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HomeMy WebLinkAboutNC0000272_Historic Docs 1996-1997_19970101 ITN OFFICE D:2166 MAY 0 '97 10 :32 No .003 P .01 f L.i dnn Idill Ihw f 10 Champion CI-ampinn I nnfimu,I Cnrfwnfion [ May 1, 1997 To: Roy Davis Fr: Michele Reaves RE: Purchased Goods and Services I Year to date purchases for the Canton mill from suppliers in North Carolina, Tennessee and South Carolina (does not Include wood purchases). Year to Date -Annualized NC $27,658,286 $B2,974,858 TN $ 3,586,366 $10,759,098 Sc $ 5,997,542 $17,992,626 Note: "Annualized" numbers ate basest off of the first three months of 1997. Champion has incurred approximately $40,000,000 in wood purchases from Western North Carolina. Wood purchase figures from Tennessee sources are not available at this time. If you have any questions, I can be reached at 646-2308 or via digital pager 444-3536. iJ d n I li � t y� ENVIRONMENTAL MANAGEMENT COMMISSION IN THE MATTER OF REQUEST FOR ) AMENDED ORDER VARIANCE FROM WATER QUALITY ) FOR STANDARD-BASED EFFLUENT ) MODIFICATION OF COLOR LIMITATIONS BY CHAMPION ) VARIANCE GRANTED ON INTERNATIONAL CORPORATION ) JULY 13, 1988 CANTON,NORTH CAROLINA ) THIS MATTER came on to be heard before the NPDES (National Pollutant Discharge Elimination System) Committee at its scheduled meeting in Raleigh, North Carolina, on December 11, 1996, on its own motion to amend its order, dated October 9, 1996, for modification of an existing color variance which was granted to Champion International Corporation on July 18, 1988. Upon duly made motion and vote, the NPDES Committee hereby re-adopts its order, dated October 9, 1996, and further adopts the additional, following Findings of Fact and Conclusions of Law: FINDINGS OF FACT 1) On October 17, 1996, the Director of the Division of Water Quality transmitted to the United States Environmental Protection Agency, for its review, the October 9, 1996, order for Modification of Color Variance Granted on July 18. 1988, 2) On December 9, 1996, the United States Environmental Protection Agency advised the Division of Water Quality and the NPDES Committee, by letter from Regional Administrator John Hankinson to Assistant Secretary Linda Rimer, that the modification of the color variance with certain more restrictive clarifications to the order is acceptable to the agency. l — 2 3) The Division of Water Quality and' Cham_ pion International Corporation have -advised the NYDES:.Committee that;the.changes-proposea`by the United'States hndiiorimental .. Protection Agency are acceptable. 4) The following changes to the conditions of the modified variance are more restrictive on the company, and are accepted by the NPDES Committee: (Words recommended for removal are stricken through and additional wording is in bold.) Conditions identified below of the "Ordered" section of the October 9, 1996, order of the NPDES Committee should be modified to: CONDITION 211 II. The average daily discharge of true color for each calendar month shall not exceed '']� 125,434 pounds per day. The average annual effluent true color loading shall not exceed 124,923 98,168 pounds per day. For the purpose of this permit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units)x 8.34. CONDITION 4 4. Champion shall continue to study, evaluate, and pursue and operate color removal technologies and report its findings to the NPDES Committee and the Division of Water Quality in accordance with the following schedule: DATE ACTIVITY EeatkHgfig January 1, 1997 The Company will implement a one year Eemmereial demonstration of full scale bleach filtrate recycling (1317k") technology on the mill's pine line. March 1, 1998 In conjunction with the scheduled Triennial Review of N.C. Water Quality Standards the-Company shall: 1. Submit a status report to the NPDES Committee on the technical, economic, and operational feasibility of the BFR' technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. PPPPP� 3 r 2. Evaluate and report to the NPDES Committee on the application of end-of-pipe color reduction;technologies - _- --- - and, additional mini-nization,of-,colar,lones from.the manufacturing processes and raw material' storage • `' areas. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. . The,,intermittent application of these technologies and minimization efforts must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing and adopting these technologies and minimization efforts at the mill. The report will also project the expected additional color reduction for each technology and in-mill minimization effort evaluated and the maximum color reduction possible using the identified technology or action. 3. Champion will evaluate color reduction strategies for further optimization of BFRTm technology and report on the feasibility of implementation on the hardwood line. 3 area December 1, 1998 Based en the results of the demenstFatien prejeet and the presented in*14he "' , Champion will deeide and FepeFt en the desist,.., to fully implement and operate on a continuing basis the BFRT' technology on the mill's pineweed line., unless the Company can demonstrate to the NPDES Committee that BFRTm is not a commercially viable process at this location. March 1, 2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. The evaluation shall include ' au incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies must look.particularly at periods of low river flow. The ,t 4 report will identify specific economic and implementation.issues associated.with the incremental ` irnler vei .ent of color.levels-expected..by,irisi lli^g these- _. technologies at the mill. The report will also project the- expected additional color reduction for each technology evaluated and the maximum color reduction possible using the identified technology. June 1, 2001 Champion will submit a report to the NPDES Committee and N.C. DEHNR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the Variance review process (Triennial Review of North Carolina Water Quality Standards). CONDITION 5 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee and the Variance Review Committee within 30 days of the availability of Champion's reports as required above. The Variance Review Committee, utilizing the information available,will, by July 1, 1998, and July 1, 2001, make recommendations to the NPDES Committee concerning revisions_ to the color variance. Those recommendations will include lower limits for the monthly average and annual average color limitations applicable to the mill due to color removal performance and the Committee's position on additional revisions needed in the variance to reflect the application of BFRTm, end-of-the pipe treatment and in-mill color reduction technologies. Based on the instream color data available at that time, the Committee will also provide recommendations on the applicability of any instream color compliance point in N.C. The NPDES Committee will review the available information, the recommendations of the Variance Review Committee and the staff recommendations in proposing any changes to the variance. CONDITION 6 6. In conjunction with subsequent triennial water quality standards reviews, the Division will nominate a variance review committee. The NPDES Committee will have final approval of the selection of this Committee. Committee membership may consist of Department Staff and individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university or research communities. The'Committee will also include in its membership a representative of Tennessee's Department of Environment and Conservation who shall be appointed by the Governor of Tennessee. That review committee's report and recommendation will be U ` examined by the NPDES Committee for a decision on the adequacy of the existing variance. :The NPDES Committee will determine if changes in the r,m rrj..%rc was mm ted duc to the Y_� ti:reness.of the reatirient systerp or,because - 1-7 - - -of advances-in color' reduction technologies for this 'type wastewater. . ;All revisions adopted by the NPDES Committee will required the modification of the Company's NPDES Discharge Permit, CONDITION 7 7. The.tvariance;proceeding, and the NPDES Permit Number"NC0000272, shall ages be subject to reopening in order to modify the color requirements based upon the following and in association with the required triennial reviews: 1. a Any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion and the Division of Water Quality, as soon as they are discovered. 2._ An acceptable statistical analysis of effluent color discharge data demonstrating significantly better color removal performance than that currently prescribed in the variance and permit. 3. Successful application of end-of-pipe color reduction technology or in-mill color minimization effort that results in significant and measurable reduced mass color discharge. CONCLUSIONS OF LAW 1) On its own motion and prior to the effective date of the October 9, 1996, order for Modification of Color Variance Granted on July;1'8. 1988, the NPDES Committee may amend its October 9, 1996, order, to satisfy concerns of the United States Environmental Protection Agency, to clarify its conditions and to make the conditions more restrictive on Champion International Corporation. Based on the re-adopted October 9, 1996, Findings of Fact and Conclusions of Law and the additional, foregoing Findings of Fact andtConclusions of Law, it is hereby ORDERED that the previously existing variance from the North' Carolina water quality standard for color as 6 memorialized in the July 13, 1988 Final Decision Ordering Paragraphs, continues in effect as hereby modified,to.read as follows:' 1. Champion's petition for a variance is granted, pursuant to G.S. 143-215.3(e), as a variance to water quality based effluent limitations for color. 2. The Division of geine Water Quality2 shall issue NPDES Permit No. NC0000272, for the Canton Mill, and medif3, draft its provisions to reflect all the conditions of •' ^ F-b ^^ , +n84 a_^a inn sempreraise rronEc . Fmi this modification, including the following specific wording. I. Champion shall take such action as necessary to prevent their contribution of true color from causing the true color at the North Carolina/Tennessee State line from exceeding 93 50 true color units at all flows equal to or exceeding 126 cfs (81.4 MGD, the seven-day, ten-year low flow level) at the Hepco Gauging Station. Compliance with this requirement shall be measured through a calculation a of instream true color levels at the North Carolina/Tennessee state line by the following equation: 91a= 0.224 Sly_ (W tP4/8.34) +((HEI-WTP. x__). (-0.224 x LOG(FIE,)+ 0.781) HE1 x 10 Where: WTP�=Monthly average Waste Treatment Plant discharge color. (QU3 Calculated as the average of all daily loading values (pounds of true color per day) for a calendar month. For ease of reference, the language of the July 13, 1988 Final Decision Ordering Paragraphs is included verbatim, with the modifications made on October 9, 1996 and by this Amended Order denoted by overstriking for deletions and bolding for additions. 2 The Division of Environmental Management has been reorganized and NPDES pemritting is now administered by the Division of Water Quality. pppppp 7 . WTPf=Monthly average Waste Treatment Plant discharge flow(mgd). ".r HEf = Monthly. average HEPCO, North Carolina flow, (MGD).' Daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. Sly = Monthly average Instream true color at North Carohna/Tennessee border(state line). Dl.= Color concentration of all dilution streams (13 C.U.). r The SL, shall be calculated on a daily asis for each calendar month. The aveFage.of aay ealendar week (seven days) of ealeulate,7 SL. values for each month shall not exceed 95 50 true color units. Any exceedance of SS 50 true color units for this average value shall be considered a violation of this permit/variance exeept as provided in item M of 1aEt-- II. The average daily discharge of true color for each calendar month shall not exceed 258,945 125,434 pounds per day. The average annual effluent true color loading shall not exceed 1'rr2,369 98,168 pounds per day. For the purpose of this permit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. leading to less than 124,193 peupt per day. Ill,. IV7 The method of analyses used to measure true color shall be the procedure referenced in FR 39 430.11(b) (May 29, 1974). 3. The Division of Efwiranmenta4 Management Water Quality shall include review of this variance as a specific item in its Triennial Water Quality Standards review, as required by the federal Clean Water Act, and make appropriate recommendations to the NPDES Committee. 4. Champion shall continue to study, and evaluate, pursue and operate color removal technologies and shall report its findings to the NPDES Committee and the Division of EavkenmeaW Management Water Quality r_ �, 7 n , .e _ accordance�ritfi the following schedulc 47 PPP"P7- 9 .. DATE ACTB= January 1, 1997 ::The Company will implement a one=year demonstration of full scale bleach filtrate recycling.(BFRT"') technology on the mill's pine line. March 1, 1998 In conjunction with the scheduled Triennial Review of _ N.C. Water Quality Standards the Company shall: 1. Submit a status report to the NPDES Committee on the technical,,economic, and operational feasibility of the BFRTm technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2. Evaluate and report to the NPDES Committee on the application of end-of-pipe color reduction technologies and additional minimization of color losses from the manufacturing processes and raw material storage areas. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies and minimization efforts must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing and adopting these technologies and minimization efforts at the mill. The report will also project the expected additional color reduction for each technology and in-mill minimization effort evaluated and the maximum color reduction possible using the identified technology or action. 3. Champion will evaluate color reduction strategies for further optimization of BFIff technology and report on the feasibility'of implementation on the hardwood line. 10 ' • ' u. .:.f. 1 'f .ef_ ,.. v ' _ •_.._V: r •F' . ,. _ r r:l +. ._ . December 1, 1998 Based on the results af the d-em—anstr-afien pr-ojeet and Champion will deeide and report an the deeislan to fully implement and operate on a continuing basis the BFRT" technology on the mill's pineweed line., unless the Company can demonstrate to the NPDES I Committee that BFR` is not a commercially viable process at this location. March 1,2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing these technologies at the mill. The report will also project the expected additional color reduction for each technology,,, evaluated and the maximum color reduction possible'using the identified technology. June 1,2001 Champion will submit a report to the NPDES Committee and, N.C. DEHNR, Division of Water Quality, on the'comparative evaluation of the above collective efforts'as part of the Variance review process (Triennial Review of North Carolina Water Quality Standards). 5. The Division will provide a statu 1 s summary report on color removal at the Canton Mill to the NPDES Committee and the Variance Review Committee allnually, en er be Ame 30 of eaeh year, within 30 days of the availability of Champions' reports as required above. The Variance Review Committee, utilizing the information available,will, by July . 11 • PPPPP� 1, 1998, and July 1, 2001, make recommendations to the NPDES Committee concerning revisions io;the coior variance. ' I hose'r6comifiendations vrill:-include lower limits for the monthly average and annual average color limitations applicable to the mill due to color removal performance and the Committee's position on additional revisions needed in the variance to reflect the application of BFRT , end-of-the pipe treatment, and in-mill color reduction technologies. Based on the instream color data available at that time, the Committee will also provide recommendations on the applicability of any instream color compliance point in N.C. The NPDES Committee will review the available information,the recommendations of the Variance Review Committee and the staff recommendations in proposing any changes to the variance. 6. Following the rletiea and r and In conjunction with theft subsequent triennial water quality standards reviews afteF period, the Division will nominate a variance review committee. The NPDES Committee will have final approval of the selection of this committee. Whi 11 Committee membership may corisist of Natuml ReseuFees and Geffh amity Develepraeat Department Staff and at individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university or research communities.' The Committee will also include in its membership a representative of Tennessee's Department of Environment and Conservation who shall be appointed by the Governor of Tennessee. That review committee's report and recommendation will be examined by the NPDES Committee for a decision on the adequacy of the existing variance. The NPDES ' The Variance Review Committee membership qualifications are changed to provide greater flexibility in appointments. 12 Committee will determine if changes in the variance are warranted due to the effectiveness of the treatment-system or because of advances-in coloi'reducfion.techuolc giEs fa2.this type wasfewatef. . All revisions adopted by the NPDES Committee will require the modification of the Company's State NPDES Discharge Permit. 7. The variance proceeding, and the NPDES Permit No. NC 0000272, shall at-au times be subject to reopening in order to modify the color requirements based upon ar3y the following and in association with the required triennial reviews: 1) Any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion and the Division of b Water Quality, as soon as they are discovered. 2) An acceptable statistical analysis of effluent color discharge data demonstrating significantly better color removal performance than that currently prescribed in the variance and permit. 3) Successful application of end-of-pipe color reduction technology or in-mill color minimization effort that results in significant and measurable reduced mass color discharge. 8. This variance shall extend for an indefinite period of time, subject to consideration of the three-year reviews and the annual repefts. aFA Any modification or termination based thereon shall be subjected to the public hearing process required by G.S. 143-215.3(e). pppppp� 13 It is further ORDERED that this Modification of Color Variance shall be effective as of ".The"effective(ia2e ii'Cue re-issueu'T11'i) 5 Perriit^I1u."Ni `0�?OU272`for ihe"i;hitioa-Mill;and the terms of the previously existing variance shall continue in effect until that time. NOTICE OF CONTESTED CASE RIGHTS This Amended Order for Modification of Color Variance Granted on July 13 1988 is made effective on the effective date of, and is issued in conjunction with, the re-issued NPDES Permit No. NC0000272 for the Canton Mill. A person aggrieved by this Amended Order may commence a contested case in accordance with G.S. 143-215.1(e), by filing a petition under G.S. 150B-23 within thirty(30) days after Champion International Company is notified of the NPDES Permit decision. That date has been established as December 12, 1996; thus any contested case petitions must be filed with the Office of Administrative Hearings no later than January 13, 1997. :�; s 4 14 This the' of December, 1996: m aniel V. Besse, Chairman NPDES Committee ppppp� 15 CERTIFICATE OF SERVICE This is to certify that I have this day served a copy of the foregoing AMENDED.ORDER FOR MODIFICATION OF COLOR VARIANCE GRANTED ON DULY 13, 1988 on the parties listed below by the methods indicated, addressed to each as follows: William Clarke HAND DELIVERY Roberts & Stevens P.O. Box 7647 Asheville,North Carolina 28802 A.Preston Howard,Jr.,Director HAND DELIVERY Division of Water Quality N.C.Department of Environment,Health and Natural Resources 9th floor,Archdale Building Raleigh,North Carolina 27601-7687 Jennie Odette, Clerk HAND DELIVERY Environmental Management Commission N.C.Department of Environment, Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 Paul Davis CERTIFIED MAIL Tennessee Department of Environment RETURN RECEIPT REQUESTED & Conservation 6th floor, L& C Annex 401 Church Street Nashville, Tennessee 37243-1534 David McKinney CERTIFIED MAIL Tennessee Wildlife Resources RETURN RECEIPT REQUESTED Ellington Agriculture Center P. 0. Box 40747 Nashville, Tennessee 37204 Gary Davis CERTIFIED MAIL Tennessee Environmental Council RETURN RECEIPT REQUESTED 1700 Hayes Street, Suite 101 Nashville, Tennessee 37203 16 i� Mike McGhee CERTIFIED MAIL TXie:u ,,W er •Zr.w_:e nunt ..,i.o..6Cr of"..�t.:a isiz.._g..i.utaa 100 Alabama Street, SW Atlanta, Georgia 30303 Barry Turner CERTIFIED MAIL Deputy Attorney General RETURN RECEIPT REQUESTED Tennessee Attorney General's Office 450 James Robertson Parkway Nashville,Tennessee 37243-0495 This the ffi!-day of December, 1996. MICHAEL F.EASLEY Attorney General Daniel C. Oakley Senior Deputy Attorney General Environmental Division P. O. Box 629 Raleigh,North Carolina 27602-0629 919/733-5725 /14287 State of North Carolina Department of Environment, Health and Natural Resources • Division of Water Quality r James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary p E A. Preston Howard, Jr., P.E., Director December 19, 1996 John Hankinson> Jr. Region IV Administrator I' U.S. Environmental Protection Agency DEC 3 06 100 Alabama Street, S.W. Atlanta, Georgia 30303 AS WATER UAi ;i-°c t G;0 SUBJECT: Color Variance Champion International Corporation NPDES Permit NC0000272 Haywood County Dear Mr. Hankinson: As EPA requested, North Carolina re-evaluated the amendment to the 1988 water quality standard variance for color issued to the Champion International Corporation Canton Mill wastewater discharge approved by the NPDES Committee in October of this year. Modifications to the variance were prepared further reducing the allowable discharge load of color, explicitly describing the continued color minimization studies required, strengthening the re-opener condition and specifically establishing that Tennessee would have representation on the Variance Review Committee. Based upon staffs discussion with EPA and Champion,the NPDES Committee approved the modifications previously sent to EPA in draft at their December 10, 1996 meeting. Enclosed are the documents pertaining to the adoption of the modification. I hereby request that EPA approve the modified variance. Your prompt consideration of this matter would be greatly appreciated. Thank you for all the attention that you and your staff have devoted to this issue. If you have any questions regarding the variance,you may contact Coleen Sullins of my staff at 919/733-5083, extension 550. Sin rely, A. Preston Howard, Jr., E. cc: Mike McGhee,Water Management Division Director,EPA Region IV Harlan Britt,Deputy Director, Division of Water Quality Steve Tedder, Chief,Water Quality Section Dan Oakley, Senior Deputy Attorney General,Environmental Division Forrest Westall,Water Quality Supervisor, Asheville Regional Office Greg Thorpe. Assistant Chief Water Quality Section, Planning Branch Colleen Sullins, Supervisor, Pemuts &Engineering Unit P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733.0719 An Equal Opportunity Affirmative Action Employer 50% recycled/10%post-consumer paper ENVIRONMENTAL MANAGEMENT COMMISSION IN THE MATTER OF REQUEST FOR ) AMENDED ORDER VARIANCE FROM RATER QUALITY ) FOR STANDARD-BASED EFFLUENT ) MODIFICATION OF COLOR LIMITATI4) CHAMPION ) VARIANCE GRANTED ON INTERNATI CORPORATION ) JULY 13, 1988 CANTON,NO CAROLINA ) THIS MATTER came on to be heard before the NPDES (National Pollutant Discharge Elimination System) Committee at its scheduled meeting in Raleigh, North Carolina, on December 11, 1996. on its own motion to amend its order, dated October 9, 1996, for modification of an existing color variance which was granted to Champion International Corporation on July 18. 1988. Upon duly made motion and vote, the NPDES Committee hereby re-adopts its order, dated October 9, 1996. and further adopts the additional, following Findings of Fact and Conclusions of Law: FINDINGS OF FACT 1) On October 17, 1996, the Director of the Division of Water Quality transmitted to the United States Environmental Protection Agency, for its review, the October 9, 1996, order for Modification of Color Variance Granted on July 18. 1988, 2) On December 9, 1996, the United States Environmental Protection Agency advised the Division of Water Quality and the NPDES Committee, by letter from Regional Administrator John Hankinson to Assistant Secretary Linda Rimer, that the modification of the color variance with certain more restrictive clarifications to the order is acceptable to the agency. z 3) The Division of Water Quality and Champion International Corporation have advised the NPDES Committee that the changes proposed by the United States Environmental Protection Agency are acceptable. 4) The following changes to the conditions of the modified variance are more restrictive on the company, and are accepted by the NPDES Committee: (Words recommended for removal are stricken through and additional wording is in bold.) Conditions identified below of the "Ordered" section of the October 9, 1996, order of the NPDES Committee should be modified to: CONDITION 2.II II. The average daily discharge of true color for each calendar month shall not exceed 132,341 125,434 pounds per day. The average annual effluent true color loading shall not exceed 124,923 98,168 pounds per day. For the purpose of this permit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. CONDITION 4 4. Champion shall continue to study, evaluate, and pursue and operate color removal technologies and report its findings to the NPDES Committee and the Division of Water Quality in accordance with the following schedule: DATE ACTIVITY Gentiaeing January 1, 1997 The Company will implement-a one year Cemmereial demonstration of full scale bleach filtrate recycling (BFRTm) technology on the mill's pine line. March 1, 1998 In conjunction with the scheduled Triennial Review of N.C. Water Quality Standards the Company shall: 1. Submit a status report to the NPDES Committee on the technical, economic, and operational feasibility of the BFRTm technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 3 2. Evaluate and report to the NPDES Committee on the application of end-of-pipe color reduction technologies and additional minimization of color losses from the manufacturing processes and raw material storage areas. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies and minimization efforts must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing and adopting these technologies and minimization efforts at the mill. The report will also project the expected additional color reduction for each technology and in-mill minimization effort evaluated and the maximum color reduction possible using the identified technology or action. 3. Champion will evaluate color reduction strategies for further optimization of BFRTAf technology and report on the feasibility of implementation on the hardwood line. F e and raw fnate:al storage- afeas. December 1, 1998 Based _.. the result_ of the deems'-" `en ; Oad the presented in the eenelusien of the status i:epeFt, Champion will deside and . pei4 en the deeision to fully implement and operate on a continuing basis the BFRTA4 technology on the mill's pineweed line., unless the Company can demonstrate to the NPDES Committee that BFRT"' is not a commercially viable process at this location. March 1, 2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies must look particularly at periods of low river flow. The 4 report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing these technologies at the mill. The report will also project the expected additional color reduction for each technology evaluated and the maximum color reduction possible using the identified technology. June 1, 2001 Champion will submit a report to the NPDES Committee and N.C. DEHNR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the Variance review process (Triennial Review of North Carolina Water Quality Standards). CONDITION 5 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee and the Variance Review Committee within 30 days of the availability of Champion's reports as required above. The "Variance Review Committee,utilizing the information available,will, by July 1, 1998, and July 1, 2001, make recommendations to the NPDES Committee concerning revisions to the color variance. Those recommendations will include lower limits for the monthly average and annual average color limitations applicable to the mill due to color removal performance and the Committee's position on additional revisions needed in the variance to reflect the application of BFRr", end-of-the pipe treatment and in-mill color reduction technologies. Based on the instream color data available at that time, the Committee will also provide recommendations on the applicability of any instream color compliance point in N.C. The NPDES Committee will review the available information, the recommendations of the Variance Review Committee and the staff recommendations in proposing any changes to the variance. CONDITION 6 6. In conjunction with subsequent triennial water quality standards reviews, the Division will nominate a variance review committee. The NPDES Committee will have final approval of the selection of this Committee. Committee membership may consist of Department Staff and individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university or research communities. The Committee will-also include in its membership a representative of Tennessee's Department of Environment and Conservation who shall be appointed by the Governor of Tennessee. That review committee's report and recommendation will be 5 examined by the NPDES Committee for a decision on the adequacy of the existing variance. The NPDES Committee will determine if changes in the variance are warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater. All revisions adopted by the NPDES Committee will required the modification of the Company's NPDES Discharge Permit. CONDITION 7 7. The variance proceeding, and the NPDES Permit Number NC0000272, shall -�'itimes be subject to reopening in order to modify the color requirements based upon the following and in association with the required triennial reviews: 1. a Any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion and the Division of Water Quality, as soon as they are discovered. 2. An acceptable statistical analysis of effluent color discharge data demonstrating significantly better color removal performance than that currently prescribed in the variance and permit. 3. Successful application of end-of-pipe color reduction technology or in-mill color minimization effort that results in significant and measurable reduced mass color discharge. CONCLUSIONS OF LAW 1) On its own motion and prior to the effective date of the October 9, 1996, order for Modification of Color Variance Granted on July 18. 1988.the NPDES Committee may amend its October 9, 1996, order, to satisfy concerns of the United States Environmental Protection Agency, to clarify its conditions and to make the conditions more restrictive on Champion International Corporation. Based on the re-adopted October 9, 1996, Findings of Fact and Conclusions of Law and the additional, foregoing Findings of Fact and Conclusions of Law, it is hereby ORDERED that the previously existing variance from the North Carolina water quality standard for color as 6 memorialized in the July 13, 1988 Final Decision Ordering Paragraphs, continues in effect as hereby modified,to read as follows:' 1. Champion's petition for a variance is granted, pursuant to G.S. 143-215.3(e), as a variance to water quality based effluent limitations for color. 2. The Division of MaMagement Water Quality' shall issue NPDES Permit No. NC0000272, for the Canton Mill, and medify draft its provisions to reflect-all the conditions of the Fekuafy, 1989 draft EPAeempi:emise NPDEo Ftmk this modification, including the following specific wording. I. Champion shall take such action as necessary to prevent their contribution of true color from causing the true color at the North Carolina/Tennessee State line from exceeding 95 50 true color units at all flows equal to or exceeding 126 cfs (81.4 MGD, the seven-day, ten-year low flow level) at the Hepco Gauging Station. Compliance with this requirement shall be measured through a calculation of instream true color levels at the North Carolina/Tennessee state line by the following equation: (RE') , (-0.224xL0GME,)+ 0.781) HEf x 10 Where: WTP,=Monthly average Waste Treatment Plant discharge color. (Q.4.� Calculated as the average of all daily loading values (pounds of true color per day) for a calendar month. ' For ease of reference, the language of the July 13, 1988 Final Decision Ordering Paragraphs is included verbatim, with the modifications made on October 9, 1996 and by this Amended Order denoted by overstriking for deletions and bolding for additions. 2 The Division of Environmental Management has been reorganized and NPDES permitting is now administered by the Division of Water Quality. 7 WTPr=Monthly average Waste Treatment Plant discharge flow(mgd). HEr = Monthly average HEPCO, North Carolina flow (MGD). Daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. Sl, = Monthly average Instream true color at North Carolina/Tennessee border(state line). D,= Color concentration of all dilution streams (13 C.U.). The SL, shall be calculated en a daily basis for each calendar month. The everage e ,... ^_of lend week (seven ,le.,^) e f ealeulaied SL, values for each month shall not exceed 95 50 true color units. Any exceedance of SS 50 true color units for this average value shall be considered a violation of this permit/variance exeept as previded :n item rrr of t ^ 1� II. The average daily discharge of true color for each calendar month shall not exceed 258,945 125,434 pounds per day. The average annual effluent true color loading shall not exceed 172,368 98,168 pounds per day. For the purpose of this permit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. 9-1- Champion ea ., reduee the Bail effluent ^lam a te less than 124,193 II PA The method of analyses used to measure true color shall be the procedure referenced in FR 39 430.11(b) (May 29, 1974). 3. The Division of gemen Water Quality shall include review of this variance as a specific item in its Triennial Water Quality Standards review, as required by the federal Clean Water Act, and make appropriate recommendations to the NPDES Committee. 4. Champion shall continue to study, and evaluate, pursue and operate color removal technologies and shall report its findings to the NPDES Committee and the Division of s Water Quality b_c- ^—Fi' 39 of eaeh yeaF in accordance with the following schedule: 9 DATE ACTIVITY January 1, 1997 The Company will implement a one-year demonstration of full scale bleach filtrate recycling(BFRT'") technology on the mill's pine line. March 1, 1998 In conjunction with the scheduled Triennial Review of N.C.Water Quality Standards the Company shall: 1. Submit a status report to the NPDES Committee on the technical, economic, and operational feasibility of the BFRT"' technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2. Evaluate and report to the NPDES Committee on the application of end-of-pipe color reduction technologies and additional minimization of color losses from the manufacturing processes and raw material storage areas. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies and minimization efforts must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing and adopting these technologies and minimization efforts at the mill. The report will also project the expected additional color reduction for each technology and in-mill minimization effort evaluated and the maximum color reduction possible using, the identified technology or action. 3. Champion will evaluate color reduction strategies for " further optimization of BFRT"' technology.and report on the feasibility of implementation on the hardwood line. 10 I;III December;1, 1998 =.�a 41��a Champion will fully implement and operate on a continuing basis the BFRT technology, f "" ""'";" `"' "' ^^ •on the mill's pinewood line., unless the Company can demonstrate to the' NPDES' ,Committee that: BFRT"' is not a commercially viable process at this location. March 1,2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. The evaluation':,,shall , include S; an incremental color improvement analysis. This analysis will concentrate on the technical, economic, and operational feasibility of the application of these technologies on a continuous or ' intermittent basis. The intermittent application of these technologies must look particulirly­at periods of low river flow.. •The .report„will.;identify-specific economic and implementation issues associated With ' the -incremental-improvement"of.color,.leVels ,expected by installing these technologies-at thill.e m The report will also project the expected additional•color.reduction for each technology.�,evaluated and the-'maximum color reduction possible using the,identified technology. - June 1,3001, Champion will .submit , a, report„ to,,,the. NPDES Committee and N.C. DEHNR, Division of Water Quality, .on• the comparative evaluation,of'the above collective efforts as part of the,Variance review process (Triennial,Review,of North Carolina Water Quality Standar&). 5. The Division will provide'a status summary report on color=removal at the Canton Mill to tfie NPDES'Committee and the Variance Review Committee apnually, en ofI;PfeFB- june ^^ of eaeh within'30 days of the adailability'of Champions';reports as required, ' above. The Variance Review,Committee, utilizing the-information available, will, by July III Champion �J ampion Internauonai Corporation December 13, 1996 Ms. Colleen H. Sullins Supervisor, Stormwater Group North Carolina Department of Environmental, Health and Natural Resources PO Box 27687 [ 0 d D Raleigh, NC 27611-7687 DEG 3 � 1996 Subject:: Stormwater Permit NCS000105 Champion International pp A ITYSEWON Canton, NC WAVIRLEVRE010NALOFFICE Data for 2nd year of permit Dear Ms. Sullins: As required in Champion's stormwater permit (page 7, 2.d.) samples analyzed in accordance with the terms of the permit shall be submitted no later than January 31 for the previous year. Attached is the data for the year of 1996. The cut off concentration has been met for BOD at No. 3 outfall, COD at No. 9 outfall , TSS at 5C-17 and 6-10 outfalls and fecal coliform at No. 1 Outfall . These outfalls will be sampled again in the last year of the permit. If you have questions or need additional information, please call (704) 646-2372 or 646-2255. Sincerely, LouiestJ William Chapman Sr. Environmental Engineer CEM Maintenance Technician Champion Internation ooration copy: Mr. Roy Davis North Carolina Department of Environment, Health and Natural Resources Water Quality Section t 59 Woodfin Place Asheville, NC 28801 Mr. William Manzer Vice-President-Operations Manager Champion International Corporation PO Box C-10 Canton, NC 28716 c:\flj\doc\strwate\monrpt96.doc STORMWATER DISCHARGE OUTFALL(SDO) MONITORING REPORT PERMIT NO.NCS 000105 SAMPLES COLLECTED DURING CALENDAR YEAR: 1996 (all samples collected during a calendar year shall he reported no later than January 31 of the following year) FACILITY NAME COUNTY Haywood PER A SON C01,1,1?CTINC MPLF(S)_ 7 1 am a haom ll PHONE NO.( 704 ) 646-2318 CERTIFIEDLABORATORY(S)_Hydrologic Lab# 47 Lab# (SIGNATURE OF PERMITTEE OR DESIGNEE) By this signature,I certify that this report is accurate Part A:Specific Monitoring Requirements complele In the best of my knowledge Oulfall 'I DatC y tf i MR 501150 W;' i i No: SamDle`:> .Total p C mom; h 4 e L Collected Flow a 0. . coed o f�i fo.rtn ": r` m o/d il/ r a MG a r '1°col• 100 9-2 -96 0,0100 500-0 2 6-4-96 0,3328 3 6-4-96 0,3586 0 460 4 9-2 -96 0 0 23 762.0 5 9- 6 5-6-9 7 5-6-96 0,7308 8 5-6-96 0,0438 176.0, 9 5-6-96 0,0002 0 5B-20 9-2 -96 0,0269 11 .6 6-4 9-2 -96 00034 90 0 Page I of 2 Form MRNCS Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_yes -.no (if yes,complete Part Il) Part It: Vehicle Maintenance Activitv Monitorine Re uirements Ou/fall Date, : s E. 50050 - 00556:' 00400 01051 38260 No. Sample Total Flow Oil and Grease Lead, Total Detergents pH New Motor Oil F, Collected <;: @! Rcrnverablel• ' (MBAS)2 Usage mo/dd/ rrtc�: MG•x m ugn m unit al/mo No vehicle maintenance activity conducted within any stormwater drainage area Footnotes: I Applies only for facilities at which fueling occurs. 2 Detergent monitoring is required only at facilities which conduct vehicle cleaning operations. \STORM EVENT CHARACTERISTICS: Dale 5-6-96 Date : 9-a1 �6 Mail Original and one copy to: 0,26 Total Event Precipitation(inches): inches) Attn: Central Files Event Duration(hours): 7,33 1 .75 hours) DEIINR Division of Environmental Mgt. (if morg tlenffe storm event was sampled) P.O. Box 29535 Date Raleigh,NC 27626-0535 Total Event Precipitation(inches): 0.14 Event Duration(hours): 0 25 "I certify,under penally of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete. 1 am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of Permiltec) (Date) Page 2 of 2 Form MRNCS Canton Mill Box C-t 0 Canton,North Carolina zan e Champion Champion International Corporation �jf December 18, 1996 wqF O �yEVrE�EPlrq(� FF� Mr. Billy Ray Cameron NC Emergency Response Commission NC Division of Environmental Management 116 West Jones Street Admimstratton Building Raleigh, NC 27603-1335 RE: Release of Sodium Hydroxide on December 17, 1996. Dear Mr. Cameron: Champion International is providing written notification of a release 3760 pounds of sodium hydroxide at the Canton Mill on December 17, 1996 at approximately 1:12 pm EST. The spill occurred as a result of a check valve cracking upon start up of Brown Stock Washing System. The material containing sodium hydroxide was contained on a concrete pad and drained to the mill's NPDES permitted wastewater treatment plant. The spilled material was neutralized once it entered this system with no adverse impacts to the treatment system. Additional information concerning the release is attached. If you need further information, please contact Robert Kahle at (704) 646-2747. Sincerely, T Robert Kahle Jim Giauque Advanced Environmental Engineer Advanced Environmental Engineer Attachment copy: Mr. Keith Haynes Environmental Specialist Division of Environmental Management Water Quality Section 59 Woodfin Place Asheville, NC 28802 Mr. Nolan Palmer Haywood County Emergency Management Commission 2143 Asheville Road Waynesville, NC 28786 NOTIFICATION REPORT FOR SPILL/RELEASE 1. Name of Chemical: Sodium Hydroxide 2. Is substance an Extremely Hazardous Substance?: No 3. Caller's Name and Position: Robert Kahle Advanced Environmental Engineer 4. Company where release occurred: Champion International Corporation 5. Address of company, including county: 175 Main Street Canton,NC 28716 Haywood County 6. Media into which release occurred: Concrete, then to mill NPDES Permitted wastewater treatment plant 7. Quantity released: 3760 pounds 8. Date, Start and Stop of release: 12/17/96 from 1:12pm to 1:26pm EST 9. Causes and sources of release: Start up of the No. 1 Fiberline Brownstock Washing System resulted in a dilution pump "hammering'; which caused the adjoining check valve to crack. The pump draws weak black liquor containing sodium hydroxide from the No. 1 Seal Tank. The spilled material was contained on concrete and drained via a u-drain to the mill's wastewater treatment plant where it was neutralized. 10. Action taken to respond to release and status of actions: The release was stopped by closing a manual valve located inside the building adjacent to the pump. The wastewater treatment plant personnel were notified. No adverse impacts on this NPDES-permitted system were identified. Also, there were no off-site impacts. The check valve was replaced and the area around the r spill was washed up with a water hose. 11. Other notifications made: National Response Center; December 18, 1996, 9:00 am EST to Mrs. Sanchez. Report 9370801 U.S. EPA Region IV Emergency Response Hotline, December 18, 1996, 9:03 am EST NC Division of Emergency Management; December 18, 1996, 9:07 am EST to Mr. Keith Haynes 12. Any injuries?: No 13. Name and telephone number of person to contact for further information: Robert Kahle (704) 646-2747 14. Action taken for clean-up: Area around spill was washed up using a water hose and draining to the wastewater treatment plant. 15. Does release require written notification under Section 204 of Emergency Planning and Community Right to Know Act (Title III SARA)?: NO bxc: John Bengel Derric Brown Bob Cicale Louie Justus Bill Manzer Pete Maxey Bob Williams GJCS-fa t ( q ) t�� Tennessee Wildlife Resources Agen Ellington Agricultural Center P.O. Box 40747 Nashville, Tennessee 37204 DEC 10 1996 December 7, 1996 WAr �ECTUAI/TY Reeistered Mail Ms. Beverly H. Banister, Acting Chief Water Permits and Enforcement Branch Q L Water Management Division 0 U.S. Environmental Protection Agency, Region IV 100 Alabama Street, SW L—O - 17 M Atlanta, Georgia 30303 WATER ELI MSSECfiON Mr. Steve Tedder, Chief ti I REGIONAL OFF;CE Division of Environmental Management Water Quality Section P.O. Box 29535 Raleigh, North Carolina 27626-0535 RE: Formal Objection Draft NPDES Permit and Variance Champion International Corporation Canton Mill, No. NC 0000272 Haywood County, NC Dear Ms. Banister and Mr. Tedder: On November 13, 1996, the Tennessee Wildlife Resources Agency contacted you by certified mail to advise you that on November 8, 1996, we received for the first time a copy of a final draft NPDES permit for Champion's Canton, NC, paper mill. We requested confirmation that we would have a minimum of thirty (30) days to review the draft and provide comments. As of this date, we have not had the courtesy of any return correspondence. This correspondence is a Formal Objection on behalf of the Tennessee Wildlife Resources Agency and the Tennessee Wildlife Resources Commission to both the variance and the final draft NPDES permit as proposed by North Carolina. 1. On June 6, 1996, we provided North Carolina with both oral and written objections to the proposed variance and draft permit during the public hearing in Waynesville, NC. As of this date, we have not been notified in writing by North Carolina of failure or refusal to accept our recommendations or of any rationale rOR ' ? �. Ms Beverly Banister Mr. Steve Tedder December 7, 1996 Page 2 for such failure or refusal, as required by the Clean Water Act at 402(b)(5). We incorporate and continue herein our objections, comments and recommendations of June 6, 1996. 2. Having observed the Pigeon River in Tennessee for the past thirty-six (36) months under conditions of sustained NPDES permit compliance by Champion, it is obvious that color in the Pigeon River during summer and fall continues to violate Tennessee water quality criteria of "...no objectionable color." The 50 True Color Limit as proposed for the Pigeon River at the TN/NC state line is wholly inadequate to protect the Tennessee water quality criteria for color during summer and fall. 3. Recognition by the North Carolina Variance Committee that 50 True Color Units results in sufficient instream color to require a variance from water quality standards is conclusive that such color is objectionable. By inclusion of such a variance into the NPDES permit, North Carolina in fact utilizes the permit as a vehicle to extend a North Carolina variance to thirty (30) stream miles of waters of the State of Tennessee, resulting in the continuation of objectionable color in the Pigeon River. 4. Champion is responsible for contaminated sediments in Waterville Reservoir and resultant contamination of fish in Tennessee. Champion should be required to begin the process of understanding the behavior and likely long term impact of contaminated reservoir sediments on the Tennessee portion of the Pigeon River 5. Both the variance and the draft NPDES permit are devoid of requirement that Champion further reduce color in the Tennessee portion of the Pigeon River. We conclude, as did our June 6, 1996 comments, the final draft permit requires no further advancement in color removal, maintains the Pigeon River in its current objectionable condition, and is unacceptable. Ms Beverly Banister Mr. Steve Tedder December 7, 1996 Page 3 Please enter this correspondence into the variance/permit record. Your time and consideration in this matter are greatly appreciated. If you have questions or need additional information, please contact me at 615n8l 6643. Sincerely, G Aubrey D. McKinney, Chief Environmental Services Division cc: Mr. Paul Davis Mr. Barry Turner c� December 16, 1996 Mr. Roy Davis Asheville Regional Office Division of Water Quality Interchange Building 59 Woodfin Place Asheville,NC 28801 Dear Roy: As requested, enclosed is a copy of the forthcoming article, "The River and Time: Pigeon's Toxic Past",to be published in the Forum for Applied Research and Public Policy. Please call me if you have any questions. Thanks. 9!9 �� 2 3sso DEC la '96 05:46 'ERATIONS & EM/IROWIENT SLPPO?T PA FAX TO: Roy Davis FROM: Buzz Bryson SUBJECT: Requested Address Mick Grecson asked me to send you the attached cover letter we received with the article in the Forum for Applied Research and Public Policy_ Please call me at(919)362-3551 or Mick at 362-3550 if you have any questions. Thanks. And Merry Chris n,as r r i DEC 18 196 05:46 'EP,ATIOIS & E�IR014MENT SLPPORT - P.2 K&Wp ke kf Ad,yno R.I.wx Hook ■.■. FOR ,M flute IL'Jya Nufvaal Lakratary U Mu:rox BussEu Urvu,veyw RaaQare £,Rroad,t ava.rl 1N uRRe mGE FOR APPLIED RESEARCH AND PUBLIC POLICY l i"i,1"rtmnn,1I LINDA C CAM Oak Rid,xyia.al rpkyyrvy AbleRiafnuanl G11=2 AIPIW AIW IaW"y kd RICHARD IL R"I^411SRR xma" 1py H�VhJ*RM'C SAND SANDRAS 6K� November 1, 1996 3 1 Iluiuemly clrnr.Ltrs emtc - fr°enaaxm.a rlafgm'y . NORMAH BERG Awnlam IEnA dTmr &°r B`e"B`�">bN-.,k®.fau,;m�a George Oliver Carolina Power & Light Co, elAnvavaaooxs Raleigh, NC 27602 rra,.a.d vaf.,r,;ry lf000tT D.EULfA/lD cla A1lmmlAaacrRy Dear Dr. Oliver: BEYPAILY A.OGLER Jkrtrtayfw�tla Seat°M�iveaairq B.A,s.c,.ARB lease find an advance WAS,G.[°a SfNa Enclosed UrtA\ p copy of an article RAY CLARN that will appear in an upcoming edition of Forum for awnrtr va Brtvl.Dyal1ty p.N)I.LIAM CV LDLA'LIKtt [applied Research and Public Policy: "The River and Time: MamavrAea.f�.a4:n---, pigeon' s Toxic Past, ' by Richard Bartlett. nORSxr w y>U Nra,,,,mfa a"rfRrtx vrR.Ix xaeor AM yDix. I hope you find the article of interest, I also M.r.7✓R.rrfcr R.rq Me you would consider pret:laring a brief {250 to 500 ICAIu(.5 Mimh.1IuMriE k words] -letter-to-the-editor based on the author's , 9.nA'r,a1C.wnpOOm�Dy&4er observations. For possible publication in a subsequent RUCHRUMADIInN edition, we need to receive copy by February 13, 1997. wr1T w mAmYa°yA..emr.a ApCR-M IL XeCH r MCA.a` ` I have enclosed a recent edition of Forum for. your Wh AWhx Na,iaaarretro,aeap review which contains some previously published letters- IONAMANxN( FS oahrrai,mrrrrN fdwfma to-the-editor. if you have any questions or would like IRRIQLN Un( 1tYmnry m - I additional information, please contact e at RATxnrnlI.uRsox (423) 974-4251. rgnnnmc 15�iy,Lxbnny LO[ILS1.LAxgyxeJrin A24T9rrfLabda»ra Sincerely, IE.I.ux MADRweEiM .AuvrAmnu(bRpn Oaniekchaffer NAPIERTI=MYNOYBLLR MUCH rlAsafxl Rrnc:Marr P"WerF,N:AMrurc Editor-in-Chief ALLAN G.rumipum 1✓ '' �,ivw SmN Dai,crsily ' rt wRII.&hA'm�.y DS/Cbg UAVIrMREILMLtw`'rlaAvawy Enclosures I:x881ann.nicHmottD Aaweiun4 NF.ara Uxiueasrmc Lac JAIM n.r MA.Il[M Npp lywv SMART A.ROSENFIRM ItrgNmlTWnx.Ia,gIH d5rur<y'Ire.Le: R.NEIL SAMPSON Aana Z&,"AM.Aal e PRANCPS R SHAMES G,A R'v{rsiAtiavlfaWnlorp N 6dirfvipl Offim;Energy,EnvGonrneai and Eewwws C; Ier,Tim Uaivr s4 d TLnncasec,Boo Healey Sir.,Suite 311,ftnoxvillS M ANSON YAN FLEET TN 379964134,Teluphoau(423(9744Z51,Pax(4231 974,8491,a-mail:Pomm@eeragw.Utk.edu fYnw.nimti,m A mriutc ON.dBR'1'8 Y,nrrE ■ 8usineaa Olflcer Executive 5denees Instltute,1005 Misulu i Avenue,Davcn ort,IA 52803,Tile hone(319 324.4463 .Inaa.,.Rywczfmma iPP P n 1 1'XOAUBI.WILEANxS m rra Rxr�r Am;,.Armea,mary n Publication oJOah kud'e NrLionaf laboratory and The Univeniy a77krBttuee's Sfarg;EnvirurRnwl and RGtaare[4 Can[rr �3Y 1 P.2 I. II__ ..xussRLL ■ V RU IVp✓J 1�A r aia,d•1nwN � 12i N➢hRR WBDf FOR APPLIED RESEARCH AND PUBLIC POLICY LINDA C G W DL RmW.AtVi°W 14bW1.V 6N'hma/DuvN C20MRAIMY AII/CAy ",,ra HICIIAROaR JILSRR Nttlnu Ip.yr R yuaA Mr•Mrc UNDRS.Rl STS Abd,—wl. November 1, 1996 lln y c11M1=BURG JtuH.n,N,v u,uw oy N KMMI BURG AwYlxe R,nles4 r)Ax R aukQ�Gk kD,r,O LLvvaim Vtp�D4 w.Bn7 A1i°ni v.irvulr IIARYRY BROOKS ua,�e IA.r,e,;y HOtnmr D.BuL crmtnlm,°u,°.s.,Ry REvMY A.CIGUR nrt,�s,va,sam 1Ari.°,.iy B.Km .wvu p copy of an article tm. GerMA,m.uAAr Enclosed lease find an advance HAY ClARA that will appear in an upcoming edition of Forum for c.,rwwRnvic p,mRy E.WILLIAM L'f,LeltA= Applied Research and Public .Po2jcy. HThe River and Time: HORRKI Aw1 A W A'NI rrc4'°ryaA"""` Pigeon' s Toxic Past, • by Richard Bartlett. NU ' 11Nwnm/a Mr Nner SM.I.IAM fulAtHand ndn,lwinvr la 6x.•a I hope you find the article of interest. I also adsW.GIL' hope you would consider orenarin a brief {250 to 500 BS W. ILTMIBR .irR•e Ttlmhw mvirr.N words) 1Ptter-to-the-editor based on the author's OIUHLEs coaunun s•rrHrfA cay.�ys,.rti.. observations. For possible publication in a subsequent xveKn;' �.�N edition, we need to receive copy by February 13, 1997. M)CNAFL U.HICH r Nlrnc,l.s. ` I have enclosed a recent edition of Forum for your dR lr n.NIRS'r � "°""�•""°°" °� review which contains some previously published letters- ii;niaiirRnrRmawfirtl, to-the-editor. If you have any questions or would like LP.LINARI] HYMAN additional information, please contact me at RATHnvN AURsoN (423). 974-4251. Y,.na..°eda�ra,ro„Ry 1A11LS .LAx4RHITrp "M �l/w w°^ Sincerely, BuBU MAC.Em I➢IM SwrlAMiu,C41YH° . TSD NAPI➢N Ohm 4°lr ffuirT,eT/ TIMERYNOYRLLR Rud« n3ucx r,nsRaanxCKI Mu°Lyy„°.I Oanie#1 Schaffer RAaalc,r PoWMh,dn Mi,u,r Editor-in-Chief AI G.rUUIPIIM 4�4;iwn.9t,m Ucnr,ily 8 BwUNTOUR r N DS/cbg URNID HER'HLB Enclosures JoL A.ke Natianef GEavtvy CHE312RR nICI1MOIID 4"vsiume W61,.c VnirrNi4,r,/ ' IAMRS n,n,wrt.,tlwr P�,rrrry hail w A RO'aNFBLD ItrTtvytl TWrrAj114, ti rvlrbit(Irr. R.NEWSAMPSON Artrcn:w tLratry Aastelwlav FRANCES H SRAKrLn rhv<Hid"`^t",°",/adni'°'I' ■ 6ili,orial Uijce:Energy,EnvirOluueal and Aeaou,cHs CuDley The llnivcrnity uF'hmlB3ce,e0o 1{Lv]Ly Sir.,Suite 311,1CDeravillt hlAN90N YnN FLRer TN 379964134,7L•lc hoax 4E1 974-4251,Fa: 423 974-8491,a-mail:Ibmm@cera¢w.utk.edu ILn. druGw,l�orut P I ' I I 1 VI I.88h'1'P.wHrrR ■ ewinen office.,Executive Sameas lnstltute,3006 MI,d"ippl Amiuc,Davmpost,1A 52803,7hlephond(3191 324-4403 THOMA3J.Wu.14lNK3 ,xD Htkr AV,IimlfuAwaurT A Publicarion o(oak RickE National ZaboralnTy and 77Ke University ol7bimrstee's Rwgy,SAvimu tand Re umas Canter In the early 20th century,after a brief period as a mountainous retreat for some of the nation's wealthiest families, pulp and pa- per manufacturing supplanted tourism as the Pigeon River basin's primary industry. In fact, Champion's Fibre Mill was prob- ably the largest pulp mill in the world when it became operational in I908. If we include purchases of wood and other locally produced products used in the manufacture of pulp and paper, this industry dominated a region far larger than the area defined by the basin WN itself. Meanwhile, the damage done by the mills' liquid effluent defined a larger region still, ex- The River and Time. Carolinng aintoCobout 65 keCoes rnty,Teom Ten- nessee. into Cocke County,Ten- Pigeon's Toxic Past neInt In the late 19th and early 20th centuries, cash income was des- perately needed by the mountain people of southern Appalachia. Richard Bartlett is professor emeritus of history at Florida State Expanding families and shrinking University in Tallahassee, Florida. patrimonies ensured a diminish- ing agricultural base. As a conse- quence, cash was scarce, educa- The 660-square-mile Pi- continuing through the county tion poor, and medical facilities geon River basin in west- seat of Newport (population inadequate. ern North Carolina and 7,000), to its junction with the By the early 20th century, northeastern Tennessee includes a French Broad. Just beyond, the mountain people were in desperate spectacular gorge, high moun- French Broad River runs into need of a stable economic base. tains, and lush timber stands.I artificially created Douglas Lake. Enter the pulp and paperindustry.2 North Carolina's Haywood This well-watered, richly for- County, home to 47,000 people, ested mountainous region would Propensity for Pulp boastQ.8 peaks rising 6,000 feet seem to be ideal for a flourishing above ea level. It receives 50 tourism industry. In fact,along a By the turn of the last century, 2`\ inches of rainfall each year that 5-mile stretch through Cocke the exploitation of Appalachia's help fill several freshwater tribu- County,Tennessee,the river cre- natural resources,especially coal taries, all but one of which flow ates rolling rapids that spawn and timber,had been progressing \113`,, into the Pigeon River. some of the nation's best for several decades. Concerns of From there, the Pigeon River whitewater for rafters, kayakers, the region's few conservationists flows across the state line into andcanoeists. were muted. In fact, state gov- Tennessee's,Cocke County. By Until recently, however, the emments either ignored the ex- the time it reaches the tiny mu- river's usefulness as a recreational ploitation or,more likely,encour- nicipality of Hartford(population resource has been limited because aged it. Indeed, when the paper 500), the river flows placidly, of the pollution its waters carry. industry expanded at a phenom- 88 FORUM FOR APPLIED RESEARCH AND PUBLIC POLICY/WINTER 1996 a - 4 r enal pace at the turn of the cen- who needed a steady source of ent carried off by the Pigeon tury, and pulp and paper entre- pulp for his Champion Coated River. preneurs cast covetous eyes on the Paper Company in Hamilton, Thomson had settled on Can- great forests of Southern Appala- Ohio. By 1905, he was actively ton because land was abundant chia,state governments were there purchasing thousands of acres of and available, as were the pure to help them exploit the resource. North Carolina timberland. He waters of the Pigeon River. Be- The behavior of North Caro- also was surveying eastern Ten- yond that, he had already pur- lina's state government typified nessee for a suitable location for chased thousands of acres of tim- such cooperation. In 1901,Colo- his proposed mill. ber, which were ready to be cut. nel S.A. Jones of Waynesville Many still believe that Thomson The Southern Railroad reinforced secured passage through the faced no opposition in locating his Thomson's choice of Canton by state's general assembly of an"act pulp mill,but that was not the case. agreeing to haul wood and fiber to encourage the building of pulp In fact, handed-down stories in and construct necessary trackage and paper mills and tan- Cocke County,Tennessee,relate at a reasonable cost. neries in the counties of Haywood how he approached some of the In the 1900 U.S. Census, Can- and Swain." The act stipulated: county's large landowners for the ton boasted a population of 230 that every corporation, com- purchase of land along the French residents. By 1910, two years pany,or firm who may expend Broad River for his mill. Though after the mill became operational, one hundred thousand dollars environmentalism had yet to be the city's population had grown in establishing a factory to con- bom, these landowners knew of to 1,393.1 vert wood into wood pulp shall the stench and dirtying of the wa- Though Thomson had won the not be subject to any criminal prosecution for the pollution ter that would accompany pulp North Carolina legislature's of any watercourses upon production, and so, as the story blessing, he was not finished which such factory or factories goes, they refused to sell.4 safeguarding his business. The are located,and the measure of What little opposition that sur- legislation merely protected his damages to the owner or own- ers of lands overwhich the wa- faced, however, was of minor company from injunctions that ter flows from such factory or consequence in the face of the could halt production; thus factories shall be confined to overwhelming support and enthu- Champion Fibre was still vul- actual damages, to be ascer- siasm for the mill. In fact, a bid- nerable to lawsuits. tained as provided by law. dingwarof sorts began,with vari- To protect himself from legal The act goes on to say that, in ous localities offering themselves action, Thomson sent his agents case of a lawsuit, the company to Thomson. The mill could be downriver as far as the mouth of could file a bond and in so doing located in Cocke County, the Jonathan Creek knocking on was relieved of any threat"of re- Newport Plain Talk editorialized doors of nearby residents and straining order or injunction." In in early 1906, "if the people act obtaining their signatures on a other words,while a lawsuit was promptly. The entire county document"releasing Mr.Thomson underway,operations could con- would be greatly benefited." and his heirs...from damages on tinue.' The newspaper, in fact, urged account of the pollution of the Such favorable legislation the county's Board of Trade to waters of the Pigeon." came about because rumors were pursue the mill "with all haste Prosperity was on the way to rife that a paper manufacturer was and energy possible."' Haywood and adjoining counties. studying the area as a potential In fact, the rumble of prosperity site for a pulp mill. Indeed,com- Carolina Wins Out reached as far west as Cocke mon knowledge at the time held County, Tennessee. Lumber that pulp and paper industrialists At it turned out,Cocke County camps on Champion land em- or their agents were investigating did notgetthemill;thathonorwent ployed scores of laborers. Inde- the lay of the land,forests,rivers, to Canton, North Carolina, 60 pendent farmers cut their stands railroad facilities,and labor force. miles upstream. In fact,all Cocke oftimber to Champion's specifica- One of the tycoons investigat- County received after the plant tions,and the company paid them ing the area in 1901 was Peter G. became operational in 1908 was cash for their wood. Employees Thomson, an Ohio industrialist the colored,foamy,smelly efflu- at the huge mill received steady BARTLETT: THE RIVER AND TIME: PIGEON'S TOXIC PAST 89 • - r paychecks,and the pay was good. W. Hooper, who had been born tently below the 50-unit color Economically and socially as in a cabin overlooking the Pigeon limit required by Tennessee law. well,the coming of the Champion River,promised to push litigation The water does not smell as bad mill was a boon for the region. during his term of office (1910- asitdidinthepast,norisittopped Only the environment suffered, 1914). Despite his pledge, anti- with as much foam. and in the climate of opinion of pollution legislation never materi- How does it happen that today 1908, the people of Haywood alized. the Pigeon River flows cleaner County and North Carolina ac- In the pages of the Newport despite decades of Champion's cepted the stench and the pollu- Plain Talk of April 18, 1912, the denial and recalcitrance? Did the tion as a suitable trade-off. They sinking of the Titanic took sec- states of North Carolina and/or were delighted and proud to have and place to a Champion an- Tennessee bring this about? Did the new industry in their domain. nouncement that the company was a popular uprising of environ- The Pigeon River System is an making massive changes to cut the mentalists force Champion's interstate waterway, originating pollution even though the com- hand? Was the federal Environ- high in the mountains of North pany insisted the effluent was mental Protection Agency(EPA) Carolina and flowing across the harmless in spite of the stench, instrumental in forcing the clean- state line into the Volunteer state. the color,and the foam. Regard- ing of the Pigeon River? Before the Walters' project, less of Champion's claims, the No. In fact, none of these fac- which dammed the Pigeon and pollution continued.' tors turned the tide. Champion created Waterville Lake in the late The company litany continued was motivated more by an inter- 1920s,the polluted Pigeon River for decades: The pollution was est in modernizing and boosting flowed unrestricted into Tennes- nontoxic and harmless; the com- its plant's efficiency than by see and through the heart of pany was doing everything to cleaning up after itself. Some Newport. For decades,pollution limit it; and when new technol- observers predicted that the was so bad that Cocke countians ogy was developed, Champion company's modernization pro- dubbed the Pigeon the "Black would use these advances to cut gram would cost the region 300 River." the pollution. to 500 jobs. However,as of Feb- In addition to its offensive Not until 1983, 74 years after ruary 1996, Champion had an- color,the stench,especially on hot its initial attempt, did Tennessee nounced less than 65 layoffs" summer days,was almost intoler- mount a strong legal case against Indeed,a cleaner Pigeon River able,and the foam was sometimes Champion. North Carolina, is little more than a fortuitous two to three feet thick. Few in- which continues to reap the finan- byproduct of Champion's yen to dustrialists wanted to establish cial benefits from the pulp mill, update its plant. factories along such a stream,and sided with Champion and has It is a fact that improved tech- tourists took one whiff and packed continued to do so. nology aimed at efficiency and their suitcases. economy in the pulp and paper Guided by their disgust over Pigeon River Today industry usually results in less the condition of the Pigeon,Ten- pollution. This is especially true nesseans voiced their protest. Today, more than 80 years af- at Champion's new oxygen- Time and again,state representa- ter the mill opened,the waters of delignification process, which tives,usually from Cocke County the Pigeon flow substantially reduces but does not eliminate and Newport, introduced bills in cleaner, though still not clean chlorine-derived effluent. the general assembly imploring enough. The water's brown hue, Scientific investigations have the attorney general to bring suit measured in color units near the a place in the story because the against Champion for damages. Tennessee line, differs greatly effluent, long described by the In 1909, just a year after the from day to day and would differ company as harmless, has been plant opened,the attorney general from hour to hour if measure- proven extremely toxic. More- promised to bring suit against ments were taken that often. over, most of the cutting-edge Champion but failed to do so be- In the past,measurements com- scientific research on pulp and cause of lack of funds. Ten- monly read as high as 200, but paper mill toxins continues to be nessee's colorful Governor Ben today they are registering consis- negative. This is especially true 90 FORUM FOR APPLIED RESEARCH AND PUBLIC POLICY/WINTER 1996 of the breakdown of chlorine, a bleaching technology would be will be granted, but all signs are chemical used heavily in paper used at the Canton mill. Accord- that Champion will continue its bleaching. ing to the company's news re- efforts to clean the river. Mean- Throughout this process,envi- lease,the new system,at a cost of while, the future of Haywood ronmentalists—locally the Pigeon up to $30 million, should further and Cocke counties looks bright. River Action Group, the Dead clean the Pigeon River.' The climate of opinion con- Pigeon River Council, the Foun- What of the people of the Pi- cerning uses of the Pigeon River dation for Global Sustainability, geon River basin? Tourism is has changed, and a new era is be- and the Izaak Walton League— clearly taking a more important ginning for the people of the Pi- have maintained a drumbeat of place in the region's psyche,and geon River basin—one in which protest, some since the mid- certainly in its economy. Tourist economic developmentand envi- 1980s. Yet,there is no proof that shops now line the main street of ronmental protection will proceed this sustained opposition moti- Waynesville. Folkmoot,an inter- hand in hand. vated Champion's corporation national dance festival, is held officials to launch the plant's every summer in Haywood SEEN modernization scheme. County. There is an annual vin- When Tennessee began litiga- tage car meet, balloon rallies at NOTES tion against Champion in 1983, Maggie Valley,and plans for the the situation had changed drasti- Smoky Mountain Railroad to en- 1. For a fuller discussion of the cally since the first demand to sue ter Waynesville. issues raised in this essay, see Richard Bartlett, Troubled Waters: in 1909. One difference was the Whitewater rafting, always a Champion International and the stable of rules and regulations to potential tourist attraction, has Pigeon River Controversv (Knox- which the mill must adhere. When come into its own for two reasons. ville: University ofTennesseePress, North Carolina ignored its own First, Carolina Power and Light 1995). regulations by issuing variances, Company, the local utility, now 2. Ronald D. Eller, Miners, and when there was finally a fed- periodically releases water from Millhands, and Mountaineers: eral EPA to back up Tennessee's Waterville Dam for the use of Industrialization ofrheAppalachian assertions, Champion's situation whitewater runners; second, the South, 1880-1930 (Knoxville: changed. Pigeon is now sufficiently clean University of Tennessee Press, to support a profitable rafting in- 1982). Champion Today dustry. 3. State of North Carolina, As a result, a dozen rafting Sessions Laws, 1901, pp. 917-918. 4. Interview with Charles Champion officials are facing companies have set up shop, and Moore,formerly executive officerof a new era in which environmen- more than 30,000 rafters and Cocke County,September 14, 1989. talism will not go away,in which kayakers enjoy the thrills of the 5. Plain Talk (Newport, TN), an increasing population needs Pigeon each summer. Champion circa 1906. more potable water,and in which is playing a role in the region's 6. The Log (House Organ of scientific discoveries link more tourist boom by sponsoring an Canton Mill), December 16, 1926. and more carcinogens to chlorine annual whitewater competition. 7. Ben W. Hooper (Edward and its derivatives. Yet, with barely half the per- Robert Boyce, ed.), The Unwanted The situation has so changed sonnel it employed during the Boy: The Autobiography of Gover- that the corporation finally isfac- 1980s, Champion will watch its or Ben W. Hooper (Knoxville: ing reality—that is, it's finally influence on the economy, soci- University of Tennessee Press, seeing the light. Instead of being ety, and politics of the region 1963), pp. 6-16. 8. Enterprise Mountaineer dragged kicking and screaming decline as tourism rises. In fact,its (Waynesville, North Carolina), into the 21st century, Champion application for anew North Caro- February 23, 1996. may be taking the lead in ending lina water-release permit in 1996 9. Champion news release, pulp and paper company pollution. has been met with the usual com- June 14, 1994; Mountaineer, June An indication of this change plaints: The Pigeon remains pol- 15, 1994; Newport Plain Talk, occurred in June 1994 when luted, smelly, and discolored. editorial,June 27, 1994. Champion announced that a new No one doubts that the permit BARTLETT: THE RIVER AND TIME: PIGEON'S TOXIC PAST 91 Mate of North Caroni .a 1~ Department of Environment, Health and Natural Resources 1 • Division of Epidemiology _ James B. Hunt, Jr., Governor r� Jonathan B. Howes, Secretary 1D E H N FR Michael Moser, M.D., M.P.H. December 9, 1996 Mr. Roy Davis D O D Asheville Regional Office DEC I I Interchange Building, 14 59 Woodfin Place Asheville, North Carolina 28801 AHATERtQREGOI NAiCOrFICE Dear Mr. Davis: At your request, I have provided a risk assessment based upon my review of the mercury in fish tissue sample results collected on October 7 and 8 from the North Carolina section of the Pigeon River (see enclosure). This sampling was conducted in response to growing concerns over possible mercury bioaccumulation in the Pigeon River. The mercury levels found in the fish sampled were low and comparable to levels expected for fish across North Carolina. None of the sixty-five samples exceeded the North Carolina action level of 1 mg/kg for issuing an advisory. Consumption of the mercury- containing fish tissue (ranging from 0.02 to 0.54 mg/kg) should not pose a health risk. A fish consumption advisory, with respect to the mercury levels found, is not warranted. However, the current fish consumption advisory, due to the presence of elevated dioxin levels in carp and catfish, should be followed : "Carp and catfish in the Pigeon River may contain low levels of dioxins and should not be consumed. Consumption of all other fish species is not considered to present a health risk and are not affected by this advisory. Swimming, boating, and other recreational activities present no health risk." Call me if you have/any questions at 919-715-6429. c I air- i• r, Sincerely, . V w� r� Luanne K. Williams, Pharm.D., Toxicologist Yh 0 Medical Evaluation and Risk Assessment Branch t� Occupational and Environmental Epidemiology Section KW:Ip Enclosure P.O. x 27687, aleigh, UP C An Equal Opportunity Affirmative Action Employer North Carolina 27611-7687 50%recycled/10%post-consumer paper Stag-North Caroli. ._ epartment of Environment, ealth and Natural Resources 1 • Division of Water Quality _ James B. Hunt,Jr., Governor Jonathan B. Howes, Secretary p E H N R A, Preston Howard, Jr„ P.E., Director December 6, 1996 Mr. John J. Prvately Champion International WWTP Lab. P.O. Box C-10 Canton, NC 28716 SUBJECT: Additional Parameter Certification CONDUCTIVITY Dear Mr. Prvatelv: The Department of Environment, Health and Natural Resources, in accordance with the provisions of 15A NCAC 2H .0800, is pleased to certify your laboratory to perform additional analytical parameter(s). This chanqe to vour certification is effective December 3, 1996. Enclosed is an amended certificate that includes the new parameter(s). The same requirements applying to your present certification are applicable to the new parameter addition(s). Please review this certificate to insure that your laboratory is certified for all parameters required to properly meet your certification needs. Contact us at (919) 733 3908 if you have questions or need additional information. Sincerely, Bernard E. Sims, PhD Chief, Laboratory Section ` C BES:iwm Q`�G +'A w p(O Enclosure & cc James W. Meyer �P William B. Edwards, Jr. Gary W. Francies -Ashville Regional Office rR� Laboratory section,4405 Reedy Creek Road, �I��y.� FAX 919-733-6241 Raleigh,North Carolina 27607-6445 11 , �� An Equal Opportunity/Affirmative Action Employer Voice 919-733-3908 50%recycles/10%post-consumer paper Attachment North Carolina Wastewater/Groundwater Laboratory Certification Certified Parameters Listing Lab Name: Champion International WWTP Lab. Certificate Number: 198 Address: P.O.Box C•10 Effective Date: 1/1/96 Canton,NC 28716 Expiration Date: 12/31/98 Date of Last Amendment: 1216196 The above named laboratory,having duly met the requirements of 15A NCAC 21-1.0800,is hereby certified for the measurement of the parameters listed below. CERTIFIED PARAMETERS INORGANIC BOD COD COLIFORM,FECAL TUBE _ COLOR,PLATINUM COBALT CONDUCTIVITY HARDNESS,TOTAL AMMONIA NITROGEN pH .RESIDUE,SETTLEABLE RESIDUE,TOTAL RESIDUE,DISSOLVED 180 C RESIDUE,SUSPENDED Thic reninrarinn runuime maimm�nu of en onnnnm6ln nunlin,�eo,mngo�rnnmT uen of annrmmd motbndnLvv and<al'mlarmm nednm.anr.nn n•mL,alinn eomnb< I<Mmtndce er. State of North Carol � Department of Environment, Health and Natural Resources • Division of Water Quality IV r James B, Hunt, Jr., Governor r -a A. Preston Howard, Jr., P.E., Director v " 7 Asheville Regional Office December 2 , 1996 MXK0iRANDIIM TO: Steve Tedder, Chief Water Quality Section FROM: Roy M. Davis, Regional Supervisor ^� Division of Water Quality SUBJECT: Sediment Study Waterville Reservoir Carolina Power & Light Company Haywood County On September 20, 1996 Keith Haynes, Forrest Westall and I visited Knoxville, Tennessee to discuss the draft Champion NPDES Permit with Paul Davis and David McKinney of the State of Tennessee . The purpose of the meeting was to give us the opportunity to inform the State of Tennessee how we thought the Division of Water Quality would respond to comments offered by that State at our Champion NPDES Permit public hearing. One request made by Tennessee at the hearing was that Champion be required to study the fate of dioxin found in the sediment in Waterville Reservoir. We told Paul and David that we felt we had no legal basis to include such a requirement in Champion' s discharge permit . We also told them that Carolina Power and Light Company' s (CP&L) Federal Energy Regulatory Commission (FERC) order for the Walter' s Power Complex which includes Waterville Reservoir requires CP&L to submit to FERC by the last day of 1998 a study of sediment bound dioxin in Waterville Reservoir and a recommendation regarding further action, if any, to address dioxin contaminated sediment in Waterville reservoir. We told Paul and David that we would approach CP&L to see if they were willing to listen to what Tennessee might recommend in the way of a sediment dioxin study. On November 20, 1996 Keith, Forrest, Bryn Tracy and I met with Mick Greeson and Phil Lucas of CP&L. At the conclusion of the Interchange Building,59 Woodfin Place N���C FAX 704-251-6452 Asheville, North Carolina 28801 11 , �r An Equal Opportunity/Affirmative Action Employer Voice704-251-6208 N 50%recycles/10%post-consumer paper Steve Tedder Memorandum December 2 . 1996 ---- - -- Page Two meeting Mick was inclined that CP&L would update an earlier Waterville sediment dioxin study. Without making a commitment, Mick thought CP&L might be willing to look at the same lake stations, (approximately twelve in number) , as were looked at in the earlier study. This would allow comparison from the standpoint of amount of deposition since the earlier study and dioxin currently present in the surface sediment . Bryn felt this is the most useful thing CP&L could do. Mick also felt that CP&L might be agreeable to sitting around a table with Tennessee and Champion and receiving their input . We plan to call such a meeting sometime after the permit/variance issues are settled. I would want DWQ to know what it would like CP&L to do when we meet and therefore I will be discussing this matter with Jimmie Overton. We had a much better meeting as a result of Bryn Tracy' s involvement and I very much appreciate his being with us . xc : Harlan Britt Jimmie Overton Bryn Tracy Trish Macpherson Forrest Westall Keith Haynes wanton Mill 3OX C-t0 ,anton.North Carouna 287;E UUyampion - ampion Internatlonai Carporanon D ASHE`� E RE6n��F NICE December 2, 1996 Mr. Billy Ray Cameron NC Emergency Response Commission NC Division of Emergency Management 116 West Jones Street Administration Building Raleigh, NC 27603-1335 RE: Release of Sodium Hypochlorite at Champion International Corporation's Canton Mill on November 26, 1996 Dear Mr. Cameron: Champion International Corporation is providing written notification of a CERCLA hazardous substance release at the Canton MID which exceeded the reportable quantity.The release was discharged from a storage tank to a concrete containment area. It was then neutralized in the on-site Wastewater Treatment Plant and none of the released material went off site. The information concerning this release is attached. Please contact Susanne Koelsch at(704) 646-2381 or Jim Giauque at(704) 646-2028 if you need additional information. Sincerely yours, Susanne Koelsch / ames A. Giauque Sr. Environmental Engineer Adv.Environmental En eer Attachment Mr. Billy Ray Cameron December 2, 1996 Page 2 xc: Mr. Keith Haynes Environmental Specialist Division of Environmental Management Water Quality Section 59 Woodfm Place Asheville, NC 28801 Mr. William Manzer Vice-President, Operations Manager Champion International Corporation Canton Mill PO Box C-10 Canton, NC 28716 Mr. Nolan Palmer Haywood County Emergency Management Commission 2143 Asheville Rd. Waynesville, NC 28786 NOTIFICATION REPORT FOR EMERGENCY RELEASE OF HAZARDOUS SUBSTANCE 1. Name of chemical: 16% Sodium Hypochlorite solution. 2. Is substance an Extremely Hazardous Substance?: No 3. Caller's name and position: Susanne Koelsch Sr. Environmental Engineer 4. Company where release occurred: Champion International Corporation 5. Address of company, including county: Box C-10 Canton, NC 28716 Haywood County 6. Media into which release occurred: The sodium hypochlorite solution was released onto a sealed concrete floor inside a tank farm containment area. 7. Quantity released: Approximately 8800 lbs of sodium hypochlorite was released. 8. Date and time of release: The release occurred on November 26, 1996 between approximately 2:55 pm and 3:25 pm. 9. Cause(s) and source of release: The release occurred shortly after refilling the bulk storage tank when a gate valve on the tank failed. This resulted in the loss of approximately 75% of the tank volume to the containment area. 10. Actions taken to respond to release, and status of actions: An operator went to inspect the tank when an operator in the control room noted — that rapid drop in tank level was occurring. Because of the nature of the mechanical failure, the release could not be stopped. The operator checked that the containment valve was closed in order to keep the release in the containment area. 11. Notifications made: National Response Center: November 26, 1996 at 4:05 pm to Petty Officer Blanchard- Report#368769 Mr. John Glance of the Haywood County Commications Department, Emergency Management at 4:15 pm. Mr.Keith Haynes of the Water Quality Section of the North Carolina Department of Environmental Management in Asheville at—4:30 pm. 12. whether any injuries occurred: No Notification Report of Emergency Release of Hazardous Substance Sodium Hypochlorite December 2, 1996 Page 2 13. Name and telephone number of person to contact for further information: Susanne Koelsch 704-646-2381 14. Action taken for clean-up: The released sodium hypochlorite was metered to the wastewater treatment plant over the -course-of the next 30-hours-This sodiutn hypochlorite was treated in the-on-site - - wastewater treatment plant and none of the released material went off site. There was no adverse effect on wastewater treatment performance. The concreted area affected by the spill was washed with water to remove any residual chemical. 15. Does release require written notification under Section 204 of Emergency Planning and Community Right to Know Act (Title III SARA)?: No Agreed to Variance Conditions 11/27/96 ��J (Words recommended for removal are stricken through and additional wording is in bold:) Conditions identified below of the"Ordered" section of the variance should be modified to: «f. CONDITION 2.II II. The average daily discharge of true color for each calendar month shall not exceed 98,16 12s,434 pounds per day. The average annual effluent true color loading shall of excels cal' d by 8 pounds per day. For the purpose of this permit/variance only,-pounds _ the following equation: Effluent Flow(mgd)x Effluent True Color Level(Platinum Cobalt Units)x 8.34. ; CONDITION 4 4. Champion shall continue to study,evaluate, and pursue and operate color removal technologies and report its findings to the NPDES Committee and the Division of Water Quality in accordance with the following schedule: DATE ACTIVITY Continuing Commercial demonstration of bleach filtrate recycling (BFRTM) March 1,1998 In conjunction with the scheduled Triennial Review of N. C.Water Quality Standards the Company shall: 1. Submit a status report to the NPDES Committee on the technical, economic, and operational feasibility of the BFRTM technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2. Evaluate and report to the NPDES Committee on the application of end- of-pipe color reduction technologies and additional minimization of color losses from the manufacturing processes and raw material storage areas. The evaluation shall include an incremental color improvement analysis. This analysis will concentrate on the technical,economic,and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies and minimization efforts must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing and adopting these technologies and minimization efforts at the mill. The report will also project the expected additional color reduction for each technology and in-mill minimization effort evaluated and the maximum color reduction possible using the identified technology or action. Evaluate and-repert-0�truffflzad December 1,1998 eenelusieft of the ,Champion will Oeidp and repert eft. - - to iuily impiemeni and operaie'the b Rl.'-tecnnoiogy-as-a eeenaiem preeess on the mill's pinewood line-,unless the Company can demonstrate to the NPDES Committee that BFRTM is not a commercially viable process at this location. December 1,2000 Champion will evaluate color reduction strategies for further optimization of BERTM technology and report on the feasibility of implementation on the hardwood line. ' March 1,2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N. C.Water Quality Standards. The evaluation shall include an incremental color improvement analysis.This analysis will concentrate on the technical,economic,and operational feasibility of the application of these technologies on a continuous or intermittent basis. The intermittent application of these technologies must look particularly at periods of low river flow. The report will identify specific economic and implementation issues associated with the incremental improvement of color levels expected by installing these technologies at the mill. The report will also project the expected additional color reduction for each technology evaluated and the maximum color reduction possible using the identified technology. June 1,2001 Champion will submit a report to the NPDES Committee and N. C.DEHNR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the Variance review process (Triennial Review of North Carolina Water Quality Standards). CONDrnON 5 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee and the Variance Review Committee Water Quality Standards review within 30 days of the availability of Champion's reports as required above. The Variance Review Committee,utilizing the information available,will,by July 1,1998 make recommendations to the NPDES Committee concerning revisions to the color variance. Those recommendations will include lower limits for the monthly average and annual average color limitations applicable to the mill due to color removal performance and the Committee's position on additional revisions needed in the variance to reflect the application of BFRTM,end-of-the pipe treatment and in-mill color reduction technologies. Based on the instream color data available at that time,the Committee will also provide recommendations on the applicability of any instream color compliance point in N. C. The NPDES Committee will review the available information,the recommendations of the Variance Review Committee and the staff recommendations in proposing any changes to the variance. CONDITION 6 6. In conjunction with subsequent triennial water quality standards reviews,the Division will nominate a variance review committee. The NPDES Committee will have final approval of the selection of this Committee. Committee membership may consist of Department Staff and individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the 2 university or research communities. The Committee will also include in its membership at least one representative of Tennessee's Department of Environment and Conservation. That review committee's report and recommendation will be examined by the NPDES Committee for a decision on the adequacy .. •f'.tl:_ Tl-- .. DE-5 iC ctculdiie warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater. All revisions adopted by the NPDES Committee will required the modification of the Company's NPDES Discharge Permit. CONDITION 7 7. The variance proceeding, and the NPDES Permit Number NC0000272, shall at all-tirne be subject to reopening in order to modify the color requirements based upon the following and in association with the required triennial reviews: 1. aAny breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration,by Champion and the Division of Water Quality, as soon as they are discovered. 2. An acceptable statistical analysis of effluent color discharge data demonstrating better color removal performance than that currently prescribed in the variance and permit. 3. Successful application of end-of-pipe color reduction technology or in-mill color minimization effort that results in significant and measurable reduced mass color discharge. 3 SENT BY:CHAXP10N INTERNATI0NAL;11-26-96 ; 9;18:A11 LEGAL _AFFAIRS CHMPIM' EOHS;n 2/ 3 DRAFT 11/25/96 F. SCHEDULE FOR CONTINUED COLOR MINIMIZATION Champion shall continue to study, evaluate,and pursue color removal technologies and shall report its findings to the Division of Water Quality in accordance with the following schedule: LATE ACLTMTY Continuing Commercial demonstration of bleach filtrate recycling(BFRTM) .Tamrary 1, 1997 The average daily discharge of true color for each month shall not exceed 125,434 pounds per day, and the average annual effluent true color loading shall not exceed 98.166 pounds per day. March 1, 1998 In conjunction with the scheduled Triennial Review of North Carolina Water Quality gtandardc: 1. Submit a status report to the Variance Review Committee on the technical, economic and operational feasibility of the BFRTM technology, including those analyses prepared for other permitting agencies concerning its offsets on air emissions. 2. Fvvaluate and report on and-nf-pipe color reduction technologies and minimization of color losses from midnul'acttuing processes and raw material storage areas. The evaluation shall include an incremental color improvement analysis. The Variance Review Committee shall be made up of the same types of members as provided for in the initial variance, with the addition of a representative of the Tennessee DEC, Division of Water pollution Cnntml. June 1, 1998 Based upon the above reports,the Variance Review Committee will recommend lower limits for monthly average and annual average discharge of color pounds per day to reasonably reflect the color reduction achieved by the BFR technology or another in mill or end-of-plpc Wchaulogy. The Variance Review Committee shall submit its recommendations to the NPFDES Committee, which will take final action thereon. SENT BY:CHAIIIPION INTEMATIONAL;11-26-96 ; 9:18AIM LEGAL AFFAIRS- CHAMPION EOHS;r 3/ 3 December 1, 1998 Champion will implement BFRTu technology on the pine line if'it has proven io be a fully commercial process. December 1, 2000 Champion will evaluate color reduction strategies for further optimization of BFRT"r technology and report on the feasibility of implementation on the hardwood line. March 1. 2001 Champion will evaluate and report on crrd-of-pipe wlor reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. The evaluation shall include an incremental color improvement analysis. A new statistical analysis of effluent data will be completed by the State as to the demonstrated performance regarding color levels and loadings which are attainable in the discharge. June 1, 2001 Champion will submit a report to N,C, DEHNR,Division of Water Quality,on the comparative evaluation of the above cnllective efforts as part of the variance review process(Triennial Review)and the NPDES renewal process. During the March 1, 1998 and March 1, 2001 Triennial reviews, the State urill review the instream color data collected at all NC instream color monitoring stations specified in Itcm 1.A to determine if the variance can be revised to include a maximum instream color level or to change the point of its application, Champion International Corporation - Canton, NC Calculation of Color Limits for the Variance Based on Post CMP Performance Monthly Average Color Data SE color lbs/day Natural Log Aug-95 89,795 11.4053 Sep-95 78,026 11.2648 Oct-95 96,786 11.4803 Nov-95 97,637 11 .4890 Dec-95 83,586 11 .3336 Jan-96 101,363 11.5265 Feb-96 96,968 11.4821 Mar-96 77,639 11.2598 Apr-96 70,227 11.1595 May-96 72,694 11 .1940 Jun-96 80,560 11.2968 Jul-96 84,481 11 .3443 Aug-96 71,346 11.1753 Sep-96 90,495 11 .4130 Oct-96 78,689 11 .2733 Average 8/95-10/96 84,686 11 .34 Std dev 8/95-10/96 10,289 0.12 Skew 8/95-10/96 0.21 0.07 8/95 -10/96 99th percentile max mo 108,659 11 .62 8/95-10/96 straight 99th pet max yr 91,607 11.42 Exponent of Nat. log of 99th pet max month 111 ,572 Exponent of Nat. log of 99th pet max yr 91,255 8/l/95-10/31/96 avg daily pulp production 1,320 Post CMP max monthly pulp production 1,484 / design daily pulp production 1,420 Proposed Color Variance Limits 99th pet Max mo' 1484/1320 Monthly average 125,434 99th pet Max yr ' 1420/1320 Annual Average 98,168 SKK 11/26/96 State of North Carol'„ ,., Department of Environment, alth and Natural Resources 14 • �1 ivision of Water Quality _ James B. Hunt, Jr., Governor k inn,rest. 1 B. ! r�Howard, ., . � A. Preston Howard, Jr., P.E., Director Asheville Regional Office November 21, 1996 MR. JOHN PRYATELY CHAMPION INTERNATIONAL WWTP LAB P.O. BOX C-10 CANTON, NC 28716 Dear Mr. Pryately: Your letter dated November 19, 1996 that describes corrective actions for your analytical procedures has been received and reviewed. The actions taken are acceptable for your North Carolina Wastewater/Groundwater laboratory certification. If a future inspection should reveal that the deviations cited in the inspection report were not corrected, enforcement actions may be recommended. Thank you again for your cooperation. Contact us at (704) -251- 6208 ext . 285 if you have questions . Sincerely, Gel Gary Francies Laboratory Section CC : W.B . Edwards, Jr. James W. Meyer ,�419Mheville Fallillijignal Off'ce Interchange Building,59 Woodfin Place �Aw C FAX 704-251 6452 Asheville,North Carolina 28801 An Equal Opportunity/Affirmative Action Employer Voice 704-251-6208 r 50%recycles/10%post-consumer paper Division of Water Quality V�✓/ Biological Assessment Group VNovember 21, 1996 MEMORANDUM To: Roy Davis Regional Supervisor, ARO Q t5 Through: Jimmie Overt 1 2 s Trish MacPhe Cain RAL OFfiCE Wp1ER From: Mark Hale I,/ AStl�l E Subject: Results of DWQ Fish Tissue Mercury Assessment Pigeon River, October 1996 The following are results of the DWQ Environmental Sciences Branch assessment of mercury levels in fish collected from the Pigeon River during October 7 and 8, 1996. DWQ personnel conducted the study to examine mercury concentrations in fish from the North Carolina section of the Pigeon(above Canton to Walters Lake). The survey was conducted at the request of the Asheville Regional Office in response to growing concerns over possible mercury bioaccumulation in the Pigeon system below Canton. Sixty fish samples were collected from five stations along the Pigeon River during the study. The following stations stretched from just above Canton and the Champion mill discharge, to Walters Lake (see map). 1] Below NC 215 Bridge above Canton(at the high school) 2] SR 1513 above Clyde at river mile 59.0 31 Old Rt. 209 at river mile 52.3 41 SR 1364 at Ferguson Bridge,river mile 48.2 51 Walters Lake, river mile 39-40 Fish were collected via backpack and boat-mounted electrofishing units. Piscivores,insectivores, and/or omnivores were collected at each station, wrapped individually in foil,bagged, and transported on dry ice back to the ESB laboratory for processing. Field identifications of all fish were confirmed in the laboratory. All fish samples were processed at the ESB laboratory on October 11, 1996 and delivered to the DWQ chemistry lab for analysis of total mercury. Split samples were also prepared and shipped to Quanterra Environmental Services for analysis at the request of Champion Paper personnel. Samples sent for analysis included individual and composited fish. DWQ results show all fish from all stations contained total mercury levels below the EPA and FDA limits of 0.6 ppm and 1.0 ppm respectively. Mercury concentrations ranged from 0.02 ppm in insectivores and omnivores, to 0.54 ppm in a largemouth bass collected above Canton(see attached statistical summaries). Piscivores such as bass are expected to contain higher levels of mercury due to their longevity and trophic level. All total mercury results were comparable to "background" levels expected for fish across North Carolina. V s November 21, 1996 Page 2 Results from split sample analyses by Quanterra correlate well with DWQ data. Quanterra results were consistently higher than results generated by the DWQ lab,but were considered to be well within the same range(see enclosed Champion Paper fax,Table 1). All Quanterra results were lower than the FDA limit of 1.0, and only one result for the aforementioned bass collected above Canton exceeded the EPA screening value of 0.60 ppm. The average of DWQ and Quanterra results for the bass equals 0.59 ppm,just under the EPA screening value. Mercury levels approaching the EPA value are not uncommon in older, larger bass in systems across the state. Individual sample results from both labs remained under current FDA criteria. The current EPA screening value of 0.60 ppm was exceeded by only one individual Quanterra result. All mean mercury results for species and station from both labs were less than EPA and FDA limits. Mercury results from both labs reflect levels that would be encountered in fish from NC waters not subject to excessive discharges or impacts. cc: Steve Tedder Forrest Westall,ARO Keith Haynes, ARO Susan Wilson, NPDES Group Luanne Williams, Envir. Epidemiology Section Pigeon River Fish Tissue Stations NCDWQ Mercury Assessment October 1996 WaAn UM Mfar&Uke ra Greo Walters Lake �k (38.1) creek P (42- ) New Hepea Bridge '\FLOW Ferguson Bridge (48.2) JmaCarrs creek Old Rt. 209 (52.3) Above Clyde (59.0) YiUWall Canton,HC (633) WayneW4 A; a d Cryde,NC Below 215 Bridge WWTP creek Above Canton (54.8) Mercury in Fish Tissue Pigeon River NCDWQ, October 1996 (Results are expressed as ppm) Station and Species Mean Count Minimum Maximum Total,All species and stations 0.11 60 0.02 0.54 Pigeon River at Canton,Bass 0.42 3 0.34 0.54 Pigeon River at Canton,Hogsucker 0.06 2 0.02 0.10 Pigeon River at Canton,Redbreast 0.15 4 0.05 0.26 Pigeon River at Canton,Rock Bass 0.24 3 0.08 0.45 Pigeon River at Canton,Warmouth 0.31 1 0.31 0.31 Pigeon River at SR-1513,Blue ill 0.04 2 0.03 0.05 Pigeon River at SR-1513,Carp 0.09 3 0.08 0.09 Pigeon River at SR-1513,Bass 0.10 2 0.07 0.13 Pigeon River at SR-1513,Redbreast 0.04 3 0.04 0.05 Pigeon River at SR-1513,Rock Bass 0.03 1 0.03 0.03 Pigeon River at SR-1513,SmaUmouth 0.07 1 0.07 0.07 Pigeon River at SR-1513,Warmouth 0.09 1 0.09 0.09 Pigeon River at SR-1513,White Sucker 0.05 2 0.02 0.08 Pigeon River at NC-209,Carp 0.08 3 0.08 0.08 Pigeon River at NC-209,Bass 0.18 3 0.07 0.25 Pigeon River at NC-209,Redbreast 0.06 5 0.05 0.07 Pigeon River at NC-209,Smallmouth 0.09 1 0.09 0.09 Pigeon River dwnstrm of Ferguson Bridge,Redbreast 0.02 3 0.02 0.03 Pigeon River dwnstrm of Ferguson Bridge,Rock Bass 0.03 1 0.03 0.03 Pigeon River dwnstrm of Ferguson Bridge,Smallmouth 0.04 1 0.04 0.04 Walters Lake,Bluegill 0.05 6 0.04 0.07 Walters Lake,Crappie 0.08 3 0.06 0.10 Walters Lake,Bass 1 0.071 61 0.041 0.10 . y � Mercury in Fish Tissue: DWQ Results Pigeon River-October 1996 DATE SAMPLED DESCRIPTION SPECIES LENGTH(cm) WEIGHT(g) SAMPLE TYPE Hg (mg/Kg) 1018/96 Pigeon River at Canton NHS 22.6 136 FC2 0.1 1018/96 Pigeon Riverat Canton NHS 23.4 128.5 FC2 <0.02 1018/96 Pigeon River at Canton RKB 14.5 54 FC2 0.08 10/8f96 Pipeon River at Canton RKB 17.9 93 F 0.45 10/8/96 Pigeon River at Canton RKB 20 136 F 0.2 10/8196 Pigeon River at Canton W 17.5 99 F 0.31 10/8196 Pigeon River at Canton LMB 26.9 268 F 0.38 10/8196 Pigeon River at Canton LMB 38 892 F 0.34 10/8196 Pigeon River at Canton RBS 17.5 100 FC2 0.12 10/8196 Pigeon River at Canton RBS 16.4 87.5 FC2 0.05 10/8196 Pigeon River at Canton RBS 22.3 55.3 FC3 0.18 10/8/96 Pi eon River at Canton RBS 16.2 72.6 FC3 0.26 10/8/96 Pigeon River at Canton LMB 44.7 2129 F 0.54 10/7/96 Pi eon River at SR-1513 C 60.3 2937 F 0.09 10/7196 Pigeon River at SR-1513 C 54.7 2435 F 0.09 10/7/96 Pi eon River at SR-1513 C 51.8 2085 F 0.08 1017196 Pigeon River at SR-1513 RKB 18 116 F 0.03 10/7/96 Pigeon River at SR-1513 SMB 25 186 F 0.07 IOM96 Pigeon River at SR-1513 LMB 36.4 749 F 0.13 10n196 Pigeon River at SR-1513 LMB 34 545 F 0.07 10n196 Pigeon River at SR-1513 W 17.9 115 F 0.09 10/7/96 Pigeon River at SR-1513 BGS 19.2 164 F 0.03 10n196 Pigeon River at SR-1513 BGS 19.5 - 142 F 0.05 10n196 Pigeon River at SR-1513 RBS 18 111.3 FC3 0.04 10n196 Pigeon River at SR-1513 RBS 15.9 66.2 FC4 0.04 10/7/96 Pi eon River at SR-1513 RBS 15 56.5 FC4 0.05 10n196 Pigeon River at SR-1513 WSU 26.6 224 F 0.02 10n196 Pigeon River at SR-1513 WSU 37.9 663 F 0.08 10/7/96 Pigeon River at NC-209 SMB 27 269 F 0.09 10n196 Pigeon River at NC-209 RBS 18.1 119 FC2 0.07 10/7196 Pigeon River at NC-209 RBS 17.6 114 FC2 0.05 10/7/96 Pigeon River at NC-209 RBS 17 98 FC2 0.06 10/7196 Pigeon River at NC-209 RBS 18.3 129 FC2 0.06 10M96 Pi eon River at NC-209 RBS 17.8 13.3 FC2 0.05 10n196 Pi eon River at NC-209 LMB 43.7 1367 F 0.25 10n196 Pi eon River at NC-209 LMB 36.8 746 F 0.21 10n196 Pigeon River at NC-209 LMB 24.6 189 F 0.07 1017/96 Pigeon River at NC-209 C 52 1891 F 0.08 10M96 Pigeon River at NC-209 C 49.2 1786 F 0.08 1017/96 Pigeon River at NC-209 C 42.8 1020 F 0.08 10M96 Pigeon River dwns=ofFerguson Brid eSMB 22.6 235 F 0.04 10n196 Pi eon River tl n trm of Ferguson Bridge RKB 16.3 82 F 0.03 1017196 Pigeon River dwnstrm ofFerguson BrideRBS 19.4 190 F 0.02 10/7/96 Pigeon River dwnstrm ofFerguson BrideRBS 16.9 94 FC4 0.03 10n196 Pigeon River dwmtrm ofFer uson BrideRBS 14.6 65.2 FC4 0.02 10/8196 Walters Cake BKS 22.3 174 F 0.09 10/8196 Walters Lake BKS 21.5 141 F 0.06 10/8/96 Walters Lake BKS 22.2 145 F 0.1 10/8/96 Walters Lake BGS 18 117 FC2 0.04 10/8196 Walters lake BGS 18 123 F 0.07 10/8196 Walters Lake BGS 19.3 139 F 0.05 10/8196 Walters Lake BGS 19.4 129 F 0.06 1018/96 Walters Lake BGS 19.6 161 F 0.04 10/8196 Walters Lake BGS 16.4 87 FC3 0.04 1018196 Walters Lake LMB 30.8 404 F 0.1 1018/96 Walters Lake LMB 29.3 381 F 0.1 1018/96 Walters Lake LMB 28.7 359 F 0.07 10/8/96 Walters lake LMB 29 333 F 0.07 10/8196 Walters Iake LMB 24 186 IF 0.06 10/8/96 JIValters Lake ILMB 21.5 1 130 IF 0.04 i CHRMPION EOHS I 04-646-6892 NOY V, - `5 15 :36 N0 .009 P .02 TABLE 1: Results from NCDEHNR Fish Tissue Analysis for Pigeon River Mercury Assessment Fish tissue collected on 1017/96 and 10/8196 quantarra NCDEHNR Pigeon River Sample Fish Total Hg Total Hg Sample Site Mile ID Species ID m m Canton Upstream 64.5 96-300 N. Hogsucker 0.18 0.1 {f Canton Upstream 64.5 96-301 N.Hogsucker 0.18 <0.02 t Canton Upstream 64.5 9B-302 Rook Bass 0.13 0.08 Canton Upstream 64.5 98-303 Rook Base 0.56 0.45 j Canton Upstream 64.5 96-304 Rock Bass 0.28 0.2 Canton Upstream 64.5 96-305 Warmouth 0.42 0.31 Canton Upstream 64.5 96-305 Largemouth Bass 0.43 0.3B Canton Upstream 64.5 96.307 Largemouth Bass 0.40 0.34 Canton Upstream 64.5 95-306 Redbreast 0.23 0.12 Canton Upstream 64.5 96-300 Redbreast 0.089 0.05 Canton Upstream 64.5 96-310 Redbreast 0.14 0.18 Canton Upstream 64.5 96-311 Redbreast 0.41 0.26 Canton Upstream 64.5 1 96-313 Largemouth Bass 0.64 0.54 t t Above Clyde(SR 1513) 59.0 95.350 Carp 0.077 0.09 Above Clyde(SR 1513) 59.0 96-351 Carp 0.085 0,09 Above Clyde(SR 1513) 59.0 96-352 Carp 0.086 0.08 Above Clyde(SR 1513) 59.0 95.354 Rock Bass ND 0.03 Above Clyde(SR 1613) 69.0 96-365 Smallmouth Bass 0.080 0.07 Above Clyde(SR 1513) 59.0 96-366 Largemouth Bass 0.16 0.13 Above.Clyde(SR 1513) 59.0 96.357 Largemouth Bass 0.092 0.07 Above Clyde(SR 1513) 59.0 96-359 Warmouth 0.13 0.09 Above Clyde(SR 1513) 59.0 96-360 Bluegill 0,044 0.03 3 Above Clyde(SR 1613) 59.0 96-351 Bluegill 0.083 0.05 ;) Above Clyde(SR 1513) 59.0 90-362 Redbreast 0.073 0.04 y Above Clyde(SR 1513) 59.0 96-363 Redbreast 0,081 0.04 Above Clyde(SR 1613) 59.0 96-364 Redbreast 0.084 0.05 ' Above Clyde(SR 1513) 59.0 96-365 White Sucker 0.099 0.02 Above Clyde SR 1513 59.0 1 96-366 White Sucker ND 0.08 Old NO Route 209 52.3 96.337 Smallmouth Bass 0.12 0.09 Old NO Route 209 62.3 96.338 Redbreast 0.080 0.07 Old NO Route 209 52.3 90-339 Redbreast 0.020 0.05 Old NO Route 200 52.3 96-340 Redbreast 0.096 0.08 Old NO Route 209 52.3 96.341 Redbreast 0.10 0.08 Old NC Route 209 52.3 96.342 Redbreast 0.076 0.05 Old NO Route 209 52.3 98.343 Largemouth Bass 0.25 0.25 Old NO Route 209 52.3 95-346 Largemouth Bass 0.26 0.21 Old NO Route 209 52.3 96.346 Largemouth Bass 0.087 0.07 Old NO Route 209 52.3 95.347 Carp 0.060 0.08 Old NC Route 209 62.3 98-346 Carp 0.057 0.08 Old NO Route 209 52.3 96-349 Carp 0.080 0.08 Ferguson Bridge 48.2 96-314 Smallmouth Bass 0.084 0.04 Ferguson Bridge 4B,2 95-316 Rock Bass 0.076 0.03 Ferguson Bridge 48.2 96.317 Redbreast 0.050 0.02 Ferguson Bridge 48.2 96-318 Redbreast 0.087 0.03 Ferguson Bride 48.2 96.319 Redbreast 0.047 0.02 Page 1 CMS1116196 6AMPLON EOHS 1 '04-646-6892 NOV 13'---6 15 :36 N0 .009 P .03 TABLE 1: Results from NCDEHNR Fish Tissue Analysis for Pigeon River Mercury Assessment Fish tissue collected on 10/7/96 and 1018/96 Quanterra NCDEHNR Pigeon River Sample Fish Total Hg Total Hg Sam le Site Mile ID Spades ID (Dom) m Walters lake NA 96-320 Crappie 0.17 0.09 Walters Lake NA 96-321 Crappie 0.18 0.08 Walters Lake NA 96-322 Crappie 0.13 0.1 Walters Lake NA 96-323 Bluegill 0.097 0.04 Walters Lake NA 96-32d Bluagill 0.083 0.07 Walters Lake NA 96-325 Bluegill 0.16 0.05 Walters Lake NA 96-326 Bluegill 0.12 0.06 Walters Lake NA 96-327 Bluegill 0.14 0.04 Walters Lako NA 96.328 Bluegill 0.11 0.04 Walters Lake NA 98-330 Largemouth Bass 0.16 0.1 Walters Lake NA 96-332 Largemouth Bass 0.21 0.1 Walters Lake NA 96.333 Largemouth Bass 0.15 0.07 Walters Lake NA 96.334 Largemouth Bass 0.16 0.07 Walters Lake NA 96.335 Largemouth Bass 0.12 0.05 Walters Lake NA 1 96.336 1 Largarnouth Bass 0.12 0.04 ND=Not Detectable at 0.040 ppm Reporting Limit NA=Not Applicable The FDA fish consumption standard fo methyl mercury is 1 ppm Page 2 CMS11/8/a8 State of North Carolina IT a Department of Environment, ealth and Natural Resources 4 • Ozjvision of Water Quality � mes B. Hunt, Jr., Governor natha B. Howes, Secretary Preston Howard, Jr., P.E., Director Asheville Regional Office November 13, 1996 MR. JOHN PRYATELY CHAMPION INTERNATIONAL WWTP LAB P.O. BOX C-10 CANTON, NC 28716 Dear Mr. Pryately: We evaluated results from your analysis of the wastewater/groundwater laboratory certification sample(s) received on November 12, 1996. The information from this evaluation is summarized below: Value True Acceptable Parameter Reported Value Range Performance Conductivity,umhos/cm 398.2 398 368-435 Acceptable Acceptable result: No further action is required. Contact us at (704) 251-6208 ext. 285 if you have questions concerning this matter. Sincerely, Gary Francies Laboratory Section cc: W.B. Edwards, Jr. James W. Meyer Asheville Regional Office Interchange Building,59 Woodfin Place MAXAn FAX 704-251-6452 Asheville,North Carolina 28801 Equal Opportunity/Affirmative Action Employer Voice 704-251Voice 704-251-6208�50%recycles/10%post-consumer paperrecycles/10%post-consumer paper (� Stage of North Environment, to artment of Environment, �1 ealth and Natural Resources • Division of Water Quality James B. Hunt, Jr., Governorya Jonathan B. Howes, Secretary p E H N fR A. Preston Howard, Jr., P.E., Director Asheville Regional Office October 31, 1996 MR. JOHN PRYATELY CHAMPION INTERNATIONAL WWTP LAB P.O. BOX C-10 CANTON, NC 28716 Dear Mr. Pryately: Enclosed for your use are certification materials as follows: ( ) Certification Regulation ( ) Federal Register ( ) Application ( ) List of Certified Labs. (X) Please complete and return the enclosed checklist(s) (X) Other Also enclosed is an invoice. DO NOT submit fess until an acceptable value has been reported on the evaluation sample. Evaluation Samples ( ) ROD Metals. Group I ( ) Total Phosphorus ( ) Purgeables 601 < ) COD ( ) Regular Level ( ) Orthophosphate ( ) Purgeables 602 ( ) Chloride ( ) Lou Level ( ) Oil 8 Grease ( ) Aerolien 603 ( ) Chlorine Metals. Group II ( ) pH ( ) Phenols 604 ( ) Color PC ( ) Regular Level ( ) Phenols ( ) Renzidines 605 ( ) Color ADMI ( ) Low Level ( ) Res. Total ( ) Phthalates 606 (X) Conductivity ( ) Barium ( ) Res. Dissolved 180°C ( ) Nitrosamines 607 ( ) Cyanide ( ) Mercury ( ) Res. Suspended ( ) Pesticides 608 ( ) Fluoride ( ) Ammonia Nitrogen ( ) Sulfate ( ) PCB 608 ( ) Hardness ( ) T. Kjeldahl Nitrogen ( ) TOC ( ) Nitroaromatics 609 ( ) MBAs ( ) NO? + N0.� Nitrogen ( ) Turbidity ( ) PAH 610 ( ) Nitrate Nitrogen ( ) Others ( ) Hal oethers 611 ( ) Chi Hydrocarbons 612 ( ) Purgeable Organics 624 ( ) SN/A Organics 625 C ) Herbicides ( ) EDB - EPA 504 Sample Tvce ( ) TPH ( ) Required Samples (X) Initial Samples ( ) Recertification Samples ( ) Samples for your use only - No report needed ( ) Replacement Ampules Please contact us at 704-251-6208 Ext. 285 if you have questions or need additional information. Sincerely, Gary F7ancies Laboratory Section cc: W.B. Edwards, Jr. James W. Meyer Interchange Building,59 Woodfin Place NV y.■ FAX 704-251-6452 Asheville,North Carolina 28801 r■tl An Equal Opportunity/Affirmative Action Employer Voice 704-251-6208 I7!TFYT7Twj?FT77 50%recycles/10%post-consumer paper State of North C l on Department of Environment, Health and Natural Resources ` 0 Division of Water Quality James B. Hunt, Jr., Governor Jonathan B: Howes, Secretary H N A. Preston Howard, Jr., P.E., Director October 17, 1996 OCT 2 9 10 WATcc c tdAL OFFICE Mr. John Hankinson, Jr. pSHE`1ILLE• F�• Region IV Administrator U.S. Environmental Protection Agency _ 100 Alabama Street, S.W. Atlanta, Georgia 30303 SUBJECT: Color Variance Champion International Corporation NPDES Permit NC0000272 Haywood County Dear Mr. Hankinson; As I am sure you are aware,North Carolina recently has reviewed Champion International Corporstior's Canton Mill variance for color. The color variance was originally granted to Champion International Corporation in July 1988 and later approved by the United States Environmental Protection Agency (USEPA). The color variance, as approved by the USEPA, required that the Division of Water Quality(DWQ) review the color variance for Champion International Corporation during the state's Triennial Review of Water Quality Standards (required by the Clean Water Act), and make appropriate recommendations to the NPDES Committee (a committee of the state's Environmental Management Commission, our rulemaking and policy making board). The variance more specifically required that, during the Triennial Review period, following the completion and startup of the Canton Mill's modernization project,the Division nominate a Variance Review Committee (VR Committee). The VR Committee was charged with developing a report with recommendations on the adequacy of the existing variance and presenting these recommendations to the NPDES Committee. The NPDES Committee was then to decide if the variance should be changed based on available color removal technologies for this type of wastewater or effectiveness of the color removal system at the Canton Mill. Any revisions to the variance adopted by the NPDES Committee would require modification of the NPDES permit for this facility. The modernization of the Canton Mill was completed in 1994. On February 8, 1996, the VR Committee proposed modifications to the color variance and recommended that the NPDES Committee send these proposed modifications to public hearing. On March 13, 1996, the NPDES Committee voted to send the proposed modifications to the color variance to public hearing. The Hearing Officer's recommendation from the June 6, 1996 public hearing was taken back to the NPDES Committee to consider for final approval at their October 9, 1996 meeting. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10%post-consumer paper a r -iP The NPDES Committee adopted the hearing officer s recommendations,with one modification, at their October 9, 1996 meeting. Enclosed are the documents pertinent to the adoption of the modified variance. I hereby request that the USEPA review the enclosed documents and approve the modified variance accordingly. _ The NPDES permit is scheduled to be issued in early November with the approved variance incorporated into the permit. Your prompt consideration of this matter would be greatly appreciated by the Division. If you have questions regarding the variance,you may contact Coleen Sullins or Greg Thorpe of my staff at (919)_733.5083, ext. 550 and 557, respectively. Sincerely, A. Preston Howard, Jr., P.E. cc: Harlan Britt,Deputy Director, Division of Water Quality Steve W. Tedder, Chief,Water Quality Section Dan Oak1g Senior jDeputy Attorney General,Environmental Division F_orres`i_Westall Water Qualrty Stipet sorfAs'h6W16Regional O ce Greg Thorpe,Assistant Chief Water Qualtty Section, Planning Branch Coleen Sullins,Supervisor, Permits &Engineering Unit State of North Carolina MICHAEL F. EASLEY Department of Justice A7r0kNEY GENERAL P.O. BOX 629 Reply to:Daniel C.Oakley RALEIGH Environmental Division 27602-0629 (919)733-5725(Phone) (919)733-0791 (Fax) October 15, 1996 Mr. John Hankinson, Jr. Region IV Administrator U.S. Environmental Protection Agency 100 Alabama Street, SW Atlanta, Georgia 30303 Re: Modification of Color Variance; Champion International Corporation, Canton Mill Dear Mr. Hankinson: Under the provisions of a Color Variance granted to Champion International Corporation, for its Canton Mill, on July 13, 1988, and GS. 143-215.3(e), the North Carolina Environmental Management Commission, acting through its NPDES Committee, has modified the terms of the existing variance. The order providing for the modifications is attached for your reference. The modification process was undertaken in accordance with established North Carolina law and procedure, and will effect changes in the Color Variance contemporaneously with the effective date of re-issued NPDES Permit No.NC 0000272 Please advise if you require any further information. Very truly yours, 4 Li If. opt Daniel C. Oakley Senior Deputy Attorney General DCO/dw cc: Preston Howard Andy Vanore John McArthur attachment /13517 r An Equal Opportunity/Affirmative Action Employer ��� ENVIRONMENTAL MANAGEMENT COMMISSION RECEIVE ® OCT 1 5 1996 IN THE MATTER OF REQUEST FOR ) EDNi r: i I7AL MANAGE,`�I VARIANCE FROM WATER QUALITY STANDARD-BASED EFFLUENT ) MODIFICATION OF COLOR LIMITATIONS BY CHAMPION ) VARIANCE GRANTED INTERNATIONAL CORPORATION, ) ON JULY 13, 1988 CANTON,NORTH CAROLINA ) THIS MATTER came on to be heard before the NPDES (National Pollutant Discharge Elimination System) Committee of the North Carolina Environmental Management Commission at its scheduled meeting in New Bern, North Carolina, on October 9, 1996, pursuant to the NPDES Committee's proposal to modify an existing color variance granted to Champion International Corporation on July 13, 1988. Upon duly made motion and vote, the NPDES Committee hereby adopts the following Findings of Fact and Conclusions of Law: FINDINGS OF FACT 1. Pursuant to a request for variance, dated January 12, 1988, submitted by Champion International Corporation C'Champion"), the NPDES (National Pollutant Discharge Elimination) Committee of the North Carolina Environmental Management Commission granted Champion a variance from the North Carolina water quality standard for color, as that standard is interpreted by the U.S. Environmental Protection Agency. The variance was memorialized in the NPDES Committee's Final Decision, dated July 13, 1988. 2. Pursuant to Ordering Paragraph 6 of its Final Decision, the NPDES Committee established a Variance Review Committee to review the Canton Mill's proposed modernization a 2 program and to recommend any changes to the existing variance. As stated in Ordering Paragraph 6 of its Final Decision,-.the NPDES Committee is charged with determining "if changes in the variance are warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater." 3. The Variance Review Committee convened three times, and presented the results of its review and consideration of Champion's effluent color discharge to the NPDES Committee at its March 13, 1996, meeting in Raleigh,North Carolina. 4. The Variance Review Committee made several recommendations to modify the existing variance to the NPDES Committee, through a verbal presentation at the March 13, 1996, meeting, and through memoranda dated March 7, 1996, from Greg Thorpe ("Review of Proposed Modifications to Champion's Canton Mill Color Variance by the NPDES Committee"), and March 6, 1996, from Dennis C. Loflin ("Consideration of Proposed Modifications to Champion International Corporation's Color Variance for the Canton Mill NPDES Permit"), which are incorporated herein by reference. 5. Based on a consideration of the Variance Review Committee's reports and recommendations, the NPDES Committee voted to propose modifications to the existing variance, and directed its staff to carry out the public notice, comment and hearing process required by G.S. 143-215.3(e) and Ordering Paragraph 8 of its July 13, 1988, Final Decision. 6. A public hearing was conducted by Mr. Harlan Britt, appointed as hearing officer for the NPDES Committee and for the contemporaneous NPDES permitting process, on June 6, 1996. in Haywood County,North Carolina. 3 Y 7. The hearing officer made several recommendations to modify the existing variance to the NPDES Committee, through .a verbal presentation at the October 9, 1996, meeting, and through a memorandum dated October 2, 1996, which is incorporated herein by reference. 8. Modification of the variance as recommended by the Variance Review Committee «ill not result in any discharge of waste that would endanger human health or safety. The variance for color is to allow discharge of wastewater at levels that will prevent Champion's contribution to the true color from causing the true color at the North Carolina/Tennessee State line to exceed 50 true color units at all flows equal to or greater than 126 efs at the Hepco Gauging Station. The substance being discharged, for which the variance is sought, is not bioaccumulative. The color does not, at the volumes and levels involved here, present a risk of indirect or direct human impact or broad environmental damage. The waters are not water supply. Therefore, the discharge will not endanger human health or safety. 9. Reduction of color discharge by application of best available technology is still not economically reasonable and results in serious hardship without equal or greater benefit to d and thorough study and evaluation of color removal technologies was the public. A detaile performed and reported in Champion's 1995 and 1996 Color Removal Technoloev Reports submitted to Division as rcquired by the existing color variance. 10. Champion has now completed its mill modernization project which re-configured its facility as an oxygen delignification, 100% chlorine dioxide substitution (OD-100) bleach mill. The project resulted in limited color reduction in its effluent discharge. The end-of-pipe technologies considered in 1988 and updated for the 1996 review established: a) standard 4 water/wastewater separation technology (lime, alum, or polymer) has not been applied in a similar fashion, b) these technologies would result in high capital and operating costs at the mill, c) color reduction on this type of waste, using these type .technologies has no operational efficiency "track record" (effective under normal paper mill production variations, and consistent and reproducible color removal), and d) the process color removal effectiveness of OD-100 may present other in-process reduction opportunities that have not yet been realized. 11. A schedule for continued color minimization is necessary. Members of the public, EPA and the State of Tennessee commented that the variance document proposed in the public notice did not include any milestones for continued color reduction. Therefore, the schedule contained in the Ordering Paragraph 4, infra, is established. 12. In review of the color data, including the short time since the re-configured mill became fully operational, it is determined that a more restrictive limitation should apply for color. Therefore, the more restrictive monthly and annual average color limitations contained in the Ordering Paragraph 2, infra, are established. 13. Based on the continued development of color discharge information from the reconfigured mill, Champion is required to statistically evaluate its monthly average color discharge,-its annual average color discharge, and the performance of the state line color model. These evaluation processes are to be ongoing and the results of the evaluations are required to be reported to the Division of Water Quality prior to each water quality standards triennial review period. The results of these evaluation processes shall be utilized by the Division and the next Variance Review Committee to make recommendations to the NPDES Committee on future 5 revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and the hearing officer, in reporting these evaluations. 14. As provided in Findings of Fact#8, supra, Champion is also required to take such actions as necessary to prevent their contribution of true color from exceeding 50 true color units at the North Carolina/Tennessee state line at all flows equal to or greater than 126 cfs at the Hepco Gauging Station. Furthermore, the method by which compliance is determined shall continue to be the color predictive model. CONCLUSIONS OF LAW 1. Pursuant to the Ordering Paragraph 6 of the July 18, 1988, Final Decision, the NPDES Committee has reviewed the existing variance following the Champion Canton Mill modernization program. 2. The previously existing variance from the North Carolina water quality standard for color, memorialized in the NPDES Committee's Final Decision, dated July 18, 1998, remains in effect except as specifically modified herein. 3. Based on the effectiveness of the treatment system subsequent to the Canton Mill . modernization project and due to the potential for improvements in color reductions by use of bleach filtrate recycling (BFR'), changes to the variance are warranted. Based on the foregoing Findings of Fact and Conclusions of Law, it is hereby ORDERED that the previously existing variance from the North Carolina water quality standard for color as memorialized in the July 13, 1988 Final Decision Ordering Paragraphs, continues in effect as hereby modified, to read as follows:' For ease of reference, the language of the July 13, 1988 Final Decision Ordering Paragraphs is included verbatim, with the modifications denoted by overstriking for deletions 1. Champion's petition for a variance is granted, pursuant to G.S. 143-214.3(e), as a variance to water quality based effluent limitations for color. 2. The Division ofEavireFffneaW Manageme Water Quality' shall issue NPDES Permit No. NC0000272. for the Canton Mill, and mediy draft its provisions to reflect all the conditions of the Fe1F1a15", 1988 draft EPA eeme-emise 'TD^—.� pen ak this modification, including the following specific wording. I. Champion shall take such action as necessary to prevent their contribution of true color from causing the true color at the North Carolina/Tennessee State line from exceeding 95 SO true color units at all flows equal to or exceeding 126 cfs (81.4 MGD, the seven-day, ten-year low flow level) at the Hepco Gauging Station. Compliance with this requirement shall be measured through a calculation of instream true color levels at the North Carolina/Tennessee state line by the following equation: Sl,6-- �^_�o(RE d Sl,_ (W�CP. /8.34) + (M WIPfjx_pil (-0.224 x LOG(HE,)+ 0.781) HE,x 10 Where: WTP,= Monthly average Waste Treatment Plant discharge color. L)' Calculated as the average of all daily loading values (pounds of true color per day) for a calendar month. WTPr= Monthly average Waste Treatment Plant discharge flow(mgd). HEf = Monthly average HEPCO, North Carolina flow (MGD). Daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. and bolding for additions. '- The Division of Environmental Management has been reorganized and NPDES permitting is now administered by the Division of Water Quality. 7 Sly = Monthly average Instream true color at North Carolina/Tennessee border (state line). D,= Color concentration of all dilution streams (13 C.U.). a":, basi., for each calendar The SLR shall be calculated --� month. �t SLR values The Fany i si ( ,.e.. ,a", F 11 for each month shall not exceed 85 50 true color units. Any exceedance of 95 50 true color units for this average value shall be considered a violation of this permit/variance II. The average daily discharge of true color for each calendar month shall not exceed 298,945 132,341 pounds per day. The average annual effluent true color loading shall not exceed 172,369 124,923 pounds per day. For the purpose of this permit/variance only,-"pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (platinum Cobalt Units) x 8.34. 114 ,ess _ j,4 19cI p a III. PIL The method of analyses used to measure true color shall be the procedure referenced in FR 39 430.11(b) (May 29, 1974). 3. The Division of 4;;nagejRentWater Quality shall include review of this variance as a specific item in its Triennial Water Quality Standards review, as required by the federal Clean Water Act, and make appropriate recommendations to the NPDES Committee. 4. Champion shall continue to study, and evaluate and pursue color removal technologies and shall report its findings to the Division of "l .4a ag eat Water . in accordance with the following schedule: DATE ACTIVITY Continuing Commercial demonstration of bleach filtrate recycling (BFRT") March 1, 1998 In conjunction with the scheduled Triennial Review of N.C.Water Quality Standards: 1. Submit a status report on the technical, economic, and operational feasibility of BFR7 technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2. Evaluate.and report on end-of-pipe color reduction technologies. 3. Evaluate and report on minimization of color losses from manufacturing process and from raw material storage areas. December 1, 1998 Based on the results of the demonstration project and the conclusion of the status report. Champion will decide and report on the decision to operate BFRT" technology as a fully commercial process on the pinewood line. December 1, 2000 Champion will evaluate color reduction strategies for further optimization of BFR7 technology and report on the feasibility of implementation on the hardwood line. March 1, 2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. June 1, 2001 Champion will submit a report to N.C. DEHNR, Division,of Water Quality, on the comparative evaluation of the above collective efforts as part of the variance review process (Triennial Review of North Carolina Water Quality Standards). 8 9 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee „ eH er, c _e June 3n c,.ae. . .,- prior to completion , of the Triennial Water Quality Standards review. 5A. Based on the continued development of color discharge information from the reconfigured mill, Champion will statistically evaluate its monthly average color discharge, its annual average color discharge, and the performance of the state line color model. This evaluation process shall be ongoing and the results of the evaluation shall be reported to the Division prior to each triennial review period referenced in this variance. The results of this evaluation process will be utilized by the Division and the Variance Review Committee to make recommendations to the NPDES Committee on revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and the hearing officer in reporting these evaluations. 6. Fegewing the ee npletien Gantan - and In conjunction with ;�e—€rrst subsequent triennial water quality standards reviews a€teF r v ;,.lle,. .t rie , the Division will nominate a variance review - - ' committee. The NPDES Committee will have final approval of the selection of this committee. Whirl; will Committee membership may consist of NattffE4 D pe*ekTmei3; Department Staff and at least twe individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university or research communities.' That review committee's report and recommendation will be examined by the NPDES Committee for a decision on the adequacy of the existing variance. The NPDES 31 The Variance Review Committee membership qualifications are changed to provide greater flexibility in appointments. 10 Committee will determine if changes in the variance are warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater. All revisions adopted by the NPDES Committee will require the modification of the Company's State NPDES Discharge Permit. 7. The variance proceeding, and the NPDES Permit No. NC 0000272, shall at all times be subject to reopening in order to modify the color requirements based upon any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion and the Division of Em-ireFmeatal `T.,nage.. ee Water Quality, as soon as they are discovered. - S. This variance shall extend for an indefinite period of time, subject to consideration of the three-year reviews . and Any modification or termination based thereon shall be subjected to the public hearing process required by G.S. 143-2153(e). It is further ORDERED that this Modification of Color Variance shall be effective as of the effective date of the re-issued NPDES Permit No. NC 0000272 for the Canton Mill, and the terms of the previously existing variance shall continue in effect until that time. • y . I1 This the day of October, 1996. `/icy} •//, ,� , � ,`;i Daniel V. Besse;Chairman NPDES Committee 12 CERTIFICATE OF SERVICE This is to certify that I have this day served a copy of the foregoing MODIFICATION OF COLOR VARIANCE GRANTED ON JULY 13, 1988 on the parties listed below by the methods indicated, addressed to each as follows: William Clarke U.S. MAIL Roberts & Stevens Suite 900 One W. Park Square Asheville,North Carolina 28802 A. Preston Howard, Jr., Director HAND DELIVERY Division of Water Quality N.C. Department of Environment, Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 Jennie Odette, Clerk HAND DELIVERY Environmental Management Commission N.C. Department of Environment, Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 Paul Davis U.S. MAIL Tennessee Department of Environment & Conservation 6th floor, L & C Annex 401 Church Street Nashville, Tennessee 37243-1534 David McKinney U.S. MAIL Tennessee Wildlife Resources Ellington Agriculture Center P. 0. Box 40747 Nashville, Tennessee 37204 Gary Davis U.S. MAIL Tennessee Environmental Council 1700 Hayes Street. Suite 101 Nashville, Tennessee 37203 13 Mike McGhee U.S. MAIL Director of Water Management 100 Alabama Street, SW Atlanta; Georgia 30303 This the 15th day of October, 1996. MICHAEL F. EASLEY Attorney General /13=_-4 Daniel C. Oakley Senior Deputy Attorney General Environmental Division P. O. Box 629 Raleigh,North Carolina 27602-0629 919/733-5725 Box C-10 • Canton,North Carobw—116 UChampion Champion International Corporation D 0 November 19, 1996 NOV 2 f► Q Mr. James W. Meyer ASHfVr�R �A(r)Y 4405 Reedy Creek Road �EGrpNp[OF f Raleigh, North Carolina 27607-6445 Dear Mr. Meyer: This la".: r is Lkc r ceponse to your latter dated November 6. 1996, regarding deviations cited from the laboratory certification maintenance inspection of October 2, 1996. Deviation: Color- Values less than the established minimum reporting level were reported. Comments: This occurs at the Big Creek sampling site using the spectrophotometric procedure. The minimum reporting level has been established at 10 C.U. Correction: All spectrophotometric river color tests that produce a result less than the minimum detection limit of 10 C.U. are now reported as less than 10, (<10). Deviation: Ammonia Nitrogen - The meter being used, an Orion 940, does not calibrate a straight line curve when a multiple point calibration is used. Comments: If each segment of the curve is not checked, a linear regression Calculation may be done to establish a straight line curve. Other options would be to do a two point calibration or use the spectrophotometric procedure. Correction: A two point Calibration is now being used and verified with a mid-range QC standard. Deviation: Ammonia Nitrogen - The value obtained on the mid-range QC standard was often not acceptable. Comments: When the mid-range standard varies by more than + or- 10%, the analysis is out of control. The analysis must be terminated and the problem corrected. Correction: If the mid-range QC standard is out of range, the cause of the out of range standard is determined, corrections made, the instrument recalibrated, and the mid- range QC standard rerun. Samples will not be run until the mid-range QC standard is in range. Deviation: Fecal Colifomt - The water bath thermometer is calibrated quarterly, but it is not documented. Comments: Supporting records shall be maintained as evidence that these practices are being carried out. Correction: A traceable thermometer is now being used in the water bath eliminating the need to calibrate quarterly. The traceability documentation is on hand for inspection. Deviation: Fecal Coliforn - The calibration of the pH meter used to check the media was not documented. Comments: Supporting records shall be maintained as evidence that these practices are being carried out. Correction: The pH meter is being calibrated with the calibration documented each time media is prepared. Deviation: Fecal Coliform - The Town of Canton effluent sample was not dechlorinated. Comments: All chlorinated samples must be dechlorinated at the time of sample collection. Correction: The Town of Canton effluent sample collection bottle now has sodium thiosutfate added to remove any possible chlorine residual, when the sample is collected. If you have any questions, comments, or need additional information please contact me at 704-646-6720. Sincerely, John Pryately Laboratory Supervisor cc: Derric Brown, Mike Cody, Joe Deschene, Gary Francies, Keith Haynes, Bill Manzer State rt Environment,North i Department of Environment, Health and Natural Resources • Division of Water Quality James B. Hunt,Jr., Governor Jonathan B. Howes, Secretary p E H N R. A. Preston Howard,Jr„ P.E., Director Asheville Regional Office DIVISION OF WATER QUALITY November 20, 1996 Mr. Derric Brown Champion Canton Mill Post Office Box C-10 Canton, North Carolina 28716 Subject: Sampling Results Performance Audit Inspection Champion Canton Mill NPDES Permit No. NC0000272 Haywood County 'Dear Mr. Brown: Attached are the remaining laboratory analyses results, for the samples collected during the Performance Audit Inspection conducted on October 2, 1996. If you have any questions or comments, please do not hesitate to contact me at 251-6208 . Fnre Ith Ha ynonmental Specialist Enclosure cc: Roger Pfaff, EPA Interchange Building,59 Woodfin Place NOCAn Equal FAX 704-251-6452 Asheville,North Carolina 28801 Opportunity/Affirmative Action Employer Voice 704-251-6208 50%recycles/10%post-consumer paper DIVISION OF ENVIRONMENTAL MANAGEMENT _ - CArmisOy L.banlop Report/1Yala Quality ,. I.b Numbs 6W5818 W� SAAIPLETYPE Dme Recei,ed: IWJAK COUNTY HAYWOOD PRIORITY - Tame Recei.N: 9:I0ARI RISER BASIN: AhI01ENT QA STREAM .\�' EmUENT Raeleed By 1Imw REPORT TO , ARO R,ai.o.1 Once O COMPLIANCE CHAINOFCUSTODY I LAKE, INFLUENT Other : EMERGENCYESTUAR\' ❑ Om R,,.c: TM COLLECTORISI r IIAITJFS � Ume R,poned: II/JN6 E armed ROD Be.,: Sution Lisbon:CHAMPION - Seed: C6ladnated: Reinulo: 5lalianR _ D.C.Depin('T/mm/ddl Data End D7'Imm/dd) Ti.,Bepin Time End Depth-Dhl.OD,D851 V.I.,TJ'pe-A,II,L Cnmpmlle-T,5• Snmple TSye 0043272 Mimi caw / BOD310 mg4. CLloride940 mpL X NHJu N610 6.0 mpL X LI-Lithium 1132 450 u,JL COD IFagh 340 ma/L Chi a TA 32217 uFL X TKN an N 623 6.6 mg1L X Mg.hbgnmium9 5.8 .,L COD Lav]J3 mP/L CRI.:Ccar322D9 ug/L X NO2 plot NO3 u N 630 0.01 ro'L X hin-man'sear,III B50 uVL CRIi10ociAr FeW31616 /IOOmI Ph.,h,,l..32213 uFA. P:Totalas P663 mg/L X Na Sdium 929 390 mg/L Colifam:hlFTeW31504 /IOGmll X Color.True 10 ISO e.u. POla P 70307 m,L X Anaic:Tml COD 131rWL Calif:tube Fed 31615 /IOOmI Col.:(9Hl aJ pH. C.U. P:DirsolvedIts PW mA X Se-Sclaium 1147 6x uao. Colifatm:F.IStrop J167J /IUUmI Col.:PH 7.6 92 c.0 K-Poucsium mgA. X Ito-hlacury 1190 col ugfL Rmiduc:ToW5OO mg/L Cyanide 720 mVL X Cd.Ctdtoium 1027 e2.O uA Be Borium ug/L Volatile 303 mgA. ricc,lde 951 mgA. X Ur '.mium:Tmsi 1034 e25 ug)L O.a.chl.ine Peckides Fixed 51D - mg/L Fameldehyde71180 mWL 1XI Co-Copar l0/2 6.6 uSIL Orgcaopho.haus Peaticida Residue:Suspended 530 mg/L 0.ase Coal Oil,336 .,/L Ni-Nickel 1057 e10 ugR. Volatile 535 .,/L HCodnas Tmd 900 .;M1 Pb-Led IDS e10 uVL Add llabicides — - FixedSJO .,L Spairic Cpd.95 uhlhoicm5 Z -Zinc 1092 36 vg•L {:, I pH JDJ unh. hIBAS 39260 Ce A. V.VJndima "WIL BveMeulnlCAddE .bl,Oalanics . Acidity to pH 4.5 436 .,UL Ph.1.32730 ugh. A,Sit,or 1077 e5.0 ugA. TWI Diesel Range Aciditymp7laJJJS m.i Su11Coe9J5 .,'L AI-Aluminum 1103 B70 ug/1. ADdlnitytopHIJJ15 m�A. Sulfide 745 mg A. Br B,glliun 1012� e10 ug/L Pmpable O.mi.(VOA bonle,eQd) ANA - Alkalinimlo,HJJJ1D -A 0o.n Cg-C.16.916 7B mg1l. TFIl Gasolia Range TOC610 mp/L Co-Ccb,lt ID37 e50 co& TPNJBMX G.R.RCoge - - - Turbidity l6 NTU Wif.Tout Tube •II00 mU X jFe,l.IW3 550 '4. Ph7lopl.kaon - ' COMMENTS: 'I _. .. ._. . . , ' .. .... _....— ..: .. .... . U uuL Nov 15 ice: 1� 17.TER OUP:LIT-i SEM ON ASFIEVILLE REGIMAL OFFICE ' DIVISION OF ENVIRON ENTAL MANAGEMENT WATER QUALITY FIE...,-LAB FORM (DM1) O For Lab Use ONLY COUNTY C� Q 0 Lab Number: PRIORITY SAMPLE TYPE Date Received• & a6 TIme:Q RIVER BASIN yy\ 4 . ^❑ ❑ ❑REPORT T CdRd FRO MRO RRO WORO WIRO WS O TS AMBIENT Qp STREAM EFFLUENT Reed by: N/ From: Bus ourie nd Del AT BM A Other 'COMPLIANCE ❑ CHAIN ❑ LAKE ❑ INFLUENT DATA ENTRY BY: CK: OF CUSTODY Shipped by: Bu Staff, Other, ❑EMERGENCY ❑ESTUARY DATE REPORTED: COLLECTOR(S): S Estimated Boo Range:0.5/5-23/25-65/40-130 or 100 plus STATION LOCATION: Seed: Yes ❑ No Chlorinated: Yes❑ No❑ REMARKS: Stat� Q Date Begin (yy/rem/dal) Time Begin Dats End Time End I Depth DM DB­DBM Value Type Composite Stipple Type O d 'QU c ( 'a '�;Q A H L T'�B G GNXX 1 BOD5 310 m2/1 Chloride 940 mg/I NH3 as N 610 m9A LI4.Ithlum 1132 00/1 COD High 340 mg/1 Chi a:Trl 32217 u /1 TKN as N 625 2 g arg/I Mgi4a0nes1um 927 mgA 3 COD Low 335 mg/1 Chi a: Corr 32209 USA NO2 plus NO3 as N 630 mgA Mn-Mangeneae 1055 ORA 4 Colllorm:MF Feeai 31616 /IOOmI Phaophytin a 32213 ug/I P:Torsi as P 665 orp/I I>< Na•Sodlum 929 mgA 5 Colllorm:ME TO 31504 /100mI 4 Color:True 80 Pt-Co PO4 as P 70507 mgA ArserdmToml 1002 m1A 6 Colllorm:Tube Fecal 3I615 /100mi COIor:(PH ) 83 ADMI P.Dlssolvd as P 666 ma/1 Se•Selenlum I147 agA 7 Calif..;Fecal Strap 31673 /100m1 Color:pH 7.6 82 ADMI Hg-Me.mv 71900 USA S Residue:Total 500 mg/I Cyanide 720 mg/I Cdfsdmlum 1027 u9A Ora anochlodne Pesticides 9 Volatile 505 m9/1 Fluoride 951 mg/I C,-Chromium:Total 1034 agA Omeoupt Fhorus Pwdd-d. 10 Fixed 310 mg/I Formaldehyde 71880 mg/I CuCoppm 1042 og/1 11 Residue:Suspended 530 me/1 Grease and Oils 556 mg/I NI-Nickell 1067 u#A Acid Hmbkides 12 Volatile 535 me/1 Hardrress Total 900 m9/1 Pb•Lud 1051 ORA 13 Fl:ed 540 mg/1 SpecRic Cold.95 uMhos/am2 2n-21nc 1092 egA BOW Neutral Extractable Organics 14 PH 403 unite MBAS 38260 mg/1 Acid Extractable Organics 15 Acidity to pH 4.5 136 mg/I Phenols 32730 ug/I A Ilver 1077 ugA 16 Acidity to PH 6.3 435 mg/I Sulfate 945 mall AI-Aluminum 1105 uVI Purr eable Organics(VOA battle re0'd) 17 Alkalinity to PH 8.3 415 mg/1 Sulfide 743 mg/I Be4lerYlllum 1012 ORA 18 Alkalinity to pH 4.5 110 mg/I Catalcium 916 RWA 19 TOC 680 mgA Co-Cobalt 1037 ugA 20 Turbidity 76 NTU X Fe-Iron 1045 USA Minuplankton Sampling Point■ Conductance at 25 C Water Temperature C D.O.mg/l PH Alkalinity Acidity Air Tempemmre 10 PH 8.3 PH 4.5 pit 4.5 pit 8.3 2 94 10 300 1. 400 1. 827A4 431 82243 182242 20 Sslinily 8 Precipillon UNdey) Cloud Cover X Wind Direction Well) Strearn Flow Severity Turbidity Severity Wind Velocity MA4 Stream Depth IL St eaam Width IL 480 45 32 % 1351 1350 35 [earr 4 4 DM1Aistdsed 10/86 DIVISION OF ENVIRONMENTAL MANAGEMENT Chemblry L.boratory Repo"/Water Qusiy Lab Numbm : 6WS818 ElSAMPLETYPE D.Re«iud: Iw4M COUNTY XAYWOOD PRIORITY Time Rttd,d: 9:I0AM RIPER BASIN: AMBIENT QA STREAM Eleceiv EFFLUENT Red By HMW REPORT TO ARO Regional ODin X❑ COMPLIANCE CHAIN OF(,USTODY I LAKE ❑ INFLUENT OOer : EMERGENCY ESTUARY a Dora Releazed TNT COLLF.CTORIS): HAYNES Unm RcPnned 11u;M, Eellm.ted ROD Range: Stallon Localloe:CHAMPION S,d: CM1lorinaed: Remnkr. S..6.ox D.le Beeln lyylmmfed) Data E.d U]'/mm/dd) Time Begin Time End Deplb-DRI,DO.DBM 3'alae Typa-A,H.L Ctua,"tsT,5, Sample Type OOfl2)2 %TOOT o800 BOD 310 mg/L Cf,Wde 940 mu/L X NH3 w N 610 5.0- myiL X Li-Lithium 1132 150 ug/L COD High 340 mg/L CM.:Tri 32217 .,L X TKN an N 625 6.8 mg/L X 61g-klagxdum 9 5.8 mglL COD Low 335 me/L CH a:Car 322W ug/L X NO2 plan NO3 a N 6" 0A1 mg/L X MP-Manemmw 10 R50 ug/L Colifoml:klF Fecal 31616 /100ml Pheoph5ma 32213 ug/L PTolal.a P665 mWL X Na Adlum929 380 mg/L CPU. MFTad31501 /IWmI X Col,True 80 360 POI as P)O30] mVL X AramicTaal 1002 13 ug/L Colifmm luba Fad31615 /100ml Colo,(PH)83 PH. au. P:DissohNas P666 mg/L X Se-Selenium lla] <5.0 ug/L Colifi Fwal Sim 11673 IIOOmI Cola:PH 7,6 82 pu K-POlwdom mg/L X 118-6lmcury]I% <0.2 ue/L Residue.Tuml 500 mg/L Cyanide 720 mWL X Cd.Cadmium 1027 <2 0 uglL Be euium ug2 Volui1e505 mg/L Fluoride 951 PTWL X Cl{lromium.Total 1034 <25 ug/L Orgumchlai:m Pnikides Fixed 510 rng/L Famald6yde7I8W mg/L X Cu-Copya 1012 66 ug/L pgumphwphorus Peairidea Residua.Suspended$30 m4/1, Gmaa and Oils 5% mg/L X Ni-Nickel 1057 <10 uglL \'nlmik 535 mg/L Hadneu Tmal Opp mmi X Pb-Land 1051 <10 ug4. A6dllabicides Fi.ad 540 n:g L Spaific Cund.95 uMluo'cm2 X Zn-Ziw 1092 36 ua-L PH KU uni¢ MBAS 38260 mg/L VA'anadium ug/L 92wMeuoal&Acid Extrwtable Organics Acidily to PH 45436 nm,L Phgm,632730 ug/L X Ag-Sihm 1017 <5.0 ,1, 11-11 Diewl Range Acidi.�to pH 83435 ."'1 Su11ue915 mgQ. X AT Aluminum 1105 870 ug1 Alblinily to PIT 8.3 4I3 mg;L Sulfide 745 mg/L X Ba,8 Ilium 1012 <10 aY uga. Pmgeable Oreanica(VOA bonle.epol Alkalinity to PH 4 5 t 10 mg/L Boron X Ca.Calcium 916 TO m'L TPH Gasoline Ran e TOC 650 m&fL X Co-C96all 1037 <50 'l- TPH/BTEX Gaoline Range m Tbidily]6 NTU Collform Tmal Tube '/MOO mp X Fa Iron 105 560 uRL Pbcmnlankwn COMMENTS: D � NOV 996 I WATtR C'"'PLITY SECTION _i- -.INNAL OFFICE CHAMPION EDHS D:704-646-6892 NOV " " "96 8:20 No .001 P .01 IF/IAX FAX COVER SHEET ENVIRONMENTAL, OCCUPATIONAL, HEALTH AND SAFETY. CHAMPION INTERNATIONAL CORP. CANTON MILL TO: K�t't n e S FROM: Susanne, K0t.15 � 1, DATE: 1 1 \I i l 4 NUMBER OF PAGES: (INCLUDING COVER) NOTE: e. e q.jes 1p. COL1/ , �. / F A4 vc_Sfluhs or fr b)erns SENDERS PHONE NUMBER: (704) 646-6700 FAIL NUMBEA:(704) 646-6892 FAX PROBLEMS: (704) 64"700 D 4w Ov � asH�TfR � O f N. C . DEPA: 4ENT OF ENVIRONMENT, EALTH, AND NATURAL RESOURCES DIVISION OF WATER QUALITY WATER QUALITY SECTION ASHEVILLE REGIONAL OFFICE 59 WOODFIN PLACE ASHEVILLE, NORTH CAROLINA 28801 PHONE/704/251- 6208 FAX/704/251-6254 TO: IV\��F_ 1°�C_ � e-2 FAX # : ��Uc 156a FROM: DATE: \b \ 1 \a # OF PAGES INCLUDING THIS COVER: MESSAGE : If questions, please call 704/251-6208 . \OD��C\Q, -vOC � f CHAMPION EOHS 0:704-646-6892 NOV 11 '96 8:20 Na .001 P.02 Champion International Canton, NC . _ NC/TN State Line True Color mg/1 (SLc) _ NFDES Color Model Calculation Date SU Color Date Sl.c Color Date SLc Calor 01/01/95 21.5 02/07/95 22T . 16/95 16.5 01/02195 22.8 2/08/95 23.7 03/17/95 17.1 01/0 9S 25.4... 02/09/95 23.1 03/18/95 18.5 01/04/95 25.6 02/10/95 20.3 03/19/95 18.1 01/05/95 29.0 a2/11195 17.6 63120195 19.8 WOOS- 23.8 02/12N5' 18.1_ 03/21/95 7.7 _ 01/07(95' 17.2 02/13/95 19.2 0322J95 17.9 01108T95 20.1 02114195 19.3 0323/95 17.8 Ol/09/95 22.S 02/15/95 19.8 03/24195 18.1 01/10/95 21.2 02/16/95 16.0 0325/95 fs.5 01/11/95. 20.9 02/ 77/95 "15.4 03/26/95 17.6 01/12/95 ­ 8. 02/18/95 15.6 03/27/95 ]7.4- 01/13/95 20.6 02/19/95 15.4 0398/95 16.8 01/14/95 1&1 02/20/95 14.6 03/29/95 15.2 01/15195 16.2 02/21/95 14.8 03/30/95 16.7 01/16/95 14.6 02/22/95 14.8 03/31/95 19.3 01/17/95 15.0 02/23%95 13.8 04101/95 20.3 01/18/95 15.0 02/24/95 14.3 04/02/95 20.8 01/19/95 14.8 _ 02/25/95 14.2 04/03/95 22.0 0120/95 1s.0 02/26/95 15.4 b4jUW.S 26.1 6 l/21T95 15.5 0227/95 15.9 04/05/95 26.2 0122/95 15.6 0228/95 15.2 04p16/95 23.5 0123/95 15.7 03/01/95 ]5.8 04107/95 22.0 0124/95 17.3 03/02/95 - 17.2 04/08/95 22.3 01/25/95 17.6 03/03/95 19.5 04/09/9.5 25.1 01/26/95 16.6 03104/95 17. 04/10/95 29.6 0127/95 16.0 03/05/95 16.5 04/11/95 31.7 0128195 18.3 03/06/95 17.4 04/12(95 32.1 01 J29/95 19.0 03/07/95 18.6 04/13/95 26.5 01/30/95 20.0 03J08/95 1.5.7 *04/147§5 24.9 01/31/95 _ 20.0 )3/09/95 16.0 - 04115/95 23.5 02/01/95 21.b 03/10/95 TO 04116/95 23.4 02/02/95 20.1 03/11/95 16.2 04/17195 22.3 02/03/95 24.8 03/12/95 14.7 O4/18/95 20.3 02/04/95 19.0 03/13/95 14.7 1 /95 19.6 02/05/95 17.6 0371 15.3 O4/20/95 20.6 02/0 /9 20.8 03 5 5 1 15.5 04/21/95 20.7 SKK 11/8196 CHAMPION EOHS }:704-646-6892 NOV ' "96 8:21 No .001 P .03 Champion International - -- -- I Canton, NC I - __ NCIITI State Line True Color ME (SLO N1'DLS Color Model Calculation 64/22195 17.4 _ 5/31/95 26.7 07/09%95 30.5 04123/95 21.9 06/01/95 24.0 07/10/95 36.7 _ 04/24/95 - 20.9 06/02/95 17.6 - 07/11/95 30.0 _ _04125/95 21.3 06/03/95 _ 17.$ •• 12I0 27.9 /95 _ 19.9 06/04/91 21.9- 07/13/95 28.8 04MI95 18.1 06/05/95 24.0 07/14/95 32.4 04/28/95 16.5 06/06/95 23.6 07/i3X5 25.8 04/29/95 21.6 06/07/95. 24.8 07/23/95 35.1 04/30/95 26.3 06/08/95 33.1 07/24/95 05/01/95 26.8 06/09/95. .. .......37. 07/25/95 36.6 05/OW95 .. ........1 .3 06/10/95 31.6 07/205 _ 35.8 05103/95 22.5 06/11/95 29.7 07/2'1195 39.8 051005 25.3 06/12/95 25.4 07/28/95 30.4 05105/95 24.4 06/13/95 26.9 07/2 5 30.1 05 5 22.3 06/14/95 25.7• 07/30/95 34.6 0 7 5 22.5 06/15/95 20.9 07/31/95 38.8 05/08J95 -- 22.1 06/16/95 19.8 08/)l/95 26.9 05/09/95 23.9 _ 06/17/95 18.7- O8%O7J95 35.0 05/10/95 ­23.1 06/18/95 21.9 OS/03/95 35.1 051II/95 21.7 0 195 25.3 08/04/95 29.5 05/12/95 21.3 06/20/95 223 08/05/95 26.7 05/13/95 27.8 _ 06/21/95 21.1 MOOS- 249.3 05/14/95 ...._.._.24.6 06122/95 18.5 _08/07/95 30.3 05/15/95 20.4 06/23/95 21.1 08/08/95 05/16N5 22.5 06/24/95 24.7 • 08/09/95 30.1 05/17/95 24.5 06/25/95 22.0 08%10%95• 31.4 05/18/95 23.8 06/26/95 19.9 08/11/9S 31.4 05/19/95 22.0 06/27/95 21.1 08/12/95 35.7 05/2.0/95 26.2 06128/995 27.$ 08/13/95 42.9- 05/21/95 29.8 06/29/95 26.6 08/14/95 59.4 05/22/95 28.9 06/30/95 zf,9 08/15/95 80.1 05/23/95 25.9 07/01/95 22,6 08/16/95_ 43.2 05/24/95 30.5 07/62/95 24.7 08/17/95 29.6 05/25/95 _ 32.1 07/03/95 28.3 8/18/95 53.0 O5/26/9$ 31 07/04/95 41.7 _ . 691ff 5 22.6 05/27/95 25.1 07/05/95 42.7 09j(15/95 23.3 05/28/95 --25.3 07/06/95 34.6 09/06/95 73.6 OS/29/95 23.3 07/07/95 28.9 09/07/95 23.4 05130/95 _... 29.2 07/08/951 28.2 09MI95 1 243 SKK 11/8/96 CHAMPION EDHS 1:704-646-6892 NOV ?1r'96 8:22 No .001 P .04 Champion International -- I Canton,NC __ NC/IN State Line True Color mg/l (SLc NPDES Color Model Calculation 09/09/95 26.3 - 10/17/95 26.0 li/24/95 22.3 09/10/95 30.5 / 5 24.6 11125/95 22.4 09/11/�526.5 101106 23.1 11/2619.5 25.4 69/12/95 26.7 10/20/95 23.9 11/27/95 23.5 09/13/95 27.9 10%21/95 24.7 11/28/95 23.2 09/14/95 26.2 10/2?,/95 25.0 11)29%95 24.0 09/15/95 32.4 10123/95­ 25.8 11/30/95 7.5 09/16/95 30.9 10/Z4j93 2 .3 12/01/95 26.3 0 17 5 27.6 10/25/95 26.5 1ZI02/95 31.5 09/18/95 26.9 10126/95 34.8 12103/95 25.6 _ 09/19/95 27.1 10/27/95 32.8 12/04/95 25.2 09/20/95 29.8 10/28/95 29.0 12/05/95 23.1_ "& 5 40.1 10/29/95 34.6 12/06/95 25.6 09/22/95 36.7 10/30/95 36.8 12/07/95 27.0 09/23/95 28.3 10/31/95 _ 34.0 12/08/95 27.4 O§/1 95 28.6 11/01/95 - 29.3 12/09/95- 22.6 09/25/95 32.0 11/02/95 26.1 12/10/95 25.3 -09/26/95 34.7 I1/03/0 7.2 12/11/95 26.2 7 5 35.5 11/04/95 29.0 12/12/95 29.2_ 09/28/95 39.2 11/05/95 30.2 12/13/95 32.8 09/29/95 40.7 11/06/95 45.0 IW14/95 23.7 09/30/95 41.5 11/07/95 27.5 12/15/95 27.2 10/01/95 44.2 '11/68/95 21.2 12/16/95 30:4 10/02/95 38.6 11/09/95 23.5 12/17/95 13.3 10/03/95 35.4 _ 11/10/95 22.8 12/18/95 24.7 LO/04/95 17.5 11/11195 18.2 12/19/95 20.1 _ I0105195 17.3 11lIZ195 17.5 12/20/95 19.5 10/0619.5 16.2 11/13/95 18.3 12121%95 24.1 10/07/95 18.1 11114/95 20.7 12/22/95 22.9 10/09/95 19.0 11/15/95 21.1 I2/23/95 23.4 10/09/95 70.1 11/16/95 21.6 12/24/95 24.0 10/10/95 20.7 11/17/95 210 12/25/95 23.4 10/11/95 20.5 11/18/95 20.4 12/26/95 24.1 IO/12/95 20.6 11/19/95 23.5 12/27/95 253 10/13/95 20.9 11/20/95 26.2 12/28/95 26.5 10/14/95 22.8 W21/95 -- 21.8 12/29/95 25.8 10/15/95 22.1 11/22/95 25.7 12J 5 24.7 10/16/95 25.9 *' '11 3/ 5 26.5 12/31195 28.1 SKK 11/8196 CHAMPION EOHS :704-646-6892 NOV 11106 8:22 Na .001 P .OS Chain ion International - - Canton.NC _ N4&N State line True Color mg/1(SLc) NPDES Color Model Calculation 01/01/96 23.1 02l10/J 17.3 03%2I%96 24.3 Ol/U2/96 21.7 62/il/96 17.8 _ 03/'Z(96 21.6 01/03/96 20.1 02/17496 19.5 03/23I96 18.5 01/04/96 27.1 02/13/96 19.6 03 6 18.7 01/05/96 27. U 14/96 19.9 03/25/96 24-7 ___ 27.5 02/15/96 20.7 03/26/96 22.2 61/07/96 6.3 1 02/16/96 19.6 03/27/96 19.9 _ 01/08/96 32.8 _ 02/17/96 19.3 03/28/96 15.6 01/09/96 45.6 �02/18/96 26.5 03/29( 16.5 OV10196 36.0 .._.OVI-9/96 27.3 03/30/96 17.2 11 25.8 62NI96 21.9 03/31/96 20.1 _ 01/12/96 33.3 02/21/96 _ 21.9 04/01/96 17.4 .01/13/96 39.0 02/22/96 _ ._20.1 04/02/96 I9.3 01/14/96 28.6 0223/96 18.6 04/03/96 01/15/96 23.6 18..5 04/04/96 -_ 19.2 Olt 6 22.3 02J25/96 23.4 04/05/96 19.6 01/17/96 19.2 02126/96 26.1 04/06/96 ---_ 17.6 01%18/96 16.3 _ 02/27/96 211*­ -04/07/96 17.3 01/19/96 17.4 0228/96 17.2 04 17.0 01/20/996 1 .1 02/29/96 19.3 04/09/96 16.7 �01121196 19.3 03/01/96 18.7 04/10/96 17._5 OM2196 19.7 03/02/96 211.5" b4%11196 17.6 01/23/96 -- 18.7 03/D3/96 20.5 04/12/96 - 22.1 01/24/96 18.2 -03/04/96 18.2 04/13/96 _..- 0 25/96 I8.4 ...11'9/I15/96 18.0 04/1*6 - 17.5 0126/96 17-5 03/06/96 15.4 04/15196 19.2 0127/96 16.6 03/07/96 16.8 04/16/96 22.1 0128/96 15.6 03/08(96 15.9 04/17/96 R-9 _ 01/29/96 16.3 03/00/96 17.4 04/18/96 19.9 I 0 6 17.2 03/10/96 F _ 19.0 04/19/96 19.5 01/31/96 20.0 03/11/96 19.3 04/20/96 2{l2 02/Dl/96 17.1 03/12/96 26.4 04/21/96 18.9 - OZ(02/96 17.1 03/13/96 21,4 0422/96 21,8 02103/96 .. 1.5.8 03/14/96 20.1 00RD 5 02/04/96 15.0 (3/15/96 18.3 64)t4%96 27.5 0210S/96 15.8 03/16/96 17.5 04,25/96 2-4,0 02/06/96 27.0 D3/17/96 17.7 [M%l6%9G 17.8 02/07/96 23.6 03/18/96 21.3 04I27/96 ] . 02/08/96 20.5 17.5 04/28196 17.5 02/09/96 17.1 68 16.4 04/29/96 16.9 SKK 1118/96 CHAMPION EDHS :704-646-6892 NOV 11 '06 8:23 Na .001 P .06 4� C11aMpinn Intemational Canton, NC NQ TN State Line True Color mg/1(SLc) NPDES Color Model Calculation 04/30/96 15.8 28.9 07/17/96 30.6 05/01/96 ]7.4 06/09/96 19,2 .07/18/96 25.5. 05/02/96 17,6 66110/96 17.2 U7119/9G 25.2 05/03/96 17.9 66%11/96 18.5 28.0 6S/U4/96 18.4 06/12/96 17.6 07/21/96 32.7 05/05/96 18.6 06/13/96 - 1 .9 07MB6 32.5 05/06/96 19.1 06/14/96 17.9 07/23%96 31.7 05/07/96 21.1 06/15/96 23.8 07/24196 31.5 05/08/96 19.9 06/16/96 20.7 07/25/96 05/09/96 20.5 06/17/96 21.7 07/26/96 24.2 05/10/96 21.4 06/18/96 25.5 07/27/96 24.5 05/11/96 24.4 06/19/96 23.0 07/28/96 23.2 _ 05/12/96 21.0 06/20/96 23.2 07/29/96 D.8 05/13/96 25.1 b07/3 06/2l/96 22.3 0173- 22.7 0 05/14/96 22.2 ... . 27.6 1%96 22.0 05/15/96 22.6 06/23/96 30.3 08/01/96 18.9 05/16/96 17.9 06/24/96 31,7 08/02/96 19.4 05/17/96 25.5 06/25/96 31.1 08/03/96 24.9 05/18/96 23.8 --06126/96 26.8 O8/04/96 - 44.0 05/19/96 25.0 _ OG/27 9 30.8 08/05/96 58.2 5 0/96 25.3 06/28/96. 29.3 08/D6/96 31.G 05/21/96 23.6 0029/96 28.8 08/07/96 25.7 05%22/96 _ 18.9 06/10/96 26.1 08/08/96 277- ..._ 05/23/96 13.8 07/01/96 35.2 U /0 6 25.7 05/24/96 12.4 --- 07/02/96 39.7 08/10�6 28.4 05/25/96 15.2 07/03/96 30.0 68/106' _ 27.7 05/26/96 17.9 07/04/96 38.0 08/12/96 17.1 05/27/96 19.3 07/05/96 38.1 08/0196 16.4 05/28/96 15.6 07/06/96 37.9 08/14/96 20.4 05/29/96 I8.8 61/07/06 38.9 08/15/96 25.9* 05/30/96 17.9 07/08/96 40.7 08/16/96 2A.4 05/31/96 19.2 07/09/96 44 3 08/17/96 21.6 06/01/96 22.8 07% _10/96 37.0 08%18/96 .0 06/02/96 _ 22.4 0711/96 31.1 09/19/96 _ 210 06/03/96 3. 07/12/96 28.9 08/20/96 19.7 06/04/96 - 23.3 07/13/96 33.8 08/21/96 _ 30.0 06/05/96 23.9 07/14/96 '35.7 08/22J96 33.7 06/D6J96 26.0 07/15/96 32,7 08/23/96 21.4 O6/07/96 23.6 -- 07/16/96 30.3 08/24J96 22.5 SKK 1118196 CHRMPION EOHS :704-646-6892 NOV 11 '96 8:23 No .001 P .07 Champion International Canton,NC _ NC/IN State Line True Colormg/l (SLc) NPDES Color Model Calculation 08/25/96 21.7 (T/29/96 17.1 11/04/96 30,1 08/26/96 21.5 09/30/96 20.0­ 111/05/96 25.9 08/27/96 23.8 - 10/01/96 21.4 11/06/96 22.0 08)28/96 -- 28.7 10/02/96 20.8 - 08/29/96 _ 21.9 10/03/96 19.7 08/30/96 24.9 10/04/96 23.6 08/31/96 23.5 10/05/96 24.1 _ 09/01/96 24.6 10/06/96 22.9 09102/96 _31.2 10/07/96 22.0 -- - 69/03/96 25.8 10/09/96 23.9 - 09/04/96 17.5 _ 10/09/96 24.5 _ 09/05/96 17.1 10J10/96 25.8 09/06/96 21.6 10/11/96 19.8 09/07/96 304 10/12/96 21.3 09/O8/96 27.3 10/13/96 _ 47.1 09/09/96 54.8 10/14/996 80.4 - 09/10/96 51.3 10/15/96 43.3 09/11/96 35.7 10/16/96 28.0 09/12/96 _ 33.5 10/17/96 22.6 09/13/9b 31.0 10/18/96 18.0 09/14/96 40.2 W19/96 14.9 09/15/96 36.3 10/20/96 15.4 09/16/96 28.0 10/21/96 16.3 09/17/96' 18.5 10/22/96 09/18/96 24.8 10/23/96 22.2 09/19/96 28.7 10/24/96 27.4 09/20196 27.3 10/25/96 30.9 - 09/21/96 - 24.2 - l0/26/96 27.3 09 9 27.5 10/27N6 28.1 _.._ --09/23/9b 31.8 10/28%96 __ 36.0 09/24/96 32.7 10�29/96 32.5 - 09/25/96 40.8 i /9 Z7.8 -6.q12 39.6 - 10/31/96 28.5 - 09/27/96 31.3 -11/01/96 32.1 09/28/96 17.2 --11/0Z/96 31 Y- 09/29l96 17.1 11/03/96 25.7 - SKK 11/8f96 NC CEM WO ENVSCI Fax:919-733-9959 Nov 8 'w- 14:11 P.01/03 Sevee ofNoi*:Corolina Depart[rlent of Environment, Health Ond r t rat Resources James B, Hu&. Jr:..Gb'veinar + `� Jonathan B."HoaIssb Secretary Steven J! LOG4as:Dep6y Secretory � �H N F=?L Darn, le . . ; Div sion of Wczter Quality Environmental Sciences Branch 4401 Reedy Creek Road Raleigh. N.C. 27607 FAX.(919)733 99S FAXiO . r �rtf.. �ciTN AA<. e FAX NUMBER: FR6M. -#f r AAL uc,-D�Q r, PHOh#Ei. NO. OF PA. $ tkCLUDING- HLS SHEEP: Pveota � 5 t cf ATA V�Ave 7 ve'5Tt0A,/S i XIal AgF� " NC DEM WQ ENVSCI Fax;919-733-9959 Nov 8 '9h 14:11 P.C2iO3 J Y, ••i . plReDn.lg.faw "r r . M Tissue Pi eon River-October 7996 PLTS:a.:-"•ei e••: n ': . SeaCLE6 LENUM.a, wE[car snB�GSasra alb - 0.1 dwvacaCm 2ID ]285 !« = 0M Rlva!ai P;din+a: 23A 414.5 S4 A [aeA6 . 711vo1�C�o : o.as 10/8196, i' P!vlrat(1ootF 17.9 93 RKS 1041036 f ... RlvtraOlntaa W 17.5 99 .0.31 1111696; Rivae6[CariiaO 12i1B 26.9 26R 638 1018t96'. htNl'[ittl�o ]8 892 Au . 1018199 - 3Uwxak0000a: LT18 17.3 i 7. 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'LiV"letoS '. um .um IM 03 I S.P4s.m4t1!riS: .la j�2t6 .7tasl/nf7H) ! 966T- ZASQ3N 6suuayy ifli£0'd ZT:VT 70. 8 AON 6S66-22L-6T6:x2d M AN3 6M k9J JN ' State of North Carolina Y ' Department of Environment, Health and Natural Resources �4 61 f� A Division of Water Quality _ X James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary p E H N R A. Preston Howard, Jr., P.E., Director November 6, 1996 Mr. John Pryately Champion International WWTP Lab P.O. Box C-10 Canton, NC 28716 SUBJECT: Laboratory Certification Maintenance Inspection Dear Mr. Pryately: Enclosed is a report for the inspection performed on October 2, 1996 by Mr. Gary W. Francies. Within thirty days, please supply this office with a written item for item description of flow these deviations were corrected. A response is not required for comments or recommendations. If the deviations cited in the enclosed report are not corrected, enforcement actions may be recommended. For certification maintenance, your laboratory must continue to carry out the requirements set forth in 15A NCAC 2H .0800. Thank you for your cooperation during the inspection. Please contact us at 919- 733-3908, extension 243, or, 704/251-6208 ,extension 285, if you have questions or need additional information. Sincerely, /� "� -mgf- James W. Meyer Laboratory Section Enclosure cc: William B. Edwards, Jr. Gary W. Francies Asheville Regional Office Laboratory Section,4405 Reedy Creek Road, yC FAX 919-733-6241 Raleigh,North Carolina 27607-6445 Niq An Equal Opportunity/Affirmative Action Employer Voice 919-733-3908 50%recycles/10%post-consumer paper ON- SITE INSPECTION REPORT w LABORATORY NAME: Champion International WWTP Lab ADDRESS: P. O. Box C-10 Canton, NC 28716 CERTIFICATE #: 198 DATE OF INSPECTION: 10/2/96 TYPE OF INSPECTION: Maintenance EVALUATOR(S) : Gary Francies LOCAL PERSON(S) CONTACTED: John Pryately, Derric Brown, Mike Cody I. INTRODUCTION: This laboratory was inspected to verify its compliance with the requirements of 15A NCAC 2H . 0800 for the analysis of environmental samples . II. GENERAL COMMENTS: The laboratory is spacious and well equipped. All equipment is well maintained. Since the last inspection the laboratory has obtained the following equipment : 1) a water distillation system for the bacteriology lab, 2) an ice machine, 3) a DR 4000 spectrometer for COD and river Color analyses, and 4) two Accument 10 pH meters . Records are well kept and most data appeared accurate. Excellent sops (Standard Operating Procedures) have been developed for each parameter. Some further quality control procedures need to be implemented. A Fecal Coliform MPN sample was split with the following results : Champion Laboratory State Laboratory 70/100 ml 170/100 ml gassed 2-1-0 gassed 4-1-0 An effluent Fecal Coliform MPN sample was split with the following results : Champion Laboratory State Laboratory <20/100 ml 13/100 ml Page 2 . Champion General Comments continued Effluent samples were split with the following results (all values are mg/1) : Champion Laboratory State Laboratory COD 184 154 Ammonia nitrogen, distilled, electrode Not Analyzed 4 . 9 undistilled,electrode 6 .4 4 . 6 The States central lab also analyzed the ammonia nitrogen sample by the Automated Method and obtained a value of 5 . 0 mg/l. TSS 13 13 .5 Total Residue 1713 1776 Hardness 210 211 BOD 6 .7 7 . 1 III. DEVIATIONS, REQUIREMENTS and COMMENTS: Color DEVIATION: Values less than the established minimum reporting level were reported. REQUIREMENT: For analytical procedures requiring analysis of a series of standards, the concentrations of these standards must bracket the concentration of the samples analyzed. One standard must have a concentration equal to the laboratory' s lower reporting concentration for the parameter involved. For example, if you choose to have a lower reporting limit of 5 mg/l for a particular parameter, you must analyze a 5 mg/l standard and report lower samples as <5 mg/l . If you choose 100 mg/1 for the top of your standard curve, you must analyze a 100 mg/l standard and all samples above this limit must be diluted and reanalyzed to fall within the curve. For colormetric analyses a curve consisting of a blank and five standards must be analyzed. This curve must be checked each time samples are analyzed with a blank and a medium level standard. Instead of a standard curve, a three point (low, medium and high standard) curve may be analyzed with each group of samples . Ref: 15A NCAC 2H . 0805 (a) (7) (I) . COMMENTS : This occurs at the Big Creek sampling site with the spectrophotometric procedure. The minimum reporting level has been established at 10 C. U. COMMENTS : It is recommended that the absorbance reading of the lowest standard (minimum reporting level) occasionally be documented. It should be >. 005, preferably > . 010 absorbance units . Page 3 . Champion COD COMMENTS : It is recommended that the absorbance reading of the lowest standard (minimum reporting level) occasionally be documented. It should be >. 005, preferably >. 010 absorbance units. Ammonia Nitrogen DEVIATION: The meter being used, an Orion 940, does not calibrate a straight line curve when a multiple point calibration is used. It makes a point to point calibration. A mid-range calibration check standard was not analyzed to verify both segments of the calibration. REQUIREMENT: The calibration curve must be checked with a mid-range standard. If a point to point curve is established, each segment must be verified. Ref : 15A NCAC 2H . 0805 (a) (7) (I) . COMMENTS: If each segment of the curve is not checked, a linear regression calculation may be done to establish a straight line curve. Other options would be to do a two-point calibration or use the spectrophotometric procedure. DEVIATION: The value obtained on the mid-range quality control standard was often not acceptable. REQUIREMENT: For analyses that require a series of standards, a mid- range standard must be analyzed with each group of samples . When the mid-range standard varies by more than ± 10%, or is outside the established control limits, whichever is lower, the analysis is out of control. The analysis must be terminated and the problem corrected. Ref: 15A NCAC 2H . 0805 (a) (7) (B) , (F) and (I) . COMMENTS : It is recommended that the slope value be documented. The ten fold concentration millivolt change for should be 54-60 . If the slope value is not acceptable, the samples should be reanalyzed. Fecal Coliform DEVIATION: The water bath thermometer is calibrated quarterly, but it is not documented. REQUIREMENT: Supporting records shall be maintained as evidence that these practices are being effectively carried out. All analytical records must be available for a period of three years . Ref : 15A NCAC 2H . 0805 (a) (7) and (a) (7) (G) . DEVIATION: The calibration of the pH meter used to check the media was not documented. REQUIREMENT: See the requirement above. ppppp- Page 4 . Champion DEVIATION: The Town of Canton effluent sample was not dechlorinated. REQUIREMENT: All chlorinated samples must be dechlorinated at the time of sample collection. Ref: Standard Methods, 18th Edition - Method 9060 A.2 . IV. PAPER TRAIL: A review of data was conducted. This consisted of comparing laboratory bench sheets and contract lab reports to DMRs submitted to this Division. Data were reviewed for these months : March and June 1996 . No errors were noted. It appears the facility is doing a good job of accurately transferring data. V. CONCLUSION: overall, the laboratory is doing a good job and appears to be producing quality data. Upon correction of the above deviations, the requirements of certification will be met. Implementing the recommendations will further improve the quality of the data. Report prepared by: Gary Francies Date: 10/18/96 State(pf North Carolil-ICA Department of Environment, Health and Natural Resources10 `� • Division of Water Quality James B. Hunt,Jr., Governor Jonathan B. Howes,Secretary ID E H N R A. Preston Howard,Jr., P.E., Director Asheville Regional Office WATER QUALITY SECTION October 30, 1996 Mr. Derric Brown Champion International Corporation Canton Mill Post Office Box C-10 Canton, North Carolina 28716 Subject : Performance Audit Inspection Status : Compliant Canton Mill WWTP NPDES Permit No. NC0000272 Ha . ood County Dear Mr. Brown: The Performance Audit Inspection which Gary Francies of the Division' s Regional =Office Laboratory and I conducted on October 2, 1996 on Champion' s Canton Mill wastewater treatment program indicated that the self-monitoring program (flow measurement, sample collection, and laboratory analyses) was being conducted in accordance with terms and conditions contained in the subject NPDES Permit. Personnel present from the Mill during the inspection were: Derric Brown, John Pryately, Richard Davis, and Mike Cody. The purpose of this inspection was to determine the quality of the self-monitoring program being conducted by the Mill and assess the reliability of its reported data. The inspection consisted of evaluation of the following: flow monitoring equipment, sample collection and preservation techniques, and of laboratory analytical techniques, record . keeping and data reporting procedures : , The self-monitoring program being conducted by the Mill was shown to be operating according to applicable standards with the exception of some minor deviations which are outlined in the attached Laboratory On-site Inspection Report . Flow measurement and sampling procedures were acceptable. Interchange Building,59 Woodfin Place - NIAXAn Equal OpportFAX 704-251-6452 Asheville,North Carolina 28801 unity/Affirmative Action Employer Voice 704-251-6208 lll� 50%recycles/10%post-consumer paper Mr. Derric Brown October 30, 1996 Page Three B. LABORATORY EVALUATION 1 . FACILITIES AND EQUIPMENT: Laboratory space is adequate for testing performed for the facility. All equipment is well maintained. The lab routinely conducts NPDES testing for temperature, ammonia nitrogen, pH, five- day biochemical oxygen demand (BOD5) , dissolved oxygen, total suspended solids, total dissolved solids, total solids, chemical oxygen demand (COD) ,. total hardness, color, and settleable matter. Hydrologic Inc. , performs testing for effluent toxicity. Dioxin analysis is performed at Champion' s West Nyack lab. Zinc and chloroform analyses are performed at Pace Labs in Charlotte, NC. 2 . METHODOLOGY: All testing procedures are based upon Standard Methods 18th edition. Any deviations are addressed in the attached ON-SITE INSPECTION REPORT completed by Mr. Francies as part of the Laboratory Certification Program. A review of data revealed no errors . The facility appears to be doing a good job of accurately transferring data. a. Color; Values are being reported which are less than the established minimum reporting level. (REGULATORY REQUIREMENT) b. Ammonia Nitrogen; The meter being used does not calibrate a straight line curve when a multiple point calibration is performed. (REGULATORY REQUIREMENT) C . Ammonia Nitrogen; An unacceptable value was often obtained on the mid-range quality control standard. (REGULATORY REQUIREMENT) 3 . RECORDS KEEPING: Laboratory record keeping generally was appropriate and consistent with good laboratory practice . a. Fecal Coliform; Documentation is not kept for the quarterly calibration of the water bath thermometer. (REGULATORY REQUIREMENT) l i Mr. Derric Brown October 30, , 1996 Page Four b. Fecal Coliform; Documentation of the calibration of the pH meter used to check the media was lacking. (REGULATORY REQUIREMENT) The results of the laboratory analysis, not included in the attached Report, for the samples collected during the inspection will be forwarded to you upon receipt. Should you have any questions concerning this Report, please do not hesitate to contact me at 704-251-6208 . The assistance provided to me by all Mill personnel involved during the inspection was greatly appreciated. Si erely, D. Keith Ha es Environmental Specialist Attachment xc : Roger Pfaff, EPA Gary Francies United Siates mmental Protection Agency Form Approved •. W_------oton, D.C. 20460 OMB No. 2040-0003 PA NPDES Compliance Inspection Report Approval Expires 7-31-85 Section A: National Data System Coding Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 IN 21_.I 3 1 NC0000272 11 12 96/10/2 17 18 Iq I 19 �g � L I 201 Remarks u t_ , I` I I I I I I I I I I I I I I I I I I I I I I I I I I I I " Reserved Facility Evaluation Rating BI QA Reserved 67 I I I_I I69 70 14LJ I L 71 �N I 72 [N J j 73 �74 75 �ao W Section 0:Facility Date Name and Location of Facility Inspected Entry Time Permit Effective Date Champion International Corp. 8:30 am Canton Mill Canton, Haywood County Exit rime/Date Permit Expiration Date 4:30 pm Name(s)of On-Site Representative(s)/ritle(s) Phone No(s) Derric Brown- Environ. Supervisor 704-646-2318 Name,Address of Responsible Official Title Mr. Steve Hadden Vice-President/Operations Mgr. PO Box 10-C Canton, NC. 28716 Phone No. Contacted No Section C:Areas Evaluated During Inspection CODES L S-Satisfactory M-Marginal U-Unsatisfactory N-Not evaluated/Not applicable $ Permit $ Flow Measurement $ Pretreatment ES Operations &Maintenance S Records/Reports $ Laboratory N Compliance Schedules Sludge Disposal S Facility Site Review S Effluent/Receiving Waters $ Self-Monitoring Program Other. Section D:Summary of Findings/Comments (Attach additional sheets if necessary) Effluent Data ARO Mill Permit Limits(Daily Avg/Mon Ave) BODs = 7.1 mg/1 6.7 mg/1 30.0 mg/l - 45.0 mg/l TSS = 14 mg/l 13 mg/l 30.0 mg/l - 45.0 mg/l TR = 1776 mg/1 1713 mg/l COD = 154 mg/1 184 mg/l NH3 = 4.6 mg/l 6.4 mg/1 Fecal = 13/100 ml <20/100 ml Two of the four aeration basins were in operation, with the other two in the digester mode. One (#1) of the three primary clarifiers was down for repairs to the sweeper support shaft. All three final clarifiers were in operation. The Parshall Flume/flow meter is calibrated quarterly. Effluent flow at the time of the inspection was 24.7 MGD. Maintenance records are kept by computer in the treatment maintenance shop. Effluent samples were split with the facility. All sampler refrigeration units were operating at the proper temperature. One of the four belt presses was in operation and one was out of service for rebuilding. Maintenance work is still being performed on the aerator platforms. Name(s)and Signature(s) of Inspector(s) Agency/Office/Telephone Date D.KEITH HAYNES[ l/ DWQ/ARO 704-251-6208 ?6030 Si of Review r Agency/Office Date DWQ/ARO 704-251-6208 Regulatory Office Use Only Action Taken Date Compliance Status El Noncompliance P Compliance 1 Mr. Derric Brown October 30, 1996 Page Two The Performance Audit •Inspection (PAI) rating for this facility is "B" . A PAI rating sheet is attached for your review. FINDINGS AND RECOMMENDATIONS Recommendations found in this section will appear as PERMIT (REGULATORY) REQUIREMENTS to correct deviations or as SUGGESTIONS to strengthen the self-monitoring and laboratory program. Regulatory requirements will be referenced by the appropriate authority. A. FIELD EVALUATION 1. FLOW MEASUREMENT: Flow is measured prior to the 001 covered discharge structure using an eight foot free flow Parshall flume in conjunction with a Fischer & Porter Ultra-sonic flow meter with Foxboro recorder and totalizer. 2 . " The effluent sampling devices for outfall 001 are three ISCO model 3710 composite samplers. with refrigeration. Proportional composite samples are collected for every 250, 000 gallons of effluent . One of the samplers is used for special studies . Sampler tubing is changed on a monthly basis . The two influent composite samplers are both ISCO model 3170 with refrigeration. The temperature in each of the samplers was about 3°C. 3 . RECORD MAINTENANCE: Records and data handling procedures appear to be satisfactory and consistent with self-monitoring requirements contained in the NPDES Permit . 4 . PERMIT VERIFICATION: The Permit was issued by EPA and expired on October 24, 1994 . The Permit will be reissued by DWQ early in November to correspond with the French Broad River Basin Plan renewal schedule. 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A.;T.TGA og pagoadsuT span A3o4e3ogeT sTuy NolsonaMUNI I ApoO G--UN 'uMOag OTsiGQ 'ATGgeAzd uuOP :a3SOvSNOO (S)HOSHaci 7voo'I saToupag Aapo : (S)'HOIVnrMAS GOueuaguTeN :NOIS03dSNI ao 3d7l,L 96/Z/OT :NommaSNI ao 3S'da 86T :# 3s'dOIdIS2t30 9TL8Z ON 'uo4ue0 OT-0 xOg -'O •d :Ssauaa'd qpq dZMM T2uOT4euaa4ul uOTdIImLiO :3F1'dN xlaolvaoavi sxoazx Hozs0:gasxi asis-Ho Page 2 . Champion General Comments continued Effluent samples were split with the following results (all values are mg/1) : Champion Laboratory State Laboratory COD 184 154 Ammonia nitrogen, distilled, electrode Not Analyzed 4 . 9 undistilled, electrode 6.4 4 . 6 The States central lab also analyzed the ammonia nitrogen sample by the Automated Method and obtained a value of 5. 0 mg/l. TSS 13 13 . 5 Total Residue 1713 1776 Hardness 210 211 BOD 6.7 7 . 1 III. DEVIATIONS, REQUIREMENTS and COMMENTS: Color DEVIATION: Values less than the established minimum reporting level were reported. REQUIREMENT: For analytical procedures requiring analysis of a series of standards, the concentrations of these standards must bracket the concentration of the samples analyzed. One standard must have a concentration equal to the laboratory' s lower reporting concentration for the parameter involved. For example, if you choose to have a lower reporting limit of 5 mg/l for a particular parameter, you must analyze a 5 mg/1 standard and report lower samples as <5 mg/l . If you choose 100 mg/l for the top of your standard curve, you must analyze a 100 mg/1 standard and all samples above this limit must be diluted and reanalyzed to fall within 'the curve. For colormetric analyses a curve consisting of a blank and five standards must be analyzed. This curve must be checked each time samples are analyzed with a blank and a medium level standard. Instead of a standard curve, a three point (low, medium and high standard) curve may be 'analyzed with each group of samples . Ref: 15A NCAC 2H . 0805 (a) (7) (I) . COMMENTS : This occurs at the Big Creek _ sampling site with the spectrophotometric procedure. The minimum reporting level has been established at 10 C. U. Page 3. Champion Color continued COMMENTS: It is recommended that the absorbance reading of the lowest standard (minimum reporting level) occasionally be documented. It should be >. 005, preferably >. 010 absorbance units . COD COMMENTS: It is recommended that the absorbance reading of the lowest standard (minimum reporting level) occasionally be documented. It should be >.005, preferably >. 010 absorbance units. Ammonia nitrogen DEVIATION: The meter being used, an Orion 940, does not calibrate a straight line curve when a multiple point calibration is used. It makes a point to point calibration. A mid-range calibration check standard was not analyzed to verify both segments of the calibration. REQUIREMENT: The calibration curve must be checked with a mid-range standard. If a point to point curve is established, each segment must be verified. Ref: 15A NCAC 2H .0805 (a) (7) (I) . COMMENTS: If each segment of the curve is not checked, a linear regression calculation may be done to establish a straight line curve. Other options would be to do a two-point calibration or use the spectrophotometric procedure. DEVIATION: The value obtained on the mid-range quality control standard was often not acceptable. REQUIREMENT: For analyses that require a series of standards, a mid- range standard must be analyzed with each group of samples . When the mid-range standard varies by more than ± 10%, or is outside the established control limits, whichever is lower, the analysis is out of control. The analysis must be terminated and the problem corrected. Ref: 15A NCAC 2H . 0805 (a) (7) (B) , (F) and (I) . COMMENTS: It is recommended that the slope value be documented. The ten fold concentration millivolt change for should be 54-60 . If the slope value is not acceptable, the samples should be reanalyzed. l . Page 4 . Champion Fecal coliform DEVIATION: The water bath thermometer is calibrated quarterly, but is not documented. REQUIREMENT: Supporting records shall be maintained as evidence that these practices are being effectively carried out. All analytical records must be available for a period of three years . Ref: 15A NCAC 2H . 0805 (a) (7) and (a) (7) (G) . DEVIATION: The calibration of the pH meter used to check the media was - .� not documented. REQUIREMENT: See the requirement above. DEVIATION: The Town of Canton effluent sample was not dechlorinated. REQUIREMENT: All chlorinated samples must be dechlorinated at the time of sample collection. Ref: Standard Methods, 18th Edition - Method 9060 A.2 . IV. PAPER TRAIL: A review of data was conducted. This consisted of comparing laboratory bench sheets and contract lab reports to DMRs submitted to this Division. Data were reviewed for these months : Marchand June 1996. No errors were noted. It appears the facility is doing a good job of accurately transferring data. V. CONCLUSION: Overall, the laboratory is doing a good job and appears to be producing quality data. Upon correction of the above deviations, the requirements of certification will be met. Implementing the recommendations will further improve the quality of the data. Report prepared by: Gary Francies Date: 10/18/96 V `Juau1 � �✓ .; � f/f log Ado?I �/d3 C 11 h r�17-Urt1 i,.dM / tJ3Uh a� '?J-LLl 371vitl�fJ1 J° H�7 � 12'7 �71 n�j� /f{vIW.��'� Sn'ol�yCr�wwoy7-� S N 1 N�1,73SN%�3 "�D� �/'b��`�31MSb jaa,� Snlon*ag� �r.vsw�vv7 eL 94r'�d—a 71NI� o�r 133rans - of 9 0 31HO ON t Permit No. NC0000272 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT -� r _ . TO DISCHARGE WASTEWATER UNDER THE i NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM��/ In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Champion International Corporation is hereby authorized to discharge wastewater from a facility located at Champion Canton Mill Wastewater Treatment Plant off Highway 215 Canton Haywood County to receiving waters designated as the Pigeon River in the French Broad River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. The permit shall become effective This permit and the authorization to discharge shall expire at midnight on November 30, 2001. Signed this day F+N,i!-� DpAr- r— T A. Preston Howard, Jr., P.E., Director Division of Water Quality By Authority of the Environmental Mangement Commission �2nPr Rat - SuS:J'Ecr Tb 6�140J4e —Sue oN �I�,arcr v5 oPPicF2.5 Rc(oMMOA)DArnoag AND tDtAe(,roa's Ft) nW' 7tu5(aA1 Permit No. NC0000272 SUPPLEMENT TO PERMIT COVER SHEET Champion International Corporation Canton Mill Wastewater Treatment Plant Y is hereby authorized to: 1. Continue to operate an existing wastewater treatment facility for the treatment of wastewater d paper mill, the Town of Canton's and stormwater associated with the pulp an chlorinated domestic wastewater, and Champion's landfill leachate consisting of a grit chamber, bar screens, lift pumps, polymer addition, pH control (CO2 injection or H2SO4 backup), three primary clarifiers, nutrient feed, aeration basins, three secondary clarifiers, residual belt presses, effluent flow measurement, cascade aeration (with oxygen injection), and Canton mill gen Wast waterection facilities Treatment Plant, off Hiecified in ghway 215, Canton,located Hay Haywood County,Champion . 2. Discharge from said treatment works at the location specified on the attached map into the Pigeon River which is a Class C waters in the French Broad River Basin. I ,t�l.! v,✓�d 2B \ I _ _ -- s �rl� '' � e 1 ,fie• ��t Il�I 1�' 'M � � —�� '�q4 � 'i • •�� � Rock d IiVR •�`/1(e � �_of ;1 ����` ��� � • 1..�/' .� �� � ilo "a� _ �_ �r� ; . ���j'\!,����� No• antan�hj •� � Q%oo ti. { ..- .'" YKV // m _ �,�- � - c,r �, D%solid •.. ^'; /i � raHc r�/ aKJ i' .i• .V rYe Pofq IL :. "If. illy i• _ I'� 'µsr .�J• t\�l l"Zts — T)�� yYq L .,+�- .. Sm • ms� .. yam. ,f_ / •n vim✓ = %' ' ' ��- �� �7^� ROAD CLASSIFICATION SCALE 1 :24 000 =' PRIMARY HIGHWAY UGHr•DUTY ROAD,HARD OR 0 1 MILE HARD SURFACE IMPROVEDSURFACE e SECONDARY HIGHWAY 0 7000FEET HAROSURFACE C=311111111111= UNIMPROVED ROAD - 1 0 1 KII OMFTEP Lat: 35032'08" Long: 820 5042r rr =3 �= Map # E7SE Sub-basin 04-03-05 CONTOUR INTERVAL 5 FEET - ` Stream Class C ' =s QUAD LOCATION Champion International Discharge Class Indust rial/ Domestic Canton Mill WWTP Receiving Stream Roeon Rver r NC0000272 Qw: 29.9 Permit exp. 11/30/01 Haywood County A. (I). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NC0000272 During the period beginning on the effective date of the permit and lasting until expiration of the permit, the Permittee is authorized to discharge from outfall(s) serial number 001. Such discharges shall be limited and monitored by the pennillce as specified ied below: (Ufluent Characteristics Discharge Limitations Monitoring Requirements Lbs Units (Specifyi Measurement Sample ISample Mon. Avg. Daily Max. Mon. Avg, Rally Max. Frequency_ Tyne Location I-low 29.9 MGD Continuous Recording I or E UODs 3598.0 12458.0 Daily Composite E,I OCO Weekly Composite E TSS 12549.0 49560.0 Daily Composite E.1 NH3-N Daily Composite E Fecal Coliform 200 /100 ml 400 /100 ml Weekly Grab E Dissolved oxygen 2 Daily Grab E Total Nitrogen (NO2 + NO3 + TKN) Monthly Composite E 'total Phosphorus Monthly Composite E Temperature 3 Daily Grab E Chronic Toxicity 4 Quarterly Composite E Total Residue Daily Composite E Total Dissolved Solids Daily Composite E Hardness 2/Month Composite E Mercury s .014 pg/I 2/Month Grab E I Sample locations: E- Effluent, l - Influent. Instream sampling is specified in Part [, A (2). 2 The daily average dissolved oxygen effluent concentration shall not be less than 6.0 mg/l. See Part f, Section A(2)and Part III,Condition 1. 3 The monthly average instream temperature measured at a point 0.4 miles downstream of the discharge location shall not exceed 32.0°C during the months of July, August,and September and shall not exceed 29.0°C during the months of October through June. The monthly average instream temperature measured at this location shall not exceed the monthly average instream temperature of the upstream monitoring location by more than 13.9°C. See Part 111, Condition L. 4 Chronic Toxicity Testing at 87 %; March,June,September, and December; See Part Ill,Condition G. 5 The mercury limit shall be implemented December 1, 1997 unless those conditions specified in Part III, Condition M can be met. Values detected at less than 0.2 µg/I will be considered zero for 'purposes of compliance. The effluent pli shall not be less than 6.0 standard units nor greater than 9.0 standard units. '['here shall be no discharge of floating solids or visible foam in other than trace amounts. \. (I). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL (Continued) Permit No. NC0000272 During the period beginning on the effective date of the permit and lasting until expiration of the permit, the Permittee is authorized to discharge from outfali(s) serial number 001. Stich discharges shall be limited and monitored by the permiuce as specified below: Discharge Limitations Monitoring Requirements eristics Effluent Charact Lbs/day Units (S ep clfv) Measurement Samote 'Sampi Mon. Avg. Daily x.Ma Mon. Avg. Daily Max. Frequency Type Location Quarterly Composite E Trichlorophenol Quarterly Composite E Penlachlorophenol 2/Month Composite E Zinc Quarterly Composite. E Cadmium Quarterly Composite E Selenium Quarterly Composite E Silver Monthly Composite E AOX 0.1 pg/l Quarterly Composite E 2,3,7,8 Tetrachloro-dibenzo-p- dioxin (See Part III, Condition 11) Daily Composite , E,I Color (See Part III, Condition E) Daily Grab E Conductivity Daily Grab E 1�1 Part I DES No. NC0000272 A. (2). INSTREAM MONITORING REQUIREMENTS Stream Mile Location Description Parameter Frequency _Designation Marker UP 64 5 Pigeon River upstream of the Temperature : Daily waste treatment plant outfall D.O. Daily (prior to mixing with the BODS I/Week discharge) Conductivity Dail Color * e 2/Week Flow * Daily Fecal coliform DN 1 62.9 Pigeon River at Fiberville Bridge Temperature D�k D.O. Daily r Conductivity Daily Fecal Coliform I/Week DN2 Color * 2/Week 57.7 Pigeon River Above Clyde Temperature Daily DN3 D.O. Daily 55.5 Pigeon River Below Clyde Temperature I/Week - • D.O. I/Week DN4 Color * 2/Week 53.5 Pigeon River at NCSR 1625 Temperature 1/Week bridge D.O. I/Week Color * 2/Week DNS 42.6 Pigeon River at Hepco Temperature 1/Week D.O. I/Week Color * yWcek Flow * Dail Waterville Reservoir (See Pan III, Condition Annually IC) DN6 26.0 Pigeon River prior to mixing Color * 2/Week with BigCreek BC — 26.0 Mouth of Big Creek prior to Color * ypycek mixing with the Pi eon River D v? 24.7 Pigeon River at Browns Bridge Temperature I/Week (—NC/IN State Line) D.O. ]/Week BODS I/Week Color * yWcek All instream samples shall be grab samples. *Color(Additional,See Pan III,Condition E) All instream samples collected for these streams shall be representative of the Pigeon River and Big Creek,respectively. Both true and apparent color shall be monitored using the methods specified in Pan III, Condition E. Samples shall be collected at stations DN6, BC,and DN7 only during times when at least one generator at CP&L is in operation and releasing water to the Pigeon River. Flow monitoring is necessary,as specified above,for the True Color calculation stipulated in Part III,Condition E. Dissolved Oxygen. The average daily dissolved oxygen concentration measured at River Mile 62.9(DNI),57.7 (DN2), and 55.5 (DN3)shall not be less than 5.0 mg/l and the instantaneous minimum dissolved oxygen concentration shall not be less than 4.0 mg/1 (See Part III, Condition I). E. REQUIREMENTS FOR COLOR ANALYSIS AND COMPLIANCE 1) Champion shall take such action as necessary to prevent their contribution of true color from causing true color at the North Carolina/ Tennessee state line from exceeding 50 true color units at all flows equal to or exceeding 126 cfs.(81.4 MGD, the seven day, ten year low flow level). Compliance with this requirement shall be measured through a calculation of instream true color levels at the North Carolina/ _Tennessee stake line by the following eq SL _ (WTP� /R 341+((HEf-WfP f x Dcl c HE x 10 (-0.224 x LOG kru + 0.781) f Where: WTPc = Monthly average Waste Treatment Plant discharge color. Calculated as the average (pounds of all daily loading values (p of true color per day) for a calendar month. WTpf = Monthly average Waste Treatment Plant discharge flow (mad). I lE f = Monthly average HEPCO,North Carolina flow (mad) - daily now values less than 81.4 mad shall be entered as 81.4 mad. SLc = Monthly average Instream true color at North Carolina/Tennessee border (state line). D = Color concentration of all dilution c streams (13 C.U.). The SLc shall be calculated for each calendar month. The SLc values for each month shall not exceed 50 true color units. Any violation t is true color units for this average value shall be considered a violation of this permit. 2) The average daily discharge of true color for each calendar month shall not exceed 132,341 pounds per day. The average annual effluent true color loading shallexceed 1249923 pounds per day. For the purpose of this perindonly, "pounds of true color' is calculated by the following equation: Effluent Flow (mad)x Effluent True Color Level (Platinum Cobalt Units) x 8.34. 3) The method of analyses used to measure true color for this calculation shall be the procedure referenced in FR 39 430.11(b) (May 29, 1974). 4) All samples collected for color analysis shall be measured and reported as true color and apparent color using the procedure referenced in FR 39 430.11 (b) (May 29, 1974) -"true and apparent color. 5) Prior to the next permit renewal, the color model specified in 1) above, shall be recalibrated using the period of record and simulations specified in the supplement to the hearing record and in the color variance document. F. SCHEDULE FOR CONTINUED COLOR MINIMIZATION Champion shall continue to study, evaluate, and pursue color removal technologies and shall report its findings to the Division of Water Quality in accordance with the following schedule: Date Activitv Continuing Commercial demonstration of bleach filtrate recycling (BFRTM) March 1, 1998 In conjunction with, the Triennial Review of NC Water Quality Standards: 1) Submit a status report on the technical, economic, and operational feasibility of BFRTM technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2) Evaluate and 'report on end-of-pipe color reduction technologies. 3) Evaluate and report on minimization of color losses from manufacturing processes and from raw material storage areas. December 1, 1998 Based on the results of the demonstration project and the conclusions of the status report, Champion will decide and report on the decision to operate BFRTM technology as a fully commercial process on the pine line. December 1, 2000 Champion will evaluate color reduction strategies for further optimization of BFRTM technology and report on the feasibility of implementation on the hardwood line. March 1, 2001 Champion .will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of NC Water Quality Standards. June 1, 2001 Champion will submit a report to NCDEHNR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the variance review process (Triennial Review) and the NPDES renewal process. This NPDES permit shall be subject to reopening in order to modify the color requirements based upon any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion, and the Division of Water Quality, as soon as they are discovered. G. CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The permittee is required to perform the toxicity test as specified below or an equivalent toxicity test as approved by the Division. The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in the"North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised November 1995, or subsequent versions. The effluent concentration at which there may be no observable inhibition'of reproduction or significant mortality i87% (defined as treatment two in the procedure document).The permit holder shall perform auanerly monitoring using this procedure to establish compliance with the permit condition.The tests will be performed during the months of be March June Se tember and December.Effluent sampling for this testing shall performed at the NPDES pemutted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the rformed, Effluent Discharge Monitoring Form(MR-1) for the month in which it was pe : using the parameter code TGP3B. Additionally,DWQ Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Road Raleigh,North Carolina 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data.Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required,the permittee will complete the information located at the number, of the aquatic toxicity (AT)test form indicating the facility name, permit number,pipe county, and the month/year of the report with the notation of"No Flow"in the comment area of the form.The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should any single quarterly monitoring indicate a failure to meet specified limits,then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing,this monthly test requirement will revert to quarterly in the months specified above. , Should the permittee fail to monitor during a month in which toxicity monitoring is required,then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream,this dified to include alternate monitoring requirements or permit may be re opened and mo limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month ' following the month of the initial monitoring. H. DIOXIN MONITORING For permit compliance purposes, the point of compliance shall be defined as the final effluent before discharge. Compliance with the daily maximum permit limit shall be demonstrated by determining the TCDD concentration at the final discharge point. Adequate sample volume shall be collected to perform the analysis. The total sample volume shall be collected and preserved in accordance with Part 11, Section D Monitoring and Records. The sample shall be analyzed in accordance with the appropriate method of analysis specified in AlalVtleal procedures and Quality Assurance for Multimedia Analysis of Pol chlorinated Dibenzo are dioxins a )li.,chlorinated Dibenzofurans by High Resolution Gas Chromatoora h /Hi h Resolution Mass S ectromet ,EPA, 1987 (EPA Method 8290), or another equivalent analytical protocol approved by DWQ. A single sample may be analyzed to determine compliance with the daily maximum effluent limitation. Alternatively, a sample volume may be collected to enable the sample to be split (duplicate analysis). If the analysis of either split sample is below the detection limit, the quantity, for the purposes of compliance evaluation, is considered to be zero. If both splits are positive, the results of the two analyses shall be averaged to determine compliance with the daily maximum effluent limitation. If the measurement is below detection limits the q::y.:ity for the purposes of compliance evaluation is considered to be zero. The detection limit using these methods for the purpose of compliance evaluation is considered to be 10 picograms per liter. The dioxin isomer to be limited at the effluent by this permit is 2,3,7,8 TCDD. The chlorodibenzo dioxins and furans to be monitored are: DIOXIN DIBENZOFURAN Isomer Isomer 2,3,7,8 TCDD 2,3,7,8 TCDF 1,2,3,7,8 PeCDD 1,2,3,7,8 PeCDF 1,2,3,4,7,8 HxCDD 2,3,4,7,8 PeCDF 1,2,3,7,8,9 HxCDD 1,2,3,4,7,8 HxCDF 1,2,3,7,8,9 HxCDF 1,2,3,6,7,8 HxCDD 1,2,3,6,7,8 HxCDF 1,2,3,4,6,7,8 H CDD 2,3,4,6,7,8 HpCDF P 1,2,3,4,6,7,8 HpCDF 1,2,3,4,7,8,9 HpCDF Fish tissue analysis will be performed in accordance with the Division of Water Quality approved monitoring plan, which shall be reviewed as necessary. The monitoring plan is an enforceable part of this permit. All dioxin data collected as part of this monitoring requirement will be reported as required in the plan, no later than 180 days after sampling. The permittee shall perform the following analyses for the above listed isomers: Quarterly COMPOSITE 1. Influent to wastewater treatment facility Quarterly COMPOSITE 2. Sludge • Quarterly COMPOSITE 3. Landfi11leachate Quarterly COMPOSITE 4. Effluent r , 1. DISSOLVED OXYGEN REQUIREMENT concentration of not less The permittee shall maintain an average daily dissolved oxygenat River Miles than 5.0 mgl1 with a minimum instaZaneoussve value not te less than operate o�gen injection 62.9 (DNl), 57.7 (DN2), and 55S ( 9 n-dI P requirement . These facilities at the out structure,at 0.9 miles downstream with this hts disegchazge, and at 2.1 miles downstream of the discharge,as necessary,to comply facilities shall be operated in a manner which will maintainthe water quality standard for n use as a suplement to the dissolved oxygen in the Pigeon River downstream of the discharge. Champion shall report the date and duration of oxygen injectio p monthly Discharge Monitoring Report (DMR) forms. J. INFLOW[I.IFILTRATION AT THE TOWN OF CANTON The permittee shall make continued efforts to promote reduction of inflow/infiltration to the Town of Canton's wastewater collection system. K, WATERVILLE RESERVOIR SAMPLING REQU�MENT Sampling for Waterville Reservoir shall be conducted once annually during 1 and 2000. Sampling shall be performed during a low flow period to corresponndd with the with fish tissue study. Sampling parameters and stations are as follows: Parameters* Sampling Statr°n H, TN, Waterville Reservoir prior to Laurel Branch PO4, TP, Temperature, D.O., conductivity, p NO2 + NO3, NH3-N, TKN, Chlorophyll-a, Secchi Depth Waterville Reservoir near Wilkins Creek Same as above Same as above Waterville Reservoir near the dam All samples shall be collected at 0.1 meters beneath the surface of the water in the lake. L. TEMPERATURE VARIANCE REVIEW During the next permit renewal, Champion shall complete an analysis of temperature data using the period of record and simulations specified in the supplement to the hearing record. As part of this analysis, Champion shall submit a complete temperature variance report documenting the need for a continued temperature variance in accordance with 40 CFR 125, Subpart H. The report shall be submitted with the request for permit renewal, no later than June 1, 2001. r M. MERCURY MONITORING Mercury shall be monitored twice per month at the effluent for a period of twelve months after the effective date of the permit. Results shall be reported using a quantitation level of 0.2 µg/l. As indicated in Part I, A (1), a mercury limit of 0.014 µg/l shall be implemented twelve months after the effective date unless: 1) Champion submits the appropriate minor modification fee and requests that the Division of Water Quality review the existing effluent data upon completion of nine months worth of sampling, and 2) All effluent mercury samples indicate values less than the quantitation level during this nine month period. If both conditions 1) and 2) are met, the Division will modify the permit to eliminate the mercury limit and reduce the effluent monitoring to quarterly. N. BALANCED AND INDIGENOUS SPECIES STUDY. Champion shall submit a balanced and indigenous species study prior to the next permit renewal, no later than June 1, 2001. The study shall be performed in accordance with the Division of Water Quality approved plan. This plan shall be submitted for approval no later than March 1, 2000. The .balanced and indigenous study plan shall conform to the specifications outlined in 40 CFR 125 Subpart H. ENVIRONMENTAL MANAGEMENT COMMISSION RECEIVED OCT 1 .5 1996 IN THE MATTER OF REQUEST FOR ) EPnARCiiF_UT��64:1nl4Gi`^ T VARIANCE FROM WATER QUALITY ) CC,;""^""' STANDARD-BASED EFFLUENT ) MODIFICATION OF COLOR LIMITATIONS BY CHAMPION ) VARIANCE GRANTED INTERNATIONAL CORPORATION, ) ON JULY 13, 1988 CANTON,NORTH CAROLINA ) THIS MATTER came on to be heard before the NPDES (National Pollutant Discharge Elimination System) Committee of the North Carolina Environmental Management Commission at its scheduled meeting in New Bern, North Carolina, on October 9, 1996, pursuant to the NPDES Committee's proposal to modify an existing color variance granted to Champion International Corporation on July 13, 1988. - Upon duly made motion and vote, the NPDES Committee hereby adopts the following Findines of Fact and Conclusions of Law: FINDINGS OF FACT 1. Pursuant to a request for variance, dated January 12, 1988, submitted by Champion International Corporation ("Champion"), the NPDES (National Pollutant Discharge Elimination) Committee of the North Carolina Environmental Management Commission granted Champion a variance from the North Carolina water quality standard for color, as that standard is interpreted by the U.S. Environmental Protection Agency. The variance was memorialized in the NPDES Committee's Final Decision, dated July 13, 1988. 2. Pursuant to Ordering Paragraph 6 of its Final Decision, the NPDES Committee established-a Variance Review Committee to review the Canton Mill's proposed modernization program and to recommend any changes to the existing variance. As stated in Ordering Paragraph 6 of its Final Decision, the NPDES Committee is charged with determining "if changes in the variance are warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater." ee convened three times, and presented the results J. The Variance Review Committ ion's effluent color discharge to the NPDES Committee of its review and consideration of Champ at its March 13, 1996, meeting in Raleigh,North Carolina. 4. The Variance Review Committee made several recommendations to modify the existing variance to the NPDES Committee,through a verbal presentation at the March 13, 1996, meeting, and through memoranda dated March 7, 1996, from Greg Thorpe ("Review of Proposed Modifications to Champion's Canton Mill Color Variance by the NPDES Committee"), and March 6, 1996, from Dennis C. Loflin ("Consideration of Proposed Modifications to Champion International Corporation's Color Variance for the Canton Mill NPDES Permit"), which are incorporated herein by reference. 5. Based on a consideration of the Variance Review Committee's reports and e NPDES Committee voted to propose modifications to the existing recommendations, th variance, and directed its staff to carry out the public notice, comment and hearing process required by G.S. 143-215.3(e) and Ordering Paragraph 8 of its July 13, 1988,Final Decision. onducted by Mr. Harlan Britt, appointed as hearing officer 6. A public hearing was c for the NPDES Committee and for the contemporaneous NPDES permitting process, on June 6, 1996, in Haywood County,North Carolina. " 3 l 7. The hearing officer made several recommendations to modify the existing variance to the NPDES Committee, through a verbal presentation at the October 9, 1996, meetine,'and through a-memorandum dated October 2, 1996, which is'incorporated herein by reference. 8. Modificatioe of the variance as recommended by the Variance Review Committee r= AU not result in any discharge of waste that would endanger human health or safety. The variance for color is to allow discharge of wastewater at levels that will prevent Champion's contribution to the true color from causing the true color at the North Carolina/Tennessee State line to exceed 50 true color units at all flows equal to or greater than 126 cfs at the Hepco Gauging Station. The substance being discharged, for which the variance is sought, is not bioaccumulative. The color does not, at the volumes and levels involved here, present a risk of indirect or direct human impact or broad environmental damage. The waters are not water supply. Therefore, the discharge will not endanger human health or safety. 9. Reduction of color discharge by application of best available technology is still not economically reasonable and results in serious hardship without equal or greater benefit to the public. A detailed and thorough study and evaluation of color removal technologies was performed and reported in Champion's 1995 and 1996 Color Removal Teehnoiogv Reports submitted to Division as required by the existing color variance. 10. Champion has now completed its mill modernization project which re-con gured its facility as an oxygen delignification, 100% chlorine dioxide substitution (OD-100) bleach mill. The project resulted in limited color reduction in its effluent discharge. The end-of-pipe technologies considered in 1988 and updated for the 1996 review .established: a) standard ,4 waterhvastewater separation technology (lime, alum, or polymer) has not been applied in a similar fashion,b)these technologies would result in high capital and operating costs at the mill, c) color reduction on this type of waste, using these type technologies' has no operational rmal paper mill production variations, and consistent efficiency track record" (effective under no moval), and d) the pr ocess color removal effectiveness of OD-100 may and reproducible color re present other in-process reduction opportunities that have not yet been realized. 11. A schedule for continued color minimization is necessary. Members of the " public. EPA and the State of Tennessee commented that the variance document proposed in the public notice did not include any milestones for continued color reduction. Therefore, the schedule contained in the Ordering Paragraph 4, infra, is established. 12. In review of the color data, including the short time since the re-configured mill became_ fully operational, it is determined that a more restrictive limitation should apply for color. Therefore, the more restrictive monthly and annual average color limitations contained in the Ordering Paragraph 2, infra, are established. _ olor discharge information from the 13. Based on the continued development of c hampion is required to statistically evaluate its monthly average color reconfigured mill, C discharge, its annual average color discharge, and the performance of the state line color mto be These evaluation processes are to be ongoing and the results of the evaluations are required reported to the Division of Water Quality prior to each water quality standards triennial review period. The results of these evaluation processes shall be utilized by the Division and the next variance Review Committee to make recommendations to the NPDES Committee on future 5 revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and the hearing officer, in reporting these evaluations. 14. As provided in Findings of Fact#8, supra, Champion is also required to take such actions as necessary to prevent their contribution of true color from exceeding 50 true color units at the North Carolina/Tennessee state line at all flows equal to or greater than 126 cfs at the r Hepco Gauging Station. Furthermore, the method by which compliance is determined shall continue to be the color predictive model. CONCLUSIONS OF LAW 1. Pursuant to the Ordering Paragraph 6 of the July 18, 1988, Final Decision, the NPDES Committee has reviewed the existing variance following the Champion Canton Mill modernization program. 2. The previously existing variance from the North Carolina water quality standard for color, memorialized in the NPDES Committee's Final Decision, dated July 18, 1998, remains in effect except as specifically modified herein. 3. Based on the effectiveness of the treatment system subsequent to the Canton Mill modernization project and due to the potential for improvements in color reductions by use of bleach filtrate recycling (BFR"), changes to the variance are warranted. Based on the foregoing Findings of Fact and Conclusions of Law, it is hereby ORDERED that the previously existing variance from the North Carolina water quality standard for color as memorialized in the July 13, 1988 Einal Decision Ordering Paragraphs, continues in effect as hereby modified, to read as follows:' ' For ease of reference, the language of the July 13, 1988 Final Decision Ordering Paragraphs is included verbatim, with the modifications denoted by overstriking for deletions ;6 van is granted, pursuant to G.S. 143-214.3(e), as a 1 Champion's petition for a variance to water quality based effluent limitations for color. 2. The Division of r ,, ,,r.,�Water Quality' shall issue NPDES Permit No. NC0000272, for the Canton Mill,•and medif3 draft its provisions to reflect all the this modification, conditions of r including the following specific wording. 1 Champion shall take such action as necessary to prevent their contribution of true color from causing the true color at the North Carolina/Tennessee State line from exceeding S& 50 true color units at flows equal to or exceeding 126 cfs (81.4 MGD, the seven-day, low flow level) at the Hepco Gauging Station. on of instream true color leveComliance with this requirement shall be measured throuh a ls at the North Caro ina/Tennessee sta eclinelby the following equation: \ RE4� Sly_ (NyTP"LR 41 + ((HEt_--MaRtLDW (-0.224 x LOG(ITO+ 0.781) HEf x 10 Where: tNTp�= Monthly average Waste Treatment Plant discharge color. (E-L� age of all daily loading values (pounds of true Calculated as the aver color per day) for a calendar month. Wrlpf= Monthly average Waste Treatment Plant discharge flow(mgd). HE/ = Monthly average HEPCO, North Carolina flow (MGD). Daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. and bolding for additions. Management has been reorganized and NPDES 2The Division of Environmental Manag permitting is now administered by the Division of Water Quality. 7 , SI, = Monthly average Instream true color at North Carolina/Tennessee border(state line). D,= Color concentration of all dilution streams (13 C.U.). The SL,-shall be calculated for each calendar month. The aver-age of any'ea. 11--days) r ealeulated SL values for each month shall not exceed SS 50 true color units. Any exceedance Of '95 50 true color units for this average value shall be considered a violation of this permit/variance aYePpt as Y e .:.,ea in T **,z==_ f II. The average daily discharge of true color for each calendar month shall not exceed258,945 132,341 pounds per day. The average annual effluent true color loading shall not exceed 172,368 124,923 pounds per day. •For the purpose of this permit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. III. Champien is nei required te edu dailya ♦1 effluent tFae 7 leading to less than 124,193 _ a per a JL PIL. The method of analyses used to measure true color shall be the procedure referenced in FR 39 430.11(b) (May 29, 1974). 3. The Division of Effi,irenmenW ManagefneiA Water Quality shall include review of this variance as a specific item in its Triennial Water Quality Standards review, as required by the federal Clean Water Act, and make appropriate recommendations to the NPDES Committee. 4. 'Champion shall continue to study, 'artd evaluate and pursue color removal technologies and shall report its findings to the Division of Efwireflmeatal MmagemeWater Quality im nedintel upen dissevery d afmuallyon er bee_ April en. _f _--h ye in accordance with the following schedule: \ 8 ^ DATE ACTIVITY Continuing Commercial demonstration of bleach filtrate recycling(BFRT") _ March 1, 1998 In conjunction with the scheduled Triennial Review of N.C.Water Quality Standards: 1, Submit a status report on the technical, economic, and operational feasibility of r` BFRTb1 technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. 2. Evaluate and report on end-of-pipe color reduction technologies. . 3. Evaluate and report on minimization of color losses from manufacturing process and from raw material storage areas. December 1, 1998 Based on the results of the demonstration project and the conclusion of the status report. Champion will decide and report on the decision to operate BFRT" technology as a fully commercial process on the pinewood line. December 1,2000 Champion will evaluate color reduction strategies for further optimization of BFRT" technology and report on the feasibility of implementation on the hardwood line. March 1,2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. June 1,2001 Champion will submit a report to N.C. DEHNR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the variance review process (Triennial Review of North Carolina Water Quality Standards). q 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee amually, an erbefore Ame 30 of eae ""_, prior to completion of the Triennial Water Quality Standards review. 5A. Based on the continued development of color discharge information from the reconfigured mill, Champion will statistically evaluate its monthly average color discharge, r its annual average color discharge, and the performance of the state line color.model.-This evaluation process shall be ongoing and the results of the evaluation shall be reported to the Division prior to each triennial review period referenced in this variance. The results of this evaluation process will be utilized by the Division and the Variance Review Committee to make recommendations to the NPDES Committee on revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and,the hearing officer in reporting these evaluations.Fella'Ain . ,. r i and r arA In conjunction with the firs subsequent triennial water quality standards reviews aft r a tFieaaial , the Division will nominate a variance review committee. The NPDES Committee will have final approval of the selection of this committee. _A44eh will Committee membership may consist of Natural ReseuE nd- Developinen Department Staff and at least twe individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university or research communities; That review committee's report and recommendation will be examined by the NPDES Committee fora decision on the adequacy of the existing variance. The NPDES 3 The Variance Review Committee membership qualifications are changed to provide greater flexibility in appointments. 10 , Committee will determine if changes-in the variance are warranted due to the effectiveness of the treatment system or because of advances in color reduction technologies for this type wastewater. All revisions adopted by the NPDES Committee will require the modification of the Company's State NPDES Discharge Permit. 7: The variance proceeding, and the NPDES Permit No. NC 0000272, shall at all times be subject to reopening .in order to modify the color requirements based upon any breakthrough in color removal technologies.-Such breakthroughs shall be brought to the NPDES Management Committee for consideration, by Champion and the Division of Water Quality, as soon as they are discovered. g, This variance shall extend for an indefinite period of time, subject to ,, — and Any modification or consideration of the three-year reviews ="� termination based thereon shall be subjected to the public hearing process required by G.S. 143-21 5.3(e). it is further ORDERED that this Modification of Color Variance shall be effective as of -issued NPDES Permit No. NC 0000272 for the Canton Mill, and the the effective date of the re terms of the previously existing variance shall continue in effect until that time. This the day of October, 1996. Daniel V. Besse, Chairman NPDES Committee 12 CERTIFICATE OF SERVICE This is to certify that I have this day served a copy of the foregoing MODIFICATION OF COLOR VARIANCE GRANTED ON JULY 13, 1988 on the parties listed below by the methods indicated, addressed to each as follows: U.S. MAIL William Clarke Roberts & Stevens Suite 900 r One W. Park Square Asheville,North Carolina 28802 A. Preston Howard.Jr.,Director HAND DELIVERY Division of Water Quality N.C. Department of Environment,Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 HAND DELIVERY Jennie Odette, Clerk Environmental Management Commission N.C. Department of Environment,Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 U.S.MAIL Paul Davis Tennessee Department of Environment & Conservation 6th floor, L & C Annex 401 Church Street Nashville,Tennessee 37243-1534 U.S.MAIL David McKinney Tennessee Wildlife Resources Ellington Agriculture Center p. 0. Box 40747 Nashville,Tennessee 37204 U.S. MAIL Gary Davis Tennessee Environmental Council 1700 Hayes Street. Suite 101 Nashville.Tennessee 37203 13 Mike McGhee U.S. MAIL Director of Water Management 100 Alabama Street, S W Atlanta, Georgia 30303 This the 15th day of October, 1996. MICHAEL F. EASLEY Attorney General /13354 //nn Daniel C. Oakley , Senior Deputy Attorney General Environmental Division P. O. Box 629 Raleigh,North Carolina 27602-0629 919/733-5725 ENVIRONMENTAL MANAGEMENT COMMISSION RECEIVED OCT 1.5 1990 IN.THE MATTER OF REQUEST FOR ) " Et+�,1RCtF!c4T14 n!�G4_ r VARIANCE FROM WATER QUALITY STANDARD-BASED EFFLUENT ) MODIFICATION OF COLOR LIMITATIONS BY CHAMPION ) VARIANCE GRANTED INTERNATIONAL CORPORATION, ) ON JULY 13, 1988 CANTON,NORTH CAROLINA ) THIS MATTER came on to be heard before the NPDES (National Pollutant Discharge Elimination System) Committee of the North Caroliria•Environmental Management Commission at its scheduled meeting in New Bern, North Carolina, on October 9, 1996, pursuant to the NPDES Committee's proposal to modify an existing color variance granted to Champion International Corporation on July 13, 1988. Upon duly made motion and vote, the NPDES Committee hereby adopts the following Findings of Fact and Conclusions of Law: FINDINGS OF FACT 1. Pursuant to a request for variance, dated January 12, 1988, submitted by Champion International Corporation ("Champion"), the NPDES (National Pollutant Discharge ' Elimination) Committee of the North Carolina Environmental Management Commission granted Champion a variance from the North Carolina water quality standard for color, as that standard is interpreted by the U.S. Environmental Protection Agency. The variance was memorialized in the NPDES Committee's Final Decision, dated July 13, 1988. 2. Pursuant to Ordering Paragraph 6 of its Final Decision, the NPDES Committee established a Variance Review Committee to review the Canton Mill's proposed modernization 2 program and to recommend any changes to the existing variance. As stated in Ordering Paragraph 6 of its Final Decision, the NPDES Committee is charged with determining "if changes in the variance are warranted due to the effectiveness of the treatment system or because ' of advances in color reduction technologies for this type wastewater." 3. The Variance Review Committee convened three times, and presented the results r r of its review and consideration of Champions effluent color discharge to the NPDES Committee at its March 13, 1996, meeting in Raleigh,North Carolina. 4. The Variance Review Committee made several recommendations to modify the existing variance to the NPDES Committee, through a verbal presentation at the March 13, 1996, meeting. and through memoranda dated March 7, 1996, from Greg Thorpe ("Review of Proposed Modifications to Champion's Canton Mill Color Variance by the NPDES Committee"), and March 6. 1996, from Dennis C. Loflin ("Consideration of Proposed Modifications to Champion International Corporation's Color Variance for the Canton Mill NPDES Permit"), which are . incorporated herein by reference. 5. Based on a consideration of the Variance Review Committee's reports and recommendations, the NPDES Committee voted to propose modifications to the existing variance, and directed its staff to carry out the public notice, comment and hearing process required by G.S. 143-215.3(e) and Ordering Paragraph 8 of its July 13, 1988,Final Decision. 6. A public hearing was conducted by Mr. Harlan Britt, appointed as hearing officer for the NPDES Committce and for the contemporaneous NPDES permitting process, on June 6, 1996, in Haywood County,North Carolina. _.3 7• The hearing officer made several recommendations to modify the existing variance to the NPDES Committee, through a verbal Presentation .at the October 9, 1996, meeting, and through a memorandum dated October 2, 1996, which is incorporated herein by reference. 8. Modification of the variance as recommended by the Variance Review Committee Y., will not result in any discharge of waste that would endanger human health or safety. The variance for color is to allow discharge of wastewater at levels that will prevent Champion's contribution to the true color from causing the true color at the North Carolina/Tennessee State line to exceed 50 true color units at all flows equal to or greater than 126 cfs at the Hepco Gauging Station. The substance being discharged, for which the variance is sought, is not bioaccumulative. The color does not, at the volumes and levels involved here, present a risk of indirect or direct human impact or broad environmental damage. The waters are not water supply. Therefore, the discharge will not endanger human health or safety. 9. Reduction of color discharge by application of best available technology is still not economically reasonable and results in serious hardship without equal or greater benefit to the public. A detailed and thorough study and evaluation of color removal technologies was performed and reported in Champion's 1995 and 1996 Color Removal Technolo Reports in submitted to Division as required by the existing color variance. 10. Champion has now completed its mill modernization project which re-configured its facility as an oxygen delignification, 100% chlorine dioxide substitution (OD-100) bleach mill. The project resulted in limited color reduction in its effluent discharge. The end-of--pipe technologies considered in 1988 and updated for the 1996 review established: a) standard .4 _ water/wastewater separation technology (lime, alum, or polymer) has not been applied in a similar fashion,b)these technologies would result in high capital and operating costs at the mill, c) color reduction on this type of waste, using these type technologies has no operational efficiency "track record" (effective under normal paper mill production variations, and consistent and reproducible color removal), and d) the process color removal effectiveness of OD-100 may present other in-process reduction opportunities that have not yet been realized. Members of the 11. A schedule for continued color minimization is necessary. ate of Tennessee commented that the variance document proposed in the public. EPA and the St public notice did not include any milestones for continued color reduction. Therefore, the schedule contained in the Ordering Paragraph 4, infra, is established. 12. In review of the color data, including the short time since the re-configured mill is determined that a more restrictive limitation should apply for became fully operational, it - ons contained in color. Therefore, the more restrictive monthly and annual average color limitati the Ordering Paragraph 3, infra, are established. 13. Based on the continued development of color discharge information from the nthly average color reconfigured mill, Champ Y Champion is required to statistically evaluate its mo " discharge, its annual average color discharge, and the performance of the state line color model. These evaluation processes are to be ongoing and the results of the evaluations are required to be reported to the Division of Water Quality prior to each water quality standards triennial review period. The results of these evaluation processes shall be utilized by the Division and the next Variance Review Committee to make recommendations to the NPDES Committee on future 5 revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and the hearing officer, in reporting these evaluations. 14. As provided in Findings of Fact#8,supra, Champion is also required to take such actions as necessary to,prevent their contribution of true color from exceeding 50 true color units at the North Carolina/Tennessee state line at all flows equal to or greater than 126 cfs at the a r Hepco Gauging Station. Furthermore, the method by which compliance is determined shall continue to be the color predictive model. CONCLUSIONS OF LAW - 1. Pursuant to the Ordering Paragraph 6 of the July 18, 1988, Final Decision,-the NPDES Committee has reviewed the existing variance following the Champion Canton Mill modernization program. 2. The previously existing variance from the North Carolina water quality standard for color, memorialized in the NPDES Committee's Final Decision, dated July 18, 1998, remains in effect except as specifically modified herein. 3. Based on the effectiveness of the treatment system subsequent to the Canton Mill modernization project and due to the potential for improvements in color reductions by use of bleach filtrate recycling (BFRTm), changes to the variance are warranted. Based on the foregoing Findings of Fact and Conclusions of Law, it is hereby ORDERED that the previously existing variance from the North Carolina water quality standard for color as memorialized in the July 0, 1988 Final Decision.Ordering Paragraphs, continues in effect as hereby modified', to read its follows:[ For ease of reference, the language of the July 13, 1988 Final Decision Ordering Paragraphs is included verbatim, with the modifications denoted by overstriking for deletions 6 1. Champion's petition for a variance is granted, pursuant to G.S. 143-214.3(e), as a variance to water quality based effluent limitations for color. 2. The Division of *4a ent Water Quality2 '" shall issue NPDES Permit No. NC0000272, for the Canton Mill, and medi€y draft its provisions to reflect all the i ooc a a cvn *T;ppEc ^exit this modification, conditions of r including the following specific wording. 1. Champion shall take such action as necessary to prevent their contribution of true color from causing the true color at the North Carolina/Tennessee State line from exceeding Sd 50 true color units at all flows equal to or exceeding 126 cfs (81.4 MGD, the seven-day, ten-year low flow level) at the Hepco Gauging Station. Compliance with this requirement shall be measured through a calculation of instream true color levels at the North Carolina/Tennessee state line by the following equation: 91 1�4�18 Sl._ (WTP / 8 341 + ((Uf_—W_UOJD-J (-0.224xLOG(HE,)+ 0.781) HEfx 10 Where: WTP,= Monthly average Waste Treatment Plant discharge color. (C—L�3 Calculated as the average of all daily loading values (pounds of true color per day) for a calendar month. WTPf= Monthly average Waste Treatment Plant discharge flow(mgd). HEf = Monthly average HEPCO, North Carolina flow (MGD). Daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. and bolding for additions. '- The Division of Environmental Management has been reorganized and NPDES permitting is now administered by the Division of Water Quality. • ram• 7 SI, = Monthly average Instream true color at North Carolina/Tennessee border(state line). D,= Color concentration of all dilution streams (13 C.U.). The SL, shall be calculated ee-a- y-?3asis for each calendar month. The average of a�l ealead& week (seven days) ef ealeul SL, values for each month shall not exceed 83 50 true color units. Any exceedance of 83 50 true color units for this average value shall be considered a violation of thus permit/variance exee r n r t • -�� cded ' * ill r L• r I� II. The average daily discharge of true color for each calendar month shall not exceed 258,945 132,341 pounds per day. The average annual effluent true color loading shall not exceed 17'_� 124,923 pounds per day. For the purpose of this pennit/variance only, "pounds of true color" is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. I Gha.mrinr is net required te feduee L daily ra leading, less F ian '1'A 1 n: p a a a •e 1 v �'p�4cJ- l The method of analyses used to measure true color shall be the procedure referenced in FR 39 430:11(b) (May 29, 1974). 3. The Division of>;...•:_... .. eat l ManagementWater Quality shall include review of this variance as a specific item in its Triennial Water Quality Standards review, as required by the federal Clean Water Act, and make appropriate recommendations to'the NPDES Committee. 4. Champion shall continue to study study, a*d evaluate' and pursue color removal technologies.and shall report its.findings to the Division of,;nvife l *R z ea � Water �" _ Quality d r}�-upaii-disee PN and aaii 11y en er beAre A '1 30 C 1 yeaF in accordance with the following schedule: 8 _ DATE ACTIVITY Continuing Commercial demonstration of bleach filtrate recycling 03FRTM March 11 1998 In conjunction with the scheduled Triennial Review of N.C.Water Quality Standards: I. Submit a status report on the technical, economic, and operational feasibility of BFRT" technology, including those analyses prepared for other permitting agencies concerning its effects on air emissions. „ 2. Evaluate and report on end-of-pipe color reduction technologies. 3. Evaluate and report on minimization of color losses from manufacturing process and from raw material storage areas. December 1, 1998 Based on the results of the demonstration project and the conclusion of the status report. Champion will decide to report ep technology on ahe decision to operate BFRT" g s a fully commercial process on the pinewood line. December 1,2000 Champion will evaluate color reduction strategies for further optimization of BFRT" technology and report on the feasibility of implementation on the hardwood line. March 1,2001 Champion will evaluate and report on end-of-pipe color reduction technologies in conjunction with the Triennial Review of N.C. Water Quality Standards. June 1,20U1 Champion will submit a report to N.C. DE11NR, Division of Water Quality, on the comparative evaluation of the above collective efforts as part of the variance review process (Triennial Review of North Carolina Water Quality Standards). _ r _ 9 5. The Division will provide a status summary report on color removal at the Canton Mill to the NPDES Committee " '^ Af prior to completion of the Triennial Water Quality Standards review. 5A. Based on the continued_development of color discharge information from the reconfigured mill, Champion will statistically evaluate its monthly average color discharge, Y its annual average color discharge, and the performance of the state line color model. This evaluation process shall be ongoing and the results of the evaluation shall be reported to the Division prior to each triennial review period referenced in this variance. The results of this evaluation process will be utilized by the Division and the Variance. Review Committee to make recommendations to the NPDES Committee on revisions to the variance. Champion shall follow the Color Data Variance Review Requirements proposed by the staff and the hearing officer in reporting these evaluations. 6. Fellewing the eempl n.,...,.f the _ w 41's __i - - a-d In conjunction Nvith theist subsequent triennial water quality standards reviews aft st ,p ...t f _ eaeh fell, .....,a tdie • , ;qp4AAthe Division will nominate a variance review . committee. The NPDES Committee will have final approval of the selection of this committee. v4iieh will Committee membership. may consist of bra^ ! Rese ees. and G �ffter Development Department Staff and aleas4individuals considered authorities on pulp and paper technology or environmental aspects of that industry from the university. or research communities' That review committee's report and recommendation will be examined by the NPDES Committee fora decision on the adequacy of the existing variance. The NPDES The Variance Review Committee membership qualifications are changed to provide greater flexibility in appointments. . .10 - variance are warranted due to the effectiveness of the Committee will determine if changes in the treatment system or because of advances in color reduction technologies for this type wastewater. the modification of the Company's All revisions adopted by the NPDES Committee will require $rate NPDES Discharge Permit, S Permit No. NC 0000272, shall at all 7.: The variance proceeding, and the NPDE times be subject to reopening in order to modify the color requirements based upon any breakthrough in color removal technologies. Such breakthroughs shall be brought to the NPDES Committee for consideration, by Champion and the Division of n Water Quality, as soon as they are discovered. g. This variance shall extend for an indefinite period of time, subject to h ��. - and Any modification or consideration of the three-year reviews �^^�`'� termination based thereon shall be subjected to the public hearing process required by G.S. 143-215.3(e). It is further ORDERED that this Modification of Color Variance shall be effective as of the re-issued NPDES Permit No.NC 0000272 for the Canton Mi1L and the the effective date of existing variance shall.continue in effect until that time. terms of the previously This the day of October, 1996. Daniel V. Besse, Chairman r NPDES Committee 12 CERTIFICATE OF SERVICE This is to certify that I have this day served a copy of the foregoing MODIFICATION OF COLOR VARIANCE GRA-NTED ON JULY 13, 1988 on the parties listed below by the methods indicated, addressed to each as follows: William Clarke U.S. MAIL Roberts & Stevens Suite 900 e One W. Park Square Asheville,North Carolina 28802 A.Preston Howard. Jr.,Director HAND DELIVERY Division of Water Quality N.C. Department of Environment,Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 Jennie Odette, Clerk HAND DELIVERY Environmental Management Commission N.C. Department of Environment, Health and Natural Resources 9th floor, Archdale Building Raleigh,North Carolina 27601-7687 U.S. MAIL Paul Davis Tennessee Department of Environment & Conservation 6th floor, L & C Annex 401 Church Street Nashville,Tennessee 37243-1534 U.S. MAIL David McKinney Tennessee Wildlife Resources Ellington Agriculture Center . P. 0. Box 40747 Nashville,Tennessee 37204 Gary Davis U.S. MAIL Tennessee Environmental Council 1700 Hayes Street, Suite 101 Nashville,Tennessee 37203 13 Mike McGhee U.S. MAIL Director of Water Management 100 Alabama Street, SW Atlanta,,Georgia 30303 This the 15th day of October, 1996. MICHAEL F. EASLEY Attorney General /13354 Daniel C. Oakley , Senior Deputy Attorney General Environmental Division P. 0. Box 629 Raleigh,North Carolina 27602-0629 919/733-5725 FA('l SHEET: CHAMPION - CANTON`M ii,NC0000272 REVISED DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF WATER QUALITY -. FRCT SHEET REVISED APPLICATION FOR NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT TO DISCHARGE TREATED WASTEWATER x. Application No. NC0000272 Date: 9/30/96 1. ' SYNOPSIS OF APPLICATION Applicant's Name Champion Intemational Corporation-Canton Mill WWTP Applicant's Address P. 0. Box C - 10 Canton, NC 28716 Facility Address off Highway 215 Canton Haywood County T e of Operation Integrated bleached Kraft pulp and paper manufacturing facility producing food board and fine paper. Design Capacity of Facility Treatment of wastewater stormwater associated with pulp and paper mill, chlorinated domestic wastewater from the Town of Canton, and leachate from Champion's existing landfill. The plant will be limited at 29.9 MGD average monthly flow. Production Capacity of Facility 712 tons per day BCT bleached Kraft 901 tons per day fine bleached Kraft (This is based on the NPDES permit renewal application submitted by Champion) Applicant's Receiving Water Receiving Stream: Pigeon River Classification: C Sub-Basin: 04-03-05 Page 1 FACTSHEET: CHAMPION - CANTON MILL,NC0000272 REVISED See Attachment A for a map showing the discharge location(s). Description of Wastewater Treatment Facilities The wastewater treatment facility consists of a grit chamber,bar screens,lift Pumps, polymer addition,pH control (CO2 injection or H2SO4 backu ),three Primary nutrient feed, aeration basins,three secondary clarifiers,residual belt presses, effluent flow measurement,cascade aeration(with oxygen injection), and oxygen injection facilities. The treatment plant receives an average of 0.9 MGD of chlorinated domestic (untreated).wastewater from the Town of Canton; leachate from Champion's existing landfill (which has variable flow based on storm incidences); stormwater; and the majority of wastewater from pulp and paper mill production and associated process wastewater. North Carolinas wastewater treatment plant certification guidelines rate this plant as a Class IV facility. Unless otherwise noted,monitoring frequencies reflect a Class IV facility as outlined in 15A NCAC 2B .0500. Summary of Existing Wastewater Treatment Plant Operation See Attachment B (copy of the EPA issued permit-excluding boiler plate language). Type of Wastewater(as reported by applicant). 3 %Domestic (approximately 0.9 MGD from the Town of Canton) 97 %Industrial 2. PROPOSED EFFLUENT LIMITATIONS Basis for Final Effluent Limits and Permit Conditions This permit was previously issued in 1989 by EPA. From that time, Champion has incorporated thethe oxygen delignifrcation process and elemental chlorine freewith art of C other internal modificatiolant as ns has significantly reduced the effluent :MP (Canton Modernization flow(from 485 MGD to 29.9 MGD). The production values listed in 1. above were used to calculate the federal effluent guideline limits for Pulp,Paper, and Paperboard Point Source Category(See Attachment). However,the Champion Mill is water quality limited for BODS,so more stringent limits have been applied. BODSandlnst m Dissolved Oxyeen: An EPA-approved computer model indicated that more stringent limits than those given by federal effluent guidelines were necessary to protect North Carolinas instream dissolved oxygen standard of 5 mg/l for Class C waters [15A NCAC 2B .0211 (b) (3) (B)]. ol to the absence of an end-of-pipe technology capable of consistently treating to levels necessary to meet the limits specified by the model,North Carolina has agreed with the continuation of the requirement that Champion meet the instream dissolved oxygen standard by use of sidestream oxygen injection facilities, as necessary (See Part III, Page 2 F,4C -,�.IEET: CHAMPION - CANTON Ml- , NCoo60272 REVISED Condition I of the draft permit). Historically, Champion has maintained oxygen injection facilities at the effluent and at approximately 0.9, 2.1, and 3.7 miles downstream of the discharge. Oxygen injection facilities will continue to be maintained at the effluent, 0.9, and 2.1 miles-downstream, and used as necessary to maintain an instream`dissolved.oxy&n' level of 5 mg/l."To ensure'compliarice with the above requirement,the average daily instream dissolved oxygen levels at river miles 62.9, 57.7, and 55.5 shall not be less than 5 mg/1 and the minimum instantaneous instream value shall not be less than 4 mg/l. This method is acceptable based on 40 CFR 125.3 (f). Extensive instream monitoring is required to assess Champion's impact on the Pigeon River and to ensure that the dissolved oxygen standard is maintained throughout the impacted zone of the river(See Part I.A(2) of the draft permit). No instream D.O. violations have occurred since 1990. The draft permit BOD5 limit was established based on the demonstrated level of performance of the existing treatment plant(a site specific Best Available Technology requirement). The monthly average BOD5 limit (3598 lbs/day)is based on the 95th percentile value analyzed by the Log-Pearson Skew method on data from 1/91 to 12/95. The 1/91 to 12/95 data were used as a result of the incomplete data base of post-CMP values at optimal production and the need to simulate the projected mill " variability under post CMP conditions including cold mill shut downs and start ups. The 95th percentile represents two standard deviations around the mean of daily values. In this way, day-to-day variability is measured and used to set monthly average limits. Although the Log Pearson III method is not typically applied to monthly averages, in this case the 60 data values were a skewed " distribution. Upon the next permit renewal, post-CMP data, from 8/95 to the renewal application date will be used for the data analysis (and analyzed based on influent values and plant removal efficiencies). Based on limited post-CMP and optimal production data, and as a result of the fact that Champion is in the demonstration process of Bleach Filtrate Recycle (BFR), the above procedure was used for this permit cycle. The daily maximum value has remained the same as the previous permit(124581bs/day). During the next permit renewal,the post-CMP monthly average:daily maximum ratio will be compared and used to calculate a new daily maximum. As stated previously, the Champion Canton Mill cannot comply with the predicted BOD5 level to protect the instream dissolved oxygen water quality limit of 5 mg/l. Therefore, the limit presented in the draft permit represents an achievable level for the mill. Because Champion has oxygen injection facilities in place to maintain the instream dissolved oxygen standard should worst case conditions arise, Champion complies with the conditions set forth by 40 CFR 125.3 (f). Effluent Dissolved Oxygen' Effluent dissolved oxygen is limited at no less than 6 mg/l based on the above discussion. Daily monitoring is required based on 15A NCAC 2B .0508 (d),Paper and Allied Products, Class IV facility. Page 3 FACTSHEET: CHAMPION - CANTON MILL,NC0000272 Total Suspended Solids The draft TSS limits are more stringent than the current federal effluent guidelines and are based on the 1993 proposed guidelines for the oxygen delignification process. Champion has accepted these proposed gudielines for TSS (monthly average) in the draft permit. The monthly average was calculated as follows: 1613 tons/day, (total production) * 2000lbs/ton * 3.89 lbs TSS/1000 lbs product = 12549 lbs/day the rato of The daily maximum was based on post-CMP operatio (8/95 to 1/96 o accounttaslight highest daily maximum:monthly average for that time period (taking intproduction increase). The proposed daily maximum values are also more stringent than the current federal effluent.guidelines. The production value used was as indicated on the permit application and is within 10% of reported production capacity values (post-August 1995). North Carolina does not have a numeric standard for TSS. The rules specifically regulate floating solids, The draft pertleable mit restricts solids.[ref. 15A NCAC 2B .0211(3)(c)]. solids. Settleable solids monitoring was removed from the permit due to consistently low values (well below North Carolina's long term average restriction of 5 ml/1). Additionally, the limit imposed in the permit is more stringent than current applicable federal guidelines. Finally, both benthic and IBI studies have indicated further improvement to the Pigeon River. Therefore, the negotiated .limit of 12,549 lbs/dap represents a reasonable . .. compromise for, this permit cycle. Daily monitoring is required based on 15A NCAC 2B .0508 (d) for Paper and Allied Products, Class IV facility. Total Residue/Total Dissolved Solids Monioring for these parameters is uired assess the plant• Daily monitoring has been required to o total correspond ndwith the requirement for TSS. Color Champion has applied for a variance from the instream color narrative criteria in North Carolina[15A NCAC 2B .0211(b)(3)(F)]. The permit and variance requires that compliance be based on 50 true color units as calculated by the color model. The color model provides Champion a predictive tool for color loads at the state line based on effluent values. Application of the color model allows the Division and Champion to assess the plant's contribution to the color levels at the state line through effluent measurements which are not compromised by introduction of other color sources. If the model predicts an exceedance, Champion can take immediate steps to investigate and correct potential problems. Thus the model allows for real time adjustments to be made in the operation of the mill to ensure protection of the 50 CU requirement at the state line. Recent data demonstrate that true color units at the state line Page 4 FAC,oAEET:'CHAMPION - CANTON ML—;"NC0000272 REVISED have been below 50 CU. Monthly average numbers are around 30 CU for the river at the state line since the reconfigured mill came on line. Champion will be required .to comply,with a calculated monthly average color 'load' of^132,341:Ibs/day I'at the"effluent and an annual average 'load' of ,124,923 lbs/day. The permit also requires that the predictive color model be recalibrated prior to the next permit renewal. The period of record and simulations to be used are provided as a supplement, to the hearing record. Instream color monitoring was recommended at the first downstream station (DNI), below Clyde (DN3), and at NCSR 1625 (DN4),-in addition to the existing color monitoring., -Color monitoring was included at these stations to better describe the color impacts within North Carolina. The station above Clyde (DN2) was not included due to its proximity to DN1 and DN3 and lack of other potential contributions (such as significant streams or discharges) within that area. Instream true and apparent color monitoring is -required (Part LA (2)). A schedule for continued evaluation of color minimization has been added to the modified variance and the revised permit (See Part III, Condition F). Essentially, the color minimization requires: 1) continued operation and evaluation of the BFRTM system installed at the Canton Mill to establish the operational integrity of the system and to ultimately determine that the system is appropriate :and• can.be counted on, 2) evaluation,of applicability of BFRTM technology to the other bleach lines at the mill (the hardwood line), 3) identifying and evaluating other in-process opportunities:to. _ .. reduce color discharges to the waste treatment system and development of an appropriate time frame to integrate the recommended changes, 4) evaluation of raw material storage areas and the feasibility of modifying the existing system to reduce color discharges to the WWTP, and 5) evaluate the applicability of end-of-pipe treatment technologies to achieve significant reductions in color discharges. -The intent of the schedule is to ensure that Champion reviews in-process modifications prior to end-of-pipe technologies. . A reopener clause 'vas also added in order to modify the color requirements based upon any breakthrough in color removal technologies. Ammonia Monitoring requirements are included in the permit to provide data conceming levels of ammonia discharged to the'pigeon River(which may affect instream dissolved oxygen). f Page 5 FACTSHEET::CHAMPION -CANTON MILL;NC0000272 Trichloronhenol/Pentachloronhenol The pennittee has certified that chlorophenolic biocides are not used at the facility- certification elitninates the requirement to'include effluent limits omonitorine two g will be eters based on 40 CFR 430.84 and 40 CFR 430.94. However, quarterly required. .Chloroform-.'-,.; Chloroform monitoring/limit has been removed from the permit. Based on an allowable level of.,*.8 mg/l (using the federal criteria of 470 µg/1 and existing data indicated no reasonable potential to exceed this average flow) _ allowable effluent level. Therefore, this parameter was dropped from the permit. .. Fecal— Co - Limitations for fecal coliform are based on the contribution of domestic wastewater from the Town of Canton and the requirements of 15A NCAC 2B .0211 (b) (3) (E)• Limitations for pH are based on 15A NCAC 2B .0211 (b) (3) (G). Temcerature The temperature limit and monitoring requirement is based on a.Section 316 (a)variance.:::: determination was accepted by the NC Environmental Management Commission October 11, 1984 and.approved by EPA August 6, 1985. Upon the next permit renewal Champion shall submit documentation regarding the continued need for a temperature variance along with temperature data and simulations specified in the supplement submitted with the hearing record. This will give Champion the opportunity to stabilize the mill (with regard to production and BFRTM implementation) and provide an ample data base for review. Periods of record for data review have been specified in the supplement so that no confusion will occur with the next permit renewal period. In making the recommendation to retain the current 316(a) variance, staff note that a balanced and indigenous population was determined in 1984. The 316(a) variance for Champion was also retained during the 1992 Triennial Review. Both benthic community studies and Index of Biological Integrity studies have shown improvement below her viewed entonxisting sincell the post Canton Modernization Program (CMP). Staff temperature data and although some improvement has occurred (most likely due to overall effluent flow decrease), Champion still cannot meet the North Carolina temperature requirement. Because the Champion plant has on and 7Q10 have not been reached during post limited data at full producti CMP, the temperature variance will be reviewed more thoroughly during the next permit renewal (See Part III, Condition L of the permit). Page 6 FAC `srJEETC CHAMPION-CANTON MI NC0000272 .REVISED Flow The flow limit is based on Champion's current flow values and post-CMP production plus 0.9 MGD for the Town of Canton's'wastewater (See more specific description in 'Description of Wastewater-Treatment Facility'). Due to potential inflow/infiltration problems with the Town of Canton,the Division granted Champion's request for 0.9 MGD increase in flow-with the provision that Champion continue to work with Canton to reduce 1/I problems (Part III, Special Condition J). Effluent Toxicity , r The toxicity testing requirement is placed on all major facilities and other facilities with complex wastestreams (Departmental memo 7/22/87). The toxicity limit is based on the instream waste concentration under 7Q10 conditions (54 cfs): For Champion,the instream waste concentration was determined by also accounting for the out-take of surface water from the facility (30.4 MGD, as per application). Therefore, the instream waste concentration was determined to be 87% under 7Q 10 conditions. Champion is required to perform the NC Whole Effluent Toxicity Test or an equivalent method(as approved by the Division)on a quarterly basis at 87%. Any equivalent method shall also be performed on a quarterly basis. Mercury Mercury was found in the Champion effluent at values above detection levels in 3 out of 4 samples taken.. Mercury is not an expected parameter..of.. _.. : concern in pulp and paper wastewater. Due to the potential for testing interference and the limited data set, 'monitoring shall be conducted 2/month on the effluent for one year. On December 1, 1997 an effluent mercury limit of 0.014 99/1 will be implemented unless Champion can meet the conditions specified in Part III, Special Condition M. In general, should Champion show effluent mercury levels less than 0.2 µg/I (the quantitation level) after nine months of sampling, the Division will eliminate the mercury limit and reduce monitoring to quarterly. Zinc/Hardness Reported values for zinc have exceeded the state action level. Monitoring requirements for zinc have been included in the draft permit(15A NCAC 2B .0211 (b) (4)). Numerical limits for zinc are not being included in the NPDES permit since the water quality standards do not contain a numeric criteria for zinc and the biomonitoring requirements in the NPDES permit are adequate to control toxicity due to the presence of zinc in the facility effluent. Zinc is a function of water hardness, so hardness monitoring is required in coordination with zinc monitoring. The monitoring frequency for zinc (2/month)is based on the Division's standard operating procedure for monitoring of toxicants for Class IV facilities. Champion is rated as a Class IV facility. r Page 7 CHAMPIOONNVICA TON MILL,NC0000272 FACTSHEET: Traces Cadmium, selenium, and silver-have been recommended for quarterly effluent monitoring. The limited data set indicated at least one value above allowable levels for each parameter. . Although tra a metals r concern and pulp and paper.wastewater, these are not typical p no limit is recommended at this time. Dioxin bee er discharge this Measurable since the levels o f dioxin iox n a e not AP There is currently a fish detected in the tconsumption advisory for the Pigeon River downstream of the discharge. Although the advisory was initially .in effect for consumption of all fish species, this advisory has due to continued been reduced to carp and catfish species only - improvements in the River. influent sludge,llandfill leachaterand efflue dioxin nt (See enzofuran isomersPart III,Condition H).arterly from the 7 The effluent 2,3, ,8 TCDD limit is based on 15A NCAC 2B .0208 (a) (2) (B). The average flow of the Pigeon River(325 cfs)was used in the calculation of the allowable effluent limit for dioxin at the NC instream water quality standard of 0.00014 ng/l [15A NCAC 2B .0206 (a) (3) (B)J. The limit is a daily maximum limit. Annual fish tissue analysis shall also be performed by the facility in accordance with the monitoring plan approved by the Division. Total Phos horusrrotal Nitrogen Total phosphorus and total nitrogento hoeingssess is contribution l of nutrients from Champion (A). Monthly monitoring is required to and the potential impact to Waterville Reservoir. Waterville Reservoir it is io be to monitored once annually (during oppositeY assist in characterizing nutrient impacts to the lake. Conductivity Conductivity monitoring is required based on 15A NCAC 2B .0508 (d), Paper and Allied Products (Water Quality Limited Facilities),for a Class IV facility. COD assess the potential impact of chemical oxygen demand from COD monitoring is required to the Champion wastewater effluent. Neither federal guidelines nor NC water quality standards require a limit for COD. Current draft EPA regulations and supporting documents state that COD may be related to effluent toxicity. As the permit contains a chronic toxicity limit and the plant has not documented any toxicity problems, no limit for COD has been proposed. Page 8 'FAC'.'SriEET: CHAMPION - CANTON M1L,=, 4C0000272 'REVISED AOX Monthly effluent monitoring for AOX has been required in the permit.. .;.; AOX,is an-overall''test"for"adsorbable organic"halides, which include =-,,, chlorinated"organics. Trends 'in concentration changes have been observed between AOX and specific-pollutants (dioxins, chlorinated organics) at - pulp and paper mills. Therefore, any decrease in AOX may also indicate a decrease in chlorinated organics. Limits for AOX are proposed .in the draft EPA Cl'uster'Rules. Monitoring has been added with this permit to better . characterize the effluent. A y 3: _ EFFECTIVE DATE OF PROPOSED EFFLUENT LIMITS LAND COMPLIANCE SCHEDULE IF APPLICABLE) The limits become effective on the date of permit issuance. 4. PROPOSED SPECIAL CONDITIONS WHICH WILL HAVE A SIGNIFICANT IMPACT ON THE DISCHARGE Toxicity Testing Requirement Color Monitoring Requirement Color Minimization Schedule Dioxin Limit and Monitoring - Waterville Reservoir Sampling Dissulved Oxygen Requirement 5. REQUESTED VARIANCES OR ALTERNATIVES TO REQUIRED STANDARDS The facility requested and received a 316 (a)variance granted by EPA 8/6/85. This determination demonstrated that the effluent limitations relating to the thermal component of the Champion discharge based on application of NC water quality standards were more stringent than necessary to assure protection and propagation of a balanced indigenous population of shellfish, fish, and wildlife in the Pigeon River. Therefore, the 316(a) determination was approved based on protection of the appropriate use classification of the Pigeon River. This permit continues the 316(a) variance and requires studies to be completed prior to the next permit cycle to enable re-evaluation of the variance. As discussed previously, Champion has applied for a variance from the instream color narrative criteria in North Carolina [15A NCAC 2B .0211(b)(3)(F)]. See Section 2 and the attached variance documents. 6. DISCUSSION OF PREVIOUS NPDES PERMIT CONDITIONS See attached EPA permit. Page 9 FACTSHEET: CHAMPION - CANTON MILL,NC0000272 REVISED 7 THE ADMINISTRATIVE RECORD The administrative record, including application, draft permit, fact sheet,public notice, comments received, and additional information is available by writing the Division of Environmental-Management,Water Quality Section, P. 0.Box 29535,Raleigh,North Carolina 27626-0535. The above documents are available for review and copying at the Archdale Building,9th Floor,Water Quality Section,Permits and Engineering Unit, 512 North Salisbury Street, Raleigh,North Carolina 27611 between the hours of 8:00 a.m. and 5:00 p.m.Monday through Friday. Copies will be provided at a charge of 10 cents per page• r g. STATE CONTACT Additional information concerning the permit application may be obtained at the above address during the hours stated in item No. 9 by contacting: Susan Wilson at(919)733- 5083, extension 555. 9, PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice- 5/6196 Public Hearing -6/6/96 Permit Scheduled to Issue- October 1996 10- PROCEDURES FOR THE FORMULATION OF FINAL DETERMINATIONS a. Comment The Division of Environmental Management proposes to issue an NPDES Permit to this deterrminations ar to the e tentative andent limitations are open t acomment from the publcial conditions ic. above. These Interested persons are invited to submit written comments on the permit application or on the Division of Environmental Management's proposed determinations to the following address: DIVISION OF ENVIRONMENTAL MANAGEMENT WATER QUALITY SECTION POST OFFICE BOX 29535 RALEIGH,NORTH CAROLINA 27626-0535 Y All comments received within thirty days following the date of public notice will be considered in the formulation of final determinations with regard to this application. b. Public Hearin Due to the public interest in the permit and the requirement of a public hearing for variance review, a public hearing has already been scheduled. The hearing will be held June 6, 1996. Page 10 FACTSHEET: CHAMPION - CANTON MILL, NC0000272 REVISED C. Appeal Hearings An applicant whose permit is denied, or is granted subject to conditions he deems unacceptable, shall have the right to a hearing before the Commission upon making written demand to the-Director within 30 days following issuance or denial of the permit. d. Issuance of the permit when no hearing is held Not applicable. r a Page 11 W RESPONSE TO COMMENTS e CHAMPION NC0000272 TEMPERATURE Comment: The temperature variance should be re-evaluated. Response: Staff has recommended that the 316(a)temperature variance granted by EPA August 6, 1985 remain in the permit. However,-upon the next permit renewal, Champion must submit documentation regarding the need for a temperature variance along with temperature data and simulations specified in the supplement submitted with the attached recommendations. This will give Champion the opportunity to stabilize the mill (with regard to production and BFR'M implementation) and provide an ample data base for review: Periods of record for data review have been specified in the supplement so that no confusion will occur with the next permit renewal period. . In making the recommendation to retain the current 316(a)variance, staff noted that a balanced and indigenous population was determined in 1984. Since that time, both . benthic and fish community structure studies have shown improvement below the Canton Mill. The 316(a) variance for Champion was also retained during the 1992 Triennial a Review and submitted to EPA. Because the Champion plant has limited data at full production and 7Q10 conditions have not been reached since completion of the Canton Modernization Program (CMP), the temperature variance will be reviewed more thoroughly during the next permit renewal. DISSOLVED OXYGEN AND BOD5 Comment: The BOD and DO provisions of the permit constitute a variance to the water quality standards for the Pigeon River, which is not authorized under the Clean Water Act. Response: Champion satisfies the requirements of 40 CFR 125.3 (f), therefore, the BOD5 and DO limits do not constitute a variance. Part (1) of 40 CFR 125.3(f) is satisfied because technology based treatment requirements are not sufficient to achieve the standards.. The limit for BOD5 was developed based upon a site specific evaluation of the treatment capabilities of the existing facility. This limit is less than the existing federal guidelines and any currently proposed modifications to the guidelines. Part (2), Champion has waived any variance request under these CWA subparts. Part (3), 02 injection is the preferred environmental and economic method to achieve the standard at this time. Champion has already chosen and installed OD/ECF manufacturing processes and is in the process of pilot studies for BFR on the pine line. These technologies have reduced the BOD5 and color load on the WWTP, thereby, resulting in improved efficiency of treatment. This was the chosen alternative during the previous permit cycle. Champion continues to investigate further technologies (such as BFR on the hardwood line). Further technologies should assist Champion in meeting a more stringent BOD5 limit in the future. A compliance schedule has been implemented in the revised permit to help promote further reductions in color to the plant (which in turn should reduce wasteloads). Comment: The permit limits on BOD5 discharges are inadequate to meet the water quality standard for dissolved oxygen in the river. Response: The Champion Canton Mill cannot comply with the predicted BOD5 level required to protect the instream dissolved oxygen water quality limit of 5 mg/l. Therefore, the limit presented in the draft permit represents an achievable level for the mill. However, Champion is required to maintain the instream dissolved oxygen standard through the use of oxygen injection stations. Because Champion has oxygen injection RESPONSE TO COMMENTS CHAMPION NC0000272 facilities in place to maintain the instream dissolved oxygen standard should worst case conditions arise, Champion complies with the conditions set forth by 40 CFR 125.3 (f). Champion has not had to use the instream oxygen injection facilities since the end of 1993. The revised permit requires that Champion record the date and duration of instream oxygen injection,when used. Because of the resilient nature of BOD5;BOD5 monitoring has been required at the state line. This is in addition to the extensive DO monitoring at multiple sampling points downstream. Comment: Sewage discharges have not been adequately addressed in the draft permit. Response: The contribution of domestic wastewater will be more specifically addressed in the permit and the fact sheet. The Town of Canton chlorinates untreated domestic wastewater prior to its combining with Champion influent. The Town does not have a combined sewer overflow system,but has had problems with inflow and infiltration (which has been addressed in the permit). Flows from the Town average 0.7 MGD. The Town does not have any significant industrial users and is not required to have a pretreatment permit. Secondary limits are not required in the Champion permit. Secondary limits only apply to municipal discharges. This discharge is not considered to be municipal. Even so,the Champion permit reflects a BOD5 limit of less than 30 mg/1. Because the pulp and paper waste stream is nitrogen deficient and NH40H is added to ensure the biological activity of the treatment system function properly, the Division sees no need for NH3-N limits. Champion has averaged below 1.5 mg/1 monthly average for the past year additional nutrient seed')for anion provides the Champion wastewater treatment facility. SOLIDS Comment: Suspended solids limits are inadequate to protect water quality standards. Response: North Carolina does not have a numeric standard for TSS. The rules specifically regulate floating solids, settleable solids, and sludge deposits [ref. 15A NCAC 2B .0211(3)(c)). The draft permit restricts floating solids. Settleable solids monitoring was removed from the permit due to consistently low values (well below North Carolina's long term average restriction of 5 m]/l). Additionally, the limit imposed in the permit is more stringent than current applicable federal guidelines. Finally,both in the p and IBI studies have indicated further improvement to the Pigeon River. PARAMETERS OF CONCERN Comment: The permit should contain limits on AOX, COD, Chloroform, and other specific pollutants as contained in the proposed cluster rule. Response: AOX has been recommended for monthly effluent monitoring in the revised permit. COD monitoring is contained in the permit. Chloroform monitoring/limit has been removed from the permit. Based on an allowable level of 2.8 mg/1(using the federal criteria of 470 µg/1 and average flow) existing data indicated no reasonable potential to exceed this allowable effluent level. Many of the other specific pollutants listed in the proposed 1993 Cluster Rules have been dropped from the proposed 1996 Cluster Rules. Since o have aa these bsis o implement theme npermit. not enforceable at Champion sta and North Carolina does n Comment: Chlorine limits should be included. RESPONSE TO COMMENTS CHAMPION NC0000272 Response: Champion has not shown toxicity attributable to total residual chlorine, so no chlorine limit is required. Comment: Metals and other parameters should be included. Response: Cadmium, selenium, and silver have been recommended for quarterly effluent monitoring. The limited data set indicated at least one value above allowable levels for each parameter. Although trace metals are possible in pulp and paper wastewater, these are not typical parameters of concern and staff do not recommend a limit at this time. Mercury was found in the Champion effluent at values above detection levels in 3 of 4 samples collected. One of the three samples taken was a split sample in which one value was below detection. Mercury is not an expected parameter of concern in pulp and paper wastewater. Due to the poiential for testing interference and*the limited data set, monitoring shall be conducted 2/month on the effluent for one year. On December 1, 1997 an effluent mercury limit of 0.014 µg/I will be implemented unless Champion can meet the conditions specified in the permit. Other parameters for which North Carolina has a water quality standard were reported below allowable levels and are not considered parameters of Eoncem. DIOXIN Comment: Dioxin and Furaif limits are inadequate. Response: The effluent 2,3,7,8 TCDD limit is based on 15A NCAC 2B .0208 (a) (2) (B) and the NC instream water quality standard of 0.00014 ng/l [15A NCAC 2B .0206 (a) (3) (B)]. The limit is a daily maximum limit. The dioxin and dibenzofuran isomers have been recommended for quarterly monitoring (the same parameters in the previous EPA permit and the most toxic forms) with the revised permit. The only limited parameter will be 2,3,7,8 tetrachloro-dibenzo-p-dioxin. This is the most toxic isomer and the parameter for which there is a North Carolina water quality standard. I Comment: The dioxin quantitation limit specified in the permit is inadequate. Response: The 10 pg/1 quantitation limit is the minimum for water samples, based on EPA-approved method. Below this level, data accuracy and precision is compromised. Comment: Sediment sampling should be performed in Waterville Reservoir. Response: Studies have been performed (CP&L) which correlate reduction of dioxin in fish tissue with reduction in sediment. Both the state of Tennessee and North Carolina have shown reduction of dioxin in fish tissue. The permit requires annual fish tissue analysis for dioxin. Through CP&L's FERC re-licensing process, options were studied for removal or cover of the sediment, with the recommendation that artificial capping of sediments be required if dioxin concentrations do no continue to decrease. Staff concurs with this assessment, due to decreasing concentrations of dioxin in the biota and the potential problems associated with disturbing these sediments. MISCELLANEOUS Comment: Landfill leachate should be addressed by the permit. Response: Leachate is directed to the Town of Canton, which discharges to the mill. Champion is required by the permit to monitor dioxin/furan isomers from the leachate. Champion has begun flow monitoring of the leachate and flow has been variable (dependent on storm incidence), with averages less than .05 MGD. � '; Canton Mill * 7 Box C-10 Canton,North Carolina 28716 �III o d � od � V Champion Champion International Corporation f1f�T I 5 P* WATER CISALITY SE10'IN ASHEVILL[ kr "'%NAI off October 10, 1996 Mr. Keith Haynes Environmental Specialist Division of Environmental Management Water Quality Section 59 Woodfin Place Asheville, NC 28802 RE: Stormwater Release at Champion's Canton Mill on October 8, 1996 Dear Mr. Haynes. Champion Intemational is providing written notice of a storrnwater release from a Chip Blower System sump to the Pigeon River. The release on October 8 was the result of water being lost from a hole in the discharge line. No effect to the Pigeon River was observed. The information concerning the release is attached. If you have any questions, please call Noureen Shaikh at (704) 646-6814 or Jim Giauque at (704) 646-2028. Sincerely, Noureen Shaikh Jim Giauque Assoc. Environmental Advanced Proce s Engineer Engineer Attachment file:c:lkhayns4.doc NOTIFICATION REPORT CHAMPION INTERNATIONAL CORPORATION MAIN STREET PO BOX C-10 CANTON, NC 28716 HAYWOOD COUNTY 1. Name of Material: Stormwater from Sump at Chip Unloading System 2. Caller's name and position: Jim Giauque Advanced'Environmental Engineer 3. Media into which release occurred(air, water or land): Ground, Pigeon River 4. Quantity released: Approximately 1,000-2,000Gallons 5. Date, start and stop of release: Start date and time: Approximately 1:30 p.m. October 8, 1996 Stop date and time: Approximately 2:00 p.m. October 8, 1996 6. Causes and source of release: A sump pump was activated to empty stormwater that had collected in the basement of the Lower Truck Unloading System. Water was inadvertently discharged from a hole in the pump discharge line onto the ground. Approximately 1,000-2,000 gallons of the water overflowed a ditch line and escaped through a storm drain (Outfall #4) and flume to the Pigeon River. 7. Action taken to respond to release and status of actions: The Pump was shut off to prevent further discharge. Notification Report for Spill/ReleaseNent Page 2 8. Notification made: NCDEHNR -Asheville Date: 10/09/96 Time: 08:50 a.m. Contact: Keith Haynes (voice mail) Follow-up: NCDEHNR -Asheville Date: 10/10/96 Time: 11:40 a.m. Contact: Keith Haynes 9. Name and telephone number of person to contact for further information: Jim Giauque (704) 646-2028 10. Action taken for clean-up: Wood chips in the ditchline and a culvert have been removed to facilitate flow of water. Sump discharge line will be properly repaired. file:c:Xnotify07.doc Division of Water Quality v Biological Assessment Group G October 4, 1996 MEMORANDUM To: Ken Eagleson CS Through: Jimmie Overton " Trish MacPherson From: Mark Hale Subject Revised Study Plan for Fish Tissue Mercury Assessment- Pigeon River Attached is a revised DWQ study plan for the investigation of mercury levels in fish from Pigeon River rescheduled for October 7-9, 1996. I have altered some text in the background discussion of this plan regarding results that Champion has submitted. Due to a transcription error, I stated that Champion had collected one redbreast sample below the discharge which contained mercury exceeding the EPA screening value. After further review of Champion's results, it is evident that no fish samples contained mercury exceeding FDA or EPA criteria in the Champion study. Please replace the original DWQ study plan dated September 26, 1996 with the attached document. cc: Dr. Luanne Williams - Envir. Epidemiology Section Roy Davis-ARO Bryn Tracy-ESB Susan Wilson-NPDES Group Revised Division of Water Quality Study Plan Assessment of Mercury in Pigeon River Fish Tissue October 1996 f Background Information compiled by the Clean Water Fund of North Carolina in July of this year from Champion International's NPDES permit application indicated the presence of mercury in the Canton Mill effluent. The Clean Water Fund subsequently requested that the DWQ investigate the likelihood of mercury contamination of Pigeon River fish. The ARO responded by examining historical sets of mercury results for Pigeon River fish provided by TVA, the Tennessee Div. of Water Pollution Control, and North Carolina(CP&L and DWQ). The most recent mercury data dates from 1995 and was submitted by TVA and Tennessee Div. of Water Pollution Control. Data from North Carolina sources were older(from 1989s) and sketchy at best. Information from North Carolina and Tennessee indicated that mercury concentrations in fish (fillet tissue) collected from the Pigeon were comparable to "background"levels found in fish throughout the state. Results for fillet tissue showed no total mercury concentrations above the FDA action level of 1.0 ppm. (Although health concerns are focused on methylmercury, results and criteria are generally expressed as total mercury. Most mercury(90-95%) in fish and shellfish is in the form of methylmercury, but due to the high cost of the analysis the EPA recommends that total mercury be analyzed and the conservative assumption be made that all mercury present in fish is methylmercury.) Further fish sampling was conducted by Champion in August 1996 at two sites near the mill e discharge as part of their dioxin monitoring program. Mercury analyses were conducted on fish I from two stations,NC-215 above the mill discharge, and near Clyde below the discharge. t Mercury results above and below the Champion discharge were lower than the FDA (NC) and 1 EPA action levels of 1.0 ppm and 0.60 ppm respectively. Champion results did not suggest that the mill discharge is a significant source of mercury pollution with respect to fish tissue in the Pigeon River. 4 Concerns over the possibility of mercury contamination in Pigeon River fish continue to arise from DWQ staff, State Health Department officials, and others due to the incomplete nature of North Carolina fish tissue data and the lack of piscivorous species analyses in the recent Champion study. Releases of mercury have also been detected in the Waynesville WWTP effluent as recently as February 1996. The DWQ Environmental Sciences Branch proposes the following study as a means to more closely examine mercury levels associated with fish in the North Carolina section of the Pigeon River from the Champion Mill to the Walters Lake. Sample Collection Fish samples will be collected from 5 stations stretching along the mainstem Pigeon River from just above the Champion mill discharge to the Walters Lake (see map). 1) NC-215 Bridge above the Champion discharge 2) SR 1513 above Clyde at river mile 59.0 3) Old Rt. 209 at river mile 52.3 4) SR 1364 atFerguson Bridge,river mile 48.2 5) Walters Lake i Page 2 Fish will be collected by DWQ staff at the above stations during October 7-9, 1996 via backpack or boat electrofishing, depending on flow and access restrictions. Since mercury has been found to bioaccumulate to a higher degree in piscivorous fish species, these will be targeted for collection at all stations along the Pigeon. Piscivores most likely to be encountered include largemouth bass, smallmouth bass, and rock bass. Additional insectivores, omnivores, and bottom feeding species will be collected at each site whenever possible. Individuals of each species collected at each site will number at least 4 but no more than 10 and will include various size classes when possible. Collected fish will be sorted immediately after collection, placed by species in plastic bags, and tagged with date, location, time, and collector information. Samples will be placed on dry ice for transport back to the ESB laboratory in Raleigh. I Sample Processing and Analysis i All samples will be processed at the ESB laboratory. Fish will be weighed to the nearest gram and lengthed to the nearest centimeter(total length)before processing. Analysis of mercury will be conducted using the fillet or edible portion. All fillets except for catfish (Ictalurids) will be processed with skin on. Processed fillets will be sent to the laboratory as individuals or may be combined to form composite samples. Composites will contain no more than 10 fillets of the same species and will be of similar size. Processed fish samples will be hand delivered to the DWQ Chemistry Laboratory for mercury analysis. Results will be expressed as total mercury. QA/QC To assess total variability, duplicates will be prepared from at least 10% of fish samples. Duplicates will be prepared from the same original fillet or composite homogenate. At least 10% of fillet samples will be frozen and archived at the DWQ laboratory for a period of 6 months after the survey. Fish Tissue Sampling Stations for Pigeon River Mercury Assessment NCDWQ October 1996 waxem Dam ♦� Walters Lake fatalmd�ee Oak ( �1 Gad (42-) Her Hepco Bridge Ferguson Bridge (48.2) FLOW yay Old Rt. 209 (52.3) C ee Above Clyde (59.0) IBM DL*f cwdvn HC (�I waymmk R-djnd Cy®'NC lN�1 1 Hwy. 215 Bridge -State of North Cart a - Department of Environment, Health and Natural Resources Division of Water Quality , James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary E) G A. Preston Howard, Jr., P.E., Director C •October 1, 1996 Ms. Beverly H. Banister, Acting Chief Water Permits and Enforcement Branch,Water Management Division �, EPA Region IV 4 as 0 gib, O 100 Alabama Street, S.W. Atlanta, Georgia 30303 CFO/OryysFOr A(O,rFJN Subject: NPDES Permit Champion International Corporation Canton Mill WWTP NPDES Permit No. NC0000272 Haywood County Dear Ms. Banister: Staff of the North Carolina Water Quality Section met with EPA Region IV staff on August 28, 1996 regarding the Champion International Corporation draft permit and color variance. This letter, along with the permit, fact sh-zet, and modified variance document, is offered in response to your comments submitted July 3, 1996. The following summarizes the Division's response to EPA Region IV's comments: • BOD5. The Champion Canton Mill cannot comply with the predicted BODS level necessary to protect the instream dissolved oxygen water quality limit of 5 mg/1, without instream treatment under low-flow conditions. Therefore, the limit presented in the draft permit represents a site specific BAT for the mill. The monthly average BOD5 limit (35981bs/day) is based on the 95th percentile value analyzed by the Log-Pearson Skew method on data from 1/91 to 12/95. The 1/91 to 12/95 data were-used as a result of the incomplete data base of post-Canton Modernization Program (CMP) values at optimal production available and the need to simulate the projected mill variability under post-CMP conditions including cold mill shut downs and start ups. The 95th percentile represents two standard deviations around the mean of daily values. In this way, day-to-day variability is measured and used to set monthly average limits. Although the Log Pearson III method is not typically applied to monthly averages, in this case the 60 data values were a skewed distribution. The daily maximum value has remained the same as the previous permit (12458 lbs/day). EPA stated in their letter that the proposed BOD5 limit does not reflect actual conditions at the mill. The values listed in their letter were taken from the permit application, which was submitted in March 1994. Current data, which was used for the draft permit (up to December 1995) indicates that the values listed in EPA's letter are beyond BAT at this facility. Additionally, the data EPA presented does not include any post-CMP data or data at predicted optimal production levels. P.O. Box 29535, Raleigh, North Carolina 27626.0535 Telephone 919-733-5083 FAX 919-733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10%post-consumer paper EPA Region IN, Response Champion-Canton Mill WWTP NPDES No. NC0000272 Pase 2 Upon the next permit renewal,post-CMP dataed , from 8/95 to the renewal application date will be used for the data analysis (and anal the postSCMP monthly average dailinfluent values and ylmaximum ratio ant removal will be co parted during the next permmt renewal, and used to calculate a new daily maximum. Based on limited post-CMP and optimal production data, aesult of the fact that Chmion is in nd as a)r the above procedure was used for this a demonstration process of Bleach Filtrate Recycle ( 2ermit cycle. Several protect themodeling dissolved oxyses were gen standard uerformed to ndertct the allowable 7Q10 conditions wiitthDouallocation ithe use of supplemental proteP ct injection. The allowable allocation under this scenario was less than 12001bs/day. Therefore, en injection facilities in in order to ensure continued protection of the dissolved oxygen standard under low flows,Champion must continue to use the oxygen injection system. Because Champion has oxygen j instream dissolved oxygen standard should worst case pl conditions arise, the ace to maintain the applicability of 40 CFR 125.3 (f) continues. No change is proposed for the BODE limit. • TSS. As stated in the Fact Sheet submitted to EPA,North Carolina does not have a numeric standard settfor TSS. The rules specifically draft permit trestric sng floating solids. Settleable le solids, and solidsemon o[ring 15A NCAC 2B .0211(3)(c)]; na term a er removed a a restriction n the permit due to the limit low imposed(well inthe permit isCarolina's m oei str nge t than structure studies have current applicable federal guidelines.the Pigeon Rrverb Thhrefore, the negotiated trait of 12,549 Ibs/day in.iicatz., furthcr imp Riv cycle. represents a reasonable compromise for this permit industry. The daily maximum value Champion agreed to accept the 1993 proposed Cluster Rules for the monthly average value, which is more stringent than the current regulations for the pulp and paper average values. The production was based on the maximum ratio of daily maximum values to monthly a value optimal's within ntapproximately pn roxim teAgain%the va of lues s EortedPA used tfor con o ptarison purposes were taken 4 application and do not reflect current data that was used to derive the TSS limit. from the March 199 No change is proposed for the TSS limit. -s from the a were above • Mercury. North Carolina agrees that the reported value effluent at values aboted vte d tect on levels n 3 of allowable levels. Mercury was found in the Champ 4 samples collected. Mercury is not an expected parameter of concern in pulp and paper wastewater. Due to the potential for testing interference and the limited data set, monitoring shall be conducted 2/month on the effluent for one year. On December 1, 1997 an effluent mercury limit of 0.014 µg/1 the uantitation will be implemented unless Champion can meet the conditions specified in Part III, Special Condition M. In general, should Champion show effluent mercury levels less than the elirrmercury µ� ( 9 level) vmonitoringafter t i e months of s�Champion has alsDotperformedvision la fish t slinasue study formlercury to further characterize mercury impacts. Preliminary results from the fish tissue analysis show levels similar to fish tissue analyses from other water bodies in North Carolina. EPA Region IV Respc- -- Champion-Canton NEI_ WTP _ NPDES No. NC0000272 Page 3 • Temperature. Champion has requested continuance of the current 316(a) variance granted by EPA August 1985. Again, the data reviewed by EPA included only those values from 1990 to 1994. Post- CMP and optimal production have only been reached after April 1994 (with optimal production reached in August 1995). A balanced and indigenous population was documented in 1984. The 316(a) variance for Champion was also retained during the 1992 Triennial Review and submitted to EPA. Both benthic community studies and fishery studies have shown improvement below the Canton Mill since the post-CMP. Staff reviewed existing temperature data and, although some improvement has occurred (most likely due to overall effluent flow decrease), Champion still cannot meet the North Carolina temperature requirement. Because the Champion plant has limited data at full production and 7Q10 conditions have not been reached during post-CMP, the temperature variance will be reviewed more thoroughly during the next permit renewal with pre-established periods of record and simulations. This condition has been specified more fully in the permit (see Part III, Condition L) and supplement to the hearing record. S • Instream Monitoring. North Carolina agrees with EPA in the addition of color monitoring within North Carolina. Instream color monitoring shall be conducted 2/week at downstream locations DNI, DN3, and DN4. Color monitoring was included at these stations to better indicate color impacts within North Carolina. The station above Clyde (DN2) was not included due to its proximity to DNI and DN3 and lack of other contributions (such as significant streams or discharges) within that area. Instream true and apparent color monitoring is required (Part I.A (2)). • Color. The color equation has been corrected as noted. The variance will be reviewed by the NPDES Committee in October prior to issuance of the permit. If the variance is approved by the committee,the Division will proceed to issue the permit after approval from the Director. The permit will not become effective until at least 30 days after issuance. Due to the complexities of the permit, the Division does not believe that separation of the permit and the color variance is beneficial. Champion is required to comply with a calculated monthly average color'load' of 132,341 lbs/day at the effluent [decreased from 198,813 lbs/day] and an annual average 'load' of 124,923 Ibs/day [decreased from 132,341 lbs/day] with the modified variance. • Implementation of a Schedule for Continued Color Improvements. Staff have worked with Champion to establish a timeline for continued evaluation of color reduction at the mill. This is outlined in Part III, Special Condition F of the permit. The color variance is presented in more detail in the attached memo from Forrest Westall. • Statistics and Periods of Record. The staff stands behind use of the Log Pearson data analysis. The data are not normally distributed, therefore, this statistical analysis is appropriate. Due to the limited data base for post-CMP and optimal production values, the period of record used for analysis of color, BODS, and TSS is appropriate. During the next permit renewal, a more consistent period of record can be established for estimations of achievable limits. r EPA Reg*ion 1V Response Champion-Canton Mill W`YTP NPDES No. NC0000272 Page 4 sfies EPA's concerns ardin�g the The WatLrieQuality ion NPDES permit and acolots letter r variance.ttWe look forward to ourgresponse to development of pion e contact David Goodrich, these comments. f have htionsoncernthi3etenion 517 Supervisor, Group, telephone 73 s Sincerely, /f v,Steve W.Tedder, Chief Water Quality Section cc: Central Files Mike McGhee,EPA Region IV WestallwAshevill2,&O°na Office Greg Thorpe,Planntn ranch,Water Quality Section g Permits and Engineering Unit Permit No. NC0000272 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES DIVISION.OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Champion International Corporation is hereby authorized to discharge wastewater from a facility located at Champion Canton Mill Wastewater Treatment Plant off Highway 215 Canton Haywood County to receiving waters designated as the Pigeon River in the French Broad River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III, and IV hereof. The permit shall become effective This permit and the authorization to discharge shall expire at midnight on November 30, 2001. Signed this day A. Preston Howard, Jr., P.E., Director Division of Water Quality By Authority of the Environmental Mangement Commission nzx-, Air e 1Jc my ir! >;e t_D. rb-5cl Bclt Et�PiArC ��t,r ,I.'wt�oer. Permit No. NC0000272 SUPPLEMENT TO PERMIT COVER SHEET Champion International Corporation Canton Mill Wastewater Treatment Plant is hereby authorized to: wastewa i. Continue to operate an existing wastewater treatment facility for the Le tment Town Canton's and stormwater associated with the pulp and pap er mill;chlorinated domestic wastewater, and Champion's landfill rol (CO2 injection or H2S leachate consisting of aO4 T chamber, bar screens, lift pumps, polymer addition, p backup) belt presses, eeffllanfiflonutrient measurement, cascade aeration tion basins, h(with oxygen injection), III ed in Part Condition located the Champion oxygenand 1 1 ay 215Canton,HaywoodCounty d Cantnill WastewaterTreatm Treatment Plant, of Hihw 2. Discharge from said treatment works at the location specified on the attached map into the Pigeon River which is a Class C waters in the French Broad River Basin. /jam\��-CO. l���l P t (iI �/ �• u/ `/� �r � �- ' '�� \X\ .,�1, % ; / �'. ... �• i. il, Lr•,, � � °,�� — �� •=ram J -A. / .. �• jY 1 rfN°• anton\Chi• —G L�.ee. • U �./'•%i--,ram � ��e\ rt n �'C IA L�.', O. ',j'5 tlk "�� / / .�_-�ii/ `� �•����, � L �/� 'R�h ,._•,fay �/�\ I` � /� b /"'i O� Jv _ '_:f �Caa;n,�. ��.r fY l ,jl,:�J` - �fl`. "\v �- .,r •�� 'e w Ischarge Po. int Tf \I _ '�� Fc...,._ •C•\' -%\ 4!`f•.] /�. .:•Y /. TBM_5 38 •� ✓^�. ROAD CLASSIFICATION PRIMARYHIGHWAY WGHT-DUTY ROAD,HMO OR . SCALE 1 :24000 HARD SURFACE IMPROVED SURFACE 0 MALE + ; SECONDARY HIGHWAY XMDSURFACE � UNIMPROVED ROAD = 0 7000 FEET m� . Let: 35° " Long: 82°50'42" ° KtIOMFTER 32'08 411 Map # E7SE Sub-basin 04-03-05 CONTOUR INTERVAL 5 FEET Stream Class C Discharge Class Indust rial/ Domestic QUAD LOCATION Champion International Receiving Stream Pigeon Rver Canton Mill WWTP Ow: 29.9 Permit exp. 11/30/01 NC0000272 Haywood County A. (1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Pertnit No. NC0000272 During the period beginning 01,the be If effective e and monitored by the per lasting igee ntil expiration of fret bclowlhe permit, the Pennittee is authorized to discharge from outfnll(s) serial number 001. Such discharges Monitoring Requirements DI s Q InK99 Ll11ft1111-M. MS2kVicement Sample .t ample Etlluent Characteristics noire (5pecifyl Location Lb Daily Max. Frequency T—Xfe Mon Avg. Daily Max. Mon• Avg. Continuous Recording I or E 29.9 MGD Daily Composite E,1 Flow 3598.0 12458.0 Weekly Composite E 60D5 Daily Composite E,l CCD 12549.0 49660.0 Daily Composite E TSS W E 400 /100 ml Weekly Grab NH3-N 200 /100 ml Daily Grab E Fecal Coli(orm Monthly Composite E Dissolved oxygen 2 Monthly Composite E Total Nitrogen (NO2 + NO3 +TKN) Daily Grab E Total Phosphorus Quarterly Composite E Temperature 3 Daily Composite E Chronic Toxicity Daily^ Composite E Total Residue 2/Month Composite E Total Dissolved Solids 2/Month Grab E Hardness 01 4 µ g/ Mercury s I S:mtple locations: C-Effluent, 1 - Influent. Instream sampling is specified in Part 1, A (2). 2 The daily average dissolved oxygen effluent concentration shall not be less than 6.0 mg/l. See Part I,Section A(2)and Part III,Condition 1. -1 The monthly average insiream temperature measured at a point 0.4 miles downstream of the discharge location shall not exceed 3 measu.00Cred during the months of July,August,and mperature September and se 111 not exceed temperature grin ethe monthsmof October through June oniito ng location by more than I13.9 C. Sely averagee Part III,nstrearn Condition L asured at this location shall not exceed the uwnthly average 'I Chronic Toxicity Testing at 87 %; March,June,September, and December; See Part III,Condition G. The mercury limit shall he implemented December 1,, 1997 unless those conditions specified in Part Ills Condition M can be met. Values detected at less than 0.2 99/1 will be considered zero for purposes of compliance. The effluent pF1 shall not be less than 6.0 standard units nor greater than 9.0 standard units. ting solids or visible foam in other than trace amounts. There shall be no discharge of floa r A. (I). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL (Continued) Permit No. NC0000272 During the Period beginning on the effective date of the permit and lasting until expiration of the permit, the Permittee is authorized to discharge from outfall(s) serial number 001. Such discharges shall be limited and monitored by the pemii(tee as specified below: Eftlu�er t -Characteristics Discharge Limitations Monitoring —Requirement Mon. Av�o. Deily Max. Mon. Units �S Da—fly Measurement Sa—m� tSam—I9 Pentao lorophe —�& Daily Max. Frequency Pentachlorophenol Ing— Location 'Line Quarterly Composite E rlrly Cadmium Quarte Composite E Selenium Composite E Silver Quarterly Composite E AOX Quarterly Composite E Quarterly Composite E 2,3,7,8 Tetrachloro-dibenzo-p- Monthly Composite E H)dioxin (See Part III, Condition 0.1 P9/1 Quarterly Composite E Color (See Part III, Condition E) Conductivity Daily Composite E.1 Ikl Daily Grab E Daily Grab E NF_ > No. NC0000272 Part I A.(2). INSTREAM NIONITORING REQUIREMENTS Frequency Stream Mile Location Description Parameter Designation Marker DIY Pigeon River upstream UP — 64.5 of the D.O. TDepernture Daily waste treatment plant outfall BOOS 1/Week (prior to mixing with the Conductivity Daily discharge) Color* 21Week Flow * Daily Fecal coliform 1/Week Daily DN 1 62.9 Pigeon River at Fiberville Bridge TDemOperature Daily Conductivity Daily Fecal Coliforrn 1/Week Color * 2/Week Dail DN2 57.7, Pigeon River Above Clyde TemperatureD. Daily 55.5 Pigeon River Below Clyde Tempeature 1/Week DN3 D.O. 1/Week Color * 2/Week Temperature 1/Week DN4 53.5 Pigeon River at NCSR 1625 D O I/Week bridge Color * 2/Week Tempeature 1/Week DN5 42.6 Pigeon River at Hepco D.O. O I/Week Color* 2iWeek Flow * Dail Waterville Reservoir (See Part III,Condition Annually IQ 26.0 Pigeon River prior to mixing Color DN6 with Big Creek _ �6•0 Mouth of Big Creek prior to Color* 2/Week mixing with the Pigeon River l/Week DN7 24.7 Pigeon River at Browns Bridge TDemOpeature I/Week (—NC/IN State Line) BOOS I/Week Color * 21Week All instream samples shall be grab samples. respectively. Both true and apparent color shall be monitored using * m samples collected for these streams shall e Color(Additional,See Part III,Condition E) All instrea representative of the Pigeon River and Big Creek,Samples Y• the methods h specified one generator o Condition sin operation anld releasing wate be collected at r to the Pigeon River.. Flow onlyd DN7 during is necessary, as specified above,for the True Color calculation stipulated in Part III,Condition E. Dissolved Oxygen. The average daily dissolved oxygen concentration measured at River Mile 62.9 (DN1),57.7 (DN2),and 55.5 (DN3) shall not be less than S.0 Part and the instantaneous nstan I)eous minimum dissolved oxygen concentration shall not be less than 4.0 mg/I E. REQUIREMENTS FOR COLOR ANALYSIS AND COMPLIANCE 1) Compliance shall be based on 50 true-color units at the I-40 bridge (DN7) as a monthly average [measured by the method specified below]. Should the instream 50 true color units (monthly average) be exceeded at DN7, Champion shall provide the Division of Water Quality a summary of the monthly calculated true color units, based on the model, as well as a summary of the measured instream values specified . in Part I. A.(2). If Champion can demonstrate to the satisfaction of the Director that the exceedance was not caused-by the Champion discharge, but a result of other contributions, the' exceedance will not be considered a permit violation. If no demonstration can be made to the satisfaction of the Director, then the exceedance shall be considered a permit violation. 2) Color shall be predicted through a calculation 'of3instream true color s levels at the North Carolina/Tennessee state line by the following equation: SLc = TP /8.34) + ((HEf_ WTPf x D HEfx 10 (-0.224 x LOG (HEf) +0.781) Where: WTPc = Monthly average Waste Treatment Plant discharge color. Calculated as the average of all daily loading values (pounds of true color per day) for a calendar month. WTPf = Monthly average Waste Treatment Plant discharge flow (mgd). HEf = Monthly average HEPCO, North Carolina flow (mgd) - daily flow values less than 81.4 mgd shall be entered as 81.4 mgd. - SLc = Monthly average Instream true color at North Carolina/Tennessee border (state line). Dc = Color concentration of all dilution streams (13 C.U.). The SLc shall be calculated for each calendar month. S f runits of thi eaeh month shall pemak-. 3) The average daily discharge of true color for each calendar month shall not exceed 132,341 pounds per day. The average annual effluent true color loading shall not exceed 124,923 pounds per day. For the purpose of this permit only, "pounds of true color' is calculated by the following equation: Effluent Flow (mgd) x Effluent True Color Level (Platinum Cobalt Units) x 8.34. 4) The method of analyses used to measure true color for this calculation shall be the procedure referenced in FR 39 430.11(b) (May 29, 5) All samples collected for color analysis shall be measured and reported as true color and apparent color using the colo procedure referenced in FR 39 430.11 (b) (May 29, 1974) -true and apparentr. 6) Prior to the next permit renewal, the color model specified u 1) above, shall be recal ment using sthe the hearing andd ofdin theandscolorations specified in the supple variance document. F. SCHEDULE FOR CONTINUED COLOR MINIMIZATION Champion shall continue to study, evaluate, and pursue color removal to accordance end shall following findings schedulto the Division of Water Quality Date Activitv Continuing Commercial demonstration of bleach filtrate recycling (BFRTM) March 1, 1998 In conjunction with the Triennial Review of NC Water Quality Standards: 1) Submit a status report on the technical, economic, and operational feasibility of BFRTM technology. e color reduction 2) Evaluate and report on end-of-pip technologies. on minimization of 3) Evaluate and e report ; and from raw material rstorage areas. manufacturing procss December 1, 1998 Based on results of one usionsh of the stat shreport, Champion e demonstration will decide and report on the decision to operate BFRTM technology as a fully commercial process on the p' December 1, 2000 Champion will evaluate color reduction strategies for further optimization of BFRT`t technology and report on the feasibility of implementation on the hardwood line. March 1, 2001 Champion will evaluate and report on end-the T reduction technologies in conjunction with the Triennial Review of NC Water Quality Standards. June 1, 2001 Champion will onbthe comparative evaDluation ofthetabove Water Quality, collective efforts as part of the variance review process (Triennial Review) and the NPDES renewal process- G. CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The permittee is required to perform the toxicity test as specified below or an equivalent toxicity test as approved by the Division. The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised November 1995, or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 87% (defined as treatment two in the procedure document). The permit holder shall perform uarterly monitoring using this procedure to establish compliance with the permit condition. The tests will be performed during the months of March. June.September, and December. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DWQ Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Water Quality 4401 Reedy Creek Road Raleigh, North Carolina 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity(AT) test form indicating the facility name,permit number, pipe number, county, and the month/year of the report with the notation of"No Flow"in the comment area of the form. The report shall be submitted to the Environmental Sciences Branch at the address cited above. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing,this monthly test requirement will revert to quarterly in the months specified above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream,this permit may be re-opened and modified to include alternate monitoring requirements or limits. [Is as ed in the cited document, such as lure to ve test minimum mum ciontrol organism e survivalltiminimumc nit of organism eprodu tion, and appropriate environmental controls, shall constitute an invalid test and will require leted no later than the last day of the month immediate follow-up testing to be comp following the month of the initial monitoring. H. DIOXIN MONITORING nal For permit compliance purposes,the point of compliance shall be demist limit shall ned as the be effluent before discharge. Compliance with the daily maximum pe demonstrated by determining the TCDD concentration at the final discharge point. olume shall be collected to perform the analysis. The Lora sample Adequate sample v ed in accordance with Part II, Sectiopn D Monitoring volume shall be collected and presery and Records. The sample shall be analyzed in accordance with the a ro riate method s of Pol analysis chlorinated Dibenzo c araal tdio z ns and Pol chlorinLi ated Dibenzofur, Assurance for la s b 1 HA h vsis Resolution Gas Chromato�ra h [Hi gh Resolution Mass PP ctromey EPA,A1 single 997 (EPA Method 8290), or another equivalent analytical protocol approved b DWQ• sample may be analyzed to determine compliance with the daily maximum effluent (dtuplicate anaysiatiVIl the anal psis of either piay t collected below to the detectiole the n limit,theist quantity,for the purposes of compliance evaluation, is considered to be zero. If both splits are he positive, its limitation.ylf the measurement averagedses shall be beto low detection etermine compliance the with quantity for the purposes of compliance evaluation is considered to be zero. The detection considered aluation is pic alit using tper 1 err The d oxin isomer to b otms e limited at the effluentby th se 10 permit is 2,3,7,8 TCDD. The chlorodibenzo dioxins and furans to be monitored are: DIOXIN DIBENZOFURAN Isomer Isomer 2,3,7,8 TCDF 2,3,7,8 TCDD 1,2,3,7,8 PeCDF 1,293,7,8 PeCDD 2,3,4,7,8 PeCDF 1,2,3,4,7,8 HxCDD 1,2,3,4,7,8 HxCDF 1,2,3,7,8,9 HxCDD 1,2,3,7,8,9 HxCDF 1,2,3,6,7,8 HxCDF 1,2,3,6,7,8 HxCDD 2,3,4,6,7,8 HxCDF 1,2,3,4,6,7,8 HpCDD 1,2,3,4,6,7,8 HpCDF 1,2,3,4,7,8,9 HPCDF Fish tissue analysis will be performed in accordance with the Division f Water a ering plan is approved monitoring plan, which shall be reviewed al necessary. an enforceable part of this permit. All dioxin data collected as pals of this monitoring requirement will be reported as required in the plan,no later than 180 days after sampling. The permittee shall perform the following analyses for the above listed isomers: 1. ent facility Quarterly COMPOSITE Influent to wastewater treatm 2. Sludge Quarterly COMPOSITE 3. Landfill leachate Quarterly COMPOSITE 4. Effluent Quarterly COMPOSITE I. DISSOLVED OXYGEN REQUIREMENT The permittee shall maintain an average daily dissolved oxygen concentration of not less than 5.0 mg/I with a minimum instantaneous value of not less than 4.0 mg/l at River Miles 62.9 (DNI), 57.7 (DN2), and 55.5 (DN3). The permittee shall operate oxygen injection facilities at the outfall structure, at 0.9 miles downstream of the discharge, and at 2.1 miles downstream of the discharge, as necessary, to comply with this requirement. These facilities shall be operated in a manner which will maintain the water quality standard for dissolved oxygen in the Pigeon River downstream of the discharge. Champion shall report the date and duration of oxygen injection use as a supplement to the monthly Discharge Monitoring Report (DMR) forms. J. INFLOW/INFILTRATION AT THE TOWN OF CANTON The permittee shall make continued efforts to promote reduction of inflow/infiltration to the Town of Canton's wastewater collection system. K. WATERVILLE RESERVOIR SAMPLING REQUIREMENT Sampling for Waterville Reservoir shall be conducted once annually during 1997, 1999,, and 2000. Sampling shall be performed during a low flow period to correspond with the fish tissue study. Sampling parameters and stations are as follows: Sampling Station Parameters * Waterville Reservoir prior to Laurel Branch Temperature, D.O., conductivity, pH, TN, NO2 + NO3, NH3-N, TKN, PO4, TP, Chlorophyll-a, Secchi Depth Waterville Reservoir near Wilkins Creek Same as above y Waterville Reservoir near the dam Same as above All samples shall be collected at 0.1 meters beneath the surface of the water in the lake. L. TEMPERATURE VARIANCE REVIEW During the next permit renewal, Champion shall complete an analysis of temperature data using the period of record and simulations specified in the supplement to the hearing record. As part of this analysis, Champion shall submit a complete temperature variance report documenting the need for a continued temperature variance in accordance with 40 CFR.1259 Subpart H. The report shall be submitted with the request for permit renewal, no later than June 1, 2001. NJ. MERCURY MONITORING periodr a of Mercury shall be monitored twice per month aermit the ef Resultsfluent oshall be twelve months after the effective date of the p reported using a quantitation level of 0.2 µg/l. As indicated in Part 1, A (1), a mercury limit of 0.014 µg/1 shall be implemented twelve months after the effective date unless: 1) Champion submits the appropriate minor modification fee aneffluent requests that the Division of Water Quality review the existing data upon completion of nine months worth of sampling, and 2) All effluent mercury samples indicate values less than the quantitation level during this nine month period. If both conditions 1) and 2) are met, the Division will modify the permit to eliminate the mercury limit and reduce the effluent monitoring to quarterl y• N. BALANCED AND INDIGENOUS SPECIES STUDY. riot to the Champion shall submit a balanced and indigenous species study p next permit renewal, no later than June 1, 2001. The study shall be performed in accordance with the Division no laterof t thaer n Marchality e, 2000.proved pThe This plan shall be submitted for approval outlined is 40 CFR aenous Subparstan udy shall conform to the specifications FE SHEET: CHAMPION - CANTON Is _ NC0000272 REVISED DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES DIVISION OF WATER QUALITY FRCT SHEET REVISED APPLICATION FOR NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM PERMIT TO DISCHARGE TREATED WASTEWATER Application No. NC0000272 Date: 9/30/96 7. SYNOPSIS OF APPLICATION Applicant's Name Champion International Corporation -Canton Mill WWTP Applicant's Address P. 0. Box C - 10 Canton, NC 28716 Facilitv Address off Highwal, 2l i Canton Haywood County Typeof Operation Integrated bleached Kraft pulp and paper manufacturing facility producing food board and fine paper. Design Capacity of Facile Treatment of wastewater stormwater associated with pulp and paper mill, _ chlorinated domestic wastewater from the Town of Canton, and leachate from Champion's existing landfill. The plant will be limited at 29.9 MGD average monthly flow. Production Ca acit of Facilitv 712 tons per day BCT bleached Kraft 901 tons per day fine bleached Kraft (This is based on the NPDES permit renewal application submitted by Champion) Applicant's Receiving Water Receivins Stream: Pigeon River Classification: C Sub-Basin: 04-03-05 Page I FACTSHE T: CHAMPION`-??1SEDTON MILL. '0000272 See Attachment A for a map showing the discharge location(s). Descri tion of Wastewater Treatment Facilities The wastewater treatment facility consists of a grit chamber up screens,lift primary clPumarifiers, polymer addition, pH control (CO2 injection or H2SO4 backu ),three rimary nutrient feed, aeration basins, three secondary clarifiers,residual belt presses, effluent flow xygen injection), and oxygen infection facilities. measurement, cascade aeration (with o The treatment plant receives an average of 0.9 MGD of chlorinated domestic (untreated) wastewater from the Town of Canton; leachate from Champion's existing landfill (which has variable flow based on storm incidences); stormwater; and the majority of wastewater from pulp and paper mill production and associated process wastewater. i. Carolina s wastewater treatment plant certification guidelines rate this plant as a North ted,monitoring frequencies reflect a Class IV facility Class IV facility. Unless otherwise no as outlined in 15A NCAC 2B .0500. Summary of Existing Wastewater Treatment Plant O eration ssued permit-excluding boiler plate language). See Attachment B (copy of the EPA i TVDe of Wastewater (as reported by applicant). 3 % Domestic (approximately 0.9 MGD from the Town of Canton) 2. PROPOSED EFFLUENT LIMITATIONS Basis for Final Effluent Limits and Permit Conditions This permit was previously issued in 1989 by EPA. From that time, Champion has incorporated the oxygen delignification process and elemental chlorine free other bleachin he gt as has significantly art of CTIAP reduton cde ed the mizefflu efion fluent o (from 48.5 MGD to 29.9 MGD). The production values listed in 1. above were used to calculate the federal effluent guideline limits for Pulp, Paper, and Paperboard Point Source Category (See Attachment). However,the Champion Mill is water quality limited for BOD5, so more stringent limits have been applied. BOD5 and Instream Dissolved Oxvoen: An re stringent ts than se iven federal effluent guidelines were necesuter model sary to proteccated that t North Carolinas instreamodissolvedy ass C waters [15A NCAC 2B .0211 (b) (3) (B)]. Due to oxygen standard of 5 mg/l for Cl the absence of an end-of-pipe technology capable of consistently treating to levels necessary to meet the limits specified by the model,North Carolina has agreed with the continuation of the requirement th io vecha injection fac'litn meet hesl as necessary trearndissolved (See Part III, standard by use of sidestream ox�= j Paee 2 F. ` 'SHEET: CHAMPION - CANTON i ,_L, NC0000272 • REVISED Condition I of the draft permit). Historically, Champion has maintained oxygen injection facilities at the effluent and at approximately 0.9, 2.1, and 3.7 miles downstream of the discharge. Oxygen injection facilities will continue to be maintained at the effluent, 0.9, and' 2.1 miles downstream, and used as necessary to maintain an instream dissolved oxygen level of 5 mg/l. To ensure compliance with the above requirement, the average daily instream dissolved oxygen levels at river miles 62.9, 57.7, and 55.5 shall not be less than 5 mg/1 and the minimum instantaneous instream value shall not be less than 4 mg/I. This method is acceptable based on 40 CFR 125.3 (f). Extensive instream monitoring is required to assess Champion's imp throughout the act on the Pigeon River and to ensure that the dissolved oxygen standard is maintained impacted zone of the river(See Part LA (2) of the draft pe i t). No instream D.O. violations have occurred since 1990. The draft permit BODS limit was established based on the demonstrated level of Performance of the existing treatment plant(a site specific Best Available Technology requirement). The monthly average BODS limit (J598 Ibs/day)is based on the 95th percentile value analyzed by the Log-Pearson Skew method on data from 1/91 to 12/95. The I/91 to 12/95 data were used as a result of the incomplete data base of post-CMP values at optimal production and the need to simulate the projected mill variability under post CMP conditions including cold mill shut downs and start ups. The 95th percentile represents two standard deviations around the mean of daily values. In this way, day-to-day variability is measured and used to set monthly average limits. Although.the Log Pearson III method is not typically applied to monthly averages, in this case the 60 data values were a skewed distribution. Upon the next permit renewal, post-CMP data, from 8/95 to the renewal apPlica,ion date will be used for the data araly;;;s (ant ana:)•zed based on influent values and plant removal efficiencies). Based on limited post-CMP and optimal production data, and as a result of the fact that Champion is in the demonstration process of Bleach Filtrate Recycle (BFR), the above procedure was used for this permit cycle. The daily maximum value has remained the same as the previous permit(12.458 lbs/day). During the next permit renewal, the post-CMP monthly average:dady maximum ratio will be compared and used to calculate a new daily maximum. As stated previously, the Champion Canton Mill cannot comply with the Predicted BODE level to protect the instream dissolved oxygen water quality limit of 5 mg/l. Therefore, the limit presented in the draft permit represents an achievable level for the mill. Because Champion has oxygen injection.facilities in place to maintain the instream dissolved oxygen standard should worst case conditions arise, Champion complies with the conditions set forth by 40 CFR 125.3 (f), Effluent Dissolve Effluent dissolved oxygen is limited at no less than 6 me based on the above discussion. Daily monitoring.is required based on 15A NCAC 2B .0508 (d), Paper and Allied Products, Class IV facility. .. Page 3 FACTSH�tr: CHA�dPlON - CANTON N�11LL.', i000272 RED Total SuS lids than the current federal effluent guidelines an uidngnent es for the oxygen delignification process. Champion I are more string are The draft TSS based on the 1993 proposed g eli has accepted these proposed guidelines for TSS (monthly average) in the draft permit. monthly average was calculated as follows: 1613 tons/day (total production) * 2000 lbs/ton * 3.891bs TSS/10001bs product 12549 lbs/day The daily maximum was based on post-CMP operation (8/95 to 1/96in nd the o accountto Of aslight maximum values are also more stringent than the highest daily maximum:monthly average for that time period (taking production increase). The proposed daily production value used was as indicatadit current federal effluent guidelines. The production capacity on the permit application and is within l0�l0 of reported values (post-August 1995). numeric standard for TSS. The rules solids, settleable solids, and sludge deposits North Carolina does not have a specifically regulate floating The draft permit restricts floating due to [ref. 15A NCAC 2B .0211(3)(c)]. was removed from the term average solids. Settleable solids monitoring longpermit is more consistently low values Addition ally, hwell below e limit o imposed in he both t is me restriction of 5 ml/1). Addition federal guidelines. Finally, stringent than current applicable rovement to the Pigeon River. and IBI studies have indicated further imp resents a reasonable Thcrcfore, the negotiated limit of12,5'1. bs/day rep compromise for this permit cycle. Daily monitoring is required based on 15A NCAC 2B .0508 (d)for Paper and Allied Products, Class IV facility. Total Res!duefIlotal Dissolved Solids t. Dail monitoring has been required to correspond with the requirement for TSS. ribution from e Monitoring for these parameters is required to assess the total solids cont plan Y Color ce from Champion has NCAC 2B A2 applied for a 11(b)(3)(F)]the instream color narrative criteria in Notch Carolina lmance be based on 50 true color The permit and variance requires model that color model provides units as calculated by Champion Th a predApplication for of thecolor colorsmodel the allows line the Division and effluent values. Application contribution to the color levels at compromised by a state Champion to assess the ppredicts an exceedance, line through effluent measurements which are not introduction of other color sources. If the model p Champion can take immediate steps to inveime adjustments to be made in stigate and correct potential I problems. Thus the model allows for real al t in of the 50 CU requirement at the operation of the mill to ensure prote the state line. Recent data demonstrate that true color units at the state line Page 4 F/: SHEET: CHAn4P1ON - CANTON A ,, NC0000272 REVISED have been below 50 CU. Monthly average numbers are around 30 CU for the river at the state line since the reconfigured mill came on line. Champion will be required to comply with a calculated monthly average color 'load' of 132,341 lbs/day at the effluent and an annual average 'load' of 124,923 lbs/day. The permit also requires that the predictive color model be recalibrated prior to the next permit renewal. The period of record and simulations to be used are provided as a supplement to the hearing record. Instream color monitoring was recommended at the first downstream station (DNI), below Clyde (DN3), and at NCSR 1625 (DN4), in addition to the existing color monitoring. Color monitoring was included at these stations to better describe the color impacts within North Carolina. The station above Clyde (DN2) was not included due to its proximity to DNI and DN3 and lack of other potential contributions (such as significant streams or discharges) within that area. Instream true and apparent. color monitoring is required (Part I.A A schedule for continued evaluation of color minimization has been ,added to the modified variance and the revised permit (See Part I11, Condition F). Essentially, the color minimization requires: 1) continued operation and evaluation of the BFRTM system installed at the Canton Mill to establish the operational integrity of the system and to ultimately determine that the system is appropriate and can be counted on, 2) evaluation of applicability of BFRTM technology to the other bleach lines at the mill (the hardwood Iine), 3) identifying and evaluating other in-process opportunities to - reduce color discharges to the waste treatment system and development of an appropriate time frame"to integrate the recommended changes, 4) evaluation of raw material storage areas and the feasibility of modifying the existing system to reduce color discharges to the WWTP, and 5) evaluate the applicability of end-of-pipe treatment technologies to achieve significant reductions in color discharges. The intent of the schedule is to ensure that Champion reviews in-process modifications prior to end-of-pipe technologies. A reopener clause was also added in order to modify the color requirements based upon any breakthrough in color removal technologies. Ammonia Monitoring requirements are included in the permit to provide data concerning levels of ammonia discharged to the Pigeon River(which may affect instream dissolved oxygen). Page 5 FACTSHEET: CHAMPION - C D TON MILL. 0000272 R.E Trichloroahenol/Pentachloronhenol The permittee has certified that chlorophenolic biocides are not.used at the facility. This certification eliminates the requirement to ts for two ram hese ters based on 40 CFR 430.84 and include 40 CFR 430 94. However, quarterlytmoni orin w llebe required. Chloroform Chloroform monitoring/limit has been removed from the permit. Based on an allowable level of 2.8 mg/1 (using the federal criteria of 470 µg/I and average flow) existin allowable effluent level. Therefore, this parameter indicated no reasonable potential dropped from the permit. ' Fecal._ Cow cal estic tLimitations for fe he Town of Canton and thcolioe requements of 15A NCAC 2Bare based on the contribution of 02111 (b) (3) (E),wastewater from Limitations for pH are based on 15A NCAC 213 .0211 (b) (3) (G). Temoerature aturnture limit and monitoring rcquirement is based on a Section 316 (a)variance The r -- determination was accepted by the NC Environmental Management Commission October 11, 1984 and approved by EPA August 6, 1985. Upon the next permit renewal Champion shall submit documentation regarding the ture variance along with temperature data and continued need for a tempera This lwill give Champion the opportunity ont rstablizetthe the (with regard to production and BFRTM implementation) and provide an ample data base for review. Periods of record for data review have been specified in the supplement so that no confusion will occur with the next permit renewal _ period. 316(aIn making the recommendation to retain the current deter variance, staff mined in note th6taa baa=variance for Champ on was alsotreta ned dur ng the 1992 84 The 31 ( ) Triennial Review. Both benthic community studies and Index of Biologic, Integrity studies have shown improvement below therCantoniewed existsince the Staffpost Canton Modernization Program (CMP). temperature data and although some i Cham ontst it cannot meehas occurred t thelikely due to overall effluent flow decrease), P North Carolina temperature requirement. Because the Champion h t been reached during post limited data at full production and 7Q10 have nouil t reviewed more. thrn the nextt permitterenewal (See nPartce t11I,ll eCondition L of theopermit). during Pa.-e 6 • R — 'SHEET: CHAMPION - CANTON I:._ L, NC0000272 REVISED Flow The flow limit is based on Champion's current flow values and post-CMP production plus 0.9 MGD for the Town of Canton's wastewater (See more specific description in 'Description of Wastewater Treatment Facility'). Due to potential inflow/infiltration problems with the Town of Canton, the Division granted Champion's request for 0.9 MGD increase in flow-with the provision that Champion continue to work with Canton to reduce I/I problems (Part III, Special Condition J). Effluence The toxicity testing requirement is placed on all major facilities and other facilities with complex wastestreams (Departmental memo 7/22/87). The toxicity limit is based on the instream waste concentration under 7Q10 conditions (54 cfs). For Champion, the instream waste concentration was determined by also accounting for the out-take of surface water from the facility (30.4 MGD, as per application). Therefore, the instream waste concentration was determined to be 87% under 7Q10 conditions. Champion is required to perform the NC Whole Effluent Toxicity Test or an equivalent method (as approved by the Division) on a quarterly basis at 87%. Any equivalent method shall also be performed on a quarterly basis. Mercury Mercury was found in the Champion effluent at values above detection levels in 3 out of 4 samples taker.. Mercury is not an expected parameter.of .. concern in pulp and paper wastewater. Due to the potential for testing interference and the limited data set, monitoring shall be conducted 2/month on the effluent for one year. On December 1, 1997 an effluent mercury limit of 0.014 99/1 will be implemented unless Champion can meet the conditions specified in Part III, Special Condition M. In general, should Champion show effluent mercury levels less than 0.2 µg/I (the quantitation level) after nine months of sampling, the Division will eliminate the mercury limit and reduce monitoring to quarterly. Zinc/Hardness Reported values for zinc have exceeded the state action level. Monitoring requirements for zinc have been included in the draft permit (15A NCAC 2B .0211 (b) (4)). Numerical limits for zinc are not being included in the NPDES permit since the water quality standards do not contain a numeric criteria for zinc and the biomonitoring requirements in the NPDES permit are adequate to control toxicity due to the presence of zinc in the facility effluent. Zinc is a function of water hardness,so hardness monitoring is required in coordination with zinc monitoring. -The monitoring frequency for zinc (2/month)is based on the Division's standard operating procedure for monitoring of toxicants for Class IV facilities. Champion is rated as a Class IV facility. Page 7 FACTSHEET: CHAMPION - C D TON MILL. 1,4 0000272 REV Trac Metals Cadmium, selenium, and silver have been recommended for quarterly effluent monitoring. The limited data set indicated at least one value a one allowable levels for each parameter. Although tra a of Concern. and pulp and paper wastewater, these are not typicalparameters no limit is recommended at this time. Dioxin Measurale levels of dioxin have t been dischar this facility since the completion of theo detected There is wastewater currently a fish hconsumption advisory for the Pigeon River downstream of the discharge. Although the advisory was initially in effect for consumption of all fish species, this advisory has been reduced to carp and catfish species only due tb continued improvements in the River. influent, is required to sludge, landfill leachaterand efflue dioxin nt (See enzofuran Part I1I, Condiitions ),quarterly from the The effluent 2,3,7,8 TCDD limit is based on 15A NCAC 2B .0208 (a) (2) (B). The average flow of the Pigeon River(325 cfs)was used in the calculation of the allowable effluent limit for dioxin at the NC inst to as dailywater maximum lstandard of 0.00014 n A [15A NCAC 2B .0206 (a) (3) (B)J. Annual fish tissue analysis shall also be performed by the facility in accordance with the monitoring pluu approved by the Division. Total Phosl2horusfTotal Nitrogen monitoring is required by 15A NCAC 2b .0508 (d) (2) Total phosphorus and total nitrogen-d to assess the ntribution of and the Monthly potential is reuire Waterville Reservoir.co Waterville Reservoir isto be �pion monitored once annually (during opposite years of CP&L's montioring) to assist in characterizing nutrient impacts to the lake. _ Condom Conductivity monitoring is required based on 15A NCAC 2B .0508 (d),Paper and Allied Products (Water Quality Limited Facilities), for a Class IV facility. COD COD monitoring is required to as, the potential impact of chemical oxygen demand from the Champion wastewater effluent. Neither federal guidelines nor NC water quality . Current draft EPA regulations and supporting standards require a limit for COD documents state that COD may be related to effluent toxicity. As the permit contains a chronic toxicity limit and the plant has not documented any toxicity problems, no limit for COD has been proposed. Paee 8 FA _ iHEET: CHAMPION - CANTON Dyii , NC0000272 REVISED AOX Monthly effluent monitoring for AOX has been required in the permit. AOX is an overall test for adsorbable organic halides, which include chlorinated organics. Trends in concentration changes have been observed between AOX and specific pollutants (dioxins, chlorinated organics) at pulp and paper mills. Therefore, any decrease in AOX may also indicate a decrease in chlorinated` organics: Limits for AOX are proposed in the draft EPA Cluster Rules. Monitoring has been added with this permit to better characterize the effluent. 3. EFFECTIVE DATE OF PROPOSED EFFLUENT LIMITS (AND COMPLIANCE SCHEDULE IF APPLICABLE) ' The limits became effective on the date of permit issuance. 4. PROPOSED SPECIAL CONDITIONS WHICH WILL HAVE A SIGNIFICANT IMPACT ON THE DISCHARGE Toxicity Testing Requirement Color Monitoring Requirement Color Minimization Schedule Dioxin Lunit and Monitoring Waterville Reservoir Sampling Dissolved Oxygen Requirement 5• XUESTED VARIANCES OR ALTERNATIVES TO REQUIRED STANDARDS The facility requested and received a 316 (a)variance granted by EPA 8/6/85. This determination demonstrated that the effluent limitations relating to the thermal component of the Champion discharge based on application of NC water quality standards were more stringent than necessary to assure protection and propagation of a balanced indigenous V population of shellfish, fish, and wildlife in the Pigeon River. Therefore, the 316(a) determination was approved based on protection of the appropriate use classification of the Pigeon River. This permit continues the 316(a) variance and requires studies to be completed prior to the next permit cycle to enable re-evaluation of the variance. As discussed previously, Champion has applied for a variance from the instream color narrative criteria in North Carolina [15A NCAC 2B .0211(b)(3)(F)]. See Section 2 and the attached variance documents. 6. DISCUSSION OF PREVIOUS NPDES PERMIT CONDITIONS See attached EPA permit Page 9 1 I-ACTS14EET: C14AMPION - CANTON A d ON MILL.NC0000272 EV_ 7. THE ADMINISTRATIVE RECORD The administrative record, including application, draft permit, fact sheet, public notice, comments received, and additional information is available by writing the Division of Environmental Management,Water Quality Section, P. O.Box 29535, Raleigh,North Carolina 27626-0535. The above documents are available for review and copying at the Archdale Building, 9th Floor,Water Quality Section,Permits and Engineering Unit, 512 North Salisbury Street,Raleigh,North Carolina 27611 between the hours of 9:00 a.m. and 5:00 p.m. Monday through Friday. Copies will be provided at a charge of 10 cents per page. 8. STATECONTACT be the above ained aAdditional information ddress during he hours ostated in item No. 9 by contacting:ncerning the permit application S santWil ontat (9 9) 733- 5083, extension 555. 9, PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice - 5/6/96 Public Hearing- 6/6/96 Permit Scheduled to Issue - October 1996 10. PROCEDURES FOR THE FORMULATION OF FINAL DETERMINATIONS 1. Comme�nod oses to issue NPDES aThe pplicntssubject ttovironmental the effluent limitations ns anement d special conditions outlined above. to this These PP n to comment from the public. determinations are tentative and are open interested io oeatitP ication or n the Division of Env onmental Management's prop determinations t he following address: DIVISION OF ENVIRONMENTAL MANAGEMENT POSTRUALITY SECTION OFFICE BOX 29535 RALEIGH,NORTH CAROLINA 27626-0535 All comments received within thirty days following the date of public notice will be considered in the formulation of final determinations with regard to this application. b. Public Q Due to public hearingt in the has already sche the duled.ed. The heariuirement of a public g will b he d June for ance 1996. Page 10 FACTSHEET: CHAMPION - CANTON MILL. NC0000272 REVISED C. Appeal Hearings An applicant whose permit is denied, or is granted subject to conditions he deems unacceptable, shall have the right to a hearing before the Commission upon making written demand to the Director within 30 days following issuance or denial of the permit. d. Issuance of the permit when no hearing is held Not applicable. Page l 1 ,� - „.. ... the Holiday Inn v - n Cost is$20.So JIM BURGIPUCIn EN-TIMES for the North G area. TRANSYLVANIA CRoSSNORE—A tractor-trailer carrying garbage from a landfill ran of Highway 19 r Thursday in Avery Make re K GARi Land to be marketed #tear indnstey County, Bill a vacant house and overturning where the highway intersects with Prison Camp Road. monthly meettir The driver was not injured in the accident. Chapter of the BREVARD—Facing a March 26 expiration of a will be held at purchase option with Mars Hill College,Transylva- Mr.and Mrs.E nia County is moving ahead with plans to market the �� sandwich and remaining two parcels in its developing Brevard � ��ee �� ���� cO 884-5479. Commerce Center. Commissioners gave their approval Monday for C L A S S i planning and economic development director Mark ® �� Burrows to seek tenants to bring t new jobs to the AM full: �r� pig�� ke NANDMAO Railroad Avenue property,where there is roam onwanis i!�/_ha toI� n 1�1��1 Arboretum wil the 11-acre site for four small industries. - make garland The other two of four lots have been claimed,as tervene in a dispute between North The cost for n pater and sewer lines and a road into the property AP AND STAFF REPORTS Earl Bee Tennessee Wildlife Re- Carolina and Tennessee over Chain 5 The Arbor are ready. Stillwater Products moved from Califor- KNO�LLE, Tenn. — The Road)in Ash nick and began producing its copper window roofs in Tennessee Wildlife Resources Cook- sources Commission voted unani- pion s wastewater discharges in the SOUTHER Ash the park in early October on the back lot next o . mission wants the state attorney mousy Wednesday o send y Gen-reso- late 1A9s8 a result, Champion invested Museum pre Tinsley Road. A small-business incubator funded general to object o Champion In- lution to Tennessee Attorney Gen- 30 million in the early 1990E to Circuit films c from county and grant monies is planned for the ternational citing another o erat sstate'sharles waters egon rotected that the make the plant cleaner after the middle of the three other lots. ing permit. p p downtown p.m.Frig Burrows said Thursday he and County Making- The company's Canton plant is Champion spokesman n Joyce EPA imposed stricter wastewater downtown A: shortly seeking a wastewater discharge said he'd heard about Tennessee's regulations on the paper maker. Madonna am er Artie Wilson will meetemployers to decide how o The state of North Carolina Admission is get word out to prospective employers that the land permit to continue operating far abjection o the variance but was „ is available. That meeting had not been scheduled five years. Tennesseans have long not sure what effect it might have tries o say the color of the river is others. 3 complained of Champion's pollution on Champion's permit application. natural and comes from trees,"said WRITING Thursday afternoon, count- clerk Sandra Jameson Nelson Ross of the Izaak Walton working on tl said of the paper-making River.The Champion Noon a variance allowing it to League. creating sale The county's posture in attracting new jobs is paper-making plant is about ee Champ' improving. A Superior Court judge in July dis- miles upriver from the Tennessee continue discharges at present Protection missed the last fragment of a lawsuit that was block- border. Agency The Environmental Protection "Anybody who knows anything finding an at "How do they get away with Agency will not intervene unless about this part of the country 1moc+2.; Saturdayfnaii ing progress on the incubator. I Betiding,20 The county is also working with Cashiers build- this?" said Wildlife Commissioner Tennessee objects.The EPA did in- that's not true:' ing supply store owner Richard .Jennings —who is RIVER P 1,building another store r Pisgah Forest just north of �q ty ® s+ the National Brewazd — to certify his private development of an Forsyth ����"Je 0����'�`� �`�������� ������� �� � � the Lifebloc industrial park with the sate and regional market- y p a Lash's release also was the at the Botar ing agency AdvantageWest,Burrows said. THE ASSOCIATED PRESS day after a paperwork itix-u�al fourth time in 18 months that jailers WINSTON-SALEM — An in- jailer said. Lash was awaiting fij i Brevard banker Perry Hendr x chairman of the Lt. Col. Michael Schweitzer, non-profit Transylvania Partnership that is building was released mistakenly from the and possessing stolen goods. have released di inmate by mistake. 1IPfON the incubator, said the 20,000 square-foot shell of a Forsyth County Jail, the second on Sept. 10, jailers released the county s director of detention reunion is p building is on hold while the private group seeks an time in two months that jailers have Jermaine Wright who was charged services, said it appears that some Tipton High re lax in other grant from the Farmer's Home Administra- cafeteria.B lion o lessen what will need to be borrowed. Hen- released an innate by mistake. gi girlfriend.tin In restiga Investigators found procedures- jaila thates ew would havefoll 688-3952. Reginald Jerome Lash, 42, gir Lash behind bars. drix said he hopes to have an answer on that loan by walked out of jail about 8 p.m.Tues- Wright within five hours. the end of the year. rCa�►7�lE�E ��9A�KEGffiNCYIM Uft PLEASE CLIP AND MAIL wint YOUR eDINNER--$1.5i I 1 nITILPleasehsprovidetraditionalhome-rookedr `.,v - 6Jls t Thin strips of beet chmeals with all the trimmings for the hungry ,`�.5`, b SPECIA�, {�E 9 r `ts 5es r7 5�, eta ® unu TMRLt THURS. FSpeppers a duoons. Ser.6nUer far the homeless durin this �'� '� "^A , ' '� _.1 Pile C u 419/23/1996 15;02 7842525452 PAGE 02 •rota igbacM,firaad:ltb atWiltaY `� '1�,7111 ASSOCIATED PRICS $Iona maoltadala8 puhUc anowapapar�'hr1 ^ ' ' Darr11 I gervi Icmlvlai 9lrieIN 'it'.,;,Greap■itlsd%]A1thithaim&r hl locco riods haw Floridaitan1l. Ccta don •,:. , c-wt' ". 1datA<aetq'7g42 tharghhs'j i yeas gboat faeTSaadeyvTsin ha' d with to ova : C ' lots two estaana ahts tkkd*,Too* {[imlaBmlEh Wld'11 e'!: i 5�r orth :�CuoYrikVlt'aoPl sholdn'R onalrawlY 1 InmPr �4f NaWldl,H{m''' (,`'i l �tl0 til a ono market to the South- 01 d! y',bpdrAWT „l 6ualtat Thar.tappea adds';" 7 anuy Eft Yearn. aaddhe �ota.entea• it i10e.t{f.�a t'aaud sad t*7gkad mch 254- t'• 't TM primm amve,l after Hurrl- .. 'x. ,+a• rM7Yhrawwalhat �aa an lbe nmAaaocwlrJ.traess . coon Ran and RUVIR sluDlraad et but tasesyean &nIM Saki: , Fehwrar U.Cw.lMnny!irNa to h"the same strnluh of the Nuhth ar AR&Mfft -012 plea It port of tfia 1v¢orCwollna aahwt within pap off N.C107 a mveottlI�paiidan butAfropployaancladoa aiW14bpleadgiftt►tea Car icon thin h4 allardlag to the Cur elta U In that tOvaltlgSum," sdea blot a tadard Baw l SO month, Ths huh$• Aaer Smith told tha newepmppeerr Our Wgrlakl{SM klerMw Y an alfat to oana.vvhkh lilt July Ater ambonkn a it,wren hope is that when A1r, Green An, Sad ku fdk h a blood fro Ura patrol.The Ishoa this plus and UNM hh re- IAypdption fob toliam hood. IJ and Elept.hear o tore purr L,about nine colas apvnemWty,he will lure couclsdcd Into the Vast!of the bl. association with the Inveetyn• Creep,76,feu geutan.nE low atata'o tobacco Dla); . met Ban=Urel ;' ernarlleml0RtolBWdel*Gov. uprooting planta and ahredding Can _ Calls to BMWs hdmp and haw Jim Hunt'a tTrattwa tome.He tidn leaves on thA stalks. Swi office went unaswered Sunday. worked for Oor dim h WIA a its- 'One rraon s fortune Is anoth- Yell lg111111111tien (iron Arta the U.S.Attarrrye Cf- publtelm. er Pomona mlerortDneo Oaorgis gra 4041pod tWnment to the haws• No ran for governor In IOW, Agriculture 0onmiAsloner 7bmmy at E to trikkal eoraAom but btu candid n'W hempeeed by Irvin laid. ,rho misfortune or our Tun Idlhd anAahornto p r The fodmol govorrimemm to trp a 19m Charge or aces ng a 42A00 Carolina fanners has earned the an Ing to determine who le rnpmulbla btll» horn So FSt undercover supply to tglitwt■t�and bw klokeJ prsl u In CHtkd Solidi• rot v4111ng milikete of hale rat to agsnA Ha refbaad to plea bargain In up the price aevera rants o pound." HdMiWonHwpl. I=01aeandwn Idttod, NorWCaroltnaYwoonarcwan- bxea illegally het meghhg the ac') Pa 7aISSIngerinalm The flarcoly aoiweNatYa and d6rM Ravi fgr2,1001kar6iatubao- min Interstate,40 out araPt decal Ppaf't rO' uncompromising Dumami n-ed bid cc farmers aM snothers001n F1orl- Fep pro 211y a hove been tan a ng. lid, adn9.according b imeatptLrg vh4odly every tole in ofnhm sa a power center. Crean CIA. eni Uhl Chain or tobacco calm, from ablamp laved business aml hhdumuy. The mpsre Idasgo manna an ax• Hal 17-mr,91ADavkl d errviranmentallate slid Be Ara IBBOIkO in ¢roes mauul wdae r wreak.on driver ferrraan to tmeharthheman ca tobeo- , and adroeaWd fiscal Inv Roger r/avle,a FIoHc4 W17acco <o "ere, Severaf people have t>�gnm AIR ad 11), also of bem co wletad. and eodal conamvaFl»r. with 40 Der o of tabacca, itt midr C_.-T hAmfate In an extra 41%(M. N no o guarantee fieom N.C. Tall even prices wore the and at cedgr m await even !afore Berths andIto Fran belted the c arvIlm couWue wig doaaffon boa b0a9t, ■ Lac■tae of Idglt worldwide dItmand n 4s Mild Ifs new on Champion pollution amdtghp tobacco stocks thMugheut yr the Honuraait.Irvin Sold. and aonsteaeton of out the kosvy rsitrm, floodhig NA ea 220•seat dSi,vll nwAselwuvaD¢Sass mot it in move in the direction of a and power ouugas caused en eetf- forthe edlagsL ill• NASHVILLE, Tone. — North no-avniwlons mill," peal Nvle, all• mated i331 mWldn lops to caliper, Catalina elflalalm are making no ncior of Tannaeeao's water pcild. trope In North Carolina,making It R be used to expand comlaas aboutreafdng Champlon lion control division,said the ststS'o wafet'"or agricultural on��, ed eye,' nfan+dlathal Corp.y.to ken polko- 'That Justwam'tln na ruvutar. alatallelan Crag Hayes We sAm"buflding. don Into the f9goon Rlvar rf partor Baia, krge4Watory,eame a pendingfvaycarparmlh to dompsny 'ba< invested Mara than half the ataida 11 laaterymhg. Champlan4la .tv"In Cue- mor0 thAa>jROOnllllan fn poluton 2M.g00 acres devokd to F,LAooa of tea bin bum dun Ailywaste In the arntfoL In reaerd yore Ibht hot was damaged,said Hayes,awlatant Co river that flews Into Timmopose for brain foam from the m111 dlll or- diNctm•Of flop North t:aro0nt De. 911 more than be years It Is weking a Taste Ash and given off an odor In parbnent of Agriculture's AVOW, pk spoofed In new permit and virisnutoomtron• turalstathticsdivttforl, mental team. ay Camillus atll- "1'd rather it be you thou mq:' Th *08pp ai In Am It atenda,the omit w1U Inv chh)Bald We IMW you oral we've gold Davis,who gismo e0 Scree of, be Itp�2, strict mampian to And ways to ro• got aurae(date and pull See them Wwav qn Alacbu� Elm "Nohady aeI dwe pvllatahr.but recqulre nothing. later.' wSnht eavbgdy to IQee At all.but V , Inn "We,wattled W Me aaoetbing OIL moats sans for an anawSr," it's lotto boeamahody,putnutme; "ball MyaEimgisapeectlm. In the permit with a fen MO..hIt- TIP,$sad, ATgh,aybuLMe." r:411 am.-teaches teen-aged girls the importance4 of ;gib out with to Heel Friand girt bacalaa Members of the newly formed "You can trod hays Moro than to follow the rules.Some du- they cant bave leg,"said Devin Sto- I0g Hlull Women of Grcater Char girls btallia tf you fella boy oome- hear ablatt the rulei aml bar- va,ill,who attenaY Ramon7auddla lolls will be mantars U the pautr, • thl�,thadrg n9t¢olpg to run tuwk bom atrango logos, Ito IldwvL"Bat the nkssjng the wad The girls u_M tliq 11 ri a lot Ilan i to al) their Mende and may. 'Ray, • "1 w.. satklmg W s .. ..� + ..ter.. .LLL -...�,.�..aJ �......L.a...�J... J,J •'re, —J— . .rY £ 'd 15:60 9661.10-81 nl •3l1In05nn siioisIn Ia a31nn 03a1 unmd rrraN3rr• q/zz/fib lr•. Y 15 '�' , ; ,. °for. cleaxier`raver ' ''; '�t�'�NrrE vair�•:'�ciM1�ss¢or: .':��h:� � ' North Carolina d:dak say no butt[didn't SOY 1' :yes elmer.M a re9upt from Tetlita�ee to tlwtial to Au"I re4ulre'Cbamplon Iateraa Care •frt->. . ther cleat up the Coltee-Colored wagewate[ It r; ', kis;•;::.:..,, •,S'•' • uumOstu the. Riven 'u The'eelghboring'state.1a Poised to lssue'a •' rtew five year peredt and verlaaee to eIMMA- i rnea(al"laws to'the champion Paper mnl In Canton"'N,C.,'ghlch Is 87 mnes UPTi of <k!�'BeeetZ8e.:8, 3ai:t s•icCoikL.®ro.pr WermaTYist"„Mes p po�:n:u:l�get.:ft tw champion to I.. without including!'We wasted to;see,aaeieWhtg In ILO perml .. a r4at armmlmteat to mavw to tLa sires.: tToo':gt a noer athAs:rglL�n.pA 1)avla.'dtrea ;or 1lnndsese:rf etef Wh eontrel yefdn,:Ce7A'y',este'dpy a•>,� /W���µ�w t.•. Orlwln.`./,�<"�.�/Nlfi-'_•',Y^yn•Y<j'FNI�i IA' •h'I j `\Sn I:VYp(H wlwse V r YYG�d,en the OU got a'tetpanse from North .ratt on 2¢ae,8,. �'•`,lt,droftne eavlroameatet wtl:Ctels to a•rneethi8 Fjiday,iq Knoxville.He =a interviewed Yes• rat me Tenneteea Eevt- t6rdaY earl�Itft n1a1 C VI I . . rebrRental Counet's INN Fltvlrunr[Ie ) con.:1 g Wt Uld bt the,$eCond Pfesliyteill+n. Q[�13w moat Boulevard..'::!J,•.• t° , . . ;,;G�"'"Ihe DeCmlts�are;w8ttea.for.tivaYean,.; • kira-We wdnt to see Sve years of _' i •...:.� ..�•i.;. ... . .','.... g11i1E14~ ��.IY.C;i�ii✓f 9&ii:-..•,. 5+r'�1. +; , yy ewa year You an weYe some.ldees end yofi I!?see them later"ft tseab - :'no''for en'enewmt,i: ,As ton-has.dumPe Waglewateta laM the plgton lUvertior,-more than 80 years,foaling:. ,•; the shum.lmat enteis.Tenmseee with brown and.emgmlet�la:STh®•state vpen!M'eourt8 I f the inasto Mop North L'arb7loa from'allow is �(tg the pollution and won 1m0;i ewe butally eveltha Grokin MCTO so ahpioo laa� cqu�Yserr's Our tree i' $300 million to ponution,'Cunhomi The rlvdr b •. cleaner as a rcsmn,and'It;Oa=omlal mmm •ChMed up mtor0 Iluui;40,000 trips last.yeer<;. But all ls'actlwell :The'mm slut Buts abut dart'weetewater�that�'� ' a bI mole thad'W'dogrees holterAhanbe t natural river watel8, ''; :The color wad the smell es;Wdi"ss the etteek Twn to 1",tGB 211,LWOW 6 b -d L5:60 9fi6r•I0'0r Nl •3-I'Irrmstm smo IsinIO N31ea 3301 Ilued FAX FAX COVER SHEET ENVIRONMENTAL, OCCUPATIONAL, HEALTH AND SAFETY. CHAMPION INTERNATIONAL CORP. CANTON MILL TO: er �oys FROM: DATE: NUMBER OF PAGES: O (INCLUDING COVER) Q NOTE: SF.OjPENOE p2 pP1P�0 PN�E�ER SENDERS PHONE NUMBER: (704) 646-67OO FAX NUMBER.-(704) 646-6892 FAX PROBLEMS: (704) 04"700 TO' d 800' ON 90:O1 96.£0 00 Z689-9b9-voZ:OI SH03 NOIdWHHJ ::snton Mnl Canton.NWh Qwoima 7.871 n c Champion .-amnion lnlern,V.ona1 Corwranon September 24, 1996 Mr.Roy Davis NCDEHNR 59 Woodfin Place Asheville,NC 28801 Dear Mr.Davis, Champion has received the final results of analyses for total mercury on fish tissue samples collected during August 1996. These analyses were performed by Quantertll Environmental Services using Method SW 7471-M. All samples analyzed were composites of the right fillets of five fish. All samples collected upstream of the mill in Canton at Pigeon River mile 04.5 are identified as CHI-I.These samples were collected on August 14, 1996. The dam which exists in the Pigeon River just below Champion's intake prevents the migration of fish from downstream of Champion's discharge to the upstream sampling point. Samples from downstream of the nrill were collected in Clyde at Pigeon river mile 59.0 and are identified as CHI-2. These fish were collected on August 13th. The species collected at both sites are representative of populations that have been collected Annually for the previous five years The results for both locations are summarized as follows: Pigaen River Mile 64.5 Canton Upstream TQtal Mercury Insft CEH-I-IRF-Redbreast SF 0.13 CHI-I-2RF-Rock Bass 0.51 CHI-1-3RE-Bik Redhorse 0.38 Nircon River Mile 59.0 Clyde Total memilly Tylgft CHI-2-IRF-Redbreast SF 0.048 CHI-2-2RF-Redbreast SF 0.068 CHI-2-3RF-Carp 0.041 ZO' d 800' 4N 90:OT 96.20 100 Z689-9b9—t•0L:OI SH03 N0I8WUHD CHAMPION EOHS ID:704-646-6892 OCT 03'96 10:07 No .008 P .03 mp/SIs aaaulSnq lemouruoap% ug gaslao51 auuasns 'iS£Z-9V9-vol le aIu lira en+p osogl lnogr suoTlsonb Sue anuq nod g •SluouTgaelln agl ul popinoad oae rlrp aaueanksp dlllenb pue sl)nsaa anss9 11s9 211•L •palueimmun sT 22augoslp s,uoldmq:)dq palogl3u sn qsy ul Sanawaru 3ulpar.9aa maauoa glleall.Sur. s)lnsaa osogl uo paseg 'lip aql anogn poloalloa sald=s al paansumu osogl uegl=I Spuea9ludrs aas a2ngos)p [lltu mil molo9 sordTurs oql ul suog=uaauoa agl legl Rupou guom sr II •pouodaa 2ulaq dpue.una slanal dauaraur lelnl aql 3o uollomj u Sluu aq of pmoadxa aq pinom sasdleue Ajnm=Id1lai4l 'wdd [ ;o gsll ul lomol dmaaaw ldgTmv r.sl galgm qs9 aoI daosrnpu uLIIloju311110 l aql pue uonmislulurpV srLTQ pue pool•S-fl mp moNq )lam oslr.aaa. XQq L Sanoaotu ao;slanal puncv8jar.q sn pozruRoaaa Sllu=ou sl lugm ulgllm ore saldwes oql IIV 9661 VZ xquoldas surd dog-aW of sllnsag onssly gsi3 uancma!o`IY.U(P:eVli9l�l uuKlwP.y:l ' CHAMPION EOHS ID:704-646-6892 OCT 03'96 10:07 No .008 P .04 waay iluuad SaQdN oaunuwoa 5uuaa78 SH(r im :aaq DES PERMIT RENEWAL NPOES STEERING TEAM COMMITTEE Ben Bilus (Stamford) Ben Bilus (Stamford) Dardc Brown Dick Diforio (Stamford) Ed Clem (Stamford) Gerard Closset(West Nyack) Mike Cody AI Joyce (Canton) Al Joyce(Canton) Steve Hadden (Canton) Susanne Koeisch Dave Hearne (Stamford) Tom Siegrist(Stamford) Billy Clarke (Roberts &Stevens) Jeff MoNealey (Porter, Wright, Morris&Arthur) SO' d 800' cN LOOT 96,£0 130 Z689-9b9-VOZ:GI SH03 NOIJWHHJ CHAMPION EOHS ID:704-646-6892 OCT 03'96 10:08 No .008 P .06 aodea s ISOM Aaa } lql ;o lied lea e}ul UP SL AeZZal aanoa aql Melon AAMS =.fU PdnUgddV ACamool ualEaeW :a8 palaodaa elgealldde pN - VN pa}�a}aP ZoN � aN 96 9nV BE 96 9nV 83 W-11W MS 00'0 6x/eui 960'0 6an�aW ® as alea PoglaW 4 uu1�1 sgun llnsaa aalMeaed Paz LVuV paaedaad leailiSlVuV 6u4}aodON •ZM IBM Malafi aaS :pazAleUV MOLDS DOS :peaedead 96 DOV oz :PazEaoglnV 9a 9nV oz sPUnieDeg 96 J1{V EL :PaldnS 3nSSI1 :xialsW VS-9I00-I3I680 :0I qel 95 }seeagPaa-daT- -IHy :U1 fUaFIO ON - Ieuotpuaa}uI uoi me40 :swell lua4l0 (anssll) AVAW Sle}aW IV301 TiRB'd Z6H99r9v0Li OL beds ItIM W 62:Yi 96, 6i d3S SEP 19 '96 14:29 FR Q ANTERnA TO i704646GB92 P.0Sr11 . Enr4o�m�1 Total Metals (Tissue) Client Name: Champion International - NC Client IO: CHI-2-2RF-Redbroact SF Lab ID: 08912I-0019-SA Matrix; TISSUE SamplaA: 13 AUG 96 Received: 20 AUG 96 Authorized: 20 AUG 96 Prepared: See Below Analyzed: See Below Wet wt. Repporting Analytical Prepared Analyzed Parameter Result Units Limft Method Date 04.0 Mercury 0.068 mg/kq 0.040 SW 7411-M 28 AUG 96 28 AUG 96 NO Not detected NA - Not applicablc Reported By: Marilyn Toomey Approved By: Barry votaw The cover letter is annein2egraal part of this report. 30 LO' d 800' oN 80:OT 96,20 100 Z:689-9b9-rOL:OI SH03 N0IdHbH3 r SEP 19 '96 14:31 FR QUANTERRR To 14TJ4S466892 P.04/it Total Metals + (Tissue) Client Name: Chaammppion International - NC Client ID: CHI 2-3RF-Caro Lab III: 089121-0020-SA Matrix: TISSUE Sampled: 13 AUG 96 Received: 20 AUG 96 Authorized: 20 AUU 96 Prepared: See Below Analyzed: See Below Wei, wt. Repporting Analytical Prepared Analyzed Parameter Result Units Limtt Method bate Date Mercury 0.041 mg/kg 0.040 SW 7471-H 28 AUG 96 28 AUG 96 90 = Net detected HA = Not applicable Reported By: Marilyn Toomey Approved BY: Barry Votaw The cover letter is an integgral part of this report. Rev 130787 80'd 800' eN 80:OT 96.20 1D0 T689-9t+9-bOL:OI SH03 NOIdWUH3 5EP 11 196 142-32 FR GUWFEPM m 17046466692 P.05r11 Total Metals swim (Tissue) Client Name: Champion International - NC L Cent ID: CHI-I-IRF-Redbreast SF 10: 06912i-0021-31k Matrix: TISSUE Sampled: 14 AUG 96 Received: 20 AUG 96 Authorized: 20 AUG 96 Prepared: See Below Analyzed: See Below Net wt. Reporting Analytical Prepared Analyzed Parameter Result Units Limit Method Date Date Mercury 0.13 mg/kg 0.040 SW 7471-M 28 AUG 95 28 AUG 96 NO = Not detected NA = Not applicable Reported By: Marilyn Toomey Approved By: Barry Votaw The cover letter is an integral part of this report. Rev E80707 60'd 800' oN 60:01 96.20 130 Z689-9b9-b0A:0I SH03 NDIdHUH0 SEP 19 1% 14,34 FR UjA nTERRA Tn i7U6466692 P.05i11 rAtall 011 Total Metals �* (Tissue) Client Name: Cbamppion International - NC Client ID: CIiI-1.1RF-Redbreast SF Lab 10, OH9121-0021-SA Matrix: TISSUE Sampled: 14 AUG 96 deceived: 20 AUG 96 Authorized: 20 AUG 96 Prepared: See Below Analyzed: See below Wet tit, Reporting AnalyLlcal Prepared Analyzed Parameter Result Units Limit Method Date Date Mercury 0.13 mg/kg 0,040 SW 7471-M 28 AUG 96 28 AUG 96 NO - Not detected NA = Not applicable Reported By: Marilyn Toomey Approved By: Barry Votaw The cover letter is an integral part of this report. Rey 230707 OT' d 800' ON 60:O1 96,20 L00 Z689-9#9-roL:OI SH03 NOIdWUH3 r� SEP L9 '96 14.34 FR GU*rERRA To 1?246466892 P.06i11 Total Metals (Tissue) Client NZMQ: ChAMVpon International - NC Client ID: CHI-I-2RF-Rock Bass Lab ID: 099121-0022-SA Matrix• JFSUE Sampled: T4 AUf A6 Reeoived: 20 AUG 96 Author;zed: Eu AUG 96 prepared: See Below Analyzed: See Below Net wt. Reporting Analytical Prepared Analyzed Parameter Result Units Limit Method Date _ Date Mercury 0.51 mykg 0.040 SW 7471-M 28 AUG 96 28 AUG 96 NO - Not detected RA - Not applicabla Reported By: Marilyn Tnomay Approved By: Barry Votaw The cover letter is aneinto ral part of this report. TT' d 800' oN 60:OT 96.£0 130 Z689-9#9-b0L:OI SH03 NOIdWUH3 S'FP 19 '96 14:34 FR QURNTSM M 17046466892 P.07/11 aatita� Total Metals �^ (Tissue) Client Name: Champion International - NC Client 10: CHI-1-3RF-Rlk Redhorse Lab I0: 089121-0023-SA Hatrix: TISSUE Sampled: 14 AUG 96 Received: 20 AUG 96 Autburized: 20 AUG 96 Prepared: See Below Analyzed: Sea Below Wet wt. Reporting Analytical Prepared Analyzed Parameter Result Units Limit Method Date Date Mercury 0.38 mg/kg 0.040 SW 7471-M 29 AUG 96 30 AUG 96 HO n Not detected HA - Not applicable Reported By: Marilyn Toomey Approved By: Barry V4t4W The cover letter is an Interal part of this report. Rev 1SB187 ZT' d 800' oN OT:OT 96.50 100 Z689-9b9—bOL=OI SH03 NOIdWUHO CHAMPION EOHS ID:704-646-6892 OCT 03'96 10:10 Na .008 P .13 •S310981 pgxelnaLV3 UR SlodJa ljo-punva p;nAt' 04 euipun0.1 a.4v;aq pauuo;,tao 8AL' Su01120ole2 LLV 4'£ Uat8 SL Iwo Oro 49.0 E9'0 QE'0 d+nacoW OdV A'.iW SW US14 dSW dna nX1dS Xaxl ds aLd:I1V$ 8}C LFUa H pjIs f4W 1i3w quay®d -------------- UDj:tVt31W3uo3 -------------- 6l/bw :31jun U014VAJuBDU03 305SI1 :xla3upp e-96 env 6Z =unH 00 XV-96 SQV 6Z !401 00 I'v a 96 OnV of ;pbp-RLeuV 96 90V K :POLUWVS idwI W-ILVI MS 'pd43ew 3n5SI1-VVA069H -a;45a1 unlgraFdv.td put' sl4Rsp W 91246d L l 4aW 1110d3N 31V31ldf10 3XIdS XINDW / 3XIdS XMVw '[S/B0'd Z6899p9rmLS Oi tl21ti31t�WR1 � S£:4[ 96 . 6S d35 f� + SW 19 496 14:35 FR QUANTERRA TO 144746466592 p.e9i11 Sod= MFTHnn BLANK REPORT Metals Analysis and Preparation project: 089121 Test: HG-CYAA-TISSUE Mercury, Cold Vapor AA Method: SW 7471-M McLrix: TISSUE QC Lot: 28 AUG SO-GX QC Run: 28 AUG 96-G Reporting Analyto Result Unite Limit Mercury No mg/kg 0,040 Test: MG-CVAA-TISSUE Mercury, Cold Vapor AA Method: SW 7471-M Matrix: IISSUt QC Lot: 29 AUG 96-JX QG Run: 29 AUG 96-J gg Anelyte Result UIIILS ReLimitn9 Moreury NB mg/kg 0.040 No - Not petected VT'd 800' oN 01:OT 96.20 130 Z689-9b9-b0L:GI SH03 NOIdWHHO CHAMPION EDHS ID:704-646-6892 OCT 03'96 10:11 No .008 P .15 v 's3lnsaa palpinalea uI saoAra Ilo-punoi pion o} 6u}punui ajo}aq pamao3aed an suG112 0aLV3 pa}aa;oo 40H ON 09I-¢9 101 ZVI 02*1 A.+nojoW TVS71 padnseaW PON* n2gLeav eanuay uoE).erJuaaue0 64/bm :14}un uo}}eiJuBsuoa P-96 env 4Z :unu 5b x(,-9a env a :zoi ib 3nsSI1 :XwVw 3nSSIi-tltlAO^9H •4sel eussEt xo} VVA7 xq Kam-lug USSI1-OR :K-1o50lp0 10 ( 3uoo) uof3nL09wH 4610 - dneup 9S*tVuq ai peuunapv iwd38 31dWUS 'IOULN03 AIIo1VI owl 1 TT/6T'd 26B9g499BLT Ol trdMLNUM ZU 9MOT 96, 61 d35 SEP 19 196 14136 FR MJRiTERRR TO 17046466992 P.11/ii • r�&nemmmml SWAM MetalsAAnagyaisOand Preparation Project: 089121 Category: HA-TISSU Mercury by CVAA for Tissue Testcode: HG-CVAA-TISSUE Method: 30 747I-M Matrixz TISSUE Concentration Units: mg/kg QC Lot: 28 AUG 96-GX Analyzed Date: 28 AUG 96 Time: 17. 3 ---Concentration------- Accuracy Precision Analyte Spiked -----Mpasurad----• Avara?@J%) (RFD) DCSI DCS2 AVG DCS Lmitts D Limit Mercury 15.0 13.4 13.4 13.4 89 63-150 0.0 28 Category: HO-TISSU Mercury by CVAA fur T]saum Testcode: HG-CVAA-TISSUE Method: SW 7471-M Matrix: TISSUE Concentration Units: mg/kg QC Lot: 29 AUG 96-OX Analyzed Date: Time: ----Concentrauan------- Accuracy Precision Analyte Spiked -----ft&3urnd----- Avaraga(q� (tRPO p DCS1 DCS2 AVG OCS Limits DC S Limit This is a Lot Identifier. An LCS was performed instead of a OCS. Calculations are performed before rounding to avoid round-off errors to calculated results. 9T' d 800' oN TT:OT 96.£0 130 Z689-9V9-b0L:0I 87Hd3 NE-idWdHb