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Home My WebLink AboutNC0000272_Compliance Insp. Toxicity_20181228 DocuSign Envelope ID:CF5621E7-B140-4571-A887-468AAOE85F39 RDY COOPER NORTH CAROLINA Gassrraar Environmental Quallty MICYL EL S. REGA-W .]BCYRIa--N LL-TL?�CLZLPEPPF-R Intsrbn Diraefar December 28, 2018 Jacob Trantham Blue Ridge Paper Products Inc PO Box 4000 Canton, NC 28716 SUBJECT: Bioassay Compliance Inspection Report Canton Mill NPDES WW Permit No. NC0000272 Haywood County Dear Permittee: On 12/11/2018 & 12/13/2018, a Bioassay Compliance Inspection of the Evergreen Packaging WWTP was conducted. This inspection was conducted to split samples with the facility for the chronic Ceriodaphnia dubia toxicity tests. All samples resulted in a pass and were found compliant. The assistance of Mr. John Pryately during this event was appreciated. There were no significant issues or findings noted during the inspection and therefore, a response to this inspection report is not required. If you should have any questions, please do not hesitate to contact me with the Water Quality Regional Operations Section in the Asheville Regional Office at 828-296-4500 or via email at tim.heim@ncdenr.gov. Sincerely, by: ED11"li,111 627B'D27�37�. (For) G. Landon Davidson, P.G., Regional Supervisor Water Quality Regional Operations Section Asheville Regional Office Division of Water Resources, NCDEQ ATTACHMENTS Ec: WQS-ARO Server LF G:\WR\WQ\Haywood\Wastewater\Industrial\Blue Ridge Paper 00272\Inspections\2018 Tox Split\Tox Split 2\20181228_NC0000272_CBI Ltr.Docx ��Q-� North Carolina Department of Environmental Quality I Division of Water Resources 2090 U.S.70 Highway,Swannanoa,NC 28778 828-296-4500 DocuSign Envelope ID:CF5621E7-B140-4571-A887-468AAOE85F39 United States Environmental Protection Agency Form Approved. EPA Washington,D.C.20460 OMB No.2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding(i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 2 15 1 3 I NCO000272 I11 12 I 18/12/13 I17 18 L Q j 19 L G j 201 21111I I I I I I I II I I I I I I I I I I I I I I I I I I I I I I I II I I I I I f6 Inspection Work Days Facility Self-Monitoring Evaluation Rating B1 CA ----------------------Reserved------------------- 671 70 IJ 71 [ ] 72 LIJ N I 73 L_LJ74 751 I I I I I I I80 Section B: Facility Data Name and Location of Facility Inspected(For Industrial Users discharging to POTW,also include Entry Time/Date Permit Effective Date POTW name and NPDES oermit Number) 09:OOAM 18/12/13 10/07/01 Canton Mill 175 Main St Exit Time/Date Permit Expiration Date Canton NC 28716 10:OOAM 18/12/13 15/06/30 Name(s)of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data John J Pryately/ORC/828-707-7976/ Name,Address of Responsible Official/Title/Phone and Fax Number Contacted Derric Brown,PO Box 4000 Canton NC 28716//828-646-2318/ No Section C:Areas Evaluated During Inspection(Check only those areas evaluated) Self-Monitoring Program 0 Effluent/Receiving Waters Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s)and Signature(s)of Inspector(s) Agency/Office/Phone and Fax Numbers Date Timothy H Heim ARO WQ//828-296-4665/ 12/28/2018 D-Signed by: 14t1011AAA C1 t,1414 Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date L gnetl by: 12/2 8/2 018 EPA Form 3560-3(Rev 9-94)Previous editions are obsolete. Page# 1 DocuSign Envelope ID:CF5621E7-B140-4571-A887-468AAOE85F39 NPDES yr/mo/day Inspection Type (Cont.) 1 31 NC0000272 I11 121 18/12/13 117 18 I B Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) Tim Heim of the Asheville Regional Office performed a Bioassay Compliance Inspection on December 11th and 13th, 2018 for chronic toxicity. John Pryately (ORC), and John Frazier(Water and Wastewater Manager)of Evergreen Paper were present at the time of the inspection. The facility appeared well maintained and operated at the time of the inspection, and in compliance with Permit NC0000272. No violations of permit requirements or applicable regulations were observed during this inspection. This sampling event result was reported as a pass by the Central Toxicity Lab in Raleigh for chronic multi-concentration toxicity. Page# 2 DocuSign Envelope ID:CF5621E7-B140-4571-A887-468AAOE85F39 Permit: NC0000272 Owner-Facility: Canton Mill Inspection Date: 12/13/2018 Inspection Type: Bioassay Compliance Yes No NA NE Page# 3 Division of Water Resources December 21, 2018 MEMORANDUM To: Landon Davidson Water Quality Program Regional Supervisor,ARO Through: Cindy A. Moore �� Supervisor,Aquatic Toxicology Branch From: Carol Hollenkamp Quality Assurance �'f icer,Aquatic Toxicology Branch Subject: Whole effluent toxicity test results Evergreen Packaging NPDES Permit# NC0000272/001 Haywood County The aquatic toxicity test using flow proportional composite samples of effluent discharged from the Evergreen Packaging has been completed. Evergreen Packaging has a permitted discharge of 29.9 million gallons per day (MGD) to the Pigeon River (7Q10 of 52 CFS). Whole effluent samples were collected on December 11 and December 13 by Tim Heim for use in a chronic Ceriodaphnia dubia multi-concentration toxicity test. The test using these samples resulted in a pass with a Chronic Value (ChV) of>100%. Toxicity test information follows. Test Type 3-Brood Ceriodaphnia dubia chronic multi-concentration Test Concentrations 0, 45, 75, 90, 95, 100% Test Result ChV= >100%(Pass) Control Survival 100% Control Mean Reproduction 29.0 neonates Test Treatment Survival 100%at 75, 90, 100, and 90%at 45 and 95%concentration Treatment Mean Reproduction 26.7 neonates in 90%(90%is permit limit) First Sample pH 8.47 SU First Sample Conductivity 2.71 millimhos/cm First Sample Total Residual Chlorine 0.17 mg/L* Second Sample pH 8.15 SU Second Sample Conductivity 2.74 millimhos/cm Second Sample Total Residual Chlorine 0.16 mg/L* Test results for the above samples indicate that the effluent would not be predicted to have water quality impacts on receiving water.These samples were split with ETS, Inc. The test conducted by ETS, Inc. also passed with a ChV>100%. Please contact us if you have any questions or if further effluent toxicity monitoring is desired. We may be reached at (919) 743-8401. * Sample is non-chlorinated. Chlorine readings are likely interference from other substances. Basin: French Broad cc: Tim Heim (ARO) Aquatic Toxicology Branch Water Sciences Section PO Box 7565 Asheville,NC 28802 Phone: (828)350-9364 Fax: (828)350-9368 Environmental Testing Solutions,Inc. January 02, 2019 Mr. Jacob Trantham Evergreen Packaging PO Box 4000 Canton,NC 28716 RE: ETS PROJECT NUMBER: 13842 Dear Mr. Trantham: Enclosed are toxicity test results for samples from the Evergreen Packaging received by Environmental Testing Solutions, Inc. December 11 and December 13, 2018. Parameter Test Procedure EPA Method Final Result Code Number North Carolina Phase II Chronic Whole THP3B Effluent Toxicity Test Procedure EPA-821-R-02-013 ChV>100% (Cerioclaphnia Full-range Toxicity Test) Note: ChV=Chronic Value. A numeric value representing the geometric mean of the highest concentration having no detectable impairment of survival or reproduction and the lowest concentration that does have a detectable impairment of survival or reproduction. If this test was performed as an NPDES requirement or by Administrative Letter, please enter the ChV value>100% on the Effluent Discharge Monitoring Form(MR-1) for the collection date December 11,2018 using the parameter code THP3B. Additionally, please sign and submit the original DWQ Aquatic Toxicity Form(AT-3) by January 31,2019. If you have any questions concerning these results, please feel free to contact tne. Sincerely, tiner Laboratory Director This report should not be reproduced,except in its entirety,without the written consent of Environmental Testing Solutions,Inc. The results in this report relate only to the samples submitted for analysis. North Carolina Certificate Numbers: Biological Analyses: 37, Drinking Water: 37786, Wastewater: 600 South Carolina Certificate Number: Clean Water Act: 99053-001 PO Box 7565 Asheville.NC 28802 Phone: (828)350-9364 Fax: (828)350-9368 Environmental Testing Solutions,Inc. Effluent Aquatic Toxicity Report Form-Phase II Chronic Ceriodaplrnia dnbia Date: January 02,2019 Facility: Evergreen Packaging NPDES#: NC-0000272 Pipe#: 001 County: IIaywood Laboratory Performing Test: Environmental Testing Solutions,Inc. Comments: . Signature of Operator in Responsible Charge: Signature of Laboratory Supervisor: Project. 13842 Samples: 181211.02,181213.02 Mail Original To:North Carolina Department of Environment and Natural Resources DWQ/Environmental Sciences Branch 1621 Mail Service Centel- Start date: End date: Start time: End time: Raleigh,NC 27699-1621 12-12-18 12-19-18 1170 0739 Sample Information Sample 1 Sample 2 Control Collection start date: 12-10-18 12-12-18 Test Information Start Ren-al I Renacal2 Stan Rcncnal I Ren-al2 Grab: Treatment: 100% 100% 100% Control Control Control Composite duration: 24-h 24-h Initial pH(SU): 8.53 8.45 8.60 7.60 7.65 7.79 Alkalinity(mg/L CaCO3): 34 Final pH(SU): 8.74 8.64 8.34 7-79 7.96 7.59 Hardness(mg/L CaCO,,): 34 Initial DO(mg/L): 8.1 8.3 8.1 7.7 7.8 7.8 Conductivity(µmhos/cm): 2600 2610 152.149.158 Final DO(ng/L): 8.3 8.3 8.2 8.0 8.0 8.0 Total residual chlorine(ng/L): <0.10 <0.10 Initial Temp.(°C): 25.0 25.0 24.9 24.8 24.8 24.7 Sample Temp.at Receipt(°C): 2.2 0.8 Final Temp.IT): 24.9 24.8 24.7 25.0 25.0 24.8 Organism Number Control Organisms 1 2 3 4 5 6 7 8 9 10 %ican Chronic Test Results Number of Young Produced 35 33 27 31 30 30 33 33 30 35 31.7 Final Control Mortality(%): 0 Adult Survival: (L)ive,(D)ead LI L I L I L I L I L I L I L I L I L I %Control with 3rd Broods: 100 Control Reproduction CV: 8.0 Effluent Percentage 45/ 48 Hour Mortality Treatment 2 Organisms 1 2 3 4 5 6 7 8 9 10 Mean Control: 0 of 10 Number of Young Produced 1 371 34 31 1 341 28 35 1 35 1 361 32 1 371 33.9 11WC: 0 of 10 Adult Survival: (L)ive,(D)ead I L I L I L I L I L I L I L I L I L I L I -6.9 Significant?: No Reduction Final Mortality Significant at: No cone. Effluent Percentage 7s/ Treatment 3 Organisms 1 2 3 4 5 6 7 8 9 10 moean Reproduction Analyses Number of Young Produced 1 371 34 38 1 34 1 321 37 33 1 301 32 1 301 33.7 Reproduction LOEC: >100% Adult Survival: (L)ive,(D)ead L L L L L L L L L L -6.3 Reproduction NOEL 100% %Reduction Overall Method: Dunnett's Effluent Percentage 90/ Nonnal Distribution: Yes Treatment 4 Organisms 1 2 3 4 5 6 7 8 9 10 mean Method: Kolmogorov D Number of Young Produced 133 1 31 301 28 1 301 31 31 32 1 28 1 32 1 30.6 Statistic: 0.920 Adult Survival- (L)ive,(D)ead I L I L L I L I L I L L L I L L 1 3.5 Critical Value: 1.035 %Reduction Equal Variances: Yes Effluent Percentage 95% Method: Bartlett's Test Treatment 5 Organisms 1 2 3 4 5 6 7 8 9 10 mean Statistic: 3.654 Number of Young Produced 1321 33 31 128 1 291 341 27 301 33 1 311 30.8 Critical Value: 15.086 Adult Survival: (L)ive,(D)ead I L I L I L I L I L I L I L I L I L I L 1 2.8 Non-Parametric Analysis(ifapplicable) %Reduction Method: Effluent Percentage 100% Effluent% Rank Sum Critical Sum Treatment 6 Organisms 1 2 3 4 5 6 7 8 9 10 dean 45% Number of Young Produced 26 29 29 33 1 261301291 28 291301 28.9 75% Adult Survival- (L)ive,(D)ead L L L L L L L L L L 8.8 90% %Reduction 95 Overall Analysis: 100% Result: PASS LOEC: >100% NOEC: 100% ChV: >100% DWQ form AT-3(8191)Rei. 11195 Page 1 of 4 North Carolina Chronic Phase II Whole Effluent Toxicity Test,Species: Ceriodaphnia dubia (EPA-821-R-02-013 Method 1002.0, NC Modification—December 2010,Version 3.0) Client Evergreen Packaging NPDES# NC0000272 Facility Canton Mill outfall 001 Project# \ County Haywood Chronic Limit 90% Dilution Preparation: Test concentrations(%) 45 75 90 95 100 Sample was not aerated or treated unless otherwise noted on this form. Sample was warmed to 25.0±1.0°C in a warm mL Sample 90 150 180 190 200 water bath and then diluted to the test concentrations with soft synthetic water. mL Dilution water 110 50 20 10 0 Total volume(mL) 200 200 200 200 200 Daily Renewal Information Test Initiation,renewal,feeding or Selenastrum YWT Location Randomizing Day Date termination Sample Number SSW Batch Time Analyst Batch Batch Incubator/Shelf Template Q Initiation/Feeding Sample 1 1z-1z-1s 1\'LO %k \21\.CL ZC2 gU�e- 1 Feeding T 12-13-18 OU0 - 1 S 2 Renewal 1/Feeding Sample 2 12-14-18 �-1._-to 1&►'t t3.01 3 Feeding 12-15-18 aS a'5 Ts 4 Feeding 12-16-18 p O T• 5 12-17-18 Renewal 2/Feeding ` Sample 2 \wL\-;5xL ruob-4 Feeding 12-18-18 O 9/O T J_ ] Termination 1z-19-1s Test was initiated using Sample 1. Sample 2 was used for Renewals One(day 2)and Two(day 5). Test Organism Information: Final Results-Summary of Test Endpoints: Organism Source: In-house Culture ? li Co,7, 7-day LCso Age: <24-hours old Source(culture board): %1•UA-Q 11n, NOEC 1�? Replicate# 1 1 2 3 1 4 1 5 1 6 1 7 1 8 9 1 10 Culture board cup# 1 tp t 1 t 13 Il 1$ tq 10 14 Date and time organisms were born To 1 LOEC >100 7 between: �! �. Average transfer volume: 0.0194 mL ChV t oo Transfer bowl information: pH(S.U.): g,00 IC21 7 i col. Temperature(°C): +'S SOP AT13-Exhibit AT13.2,revision 11-01-14 _ Page 2 of 4 North Carolina Chronic Phase II Whole Effluent Toxicity Test,Species: Ceriodaphnia dubia i (EPA-821-R-02-013 Method 1002.0, NC Modification—December 2010,Version 3.0) Facility Evergreen Packaging Project# t'J$`I1L Survival and Reproduction Data: Control serva irons Replicate number Day 2 Adult mortality Renewal One (L=Live,D=dead) Number of broods present T t t Z 2 '\- 5 Number of young produced Renewal Two Adult mortality (L=Live,D=dead) Number of broods present 1 L \ 1 IL, IL L l Number of young produced t 1 it. 13 15 \:I� 1 S 1 \ I'A QS i�o 7 Total young produced cc Final Final adult mortality (L=Live,D=dead) v `/ X for 3rd Broods /� x Survival o Mean offspring per female Test concentration: 45% Day Observations Replicate number 2 Adult mortality Renewal One (L=Live,D=dead)Number of broods present 5 Number of young produced 1� 1� t 1�i 1 O 1 \ 115 lq Renewal Two Adult mortality (L=Live,D=dead) v Number of broods present 1 \ \ ET E\ \ \ —77 Number of young produced 7 Total young produced Final NA -SN �� Lg IS 31 Final adult mortality L (L=Live,D=dead) Survival �u Z� I [ Mean offspring %Reduction r 1 per female from Control Test concentration: 75% Day Observations Replicate number 2 A u t morta ity Renewal One (L=Live,D=dead) L- Num er o roods present Li 'L. —l. 1 ^1- 'L 1 L 5 Number of young produced \ I l 1 (� I� L I q (e9 Renewal Two Adult mortality (L=Live,D=dead) �— Number of broods present \ 1 \ k 1 Number of young produced 7 Total young produced l Final Final adult mortality (L=Live,D=dead) L L L L Survival 1007, Mean offspring -t %Reduction _14 per female ' + from Control SOP AT13-Exhibit AT13.2,revision 11-01-14 Page 3 of 4 North Carolina Chronic Phase II Whole Effluent Toxicity Test,Species: Ceriodaphnia dubia I (EPA-821-R-02-013 Method 1002.0, NC Modification—December 2010,Version 3.0) Facility Evergreen Packaging IProject# l'5l�Ji'1_ Survival and Reproduction Data: ITest concentration: 90% Observations Rep icate num er Day 1 2 3 1 4 5 6 7 8 9 10 2 Adult mortality Renewal One (L=Live,D=dead) `-- `— t✓ �" `- `-- L-- `- Number of broods present L 1 Z -L 5 Number of young produced Q 15 1'� 1 ( 15 1 Renewal Two Adult mortality (L=Live,D=dead) Number of broods present lLN L,—. \ 1 \ t 1 \ Number of young produced \ Cj 1\c \J 7 Total young produced 3.� bu u -�b Final Final adult mortality (L=Live,D=dead) Survival Mean offspring y�O•b %Reduction per female from Control S �• Test concentration: 95% Observations Replicate number Day 1 2 3 4 5 6 7 8 9 10 2 Adult mortality � � � � � � 1 Renewal One (L=Live,D=dead) Number of broods present 5 Number of young produced LO Renewal Two Adult mortality(L=Live,D=dead) 1`-' \-' �"" `" `. Number of broods present \ \ LT \ IT \ \- L Number of young produced \ Z \`A 1-A is 1-b 1 7 Total young produced Final Final adult mortality L (L=Live,D=dead) Survival I Mean offspring %Reduction bCl7• • .7, per female from Control Test concentration: 100% Observations Replicate number Day 1 2 3 4 5 6 7 8 9 10 2 Adult mortality Renewal One (L=Live,D=dead) Number of broods present 1 L \ Fa �, 5 Number of young produced l L' i 1 \ (o I 0\ Renewal Two Adult mortality (L=Live,D=dead) Number of broods present L t \ 1 \ 1 1 L Number of young produced 7 Total young produced b Final Z� -2�A p' Z(o Final adult mortality (L=Live,D=dead) Survival Mean offspring %Reduction 7 ��' per female g ` from Control �` t In 00 00 - c G M N 00 'n O 1 cz • .n W cd ° 3 n r > o = W V 00 00 In l- r- i a c a a � o •r•+� .� u r C\ r l0 00 C, O N M O O 00 > O M O >� 00 M M M M N -4—j P., ` N C�' O G` V 'Inn fi 00 rV 7 O r .n N r o ^ OM _ _ r., ^ M _. M ^ r.4 > .r yC Cv '+� = m � —' Gl M N r ^ 00 O M M 10 M G1 = ^ ^ Q M N N ^ M N Ocn V N r o = = cl 00 r 00 ' r M ^ M ^ M N ^ M M N it V] �-• J � � a � O 01 'S M 00 r In V G'\ M r 7 �n N Nr c O_ � M _ Nc� a -6' El co o a Q 3 O '"I cr V � •n •n o o •n 1n G� oo r •n l7 ^ G� .n Y � � o cs � � r � ? � - o, — > U i o u on Q Jo, .�, y. yu, va c = Ln CO U r M O V• N 00 In r IN N O o0 ^ C� V� O l� s C„� u In •- M _--. .-� N ..r _ ,y _ _ M _ _ M " G\ .n 7 .n M 00 .n M 00 O M M II M M N ^ ell N M t] Coo '�v M'•I � � G C p M 7 M N W M M G, G1 M r M M r 7 M In 7 N TT W - N r V' M ni N 7 P V 1 7 •nV •- � 7 M r N Cl r � O Vl M rA O ^ M M M M N ^ M N ca - jr F. V C N - O o U N U i 0 In r In r C In r C •n r •n r .n r F F F F = Q 4-1 N O NKO O O o 0 0 0 p L _ _ W u o O 7 r C., C\ O C u V u C O V] W G :D W Environmental Testing Solutions,Inc. Ceriodaphnia Survival and Reproduction Test-Reproduction Start Date: 12/12/2018 Test ID: CdFRCRNC Sample ID: Evergreen End Date: 12/19/2018 Lab ID: ETS-Envir.Testing Sol. Sample Type: DMR-Discharge Monitoring Report Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: CD-Ceriodaphnia dubia Comments: Conc-% 1 2 3 4 5 6 7 8 9 10 D-Control 35.000 33.000 27.000 31.000 30.000 30.000 33.000 33.000 30.000 35.000 45 37.000 34.000 31.000 34.000 28.000 35.000 35.000 36.000 32.000 37.000 75 37.000 34.000 38.000 34.000 32.000 37.000 33.000 30.000 32.000 30.000 90 33.000 31.000 30.000 28.000 30.000 31.000 31.000 32.000 28.000 32.000 95 32.000 33.000 31.000 28.000 29.000 34.000 27.000 30.000 33.000 31.000 100 26.000 29.000 29.000 33.000 26.000 30.000 29,000 28.000 29.000 30.000 Transform:Untransformed 1-Tailed Isotonic Conc% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean D-Control 31.700 1.0000 31.700 27.000 35.000 8.015 10 33.100 1.0000 45 33.900 1.0694 33.900 28.000 37.000 8.395 10 -2.040 2.287 2.466 33.100 1.0000 75 33.700 1.0631 33.700 30.000 38.000 8.514 10 -1.855 2.287 2.466 33.100 1.0000 90 30.600 0.9653 30.600 28.000 33.000 5.381 10 1.020 2.287 2.466 30.700 0.9275 95 30.800 0.9716 30.800 27.000 34.000 7.467 10 0.835 2.287 2.466 30.700 0.9275 *100 28.900 0.9117 28-900 26.000 33.000 7.006 10 2.596 2.287 2.466 28.900 0.8731 Auxiliary Tests Statistic Critical Skew Kurt Kolmogorov D Test indicates normal distribution(p>0.01) 0.9202 1.035 -0.267 -0.3583 Bartlett's Test indicates equal variances(p=0.60) 3.65366 15.0863 Hypothesis Test(1-tail,0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df Dunnett's Test 95 100 97.4679 1.05263 2.46596 0.07779 37.28 5.81481 9.6E-05 5,54 Treatments vs D-Control Linear Interpolation(200 Resamples) Point % SD 95%CL Skew IC05 85.344 4.186 80.197 96.023 0.8840 IC10 97.528 IC15 >100 1.0 IC20 >100 IC25 >100 0.8 IC40 >100 IC50 >100 0.7 w 0.5 c CO 0.4 N N 0� 0.2 0.1 -0.3 0 50 100 150 Dose% Dose-Response Plot 40 35 30 1-tail,0.05level ------- --------------- ------- of significance 25 i� 0 20 a 15 10 5 0 0 0 U d Evergreen 12-12-18 ,_�_.............. North Carolina Chronic Phase II Whole Effluent Toxicity Test,Species: Ceriodaphnia dubia Page 4 of 4 (EPA-821-R-02-013 Method 1002.0, NC Modification—December 2010,Version 3.0) Facility Evergreen Packaging Project# Cheirnkal Analyses: Initiation Renewal One Renewal Two Initial Final Initial Final Initial Final Concentration Analyst f f �-�� /YS K1' pH(S.U.) Dissolved oxygen(mg/L) Control Conductivity(µmhos/cm) 1 SSW *Alkalinity(mg/L CaCO3) ` *Hardness(mg/L CaCO3) SA *Temperature(°C) ZS •Cl -LA.i ZS-1C) %A.1 Z.{,4 ry pH(S.U.) & 8. 45% Dissolved oxygen(mg/L) Lp �i.p 16-o �•�[ �2 Conductivity(µmhos/cm) p3�o 6 �Z90 *Temperature CC) 1350 Z`1-4) �l"`� c1 Z`�•� '%5., __vk-& -LA- I pH(S.U.) 8• 31� e.5 ti 75 Dissolved oxygen(mg/L) 6-o 90 I Pt `? 6 Z Conductivity(µmhos/cm) Lei Z�0 NCO *Temperature(°C) t�•� Z-��• '1,�1,� -La• -Z,�. •LS.D IpH(S.U.) O.3f3 V• 7� �.23 O°la2 �•�� _3l Dissolved oxygen(mg/L) p e ,pp s�oo 90% �� i•2 U'6 O• u'� •Z f Conductivity(µmhos/cm) I2Z'10 a Z3(oo*Temperature(°C) -i 1.`� a - -A. -LA •� 1:� a -o- pH(S.U.) (6.3\ 8 73 6.35 6�67' e33 Dissolved oxygen(mg/L) 9s% 61\ 6•2 �� '••3 �o (6!2 Conductivity(µmhos/cm) *Temperature(°C) ,t o LS 1 ZS.Q -0- Z�•� pH(S.U.) Dissolved oxygen(mg/L) (5�1 i�•3 8.3 �,°3 �1 100% Conductivity(µmhos/cm) Z(0 Z�lo 2� *Total residual chlorine(mg/L) O '�U.)0 *Temperature(°C) IS.() ly.� -� O Z�' C 1� -LA. . *Analyst identified for each day,performed pH,dissolved oxygen and conductivity measurements only. Temperatures performed at the time of test initiation, renewal or termination by the analyst identified in the Daily Renewal Information table. Alkalinity,hardness and total residual chlorine performed by the analysts identified on the test specific bench sheets and transcribed to this bench sheet. SOP AT13-Exhibit AT13.2,revision 11-01-14 351 Depot Street Asheville,NC 28801 Phone: (828)350-9364 Fax: (828)350-9368 Environmental Testing Solutions,Inc. Whole Effluent Toxicity Chain-of-Custody Form Facility: Evergreen Packaging NPDES#: NC0000272 Pipe#: 001 County: Haywood Purchase order: 8901197436 Species: Cer[odaphida dub[a Effluent dilution: 45,75, 90,95, 100% Test type: Phase II Chronic Parameter code: THP3B Sample information: (to be completed by sample collector) Composite sample: Sample location: Start date: Time: ;"' S Volume collected for testing:it � �� End date: Time: s j Number of containers filled for testing: One { Number of samples per hour: Method of transport to laboratory: p`�,. ✓G Chilled during collection? yC Comments: If chilled,specify temperature: Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory. Sample custody: (to be completed by sample collector and facility personnel) Sample collected by: P n / Si urc - Date and time Relinquished by: Received by: �-�2 P 5� Vint ign re Date and time Print Signature Date and time Relinquished by: Received by: Print Signature Date and time Print Signature Date and time Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: Received at ETS by: ,{ — 10 Print Signature Date and time f� Print (/`Signature Date and lime Custody seals intact?: = = Sample temperature upon receipt at ETS(°C): Yes No not used 2�2 Samples received in good condition?: Yes No Total residual chlorine upon receipt at ETS: Tracking number: (DPD Presence/Absense Indicator,MDL—0.10 mg/L) Preset Absent '`� (30�2 Project number: Sample number: 'eum-p'L Comments: 351 Depot Street Asheville,NC 28801 Phone: (828)350-9364 Fax: (828)350-9368 Environmental Testing Solutions,Inc. Whole Effluent Toxicity Chain-of-Custody Form Facility: Evergreen Packaging NPDES#: NC0000272 Pipe#: 001 County: Haywood Purchase order: 8901197436 Species: Ceriodaphnia dubia Effluent dilution: 45,75, 90,95, 100% Test type: Phase II Chronic Parameter code: THP3B Sample information: (to be completed by sample collector) u Composite sample: Sample location: Start date: �� l� Time: �8,`�� Volume collected for testing: { End date: Time: �j''�'yS Number of containers filled for testing: c Number of samples per hour: Method of transport to laboratory: ETS Chilled during collection? Comments: t If chilled,specify temperature: j{ Triple rinse sample container with sample before filling. Completely fill the sample container with no air space. Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory. I I, Sample custody: (to be completed by sample collector and facility personnel) Sample collected by: 1.21131.19 laz�'L7 J9 i� 'Print / nature Dalc and lime Relinquished by: Received by: /o? %3� I t � l 1Z-13—►� tint IV Si' ure Date and time Print Signature Dale and lime Relinquished by: Received by: j ` ff` r' f lZ1&6� I Print Signature Date and lime Print Signature Date and time Sample receipt information: (to be completed by ETS personnel) Relinquished to ETS by: Received at ETS by: iti•t3-�F F71A4tJeK- 1 l by Print Signature Dale and time Print Signature Date and time Custody seals intact?: = = Sample temperature upon receipt at ETS(°C): (('' Yes No Not used 0.Q•�, Samples received in good condition?: = Yes No Total residual chlorine upon receipt at ETS: = (DPD Presence/Absease hidicator,MDL=0.10 mg/L) Present Absent Tracking number: ON Project number: t{2 Sample number: 1612119 Comments: -- Ceriodaphnia dubia Chronic Reference Toxicant Control Chart Environmental Testing Solutions,Inc. Source: In-house Culture 1.12 1.10 Control Limits (± 2 Standard Deviations) 1.08 • m .� 1.06 V 1.04 _a� ® ��_a—m .- ®a�—— . ca Z 1.02 M Ln N V_ 1.15 ....................................................................................................... Warning Limits n 1.10 1.00 0.95 1 1 1 1 1 1 3 a s a a 1ti 6ti titi 3ti 11 5ti 91 61 61 31 31 a1 5ti Oti 11 11 9ti 9ti 6ti Rti 011 0�'� 091 10� 110 '11 '010 Oti0 03� O�0 ORO 05� 06� 011 0`�� 09� 10� 10� 11� '1ti0 Test date • 7-day IC25=25%inhibition concentration. An estimation of the sodium chloride concentration which would cause a 25%reduction in Ceriodaphnia reproduction (calculated using ToxCalc). Central Tendency(mean logarithmic IC25 converted to anti-logarithmic values) Control Limits (mean logarithmic IC25±2 standard deviations converted to anti-logarithmic values) �..®. Laboratory Warning Limits(mean logarithmic IC25±2 coefficent of variations converted to anti-logarithmic values) ••••••••• USEPA Warning Limits (mean logarithmic IC25±SA.io converted to anti-logarithmic values, SA to=10th percentile of CVs reported nationally by USEPA) cemC abd y Rev d.b llm Sumo