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HomeMy WebLinkAboutWQ0040918_Monitoring - 11-2020_202012297 • - W-59A COMPLIANCE REPORT FORM ermit ;-!1" V V q I a (Subaru one each aw n taring periad with GW--59 forms.) j Enter date monitoring results were due. Will this monitoring report (GW-59 and GW-59A) YES O be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is 'NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) standards in the spade provided below: exceeding �.i (`nui_y �-3 `� N St nj 5 For the constituents identified in question 4 above, have standards been excdeA&d previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is 'NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding � W ards, car ntiation(s) re rted, and sample collection date for each occurre ce (for the last two years). MvJ—a mw-a, , �1-1�-ao�.°I�t•s <<-1�-ao ���s Are the monitoring wells list din section 5 located at or beyond the review boundary? YE NO If the answer is "YES", a groundwater quality problem may be occqqr� n�gs-CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", mo►#ItblHho wells maybe improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is 'YES", describe those actions in the space provided below. If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Vio/a6"Qn fine1s, and/orpenalties. j Q 1, WWS C� l S 6&u) S-� Ul l MW —3 C --gy p _ -c�� (Ooa OCc j C\ 0 Tcev) 4. aA g The person completing tWs portion (GW-59A) of the monitoring report shOild sign below anOAmifthis form with G W-59 forms for required wells to the address provided at the top of the current G "$ form. l hereby acknowkKige that the above rformation was evaluated and the informabon submitted itiVft report (Compliance Report GW ) is complete to the best of my knowledge. an Signature of Pe ittee (or Authorized Agent) Date "-I, GW-59A 12/8/2003 —�X\w — 3 eD �4 --wN) — �) ��ico-( UAorrfA -- R-- ao �, Ste— o -73-1 0 0 SAS L ` - ` � 1-" oZ Vy 7 Ii--_. `-- — r)-`I -ao 33,3v� _--6 - Ck.- a o _ - SUBMIT FORM PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORMA Facility Name: Permit Name (If Facility Address: act Person: Location/Site hq or Telephone#: __a93- No. of wells to be sampled: PERMIT NumberQ01JAZi Ixiration Date: 0 Non -Discharge UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED k-Ingoon ❑ Remediatlon: Infiltration Gallery 'Spray Field ❑ Remedlation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from ermit):VV *~\ Date sample collected�1� `' 1" FIELD ANALYSES: Well Depth: o ® ft. Well Diameter: In. pH 00400:'t, units Temp. 00010 S°C Depth to Water Level 82546:ft. below measuring point Screened Interval: ft. to ft. Spec, Cond. 00004: µMhos Measuring Point Is _ft. above land surfac Relative M.P. Elevation: ft. Odor 000m: t 9,� Volume of water pumped/bailed before sampling: gallons Appearance Samples for metals were collected unfiltered: I] YES ❑ NO and field acidified: 0 YES ❑ NO LABORATORY INFORMATInKI --+ �. Date sample analyzed:\ —�� �� �`�- `�— PARAMETERS NOTE: Valu es sho Id reflect c COD 00335 mg/L Coliform: MF Fecal 31616 s /100mL Coliform: MF Total 31504 /100mL (Note: Use MPN method for highly turbid samples) solved Sollds:Total 70300 mg/L pH (Lab) 00403 units TOC ooseo_�Q, mg/L Chloride 00940 mg/L Arsenic 01002 ug/L Grease and Oils 00552 mg/L Phenol 32730 ug/L Sulfate 00945 mg/L :cific Conductance 00095 µMhos Total Ammonia oosao mg/L (Ammonia Nitrogen; NH. as N; Ammonia Nitrogen, Total) TKN as N 00625 mg/L For Remedlation Systems Only (Attach Lab Reports): ,,_ao— aboratory Name: � �V1 �'O .cy� Certification No,�� and collafdal concentrations. Nitrite (NO2) as N 00615 mg/L Pb - Lead oio5i ug/L Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Phosphorus: Total as P oo665 y', / () mg/L Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): AI -Aluminum olio5 mg/L Ba - Barlum 01007 ug/L Ca - Calcium 00916 mg/L Cd - Cadmium 01027 ug/L Chromium: Total 01034 uglL Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Hg - Mercury 71900 ug/L Lab Report Attached? P"' Yes (1) ❑ No (0) K - Potassium 00937 mg/L VOC 7873 method # S l 6''Rme Mg - Magnesium 00927 mg/L method # Mn - Manganese oio55 ug/L method # NI - Nlckei 01067 ug/L method # Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% WELL DRY at time of here:0 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER (QUALITY MONITORING: COMPLIANCE REPORT FORM earyor iype PERMIT Number �� p (ration Date: Facility Name: Aq�(b� f1 �{���e�-- Non -Discharge UIC Permit Name (if different)rrr:� NPDES Other Fac Iity Address: TYPE OF PERMITTED OPERATION BEING MONITORED S'3 County \' goon ❑ Remediatlon: Infiltration Gallery tr;tzdel (zIp) � � e(�p� Telephone � Ly'°Spray Field ❑Remedlation: Contact Person: 6 33 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name:m e No. of wells to be sampled: ❑ Water Source Heat Pump ❑ Other: ...,,... �..�....� .,'.'„-. ' ,,.aa WELL ID NUMBER (from Permit): Date sample collected:,' �— o ® •FIELD ANALYSES: If WELL Well Depth: �ft. Well Diameter:f,), in. pH 0040041 units Temp. 000io:l6/ 9 °C WAS DRY at Depth to Water Level 82546: ,,11_4 ft. below measuring point Screened Interval: ft. to ft. Spec, Cond. 00094: µMhos time of Measuring Point Is _ft. above land surface Relative M.P. Elevation: ft. Odor 00085: 0 sampling, Volume of water pumped/balled before sampling: Appearance check _gallons Samples for metals were collected unfiltered: ® YES ❑ NO and field acidified: 0 YES ❑ NO here: LABORATORY INFORMATION k \ — — _ r%, Date sample an PARAMETERS COD 00335 _mg/L Coliform: MF Fecal 31616� , /100ml- Collform: MF Total 31504 /100ml- (Note: Use MPN method for highly turbid samples) Issolved Sollds:Total 70300_ ® mg/L pH (Lab) 00403 units TOC oosao ` 3 mg/L Chloride oosao mg/L Arsenic 01002 ug/L Grease and Oils 00552 mg/L Phenol 32730 ug/L Sulfate 00945 mg/L Specific Conductance 000s5_ µMhos Total Ammonia ooeto (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) TKN as N 00625 mg/L For Remedlation Systems Only (Attach Lab Reports): ':10—Qp .aboratory Name: V1 t 6� Certification No. and colloidal concentrations. �! _ Nitrite (NO2) as N oo615 mg/L Pb - Lead olo51 ug/L Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Phosphorus: Total as P 00655 mg/L Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Al - Aluminum oil oe mg/L Ba - Barium 01007 ug/L Ca - Calcium oogis mg/L Cd - Cadmium 01027 ug/L Chromium: Total 01034 ug/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Fe- Iron 01045 ug/L method (Specify test and method #. TTACH LAB REPORT.) Hg - Mercury 71900 ug/L Lab Report Attached? (1) ❑ No (0) K - Potassium 00937 mg/L VOC 7873 method #cSrj�1 caca_ Mg - Magnesium 00927 mg/L method # Mn - Manganese olo55 ug/L method # NI - Nickel 01067 ug/L method # Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facility Name: Permit Name (If d Facility Address. Contact Person: �CC Well Location/Site Name: SUBMIT FORM ON YELLOW PAPER ONLY 3arly or Type 11 VC S ck-d- S County -aq3 -3�3l� of wells to be sampled: ^!.1211 S r jQ'+' , .VRrIN {Ii l�lcl�IICbHf N,t�7 eAA+�9h f PERMIT Number(g0gftpiration Date: Non -Discharge UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED I -Lagoon ❑ Remediation: Infiltration Gallery Dray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: onrvir�nvta nvrvretutr t rvty _,(1� '' ``\\ WELL ID NUMBER (from Permit): \' �w '—� Date sample collected: `� " — O FIELD ANALYSES: If WELL WAS r Well Depth: 1 s ft. Well Diameter: In. pH oogooS,S units Temp. 000io: °C DRY at Depth to Water Level 8254e:!26 1�� ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: µMhos time of Measuring Point Is ft. above land surface Relative M.P. Elevation: ft. ^ Odor 000e5: O fAQ. sampling, check Volume of water pumped/balled before sampling: _gallons Appearance W here: Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: N YES ❑ NO LABORATORY INFORMATION - Date sample analyzed: - `� $� - 0 -aQLaboratory Name: EAU\ coe.�ne.� Certification No. PARAMETERS NOTE: Values sh uid reflect d1sigolved and colloidal concentrations. COD oo335 _ mg/L Nitrite (NO2) as N oo615 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 '� /100ml- Nitrate (NO3) as N 00620 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Issolved Sollds:Total 70300_ mg/L Al -Aluminum o1105 mg/L pH (Lab) 00403 _ units Be - Barlum 01007 ug/L TOC ooelo _ mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug1L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #"LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? fN Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia ooelo mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese o1o55 ug/L , method # TKN as N 00625 mg/L NI - Nickel 010e7 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facllity Name: Permit Name (if d Facility Address: act Person: Locatlon/Site Name: (V S _ T, — or County ilephone#: l 0- 3w 3 No. of wells to be sampled:_ PERMIT Number0j-�004f6q/expiration Date: Non -Discharge UIC NPDES Other _ TYPE OF PERMITTED OPERATION BEING MONITORED - agoon ❑ Remediatlon: Infiltration Gallery Spray Field ❑ Remedlation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: �cv naryneiM i w�V NU WELL ID MBER (from jI11 Date sample collected: llO� FIELD ANALYSES: If WELL `Permit): Well Depth: 1 ft. Well Diameter: 21" In. pH 0040015i►l units Temp. 000io: eC WAS DRY at Depth to Water Level 82545: �. Q; ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: µMhos time of Measuring Point Is _ft. above land surface Relative M.P. Elevation: ft. Odor 00085: sampling, Volume of water pumped/bailed before sampling: 1 6—gallons Appearance check Sam les for metals were collected unfiltered: 0 YES ❑ NO and field acidified: ® YES ❑ NO I la!' 1t2ATnDV IRICr10e11AT1nn1 ♦ _ O'6 here: Date sample analyzed: fj fj-t PARAMETERS NOTE: Values sifould reflect COD 00335 mg/L Collform: MF Fecal 31616 ,�/100mL Coliform: MF Total 31504 /100mL (Note: Use MPN method for high turbid samples) solved Sollds:Total 70300 mg/L pH (Lab) 00403_ _units TOG oosao mg/L Chloride oosao �L 5Q� mg/L Arsenic 01002 ug/L Grease and Oils 00552 mg/L Phenol 32730 ug/L Sulfate 00945 mg/L ;cific Conductance 00065 _ µMhos Total Ammonia oosio _ mg/L (Ammonia Nitrogen; NH3 as N; Ammonia N�, Tota ) TKN as N 00625 mg/L For Remedlation Systems Only (Attach Lab Reports): q- Laboratory Name: ) ry ��\ Certification No._ d and colloidal concentrations. Nitrite (NO2) as N oo615 mg/L Pb - Lead olo5i ug/L Nitrate (NO3) as N 00620 ! mg/L Zn - Zinc 01092 mg/L Phosphorus: Total as P 00555 Q,_mg/L Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Al -Aluminum oilo5 mg/L Be - Barlum 01007 ug/L Ca - Calcium oosio mg/L Cd - Cadmium 01027 ug/L Chromium: Total 01034 ug/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Fe - Iron 01045 ug/L (Specify test and method #.,ATTACH LAB REPORT.) Hg - Mercury 71900 ug/L Lab Report Attached? V Yes (1) ❑ No (0) K - Potassium 00937 mg/L VOC 7873 method #aAO a Mg - Magnesium 00927 mg/L method # Mn - Manganese olo55 ug/L method # NI - Nickel 01067 ug/L method # Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% ip-invironmental Chemists, Inc. Go ^� °I 4 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab = 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 - 252.473.5702 Lab/Fax SHighway, Jacksonville, NC 28540 910.347.5$43 Lab/Fax J 255-A Wilmington ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein Lab ID Sample ID: Collect Date/Time Matrix Sampled by 20-49840 Site: MW-1 11/17/2020 12:00 PM Water jcb/envirochem Test Method Results Date Analyzed Color color Tan/Turbid 11/17/2020 Depth to water, ft. Depth to Water, Ft. 5.7 feet 11/17/2020 Ammonia Nitrogen EPA 350.1 < 0.2 mg/L 11/20/2020 Gallons bailed before sampling Gallons Bailed before sampling 10 gallons 11/17/2020 Odor Qualitative None 11/17/2020 Total Dissolved Solids (TDS) SM 2540 c 72 mg/L 11 /18/2020 Temperature SM 2550 B 21.5 C 11/17/2020 Chloride SM 4500 Cl E < 5 mg/L 11/24/2020 pH SM 4500 H B 4.9 units 11 /17/2020 Total Phosphorus SM 4500 P F 4.70 mg/L 11/24/2020 Total Organic Carbon (TOC) SM 5310 B 2.7 mg/L 11/17/2020 1, 1, 1,2-Tetrachloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1,1-Trichloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1,2,2-Tetrachloroethane SM 62008 <0.5 pg/L 11/24/2020 1,1,2-Trichloroethane SM 6200B <0.5pg/L 11/24/2020 1,1-Dichloroethane SM 6200B <0.5 pg/L 11124/2020 1,1-Dichloroethene SM 6200B <0.5lig/L 11/24/2020 1,1-Dichioropropene SM 6200B <0.5 pg/L 11/24/2020 1,2,3-Trichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,2,3-Trichloropropane SM 6200B <0.5 pg/L 11/24/2020 1,2,4-Trichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,2,4-Trimethylbenzene SM 6200B <0.5pg/L 11/24/2020 1,2-Dibromo-3-Chloropropane SM 6200B <0.5 pg/L 11/24/2020 1,2-Dibromoethane SM 6200B <0.5pg/L 11/24/2020 1,2-Dichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,2-Dichloroethane SM 6200B <0.5pg/L 11/24/2020 Report #:: 2020-19581 Page 1 of 12 Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 = 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report M 2020-19581 Project ID: AG Protein 1,2-Dichloropropane SM 6200B <0.5 pg/L 11/24/2020 1,3,5-Trimethylbenzene SM 6200B <0.5pg/L 11/24/2020 1,3-Dichlorobenzene SM 6200B <0.5pg/L 11/24/2020 1,3-Dichloropropane SM 6200B <0.5pg/L 11/24/2020 1,4-Dichlorobenzene SM 6200B <0.5pg/L 11/24/2020 2,2-Dichloropropane SM 62008 <0.5 pg/L 11/24/2020 2-Chlorotoluene SM 6200B <0.5 pg/L 11/24/2020 4-Chlorotoluene SM 6200E <0.5 pg/L 11/24/2020 Benzene SM 6200B <0.5 pg/L 11/24/2020 Bromobenzene SM 52008 <0.5 pg/L 11/24/2020 Bromochloromethane SM 6200B <0.5 pg/L 11/24/2020 Bromodichloromethane SM 6200B <0.5 pg/L 11/24/2020 Bromoform SM 62006 <0.5 pg/L 11/24/2020 Bromomethane SM 6200B <0.5 pg/L 11/24/2020 Carbon tetrachloride SM 6200B <0.5 pg/L 11/24/2020 Chlorobenzene SM 6200B <0.5 pg/L 11/24/2020 Chloroethane SM 6200B <0.5 pg/L 11/24/2020 Chloroform SM 6200B <0.5 pg/L 11/24/2020 Chloromethane SM 6200B <0.5 pg/L 11/24/2020 cis-1,2-Dichloroethene SM 6200B <0.5pg/L 11/24/2020 cis- 1, 3-Dichloropropene SM 62006 <0.5pg/L 11/24/2020 Dibromochloromethane SM 6200B <0.5 pg/L 11/24/2020 Dibromomethane SM 62006 <0.5 pg/L 11/24/2020 Dichlorodifluoromethane SM 6200B <0.5 pg/L 11/24/2020 Ethylbenzene SM 62008 <0.5 pg/L 11/24/2020 Hexachlorobutadiene SM 6200B <0.5 pg/L 11/24/2020 Isopropylbenzene SM 6200B <0.5pg/L 11/2412020 M+P Xylene SM 62006 <1.0 pg/L 11/24/2020 Methylene chloride SM 6200B <0.5 pg/L 11/24/2020 Naphthalene SM 6200B <0.5 pg/L 11/24/2020 Report #1 : 2020-19581 Page 2 of 12 Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 , 910.392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 , 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Post Office Box 856 Warsaw NC 28398 Attention: Amy Elmore n-Butylbenzene SM 62008 n-Propylbenzene SM 6200B ortho-Xylene SM 6200B p-Isopropyltoluene SM 62008 sec -Butyl benzene SM 6200B Styrene SM 5200B tert-Butyl benzene SM 6200B Tetrachloroethene SM 6200B Toluene SM 6200B Trans-1,2-Dichloroethene SM 6200B Trans- 1,3-dichloropropene SM62DOB Trichloroethene SM 6200B Trichlorofluoromethane SM 6200B Vinyl chloride SM 5200B Fecal Coliform SM 9222D MF Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2 Nitrate+Nitrite-Nitrogen EPA 353.2 Nitrate Nitrogen Subtraction Method Date of Report: Dec 02, 2020 Customer PO #: Customer ID: 08110011 Report #: 2020-19581 Project ID: AG Protein <0.5 pg/L 11/24/2020 <0.5pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5pg/L 11/24/2020 <0.5pg/L 11/2412020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/24/2020 <0.5 pg/L 11/2412020 <0. 5 pg/L 11/24/2020 <1 Colonies/100ml- 11/17/2020 < 0.02 mg/L 2.61 mg/L 2.61 mg/L 11 /18/2020 11/24/2020 11/25/2020 Report #:: 2020-19581 Page 3 of 12 ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 4 910.392.0223 Lab , 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 ., 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax infoCa environmentalchemists.com Smithfield Flog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein Lab ID Sample ID: Collect Date/Time Matrix Sampled by 20-49841 Site: MW-2 11/17/2020 12:15 PM Water jcb/envirochem Test Method Results Date Analyzed Color Color White/Tan 11/17/2020 Depth to water, ft. Depth to water, Ft. 11.4 feet 11 /17/2020 Ammonia Nitrogen EPA 350.1 < 0.2 mg/L 11/20/2020 Gallons bailed before sampling Gallons Bailed before sampling 10 gallons 11/17/2020 Odor Qualitative None 11/17/2020 Total Dissolved Solids (TDS) SM 2540 C 140 mg/L 11/18/2020 Temperature SM 2550 B 16.7 C 11/17/2020 Chloride SM 4500 Cl E 6 mg/L 11/24/2020 ,pH SM 4500 H B 4.8 units 11/17/2020 Total Phosphorus SM 4500 P F 0.73 mg/L 11/24/2020 Total Organic Carbon (TOC) SM 5310 B 1.3 mg/L 11/17/2020 1,1,1,2-Tetrach loroethane SM 6200B <0.5 pg/L 11/24/2020 1, 1, 1 -Trichloroetha ne SM 6200B <0.5 pg/L 11/24/2020 1,1,2,2-Tetrachloroethane SM 6200B <0.5pg/L 11/24/2020 1,1,2-Trichloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1-Dichloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1-Dichloroethene SM 6200B <0.5pg/L 11/24/2020 1,1-Dichloropropene SM62008 <0.5pg/L 11/24/2020 1,2, 3-Trichlorobenzene SM 6200B <0. 5 pg/L 11/24/2020 1, 2, 3-Trich loropropane SM 6200B <0.5 pg/L 11/24/2020 1,2,4-Trichlorobenzene SM 6200B <0.5pg/L 11/24/2020 1,2,4-Trimethylbenzene sM62008 <0.5pg/L 11/24/2020 1,2-Dibromo-3-Chloropropane SM 6200B <0.5pg/L 11/24/2020 1,2-Dibromoethane SM 6200B <0.5pg/L 11/24/2020 1,2-Dichlorobenzene SM62o08 <0.5pg/L 11/24/2020 1,2-Dichloroethane SM 6200B <0.5pg/L 11/24/2020 Report # � 2020-19581 Page 4 of 12 c�ct 0 co G IaIIn ANALYTICAL & CONSULTING CHEMISTS finvir®nmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 . 910.392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 1 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax info@environmentalchemists_com Smithfield Hog Productions -Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein 1,2-Dichloropropane SM 6200B <0.5pg/L 11/2412020 1,3,5-Trimethylbenzene SM 6200B <0.5pg/L 11/24/2020 1,3-Dichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,3-Dichloropropane SM 6200B <0.5pg/L 11/24/2020 1,4-Dichlorobenzene SM 6200B <0.5pg/L 11/24/2020 2,2-Dichloropropane SM 5200B <0.5 pg/L 11/24/2020 2-Chlorotoluene SM 6200B <0.5 pg/L 11/24/2020 4-Chlorotoluene SM 6200B <0.5 pg/L 11/24/2020 Benzene SM 6200B <0.5 pg/L 11/24/2020 Bromobenzene SM 6200B <0.5 pg/L 11/24/2020 Bromochioromethane SM 6200B <0.5 pg/L 11/24/2020 Bromodichloromethane SM 62008 <0.5 pg/L 11/24/2020 Bromoform SM 5200B <0.5 pg/L 11/24/2020 Bromomethane SM 62008 <0.5 pg/L 11/24/2020 Carbon tetrachloride SM 6200B <0.5 pg/L 11124/2020 Chlorobenzene SM 6200B <0.5pg/L 11/24/2020 Chloroethane SM 6200B <0.5 pg/L 11/24/2020 Chloroform SM 6200B <0.5 pg/L 11/24/2020 Chloromethane SM 62006 <0.5 pg/L 11/24/2020 cis- 1,2-Dichloroethene SM 62008 <0.5pg/L 11/24/2020 cis- 1,3-Dichloropropene SM 6200B <0.5 pg/L 11/24/2020 Dibromochloromethane SM 62008 <0.5 pg/L 11/24/2020 Dibromomethane SM 6200B <0.5 pg/L 11/24/2020 Dichlorodifiuoromethane SM 6200B <0.5pg/L 11/24/2020 Ethylbenzene SM 5200B <0.5 pg/L 11/24/2020 Hexachlorobutadiene SM 6200B <0.5pg/L 11/24/2020 Isopropylbenzene SM 6200B <0.5 pg/L 11/24/2020 M+P Xylene SM 62008 <1.O pg/L 11/24/2020 Methylene chloride SM 6200B <0.5 pg/L 11/24/2020 Naphthalene SM 6200B <0.5 pg/L 11/24/2020 Report #:: 2020-19581 Page 5 of 12 ANALYTICAL & CONSULTING CHEMISTS -Environmental a issg Inc. 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein n-Butylbenzene SM 6200s <0.5 pg/L 11/24/2020 n-Propylbenzene SM 6200B <0.5 pg/L 11/24/2020 ortho-Xylene SM 6200B <0.5 pg/L 11/2412020 p-Isopropyltoluene SM 6200B <0.5pg/L 11/24/2020 sec -Butyl benzene SM 6200B <0.5 pg/L 11/2412020 Styrene SM 6200B <0.5 pg/L 11/24/2020 tert-Butyl benzene SM 620as <0.5 pg/L 11/24/2020 Tetrachloroethene SM 6200B <0.5 pg/L 11/2412020 Toluene SM 6200B <0.5 pg/L 11/24/2020 Trans-1 ,2-Dichloroethene SM 6200s <0.5 pg/L 11/24/2020 Trans-1,3-dichloropropene SM62008 <0.5pg/L 11/24/2020 Tiichooroethene SM 6200B <0.5 pg/L 11/24/2020 Trichlorofluoromethane SM 6200s <0.5 pg/L 11/24/2020 Vinyl chloride SM 6200s <0.5 pg/L 11/24/2020 Fecal Coliform SM 9222D MF <1 Colonies/100ml- 11/17/2020 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2 < 0.02 mg/L 11/18/2020 Nitrate+Nitrite-Nitrogen EPA 353.2 16.4 mg/L 11/24/2020 Nitrate Nitrogen Subtraction Method 16.4 mg/L 11/25/2020 Report #:: 2020-19581 Page 6 of 12 Environmental Chemists, Inc. 1 1 3 9 e 6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab = 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax sM, 255-A Wilmington Highway, Jacksonville, NC 28540 _ 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein Lab ID Sample ID: Collect Date/Time Matrix Sampled by 20-49842 Site: MW-3 11/17/2020 12:30 PM Water jcb/envirochem Test Method Results Date Analyzed Color Color Tan/Brown 11/17/2020 Depth to water, ft. Depth to water, Ft. 6.6 feet 11/17/2020 Ammonia Nitrogen EPA 350.1 1.6 mg/L 11 /20/2020 Gallons bailed before sampling Gallons Bailed before sampling 10 gallons 11/17/2020 Odor Qualitative None 11/17/2020 Total Dissolved Solids (TDS) SM 2540 c 134 mg/L 11/18/2020 Temperature SM 2550 B 21.2 C 11/17/2020 Chloride SM 4500 Cl E 6 mg/L 11/24/2020 pH SM 4500 H B 5.5 units 11/17/2020 Total Phosphorus SM 4500 P F 3.13 mg/L 11/24/2020 Total Organic Carbon (TOC) SM 5310 B 34.0 mg/L 11/17/2020 1, 1, 1,2-Tetrachloroethane SM 6200B <0.5 pg/L 11/24/2020 1, 1, 1 -Trichloroethane SM 6200B <0.5pg/L 11/24/2020 1,1,2,2-Tetrachloroethane SM 6200B <0.5pg/L 11/24/2020 1,1,2-Trichloroethane SM 6200B <0.5pg/L 11/24/2020 1,1-Dichloroethane SM 6200B <0.5pg/L 11/24/2020 1,1-Dichloroethene SM 6200B <0.5pg/L 11/24/2020 1,1-Dichloropropene SM 6200B <0.5pg/L 11/24/2020 1,2,3-Trichlorobenzene SM 6200B <0.5pg/L 11/24/2020 1,2,3-Trichloropropane SM 6200B <0.5pg/L 11/24/2020 1,2,4-Trichlorobenzene SM 6200B <0.5 µg/L 11/24/2020 1,2,4-Trimethylbenzene SM 6200B <0.5pg/L 11/24/2020 1,2-Dibromo-3-Chloropropane SM 6200B <0.5 pg/L 11/24/2020 1,2-Dibromoethane SM 6200B <0.5pg/L 11/24/2020 1,2-Dichlorobenzene SM 6200B <0.5pg/L 11/24/2020 1,2-Dichloroethane SM62008 <0.5pg/L 11/24/2020 Report #:: 2D20-19581 Page 7 of 12 Environmental Chemists, Inc® (R 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab 910.392.4424 Fax G�� �) J 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax SM, 255-A Wilmington Highway, Jacksonville, NC 28540 , 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions -Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein 1,2-Dichloropropane sM 5200B <0.5 pg/L 11 /24/2020 1,3,5-Trimethylbenzene sM 62008 <0.5 pg/L 11/24/2020 1,3-Dichlorobenzene sM6200B <0.5pg/L 11/24/2020 1,3-Dichloropropane sM6200B <0.5pg/L 11/24/2020 1,4-Dichlorobenzene sM 62008 <0.5 pg/L 11/24/2020 2,2-Dichloropropane sM6200B <0.5pg/L 11/24/2020 2-Chlorotoluene sM 6200a <0.5 pg/L 11/24/2020 4-Chlorotoluene sM 6200B <0.5 pg/L 11/24/2020 Benzene sM 6200a <0.5 pg/L 11/24/2020 Bromobenzene sM 6200B <0.5 pg/L 11/24/2020 Bromochloromethane sM 6200a <0,5 pg/L 11/24/2020 Bromodichloromethane sM 6200B <0.5 pg/L 11/24/2020 Bromoform sM 6200a <0.5 pg/L 11/24/2020 Bromomethane sM 62008 <0.5 pg/L 11/24/2020 Carbon tetrachloride sM 6200a <0.5 pg/L 11/24/2020 Chlorobenzene sM 6200B <0.5 pg/L 11/24/2020 Chioroethane sM 6200a <0.5 pg/L 11/24/2020 Chloroform sM 6200B <0.5 pg/L 11/24/2020 Chloromethane sM 6200a <0.5 pg/L 11/24/2020 cis- 1,2-Dichloroethene sM6200B <0.5pg/L 11/24/2020 cis-1,3-Dichloropropene sM62009 <0.5pg/L 11/24/2020 Dibromochloromethane sM 6200B <0.5 pg/L 11/24/2020 Dibromomethane sM 6200a <0.5 pg/L 11/24/2020 Dichlorodifluoromethane sM 6200a <0.5 pg/L 11/24/2020 Ethylbenzene sM 6200B <0.5 pg/L 11/24/2020 Hexachlorobutadiene sM 62008 <0.5 pg/L 11/24/2020 Isopropylbenzene SM 6200a <0.5 pg/L 11/24/2020 M+P Xylene sM 6200a <1.0 pg/L 11/24/2020 Methylene chloride sM6200B <0.5pg/L 11/24/2020 Naphthalene sM6200B <0.5pg/L 11/24/2020 Report #:: 2020-19581 Page 8 of 12 �M I ANALYTICAL & CONSULTING CHEMISTS 1-13 milivironmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax info@environmentalcliemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein n-Butylbenzene SM 62008 <0.5 pg/L 11/24/2020 n-Propylbenzene SM 6200B <0.5 pg/L 11/24/2020 ortho-Xylene SM 6200B <0.5 pg/L 11/24/2020 p-Isopropyltoluene SM 62008 <0.5pg/L 11/24/2020 sec -Butyl benzene SM 62008 <0.5 pg/L 11/24/2020 Styrene SM 6200B <0.5 pg/L 11/24/2020 tert-Butylbenzene SM 6200B <0.5 pg/L 11/24/2020 Tetrachloroethene SM 6200B <0.5pg/L 11/24/2020 Toluene SM 62008 <0.5 pg/L 11/24/2020 Trans-1,2-Dichloroethene SM 6200B <0.5 pg/L 11/24/2020 Trans-1,3-dichloropropene SM 6200B <0.5pg/L 11/24/2020 Trichloroethene SM 6200B <0.5 pg/L 11/24/2020 Trichlorofluoromethane SM 6200B <0.5pg/L 11/24/2020 Vinyl chloride SM 6200B <0.5 pg/L 11/24/2020 Fecal Coliform SM 9222D MF 33 Colonies/100ml- 11/17/2020 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2 0.04mg/L 11/18/2020 Nitrate+Nitrite-Nitrogen EPA353.2 0.95mg/L 11/24/2020 Nitrate Nitrogen Subtraction Method 0.91 mg/L 11/25/2020 Report #:: 2020-19581 Page 9 of 12 Environmental Cheists, Inc. 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 252.473.5702 Lab/Fax sM 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions -Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO M Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report M 2020-19581 Project ID: AG Protein Lab ID Sample ID: Collect Date/Time Matrix Sampled by 20-49843 Site: MW-4 11/17/2020 12:50 PM Water jcb/envirochem Test Method Results Date Analyzed Color Color Tan/Brown 11/17/2020 Depth to water, ft. Depth to Water, Ft. 1.6 feet 11/17/2020 Ammonia Nitrogen EPA350.1 < 0.2 mg/L 11/20/2020 Gallons bailed before sampling Gallons Bailed before sampling 10 gallons 11/17/2020 Odor Qualitative Sulfur 11/17/2020 Total Dissolved Solids (TDS) SM 2540 c 123 mg/L 11 /18/2020 Temperature SM 2550 B 19.3 C 11/17/2020 Chloride SM 4500 Cl E 20 mg/L 11/24/2020 pH SM 4500 H B 5.8 units 11/17/2020 Total Phosphorus SM 4500 P F 1.22 mg/L 11/24/2020 Total Organic Carbon (TOC) SM 5310 B 0.8 mg/L 11/17/2020 1, 1, 1,2-Tetrachloroethane SM 6200E <0.5 pg/L 11/24/2020 1, 1, 1 -Trichloroethane SM 62006 <0.5 pg/L 11/24/2020 1,1,2,2-Tetrachloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1,2-Trichloroethane SM 6200B <0.5 pg/L 11/24/2020 1,1-Dichloroethane SM 6200B <0.5 pg/L 11/24/2020 1, 1 -Dichloroethene SM 6200B <0.5 pg/L 11 /24/2020 1,1-Dichloropropene SM 6200B <0.5pg/L 11/24/2020 1,2,3-Trichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,2,3-Trichloropropane SM 6200B <0.5 pg/L 11/24/2020 1,2,4-Trichlorobenzene SM62008 <0.5pg/L 11/24/2020 1, 2,4-Trimethyl benzene SM 6200B <0.5 pg/L 11/24/2020 1,2-Dibromo-3-Chloropropane SM 6200B <0.5pg/L 11/24/2020 1,2-Dibromoethane SM 6200B <0.5 pg/L 11/24/2020 1,2-Dichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 1,2-Dichloroethane SM 6200B <0.5 pg/L 11/24/2020 Report # : 2020-19561 Page 10 of 12 _ $M ANALYTICAL & CONSULTING CHEMISTS ID Environmentale ists9Inca 6602 Windmill Way, Wilmington, NC 28405 = 910.392.0223 Lab 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 , 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein 1,2-Dichloropropane SM 6200B <0.5pg/L 11/24/2020 1,3,5-Trimethylbenzene SM 6200B <0.5 pg/L 11/24/2020 1,3-Dichlorobenzene SM 6200B <0.5pg/L 11/24/2020 1,3-Dichloropropane SM 6200B <0.5pg/L 11/24/2020 1,4-Dichlorobenzene SM 6200B <0.5 pg/L 11/24/2020 2,2-Dichloropropane SM 6200B <0.5 pg/L 11/24/2020 2-Chlorotoluene SM 6200B <0.5 pg/L 11/24/2020 4-Chlorotoluene SM 6200B <0.5 pg/L 11/24/2020 Benzene SM 6200B <0.5 pg/L 11/24/2020 Bromobenzene SM 6200B <0.5 pg/L 11/24/2020 Bromochloromethane SM 6200B <0.5 pg/L 11/24/2020 Bromodichloromethane SM 6200B <0.5 pg/L 11/24/2020 Bromoform SM 62006 <0.5 pg/L 11/24/2020 Bromomethane SM 62008 <0.5 pg/L 11/24/2020 Carbon tetrachloride SM 62008 <0.5 pg/L 11/24/2020 Chlorobenzene SM 6200E <0.5 pg/L 11/24/2020 Chloroethane SM 5200B <0.5 pg/L 11/24/2020 Chloroform SM 6200B <0.5 pg/L 11/24/2020 Chloromethane SM 6200E <0.5 pg/L 11/24/2020 cis- 1,2-Dichloroethene SM 6200B <0.5pg/L 11/24/2020 cis- 1,3-Dichloropropene SM 6200B <0.5pg/L 11/24/2020 Dibromochloromethane SM 6200B <0.5 pg/L 11 /24/2020 Dibromomethane SM 6200B <0.5 pg/L 11/24/2020 Dichlorodifluoromethane SM 6200B <0.5 pg/L 11/24/2020 Ethylbenzene SM 6200B <0.5 pg/L 11/24/2020 Hexachlorobutadiene SM 6200B <0.5 pg/L 11/24/2020 Isopropylbenzene SM 6200B <0.5pg/L 11/24/2020 M+P Xylene SM 6200B <1.0 pg/L 11/24/2020 Methylene chloride SM 6200B <0.5 pg/L 11/24/2020 Naphthalene SM 6200B <0.5 pg/L 11/24/2020 Report #:: 2020-19581 Page 11 of 12 ,; sM ANALYTICAL & CONSULTING CHEMISTS EnvironmentalChemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 910.392.0223 Lab ' 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 ° 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 910.347.5843 Lab/Fax inro@environmentaIchemists.com Smithfield Hog Productions - Warsaw Date of Report: Dec 02, 2020 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2020-19581 Project ID: AG Protein n-Butylbenzene SM 6200E <0.5 µg/L 11/24/2020 n-Propylbenzene SM 6200B <0.5 µg/L 11/24/2020 ortho-Xylene SM 6200B <0.5 µg/L 11/24/2020 p-Isopropyltoluene SM 6200B <0.5µg/L 11/24/2020 sec-Butylbenzene SM 62006 <0.5 µg/L 11/24/2020 Styrene SM 6200B <0.5 µg/L 11/24/2020 tert-B utyl benzene SM 62008 <0.5 µg/L 11/24/2020 Tetrachloroethene SM 6200B <0.5 µg/L 11/24/2020 Toluene SM 6200B <0.5 µg/L 1112412020 Trans-1,2-Dichloroethene SM 6200B <0.5µg/L 11/24/2020 Trans-1,3-dichloropropene SM 6200B <0.5µg/L 11/24/2020 Trichloroethene SM 6200B <0.5 µg/L 11/24/2020 Trichiorofluoromethane SM 6200B <0.5 µg/L 11/24/2020 Vinyl chloride SM 6200B <0.5 µg/L 11/24/2020 Fecal Coliform SM9222DMF <1 Colonies/100ml- 11/17/2020 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2 0.02 mg/L 11/18/2020 Nitrate+Nitrite-Nitrogen EPA353.2 1.21 mg/L 11/24/2020 Nitrate Nitrogen Subtraction Method 1.19 mg/L 11/25/2020 Comment: Reviewed by: Report #:: 2020-19581 Page 12 of 12 Date: jAX Anal%st- Certification A! 9a Facilih Name: A ,Ira Permit9. 0'a 00V%Srj0 Reference Method SSI4500 H-B -201 1 Instrument [D 6,4, Calibration Time Cal Buffer 4 0 s u Cal Buffer 10 0 s u Check Buffer 7.0 s u Comments 'pH check buffer must read % tthin = 0 1 pH units of the buffer's true value 4 su buffer Lot,' Ricca 2001 B20 Exp 1/2022 7 su buffer Lot=.: Ricca 2009993 Exn, 7,2022 10 su buffer Lot-7 Ricca 1001791 7-2021 Sam re I,3cation Sample Collection p Sample Analysis pH Result IdPost-analysis Buffer I Comments DataQualiFers f Time• Time s u Check values u M w�— �- /[ S7. /LrL I S•�� ► Post analysis buffer check is required «hen performing analyses at multiple sampling locations and must be within = 0 1 unitss of the buffer's true value A11 pH values in pH un±ts (i e , s u ) Record all data to the nearest 0 DI s u and report to the nearest 0 1 s u Total Residual Chlorine (TRC) Reference Method SM 450o Cl-G201 1. Flach 8167 HR ( Please circle aritilicable Method Instrument ID Post -anal) sis Dail} Chock Time check Sample Sampi� Check Sid Sample TRC Result Standard Result Standard Location Collection Analysis Q Comments Data Qualifier, eL or mg L (when anahzin� Anahzed µ> L ormg'L µ` at multiple sites) Time Timz7 TRC Daily Check Standard true talus µgfL or mg11, acceptance range or mg'L Check standards must recover %v ithin _l0°, u of the check standards true value Annual Calibration Curve Verification Date: LOT# Exp. Date Reagent Blank Value. When applicable Analyze and document a reagent blank when standards. sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Method S:`4 4500 0 G: 2u:1 1 Instrument ID • Post -anal} sis calibration I Calibraunn Calibration variable Meter reading %enfication (when necessan ) Ventica ion or °o efficiency Comments Time Barometne a ftercalibration Theoretical Calculated Temperature pressure Value me L Value meL I I I I Use this rove %then performing a %erincation instead of calibration Sample Location Sample Collection 'Sample Analysis DO reading P Time Time ma L Comments Data Qualifiers • When performing analyses at multiple locations, the meter must be recalibrated at each site before analysis or a post -analysis calibration verification must be performed ` [f sample is measured directly inthe stream and or onsite. only time anal} zed could be recorded with a nore that they are measured in situ or immediately Temperature Reference Method Ski 2550 B-2010 Instrument ID. Sample 'Sample Temperature Sample Location Collection Anaysis I °C CommentsData Qualifiers Time Time /!A V t I .s %% e_ 1 /. S 3 L I, it. ` If sample is measured d;rec j m the stream and or on site, only time anahzed would be recorded. with a note that the% are measured in situ or immediate!} Annual Venfication Date )&w� Field Personnel Note: Q k.001 Rev 9-2020 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way Wilmington, NC 28405 910.392.0223 Sample Receipt Checklist Client�`L l`" ] Eu�) Date: Report Number: f Receipt of sample: ECHEM Pickupt Client Delivery ❑ UPS [7 Far1F rn nthor r'1 ❑ YES ❑ NO N/A 1. Were custody seals present on the cooler? YES [O'riginal ❑ NO N/A 2. If custody seals were present, were they intact/unbroken? temperature upon receipt _.__�—°C Corrected temperature upon receipt C. How temperature taken: ❑ Temperature Blank tj Against Bottles IR Gun ID: Thomas Traceable S/N 192511657 IR Gun Correction Factor °C: 0.0 ❑ YES 10 NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? YES I ❑ NO 4. Were proper custody procedures (relinquished/received) followed? YES 113 NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? IR YES ❑ NO c? nirl camnlcc 7rrivo in nr- r ..t ; F L. � �a l [X YES 10 NO 110. Did samples arrive in good condition for each test? YES 10 NO 111. Was adequate sample volume available?' LV YES 10 NO 112. Were samples received within proper holding time for requested tests? YES ❑ NO 113. Were acid preserved samples received at a pH of <2? YES 10 NO 114, Were cyanide samples received at a pH >12? O YES 10 NO 15. Were sulfide samples received at a pH >9? YES ID NO 16. Were NH3/TKN/Phenol received at a chlorine residual of <0.5 m/L? ** 19 YES ❑ NO 17. Were Sulfide/Cyanide received at a chlorine residual of <0.5 m/L? ❑ YES 10 NO 18. Were orthophosphate samples filtered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet. ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accordingly by adding (circle one): H2504 HNO3 NCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note: Notify customer service immediately for incorrectly preserved samples. Obtain a new sample or notify the state lab if directed to analyzed by the customer. Who was notified, date and time: Volatiles Sample(s) were received with headspace COMMENTS: DOC. QA.002 Rev 1 _ ENVIRONMENTAL CHEMISTS, INC OFFI E:9101392-02 3f1FAX910392-44245 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY Client: Smithfield Hog Production -Warsaw PROJECT NAME: Ag Protein (Magnolia,NC) REPORT NO: 1� - i, ADDRESS: CONTACT NAME: Permit Number: W00040918 REPORT TO: Kraig Westerbeek PHONE/FAX: COPY TO: Amy Elmore email: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection -' w E h m a E° C! ct7 o c ° E " �W m g z PRESERVATION ANALYSIS REQUESTED t Time Temp i $ u _ H o y 0 z o w c 9 MW: ro f� tL�J C P 9�� cj X Chloride, NO2,TDS, G G B Depth to water: C P �' X INH3,NO3,Total P G G Gallons bailed: { ® C P X TOC G G H field): �• C P X Fecal Coliform G G Depth to water: C P X VOC's November only) G G Color: 4A j ¢d, C P G G Odor: sij .L_ C P G G C P G G C P G G, Total of 4 wells due march, july, november: MW1,2,3,4. Site located on Bonham Road, Magnolia, NC. Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. ,® Temperature when Received °C: Accepted: Rejected: Resample a ested: Delivered By: Received By: Date: '/ 1 h Time: Comments: T R AROUND: y Way ton ENVIRONMENTAL CHEMISTS, INC OFFICE: 910i1392-02 3'IFAX9910'392-44245 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY Client: Smithfield Hog Production -Warsaw PROJECT NAME: Ag Protein Magnolia,NC) REPORT NO: 0 — 06(3 % ADDRESS: CONTACT NAME: - Permit Number: W00040918 REPORT TO: Kraig Westerbeek PHONE/FAX: COPY TO: Amy Elmore email: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream. SO = Soil. SL = Sludge. Other: Sample IdentificationE Collection y w E o `o '" `o m " E inz g z PRESERVATION ANALYSIS REQUESTED Date Time Temp oz J x o "_ 0 0 Z 0 o MW X Chloride, NOUDS, G G Depth to water: j lt C P X Z INH3,NO3,Total P G G Gallons bailed: f C P X TOC G G pH (field): - C P X Fecal Coliform G G De to water: C P VOC's (November only) G HX G Color. �• ,., C P G G Odor: A j o„e. C P G G C P G G C P G G Total of 4 wells due march, july, november: MW1,2,3,4. Site located on Bonham Road, Magnolia, NC. Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. i emNeratUre when mecelvea -c: _ Accepted: v Reje ted: Resattap�e R quested: Delivered By: FGC-E Received By: P� Date: 1-1 12Z Time: Comments: TURNAROUND: ll Way on, NC ndm EE � �e� ENVIRONMENTAL CHEMISTS' INC OFFICE: 9 0,392-0223'IFAX 910392-44245 Analytical &Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY Client: Smithfield Hog Production -Warsaw PROJECT NAME: Ag Protein (Magnolia,NC) REPORT NO: ZO — f ADDRESS: CONTACT NAME: Permit Number: W00040918 REPORT TO: Kraig Westerbeek PHONE/FAX: COPY TO: Amy Elmore email: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil. SL = Sludge. Other: Sample Identification Collection d d ~ � a a E `o cf7 3 `o c J `o E t " CW m g Z PRESERVATION ANALYSIS REQUESTED D to Time Tempa z m $ u _ o m _ h ° = x o z G W x MW. Lf• L C P X Chloride, NOUDS, G G Depth to water: 9� •� C P X L" NH3,NO3,Total P G G Gallons bailed: / d C P X TOC G G H (field): C P X I Fecal Coliform G G Depth to water: C P X VOC's (November only) G G Color: 4w. u (®,J C P G G Odor: W'k C P G G C P G G C P G G Total of 4 wells due march, july, november: MW1,2,3,4. Site located on Bonham Road, Magnolia, NC. Transfer Relinquished By: DatelTime Received By: Date/Time 1. 2. I emperature When Received -G: Accepted: L­-� R 'ected: Resampl Requested: Delivered By: Received By:_ Date: —MY? 1 Time: Comments: TURNAROUND: E4E1#:k:) Analytical & Consulting Chemists Client: Smithfield Hog Production -Warsaw ADDRESS: �Sampled By: Sample Identification MW: y Depth to water: Gallons bailed: t a PH (field): S• �1 Depth to water: �_ Color: !' 6(�r Odor: S-41-W otal of 4 wells due Transfer 1 INC 6602WindmillWayWilmington,NC28405 ENVIRONMENTAL CHEMISTS OFFICE: 910-392-0223 FAX 910-392-4424 NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 Info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY PROJECT NAME: Ag Protein (Ma nolia,NC) REPORT NO: CD0 CONTACT NAME: Permit Number: WQ0040918 REPORT TO: Kraig Westerbeek PHONE/FAX: COPY TO: Amy Elmore email: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = ollection W PRESERVATION a ° m F E° 0 c° .2 E Q M o � 0 o 0 0 T Time Temp v, u ° u .I Z = = s i Z F- 0 3 c G G � S� X Chloride C P november: MWI,2,3,4. Site located on Bonham Road, Magnolia, NC. Relinquished By: Date[Time Ave Temperature when Received °C: Accepted: Delivered By: Received By: Comments: SL = Sludge, Other: ANALYSIS REQUESTED TDS Resam a Requested: Date :I 1 2 Time: TURNAROUND: Date/Time