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HomeMy WebLinkAboutWQ0006373_Complete File - Historical_20171231w Permits and Engineering Unit Water ualit Section o Date: April 30, 1992 NON -DISCHARGE SA `F REPORT AND RECOMMENDATION County: Mecklenburg Permit No. WQ 0 373 9' - 7 PART I - GENERAL INFORMAT10N I. Facility and Address: Fehr Property -Infiltration Gallery Martin Marietta Corporation 7921 Southpark Plaza, Suite 210 Littleton, Colorado 80120 a Date of Investigation.- Aril 30, 199 33. Report Prepared T. Chen . Persona Contacted and, Telephone Nu r: Chalam V. Pakala, E. I .T. , Laws Environmental, Inc. 7 4 3 7 1747 . Directions to Site; From the junction of Highway 27 and Mt* H lly Hunt ra ill.a Road H 1666) approximately 2. miles northwest of the Charlotte City Limits, travel south- east on Highway 7 about 0.5 mile. The proposed site is on the right (southwest) aide of the road approximately 150 feet after crossing the bridge over Long, Creek. 6. Size (land available for expansion and upgrading)*- Adequate land area: available for expansion/upgrading 7. Topography (relationship to 100 year fled plain included):, The site was graded and. level; and is not in a flood plain. . Disposal Sites, list for all disposal sites. - Latitude: 35 171 Longitude: 80 0 58, 4511 Attach a U.S.G.S. map extract and indicate facility site. USGS Quad No.: F 15 SW USGS Quad Name: Mtn. Island Lake 9: Location of Nearest Dwelling and;; Water Supply Well: One dwelling with water supply well is approximately 250 feet northwest st of the proposed groundwaterre : diati n site. 10. Watershed Stream Basin Information: ation a. watershed 1 aaifi atien: +� r �• • • F ',. PART II -DESCRIPTION DISCHARGE AND TREATMENT T WORKS 1. Type of wastewater, sludge or contaminated soil: Domestic 1 Industrial *Pretreated petroleum contaminated groundwater aVolume: 0.00720 MGD (Design Capacity) . Types and quantities of industrial wastewater: Wastewater is to be venerated from a groundwater recovery system The groundwater is contaminated with petroleum products,. C. Prevalent toxic constituents in wastewater: The retreated groundwater may contain trace amount of petroleum products and metals (Lead). dPretreatment Program (POTWs only): A in development approved should be required not needed 2. Production Rates ( industrial discharges oil ►) in Rounds Per Zia RA . Description of Industrial Process (for industries only) and Applicable CFR Part and Subpart: N/A . Type of Treatment (specify whether proposed or existing): The groundwater recovery system is proposed d to consist of an oil/water separator, Pero idation infiltration gallery, and a number of monitoring and recovery wells , 5, Sludge handling and disposalscheme: / . Treatment Plant Classification. Proposed facility, no rating determined. SIC Code(s Wastewater cad+ (s): N Primary: Pretreated petroleum contaminated groundwater Secondary: Main Treatment Unit Code: N PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grant Funds (municipals only) N . Special monitoring requests: 3. Air Quality and/or Groundwater concerns or hazardous materials utilized at this facility that may impact water uality, air quality, or groundwater? The proposed waste - flow is to be generated from a a groundwater recovery system. The groundwater in the area of a gasoline station,, which ceased operation in May, 1 83, was contaminated with petroleum products. Prosper treatment to remove contaminants from recovered groundwater for to re -injection into the aquifer may prevent any impact on groundwater. Also no hazardous materials will be utilized at this facility. No detrimental impact to the environment is anticipated from this operation 4. Other: `/ PA. It Is recommended that a Nbnttrischarge Permit be issued for the groundwater r out y p ,.,� \� . '� ram"-^..*v?tk4�. t•.. $^4 �A d "° ` w �r ✓ k �' ,.. �� °4 a�r" B "a �r ANY Y Elm- . crab t ; State of North Carolina t3rv�a.�)r��r. _. TY Department of .nviron -,e t, Health and Nato Source's Division of Environmental Management ement WIR 2 '1992 512 NorthSalisbury Street - Raleigh, North Carolina 27604 J rnes G. Martin, Governor George Ti William W. Cobey, Jr., Secretary April 1, 199 MR LLIAM ARTICOLA MARTIN MARIETrA AGGRIGATES 71 SOUTTIPARK PLAZA; SUITE 210 uhJ t; Application No. WQ0006373 purr Property Subsurface Disposal Facility Mecklenburg County Dear MR AR I LA. TheDivision's Permits and Engineering Unit acknowledges receipt of your permit application and supporting materials on April 7, 1992. This application has been assigned the number shown above.. Please refer to this number when making inquiries on this project. Your project has been assigned to John Seymour for a detailed engineering review. A technical, acknowledgement will be forthcoming. e aware that theDivision's regional office, copied below, must provide recommendations from the Regional Supervisor or a Procedure Four evaluation for this project, prig to final action by the f you have any questions, please contact John Seymour at 1 733-5083. Sincere y, t CDonald a P.E. Supervisor, rinits and Engineering Unit cc: Mooresville Regional Office Law Environmental' Pollution Prevention Pays P.Oox 29535, Raleigh, North Carolina 27626--0535 Telephone 919-73 -"7ilt An Equal Opportunity Affirmative ct on Employer LAW ENVIRONMENTAL, INC. 4333 WILMONT ROAD, SUITE 300 CHARLOTTE, NORTH CAROLINA 26217 RU. BOX 246674 CHARLOTTE, NORTH 6ARGUNA 26224-0674 704-35 -1747 704-357-1622 (FAX) April 2, 19 . c ou North Carolina Department rent; 1991 and Natural Resources Division of Environmental Management t w s Permits and Engineering Unit P.O. Box 7687 Raleigh, NC 27611 n Attention: Mr. John Seymour Engineer ubj t: Non -Discharge Permit Application , urr Property C" Highway 27 at Long Creek Mecklenburg ;County, North Carolina LEI Jon No. 5 - 5 -U 5 {gentlemen: n behalf of Martin Marietta o tion, Law Environmental is pleased to submit the attached non -discharge permit application. This submittal is in response to the North Carolina Division of Environmental Management E letter dated February 14, 19-0 The purpose f the proposed system is to recover ground water at the referenced site that has been impacted by the apparent leakage or spillage of fuel oil. Recovery of the ground water from three -wells -1, l - d l -) will reduce the size of the contaminant plume in both the vertical and lateral dimensions, minimizing the potential for off -site migration and reducing concentrations o contaminants present in the shallow aquifer. Although'the '"-Pero idati n system has been designed for a 3.8 gallons per minute (gpm) flow rate, a 1 gpm flow rate is being utilized until an optimum infiltration rate is determined from onsite field tests The treatment system is designed to reduce the concentrations of dissolved volatile organic compounds in the recovered ground water, The treatment system will employ UV -Pero idation to produce effluent acceptable for re -injection into the aquifer through an infiltration gallery in accordance th the North Carolina Division of Environmental Management's (1' guidelines. s 5-AMT1 "rPrmte'don R sgd'd apt! Carolina Department of Health [ Natural Resources 2, 1992 Action Plan was submitted to NCDEM on January 16, 1992. This permit is one of the requirements 1r► the SOC which,will be issued by the Mooresville appreciateWe our consideration of our application. Please contact us if you have any comments or questions. Sincerely, LAW ENVIRONMENTAL, INC. ANMVY . McCormick, E.I.T. Staff Engineer Chal*am. Pakala, E.I.T. Pro ect Engineer C KeithA. Anthony, P.E. Principal cfm cc: Mr. William Articola Martin Marietta Corporation Littleton, CO AllenSchiff MooresvilleNCDEM ff 5 TIO TABLEOF CONTENTS 1.0 NON -DISCHARGE PERMIT APPLICATIONFORM SUBSURFACEA . . ................. 1_1 2.0 DESCRIPTION OF THE ORIGIN, TYPE AND FLOW OF WASTE TO BE TREATED AND WASTE ANALYSIS....... ... ..........�2-1 .0 FOLLOW-UP EVALUATION ............ 3-1 .0 SOILS AND HYDROGEOLOGICI .... ............... 4-1 .1 Soils Description ........., .............. ... ...... .... .... 4.2 Hydrogeologic Desciiption ..... _ ....... a........ ........... - ; 5.0 FIGURES ....... .......... ......... — ., _1 Figure1- Site Location Site Plan Pi - OperationalSchematic of Proposed Treatment System Figure - Typical Recovery Well Figure -' y o loie Profiles Proposed'Infiltration Chile - Plan and Section Details 6.0 SOILS SCIENTIST'SEVALUATION RECOMMENDATIONS....... .. ... ....... .. .... ........ , _ 1 7.O TECHNICALP CI A A AC' ' LITERATURE-1 .+ .... ... ... ... Drawing I - Site Plan DrawingUtility Trench Plan and Sections Treatment y tetEquipment Plan APPENDICES Appendix I w Test Boring Records Appendix H - Infiltration Gallery Design Calculations A - Laboratory Analysis Department of Environment, Health, anNatural Resources Division ofEnvironmental Management Non -Discharge it Application (THISAI* BE PHOTOCOPIEDFOR USE AS AN O SEPTICE PIPE / GRAVITY SUBSURFACE SYSTEMS IFOR MECHANICAL TREATMENT Y SUBSURFACE DISPOSAL USE FORM MTDS1 (THE DIVISION of ENVIRONMENTAL MANAGEMENT HAS JURISDICTION IF THE SYSTEM TREATS INDUSTRIAL WASTEWATER OR IF THE SYSTEM IS OWNED BY A SANITARY DISTRICT, A METROPOLITAN SEWAGE DISTRICT, A WATER & SEWER AUTHORITY, A COUNTY, A MUNICIPALITY, OR A PUBLIC VTILITY. THE DIVISION OF ENVIRONMENTAL HEALTH HAS JURISDICTION FOR OTHER DOMESTIC SUBSURFACE SYSTEMS) L GENERAL INFORMATION: 1. Applicant'(o gyration individual, or otherMARTIN t RI TT . CORPORATION TON . Print Owners or Signing ffi i l's Name and Title (the person Who is legally responsible for the facility and its compliance): NCR WILLf ART COL F Mailing Address:tTI=R I't At rr City: _ LITTLETON State: C 0 Zip* 80120 Telephone o.: 303 971-1885 4. Project Name (subdivision, facility, or establishment name - should be consistent with project name on plans/specs., letters of flow acceptance; Operational Agreements, etc,): FURR Ptr z TI 5. Application ate; 4-3-92 6. Fee Submitted: ` � 0-0 7. County where project is located: MECKL ` %3UR 8. Address of treatment and subsurface facility; NC HIGHWAY 7 AT LONG CREEK (ERR FIGURE ; FOR SITE PLAN) 9. Latitude: 35' 1 7' 5 " Longitude: 0° S « " of subsurface fields FORM: LPPG 4/91 Page 1 of 1 PAGE 2 (4/9 1) !L PERMIT INFORMATION: 1. Permit No. (will be completed by DEM): If this application is being submitted as a retolt of a renewal or modification to an ttistingi;trai� list the exisfingpetmitournbor N��.Ahaissutdate,-Lx 4. Spocifywitetherthoapplitahtis,,'' —private, poblk or X S. Spe.64 whether applicant is* _ sanitary distritt._� metropolitan sewage district; wate+ oeityl -- county; public ufifiry; am) tQZ= �,A�QLI�t STATION ZELL 3 1. Nat= of Wislt*Ote� Dotnestic-, % Com�l % Industrial; —iu % Other waste (specify): TMPkL=, L2jJJJJJL IJ4%TR'R 2,. please provide a one or two word description specifying the Origin of the wa=water� 4 industria� such as scho6l, siIMVisidb n, hospital, cmth6176 In 11��ACTED LLIU� �61111 , -- I — I 3. If wastewater is not domestic in nature, what level of pretreatment has been provided J-IAJ�Kr�()R �,IILL REMOVE FU,,E to ensure protection of the receiving treatment system: —0 —IL—,A—qA —rE L —SE� OPERAT""NA PRODUC 'SIGN 7200 gallons per daSCH'MATI' 4. Volume of wastewec ater, generated by this projt: y 5. Exp Ian and of how w ast to water volume was Bete in �PT �:s 1 �tNq ', 0 N �x c'-' '�LOVERY DA'1 - A PICA 1,1)1 "ATEI'l A KA,11M PUMP �1ICIM �11'-Mrillxl �111111-11-1 �011-11 �11Y'11�1;11- on Brief project description: IMPACTEI) GROUND WATER IS PUMPED TO AN 0,1L/WA'rER SEPARATOR. WIIER,-r.A.. rf7V DDtIrITTOT IV vT?P(z4'VT1 LYTTT R.V.�VPARATFI") F'ROM TTIT' RECOVERED CROUND WATER. ALL WTAT]"'R FROM IV. DESIGN INFORMATION: 1 Specify the type of system that is being installed: low pressure', FATL�R STE ik I gravity; L other TOTAL ITX0VERY SYSTEM,-IIIPACTED GROUND Ga�F , �T,' 77 1 7, 7; -c7 V - 11 F] < 0'X I NE 717 ,1-.,,jT'.DMiN'r FOLLOWED BY AN 17NFILTRIMON GAM LEIRY 2 of 10 *SYSTEII. HOWEVER, 11202 INCREASES THE OXYCEN CONTENT IN THE TREATED EFFLUENTS FR01M THE UV-PE11,0XID1, UNIT, TITUS, ENIHM'41.NG CONTAMINANT DECRADAIA,ON, IN TITS AQUIFFR. LOW PRESSURF-/GRAVITy PAGE 3 (4/9 1) ', *2. Provide a brief listing of the compot"ents of this treatment and disposal system (if not covered by specific questions below), including dimensions, capacities, loading rates, and detention times of tanks, Pumping facilities (duplex pumps), high water alarms, filters (specify type), ponds, lagoons, disinfection facilities, subsurface fields. etc-- 7. The fDIlOwing criteria should be used for the sizing of residential septic tanks: a- three bedrooms or less, use minimum 900 gallons; b. four bedrooms, use minimum 1000 gallons; C. five bedrooms, use minimum 1250 gallons. 8. For businesses with a design flow less than 600 GPD, the minimum tank capacity shall be twice the flow. 3 of 10 LOW PRESS URF,(GRAVITY PAGE 4 (4/91) 9. - The following criteria should be used for the sizing of septic tanks for residences with more than five bedrooms, multiple family residences, tanks serving two or more residences*, or establishments with a flow between 600 GPD and 1500 GPD: Septic Tank Volume = (L 17) (daily sewage flow) + 500 gallons *Minimuna septic tank capacity shall be 1500 gallons 10. For design flows between 1500, GPD and 4500 GPD, the following criteria shall be used: Septic Tank Volume = (0.75) (daily sewage flow) + 1125 gallons 11. For design flows which exceed 4500 GPD, use a septic tank capacity equal to the flow. 12. Specify the septic tank Volume: _ NZA gallons 13. Specify the pump tank volume:, NA gallons 14. Specify the number of pumps and their capacity- --I— pumps at —aL---L-OGPM 15. Specify the high water a ETA BI,Eaidable & visual; sFF,_UW.L_I_ auto dialer 16. Name, of closest downstlope surface waters: .. U i.oN,, . cF�F _c_ Y� 17. Classification of closest downslope surface waters: C (as established by the Environmental Management Commission and specified on page 7 of this application). 18. If a power failure at the facility could impact waters classified as WS, SA, B, or SB, describe which of the measures are being implemented to prevent such impact, as required in 15 NCAC 2H.0200: THE SYSTEM IS EQUIPPED WITF A SAFETY FEATURE . SUCH THAT DURING A POWER FAILURE THE ENTIRE SYSTEM WIIJ, BE SHUT DOWIN 19. The different disposal fields, laterals, or groups of laterals in a subsurface system are typically designed to be dosed at different rates or volumes from one another. Explain the method that will be used to ensure that the proper dosing rates and volumes occur: 20. The project must conform to the following buffers: a) 100 feet between the disposal area and any public or private water supply including wells; b) 50 feet between disposal area and waters classified as WS-1, S-II, WS-Ill or B; and 100 feet between the disposal area and the normal high water level of waters classified as SA or SB; c) 50 feet between any the disposal area and any stream, lake, river, or natural drainage way; d) 50 feet between the treatment/disposal systems and property lines; 4 of 10 LOW PRESSUREIGRAVITY PAGE 5 ' (4 1 10 feet between the disposal area and any surface water interceptor drains or diversions (ups o e feet between the disposal area and any surface water intercepter drains or diversions (downslo d any groundwater drainage systems; feet between disposal area and any other subsurface disposal area except the repair 1+ If any of the applicable buffers are are not being met, please explain how e proposed buffers 1 provide equal or better protection of the Waters of the State with n increased potential for nuisance conditions: THE INFILTRATION CALLER' IS DESIGNED SUCH THAT IT IS ENTIRELY WITHIN THE CAPTURE ONE OF THE RECOV S THEREBY CREATING A CLOSED LOOP HYD IILZC a TES T TII + LOW P tT h. For systems " g industrial waste or any system with a design flow greater than GPD ahYdrOgeOlOgic and soils description of the subsurface to a depth of twenty feet Or bedrock, whichever ;is less. The number of rings shall be sufficient to determine significant changes in lithly, the vertical permeability of the unsaturated zone and the hydraulic conductivity of the saturated n , depth to the mean season al high water table, and a dete ination of transmissivity and specific yield of the unconfinedaquifer, i. Proposal for groundwater monitoring. . Information on the location, construction details, and primary usage of all wells within 500 feet of the treatment/disposal facilities. k. dr industrial caste a complete chemical analysis Of the typical wastewater to include but not be limited to Total Organic Carbon, Chlorides, Phosphorus, Ammonia, Nitrates, Phenol, Total Trihalom thanes, Tonicity 'Vest Parameters, Total Halogenated Compounds, Total COlifOrms, and Total Dissolved lids. cf 1 LOW PRESSURF PAGE 7 (4/91) JGRAVITy TO: REGIONAL WATER QUALITY SUOERVISOR Please provide me with the classification of the surface waters identified in number 5 below and on the attached map segment: Name of stitface, waters: Classification (as established by the Environmental Management Commission): Proposed Classification, if applicable: Signatum of regional office personnel: Date: gy INSTRUCTIONS TO ENGINEER I. Applicant (corporation, individual, or other): MARTIN MARIETTA CORPORATION 2. Nam and Complete Address of Engineering Firm: LAW _ENVIRON`MENTAL, INC. 4333 WILMONT ROAD, SUITE 300 City: ----CHARLOTTE--. State: NC Zip: 28208 Telephone No. 3. Project Name: EE BEET 4. Facility design flow TtGPD 5. Name of closest downslopo surface waters: L_0NG CIEEK 6. County(s) where project and surface waters are located: MECKLENBURG 7. Map name and dittv, AD-7.5 MIN, 1969. 8. North Carolina Professional Engineer's Registration No. 9. Print Name of Engineer MR. KEITH A. ANTHONY 10. See and Signature (specify date): "o' " CAqo V/", ENVIRONMENTALN. DIVISION OF A Asheville1 n 59 Woodfin Washington 'n 'u F 0 Box Raleigh Regional wQ Super. Asheville, NC 28802Washington. 1507 NC 27889 1)ra, Suite 10 1 7 1 2 9194 1 Ralcigh, NC 27609 919/733-2314 Avery n Buncombe Madison Beaufort Chatham Nash Burke McDowell Berde s>e' Camden Martin Durham Northampton MitchellCherokee hts ;Pamlico rn be Orange Polk Clay Ruthoerford Craven unPerson Currituck Franklin Granville Vance Graham Swain Perquimans Date Fitt Halifax Wake HaYWOW l Henderson yancyGreene 11 Johnston Wilson Jackson Washington Herdord Wayne Hyde Fayetteville a Super. " oil71 WaChovFayetteville, M00resville, Regional WQ Su 919 Nn its Wilmington Region. super NC 2S301 Mooresville, NC 28115127 Cardinal Drive Extension 91 /4 1541 / 5-1 99 Wilmington, NC 0 - S ` 919/395-3900Anson Moore Robeson Al"ander MecklenburgBladen Csbanus New+ yr Cumberland Richmond Rowan Catawba Stanly CmImet. Onslow Hamett e Sampsonl+ln Union Columbus ulin ntutxt Cleveland Lincoln Winston-Salem egi Super, 8025 North Point Boulevard,Suite 100 Winston-Salem, NC 27106 919/7 1-2 51 RockinghamAlamance Alleghany Randolph StokesAshe Caswell Suiry Davidson Watauga Davie Wilkes Forsyth n; Guilford 8 Of 1 LOW PRESSLTREIGRAVTI'Y Page Name and Complete Address of Engineering Fi m LAW ENVIRONMENTAL City.- CRARLOTTE State: NC Zip: 28208 «'rohssjonal Efioneer's Ceitificttion.. w �rw w r w . w � _w, .•. �w .� .w � w«,. w � w ws °• w. w M Applicant's Certification: attest that this application for MARTIN MARIETTA has been reviewed by tie and is accurate and complete to the best of my knowledge. 1 understand that if all required parts of this application are not completed and that if all required supporting information and attachments aTe not included, this application package will be retumed as incomplete. P /f . Signature _ � ateTHE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATEPJALS, SHOULD BE SEND' TO THE FOLLOWING NORTH CAROLINA; i i V MANAGEMENT WATER QUALITY SECTION PERMITS AND ENGINEERING UNIT POST OFFICE 512 NORTH SALISBURY STREET RALEIGH,NORTH CAROLINA 27626-0535 TELEPHONE NUMBER: 9191733-5083 1 LOW PRESSUREIGRANTrY Page 10 (41) PERMIT APPLICATION PROCESSING FEES (effective etber 1, 1 MODTICAMNS MODIRCATIONS 1 dtts $300 10,001 - 1 Industrial DomesWCoolingat 1 1,001 - 1, Industrial Domestic/Cooling Water, or = 1, Single Family Dwelling $4$120 Sludge < or = 300 Actes 4' Sludge > 300 Acres Sewer Extensions o dele Seweract sip (delegated) Closed -Loop Recycle Evaporativeor NOTE: The Fees for Soil Remediation Projects are the same as for Sludges. Underthe Sewer Extension Fee, "delegated tomunicipalities"' applies only to those governmental jurisdictions . that have specific delegation review tort , as granted by the Division of Environmental Management. 10 of 1 TABLE I TREATMENT/DISPOSAL SYSTEM FURR PROPERTY MECKLIMURG COUNTY, NORTH CAROLINA LE[ JOB .- Equipment Loading Rate (Q) Dimensions Volume Detention LxWxH Time t t Oil/Water t ft x 1.75 If x 1.42 ft 7.46 fe 14.63 min. Separator (0.51 fe/ in UV -Peroxide 3.8 gpm 3 ft x 4 ft x 5 ft 60 ft' 117.65 thin. Treatment Unit f Infiltration 3.8 glint 100 ft x 20 ft x 4 ft Gallery fete rest Oil/water separator: high level shut off switch Product storage high level shut off switch Equalization k:: low level shut off switch high level system on switch h high -high level shut off switch UV-P,eroxidation unit auto dialer is installed alarm and/or automatic system shutdown for flow conditions out of range alarm and shutdown on lamp failure alarm n lamp overheating alarm d shutdown n n reactor high temperature alarm d shutdown on UV access covers alarm when transmittance controller fails to operate alarm and shutdown, can lower air pressure 8 55 : .T1 ORIGIN,2.0 DESCRIPTION OF THE TYPE L TO BE TREATED AND WASTE ANALYSIS o property wasleased and operated as a gasoline service station. gasoline station ceased operations in ay 18. The generalsite location and site I shown on :figures respectively. Law Environmental (and previously Law Engineering) has been providing assessment services at the subject site since 1986. or r initiated following apparent leakage from underground gasoline and other petroleum product r piping at the site. The tanks have since been removed eight monitoring wells and; one recovery well have been installed on -site. The locations of the swells are shown on Figure 2. after several phases of assessment, the extent of petroleum contamination in ground water has been reasonably defined. Quarterly monitoring at selected wells has been conducted for almost two years. A summary of the most -recent test results indicating the presence of NME, Benzene, Toluene, Fthylb n ono, Chloride and Total Suspended Soli SS is shown on Table(Waste nalysis o proposed location of recovery wells RW-2 and R`W-3 are shown on Figure 2, if free product is present in any of the recovery ells, it will be separated from the ground water and recovered in the oillwater separator. Effluent from the oil/water separator will be discharged to an equalization,It to achieve a constant flow to a -Peroxide treatment system for volatile organic compound removal. Effluent from the UV-Peroxidetreatment will be reinjected into the underlying shallow aquifer via an infiltration gallery. The operational floe rate is not expected o exceed s 5- M TABLE 2 SUMMARY A" l A TES -MG FURR PROPERTY CIIARtMIE, NORTH CAROLINA LER 3 l.ab ratory tory Laboratory detection limit detection -1 MW- Mir"- M - - -6 -7 - Rom'- Parameter (n /l limit ( /1 (n /1 (Lt /1 (d /l) (n /l C /l� n /l ' �t fly (��1�/l (n€1/l ( /1) (MW-1, 2,, 3, , d 6, i°, Q).. —I a _. Date 1 /30/ 2 1 /3t / 2 1130/ 2 1 /3 / -2 1 /30/92 1 /30/ 1 /30/ 2 1 /301 2 1/30/92 MTBE 5.0 25 430 553 NOD 6.5 800 NTH 18 47 Ni 70 Benzene Lo 5.0 30.3 8A ND 1.3 160 Nib ND ND N1 60 Toluene 1,0 5,O 1.6 1.5 ND 3A Nip N13 NO Nib ND 1 Ethylbenzene Lo 5.0 11.3 L2 Nil ND 40 ND NOD ND NO 30 yl n , Total 2 10.0 24.7 O3 ND, 9,5 70 NOD ND ND ND 60 COD 5 mg1l 5 ni d, NA NA NA NA N.A NA NA NA NCB Chloride rid Oi 2 rngll 02 mg, /I NA NA NA NA NA NA. NA NA l l ntS/l TSS 111-mg/l 10 cell/l I NA NA, NA NA NA NA NA NA 490 K /l ND , Not detects above laboratory detection limit NA - Not analyzed *Constituent etmeentrations are based pan triplicate analyses for 141'? -la 'nie values in the table represent the average the standard deviation, TABLE 3 REMOVAL EFFICIENCY OFUV-PEROXIDATION FURR PROPERTY MECKLENBURG COUNTY, NORTH CAROLINA L1 JOB NO.56-8555-005 Influent Concentration Effluent Percent Removal Constituent (u /L) Concentration efficiency (u/L) Benzene 60 < 1 > 99.9 `toluene 1. < 1 > 99.9 Ethylbenzene 30 < 1 > 99.9 r 3 Recovery well (R d-1) data, from January 30, 1992, water sampling al s s. Laboratory and chain -of -custody records `are provided in Appendix 11. U -Pero i l Lion system is designed to remove above 99.9% for benzene, toluene, ethylbenzene and xylenes and above 93 for MTBE. 95s - .TI 3.0 FOLLOW-UP SITE MONITORING AND PLAN EVALUATION A monitoring program will be initiated after activation of the recovery and treatment systems to assess its effectiveness. The monitoring program will include: I. Quarterly field measurements of ground -water levels in the monitoring wells to verify the dimensions of the ground -water capture one. 2. Measurements of flow rate from the recovery wells to the treatment system to check the placement and efficiency of the recovery pumps, and measurements of the effluent flow to from the treatment system. The measurements will be performed in accordance with the requirements of the discharge permit. 3. Quarterly sampling and laboratory testing of ground water from selected plume perimeter and inside -perimeter monitoring wells to document recovery of the ground -water contamination plume. Laboratory testing will be performed for Class I petroleum -related ground -water contaminants, specifically benzene, ethyl benzene, toluene, xylenes, and MTBE. All parameters that show positive identification will be reported. The laboratory test will be performed using EPA Methods 601 and 602 or comparable documented methods; the report will include method detection limits. 4. Sampling of the water treatment system influent and effluent to document effectiveness of the system in removing the ground -water contaminants. The sampling will be performed for the parameters and at the frequency required by the non -discharge permit. The remediation program will be re-evaluated after each sampling and testing episode to monitor the effectiveness of the ground -water recovery system and of the water treatment system. Adjustments to the recovery pump flow rates and of the operation of the water treatment system likely will be necessary to obtain the optimum contaminant capture and contaminant removal efficiencies. 8555-AIMMO 3-1 4.0 SOILS AND HYDROGEOLOGIC: DESCRIPTIONS 4.1 Solis Description Three soil test borings, B-1, B-2 and B-3, were drilled at the site on May 16, 1991, to explore potential soil contamination in the vicinity of the previous kerosene -tank and gasoline -tank pit areas. These borings were drilled to depths of approximately 15 ft below the existing ground surface. The general subsurface conditions encountered in the borings are indicated in the Test Boring Records provided in Appendix 1. The locations of the borings are noted on Figure 2. Fill material was encountered at boring B-1 to near the termination depth of about 16.4 feet. Fill material extended to an approximate depth of 10 ft in borings B-2 and B-3. Alluvium was encountered beneath the fill material in those borings to a depth of 15 feet (termination depth). The fill material encountered consisted of sandy silts, silty sands and silty clays, The alluvium encountered in borings B-2 generally consisted of silty clay. The Test Boring Records represent our interpretation of soil, conditions at the borings based on our "animation of the soil samples. The lines designating the interfaces between the various strata represent approximate boundaries and the transition between strata may be gradual. Eight monitoring wells were also installed on -site. The general subsurface conditions encountered in the wells are illustrated in profile on Figure 5. The locations of the profile lines are shown on Figure 2. ' ^ ,''"' 4°1 ` 4.2 Hydrogeologic Description Inflow permeability tests were performed at wells MW- I and MW-3 to estimate the hydraulic conductivity of the formation materials exposed to the screened interval at each well location. Hydraulic conductivity (K) is a constant of proportionality relating to the ease of which fluid passes through a porous medium. Theflield procedure used to measure hydraulic conductivity is as follows: * measure the stabilized water level in the well: a remove water from the borehole by bailing; and # measure the ground -water level as it recovers to the static level. The data were reduced and saturated hydraulic conductivity of the screened interval was calculated using a computer program based on the variable -head method (NAVFAC DM-7. 1). The average horizontal saturated hydraulic conductivity (KO for MW-1 and MW-3 was determined to be 3.0 x 101 cm/sec (Report of Continued Assessment and Quarterly Sampling, dated July 19, 1991). The vertical permeability (Kj was estimated from the field horizontal saturated hydraulic conductivity data by employing the following ratio: 5: 1 = Kl,:K, (from Walton; Freeze and Cherry). The infiltration gallery design calculations using the above vertical and horizontal permeability are provided in Appendix 11 of this application. An average & value (1.8 x 10' ft/min) obtained from the Soil Conservation Service (SCS) data for Mecklenburg County was used to verify the estimated average K, value (1.2 x 10' ft/min). Although the values were not significantly different, the K, value obtained from SCS data was less conservative than the estimated value. Thus, the estimated K, was utilized in the design of the infiltration gallery. 8555-AIM,TIO 4-2 Water levels at this site were measured during the quarterly sampling episodes for about 3 years. The approximate depth to high water level at this site was found to be feet. soil evaluation of the site conducted by Mr. Fred Smith, a ails scientist with Law, is included in Section 6.0 of the Application. This comprehensive soil evaluation includes field descriptions of soil and hydrogeologic characteristics, d infiltration gallery recommendations. 8555-A M,TI 4- 1 ENGINEERINGla LAW GEOTECHNICAL, ENVIRONMENTAL CON TRUCT�ON MATERIALS CONSULTANTS March 31, 1992 Law Environmental P. 0. Box 240674 Charlotte, N.C. 28224-0674 Attention: mr. Chalam Pakala SUBJECT: LAW PURR PROPERTY ENGINEERINGLAW J' - " 1 Dear Mr. Pakala: Law Engineering had completed the soil testing and groundwater mounding l ulati a for the project described above. Our report includes our understanding of the preset; information, study methods, a description of the site and soils, the results of our testing and our recommendations for the design loading rate. We have appreciated bein r l to u in the exploration phase of this project and are re ar d to assist you further.if you have any questionsconcerning this is si ` or any of our testing, inspection, design_and consultingservices, l a e do not hesitate to contact Very truly yours ' 0; `r,�! w w.qt g# i LAW ENGINEERING .m r V I. t u �t5i' niA� d Zle, Fred D. Smith +�'yn may. y�,���yTM per, �pr� �Wl. i. 'w�rt ` P.E.i. .b�A Principal Soil ienti f Principal'°€ eot hn . al Engineer Certified No. 2312 Registered, N. C. 11285 FDS/BCH/pap Attachments 3301 <ATLANTIC AVE. P.OOX 18288 RAEEGH, NC 27619 91 .876-0416 Ak PROJECT INFORMATION � Vk ., results in sampling "ted i�aodrted to we compute an average transmissivitY of the aquifer to be 11.91, ft2/day using an aquifer thickness of 14 feet. We - calculated the maximumheight of the groundwater mound under the infiltration gallery using Recharge Groundwater Model. The Recharge l data r rcvi e n the Appendix. following parameters 0 a loading rate of .096 f / y 1 gallon/minute or 1,440 gallons/day), 91 ft d ' tran;� is iv / r depth to the bottom of the gallery of 4 feet low the existingsurface, depth to groundwater of 8 feet from the bottomof the gallery, the model lculate as maximum groundwater ound height of approximately 2.5 feet as shown in Drawing No. 3. CONCLUSIONS Based our soil evaluation and the results of the permeability tests, a expect treated groundwater to infiltrate the saprolite sails at a rate of 3x104 cm/sec and to percolate downwardto the groundwater aquifer. in addition, we expect e lateral movement of water in the unsaturated ne toward n Creek. The movement f treated water through the soil will provide additional treatment of the contaminated water. Increased rates of flow might be achievable if the actual saturated thickness is greater and/or if the actual transmia i ity is higher than the value used for tress calculations. s RECHARG TRANSMIS SPECIFIC BEGINNIFi FINA TIME INC TIME F C BEGINNING I FINAL DI DISTANCE IC STREAM 1 MOUND STREAM I TIME (DAYS), 5 5 5 5 5 5 5 5 5 %too %100 %100 %too %100 10 %100 %100 %150 %150 %am^'15 % V 150 %150 %150 15 %150 %200 pg: 420 %200 %200 %200 %200 %200 %200 %250 25 %250 RATE = . AY IVITY = 11.91 .FT Y YIELD = .15 TIME 50 DAYS TIME = 350 DAYS �EMENT = 50 DAYS 350 DAYS TANCE = 100 FT XMENT= 25 F DEPTH F WIDTH20 FT ,ENGTH = 100 FT DEGREES ;TANCE = 10 FEET t FIL YES YES DISTANCE HEIGHT FT FT 0 3.904 25 3.496 5 3.33 0 2.25 50 2.4' 75 0.843 75 1.264 100 Q. 100 0.742 4.464 25 4.019 25 4.252 50 2.630 50 3.220 75 1.127 75 1.943 100 0.000 100 1.265 0 4.741 25 4.255 25 4.555 50 2.914 50 3.43 75 1.224 5 2.251 100 0.000" 100 1.605 5.043 25 4.5�� 2 25 .04 50 3.017 so 3.2 75 1.277 75 2.355 100 0.000 100 1.671 _ 5.13 25 4.15 25 5.15 %250 __ 5=" 3 %250 50 3.74 %250 75 1.31 %250 75 2.489 %250 100 0.000 %250 100 1.800 ,%300 0 5.247 %300 25 , 4.681 %300 25" 5.115 %300 50 3.129 %300 50 4.027 %300 75 ` 1.,334' %300 75 2.593 %300 100 0.000 %300 100 1.`'91 %350 0 5.31 %350 25, 4.3' %350 25 5.19 %350 50 3.162 %350 50 4.111 %350 75 1.351 %-350 75 2.5 %350 100 0.000 %350 100 1.984 DISCHARGEO STREAM DISTANCE5 GEC ALONG1 STREAM 1 FOOT LENGTH (FT) T . . /DAY) 50 DAYS 0.0342 .4 5 0.0338 0.4 10 0.0333 0.4 20 0.0309 0.4 40 0.0246 0.3 so 0.0120 0.1 160 0.0000 0.0 DISCHARGETOTAL +5.7772+1 CUBIC FT./DAY 100 DAB' 4 0.0430 .5 5 0.0426 0.5< 10 0.0420 0.5 20 0.0395 0.5 40 0.0325 o.4 0 0.0181 0.2 160 0.0054 0.1 320 0.0000 0.0 TOTAL DISCHARGE= +9.3 10 + 1 CUBIC FT./DAY 150 DAYS 0 0.0470 0. 5 0.0465 0. 10 0.0459 0. 20 0.044 0.; 40 0..062, 0.4 0 0.0214 0. 160 0.0000 0.; TOTAL DISC 8.85680E+01 CUBIC FT./DAY 200 DAYS 0 0..041 0.6 5 0.0457 0. 10> 0.0481 0.6 20 0.0455 0. 40 0.0383 0.5 so 0.024 0. 160 0.0077 0.1_ 20 0.0008 0. 640 0.0000 0. TOTAL DISC 1.21161 02 CUBIC FT./DAY' 250 DAYS 6 0.0505 0.6 5 0.0501 0.6 10 0.044 0. 20 0.0469 0.' 40 0.07 0.5 0 0.024 0. 160 0.0087 0.1 20 0.0019 0. 640 0.0000 0.0 TOTAL + I DISCHARGE -�1:.56_ 02 . AY 00 DAPS 0 0.0514 0.6 0.0510 0. 10 0.0504 0.6 20, 0.047 0.6 40 0.0406 0.5 80- 0.0255 0. 160 0.0094 0.1 20 0.002`6 0. 640 0.0000 0. TOTAL DISC = +1.42 86 02 CUBIC FT./DAY 350 DAYS 0 0.0521 0.6 5 0.0517 0.6 RECHARGE.13 FT/DAY TRANSMISSIVITY= 11.91 . F AY SPECIFIC YIELD = .15 BEGINNING I 0 DAYS FINAL TIME 350 DAYS TIME INCREMENT = 50 DAYS TIME OF CUT OFF = 350 DAYS BEGINNING DISTANCE FINAL I 100 FT DISTANCEINCREMENT = 25 FT F WIDTH20 F' LENGTH100 F , ANGLE0 DEGREES STREAM DISTANCE = 100 FEET MOUNDPROFILE F STREAM DISCHARGE YES TIME DISTANCEHEIGHT (DAYS) ) FT 50 0 5.274 50 25 4.71 so 25 4.905 50 50 3.046 50 5o 3.369 so 75 1.13 50 75 1.70E so 100 0.00 50 100 1.001 %loo %loo 25 5.426 %loo 25 5.740 %100 50 3.551 %100 50_ 4.347 *100 75 1.521 too 75 2.623 %100 100 0.000 l q 100 1.70 %150 0 5.400 150 25 5.745 %150 25 6.149 %150 50 3.933 %150 50 4.641 tiso 75' 1.52 %150 75 3.080 %150 100 2.166 %2,006.807 %200 25 5.11 %200 25 6.399 %200 50 4.073 %200 50 4.86 %200 75 1.724 %200 75 3.17 ,%200 1 %200 100 2.255 %250 0 6.7 %250 25 6.3 %250 25 6.772 %250 50 4.162 ,%250 50 - 5.081 %250 75 1.77 %250 75 3.36 %250 100 0.000 %2 100 2.43 %300 0 7.4 %300 25 6.31 %300 25 6.906 %300 50 4.224 %300 50 5.436 %300 75 3.501 %300 100 0.000 %300 100 2.566 350 0 7..16 -%350 25 6.385 %350 25 76 %350 50 4.26 %350 50 5.54 -%350 75 1..624 %350 75 3.847 %350 100 0.000 %350 100 267 DISCHARGE TO STREAM DISTANCE5 GEC ALONG AT T STREAM 1 FOOT ZIT " FT ( Y )' 50 DAYS 0.0462 0.6 .456 0.5 10 0.0449.5 20 0.0417 0.5 40 0.0332 80 0.0162 o.2 160 0.0000. TOTAL DISC = +7.798E+ 1 CUBIC FT./DAY 100 DAYS 0.0581 0.7 5 0.0575 0.7 10 0.0567 0.7 20 0.0533 o.6 40 0 0438 0.5' 80 0.0244 0.>' 160 0.0073 0.1 320 00000 0. TOTAL DISCHARGE+1. 2663 +0 CUBICFT./DAY 150 DAYS .0634 0. 5 0.0628 0. 10 0.060 0.7 20 0.0585 0.7 40 0.0489 0. 80 0.0289 0.3 160 0.0000 0. TOTALDISC - 1.15 +02 CUBIC FT./DAY 200 DAYS 0 0.0663 0. 5 0.0657 0.8 10 0.0649 0.8 20 0.0614 0.7 40- 0.0518 0.6 0 0.0315 0.4_ 160` 0.0104 0.1 320 0.0011. 0.0 640" 0.0000 0.0 TOTAL DISCHARGE = +1.. 15 1 +0 OFT./DAY 250 DAYS 0 0.0681 0. 5 0.0676, 0. 10 0.0667 0. 20" 0.0633 0. 40 0.0536 0. 80 0.0332 0.4 160 0.0117 0.1 320 0.0025 0.0 640, .0000 0.0 TOTALDISCHARGE +1 .80334 +02 CUBIC FT./DAY 300 DAYS 0 0.0694 0. 5 0.0688 0. 10' 0.0680 0. 20 0.0645 0. 40 0.0548 0. 0; 0.0344 0.4 160 0.016 0. 1 ar 1 t d r " I „e-�..,.,w �.� p +, a � '� � ,,`, ate, S�"m •���' "� �" , � "� * �cp to y M: (d"a�"`t"`-�.a� �, , � "`e� �, ea � ��w�. � `� � ��w P°x�,j •q � � '"• pr � R_..,�� 't �, �, ......" ''� . °tea.. `��' < '`�`*'„a w. a ° *�°" ' y �"-•� r .�'.' � s,.,,,�,,.. `wM r^ p°.="'\.r� tit '� '�� � �`'ae"`: '�a ��� ��"" ,•. j' e! t.. }r y V _ R OWN wrwwuuw CHARLOTTE,LAW ENVIRONMENTAL, INC. SITE LOCAMM MAP 11W 409 w 944MM FIGURE i ui G h TABLE10 GROUND-WATERLAW I E I PROPERTYFURR L I LI N CHARLOTTE, NORTLI DRAWN.- ENGCiEC FEB. 1 : °i 4- -1 `T : SCALE: NOT TO SCALE DWG: 3 EE E E: FIELD NOTES CompactThe can t ` r developed to measure the saturatedhydraulic conductivity (R.) of the v do (unsaturated) zone. The instrument determines utilizing per techniques su the shallow well n method, borehole t r, or borehole infiltration test. Thesemethods are describedin many publications including it Analysis" published by the aerie oci ty of Agronomy. The ccHP measures -to a depth of two teas below the soil surface. Measurementdepth can be increased y additional sets of constant head tubes and a portablepressure measuring device. The measures the in - situ K, of a soil layer by creating constant n head of water at the selected s th of measurement by a series of pressure regulatingl of water called constant head tubes. Basedon a steady state flow rate from e cylindrical auger hole under a constant head of water, the Glover solution can be used to calculateKsat. The tion is Ksat flow of water The Glover solution sn n the depth of water in the hole ( � the radius of the hole(r) , and thesteady tad flow rat ( . 1 PROCEDURE . Select the landscape where e` ur f Y.. is desired. » Describe the soil profile. » Bore a 6-cm diameter hole to desired » Plane andclean the bottom of the augerl i the n laver» 5. Measure and recordthe distancechole to LEVELthe REFERENCE on the permeameter. . Connect the constant head tubesit tubes as directed the manual and turn the eameter on to fill; the hole it water. 7. Allow the permeameter to achieveconstant of t r i the hole. This providesto i ; of the it at the depth measured.to be Start8. nt of flow rates to determineif steadystate conditions hav en accomplished. 9. After t .nin three steady flow rates, a r nrecord the depthwater in the cl . 10Record all field ata and calculate K» TECHNICAL SPECIFICATIONS AND MANUFACTURER'S LITERATURE GROUND -WATER RECOVERY/TREATMENT SYSTEM AT FURR PROPERTY MECKLENBURG COUNTY, NORTH CAROLINA FOR MARTIN MARIETTA CORPORATION LITTLETON, COLORADO '00'04 11 Ro j /6k tssfo s % Al APRIL 1992 427G i N A .. tilt, 04,41soolit' OWNER: MARTIN MARIETTA CORPORATION ENGINEER: LAW ENVIRONMENTAL, INC. 4333 WILMONT ROAD, SUITE 300 CHARLOTTE, NORTH CAROLINA 28217 LEI JOB NO. 568655005 CONSIRUCnON SPECIFICAnONS MIO Stttnm� 4 Work The scope of work includes trenching, furnishing and installing subgrade PVC piping and associated fittings, including unions and valves, installing recovery vaultsfor the ground water recovery system, and installing treatment system equipment on the pad including mechanical and electrical hook-up. Also included are steel piping inside the building among treatment system components. The treatment system equipment is to be connected to 2-inch PVC total fluids and discharge pipes described on Drawing 2 of 3. The connection between the recovery system (PVC pipes) and the treatment system components (steel pipe) is the responsibility of the contractor, Future work (not included in this contract) includes connecting pneumatic ground -water pump system to control panel and air compressor and installing pneumatic hose and regulator for air lift. Law Environmental will furnish the following treatment system equipment components: a 5-hp air compressor, an oil/water separator, a product storage tank, an equalization tank, a UV -Peroxide unit, a hydrogen peroxide storage tank, transfer pumps, vaults, a flow meter, an air conditioning unit, a heater, and a vent fan. The contractor will be responsible for posting local permits necessary to perform the work. Permits required by the North Carolina Division of Environmental Management (NCDEM) Authorization -to -Construct and non -discharge will be provided by the owner. Soil sampling and testing will be performed by a qualified testing contractor. Costs for testing are to be borne by the Contractor. Copies of the test results will be forwarded to Law Environmental. Based on the test results, Law will either accept or reject the work. Temporary electrical power, water and sanitation facilities will be the responsibility of the Contractor. Security of Contractor's equipment and tools will also be the responsibility of the Contractor. Upon completion and final acceptance of the work by the Field Representative, the Contractor shall clean the work area to match preexisting conditions. DIMION 2: SITEWORK 02100 Site Prepa-Ation PULL__QLnZBI This section includes utility locating and trench lay -out, for the recovery system. SM.FMCON&SM p —PrQdugcU Not applicable. _' ut .1. Contact a utility locating service. Locations of underground utilities must be clearly marked prior to initiation of trenching activities. 3.2 Lay out proposed nches from recovery wells to the treatment system pad. 10 Piping Fittings :part 1 dnc This section includes installation of PVC pipes and conduits in the trench but not inside of the building 1.1 Comply with all laws, ordinances, codes, rules and regulations of local, stud and federal authorities having jurisdiction; over any of the work specified herein. RMLZ_PIMQcts .1; Pipes, and fittings for ®inch hose conduits, -inch total fluids pipe and -inch PVC discharge pipe shall be Schedule 40 Type 1 Grade 1 PVC and shall be pressure rated. 4-inch hose conduits shall include "sweep" DWV fittings. 2.2 The vaults shall be provided by owner: 2.3 Concrete used for the s' urexent of recovery well vaults shall consist of Type I Portland -cement concrete, minimum 3000 PSI compressive strength at 28 days. Part.3 E uiifon 3.1 The contractor responsible for this performance shall employ personnel who have been qualifiedy training and experience for executing this Work. 3.2 Piping shall be aligned, connected, and properly supported. Install piping in longest practical lengths, avoiding insofar as possible the use of short lengths and couplings, Remove scale, dirt, grease, oil and debris from all pipes before installation. Pipe connections shall be properly primed and glued with PVC cement. Construct pipelines with as fear joints as possible. Piping shall stub -up into vaults as shown on drains. Cap or plug open ends of all pipes and valves until final connections are made.; .3 Ropes to be used later to pull hoses for pneumatic ground -water pumps will be installed in the -inch diameter hose conduits Enos of ropes will be tied off to stub -ups inside e recovery well vaults and on the treatment system equipment pad. s ms 3.4 Backfill, trench with compacted crushed stone for pipe bedding. 3.5 Upon completion of the 2-inch to fluids pipe installation, a 75 psi pressure test shall be conducted as directed by the Law Environmental representative before the trench is backfilled. Seal ends of PVC pipes in vaults with duct tape. 3.6 Recovery well vaults and covers shall be installed as shown on drawings, 17 Exterior steel surfaces which will be in contact with grout shall be coated with a grouting adhesive. 3.8 Clean crushed stone shall be placed in a 2-inch layer at the base of the vault excavation. 3.9 Portland -cement concrete shall be placed at the sides of the excavation to the top of the vault. The concrete around the vault shall be at least 4 inches thick. Taper concrete down away from vault to drain away surface water. 4,0 Concrete used in vaults shall be kept moist by spraying or by covering with moist burlap or plastic for at least 14 days after initial placement. The finished concrete surface shall be level with a smooth surface. 4.1 An additional 2-inch layer of crushed stone shall be placed at the base of the vault. DWISIGN 11: EQUIPM[ENT 11300 Fluid Waste Treatment and Dispo&-d Equipment Part I General L)= 2 ErQd= 2.1 Four (4) 2-inch x 2-inch x 1/4-inch thick angle steel tabs for anchoring UV -Peroxide unit, 12 Twelve (12) Phillips Red -Head Self -Drilling Anchors A307 to equivalent) with single cone expander made from heat treated steel. 2.3 Two (2) 2-inch steel valves. 2.4 Two (2) 3/4-inch steel spigots. 2.5 One-way flap -type check valve for horizontal installation. SMFURRCONSAM 2.6 Two (2) 1/4-inch mate -threaded hose barbs for air lifts. Part 3 Engution 3.1 Position air compressor, oil/water separator, product storage tank, equalization tank and UV -Peroxide treatment unit as shown on Drawing 3. 3.2 Weld anchor tabs on frame of UV -Peroxide unit. 3.3 Shim up and level UV -Peroxide unit before anchoring. 3.4 Anchor air compressor, product storage tank, equalization tank, and UV -Peroxide treatment unit to equipment pad. A. Anchors shall have: It diameter = 3/8-inch Anchor diameter = 9/16-inch Minimum embedded depth = 1.5-inch B. Anchors shall be used as drill bit and holes should be drilled until chuck holder is flush with the surface. C. The anchor hole shall be cleaned of loose material. D. Plug shall be inserted in the anchor. E. Anchor shall be expanded by inserting it into hole and driving it in until the chuck holder is flush with the top of the concrete. F. Equipment shall be bolted to complete the anchoring work. 3.5 Install air lift "wye" connection on the influent and effluent pipe of oil/water separator as shown on Drawing 3. Install 2-inch x 1/4-inch bushing with 1/4-inch female threads. Install 1/4-inch threaded hose barb in 1/4-inch threaded bushing. 3.6 Install flow meter using neoprene boots for ease of disconnecting flow meter for cleaning and servicing. Connections are to be located 1-foot from both sides of the flow meter. 11370 Compm=rs Part I General Installation of air compressor. Part 2 Prodg-cla 2.1 Air system shall have: A. Air supply tubing: Nylon UV protected, 1/2". B. Logic tubing: 1/4" nylon UV protected. CLevel controller: QED or equivalent Well Master Level Controller. D. Main controller: QED or equivalent Pulse Sender Main Controller. E. Remote Well Operator: QED 2" or equivalent Remote Well Operator. SM-FMCOM-sm FAII-I—En"tLM .1 Install air supply components in accordance with manufacturer's instructions. II FAr1j--Q0z9 Installation of oil/water separator unit. p Iruets 2.1 AFL Industries Vertical Tube Coalescingfor 5 gpm.. A. Flow Capacity: 5 gpm. power source required. C. EquipmentEnvelope: old corrosion -resistant fiberglass. . Equipment Dimension: ' - J " long by I'+- wide by IA - 511 " high. 2.2 Flow Failsate Features. A. Provide automatic system shutdown for flow conditions out of .' high level shut off switch. 2.3 piping. A. Inlet: M flanged. B. Outlet: " C. OilOutlet: " flanged. .4 Stage for oil/water separator. A. Concrete blocks, d mortar. I' 3.1 Performe Work in accordance with applicable local, state and federal codes, latest editions. 3.2 Install treatment unit in complete accordance th e manufacturer's instructions. 3.3 Construct a '-5" tall stage for the oil/water separator using concrete blocks and mortar. ,4 Provide all required connections indicated on the Drawings. 3.5 Protect Work from theft, vandalism and unauthorized entry throughout the construction period. S 11337 ua a La-qj--D&nsnj Installation of 'Equalization Tank. 2.1 Delta CoolingTowers Storage Tank. StorageA. K 500 gpm. B. Equipment Envelope: polyethylene: C. Equipment Dimension: 4' - " diameter, ' - 3" height. 2.2 Flora Failsafe to A. Provide automatic system shutdown for floc conditions out of g low level shutoff switch, high level turn on switch, and high -high hovel shutoff switch. 2.3 Piping. A. Inlet: 3'" fi B. Outlet: 3" flanged. C. Overflow: " flanged. Drain:D. 2" Hang Part 3 Ex=lfio 3.1 Perform or in accordance with all applicable local, state and federal codes, latest editions. 3.2 Install treatment unit in complete accordance with themanufacturer's instructions. 3.3 Provide all required connections indicated on the Drawings.:' 3.4 Protect t or :from theft, vandalism and unauthorized entry throughout the construction 11377 UV -Peroxide Treatment Systetn F Installation of UV -Peroxide treatment systems. RW12--PBQd= 2.1 Rayox System, Model101-1 1. A. Flow Capacity: 3.8 gallons per minute. B. Pipe Diameter: 3 4" 316L stainless steel, Schedule 10 C. Netted Materials: 316 or 31 L stainless steel, quartz, t flon, viton. SM.PMRCONSAM D. Sample Points: Provide sample port on system discharge line. E. Hydraulic System Pressure Requirements: 25 psig. F. UV Reactor: One 4 kw Sol them Lamp, UV shielded, with high temperature shutdown. G. Transmittance Controller: Pneumatic drive with adjustable action cycle. Controller to have automatic action for cleaning UV reactor quartz sleeve. H. Hydrogen Peroxide System: Capable of providing 35% hydrogen peroxide at a flow rate of 4 gallons per day. 1. Equipment Envelope: 3 feet wide by 4 feet long by 5 feet high. J. Sldd Material: Structural steel with acid wash primer chemical resistant enamel paint. 2.2 High Voltage System. A. Enclosure: NEMA 1, ventilated, drip proof. B. 480 VAC. C. One 4 kw lamp power supply. D. 480/120 VAC transformer. E. Power Factor: Better than 0.9 at 2.3 Low Voltage Control System. A. 120 VAC, 24 VDC, NEMA 12 enclosure. 2.4 System and Process Control. A. Provide system control via programmable logic controller by Texas Instruments. B. Fault Annunciator: Message system on control panel C. Temperature: Reactor high temperature switches. 2.5 Flow Failsafe Features. A. Provide alarm and/or automatic system shutdown for flow conditions out of range. 2.6 Lamp Failsafe Features. A. Provide alarm and shutdown on lamp failure. B. Provide alarm on lamp overheating. C. Provide power interlock on HV cabinet door. D. Provide alarm and shutdown on reactor high temperature. E. Provide alarm and shutdown on LTV access covers. 2.7 Transmittance Controller Failsafe Features. A. Provide alarm on failure to operate. B. Provide alarm and shutdown on low air pressure. 18 Feed Pump. A. Capable of delivering I to 5 USGPM. SM-FURRCOMAM 2.9 Piping. A. Inlet: 3/4" flanged. B. Outlet: 3/4" flanged. Part 3 EXWdM 3.1 Perform the Work in accordance with all applicable local, state and federal codes, latest editions. 3.2 Install treatment unit in complete accordance with the manufacturer's instructions. 3.3 Provide all required connections indicated on the Drawings. 3.4 Protect Work from theft, vandalism and unauthorized entry throughout the construction period- DIMION It ME.CFUMCAL 15050 Basic Mechanical Materials and Methods Bart-L—fkllml This section includes installation of steel piping between treatment system components, installation of steel piping for the exposed influent and discharge pipes including steel/PVC connection in the ground outside the treatment system building, and installation of valves, spigots, air lifts and flow meters. Part 2 g[Qdj= 2.1 All pipes and fittings inside the building shall be steel. 12 Steel union joints, check valves and other valves are the responsibility of the contractor. 2.3 All steel pipes shall be threaded. RaA2--E—XM1l1ffl 11 3.2 All steel piping shall be aligned, connected and properly supported. No sharp bends or elbows shall be used at the change of direction, instead long 900 sweeps shall be used. Steel union joints shall be installed on either end of the treatment system components. SM-YU"CONSAM DIVISIONI: ELECIRICAL Distribution16400 Service and Part l jat& Is section applies to installation, and hook-up of electrical power to treatment system control panel located inside the .1 Contractor shall furnish Pratt hour meter bass and switch capable of 120/480 VAC, single phase/three phase100 amp application. Products and workmanship shall meet or exceed NEC or local codes (the strictest code shall apply). Part 3 `Q .1 Install a main disconnect switch under'the watt hour meter. Switch shall be housed In heavy duty outdoor elosu i identifiable lever switch to controlon/off status from the outside. . s l a watt hour meter base to existing electric pole. 3.2 Hook up electrical to each system neat as specified in the manufacturers specifications. TMSOLO is an intelligent,h igh -rate pneumatic mp for total OU Js applications. It runs itself,with an internal float system and a magnetic "brain"cartridge. The brain senses liquid level in the pump, turning the air supply on when the pump is full,and turning s off as soon as the pump empties. With its bulk- in za brain, SOLO doesn't require air cycle or ` -tiff level control at the well heed, simplifying system design. AJI you need above the well cap is a compact air filter/speed control. SOLO is easy to Install -just nun air to each well. Continued operation is truly hands-off.SOLO constantly reacts to changes in well recovery rate, so Ws always pumping t the highest rate possible. It also shuts down automatically ter in the well drops below pumping l a SOLO requires a minimum of 3.5 feet of liquid in order to pump.) because cycling is controlled at the pump, SOLO is either refilling or discharging of the time. `here's no waiting between active phases of the cycle for the entire length of air supply tubing to re -pressurize. This operating efficiency enables SOLO to delver pumping rates of up to 6 gallons per minute while also saving on air supply requirements. The pumping mechanism in SOLO uses the same high-dearance design that has made PULSE FRUMP the standard for field performance without clogging or breakdowns. All parts, including the magnetic brain cartridge, are rated for at least 5,000,000 cycles and are field-replacable if necessary. TABLE OF CONTENTS_ GE 2. HOW SOLO WORKS 2 3. INSTALLATION A. HOSE/TUBING ATTACHMENT TO TOP OF PUMP-,-----,- 3 B. CAP AND TUBING/HOSE: 1. PUMPS WITH ALL NYLON TUBING -4 ;. PUMPS WITH HOSES AND NYLON TUBING,- 5 HOW THE SOLO PUMP WORKS E SOLO PUMP REQUIRES A MINIMUM OF . ' F LIQUID TO PUMP. THE SOLO PUMP AUTOMATICALLY SHINS OFF WHEN THE LIQUID LEVEL IS PUMPED DOWN. E THE SILO PUMP WILL AUTOMATICALLY BEGIN PUMPING AGAIN ONCE WELL LEVEL HAS RE O EREI TOP CHECK ... BALL r iNITI aL STATIC j .- •+ { � 4 AIRPORTAL r yy "�'g-�'g WATER E:::t-i LEVEL t"1fEi 1"� L:✓I-iTTi.,: } HERE CAR HIGHER PUMP � „^ DILL TUBE FLOAT WITH PUMP FULL. FLO AT IN THIS POSITION SLICES THE ACTUATOR ROD UPWARD CAUSING AIR TO ENTER THE PUMP. THE AIR PRESSURE FORCES ITHE INLET CHECK BALL TO SEAT KEEPING ANY MORE LIQUID FROM ENTERING THE PUMP. THE LIQUID IN THE PUMP'S BODY IS EN FORCED INTO THE PUMP'S PILL TUBE AND UP THE II; fl DISCHARGE LIFE TO THE SURFACE. THE TOP CHECK BALL IS I 1 UNSEATED BY THE UPWARD FORCE OF THE DISCHARGED LIQUID, ACTUATOR ROD FLOAT WITH PUMP EMPTY FLOAT AT IN IS POSITION SLIDES ACTUATOR ROD DOWNWARD ALLOWING THECOMPRESSED AIR IN THE PUMP TO VENT. THE INLET CHECK BALL UNSEATS (NO LONGER HAVING ANY AIR AIR PRESSURE HOLDING IT DO N ) WHICH ALLOWS THE NEXT VOLUME OF LIQUIDIN THE WELL INTO THE PUMP. AS THE LIQUID REFILLS THE PUMP THE FLOAT RISES BACK LIP INTO THE POSITION MENTIONED ABOVE AND THE PUMPING PROCESS IS REPEATED. THE TOP CHECK BALL IS SEATED BY THE WEIGHT F ANY LIQUID IN THE DISCHARGE E LINE ABOVE IT PREVENTING THAT LIQUID FROM RE-ENTERINGTHE PUMP BODY, INLET CHECK BALL PUMP INLEr HOSE/TUBING ATTACHMENTS TO TOP OF SOLO PUMP PUMP DISCHARGE FITTING BRAIN EXHAUST FITTING PUSH HOSEj FLJ81NG DOWNIO -nitsb BARB PUSH ENOAG& TUBING DOWN MENT (MINIMUM) FLUSH WITI 4 TH8 VillINGS NUT CLAMP t I PLACEMENT Pu Mp EXHAust lFif TING PUMP D[S�NAAOE 01 �CLAMP 1 1 V I I EYELET HOLE FOR ROPE ATTACHMENT PUMP EXHAUST FITTING PUMP AIR SUPPLY PUSH HOSE1 FLUSH WITH THE FITTJN6rs PUMP AIR SOPPLY CLAMP --, I PLACEMENT 413ARBS (TAPERED) 713AR1ST APER ED) 3 BARBSHAPERED) -AMPS PLACE CLAMP TOOL OVER THE DIMPLED EAR PORTION OFTI-IE CLAMP AND SQUEEZE EAR TOGETHER { AS SHOWN BELOW), A B A. CLAMP IN CLOSED POSITION B. CLAMP IN OPEN POSITION ALL NYLON TUBING 496, 8" CAPS 18 LOWER PUMP TO DESIREDDEPTH. . ICI ww DETER- MINED, MEASURE OFF APPROXIMATELY OF TUBING LENGTH PUMP TOP OF WELL CASING) FROM BOTH THE EXHAUSTLINE BRAIN DEFLECTOREXHAUSTLINE.* 3. CUT BOTH I 4. ATTACH THE PUMP EXHAUST DEFLECTOR : CLAMP TO THE PUMP EXHAUST LINE. FOR CLAMP INSTRUCTIONS) . TIE STRAP ALL TUBING INTO ,qq ,p^�. PUMP p P DISCHARGE {7 � LONE I TLC w. " BELOW WHERE YOU CLIP` OFF YOUR EXHAUST LINES. 6. PASS PUMP DISCHARGE AND .D. PUMP AIR SUPPLY AIR SUPPLY LINES THE WELL . T 7. RE -ADJUST DESIRED DEPTH. 1 8. I LL I I / " .5 . PUMP EXHAUST DOWN ONTO AIR/DISCHARG LINES. NOTE: EXHAUST TUBING OUTLETS SHMD BE LOCATED AO . V BELOW WELL CAP OR IN A TOPMEW PUMP LOCATION CIt TO THE AIR CAP BB THEY WU NOT BECOME SLINE UBMERGED- w PLUG (PROBE HOLE) t DISCHARGE LINE IP ----------- Itom all At 12 ZAN rMixt-i KIM" HOSE& 04000F spi0o" TUSIUG SPOT SPIDOT Pulse Pump -) D Environmental Systems, Inc, (QED) warrants to the original purchaser of lis products that, subject to the limitations and conditions provided below, the products, materials and/or 'workmanship shall' reasonably conform to descriptions of the products and shall be free of defects in materials and workmanship. Any failure of the products to conform to this warranty will be remedied by QED in the manner provided herein, This warranty shall be limited to the duration and the conditions set forth below. All warranty durations are calculated from the original date of purchase. t , Liquid uid contacting equipment (including pumps), tubing; liquid contacting supplies and Ilow totali ation equipment are warranted for t year; . Control devices, control device mounting, and surface air supply hose are warranted l for t year. i Separately sold parts and spare parts hits are warranted for ninety ff days. 4. Repairs performed by QED are warranted i for ninety f days from date of repair or for :ire full terra of the original warranty, wnioliever is longer. r Buyer's exclusive remedy for breach of said warranty shall be as follows: if, and only if, QED is notified in writing within the :applicable warranty period of the existence of any such defects in the said products„ and QED upon examination of any such defects, shall find the same to be within the terra of i and covered by the warranty running from QED to Buyer, QED will, at its option, as soon as reasonably possible, replace or !ny such product, without charge tuyer. If CE for are reason, cannot repair TM Warranty ra product covered hereby within four f weeks after receipt of the original Pur- chaser'sl uyer's notification of a wairranty claim, then Et 's sole responsibility shall be, at its option, either to replace the detective product with za comparable new unit at no charge to the Buyer, or to refund the full purchase price. In no event shall such allegedly detective products be returned to QED without its consent, and C Ef 's obligations of repair, replacement or refund are conditioned upon the Buyers return of the defective product to QED. IN NO EVENT SMALLCOED ENVIRONMENTAL T, L ,Y TE@ , ENC. BE LIABLE FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES FOR B EA IA iF SAID WARRANTY. The foregoing warranty does not apply to major subassemblies and other equipment, accessories, and other parts manufactured by others, and such other parts, accessories, and equipment are subject only to the warranties, it any, supplied by their respective manufacturers. QED makes no warranty concerning products or accessories not manufactured, by QED. In the event of failure of any such product or accessory, QED will dive reasonable assistance to Buyer in obtaining from the respective manufacturer whatever adjustment cs reasonable in light of the manufacturer's oven warranty. THE FOREGOING WARRANTY IS IN LIEN F ALL OTHER WARRANTIES, TIE: ,. EXPRESSED, IMPLIED OR STATUTORY (INCLUDING BUT NOT LIMITED TO THE WARRANTIES OF MERCHANTABILITY ' AN FITNESS FOR A PARTICULAR PURPOSE), WHICH OTHER WARRANTIES ARE EXPRESSLY EXCLUDED HEREBY, Y, and of any other obligations or liabilities on the part of QED, and QED neither assumes nor r authorizes any person to assume for it any other obligation or liability in connection with said products, materials and/or workman- ship. aship. It is understood and agreed that QED shelf in no event be liable for incidental or cdnse- gUential damages resulting from its breach. f any of the terms of this agreement, nor for special damages, nor for improper selection of any product described or referred to for particular application This warranty will be void in the event of unauthorized disassembly of component assemblies. Defects in any equipment that result from abuse, operation in any manner outside the recommended procedures, use and applications other than for intended use, or exposure to chemical or physical environ- ment beyond the designated' limits of materials and cuntruction will also void this warranty. Chemical attack to liquid contacting equip- ment and supplies shall not be covered by this warranty. A range of materials is avai- lable from QED and it is [lie Buyer's respon- sibility to select materials to fit the Buyer's application, QED will only warrant that the supplied liquid contacting materials will conform to published f. specifications and generally accepted standards for that particular material. D shall be released from all obligations under all warranties if any product covered hereby is repaired or modified by persons other than Q 's service "personnel unless such repair by others is made with the writ- len consent of QED. If any product covered hereby is actually defective within (lie terms of this warranty, Purchaser must contact Vnasknng •Sga1 QED for determination of warranty coverage. If the return of a component is determined to be 'necessary, QED will authorize the return, of the component, at owner's expense, if the product proves not to be defective within tale terms of this warranty, then all costs and ex- penses in connection with the; processing of the Purchaser's claims and all costs for repair, parts and labor as authorized by owner hereunder shall be borne by the Purchaser. The original Purchaser's sole responsibility in the instance of a warranty claim shalt be to notify QED of the defect, malfunction, ' or other manner in which the terms of this war- ranty are believed to be violated. You may secure performance of obligations here- i under by contacting the Customer Service Department of QEDand: 1 Identifying the product involy d by model or serial number or other sufficient descrip- tion that will allow QEDAo determine which product is defective. 2. Specifying where, when, and from whom the product was purchased. 3. Describing the nature of the defect o malfunction covered by this warranty. a Sending' the malfunctioning component, after authorization by QED to D Environmental Systems Inc. 6155 Jackson load Aran arbor, MI51 g Telephone: 1-313-995-2547 -tl-S-5 1-51 - .5-g g (Canada) 1- 1 d®g 5--11(Fax) Environmental QED Systems, Inc., RO, Box 3726, Ann Mar, MI 48106 3001624 -2026 In McJiizg n, 3131 - 547 In Canada, 5 M85-0290 2 Fax 0 313/995.1173 SELM- JUI IM + w 1 V M � P VIRP-'S spwlAL 1Sb i 1 TRANSFill fi P _._ eL ;tllllllAAEtl0ll I t4fA � .:NEMAI 4�OH --- -M Aip— S-rm,ppeiz Fil NT � I n , y iv � mt#aw♦y, 1#wRJA - sw��#fix 551 ilviz TRANsFR pumpIr e R(OprtOWAL) OPTIONAL) L AND kS5eM5Ly LIS"I'l 4'lj c L V Z- a all "Ott to I--% w.j 00 th. ­J'. F41 T.T.t bffl* 0'--x Pr molt. 0--i -wl~t A motor, #tot 01—of t ..It, I Ot -X-tl- bfol. Vlo" 4*4 "J( oo� '#jtrjgA tot a G.: , t —4, 1, Aft, co#wWotloot to bqti # too as.* 0.4 t.#t,~ tt of#** 9, 1" 0 all OfOO .:th 01.4 It '04,41 to W" 0#10.0 I-Oiov 000 "A 01014. I DtAant 'Z IN" Ik fittoo tt* wk. 40 PM of"� 14" Is C"Stettd of IN 0-094d St.$* Wood Ift ISAVAIRAlft motic O"ratlo, l000 lei --ElA. -flj -ELE,'VATfOW- CUtLET Eto-Ab-- > AtV NO DATE or sudustf x-,, w. SECM01"J 'A-4 RN-2 LER—INGA BEIT!R ENVIRONM=ENT SYSTEM SPECIFICATION DOCUMENT RAYOX8 ENHANCED Solarche 201-RB-500085 Rayoxv Flow Schematic forms part of this Specification SOLARCIIEM ENVIRONMENTAL S` DOCUMENTN. —,. Dmwn y;Wtgg I 1 Wagg 7-D a Approved7 By: It THESE R1�VfNNS, S=ANS; lESfNSARE `SHE PR PE� EE NM A S'Yti SUBT RETURN�'f NTHEY RS 1 ED 0 THEHA THEYWILL OT E LS EE IN i�WAY i �itJR W" Page I of SYSTEM SPECIFICATION 201-RB-000064 SYSTEM OPERATING DESCRIPTION page 2 of this document HYDRAULIC SYSTEM FWW CAPACITY 3.8 gallons per minute PIPE DIA.METER 4 3" 316L stainless steel, schedule 0 :,"T W 316 or 316L Stainless steel, quartz, teflon, viton SAMPLE POINTS 0After reactor(system dish MAXIMUM SYSTEM PRESSURE ® 25 psi PUMP 0 Suppliedby customer UV REACTOR SYSTEM UV REACPOR BOnekW Solarchem 0 UV shielded 0 High Ternpemnue shutdown TRANSMITTANCE CONTROLLER * Automatic action cleaning UV reactor quartz sleeve Pneumatic drive Adjustable action cycle * (supplied by cyst 80 to 100 psi, <5 micron filter, dew pt < 38*17 Page I of SYSTEM SPECIFICATION 1 DELIVERYLIQUID REAGENT HYDROGEN PEROXIDE SYSTEM 35%Hydrogen Peroxide Estimatednt ). Deliveryvia metering pump Storage and unloadingothers EQUIPMENT COPE ' S Strucnirai steel, with acid wash primer chemical resistant enamel paint WEIGHT(approximate) 1000 is ELECTRICAL • 480VAC, 60 Hz, 3 Phase Running• nt Full Load 15 Amps+ 10 _ Housed• In k NEMA T vends drip -proof enclosure One 4 kW Lamp Poorer Supply 480/120 VAC Transformer Transfortners in the high voltage enclosure capable of rugged long term performance Power Factor better than 0.9 at 4 k Page 3 of 6 120 VAC,2 4 VDC, NEMA 12 Enclosure Contains PLC, metering pump controls and instrument indicators Panel r has start/stopstart/stop push buttons, instrument and alarm annunciators CSA Special Approval obtained on finished Systemt Solarchern plant NTROL • System Controlvia Programmable Controller (Texas Instruments) • _ Message Systemn control panel • Reactor high temperature switches and/orAlarm automatic system ; shutdown on flow out of range Alarrn d shutdown on iamp failure Alarm n lamp overheating Power interlock on HV cabinet door Alarm and shutdown n reactor high temperature Page 4 of SYSTEM SPECIFICATION 2101-RB-000064 * Alarm and shutdown on UV access covers TRANSMITTANCEC n failure to operate Alarm and shut down on low air pressure SYSTEM DOCUMENTS d Maintenance including: - System Description Piping and Instrumentation Diagram - Control Description Operating Procedure Set of Drawings OEM Nbnuals Fags 5 of 6 SYSTEM SPECIFICATION 201.RB-000064 System Operating Description Solarchem's Rayox,& Enhanced Oxidation system is designed to treat up to 3.8 U.S, gallons per minute of contaminated groundwater, pre reated to the influent water characteristics provided below. A flow schematic of the Rayox* system is shown as drawing number 201-RB-500085. The system is designed to run at a steady flow rate between 2.5 and 3 USGPM, dependin on the rate of groundwater flow and contaminant loading. Before the water enters theg Rayox-O reactor, up to 200 ppm peroxide is added to the stream barpump. metering addition rate, and the flow rate, will be adjusted as part of the This e system oprison following commissionin . Steady flow through the reactor is made posib mizati 9 le by an equalization tank (supplied by customer) which accumulates the irregular groundwater flow. The Rayoxv system is stopped and started by level switches in the equalization tank, cycle duration in a function of the groundwater flow rate. TYPICAL INFLUENT WATER CHEMISTRY: PH: 60 nommai UV Absorbancr*m: COD: 50 ppm 280 nm 0.10 260 0.12 [C031: 300 ppm as Na,2 CO, 240 0.15 Tel� <5 pp m 230 0.17 [CII: 50 pm, 220 020 Color p. <10TCU 210 0.30 Turbiditv: <50 NTU 100 O45 TPH: <20 ppm The Rayox* reactor is a cylindrical stainless steel vessel at the centre of which is a single high powolarchem Ultraviolet lamp. A quartz sleeve separates the lamp from the water. The quartz sleeve is kept clean automatically by an air actuated transmittance controller that wipes the surface at regular intervals. The system operates under the control of a PLC (Programmable is Controller). The main function of the PLC software is to control the process and to monitor the system status and alert the operator to any fault conditions. The system is failsafe for operator safety. Alarm and status messages are displayed on a message annunciator on the control panel. Four options are offered for this system. The first is a 3-way valve which will allow the system to recycle water to the equalizing tank during start-up such that no untreated water will be discharged. The second option is a modem which will allow remote system monitoring and fault reporting. The third option is an automatic voice dialer which would warn of system shutdown but could not be accessed from a remote location (option 3 is a less expensive alternative to option 21. The fourth option allows the use of 220 VAC instead of 480 VAC. Pap 6 of 6 ENHANCED OXIDATION SYSTEM So SITE SERVICE REQUIREMENTSRAYOX0 TO BE PROVIDED BY M ENVIRONMENT Industrial Ind , "" Seated r Painted Concrete Floor ELECTRICAL SUPPLY 480 VAC, 60 Hz, 3 phase Running l SAmp - 1 INSTRUMENT AIR 3 scfin, 80-100 psi, <5 Micron filter dew pt EQUALIZING5K Recommended volume w high d low level e1 switches FEED PUMP To deliver 1 to REAGENT UNLOADING Hydrogen Peroxide 35% 4 U.& AND STORAGE PIPING t 3/ " Flanged Outlet 3/4" Flanged Drain piping UNLOADING Requires loading dock and fork lift INSTALLA'nON LABOR Unloading, placing, leveling and anchoring the equipment Electrical hook-up Tubing pump and storage tanks, and between metering pump and Rayox,&skid wiringElectrical e metering pump and aax skid 0EMIZ7101 ENVtRUN__N1_E_N7"XLSYSTENYS- Dew DocumentNo.- Z0I-RJB Is By-, L.. Checked By: Approved By: THESE DRAWINGS, SPE IFi A _RN97 DYES NS ARE THE PROPERTY OF SOLARCHEM ENVIRONMENTAL SYSTEMS, AND, ARE SUBJECT TO RETURN UPON REQUEST, THEY ARE SUBMITTED ON THE CONDMON THAT THEY WILL NOT BE USED OR REPRODUCED LN ANY WAY WITHOUT OUR WR=N APPROVAL Section System overview General This section is intended to introduce the reader to thevox vstern and provide a functional description. of the overall process. I r w ' 171-RB-000047 shows a perspective views of the Ravox Svstem, Model I0 -171.' The system is used to treat groundwater contaminated with Benizene, Toluene, Ethvlbenzene,a" vlene, and IMTBE This is accomplished by means of a single Rayox Reactor () driven by a high voltage Ravox Power Suppiv (9), All ether equipment is used for control or system support functions. Drawings Referenced i 1-R - 00048: Svstem, Instrumentation Location irl-RB- 00 1 . P&II Functional description Peter to Drawing 11- - 0041 . Groundwater is delivered by the customer's Process Pump at up to 2.5 USGPMto the influent point. Influent flow is controlled by a Manual Flow Control Valve (FV 10 ) located downstream of the Automatic Shut-off valve (FV 1002), Addition of Hydrogen Peroxide Refer to Drawing 171-RB-000048. Hydrogen Peroxide is injectedintothe influent line at the Peroxide Injection Port (1) and is mixed into the water by the Static Mixer t20). T lie delivery rate of Hydrogen Peroxide is controiled by an adjust ent on the Peroxide Pump t l). reatment inside the Reactor Water then enters at the bottom of the I.a rox Reactor () and flowers up in a turbulent plug -flow p tte for efficient destruction of contaminants. A UV Lamp situated at the centre of the Reactor, emits ultra -violet light which is absorbed by the target the is i(s). After absorption of the appropriate wavelength th of light, a hiighiv reactive compound called a radical is produced. liven the right conditions in the reactor, these radicals are produced very fast and ww;ill in tan;tiv break -down to carbon dioxide tw#ate , and chloride, in the case of chlorinated compounds. These' products can be safely emitted into the atmosphere. . x., RayoxJ C A do and ,' llaintc &4+nce M4fi\ uai _147he Reactor Assembly bly The UT%7 Lamp is pnvsicarly isolated from the Reactor Chamber by e of a Quartz Tube. The surface of the Quartz Tube is �,,,riped clean at regular intervals by an air - actuated Transmittance Controller (2). The pourer required to drive the LJV Lamp is supplied by a high -voltage Ravox Power Supply (21). Blower assemblies mounted at the top () and botto of the Chamber are used to blow cooling air across the electrical connections to the Lamp, Ultra -violet shielding is designed into each Reactor assembly, Sampling Sampling ports are provided at various points in the syste to allow for analysis of treated water and ensure that the water is decontarninated prior to discharging Draining reactors The Reactor is also fitted vrith a drain for maintenance purposes process control The Ravox Systemoperates under control of a process Controller (6). A Programmable Logic Controller (or PLC) inside the Process Controller, monitors various sensors, adjusts 'parameters accordingly, and displays status information. Various interlocks and ala male the syste tail sate both in terms of operator safety and quality of discharged water f, for example, a UV La p fails, an al arm is activated and the syste is automatically shut dawn: Operation p minimal can required to run the, lao�ivste n do-1 e. "he fr front panel of the process Controller has various operator controls and displays used to primarily start-up and shut-dov the system. jOperation is described in detail in Chapter . Release 1.0 pat it tion 171-R- MUM UNE F➢ OW Ir➢E Ff.1I , qq pp qq g ,p+ p G PEROME FLOW .� ;PVT �..ry PROCESS C;CIiiM01l.k @ i NI, I' . h l➢I 1A SIC ... �I k�` ''t'CJX Pal, AC I CAI F2<^�YOX POWER �xt ➢PP1 �`; � .: � — � _ .. )AIR c:OM IEC�T➢C�IJ I�CaF�T w r i CCONI k�01 E R ,�.� ICI E 1 PORT m� <.: _ MI5Bi. C OVL R I='AH i SMICH 111LU II ( f !I!E —__. - A6I BAHK — YtYON fAwo l�«A?.r.t 7Gi"f4 Cd0 oANi � AR PRESSURE. S ➢FcI1 .� $YCk.`� lYkSY�VJaY�.k@PAC9Utl t{Yi:,is71L�Mp ---- FMURE USE) PUMP _._. Aiw -: hEC6F i2 i"BtaG � J Eli VF Ick L [ C' t n 1 COMPRESSOR Mill IAIx W ��J � rr � �°C�� � } 'rx"} 1f L i�f C ���� I� 1 1 i u /V low Asa, Ii`l' _.. SS*J __,__. M-103 -- � .* SIAM MIXER �a+a'FAPI E w PE6wOXIDi. iAPJKMl d QYN fi0."El 56Gh9t+3 � ;�'� �,r.+aaar I tip... Gi4' (dRtu.. .k5 9r�r2. `e:ftf_ a+er fie AN 1 tt aat�PS-'191 Tar LAMP POWER SUPPLY N£trAE [[ f7t WiEi *ad3t7d8d A .�" a sola"it SOLARCHEM WARRANTY arfce '� Solarchern Enterprises Inc. ("Solarchem") warrants that its Rayoxo water Purification system ("Rayoxv,) specified in the Rayoxo System Specification document will, if operated and maintained in accordance wcrion ith the instr s containin the Sol ed he Operations and Maintenance Manual delivered with u m Rayox'&, perform in accoarcrdance with the Rayox,3, performance specifications contained therein. If RayoxO does not perform in accordance with the specifications contained in the said quotation number and Solarchern is unable within a reasonable period of time to remedy the defective performance, the Buyer may remove and return Rayox,& to Solarchem and olarchern will reimburse the Buyer for the full purchase price of Rayoxo less 25% of the purchase price per year that Rayoxe was in the Buyer's possession. M=dalp� of cheat warrants that for a period of 12 months from delivery FOB Sol arthe m's warehouse (Incoterms 1980) of Rayox,& to the Buyer, Solarchein will replace or repair non -consumable parts of RaVoX1& proved to be defective in material or workmanship provided that the Buyer gives prompt written notice of each defect to Solarchem. of hem Aifl be liable for the direct labour and material cost;of such repair or replacement by the Buyer only if Solarchern give prior authorization in writing for the repair or replacement involved. There are not representations, warranties or conditions express or implied statutory or otherwise with respect to Rayoxo or any part thereof except as expressly proved herein. Solarch LAMP SOLARCHEM ENVIRONMENTAL SYSTEMS SOlarchern lamps are guaranteed at rated destruction perfor-n=ce on the following basis "" ETA RTC ( "r L I 1 d Continuous up to 100 Hours replayed at no charge. 101 _F'rice oursprorated d credit allowed for unused portion of 3000 hours, applied to. purchase of snke Discontinuous 51 to 400 lamps. 100 Tours Lamp replaced at no charge, 101 -2000 Hours Price Prorated and credit allowed for unused portion of 2000 hours, applied to purchase of subsequent lamps. REACMION RATES OF OZOINEkND HYDROXYL RADICALSF ORGANIC () Cx olefins 1 to 450 x 1 10 to I tI t 1 S-contaming 0 to L6 x 103 109 to 10 orgarucs Phenois109 N�contarmng 10 to i 101 to 11 cry ids Almancs 1 to f t fly to 1 1t1 Acetyienes .04 to 104 ,k1dehydes 10 io Ketones s 1 to 1o!o Alcohols itl-Z to 1 10 to 10 A&AM 10-2 104 to 109 Carboxyiid 10-3 to io", 10 to 109 acids Table These radicals, once formed, aggressively at=k a waterbome contaminant and vtpicaily inniate a rapid, oxidative cascade of reactions, which, in the caw of a fty n or an �)xygenated hydrocarbon. results uitimatety In C07. and Ham, xf the cote ut is chlorinated o compound. Lhe ,nine tenon; process will also resuit to the formation of �diohd (CI-) sore. appreciationof the reason for the. increased rate of decontamination obtainable by enhanced oxidation can be obtamed by reviewing the data in Table 1, above, which his ,Jhe mic constant, k. for the don o e ozone, d the hydroxvt radical H number of different classes of organic compounds. These data shoes that the rate constant for H it on orga= compounds is typically rrrtfiaon It ) to a billion t 1 tithes faster than molecular ozone - ,,ere nave n a number ofinvesuizattons into the de is o aloe chemistry invaived in the enhanced oxidation process. he detailed, step by step chemical s involved in the Jill" ':ie rate constant for the reacuon between the oxidant and the R e a s o n s r g -'OMPOUnd in queSUon. NiAtherrs aticailv this can be expres=' is: The Proprietary Solarchem Lamps. A System Design that allows for Variable, 4fetime of contaminant x Muiti-stage Treatment. 'kx first order rate constant for the decay of x ki rate constant for the reaction between gA Unique Reactor Design Wbich radical oxidizing species Ri Enhances Mr us and Rad." tion Transfer. = concentration of the radical oxidizing species present ENOX Additive& HO-) High Efficiency Power Suppfim For example, even if the by product was relatively refractory ,such as a carboxylic acid (e.g. formic acid) then Automated Quartz Cleaning Device. l0iiUmole - s x 10-9 moies iLl-I = IN Contaminant Photo decomposition Where the following assumptions have been made: Proprietary process conditions 107 Lf mole , s �Jrorn Table 1) HO- I = steady stave concentration of the hvdroxvi maical. Figure ('21) on page 4, shows that the basic Ravox,& wax 'Which is: (10-9 rnoiesiLi decontatumation system typically consists of a series c 'a that the HO- radical is the only oxidant reacting with the annular reacMs) complete with roprietary Uv jamp, pq carboxviic acid in questionve qua= sleeve to protect the iamp, a trarisnuttance controller c keep the quartz sleeve clean. a variable length annulus fo In the above example, the concentration of the carboxviic acid water flow, and a stainless steel outer shell wail. nus deing, °,vould decrease by a factor of (1/e) (-0.37) every lifetime. or f3cilitates variable. multistep treatment and efficient mass an( every 10 seconds. If the byproduct reacted more quickly (i.e. radiation transfer. had a larger raw con with the oxidants in solution, or Lhe concentration of the oxidizing species were higher, then RFACID2& 1.he iifedme of the intermediate would be further reduced. The importance of reactor design on the performance can b seen from the results shown in Figure 1. From act F t-rorn me foregoing discussion, it can be seen that [ne treatment results, the dioxane concentration .oncentration of any intermediates or by-products that might ­)c formed -as a result of the 140- anack on the original xmpound, can be reduced to whatever levels desurd by -imply ensuring Lhat the contact or residence time Ls sufficiently long to achieve the target discharge, criteria What is usually observed in practice, however, given the highly reactive nature of the radical oxidizing species generated in ." e enhanced oxidation process. is that the contact times . eacd to rcduce trie concentration ot Lhe mitiai con Luninanu; to target discharge values, also results in the sausfactonly complete destruction of any intermediates or by-products, As a, resuft of this near complete rnineratizauon "des trucoon ') of any waterbome organic conLunmants, the use of enhanced oxidation for process and groundwater -2mediation means that them is vimiailv never a se-condary fir .ownstrearn aisoosai or handling pronlem. Figure i SOLARCHEM ENVIRONMENTAL SYSTEMS i k%xakL THREERAYOXRF-ACTORS R s r T r FIL MW SWITM LW MOW AIAAX LOW EFFLUENTrAL INFLUENT Drain Bile Transmittance Controders TEI 63 1p350 [ELRAYOX FLOW' SCHEME Figure , emaining after a dose of three in reactor B is roughly one half important for iarger throughputs, e.g. > 100 gpM, or for more hat remaining w Since dose is proporuortairefractory contaminants such as TCA and methylene chloni t _ st. it can be seen that the operational costs involved with which require higher LTV do e& ,,,chieving the discharge concentration obtained with 3 dose is —0.2 ppm with reactor B wouid beapproxiniatedy 3 The importance of the choice at UV Lamp can be seen b, more with reactor A (i.e. 4 dose units with A vs 3 units with :. results , tit i 6�ja drt figure JQk.Ft reviewingf} qq is i.results are shown for the destruction of waterborne dioxane a a function of dose using two different So data shoes that the cost of achieving a dischargE he Solarchern dimps am high intensity broad spectrum UV concentration of l Mot with lamp 8 would be toughly �nt v s xhich have particuiariv Szmng output .r s Pe Lhat for p A with this particular c tt photo -active absorption bands of most waterborne c,ontarnmants. Powers to 300 times thm o0mituible with Generally then. it is important to achieve a judicious m ;ow pressuremercury typical of first genemuon between the iamp emission d the p tiv mrianced oxidation systems, am attainame with e absorption bands of the target con t(s) as this ca- Solarchern Lamps. cream a significant new contamintint destruction channel i.c phoutilvsis or phouidecomposition of the contaminant. ;s �,ubstanuai enhancement in en , fcctive rower -awn !h i� tip itt Ste€ VS L.anSlaICS Uiiia �;TUUCr, .Aalt)cet K Yti systerns for a given throughput capacity, resulting in lower ° pital and operaung costs. This. of course. becomes critically THE EFFECT OF ISOLARCHEIM LAIAPS ON DIOXANE REMOVAL Rayox Dose Figure BENZENELTV ABSORPTION PE i 100 o 40 20 ro 46 r Wavelength, not Ft Selecung the appropriate UV lamp is facilitated anderstanding the Peak abwr&vwe of a particular water 'tmara' nis is accomplished by obtatning a printout of the dosorbance with respect to the UV wavelengtha ,pectrophotorneter as is shown in figure (4 & 5). Figure 0) meows the PeA apsorbame of waterborne berztene to be about :0 nm while that of NDMA to be about 228as shown in zuret.Jj. It can oe concluded fay utifizing protons of L to take advantageof the photo chemical destructionof . , rise contarninarv, in addition to the oxidation way unitiated by file hydroxyl and perhydroxyt radical 4 wiil -zsfait in a lower operating and capital cost as wed as smaller care compact yoprocessing egtu UV Absorption SPectrum o(NDMA ca It 7 Wavelength, arn Figure in Gmujvwster i Ilan ze Figure d Af)f)rrrw.1,9 A further factor contributingto Ray"Iss supenc pertornunce is the use of o rta` additives a Process '.know how. These ad&nvp- enhancethe rate of contartuniant destruction by enhancing th raw Of r3dicW forniation or the efficiency of radii utifization. The exnordinary enhancement decomanimation efficiency obtained by Easing one or met ENOX additives n from the data an Figures (6 & 7` wherein die dog of the concentradon of benzene in water plotted as a function of Ravoxo dose. From Figure(o), it c be n that the use of ENOENOX 510 resents in a cost one quarte (11) of that required for UV/peroxide alone to achieve s; f=- benzene concentration of i ppb franc an initial value of aboL » "ram SOLARCHEM ENVIRONMENTAL SYSTEMS • �, �« ��. �_ ,, ie a � „� _. ., s i, ea e '" � , ., r � .. � t .. _ « , "� m i � w .„ ,.. i' . e �; ti � �� �. �� � c �� '� .4� � ;�,;..�^ �� � i V t� i;, „y,, ,. . �. '`""� �# ,u � �.., �, r ,' ! � ,. .: ,. r., �, ....: .., _. � .. � .. w � 4 � t-...: i y • �, � - M. . � a � �.... r t �� ,. � � � �; -... of . �. .. , �. �� ., „tt maatir U.. wood t1t=9 firm has PCP con 'nadenuate"vaste handling Pr3cuceS havein the 90undwater at one of its is in the Soudieastern States, r. rt t of sod as well as the 3quders undera major` crag tt of the PCP in the groundwater is about 3 �` se facility in athvsifefi Ontario. e tt rtca the dISCharge Criteria was set at less than 10 ppb. Ministry of the Environment wanted to achieve a discharge results shrswIl in Fig= (li) cttttsrp sftt this ttiret way sserttsattcttt at l ppt (ttMetft detection limit). t�assi achtev The treatment results Shown In Figure ( demonstrate that the <20 PIX target was readily amune& REMOVAL OF PENTACHLOROPHENOL t3 CONTAMINATEDO SITE PCB GROUNDWATER REMEDIATION I � .t Z .01 Z. 0 Ptit t. detection 0.001tt d t z a 1 3 Rayox Dose Rayox Dose Figure 10 Figure1 Dioxane is an excellent, water xmiscible r lv nt mth a TO illustrate the powerful decontamination tion ility of range of industrial li o . Unfortunately past Rayox,9 some typical results for the desauction of Several process wastewater eut s i.e. Lagoons, have refractory cart is vets below: ,esufted in Elie contamination of some groundwater aquifers, - r ux pfe. a Michigan tst inadvertently pi (13) shrews nits liar reduction of the yontammawd an aquifer beneath one of its facilities with up to �hloraform from about 3 0 pput to less than 0. t pprtt._ 3.0 ppta of dioxane. The results shown i ; (11) ,ientonstrate that discharge concentranons of <2 ppb Chloroform Destruction Using Rayox 99.999+% destruction) tip achievable with t Dioxane Destruction using Rayox t too x to. y'y [ st 0.1 1i Rayne Dose k1 , Ravox Dose Figure 11 'igurc d l i 91ves some results for the reducuon of the i '. a oncentration from atiout 2000 ppb to i ss than 5 ppb. Using star ox Degruction of TCAin ` Ci C t 00 W ,� ait 10000, U V/112t 1001, L 0 sla t tt EII— 10 E001610 0 2 4 10 Dose Figure 1-5 FigureRavox 1 4I? .fit The effect of y on waterborne - DCA was Figure 0) presencs results showing the reduction of Freon evaluated on a groundwaterat the Law7v= Livermore from about 100 ppb to less than 10 ppb. National Labomtory on Livermore Califorma to july 199(). Groundwater _ l was transported by uink truck to For h of the above examples, evert tower discharge criteria be treated to batch mode by a Rayoxg tivisportableit, could easily be ,achieved by simply increasing the y located on the Lawrence Livermore National Laboratory slit, dose. This transportable utut was Sunda to that shown in Figure 8. Ott results of DCA reduction shown to Figure 16 confirm the capability of Ravos(S to reduce waterhome 1, , DCA from rntare than 100 ppb to the tow ppb range. t KzkWhr�t HI Symbol Test So. Destruction 7w8 30 25 3 n+ 4. .6 0 100 6.0 30 12.8 X t oSC07> 7. t o 10so 12. ,gg 4.9 40 scio 3.0 a a. E ��ryry 40 Energy tkwhtl000 gulonq) Figured 7o illustrate the Powerful decontamination capability C PESTICIDES Two examples of the effect of SoLvtoems Rayinisl yra . : is for the destruction of sever n-picalon waterbomex California am worthy of note. .ontarninants are irivenbelow: Field tests completed in January 1990 in San Luis Obispo on Destruction ot Petroleum Hydrocarrons m pesuciderinsate stream confirm the mpid destruction of Rauast rater waterborne Roundup in Figure (19), lam Roundup a 'on using Ravox g xr t m low ofto Figure 1 i Figure (17) shows the results for the reduction of BETX and in barge ballast wata as a function of Rayov&o t a site in New York state, Figure 1 ZENZMM At a second site near Bakentield California, Solarcherr Tlie groundwater under a New Brunswick Department of successfully reduced waterborne DINOSEB. a banned pre art fueting station in New Brunswick had become emergence herbicide, it a large quantity of sots wash water ,,ontaminated over the years with BETX, As can be seen from shown in Figure t 20). rotor reduction from that of s deer -ke dam in Figure (18), benzene was reduced from about 80 orange to essentudly water white was alsoa riamed to t ppb.. As benzene is the most refractory of the t uon. the other contaminants t to even f over concentrations. Another point worth noting was that noof Ptre , r : _ Effect of Rayox on The Destruction Dinosebin Soil Washwater ,..s ne was used. so there was no tiff gas with s � t Lo am In some tim generation enhanced oxidation systems, is a as a H the nit t o st t t ,uanutv of any volatile contardinant will be air strip ped due to ae large gas-houid ratio invoived,,inth such systetras. Destruction o(BTX In Groundwater at New k Dept. o(Transport site� 100 i 1 t 1 -rRayox Dose 0,01 i RAYOX DOSE Figure 1 77he man4facttire ai TNT (trinitrowfueftf dith mmits in ibe OroducUbn of pink waw. contarnmaLed with �50- 1 �25 mg�t of 7�NTSdLg� qxrutd out dtaobifity Saidies wsigned to find the hld�( cb�t tffks� conftgj� of !Wo� to aeat 77NT to tfie rNU#0 djku3* C-hMrmi of <005 ni*j�. n tesults a tbi� studitS indir-awd that Ofthwiced oxidithid�*& MeOd, �* ��ve f0f Oittk water atamem T*4T Destruction in Water Using Rayox RAyox Dose '�t die Indian Hitad M*iand NavAj Ordinahce 8t4oii th�* a nitmglYtCTtne Contanith4ted wagttwWa, sucani ftoM tl ,extrusion piam F6r this sumam. Lho best approach Usin �nhanwd oxidaticul: for the destrucla6b Of NO frolll i lba 10P - WL SOi-kRCHEM ENVIRONMENTAL SYSTUAS LO < 1 n*L, was a tN*ydwpn pex� symm�k lestrircuon curve fbf NQ is zurt in MIMMU."M VWO�M"'Y� -7 U �drnbioed hydroxyt m� and photdfy�rs based mepnanjsm "Or the rnaximuru effip�, Wtild ihe o*d 4 trtattatent of all ihe dds stream with tieffva• b» » 4re e0foo4ra» ;, rniugg= in tivour of the 14der ippr� Other retated ordnance rompounds successfully destroyed by Ravox,& include: TNT PGDN DNT TIMETN Nix 71-:GDN i4MX RDX 2 A Y-Q V I "mfirninary estanates of Capital and (�xratmg cost -ut available frGm Soiarchern Won receipt of the following nf6rination: ,nietwin tarninants of coxem & concenuawn * Desired effluent qUaiitV * �,Iectric power rnte in c,,kWhr Very versatile system cao: d up or dol ugh Degree of Safety can be built to UL Standards. SOLA erences ;gen ie. 11. .A Hewes, `.%.. Ma , t -E. 1976 Oxidation to Refractory Altatertais by Ozone with L"ltr :bier Radiation. 1n Proc. C '.nd Internanonai SYMiPosium on Ozone Technoiogy, Inteernat. Ozone Institute pp. 224-252 Peyton. Glaze. W,H. 1988. Destrucaon or Pollutants with Ozone in Combination with Ultra Violet Radiation 3. Photolysis qf Aqueous Ozone, Environ., S is Techn. 22, 71 1- 6 : `. Pailt ra, I1, Brunet, H� Dore, . 1. Conaitions opta s j*appiicaaon du Systemexi Oro - Perorvae "'Hydrogene Water Research, Voint 22, N, r Pg. d. Htinge, 1. et Bader, 11. (1 `6) 7`he Role of 1lv os t Radical Reacaons in Ozonatian Processes in Aoueous Solutions. Water lies 10. 3 -S t . 5. Barker, R., Improving the Effleiency o1 Ozone to Odour Treatment with UV Light Ejecmcay Research Centre Report M1233 (1979), 6, Dr, P.D. S. Stevens "Application of Rayox3 w'nr the ,emetuarion of contaminated Ciro ester ° HAZ.VAT Central C nterences* Chicago. IL.Vid 1990. Dr. Sol Lvandres et at 7reatment of Grounawater Contammants with ' oldle Or ; n .'7econd Generadon UV Light Tec` log' ` HALVACON 1. Sama Clara California, April, 1 1 1. P. W. Smith "AOX Reduction in Bleach Plans Effluent', �Wo e 90 Conii!rence, March 19 to 23,1990, , 1. Mr. Doug Reed 'Enhanced n Treatment of Process Wastewater Containing Explosives-, IMZVAT Conference, June 1990. Atlantic City, , " ,_ -kCKNOWLERUMUM The author gratefuilyowi the very vaivable preparanon of thts articie. Without their c ntnbution, Lhe prepartiaon of the articie would not have been ~passable. SOLARCHE ONMENTALSYSTEMS TEST BORING RECORD EUVATION D. NE;S' A[`ION- t o Foat t (VEM MICRIPMN 0 1 to 0 :0 40 60 as too 0, Tod 11 1 [ S r Fill kFirm to Soft 0(a gs to Tan to Brown I_ Slightly Clayey Fine to glum Sandy SILT Hit - Loose to Very Loose Orange to Tan r a i 3 i Slightly Silty Fine to Medium SAND with Organic Matter and Rock Fragments - Moist g a 2 s t t 10.5Fill - Soft Tan to Gray Fins to Medium Slightly Sandy Silty CLAY - foist I r � � E 1 e t 4 � A 1 tlee f 4A } Boring Terminated at 16A Feet. t No Ground dater Encountered at Time of REMARKS., DRILLED BY LAW ENG.BORINGN •1 LOGGED BY SBF DATE STARTED 5-14- 1 CHECKEDY CRL- AT MPL T EIS -1 - 1 JOB NUMBER 56-8555 PAGE t OF 4 Law Environmental TEST BORING RECORD UJ-VATION Drfq, REMARKS: FENETRATION-BLOWS PFX FAT DRILLED BY LAW 1BORING NUMBER B-2 LOGGED BY SBF DATE STARTED 5-14- 1 CHECKED BY CRL DATE O PLET -1 - 1 JOB NUMBER 56-8555 TEST BORING ELEVATION DEEM PENETRATION-BLOWSPER FOOT Lei 100 0.2 Topsoil Fill - Firms to Soft Tan to Brown to grange Fine to Medium Slightly Sandy silty CLAY � s -0 —IF—UtSoft grange to Brown Fine to lure j P Slightly saner silty CLAY with Rook Fragments - Slight Petroleum Odor 1 i1. k Alluvium .Firsts Orange to Green Fine to } Medium Slightly sandy Silty LAY - Moist L i t � 13.0 Alluvium ;-Firm Brown to Green Fine to Medium lightly Clayey Silty SAND - Moist 1 ith strong Petroleums Odor s _.. Boring Terminated at 15.0 Feet. No Ground Water Encountered at Time of Boring. E i ; z s ; 6 I E t i � j!t E a 9 r s i t t ; a V I ; f ; a F � R REMARKS: DRILLED BY LAW B G BORING NUMBER B_ LOGGED BY SBF GATE STARTED 5-1 - 1 CHECKED BY CRL DATE'COMPLETED 5-14-91 JOB NUMBER - 5 zr PAGE 1 OF 1 Law nvironrrserstal 400160. I�r Vow Am~ Amum & ENVIRONMENTAL ,SOB NO SHOE_`.. _ CHECKED ^ , r PA o u VN,4 7, AA) E �µpM' '1A+ A., $ m ute :, A - . -, g-,eG, c V,, s ti- . f V CkII �::.. �0ioX"'^'.'. ,. A '#" q"j; ° 'k 1r'.-c .0 " :: .. �^"4 . VII el f Vl o'er s aA "� �'�" ` -t C t: t I'VN ` . Jlk m: i C OB NO, El 55' SHEET 1-3 R N, At, NV4 E 7_C_il3_cx__ 47if mew LAW ENVIRONMENTAL. INC. - Mw lom g aw low o Professional engi�neering!an ond My DATE earih science consultingfirmF ,riE'_' t DATE_ ,.fie n Ft"u., ;r mom ANOM-000 LAW ENVIRONMENTAL. INC. mom lom as professional enginME ow eering earth science a'onsullin erase a ON F o t _.. cN .,' , ," �w SHEE op AwNwom LAW ENVIRONMENTAL, INC. law low ftssional engineering and earth .science consulting firm r C�t t= ov P L (s �-- L LY ca lug ��t k W4-o G 14 Dew W- t d !- ' has' A 63' a J.q' �-z t IS 1 i ".. 0 �. V""t P-t -Y-Y , Cjl:O'r",., ar 64 JOB NO.SH EET 6 . �'-F 4M LAW ENVIRONMENTAL INC. Ow �.+ t C % t Pov LL r Y` `tea ,:r ,... - "« m " :.. $ a: k tywr . 7{ j a'. a 1 24 9 srL N4 A p 88 SOIL SURVEY TABLE 14.—ENGINEERING PROPERTIES AND CLASSIFICATION [The symbol < means leas than,; > means greater than, Absence of an entry means data were not estimated] C3assi 'lcaticn rag- 1 ercontage passing 4 Sail n e andoC'e�tha USDA texture a f lnches _. 4U2f1G a t 4see n4mr-t Liquid I Plas- map symbol 1 1 Unified AASHiCJ o 1 1 ; limit ticity a x e a R m e a s__ _ ------------- �n Pet 4p , A DS---..-;,.»---1 0-111 Andy loam--- --ISM, SM-SCIA-1 0 18 -1001 -»1001 -7 15-35 i < ApplinR 111--4315andy clay, claylMH, CL, 1A-7 1 0-5 1 5-1 1 5-7 04 0-9 1 5- p 1 41-74 1 1 1 bars, clay. 1 ML, SC 1 t 1 t 1 1 1 143-6613andy clay, clayiSC, CL iA-4, --bo O 5 195-100195-100170-90 140-75" + 25-45 1 1 i t. loam, dandy R 1- clay loaar 1 R d R p f 5 1 R y 1 1 B t 1 C S2, CeD2--..- ---_1 0- bandy clay to 1 �9, , ;A -A A- 1 174-100172-1 i 5-95 138- 1 „ 1-35 1 Cecil t ; CL, ML t 1-531Clay, clay lupin 1M , ML 1A-7 t 0 197-1001 2-100 172-w99 155-95 1 41-81 15 .651 ea herec 1 1 a bedrock. 1 1 1 1 1 1 1 m 11YM'<Ap x 5 4 ➢ 8 t 1 i i } Y p Cecil— ----------- 1 0-6 iSandy clay loam 'ISM, 5C 1A--4, A-61 0 174-10I4172-10015- S 38-51 1 21-3.5 ; 1 i i CL, ML I1 1 t is 6-531 lay, clay loam 'MH, ML to-7 1 0 19-1001192-lGOt 2-99 055-95 1 41 t 15-651Meathered a Urban land 1 1 1 1 t t 1 DaS, OaD, DaE------t 0-7 tSandy clay loam 1CL, SC, a A-,6, A-^41 0 i 94_1001 4-.100175y-95 '40_70 1 25-40 1 Davidson 1 i CL-ML,; 1 i 1 1 t 1 1 1 SM-SC; 1 t 7-16tClay loam ------- JCL iA-6 i O 196-100190-1f1o175--95 5t1-75 1 25-40 1 16-99 i C a---_- w--.-.--1 CL, CH, i A-7, -°61 0 196-100195-1001185-100165-85 1 3 «-65 1 F 1 ML, MH EnB. EnD ----------- 1 0-7 'Sandy Lean ----ISM, iA-2-4, 1 -5 181-100180-1001155-6 125-49'; 1 <3 I Enon 1 r SM-SC- l A-4 4& 1 1 r 1 m 1 1 Sc l A-, 1. t 1 A--2-x6 7- 61C1ay loam, clay 1C11 1A-7-6 1 0-5 15 100 16-tUI11'75-9 16 -9 1 51-79 1 3 - 6011We t ere „ «- 1 - - t .. - -. - 1 --.- 1 --- t -. - --- bedrock. 1 1 p ( 1 a GeB2, GeD2------- --d 0-5 lSilty clay loam 1CL,. ML IA-6, 1 €1-3 195--1Cti3195-100:490-100i65-Kill 30-49 George" l le r t 1 1 A ,7-6 u 5-• 5n5ilty clay,, iMH ML tA•-7— i 40 i3-100'195-1001 0-100 75-98 i 41-75 1 1 silty clay loam, clay t 1 t k t 1 t 1 t loam- t ► t i t t & 1 1 5--4913ilty clay loam,,MH IA-7-5 It 0 195-100i90-..100165--100I6G-96 1 50-75 t a silt loam, clay,,a 1 1 e 1 1 1" loam. % 1 1 i49-99tS It 1L1ast------- 1ML C& ,' iA 4 1 Ci 5 190-10019U-100165-100160-95 a <30 t 1 1 CL-ML It Gas, Gn[-------.- 0-6 1Slaty silt loam 1GM, SM iA_4 1 5- 4 t60-&C 155--75 150-70 4�0-60 1 <35 Gc lds ton 1 t ML { 1 1 1 c 1 1 1 GM -GC t 5-161 1aty silt loam.IGM, OR, ! A«. , 110-30 t55-100150-92 145-90 125-80 1 <45 slaty very fine' ML, 1 A-4 $ B 1 a 1 t 1 sandy loam, 1 GM -GC 1 A-,5 i 1 t 1 116--241 laty silt loam 1GM iA-2 i20-40 125_40 125-40 120-40 115-35 <20 1247-621Weathered bedrock. 1i S-___ __®®_ -_®__b C®6 o"Sandy loam _ -1SMy ;A-»2, A-41 0 195-100c1 G 100151^8127-46 1 <30 Helena a 1, 1 M-sc, 1 1 1 Sc 1 8-11tSandy clay loam,iC 1A-6; Aa71 0 195-1430t95-100t1'0--90 R55--70 i 30^4:9 1:... clay loamy { 11-40JClay loam, sandy,CH, MH 'A-7 1 U 195"100195-100t73-93 156--80 1 50-85 1 , clay, clay. 1 t 1 1 1 1 14U�-6411�eathere t t bedrock. Sea footnote at and of table: NP-5 15-,3or R-22' 3-15 9--37 3- 1 9-37 5-1d 1 1 -25 15--35 NP-15 25-80 11-24 15-35 15-35 N-10 P'-1G N - 1 t NP-3 NP-9 15-25 2 4-5 r1 MECKLENBURG COUNTY, NORTH CAROLINA 91 TABLE 15.--PHYSICAL AND CHEMICAL PROPERTIES OF SOILS !The symbol < means less than; > means greater than. The erosion tolerance factor (T) is for the entire profile. Absence of an entry means data were not available or were not estimated! rowan Soil name and e Depth t Permeability i Available !Soil reaction; Shrink-sweli I factors map symbol ; B water capacity potential 1 AAR, Ape-_.._.:,- -- 0-11 f Appling, 11-43 43-66 CeS2, CeD2 ------- 0-6 i Cecil 6-53 1 53-65 CuB*, CuD*: Cecil--,.--_----- Q-6 B. 6-53 1 53-65 1 Urban land. ti DaB, DaD, DaE ---- o-7 Davidson 7-16 16-99 En8, EnD --------- f 0-7 Enon 7-36 0 36-60 t GeB2, Ge112 ------- 0-5 Georgeville 5-35 1 35-49 49-99 t Goldston 8-16 16-24 24-62 HeB -------------- 0-8 Helena 8-11 i 11-40 0 40-64 i HuH*: Helena-___-.-..__ f 0-8 1 11-40 0 1 40-64 tl Urban land. Ire ell 1 6-24 is 24-28 0 28-65 Iredell --------- o-6 6-24 0 24-28 i 0 28-65 1 Urban land. LAS -------------- 0-5 Lignum 5-37 ; 37-50 See footnote at end of table, In/hr in/in 4.5-5.5 :Low ------------ 0,24 4.5-5.5 :Mader -ate ------- :Low 0.20 0.12-0.16 4.5-5.5 ------------ 0.24 0.6-2O A 0.13-0.15 1 4.5-6.0 tl 3Low ------------ 0.6-2.0 1 0.13-0-15 4,5-5, ,5 !Moderate ------- 0.28 --------------- 0.6-2.0 1 0.13-0-15 1 4,5-6,0 !Low ------------ 0.28 0.6-2.0 0.13-0-15 1 4.5-5�5 !Moderate ------- 0.28 0.6-2.0 Or14-0.18 1 4.5-6,5 :Low ------------ O�28 o.6-2.0 1 0.15-0.18 4x5-6.c 8Low ------------ 0.32 O6-2.0 0.12-0,16 4,5-6.o !Low ------------ Oa24 2.0 -6.0 0�11-0.15 5a1-6�5 tIs !Low ------------ O.17 6-0.2 0.15-0.20 5.1-7.8 sHigb ----------- 0.'32 --------------- o.6-2.0 t 0-13-0a18 4ro5-6.0 fiLow ------------ 0.37 0.6-2.0 0.13-0-18 4,5-5.5 trLow ------------ 0,37 0.6-2<O 0.13-0-18 i 4.5-5.5 '9Low ------------ f 0.43 o.6�-2 .0 0105-0.10 1 4.5-5.5 ILow ------------ 1 0.43 2.0-6.o 0.10-0115 4.0-6.0 wLow ------------ 0.20 2.o-6.o 0.10-0.15 4.0-6.0 tLow ------------- 2.o-6.o 005-0.10 4,0-6.G Mow ------------ 0.20 --------------- 2.o-6.o 0.10-0.12 d 4 4Low ------------ 0.37 0.2-0.6 O,13-01.15 1 4.5-5.5 !Moderate ------- 0.37 .06-0.2 1 0.13-0-15 1 4.5-5.5 oHigh....®--------i 0.32 --------------- ry 2,o-6.o O10-0.12 4.5-6.0 !Low..------_---- 0.37 0.2-0.6 1 0-13-0.15 4,5-5.5 !Moderate--------; 0.37 .06-0.2 O13-0-15 4.5-5.5 lHigh ----------- 0.32 --------------- 2.0-6.0 0.12-0,15 56-7-3 'KLow ------------s 0,32 .06-0.2 0.16-0.22 6.1-7,3 ;Very high--- --- 0.20 .06-0.6 5, 0.14-0.18 l ti 6>1-7.8 thigh ----------- --------------- 0.28 2.o-6.o 0.12-0.15 5.6-7.3 !Low----- _--_ 0.32 .06-0®2 0.16-0.22 6,1-7t3 flyer y high ------ 0.20 ,.06-0.6 0.14-0.18 1 6.1-7,8 Nigh----------- O28 --------------- 0.6-2,C 0.11-0.18 4.5-5.5 ',Low ------------ c .43 .,06-0.6 0,10-0.18 4.5-5.5 'Moderate--_.---- f 0.43 -------i. -------- 4 3 3 5 4 2 3 N 2 NOW A-monam LAW ENVIRONMENTAL, INC. I Now vow am 1. a prqj�ssional engineering and -ay earth science cons dung fir '— KED -_ . . e-,), (A, `: � f ki t(A vv Ij x l ; LAJ 1a 5k Lr aq t I I ti t Oe c W W k cr. 14,0. 1 C �-4 14,?« Y--�;-=t. ;k A'" . JOB O. .'( " , SHEET,---?-- F_ mamma E ahw_ L I m_ mw a prq&ssional engineering and DA E earth science eonsu taaa firm OLY CA�LrLj : r LAW ERVIAONMENTAL, INC. Olrow J O—i( . jOB NAME-- i r ,. e/ 2" Y c1s K i T y1 v tAW ENVIONMENTAL INC. a prqpssional �ewgineeriing and mwmww earth sekno rOnSalfi#g firm Da- Laxj �N S11-11w- Fj,0DEB3 Fy DATE,___ 'HECKED BY CAT WIN go� LAW ENVIRONMENTAL, iNt a pr*ssfohal enonveriog and eatih seknee JOB NaF_ SHEET—, 1,2- OF__'� C6 NAME —ELL ey E ClHECKED BY DA7E,_+f_14q,2_ (LZA- a_cLL,4,,6-t, CIA C, Q V'. Yak Lx; CAoAc..# cx, IAI�l J"V� 61AA LAI^ f-A-1 00 0""' Cp�'Lu"�Oj;:* too 6+- ,kc_ j ry I aj 0"01 Do 0 0 1 a i C� -K Co LAW ENVIRONMENTAL, 1 A >1 -Air QAI: 'A' ---w 'jLL I-D NIPPON E31VC] f) ul AM jvoss�jimld v Wom AMM vammum ASNW INI *lVIN3WNOHIAN3 MV1 ------- 90' vam Amw ,'am AMW - ---c', 't ON 13C)r �,a F SHEET--,' .F AVOW ,: � LAW E VIRONM NTAL. INC. i =6 �KAE-�v professional engineering and earth science consulting 'rrnt ,rjy 13 vkv 1 &+ I Y i vv'+yk„'kua"M' Wa+,e--A 71, 6 pp p n omm JOB NO 7� SHEE A~ jumom JCB NAME F7.,- andDATE earth science 41.+'engineeringL nsultingfirm � j C w. It vko �..'mkU, j G';K t v PAS a. " w,s ,apt 4" a i'. F G✓r ! 01 VYX4 fu..,� .: ' m .g�"i✓ t � .. f ' a..rw. vw.�'" yt ? rig:^ W q{ cyp vc p %qy .�.:. yy 6vef t t. yp _.. t o' �o-jam g AAf Av'ok , r ya Al -� 11 oA 22- CAB NC r1 A r Avow l AVOW Ammomm Maw Ammmomm LAW ENVIRONMENTAL, INC. � vt,� �� � � �_�$ �VAw ow a prpfessional engineering, and*"' -HECK' BY o PAW r. +sae ', kA oA ,r R d airy. — 7 n r,CA a c BF C , , x {9 x Ir _t *a ew ,s-, : I I t G uted by certain and basal beds : drding to the ,n by an ' ertically ouifer. Where e rocks below, ccurate main- ult. Confined e called ieakv ,,it to analyze timed aquifer no a conduit and are part :ese conduits year to feet # if not used, at openings and gravel rocks, eolorniteLL td intercon° 'notion are rctermtned n index of ex pressed, or pores, )resented N, OCCURRENCE -AND MOVEMENT OF GROUNDWATER P Table 3.1 Porosities for Common Consolidated and Unconsolidated Materials f lav33 [ Sandstone Silt 3-3 y ; Limestone/dolomite (original Sand `3d Q secondary porosity Gravel I , 0 } Shale 1-�0 :Sand & gravel,mixes i 3 Fractured r t litrte rock -i ilaciai till d l ll 33 Vesicular basalt ( t0-5 Dense. solid rock volume of weer an aquifer can hold, it does not indicate how much water the aquifer will yield, When 'pater is drained from a saturated material tinder the force of material releases only he part of the total volume stored in its pores. Thequantitytof water that a unit volume of unconfined aquifer gives ups by gravity i called its specific yield (Figure Specific yields for certain rocks and sediment types are presented in Table 5,2, Some water is retained in the pores by molecular attraction and captlm laxity, The amount of water that a unit vOlurne of aquifer retains after gravity drainage is called its specific retention. fhe smaller the average grain size, the greater is the Percent of retention, the coarser the sediment, the when comparedtca the greater will be the speciMc yield; porosity, The surface area for differero size sand grains is shown in Table 53. Note the large increase in surface area forthe finest sediment. As the surface area increases, a larger percentage of the; water in the pores is field by surface tension or other adhesive farces. Therefore -finer sediments have lower specific yields compared to coarser sediments, even if they both have the same porosity, Specific yield plus specific retention equals the porosity of an aquifer® Both specific yield and specific retention are expressed as decrial fractions or percentages. Specific yields of unconfined aquifers (equivalent to their storage Coefficients*) range from 0.01 to 030. Specific yields cannot be determined for confined aquifers because the aquifer materials are not dew atered during pumping. t Storage coefficients cients are much lower in confined aquifers because they are not drained during pumping- and any water released from storage is obtained primarily by compression of the aquifer and expansion Of the water when pumped. During Table S.?. Representative Sp ; 3fic Yield ranges for Selected"Earth Materials t Sediment tild 4`inld, % � Clay 1�3 Sand 10- 0 Gravel Sand and Gravel 1 5-3f1 25 Sandstone 85-1 t 0.3-3 Y Shale Limestone U 3 *The coerricient or storage is Tulip^ defined in Cha ter 4, Bric"Y. it is the volume of water taken into or releasedfrom storage Per unit change in head per unit area: ENVIRONMENTAL,SNOW INC. JOB Now vm professional engineering carat' � earth science consulting gar AT 0 Pt iv °P I w. 61 4 af lamu wR c 3 'wc" - _. 00 00 _m.. vim^. ° c -' JOB NO S%W Al-MMOMM LAW ENVIRONMENTAL, INC. low Now arrr . a prts ssion l engineering `airy �:"}.. 1 s e� r h science c°onsultin rm t # mo(AVAA `'. ------------------ "' 0.5 0.01St 35-0 14 0 0 34 t 1 4' t k5 3 tTo 0w0" i- 2— t5 too � ( 6Ctooa i 100 t k 0 r p 13 1 L ,« t 50 0-5 0.032- 1 k I mo`- t�o O.C)('+430 l 000 4 1k s 4N 1 ° 1. r t 310 1+ 57 1t 1040 1000 =ea t 01 oat) 5-0 0t6?(000 Roo 1.0S 3 1 °0 4 toy° 07, t0 4 too 0 $ova t �000. " too 00 t a'3 JO SHEET OF LAW ENVIRONMENTAL, INC. t NAME professional engineering DATE 7+ earth saga consaa tingBY CHECKED DDT Vo LO 6�jl> �AM y d r t P 44 -F+ i ` " pp W T "wt b�ui fir" I 11 r ` � �`-�"°°.�,' ��• �.'."'„ � ;i ,�N ; ,,,. i` � � k a� rye J � � sue. � � . ! (: m4r -rno l� " jOB NO, SHEET LAW ENVIRONMENTAL.INC. low earth . cit,,note consultingfirm CHECK ED s». et �. 1 , t ;v, U. C,? 4 ey- " - ': t4l 1 too x fool JOB NO, SHEET 24_ OF ANOW 'NOW LAW ENVIRONMENTAL, INC. JOB NAME _Lvelt--�P4�p-r a sw Bprofiessional engineering and y DATE earth science consultingfirm CHECKED BY DATE C�e,TEC-rl Vf, �ALCU4.A ne- 47A 5702AIAC-76, L-APACA Ty rut iv jkolb C-� 1k)Fi4--rXA-rjo^j 6ALLCR-3 V = Zo' x /00, x & del- AVAtL-AeL-L- Vm 'z-- V X 0,.3 VN jF�:' 'Q'XrtJt- CAP 15L, —lc> I A) Al LIA4 + p —�N A~ ANNAft UW M11401WAL, NATIONAL ORATORIES DIVISION 300 CHAST IN CENTER BLVD. SMITE 31 KENNES W, G OROIA 3014 5 FAX 426-0243 February Lawn Environmental, Inc. Lake Points office Park 4333 t Road Suite Charlotte, 28217 Attention: Susan Fadero LE Jor:6 4. Subject: l analysis of sa l received n01/31/92. Dear Ms. Fadero: Law Environmental National Laboratories has completed its analysis of your samplesreports results the following Theseresults I tonly to the contents of the, samples submitted. 1 l not be reproduced except in full without 1 of Law EnvironmentalNational Laboratories. If there arequestions, please do not hesitate to contact us. Sincerely, LAW ENVIRONMENTAL A LL LABS Linda Harris Hydrocarbon Laboratory Sa r isor . tt ut : Data Report Invoice LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/07/92 page 1 --- Project Information --- Lab Number : 62-3726-01 project No. : 56-8555-004.20 Cust. No. Project Name : FURR PROPERTY Manager: SAS AN FADERO --- Sample Information --- Station ID : RW-1 Sampled Date/Time 01/30/92 l6i07 Matrix : W Received Date/Time 01/31/92 14:00 Type GRAB Received From/By EES/SN Collector WAT Chain of Custody 242 Number of Containers a 5 Remarks --- Test Data --- Parameter. ............................. Method.... Units PQL ....... Results... Test Data Analy -- SAMPLE PREPARATION RESULTS -- EXT/TPH SEMI-VOLATILE/W SP 3510 NA 02/04/92 JMK --- SERIES 16000 TPH-VOLATILE SPS 5030 mg/l 5 ND 02/06/92 BE --- SERIES 17000 PH-SEMI-VOL TILE EPA SFB mg/l 0.5 ND 02/05/92 RD LAW ENVIRONMENTAL, INC. NATIONAL LABORATORY 112 TOWNPARK DRIVE SAMPLING NAME OF FACILITY: ow ENNE A a', AR IA 0144 INFORMATION 4) 4 1 PI NUMBER STREET ADDRESS' 7 PR=OJEME J, vo 13- _.. , AMPLER $SIG AT RED A� � SAMPLING DATE�/3 6) LENL LAD NO iNMA SAMPLE STATIONDESCRIPTION CODE DATIE I TIME H lsmw fly y T- Y;,"d �ela� SIG 11)"e) NOTE' ALL OF THE ABOVE INFORMATION HAS BEEN TRANSCRIBED FROM ORIGINAL L IFAIL 92- /901 LAW IAINC. 11 404-4 w34 Lam Environmental, Inc L.nint Office Park 4333 Wilmont Road, Suite 300 Charlotte, NC. 282,17 Attention: Susan Fadero Subject: Chemical analysis of samples received n 01/31/92. Dear Ms. Fade:r Law Environmental National Laboratories has completedits analysis of your samples and reports the results on the following These results relate only to the o ten f the samples submitted. hi report shall not be reproduced except in full without the approval of Lacy Environmental National Laboratories. If there are any questions, please Rio not hesitate to contact us. Sincerely LAW ENVIRONMENTAL 'NATO LABS Clifford ride QC Coordinator Attachment: Data Report Invoice CASE NARRATIVE Project Name: Furr Property Date: 02/17/92 Project Number: 56-8555004 T20 This Narrative pertains to the following sample(s) submitted to Law Environmental National Labs (LENL Kennesaw) on Ja,nM4ry21_, 1992. Client ID # Lab Number Matrix Spike (MW-1) 92-1901-10 Matrix Dup (MW-1) 92-1901-11 The request to utilize sample MW-1 as the matrix spike and matrix spike duplicate for the Aromatic Volatiles (EPA 602) was accidently overlooked by the analyst. Sample MW-8 (91-1901-08) was spiked instead and the results are reported on the MS/MSD summary report. MW-1 however, was analyzed in duplicate and the results have been reported in this transmittal. We apologize for this oversight and do not expect to have a similar reoccurrence. Signed: VV LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Cate 02/ 1/92 Page 1 Lab Number 2-1901-01 Project No. : 56-855SO04 "T20 Project Name : FURR PROPERTY Manager: SUSAN FACER Station ID -: -1 Matrix T S, Collector z WA Remarks --- Project Information --- Cut;. No. --- sample Information --- Sampled Date/Time 01/30/92 15:13, Received Date/'dime 01/ 1/92 11:40 Received From/By WA"T/E S Chain of Custody 'ff 9630 Number of Containers 3 -_ 'feet Data --- Parameter .......... .......... ........ Method.... Unit ....... Results... Test Date Anal - CC ORGANIC ANALYSIS RESULTS Diohl srodifluor meth ne EPA 601 ug/l 18 ND 012/05/92 VZ Chlordmethan EPA 601 ug/1 0.80 NU 02/05/92 VZ Vinyl Chlorides EPA 601 ug/l 1.8 NU 02/CS/92 VZ Bromomethane EPA 601 ug/l 12 ND 02/05/92 VZ Chloroethane SPA 601 ug/l 5.2 ND 032/05/92 VZ Sri tlorofluor a th EPA 601 ug/l 3.2 Nth 02/05/92 VZ 1,1-D chloroethene EPA 601 g/l 1.3 ND 2/05/92 VZ Methylene Chloride EPA 6031 ug/l 2.5 ND 02/05/92 VZ trans l,2-Dichloroethene EPA 601 ug/l 1.0 N0 02/05/92 VZ 1,1°-Dichloroeth;ane EPA 601 Ug/l 0.70 ND 02/05/92 VZ Chloroform EPA 601 ug/1 0.50 NC 02/05/`92 VZ; 1, 1, 1-Trichlor ethane EPA 601 Ug/1 0.86 ND 02/05/92 VZ Carbon Tetrachloride EPA 601 ug/la 1.2 ND 02/05/92 VZ 1,2-Uichl+ roethane EPA 601 ug/l 0.30 ND 602/05/92 VZ Trichloroethen EPA 601 ug/l 1.2 N 02/05/92 VZ 1,2- ichloropr ane EPA 6031 ug/l 0.40 ND 02/05/92 VZ Sromod chloromethane EPA 601 ug/I 1.0 NC 2/05/92 VZ 2-ChloroethylvLnyl ether EPA 60ug/l 1 ND 602/035/92 VZ cis-1,3-C chloro ro ne EPA 601 ug/l 3.4 NU 02/05/92 VZ trans-1,3-LOichloro o n EPA 601 ug/l, 3.4 ND 02/05/92 VZ 1,1,2-Trichloroethah PA 601 ug/l 0.20 Nei 02/05/92 VZ Tetra.chlo oethene EPA 601 ug/l 0.96 Nib 2/05/92 VZ Uihr moth oroc thane EPA 601. ug/1 0.960 N} 02/ OS/92 VZ ChltrohenZene EPA 601 ug/l 1®C Nil 02/05/92 VZ Sromofora EPA 601 ug/l 2.0 NU 02/05/92 VZ 1, 1,2, 2--'Tetr c loro th n EPA 601 uq/1 0.30 ND 02/05/92 VZ 1,3-ichloroben ene EPA 601 ug/l 1.0 ND 02/05/92 Vz 1, 'Uichloro en ens EPA 601 ug/1 1 U 02/05/92 VZ r Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Dare + 2 / 14/92 Page 2 Lab 'Number : -1 1 - 1 Project No. : 56 66550 4 T20 --- Test data --- Parameter . ....»........,.........a.»... Method.... Unit .....,.. Results,.. 'Test Date Analy -- GC ORGANIC1 BUNTS -- 1,2-Dichlorobenzene EPA 601 / 1 1.0 ND 02/ 5/ 2 VZ Methyl -tertiary -butyl sheer (MTSE) EPA 602 /l 5.0 440 02/06/ 2 VZ Benzene EPA 602 /1 1.0 40 02/05/92 VZ Toluene EPA 62 ug/1- 1.0 1. /66/2 VZ th l enze e EPA 602 /l 1.0 10 2/ 6/ 2 VZ Xylan , "Total EPA 602 /l 2.0 24 / / 2 VZ Signed Date 2/1/92 Page LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT --- Project Information -- Lab Number 92-19 1-62 Project No. w 56-8555004 T20 Gust. Project tams FURR PROPERTY "tanager SUSAN FADER ' _-- Sample Information ,--- Station I 2 Sampled Date/Tim 11/9 15:30 MatrixReceived Date/'lime 01/31/92 11 Type Received Prom/By AT/EE9 Collector t WAT Chain of custody 963 Number f Containers Remarks -- Fast Data --- Parameter .............. ...t ..#...... Method.... units P L.... A. Results ... Test bats Analy - cc ORGANIC ANALYSIS RESULTS Dichloradifluoromethane EPA 601 a /l is NO 02/06/92 VZ chl rom than EPA 601 u /1 0.80 ND 02/06/92 2 Vinyl chloride EPA 601 Ug/l 1. 02/06/92 VZ From m th n EPA 601 a/1 12 ND 02/06/92 V chl rusth n EPA 601. ug/1 5.2 ND 02/06/92 V2 Trichl rcfluor m th n EPA 601 ug/l 3.2 Nib 02/06/92 V 1, 1- ichloro th ne EPA 601 a /l 1..3 NO 02/06/92 V Methylene Chloride EPA 601 u /l. 2.5 NO 02/06/92 VZ trans-1, 2 i hl ru th n EPA 601 ug/l 1. 02/06/92 VZ I,I-Dichloroethane EPA 601 u /l 0.70 NO 2/ 6/92 V chloroform EPA 601 u9/l 0.50 ND 02/06/92 V 1,1,1-Trschl ru than EPA 601 u /l 0.30 NO 02/06/92 VZ Carbon Tetrachloride EPA 661 a /l 1. 2/06/92 V 1,2-Dichloroethane EPA 601 ug/l 0.30 ND 02/06/92 VZ Trichloroethene EPA 601 Ug/l 1.2 ND 02/06/92 VZ- 1,2-Dichlurupr pan EPA 601 ue /1 0.40 NO 02/06/92 VZ Eromodichloro than EPA 601 u / L 1.0 NO 02/06/92 VZ 2-chloro thy ° inyl ether EPA. 601 u9/1 1.3 ails 02/06/92 V ' ris-1, -Di hl p ° pen EPA 601 ug/1 3.4 02/06/92 VZ trans-1,3-Di hl r p p n EPA 601. u9/l, 3.4 ND 02/06/92 VZ 1,1,2-Tri:chl r than EPA 601 u9/1 0.20 NO 02/06/92 V Tetrachloroethene EPA 601 u /l 0.30 STD02/06/92 VZ Dibromochloromethane EPA 601 u9/ 1 0.90 NO 02/06/92 VZ Chlorobenzene EPA 601 a /l 1.0 NO 02/06/92 V Bromoform EPA 661 Ug/l 2.0 ND 02/06/92 V 1, 1, 2, 2-T tra. hloro than EPA 601 ug/1 0.3 2/06/92 V 1,3-Di.chlora n ens EPA 601 ug/lY 1 2/06/92 VZ 1, - ichlorobenzen EPA 601 a /l 1-0 ND 02/06/92 V Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 1/9 Page Lab Number : 9 -19 1 02 Project N. s 5 ,-955 T20 --- Test Data --- Parameter ........ ..................... Method.... emit L ....... Results... Teat Pate Analy -- GC ORGANIC ANALYSIS RESULTS ,2- i hloro a EPA 601 Ug/1, 1.0 N / 6/9 Methyl -tertiary -butyl. ether { * BEPA 602 ug/1 S.0 N / 6/9 Benzene'PEA 602 Uq/1 1.0 N / 6/9 Toluene EPA 602 Uq/1 1.0 ND 0/ 6/9 Ethylbenzene EPA 602 ug/1 1.0 ND / 6/9 Xylene, 'Total EPA 602 ug/l, ND 0/ 6/9 LAID ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/14/92 ?age 1 Lab Number : 52�190 Project Name - .« Manager: SUSAN FADERO Station I -3 Matrix ' Type : GRAB Collector r WAT -- Project information -- Cunt* No. . -_- Sample Information --- Sampled ile Date/Time 01/30/92 1 z3 Received Date/"ire 1/1/92 11:4 Received Fr m/ AT/EE Chain of Custody 963 Number of Containers -- Teat Data Parameter ..... .......... ......m.., b. Method.... Units P ....... Results... Teat Nate Anal -- GC. ORGANIC ANALYSIS RESULTS ichl rod fluor eth n EPA 601 u /1 16 ND 02/06/92 V hlor meth ne EPA 601 /l 0.80 ND 02/06/92 VZ Vinyl Chloride EPA 601 /l 1.E ND 02/06/92 VZ Eromomethane EPA 601 u /1. 12 NO 02/06/92 V hlo°ethane EPA 61 u/l 6.2 ND 02/06/92 VZ Trichlorof uoro ethan EPA 601 ug/l 3.2 ND 02/06/92 V 1,1-IDichloroethenEPA 661 a/1 1.3 ND 02/06/92 VZ Methylene Chloride EPA 601 u /l 2.5 ND 02/06/92 VZ trans,-1,2-Dichloroethene EPA 601 ug/1 1.0 ND 02/06/92 V 1, 1- Dichlotn th n EPA 601. Ug/l 0.7 ND 02/06/92 VZ Chloroform EPA 601 uD9/l 0.50 ND 02/06/92 VZ 1, 1.1-Tric lcrc> t,ha¢ EPA 601 u /l 0.30 ND 02/06/92 VZ Carbon Tetrachloride EPA 611 u /1 1.2 NO 02/06/92 6/92 1,2-Dl chloroethane EPA 661 a /l 030 NO 02/06/92 VZ Trichlsrc there EPA 601 a /l 1.2 ND 02/06/92 1.,2-Dichl ropr span EPA 601 ug/1 0.40 DAD 02/06/92 V Promodichloromethan EPA 601 a /l 1. ND 2/06/92 V 2-Chloroethylvinyl ether EPA 601 u /l 1.3 ND 02/06/92 ' cis-1,3-Dichlorop ` n EPA 601 ug/l 3.4 ND 02/06/92 VZ trans 1, Dichloropropen EPA 601 u9/1 3.4 ND 02/06/92 i 1, 1, `3-Trl.chlor+ ethan EPA 601 a /l 0.20 ND 02/06/92 V Tetrachloroethen EPA 601 ua3/l 0.30 ND 02/06/92 VZ Di%romochloromethan EPA 601 uDl/l 6.96 NOD 02/06/92 VZ hl.oroten ene EPA 631 u /l 1.6 N 2/06/92 VZ rcm form EPA 601 u+ /l 2.0 ND 02/06/92 VZ 1,1,2,2-Tdtrachloro than EPA 601. Ug/l, 0.30 ND 02/06/92 VZ 1,3-Dichlorobenzens EPA 661 Ug/1 110 ND 02/ 6192 t 1,4-Dichi roben ene EPA 601 u /l 1.0 NO 02/06/92 VZ Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA O T Date 32/1/2 Page Lab Number : -1 --0 Project N. : 56«-5555 T2 _-- Test Data --- Parameter ...................... .... .... Method.... Units P ....*.. Results... Test Date Analy -- GO ORGANIC ANALYSIS RESULTS -- 1,2 l lalc r b n n EPA 601 a/1 1.0 NO 02/ 6 92 VZ methyl -tertiary -butyl ether ( ) EPA 602 u /l 5.0 6.5 02/ 6/ 2 VZ Benzene EPA 602 u /1 1.10 1.3 2/ 6/°2 V Toluene EPA 602 u /l 1.0 3. 2/ 6/ 2 V EthylbenzeneEPA 62 gag/1 1.0 NO 02/06/92 VZ 1. n , Total EPA 602 u /1 2.0 9.5 2/ 6/ 2 V Signed LAW ENVIRONMENTAL NATION 'LABORATORIES TEST DATA REPORT 2/17/92- I, --- Project Information --- Lab Number ; 92-19 1.- 4 Project No. ; 56-8555004 T20 Cram. No. Project Name : PURR PROPERTY Manager: SUSAN FADERO Sample Information --- Station ID : -4 Sampled Date/Time 1/3 /9 15:37 Matrix : W ReceivedDate/Time : 01/31/9 11:40 Type GRAB Received,From/ByWAT/EES Collector WAT, Chain of Custody9630 Number of Containers ; 3 Remarks -- Test data --- Parameter ................A............Method.... mite -- GC ORGANIC ANALYSIS RESULTS Dichlorodifluoromethane EPA 601 gag/i Chloromethane EPA 61 /1 Vinyl Chloride EPA 601 g/1 Bromomethane EPA 601 u/ l hl.nrethn :PA 61 / 1 'rihlrflur:ethh EPA 61 e 1,1-Dichloroethene EPA 601 u /l Methylene Chloride EPA 51 as/l tr n 2,2 Dich r et ene EPA 601 t /1 1,1 1 hlor eth ne EPA 601 a /l- Chloroform EPA 601 tag/l. 1, 1,1-Trichl r° th nd EPA 601 a /l Carbon Tetrachloride EPA 601 /l 1, 2--D i. h l methane EPA 601 u/ Trichloroethene EPA 601 u / 1,2-'ihlrprdpn EPA, 661 1 6resdihlerethene, EPA 61 u/; 2a hleroeth l in l ether EPA 601 a /l i s- , 3- irhl r apr pen EPA 601 a / l: trans-1, 3- ichlereprn rye EPA 601 u+ / 1,1,2-Tri hl e th h SPA 601 ug/1 Tetrachloroethene EPA 601 u /l Di. r c e hlar met e Epp, 601 1 hl r den ene EPA 601 ug/l Bromoform EPA 61 u/. 1,1,2,2-Tetrahlrthend EPA 61 u9/l 1, 1-tli hlor he rene EPA 601 u /l 1, - i hl r benzene EPA 631 /l PQL ...... Results— Test Date An l 9 /6/92 V" 4. 2/6/92 VZ 9. 2/6/92 V 60 ND 02/06/92 VZ 26 2/6/92 VZ 16 ND 02/06/92 VZ 6.5 ND 02/06/92 VZ 2 ND 02/06/92 VZ 5.0 ND 02/ 6/92 VZ 3.5 ND 02/06/92 V 2.5 ND 2/ 6/92 VZ 1.5 ND 02/ 6/ 2 VZ 6.0 ND 02/06/92 VZ 1.5 ND 02/06/92 VZ 6.o ND 2/ 6/92 VZ 2. 2/6/92 VZ 5. 2/6/92 VZ. 6.5 ND 02/06/92 VZ 17 ND 02106/92 VZ 17 ND 02/06/92 VZ 1. 2/6/92 VZ 1.5 ND 02/06/92 VZ 4m 2/6/92 VZ 5.. 2/6/92 `Z 10 ND 02/06/92 VZ 1.5 ND 02/06/92 VZ 5.0 ND 02/ 6/92 VZ 5.0 ND 02/ 6/92 VZ SignedXd LAW ENVIRONMENTAL NATI PIES "EST DATA REPORT Date 2/1/92 Page 2 Lab Number : 92-1901-04 Project No. z 5 - 55 T20 --- Test Data --- Parameter . .... ............... ........ Method.... Units P L... 4v . Results... Test Date Analy ORGANIC'5 -- 1,2-Dichlorobenzene EPA 601 / 02/ 6/92 VZ t -t r r ty ether (M EPA 602 ug/l 25 800 02/06/92 V Benzene EPA 602 u /1 5.0 160. 2/ /92 V Toluene EPA 602 u /l 5..0 ND 02/06/92 V Ethylbenzene EPA 602 u9/1 5.0 40 02/06/92 VZ Z l n, Total EPA 602 a /l 10 70 02/06/92 VZ LAW ENVIRONMENTAL NATIONAL, LABORATORIES TEST DATA REPORT Date2/14/92 Page' __- Project Information ---- Lab Number ; --19 1- 05 Project No. 56-8555004 T2 Project Name FURR PROPERTY Manager: SU aAN FADERG --- Sample Information --- Station I MW-5 Sampled bate/'Tine 1/3 /92 15:45 Matrix : W Received Late/Time : 01/31/92 11:40 Type Received From/By : WAT/EE Collector m WAT Chaim of Custody 9636 Number of Containers . Z Remarks --- Test Data --- Parameter ......................... ..... Method.... Units P L— .. Results... 'Peet Date Analy GG ORGANIC ANALYSIS RESULTS ichlorodifluoroethane; EPA 61 g/l is ND 02/06/92 VZ hloromethane EPA 601 ug/l 0.60 ND 02/06/92 VZ Vinyl Chloride EPA 601 ug/l 1.8 ND 02/06/92 VZ Eromomethane EPA. 601 ug/l 12 ND 2/06/92 VZ Ghloroethane, EPA 61: ug/l 5.2 ND 02/06/92 V "Trichloro'luoremethane EPA 601 ug/l 3.2 NU 02/06/92 VZ 1.,1-Dichloroethene EPA 601 ug/1 1.3 ND 02/06/92 VZ Methylene Chloride EPA 601 ug/, 2.5 ND 02/06/92 VZ trans-1,2--Dichloroe hene EPA 6E1 ug/l 1.6 Nib 2/06/92 VZ 1,1-9ichleroethane EPA 601 ug/l 0.70 NO 02/06/92 VZ Chloroform EPA 601 ug/l 0.50 ND 02/06/92 VZ 1,1,1-Trichloroethane EPA 601 ug/l 0.30 ND 02/06/92 VZ Carbon Tetrachloride EPA 601 Ug/l 1.2 Nib 02/06/92 VZ 1, 2- Diehl rcet ne EPA. 601 Ug/l 0.302/06/92 VZ Trichlor°oethen EPA 601 ug/l 1.2 ND 02/06/92 VZ 1 , 2- ichl ro-propane EPA 601 g/l 0.40 ND 02/06/92 VZ 5romodich oromethane EPA 601 ug/l 1..6 ND 02/06/92 VZ 2-Gh oroethylvinyl ether EPA 601 ug/I 1.3 ND 02/06/92 VZ cis,-1, 3-D chlorc sro ene EPA 661 ug/l 3.4 ND 02/06/92 VZ trans-1, -Dichloro ropene EPA 601 ug/lu 3.4 NO 02/06/92 VZ 1,1,2-Trichlor ethane EPA, 601 ug/l 0.20 ND 02/06/92 VZ Tetrachloroethene EPA 601 Ug/1 0.30 ND 02/06/92 VZ Uibr moch pros ethane EPA: 601 ug/1 0.90 ND 02/06/92 VZ hl rober ene EPA 601 ug/l 1.0 ND 02/06/92 VZ Bromoform EPA 601 ug/1 2.0 ND 02/06/92 VZ 1,1,2,2-Tetrachlor ethane EPA 601 ug/1 0.30 ND 02/06/92 VZ 1,3-Dichlorobenzene EPA 60ug/1 1.0 NO 02/06/92 V 1,4-Uichl;oroben ene EPA 601 ug/1 1.0 ND 02/06,/92 VZ Signed � LAW ENVIRONMENTAL NATIONAL LABORATORIES °T DATA REPORT Data 02/1 /9 Page Lab Number : 92-1961-05 Project No. : 56 6666 2 - Teat Data --- Parameter ...................... ....<.. Method.... Units T L........ Results... Teat Date Analy ORGANIC ANALYSIS RESULTS 1,2-Dichlorobenzene EPA 601 u 1 1. 2/ 6 f 92 V Methyl -tertiary -butyl ether (ELT EPA 602 ug/1 5.0 TAD /06 Toluene EPA 602 Ug/1 1.0 ITT! 6/92 VZ i n , Total EPA 602 9/1 2.0 ND 02/06/92 V r Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 2/14/92 Page __- Project Information ®_- tab Chamber : 2-1901-06 Project No. : E6-E555 04 T20 Cust. No. Project Name : FURR PROPERTY Manager: EC16A 1 FADERO -- sample Information --- Station bE : -6 Sampled Date/Time : 01/9 /92 15:4 Matrix : W Received Date/Time 91/ 1/ 11:4' Type : GRAB Received From/By : WAT/EEE Collector : WAT Chain of Custody 963 Number of Containers : 3 Remarks --- 'cat Data. --- Parameter ................... .................... Method.... Units P T........ Results... Test Date Analy -- GC ORGANIC ANALYSIS RESULTS; lrhl r diflu r methane EPA 601 ug/l 1E ND 02/06/92 V Eh or me hane EPA 601 /1 0.80 ND 02/06/92 VZ Vinyl Chloride EPA. 601 ug/1 1.E ND 02/06/92 VZ Er m methane EPA 601 dg/l 12 NE 02/06/92 V hlor ethane EPA 601 /l 5.2 Nil 02/06/92 V2 richl rofluoro ethane EPA 601 ug 3.2 NCI 02/06/92 V 1,1- 1l hlor ethene EPA 601 ug/1 1.3 ND 02/06/92 VZ Methylene Chloride EPA 601 ug/1 2.5 ND 2/06/92 vz trans-1 , 2- Dichler ether EPA 601 ug/1 1.0 ND 02/06/92 VZ 1, 1-Elchlntoethane EPA 601 ug/l 0.70 ND 02/06/92 V Chloroform EPA 601 ug/l 0.50 ND 02/06/92 V 1, 1-Tri hlor ethane EPA 601 :g/1 0.30 ND 02/06/92 VZ Carbon Tetrachloride EPA 601 ug/l 1.2 NE 02/06/92 VZ 1,2-Dichloroethane EPA 601 Ug/1 0.30 NE 02/06/92 VZ Erl hloroethene EPA 601 g/l 1.2 ND 02/06/92 VZ 1, 2-91 hl aropropane EPA. 601 ug/l 1.4E NE 02/06/92 VZ From dlehl r methane EPA 641 ug/1 1.0 ND 02/06/92 V 2z- hl roethylvinyl. ether EPA 601 ug/1 1.3 Nil 02/06/92 V la-1 3- 1 hl:a Pr a n EPA 601 ug/l 3.4 ND 02/06/92 V trans- , 3-Di hl rr P Pens; EPA 601 a /1 3.4 NO 02/06/92 VZ 1,1,2-Trichloroethane EPA 601 ug/l 0.20 ND 02/06/92 VZ Tetra hl r e hene EPA. 601 ug/1. 0.30 ND 02/06/92 VZ Dibromo hlbr :methane EPA 601 Ug/1 0.90 NE 02/06/92 V hlor ben ens EPA 661 ug/l 1.0 NO 02/06/92 V Bromoform EPA 601 ug/l 2.0 ND 02/06/92 VZ 1,1,2,2RT t.ra hl r e hane EPA 601 ug/1 0.30 ND 02/06/92 VZ 1,3-Di hl robenxene EPA 601 ug/1 1.0 ND 02/06/92 VZ 1,4-E . hlc roben ene EPA 601 ug/l 1.0 ND 02/06/92 V Signed Eaa� LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/14/92 Page 2 Lab Number : 92-1901-06 Project No. : 56-8555004 T20 --- Test Data --- Parameter .................. ............ Method .... Units PQL.— .... Results ... Test Date Analy -- GC ORGANIC ANALYSIS RESULTS -- 1,2-Dichlorobenzene EPA 601 Ug/l 1.0 ND 02/06/92 VZ Methyl -tertiary -butyl ether (MIRE) EPA 602 ug/l 5.0 18 02/06/92 VZ Benzene EPA 602 Ug/1 1.0 ND 02/06/92 VZ Toluene EPP, 602 ug/1 1.0 ND 02/06/92 VZ Ethylbenzene EPA 602 fag/1 1.0 ND 02/06/92 VZ Xylene, Total EPA 602 Ug/l 2.0 ND 02/06/92 VZ SAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/14/92 Page --- Project Information -- 1,ab Num r :-i70.L-- Project No. s: 56-8555004 T2 Project Name ; FURR PROPERTY Manager: SUSAN FADERO Station I Matrix Tyra R Collector : DRAT u t . No. --- Sample Information --- Sampled Date/Time w 01./3 /92 16: 6 Received Date/"Time i 01/31/92 11:40 Received Prom/By T/ R6 Chain of Custody 963 Number of Containers m ®-- Teat data --- Parameter ........... .... ............. Method.... Units P L....... Results... Teat Date Analy __ GC ORGANIC NALYS S RESULTS IDichl rr difluor meth n EPA 601 uq/1, 19 ND 02/06/92 ii hl ar c eth ne EPA 601 ug/l 0.80 ND 02/06/92 VZ Vinyl Chloride EPA 601 ug/1 1.8 ND 02/06/92 VZ r mo ethane EPA 601 ug/l 12 ND 2/06/92 VZ Chloroethane EPA 601 XJg/l 3.2 ND 02/06/92 VZ Trichlorofluoromethane EPA 601 gag/1 3.2 ND 02/06/92 VZ 1, 1-iDichlor Seth n EPA 601 ug/1 1,3 ND 02/06/92 VZ Methylene Chloride EPA 601 ug/l 2.6 ND 02/06/92 VZ trans , 2- ichl aroeth n EPA 601 ug/1 1.0 ND 02/06/92 VZ , 1-DD chlcr reth n PDT 601 ug/1 0.70 NO 02/06/92 VZ Chloroform EPA 601 ug/1 0.50 ND 02/06/92 VZ 1, 1, 1 Trichloro than EPA 601 ug/l 0.30 ND 02/06/92 VIZ Carbon Tetrachloride EPA 601 ug/l 1.2 ND 02/06/92 VZ 1, 2-DDichl :r ethane EPA 601 ug/1 0.30 ND 02/06/92 VZ Trichlo n +bhene PPP 661 ug/1 1.2 ND 02/06/92 vz 1,2- ichl r pr an EPA 601 ug/l 0.40 ND 02/06/92 VZ Promodichlorum th n EPA 601 ug/I 1.0 ND 02/06/92 VZ 2-chlornethylvi yl other; EPA 601 rag/1 1.3 ND 02/06/92 V cis 1,3- ichlor pr pen EPA 601 ug/1 3.4 ND 02/06/92 V trans- , 3-DDi hl r pene EPA 601 ug/l 3.4 DAD 02/06/92 V 1,1, 2-Tr dhlr r ethan EPA 601 ug/l 0.20 ND 02/06/92 BIZ Tetr chlor eth n PA 601 ug/1 0.30 ND 02/06/92 VZ Dibromochlaromethane RPM, 601 ug/l 0.90 ND 02/06/92 VZ hloroben en EPA 601 ug/1 1.0 ND 02/06/92 BIZ DDrom form EPA. 601 g/l 2.0 ND 02/06/92 VZ 1, 1, 2, 2-T trachl ro thane EPA 601 ug/ � 39 NO 02/06/92 VZ 1, 3 DDi.chl robenren EPA 661 ug/1 1.0 ND 02/06/92 VE 1,4-Dichlarobenzene EPA 601 ug/1 1.0 ND 02/06/92 VZ; Signed 4L� -,iu" LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 2/1.4/92 Page Lab Number ; 92-1901-07 Project No. : 56 855 0 4 T20 a_.. Test Data --- Parameter....... .... ..... ............. Method.... Emits 9 L, ....... Results... Test Cate Analy -- CC ORGANIC ANALYSIS RESULTS -- 1, 2-Diehl pro n EPA 601 ug/1 1.0 ND / v Methyl -tertiary -butyl ether (H EPA 602 uq/ 1 5.0 47 2 VZ Benzene EPA 602 9/l 1. 2/ 6/92 VZ Toluene ERA 602 is/1 1. 6/92 VZ thylbenzen ERA 602 + / ,, 1.0 ND 02/06/92 VZ len , Total EPA 602 '/1_ 2.0 ND 02/ 6/92 VZ 11 Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 2/14/92 Page 1 ---- Project Information -- Lab Number ¢-1901-08 Project No. 56-8555004 V23 Cust. No. Project Name : 'FURR PROPERTY Manager SUSSUSAN FADERO . - Sample Information --- Station ID MW-B Sampled gate/Time : 01/30/92 16.6 Matrix ; W Received Date/`dime : 1/31/92 11:4 Type Received From/By : WAT/EES Collector : WAT Chain of Custody :: 963 Number of Containers Pemarl�a -_- Test Data --- Parameter .......... ... Method.... Units P T,....... Results... Teat Date ,Deal} -- GC ORGANIC ANALYSIS RESULTS Dichlorodifluoromethane EPA 601 ug/1 18 NO 02/06/92 VZ hl+r urethan EPA 601 ug/1 0.6 02/06/92 VZ Vinyl Chloride EPA 601 ug/1 1.6 ND 02/06/92 VZ Sr+ moethan EPA, 601 ug/ L 12 ND 02/06/92 V hl r ethane EPA 601 ug/1 5.2 NO 02/06/92 V Trichlorofluoromethane EPA01 ug/ l 3.2 Nth 02/06/92 VZ i, -ichloroethene EPA 601 ug/1 1.3 NO 02/06/92 VZ Methylene chloride ERA 661 ug/1 2.3 NO 2/06/92 VZ trans l,2 i hlar et ens EPA 601 ug/l 1.0 ND 02/06/92 VZ 1, 1.-[Di hl r et ane EPA 601 ug/1 0.70 NO 02/06/92 V - chloroformEPA 601. Ug/l 0.50 ND 02/06/92 VZ 1,1,1-Trichloroethane SPAS 601 ug/l 0.30 NO 2/06/92 VZ Carbon Tetrachloride EPA 601 ug/l 1.2; NO 02/06/92 VZ 1,2- i hler ethane EPA 661 ug/l 0.3 02/06/92 VZ Trichloroethene EPA 601 Ug/1 1.2 ND 2/06/92 VZ 1,2-ichl r pr pane EPA 601 ug/l 0.40 ND 02/06/92 VZ Bromodichloromethane EPA 601 ug/1 1.0 NO 02/06/92 VZ 2-Chloroethylvinyl ether EPA 601 ug/ . 1.3 NO 02/06/92 V ci -1,3- 1chl ropr gene EPA 601 ug/l 3<4 ND 02/06/92 V" t an -1,3 TDichl r p pen EPA 601 g/l 3.4 NO 02/06/92 VZ 1,1,2 ri hl r ethane EPA 661 ug/l 0.20 NO 02/06/92 VZ' Teti . hlnroeth ne EPA 601 ug/1 6.30 ND 02/06/92 V Dibromochloromethane EPA 601, ug/1 0.90 ND 02/06/92 VZ hl r uben ens EPA 601 ug/ 1 1.0 ND 02/06/92 VZ Bromoform EPA 601 ug/1 2.0 NO 02/06/92 VS 1,1,2,2-Tetra hlar ethane SPA 601 ug/1 0.30 ND 02/06/92`tile 1,3-Dichlorobenzene EPA 661 ug/1 1.0 ND 2/06/92 VZ 1, -Di hl roben ens EPA 601 Uq/1. 1.0 ND 02/06/92 VZ Signed D LACE ENVIRONMENTAL NA IONA LABORATORIES TEST DATA REPORT` Data 2/14/92 Page 2 Lab Number : 92-1901-08 Project No. : 6-566 Ci4 T20 --- "feat Data --- Parameter ............. ——............. Method.... Units P L« ...... Results... feat Tate Ahaly CSC ORGANIC ANALYSIS RESULTS,' 1 2-Di hlo oben EPA 601 Ug/l 1.0 ND 2/06/ 2 VZ Methyl -tertiary -butyl ether (MTBE) EPA 602 Ug/1 5.02/ 6/ 2 VZ Benzene RSA 602 /1 1.0 RT 2/06/ 2 VZ Toluene n SPA 662 /l 1.0 NTH / 6/ 2 VZ Ethylbenzene EPA 602 /l 1.0 ND 02/06/ 2 VZ yl en , Total SPA 602 a / l 2.0 D / 6/ 2 y Signed LAB ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02117/92 Wage _ - Project Information --- Lab Number 2-191-69 Project No. s 56 8555004 120 Cult. No. Project Name z FURR PROPER' Manager: SUSAN FADERO --- Sample Information --- Station 1 , - l Sampled Date/Time l/ 0 16:07 Matrix " Received Date/Time 01/ 1192 11:40 Type GRAS Received From/By NA E S Collector WAS Chain of Custody : 9630 Number of Containers : 6 Remarks Teat Data --- Parameter ....... ..........I ......Method.... units P 1..... .. Results... Test Este A aly -- -- INORGANIC CHEMISTRY RESULTS Chemical Oxygen Demand EPA 410.. mg/1 5 NO 02/07/92 AAT Chloride EPA 325.3 a /l 0.2 11 02/ 5/92 EC Residue, ion Filterable ( SS) EPA 160.2 m /l 10 490 02/ 1/92 S True Color EPA 110.2 P.C.U. 5 ISO 1/31/92 EC Turbidity EPA 180.1 U.T.U. 0.7 110 01/31/92 BC -- -- METALS ANALYSIS - METALS PREP RESULTS Iron, Dissolved EPA 6010 m /l 0.1 1.7 02/04,/92 JST --- SERIES 35000 Dissolved Metals Prep; Aqueous ICP EPA 3010 N/ 2/02 2 HH -- CC ORGANIC ANALYSIS RESULT ®- Cichlc°cdifl.umethsne EPA 61 u/l 90 Nib 2/07/92 V Chlor methane EPA 601 u /l 4.0 ND 02/07/92 VZ Vinyl Chloride EPA 601 a /l 9.0 NO 92/07 92 V' P cmdmethane EPA 601 a/1 60 ND 02/07/92 VZ Chloroeth ne EPA 601 a /l 26 ND 02/07/92 VZ Trichlorofluoromethane EPA 601. 1, 16 ND 02/07/ 2 VZ 1,1-ichlrethene- EPA 61 /l 6.5 NO 12/792 V Keth lease Chloride EPA 601 a/1 12 ND 12/07/92 VZ trans-1, 2-Pichlc ° eth e EPA 601 /l 5.0 ND2/07 92. VZ 1,1-Dlchld cethane EPA 601 /l 3.5 ND 02/07/92 V Chloroform EPA 601 u /1 2..5 ND 2/ 7/92 VZ 1,1,1 i hlc ethane EPA 60 a /l: 1.5 NC 2/07/92 V Carbon Tetrachloride EPA 601 u9/1 6.0 ND 02/07/92 v72 1,2-Dichloroethane EPA 601 ug/l 1.5 N} 2/07 2 VZ Trichlaroethene EPA 601 a/1 6.0 ND 02/07 92 V LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/17/92 Page 2 Lab Number : 92-1901-09 Project No. : 56-8555004 T20 --- Test Data --- Parameter ....... — ..................... Method .... Units PQL ....... Results... Test Date Analy -- GC ORGANIC ANALYSIS RESULTS 1,2-Dichloropropane EPA 601 g/l 2.0 ND 02/07/92 VE Bromoth chloromethane EPA 601 ug/l 5.0 ND 02/07/92 VZ 2-Chloroethylvinyl ether EPA 601 ug/l 6.5 ND 02/07/92 VZ cis-1,3-Dichloropropene EPA 601 ug/1 17 ND 02/07/92 VZ tran s-1,3-Dichloropropene EPA 601 ug/1 17 ND 02/07/92 VZ 1,1,2-Trichloroethan e EPA 601 ug/l 1.0 NO 02/07/92 VZ Tetrachloroethene EPA 601 ug/l 1.5 ND 02/07/92 VZ Dibromochloromethane EPA 601 ug/l 4.5 ND 02/07/92 VZ chl,oroben zene EPA 601 Ug/1 5.0 ND 02/07/92 VZ Bromoform EPA 601 ug/1 10 ND 02/07/92 VZ 1,1,2,2-Tetrachloroethane EPA 601 Ug/l 1.5 ND 02/07/92 VZ 1,3-Dichloroben zene EPA 601 ug/l 5.0 ND 02/07/92 VZ 1,4-Dichloroben zone EPA 601 ug/l, 5.0 ND 02/07/92 VZ 1,2-Dlchlorobenzene EPA 1 ug/l 5.0 ND 02/07/92 VZ Methyl -tertiary -butyl ether (MTBE) EPA 602 ug/l 25 70 02/07/92 VZ Benzene EPA 602 ug/1 5.0 60 02/07/92 VZ Toluene EPA 602 ug/1 5.0 12 02/07/92 VZ Ethylbenzene EPA 602 ug/1 5.0 30 02/07/92 VZ Xylene, Total EPA 602 ug/l 10 60 02/07/92 VZ signed LAW AL 112TONWWDRK IA30144-5599 40"21-3400 February 19, 1992 Lam Environmental, Inc. LakePoint Office Park 333 Wilmont Road, Suite 300 Charlotte, NC 28217 Attention: Susan Fadero Subject: Revised report of samples received n 01/31/92. Dear Maw adr Law Environmental National Laboratories has revisedits chemical analysis of your samples and reports the results on the following pages. These results relate only to the contents of the samples submitted. This report shall not be reproduced except in full without the approval Laws Environmental National Laboratories. If there are any questions, please do not hesitate to onta t us. sincerely, LAW ENVIRONMENTAL L LABS Clifford H. McBride QC/Coordinator i Attachment: Data Report LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/14/92 Page I --- Project Information --- Lab Number ; 92-1901-11 Project No. : 56-8555004 T20 Cust. No. : Project Name : FURR PROPERTY Manager: SUSAN FADERO --- Sample Information --- Station ID : MW-1 (DUPLICATE) Sampled Date/Time : 01/30/92 15:13 Matrix ; W Received Date/Time : 01/31192 11:40 Type : GRAB Received From/By : WAT/EEs Collector : WAT Chain of Custody : 9630 Number of Containers : 3 Remarks : --- Test Data --- Parameter ..................... Method.... Units PQL ....... Results... Test Date Analy -- GO ORGANIC ANALYSIS 'RESULTS Methyl -tertiary -butyl ether (MTBE) EPA 602 Ug/l 5.0 480 02/08/92 VZ Benzene EPA 602 ug/l 1.0 26 02/06/92 VZ Toluene EPA 602 ug/l 1.0 3.0 02/06/92 VZ Ethylbenzene EPA 602 ug/l 1.0 12 02/06/92 VZ Xylene, Total EPA 602 ug/I 2.0 25 02/06/92 VZ Signed LAW ENVIRONMENTAL IATION LABORATORIES "BEST DATA REPORT Cate 2/1/2 Cage --- Project Information --- Lab Number , 2 1 01 1 Project No. : 56-8555004 T20 Cust. No. Project Name FURR PROPERTY Manager: "SUSA FAD Rt --a Sample Information --- Station I 1 (TRIPLICATE) Sampled Date/Tim 1/ / 2 15: 3 Matrix Received Date/Time 1/31/ 11:40 Typea GRAB Received From/By AT/R collector WAS Chain of Custody 9630 Number of Containers 3 Remy --- "hest Data --- Parameter .......... .................... Method.... Units P 1....... Results.,. Test Date Analy ORGANIC ANALYSIS RESULTS -- Methyl-tertiary-butyl ether { RS} EPA 602 ug/1 5.0 37 / 7/ 2 VZ Benzene EPA 602 g/l 1.0 25 02/06/92 VZ Toluene EPA 602 /l; 1.0 NO 02/06/92 VZ Ethylbenzene EPA 602 /l 1.0 12 2/ «/ 2 VZ len , Total EPA 602 a/1 2.0 25 2 / 2 VZ LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA. REPORT Data 02114,/92 Page --- Project Information --- Lab Number m 92-1901-13 Project No. : 6-8555004 T20 Project Name : FURR PROPERTY' Manager: SUSAN FAD "NO -_- Sample Information -- - Oust. No. . Station 10 , METHOD BLANK pled Date/Tim / Matrix $ Received Date/Time- / / Type Received From/By Collector Chain of Custody 0 Number of containers 0 Remarks "Teat Data --- Parameter..... ..........,.............. Method.... Unit, Test Date Analy -- 00 ORGANIC ANALYSIS RESULTS Oichlorodifluoror than EPA 601 ug/1 16 ND 02/05/92 V Ohlor m than EPA 601 ug/1 0.80 ND 02/05/92 VZ Vinyl Chloride EPA 601 ug/1 1.8 NO 02/05/92 V Bromomethane EPA 601 ug/ l 12; N0 02/05/92 VZ Ohloro than EPA. 601 Ug/1 5.2 ND 02/05/92 VZ Trichl rof uor m than EPA 601 Ug/l 3.2. ND 02/05/92 1,1-illchloroath n EPA 601 ug/l 1.3 N0 02/05/92 V Methylene Chloride EPA 601 ug/l 2..5 NO 02/05/92 VZ trans-1,2-Dichloro than EPA 601 ug/l 1.0 NO 2/05/92 VZ 1,1 Oichl ro than EPA 601 ug/I 0.70 ND 02/05/92 VZ Chloroform EPA 601 ug/l 0.50 N0 2/05/92 VZ 1,1.,1-Trtchlord thane EPA 601 Uq/1 0.30 N0 02/05/92 VZ Carbon Tetrachloride EPA 601 ug/< 1.2 NO 02/05/92 VZ 1,2 ichl ro than EPA 601 ug/1 0.30 N0 02/05/92 Vz Trichlorothna EPA 601 g/l; 1.2 N7 020592 VZ 1,2-Dichloropr ana EPA 601 ug/I 0.40N0 02/05/92 V Bran dish orom than EPA 601 ug/I 1.0 N0 02/05/92 VZ 2-hl. ro th 1. i yl ether EPA 601 Ug/11.3 ND 02/05/92 cis-1,3-Dichloro ro n EPA 601 ug/l 3.4 ND 02/05/92 ti trans-1, 3°-Oichloro ro n EPA 601 ug/l 3.4 N0 02/05/92 VZ 1,1,2-Trichlarnathan EPA 601 ug/1 0.20 NO 02/05/92 VZ T trachlo o th na EPA 601 ug/1 0.30 ND 02/05/92 VZ Oibrcmochlorom than EPA 601 ug/1, 0.90 N0 02/05/92 VZ Ohlo°oh n an EPA 601 ug/l 1.0 ND 02/05/92 V Bromoform EPA 601 ug/1 2.-0 ND 02/05/92 VZ 1,1,-2,2-Tatrachloroathan EPA 601 ug/l 0.30 N0 02/05/92 VZ 1,3-OichloroL n an EPA 601 ug/l 1.0 ND 02/05/92 VZ 1,4-Dichlarobenzene EPA 601 Ug/1 1.0 N0 02/05/92 VZ Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES "BEST DATA REPORT; Date /1 /92 Page Lab Number :-1901-13 Project No. : 56-855500 I"20 --- Test Data --- Parameter te.-.....„................,......... Method.... Units L.....-. Results.... Test Date Analy - - GC ORGANIC N YS RESULTS -- 1., -Dick .o enzen EPA 601 auq/1 1.0 rite 02/05/92 V methyl -tertiary -butyl ether (MTBE) EPA 602 . /1 5.0 ND 02/05/92 VZ Benzene EPA 602 sag/l 1.0 ND 02/05/92 VZ Toluene EPA 602 /1 1..0 ND 02/05/92 V Ethylbenzene EPA 602 u9/1 1.0 ND 02/05/92 VZ ylen , Total EPA 602 ug/1 2.0 ND 02/05/92 VZ Signed LAW ENVIRONMENTAL ATIO LABORATORIES TEST DATA REPORT Date 02/1 /92 Page I I Lab Number : 92-1901-1 Project No. : 56-8555004 T20 Project Name c 'FU R PROPERTY Manager: SUSAN FAOERO Station I0 ETli00 BLANK Matrix : W Type collector Remarks Project. w --_ Sample Information --- Sampled Cate/'dime Received Date/Time Received From/By Chain of custody0 Number of Containers 0 Test Data --- Parameter ..................... ........ Method.... units P L....... Results... Test Date Analy -- 00 ORGANIC ANALYSIS RESULTS Dichldrod fl#unr meth ne EPA 601 ug/l 18 ND 02/06/92 VZ hl rdmethane EPA 601 ug/l 0.80 ND 02/06/92 V vinyl Chloride EPA 601 ug/l 1.6 RO02/06/92 VZ Brcmomethane EPA 601 ug/1 12 ND 02/06/92 V8 hlor etha€e EPA 601; ug/l 5.2 ND 02/'06/92 VZ Trichlorofluaromethane EPA 601 ug/l 3.2 ND 02/06/92 V 1,1-Dichl roethen EPA 601 ug/l 1>3 ND 02/06/92 V Methylene chloride EPA 601 ua/1 2.5 R0 2/06/92 V trans 1,2- ichl r ethen EPA. 601 ug/l 1.0 ND 02/06/92 Vz 1,1Oichlethane EPA 601 ug/l 0.0 M0 02/06/92 VZ chloroform EPA 601: ug/l 0.50 ill. 02/06/92 VZ: 1,1,1-Trichloroethane EPA 601 ug/l 0.30 ND 02/06/92 VZ Carbon Tetrachlorides EPA 601: ug/l 1.2 ND 02/06/92 VZ 1,2-Oichlorcet.h ne EPA 601 ug/l 0.30 ND 02/06/92 VZ Trichloroethene EPA,. 601 ug/l 1.2 ND 02/06/92 VZ 1, 2-Dichloropropan EPA 601 ug/l 0.40 M0 02/06/92 VZ Brom dichl arum thane EPA 601. ug/l 1.0 ND 02,/06/92 VZ 2-Ohl rceth l inyl ether EPA 601 ug/l 1.3 ND 02/06/92 VZ cis-1,3-Dichloropropene SPA 601 ug/l 3.4 ND 02/06/92 VZ trans l,3-Oichldr pr pen EPA 601 ug/l 3.4 ND 02/06/92 VZ 1,1,2-Trichlor ethan EPA 601 ug/l 0.20 ND 02/06/92 VZ Tetrachloroethene EPA 601 ug/l 0.30 ND 02/06/92 VZ Oibrcmochlor methane EPA 601 ug/1 0.90 ND 02,/06/"92 VZ Ohlcrchen ene EPA, 601 ug/1 1.0 ND 02/06/92 VZ Br m font EPA 601 ug/1 2.0 ND 02/06/92 VZ 1,1,2,2-'T t.rachl. rc h n EPA 601 ug/l 0.30 ND 02/06/92 BIZ 1,3-Dichl.oroben ene EPA 601 uqJ/1 1.0 ND 02/06/92 V 1, 4-Dtchlcrcten ene EPA 601 ug/1 1.0 ND 02/06/92 VZ Signed 4��k 4't'-�d LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 2/14/92 Page 2, Lab tTuMber : 92-19 1-14 Project No. ; S-S5SSCCi4 "T20 --- 'Teat Data -- -- CC ;ORGANIC ANALYSIS RESULTS - 1,2-Tilc lorob nzen EPA 60 /l 1. /06/ 2 VZ Methyl -tertiary -butyl ether (MTBE) TPA 602 °act/l 5.0 ND 02/ 6/92 VZ BenzeneEPA 602 ug/1 1.0 TAT? 02/06/92 VZ Toluene EPA 60 ug/l 1.0 TAT) 2/06/ 2 V Ethylbenzene EPA 602 u /] 1.0 NTH 02/ 6/92 V Xylene, Total EPA 602 ug/1 2.0 ND 02/06/92 VZ Signed _ia,6"t LAW ENVIRONMENTAL NATIONAL LABORATORIES 'EST DATA REPORT Date 02/14/9 Page l --- Project Information -..- Lab Number : 2-1901-1 ; Project No. : 56-85550 4 T20 Cust. No. Project [dame : PURR PROPERTY Manager: SUSAN FACDERO --- Sample Information --- Station IB A METHOD BLANK pled Date/Time Matrix i Received Date/Time Type D Received From/By -; Collector t Chain of Custody ; Number of Containers z Remarks Test Data Parameter...... ...> w................... Method..... Units PQL....µ.. Results— Test Date Analy -- GO ORGANIC ANALYSIS RESULTS Dichlorodifluoromethane EPA 601 ug/l 18 ND 02/07/92 Chlcromethane EPA 601 Ug/1 0.80 ND 02/07/92V Vinyl Chloride EPA 601 u /l 1.8 ND 02/07/92 V" Brom meth ne EPA 601 a /l: 12 ND 02/07/92 V hlordeth n EPA 601 u /l s-2 STD 02/07/92 V Trichlorofluoromethane EPA 601 Ug/l 3.2 ND 02/07/922 1, 1-CDichloroeth ne EPA 601 u9/l 1.3 ND 02/07/92 VE Methylene Chloride EPA. 601 a/1 2.5 ND /07/92 V2 trans-1, 2-Dichldreethene EPA 601 ug/l 110 STD 02/07/92 V2 1, 1- ichloroet ne EPA 601 a /l 0.70 PATS 02/07/92 V Chloroform EPA 601 Ug/l 6.50 ND 02/07/92 V 1,1,-Trichlcr ethane EPA 601 u /l 0.30 3.6 2/07/92 V Carbon Tetrachloride EPA 601 u /1 1.2 ND 02/07/92 V 1,2-5Dichlorcethan EPA 601 u /1 0.30 ND 2/07/92 V' Tricklcroethene EPA 601 /1 1.2 ED 02/07/92 V2 1,2-Dichl ropr ane EPA 601 u /l 0.40 ND 2/07/92 V Bromddichlorom thane EPA 601 a /l 1. 02/07/92 'V 2-°Chlcroeth lvinyl ether EPA 601 a /l 1#3 ND 02/07/92 V cis-1,3®Bichlor pr pene' EPA 601 ug/l 3.4 ND 2/07/92 VZ trams-1,3-Dichloro r ene EPA 661 a /l 3.4 ND 02/07/92 V 1,1,2-Trichlorcethane EPA 601 u /l 0.20 ND 32/07/92 V Tetrachlcroethene EPA 601 u+ /1 0.30 ND 2/07/92 V" Bibromochloromethane EPA 601 a /l 0.90 ND 02/07/92 V Chlcrobenzene EPA 601 ug/l 1.0 ND 02/07/92 V Bromofcrtat EPA 601 u /l 2.0 ND 02/07/92 V 1,1, ,2-Tetrachlcrcethane EPA 681 Ug/l 0.30 0.31 02/07/92 V 1,3-Bichlcro enzene EPA 601 ug/1 1.0 MD 02/07/92 V2 1,4-Dichlorobenzene EPA 601, a /l 1.0 NO 02/07/92 V2 Signed LAW ENVIRONMENTAL NATIONAL LABORATORIES TEST DATA REPORT Date 02/14/92 Page 2 Lab Number c 92-1901-15 Project No. 56-8555004 T20 --- Test Data --- Parameter .............................. Method.... Units PQL ....... Results... Test Date Analy -- GC ORGANIC ANALYSIS RESULTS -- 1,2-Dichlorobenzene EPA 601 ug/l 1.0 ND 02/07/92 VZ Methyl -tertiary -butyl ether (MTBE) EPA 602 ag/1 5.0 ND 02/07/92 VZ Benzene EPA 602 ug/l 1.0 ND 02/07/92 VZ Toluene EPA 602 ug/l 110 ND 02/07/92 VZ Ethylbenzene EPA 602 ug/l 1.0 ND 02/07/92 VZ Xylene, Total EPA 602 Ug/l 2.0 ND 02/07/92 VZ Signed IW-41 Project L b Sample ID - Date ,analyzed- COMMENTS. � � .•r s • Chloride 56-8555004-T20 Project Name: 92-1901-12 Instrument l 2-5-92 Date Extracted: Matrix: Farr Property Aq X Soil ZIS Law Environmental National Laboratories Ater Matrix Spiker atria Spike Duplicate Recovery ProjectName: urr Property Project plumber: 56-8555004-T20 Lab Sample ID: -158-01 Matrix: X Soil MS/MSD Data Apply" to the following samples: 92-1901-09 SPIKE SAMPLE MS Ms 0C COMPOUND ADDED ONCE T TIN CONCENTRATION LIMITS l q LI t g/Ll mg L # Chloride 30.0 6.28 34,7 95 -11 SPIV COMPOUND ADDED CONCENTRATION LIMITS (mg L) trng/LD REC #` RPD # RPD ! REC. Chloride d. -11 # Column to be used to flag recovery and RPD values with an asterisk., Values outside of OC Limit RP out of 1 outside limits Spike Recovery , £1 - out of 2 outside limits COMMENTS: Project Lab Sample 1 Date Analyzed? Law EnvironmentalNational Laboratories Method Blank Summary Chemical Oxygen Demand 55-555 -T2 Project me: 92-1901-12 Instrument ID: 2-7-92 Date Extracted: Matrix: Purr Property 1 Law Environmental National Laboratories Water Matrix Spike/Matrix SpIkDuplicate Recovery Project e;: Furr Property Project Number:56-8555004-T20 Lab Sample ICE: -`i 1 - stria: Aq X Soil Data ly to a following samples: 92-1901-09 SPIKESAMPLE Ms MS Oc COMPOUND ADDED CONCENTRATION CONCENTRATION % LI i coo 40.0 NO 9P78-125 PIKE COMPOUND ADDED CONCENTRATION % % OC LIMITS IFCOD 4001 7 �1 Column to be used to flag recovery and RPD values with an asterisk, * Values outside of QC Limits out of f _ outside limits Spike Recovery: out of 2 outside limits COMMENTS: APPROVED Y: _. Project #- Lab Sample ID: Date Analyzed - i EDITS. Law Environmental National Laboratories Method Blank Summary Turbidity 5-55FT2 Project arse: 92-1901-10 Instrument 1 1 -1-92 Date Extracted - Matrix: m Farr Property Sell Law Environmental National Laboratories Project Lab Sample to - Date Analyzed- COMMENTS: Environmental National Laboratories Method Blank Summary Color - -T 0 Project m Farr Property 92-1901-10 Instrument ID: 1-31-92 Date Extracte& Matrix: Aq X _ 1l Law Environmental National Laboratories Methodl l Summary TSS I Project #: 56-5655 -T 6 Project Name. Farr Property Lab Sample l 92-1901-10 Instrument ID: Date Analyzed; 2-1-92 Date Extracted: Matrix:; Soil lint Ce -Sample Lai ID Sample ID Industrial Wastewater S -1 S -01 6 6 10 11 1 _1 1 1 _1 1 Law Environmental NationalLaboratories TSS Duplicate Analyses Record G Project urr Prra Project 6-8555004-T20 Matrix: AQ X or SOIL- PL Iv l Al P 9_1 9-1 17 17,5 9.12.1-921 '. =L4L Range' = X, ® 2 Average' ,, + X, } Relative percent difference'' --- (PF) = P n s x 100 Average Do not Calculate If results are B L. .JfV APPROVED 4 Law Environmental National Laboratories Water to Method Bleak Summary Project game : Purr Property Project 66666 6 eT6 Lab Sample l -1 6 -1 atria: Aq X TCLP Method Blank Date Apply to the following samples. 92-1901-09 RESULT"` ELEMENT (` L) 1 -Aluminum Antimony Arai Barium Law Environmental National Laboratories Water t l atria Spike/Matrix Spike Duplicate Recovery Mile, VIM` ow 1W Project 568555004-TZO Project Name Furr Property Lab Sample l 92-1992- 1 Matrix: Aq x 1 Units ugll M$JMSD,Data Apply to the following aamplee:, 9 3-19 1-09 SPIKE SAMPLEMae M� CONTROL ELEMENT T ADDED %Ms CONC. %M80 RP ITEM 1 Aluminum 1 33 - 162 2 Antimony 12 45. 139 3 Arsenic 3 54 - 132 estrum i 77 - 122 6 Beryllium 1 67 - 145 6 Cadmium 12 63 a 149 7 Chromium 3 54 - 13 8 Cobalt 1 9 112 9 Copper 1000 85 . 114 10 Iron 1 246 1274 13 1392 16 3 66.129 11 Lead 3+3 49' - 14 12 Manganese nese 1000 7 - 124 13 Mercury 5 57 - 1 9 14 Mickel 1000 62 - 1 95 15 Selenium 30 45 - 127 16 Silver 313 1 Thallium 3 33 - 127 19 Vanadium 1000 9 , 12 19Zinc 500 76-123, VALUES OUTSIDE OF DO LIMITS Recovery Outside of Control Limit N Not Analyzed for Spike Spike Diluted Out Precision Outside of Control Limits »>« Environmental »c::+*«i Laboratories Gc ::;,»::. Met�hod t:»«< SUZZaty 54-0552004-1<O Project Name 92",190 <<» ±:<e <* •..: 20:52 »c»»<« Furr Prpper» 2 COMMENTS:/ \..... .. .. ... . : Law Environmental ..w. MethodGC volatile Blank 5 04-T2Project Name 1901 13 Lab File 2-5-92 Date c 12:08 Matrix 99 client Sample -ID -1 1 1 3 92-1901-02 3, _ 1 01 3 1 4 4 114 4 1 01. 3 1 1 1 7 1 10 11 1 13 14 1 COMMENTS: #M R.. e. Lab Vile X:.: client SampleID Sample ID Analyzed MW-4 -1 C1- 4 1:31 1 01 ! 3 : 26 3 1 01 :1 -138 5 Matrix Spike 1 191121:18 Matrix Dup MW-1 111 :1 1' 1 12 14 C APPROVED BY-. L� J�� J, ____ Law Environmental National Laboratories GC Volatile Method BlankAOM vow - -TProject Lab Sample ID 92-1901-15 Lab File Date Analyzed 2-7-92 Date Extracted; Time Analyzed0.03 Matri i R Lab Time client Sample ID S M le ID Analysed Matrix Spike 1 92 19 1-1 3 1 1 Law EnvircoMAUtal National Laboratories Water GC Volatile Surrogate Summary Report Project art Project 9010 :: �► 92-19,01-04 92��1400. nR 52 001�09 p.. q LIMITSOC seal ae P 1 1e D(48-130) Surrogate# Column to be used to flag recovery values ute u Values .dlimit Volatiles: 0 out of 45 ; outside of QC limits COMMENTS: Law Environmental Laboratories Water GC Volatile Surrogate Summary Report Pro,j actrc r Project - 5 04- 2 29 LAB 1 L 3 (ELCD) TOT T 1 2 190 2 102 87 1.1.4 24 94 88 108 4 2 7 1 2 13 4 LIMITSOC (FB) = Fluorobenzene(PID) ( 2 1) SMC2 ) = ado-m+ hl than ) 2-1 22 ) = 4 h r t 1.0E ) 4 -, ) column to be usedto flag recovery Surrogate poursd diluted out Values outside of OC limits olati u ___1_2 outside of QC limits USTODY RECORD LAW ENVIRONMENTAL, jW NATIONAL LABORATORY 1NPARK NAMEFACILITY: DRIVE � �� EN ESA , GEORGIA 30144 INFORMATION (404) 4 1- 4 6 NUMBER STREET S _ _ -_ _ __ PROJECT NAME JOB NCL 7/; dui w ca A+ SAPLE STATIONDESCRIPTION � � � . � Ca ` � L N L LAB NO, zi TIME sotm a CODE ... of m i, y H I I SY* D 9�C! I TIME RE EBY: CATS I Tilk I HED .' � 1 t A A DISTRIBUTION.* F31GI AL AND YELLOW COPIES ACCOMPANY SAMPLE SHIPMENT EhNT TO LABORATORY, PINK COPY RETAINED BY SAMPLERS. YELLOW COPY RETAINED BY LABORATORY.; *SOURCE REMARKSRECOVERY WELL - RW NRDES DISCHARGE - INNS ell Rem MONITORING WELL DRINKING WATER - D SOIL / SEDIMENT HAZARDOUS WASTE - N-iW SLN E - SL: SURFACE WATER SIN WAOUE US Y NA