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HomeMy WebLinkAboutNC0023736_Fact Sheet_20210222Fact Sheet NPDES Permit No. NCO023736 Permit Writer/Email Contact Gary Perlmutter, gary.perlmutter@ncdenr.gov: Date Initiated: January 7, 2021 Division/Branch: NC Division of Water Resources / NPDES Municipal Permitting Unit Fact Sheet Template: Version 09Jan2017 Permitting Action: ® Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) Note: A complete application should include the following: • For New Dischargers, EPA Form 2A or 2D requirements, Engineering Alternatives Analysis, Fee • For Existing Dischargers (POTW), EPA Form 2A, 3 effluent pollutant scans, 4 2nd species WET tests. • For Existing Dischargers (Non-POTW), EPA Form 2C with correct analytical requirements based on industry category. Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: City of Lenoir/Gunpowder Creek WWTP Applicant Address: P.O. Box 958, Lenoir, NC 28645 Facility Address: 450 Pine Mountain Rd, Hudson, NC 28638 Permitted Flow: 2.0 MGD Facility Type/Waste: MAJOR Municipal; 55% domestic, 45% industrial' Facility Class: Grade III Treatment Units: Screening, Grit Removal, Sequence Batch Reactors, Post Equalization, Chlorination, Dechlorination, Step Aeration 1 Pretreatment Program (Y/N) Yes County: Caldwell Region Asheville 'From permitted industrial flow of 0.899 MGD. Briefly describe the proposed permitting action and facility background: The City of Lenoir had applied for an NPDES permit renewal for its Gunpowder Creek WWTP, received by DWR on August 24, 2018. Review of the application found it to lack the three Effluent Pollutant Scan reports, which were received from the Permittee by request. Effluent Pollutant Scans were sampled on 1/5/2017, 3/31/2017, 11/7/2017, and 8/2/2018. The required four second species WET tests were sampled on 11/20/2013, 1/14/2014, 2/11/2014, and 4/1/2014 with three additional tests sampled on 4/18/2018, 5/15/2018, and 6/12/2018. Also Page 1 of 14 missing were a system process narrative and the process diagram lacked water balances. These items were received by request on January 6, 2021. This 2.0 MGD facility serves the communities of Hudson, Lenoir and Sawmill. The WWTP treats a combination of domestic and industrial wastewater with a pretreatment program involving 2 Significant Industrial Users (SIUs). 2. Receiving Waterbody Information Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001/Gunpowder Creek Stream Segment: 11-55-(1.5) Stream Classification: WS-IV Drainage Area (mi2): 12.9 Summer 7Q10 (cfs) 2.9 Winter 7Q10 (cfs): 4.0 30Q2 (cfs): 5.8 Average Flow (cfs): 17.4 IWC (% effluent): 52% 303(d) listed/parameter: Benthos Subject to TMDL/parameter: State-wide Mercury TMDL Basin/Sub-basin/HUC: Catawba/03-08-32/03050101 USGS Topo Quad: D13SW/Granite Falls, NC The receiving stream segment of Gunpowder Creek is impaired for Benthos (fair rating) per the 2018 NC 303(d) list. The listing results from a 39% decrease in the benthic community from 2002 to 2007 as reported in the 2010 Catawba River Basin Plan. According to the plan, the receiving stream is designated in the Restoration Opportunities category, defined as a degraded waterbody in need of restoration to return the water quality back to natural conditions. The basin plan also recommends a watershed stressor study in Gunpowder Creek to determine the cause of a significant decline in the biological community. 3. Effluent Data Summary Effluent data for Outfall 001 is summarized in Table 1 for the period of August 2016 - July 2020. Table 1. Effluent Data Summary Outfall 001. Parameter Units Average Max Min Permit Limit 1 Flow ` MGD 1.213 7.775 0.197 MA = 2.0 Farameter Units Average Max Min Permit Limit' Page 2 of 14 BOD5 mg/L 6.3 60.0 0.7 MA = 30.0 WA = 45.0 BOD removal % 96.8 98.9 92.0 > 85 TSS mg/L 8.7 220 0.17 MA = 30.0 WA - 45.0 TSS removal % 95.6 99.0 87.5 > 85 NH3-N (Apr 1 - Oct 31) mg/L 0.51 6.41 0.014 MA = 2.0 WA = 6.0 NH3-N (Nov 1 - Mar 31) mg/L 0 44 5.0 < 0.1 MA = 4.0 WA = 12.0 DO mg/L 8.57 10.70 6.08 DA > 5.0 Fecal Coliform (geometric mean) #/100 mL 14 110,000 < 1 MA = 200 WA = 400 pH S.U. 6.6 8.6 6.0 6.0 - 9.0 TRC gg/L 23 49 7 DM = 28 3 Temperature °C 17.6 26.1 6.1 Monitor & Report Total Nitrogen (NO2 + NO3 + TKN) mg/L 7.69 13.90 3.49 Monitor & Report Total Phosphorus mg/L 2.68 6.61 0.31 Monitor & Report Conductivity µmhos/cm 239 478 18 Monitor & Report Total Cadmium gg/L 0.2 2.0 < 0.2 MA = 4.0 DM - 27.0 Cyanide gg/L 5.2 < 5.0 7.0 MA = 10.0 DM = 39.0 Total Copper gg/L 13 43 < 1 Monitor & Report Total Silver gg/L 1 4 < 1 Monitor & Report Total Zinc gg/L 91 507 < 1 Monitor & Report 1 MA = Monthly Average, WA = Weekly Average, DM = Daily Maximum; DA = Daily Average. 2 Average for CY2019 = 1.337 MGD, 67% of design flow. 3 Values < 50 gg/L considered compliant. A flow exceedence was reported in December 2018, with a note of a significant snow event occurring on Dec. 9 on that month's DMR. A BOD exceedence was reported in April 2019 with a note of a high rain/storm event occurring on Apr. 14, causing the SBR tanks to enter storm mode, on that month's DMR. A Fecal Coliform exceedence was reported in January 2018, with a note of significant rain (near 2 inches per day) on Jan. 24-25 on that month's DMR. 4. Instream Data Summary Page 3 of 14 Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/L of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: The current permit requires instream monitoring for Dissolved Oxygen (DO), Temperature, Conductivity, pH, Total Nitrogen and Total Phosphorus. Instream monitoring locations in the current permit include one upstream, at least 100 ft upstream of the outfall, and one downstream at approximately 2,000 ft below it. Instream data from August 2016—July 2020 were obtained from submitted DMR reports and compared against state water quality standards where applicable. Data were visually checked for differences followed by statistical testing of averages using t-test. Instream data review findings for each parameter are summarized below. Dissolved Oxygen (DO) — DO remains in the permit as a parameter of concern for aquatic life. Reviewed instream DO data showed seasonal patterns of summer lows and winter highs. Instream summer minima were above the 5 mg/L daily average water quality standard for non -trout waters (15A NCAC 02B .0211) at both locations. Downstream DO was, on average lower than upstream DO (downstream average = 8.6 mg/L; range: 7.1-13.0 mg/L; upstream average = 8.8 mg/L; range: 6.9-14.2 mg/L). Concurrent effluent DO data averaged 8.4 mg/L, lower than either instream average, with a range of 6.4-10.4 mg/L; however, both forms of oxygen -consuming waste (BOD and NH3) in the effluent were found to be within their permit limits (see Table 1 above). Therefore, the effluent does not appear to negatively impact instream DO levels sufficiently to affect the stream standard. Temperature — Temperature remains in the permit as a parameter of concern for aquatic life. Reviewed instream temperature data showed seasonal patterns of summer highs and winter lows at both locations. Downstream temperature was slightly higher (average = 17.1°C; range: 1.2-24.9°C) than that upstream (average = 17.0°C; range: 0.1-23.5°C) with no statistically significant difference found. Temperature maxima were below the water quality standard of 29°C for upper piedmont and mountain waters (15A NCAC 02B .0211) at both locations. Review of paired up- to downstream temperatures revealed four exceedences of the 2.8°C increase standard, all in 2017. The concurrent effluent temperatures averaged higher overall at 19.36°C with higher range, substantially so in winter (range: 6.4-26.1 °C). While instream average temperatures did not statistically test different between up- and downstream, statistical differences were found when tested with concurrent effluent data (ANOVA: F = 2.65; p < 0.05). It appears that the effluent can have an impact on the receiving stream temperature. Conductivity — Conductivity (Specific Conductance) remains in the permit as a parameter of concern due to industrial discharges. Reviewed data showed the downstream conductivity, on average, tested higher than upstream conductivity (downstream average = 72 µmhos/cm; range: 7-118 µmho/cm; upstream average = 62 µmho/cm; range: 35-260 µmho/cm). Concurrent effluent Conductivity data averaged substantially higher at 244 µmho/cm (range: 90-387 µmho/cm). Comparisons of the three data sets suggest that the effluent is impacting the instream conductivity. Fecal Coliform — Fecal Coliform remains in the permit as a parameter of concern for aquatic life and human health. Instream standards include: a geometric mean of 200 cfu/100 mL (MF count) based upon at least five samples taken over a 30-day period, and 400 cfu/100 mL in more than 20 percent of the samples examined during such period (15A NCAC 02B .0200). Review of submitted DMR instream data found Page 4 of 14 both instream standards to be exceeded consistently both upstream and downstream, and often throughout the period of data reviewed (Fig. 1). The receiving stream is not impaired for Fecal Coliform according to the 2018 NC 303(d) list. The Division's Modeling and Assessment Branch was notified, who will sample the stream to confirm the exceedences and reassess its impairment. Gunpowder Creek,11-55-(1.5) upstream of WWTP Figure 1. Instream Fecal Coliform weekly and monthly geometric means, upstream of the Gunpowder WWTP discharge. pH — pH remains in the permit as a parameter of concern for aquatic life. Review of DMR submitted data found all instream measurements to be within the standards of 6.0 and 9.0 SU (15A NCAC 02B .0200). Downstream pH (avg = 7.01 SU; range: 6.04-8.30 SU) was found to be statistically lower than upstream pH (avg = 7.17 SU; range: 6.13-8.30 SU) (t-test; t = 10.44; p < 0.0001). Concurrent effluent pH was lower than either instream station on average with avg = 6.63 SU and a range of 6.00-8.18 SU. The effluent appears to be affecting the instream pH, but not so much as to cause an exceedence of the instream standards. Nutrient monitoring — Instream monitoring for nutrients (Total Nitrogen and Total Phosphorus) is in the current permit with monthly sampling required from April 1—September 30. Nutrient monitoring is all that remains of a larger set of special instream monitoring requirements placed in the permit in 1992 out of concerns for eutrophication and resulting algal blooms in Old Millpond and Lake Hickory, located 7.0 and 9.5 miles downstream, respectively. Submitted data were reviewed like for other instream parameters. Total Nitrogen — Total Nitrogen (TN) remains in the permit as a parameter of concern due to its potential to cause eutrophication of the Old Millpond section of Gunpowder Creek. Review of submitted instream data found no statistical difference between up- and downstream TN (two -sample t-test: t = 1.05; p > 0.05). Concurrent effluent TN values were considerably higher than instream values (Table 2). While higher in concentration, it appears that the effluent is not affecting the instream TN. Page 5 of 14 Table 2. Instream and effluent Total Nitrogen concentrations (mg/L) at Gunpowder Creek WWTP. Statistic Upstream' Downstream Effluent N 27 26 27 Average 3.9 3.1 8.2 Minimum 0.4 0.5 3.5 Maximum 9.1 7.6 13.9 Total Phosphorus — Total Phosphorus (TP) remains in the permit as a parameter of concern due to its potential to cause eutrophication of Old Millpond section of Gunpowder Creek. Review of submitted instream data found downstream average TP to be significantly higher than upstream TP (two -sample t- test: t = 1.05; p < 0.005). Concurrent effluent TP values were considerably higher than instream values (Table 3), suggesting that the effluent is increasing the instream TP. Table 3. Instream and effluent Total Phosphorus concentrations (mg/L) at Gunpowder Creek WWTP. Statistic Upstream Downstream Effluent N 27 26 27 Average 0.18 0.33 2.33 Minimum < 0.02 < 0.02 0.31 Maximum 0.54 0.76 6.61 Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): NO. Name of Monitoring Coalition: N/A. 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): From October 2015 through September 2020, four limit exceedences resulted in a violation action (Table 4). Table 4. Monitoring Report Violations: 2015-2020. Violation Date Parameter Violation Type Action 1 3/4/2017 Ammonia-N Weekly Average Exceeded NOV 1/26/2019 Fecal Coliform Weekly Geometric Mean Exceeded NOV 2/26/2019 pH Daily Minimum Not Reached NOD 4/20/2019 TSS Weekly Average Exceeded NOD 1. NOD = Notice of Deficiency issued; NOV = Notice of Violation issued. The City obtained an Authorization to Construct (ATC) in February 2014 to add an SBR tank and improvements to the existing system. An Engineering Certification for construction completion was received by the Division in April 2016. Page 6of14 Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility passed 19 of 19 quarterly chronic toxicity tests from March 2016 through June 2020, as well as all four 2nd species tests, sampled in April, May, June and July 2018. Summarize the results from the most recent compliance inspection: The most recent facility inspection, conducted on 12/18/2019, reported no compliance issues. The most recent pretreatment compliance inspection, conducted on 01/09/2019, also reported no compliance issues. 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1 Q 10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA. If applicable, describe any mixing zones established in accordance with 15,4 NCAC 2B. 0204(b): NA. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD = 30 mg/L for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: BOD limits are based on a Level B water quality model run in 1992, and are maintained in the permit. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/L (summer) and 1.8 mg/L (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 µg/L) and capped at 28 µg/L (acute impacts). Due to analytical issues, all TRC values reported below 50 µg/L are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: The ammonia limits in the permit of 2.0/6.0 mg/L monthly average/weekly average (summer) and 4.0/12.0 mg/L monthly average/weekly average (winter) are based on a Level B water quality model run in 1992 for oxygen - consuming waste. Toxicity -based Ammonia was reviewed in the attached Wasteload Allocation (WLA) sheet using the flow design of 2.0 MGD and receiving stream low flows of summer 7Q10 = 2.9 cfs and winter 7Q10 = 4.0 cfs. The resulting allowable concentrations were 1.7/5.1 mg/L monthly average/weekly average (summer) and 3.8/11.4 mg/L monthly average/weekly average (winter). Because both sets of limits approximate each other, no changes were made in the permit. The current TRC limit of 28 µg/L was first established in the permit in 2000 as capped to protect against acute impacts in the receiving water per the then new TRC policy. WLA calculations for TRC also cap the allowable concentration at 28 µg/L. The current TRC limit is maintained in the permit. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. Page 7 of 14 The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of 1/2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. Effluent and upstream hardness data (n = 5 samples per sampling site) were received from the Permittee by request. All upstream data were below the default value of 25 mg/L (range: 14.8-20.2 mg/L). Therefore, the default value was used for upstream hardness in the RPA. A reasonable potential analysis was conducted on effluent toxicant data collected from December 2016 through June 2020. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: • Effluent Limit with Monitoring. The following parameters will receive a water quality -based effluent limit (WQBEL) since they demonstrated a reasonable potential to exceed applicable water quality standards/criteria: Copper, Lead, Zinc. • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria, but the maximum predicted concentration was > 50% of the allowable concentration: Total Chromium, Silver (see Table 6). • No Limit or Monitoring: The following parameters will not receive a limit or monitoring, since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria and the maximum predicted concentration was < 50% of the allowable concentration: Arsenic, Cadmium, Chlorides, Total Phenols, Cyanide, Molybdenum, Nickel, Selenium. • POTW Effluent Pollutant Scan Review: Three effluent pollutant scans were evaluated for additional pollutants of concern. o The following parameter(s) will receive a water quality -based effluent limit (WQBEL) with monitoring, since as part of a limited data set, two samples exceeded the allowable discharge concentration: None. o The following parameter(s) will receive a monitor -only requirement, since as part of a limited data set, one sample exceeded the allowable discharge concentration: None. If applicable, attach a spreadsheet of the RPA results as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: This facility is a Major POTW, and a chronic WET limit at 52% effluent will continue on a quarterly frequency. The WET limit is based on the Instream Waste Concentration (IWC) as calculated from the design flow of 2.0 MGD and the receiving stream 7Q10s of 2.9 cfs (WET Permitting Limits and Monitoring Requirements guidance memo, 8/2/1999). Page 8 of 14 Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (> 1 ng/L) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/L) and/or if any individual value exceeds a TBEL value of 47 ng/L. Describe proposed permit actions based on mercury evaluation: A Mercury Minimization Plan (MMP) special condition was added to the permit in 2014. An MMP summary was included with the permit renewal application. Submitted low level mercury data from December 2016 through June 2020 were reviewed for TMDL evaluation. All data were detected with no averages exceeding the TBEL of 47 ng/L and no individual values exceeding the WQBEL of 23.2 ng/L (Table 5). Because the design flow is 2 MGD and mercury was detected in the effluent, an MMP is required. Therefore, the MMP special condition has been reworded to maintain the MMP. Table 5. Mercury Effluent Data Summary 2016 2017 2018 2019 2020 # of Samples 2 4 5 4 2 Annual Average Conc. ng/L 0.5 1.0 0.6 1.2 0.9 Maximum Conc., ng/L 0.50 2.30 1.... 3.10 1.20 TBEL, ng/L 47 WQBEL, ng/L 23.2 Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: Monthly instream monitoring of nutrients (Total Nitrogen and Total Phosphorus) is in the permit, with samples required from May 1—September 30. Nutrient monitoring was originally placed as part of special instream monitoring requirements in 1992 out of concern for eutrophication in Old Millpond, downstream of the discharge. Special instream monitoring requirements were included one upstream and three downstream locations: DI at —2,000 ft from the outfall, D2 before the start of Old Millpond or at SR 1002, and D3 in the pooled area of Old Millpond. Upstream Chl-a was removed from upstream, DI and D2 in the 2000 permit as well as the monitoring site D2. Monitoring in Old Millpond was removed from the permit in 2005. In the 2005 permit a nutrient optimization study requirement was inserted based on nutrient loading concerns into Lake Hickory of the Catawba River. The resulting report, dated March 20, 2007, described the treatment process and reported 78% TN reduction and 42% TP reduction from influent to effluent concentrations. The requirement was removed in the subsequent (2011) permit renewal. Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: The receiving water is a water supply water, which is subject to the Nitrate -Nitrogen (NO3-N) standard of 10 mg/L. An RPA was run on effluent TN data, which includes NO3-N. Results revealed the TN maximum predicted value to be Page 9of14 less than the NO3-N allowable concentration. No limits or monitoring of NO3-N are required and thus were not added to the permit. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: NA. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H0107(c)(2)(B), 40CFR 122.47, and EPA May 2007 Memo: The Permittee was asked if a compliance schedule is needed for Copper, Lead and/or Zinc. None requested by Permittee. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B.0226 for this permit renewal: NA. 7. Technology -Based Effluent Limitations (TBELs) Municipals (if not applicable, delete and skip to Industrials) Are concentration limits in the permit at least as stringent as secondary treatment requirements (30 mg/L BOD5/TSS for Monthly Average, and 45 mg/L for BOD5/TSS for Weekly Average). YES. If NO, provide a justification for alternative limitations (e.g., waste stabilization pond). NA. Are 85% removal requirements for BOD5/TSS included in the permit? YES. If NO, provide a justification (e.g., waste stabilization pond). NA. 8. Antidegradation Review (New/Expanding Discharge) The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105(c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA. 9. Antibacksliding Review Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): NO. Page 10 of 14 If YES, confirm that antibacksliding provisions are not violated: NA. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti -backsliding prohibitions would not be triggered by reductions in monitoring frequencies. All parameters are monitored according to 15A NCAC 2B .0500. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions Table 6. Current Permit Conditions and Proposed Changes. Parameter Current Permit' Proposed Change Basis for Condition/Change Flow MA 2.0 MGD No change 15A NCAC 2B .0505 BOD5 MA — 30.0 mg/L WA — 45.5 mg/L No change TBEL. Secondary treatment standards/40 CFR 133/15A NCAC 2B .0406. TSS MA — 30.0 mg/L WA = 45.0 mg/L No change TBEL. Secondary treatment standards/40 CFR 133/15A NCAC 2B .0406. Parameter Current Permit' Proposed Change Basis for Condition/Change NH3-N Summer: MA = 2.0 mg/L WA = 6.0 mg/L Winter: MA = 4.0 mg/L WA = 12.0 mg/L No change WQBEL. Calculation results based on NC's use of EPA criteria in developing 1.0 mg/L summer and 1.8 mg/L winter values in wasteload allocations to protect against NH3-N toxicity approximate existing limits for Page 11 of 14 oxygen -consuming waste (see WLA sheet attached). DO DA > 5.0 mg/L — No change WQBEL. State WQ standard 15A NCAC 2B .0200. Fecal Coliform MA = 200 /100 mL WA = 400 /100 mL No change WQBEL. State WQ standard, 15A NCAC 2B .0200. Total Residual Chlorine (TRC) DM = 28 µg/L No change WQBEL. State WQ acute standard, 15A NCAC 2B .0200 pH 6 — 9 SU No change WQBEL. State WQ standard, 15A NCAC 2B .0200. Temperature Monitor daily No change State WQ reporting requirements 15A NCAC 2B .0500. Conductivity Monitor only No change State WQ reporting requirements 15A NCAC 2B .0500. Total Nitrogen (NO3+NO2 + TKN) Monitor monthly No change State WQ reporting requirements 15A NCAC 2B .0500. Total Phosphorus Monitor monthly No change State WQ reporting requirements 15A NCAC 2B .0500. Toxicity Test Chronic Ceriodaphnia dubia Pass/Fail at 52% effluent No change WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500. Total Hardness No requirement Add effluent and upstream monitoring Hardness -dependent dissolved metals water quality standards, approved in 2016, need effluent and instream hardness data for calculations of permit limitations. Total Cadmium MA = 4.0 µg/L DM = 27.0 µg/L Remove from permit No reasonable potential to exceed allowable discharge concentration (RP) found. Total Chromium No requirement Add quarterly monitoring No RP found; one value > 50% of but < Chromium VI Allowable Conc. DWR dissolved metals guidance, 2016. Total Copper Monitor quarterly MA = 15.4 µg/L DM = 18.8 µg/L Monitor monthly WQBEL. Reasonable potential to exceed allowable discharge concentration found. Cyanide MA = 10 µg/L DM = 39 µg/L Remove from permit No detections above compliance level of 10 µg/L; DWQ cyanide compliance guidance memo, 2007. Parameter Current Permit' Proposed Change Basis for Condition/Change Total Lead No requirement MA = 5.7 µg/L DM = 136 µg/L Monitor monthly WQBEL. Reasonable potential to exceed allowable discharge concentration found. Total Silver Monitor quarterly No change No detects at < 1 µg/L in previous 2 years with one low detection in March Page 12 of 14 2017. Division guidance for dissolved metals, June 2016. Total Zinc Monitor quarterly MA = 225 µg/L DM = 225 µg/L Monitor monthly WQBEL. Reasonable potential to exceed allowable discharge concentration found. Total Mercury Mercury Minimization Plan (MMP) Revise MMP to require its maintenance In accordance with 2012 Statewide Mercury TMDL Implementation, per facility size and monitoring data criteria. Effluent Pollutant Scan Three times per permit cycle Update sampling years to 2023, 2024, 2025 40 CFR 122 Electronic Reporting Electronic Reporting Special Condition Update condition to remove submittal of hardcopies and extended Phase 2 deadline to 2025 In accordance with EPA Electronic Reporting Rule 2015. 1MGD = Million gallons per day, MA = Monthly Average, WA = Weekly Average, DM = Daily Maximum. 13. Public Notice Schedule: Permit to Public Notice: 01/17/2021. Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. NPDES Division Contact: If you have questions regarding any of the above information or on the attached permit, please contact Gary Perlmutter at (919) 707-3611 or via email at gary.perlmutter@ncdenr.gov. 15. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes. Comments were received from the Lisa Triplett (Permittee) and Zachary Thomas (DWR-Aquatic Toxicity Branch). Ms. Triplett suggested correcting monitoring frequencies of pH an TRC; Mr. Thomas commented that the draft looked good from an aquatic toxicity standpoint. A signed review form was received from Nichole Hairston (DWR-Public Water Supply/Asheville Regional Office) indicating her concurrence with issuing the permit. No comments were received from USEPA or any other party. If Yes, list changes and their basis below: Two minor corrections were made in response to comments by Lisa Triplett (Permittee): • Monitoring frequencies for effluent pH and TRC were corrected from weekly (pH) and 2/week (TRC) to daily for consistency with the existing permit. Page 13 of 14 16. Fact Sheet Attachments (if applicable): • EPA Application 2A, Attachment A (completed) with requested Process Diagram and Process Narrative • Pretreatment information form, completed • Final 2018 NC 303(d) list, page 42 • 2010 Catawba River Basin Plan, pages 59-60, 167 • Effluent summary charts and tables • BOD and TSS removal calculator output tables • Instream Monitoring summary charts and tables • Monitoring Report (MR) Violations page • WET testing and Self -Monitoring Summary, page 67 • Permit and Pretreatment Compliance Inspection Reports • NH3/TRC WLA Calculations sheet • RPA Spreadsheet Summary • Dissolved Metals Implementation — Freshwater • Effluent, upstream hardness results • Mercury WQBEL/TBEL Evaluation data and summary table • Draft permit comment e-mail from Lisa Triplett (Permittee) • Draft permit comment from Zachary Thomas (DWR-Aquatic Toxicity Branch) • Signed draft permit PWS review form from Nichole Hairston (DWR-Asheville Region) Page 14 of 14 Attachment A —Request for Missing Information Table 2. EPA Application Form 2A Missing Information 40 CFR 1.1 122.21(j)(1) Email address of facility contact Irtriplett@ci.lenoir.nc.us 1.2 Applicant email address Same as above 1.3 Email address of the organization transporting the discharge for treatment prior to discharge 1.4 Email address of the organization receiving the discharge for treatment prior to discharge 1.5 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)? (Check all that apply. Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) ❑ Discharges into marine waters (CWA Section ❑ Water quality related effluent limitation (CWA 301(h)) Section 302(b)(2)) X❑ Not applicable 1.6 Email address of contractor responsible for operational or maintenance aspects of the treatment works 40 CFR 122.21(j)(6) 1.7 40 CFR Indicate the number of SIUs and NSCIUs that discharge to the POTW. Number of SIUs Number of CIUs 2 122.22(a) and (d) Certification Statement I certify under penalty of law that this document and all attachments with a system designed to assure that qualified personnel properly inquiry of the person or persons who manage the system, or those information submitted is, to the best of my knowledge and belief, true, penalties for submitting false information, including the possibility 0 were prepared under my direction or supervision in accordance gather and evaluate the information submitted. Based on my persons directly responsible for gathering the information, the accurate, and complete. I am aware that there are significant of fine and imprisonment for knowing violations. Name (print or type first and last name) Elise Triplett Official title Superintendent Signature E Triple,rriple,tt Date signed 1 /6/2021 2.00 MGD INFLUENT PARSHALL FLUME AN D MECHANICAL SCREEN VORTEX GRIT SYSTEM INFLUENT PUMP STATION (4 PUMPS) 0.67 MGD 0.67 MGD 0.41 MGD 0.26 MGD 0.41 MGD 0.26 MGD 0.66 MGD A/R SBR TANK #1 SBR TANK #3 SBR TANK #2 • 1 i SBR TANK #4 \ \ SBR TANK #5 5 BLOWERS i SODIUM HYPOCHLORITE 1 POST-EQ BASIN WASTE ACTIVATED SLUDGE (WAS) PROCESS FLOW DIAGRAM GUNPOWDER CREEK WWTP CITY OF LENOIR SULFUR DIOXIDE SLUDGE HOLDING TANK CHLORINE CONTACT BASIN DECHLORINATION AND POST AERATION SLUDGE HAULED TO LOWER CREEK WWTP 2.00 MGD EFFLUENT �I 0 I � I : O: mcgill Process Flow Diagram Narrative Gunpowder Creek WWTP City of Lenoir, North Carolina Wastewater enters the WWTP by gravity and flows through the Parshall Flume and influent fine screen, where inorganic screenings are removed. The influent pump station contains four (4) pumps that deliver raw wastewater to the five (5) Sequencing Batch Reactor (SBR) tanks. The SBR tanks operate as a three (3) train treatment system on offset cycle schedules. SBR Tanks #1 and #3 are on the first cycle, Tanks #2 and #4 are on the second cycle, and Tank #5 is on the third cycle. Each SBR tank has diffused aeration fed by a bank of blowers, a floating mixer, a floating decanter, and submersible WAS pump. SBRs provide flow equalization, aeration, settling, and sludge wasting processes all in one tank. The SBR process is operated and sequenced by a control system that determines the cycle times and influent/effluent valve operation. As wastewater enters the SBR, the tank fills from the minimum water level for a pre -determined time period, with mixing by a floating mixer to begin the process. During the React -Fill stage, the blowers provide air to the basin while the mixer continues to operate. After the fill phases are completed, the influent valve to the SBR tank is closed and the unit enters the React phase. Simultaneously, influent valves open to another SBR treatment train to maintain a continuous inflow into the overall SBR system. Aeration is provided by blowers located adjacent to the tanks providing air to the diffusers installed in the bottom of each tank to achieve BOD and ammonia reduction. The aerators and mixers are then turned off and settling commences. During the Settle phase, quiescent conditions are provided to allow liquid -solid separation in the basin. After solids have settled, the floating mechanical decanter withdraws supernatant from the top of the fluid in the basin and discharges the treated wastewater to the post -equalization basin. Since SBRs decant in a "batch" process in the Decant phase, supernatant discharged from each unit is transferred to a post -equalization (post-EQ) basin where peak effluent flows are equalized. The flow in this basin is chlorinated for disinfection using a 12.5% sodium hypochlorite solution before being pumped by two (2) submersible pumps equipped with variable frequency drives to the chlorine contact basin. The chlorine contact basin provides contact time to disinfect the plant flow. After disinfection is complete, the flow stream is dechlorinated using sulfur dioxide and feed pumps. Finally, treated wastewater is discharged over the cascade aerator to raise the dissolved oxygen level prior to discharging to Gunpowder Creek. Since the treatment process occurs within a single tank, SBRs do not require return pumping sludge facilities. Submersible waste activated sludge (WAS) pumps are included to waste sludge from each basin to control biomass and to maintain a consistent level of mixed liquor suspended solids. Following the SBR Decant phase, the WAS pumps transport sludge to the sludge holding tank equipped with a coarse bubble diffuser system. Liquid sludge is stored in the Sludge Holding Tank, before being hauled to the City's Lower Creek WWTP for processing as a Class A sludge. NPDES/Aquifer Protection Permitting Unit Pretreatment Information Request Form PERMIT WRITER COMPLETES THIS PART: PERMIT WRITERS - AFTER vou get this form back from PERCS: Check all that apply Notify PERCS if LTMP/STMP data we said should Date Prepared 9/23/2020 municipal renewal X be on DMRs is not really there, so we can get it for Prepared by Gary Perlmutter new industries you (or NOV POTW). Facility Name Gunpowder Cr WWTP WWTP expansion - Notify PERCS if you want us to keep a specific POC Permit Number NC0023736 Speculative limits in LTMP/STMP so you will have data for next permit Region Asheville stream reclass. renewal. - Email PERCS draft permit, fact sheet, RPA. Basin Catawba outfall relocation - Send PERCS paper copy of permit (w/o NPDES 7Q10 change boilerplate), cover letter, final fact sheet. Email RPA if other changes. other Comments: Facility is a 2.0 MGD POTW w/ a pretreatment program involving 2 Sills reported in the permit application. PERCS Status PRETREATMENT STAFF COMPLETES THIS PART: of Pretreatment Program (check all that apply) 1) facility has no SIU's, does have Division approved Pretreatment Program that is INACTIVE _ 2) facility has no SIU's, does not have Division approved Pretreatment Program _ x 3) facility has Sills and DWQ approved Pretreatment Program (list "DEV" if program still under development) x 3a) Full Program with LTMP 3b) Modified Program with STMP 4) additional conditions regarding Pretreatment attached or listed below Flow, MGD Permitted Actual Time period for Actual STMP time frame: Industrial 0.889 0.12 2013-2016 Most recent: Uncontrollable n/a 1.101 Next Cycle: POC in LTMP/ STMP Parameter of Concern (POC) Check List POC due to Non- D sDChSPermit Limit Requiredby Required by 503 Sludge** tOC o SIU**e POTW POC (Explain below)**** STMP Effluent Freq LTMP Effluent Freq BOD x x 4 Q TSS x x 4 Q Q = Quarterly NH3 x x 4 Q M = Monthly Arsenic x x 4 Q Al Cadmium x AI x x 4 Q AI Chromium AI x 4 Q AI Copper x AI x x 4 Q Cyanide x x 4 Q Is all data on DMRs? AI Lead AI x x 4 Q YES x Mercury x x 4 Q NO (attach data) Molybdenum x x 4 Q AI Nickel A/ x x 4 Q Silver x x 4 Q Selenium x x 4 Q AI Zinc x AI x x 4 Q Is data in spreadsheet? Total Nitrogen x 4 Q YES (email to writer) Phosphorus x x 4 Q NO 4 Q M 4 Q M 4 Q M 4 Q M *Always in the LTMP/STMP ** Only in LTMP/STMP if sludge land app o composte (dif POCs for incinerators) *** Only in LTMP/STMP while SIU still discharges to POTW **** Only in LTMP/STMP when pollutant is still of concern to POTW Comments to Permit Writer(ex.. explanation of anv POCs; info vou have on IU related investigations into NPDES problems): 23736 Pretrtmt info form_2020 Revised: July 24, 2007 2018 NC Category 5 Assessments "303(d) List" Final Catawba River Basin Upper Catawba Subbasin 03050101 D¢.ilerfl u] Lint. menial R�y� 11-39-4b Greasy Creek From SR 1305 to Lower Creek Classification C Length or Area 3 Units FW Miles Previous AU Number Assessment Criteria Status Reason for Rating Parameter of Interest Category Exceeding Criteria Fair rExceeding Criteria FCB 5in30 GM >200 or >20% Benthos (Nar, AL, FW) Fecal Coliform (GM 200/400, REC, FW) 5 5 11-55-(1.5) Gunpowder Creek (Old Mill Pond) From a point 0.5 mile downstream of Caldwell County SR 1127 to a point 0.8 mile downstream of Billy Branch Classification [WS-IV Length or Area L 13 Units FW Miles Previous AU Number Assessment Criteria Status Reason for Rating Parameter of Interest Category Exceeding Criteria Fair Benthos (Nar, AL, FW) 11-54-(0.5) Horseford Creek From Frye Creek to a point 0.7 mile upstream of mouth Classification WS-IV Length or Area 0 Units FW Miles Previous AU Number Assessment Criteria Status Reason for Rating arameter of Interest Category Exceeding Criteria Poor Benthos (Nar, AL, FW) 5 11-54-(3) Horseford Creek From a point 0.7 mile upstream of mouth to Lake Hickory, Catawba River Classification WS-IV;CA Length or Area 1 Units FW Miles Previous AU Number Assessment Criteria Status Reason for Rating Parameter of Interest Category Exceeding Criteria Poor Benthos (Nar, AL, FW) 6/3/2019 2018 NC Category 5 Assessments "303(d) List" Approved by EPA May 22,2019 Page 42 of 262 A57 FCB: DWQ's Asheville Regional Office will be conducting a routine inspection of the City of Lenoir's wastewater collection system in coordinated efforts with the city to assist in finding leaks and pipe failures. The City has contacted an engineering firm to evaluate the WWTP and the collection system. EEP has been a strong lead in this watershed and will be conducting additional studies and stream walks to find additional sources such as failing septic systems. DWQ, along with EEP and the City of Lenoir, will also be working with Caldwell County SWCD to find additional solutions for excess FCB within this system. Water Quality Improvements & Success Stories Upper Lower Creek (030501010701) Unnamed Tributary to Zacks Fork: A Notice of Violation (NOV) was issued by Division of Land Resources (DLR) in March of 2008 to the property owner of a development under construction in Caldwell County NC for sediment and erosion control violations. DLR notified DWQ of the violations and noted the failure to control sediment on the property was causing water quality issues. In April 2008, DWQ performed an inspection of the development to address this situation and found the site was in violation of the permit resulting in another NOV following this inspection. The site was found to have NCG010000 Stormwater Permit condition violations due to sediment impacts to an Unnamed Tributary (UT) to Zacks Fork. The impacts averaged 8 inches of sediment buildup throughout the channel for approximately 400 linear feet. The DWQ NOV required a response from the property owner which was received in May of 2008. The responsible party hired an Environmental Consultant to assist with compliance. The Consultant submitted to DWQ a response indicating how and when all permit condition violations were to be resolved or met. The response included a Sediment Removal Restoration Plan. This plan was approved by DWQ in May of 2008 and restoration work began on the site in June 2008. Sediment was removed from the channel by manual labor with shovels and buckets. The laborers were overseen by the Consultant, who is experienced in stream geomorphology, to make sure the sediment was removed without further damage to the stream bed and bank. The Consultant sent a Final Sediment Removal Restoration Report to DWQ in June 2008. DWQ performed a follow up inspection in June 2008. In July 2008, DWQ sent a letter to the responsible party indicating the violation had been resolved. LAKE RHODHISS - CATAWBA RIVER (0305010108) Restoration Opportunities McGalliard Creek -Lake Rhodhiss (030501010801) McGailiard Creek [AU: 11-44-(3)]: McGailiard Creek is approximately four miles long and drains residential, agricultural and forested land cover into Lake Rhodhiss. The creek was monitored in 2007 and received an improved benthic rating of Good -Fair as compared to the Fair rating in 2003. There is no indication as to why the benthic community has improved. This rating will remove the creek from the Impaired Waters list for its benthic impairment; however, it will remain on the 2008 and 2010 Impaired Waters lists for the fish community impairment from a Poor rating in 2003. DWQ will re -sample the fish community during the next sampling cycle to evaluate if water quality improvements are seen there as well. Gunpowder Creek (030501010803) Gunpowder Creek [AU: 11-55-(1.5)]: This middle portion of Gunpowder Creek is a little over 13 miles long and flows through parts of the Town of Hudson and Granite Falls. The creek eventually flows into Lake Hickory. This creek will be on the Impaired Waters list for the first time in 2008 due to a Fair benthic rating. Between the 2007 sample and the 2002 sample, the benthic community decreased by 39%. This is a significant decline and indicates major impacts to the community between 2002 and 2007. The habitat had not changed much since the USE SUPPORT: IMPAIRED (4 MI) 2008 IR Cat. 5 2010 IR Cat. 5 Benthos (CB82) Good -Fair (2007) Fish Com (CF41) Poor (2003) USE SUPPORT IMPAIRED (13 MI) 2008 IR Cat. 2 2010 IR Cat. 5 Benthos (CB254) Fair (2007) 1.33 NC DWQ CATAWBA RIVER BASIN PLAN: Catawba River Headwaters Subbasin HUC 03050101 A58 previous sample, concluding the decline is due to waterborne pollutants. The cause of this decline is unknown. Possible sources could include urban stormwater runoff and impacts from drought. The protection of this subwatershed is critical to the health of Lake Hickory because inputs here flow downstream and impact the lake. As resources become available, DWQ will conduct further biological, and if possible, physical/chemical monitoring to narrow down the possible sources. However, DWQ supports and recommends this issue be studies on a local level. Drowning Creek -Catawba River (030501010804) Horseford Creek [AU: 11-54-(0.5)]: A half mile portion of Horseford Creek flows through the City of Hickory and drains a large industrial area. It was monitored in 2002 for the first time to assess a citizen complaint. The instream habitat was stable; however, the benthic community received a Poor rating. This unusual combination of good habitat and poor biological integrity suggests that even favorable instream habitat cannot compensate for the toxic effects of poorly controlled urban runoff. The City of Hickory adopted a Phase II Stormwater Ordinance in July of 2007 to address the impacts of urban stormwater runoff. The creek has not been monitored since these efforts were made by the City. DWQ will re -sample this site during the next monitoring cycle to re-evaluate the stream's health. For more information on the City of Hickory's Stormwater Program, visit the City's website. USE SUPPORT IMPAIRED (0.4 MI) 2008 IR Cat. 5 2010 IR Cat. 5 Benthos (CB115) Poor (2002) Protection Priorities McGalliard Creek -Lake Rhodhiss (030501010801) Smoky Creek [AU: 11-41-(1)]: The eight mile upper portion of Smoky Creek drains mostly residential and forested lands and some agricultural land. During the 2002 monitoring, excess sediment covered much of the benthic habitat causing the creek to be rated as Good -Fair. Since that time, silt within the creek has been reduced and there are signs of the benthic community returning. Sources of the sediment could be farming activities near the monitoring site. DWQ will work with SWCD to evaluate the need for agricultural BMPs that target sediment runoff. Gunpowder Creek (030501010803) Silver Creek [AU: 11-56-(2)]: The lower segment of Silver Creek drains mostly agricultural properties as well as residential properties into Gunpowder Creek just before it reaches Lake Hickory. In 2002, this creek was sampled for the first time and received a benthic rating of Good Fair. The local SWCD completed the placement of 16 agricultural BMPs within the creeks drainage area between 2006 and 2008. These BMPs are focused erosion and nutrient reductions, waste management, sediment reductions and stream protection. DWQ will sample this site again during the next sampling cycle to assess for stream health improvements as a result of these efforts. Drowning Creek -Catawba River (030501010804) Drowning Creek [AU: 11-52-(1)]: Drowning Creek drains mostly residential and agricultural lands before flowing into the western portion of Lake Hickory. This creek was sampled for the first time in 2007 and received a Good -Fair fish community rating. This moderate rating is likely a result urban stormwater runoff and sedimentation from non -point sources. The City of Hickory adopted a Phase II Stormwater Ordinance in July of 2007 to address the impacts of urban stormwater runoff. DWQ will continue to monitor this location during the next sampling cycle to help further understand the streams biological health. USE SUPPORT: SUPPORTING (8 MI) 2008 IR Cat. 2 2010 IR Cat. 2 Benthos (CB88) Good (2007) Fish Com (CF53) Excellent (2007) USE SUPPORT: SUPPORTING (0.8 MI) 2008 IR Cat. 2 2010 IR Cat. 2 Benthos (CB129) Good -Fair (2002) USE SUPPORT. SUPPORTING (9 Mi) 2008 IR Cat. 2010 IR Cat. 2 Fish Com (CF72) Good -Fair (2007) Watershed Recommendations Ft Action Plans As with the Lower Creek Watershed, this entire 10-digit watershed (Lake Rhodhiss-Catawba River) drains directly into Lake Rhodhiss or Lake Hickory making protection and enhancement of its water quality critical to protecting Lake Rhodhiss and Hickory. A multi -partnership effort led to the completion of the Lake Rhodhiss Watershed Management Plan 1.34 BENTHIC MACROINVERTEBRATE SAMPLE A165 Waterbody Location Station ID Date Bioclassification Gunpowder Cr SR 1718 CB114 08/01/07 Fair County Subbasin 8 digit HUC Latitude Longitude AU Number Level IV Ecoregion Caldwell 32 03050101 355039 812610 11-55-(1.5) Northern Inner Piedmont Stream Classification Drainage Area (mi2) Elevation (ft) Stream Width (m) Stream Depth (m) WS-Iv 19 1070 10 0.3 Visible Landuse (%) Forested/Wetland Urban Agriculture Other (describe) 60 20 20 0 Upstream NPDES Dischargers (>1MGD or <1MGD and within 1 mile) NPDES Number Volume (MGD) City of Lenoir, Gunpowder Creek WWTP NC0023736 2 Water Quality Parameters Temperature (°C) Dissolved Oxygen (mg/L) Specific Conductance (pS/cm) pH (s.u.) Water Clarity 20.6 7.4 103 6.7 slightly turbid Habitat Assessment Scores max) Channel Modification (5) Instream Habitat (20) Bottom Substrate (15) Pool Variety (10) Riffle Habitat (16) Left Bank Stability (7) Right Bank Stability (7) Light Penetration (10) Left Riparian Score (5) Right Riparian Score (5) Total Habitat Score (100) Sample Date 4 8 3 8 7 6 6 10 1 4 57 Sample ID Substrate ST Site Photograph mostly sand with small amounts of cobble and gravel near bridge EPT BI EPT BI Bioclassification 08/01/07 10283 --- 14 --- 4.80 Fair 08/21/02 8967 --- 23 --- 4.73 Good -Fair Taxonomic Analysis There was a loss of nine EPT taxa from the sampling event in 2002 compared to the effort in 2007. Most of the loss occurred within the Ephemeroptera as eight of those taxa collected in 2002 were not collected in 2007: Heterocloeon, Plauditus, Pseudocloeon propinquum, Baetisca, Caenis, Hexagenia, Heptagenia marginalis, and Stenacron pallidum. Maccaffertium pudicum was uncollected in 2002 and rare in 2007. Plecoptera were entirely different between the two sampling events: Leuctra, Acroneuria abnormis, and Pteronarcys were collected in 2002; Tallaperla and Perlesta in 2007. All stonefly taxa were rare in the sample from each year except for Pteronarcys , which was common in 2002. Conversely, Trichoptera were very similar in both years with only the loss of Leucotrichia pitciptes in 2007 (it was abundant in 2002). Abundant taxa in 2007 were Baetis pluto, Maccaffertium modestum, Isonychia, Cheumatopsyche, Hydropsyche betteni, and Neophylax oligius. Data Analysis The site is 7.5 miles southeast of Lenoir and about 2.5 miles stream -miles downstream of the City of Lenoir Gunpowder Creek WWTP. Macroinvertebrate habitat is quite limited at the site. The only rocky sustrate is an artifact of the bridge; otherwise bottom sustrate is almost entirely sand. The large loss of EPT taxa between 2002 and 2007 is not reflected by the EPT BI, i.e. it was not just sensitive taxa that were eliminated from the latter sample. However, the loss of 39% of the number of EPT taxa between the sampling events from 2002 to 2007 is significant. No particular stressor is indicated by the taxa lost. Macroinvertebrate habitat was limited for both sampling events and specific conductance is elevated, so differences in the benthic community are very likely due to additional water -borne stressors. 1-B.39 Gunpowder Creek WWTP Effluent Monitoring NC0023736 2.5 2.0 p 1.5 2 1.0 0.5 0.0 Flow • Mo Avg Limit • • • • • •• • • • •• •• • • • • ••i• •• • •• • • • • •,. • •• � O�� O,� 61\ O�� O,� O�� e O,� OHO O�y ti��y\� ro�ti�\� '���\� ��n�\� o\tip\� O,,,15 4,41, titiy\� ��tic\, ,\o, ti 50 45 40 35 30 Sao 25 E 20 15 10 5 0 Summary Statistics N 1461 Avg 1.213 SD 0.797 Min 0.197 Max 7.775 Summary Statistics N 995 Avg 6.3 SD 5.8 Min 0.7 Max 60 Summary Statistics N 996 Avg 8.7 SD 13.7 Min 0.17 Max 220 Page 1 of 6 GB Perlmutter, rev. 1/11/2021 Gunpowder Creek WWTP Effluent Monitoring NC0023736 Ammonia-N (NH3-N) Wk Avg ♦ Mo Avg 14 12 10 ▪ 8 E 6 4 2 0 WA Limit MA Limit ON' oti° oti oti ON' oti oti• ° oti° ov° otiy ti Summary Statistics Summer N 598 Avg 0.51 SD 0.71 Min 0.01 Max 6.41 Winter N 397 Avg 0.44 SD 0.34 Min 0.10 Max 5.00 Summary Statistics N 995 Avg 8.57 SD 0.75 Min 6.08 Max 10.70 Summary Statistics N 995 Geomean 14 Min 1 Max 110000 Page 2of6 GB Perlmutter, rev. 1/11/2021 Gunpowder Creek WWTP Effluent Monitoring NC0023736 10.0 9.0 8.0 7.0 6.0 5.0 4.0 pH • Effluent — — L. Limit U. Limit • • • • • • - - i • • • O(c) ON'°' 01° 01> °pc0' �\y61' '0' h\y41' y�\ti °\y90\1' 60 50 40 ▪ 30 20 10 0 Total Residual Chlorine(TRC) • Effluent • Limit Compliant . . I... �'. •r • / • • •t. • 9 .04. •• s y i .• • }• • •* J « o !' • • •s - - •4--s• tQv t : -• - ! • 1 • • • oti° oti° oti oti oti' oti' oti° oti° oti° otiy \°oti o\���ti �\�°\���ti h\yh�ti y�\ti�ti °\���ti Summary Statistics N 995 Avg 6.64 SD 0.23 Min 6.00 Max 8.63 Summary Statistics N 1444 Avg 23 SD 7 Min 7 Max 49 Summary Statistics N 995 Avg 18 SD 5 Min 6 Max 26 Page 3 of 6 GB Perlmutter, rev. 1/11/2021 Gunpowder Creek WWTP Effluent Monitoring NC0023736 Summary Statistics N 49 Avg 7.69 SD 3.19 Min 3.49 Max 13.90 Summary Statistics N 49 Avg 2.68 SD 1.63 Min 0.31 Max 6.61 Summary Statistics N 995 Avg 239 SD 55 Min 18 Max 478 Page 4 of 6 GB Perlmutter, rev. 1/11/2021 Gunpowder Creek WWTP Effluent Monitoring NC0023736 Summary Statistics N 49 Avg 0.2 SD 0.3 Min 0.2 Max 2.0 Summary Statistics N 48 Avg 5.2 SD 0.5 Min 5.0 Max 7.0 Summary Statistics N 17 Avg 13 SD 13 Min 1 Max 43 Page 5 of 6 GB Perlmutter, rev. 1/11/2021 Gunpowder Creek WWTP Effluent Monitoring NC0023736 4.5 4.0 3.5 3.0 2.5 D 2.0 1.5 1.0 0.5 0.0 Summary Statistics N 17 Avg 1 SD 1 Min 1 Max 4 Summary Statistics N 17 Avg 91 SD 118 Min 1 Max 507 Page 6 of 6 GB Perlmutter, rev. 1/11/2021 NC0023736 Gunpowder Cr WWTP BOD monthly removal rate Month RR (%) Month RR (%) August-16 September-16 October-16 November-16 December-16 January-17 February-17 March-17 April-17 May-17 June-17 July-17 August-17 September-17 October-17 November-17 December-17 January-18 February-18 March-18 April-18 May-18 June-18 July-18 August-18 September-18 October-18 November-18 December-18 January-19 97.51 98.35 98.38 96.87 97.50 95.79 95.92 94.95 96.73 97.51 97.64 96.56 97.99 98.46 97.49 97.73 98.22 95.91 96.80 96.36 95.83 97.02 97.48 98.07 98.14 98.46 97.64 96.76 96.85 92.51 February-19 March-19 April-19 May-19 June-19 July-19 August-19 September-19 October-19 November-19 December-19 January-20 February-20 March-20 April-20 May-20 June-20 July-20 August-20 September-20 October-20 November-20 December-20 January-21 February-21 March-21 April-21 May-21 June-21 July-21 92.13 91.97 92.80 97.72 97.96 97.66 97.52 98.89 98.40 98.27 97.15 98.25 96.83 97.32 96.76 94.17 92.54 97.86 #N/A #N/A #N/A #N/A #N/A #N/A #N/A Outfal 1001 1/11/2021 TSS monthly removal rate Month RR (%) Month RR (%) August-16 September-16 October-16 November-16 December-16 January-17 February-17 March-17 April-17 May-17 June-17 July-17 August-17 September-17 October-17 November-17 December-17 January-18 February-18 March-18 April-18 May-18 June-18 July-18 August-18 September-18 October-18 November-18 December-18 January-19 97.96 98.95 98.71 95.03 95.80 91.85 95.18 92.59 96.07 98.29 98.25 97.81 97.16 98.34 95.88 97.04 97.92 95.32 91.80 96.12 93.16 95.98 95.96 97.99 97.53 98.04 98.00 95.18 90.97 92.67 February-19 March-19 April-19 May-19 June-19 July-19 August-19 September-19 October-19 November-19 December-19 January-20 February-20 March-20 April-20 May-20 June-20 July-20 August-20 September-20 October-20 November-20 December-20 January-21 February-21 March-21 April-21 May-21 June-21 July-21 89.94 Summary Statistics 93.37 87.54 n 48 96.35 Avg 96.78 92.91 SD 1.79 98.55 Min 91.97 97.66 Max 98.89 98.90 TSS removal rate 97.28 n 48 94.65 Avg 95.57 93.60 SD 2.65 96.74 Min 87.54 95.48 Max 98.95 BOD removal rate 93.93 95.60 91.83 93.36 98.13 #N/A #N/A #N/A #N/A #N/A #N/A #N/A Overall BOD removal rate #N/A 1 Overall TSSD removal rate #N/A Gunpowder Creek WWTP Instream Monitoring NC0023736 Statistic Upstream Dnstream Effluent N Avg SD Min Max 345 8.80 1.24 6.9 14.2 345 8.64 1.21 7.1 13 345 8.36 0.70 6.4 10.4 t-Test: Paired Two Sample for Means Upstream Dnstream Mean Variance Observations Pearson Correlation Hypothesized Mean Difference df t Stat P(T<=t) one -tail t Critical one -tail P(T<=t) two -tail t Critical two -tail 8.803536 1.538601 345 0.969842 0 344 10.22094 6.84E-22 1.649295 1.37E-21 1.966884 8.637159 1.456086 345 Conclusion: downstream DO is significantly lower than upstream DO. Page 1 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NC0023736 Statistic N Avg SD Min Max Upstream 345 17.03 5.39 0.1 23.5 Dnstream 345 17.09 5.29 1.2 24.9 Up - Dn increase Effluent 345 345 0.06 8.36 1.05 0.70 -5.2 6.4 8.2 10.4 t-Test: Paired Two Sample for Means Upstream Dnstream Mean Variance Observations Pearson Correlation Hypothesized Mean Difference df t Stat P(T<=t) one -tail t Critical one -tail P(T<=t) two -tail t Critical two -tail 17.03285 29.09807 344 0.9808 0 343 -1.05067 0.147076 1.649308 0.294151 1.966904 17.09244 28.02647 344 Conclusion: Downstream Temperature is not statistically different from upstream Temperature. Page 2 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NC0023736 Statistic Upstream Dnstream N 345 345 Avg 62 72 SD 23 15 Min 35 7 Max 260 118 Effluent 345 244 49 90 387 t-Test: Paired Two Sample for Means Upstream Dnstream Mean Variance Observations Pearson Correlation Hypothesized Mean Difference df t Stat P(T<=t) one -tail t Critical one -tail P(T<=t) two -tail t Critical two -tail 62.00261 540.0021 345 0.098946 0 344 -7.15778 2.49E-12 1.649295 4.99E-12 1.966884 72.17933 226.6191 345 Conclusion: downstream Conductivity is higher than upstream Conductivity. Page 3 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NCO023736 100,000 10,000 1,000 100 U 10 1 Fecal Coliform • Upstream • Effluent • Dnstream • ! • ■ Y.►~♦♦ • ■ ••••:11% * 1r ■ • ■ ■ •• ■■ ■ ■� ON' O�� O,O � OLO O�y �\���ti N\�o�ti h\y��ti Statistic Upstream Dnstream Effluent N 345 345 345 Geomean 446 426 18 Min 4 21 1 Max 9400 11000 11300 Gunpowder Creek, 11-55-(1.5) upstream of WWTP Page 4 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NC0023736 10.0 9.0 8.0 7.0 6.0 5.0 4.0 • Upstream pH • Effluent Lower Std Upper Std Dnstream • • /\f O cb9' C)\���ti y�\ti�ti ��tiy\��ti Statistic Upstream Dnstream Effluent N Avg SD Min Max 345 7.2 0.3 6.1 8.3 345 7.0 0.3 6.0 8.3 345 6.6 0.2 6.0 8.2 t-Test: Paired Two Sample for Means Upstream Dnstream Mean Variance Observations Pearson Correlation Hypothesized Mean Difference df t Stat P(T<=t) one -tail t Critical one -tail P(T<=t) two -tail t Critical two -tail 7.171507 0.096249 345 0.533001 0 344 10.43686 1.23E-22 1.649295 2.45E-22 1.966884 7.01229 0.074014 345 Page 5 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NC0023736 16 14 12 10 g 6 4 2 0 Total Nitrogen • Upstream • Effluent • Dnstream r ■ ■ • •• • ■••• • � • • • • ■ ■ me■ ■ •. ■ •• $ 0'. o'° ti\�'Y °\tip\\ oti oti oti oti° oti° oti oti° 3\°\� °\tip�\ti°\� �o\tip\� h\tip'\� titi\ti\�\tip� Statistic Upstream Dnstream N 27 26 Avg 3.9 3.1 SD 2.9 2.1 Min 0.4 0.5 Max 9.1 7.6 Effluent 27 8.2 2.9 3.5 13.9 t-Test: Two -Sample Assuming Unequal Variances Upstream Dnstream Mean Variance Observations Hypothesized Mean Difference df t Stat P(T<=t) one -tail t Critical one -tail P(T<=t) two -tail t Critical two -tail 3.868222 8.636588 27 0 48 1.051034 0.149253 1.677224 0.298506 2.010635 3.127192 4.607711 26 Conclusion: no differences were detected between up- and downstream average TN. Page 6 of 7 GB Perlmutter 1/11/2021 Gunpowder Creek WWTP Instream Monitoring NC0023736 7.00 6.00 5.00 4.00 3.00 2.00 1.00 0.00 Total Phosphorus • Upstream • Effluent • Dnstream NM � w • ■ ■ ■ ■ ■ •• • Y • ■■ ■ • y • • • ONE Otis O,� Otis O�� O,� Otis 01O Off' Statistic Upstream Dnstream Effluent N 27 26 27 Avg 0.18 0.33 2.33 SD 0.16 0.23 1.59 Min 0.02 0.02 0.31 Max 0.54 0.76 6.61 Page 7 of 7 GB Perlmutter 1/11/2021 MONITORING REPORT(MR) VIOLATIONS for: Report Date: 10/02/2C Page 23 o1 24 Permit: NC0023736 MRs Betweei 0 - 2015 and10 - 2020 Facility Name: % Param Nam( % Major Minor: % Region: County: % Violation Category:Limit Violation Subbasin:% Program Category: NPDES WW Violation Action: % PERMIT: NC0023736 FACILITY: City of Lenoir - Gunpowder Creek WWTP COUNTY: Caldwell REGION: Asheville Limit Violation MONITORING OUTFACE REPORT LOCATION PARAMETER VIOLATION UNIT OF FREQUENCY DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 01-2020 001 01-2020 001 01-2020 001 02-2020 001 03-2020 001 04-2020 001 04-2020 001 05-2020 001 05-2020 001 05-2020 001 06-2020 001 06-2020 001 06-2020 001 06-2020 001 06-2020 001 01-2019 001 Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Effluent Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual Chlorine, Total Residual 01/03/20 5 X week 01/07/20 5 X week 01/13/20 5 X week 02/29/20 5 X week 03/24/20 5 X week 04/05/20 5 X week 04/06/20 5 X week 05/03/20 5 X week 05/20/20 5 X week 05/31/20 5 X week 06/04/20 5 X week 06/10/20 5 X week 06/15/20 5 X week 06/16/20 5 X week 06/18/20 5 X week ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I ug/I Coliform, Fecal MF, MFC 01/26/19 5 X week #/100m1 Broth, 44.5 C 28 31 10.7 Daily Maximum Exceeded 28 32 14.3 Daily Maximum Exceeded 28 30 7.1 Daily Maximum Exceeded 28 29 3.6 Daily Maximum Exceeded 28 38 35.7 Daily Maximum Exceeded 28 40 42.9 Daily Maximum Exceeded 28 39 39.3 Daily Maximum Exceeded 28 31 10.7 Daily Maximum Exceeded 28 42 50 Daily Maximum Exceeded 28 38 35.7 Daily Maximum Exceeded 28 47 67.9 Daily Maximum Exceeded 28 31 10.7 Daily Maximum Exceeded 28 29 3.6 Daily Maximum Exceeded 28 44 57.1 Daily Maximum Exceeded 28 38 35.7 Daily Maximum Exceeded 400 528.07 32.0 Weekly Geometric Mean Exceeded No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ No Action, BPJ Proceed to NOV MONITORING REPORT(MR) VIOLATIONS for: Report Date: 10/02/2C Page 24 of 24 Permit: NC0023736 MRs Betweei 0 - 2015 and10 - 2020 Facility Name: % Param Nam( % Major Minor: % Region: % Violation Category:Limit Violation Program Category: NPDES WW County: % Subbasin:% Violation Action: % PERMIT: NC0023736 FACILITY: City of Lenoir - Gunpowder Creek WWTP COUNTY: Caldwell REGION: Asheville Limit Violation MONITORING UNIT OF OUTFALL LOCATION PARAMETER VIOLATION FREQUENCY REPORT DATE MEASURE LIMIT CALCULATED VALUE Over VIOLATION TYPE VIOLATION ACTION 03 - 2017 001 Effluent Nitrogen, Ammonia Total (as 03/04/17 5 X week mg/I 12 12.81 6.8 Weekly Average Proceed to NOV N) - Concentration Exceeded 02-2019 001 Effluent pH 02/26/19 5 X week su 6 5.8 3.3 Daily Minimum Not Proceed to NOD Reached 06-2020 001 Effluent pH 06/09/20 5 X week su 9 67 644.4 Daily Maximum None Exceeded 04 - 2019 001 Effluent Solids, Total Suspended - 04/20/19 5 X week mg/I 45 53.5 18.9 Weekly Average Proceed to NOV Concentration Exceeded Whole Effluent Toxicity Testing and Self Monitoring Summary Lawrence Sprinkle-Weaverville WTP NC0085154/001 County: Buncombe Region: ARO Basin: FRB04 Jan Apr Jul Oct SOC JOC: Ceri7dPF Begin: 12/1/2015 Chr Monit: 90% NonComp: 7Q10: PF: IWC: Freq: Q J F M A M 1 J A S 0 N D 2016 Pass Pass - Fail - - Pass 2017 Pass - - Pass - Pass - - Pass 2018 Pass - - Pass Pass - - Pass 2019 Pass - - Pass - Pass - - Pass 2020 Pass - - Pass - - Pass - - - LCP Plastics, Inc. NC0036366/001 County: Guilford Region: WSRO Ceri7dPF Begin: 3/1/2003 fathead 24h LC50 ac + NonComp: Single 7Q10: 0.00 1 F M A M 1 2016 H - H 2017 - H - - H 2018 - H - - H - 2019 H - - H 2020 - H - - H - Basin: CPF08 Feb May Aug Nov PF: NA IWC: 100 Freq: Q P/F A S 0 H H H H SOC_JOC: N H H H H Lee S. Dukes WTP (CMUD) NC0084387/001 County: Mecklenburg Region: MRO Basin: CTB33 Jan Apr Jul Oct SOC JOC: Ceri7dPF Begin: 5/1/2015 Chr Monit: 37% NonComp: 7Q10: PF: IWC: Freq: Q J F M A M J J A S 0 N D 2016 Pass Pass Pass - Pass 2017 Pass - - Pass - Pass - - Pass - 2018 Pass - - Pass - Pass - - Pass - 2019 Pass - - Pass - - Pass - - Pass - 2020 Pass - - Pass - Pass - - Lenoir- Gunpowder Creek WWTP NC0023736/001 County: Caldwell Region: ARO Ceri7dPF Begin: 2/1/2012 chr lim: 52% NonComp: Single 7Q10: 3.0 J F M A M J 2016 Pass Pass 2017 - - Pass Pass 2018 - - Pass Pass >100(P) >100 Pass >100(P) 2019 - - Pass - - Pass 2020 - Pass - - Pass Lenoir- Lower Creek WWTP NC0023981/001 County: Caldwell Ceri7dPF Begin: 1/1/2017 chr lim: 44% NonComp: Single Basin: CTB32 Mar Jun Sep Dec PF: 2.0 IWC: 52.0 Freq: Q J A >100(P) J F M A M 2016 Pass - Pass 2017 - Pass - - Pass 2018 - Pass - - Pass 62.2(P) 2019 - Pass >100(P) - - Pass 2020 Pass - Pass Region: ARO SOC JOC: S 0 N D Pass - - Pass Pass - - Pass Pass - - Pass Pass - - Pass Basin: CTB31 Feb May Aug Nov SOC JOC: 7Q10: 11.75 PF: 6.0 J J IWC: 44 Freq: Q A Pass Pass Pass >100(P) Pass Pass S 0 N Pass Pass Pass >100(P) Pass Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facility is active). s = Solit test between Certified Labs Page 67 of 122 NH3/TRC WLA Calculations Gunpowder Creek WWTP PermitNo. NC0023736 Prepared By: Gary Perlmutter Enter Design Flow (MGD): Enter s7Q10 (cfs): Enter w7Q10 (cfs): 2 2.9 4 Total Residual Chlorine (TRC) Daily Maximum Limit (ug/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (UG/L) Upstream Bkgd (ug/I) IWC (%) Allowable Conc. (ug/I) Fecal Coliform Monthly Average Limit: (If DF >331; Monitor) (If DF<331; Limit) Dilution Factor (DF) 2.9 2 3.1 17.0 0 51.67 33 Ammonia (Summer) Monthly Average Limit (mg NH3-N/I) s7Q10 (CFS) DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Ammonia (Winter) Monthly Average Limit (mg NH3-N/I) w7Q10 (CFS) 200/100m1 DESIGN FLOW (MGD) DESIGN FLOW (CFS) STREAM STD (MG/L) 1.94 Upstream Bkgd (mg/I) IWC (%) Allowable Conc. (mg/I) Total Residual Chlorine 1. Cap Daily Max limit at 28 ug/I to protect for acute toxicity Ammonia (as NH3-N) 1. If Allowable Conc > 35 mg/I, Monitor Only 2. Monthly Avg limit x 3 = Weekly Avg limit (Municipals); capped at 35 mg/I 3. Monthly Avg limit x 5 = Daily Max limit (Non-Munis); capped at 35 mg/I 2.9 2 3.1 1.0 0.22 51.67 1.7 4 2 3.1 1.8 0.22 43.66 3.8 Fecal Coliform 1. Monthly Avg limit x 2 = 400/100 ml = Weekly Avg limit (Municipals) = Daily Max limit (Non -Muni) Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream HUC Number Stream Class ❑ CHECK IF HQW OR ORW WQS Gunpowder Creek WWTP IV NC0023736 001 2.000 Gunpowder Creek 03050101 Apply WS Hardness WQC 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1 Q10s (cfs) WS-IV 2.90 4.00 5.80 17.40 2.43 Effluent Hardness Upstream Hardness 25.4 mg/L (Avg) 25 mg/L (Avg) Combined Hardness Chronic 25.21 mg/L Combined Hardness Acute 25.22 mg/L Data Source(s) ❑ CHECK TO APPLY MODEL Darta are from DMRs with Hardness data provided by the Permittee upon request. All upstream hardness data are < 25 mg/L default value; 25 mg/L used instead. CHECK WQS NEED ADDITIONAL DATA INPUTS Table 2. Parameters of Concern Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 Par23 Par24 Name WQS Type Chronic Modifier Acute PQL Units Arsenic Aquactic Life C 150 FW 340 ug/L Arsenic Human Health Water Supply C 10 HH/WS N/A ug/L Beryllium Aquatic Life NC 6.5 FW 65 ug/L Cadmium Aquatic Life NC 0.5936 FW 3.2650 ug/L Chlorides Aquatic Life NC 230 FW mg/L Chlorinated Phenolic Compounds Water Supply NC 1 A ug/L yTotal Phenolic Compounds Aquatic Life NC 300 A ug/L Chromium III Aquatic Life NC 118.5290 FW 911.7250 ug/L Chromium VI Aquatic Life NC 11 FW 16 pg/L Chromium, Total Aquatic Life NC N/A FW N/A pg/L Copper Aquatic Life NC 7.9363 FW 10.5605 ug/L Cyanide Aquatic Life NC 5 FW 22 10 ug/L Fluoride Aquatic Life NC 1,800 FW ug/L Lead Aquatic Life NC 2.9690 FW 76.2500 ug/L Mercury Aquatic Life NC 12 FW 0.5 ng/L Molybdenum Human Health NC 2000 HH ug/L Nickel Aquatic Life NC 37.4916 FW 337.7505 pg/L Nickel Water Supply NC 25.0000 WS N/A pg/L Selenium Aquatic Life NC 5 FW 56 ug/L Silver Aquatic Life NC 0.06 FW 0.3010 ug/L Zinc Aquatic Life NC 127.6206 FW 126.6599 ug/L Chloroform Water Supply NC 60 WS pg/L Methyl Bromide Water Supply NC too° WS pg/L Nitrate -Nitrogen Water Supply NC 10 WS mg/L 23736 RPA 2020, input 1/11/2021 23736 RPA 2020, input 1/11/2021 REASONABLE POTENTIAL ANALYSIS H1 Effluent Hardness Date Data BDL=1/2DL Results 1 12/13/2016 26.9 26.9 Std Dev. 2 4/17/2018 17.4 17.4 Mean 3 10/12/2020 26.4 26.4 C.V. (default) 4 10/13/2020 22.4 22.4 n 5 10/14/2020 28.7 28.7 10th Per value 6 10/15/2020 24.3 24.3 Average Value 7 10/16/2020 31.7 31.7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 H2 Upstream Hardness 4.6195 25.4000 0.6000 7 20.40 mg/L 25.40 mg/L 31.70 mg/L Date Data BDL=1/2DL Results 1 25 25 Std Dev. 2 Mean 3 C.V. 4 n 5 10th Per value 6 Average Value 7 Max. Value 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 N/A 25.0000 0.0000 1 25.00 mg/L 25.00 mg/L 25.00 mg/L 23736 RPA 2020, data - 1 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Par01 & Par02 Arsenic Date Data BDL=1/2DL Results 1 12/13/2016 < 0.5 0.25 Std Dev. 2 3/16/2017 < 1 0.5 Mean 3 6/13/2017 < 0.5 0.25 C.V. 4 9/12/2017 < 10 5 n 5 12/12/2017 < 1 0.5 6 3/13/2018 < 0.5 0.25 Mult Factor = 7 4/17/2018 < 0.5 0.25 Max. Value 8 6/12/2018 < 1 0.5 Max. Pred Cw 9 9/11/2018 < 1 0.5 10 12/18/2018 0.16 0.16 11 3/12/2019 < 2 1 12 6/11/2019 < 2 1 13 9/17/2019 < 2 1 14 12/10/2019 < 2 1 15 3/10/2020 < 2 1 16 6/9/2020 < 2 1 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 1.1473 0.8850 1.2964 16 1.99 5.0 ug/L 10.0 ug/L 23736 RPA 2020, data - 2 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Par03 Beryllium Date Data BDL=1/2DL 10 10 12/13/2016 < 20 4/17/2018 < 20 Results Std Dev. Mean C.V. (default) n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par04 Cadmium 0.0000 10.0000 0.6000 2 3.79 10.00 ug/L 37.90 ug/L Date Data BDL=1/2DL 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 8/2/2016 9/13/2016 10/18/2016 11/2/2016 12/13/2016 1/17/2017 2/14/2017 3/16/2017 4/13/2017 5/11/2017 6/13/2017 8/1/2017 8/2/2017 8/15/2017 9/12/2017 10/10/2017 11/14/2017 12/12/2017 1/9/2018 2/13/2018 3/13/2018 4/17/2018 5/8/2018 6/12/2018 7/10/2018 8/14/2018 9/11/2018 10/9/2018 11/13/2018 12/18/2018 1/8/2019 2/12/2019 3/12/2019 4/24/2019 5/14/2019 6/11/2019 7/9/2019 8/12/2019 9/17/2019 10/15/2019 11/12/2019 12/10/2019 1/28/2020 2/11/2020 3/10/2020 4/27/2020 5/12/2020 6/9/2020 7/24/2020 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Results Std Dev. Mean C.V. n Mult Factor = Max. Value Max. Pred Cw Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 0.0143 0.1020 0.1400 49 1.01 0.200 ug/L 0.202 ug/L 23736 RPA 2020, data - 3 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Par05 Chlorides Date Data 12/13/2016 43.7 Use "PASTE SPECIAL - Values" then "COPY" . Maximum data points = 58 BDL=1/2DL Results 43.7 Std Dev. N/A Mean 43.7 C.V. (default) 0.6000 n 1 Mult Factor = Max. Value Max. Pred Cw 6.2 43.7 mg/L 270.9 mg/L Par06 Use "PASTE SI Values" then "1 . Maximum points = Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. NO DATA 4 n 0 5 6 Mult Factor = N/A 7 Max. Value N/A 8 Max. Pred Cw N/A 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chlorinated Phenolic Compounds 23736 RPA 2020, data - 4 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" fata i8 Par07 Total Phenolic Compounds ug/L ug/L Date Data BDL=1/2DL Results 1 12/16/2015 < 10 5 Std Dev. 2 12/13/2016 < 10 5 Mean 3 7/17/2018 < 10 5 C.V. (default) 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 0.0000 5.0000 0.6000 3 3.00 5.0 ug/L 15.0 ug/L Par08 Use "PASTE SF Values" then " ; . Maximum points = 5 Date Data BDL=1/2DL Results 1 Std Dev. NO DATA 2 Mean NO DATA 3 C.V. NO DATA 4 n 0 5 6 Mult Factor = N/A 7 Max. Value N/A 8 Max. Pred Cw N/A 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Chromium III 23736 RPA 2020, data - 5 - 1 /11 /2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iata i8 Par09 Chromium VI pg/L pg/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 Use "PASTE SPECIAL. Par10 Values" then "COPY" . Maximum data points = 58 Chromium, Total NO DATA NO DATA NO DATA 0 N/A N/A pg/L N/A pg/L Date Data BDL=1/2DL Results 1 12/13/2016 < 1 0.5 Std Dev. 3.3824 2 3/16/2017 14 14 Mean 1.5938 3 6/13/2017 3 3 C.V. 2.1223 4 9/12/2017 < 1 0.5 n 16 5 12/12/2017 < 1 0.5 6 3/13/2018 2 2 Mult Factor = 2.47 7 4/17/2018 < 1 0.5 Max. Value 14.0 8 6/12/2018 < 1 0.5 Max. Pred Cw 34.6 9 9/11/2018 < 1 0.5 10 12/18/2018 < 1 0.5 11 3/12/2019 < 1 0.5 12 6/11/2019 < 1 0.5 13 9/17/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 3/10/2020 < 1 0.5 16 6/9/2020 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SI Values" then " . Maximum points = 23736 RPA 2020, data - 6 - 1 /11 /2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" lath 18 Pal Copper pg/L pg/L Date Data BDL=1/2DL Results 1 9/13/2016 16 16 Std Dev. 2 12/13/2016 28 28 Mean 3 3/16/2017 29 29 C.V. 4 6/13/2017 < 1 0.5 n 5 9/12/2017 43 43 6 12/12/2017 < 1 0.5 Mult Factor = 7 3/13/2018 5 5 Max. Value 8 4/17/2018 23 23 Max. Pred Cw 9 6/12/2018 16 16 10 9/11/2018 < 1 0.5 11 12/18/2018 12 12 12 3/12/2019 21 21 13 6/11/2019 < 1 0.5 14 9/17/2019 < 1 0.5 15 12/10/2019 < 1 0.5 16 3/10/2020 10 10 17 6/9/2020 8 8 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 12.7393 12.5882 1.0120 17 1.74 43.00 ug/L 74.82 ug/L Par12 Use "PASTE SI Cyanide Values" then . Maximum( points = 5 Date Data BDL=1/2DL Results 1 8/2/2016 < 8 5 Std Dev. 0.0000 2 9/13/2016 5 5 Mean 5.00 3 10/18/2016 < 5 5 C.V. 0.0000 4 11/2/2016 6 5 n 48 5 12/13/2016 < 5 5 6 1/17/2017 5 5 Mult Factor = 1.00 7 2/14/2017 5 5 Max. Value 5.0 8 3/16/2017 7 5 Max. Pred Cw 5.0 9 4/13/2017 < 5 5 10 5/11/2017 < 5 5 11 6/13/2017 6 5 12 8/1/2017 < 5 5 13 8/2/2017 < 5 5 14 8/15/2017 < 5 5 15 9/12/2017 < 5 5 16 10/10/2017 < 5 5 17 11/14/2017 < 5 5 18 12/12/2017 7 5 19 1/9/2018 < 5 5 20 2/13/2018 5 5 21 3/13/2018 < 5 5 22 4/17/2018 5 5 23 5/8/2018 6 5 24 6/12/2018 < 5 5 25 7/10/2018 < 5 5 26 8/14/2018 < 5 5 27 9/11/2018 < 5 5 28 11/13/2018 < 5 5 29 12/18/2018 < 5 5 30 1/8/2019 < 5 5 31 2/12/2019 < 5 5 32 3/12/2019 < 5 5 33 4/24/2019 6 5 34 5/14/2019 < 5 5 35 6/11/2019 < 5 5 36 7/9/2019 5 5 37 8/12/2019 5 5 38 9/17/2019 < 5 5 39 10/15/2019 5 5 40 11/12/2019 < 5 5 41 12/10/2019 < 5 5 42 1/28/2020 < 5 5 43 2/11/2020 < 5 5 44 3/10/2020 < 5 5 45 4/27/2020 < 5 5 46 5/12/2020 5 5 47 6/9/2020 5 5 48 7/24/2020 < 5 5 49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data -7- 1/11/2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iata i8 Par13 Fluoride ug/L ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par14 Lead NO DATA NO DATA NO DATA 0 N/A N/A ug/L N/A ug/L Date BDL=1/2DL Results 1 12/13/2016 1.4 1.4 Std Dev. 2 3/16/2017 3.2 3.2 Mean 3 6/13/2017 98 98 C.V. 4 9/12/2017 < 10 5 n 5 12/12/2017 < 1 0.5 6 3/13/2018 0.57 0.57 Mult Factor = 7 4/17/2018 2.3 2.3 Max. Value 8 6/12/2018 < 1 0.5 Max. Pred Cw 9 9/11/2018 < 1 0.5 10 12/18/2018 0.39 0.39 11 3/12/2019 < 0.5 0.25 12 6/11/2019 < 0.5 0.25 13 9/17/2019 < 0.5 0.25 14 12/10/2019 < 0.5 0.25 15 3/10/2020 < 2 1 16 6/9/2020 < 0.5 0.25 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SI Values" then "i . Maximum( points = 5 24.2598 7.1631 3.3868 16 3.01 98.000 294.980 23736 RPA 2020, data - 8 - 1 /11 /2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iata i8 Par15 Mercury ug/L ug/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par16 Molybdenum NO DATA NO DATA NO DATA 0 N/A N/A ng/L N/A ng/L Use "PASTE SF Values" then " , . Maximum points = Date Data BDL=1/2DL Results 1 12/13/2016 < 1 0.5 Std Dev. 0.0000 2 3/16/2017 < 1 0.5 Mean 0.5000 3 6/13/2017 < 1 0.5 C.V. 0.0000 4 9/12/2017 < 1 0.5 n 16 5 12/12/2017 < 1 0.5 6 3/13/2018 < 1 0.5 Mult Factor = 1.00 7 4/17/2018 < 1 0.5 Max. Value 0.5 8 6/12/2018 < 1 0.5 Max. Pred Cw 0.5 9 9/11/2018 < 1 0.5 10 12/18/2018 < 1 0.5 11 3/12/2019 < 1 0.5 12 6/11/2019 < 1 0.5 13 9/17/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 3/10/2020 < 1 0.5 16 6/9/2020 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data - 9 - 1 /11 /2021 REASONABLE POTENTIAL ANALYSIS 'ECIAL COPY" iata 18 Par17 & Par18 Nickel ug/L ug/L Date Data BDL=1/2DL Results 1 12/13/2016 < 1 0.5 Std Dev. 2 3/16/2017 < 1 0.5 Mean 3 6/13/2017 < 1 0.5 C.V. 4 9/12/2017 < 1 0.5 n 5 12/12/2017 < 1 0.5 6 3/13/2018 < 1 0.5 Mult Factor = 7 4/17/2018 < 1 0.5 Max. Value 8 6/12/2018 < 1 0.5 Max. Pred Cw 9 9/11/2018 < 1 0.5 10 12/18/2018 < 1 0.5 11 3/12/2019 < 1 0.5 12 6/11/2019 < 1 0.5 13 9/17/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 3/10/2020 < 1 0.5 16 6/9/2020 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par19 Selenium 0.0000 0.5000 0.0000 16 1.00 0.5 pg/L 0.5 pg/L Date Data BDL=1/2DL Results 1 12/13/2016 < 0.5 0.25 Std Dev. 2 3/16/2017 < 1 0.5 Mean 3 6/13/2017 < 0.5 0.25 C.V. 4 9/12/2017 < 10 5 n 5 12/12/2017 < 1 0.5 6 3/13/2018 < 0.5 0.25 MultFactor= 7 4/17/2018 < 0.5 0.25 Max. Value 8 6/12/2018 < 1 0.5 Max. Pred Cw 9 9/11/2018 < 1 0.5 10 12/18/2018 < 0.5 0.25 11 3/12/2019 < 1 0.5 12 6/11/2019 < 1 0.5 13 9/17/2019 < 1 0.5 14 12/10/2019 < 1 0.5 15 3/10/2020 < 1 0.5 16 6/9/2020 < 1 0.5 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data - 10 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par20 Silver 1.1519 0.7031 1.6382 16 2.21 5.0 ug/L 11.1 ug/L Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Date Data BDL=1/2DL Results 1 9/13/2016 < 1 0.5 Std Dev. 0.8489 2 12/13/2016 < 1 0.5 Mean 0.7059 3 3/16/2017 4 4 C.V. 1.2026 4 6/13/2017 < 1 0.5 n 17 5 9/12/2017 < 1 0.5 6 12/12/2017 < 1 0.5 Mult Factor = 1.86 7 3/13/2018 < 1 0.5 Max. Value 4.000 ug/L 8 4/17/2018 < 1 0.5 Max. Pred Cw 7.440 ug/L 9 6/12/2018 < 1 0.5 10 9/11/2018 < 1 0.5 11 12/18/2018 < 1 0.5 12 3/12/2019 < 1 0.5 13 6/11/2019 < 1 0.5 14 9/17/2019 < 1 0.5 15 12/10/2019 < 1 0.5 16 3/10/2020 < 1 0.5 17 6/9/2020 < 1 0.5 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Par21 Zinc Date Data BDL=1/2DL Results 1 9/13/2016 105 105 Std Dev. 2 12/13/2016 139 139 Mean 3 3/16/2017 82 82 C.V. 4 6/13/2017 79 79 n 5 9/12/2017 507 507 6 12/12/2017 < 1 0.5 Mult Factor = 7 3/13/2018 41 41 Max. Value 8 4/17/2018 58 58 Max. Pred Cw 9 6/12/2018 88 88 10 9/11/2018 < 1 0.5 11 12/18/2018 5 5 12 3/12/2019 15 15 13 6/11/2019 < 1 0.5 14 9/17/2019 118 118 15 12/10/2019 61 61 16 3/10/2020 117 117 17 6/9/2020 134 134 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data - 11 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par22 Chloroform 117.5997 91.2059 1.2894 17 1.92 507.0 ug/L 973.4 ug/L Date Data BDL=1/2DL Results 1 12/16/2015 6.77 6.77 Std Dev. 2 12/13/2016 11.6 11.6 Mean 3 4/7/2018 6.35 6.35 C.V. (default) 4 n 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par23 Methyl Bromide 2.9174 8.2400 0.6000 3 Mult Factor = 3.00 Max. Value 11.600000 pg/L Max. Pred Cw 34.800000 pg/L Date Data BDL=1/2DL 1 12/16/2015 < 5 2.5 2 12/13/2016 6.25 6.25 3 4/7/2018 < 5 2.5 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data - 12 - 1 /11 /2021 REASONABLE POTENTIAL ANALYSIS e Results Std Dev. Mean C.V. (default) n Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 Par24 Nitrate -Nitrogen 2.1651 3.7500 0.6000 3 Mult Factor = 3.00 Max. Value 6.250000 pg/L Max. Pred Cw 18.750000 pg/L Date Data BDL=1/2DL Results 1 Std Dev. 2 Mean 3 C.V. 4 n 5 6 Mult Factor = 7 Max. Value 8 Max. Pred Cw 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 Par25 Total Nitrogen NO DATA NO DATA NO DATA 0 N/A N/A mg/L N/A mg/L Date Data BDL=1/2DL 1 8/2/2016 6.23 6.23 2 9/13/2016 6.55 6.55 3 10/18/2016 4.83 4.83 4 11/2/2016 6.97 6.97 5 12/13/2016 3.6 3.6 6 1/17/2017 7.09 7.09 7 2/14/2017 6.43 6.43 8 3/16/2017 11.04 11.04 9 4/13/2017 12.6 12.6 10 5/11/2017 10.9 10.9 11 6/13/2017 11.9 11.9 12 8/1/2017 13.9 13.9 13 8/2/2017 13.89 13.89 14 8/15/2017 10.58 10.58 15 9/12/2017 11.58 11.58 16 10/10/2017 13.2 13.2 17 11/14/2017 11.47 11.47 18 12/12/2017 9.9 9.9 19 1/9/2018 11.8 11.8 20 2/13/2018 9.86 9.86 21 3/13/2018 9.63 9.63 22 4/17/2018 8.57 8.57 23 5/8/2018 9.8 9.8 24 6/12/2018 9.92 9.92 25 7/10/2018 9.33 9.33 26 8/14/2018 9.33 9.33 27 9/11/2018 9.1 9.1 28 10/9/2018 10.58 10.58 29 11/13/2018 7.7 7.7 30 12/18/2018 8.97 8.97 31 1/8/2019 8.26 8.26 32 2/12/2019 4.83 4.83 33 3/12/2019 4.4 4.4 34 4/24/2019 3.81 3.81 35 5/14/2019 4.95 4.95 36 6/12/2019 3.86 3.86 37 7/9/2019 4.27 4.27 38 8/12/2019 4.4 4.4 39 9/17/2019 5.46 5.46 40 10/15/2019 6 6 41 11/12/2019 4.54 4.54 42 12/10/2019 3.58 3.58 43 1/28/2020 3.59 3.59 44 2/11/2020 4.58 4.58 45 3/10/2020 4.64 4.64 46 4/27/2020 4.09 4.09 47 5/12/2020 4.83 4.83 48 6/9/2020 5.77 5.77 49 7/24/2020 3.49 3.49 50 51 52 53 54 55 56 57 58 23736 RPA 2020, data - 13 - 1/11/2021 REASONABLE POTENTIAL ANALYSIS Results Std Dev. Mean C.V. n Use "PASTE SPECIAL Values" then "COPY" . Maximum data points = 58 3.1920 7.6857 0.4153 49 Mult Factor = 1.03 Max. Value 13.900000 mg/L Max. Pred Cw 14.317000 mg/L 23736 RPA 2020, data - 14 - 1 /11 /2021 Gunpowder Creek WWTP NC0023736 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw (MGD) = 2.0000 1Q1OS (cfs) = 2.43 7Q1OS (cfs) = 2.90 7Q1OW (cfs) = 4.00 30Q2 (cfs) = 5.80 Avg. Stream Flow, QA (cfs) = 17.40 Receiving Stream: Gunpowder Creek HUC 03050101 WWTP/WTP Class: IV IWC% @ 1Q1OS = 56.05786618 IWC% @ 7Q1OS = 51.66666667 IWC% @ 7Q1OW = 43.66197183 IWC% @ 30Q2 = 34.83146067 IW%C @ QA = 15.12195122 Stream Class: WS-IV Outfall 001 Qw = 2 MGD COMBINED HARDNESS (mg/L) Acute = 25.22 mg/L Chronic = 25.21 mg/L YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY Effluent Hard: 0 value > 100 mg/L Effluent Hard Avg = 25.4 mg/L PARAMETER TYPE NC STANDARDS OR EPA CRITERIA J a cn F n REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Applied Chronic Standard Acute tl # Det. Max Pred Cw Allowable Cw Arsenic Arsenic C C 150 FW(7Q10s) 340 10 HH/WS(Qavg) ug/L ug/L 16 1 10.0 Acute (FW): 606.5 __ _ _ ______________________________________ Chronic (FW): 290.3 No value > Allowable Cw _ _ Chronic (HH) 66.1 No value > Allowable Cw 1 _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Beryllium NC 6.5 FW(7Q10s) 65 ug/L 2 0 Note: n < 9 Limited data set 37.90 C.V. (default) NO DETECTS Acute: 115.95 ____ __________________________ Chronic: 12.58 Max MDL = 20 No detects at < 20 ug/L; PQL is 5 ug/L. Notify to test and report to lower level. Cadmium NC 0.5936 FW(7Q10s) 3.2650 ug/L 49 1 0.202 Acute: 5.824 __ _ _ ______ _____ Chronic: 1.149 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Chlorides NC 230 FW(7Q10s) mg/L 1 1 Note: n < 9 Limited data set 270.9 C.V. (default) Acute: NO WQS ____ _____________ Chronic: 445.2 No value > Allowable Cw ___________ No RP (Limited data, n < 8); no monitoring required Chlorinated Phenolic Compounds NC 1 A(30Q2) ug/L 0 0 N/A Acute: NO WQS __ _ _ ____________ Chronic: 2.9 _ _ _ _ _ _ _ _ _ _ _ _ _ _ Total Phenols MDL < Chlorinated Phenol Allowable Cw - apply quarterly monitoring. Total Phenolic Compounds NC 300 A(30Q2) ug/L 3 0 Note: n < 9 Limited data set 15.0 C.V. (default) NO DETECTS Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 861.3 Max MDL = 10 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Chromium III NC 118.5290 FW(7Q10s) 911.7250 µg/L 0 0 N/A Acute: 1,626.4 -- Chronic: -----229.4-------------------------------- Chromium VI NC 11 FW(7Q10s) 16 µg/L 0 0 N/A Acute: 28.5 -------------------------------- Chromium, Total NC µg/L Tot Cr value(s) 16 3 > 5 but < Cr VI 34.6 Allowable Cw Max reported value = 14 b: Maintain Total Chromium monitoring or defer to LMTP if any Total Chromium sample is >_ 50% of but < the Chromium VI Allowable Cw. Copper NC 7.9363 FW(7Q10s) 10.5605 ug/L 17 11 74.82 Acute: 18.84 RP shown - apply Monthly Monitoring with Limit Page 1 of 3 23736 RPA 2020, rpa 1 /11 /2021 Gunpowder Creek WWTP NC0023736 Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators Outfall 001 Qw = 2 MGD Chronic: 15.36 7 value(s) > Allowable Cw ----------------------- - - Cyanide NC 5 FW(7Q10s) 22 10 ug/L 48 16 5.0__________________ Acute: 39.2 Chronic: 9.7 No value > Allowable Cw No RP, Predicted Max < 10 ug/L, considered the compliance level. Fluoride NC 1800 FW(7Q10s) ug/L 0 0 N/A Acute: NO WQS -_ _ ---_ _ -Chronic: -------------------------------- 3,483.9 Lead NC 2.9690 FW(7Q10s) 76.2500 ug/L 16 6 294.980 Acute: 136.020 Inc' 5.746 I value(s) > Allowable Cw RP shown - apply Monthly Monitoring with Limit Mercury NC 12 FW(7Q10s) 0.5 ng/L 0 0 N/A Acute: NO WQS -_ _ ----- _ _ -Chronic: -------------------------------- 23.2 Molybdenum NC 2000 HH(7Q10s) ug/L 16 0 0.5 NO DETECTS Acute: NO WQS ____ __________________________ Chronic: 3,871.0 Max MDL = 1 No detects at < 1 ug/L. No monitoring or limits required. Nickel Nickel NC NC 37.4916 FW(7Q10s) 337.7505 25.0000 WS(7Q10s) µg/L µg/L 16 0 0.5 NO DETECTS Acute (FW): 602.5 __ _ _ - _ _ Chronic (FW): 72.6 Max MDL _____________ Chronic (WS):48.4 Max MDL = 1 - - - ___ No detects at < 1 ug/L. No monitoring or limits required. Selenium NC 5 FW(7Q10s) 56 ug/L 16 0 11.1 NO DETECTS Acute: 99.9 _______________________________ Chronic: 9.7 Max MDL = 10 No detects at < 10, < 1, < 0.5 ug/L. No monitoring or limits required. Silver NC 0.06 FW(7Q10s) 0.3010 ug/L 17 1 7.440 Acute: 0.537 ____ _________________________ Chronic: 0.116 17 value(s) > Allowable Cw RP shown based on one detection of 4 ug/L in 2017; no limit or monitoring required based on BPJ Zinc NC 127.6206 FW(7Q10s) 126.6599 ug/L 17 14 973.4 Acute: 225.9 ___ ______________ Chronic: 247.0 1 value(s) > Allowable Cw _____ RP shown - apply Monthly Monitoring with Limit Chloroform NC 60 WS(7Q10s) µg/L 3 3 Note: n < 9 Limited data set 34.80000 C.V. (default) Acute: NO WQS ___ ____________________ Chronic: 116.12903 No value > Allowable Cw No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Methyl Bromide NC 1000 WS(7Q10s) µg/L 3 1 Note: n < 9 Limited data set 18.75000 C.V. (default) Acute: NO WQS _ _ _ _ _ _ _ _ _ _ _ _ Chronic: 1935.48387 No value > Allowable Cw _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ No RP, Predicted Max < 50% of Allowable Cw - No Monitoring required Nitrate -Nitrogen NC 10 WS(7Q10s) mg/L 0 0 N/A Acute: NO WQS ____ ________________________ Chronic: 19.35484 Total Nitrogen Predicted Max < Allowable Cw - No Monitoring required. Acute: NO WQS Page 2 of 3 23736 RPA 2020, rpa 1 /11 /2021 Gunpowder Creek WWTP NC0023736 Total Nitrogen Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators NC FW(???) mg/L 49 49 1 14.31700 ric: No Chvalue on > Allowable Cw Outfall 001 Qw = 2 MGD 23736 RPA 2020, rpa Page 3 of 3 1/11/2021 FACILITY: Gunpowder Creek WWTP Outfall 001 NPDES PERMIT: NC0023736 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Stream summer 7Q10 (CFS) Receiving Stream summer 7Q10 (MGD) Rec. Stream 1Q10 [MGD] NPDES Flow Limit [MGD] Total Suspended Solids -Fixed Value- (mg/L) Combined Hardness chronic (mg/L) Combined Hardness Acute (mg/L) Instream Wastewater Concentration Chronic) Instream Wastewater Concentration (Acute) UpstreamHardness Hardness Average (mg/L) Effluent Average (mg/L) 2.9000 1.8710 1.5677 2.0000 10 25.207 25.224 51.6667 56.0579 25 25.4 PARAMETER Cadmium (d) Cd -Trout streams Dissolved Metals Criteria after applying hardness equation Chronic Acute [ug/I] 0.15 0.15 [ug/I] 0.82 0.51 US EPA Translators- using Default Partition Coefficients (streams) 0.252 0.252 Total Metal Criteria Total Metal = Dissolved Metal+Translator Chronic Acute Upstream Hard Avg (mg/L) = 25 EFF Hard Avg (mg/L) = 25.4 [ug/I] 0.59 0.59 [ug/I] 3.26 2.03 Chromium III (d)(h) Chromium VI (d) Chromium, Total (t) Copper (d)(h) Lead (d)(h) 24 11 2.8 0.55 184 16 3.7 14 0.202 1.000 0.348 0.184 118.53 11.00 N/A 7.94 2.97 911.72 16.00 N/A 10.56 76.25 Nickel (d)(h Silver (d)(h,acute) Zinc (d)(h) 16 0.06 37 146 0.30 36 0.432 1.000 0.288 37.49 0.06 127.62 337.75 0.30 126.66 Beryllium 6.5 Arsenic (d) 150 65 340 1.000 1..16 000 6.5 150 COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more information. (t) = based upon measurement of total recoveable metal. See 15A NCAC 02B .0211 for more information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which is Total Recoverable metal standard. The Human Health standard for Arsenic is 10 pg/L which is Total Recoverable metal standard. Permit No. NC0023736 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/1 (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, µg/I Cadmium, Acute WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151 [In hardness]-3.1485} Cadmium, Acute Trout waters WER*{1.136672-[ln hardness](0.041838)} • e^{0.9151[ln hardness]-3.6236} Cadmium, Chronic WER*{1.101672-[ln hardness](0.041838)} • e^{0.7998[ln hardness]-4.4451} Chromium III, Acute WER*0.316 • e^{0.8190[ln hardness]+3.7256} Chromium III, Chronic WER*0.860 • e^{0.8190[ln hardness]+0.6848} Copper, Acute WER*0.960 • e^{0.9422[In hardness]-1.700} Copper, Chronic WER*0.960 • e^{0.8545[ln hardness]-1.702} Lead, Acute WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[In hardness]-1.460} Lead, Chronic WER*{1.46203-[ln hardness](0.145712)} • e^{1.273[In hardness]-4.705} Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255} Nickel, Chronic WER*0.997 • e^{0.8460[ln hardness]+0.0584} Page 1 of 4 Permit No. NC0023736 Silver, Acute WER*0.85 • e^{1.72[In hardness]-6.59} Silver, Chronic Not applicable Zinc, Acute WER*0.978 • e^{0.8473[ln hardness]+0.884} Zinc, Chronic WER*0.986 • e^{0.8473[In hardness]+0.884} General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WQBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q10 (the spreadsheet automatically calculates the 1Q10 using the formula 1Q10 = 0.843 (s7Q10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. Page 2 of 4 Permit No. NC0023736 The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q10, cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q10, cfs) The Combined Hardness for acute is the same but the calculation uses the 1 Q 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator: Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: Cdiss = 1 Ctotal 1 + { [Kpo] [SS(1+a)] [10-6] } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q10 may be incorporated as applicable: 1 Q 10 = used in the equation to protect aquatic life from acute toxicity Page 3 of 4 Permit No. NC0023736 QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness, mg/L (Total as CaCO3) 25.4 Data provided by Permittee Average Upstream Hardness, mg/L (Total as CaCO3) 25 Default value (Data provided by Permittee were all < 25 mg/L) 7Q10 summer (cfs) 2.9 Reported in previous permit Fact Sheet 1Q10 (cfs) 2.43 Calculated in RPA spreadsheet Permitted Flow (MGD) 2.0 Design flow Date: November 20, 2020 Permit Writer: Ga Perlmutter Page 4 of 4 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgela bslenoir@gmair.com Client : Attention Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett l 6-Oct-20 30-Oct-20 14-Oct-20 BRL-2020-0692 LS1D-2020-02802 101420H-GCUP Result MQL 19.4 0,03 Reported By: Gc,41 Vdf'1 Unit Method Analysis Time Analysis Date Analyst rng/1 2340B 1997 10:29 10/30/2020 KCJ * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 11 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.cam Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 30-Oct-20 12-Oct-20 BRL-2020-0692 LSID-2020-02799 101220H-GEFF Result MQL 26.4 0.03 Reported 13y: Unit E:-If toil 7-- Analysis Method Tim e Analysis Date Analyst mgll 2340B 1997 10:23 10/30/2020 KCJ S. J. JohnS'6ti, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 11 lue Ridge Labs PU Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmaii.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 30-Oct-20 12-Oct-20 BRL-2020-0692 LSID-2020-02798 101220H-GCUP Result 16.2 Reported 13y: (A? Analysis Analysis MQL Unit Method Time 0.03 mgil 2340B 1997 10:21 10/30/2020 F 4i S. J. Johnson, D.R. Wessinger 4' Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 11 Date Analyst KCJ Blue Bulge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir©gmail.com Client : Attention: Date Received: Report Date: Sample Date: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 30-Oct-20 13-Oct-20 I3RI, 2020-0692 LSID-2020-02801 101320H-GEFF Result MQL Unit Method 22.4 0.03 mg/I 2340E 1997 Reported By: o Analysis Time Analysis Date Analyst 10:27 10/30/2020 KCJ S. J. Joson, D.R. Wessinger Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 11 Blue Ridge Labs pp Vox 2940 Lerrdrr, NC 28645 828-728-0149 Client : Attention: Date Received: Report Date: Sample Date: BRI, #: 1-,ab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 30-Oct-20 13-Oct-20 BRL-2020-0692 LSTD-2020-02800 101320H-GCUP Result MQL 14.8 0.03 Reported 13y: blueridgela bslenoir@gma il.coni 6 (Jo Unit Method mg/l 234013 1997 Analysis Time 10:2.5 AnalYsis Date 10(30/:2020 S. J. Johnsen, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 11 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 17-Nov-20 14-Oct-20 BRL-2020-0692 LSID-2020-02803 101420H-GEFF Parameter Result GEFF 10/14 Reissued due to typographical error. Analysis Analysis MQL Unit Method Time Hardness 28.7 0.03 mg/1 2340B 1997 10:31 Reported By: S..l. nson, l).12. Wessinger Date Analyst 10/30/2020 KCJ * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 1 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 05-Nov-20 15-Oct-20 BRL-2020-0692 LS1D-2020-02804 101520H-GCUP Parameter Hardness Result MQL Gup 10/15 Reissued due to typographical error on COC. Analysis Analysis Unit Method Time 15.7 0.03 Reported By: Date Analyst mg/1 2340E 1997 10:33 10/30/2020 KC/ S. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 11 Blue Ridge Labs P4 Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 05-Nov-20 15-Oct-20 BRL-2020-0692 LSID-2020-02805 101520H-GEFF Result IVIQL 24.3 0.03 Reported By: GEFF 10/15 Reissued due to typographical error on COC. Analysis Analysis Unit Method Time Date Analyst mg/1 2340B 1997 10:35 10/30/2020 KCJ S. 'l ()boson, D.R. Wessinger Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 11 Blue Ridge Labs Pa Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmaii.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Hardness City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 16-Oct-20 30-Oct-20 16-Oct-20 BRL-2020-0692 LSCD-2020-02807 101620H-GEFF Result MQL 31.7 0.03 Reported By: Unit Method mgll 2340B 1997 6% 130(0 Analysis Time Analysis Date Analyst 10:39 10/30/2020 * Concentrations are below Minimum Quantification Limitexcept where noted. NC Laboratory Certificate No. 275 Page 10 of 11 KGi Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett Date Received: 16-Oct-20 Report Date: 30-Oct-20 Sample Date: 16-Oct-20 BRL #: BRL-2020-0692 Lab Sample ID: LSID-20204J2806 Client Sample ID: 101620H-GCUP up 00 Analysis Analysis Parameter Result MQL Unit Method Time [)ate Amalysl Hardness 20.2 0.03 mg/1 2340B 1997 10:37 10/30/2020 KCJ Reported By: S. ' nson, D.R. Wessinger '" Concentrations are below Minimum Quantification 1irimit except where noted. NC Laboratory Certificate No. 275 Page 9 of 11 1/11/21 WQS = 12 ng/L Facility Name City of Lenoir - Gunpowder Cr WWTP/NC0023736 /Permit No. : Total Mercury 1631E PQL = 0.5 ng/L 7Q10s = Date Modifier Data Entry Value Permitted Flow = 12/13/16 < 1 12/19/16 < 1 3/16/17 2.3 6/13/17 < 1 9/12/17 < 1 12/12/17 < 1 3/13/18 < 1 4/17/18 < 1 6/12/18 < 1 9/11/18 1.1 12/21/18 < 1 3/12/19 < 1 6/11/19 < 1 9/17/19 < 1 12/10/19 3.1 3/10/20 < 1 6/9/20 1.2 MERCURY WQBEL/TBEL EVALUATION V:2013-6 No Limit Required MMP Required 0.5 0.5 2.3 0.5 0.5 0.5 0.5 0.5 0.5 1.1 0.5 0.5 0.5 0.5 3.1 0.5 1.2 2.900 2.000 cfs WQBEL = 23.23 ng/L 47 ng/L 0.5 ng/L - Annual Average for 2016 1.0 ng/L - Annual Average for 2017 0.6 ng/L - Annual Average for 2018 1.2 ng/L - Annual Average for 2019 0.9 ng/L - Annual Average for 2020 City of Lenoir - Gunpowder Cr WWTP/NC0023736 Mercury Data Statistics (Method 1631E) 2016 2017 2018 2019 2020 # of Samples 2 4 5 4 2 Annual Average, ng/L 0.5 1.0 0.6 1.2 0.9 Maximum Value, ng/L 0.50 2.30 1.10 3.10 1.20 TBEL, ng/L 47 WQBEL, ng/L 23.2 INVOICE Blue Ridge Labs, Inc. Invoice # 2017- 0707 Date: 9/29/2017 P.O. Box 2940 Lenoir. NC 28645 Phone: 8287280149 Fax: 8287280131 Client: Citv of Lenoir P. O. Box 958 Bill To: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lenoir, NC 28645 PO NUMBER LAB REF. ID TERMS LAB CONTACT 731 Net 10 Days Steve Johnson PROJECT NAME Sample Name 091117-GfN, 091117-GIM, 091117-GICN, 091217-GEM, 091217-GEN, 091217-GECN, 091217-GUN, 091217-GUN, 091217-GDN, 091217-GDN TARGET NAME QUANTITY UNIT PRICE EXTENDED PRICE Ag by ICP 2 $12.00 $24.00 Cd bu ICP 2 $12.00 $24.00 Cr by ICP 2 $12.00 $24.00 Cu by ICP 2 $12.00 $24.00 Cyanide 2 $35.00 $70. 00 Hg by Cold Vapor 2 $35.00 $70.00 Mo by ICP 2 $12.00 $24.00 Ni by ICP 2 $12.00 $24.00 Total Nitrogen 4 $40.00 $160.00 Total Phosphorus 4 $20.00 $80.00 Zn by ICP 2 $12.00 $24.00 Please Remit: $548.00 Upon submission of samples, buyer agrees that invoices are due at time of delivery. Open accounts are due 20 days following the invoice date. A finance charge of 1.5 % per month will be imposed on all past -due accounts. When relinquishing samples to Blue Ridge Labs, buyer agrees to pay all collection and attorneys fees if the account becomes deliquent. Blue Ridge Labs reserves the right to deny all QC and support documentation for all open accounts which are greater than 60 days. Additionally, Blue Ridge Labs also reserves the right to inform the appropriate local, state or federal agency that all support documentation is not available due to the failure to the above invoice teens. Data used for compliance purposes will be rendered invalid for reporting until the account is cleared. Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 11-Sep-07 BRL-2017-0731 LSID-2017-02761 Client Sample ID: 091117-GIN Parameter N2+N3 TKN Result MQL Unit Analysis Analysis Method Time Date Reported By: 3.96 0.08 mg/I SM19 4500-N 19:56 9/24/2017 13.7 0.5 mg/I SM19 4500-N 16:01 9/15/2017 S. J. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 10 Analyst KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample DI: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 11-Sep-17 BRL-2017-0731 LSID-2017-02762 091117-GIM Parameter Ag Cd Cr Cu Mo Ni Total Phosphorus Zn Hg Result MQL Unit Method Analysis Analysis Time Date Analyst Reported By: * 0.001 * 0.0002 * 0.001 0.043 0.001 * 0.001 * 0.001 2.41 0.02 0.106 0.001 * 0.0001 mg/I 200.7 1994 20:14 9/27/2017 KCJ mg/I 200.7 1994 20:14 9/27/2017 KCJ mg/l 200.7 1994 20:14 9/27/2017 KCJ mg/1 200.7 1994 20:14 9/27/2017 KCJ mg/1 200.7 1994 20:14 9/27/2017 KCJ mg/I 200.7 1994 20:14 9/27/2017 KCJ mg/1 200.7 1994 20:14 9/27/2017 KCJ mg/I 200.7 1994 20:14 9/27/2017 KCJ mg/l 245.1 1994 16:20 9/22/2017 KCJ S. J. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 10 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P.O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 11-Sep-17 BRL-2017-0731 LSID-2017-02763 091117-GICN Reported By: Result MQL 0.007 0.005 Analysis Analysis Unit Method Time Date Analyst KCJ mg/I 4500-CN-E 1 17:45 9/25/2017 S. J.' ' h neon, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 10 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag Cd Cr Cu Mo Ni Total Phosphorus Zn Hg City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LSID-2017-02764 091217-GEM Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 0.001 mg/1 200.7 1994 20:16 9/27/2017 KCJ * 0.0002 mg/1 200.7 1994 20:16 9/27/2017 KCJ * 0.001 mg/I 200.7 1994 20:16 9/27/2017 KCJ 0.051 0.001 mg/I 200.7 1994 20:16 9/27/2017 KCJ * 0.001 mg/I 200.7 1994 20:16 9/27/2017 KCJ * 0.001 mg/1 200.7 1994 20:16 9/27/2017 KC] 2.65 0.02 mg/I 200.7 1994 20:16 9/27/2017 KCJ 0.507 0.001 mg/I 200.7 1994 20:16 9/27/2017 KCJ * 0.0001 mg/I 245.1 1994 16:22 9/22/2017 KCJ Arroir �� - S. J. Idi oson, D.R. Wessinger * Concentrations are below Minimum Quantification tidilt except where noted. NC Laboratory Certificate No. 275 Page 4 of 10 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LSID-2017-02765 091217-GEN Reported By: Result MQL 2.62 0.08 8.96 0.5 Analysis Analysis Unit Method Time Date mg/1 SM19 4500-N 19:58 9/24/2017 mg/1 SM194500-N 16:55 9/15/2017 S. Jfir nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 10 Analyst KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LSID-2017-02766 091217-GECN Reported By: Result MQL * 0.005 Unit Method ------ ------ mg/I 4500-CN-E 1 17:47 9.125/2017 S. J nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 10 Analysis Analysis Time Date Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LSID-2017-02767 091217-GUN Result 1.33 6.02 Reported By: MQL Unit Method 0.08 mg/I SM19 4500-N 0.5 mg/I SM19 4500-N `.'Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page7of 10 Analysis Analysis Time Date Analyst 20:01 9/24/2017 KCJ KCJ 17:39 9/15/2017 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 21-Sep-17 BRL-2017-0731 LSID-2017-02768 091217-GUN Parameter Result MQL Total Phosphorus 0.060 Reported By: 0.02 Unit Method mg/1 200.7 1994 20:20 9/27/2017 Analysis Time S. J. Ji .son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 10 Analysis Date Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LSID-2017-02769 091217-GDN Parameter N2+N3 TKN Reported By: Analysis Result MQL Unit Method Time 0.71 0.08 mg/I SM194500-N 20:01 4.90 0.5 mg/1 SM194500-N 18:10 S. J. J (ton, D.R. Wessinger Analysis Date Analyst 9/24/2017 9/15/2017 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 10 KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 12-Sep-17 29-Sep-17 12-Sep-17 BRL-2017-0731 LS1D-2017-02770 091217-GDN Parameter Total Phosphorus Reported By: Result MQL Unit Method * 0.02 mg/1 200.7 1994 S. J. nson, D.R. Wessinger Analysis Analysis Time Date Analyst 22:02 9/27/2017 KCJ * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 10 13( 0 a L i� Analysis Requested 21- q. a ,(s- 1 -, N! U Q 7 1 V �) S s2 ^'a x 4.- .a c $ iN6 n Z �"" G co ! L. E G 5U 5° d nt 6 moo¢ g €t 1 't `n V'A X NA N Field bechlorination Y ' N \ \ \ \ \ \ \ 72oo-z Uc_t} \ \ \ \ \ \ N. \ . �>z p E is. c, 0.]. y�iT \ \ \ \ \ \ \ G '"? z m \ , \ \ \ l \ \ 0E u =S. a° Q O t p O t 'i O O p' trs Y ; p m S O. i1 cf,E. \1 �1 � \) � � .3 t... , (r.....r.... r� 39 Ctz/k IN':. INVOICE Blue Ridge Labs, Inc. Invoice # 2017- 0163 Date: 3/31/2017 P.O. Box 2940 Lenoir. NC 28645 Phone: 8287280149 Fax: 8287280131 Client: Citv of Lenoir P. O. Box 958 Lenoir, NC 28645 PO NUMBER LAB REF. ID TERMS 155 Bill To: LAB CONTACT Net 10 Days Steve Johnson City of Lenoir P. O. Box 958 Lenoir, NC 28645 PROJECT NAME Sample Name 031617-LEFF, 031617-GEFF,031617-GD, 031617-GUP, 031517-GINF TARGET NAME Ag by ICP Cd bu ICP Cr by ICP Cu by ICP Cyanide Ng by Cold Vapor Mo by ICP Ni by ICP Total Nitrogen Total Phosphorus Zn by ICP QUANTITY UNIT PRICE EXTENDED PRICE 3 3 2 3 2 1 2 2 5 5 2 $12.00 $36.00 $12.00 $36.00 $12.00 $24.00 $12.00 $36.00 $35.00 $70. 00 $35.00 $35.00 $12.00 $24.00 $12.00 $24.00 $40.00 5200.00 $20.00 $100.00 $12.00 $24.00 $609.00 Please Remit: Upon submission of samples, buyer agrees that invoices are due at time of delivery. Open accounts are due 20 days following the invoice date. A finance charge of 1.5 % per month will be imposed on all past -due accounts. When relinquishing samples to Blue Ridge Labs, buyer agrees to pay all collection and attorneys fees if the account becomes deliquent. Blue Ridge Labs reserves the right to deny all QC and support documentation for all open accounts which are greater than 60 days. Additionally, Blue Ridge Labs also reserves the right to inform the appropriate local, state or federal agency that all support documentation is not available due to the failure to the above invoice terms. Data used for compliance purposes will be rendered invalid for reporting until the account is cleared. 1 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag Cd Cu Total Phosphorus City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00689 031617-TP-LEFF Result MQL Unit Analysis Analysis Method Time Date Analyst Reported By: * 0.001 mg/1 200.7 1994 14:56 3/23/2017 KCJ 0.0003 0.0002 mg/I 200.7 1994 14:56 3/23/2017 KCJ 0.006 0.001 mg/1 200.7 1994 14:56 3/23/2017 KCJ 5.08 0.02 mg/1 200.7 1994 14:56 3/23/2017 KCJ oir S. J. Johnson, D.R. Wessinger: " Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gma il.com Client : City of Lenoir P. O. Box 958 Lenoir, NC 28645 Attention: Lisa Triplett Date Received: 17-Mar- I7 Report Date: 31-Mar-17 Sample Date: 16-Mar-17 BRL #: BRL-2017-0155 Lab Sample ID: LS1D-2017-00690 Client Sample ID: 031617-TKN-LEFF Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst N2+N3 5.56 0.08 mg/I SM19 4500-N 13:28 3/21 /2017 KCJ TKN 9.24 0.5 mg/I SM19 4500-N 15:48 3/22/2017 KCJ Reported By: r /y ' ;p1"111f— S.;, •hnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00691 031617-CN-GEFF Result MQL Unit Analysis Method Time Reported By: 0.007 0.005 Analysis Date Analyst mg/1 4500-CN-E 1 16:02 3/20/2017 S. J / r nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 12 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00692 031617-TKN-GEFF Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst 2.92 0.08 mg/I SM194500-N 13:30 3/21/2017 KCJ 8.12 0.5 mg/1 SM194500-N 16:19 3/22/2017 KCJ hnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag Cd Cr Cu Mo Ni Total Phosphorus Zn City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00693 031617-M-GEFF Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst 0.004 0.001 mg/I 200.7 1994 15:00 3/23/2017 KCJ * 0.0002 mg/I 200.7 1994 15:00 3/23/2017 KCJ 0.014 0.001 mg/1 200.7 1994 15:00 3/23/2017 KCJ 0.029 0.001 mg/1 200.7 1994 15:00 3/23/2017 KCJ * 0.001 mg/I 200.7 1994 15:00 3/23/2017 KCJ * 0.001 mg/1 200.7 1994 15:00 3/23/2017 KCJ 5.51 0.02 mg/1 200.7 1994 15:00 3/23/2017 KCJ 0.082 0.001 mg/1 200.7 1994 15:00 3/23/2017 KCJ etW,IIIrrnOr Mir S. J/ , nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00694 031617-TP-GD Result MQL Unit Method Total Phosphorus Reported By: 1.21 0.02 mg/1 200.7 1994 S. J. nson, D.R. Wessinger Analysis Analysis Time Date Analyst 15:11 3/23/2017 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 12 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Lenoir P. O. Box 958 Lenoir, NC 28645 Attention: Lisa Triplett Date Received: 17-Mar-17 Report Date: 31-Mar- l 7 Sample Date: 16-Mar-17 BRL #: BRL-2017-0155 Lab Sample ID: LSID-2017-00695 Client Sample ID: 031617-TKN-GD Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst N2+N3 1.58 0.08 mg/1 SM19 4500-N 13:32 3/21/2017 KCJ TKN 6.44 0.5 mg/I SM194500-N 17:02 3/22/2017 KCJ Reported By: S. J. '/•lill�Ilsm nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Total Phosphorus City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 16-Mar-17 BRL-2017-0155 LSID-2017-00696 031617-TP-GUP Reported By: Result MQL * 0.02 Unit Method Analysis Analysis Time Date Analyst nig/1 200.7 1994 15:15 3/23/2017 �f� --Or S. rhnson, D.R. Wessinger "Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 12 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : City of Lenoir P. O. Box 958 Lenoir, NC 28645 Attention: Lisa Triplett Date Received: 17-Mar-17 Report Date: 31-Mar-] 7 Sample Date: 16-Mar-17 BRL t#: BRL-2017-0155 Lab Sample ID: LSID-2017-00697 Client Sample ID: 031617-TKN-GUP Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst N2+N3 1.67 0.08 mg./1 SM194500-N 13:36 3/21/2017 KCJ TKN 7.6 0.5 mg/I SM 19 4500-N 17:42 3!22/2017 KCJ Reported By: S. J. iron, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 12 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2+N3 TKN City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 15-Mar-17 BRL-20I 7-0155 LSID-2017-00698 031517-TKN-GINF Result 0.95 38.1 Reported By: MQL Unit Method 0.08 mg/I SM19 4500-N 0.5 mgil SM 19 4500-N S. J i nson, D.R. Wessinger Analysis Analysis Time Date Analyst 13:36 3/21/2017 18:16 3/22/2017 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 12 KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 15-Mar-17 BRL-2017-0155 LSID-2017-00699 031517-CN-GINF Result MQL 0.010 0.005 Reported By: Unit Method mg/1 4500-CN-E 1 16:08 Analysis Analysis Time Date Analyst 3/20/2017 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 12 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Mar-17 31-Mar-17 15-Mar-17 BRL-2017-0155 LSID-2017-00700 Client Sample ID: 031517-M-GINF Parameter Ag Cd Cr Cu Mo Ni Total Phosphorus Zn Hg Reported By: Result MQL 0.014 0.001 0.0044 0.0002 0.013 0.001 0.120 0.001 * 0.001 * 0.001 8.88 0.02 0.180 0.001 0.0002 S. J. Unit Analysis Analysis Method Time Date Analyst mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg I 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 200.7 1994 15:17 3/23/2017 KCJ mg/1 245.1 1994 j//-' son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 12 of 12 /53 Non State Reporting Industrial or QC .J 124 cn 6L Analysis Requested ----....H ,,i ,,,...„ ---‹ ,-, i,.......‹ ----, ,..., .....„,,,,, -_._ -,... r \I --6:,,, ,- ci , --<_ \___. _....., _g , ,- fli• , , ,ja. � = ...„,. i 1 ,,,_ a EU V :O O Q ova Field chlorination Y N \ \\ \ \ V 04Uix. U›. 0 o� aC �E` ��cr. -z To 0 s tz. cn CJ ?- Q13 Q. O 17 /"--? M `: i \A,t `3WijV t Q MM r\ M qr, 0. j tt „ rs 5 n a 3 5 7 — e 4 'D a 1 • Y V L R � 3 • C y gL C E. L y D - 3 _▪ �Q gyre n U c: or � N V {9 o w as u ▪ v C rE{E{� U C • C 4 w q u ti 0 C R E ` E ml g. • g N } ^ (NI 7M g 9 q N40 `z L w • Q - • z = G C vv J L r G C c 31 c G E r E i • e L V 4 • a _ 9 a O S L = c c Y `a 5 3 T z • Q L O 0C-11 9 y 7 6- Ca 0 e C C Ua N • L N G y Gt u r �325 Non State Reporting Analysis Requested \� \r TITI L N C 1 I 1 F M a O Q � Ua. z o. r.1 v N v N ,. N v Field chlorination Y ' N \ \ \ \ 72 o .:„ .. z 6Ue:U>- \< \ \ \ 'a q1 aJ E \ \ \ \ a) d ta. ci U \ \ \ E u i i��' z v S .6 IV V v V o a 1'V F o � 4 q C v rvi 6 6. o Y - � T u N8 L tVC = C ▪ T .k. c. E? 2 R 3 t 2 ti • z ▪ 0 0 11 61;,1t E c rogc 8o :3 Q O py • u S • 3 � � n - c O w Cwy G U a r = L L A = �W e• Vi ol 7 q G t >s u ra 1 2 L u C EMB J C. C .A • zumcm o n � • T$ ✓ v c a . .r 7 • 3... L -3>. yu "• . �3 7 G G y• 1 V V J 0c. T Cy n y . -71 00 0 E Ezzt Rerall Gz u r �327 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P.O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03632 121316M-GEFF PPA Parameter Ag Cd Cr Cu Ni Sb Zn Hardness Fig Total Phosphorus Be TI Result MQL * 0.001 * 0.0002 * 0.001 0.028 0.001 * 0.001 * 0.01 0.139 0.001 26.9 0.03 * 0.0001 3.46 0.02 * 0.02 * 0.02 Reported By: Analysis Analysis Unit Method Time Date Analyst mg/1 200.7 1994 12:11 12/29/2016 KCJ mg/1 200.7 1994 12:11 12/29/2016 KCJ mg/1 200.7 1994 12:11 12/29/2016 KCJ mg/I 200.7 1994 12:11 12/29/2016 KCJ mg/1 200.7 1994 12:11 12/29/2016 KCJ mg/I 200.7 1994 12:11 12/29/2016 KCJ mg/1 200.7 1994 12:11 12/29/2016 KCJ mg/I 2340B 1997 12:11 12/29/2016 KCJ mg/1 245.1 1994 11:38 12/15/2016 KCJ mg/I 6010C 1994 12:11 12/29/2016 KCJ mg/I EPA 200.7 14:09 12/30/2016 summit mg/I EPA 200.7 14:09 12/30/2016 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03633 121316TDS-GEFF PPA Result MQL Unit Method TDS Reported By: Analysis Analysis Time Date Analyst 210 1 mg/1 2540C 1997 13:51 S. J. (n, D.R. Wessinger 12/17/2016 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 14 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03634 121316-625-GEFF PPA Internal QC data on attached vendor report. Parameter 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,2-Diphenyl-hydrazine 1,3-Dichlorobenzene l,4-Dichlorobenzene 2,4, 6-Tric h lorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3, 3'-D ich l oroben zid ine 3,4 benzofluoranthene 4,6-Dinitro-o-cresol 4-Bromophenyl-phenylether Reported By: Result MQL Unit Method * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/I EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.01 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.002 mg/1 EPA 625 * 0.00 mg/1 EPA 625 /01 S. J. 7/07 ' nson, D.R. Wessinger Analysis Analysis Time Date Analyst 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit 12:37 12/21/1916 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03634 121316-625-GEFF PPA Parameter Analysis Analysis Result MQL Unit Method Time Date Analyst 4-chlorophenyl phenyl ether 4-Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine Benzo[a]anthracene Benzo[a]pyrene Benzo[g,h,i]perylene Benzo[k]fluoranthene bis (2-Chloroethoxy) methane bis (2-Chloroethyl) ether his (2-Chloroisopropyl) ether bis (2-Ethylhexyl) phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Reported By: * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/I EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/I EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit * 0.002 mg/I EPA 625 12:37 12/21/1916 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03634 121316-625-GEFF PPA Parameter Dibenz[a,h]anthracene Diethylphthalate Dimethylphthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadine Hexachloroethane I ndenol 1,2,3-cd]pyrene lsophorone N-N itroso-d i-n-propylam ine N-Nitrosodimethylamine N-N itrosodiphenylam ine Naphthalene Nitrobenzene p-Chloro-m-cresol Pentachlorophenol Result Analysis Analysis MQL Unit Method Time Date Reported By: * 0.002 mg/l EPA 625 12:37 12/21/1916 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/I * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/1 * 0.002 mg/I * 0.002 mg/1 * 0.01 mg/1 r..f r' S. J. Jo D.R. Wessinger Analyst Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit EPA 625 12:37 12/21/1916 Summit * Concentrations are below Mini um Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03634 121316-625-GEFF PPA Analysis Analysis Parameter Result MQL Unit Method Time Date Analyst Phenanthrene * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit Phenol * 0.002 mg/1 EPA 625 12:37 12/21/1916 Summit Pyrene * 0.002 mg/I EPA 625 12:37 12/21/1916 Summit Reported By: S. J. !'. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03635 121316-0&G-GEFF PPA Result MQL Unit Analysis Analysis Method Time Date Fats, Oil & Grease Reported By: 3.5 1 r. S. J. fin, D.R. Wessinger mg/1 5520B 2001 15:30 12/20/2016 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 14 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03636 121316-Ph-GEFF PPA Parameter Phenols Reported By: Result MQL Unit Analysis Analysis Method Time Date " 0.01 mg/1 420.1 1978 16:20 12/15/2016 S. ,ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 14 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03637 Client Sample ID: 121316-CI-GEFF PPA Parameter Chloride Result MQL Unit Analysis Analysis Method Time Date Analyst 43.7 0.1 mg/l SM19 4500-C 7:47 Reported By: 12/22/2016 Summit S. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03638 121316-A-GEFF PPA Parameter Ammonia Nitrogen Reported By: Result MQL 1.12 0.5 Analysis Analysis Unit Method Time Date mg/1 SM4500 199 11:19 12/14/2016 S. J. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 14 Analyst KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03639 121316-TKN-GEFF PPA Nitrate + Nitrite Nitrogen (N2+ Total Kjeldahl Nitrogen (TKN) Reported By: Result MQL Unit Analysis Analysis Method Time Date 1.77 0.08 mg/1 4500-NO3-E 5.32 0.5 mg/I 4500-Norg B 15:56 12/28/2016 13:19 12/28/2016 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 14 Analyst KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL k: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03640 121316-CN-GEFF PPA Result Reported By: Analysis Analysis MQL Unit Method Time Date Analyst * 0.005 mg/I 4500-CN-E 1 16:58 12/15/2016 KCJ S. hnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 12 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 • 05-Jan-17 13-Dec-16 BRL-2016-0980 LSID-2016-03641 I21316-624-GEFF PPA Result MQL 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 1,2-Dichloropropane 1 ,3-Dichloropropylene 2-Chloroethylvinyl Ether Acrolein Acrylonitrile Benzene Bromoform Carbon Tertachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Reported By: Analysis Unit Method Time 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.01 0.05 0.05 0.005 0.005 0.005 0.005 0.005 0.005 0.005 ug/I EPA 624 2:51 ug/1 EPA 624 2:51 ug/I EPA 624 2:51 ug/I EPA 624 2:51 ug/I EPA 624 2:51 ug/I EPA 624 2:51 ug/I EPA 624 2:51 ug/1 EPA 624 2:51 ug/1 EPA 624 2:51 ug/1 EPA 624 2:51 ug/I EPA 624 2:51 ug/I EPA 624 2:51 ug/1 EPA 624 2:51 mg/I EPA 624 2:51 mg/1 EPA 624 2:51 mg/I EPA 624 2:51 mg/1 EPA 624 2:51 mg/1 EPA 624 2:51 S. J. `arson, D.R. Wessinger Analysis Date 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 12/17/2016 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 13 of 14 Analyst Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 13-Dec-16 05-Jan-17 13-Dec- 16 BRL-2016-0980 LSID-2016-0364] Client Sample ID: 121316-624-GEFF PPA Parameter D ichlorobromomethan e Ethybenzene Methyl Bromide Methyl Chloride Methylene Chloride Tetrachloroethene Toluene Trans-1,2-dichloroethene Trichloroethene Vinyl Chloride Reported By: S. J. Result MQL * 0.005 * 0.005 0.00628 0.005 * 0.005 * 0.005 * 0.005 * 0.005 * 0.005 * 0.005 * 0.005 Analysis Analysis Unit Method Time Date Analyst mg/I EPA 624 2:51 12/17/2016 Summit mg/I EPA 624 2:51 12/17/2016 Summit mg/1 EPA 624 2:51 12/17/2016 Summit mg/1 EPA624 2:51 12/17/2016 Summit mg/1 EPA 624 2:51 12/17/2016 Summit mg/I EPA 624 2:51 12/17/2016 Summit mg/I EPA 624 2:51 12/17/2016 Summit mg/I EPA 624 2:51 12/17/2016 Summit mg/1 EPA 624 2:51 12/17/2016 Summit mg/1 EPA 624 2:51 12/17/2016 Summit nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 14 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ammonia Nitrogen City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01009 041718A-GEFF Reported By: Result MQL * 0.5 Unit Method mg/I SM4500 199 nson, D.R Wessinger Analysis Time 15:40 Analysis Date Analyst 4/20/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 5 of 14 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Be TI City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01010 0417186E-GEFF Result MQL 0.02 0.02 Reported By: Analysis Analysis Unit Method Time Date mg/I EPA 200.7 18:27 4/24/2018 mg/1 EPA 200.7 18:27 4/242018 S. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 6 of 14 Analyst Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May- l 8 17-Apr-18 BRL-2018-0213 LSID-2018-01011 041718-GEFF624 1,1,1-Trichloroethane 1,1 2,2-Tetrachloroethane 1,1,2-Trichloroethane 1, I-Dichloroethane 1,1-Dichloroethene 1.2-Dichloroethane 1,2-Dichloropropane 1.3-Dichloropropylene 2-Chloroethylvinyl Ether Acrolein Acrylonitrile Benzene Bromoform Carbon Tertachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/1 EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 10 ug/I EPA 624 14:31 4/20/2018 Summit * 50 ug/I EPA 624 14:31 4/20/2018 Summit * 50 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/1 EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/1 EPA 624 14:31 4/20/2018 Summit * 5 ug/1 EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit 6.35 5 ug/1 EPA 624 14:31 4/20/2018 Summit son, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 7 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01011 041718-GEFF624 Dich lorobromomethane Ethybenzene Methyl Bromide Methyl Chloride Methylene Chloride Tetrachloroethene Toluene Trans-1,2-dichloroethene Trichloroethene Vinyl Chloride Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 5 ug/I EPA 624 14:31 4/20/2018 Summit 5 ug/I EPA 624 14:31 4/20/2018 Summit 5 net EPA 624 14:31 4/20/2018 Summit 5 ug/t EPA 624 14:31 4/20/2018 Summit 5 ug/I EPA 624 14:31 4/20/2018 Summit 5 ug/I EPA 624 14:31 4/20/2018 Summit * 5 ug/I EPA 624 14:31 4/20/2018 Summit 5 ug/l EPA 624 14:31 420/2018 Summit * 5 ug/l EPA 624 14:31 4/20/2018 Summit * 5 ug/1 EPA 624 14:31 4/20/2018 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 8 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01012 041718-GEFF625 Result 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,2-Diphenyl-hydrazine 1,3-Dichlorobenzene 1,4-Dichlorobenzene 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloronaphthalene 2-Chlorophenol 2-Nitrophenol 3,3'-D ich lorobenzidine 3,4 benzofluoranthene 4,6-Dinitro-o-cresol 4- B ro m o p h en y l -p h e n y l et h e r Reported By: Analysis Analysis MQL Unit Method Time Date Analyst * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0217 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4725/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0272 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/I EPA 625 17:10 4/25/2018 Summit * 0.0054 mg/1 EPA 625 17:10 4/25/2018 Summit * 0.0054... m_'1 A 625 17:10 4/25/2018 Summit S. J. J. son, D.R. Wessinger Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 9 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01012 041718-GEFF625 Result 4-chlorophenyl phenyl ether 4-Nitrophenol Acenaphthene Acenaphthylene Anthracene Benzidine Benzo[a]anthracene Benzo[a]pyrene Benzo[g,h,i]perylene Benzo[k]tluoranthene bis (2-Chloroethoxy) methane bis (2-Chloroethyl) ether bis (2-Chloroisopropyl) ether bis (2-Ethylhexyl) phthalate Butylbenzylphthalate Chrysene Di-n-butylphthalate Di-n-octylphthalate Reported By: * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 MQL Unit Method mg'I EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg'I EPA 625 mg'I EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/I EPA 625 mg/1 EPA 625 mg/I E' • 625 del eT,4r it S. J. Jt %son, D.R. Wessinger Analysis Time 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 17:10 Analysis Date Analyst 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25%2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 4/25/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 10 of 14 Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01012 Client Sample ID: 041718-GEFF625 Parameter Dibenz[a,h]anthracene Diethyl phthalate Dim ethy 1phthalate Fluoranthene Fluorene Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadine Hexachloroethane Indeno[1,2,3-cd]pyrene Isophorone N-N itroso-di-n-propy lam ine N-N itrosodimethy lamine N-N itrosodipheny lam ine Naphthalene Nitrobenzene p-Chloro-m-cresol Pentachlorophenol Reported By: Result MQL * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0054 * 0.0272 S. J. J 'iirson, D.R. Wessinger Unit Method mg/1 EPA 625 mg/1 EPA 625 mg/I EPA 625 mg/I EPA 625 mg/I EPA 625 mg/I EPA 625 mg/1 EPA 625 mg/I EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/l EPA 625 mg/I EPA 625 mg/l EPA 625 mg/1 EPA 625 mg/1 EPA 625 mg/I EPA 625 mg/l EPA 625 mg/I E A 625 Analysis Analysis Time Date 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 17:10 4/25/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 11 of 14 Analyst Summit Summit Summ it Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Summit Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-02 13 LSID-2018-01012 Client Sample ID: 041718-GEFF625 Parameter Phenanthrene Phenol Pyrene Result MQL * 0.0054 * 0.0054 * 0.0054 Reported By: Analysis Analysis Unit Method Time Date Analyst mg/1 EPA 625 17:10 4/25/2018 Summit mg/1 EPA 625 17:10 4/25/2018 Summit mg'l EPA 625 17:10 4/25/2018 Summit * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No.-275 Page 12 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Phenols City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr- 18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01013 041718-GEFF Result MQL * 0.01 Reported By: Unit Method Analysis Time Analysis Date Analyst mg/I Phenol 420.1 16:12 4i26/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 13 of 14 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Ag As Cd Cr Cu Ni Pb Sb Se Total Phosphorus Zn Hardness Hg City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01005 041718M-GEFF Reported By: Analysis Analysis Result MQL Unit Method Time Date Analyst * 0.001 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.01 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.0002 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.001 mg/I 200.7 1994 12:16 5/2/2018 KCJ 0.023 0.001 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.001 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.01 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.01 mg/1 200.7 1994 12:16 5/2/2018 KCJ * 0.01 mg/1 200.7 1994 12:16 5/2/2018 KCJ 1.12 0.02 mg/1 200.7 1994 12:16 5/2/2018 KCJ 0.058 0.001 mg/1 200.7 1994 12:165/2/2018 KCJ 17.4 0.03 mg/1 2340B 1997 12:16 5/2/2018 KCJ * 0.0001 mg/1 245.1 1994 15:12 4/25/2018 KCJ lgr S. J. nson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 1 of 14 Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01006 Client Sample ID: 041718TDS-GEFF Parameter TDS Result MQL 76 1 Reported By: Unit Method Analysis Time Analysis Date Analyst mg/1 2540C 1997 10:26 4/20/2018 S. J. Johnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 2 of 14 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter Cyanide City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01007 041718CN-GEFF Result MQL 0.005 0.005 Reported By: Unit Method Analysis Analysis Time Date Analyst mg/I 4500-CN-E 1 16:56 4/24/2018 S. J. ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 3 of 14 KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: Client Sample ID: Parameter N2—N3 TKN City of Lenoir P. O. Box 958 Lenoir. NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01008 041718N-GEFF Result MQL Unit Method 2.37 0.08 mg/1 SM19 4500-N 6.20 0.5 mg/I SM19 4500-N Reported By: Analysis Analysis Time Date Analyst 10:55 4/19/2018 11:52 4/18/2018 * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 4 of 14 KCJ KCJ Blue Ridge Labs PO Box 2940 Lenoir, NC 28645 828-728-0149 blueridgelabslenoir@gmail.com Client : Attention: Date Received: Report Date: Sample Date: BRL #: Lab Sample ID: City of Lenoir P. O. Box 958 Lenoir, NC 28645 Lisa Triplett 17-Apr-18 02-May-18 17-Apr-18 BRL-2018-0213 LSID-2018-01014 Client Sample ID: 041718-GEFF Parameter Fats, Oil & Grease Result MQL 1.2 Reported By: Unit Analysis Method Time Analysis Date Analyst mg/1 5520B 2001 10:22 4/26/2018 S. . ohnson, D.R. Wessinger * Concentrations are below Minimum Quantification Limit except where noted. NC Laboratory Certificate No. 275 Page 14 of 14 KCJ 1/12/2021 Mail - Perlmutter, Gary - Outlook [External] RE: Gunpowder draft permit Triplett, Lisa R. <Irtriplett@CI.LENOIR.NC.US> Tue 1/12/2021 1:12 PM To: Perlmutter, Gary <gary.perlmutter@ncdenr.gov> 1 attachments (10 MB) Gunpowder draft permit; CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Hi Gary, Thanks for the draft permit to look at. I noticed on the effluent pH it will be one time per week, is that correct. The current permit it is daily. Also the effluent total chlorine is 2 times per week, on the current permit It is daily as well. Just checking to make sure. Seem. 71.0eete, Veatew4tez 7re4tmerit React Suizenic ade to (8281 757- 2/998 LENOIR A PUBLIC UTILITIES.' https://outlook.office365.com/mail/inbox/id/AAQkADRjNGZkNGYwLWNjOTctNGQ4MS1 hZDQ3LWJjMGMOYmRiN2M3NwAQAPuR1ZvRdZ9MgnZFa7L... 1/1 1/13/2021 Mail - Perlmutter, Gary - Outlook RE: Gunpowder WWTP draft permit Thomas, Zachary T <zachary.thomas@ncdenr.gov> Wed 1/13/2021 11:43 AM To: Perlmutter, Gary <gary.perlmutter@ncdenr.gov> Cc: Moore, Cindy <cindy.a.moore@ncdenr.gov> Everything looks good for Tox! Thank you, Zach Thomas Environmental Specialist II Aquatic Toxicology Branch NCDEQ— Division of Water Resources 919-743-8439 Submit ATForms electronically to: ATForms.ATB@ncdenr.gov DEQ Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Perlmutter, Gary Sent: Tuesday, January 12, 2021 11:32 AM To: Heim, Tim <Tim.Heim@ncdenr.gov>; Kinney, Maureen <Maureen.Kinney@ncdenr.gov>; Thomas, Zachary T <zachary.thomas@ncdenr.gov>; Moore, Cindy <cindy.a.moore@ncdenr.gov>; Barnett, Kimberly <kimberly.barnett@ncdenr.gov> Subject: Gunpowder WWTP draft permit Dear everyone, Attached is the draft permit for Gunpowder Creek WWTP (NC0023736), scheduled to be Public Noticed this week. Please let me know if you have any questions. Thanks, Gary Perlmutter Gary Perlmutter, Environmental Specialist II NCDEQ/Division of Water Resources NPDES Municipal Permitting Unit 919-707-3611 Office 919-306-1017 Cell gary.perlmutter@ncdenr.gov Physical Address: 512 N Salisbury St., Raleigh, NC 27604 Mailing Address: 1617 Mail Service Center, Raleigh, NC 27699-1617 https://outlook.office365.com/mail/inbox/id/AAQkADRjNGZkNGYwLWNjOTctNGQ4MS1 hZDQ3LWJjMGMOYmRiN2M3NwAQAH6cOu31oIIKlsomfkjUtiA... 1/2 1/13/2021 Mail - Perlmutter, Gary - Outlook Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. https://outlook.office365.com/mail/inbox/id/AAQkADRjNGZkNGYwLWNjOTctNGQ4MS1 hZDQ3LWJjMGMOYmRiN2M3NwAQAH6cOu31oIIKlsomfkjUtiA... 2/2 ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Director MEMORANDUM To: From: Subject: NORTH CAROLINA Environmental Quality January 21, 2021 Kimberly Barnett NC DEQ / DWR / PWS Regional Engineer Asheville Regional Office Gary Perlmutter 919-707-3611 NPDES Unit Review of Draft NPDES Permit NC0023736 Gunpowder Creek WWTP Caldwell County Please indicate below your agency's position or viewpoint on the draft permit and return this form by April 18, 2019. If you have any questions on the draft permit, please feel free to contact me at the telephone number shown above. RESPONSE: (Check one) X Concur with the issuance of this permit provided the facility is operated and maintained properly, the stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. Concurs with issuance of the above permit, provided the following conditions are met: Opposes the issuance of the above permit, based on reasons stated below, or attached: Signed iv(,001,e- F(Guva-t tV Date: 01/21/21 NORTH CAROLINA Opartnem W Environmental Quellry North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617Mail Service Center I Raleigh, North Carolina 27699-1617 919.707.3601