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Home My WebLink AboutWQ0035720_Residual Annual Report 2020_20210204Initial Review Reviewer Thornburg, Nathaniel Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application what is the submittal type?* Annual Report Year* Permit Number (IR)* Applicant/Permittee Email Notifications ........................................................................................................................................................................ Does this need review by the hydrogeologist?* Regional Office CO Reviewer Admin Reviewer * Annual Report * Residual Annual Report r Additional Information r Other 2020 WQ0035720 Denali Water Solutions, LLC r Yes c No Submittal Form Project Contact Information Rease provide information on the person to be contacted by N B Staff Name * Jeff J Retzke Email Address* jeff.retzke@denalivvater.com electronic subnittal, confirmation of receipt, and other correspondence. Project Information ........ ......... ............................................................................................................................... . Application/Document Type* r New (Fee Req ui red) r Modification - Major (Fee Required) r Renewal with Major Modification (Fee Required) r Annual Report r Additional Information r Other Phone Number* 2565034300 O Modification - Minor C Renewal C GW-59, NDMR, NDMLR, NDAR-1, NDAR-2 r Residual Annual Report r Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* r Wastewater Irrigation r High -Rate Infiltration r Other Wastewater r Reclaimed Water r Closed -Loop Recycle r Residuals r Single -Family Residence Wastewater r Other Irrigation Permit Number:* W00035720 Fbs Current Existing permt number Applicant/Permittee Address* 3308 Bernice Avenue, Russellville, AR 72811 Facility Name * Denali Water Solutions DCAR Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here.* (Application Form Engineering Rans, Specifications, Calculations, Bc.) WQ0035720- 2020 Lake Kilby WTP annual report.pdf 1.24MB Upload only 1 FLFdocurrent (less than 2501vB). Miltiple documents mist be combined into one FDFfile unless file is larger than upload limit. * V By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non - Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/4/2021 0 Dena I i WATER SOLUTIONS February 4, 2021 3308 Bernice Avenue Russellville, AR 72802 PO Box 3036 • Russellville, AR 72811 Phone: 479-498-0500 North Carolina Department of Environment and Natural Resources Division of Water Quality Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: 2020 Annual Report - Distribution of Class A Residuals: Denali Water Solutions (Lake Kilby Water Treatment Plant) Permit No. WQ0035720 To Whom it May Concern: Denali Water Solutions is submitting the required 2020 Annual Report for Permit No. WQ0035720. This permit is associated with the distribution of water treatment residuals produced at the City of Portsmouth - Lake Kilby Water Treatment Plant located in Suffolk, Virginia, with distribution in Gates County, North Carolina. This Annual Report contains the following information: • Form DMSDF • Form RSSF • Lab Reports If you have any questions, or need any additional information, please do not hesitate to contact me at (256) 503-4300 or via email at jef£retzkePdenaliwater.com. Sincerely, Jeff Retzke Senior Environmental Manager, East Region cc: Nathan Litteral (Water Plant Manager, City of Portsmouth, Virginia) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: WQ0035720 FACILITY NAME: Lake Kilby Water Treatment Plant PHONE: 336-266-9134 COUNTY: Suffolk, VA OPERATOR: Nathan Litteral (Water Plant Manager) FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) 0 Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? Yes 0 No ❑ o If No skip parts A, B, C and certify form below Part A*• Part B*• Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January February March April May June July August September October Lake Kilby WTP 0 391.68 391.68 See FSF 391.68 Soil Amendment November Lake Kilby WTP 0 558.55 558.55 See FSF 558.55 Soil Amendment December Lake Kilby WTP 0 431.33 431.33 See FSF 431.33 Soil Amendment Total from FORM DMSDF (sup) Totals: Annual (dry tons): 0 1381.56 1381.56 1381.56 Amendment(s) used: I Bulking Agent(s) used: (supp)): Total Number of Form DMSDF (Supp) * If more space is required, attach additional information sheets (FORM DMSDF Part C: Facility was compliant during the past calendar year with all conditions of the land application permit 0 Yes (including but not limited to items 1-3 below) issued by the Division of Water Resources: ❑ No o, If No, Explain in Narritive 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Permittee 9�� Date ignature of Preparer** (if different from Permittee) **Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) 2-4-21 Date DENR FORM DMSDF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0035720 Facility Name: Lake Kilby WTP Residual Source WQ # or NPDES #: WWTP Name: Residual Analvsis Data Laboratory: 1) Waypoint Analytical, Richmond, VA 2) 3) 4) 5) Parameter (mg/kg) Conc. Limit m /k a Sample or Composite Date 10/15/20 10/15/20 11/4/20 11/4/20 Max Percent Solids (%) NA 21.7 18.4 16.3 17.1 21.7 Arsenic 75 6.91 7.77 9.45 9.3 9.45 Cadmium 85 0.461 0.543 0.613 0.585 0.613 Copper 4,300 45.9 35.8 43.3 37.8 45.9 Chromium NA 105 130 148 133 148 Lead 840 9.45 11 16.6 14.2 16.6 Mercury 57 0.0635 0.0847 0.0871 0.0912 0.0912 Molybdenum 75 2.12 1.51 1.53 1.46 2.12 Nickel 420 19 13.9 14.5 13.3 19 Selenium 100 2.3 2.72 5.66 4.49 5.66 Zinc 7,500 113 67.4 84 74.9 113 Total Phosphorus NA 1080 1080 1190 1060 1190 TKN NA 8200 9080 13000 10500 13000 Ammonia -Nitrogen NA 410 212 681 292 681 Nitrate and Nitrite NA 102 27.1 31 31.1 102 " For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 2-4-21 Si�WWture of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) Waypointo ANALYTICAL 10/26/2020 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville, AL, 35801 Ref: Analytical Testing Report Number: 20-290-0002 Project Description: Lake Kilby WTP 2019 1 &2 of 6 Jeff Retzke/ Denali Water 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Jeff Retzke: Waypoint Analytical Virginia, Inc. received sample(s) on 10/16/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-290-0002 Client Project Description: Lake Kilby WTP 2019 1&2 of 6 Jeff Retzke/ Denali Water Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 73967 1 Solids 10/16/2020 73967 1 Solids 10/16/2020 4500NO3F-2011 WP MTN 73967 1 Solids 10/16/2020 SW-7471B WP MTN 73967 1 Solids 10/16/2020 SM-4500-NH3C WP MTN 73967 1 Solids 10/16/2020 6010D WP MTN 73967 1 Solids 10/16/2020 SM-2540G WP MTN 73967 1 Solids 10/16/2020 AOAC 955.01 WP MTN 73967 1 Solids 10/16/2020 9045D WP MTN 73967 1 Solids 10/16/2020 SM-4500-NH3C-TKN WP MTN 73968 2 Solids 10/16/2020 73968 2 Solids 10/16/2020 SM-4500-NH3C-TKN WP MTN 73968 2 Solids 10/16/2020 SM-4500-NH3C WP MTN 73968 2 Solids 10/16/2020 SM-2540G WP MTN 73968 2 Solids 10/16/2020 4500NO3F-2011 WP MTN 73968 2 Solids 10/16/2020 AOAC 955.01 WP MTN 73968 2 Solids 10/16/2020 9045D WP MTN 73968 2 Solids 10/16/2020 SW-7471B WP MTN 73968 2 Solids 10/16/2020 6010D WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 8 • 7621 0 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-290-0002 Lab No : 73967 Sample ID : 1 Project Lake Kilby WTP 2019 1&2 of 6 Report Date : 10/26/2020 Information : Jeff Retzke/ Denali Water Received : 10/16/2020 REPORT OFANALYSIS Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 78.3 % 0.010 1 10/21/20 16:53 CJR SM-2540G Calcium Carbonate Equivalent 5.9 % - dry 0.1 1 10/21/20 13:00 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 410 mg/Kg - dry 115 1 10/23/20 14:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N 102 mg/Kg - dry 22.4 1 10/21/20 14:41 ZBD 4500NO3F-2011 Organic N 7790 mg/Kg - dry 1150 1 10/23/20 10:00 CALCULATION pH 6.8 S.U. 1 10/22/2015:04 ADM 9045D Total Solids 21.7 % 0.010 1 10/21/20 16:53 CJR SM-2540G Total Volatile Solids 47.5 % 0.010 1 10/21/20 16:53 CJR SM-2540G Total Kjeldahl Nitrogen 8200 mg/Kg - dry 1150 1 10/23/20 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 1080 mg/Kg - dry 23.0 1 10/22/20 02:31 JTR 6010D Aluminum 163000 mg/Kg - dry 115 5 10/23/20 00:09 JTR 6010D Arsenic 6.91 mg/Kg - dry 2.30 1 10/22/20 02:31 JADS 6010D Calcium 2890 mg/Kg - dry 230 1 10/22/20 02:31 JTR 6010D Cadmium <0.461 mg/Kg - dry 0.461 1 10/22/20 02:31 JADS 6010D Chromium 105 mg/Kg - dry 1.15 1 10/22/20 02:31 JADS 6010D Copper 45.9 mg/Kg - dry 2.30 1 10/23/20 00:04 JTR 6010D Iron 21800 mg/Kg - dry 46.1 1 10/22/20 02:31 JTR 6010D Lead 9.45 mg/Kg - dry 1.38 1 10/22/20 02:31 JADS 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 3 of 8 • 0 Waypoint 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 07274 Denali Water Project Lake Kilby WTP 2019 1&2 of 6 Jeff Retzke Report Date : 10/26/2020 1001 Fraser Ave Information : Jeff Retzke/ Denali Water Received : 10/16/2020 Huntsville , AL 35801 '�awl �. "� k' 0 I-ly Pauric Mc Groary Ph.D., CPA Report Number : 20-290-0002 REPORT OFANALYSIS Agronomist Lab No : 73967 Matrix: Solids Sample ID : 1 Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Magnesium 544 mg/Kg - dry 23.0 1 10/22/20 02:31 JADS 6010D Manganese 5070 mg/Kg - dry 11.5 5 10/23/20 00:09 JTR 6010D Mercury <0.0635 mg/Kg - dry 0.0635 1 10/21/20 13:08 DDB SW-7471B Molybdenum 2.12 mg/Kg - dry 1.15 1 10/22/20 02:31 JADS 6010D Nickel 19.0 mg/Kg - dry 1.15 1 10/22/20 02:31 JADS 6010D Potassium 119 mg/Kg - dry 46.1 1 10/22/20 02:31 JTR 6010D Selenium <2.30 mg/Kg - dry 2.30 1 10/23/20 00:04 JTR 6010D Sodium 239 mg/Kg - dry 115 1 10/22/20 02:31 JADS 6010D Zinc 113 mg/Kg - dry 5.76 1 10/22/20 02:31 JADS 6010D Sulfur 10600 mg/Kg - dry 46.1 1 10/22/20 02:31 JTR 6010D Sodium Absorption Ratio <23.0 mg/Kg - dry 23.0 1 10/22/20 02:31 CALCULATION Qualifiers/ DF Dilution Factor Definitions MQL Method Quantitation Limit L Limit Exceeded Page 4 of 8 • 7621 0 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-290-0002 Lab No : 73968 Sample ID : 2 Project Lake Kilby WTP 2019 1&2 of 6 Report Date : 10/26/2020 Information : Jeff Retzke/ Denali Water Received : 10/16/2020 REPORT OFANALYSIS Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 81.6 % 0.010 1 10/21/20 16:53 CJR SM-2540G Calcium Carbonate Equivalent 4.9 % - dry 0.1 1 10/21/20 13:00 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 212 mg/Kg - dry 136 1 10/23/20 14:00 JPJ SM-4500-NH3C Nitrate+Nitrite-N <27.1 mg/Kg - dry 27.1 1 10/21/20 14:42 ZBD 4500NO3F-2011 Organic N 8860 mg/Kg - dry 1360 1 10/23/20 10:00 CALCULATION pH 6.7 S.U. 1 10/22/2015:04 ADM 9045D Total Solids 18.4 % 0.010 1 10/21/20 16:53 CJR SM-2540G Total Volatile Solids 49.0 % 0.010 1 10/21/20 16:53 CJR SM-2540G Total Kjeldahl Nitrogen 9080 mg/Kg - dry 1360 1 10/23/20 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 1080 mg/Kg - dry 27.2 1 10/22/20 02:46 JTR 6010D Aluminum 189000 mg/Kg - dry 136 5 10/23/20 00:18 JTR 6010D Arsenic 7.77 mg/Kg - dry 2.72 1 10/22/20 02:46 JADS 6010D Calcium 1780 mg/Kg - dry 272 1 10/22/20 02:46 JTR 6010D Cadmium <0.543 mg/Kg - dry 0.543 1 10/22/20 02:46 JADS 6010D Chromium 130 mg/Kg - dry 1.36 1 10/22/20 02:46 JADS 6010D Copper 35.8 mg/Kg - dry 2.72 1 10/23/20 00:13 JTR 6010D Iron 23300 mg/Kg - dry 54.3 1 10/22/20 02:46 JTR 6010D Lead 11.0 mg/Kg - dry 1.63 1 10/22/20 02:46 JADS 6010D Qualifiers/ DF Dilution Factor L Limit Exceeded Definitions MQL Method Quantitation Limit Page 5 of 8 • 0 Waypoint 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com 07274 Denali Water Project Lake Kilby WTP 2019 1&2 of 6 Jeff Retzke Report Date : 10/26/2020 1001 Fraser Ave Information : Jeff Retzke/ Denali Water Received : 10/16/2020 Huntsville , AL 35801 '�awl �. "� k' 0 I-ly Pauric Mc Groary Ph.D., CPA Report Number : 20-290-0002 REPORT OFANALYSIS Agronomist Lab No : 73968 Matrix: Solids Sample ID : 2 Sampled: Test Results Units MQL DF Date / Time By Analytical Analyzed Method Magnesium 679 mg/Kg - dry 27.2 1 10/22/20 02:46 JADS 6010D Manganese 2230 mg/Kg - dry 2.72 1 10/22/20 02:46 JTR 6010D Mercury <0.0847 mg/Kg - dry 0.0847 1 10/21/20 13:09 DDB SW-7471B Molybdenum 1.51 mg/Kg - dry 1.36 1 10/22/20 02:46 JADS 6010D Nickel 13.9 mg/Kg - dry 1.36 1 10/22/20 02:46 JADS 6010D Potassium 114 mg/Kg - dry 54.3 1 10/22/20 02:46 JTR 6010D Selenium <2.72 mg/Kg - dry 2.72 1 10/23/20 00:13 JTR 6010D Sodium 274 mg/Kg - dry 136 1 10/22/20 02:46 JADS 6010D Zinc 67.4 mg/Kg - dry 6.79 1 10/22/20 02:46 JADS 6010D Sulfur 13100 mg/Kg - dry 54.3 1 10/22/20 02:46 JTR 6010D Sodium Absorption Ratio <27.2 mg/Kg - dry 27.2 1 10/22/20 02:46 CALCULATION Qualifiers/ DF Dilution Factor Definitions L Limit Exceeded Page 6 of 8 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 07274 Customer Name: Denali Water Report Number: 20-290-0002 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes ® No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes ® No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: ISamantha Clarke Date & Time: 10/16/2020 11:43:17 Page 7 of 8 SAMPLE ¢�z 7621 Whitepine Road Richmond V, Denali water 11.40.43 TSTQDY upportale aleastcm.com Account # Lake KitbV W 1 P LaIS IbL i Submitted By a Copy To L Jeff Retake/Denali Water 20: DEW jeff.retzkeadenaliwater.com 3308 Bernice Avenue Jeff's Cell: 256.503.4300 Russellville, AR 72802 Project Lake Kilby WTP 2019 1&2 0 6 Sample Information Lab Number Collection information Container Information Please Check Desired Tests Number 503 Nitrogen Volatile Sample 10 (Lab Use Only) Type Date Time of Bottles Type Volume SL1 SL2 Metals Series pH CCE Ag Cl Solids others Grab Standard Compoa 1 _ + _ Glass x X pint w/Aluminum, CCE Composite Plastic qt and S.A.R. ~ r ` Grab % 1 _ Glass x az pint same as above x Plastic Cam osite Grab Glass 02 Plastic pint Composite qt Grab Glass — — Oz — Plastic pint Composite Relin ui d B (Signature) Date Jime Received B (Signature) bate Time Test Package Detailils Special Instructions or Remarks SL1: Total Solids (Moisture) Total K.leldahl Nitrogen, phosphorus and Potassium SL2: 9asic Test SL I plus Sulfur, Calcium, Magpesium,5odium_ Iron, Aluminum, Manganese, Copper And Zinc 503 Metals: Arsenic, Cadmium, Chromium, Mercury, Molybdenum. Lead, Nickel, Selenium. (Copper & Zinc included in SL2) ice Nitrogen Series: total k1eldahl. Ammonium, Nitrate & OrWic Nitrogen CCE: Calcium Carbonate Equivalent or Total neutralization Value (For Lime Treated Sludge) Waypointo ANALYTICAL 11 /16/2020 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville, AL, 35801 Ref: Analytical Testing Report Number: 20-310-0005 Project Description: Lake Kilby WTP 2019 5&6 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Jeff Retzke: Waypoint Analytical Virginia, Inc. received sample(s) on 11/5/2020 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 • 7621 Whitepine Road, Richmond, VA 23237 Waypoint Main 804-743-9401 0 Fax 804-271-6446 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 20-310-0005 Client Project Description: Lake Kilby WTP 2019 5&6 Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74112 5 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 74113 6 Solids 11/04/2020 11:40 11/05/2020 4500NO3F-2011 WP MTN SW-7471B WP MTN SM-4500-NH3C WP MTN 6010D WP MTN SM-2540G WP MTN AOAC 955.01 WP MTN 9045D WP MTN SM-4500-NH3C-TKN WP MTN SM-4500-NH3C-TKN WP MTN SM-4500-NH3C WP MTN SM-2540G WP MTN 4500NO3F-2011 WP MTN AOAC 955.01 WP MTN 9045D WP MTN SW-7471B WP MTN 6010D WP MTN WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN Page 2 of 8 Waypointo ANALYTICAL 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-310-0005 Lab No : 74112 Sample ID : 5 Project Information 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Lake Kilby WTP 2019 5&6 REPORT OFANALYSIS Report Date : 11/16/2020 Received : 11/05/2020 Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: 11/ 4/ 2020 11:40 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 83.7 % 0.010 1 11/09/20 17:05 FMM SM-2540G Calcium Carbonate Equivalent 9.7 % - dry 0.1 1 11/09/20 10:25 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 681 mg/Kg - dry 153 1 11/12/20 14:30 JPJ SM-4500-NH3C Nitrate+Nitrite-N <31.0 mg/Kg - dry 31.0 1 11/12/20 15:47 CLP 4500NO3F-2011 Organic N 12300 mg/Kg - dry 1530 1 11/12/20 10:00 CALCULATION pH 6.7 S.U. 1 11/09/2016:44 ADM 9045D Total Solids 16.3 % 0.010 1 11/09/20 17:05 FMM SM-2540G Total Volatile Solids 51.8 % 0.010 1 11/09/20 17:05 FMM SM-2540G Total Kjeldahl Nitrogen 13000 mg/Kg - dry 1530 1 11/12/20 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 1190 mg/Kg - dry 30.7 1 11/12/20 00:10 TJS 6010D Aluminum 96300 mg/Kg - dry 307 10 11/12/20 19:06 TJS 6010D Arsenic 9.45 mg/Kg - dry 3.07 1 11/12/20 00:10 TJS 6010D Calcium 1500 mg/Kg - dry 307 1 11/12/20 00:10 TJS 6010D Cadmium <0.613 mg/Kg - dry 0.613 1 11/12/20 00:10 TJS 6010D Chromium 148 mg/Kg - dry 1.53 1 11/12/20 00:10 TJS 6010D Copper 43.3 mg/Kg - dry 3.07 1 11/12/20 00:10 TJS 6010D Iron 22900 mg/Kg - dry 61.3 1 11/12/20 00:10 TJS 6010D Lead 16.6 mg/Kg - dry 1.84 1 11/12/20 00:10 TJS 6010D Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions L Limit Exceeded MQL Method Quantitation Limit Page 3 of 8 Waypointo ANALYTICAL 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-310-0005 Lab No : 74112 Sample ID : 5 Project Information 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Lake Kilby WTP 2019 5&6 REPORT OFANALYSIS Report Date : 11/16/2020 Received : 11/05/2020 Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: 11/ 4/ 2020 11:40 Test Results Units MQL DF Date / Time Analyzed By Analytical Method Magnesium 724 mg/Kg - dry 30.7 1 11/12/20 00:10 TJS 6010D Manganese 2360 mg/Kg - dry 3.07 1 11/12/20 00:10 TJS 6010D Mercury <0.0871 mg/Kg - dry 0.0871 1 11/10/20 12:42 DDB SW-7471B Molybdenum <1.53 mg/Kg - dry 1.53 1 11/12/20 00:10 TJS 6010D Nickel 14.5 mg/Kg - dry 1.53 1 11/12/20 00:10 TJS 6010D Potassium 125 mg/Kg - dry 61.3 1 11/12/20 00:10 TJS 6010D Selenium 5.66 mg/Kg - dry 3.07 1 11/12/20 00:10 TJS 6010D Sodium 291 mg/Kg - dry 153 1 11/12/20 00:10 TJS 6010D Zinc 84.0 mg/Kg - dry 7.67 1 11/12/20 00:10 TJS 6010D Sulfur 14800 mg/Kg - dry 61.3 1 11/12/20 00:10 TJS 6010D Sodium Absorption Ratio <5.00 Ratio 5.00 1 11/12/20 00:10 CALCULATION Qualifiers/ B Analyte detected in blank Definitions L Limit Exceeded DF Dilution Factor MQL Method Quantitation Limit Page 4 of 8 Waypointo ANALYTICAL 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-310-0005 Lab No : 74113 Sample ID : 6 Project Information 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Lake Kilby WTP 2019 5&6 REPORT OFANALYSIS Report Date : 11/16/2020 Received : 11/05/2020 Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: 11/ 4/ 2020 11:40 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Moisture 82.9 % 0.010 1 11/09/20 17:05 FMM SM-2540G Calcium Carbonate Equivalent 9.2 % - dry 0.1 1 11/09/20 10:25 DXT AOAC 955.01 Test Results Units MQL DF Date / Time By Analytical Analyzed Method Ammonia Nitrogen 292 mg/Kg - dry 146 1 11/12/20 14:30 JPJ SM-4500-NH3C Nitrate+Nitrite-N 31.1 mg/Kg - dry 30.1 1 11/12/20 15:48 CLP 4500NO3F-2011 Organic N 10200 mg/Kg - dry 1460 1 11/12/20 10:00 CALCULATION pH 6.7 S.U. 1 11/09/2016:44 ADM 9045D Total Solids 17.1 % 0.010 1 11/09/20 17:05 FMM SM-2540G Total Volatile Solids 52.4 % 0.010 1 11/09/20 17:05 FMM SM-2540G Total Kjeldahl Nitrogen 10500 mg/Kg - dry 1460 1 11/12/20 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 1060 mg/Kg - dry 29.2 1 11/12/20 00:15 TJS 6010D Aluminum 90600 mg/Kg - dry 292 10 11/12/20 19:11 TJS 6010D Arsenic 9.30 mg/Kg - dry 2.92 1 11/12/20 00:15 TJS 6010D Calcium 1350 mg/Kg - dry 292 1 11/12/20 00:15 TJS 6010D Cadmium <0.585 mg/Kg - dry 0.585 1 11/12/20 00:15 TJS 6010D Chromium 133 mg/Kg - dry 1.46 1 11/12/20 00:15 TJS 6010D Copper 37.8 mg/Kg - dry 2.92 1 11/12/20 00:15 TJS 6010D Iron 20300 mg/Kg - dry 58.5 1 11/12/20 00:15 TJS 6010D Lead 14.2 mg/Kg - dry 1.75 1 11/12/20 00:15 TJS 6010D Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions L Limit Exceeded MQL Method Quantitation Limit Page 5 of 8 Waypointo ANALYTICAL 07274 Denali Water Jeff Retzke 1001 Fraser Ave Huntsville , AL 35801 Report Number : 20-310-0005 Lab No : 74113 Sample ID : 6 Project Information 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Lake Kilby WTP 2019 5&6 REPORT OFANALYSIS Report Date : 11/16/2020 Received : 11/05/2020 Pauric Mc Groary Ph.D., CPA Agronomist Matrix: Solids Sampled: 11/ 4/ 2020 11:40 Test Results Units MQL DF Date / Time Analyzed By Analytical Method Magnesium 655 mg/Kg - dry 29.2 1 11/12/20 00:15 TJS 6010D Manganese 2110 mg/Kg - dry 2.92 1 11/12/20 00:15 TJS 6010D Mercury <0.0912 mg/Kg - dry 0.0912 1 11/10/20 12:44 DDB SW-7471B Molybdenum <1.46 mg/Kg - dry 1.46 1 11/12/20 00:15 TJS 6010D Nickel 13.3 mg/Kg - dry 1.46 1 11/12/20 00:15 TJS 6010D Potassium 116 mg/Kg - dry 58.5 1 11/12/20 00:15 TJS 6010D Selenium 4.49 mg/Kg - dry 2.92 1 11/12/20 00:15 TJS 6010D Sodium 271 mg/Kg - dry 146 1 11/12/20 00:15 TJS 6010D Zinc 74.9 mg/Kg - dry 7.31 1 11/12/20 00:15 TJS 6010D Sulfur 13200 mg/Kg - dry 58.5 1 11/12/20 00:15 TJS 6010D Sodium Absorption Ratio <5.00 Ratio 5.00 1 11/12/20 00:15 CALCULATION Qualifiers/ B Analyte detected in blank Definitions DF Dilution Factor Page 6 of 8 WayPAoInt.. NALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Shipment Receipt Form Customer Number: 07274 Customer Name: Denali Water Report Number: 20-310-0005 Shipping Method 0 Fed Ex 0 US Postal 0 Lab ® UPS 0 Client 0 Courier 0 Other: Thermometer ID: Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F-71 Custody seals intact on shipping container/cooler? 0 Yes 0 No ! Not Present Custody seals intact on sample bottles? 0 Yes 0 No ® Not Present Chain of Custody (COC) present? 0 Yes 0 No COC agrees with sample label(s)? 0 Yes 0 No COC properly completed 0 Yes 0 No Samples in proper containers? 0 Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? 0 Yes 0 No All samples received within holding time? 0 Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. 0 Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No ® N/A Water - VOA vials free of headspace 0 Yes 0 No ® N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes ® No Comments: Signature: lBrandi Watson Date & Time: 11/05/2020 13:34:49 Page 7 of 8 SAMPLE Tl 7621 Whitepine Road Richmond VA 2 I IIII I III I IIIi llllll l 111111111111111 III I IIIII III IIII IIII 274 Denali Water 13.30:27 Lake Kilhy WTP 2019 5&6 3TODY pportal e(o al east ern. c om Account # Submitted By Charge To Copy To PO: DEW jeff.retzke@denaliwater.com Jeff RetzkelDenali Water 3308 Bernice Avenue Jeff's Cell: 256.503.4300 Russellville, AR 72802 Project Lake Ki lby WTP 2019 & o f 6 :3am le Information Lab Number Collection Information Container Information Please Check Desired Tests Sample ID (Lab Use only) Type mate Time Number Type Volume SL1 SL2 503 Nitrogen pH CCE Ag Cl Volatile Others of Bottles Metals Series Solids �4111 Grab r 1 Glass oz mint S r. arlJa rc :'ompo wlAlutninum, CCE f 1 I �O J� x Plastic y Composite I qt and S.A.R. �1 Grab ELF. 1 1 _ Glass Plastic oz x int Same as above Cam site 1 1 Grab Glass oz Plastic Int composite qt Grab Glass oz Plastic pint Composite qt l uuis (Signature) Date Time Received 8 : (Signature) Date Time OK's L Test Packa a Details Special Instructions or Remarks SLI: Total Solids (Moisture) Total Kieldahl Nitrogen, Phosphorus and Potassium SL2: Basic Test SLI plus Sulfur. Calcium, Magn aium Sodium, Iron, Aluminum, Manganese, Copper And Zinc 19 503 Metals: Arsenic, Cadmium, Chromium, Mercury, Molybdenum, Lead, Nickel, Selenium. (Copper & Zinc included in SL2) Nitrogen Series: Total Kieldahl, Ammonium, Nitrate & Organic Nitrogen. CCE: Calcium Carbonate Equivalent or Total neutralization Value (For Lime Treated Sludge)