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HomeMy WebLinkAboutNC0000272_NPDES_Permit_Report_20030929 "BLUE RIDGE PAPER PRODUCTS INC. September 29, 2003 Mr. Forrest Westall Regional Water Quality Supervisor North Carolina Department of Environment and Natural Resources 59 Woodfin Place Asheville,NC 28801 RE: NPDES Permit No. NC0000272, Blue Ridge Paper Products, Inc. October 1, 2003 Required Report Dear Mr. Westall: Attached is the October 1, 2003 Report. This report is submitted to fulfill the requirements stated in Section A(8),Paragraph 5 of the 2001 NPDES Permit. Blue Ridge Paper Products is submitting this report to you in your capacity as Regional Water Quality Supervisor for the Division of Water Quality and as a member of the Technology Review Workgroup. Please call me at(828) 646-2033 or Melanie Gardner at(828) 646-6749 if you have any questions or concerns regarding this report. Sincerely, l Bob Williams A-21 Director- Environmental,Health and Safety Attachment 175 Main Street • P.O. Box 4000 Canton, North Carolina 28716 Phone: 828-646-6700 • Fax: 828-646-6892 Raising Your Expectations October 1,2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina I. Introduction The following report details the Canton Mill's ability to attain the lowest achievable annual average and monthly average color loading limits based on the Mill's performance from December 2001 —August 2003. Section A(8.),Paragraph 5 of the 2001 NPDES Permit provides in part, as follows: "...By October 1, 2003, the permittee shall submit to the North Carolina Division of Water Quality a report including a statistical analysis of the permittee's monthly average color discharge, mill performance as related to color, all available data necessary to derive the lowest achievable annual average and monthly average color loading limits... " This report is submitted to fulfill the requirements of Section A(8.), Paragraph 5. Based on the Mill's performance from December 2001 —August 2003 and the Mill's continued commitment to color improvement, Blue Ridge Paper Products believes an annual average color limit of 42,000 pounds per day and a monthly average color limit of 52,000 pounds per day are feasible. �1, 5EP g U 20Q3 l � 1 \lA+c �,It �fL 1 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina II. Color Performance Set forth below is a summary of the actions implemented and planned for further color improvement at the Canton Mill. These actions satisfy the `Highest Certainty' items recommended by the Division of Water Quality and the Technology Review Workgroup. 2.1 Process Optimizations Items The sixteen Process Optimization Items recommended in the Bleach Environmental Process Evaluation and Report prepared by Liebergott &Associates Consulting Inc. and GL&V Pulp Group Inc. have all been evaluated and implemented where appropriate. 2.2 Improved Black Liquor Leak and Spill Collection and Control This recommendation consists of four elements including: 1) Continuous improvement of operating practices so more leaks and spills are recovered rather than discharged to the sewer; 2) Improvement in preparation for planned outages to maximize capture of tank clean-out waste and routing to recovery; 3) Reduction of clean water that continuously runs into sewers to prevent dilution of smaller spills and facilitate recovery of highly colored wastewaters; and 4)Improvement in the equipment used for the handling of knot rejects to prevent black liquor leaks into the recovery sumps. The following is a discussion of actions relating to each element. 2.2.1 Continuous Improvement of Operating Practices etc. A number of Best Management Practices (BMPs)have been implemented to improve the recovery of colored discharges within the mill. These include: A) Color testing on the 2 October 1,2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina Primary Influent every 2 hours; B) The use of the off-line, spare clarifier for process losses and intentional diversions; C)Piping the Hardwood Brown Spill tank to the Pine Blow Tower for additional spill collection capability and Hardwood Fiberline outage management; and D) Implementation of control logic in the Pine Brownstock area to minimize tank overflows during shutdowns. The Mill began 24-hour color testing in 2-hour increments on the primary influent in 2001. The purpose of this increased color testing is to improve the mill's ability to respond to process upsets on an immediate,real-time basis. If high 2-hour color results are detected, the Wastewater Treatment Plant(WWTP) operators communicate the information to mill operations and in-mill investigations begin. If necessary, diversion of the primary influent to the off-line, spare clarifier is initiated. The high color material that is captured in the off-line clarifier is later discharged into the system at a rate that has a minimum impact on color and is not disruptive to the W WTP system. The off-line spare clarifier is also used during outage situations when high color material cannot be recovered by the in-mill spill control systems due to upset conditions, lack of recycle or evaporator capacity or intentional diversions. In order to increase the Hardwood Fiberline's ability to recycle recovered brownstock material,piping was installed from the Hardwood Brown Spill tank to the Pine Blow Tower. Prior to installation of this piping, there was no outlet for recycled hardwood brownstock material when that system was shut down. This design allows for the Hardwood Brown Spill tank to be recycled into the Pine Blow Tower and is especially useful in hardwood outage situations when the recycle of additional recovered material is required. Color savings from this 2001 project are reflected in the improvements seen around the hardwood brownstock or 2B sewer area as well as improved color performance. 3 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina During the first quarter of 2003, additional control logic was developed and implemented on the pine brownstock system to prevent high colored filtrate tanks (15`, 2"d, and 3`d stage Pre-OZ filtrate tanks) from overflowing and potentially reaching the sewer. The control logic is designed to alert the operator when the brownstock filtrate tank(s) reach 85% with audible and visual alarms. If the tank level(s) continues to rise to 90%, the pine brownstock operators receive a"high-high"level alarm and warning text on their monitors. The control logic then automatically interlocks (i.e., shuts down) the washer stock feed pump that is associated with the high-level filtrate tank. Further, additional controls have been built into the logic for the Pine Brown Spill tank. The alarm logic for this tank checks the tank level at various times each day. If the tank level is greater than 50% at either time period, the Pine Brownstock Operator will receive an audible alarm as well as a text message stating that the "Pine Brown Spill tank level is high." The control logic will then check the level three hours later and if the level is still above 50%, the operator will receive another alarm stating that the "Pine Brown Spill tank level is still too high." In addition, if the Brown Spill tank level exceeds 80%, the operator receives a high level alarm on his/her Digital Control System (DCS) graphic. All of these control system improvements have enhanced the operator's ability to monitor the system and prevent spills and losses from these processes. 2.2.2 Improvement in Preparation for Planned Outages Color management of planned outages has improved significantly as a result of the following practices: • Increasing color testing from 2 hours to one hour before outages, during outages and upon start-up; • Improved communication between the Wastewater Treatment Plant and mill operations; • Utilization of the off-line, spare clarifier; 4 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton, North Carolina • Developing tank draining schedules where only the necessary vessels are emptied for inspection and scheduled maintenance; • Reducing tank levels to the lowest level possible prior to shutdown. To effectively monitor color performance during maintenance outages, the W WTP operators begin hourly color testing on the primary influent when the Recovery operation initiates its shutdown procedure. The hourly color data is posted on the mill's Plant Information(PI) System where it is widely available to operations and support personnel. If a result is greater than 300 color units, it is immediately communicated to the Recovery and Pulp Mill foremen via the mill radio system and they institute investigative action to pinpoint the source. The appropriate corrective action is then taken. The Pulp Mill and Recovery foremen also communicate their investigative findings with one another to ensure effective troubleshooting is in place. If an hourly color result is elevated and mill operations communicates that there has been a process loss, the W WTP operators will divert the primary influent flow to the 1 million gallon off-line, spare clarifier for temporary storage. There have also been instances when the W WTP operators diverted the primary influent flow without direct communication of a spill. The WWTP operators are trained to take action and route high colored primary influent to the off-line, spare clarifier when necessary. The high color material is later fed into the WWTP system at a slow, non-disruptive rate. Such a slow feed rate minimizes the material's impact on secondary effluent color and does not disrupt the W WTP process. For very high colored material captured in the off-line clarifier,polyamine may be added in small amounts. Small amounts of polyamine aid in the color removal of the concentrated material captured in the clarifier without negatively affecting the sludge quality as larger amounts of polyamine have been demonstrated to do. During normal mill operations, full-scale application of polyamine was not proven to be effective and it created unmanageable sludge conditions; however, polyamine has been effective on these higher color concentration events captured in the off-line clarifier. 5 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina Also, if at any time high colored material is seen in the primary influent, or if mill operations communicates a process loss/intentional diversion, the WWTP operators can immediately divert the primary influent flow into the off-line, spare clarifier. Improved communications between the WWTP and mill operations have allowed for optimal use of the off-line clarifier, especially in outage situations when overall spill system capacity is in demand. Tank draining schedules are developed in preparation for planned maintenance outages. Increased attention has been given to draining only the tanks and lines requiring inspection and/or maintenance rather than draining entire sequences. Draining the entire sequence was a routine approach in the past so that vessels would be empty and available for maintenance if problems were detected. The schedule has been optimized so that inspections are rotated between outages, thereby ensuring that all tanks are inspected while reducing the frequency that individual tanks must be emptied. However, issues may arise where more frequent maintenance is required on certain vessels and appurtenances and in these cases, the tanks must be drained before a scheduled inspection is due. In preparation for all scheduled outages, it is standard practice to focus on reducing tank levels to minimize the amount of material to be drained. This practice also reduces potential losses in the event of an upset process condition during shutdown, outage, or start-up periods. These practices have measurably improved outage color performance. Specifically, reductions in the color losses are demonstrated by the 2002 semi-annual shutdowns (outages performed twice per year, lasting approximately one week with each outage involving half of the mill operations). In a comparison of semi-annual outage primary influent color data,the 2002 data showed an average 38%reduction in the maximum daily primary influent color from historical performance (1996—2001). These improvements are significant given that the majority of the spill recovery systems were implemented in 1997 and 1998. i 6 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina 2.2.3 Reduction of Clean Water that Continuously Runs into Sewers There has been a greater than 90,000 gallon per day reduction in the amount of clean water being sewered, primarily in the mill's digester courtyard. This reduction in flow was achieved by implementing customized Double Mechanical Seals and Water Management Systems on the 18 digester re-circulation pumps. This project has involved extensive trialing of different types and combinations of specially designed mechanical seals over the past several years. The decrease in flow from the mechanical seals is at least 3 to 4 gallons per minute per pump,which equates to a daily flow savings greater than 90,000 gallons. The removal of non-mechanical seal pump packing water from the digester sewers has also contributed to improved color performance for the area. Since complete implementation of the mechanical seals, measured color in the area has been reduced by approximately 60%. This is due in part to the removal of seal water that could be contaminated by black liquor leaks on the non-mechanical seal packing and from the recovery sumps operating more efficiently. With less clean water dilution in the sewers leading to the recovery sumps, the effective conductivity of the material increases and can be captured for re-use in the process at a greater efficiency. Customized Double Mechanical Seals and Water Management Systems have also been installed on the Knotter feed pumps for both the Pine and Hardwood Fiberlines, to further reduce water infiltration to the sewer. 2.2.4 Improvement in Equipment used for Handling Knot Rejects Two projects have been completed to improve the equipment used for handling knot rejects. Black liquor from the Knot Rejects Collection bins is routed to a dedicated U- drain,which flows to a dedicated knot bin sump pump for each Fiberline. The flow from the knot bin areas is collected and pumped to the Brown Spill tank for each respective Fiberline. Recovery of this material has contributed to improved color performance, as 7 October 1,2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina demonstrated by Figure 1 below. The Hardwood Fiberline Brownstock sewer color has shown the most dramatic reduction in color, which results from: • Having the flexibility to send contents from the Hardwood Brown Spill tank to the Pine Blow Tower during shutdown and start-up from an outage; • Reducing the amount of clean water dilution by installing the Double Mechanical Seals and Water Management Systems; • Capturing the black liquor from the knot rejects system and; • Improved communication and color monitoring. Monthly Average Hardwood Brownstock and Digester Area Color Since Installation of Double Mechanical Seals and Water Management Systems 12000 10000 m 8000 O N 6000 O 4000 2000 F Z=� I N N N N N4 4 N N N �'l M M w N n N M O O O O O O Q O O O O Q O O Q O Q vj O Z° p _ 4v Q > > C +Hardwood Brownstock and Digester Area Color Figure 1 8 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina III. Improvements in BFRTm Reliability Approximately$1.5 Million has been spent on Bleach Filtrate Recycle process improvements for 2002—2003. This has resulted in improved BFRTm closure rates over the past year and operational variability is also showing improvement in the Metals Removal Process (MRP). In August 2003, the monthly average closure rate reached targeted levels with improved MRP uptime and equipment reliability matching Fiberline reliability. To improve process variability, a new media filter and a new ion exchange softener were installed in the MRP. Due to accelerated degradation of the original three media filters over recent months, they will also be replaced by the end of 2003. With this additional equipment,metallurgy changes and other process improvements, MRP downtime is expected to be reduced significantly. Having four media filters and three ion exchange softeners will provide enough capacity for the MRP to remain online while repairs are made to an individual media filter or softener. These projects are beginning to demonstrate improved closure rates,reduced operational variability of the MRP, and increased mechanical reliability of the MRP, all of which should aid in reducing both measured and unaccounted color. As was expected, a recent statistical evaluation demonstrated that lower closure rates are a major contributor to elevated secondary effluent color and unaccounted color, individually as a main effect and also combined with other factors as an interaction effect. These effects will be discussed in a later section. 9 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina IV. Color Challenges in 2002—2003 As a result of many years of color reduction activities and those discussed herein, the monthly average secondary effluent color for the period December 2001 through October 2002 was 39,833 lbs/day. However, due to unforeseen and complex issues discussed in this report, secondary effluent color increased in late 2002. In November 2002, secondary effluent color variability began to increase. The contributing source(s) were not readily evident. Out of the 15 sewer and process areas measured daily, there were no measured sources that were statistically out of control except for the Pine Eo filtrate, and that influent contribution was less than 5,000 lbs/day over the in-control average. Two major sewer areas, the Bleach Plant Filtrate Acid Sewer and the Hardwood Brownstock/Digester Area Sewer were actually operating below their average level of performance. The unaccounted color averaged about 23,000 lbs/day for the month(compared to a 2002 YTD average of approximately 10,000 lbs/day). A thorough review of all sewered, color-contributing sources revealed that the hardwood screen rejects were not being quantified in the daily in-mill color analysis. Data has been collected and the average color contribution from the hardwood screen rejects is 3,000 lbs/day. This source has been a small portion of the mill's unaccounted color since 1996; therefore, it is not a significant contribution to the elevated unaccounted color seen during this period. Further, the Wastewater Treatment Plant Color removal effect was dropping. Elevated unaccounted color and reduced WWTP color removal are indicators that support the presence of Sewer Generated Color(SGC),yet closure was averaging 77% and the color contribution from the Bleach Plant Filtrates, the historical pre-cursors of SGC, were running below average as illustrated in Figure 2 below. 10 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina Monthly Average Color In the Bleach Plant Acid Sewer Jan•02 through Jan•03 16000 14000 12000 0 10000 B a u 0000 0000 4000 c g m u a z o° �t Color 6A Figure 2 As the Canton Mill has reduced releases of brown colored material, a greater percentage of the primary influent color has become unaccounted color. Color is a pH dependent parameter and Blue Ridge is in un-charted territory with such low brown color effluents and the BFRTm technology. The result of increasing the pH of an acidic bleach plant filtrate in the laboratory shows a visually significant increase in color. The Sewer Generated Color phenomenon has been duplicated on the bench in multiple studies and the National Council on Air and Stream Improvement (NCASI) supports that color is a pH dependent phenomenon. Sewer Generated Color does not disappear when the pH is adjusted from alkaline back to neutral conditions. Duke University graduate level internship and thesis studies performed at the Canton Mill in 19941 and 19952 showed, on average, Sewer Generated Color for Pine D 1 filtrate was an increase of 32-47% above the original sample color and Sewer Generated Color for Hardwood D1 filtrate was 64-88%. Regarding WWTP color removal, data suggested t "A Laboratory Analysis of Color Removal Across a Pulp and Paper Mill Wastewater Treatment Facility" by Aimee Winter McCord 2 "A Laboratory Analysis of the Color Removal Mechanism Occurring Across the Wastewater Treatment Plan"by Chad Salisbury 11 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina some hardwood Sewer Generated Color may be removable across the WWTP (3% reduction in color after WWTP process),but pine filtrates showed an average increase in color of21% in the simulated WWTP process. Data from this study show brown source color removal up to 70% and the long-term average color removal across the W WTP from primary influent to secondary effluent is 25%. The annual Color Pies showing the breakdown of mill sewers compared to primary influent color support the presence of Sewer Generated Color as unaccounted color has averaged 25% (19,081 lbs/day) since 1996. Of this 25%, the hardwood screen rejects contribute a small amount(currently about 2,7001bs/day). The period from November 2002 through April 2003 is evidence that specific interactions and operational conditions can significantly intensify the Sewer Generated Color effect. Bench scale studies are planned to better understand the various types and magnitudes of the major interaction effects pinpointed during the period of elevated color. It is recognized that these conditions may change and new effects may need to be studied in the future. Figure 3 below shows the trend of increasing unaccounted color and decreasing WWTP color removal that began in November 2002. 12 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina Unaccounted Color and WWTP Color Removal % 30000 Monthly Averages: Jan-02 through Feb-03 35.00% O 25000 30.00% `0 20000 25.00%0 O 20.00%;o CD 15000 3 m 15.00%0< `= 10000 1o.00°i°o r 5000 5.00% n 0 L 0.00% 0 0 0 0 0 0 0 0 0 0 0 0 0 0 j > U C .O t Unaccounted Color 0 WVVfP Color Removal Figure 3 The trend of increasing unaccounted color and simultaneous decreasing W w I? color removal continued in December and a Color Team was formed including representatives from Operations, Environmental and the Technical Manufacturing Support group. This team initially audited the color measurement system as well as monitored sewer areas and related instrumentation for accuracy as well as potential unmeasured sources of color. When there were no anomalies discovered, the team focused on analyzing process parameters for shifts and deviations that could contribute to elevated color. Processes in the Fiberlines and Recovery area were reviewed in most detail while deviations from the Paper Machines were also considered. The Pine Eo filtrate was consistently the only color source that was running above its upper control limit but the causes were unknown. Multiple statistical analyses were performed including CUSUMs or Cumulative Sum charts to identify if, in fact, statistically significant shifts were occurring. While there 13 - October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina were several process parameters that were discovered to be operating outside their normal ranges of variability,the most notable shifts were seen in the Fiberlines. Specifically, the Pine Fiberline Bleach Plant and the Hardwood Fiberline Pre-Bleach and D I (first D) stages. Additional statistical studies were performed and targets were established for the above parameters as well as others, based on early 2002 when the color performance was in the 36,000—39,000 lbs/day range. As the Fiberlines began reaching the established targets, the unaccounted color remained elevated. During the latter part of 2002, the variability in the White Liquor strength and solids increased. This change was believed to be negatively impacting the Fiberline operations by causing increased carryover into the bleach plants. These issues corresponded to the decreased color performance seen beginning in November 2002. Elevated White Liquor solids were then identified as an interaction effect contributing to elevated secondary effluent and unaccounted color and this parameter was added to the Daily Color Monitoring list. Also during late 2002, the quality of purchased lime for the Causticizing operation was compromised due to flooding and other issues with the Mill's normal lime supplier. Negotiations with additional lime suppliers are ongoing to improve the quality of purchased lime. Upon startup from the Cold Mill Outage in April 2003,unaccounted color increased even further to the 35,000—40,000 lbs/day range from pre-Cold Mill levels in the 20,000 lbs/day range. Pine Eo filtrate color was back below the in-control average yet unaccounted color was still high. Detailed Analysis of Variance(ANOVA)Factorials were performed in an effort to determine which factors and combinations of factors were affecting secondary effluent color and unaccounted color significantly. For these analyses, an alpha of.05 was used. The results of the ANOVAs proved that there were multiple statistically significant main effects and interaction effects "responsible" for the elevated secondary effluent color and unaccounted color. This means that the effect impacting the dependent variables (secondary effluent and unaccounted color) was not 14 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina doing so by chance. The interaction effects involve relationships between certain parameters that significantly affect color. Subtle operational changes made in late 2002 had triggered a major Sewer Generated color problem and greater than 30 effects, including main and interaction effects,were pinpointed. The most significant main effects were BFRTM Closure,Pulp Mill Flow and Hardwood Pre-Bleach Conductivity. There were numerous significant interaction effects, some including up to four interacting factors, which is evidence of the problem's complex nature. To determine if the effects had been present during periods of"good" color performance, ANOVAs were performed on those periods as well. The only main effect that was statistically significant in impacting secondary effluent color from January 2002—July 2002 was Closure and there were no main effects nor interaction effects that were statistically significant for unaccounted color during the period of good color performance. As a result of the ANOVA studies, a daily color monitoring information report was created which tracks the color-impacting parameters via targets and 30-day trends. Closure was the most significant main effect contributing to elevated secondary effluent color. Given the increase in bleach plant filtrate that reaches the mill sewer when closure rates are low, there is a larger volume of low pH material available to undergo the Sewer Generated Color effect. Because it has been shown that Sewer Generated Color is not removed across the Wastewater Treatment Plant, lower closure rates translate into a measurable increase in secondary effluent color. In addition to being a main effect, closure was a statistically significant color-impacting variable in 13 different interaction effects as well. Pulp Mill flow was the second most significant main effect contributing to elevated secondary effluent color. Similar to closure, elevated flow from the Pulp Mill is likely to be low pH material,which is a pre-cursor for Sewer Generated Color. Hardwood Pre-Bleach Conductivity is the measure of conductivity from a pulp filtrate sample taken off of the Pre-Bleach washer. Elevated conductivity indicates increased carryover into that stage. Increased carryover from the pre-bleach stage can affect the 15 October 1, 2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina first stage of bleaching (D1), potentially requiring elevated acid usage on the D1 stage. This was observed during the period of elevated color and was also a statistically significant main effect and interaction effect in the ANOVA analyses. Elevated acid use in the bleach plant could intensify the Sewer Generated Color effect by further reducing pH. Also, it was believed that start-up of the entire mill from the Cold Mill outage required adequate time to reach stable operation. This stable operation was not achieved until mid-May. Challenges from the Cold Mill start-up had to be managed before the targets from the ANOVA Factorial analyses could properly be incorporated into the daily operation. At this point unaccounted color and secondary effluent color finally began reaching normal ranges. Incorporation of the results from the ANOVA studies into the Daily Color Monitoring Information report has proven to be a useful tool for color management at the Canton Mill. It is recognized that the conditions causing these effects may change in the future and new effects may need to be studied/evaluated. Since the Daily Color Monitoring Information report has been in use, the average secondary effluent color has dropped from 49,0241bs/day(average during November 2002 through April 2003 period of elevated color) to 42,6691bs/day. The Canton Mill is utilizing this new tool and will continue to use and develop innovative tools for troubleshooting color in the future. 16 October 1,2003 Report Blue Ridge Paper Products Inc. Canton,North Carolina V. Statistical Analysis of Data The average secondary effluent color from December 2001 through August 2003, excluding the period of elevated secondary effluent and unaccounted color, is 39,833 lbs/day. Based on a statistical evaluation of the mill's monthly average color performance, for the same period, the achievable secondary effluent color using a 95`h percentile distribution is 43,1891bs/day. The 2002 annual average secondary effluent color was 41,171 lbs/day. Blue Ridge is committed to continued color performance improvements and recommends an annual average secondary effluent limit of 42,000 lbs/day. Blue Ridge recommends a monthly average effluent limit of 52,000 lbs/day based on the color challenges encountered in the past year. Data for the December 2001 through August 2003 period is attached to this report. 17 Blue Ridge Paper Products Inc. Monthly Average Secondary Effluent Color: Dec-02 through Aug-03 Attachment 1: October 1, 2003 Report Monthly Average Ibs/day Month Secondary Effluent Color Dec-01 36,821 Jan-02 39,040 Feb-02 39,870 Mar-02 37,886 Apr-02 42,477 Monthly Average Ibs/day May-02 42,458 Secondary Effluent Color Excluding Nov-02-Apr-03 Jun-02 41,312 Dec-01 36821 Jul-02 41,686 Jan-02 39,040 Aug-02 40,750 Feb-02 39,870 Sep-02 39,480 Mar-02 37,886 Oct-02 36,382 Apr-02 42,477 Nov-02 48,014 May-02 42,458 Dec-02 44,701 Jun-02 41,312 Jan-03 51,269 Jul-02 41,686 Feb-03 48,324 Aug-02 40,750 Mar-03 50,412 Sep-02 39,480 Apr-03 51,423 Oct-02 36,382 May-03 40,955 May-03 40,955 Jun-03 42,458 Jun-03 42,458 Jul-03 44,734 Jul-03 44,734 Aug-03 42,527 Aug-03 42,527 2002 average 41,174 95th percentile 43,189 2003 ytd average 46,513 period average 40,591 95th percentile for 2003 51,369