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HomeMy WebLinkAboutNC0041530_Fact Sheet_20210202Fact Sheet NPDES Permit No. NC0041530 Permit Writer/Email Contact: Derek Denard / derek.denard@ncdenr.gov Date: 02Feb2021 Division/Branch: NC Division of Water Resources/Water Quality Permitting Section Compliance & Expediated Permitting Branch Permitting Action: Renewal ❑ Renewal with Expansion ❑ New Discharge ❑ Modification (Fact Sheet should be tailored to mod request) See Permit Application Attachment A: NC0041530 Renewal (Application)_20190411_10p Complete applicable sections below. If not applicable, enter NA. 1. Basic Facility Information Facility Information Applicant/Facility Name: Ocracoke Sanitary District Ocracoke Reverse Osmosis Water Treatment Plant (WTP) Applicant Address: PO Box 567, Ocracoke, NC 27960 Facility Address: 159 Water Plant Road, Ocracoke, NC 27960 Permitted Flow: Not limited Facility Type/Waste: Water Plants and Water Conditioning Discharge — Reverse Osmosis (RO) Concentrate and Softener Regeneration — Membrane Technology WTP System Facility Class: Grade I Physical Chemical WPCS Treatment Units: Not Applicable Pretreatment Program (Y/N) No County: Hyde Region Washington Briefly describe the proposed permitting action and facility background: This facility is a reverse osmosis (RO) - membrane technology water treatment system with discharge of wastewaters consisting of RO concentrate with a design potable flowrate of 0.900 MGD of high purity water, a backwash or reject flow rate of 0.45 MGD and a maximum monthly average reject flow rate of 0.184 MGD [See Attachment B]. Page 1 of 10 Chemical usage consists of the following: VITEC 1400 Antiscalant (for information see Attachment C for MSDS) and zinc phosphate. 2. Receiving Waterbodv Information: Receiving Waterbody Information Outfalls/Receiving Stream(s): Outfall 001 / Mary Ann's Pond (Pamlico Sound) Stream Segment: 29-89 Stream Classification: SA; HQW Drainage Area (mi2): NA Summer 7Q10 (cfs) Tidal Winter 7Q10 (cfs): Tidal 30Q2 (cfs): Tidal Average Flow (cfs): Tidal IWC (% effluent): NA 303(d) listed/parameter: Not listed [See Attachment D_2018 NC Integrated Report 072519 p1315] Subject to TMDL/parameter: Tar River TMDL / Nitrogen, Phosphorus Basin/Sub-basin/HUC: Tar -Pamlico / 03-03-08 / 030201050207 USGS Topo Quad: Ocracoke, NC Page 2of10 3. Effluent Data Summary Effluent data for Outfall 001 is summarized below for the period of Jun2017 through Jun2020. Table. Effluent Data Summary Outfall 001 (Compete table below or insert Excel Pivot Table.) Parameters Max Min Average Count PQL MA Conductivity 17200 14500 16541.7 12 Copper, Total (as Cu) 10 10 10 12 10 Flow, in conduit or thru treatment plant 0.2933 0.0018 0.1040 1112 Nitrite plus Nitrate Total (as N) 0.06 0.04 0.04 12 0.04 Nitrogen, Ammonia Total (as N) - Concentration 9.04 5.48 6.18 12 Nitrogen, Kjeldahl, Total (as N) 11.35 4.74 7.60 12 Nitrogen, Total - Concentration 11.39 4.8 7.65 12 Oxygen, Dissolved (DO) 8.22 4.09 5.69 41 pH 7.6 7 74 Phosphorus, Total (as P) - Concentration 0.87 0.2 0.37 12! Salinity 10.1 8.4 9.7 12 Solids, Total Dissolved 11650 9060 10376.7 12 _ Turbidity 6.7 0.16 1.68 41 1 25* DM UoM pmhos/cm pg/I mgd mg/I mg/I mg/I mg/I mg/I su mg/I ppth mg/I 25* ntu 6.8-8.5 PQL - Practical Quantitation Limit, MA - Monthly Average, DM - Daily Max, UoM - Units of Measurement, = previous permit limits 4. Instream Data Summary Instream monitoring may be required in certain situations, for example: 1) to verify model predictions when model results for instream DO are within 1 mg/1 of instream standard at full permitted flow; 2) to verify model predictions for outfall diffuser; 3) to provide data for future TMDL; 4) based on other instream concerns. Instream monitoring may be conducted by the Permittee, and there are also Monitoring Coalitions established in several basins that conduct instream sampling for the Permittee (in which case instream monitoring is waived in the permit as long as coalition membership is maintained). If applicable, summarize any instream data and what instream monitoring will be proposed for this permit action: NA. Is this facility a member of a Monitoring Coalition with waived instream monitoring (Y/N): No. Name of Monitoring Coalition: NA. 5. Compliance Summary Summarize the compliance record with permit effluent limits (past 5 years): No compliance issues with effluent limits have been noted. Summarize the compliance record with aquatic toxicity test limits and any second species test results (past 5 years): The facility experienced two (2) toxicity failures in November 2019 and December 2019. Then Jan 2020, Feb 2020, March 2020, and May 2020 were all passed. [See Attachment E: WET Testing Self Monitoring Summary HQ May 2020_p83] Summarize the results from the most recent compliance inspection: No compliance issues were noted from the August 15, 2019 inspection. [See Attachment F] Page 3of10 6. Water Quality -Based Effluent Limitations (WQBELs) Dilution and Mixing Zones In accordance with 15A NCAC 2B.0206, the following streamflows are used for dilution considerations for development of WQBELs: 1Q10 streamflow (acute Aquatic Life); 7Q10 streamflow (chronic Aquatic Life; non -carcinogen HH); 30Q2 streamflow (aesthetics); annual average flow (carcinogen, HH). If applicable, describe any other dilution factors considered (e.g., based on CORMIX model results): NA. If applicable, describe any mixing zones established in accordance with 15A NCAC 2B. 0204(b): NA. Oxygen -Consuming Waste Limitations Limitations for oxygen -consuming waste (e.g., BOD) are generally based on water quality modeling to ensure protection of the instream dissolved oxygen (DO) water quality standard. Secondary TBEL limits (e.g., BOD= 30 mg/1 for Municipals) may be appropriate if deemed more stringent based on dilution and model results. If permit limits are more stringent than TBELs, describe how limits were developed: NA. Ammonia and Total Residual Chlorine Limitations Limitations for ammonia are based on protection of aquatic life utilizing an ammonia chronic criterion of 1.0 mg/1 (summer) and 1.8 mg/1 (winter). Acute ammonia limits are derived from chronic criteria, utilizing a multiplication factor of 3 for Municipals and a multiplication factor of 5 for Non -Municipals. Limitations for Total Residual Chlorine (TRC) are based on the NC water quality standard for protection of aquatic life (17 ug/1) and capped at 28 ug/1(acute impacts). Due to analytical issues, all TRC values reported below 50 ug/1 are considered compliant with their permit limit. Describe any proposed changes to ammonia and/or TRC limits for this permit renewal: No changes. Reasonable Potential Analysis (RPA) for Toxicants If applicable, conduct RPA analysis and complete information below. The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall. The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of Y2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. A reasonable potential analysis was conducted on effluent toxicant data collected between Jun2017 through Jun2020. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, the following permitting actions are proposed for this permit: Page 4of10 • Monitoring Only. The following parameters will receive a monitor -only requirement since they did not demonstrate reasonable potential to exceed applicable water quality standards/criteria. All data for Total Copper was reported as no detection, <10 µg/L. Compliance with permit limit for Total Copper was not demonstrated with a PQL of 10 jig/L. A PQL of 2 µg/L or less would better demonstrate compliance. If applicable, attach a spreadsheet of the RPA results [See Attachment G] as well as a copy of the Dissolved Metals Implementation Fact Sheet for freshwater/saltwater [See Attachment H] to this Fact Sheet. Include a printout of the RPA Dissolved to Total Metal Calculator sheet if this is a Municipality with a Pretreatment Program. Toxicity Testing Limitations Permit limits and monitoring requirements for Whole Effluent Toxicity (WET) have been established in accordance with Division guidance (per WET Memo, 8/2/1999). Per WET guidance, all NPDES permits issued to Major facilities or any facility discharging "complex" wastewater (contains anything other than domestic waste) will contain appropriate WET limits and monitoring requirements, with several exceptions. The State has received prior EPA approval to use an Alternative WET Test Procedure in NPDES permits, using single concentration screening tests, with multiple dilution follow-up upon a test failure. Describe proposed toxicity test requirement: Acute Whole Effluent Toxicity (WET) testing - testing of Mysidopsis bahia (Mysid shrimp) shall be performed as 24-day pass/fail test at 90% effluent concentration, during February, May, August and November [See A. (2.)]. Mercury Statewide TMDL Evaluation There is a statewide TMDL for mercury approved by EPA in 2012. The TMDL target was to comply with EPA's mercury fish tissue criteria (0.3 mg/kg) for human health protection. The TMDL established a wasteload allocation for point sources of 37 kg/year (81 lb/year), and is applicable to municipals and industrial facilities with known mercury discharges. Given the small contribution of mercury from point sources (-2% of total load), the TMDL emphasizes mercury minimization plans (MMPs) for point source control. Municipal facilities > 2 MGD and discharging quantifiable levels of mercury (>1 ng/1) will receive an MMP requirement. Industrials are evaluated on a case -by -case basis, depending if mercury is a pollutant of concern. Effluent limits may also be added if annual average effluent concentrations exceed the WQBEL value (based on the NC WQS of 12 ng/1) and/or if any individual value exceeds a TBEL value of 47 ng/1 Describe proposed permit actions based on mercury evaluation: NA. Other TMDL/Nutrient Management Strategy Considerations If applicable, describe any other TMDLs/Nutrient Management Strategies and their implementation within this permit: This facility is not a member of the Tar Pamlico Basin Association. The appropriate special condition text will be added. TN and TP quarterly monitoring are required because of the Tar River TMDL for Nitrogen, Phosphorus. Page 5 of 10 Other WQBEL Considerations If applicable, describe any other parameters of concern evaluated for WQBELs: NA. If applicable, describe any special actions (HQW or ORW) this receiving stream and classification shall comply with in order to protect the designated waterbody: Mary Ann's Pond (Pamlico Sound) is currently classified SA; HQW. As a safety factor, one-half the normal standard was used in the RPA for toxicant limitations. If applicable, describe any compliance schedules proposed for this permit renewal in accordance with 15A NCAC 2H.0107(c) (2) (B), 40CFR 122.47, and EPA May 2007 Memo: NA. If applicable, describe any water quality standards variances proposed in accordance with NCGS 143- 215.3(e) and 15A NCAC 2B. 0226 for this permit renewal: NA. 7. Technology -Based Effluent Limitations (TBELs) Not applicable 8. Antidegradation Review (New/Expanding Discharge): The objective of an antidegradation review is to ensure that a new or increased pollutant loading will not degrade water quality. Permitting actions for new or expanding discharges require an antidegradation review in accordance with 15A NCAC 2B.0201. Each applicant for a new/expanding NPDES permit must document an effort to consider non -discharge alternatives per 15A NCAC 2H.0105( c)(2). In all cases, existing instream water uses and the level of water quality necessary to protect the existing use is maintained and protected. If applicable, describe the results of the antidegradation review, including the Engineering Alternatives Analysis (EAA) and any water quality modeling results: NA. 9. Antibacksliding Review: Sections 402(o)(2) and 303(d)(4) of the CWA and federal regulations at 40 CFR 122.44(1) prohibit backsliding of effluent limitations in NPDES permits. These provisions require effluent limitations in a reissued permit to be as stringent as those in the previous permit, with some exceptions where limitations may be relaxed (e.g., based on new information, increases in production may warrant less stringent TBEL limits, or WQBELs may be less stringent based on updated RPA or dilution). Are any effluent limitations less stringent than previous permit (YES/NO): YES. If YES, confirm that antibacksliding provisions are not violated: Acute WET Testing relaxed to monitoring based on WTP permitting strategy. 10. Monitoring Requirements Monitoring frequencies for NPDES permitting are established in accordance with the following regulations and guidance: 1) State Regulation for Surface Water Monitoring, 15A NCAC 2B.0500; 2) Page 6 of 10 NPDES Guidance, Monitoring Frequency for Toxic Substances (7/15/2010 Memo); 3) NPDES Guidance, Reduced Monitoring Frequencies for Facilities with Superior Compliance (10/22/2012 Memo); 4) Best Professional Judgement (BPJ). Per US EPA (Interim Guidance, 1996), monitoring requirements are not considered effluent limitations under Section 402(o) of the Clean Water Act, and therefore anti - backsliding prohibitions would not be triggered by reductions in monitoring frequencies. For instream monitoring, refer to Section 4. 11. Electronic Reporting Requirements The US EPA NPDES Electronic Reporting Rule was finalized on December 21, 2015. Effective December 21, 2016, NPDES regulated facilities are required to submit Discharge Monitoring Reports (DMRs) electronically. Effective December 21, 2020, NPDES regulated facilities will be required to submit additional NPDES reports electronically. This permit contains the requirements for electronic reporting, consistent with Federal requirements. 12. Summary of Proposed Permitting Actions: A. Table. Current Permit Conditions and Proposed Changes — Outfall 001 Parameter Current Permit Proposed Change Basis for Condition/Change Flow Monitor & Report No change 15A NCAC 2B .0505 pH 6.8 — 8.5 SU No change WQBEL. State WQ standard, 15A NCAC 2B .0200 Turbidity Monitor & Report No change from previous. Draft was 2/month. For final changed back to monthly for consistency with the WTP permitting strategy for non - limited parameters WQBEL. State WQ standard, 15A NCAC 2B .0200 Dissolved Oxygen (DO) Monitor & Report No change WQBEL. State WQ standard, 15A NCAC 2B .0200 Salinity Monitor & Report No change WQBEL. State WQ standard, 15A NCAC 2B .0200 Conductivity Monitor & Report No change Parameter of Concern WTP Permitting Strategy Total Dissolved Solids (TDS) Monitor & Report No change Parameter of Concern WTP Permitting Strategy Page 7 of 10 Ammonia Nitrogen Monitor & Report No change WQBEL. Based on protection of State WQ criteria. 15A NCAC 2B.0200 TKN NO3-N + NO2-N TN Monitor & Report No change WQBEL. Required individual TN/TP nutrient limits per 2015 Tar- Pamlico permitting strategy, and to comply with NC chl-a WQS. 15A NCAC 2B.0200 Total Phosphorus Monitor & Report No change WQBEL. Required individual TN/TP nutrient limits per 2015 Tar - Pamlico permitting strategy and to comply with NC chl-a WQS, 15A NCAC 2B.0200. Total Copper Monitor & Report No change WQBEL. State WQ standard, 15A NCAC 2B .0200 Total Zinc Not required Added monitoring WQBEL. State WQ standard, 15A NCAC 2B .0200 Added because of usage of Zinc - orthophosphate or Sweetwater CP1236 base on WP Permitting strategy. For final changed to optional since it is added only to potable water as a corrosion inhibitor. Acute WET Testing Limited Changed to Monitoring only Acute WET Testing relaxed to monitoring only based on WTP permitting strategy. WQBEL. No toxics in toxic amounts. 15A NCAC 2B.0200 and 15A NCAC 2B.0500 ELECTRONIC REPORTING OF MONITORING REPORTS Required Updated In accordance with EPA Electronic Reporting Rule 2015. PERMIT RE- OPENER: WHOLE EFFLUENT TOXICITY Required No change WTP permitting strategy PERMIT RE- OPENER: NUTRIENT REDUCTION REQUIREMENT Required No change Tar -Pamlico Nutrient Sensitives Waters (NSW) Implementation Strategy MGD — Million gallons per day, MA - Monthly Average, WA — Weekly Average, DM — Daily Max Page 8 of 10 The draft permit includes the following significant changes from the existing permit: 1. The facility classification Physical Chemical Not Classified Water Pollution Control System (WPCS) was added to the effluent page. 2. Acute WET Testing relaxed to monitoring only based on WTP permitting strategy. 3. Since the renewal application indicated the use of Zinc -orthophosphate or sweetwater CP1236, quarterly Total Zinc monitoring was added. 13. Public Notice Schedule: Permit to Public Notice: September 1, 2020 [See Attachment I] Per 15A NCAC 2H .0109 & .0111, The Division will receive comments for a period of 30 days following the publication date of the public notice. Any request for a public hearing shall be submitted to the Director within the 30 days comment period indicating the interest of the party filing such request and the reasons why a hearing is warranted. 14. Fact Sheet Addendum (if applicable): Were there any changes made since the Draft Permit was public noticed (Yes/No): Yes. If Yes, list changes and their basis below: This final permit includes the following changes from the draft permit previously sent to you on August 13, 2020. 1. Monitoring for Turbidity has been changed from 2/Month to Monthly for consistency with the WTP permitting strategy for non -limited parameters. 2. Total Zinc monitoring has been changed to optional since it is added only to potable water as a corrosion inhibitor. The following footnote has been added: Zinc: This requirement applies only to wastewater discharges that use water treated with zinc orthophosphate. Page 9 of 10 15. Fact Sheet Attachments (list in order of reference): A. NC0041530 Renewal (Application)_20190411_10p B. B_NC0041530 DMR Flow Data_Jun2017_Jun2020_lp C. MSDSus-avista-sds-vitec1400v10.201611p D. 2018 NC Integrated Report 072519 p1315 E. WET Testing Self Monitoring Summary HQ May 2020 p83 F. NC0041530 Compliance Report _20190816_5p G. NC0041530 RPA 2020_4p H. Fact Sheet Memo SW - Final 6-24-20163p I. Ocracoke Observer _20200901_lp J. Peer Review Mail_20200807_lp K. Permittee Comments Electronic Transmittal Approval_20200813_3p L. Permittee Receipt of final_ Electronic Transmittal_2p Page 10 of 10 ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Director David G. Tolson, Plant & System Manager Ocracoke Sanitary District PO Box 567 Ocracoke, NC 27960-0567 Subject: Permit Renewal Application No. NC0041530 Ocracoke Reverse Osmosis WTP Hyde County NORTH CAROLINA Environmental Quality April 23, 2019 Dear Applicant: The Water Quality Permitting Section acknowledges the April 23, 2019 receipt of your permit renewal application and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW permitting branch. Per G.S. 150B-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a timely manner to requests for additional information necessary to allow a complete review of the application and renewal of the permit. Information regarding the status of your renewal application can be found online using the Department of Environmental Quality's Environmental Application Tracker at: https://deq.nc.gov/permits-regulations/permit-guidance/environmental-application-tracker If you have any additional questions about the permit, please contact the primary reviewer of the application using the links available within the Application Tracker. Sincerely, Wren Thed ord Administrative Assistant Water Quality Permitting Section ec: WQPS Laserfiche File w/application North Carobna Department of Environmental Quality I DivSan of Water Resources Washington Regional Office 1943 Washington Square Mali I Washington, North Cs67ur6s 27889 252-94S-34S i OCRACOKE SANITARY DISTRICT P. O. BOX 567 OFFICE 252-928-5791 #159 WATER PLANT ROAD PLANT/FAX 252-928-6651 OCRACOKE, NC 27960 April 11, 2019 NC DENR Division of Water Quality NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: Permit Number NC0041530, Ocracoke Sanitary District, Hyde County APR 232019 Water Resources PsrmitZing Section The Ocracoke Sanitary District is requesting renewal of NPDES Permit No. NC0041530. Enclosed are an original and two copies of this letter. Also enclosed are an original and two copies of the completed application a schematic of wastewater flow and location map. Ocracoke Sanitary District uses Reverse Osmosis (RO) to treat its raw water at 65% product - drinking water to 35% waste - reject water. The RO process has no sludge. which explains why Ocracoke Sanitary District has no facility sludge management plan. if you have any questions, or need more information. please contact this office. Sincerely. David G.Tolson Plant & Systems Manager EFFLUENT NPDES PERMIT APPLICATION - SHORT FORM C - WTP For discharges associated with water treatment plants Mail the complete application to: N. C. Department of Environment and Natural Resources Division of Water Quality / NPDES Unit 1617 Mail Service Center, Raleigh, NC 27699-1617 NPDES Permit Number NC0041530 If you are completing this form in computer use the TAB key or the up - down arrows to move from one field to the next. To check the boxes, click your mouse on top of the box. Otherwise, please print or type. 1. Contact Information: Owner Name Facility Name Mailing Address City State / Zip Code Telephone Number Fax Number e-mail Address OCRACOKE SANITARY DISTIRCT OCRACOKE SANITARY DISTRICT P. O. BOX 567, 159 WATER PLANT ROAD OCRACOKE NORTH CAROLINA, 27960 252-928-5791 252-928-6651 Ocracokeh2oavahoo. com 2. Location of facility producing discharge: Check here if same as above X Street Address or State Road City State / Zip Code County 3. Operator Information: Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the Operator in Responsible Charge or ORC) Name Mailing Address City State / Zip Code Telephone Number Fax Number OCRACOKE SANITARY DISTRICT BOARD OF COMMISSIONERS P. O. BOX 567 OCRACOKE NORTH CAROLINA, 27960 252-928-5791 252-928-6651 Page 1 of 4 Version 5/2012 NPDES PERMIT APPLICATION - SHORT FORM C - WTP For discharges associated with water treatment plants 4. Ownership Status: Federal ❑ State ❑ Private ❑ Public ❑ A SANITARY DISTRICT IS A POLICATL SUBDIVISION OF THE STATE & A LEGAL ENTITY & A SPECIAL DISTRICT. IT IS A GOVERNMENTAL UNIT OPERATED BY AN ELECTED BOARD OF COMMISSIONERS. 5. Type of treatment plant: ❑ Conventional (Includes coagulation, flocculation, and sedimentation, usually followed by filtration and disinfection) ❑ Ion Exchange (Sodium Cycle Cationic ion exchange) ❑ Green Sand Filter (No sodium recharge) X Membrane Technology (RO, nanofiltration) Check here if the treatment process also uses a water softener 6. Description of source water(s) (i.e. groundwater, surface water) GROUND WATER - DEEP WELLS 7. Describe the treatment process(es) for the raw water: WATER IS DRAWN FROM WELLS AND GOES THROUGH 3 UM PREFILTERS, THEN HIGH PRESSURE PUMPS PUSH WATER THRU REVERSE OSMOSIS MEMBRANES WHEICH ARE 3 STAGE. POTABLE WATER GOES TO AERATOR, DENTENTION TANK AND THEN IS CHLORINATED AND HIGH PRESSURE PUMPS SEND IT TO ELEVATED TANK AND THE DISTRIBUTION SYSTEM. 1 8. Describe the wastewater and the treatment process(es) for wastewater generated by the facility: REJECT WATER GOES IN A DRAIN PIPE AND IS PUMPED TO THE PAMLICO SOUND. THERE IS NO TREATMENT. OUT OF EVERY 100 GALLONS FROM WELL ARRPDX. 65% BECOMES POTABLE AND 35% GOES TO PAMLICO SOUND. 9. Number of separate discharge points: 1 Outfall Identification number(s) OU 1_ 10. Frequency of discharge: Continuous 1 1 Intermittent X If intermittent: Days per week discharge occurs: _ i Duration: 3 TO 18 HOURS PER DAY 11. Plant design potable flowrate .900 MGD Backwash or reject flow 0.45 MGD 12. Name of receiving stream(s) (Provide a map showing the exact location of each outfall, including latitude and longitude): PAMLICO SOUND IN TAR-PAMLICO RIVER BASIN Page 2 of 4 Version 5/2012 NPDES PERMIT APPLICATION - SHORT FORM C - WTP For discharges associated with water treatment plants 13. Please list all water treatment additives, including cleaning chemicals or disinfection treatments, that have the potential to be discharged. Alum / aluminum sulfate Iron sulfate / ferrous sulfate Fluoride Yes No X Ammonia nitrogen / Chloramines Yes No X Yes No X Yes No X Zinc -orthophosphate or sweetwater CP1236 Yes X No List any other additives below: VITEC 1400 ANTISCALANT 14. Is this facility located on Indian country? (check one) Yes D No X 15. Additional Information: Provide a schematic of flow through the facility, include flow volumes at all points in the water treatment process. The plan should show the point[s] of addition for chemicals and all discharges routed to an outfall [including stormwater]. Solids Handling Plan REVERSE OSMOSIS PROCESS HAS NOT SLUDGE OR SOLIDS 16. NEW Applicants Information needed in addition to items 1-15: New applicants are highly encouraged to contact a permit coordinator with the NCDENR Customer Service Center. Was the Customer Service Center contacted? ❑ Yes ❑ No Analyses of source water collected Engineering Alternative Analysis Discharges from Ion Exchange and Reverse Osmosis plants shall be evaluated using a water quality model. 17. Applicant Certification I certify that I am familiar with the information contained in the application and that to the best of my knowledge and belief such information is true, complete, and accurate. DAVID G. TOLSON PLANT & SYSTEMS MANAGER Printed name of Person Signing Title Signature of Applicant Date Page 3 of 4 Version 5/2012 NPDES PERMIT APPLICATION - SHORT FORM C - WTP For discharges associated with water treatment plants North Carolina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false statement representation, or certification in any application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both, for a similar offense.) Page 4of4 Version 5/2012 Permit #NC0041530 Ocracoke Sanitary District Hyde County NC LOCATION MAP ROAD CLASSIFICATION PRIMARY HIGHWAY HARD SURFACE LIGHT-CUTY ROAD, HARD OR IMPROVED SURFACE SECONDARY HIGHWAY HARD SURFACE Cap UNIMPROVED ROAD Latitude 35°06'58" Map # C35sW Stream Class Longitude Sub -basin SA 75°59'19" 30155 Discharge Codes 22 Receiving Stream Pamlico Sound Design Q 0.45 MGD Permit expires 12/31/02 SCALE 1:24 000 a'�N<hMC`.Y�\q' <a`M`A\CtM:ttCr•r.. F:�:a�.:::�i:v.:�:a'.. 1 C 15zr—sii CONTOUR INTERVAL 5 FEET QUAD LOCATION 1 MILE mvrsaxaroaca�a\ce 7000 FEET 1 KILOMETER Ocracoke Sanitary District NC0041530 Hyde County OCRACOKE SANITARY DISTRICT P. O. BOX 567 OFFICE 252-928-5791 #159 WATER PLANT ROAD PLANT/FAX 252-928-6651 OCRACOKE, NC 27960 SUMMARY OF OCRACOKE SANITARY DISTRI(1 WATER PLANT TYPE OF PLANT - REVERSE OSMOSIS BEGAN OPERATION - JUNE 1977 SOURCE - DEEP WELLS 620' & 640' DEEP (CASTLE HAYNE AQUIFER) YEAR ROUND WELL WATER TEMPERATURE 73 F NUMBER OF METERS - ORIGINALLY - 349 CURRENTLY - 1277 MAXIMUM DAILY PRODUL I ION - 835,200 GALS. / 24 HOURS OR 580 GPM MONTHLY USAGE - MINIMUM - 2,100,000 MAXIMUM - 8,300,000 AVERAGE DAILY USE - MINIMUM 80,000 GPD MAXIMUM 350,000 GPD PLANT UPGRADES & ADDITIONS - 7 (1980, 1987, 1993, 1995, 2000, 2003, 2010-11) AVERAGE COST TO PRODUCE - $12.83 / 1,000 GALLONS REVERSE OSMOSIS UNITS - 9 RO'S 1-6 60 GPM RO'S 7-9 75 GPM (PUT INTO OPERATION JULY 2011) MEMBRANES - FILMTEC BW30-8040 HIGH PRESSURE PUMPS - 9 EACH WITH 40 HSP MOTOR PREFILTERS - 2 EACH HAS 21 3 UM FILTERS 30" LONG 2" DIAMETER WELLS - ONLY 1 WELL USED AT A TIME / WELL 1 CONNECTED TO EMERGENCY GENERATOR WELL #1 - PUMP 40' DEEP 600 GPM WELL #2 - PUMP 80' DEEP 1,000 GPM WELL #3 - PUMP 80' DEEP 1,000 GPM ELEVATED TANK CAPACITY - 150,000 GALLONS GROUND STORAGE CAPACITY - 400,000 GALLONS (2 200,000 GALLON CONCRETE TANKS) OSDSUMMARY PRODUCT WATER LEAVES PLANT AND GOES TO FORCED AIR AERATOR ON DETENTION TANK (DT) 2 OR STATIC AIR AERATOR ON DT 1. THIS EXPELS THE HYDROGEN SULFIDE (H2S) AND ADDS OXYGEN (02). HIGH SERVICE PUMPS - 2 MAXIMUM GPM 1,000 GALLONS EACH CHEMICALS ADDED - CHLORINE AT 1 PPM, ZINC .3 PPM AND AN ANTI-SCALENT. THE WATER SYSTEM IS RUN AND OPERATED BY THE OCRACOKE SANITARY DISTRICT WHICH WAS CREATED IN MAY 1972. A SANITARY DISTRICT IS A POLITICAL SUBDIVISION OF THE STATE OF NORTH CAROLINA UNDER ARTICLE 2, PART 2 OF THE GENERAL STATUES OF NORTH CAROLINA SEC I ION 130A-47 TO 130A-87. THERE IS A FIVE MEMBER ELECTED BOARD OF COMMISSIONERS THAT SET POLICY AND OVERSEE THE OPERATION OF A SANITARY DISTRICT. CURRENTLY THERE ARE 6 EMPLOYEES 5 WHO OPERATE THE PLANT AND TAKE CARE OF THE DISTRIBUTION SYSTEM AND 1 OFFICE EMPLOYEE. OCRACOKE SANITARY DISTRICT IS LOCATED ON OCRACOKE ISLAND, AND IS PART OF THE OUTER BANKS OF NORTH CAROLINA AND IS IN HYDE COUNTY. AT PRESENT OCRACOKE IS NOT AN INCORPORATED TOWN. OCRACOKE VILLAGE IS LOCATED ON THE SOUNDSIDE OF THE WIDEST AND SOUTHERNMOST PART OF THE ISLAND. EXCEPT FOR THE VILLAGE, THE REST OF THE ISLAND IS PART OF THE CAPE HATTERAS NATIONAL SEASHORE RECREATION AREA. OCRACOKE IS DEPENDENT ON FERRY SERVICE FOR ACCESSIBILITY. OCRACOKE IS A RESORT AREA WITH A YEAR ROUND POPULATION OF APPROXIMATELY 900 PERSONS AND A SEASONAL POPULATION OF 12,000 TO 18,000 PERSONS. OSDSUMMARY P r 11 c t i RAW OCRACOKE SANITARY DISTRICT FLOW CHART HPP MOTOR DRILL DEPTH 620 ' PUMP DEPTH 40 ' YEAR ROUND TEMP 73 F pH "5 TDS 3600 OSD only uses ONE WELL at a TL'4IE 9 HIGH PRESSURE PUMPS 40 HP MOTORS OUTLET PRESSURE OF 388 PSIG 9 RO UNITS 21 MEMBRANES EACH 65% PRODUCT; 35% REJECT DT 2 200,000 GALS DETENTION TANK v. ► HSP I 1 VFDat523Hz 0 HSP 2 DT I 200.000 GALS 1 DETENTION f TANK System Pressure 55 psiz • ► R E J E C T LEVA Nit AIREJECT WATER (WASTE) IS PUT IN THE PAMLICO SOUND Annimmomm♦ 150.000 GALS 130 ft. tall 128 ft full 100 fi empty MkIER OM .a MINI E. Parameter Flow, in conduit or thru treatment plant Row Labels Average of Measurement 2017 Jun 0.1430 Jul 0.1558 Aug 0.1237 Sep 0.1026 Oct 0.0991 Nov 0.0734 Dec 0.0640 2018 _ Jan 0.0793 Feb 0.0508 Mar 0.0649 Apr 0.0912 May 0.1161 Jun 0.1604 Jul 0.1766 Aug 0.1536 Sep 0.0926 Oct 0.1011 Nov 0.0832 Dec 0.0684 2019 Jan 0.0679 Feb 0.0497 Mar 0.0626 Apr 0.1013 May 0.1234 Jun 0.1639 Jul 0.1838 Aug 0.1667 Sep 0.1202 Oct 0.0781 Nov 0.0742 Dec 0.0662 2020 Jan 0.0776 Feb 0.0811 Mar 0.0847 Apr 0.0703 May 0.1114 Jun 0.1440 Max Monthly Avg 0.1838 4 t A -vista Vitec® 1400 T EC H N 0 LOG I ES SAFETY DATA SHEET 1. Company and Product Identification Identification — Product Name: Other means of identification Synonym: Recommended Use of the Chemical and Restrictions On Use: Name, Address, And Telephone Number of the Manufacturer, or Other Responsible Party: 1.4 Competent Person email address 24 Hour Emergency No.: 1.5 CERTIFIED BY NSF INTERNATIONAL TO NSF/ANSI 60 AS STANDARD DRINKING WATER TREATMENT CHEMICAL FOR USE IN REVERSE OSMOSIS SYSTEMS AT A MAXIMUM LEVEL OF 30 mg/I. NsFeArvel so Vitec® 1400 Organic Amine salt Mixture, none Reverse osmosis membrane online antiscalant Use only as directed on the label. AVISTA TECHNOLOGIES 140 Bosstick Street San Marcos, CA 92069 (760) 744-0536 klindsey@avistatech.com 1-800-424-9300 (United States) 1-703-527-3887 (International Collect) 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is a clear, colorless to amber liquid. Depending on the duration of contact, over- exposures can be harmful to the skin or eyes and respiratory system, or cause injury. This product is neither reactive nor flammable. Thermal decomposition of this product produces irritating vapors and toxic gases (e.g. carbon monoxide, carbon dioxide, oxides of nitrogen and sodium). Emergency responders must wear personal protective equipment (and have appropriate fire -extinguishing protection) suitable for the situation to which they are responding. Physical Hazards Summary Potential Health Hazards Summary Potential Ecological Effects Summary 2.1 Classification Of Product U.S. OSHA classification Classification as per EC 1272/2008 (CLP/GHS) WHMIS classification None Acute toxicity, oral, Category 4 Acute toxicity, dermal, Category 4 None Acute toxicity, Acute toxicity, Acute toxicity, Acute toxicity, Xi Irritant Acute toxicity, Acute toxicity, oral, Category 4 dermal, Category 4 oral, Category 4 dermal, Category 4 oral, Category 4 dermal, Category 4 Vitec® 1400 PUBLIC GHS SDS PAGE 1 OF 11 Hazardous Materials Information System (HMIS) Rating 2.2 Label Elements OSHA/GHS General Warnings Signal Word Hazard statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use P403 Store in a well -ventilated place. P233 Keep container tightly closed WARNING H317 Harmful in contact with skin H312 Harmful if inhaled Precautionary statements P280 P305 P351 P338 P310 Hazard pictograms 2.3 Unclassified Hazards None 2.4 Ingredients with unknown acute None toxicity Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INGESTED or INHALED Immediately call a POISON CENTER or doctor/physician. Vitec° 1400 PUBLIC GHS SDS PAGE 2 OF 11 3. COMPOSITION and INFORMATION ON INGREDIENTS Chemical name CAS # EINECS # % w/w US OSHA GHS/EU CLP WHMIS Chelate agent 1 Proprietary Proprietary 10 - 15 Acute toxicity, oral, Category 3 Acute toxicity, dermal, Category 3 Skin Corrosive category 1B Serious eye damage, category 1 Acute toxicity, oral, Category 3 Acute toxicity, dermal, Category 3 Skin Corrosive category 1B Serious eye damage, category 1 Acute toxicity, oral, Category 3 Acute toxicity, dermal, Category 3 Skin Corrosive category 1B Serious eye damage, category 1 Chelate agent 2 Proprietary Proprietary 5 - 10 Severe skin corrosion Category 1 Serious Eye Damage Category 1 Metal Corrosion, Category 1 H314 Causes severe skin bums and eye damage H319 Causes serious eye damage H290 May cause corrosion to metals. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Severe skin corrosion Category 1 Serious Eye Damage Category 1 Metal Corrosion, Category 1 H314 Causes severe skin bums and eye damage H319 Causes serious eye damage H290 May cause corrosion to metals. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Severe skin corrosion Category 1 Serious Eye Damage Category 1 Metal Corrosion, Category 1 H314 Causes severe skin burns and eye damage H319 Causes serious eye damage H290 May cause corrosion to metals. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. PRODUCT Acute toxicity, oral, Category 4 Acute toxicity, dermal, Category 4 NE = Not Established. C = Ceiling Limit. See Section 16 for Definitions of Terms Used. 4. FIRST -AID MEASURES 4.1 Description of Necessary Measures Skin exposure: If this product contaminates the skin, immediately begin decontamination with running water. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim should seek immediate medical attention if any adverse exposure symptoms develop. Eye exposure: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes Minimum flushing is for 15 minutes. Victim must seek medical attention. Inhalation: If mist of this product are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. Ingestion: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. DO NOT INDUCE VOMITING. Have victim rinse mouth with water, if conscious. Never induce vomiting or give a diluent (e.g., water) to someone who is unconscious, having convulsions, or unable to swallow. If contaminated individual is convulsing, maintain an open airway and obtain immediate medical attention. Vitec° 1400 PUBLIC GHS SDS PAGE 3 OF 11 4.2 Most Important Symptoms/Effects: Immediate: Inhalation exposure may cause coughing or sneezing. Symptoms of skin and eye contact may include redness and irritation. Ingestion may cause stomach pains, cramps, and gastritis. Delayed: Prolonged or repeated skin overexposure to this product may cause dermatitis (dry, red skin). Symptoms may include tingling, redness, and visible injury. 4.3 Indication Of Immediate Medical TARGET ORGANS: Acute: Skin, eyes, respiratory system. Attention And Special Treatment Needed, Chronic: Skin, eyes, respiratory system If Necessary: Victims of chemical exposure must be taken for medical attention if any adverse effects occur. Rescuers should be taken for medical attention if necessary. Take a copy of label and SDS to physician or health professional with victim. 5. FIRE -FIGHTING MEASURES Flammable properties Non-flammable aqueous solution 5.1 Suitable And Unsuitable Extinguishing Media: 5.2 Specific Hazards Arising From Chemical: 5.3 Special Protective Equipment And Precautions For Fire -Fighters: Flash Point °C: Not applicable. NFPA RATING FLAMMABILITY HEALTH OTHER See Section 16 for definitions of ratings REACTIVITY Autoignition Temperature °C: Not applicable. Flammable Limits (in air by volume, %): Upper: Not applicable. Lower: Not applicable. This material will not contribute to the intensity of a fire. Use extinguishing material suitable to the surrounding fire. Water spray YES Carbon dioxide YES Foam YES Dry chemical YES Halon YES Other YES When involved in a fire, this material may decompose and produce irritating fumes and toxic gases (e.g., carbon monoxide, carbon dioxide, and nitrogen oxides). Explosion Sensitivity to Mechanical Impact: Not applicable. Explosion Sensitivity to Static Discharge: Not applicable. Incipient fire responders should wear eye protection. Structural firefighters must wear Self -Contained Breathing Apparatus and full protective equipment. Move containers from fire area if it can be done without risk to personnel. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. Vitec° 1400 PUBLIC GHS SDS PAGE 4 OF 11 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions Uncontrolled releases should be responded to by trained personnel using pre - planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Protective equipment For small releases (< 20 L), clean up spilled liquid wearing gloves, goggles, faceshield, and suitable body protection. The minimum Personal Protective Equipment recommended for response to non -incidental releases (more than 20 L) should be Level C: triple -gloves (neoprene gloves and nitrile gloves over latex gloves), chemical resistant suit and boots, hard hat, and full -face respirator with Amine and HEPA filter. Emergency procedures Monitoring must indicate that exposure levels are below those provided in Section 8 (Exposure Controls -Personal Protection) and that oxygen levels are above 19.5% before anyone is permitted in the area without Self -Contained Breathing Apparatus. 6.2 Methods and Materials for Containment Vacuum or soak- up liquid for recovery/disposal. Neutralize residue with and Cleaning Up sodium bicarbonate or other neutralizing agent for acids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residues in a suitable plastic container. Dispose of in accordance with applicable U.S. Federal, State, or local procedures, or appropriate local standards (see Section 13, Disposal Considerations). 7.1 Precautions for Safe Handling 7.2 Conditions For Safe Storage 7. HANDLING and STORAGE All employees who handle this material should be trained to handle it safely. Open containers carefully on a stable surface. Empty containers may contain residual liquid; therefore, empty containers should be handled with care. As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat or drink while handling this material. Avoid generating dust of this product. Remove contaminated clothing immediately. During equipment maintenance follow practices indicated in Section 6 (Accidental Release Measures) to decontaminate equipment or clean-up small spills. Make certain that application equipment is locked and tagged -out safely if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or appropriate local standards. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials. Material should be stored in secondary containers, or in a diked area, as appropriate. Storage and use areas should be covered with impervious materials. Keep container tightly closed when not in use. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. Incompatibilities Bases, oxidizers, metals Vitec° 1400 PUBLIC GHS SDS PAGE 5 OF 11 8. EXPOSURE CONTROLS - PERSONAL PROTECTION 8.1 Control Parameters CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR ACGIH-TLVs OSHA-PELs IDLH mg/m3 OTHER mg/m3 TWA mg/m3 STEL mg/m3 TWA mg/m3 STEL mg/m3 Chelate agent 1 Proprietary 10-15 NE NE NE NE NE NE Chelate agent 2 Proprietary 5-10 NE NE NE NE NE NE Water and other components which are present in less than 1 percent concentration (0.1% concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers and mutagens). Balance None of the other components contribute significant additional in this product. All pertinent hazard information has been requirements of the Federal Occupational Safety and Health 1910.1200), U.S. State equivalent Standards and Canadian Identification System Standards (CPR 4). hazards at the concentration present provided in this document, per the Administration Standard (29 CFR Workplace Hazardous Materials 8.2 Appropriate Engineering Controls. 8.3 Personal Protective Equipment Respiratory protection: Eye protection: Hand protection: Body protection: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in this Section or as low as reasonably practical. Ensure eyewash/safety shower stations are available near areas where this product is used. None needed under normal conditions of use. Use NIOSH approved respirators if ventilation is inadequate to control mists or vapor. If respiratory protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the applicable local standards. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full -face piece pressure/demand SCBA or a full -face piece, supplied air respirator with auxiliary self-contained air supply is required under OSHA' s Respiratory Protection Standard (1910.134-1998). Use approved safety goggles or safety glasses, as described in OSHA 29 CFR 1910.133. Splash goggles with a faceshield may be needed if splash hazards exist. Wear chemical impervious gloves (e.g., SolvexTM, Neoprene). If needed, use body protection appropriate for task (e.g., Tyvek suit, rubber apron) to protect from splashes and sprays. 9. PHYSICAL and CHEMICAL PROPERTIES Appearance Odor Freezing Point °C Initial Boiling Point °C Flammability Vapor Density (air = 1) Solubility (in water) Viscosity Decomposition Temperature How To Detect This Substance (Warning Properties): This product is a clear, colorless to amber liquid. Light disinfectant odor <0 > 100 Non-flammable N/A Soluble Similar to water NE Litmus paper will t Odor Threshold pH Boiling Point Range °C Evaporation Rate (water = 1) Vapor Pressure mm Hg @ 20°C: Relative density (water = 1) Oil -Water Partition Coefficient NE 4.1 — 4.7 N/A Similar to water 18-20 1.05 — 1.10 N/A urn orange -red in contact with solutions of this product. Vitec° 1400 PUBLIC GHS SDS PAGE 6 OF 11 10. STABILITY and REACTIVITY 10.1 Reactivity Not considered reactive. 10.2 Chemical Stability Stable 10.3 Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4 Conditions to avoid Avoid mixing with incompatible materials. 10.5 Incompatible Materials Bases, oxidizers, metals 10.6 Hazardous Decomposition Products Thermal decomposition of this product may generate nitrogen oxides, carbon monoxide and carbon dioxide. 11. TOXICOLOGICAL INFORMATION Toxicity data for hazardous ingredients Oral LD50 mg/kg Dermal LD50 mg/kg Inhalation LD50 mg/kg Chelate agent 1 N/A N/A N/A Chelate agent 2 LD50 (Oral -Rat) 2100 mg/kg LD50 (Skin -Rabbit) > 6310 mg/kg LD50 (Oral -Quail) > 2510 mg/kg LD50 (Oral -Duck) > 2510 mg/kg TDLo (Oral -Rat) 1302 mg/kg/31 days -intermittent: Kidney, Urethra, Bladder: other changes in urine composition; Nutritional and Standard Draize Test (Skin - Rabbit) 500 mg/24 hours Standard Draize Test (Eye- Rabbit) 100 mg: Moderate N/A Gross Metabolic: weight loss or decreased weight gain, changes in sodium. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. 12.1 Ecotoxicity LC50, mg/L EC5o, mg/L Product & Constituents Aquatic NE NE Terrestrial NE NE 12.2 Persistence and Degradability The components of this product decompose in soil and water. 12.3 Bioaccumulative Potential This product is not expected to bioaccumulate 12.4 Mobility in Soil When spilled onto soil, this product will infiltrate downward, the rate being greater with lower concentration because of reduced viscosity. 12.5 Other Adverse Ecological Effects This product may be harmful to aquatic life aquatic environment. if large volumes of it are released into an Vitec° 1400 PUBLIC GHS SDS PAGE 7 OF 11 13. DISPOSAL CONSIDERATIONS Preparing Wastes of this Product for Waste disposal must be in accordance with appropriate U.S. Federal, State, and local Disposal regulations or with local regulations. This product, if unaltered by the handling, may be disposed of by treatment at a permitted facility or as advised by your local waste regulatory authority. Disposal of Contaminated Packaging Cleaned containers can be recycled or disposed of as non -contaminated waste, if authorized by your local authorities. Dispose of containers as required by local regulations. U.S. EPA Waste Number Not applicable if the product as supplied becomes a waste 14. TRANSPORT INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. 14.1 UN Number N/A 14.2 UN Proper Shipping Name N/A 14.3 Transport Hazard Class(es) N/A Transport label(s) required N/A 14.4 Packing Group N/A 14.5 Marine Pollutant N/A NA Emergency Response Guide N/A Number (2012) 14.6 Transport in Bulk (Annex II of N/A MARPOL 73/78 and IBC Code) 14.7 Special Transport Precautions N/A National Motor Freight #70 Classification International Air Transport Association 14.8 UN Number N/A UN Proper Shipping Name N/A Transport Hazard Class(es) N/A Transport label(s) required N/A Packing Group N/A Packaging Instructions N/A International Maritime Organization 14.9 UN Number N/A UN Proper Shipping Name N/A Transport Hazard Class(es) N/A Transport label(s) required N/A Packing Group N/A Marine Pollutant N/A NA Emergency Response Guide N/A Number (2012) Transport in Bulk (Annex II of N/A MARPOL 73/78 and IBC Code) Vitec° 1400 PUBLIC GHS SDS PAGE 8 OF 11 15. SAFETY, HEALTH and ENVIRONMENTAL REGULATIONS SPECIFIC FOr THE PRODUCT PROGRAM Chelate agent 1 Chelate agent 2 US EPA PROGRAMS Clean Air Act Hazardous Air Pollutants NO NO Safe Drinking Water Act NO NO RCRA F, K, P, U or D-lists NO NO Epa Priority Pollutant NO NO SARA 302 RQ NO NO SARA 302 TPQ NO NO SARA 313 LISTED NO NO SARA CHEMICAL CATEGORIES SARA 311/312 ACUTE NO NO SARA 311/312 CHRONIC NO NO SARA 311/312 FIRE NO NO SARA 311/312 PRESSURE NO NO SARA 311/312 NO NO REACTIVITY EPA EXTREMELY HAZARDOUS SUB STANCE NO NO CALIFORNIA This product does not contain any chemical listed on the California Safe Drinking Water Act list (Proposition 65) US OSHA PROGRAMS PEL NO NO PSM NO NO CHEMICAL SECURITY PROGRAMS DHS CFATS NO NO CHEMICAL WEAPONS CONVENTION NO NO DEA Controlled Substances NO NO CF CAL INVEN QRY PROG$' W HMIS NO NO DSL YES YES REACH Pre -registered List YES YES TSCA YES YES European Inventory of Existing Commercial Chemical Substances (EINECS) YES YES EU No -Longer Polymers List (NLP) N/A N/A EEC Classification Packaging, and Labeling of Dangerous Substances(Annex 1) NO NO Philippines Japan YES YES YES YES Vitec® 1400 PUBLIC GHS SDS PAGE 9 OF 11 Australia YES YES Korea YES YES China YES YES New Zealand Inventory of Chemicals YES YES 16.1 Original Preparation 16.2 Revision History 16. OTHER INFORMATION 9 Dec 2014 24 June 2016 OSHA, WHMIS GHS Update; format changes 08-05- 2016; Content corrections, October 7, 2016 16.3 Prepared by ADVANCED CHEMICAL SAFETY, Inc. PO Box 152329 San Diego, CA 92195 (858)-874-5577 16.4 Date of Printing October 7, 2016 Vitec° 1400 PUBLIC GHS SDS PAGE 10 OF 11 DEFINITIONS OF TERMS 16.5 A large number of abbreviations and acronyms appear on a SDS. Some of these which are commonly used include the following: Section 2 GHS: Global Harmonization System OSHA: U.S. Occupational Safety and Health Administration. CLP: Classification and Packaging WHMIS: Workplace Hazardous Materials Information System STOT: Specific Target Organ Toxicity Section 3 CAS #: Chemical Abstract Service index number EINECS #: European Chemical Substances Information System index number Section 5 NFPA: Nation Fire Protection Association Health Hazard: 0 (material that on exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure could cause death or major residual injury). Flammability Hazard Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System". Flash Point: Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. Autoignition Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL: The lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL: The highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. Section 8 ACGIH - American Conference of Govemmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airbome concentration of a substance which represents conditions under which it is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered PEL - Permissible Exposure Limit - This exposure value means exactly the same as a TLV, except that it is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PF.T s and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order. IDLH - Immediately Dangerous to Life and Health - This level represents a concentration from which one can escape within 30-minutes without suffering escape -preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research ann of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). When no exposure guidelines are established, an entry of NE (Not Established) is made for reference. Section 11 LD50 : Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LCso : Lethal Concentration (gases) which kills 50% of the exposed animals; ppm: Concentration expressed in parts of material per million parts of air or water; mg/m3 : Concentration expressed in weight of substance per volume of air; mg/kg: Quantity of material, by weight, administered to a test subject, based on their body weight in kg IARC - the International Agency for Research on Cancer; NTP - the National Toxicology Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are also used. TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. BEI - Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Section 12 LCso: The lowest concentration in water which kills 50% of the test subjects. ECso: The Effect Concentration in water at which 50% of the test species if affected. Section 13 US EPA Hazardous Waste Codes: refer to 40 CFR 261.20 Section 14 DOT: US Department of Transportation IATA: International Air Transport Association IMO: International Maritime Organization MARPOL: International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978 IBC Code : Merchant Shipping Code Section 15 RCRA: US Resource Conservation and Recovery Act SARA: US Superfund Amendments and Reauthorization Act PSM: US OSHA Process Safety Management CFATS: US Department of Homeland Security Chemical Facility Anti -terrorism Standard DSL: Canadian Domestic Substances List NDSL: Canadian Non -Domestic Substances List REACH: European Registration, Evaluation, Authorization and Restriction of Chemicals list TSCA: US Toxic Substances Control Act Vitec° 1400 PUBLIC GHS SDS PAGE 11 OF 11 2018 NC Intergrated Report Tar -Pamlico River Basin Pamlico Sound Subbasin 03020105 11).EC:r.p 29-73-(2)b Long Shoal River From a line extending river 506 meters south of Deep Creek to Pamlico Sound excluding area at 5th Avenue Pump canal Classification SA; H QW Length or Area 2,641 Units S Acres Previous AU Number 'arameter of Interes =ategory Assessment Criteria StatusLCollection_Year Fish Tissue Mercury (Nar, FC, NC) Shellfish Growing Area Status (Fecal, SH, SA) 29-73-(2)c 4t 1 Exceeding Criteria Meeting Criteria 2012 2010 Long Shoal River DEH closed area at 5th Avenue pump canal Classification SA; H QW Length or Area 35 Units S Acres Previous AU Number rameter of Interest Category Assessment Criteria Status Collection_Year Fish Tissue Mercury (Nar, FC, NC) Shellfish Growing Area Status (Fecal, SH, SA) 29-89 4t 5 Exceeding Criteria Exceeding Criteria 2012 2010 Mary Anns Pond Entire Pond Classification SA; H QW Length or Area 3 Units S Acres Previous AU Number �o ra Info i+ Category+ Fish Tissue Mercury (Nar, FC, NC) Shellfish Growing Area Status (Fecal, SH, SA) 29-44-5-4 4t 1 Exceeding Criteria Meeting Criteria 2012 12010 Middle Creek From source to Deep Bay Classification SA; HOW Length or Area 12 Units S Acres Previous AU Number Parameter of Interest& gory Assessment Criteria Status Collection_Year Fish Tissue Mercury (Nar, FC, NC) Shellfish Growing Area Status (Fecal, SH, SA) 4t 1 Exceeding Criteria Meeting Criteria 2012 2010 7/23/2019 2018 NC Integrated Report Page 1315 of 1727 Whole Effluent Toxicity Testing and Self Monitoring Summary • • • • • • • • • • • • • — • • — • • - • • - • • - • • - • • - • • - • • - • • - • • - • • - • • - • • - • • - • • • • - • • - • • • • • • • — • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • — — — - - — • • • • • • • • • • • • • • • - • • - • • - • • • • - • • - • • - • • • • - • • - • • - • • • • - • • - • • - • • • • m • • • • • • • • Ocracoke Sanitary District (RO) WTP NC0041530/001 County: Hyde Region: WARO Basin: Tar08 Feb May Aug Nov Mysd24PF Begin: 6/1/2017 24hr Ac PF Limit: 90% NonComp: 7Q10: NA PF: 0.45 IWC: NA Freq: Q SOC JOC: 2016 2017 2018 2019 2020 J Pass F M A M Pass - - Pass Pass - - Pass Pass - - Pass Pass - Pass Pass Pass - Pass J J A Pass Pass Pass Pass S O N Pass Pass Pass Fail Fail — - — — • • • • • • • •• •• •• •• •• • • — • • — • • • — • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • Legend: P= Fathead minnow (Pimphales promelas), H=No Flow (facility is active), s = Split test between Certified Labs Page 83 of 122 ROY COOPER Governor MICHAEL S. REGAN Secretary LINDA CULPEPPER Director David Tolson Ocracoke Sanitary District PO Box 567 Ocracoke, NC 27960-0567 NORTH CAROLINA Environmental Quality August 16, 2019 SUBJECT: Compliance Inspection Report Ocracoke Reverse Osmosis WTP NPDES WW Permit No. NC0041530 Hyde County Dear Mr. Tolson: The North Carolina Division of Water Resources conducted an inspection of the Ocracoke Reverse Osmosis WTP on 8/15/2019. This inspection was conducted to verify that the facility is operating in compliance with the conditions and limitations specified in NPDES WW Permit No. NC0041530. The findings and comments noted during this inspection are provided in the enclosed copy of the inspection report entitled "Compliance Inspection Report". If you should have any questions, please do not hesitate to contact me with the Water Quality Regional Operations Section in the Washington Regional Office at 252-946-6481 or via email at robert.e.bullock@ncdenr.gov. Sincerely, Robbie Bullock, Environmental Specialist II Water Quality Regional Operations Section Washington Regional Office Division of Water Resources, NCDEQ Cc: Laserfiche .D.IE 1, North Caro ea Department of Env+ronn erta Qi.ra ty I [Mason ofWate, Resources ,. Wash ngton Regora Dffce 1943Wash rgtor Square Mari I Wash rgtor, North Caro ra 27E59 4-::.: a.;; ._.. 252-846-6481 United States Environmental Protection Agency EPA Washington, D.C. 20460 Water Compliance Inspection Report Form Approved. OMB No. 2040-0057 Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection 1 IN 2 L 3 I NC0041530 111 12 I 19/08/15 I17 Type 18 [ j IIIIIII11II Inspector Fac Type 19 I G I 20I /j 291I1I11 111111111II III IIII I I IIIII r6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA Reserved 67 1 I 70 Li711 1 72 N 73I I �74 751 I I I I I I 180 I I I I I Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include POTW name and NPDES Permit Number) Ocracoke Reverse Osmosis WTP NCSR 1324 Ocracoke NC 27960 Entry Time/Date 10:40AM 19/08/15 Permit Effective Date 17/06/01 Exit Time/Date 11:20AM 19/08/15 Permit Expiration Date 19/11/30 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Name, Address of Responsible OfficiaVTitle/Phone and Fax Number Contacted Lonnie R Burrus,PO Box 567 Ocracoke NC 279600567/Manager/252-928-5791/2529286651 No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Records/Reports Self -Monitoring Program • Facility Site Review Effluent/Receiving Waters Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date Robert Bullock Division of Water Quality//252-948-3924i y^/V / / 2.--4‘,/y( Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# 1 NPDES yr/mo/day Inspection Type NC0041530 111 21 19/08/15 117 18 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) The review period for this inspection was January 2015 through April 2019. There were no violations over the review period. The current permit was set to expire on November 30, 2019. The facility has submitted a renewal application and the existing permit will remain effective until a new permit is issued. The facility was judged to be COMPLIANT with NPDES permit NC0041530. Page# 2 Permit: NC0041530 Inspection Date: 08/15/2019 Owner - Facility: Ocracoke Reverse Osmosis VVTP Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new M ❑ ❑ ❑ application? Is the facility as described in the permit? IM000 # Are there any special conditions for the permit? •❑ ❑ ❑ Is access to the plant site restricted to the general public? M ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? III ❑ ❑ ❑ Comment: The current permit was set to expire on November 30, 2019. The facility has submitted a renewal application and the existing permit will remain effective until a new permit is issued. Record Keeping Are records kept and maintained as required by the permit? Is all required information readily available, complete and current? Are all records maintained for 3 years (lab. reg. required 5 years)? Are analytical results consistent with data reported on DMRs? Is the chain -of -custody complete? Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? Is the ORC visitation log available and current? Is the ORC certified at grade equal to or higher than the facility classification? Is the backup operator certified at one grade less or greater than the facility classification? Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Comment: The February 2019 DMR was reviewed for accuracy with no discrepancies found. Effluent Sampling Is composite sampling flow proportional? Yes No NA NE III ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ • ❑ ❑ ❑ 0 0 0 0 0 ■ ❑ ❑ ❑ ❑ ❑ U ❑ O OUD ❑ ❑•❑ O 0110 ❑ ❑•❑ • ❑ ❑ ❑ ❑ ❑•❑ Yes No NA NE ❑ ❑ • ❑ Page# 3 Permit: NC0041530 Inspection Date: 08/15/2019 Owner - Facility: Ocracoke Reverse Osmosis WTP Inspection Type: Compliance Evaluation Effluent Sampling Is sample collected below all treatment units? Is proper volume collected? Is the tubing clean? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type representative)? Comment: Compliance samples are grab as stated in the NPDES permit. The facility is field parameter certified (#5614) for PH and DO. Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly'? Comment: No adverse conditions were observed from the shore. During the inspection the water plant was not in operation. Yes No NA NE MOOD ▪ ❑ ❑ ❑ ❑ ❑•❑ • ❑ ❑ ❑ • ❑ ❑ ❑ Yes No NA NE III000 • ❑ ❑ ❑ ❑ ❑ ❑• Page# 4 Facility Name WWTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream Stream Class 7Q10s (cfs) 7Q1Ow (cfs) 30Q2 (cfs) QA (cfs) 1Q10s (cfs) Data Source(s) Table 1. Project Information E CHECK IF HQW OR ORW WQS Ocracoke Reverse Osmosis WTP NC0041530 Mary Ann's Pond (Pamlico Sound) SA;HQW Tidal, IWC = 100% Tidal, IWC = 100% Tidal, IWC = 100% Tidal, IWC = 100% Tidal, IWC = 100% BIMS Data Jun2017 to Jun2020 Saltwater streams are tidal resulting in all IWC % = 100%. If an approved model is conducted then a chronic dilution factor is determined and can be applied to a discharge to calculate its IWC % . If a stream is classified as a SA or ORW then its is also classified as a HQW. The appropriate IWC % must be defined to properly calculate WQS-based limits. Saltwater RPA 95% Probablitv/95% Confidence MAXIMUM DATA POINTS = 58 ' REQUIRED DATA ENTRY Table 2. Parameters of Concern Name Par01 Par02 Par03 Par04 Par05 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Par18 Par19 Par20 Par21 Par22 WQS Type Chronic Modifier Acute PQL Units NOTE: The aquatic life chronic and acute WQS for several metals are calculated based on EPA conversi see "Diss. SW stds. As TM" for more details and summary of calculated WQS.. NC0041530 RPA 2020,input 7/21/2020 REASONABLE POTENTIAL ANALYSIS - DATA Par07 Copper Date Data BDL=1/2DL Results 1 8/9/2017 < 10 5 Std Dev. 2 11/7/2017 < 10 5 Mean 3 2/6/2018 < 10 5 C.V. 4 5/8/2018 < 10 5 n 5 8/7/2018 < 10 5 6 11/6/2018 < 10 5 Mult Factor = 1.0000 7 2/5/2019 < 10 5 Max. Value 5.00 ug/L 8 5/7/2019 < 10 5 Max. Pred Cw 0 DETECTS ug/L 9 8/6/2019 < 10 5 10 11/5/2019 < 10 5 11 2/4/2020 < 10 5 12 5/5/2020 < 10 5 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 Use "PASTE SPECIAL. Values" then "COPY" . Maximum data points = 58 0.0000 5.0000 0.0000 12 NC0041530 RPA 2020,data Date} Ocracoke Reverse Osmosis WTP NC0041530 Saltwater RPA 95% MAXIMUM Qw (MGD) = 0.18 1Q10S (cfs) = Tidal, IWC = 100% 7Q1OS (cfs) = Tidal, IWC = 100% 7Q1OW (cfs) = Tidal, IWC = 100% 30Q2 (cfs) = Tidal, IWC = 100% Avg. Stream Flow, QA (cfs) = Tidal, IWC = 100% Receiving Stream: Mary Ann's Pond (Pamlico Sound) Probablity/95% Confidence DATA POINTS = 58 WWTP/WTP Class: PC-1 IWC% @ 1Q10S = 100 IWC% @ 7Q1OS = 100 IWC% @ 7Q1OW = 100 IWC% @ 30Q2 = 100 IWC% @ QA = 100 Stream Class: SA;HQW Outfall 001 Qw = 0.183770967741935 MGD YOU HAVE DESIGNATED THIS RECEIVING STREAM AS HQW OR ORW. PARAMETER TYPE (1) NC STANDARDS OR EPA CRITERIA PQL UNITS REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Chronic Applied Standard Acute ri # Det. Max Pred Cw Allowable Cw Copper NC 1.85 SW(7Q10s) 2.9 2.0 ug/L 12 0 NO DETECTS Acute: 2.90 _ _ _ _ _ _ _ _ _ _ _ _maintain Chronic: 1.85 Max MDL = 10 No detects - MDL (PQL) > Allowable Cw, quarterly monitoring _ _ _ _ _ No detects - MDL (PQL) > Allowable Cw, maintain quarterly monitoring Page 3 of 4 NC0041530 RPA 2020,rpa 7/21/2020 Saltwater - Total Recoverable Metal Standards for Aquatic Life Protection The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Table 1. NC 2007-2015 Triennial Review Dissolved Metals Water Quality Standards converted to Total Recoverable Metals For Aquatic Life Protection 1 Parameter Acute SW, ug/1 (Dissolved) Chronic SW, ug/1 (Dissolved) EPA Conversion FactorsZfor Dissolved Metals Acute SW, ug/1 Chronic SW, ug/1 Saltwater CMC (Acute) Saltwater CCC (chronic) (Total Metal) (Total Metal) Arsenic 69 36 1 1 69 36 Cadmium 40 8.8 0.994 0.994 40.2 8.9 Chromium VI 1100 50 0.993 0.993 1107.8 50.4 Copper 4.8 3.1 0.83 0.83 5.8 3.7 Lead 210 8.1 0.951 0.951 220.8 8.5 Nickel 74 8.2 0.99 0.99 74.7 8.3 Silver 1.9 0.1 0.85 — 2.2 Zinc 90 81 0.946 0.946 95.1 85.6 Table 1 Notes: 1. SW= Saltwater 2. EPA Conversion Factors from US EPA website, National Recommended Water Quality Criteria - Aquatic Life Criteria Table; https://www. epa. gov/wqc/national-recom mended-water-quality-criteria-aquatic-life-criteria-table#a The dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. Permit No. NPDES Implementation of Instream Dissolved Metals Standards — Saltwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April6, 2016, with some exceptions. Therefore, metals limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Quality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, 1.ig/1 (Dissolved) Acute SW, 1.ig/1 (Dissolved) Chronic SW, 1.1g/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 --- --- Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved metal standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. Note that none of the saltwater standards are hardness -dependent. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on conversion factors determined by EPA (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance — Discharges to Saltwater (Tidal waters) The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the stream dilution. For discharges to saltwater, no allowance for dilution is given unless a dilution study, such as a CORMIX model, is performed. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. Page 1 of 3 Permit No. 1. To perform a RPA using the saltwater dissolved metal standards, the Permit Writer compiles the following information: • Permitted flow • Receiving stream classification • Instream Wastewater Concentration, if a dilution model has been performed 2. The RPA spreadsheet converts the dissolved numeric standard (SW standards listed in Table 1.) for each metal of concern to a total recoverable metal, using the EPA conversion factors published in the June, 1996 EPA Translator Guidance Document. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. Conversion Factors for Dissolved Metals Metal Saltwater CMC (Acute) Saltwater CCC (chronic) Arsenic 1.000 Cadmium 0.994 Chromium VI 0.993 Copper 0.83 Lead 0.951 Mercury 0.85 Nickel 0.990 Selenium 0.998 Silver 0.85 Zinc 0.946 1.000 0.994 0.993 0.83 0.951 0.85 0.990 0.998 — 0.946 From: US EPA website, National Recommended Water Quality Criteria - Aquatic Life Criteria Table https://www.epa.gov/wgc/national-recommended-water- quality-criteria-aquatic-life-criteria-table#a 3. The dissolved numeric standard for each metal of concern is divided by the EPA conversion factor (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. 4. If a dilution study was performed on the receiving stream and an Instream Wastewater Concentration (IWC) determined the RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q10 + Qw) (Cwqs) — (s7Q10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match 7Q10 units) s7Q10 = summer, critical low flow (cfs) * Discussions are on -going with EPA on how best to address background concentrations Assuming no background concentration, this equation can be reduced to: Ca = (s7Q10 + Qw) (Cwqs) or Ca = Cwqs Qw IWC Page 2 of 3 Permit No. Where: IWC = Qw Qw + s7Q10 or 1 D and D = modelled dilution factor (unitless) If no dilution study has been performed Ca, the allowable effluent concentration, is equal to the Total Recoverable Metal determined at ambient conditions (ie. the dissolved numeric standard divided by the EPA conversion factor (or site -specific translator) for the metal of concern). See item # 3 above. 5. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 6. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 7. The Total Chromium NC WQS was removed and replaced with a hexavalent chromium standard. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against the water quality standard chromium VI. Page 3of3 September 2020 Local news `Keeper of the light' crosses th By Rita Thiel 0 cracoke Island may not have had a human lighthouse keeper in recent years, but it has indeed had its "Keeper of the Light." Thurston, the gray and white Ocracat, had staked out the board- walk and grounds of Ocracoke's lighthouse for the last several years and seeing Thur- ston was a reason visi- tors kept returning to see a lighthouse they'd seen a half a dozen times already. "We used to go to the lighthouse just to see Thurston," said one of many Facebook post- ers. Ocracoke lost its fe- line Keeper on Aug. 11. Thurston had unfortu- nately been in declining health and was under the care of Dr. Laura Trent. Considered a "feral," or "community," cat, he eagerly greeted anyone who walked Thurston the Ocracat staked out the Ocracoke Lighthouse. "his" territory and unabash- edly solicited pets, hugs and snuggles. Over the years, both Ocracats and residents made sure Thur- ston had fresh food and water each day, often chatting with lighthouse visitors about him. When Ocracats post- ed news of his departure across the "rainbow bridge," it was met with an instant outpouring lamenting the passing of a great ambassador and one of the island's attractions. The Ocracats' Face - book page post has drawn almost 80,000 hits and hundreds of comments, and this is only one of several internet sites that has posted news of Thur- ston's passing. A common theme was how and where to honor Thurston with a memorial. Ocracats set up a fundraiser page that has raised nearly $2,800. All funds donated for Thur- ston will go toward a memorial. Ocracats is more than willing to do something in Thurston's honor somewhere, and that lo- PUBLIC NOTICE North Carolina Environmental Management Commission/NPDES Unit 1617Mail Service Center . Raleigh, NC 27699-1617 NOTICE OF INTENT TO ISSUE A NPDES WASTEWATER PERMIT NC0041530 OCRACOKE SANITARY DISTRICT The North Carolina Environmental Management Commission proposes to issue a NPDES wastewater discharge permit to the person(s) listed below. Written comments regarding the pro- posed permit will be accepted until 30 days after the publish date of this notice (Sept. 1, 2020). The Director of the NC Division of Water Resources (DWR) may hold a public hearing should there be a significant degree of public interest. Please mail comments and/or information re- quests to DWR at the above address. Interested persons may visit the DWR at 512 N. Salisbury Street, Raleigh, NC to review information on file. Additional information on NPDES permits and this notice may be found on our website: http:// deq. nc. gov/about/divisions/water- resources/water-resources-permits/wastewater-branch/np- des-wastewater/public-notices,or by calling (919) 707-3601. Ocracoke Sanitary District applied to renew NPDES permit for their RO WTP [NC0041530), 159 Water Plant Road, Hyde County, discharging treated wastewater to Mary Ann's Pond (Pam- lico Sound), Tar -Pamlico River Basin. cat wil on Na Ha tioi Ca] mo pas apf tior wit nit) I c v P tl sI e: ei el tl P' SE th MI ioo (25 RE: Peer Review - NC0041530 Ocracoke Sanitary District - Ocracoke Reverse Osmosis WTP Phillips, Emily <Emily.Phillips@ncdenr.gov> Fri 8/7/2020 1 ,6 AM To: Denard, Derek <derek.denard@ncdenr.gov> Looks good, except you have "Director" twice on page 1, down at the signature line for Danny. I updated the public access system. Have an awesome weekend! Stay safe, and take care. E From: Denard, Derek <derek.denard@ncdenr.gov> Sent: Wednesday, August 5, 2020 2:46 AM To: Phillips, Emily <Emily.Phillips@ncdenr.gov> Subject: Peer Review - NC0041530 Ocracoke Sanitary District - Ocracoke Reverse Osmosis WTP Emily, Attached is a share link to the subject peer review. Files to review are in the "peer review" sub -folder. Please update Access. ENC0041530 Ocracoke Sanitary District - Ocracoke Reverse Osmosis WTP Thanks a bunch. Hope you are doing well. Derek Derek Denard Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919 707 3618 office 919 707 9000 main DWR derek.denard@ncdenr.gov 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. 2/2/2021 Mail - Denard, Derek - Outlook Re: [External] Re: Draft NPDES Permit NC0041530 - Ocracoke Reverse Osmosis WTP Denard, Derek <derek.denard@ncdenr.gov> Wed 8/19/2020 10:39 PM To: David Tolson <ocracokeh2o@yahoo.com> David, Thanks for the comments. I will get back with you with an answer to your requests for the final. Thanks, Derek Denard Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919 707 3618 office 919 707 9000 main DWR derek.denard@ncdenr.gov 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. From: David Tolson <ocracokeh2o@yahoo.com> Sent: Thursday, August 13, 2020 10:19 AM To: Denard, Derek <derek.denard@ncdenr.gov> Subject: [External] Re: Draft NPDES Permit NC0041530 - Ocracoke Reverse Osmosis WTP CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to report.spammnc.gov Mr. Denard We received and opened and printed the attached for our review and records. Electronic transmittal from you is fine, just keep in mind that we are a small system and we do not have a scanner to get documents into the computer on our end, so anything you may need from us that is not in our computer or if forms have to be printed and signed we cannot get them back into our computer to send them back to you. We note that you have Turbidity to be tested twice a month, as was in our draft the last time our permit was renewed, but it was reduced to once per month. We have a limit of 25 NTU for Turbidity, but since October 2017, the highest result we have had is 6.7. We tested years ago for this and that was the reason for years they removed this from our permit. https://outlook.office365.com/mail/AAMkADdhYTVmZDBILTESZDctNG15MC04Zj1iLWU4MjVhZTBhMmJkMgAuAAAAAADg3GZR8iZnTYW56121 cjmNA... 1/3 2/2/2021 Mail - Denard, Derek - Outlook Being on an Island accessible only by ferry can make getting water test off Island to the Lab in the time required very challenging because wind, tide, fog and mechanical failure of ferries and can affect ferry schedule and make it very difficult to get UPS to pickup and get back to Manteo in time to meet the trucks to go out on time. We request that you make Turbidity testing either quarterly like the rest of our effluent (except for flow, pH and DO) or at least leave it monthly as it is now. We use Zinc orthophosphate for corrosion control since RO water is very soft and can cause corrosion in customers lines and plumbing and it is like the chorine, it is added only to the potable water, it does not go thru the RO units so it never comes into contact with the effluent/discharge. After the water goes into the RO units, effluent goes out thru one pipe and potable water goes out thru another towards the tanks and that is where the zinc and chlorine are added. Thank you for your consideration in this matter. If you have any questions, please contact this office. David Tolson Ocracoke Sanitary District --Manager 159 Water Plant Rd. PO Box 567 Ocracoke, NC 27960 252-928-5791--office 252-928-6651--Plant& Fax ocracokeh2o@yahoo.com On Thursday, August 13, 2020, 01:12:20 AM EDT, Denard, Derek <derek.denard@ncdenr.gov> wrote: Mr. Tolson, Please find the attached draft NPDES Permit NC0041530 for Ocracoke Reverse Osmosis WTP. In order to provide more convenience, control, and security to our permittees and assist them in processing their transactions, The Division of Water Resources is currently transitioning towards electronic correspondence. This will hopefully provide more efficient service to our permittees and other partners and will allow us to more effectively process and track documents. We are writing to ask you for your approval of the transmittal of documents related to your permitting and related activities with the Division in an electronic format. Documents will be emailed to the appropriate contact person(s) in your organization in a PDF format. Please respond to me through email with verification that transmittal of your documents in an electronic manner is acceptable to you. Please respond to this email confirming that you received the attached document(s), were able to open and view the document(s) and have saved/printed a copy for your records. If you have questions concerning the draft, please contact me at 919-707-3618, or via e-mail at derek.denard@ncdenr.gov. Sincerely, Derek Denard https://outlook.office365.com/mail/AAMkADdhYTVmZDBILTESZDctNG15MC04Zj1iLWU4MjVhZTBhMmJkMgAuAAAAAADg3GZR8iZnTYW56121 cjmNA... 2/3 2/2/2021 Mail - Denard, Derek - Outlook Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919 707 3618 office 919 707 9000 main DWR derek.denard@ncdenr.gov 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. https://outlook.office365.com/mail/AAMkADdhYTVmZDBILTESZDctNG15MC04Zj1iLWU4MjVhZTBhMmJkMgAuAAAAAADg3GZR8iZnTYW56121 cjmNA... 3/3 2/2/2021 Mail - Denard, Derek - Outlook [External] Re: Issuance of NPDES Permit NC0041530 - Ocracoke Reverse Osmosis WTP David Tolson <ocracokeh2o@yahoo.com> Tue 1/19/2021 8:50 AM To: Denard, Derek <derek.denard@ncdenr.gov> CAUTION: External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to Report Spam. Mr. Denard: Transmittal of documents in electronic format is fine. We received printed and saved our new permit with no issues. Thank you for granting our request of taking Turbidity monthly rather than twice a month. Janie M. Garrish Office Manager David Tolson Ocracoke Sanitary District --Manager 159 Water Plant Rd. PO Box 567 Ocracoke, NC 27960 252-928-5791--office 252-928-6651--Plant& Fax ocracokeh2o@yahoo.com On Tuesday, January 19, 2021, 08:00:24 AM EST, Denard, Derek <derek.denard@ncdenr.gov> wrote: Mr. Tolson, Please find the attached issuance for NPDES Permit NC0041530 for Ocracoke Reverse Osmosis WTP. In order to provide more convenience, control, and security to our permittees and assist them in processing their transactions, The Division of Water Resources is currently transitioning towards electronic correspondence. This will hopefully provide more efficient service to our permittees and other partners and will allow us to more effectively process and track documents. We are writing to ask you for your approval of the transmittal of documents related to your permitting and related activities with the Division in an electronic format. Documents will be emailed to the appropriate contact person(s) in your organization in a PDF format. Please respond to this email confirming that you received the attached document(s), were able to open and view the document(s) and have saved/printed a copy for your records. If you have questions concerning the draft, please contact me at 919-707-3618, or via e-mail at derek.denard@ncdenr.gov. Sincerely, https://outlook.office365.com/mail/AAMkADdhYTVmZDBILTESZDctNG15MC04Zj1iLWU4MjVhZTBhMmJkMgAuAAAAAADg3GZR8iZnTYW56121 cjmNA... 1/2 2/2/2021 Mail - Denard, Derek - Outlook Derek Denard Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919 707 3618 office 919 707 9000 main DWR derek.denard@ncdenr.gov 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. https://outlook.office365.com/mail/AAMkADdhYTVmZDBILTESZDctNG15MC04Zj1iLWU4MjVhZTBhMmJkMgAuAAAAAADg3GZR8iZnTYW56121 cjmNA... 2/2