WQ0011431_Regional Office Historical File Pre 2018

I
I
RECEIVEDINCDENRIDWR j
MAR i 3 2020 �
WQROS
MOORESVILLE REGIONAL OFFICE
2019 ANNUAL REPORT
LAND APPLICATION PROGRAM
TOWN OF CLEVELAND
PERMIT #WQ0011431
Compiled By:
Bio-Green Services, Inc.
383 Potts Road
Advance, NC 2700E
RECENEDJNCDE6I/DER
FEB 2 8 2920
January 2010
Non -Discharge
perrnming Unit

ANNUAL LAND APPLICATION CERTIFICATION FORM
Q WQ0011431 County: lRow"an earl
9
F d'efily ft Perini c (as shown on permit): Town Acie'veland
li
L nd, POperator: Bio-Green Services, Inc. Phone: 1�, 336 940-44,141 1
!
L Apd!appli6a ionl of residuals as allowed by the permit occurred during the past calendar year?
Q IYes'i '(] (� No If No, skip Part A, and Part B and proceed to Part C. Also, If:residuals Wer
gel edjb, I not land applied,'please attach an explanation on how the residu
al's were liandleid! !j ifi I! �f ''a '
Part sicuals ApplicatioR Summary:
th
Total number of application fields in the permit: T!
Total number of fields utilized for land application during the year:
Total I amount of dry tons applied during the year for all application sites]' 1�.�415 11:1111
1 Total 'number of acres utilizes fdr land application during'fhe year:
Pak B21 nhual lt'-iTiDiance Statement:
I! Facilit
I
Y V mpliant during calendar year I with all conditions of the'land applic6lti
'I IaF 18:` c: !1)! PI ,on per
,-�.,bu'ti;'not limited
s No
1111 ii; (ificludin to items 1-13 below) issued by the Division of Water Resources. Y
11 0 e
If no V6 I §s�i e; provide a written description why the facility was not compliant, the dates, and in corrective action
explain
en.
1 [c:;
;1110ilv bal§'approved for this permit were applied to the permitted sites.
ve
if
2)!I-Soil pN.i s: adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at,' east 6.0 r
N'!:Ithe lift.ffs permit. I
ecified in the
3) Annual soils s analysis were performed on each site receiving residuals during the pastcaleridar year and thr66 ies
of ldboiatoky results are attached.
14)- A
certified laboratory results are attache pnhWIIT� analysis (if required) was performed and three (j) copies of certif
H11 kiql,
11 5):All U& was performed in accordance with the perinit and reported during the year as r and Q)
i . I . e!
."copie J;: rtified laboratory results are attached.
6) 1 The;1' 11' did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .11105(4.) or ifill Plollittai i�
I if
I!,1,16ad hg,' hte§"in 15A NCAC 02T.1 105(b) (appli6able to 40 C!FRP'art 503teguldtled facilities).1 I 1i ill
11 j7)!All g hL.r requirements in as specified in the Land Application Permit were complied with abl'ito'40',Cl R Part, !!! 1 '! h (applic e
j4 J
if il',1503:r acilities).
it lif
wl* 8XAll ,f?1,.!tormg and reporting requirements in 15A NCAC 02T'. I I I I were complied with (applicable to 401.0 R
ik,
A r&& 01 - I ij�503edfacilities). ,I ,, + !
Ali:
II
9) All"6 t ons and maintenance requirements in the permit were complied with or, in the case of' a' d 1hboh p 1 deviation; ,
Tral V
,-,.,2utho izat on was received from the Division of Water Resources.
r 10Y No 60I i I.
1 ention of Ground Water Quality Standards occurred at a monitoring well or explanations f
I�Ikitt
ia do ed,alifie lud6 appropriate actions and remediations.
i fll)�Xegelativ,�lc&er'was maintained and proper crop management was performed on each site receingresiduals;! as
-:;SpecJ "I ,i the permi
ft 6f residuals from the application sites onto adjacent property ofln6arby surface w oce d.
12) T�ld waters has . lu
13;);All;b1 Ile irements,as specified on the permit were maintained during each applicatio"n d of residulals
Part C t4i Ication:
1113 terld 11n, er penalty of law, that the above information is, to the best of my knowledge and; bel , ief,.1trueka ou al
,1! and comfile 1 am aware that there are significant penalties foi- submitting false information'Incl dingli't
.1; p0s'sibili Vill f,fines and imprisonment for knowing violations."
d
AA o0e
II
1 1 WX R, ZZI
&.1nifte6 arr e and Title (type or print) Signature of PerAittee Date I I;
X� �^2V I r I� 'i : !� � ,►1 Is� �Ijl ► I' l
0 .,�,eparer* Date Signature 'of LandAp jili Tier
�Permittee)l
I Date
! H�2 if different from Permittee and Prep� re
Piepl4H;Ii�,! in 40 CFR Part 503.9 (r) and 15A NCAC 02T. 1102 (26) DENR FORM jACF (112,120,q6)11

SAMPLING SUMMARY FORM

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can .be reportedn FORM
WQ Permit Number: WQ0011431
Facility Name: Town of Cleveland
Residual Source WQ # or NCO049867
NPDES #:
WWTP Name: - Cleveland WWTP
RaciArial Analveie llata
Laboratory:
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m /k a
Sample or Composite Date
4/15/19
4/15/19
Percent Solids (%)
NA
2.28
2.28
Arsenic
75
0.402
0.402
Cadmium
85
1565
1565
Copper
4,300
591
591
Chromium
NA
0.5
0.5
Lead
840
0.43
0.43
Mercury
57
0.685
0.685
-
Molybdenum
75
14.5
14.5
Nickel
420
16.1
16.1
Selenium
100
<0.44
<0.44
Zinc
7,500
1399
1399
Total Phosphorus
NA
330
330
TKN
NA
43818
43818
Ammonia -Nitrogen
NA
-270.18
270.18
Nitrate and Nitrite
NA
3964.9
1 3964.9
a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signat Preparer * Date j
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
i
WQ Permit Number: WQ0011431 Laboratory: 1) Statesville Analytical F
Facility Name: Town of Cleavland 2)
Residual Source NC0049867 3)
NPDES # or WQ#: 4)
WWTP Name: Cleavland WWTP 5)
Residual Analvsis Data
meter
•(mg/kg).aluminum
or • .•site Date
list
"I certify, under penalty of law, that this document was prepared under my direction or supervision in -accordance with -a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
iignattfi-6-of Preparer
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF - B (1212006)

ANNUAL LAND APPLICATION SUMMARY FORM

_- ANNITALZAND APPI:TCATIONEIELD:SIRvI1AiZF-0;_-
- --
_ PLEASE MAKE A COPY OF THIS -BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED -ON -
_; PLACE -A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE:
-
h' WQ0,011431 - -- -Field#: -- - - - - -
I Acres Utilized: ".1 - - -
-Laiifd=Owner: GByr� _ _ ------ �►nnuat Dryliairs>Applied -t=7 54i5=- - --=Situ#: NC=RA-OI - Acres-Permitted:-10--
. - Operator: Same ._ .. - .. - -- - .....--
Crop 1 Name: Fescue_
Predominant Soil -Series: Enon
Crop 1 Max. PAN: 188 Crop 2 Name:
Cation Exchange Capacity (non 503):
Fescue Cron 2 Max. PAN:
°
a�
m °
Q
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
PP P
Acre
o Tons/Ac
(Dry )
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Wei
Moist)
Precip.
Past 24
Hrs.
inches
Y
c'o b
o
a. o
<
o
qy �;
�, _
N --
*
°
7
7� �
c;
* �,
*
]
TKN
mg/kg
Z y
ix
o
5
�.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
lbs/acre
( )
Name of CropType
yP
Receiving Residual
Application
Crop l
Crop 2
Crop I
Crop 2
may
90000
2.28
0.856
TOC
Dry
0
S
0.5
0.3
43817.5
270.175
3964.91
29.374
NA
F
Oct
94500
2.28
0.898
TOC
Dry
0
S
0.5
0.3
43818
270.18
3964.9
30.843
NA
F
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-
0.000
0.000-
-0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
_
0.000
0.000
0.000
0.000
0.000
0.000
0.000
710.000
y0.000
Residuals Applications totals
on FORM FSF supp ( attach FORM
FSF supp to this for;7).71
TOTALS:
R7 01
184500
.....:
As
Cd
Cu
r; Cr
Pb
rHg
Mo
Ni
Se
Zn,
P
60.21<7
-0.000
Lime. pplied
Annual
lbs/acre - -
0.014
54.900
20.732
--0.018
0.015
0.023
0.509
0.565 _-
#######
49.077 -
- 11.576
:'::`•:: <:::::::`•:::::':':::::::::::::::::::::
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.001
. 0.002
0.674
0.037
0.004
0,001
0.007
0.024
0.001
1.121
Current Cumulative lbs/ac
0.01'5
54.902
21.406
-0.055
0.019
0.024
0.516 '
0.589
#######
50.1�8
Permitted C. P. L. R.
36
34
1 1338
na
267-
15
na
374
89
1, 2498
Permit P.AN Limit= 1 st/2nd 'Prop
1 88
--1 certily, under penalty oI taw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted,_ I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*A lication Method: S - Surface; IN Injection, INC -Incorporation _ PP
2 ^20 "Volatilization Rate: Surface 0:5, Injection/Incorporation - 1:0 _ -
- Signature of Land Applier -- = = - Date --- = xx Mineralization Co t s• .Rate , Compost -0.1, anaerobially digested -0.2, -
aerobically digested -0.3, raw sludge -0.4
C:P L.R. Cumulative Pollutant-Loadfii Rate=
DENR FORM FSF (12/2006)

LAB SHEETS

Analytical Results
.� t. Alf � a:.. 4
NAUMC
L
Bio Green
Services
383 Potts Road
Advance, NC 27006
Receive Date:
04/15/2019
Reported:
05/30/2019
For:
Cleveland Digestor
Comments:
Sample Number
Parameter
Sample ID
Result
Unit
Method Analyzed
Analyst
190415-17-01
30 Day Benchscale
Cleveland
13.3
%
EPA625-R-92f0 04/15/2019
WC
190415-17-01
Aluminum
Cleveland
49000
mg/kg
EPA 200.7 rev4.4 1994 04/29/2019
MD
190415-17-01
Ammonia Nitrogen
Cleveland
270.175
mg/kg
SM45DONH3EE-1997 04/16/2019
CL
190415-17-01
Arsenic - Solid
Cleveland
0.402
mg/kg
SM3113 H-2004 04/30/2019
MD
190415-17-01
Cadmium ICP
Cleveland
1565
mg/kg
EPA200.7 04/24/2019
MD
190415-17-01
Calcium
Cleveland,
32300
mg/kg
EPA200.7 04/24/2019
MD
190415-17-01
Copper
Cleveland
591
mg/kg
EPA200.7 04/29/2019
MD
190415-17-01
Lead
Cleveland
0.43
mg/L
SM3113B-2004 04/17/2019
MD
190415-17-01
Magnesium
Cleveland
2330
mg/kg
EPA200.7 04/24/2019
MD
190415-17-01
Mercury Solid
Cleveland
0.658
mg/kg
SM3112B-2011 04/26/2019
MD
190415-17-01
Molybdenum
Cleveland,
14.5
mg/kg
EPA200.7 04/29/2019
MD
190415-17-01
Nickel
Cleveland
16.1
mg/kg
EPA200.7 04/29/2019
MD
190415-17-01
Nitrate/Nitrite -
Cleveland.
3964.91
mg/kg
SM4500F/A 05/01/2019
CL
Solids
190415-17-01
PAN
Cleveland
210.7
mg/L
calculation 05/02/2019
CL
190415-17-01
pH
Cleveland
5.65
Std. Units
SM4500H&2011 04/16/2019
MD
190415-17-01
Potassium - Solid
Cleveland
2510
mg/kg
EPA200.7 04/22/2019
Meritech
190415-17-01
SAR
Cleveland
2.06
%
calculation 05/02/2019
CL
190415-17-01
Selenium
Cleveland
<0.44
mg/kg
EPA 200.7 04/30/2019
MD
190415-17-01
T. Phosphorous
Cleveland
330
mg/L
SM450OPE-2011 04/25/2019
CL
190415-17-01
TCLP
Cleveland
See Attached
as Noted 04/16/2019
PACE
190415-17-01
TKN
Cleveland
43817.5
mg/kg
SM4500Norg &2011 04/17/2019
CL
190415-17-01
Zinc
Cleveland
1399
mg/kg
EPA200.7 04/29/2019
MD
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 45

Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
190415-17-01 Percent Solids Cleveland 2.28 % SM2540&2011 04/16/2019 MD
190415-17-01 Sodium - Solid Cleveland 415512 mg/kg SM 3111 B 04/18/2019 MD
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 o Statesville, NC 28687 • 704/872/4697
Page 2 of 45

Condition of Receipt
Sample Number 190415-17-01 Temp on Arrival: 3.2
Parameter Schedule:
Nitric Acid Received on Ice
Parameter Schedule:
Nitric Acid
Parameter Schedule:
Nitric Acid
Parameter Schedule:
Nitric Acid
Parameter Schedule:
Nitric Acid
Chemicals in containers, lab
Received on Ice
Chemicals in containers, lab
Received on Ice
Chemicals in containers, lab
Arsenic - Solid
Received on Ice
Chemicals in containers, lab
Copper
Received on Ice
Chemicals in containers, lab
Lead
Received on Ice
Chemicals in containers, lab
Selenium
Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Nitric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule: Sodium
Nitric Acid Chemicals in containers, lab
Received on Ice
Parameter Schedule: Sodium -Solid
Nitric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Nitric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Received on Ice
Chemicals in containers, lab
PO Box 228 - Statesville, NC 28687 • 704/872/4697
Page 3 of 45

ra
Parameter Schedule:
Parameter Schedule:
Received on Ice
Chemicals in containers, lab
Received on Ice
Chemicals in containers, lab
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: pH
Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Received on Ice
Parameter Schedule: TCLP
Received on Ice
Parameter Schedule: TKN
Sulfuric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule: Ammonia Nitrogen
Sulfuric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule: T. Phosphorous
Sulfuric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Parameter Schedule:
Received on Ice
Received on Ice
Parameter Schedule: Potassium
Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 4 of 45

Parameter Schedule: Potassium - Solid
Chemicals in containers, lab
Received on Ice
Parameter Schedule: Nitrate/Nitrite
Received on Ice
Chemicals in containers, lab
Parameter Schedule: Nitrate/Nitrite - Solids
Chemicals in containers, lab
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 45

Pace Analytical Services, LLC
er - 9800 KinceyAve. Suite 100
;aceAnalytreal Huntersville. NC 28078
mvw.pacelabsmn [phone]
ANALYTICAL RESULTS
Project: 190415.17.01
Pace Project No.: 92425692
Sample: 190415.17.01 Lab ID: 92425692001 Collected: 04/15/19 10:D0 Received: 04/16119 13:55 Matrix: Solid
Results reported on a 'dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010A
Flashpoint
>200 deg F 70.0 1 04/28/19 14:44
9D45 pH Solt
Analytical Method: EPA 9045D
pH at 25 Degrees C
6.7 Sid. Units 0.10 1 04/29/1911:23 H3
9095 Paint Filter Liquid Test
Analytical Method: EPA 9095E
Free Liquids
Fail 1.0 1 04M8/1917:55
733C S Reactive Cyanide
Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.32
Cyanide, Reactive
ND mg/kg 39.1 1 0412211917:39 04/22/1918:54
734S Reactive Sulfide
Analytical Method: SM 4500S2F-00 Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive
ND mg/kg 391 1 04/22/19 17:39 04/2211917:48
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced. except in lull.
Date: 05/28/2019 05:00 PM
wlthout the written consent of Pace Analytical Services, LLC. Page 6 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 15 of 45

L
Client:
STATF.SVILLE ANALYTICAL
122 Court Strcet - P.O. Box 228
Slalosyli1c. NC 286R7
[phone]
Address:
0-7
Contact Person:
I Phone # AX#
Chain of
Custody Record
pp # Requisitioned by: (rime M,7e)'
Custom
SampleIDM er
Time Sampled
(Grab Only)
F5ats Sampled
(Grab Ordy)
A
a.
V'W
P.aracters reclucsid for analysis
V
7TV
10015,irl
I
I
7-yr) rnaIV0-1
W-H3 IV
016 & Ud
Relinquished by. :�:��
Time am, Date
Sampled by:
R6celved by:
Time am, pm Date qkl •_'E�l
Transported by:
Relinquished by:
Time am, pm Date
Holding times met:
Received by:
Time am, pm Date
Compliance work:
Composite Sampling #1:
Time begin .am,
pm Date L_L_
Non-compliance work:
Time end —am,
pm Date _./_/�
Lab Comments: Samples Transported On Ice:
Composite Sampling #2
Time begin-....—
am, pm Date __1_J_
Time end _am,
pm Date _J__L—
Initials:

Meritech, Inc.
Environmental Laboratory
Y Laboratory Certification No.165
0. i.
Contact: C. Little Report Date: 5/1/2019
Client: Statesville Analytical
122 Court St
Statesville, NC 28677 Date Sample Rcvd: 4/18/2019
Meritech Work Order # 04181972 Sample: 190415.17.01 Grab 4/15/2019
Paramete Results Analysis Date Reporting Limit Method
Potassium, total 57.2 mg/I. 4/22/2019 1.00 mg/L EPA 200.7
I hereby certify that I have reviewed and approve these data. oz, ff
Lab ratoryRt presentative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 8 of 45

Arena
Chain of Custody Record (COC)
NPDES#:
Client; -5W1 I I I F A -%A - Phone:-- - -7 t'� Y7;Z - Cl-0(
Addre's:1;-L'z L)w-t--�k Fax:
-ST1qTM'h1 LLE M2Z. M- 0 Email:
Project:
P.OX:
Attention:.C.- UP TumAroundriimel
'RUSH work needs prior approval,
How would you like your report sent? LI Ofi�rees Ann1v
Circle all that apply. Email (preferred), Fax, Mail StAL -0 dAys) 5 Da s 24 - 48 Hrs
MER"'ITEC11 1'. 1 NC.
ENVIRONMENTAL LABORATORIES
I IN 1.642 Tamco Rd. Phone: [phone]
Reidsville NC 27320 Fax* 336-342-1522
Email: [e-mail]
www.meritechiabs.com
Sample Location and/or ID #
Sampling Dates & Times
Person Taking Sample (Sign/Print):
Lab Use Only
Start
End
Comp?
Grab?
ft of
Cont.
Test(s) Required'��-.
mice?
Yes I No
pH OK?
CI OK?
Date
Time
Date
Time
Y-7- MCP. iI q t �I - 0
Q
Temperature Upon
Receipt.,
Method of
Shipment:
Dechlorination (<0.5 ppm) of Ammonia, Cyanide, Phenol and TKN samples must be done In the field prior to preservation.
Comments:
Compositor #
Ui UPS
Jug #
Fed Ex
/ArerXhp��sults for regulatory purposps? Yes
No
Report results in: mg1L mg/,kg u g/L
Hand Delivery
Other ry
Relinquis e Time:
7%
Time: .4
7
Tirne.,,/.
RecKvedby: Date: Time:
M1L
Relinquislied try: Date: Time:
Received
�?a Fra lim
n
00
LD
00
r"I
U
ai
Ln
Ln
IU
M
V)4�
00
0
Do
0
CL

' _ , 4eAnaltical
Tom, � J'
jrwewpxefabtcam
May 28, 2019
Crystal Little
Statesville Analytical, Inc.
122 Court Street
PO Box 228
Statesville, NC 28687
RE: Project: 190415.17.01
Pace Project No.: 92425692
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Crystal Little:
Enclosed are the analytical results for sample(s) received by the laboratory on April 16, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Tyriek Hooks
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
,BpRATOF'
Page 1 of 36
PO Box 228 • Statesville, NC 28687 . 704/872/4697
Page 10 of 45

r.. aceAnalXical o
~_� wwwpacela6sahm
��
Project: 190415.17.01
Pace Project No.: 92425692
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Red Accreditation M L2417
Alabama Certification #. 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification.#: 04222CA
Colorado Certification M PA01547
Connecticut Certification M PH-0694
.Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification it: C040
Guam Certification
Florida: Cert E871149 SEKS WET
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391 -
KansasfTNl Certification M E-10358
Kentucky Certification #: KY90133
KY W W Permit #: KY0098221
KY W W Permit #,. KY0000221
Louisiana DHHfTNI Certification #: LA180012
Louisiana DEQITNI Certification M 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification 4. 9991
CERTIFICATIONS
Missouri Certification M 235
Montana Certification M Cer10082
Nebraska Certification #: NE-OS-29-14
Nevada Certification M PA014572018-1
New Hatnpshire/TNI Certification #. 297617
New Jersey/TNI Certification#: PA051
New Mexico Certification #: PA01457
New YorklTNI Certification #: 10888
North Carolina Certification M 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/MI Certification M PA200002-010
Pennsylvania/TNI Certification M 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification M 65-00282
South Dakota Certification
Tennessee Certification #: 02867
TexaslrNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Sol] Permit #: P330-17-00091
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Virgin Island/PADEP Certification
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Washington Certification M C868
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Charlotte Certification IDs
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Pace Analytical Services, LLC
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REPORT OF LABORATORY ANALYSIS
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Page 11 of 45

AaceAnalytical"
xrrwpacelabs-eon
-
Project: 190415.17.01
Pace Project No.: 92425692
i
Lab ID Sample ID
SAMPLE ANALYTE COUNT
Method
Analysts
Pace Analytical Services, LLC
9800 Klncey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Reported Laboratory
92425692001 190415.17.01
EPA 8081B
SEM
9 PASI-C
EPA 8082A
SEM
8 PASI-C
EPA 8082A
SEM
8 PASI-C
1
EPA6010D
SH1
7 PASI-A
EPA7470A
JMW1
- 1 PASI-A
-"
EPA 8270E
Bpi
18 PASI-C
EPA8260D
GAW
14 PASI-C
ASTM D2974-87
KDF
1 PASI-C
EPA 1010A
SMK
1 PASkA
EPA 9045D
SMK
1 PASI-A
EPA9095B
MDW
1 PASI-A
EPA 9014
PAS
1 PASI-PA
SM 4500S2F-00
PAS
1 PASI-PA
�1
REPORT OF LABORATORY ANALYSIS
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Without the written consent of Pace Analytical Services, LLC.
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Page 12 of 45

Pace Analytical Services, LLC
aceAnalyticalC 9800 KinceyAve. Suite 100
�1 -- Hunlersville. NC 28078
W*,pnetabs can
[phone]
ANALYTICAL RESULTS
Project: 190415.17.01
Pace Project No.: 92425692
Sample: 190415.17.01 Lab ID: 92425692001 Collected: 04/15/19 10:00 Received: 04116119 13:55 Matrix: Solid
Results reported on a 'dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081B Preparation Method: EPA 3510C
Leachate Method/Dale: EPA 1311; 04/23/1912:30 Initial pH: 4.68; Final pH: 5
gamma-BHC (Lindane)
ND uglL 0.50 1 04/24/19 12:09 0425/19 20:53 58-89-9
Chlordane (Technical)
ND ug/L 3.0 1 04124/19. 12:09 04/25/19 20:53 57-74-9
Endrin
ND ug/L 0.50 1 04124/19 12:09 04/25/19 20:53 72-20-8
Heptachlor
ND ug/L 0.50 1 04/24/19 12:09 6425119 20:53 7644-8
Heptachlor epoxide
ND ug/L 0.50 1 04124/19 12:09 0425119 20:53 1024-57-3
Methoxychlor
ND ug/L. 1000 1 04/24/19 12:09 04/25/19 20:53 72-43-5
Toxaphene
ND uglL 3.0 1 04/24/19 12:09 04/25/19 20:53 8001-35-2
Surrogates
Decachlorobiphenyl (S)
96 % 10-138 1 04124/19 12:09 04/25/19 20:53 2051-24-3
Tetrachloro-m-xylene (S)
84 % 10-110 1 04/24/19 12:09 04/25/19 20:53 877-09-8
8082 GCS PCB
Analytical Method: EPA6082A Preparation Method: EPA3546
PCB-1016 (Aroclor 1016)
ND ug/kg 1300 1 04/18/19 16:18 04/24/19 05:03 12674-11-2
PCB-1221 (Aroclor 1221)
ND uglkg 1300 1 04/18/19 16:18 0424/19 05:03 11104-28-2
PCB-1232 (Aroclor 1232)
ND. ug/kg 1300 1 04/18/19 16:18 0424/19 05:03 11141-16-5
PCB-1242 (Aroclor 1242)
ND uglkg 1300 1 04/18119 16:18 04/24/19 05:03 53469-21-9
PCB-1248 (Aroclor 1248)
ND ug/kg 1300 1 04/18/19 16:18 0424/19 05:03 12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/kg 1300 1 04/18119 16:18 0424/19 05:03 11097-69-1
PCB-1260 (Aroclor 1260)
ND ug/kg 1300 1 04/19/19 16:18 04/24/19 05:03 11096-82-5
Surrogates
.� Decachlorobiphenyl (S)
79 % 10-130 1 04/18119 16:18 04/24/19 05:03 2051-24-3
8082 TCLP PCBs RVE
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 04/23/19 12:30 Initial pH: 4.68; Final pH: 5
PCB-1016 (Aroclor 1016)
ND ug/L 1000 1 04/24/19 12:09 04/25/19 23:39 12674-11-2
PCB-1221 (Aroclor 1221)
ND ug/L 1000 1 0412411912:09 0425119 23:39 11104-28-2
PCB-1232 (Aroclor 1232)
ND ug/L 1000 1 04/24/19 12:09 04125/19 23:39 11141-15-5
PCB-1242 (Aroclor 1242)
ND uglL 1000 1 04124/1912:09 04125/19 23:39 53469-21-9
PCB-1248 (Aroclor 1248)
ND ug1L 1000 1 04/24/19 12:09 0425/19 23:39 12672-29-6
PCB-1254 (Aroclor 1254)
ND ug/L 1000 1 04/24/19 12:09 G4125119 23:39 11097-69-1
PCB-1260 (Aroclor 1260)
ND uglL 1000 1 0412411912:09 04/25/19 23:39 11096-82-5
Surrogates
Decachlorobiphenyl (S)
92 % 10-132 1 04/24/19 12:09 04/25/19 23:39 2051-24-3
6010 MET ICP. TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 05/01/19 18:34 Initial pH: 6.7; Final pH: 4.5
Arsenic
ND mg/L 0.050 1 0510311912:39 0510411916:08 7440-38-2
1g
Barium
ND mg/L 0.25 1 05/03/1912:39 0510411916:08 7440-39-3
19
Cadmium
ND mg/L 0.0050 1 05103/1912:39 05/04/1916:08 7440-43-9
1g
Chromium
ND mg/L 0:050 1 05/03/1912:39 05104/1916:08 7440.47-3
1g
Lead
ND mg/L 0.025 1 05/03/1912:39 05104/1916:08 7439-92-1
1g
Selenium
ND mg/L 0.10 1 05103/1912:39 0510411916:08 7782-49-2
1g
Silver
ND mg/L 0.025 1 05103/1912:39 0510411916:08 7440-22-4
1g
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 05/2812019 05:00 PM
without the written consent of PaceAnalylical Services. LLC. Page 4 of 36
PO Box 228 • Statesville, NC 28687 e 704/872/4697
Page 13 of 45

ell
aceAnalytical
xvnvpacdabs.�n.
ANALYTICAL RESULTS
Project: 190415.17,01
Pace Project No.: 92425692
Pace Analytical Services, LLC
9800 Kincey Ave- Suite 100
Hunlersville, NC 28078
[phone]
Sample: 190415.17.01 Lab ID: 92425692001 Collected: 04/15/19 10:00 Received: 04/16/19 13:55 Matrix: Solid
Results reported on a 'dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
7470 Mercury, TCLP
Mercury
8270E MSSV TCLP Sep Funnel
1,4-Dichlorobenzene
2,4-Dinitrotoluene
H exachloro-1,3-bu tad iene
Hexachlorobenzene
Hexachloroelhane
2-Me thyiphe nol (o-Cresol)
3&4-Melhylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S).
Terphenyl-d14- (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol(S)
8260D MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dici)loroben7ene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichlorcethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (5)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
Date: 05/28/2019 05:00 PM
Analytical Method: EPAT470A Preparation Method: EPA7470A -
Leachate Method/Date: EPA 1311; 05/01/19 18:34 Initial pH: 6.7; Final pH:4.5
ND mg/L 0.00020 1 05/02/1916:48 05/0311914:11 7439-97-6 19
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
NO
ug1L
50.0
1
04/24/19 22:40 04/25/1918:35 106416-7
NO
ug/L
50.0
1
04/24/19 22:40 04/2511918:36 121-14-2
NO
ug/L
50.0
1
04/24/19 22:40 04125119 18:36 87-68-3
ND
ug/L
50.0
1_
04/24/19 22:40 04/25119 18:36 118-74-1
ND
ug/L
50:0-
1
0412411922:40 0412511918`:36 67-72-1
NO
ug/L
50.0
1
04/24/19 22:40 04/25/19 18:36 95-48-7
NO
ug/L
50.0
1
04/24/19 22:40 0412511618:36 15831-10A
ND
ug/L
50.0
1
04/24/19 22:40 04/2511918:36 98-95-3
NO
ug/L
100
1
04124/19.22:46 D4125/19 18:36 87-86-5
NO
ug/L
50.0
1
04/24/19 22:40 04/25/19 18:36 110-86-1
NO
ug/L
60.0
1
04/24/19 22:4b 04125/1918:36 95-954
ND
ug/L
50.0
1
04/24/19 22:40 04125/19 18:36 88-06.2
50 %
71 %
113 %
7 %
5 %
17 %
Analytical Method: EPA82600
ND
ug/L
NO
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
NO
uglL
NO
ug/L
NO
ug/L
ND
ug/L
ND
uglL
ND
ug(L
103 %
108 %
103 %
Analytical Method: ASTM D2974-87
97.5 %
12-102
1
04124/19 22AO 04125/19 18:36 4165-60-0
13-107
1
04/24/19 22:40 04/25/19 18:36 321-60-8
21-132
1
04/24/19 22:40 04/2511918:36 1718-51-0
10-110
1
04/24/19 22:40 04/25119 18:36 13127-88-3 S2
10-110
1
04/24/19 22:40 04/2511918:36 367-12-4 S2
27-108
1
04/24/19 22:40 04/25/1918:36 118-79-6 S2
100
20
04126/19 03:11 71-43-2
200
20
04/26/19 03:11 78-93-3
100
20
04/26/19 0314 56-23-5
100
20
04/26/19 03:11 108-90-7
100
20
04/26/19 03:11 67-66-3
100
20
04/26119 03:11 106-46-7
100
20
04/26/19 03:11 107-06-2
100
20
04/26/19 03:11 75-354
100
20
04126/19 03:11 127-18-4
100
20
04/26/19 03:11 79-01-6
100
20
04/26/19 03,11 75-01-4
70-130
20
04/26/19 03:11 17060-07-0
67-135
20
04126/19 03:11 2037-26-5
70-130
20
04/26119 03:11 460-00-4
0.10
1
0411611917:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services: LLC.
Page 5036
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Page 14 of 45

,, / 9 e
O Analytical
mil/ dCEAM.PaU SCOM
vnxvpacela6swm
`
-
Project: 190415.17.01
Pace Project No.: 92425692
Pace Analytical Services, LLC
9800 ktncey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
,
Sample: 190415.17.01
Lab ID: 92425692001 Collected: 04/15/19 10:00 Received: 04/16119 13:55 Matrix: Solid
Results reported on a 'dry weight"
basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010A
Flashpoint
>200 deg F. 70.0 1 04/28/19 14:44
9045 pH Boll
Analytical Method: EPA 9045D
pH at 25 Degrees C
6.7 Sid. Units 0.10 1 04129/1911:23 H3
9095 Paint Filter Liquid Test
Analytical Method: EPA 9095E
Free Liquids
Fail 1.0 1 04/1611917:55
733C S Reactive Cyanide
Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive
ND mg/kg 39.1 1 04/22/19 17:39 0412211918:54
734S Reactive Sulfide
Analytical Method: SM 4500S2F-00 Preparation Method: SW-846 7.3.42
Sulfide. Reactive
ND mg/kg 391 1 04/22/19 17:39 04/22/19 17:48
REPORT OF LABORATORY ANALYSIS
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Date: 05/28/2019 05:00 PM
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PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 15 of 45

PaCeAnal ical
vnvlrPacdaM.cam
QUALITY CONTROL DATA
Project: 190415.17.01
Pace Project No.: 92425692
QC Batch: 472928 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92425692001
METHOD BLANK: 2563088
Associated Lab Samples: 92425692001
Parameter Units
Mercury mg/L
LABORATORY CONTROL SAMPLE: 2565344
Parameter Units
Mercury mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.00020 0510311913:55
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
0.0025 0.0024 95 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2565345 2565346
MS MSD
92425680001 Spike Spike MS MSO MS MSD % Rec
Parameter Units Result Cone. Cone: Result Result % Rae % Rec Limits RPD Qual
Mercury mgfL ND 0.0025 0.0025 0.0026 0.0026 104 103 75-125 '2
Results presented on this page arc In the units indicated by the -Units- column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 0512812019 05:00 PM without the written consent of Pace Ana"cal Services. LLC. Page 7 of 36
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Page 16 of 45

aceAnal ical
vnnvpacMa6smm
Project: 190415.17.01
Pace Project No.: 92425692
QC Batch: 472926
QC Batch Method: EPA 3010A
Associated Lab Samples: 92425692001
METHOD BLANK: 2563088
Associated Lab Samples: 92425692001
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
LABORATORY CONTROL SAMPLE: 2565337
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg1L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 601 OD
Analysis Description: 6010
MET TCLP
Matrix: Water
Blank Reporting
Result Limit
Analyzed Qualifiers
NO 0.050
05/0411915:38
NO 0.25
05/0411915:38
NO 0.0050
05/0411915:38
ND 0.050
05/04/1915:38
NO 0.025
05/04/1915:38
ND 0.10
05/04/19 15:38
NO 0.025
0510411915:38
Spike
Conc.
LCS
Result
LCS
% Rec
%Rec
Limits Qualifiers
2.6
2.3
92
80-120
2.5
2.3
93
80-120
2.5
2.4
94
80-120
2.5
2.4
94
80-120
2.5
2.3
91
80-120
2.5
2.4
97
80.120
1.2
1.2
96
80-120
MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE:
2565338
2565339
MS
MSD
92422459001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg!L
ND
2.5
2.5
2.3
2.3
94
92
75-125
2
Barium
mg/L
0.74
2.5
2.5
3.2
3.1
97
95
75-125
1
Cadmium
mg/L
NO
2.5
2.5
2.4
2.3
95
94
75-125
2
Chromium
mg/L
NO
2.5
2.5
2.4
2.3
96
94
75-125
2
Lead
mgfL
ND
2.5
2.5
2.3
2.3
92
91
75-125
2
Selenium
mg/L
ND
2.5
2.5
2.4
2A
97
96
75-125
1
Silver
mg/L
NO
1.2
1.2
1.2
1.2
96
95
75-125
1
Results presented on this page are In the units Indicated by the -Units" column except whore an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2019 05:00 PM without the written consent of Pace Analytical Services, I.I.C. Page 8 of 36
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el
aceAnalytical
wwwpacdabs.tom
Project 190415:17.01
Pace Project No.: 92425692
QC Batch: 471650
QC Batch Method: EPA 8260D
Associated Lab Samples: 92425692001
METHOD BLANK: 2559314
Associated Lab Samples: 92425692001
Parameter
1.1-Dichloroethene
1,2-Dichloroethane
1,4-Dichlorobenzene
2-Butanone (MEK)
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
QUALITY CONTROL DATA
Analysis Method: EPA 8260D
Analysis Description: 8260D MSV TCLP
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed Qualifiers
ug/L
NO
5.0
04/26/19 01:29
ug/L
NO
5.0
04126/19.01:29
ug/L
NO
5.0
04/25/19 01:29
ug/L
ND'
10:0
04/26/19 01:29
ug/L
NO
5.0
04126/19 01:29
ug/L
NO
5.0
04/26/19 01:29
uglL
NO
5.0
04/26/19 01:29
ug/L
ND
5.0
04/26/19 01:29
ug/L
NO
5:0
04/26/19 01:29
ug/L
NO
5.0
04/26/19 01:29
ug/L
NO
5:0
04/26/19 01:29
%
104
70-130
04/26/19 01:29
%
102
70-130
04/26/19 01:29
%
112
67-135
04/26/19 01:29
Pace Analytical Services, LLC
98001GnceyAve. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2559313
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
V 1,1-Dichloroethene
ug/L
50
46.6
93
70-130
1,2-Dichloroethane
ug/L
50
45.4
91
70-130
1,4-Dichlorobenzene
ug/L
50
49.3
99
70-130
2-Butanone (MEK)
ug/L
100
123
123
64-135
Benzene
ug/L
50
48.5
97
70-130
Carbon tetrachloride
ug/L
50
47.3
95
70-130
Chlorobenzene
ug/L
50
48.9
98
70-130
Chloroform
ug/L
50
43.7
87
70-130
Tetrachloroethene
ug/L
50
51.4
103
69-130
Tdchloroethene
ug/L
50
51.6
103
70-130
Vinyl chloride
ug/L
50
42.0
84
70-131
1,2-Dichloroethane-d4 (S)
%
92
70-130
4-Brornolluarobenzene (S)
%
93
70-130
Toluene-d8(S)
%
93
67-135
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2559315 2559316
MS MSD
92425692001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene ug/L NO 400 400 381 410 95 103 70-154 7
Results presented an this page are in the units indicated by the "Units" column exceptwhore an alternate unitis presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 05/28/2019 05:00 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 18 of 45

Pace Analytical Services, LLC
e
eAnalytical
9800 KlnceyAve- Suite 100
...� _
Runtersvlle. NC 28078
wawpacelabscom
[phone]
QUALITY CONTROL DATA
Project: 1904.15.17.01
Pace Project No.: 92425692
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2559315
2559316
MS
MSD
92425692001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
381
384
95
96
70-137
1
1,4-Dichlorobenzene
ug/L
ND
400
400
411
433
103
108
70-133
5
2-Butanone (MEK)
ug/L
ND
800
800
852
830
107
104
60.139
3
Benzene
uglL
ND
400
400
421
437
105
109
70-151
4
Carbon tetrachloride
ug/L
ND
400
400
427
469
107
117
70-143
9
Chlombenzene
ug/L
ND
400
400
412
424
103
106
70-138
3
Chloroform
ug/L
ND
400
400
352
386
86
94
70-139
9
Tetrachloroethene
ug/L
ND
400
400
415
424
104
106
59-143
2
Trichloroethene
ug/L
ND
400
400
459
450
115
112
70-147
2
Vinyl chloride
ug/L
ND
400
400
434
436
108
109
70-156
1
1,2-Dichloroethane-d4 (S)
e%
91
89
70-130
4-Bromofluorobenzene (S)
%
96
96
70.130
Toluene-d8 (S)
%
96
95
67-135
—1-1
Results pre—tod an. this page are in the units Indicated by the'UniW column except where an alternate unit Is presented to the right or the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 05/28/2019 05:00 PM without the mitten consent of Pace Analytical Services, LLC.
Page-10 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 19 of 45

~�
Pace Analytical Services, LLC
ceAnalytieal c
Vincey Ave. Suite 100
g800Huntersville,
NC 28078
W"pacelabs.Cam
[phone]
QUALITY CONTROL DATA
Project: 190415.17.01
Pace Project No.: 92425692
QC Balch: 471215
Analysis Method: EPA 8081 B
QC Balch Method: EPA 3510C
Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92425692001
METHOD BLANK: 2555379
Matrix: Water
Associated Lab Samples: 9242,9692001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Chlordane (Technical)
ug/L
ND 3.0
04/25/19 20:40
Endrin
ug/L
NO 0.50
04/25/19 20:40
gamma-BHC (Lindane)
ug/L
ND 0.50
04/25/19 20:40
Heptachlor
uglL
ND 0.50
04/25/19 20:40
Heptachlor epoxide
ug/L
NO 0.50
04/25/19 20:40
Methoxychlor
ug/L
ND 1000
04/25/19 20:40
Toxaphene
ug/L
ND 3.0
04/25/19 20:40
Decachlorobiphenyl (S)
%
93 10-138
04/25/19 20:40
Tetrachloro-m-xylene (S)
%
64 10-110
04/25/19 20:40
LABORATORY CONTROL SAMPLE: 2557097
Spike LCS
LCS %
Rec
Parameter
Units
Cone. Result % Rec Limits Qualifiers
Endrin
ug/L
1.2 1.1
89
20-134
gamma-BHC (Lindane)
ug/L
1.2 1.1
87
20-118
Heptachlor
ug/L
1.2 1.0
81
20-142
,.� Heptachlor epoxide
ug/L
1.2 1.1
91
22-133
Methoxychlor
ug/L
3.8 3.7.1
97
44-150
Decachlorobiphenyl (S)
%
93
10-138
Tetrachloro-m-xylene (S)
%
82
10-110
MATRIX SPIKE SAMPLE: 2557098
92425245001 Spike
MS
r0s
% Rec
Parameter
Units
Result Conc.
Result
e/ Rec
Limits Qualifiers
Endrin
ug/L
ND 1.2
1.1
86
21-133
gamma-BHC (Lindane)
ug/L
NO 1.2
1.0
83
24-119
Heptachlor
ug/L
ND 12
0.95
76
16-128
Heptachlorepoxide
uglL
ND 1.2
1.0
81
50=150
Methoxychlor
ug/L
ND 3.8
3.SJ
94
50-150
Decachlorobiphenyl (S)
%
82
10-138
Tetrachloro-m-xylene (S)
%
77
10-110
SAMPLE DUPLICATE: 2557099
92425245002 Dup
Parameter Units Result Result RPD Qualifiers
Chlordane (Technical) Ug/L ND NO
Endrin ug/L NO NO
Results presented on this page are in the units Indicated by the -Units- column except where an alternate unit is prosented to the right of the re-ft.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced. except in full.
Date: 05/2812019 05:00 PM without the written consent of Pace Analytical Services, I.I.C. Page 11 of.36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 20 of 45

7�aceAnalyfical m
w�nvpacela6s.mn•
QUALITY CONTROL
DATA
Project: 1904.15:17.01
Pace. Project No.: 92425692
SAMPLE DUPLICATE: 2557099
92425245002
Dup
Parameter
Units
Result
Result
gamma-BHC (Lindane)
ug/L
NO
ND
Heptachlor
ug/L
NO
ND
Heptachlor epoxide
ug/L
ND
NO
Methoxychlcr
ug/L
ND
ND
Toxaphene
ug/L
ND
ND
Decachlorobiphenyl (S)
%
93
78
Tetmchloro-m-xylene (S)
%
93
72
RPD Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page am in the units Indicated by the'Units" column except he. an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28!2019 05:00 PM without the written consent of Pace Analytical Services. LLC.
Page 12 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 21 of 45

�aceAnal ical
" w.vwAacela6smn
QUALITY CONTROL DATA
Project: 190415.17.01
Pace Project No.: 92425692
QC Batch: 470280
QC Batch Method: EPA 3546 -
Associated Lab Samples: 9242569200.1
Analysis Method:
Analysis Description:
EPA 8082A
8082 GCS PCB
METHOD BLANK: 2553290
Matrix: Solid
Associated Lab Samples: 92425692001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
PCB-1D16 (Aroclor 1016)
ug/kg
ND
33.6
04/24/19 07:08
PCB-1221 (Aroclor 1221)
ug/kg
ND
33.6
04/24/19 07:08
PCB-1232 (Aroclor 1232)
ug/kg
ND
33.6
04/24/19 07:08
PCB-1242 (Aroclor 1242)
ug/kg
ND
33.6
04/24/19 07:08
PCB-1248 (Aroclor 1248)
uglkg
NO
33.6
04/24/19 07:08
PCB-1254 (Aroclor 1254)
uglkg
ND
33.6
04/24/19 07:08
PCB-1260 (Aroclor 1260)
uglkg
ND
33.6
04/24/19 07:08
Decachlorobiphenyl(S)
%
86 10-130
04/24/19 07:08
LABORATORY CONTROL SAMPLE:
2553291
Parameter
Units
PCB-1016 (Aroclor 1016)
ug/kg
PCB-1260 (Aroclor 1260)
ug/kg
Decachlorobiphenyl (S)
%
MATRIX SPIKE SAMPLE:
2553292
Parameter
Units
PCB-1016 (Aroclor 1016)
uglkg
PCB-1260 (Aroclor 1260)
ug/kg
Decachlorobiphenyl (S)
%
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
169 164 97 35-130
169 129 76 46-130
91 10-130
92425960001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 206 174 85 10-130
ND 206 125 61 10-130
71 10-130
Results presented an this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS "
This report shall not be reproduced, except in full,
Date: 05/2812019 05:00 PM without the written consent of Pace Analytical Services. LLC. Page 13 of 36
PO Box 228 a Statesville, NC 28687 e 704/872/4697
Page 22 of 45

_ r.PaceAnalytic a-1
�•
lrmvpacNaAswn
QUALITY CONTROL DATA
Project: 190415.17,01
Pace Project No.: 92425692
Pace Analytical Services, LLC
9800 KlnceyAve. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 471354
Analysis Method:
EPA 8082A
QC Batch Method: EPA 3510C
Analysis Description-
8082 TCLP PCB RV
Associated Lab Samples: _ 92425692001
METHOD BLANK: 2555379
Matrix: Water
Associated Lab Samples: 92425692001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
NO
1000
04/26119 00:04
PCB-1221 (Aroclor 1221)
ug/L
NO
1000
04/26/19 00:04
PCB-1232 (Aroclor 1232)
ug/L
NO
1000
04126119 00:04
PCB-1242 (Aroclor 1242)
ug/L
NO
1000
04/26/19 00:04
PCB-1248 (Aroclor 1248)
ug1L
NO
1000
04/26119 00:04
PCB-1254 (Aroclor 1254)
ug/L
NO
1000
04/26/19 00:04
PCB-1260 (Aroclor 1260)
ug/L
NO
1000
04/26/19 00:04
Decachlorobiphenyl (S)
%
89 10-132
04/26/19 00:04
LABORATORY CONTROL SAMPLE:
2557804
Spike LCS
LOS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
25 NO
90
38-113
PCB-1260 (Aroclor 1260)
ug/L
25 NO
76
35-120
Decachlorobiphenyl (S)
%
98
10-132
MATRIX SPIKE SAMPLE:
2557805
92425245001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
NO 25
NO
82
19-142
PCB-1260 (Aroclor 1260)
ug/L
NO 25
NO
64
19-142
Decachlorobiphenyl (S)
%
77
10-132
SAMPLE DUPLICATE: 2557806
92425245002
Dup
Parameter
Units
Result
Result RPD Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
NO
NO
PCB-1221 (Aroclor 1221)
ug/L
NO
NO
PCB-1232 (Aroclor 1232)
ug/L
NO
NO
PCB-1242 (Aroclor 1242)
ug/L
NO
NO
PCB-1248 (Aroclor 1248)
uglL
NO
NO
PCB-1254 (Aroclor 1254)
ug/L
NO
ND
PCB-1260 (Aroclor 1260)
ug/L
NO
NO
Decachlorobiphenyl (S)
%
91
76
Results presonted on this page are in the units indicated by the -Units' column except where an altemate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This;report shall not be reproduced. except in full,
Date: 05/28/2019 05:00 PM without the written consent or Pace Analytical Services. LLC. Page 14 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 23 of 45

aceAnalytical
� www.pacelabs.cum
Project: 190415:17.01
Pace Project No.: 92425692
QC Batch: 471352
QC Batch Method: EPA3510C
Associated Lab Samples: 92425692001
METHOD BLANK: 2555379
Associated Lab Samples: 92425692001
Parameter
2,4,6-Tribromophenoi (S)
2-Fluorabiphenyl (S)
2-Fluorophenol (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Terphenykdl4 (S)
QUALITY CONTROL DATA
Analysis Method: EPA 8270E
Analysis Description: 8270E TCLP MSSV
Matrix: Water
Blank
Reporting
Units
Result
Limit
Analyzed Qualifiers
%
90
27-108
04/25/1910:33
%
67
13-107
04/25/19 10:33
e/
18
10-110
0412511910:33
%
68
12-102
04/25/19 10:33
10
10-110
04/25/1910:33
e/
85
21-132
04/2511910:33
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2557796
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
500
317
63
10-110
2,4,5-Trichlorophenol
uglL
500
393
79
39-108
2,4,6-Trichlorophenol
ug/L
500
412
82
40-104
2,4-Dinitrololuene
ug/L
500
430
85
42-109
2-Methylphenol(o-Cresol)
ug/L
500
302
60
31-110
3&4-Methylphenol(m&p Cresol)
uglL
500
265
53
30-110
Hexachloro-1,3-butadiene
ug/L
Soo
260
52
10-110
Hexachlorobenzene
ug/L
500
424
85
39-121
Hexachloroethane
ug/L
500
232
46
10-110
Nitrobenzene .
ug/L
500
362
72
32-101
Pentachlorophenoi
ug/L
1000
737
74
18-108
Pyridine
ug/L
500
179
36
10-110
2,4.6-Tribromophenol (S)
%
92
27-108
2-Fluorobiphenyl (S)
%
77
13-107
2-Fluorophenol(S)
%
40
10-110
Nitrobenzene-d5(S)
%
76
12-102
Phenol-d6(S)
%
24
10-110
Terphenyl-dl4 (S)
%
88
21-132
Results presonted on this page are In the units Indicated by the -Units' coturnn except where an altomate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This:report shall not be reproduced, except in full,
Date: 05/2812019 05:00 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 24 of 45

,eAnalltical
J '
wwwpacdabscom
QUALITY CONTROL DATA
Project: 190415.17.01
Pace Project No.: 92425692
QC Batch: 469764 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry WeighUPercent Moisture
Associated Lab Samples: 92425692001
SAMPLE DUPLICATE: 2550987
92425391001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 20.5 20.0 2
SAMPLE DUPLICATE: 2550989
92425692001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 97.5 97.4 0
Pace Analytical Services, LLC
9800 Kincey Ave_ Suite 100
Huntersvilie, NC 28078
[phone]
Results presented on this page am In the units rndicatod by the -Units" column except whore an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced except in full.
Date: 05/2812019 05:00 PM without the written consent at Pace Analytical Services: LLC. Page 16 ot.36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 25 of 45

aceAnalytical o
wmvpacelabs.com
Project: 1904.15,17.01
Pace Project No.: 92425692
QC Batch: 471992
QC Batch Method: EPA 1010A
Associated Lab Samples: 92425692001
SAMPLE DUPLICATE: 2561048
Parameter Units
Flashpoint deg F
QUALITY CONTROL DATA
Analysis Method: EPA 1010A
Analysis Description: 1010 Flash Point, Closed Cup
92426441001 Cup
, ' Result Result RPD Qualifiers
>200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersvflle, NC 28078
[phone]
Results presented an this page ate in the units Indicated by the 'Units" column except where an allemate unit Is presented to the right of tho result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, -
Date: 05/2812019.05:00 PM without the written consent of Pace Analytical Services, I.I.C. Page 17 of.36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 26 of 45

_ �Anal4ical"
wsrwpacelabs.com
Project: 190415.17.01
Pace Project -No.: 92425692
QC Batch:, 471999
QC Batch Method: EPA 9045D
Associated Lab Samples: 92425692001
SAMPLE DUPLICATE: 2561062
Parameter
pH at 25 Degrees C
SAMPLE DUPLICATE: 2561063
Parameter
pH at 25 Degrees C
QUALITY CONTROL DATA
Analysis Method: - EPA 9045D
Analysis Description: 9045 pH
92425490001 Dup
Units Result Result RPD Qualifiers
Std. Units 5.4 5.5 2 H3
92426076004 Dup
Units Result Result RPD Qualifiers
Sid. Units 7.4 7.4 0 H3
Pace Analytical Services, LLC
9800 KlnceyAve. Suite 100
Hunlersville, NC 28078
[phone]
Results presented on this page are In the units Indicated by the 'Units' column exsoptwham an alternateunit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05128/2019 05:00 PM without the written consent of Pace Analytical Services: LLC. Page 18 of 36
PO Box 228 • Statesville, NC 28687 a 704/872/4697
Page 27 of 45

t
F.�1,,PaceAna1yfica1"
w:nvpacela6s.com
Project: 190415.17.01
Pace Project No.: 92426692
QC Batch: 470323
QC Batch Method: EPA 90956
Associated Lab Samples: 92425692001
SAMPLE DUPLICATE: 2553508
Parameter
Free Liquids
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville. NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 9095B
Analysis Description: 9095 PAINT FILTER LIQUID TEST
92425692001 Dup
Units Result Result RPD Qualifiers
Fail Fail
RaeuIts presented on this page era In the units indicated by the "units" column except whom an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
Thisreportshall not be reproduced. except in full.
Date: 05/28/2019 05:00 PM without the written consent of Pace Analytical Services. LLC.
Page 19 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 28 of 45

aceAnal ical
wxwpac"S.com
QUALITY CONTROL DATA
Project: 190415:17.01
Pace Project No.: 92425692
QC Batch: 339303 Analysis Method: EPA 9014
QC Batch Method: SW-846 7.3.3.2 Analysis Description: 733C Reactive Cyanide
Associated Lab Samples: 92425692001
METHOD BLANK: 1651467
Associated Lab Samples: 92425692001
Parameter
Cyanide, Reactive
Matrix: Solid
Blank Reporting
Units Result Limit Analyzed Qualifiers
mg/kg ND 1.0 04/22/1918:38
LABORATORY CONTROL SAMPLE:
1651468
Parameter
Units
Cyanide, Reactive
mg/kg
SAMPLE DUPLICATE: 1651469
Parameter
Units
Cyanide, Reactive
mg/kg
Pace Analytical Services, LLC
9800 Kincoy Ave- Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
99A ND 0 0-8
30289318001 Dup
Result Result RPD Qualifiers
NO ND
Results presented on this page am in the units Indicated by the 'Units' column except whore an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28/2019 05:00 PM. without the written consent of Pace Analytical Services. I.I.C. Page 20 of 36
PO Box 228 a Statesville, NC 28687 • 704/872/4697
Page 29 of 45

/ ,PaceAnalXical "
w*vpace!abs.con.
Project: 190415:17.01
Pace Project No.; 92425692
QC Batch: 339302
QC Batch Method: SW-846 7.3.4.2
Associated Lab Samples: 92425692001
METHOD BLANK: 1651463
Associated Lab Samples: 92425692001
Parameter
Units
Sulfide, Reactive
mglkg
LABORATORY CONTROL SAMPLE: 1651464
Parameter
Units
Sulfide, Reactive
mg/kg
SAMPLE DUPLICATE; 1651465
Parameter
Units
Sulfide, Reactive
mglkg
Pace Analytical Services, LLC
980010ncey Ave. Suite 100
Huntersvlle. NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: Ski 4500S2F-00'
Analysis Description: 734S Reactive Sulfide
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 10 0412211917:48
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
199 35.8 18 0-52
30289318001 Dup
Result Result RPD Qualifiers
ND ND
Results presented on this page are In the units indicated by the 'Units' column except where an altomate unit is presented to tho right of the resulL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Full, ...
Date: 05/2812019 05:00 PM without the written consent of Pace Analytical Services. LLC. Page 21 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 30 of 45

j aceAnal�/'tical
- imwpacelaDsmm
QUALIFIERS
Project 190415617.01
Pace Project No.: 92425692
DEFINITIONS
Pace Analytical Services, LLC
9800 KnceyAve- Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported: represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL- Practical Quantitalion Limit.
RL - Reporting Limit -The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydra7ine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable -
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260. .
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyle is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute:
LABORATORIES
PAST -A Pace Analytical Services -Asheville
PASI-C Pace Analytical Services - Charlotte
PAS[ -PA Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
1g The temperature in the TCLP/ZHE extraction area was outside the method required range of 21-25 degrees C.
H3 Sample was received or analysis requested beyond the recognized method holding time.
g2 Surrooate recovery outside laboratory control limits duo to matrix inlerforonces (confirmed by similar results from sample
re -analysis).
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/28!2019 05:00 PM without the written consent of Pace Analytical Services.-L.W.
Page 22 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 31 of 45

/7Pa1ce Analytical
ewxpacelabtwm
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 190415.17,01
Pace Project No.: 92425692
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92425692001
190415.17.01
EPA 3510C
471215
EPA 80818
471416
92425692001
190415.17.01
EPA 3546
470280
EPA 8082A
470695
92425692001
190415.17.01
EPA 3510C
471354
EPA 8082A
471417
92425692001
190415.17.01
EPA 3010A
472926
EPA 6010D
473223
92425692001
190415.17.01
EPA 7470A
472928
EPA 7470A
472965
92425692001
190415.17.01
EPA 3510C
471352.
EPA 8270E
471456
92425692001
190415.17.01
EPA 8260D
471650
92425692001
190415.17.01
ASTM D2974-87
469764
92425692001
190415.17.01
EPA 1010A
471992
92425692001
190415.17.01
EPA 90450
471999
92425692001
190415.17.01
EPA90958
470323
92425692001
190415.17.01
SW-8467.3.3.2
339303
EPA9014
339409
92425692001
190415.17.01
SW-B46 7.3.4.2
339302
SM 4500S217-00
339407
Date: 05/2812019 05:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full.
without the written consent of Pace Analytical Services, LLC.
Page23 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 32 of 45

aceAna�ocal'
Document Name:
Sample Condilion Upen Recei t(SCUR
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.06
Issuing authority:
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑
Huntersville '< RalelehM
Wa# : 9242569ia
. - - If Client Name:
Project
t `
Courier: [Fed Ex QUP5 QUSPS
❑ Commercial OPace ❑Other._
[]Client
92426I92
Custody Seal Present? ❑Yes QNo Seals Intact? ❑Yes
QPo
Date/tnilials Person Examining Contents:
Packing Material: ❑Bubble Wrap ❑Bubble Bags []NonerD- Other Biological Tissue .
Therrhometer:
'01116un ID; 92TO48 Type of lee: QWet
±Frazen?
❑Yes ❑No []N/A
❑Blue ❑none
Cooler Temp ('C): '- (: Correction Factor: Add/Subtract ('C) p,()
- ( -
Cooler Temp Corrected ('C):
Temp should be above freezing to VC
[]Samples out of temp criteria. Samples on ice, cooling process
USDA Regulated Soil ([5 N/A, water sample)
has begun
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples origirrote from a foreign source [internationally,
My— nR !_-,...__.,...._ __.,�_ __�.__„ri..-_ "".._
Comments/Discrepancy:
Chain of Custody Present?
Yes
[No
❑N/A
1.
Samples Arrived within Hold Time?
yes
❑No
❑N/A
2.
Short Hold Time Analysis 02 hr.)?
❑Yet
No
❑NIA
3.
Rush Turn Around Tlme Requested?
Des
91No
❑N/A
4.
Sufficient Volume?
's Yes
❑Na
❑NIA
S.
Correct Containers Used?
-Pace Containers Used?
❑Yes
❑No
ONO
[3N/A
N/A
6.
Containers Intact?
Dyes
ONG
ONIA
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
ONO
.E]N/A
B.
Sample Labels Match CCC?
-Includes Date/Time/10/Analysis Matrix:
i❑Yes
ONO
❑N/A
9.
Headspace In VOA Vials (>5-6mm)?
Yes
[]NO
, ,. N/A
io.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
Dyes
ONO
❑Nn
[jN/A
.❑lNIA
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time: _
Project Manager SCURF Review:
Project Manager SRF Review:
Date:
Date:
Field Data Required? []Yes ❑No
Page 24 of 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 33 of 45

I
O
Co
O
x
N
N
00
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(D
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to �
LD
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9
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H
n v
a 2
3
p
a v
c�
5
0
Rome
8P4U-125 mL Plastic Unpreserved (N/A) (a-)
BPBU-250 mL Plastic Unpreserved (NIA)
MU-500 mL Plastic Unpreserved (N/A)
SP1U•1 lifer Plastic Unpre3erved (N/A)
BP4S-125 mL Plastic H25D4 (pli < 2) (CI-)
BP3N-25O mL plastic HNO3 (pH < 2)
BP4Z-125 mL Plastic ZN Acetate & NaOH (a9)
BP4C-125 mL Plastic NaOH (pH � 12) (O-)
WGFU-Wide-mouthed Glass Jar Unpreserved
AG1U-1 Ilter Amber Unpreserved (N/A) (CI-)
AGM-1 liter Amber HCI (PH <2)
AG3U-250 mL Amber Unpreserved (N/A) (CI-)
AG1S-1 liter Amber H2SO4 (pH < 2)
AG3S-250 mL Amber H2504 (pH < 21
AG3A(DG3A)-2SO mi. Amber N114CI (N/A)(CI-)
DGSH-40 mL VOA "Cl (N/A)
VG9T-40 mi. VOA Na2S203 (N/A)
VGSU-40 ml VOA Unp (N/A)
OG9P.40 mL VOA 143PO4 (N/A)
VOAK (6 Viats per kit) -SOBS kit (N/A)
V/GK 13 vials Per kit)-VPHIGaS kit (NIA)
SPST-125 mLSterlle Plastic (N/A — tab)
SP2T-250 mLSterile Plastic (NIA —lab)
11P3A-2SO mL Plastic(NH2)2SO4 (9.3.9.7)
AGOU-100 mL Amber Unpreserved vials (N/A)
VSGU-20 ME. Scintillation vials (N/A)
DG9U-40 mL Amber Unpreserved vials (N/A)

CHAIN -OF -CUSTODY / Analytical Request Document
....'Pace/InalAcal The ChNn-ol-CUSlody -a a LEGAL DOCUMENT, All relevant gle.lds FrIz,l be con1p,
Wled accuralNy
Section A Section B
Re4ulmd CIienl Infamiaticn. I —.— I . .......... . Section C
GrKn- psy
EQ
To
:Alcmon:
—nY is
Ccinrnny No—
FF-IJ I.:
tz. K
P-11— QIWI NI.
Requnelea -110 Wt./TAT:
, eoon V.Ild Mar
oq.[,.o cuL,.,l 10--n
Cod-
16,
l
fli
SAMPLE ID
.,Impe IDs NIUS-, BE UNIQUG 'iWlti
c
w
tx
TIT
. h
I DATE
2
IT�
3
7
10
11
12
ADOITIDNAL COMMENTS
ey�
J
"Y P.—.11, 1. In, "I" in I
F-ALL-0-020re%Q7. IS-Feb-2007

;ZeAnalytical- ANALYTICAL REPORT
kE
%
1r
��r,_.:c�•rur _:: April 25, 2019
Pace Analytical - Huntersville, NC
Sample Delivery Group: L1090481Cn
Samples Received: 04/1812019
Sr
Project Number: 92425692
-Description: 190415.17.01
c
Site: 001
Report To: Tyriek Hooks
9800 Kincey Avenue, Suite 100
Huntersville. NC 28078
J'
Entire Report Reviewed By:
jAVI
1
Nancy McLain
Project Manager
Res_h,,late owy to the items tested ur W bbalad and are rpC:•led a,, roanded gaUeS. TKS test report shall not be
reprcduced.e:CeG: in f0l, Snlhait vmllert appr szl et.:he 131301R:05'. V7rmapcllaab1e. 9-0 in9 r01-dncted bfpace Notional
�
is pedowted pei ;uid� 1e prarded In sloadvil eperaling p ccedu,s: 060302, 060303,:utd 060304.
ACCOUNT: PROJECT: SDG: DATEMME: PAGE
Pace Analytical - Huntcasw!e. 4C 92425692 L1090481 04.254912.35 1 of 10.
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 36 of 45

TABLE OF CONTENTS oNE L,-s NATI:DNWIDE.
Tc-, Table of Cantents
Ss: Sample Summary
3
T
Cn: Case Narrative
4
.._:.'
Sr: Sample Results
5
Sc
190415.17.01 L1090481-01
5
Cc: Quality Control Summary
6
rn]
Chlorinated Acid Herbicides (GC) by Method 8151A
6
Sr
GI: Glossary of Terms
7
A;:
Sc: Sample Chain of Custody
9
ci
ACCOUNT:
Pace Anal fecal - Huntersvitle. NC
Page 28 of 36
PROJECT: SDG: DATEMME: PAGE:
92425692 L1090431 04:25119 12:35 2 of 10
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 37 of 45

SAMPLE SUMMARY ONF i.Al, NAT W)NIAIDE. ZA
Ccll-rtcd b-i
1904115.17.01 L1090481-01 Waste 0411519 10:00, 08AS
Method
Preparation by f0leillod 1311
ChIctinated Acid Herbicides (GQ by Method 9151A
ACCOUNT:
Pace Anrlytscal - HuMcisville. NC
Balch
VIG1270125
kl.'G1270887
PROJECT:
92425692
Dilution Preparation
eatphirne
1 MOM 20:03
1 04.:24!19 07:35
SDG:
L1090491
Analysis Ana!rsl
04122.q9 20,03 CGD
04124:19 22:28 KW
DATE/TIME.'
04125M912:35
Location
ILL Juliet, TN
10t. Juliet. TN
Page 29 of 36
PAGE:
3 oflo
PO Box 228 9 Statesville, NC 28687 - 704/872/4697
Page 38 of 45

CASE NARRATIVE ONE CAS NATIONVITE=. M
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples El
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative; a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my S�
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that.would affect the quality of the data.
-Sr
IOc
ik LV-,,
u
Nancy McLain
Project Manager '
Page 30 of 36
ACCOUNT: _ PROJECT: SDG: DATE(riME: _ PAGE:
Pace Analn+cal • Huntemille. NC: 92425692 L1090481 04.25d91235 a -of t0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 39 of 45

WG1270887
QUALITY CONTROL.. SUMMARY
Chlor,naled Acid Nelbicides (CC) by Method 8151A
L!D904fii•01
(MB)R3405082-1 04)i4/1914:43
1.18 Result MB O. Mier NIB MDL
MB RDL
- - Aiwyie mg4 mg4
_ .._ .... _'
mgil
.. _. ....._. ..
;,._
i ':
2.A41 U p.PG0657
O.D32D0
.
2,4:5-TP(59,Fq U 0.000667
0.00200
tS5
- 07.4-D±cr'waRxW. Ac P
ACN fi5.6
i4 GLS?
_
'Ctl
L5(:Ufd(.•ty ai^.t `';8n;,'sIE Q f S1
(LCSIR3405082.204t<49914.57
- Spike Amount LCSResult LES Rea
R-Limi15 LES OualiOer
Anah/te mg!] mg4 %
b
,
2.44) 0.0500 0.6117 83A
50 -120
2.4,54P ISIve.) 0.0500 00405 812
50.0-125
pdrf 85.0
i40158 _
e
sampie ! %sl - Matrix $,.)ii--< (:'•.=ji - :iiii' x Dliw=%0��i)Cili r., d"'S''X
(0S) U(1903G3.01 04124191526 - (hf,S) R3405082-3 04?24/191539
- (NI501 R3405082.4 0474(191553
- �!
{
Spike Amount Original Result M ilesuit
MSD R-11 MS Rec. MSORe4.. Dulti.o
Rm Llmils IAS OuaGOer MSD Oua66n RPD
.. RPD Lai$
A-yte mg7 my? mgrl
Ruy7 -
2.4-D 0.0510 ND 00500
0,0440 100 89.6 1
500.60 11.0
20
.. 2,4,5.TP(Siveu) 0.M00 RD 0.0395
0.7350 79.0 W.0 1
50.0-125 12.1
20
6)2.4 r:p upr: ry/A;rlic
Atir7
6'Q4 721
[l0-158
. ' Page 32 of 36
ACCOUNT: PROJECT: sm- DATEMME: PAGE:
Pxd Anlay11a1-77anler„Jk. RC 92425692 LIG90181- D4/2S'1912:.35 - 6N70
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 41 of 45

A..
GLOSSARY OF TERMS ONE LAG,NATIC'Ntr'E.
Guide to Reading and Understanding Your Laboratory Report
The Information below is designed to better explain the various terms used in your report of analytical results frost the Laboratory. This is not -
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Abbreviations and Definitions
--•---
LEI
MDL
Method Detection Limit
ND -
Not detected at the Reporting Limit (or MDL where applicablef.
RDL
Reported Detection Limit-
Rec.
Recovery -
ROD
Relative Percent Difference.
Cn
SDG
Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) = Analytesadded to every blank, sample, Laboratory Control Sampte/Duplicate and
Matrix Spike/Duplicale: used evaluate analytical efficiency by measuring Surrogates not to be
Fri
recovery. are expected
detected in all environmental media. -
U
Not detected' at the Reporting Limit (or MDL where, applicable).
h><C
Analyte
The name of the particular compound or analysis performer!. Some Analyses and Methods will have multipleanalyses
reported.
If the.sample matrix contains an interfering material, the sample preparation vol in or weight vathee [ties differ from e
Dilution
standard, or if. concentrations of analyses In the sample are higher than the highest limit of concentration that the
laboratory.can accurately report: the sampte may be diluted for analysis.. tf a value different than 1 is used in this field, the
result reported has already been corrected for this fader.
These are the target b recovery ranges or % difference value that the laboratory has historically determined as normal
^�
Limits -
for the method and analyte being reported. Successful QC Sample analysiswill target all anatyles recovered or
duplicated within these ranges.
Original Sample
Tile non spiked sample in the prep batch used to detemline.the Relative PercentDifference (ROD) from a quality control'
sample The Original Sample may not be included -within the reported" SDG.
This column provides a letter and/or number designation that corresponds to additional infomtation concerning the result
Qualifier
reported. If a Oualiner is present, a definition per.Qualifler is provided vi(hin the Glossary, and Definitions page and
potentially a discussion of possible Implications of the Qualifier in the Case Narrative if applicable.
The actual' analytical final result (corrected for any sample specific characteristics) report ad for your sample. If there was
no measurable result returned for a specific bnalyte..the result in this colmmn,may state 'ND' (Not. Detected) or'BDL-
Result
(Below Detectable Levels). The information in the results column should always be.accompanied by either an MDL
(Method DetecdonLimit) or RDL '(Reporting Detection Limit) that defines the lowest value that thelaboratory could detect
or report for this anaiyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma
_
A brief discussion about the included sample results. including a discussion of any non,con(ormances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during:the analytical process. If present, there. will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used (n the report
Quatity.Conirol
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Oc)
analytical methods to assist In evaluating the validity of the results reported for your samples. These analyses are not
being.performed on your samples typically, but on laboratory generated material.
This is the document created:lit the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
crate of collection,�the{person collecting the samples, and the analyses that the laboratory Isrequested to perform. This
..
Custody (Sc)
chain of custody also documents all persons (eacluding.commercial shippers) thathave had controLor possession ofihe
samples from"tile time of collection until delivery to the laboratory for analysts:
This section of your repoMmil provide the results of all testing performed on your samples. These results are provided
-Sample Results Sr)-
by sample to and are separated by the analyses perfomied on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported
Sample Summary (Ss)
This. section of the Analytical Report defines the specific analyses performed for each sample -to' including the dates and
times of preparation and/or analysis. _
Qualifier Description
The remainder of this page intentionally left blank, there are no qualifiers applied to this SDG.
ACCOUNT:
Pace Ansfylicai- HuntcrsAle. NC
Page 33 of 36
PROJECT: SDG: DATE/TIME - PAGE
92425692 - L1090481 04!25ri9 7235 - - 7 of i0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 42 of 45

ACCREDITATIONS & LOCATIONS Ot4Et;.6 t4ljIONARDE.
---.
., .Pace National is the environmental W6amlory acaetliledfCertified to supWrt your work nail from oBomonelcaton l Oneplmna toll<ora point the collective et other lab is as
accessible or prepared to handle your needs throughout the country. Our capacity' and capability from our single location laboratory is comparable to the collective [clots of the network
laboratories in our industry. Tile most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity,decreasing
trim-armorddme. and wevenung crass crummanation. thus protecting sample integrity. Ourfocus on premium quality andpramptservi a allows uslo be YOUR LAO OF CHOICE.
' Natal] certifications held by the laboratory am applicable to,tile results reported In the attached mpon. "
' Accreditation is only applicable to the test methods specified an each scope of accreditation held by Pace NAUonal.
-
..
iC
ebr.
40660 _.. Naska
Alabama .. _ - ... _ _ _ _ ..
NE-OS
-
. _,..._.
Alaska 17.026 - Nevada
7N 03-2002.34
-
Arizona AZO612 New Hampshire
2975 "
a
Arkansas - 88-0469 Nevi Jersey -NEW
TNO02
Cn
California 2932 - New Mexico'"
ma
Colorado TN00003 New York
11742
.'
Connecticut PH-0197 North Carolina
Env375
S f
Florida - EB7487 - North Carolina' -
DV/2t704
Georgia . NELAP North Carolina' -
41
rCC
923- Korth Dakota _ __. .-
Georgia' _ .-..
9
R•140 _.. _ _
.. .. _.
._. ...
Idaho TN00003 _ Ohio-VAp
CL0069
200008 - Oklahoma
Illinois -
9915
7
IndianaGTN-01 Oregon
TN2000W
G�
Iowa 364 - Pennsylvania
68-02979
Kansas E-10277 Rhodeisland
LA000356
84004
y„'T
' �^ 900I0 Soufl Carolina -.....___
Kentucky .._ -. _.._- ., .... .... _ . .: ,_ .._
_
Kentucky' 16 South Dakota
Ni
A130792 - _ Tennessee" _.
20 6
-
Lours;.ana - _.. .. .
" 1A180010
T10 45.16•I5
7042
..
Louisiana ...._ _Texas
iN0002 � Texass
1A80162
Maine
Maryland 324 Utah
TN00003
massacinselts M-TN003 ' Vermont
_ -
%R006
- ... . _._ .. _ . .-
9958 .. - _ ..... _-.. - _ Nrgmra..._.._
Michigan.-
460.132
.....
f4innesota 047-999-395 Washington,
C847
Mississippi - TH00003 ._. .._ .. _. ._Vlestvuglnia . _• _.
.
Mlssaud 340 _ \Ylsconsm
_ 9980939910 "
Montana CERT0086 Wyoming
A2LA .
A2LA-IS017025� 1961.01 W..---.�..w•.. AIHA•LAP,LLC EMLAP
100789
A2LA-ISO 17025s 1461.02' DOD
_ 1461.01
_ ._.
Canada 146101 USDA
P330-15-00234
- EPA-Crypto TNUM03
'Drinklag Water ' Underground Storage Tanks 'Aquatic Toxicity 'ChemlcaUMicro nilogical sMOW °LVasleLvaler nla Accredrtalionnotapplicabte
Pace National has.sixly-lom client support centers that provide sample pickup mWor the del" of sampling supplim.11 you would Irke assistance from one of out support offices, please contact
our main office Pace National pedorms all testing at our contial laboratory.
r
: < i
h > c 9
/
s'A .•y ,�,z ; h
AL
Tx I -A
AX FL
. t
_ .. Page 34 of.36
ACCOUNT: PROJECT: SDG: Ewvr - - PAGE
Pace Arialyhcal - Huntefsvilie. NC 92425692 1-10904131 04.2SA91235 8 of 10
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 43 of 45

............... I .................
Chain of Custody
/!W8cIeAnaIytica(
Jr
Warkorder: 024256q? VV—In-!.' NJ
Twlek Hanks
pac e Aymlyt� -zl
Pace Nat;onal
P.o,
9809 Kinoey A 0. SUIle. 1 ()0
I JuntersVille, NC 28078
1.2065 Lebanon Rd
Phone [phone]'-2
Mt Juliet, T-N 37122
Email:
61.5-75&.5858
state f Samole OrIqUn NC
11 Rem
samp'OD
. . —
O*WTIMV'
-
J-111 ID
LAB UK, ONLY
. .......... . ......... . . ........... .
rII
. ............... . .. . .........
. .........
J
. .... —
—
—
---------
- ---
.
. .......
. . .
.
. ....
.... .
.
.
..... .
[
.
. ........ . . . ...... .
.....
.......
.......
4
. . ...... .
Iitansfers
RefeasP.d By
DMOTime
.
Rea., , 'd By
. . ..........
..........
Oh's
f" tell I t
. .....
lCoole Temperatureon Receipt C Cust—Ody'-Seal
Y or Received on Ice
or N Samples Intact 1Y or N
F036
............
LI�3ci" E-1 I 1., '5 7 qO
RAD SCi7laTnlj: FT)fylr
F&AT-ALL-O.W.2re, M; '.4NMTCJ1V',,W.
pap.s of 56 1
PO Box 228 - Statesville, NC 28687 e 704/872/4697
Page 44 of 45

Cooler Receipt
Iai_�nr.
Innovation' -
•
Cu,;ler ftirri:<ri.:+Jrnrait 4)R:J I a l
1'rnrl;cr•,it:r : 3'U
ti4::,•:.l•U t±Y: :�l'rsE i{7 iS'ill�r _
-
Receipt Check List
NP
Yes
No
COC Seal Present i Intact?
COC Signed f Accurate?
`
Bottles arrive intact?
Correct'bottles used?
Sufficient volume sent?
Id Apsilicable
VOA Zero headspace?
t=reseruaiton.forrectLCheckdd7-:
' -
Page 36 & 36
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 45 of 45

a
I
VECTOR ATTRACTION REDUCTION UAL PATHOGEN AND FORM (02T Rules),
WQ Permit Number: WQ001 311.
u
; f Clevelad
aciliiAMP' own 0
W NC9049"867-1
W NPDES Number:
TIP� Cleveland VPNTP
12/31/2019
M t�r 01111 1'Period: From 1/1/2019 To
ath CAC 02T .1106) - Please indicate 1��l 'achieved' and 'alternative peifo ed:
dge rM
jaction (15A N
ii-i­'Class ""A". Aij
Alt, A (time El Alt B (Alk Treatment)[] "Alt. C'(Pri6r Testing)
(time/temp)
Ali D (No Prior Test) 0 Process to Further Reduce Pathogengs LJ
If oppilc4l I10,
to, alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":,
ompbsf 11
Heat Drying El Heat Treatment 0 ThermOphiliC 0
Beta Ray
V: - 0
1 Gamma Ray El
Pasteurization U
(1) Fecal Density 21 Alt. (2)Process to Significantly, Reduft Pathogens El
#a,ppikalg 61$e"t4l!Alte;rn2itive
performed (Class B only) indicate "Process to Significantly Reduce Pathogens".
Lime gia I
Air DryingEl Cbmposting 11 Aerobic Digestio
.............. ...................
Anae
.............
.. ........
In stio
Xiapplic i'AeI
alternative performed (Class A or Class B) complete the following monitoring data!::
9
PE
Density NumDer ot Frequency S��ple"
Allowable Level Pathogen Dens Freq
-al
of Analysis Type!
Tech'
in Sludge Minimu Mean Maximum Units
Geo.
I
2x 10 to the MPN 132743 225601 394737 mpn/gr 0 annual grab
e'�
6th power
iiIII per gram o,
CFU
Fb' 1,Cot
1l total solids
�lj
p 1000 mpner gram
of total (dry
weight)
Salmonella
e a 1 MPN per 4 grams
total solid (dry
C
Vector Afty
_j I
lweight)
(15A NCAC 02TA107) - Please indicate alternative performed: �1: A'11,
Alt. I (US, f
,#c'tion-Reducti.
c4on) [I Alt. 2 (40-day bench) E3 Alt. 3 (3 0-day bench) P �Alt. 4, (Spec. 02 uptake) !IT
I' Cl�
,�lt;­5.(i4,�",
ay;Aerobic)- 0 Alt. 6 (Alk. Stabilization Alt 7 (Drying - Stable) El Alt. 8 (Drying - Unstable), dd,
AA]t. i ig � (Wn"l
0[I' Alt. 10 (Incorporation) El No vector Attraction reduction alternatives were performed
CERTIFIC"ATION
STATEMENT (please check the appropriate statement)
rtify, under penalty of law , that the pathogen requirements in 15A NCAC .02T.�10fiand
1',0cjt4_',r attraction reduction requirement in 15A NCAC: 02h.110716ave.,6ee� nut
the' !
under of law, that the pathogen requirements in 15i NCAC 0' 2T .1106
and Ithe
it "
certify, penalty
attraction: reduction requirement in 15A NCAC 02T.1107 have not been met."' (Plea'sell,no
V�Vlv c t r attrac
Oct
, 1
j4,
i114!
ot check this statement attach an explanation why you have not met one or bo, th of the
1 i,
,
"This! d6lee"ini
uirements.)
sion in accordancewith the' 7
ation has been made under my.direction and supervi,
I I n
tep�
iine
_d esig 6d
toWen u e that qualified personnel properly gather and evaluatelthe information. usedfo,
iii
il!hiit the,
4th en' and vector attraction reduction requirements have been met. I am aware that there
are
s ifledi
e� a4fie for false certification including fine and 'imprisonment."
'p:
fi _z
and it e (type or print) Land Appifer Name and Title (if appjicable)fty�q
9r, PpT
Pre r
Signature
f frepd r er Date Signaof Land Applier (if applicable)
D" ate
P reper
S de ' med in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Tj
DENR FORM IPVR�F=Qi
�l( W2

Town of Cleveland
Non -Discharge Permit No. W00011431
2019
Sample Date
Fecal `Coliform : '
; MPN/ ram d wea ht
=Log . 1
= f
�' 09%24/19
213,675
5.33
J P09/24/19
221,239
5.34
09/24/19
225,225
5.35
09/24/19
246,305
5.39
09/24/19
132,743
5.12
09/24/19
394,737
5.60
09/24/19
216,450
5.34
Total 37.47
Average 5.35
Geometric Mean - 225,60L; Fecal Coliform - MPN/gram dry weight
Geometric Mean of Less than 2,000,000 mets Class B -Alternative 1 Pathogen Reduction
Town of Cleveland Fecals 2019.xis
Page 1

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STATFSVII,LEANALYTICAL
122 Court Street P.O. Box 228
Address:
Statesville, NC 78687
[phone]
Chain of
Contact Person:
I Phone # FAX#
PO 1 rQ Y&V0,12t ,
Requisitioned by;(Time Date)
Custody Record
Customer
Sample 10#
Lab-lD #
Time sampled
(Grab Only)
Date Sampled
(Grab Only
Matrix
w
my
t�t�aten requested t'or andysis'
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Time Qh, pm Date �,l.. l Sel pled by:
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Time am m Date ll "1 f
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Relinquished by: - _
Time am, pm Date —/ / Holding times met:
Received by:
II Time am, pm Date
Compliance work::
Cotttp031te Sampling #1
i
Time begin am, pm Date ^/_/_
Non-compliance work:
i
Time end am, pm Date
v
Lab Comments: Samples Tr
COMRoslte Sampling 2:
nsported On Ice;
--
Time begin am, pm Date
Time end am, pm Date _/ /_
Initlals:
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` Condition of Receipt
{ j Sample Number 190924-23-01 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
i J Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
i
Chemicals in containers, lab
Sample Number 190924-23-02 Temp on Arrival:
Parameter Schedule: Percent Solids
_ - — ---- - — - -- - - - : - Received on Ice -
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 190924-23-03 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
' Sample Number 190924-23-04 Temp on Arrival:
Parameter Schedule: Percent Solids
- — Received on Ice --
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 190924-23-05 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
t
PO Box 228 - Statesville, NC 28687 - 704/872/4697
Page 2 of 4

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2018 ANNUAL REPORT
LAND APPLICATION PROGRAM
TOWN OF CLEVELAND
PERMIT #WQ0011431
Compiled By:
Bio-Green Services, Inc.
383 Potts Road
Advance, NC 27006
January 2019
M`
RECEIVEDINCDENR/DWR
MAR 18 2019
WQROS
MOORESVILLE REGIONAL OFFICE
®INc'DS0@NlR
E e 2019
IJ�AR 1
r —N
— - -- - 1AAR o 7019
IR

Town of Cleveland
PO BOX 429
Cleveland, NC 27013
704-278-4777
NC PERMIT # NC0049867
The Honorable Danny Gabriel -Mayor
Town of Cleveland
PO BOX 429
Cleveland, NC 27013
704-278-4777
LAND APPLIERS:
Bio-Green Services, Inc.
383 Potts Road
Advance, North Carolina 27006
2018 Total Dry Tons 11.739
2018 Total Metric Tons 10.68

January 1, 2018
NCDEQ-DWR
512 N Salisbury St
61h Floor Room 640-A
Raleigh, NC 27604
Attention: Information Processing Unit
Reference: 2018 LAND APPLICATION ANNUAL REPORT
Town of Cleveland
Permit No. WQ0011431
Non -Discharge Compliance Unit:
Bio-Green Services, Inc. (Bio-Green) is submitting all monitoring and reporting requirements as
specified in the above referenced permit. Bio-Green compiled this report using data gathered during
the compliance year by Bio-Green and the Town of Cleveland. This data includes:
1) Certification Form required by permit
2) Sampling Summary Form
3) Application Field Summary Form
4) Metals Field Loading Summary Form
5) Lab Sheets
6) Pathogen and Vector Reduction Form
7) Soil Analysis
If there is any further information required or questions regarding this annual report please do not
hesitate to contact Bio-Green for further assistance.
Sincerely,
Ray Gambill
NC Land Application/Residuals Operator

TABLE OF CONTENTS
SECTION NO. TITLE
I
Annual Land Application Certification Form
Form ACF
II
Annual Residual Sampling Summary Form
Form RSSF
III
Annual Land Application Field Summary Form
Form FSF
IV
Annual Metals Field Loading Summary Form
Form MFLSF
V
Lab Sheets (Analytical Data)
VI
Annual Pathogen and Vector Reduction Forms
VII
Soil Analysis

ANNUAL LAND APPLICATION CERTIFICATION FORM

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0011431 County:
Facility Name (as shown on permit):
Land Application Operator:
Rowan
Bio-Green Services, Inc.
Year: 2018
Town of Cleveland
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
0 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the ermit:
1
Total number of fields utilized for land application during the year:
1
Total amount of dry tons applied during the year for all application sites:
11.739
Total number of acres utilizes for land application during the year:
10
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2018 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. i] Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T. I 105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Permittee Name and Title (type or print)
Signature of P ittee Date
Sign" re of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

SAMPLING SUMMARY FORM

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0011431
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual Annlvcis Dntn
Town of Cleveland
NCO049867
Cleveland WWTP
Laboratory: 1) Statesville Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
5/26/18
Percent Solids (%)
,-NA
2.04
Arsenic
75
5.88
Cadmium
85
0.98
Copper
4,300
630
Chromium
NA
0.05
Lead
840
1.274
Mercury
57
0.706
Molybdenum
75
7.35
Nickel
420
25.2
Selenium
100
2.45
Zinc
7,500
1323.5
Total Phosphorus
NA
22060
TKN
NA
54902
Ammonia -Nitrogen
NA
2580.4
Nitrate and Nitrite
NA
0.1
- - -- ---- - Y ---- -- .,., —r, Un ttwM. abLVU ul uns corm are not appacame. Keterence the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel pro erly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting fal in ati n, including the possibility of fines and imprisonment for knowing violations."
Signature of Prepa;-ex.,*
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL LAND APPLICATION SUMMARY FORM

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Town of Cleveland WQ Permit #: WQ0011431 Field #: 1 Acres Utilized: 10
Land Owner: G Byrd Annual Dry Tons Applied: 11.7394 Site #: NC-RA-01 Acres Permitted: 10
Operator: Same Predominant Soil Series: Enon Cation Exchange Capacity (non 503):
Crop 1 Name: Fescue Crop 1 Max. PAN: 188 Crop 2 Name: Fescue Cron 2 Max. PAN:
o
Volume applied
pP
Volume
Residual Sources
Soil
Cond.
Precip.
o
4 `b
<
o
4
a
Z B
Nitrate
Name of Crop Type
N C
(enter one) Solids/
%
Applied per
PP P
(NPDES #, WQ#,
Past 24
;n �;
„ _
z �,
m .,
TKN
o
and
PAN Applied
ReceivingResidual
Q
Liquid
Solids
Acre
Fert., Animal
(Dry'
Hrs.
o w
* N'
w'
°°
a
Nitrite
(lbs/acre)
Application
Cu. Yds Gallons
(Dry Tons/AC)
Waste, etc)
Wet,
Moist)
inches
a �.
* °
w
°
a
* ;v
* o
mg/kg
mg/kg
mg/kg
Crop 1
Crop 2
Crop 1
Crop 2
Jan
53000
2.04
, 0.451
TOC
Dry
0
S
0.5
0.3
54902
2580.39
0.1
15.317
NA
F
June
85000
2.04
0.723
TOC
Dry
0
S
0.5
0.3
54902
2580.4
0.1
24.566
NA
F
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
`:.
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this formJ39.883
TOTALS:
0
138000
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
0.000
Lime A lied
Annuallbs/acre
0.014
0.001
0.015
36
0.002
0.002
1 0.004
34
1.479
0.674
2.153
1338
0.000
0.037
0.037
na
0.003
0.004
0.007
267
0.002
0.001
0.003
15
0.017
0.007
0.024
na
0.059
0.024
0.083
374
0.006
0.001
0.007
89
3.108
1.121
4.229
2498
53.774
Date
Ibs/ac
Prior Years Cumulative lbs/ac
Current Cumulative lbs/ac
Permitted C. P. L. R.****
Permit PAN Limit l st/2nd Crop
188
III L..y, u11uc1 l7CII211Ly 01 law, milt ims aocument was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
✓ Z0 % **Volatilization Rate: Surface - 0.5, Injection/Incorporation -1.0
Signatur f Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
r1FAIR F(1DRA CCC /'loionnaN

ANNUAL METALS FIELD LOADING SUMMARY FORM

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Town of Cleveland Total Dry Tons Applied (Annual): 117.81
Permit #: WQ0011431 Cation Exchange Capacity (non 503 only):
erator: Bio-Green Services, Inc. Owner: G Byrd Predominant Soil Series: Enon
Acres Used: 10 Acres Permitted: 10 Site #: NC-RA-01 Field #: 1
Residual Analvsis Data (Heave Metals and Total Phn.cnhnrnc »vP mcdlra o/ cnrfic ,.ca Paxw Pav- ant 411.
Com-
..
Date
6 MIMEMENEENEENE1
nuai rieavv ivietai r iew Loaainss (ualculatea in ws/acre):
Total
1 1
L2J
L31
4j
i
i 6
7
8
9
10
11
12
DT/Ac./
c
App-
Event
11.78
y
Arsenic
0.139
0.000
.0.060
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
0.139
Cadmium
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Copper
14.844
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14.844
Chromium
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Lead
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Mercury
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
denum
0.173
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.173
Nickel
0.594
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000 1
0.000
0.594
Selenium
0.058
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.058
Zinc
31.185
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31.185
Total
Phos-
539.617
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
horus
1
1
1
1
1
Ll
it cerniy, unuer penalty of ►aw, tnat tors aocument was prepared under my airection or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
)risonment for knowing violations".
Signa a of Land Applier Date
DENR FORM MFLSF (12/2006)

LAB SHEETS

TOWN OF CLEVELAND LAND APPLICATION PROGRAM 10.002
RESIDUALS ANALYSIS
Residual Type: Wastewater Treatment Plant
Date Sample May 23,2018
Permit No. WQ0011431
Mineralization rate 0.30 2.04% Solids
7.14pH
Parameter
%
PPM (ma/kq)(% *10.000)
Lbs/DryTon (Mq/Kq * 0.002)
PAN Surface
16986.778
33.973556
PAN Injection
18276.973
36.55
TKN
54902
109.804
Ammonia Nitrogen (Am)
2580.39
5.16078
Nitrate Nitrogen (Nin)
0.1
0.0002
Organic Nitrogen (Orn)
0
0
Total Phosphorus (P)
22060
44.12
Total Phosphate (P205)
0
0
Estimated Avail. P205
0
0
Total Potassium (K)
3090
6.18
Total Potash (K20)
0
0
Arsenic (As)
5.88
0.01176
Cadmium (Cd)
0.98
0.00196
Chromium (Cr)
0.05
0.0001
Copper (Cu)
630
1.26
Lead (Pb)
1.274
0.002548
Mercury (Hg)
0.706
0.001412
Molybdenum (Mo)
7.35
0.0147
Nickel (Ni)
25.2
0.0504
Selenium (Se)
2.45
0.0049
Zinc (Zn)
1323.53
2.64706
Aluminum (AI)
651.961
1.303922
Calcium (Ca)
43382.4
86.7648
Iron (Fe)
0
0
Sodium (Na)
1617.65
3.2353
Sulfur (S)
0
0
Magnesium (Mg)
3520
7.04
Manganese (Mn)
0
0
Statesvuie Analytical :180523-19-02
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N)+ Ammonia N + Nitrate N +Nitrate N - % PAN
Surface Application
(Mineralization Rate) (TKN-Ammonia N)+ (0.5) (Ammonia N) + Nitrate N +Nitrate,N - % PAN
Note: Constituents N.D. (Not Detected) or < direction limits are listed as detection limits for calculation purposes.
4500.gallon loads 13.00 PAN

Analytical Results
3io Green Services
383 Potts Road
Advance, NC 27006
' Receive Date: 05/23/2018
Reported: 06129/2018
' For: CL Ray
Comments:
1
Sample Number
Parameter
Sample ID
Result
Unit
Method
Analyzed
Analyst
'
180523-19-01
TCLP
CL1
See Attached
as Noted
05/25/2018
PACE
180523-19-02
Aluminum
CL2
651.961
mg/kg
SM 3111 D-2011
06/05/2018
MD
'180523-19-02
180523-19-02
Ammonia Nitrogen
Arsenic
CL2
2580.39
mg/kg
SM4500NH3BE-1997
SM3113 B-2004
06/01/2018
MD
- Solid
CL2
5.88
mg/kg
05/29/2018
MD
180523-19-02
Cadmium - Solid
CL2
0.980
mg/kg
SM3111B-1999
06/06/2018
MD
'
180523-19-02
Calcium
CL2
43382.4
mg/kg
SM3111B2011
06/05/2018
MD
180523-19-02
Lead -Solid
CL2
1.274
mg/kg
SM3113B
05/30/2018
MD
180523-19-02
30523-19-02
Magnesium
Mercury Solid
CL2
CL2
3520
0.706
mg/kg
mg/kg
EPA200.7
SM3112B-2011
06/05/2018
06/12/2018
MD
MD
180523-19-02
Molybdenum - Solid
CL2
7.35
mg/kg
EPA200.7
06/05/2018
MD
'180523-19-02
Nickel - Solid
CL2
25.20
mg/kg
SM3113 B
06/07/2018
MD
180523-19-02
Nitrate/Nitrite -
CL2
<0.1
mg/kg
SM450OF/A
06/07/2018
CL
Solids
'
180523-19-02
Percent Solids
CL2
2.04
%
SM254OB-1997
05/24/2018
CL
180523-19-02
pH
CL2
7.14
Std. Units
SM4500HB-2011
05/23/2018
MD
180523-19-02
Potassium
CL2
3090
mg/kg
EPA200.7
06/01/2018
ENCO
I180523-19-02
SAR
CL2
0.29
%
calculation
06/07/2018
CL
180523-19-02
Selenium Solid
CL2
2.45
mg/kg
SM3113B
05/29/2018
MD
180523-19-02
Sodium - Solid
CL2
1617.65
mg/kg
SM 3111 B
06/05/2018
MD
180523-19-02
T. Phosphorus Solid
CL2
22060
mg/kg
SM450OPE-2011
05/29/2018
CL
180523-19-02
TKN
CL2
54902
mg/kg
SM4500Norg B-2011
05/30/2018
CL
I180523-19-02
Zinc - Solid
CL2
1323.53
mg/kg
SM3111B-2011
05/29/2018
MD
180523-19-03
30 Day Benchscale
CL3
10.3
%
EPA625-R-92/0
05/24/2018
WC
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Pagel of 40

ISample Number Parameter
Sample ID Result Unit Method Analyzed Analyst
160523-19-02 Copper
1.80523-19-02 PAN
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
1
EPA #NC00909
1
CL2 630 mg/kg EPA 200.7
CL2 346.5 mg/L Calculation
05/29/2018 MD
06/12/2018 CL
PO Box 228 • Statesville, NC 28687 . 704/872/4697
Page 2 of 40

I - Condition of Recei t
P
ISample Number 180523-19-01 Temp on Arrival: 2.3
Iv
Parameter Schedule:
TCLP
Received on Ice
'
Sample Number 180523-19-02
Temp on Arrival: 2.3
pH on Arrival: <2
Parameter Schedule:
'
Nitric Acid
Received on Ice
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Aluminum
Nitric Acid
Received on Ice
'
Received on Ice
Chemicals in containers, lab
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Arsenic - Solid
Nitric Acid
Received on Ice
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Cadmium
Nitric Acid
Received on Ice
1,--.,pH
Chemicals in containers, lab
on Arrival: <2
Parameter Schedule:
Cadmium - Solid
'
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Copper
'
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Molybdenum - Solid
'
Nitric
Acid
Received on Ice
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Nickel
Nitric Acid
Received on Ice
'
on Arrival: <2
Chemicals in containers, lab
pH
Parameter Schedule:
Nickel - Solid
Nitric Acid
Chemicals in containers, lab
'Received
on Ice
pH on Arrival: <2
Parameter Schedule:
Zinc - Solid
Nitric Acid
Received on Ice
'
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
' Page 3 of 40

'
pH on Arrival: <2
Parameter Schedule:
Nitric Acid
Received on Ice
'
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Sodium
Nitric Acid
Received on Ice
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Sodium - Solid
Nitric Acid
Chemicals in containers, lab
'
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite
'
Nitric Acid
Received on Ice
Chemicals in containers, lab
'
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite - Solids
Nitric Acid
Chemicals in containers, lab
Received on Ice
1
pH on Arrival: <2
Parameter Schedule:
'
Nitric Acid
Received on Ice
Chemicals in containers, lab
1
aH on Arrival: <2
Parameter Schedule:
--
Received on Ice
'
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
'
Received on Ice
Chemicals in containers, lab
Percent Solids
Parameter Schedule:
Received on Ice
1
Parameter Schedule:
pH
tReceived
on Ice
pH on Arrival: <2
Parameter Schedule:
TKN
tSulfuric
Acid
Received on Ice
Chemicals in containers, lab
'
Ammonia Nitrogen
pH on Arrival: <2
Parameter Schedule:
Sulfuric Acid
Received on Ice
'
-
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
'
Page 4 of 40

pH on Arrival: <2 Parameter Schedule: Phosphate, Total as P
Sulfuric Acid Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Received on Ice
Received on Ice
pH on Arrival: <2 Parameter Schedule: Potassium
Received on Ice
Chemicals in containers, lab
Sample Number 180523-19-03 Temp on Arrival: 2.3
Parameter Schedule:
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 40

i
L
The TCLP analysis shall intrude the following parameters (1 he regulatory level in milligrams per liter
is in parentheses):
Arsenic (5.0)
1,4-Dichlorobenzene
.5)
Nitrobenzene (2.0)
Barium (100.0)
1,2-Dichloroethane ((
5)
Pentachlorophenol (100.0)
Benzene (0.5)
1,1-Dichloroethylene
.7)
Pyridine (5.0)
Cadmium (1.0)
2,4-Dinitrotoluene (0.
3)
Selenium (1.0)
Carbon tetrachloride (0.5)
Endrin (0.02)
Silver (5.0)
Chlordane (0.03)
Hexachlorobenzene (0
13)
Tetrachloroethylene (0.7)
Chlorobenzene (100.0)
Heptachlor (and its hydri
o.00g
ixide)
Toxaphene (0.5)
Chloroform (6.0)
I4exachloro-1,3-butadien
(0.5)
Trichloroethylene (0.5)
Chromium (5.0)
Hexachloroethane (3
}
2,4.5-Trichlorophenol (400.0)
m-Cresol (200.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
o-Cresol (200.0)
Lindane (0.4)
2,4,5-TP (Silvex) (1.0)
p-Cresol (200.0)
Mercury (0.2)
Vinyl chloride (0.2)
Cresol (200.0)
Methoxychlor (10.0
2,4-D (10.0)
Methyl ethyl ketone (2(10.0)
Once the residuals have been rlionitored for two years at ti e frequency specified in Attachment A.
the Permittee may submit a peit modification request to educe the frequency of this monitoring
AW& requirement. In no case shall monitoring frequency be le than once per permit cycle.
3. An analysis shall be conduct:eon residuals from each source generating facility at the frequency
specified in Attachment A, and the Permittee shall maintain he results for a minimum of five years.
The analysis shall include the fglowing parameters: _
i
Aluminum
Mercury
Potassium
Ammonia -Nitrogen
Molybdenum
Selenium
Arsenic
Nickel
Sodium
Cadmium
Nitrate -Nitrite Nitroge
Sodium Adsorption Ratio
(SAR)
Calcium
Percent Total Solids
TKN
Copper
pH
Zinc
Lead
Phosphorus
Magnesium
Plant Available Nitro
(by calculation) d
n
I
4. Residuals shall be monitored ror compliance with path3gen and vector attraction reduction
requirements at the frequency socified in Attachment A, ard at the time indicated in the sampling
and monitoring sections of thSIAC
provcd O&M plan. The required data shall be specific to the
stabilization process utilized, aufficient to demonstrate ompliance with the Class B pathogen
reduction requirements in 15A 02T .1106 (a) and (b) 2), and one vector attraction reduction
requirement in 15A NCAC 02T .1107 (a) shall be met. Any . ceptions from the requirements in this
condition shall be spccified in Attachmcnt A.
W00011431 Version 3.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 7 of 40

ENCO Laboratories
Accurate. Timely. Responsive. innovative.
102-A Woodwinds Industrial Court
Cary NC, 27511
Phone: [phone] FAX: [phone]
Tuesday, June 5, 2018
Statesville Analytical Holdings, LLC (ST032)
Attn: Crystal Little
PO Box 228
Statesville, NC 28687
RE: Laboratory Results for
Project Number: 180523-19-02, Project Name/Desc: Misc. Subcontract
ENCO Workorder(s): CB07902
Dear Crystal Little,
Enclosed is a copy of your laboratory report for test samples received by our laboratory on
Friday, May 25, 2018.
Unless otherwise noted in an attached project narrative, all samples were received in
acceptable condition and processed in accordance with the referenced methods/procedures.
Results for these procedures apply only to the samples as submitted.
The analytical results contained in this report are in compliance with NELAC standards, except
as noted in the project narrative if applicable. This report shall not be reproduced except in
full, without the written approval of the Laboratory.
This report contains only those analyses performed by Environmental Conservation
Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from
outside organizations will be reported under separate cover.
If you have any questions or require further information, please do not hesitate to contact me
Sincerely,
awzLc,—�O
Chuck Smith
Project Manager
Enclosure(s)
FINAL This report relates only to me sample as received by the laboratory, and may only be reproduced in full. Page 1 of 7
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 8 of 40

www.encolabs.com
SAMPLE SUMMARY/LABORATORY CHRONICLE
Client ID: 18052.3-19-02 Lab ID: CB07902-01 Sampled: 05/23/18 08:30 Received: 05/25/18 10:30
Parameter Preparation Hold Date/T'ime(s) Prep Date/Time(s) Analysis Date/Trme(s)
EPA 6010D EPA 3050B 11/19/18 05/31/18 08:54 06/01/18 13:56
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced In full. Page 2 of 7
PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 9 of 40

� Ea
www.enc.labs.com
SAMPLE DETECTION SUMMARY
Client ID: 180523-19-02 Lab ID: C807902-01
Anal Results Fla9 MDL 9S Unbts Method Notes
Potassium - Total 3090 180 1120 mg/kg dry EPA 60100
FINAL This report relates only to the sample as received by the laboratory, and may only he reproduced in lull. Page 3 of 7
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 10 of 40

www.encolabs.com
QUALITY CONTROL DATA
Metals by EPA 6000/7000 Series Methods - Quality Control
Satrh 0E3I005 - EPA 30500
Blank (SE31005-BLK3) Prepared: 05/31/2018 08:54 Analyzed: 06/01/2018 12:55
Spike Source %REC RPD
Analyte Result Flan POL Units Level Result %REC Limits RPD Limit Notes
Potassium 4.00 U 25.0 mg/kg wet
LCS (SE31005-BS1) Prepared: 05/31/2018 08:54 Analyzed: 06/01/2018 13:01
Spike Source %REC
RPD
Analyte
Result
Flaa
POL
Units
Level Result %REC Limits RPD
Limit Notes
Potassium
444
25.0
mg/kg wet
500 89 80-120
Matrix Spike (SE31005-MSI)
Prepared: 05/31/2018 08:54 Analyzed: 06/01/2018 13:04
Source: C806637-01
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Result %REC Limits RPD
Limit Notes
Potassium
1090
28.5
mg/kg dry
569 456 112 75-125
Matrix Spike Dup (SE31005-MSD1)
Prepared: 05/31/2018 08:54 Analyzed: 06/01/2018 13:06
Source: C506637-01
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Result %REC Limits RPD
Limit Notes
Potassium
1110
28.5
mg/kg dry
575 456 114 75-125 1
20
Post Spike (SE31005-PSI)
Prepared: 05/31/2018 08:54 Analyzed: 06/01/2018 13:08
Source: CB06637-01
Spike Source %REC
RPD
Analyte
Result
Flan
POL
Units
Level Result %REC Limits RPD
Limit Notes
Potassium
17.8
0.500
mg/L
10.0 8.01 98 80-120
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 5 of 7
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 12 of 40

�lV ESP
www.encolabs.com
FLAGS/NOTES AND DEFINITIONS
B The analyte was detected in the associated method blank.
D The sample was analyzed at dilution.
] The reported value is between the laboratory method detection limit (MDL) and the laboratory method
reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable.
U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation
data and moisture content, where applicable.
E The concentration indicated for this analyte is an estimated value above the calibration range of the
instrument. This value is considered an estimate.
MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is
based on the low point of the calibration curve, when applicable, sample preparation factor, dilution
factor, and, in the case of soil samples, moisture content.
PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL.
N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater
confidence) to make a "tentative identification".
P Greater than 25% concentration difference was observed between the primary and secondary GC column.
The lower concentration is reported.
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 7
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 13 of 40

ENVIRONMENTAL CONSERVATION LABORATORIES
CHAIN -OF -CUSTODY RECORD
www.encolabs.com
01b),W0. FL 32d94
FI_ 32? 16-43l)69
Cary, N('. 27511
A011826 5j'-' Vill ;-'(370 1341, 694,
(90-1)296-3W.7
(919j4b,'T)90
Page of
Pl,,Io,t Numbs,
Rq...,.d A,,.Iy...
Requested Turnaround
Statesville Analytical, Inc.
Times
2 Court Street
12PO
Box 228
_",.Pw'_ by (r. ucflb"
Statesville, NC 28687
Pr, Kiwx"
Standard
Expedited
3.111plewll Nall : AI1;I9,j,,,n [Ptir,11
('0n,acl
Due
X1
P--fl— ($,,o CMr,, ,Como -,j o
:
-;m­;; . wov
Sample Comments,
I Y052-5- (Q.02
5-23
-total k nt Ccintamor,
sk,ilpw RI; Nup.o.! R, i
Fl,
5 A.
Mao, In
U'n I,pl
Xp-
_ Acceptable Unacceptable
...... ourare'. A -All ­Q11,01 tdlloll :n Premmatlon; I i,ii ti , 'cl N HNo3 5-lvbu.l NamiuH o.ottlo- (.jp.oail ll•. Cumin Gnl51
W­ All Se ,,o,cd w LNCQ L,,t" ­", ll"w­ 11111 Cur,dII-15 -In,! to I,, .... ­*1

Sample Preservation Verification ���
EP1C0 Cary �; •
Work Order: CB07902 Project: Misc. Subcontract
Client: Statesville Analytical Holdings, LLC (ST032) Project #: 180523-19-02
Logged In: 25-May-18 14:56 I/ Logged By: Rachel Ann Yonish /L
Preservation Check Performed By: DatetTme: r-5 �� /`i'Oy
^nf1Vnn'-5 AA
i� , �
4't7�1f�tias(r Al^iq' ti Erlffld r:a„ kr +..i y.. �" yt @gg�tY L3,4 "kril�f 'w t
1r,«rr>`r�,1++nv."iun""Y�Y�p�Afr�rm�l:�wA'Si"iFi lR�R n�h hk'u5�v�`rti,&'4�,�,�"i� r"+��?l�+^". M`;+.kr k`i+sSin.f �i� er dl .•�'� 3 S �kk�g tslh I_�G
A 500mLP+HNO3 <2 Y / N / NA I Y / / NA
Reaclent Name ID
1
2
Rea ent Name ID
3
4
Reagent Name ID
5
6
pH Strip ID:
PH Strips C710820
C:\elmnt\Print\wKo_Flreservation Check.rpt Page 1 of 1
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 15 of 40

ceAnalyfical
www.pacelabs.com
June 12, 2018
Crystal Little
Statesville Analytical, Inc.
122 Court Street
PO Box 228
Statesville, NC 28687
RE: Project: 180523-19-01
Pace Project No.: 92386216
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Crystal Little:
Enclosed are the analytical results for sample(s) received by the laboratory on May 25, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNUNELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Clrx 0- q tl , �-Niam
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
"
without the written consent of Pace Analytical Services. LLC.
Page 1 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 16 of 40

aceAnalytical
~vpacelabs.com
CERTIFICATIONS
Project: 180523-19-01
Pace Project No.: 92386216
Atlanta Certification IDs
110 Technology Parkway Peachtree Comers, GA 30092
North Carolina Certification #: 381
Florida DOH Certification #: E87315
South Carolina Certification #: 98011001
Georgia DW Inorganics Certification #: 812
Texas Certification #: T104704397-08-TX
Georgia DW Microbiology Certification #: 812
Virginia Certification #: 460204
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
Missouri Certification #: 235
ANAB DOD-ELAP Rad Accreditation #: L2417
Montana Certification #: Cert0082
Alabama Certification #: 41590
Nebraska Certification #: NE-OS-29-14
Arizona Certification #: AZ0734
Nevada Certification #: PA014572018-1
Arkansas Certification
New Hampshire/TNI Certification #: 297617
California Certification #: 04222CA
New Jersey/TNI Certification #: PA051
Colorado Certification #: PA01547
New Mexico Certification #: PA01457
Connecticut Certification #: PH-0694
New York/TNI Certification #: 10888
Delaware Certification
North Carolina Certification #: 42706
EPA Region 4 DW Rad
North Dakota Certification #: R-190
Florida/TNI Certification #: E87683
Ohio EPA Rad Approval: #41249
Georgia Certification #: C040
Oregonrl-NI Certification #: PA200002-010
Guam Certification
PennsylvaniarrNI Certification #: 65-00282
Hawaii Certification
Puerto Rico Certification #: PA01457
Idaho Certification
Rhode Island Certification #: 65-00282
Illinois Certification
South Dakota Certification
Indiana Certification
Tennessee Certification #: 02867
Iowa Certification #: 391
Texas/TNI Certification #: T104704188-17-3
Kansas/TNI Certification #: E-10358
Utah/TNI Certification #: PA014572017-9
Kentucky Certification #: KY90133
USDA Soil Permit #: P330-17-00091
KY WW Permit #: KY0098221
Vermont Dept. of Health: ID# VT-0282
KY WW Permit #: KY0000221
Virgin Island/PADEP Certification
Louisiana DHH/TNI Certification #: LA180012
VirginiafVELAP Certification #: 9526
Louisiana DEQITNI Certification #: 4086
Washington Certification #: C868
Maine Certification #: 2017020
West Virginia DEP Certification #: 143
Maryland Certification #: 308
West Virginia DHHR Certification #: 9964C
Massachusetts Certification #: M-PA1457
Wisconsin Approve List for Rad
Michigan/PADEP Certification #: 9991
Wyoming Certification #: 8TMS-L
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
South Carolina Certification #: 99006001
Louisiana/NELAP Certification # LA170028
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
Virginia/VELAP Certification #: 460221
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Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030 VirginiaNELAP Certification #: 460222
North Carolina Drinking Water Certification #: 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 17 of 40

//4PaceAnal ical
www.paceiabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
180523-19-01
92386216
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92386216001
180523-19-01
EPA8081
NU1
9
PASI-C
EPA 8082
NU1
8
PASI-C
EPA 8151A
ACM
3
PASI-GA
EPA 6010
SH1
7
PASI-A
EPA7470
JMW1
1
PASI-A
EPA8270
RES
18
PASI-C
EPA8260
GAW
14
PASI-C
ASTM D2974-87
KDF
1
PASI-C
EPA 1010
ECH
1
PASI-A
EPA 9045
RLO
1
PASI-A
EPA 9014
PAS
1
PASI-PA
SM4500S2F-00
PAS
1
PASI-PA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC. Page 3 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 18 of 40

www.encolabs.com
ANALYTICAL RESULTS
Description: 180523-19-02 Lab Sample ID:CB07902-01 Received: 05/25/18 10:30
Matrix: Sludge Sampled:05/23/18 08:30 Work Order: C807902
Project: Misc. Subcontract Sampled By: Client % Solids: 2.22
Metals by EPA 6000/7000 Series Methods
Analvte rCAS Numberl Results RU Units PE MB.6 Ea Batch Method Analyzed By Notes
Potassium [7440-09-7] 3090 mg/kg dry 1 180 1120 8E31005 EPA 6010D 06/01/18 13:56 1DH
FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full.
Page 4 of 7
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ANALYTICAL RESULTS
Project: 180523-19-01
Pace Project No.: 92386216
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 180523-19-01 Lab ID: 92386216001 Collected: 05/23/18 08:30 Received: 05125/18 08:08 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 TCLP Pesticides RVE
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
.Surrogates
Decachlorobiphenyl (S)
8151A CI Acid Herbicides TCLP
2,4-D
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
Date: 06/1212018 09:32 AM
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 06/05/18 13:00
ND
ug/L
0.50
1
06111/1811:44 06/11/18 16:43 58-89-9
ND
ug/L
3.0
1
06/1111811:44 06/11/18 16:43 57-74-9
ND
ug/L
0.50
1
06111/1811:44 06/1111816:43 72-20-8
ND
ug/L
0.50
1
06/11/18 11:44 06/11/18 16:43 76-44-8
ND
ug/L
0.50
1
06/11/18 11:44 06/1111816:43 1024-57-3
ND
ug/L
1000
1
06/11/18 11:44 06/11/18 16:43 72-43-5
ND
ug/L
3.0
1
06/1111811:44 06/11/18 16:43 8001-35-2
64
%
10-138
1
06/11/18 11:44 06/11/18 16:43 2051-24-3
45
%
10-110
1
06111/1811:44 06111/1816:43 877-09-8
Analytical Method: EPA 8082 Preparation Method: EPA 3546
ND
ug/kg
1530
1
05/26/1811:15 05/30/1818:13 12674-11-2
ND
ug/kg
1530
1
05/2611811:15 05/3011818:13 11104-28-2
ND
ug/kg
1530
1
05/26/1811:15 05/3011818:13 11141-16-5
ND
ug/kg
1530
1
0512611811:15 05/30/1818:13 53469-21-9
ND
ug/kg
1530
1
05/2611811:15 0513011818:13 12672-29-6
ND
ug/kg
1530
1
05/26/18 11:15 05/30/18 18:13 11097-69-1
ND
ug/kg
1530
1
05/2611811:15 05/30/1818:13 11096-82-5
18
%
21-132
1
0512611811:15 05/3011818:13 2051-24-3 S5
Analytical Method: EPA 8151A Preparation Method: EPA 8151A
Leachate Method/Date: EPA 1311; 06104/18 17:10 Initial pH: 7.71: Final pH: 5.05
ND mg/L 0.0050 1 06/05/18 11:00 06/06/18 13:36 94-75-7
ND mg/L 0.010 1 0610511811:00 06106/1813:36 93-72-1
110 %. 10-155 1 06105/1811:00 06/06/1813:36 19719-28-9
Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 06/04/18 15:30 Initial pH: 7.65: Final pH: 4.5
ND
mg/L
0.050
1
06/05/18 18:35 06/07/18 00:33 7440-38-2
ND
mg/L
0.25
1
06/05/18 18:35 06/07/18 00:33 7440-39-3
ND
mg/L
0.0050
1
06/05/18 18:35 06/07/18 00:33 7440-43-9
ND
mg/L
0.050
1
06/05/18 18:35 06/07/18 00:33 7440-47-3
ND
mg/L
0.025
1
06/05/18 18:35 06/07/18 00:33 7439-92-1
ND
mg/L
0.10
1
06/05/18 18:35 06/07/18 00:33 7782-49-2
ND
mg/L
0.025
1
06/05/18 18:35 06/07/18 00:33 7440-22-4
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 06/04/18 15:30
Initial
pH: 7.65; Final pH: 4.5
ND
mg/L
0.00020
1
06/06/18 08:15 06/06/18 11:09 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 25
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ANALYTICAL RESULTS
Project: 180523-19-01
Pace Project No.: 92386216
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 180523-19-01 Lab ID: 92386216001 Collected: 05/23/18 08:30 Received: 05/25/18 08:08 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
8270 MSSV TCLP Sep Funnel
Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date:
EPA 1311;
06/05/18 13:00
1,4-Dichlorobenzene
ND
ug/L
50.0
1
06107/1811:42 06107/1819:03 106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0
1
0610711811:42 06/0711819:03 121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0
1
06/0711811:42 06/07/18 19:03 87-68-3
Hexachlorobenzene
ND
ug/L
50.0
1
06/07/18 11:42 06/0711819:03 118-74-1
Hexachloroethane
ND
ug/L
50.0
1
06/07/18 11:42 06/07/18 19:03 67-72-1
2-Methylphenol(o-Cresol)
ND
ug/L
50.0
1
06/07/18 11:42 0610711819:03 95-48-7
3&4-Methylphenol(m&p Cresol)
ND
ug/L
50.0
1
06/07/18 11:42 06/07/18 19:03 15831-10-4
Nitrobenzene
ND
ug/L
50.0
1
06107/1811:42 06107/1819:03 98-95-3
Pentachlorophenol
NO
ug/L
100
1
06/07/18 11:42 06107/1819:03 87-86-5
Pyridine
ND
ug/L
60.0
1
06/0711811:42 06107/1819:03 110-86-1
2,4,5-Tdchlorophenol
ND
ug/L
50.0
1
06/07/18 11:42 06/0711819:03 95-954
2,4,6-Trichlorophenol
ND
ug/L
50.0
1
06/0711811:42 06107/1819:03 88-06-2
Surrogates
Nitrobenzene-d5(S)
36
%
12-102
1
06/07/18 11:42 06/07/18 19:03 4165-60-0
2-Fluorobiphenyl(S)
34
%
13-107
1
06/07/18 11:42 06/07/18 19:03 321-60-8
Terphenyl-d14 (S)
41
%
21-132
1
06/07/18 11:42 06/07/18 19:03 1718-51-0
Phenol-d6 (S)
10
%
10-110
1
06/07/18 11:42 06/07/18 19:03 13127-88-3
2-Fluorophenol(S)
14
%
10-110
1
06/07/18 11:42 06/07/18 19:03 367-12-4
2,4,6-Tribromophenol (S)
41
%
27-108
1
06/07/18 11:42 06/07/18 19:03 118-79-6
8260 MSV TCLP
Analytical Method:
EPA 8260 Leachate Method/Date:
EPA 1311; 05/29/18 11:02
Benzene
ND
ug/L
50.0
10
05/30/18 09:59 71-43-2
2-Butanone (MEK)
NO,
ug/L
100
10
05/30/18 09:59 78-93-3
Carbon tetrachloride
ND
ug/L
50.0
10
05/30/18 09:59 56-23-5
Chlorobenzene
ND
ug/L
50.0
10
05/30/18 09:59 108-90-7
Chloroform
ND
ug/L
50.0
10
05/30/18 09:59 67-66-3
1,4-Dichlorobenzene
NO
ug/L
50.0
10
05130/18 09:59 106-46-7
1,2-Dichloroethane
ND
ug1L
50.0
10
05/30/18 09:59 107-06-2
1,1-Dichlorcethene
ND
ug/L
50.0
10
05/30/18 09:59 75-35-4
Tetrachloroethene
NO
ug/L
50.0
10
05/30/18 09:59 127-184
Trichloroethene
ND
ug/L
50.0
10
05/30/18 09:59 79-01-6
Vinyl chloride
ND
ug/L
50.0
10
05/30/18 09:59 75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
105
%
70-130
10
05/30/18 09:59 17060-07-0
Toluene-d8 (S)
106
%
67-135
10
05/30/18 09:59 2037-26-5
4-Bromofluorobenzene (S)
105
%
70-130
10
05/30/18 09:59 460-00-4
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 97.8 % 0.10 1 05/29/18 13:54
1010 Flashpoint,Closed Cup Analytical Method: EPA 1010
Flashpoint >200.0 deg F 70.0 1 06/01/18 09:15
Date: 06/12/2018 09:32 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services. LLC.
Page 5 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 20 of 40

� .-�°aceAnal' tical
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ANALYTICAL RESULTS
Project: 180523-19-01
Pace Project No.: 92386216
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 180523-19-01 Lab ID: 92386216001 Collected: 05/23/18 08:30 Received: 05/25/18 08:08 Matrix: Solid
Results reported on a 'dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
9045 pH Soil Analytical Method: EPA 9045
pH at 25 Degrees C 7.4 Sid. Units 0.10 1 05/26/18 05:54
733C S Reactive Cyanide Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive ND mg/kg 46.1 1 05/31/18 22:55 06/01/18 01:03
734S Reactive Sulfide Analytical Method: SM4500S2F-00 Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive ND mg/kg 461 1 05/31/18 22:55 05/31/18 23:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services, LLC.
Page 6 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 21 of 40

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Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 413914
QC Batch Method: EPA 7470
Associated Lab Samples: 92386216001
METHOD BLANK: 2295274
Associated Lab Samples: 92386216001
Parameter Units
Mercury mg/L
METHOD BLANK: 2295334
Associated Lab Samples: 92386216001
Parameter Units
Mercury mg/L
LABORATORY CONTROL SAMPLE: 2295275
Parameter Units
Mercury mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 7470
Analysis Description: 7470 Mercury TCLP
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.00020 06/06/1810:47
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.00020 06106/1811:35
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
.0025 0.0026 106 80-120
LABORATORY CONTROL SAMPLE:
Parameter
2295335
Units
Spike
Cone.
LCS
Result
LCS
e/ Rec
% Rec
Limits Qualifiers
Mercury
mg/L
.0025
0.0025
102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2295276
2295277
MS
MSD
92386077001
Spike
Spike MS
MSD
MS MSD % Rec
Parameter
Units Result
Cone.
Cone. Result
Result
% Rec % Rec Limits RPD Qual
Mercury
mg/L <0.0002
.0025
.0025 0.0026
0.0027
106 107 75-125 1
0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 22 of 40

2aceAnalytical
J . wwwpaceiabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 413912
Analysis
Method: EPA 6010
QC Batch Method: EPA 3010A
Analysis
Description: 6010 MET TCLP
Associated Lab Samples: 92386216001
METHOD BLANK: 2295267
Matrix:
Water
Associated Lab Samples: 92386216001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Arsenic
mg/L
ND
0.050
06/06/18 23:51
Barium
mg/L
ND
0.25
06106/18 23:51
Cadmium
mg/L
ND
0.0050
06/06/18 23:51
Chromium
mg/L
ND
0.050
06/06/18 23:51
Lead
mg/L
ND
0.025
06/06/18 23:51
Selenium
mg/L
ND
0.10
06/06118 23:51
Silver
mg/L
ND
0.025
06/06/18 23:51
METHOD BLANK: 2295336
Matrix:
Water
Associated Lab Samples: 92386216001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Arsenic
mg/L
ND
0.050
06/07/18 01:08
Barium
mg/L
ND
0.25
06/07/18 01:08
Cadmium
mg/L
ND
0.0050
06/07/18 01:08
Chromium
mg/L
ND
0.050
06/07/18 01:08
Lead
mg/L
ND
0.025
06107/18 01:08
Selenium
mg/L
ND
0.10
06107/18 01:08
Silver
mg/L
ND
0.025
06/07/18 01:08
LABORATORY CONTROL SAMPLE: 2295268
Spike
LCS
LCS %Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Arsenic
mg/L
2.5
2.5
101
80-120
Barium
mg/L
2.5
2.5
99
80-120
Cadmium
mg/L
2.5
2.5
98
80-120
Chromium
mg/L
2.5
2.5
99
80-120
Lead
mg/L
2.5
2.3
92
80-120
Selenium
mg/L
2.5
2.5
101
80-120
Silver
mg/L
1.2
1.2
100
80-120
LABORATORY CONTROL SAMPLE: 2295337
Spike LCS LCS %Rec
Parameter Units Cone. Result % Rec _ Limits Qualifiers
Arsenic ------ -- mg/L — — -- 2.5 2.5 -_-- 99 - 80-120
Barium mg/L 2.5 2.5 102 80-120
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 8 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
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aceAnalytical
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Project: 180523-19-01
Pace Project No.: 92386216
LABORATORY CONTROL SAMPLE:
2295337
Parameter
Units
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Muntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Spike
LCS
LCS
% Rec
Conc.
Result
% Rec
Limits Qualifiers
2.5
2.5
99
80-120
2.5
2.5
98
80-120
2.5
2.4
97
80-120
2.5
2.5
101
80-120
1.2
1.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2295269
2295270
MS
MSD
92386698001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.5
2.5
101
100
75-125
1
Barium
mg/L
0.32
2.5
2.5
2.8
2.8
98
99
75-125
1
Cadmium
mg/L
ND
2.5
2.5
2.4
2.4
98
97
75-125
1
Chromium
mg/L
ND
2.5
2.5
2.4
2.5
97
98
75-125
1
Lead
mg/L
0.027
2.5
2.5
2.3
2.3
91
91
75-125
0
Selenium
mg/L
ND
2.5
2.5
2.5
2.5
100
99
75-125
1
Silver
mg/L
ND
1.2
1.2
1.2
1.2
98
99
75-125
1
Results presented on this page are in the unite Indicated by the "Units" column except where an alternate unIt is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06/1212018 09:32 AM without the written consent 'of Pace Analytical Services, L-C. Page 9 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
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Analytical�e
w rpacelabs.com
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 412862
QC Batch Method: EPA 8260
Associated Lab Samples: 92386216001
METHOD BLANK: 2289961
Associated Lab Samples: 92386216001
Parameter
1,1-Dichloroethene
1,2-Dichloroethane
1,4-Dichlorobenzene
2-Butanone (MEK)
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl chloride
1,2-Dichloroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
QUALITY CONTROL DATA
Analysis Method: EPA 8260
Analysis Description: 8260 MSV TCLP
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
10.0
05/30/18 09:08
ug/L
NO
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30118 09:08
ug/L
ND
5.0
05/30/18 09:08
ug/L
ND
5.0
05/30/18 09:08
%
113
70-130
05/30/18 09:08
%
104
70-130
05/30/18 09:08
%
101
67-135
05/30/18 09:08
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
2289962
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1.1-Dichloroethene
ug/L
50
53.7
107
66-135
1,2-Dichloroethane
ug/L
50
51.9
104
67-128
1,4-Dichlorobenzene
ug/L
50
49.7
99
78-130
2-Butanone (MEK)
ug/L
100
100
100
61-144
Benzene
ug/L
50
52.5
105
80-125
Carbon tetrachloride
ug/L
50
50.3
101
69-131
Chlorobenzene
ug/L
50
49.9
100
81-122
Chloroform
ug/L
50
53.8
108
73-127
Tetrachloroethene
ug/L
50
49.2
98
78-122
Trichloroethene
ug/L
50
53.3
107
78-122
Vinyl chloride
ug/L
50
45.0
90
58-137
1,2-Dichloroethane-d4 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8(S)
%
98
67-135
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2289963 2289964
MS MSD
92385923001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec a/ Rec Limits RPD Qual
1,1-Dichloroethene ug/L ND 20 20 22.6 23.4 113 117 70-150 3,
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 10 of 25
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aceMalXical
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QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2289963
2289964
MS
MSD
92385923001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPO Qual
1,2-Dichloroethane
ug/L
ND
20
20
21.5
21.8
108
109
70-150
1
1,4-Dichlorobenzene
ug/L
ND
20
20
20.5
20.6
103
103
70-150
0
2-Butanone (MEK)
ug/L
ND
40
40
44.1
44.8
104
105
70-150
2
Benzene
ug/L
ND
20
20
21.8
21.8
109
109
70-150
0
Carbon tetrachloride
ug/L
ND
20
20
21.0
21.8
105
109
70-150
3
Chlorobenzene
ug/L
ND
20
20
20.2
20.4
101
102
70-150
1
Chloroform
ug/L
ND
20
20
21.3
23.5
103
114
70-150
10
Tetrachloroethene
ug/L
ND
20
20
19.7
19.6
98
98
70-150
1
Trichloroethene
ug/L
ND
20
20
21.7
22.0
109
110
70-150
1
Vinyl chloride
ug/L
ND
20
20
17.9
18.3
89
91
70-150
2
1,2-Dichloroethane-d4 (S)
%
97
111
70-130
4-Bromoflucrobenzene (S)
%
100
102
70-130
Toluene-d8 (S)
%
98
98
67-135
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. L-C.
Page 11 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 26 of 40

1'!;aceAna1yNca1'
~..pacelabsxorn
QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 414732 Analysis Method: EPA 8081
QC Batch Method: EPA 3510 Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92386216001
METHOD BLANK: 2299854
Associated Lab Samples: 92386216001
Parameter
Units
Chlordane (Technical)
ug/L
Endrin
ug/L
gamma-BHC (Lindane)
ug/L
Heptachlor
ug/L
Heptachlor epoxide
ug/L
Methoxychlor
ug/L
Toxaphene
ug/L
Decachlorobiphenyl (S)
%
Tetrachloro-m-xylene (S)
%
Matrix: Water
Blank
Reporting
Result
Limit
Analyzed Qualifiers
ND
3.0
06/11/181T21
ND
0.50
06111/1817:21
ND
0.50
06111/1817:21
ND
0.50
06/1111817:21
ND
0.50
06/11/1817:21
ND
1000
0611111817:21
ND
3.0
06/1111817:21
92
10-138
06/11/1817:21
72
10-110
06111/1817:21
LABORATORY CONTROL SAMPLE & LCSD:
2299855
2299856
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
Endrin
ug/L
1.2
1.0
1.2
82
93
20-134
gamma-BHC (Lindane)
ug/L
1.2
0.99
1.3
80
103
20-118
Heptachlor
ug/L
1.2
1.0
1.1
81
87
20-142
Heptachlor epoxide
ug/L
1.2
1.0
1.2
81
94
22-133
Methoxychlor
ug/L
3.7
NO
ND
82
97
44-150
Decachlorobiphenyl (S)
%
83
93
10-138
Tetrachloro-m-xylene (S)
%
79
83
10-110
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Max
RPD RPD Qualifiers
12 30
25 30
6 30
15 30
30
Results presented on this page are In the unit. Indicated by the -Units- column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06112/2018 09:32 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 27 of 40

aceAnalytical
www.paceiabs.com
QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 412559 Analysis Method: EPA 8082
QC Balch Method: EPA 3546 Analysis Description: 8082 GCS PCB
Associated Lab Samples: 92386216001
METHOD BLANK: 2288572
Associated Lab Samples: 92386216001
Parameter-
Units
PCB-1016 (Aroclor 1016)
ug/kg
PCB-1221 (Aroclor 1221)
ug/kg
PCB-1232 (Aroclor 1232)
ug/kg
PCB-1242 (Aroclor 1242)
ug/kg
PCB-1248 (Aroclor 1248)
ug/kg
PCB-1254 (Aroclor 1254)
ug/kg
PCB-1260 (Aroclor 1260)
ug/kg
Decachlorobiphenyl (S)
%
Matrix: Solid
Blank
Reporting
Result
Limit
Analyzed Qualifiers
ND
33.6
05130/18 20:19
ND
33.6
05130/18 20:19
ND
33.6
05/30/18 20:19
ND
33.6
06/30/18 20:19
ND
33.6
05/30/18 20:19
ND
33.6
05/30/18 20:19
ND
33.6
05/30/18 20:19
85
21-132
05/30/18 20:19
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE & LCSD:
2288573
2288574
Spike
LCS LCSD
LCS
LCSD
% Rec Max
Parameter
Units
Conc.
Result Result
% Rec
% Rec
Limits _RPD RPD Qualifiers
PCB-1016 (Aroclor 1016)
ug/kg
169
88.8 100
53
60
31-120 12 30
PCB-1260 (Aroclor 1260)
ug/kg
169
129 144
77
86
32-120 10 30
Decachlorobiphenyl (S)
%.
79
89
21-132
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06112/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 13 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 28 of 40

`,2eAnalyticalo
www.pacalabs.com
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 7304
QC Batch Method: EPA8151A
Associated Lab Samples: 92386216001
METHOD BLANK: 33926
Associated Lab Samples: 92386216001
Parameter
Units
2.4,5-TP (Silvex)
mg/L
2,4-D
mg/L
2,4-DCAA (S)
.
QUALITY CONTROL DATA
Analysis Method: EPA 8151A
Analysis Description: 8151 GCS TCLP Herbicides
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.010 06106/1811:46
ND 0.0050 06/06/1811:46
87 10-155 06/06/18 11:46
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Hunlersville, NC 2807E
[phone]
LABORATORY CONTROL SAMPLE: 34229
Spike LCS LCS %Rec
Parameter Units Conc. Result _% Rec Limits Qualifiers
2,4,5-TP (Silvex) mg/L J 2 1.7 87 39-138
2 4 D mg/L 2 1.9 93 29-145
2,4-DCAA (S) %. 112 10-155
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 34230
MS
265529001 Spike
Parameter Units Result Conc.
34231
MSD
Spike MS MSD MS MSD
Conc. Result Result % Rec % Rec
% Rec
Limits RPD Qual
2,4,5-TP (Silvex) mg/L
2,4-D mg/L
2% .
,4-DCAA (S)
NO 2
ND 2
2 1.3 1.7 64 84
2 1.2 1.6 62 79
65 89
10-156 26
10-156 24
10-155
Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 25
PO Box 228 a Statesville, NC 28687 • 704/872/4697
Page 29 of 40

aceAnalytical
~..pacelshs.cdm
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 414273
Analysis Method:
EPA 8270
QC Batch Method: EPA 3510
Analysis Description:
8270 TCLP MSSV
Associated Lab Samples: 92386216001
METHOD BLANK: 2297232
Matrix: Water
Associated Lab Samples: 92386216001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
1,4-Dichlorobenzene
ug/L
NO
50.0
06107l18 17:02
2,4,5-Trichlorophenol
ug1L
ND
50.0
06/0711817:02
2,4,6-Trichlorophenol
ug/L
NO
50.0
06/0711817:02
ug/L
NO
50.0
06/07/18 17:02
2,4-Dinitrotoluene
ug/L
ND
50.0
0610711817:02
2-Methylphenol(o-Cresol)
NO
50.0
06107/18 17:02
3&4-Methylphenol(m&p Cresol)
ug/L
ND
50.0
06/07/18 17:02
Hexachloro-1,3-butadiene
ug/L
NO
50.0
06/07/18 17:02
Hexachlorobenzene
ug/L
ug/L
NO
50.0
06/0711817:02
Hexachloroethane
ug/L
NO
50.0
06/0711817:02
Nitrobenzene
ug1L
ND
100
06107/1817:02
Pentachlorophenol
ug/L
NO
50.0
06107/1817:02
Pyridine
%
49
27-108
06/07/18 17:02
2,4,6-Tribromophenol(S)
%
79
13-107
06/07118 17:02
2-Fluorobiphenyl(S)
%
25
10-110
06/07/18 17:02
2-Fluorophenol (S)
%
83
12-102
06/07118 17:02
Nitrobenzene-d5 (S)
%
23
10-110
06/0708 17:02
Phenol-d6 (S)
%
62
21-132
06/07/18 17:02
Terphenyl-d14 (S)
LABORATORY CONTROL SAMPLE & LCSD:
2297234 2297235
Max
Spike LCS
LCSD
LCS LCSD
% Rec
Parameter
Units
Conc. Result
Result
% Rec % Rec
Limits RPD
RPD Qualifiers
ug/L
500 343
302
69 60
10-110
13 30
1,4-Dichlorobenzene
ug/L
500 218
395
44 79
39-108
58 30 Rt
2,4,5-Trichlorophenol
ug/L
500 214
421
43 84
40-104
65 30 R1
2,4,6-Trichlorophenol
ug/L
500 484
479
97 96
42-109
1 30
2,4-Dinitrotoluene
ug/L
500 281
320
56 64
31-110
13 30
2-Methylphenol(o-Cresol)
ug/L
500 238
284
48 57
30-110
18 30
3&4-Methylphe nol(m&p Cresol)
nol( &p
500 402
313
80 63
10-110
25 30
Hexachloro-1,
ug/L
500 457
438
91 88
39-121
4 30
Hexachlorobenzene
uglL
ug/L
500 330
272
66 54
10-110
19 30
Hexachloroelhane
ug/L
500 394
387
79 77
32-101
2 30
Nitrobenzene
ug/L
1000 355
702
35 70
18-108
66 30 R1
Pentachlorophenol
ug/L
500 202
168
40 34
10-110
18 30
Pyridine
%
47 80
27-108
2.4,6-Tribromophenol(S)
83 80
13-107
2-Fluorobiphenyl (S)
%
22 43
10-110
2-Fluorophenol (S)
%
83 78
12-102
Nitrobenzene-d5 (S)
%
23 29
10-110
Phenol-d6 (S)
%
57 91
21 132
Terphenyl-d14 (S)
%
Results presented on this page are
In the
units Indicated by the 'Units" column
except where
an alternate unit is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 0611212018 09:32 AM
without the written consent of Pace Analytical
Services. LLC.
Page 15 of 25
PO Box 228 a Statesville, NC 28687 • 704/872/4697
Page 30 of 40

11*;ZeAnaly/'ylcal
www.pacelabs.com
QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
QC Balch: 412532 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92386216001
SAMPLE DUPLICATE: 2288484
92386203001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
14.0
14.2 1
SAMPLE DUPLICATE: 2288485
92386218o04
Dup
Parameter
Units
Result
Result RPD Qualifiers
Percent Moisture
%
12.1
10.8 11
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented an this page are in the unit. Indicated by the "Unha' column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 16 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 31 of 40

11'a'ceAnalj4ical'
ww ..pacelabs.com
QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 413315 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92386216001
SAMPLE DUPLICATE: 2292215
Parameter
Flashpoint
92386216001 Dup
Units Result Result RPD Qualifiers
deg F >200.0 >200.0
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are In the unite Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 17 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 32 of 40

i. ; eAnal ical
www.pacelabs.com
QUALITY CONTROL DATA
Project: 180523-19-01
Pace Project No.: 92386216
QC Balch: 412541 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92386216001
SAMPLE DUPLICATE: 2288518
Parameter
pH at 25 Degrees C
92386154003 Dup
Units Result Result RPD Qualifiers
Sid. Units 7.6 7.6 0
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are In the units Indicated by the "units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 18 of 25
PO Box 228 e Statesville, NC 28687 • 704/872/4697
Page 33 of 40

/ !; eAnal ical e
wuw.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 180523-19-01
Pace Project No.: 92386216
QC Batch: 300378
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92386216001
METHOD BLANK: 1470266
Matrix: Solid
Associated Lab Samples: 92386216001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND 0.99 06101/18 00:47
LABORATORY CONTROL SAMPLE: 1470267
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
e/ Rec Limits Qualifiers
Cyanide, Reactive
mglkg
99.2 ND
0 0-8
SAMPLE DUPLICATE: 1470268
4612725001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
<1.0 ND
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 19 of 25
PO Box 228 a Statesville, NC 28687 • 704/872/4697
Page 34 of 40

ceAnal lcal
www,pacelahs.com
Project: 180523-19-01
Pace Project No.: 92386216
UL; batch: 300377
QC Batch Method: SW-846 7.3.4.2
Associated Lab Samples: 92386216001
METHOD BLANK: 1470263
Associated Lab Samples: 92386216001
Parameter Units
Sulfide, Reactive mg/kg
LABORATORY CONTROL SAMPLE: 1470264
Parameter Units
Sulfide, Reactive mg/kg
SAMPLE DUPLICATE: 1470265
Parameter
Sulfide, Reactive
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: SM4500S2F-00
Analysis Description: 734S Reactive Sulfide
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 9.9 05/31/18 23.00
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
198 43.7 22 --- 0-52
4612725001 Cup
Units Result Result
mg/kg <10 ND
RPD Qualifiers
Results presented on this page are In the unite Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, ,
Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services. LLC. Page 20 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 35 of 40

aceAnalytical
w ..Dacelabs.com
QUALIFIERS
Project: 180523-19-01
Pace Project No.: 92386216
DEFINITIONS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services -Asheville
PAST-C
Pace Analytical Services - Charlotte
PASI-GA
Pace Analytical Services -Atlanta, GA
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
Rt RPD value was outside control limits.
S5 Surrogate recovery outside control limits due to matrix interferences (not confirmed by re -analysis).
Date: 06112/2018 09:32 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services. I.I.C.
Page 21 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 36 of 40

2emalytical'
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
18 0523-19-01
92386216
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92386216001
180523.19-01
EPA 3510
414732
EPA 8081
414787
92386216001
180523-19-01
EPA 3546
412559
EPA 8082
412856
92386216001
180523.19-01
EPA 8151A
7304
EPA 8151A
7401
92386216001
180623-19-01
EPA 3010A
413912
EPA 6010
414106
92386216001
180523-19-01
EPA 7470
413914
EPA 7470
414014
92386216001
180523-19-01
EPA 3510
414273
EPA 8270
414328
92386216001
180523-19-01
EPA 8260
412862
92386216001
180523-19-01
ASTM D2974-87
412532
92386216001
180523-19-01
EPA 1010
413315
92386216001
180523-19-01
EPA 9045
412541
92386216001
180523-19-01
SW-846 7.3.3.2
300378
EPA 9014
300582
92386216001
180523-19-01
SW-846 7.3.4.2
300377
SM4500S2F-00
300581
REPORT OF LABORATORY ANALYSIS
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Date: 06/12/2018 09:32 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 37 of 40

Laboratory receiving samples:
❑ Eden❑
Greenwood ❑
Huntersvilly.0� Raleigh[]Mechanicsville❑
Asheville
• CH nt Name:
Project R: r Wo# : 92386216
f /
'I
Courier: Fe
UPS USPS
❑Client
II'III' I I II IIItIIIII III
❑ Commercial ace
❑Other:_
92386216
Custody Seal Present? []Yes No
Seals Intact? ❑Yes
216
L
Date/Initials Person Examining Contents:
Biological Tissue Frozen?
Packing Material: ❑Bubble Wrap
[]Bubble Bags None
❑ Other
Oyes ❑�!o [�
Thermometer•
92T040
Type of Ice: et ❑Blue
[Ncne
IR Gun ID:
Cooler Temp ('C): 2 - ) Correction
Factor: Add/Subtract (•C)
+0.4
Temp should be above freezing to 61C
Cooler Temp Corrected ('C): ,?
(]Samples out of temp criteria. Samples an ice, cooling process
has begun
USDA Regulated Soil t�N/A, water sample)
Did samples origipzlie in a quarantine zone within the
United States: CA, NY, or SC
(check maps)?
Did samples originate from a foreign source (internationa y,
inc.'uding Hawad and Puerto Rico)? ❑Yes
❑Yes No
Comments/Discrepant 1
Chain of Custody Present?
es ❑No
❑N/A 1.
Samples Arrived within Hold Time?
es ❑No
❑N/A i.
Short Hold Time Analysis (<72 hr.)?
[]yes J�No
❑N/A 3.
Rush Turn Around Time Requested?
❑Yes t7No
❑N/A 4.
Sufficient Volume?
Yes []No
❑N/A 5'
Correct Containers Used?
�J Yes No
❑N/A 6.
-Pace Containers Used?
❑N/'t
Containers Intact?
des
21Yes ❑No
[]N/A 7.
Dissolved analysis: Samples Field Filtered?
QYes []NO
❑No
❑N/A 9•
j
Sample Labels Match COOYes
r
Includes Date(Tme/ID/Analysis Matrix:
-includes
Headspace in VOA Vials (>5-6mm)?
[]Yes ❑No
N/A 10.
Trip Blank Present?
❑Yes ❑No
1.
Trip Blank Custody Seals Present?
QYes ❑No
Field Data Required? ❑Yes Milo
COMMENTS/SAMPLE DISCREPANCY
,� r
Lot ID
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
i�i
Project Manager SCURF Review: Date: �
1
Project Manager SRF Review: -11rij Date:
Page 23 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 38 of 40

Sample Condition Upon Receipt(SCUR) regc — I
/ CeAnal ftvl • Document No.: issuing Authority:
F-CAR-CS-033-Rev 06 Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Project # W04 : 923862'16
verified and within the acceptance range for preservation ---- ---'
samples. PM: AMB Due Date: 06/21/18
Exceptions: VOA, Colifortn, TOC, Oil and Grease, oR0/8015 (water) DOC, LLHg CLIENT.: 92—Statesvil '
"Bottom half of box is to list number of bottle
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot X
r-runa OEHNR Certification
Office
"..�c...,,ci,cvc,
out of hold, incorrect preserlative, out of temp, incorrect containers.
Page 24 of 25
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 39 of 40

CHAIN -OF -CUSTODY / Analytical Request Document N
�ceAnalytical o
I he Chain nl-(;usluny Is a I.I GAL Uq(;UMLN I All rclevanl fields nIUSI be corn �
plelCtl acCU(alCly N
7
oction A m
B O-
Rx.+,d.en nq.nl mrwnuxnn Section soc6on C
Reoulro0 Prnpcl Inlorme:,w,
I Invwcn rniwmnnxl Pnpo: Statesville Analytical, Inc.
of
122o
Court Street Corr!(vmy Narnn
PO Box 228
AUnmss
Statesville, NC 28687
suOrN "°
PKn Oumn
Name
nnlerence
Due Da UlTA T;
a cn Rgrl
F'rgacl
Numoer
a'""vMr
Pxtt P!a4 a
aloe 0 Mid 11110ft Cooae
lulr„n rl„,M Immn.,u.,n MAINIA cgJt
COLLECTED
ervative-
SAMPLE ID
n
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—) In
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ADDITIONAL COMMENTS
AEGULATCRY AGENCY
DATE TIME ACCEPTED DY I AFFILIATION
DATE TIME
'OS
SAMPLER NAME AND SIGNATURE
PRINT Namn of SAMPLER:
SIGNATURE of SAMPLER!
!mry+nxn! worn aT uSmnv !xe fvrm yrx, aro xcnPluw Pw.n f NF 1 W nvY n mnnl Inm� arly vyrxelnv o Iv,n. _—
� .nnrgef or , 5'r (r. murex Inr nn1 In.rwcxx nn Ox.n w+!Mn }p exyv
Pace Pro ect No.I Lab I.D.
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SAMPLE CONDITIONS
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ANNUAL PATHOGEN AND VECTOR FORMS

A1NA UAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Town of Clevelad
WWTP Name: Cleveland WWTP
WQ Permit Number:
NPDES Number:
WQ0011431
NCO049867
Monitoring Period: From 1/1/2018
To 12/31/2018
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp)
Alt B (Alk Treatment)$
Alt. C (Prior Testing)
A1t.D (No Prior Test) 0
Process to Further Reduce Pathogengs Of
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ®
Heat Drying El
Heat Treatment
Thermophilic 0
Beta Ray LQ
Gamma Ray ®
Pasteurization 1
.............
Class B:
Alt. (1) Fecal Density Ej
Alt. (2) Process to Significantly Reduce Pathogens Ll
If applicable to alternat)ve performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization Air Drying D composting 0 jAerobic Digestion ltil
Anaerobic Di gs it' e on C.I
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
Pathogen Density
um er o
Frequency
9 y
Sample
pe
Analytical
in Sludge
Excee-
denceq
of Analysis
Type
Tech -
i oue
Minimurr
Geo. Mean
Maximurr
Units
2 x 10 to the
MPN
6th power
per gram of
Fecal Coliform
total solids
CFU
1000 mpn per gram
of total solid (dry
weight)
monella bacteria
r(inlieu
3 MPN per 4 grams
of fecal
total solid (dry
coliform)
weight)
�7..L_� ♦
v ecwr rIuracuun tceauctlon 03A INCAU 02 F .1107) - Please indicate alternative nerfnrmerl-
Alt. (VS reduction)
Alt. 2 (40-day bench) (@
--------- -
Alt. 3 (30-day bench)
I ------------
Alt. 4 (Spec. OZ uptake) CI
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization 0
Alt 7 (Drying - Stable) 0
Alt. 8 (Drying - Unstable) 01,
Alt. 9 (Injection)
Alt. 10 (Incorporation) C,1
No vector attraction reduction alternatives were performed Ll
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
® "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
6_0Y41W
Prepar6r Name and Title (type or print)
La Applier Name and Title (if applicable)(type or print)
Signature of Preparer* Date Signature of Land Applier (if applicable)
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM PVRF 02T (12/2006)

Average
Average
Average
Average
Average
30 Day Bench Worksheet
�0
Sample ID # _�R0523 • t61_ 03
Week 1
Total Solids Volatile Solids % Volatile Fracti
Week 2
Total Solids Volatile Solids % Volatile Fraction
INESM-12- 4
UN
MAN
Week 3
Total Solids Volatile Solids % Volatile Fraction
k4
. • rel F1 11 M&T*1 tre
!k 5
I Solids Volatile Solids a/o Volatile Fracti
Van Kleeck Reduction: Initial % Vol Fraction- Final % Vol. Fraction X 100
Initial % Vol. Fraction -(Initial °% Vol. Fraction X Final 0,6 Vol. Fraction)
.U�37 10

SOIL SAMPLES

NCDA&CS Agronomic Division Phone: [phone]
Website; Www.ncagr.govlagronomi/
Report No. FY18-SL011368
Client: Denise Harrison
�, PrediCtlVe
Bio-Green Services Inc.
Advisor:Denise Harrison
','
383 Potts Rd
Bio-Green Services, Inc.
�P
Soil
Mehlich-3
Report
Extraction
Advance, NC 27006
383 Potts Road
Advance, NC 27006
p,
�'t�' ''^ Y Links to Helpful. Information
Sampled County :Rowan
Client ID: 275491
Advisor ID: 275491
Sampled: Received: 1/08/2018 Completed: 01/28/2018
Farm:
Sample ID: CLRA1
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P205
K20 Mg S
Mn Zn
Cu B
Information
Lime History:
1-Fescue/OGrass/Tim, E 0.0
50-70 50
30 0 0
0 0
0 0
Note: 12
2-Fescue/OGrass/Tim, M 0.0
120-200 40
70 0 0
0 0
0 0
Note: 12
Test Results [units - W/V in g/cm3; CEC and Na in meg1100 cO; NO3-N in mg/dmi]:
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH P-1 K-1
Ca% Mg%
S-1 Mn-1 Mn-All Mn-AI2 Zn-I Zn-AI
Cu-1 Na ESP SS-1 NO3-N
0.32 1.12 17.1 89 1.5 6.6 51 30
63 36
35 364 235 219
89 89
128 0.3 2
,North Carotin
yob[ cw Trot } Ujw t:'w1v1a'M.'k 1
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
Steve Troxler, Commissioner of Agriculture

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY18-SL011368
Denise Harrison
Page 2 of 2
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
Report Abbreviations
Lime
Ac
exchangeable acidity
If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either
B
boron
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
BS%
% CEC occupied by basic cations
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE
Ca%
% CEC occupied by calcium
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate
CEC
cation exchange capacity
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Cu-I
ESP
copper index
exchangeable sodium percent
Fertilizer
HM%
percent humic matter
Recommendations for field crops or otherlarge areas are listed separately for each nutrient to be added (in units of
K-1
potassium index
lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
K20
potash
for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they
Mg%
% CEC occupied by magnesium
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
MIN
mineral soil class
an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear
Mn
Mn-All
manganese
Mn-availability index for crop 1
only on reports for greenhouse soil or problem samples.
Mn-AI2
Mn-availability index for crop 2
Mn-I
manganese index
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
M-0
mineral -organic soil class
notations appear on the soil report, refer to $Note' Secondary Nutrients and Micronutrients. In general, homeowners do not
N
nitrogen
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
Na
sodium
ncagr.gov/agronomi/pubs.htm,
NO3-N
nitrate nitrogen
ORG
organic soil class
Recommendations for small areas, such as home lawnslgardens, are listed in units of Ib/1000 sq ft. If you cannot find
pH
current soil pH
the exact fertilizer grade recommended on the report, visit www.ncagrgov1agronomUobyart4.html ind information that
P-1
phosphorus index
Tay help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer.
P206
phosphate
S-1
sulfur index
SS-1
soluble salt index
Test Results
W/V
weight per volume
Zn-AI
zinc availability index
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The
Zn-I
zinc index
remaining 16 [P-1, K-1, Ca%, Mg%, Mn-1, Mn-All, Mn-AI2, Zn-I, Zn-Al, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel
available)] indicate levels of plant nutrients or other fertility measurement. Visit www•ncagrgov/agronomiluvrsthtm

Report No.
FY18-SL024864
NCDA&CS Agronomic Division Phone: [phone]
Website: www.ncagr.gov/agronomU
fV, Predictive
Client: Denise Harrison
Bio-Green
Advisor:
Services Inc.
383 Potts Rd
Soil Re o Mehlich-3 Extraction
p rt
Advance, NC 27006
Links to Helpful Information
Sampled County: Davie
Client ID: 275491
Advisor ID:
Sampled: Received: 12/20/2017 Completed: 02/19/2018
Farm:
Sample ID: CLRA1
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre)
N P2O5
K2O Mg S
Mn Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, E 1.3
50-70 50
30 0 0
0 0
0 0
Note: 12
2- Fescue/OGrass/Tim, M 0.0
120-200 40
70 0 0
0 0
0 0
Note: 12
Test Results [units - WN in glcrrP; CEC and Na in meq/100 crrP; NO3-N in mg/drift
Soil Class:
Mineral
HM% WN CEC BS% Ac pH P-1 K-1
Ca% Mg% S-1
Mn-I Mn-All Mn-AI2 Zn-I Zn-AI
Cu-I Na
ESP SS-1 NO3-N
0.22 1.10 16.2 90 1.6 6.1 42 33
57 31 33
354 222 228
88 88
136 0.3
2
North Carol ilia
t{ �+
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler. Commissioner of Agriculture

January 1; 2018
NCDEQ-DWR
512 N Salisbury St
61h Floor Room 640-A
Raleigh, NC 27604
Attention: Information Processing Unit
Reference: 2017 LAND APPLICATION ANNUAL REPORT
Town of Cleveland
Permit No. WQ0011431
Non -Discharge Compliance Unit:
IC:CDEI IRIDNNR
1 % r
���1,4R •,, c.,a k
WQROS
VpORESVILLE RE
RECEIVEDINCDENRIDWR
MAR 2018
WOROS
MOORESVILLE REGIONAL OFFICE
Bio-Green Services, Inc. (Bio-Green) is submitting all monitoring and reporting requirements as
specified in the above referenced permit. Bio-Green compiled this report using data gathered during
the compliance year by Bio-Green and the Town of Cleveland. This data includes:
1) Certification Form required by permit
2) Residuals Analysis and PathogenNVector data
3) Application Summary
4) Soil Analysis
If there is any further information required or questions regarding this annual report please do not
hesitate to contact Bio-Green for further assistance.
Sincerely,
Ray Gambill
NC Land Application/Residuals Operator

Town of Cleveland
PO BOX 429
Cleveland, NC 27013
704-278-4777
NC PERMIT # NC0049867
The Honorable Danny Gabriel -Mayor
Town of Cleveland
PO BOX 429
Cleveland, NC 27013
704-278-4777
LAND APPLIERS:
Bio-Green Services, Inc.
383 Potts Road
Advance, North Carolina 27006
2017 Total Dry Tons 5.970
2017 Total Metric Tons 5 408

TABLE OF CONTENTS
SECTION NO. TITLE
I
Annual Land Application Certification Form
Form ACF
II
Annual Residual Sampling Summary Form
Form RSSF
III
Annual Land Application Field Summary Form
Form FSF
IV
Lab Sheets (Analytical Data)
V
Annual Pathogen and Vector Reduction Forms
VI
Soil Analysis

ANNUAL LAND APPLICATION CERTIFICATION FORM

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ001 1431 County:
Facility Name (as shown on permit):
Land Application Operator:
Rowan
Bio-green Services, Inc.
Year: 2017
Town of Cleveland
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
❑ Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summarv:
Total number of application fields in thepermit:
3
Total number of fields utilized for land application during the year:
1
Total amount of dry tons applied during the year for all application sites:
F 5.97
Total number of acres utilizes for land application during the year:
110
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2017 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. R1 Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T. 1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T . I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for Zsubmitg alse informa ing the
possibility of fines and imprisonment for knowing violations."1-4
,
Permitte me and Title (type or print) Signat e of Permittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: WQ0011431 Laboratory: 1)
Facility Name: Town of Cleveland 2)
Residual Source WQ # or NCO049867 3)
NPDES #: 4)
WWTP Name: Cleveland WWTP 5)
Residual Annlvcia ilntn
Statesville Analytical
Parameter
(mg/kg)
Conc.
Limit
m a
Sample or Composite Date
1/11/17
Percent Solids (%)
NA
1.79
Arsenic
75
0.76
Cadmium
85
1.27
Copper
4,300
564.2
Chromium
NA
31.2
Lead
840
' 3.62
Mercury
57
0.614
Molybdenum
75
5.62
Nickel
420
20.5
Selenium
100
0.726
Zinc
7,500
938.55
Total Phosphorus
NA
15640
TKN
NA
33882
Ammonia -Nitrogen
NA
187.71
Nitrate and Nitrite
NA
2162
-. ,,...u. wopu,a1 1au111L1eb LIX UU1111% cvncentranon 1IImis usiea in ims corm are not applicable. Keterence the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to ass that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
pen ties or submitting fa e ' fo ation, including the possibility of fines and imprisonment for knowing violations."
Signature of Prepay r * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: WQ0011431 Laboratory: 1) Statesville Analytical
Facility Name: Town of Cleveland 2)
Residual Source NCO049867 3)
NPDES # or WQ#: 4)
WWTP Name: Cleveland WWTP 5)
Residual Analvsis Data
Parameter
(mg/kg)
Samp m4osite Date
M
MMOMM
I Aluminum
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
signi t penalties for sub Zing false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF - B (12/2006)

ANNUAL LAND APPLICATION SUMMARY FORM
m

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Town of Cleveland WQ Permit #: WQ0011431 Field #: 1 Acres Utilized: 10
Land Owner: G Byrd Annual Dry Tons Applied: 5.9714 Site #: NC-RA-01 Acres Permitted: 10
Operator: Same Predominant Soil Series: Enon Cation Exchange Capacity (non 503):
Crop 1 Name: Fescue Crop 1 Max. PAN: 188 Crop 2 Name: Crop 2 Max. PAN:
.c
° +-
+; o
Volume applied
(enter one) Solids/
Liquid
Cu. Yds Gallons
%
Solids
Volume
Applied per
Acre
(Dry TonsIAC)
Residual Sources
(NPDES # WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Moist)
Precip.
Past 24
Hrs.
inches
>
3 n
v_
g
c m
0.
'
c
z E.
E.
*
w -,
cow
TKN
mg/kg
z
:,
o 5
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
ReceivingResidual
Application
Crop 1
Crop 2
Crop 1
Crop 2
July
80000
1.79
0.597
TOC
Dry
0
S
0.5
0.3
33881.6
187.709
2162.01
14.766
NA
F
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach
FORM
FSF supp to this form):
TOTALS:
01
80000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
14.766
0.006
Lime Applied
Annuallbs/acre
0.001
0.002
0.674
0.037
0.004
0.001
0.007
0.024
0.001
1.121
18.674 1
Date
Ibs/ac
Prior Years Cumulative lbs/ac
0
0
1
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.001
0.002
0.674
0.037
0.004
0.001
0.007
0.024
0.001
1.121
Permitted C. P. L. R.****
1 36
1 34
1338
1 Naa
1 267
1 15
1 NA
1 374
1 89
1 2498
Permit PAN Limit 1 st/2nd Crop
1
1 188
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
/ �**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
Signature of Land Applier Date aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
icility Name: Town of Cleveland Total Dry Tons Applied (Annual): 5.97
-ermit #: WQ001 1431' Cation Exchange Capacity (non 503 only):
irator: G Byrd Owner: Same Predominant Soil Series: Enon
..res Used: 10 Acres Permitted: 10 Site #: NC-RA-01 Field #: 1
Residual
mple or
Analysis Data
1 1 2
(Heavy
3
Metals and Total Phosphorus
4 5 -6j
use mgtkg,
71
"/o Nouas use
9 10
Kaw rercent ff):
ill 12
Com-
posite
'Date
1/II/17
Solids
1.79
Arsenic
0.76
tdmium
1.27
topper
564.2
3hrornium
31.2
Lead
3.62
..lercury
0.614
Molyb-
lenum
5.62
gckel
20.5
Selenium
0.726
Zinc
938.55
Total
Phos-
15640
1horus
ival
Heavy Metal Field Loadings
(Calculated in lbs/acre):
Total
T/Ac./
L1J
L2J3
4J
L_5j
6
71
L-9i10
11
12
0
App.
y
Event
0.60
`,rsenic`'
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
idmium
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Copper
0.674
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.674
rornium,
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Lead
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.004
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
4olyb-
lenum
Nickel
0.007
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.024
;1enium
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000-1
0.000
0.000
0.000
0.001
Zinc
1.121
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1.121
Total
Phos- 18.674
0.000 0.000 0.000 0.000 0.000 0.000 0.000
0.000 0.000 0.000 0.000 18.674
chorus
...14- „s i.,,,, *h.+ +h:e an.-nmPni wac nrenared under my direction
or supervision in accordance
-Ath a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
im aware that there are significant penalties for submitting false information, including the possibility of fines and
trisonment for knowing violations".
signature and Applier Date
DENR FORM MFLSF (12/2006)

LAB SHEETS

Condition of Receipt
Sample Number 170201-13-01 Temp on Arrival: 3
pH on Arrival: <2
Parameter Schedule:
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Aluminum
Nitric Acid
Received on Ice
Received on Ice
Chemicals in containers, lab
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Arsenic - Solid
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Cadmium
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Cadmium - Solid
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Copper
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Copper - Solid
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Magnesium
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Magnesium - Solid
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Silver - Solid
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Zinc - Solid
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Temperature
Nitric Acid
Received on Ice
PO Box 228 a Statesville, NC 28687 • 704/872/4697
Page 3 of 6

pH on Arrival: <2 Parameter Schedule: Ammonia Nitrogen
Sulfuric Acid Received on Ice .
Chemicals in containers, lab
Parameter Schedule:
Parameter Schedule:
Received on Ice
Received on Ice
pH on Arrival: <2 Parameter Schedule: Molybdenum - Solid
Received on Ice
pH on Arrival: <2 Parameter Schedule: Potassium
Received on Ice
pH on Arrival: <2 Parameter Schedule: potassium - Solid
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 6

Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Sodium
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Sodium - Solid
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite
Nitric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Nitrate/Nitrite - Solids
Nitric Acid
Chemicals in containers, lab
Received on Ice
pH on Arrival: <2 Parameter Schedule:
Nitric Acid Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
Received on Ice
Chemicals in containers, lab
Parameter Schedule:
Percent Solids
Received on Ice
Parameter Schedule:
pH
Received on Ice
pH on Arrival: <2
Parameter Schedule:
Phosphate, Total as P
Sulfuric Acid
Received on Ice
Chemicals in containers, lab
pH on Arrival: <2
Parameter Schedule:
TKN
Sulfuric Acid
Received on Ice
Chemicals in containers, lab
PO Box 228 - Statesville, NC 28687 - 704/872/4697
Page 4 of 6

TOWN OF CLEVELAND LAND APPLICATION PROGRAM 0.002
RESIDUALS ANALYSIS
Residual Type: Wastewater Treatment Plant
Date Sample February 1,2017
Permit No. WQ0011431
Mineralization rate 0.30 1.79% Solids
6.33 p H
Parameter
%
PPM (mg/kq)(% *10,000)
Lbs/DryTon (Mg/Kq * 0.0021
PAN Surface
12364.031
24.728062
PAN Injection
12457.886
24.915
TKN
33881.6
67.7632
Ammonia Nitrogen (Am)
187.709
0.375418
Nitrate Nitrogen (Nin)
2162.01
4. 2402
Organic Nitrogen (Orn)
0
0
Total Phosphorus (P)
15640
31.28
Total Phosphate(P205)
0
0
Estimated Avail. P205
0
0
Total Potassium (K)
3330
6.66
Total Potash (K20)
0
0
Arsenic (As) ,
0.76
--"-- "--" 0.00152
Cadmium (Cd)
1.27
0.00254
Chromium (Cr)'
31.2
0.0624
Copper (Cu)
564.2
1.1284
Lead (Pb) `
3.62
0.00724
Mercury (Hg)
0.614
0.001228
Molybdenum (MO)
5.62
0.01124
Nickel (Ni)
20.5
0.041
Selenium (Se)
0.726
0.001452
Zinc (Zn) 4.
938.547
1.877094
Aluminum (AI)
25474.9
50.9498
Calcium (Ca) Y
39106.1
78.2122
Iron (Fe) y
0
0
Sodium (Na)
100
0.2
Sulfur (S)
0
0
Magnesium (Mg)
2540
5.08
Manganese (Mn)
0
0
Statesville Analytical :170201-13-01
*Determination of Plant Available Nitrogen (PAN):
Injected Application:
(Mineralization Rate)(TKN-Ammonia N)+ Ammonia N + Nitrate N +Nitrate N - % PAN
Surface Application
(Mineralization Rate)(TKN-Ammonia N)+ (0.5) (Ammonia N) + Nitrate N +Nitrate N - % PAN
Note: Constituents N.D. (Not Detected) or < direction limits are listed as detection limits for calculation purposes.
4500 gallon loads 11.997 PAN

Analytical Results
Town of Cleveland
PO Box 429
Cleveland, NC 27013
Receive Date: 02/01/2017
Reported: 03/08/2017
For: Digestor
Comments:
Sample Number
Parameter
Sample ID
Result
Unit
Method
Analyzed
Analyst
170201-13-01
Aluminum
Digestor
25474.9
mg/kg
SM 3111 O
02/24/2017
MD
170201-13-01
Ammonia Nitrogen
Digestor
187.709
mg/kg
SM4500NH38E-1997
02/02/2017
CL
170201-13-01
Arsenic - Solid
Digestor
0.76
mg/kg
SM3113 B-2004
02/22/2017
MD
170201-13-01
Cadmium - Solid
Digestor
1.27
mg/kg
SM3111B-1999
02/23/2017
MD
170201-13-01
Calcium
Digestor
39106.1
mg/kg
SM3111B
02/24/2017
MD
170201-13-01
Chromium - Solid
Digestor
31.2
mg/kg
SM3113 B
02/09/2017
MD
170201-13-01
Copper - Solid
Digestor
564.2
mg/kg
SM31118-1999
02/08/2017
MD
170201-13-01
Lead -Solid
Digestor
3.620
mg/kg
SM3113B
02/21/2017
MD
170201-13-01
Magnesium - Solid
Digestor
2540
mg/kg
SM 3111 9-1999
02/24/2017
MD
170201-13-01
Mercury Solid
Digestor
0.614
mg/kg
SM3112
02/03/2017
2/3/17
16:28
170201-13-01
Molybdenum - Solid
Digestor
5.62
mg/kg
EPA200.7
02/20/2017
ENCO
170201-13-01
Nickel - Solid
Digestor
20.50
mg/kg
SM3113 B
02/09/2017
MD
170201-13-01
Nitrate/Nitrite -
Digestor
2162.01
mg/kg
SM4500F/A
02/08/2017
CL
Solids
170201-13-01
PAN
Digestor
16.5
per dry ton
03/07/2017
CL
170201-13-01
Percent Solids
Digestor
1.79
%
SM254OB-1997
02/01/2017
WC
170201-13-01
Potassium - Solid
Digestor
3330
mg/kg
EPA200.7
02/20/2017
ENCO
170201-13-01
Selenium Solid
Digestor
0.726
mg/kg
SM3113B
02/28/2017
170201-13-01
Silver - Solid
Digestor
1.25698
mg/kg
SM3111B-1999
02/07/2017
MD
170201-13-01
Sodium - Solid
Digestor
100
mg/kg
SM 3111 B
02/08/2017
MD
170201-13-01
T. Phosphorus Solid
Digestor
15640
mg/kg
SM450OPE
02/03/2017
CL
170201-13-01
TKN
Digestor
33881.6
mg/kg
SM4500NH3BE
02/03/2017
CL
170201-13-01
Zinc - Solid
Digestor
938.547
mg/kg
SM3111B-1999
02/08/2017
MD
PO Box 228 • Statesville, NC 28687 • 104/872/4697
Page 1 of 6

Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
170201-13-01 pH Digestor 6.33 Std. Units SM4500HB-2000 02/01/2017 TR
170201-13-01 SAR Digestor 1.95 % 03/07/2017 CL
170201-13-01 Temperature Digestor 9.3 deg C SM25508-2000 02/01/2017 TR
Respectfully submitted,
Dena Myers U
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 6

Client:
��_.—__ey��i
—��— — ---
-- ��
----
--
----- —
st:art.F.:1 rsvn.NA1.1 :\L "1IC'
12Court Slll'CI • PO. 11u� 218
Address: --
_
Chain of
Custody Record
—T— — ---
Contact Person: Phone # --__�— — FAX#
_
PO # Requisitioned by: `y (Thne -��
tiaiei
Customer
i Sample IDN
e
laU-ID d
Time Sampie
(6raU Only) �—�
Date Sampled —
(Grab UnIy) �
j ;;
�—
I
'sn,eR
-Mainz
Ww
vav
Parameters
rl-
re uesteo Iw aru�lysrs
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I Relinquished by:
Time
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2 I
pm Date I/
_ �—�
Sampled by: ��
Received by:
Time L t L
�m �im Date _/
1—� Transported by:
Relinquished by:
�— _— Time —
am, pm Date —//^
Holding times met: ,
Received by:
Time
am, pm Date
Composite SamQlin9 #1; —
Compliance work: _" I
Time begin
am, pm Date —_/—/�
Non-compliance work:
Time end—
am, pm Date Lab Comments -
Time begin----
am, pm Date —/__/__
Time end
_ am, pm Date —/_/u `
ai
V)
v
Ln

/!�aneAnalyticalo
www.pacelabs.com
March 01, 2017
Tracy Moore
Statesville Analytical
122 Court St.
Statesville, NC 28687
RE: Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Dear Tracy Moore:
Enclosed are the analytical results for sample(s) received by the laboratory on February 02, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Non - w, . k-�)C Lam
Angela Baioni
angela.baioni@ pacelabs.com
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

PaceAnalytical
WWW'.pacelaos.eorn
CHAIN -OF -CUSTODY / Analytical Request Document
N
The Chain-of-Cus!ody is a LEGAL DOCUMENT. All relevant folds rnusl be completed acavatrly. `o
r—
N
Section A Section B
Required Client InfonnaGon: Required Prni—t hifnrmaHn
C ,any .. r� i i.
Acdress.
Re •o o, - --i __._�_.'.
_
Copy To:
Erna;l T .:
Phone: Fax:
PUrchase Order No.:
Project Name:
Requested Due Date/TAT:
Project Number:
Section D Matrix Codes
-
Rcryuvoc!Q,en: h ern::iann "_IAl'R!x°-
Dnnkinq Walor__. DW
j
V/ak?r WT
R
T1aSte Wa Io' WIN
Product P
--
coCOL.
ST,
SoNso';d SL
SAMPLE ID Oil OL
`'
a:
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Wipe WP
(A-Z. 0-9 ; .-'t Air AR
U
Sample lDs MUST CC UNIQUE Tissue TS
�
a
ae
Olher 01
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_x
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F
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DATE
1
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7
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ADDITIONAL COMMENTS
RELINQUISHEDBY
N`cl :11daY ir:nam•nt :: rr :::.

�71aceAnalytical'
Laboratory receiving samples:
Asheville ❑ Eden[:]
Sample Condition Upon Receipt(SCUR)
Document No.:
F-CAR-CS-033-Rev.01
Greenwood ❑ Huntersville OF
vvwuienc Reviseu: -,ep[. L1, ZV1b
Page 1 of 2
Issuing Authority:
Pace Quality Office
Raleigh❑ Mechanicsville❑
° Client Name: WO# : 92323515
' I: Project ff: ff
>`1;';•;t1`(` ('•.11rr!I'��ti(`(.'i:!.- II II'(�II'll'lllII�II
Courier; ❑Fed Ex ❑UPS ❑LISPS ❑Client
❑ Commercial []Pace ❑Other: 92328515
Custody Seal Present? Dyes ONO Seals Intact? El -Yes ❑No
Date/Initials Person Examining Contents:l_l'..1_ .
Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑Other:
Thermometer:
❑ IR Gun ID: Type of Ice: ❑Wet ❑Blue []None ❑Samples on ice, cooling process has begun
Correction Factor; Cooler Temp Corrected (°C): Biological Tissue Frozen? ❑Yes ❑No ❑N/A
Temp should be above freezing to 6°C
USDA Regulated Soil { ❑'N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
Ayes FIN'n
iuuni� nGwml auu VUCRu RIGUlf Ores .LJIVU
Comments/Discrepancy:
Chain of Custody Present?
❑Yes
❑No
❑N/A
1,
Samples Arrived within Hold Time?
Dyes
El No
❑N/A
2.
Short Hold Time Analysis (<72 hr,)?
❑Yes
[]NO.
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
❑No
❑N/A
4.
Sufficient Volume?
❑Yes
❑No
❑NIA
5.
Correct Containers Used?
-Pace Containers Used?
01/ 1'r
El"
❑No
ONO
❑N/A
❑N/A
6.
Containers Intact?
Dyes
[]No
❑N/A
7.
Samples Field Filtered?
❑Yes
❑No
N %A
8. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
-Includes Date/Time/fD/Analysis Matrix:
Headspace in VDA Vials (>5-6mm)?
t. Yes
�`,
Dyes
ONO
-
❑N/A
9.t, ,..1_I 1.,..i ... ') r. l :a -'•t;. C ' :-'. C' 1�,t....( (`(: (:
�.t! r •� ``
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
❑No
❑No
❑N/A
❑NIA
11.
np —V 1 IU14
Field Data Required? ❑Yes ❑No
Person Contacted: Date/Time:
Comments/Sample
Discrepancy:
Project Manager SCURF Review: }'1'1 �`) Date: -•3 111
Project Manager SRF Review; 117}'1j?) Date: / j �I r
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, Incorrect containers)
Page 25 of 27

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AG1H-1 liter Amber HCI (pH < 2)
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AG3A(DG3A)-250 mL Amber NH4CI (N/A)(CI-)
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SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
170201-09
92328515
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92328515001
170201-09
EPA 8081
SWB
9
PASI-C
EPA 8151
LJM
3
PASI-O
EPA 6010
SH1
7
PASI-A
EPA7470
JMW
1
PASI-A
EPA 8270
RES
18
PASI-C
EPA 8260
GAW
14
PASI-C
ASTM D2974-87
CLW
1
PASI-C
EPA 1010
ALC
1
PASI-A
EPA 9045
KDF1
1
PASI-A
EPA 9014
PAS
1
PASI-PA
SM4500S2F-00
PAS
1
PASI-PA
92328515002
170201-09 PCB
EPA 8082
SWB
8
PASI-C
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ANALYTICAL RESULTS
Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 170201-09 Lab ID: 92328516001 Collected: 02/01/17 09:35 Received: 02/02/17 09:17 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quai
8081 GCS Pesticides, TCLP
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 02/13/17 15:00
ND
ug/L
0.50
1
02/15/1717:09
02/1811714:49
58-89-9 L1,L3
ND
ug/L
3.0
1
02/15/1717:09
02/18/1714:49
57-74-9
ND
ug/L
0.50
1
02/15/1717:09
02/1811714:49
72-20-8
ND
ug/L
0.50
1
02/15/1717:09
02/18/1714:49
76-44-8
ND
ug/L
0.50
1
02115/1717:09
02/18/1714:49
1024-57-3
ND
ug/L
1000
1
02/15/1717:09
02/18/1714:49
72-43-5
ND
ug/L
3.0
1
02/15/1717:09
02/18/1714:49
8001-35-2
74
%
10-138
1
02/15/1717:09
02/18/1714:49
2051-24-3
98
%
10-110
1
02/15/1717:09
02/18/1714:49
877-09-8
8151 Chlorinate Herbicide TCLP
Analytical Method: EPA 8151 Preparation Method: EPA 3510
2,4-D
ND
mg/L
0.59 1
02/18/17 15:35
02/23/17 21:14
94-75-7
2,4,5-TP (Silvex)
ND
mg/L
0.59 1
02/18/17 15:35
02/23/17 21:14
93-72-1
Surrogates
2,4-DCAA (S)
98
%
39-139 1
02/18/17 15:35
02/23/17 21:14
19719-28-9
6010 MET ICP, TCLP
Analytical Method: EPA 6010
Preparation Method: EPA
3010A
Leachate Method/Date:
EPA 1311;
02/07/17 17:50 Initial
pH: 6.9; Final
pH: 6.9
Arsenic
ND
mg/L
0.050 1
02/08/17 17:20
02/09/17 22:38
7440-38-2
Barium
ND
mg/L
0.25 1
02/08/17 17:20
02/09/17 22:38
7440-39-3
Cadmium
ND
mg/L
0.0050 1
02/08/17 17:20
02/09/17 22:38
7440-43-9
Chromium
ND
mg/L
0.050 1
02/08/17 17:20
02/09/17 22:38
7440-47-3
Lead
ND
mg/L
0.025 1
02/08/17 17:20
02/09/17 22:38
7439-92-1
Selenium
ND
mg/L
0.10 1
02/08/17 17:20
02/09/17 22:38
7782-49-2
Silver
ND
mg/L
0.025 1
02/08/17 17:20
02/09/17 22:38
7440-22-4
7470 Mercury, TCLP
Analytical Method:
EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date: EPA 1311; 02/07/17 17:50 Initial
pH: 6.9; Final pH: 6.9
Mercury
ND
mg/L
0.00020 1
02/08/1718:10
02/09/1714:57
7439-97-6
8270 MSSV TCLP Sep Funnel
Analytical Method:
EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 02/13/17 15:00
1,4-Dichlorobenzene
ND
ug/L
50.0 1
02/1511715:16
02/16/1712:52
106-46-7
2,4-Dinitrotoluene
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
87-68-3
Hexachlorobenzene
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
118-74-1
Hexachloroethane
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
67-72-1
2-Methylphenol(o-Cresol)
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
95-48-7
3&4-Methyiphenol(m&p Cresol)
ND
ug/L
50.0 1
02/15/17 15:16
02/16/17 12:52
Nitrobenzene
ND
ug/L
50.0 1
02/15/1715:16
02/16/1712:52
98-95-3
Pentachlorophenol
ND
ug/L
100 1
02115/1715:16
02/16/1712:52
87-86-5
Pyridine
ND
ug/L
50.0 1
02/15/1715:16
02116/1712:52
110-86-1
2,4,5-Trichlorophenoi
ND
ug/L
50.0 1
02115/1715:16
02/16/1712:52
95-95-4
REPORT OF LABORATORY ANALYSIS
L1,L3,
MO
This report shall not be reproduced, except in full,
Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 27

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ANALYTICAL RESULTS
Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 170201-09 Lab ID: 92328515001 Collected: 02/01/17 09:35 Received: 02/02/17 09:17 Matrix: Solla
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 02/13/17 15:00
2 4 6-Trichlorophenol ND ug/L 50.0 1 02/15/17 15:16 02/16/17 12:52 88-06-2
Surrogates
Nitrobenzene-d5 (S)
44
%
12-102
1 02/15/17 15:16
02/16/17 12:52 4165-60-0
2-Fluorobiphenyl (S)
44
%
13-107
1 02/15/17 15:16
02/16/17 12:52 321-60-8
Terphenyl-d14 (S)
77
%
21-132
1 02/15/17 15:16
02/16/17 12:52 1718-51-0
Phenol-d6 (S)
18
%
10-110
1 02/15/17 15:16
02/16/17 12:52 13127-88-3
2-Fluorophenol (S)
26
%
10-110
1 02/15/17 15:16
02/16/17 12:52 367-12-4
2,4,6-Tribromophenol (S)
51
%
27-108
1 02/15/17 15:16
02/16/17 12:52 118-79-6
8260 MSV TCLP
Analytical Method: EPA 8260 Leachate Method/Date: EPA 1311; 02/06/17 09:04
Benzene
ND
ug/L
5.0
1
02/08/17 17:16 71-43-2
2-Butanone (MEK)
ND
ug/L
10.0
1
02/08/17 17:16 78-93-3
Carbon tetrachloride
ND
ug/L
5.0
1
02/08/17 17:16 56-23-5
Chlorobenzene
ND
ug/L
5.0
1
02/0811717:16 108-90-7
Chloroform
ND
ug/L
5.0
1
02/0811717:16 67-66-3
1,4-Dichlorobenzene
ND
ug/L
5.0
1
02/08/17 17:16 106-46-7
1,2-Dichloroethane
ND
ug/L
5.0
1
02/08/17 17:16 107-06-2
1,1-Dichloroethene
ND
ug/L
5.0
1
02/0811717:16 75-35-4
Tetrachloroethene
ND
ug/L
5.0
1
02/08/17 17:16 127-18-4
Trichloroethene
ND
ug/L
5.0
1
02/08/17 17:16 79-01-6
Vinyl chloride
ND
ug/L
5.0
1
02/08/17 17:16 75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
94
%
70-130
1
02/08/17 17:16 17060-07-0
Toluene-d8 (S)
104
%
67-135
1
02/08/17 17:16 2037-26-5
4-Bromofluorobenzene (S)
93
%
70-130
1
02/08/17 17:16 460-00-4
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
98.3
%
0.10
1
02/03/17 09:28
1010 Flash point, Closed Cup
Analytical Method: EPA 1010
Flashpoint
>200
deg F
70.0
1
02/03/17 09:37
9045 pH Soil
Analytical Method: EPA 9045
pH at 25 Degrees C
6.6
Std. Units
0.10
1
02/03/17 14:12
733C S Reactive Cyanide
Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive
ND
mg/kg
58.9
1 02/09/17 13:10
02/09/17 20:06
734S Reactive Sulfide
Analytical Method: SM4500S2F-00 Preparation
Method: SW-846 7.3.4.2
Sulfide, Reactive
ND
mg/kg
589
1 02/09/17 13:10
02/09/17 17:46
REPORT OF LABORATORY ANALYSIS
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Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 27

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ANALYTICAL RESULTS
Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersviile. NC 28078
[phone]
Sample: 170201-09 PCB Lab ID: 92328515002 Collected: 02/01/17 09:35 Received: 02/02/17 09:17 Matrix: Non Aqueous
Liquid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8082 GCS PCB
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
Date: 03/01/2017 11:29 AM
Analytical Method: EPA 8082 Preparation Method: EPA 3580
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
12674-11-2
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
11104-28-2
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
11141-16-5
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
53469-21-9
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
12672-29-6
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
11097-69-1
ND
mg/kg
1.0
1
02/07/17 13:30
02/08/17 08:50
11096-82-5
36
%
49-130
1
02/07/17 13:30
02/08/17 08:50
2051-24-3 S4
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 347461 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92328515001
METHOD BLANK: 1927755
Associated Lab Samples: 92328515001
Parameter Units
Mercury
mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.00020 02/09/1714:01
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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LABORATORY CONTROL SAMPLE: 1927756
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/L .0025 0.0023 91 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1927757 1927758
MS MSD
92328597009 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Mercury mg/L ND .0025 .0025 0.0017 0.0023 68 90 75-125 28 M1,R1
Results presorted on this page are In the units Indicated by the "Units" column except inhere an alternate unitis presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: 347460
Analysis Method:
EPA 6010
QC Batch Method: EPA 3010A
Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92328515001
METHOD BLANK: 1927750
Matrix: Water
Associated Lab Samples: 92328515001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Arsenic
mg/L
ND
0.050
02/09/17 21:31
Barium
mg/L
ND
0.25
02/09/17 21:31
Cadmium
mg/L
ND
0.0050
02/09/17 21:31
Chromium
mg/L
ND
0.050
02/09/17 21:31
Lead
mg/L
ND
0.025
02/09/17 21:31
Selenium
mg/L
ND
0.10
02/09/17 21:31
Silver
mg/L
ND
0.025
02/09/17 21:31
LABORATORY CONTROL SAMPLE:
1927751
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Arsenic
mg/L
2.5
2.9
115
80-120
Barium
mg/L
2.5
2.6
105
80-120
Cadmium
mg/L
2.5
2.7
109
80-120
Chromium
mg/L
2.5
2.6
103
80-120
Lead
mg/L
2.5
2.7
106
80-120
Selenium
mg/L
2.5
2.9
115
80-120
Silver
mg/L
1.2
1.2
97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1927752
1927753
MS
MSD
92328597008
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.9
2.9
116 115
75-125
1
Barium
mg/L
ND
2.5
2.5
2.7
2.7
105 106
75-125
1
Cadmium
mg/L
ND
2.5
2.5
2.7
2.7
109 110
75-125
1
Chromium
mg/L
ND
2.5
2.5
2.6
2.6
103 103
75-125
0
Lead
mg/L
ND
2.5
2.5
2.7
2.7
107 107
75-125
0
Selenium
mg/L
ND
2.5
2.5
2.9
2.9
115 114
75-125
1
Silver
mg/L
ND
1.2
1.2
1.2
1.2
97 97
75-125
0
Results presented on this page are In the units Indicated by the "Units" column except there an alternate unitis presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 347397 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV TCLP
Associated Lab Samples: 92328515001
METHOD BLANK: 1927109
Associated Lab Samples: 92328515001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
02108/1710:10
1,2-Dichloroethane
ug/L
ND
5.0
02/08/17 10:10
1,4-Dichlorobenzene
ug/L
ND
5.0
02/08/17 10:10
2-Butanone (MEK)
ug/L
ND
10.0
02/08/17 10:10
Benzene
ug/L
ND
5.0
02/08/17 10:10
Carbon tetrachloride
ug/L
ND
5.0
02/08/17 10:10
Chlorobenzene
ug/L
ND
5.0
02/08/17 10:10
Chloroform
ug/L
ND
5.0
02/08/17 10:10
Tetrachloroethene
ug/L
ND
5.0
02108/1710:10
Trichloroethene
ug/L
ND
5.0
02108/1710:10
Vinyl chloride
ug/L
ND
5.0
02/08/17 10:10
1,2-Dichloroethane-d4 (S)
%
92
70-130
02/08/17 10:10
4-Bromofluorobenzene (S)
%
92
70-130
02/08/17 10:10
Toluene-d8 (S)
%
100
67-135
02/08/17 10:10
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1927110
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
55.4
111
66-135
1,2-Dichloroethane
ug/L
50
49.4
99
67-128
1,4-Dichlorobenzene
ug/L
50
49.6
99
78-130
2-Butanone (MEK)
ug/L
100
101
101
61-144
Benzene
ug/L
50
54.2
108
80-125
Carbon tetrachloride
ug/L
50
54.5
109
69-131
Chlorobenzene
ug/L
50
52.0
104
81-122
Chloroform
ug/L
50
49.8
100
73-127
Tetrachloroethene
ug/L
50
52.8
106
78-122
Trichloroethene
ug/L
50
56.9
114
78-122
Vinyl chloride
ug/L
50
45.0
90
58-137
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
95
67-135
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1927111 1927112
MS MSD
92328443002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene ug/L ND 200 200 224 239 112 120 70-150 6
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unitls presented t) the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1927111
MS
92328443002
Spike
Parameter
Units
Result
Conc.
1,2-Dichloroethane
ug/L
ND
200
1,4-Dichlorobenzene
ug/L
ND
200
2-Butanone (MEK)
ug/L
427
400
Benzene
ug/L
ND
200
Carbon tetrachloride
ug/L
ND
200
Chlorobenzene
ug/L
ND
200
Chloroform
ug/L
ND
200
Tetrachloroethene
ug/L
ND
200
Trichloroethene
ug/L
ND
200
Vinyl chloride
ug/L
ND
200
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
1927112
MSD
Spike
MS
MSD
MS
MSD
% Rec
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
200
186
188
92
93
70-150
1
200
199
198
100
99
70-150
1
400
906
901
120
119
70-150
1
200
219
232
108
114
70-150
5
200
214
229
107
114
70-150
7
200
207
221
103
111
70-150
7
200
197
198
98
99
70-150
1
200
215
226
107
113
70-150
5
200
234
259
117
129
70-150
10
200
182
196
91
98
70-150
7
97
88
70-130
107
106
70-130
101
100
67-135
Results presented on this page are In the units Indicated by the "Units" column except Hhere an alternate unitis presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. r
Qual
Page 11 of 27

aceAnalXical
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 348417 Analysis Method: EPA 8081
QC Batch Method: EPA 3510 Analysis Description: 8081 GCS TCLP Pesticides
Associated Lab Samples: 92328515001
METHOD BLANK: 1933062
Matrix: Water
Associated Lab Samples: 92328515001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
02/18/17 18:59
Endrin
ug/L
ND
0.50
02/18/17 18:59
gamma-BHC (Lindane)
ug/L
ND
0.50
02/18/17 18:59
Heptachlor
ug/L
ND
0.50
02/18/17 18:59
Heptachlor epoxide
ug/L
ND
0.50
02/18/17 18:59
Methoxychlor
ug/L
ND
1000
02/1811718:59
Toxaphene
ug/L
ND
3.0
02/18/17 18:59
Decachlorobiphenyl (S)
%
107
10-138
02/18/17 18:59
Tetrachloro-m-xylene (S)
%
113
10-110
02/18/17 18:59 S3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1933063
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Endrin
ug/L
1.2
1.6
127
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.5
122
20-118 L1
Heptachlor
ug/L
1.2
1.3
106
20-142
Heptachlor epoxide
ug/L
1.2
1.5
122
22-133
Methoxychlor
ug/L
3.7
ND
118
44-150
Decachlorobiphenyl (S)
%
106
10-138
Tetrachloro-m-xylene (S)
%
108
10-110
MATRIX SPIKE SAMPLE:
Parameter
1933064
Units
92328512001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Endrin
ug/L
NO
1.2
1.5
120
21-133
.gamma-BHC (Lindane)
ug/L
ND
1.2
1.3
109
24-119
Heptachlor
ug/L
ND
1.2
1.1
90
16-128
Heptachlor epoxide
ug/L
NO
1.2
1.3
108
50-150
Methoxychlor
ug/L
ND
3.7
NO
113
50-150
Decachlorobiphenyl (S)
%
75
10-138
Tetrachloro-m-xylene (S)
%
101
10-110
SAMPLE DUPLICATE: 1933065
92328515001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Chlordane (Technical)
ug/L
NO
ND
Endrin
ug/L
NO
NO
Results presented on this page are In the units Indicated by the "Units" column except Mere an alternate unitls presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 27

-IdaceAnalytical
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
SAMPLE DUPLICATE: 1933065
Parameter
Units
92328515001
Result
Dup
Result RPD Qualifiers
gamma-BHC (Lindane)
ug/L
ND
ND
Heptachlor
ug/L
ND
ND
Heptachlor epoxide
ug/L
ND
ND
Methoxychlor
ug/L
ND
ND
Toxaphene
ug/L
ND
ND
Decachlorobiphenyl (S)
%
74
68 9
Tetrachloro-m-xylene (S)
%
98
90 9
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are In the units Indicated by the "Units" column except Mere an alternate unit Is presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, I.I.C.
Page 13 of 27

aceAnalytical
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 347230 Analysis Method: EPA 8082
QC Batch Method: EPA 3580 Analysis Description: 8082 GCS PCB Oil
Associated Lab Samples: 92328515002
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 1926063
Associated Lab Samples: 92328515002
Parameter
Units
Matrix: Non Aqueous Liquid
Blank Reporting
Result Limit Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1221 (Aroclor 1221)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1232 (Aroclor 1232)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1242 (Aroclor 1242)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1248 (Aroclor 1248)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1254 (Aroclor 1254)
mg/kg
ND
1.0
02/08/17 10:10
PCB-1260 (Aroclor 1260)
mg/kg
ND
1.0
02/08/17 10:10
Decachlorobiphenyl (S)
%
96
49-130
02/08/17 10:10
LABORATORY CONTROL SAMPLE: 1926064
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
PCB-1016 (Aroclor 1016)
mg/kg
10
8.5
85 50-148
PCB-1260 (Aroclor 1260)
mg/kg
10
8.6
86 53-149
Decachlorobiphenyl (S)
%
96 49-130
MATRIX SPIKE SAMPLE:
Parameter
1926065
Units
92328512002
Result
Spike
Conc.
MS MS % Rec
Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016)
mg/kg
ND
11.2
PCB-1260 (Aroclor 1260)
mg/kg
ND
11.2
Decachlorobiphenyl (S)
%
114 49-130
SAMPLE DUPLICATE: 1926066
92328515002
Dup
Parameter
Units
Result
Result
RPD Qualifiers
PCB-1016 (Aroclor 1016)
mg/kg
ND
ND
PCB-1221 (Aroclor 1221)
mg/kg
ND
ND
PCB-1232 (Aroclor 1232)
mg/kg
ND
ND
PCB-1242 (Aroclor 1242)
mg/kg
ND
ND
PCB-1248 (Aroclor 1248)
mg/kg
ND
NO
PCB-1254 (Aroclor 1254)
mg/kg
ND
ND
PCB-1260 (Aroclor 1260)
mg/kg
ND
ND
Decachlorobiphenyl (S)
%
36
46 25 S4
Results presorted on this page are In the units Indicated by the "Units" column except Mere an alternate unitis presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 27

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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 351394 Analysis Method: EPA 8151
QC Batch Method: EPA 3510 Analysis Description: 8151 GCS Herbicides TCLP
Associated Lab Samples: 92328515001
METHOD BLANK: 1889618
Matrix: Water
Associated Lab Samples: 92328515001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
2,4,5-TP (Silvex)
mg/L
ND 0.00019
02/23/17 20:14
2,4-D
mg/L
ND 0.00094
02/23/17 20:14
2,4-DCAA (S)
%
98 39-139
02/23/17 20:14
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
1889619
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
2,4,5-TP (Silvex)
mg/L
.012 0.014 115
53-134
2,4-D
mg/L
.06 0.077 129
35-124 L1
2,4-DCAA (S)
%
106
39-139
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1890606
1890607
MS
MSD
92328515001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qua[
2,4,5-TP (Silvex)
mg/L
ND
.707
.707
0.73
0.79
103
112
53-134 8
2,4-D
mg/L
ND
3.53
3.53
4.5
4.5
126
127
35-124 1 MO
2,4-DCAA (S)
%
104
106
39-139
Results presented on this page are In the units Indicated by the "Units" column except Where an alternate unitts presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/01 /2017 11:29 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 27

;aceAnalyficafo
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 348381 Analysis Method: EPA 8270
QC Batch Method: EPA 3510 Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92328515001
METHOD BLANK: 1932892
Associated Lab Samples: 92328515001
Matrix: Water
Blank
Parameter
Units
Result
1,4-Dichlorobenzene
ug/L
2,4,5-Trichlorophenol
ug/L
2,4,6-Trichlorophenol
ug/L
2,4-Dinitrotoluene
ug/L
2-Methylphenol (o-Cresol)
ug/L
3&4-Methylphenol(m&p Cresol)
ug/L
Hexachloro-1,3-butadiene
ug/L
Hexachloro benzene
ug/L
Hexachloroethane
ug/L
Nitrobenzene
ug/L
Pentachlorophenol
ug/L
Pyridine
ug/L
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol (S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
LABORATORY CONTROL SAMPLE:
1932893
Spike
Parameter
Units
Conc.
1,4-Dichlorobenzene
ug/L
500
2,4,5-Trichlorophenol
ug/L
500
2,4,6-Trichlorophenol
ug/L
500
2,4-Dinitrotoluene
ug/L
500
2-Methylphenol(o-Cresol)
ug/L
500
3&4-Methyiphenoi(m&p Cresol)
ug/L
500
Hexachloro-1,3-butadiene
ug/L
500
Hexachlorobenzene
ug/L
500
Hexachloroethane
ug/L
500
Nitrobenzene
ug/L
500
Pentachiorophenol
ug/L
1000
Pyridine
ug/L
500
2,4,6-Tribromophenol (S)
%
2-Fluorobiphenyl (S)
%
2-Fluorophenol(S)
%
Nitrobenzene-d5 (S)
%
Phenol-d6 (S)
%
Terphenyl-d14 (S)
%
Reporting
Limit
Analyzed
ND
50.0
02116/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/1711:05
ND
50.0
02/16/17 11:05
ND
100
02/16/1711:05
ND
50.0
02/16/1711:05
75
27-108
02/16/1711:05
78
13-107
02116/1711:05
46
10-110
02/16/1711:05
77
12-102
02/16/1711:05
32
10-110
02/16/1711:05
100
21-132
02/16/1711:05
Qualifiers
LIDS
Result
LCS
% Rec
% Rec
Limits
282
56
10-110
340
68
39-108
416
83
40-104
478
96
42-109
294
59
31-110
268
54
30-110
314
63
10-110
401
80
39-121
259
52
10-110
432
86
32-101
710
71
18-108
195
39
10-110
81
27-108
73
13-107
46
10-110
77
12-102
33
10-110
93
21-132
Pace Analytical Services, LLC
9600 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are In the units Indicated by the "Units" column except Mere an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
MATRIX SPIKE SAMPLE:
Parameter
1932894
Units
92328512001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,4-Dichlorobenzene
ug/L
ND
500
180
36
30-150
2,4,5-Trichlorophenol
ug/L
ND
500
208
42
30-150
2,4,6-Trichlorophenol
ug/L
ND
500
255
51
30-150
2,4-Dinitrotoluene
ug/L
ND
500
324
65
30-150
2-Methylphenol(o-Cresol)
ug/L
ND
500
165
33
30-150
3&4-Methylphenol(m&p Cresol)
ug/L
ND
500
146
29
30-150 M1
Hexachloro-1,3-butadiene
ug/L
ND
500
189
38
30-150
Hexachlorobenzene
ug/L
ND
500
281
56
30-150
Hexachloroethane
ug/L
ND
500
161
32
30-150
Nitrobenzene
ug/L
ND
500
262
52
30-150
Pentachlorophenol
ug/L
ND
1000
524
52
30-150
Pyridine
ug/L
ND
500
112
22
30-150 M1
2,4,6-Tribromophenol (S)
%
56
27-108
2-Fluorobiphenyl (S)
%
46
13-107
2-Fluorophenol(S)
%
27
10-110
Nitrobenzene-d5 (S)
%
46
12-102
Phenol-d6 (S)
%
19
10-110
Terphenyl-d14 (S)
%
65
21-132
SAMPLE DUPLICATE: 1932895
Parameter
Units
92329286001
Result
Dup
Result
RPD Qualifiers
1,4-Dichlorobenzene
ug/L
ND
ND
2,4,5-Trichlorophenol
ug/L
ND
ND
2,4,6-Trichlorophenol
ug/L
ND
ND
2,4-Dinitrotoluene
ug/L
ND
ND
2-Methylphenol (o-Cresol)
ug/L
ND
23.1J
3&4-Methylphenol(m&p Cresol)
ug/L
ND
ND
Hexachloro-1,3-butadiene
ug/L
ND
ND
Hexachlorobenzene
ug/L
ND
ND
Hexachloroethane
ug/L
ND
ND
Nitrobenzene
ug/L
ND
ND
Pentachlorophenol
ug/L
ND
ND
Pyridine
ug/L
ND
ND
2,4,6-Tribromophenol (S)
%
73
74
1
2-Fluorobiphenyl (S)
%
69
72
4
2-Fluorophenol (S)
%
39
41
5
Nitrobenzene-d5 (S)
%
68
70
3
Phenol-d6 (S)
%
27
30
9
Terphenyl-d14 (S)
%
83
91
9
Results presorted on this page are in the units Indicated by the "Units" column except Mere an alternate unit Is presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC.
Page 17 of 27

_ 2ce A nalXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 346763 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92328515001
SAMPLE DUPLICATE: 1923588
92328432001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 87.7 87.8 0
SAMPLE DUPLICATE: 1923589
92328515001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 98.3 98.2 0
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are In the units Indicated by the "Units" column except Inhere an alternate unitis presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01 /2017 11:29 AM without the written consent of Pace Analytical Services, LLC.
Page 18 of 27

i
Pace Analytical Services, LLC
i aceftlytical ® 9800Hunte sv Ile, NCKinceyAve.1100 te 28078
wwwpace/abs.com [phone]
QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 346861 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92328515001
SAMPLE DUPLICATE: 1924063,
92328443001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented b the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 27

aceAnalytical
,1 www.pacelabs.com
QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515 l
QC Batch: 346843 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Descriptio 9045 pH
Associated Lab Samples: 92328515001
SAMPLE DUPLICATE: 1923992
92327982001 Dup
Parameter Units Result Result
pH at 25 Degrees C Std. Units 6.0 6.0
RPD Qualifiers
0 H1
Pace Analytical Services, LLC
9B00 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
Results presorted on this page are In the units Indicated by the "Units" column except Mere an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01 /2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 27

17ZAnalytical'
wwwpacelabs.com
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 248878
QC Batch Method: SW-846 7.3.3.2
Associated Lab Samples: 92328515001
METHOD BLANK: 1223965
Associated Lab Samples: 92328515001
Parameter
Units
Cyanide, Reactive
mg/kg
LABORATORY CONTROL SAMPLE: 1223966
Parameter
Units
Cyanide, Reactive
mg/kg
SAMPLE DUPLICATE: 1223967
Parameter
Units
Cyanide, Reactive
mg/kg
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 9014
Analysis Description: 733C Reactive Cyanide
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 02/09/17 20:01
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
100 ND 0 0-8
40145270001 Dup
Result Result RPD Qualifiers
<0.55 ND
Results presented on this page are in the units Indicated by the "Units" column except Where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in fuil,
Date: 03/01 /2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 27

aceAnalytical
www.pacelabs.mm
QUALITY CONTROL DATA
Project: 170201-09
Pace Project No.: 92328515
QC Batch: 248881 Analysis Method: SM4500S2F-00
QC Batch Method: SW-846 7.3.4.2 Analysis Description: 734S Reactive Sulfide
Associated Lab Samples: 92328515001
METHOD BLANK: 1223984 Matrix: Solid
Associated Lab Samples: 92328515001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide, Reactive mg/kg ND 10 02/09/17 17:46
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE: 1223985
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide, Reactive mg/kg 200 56.2 28 0-52
SAMPLE DUPLICATE: 1223986
40145270001 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg <13.7 ND
SAMPLE DUPLICATE: 1224197
30209885001 Dup
Parameter Units Result Result RPD Qualifiers
Sulfide, Reactive mg/kg 88.4 88.4 0
Results presented on this page are In the units Indicated by the "Units" column except Mere an alternate unitls presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/01/2017 11:29 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 27

Pace Analytical Services, LLC
e
aceAnalytical 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: 170201-09
Pace Project No.: 92328515
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
' MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
' 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
' NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
' Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
' PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
' PASI-PA Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
H1 Analysis conducted outside the EPA method holding time.
I L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L3 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
' S4 Surrogate recovery not evaluated against control limits due to sample dilution.
Date: 03/01/2017 11:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 27

Pace Analytical Services, LLC
m 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville, NC 28078
wwwpacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: 170201-09
Pace Project No.: 92328515
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92328515001
170201-09
EPA 3510
348417
EPA 8081
348500
92328515002
170201-09 PCB
EPA 3580
347230
EPA 8082
347337
92328515001
170201-09
EPA 3510
351394
EPA 8151
352158
92328615001
170201-09
EPA 3010A
347460
EPA 6010
347490
92328515001
170201-09
EPA 7470
347461
EPA 7470
347556
92328515001
170201-09
EPA 3510
348381
EPA 8270
348553
92328515001
170201-09
EPA 8260
347397
92328516001
170201-09
ASTM D2974-87
346763
92328515001
170201-09
EPA 1010
346861
92328515001
170201-09
EPA 9045
346843
92328515001
170201-09
SW-846 7.3.3.2
248878
EPA 9014
248932
92328515001
170201-09
SW-846 7.3.4.2
248881
SM4500S217-00
248931
Date: 03/01/2017 11:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 27

ANNUAL PATHOGEN AND VECTOR FORMS
F
1
1
1
u
1

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (503 Rules)
Facility Name: Town of Cleveland
IWWTP Name: Cleveland WWTP
Monitoring Period: From To
WQ Permit Number:
WQ0011431
NPDES Number: NCO049867
503 32 Pl a indicate level achieved and alternative performed:
Pathogen Reduction
(40 CFR . ) - eas
Alternative 1 lJ
Alternative 2 ElAlternative
3
Class A:
Alternative 4 iL
Alternative 5
Alternative 6 l
.........................
If applicable to alternative performed (Class A only) indicate "Process to Further
Reduce Pathogens":
Compost (. Heat Drying 11Heat Treatment Ll
Thenmophilic Ll
Beta Ray El
Gamma Ra
Pasteurization E
Class B:
Alternative 1
Alternative 2 l
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization D Air Drying[] Composting Aerobic Digestion I
.:
Anaerobic Digestion
:.:
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Number o
Allowable Level Pathogen Density
Excee-
Analytical
Frequency Sample Tech -
Parameter
in Sludge inimun Geo. Mean aximun Units
of Analysis Type
Yp
2 x 10 to the
MPN
1124
4682
13855
pn/gran
0
Annual
Grab
922ICE
6th power
CFU
per gram of
Fecal Coliform
total solids
1000 mpn per gram
of total solid (dry
weight)
monella bacteria
3 MPN per 4 grams
in lieu of fecal
r
total solid (dry
coliform)
weight
r__ ..a.
A t' R d ction (4U l'rK Sus 33) - Rease inaicate optio„ ullek—[ uieu.
Vector tti ac ion e u
Alt-1 (VS reduction) (
Alt. 2 (40-day bench)
Alt. 3 (30-day bench) Alt. 4 (Spec. O, uptake) 0
Alt. 5 (14-Day Aerobic) El
Alt. 6 (Alk. Stabilization (v;;;l
Alt 7 (Drying - Stable) jAlt. 8 (Drying - Unstable)
Alt. 9 (Injection) Lj
Alt. 10 (Incorporation) Ej
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
l "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
L1 "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check
this statement attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
6A( PrestAeal
Land A lier Name and Title (if applicable)(type or print)
i , 1al
Date Signatt of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 503 (12/2006)

Town of Cleveland
Non -Discharge Permit No. WQ0011431
2017
7 �f
S�Iffipl
�e,�Date
l Fe Collforan' i; r s`
yids
f� s ��
si
, ,Rl
i' q
µ
01/30/17
! 12,849-
4.11
01/30/17
13,855
4.14
01/30/17
13,529
4.13
01/30/17
12,777
4.11
01/30/17
1,212
3.08
01/30/17
1,176
3.07
01/30/17
1,124
3.05
Total 25.69
Average 3.67
Fecal Coliform - MPN/ ram dry weight
Geometric Mean g Y g
I
Geometric Mean of Less than 2,000,0001 mets Class B -Alternative 1 Pathogen Reduction
I�
Fecals 2017 Page 1

Client: -TOINI to
11 IVY ) 1
r
-
STATESVfLLEANALYTICAL�
l
Address:
--
122 Court Strict • P.O. Box 228
Statesville. NC 28687
[phone]
Contact Person:
Phone #
FAX#
Chain of
Custody Record
Po # Requisitioned by: (Time Dale)
Customer
Sa IDb
Lab -ID p
Time Sampled
(Grab Onty) I
Date Sampled
(Grab Only)
na
S
Matrix
w
tw+
Parameters requested for analysis
!
V'If
1 0201 Lf '16-C'f
7;30_
T�-- I Ole &�
5
02
9:3/
c3--
'7
�G-
:ao
0 o
h.
Relinquished by:_ :Zzz
Time d
�J", pm Date a / / / / %
Sampled by: _-
Time
6�m Date LLL Ij
Transported by:
Received by: —�
Relinquished by:
Time
am, pm Date _/ /—
Holding times met:
Received : b
Y
_
Time
am, pm Date �_/_
✓
Compliance work:
Composite Sampling
#1:
Time begin-..-
am, pm Date —J^/_
Non-compliance work:
Time end
am, pm Date �_/__
Lab C� omments:
CoMposite Samplings
_
Time begin
am, pm Date
Time end`
am, pm Date
I-
rn
N p
00
lb �
O d
ai
00
N
N
X
O
m

Client: —rut n i n fl I
1 V I V .j
t/ p �} ��
�t -C� l�l,
sraTEsvn.Ltr axa[.Yrrcal.
122 Coun Street • P.O. Buz 229
titatesville, NC 28687
_
Address:
--
[phone]
Contact Person:
Phone #
FAX#
Chain of
Custody Record
PO # Requisitioned by: (Time "'Y Date)
Customer
Sample IDN
Lab -ID fr
Time Sampled
(Grab Only)
Data Sampled
(Grab Only)
0
swya
Matrix
w
r vnv
Parameters requested for analysis
i
) r
1 '? Q .-
-C
!.3 s
—i
iCIL, P
q.3 `
37
Relinquished by:yj�gj,
Received by:
Relinquished by:
Received by:
ComrsositeSSampling #1;
Time begin am, pm Date
Time end ---am, pm Date
Composite Sampling:
Time begin am, pm Date
Time end am, pm Date
r_
I I_
^/ /_
Time �� : ro
r� �(� J t�L- Time I L
Time
Time
Lab Comments:
�, pm Date l� /�
m m Date ZI I
am, pm Date _/_J_
am, pm Date �_/_
Sampled by:
Transported by: rt/(
Holding times met:
Compliance work: V
Non-compliance work:
I
rli
N
Y
M
00
N
N
x
0
m
0
a

Analytical Results
Town of Cleveland
PO Box 429
Cleveland, NC 27013
Receive Date: 02/01/2017
Reported: 03/07/2017
For:
Comments:
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
170201-09-01 Fecal Coliforms
1
12849
MPN/g
SM92210E-2006
02/01/2017
WC
170201-09-01 Percent Solids
1
1.79
%
SM254OB-1997
02/01/2017
WC
170201-09-02 Fecal Coliforms
2
13855
MPN/g
SM92210E-2006
02/01/2017
WC
170201-09-02 Percent Solids
2
1.66
%
SM2540B-1997
02/01/2017
WC
170201-09-03 Fecal Coliforms
3
13529
MPN/g
SM92210E-2006
02/01/2017
WC
170201-09-03 Percent Solids
3
1.70
%
SM254OB-1997
02/01/2017
WC
170201-09-04 Fecal Coliforms
4
12777
MPN/g
SM92210E-2006
02/01/2017
WC
_. 170201-09-04 Percent Solids
4
1.80
%
SM254OB-1997
02/01/2017
WC
170201-09-05 30 Day Benchscale
Digestor
2.1
%
EPA625-R-92/0
02/01/2017
WC
170201-09-06 Corrosivity
Digestor
See Attached
SW-646
02/18/2017
PACE
170201-09-06 Ignitability
Digestor
See Attached
1010M
02/18/2017
PACE
170201-09-06 Reactivity
Digestor
See Attached
Sw-846
02/18/2017
PACE
170201-09-06 TCLP
Digestor
See Attached
as Noted
02/18/2017
PACE
_ Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 5

Condition of Receipt
Sample Number 170201-09-01 Temp on Arrival: 3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 170201-09-02 Temp on Arrival: 3
Parameter Schedule:
Percent Solids
Received on Ice
Parameter Schedule:
Fecal Coliforms
Sodium Thiosulfate
Received on Ice
Sample Number 170201-09-03 Temp on Arrival: 3
Parameter Schedule:
Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 170201-09-04 Temp on Arrival: 3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule:
Fecal Coliforms
Sodium Thiosulfate
Received on Ice
Sample Number 170201-09-05 Temp on Arrival: 3
Parameter Schedule:
Received on Ice
Sample Number 170201-09-06 Temp on Arrival: 3
Parameter Schedule:
Reactivity
Received on Ice
' PO Box 228 • Statesville, NC 28687 0 704/872/4697
Page 2 of 5
1

Parameter Schedule: Corrosivity
Received on Ice
Parameter Schedule: Ignitability
Received on Ice
Parameter Schedule: TCLP
Received on Ice
PO Box 228 • Statesville, NC 28687 e 704/872/4697
Page 3 of 5

Client: �j\in
Yy V� 1 1
11 ��,
7 v
STAI'MV(LLEANALVTIChl,
122 CourtStmet • P.O. Box ?28
Statr yille,NC 28697
[phone]
Address:
Contact Person:
Phone #
FAX#
Chain of
Custody Record
PO # Requisitioned by: (Time Date)
Customer
Sample IDA
�IC�QStGY ;I'7C(3d
lab -ID t1
1lG
CI
Time Sampled
(Grab Only)
Cr-_�--/
Date Sampled
(Grab Only)
°
P
8
s.raa
Matrix
w
win
I
Parameters requested for analysis
--- '-
IYIT ��o
i
i
Time O: au it?pm Date ! l L&I
Relinquished by: �� / _�_ LZ
Sampled by:
Received by: —
_ _
J Mime t pm Date �_/U 7
L 1�
Transported by:
Relinquished by:
_—_—_ Time
am, pm Date _/_/_
Holding times met:
Received by:
Time
am, pm Date _/_!_
Compliance work:
CQmposite Sampling #1• — -
.... ._......... _...... .....-- --—...... —
Time begin -_..—_....... ...
am, pm Date _/_/_
Non-compliance work:
Time end
am, pm Date
/_/_ Lab Comments:
ComMsite Sampling #t2
Time begin
am, pm Date ---J_/_
Time end
am, pm Date _/---J_
n
00
W
e0
N
ai
v
V)
00
N
N
X
O
on

Analytical Results
Town of Cleveland
PO Box 429
Cleveland, NC 27013
Receive Date: 01/30/2017
Reported: 03/07/2017
For: Digestor
Comments:
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
170130-16-01
Fecal Coliforms
1
<1212
MPN/g
SM92210E-2006
01/30/2017
WC
170130-16-01
Percent Solids
1
1.65
%
SM254OB-1997
01/30/2017
WC
170130-16-02
Fecal Coliforms
2
<1176
MPN/g
SM92210E-2006
01/30/2017
WC
170130-16-02
Percent Solids
2
1.70
%
SM2540B-1997
01/30/2017
WC
170130-16-03
Fecal Coliforms
3
<1124
MPN/g
SM92210E-2006
01/30/2017
WC
170130-16-03
Percent Solids
3
1.78
%
SM254OB-1997
01/30/2017
WC
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 3

Condition of Receipt
Sample Number 170130-16-01 Temp on Arrival: 3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 170130-16-02 Temp on Arrival: 3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 170130-16-03 Temp on Arrival: 3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 3

SOIL SAMPLES

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/
Report No. FY18-SL024864
Predictive
Client:
Denise Harrison
Bio-Green Services Inc.
Advisor:
Soil Report
Mehlich-3 Extraction
383 Potts Rd
Advance, NC 27006
Links to Helpful Information
Sampled: Not Provided
Sampled County :Davie
Received: 12/20/2017
Farm: Not Provided
Completed: 02/19/2018
Client ID: 275491
Advisor ID:
Sample ID: CLRA1
Recommendations:
Lime
Nutrients (lb/acre)
More
Crop
(tons/acre) N P2O5
K2O Mg S
Mn
Zn
Cu B
Information
Lime History:
1 - Fescue/OGrass/Tim, E
1.3 50-70 50
30 0 0
0
0
0 0
Note: 12
2- Fescue/OGrass/Tim, M
0.0 120-200 40
70 0 0
0
0
0 0
Note: 12
Test Results [units - W/V in g/criti3; CEC and Na in meq/100 crii3; NO3-N in mg/daft
Soil Class:
Mineral
HM% W/V CEC BS% Ac pH
P-1 K-1 Ca% Mg%
S-1 Mn-I Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-1 Na ESP SS-1 NO3-N
0.22 1.10 16.2 90 1.6 6.1
42 33 57 31
33 354 222 228
88
88
136 0.3 2
North Carolina
Tobacco Trust Fund Commission
Reprogramming of the laboratory -information -management system that makes this report possible is
being funded through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

'ILE
NCDENR
North Carolina Department of Environment and Natural Resources
Pat McCrory Donald van der Vaart
Governor Secretary
March 20, 2015
Mr. Danny Gabriel, Mayor
Town of Cleveland
P.O. Box 429
Cleveland, North Carolina 27013
Subject: Acknowledgement of Receipt of the 2014 Annual Report
Town of Cleveland - Permit No.: WQ0011431
Land Application of Residuals
Rowan County
Dear Mr. Gabriel:
The Mooresville Regional Office received and reviewed the 2014 Annual Report for the above
permit. The information submitted indicates there was no land application activity conducted
under this permit in 2014. 1 may be reached by phone at [phone] or email
(maria.schutteancdenr.gov) should you have questions about this permit.
Sincerely,
Maria Schutte, Environmental Specialist
Mooresville Regional Office
Water Quality Regional Operations Section
Division of Water Resources, NCDENR
CC: Dena Myers, Contract ORC, Statesville Analytical (Email)
Ed Hardee, LAU Compliance, CO -Raleigh (Email)
Mooresville Regional Office
610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115
Phone: [phone] / Fax: [phone]/Customer Service 1-877-623-6748
Internet: www.ncdenr.gov
An Equal Opportunity 1 Affirmative Action Employer— Made in part by recycled paper

RECEIVEDINCDENRIDWR
MAR 9 2015
WOROS
MOORESVILLE REGIONAL OFFICE
TOWN OF f-VUEA 16 C'�
RESIDUALS LAND APP I jlgMf ROGRAM
Permit No. W00031:1431
2014 ANNUAL REPORT

ANNUAL LAN® APPLICATION CERTIFICATION FORM
Permit Number W00011431 County Rowan Year 2014
Facility Naine (as shown on permit) Town of Cleveland WWTP NPDES No. NC0049867
Land Application Operator Synagro Phone# [phone]
Land application of residuals as allowed by the above pen -nit occurred during the past calendar year?
YES X NO. If NO, skip Part A and Part B and proceed to the certification. Also, if residuals were generated
but not land applied, please attach an explanation on how the residuals were handled.
PART A
Total number of application fields in pen -nit:
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres land application occurred during the year:
PART B
Facility was pliant during cal ar y 0 t c o f t a a ication permit (i din but not
t o ite 1- y
se ti w a s of n t o la'Q
n• 1'
i
1.
Only residuals approved for this permit were applied to the permitted sites.
2.
Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least
-
6.0 or the limit specified in the permit.
3.
Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3)
--
copies of laboratory results are attached.
4.
Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
- 5.
All other monitoring was performed in accordance with the permit and reported during the year as required and
three (3) copies of certified laboratory results are attached.
6.
The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (Applicable to 40 CFR Part 503 regulated
facilities).
7.
All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (Applicable to 40 CFR Part 503 regulated facilities).
8.
All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9.
No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10.
Vegetative cover as specified in the permit was maintained on this site and crops grown were removed in
I
accordance with the crop management plan.
11.
No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12.
All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the possibility
of fines and imprisonment for knowing violations."
lj Gfln
Gabriel, Mayor
Permittee Name and Title (type or print) Signature o� ririittee Date
Signature of Preparer* Date
(if different from Penmittee)
Signature of Land Applier Date
(if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9(r) DENR FORM ACF (5/2003)

Residuals Handling In Calendar Year 2014
Town of Cleveland, North Cai°olina
Permit No. WQ001143
No biosolids from the Cleveland wastewater treatment plant (NPDES permit
Number NC0049867) in Cleveland, NC were land applied in 2014. The
facility has been retaining the residuals within available onsite storage
vessels at the treatment facility location.

2014 ANNUAL REPORT
PROJECT: Town of Cleveland NC
FACILITY: Town of Cleveland NC
625 Third Creek Church Road
Cleveland, NC 27012
NPDES PERMIT NUMBER:
RESPONSIBLE OFFICIAL:
FACILITY OPERATOR:
LAND APPLIER AND
PREPARER OF LAND
APPLICATION ANNUAL REPORT:
NC0049867
Daniel Gabriel, Mayor
Town of Cleveland
Post Office Box 429
Cleveland, NC 27013
[phone]
Dena Myers, Contract ORC
c/o Statesville Analytical
122 Court Street
P.O. Box 228
Statesville, NC 28687
[phone]
Synagro Central, LLC
Contact: Marshall Puryear
[phone] ext. 17

Formula Sheet for all Wastewater Operator Exams
Revised 8/15
F001
Surface area of a pond, acres = Length, ft x Width, ft
43560
F002
Volume of a pond, MG = C(Sur-face area, sf)2+ (Bottom area, sf)1 X (Depth, ft)X 7.48
(1,000,000)
F004
o _ Influent BOD, mg/L- Effluent BOD, mg/L o
BOD removal efficiency, /o - X 100 /o
InfluentBOD,mg/L
F008
Theoretical detention time of a pond, days = Volume of the pond, MG
Flow rate, M G D
F011
Removal efficiency, % -_ Influent concentration- Effluent concentration) X 100%
Influent concentration J
F012
Solids, Ibs= (Volume, MG) x (MLSS, mg/L) x (8.34)
F016
Average flow rate, MGD = (Final flow, MG) - (Initial flow, MG)
Time elapsed, days
F017
BOD loading, Ibs/day = (Flow rate, MGD) x (BOD, mg/L) x 8.34
F018
TSS removal efficiency, % = C Influent TSS -Effluent TSS X 100% InfluentTSS
F020
Volume of sample needed for a BOD test bottle, mL =
1200
EstimatedBOD of the sample,mg/L
F021
BOD, mg/L = Initial D.O., mq/L - Final .D.O., mq/L) x 300 mL
Sample volume, mL
1

e
F022
Chlorine feed rate, Ibs/day = (Flow, MGD) x (Dosage, mg/L) x (8.34)
F023
TSS test results, mg/L = Net dryweight, mg X 1000 mUL
(Samplevolume,mL)
F030
Pump capacity, gpm = ,(Width, ft)x(Length, ft) x (Draw -down, ft) x 7.48
Time of draw -down in minutes
F030B
Increased flow = (New pipe diameter, inch
(Old pipe diameter, inch) 2
F030C
Flow rate in a pipe, gpd =
(Pipe diam ) nches)2
in/ft
(12 in/ft)2 x 0.785x (Velocity, ft/sec)x 60 sec/m inx 1440 m in/dayx 7.48 gal/cf
F032
Desired suspended solids, Ibs = (Sludge age, days) x (Primary effluent solids, lb/day)
F033
Volume per stroke, gal/stroke = (0.785)x (Di1 meter,inches)2 x r(Stroke, inches) x (7.48)1
F034
Total dry solids, Ibs = (Raw sludge, gal) x (Total solids, %) x (8.34)
100%
F035
MLSS, Ibs = (Aeration volume, MG) x (MLSS conc, mg/L) x (8.34)
F037
Digestion time, days = Digester volume, gal
Flow, gpd
F038
InfluentP mg/L—EfFluentP,mg/L o
Phosphorus (P) removal, % _ x 100 /o
Influent P, mg/L

F039
Sludge applied, gal = (Area, sf) x (Depth of application, in) x (7.48)
12 in/ft
F040
Pollutant emission rate, Ibs/day = (Flow, gpd) x ( Pollutant conc., mq/L) x (3.785 L/gal)
453,600 mg/lb
F043
Chemical application rate, Ibs/day = (Flow, MGD) x ( Chemical dosage, mg/L) x 8.34
F045
Flux, gpd/sf =(Flow rate, qpm) x (60 min/hr) x (24 hr/day)
Surface area of membrane, sf
F047
New, or actual, WAS flow rate, MGD = (Calculated WAS flow, MGD) x (24hr/day)
Actual hours of sludge wasting, hr/day
F048
Solids produced, Ibs/day = (BOD removed, Ibs/day) x (Yield factor)
F050
Primary sludge, Ibs/day = (Flow rate, MGD) x (Inflow SS, mg/L - Effluent SS, mg/L) x 8.34
F052
Hydraulic loading of a DAF. unit, gpd/sf = (Inflow rate,gpm)x(1440)
Liquid surface area, sf
F053
Solids loading to a centrifuge, Ibs/hr = Sludge flow rate, gal/hr) x (Sludge conc %) x 8.34 Ibs/gal
100%
F054
Efficiency of solids removal, /o = Influent SS, %—Effluent SS, % x
o � 100 o/o
Influent SS, %
3

F055
Dry polymer, Ibs = (Volumeof solution,gal)x Polymer concentration,% x(8 341b/gal)
100%
F058
Pumping rate, gpm = (Volume, cf) x (7.48 gal/cf)
Time, min
F061
Surface loading,d/sf = Flow, gpd
gp Surface area, sf
F062
Solids loading, Ibs/day/sf = (Flow, MGD) x (TSS, mg/L x (8.34)
Surface area, sf
F063
Sludge age =
TSS in aerator, Ibs
TSS in primary effluent, Ibs/day
F064
F/M = Ibs BOD/day to aeration tank
Ibs of MLVSS under aeration
F065
Waste sludge pumping rate, MGD =
Current pump rate, MGD+ (Difference in aerator sludgeinventory, Ibs)
(RAS concentration, m g/L)x 8.34
F066
MCRT, days = MLSS in aerationtion tank, Ibs
(TSS wasted, lbs/day)+ (TSS in effluent, Ibs/day
F068
MLVSS, mg/L = BOD Loadingfrom primary,lbs/day,
(F/M Ratio)x (Aerator volume, MG)x (8.34)
F069
Return sludge rate, MGD = Settled solids, mL x (Flow, MGD)
(1000 mL - Settled solids, mL)
F073
S02 feed, Ibs/day =(Flow, MGD) x (Residual chlorine, mg/L + SO2 overdose, mg/L) x (8.34)
4

F074
Chlorine demand, mg/L = (Chlorine dose, mg/L) - (Chlorine residual, mg/L)
.11
Polymer dose, mg/L = (Polymer delivery rate, qpm) x (Polymer, lbs/qal) x (1,000,000)
(Flow, gpm) x (8.34)
F077
Polymer dose, mg/L = (Polymer feed rate, Ibs/day) x (1,000,000)
(Flow, gpm) x (1440) x (8.34)
F078
Volume of seed sludge, gal = (Volume of digester, gal) x (% seed)
F079
_Solid loading, Ibs/day = (Raw sludge volume,gal)x(Solid conc,%)x(Volatile fraction,%)x(8.34)
F081
Total settleable solids to pump to digester, gpd = (Sludge removed, mL) x (Flow, MGD) x (1000)
F082
% reduction of volatile matter, % = (In - Out) x (100)
In - [(In) x (Out)] ('in" and "out' in fraction, not in %)
F083
/o
0 reduction of volatile matter, /o 0 _ C(initial volatile matter, Ibs)- (Final volatile matter, Ibs)I
x 100/o
0
-
Initial volatile matter, Ibs
F087
Seed correction per 1.0 mL of seed = Initial D.O. - Final D.O.
mL of seed in bottle
and
BOD5, mg/L -_ [(Initial DO, mg/L)- (Final DO, mg/L)]- (Seed correction, mg/L) x 300 m L
Samplevolume,mL
F088
Volume diluted, mL = (Target normality) x (Target volume, mL)
Stock acid normality
F091
Sludge flow, MGD = (Thickener loading, Ibs/day/sf) x (Surface area, sf)
(8.34) x (10,000) x (% solids)
F092
Desired Ibs of solids in aeration tank = (Daily solids addition, Ibs/day) x (Sludge age, days)
5

F094
New digestion time, days = (Digester volume, gal)x(Increase in sludge conc,%-Initial sludge conc,%)
(Initial sludge flow, gpd) x (Initial sludge conc, %)
F096
Volume of working solution, mL ='(Beaker volume, mL) x (Dosage, mg/L)
(Stock solution conc, %) x (10,000)
F097
Chemical feed rate, gph = (Flow, MGD) x (Dosage, mg/L) x 100%
(Solution strength, %) x (24 hr/day)
F098
Surface loading rate, gpd/sf = (Flow rate, MGD) x (1,000,000 gal/MG)
(Diameter, ft)2 x (0.785)
F099
Polymer dosage, mg/L = (Polymer pumping rate, gpm) x (Polymer conc. Ibs/gal) x (1,000,000)
(Sludge flow rate, gpm) x (8.34 Ibs/gal)
F100
Retention % - (Retentate conc., mg/L) -(Permeate conc., mg/L) x 100%
Retentate conc., mg/L
F101
Average transmembrane pressure, psi =
(Inlet pressure, psi + Outlet pressure, psi) - Permeate pressure, psi
2
F103
RAS, MGD = (Settled volume, mUL) x (Influent flow rate, MGD)
(1000 mL/L) - (Settled volume, mL/L)
F105
Sludge age, days -_ (Tank volume, MG)x (MLSS, mg/L)
(Inflowrate, MGD)x (Primary effluent SS, mg/L)
F106
F/M, lb COD/day per lb MLVSS -_ (Flow, MGD)x (COD, mg/L)x (8.34lbs/gal)
(Solids under aeration,lbs)x (Volatile fraction
F108
Phosphorus to be added, Ibs/day = [BOD Ibs/day x P/BOD (desired ratio)] - (P in wastewater, Ibs)
M

F110
Desired COD loading, Ibs/day = (COD loading rate, Ibs COD/Ibs VS) x (VS, Ibs)
F111
Sludge produced, Ibs/day =
(Flow, MGD.) x (Influent BOD, mg/L - Effluent BOD, mg/L) x (8.34 x yield factor)
F112
Thickened sludge volume, gal/day = SlOge,lbs/day x 100% °
8.34lbs/gal. Sludges olidsconcentration, /o
F114
Solids loading, Ibs/hr/sf = (Flow, gpm) x (60) x (8.34 Ibs/gal) x (SS%)
(Liquid surface area, sf) x (100%)
F115
Air to solids ratio -_ (Air supplyrate, cfm)x (0.075 Ib/cf)x (100%)
(Solidsfeed rate, gpm)x (Sludgeconc, %)x (8.34 Ibs/gao
F116
Feed time to a centrifuge, min = (Storage volume cf) x (Basket sludge conc, %) x (62.4 Ibs/cu ft)
(Flow, gpm) x (Influent solids, %) x (8.34 Ibs/gal)
F117
Increase of detention time, days = (Aerobic digestervolume, gal)x (Increasein sludgec°onc., %)
(initialsludgeflow, gpd)x (Initial sludgeconc., /°)
F122
Polymer dosage, Ibs/ton = (Polymer solution conc %) x (Polymer added, gpm) x (2,000 Ibs/ton)
(Sludge conc, %) x (Sludge flow rate, gpm)
F123
Sludge loading,lbs/dayx Recovery, %1
Vacuum filter yield, Ibs/hr/sq ft = 100% J
(Duration of filter operation,hr/day)x (Filterarea,sf)
F124
Required filter run time, hr/day = Sludge solids loading, Ibs/day x Solids recovery,
(Filter yield, Ibs/hr/sf) x (Filter area, sf) x (100%)
7

1.
Cell Yield M in wastewater systems
W1912015 .
0 Comments
Cell yield (Y) is the amount of new cell mass created per unit of substrate removed. In wastewater, we usually define
substrate as BOD5, COD, orTOG Inmost cases a true defined substrate is unknown becuase the influent is a mix from
multiple streams. So over the years, data has been collected from multiple systerns with differing influent makeup,
temperatures. F/M ratios, pH, and any number of other environmental factors` I'll distill some of the infbrination below
Aerobic Yield
+ With no information on F1M ratio or influent makeup, I use 0.5 g ceiWg BOD5 in the influent ,
• Vilith starch and other readily degradable infi;uents, you can increase this to 0.6 g cells}g BOD5.
• Nigh FIM rations (less biomass, more substrate) - you have a higher cell yield which decreases gradually as the
F1M lowers - N.B. it is not a linear relationship between F/M and Y The lower cell yield is actually do to
endogenous respiration (cell death) that occurs in the confines of the treatment system so it does have some
advantages & disadvantages (III post more on this lager)`:
+ in practice you see cell yields anywhere From 0A - 0.6 in most cases.
Annerchic geld
• From an energy generation standpoint: anaerobic respiration results in less "energy' for cell growth than aerobic
systems. The result is less cell yield per unit of substrate.
• Normal cell yield (Y) is 0.06 g cellsfg substrate - which is approximately 1 Qx less than yields fro aerobic system.
This is why high strength wastewaters are often treated with anaerobic digestion.
Nowfor a general table of Cell Yield

Water Resources
ENVIRONMENTAL QUALITY
Mr. Danny Gabriel, Mayor
Town of Cleveland
P.O. Box 429
Cleveland, North Carolina 27013
Dear -Mr. Gabriel:
f' �.l--=�PAT MCCRORY
iiI �!_.� Governor
DONAL.D R. VAN DER VAART
Secrelaty
S. JAY ZIMMERMAN
Director
March 22, 2016
Subject: Acknowledgement of Receipt of the 2015 Annual Report
Town of Cleveland - Permit No.: WQ0011431
Land -Application of Residuals
Rowan County
The Mooresville, Regional Office (MRO) received and reviewed the 2015 Annual Report
for the above permit. The report reflects there was no land application of residuals
conducted under this permit in 2015.
The MRO plans to conduct an on -site facility inspection within, the calendar year;
however, if you have any immediate concerns or questions, please contact me at
[e-mail] or (704) 663-.1699.
Sincerely,
Maria Schulte, Environmental Specialist
Mooresville Regional Office
Water Quality Regional Operations Section
Division of Water Resources, NCDEQ
CC: Dena Myers, Contract ORC, Statesville Analytical (Email)
Nathaniel Thornburg, LAU Compliance, CO -Raleigh (email)
State of North Carolina Environmental Quality I Water Resources I Water Quality Regional Operations
Mooresville Regional Office) 610 East Center Avenue, Suite Ml I Mooresville, North Carolina 28115
704 663 1699

1 p
TOWN OF CLEVEN1r1C�'�
RESIDUALS LAND APPLICAT� PROC M
RECEIVED/NCDENR/DWR 2 3 .2016
MAR I Fmv 'iit No. WQ0011 1SECTION
INFORMATION PROCESSING UNIT
WQRO�.2015 ANNUAL REPORT
MOORESVILLE RFGIONAL OFFICE

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit Number W00011431 County Rowan Year 2015
Facility Name (as shown on permit) Town of Cleveland WWTP NPDES No. NCO049867
Land Application Operator Synaero Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
YES X NO. If NO, skip Part A and Part B and proceed to the certification. Also, if residuals were generated
but not land applied, please attach an explanation on how the residuals were handled.
PART A
Total number of application fields in permit:
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres land application occurred during the year:
PART B
as QUmpliant durm cal ar y 0 At c o f t a a cation permit (i dine but not
ite 1-1 y t AWM
se ti w a lair& ocatis
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least
6.0 or the limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3)
copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and
three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (Applicable to 40 CFR Part 503 regulated
facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (Applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and crops grown were removed in
accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false info ation, including the possibility
of fines and imprisonment for knowing violations."
Daniel Gabriel Mayor
Permittee Name and Title (type or print) Signature o f 3ittee Date
Signature of Preparer* Date
(if different from Permittee)
Signature of Land Applier Date
(if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9(r) DENR FORM ACF (5/2003)

hQ,
ivIAR
3 2014
L-J
Ali-, A
RECEI'/Ft-k,
_�Av TOWN OF CLEVE��pq Nc
RESIDUALS LAND APPLIC1NOROGRAM
WAFER QUALITY SECTION
Permit No. MMM4�t-SSING ON117
2013 ANNUAL REPORT

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit Number W00011431 County Rowan Year 2013
Facility Name (as shown on permit) Town of Cleveland WWTP NPDES No. NC0049867
Land Application Operator Synaero Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
YES X NO. If NO, skip Part A and Part B and proceed to the certification. Also, if residuals were generated
but not land applied, please attach an explanation on how the residuals were handled.
PART A
Total number of application fields in permit:
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres land application occurred during the year:
PART B
Facility w
t o
"no'
.
asLliant Burin cal ar y 0 t c Oth
t a a ication permit (' din but not
rte y tJse ti w a s ot o
3
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least
6.0 or the limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3)
copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and
three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Lunits in Table 1 of 40 CFR part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (Applicable to 40 CFR Part 503 regulated
facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (Applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and crops grown were removed in
accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the possibility
of fines and imprisonment for knowing violations."
John I. Steele, Jr„ Mayor
Permittee Name and Title (type or print)
Signature of Preparer* Date
(if different from Permittee)
Signature of Permittee Date
Signature of Land Applier Date
(if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9(r) DENR FORM ACF (5/2003)

Residuals Handling in Calendar Year 2013
Town of Cleveland, North Carolina
Permit No. WQ0011431
No biosolids fiom the Cleveland wastewater treatment plant (NPDES permit
Number NC0049867) in Cleveland, NC were land applied in 2013. The
facility has been retaining the residuals within available onsite storage
vessels at the treatment facility location.

PROJECT:
2013 ANNUAL REPORT
Town of Cleveland NC
FACILITY: Town of Cleveland WWTP
625 Third Creek Church Road
Cleveland, North Carolina 27013
NPDES Permit Number: NCO049867
_- RESPONSIBLE OFFICIAL: John I. Steele, Jr., Mayor
Town of Cleveland
Post Office Box 429
Cleveland, North Carolina 27013
[phone]
FACILITY OPERATOR:
Dena Myers, Contract ORC
c/o Statesville Analytical
122 Court Street
P.O. Box 228
Statesville, North Carolina 28687
[phone]

FILE
NCDENtt
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Pat McCrory Thomas A. Reeder John Skvarla
Governor Acting Director Secretary
June 26, 2013
Mr. John I. Steele, Jr., Mayor
Town of Cleveland
P.O. Box 429
Cleveland, North Carolina 27013
Subject: Acknowledgement of Receipt of the 2012 Annual Report
Town of Cleveland - Permit No.: WQ0011431
Land Application of Residuals
Rowan County
c -f
Dear Mr. Branch:
The Mooresville Regional Office (MRO) received and reviewed the 2012 Annual Report
(AR) for the above permit. Supporting data for volatile solids reduction was missing from the
report, but the MRO received a copy via email. Please verify all data is submitted in future reports
and maintained on file, at the wastewater treatment plant, in accordance with requirements of your
permit. The MRO plans to conduct an on -site facility inspection within the calendar year; however,
if you have any immediate concerns or questions, please contact me at [phone].
Sincerely,
c
Maria Schulte
Environmental Specialist
cc: Chonticha McDaniel, Residuals Management, CO-LAU (email)
Dena Myers, Contract ORC, Statesville Analytical (email)
Marshall Puryear, Synagro (email)
Division of Water Quality / Aquifer Protection Section I Mooresville Regional Office One
�+ t'„
610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 NorthCarolina
Phone: [phone] Fax: [phone] Customer Service: 1-877-623-6748 ��N��`®�
Internet: www.ncwaterquality.org AaL
An Equal Opportunity 1 Affirmative Action Employer

TOWN OF CLEVELAND, NC
RESIDUALS LAND APPLICATION PROGRAM
Permit No. WQ0011431
2012 ANNUAL REPORT

Town of Cleveland, NC
Residuals Land Application Program
2012 Annual Report
TABLE OF CONTENTS
1. Certification Form, Annual Operations Summary, Facility and
Land Applier Contact Information
2. Annual Residual Sampling Summary Forms, Residuals
Analysis, & SAR Calculation Pages
3. Annual Land Application Field Summary Forums
4. TCLP Analysis
5. Pathogen Reduction/Vector Attraction Reduction
6. Soil pH & Lime Application Records
7. Soil Analysis

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit Number W00011431 County Rowan Year 2012
Facility Narne (as shown on pen -nit) Town of Cleveland WWTP NPDES No. NCO049867
Land Application Operator Synag_ro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip Part A and Part Band proceed to the certification. Also, if residuals were generated
but not land applied, please attach an explanation on how the residuals were handled.
PART A
Total number of application fields in pen -nit: 5
Total number of fields land application occurred during the year: 1
Total amount of dry tons applied during the year for all application sites: 3.44
Total number of acres land application occurred during the year: 13.7
PART B
Facility was compliant during calendar year 2012 with all conditions of the land application permit (including but not
limited to items 1-12 below) issued by the Division of Water Quality X YES NO.
If no, Please provide a written description why the Facility was not compliant, the dates, and explain corrective action
taken.
1. Only residuals approved for this pen -nit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least
6.0 or the limit specified in the pen -nit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3)
copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the pen -nit and reported during the year as required and
three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (Applicable to 40 CFR Part 503 regulated
facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (Applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and crops grown were removed in
accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of
fines and imprisonment for knowing violations."
John I. Steele, Jr., Mayor
Permittee Name and Title (type or print)) (l
rgnature of Preparer* Date
(if different from Permittee)
Sim e i e a FEB �_
`1
Signature of Land Applier Date
(if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9(r) I)1FNR FORM ACF (5/2003)

2012 ANNUAL OPERATIONS SUMMARY o LAND APPLICATION
CLEVELAND, NC
LEVELAND, NC AEROB. DIGESTED LIQUID
MONTH/YEAR
April 2012
YEARLY TOTAL
AMOUNT UNIT
93,600.00 G
93,600.00 G
DRY TONS UNIT
3.44 D
3.44 D
DRY METRIC
TONS
3.12
3.12
1 /21 /2013

2012 ANNUAL REPORT
PROJECT:
FACILITY:
NPDES PERMIT NUMBER:
RESPONSIBLE OFFICIAL:
FACILITY OPERATOR:
LAND APPLIER AND
PREPARER OF LAND
APPLICATION ANNUAL REPORT:
Town of Cleveland NC
Town of Cleveland NC
625 Third Creek Church Road
Cleveland, NC 27012
NCO049867
John I. Steele, Jr., Mayor
Town of Cleveland
Post Office Box 429
Cleveland, NC 27013
[phone]
Dena Myers, Contract ORC
c/o Statesville Analytical
122 Court Street
P.O. Box 228
Statesville, NC 28687
[phone]
Synagro Central, LLC
Contact: Marshall Puryear
[phone] ext. 17

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: W00011431
Facility Name: 'CLEVELAND, NC
NPDES## : NCO049867
or WQ# (residual only)
WWTP Name: CLEVELAND, NC
Residuals Analysis Data
Product Type AEDLIQ
Date Sampled (grab) or 03 / 12 / 12
Date Composited
Percent Solids 0.88
PARAMETERS (mg/kg dry weight)
Arsenic
0.89
Cadmium
2.84
Mercury
1.47
Chromium
585
Copper
469
Lead
22.7
Molybdenum
0.09
Nickel
24.4
Selenium
1.82
Zinc
1030
Total Phosphorus
20455
TKN
39432
Ammonia -Nitrogen
3420
Nitrate and Nitrite
12273
Laboratory
STATESVILLE ANALYTICAL
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
T \
GNATURE OF
Date -P
DENR FORM RSSF (5/2003) Printed: Monday - January 21 2013 at 08:02:38 for: 2173 01

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0011431
Facility Name: CLEVELAND, NC
NPDES# : NCO049867
or WQ# (residual only)
WWTP Name: CLEVELAND, NC
Residuals Analysis Data
Product Type AEDLIQ
Date Sampled (grab) or 03/12/12
Date Composited
Percent Solids 0.88
PARAMETERS (mg/kg dry weight)
Aluminum
3523
Calcium
21364
Magnesium
1892
pH
5.44
Potassium
93.3
Sodium
9204
Laboratory
STATESVILLE ANALYTICAL
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Date,
NATURE OF PR
NR - Data Not Reported or Data Not Required
DENR FORM RSSF-B (7/2002) Printed: Monday - January 21 2013 at 08:03:09 for. 2173 01

Analytical Results
Town of Cleveland
PO Box 429
Cleveland NC 27013
Entered 3/1212012 -
Reported: 4/10/2012
For: Digester
sample ID ParanjeW Cuot 10 i1esult. t)nIts P ...14O.d date Apalypo Analyst
120312-2
% Sollds' Digester
0.88
%
SM2946B
3/12/12 •
CL
120312-2
Aluminum-flame/sollOigester
3523.
mg/kg
SM 3111 D.
3/27112'.
MD
120312 2
Arsenio-Pumace/sollOigester
0.89
mg/kg
SM3113 B
4/3112
MD
120312-2
Cadmium- Digester
2.84
mg/kg .
SM3111B
3/21/12
MD
120312-2
Calclum=Flame/solid Digester
21,364
mpg
SM 3111 D
3/19/12
MD
1312-2
Chromlutn- Digester
585
mg/kg
SM3111B
3/27/12.
MD'
_.1312 2
Copper-Flame/solid Digester.
469
meft
-SM3111B
3119/12
MD
120312-2
Lead-furn: ace/solid Digester
22.7
mg/kg
SM3111B
3121/12
MD
420312-2
Magnesium- Digester
- 1892
mg/kg
SM 3111 D
3/27/12
MD
120312-2
Mercury -solid - Digester
1.47
m9�9
245.1
3/21/12
MD
120312-2
Moiybdehum - Digester
0.09090000
mg/kg
EPA200.7
3/26112
PACE
1203122
NI13N-solid Digester
3420
mg/kg
SM4500NH3B 3112112
CL
120312-2
Nickel-Flame/solld Digester
24.4
mg/kg
SM3111B
3/27112
MD
1203i2-2
NO3NO2-solid Digester
12,273
mg/kg
SM460OF/A
3127/12
CL
120312-2
PH Digester
5.44
STD units
SM4500HB
3/12112
CL
120312-2
Potassium-ICP/soild Digester
93.3
mg/kg
EPA200.7
3/26112
PACE
120312 2
SelenlurTrsolld Digester
1.82
mg/kg
SM 3113 B
3/20/12
MD
120312 2
Siiver-Flame/solid Digester
8-3
mg/kg
SM3111B
3/27112
MD
120312-2
Sodium -solid Digester
9204
mg/kg
SM 3111,8
3/19/12
MD
120312 2
T.Phosphorous-solldDigest,er
20,455
mg/kg •
SM450OPE
3127/12
CL
120312-2
TCLP Digester
See Attached
1311-
3126/12
PACE
120312-2
TKN-solid Digester
39,432
mg/kg
SM4SOO.NMB
8115/12
MD
120312-2
zinc,-Flame/solid Digester
1030
mg/kg
SM3111B
3119/12
MD
Apt nIt T2oGsd �6, of I rfllk.5. �40,f 7, e •�
P,O,'Box 228 ® Statesville, North Carolina 28687 o 704187214697
T a.�ecd LBL2-BL87f'OL ieox-4RTeud QTjTAs9ge,4S wdso:i? ZToa OT u,

Town of- Cleveland - -
PO Box 429
Cleveland NC 27013
_..aced 3/12/2012
Reported: 4/10/2012
For: Digester
Sample ID Parameter oust 1® - -Result U.i�l MOWD.a A
Respectfully submitted,
Dena Myers
NC Cert #440,
NCDW Cert #37755;
EPA NCO0909
0
2 a2ed
1
P.O. Sox 228 Statesville; North Carolina 28687 a 704/872/4697
L9L2-.8L8-tr0L ie0XgRZeud 911Tn.s91.e,4g 6ld60:}, 2T02 01 Jd0

Sodium Absorption Kato® Calculation (SAR)
Product Code Product Name Sample Date Report Range Ratio
2173-01-AEDLIQ-NC CLEVELAND, NC AEROB. DIGESTED 3/12/2012 411/2012-4130/2012 1.5163
. ILIQUID
Na mg/1= (Na mg/kg x % Solids) _ 100 = (9204 x 0.8800) = 100 = 80.9952
Ca mg/I = (Ca mg/kg x % Solids) _ 100 = (21364 x 0.8800) _ 100 = 188.003
Mg mg/1 = (mg mg/kg x % Solids) _ 100 = (1892 x 0.8800) _ 100 = 16.6496
Na meq = Na mg/I _ Molec.Wgt.Na = 80.9952 _ 23 = 3.52153
Ca meq = Ca mg/I _ Molec.Wgt.Ca = 188.003 _ 20 = 9.40016
Mg meq = Mg mg/I _ Molec.Wgt.Mg = 16.6496 + 12 = 1.38747
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.52153 - SgrRoot[0.5(9.40016+1.38747)] = 1.51629
Printed: 1 /21 /2013
Page 1 09:45

FACILITY NAME: CLEVELAND, NC
OWNER: DARLENE DOBY
SITE #: NC RA 00054 FIELD# : RA 00054 0002 B
RESIDUAL SOURCE(S):* See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PERMIT #: WQ0011431 ANNUAL DRY TONS APPLIED: 3.44
OPERATOR: DARLENE DOBY CATION EXCHANGE CAPACITY (NON-503):
ACRES UTILIZED: 13.70 ACRES PERMITTED: 13.70
Page
Lime Applied'•+
Date
Lbs Ac
DATE or
allons (G) or Cubic Yards (CY)
or Wet Tons (WT) (specify)
ova
Dry
Tons
per
Residual
Site
Cond.
Dry, Wet,
Inches
Precip.
Past 24
Appli-
cation
Method
Vola-
tili-
zation
Miner -
ali-
zation
TKN
Ammonia
Nitrogen
Nitrate
and
PAN
(ppm)
Crop
MONTH
Total
Per Acre
Solids
4/24/12
43,200.00 (G)
3153.285
0.88
0.116
CLEAEDL
DRY
0-<1/2"
SUR
0.5
0.30
39,432. p
3,420.00 p
12,273.01 p
24787
I FESCUE
4/25/12
50,400.00 (G)
3678.832
0.88
0.135
CLEAEDL
DRY
0-<1/2"
SUR
0.5
0.30
39,432.p
3,420.00 p
12,273.0(p
24787
FESCUE
Apr-12
1 93,600.00 (G)
6,832.117
1
Total Gallons/Ac: 6,832.12
i Mai %.Uv1 i uyric. U.UU
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn
P
PAN
TOTALS:
Annual lbs/acre
12
<.001
0.001
0.293
0.235
0.011
<.001
<,001
0.012
<.001
0.516
10.26
Cumulative lbs/acre
0.013
1 0.154
1 0.904
1 5.987
1 0.405
0.045
0.292
0.355
0.062
13.395
Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop
}
2
s
FD Cumulative Pollutant Loading Rate Limit (lbs/acre)
36.6
34.8
1339.0
267.9
15.0 375.0
89.0
2500.0
CLEAEDL = CLEVELAND, NC AEROB. DIGESTED LIQUID
X:`
(SIGNATU L APPLIER) DATE
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and
evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0
* Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2013

e
/74
PaceHn'aiytlomil.t3arvicsim;tnC • '
^c05 EaetMeaifctivfioeld'-SviteA
PacaAi> iylii le",inc, '
-'=` 4225 ('thlerBfde.Dr.
A
Paeijnalyttnal8ervtoee,too.
esuo 10ttoayAVG. Sulfa 100.
Edon, NC 27288
-
AMevlle, NO 28404
Hunrarsvilie, NO 28078
(339)62"921
[phone]
[phone]
ANALYTICAL RESU4TS
Project: 120312
Pace Project No.: 92114247
Sample: 120312-2
L.ab"(l)r; 92i14wb01
Co%cted: 03)12rl2.0000
Reoelvgd: 03114/1210:10 Matrix: Vlrater .
Parameters
Results . Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
8681 GCS Pasticides,TCLP SPE
ArialyboalMethod: EPA8081 -Preparation Method: EPA 3536
Leachate Method/Date: EPA 1311; 023/12 08:00
gamma-SHC (Uridane)
ND ug1L'
0.60
1
03/23/12 09.:45 OW27/1918:19 68.89.9
Chlordane (Technical)
NQ ug/L
3.0
1
03123112;09;45. 02.7112 1019. 57.74.9
Endrtn
ND ug/L
0,50
• 1
031231i209:41i 03/711216:19 72-20-8
Fteptachlor epoxide
ND ug[L
0.50
1
0312311209:46..031271.1-g16:19; 1024.67.3
Methoxychfo[
ND uglL
1000•
--1-
03/23/12.09'A6: 03/27/1216;19 72.43.E
Toxaphene
ND ug1L
3..0
1
03/23/12.09:45 03 VA/ 10:19 8001-36.2
5[rmtga,199
.
Decachicrobfphenyl (S)
86 %
1D-130
1
03/23/12 DOAS 03127/1218:18 2061=24.3
Tet[echloro-m-xylene (S)
126 °%'
10-110
1
03/23112 09:45 03/2711216:19 877-09-8 .82
8161 Chlorinate Herbicide TCLP Anelytloal Method: EPA8161
2.4-D
2A5-TP (Sitvex)
surragate:9
2.4-DCAA (S)
200.7 MET ICP
Molybdenum
Potassium
ti010 MET 1CP, TCLP
Arsenic
Barium
Cadmium
Chromium .
Lead
Selenium
$Aver
7470 MorcPry, TCLP
Mercury
8270 M88V TCLP Sep Funnel
1,4-131chlorobenzene
2.4-Dlnitratoluene
Hexachlo-1,3-buted lens
Hexacmvhlorobehzene
Hexachlordelhine
2-Methylphenoko:Cresol) -
3U-Methylphenol(m&p Cresol)
Nitrobenzene
ND mg/L
0.010 1
03/2311212:36 03127/1204:47 94-76.7
ND mg/L
0.010 1
03/231121215. 03/27/12 04:47 93.72-1
113 %
70A30 1
0312311212:35 03/2711204:47 19719.28-9
Analytical Method: EPA'200.7 Preparation Method: EPA200.7
90.9 ug1L
5.o- 1-
03/17/1214:06. 03123/12 02:48 7439-98-7
93300 uglL
8000 1
0311711214:06 03123N2-02:48 7440-09-7
Analylloal Method: EPA6010 Preparation Method: EPA3010
Leachate Method/Date: EPA 1311; 0312311219:00
ND mg/L -
0.025 1
03/25111211:00 03128/1215:21 744D-1&2
1A mg/L
0.60 1
-0=5/1211-.0Q 03128/12.02'25 7440-35.3
- ND mgfL
0.0050 • 1
03/25112-1'I :'00 03128112 02:25 74404M
-0.090 mg/L
0,025. 1
03126112likb .03/2811?_02:26 7440-47-3
ND mg/L
0.025 1.'
03/25/1211:00 03/2811202i25 7439-92-1 .
ND mg/L
0.10 1
031251.1211.1)0- t)31261:12-02;26' 778249-2
ND mg1L
0.026 1
0312.6/1211:00. Uil!1112 02:25 744o-22-4
Analytical Method: EPA7470 Preparation Mathod: EPA7470
Leachate Method/Date. EPA 1311; 03/23/1210:66
ND ug/L
0.20 ' 1
03/20/12 1106 03126/121635.7439.97-8
Analytical Method: EPA0270 Preparation Method: EPA3610
Leachate Mothod/Date: EPA 1311; 03r23/12 08;00
ND Ug/L
60.0 1
03123/12 09:00 03/2811216:67 106.46-7
ND ug/L
50.0 - 1
03/23/12 09:00 03128/1 � 18:67 121-14.2 -
ND ug/L
60.0 1
0=31,12 09.00" 03/28/1E 16:67 87-6M
ND ug/L
60.0 1 •
02iM200:00 03/28/1218:67 118.74.1
ND ug/L
50.6 1
03/23/i209:00. 03126/1218:57 67-72-1
ND ug/L
60.0 1
03/2311200.`00 03126/1218;67 W48-7 .
ND ug/L
50.0 1
03/23/12.09 00 D3/26/12.48:67
ND ug/L
50.0 1
0312'3l1209;00 03/2611218:57 98-96-3
Date: 03/2912012 05:13 PM -.REPORT OF LABORATORY ANALYSIS Page 4 of 21
7ria report shall riot bereproduced, Wept In fuf,
without thswriHen consebt of PaceArWyt(cel Services, lno..
9 a2ecl LBGz-81-8-i7DL ieoigRTeu9 9jjTASa4e4S Wd8b:Z aloe of ,gad

Aac®Ansiyticg_I eiviaedilvc., 3?a0pa icsl:8®ryicea;r0a: - P.g4AnaWcaI3erviceaslno.
CeAr➢alj l 2D5 EdstMe2226:R&aarside Dr.. 9840'Mn eyAve. SOW 100
Eden, 40 27286 AehWiie, NO 28804 Huntersvile, NO 28078
(3S8�ZS•8921 _ (828)254-717e [phone]
.. • ANALYTICAL RESULTS
Project: 120312
Pace Project No.: 92114247
Sample: 126312-2
Lab ID: 929142470Q9 --olle'ded:
• .03112/12 04:00
-11"ved: W14112:16:10 : Matdx:.Water
Paramebars
RestAts Units Report Urri t '
DF '
Prepared' Analyzed' CAS No. Qual
8270 AtSSV TCL•P Sep. Funnel
Analytical Method: EPA0270 Preparatlon Method: EPA3510
Leachate Method/Date:-EPA 1311; 03/23/12 08:00
Pentachiorophenol
NO ug/L
100
1
03/23/12 09:00. 0312611218:57 87-80-5
Pyridine
NO ug/L
80.0
1
03123/12-=09:00.:03128(i2•iB:67.• 110.86.1
2,4,6-Trlohlorophenol
NO ug/L
50.0
1
03i2Wi2 09, 0 03t20(12-18;67 $5fi15-4
2,A,6'-Trichforophenol
ND ug/L
50.0
1
0$/23H201;. .0312617i216:67 88-082'
Srlrrogaf8�
.
Ntrobenzene-d6 (8)
_
41 %
12.102
1
03/23/42 09:00 03128112 467 4166-80.0
2-Fluoibblphenyl ($)
40 %
13-1.07
1-
03123112-09.00• :0312611218.67 321-60-8
Terpheny)-d14 (6)
62 %'
21:132
1
0�23112'. no O n61121$:67 1718-51-0
Phenol-d6 (8)
13 %
10410
1
03/23/1,g 09:00- 034�611218:57
13127-88.3
2-Fluorophenol (8)
22 %
10-110
1
03123f12 0:00 Q3/28112:18:57
=367--12-4
2,4,6-Tribromophenoi(8)
46 %
27-108
1
03311209:0Q'031Z81i218:57 118-79-6
8260 Ml8V TCLP
AnaWcal Method: EPA 8260
Benzene
ND ug/L
100 .
20
03/2311212:27 71-43-2
2-Butabone (MEIn
ND ug/L
200
20
03/2 1,02:27 78.93-3
Carbon tetrachloride
ND ug/L
100
20
03/2311212:27 56-23-5
Chlorobenzene
'ND ug/L
100
20
03/23/1212:27 108-90-7
Chloroform
ND ug/L
-100
20
03123/1212:27 67.68-3
1,4-Dlohlorobenzene .
ND ug/L.
100
20
03/2311212:27. 1064-7
1,2-Dichloroethane
ND ug/L
100
20
03123/12 12;27- i07-06-2
IIJ-01ohlbroethene
ND ug/L
100
20
03123l7212;27 75-35-4.
Tetrachloroelhene
. ND uq&
t00'
20
03/23/12 12:27 127-18-4
Tdchloroethene
NO ug/L
1100'
20
0312311212:27 79.01-6
Vinyl Chloride
ND ug/L
100
20
03/23/12"12;27 75 01.4
Surrogates
1,2-01chloroethane•d4 (S)
117
70:130
20
03/2311212:27 17060-07-0
Tolvene-d8 (8)
98 %
67-135
20
03/23/1212:27 2037-26-5
4-Bromoftuorobenzene (S)
97 %
70-130
20
0312VI212:27 460-00-4
Dibromofluorornelhane (8)
114 %
70-130
20
03/2&12 12:27 1868-53.7-
Percent Molsttiro
Analytical Method: ASTM 02074-87
Percent Moisture
88.1 %
0.50
1
03/21/12 00:00
1010 Fiashpolnt,Closed Cup
Analytical Method: EPA 1010
Fisshpolnt
>200 deg
70.0
1
03/2711209:00
Reactiva Sulfide
Analytical Method:-$W-84$ 7.3.4.2
Sulfide; Reactive
NO mg/kg
100
1
03/23/1212:16
9040 pH
Anafylicel Metttod: EPA 9040
PH
&0 Sid. Units
0.10
1
Q3/18/12 93;30 H6
733C S Reactive Cyanide
Analytical Method: SW-846 7.3.3.2
Cyanide, Reactive NO mg/kg 0.026 1 03/2311211:12
Date: 03/29/2012 06:13 PM
REPORT of LABORATORY ANALYSIS
This report sha@ not b's reproduced, except in rull,
without the wriften consent of Pace Aneybeat services, Ira,
Page 5 of 21
L abed aJIznsaJeqS Wdg3':Z aloa 01 Jdd

-
Page Ana cel:&etvtccii; fnc: ` =
FfaEeAifa aef_Srsi+lc8s,.t(tc..
Pi ce.,4b t o i Serilwe, in*.
)qA�
6
205Eaexmdddq�dRoad : Su.ReA
1226RfNerakdeDr.
S>800iCiriCefrAve. Suite SOD
•
Eden, NC 272BB
AehevHle, t1. 28804
HunterdHlle, NO 28079
[phone]
[phone]
(704)87"092
SAMPL ANA- 4YTE.ce5UNT
Project: . i 20312
Pace Project No.: • 92114247
Ana"
Lab ID 8ample'lD Method
Analy* .
Red Add
'Laboratory
9211424TOD1 120312-2 EPA8081
RES
8
PASI-C
EPA8161
SMB
.3
PASI-O
EPA200.7
•SHB
2
PAST -A
EPA6010
JMW
7
PASI-A
EPA7470
DMB.
1
PASI•A
EPA8270
PPM
18
PASI•C
EPA8260
KdM
16
PASI•C
ASTM D2974-87
DVVC
1
PASI-K
EPA 1010
SMW
1
PAST -A
SW-848 7.3.4.2
OL
1
PASI•K
EPA-9040
EVVS
1
PASI•A
SW-846 7.3.3.2
OL
1
PASI-K
REPORT OF LAsokATORY ANALYSIS Page 3 of21
Thfs report shall not be reproduced, except in rue,
without the written consent of PaceAnaiytieal Services, lne..
6 92ecl L 8 L Z - 8 L 8 - ir 0 L TeolgRTeuu aii3ns0,4egs Wd6t,:z 2TOZ 01 Jdu

paeaAftiOeaf3efvloep,'InJ:: - 'PdabA piyU�81,6ervloda�tne. PacgArut IC411SONiAa,lne.
A6 EBsille0o,wFZ6M 9uI1q-X, 2226,Rfvo'rsWeDr. 98Q0"!(InocyAve._ Sulle IN
4A
Eden, NC 27388 Ashev719, NG.288D4 HuntarBvitle, t 28070
(ss©)6zs ssx� [phone] (704)875•9092
QUALITY CONTROL DATA
Project; 120312
Pace Project No.: 92114247
QC Batch: GCSV/78t36
Analyd{ Method: ' EPA8161
QC Batch Method: EPA 81bi
Analysis Desai*n: 8161 GCS Hertilddes.TCLP
Associated Lab Samples: 92114247001
METHOD BLANK:- 361748
Matrix: Water
Associated Lab Samples: 92114247001
Blank Reporting
Parameter Units
Result Limit Ahalyzed Qualifiers
2,4,5-TP (S•rlvex) mg/L
ND 0.010'-03471t2 03:47
2,4-D mg/L
ND 0.010 03ts7�12 03:47
2,4-DCAA(S) %
111 70.130 •63)27l12 0$:47
LABORATORY CONTROL SAMPLE: 361749 • "
Spike LC5 LCS % Reo
Parameter Untts
Qonc. Result % Reo Limits Qualifiers
2,4,5-TP(Slfvex) mg/L .
.0112. 0.014- 117 70.130
'
2,4-D mg/L
.06 0.069 116 70430
2,4 •D CAA (8) %
110 70.130
MATRIX SP_ IKE & MATRIX SPIKE DUPLICATE: $61900
361999
MS MSD
92114247001
Spike Spike Mi MSD MS MSD
% Rec
Parameter Units Result
Conc, Cono, Result Resuft• " . % Ren 1/6 Rec •
Limits RPD Qual
2,4,6--TP (Sllvex) mg/L ND
1012 .012 . 0,014 0.014 -118 .115
_ 70-130 3
2,4•D mg/L NO
D6 ..be 0.076 0.072 126 120
70.130 6
2,4-DCAA (S) %
113 109
70-130
Date: 03/29/2012 06;13 PM REPORT OR LABORA70R.Y ANALYSIS Page 6 of 21
This reportshalt notbe reproduced, except inful,
without the written convent of Pace ArwJyrtiml Services, Ina,
g a�ecd LBLz-BLB-bOL ieoi�RTeuO aTIznsa�e�S WdB3':a zTOZ OT JJU

a
Face;Andyttci(Bmr!7t4ea,lnb:.,. ';
,Pabplri+}1$eivt�ea,'tfio.•
Pace.AnalytZeeiServfces,hie.
o
��
206 East'flFeadow Road, •8uit9A
?22b F21v0telds:l7G''
0600 KinosyAvO.'Su'rte tOD
Edon, NO 2728a
Mhbft; NO 28804 -
Hunt.sMV116., NO 28018
(336)6239921
[phone]
(704)876.80e2
4QL)AjTY_C0NTRq L-DATA
Project: 120312
Pace Project No.: 92114247
QC Batch: MERP14131 'Analysts Method: EPA.7470
0C Batch Method: EPA7470 Anatyals be aiptsap:. 7470 Mereury.TCLP-
Associated Lab Samples: 92114247001
METHOD BLANK: 140823 • Matdx: Water
Associated Lab Samples: 92114247001
Blank Reporting
Parameter Units Result' 1-h-dl . Anplyzed• Qualifiers
Mercury ug/L ND 0.0.20 `03128/12.1fi:14 �+
LA130RATORY CONTROL SAMPLE: 740924
Spike LOS LOS % Rea
Parameter Units Cone. Result- % Roo Limits Qualifiers
Mercury ug/L ' 2.6 4.7 168 80.120
MATRIX SPIKE SAMPLE: 740926
W114097001 Spike M is MR % Rea
Parameter Unite Result . ' Cone. Resell 0/6 Ree Limits Qualifiers
Mercury. ug/L- RE 2.5 2.6 103 i5-125
SAMPLE DUPLICATE: 740928
Parameter
Mercury
Date: 03/29/2012 05:13 PM
921144135001 Dup
Units F3eeuit Regult RPD Qualifiers
ug1L �ND , - ND
iREPORT or-. LA®oRAT®RV AMALYSIS
Thin report shell not baseproduodd, except in full,
Without the voitten oonaant of Pate Analytical Se Moss. Inc.,
Page 7 of 21
OT a2eol LeLa-el. 8-BOG IeO14RIeud 91ITASa-4e4S WJGf,:z -dTOa 01 JdU

Client:
dn"
STATESVILL£ ANALYTICAL
Address:
h? Court street • P.O. Sox =
Statesville. NC 28637
[phone]
Contact Person:
Phone #
FAX#
Chain of
1
Custody Record
PO # Requisitioned by: (Time Date)
Customer
sample IN
Lab -ID a
'rime Sampled
(Grab Only)
Date Sampled
(Grab Only)
a
Matrix
P rameters requested for analysis
studgol
W
i
c
1Z
Relinquished by:
per— ~
Time ��(; 3
a%, mm Date ! ��/LZ
Sampled by:
Received by:
Time j 2: U4'3a ,Date /I y 2
Transported by:
Relinquished by:
Time
am, pm Date _/ /�
Holding times met:
Received by:
Time
am, pm Date —/�/�
Compliance work:
Composite Sampling
#1:
Time begin
am, pm Date _/ /_
Non-compliance work:
Time end
am, pm Date �/ /�
Lab Comments-,
Composite Sampling
#2:
Time begin
am, pm Date
Time end
am, pm Date
J
;1
%J

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name Town of Cleveland Permit Number W0001 1431
WWTP Name Cleveland WWTP NPDES # NCO049867
Monitoring Period: From 01/01/2012 To 12/31/2012
Pathogen Reduction (40CFR 503.32) - Please indicate level achieved and alternative performed
Class A
Class B
Alternative 1 Alternative 2 Alternative 3
Alternative 4 Alternative 5 Alternative 6
Alternative 1 X Alternative 2 Alternative 3
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens";
Aerobic Dig. Air Dry Anaerobic Dig. Compost Lime Stab.
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable
Pathogen Densi
No. of
Freq. Of
Sample
Analytical
Level in
Exceed
Analysis
Type
Tech.
Sludge
Min. Geo. Max. Units
Mean
Fecal
2x10
<2,410
<2,520
<2,597
MPN/g
0
Annual
grab
SM 9221E
Coliform
MPN/g or
2X 106
CFU/g
1000
MPN/g
Salmonella
3 MPN/
bacteria
4 g
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed
Option 1 Option 2 Option 3 X Option 4 Option 5
Option 6 Option 7 Option 8 Option 9 Option 10
No vector attraction options were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
XX
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
"I certify, under penalty of law that the athogen requirements In 40 CFR 503.32 and the vector attraction
reduction requirement in 40 CAR 503ff have not been met." (Please note if you check this statement
attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to
ensure that qualified personnel properly Qather and evaluate the information used to determine that the pathogen and
vector attraction reduction requirements Piave been met. I am aware that there are significant penalties for false
certification including fine and imprisonment."
Preparer "Name and Title
VA�2=- S&
gnature of Preparer Dat
Land Appher Name and Title (if applicable)
Signature of Land Applier (if applicable) Date

Analytical Results
Town of Cleveland
PO Box 429
Cleveland NC 27013
Entered 113012012
Reported., 411212012
ForDigester Sludge
Sample ID
Parameter
Cust ID
Result
Units
Method
Date Analyzed
Analyst
120130-7.1
% Solids
1
0.80
%
SM2540B
1131112
CL
120130-7.1
Fecal Coliform MTF
1
<2500
MPN1g
SM9221 CE
1131112
CL
120130-7.1
Geometric Mean
1
<2520
MPN1g
dry wt. basis
211112
CL
120130-7.2
% Solids
2
0.77
%
SM2540B
1131112
CL
120130-7.2
Fecal Coliform MTF
2
<2597
MPN/g
SM9221 CE
1131112
CL
120130-7.3
% Solids
3
0.79
%
SM2540B
1131112
CL
120130-7.3
Fecal Coliform MTF
3
2532
MPN1g
SM9221 CE
1131112
CL
120130-7.4
% Solids
4
0.83
%
SM2540B
1131112
CL
120130-7.4
Fecal Coliform MTF
4
<2490
MPN/g
SM92210E
1131112
CL
120130-7.5
% Solids
5
0.78
%
SM2540B
1131112
CL
120130-7.5
Fecal Coliform MTF
5
<2564
MPN1g
SM9221 CE
1131112
CL
120130-7.6
% Solids
6
0.77
%
SM2540B
1131112
CL
120130-7.6
Fecal Coliform MTF
6
<2597
MPN1g
SM9221 CE
1131112
CL
120130-7.7
% Solids
7
0.79
%
SM2540B
1131112
CL
120130-7.7
Fecal Coliform MTF
7
<2532
MPN1g
SM9221 CE
1131112
CL
120130-7.8
Bench 30 Day
Digester Basin
4.19
%
EPA625R-9210315112
CL
P.O. Box 228 * Statesville, North Carolina 28687 * 704/87214697

Rpr 10 2012
2:48PM Statesville Analytical 704-878-2787
o
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page 3

Agricultural Lime Application Log
Year: 2012
Project:
Town of Cleveland
Field
Soil pH
Lime Requirement
Tons/Acre
Date Applied
(state -county -site -field code)
(from soil analySls)
Applied
NC-RA-54-213 1 5.6 1 0.6 1 0.6 1 11/26/2012

NCDA&CS AL uric Division Phone: [phone] Web site: www.ncagr.gov/agronoi
Report No: 45477
�currerF.,.�,
Grower:
Doby, Karlene
Copies To:
Synagro Centrals
1630 Baker Mill Rd.*
r �
p �
Cleveland, NC 27013
EY e�, t
o�� e or
Fai7n: RA-54
SERVING N.C. RESIDENTS FOR OVER 60 YEARS
Received: 06/19/2012
Completed: 06/26/2012 Links to Helpful Information
Rowan County
Agronomist Comments
12
Field Information
Applied Lime
Recommendations = -
Sample No. Last Crop
Mo Yr T/A
Crop or Year :Lime
N P205
K20 Mg S
Cu
Zn
B Mn See Note
2B
1st Crop: Fes/OG/fim,M i .6T
120-200 80-100
80-100 0 0
0
0
.0 0 12 Fs�_ %, j j
2nd Crop: Fes/OG/rim,M i 0
120-200 80-100
80-100 0 0
0
0
.0 0 12
Test Results
Soil Class HM%
W/V CEC BS% Ac ip H P-I K-I Ca% Mg%
Mn-I Mn-AI(1)
Mn-AI(2) Zn-I Zn-AI
Cn-I
S-I
SS -I NO3-N NH4-N Na
MIN 0.41
1.01 8.0 80.0 1.6 1 5.6 22 24 62.0 17.0
1593 973
973 80 80
113
26
0.1
U
North Carolina Reprogramming of the laboratory -information -management system that makes this report possible is being funded
-`� through a grant from the North Carolina Tobacco Trust Fund Commission.
Tlzank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture
Tobacco Trust Fund Commission

�cw4vNAGP\,O�z S
A Residuals Management Company
1999 ANNUAL REPORT
BIOSOLIDS LAND APPLICATION PROGRAM
T6-Wh--Of-Clev_eiand,�NC
Permit V1fQ00114`31
A better tomorrow for our Client Trian;le: The GENERATOR, The LANDOWNER, and The ENVIRONMENT
Prepared by:
SYNAGRO SOUTHEAST
P. O. Box 1770
6490 Stadium Drive
Clemmons, NC 27012
Toll Free: 1.877.267.2687
Fax: [phone]

Town Of Cleveland
Biosolids Land Application Program
1999 Annual Report
TABLE OF CONTENTS
I. Certification Form / Project Overview
II. Biosolids Analysis
III. TCLP Analysis
IV. Annual Operations Summary
V. Field Summary Form
VI. Pathogen Reduction/Vector Attraction Reduction
VII. Site pWAg Lime Applications
VIII. Soil Analysis

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit Number W00011431 County Rowan Year 1999
Facility Name (as shown on permit) Town of Cleveland WWTP
Land Application Operator Synagro Southeast Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year
✓ YES NO. If NO, skip Part I and Part II and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
PART
*Total number of application fields in permit. 4.
*Total number of fields land application occurred during the year. 1.
*Total amount of dry tons applied during the year for all application sites. 32.2
*Total number of acres land application occurred during the year. 42.5
PART II
Facility was compliant during calendar year 1998 with all conditions of the land application permit ( including but not
limited to items 1-12 below) issued by the Division of Water Quality_YES NO.
IF NO, PLEASE PROVIDE A WRITTEN DESCRIPTION WHY THE FACILITY WAS NOT COMPLIANT, THE
DATES, AND EXPLAIN CORRECTIVE ACTION TAKEN.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and the
three (3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and the three(3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13. (Applicable to 40 CFR Part 503 regulated
facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with
(Applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and crops grown were removed in
accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has
occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I CERTIFY, UNDER PENALTY OF LAW, THAT THE ABOVE INFORMATION IS, TO THE BEST OF MY
KNOWLEDGE AND BELIEVE, TRUE, ACCURATE, AND COMPLETE. I AM AWARE THAT THERE ARE
SIGNIFICANT PENALTIES FOR KNOWING VIOLATIONS."
C "4k &nc --T cor-, cler
Permittee Name and Title (type or print)
Signature of Preparer Date
(if different from Permittee)
NOTE: Preparer is defined in 40 CFR Part 503.9(r)
(1 n w w 4 'a, v � a 3-j-z)
Signature of rmittee �JLj
1Date
Synagro SoutheastSignature of Land AppleDate
(if different from Permittee and Preparer)
DEM FORM CF
(10/94)

Project Overview
The Town of Cleveland, NC land applied 335,000 gallons (32.2 dry tons) of biosolids in
1999 on a permitted farm in Rowan County. Land application events occurred in May,
August and December.
Wastewater is treated using activated sludge technology and residuals are stabilized
through aerobic digestion.

CERTIFICATION STATEMENT
per August 4, 1999 Federal Register/Vol. 64, No. 149
Certification Statement per 40 CFR 503.17(a) (4) (ii) (A)
Subject to Table 3, not necessary to keep up with Cumulative Loadings (a)(4)(ii).
Project: Cleveland, NC
Time Period: 1999
I certify, under penalty of law, that the management practices in 503.14 and the
site restrictions in 503.32(b)(5) were prepared for each site on which bulk sewage
sludge is applied under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate this
information. I am aware that there are significant penalties for false certification
including the possibility of fine and imprisonment.
Technical/Operations Director

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Permit Number:
Facility Name: Town of Cleveland NC
NPDES#:
WWTP Name: Cleveland Storage
,�lll/, SYNAG O
A Xrjidualt Management C.mpan)
PARAMETERS (mg/kg dry weight)
RESIDUAL ANALYSIS DATA
Laboratory
A&L
A&L
A&L
A&L
A&L
From
4/ 1/99
5/ 1199
6/ 1/99
8/ 1/99
12/ 1/99
Average
4/30/99
5/31 /99
6/30/99
8/31 /99
12/31 /99
Percent Solids
1.84
1.84
1.84
2.68
2.68
2.18
Arsenic
0.98
0.98
0.98
1.67
1.67
1.26
Cadmium
21.8
21.8
21.8
32.5
32.5
26.08
Chromium
NA
NA
NA
72
72
28.80
Copper
401
401
401
723
723
529.80
Lead
81
81
81
120
120
96.60
Mercury
4.68
4.68
4.68
4.5
4.5
4.61
Molybdenum
17
17
17
30
30
22.20
Nickel
28
28
28
25
25
26.80
Selenium
3.19
3.19
3.19
3.87
3.87
3.46
Zinc
1060
1060
1060
2360
2360
1580.00
TKN
70700
70700
70700
39200
39200
58100.00
Ammonia -Nitrogen
1100
1100
1100
400
400
820.00
NO2 + NO3
54
54
54
0
0
32.40
Total Phosphorus
27000
27000
27000
35100
35100
30240.00
x T.� dl V-___ (�, ('4,/
(SIGNATURE OF REPARER) DATE
"I certify, under penalty of law, that this document was prepared under my direction or supervision to accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Monday, January 24, 2000

A & L EASTERN AGRICULI vr;AL LABORATORIES, INC.
7621 Whitepine Road - Richmond, Virginia 23237 - [phone]
R122-a6a ACCOUNT 45128 Fax No. ( 80l4�E71-6446
REPORT NUMBER
ENVIRONMENTAL TASTE
RECYCLING, INC.
149 YADKIN VALLEY ROAD
ADVANCE NC 27006
LAB NUMBER = 42026
SAMPLE ID = STOR•AGE
RESULT
PARAMETER ( % )
----------------------------
CLEVELAND NC
F3$.%-fi�i lY.rrt
L1j pl (�
MIKE COLLINS
SLUDGE ANALYSIS REPORT R E D El V E D
DATE SAMPLED 04/22195
APR 3 () 1999 DATE RECEIVED 04/23/99
DATE REPORTED 04/28/99
DETECTION
RESULT LIMIT ANALYSIS
(MG/KG) (HG/KG) ANALYST DATE METHOD REFERENCE
----------------------------------------------------
SOLIDS(AS IS) 1.64 18400 100 KCS 04/23/99 SM 25406
NITROGEN(TKN) 7.07 70700 100 KCS 04/2G/99 EPA 351.3
PHOSPHORUS 2.70 27000 100 KM 04/26/99 EPA 365.4
POTASSIUM 0.70 7000 100 JCM 04/26/99 SN 846-6010
SULFUR 0.85 8500 100 JCM 04/26/99 sw 846-GOIO
CALCIUM 3.33 33300 100 13CS# 04/26/99 SN 846-6010
MAGNESIUM 0.32 3200 100 JCM 04/26/99 SW 846-601d
SODIUM. 1.22 12200 100 JCM 04/26/99 SW 846-6010
IRON 9150 1 JCM 04/26/99 Ski 846-6010
ALUMINUM 17200 10 JCM 04/26/99 sw 846-6010
MANGANESE 152 1 JCN 04/26/99 SW 846-6010
COPPER 401 1 JCM 04/26/99 Sw 846-6010
ZINC 10GO 1 JCM 04/26/99 SW 846-6010
AMMONIA -NITROGEN 0.11 1100 100 KCS 04/26/99 EPA 350.2
NO3-NO2 NITROGEN 54 10 KCS 04/26/99 SM 4500-NO3 F
CADMIUM 21.8 1 JCM 04/26/99 SW 846-6010
NICKEL 28 5 JCM 04/26/99 SW 846-6010
LEAD 81 5 JCM 04/26/99 Sw 846-6010
ALL VALUES ARE ON A DRY WEIGHT BASIS EXCEPT AS NOTED."
QULIL_�C . H. C H U C. NORMA J NES
,c:::f .- i;;•i conlioenlial use of our clients, and may not be reproduced in whole or :n part, nor may any reference be made to the
r,. iiie ; es.." : or ;iruI, ne:vs release, or other publl )uncements �.vilhout ob!aining our prior written authorization. Copyright 1977

A & L EASTERN AGRICULTURAL LABORATORIES, INC.
7621 Whitepine Road • Richmond, Virginia 23237 • [phone]
Fax No. (804� 271-6446
R122-060 ACCOUNT 45128 PA E 2
REPORT NUMBER
ENVIRONMENTAL WASTE
RECYCLING, INC. '
149 YA-DKIN VALLEY ROAD
ADVANC.F NC 27006
LAB NUMBER = 42026
SAMPLE ID = STORAGE
RESULT
PARAMETER ( X )
-------------------- --------
CLEVELAND NC
SLUDGE ANALYSIS REPORT
DETECTION
RESULT LIMIT
(MG/KG) (MG/KG) ANALYST
---------------------
MIKE COLLINS
DATE SAMPLED 04/22/99
DATE RECEIVED 04/23/99
DATE REPORTED 04/28/99
ANALYSIS
DATE METHOD REFERENCE
------- ------------------------
ARSENIC
0.98
0.4
KH
04/27/99
SR
846-7061A
MERCURY
4.68
0.1
KM
04/27/99
SW
846-7471A
SELENIUM
3.19
0.1
KM
04/27/99
SW
846-7741A
PH (STD.UNITS,AS:,IS) 7.10
RD
04/26/99
EPA
150.1
VOLATILE SOLIDS 74.98
749800
100
KCS
04/26/99
Ski
25406
ORGANIC NITROGEN 6.96
69600
100
DCH
04/26/99
CALCULATION
MOLYBDENUM
17
5
0CM
04/26/99
SH
846-6010
CHLORIDE
10490
1
AB
04/26/99
SM
4500-CL D
ALL VALUES ARE ON 'A DRY WEIGHT BASIS EXCEPT AS NOTED." &�.
H. CHU C. 4ORMADNES;
Our reports and letters are to; the exclusrre and confidential use of our clients, and �7ay not be reproduced in whole or in part, nor may any reference be made to the
k ork.. the resulls. of U),• compaurr in anv ,luveitising, news release, or other pub,,.. ouncements without obtaining our prior written authorization. Copyright 191 t

R240-103
REPORTNUMBER
A & L EASTERN AGRICLI JRAL LABORATORIES, INC.
7621 Whitepine Road - Richmona, Virginia 23237 • [phone]
Fax No. (804d 271-6446
ACCOUNT 45230 PA E 1
AMSCO
P 0 BOX 1.770
6490 STADIUM DRIVE
CLEMMONS NC 27012
LAB NUMBER = 44625
SAMPLE ID = AUG LAND APP
RESULT
PARAMETER
CLEVELAND NC
BIOSOLIDS ANALYSIS REPORT
DETECTION
RESULT LIMIT
(MG/KG) (MG/KG) ANALYST
---------------------
RECEIVES£SSIE
SUP
HEPLER
DATE SAMPLED 08/27/99
DATE RECEIVED 09/02/99
DATE REPORTED 09/08/99
ANALYSIS
DATE METHOD REFERENCE
- - - - - - - ----------------------
SOLIDS(AS IS) 2.68 26800 100 KCS 09/02/99 SM 2540G
NITROGEN(TKN) 3.92 39200 100 KCS 09/03/99 EPA 351.3
PHOSPHORUS 3.51 35100 100 JCM 09/03/99 SW 846-60108
POTASSIUM 0.44 4400 100 JCM 09/03/99 SW 846-6010B
SULFUR 0.98 9800 100 JCM 09/03/99 SW 846-6010B
56200 100 JCM 09/03/99 SW 846-6010B
CALCIUM 5.62
MAGNESIUM 0.35 3500 100 JCM 09/03/99 SW 846-6010B
SODIUM 0.95 9500 100 JCM 09/03/99 SW 846-6010B
IRON 12400 1 JCM 09/03/99 SW 846-GOIOB
ALUMINUM 21200 1.0 JCM 09/03/99 SW 846-6010
MANGANESE 226 1 JCM 09/03/99 SW 846-60109
COPPER 723 1 JCM 09/03/99 SW 846-6010B
ZINC 2360 1 JCM 09/03/99 SW 846-GOIOB
AMMONIA -NITROGEN 0.04 400 100 KCS 09/03/99 EPA 350.2
NO3-NO2 NITROGEN ND 10 KCS 09/03/99 SM 4500-NO3 F
j CADMIUM 32.5 1 JCM 09/03/99 SW 846-6010B
CHROMIUM 72 5 JCM 09/03/99 SW 846-6010B
NICKEL 25 5 JCM 09/03/99 SW 846-6010B
ALL VALUES ARE ON A DRY WEIGHT BASIS EXCEPT AS NOTED." OF194. CHU C�kOaRM4NJONE
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made to the
work, the results. or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Copyright 1977

A & L EASTERN AGRICL JRAL LABORATORIES, INC.
t
7621 Whitepine Road • Richmond, Virginia 23237 [phone]
Fax No. [phone]
R240-103 ACCOUNT 45230 PAGE 2
REPORT NUMBER
AMSCO CLEVELAND NC JESSIE HEPLER
P 0 Box 1.770
6490 STADIUM DRIVE
CLEMMONS NC 27012
LAB NUMBER = 44G25
SAMPLE ID = AUG LAND APP
RESULT.
PARAMETER ( % )
-------------------- --------
BIOSOLIDS ANALYSIS REPORT
DETECTION
RESULT LIMIT ANALYSIS
(MG/KG) (MG/KG) ANALYST DATE
DATE SAMPLED 08/27/99
DATE RECEIVED 09/02/99
DATE REPORTED 09/08/99
METHOD REFERENCE
-----------------------
LEAD
120
5
JCM
09/03/99
SW
846-GO10B
ARSENIC
1.67
0.4
KM
09/03/99
SW
846-7061A
SELENIUM
3.87
0.1
KM
09/03/99
SW
846-7741A
PH (STD.UNITS,AS IS) 7.00
RD
09/03/99
EPA
150.1
ORGANIC NITROGEN 3.88
38800
100
DCH
09/03/99
CALCULATION
MOLYBDENUM
30
5
JCM
09/03/99
SW
846-GOIOB
CHLORIDE
8180
1
AB
09/03/99
SM
4500-CL D
MERCURY TO FOLLOW.
ALL VALUES ARE ON A DRY WEIGHT BASIS EXCEPT AS NOTED." UAQL*.
H. CHU E. NORMAN JONi
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made to the
wor1�, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Copyright 1977

CAROUNA .ENVIRONMENTAL LABORATORIES, LLC
FINAL REPORT OF ANALYSES
Environmental Waste Recycling PROJECT NAME: Cleveland, NC
Attn: David Wanucha REPORT DATE: 05/28/99
149 Yadkin Valley Road
Advance, NC 27006-9801
SAMPLE NUMBER- 12424 SAMPLE ID- Cleveland, NC - TCLP SAMPLE MATRIX- OT
DATE SAMPLED�22 99'- TIME SAMPLED- 1100
DATE RECEIVED- 04/23/99 SAMPLER- Alan Brown RECEIVED BY- HCG
TIME RECEIVED- 13SS DELIVERED BY- UPS
Page 1 of 2
SAMPLE PREP
ANALYSIS
ANALYSIS
METHOD
DATE
BY
DATE
BY
RESULT
UNITS
LRL
1pP Arsenic
1311/7060A
05/05/99
PAK
05/27/99
ERP
<0.005
mg/L
0.005
:LP Barium
1311/7080A
05/05/99
PAK
05/11/99
DMG
< 2.5
mg/L
2.5
TCLP Cadmium
1311/7130
05/05/99
PAK
05/17/99
ERP
< 0.05
mg/L
0.05
TCLP Chromium
1311/7190
05/05/99
PAK
05/18/99
ERP
<0.25
mg/L
0.25
TCLP Lead
1311/7420
05/05/99
PAK
05/17/99
ERP
<0.50
mg/L
0.50
TCLP Mercury
1311/7470A
05/05/99
PAK
05/11/99
ERP
0.00128
mg/L
0.0002
TCLP Selenium
1311/7740
05/05/99
PAK
05/13/99
ERP
< 0.005
mg/L
0.005
TCLP Silver
1311/7760A
05/05/99
PAK
05/17/99
ERP
<0.20
mg/L
0.20
TCLP Herbicides
1311/6640B
05/05/99
PAK
05/21/99
PAK
2,4-D
1311/6640B
< 1.0
mg/L
1.0
2,4,5-TP (Silvex)
1311/6640B
< 0.10
mg/L
0.10
TCLP Pesticides
1311/8270
05/05/99
PAK
05/21/99
PAK
Chlordane
1311/8270
< 0.010
mg/L
0.010
Endrin
1311/8270
< 0.005
mg/L
0.005
Heptachlor
1311/8270
< 0.005
mg/L
0.005
Lindane
1311/8270
< 0.005
mg/L
0.005
Methoxychlor
1311/8270
< 0.005
mg/L
0.005
Toxaphene
1311/8270
< 0.050
mg/L
0.050
TCLP Volatiles 1311/8021B 05/05/99 PAK 05/18/99 PAK
Benzene 1311/8021B < 0.050 mg/L 0.050
Carbon Tetrachloride 1311/8021B < 0.050 mg/L 0.050
1229 North Horner Boulevard., Sanford, North Carolina 27330 919/775-1880 Fax [phone]
NC WW/GW 306 NC DW 37741 SC 99035

CAROLINA ENVIRONMENTAL LABORATORIES, LLC
Page 2 of 2
CONTINUATION OF DATA FOR SAMPLE NUMBER 12424
SAMPLE PREP ANALYSIS
ANALYSIS METHOD DATE BY DATE BY RESULT UNITS LRL
Chlorobenzene
1311/8021D
< YO
mg/L
10
Chloroform
1311/8021B
<
0.60
mg/L
0.60
1,4-Dichlorobenzene
1311/8021B
<
0.75
mg/L
0.75
1,2-Dichloroethane
1311/8021B
<
0.050
mg/L
0.050
1,1-Dichloroethene
1311/8021B
<
0.070
mg/L
0.070
Methyl Ethyl Ketone
1311/8021B
< 20
mg/L
20
Tetrachloroethene
1311/8021B
<
0.070
mg/L
0.070
Trichloroethene
1311/8021B
<
0.050
mg/L
0.050
Vinyl Chloride
1311/8021B
<
0.020
mg/L
0.020
TCLP Acids
1311/8270 05/05/99 PAK 05/21/99 PAK
o-Cresol
1311/8270
<
0.010
mg/L
0.010
m,p-Cresol
1311/8270
<
0.010
mg/L
0.010
Ntal Cresol
1311/8270
<
0.010
mg/L
0.010
-entachlorophenol
1311/8270
<
0.010
mg/L
0.010
2,4,5-Trichlorophenol
1311/8270
<
0.010
mg/L
0.010
2,4,6-Trichlorophenol
1311/8270
<
0.010
mg/L
0.010
TCLP Base/Neutrals
1311/8270 05/05/99 PAK 05/21/99 PAK
2,4-Dinitrotoluene
1311/8270
<
0.010
mg/L
0.010
Hexachlorobenzene
1311/8270
<
0.010
mg/L
0.010
Hexachloro-1,3-butadiene
1311/8270
<
0.010
mg/L
0.010
Hexachloroethane
1311/8270
<
0.010
mg/L
0.010
Nitrobenzene
1311/8270
<
0.010
mg/L
0.010
Pyridine
1311/8270
<
0.010
mg/L
0.010
LRL = Lower Reporting Limit
LABORATORY DIRECTOR U
1229 North Horner Boulevard, Sanford, North Carolina 27330 919/775-1880 Fax [phone]
NC R''W/GW 306 NC DW 37741 SC 99035

�titr
kN
SYNAGR
A Residuals Afanagenaent Company
SUMMARY OF BIOSOLIDS APPLICATION per TREATMENT PLANT
YEAR: 1999 NPDES NUMBER: NCO049867
PROJECT: Town of Cleveland, NC TREATMENT PLANT:
Month
JANUARY
FEBRUARY
MARCH
APRIL
MAY
JUNE
JULY
AUGUST
SEPTEMBER
OCTOBER
NOVEMBER
DECEMBER
TOTALS:
Gallons Percent Solids Dry Tons
149750
81250
104000
335000
1.84%
2.68%
Cr7
0
0
0
11.49
0
0
9.08018
0
0
0
2.68% 11.6226
32.1928
29.2053 Metric tons

;III//, SYNAGRO
A Hnidnn li Al—g—,I C..p,,,y
Town of Cleveland NC
Total Applications (Detail) 1/1/99To 12/31/99
Date Farmer Site Plant Dry Tons Gallons Yards Wet
5/4/99
Garnet Doby
1
Cleveland Storage
5.98
78,000
5/5/99
Garnet Doby
1
Cleveland Storage
5.51
71,750
8/27/99
Garnet Doby
1
Cleveland Storage
5.81
52,000
8/28/99
Garnet Doby
1
Cleveland Storage
3.27
29,250
12/7/99
Garnet Doby
1
Cleveland Storage
8.05
72,000
12/8/99
Garnet Doby
1
Cleveland Storage
3.58
32,000
Total
32.19
335,000•
Monday, January 17, 2000 Page 1 of 1

ANNUAL LAND APPLICATION TRACT SUMMARY FORM
Facility Name: Town of Cleveland NC
Tract Owner: Garnet Doby FSA: 2 Tract: 1
Operator: Garnet Doby ACRES: 50 Buffered Acres: 42.5
Total Dry Tons Applied (Annual): 32.19 Crop: Fescue
Lime Application (tons/acre):
SYNAGRO-
A Rriid-h Alauag,m-i C-panj
Cation Exchange Capacity:
Date
Gallons Yards Wet Tons
Applied Applied Applied
Per Acre
Dry Tons
Per Acre
Residual Source
%
Solids
Min.
Rate
Temperature
Rain
Past 24
Hrs
Site
Conditons
Method
5/4/99
78,000
1,835.29
0.14
Cleveland Storage
1.84
0.3
70-90
No rain
Dry
Surface
5/5/99
71,750
1,688.24
0.13
Cleveland Storage
1.84
0.3
70-90
No rain
Dry
Surface
8/27/99
52,000
1,223.53
0.14
Cleveland Storage
2.68
0.3
70-90
<.5 inch
Moist
Surface
8/28/99
29,250
688.24
0.08
Cleveland Storage
2.68
0.3
70-90
<.5 inch
Moist
Surface
12/7/99
72,000
1,694.12
0.19
Cleveland Storage
2.68
0.3
32-70
No rain
Moist
Surface
12/8/99
32,000
752.94
0.08
Cleveland Storage
2.68
0.3
32-70
No rain
Moist
Surface
Lbs/Acre
Totals
PAN P As
Cd
Cr
Cu Pb
Hg
Mo Ni
Se Zn
Annual
335,000
7,882.35
0.76
23.15 56.11 0.00
0.04
0.07
0.92 0.16
0.007
0.04 0.04
0.01 2.87
Cumulative
0.00
0.07
0.07
1.45 0.21
0.012
0.08 0.07
0.01 4.29
Permit limit (Ibs/acre/year) 250
Cumulative Pollutant Loading Limit (Ibs/acre) 36.57 34.79 2676 1338 267.6 15.16 16.06 374.64 89.2 2497.6
(SIGNATURE OF LAND APPLIER) DATE
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Monday, January 17, 2000

CERTIFICATION STATEMENT
per August 4, 1999 Federal Register/Vol. 64, No. 149
Preparer Certification Statement per 40 CFR 503.17(a)(4)(i)(B)
Subject to Table 3, not necessary to keep up with Cumulative Loadings (a)(4)(ii).
Project: Cleveland, NC
Time Period: 1999
I certify, under penalty of law, that the information that will be used to determine
compliance with the Class B pathogen requirements in 503.32(b) and the vector
attraction reduction requirement in 503.33(b)(4)were prepared under my direction
and supervision in accordance with the system designed to ensure that qualified
personnel properly gather and evaluate this information. I am aware that there are
significant penalties for false certification including the possibility of fine and
imprisonment. -
Preparer Signature GL

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM
Facility Name Town of Cleveland, NC
WWTP Name Town of Cleveland WWTP NPDES # NC0049867
Monitoring Period: From 1-1-99 To 12-31-99
Pathogen Reduction (40CFR 503.32) - Please indicate level achieved and alternative performed
Class A
Alternative I Alternative 2 Alternative 3
Alternative 4 Alternative 5 Alternative 6
Class B I( -
Alternative 1 ✓ Alternative 2 Alternative 3
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens";
Aerobic Dig. Air Dry Anaerobic Dig. Compost Lime Stab.
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Parameter
Allowable
Pathogen Densi
No. of
Freq. of
Sample
.Analytical
Level in
Exceed
Analysis
Type
Tech.
Sludge
Min. Geo. Max. Units
Mean
Fecal
2x 10
MPN
Coliform
MPN/g or
2xl06
20,000
42134
150000
CFU
0
Annual
Grab
9222D
CFU/g
1000
MPN
MPN/g
Salmonella
3 MPN/
bacteria
4 g
Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed
Option 1 Option 2 Option 3 Option 4 ✓ Option 5
Option 6 Option 7 Option 8 Option 9 Option 10
No vector attraction options were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
If "I certify, under penalty of law, that the CPR
requirements in 40 CFR 503.32 and the vector
attraction reduction requirement in 40 CFR 503.33 have been met."
"I certify, under penalty of law that the pathogen requirements In 40 CFR 503.32 and the vector attraction
reduction requirement in 40 CVR 503.33have not been met. (Please note if you check this statement
attach an explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to
ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and
vector attraction reduction requirements have been met. I am aware that there are significant penalties }or false
certification including fine and imprisonment."
David J. Wanucha Synagro Southeast, Inc.
Pre arer Name and Title Land Applier Name and Title (if applicable)
Signature of greparer Date Signature of Land Applier (if applicable) Date

May 12, 1999
CLIENT NAME
CLIENT NUMBER
SAMPLE NUMBER
COLLECTED DATE
RECEIVED DATE
DESCRIPTION
TEST
% SOLIDS
FECALSLUDGE
..,S.O`.0 R._�
TOTAL SOLIDS
CERTIFICATION #
CERTIFIED BY:
I$YDR0 ANALYTICAL LABORATORIES
6300 Ramada Drive, Box C-2
Clemmons, NC 27012
[phone]
Fax [phone]
CERTIFICATE OF ANALYSIS
EWR I CLEVELAND
(f�
800943
170418
170419
170420
170421
170422
170423
170424
170425
4/22/99
4/22/99
4122/99
4122/99
4/22/99
4122/99
4/22199
4122199
4/22/99
4122/99
4122/99
4122/99
4/22/99
4/22/99
4/22/99
4/22199
SLUDGE
SLUDGE
SLUDGE
SLUDGE
SLUDGE
SLUDGE
SLUDGE
SLUDGE
UNITS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS RESULTS
#/G RAM
MG/L� 18740
NC 103
C 37733
.1
3 2 2 3 2 2 2
26,667 20,000 40,000 56,667 150,000 20,000 65,000

M
Time
(minutes)
0
1
2
3
4
5.
6
7
`8
()
11
12
13
14
15
Specific Oxygen Uptake Rate
SOUR
Facility Name:
Biosolids Permit Number:
Digester Temperature:
Sampling Date/Time:
Sampled By:
Analysis Date/Time:
Analyzed By:
Sample Volume:
Total Solids:
Beginning Temperature:
End Temperature:
Dissolved Oxygen Level
(mg/1)
Slope:
Intercept:
milliliters
% Dry Solids
degrees Celsius
degrees Celsius .
14
.
an, =
=a�,o
.014 logo
Correlation Coefficient:
Oxygen Uptake Rate4t24,I gv4,Q mg Oxygen/L/Hr
Ambient Specific Oxygen'Uptake Rate: , a mg Oxygen/g/hr
Average Temperature: degrees Celsius
Temperature Correction Factor: �Q
Temperature Corrected Specific Oxygen .Uptake Rate:Lf 1mg Oxygen/g/hr
Instructions: Enter Data In the,Blue Boxes. The Calculation and the Spreadsheet execute automatically.

H.
7
11 Al
roml
Oxygen Uptake Rate Chad
-n
NONE
"low
EYtk
n
.....
'N"
REM-_
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kk
RM
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M MI1.
MI, MI,
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-gg
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♦
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oil
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10,
low
IN
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MENEM
..................
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I I I I I 111111111
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I ............ k,
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. . . . . . . . . . . . . . .
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so
km
wmwi"
k
'M�kn"knk'
-•
-MOM=
,Ekt„
NOm•
"IX,
2
4
6 7 8 9 10 11 12 13 .14 15 16
Time (minutes)

FILE NAME: 5C IAIN2 (12-27-94)
HYDRO ANALYTICAL
6300 RAMADA DRIVE
CLEMMONS, NC 27012
CHAIN OF . CUSTODY RECORD;
REGULATORY CLASSIFICATION
TELEPHONE [phone] • FAX [phone]
❑ PRETREATMENT ❑ NPDES ❑ DRINKING WATER ❑ OTHER
PROJECT NO
CLIENT NAME
c
U
~
a ,
i
REQUESTED PARAMETERS
REMARKS/
PRESERVATION
�� _
S PLERS: (SIGNATURE)
(PRINT)
LAB
SAMPLE
DATE
1111E
LOCATION
,,af�tt
25
Io qS
1 J �
(
1.,14
HN0342 HX4<2 Nsaw12 H=
HC1Q NaeS,O, Omer
��1
b
HNO,d HZSO,Q NaCf612 None
H01Q Na -,A Omer
�f
1
O
Oct
�
HNO;Q HX.Q NaOH>12 None
MC 2 NgAA Omer
2,1
0 O dc
HNO,Q H?SO,Q NCH>12 Nine
M<2 NNSA Omer
Z L •
/
0
HN%<2 HzSO,Q NdXf 12 Nano
HC1Q NazSA. Omer
Co
HNO,Q HzSO,Q Na04i>12 Now
HClQ- - NarSA Omer
o�
v
IHM42
HNO,Q H,SO,Q NaOH>12 Nano
H01Q NazSA Omer
HNO,Q HX,<2 NaCH>12 Nano
HM<2 NayzSA Omar
WA<2 HX,Q NaOH>12 Nano
HC1Q NarS,O, Omer
HNO,Q HzSO,<2 Nd>-b12 Now
N%SA Cow
RELINQ ISHED BY: (SIGNATURE)
DATE
TIME
R EIVED BY:
DATE
11ME
LAB USE ONLY
SAMPLES < 4'C: Yln
SAMPLES PRESERVED: 1�
HOLDING TIME:
CHLORINE:
1.
'
1
2.
LAB REMARKS:
>
CHECKED BY: tile-
f'flCTnnV CCAi .

Town of Cleveland, NC
1999 Summary
Soil pH and Lime Applications
Landowner
Field #
I Acres
pH*
I Tons/ac
Garnet Doby
2-1
42.5
6.3
-
* Lime has been ordered, applications on some fields will occur as weather and field conditions allow.

NCDAA ron Division
4300 Reedy Creek Road Raleigh, NC 27607-6465 9) 733-2655
ReportN( 721
uiozver:
Garnet, Dolly
Copies to: Amsco, Inc.
'
1630 Baker Mill Rd.
Cleveland, NC 27013
SoilTestReport
Parzn: Z
Ams
Attu: ,Inc.
Attn: David Wanucha
�
PO Box 1770
8/23/99 SERVING N.C. CITIZENS FOR OVER 50 YEARS
Rowan County
Clenunons NC 27012
Agronomist Comments:
Field Information
Lime
Recommendations
—Applied
Sample No. bast Crop
Mo Yr I'li1
Crop or Year blaze N
h05 K,0 Mg Crc
Zn B Nil See Note
O1 Fes/0G/1'im,M
1st Crop: Fes/0G/I'im,M 0 120-200
110-130 0-20 0 0
0 0 12
2nd Crop:
'Pest Results
Soil Class HM% W/V CEC BS%
Ac pH P-I K-I Ca% Mg% Mn-I Mn-AI (1) Mn-AI (2) Zn-I Zn-AI
Cu-I S-1 SS-1 NO3-N NHt-N Na
MIN 0.46 1.17 11.7 91.0
1.1 6.3 10 72 70.0 18.0 1024
627 119 119
135 52 0.1
RE C V E 0
AUG 2 3 iggq