 114 28.7 144 2,4,6-Trichlorophenol 0.936 0.500 0.8000 0 117 12.8 153 2,4-Dinitrotoluene 0.927 0.100 0.8000 0 116 20.4 155 o-Cresol 0.704 0.500 0.8000 0 88.0 10 148 Cresols, Total ND 10.0 1.600 0 89.6 10 148 Hexachloro-1,3-butadiene 0.490 0.0400 0.8000 0.006000 60.6 29 126 Hexachlorobenzene 0.909 0.100 0.8000 0 114 33.7 134 Hexachloroethane 0.452 0.200 0.8000 0.006400 55.7 32.8 132 Nitrobenzene 0.602 0.200 0.8000 0 75.2 20 158 Pentachlorophenol 0.703 0.500 0.8000 0 87.9 10 176 Pyridine ND 0.500 0.8000 0 37.2 10 130 Surr:2-Fluorophenol 0.782 1.000 78.2 3.39 130 Surr: Phenol-d6 0.861 1.000 86.1 5 130 Surr: Nitrobenzene-d5 0.648 1.000 64.8 14.5 154 Surr: 2,4,6-Tribromophenol 1.23 1.000 123 19.5 130 Surr:2-Fluorobiphenyl 0.868 1.000 86.8 34.4 130 Surr: p-Terphenyl-d14 1.27 1.000 127 8.86 156 QMR Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 13 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42926 WO#: 20040157 21 Apr-20 Sample ID: 20031698-001AMSD SampType: MSD TestCode: SVOC-BNA_T Units: mg/L Prep Date: 4/9/2020 RunNo: 111624 Dient ID: Batch= Batch ID: 42926 TestNo: SW8270 SW3510C Analysis Date: 4/10/2020 SegNo: 2724317 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.549 0.200 0.8000 0 68.6 33.8 126 0.4888 11.6 30 2,4,5-Trichlorophenol 0.870 0.500 0.8000 0 109 28.7 144 0.9092 4.36 30 2,4,6-Trichlorophenol 0.944 0.500 0.8000 0 118 12.8 153 0.9364 0.851 30 2,4-Dinitrotoluene 0.922 0.100 0.8000 0 115 20.4 155 0.9272 0.519 30 o-Cresol 0.797 0.500 0.8000 0 99.6 10 148 0.7036 12.4 30 Cresols, Total ND 10.0 1.600 0 96.7 10 148 0 0 30 Hexachloro-1,3-butadiene 0.586 0.0400 0.8000 0.006000 72.6 29 126 0.4904 17.8 30 Hexachlorobenzene 0.902 0.100 0.8000 0 113 33.7 134 0.9092 0.751 30 Hexachloroethane 0.530 0.200 0.8000 0.006400 65.4 32.8 132 0.4520 15.8 30 Nitrobenzene 0.664 0.200 0.8000 0 83.0 20 158 0.6020 9.79 30 Pentachlorophenol 0.596 0.500 0.8000 0 74.6 10 176 0.7032 16.4 30 Pyridine ND 0.500 0.8000 0 13.8 10 130 0 0 30 Surr:2-Fluorophenol 0.892 1.000 89.2 3.39 130 0 Surr: Phenol-d6 0.927 1.000 92.7 10 130 0 Surr: Nitrobenzene-d5 0.735 1.000 73.5 14.5 154 0 Surr: 2,4,6-Tribromophenol 1.30 1.000 130 19.5 130 0 Surr:2-Fluorobiphenyl 0.900 1.000 90.0 34.4 130 0 Surr: p-Terphenyl-d14 1.25 1.000 125 8.86 156 0 Rm Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20040157 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: 42928 Sample ID: 20040321-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: Batch= Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724298 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.6508 99.2 70 130 TCLP Cadmium(Cd) 2.18 0.100 2.000 0.004215 109 70 130 TCLP Chromium(Cr) 2.00 0.200 2.000 0.006405 99.8 70 130 TCLP Lead(Pb) 1.97 0.500 2.000 0 98.4 70 130 TCLP Selenium(Se) 2.46 0.0500 2.000 0.06040 120 70 130 TCLP Silver(Ag) 2.15 0.500 2.000 0 107 70 130 Sample ID: 20040321-001AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: Batch= Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724299 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.18 0.500 2.000 0 109 70 130 2.269 4.01 20 TCLP Barium(Ba) ND 5.00 2.000 0.6508 97.8 70 130 0 0 20 TCLP Cadmium(Cd) 2.10 0.100 2.000 0.004215 105 70 130 2.178 3.45 20 TCLP Chromium(Cr) 1.98 0.200 2.000 0.006405 98.9 70 130 2.003 0.973 20 TCLP Lead(Pb) 1.92 0.500 2.000 0 96.1 70 130 1.967 2.36 20 TCLP Selenium(Se) 2.45 0.0500 2.000 0.06040 119 70 130 2.465 0.782 20 TCLP Silver(Ag) 2.11 0.500 2.000 0 105 70 130 2.148 1.90 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20040157 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: 42928 Sample ID: MB-42928 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724377 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: LCS-42928 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 Client ID: LCSS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724378 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.99 0.500 2.000 0 99.7 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 102 80 120 TCLP Cadmium(Cd) 2.07 0.100 2.000 0 104 80 120 TCLP Chromium(Cr) 1.99 0.200 2.000 0 99.7 80 120 TCLP Lead(Pb) 2.02 0.500 2.000 0 101 80 120 TCLP Selenium(Se) 2.10 0.0500 2.000 0 105 80 120 TCLP Silver(Ag) 1.96 0.500 2.000 0 97.9 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42928 WO#: 20040157 21 Apr-20 Sample ID: TCLP BLANK 1 4-9- SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 lient ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724380 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID: TCLP BLANK 2 4-9- SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 4/9/2020 RunNo: 111621 lient ID: PBS Batch ID: 42928 TestNo: SW6010D SW3010A Analysis Date: 4/10/2020 SegNo: 2724381 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 28 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: 42934 TCLP Mercury ND 0.00200 TCLP Mercury 0.00400 0.00200 0.00400 0 100 80 120 TCLP Mercury ND 0.00200 Sample ID: TCLP BLANK 1 4-9- SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 4/10/2020 RunNo: 111636 Client ID: PBS Batch ID: 42934 TestNo: SW7470A SW7470A Analysis Date: 4/10/2020 SegNo: 2724802 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury ND 0.00200 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 28 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG Lggir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: 42934 TCLP Mercury ND 0.00200 TCLP Mercury 0.00432 0.00200 0.00400 0.000141 104 75 125 Sample ID: 20040321-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 4/10/2020 RunNo: 111636 Client ID: Batch= Batch ID: 42934 TestNo: SW7470A SW7470A Analysis Date: 4/10/2020 SegNo: 2724813 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00441 0.00200 0.00400 0.000141 107 75 125 0.00432 2.06 20 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit Original RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Newton WWTP BatchID: 42936 WO#: 20040157 21 Apr-20 Sample ID: MB-42936 SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: 4/9/2020 RunNo: 111633 lient ID: PBS Batch ID: 42936 TestNo: SW8260 SW1311M Analysis Date: 4/10/2020 SegNo: 2724722 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.0500 1,2-Dichloroethane ND 0.0500 MEK ND 1.00 Benzene ND 0.0500 Carbon tetrachloride ND 0.0500 Chlorobenzene ND 0.500 Chloroform ND 0.0500 Tetrachloroethene ND 0.0500 Trichloroethene ND 0.0500 Vinyl chloride ND 0.0200 Surr: 4-Bromofluorobenzene 493 Surr: Dibromofluoromethane 466 Surr: Toluene-d8 472 500.0 98.6 70 130 500.0 93.2 70 130 500.0 94.3 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 20 of 28 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: 42951A Sample ID: MB-42951 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 4/10/2020 RunNo: 111755 Client ID: PBS Batch ID: 42951A TestNo: SW8081 Analysis Date: 4/13/2020 SegNo: 2730551 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 QC+ gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 13.3 20.00 66.7 10 119 Surr: DCB 15.4 20.00 77.2 10 119 m Sample ID: LCS-42951 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 4/10/2020 RunNo: 111755 Client ID: LCSS Batch ID: 42951A TestNo: SW8081 Analysis Date: 4/13/2020 SegNo: 2730552 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.0112 0.000500 0.0100 0 112 10 130 QC+ gamma-BHC 0.00849 0.000500 0.0100 0 84.9 10 130 Heptachlor 0.00893 0.000500 0.0100 0 89.3 10 130 Heptachlor epoxide 0.00946 0.000500 0.0100 0 94.6 10 130 Methoxychlor 0.0104 0.000500 0.0100 0 104 10 178 Surr: TCMX 13.8 20.00 69.1 10 130 Surr: DCB 13.5 20.00 67.7 10 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 21 of 28 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: R111414 pH 7.0 7.0 0 99.9 90 110 pH 7.0 0 0 6.9 0.6 10 Sample ID: CHECK 7 SampType: LCS TestCode: pH_Oil(9045D Units: s.u.@20.7C Prep Date: RunNo: 111414 Client ID: LCSW Batch ID: R111414 TestNo: SW9045D Analysis Date: 4/6/2020 SegNo: 2716045 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 28 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: R111515 Cyanide, Reactive ND 0.481 Cyanide, Reactive 8.98 0.485 10.00 0 89.8 85 115 Cyanide, Reactive ND 0.476 0.5000 0 92.5 65 135 Sample ID: 20040156-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Batch= Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719602 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.43 0.476 10.00 0 84.3 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 28 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: R111515 Sample ID: 20040156-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Batch= Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719602 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 20040156-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 111515 Client ID: Batch= Batch ID: R111515 TestNo: SW9014 Analysis Date: 4/6/2020 SegNo: 2719603 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.00 0.485 10.00 0 90.0 75 125 8.431 6.56 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 24 of 28 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 20040157 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: R111516 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4610 25.0 4800 0 96.0 85 115 Sulfide, Reactive 4560 25.0 4800 0 95.0 80 120 Sample ID: 20040156-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 111516 Client ID: Batch= Batch ID: R111516 TestNo: SW9034 Analysis Date: 4/6/2020 SegNo: 2719611 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4580 25.0 4800 0 95.4 80 120 4560 0.438 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 28 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 20040157 21 Apr-20 Client: Synagro Project: Newton WWTP BatchID: R111516 Sample ID: 20040156-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 111516 Dient ID: Batch= Batch ID: R111516 TestNo: SW9034 Analysis Date: 4/6/2020 SegNo: 2719611 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 28 DBPix Evaluation �6iSummit Environmental Technologies, Inc. 2`ll fl Win Rtrftet Analysis Request/Chain of Custody r— R..,nmit F.nvimnnirninT Tarhnnlnal P.c Tnn r.cP. —1— �, Guyahaga Falls, Ohio 44223 Tel: 330.253.8211 tax: 330.253.4489 pap of v sET No. I Company Name (Fle= Prmt) Project Namz Analytical Parameters and Metbods ..J6iE •7 Fc� Project Address ampany rats CCC Client Phone No. Repast to C � OICT11 Fax a ReSy1l� €'C# A 04 7 ClIvil Emai 1 iS Quote'Vo. q y a C.:on=t person 4(, 4X Sampled 6y U11MR if Ohio YAP samples J i d J Date 'lime A }0 L. # Saw Identl['eesttinn Collected [;ulledtd Q z �r■■■MI■■■■■■■■■■■ r■�■■■MIME■■■■■■■■■■■ l Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGa1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 20040157 RcptNo: 1 1.f' Logged by: Jesseca E. Westfall 4/2/2020 10:20:00 AM ,�4G r.f' Completed By: Jesseca E. Westfall 4/2/2020 3:18:28 PM 444 G Reviewed By: Jennifer Woolf 4/2/2020 5:25:06 PM )V'of'� Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes d❑ No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑d No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes V No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes V No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes V No ❑ 8. Sufficient sample volume for indicated test(s)? Yes V No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes V No ❑ 10. Was preservative added to bottles? Yes ❑ No V NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No V 13. Does paperwork match bottle labels? Yes V No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑ No ❑d 15. Is it clear what analyses were requested? Yes V No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 15.4 Goodl Not Present Page 28 of 28 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Newton WQ Permit Number: WQ 0003902 WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196 Monitoring Period: From 01/01/20 To 3/31/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative performed Class A or Class B complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 61h MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) x (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification chiding fine and imprisonment" / James Wentz PWU Director kpCti/[sAIL S y/7�5 f-,v Preparer Name and Title ( type or print) Land plher Name and Title (if applicable) (type or print) 57 Signalf. of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) YEAR I•' L"7 Sludge Grab Sampling Data DATE Sample ID Initial Sample 2hr Sample 22hr Sample Collection Analysis Collection Analysis Collection Analysis By Time pH Corrected pH Temp By By Time pH Corrected pH Temp By By Date Time pH re Corrected pH Temp By l ZC Z, # '' THICK ;i f;'� i% ' - / /n. i /l j ;�/' i iC THICK o�G'L'v'' i L I�,L� �, 1 ,Gi � .�I �, . 1.3. �� L!` U.(r5 �a�•S3 t� .�� 3+> # oC THICK ' C-F;1 �_i j %�J� Ij� � "PW, %W !C%:/ ,�, S / % �, � ✓ -�; �'- vi-L- 1 ' 4Y n _;, J-ge-LQ #THICK. i A , 3•-3 .;fie; 1-MO THICK _S 1;�; r' 3 L 171 z� .<v # f, THICK .2, %Z`/ DUI, # THICK, / `3� ?i r'. ' IF # 3 THICK` Ll' 15 !i' # THICK �,'-S � � I2.z7 7.0' il; CJ J1, !+o r%>` Z #.� THICK rkIP- 13, 71� ,'� %�1 �C� � Y"� ,� /� � �:�[� . 35"' r 7 f�'iCr' g �"��% ?& `ri? W,-37 ^ 7, 2 !,3 Z THICK �.� 7` f1 i� • .�� / .3 .i r i� /C� l C� �r�.4 - i f !i� - WWII T 13 �1 4 77 91-101A # THICK I .off vYr� l`d3Z 11.q S t2,.01 Z-f_! it ZCS { i u•_ HICK 4 5 a - THICK Z IZ,��. I' �� a I },U3 �� 1Z.(? �� .3 1 , Z'Z 1Z o e) I.�� u - t�` #-YTHiCK AT # e� THICK J, T /.4,} / ,� / U;�(� .Z,�%� %+yy�i1`.i `� d"'�«��{ye 7J 10 It Ito # THICK r I1� I'`L' 32 , 3 14S© 7 2g:0 i7 131 tC !Z,`: IZ, 34 l )A 3 12- 'ZIJ #� THICK 0 ' /u,y- / 12 , q `2 / 4/i vt ��J'y�" �,� /U ; /vR/1 /.S i 7-c' %� � % l7i % +�'��%! l�"�.20 0 E ; eC v t / ` r � �r l / � /Z7' --ZC # _� THICK %3,yc��.�, /` %, �ri� l "�ri7 / i'iC'>'in /f%,•luv It, 3� /� % ��� � f� /g-( ae) )3T,`vi /%� �,fG'� `, j 1 r #_].. THICK ��,1; :�. i G:LL (N .�t11 3� ` .{{zz 711or+1!9 camnla fnr nN ;"han tank k rPAr1v fnr tactina Temnerature is measured in °C Method - SM2550 B-2000 Sampling Collect #2 sample at least 2 hours after first sample. Guidelines: Collect #3 Sample at least 22 hours after second sample. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+B-2000 (Aqueous) pH is corrected to 25"C Year City of Newton - Clark Creek WWTP Sludge Grab Sampling Data �+ - •2 Hour Sample 22 Hour Sample •Collection MIMI or F To Temp Time a — 00-0 MMM Sampling Collect #1 sample for pH when tank is ready for testing. Guidelines Collect #1 sample for pH when tank is ready for testing. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+13-2000 (Aqueous) pH is corrected to 25°C ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Newton WQ Permit Number: WWTP Name: Newton Clark Creek WWTP NPDES Number: Monitoring Period: From 04/01/20 To 6/30/2020 WQ 0003902 NC 0036196 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion If applicable to alternative nerformed (Class A or Class B) comnlete the followine monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6"' MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) x (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certificatAL *including fine and imprisonment." James Wentz PWU Director Fax- 1111ea 461 ZIC Preparer ame and Title ( type or print) Land Tier Name and Title (if applicable) (type or print) V Signal of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) YEAR I•' L"7 Sludge Grab Sampling Data DATE Sample ID Initial Sample 2hr Sample 22hr Sample Collection Analysis Collection Analysis Collection Analysis By Time pH Corrected pH Temp By By Time pH Corrected pH Temp By By Date Time pH re Corrected pH Temp By l ZC Z, # '' THICK ;i f;'� i% ' - / /n. i /l j ;�/' i iC THICK o�G'L'v'' i L I�,L� �, 1 ,Gi � .�I �, . 1.3. �� L!` U.(r5 �a�•S3 t� .�� 3+> # oC THICK ' C-F;1 �_i j %�J� Ij� � "PW, %W !C%:/ ,�, S / % �, � ✓ -�; �'- vi-L- 1 ' 4Y n _;, J-ge-LQ #THICK. i A , 3•-3 .;fie; 1-MO THICK _S 1;�; r' 3 L 171 z� .<v # f, THICK .2, %Z`/ DUI, # THICK, / `3� ?i r'. ' IF # 3 THICK` Ll' 15 !i' # THICK �,'-S � � I2.z7 7.0' il; CJ J1, !+o r%>` Z #.� THICK rkIP- 13, 71� ,'� %�1 �C� � Y"� ,� /� � �:�[� . 35"' r 7 f�'iCr' g �"��% ?& `ri? W,-37 ^ 7, 2 !,3 Z THICK �.� 7` f1 i� • .�� / .3 .i r i� /C� l C� �r�.4 - i f !i� - WWII T 13 �1 4 77 91-101A # THICK I .off vYr� l`d3Z 11.q S t2,.01 Z-f_! it ZCS { i u•_ HICK 4 5 a - THICK Z IZ,��. I' �� a I },U3 �� 1Z.(? �� .3 1 , Z'Z 1Z o e) I.�� u - t�` #-YTHiCK AT # e� THICK J, T /.4,} / ,� / U;�(� .Z,�%� %+yy�i1`.i `� d"'�«��{ye 7J 10 It Ito # THICK r I1� I'`L' 32 , 3 14S© 7 2g:0 i7 131 tC !Z,`: IZ, 34 l )A 3 12- 'ZIJ #� THICK 0 ' /u,y- / 12 , q `2 / 4/i vt ��J'y�" �,� /U ; /vR/1 /.S i 7-c' %� � % l7i % +�'��%! l�"�.20 0 E ; eC v t / ` r � �r l / � /Z7' --ZC # _� THICK %3,yc��.�, /` %, �ri� l "�ri7 / i'iC'>'in /f%,•luv It, 3� /� % ��� � f� /g-( ae) )3T,`vi /%� �,fG'� `, j 1 r #_].. THICK ��,1; :�. i G:LL (N .�t11 3� ` .{{zz 711or+1!9 camnla fnr nN ;"han tank k rPAr1v fnr tactina Temnerature is measured in °C Method - SM2550 B-2000 Sampling Collect #2 sample at least 2 hours after first sample. Guidelines: Collect #3 Sample at least 22 hours after second sample. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+B-2000 (Aqueous) pH is corrected to 25"C Year City of Newton - Clark Creek WWTP Sludge Grab Sampling Data �+ - •2 Hour Sample 22 Hour Sample •Collection MIMI or F To Temp Time a — 00-0 MMM Sampling Collect #1 sample for pH when tank is ready for testing. Guidelines Collect #1 sample for pH when tank is ready for testing. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+13-2000 (Aqueous) pH is corrected to 25°C ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Newton WQ Permit Number: WQ 0003902 WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196 Monitoring Period: From 07/01/20 To 9/30/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion If annlicable to alternative performed (Class A or Class B) comolete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Gen. Mean Maximum Units dences Analysis Fecal 2x10 to the 01 MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0ption/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) x (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certificatio including fine and imprisonment." James Wentz PWU Director I✓,Sl �•• x f 1�46 k.", 1V in ac i0 Preparer%ame and Title ( type or print) L Applier Name and Title (if applicable) (type or print) / Z-S—� jp �� 2-s 7 ( Signatur of Prepare14 Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) YEAR I•' L"7 Sludge Grab Sampling Data DATE Sample ID Initial Sample 2hr Sample 22hr Sample Collection Analysis Collection Analysis Collection Analysis By Time pH Corrected pH Temp By By Time pH Corrected pH Temp By By Date Time pH re Corrected pH Temp By l ZC Z, # '' THICK ;i f;'� i% ' - / /n. i /l j ;�/' i iC THICK o�G'L'v'' i L I�,L� �, 1 ,Gi � .�I �, . 1.3. �� L!` U.(r5 �a�•S3 t� .�� 3+> # oC THICK ' C-F;1 �_i j %�J� Ij� � "PW, %W !C%:/ ,�, S / % �, � ✓ -�; �'- vi-L- 1 ' 4Y n _;, J-ge-LQ #THICK. i A , 3•-3 .;fie; 1-MO THICK _S 1;�; r' 3 L 171 z� .<v # f, THICK .2, %Z`/ DUI, # THICK, / `3� ?i r'. ' IF # 3 THICK` Ll' 15 !i' # THICK �,'-S � � I2.z7 7.0' il; CJ J1, !+o r%>` Z #.� THICK rkIP- 13, 71� ,'� %�1 �C� � Y"� ,� /� � �:�[� . 35"' r 7 f�'iCr' g �"��% ?& `ri? W,-37 ^ 7, 2 !,3 Z THICK �.� 7` f1 i� • .�� / .3 .i r i� /C� l C� �r�.4 - i f !i� - WWII T 13 �1 4 77 91-101A # THICK I .off vYr� l`d3Z 11.q S t2,.01 Z-f_! it ZCS { i u•_ HICK 4 5 a - THICK Z IZ,��. I' �� a I },U3 �� 1Z.(? �� .3 1 , Z'Z 1Z o e) I.�� u - t�` #-YTHiCK AT # e� THICK J, T /.4,} / ,� / U;�(� .Z,�%� %+yy�i1`.i `� d"'�«��{ye 7J 10 It Ito # THICK r I1� I'`L' 32 , 3 14S© 7 2g:0 i7 131 tC !Z,`: IZ, 34 l )A 3 12- 'ZIJ #� THICK 0 ' /u,y- / 12 , q `2 / 4/i vt ��J'y�" �,� /U ; /vR/1 /.S i 7-c' %� � % l7i % +�'��%! l�"�.20 0 E ; eC v t / ` r � �r l / � /Z7' --ZC # _� THICK %3,yc��.�, /` %, �ri� l "�ri7 / i'iC'>'in /f%,•luv It, 3� /� % ��� � f� /g-( ae) )3T,`vi /%� �,fG'� `, j 1 r #_].. THICK ��,1; :�. i G:LL (N .�t11 3� ` .{{zz 711or+1!9 camnla fnr nN ;"han tank k rPAr1v fnr tactina Temnerature is measured in °C Method - SM2550 B-2000 Sampling Collect #2 sample at least 2 hours after first sample. Guidelines: Collect #3 Sample at least 22 hours after second sample. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+B-2000 (Aqueous) pH is corrected to 25"C Year City of Newton - Clark Creek WWTP Sludge Grab Sampling Data �+ - •2 Hour Sample 22 Hour Sample •Collection MIMI or F To Temp Time a — 00-0 MMM Sampling Collect #1 sample for pH when tank is ready for testing. Guidelines Collect #1 sample for pH when tank is ready for testing. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+13-2000 (Aqueous) pH is corrected to 25°C ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Newton WQ Permit Number: WQ 0003902 WWTP Name: Newton Clark Creek WWTP NPDES Number: NC 0036196 Monitoring Period: From 10/01/20 To 12/31/2020 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens x If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion Tf annlieable to alternative nerformed (Class A or Class B) complete the followine monitorinc data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6'h MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0ption/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) x (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option(Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certificatio including fine and imprisonment." / James Wentz PWU Director o f 9.L TS5 1✓S� �.1����,7u rp Preparer Name and Title ( type or print) Lad pplier Name and Title (if applicable) (type or print) e Signatu of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) YEAR I•' L"7 Sludge Grab Sampling Data DATE Sample ID Initial Sample 2hr Sample 22hr Sample Collection Analysis Collection Analysis Collection Analysis By Time pH Corrected pH Temp By By Time pH Corrected pH Temp By By Date Time pH re Corrected pH Temp By l ZC Z, # '' THICK ;i f;'� i% ' - / /n. i /l j ;�/' i iC THICK o�G'L'v'' i L I�,L� �, 1 ,Gi � .�I �, . 1.3. �� L!` U.(r5 �a�•S3 t� .�� 3+> # oC THICK ' C-F;1 �_i j %�J� Ij� � "PW, %W !C%:/ ,�, S / % �, � ✓ -�; �'- vi-L- 1 ' 4Y n _;, J-ge-LQ #THICK. i A , 3•-3 .;fie; 1-MO THICK _S 1;�; r' 3 L 171 z� .<v # f, THICK .2, %Z`/ DUI, # THICK, / `3� ?i r'. ' IF # 3 THICK` Ll' 15 !i' # THICK �,'-S � � I2.z7 7.0' il; CJ J1, !+o r%>` Z #.� THICK rkIP- 13, 71� ,'� %�1 �C� � Y"� ,� /� � �:�[� . 35"' r 7 f�'iCr' g �"��% ?& `ri? W,-37 ^ 7, 2 !,3 Z THICK �.� 7` f1 i� • .�� / .3 .i r i� /C� l C� �r�.4 - i f !i� - WWII T 13 �1 4 77 91-101A # THICK I .off vYr� l`d3Z 11.q S t2,.01 Z-f_! it ZCS { i u•_ HICK 4 5 a - THICK Z IZ,��. I' �� a I },U3 �� 1Z.(? �� .3 1 , Z'Z 1Z o e) I.�� u - t�` #-YTHiCK AT # e� THICK J, T /.4,} / ,� / U;�(� .Z,�%� %+yy�i1`.i `� d"'�«��{ye 7J 10 It Ito # THICK r I1� I'`L' 32 , 3 14S© 7 2g:0 i7 131 tC !Z,`: IZ, 34 l )A 3 12- 'ZIJ #� THICK 0 ' /u,y- / 12 , q `2 / 4/i vt ��J'y�" �,� /U ; /vR/1 /.S i 7-c' %� � % l7i % +�'��%! l�"�.20 0 E ; eC v t / ` r � �r l / � /Z7' --ZC # _� THICK %3,yc��.�, /` %, �ri� l "�ri7 / i'iC'>'in /f%,•luv It, 3� /� % ��� � f� /g-( ae) )3T,`vi /%� �,fG'� `, j 1 r #_].. THICK ��,1; :�. i G:LL (N .�t11 3� ` .{{zz 711or+1!9 camnla fnr nN ;"han tank k rPAr1v fnr tactina Temnerature is measured in °C Method - SM2550 B-2000 Sampling Collect #2 sample at least 2 hours after first sample. Guidelines: Collect #3 Sample at least 22 hours after second sample. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+B-2000 (Aqueous) pH is corrected to 25"C Year City of Newton - Clark Creek WWTP Sludge Grab Sampling Data �+ - •2 Hour Sample 22 Hour Sample •Collection MIMI or F To Temp Time a — 00-0 MMM Sampling Collect #1 sample for pH when tank is ready for testing. Guidelines Collect #1 sample for pH when tank is ready for testing. Sample must arrive in lab within 15 minutes of collection. pH is measured in s.u. pH Method - SM4500 H+13-2000 (Aqueous) pH is corrected to 25°C SECTION 6 Agricultural Lime Application Log Year: 2020 Project: Newton Field (state -county -site -field) Soil pH Lime Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied NC-CA-18-1 7.5 O.OT/Ac. NC-CA-18-2 7.8 O.OT/Ac. NC-CA-18-3 7.8 0.0 T/AC NC-CA-18-4 7.8 O.OT/Ac. NC-CA-18-5 7.8 O.OT/Ac. NC-CA-20-3 7.3 O.OT/Ac. NC-CA-20-8 6.8 O.OT/Ac. NC-LT-119-5 5.9 O.OT/Ac. NC-CA-27-1 5.1 O.OT/Ac. NC-CA-27-2 5.1 O.OT/Ac. NC-CA-25-1 4.8 O.OT/Ac. NC-CA-32-1 5.4 O.OT/Ac. CA-47-6 6.5 O.OT/Ac. CA-47-7 5.7 O.OT/Ac. CA-21-1 6.7 O.OT/Ac. They get their lime in the sludge since Newton is Lime stabalized. SECTION 7 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031451 Client: Gordy Goins Advisor: Alex Fox vo- Predictive 2924 Blackburn Bridge Rd / 1489 Ed Synagro Craig Lane 284 Boger Rd Mehlich-3 Extraction Soil Report Vale, NC 28168 Mocksville, NC 27028 Links to Helpful Information Sampled County: Catawba Client ID: 284170 Advisor ID: 501947 Sampled: 05/07/2020 Received: 05/29/2020 Completed: 06/05/2020 Farm: CA-18 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 40 0 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.02 11.8 100 0.0 7.5 40 82 86 11 36 548 324 235 235 225 0.1 1 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 50 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 0.94 19.3 100 0.0 7.8 69 47 91 8 51 393 225 373 373 274 0.1 1 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 40 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.46 1.05 17.3 100 0.0 7.8 90 52 93 6 44 415 238 327 327 193 0.1 1 North Carolina r Tobww Trust Fw►d C47mmisslan Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL031451 Gordy Goins Page 2 of 3 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.27 0.89 28.4 100 0.0 7.8 155 112 88 10 67 171 93 744 744 226 0.1 0 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.18 0.94 25.3 100 0.0 7.8 98 79 88 11 64 150 80 473 473 225 0.1 0 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO31451 Gordy Goins Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL029832 �5{i �141..tiL Client: Tim Woodrff Advisor: Alex Fox Predictive PO Box 1151 Synagro ;• Garner, NC 27529 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Catawba Links to Helpful Information Client ID: 349468 Advisor ID: 501947 Sampled: Received: 04/17/2020 Completed: 04/27/2020 Farm: CA-20-3 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.07 10.3 99 0.1 7.3 84 40 87 10 29 752 449 252 252 160 0.1 1 Noah Carolina FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO29832 Tim Woodrff Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032834 �5{i �141..tiL Client: Tim Woodrff Advisor: Alex Fox Predictive PO Box 1151 Synagro ;• Garner, NC 27529 284 Boger Rd +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Catawba Links to Helpful Information Client ID: 349468 Advisor ID: 501947 Sampled:06/23/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: Sample ID: 8 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 120 90 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.18 0.97 6.7 98 0.2 6.8 10 26 79 17 110 643 391 77 77 76 0.1 1 Noah Carolina i� FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32834 Tim Woodrff Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 21-004-0512 Account No: 12259 Advisor: Synagro/Columbus NC Mary Brewer 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Tim Woodliff 2020 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: CA-21 Date Received:01/04/2021 Date of Report: 01/05/2021 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na 109901 1 MIN 1.8 6.7 0.3 8 14 29 88 59 0 65 65 70 5.7 96 80 13 0.8 0 Crop Recommendations: Rec Uom Lime (Vacre) N P205 K20 S Mn Zn Cu B Mg Last Crop 1- Fescue Hay Ib/acre 0.0 150 125 114 20 0 0 0 0 0 Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002562 �5{i �141..tiL Client: Gary Dellinger Advisor: Synagro Predictive 965 Hopewell Church Rd Synagro ;• Catawba, NC 28609 284 Boger Rd. +_ Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Catawba Links to Helpful Information Client ID: 493739 Advisor ID: 503079 Sampled: 08/12/2020 Received: 08/19/2020 Completed: 08/26/2020 Farm: ca-25 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Soybean 1.3 0 130 0 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-I Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.18 1.00 4.4 53 2.0 4.9 6 83 18 26 94 138 93 27 27 44 0.1 2 Noah Carolina i� FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL002562 Gary Dellinger Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032837 �5{i �141..tiL Client: Alex Fox Advisor: Alex Fox Predictive Synagro Synagro ;• 284 Boger Rd 284 Boger Rd $. Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Mocksville, NC 27028 Links to Helpful Information Sampled County: Catawba Client ID: 501947 Advisor ID: 501947 Sampled: 06/15/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: CA-27/little Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.1 120-200 30 20 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.71 0.88 4.3 58 1.8 5.1 49 68 31 19 84 608 382 46 46 89 0.2 5 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.8 120-200 130 100 0 0 0 $ 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.18 0.95 3.9 65 1.4 5.1 7 18 38 25 188 136 99 16 16 39 0.1 3 Noah Carolina i� FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32837 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SL011130 �5{i �141..tiL Client: Synagro Advisor: ;• Predictive Synagro r. 284 Boger Rd. r, Soil Report Mehlich-3 Extraction Mocksville, NC27028 Links to Helpful Information Sampled County: Catawba Client ID: 503079 Advisor ID: Sampled: Received: 10/28/2020 Completed: 11/12/2020 Farm: CA-32/ Ronnie Sugmond Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.0 120-200 0 50 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 1.08 1.02 7.9 76 1.9 5.4 85 44 60 13 46 201 138 215 215 83 0.1 1 Noah Carolina i� fdtaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY21-SLO11130 Synagro Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm Page 1 of 1 Report No: 21-004-0520 Account No: 12259 Advisor: Synagro/Columbus NC Mary Brewer 284 Boger Rd Mocksville NC 27028 Waypoint'(D ANALYTICAL Client: Randy Leatherman 2020 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: LT-47 CA-47 Date Received:01/04/2021 Date of Report: 01/05/2021 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na 109910 2 MIN 1.9 5.7 1.1 70 51 64 88 74 0 130 130 210 5.1 78 53 19 1.1 0.1 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.5 N 150 P205 0 K20 40 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop 09911 6 MIN 1.9 6.6 0.8 564 54 12 188 121 0 433 433 200 13.9 94 84 7 0.8 0.1 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.0 N 150 P205 0 K20 40 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop 09912 7 MIN 1.6 5.7 1.4 164 35 12 288 194 0 128 128 95 6.6 78 63 12 0.7 0 Crop Recommendations: 1- Fescue Hay Rec Uom Ib/acre Lime (Vacre) 0.5 N 150 P205 0 K20 68 S 20 Mn 0 Zn 0 Cu 0 B 0 Mg 0 Last Crop Comment: Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SL032836 �5{i �141..tiL Client: Gordy Goins Advisor: Alex Fox Predictive 2924 Blackburn Bridge Rd / 1489 Ed Synagro ;• Craig Lane 284 Boger Rd $. Soil Report Mehlich-3 Extraction Vale, NC 28168 Mocksville, NC 27028 Links to Helpful Information Sampled County: Catawba Client ID: 284170 Advisor ID: 501947 Sampled:06/22/2020 Received: 06/30/2020 Completed: 07/09/2020 Farm: It-110 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 130 50 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.27 0.92 5.7 87 0.7 5.9 8 43 56 27 44 1072 660 47 47 97 0.2 4 Noah Carolina FutaiW frum FundCiwn1nl55km Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Aqriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY20-SLO32836 Gordy Goins Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htn*fsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-Al2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagr.gov/agronomi/uvrst.htm