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Home My WebLink AboutWQ0003698_Monitoring - 11-2020_20201229GW-59A COMPLIANCE REPORT FORM Permit # W Q0p9a-3(c g,? (Submit one each monitoring period with GW-59 forms.) j Enter date monitoring results were due. Q V1412PV ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES N z IF the answer to question 1 or 2 is "YES", list in the space provided below the well identi 'orx�umb and explain the problems encountered in obtaining the required information. N Ll. CO M U �Z LUJ O 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked o sing cap, m ing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes ", contact the Regional Ofce�uidance. X 4 Are any monitored constituents equal to or above the established standards? YES X NO If the answer to question 4 is "NO", skip to section 8. �, If the answer to 4 is "YES" list the question affected wells individually with constituent(s) cond ration(s) exceeding standards in the space provided below: See- 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? X If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). �� A444d1ec' Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO x If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly located, contact the Regional Office. 'w 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? u If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be required to determine the impact the waste disposal system is having at the review and compliance boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation fines, and/or penalties. 0—f:6ce CO rv+ciG-�—L 8 The person completing this portion (G W-59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form. I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. Z_ Signature f Permittee orize gent) Date GW-59A 12/8/2003 For Qc(e5fioh-Af Lf 11/16/2020 1 Iron 0.691 mg/L Manganese 50.6 ug/L pH 6 2 Ammonia 5.6 mg/L Iron 21.6 mg/L Manganese 1490 ug/L pH 6.4 3 Nitrate 32.1 mg/L Iron 1.07 mg/L Manganese 434 ug/L pH 5 4 Manganese 127 ug/L pH 5.1 11/12/2018 1 pH 5.9 2 Ammonia 6.2 mg/L Iron 32 mg/L Manganese 1300 ug/L pH 6.3 3 Nitrate 34.6 mg/L Iron 0.62 mg/L Manganese 360 ug/I 4 Iron 5.1 mg/L Manganese 130 ug/L pH 4.9 5/13/2019 1 Iron 3.5 mg/L Manganese 81 ug/L pH 5.8 0.063 Ammonia 7.2 mg/L Iron 36 mg/L Manganese 960 ug/L 3 Nitrate 39 mg/L Iron 2.5 mg/L pH 4.6 4 Iron 15 mg/L Manganese 120 ug/L pH 4.9 11/20/2019 1 Iron 0.34 mg/L pH 5.9 2 Ammonia 5.0 mg/L Iron 17 mg/L Manganese 1100 ug/L 3 Nitrate 39.2 Iron 2.3 mg/L Manganese 5800 ug/L pH 4.8 4 Iron 1.1 mg/L Manganese 93 ug/L pH 5.1 5/19-27/2020 1 Iron 0.34 mg/L pH 5.2 2 Ammonia 6.7 mg/L Iron 43 mg/L Manganese 1360 ug/L 3 Nitrate 40.5 mg/L Iron 0.5 mg/L Manganese 573 ug/L pH 4.7 4 Manganese 149 ug/L pH 4.5 11/16/2020 1 Iron 0.691 mg/L Manganese 50.6 ug/L pH 6 2 Ammonia 5.6 mg/L Iron 21.6 mg/L Manganese 1490 ug/L pH 6.4 3 Nitrate 32.1 mg/L Iron 1.07 mg/L Manganese 434 ug/L pH 5 4 Manganese 127 ug/L pH 5.1 SUBMIT FORM ON YELLOW PAPER ONLY (GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Corpening Creek WWTP--City of Marion Permit Name (if different): Facility Address: Marion NC 28752 Marion NC 28752 County McDowell cnv, (Stan) Z;P; ntact Person: Tim Horton Telephone#: (828) 652-8843 fll Location/Site Name: Monitoring Well #1 R No. of wells to be sampled: 4 =LL ID NUMBER (from Permit): Monitoring Well #1 R Date sample collected: 11/16/2020 A Depth: 65 ft. Well Diameter: 2 in. pth to Water Level 82546:20.26 ft. below measuring point Screened Interval: 55 ft. !asuring Point is 1.5 ft. above land surface Relative M.P. Elevation: lume of water pumped/bailed before sampling: gallons moles for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: X YES DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES INFORMATION PROCESSING UNIT 17 Phone:919-807-6306 PERMIT Number: Expiration Date: 3/ ZbZZ Non -Discharge WQ00003698 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: to 65 ft ft. ❑ NO FIELD ANALYSES: pH 00000: 6.0 units Spec. Cond. 00094: Odor 00085: Appearance Temp. 000lo: 13.7 °C uMhos None Clear If WELL DRY at time of sampling, here: ❑ Date sample analyzed: 11/16 - 25/2020 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 <5 Coliform: MF Fecal 31616 /100mL Nitrate (NO) as N 00620 0.063 mg/L Zn - Zinc 01092 g/L Coliform: MF Total 31504 (Note. Use MPN method for highly turbid samples) /100mL Phosphorus: Total as P 00665 mg/L R� 1 �b`h Orthophosphate 70507 mg/L Other (Specify Compounds and Concent ln)2020 issolved Solids:Total 70300 26 mg/L Al -Aluminum 01105 mg/L TSS 15.5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 <1 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.54 ug/L Arsenic 01002 <10 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <20 ug/L Fe - Iron 01045 691 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn - Manganese 01055 50.6 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Apent) Name and Title - Please print or type GW-59 Rev.05-02-2017 (Date) SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please f1rint cleanyor type Facility Name: Corpening Creek WWTP--City of Marion Permit Name (if different): Facility Address: Marion NC 28752 Marion "`''' NC 28752 County McDowell , Ay? Contact Person: Tim Horton Telephone#: (828) 652-8843 Well Location/Site Name: Monitoring Well #2 No. of wells to be sampled: 4 DIV. OF WATER INFORMATION PROCESSING UNIT :E CENTER, RALEIGHiJK271 %j,7, ,PtW *: RMIT Number: Expiration Date: 3 / 22 n-Discharge WQ00003698 UIC DES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: WELL ID NUMBER (from Permit): Monitoring Well #2 Date sample collected: 11/16/2020 Well Depth: 40 ft. Well Diameter: 2 in. Depth to Water Level 82546:16.58 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Measuring Point is 0.22 ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO FIELD ANALYSES: pH oo400: 6.4 units Temp. 00010: 14.8 °C Spec. Cond. 00094: µMhos Odor 00085: Sulfur Appearance Clear WAS DRY at time of sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed:11/16/2020 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 <5 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 0.73 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note. Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 <25 mg/L Al -Aluminum 01105 mg/L TSS 13.6 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2.1 mg/L Ca - Calcium 00916 mg/L Chloride oo94o mg/L Cd - Cadmium 01027 <1 ug/L Arsenic 01002 <10 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <20 ug/L Fe - Iron 01045 21600 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200B Total Ammonia 00610 5.6 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH,asN, Ammonia Nitrogen. Total) Mn - Manganese 01055 1490 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Aqent) Name and Title - Please print or type GW-59 Rev.05-02-2017 (Date) SUBMIT FORM ON YELLOW PAPER ONLY (GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Name: Corpening Creek WWTP--City of Marion Name (if different): Address: Marion Marion �YI NC 28752 IStdle) (Z it'j or type NC 28752 County McDowell 8ct Person: Tim Horton Telephone#: (828) 652-8843 Location/Site Name: Monitoring Well # 3 No. of wells to be sampled: 4 (from Permit) DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES INFORMATION PROCESSING UNIT EIGH, NC 27699-1617 Phone: 919-807-6306 RMIT Number: Expiration Date: 51 n-Discharge WQ00003698 UIC 'DES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: If WELL WELL ID NUMBER (from Permit): Monitoring Well #3 Date sample collected: 5/27020 Well Depth: 52 ft. Well Diameter: 2 in. Depth to Water Level 82546:30.67 ft. below measuring point Screened Interval: 30 ft. to 40 ft. Measuring Point is 1.09 ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO FIELD ANALYSES: pH oo400: 5.0 units Temp. 00010: 10.9 °C Spec. Cond. 00094: µMhos Odor 00085: Musty Appearance Semi Cloudy WAS DRY at time of sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed:11/16/2020 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 <5 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 32.1 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 309 mg/L Al -Aluminum 01105 mg/L TSS 18.5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.1 mg/L Ca - Calcium 00916 mg/L Chloride oo94o mg/L Cd - Cadmium 01027 1.5 ug/L Arsenic 01002 <10 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <20 ug/L Fe - Iron 01045 1070 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? K Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen, NH3 as N, Ammonia Nitrogen, Total) Mn -Manganese 01055 434 ug/L ,method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTM _ TER RESOURCES GROUNDWATER QUALITY MONITORING: , , , , _ _.._ fWORMATION PROM" NGUNIT COMPLIANCE REPORT FORM I - '8MvtcECENTER, RAt r t z a t6�7 ,; a�aso7 3o6 : FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: Facility Name: Corpening Creek WWTP--City of Marion Non -Discharge WQ00003698 UIC NPDES Other Permit Name (if different): Facility Address: Marion NC 28752 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Marion ` " INC 28752 County McDowell C11y fS::1rF, ;.... ❑ Spray Field El Remediation: Contact Person: Tim Horton Telephone#: (828) 652-8843 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Monitoring Well #4 No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Monitoring Well #4 Date sample collected: 5/219/2020 FIELD ANALYSES: WAS Well Depth: 33 ft. Well Diameter: 2 in. pH 00400: 5.1 units Temp. 000lo: 14.7 eC DRY at Depth to Water Level 82546: 16.61 ft. below measuring point Screened Interval: 18.5 ft. to 33 ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 0.51 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume ofwater pumped/bailed before sampling: gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑■ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 11/16/2020 Laboratory Name: Pace Analytical Certification No. 12 & 40 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 mg/L Pb - Lead 01051 <5 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 <0.040 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): Dissolved Solids:Total 70300 35 mg/L Al -Aluminum 01105 mg/L TSS <2.5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 <1.00 mg/L Ca - Calcium 00916 mg/L Chloride 00940 mg/L Cd - Cadmium 01027 0.59 ug/L Arsenic 01002 <10 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 <20 ug/L Fe - Iron 01045 <50 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # 6200B Total Ammonia 00610 <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 127 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% GW-59 Rev.05-02-2017 alceAnalytical www.pacelabs.eom Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 December 04, 2020 Mr. Tim Horton City of Marion 3982 NC Hwy 226 South Marion, NC 28752 RE: Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Dear Mr. Horton: Enclosed are the analytical results for sample(s) received by the laboratory on November 16, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services -Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Lord Patton lorri.patton@pacelabs.com 1(828)254-7176 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 34 � acekAnalytical www.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Project: Pace Project No.: City of Marion MWs_Nov 2020 92506300 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92506300001 MW-1R EPA 200.7 Rev 4.4 1994 BG2 5 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2011 RED 1 PASI-A SM 2540D-2011 RED 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 1 PASI-A EPA 420.4 Rev 1.0 1993 JKG 1 PASI-A SM 5310B-2011 ECH 1 PASI-A 92506300002 MW-2 EPA 200.7 Rev 4.4 1994 BG2 5 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2011 RED 1 PASI-A SM 2540D-2011 RED 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 1 PASI-A EPA 420.4 Rev 1.0 1993 JKG 1 PASI-A SM 5310B-2011 ECH 1 PASI-A 92506300003 MW-3 EPA 200.7 Rev 4.4 1994 BG2 5 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2011 RED 1 PASI-A SM 2540D-2011 RED 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 1 PASI-A EPA 420.4 Rev 1.0 1993 JKG 1 PASI-A SM 5310B-2011 ECH 1 PASI-A 92506300004 MW-4 EPA 200.7 Rev 4.4 1994 BG2 5 PASI-A SM 6200B SAS 63 PASI-C SM 2540C-2011 RED 1 PASI-A SM 2540D-2011 RED 1 PASI-A EPA 350.1 Rev 2.0 1993 KDF1 1 PASI-A EPA 353.2 Rev 2.0 1993 CJL 1 PASI-A EPA 420.4 Rev 1.0 1993 JKG 1 PASI-A SM 5310B-2011 ECH 1 PASI-A PASI-A = Pace Analytical Services Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 34 t r aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MWAR Lab ID: 92506300001 Collected: 11/16/20 12:10 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/04/20 07:49 Collected By Ryan Byas 1 12/04/20 07:49 Collected Date 11/16/20 1 12/04/20 07:49 Collected Time 12:10 1 12/04/20 07:49 pH 6.0 Std. Units 1 12/04/20 07:49 Temperature 13.7 deg C 1 12/04/20 07:49 Static Water Level 20.26 feet 1 12/04/20 07:49 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/24/20 02:24 11/25/20 15:13 7440-38-2 Cadmium 0.54J ug/L 1.0 1 11/24/20 02:24 11/25/20 15:13 7440-43-9 Iron 691 ug/L 50.0 1 11/24/20 02:24 11/25/20 15:13 7439-89-6 Lead ND ug/L 5.0 1 11/24/20 02:24 11/25/20 15:13 7439-92-1 Manganese 50.6 ug/L 5.0 1 11/24/20 02:24 11/25/20 15:13 7439-96-5 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/18/20 15:36 71-43-2 Bromobenzene ND ug/L 0.50 1 11/18/20 15:36 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/18/20 15:36 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/18/20 15:36 75-27-4 Bromoform ND ug/L 0.50 1 11/18/20 15:36 75-25-2 Bromomethane ND ug/L 5.0 1 11/18/20 15:36 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/18/20 15:36 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/18/20 15:36 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/18/20 15:36 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/18/20 15:36 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/18/20 15:36 108-90-7 Chloroethane ND ug/L 1.0 1 11/18/20 15:36 75-00-3 Chloroform ND ug/L 0.50 1 11/18/20 15:36 67-66-3 Chloromethane ND ug/L 1.0 1 11/18/20 15:36 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/18/20 15:36 9549-8 4-Chlorotoluene ND ug/L 0.50 1 11/18/20 15:36 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/18/20 15:36 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/18/20 15:36 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/18/20 15:36 106-93-4 Dibromomethane ND ug/L 0.50 1 11/18/20 15:36 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:36 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:36 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:36 10646-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/18/20 15:36 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/18/20 15:36 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/18/20 15:36 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/18/20 15:36 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 34 t � keAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MWAR Lab ID: 92506300001 Collected: 11/16/20 12:10 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte cis-1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 15:36 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 15:36 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/18/20 15:36 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/18/20 15:36 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/18/20 15:36 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/18/20 15:36 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 15:36 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 15:36 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/18/20 15:36 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/18/20 15:36 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/18/20 15:36 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/18/20 15:36 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/18/20 15:36 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/18/20 15:36 1634-04-4 Naphthalene ND ug/L 2.0 1 11/18/20 15:36 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/18/20 15:36 103-65-1 Styrene ND ug/L 0.50 1 11/18/20 15:36 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 15:36 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 15:36 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/18/20 15:36 127-18-4 Toluene ND ug/L 0.50 1 11/18/20 15:36 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/18/20 15:36 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/18/20 15:36 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/18/20 15:36 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/18/20 15:36 79-00-5 Trichloroethene ND ug/L 0.50 1 11/18/20 15:36 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/18/20 15:36 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/18/20 15:36 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/18/20 15:36 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/18/20 15:36 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/18/20 15:36 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/18/20 15:36 179601-23-1 o-Xylene ND ug/L 0.50 1 11/18/20 15:36 9547-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 11/18/20 15:36 17060-07-0 4-Bromofluorobenzene (S) 93 % 70-130 1 11/18/20 15:36 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/18/20 15:36 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services - Asheville Total Dissolved Solids 26.0 mg/L 25.0 1 11/19/20 17:36 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Pace Analytical Services - Asheville Total Suspended Solids 15.5 mg/L 2.5 1 11/20/20 18:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 34 aceAnalytical www.pecolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MWAR Lab ID: 92506300001 Collected: 11/16/20 12:10 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/25/20 12:31 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.063 mg/L 0.040 1 11/17/20 22:13 14797-55-8 420.4 Phenolics, Total Analytical Method: EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993 Pace Analytical Services -Asheville Phenol ND mg/L 0.020 1 11/18/2010:40 11/18/2014:54 108-95-2 5310E TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 11/25/20 20:43 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 34 GAnalytcal' www.pacolobs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-2 Lab ID: 92506300002 Collected: 11/16/20 10:45 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/04/20 07:46 Collected By Ryan Byas 1 12/04/20 07:46 Collected Date 11/16/20 1 12/04/20 07:46 Collected Time 10:45 1 12/04/20 07:46 pH 6.4 Std. Units 1 12/04/20 07:46 Temperature 14.8 deg C 1 12/04/20 07:46 Static Water Level 16.58 feet 1 12/04/20 07:46 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/24/20 02:24 11/25/20 15:16 7440-38-2 Cadmium ND ug/L 1.0 1 11/24/20 02:24 11/25/20 15:16 7440-43-9 Iron 21600 ug/L 50.0 1 11/24/20 02:24 11/25/20 15:16 7439-89-6 Lead ND ug/L 5.0 1 11/24/20 02:24 11/25/20 15:16 7439-92-1 Manganese 1490 ug/L 5.0 1 11/24/20 02:24 11/25/20 15:16 7439-96-5 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/18/20 15:54 71-43-2 Bromobenzene ND ug/L 0.50 1 11/18/20 15:54 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/18/20 15:54 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/18/20 15:54 75-27-4 Bromoform ND ug/L 0.50 1 11/18/20 15:54 75-25-2 Bromomethane ND ug/L 5.0 1 11/18/20 15:54 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/18/20 15:54 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/18/20 15:54 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/18/20 15:54 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/18/20 15:54 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/18/20 15:54 108-90-7 Chloroethane ND ug/L 1.0 1 11/18/20 15:54 75-00-3 Chloroform ND ug/L 0.50 1 11/18/20 15:54 67-66-3 Chloromethane ND ug/L 1.0 1 11/18/20 15:54 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/18/20 15:54 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/18/20 15:54 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/18/20 15:54 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/18/20 15:54 12448-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/18/20 15:54 106-93-4 Dibromomethane ND ug/L 0.50 1 11/18/20 15:54 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:54 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:54 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/18/20 15:54 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/18/20 15:54 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/18/20 15:54 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/18/20 15:54 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/18/20 15:54 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 34 � r aceAnalytical www.pacollbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-2 Lab ID: 92506300002 Collected: 11/16/20 10:45 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte cis- 1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 15:54 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 15:54 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/18/20 15:54 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/18/20 15:54 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/18/20 15:54 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/18/20 15:54 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 15:54 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 15:54 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/18/20 15:54 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/18/20 15:54 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/18/20 15:54 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/18/20 15:54 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/18/20 15:54 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/18/20 15:54 1634-04-4 Naphthalene ND ug/L 2.0 1 11/18/20 15:54 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/18/20 15:54 103-65-1 Styrene ND ug/L 0.50 1 11/18/20 15:54 10042-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 15:54 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 15:54 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/18/20 15:54 127-18-4 Toluene ND ug/L 0.50 1 11/18/20 15:54 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/18/20 15:54 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/18/20 15:54 120-82-1 1.1,1-Trichloroethane ND ug/L 0.50 1 11/18/20 15:54 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/18/20 15:54 79-00-5 Trichloroethene ND ug/L 0.50 1 11/18/20 15:54 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/18/20 15:54 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/18/20 15:54 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/18/20 15:54 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/18/20 15:54 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/18/20 15:54 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/18/20 15:54 179601-23-1 o-Xylene ND ug/L 0.50 1 11/18/20 15:54 9547-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 11/18/20 15:54 17060-07-0 4-Bromofluorobenzene (S) 95 % 70-130 1 11/18/20 15:54 460-00-4 Toluene-d8 (S) 99 % 70-130 1 11/18/20 15:54 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids ND mg/L 25.0 1 11/19/20 17:36 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Pace Analytical Services -Asheville Total Suspended Solids 13.6 mg/L 2.5 1 11/20/20 18:13 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 34 • a aceAnalytical www.paceilbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-2 Lab ID: 92506300002 Collected: 11/16/20 10:45 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 5.6 mg/L 0.10 1 11/25/20 12:33 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.73 mg/L 0.040 1 11/17/20 22:14 14797-55-8 420.4 Phenolics, Total Analytical Method: EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993 Pace Analytical Services -Asheville Phenol ND mg/L 0.020 1 11/18/2010:40 11/18/2014:58 108-95-2 5310E TOC Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 2.1 mg/L 1.0 1 11/25/20 20:58 7440-44-0 Date: 12/04/2020 07:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 34 t aceAnalytical www.pacollbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-3 Lab ID: 92506300003 Collected: 11/16/20 09:55 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/04/20 07:50 Collected By Ryan Byas 1 12/04/20 07:50 Collected Date 11/16/20 1 12/04/20 07:50 Collected Time 09:55 1 12/04/20 07:50 pH 5.0 Std. Units 1 12/04/20 07:50 Temperature 10.9 deg C 1 12/04/20 07:50 Static Water Level 30.67 feet 1 12/04/20 07:50 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/24/20 02:24 11/25/20 15:20 7440-38-2 Cadmium 1.5 ug/L 1.0 1 11/24/20 02:24 11/25/20 15:20 7440-43-9 Iron 1070 ug/L 50.0 1 11/24/20 02:24 11/25/20 15:20 7439-89-6 Lead ND ug/L 5.0 1 11/24/20 02:24 11/25/20 15:20 7439-92-1 Manganese 434 ug/L 5.0 1 11/24/20 02:24 11/25/20 15:20 7439-96-5 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/18/20 16:12 71-43-2 Bromobenzene ND ug/L 0.50 1 11/18/20 16:12 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/18/20 16:12 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/18/20 16:12 75-27-4 Bromoform ND ug/L 0.50 1 11/18/20 16:12 75-25-2 Bromomethane ND ug/L 5.0 1 11/18/20 16:12 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/18/20 16:12 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/18/20 16:12 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/18/20 16:12 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/18/20 16:12 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/18/20 16:12 108-90-7 Chloroethane ND ug/L 1.0 1 11/18/20 16:12 75-00-3 Chloroform ND ug/L 0.50 1 11/18/20 16:12 67-66-3 Chloromethane ND ug/L 1.0 1 11/18/20 16:12 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/18/20 16:12 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/18/20 16:12 106-434 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/18/20 16:12 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/18/20 16:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/18/20 16:12 106-93-4 Dibromomethane ND ug/L 0.50 1 11/18/20 16:12 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:12 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:12 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:12 10646-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/18/20 16:12 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 11/18/20 16:12 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/18/20 16:12 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/18/20 16:12 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 34 t aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-3 Lab ID: 92506300003 Collected: 11/16/20 09:55 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte cis- 1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 16:12 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 16:12 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/18/20 16:12 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/18/20 16:12 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/18/20 16:12 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/18/20 16:12 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 16:12 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 16:12 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/18/20 16:12 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/18/20 16:12 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/18/20 16:12 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 11/18/20 16:12 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/18/20 16:12 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/18/20 16:12 1634-04-4 Naphthalene ND ug/L 2.0 1 11/18/20 16:12 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/18/20 16:12 103-65-1 Styrene ND ug/L 0.50 1 11/18/20 16:12 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 16:12 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 16:12 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/18/20 16:12 127-18-4 Toluene ND ug/L 0.50 1 11/18/20 16:12 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/18/20 16:12 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/18/20 16:12 120-82-1 1, 1, 1 -Trichloroethane ND ug/L 0.50 1 11/18/20 16:12 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/18/20 16:12 79-00-5 Trichloroethene ND ug/L 0.50 1 11/18/20 16:12 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/18/20 16:12 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/18/20 16:12 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/18/20 16:12 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/18/20 16:12 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/18/20 16:12 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/18/20 16:12 179601-23-1 o-Xylene ND ug/L 0.50 1 11/18/20 16:12 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 11/18/20 16:12 17060-07-0 4-Bromofluorobenzene (S) 95 % 70-130 1 11/18/20 16:12 460-00-4 Toluene-d8 (S) 98 % 70-130 1 11/18/20 16:12 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 254OC-2011 Pace Analytical Services -Asheville Total Dissolved Solids 309 mg/L 25.0 1 11/19/20 17:36 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Pace Analytical Services -Asheville Total Suspended Solids 18.5 mg/L 2.5 1 11/20/20 18:13 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-3 Lab ID: 92506300003 Collected: 11/16/20 09:55 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/25/20 12:44 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate 32.1 mg/L 0.40 10 11/17/20 22:53 14797-55-8 420.4 Phenolics, Total Analytical Method: EPA420.4 Rev 1.0 1993 Preparation Method: EPA420.4 Rev 1.0 1993 Pace Analytical Services - Asheville Phenol ND mg/L 0.020 1 11/18/2010:40 11/18/2014:59 108-95-2 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1.1 mg/L 1.0 1 11/25/20 21:15 7440-44-0 Date: 12/04/2020 07:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 34 ace Analytical www.pacolobs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-4 Lab ID: 92506300004 Collected: 11/16/20 13:05 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual Monitoring Well Data Analytical Method: Pace Analytical Services - Charlotte Performed by Pace 1 12/04/20 07:52 Collected By Ryan Byas 1 12/04/20 07:52 Collected Date 11/16/20 1 12/04/20 07:52 Collected Time 13:05 1 12/04/20 07:52 pH 5.1 Std. Units 1 12/04/20 07:52 Temperature 14.7 deg C 1 12/04/20 07:52 Static Water Level 16.61 feet 1 12/04/20 07:52 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 11/24/20 02:24 11/25/20 15:29 7440-38-2 Cadmium 0.59J ug/L 1.0 1 11/24/20 02:24 11/25/20 15:29 7440-43-9 Iron ND ug/L 50.0 1 11/24/20 02:24 11/25/20 15:29 7439-89-6 Lead ND ug/L 5.0 1 11/24/20 02:24 11/25/20 15:29 7439-92-1 Manganese 127 ug/L 5.0 1 11/24/20 02:24 11/25/20 15:29 7439-96-5 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte Benzene ND ug/L 0.50 1 11/18/20 16:30 7143-2 Bromobenzene ND ug/L 0.50 1 11/18/20 16:30 108-86-1 Bromochloromethane ND ug/L 0.50 1 11/18/20 16:30 74-97-5 Bromodichloromethane ND ug/L 0.50 1 11/18/20 16:30 75-27-4 Bromoform ND ug/L 0.50 1 11/18/20 16:30 75-25-2 Bromomethane ND ug/L 5.0 1 11/18/20 16:30 74-83-9 n-Butylbenzene ND ug/L 0.50 1 11/18/20 16:30 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 11/18/20 16:30 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 11/18/20 16:30 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 11/18/20 16:30 56-23-5 Chlorobenzene ND ug/L 0.50 1 11/18/20 16:30 108-90-7 Chloroethane ND ug/L 1.0 1 11/18/20 16:30 75-00-3 Chloroform ND ug/L 0.50 1 11/18/20 16:30 67-66-3 Chloromethane ND ug/L 1.0 1 11/18/20 16:30 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 11/18/20 16:30 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 11/18/20 16:30 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 11/18/20 16:30 96-12-8 Dibromochloromethane ND ug/L 0.50 1 11/18/20 16:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 11/18/20 16:30 106-93-4 Dibromomethane ND ug/L 0.50 1 11/18/20 16:30 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:30 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:30 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 11/18/20 16:30 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 11/18/20 16:30 75-71-8 1, 1 -Dichloroethane ND ug/L 0.50 1 11/18/20 16:30 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 11/18/20 16:30 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 11/18/20 16:30 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 34 aceAnalytical www.pacellbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-4 Lab ID: 92506300004 Collected: 11/16/20 13:05 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B Pace Analytical Services - Charlotte cis- 1,2-Dich loroethene ND ug/L 0.50 1 11/18/20 16:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 11/18/20 16:30 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 11/18/20 16:30 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 11/18/20 16:30 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 11/18/20 16:30 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 11/18/20 16:30 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 16:30 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 11/18/20 16:30 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 11/18/20 16:30 108-20-3 Ethylbenzene ND ug/L 0.50 1 11/18/20 16:30 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 11/18/20 16:30 87-68-3 1sopropylbenzene (Cumene) ND ug/L 0.50 1 11/18/20 16:30 98-82-8 Methylene Chloride ND ug/L 2.0 1 11/18/20 16:30 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 11/18/20 16:30 1634-04-4 Naphthalene ND ug/L 2.0 1 11/18/20 16:30 91-20-3 n-Propylbenzene ND ug/L 0.50 1 11/18/20 16:30 103-65-1 Styrene ND ug/L 0.50 1 11/18/20 16:30 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 16:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 11/18/20 16:30 79-34-5 Tetrachloroethene ND ug/L 0.50 1 11/18/20 16:30 127-18-4 Toluene ND ug/L 0.50 1 11/18/20 16:30 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 11/18/20 16:30 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 11/18/20 16:30 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 11/18/20 16:30 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 11/18/20 16:30 79-00-5 Trichloroethene ND ug/L 0.50 1 11/18/20 16:30 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 11/18/20 16:30 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 11/18/20 16:30 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 11/18/20 16:30 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 11/18/20 16:30 108-67-8 Vinyl chloride ND ug/L 1.0 1 11/18/20 16:30 75-01-4 m&p-Xylene ND ug/L 1.0 1 11/18/20 16:30 179601-23-1 o-Xylene ND ug/L 0.50 1 11/18/20 16:30 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 70-130 1 11/18/20 16:30 17060-07-0 4-13romofluorobenzene (S) 95 % 70-130 1 11/18/20 16:30 460-00-4 Toluene-d8 (S) 99 % 70-130 1 11/18/20 16:30 2037-26-5 2540C Total Dissolved Solids Analytical Method: SM 2540C-2011 Pace Analytical Services -Asheville Total Dissolved Solids 35.0 mg/L 25.0 1 11/19/20 17:27 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Pace Analytical Services -Asheville Total Suspended Solids ND mg/L 2.5 1 11/20/20 18:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 Sample: MW-4 Lab ID: 92506300004 Collected: 11/16/20 13:05 Received: 11/16/20 16:40 Matrix: Water Parameters Results Units PQL DF Prepared Analyzed CAS No. Qual 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 11/25/20 12:49 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2 Rev 2.0 1993 Pace Analytical Services - Asheville Nitrogen, Nitrate ND mg/L 0.040 1 11/17/20 22:16 14797-55-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993 Pace Analytical Services -Asheville Phenol ND mg/L 0.020 1 11/18/2010:40 11/18/2015:00 108-95-2 5310B TOC Analytical Method: SM 531OB-2011 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 11/25/20 21:32 7440-44-0 Date: 12/04/2020 07:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 34 Pace Carolinas Groundwater Sampling Site Checklist PagelofL LOCATION/SrrE C -�y or- Me-rrg n/Opt rl L PROIECTID_ L. {y (}F Mccr-i!J/} M W ,lQrn,A-All M4 f SAMPLE DATE Io ui—c. / n — . FIELD CREW Q M f-w 3 w-Z Mw-1R M _ _ Access cleared into well Access cleared around well Tall grass or weeds -needs mowed Road washed oat/muddy/needs gracfing Fallen tree blocking access .45E�.n +Rv:1� lL�•. �.: tY,i 3'�'w 7, :..'i.'?RtSi ..: ip3 �• "+''- 'a...:. .. a Well found locked / J well found unlocked/No lode ��gg..�� ,y":F: � �, y TYC1i��N� `s�../.i',� "�-ck_-`2�'+ _•6~'f� .P �� Fir: •^.'^'F^ w� .�. ii.' �.x S �' �„ �'t1�J+ � �c �.'�� 'T:�c'. '. YiLFl•1: ;�� tRlef.+i �. `t- -..>r-- - L x ,+ .a., _y. -,�. Lock in good condition Lode rusted needs r lacin O Replaced dameWd lock _ �\ i�'. - •.F . -C'.b-. 'a R _. h! -•��^ r ';}'�3� M � .r ♦'� W.Iv.a.. � . j :i:yYyS� _ } 'w�oasT 11 i ., h � Casing in good condition Damaged casing/still functional DamaCed casingtrepair required __...�...._ :...n..�.:�.:ii�:,,�^J.Qn: ' . :� J� ;Y_ - _.L•Vadnb� :w =_ F io'.+e_.x'iP. ., u��•� �� ....-5�_�,�., _ r.J+l- —- 4 W"Sr-� • r t[1 .,. 1- a 'w - u .' �iG.. iL✓ gam• ....." .:.:,> �Iii`u`.==. _ Pad in good condition^ Minor cracks Major aacks/broken/repair required Undermined/washing out Fire ants around concrete pad Protective bollards a H s iY.�: 1, .. _ •A YL..t:.!. lad Casing in good condition f Damaged casing/still functional Damaged casin re air required Broken hinge on protective lid Wasp nest inside protective Casio Ants inside protective casing_ s Well cap in good condition / o Damaged/needs replacement FISElaced dam ed well cap 00SIN.MFS,t1NfiWELlS _ _s - - •ry � t, '�sfi^t (n� ":i_._. s "� :+09:'` r< ; Vault In good condition Water inside vault Vault bolt holes broken or stripmg Baits stripped Bolts Missing Vault lid cracked or broken - tl., ..4,. a?.ii.F .�4 _ i_r f .L .O'�i J.�' I:(- �1 .\.j +Z',Z�`_� � Tt..r. = Se. Sii � }' 'N1•-a Wel ID tag correct - Wei tag in good condition .+r Well tax missingjrnissinx well ID Well tag amagedfollegible Lacks required information -Driller ig N Lacks required information -Completion date r Lacks required informatiowTotal well depth Lacks required information -Depth to screen Lacks required information -Non ota-P to / ✓ NOTES: aceAnalytical www.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 582325 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3079609 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Arsenic ug/L ND 10.0 11/25/2014:28 Cadmium ug/L ND 1.0 11/25/2014:28 Iron ug/L ND 50.0 11/25/2014:28 Lead ug/L ND 5.0 11/25/2014:28 Manganese ug/L ND 5.0 11/25/2014:28 LABORATORY CONTROL SAMPLE: 3079610 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Arsenic ug/L 250 245 98 85-115 Cadmium ug/L 250 248 99 85-115 Iron ug/L 2500 2490 99 85-115 Lead ug/L 250 250 100 85-115 Manganese ug/L 250 254 101 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3079611 3079612 MS MSD 92505920001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 250 250 256 255 101 101 70-130 0 Cadmium ug/L ND 250 250 265 264 106 106 70-130 0 Iron ug/L 0.94 2500 2500 3630 3580 107 106 70-130 1 mg/L Lead ug/L ND 250 250 265 260 106 104 70-130 2 Manganese ug/L 0.028 250 250 299 295 108 107 70-130 1 mg/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3079613 3079614 MS MSD 92506300003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Arsenic ug/L ND 250 250 265 250 105 99 70-130 6 Cadmium ug/L 1.5 250 250 264 258 105 103 70-130 2 Iron ug/L 1070 2500 2500 3650 3770 103 108 70-130 3 Lead ug/L ND 250 250 256 253 102 101 70-130 1 Manganese ug/L 434 250 250 687 683 101 100 70-130 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 581228 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3074021 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/18/20 12:20 1,1,1-Trichloroethane ug/L ND 0.50 11/18/20 12:20 1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/18/20 12:20 1,1,2-Trichloroethane ug/L ND 0.50 11/18/20 12:20 1,1-Dichloroethane ug/L ND 0.50 11/18/20 12:20 1,1-Dichloroethene ug/L ND 0.50 11/18/20 12:20 1,1-Dichloropropene ug/L ND 0.50 11/18/20 12:20 1,2,3-Trichlorobenzene ug/L ND 2.0 11/18/20 12:20 1,2,3-Trichloropropane ug/L ND 0.50 11/18/20 12:20 1,2,4-Trichlorobenzene ug/L ND 2.0 11/18/20 12:20 1,2,4-Trimethylbenzene ug/L ND 0.50 11/18/20 12:20 1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/18/20 12:20 1,2-Dibromoethane (EDB) ug/L ND 0.50 11/18/20 12:20 1,2-Dichlorobenzene ug/L ND 0.50 11/18/20 12:20 1,2-Dichloroethane ug/L ND 0.50 11/18/20 12:20 1,2-Dichloropropane ug/L ND 0.50 11/18/20 12:20 1,3,5-Trimethylbenzene ug/L ND 0.50 11/18/20 12:20 1,3-Dichlorobenzene ug/L ND 0.50 11/18/20 12:20 1,3-Dichloropropane ug/L ND 0.50 11/18/20 12:20 1,4-Dichlorobenzene ug/L ND 0.50 11/18/20 12:20 2,2-Dichloropropane ug/L ND 0.50 11/18/20 12:20 2-Chlorotoluene ug/L ND 0.50 11/18/20 12:20 4-Chlorotoluene ug/L ND 0.50 11/18/20 12:20 Benzene ug/L ND 0.50 11/18/20 12:20 Bromobenzene ug/L ND 0.50 11/18/20 12:20 Bromochloromethane ug/L ND 0.50 11/18/20 12:20 Bromodichloromethane ug/L ND 0.50 11/18/20 12:20 Bromoform ug/L ND 0.50 11/18/20 12:20 Bromomethane ug/L ND 5.0 11/18/20 12:20 Carbon tetrachloride ug/L ND 0.50 11/18/20 12:20 Chlorobenzene ug/L ND 0.50 11/18/20 12:20 Chloroethane ug/L ND 1.0 11/18/20 12:20 Chloroform ug/L ND 0.50 11/18/20 12:20 Chloromethane ug/L ND 1.0 11/18/20 12:20 cis-1,2-Dichloroethene ug/L ND 0.50 11/18/20 12:20 cis-1,3-Dichloropropene ug/L ND 0.50 11/18/20 12:20 Dibromochloromethane ug/L ND 0.50 11/18/20 12:20 Dibromomethane ug/L ND 0.50 11/18/20 12:20 Dichlorodifluoromethane ug/L ND 0.50 11/18/20 12:20 Diisopropyl ether ug/L ND 0.50 11/18/20 12:20 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 34 aceAnalytical www.pecolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 METHOD BLANK: 3074021 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Ethylbenzene ug/L ND 0.50 11/18/20 12:20 Hexachloro-1,3-butadiene ug/L ND 2.0 11/18/20 12:20 Isopropylbenzene (Cumene) ug/L ND 0.50 11/18/20 12:20 m&p-Xylene ug/L ND 1.0 11/18/20 12:20 Methyl-tert-butyl ether ug/L ND 0.50 11/18/20 12:20 Methylene Chloride ug/L ND 2.0 11/18/20 12:20 n-Butylbenzene ug/L ND 0.50 11/18/20 12:20 n-Propylbenzene ug/L ND 0.50 11/18/20 12:20 Naphthalene ug/L ND 2.0 11/18/20 12:20 o-Xylene ug/L ND 0.50 11/18/20 12:20 sec-Butylbenzene , ug/L ND 0.50 11/18/20 12:20 Styrene ug/L ND 0.50 11/18/20 12:20 tert-Butylbenzene ug/L ND 0.50 11/18/20 12:20 Tetrachloroethene ug/L ND 0.50 11/18/20 12:20 Toluene ug/L ND 0.50 11/18/20 12:20 trans- 1,2-Dichloroethene ug/L ND 0.50 11/18/20 12:20 trans-1,3-Dichloropropene ug/L ND 0.50 11/18/20 12:20 Trichloroethene ug/L ND 0.50 11/18/20 12:20 Trichlorofluoromethane ug/L ND 1.0 11/18/20 12:20 Vinyl chloride ug/L ND 1.0 11/18/20 12:20 1,2-Dichloroethane-d4 (S) % 97 70-130 11/18/20 12:20 4-Bromofluorobenzene (S) % 95 70-130 11/18/20 12:20 Toluene-d8 (S) % 99 70-130 11/18/20 12:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 3074022 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.2 102 60-140 1,1,1-Trichloroethane ug/L 50 45.9 92 60-140 1,1,2,2-Tetrachloroethane ug/L 50 47.0 94 60-140 1,1,2-Trichloroethane ug/L 50 47.3 95 60-140 1,1-Dichloroethane ug/L 50 43.7 87 60-140 1,1-Dichloroethene ug/L 50 48.1 96 60-140 1,1-Dichloropropene ug/L 50 44.9 90 60-140 1,2,3-Trichlorobenzene ug/L 50 50.8 102 60-140 1,2,3-Trichloropropane ug/L 50 47.9 96 60-140 1,2,4-Trichlorobenzene ug/L 50 53.7 107 60-140 1,2,4-Trimethylbenzene ug/L 50 48.7 97 60-140 1,2-Dibromo-3-chloropropane ug/L 50 55.5 111 60-140 1,2-Dibromoethane (EDB) ug/L 50 49.7 99 60-140 1,2-Dichlorobenzene ug/L 50 51.9 104 60-140 1,2-Dichloroethane ug/L 50 41.6 83 60-140 1,2-Dichloropropane ug/L 50 45.5 91 60-140 1,3,5-Trimethylbenzene ug/L 50 49.6 99 60-140 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 34 aceAnalytical www.pecolibs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 LABORATORY CONTROL SAMPLE: Parameter 3074022 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,3-Dichlorobenzene ug/L 50 52.0 104 60-140 1,3-Dichloropropane ug/L 50 49.1 98 60-140 1,4-Dichlorobenzene ug/L 50 51.9 104 60-140 2,2-Dichloropropane ug/L 50 47.7 95 60-140 2-Chlorotoluene ug/L 50 49.6 99 60-140 4-Chlorotoluene ug/L 50 49.0 98 60-140 Benzene ug/L 50 44.7 89 60-140 Bromobenzene ug/L 50 49.9 100 60-140 Bromochloromethane ug/L 50 45.8 92 60-140 Bromodichloromethane ug/L 50 46.5 93 60-140 Bromoform ug/L 50 49.6 99 60-140 Bromomethane ug/L 50 54.0 108 60-140 Carbon tetrachloride ug/L 50 48.2 96 60-140 Chlorobenzene ug/L 50 48.5 97 60-140 Chloroethane ug/L 50 36.9 74 60-140 Chloroform ug/L 50 44.2 88 60-140 Chloromethane ug/L 50 36.8 74 60-140 cis-1,2-Dichloroethene ug/L 50 43.4 87 60-140 cis- 1, 3-Dichloropropene ug/L 50 48.8 98 60-140 Dibromochloromethane ug/L 50 52.9 106 60-140 Dibromomethane ug/L 50 50.4 101 60-140 Dichlorodifluoromethane ug/L 50 36.0 72 60-140 Diisopropyl ether ug/L 50 42.7 85 60-140 Ethylbenzene ug/L 50 47.4 95 60-140 Hexachloro-1,3-butadiene ug/L 50 44.4 89 60-140 Isopropylbenzene (Cumene) ug/L 50 50.9 102 60-140 m&p-Xylene ug/L 100 96.7 97 60-140 Methyl-tert-butyl ether ug/L 50 45.4 91 60-140 Methylene Chloride ug/L 50 41.2 82 60-140 n-Butylbenzene ug/L 50 49.9 100 60-140 n-Propylbenzene ug/L 50 49.4 99 60-140 Naphthalene ug/L 50 54.0 108 60-140 o-Xylene ug/L 50 48.5 97 60-140 sec-Butylbenzene ug/L 50 49.2 98 60-140 Styrene ug/L 50 49.4 99 60-140 tert-Butylbenzene ug/L 50 42.9 86 60-140 Tetrachloroethene ug/L 50 50.1 100 60-140 Toluene ug/L 50 45.5 91 60-140 trans-1,2-Dichloroethene ug/L 50 44.1 88 60-140 trans-1,3-Dichloropropene ug/L 50 48.8 98 60-140 Trichloroethene ug/L 50 48.9 98 60-140 Trichlorofluoromethane ug/L 50 41.6 83 60-140 Vinyl chloride ug/L 50 37.2 74 60-140 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 96 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3074023 MS 92506250001 Spike Parameter Units Result Conc. MSD Spike Conc. 3074024 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 21.3 22.1 107 110 60-140 3 1,1,1-Trichloroethane ug/L ND 20 20 20.5 20.9 103 104 60-140 2 1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.8 19.4 94 97 60-140 3 1,1,2-Trichloroethane ug/L ND 20 20 19.2 19.9 96 99 60-140 3 1,1-Dichloroethane ug/L ND 20 20 19.2 19.5 96 97 60-140 1 1,1-Dichloroethene ug/L ND 20 20 22.3 22.0 111 110 60-140 1 1,1-Dichloropropene ug/L ND 20 20 19.7 19.7 99 98 60-140 0 1,2,3-Trichlorobenzene ug/L ND 20 20 18.4 18.9 92 94 60-140 3 1,2,3-Trichloropropane ug/L ND 20 20 18.8 20.0 94 100 60-140 6 1,2,4-Trichlorobenzene ug/L ND 20 20 19.3 20.1 96 100 60-140 4 1,2,4-Trimethylbenzene ug/L ND 20 20 20.2 20.7 101 103 60-140 2 1,2-Dibromo-3-chloropropane ug/L ND 20 20 20.4 21.1 102 105 60-140 3 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.0 21.2 100 106 60-140 6 1,2-Dichlorobenzene ug/L ND 20 20 20.1 20.9 101 105 60-140 4 1,2-Dichloroethane ug/L ND 20 20 17.6 17.5 88 87 60-140 1 1,2-Dichloropropane ug/L ND 20 20 19.3 19.5 97 98 60-140 1 1,3,5-Trimethyl benzene ug/L ND 20 20 20.8 21.5 104 107 60-140 3 1,3-Dichlorobenzene ug/L ND 20 20 20.4 21.1 102 105 60-140 3 1,3-Dichloropropane ug/L ND 20 20 20.0 20.5 100 103 60-140 2 1,4-Dichlorobenzene ug/L ND 20 20 20.4 21.0 102 105 60-140 3 2,2-Dichloropropane ug/L ND 20 20 20.1 20.2 100 101 60-140 1 2-Chlorotoluene ug/L ND 20 20 20.7 21.2 104 106 60-140 2 4-Chlorotoluene ug/L ND 20 20 20.2 20.8 101 104 60-140 3 Benzene ug/L ND 20 20 19.4 19.9 97 99 60-140 2 Bromobenzene ug/L ND 20 20 20.9 21.3 104 106 60-140 2 Bromochloromethane ug/L ND 20 20 19.2 19.3 96 97 60-140 0 Bromodichloromethane ug/L ND 20 20 19.8 20.2 99 101 60-140 2 Bromoform ug/L ND 20 20 19.1 19.9 96 100 60-140 4 Bromomethane ug/L ND 20 20 24.6 24.6 123 123 60-140 0 Carbon tetrachloride ug/L ND 20 20 21.1 21.2 105 106 60-140 1 Chlorobenzene ug/L ND 20 20 20.4 21.2 102 106 60-140 4 Chloroethane ug/L ND 20 20 19.4 19.3 97 97 60-140 0 Chloroform ug/L ND 20 20 19.4 20.4 97 102 60-140 5 Chloromethane ug/L ND 20 20 17.5 17.6 87 88 60-140 1 cis- 1,2-Dichloroethene ug/L ND 20 20 18.7 18.9 94 95 60-140 1 cis- 1, 3-Dich loropropene ug/L ND 20 20 19.3 20.6 97 103 60-140 6 Dibromochloromethane ug/L ND 20 20 21.1 21.7 106 108 60-140 3 Dibromomethane ug/L ND 20 20 21.1 22.0 105 110 60-140 4 Dichlorodifluoromethane ug/L ND 20 20 15.7 15.5 79 78 60-140 1 Diisopropyl ether ug/L ND 20 20 17.5 17.6 87 88 60-140 1 Ethylbenzene ug/L ND 20 20 20.3 20.8 102 104 60-140 2 Hexachloro-1,3-butadiene ug/L ND 20 20 16.8 17.8 84 89 60-140 6 1sopropylbenzene (Cumene) ug/L ND 20 20 21.4 22.3 107 112 60-140 4 m&p-Xylene ug/L ND 40 40 40.9 41.9 102 105 60-140 2 Methyl-tert-butyl ether ug/L ND 20 20 18.3 18.4 91 92 60-140 1 Methylene Chloride ug/L ND 20 20 17.1 17.3 85 86 60-140 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3074023 3074024 MS MSD 92506250001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua] n-Butylbenzene ug/L ND 20 20 19.5 20.5 97 102 60-140 5 n-Propylbenzene ug/L ND 20 20 21.0 21.5 105 107 60-140 2 Naphthalene ug/L ND 20 20 18.4 18.9 92 95 60-140 3 o-Xylene ug/L ND 20 20 20.4 20.6 102 103 60-140 1 sec-Butylbenzene ug/L ND 20 20 20.6 21.3 103 106 60-140 3 Styrene ug/L ND 20 20 19.6 20.4 98 102 60-140 4 tent-Butylbenzene ug/L ND 20 20 18.5 19.1 93 95 60-140 3 Tetrachloroethene ug/L ND 20 20 21.5 22.5 107 112 60-140 4 Toluene ug/L ND 20 20 19.7 20.2 99 101 60-140 2 trans-1,2-Dichloroethene ug/L ND 20 20 19.6 19.4 98 97 60-140 1 trans-1,3-Dichloropropene ug/L ND 20 20 19.5 19.4 98 97 60-140 1 Trichloroethene ug/L ND 20 20 21.1 21.4 106 107 60-140 1 Trichlorofluoromethane ug/L ND 20 20 20.8 20.5 104 103 60-140 1 Vinyl chloride ug/L ND 20 20 16.9 16.7 84 84 60-140 1 1,2-Dichloroethane-d4 (S) % 101 101 70-130 4-Bromofluorobenzene (S) % 98 98 70-130 Toluene-d8 (S) % 97 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 34 aceAnalytical www.pacellbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 581685 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003 METHOD BLANK: 3076673 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/19/20 17:33 LABORATORY CONTROL SAMPLE: 3076674 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids mg/L 250 246 99 90-110 SAMPLE DUPLICATE: 3076675 92506369005 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 122000 129000 6 SAMPLE DUPLICATE: 3076676 92506293001 Dup Parameter Units Result Result RPD Qualifiers Total Dissolved Solids mg/L 136 143 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 34 aceAnalytical www.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 581687 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300004 METHOD BLANK: 3076678 Matrix: Water Associated Lab Samples: 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Dissolved Solids mg/L ND 25.0 11/19/20 17:27 LABORATORY CONTROL SAMPLE: 3076679 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 3076680 Parameter Units Total Dissolved Solids mg/L Spike LCS Conc. Result 250 242 92506300004 Dup Result Result 35.0 33.0 SAMPLE DUPLICATE: 3076681 92506314010 Dup Parameter Units Result Result Total Dissolved Solids mg/L 118 120 LCS % Rec % Rec Limits Qualifiers 97 90-110 RPD Qualifiers 6 RPD Qualifiers 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 34 aceAnalytical www.pacollbs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 582001 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3078278 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 11/20/20 18:07 LABORATORY CONTROL SAMPLE & LCSD: 3078279 3078429 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD, RPD Qualifiers Total Suspended Solids mg/L 249 242 240 97 96 90-110 1 25 SAMPLE DUPLICATE: 3078280 92507041001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 278 264 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 34 c � aceAnaljftal www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 582544 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002 METHOD BLANK: 3080509 Matrix: Water Associated Lab Samples: 92506300001, 92506300002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/25/20 11:50 LABORATORY CONTROL SAMPLE: 3080510 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080511 3080512 MS MSD 92507461001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.27 5 5 4.9 4.9 92 92 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080513 3080514 MS MSD 92505432001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 2.9 5 5 7.5 7.5 92 92 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 34 aceAnalytical www.pacolabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 582545 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300003, 92506300004 METHOD BLANK: 3080515 Matrix: Water Associated Lab Samples: 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 11/25/20 12:34 LABORATORY CONTROL SAMPLE: 3080516 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 4.9 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080517 3080518 MS MSD 92506701003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.13 5 5 5.0 5.0 98 98 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080519 3080520 MS MSD 92506300003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L ND 5 5 4.7 4.7 93 93 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 34 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 581057 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3073418 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.040 11/17/20 22:00 LABORATORY CONTROL SAMPLE. 3073419 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073428 3073429 MS MSD 92506265001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.45 1.5 1.5 2.0 2.0 102 101 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073430 3073431 MS MSD 92506265002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.23 1.5 1.5 1.7 1.7 99 98 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 34 aceAnalytical www.pacolobs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 581160 Analysis Method: EPA 420.4 Rev 1.0 1993 QC Batch Method: EPA420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3073672 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phenol mg/L ND 0.020 11/18/2014:30 LABORATORY CONTROL SAMPLE: 3073673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenol mg/L 0.05 0.049 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3073674 3073675 MS MSD 92506300001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phenol mg/L ND 0.05 0.05 0.047 0.051 95 102 90-110 7 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 34 r aceAnalytical www.pactiabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 QC Batch: 582634 Analysis Method: SM 531OB-2011 QC Batch Method: SM 531OB-2011 Analysis Description: 5310B TOC Laboratory: Pace Analytical Services - Asheville Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 METHOD BLANK: 3080839 Matrix: Water Associated Lab Samples: 92506300001, 92506300002, 92506300003, 92506300004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 11/25/20 14:23 LABORATORY CONTROL SAMPLE: 3080840 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.6 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080841 3080842 MS MSD 92506927001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 1.8 25 25 26.9 27.0 100 101 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3080843 3080844 MS MSD 92506265003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L ND 25 25 25.7 25.7 101 101 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 34 aceAnaljftal www.pacelobs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALIFIERS Project: City of Marion MWs_Nov 2020 Pace Project No.: 92506300 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/04/2020 07:53 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 34 aceAnalytical www.pscelabs.com Pace Analytical Services, LLC 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: City of Marion MWs_Nov 2020 92506300 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92506300001 MW-1R 92506300002 MW-2 92506300003 MW-3 92506300004 MW-4 92506300001 MW-1 R EPA 200.7 Rev 4.4 1994 582325 EPA 200.7 Rev 4.4 1994 582527 92506300002 MW-2 EPA 200.7 Rev 4.4 1994 582325 EPA 200.7 Rev 4.4 1994 582527 92506300003 MW-3 EPA 200.7 Rev 4.4 1994 582325 EPA 200.7 Rev 4.4 1994 582527 92506300004 MW-4 EPA 200.7 Rev 4.4 1994 582325 EPA 200.7 Rev 4.4 1994 582527 92506300001 MW-1R SM 6200B 581228 92506300002 MW-2 SM 6200B 581228 92506300003 MW-3 SM 6200B 581228 92506300004 MW-4 SM 6200B 581228 92506300001 MW-1R SM 2540C-2011 581685 92506300002 MW-2 SM 2540C-2011 581685 92506300003 MW-3 SM 2540C-2011 581685 92506300004 MW-4 SM 254OC-2011 581687 92506300001 MW-1R SM 254OD-2011 582001 92506300002 MW-2 SM 2540D-2011 582001 92506300003 MW-3 SM 254OD-2011 582001 92506300004 MW-4 SM 2540D-2011 582001 92506300001 MW-1 R EPA 350.1 Rev 2.0 1993 582544 92506300002 MW-2 EPA 350.1 Rev 2.0 1993 582544 92506300003 MW-3 EPA 350.1 Rev 2.0 1993 582545 92506300004 MW-4 EPA 350.1 Rev 2.0 1993 582545 92506300001 MW-1R EPA 353.2 Rev 2.0 1993 581057 92506300002 MW-2 EPA 353.2 Rev 2.0 1993 581057 92506300003 MW-3 EPA 353.2 Rev 2.0 1993 581057 92506300004 MW-4 EPA 353.2 Rev 2.0 1993 581057 92506300001 MW-1R EPA 420.4 Rev 1.0 1993 581160 EPA 420.4 Rev 1.0 1993 581220 92506300002 MW-2 EPA 420.4 Rev 1.0 1993 581160 EPA 420.4 Rev 1.0 1993 581220 92506300003 MW-3 EPA 420.4 Rev 1.0 1993 581160 EPA 420.4 Rev 1.0 1993 581220 92506300004 MW-4 EPA 420.4 Rev 1.0 1993 581160 EPA 420.4 Rev 1.0 1993 581220 92506300001 MWA R SM 531OB-2011 582634 92506300002 MW-2 SM 531OB-2011 582634 92506300003 MW-3 SM 531 OB-2011 582634 92506300004 MW-4 SM 531OB-2011 582634 Date: 12/04/2020 07:53 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 34 b Document Name: F1eId data Sheet HCC"AtV134kal' V ¢•e w Page: I of •, y' Document Numb& F-CAR-FLD-001-rev,03 Issuing Authority: Pace Huntersvifl� r Office . Field Data Sheet Clienf: 6i4y Ma Mo .-1 a R Location: Mo, ri o/t, f.16 Project #: L +Y r aAL& on A� Wltwt; e,A,tcta( nov �02�0 *r,..,..... ' A A4=;i• Mamnlorfal• M13 P. tCo Name and Affiliation (Inspector): 'N /�• V Well Information Well ID• Mw-((z Well Diameter: 1 n Total Well Depth: 0, G ft Static Water Level: 2. P- •0-10 'ft Height of Water Column:.'l lt ft Well Locked: Date: I t ' La LO-' By: 00, NO / Construction: VC teel/Stainless Steel) Multi Factor*: C' I b -3 1(Radius/12)2 x 3,14 x 7.481. Casing Volume: 6. SON gallons. Cal, 3 Volumes: t rA ,7 7 gallons Pump Intake: ft Purge Information_ Date Purged: i I / 6 ./ 'Z Start: 1 lA Finish: 12 0 5 Purge Rate: 100 i 1 �i /A; Purging Method: P 2.r i5 4al t i 6 P,t M P Total Volume Purged: S °_O (gallons�(L) Sannuling Information Date Collected: i i / b / •t a Time Collected: ( Z 10 (amlinn) Sampling ui went Used: t'4^ i 5 t- N' t• L u MP Instrument ID: T O h b o g� � � Bottle Type - , Preservation Analysis Required Me+o.r S, Tot•; A(Am, 0.-t,-o,_Ae �ToI�� pl.eI-) Tb5, M \/o G5 Sample Temp (°C): 1 ? Time: (Z ` Turbidity (ntu): 6 Time: I Diss Oxy (mg/L): Time: t_ Fe 2+ mg/L: - Time: �-- Specific Cond. (6). ZZ • 1 Time: t Z l /3 Res. Cl (mg/L)/(µg/L) - — Time, Sar tple pH (s.u.): (9 Q Time: �-��-Odor: N o'\ P- Timer_ ReDox (mV): r- Time: Appearance: L / Time: ReDox (EH value):YSI ProPlus +200=V � GeneraV/ Veather Observations: . Other: Time: 1 y/rainy) Temp.&!(°F) Wind Q:: (mph) Sampler Signature: Ryon g y a`S Date: ) 1 ✓' / Zo Stabilization Test Time Purged Temp. o -( C) Diss Oxy, (mg/L) Spec. Cond. (US) pH (s.u.) ReDox (mV) Turbidity (ntU) oume removed (gallo mis Water level (ft) Other 1-7, 6.0 ---- Q. 5 s eo0 5+..+, t N� - �3 --- zi.g7 za .1 a _� x _5 _.(3.7 .- . 1._........ZZ:2, . ,a_...� 3- ao_ Document Name: Field data Sheet Document Number: F-CAR-FLD-001-[ev.03 ---- Page: 1 ofl .uthority: Pace Huntersvill Office Field Data Sheet Name- wid AffiliatipnGamplerj(g7• k M R Q D�/_ e Name and Affiliation (Inspector):_ Well Information Well ID: /A Ar ' Z Well Diameter: ' Total Well Depth: 3a. - 0 ft Static Water Level: 4639 . ft Height of Water Column: 'L I.51 ft Well Locked: It YES Construction: Project #: 4 -Id Data FgieefRovie Date: it - Lo ' O / Fluslun`r ) eel/Stainless Steel) Multi Factor*: (*(Radius/12)20.14x7.481 Casing Volume: 3.5 gallons. Cal. 3 VoIumes: l . S `L gallons Pump Intake: '0`' � ft By: W Purge Information Date Purged: < < / % . / . Z Start: 19 Finish: 10 TO Purge Rate: I0 o to Purging Method:_P U M :t Total Volume'Purged: 1 5� (gallon Sainvline Information Date Collected: 1 /L6, / "z 0 Time Collected: 10 5 am tn) Sampling Equipment Used: ft -i Sfa.14 L Qom{ rn 12 _ Instrument iD -y 4 O S6 Zi✓b 98 Bottle Type Preservation Analysis Required N;t�,,,l¢ , tonal i�er,ori TO, T5 ) Sample Temp (°C): . 4 Time: 19 i{ 5 Turbidity (ntu); ` 3 Timer. I S Digs Oxy (mg/L): Time: Fe 2+ mg/L:'-'�- Specific Cond. (uS): "2w. Q.O Time: I OR S Res. Cl (mg/L)/(µg/L): -----Time:. Sample pH (s.u.): Time: +_ Odor: .. 4z t w r Time; 1° K 5 ReDox (mV): Time: z=- Appearance: Time: ReDox (EH value):YSI ProPlus +200trtV Other: �' Time: General/Weather Observations: . sunny oudy/rainy) Tem4Sp. ('F) Wind�(mph) Sampler Signature: (Z%j a jj Y S ate: 11 / 2 '7 Stabilization Test , Time Purged Temp. -CC) Digs Oxy. (mg/L) Spec. S) pH (s.u.) ReDox (mV) Turbidity (ntu.) oume reinov (gallons/ ls/ L Water level (ft) Other o 0 D D u ry. .1-. ZH.L 4-- 5 5�4 16,10 i.� D i'1.� ----- zQq.1 b o, 1 b.'7 �. ace.Awllltleal' {1r he Mal'.1 A Document Name: Field data Sheet Document [dumber. F•CAR-FLD-001-rev.03 Field Data Sheet • lM0.t-i0n.. 1�� Page: i of - - wthority: Pace Hunterwiile Quality Office :;+7 or rt-,r:o (NW 59m; AMtw N9V.LA2,,o AnReld pm it Name and Affiliation (Inspector):. t4 Well Information Date: +' . ? u • u' By: Well ID: r"w - 3 Well Locked: YES NO / Flushtnount) ' Well Diameter: ' ^ Construction: PVC teel/Stainless Steel) Total Well Depth: SO., fl Z ft Multi Factor*:0,.(6 3 r(Radius/12)2x3.14x7.481 Static Water Level: 30do i ft Casing Volume: 3 gallons ` Height of Water Column: t 1.3 ) ft Cal. 3 Volumes: " g " �I 6 gallons Pump Intake: ' ' 4 O ft Puree Infortnati'on Bate Purged: l 1 / )1? ./_ Start : aq 3 Finish: O q 5'0 Purge hate: SrJ M1 fi Purging Method: V- r . 94\4p. P u M 3 Total Volume' Purged: —�-a (4 (gallon ) Smnvline Information Date Collected:. M � J�/ 2 o Time Collected:- 01 S epm) Sampling Equipment Used: l' s-r • 0-4t 4 kA- M P Instrument ID: K S L OS 6 0L, TV tv 6 �33 Bottle Type Preservatign Analysis Required k-koj 5, l `JCt VQLJ vleaagT_ r.�i L-La .— Sample Temp (oq, Time: 0015 h Turbidity (ntu): �Time: 0 S Dins Oxy (mg/L): Time: Fe 2+ mg/L: Specific Cond. (us): Time: OA y Res. Cl (mg/L)&g/L): Time:. �— Sample pH (s.u.): K . O Time: ` Odor: MaTime: of S S ReDox (mV): Time: '—r Appearance: S I , !' (,oy dL,/ Time: ReDox (EH value):YSI ProPlus +200mV -�Other: Time: General/Weather Observations: (sunny oudy/rainy) Temp.� z("F) Wind�(Mph) /� Z Sampler Signature: �..i f�l\ � � c`'"% Date: l I / Stabilization Test Time Purged Temp. (C) Disc Oxy. (mg/L) ConSpy } pH (s.u.) ReDox (mV) Turbidity (ntu) oume remov (gallons m1S/ Water level (ft) Other Q 5 10 ---Lk4 4 . g 4 So `� V - C3. �Q $ 01y\q �� . ---- yS7 S . o ---- 3 S o0 3D.,p . 0R't P-7 a 4. - D. -7 '75 d. 15 1— --ata n ,. aceA=441c&A Document Name: Field data Sheet Document Number. F-CAR-FLD-001-rev.03 Authority: Pace Huntersvill Office Field Data Sheet Client"4Y o c /M`r Location: M k-1� r L JV C Pzoject RA a too- I-2 Name and Affiliation (Inspector):_- A Date: PI-ab Well Information Well ID: M W : . Well Locked: (YES / O / Flushmount ) Well Diameter: Construction: PVC eel/Stainless Steel) Total Well Depth: S. ft Multi Factor*; DDI l*(Radius/12)2x3.140.48J. Static Water Level: H b 6. 1 ft Casing Volume: �' gallons Height of Water Column: 17 S ft Cal. 3 Volumes: 9� gallons Pump Intake: ''� � 3 ft on Mw5a-"iA4nun4 Nol.2oao By: W S Purge Information Tate Purged: l I / 1 6 ./ . Zn Start :1 L 45 Finish:_ Purge Rate: 1001n15/ Purging Method: Pfr'i If o.Li ,'G PA ME Total Volume Purged: 1500 (gallons Samylina Information Date Collected:,J._/JL/'10_ Time Collected: 130 5 (a ut) SamplingEquipment Used: Nr-i i-zeJ4,*C- P I M P- Instrument ID: 5 5 b 7�w o8 3 Bottle Type Preservatimn Analysis Required r¢ ►ar o (-,-Am At- , rS 5 V�r.� Sample Temp (°C): W 7' Time. 1305 Turbidity (ntu): Time: Diss Oxy (mg/L): "�"� Time: Fe 2+ mg/L: — Time:. --� Specific Cond. (uS): 3 Time:. l 30 5 Res. Cl (mg/L)/(µg/L): Time:. Sample pH (s.u.): C' ' Time: l Odor: N 13n12 Time: 1305 ReDox (m.V): Time: Appearance: L lea Time: ReDox (EH value):YSI ProPlus +200MV - Other: Time: --� General/Weather Observations: unny/ loudy/rainy) Temp. 5 O� (°F) Wind 5- iO(mph) Sampler Signature: Rytx n 8)1 *`6 Date: 1 Stabilization'test Time Purged Temp. .(q Diss Ozy. (mg/L) Spec. Cond. pH (s.u.) ReDox (mV) Turbidity (ntu) oume removed (gallons Water level (ft) Other 5 1,000. 13ob �w.� �-- S 5,1 Pace Carolinas Groundwater Sampling Site Checklist PageJ4 LOCATiON/srFE C 1'-kt Or- r- , on tll e- PROJECT ID: ( .4 SAMPLE DATE 11/47/20 WEATHER L FIELD CIRE AW-3 M%-- Z. MW-1 K XV-141 I I—'— p. Access cleared into weft Access cleared around well 7 Tall grass or weeds -needs mowed Road washed out/muddy/needs gratFing Fallen tree blocking access Well found tacked well found unlocked/No lock Lock in good condition Lock rusted/needs replacinL Replaced damaged lock x, Casing in jpod condition Damaged casine/still furxtional 0amaCed casing/repair required - .,7 4 -5M 5 MV M i Pad in good condition Minor racks Mamor cracks/broken/repair required Undermined/washing out Fire ants around concrete pad Protective bollards I Casing in good condition Damaged casing/still functional Damaged casiniVrepair required Broken hinge on protective lid Was nest inside protective czslng Ants 1; Ide protective casing Well cap in good condition 000, Damaged/needs replacement - B!pjaced damaged well caP 77 - Vault In good condition .001— Water inside vault Vault bolt holes broken or stripped Bolts sM ed Bolts missing lVault lid cracked or Woke j, WeM ID tag correct wel tag In good condition Well tag missing(missing well 10 Well to dam aged[die Mble Lacks (equired information -Driller reg N Lacks required information -Completion date Lacks required information -Total well depth 1 Lacks required information-oepth to screen IoA Lacks required information -Non poWe tag ..0 - a NOTES: Sample Condition Upon Recei t(SCUK) 'G M ,7ce/l1aIyt1CdI Document No.: Issuing Authority: F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ( Raleigh ❑ Mechanicsville[] Atlanta[] Kernersville❑ : Client Name: Project #: WO# : 92506300 , Cdurier-. Ex [:]UPS OUSPS ❑Client II'II' I IIIII IIII III III ❑ commercial (Apace [-]Other: 92505300 Custody Seal Present? ❑Yes []No Seals intact? ❑Yes [JNo Date/Initials Person Examining Contents: (` Packing Material: 58ubble Wrap [Bubble Bags []None ❑ Other Biological Tissue Frozen? ❑Yes []No ZJN/A Thermometer: [SWet ❑Blue ❑None [AIR Gun 10: 92TO61 Type of Ice: Correction Factor: Cooler Temp: Add/Subtract VC) 0.0 Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): v ' has begun USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, � _. u�....:i 4 o.'e.fn Rirnli F-lYe5 I INo yes uimo - -- Comments/Discrepancy: Chain of Custody Present? Yes QNo ❑N/A 1. Samples Arrived within Hold Time? O Yes ONo N/A 2. Short Hold Time Analysis 02 hr.)? Des No N/A 3. E)LNg 0NIA 4. Sufficient Volume? linYes ❑No N/A S. Correct Containers Used? -Pace Containers Used? Yes 4 Yes [-]NO ONo ❑N/A ❑N/A 6. Containers Intact? Yes ONo ❑N/A 7. Dissolved analysis: Samples Field Filtered? Oyes No N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix:7 Headspace in VOA Vials (>5-6mm)? (Yes ,v ❑y7][]No ❑No [-]N/A (&N/A 9. 10. Trip Blank Present? TripBlank CustodySeals Present? ❑Yes yes ❑No ❑No [ZN/A N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Field Data Required? Des ❑No Project Manager SCURF Review: Date: l �U Project Manager SIRF Review: /�� Date: - — ------------Paq '12nf 34 m 3 n 0 t ro v O 'c m a S c a � s a D o C N m o i � A rF I O o � s 4 Q � rz t9 T f9 e C, E a u LA u CU fO z �A r n o c ii a o v m n m z TJ m � i a� 0 0 ro 0 � r d DD �! iT U1 A W Iternp SMU-125 mL Plastic Unpreserved (N/A) (0-) BP3U-250 ml Plastic Unpreserved (N/A) BPZU-500 ml Plastic Unpreserved (N/A) BP1U-1 liter Plastic Unpreserved (N/A) �~ CFO-', mL Plastic H2SO4 (PH < 2) (CV) 8P3N-250 mL plastic HNO3 (pH < 2) BP4Z-125 mL Plastic IN Acetate & NaOH (>9) BP4C-125 mL Plastic NaDH IpH > 12) (Cl-) j WGFU-Wide-mouthed Glass jar Unpreserved AG1U-1 liter Amber Unpreserved (N/A) (Cl-) AG1H-1 liter Amber HCI (pH < 2) ' i AG3U-250 mL Amber Unpreserved (N/A) (CI-) AG1S-1 titer Amber H2504 (pH < 2) AG3S-;ISO mL Amber HZS04 (PH < 2) AG3A(DG3A)-250 mL Amber NH40 (N/A)(CI-) `- DG9H40 mL VOA HCI (N/A) V1G9T-00 mL VOA Na25203 (N/A) VGSU-4U mL VOA Unp INN — — DGBP-40 mL VOA H3PO4 (N/A) VOAK (6 vials per kit)-5035 ¢it (N/A) V/GK 13 vials per kit)-VP"/Gas kit IN/A) SPS7-12S mL Stenle Plastic (N/A - tab) SPZT-2SD mL Sterile Plastic (N/A - lab) 8P3A•250 mL Plastic (NH2)ZS04 (9.3-93) AGOU-100 mL Amber Unpreserved vials (N/A) VSGU 20 mL Scintillation vials (N/A) DG9U-40 ml Amber Unpreserved vials (N/A) )1 7CHAIN-OF-CUSTODY / Analytical Request Document eCeAn�flr�l The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. www Heron co. >ection A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page : 1 Of 1 :ompany Cdy of Marion Report To'. Tim Horton Attenhen. Nddress_ 3982 NC Hwy 226 South Copy To Company Name. Nanon, NC 28752 Address. Regulatory Agency °malt. thorton marionnc arg Purchase Order # Pace Quote. -hone. IFax Project Name. City of Marton MWs NOV 2020 Pace Project Manager, torn patton .pacelabs.com, State I Location Requested Due Date: Project #: Pace Profile* 13150 R uested Ana is Filtered !N _ Z MATRIX CODE — OU COLLECTED Z Preservatives >- D—kmg Winer DW ° I, O Wain WT Waste Weter u U N-1— P SAMPLE ID sows0d sL On OL �_ START END o m ~ } One Character per box. W'Pe WP W w p, Z V O (A,7- 0-9 1, -) Au AR o a < y ,,. in ^ g m Sample Ids must be unique T,,.- Ts = w p` m O 14 c ~ 1E W O w OZ % �So63oo F- — N DATE TIME DATE TIME ¢ N a ca S x U x z m z i t O m O r E m z L a rNi� F- O > m 1 MW-1R WT V mwz alo t3 3 t (ti I 3 I X X X X X X X X 6w lr- 1e 1+5 13 3 2 14 131 00-L- 2 MW-2 wT X X X X X X X X 3 2 I $ MW-3 WT X X X X X X X X 13a5 l?► ' 4 MW-4 WT X X X X X X X X 5 b 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY rAFFILIATiON DATE TIME ACCEPTED BY / AFFILIATION DATE TIME SAMPLE CONDITIONS Metals = As, Cu. Fe, Pb, Mn A AO. SAMPLER NAME AND SIGNATURE � U c c o v r PRINT Name of SAMPLER: CL o SIGNATURE of SAMPLER: 74� p y _ ` fJ oL./ DATE Signed: / f w m u 2 min } oz_ E uZ to � �— K u �UO} C