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HomeMy WebLinkAbout20070812 Ver 1_Draft Dissolved Oxygen MP 2007_20070510b~os~2 Yadkin Project (FERC No. 2197) Draft Dissolved Oxygen Monitoring Plan Alcoa Power Generating Inc. May 2007 0 ALCOA Licensee Contact: Gene Ellis APGI, Yadkin Division P.O. Box 576 Badin, NC 28009 (704) 422-5606 gene.ellis@alcoa.com ~, ~r~ MAY 1 C' 200; ~r,'~,''~R G?,~a..,7'~' Table of Contents Table of Contents List of Tables ....., List of Figures ..... Acronyms ............ 1 Introduction .............................................................................................. . 1.1 Project Description .......................................................................... 1.2 Background ..................................................................................... 1.3 Purpose of the Dissolved Oxygen Monitoring Plan ....................... 1.4 Dissolved Oxygen Monitoring Plan Development ......................... 2 Background on Continuous Tailwater Monitoring at the Yadkin Project 3 Continuous Dissolved Oxygen Monitoring .............................................. 3.1 Monitoring Locations ...................................................................... 3.2 Methods ........................................................................................... 4 Unit Aeration Technology Evaluation ...................................................... 5 Quality Control/Quality Assurance Procedures ........................................ 6 Schedule, Implementation, Reporting ....................................................... 6.1 Continuous Dissolved Oxygen Monitoring Schedule ..................... 6.2 Aeration Technology Evaluation .................................................... 7 References ................................................................................................. Appendices Appendix A: Quality Assurance Project Plan Appendix B: Summary of Consultation Appendix C: Consultation Record Appendix D: Comments Received on Draft Dissolved Oxygen Monitoring Plan and APGI's Responses ..i . ii iii iv .1 .l .1 .1 .2 .4 .5 .5 .5 11 13 14 14 14 15 Yadkin Project i Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 List of Tables Table 1: DO Monitoring Plan Specified Instrument Site Locations ............................................... 5 Table 2: Schedule for Continuous Dissolved Oxygen Monitoring ............................................... 14 Yadkin Project ii Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 List of Figures Figure 1: Yadkin Project Regional Locus Map .............................................................................. 3 Figure 2: Location of High Rock Tailwater Continuous Monitoring Instrument ........................... 7 Figure 3: Location of Tuckertown Tailwater Continuous Monitoring Instrument ......................... 8 Figure 4: Location of Narrows Tailwater Continuous Monitoring Instrument .............................. 9 Figure 5: Location of Falls Tailwater Continuous Monitoring Instrument .................................. 10 Yadkin Project iii Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Acronyms APGI DO FERC Licensee NCDWQ NCDWR NCWRC Plan Project QAPP USEPA USFWS Yadkin Yadkin Project Yadkin Project FERC No. 2197 Alcoa Power Generating Inc. or Licensee Dissolved Oxygen Federal Energy Regulatory Commission Alcoa Power Generating Inc. (APGI) North Carolina Division of Water Quality North Carolina Division of Water Resources North Carolina Wildlife Resources Commission Dissolved Oxygen Monitoring Plan Yadkin Project or Yadkin Hydroelectric Project (FERC No. 2197) Quality Assurance Project Plan U.S. Environmental Protection Agency U.S Fish and Wildlife Service Yadkin Division of Alcoa Power Generating Inc. Yadkin Hydroelectric Project (FERC No. 2197) or Project iv Draft Dissolved Oxygen Monitoring Plan May 2007 1 Introduction 1.1 Project Description The Yadkin Hydroelectric Project (Yadkin Project or Project) is owned by Alcoa Power Generating Inc. (APGI), awholly-owned subsidiary of Alcoa Inc. (Alcoa). APGI's Yadkin Division (Yadkin) is responsible for operation of the Project. The Yadkin Project includes four hydroelectric developments, the High Rock, Tuckertown, Narrows and Falls developments, which are located on a 38-mile stretch of the Yadkin River (see Figure 1). High Rock, the most upstream development, is located at mile 253 on the Yadkin River and serves as the principal storage facility for the entire Yadkin-Pee Dee River. The Tuckertown, Narrows, and Falls developments are located approximately 8.7 miles, 16.5 miles, and 19.0 miles downstream, respectively, of the High Rock Development. The Yadkin Project is located approximately 60 miles northeast of Charlotte on the Yadkin River in Davidson, Davie, Montgomery, Rowan, and Stanly counties in central North Carolina. The Yadkin River and its tributaries are part of the Yadkin-Pee Dee River Basin, which extends from the eastern slopes of the Blue Ridge Mountains to the Atlantic coast near Georgetown, South Carolina. The Yadkin River's name changes to the Pee Dee River at its confluence with the Uwharrie River. The Pee Dee River continues its southeastern flow to Winyah Bay, where it meets the Atlantic Ocean. 1.2 Background The Yadkin Project is licensed by the Federal Energy Regulatory Commission (FERC No. 2197). On ,the North Carolina Division of Water Quality (NCDWQ) issued a water quality certification for the Yadkin Project under Section 401 of the Clean Water Act. On APGI received a new license for the Project from FERC. In accordance with the conditions of the 401 Water Quality Certification and the FERC License (Article X), APGI is required to prepare a Dissolved Oxygen (DO) Monitoring Plan (Plan) and a Quality Assurance Project Plan (QAPP) for the Project, and to monitor dissolved oxygen and temperature conditions in accordance with the specifications of the DO Monitoring Plan and the QAPP. The QAPP is located in Appendix A of this DO Monitoring Plan. 1.3 Purpose of the Dissolved Oxygen Monitoring Plan The purpose of the Yadkin Project DO Monitoring Plan is to monitor ongoing dissolved oxygen and temperature conditions in the four Yadkin Project tailwaters and to allow an assessment of changes to tailwater DO concentrations that occur as aeration equipment is installed and DO enhancement measures undertaken at the Project, in accordance with the conditions of the 401 Water Quality Certification issued by NCDWQ for the Yadkin Project. The 401 Water Quality Certification outlines the schedule for the installation of the aeration equipment designed to increase tailwater DO concentrations and enhance water quality in the four Project development tailwaters. The DO enhancement program is designed to meet water quality standards for DO Yadkin Project 1 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 downstream of each of the hydro developments. The DO enhancement program will first address DO concentrations below the Narrows and High Rock developments, and then monitor these results to determine what DO enhancements might be needed in the tailwaters of the Tuckertown and Falls developments. 1.4 Dissolved Oxygen Monitoring Plan Development On , a Draft Dissolved Oxygen Monitoring Plan and QAPP were distributed to NCDWQ, North Carolina Division of Water Resources (NCDWR), North Carolina Wildlife Resources Commission (NCWRC), U.S. Environmental Protection Agency (USEPA), and the U.S Fish and Wildlife Service (USFWS) for comment and review. Comments were requested by Comments were received from A complete record of this consultation is provided in Appendices B, C, and D. Yadkin Project 2 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Figure 1: Yadkin Project Regional Locus Map -_ ~`~,(h aP ~QiL ~ ,'" ., ~ ~, i - , ~ ~, r~ - ~~~ ~atis;bu ~ ~ ~'i ~ ~~~~ / 52 ~ ~ ,.-~~I .. ,~ _ ~ f ~/ t J -__- i,; i'~ -- kligh Rock {~~ ~~ _ ~'~ r ~ ' Reservgir ! Y ,~ ! 1 High Rock-~ I g ~ , 1 ~~ Darn ~ j ... , r ~ i ~ - -- ~ ~~ ~/~~ Tytke~rtow ~' _ ~ ~ _ ~ ~ r" ,t ~~ 1 ~ ~ `Res rvoiJ . d' ~~ 111 J '~ 1 - as ~ ~ , i ~ i / _ r R wan Coon( ~ r. _ ti .___~ ~__..~;.~-i-___. _ _ -_._ i _ ~ ~~ .~ q ~.me ~Coun~y~ if ~ l f ~, ~ 52 "~ , / ~` ~\ ~__ Tuckertavn ~ ~' ~, ~ °- .,/~ r ' , ~ ~~// ~, /~}-~ r / Rese?~oir ~ _. - -- i ~, 49 i~ ,:~ ~ ~~~~ ~ Dam ~~ ~ 1 ~~'`'~ ~ , Ba. - ~~ , ~ / /r ~ ~ _ Falk Dem F~ ~ ~~ ~a - - ~/ ~ J `~ ~. 73 ~" - %h~,~. , 740 ~F^~, I ~ ~~/ 6 J ~~ L 1~ ~~ ~ ~ ~ _~ ~_. ~~A9ou rn ;~' c` i Stat Park t f.,,_ ' ._ _ ~~ Q ~>.5. - li«~cd FERC Buunduy J, R..« and sus Regional Locus Map ~ , Highways _ ~~ hLjarRoads } adkln Project '~~ __._ ca~a.• ea~aai<a O Orhm Arcas N j Lakes W~E I 5 ~ ~ Mazch 2006 0~ z 4 s s io AAA es Yadkin Project 3 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 2 Background on Continuous Tailwater Monitoring at the Yadkin Project In August 2001, APGI filed a Dissolved Oxygen Plan developed as required by FERC Order dated August 2, 2000. FERC's Order approved APGI's license amendment request and amended the FERC License for the Project to reflect changes in the Project associated with proposed generating unit upgrades. To address concerns regarding the potential effects of the proposed unit upgrades on Project water quality, FERC included Article 39 in the amended license requiring a DO Plan to assess the effect of the generating unit upgrades on DO concentrations below the Project developments and, if necessary for compliance with state water quality standards, to develop and implement measures to improve tailwater DO conditions. Since 2001, APGI has been operating continuous dissolved oxygen and temperature monitors in the Narrows and Falls tailwaters from May 1 through November 30 of each year. The monitoring instruments were located to provide a representative sample of DO concentrations throughout each of the tailwater areas. To confirm the representativeness of the current monitor locations, APGI conducted several field surveys designed to examine the lateral and longitudinal change in tailwater DO conditions and to determine if the monitor locations were indicative of overall tailwater conditions. Results of these studies demonstrated that both monitoring instruments are located in areas that are generally representative of overall tailwater conditions (NAI, 2005). Beginning in 2003, continuous tailwater DO and temperature monitoring instruments were added to the Tuckertown and High Rock tailwaters. The representativeness of these instrument locations within the tailwaters was also evaluated through field investigations by APGI (NAI, 2005). Yadkin Project 4 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 3 Continuous Dissolved Oxygen Monitoring 3.1 Monitoring Locations One site in each of the four Project tailwaters (High Rock, Tuckertown, Narrows, Falls) will be monitored. The locations of each monitoring instrument will be the same year to year (see Table 1 and Figures 2-5) unless other conditions require the evaluation of a new location for placement either on a temporary or permanent basis. However, no change in instrument location will occur without consultation with NCDWQ. Table 1: DO Monitoring Plan Specified Instrument Site Locations Tailwater Latitude Longitude High Rock N35 35 48.279 W 80 13 54.184 Tuckertown N 35 29 01.739 W 80 10 21.234 Narrows N 35 25 05.637 W 80 OS 28.767 Falls N 35 23 28.734 W 80 04 14.938 The continuous DO monitoring instruments located in the High Rock, Tuckertown and Falls tailwaters are anchored to buoys and sit approximately one meter below the water surface. The Narrows tailwater instrument is suspended in a pipe anchored to a bridge abutment. The Narrows tailwater instrument is approximately one to four meters below the water surface depending upon discharge from the development. 3.2 Methods YSI 6920 in situ field instruments will be used for the monitoring in each of the monitoring locations. A small boat is required to reach each monitoring location. Once the instruments are deployed and anchored to the existing buoys or pipe at the monitoring locations (see Section 3.1), the instruments will be set to record and store DO and water temperature measurements every 15 minutes for the period May 1 through November 30, annually. Weekly site visits will be made to each instrument to download data, check for fouling, and to calibrate the field instruments in accordance with the manufacturer's specifications and the attached QAPP (Appendix A). The field instruments will be fully serviced and DO membranes will be replaced monthly in accordance with the manufacturer's procedures and the QAPP (Appendix A). At the end of the monitoring season, field instruments will be retrieved, cleaned and stored. The instrument model specified above may be modified, as necessary or desired. However, the Licensee will notify NCDWQ of its intention to change the instrument model before a new model is deployed. Yadkin Project 5 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 If an instrument is lost, stolen, damaged or not functioning properly, it will be replaced with a backup instrument as soon practicable. If at any time APGI or its Monitoring Subcontractor determines conditions in the Yadkin Project tailwaters are unsafe, APGI may at its sole discretion suspend monitoring or related calibration, data retrieval, and downloading activities until conditions are determined to be safe. If APGI determines that it is no longer safe to continue monitoring at a specific location, APGI will notify NCDWQ. The Monitoring Subcontractor will at all times follow APGI's Subcontractor Health and Safety Plan and all applicable safety requirements required by regulating agencies and APGI. Yadkin Project 6 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Yadkin Project 7 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Figure 2: Location of High Rock Tailwater Continuous Monitoring Instrument Yadkin Project 8 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Yadkin Project 9 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Figure 4: Location of Narrows Tailwater Continuous Monitoring Instrument Yadkin Project 10 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 4 Unit Aeration Technology Evaluation APGI plans to undertake a series of Project modifications designed to increase DO concentrations and enhance water quality in the four Project development tailwaters, in accordance with the DO Enhancement Schedule approved by NCDWQ in the 401 Certification for the Yadkin Project (Table X). The continuous tailwater DO monitoring will measure ongoing dissolved oxygen and temperature conditions in the four Yadkin Project tailwaters to allow an assessment of changes to tailwater DO concentrations that occur as aeration equipment is installed at each of the refurbished/upgraded units at the Project developments. The DO enhancement program is designed to meet water quality standards for DO downstream of each of the hydro developments. The DO enhancement program will first address DO concentrations below the Narrows and High Rock developments, and then monitor these results to determine what DO enhancements might be needed in the tailwaters of the Tuckertown and Falls developments. In accordance with the DO enhancement schedule set forth in the 401 Water Quality Certification for the Project, APGI will install aeration technology to Narrows Units 1-3 in conjunction with a planned unit refurbishment/upgrade program followed by a special DO monitoring study (up to a period that includes two summer seasons) to assess the effectiveness of the aeration technology in increasing DO concentrations in the Falls tailwater. At the end of the study, APGI will prepare and file a study report with NCDWQ and FERC. If the special study fails to demonstrate that APGI can operate the Yadkin Project so as to meet state dissolved oxygen standards in the Falls tailwater, APGI shall prepare and file an Action Plan for DO enhancement in the Falls tailwater with NCDWQ and FERC. Similarly, in accordance with the DO enhancement schedule set forth in the 401 Water Quality Certification, APGI will install aeration technology to High Rock Units 1-3 in conjunction with a planned unit refurbishment/upgrade program followed by a special DO monitoring study (up to a period that includes two summer seasons) to assess the effectiveness of the aeration technology in increasing DO concentrations in the Tuckertown tailwater. At the end of the study, APGI will prepare and file a study report with NCDWQ and FERC. If the special study fails to demonstrate that APGI can operate the Yadkin Project so as to meet state dissolved oxygen standards in the Tuckertown tailwater, APGI shall prepare and file an Action Plan for DO enhancement in the Tuckertown tailwater with NCDWQ and FERC. For each of the special DO monitoring studies, the existing locations of the continuous monitoring instruments will be used to evaluate various operating regimes. During each special study, the DO and temperature measurements will be continuously measured every 15 minutes and reviewed in the field in "real time." DO concentrations for each scenario will be recorded throughout the study period or until equilibrium is reached (when three successive DO measurements are within 0.5 mg/1 of each other). Once equilibrium is reached in the tailwater under each operating scenario, real time monitoring will continue for at least two hours. At the end of each day's testing, all data will be downloaded and evaluated to guide the following day's testing. Various test scenarios will be run on successive days. Field instruments will be serviced Yadkin Project 11 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 and calibrated prior to and after testing and checked with an independent instrument at the beginning and end of each test scenario and in conjunction with each data download. In addition to the DO and water temperature data measured from the existing continuous monitoring locations, turbine power output and turbine discharge data will also be needed for each of the special studies. The turbine power output for each powerhouse, measured with existing metering equipment, will be recorded in the APGI Operating Center. Water flow through all turbines will be calculated from power output for the turbine discharge. Yadkin Project 12 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 5 Quality ControUQuality Assurance Procedures In recognition of the requirements for valid and reliable information as the basis for sound management decisions, APGI and its Monitoring Subcontractor will implement a QAPP designed to attain desired quality levels in field and reporting activities. The QAPP was developed in accordance with USEPA guidance documents for QAPPs~ in consultation with NCDWQ in conjunction with this DO Monitoring Plan. The QAPP as approved by NCDWQ is included as Appendix A of this Plan and should be referred to for specific details. ~ USEPA guidance documents used included: USEPA Requirements for Quality Assurance Project Plans (EPA QA/R-5) dated March 2001 and USEPA's Guidance for Quality Assurance Project Plans (EPA QA/G-5) dated December 2002. Yadkin Project 13 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 6 Schedule, Implementation, Reporting 6.1 Continuous Dissolved Oxygen Monitoring Schedule Upon approval of this DO Monitoring Plan and the QAPP located in Appendix A by NCDWQ, APGI will modify the ongoing tailwater monitoring in accordance with this Plan and the QAPP. Tailwater DO and water temperature monitoring will be conducted May 1 through November 30, annually. Final data and an annual report will be filed with NCDWQ and Progress Energy by March 31 of each year for the previous monitoring season. Final data and an annual report will be filed with FERC within 30 days of the filing with NCDWQ. Continuous DO monitoring and data reporting will be conducted in accordance with the schedule outlined in Table 2. Table 2: Schedule for Continuous Dissolved Ox en Monitorin Task Date DO Monitoring Plan and QAPP effective date upon written approval by NCDWQ Begin seasonal DO/water temperature May 1, annually monitoring (measured at 15-minute intervals) Complete DO/water temperature monitoring for November 30, annually the season Provisional data made available upon request to Annually, as requested NCDWQ Final data and annual report filed with NCDWQ By March 31, annually and Progress Energy Final data and annual report filed with FERC Within 30 days of filing with NCDWQ 6.2 Aeration Technology Evaluation In accordance with this Plan (Section 4) and the schedule outlined in the 401 Water Quality Certification for the Yadkin Project, APGI will conduct two special DO monitoring studies (up to two-years each during the summer season following installation of aeration technology at the Narrows and High Rock developments) to evaluate the effectiveness of the aeration technology installed at the Narrows and High Rock developments. At the completion of each study, APGI will prepare and file a study report with NCDWQ and FERC. As discussed in Section 4, if the special studies fail to demonstrate that APGI can operate the Yadkin Project so as to meet state dissolved oxygen standards in the Tuckertown or Falls tailwater, APGI shall prepare and file an Action Plan for DO enhancement for that tailwater with NCDWQ and FERC. Yadkin Project 14 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 7 References Federal Energy Regulatory Commission (FERC). 2000. Order Amending License on Project Number 2197-038. August 2, 2000. Normandeau Associates, Inc. (NAI). 2005. Yadkin Water Quality Final Study Report. August 2005. U.S. Environmental Protection Agency. 2001. EPA Requirements for Quality Assurance Project Plans. EPA QA/R-5. March 2001. U.S. Environmental Protection Agency. 2002. Guidance for Quality Assurance Project Plans. EPA QA/G-5. December 2002. Yadkin Project 15 Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Appendix A Quality Assurance Project Plan Yadkin Project Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Yadkin Project (FERC No. 2197) Tailwater Dissolved Oxygen Monitoring Draft Quality Assurance Project Plan Alcoa Power Generating Inc. May 2007 Al Title and Approval Sheet Yadkin Project (FERC No. 2197) Tailwater Dissolved Oxygen Monitoring Draft Quality Assurance Project Plan Alcoa Power Generating Inc. May 2007 Approved By: Alcoa Power Generating Inc. Project Manager/Project QA Manager Monitoring Subcontractor Project Manager/QA Manager Monitoring Subcontractor Field Manager North Carolina Division of Water Quality QA Officer/Approving Officer Alcoa Power Generating Inc. Yadkin Project (FERC No. 2197) Tailwater DO Monitoring Draft QAPP Date: May 2007 Page 1 of 35 A2 Table of Contents A 1 Title and Approval Sheet ............................................................................ 1 A2 Table of Contents ...................................................................................... .. 2 A3 Distribution List ........................................................................................ .. 4 A4 Project Organization ................................................................................. .. 5 AS Problem Definition/Background ............................................................... .. 7 A.5.1 Background ............................................................................................ ..7 A.5.2 Problem Statement ................................................................................. ..9 A6 Project/Task Description ........................................................................... 11 A7 Quality Objectives and Criteria for Measurement Data ........................... 12 A8 Special Training and Certification ............................................................ 16 A9 Documents and Records ........................................................................... 17 B 1 Sampling Process Design .......................................................................... 19 B2 Sampling Methods .................................................................................... 24 B3 Sample Handling and Custody .................................................................. 24 B4 Analytical Methods ................................................................................... 25 BS Quality Control ......................................................................................... 25 B6 Instrument Testing, Inspection, and Maintenance .................................... 26 B7 Instrument Calibration and Frequency ...................................................... 27 B8 Inspection/Acceptance of Supplies ........................................................... 28 B9 Non-direct Measurements ......................................................................... 28 B 10 Data Management ..................................................................................... 29 C1 Assessments and Response Actions .......................................................... 32 C2 Reports to Management ............................................................................ 32 D1 Data Review, Verification, and Validation ............................................... 33 D2 Verification and Validation Methods ........................................................ 33 D3 Reconciliation with User Requirements ................................................... 34 A u_ _7____ ___~_ Attachment A: Standard Operating Procedures for In Situ Field Instrument Maintenance/Calibration and Data Downloads ...................................... A-1 Attachment B: Standard Operating Procedures for Calibrating YSI 58 Meters used for Comparison with In Situ Field Instruments ............................................ B-1 Attachment C: Procedures for Replacing a Dissolved Oxygen Membrane on In Situ Field Instruments .................................................................................... C-1 Attachment D: DO Calibration Form ............................................................................. D-1 Attachment E: Temperature Check Form ........................................................................E-1 Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 2 of 35 Tailwater DO Monitoring Draft QAPP List of Tables Table 1: Dissolved Oxygen Monitoring Plan Schedule .................................................... 11 Table 2: Data Quality Objectives and Criteria .................................................................. 13 Table 3: DO Monitoring Plan Specified Instrument Site Locations ................................. 19 Table 4: Field Measurement Method and Reporting Levels ............................................ 25 List of Figures Figure 1: Program Organization Chart ............................................................................... 6 Figure 2: Yadkin Project Regional Locus Map .................................................................. 8 Figure 3: Location of High Rock Tailwater Continuous Monitoring Instrument ............. 20 Figure 4: Location of Tuckertown Tailwater Continuous Monitoring Instrument........... 21 Figure 5: Location of Narrows Tailwater Continuous Monitoring Instrument ................ 22 Figure 6: Location of Falls Tailwater Continuous Monitoring Instrument ...................... 23 Figure 7: Data Flow Chart ................................................................................................ 31 Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 3 of 35 Tailwater DO Monitoring Draft QAPP A3 Distribution List This Quality Assurance Project Plan (QAPP) will be distributed to the following agencies and entities with an interest or role in water quality monitoring conducted by Alcoa Power Generating Inc. (APGI or Licensee) for the Yadkin Hydroelectric Project (FERC No. 2197). Gene Ellis, Alcoa Power Generating Inc. Darlene Kucken, North Carolina Division of Water Quality John Dorney, North Carolina Division of Water Quality Todd Ewing, North Carolina Wildlife Resources Commission Ben West, U.S Environmental Protection Agency Steve Reed, North Carolina Division of Water Resources Mark Bowers, U.S. Fish and Wildlife Service Matthew Chan, Normandeau Associates, Inc. Jeff Wollis, Normandeau Associates, Inc. Wendy Bley, Long View Associates, Inc. Joyce Brooks, Long View Associates, Inc. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 4 of 35 Tailwater DO Monitoring Draft QAPP A4 Project Organization The APGI Project Manager is responsible for overseeing all aspects of the continuous dissolved oxygen (DO) monitoring program in the four Yadkin Project (Project) tailwaters, including oversight of the subcontractor collecting the data in accordance with the Dissolved Oxygen Monitoring Plan for the Project and this QAPP. The APGI Project Manager is responsible for reporting data to the North Carolina Division of Water Quality (NCDWQ) as described in Section A6. The APGI Project Manager also acts as the Project QA Manager and is responsible for maintaining the QAPP and Quality Assurance/Quality Control (QA/QC) files. The APGI Project Manager/QA Manager is independent from personnel collecting the data and ensures that the data collected is consistent with this QAPP. Also independent of the data collection process, the APGI Project Manager/QA Manager is responsible for the final review of documentation for the continuous DO and water temperature monitoring QA/QC file. The Monitoring Subcontractor Project Manager/QA Manager is independent of the data collection process and is responsible for the review of data and supporting documentation prior to submittal to the APGI Project Manager/QA Manager. The Monitoring Subcontractor Project Manager/QA Manager oversees the field collection and maintenance of equipment in accordance with this QAPP, the DO Monitoring Plan and all associated Standard Operating Procedures (SOPs). The Monitoring Subcontractor Project Manager/QA Manager is also responsible for reporting data and any equipment/calibration issues to the APGI Project Manager/QA Manager and may reject from reporting due to known equipment/calibration issues. The Monitoring Subcontractor Field Manager is responsible for directly overseeing Monitoring Subcontractor Field Staff and the day-to-day coordination of field collection and equipment maintenance in accordance with this QAPP, the DO Monitoring Plan and all associated SOPs. The Monitoring Subcontractor Field Manager is responsible for reporting any equipment/calibration issues to the Data Processor and for making decisions related to corrective action related to equipment/calibration issues encountered by Monitoring Subcontractor Field Staff. The Monitoring Subcontractor Field Manager also makes recommendations for flagging data due to known equipment/calibration issues. The Monitoring Subcontractor Field Staff are responsible for downloading data and maintenance of equipment and field log books in accordance with this QAPP, the DO Monitoring Plan and all associated SOPS. Field Staff are responsible for reporting any equipment/calibration issues to the Monitoring Subcontractor Field Manager. The downloaded data are processed into an annual database and electronic spreadsheets by the Data Processor. The Data Processor is responsible for reviewing selected portions Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 5 of 35 Tailwater DO Monitoring Draft QAPP of the individual data files and for maintaining records of changes or flagging of data in the database. Several resource agencies have assisted in the development of this monitoring program and QAPP and will serve as Technical Advisors to the program. These include NCDWQ, North Carolina Division of Water Resources (NCDWR), North Carolina Wildlife Resources Commission (NCWRC), U.S. Fish and Wildlife Service (USFWS) and the U.S. Environmental Protection Agency (USEPA). Figure 1: Program Organization Chart APGI Project Manager/QA Manager Monitoring Subcontractor Project Manager/QA Manager Data Processor W Monitoring Subcontractor Field Manager Monitoring Subcontractor Field Staff Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 6 of 35 Tailwater DO Monitoring Draft QAPP A5 Problem Definition/Background A.5.1 Background The Yadkin Project is owned by APGI, awholly-owned subsidiary of Alcoa Inc. (Alcoa). APGI's Yadkin Division (Yadkin) is responsible for operation of the Yadkin Project. The Yadkin Project includes four hydroelectric developments, the High Rock, Tuckertown, Narrows and Falls developments, which are located on a 38-mile stretch of the Yadkin River (see Figure 2). High Rock, the most upstream development, is located at mile 253 on the Yadkin River and serves as the principal storage facility for the entire Yadkin-Pee Dee River. The Tuckertown, Narrows, and Falls developments are located approximately 8.7 miles, 16.5 miles, and 19.0 miles downstream, respectively, of the High Rock Development. The Yadkin Project is located approximately 60 miles northeast of Charlotte on the Yadkin River in Davidson, Davie, Montgomery, Rowan, and Stanly counties in central North Carolina. The Yadkin River and its tributaries are part of the Yadkin-Pee Dee River Basin, which extends from the eastern slopes of the Blue Ridge Mountains to the Atlantic coast near Georgetown, South Carolina. The Yadkin River's name changes to the Pee Dee River at its confluence with the Uwharrie River. The Pee Dee River continues its southeastern flow to Winyah Bay, where it meets the Atlantic Ocean. The Yadkin Project is licensed by the Federal Energy Regulatory Commission (FERC No. 2197). On ,APGI received a new license for the Yadkin Project from FERC. During the relicensing process, APGI formed an Issue Advisory Group (IAG) composed of members of federal and state resource agencies and other interested stakeholders to identify issues related to water resources and to develop study plans for studies to address potential impacts to water quality. Two specific studies related to water quality issues at the Yadkin Project were conducted under the guidance of the Water Quality IAG: (1) Yadkin Water Quality Study and (2) Sediment Fate and Transport Study. Another study indirectly related to water quality issues, the Tailwater Fish and Aquatic Biota Assessment, was conducted under the guidance of the Fish and Aquatics IAG whose focus was to identify issues related to fish and aquatic resources. Data generated from these studies were used during discussions with NCDWQ regarding the 401 Water Quality Certification of the Yadkin Project. On ,the NCDWQ issued a water quality certification for the Yadkin Project under Section 401 of the Clean Water Act. In accordance with the conditions of the 401 Water Quality Certification and the FERC License (Article, APGI is required to prepare a DO Monitoring Plan for the Yadkin Project, and to monitor dissolved oxygen and temperature conditions in accordance with the specifications of that plan. This QAPP will become a component of the DO Monitoring Plan. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 7 of 35 Tailwater DO Monitoring Draft QAPP Figure 2: Yadkin Project Regional Locus Map ~wf~ ~ ~/ ~ft ~ / I - \ I~ r t ~ 1 ~ ~I '. • ~ ~ .. _ ~52 ~ I ~ i ~- '. _: ~~ ~~ I ' I. ~~ ~~~ '- -,Hi4l~ Rock Leon '~~~;~ , ~ !Reservoir. _ ~ ~ i _ ~. I~~ ,°'' High Rock 8 ~ ~ I ,. ~~',~~ ~ ~ - ,t ~~ _ ~-' `T- - ~ ~ ~~~ TyCk~rtow ~~ l I r' ~ ~ "Res~rvoif 1 ~ 1 % ; ~~ ~~a `t i ~ Is 1 -'~~~! ~~- ~ x L I ( ~. 1 vi R wan Count• - ~ ~- ~~ ~ ~ ~ 7 1~~ r!Ef-CO !1~ \ / usn /~ ` , ~ , , `, 1, ~ 7ao~ ~rrdws f~. ~ -~ '~ 1 Rese?aroir _ ~ ~ ~?\,~ ~ ~ ~ Narrows - ~ x , a9~ ~ `~~\v~~~ J~ ~ o.n ~ ~ ~ ~/ ~ / ~ ~~ ~ ~ Falls Dem F? ~ ~~ ~~~/~ _ ~x Z l ~ ~ j _. 73 % ~ 740 ~ `~ ~~ 7 ~v~ J~ ~ ~ fAlb~ ~ A4ou ~n ~ ~~ ~ ~ ~G~;~~~ ~~~ ~ ~~ ~~ T~ 'r-_ ,~c` ~ J Stat Aark I f lei Iic~<d FERC Bo,sday ~ 1 Rivers rid Stre.m~ Regional Locus Map ~c6~•.r. w~rRad, S"adkin Project ~/ --•-. co~,nr•eound.de. O [~,b.n Areu ry f' L.kcs W~E I h8,-' S -• March 2006 o f z a s e io Miles Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 8 of 35 Tailwater DO Monitoring Draft QAPP A.5.2 Problem Statement The Yadkin Pee-Dee River Basinwide Water Quality Plan (Basinwide Water Quality Plan), prepared by NCDWQ in March 2003, provides an overview of the Yadkin-Pee Dee River basin. Increased monitoring of High Rock Reservoir over recent years (1999, 2000, and 2001) by NCDWQ has shown high levels of nutrients, combined with chlorophyll a, turbidity and percent DO saturation excursions from the state standards. The Basinwide Water Quality Plan discusses the low DO concentrations below High Rock Dam, which, according to the Plan, likely result from hypolimnetic (deep water) releases. The tailwater below High Rock Dam is listed on the impaired waters list (the 303[d] List) due to DO levels that do not meet state water quality standards. Additionally, portions of High Rock Reservoir are on the 2006 North Carolina draft list of impaired waters and require the development of Total Maximum Daily Loads (TMDLs). APGI began collecting baseline water quality data in the Project reservoirs and tailwaters in 1999 in accordance with a water quality study plan developed with input from the Water Quality IAG, APGI conducted monthly water quality sampling at reservoir locations and at each of the four tailraces below the dams from June 1999 to December 2003 and an additional station was added in Lick Creek in July 2003. The tailraces of the Falls and Narrows developments were continuously monitored for DO and temperature for extended periods (May through November) from 2000 through 2005; while the tailraces of the High Rock and Tuckertown developments were continuously monitored for DO and temperature for extended periods (May through November) in 2003 and 2004. Additional DO and temperature measurements were collected at two sites in the Lick Creek arm of Tuckertown Reservoir and at seven stations below the High Rock Dam tailrace beginning in July 2003. Specific to tailwater water quality, APGI's water quality study generally demonstrated that nutrient and solids concentrations in the four development tailraces were generally similar to conditions in the reservoirs immediately upstream of them, but that temperature, pH, DO, nitrate and ammonia differed considerably. Based on the study results, a downstream trend in median water quality values was apparent through the tailraces. Water quality of High Rock and Tuckertown tailraces was fairly similar. These two tailraces were turbid, nutrient rich, and contain moderate amounts of algal biomass. Between Tuckertown and Narrows tailraces, there was a moderate reduction of ammonia, chlorophyll a, nutrients, and solids. Water clarity improved somewhat in the downstream tailraces. The water quality of Narrows and Falls tailraces was almost identical. Although median concentrations were above the state standard, all four tailraces experienced low DO concentrations. The typical pattern at the High Rock tailrace showed reduced DO concentrations through the summer period, which was a direct result of low DO in High Rock Reservoir. When Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 9 of 35 Tailwater DO Monitoring Draft QAPP river flows were high, water in the reservoir was exchanged more rapidly, translating into relatively higher DO concentrations in the tailrace. The Tuckertown tailrace exhibited patterns similar to High Rack. In the Narrows tailrace, there were frequent occurrences of DO below 4 mg/1 from June to October. The study was unable to discern a clear relationship between hydrometeorologic conditions and the frequency of low DO levels in Narrows tailrace. DO concentrations in the Narrows tailrace were generally higher than conditions observed in either the High Rock or Tuckertown tailrace. The Narrows Unit 4 turbine has two air injection valves to introduce air into the flow during generation. The aeration valves on Unit 4 began operating in early 2001 and an initial study of Narrows tailwater DO, conducted by APGI in 2001, generally demonstrated that with both valves and only Unit 4 operating, about 2 to 4 mg/1 of DO was added to the tailwater. As part of the Water Quality Study, APGI conducted additional operational testing in 2004 to further examine the effect of Narrows Unit 4 air injection on tailwater DO. The 2004 test of the effect of the two aeration valves on Unit 4 generally confirmed earlier results in 2001 that with both valves operating, and just Unit 4 operating, about 2 mg/1 of DO was added to the tailwaters. The tests also demonstrated that increases in Narrows tailwater DO levels were generally translated into similar increases in DO concentrations below Falls Dam. Data generated from the Water Quality Study were used during discussions with NCDWQ regarding the 401 Water Quality Certification of the Yadkin Project. Throughout the relicensing of the Yadkin Project, NCDWQ expressed concerns about DO concentrations in each of the four Project tailwaters because they are frequently below North Carolina's state water standards during periods of warm water temperature and low river flows. The Yadkin Project DO Monitoring Plan is being implemented to monitor ongoing DO and temperature conditions in the four Yadkin Project tailwaters and to allow an assessment of changes to tailwater DO concentrations that occur as aeration equipment is installed and DO enhancement measures undertaken at the Yadkin Project, in accordance with the conditions of the 401 Water Quality Certification issued by NCDWQ for the Yadkin Project. The purpose of this QAPP is to provide a quality assurance/quality control program for the DO monitoring implemented under the DO Monitoring Plan so that the data can be used by APGI and NCDWQ. The QAPP documents the data collection and the procedures in place to ensure that the data are valid. This QAPP was developed in accordance with the USEPA guidance document "Guidance for Quality Assurance Project Plans, EPA QA/G-5" dated December 2002. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 10 of 35 Tailwater DO Monitoring Draft QAPP A6 Project/Task Description APGI's monitoring subcontractor will monitor DO and water temperature in accordance with the DO Monitoring Plan at four sites (one in each of the four Yadkin Project tailwaters), for the term of the Yadkin Project FERC License. Table 1 summarizes the tasks anticipated to occur under the DO Monitoring Plan and this QAPP. This QAPP will become part of the DO Monitoring Plan and will be effective upon written approval by NCDWQ. Table 1: Dissolved Oxygen Monitoring Plan Schedule Task Date QAPP effective date upon written approval by NCDWQ Deploy field equipment April, annually Begin seasonal DO/water temperature monitoring May 1, annually (measured at 15-minute intervals) Data downloads and field equipment May 1 through November 30, maintenance/calibration weekly Data Processor update Annual Database May 1 through November 30, every two weeks Monitoring Subcontractor Project Manager/QA May 1 through November 30, every Manager submit provisional data to APGI Project two weeks Manager/QA Manager Complete DO/water temperature monitoring for the November 30, annually season Provisional data made available upon request to Annually, as requested NCDWQ Retrieve field equipment December, annually Monitoring Subcontractor Project Manager/QA December-January, annually Manager and APGI Project Manager/QA Manager review data Final data and annual report filed with NCDWQ By March 31, annually and Progress Energy Final data and annual report filed with FERC Within 30 days of filing with NCDWQ Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 11 of 35 Tailwater DO Monitoring Draft QAPP Task Date Initiate special study (up to 2 years) to evaluate the 2011 effectiveness of the aeration technology installed at Narrows development on DO concentrations in the Falls tailrace Initiate special study (up to 2 years) to evaluate the 2013 effectiveness of aeration technology installed at High Rock development on DO concentrations in the Tuckertown tailrace A7 Quality Objectives and Criteria for Measurement Data The dissolved oxygen and temperature data collected in the tailwaters of the four Yadkin Project developments will be primarily used to assess changes to tailwater DO concentrations that occur as aeration equipment is installed and DO enhancement measures undertaken at the Yadkin Project in accordance with the conditions of the 401 Water Quality Certification issued by NCDWQ for the Yadkin Project. The DO and temperature data will be plotted every two weeks and reviewed for unusual values of DO and temperature, as well as any period where water quality standards was not met. If unusual values or periods of DO or temperature are found, the Monitoring Subcontractor Project Manager/QA Manager will check for notes by the Monitoring Subcontractor Field Manager regarding the data quality, review watershed conditions during monitoring, e.g., storm events, and then check for possible effects of Project operations affecting readings. Data quality objectives are used to assess the adequacy of data in relation to the intended use. Implementation and adherence to data quality indicators ensures that data quality objectives are met. Data quality indicators are measures of quality assurance and include statements of the precision, bias, and lower reporting limits necessary for the data to address objectives. This section focuses on several data quality indicators to ensure that the data collected are valid and repeatable. Objectives for several of these data characteristics are summarized in Table 2. Each data quality indicator is discussed briefly below along with how each is addressed by this QAPP. The following sections of this QAPP provide further detail on how each indicator is addressed. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 12 of 35 Tailwater DO Monitoring Draft QAPP Table 2: Data Quality Objectives and Criteria Parameter Method Units Measuremen t Range Accuracy Completeness Dissolved Electronic mg/L 0 - 50 mg/1 +/- 2% of the 90% Oxygen meter reading or 0.2 mg/1 (whichever is greater)/ resolution is 0.01 mg/1 Water Electronic °C -5 to +45 °C +/- 0.15 °C 90% Temperature meter Accuracy Accuracy is a measure of the overall agreement of a measurement to a known value, including a combination of random error (precision) and systematic error (bias) from sampling and analytical operations. In accordance with the SOPS in Attachment A, accuracy of the in situ field instruments will primarily be assured by calibration and maintenance of the instruments per the manufacturer's specifications. Each field instrument will be calibrated and checked for damage before deployment at the beginning of the monitoring season and on a weekly basis thereafter. The DO membranes will be replaced on each in situ field instrument on a monthly basis (or more frequently, if necessary). Temperature thermistors will be verified with a National Institute of Standards and Technology (KIST) certified thermometer before deployment and upon removal of the instruments at the end of the monitoring season to ensure the accuracy of the water temperature data. Accuracy will also be ensured by comparing the in situ field instruments to a comparable YSI 58 meter prior to the weekly calibration of each field instrument. The YSI 58 meter will be calibrated according to the manufacturer's specifications and the SOPS in Attachment B and compared to a NIST certified thermometer. Independent DO and water temperature measurements using a YSI 58 meter will be compared to the field instruments to ensure that the field instruments are not drifting (see Attachment A). If the independent DO differs by more than 0.5 mg/L or the water temperature measurements differ by more than 0.5 degree, the DO membrane of the in situ instrument will be replaced or the probes on the field instrument will be replaced or reconditioned. The Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag measurements as suspect since the last valid measurements obtained during the comparison. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 13 of 35 Tailwater DO Monitoring Draft QAPP Precision Precision is the measure of agreement among repeated measurements of the same parameter under identical, or substantially similar conditions. Prior to the weekly calibration of each in situ field instrument, independent DO and water temperature measurements using a YSI 58 meter will be compared to the field instruments. The YSI 58 meter will be calibrated according to the manufacturer's specifications and the SOPs in Attachment B. The YSI 58 meter will be compared to a NIST certified thermometer. If the independent DO differs by more than 0.5 mg/L or the water temperature measurements differ by more than 0.5 degree, the DO membrane of the in situ instrument will be replaced or the probes on the field instrument will be replaced or reconditioned. The Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag measurements as suspect since the last valid measurements obtained during the comparison. Bias Bias is the systematic or persistent distortion of a measurement process that causes errors in one direction. Measurement bias is minimized by adhering to the standard, written procedures in Attachments A, B, and C to ensure consistency if different personnel are involved in the field monitoring. Each site visit is conducted by a field crew of two personnel that provides an additional level of assurance that the SOPS are followed. The in situ field instruments will be calibrated and maintained per the manufacturer's specifications. Prior to the weekly calibration of each field instrument, independent DO and water temperature measurements using a YSI 58 meter will be compared to the field instruments to determine if there has been instrument drift. The YSI 58 meter will be calibrated according to the manufacturer's specifications and the SOPs in Attachment B. The YSI 58 meter will be compared to a NIST certified thermometer. If the independent DO differs by more than 0.5 mg/L or the water temperature measurements differ by more than 0.5 degree, the DO membrane of the in situ instrument will be replaced or the probes on the field instrument will be replaced or reconditioned. The Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag measurements as suspect since the last valid measurements obtained during the comparison. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 14 of 35 Tailwater DO Monitoring Draft QAPP Representativeness Representativeness is the degree to which data accurately and precisely represent a characteristic of a population, parameter variations at a sampling location, a process condition or an environmental condition. While the continuous DO data collected may not be representative of the watershed, it will be representative of the stream reach being sampled. The purpose of the monitoring is to monitor ongoing dissolved oxygen and water temperature conditions in the four Yadkin Project tailwaters and to allow an assessment of changes to tailwater DO concentrations that occur as aeration equipment is installed and DO enhancement measures undertaken at the Yadkin Project, in accordance with the conditions of the 401 Water Quality Certification issued by NCDWQ. To confirm the representativeness of the current locations, several field surveys were conducted prior to implementing continuous DO and temperature monitoring. These surveys were designed to examine the lateral and longitudinal change in tailwater DO conditions and to determine if the locations were indicative of overall tailwater conditions. Results of these studies demonstrated that the instruments are located in areas that are generally representative of overall tailwater conditions (the red lines in Figures 3-6 indicate the transect locations of these surveys). Additionally, the data is being collected in 15 minute intervals which allows for good representation of daily trends in the data. Comparability Comparability is the measure of confidence that one data set can be compared to another. The continuous monitoring locations are fixed and the latitude and longitude documented to ensure that data are comparable spatially. Existing buoys (in the High Rock, Tuckertown, and Falls tailwaters) and a pipe (in the Narrows tailwater) mark the locations to ensure consistency. The field instruments are attached to the existing buoys and pipe and these buoys and pipe are left in place at the end of the monitoring season. The use of standard, written procedures in Attachments A, B, and C will ensure consistency if different personnel are involved in the field monitoring. The Monitoring Subcontractor Field Manager will review the procedures with the Monitoring Subcontractor Field Staff prior to each monitoring season. Consultation with NCDWQ will ensure that data collected under this QAPP will be comparable to that collected by NCDWQ. Before modifying any measurement method, the APGI Project Manager/QA Manager will review with NCDWQ the effects of such a modification. ' Normandeau Associates Inc. 2005. Water Quality Final Study Report. August 2005. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 15 of 35 Tailwater DO Monitoring Draft QAPP Completeness Completeness is the measure of the amount of valid data needed from a measurement system. There may be data gaps caused by unavoidable circumstances such as loss of instruments due to high water, inoperability of instruments during extreme low water conditions, instrument theft or destruction, instrument malfunction or instrument maintenance/servicing and/or calibration. The goal is to have a minimum of 90% of the expected data measurements usable for analysis. It is expected that at each monitoring location, DO and water temperature measurements will be taken at 15-minute intervals from May 1 through November 30 except for gaps due to unavoidable circumstances. The reason(s) for missing data and data rejected from analysis will be included in the annual data reports. Sensitivity Sensitivity is the capability of the instrument or method to discriminate between measurement responses representing different levels of the variable of interest. The instruments used measure the range of expected values for DO and water temperature under all field conditions. Water temperature is reported to the nearest hundredth of a degree Celsius. Dissolved oxygen (mg/L) will be calculated by the Sonde from percent air saturation, temperature and salinity values. Salinity of freshwater will be considered 0 ppt. The range of the DO sensor is 0 to 50 mg/L. The accuracy (from 0 to 20 mg/L) is plus or minus 2% of the reading or 0.2 mg/L, whichever is greater, and the resolution of the sensor is 0.01 mg/L. DO values are typically reported to the nearest hundredth. A8 Special Training and Certification All personnel responsible for field monitoring must be familiar with this QAPP and the attached SOPS. The Monitoring Subcontractor Field Manager will train the Monitoring Subcontractor Field Staff in field procedures and provide the SOPS in Attachments A, B, and C (developed in accordance with the manufacturer's specifications for calibration, repair, and maintenance) prior to each monitoring season. On a monthly basis, the Monitoring Subcontractor Field Manager will visit each monitoring location for servicing the field instruments and observe the field techniques of Monitoring Subcontractor Field Staff. Any issues with technique will be corrected at that time and documented in the appropriate field log book. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 16 of 35 Tailwater DO Monitoring Draft QAPP All personnel responsible for field monitoring must complete a safety training as required by regulating agencies and APGI. Documentation of completion of this training on an annual basis will be maintained by the APGI Project Manager/QA Manager. A9 Documents and Records All personnel with a role in implementing the DO Monitoring Plan will receive the most recently approved QAPP and associated documents. These documents will be updated as necessary by the APGI Project Manager/QA Manager and distributed in electronic format to all parties listed in Section A3. Any revisions to the QAPP will be noted on the title page with the revision number and effective date. Only the APGI Project Manager/QA Manager will have access to making revisions to the electronic copy of the QAPP. During the monitoring season, the Monitoring Subcontractor Field Staff will maintain records of calibration and maintenance in a field calibration log book and other field notes/information in field log books. Each field instrument will be identified by its serial number (or assigned a unique number if it does not have a serial number) and have its own field log book. The Monitoring Subcontractor Field Staff will maintain a backup copy of the field calibration log book and field log books in a separate file location from the originals. Copies of relevant calibration forms, instrument maintenance records and other notes related to field issues/observations created by the Monitoring Subcontractor Field Staff will be transferred to the Monitoring Subcontractor Field Manager on a monthly basis. The Monitoring Subcontractor Field Manager will maintain the copies as backups until the end of each monitoring season. The Monitoring Subcontractor Field Manager will maintain Temperature Check Forms in a thermistor log book for the comparisons of the thermistors with a NIST certified thermometer. The Monitoring Subcontractor Field Manager will maintain a backup copy of the thermistor log book until the end of each monitoring season in a separate file location from the original. At the end of each monitoring season, the Monitoring Subcontractor Field Manager will provide copies of the field calibration log books, field log books, and the thermistor log book to the Monitoring Subcontractor Project Manager/QA Manager. The Monitoring Subcontractor Project Manager/QA Manager will provide copies to the APGI Project Manager/QA Manager. The APGI Project Manager/QA Manager will maintain copies of these records in the QA/QC files for this monitoring project for the term of the Yadkin Project FERC License in a fire-proof cabinet. The APGI Project Manager/QA Manager will control access to the QA/QC files. The Monitoring Subcontractor Project Manager/QA Manager will maintain scans of all forms and all data files in electronic format for five years in a fire-proof cabinet. Access Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 17 of 35 Tailwater DO Monitoring Draft QAPP to these files is controlled by the Monitoring Subcontractor Project Manager/QA Manager. All annual data reports submitted to NCDWQ (see Section A6) will also be maintained in hard copy and electronic format by the APGI Project Manager/QA Manager for the term of the Yadkin Project FERC License. Details of electronic data management are further described in Section B10 of this QAPP. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 18 of 35 Tailwater DO Monitoring Draft QAPP B1 Sampling Process Design Continuous in situ DO/temperature instruments will be used to collect data at locations in each of the four Yadkin Project tailwaters as specified in the DO Monitoring Plan. The locations of each instrument will be the same year to year (see Table 3 and Figures 3-6) unless other conditions require the evaluation of a new location for placement either on a temporary or permanent basis. However, in accordance with the DO Monitoring Plan, no change in instrument location will occur without prior consultation with NCDWQ. Table 3: DO Monitoring Plan Specified Instrument Site Locations Tailwater Latitude Longitude High Rock N35 35 48.279 W 80 13 54.184 Tuckertown N 35 29 01.739 W 80 10 21.234 Narrows N 35 25 05.637 W 80 OS 28.767 Falls N 35 23 28.734 W 80 04 14.938 The DO/temperature monitoring instruments located in the High Rock, Tuckertown and Falls tailwaters are anchored to buoys and sit approximately one meter below the water surface. The Narrows tailwater instrument is suspended in a pipe anchored to a bridge abutment. The Narrows tailwater instrument is approximately one to four meters below the water surface depending upon discharge from the development. The instruments record DO and water temperature at 15-minute intervals except during unavoidable circumstances, such as instrument theft or destruction, instrument malfunction or instrument maintenance/servicing and/or calibration, for the period May 1 through November 30, annually. The DO and temperature data will be plotted every two weeks and reviewed for unusual values of DO and temperature, as well as any period where water quality standards was not met. If unusual values or periods of DO or temperature are found, the Monitoring Subcontractor Project Manager/QA Manager will check for notes by the Monitoring Subcontractor Field Manager regarding the data quality, review watershed conditions during monitoring, e.g., storm events, and then check for possible effects of Project operations affecting readings. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 19 of 35 Tailwater DO Monitoring Draft QAPP Figure 3: Location of High Rock Tailwater Continuous Monitoring Instrument Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 20 of 35 Tailwater DO Monitoring Draft QAPP Figure 4: Location of Tuckertown Tailwatcr Continuous Monitoring Instrument Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 21 of 35 Tailwater DO Monitoring Draft QAPP Figure 5: Location of Narrows Tailwater Continuous Monitoring Instrument Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 22 of 35 Tailwater DO Monitoring Draft QAPP Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 23 of 35 Tailwater DO Monitoring Draft QAPP Figure 6: Location of Falls Tailwater Continuous Monitoring Instrument B2 Sampling Methods YSI 6920 in situ field instruments will be used for the monitoring in each of the monitoring locations. A small boat is required to reach each monitoring location. Once the instruments are deployed and anchored to the existing buoys or pipe (see Section B 1) at the monitoring locations, the instruments will be set to record and store DO and water temperature measurements every 15 minutes, for the period May 1 through November 30, annually. The Monitoring Subcontractor Field Staff will make weekly site visits to download data, check for fouling, and to calibrate the field instruments. Field instrument calibration and weekly data downloads will be conducted in accordance with the manufacturer's specifications and the attached SOPS (Attachment A). The instruments will be fully serviced and DO membranes will be replaced monthly in accordance with the manufacturer's procedures summarized in Attachment C by the Monitoring Subcontractor Field Manager. At the end of the monitoring season, field instruments will be retrieved, cleaned and stored. Instrument models specified in the QAPP may be modified, as necessary or desired. However, the Licensee will notify NCDWQ of its intention to change the instrument model before a new model is deployed, and review the QAPP for any necessary changes, and review the QAPP for any necessary changes. If an instrument is lost, stolen, damaged or not functioning properly, it will be replaced with a backup instrument as soon as practicable. This information will be recorded in the appropriate field log book. If at any time APGI, the Monitoring Subcontractor Field Staff or the Monitoring Subcontractor Monitoring Field Manager determines conditions in any of the Yadkin Project tailwaters are unsafe, APGI may at its sole discretion suspend monitoring or related calibration, data retrieval, and downloading activities until conditions are determined to be safe. This will be noted in the appropriate field log books. If APGI determines that it is no longer safe to continue monitoring at a specific location, APGI will notify NCDWQ. The Monitoring Subcontractor Field Manager and Field Staff will follow APGI's Subcontractor Health and Safety Plan and all applicable safety requirements required by APGI. B3 Sample Handling and Custody Dissolved oxygen and water temperature measurements collected under this QAPP and the DO Monitoring Plan are recorded by the monitoring instruments in situ and therefore, no samples are collected, transported or stored. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 24 of 35 Tailwater DO Monitoring Draft QAPP B4 Analytical Methods Dissolved oxygen and water temperature measurements collected under this QAPP and the DO Monitoring Plan are made in situ and therefore, no samples are analyzed by a laboratory. Field measurement methods are summarized in Table 4. Table 4: Field Measurement Method and Reporting Levels Parameter EPA Method (if applicable) Reported to Nearest... Dissolved Oxygen 360.1 0.01 mg/L Water temperature 170.1 0.01 °C DO and water temperature measurements are made in accordance with the SOPS in Attachment A. The instruction manual for the in situ instruments should also be consulted. B5 Quality Control Quality control measures for the DO and water temperature field monitoring primarily include calibration, comparing instrument performance to an independent calibrated instrument, and servicing of the instruments (see Sections B6 and B7). The in situ field instruments will be calibrated for DO prior to deployment at the beginning of the monitoring season. Weekly calibration of the in situ instruments will be in accordance with the SOPs in Attachment A and the calibrations for each instrument will be recorded on a calibration form (Attachment D) contained in the field calibration log book. Moreover, monthly servicing will include replacement of the DO membrane in accordance with the SOPs in Attachment C. Documentation of the monthly servicing of each instrument will be recorded in the field calibration log book. Prior to deployment at the beginning of the monitoring season, the temperature thermistors will be compared by the Monitoring Subcontractor Field Manager to a NIST certified thermometer as described in detail in Section B7 and recorded on a Temperature Check Form (Attachment E) contained in the thermistor log book. If the temperature measurements differ by more than 0.5 degree, then a thermistor will not be deployed. After deployment, the thermistors will be compared with the NIST certified thermometer at the end of the monitoring season. Results of this comparison will be recorded on a Temperature Check Form contained in the thermistor log book. If the temperature measurements differ by more than 0.5 degree, the Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 25 of 35 Tailwater DO Monitoring Draft QAPP to flag water temperature measurements since the last valid weekly temperature check in the Annual Database. Weekly DO and temperature checks are described below. Prior to the weekly calibration of each field instrument, independent DO and water temperature measurements using a comparable YSI 58 meter (calibrated in accordance with Attachment B and compared to a NIST certified thermometer) will be compared to measurements of the in situ field instruments made in a bucket of tailrace water (see Section B7). This comparison will be recorded in the appropriate field log book and used to determine if there has been drift in the in situ field instrument measurements. If the independent DO differs by more than 0.5 mg/L or the water temperature measurements differ by more than 0.5 degree, the DO membrane of the in situ instrument will be replaced or the probes on the field instrument will be replaced or reconditioned. The Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag measurements as suspect since the last valid measurements obtained during the comparison with the YSI 58 meter in the Annual Database. B6 Instrument Testing, Inspection, and Maintenance Testing, inspection and maintenance of the field instruments is the responsibility of the Monitoring Subcontractor Field Manager and Monitoring Subcontractor Field Staff. Prior to deployment, all instruments are inspected, calibrated, and loaded with new batteries. Any non-functioning instrument is taken out of service and shipped to the manufacturer for repair, if necessary. Instruments that are not in the field are maintained by the Monitoring Subcontractor Field Manager or Monitoring Subcontractor Field Staff. Continuous in situ field instruments will be inspected and cleaned on a weekly basis during the May through November monitoring period. The instruments will be serviced on a monthly basis. Monthly servicing includes replacement of the DO membranes and batteries and the cleaning, inspection and regreasing of o-rings of the sondes in accordance with the manufacturer's specifications (Attachment C). The SOPs in Attachments A and C contain detailed information on the maintenance procedures of the field instruments. All maintenance and servicing of the instruments will be documented by the Monitoring Subcontractor Field Manager and Monitoring Subcontractor Field Staff in the field calibration log book. Copies of relevant instrument maintenance records will be transferred to the Monitoring Subcontractor Field Manager on a monthly basis. If an instrument appears to be malfunctioning or damaged, the Monitoring Subcontractor Field Manager will note data for flagging by the Data Processor when it appears to be obviously erroneous. The Monitoring Subcontractor Field Manager will make a note on Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 26 of 35 Tailwater DO Monitoring Draft QAPP the data QA transmittal of any suspect data with instructions for the Data Processor for flagging in the Annual Database. B7 Instrument Calibration and Frequency The in situ YSI 6920 field instruments will be calibrated in accordance with the procedures outlined in Attachment A prior to deployment at the beginning of the monitoring season and weekly, except in extenuating circumstances. Each field instrument has its own unique number serial number and calibration information is recorded on calibration forms (Attachment D) contained in the field calibration log book. Once the instrument is calibrated on a weekly basis, that measurement serves as a calibration for measurements that are about to be collected and apost-calibration for measurements that were collected prior to calibration. Any non-functioning instrument is taken out of service and shipped to the manufacturer for repair, if necessary. Copies of relevant instrument calibration forms will be transferred to the Monitoring Subcontractor Field Manager on a monthly basis. If an instrument appears to be malfunctioning or damaged, the Monitoring Subcontractor Field Manager will make a note on the data QA transmittal of any suspect data with instructions to the Data Processor for flagging in the Annual Database. Moreover, a YSI 58 meter will be calibrated prior to weekly use and post-calibrated at the end of the field day to document any potential instrument drift in accordance with Attachment B. Calibration information will be recorded on a calibration form (Attachment D). The YSI 58 meter will also be compared to a NIST certified thermometer before and after weekly use (at the beginning and end of the field day) and the results recorded on a Temperature Check form (Attachment E). The YSI 58 meter will be used for comparison measurements in conjunction with the weekly site visits to the in situ field instruments. Prior to the weekly calibration of each in situ field instrument, independent DO and water temperature measurements from a YSI 58 meter will be compared to measurements of the in situ field instruments made in a bucket of tailrace water. If the independent DO differs by more than 0.5 mg/L or water temperature measurements differ by more than 0.5 degree, the DO membrane of the in situ field instrument will be replaced or the probes on the field instrument will be replaced or reconditioned and the issue will be recorded in the field log book for that field instrument. If replacing the DO membrane, servicing the probe, or replacing the probe does not resolve the problem, the in situ field instrument will be replaced and returned to the office for further analysis and repair. The Monitoring Subcontractor Field Manager will also make a note on the data QA transmittal form for the Data Processor to flag the suspect data in the Annual Database and a note on the amount of the difference for potentially correcting the data. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 27 of 35 Tailwater DO Monitoring Draft QAPP The Monitoring Subcontractor Field Manager will compare thermistors in the office with a NIST certified thermometer prior to deployment at the beginning of the monitoring season and at the end of the monitoring season using atwo-point calibration with high and low temperatures. Results of this comparison will be recorded on a Temperature Check Form contained in the thermistor log book. If the temperature measurements differ by more than 0.5 degree, then a thermistor will not be deployed. After deployment, the thermistors will be compared with the NIST certified thermometer at the end of the monitoring season. Results of this comparison will be recorded on a Temperature Check Form contained in the thermistor log book. If the temperature measurements differ by more than 0.5 degree, the Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag water temperature measurements since the last valid weekly temperature check in the Annual Database. B8 Inspection/Acceptance of Supplies Routine supplies such as DO membranes, electrolyte (KCl), deionized water, and batteries are purchased from vendors by the Monitoring Subcontractor Field Manager. Supplies and packages are inspected for damage upon receipt from vendors. Any damaged supplies will be returned to the vendor and not accepted for use. DO membranes are visually inspected prior to use. Deionized water and the electrolyte are visually inspected prior to use for discoloration, debris, or other contaminants. Supplies are stored with both the Monitoring Subcontractor Field Manager and Monitoring Subcontractor Field Staff in waterproof cases indoors under controlled temperatures. DO probes will be stored in a moist environment when not in use. B9 Non-direct Measurements Measurement data not obtained directly under the DO Monitoring Plan and this QAPP, including hydro plant generating data, reservoir elevation data, National Weather Service weather data, and U.S. Geological Survey (USGS) gage stream flow data, may be used for interpretation of continuous DO monitoring data. Data collected by regulatory and governmental agencies will be used and considered as valid data since these agencies have independent QA/QC programs to ensure valid data. Yadkin Project discharge and generation data will be obtained from APGI operations staff. Data from universities, non-governmental organizations, or industries may be used to analyze continuous monitoring results depending upon methods, sampling design, and QA/QC limitations. Citations will be made when such data are used. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 28 of 35 Tailwater DO Monitoring Draft QAPP B10 Data Management The continuous DO and water temperature data are stored on the YSI 6920 instruments upon measurement. The Monitoring Subcontractor Field Staff or Monitoring Subcontractor Field Manager will download data from the in situ instruments on a weekly basis (the Monitoring Subcontractor Field Manager will do this on a monthly basis while the Monitoring Subcontractor Field Staff will download data the other weeks) to a laptop or hand held device (YSI 650 MDS) as described in Appendix A. Data files are archived on up to two disks in addition to the hard drive on the laptop. In addition, the Monitoring Subcontractor Field Staff or Monitoring Subcontractor Field Manager saves all data on each field instrument during the monitoring season in case it is necessary to retrieve previous data. At the end of the monitoring season, the data files will be deleted from each of the field instruments as one of the last steps in demobilizing each of the field instruments. Once data files are downloaded on a weekly basis, the Monitoring Subcontractor Field Staff will transfer the files to the Monitoring Subcontractor Field Manager. Applicable calibration forms and maintenance records contained in the field calibration log books will be transferred to the Monitoring Subcontractor Field Manager on a monthly basis. The Monitoring Subcontractor Field Manager will review the data for completeness and any obvious errors and will instruct the Data Processor to flag suspect data on the data QA transmittal form. These data files are transferred electronically to the Data Processor along with a data QA transmittal form weekly. Supporting calibration forms and maintenance records will be transferred to the Monitoring Subcontractor Project Manager/QA Manager and Data Processor monthly. The Monitoring Subcontractor Field Manager will maintain two archived copies of all data files transferred to the Data Processor, one on disk and the other on the hard drive of a laptop. Data files are stored for the duration of the project on the Data Processor computer server, which is backed up electronically on a daily basis. The Data Processor reviews data files individually, inspecting the beginning and end data points for omissions or anomalies related to removing the in situ field instruments from the tailwater monitoring locations for download and servicing. Suspect data are flagged and omitted from analysis. The Data Processor processes the data into electronic spreadsheets using the YSI software interface program, Ecowatch, custom SAS programs, Microsoft Excel software. A series of SAS macros developed specifically for this study, process the data and prepare graphical representation of the data. This graphical presentation allows additional visual inspection to identify issues with the data and allow for immediate problem identification and resolution, if necessary. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 29 of 35 Tailwater DO Monitoring Draft QAPP As the data is reviewed, only the Data Processor or the Monitoring Subcontractor Project Manager/QA Manager will be able to make any changes to the data. All changes are documented on the data QA transmittal form. The Monitoring Subcontractor Project Manager/QA Manager will provide the provisional data to the APGI Project Manager/QA Manager every two weeks after it is processed and the Data Processor will update the Annual Database. Only the Data Processor and the Monitoring Subcontractor Project Manager/QA Manager have access to the database. The Monitoring Subcontractor Project Manager/QA Manager will provide the APGI Project Manager/QA Manager with a copy of the final Annual Database at the end of the field monitoring season. The APGI Project Manager/QA Manager will file a copy of the Annual Database in electronic format with the project files. Throughout the entire monitoring season the database is archived daily to ensure no loss of data and to guarantee database integrity. At the end of the field monitoring season, all forms, original data, and the database will be archived in electronic format on digital media; the Data Processor will maintain a copy in a fire-proof vault and the Monitoring Subcontractor Project Manager/QA Manager will maintain a copy in the project files. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 30 of 35 Tailwater DO Monitoring Draft QAPP Figure 7: Data Flow Chart Data downloaded weekly Monitoring Subcontractor Project Manager/QA Manager provides provisional data to the APGI Project Manager/QA Manager every two weeks 0 Data Processor finalizes and incorporates data in Annual Database Data downloaded by Monitoring Subcontractor Field Staff are transferred to the Monitoring Subcontractor Field Manager weekly Monitoring Subcontractor Field Manager reviews data and makes notes on the data QA transmittal form instructing the Data Processor to flag suspect data 0 Data processed and reviewed by Data Processor and Monitoring Subcontractor Project Manager/QA Manager Monitoring Subcontractor Project Manager/QA Manager provides copy of final Annual Database to APGI Project Manager/QA Manager at end of monitoring season for project files Monitoring Subcontractor Field Manager transfers data and data QA transmittal form to Data Processor weekly Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 31 of 35 Tailwater DO Monitoring Draft QAPP Cl Assessments and Response Actions The Monitoring Subcontractor Project Manager/QA Manager, or a qualified QA/QC auditor appointed by the Monitoring Subcontractor Project Manager/QA Manager, will perform an annual (after the field monitoring season) internal self-assessment of the QA program to ensure the QA/QC records are complete and accountable. The Monitoring Subcontractor Project Manager/QA Manager is independent of the data collection process. The self-assessment results will be documented and provided to the APGI Project Manager/QA Manager for the project QA/QC files. Any corrective actions, as required, will be implemented and documented. The APGI Project Manager/QA Manager provides additional oversight through the review of the QA/QC records generated for the continuous DO and water temperature monitoring. The APGI Project Manager/QA Manager will review and verify field data collection, data processing and data file submittals; submittal of QA records to the QA/QC file; corrections or revisions to data files and any subsequent documentation in the QA/QC file; and self-assessment results. Moreover, the Monitoring Subcontractor Field Manager will accompany and observe Monitoring Subcontractor Field Staff monthly. This field assessment is to ensure that Monitoring Subcontractor Field Staff are performing activities in accordance with this QAPP and the associated SOPS and to determine if there are any other issues that need to be addressed. Concerns or irregularities will be documented and procedures will be reviewed with any Monitoring Subcontractor Field Staff in need of performance improvement. C2 Reports to Management The Monitoring Subcontractor Field Manager reports significant issues to the Monitoring Subcontractor Project Manager/QA Manager via email. Issues are then reported to the APGI Project Manager/QA Manager as part of the reports accompanying data submittals. The APGI Project Manager/QA Manager will receive reports from the annual internal self-assessment of the QA program, and copies of all QA documentation, including field log books and calibration forms. The APGI Project Manager/QA Manager is responsible for maintaining these records in the continuous DO and water temperature monitoring QA/QC file. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 32 of 35 Tailwater DO Monitoring Draft QAPP D1 Data Review, Verification, and Validation Continuous DO and water temperature data are accepted or flagged as suspect based on instrument performance and calibrations. Instruments are calibrated for DO and compared to a calibration table to ensure accurate DO measurements. Any questionable instrument is replaced by a backup instrument, as soon as practical, until the issue can be corrected. In some cases, replacement of the DO membrane or a probe may correct the issue. As described in Sections B6 and B7, if an instrument appears to be malfunctioning or damaged, the Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form instructing the Data Processor to flag data, and not include that data in reports when it appears to be obviously erroneous. The DO and water temperature data are reviewed by the Monitoring Subcontractor Field Manager for anomalies prior to transfer to the Data Processor. The Monitoring Subcontractor Field Manager will make notes on the data QA transmittal form instructing the Data Processor to flag suspect data based upon instrument performance and professional judgment. Once the data have been processed by the Data Processor, the DO and water temperature data are reviewed by the Monitoring Subcontractor Project Manager/QA Manager and the Data Processor as described in further detail in Section D2. Any changes or flagged data will be documented on the data QA transmittal form. The Monitoring Subcontractor Project Manager/QA Manager is responsible for final review, verification and validation of all monitoring results prior to submittal to the APGI Project Manager/QA Manager. Data QA transmittal forms documenting data flagging situations and rejections of data for reporting will also be provided to the APGI Project Manager/QA Manager along with data submittals for the QA/QC file. D2 Verification and Validation Methods As described in further detail in Section B 10, continuous DO and water temperature monitoring data are downloaded in the field from the in situ instruments to a laptop or hand held device (YSI 650 MDS). The Monitoring Subcontractor Field Manager will review data for completeness and any obvious errors prior to transfer to the Data Processor. The DO and water temperature data are reviewed by the Monitoring Subcontractor Field Manager for anomalies prior to transfer to the Data Processor and the Monitoring Subcontractor Field Manager will make a note on the data QA transmittal form to the Data Processor on whether to flag data as suspect based upon instrument performance and professional judgment. The Data Processor also reviews data files individually, inspecting for data omissions or anomalies. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 33 of 35 Tailwater DO Monitoring Draft QAPP The Data Processor processes the data into electronic spreadsheets using an YSI software interface program (Ecowatch). Data continue to be inspected for completeness and accuracy via the use of custom programs in SAS and Microsoft Excel. A series of macros developed specifically for this study process the data, and prepare graphical representation of the data. Additional visual inspections may identify issues with the data and allow for immediate problem identification and resolution, if necessary. In preparation for the annual reporting of continuous DO and water temperature monitoring, the SAS software analysis allows opportunity for identification of areas of concern and permits immediate resolution of data anomalies. Additional tools, such as Microsoft Excel, afford further analysis and data presentation capabilities. Once the data have been processed by the Data Processor, the DO and water temperature data are reviewed by the Monitoring Subcontractor Project Manager/QA Manager and the Data Processor. The DO and temperature data will be plotted every two weeks and reviewed for unusual values of DO and temperature, as well as any period where water quality standards was not met. If unusual values or periods of DO or temperature are found, the Monitoring Subcontractor Project Manager/QA Manager will check for notes by the Monitoring Subcontractor Field Manager regarding the data quality, review watershed conditions during monitoring, e.g., storm events, and then check for possible effects of Project operations affecting readings. Any changes, flagged data, or deletions of data from reporting will be documented by the Data Processor or Monitoring Subcontractor Project Manager/QA Manager on the data QA transmittal form. Data QA transmittal forms documenting non-reporting, corrections to the data based on calibration records, or suspect data will also be provided to the APGI Project Manager/QA Manager along with data submittals for the QA/QC file. Once the data are finalized, the data files will be incorporated into the Annual Database and any accompanying documentation will be incorporated into QA/QC file for the continuous DO and water temperature monitoring. D3 Reconciliation with User Requirements The continuous DO and water temperature monitoring data will be used for an assessment of changes to tailwater DO concentrations that occur as aeration equipment is installed and DO enhancement measures undertaken at the Yadkin Project in accordance with the conditions of the 401 Water Quality Certification issued by NCDWQ for the Project. The DO and temperature data will be plotted every two weeks and reviewed for unusual values of DO and temperature, as well as any period where water quality standards was not met. If unusual values or periods of DO or temperature are found, the Monitoring Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 34 of 35 Tailwater DO Monitoring Draft QAPP Subcontractor Project Manager/QA Manager will check for notes by the Monitoring Subcontractor Field Manager regarding the data quality, review watershed conditions during monitoring, e.g., storm events, and then check for possible effects of Project operations affecting readings. As described in Section A6 and the DO Monitoring Plan, data will be reviewed at the end of the monitoring season and provided to NCDWQ, Progress Energy and FERC in an annual report. Any data limitations will be documented in the report. Any sampling design modifications considered for future annual monitoring will be done in consultation with NCDWQ. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page 35 of 35 Tailwater DO Monitoring Draft QAPP Attachment A: Standard Operating Procedures for In Situ Field Instrument Maintenance/Calibration and Data Downloads Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page A-1 Tailwater DO Monitoring Draft QAPP YADKIN HYDROELECTRIC PROJECT SOP for WEEKLY DOWNLOADS OF YSI 6920 Sondes A. Post-Calibration of YSI 6920 prior to weekly download of data. 1. Approach each buoy or pipe. 2. Place buoy on the boat, unlock the cap on the pipe and remove cap and YSI 6920 Sonde from the pipe. Record the time of Sonde removal from the water using the clock on the YSI 650. 3. Tie off the Sonde. 4. Connect the 650MDS to the sonde using the cable and turn the unit "on" 5. Select "Sonde Menu" using the arrow buttons and enter. 6. Select "Run" and enter 7. Select "Unattended Sample" and enter 8. Using arrow button, scroll down to bottom of the page to highlight "Stop Logging" and enter. (If the instrument asks you "are you sure", select "yes" and enter) 9. Use the "Esc" to escape back to the main menu and then turn off the 650MDS 10. Fill a 5 gallon bucket with tailrace water. 11. Place the Sonde and the probe for the YSI 58 meter in the bucket. 12. Record DO and water temperature readings from both meters in the field log book, while gently swirling water in the bucket. If differences are more than 0.5 mg/L for DO and 0.5 degree for water temperature, make a note to the Data Processor to flag the data as suspect for further review. Additionally, differences more than the criteria noted here require that at a minimum the DO membrane will need to be changed. B. Weekly Maintenance and Calibration 1. Remove the lock and ring of the YSI 6920 Sonde. 2. Clean the YSI 6920 Sonde and inspect buoy cable attachment points. 3. Clean lock and ring and spray with WD40. 4. Rinse probes 3 time with water. Water can be lake, tap, or deionized water. 5. Dry (dab) off dissolved oxygen probe and place in calibration cup with just a little bit of water at the bottom of the cup. Put the cup back on the YSI 6920 Sonde with just a couple of turns. This will allow the air in the cup to saturate with water. 6. Let the YSI 6920 Sonde sit for 10 minutes. 7. After 10 minutes, connect the handheld YSI 650MDS to the YSI 6920 Sonde using the download cable and turn on the YSI 650MDS. 8. Using the arrow buttons to select "sonde run", press "Enter" button. This is an enter button just like a computer has. 9. Record the DO (%) and temperature in the field calibration log book. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page A-2 Tailwater DO Monitoring Draft QAPP 10. Hit "Esc" to back to the main menu. 11. Using the arrow keys, select "sonde menu" and hit "Enter" button. 12. Select "calibrate" and hit "Enter" button 13. Select "dissolved oxygen" and press "Enter" button. 14. Select "DO %" and again hit the "Enter" button. 15. Enter the correct barometric pressure reading and press "Enter", IF the reading is close to the one in the lower right corner (less than 0.2mmHg of a difference), hit "Enter". If the barometric pressure differs by more than 0.2mmHg use the arrows to enter the correct barometric pressure. Note, barometric pressure changes are normal since it is not totally stable and especially since the instrument is recording down to the tenths of a millimeter of Hg. 16. The YSI 650MDS will count down and display the calibrated reading. Record the calibrated reading in the field calibration log book. 17. Use the escape (Esc) key to go backwards and get into the "sonde menu" and select "run" 18. Select "unattended sample" 19. Use the arrow to move down to file and enter the proper file name. (The file name will be the first letter of the tailrace; F=Falls, N=Narrows, T=Tuckertown, H=High Rock and the 6 digit date - mo/day/year). Then, hit enter key to make sure meter accepts the file name. 20. Record the new file you started under the date in the field log book. C. Pre-Data Collection Calibration 1. Check battery voltage, time etc. Record battery voltage in field calibration log book. Batteries are changed on a monthly basis along with the DO membrane. If battery voltage is below 8.0, change the batteries. 2. Fill a 5 gallon bucket with fresh tailrace water. 3. Place the YSI 6920 Sonde and the probe for the YSI 58 meter in the bucket. 4. Record DO and water temperature readings, while gently swirling water in the bucket, from both meters in the field log book 5. If the difference in DO is more than 0.5 mg/L between meters or the water temperature is more than 0.5 degree difference between meters, then re- perform this check with fresh tailrace water; remember to swirl the water in the bucket. 6. If differences in readings remain higher than 0.5 mg/L or 0.5 degree, replace the DO membrane or the probe. 7. If large differences in readings exist after replacing the DO membrane, then recondition the probe using the reconditioning instructions and if that does not work replace the YSI 6920 Sonde probe(s). 8. If replacing the probe does not resolve the issue, replace the YSI 6920 Sonde with a backup unit and take the problem Sonde to the office for further analysis and repair. D. Re-starting Data Collection 1. Once the Sonde readings are comparable to the YSI 58, the Sonde may be re-installed. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page A-3 Tailwater DO Monitoring Draft QAPP 2. Using arrow move down to "start logging" and push enter key 3. The meter will ask you if you are sure and select "yes" using enter key 4. Use escape key to go back to main menu 5. Unhook cable from Sonde and place cap back on and re-tape the small bulkhead cap that allows communication from 650MDS/computer to the sonde. Taping is a redundant way to protect the prongs inside the bulkhead. 6. Re-attach the YSI 6920 Sonde to the buoy using the lock and ring, and place the buoy back in the water. Record the time you reset the YSI 6920 in the filed log book. Sonde using the clock on the YSI 650MDS. E. Daily Post-Calibration Check of the handheld YSI 58 1. At the end of the day, or back at the office after a day trip, compare water temperature readings of the YSI 58 against a NIST thermometer. Record the readings on the Temperature Check form for that unit. If the difference exceeds more than 0.5 degree at either the high or low check points, then make a note to the Data Processor on the data QA transmittal form. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page A-4 Tailwater DO Monitoring Draft QAPP Attachment B: Standard Operating Procedures for Calibrating YSI 58 Meters used for Comparison with In Situ Field Instruments Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page B-1 Tailwater DO Monitoring Draft QAPP CALIBRATING DISSOLVED OXYGEN METER Meter Used to Compare Data Point at Retrieval of Sonde (This should be done before and after sampling) 1. Rinse off membrane and dry off with kim wipe. 2. Insert probe into cup and let sit for 15 minutes (make sure towel at bottom of cup is moist) 3. While waiting for 15 minutes to elapse, turn on machine and "zero" using zero knob - you can leave the instrument on after this has been done. 4. After 15 minutes has elapsed, turn knob to "temp" and record temperature on the calibration form for the corresponding YSI 58 meter contained in the field calibration log book along with your initials, date, and the barometric pressure from the 650MDS 5. Turn the knob to O.Olmg/L and get a reading. Place this reading in "Uncalibrated Reading" column of the calibration form 6. Using the barometric pressure, find the correct dissolved oxygen reading on the back of the meter and record in "Calibrated Reading" column of the calibration form 7. Unlock the 02 knob and dial in the correct value then lock the button 9. Turn off meter. Note -This instrument is to be used for comparing against long term monitors (sonde) in each tailrace for dissolved oxygen and temperature. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page B-2 Tailwater DO Monitoring Draft QAPP Attachment C: Procedures for Replacing a Dissolved Oxygen Membrane on In Situ Field Instruments Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page C-1 Tailwater DO Monitoring Draft QAPP Procedures for Replacing a Dissolved Oxygen Membrane on the YSI 6920s 1. Remove the probe guard from the sonde and hold it in a vertical position such that the sensors are upright. 2. Remove o-ring and old DO membrane and then clean probe tip with water and lens cleaning tissue. 3. Remove any debris/deposits from the o-ring groove. 4. Using the supplied bottle of electrolyte (KCl), place electrolyte on the DO probe until a high meniscus is formed. 5. Position the membrane parallel to the probe making sure all corners are supported. Using one continuous downward motion, stretch the membrane over the probe face. 6. Install o-ring by placing one side of the o-ring in the groove and rolling into place across the membrane and into the groove on the opposite side of the probe face. Avoid touching the probe face with your fingers. Make sure o-ring is securely in place by squeezing it every 90 degrees to equalize the tension. 7. Trim the excess membrane away with a scalpel or scissors making sure to stay 1/8 inch below the o-ring. 8. The finished product should have no bubbles or wrinkles. 9. Record the time and date of DO membrane replacement in the maintenance records section of the field calibration log book. Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page C-2 Tailwater DO Monitoring Draft QAPP Attachment D: DO Calibration Form Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page D-1 Tailwater DO Monitoring Draft QAPP N X O J R V J C O m .~ U C d O! K U C f6 C C . ~ y N O Z O " c ~_ ~ O ~ U N ~ ID ~ U ~ C a N .~ ~ ~ _ f0 ~ U ` ~ L r~+ Q ~ . ~ \ rn Q ~ o d ~ N E ~ ~ Z U ~ N ~ cA N '~ O ~ ~ f0 Q C0 fl. ~U ~ o H U N f0 Attachment E: Temperature Check Form Alcoa Power Generating Inc. May 2007 Yadkin Project (FERC No. 2197) Page E-1 Tailwater DO Monitoring Draft QAPP N _Q V ~ O ~ ~ V w v ~ ++ Z Q Q Z i ' v v ~, V m N ~ v I Q ~ II I ~ H I 7 _N I "a Z I i i I Q ~.;.~ M +~+ ', ~ +r ~ - -_ ', ~ ' c M I ~ ~ ++ QJ 'B ~ H I O I ' ~ t/1 Z I ' Q f'V I N +, ' +, -- ~ c I N '~ II ! ~ ~ N ~ ~ ¢ i i ~ to Q Z ~ I +, ~ N ~ ~ ++ II U ' w !I ~ 7 ~ ~, C ~ ~ I C C ~ ~ i C ~, ~ ~ '.. N ~ Z ~ I I I I I ~ I ~ N 'll N ~' ~ 'J rY1 ~ ~ I t 0 3 + + I _ z i if i if ~-- ~ i if f- L J J ~ N I ~I OI U Appendix B Summary of Consultation Yadkin Project Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Appendix C Consultation Record Yadkin Project Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007 Appendix D Comments Received on Draft Dissolved Oxygen Monitoring Plan and APGI's Responses Yadkin Project Draft Dissolved Oxygen Monitoring Plan FERC No. 2197 May 2007