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HomeMy WebLinkAboutNC0024392_Regional Office Historical File Pre 2018 (12)Duke Energy Carolinas LLC McGuire Nuclear Station 12700 Hagem Feny Road Huntersville, NC 28078 November 13, 2017 Mr. Wes Bell North Carolina Department of Environmental Quality 610 East Center Avenue Suite 301 Mooresville, NC 28115 Subj ect: Five Day Written Follow-up Notification of Oil Spill to Ground McGuire Nuclear Station Dear Mr. Bell: This correspondence serves as the five day written follow up notification of the oil release at McGuire Nuclear that was reported to you by phone on November 8, 2017. This release was due to a transformer fire due to a component failure at the McGuire Switchyard and subsequent firefighting efforts. The transformer contained a total of 16,133 gallons of transformer oil, HyVolt 11. A conservative estimate of half of the transformer oil, approximately 8,000 gallons, was reported as spilled to the ground due to the initial fault and equipment failure. A majority of the oil was routed to an oil and water separator through a series of drainage trenches as designed, Oil and firefighting foam also flowed to four nearby stormwater drains that were routed to two stormwater outfalls SW006 and SW037. Gravel coffer dams, oil absorbent boom, and oil pads have been placed at these outfalls. The firefighting foam initially overwhelmed the oil and water separator and a discharge of firefighting foam was released through stormwater outfall SWO14 and SW024. We believe the small amount of oil we observed in the adjacent wetland area and subsequently reported to the National Response Center of less than one pint was carried by this firefighting foam. The observed oil in the wetland area was absorbed by an oil pad and removed. No subsequent sheen has been observed in the area. Storm drains are currently undergoing high volume flushes to remove any residual oil. Vacuum trucks continue to work to remove any residual oily water mixture as well as clean out the oil and water separator. Within the switchyard, the gravel area surrounding the transformer is currently being excavated.. An area of approximately 3,000 square feet and 6-8 inches deep is being removed. The majority of the oil near the transformer was absorbed by a layer of carbon beneath the gravel that was pert of the original switchyard design and has been removed as well. n area of approximately 2,000 square feet beyond the convergence point of outfall SWO06 and SW037 will also be remediated. There is currently are earthen coffer dam with an 3 inch corrugated dewatering pipe with a raised midsection surrounded by oil absorbent boom and pads preventing further oily water migration. Contractors with vacuum trucks are continuing to remove water from this area. We should begin removing contaminated soil this week after we have completed flushing the upstream switchyard trenches and storm drains. All contaminated material will be properly disposed of via certified contractors. If you have any questions concerning this report, please contact Macrae Walters by phone at (80) 75-5 35 or by email at Macrae.Walters@nuke-Energy.com. Or, you can contact John Williamson at (3g) 375-5394 or by email at John.Williamson@Duke- Energy.com. Sincerely; Steven D. Capps Site Vice President Duke Energy Carolinas, t_LC McGuire Nuclear Station cc: Stove Snider Melanie Gardner John Williamson John Ballard Shannon Todd Cyndi Winston Kitty Na pan Mark Pritchard' L.C. Williams rt .i# "`# # i i # # °` • i '" #"` s � A## # .. .r • #i i i # i «i- :.. ., �... . .. #. ! " # i ; # # "` , it # • # ... i # # : # # ,,.. .. - ,.. i two -• i - • # •-# # # .i a #- ##i .. i •.s # _ - i .. # _ _, NIPPO -# - • #i##- i i# •# # -• # # vy cfIICIII Qt VVIett.vvIuIaosuaveo%'w,vufxc-L-jIVIsJY.L'viIt„ Sincerely, Brae B. Walters Sr. ENS Professional I McGuire Nuclear Station Office 980.875.5635 Celli704.641.8972 1 700 Hagers Ferry Rd (MG01 EM) Hunt rsuille, NC 28078 macr e. a9 rs d ake-ever r.com J106 DUKE V ENERGY., Please s onsic r the environment before printing this email, 2 VIWEnaclin Ref ining, Irw. SAFETY DATA SHEET 1.Identification Product identifier HYVOR II Tither means of identification Not available. Recommended use Transformer Oil Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer: Ergon Refining Address: 2611 Haining Rd" Vicksburg, Mississippi 3918 E-Mail. sds@ergon.com " Emergency Contacts Ergon Refining 1.601.638,4 60 Normal Business Hours Chemt : 1.800.424.9300 After Business Hours (North America Only) 1.703.527.3887 After Business Hours (International) . Hazard(s) identification Physical hazards Not classified. Health hazards Aspiration hazard Category Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement May be fatal if swallowed and enters airways. Prevention Do not breathe gas/mist/vapors/spray. Response IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Storage Store locked up. Disposal Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. See section 13 of this`SDS for disposal instructions: Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/ information on ingredients Mixtures Chemical name Common name and synonyms CAS number % DISTILLATES (PETROLEUM), 6442-53-6 40 - 99. HYDR{TREATED LIGHT NAPHHENI DISTILLATES (PETROLEUM), 64742-55-8 0 - 5 HYDROTREATED LIGHT PARAFFINIC DISTILLATES (PETROLEUM), 64742-56_ - 20 SOLVENT-DEWAXED LIGHT PARAFFINIC �m co ns to u udiing any mp lincompatt 8. r safe storage, Store locked up. Keep away from heat, sparks and open flame. Store in a well -ventilated place. Use care in handling/storage. Ities controls/ personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 C1FR 1910.1000) Components Type Value Form DISTILLATES PEL 5 mg/m3 mist (PETROLEUM), HYDROTREATED LIGHT NAPHTHENIC(CAS 64742-53-6) DISTILLATES PEL 5 mg/m3 mist. (PETROLEUM), HYDROTREATED LIGHT PARAFFINIC (CAS 64742-55-8) DISTILLATES PEL 5 mg/m3 mist. (PETROLEUM), SOLVENT-DEWAXED LIGHT PARAFFINIC (CAS 64742-56-9) US. ACGIH Threshold Limit Values Components Type Value Form 2,6-DI-TERT-BUTYL-P-CRES TWA 2 mg/m3 Inhalable fraction and OL[BUTYLATED vapor. HYDROXYTOLUENE(BHT)] (CAS 128-37-0) US. NIOSH- Pocket Guide to Chemical Hazards Material Type Value Form HyVolt II (CAS Mixture) STEL 10 mg/m3 Mist. TWA 5 mg/m3 mist. Components Type Value Form 2,6-DI-TERT-BUTYL-P-CRES TWA 10 mg/m3 OL[BUTYLATEO HYDROXYTOLUENE(BHT)l (CAS 128-37-0) DISTILLATES STEL 10 mg/m3 Mist, (PETROLEUM), HYDROTREATED LIGHT NAPHTHENIC (CAS 64742-53-6) TWA 5 mg/m3 mist. DISTILLATES STEL 10 mg/m3 mist. (PETROLEUM), HYDROTREATED LIGHT PARAFFINIC (CAS 64742-55-8) TWA 5 mg/m3 mist. DISTILLATES STEL 10 mg/m3 mist. (PETROLEUM), SOLVENT-DEWAXED LIGHT PARAFFINIC (CAS 64742-56-9) TWA 5 rng/m3 mist. Biological limit values No biological exposure limits noted for the ingredient(s), Appropetate engineering Provide adequate ventilation, including appropriate local extraction, to ensure that the defined controls occupational exposure limit is not exceeded. Individual protection measures, such as personal protective equipment Eye/face protection Goggles/face shield are recommended. Hand protection Chemical resistant gloves are recommended, If contact with forearms is likely wear gauntlet style gloves. Other ChemicaVoil resistant clothing is recommended. Launder contaminated clothing before reuse. ww sws• w� s • w- a- w• w w w • w °w E w r _w ws. w ►� Clear & bright tote Liquid. Liquid. Water White to Pale Mild Petroleum Odor d Not available. Not applicable (freezing paint < -40 OF (< -40 °C) ASTM D 5950 paint and > 40 OF (> 237.78 °C) ATM U 2887/ ISO 3294 >= 293.0 OF (>= 145.0 °C) Cleveland Open Cup ATM D 92/ ISO 2592 ate Not available. (sand, gas) Not available. Nammability or explosive limits city limit - lower Not available, lity limit - Not available. ) limit - lower Not available, limit - upper Not available. V Not available. Not available. ity 0.8 (59 OF ( °C) ASTM la 4052/,ISO 1218 ) i` (water) Insoluble cient Not established. Ater) temperature > 599 OF (> 315 11C) ASTM F 65 n temperature Not available. 9.3 cSt (104 OF (40 °C) ASTM 6 445) The product is stable and non -reactive under normal conditions or use, sto Stable. as Hazardous polymerization does not occur. Heat, flames and sparks. Avoid temperatures exceeding the flash point. Is Strong oxidizing agents. Lion Upon decomposition, this product emits carbon monoxide, carbon dioxide d weight hydrocarbons. information routes of exposure dry the skin, leading to discorr e eta Add NEE`' ptos re physical, the texicolo i I tact May b irritating to eyes. lsted t the Defatting of the skin. Coughing. Shortness of breath. Discomfort in the chest. mical and characteristics Information on toxicological effects Acute toxicity Not; applicable. Components Species Test Results 2,6-DI-T RT-BUTYL-P-CRESOL [iBUTYLATED HYDRt OLUENE (BHT)] (CAS 128-37-0) Acute oral LD50 Guinea pig 10700 mg/kg Mouse 100 mg/kg Rat 890 mg/kg Not available. * Estimates for product may be based on additional component data not shown. Skin corrosion/ irritation May cause defatting of the skin, but is neither an irritant nor a sensitizer. Serious eye damage/eye Not classified. May cause minor irritation on eye contact. irritation Respiratory or skin sensitization Respiratory sensitization Not classified. Skin sensitization Not classified. May cause defatting of the skin, but is neither an irritant nor a sensitizer. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Nota L - Meets EU requirement of less than 3% ( /w) DMSQ extract for total polycyclic aromatic compound (PAC) using IP 346. Not classified. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Contains no ingredient listed as toxic to reproduction Specific target organ toxicity Not classified. - single exposure Specific target organ toxicity Not classified. repeated exposure ` Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. Further information Risk of chemical pneumonia after aspiration. . Ecological information EcotoxicitV Not expected to be harmful to aquatic organisms: Product Species Test Results HyVolt II (CAS Mixture) rustaca EC50 Daphnia 863.822 mg/l,; 48 hours estimated Components Species Test Results 2,6-DI-TERT-BUTYL-P-CRESOL [BU'T'YLAT D HYDRO OLUENE (BHT)] (CAS 12 -37-0) Aquatic Crustacea EC50 Water flea (Daphnia pulex) 1.44 m /l, 48 hours Not available. * Estimates for product may be based on additional component data not shown. Persistence and degradability Not inherently biodegradable. loaccu ulative potential Bioaccumulation is unlikely to be significant because of the low water solubility of this product. Mobility in soil Not available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. ate e t regulations This product does not contain a chemical known to the State of California to cause cancer, birth F defects or other reproductive harm. California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. S. Massachusetts RTX - Substance List Not regulated. US. New 3ersey Worker and Community Right -to -Know Act Not regulated. US. Pennsylvania RTK - Hazardous Substances Not regulated. US. Rhode Island RTK Not regulated. US. California Proposition 65 Not Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)" Australia Australian Inventory of Chemical Substances (AILS) Yes Canada Domestic Substances List (DSQ Yes Canada Non -Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Substances Yes (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PIGS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates that all tom onents of this product comply with the inventory requirements administered by the governing country(s) Issue date 01-1, Revision date 03-0; Version # 06 References ACGI EPA, NL� US. I IARC Natio ACGI Cheri CRC: ILO c Inter Inter NFPA NIOS Regis US D Disclaimer The i infon guid2 to be mate mate late of preparation or last revision lals or in any process, unless specified in the text. Haut Dreovitch KESenior Vice President Environmental, Health Safety 525 S. Church Street Mail Code: E 3XP` Charlotte, NC 28202 (9 0)«373-04t 8 August 4, 2017 Mr. Jeff Poupart, Section Chief NC Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699u-117 Subject: Owner Affiliation and Facility Contacts for North Carolina NPDES Correspondence Duke Energy NPDES Permitted Facilities Dear Mr. Poupart. As discussed with you by Richard Baker and Shannon Langley on July 5, 2€717, Duke Energy has recently noted an increased number of documents and correspondence from your agency being directed to the attention of incorrect staff persons for our NPDES permitted facilities. A few recent examples include the annual NPDES inspection report for the Mayo Steam Station and a Notice of Violation for the Cape Fear plant being sent to the Vice President of Harris Nuclear Plant; as well as correspondence for the Allen Steam Station sent to the South Carolina Director of Environmental Policy. In each case, this has led to delays in the permitted facility receiving information and impacts our ability to provide time sensitive responses to the Department of Environmental Quality (DEQ). Duke staff have discussed this situation with DEC€, staff in the central and various regional offices. Based on our conversations and a review of information captured in your RIMS system, we believe the best< way to address this is with the following included information: 1. A single name/ownership change farm to request that the "owner affiliation" for entities Duke Energy Progress, LLC (DEP) and Duke Energy Carolinas, LLC (DEC) be updated with my contact information. There appear to be numerous obsolete contacts listed as "owner contact persons" in your RIMS database- that field can be updated to include my name and the Gathers removed. 2. The "permit billing contact person" should be updated for all facilities to name Cynthia Winston, Manager, 410 S. Wilmington Street, NCRH'15, Raleigh NC 27601 She can be reached at (919)56-553 and cnthia.insto duke-enerv.com. 3. The "facility contact person" for each facility should reflect the Station Manager at the site. A list of current Station Managers for all DEP and DEC facilities is attached to this correspondence. 4. The fields for `"permit contact person" and "persons with signatory authority" have been recently updated as part of the e-dmr registration process and appear accurate as of this time. Based on this information, I would envision that general correspondence applicable to more than one Duke Energy facility, such as groundwater information or other programmatic issues, should be directed Mr. Jeff Poupart August 4, 2017 to my attention, while station specific communication should be directed to the Station Manager for the site, Duke Energy will continue to routinely update the DEQ in a timely manner when facility contacts change. If you think it would be helpful, we would be available to meet with your staff to discuss the best way to assure accurate delivery of correspondence, We are providing copies of this letter to each of the regional office supervisors responsible for NPDES permit oversight. If there are any questions relating to this request please contact Anne Pifer at (980)-373-1609 or at anne.giferC@duke-energy.com. Sincer; y, P I Draovitch Senior Vice President Duke Energy Environment Health and Safety Attachments Cc; Bob Sledge/NCDEQ Jim Gregson/NC DEQ WiRO 1617 Mail Service Center 127 Cardinal Drive Ext. Raleigh, NC 27699-617 Wilmington, NC 28405 Landon Davidson/NCDEQ ARO Sherri Knight/ CDEQ WSRO 2090 US Highway 70 450 West Hanes Mill Rd, Suite 300 Swannanoa, NC 28778 Winston-Salem, NC 27105 David May/NC DEQ, WaRO Trent Allen/NC DEQ FRO 943 Washington Square Mall 225 Green Street, Suite 714 Washington, NC 27889 Fayetteville, NC 28301-5095 Corey Basinger/NC DEQ M O Danny Smith/NC DEQ RRO 610 East Center Ave; Suite 301 1628 Mail Service Center Mooresville, NC 28115 Raleigh, NC 2799-168 Bethany Georgoulias Stormwater Program, NCDEQ/ DEMLR 1612'Mail Service Center, Raleigh, NC 2799-1612 Anne Pifer/Duke Energy FileNet NPUES Stormwater NPAES Wastewater General Owner Name Facility Name Station Type Permit Number Permit Number Permit Facility Contact Facility Contact Address No., Duke Energy Carolinas, LLC Allen coal NCS000546 NCO 979 Brent Dueitt, Station Manager 253 PLANT ALLEN RD, BELONT NC 28012 Duke Energy Progress, LLC ..... __...� _.... Asheville ._ _ . Coal/CC - _.. _..._......,._ . NCS000575 NCO00,396 N ._ ....._ .:.. . . , .. — ____ ....�.... ., Ste Garry A. hlsnant, Station Manager - . ... .. _na 200 CF$ L DRIVE, ASH£VILL£ NC 2871}4 0 CP ILL 2 Duke Energy Carolinas, LLC Bear Creek Hydra NCG500124 . Preston H. Pierce, General Manager ...... . W.vC 165 BAD CREEK RO, SALEM SC 29676 Duke Energy Carolinas, LLC Belews Creek Coal NCS000573NCO024406JNCG�50(01129 af D. Anderson, Station Manager _ 3195 PINE HALL ROAD, BELEWS CREEK NC 27009 Duke Energy Progress, LLC Blewett Falls Hydro ael T. Brissfe, General Manager 257 DUKE LANE, STANLEY NO 28164 Duke Energy Carolinas, LLC Bridgewater Hydra ael T. Brissie, General Manager 257 DUKE LANE, STANLEY NC 28164 Duke Energy Progress LLC Brunswick Nuclear NCS000590 NCO007064m R. Gideon, Site VP 8470 RIVER RD. S€, SOUTHPORT NC 28461 Duke Energy Carolinas LLC Bryson Hydro on H. Pierce, General Manager 165 BAD CREEK RD, SALEM SC 29676 Duke Energy Carolinas, LLC Buck Coal/CT NCO004774 A. Botkins, Station Manager 1385 I UKEVILLE ROAD, SALISBURY NC 28146 Duke Energy Progress, LLC Cape Fear Coal/Cl, NCS000574 " NCO003433 Issa 1. Zarxar, Station Manager 411 FAYETTEVILEL STREET, RALEEIH NC 27601 Duke Energy Carolinas, LLC Cedar Cliff Hydro NCG500125 Preston H. Pierce, General Manager 165 BAD CREEK Rio, SALEM SC 29676 Duke Energy Carolinas, LLC Cliffside : Coat. NCS000571 NCO005088 Dave Barnhardt, Station Manager 573 DUKE POWE ROAD, MOOR£SBORO NC 28114 Duke Energy Carolinas, LLC Cowans Ford Hydros NC500139 Michael "f. Brissie, General Manager " 257 DUKE LANE, STANLEY NC 28164 Duke Energy Carolinas, LLC Dan River Coal/CT NCS000572 N00003468 Lawrence D. Sparks, Station Manager 864 5 EDGEWOOD RD, EDEN NO 27288 Duke Energy Progress, LLC Harris/HEEC Nuclear NCO039586 Benjamin C. Waldrop, Site VP 400 S TRYON ST, CHARLOTTE NC 29202 Duke Energy Progress, LLC Lee/Wayne County Coal/CC NCO003417 Jeffery D. Hines, Station Manager 1199 BLACK JACK CHURCH RD, GOLDSBORO NC 27530 Duke Energy Carolinas, LLC Uncofn CT NCO080781 Henry A Sotklr s, Station Manager 1385 DUKEVILLE ROAD, SALISBURY NC 28146 Duke Energy Carolinas, LLC Lookout Shoals Hydra NCG500120 Michael T. Br'rssie, General Manager 257 DUKE LANE, STANLEY NC 28154 Duke Energy Progress, LLC Marshall Hydra NCG500591 Preston H, Pierce General Manager 165 HAD CREEK RD, SALEM SC 29676 Duke Energy Carolinas LLC _ .. _ Marshall _ Coal' NCS000548 : NCO004987 _._.... . _..._ �_ m._. Rick R. Roper, Station Manager 8320 EAST NC HWY 150, TERRELL NC28682 Duke Energy Progress LLC Mayo Coal NCS000580 NCO038377 __.-- -------- Tom Couple, Station Manager 10660 BOSTON ROAD, ROXBORO NO 27574 Duke Energy Carolinas, LLC McGuire Nuclear NC5000020 NCO024392 Steven D. Capps, Site VP 12700 HAGERS FERRY RD, HUNTERSVILLE NO 28087 Duke Energy Carolinas, LLC Mission Hydro NCG500128 Preston H. Pierce., General Manager 16S BAD CREEK RD, SALEM SC 29676 Duke Energy Carolinas, LLC Mountain: Island Hydro NCG500131 Michael T. Brassie, General Manager 257 DUKE CANE, STANLEY NC 28164 Duke Energy Carolinas, LLC Nantahala Hydro NCG500136 _ Preston H. Pierce, General Manager 16S BAD CREEK RD, SALEM SC 29676 puke £hergy Carolinas, LLC _. : Oxfprd _. i-fydrii NCGS00119 Michael T. Brlssle, General Manager 257 DUKE LANE, STANLEY NO 28164 Duke Energy Carolinas, LLC Rhodhiss Hydra NCGSO0108 .__._.. Michael T, Brissie, General Manager 257 DUKE LANE, STANLEY NC 28164 Duke Energy Progress„ LLC Richmond County CC NCG500594 Thomas Hanes, Station Manager 198 ENERGY WAY,HAMLET NC 28345 Duke Energy Carolinas, LLC Riverbend Coal/CT NC5000549 NCO004961 Tim Hill, Station Manager 400 S TRYON ST, CHARLOTTE NC 28202 Duke Energy Carolinas, LLC Rnckingham Cr NCO086665 Lawrence 0, Sparks, Station Manager 864 S EDGEWOOD RD, EDEN NC 27288 Duke Energy Progress, LLC Roxboro Coat NCS000 81 NCO003425 Jason V. Haynes, Station Manager 1700 DUNNAWAY'ROAD, SEMORA NC 27343 Duke Energy Progress, LLC Sutton Coal/CT NCO001422 Jesse E. Huntley, Station Manager 801 SUTTON STEAM PLANT RD, WILMINGTON NC 28401 Duke Energy Carolinas, LLC Tennessee Creek. Hydro NCG500123 Preston H. Pierce, General Manager 165 BAD CREEK RD, SALEM SC 29676 Duke Energy Carolinas, LLC Thorpe Hydro NCG500127 Preston H. Piercer General Manager 165 BAD CREEK RD, SALEM SC 29676 Duke Energy Progress, LLC Tillery Hydra NCG500189 Michael T, Brassie, General Manager 257 DUKE LANE, STANLEY NC 28164 Duke Energy Carolinas, LLC Tuskasegee Hydro NCG500126 Preston H. Pierce, General Manager 165 BAD CREEK RD, SALEM SC 29676 Duke Energy Carolinas, LLC ITuxedc, Hydro NCGS0GI10 Michael T. Brassie, General Manager 257 DUKE LANE, STANLEY NC 28164 Duke Energy Progress, LLC :Waiters Hydro NCGS00188 Preston H, Pierce„ General Manager 165 BAD CREEK RD, SALEM SC 29676 Duke Energy Progress, LLC Weatherspoon Coal/ CT NC5004589 NC0005363 : Thomas Hanes, Station Manager 198 ENERGY WAY, HAMLET PIC 28345 ROY COOPER MICHAEL S, REGAN S. JAY ZIMMRMAN PERMIT NAMEIOWNERSHIP CHANGE FORM 1. CURRENT PERMIT INFORMATION: Permit Number: NCOO / / / / ` or NCG5 / / / / 1. Facility Name. All Duke Energy Progress LLC and Duke Energy Carolinas LLC 11. NEW OWNERINAME INFORMATION: 1. This request for a name change is a result of: a. Change in ownership of property/company b. Name change only X C. Other (please explain): owner Affiliation contact person . New owner's name (name to be put on permit): No change to permit holder 3. New owner's or signing official's name and title: Paul DraoVltch, P.E. (Person legally responsible for permit) Senior Vice President, EN&S (Title) 4. Mailing address: 526 South Church Street -ECP city: Charlotte State: Zip Code,2�2Q2 Phone: ( ) 0-37 -U U E-mailaddress: Paul.araovitch@duke-energy.com THIS APPLICATION PACKAGE WILL NOT BE ACCEPTED BY THE DIVISION UNLESS ALL OF THE APPLICABLE ITEMS LISTED BELOW ARE INCLUDED WITH THE SUBMITTAL. REQUIRED ITEMS: 1. This completed application form 2. Legal documentation of the transfer of ownership (such as a property deed, articles of incorporation, or sales agreement) [see reverse side of this page for signature requirements] State of No th Carolina I Environmental Quality I Water Resources 1617 Mail Service Center I Raleigh, NC. 7699-1617 919 80 6300 919-807-6389 VAX latips://deq.nc.8ov/abotrt/divisions/water-resources/water-resotarces-peraaaitslavasteayster-braasach/jipdes-wastewatt r-pe;rmits oppr NPDES Name & ownership Change Page 2 of 2 Applicant's Certification.` 1 Paul Drelovitch , attest that this application for a name/ownership change has been reviewed and is accurate and complete to the best of m knowledge. I understand that if all required parts of this application are not completed and that if all required su orting information and attachments are not included, this application package wil ere rite a ornplet. Signature: �`"`W Date: THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION & MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDDRESS; NC DEQ I DWR I NP E 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Version 71201 Edell, Wes F Walters, Macrae Burris <Macrae. alters ci -cn rg r.co Sent: Tuesday, May 28, 2017 8:42 A To: Bell, Wes Cc: Williamson, John C Ballard, John G; Bynum, Pete Subject: Shade Treatment on the WWCB at MNS Good morning, Mr. Bell We are going to perform a shade treatment of the WWC;B (wastewater collection basin) at MINIS today using one of the two previously approved black dyes. We will be using the Black Onyx this time as opposed to the mystic black we used last time. We will be dosing at the previously approved levels as well. This is one of our measures to control pH and algae growth for the WW B that discharges to outfall 005. We do not anticipate any overflow to the river at this time as there is no rain in the forecast until the weekend but an unforecasted rain event could cause some overflow. Please let me know if you have any additional questions. Macrae B. Walters r. EHS Professional I McGuire Nuclear Station Office 980.875.58 51 Cell 704.841.8972 12700 Hagers Ferry Rd (MG01 M) Huntersville, NC; 28078 macrae.walters duke -ever com fDUKE en ENERGY* Tease consider the environment before printing this email, Belt, Wes From Walters, Macrae Burris <Macrae.Walters@duke-energy.com> Sent. Saturday, March 11, 2017 3:27 P To: Bell, Wes Cc: Williamson, John C Subject: MNS WWCB Dye Treatment Monday Good afternoon, Wes. I called on Thursday, but as you were in the field, I wanted to follow up via email. We will be treating the WB at MNS with the dye you all approved last year at the same concentration. We have this scheduled for Monday as we are trying to get ahead of any early blooms. We are keeping the level of the WWCB low to try to avoid any overflow from minor rain events. Please let me know if you have any questions or concerns. Thanks and have a great weekend! Macrae B. Walters Sr. ENS Professional I McGuire Nuclear Station Office 980.875.5635 1 Cell 704.641.897 12700 Hagers Ferry Rd (MG01 EM) Huntersville NC 28078 macrae.walters aduke-enerv.com 1(04� DUKE Tvp ENERGY. 'tease consider the environment before printing this email, Division of Water Resources December 9, 2016 To: Corey Basinger Water QualityRegional Operations, MRO Through: Cindy A. Moore Supervisor, Aquatic Toxicology Branch (ATB) From: CarollEollen p Quality Assurance 0 1cerr, Aquatic Toxicology Branch (ATB Subject: Whole effluent toxicity test results Duke Energy McGuire ICES Pennit # NCO024392/005 Mecklenburg County The aquatic toxicity test using grab samples of effluent discharged from the Duke Energy McGuire facility has been completed. This facility has a permitted effluent discharge entering the Catawba River (7Q10 of 80 CF . Whole effluent samples were collected sn. November 15 and November 17 by Wes Bell and facility representative Michael Macsay for use in a chronic C riodaphn a dubia pass -fail toxicity test. This test passed, 'Toxicity test information follows. Test Type 3-Brood Ceriodaphnia dubia chronic pass fail Test Concentrations 2.9% TestResult Pass Control Survival 100 Control Mean Reproduction 27.0 neonates Test Treatment Survival % Treatment Mean Reproduction 25.4 neonates First Sample pH 7.22 Sf First Sample Conductivity 76.5 micromhos/cm Fiat Sample Total Residual Chlorine <0.10 mg1L Second Sample pH 7,35 SLi Second Sample Conductivity 1 .8 cro h os/c in Second Sample 'Total Residual Chlorine <tl. 10 mg/ Test results for the above samples indicate that the effluent would not be predicted to have water quality impacts. Please contact us if you have any questions or if further effluent toxicity monitoring is desired. We may be reached at (19) 743-8401. Basin: CTB33 cc:Central Files Wes Bell (MRO) Aquatic Toxicologv Branch Water Sciencev Section Division of Water Resources December 9, 2016 ,�M AMUM To: Carey l asinger" Water Quality Regional Supervisor, MRO Througb: Cindy A. Moore Supervisor, Aquatic 'Toxicology Branch From: Carol Hollenk ` p Quality Assurance > cer, Aquatic Toxicology Branch Subject. Whole effluent toxicity test results Duke energy McGuire D S Permit # NCO024392/002 Mecklenburg County The aquatic toxicity test using a grab sample of effluent discharged from the Duke Energy McGuire {lilt has been completed. Duke Energy McGuire 0 has a permitted discharge to the Catawba River (7Q10 of 80 CTS). A whole effluent sample was collected on November 3rd!by Wes Bell for use in an acute 48-hr Ceriodaphni dubia full -range toxicity test. The test resulted in a pass. Toxicity test information follows. Test Type Acute 48 hour Ceriodaphnia da to full -range Test Concentrations 16, 32, 64, 2, 14% Test Result Pass LCSti 100%; LC50 must be 80% for a pass) Control Survival 100% "Test Treatment Survival 100% Sample pH 7.69 SU Sample Conductivity 106.1 a i romhoste Sample Total Residual Chlorine <0. 10 mg11r Results for the above sample indicate that the effluent would not be predicted to have water quality impacts on receiving water. These samples were split with ETS Inc. The test conducted by ITS Inc. also passed Please contact us if you have any questions or if lbrther effluent toxicity monitoring is desired. We may be reached. at (919) 74 -8401. Basin: CTB3 cc: Central Piles Wes Bell, MRO Fr" From. Hollenkamp Carol Sent: Friday, December 09, 2016 2:44 PM To: Basinger, Carey Cc: Bell, Wes Subject: Corrected Toxicity Test reports for Duke Energy McGuire 002 and 005 Attachments: Duke Energy McGuire 002�1116.pdf; Duke Energy McGuire 005_1116.pdf Attached are corrected toxicity test reports for Duke Energy McGuire outfalls 002 and 005. These facilities do not have flow limits, as was incorrectly stated on the previous toxicity test reports dated December 61 and 51, respectively. Carol Holienkamp Environmental Specialist Aquatic Toxicology Branch/Water Sciences Section/Division of Water Resources Department of Environmental Quality 919-743-8440 office Carol. holienkamp@ncdenr.gov Mailing: 161 Mail Services Center, Raleigh, NC 27699-161 Physical: 4401 Reedy Creek Road, Raleigh, NC 27607 Nothing Compares,,,,,- E-mail correspondence to and from this address is ,subject to the North Carolina Public Records Law and may be disclosed to third parties. 1 Division of "Water Resources December 6, 2016 To. Corey Basinger Water Quality Regional Su rvisor, O Through:Cindy A. Moore � Supervisor, Aquatic Toxicology Branch From: Carol Hollenkamp Quality Assurance �icer, Aquatic "Toxicology Branch Subject: Whole effluent toxicity test results Duke energy McGuire NPDES Permit # NCO02439 /001 Mecklenburg County The aquatic toxicity test using a composite sample of effluent discharged from the Duke Energy McGuire 001 has been.. completed. Duke Energy McGuire 001 has a permitted discharge to 'Lake Norm (7 10 -NA). A whole effluent sample was collected on November 3rd by Wes Bell and facility representative John Quinn for use in an acute 24-hr C riodaphnia du,bia pass/fail toxicity test. The test resulted in a pass. Toxicity test information follows. Test Type Acute 24 hour C r iodap ania du is pass/fail Test Concentrations °rc Test Result Pass Control S ,ival 100° Test Treatment Survival 100% Sample pH 7.36 SIJ Sample Conductivity 54.7 micromhoslcm Sample Total Residual Chlorine <0.10 mg1Z Results for the above sample indicate that the effluent would not be predicted to have water quality impacts on receiving water. These samples were split with ETS Inc. The test conducted by ETS Inc. also passed Please contact us if you have any questions or if further effluent toxicity monitoring is desired. We may be reached at (919) 743- 401, Basin: CTB32 cc Central Tiles Wes Bell, MRt3 Aquatic Toxicology Branch Water Sc ienc es &ction From: Hollenkamp, Carol Sent: Tuesday, December 06, 201 1:58 PM To: Basinger, Carey Cc; Bell, Wes; Tuvia, Ori A Subject: Toxicity Test Reports Attachments: Shelby TP_1016.pdf; Duke Energy McGuire _001_111 .pdf, Duke Energy McGuire 002 111 .pdf; Duke Energy McGuire `005_11.1 .pdf The toxicity test reports for Shelby WWTP and Duke Energy McGuire Outfalls 001, 002, and 005 are attached, if you have any questions, please let me knew. Thanks, Carol Hollenkamp Environmental Specialist Aquatic Toxicology Branch/Water Sciences Section/Division of Water Resources Department of Environmental Quality 919- 43-8440 office CaroLhollenkamp@ncdenr.gov Mailing: 121 Mall Services Center, Raleigh, NC 27699-1621 Physical: 4401 Reedy Creek Road, Raleigh, NC 27667 Ernail correspondence to and from this address is subject to the North Carolina Public records Lair and may be disclosed to third parties. PPTIACCRORY Governor �� C.-INW. l G DONALD R. VAN DER VAART Secretary Water)Zesources S. JAY ZIMMERMAN ENVIRONMENTAL QUALITY . Director November 8, 2016 Mr. John Williamson Lead EHS Professional, McGuire Duke Energy Carolinas,: LLC 1200 Halters Ferry Road Huntersville, North Carolina 28078 Subject: Compliance Biomonitoring Inspection McGuire Nuclear Station NPDES Permit No. NCO 24392 Mecklenburg County Dear Mr. Williamson. Enclosed is a copy of the Compliance Biomonitorig Inspection Report for the inspection conducted at the subject facility on November 3, 2016 by Mr. Wes Bell of this Office. Please inform the facility'sOperator-in-Responsible Charge (ORC) of our findings by forwarding a copy of the enclosed report. The results of the effluent toxicity samples collected on November 3, 2016 will be forwarded to you under separate cover. Should you have any questions concerning this report, please do not hesitate to contact Mr. Bell at (704) 235-2192, or via email at wes.bell ,nedenr gov. Sincerely, W. Corey Basinger, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDEQ Enclosure: Inspection Report cc. Rusty Rozzelle, MC QP MSC-1617 Central -Basement WB State ofNorth Carolina ( Environmental Quality I Water Resources I Water Quality Regional operations •., - ,:.e _: - - _, r. __ I I I. - f.d.......:A ...,_..., 0-4- am 1 101 14 United States Environmental Protedion" Agency Faint EPA Washinglorw, P.C. 20460 OMB No. 204 57 Water Compliance Inspection Report Approval expires 8-31-98 Section A. National Data System Coding (.e., PCs) Transaction Cade NPDES yr/mo/day Inspection Type Inspector Fac Type U 3 N00024392 111 121 1611110 1" 18 �' 19 � 20 L J 21 Inspection -Work Clays Facility Self -Monitoring Evaluation Rating S1 QA ---- �- ----Preserved-•- Fr7 2.0 70 l� j 1 t 72 � 7 4 7 L f tom. Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Crate POTW name and NPDES hermit Number) 09:25AM 16111103 18106101 McGuire Nuclear Power Plant NC Hwy 73 Exlt Time/Date Permit Expiration gate Huntersville NC 28078 01:00PM 16/11/03 20/02129 , Name(s) of Onsite Representative(s)fT`ities(s)/Phone and Fax Numbers) Other Facility Data Charles Anthony Bynum/ORC/980-875.4316f Name, Address of Responsible ciallTitl hone and Fax Number Contacted Steven M Snider,12700 Hagers Ferry Rd Huntersville NC 280781PIanf Manager/980-875-41111 Na Section : Areas Evaluated (During Inspection (Check only those areas evaluated) Permit Flag Measurement Operations Maintenance RecordstReports, Self -Monitoring Program Mudge Handling Disposal Facility Site review EffluentlRecelving Waters Laboratory Section i7. Summary of Finding/ omments (Attach additional sheets of narrative and checklists as necessary) (See attachmentsummary) Names) and Signature ) of In s) Ag y Phone and Fax Numbers Crate s Bell ` MRO 1704-66 -1699 .219 / Signature of Management Q A Reviewer Agency/hone and Fax Numbers Crate W. Corey Basinger MROWQ/f7O4-236-2194/ EPA Form 3660-3 (Rev 9-94) Previous editions are obsolete. Pa ' 1 NPDSS yrimolday ', Inspedon Type NCO024392 of 121 ISMIf03 117 '18 ( i Permit: NCO024392 Owner . Facility: McGuire Nuclear Power Plant Inspection Date: 11103t2016 Inspection Type: Bioassay Compliance: Permit Yes Ne NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ ❑ ■ 0 application? Is the facility as described in the permit? 0 ❑ ❑ ❑ Are there any special conditions for the permit? ■ ❑ ❑ ❑ is access to the plant site restricted to the general public? ® ❑ Q ❑ Is the inspector granted access to all areas for inspection? ■ ❑ 0 El Comment: Uutfall 001 discharge is not Chlorinated. The last Com liance evaluation ins action was gerformed at the facili on 10l16/14 by DM Staff. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? ® ❑. 0 11 Is all required information readily available, complete and current? ■ ❑ Are all records maintained for 3 years (lab. reg, required 5 years)? 0 ❑ 0 Are analytical results consistent with data reported on DMRs? ® ❑ ❑ 11 is the chain -of -custody complete? ®0 ❑ [ Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Naive of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? a ❑ 0 11 Has the facility submitted its annual compliance report to users and DWQ? 0 ❑ a ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator ❑ D s ❑ on each shift? Is the ORC visitation lag available and current? E ❑ Is the ORC certified at grade equal to or higher than the facility classification? ® ❑ 11 Is the backup operator certified at one grade less or greater than the facility classification? ® ❑ Is a copy of the current NPDFS permit available on site? . ® 0 ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ❑ ❑ Comment: The records reviewed Buring the inspection were or ani ed and well maintained. Discharge Monitoring Reports QLARs were reviewed for the period a tember 2015 thLog h Agglust 2016. No efflu nt discharges were re o ed from Outfall 006 during the review period. No effluent limit violation` were lee orted and all monitorin fr uencies were correct. Page# 3 Permit; NCO024392 Owner. Facility. McGuire Nuclear Power Plant Inspection Date: 1110312016 Inspection Type. atoassay Compliance F12w 1Uleasurement - Effll enit s N2 NAB Is the flow meter operational? 01100 (If units are separated) toes the chart recorder match the flow meter? 1:1 ❑ N ❑ Comment. Qutfall 002 flow meter is calibrated marl and wa last calibrateei on 1 QW1 `b QUke EneMy'l I&E Qg a ment. Qgutfall L01 flows are tigljo on'2um2 Iggs and C lut alI QL4 flows are based on tank voiumg ggiculations. Outfall 002and 005 flows,combine 2HQr to bein measured by a V-ngLtc_h weir and staff au e. The flow for Ou f It 00 Is calculated b subtracting out Jhe measured flow from Outfall 002 Effluent Pipe Xes' No NA Ng Is right of way to the outfall properly maintained? W0130 Are the receiving water free of foam other than trace amounts and ether debris? If effluent (diffuser pipes are required) are they operating properly? ❑ © 0 ❑ Comment: The effluents from C lutf 11 Q 1/004 and 00 10 5 a eared clear with no floatable solids sheens or foam. Not Outf li 005 was not discharging at Jhe Jima of the ins ection. The receivina stream did net aDoear to be neizativetv im acted DWR s aff collected effiu nt toxici s m les with Luke Energy ataff at 0 tfalls 001 s lit com osiJe gam' le and 002(grab sample) during the ins ection. The results will be forwarded under se agate cover. page# 6 Bell, Wes From: Rodriguez, Teresa Senn. Friday, August 05, 2016 9: 4 AM To: Williamson, John Bell, Wes Cc: Walters, Macrae Burris; Gardner, Melanie Samuels Subject: RE: Pond Dye Toxicity Tests - NCO02439 John, I forwarded the information to Cindy Moore with the Aquatic Toxicity Branch, she reviewed it and is OK with the dye treatment protocol as proposed at 8 ppm. Teresa From: Williamson, John C [mailto.John Williamson@duke-e ergy. om] Sent: Thursday, August 04, 2016 4.12 PM To: Bell, Wes <wes.bell@ncdenr.gov>; Rodriguez, Teresa <Teresa. Rodriguez@ ncden r.gov> Cc: Walters, Macrae Burris <Macrae.Walters@duke-energy com>; Gardner, Melanie Samuels <Melanie.Gardner@duke.. energy.com> Subject: Pond Dye Toxicity Tests - NCO 2439 We would like to treat the WW B (Waste Water Collection Basin) that discharges to Qutfall 005 with dye to help control algae growth and pH. As requested, we had toxicity tests (i day chronic) performed on the 2 pond dyes we would like to use in the WWB (Outfall 005) to help control algae and pH. We had the lab perform a dilution series at 6, i, 8 9,10, and 11 ppm on the dye in soft synthetic water. We plan to treat the WCB at8 ppm.; Both dyes pasted the tests. The test results are attached. We would hike to use the Mystic Black Dye as the Black Onyx is no longer available. Please advise if it is ok to proceed with the dye treatment, We would like to perform the dye treatment as soon as possible as we are having pH issues on the WWCB. It is currently pumped down below overflow to prevent a potential discharge of water over the pH limit. Thanks II John C. Williamson Duke Energy McGuire Nuclear Station Environmental Services Office: 980-875-5894 Cell. 88-312-6002 1 PAT MCCRORY DONALD"R. VAN DER VAART WaterResources S. JAY ZIMMERMANN ENVMONMENTAL QUALITY Dh t cro March 31, 2016 . to r°,WR Michael Ruhe Duke Energy Carolinas LLB PO Box 1006 Charlotte, NC 28201-1006..� Subject: NPDES Electronic Reporting Requirements and Sixty Day Notice of Minch Modification of the NPDES Permit McGuire Nuclear Power Plant NPDES Permit Number: NCO024392 Dear NPDES Permittee: The U.S. Environmental Protection Agency (EPA) recently published the National Pollutant Discharge Elimination System (NPDES) Electronic Reporting Rule. The rule requires NPDES regulated facilities to report information electronically, instead of filing written paper reports, The rule does not change what information is required from facilities. It only changes the method by whichinformation is provided (i.e.., electronic rather than paper -based). EPA is phasing in the requirements of the rule over a 5-year period. The two phases of the rule, and their key milestones, are: • Phase 1—Starting can December 21, 2016, regulated entities that are required to submit Discharge Monitoring Reports (DMRs) will begin submitting these reports electronically, instead of on paper. if you are currently reporting your DMR data electronically using eDMR, then you simply need to continue reporting in the same way as you are now, The key change is that, starting on December 21, 2016, electronic reporting of D Rs will be required, instead of voluntary. • Phase 2—Starting on December21, 2020, regulated entities that are required to submit certain other NPDES reports will begin submitting these reports electronically, instead of on paper. Reports covered in the second phase include Notices of Intent to discharge in compliance with an NPDES general permit, Sewer Overflow/Bypass Event Reports, and a number of other NPDES program reports. For more information on EPA's NPDES Electronic Reporting Rule, visit lift : www2epa.ocom Hance'final-national- ollutant-dischargeµelimination-systemdes4 electronic reporting -rule. For more information on electronic reporting to NC DWR, visit htt :/fie .nc.gov about�divisio s/ ter-jresour"cesZedmr n des -electronic -re or or contact Vanessa j Manuel at 919-807-6392 or via email at Vanessa.Manuei cr�cdenr. ov. State of North Carolina I Enviromnental Quality I Water Resources 1611 Mail service Center I Raleigh, North Carolina 27699-1611 919 707 9000 SixtyDays' Notice of Minor Modification of the Subjeci - effective on July 1, 2016. dated (October 15, 2007. NPDES Permit incorporate electronic Inrlrar thin MMW ri d a th a Office [Drawer 11666, Raleigh, North Carolina 27604. if you do not file a petition within the required time, the agency decision shall be final and binding. If you have questions concerning this permit modification, please contact Tom Belnick at telephone number 91-807-63 0. Sincerely, forS. Jay Zimmerman, P.G. Enclosure: NPDES Permit Standard Conditions Part III Addendum Cc: NPDES File Central Files I 1 e :f4 FIL MCDEN North Carolina Department of Environment and Natural Resources Pat McCrory Donald van der Vsart Governor Secretary May 19, 2015 r. John Williamson Duke Energy Carolinas, LLC 12700 Hagers Perry Road Hunersvile, North Carolina 25070 Subject: Rescission of Notice of Deficiency -- Monitoring Limitation Tracking lumber: NOD-2015- V-0066 McGuire Nuclear Power Plant PDES Permit No. NCO024392 Mecklenburg County Deer Mr. Williamson: Can May 6; 2015, this office received a response to the above referenced Notice of Deficiency (NOD). The NOD was issued for not monitoring flow at (utfall 004 during the monitoring ~reek ending January 10, 2015. Based on the amended January 2015 DMRs for Outfall 004 received on May 6, 2015, this office is rescinding the above referenced Notice of Deficiency. if you have questions concerning this matter, please do not hesitate to contact lbs. Marcia Allocco at (04) 5-2204: Sincerely; Michael L. Parker, Regional Supervisor' Water Quality Regional Operations Section Division of Water Resources, NCENR cc: Wastewater Branch C 11 — Central files basement R. Rozzelle, MCWQP Mooresville Regional Office Location: 610 East Center Ave., Suite 301 Mooresville, NC 28115 Phone: (704) 663-16991 Fax; (704) 663-60401 Customer Service:1-877-623-6748 Internet: http:/1portal.ncdenr.orglweblwq; An Eaual Onnortunity t Affirmative Action Emolover -- 30% Recvciedil0% Past Consumer paver ..,,.3? L 'pzaM -` HCDENR North Carolina Department of Environment and Natural Resources Pat McCrory Donald van der Vaart Governor Secretary April 20, 2015 Mr. JohnWilliamson Duke Energy Carolinas, I_I_C 12700 Hagers Ferry Roan Huntersville, North Carolina 28076 Subject: Notice of Deficiency — Monitoring Limitation Tracking Number NC D-2015-MV-0066 McGuire Nuclear Power Plant NPDFS Permit NCO 24392 Mecklenburg County Dear Mr. Williamson; A review of the January 2015 self -monitoring report for the subject facility revealed a violation of the following parameter at Outfall 004; Date Parameter Reported Value Monitoring Reguirelment Week ending 1/1 /15 Flow None Monitor weekly Remedial actions, if not already implemented, should be taken to correct the causes(s) of the noted violation.. Unresolved violations may lead to the issuance of a Notice of Violation and/or assessments of civil penalties by the Division of Water Resources. If the violations are due to a transcription error' (data left off the DMR) please submit an amended January 2015 DMR (two copies) to this office along with a cover letter asking for rescission of the Notice of Deficiency, Please address your correspondence to Ms. Marcia Allo co at the letterhead address: Thank you for your attention to this matter, If you have questions concerning this matter or to apply for a SOC, please do not hesitate to contact Ms. Allocco at (704) 235-2204. Sincerely, Michael L. Parker, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NDFNR cc: RR. Rozzelle, MCWQP Wastewater Branch MSC 11 — Central Files Basement MA Mooresville regional Office Location: 610 East Center Ave„ Suite 331 Mooresville, NC 28115 Phone: (7Q4) 663-1699 t Fax: (704) 663-60401 CustomerService: 1.877-623- 748 Internet: htto.11codal,ncdenr,orgtwebl n An Equal opportunity \ Affirmative Action Employer - 30% Recycled/100/6 Post Consumer paper �►i w_F E CDENR North Carolina Department of Environment and Natural Resources Pat McCrory John E: Skvarla, lil Governor Secretary October 21. 2014 Mr. John Williamson Lead EFIS Professional, McGuire Duke Energy Carolinas, LLC 12700 Lagers Ferry Road Huntersville, North Carolina 28078 Subject: Compliance Evaluation Inspection McGuire Nuclear Station NPDES Permit No. NCO024392 Mecklenburg County Dear Mr. Williamson: Enclosed is a copy of Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on October 16 2014 by Mr. Wes Bell of this Office. Please inform, the facility's Operator -in - Responsible (ORC) of our findings by forwarding a copy of the enclosed report. The report should be self-explanatory-, however, should you have any questions concerningthis report, please do not hesitate to contact Mr. Bell at (704) 5-2192 or at 1yes.be.11(a)-ingdenir.gov. Sincerely, a Michael L. Parker, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDENR Enclosure: Inspection Report cc: MSC 1 17-Central Files/Basement Rusty "Rozzelle, MCWQP WB Mooresville Regional Office Location: 610 East Center Ave., Suite 301 Mooresville, NC 28115 Phone. (704) 663-1699 S Fax: (704) 663-6040 4 Customer Service, 1-677-623-6745 Internet: www.ncwaterquality.org -An Pniml t annorbinh � Af rninfivp Action Fmrsicver v 301% Recvc(ed110% Post Consomer Dom r� United States Environmental Protection Agency Form Approved, EPA Washington, D.C.20460 OMB No. 2040-0057 Water Compliance inspection Report Approval expires 8-31.98 Section A- National Data System Coding (i.e., PCS) Transaction Code NPDES" yr/mo/day Inspection Type Inspector FacType 1 N 5 3 1 NC0024392 Ill 121 14/10/16 117 18 LCJ 19 Lgj 20 21 6 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA-----------------Reserved ---®-_:---- __ 67 1.0 7014 1 71 N 1 72 1N 731 1 174 75 I S Section B: Facility Data Name and location of Facility inspected (For Industrial Users discharging to POTW, also include Entry Time/Gate Permit Effective Date POTW name and NPDES permit Number) 09:45AM, 14110/16 10/04/01 McGuire Nuclear Power Plant Exit Time/Date Permit Expiration Date NO Hwy'73 01;00P 14/10t16 15l02128 Huntersville NO 26078 Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data 1Jl Charles Anthony Bynum/ORC/980-875-43161 John C Williamson/1980-875-5894 / Name, Address of Responsible Ofnciai/Title/Phone and Fax Number Contacted Steven D Capps,12700 Hagers"Ferry Rd Huntersville NO 28078/Site Vice President// No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit a Flaw Measurement operations & maintenance IN Records/Reports Self -Monitoring Program 0 Sludge Handling Disposal Facility Site Review in Effluent/Receiving Waters Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/OfficelPhone and Fax Numbers Date Wes Bell MRO WQ/1704-663-1699Ext.21921 t,a Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES yr/mo/day Inspection Type (Cont.) 171 31 NCO024392 J11 121 14/10/16 17 18 Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as ner.-asarv) to discharging into the Catawba River. Page# 2 PV Permit NCO024392 Owner -Facility, McGuire Nuclear Power Plant Inspection date: 10116/2014 Inspection Type: Compliance Evaluation E it Yes _NONA N (If the present permit expires in 6 months or less), Has the permittee submitted a new Is 0 El 0 application? Is the facility as described in the permit? 0 0 El El Are there any Special conditions for the permit? Is El 11 13 Is access to the plant site restricted to the general public? 11 El El El IS the inspector granted access to all areas for inspection? 2Ld�tt Yes No NA NE Are records kept and maintained as required by the permit? 0 El El 13 Is all required information readily available, complete and current? Are all records maintained for 3 years (lab_ reg, required 5 years)? Are analytical results consistent With data reported on DMRs? 11 Cj El 11 Is the chain -of -custody complete? a 0 El El Cates, times and location of sampling 11 Flame of individual performing the sampling In Results of analysis and calibration in Dates of analysis Name of person performing analyses Transported CQCs Are CMRs complete: do they include all permit parameters? N El El 13 Has the facility submitted its annual compliance report to users and CWQ? 11 11 11 Q (if the facility is = or > 5 MCC permitted flog) Co they operate 4i7 with a certified operator El 0 11 El on each shift? Is the i RC visitation log available and current Is the ORC certified at grade equal to or higher than the facility classification Is the backup operator certified at one grade less or greater than the facility classification? Is a copy of the current NPDES permit available on site? In El 1:1 11 Facility has copy of previous year's Annual Report on file for review? 0 El 19 El Page# 3 Permit: NCO024392 Owner-Facfflty. McGuire Nuclear Power Plant Inspection Date: 10/1612014 inspection Type: Compliance Evaluation Record Keeping Yes t!o NA NE Comment: The records re Monitoring Reports (DMRs) were reviewed for the period August 2013 thr2oqgt_4q!y2014. No effluent discharges were reported from Outfall 006 during the review_p �od, No effluent limit violations were re orted and all monitorin fro uencies were correct, Laboratoa Yes No NA NE Are field parameters performed by certified personnel or laboratory? 1:1 1:1 El Are all other parameters(excluding field parameters) performed by a certified tab? 1:1 1:1 11 # Is the facility using a contract tab? # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 0.2 degrees? 11 El 0 1:1 Incubator (BOD) set to 20.0 degrees Celsius +/- 1.0 degrees? 11 El N 0 Comment: Effluent analyses (including field) are performed under Duke Energy's Envtronmental Services laboratoa certification #248 and field laboratory certification #5156. Gel Laboratories. LLC and ETS, Inc. have also been contracted to provide analyt!gal su ort. The laboratory instrumentation used for field analvses alooeared to be t)rODerlv 0�11brated/verified and documented, Effluent Sampling Yes No NA NE Is composite sampling flow proportional? Is sample collected below all treatment units? Is proper volume collected? U El 1:1 1:1 Is the tubing clean? 1:1 El 11 0 # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees a 0 El 0 Celsius)? Is the facility sampling performed as required by the permit (frequency, sampling type 13 E] El representative)? Comment: The subiect r)ermit reawires comoosite (Outfall 001-toxiciW—and grabegfflfflugnat§gsa mples. The facilitv staff must ensure to document the all not verifications 11 KODmlLsl. �minfmujmand� internal temperature measurements for each toxicitv samt)IiD_g event) on the effluent SgMpler, OlRerations &Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? N 0 13 1:1 Does the facility analyze process control parameters, for ex: MLSS, IVICRT, Settleable 13 El N 0 Solids, pH, DO, Sludge Judge, and other that are applicable? Page# 4 -AA ..nnit' NG0024392 Owner Inspection .. t !• ons & Maintena!jge Yes No NA NE Comment:The treatment facilities .rr-. -r to be prope[ly 6661rated and well maintained, Carbon dioxide is .re.r atouffall 012 (following r r • on ..••• basis. Flow Measurement - Effluent Is flaw meter used for reporting? Is flow meter calibrated annually? Is the flow meter operational? (if units are separated) Does the chart recorder match the flow meter? Comment: Effluent Pipe Is right of way to the outfall property maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Comment: Yes No NA NE loves are ftaquae Yes No NA N loves are ftaquae Yes No NA N El n addition downstream Page# 5 A.wf' - ircib'E'NR FILE North Carolina Department of Environment and Natural Resources .. Division of Water Quality Pat McCrory; Thomas A. Reeder John E. Skvarla, III Governor Acting Director Secretary July 31, 2013 Mr. Jahn Williamson Duke Energy McGuire Nuclear Station 12700 Hagers Ferry Road Huntersville NC 28078 Subject: Compliance Evaluation lnpsection .Duke Energy McGuire Nuclear Station NPlES Permit: NCO039 Mecklenburg County, County .Dear Mr. Williamson: Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on July 31, 2013 by Donna Hood of this office. Please inform the facility's Operator-m- Responsible Charge of our findings. bforwarding a copy of the enclosed report. The report should be self-explanatory; however, should you have any questions concerning this report, please do not hesitate to contact Ms. Hood a (70 ) 663-1699. t Donna Hood Environmental Specialist Surface Water Protection Mooresville Regional Office Enclosure cc. ventral Files Mecklenburg County Water Quality Protection Mooresville Regional Office Location: 610 East Center Ave.. Suite 301 Mooresville, NC 28115 C11 Phone (704) 663.1699't, Fax: (704) 6 3-6040 t Customer Service. 1-877-6 3-6748 Cl l l a Internet, htp://pottal,ncdenr.org/weblwq An Erluai Gpporfi,Mity 4 AEfr mative Action Employer 50% Recyded/10% Post Consumer paper Naturally United States Environmental Protection Agency Form Approved, EPA Washington, D.C. 20460 OMB No. 2040-0057 Approval expires 8-31-98 W,qtpr ComphancalnspecfiaaJ��. Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 LN 2 L5 31 NCO024392 111 121 13/07/31 17 18LCI 19LSI 20U L-1 L-- Remarks 21 j6f Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ----------- - ________-----Reserved---- - - - ---------- - -- 671 169 70L31 71 U 72LNI 731 1 1 74 7580 L-j-j Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) McGuire Nuclear Power Plant 01:30 PM 13/07/31 10/04/01 NC Hwy 73 Exit Time/Date Permit Expiration Date Huntersville NC 28078 03:30 PM 13107/31 15102/28 Name(s) of Onsite Representative(s)[Tities(s)/Phone and Fax Number(s) Other Facility Data N Charles Anthony Bynum/ORC/980-875-4316/ Name, Address of Responsible OfficialfTitle/Phone and Fax Number Contacted John 0 Williamson, 12700 Hagers Ferry Rd Huntersville NC 2807811704-875-5894/ No Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Flow Measurement Operations & Maintenance 0 Records/Reports S If_ elf -Monitoring Program Facility Site Review Effluent/Receiving Waters Self-Monitoring g P Section ti ection D- Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspecte'r(s) Agency/Office/Phone and Fax Numbers Date Donna Hood MRO WQH704-663-1699 Ext.2193/ Al Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete, Page # I NPDEs yrtmotday Inspection Type 1 Kr^nn A- 111 121 t 17 181 -1 (cant.) 1 standby nuclear service water pond should discharge, Both settling ponds have been lined with a synthetic liner, (outfall 0 2) This was completed since the last inspection. The carbon dioxide injection system will be upgraded(' in the near future, Page # PF Penn& NCO024392 Owner w Facility. McGuire Nuclear Power Plant , Inspection Date: 07/31/2013 Inspection Type: Compliance Evaluation Permit Yes No NA NE (if the present permit expires in 6 months or less). Has the permittee submitted a new application' Is the facility as described in the permit? 0 i t 1 Are there any special conditions for the permit 0 Is access to the plant site restricted to the general public? Igo 0 Is the inspector granted access to all areas for inspections Igo 0 0 Comment: Special Conditiow Thermal variance is granted by the Division for the months of July, August, and September based on a study conducted on 10/18/1985. Operations & Maintenance ` ; Yes No NA NE . — Is the plant generally clean with acceptable housekeeping? ]WOOD Goes the facility analyze process control parameters, for ex: MC.SS; MCRT, Settleable Solids, pH, DO, Sludge is f l 0 "0 Judge, and rather that are applicable? Comment: Record Keeping Yes No NA NE Are records kept and maintained as required by the permits MOD Is all required information readily available, complete and current Are all records maintained for 3 years (lab. reg, required 5 years)? Are analytical results consistent with data reported on DMRs? is 00 Is the chain -of -custody complete? o o bates, tunes and location of sampling Name of individual performing the sampling Results of analysis and calibration Crates of analysis Dame of person performing analyses Transported COCs Are I MRs complete: do they include all permit parameters? 0 r i 0 Has the facility submitted its annual compliance report to users and D W€ (if the facility is = or > 5 MGD permitted flow) Do they operate 2 /7 with a certified operator on each shift? 0 Is the ORC visitation lag available and current? IN D Is the ORC certified at grade equal to or higher than the facility classification Is the backup operator certified at one grade less or greater than the facility classification? 0 0 0 Page # Permit: NCO024392 Owner'a Facility: McGuire Nuclear Power Plant Inspection Date: 07/31/2013 Inspection Type: Compliance Evaluation Record Keeping Yes No NA NE Isa copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? 00150 Comment. Monthly monitoring reports were reviewed for the period of June 2012 through May 2013, No violations were reported during the period. Lagoons Yes No NA NE Type of lagoons? # Number of lagoons in operation at time of visit? 2 Are lagoons operated in? Parallel # Is a re -circulation line present? Igo 00 Is lagoon free of excessive floating materials?n- # Are baffles between ponds or effluent baffles adjustable? 0 o is 0 Are dike slopes clear of woody vegetation? 0 0 0 Are weeds controlled around the edge of the lagoon? 0 0 0 Are dikes free of seepage? 0 0 0 Are dikes free of erosion? Is 0 0 0 Are dikes free of burrowing animals? 11 0 0 0 # Has the sludge blanket in the lagoon (s) been measured periodically in multiple locations? 0 0 a 0 # If excessive algae is present, has barley straw been used to help control the growth? 0 0 a 0 Is the lagoon surface free of weeds? o o n n- Is the lagoon free of short circuiting? 0 0 0 Comment: Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? 000 0 Is flow meter calibrated annually? is 0 0 0 Is the flow meter operational? 0 0 IN 0 (if units are separated) Does the chart recorder match the flow meter? D 0 in 0 Page # 4 Permit: NCO0243 Owner - Facility. McGuire Nuclear Power Plan Inspection Date: 07131/2013 Inspection Type. Compliance Evaluation Flow Measurement - Effluent Yes No NA N Comment.- Outfall 001 - flaw based can pump log data. Ouffall 00 - flaw meter calibrated quarterly, last calibrated can 7131/ 13. C lutfall 004 is a batch treat system with a<known volume released with each batch discharge.;; Outfall 005 - staff gua e flaw measurement Outfall 006 (metal cleaning waste) this crutfall is no longer in use (there is no metal cleaning wastes generated at the facility), but has been retained in the permit. Effluent Sampling Yes No NA NE Is composite sampling flaw proportional? o o no Is sample collected below all treatment units? 0 0 Is proper volume collected? it i1 Is the tubing clean? Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? 0 0 0 Is the facility sampling performed as required by the permit (frequency, sampling type representative)? 0 0 Comment: Effluent Pipe Yes No NA N Is right of way to the outfall properly maintained? IN 0 0 Are the receiving water free of foam other than trace amounts and ether debris? IN 01 n If effluent (diffuser pipes are required) are they operating properly? 00 120 Comment: Page # Williamson n mg/L not 2+0 During their i that discharg electrodeioni the filters wo in his follow-up - e-mail to this office (located below) that the T C of the sample was ,28 /L exit permit renewal Duke noted that they were going to change out their water treatment plant +^ n" af#.�EI rIn) a "e4 4kro + +k it r ac _ r 6 rorFr +rt = fie!#wanks-- a,Ir,'a,4ai,ww8--*­ --- times per day with chlorinated water (. m /L), which Duke discovered during their incident in (toted below), Outf ll 002 has TE CH monitori i toted in units of m /L as a r onthl rab and MRO world cl rif' From: Williamson, John C [mailto:John.Williamson@ uke-energy.com] Sent: Wednesday, February 22, 2012 4.36 PM To: Parker, Michael; Allocco, Marcia; Lesley, John, Krebs, Rob Subject: McGuire Nuclear Station Toxicity Test Failure Follow-up McGuire iFailure Description of Non-Complianc McGuire experienced a failure of a NPDE (National Pollutant Discharge Elimination System) toxic waste water discharge paint 002. The sites NPDES Permit issued by the Mate of NC requires quarterly WET (Whole Effluent Toxicit be performed on waste water discharge point (Outfall) 002. The discharge sample pulled on February 14th failed its toxicity test on Friday 2/17/2012. collected in February, May, August, and Noverrib Supporting Events be 2 McGuire EHS (Environmental, Health & Safety) was notified on Thursday; 2/ 16/2012 that the; test results were not looking good after 21 hours. The test takes 48 hours to perform. FES notified Chemistry of the potential for failure and the discharge was stopped around noon on 2/16. Chemistry and EHS began to investigate potential failure mechanisms. Later in the day at around 4 PM another email was received from the toxicity lab by EIS that indicated the sample would fail based on results at 29 hours into the test. The LC50 = 62.9% at that time. Permit limit 64° The test was completed on 2/17/201 with a final LC50 of 55.. FES was notified via email and phone call of the failure. FES (John Williamson) notified the OSM (Operations Shift Manager), Alvin Perdue that we would have to notify Mooresville of the test failure at around 130 hours. Per -10 Operations notified the NRC. See PIP f-12-1241 EHS (John Williamson) contacted the Mooresville office of NCI ENR and notified Mr. Mike Parker of the toxicity failure at around 1330. Mr. Parker asked to be kept informed of our investigation results. A retest of Outfall 002 is required within 30 days; A re -test on the discharge will not be perforined until we determine if the water to be released is toxic or not (should know this by Monday or Tuesday). No release of Toxic water will be made. The following actions have been Taken to address this issue. Chemistry stopped the discharge of 002 on Thursday around noon after receiving word that the discharge would likely fail the toxicity test. Chemistry verified that the correct sample had been sent to the toxicity lab and that the lab had analyzed the correct sample. The sample was pulled on Feb. 14. EITS and Chemistry began investigation into what further actions should be taken. After consultation. with Corporate EHS, ET (toxicity lab), Chemistry and EHS, it was determined that we would pull samples from the WC Pond and the Initial Holdup Fond and have them tested for toxicity to determine if we still have a toxic WC bond: Samples were pulled by Chemistry and EHS took them to the toxicity lab (in Asheville N ) Friday afternoon for analysis. Results from these test still indicated that flip WO-11 Pond was still toxic. Further investigation into the cause and source of the toxicity will be performed. Chemistry and OPS are looking into any potential "events" that may have occurred cause. There are a lot of inputs to WC from the Plant, Island Labs, MOC, Medical, 3 n order of their potential to �d by Sodium Bi Suffite before it is released. The Chlorir as well. tle Chlorine content. ' ,HS, Chemistry and the contractor for the Water Treatment Facility reve xinking water facility so no danger to the public would be present. he toxicity test pulled on Monday 2/20 passed the WET test with 100% sur, to discharge the WC-B pond starting Thursday 2/23 and pull a compliance ",� Mr. Bruce H. Hamilton, Site Vice President Duke Energy Carolinas, LLC MCGuire Nuclear Station 12700 Havers Ferry Road Huntersville, North Carolina 28078 Subject: Notice of Violation Rescission Tracking : N V-2010-MV-0134 McGuire Nuclear Power Plant WWTP NPDES Permit No. NCO024 92 Mecklenburg County Dear Mr, Hamilton. This Office was contacted by Mr. John Williamson of Duke Energy on October 4, 2010 in response to the above referenced Notice of Violation (NOV). Mr. Williamson informed our Staff of an error correction for NCO2432 that was issued by the Wastewater Permitting Unit on March 18, 2010. The error correction removed the quarterly copper and iron monitoring at Outfall 005, Unfortunately, the error correction was not attached to the permit in our Office and the change in monitoring requirements has not been made in our Compliance Reporting Database, Our Office will follow-up to ensure the erroneous monitoring requirements are removed from the database for NCO024392 and through this letter we are rescinding NOV-2010-MV-01 34. If you have any further questions concerning this matter, please do not hesitate to contact Ms Allocco or me at (04) 053-1699. Sincerely, Robert B. Krebs Surface Water Protection Regional Supervisor c: Point Source Branch DWQ Central Files Mecklenburg County Water Quality Program, R. Ro zelle MA Mooresville Regional Office Location: 610 East Center Ave., Smite 301 Mooresville, NC 28115 One Phone: (704) 663-1 06 0 Fax: (704) 663-6040 t Customer Service: 1-877-623-6748 NotthCarolitia Internet: http:llportat,ncdenr.org/web/wq AaAllallil An Squat Opportunity l Affirmative Action Employer - 30% Recyced/10% Past Consumer paper September 30, 2010 Mr. Bruce H. Hamilton, Site Vice President Duke Energy Carolinas, LLC MCGuire Nuclear Station 12700 Hagers ferry Road Huntersville North Carolina 2807 Subject: Notice of Violation — Monitoring Violations Tracldng 9: NOV- 010- -013 McGuire Nuclear Power Plant WWTP NPDES Permit No. NCO024392 Mecklenburg County Dear Mr. Hamilton. A review of the. April -June 2010 self -monitoring reports for the subject facility revealed monitoring violations of the following parameters at Outfall 005: Date parameter Reported Monitoring Value Requirement Quarter ending 6/30/10 Total recoverable copper None Ix/quarter Quarter ending 6/30/10 Total recoverable iron None Ix/quarter Remedial actions, if not already implemented; should be taken to correct any problems. The Division of Water Quality may pursue enforcement actions for this and any additional violations. If the violations are of a continuing nature, not related to operation and/or maintenance problems, and you anticipate remedial construction activities, then you :may wish to consider applying for a Special Order by Consent. You may contact Ms. Marcia Allocco of this Office for additional information. If you have questions concerning this matter, please do not hesitate to contact Ms. Allocco or rile at 704/663-1699. Sincerely; Robert B. Krebs Surface Water Protection Regional Supervisor cc: Point Source Branch Mecklenburg County Water Quality Program,R. Rozzelle MA Mooresville Regional office Location. 616 Fast Center Ave.. Suite 301 Mooresville. NC 28115 Phone: (764) 663-1699 t Fax: (704) 663-5040 t Customer Service 1-877-623-6748 Internet http:/1portal,ncdenr.orgiweb/wq An Equal Opportunity \ Affirmative Actw Emp;ayer- 30% Recycted/10% post Consumer paper One NofthCarolina ,A'atitrally Duke /W Dine Energy lftov="eram. McGuire1tIuFe Station i 2i00 Halterss Ferry Rand Huntersviiie, NC 28078 June 30, 2010 North Carolina Department of OlVIS04 Environment And Natural Resources 2 9 .10 Division of Water Quality Surface Water Protection Section-NPDES TI ON 1617 Mail Service Center MOORESVILLE Raleigh, NC 27699-1617 Subject: Luke Energy . e iuclear Station NPDES Perm Mecklenburg County Signatory Authority Certified Mail: 7010 0290 0002 6148 7364 Attention: Mr. Tom:Belnick Part II, Section B(I 1), of McGuire's National Pollutant Discharge Elimination System (NPDES) Permit, addresses the requirements for assigning ;signatory authority to individuals who submit reports or other information to N DENR. for permit compliance purposes. As Site Vice President for the McGuire Nuclear Station, I hereby grant the following management positions signatory authority for signing reports, documents or other information as required by NCDENR for NPDES Permit compliance. F_ Management .. Position upied OccBy Steven D., Capps !Duncan n n Ian .. ,... Ross G. f. errigo III Please note that this authorization is being granted to the management, positions described above, rather than to a specific individual. The table above shows the individuals presently serving in these capacities and is shown for informational purposes only. Should you have any questions concerning this letter, you may contact Jahn C 1 7 Williamson of the McGuire Environmental; Health & Safety Group, by phon 9 0- 75-5 4 or e-mail at john.williamson@duke-energy.com. AUG2010 Sincerely, Late: d,136110 Regis T. Repko McGuire Nuclear Station Site Vice President ee: Ross Perrigo Allen Stowe Gary Spin Jeff Cage w'y rpr North Carolina Department of Environment and NaturalResources Division of Water Quality Beverly Eaves Perdue Coleen H, Sullins Governor Director February 1 2nit Eu 1 20 1 Regis T. Repko Site Vice President Duke Energy Carolinas, LLe Dee Freeman Secretary '* . .. � r r - # � wrr r *# - r *r • r- r • # # r s* r *• # r r r * r< * r' r r r r s r. # rr r a� •!R • r< r r r• r* # r- • # # - r �. - r.: -r .: r • •- # MI- � .. .. :. ,. r .r• r r# ,. �. ,, r * • r r* # r � r * r # - r- _ #+� -r • - # r #r .s rr # ,� • t P P Regis T. Repko February 15, 2010 Page We do have two comments: Comments' 1. In other environmental monitoring reports that are submitted by Duke Energy to DWQ to fulfill 316(a) obligations (e.g., page 1-2 of the November 2009 Allen Steam Station Report), "boiler plate" language is used to instruct the reader as to the definition of a balanced and indigenous community as first described in the Clean Water Act and later defined in 40FR15.71(): "Assessment of the potential influence of thermal discharges on biological communities is a key component of thermal discharge variances granted under section 316(a) of the Clean Water Act (C A). The term "balance, indigenous community" [40CFR125 71(c)] is synonymous with the term "balanced indigenous population" its the CWA and refers to a biotic community typically characterized by diversity, the capacity to sustain itself through seasonal changes, presence of necessary food chain species, and a lack of domination by pollution tolerant species. Such a community may include historically non-native species introduced in connection with a program of wildlife management and species whose presence or abundance results from substantial, irreversible environmental modifications (USEPA 1 77)" We encourage you to include this language in future reports for the McGuire Nuclear Station because it will aid reviewers as to the purpose of the environmental monitoring studies which are conducted to support continuation of the 316(a) variance. 2. Limnological data, presented in the report are similar to that previously collected by DQ's Intensive Survey Unit from Lake Norman. And as in past years evaluations, algal; assemblages and their related densities remain well below levels that could be considered problematic. Seasonal trends and shifts in composition follow those expected to occur in piedmont reservoirs throughout the year. If you have any questions, please do not hesitate to contact me or my staff. Yours truly, Jay Sauber Chief, Environmental Sciences Section cc: e Debra Owen, Environmental Sciences Section Jeff Poupart, Surface Water Protection Section Bryn H. Tracy, Environmental Sciences Section Mark Vander Borh, Environmental Sciences Section 1621 Mail Service Center, Raleigh, North Carolina 27699-1621 One Location:4401 Reedy Creek Road, Raleigh, North Carolina 27607 Phone: 919-743-84001 FAX: 919-743-85171 Customer Service:1-877-623-6748 NorthiCarolina Internet http:fh2g,enr,state,nc.us/esb/ NaAmally An Equal Opportunity t Affirmative Action Employer FILE� Fr NCDENR North Carolina " Environment and NAtural Resources Division of 'Aiater Ccale:��� H. Scz!?tta� �a�e BeverlyFreeman Eaves Perdue Sec:retary Governor Director Julys 27, 2011 Mr. Jolua Williamson Duke Energy McGuire Nuclear Station 1270011agers Ferry Road 1luntersville, North Carolina 2807 ulajea. Compliance F"Vatluatio a Inspection Duke Energy Mc(iruirc Nuclear `station N1' DES Permit No. NCO024392 Mecklenburg County, NC Dear 1\/1r, Williaamsoa- Enclosed is ca Copy, of the Compliance Evaluation Inspection Report for the inspection conducted at the su jet faa ilityr on July 2fi, 2011 by John Lesley. Please inform the facility's Operator -in -Responsible Charge e, of our findings by forwarding a copy ofthe enclosed report. The report should be self-explaaaatotry� however, should you haveany questions concerning this report, pleatse. do not hesitate to contact 1r Lesley at 7' -66 -l69 . Sincerely, Robert t . Krebs Division of Waiter Quality Surface Water 'rcatectitaaa Reaaioriaal Supervisor Enclosure cc: Centrat F-des \iee lenbt.,irg County nty Water Quality I'l-.aW0,101a It rfs rid 4�t =�3 ���4 OPis t N61hC'arol,irr€aaa 6(�,3-16014 t GEC. P 1) Cat -60,10 t�.ttst, incr �,w is 1-977-62 6�71t Internet: q lnrtejae ^ui�"n �entx4 re .ona,f.,/7 sorry hypprrsvlpo, ingtcn,Cli1 i aQ IviF3 yU.9Q UWa16W t r nce Iris ti rf t C�� Approval expires H-31-9t1 Section ., National Data System Coding (i,e,„ PSS) mmTransaction C' 'o (I e � NPDt by yrtrrnr !dny 1,n :pc.E,iMn l ype tnspec for F ac "Cypc 1 t1 2 j s � 31 vtew0024 y?y � 11 12 I.1 / 0 - I ° ,6 17 13I 1 19 201 Pc mar ks 91 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA w- --------- Reserved -__--__v--___ __-_ 6 1 2.0 169 70 71 L N 79 L H I 73[_Lj 74 75 Section B. Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective gate' POTW name and NPDES permit Number) 09:45 AM 1.1/0"7,f26 1.11101I01 is Gui re Nuclear Power Plant Exit Time"/Date Permit Expiration Date NC" Hwy 73 HLnte7rsv lle NC 28078 12.00 PM 11/07/26 15/02/28 Narrne(s) of Onsite Representative(s)/Titles(s)fPhorne and Fax Number(s) Other Facility ity Data r, Wr 1 .l1saca ; effrey= Cage/0RC.f i0 -; 15-441V Name, Address of Responsible Official/Title/Phone and Fax Number ICId ,Yon C wj j mscan, 1?7CJi1 H yers Ferry Rd bunter �_.� ire NC Section C: Areas Evaluated During Inspection (Check only those areas evaluated) EPermit flow Measurement Records/Reports Self -Monitoring Program ty' Site Review Effluent/Receiving Waters eotion D° Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of #nspec terr(s( Acge my/Of icelPhone and I ax Numbers [Date John E Lf sl 'yY``i r4ttC7 WQ//` 04 663-1699 Ext,219,11 1 ? iv Signotrrre of ivt magenncnt Q.A i a Wfr }\tr.rte;}�Ulr t Ih'}ko ,a =trr F N�ar)�ra r : Dale h9ar is l' �cc va a 1 r fra7 13 1/ L t; EPA Form >3; 60-3 (Rev -94) Provimm editions are obsolete. Page f yrtrnolday Inspection Type 11 121 21/07/26 117 18lC1 sr 100. ,l ar service water pond should discharge. settling ponds is out of service for repair of the synthetic liner ( utfall 002). Pa A 'AM Permit: NCO024392 Owner - Facility: McGuire Nudear Power Plant inspection Date: 07/26,12011 Inspection Type. Compliance Evaluation Permit Yes No NA NE (It the present permit expires in 6 months or less)- Has the permittee SUbrniited a new application? a Is the facility as described In the permit? 0 0 C-1 # Are there any special conditions for the permit? o o n- Is access to the plant site restricted to the general public? D 00 Is the inspector granted access to all areas for inspection? 0 01 0 Comment: Special Condition: Thermal variance is granted by the Division for the months of July, AugUst, and September based on a study conducted on 10/18/1985., Re cord Keeping Yes Wo NA NE ------ ---- Are records kept and maintained as required by the permit? L1 0 0 Is all required information readily available, complete arld current? DoD Are all records maintained for 3 years (lab. reg, required 5 years)? 000 Are analytical results consistent with data reported on DMRs? 0 0 D Is the chain-Of-CUstody complete? 01 0 0 Dates, times and foca�iori of sampfilig M Name of individual performing the sampling IM Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are, DMRs complete: do they include all permit pararneters? Has the facility submitted its annual compliance (eport to users and DWQ'? n a (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? 0 0 0 Is the ORC visitation loa available and CUrrent? 11 0 El Is the ORC certified at grade equal to or high(--,,r than the facility classification? El D U Is the backup operator cerfified all one grade less or, grea!ef than the faciWLy classificolion? 0 El Is a copy of the cun it W POE S pei a tit �ivailable o! 1C ? r1 Facility has copy of previous y(�,,.ar's AnrlUal Report on file, for icview? Cornment: All records were connplete and Lip to date- Ffiluent Yes No NA NE Is right of way to outfaH properly maintained? rj n n — — -- Page # 3 Owner - Facility � McGui than trace aniounts and other debris? they operating property? ges through outfall 001 Yes il M M ,ecorder match the flow meter? D ased on pump log data, I A — --l- � �- -1 - -Ili- --.- -1 discharge. Outfall 005 - staff guage flow measurement Outfall 006 (metal cleaning waste) this outfall is no longer in use (there is no rnetal cleaning wastes generated at the facility), but has been retained in the permit, Eff luent S 419, Yes No NA NE Is composite sampling flow proportional? n n m c3 Is sample collectod below all treatment Units? ri D D D Is proper volurne collected? D D ID Is the tubing clean? 0 0 M # Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? (11 C' D is Is the facihty sampling performed as required by the permit (frequency, sampling typi,') representative)? vs D D 0 Cornt-nent: Outfall 001 utilizes time based composite samples for toxicity testing (see footnote 2 in permit). Duke Energy Enviromental Services conducts the composite sarnpling, Environmental Testing Solutions performs toxicity testing for all outfalls with toxicity test requirements, All other, outfalls require grab samples, Field parameter testing is conducted under field parameter certification #5156 which expires on 12/31/11. Paqe Ar 4 Agv-NmAj MCDENR �114 North Carolina Department of Environmentand Natural Resources Division of Aster Quality v rly Eaves Perdue Coleen H. Sullins ; . Dee Freeman Director V September 9, 2009 UCE H f ,° O 'E VICE PRESIDENT IKE ENERGY S LLC HAGERS FERRY Subject: Receipt of p "t renewal application NPDES Pennit NCO024392 McGuire Nuclear Power Plant Medderiburg County ar Mi. Hamilton: The NPDES Unit received your pernut renewal application on August 25, 2009. A member of the NPDES it w1U review your application They wiU contactyou if additional infonnation is required to complete your nut renewal. You should expect to receive a draft pertint approximately 3 - 5 days before your existing pertnit sires. If you have any adchtional questions eau renewal of the subject permit, please contact Serget emikov at 919 7- 393. Sincerely, Dina Slifinkle Point Source Branch S 1#&MMKMmMwJk*jpM#J*#*f/Surfiace Water Protection NPDES Unit it 1617 Mail Service Center, Raleigh, North Carolina 27699-1 17 Locathn, 512 N. Salisbury St. Raleigh, North Carolina 27604 One Phone: 919-807.6 00 X FAX: 919-807-6492 t Customer Service: 1-877-3-67NorthCarohna Intermt, www.nawaterqualfty,org An Equal Opportunity t Affirmabve Action prnp dyer ;Vatural& Duke Ppp" PokEneray. August 30, 2009 McGuire Nuclear Station 1 700 Hagers Ferry Road Huntersville, NC 28078 RECEIVED Mr. Charles H. Weaver Jr. AUGa 5 2009 North Carolina Department of Environment and Natural Resources Division of Water Quality NP'iJES Unit POINT SOURCE BMNCH 1617 Mail Service Center Raleigh, NC 7699-161 Subject. Duke Energy Carolinas LLC / cGui e Nuclear Station Renewal Application for NP ES Permit : NCB 002439 Mecklenburg County Record #: NIN006121 Certified Mails 7007 0220 0002 55314767 Bear Mr. Weaver: Duke Energy y Carolinas, LLC, McGuire Nuclear Station submits the following NPDES permit renewal application for NPDES Permit Number NC 0024392, which expires February 28, 2010. The attached permit application consists of 3 copies of the following documentation: l: EPA Form 1 2.. EPA Form 2C — including: locations of each o tfall a flow diagram showing water flow through the facility (see Appendix 1 description of operations contributing wastewater to each outfall average flaw from each operation where available and quantifiable the type treatment received by the waste water a listing of intermittent or seasonal discharges with frequency and flows analytical analysis for each outfall as required including Intake analysis a discussion of analysis performed d results (see Appendix VII 3. Additional information concerning the operation of our waste water system is included in the enclosed document entitled Supplemental Information For McGuire Page 1 of 11 > StatioAppefidiklt 4.Requested chemicals to be excluded under 40 CFR 117, Clean Water Act, Section 311 Exclusion. See Appendix 111. 5. A Topographical map showing the location of each outtall. See Appendix IV. o A Site Map showing the location of each outfall and other features of the site. See Appendix V. 7 A copy of the site's Sludge Management Plan. See Appendix V1 16 (a) Thermal Variance McGuire Nuclear Station requests continuation of its 31 (a) thermal variance of 99 DEG F for the months of July — September. The site currently has an approved lake monitoring plan in support of our 316 (a) thermal variance and we request continued approval of our monitoring -plan. A copy of the results of our lake monitoring program is sent annually to the Chief of the Division. of Water Quality. Should you desire a copy o the data submitted last year or more current data please contact Jahn Williamson by pone at 98-875-5894, or via e-mail at``John.Willi son@duke-energy.com. Corporate Name Change Please note the change in our corporate name from Duke Energy Corporation to Duke Energy Carolinas, L C. This is in keeping with the company's new business structure as a result of the merger with Cinergy. Requested Permit Changes McGuire Nuclear Station requests the following permit changes: Removal of the following parameters for Outfall 005 • Total Recoverable Copper • Total Recoverable Iron The iron and copper limitations were added to Outfall 005 because we anticipated that Chemical Metals Cleaning Wastes (CMCW) could be discharged from this outfall. We no longer plan on discharging any CMCW wastes ` to this outfall, so it is appropriate to request removal of the iron and capper monitoring requirements. We have toxicity testing on this outfall on a quarterly basis. McGuire Nuclear Station 316 JbIReview e would like to request that the current references to 31 n(b) be removed from our permit until EPA publishes a final rule can this issue: Page 2-of11 ppppp" Sludge Management Sludge generated during the operation of the site's waste water system is disposed of as indicated in Appendix V1, Sludge Management. Please review this NPDES permit application package at your earliest convenience. We would be glad for the permit writer assigned to develop our permit to visit the site and discuss our waste water operations with personnel who are knowledgeable with its operation first hand. If a site visit is not possible, we would be glad to come to Raleigh to discuss any concern or issues you may have. This permit renewal package is being submitted at least 180 days prior to the permit expiration date as required by NC GS 143-215, 1 (C). Should you have questions concerning this permit application please contact John Williamson by phone at 704-875-5894, or via e-mail at jcwillia@duke-energy.com. Sincerely, Bruce H. Hamilton Site Vice President Duke Energy Carolinas LLC McGuire Nuclear Station Attachments cc: Jeff Cage Gary Sain Allen Stowe Kay Crane G�� PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA I 77RU—MBER (copy from item 1 of Form 1) this Information on separate sheets (use the same format) instead of completing these pages, EPA Facility Name: SEE INSTRUCTIONS W0024392 NWear,Stuiflon OUTFALL NO. V- INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Form 24C) 0011 PART A - You must provide the re_ nits of at least one analysis for eve ollmant in this table. Gam ate one table for each anthill. See Instructions for additional details, — 2. EFFLUENT -c—LONGTERM 3, UNITS 4, INTAKE (optional) 1. POLLUTANT a, MAXIMUM DAILY VALUE b. MAXIMUM So DAY VALUE AVG. TA—LUE a, LONG TERM AVG. VALUE Ofaval") (if Available) d, NO. OF a, Concen- ti, Mass b. NO. OF ) a . (1) Conceran0k,11 {2) M. (1) concentration (2)Man ANALYSES tration (hconcentrallon (2) Mass ANALYSES 8, atodutralos Oxygen 2.0 484010 "19A 7b4) - —y < 2,0 42559S I Demand (SOD) -7 —2420DSO to b, chensew oww 7177 i Mail lb/Day 10 ' < 212797S 1 Oamwel (COD) c, Iota c 2.5-60501,3 1 MgA ---Ib—OSY 2.5 53-199.375 1 d. Totals Wended 4A I MgA --Tb— /Day 4,0 < 85119 1 soft (rss) a. Ammonla fee N) wk 0,10 < 2420,1 1 ingA lb/Day 0,10 < 2127.975 1 t now VALUE VALUE VALUE VALUE 29M -------- asm — 2560 24 MOD N/A 2550 1 -- Tempetatwo VALUE VALUE VALUE , VALUE --24 _DEGREES CELSIUS NNYAME"Mm 730 Totpervft" VALUE VALUE VALUE VALUE aneaerMM L4 CELSIUS PH MINIMUM MAXIMUM MINIMUM MAXIMUM _DEGREES . I STANDARD UNITS 710 FrAwr 6 - Mark- "X" in column 2a for each pollutant you know or have reason to believe is present. MarkX"in column 2b fore pollutant you believe to be absent, If you mark —column 2a for any pollutant Mich is limited either directly or indirectly but expressly in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge, Complete one table for each ouffall. See the instructions for additional detail and . ulrements. I. POLLUTANT 2. MARK 3,EFFLUENT 4. UNITS 5. INTAKE (optional) AND CAS NO, Belta-ved a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG, VALUE a. LONG TERM AVG, VALUE (savailable) apre- lbeb, -me (it avaRat") (if avaflaNe) d.NO. OF a. Cancer- b. Mass b, NO, OF sent se is (1) C 0-firwoon— {2) Mass (1) Concenbadon (2) Man (1) concentaw. (2) Mass ANALYSES tration (1) Cor"nitation (2) Mass ANALYSES arom de X �TW'f 0,20 < 4840.1 '1 MgA lb(Day 020 < —4255,95 1 aces s7-s3 b, Chlotift, X 777 < 7 484,0 --�-08—yrW "nut Q. < 425,595 1 Total Resi" ---77- Clow x 10 N/A —NIA WA Std Units NIA NIA d, Fecal X 2 < N/A NIA N/A i Colones NIA NIA I COU" 1100 M1 --- ----- ------ C S1 --; —212T975 010 i f elwate� X 016 3872.1 1' mg -NA IbA)ay 0,1* 2979,165 1 settle (- N) EPA Fenn 35104C (Rev, 2.86) PAGE V-1 CONTINUE ON PAGE V-2 EPA I.D. NUMBER (copy fi ITEM V-8 CONTINUED FROM FRONT NCO02 uotear Station 1. POLLUTANT 2. MARK ^ ^ 3, EFFLUENT 4::UNITS 5. INTAKE (optional) AND CAS NO. Believed ' a, MAXIMUM DAILY VALUE b. MAXIMUM 30'DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE If available) a.pte b.ab- (if ava8abfa) {d available) d: NO. OF a. Conoen- b. Mass b. NO. OF sent sent. ANALYSES`Vatlon ANALYSES.. (1)Conaeratijon (2jmms {t)Ctmcsmra8an '(2D54ass {1)Cir stun ': (2)A9ass {f)ConeaMration (2)Mm atst Org# c A 12100.3 111 mg -NA `lb/Day 0,50 .'.:< 1039.875 1 a cease A 5,0 121002.5 1 mgA Ib/Day < 106398.75 1 asp onus {asp),Total A tD.010 < 242:0 i"' m9_P/ I6tDsy, N; 0,01q < 21 :7975 1 ------------ Radioactivity T-Pwal T star A 5,00 < NIA N/A N/A PCIA NIA � - 'S:t#D' :. < NIA + 1 ami X 15.07 < N/A /A ::. N/A * '('; '; PCU1 'N/A. NIA 1 Total A -l. 1.07 < N/A N/A N/A '...'1 ',' . PDA NIA ' 13)(111, NIA 1 4) a ,TWaIs1.('N1'.< NIA -N/A N/A ) ,,'�! '.' PoA:. N/A ^. -1..00 < N/A :. 1 as $04) 6.4, 130682.7fb/DayA . .. ,m9A . . 117038,625 ,1 1480&79.8) a 110, c 242005 < 1- m9A ' #k ay ; y, 1,0 < 21279,75 1 as S03) A 1.0 < 24200.5 1 mgA ' ib/Day 1,0, < 21279.75 1 14266-:5-3) urtaatama" A ,"�° '.0.12 29041 '' ;1 mgfl lb/Day . ,�,, ., tJ. 1458.30275 `; 1 Total X a,.a E7.050 A� < 1210.0 .1 mgti lb/Day 0.050 - <: 1063.9875 ;: 1 7429-WS) edam.:: otat A . �-1 10:0 1 mgtl Ib/f.Day 0:050 c 10fi3.9675 1 44b 39-3) .. TOW 0.0m 1669:8 .1 m9A Ib/Day %;; 0,075 1595,98125 : 1 atal X 0M20 < 484:0 1 mgA - Ib7Day Al0.020 < 42&595 1 7440484) one 7439-89-6) A ) i0.051 1234.2 t mgA Ib/Day „7" "4 MOM, 1085:26725 ': 1 ''.Total A , ""„ 1.90 45981.0 _ . 1 m9A _:: fbtDay , ;; 1,90 40431.525 [' 1 7439.96-4).... amen, otaI A 0.020 < 48CO ... ,: 1;' .: m A lb/Day 0.020 < 425.595 1 sageness, �< ofal A . `0.010 , 242:0 1 . .: m9A. VDay O �t10 < 2121975 7439-9") n, ate 7440.3t-5} A ,'�� ,mo10 < 242;0 3 m9A ib/Day Q01d - < 212 7975 1 L14-6) X ,� ,€i. s i21t#0mgA lb/Day ,0: 1063.9875 :: ,1 -: . EPA Forth 3SM2C (Rev. 2.46) EPA J.D. NUM R (cs CONTINUED FROM PAGE 3 Of, FORM 2-C NO McGuire Nuclear Station ILL # # • . i'�iui U►�'''1' ""� 1 Y� C"�i'�rK���yt • "e wgTl"MeIY'[I�^1 l"'ry=. el�a'1: X c O.Qi t70 P6gfL. Intake < 0:0100 ngtC. EP . (Rev. 2-85) PAGE V-3 CONTINUE ON PAGE V-4 EPA I.D. NUMBER (capyfro CONTINUED FROM PAGE V-3 I N O0243 Nlcuire Nciear Station � • , 'Yi4y "11'4 iur �" V! '{h Y"iY �"i r� � u,Y '�a �i�� " W �W� 9�Irl 9I�1�1 �� i +il't4� "w.�!.Wkr�' f. '+�: • s � �e��'����r�ii����w���i�i��. .. ter, %� ��� � is ������������������������� �� « � + w.•� ���' ' I MOM PAGE V3 CONTINUE ON PAGE V4 „� �• 1 ° x x x xX x x x X x x X x x x x x x x x ci a a, O €n w ha na ps {a a »a a nz n ns O cw c a cs c cn t> ca ea+ is ca cx G cr to A A A A "A A A A A TAA A A' A. A A A A A A A t7 a n na na �i Ax Ms nt �i ea !u � 9 fiJ G7 fin. Gt G�7 Cam? k} O ^.. q m a � m m to N rn hk PJ.. N N PoS Ri 1k5:. hR N ht �,�+ cn 0 N s a A A A A A A.. A A A A A A A A A A A A A A A N N !p0� of N Chi CY O 66 t7 ico OS O? OS GtS 4k Oi {A W Ckk W 1OZ6, EPA I'D. NUMBER (copy from Item 1 of Farm 1 €)U7FALC NUt Uulear Station- � r . .:, VI�r�!" WNT i"111� ylv' Mr�l . M "�" �'If� a i�•w 'f�!�; Vie' �y� ;.�� �t�Mti a=� ,��4 :.wE�r�rue �� � i': �����M���L®■� � ��Ili������������������lll���l���l����ll���������� x�. � � ���i�ll�l����� 1 ♦ R.. 1 III :t I i III r f :t .. . e � 1 I I ♦ i. i :i EPA Pmem 3510-2C (Rev. 246) PAGE V4 .. _ .._.. _ .... __.__ _..._w_....___..._._� CONTiNUEON PAGEV_y EPA M, NUMBER (copy from 6tem 1 of Farm 1 OUTFALL NUS CONTINt IFf) FROMPA I V_F, NC:nn9A'A( nm McGuire; Nuclear Station � DAILY VALUE Ii" �M c� i�a • e Is��aY" .at"� Y.I[ �?� � e� .. F ! Yla ! " + EPA Poem 8510<20 (Rev.2 95) PAGE V-T CONTINUE ON PAGE V-S 0 0 z tti z C mmma SOMME 0 mmm 0 m MEN mm m 1■�11�1■ IY 1■�1■1 ie EPA C.D. NUMBER (copy from Item 1 of Farm TFALL NUMBER CONTINUED FROM PAGE v-8 N O0 001 r McGuire Nuclear Station 1. POLLUTANT 2. RK ")C 3. EFFLUENT 4, UNITS 5- INTAKE (optional) AND GAS NO, a:re- sehevad a. MAXIMUM DAILY VALUE b:'MAXIMUM 30 DAY VALUE C: LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (If avaNabte) quk- tr.pro- crab. :':pt avaAable).. (if eva4ahle) d. ND. (7F 2 Cottcptl b. MASS d:.N4?. OF ed. sW wt (1)Conee aHon (2)Mass (I)Concenraen : (2)Mass : (1)0 atiori (2)Mass ANALYSES traton (i}0ancenVYaGon :. (2}Maas ... ANALYSES.. GC/MS FRACTION - PESTICI 3ES (continued) 17P. MeptachWr pmdde X < 0,025 < 0.51 1 ug1L Ib/Oay < 0.027 < 0.65 1 1eP.PCs-1242 x < 0.25 < 1 ug/L ItlCiay < 0.27 < 6.53 1 53469.21-8) isP. PCB-1254 X < 0.25 < 1 ug/L IbtOay c 027 < 6.53 1 TiQ97-G41} P. Pes-1221 7t < 0.25 < 1 ug/L lb/Day < 0,27 < 6.53 1 1P.PG84232 X < 0.25 < 1 ug/L lb/Day < 0.27 < 6.53 1 P. PCS-1248 X < 0.25 < i ug/L 1b/Oay < 0.27 < 6 53 1 . 3P. Pos•t26i1 X .. 0.25 . < 1 uQlL lb/Day < 0.27 < 6.53 . 1 4P. Pos 016 X < 0.25 < 1 ug/L IbA ay < 0-2-1 12674-11-2) 5P. ioxaMme X < 0.25 < 1 ug/L IbIDsy < 0.27 < 6.53 1 60t11-35-2I EPA Fwm 3$16-20 (Revv.2-E5) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of EPA LD, NUMBER (copy from Item 1 of Form 1� SPA Facility Name: this information on separate sheets (use the same format) instead of completing these pages. CPF INRTPI H".TItiN "; AtCrtil'S i"tL1? <Nwd s.9.ww Jut.--- f-41 ..e OUTFALL NO, V. INTAKE AND EFFLUENT CHARACTERISTICS (continued from page 3 of Farm 2-) 002 PART A - You must ' mvide the results of at least one analysis for every pollutant in this table. Complete one table for each ouiiall. See instructions for additional details. 2. EFFLUENT 3. UNITS 4. INTAKE (optional) 1. POLLUTANT a, MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c: LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE (if avadame) (if a -table) d. NO. OF a. Concen- b. Mass b: NO. OF (I) canaentraton (2)Mass (t)Coneentraton (2)Mo (1)(2)Man ANALYSES tratian in Concentration: M)Mo.$ ANALYSE .. moahemicai OxNan 7,2 37,3 1 mg/I IbfDay ' wand (floc?) chemical 04geng,„ ' 11 57.0 1 mgfi lb/Day Demand (COD) a Total Ckga W 4 20:7 # mgA lblC7ay 4! . 7777 Cerium (IOC) d Total Suspended ;; i 4.0 a 20:7 5.6 15.7 14 cdA lb/Day ,, ., . -... . �. ; - oRds (rSS) . Ammonia (as N) 6.9 35;8 1 mgtt Ibl(3ay .Flow VALUE VALUE VALUE VALUE 0.621 - 0,621 0,336 24 MGD NIA . Tempnratuie VALUE VALUE VALUE VALUE water) DEGREES CELSIUS .'re lure VALUE VALUE VALUE VALUE summer) 1 DEGREES CELSIUS pH MINIMUM MAXIMUM M)N)MUM MAXIMUM 7.9 42 STANDARD UNITS PART B - Mark "X" in column 2a for each pollutant you know or have reason to believe is present. Mark "X° in column 2b for each pollutant you believe to be absent: If you mark column 2a for any pollutant which is limited either directly or indirectly but expressly in an effluent limitations guideline, you must provide the results of at least one analysis for that pollutant. For other pollutants for which you mark column 2a, you must provide quantitative data or an explanation of their presence in your discharge. Complete one table for each-outfall. See the instructions for additional details and requirements; 1. POLLUTANT 2 MARK W 3. EFFLUENT 4. UNITS 5, INTAKE (optional) AND CAS NO, seiieved a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE o; LONG TERM AVG. VALUE a. LONGTERM AVG. VALUE da"llable) avroa blob- (ttavailable) (Itavow ) d. NO. OF a, Coneen- b. Mass b: NO. OF Sent sent (1)Concentration (2)Me" ruconcentraton :. (2)Moss (1) concentration (2)Mess :.ANALYSES tratian (1)Concermaton... (2)Mass... ANALYSES Bromide X 1f0 1 mgd - IbXt3ay 4959-R7-9}. . Chlorine, ' X % 0.020 < 0.1 < 0.04 < 0.1 12 mgh ` lb(Day ..7 otat R-Wual Color X t tad 25 NIA N1A NIA 1 Sid, Units NIA . facet X w ,- 92, NTA NIA NIA 2 Colonies N1A ofiiorm- P100 ml fNadda X 0.10 a 05 1 mgtl }blDay r,' u : tssaa-as:e) Nk ate X 1.0 5,2 1 m -Na 1btQa itme (as N):.. (Rev. 245) PAGE V-t CONTINUE ON PACE V-2 EPA I. NU BER (c o from Item 1 of Fotm OUTFALL NUMBER ITEM V-B:CONTINUEL FROM FRONT NCO024 92 0( POLLUTANT AND CAS NO w. 2-86) PAGE V_2 CONTINUE ON PAGE V-3 EPA l.D. N7=0024=392 it 1 of Form OUTFALL N MEER CONTINUED FROM PAGE 3 OF FORM 2-+ 002 PART C - if you are a primary Industry and this outfall contains process wastewater, refer to Table 2c-2 in the instructions to determine which of the GC/MS fractions you must test for. Mark "X" in column 2-a for aft such GC MS fractions that ripply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outfalls, and nonrequired GCtMS fractions), mark W in column 2-b for each pollutant you know or have reason to believe is present. Mark "X" in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant; you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysts for that pollutant of you know or have reason to believe It will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, scrylonitrile, 2, 4 dinitropherrol, or 2-meth", 6 dindrophenol, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater, Otherwise, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each oufall: See instructions for additional details and requirements. 1, POLLUTANT 2. MARK "X" 3. EFFLUENT 4: UNITS 5. INTAKE (optional) AND CAS NO. a.re- aefleved a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. -LONG TERM AVG. VALUE a. LONG TERM AVG, VALUE I (if available) , quiff- b.pre• c.ab- (if avaflablej to available) d. NO. OF a. Conc n. 1b, Mass d. NO; F I ad sent "ot :0)Concantration (2)Mass (t)Concenbation (2)Mass (1)Concentration:. (2}Masse ANALYSES iration (t)Concamratlon (2)Mass ANALYSE METALS, CYANIDE; AND TOTAL PHENOLS tM. Antimony, X" - :: S0 4 0,03 1 ugA tblDay k' „, ota (7440 3s o) . Aroimic'Total X: i &0 -< 0.03 1 Ugil.... IbAJay 440-36.2} 3M Beryllium, X To < 001 1 UgH otat (7440414) M. Cadmium, X 0.1 < 0.00 d ugA , lb/Day `' ,2 otal(7440-43.9) M. Chromium, X A10 -, r o.03 1 UgA lb/Day Total (7440.47-3) M, Cappev, Total X ...' t3 0.0 # .. '. mgA ibtDay.,,.,. 7440-50-9):. M. t,eed, Total X '.2.0 < ool l ugA. IblDay F'.. (7439,92-1) BM. Mercury Total X ; 010 0.00 1 UgA... IbrDw SM. Nickel, Total X. ,' 10 < 0.05 '. 1 ugA. lb/Day,. ' 7440.02.0}. .. _.. 10M. Solarium, ,X .5,0 < 0.03 1 ugA" IbID2y * 1(7782-45.2) 11 M. Shot, Total X 5.0 < 0.03 1 ugA iblDay � 440-22-4) 2M. Thatium, X '.A . 0. 50 < 0.0 1 mgA tttA3ay otat(7440.28-0) 13M. Zinc, Total 01010 < 0.05 l mgA lblDray 7440-&6.6) 14M Cyanide, X ,�..,. 0.010 = 0.05 l Iry lbA)ay . vtal (5i-fk5) ,. ISM, Phenmis, X poll o::fi LOU-, DIOXiN ,3,7e Tatra DESCRIBE RESULTS oP < 0.0 100 nglL X (Rev. 2-05) PAGE V•3 CONTINUE ON PAGE V-4 •«I! - CV:MI+a' a �muui •TFALL NUMBER NCO024M on »# ..� r a ,. Ip�r!"iP i. 7* Y1V.VIY S" YY e'r'�tl.°I+"1.N."� "»Mt ri+►� 1r�M li"�� .T .�� to 4� • 1I6��r��i rklll'�i4'N 1Y�; �" r� r i'V��w"'1hI'' : ° • +� "..�;'� r Pd X�:1'i�':; .. X -. •. w� . •. �� « « e a r i u ec i e + M e e a 5 rw. PAGE V 8 N U Ul «N Z "h LU <. v w U. n {. di r+ w V Y N Y � O O t] G? C1 � Gi KJ KS Gd Ci O Ci C! t3 Ci N a• tt �f--.'. �Y �''v� L Y �. uj Y V Y V V Y Y V Y Y Y Y Y Y p y ii N d N W x X x X }f C C to C S fig. h 117 Q w �Q ,- t ('? : qi $ td ... °S a: o; +3: G: teS ,y :C. u, tv: u. ci ' c a'. T a0.ww r M ,�., v '" EPA LD. NUMBER (copy frorr CONTINUED FROM PAGE V 5 NCO0243' on 0 s. low I EPA Fwm 3510,2C (R"- 2-85) PAGE V-9 PLEASE PRINT OR TYPE IN THE UNSHADED AREAS ONLY. You may report some or all of this information on separate sheets (use the same format) instead of completing these pages. SEE INSTRUCTIONS r7�57�NC0024392 opy from Item t of Form 1} EPA Facility Name: 06040Nudear StWon r s EFFL POLLUTANT i # +' ! • N' : � i �� ! TI c' T4'.I I * I °�' I e' , . �� . GYM►;I �119 W Im 1 a;:-,.., ra . ^r - a r ... Y ...a... . . Y.. Y..Y :Y Y.. •.. Y.. .... : ..-.:.c-.. . Y. as a Y... ,.♦ p Y r Y a r Y^ f ... Y. :. r .:. Y . ,:.f r f:.. .. a... f a. Y:.. •.- Y - :. w,.. Y .. ♦ ,. ... a.. '♦ +aY '.Y f- a. r . . + { „Y 1 aI ' DAILY VALUE ��,���* �.( A4c Ta.II,S' EPA Farm 510.2C (Rev. 2.85) PAGE V4 CONTINUE CAN PAGE V4 EPA i.D. NUMBER {capy from Item i of Form OUT ALL NUMBER ITEM V-B CONTINUED FROM FRONT N O024392 005 1. POLLUTANT 2. MARK x" 3. EFFLUENT 4. UNITS AND CAS NO. Ea3eved a. MAXIMUM DAILY VALUE" b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG. VALUE a. LONG TERM AVG. VALUE "(it 8aa4abla) a.pre- b,ub- of avallable) (If ava4able) d. NO. OF a. Concen• b. Mass b. NO. OF (t)CanOanteation (2}Hasa (i)Cunaenttaton (2)Mass : (t):Con—Gallon'. (2)Masa. ANALYSES sent suit tration {1}C `on {2)Mass ANALYSES Total Organ&i A ': Mtlq < 38.1 1 mg -NA lb/Day .. ;. `.1. 04 and "ease A :M .&0 < 381.4 1 mgtl lbA)ay as P), Total. A _ 'A020" 1.5 1 mg -PA Ib[Day 7723-14-0) Radioactivity ) ofa9 A i'&Ed' c NIA "NIA NIA i pCdl- NIA Beta, Total A < NIA NIA NIA t pCilF NIA :. .;,.. Total - A . :� i ota ' " < :NIA NIA NIA 1, PGL4 NIA 226, Total A.:NBA :NIA NIA 1 pCin NIA , to as804) A 5. 434.8 1 mgtC 1b0ay e as S) A i;U c 76,3 1 mglf ` lb/Day 0$03). A „� f i,i€`", ;" < 7&3 1 mg!): lblDa y 14265-45-3) . eta ft A U, 4:9 1 mglt Ib7Day minuet; Total A , .,.' `,O' 5:f3 1 mgtt tb?Day FL `(7429-WS) Total A 0, < 3.6 i mgif VDay , l 44Cs-39.3) '. . Oran,:: ote A : .. •a �, ;0 < 18 1 mgn lb/Day R 440-424)FrOT. ---- a ,. Total A 0,020 < 1:5 .. 1 mt�It .. lb/Day '�° .. 7440-484) . ron. O-ts (743"9.6) A 4,230, 17.5 0.242 1.7 14 mg1l lb/Day 1012 agnesann, 439-9$-4) datciim, otai A 4.tI2U' < 15 1 mgn lb/Day :'. (7439.99.7).. :. . anganese, Total A i3.0i7 5.9 1 mgn lbt0ay 439.965). i O 440.31.5) A 0,010 < OA i mgfi lb/Day Total A n. i. < 3 .8 `1 mgA thfDay , ✓440.3'X-3) EPA farm 3910-20 (Rau, 2-05) PAGE V-2 CONTINUE ON PAGE V-3 EPA I.D. NUMIl3ER (copy from item 1 of Form UTFRLL NUMBER CONTINUED FROM PAGE 3 OF FORM 2-C N O024392 1 005 1 McGuire "Nuclear Station PART C - if you are a primary industry and this outran contains process wastewater, refer to Table 2c•2 in the Instructions to determine which of the GCIMS fractions you must test for. Mark "X" in column 2-a for all such GC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total phenols. If you are not required to mark column 2-a (secondary industries, nonprocess wastewater outialls, and nonrequired GCIMS fractions), mark "X" in column 2-b for each pollutant you know or have reason to believe is present. Mark "X" in column 2-c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppb or greater. If you mark column 2b for acrolein, acryionihile, 2,4 dinitrophenoi, or 2-methyt-4, 6 dinitrophenot,-you must provide the results of of least one analysis for each of these pollutants which you know or have reason to believe that you discharge in concentrations of 100 ppb or greater. OtiieBse, for pollutants for which you mark column 2b, you must either submit at least one analysis or briefly describe the reasons the pollutant is expected to be discharged. Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outfall. See instructions for additional details and requirements. 1. POLLUTANT 2. MARKX' 3. EFFLUENT 4. UNITS 6. INTAKE optional) AND CAS NO. =axe-selle"da. MAXIMUM OAII Y VALUE b. MAXIMUM"30 DAY VALUE c. t:ONG TERM AVG. VALUE=C.n-n-b ;,a.LO;NGTERM AVG. VALUEr mvaffa> w} (r avaltat ta) (f ova table)' tl, NO.OF d: NO, OF (1) Concentration (2) MM (1) canaentration (2) Me. (1) cor oeru aPia» :: (2) Mo. ANALYSES tion (2) Mass ... ANALYSE ... METALS; CYANIDE, AND TOTAL PHENOL$ i M, Arriimcmy, - X ' i 0.38 1 ugA . IbtDay 77777777 7 otal(T"0-.36-0) . Arsenic,Total X - , 5.0 0.38 1 ugA IOiDay ; 440-383). M. sogwuraC X '-1.t2 < 0.08 1 ugA... Ib/6ay R,,, , '..Total (7440.41.7) M.Cadmium, ;t -' 'I a 0.01 1 ugA 1blDay 461 Total (744043.9) 5M, Ch€ormum, X :.ar.0' . < 038 1 u9A lb/Day '' * � : * �- 77 ,n otal((7440.47-3) M. Copper, Total X b"OoSit,< 0.38 0.00052 000 !, 14 mnA lb/Day ,;,,; 440-50.6) , M. Lead, Total X 2.0 < 0.15 1 ugA 4b/Dap 439.92-1) ~ .-.. sw Mercury, Total X 0,10 < 0.01 1 ugA tbA3ay 439-974): , M. Nmkel' Total X f0 , < 0.76 1 ugAr )b/Dey 16M selenium, X 5.0 < 0.38 1 ugA Ib1D y '' . otal(7782-49.2) ra .. e1M. siren, Total X a.0 < 0.38 1 unit 06ay 7440-22.4)`.: '.12M Thallium, X ,., b. St) < 0.0 1 mnfl lb/Day otal(7440-28-0) 13M. Zinc, Total X aofo < 0.76 1 mgA lb/Day 1 7440.66-6) [DIOXIN Cyanide, X :0.0f0 < 0,76 1 mnA lbmay <IE 57-12-6). phenols;. X 6, 0.4 1 - mnii lb/Day 8 TetraDESCRt6E RESULTS P X <0,0100 ng/L (17s4.01.6} EPA Form 3510,2C (Rev. 246) PAGE V3 CONTINUE ON PAGE V-4 a 7EPALFRU�MBER:(copyfeom Item 1 of Form OUTFACE NUMBERCONTINUED FROM PAGE V O024392 005 McGuire Nuclear Station 1. POLLUTANT 2, MARK"x" 3. EFFLUENT 4, UNITS 5, INTAKE (optional) AND CAS NO, a.Pa Behevad a, 1MUM GAILY VALUE b. M 56MUM 30 DAY VALUE c, LONG TERM AVG. VALUE a. LONG TERM<AVG, VALUE davatlable) q*- bpra- c.ab- INavaifable) I (itavabble) ----I d. NO, OF a. Conaen- b. Mass ---]ANALYSES: d. NO. OF ad sent sent (Y)Conaehtr000n (2)Maas {t)Cancantratian {2)Mass {1}:Goncen -- (2)me- ANALYSES tration I {t)Concantratian (2)Mass GC1MS FRACTION - VOLATILE COMPOUNDS IVAaOWM9 " ugh WIDay . Aaylooitrde X :" `; S;6' < 0.3e V ugfl tblDay V 8arttana X 2.0 < 0.15 1 ugA lb/Day rr� 143-2).: V. als (Chbro- V aromot'onn K 0,1$ 1` u g A IbAiay „.. . Carbon etrnahlodde X 2.0 < 0.15 ugA lblDay - -Chlarobenzene 3( 0.15 1 ugJ(- itlDeq " � omomethans X OWN �,-2.0: a 0.15 1 ugA Ib10ay Chloroetha X ';,2;0, < 0.15 „ -! - ugfl 4b1G)ay rs-oo.a} 10V. 2-chkno- nylEher X" 5,0 < 0:36 ugA lb/Day ,. Ytv.chloroform x 2.0 < 0:15 1 ugA IbA)ay romomalharro 7t ' +;2.tF < :015 1 uOli 161G2ey - 5.274) ' 13V. = .. iWoramathane X ,.� ,� 2�0 ,,, �< 015 ; 9 u lb/Day Y t , 14V. t,1d}ictilow k .w ,,2,0 ,,:. < 0,15 ? ,. ugA" lb/Day ....., .` ,.. thaoa (75-34:3) " 1W 1.2-0icFibw X 2.0' < 0,15 1 ' ugA IbiDay lev, 1,10chbr0- X �4 < 0.15 ugA::. IfatDay Moytane (75:364) 17V.1,2-DWOo a- 7{ , . :. ZO < 0.15 ' .'.1' ugAY .. IblDa 15V. 1,30chkno- X-'< 0-15 , ....1 ugA tbrcmX ; e. :', ', ." .. rapylana {sat-r5ax) '.Y9V,EUybeniene dE �, .0 .'::'3 < 0,15 "" 1 ugA ' IbMay ..... . ,`. w Maw X 0.15 , ugA tbtD y rode (74-83 0) 1V. nmethyt X T 2 0 ' ' < 0A 777 ugA IbfDay ' aMe (74.81-3) EPA Form 35 W2C (Rev. 2-85) PAGE V4 EPA LD. NUMBER (copy from Item 1 of Form OUTFALL NUMBER CONTINUED FROM PAGE V-4 N (0 4 QCiS 1. POLLUTANT 2. RK ")C 3. EFFLUENT d, UNITS AND CAS NO. a.re> aaj-d a. MAXIMUM DAILY VALUE b. MAXIMUM 30-DAY VALUE c. LONG TERM AVG. VALUE —4-ete) qdr- bone. c..b- I (rF a -#able) Of avallable) : 1, NO. OF a. Cancan-1b, May$ (1)Conscntradon (2)Mass (1)ConeenV tl. (2)Mass (Y}Concentration (2)Mass : ANALYSES. ed sent seat tration GC/MS FRACTION w VOLATILE COMPOUNDS (continued molftone ,, 0,15 '� .f" ugA Ib/Day , . 3V. 1,1,2,2-Tetra- roehane X C},. ' < 0,15 ugA' IblDay � :> 4V. TelraeMoro. X , :. ,(i . , e 0.15 . � ,,1, a , ' UgA IblDay 'r.,; , lhylone (127-t8-4) ugA lb/Day tlaa-eea) .1,2-Tram oed�lone, X .6 `-. ' <' 015 ,. '1 ';,," ugA lb/Day a a 7V. 1,1,1-Tri- oelhane" X. k* !. 2,d '. � < 0,15 .., ,0°9� :.: UgA lb/Day oraethane X 05 # UgA' lb/Day V.Ttwwo- X A < 0.15 $ `' ,.`> UgA : Ib/pa y172 ne (i9 Yr1-&) V. Trichloro-: omethana X „ r � ' , '2,,0 < 0.15 11 u9A lb/Day A 31V.Mr'A X w '.'1.0- < 0.15 1 ugA lb/Day u� Me (75-01-4) GC/MS FRACTION -ACID COMP0UND5 1X2-Chlorophenol X '''10, a c 0.76 2 ,' ugn lway 2,4,achlara- X . , :'<1(j , < 0,76 ,''2 UgA IbID;y henol (126-83.2) 2,4-am x: . , xo < 0:76 u m/bay onoi (1ti5-87-9} .4„60ndro-03 X t0: •: < 0,76 ; 2 UgA IbIDay esni(534-52.1) .2, X . < 1.81 - U9A Iblbay . hen(A(51.28:) A 2 Flk o(d snot X 104� x 0:7$ "'.; ugA ' }bJCNay A.4•Nbophenni X " 10 ; ' < 016 . 2 UgA IbJDay 1UW12-7) BA. P Ch a o-M- X itF' < 0.76'. ;" U9A IbiDay - resol (wso-.7) A pentachlow X 90 ;`, < 0.76 7777 UgA IblDay tan. Phenol X' 7 ' :'itF '7 a 0.76 7, r: U9A '. lb/Day are l X". ; -1ifi, < 0.76 u9A I �y EPA Form 3510-20 (Rev. 2.55) PAGE V-5 SPA I.D. NUMBER (copy ircm teem UTFACE NUMBER CONTINUED FROM PAGE V-5 :10 �Fortmn NCO0243J2- 00 I.POLLUTANT 2. MARK ")(" 3. EFFLUENT 4. UNITS ND CAS NO. ale- Believed a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE e. LONG TERM AVG. VALUE (f ava labia) ' qwr- b.vre- I Ceti: Id.NO,OF a. Conran- b. Mass ed send sent. (1)Concaritra9on (2)Musa (1}Caicontratlon (2)Mass {i}Canoanha8orr (2}M ANALYSES. tra#ion GC/MS, FRACTION - BASE NEUTRAL COMPOUNDS 18, Aeanaphthana XugA tbfDay ^,''?' .. B. Aeanaphtylana X 10 0 76 2 ugA lb/Day 95-9j a. Ardhraeena X " 10 0.76. ugfi lb/Day Y2o-12-it B. BenaJdine X 100 r 7.63 2 ugfi tblD--y 92.87.5j 58, Batten (aj Gene X "'." �. 10 < 0.76 2 " ugA IWbay ss-5xai W senzo (a) X 10 < 0.76 2' .: ugfi:. IbiDay ' 8. 3,4-eenm ftexamthane �.. X . 10 < 0.76 : ugtl tblDay 0& Benzo X ' '10 < 0.76:. 2 ugA lblDay . +xiytana (191-24-2) 8. Benzo (Ic) :Fluoraffftne X 10 < 016 2 ugA — 15CDay "... ` . 1tl8, Bis {2-CAlnra ethoxyt) Methane X 10 < 0.76 2 ugfi tb0ay , t YB. Bie Ether X 10 e 0.76 ugA ugA IbMay 128.Bis propyo Ether . X 10 < 0,76 2 ugA " Ibl)ay ,.x 138. 8ts (2-EUry4 erryla Phehatate X s " � 10 < 0,76 2 u 9A Ib1Da Y <. 148.4-Bromn. PhetrA X 10 < 0,76 2 ugA IbA)ay i ther (101-55.3} 458.8utyl Ben;rA X 10 .. < 0.78 2 - ugA tb/Day MhalaYe {8S&8-7} 768. 2-Chiwo-: 'aph Wone X: 10 < 0,76 2 ugA lb/Day (91-60-7) X ` 10 < 0.76; 2 ugfi lb/Day {709S-72-3) t68. X ' + e 076, 2', ugA Ib/Day,. Yffi-SSY-9} 98 o(a,h) X 10 < ugA lb/Day 53.70.3a 208,12-Otd m. X '.2,tY < GAS ugA tbfDay eras (9540.1) ugA Ib1Day * benzene (541-43-1) EPA Form 3SW2C (Rea. 2-0) PAGE V-6 EPA I,D NUMBER (copy from Item 1 of Form UTFALL NUMBER CONTINUED FROM PAGE V-6 N O0 43 2 00 r 1. POLLUTANT 2, MAR 3. EFFLUENT 4. UNITS AND CAS NO. al BeF.vad a, MAXIMUM DAILY VALUE b. MAXIMUM 3 DDAY VALUE c, LONGTERM AVG. VALUE if avaUbie) qun- b,pre- c.s6- (f ay.We) @f "Mubte) : d. NOOF.. $. Canca (1) Doneatrba$on (21 Masa (r) Cbns.nba$on (2P Masa. (r} $on (2} Maaa .d aeM sent :ANALYSES tratran GC/MS FRACTION - BASE/NEUTRAL COMPOUNDS -(continued} :. 29, 1,4-Dicrrrsrw X RW.: 2.0 0,15 1 ugA ibA3ay emene (10646.7) b 3a. 3,30cbrnrw enzrdhe X 10 a 0,76 2 ugA db/)ay sr.s4-t) 2 4B. Die#iyr Phthalate ,X 10 < 0.76 2 ugA lb/Day 2 58. DimeUiyl ht,aiare X 10 < 0.76 2 ugfl lb/Day ' ate X a,. 10 < 0.76 2 ugfl IblDay 78. 2,d-0r**- X 10 < 0 76 2 ugll IbIDa y. WIN rre (12i-f4.2) 2 $8. 2,6 DkBUp- X- , 10 < 0,76 21 ugA lb/Day luene (6tl6.20-2) P hthatate X 10 < 0,76 2 ugfl lb/Day rr7aa-o} .1,2-1*hen* hydmzine Azo- X 10 < 0,76 2 ugfl IbJDay 18,Fboranthene X; '10' e 0.76 2 ugA Ib1Day 28, Fforuerre X u4�., 10 < 0.76 2 ugA y Ib1Da 39. Wexachlo - X u 1Q 076 2 ugA tbipay 8. Wexw .. obutadiene X 10, < 016 2 ugA IWDay ...�., (87-68-3) 58, WoxM.Marw cYclopentadlene X ` 10 < 0,76 2 ugfl lb/Day'.. 1' e 68. Wexa.hioro ?C . . 10' < 016 2 ugA ; 1blDsy thane (61-721) 79, lndeam:... 1,2,3-ed) Pyrem X to' < 0.76 2 u,,,p IblDa $8. Ia.Pt aon. X 7710 < 0.76 2 ugA IblDay 90, Na ten. X W,, 40 < 0.76 2 ugA IbA)ay ar•203} B N zene X 0.76 2 ugA IbAOay one X 1Q„' e 0.76 2 ugA IbtDay 62-75 9) 8 N-ftosod- .mina X 10 F 0.76 2 ugA fWay :EPA Form 3510-2C (R", 2.55) PAGE V4 EPA I.D. NUMBER (copy from Mein 1 of Farm OUTFAL L NUMBER CONTINUED FROM PAGE V-7 N O0 43 2 OD5 1. POLLUTANT 2. MARK ")(" 3: EFFLUENT &: UNITS AND CAS NO, a,t aanaaad a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONGTERM AVG, VALUE it ndabtep . qurc- led. bMw cols:- (fta-Howe) {it auaRab#e}. d. NO. CiF- &, COncen- b. Mass satN sent {1) Cooceeihattan {2p Mass {tj Cancentratlon - {2) Mass {I) comw*abon :. (2) Maas JANALYSESitrabon GCIMS FRACTION - BASE/NEUTRAL COMPOUNDS((continued) ofthenylamina :X 10 < 0.76 2 ugA Ib/Day e6-30 6p - 49. PhenaMkirana X.. 10, < 0.26 ugA tb/Day 56. Pyrene: X 10 " < 076 2 ugA 01)ay ,,; 777:" aas-na�ip tMbenzar* x .. , 15 ugA lb/Day .... '12A2-1p GCIMS FRACTION - PESTICIDES 1P.Ndr7 X X: < 0.032 < 000 1.. —ugA Iblpay ads-oa-2p P. stpha-aHG X X < 0.032 < 0.00 1 ugA lb/Day L31 114-6) P. beWSHc X X < 0.032 < 0.00 1 ugA IbA]ay a16-6&7p P. gamma-aHc X X < 0.032 < 0.00 1 ug/t Ib/Doy 2 ea-sp SP. deft"HC x X < 0,032 < 0,00 1 ugi :. IblDay ara-ec-s} .. 6P CNmdana X < ".0.32 < 0.02 1 ugA : IbMay 51-74-9) P. 4,4'-DDT. X X < 0.032 0.00 1 ugn IbODay. (50.29.3) S P.4A'-0u0 X::. X 0.032 < 0,00 1 ugA lb/Day 72-55-9) P.4.4'-DDD. x :. < 0.032 0.00 1 ugA IbiDay (72-544) 10P. Dieidrin. x X < 0.032 < 0 00 t ugA. lb/Day 60.57.1) iP.alpha-EndosuKan X X < 0.032 0.00 1 ugA:... lb/Day (115-29-7p 12P. beta-Endowhn X X < 0.032 < 0.00 1 ugA Im y 13P. EndmNan suftte X X< 0.032 K 0.00 1 ug/L 1b/Day .. 14P Enddn X. X < 0,032 4 0,00 1 ugA. IbAaay 20-0) 5P, EndrM :.... AMehyde X X c 0,032 < 0,00 1 ugA- lb/Day 7421-93-4) Isp, Heptaehtor p X < q 032 < 0.00 1 ugA tbAJay Z-oo) 'PAGE V-6 EPA I.D. NUMBER {Copy from Item 1 of Farm flUTFALL NUMBER CcrNTtNu D RPM PAGE v-s N OO24392 005 McGuire Nuclear Station 1, POLLUTANT 2: MARK W 3. EFFLUENT 4: UNITS ' S. INTAKE optionat) AND CAS NO. a. MAXIMUM DAILY VALUE b. MAXIMUM 30 DAY VALUE c. LONG TERM AVG, VALUE a. LONG TERM AVG. VALUE m4able) - b p �..b {tt usgac eg {n evauawe> d: NOi OF a, Concon- d, NCI. OF d semt sent(1)Cane tinm {2)M t1)Caicaniratiam {2)Maas {tjCam t1an {2)MaaaANALYSES tratio{i)Cor� w*.tinn (2)Ma ANALYSES. GC/MS FRACTION - PESTICIDES (continued) IM Heptatmor axkW X < 0.032 < 0:00 i ugrL lb/Day 1W POB-1242 x < 0,32 < 0,02 1 ug1L INDay 53469.21-5}.. 19R PCB-1254 X < 0,32 < 0.02 1 vgrL lb/Day OP. PCB-122i 1 ugti.. ibPDBy 11104-28-2):. 1P,PCB-1232 X < 0.32 c O:02 1 ug1L tbdDay 11141-1G-5}.. P.PCB•1248 X < 0,32 < 0.02 1 ug1L lb/Day t2572-295} 3P. PCB-IM X < 0.32 < 0,02 1 uglL lb/Day 81096.525). 4P. PCB•4016 X < 0,32 < 0.02 1 UQA- lb/Day L 12111i 11-2) 5P, Taaapheme X < OMc 0.02 1 U9A- W011y 84Yttt-39.2j.. ::EPA Famn.5510.2C (Rao 245) PAGE V-9 NPDES SUPPLEMENTAL INFORMATION FOR MCGUIRE NUCLEAR STATION Revision b: 7I20/2009 f TABLE F CONTENTS OVERVIEW STATION IN Surface Intake 4 Subsurface Intake NUCLEAR SERVICE WATER .... .. « ... _.,« ......::: Containment Sera Heat lxchan ers...:. „ ,, _ . ,,. « ......, .....:».,._. CONVENTIONAL LOW PRESSURE SERVICE WATER FIRE PROTECTION SSE 6 OUTFALL 001 Condenser Cooljn ; Water 7 Ventilation Unit Condensate Drain Tank UCL}T S _316� (a) Stud and Thermal "Variance OI.tTFALL 00 Water Treatment Room Sum . ,:,. ...:... ......e . ...�...... 9 ..... :«.... . . , .. ........ , ...:.::...,.... ..n.«..... . ... ...... .. . ......... .. ... . «..,.::: « ......,:.... . .::..«. .....:.... ... . . . ,. Filtered Water System Drinkina Water S stun...._::, Dernineralized Water S stem l0 Turbine BuxldinSumps,.» ....:......... «,.1 Diesel Generator Room Sums w.:. . w ...::.. --- ...««..... ....... w 12 « w.... «....._..............._ .... , ... . ,....::.... «..:: , Lab Drains« < 1 Condensate Polisher Backwash 1 Steam Generator Blowdown 13 13 Aux�l�ar Electric 13o11eC Blowdrwn` 13 Groundwater Drainaize System_ 1 Cystem nwaterm 1 Closed Cool�n S stems 14 Standby Shutdown Facility ._w..... .:.... ..............«.............._,....,............,..,.....,._......,....._....,._......_...._..................._........_.. 14 ....... ..._.... .....;....... Steam Generator Cleaning ,..._......_.w_. ...,.«.- 14 .«.. «r ....«..� Miscellaneous S stem/Corn anent Clea in 14 ......................... ..... . ..... _. Alkaline Boilout Solutions _. ,,, w_.....,,...,....... 15 ' Acid Solutions ...... w ..,.. 15 Acid Solution Additives 15 Page 2 of 24 EDTA. Co iounds and HEDTA 1 Miscellaneous Cc c unds �.,.w ............ v�.n .. 1 �m..... ,..w.�. �.m. �mr.. .�..n.._n.� ....._ Landfill Leachate 1 McCune Gara w m ..� . 1 .::.,....... �A.� ...,.., rt �....w �....,.. _ . ....w .... �: .McGuire Office Co 1e- 1 iundeat cove lainaticn 17 Medical Farr t _ �...w_ �... , .._ _.....m. t �. u... .. _.W...._..v... .....� . ...rt � .a Lincoln Combustion Turbine Slade Wash Water w..... . �...� . r rt w . �... _ ,._.._ 1 �.....v__..� Ice Condenser 1 OUTFALL 00 OUTFALL 004 IF1oor ui rnent and Land }rains 1 'ventilation Unit Drains r.. _.., ...... .. _., ..._ ..... .. �w 1 .._.ry w ..... v �.,_..... as ... �.� _..: ��... Chemical Volume d Ct ntrol stem 19 Chemical Trcatinent in WPM Svstem 20 OUTFALL 00 tandb Nuclear rvice Water bond 0. Ad n�nistrat� e Buildina Drains (} RCS stem Cnatrin �. 1 Filtered Water . _..... ...... , , �., ....:.. _ �..� . 1 �,...,: �..... ........ .......... HVAC Unit brains` 1 d Drains 21 OUTFALL 006 21 Page 3 of 24 OVERVIEW The McGuire Nuclear Station is a two unit nuclear steam electric generating station. It is owned d operated by juke Energy Corporation. Each unit has a fourloop pressurized water reactor, Reactor fuel consists of uranium oxide pellets clad in zirconium alloy fuel rods. Reactor heat absorbed by the Reactor Coolant System (primary side) is transferred to four steam generators to produce steam (secondary side) sufficient enough to drive a turbine generator with a design net electrical rating of 1180 megawatts. The nuclear reaction is controlled by control rods and chemical neutron absorption. Boric acid is used as a chemical neutron absorber and to provide borated water for emergency safety injection. During reactor operation, changes are made in the reactor coolant boron concentration. schematic diagram of water use and waste water discharges for McGuire Nuclear Station is attached as Appendix 1. It is possible for any of the discharges to contain low levels of radioactivity, All discharges of radioactivity are regulated by the Nuclear Regulatory Commission in accordance with 10 CFR fart 20 and 10 CFR Part 50. The following is a brief description of the major systems. STATION All water for McGuire Nuclear Station is withdrawn from Lake Norman through a dual intake system, a surface and a subsurface system. These systems supply the Main Condenser Cooling Water RC), Conventional' Low Pressure Service Water (), Nuclear Service Water (RN), Fire Protection System /RY), and Containment Ventilation Cooling Water System (RV). Surface Intake McGuire Nuclear Station has two power generating units with four Condenser Cooling Water (RC) pumps per unit. There are two intake screens per pump for a total of 16 screens. The intake screens are back washed on an intermittent basis to prevent differential pressure buildup across the intake screens. The frequency of cleaning is determined by the amount of debris on the screens. Approximately 8,500 gallons of water are used to backwash each screen. The water is returned to Lake Norman at the intake bay. The backwash water is raw lake water. No chemicals are used in the backwash water. Subsurface Intake The subsurface intake (Low Level Intake) is located near the bottom of Lake Norman at Cowans Ford Dam. There are six low-level intake pumps with a capacity of 150,000 GPM each. Currently only 3 pumps are operational. The Unit I pumps have been taken out of service. During certain times of the year, this system pumpscoolerwater from the bottom of the lake (hypolimnion - perpetually colder water in the lower part of the lake) and mixes it with the warmer water in the surface intake structure during times of high lake surface water Page 4 of 24 temperatures. At all times of the year, the Low Level Intake (LLI) supplies water to the ITV and RN Systems. The LLI lines are periodically drained to the Catawba River just below theCowan's Ford Liam for inspection. NUCLEAR SERVICE WATER The Nuclear Service Water (RN) System is a safety related., once -through, ;non -contact Cooling water system. The RN System supplies cooling water to various heat loads in bath the primary and secondary portions of each unit. -There are two pumps per unit (four pumps total) that are capable of delivering 17,500 GPM per pump. The water supply is from Lake Norman or the Standby Nuclear Service Water Pond (SNSWP). Water from Lake Norman is supplied by the C system from the surface intake or by the Low Level Intake (LLI). The normal source of water is the LLI system. The normal discharge is to Lake Norman through C utfall 001. The SNSWP,is a 34.9 acre pond designed to provide cooling water for the safe shutdown of the station in the unlikely event that Lake Norman becomes unavailable. The level in the pond i maintained, per requirements of the McGuire Nuclear Station Technical Specifications, b pumping water from Lake Norman into the pond. The pond overflows to the Catawba River via the Wastewater Collection Basin (WWCB), Outfall 005. The pond also receives storm water runoff from a drainage area. of 100 acres, When the RN System is aligned to take suction from the SKIS , discharge is back to the SNSWP. This recirculation mode is normally implemented for three hours every six weeks. s a result of accelerated corrosion of RN System components, some components have corrosion inhibitors added. Corrosion inhibitors may contain nitrites, borates, carbonates, silicates, hydroxides, tiazoles, and azoles, Low levels of one or more of these corrosion inhibitors would e discharged at environmentally acceptable levels: Macrotouling by C rbicula (Asiatic clams) and Dreissena (Zebra Mussels) can impact the safe operation of the station. Zebra Mussels have not been problematic to date in bake Norman but ether utilities have experienced macrofouling with :Zebra Mussels. Microbial influenced corrosion (M C) has caused failures of piping and heat exchanger tubing due to pitting. Non - oxidizing biocides, chlorine, or sodium h pochlorite may be used at concentrations, which will not impact the environment to address macrofouling and MIC. Surfactants, which act as biopenetrants may be added along with biocides to improve their efficacy. To prevent mud fouling of components coaled by the RN System, dispersants are added. CONTAINMENT SPY HEAT EXCHANGERS In order to mitigate corrosion of carbon steel, a wet lay-up system is being used on the Containment Spray Heat Exchangers (N ). Various corrosion inhibitor solutions containing nitrites, borat s, axles, and trig oles may be used. The corrosion inhibitor solution is released 5 to 10 times per year per heat exchanger (2 heat exchangers per unit) to either the SNSWP or Page 5 of 2 Lake Norman via Outfall 001, during the flaw balance and heat exchanger performance testing. Each heat exchanger has a capacity of3600 gallons. Organic biocides are added for biofduling control. OUT1N A.LL 00 Inputs to Outfall 001 include discharges from the R, RL, and RN systems. Outfall 004 combines with Outfall 001 before discharging into Lake Norman. Storm drains along the discharge canal combine with Outfall 001; Page 6 of 24 Condenser Cooline Water The RC System is a once through, non -contact cooling water system that removes heat rejected from the main and feedwter pump turbine condensers and other miscellaneous heat exchangers. Each of the two power generating units has four RC pumps for a total of eight (8) pumps, The flow for each unit depends on the number of pumps operating as shown by the following table: i r.i The operational schedule of the pumps of each unit is a function of the intake water temperature and the unit load. At 100% load and with the intake temperature near its summer high, three and sometimes four, RC pumps per unit are used. During winter when intake temperatures are lower, three pumps may be used. Condenser cleaning is accomplished by mechanical means using; the "mertap" system. This system circulates small sponge rubber balls through the condenser continuously. There are 8 Amertap pumps per unit, 16 altogether. Each system (2 systemsper unit, one for main condenser and one for the FWPTs (Feedwater Pump Turbines)) has a capacity of approximately 120 balls. The balls are injected on the inlet side of the condenser and are retrieved on screens n the discharge side of the condenser. Periodically some balls escape the retrieval system and are discharged through Outfall 001. Efforts are made to minimize the loss of balls within the system. It may become necessary at times to institute chemical control for macroinvertebrate infestation; general corrosion, and microbiologically induced corrosion (IC). Chemicals anticipated to b added include chlorine (sodium or calcium hypochlorite), organic biocides, dispersants, and corrosion inhibitors. The corrosion inhibitors include nitrites, carbonates, tri toles, borates, triazols, and azoles. Discharge concentrations are maintained below permitted discharge levels, MNS has identified the need to treat for Asiatic clams in a section of the RC system; The site has determined that clams are present in a "crossover pipe" that connects the U I and U2 RC systems. The clams have caused fouling of plant components. It is planned to periodically perform localized injections of a clamicide, EVAC, into the crossover pipe section. The injection concentrations will be kept at a level to prevent toxic conditions at the plant discharge. Discharge concentrations of any treatment chemicals will be maintained below permitted discharge levels. Page 7 of 24 The Ventilation Unit Condensate Drain Tanks ( CDT) collects condensate fromairhandling units from each reactor building. Each VUCDT (1 per unit) has a volume of 4,000 gallons, This condensate typically has little radionuclide contamination. The condensate is sampled for radionuclide contamination before being released. If the results of this sampling indicates the need, the VUDT contents are transferred to the Floor Drain Tank (FDT) for processing through Outfall004. If no processing is needed, the condensate is released from the VUCDT via the RC System piping to Lake Norman (Outfall 001). Note: Outfall 004 and the VUCDTs discharge through the same piping to Lake Norman through Outfall 001, During refueling outages, the ice in the ice condenser is melted. The ice melt is normally routed to WC via the Turbine Building Sumps, however on occasion the ice melt may be routed through the VUCDT. This drainage contains small amounts of boron. Boron is used as a neutron absorber in the ice to control reactivity. Additionally,' small amounts of oil have also been found to accumulate on the ice in the ice condensers. The source of the oil is from pneumatic tools used to vibrate the ice from the condenser's ice baskets. Luring outages the KC Heat Exchangers may be drained to the CDT as well. Permission was granted for this discharge in a permit modification approved by NCDENR on April 11, 2002. 316 (a} Study and Thermal Variance 31 o() study was submitted to the state on August 9, 1985 and a 31 t(a) variance was granted on October 1, 1985. Plant operating conditions and load factors remain unchanged and are expected to remain so for the term of the permit. An annual Lake Norman aquatic environment maintenance monitoring program was implemented on July 8, 1987, A copy of this report is submitted annually to the Environmental Sciences Section of the Division of Water Quality at NCDENR and. the NC Wildlife Resources Commission. No obvious short term or long term impact of station operations have been observed in water quality, phytoplankton, zooplankton or fish communities since the inception of this program., Additionally, Doke Energy is not aware o any changes to plant discharges or other discharges in the plant site area which would negatively impact the thermal discharge or biological habitat of Lake Norman, OUTF LL 002 Outfall '002 discharges treated wastewater from the Conventional Wastewater Treatment (C) System through a Parshall flume to the Catawba River below Cowans Ford Dam. The WC System' consists of a concrete lined initial holdup pond (200,000 gallon capacity), two parallel Page 8 of 24 clay -lined settling ponds (2.5 million gallons each), and a concrete lined final holdup pond (1 Inputs to the Water Treatment Room Sump consist of drainage from all equipment including pump seal le off and bearing cooling water located in the Water Treatment Room, Other inputs include the Diatomaceous Earth (DSlurry Tank drain, Filtered Water ( F), Acid and Caustic day -tank storage overflow drains, Carbon Filter backwash and sluice, filter backwash, YM demineralizer regeneration waste, rinsate of empty hydrazine, ammonia, carbohydrazide, dimethylamine containers and backflow preenter drains. In addition, floor wash and sample line flush water are routed to this sump. Antfoa ing agents and wax strippers are routinely present in this waste stream. Rinsate :from empty microbiocide containers (used in the chased Page 9 of 2 cooling systems) are periodically added to this sump. The drains in the plant Auxiliary Electric Boiler Room also route to this sump. Additionally, inputs from the McGuire Island Industrial Waste System are routed to the sump. See the Island industrial Waste section: for additional details on these inputs. The Water Treatment Room Sump discharges to the WC System via the Initial Holdup Fond.. new building has been constructed on site that will contain a vendor supplied water treatment system to replace the existing treatment system. The conversion; is planned to be completed by late 20 10. At that time, any water treatment related waste streams will no longer be routed to the current Water Treatment room sump. Wastes from the new processes will be still be routed to the WC system. See New WaterTreatment wilding discussion below. Filtered Water System • ro a '• ,� • • 1 1 M Guire Site is supplied by is 1 in use, while the other demineralizer is being regenerated or in standby. YM pumps take suction from the Filtered Water (YF) Storage flanks and discharge through the Carbon Filters to the RO units. The RO units discharge to holding tank(s) which discharges to the YM demineralizer in service. The RO units can be bypassed during high water demands: The carbon filters remove organic substances and any residual chlorine. These filters may be cleaned by backwashing, steam cleaning, or rinsing. Backwashing is usually performed weekly on alternating filters. Rinse water is discharged via the Water Treatment Rohm Sump to the WC System (utfall 00). Approximately 15,000 gallons of water is used per rinse. Each carbon bed is sluiced and reloaded with new carbon as needed. 'Waste carbon is rousted to the WC Initial Holdup Fond where it is collected and deposited in a permitted landfill. Waste carbon may also be collected directly from the carbon filter and deposited in a permitted landfill The RO units provide pretreatment to the demineralizers. They consist of a high pressure pump for each unit which forces water through a series of membranes which cleans a portion of the water (approximately 300 GPM) to a acceptable level (permeate) and sends the rest of the water (reject water of approximately 10 GPM) to the Waste Water Collection Basin (utfall 005), Sulfuric acid can be injected to the process stream to maintain proper pH. The RO Units are periodically cleaned based an performance standards. The cleaning process may involve the use of surfactants, acids and caustics. When cleaning is conducted, the cleaning water is discharged via the Water Treatment Sump and then to the WC System (Out all 002). Demineralizers are regenerated based on through -put or chemistry limits on contaminant levels. To regenerate the resins, sulfuric acid and sodium hydroxide are flushed through the bed. At the present time, each regeneration normally takes approximately 200 gallons of 93% Sulfuric Acid; 00 gallons of 50°r'o'Sodium Hydroxide and 75,000 gallons of YM water. The amounts of required acid and caustic will vary as dictated by operational requirements. Based on annual resin analysis results, the beds may be surfactant cleaned, caustic soaked or brine soaked. The water from these cleanings is discharged via the Water Treatment Room Sump to the WC System (Outfall 002), The demineralizer resin is replenished approximately every six to eight years depending on resin sampling results. Waste resin is routed via the Water Treatment Room Sump to the WC System, Initial Holdup Pond and is ultimately placed in a permitted landfill. Waste resin may also be collected directly from the ion exchange vessel and either recycled if reusable, or deposited in a`permitted landfill. With the new vendor water treatment system, the existing demineralized water system will be abandoned, eliminating wastes from these wastestrea s. See New Water Treatment Building discussion below. New Water Treatment Bolding The site is in the process of replacing the existing water treatment system with a new vendor supplied system. While the processes will be similar, there will be some changes to waste streams: The treatment processes will consist of chlorination, filtration, dechlorinaton, reverse osmosis, electrodeionization(EDI) and ion exchange: Page 11 of 2 Sodium hypochlorite will be used for chlorination. Instead of diatomaceous earth filters, ultrafiltration (UF) will be used. This will eliminate the waste filter media (DE) that is currently produced. The OF filters will be backwashed periodically to remove accumulated lake solids. At times cleaning cycles will be combined with backwashes for the Ulu filters. Sodium hypochlorite, hydrochloric acid and sodium hydroxide may be used to clean the OF fibers, Backwash and cleaning waste water will be routed to the WC system for treatment. OF filtered water will be pumped to a 25,000 gallon storage tank at the new building. The new process will not use carbon filtration, eliminating carbon filter backwash wastewater and the need to dispose of waste carbon. Sodium bisulfite will be used to dechlorinate filtered water before it is pumped to the reverse osmosis units. Reverse osmosis will operate the same as currently with reject flow, approximately 100 gpm max flowrate, routed to the Wastewater Collection Basin. Antiscalents can be injected into the RO feed. The RO system will require periodic cleanings using surfactants, acids or caustic chemicals. Any spent cleaning solutions will be routed to the WC system for treatment. The new system will also employ an electrodeionization (EDI) unit to remove dissolved minerals from the water. Reject water from the EDI unit will be sent back to the OF filtered water storage tank for reprocessing. The EDI unit will also be cleaned periodically with the same cleaning system used for RO. The existing demineralization system will be replaced with modular, replaceable mixed ion exchange resin beds. When the resin beds are exhausted, they will be replaced with new resin beds and transported off site for regeneration. This will eliminate the demineralizer waste streams including the 75,000+ gallons of regenerant wastes currently sent to WC. Turbine Building Sum s y The Turbine Building Sumps (TBS), one for each unit, receive inputs from leakage, drainage, and liquid wastes from equipment and floor drains located in the Turbine Building. Inputs include Groundwater Drainage Sumps (WZ), Auxiliary Electric Boiler Blowdown, Steam Generator Blowdown, air handling units, Diesel Generator Room Sumps, lab drains, floor washes, normal condensate system leakage, and condensate polisher backwashes. Other possible inputs may include RC Un-watering, closed cooling system drainage, and steam generator wet lay-up/drain down. Periodically, condensate from air compressors is processed through an oil water separator and routed to the TBS then to the WC Initial Holdup Pond. The TBS's pump out to the WC Initial Holdup Pond. If radioactivity limits are exceeded, theses sumps may be routed through the Radwaste Liquid Waste Monitoring (WM) System (Outfall 004) or directly to RC (Outfall 001) depending on the treatment needed. All radioactive releases are controlled and regulated by the NRC. Discharges from the TBS may also be routed to RC (Outfall 001) if system inventory is high. Page 12 of 24 Chemicals that may be present in the TBS include the following: • ammonia • hydrazine • carbohydrazid • 3-methoxypropylamine (MPA) • dimethylamine (DMA) • microbiocides • corrosion inhibitors (examples include: molybdate, nitrite, tolyltriazole, etc.) • ,janitorial cleaning products • ethylene glycol (from ice melt • Boric Acid / Borax (from ice melt) • miscellaneous system/component cleaning products (love --volume wastes not associated with chemical metal cleaning) • laboratory chemicals • poly acrylic acid (P'AA) • surfactants • dispersants Curing refueling outages, the ice in the ice condenser is melted. The ice melt is routed to W via the Turbine Building Sumps, This drainage contains small amounts of boron. Boron is used s a neutron absorber in the ice to control reactivity; Additionally, small amounts of oil have also been found to accumulate on the ice in the ice condensers. The source of the oil is from pneumatic tools used to vibrate the ice from the condenser's icebaskets'. Page 13 of 24 Lab [trains There are several analytical laboratories on site which discharge to the WC System. These discharges contain small quantities of typical laboratory chemicals used in analytical procedures: The island environmental labs discharge to the WC System as well. Further discussion of this waste stream is provided in the Island Industrial Waste section. The lab sinks in the Island Technical Services Center (TSC), building 7406, drain to CMUD. There are signs on all of the TSC lab sinks telling lab personnel not to dispose of any chemicals down the lab sink drains. There is very little chemical use in those labs. The TSC labs perform weight calibration, and sound and vibration analysis. There are four steam generators (SG) per unit at McGuire for a total of eight steam generators. Each has an operating volume of 16,000 gallons. Each unit is provided with a Steam Generator ]lowdown Recycle System. Steam generator blowdown is continuous at a rate of approximately 200 gallons per minute per unit. The blowdown is directed to either the condensate polishing de ineralizers or to the steam generator blowdown demineralizers. If the blowdown water quality is unacceptable, it is rejected. Rejected water is discharged to the WC System or to the WM System depending on lever of radioactivity. During normal operation, hydrazine is added to the condensate system for oxygen scavenging. The hydrazine concentration is maintained within a range of -00 ppb. 3-methoxypropylamine is added for pH control. The steam generators and he ell are placed in wet lay-up if a. unit is to be in extended shutdown or per management direction. Each unit is normally shutdown every 12 — 18 months for refueling and maintenance. Dispersants may be used in the plants Steam Generators to control corrosion and sediment buildup, therefore the potential exists that rejected blowdown waste waster may contain small amounts of the dispersant. Page 14 of 24 t is et layup solution is disch444 to ft WC System or WM System via the r Groundwater Drainaae System The Groundwater Drainage System (WZ) is designed to relieve hydrostatic pressure from the Reactor and Auxiliary Buildings by discharging groundwater collected in sumps to either a yard drain or the TBS. There are three groundwater sumps with two 250 GPM sump pumps each. Two of the sumps discharge to the TBS while the third sump discharges to a yard drain that is routed to the Standby Nuclear Service Water Pond (SNSWP): C Svstem Unwaterin The RC System for each of the two units has a volume of approximately 2 million gallons. During refueling outages and periodically during other shutdowns, the'RC System must b unwatered, This water is essentially untreated lame water. The principle unatering discharge route is through the WWCB, but it can be routed through the WC System for short periods of time. See additional details under Outfall 005, Page 15 of 24 Closed Cool ne Svstems Steam Generator Cleanin Miscellaneous S stem/Com orient Cleaning Other systems/components (such as strainers, HVAC heat exchangers, etc.) are cleaned periodically because of scaling or plugging. Other components are cleaned as necessary for various fouling problems. Solutions utilized are dilute acids or caustics. Typically only small volumes of waste are generated Chemicals utilized by these methodologies, alone or in combination, mayinclude the following: Alkaline Boilout Solutions non-ionic surfactants anionic surfactants cationic surfactants Page 16 of 24 hydrochloric acid sulfuric acid phosphoric acid formic acid hydroxyacetic acid sulfuric acid citric acid nitric acid Acid Solution Additives thiourea ammonium bifluoride oxalic acid' EDTA Comnounds and HEIST 4 ' DTA s • � x chlorothene sodium chloride potassium permanganate aqua ammonia ammonium persulfat antifoam sodium sulfite chlorine Page 17 of 2 The wastes from these cleanings will be analyzed to determine proper wash disposal. These cleaning solutions will be released through the Wig System or WM System depending on levels of radioactivity. Island Industrial Waste Landfill Leachate Page 18 of 24 JIM111�11 !ill 1111111 ill iiiiiiiii ill ill �1111 1111111111 111�111�1 l illillillill 11 J! ill 11111111111 Ill III: ill 1 Jill 1111111 lilillilill 1111 1 1 1 1 6=31ITMO structive Examination structive Examination (NDE) includes X-ray testing of various components. The ;raphic waste from X-raying is routed to the WC system via the lHP. NDE is usually :ted in a building inside the protected area. When operating, the X-ray processing unit taste stream which consists of approximately 02377 GPM developer replenisher working n, 0.04490 GPM fixer replenisher working solution, and 0.75 GPM (+ or -,05) water, The per replenisher working solution contains hydroquinone, glutaraldehyde, and potassium !. The fixer and replenisher working solution contains ammonium thiosulfate and i sulfate. Other developer working solutions and /or fixer replenisher working solutions her constituents may be substituted in the future. Silver is recovered from the process w before it enters the waste stream. The developing process can be operated a am of 30 hours per week (4.3 hours/day) but averages only 6 hours per week (1.2 Jay). Operation of the developing process results in a maximum of approximately 1180 ith an average of 438 GP D of photographic waste discharging to the WC System. indenser refueling outages, ice melt from the plants ice condenser is routed to C. Potential als in ice melt include: Borax Boric Acid Trace amount of oil from ice removal pneumatic tools Ethylene Glycol from spills from the ice making equipment. The amount of Ethylene Glycol in the ice melt would be <55 gallons total. kLL 003 003 was eliminated as of June 28, 199& All sanitary wastewater is now discharged to .rlotte/Mecklenburg Utilities Devartment (CMUD). Page 19 of 24 UTFALL 004 utfall 004 discharges wastewater from the Radwaste Liquid Waste Monitoring System (WM). This discharge combines with RC water before discharging through the concrete discharge structure (Dutfall 001) into Lake Norman as a batch discharge. All radioactive and potentially radioactive liquids are collected, segregated and Processed prior to release. These effluents are classified as recyclable or non -recyclable liquids. Recyclable liquids are recirculated back to their Process streams. Non -recyclable liquids are collected and processed to Nuclear Regulatory Commission (NRC) requirements Per 10 CFR Part 20 and 10 CFR Part 50 requirements Prior to release. The type of processing depends on the type of waste. The maximum discharge rate from WM is 120 GPM. The batch discharge flow for a Waste Monitor Tank Release is a function of activity level, the number of RC pumps in operation, and the resultant boron concentration in Lake Norman. The WM collects waste in three subsystems; floor and equipment drains, laundry waste, and ventilation unit drains. Chemicals that may be present in the WM System include: boric acid borax' nitrate ammonia carbohydraide imethyla 'ine (DMA) 3-methoxypropylamine (MPA Cat Floc T- lithium hydroxide ethylene glycol (from ice melt) corrosion inhibitors (examples include; molybdate, nitrite, tolyltria ole, etc.) hydrazine chlorinelhypochlorite hydrogen peroxide pump bearing cleaning chemicals laboratory chemicals surfactants polyeectrolytes miscellaneous system/component cleaning waste (low volume waste not associated with chemical metals cleaning) microbiocides tool and component decontamination waste janitorial cleaning products. The TS can become contaminated with radioactivity. When this occurs, it can be pumped to the Floor Drain Tank (FIST) or to the WM release point in the RC crossover line. Any chemicals listed as being in the TBS have the potential to be present in the Waste Monitor Tank (WMT) Page 20 of 2 • Mb 'i i • .• ! ! ! ! b ! * • Chemical Volume and Control ys Chemical Treatment in WM System' Occasionally, it is necessary to oxidize sodium nitrite in the waste monitor tank using hypochlorite (calcium or sodium) or catalyzed hydrogen peroxide. When this treatment i performed, the waste monitor tank is isolated, recirculated, and mixed.. The tank is sampled to ensure that the nitrite has been oxidized. The addition of :the oxidation chemicals should result in a small residual of nitrite in the tank, since the oxidation chemicals will not be added in stoicheometrical excess. Page 21 of 2 OUTFALL 005 Administrative Building rains The Administrative Building drains include an HVAC sump, floor drains, ,janitorial sink, hot water bailer, and chiller water system discharge. Any chemicalsin the drains would include the typical commercial products used to clean and maintain the floors as well as closed cooling corrosion inhibitors and microbicides from leakage/drainage of the HVAC Systems. The corrosion inhibitors may contain nitrite, borate, carbonate, triazole, azle, and glycol compounds. .Additionally, HVAC cooling units are periodically cleaned using dilute coil cleaning solutions. These cleaning solutions are typically flushed to storm drains near the building which drain to the SNSWP or the WWCB. 'Volumes are less than 55 gallons. The coil cleaning solutions are typically Phosphoric Acid or Hydrofluoric Acid based. C Svstem Un-waterine The RC System for each of the two units has a total volume of approximately 2 million gallons. Whenever a unit is scheduled for refueling, periodically during other shutdowns, and for Page 22 of 24 i w �� 11 • # - o # # t v Several HVAC units have once through non- contact cooling water drains which discharge t yard drains on the east and west sides of the Administrative Building. The flow from each of these units is 10 GPM. These HVAC units are supplied by RL. Additionally, HVAC cooling units are periodically cleaned using dilute coil cleaning solutions. These cleaning solutions are typically flushed to storm drains near the building which drain to the SNSWP or the WWCB. Volumes are less than 55 gallons. The coil cleaning solutions are typically Phosphoric Acid or Hydrofluoric Acid based. Yard Drains Most yard drains discharge to the WWCB or SNS. The drainage area for the plant site is approximately 250 acres, The yard drain system is described in McGuire's Ste water Supplemental Information and the sites Storm Water Pollution Prevention Plan (SWPPP). U F LL 006 System performance standards may require that certain metal components be periodically cleaned using an acid or caustic solution. This cleaning process attacks the base metal of the component. The waste metal cleaning solutions which are generated: will be neutralized. The either compounds will be mixed; oxidized, and/or precipitated as necessary for treatment, The wastes from these cleanings will be sampled and analyzed to determine proper waste disposal. If the wastewater is in specification it will be released through the WC System or WM System. I Page 23 of 2 h b t t d further or sent the wash solution exceeds the permitted discharge limits, it will eat er r e off -site to an approved disposal facility. Page 24 of 24 APPENDIX I FLOW DIAGRAM Page 4 of 1 i LL Standby Nuclear 1 Appendix 1 Service Water Pond -- Storm Drains McGuire Nuclear Station SNSWP NPDES Flaw Diagram -----: Normal Flo path i ► LAKE NORMAN Nuclear Service 1027 MGD Water RN Alternate Flcaysrpath _ + Low Level Intake Condenser Cooling 2,579 MGD 2589 Total MGD LAKE NORMAN LLI } Water RC __: J ♦ —® DISCHARGE a I— - - —� _ I 0.00000718 MGD i ( Low Pressure I —[Fire Protection ° ° Service Water RL I I ° Radv iaste I " I I Filtered Water ReverseDem(neralized Primary System System Osmosis Unit Coolant Drainage - -� rM yVM YF Water YM I ) ( RO and Leakage WWO04 ° L_r-__ a Regen Waste I a I ° Ventilation Unit I *Garage Vehicle Condensate [gain I g I Water Treatment ° Wash Area Room Sump Secondary System Tanks (VUDT) ( *Landfill Leachate w Drainage and ., Leakage 0.0015 MGD I I I *NDEPhotoraphic '—__----_____----- _ — — _I I Waste ° Conventional I Island Lab Waste' _. w .. __- Waste TreatmentSystem ( *Island HVAC ( Turbine ( C) I Cooling Towers _ ____ _ __.�.__ ___ I Building Sump 002 I *Oil Water _ I Separators _ __ Storm Drains 0.33 MGD'__ 7777777777, I i Waste Water CATAWBA Collection Basin `" ( CB) 0.8505 MGD RIVER 00 Total: 1.185 MGD Last Revised (. : ©utfalls 002 + 005 July 29,2 09 I__—__—'—_ I APPENDIX 11 SUPPLEMENTAL INFORMATION FOR McGUIRE NUCLEAR STATION Page 5 of 11 APPENDIX III SECTION 311 LIST Page 6 of 11 The table below identifies hazardous substances located on -site that have the potential to be released in quantities greater than the Reportable Quantity (RQ) listed in40CFR 117. This list is being provided in order to qualify for the spill reportability exemption provided in 40 CFR 117. Releasesofthese chemicals will be to the Outfalls indicated below. The values listed below represent the maximum quantities on -site that could be released at one time. These quantities do not reflect quantities that are discharged through typical use. POTENTIAL RELEASE CHEMICAL NAME USE TREATMENT AMOUNT OUTFALL Bulk Chemical used for resin regeneration and wastewater: Sodium Hydroxide neutralization. Stored in bulk tanks in a diked area. 500 Gallons 4000 lbs WC - - ------ used 002 :Bulk Chemical used for resin regeneration and wastewater, pH adjustment. Stored in Bulk Tanks in a diked area and Sulfuric-A-clid-1 in 350 gallon Tote Tanks, 500 Gallons l 4000 lb s WC 002 Used as an oxygen removal agent in plant systems, The ,greatest potential for a release of Hydrazine would be from a 350 Gallon Tote Tank spilled to the ground or inside the Hyqrazine Turbine Building, 1500 lbs WC tWWCB 002/005 Date: 8/21/2009 APPENDIX IV TOPOGRAPHIC MAP Page 7 of 11 APPENDIX SITE MAP Page 8 of 11 APPENDIX VI SLUDGE MANAGEMENT Page 9 of 11 D"UKE ENERGY McGUIRE NUCLEAR. STATION SLUDGE MANAGEMENT PLAN Conventional Waste Water System sludge is disposed of in the site's permitted landfill. The landfill is a Subtitle D Solid Waste Lined Landfill which only accepts non- hazardous waste. Prior to disposal, the sludge is sampled, then removed and e-watered. The source of the site's sludge is its filtered water system which is used to provide ultra high purity system water to the plant. This system uses Diatomaceous Earth (DE) pressure filters. The filters are bacwashed and the DE is collected in the Initial Hold. -up Pend with some residual ending up in our waste water treatment ponds. The DE must b removed approximately every 24 months from the Initial Holdup Pond.- Other sources of sludge are accumulation of dusts and silts from plant operation and the areas surrounding the ponds. Sourcesof radioactivity in the sludge come from various sumps in the auxiliary and turbine buildings. ppppopr, APPENDIX VII DISCUSSION OF ANALYSIS PERFORMED AND RESULTS OBTAINED Outfall 001 Comments • GC/MS fraction — base neutral/acid compounds failed surrogate recoveries on the initial sample (5/13/09). The outfall was resampled on 6/17/09 and all surrogates passed. No compounds were detected in either sample. The laboratory Control Standard for the first sampling event (5/13/09) failed QC recovery requirements for 2 Chloronaphthalene 53% (QC limits 60-118%) and acenaphthene 56% (QC limits 60 - 132%. The Laboratory Control Standard for the second sampling event (6/17/09) failed QC recovery limits for benzidine < 1% (QC limits 1-150%). The data should be considered valid as the sample was resampled and all surrogates passed as well as all LCS compounds except benzidine. This compound is very unstable as noted by the large acceptance limits. • Sulfite results should be considered estimates as the 15 minute holding time was not met. Outfall 002 Comments • GUMS fraction — base neutral/acid compounds failed surrogate recoveries on the initial sample (5/13/09). The outfall was resampled on 6/17/09 and all surrogates but one surrogate passed, 2,4,6 tribromophenol was recovered at 40% and the limits are 41 — 144%. No compounds were detected in either sample. The laboratory Control Standard for the first sampling event (5/13/09) failed QC recovery requirements for 2 Chloronaphthalene 53% (QC limits 60-118%) and acenaphthene 56% (QC limits 60 - 132%). The Laboratory Control Standard for the second sampling event (6/17/09) failed QC recovery limits for benzidine < 1% (QC limits 1-150%). The data should be considered valid as the sample was resampled and 5/6 surrogates passed as well as all LCS compounds except benzidine, This compound is very unstable as noted by the large acceptance limits. • Sulfite results should be considered estimates as the 15 minute holding time was not met. Outfall 004 Comments We received pennission from NCDENR in Raleigh (Mr. Tom Belnick) to not sample intemal Outfall 004. This outfall discharges to Outfall 001 which was sampled. Outfall 005 Comments GC/MS fraction — base neutral/acid compounds passed all surrogate recoveries on the initial sample (5/13/09) and the resample (6/17/09). No compounds were detected in either sample. The laboratory Control Standard for the first sampling event (5/13/09) failed QC recovery requirements for 2 Chloronaphthalene 53% (QC limits 60-118%) and acenaphthene 56% (QC limits 60 -132%). The Laboratory Control Standard for the second sampling event (6/17/09) failed QC recovery limits for benzidine < 1% (QC limits Page 10 of 11 Pppppp,- 1-150%). The data should be considered valid as all LC S compounds except benzidine. This compound is very unstable as noted by the large acceptance limits. Sulfite results should be considered estimates as the 15 minute holding time was not met. Intake Comments • GC/MS fraction — base neutral/acid compounds passed all surrogate recoveries on the initial sample (5/13/09) and the resample (6/17/09). No compounds were detected in eithersample. The laboratory Control Standard for the first sampling event (5/13/09) failed QC recovery requirements for 2 Chloronaphthalene 53% (QC limits 60-118%) and acenaphthene 56% (QC limits 60 -132%). The Laboratory Control Standard for the second sampling event (6/17/09) failed QC recovery limits for benzidine < 1% (QC limits 1-150%). The data should be considered valid as all LCS compounds except benzidine. This compound is very unstable as noted by the large acceptance limits. • Sulfite results should be considered estimates as the 15 minute holding time was not met. • Fecal Coliform results should be considered estimates as the 6 hour holding time was not met (6 hours 8 minutes). Page 11 of 21 PkDuke OrEnergy- August 3 0, 200 McGuire Nuclear Station 12700 a e Road Hunters ille, IBC 28078 Mr. Charles H. Weaver Jr. North Carolina Department of Environment and Natural Resources Division of Water Quality NPI ES Unit 1617 Mail Service Center Raleigh, NC 7 - l b 17 Subject. Duke Enemy Carolinas LLC /McGuire Nuclear Station Renewal Application for NPI ES Permit : NC 0024392 Mecklenburg County Record : MN006121 Certified Mail:: 7007 0220 0002 55314767 Dear Mr. Weaver: Duke Energy Carolinas, LLC, McGuire Nuclear Station submits the following NP ES permit renewal application for NPI ES permit Number NC<00243 2, which expires February 28, 2010. The attached permit application consists of 3 copies of the following documentation: 1 EPA Form l 2. EPA Form 2C — including: locations of each outfall a flow diagram showing water flow through the facility (see Appendix I a description of operations contributing wastewater o each outf ll average e flow from each operation where available and quantifiable the type treatment received by the waste water a listing of intermittent or seasonal discharges with frequency and flows +► analytical analysis for each outfall as required including Intake analysis discussion of analysis performed d results (see Appendix II) 3. Additional information concerning the operation of our waste water system is included in the enclosed document entitled. Supplemental Information For McGuire Page I of 1 Nuclear Station. See Appendix 11 4. Requested chemicals to be excluded under 40 CFR 117, Clean Water Act, Section 11 Exclusion. See Appendix 111. . A Topographical map showing the location of each outfall. See Appendix IV. . A Site Map showing the location of each outfall and ether features of the site. See Appendix V. 7. A copy of the site's Sludge Management flan. See Appendix VI 316 ()Thermal Variance McGuire Nuclear Station requests continuation of its 316 (a) thermal variance of 99 DEG F for the months of July -- September. The site currently has an approved lake monitoring plan in support of our 316 (a) thermal variance and we request continued approval of our monitoring plan. A copy of the results of our lake monitoring program is sent ally to the Chief of the Division of Water Quality. y. Should you desire a copy of the data submitted last year or more current data please contact John Williamson by phone at 980-875- 9 , or ' `a e-mail at John.Williamson@duke-energy.com. Corporate Name Change Please note the change in our corporate narne from Duke Energy Corporation to Duke EnergyCarolinas, LLC. This is in keeping with the company's new business structure as a result of the merger with Cinergy. Requested Permit Changes McGuire Nuclear Station requests the following permit changes: Removal of the following parameters for Outfall 00 : • Total Recoverable hopper • Total Recoverable Iron The iron and copper limitations were added to Outfall 005 because we anticipated that Chemical Metals Cleaning Wastes (CMCW) could be discharged from this outfall. We no longer plan on discharging any CMCW wastes to this outfall, so it is appropriate to request removal of the ironand dapper monitoring requirements. We have toxicity testing on this outfall on quarterly basis. McGuire Nuclear Station 316 (W Review e would like to request that the current references to 31 f(b) be removed from our permit until EPA publishes a final rule on this issue. Page 2 of 1 Sludge Management Sludge generated during the operation of the site's waste water system is disposed of as indicated in Appendix VI, Sludge Management. Please review this NPDES permit application package at your earliest convenience. We would be glad for the permit writer assigned to develop our permit to visit the site and discuss our waste water operations with personnel who are knowledgeable with its operation first hand. If a site visit is not possible, we would be glad to come to Raleigh to discuss any concern or issues you may have. This permit renewal package is being submitted at least 180 days prior to the permit expiration date as required by NC GS 143-215.1 (C). Should you have questions concerning this permit application please contact John Williamson by phone at 704-875-5894, or via e-mail at jcwillia@duke-energy.com. 1 Sincerely, Bruce H. Hamilton Site Vice President Duke Energy Carolinas LLC McGuire Nuclear Station Attachments cc: Jeff Cage Gary Sam Allen Stowe Kay Crane Page 3 of 11 NCDENR North Carolina Department of Environinent and Natural Resources Division of Water QUality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary August 20, 2009 Mr. John Williamson Duke Energy McGuire Nuclear Station 12700 Hagers Ferry Road Huntersville, North Carolina 28078 Subject: Compliance Evaluation Inspection Duke Energy McGuire Nuclear Station NPDES Permit N. NCO024392 Mecklenburg County, NC Dear Mr. Williamson: Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on August 18, 2009 by John Lesley. Please inform the facility's Operator -in -Responsible Charge of our findings by forwarding a copy of the enclosed report. Whole effluent samples were collected from outfalls 002 and 005 for use in aquatic toxicity testing. Test results will be for -warded under separate cover when available. The report should be self-explanatory; however, should you have any questions concerning this report, please do not hesitate to contact Mr. Lesley at 704-66' ) - 1 699. Sincerely, Robert B. Krebs Division of Water Quality Surface Water Protection Regional Supervisor Enclosure cc: Central Files Mecklenburg County Water Quality Protection Mooresville Reoional Office Clue Location: 610 East Ceater Ave_ Suite 3301 Mooresville, NC 28115 NorthCarolina Phoiw (704) 663-1699 \ Fax: (704) 663 3-6040 \ Customer Service: 1-877-623-6748 Internet, www.ticwaterqttality.org United :Mates Environmental Protection Agency Form ,Approved. AWashington, C} C. 20460 CMG No, 2040-0057 Water ComizIliance Inso 'ctiorl Re ort Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yrimo/day inspection Type Inspector Fac Type 1 1 NI 2 151 31 NC0024392 Ill 121 r)9108.1±- 117 181 Cl 181 SI 20I j Remarks 21LLJ-LLJ8 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA __--______ _m-____ _____Reserved-._ ___.__ _ jj 87 3, 0 1 69 701 4� 71 1 p� 72 J r 1 7 74 751 11 1 1 t 180 _ijSection-& Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effective Date PC7TWname and NPDES permit Number) - 10:00 AM 09/08118 06/03/01. McGuire Nuclear Power Plant Exit TimelDate Permit Expiration Date Nc Hwy 73 Huntersville NC 28078 12:30 PM 09/08/18 10/02/ 8 Name(s) of Onsite Representative(s)/Titles(s)lPhone and Fax Number(s) Ifl Other Facility Data Jahn C Williamson//704-875-5894 1 Name, Address of Responsible Official/Title/Phone and Fax Number John C Wiiliatoson,12700 Hagers Ferry Rd Huntersville NC 'Contacted 28078,//704--875-5894/ Yes Section C. Areas Evaluated During inspection (Check only those areas evaluated) PSelf-Monitoring Flow Measurement Records/Reports Self-onitoring Program Facility Site Review Effluent/Receiving Waters Laboratory Section D, Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers gate John E Les MRO WQ//704-663-1699 Ext.2198/ $S,a'ture of Management Q t1 ReAgency/Office/Phone and Fax Numbers Late ..a�.+r�'aA�.e.n - r 7Q4-663-1699 Fxt.22041 llocco MRO WQ// 9-94) Previous editions are obsolete. Pag NPQE yr/mo/day; Inspection Type NC0024392 11 121 09/08/18 117 18lCl Haste Management. Page # 2 Permit: NCO024392 Owner - Facility: McGuire Nuclear Power Plant Inspection Date: 08/18/2009 Inspection Type: Compliance Evaluation Permit Yes No NA NE (if the present permit expires in 6 months or less). Has the permittee submitted a new application? 0 0 0 Is the facility as described in the permit? 0 0 0 # Are there any special conditions for the permit? o n n Is access to the plant site restricted to the general public? G 0 0 Is the inspector granted access to all areas for inspection? 0 0 0 Comment: The permit expires on February 28, 2010. A permit renewal application has been prepared and is under review for signature. Special Condition: Thermal variance in July, August, and September, Recorq_F �ein Yes No NA NE Are records kept and maintained as required by the permit? 0 0 0 Is all required information readily available, complete and current? 0 0 0 Are all records maintained for 3 years (lab- reg. reclpired 5 years)? 0 0 0 Are analytical results consistent with data reported on DMRs? 0 0 0 Is the chain -of -custody complete? Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? 0 0 0 (if the facility is = or > 5 MGD permitted Row) Do they operate 24f7 with a certified operator on each shift? 0 0 0 Is the ORC visitation log available and current? n n Is the ORC certified at grade equal to or higher than the facility classification? fa n n Is the backup operator certified at one grade less or greater than the facility classification? 0 0 0 Is a copy of the current NPDES permit available on site? 0 it 0 Facility has copy of previous years Annual Report on file for review? n n C) Page # 3 Permit: NCO024392 Owner - Facility` McGuire Nuclear Power Plant Inspection Date: 08/18/2009 Inspection Type: Compliance Evaluation Record Ke pin Yes No NA NE Is right of way to Are the receivinc If effluent (d'iffus Comment: Flaw Measuren # is flaw meter u Is flaw meter cal Is the flaw meter to -1- .1. Ll lG 41101t fCl✓VI Comment: The flow meter (outfall on 6110/09 by the Instrumentation Outf all 001i flow is based on pump r C lutfall 000 flow is based on weir an Outfall 004 is an internal batch rele released. fined? ian trace amounts and other debris? they operating properly? -der match the flaw meter? Yes No NA NE ■nn ■DD0 n n n Yes No NA NE ®nnn ■000 ■nnn ilibreted atch is Page # 4 Fachment 17 Product PrenFis @ 5% Active Ingredient Rotenone Standby Nuclear Service Water Pond (SNSWP) was treated with 200 gallons of Prenfish with'5% Rotenone content SNSWP Volume = 184,350,203 gallons 200 gals x 8.34 lb X 453.59 grams x (.9226) Specific Gravity 698,028 grams Product gallons/ 1 lb 698,028 grams x (.05) concentration of Rotenone in Product = 34,901 grams of Rotenone in SNSWP Volume of pond discharged in 24 hours at Pump rate of 6,000 gpM = 8,640,000 gpd 5,000 gpm 7,200,000 gpd 4,000 gpm - 5,760,000 gpd Grams Rotenone in pond X Gals discharged in 24 hrs = Grams discharged in 24 hours Total Pond Volume in Gals 34,901 grams of Rotenone 8,640,000 1,636 Grams Rotenone Day = D.R. at 6,000 gpm discharge rate 184,350,203 34,901 grams of Rotenone 7,200,000 1363 Grams Rotenone Day = D.R. at 5,0 0 gpm discharge rate 14,5,03 34,901 grams of Rotenone 5,760,000_ 1090 Grams Rotenone Day = D.R. at 4,000 gpm discharge rate 184,350,203 166 0.00014073 Receiving Stream concentration @ 6000 gpm 11,624,908 Page 1 of 2 1363 0.00011725 Receiving Stream Concentration @ 5000 gpm 11,624,08 1090 0.000094 Receiving Stream Concentration @ 4000 gpm 11,24,908 LCO pp 0.05 0.0021 0.000105 Calculated regulated limitation A.D.D. DFCalc 2497 + 0.23 497 Volume Page 2 of 2 Attachment 1 Product PrenFish @ 5% Active Ingredient Rotenone Standby Nuclear Service Water Pond (SNSWP) was treated with 200 gallons of Prenfish with % Rotenone content SNSWP Volume = 184,350,203 gallons 200 gals x 8.34 lb X 4.53.59 grams x (.9226) Specific Gravity = 698,028 grams Product gallons/ 1 l 698,028 grams x (. I5) concentration of Rotenone in Product = 34,901 grams of Rotenone in SNSWP Volume of pond discharged in 24 hours at Pump rate of 5,000 gpm = 7,200,000 Grams Rotenone in pond X gals discharged in 24 hrs - Grams discharged in 24 hours Total Pond Volume in Gals 34,901 grams of Rotenone 8,640,000 1,636 Grams Rotenone Day = D.R. at 6,000 gpm pump rate 184,350,203 rppppp� Products 6 -422 Prento PreofishT Toxicant Material Safety Data Sheet U.S. Department of Labor (OSHA 29 CF R 1910.1200) Manufacturer's Names Prentiss Incorporated C. B. 2000 :Floral Park, NY 11001 Telephone Number: (1) 326-191 Section 1s Chemical Identification Products 6-422 EPA Signal Word.DANGER AM W An(CAS # g3-79-4) Other Cube wins (10%) : N/A Chemical Names: Rotenone — NIA Chemical Cuss: Mixture Section 2: Composition/ Information On Ingredients OSHA AC GIH NTP/1ARC/OSHA Materials P1EL �TLV` Other Carc ono n Rotenone ('TWA) 5 mg/ M (STET al 0 mg/M3 No/No/No (TWA) 5 mg/M3 Other associated cube resins Not Est. Not Est: .Aromatic Petroleum Solvent (Supplier recommendation 100 ppm) (CASs# 472-94-) (Not to exceed SOT) Contains the following ingredients, by weight (typical): Naphthalene (CAS # 91-20-) 9.9% (TWA) 10 pprn 1,2,4-trimethylben aerie (CAS # 95-63-6) 1,7% (TWA) 25 plain Acetone (CAS # 67-64-1) (not to exceed 7.5%) (TWA) 250 ppm Emulsifier #1 (CAS # NIA) 1.5% N/D E ulsifier #2 (CAS # N/A:) 4.5% N/ Section 3s Hazards Identification Clear liquid with mild odor. Fatal if inhaled. May be fatal if swallowed. Harmful if absorbed through skin. Causes substantial but temporary eye injury. Causes skin irritation. This pesticide is extremely toxic to fish. Potential Health Effects. Primary Routes of Entry: Inhalation, ingestion, skin and eye contact Page -1 PpPraduct: 655-422 Prentox(R) Prenfish'T" Toxicant Health Hazards (Acute and Chronic): Causes mucous membrane irritation. Chronic exposure can cause damage to liver and/or kidneys. May be fatal if swallowed. May cause eye injury, Causes skin irritation. Do not get in eyes, on skin or on clothing. T9xJcJty.9f other coin ents; This product Von contains an aromatic solvent. Inhalation of solvent vapors at high concentrations are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anesthesia, drowsiness, unconscionsmess, and other central nervous system effects, including death. Aspiration of solvent during vomiting may cause mild to severe pulmonary injury, possibly progressing to death. Frequent or prolonged skin contact may initate and cause dermatitis. Skin contact may aggravate an existing dermatitis condition. Emulsifiers may cause severe eye injury. Signs and Symptoms of Overexposure: Can cause skin irritation. Ingestion or inhalation call cause numbness, nausea, vomiting and tremors. Medical Conditions Generally Aggravated by Exposure: None known. Section 4: First Aid Measures If swallowed, call a physician or Poison Control Center, Do not induce vomittin This product contains aromatic petroleum solvent. Aspiration may be a hazard. Promptly drink a large quantity of milk, egg white, and gelatin solution, or if these are not available, water. Avoid alcohol. If inhaled, remove victim to fresh air. If not breathing, adtninister artificial respiration, preferably by mouth to mouth. Get medical attention. If on skin, wash with plenty of soap and water. Get medical attention if irritation persists. If in eyes, flush eyes with plenty of water. Get medical attention if irritation persists. Section 5-Fire X!ghtipg Measures Fire and Explosion Flash Point (Method Used): 600 F. Closed cup. Flammable Limits-. LEL: 1.8 UEL 11.7 (Solvent -approximate) NFPA Hazard Ratings: Health- 3 Flammability: 4 Reactivity- 0 Extinguishing Media: CO2, foam, dry chemical, or water spray. Special Fire Fighting Procedures- Do not inhale smoke. Use self-contained breathing apparatus and protective clothing. This product is extremely toxic to fish, and is toxic to birds and other wildlife, prevent spread of contaminated runoff. Unusual Fire and Explosion Hazards: When heated to decomposition, product ernits acrid smoke and fumes. Flammability Classification/Rating: NFPA/OSHA Class: I NFPA Rating (Fire): 4 Section 6* Accidental Release Measures Wear protective equipment, as required, to prevent contact with product or its vapors. Cover the spilled material with generous amounts of absorbent material, such as clay, diatomaceous earth, saDd or sawdust. Sweep the contaminated absorbent onto a shovel and put the sweepings into a salvage drurn. Dispose of wastes as below. Place any leaking container into a similar drum or glass container. Mark, the drum or container with name of product, ingredient statement, precautionary statements and signal word. Contact us for replacement label. This product is extremely toxic to fish. Fish kills are expected at recormnended rates. Keep it out of lakes, streams or ponds except -under use conditions, Page - 2 P 7.. FD_ _. Product- 655-422 Section 7: Handth Do not contaminan temperature extrern skin. Avoid contac Other precaution, Section-8: Exposu Prentox* Prenfish"I Toxicant g and Stora P water, food or feed by storage or disposal. Store in a (try place away from as, Avoid inhalation of vapors. Harnifid if swallowed, inhaled or absorbed through with skin. Wear clean protective clothing. Periodically inspect stored materials. e-Controls/Persolpall Protection" organic vapor protection. Ventilation: Local Exhaust: As required to meet TLV. Special: Not applicable. Mechanical: As required to meet TLV. Other: Not applicable. Protective Gloves: Chemical resistant. Eye Protection: Safety glasses, face shield or goggles. Other protective clothing or equipment.- Wear long pants, long sleeved shirt or other body covering clothes. Avoid skin or eye contact. Work/Hygienic practices: Wash thoroughly after handling and before eating or smoking. Remove contaminated clothing and wash thoroughly before reuse. Section 9: Physical ###_Cbcmical Properties Appearance: Amber Liquid Odor: Aromatic Solvent Odor Boiling Point: N/D Specific Gravity (H2O = I)- O+9226 Vapor Pressure (niml4g): N/D Melting Point: N/D Vapor Density (Air = 1): N/D Evaporation Rate (Butyl Acetate 1): N/D Solubility in Water- Emulsifies. Section 10: Stability and Stability- Stable, Conditions to avoid for stability: None, Incompatibility: Strong acids and oxidizers, Hazardous Decomposition or Byproducts- CO, CO2 Hazardous Polymerization: Will not occur, Conditions to avoid for Hazardous Polymerization: None, Page - 3 pppppp- Product: -422 Prentox8 PrenfishTm Toxicant Section 11: Toxicological Information Acute Toxicity/Irritation Studies: (The following data were developed with Prenhsh) Ingestion: Oral LD5o 55.3 mg/Kg (Rat -- female) 4 mg/Kg (Rat — male) 178 mg/Kg (Rai — overall) ]Dermal: >2020 mg/Kg (Rabbit)! (Slightly toxic) Inhalation: 4-hour LC5() 0.048 g/l. (Rat) (Highly toxic) Eye Contact: Moderately irritating (Rabbit) Skin +Contact. Moderately irritating (Rabbit) Skin Sensitization: Non -sensitizing (Guinea Pig) (The following data were developed with rotenone technical), Muta enic Potential: Rotenone was not mutagenic when tested, Reproductive Hazard Potential: Rotenone had no reproductive effects when tested Chronic/Subehronic Toxicity Studies: Cancer Information: Rotenone was not carcinogenic when tested in rats and mice. Toxicity of Other Components: Petroleum solvent:, The supplier reports that inhalation of high vapor concentrations (over 1,000 ppm) may cause nervous system effects such as headaches, dizziness, anesthesia and respiratory tract irritation Surfactant: iCauses severe eye irritation, which could lead to permanent eye damage. Prolonged or repeated skin contact may cause discomfort and local redness. Mist can irritate the respiratory tract, experienced as nasal discomfort and discharge with chest pain and coughing. Target Organs: Eyes, skin, respiratory tract. Section 12: Ecological Information Summary of Effects: This product is extremely toxic to fish. Fish bills are expected at recommended rates. Consult your State :Fish and Game Agency before applying this product to public waters t determine if a permit is needed for such an application, Do not contaminate untreated water when disposing of equipment wastewaters. Section 13: disposal Considerations Disposal: Wastes resulting from the use of this ;product may be disposed of on site or at an approved waste disposal facility, Pesticide wastes are toxic. Improper disposal of excess pesticide„ spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the hazardous Waste representative at the nearest EPA; Regional Office for guidance, Container disposal: Triple rinse (or equivalent). Theta offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by State and local authorities, Page - 4 FPPFF"' Products 6 5-422 , Prentox PrenfishTm Toxicant Section 14s Trans ort Information DOT Classification: Pesticide liquid, flanimable, toxic, n.o.s. (Acetone, Rotenone) Hazard glass. 3, PG I Subsidiary hazard class: 6.1 DOT Shipping Labels Poisonand/or "Toxic Note: For transport purposes (49FR Part 173.132), the calculated ]-hour L 50 (Rat) is;; 0.192 rug/L Section 1s Reeulatory Information SARA Title III Classification: Section 311/312. Acute health hazard Fire hazard Section 313 Chemicals: Aromatic Petroleum Solvent (Supplier recommendation 100 ppm) (CAS #t 7 2-94- )' (Not to exceed 0%) Contains the following ingredients, by Freight (typical): Naphthalene (CAS ## 91- 0-3) 9.9% (TWA) 10 ppm 1 „2,4-tri ethylben ne (CAS # 95-63-6) 1.7% (TN A) 25 ppm This product contains a toxic chemical or chemicals subject to the reporting requirements of Section. 313 of Title III and of 40 CFR 372. Any copies or redistribution of this MS iS must include this notice. Proposition 65: This product does not contain any chernical'which is known to the State of California to cause cancer or birth defects or other reproductive harm. CER LA Reportable Quantity (RQ) None. RCRA Classifications Ignitable. TSCA. Status. Registered pesticide, exempt from T CA regulation. All ingredients are can the T CA inventory. Other: Rotenone Illinois toxic substance Massachusetts hazardous Substance New Jersey Special Health Hazardous Substance Pennsylvania Workplace Hazardous Substance Acetone Massachusetts Hazardous Substance New Jersey Environmental Hazardous Substance New Jersey Special health Hazardous Substance New: Jersey` Workplace Hazardous Substance Pennsylvania Workplace Hazardous Substance Page W ppp- pppua.. Section 11,61 Other Information NFPA Hazard Ratings: Health: 3 0 Least Flammability: 4 1 Slight Reactivity: 0 2 Moderate 3 High 4 Severe Date Prepared: August 10, 2000 Supersedes: February 2, 1994 Reason: Revised Format The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. EPA Pesticide Fact Sheet 10188 Page 1 of 5 P!Fpnoe W Hoene PesiFi des Active ingredient Vect insr-irle aici Pr.�Peia nt i crs 4afr« tin fto rotenone EPA Pesticide Fact (r�tenate Paag€ Information. NTttkA s xanthine Sheet 10/88 rotenone EPA Pesticide Fact Sheet 1 /88 EPA Pesticide Fact Sheet Name of Chemicals ROTENONE Reason for Issuance: Registration Standard Date Issued: October 7, 1988 Fact Sheet Number. 198 1 DESCRIPTION OF CHEMICAL - Common name: Rotenone (and associated resins); - Chemical Name: (2R, 6aS 12aS)-1,2,6,6a,12,12a-he ahydro-2- isopropenyl-8,9-dimethoxy hromeno[3,4-bl uro[2,3_hlchromen- -one._ - Other Chemical nomenclature:(R)-1,2-dihydro-8,9-dimethoxy-2- (1-methylethenyl) [1l benzopyrano [3, 4-bI furo [2, 3-h] ['1l ben opyran-6, 12- dione (9th Collective Index); 1,2,1 ,12a alpha- tetrahydro-2a- isopropenyl-8,9-dimethoxy[1] benzopyranol[3,4-b>furo[2,3-h) [1lbenzopyran-6 (6aF)-one (8th Collective Index); 1,2,12,12a tetrahydro-8,9-dimethoxy- methylethenyl)- [2R-(2a,6a,al.pha, 12a alpha)]-(1)benzopyrano (34 b)furo(2,3-h)-(1)benzopyran-6 (6aH)-one. -- Other Names: esker -root; ; Derris; derrzs root; Nicouline; Rotacide;-Protex; Tubatoxzn; and tuba -root; ENT-133; Barbasco-; Cube; Haiari; Nekos; and Timbo. - Chemical Abstracts Service (CAS) Number: 83-79-4 - EPA Pesticide Chemical Code (Shaughnessy Number): 71003- rotenone; 71004 - cube resins other' than rotenone; 71001'-- derris resins. - Year of Initial Registration: 1947 - pesticide Type: Botanical - Producers. Penick-Bio UCLXF Corporation' and Prentiss Drug and Chemical Company 2 USE PATTERNS AND FORMULATION Registered Uses: -- Terrestrial Food Crops: Rotenone is registered for foliar preharvest application, to vegetables, berries, tree fruit, nuts, forage crops, and sugarcane. - In addition to foliar applications; delayed dormant applications are made to deciduous tree fruit. - Soil applications may be made to vegetable crops, berries and tree nuts, - "Terrestrial Nonfood rota;: Ornamentals, turf, shade trees, and tobacco. - Greenhouse Food Crop: Vegetables. - Greenhouse Nonfood; Ornamentals: - Aquatic Non -Food Crop: Fish: - Domesticated Pets and Their Man-made Premise: Cats and Dogs. - Livestock Cattle (Beef and Dairy), Goats, Horses, Sheep, and Swine. - Household: Flying and crawling insects, - Commercial and Industrial Use: Flying and crawling insects, - Methods of Application: Dust, sprays, dips; and pumping liquid formulations into bodies of water. http:llp ep.cce.cornell.edulprofileslinsect- itelpropetatnhos-zetacyp rmlrot non l nsect-,., 11 /2011 Pp7h'e EPA Pesticide Fact Sheet 10/88 Page 2 of- l Usage: 50,000 to 120,000 1b - 'Predominant Usage: Aquatic (piscicide); agriculture (potatoes, tomatoes, pears, apples); livestock, pets, and household - Formulations: The following formulations are registered 0.4-5W dusts; up to:5 wettable powders. (WP) up to 0.55 lb/`gal emulsifiable concentrate (EC); up to 1.25% soluble concentrate/liquid (SC/L); up to 5%; wettable powder/dust (WP/D) up to 2.5W;emulsifiable concentrate (EC); up to 1.5%; soluble concentrate/liquid ( C/L); ready -to -use: (RTU) at 0.1% or less; and up to 0.1% pressurized liquid (PrL) 3. SCIENCE FINDINGS Chemical/Physical-Characteristics of Rotenone unspecified) and its associated resins: - Empirical Formula: C23H2206 - Molecular Weight: 34.4 - Color: colorless (rotenone, purity 9.5`) - Physical State Crystalline solid -- Specific Gravity: 1.27 at 20 degrees C - Melting Point: 165-166 degrees C Solubility: Water 0.0000 g/100 ml at 20 degrees C; Ethyl alcohol 0.2 g/100 ml at 20 degrees C; Carboy tetrachloride '0.6 g/100 ml at 20-C; amyl acetate 1.6 J/100 ml at 20-C; Xylene 3.4 g/100 ml at 20 degrees C; Ethylene dichloride 33.0`g/100 ml at 20 degrees C; Chloroform 47.2 g/100 ml at 20 degrees C; Acetone 6.6 g/1.00 ml at 20 degrees C; Benzene 0.0 g/100 ml at 20 degrees C; Chlorobenzene 13.5 g/100 ml at 20 degrees C. - Stability: Decomposes rapidly in organic solvents exposed to 'light and air. Toxicology Characteristics - Acute oral;LD (rat): LD50 = 39.5 +/- 2.21 mg/kg for female rat. and 102 +/- 12.6 mg/kg for male rats. - 6 Month Feeding (dog): NOEL = 0.4 mg/kg/day; LEL _ 2 mg/kg/day; levels tested. 0, 0.4, 2, and. 10 mg/kg/day. - 2 Year Feeding (rat): NOEL = 7.5 ppm; LEL = 37.5 ppm; levels tested 0, 7.5, 37.5 and 75 ppm. - 2 Year Oncogenicity (rat); Negative for oncogenic effect. - 2 Year Oncogenicity (mouse): Negative for oncogenic effects at doses below the MTD. - 'Teratology (rat and mouse) : No fetal effects at rates below NOEL for adults. - Reproduction Toxicity (rat): Reproductive NOEL = 37.5 ppm; Maternal Toxicity NOEL = 7.5 ppm; levels tested 0; 7.5, 37.5, and 75 ppm. No reproductive effects were noted. - Gene Mutation: Rotenone dad not induce gene mutations in bacteria or yeast, but it increased the frequency of gene mutations in mouse lymphoma cell in vitro without met.bolic activation. No mutations were induced in mice in vivo by rotenone•. No chromosomal effects were observed in rats or mice treated with rotenone, and yeast treated with rotenone did not show increased mitotic recombination or mitotic gene conversion. Physiological and Biochemical Characteristics http://pm p.cc .cornell.edu/profiles/insect-mite/propetamphos-z tacyperm/rotenone/insect-... 2/1/ 01 i Pp7ne EPA Pesticide Fact Sheet 10/88 Page 3 ofManism of pesticidal action: Rotenone is an inhibitor of oxidative phosphorylation Environmental Characteristics - Rotenone is rapidly degraded in soil and water with days for bath aerobic aquatic and anaerobic aquatic soils. - Avian Acute Oral LC50 Mallard 2200mg/kg Pheasant 1680g/kg - Fish AcuteLC50 Rainbow Trout 22.5 ppb Channel Catfish 2.6-.8 ppb - :Aquatic Invertebrate-EC50 TOLERANCES - Currently, use of rotenone or derris or cube roots on growing crops is exempt from the requirement of tolerances, and neither tolerances nor exemptions exist for rotenone residues in animal commodities, 4. SUMMARY OF REGULATORY POSITION Rotenone is not being referred to Special Review because none of criteria for special review were met. Cranberry and piscicide uses are classified for restricted use. Users mint consult their State Fish and. Game Agency before applying rotenone products. Because of significant data gaps on the effects of rotenone in upland game birds, waterfowl, estuarine and marine organisms, a statement is required on all end -use products giving directions for use for killing fish.- The statement requires mandatary consultation with state or federal fish and wildlife agencies and will minimize effects on non -target organisms. The Agency is concerned about residues and metabolites of rotenone and associated resins in/on plants and animals. Data on the metabolism and nature of rotenone residues are needed to reevaluate the tolerance exemption. Water treated with rotenone must not be used as potable water or for irrigation of crops. A restriction against use of rotenone within one half mile of potable water or irrigation intakes must be included on labels of products intended for use in cranberry bogs and for control of fish. This statement will be an :interim precaution until data on residues in water are available. 5. SUMMARY OF MAJOR DATA CAPS http:// m .cce.comell.edu/profiles/insect-mite/propetamphos-z cyperm/rotenone/insect-,,. 2/1/2011 OV EPA Pesticide Fact Sheet 10/88 Page 4 of 5 Toxicology Acute dermal toxicity, primary eye and skin irritation studies, dermal sensitization study,: histological examination of the low and mid dose groups in the rat chronic feeding study. - Environmental Fate: Hydrolysis, photodegradation in water and on soil, aerobic sail and aquatic metabolism, leaching, terrestrial and aquatic field dissipation, confined rotational crop study, and: irrigated crop accumulation.' - Environmental Safety: Effects on upland game birds, waterfowl, and estuarine and marine organisms. - Residue Chemistry: Plant, livestock, and fish metabolism; method validation, residue data for each registered commodity and their processed products; food handling establishment residue data, and all product chemistry data: 6. LABELING REQUIREMENTS Products containing rotenone intended or terrestrial (food and non- food) and domestic outdoor uses must include the following statement on the label: "This pesticide is toxic to fish.. Do not apply directly to water or wetlands (swamps, bogs, marshes, potholes). Runoff and drift from treatedareasmay be hazardous to aquatic organisms in adjacent sites. Do not contaminate untreated water when disposing of equipment washwater:" Products containing rotenone intended or use in cranberry bogs must include the following statement on the label: "This pesticide is toxic to fish. Runoff and drift from treated areas may be hazardous to aquatic organisms in adjacent sites. Do not contaminate untreated water when disposing of equipment washwaters.' Products containing rotenone intended for use to kill fish must include the following statement on the label: "This pesticide is toxic to fish. Fishkills are expected at recommended rates. Consult your State Fish and Game Agency before applying this product to public waters to determine if a permit is needed for such an application. Do not contaminate untreated water when disposing of equipment wastewaters.°' 7. CONTACT PERSON AT EPA Phillip Hutton, PM 17 Insecticide-Rodenticide Branch Registration Division (TS-767C) Washington, DC 20460 (703) 557 2690 or Paul Schroeder PM Team 17 Insecticide-Rodenticide Branch Registration Division (TS-767C) Washington, DC 20460 (703) 557-2602 http://pmep.cce.cornell,edu/profiles/insect-mite/ ropetamphos-zetacyperm/rotenone/insect-.., /1/2011 pppine EPA Pesticide Fact Sheet 10/88 Page 5 of DISCLAIMER: The information presented in this Chemical Information Fact Sheet is a summary only and may not be used to fulfil data requirements for pesticide registration and reregistration. Disclaimer. Please read the pesticide label prior to use. The information contained at this web site is not a substitute for a pesticide label. Trade names used herein are for convenience only; no endorsement of products is intended, nor is criticism of unnamed products implied:Most of this information is historical in nature and may no longer be applicable. To Top • Questions regarding the development of this web site should be directed to http://pmep.cc .comell.edulprofileslinsect-mite/propetarnphos- etacypermlrotenone/insect- .. 2/1/2 11 PV ac hnt 1 Product PrenFis 5% Active Ingredient Rotenone Standby Nuclear Service Water Pond (SNSWP) was treated with 200 gallons of Prenfish with 5% Rotenone content SSWP Volume = 184,350,203 gallons 200 gals x 8.34 lb X 453.59 grams x (.9226) Specific Gravity - 698,028 grams Product gallons/ 1 lip 698,028 grams x (.05) concentration of Rotenone in Product = 34,901 grams of Rotenone in SNSWP Volume of pond discharged in 24 hours at Pump rate of 6,000 gpm 8,640,000 gpd 5,000 gpm 7,200,000 gpd 4,000 gpm = 5,760,000 gpd Grams Rotenone in pond X Gals discharged in 24 hrs = Grams discharged in 24 hours Total Pond Volume in foals 34,901 grams of Rotenone 8,640,000 1,636 Grams Rotenone Day = D.R.t 6,000 gpm discharge rate 184,350,203 34,901 grams of Rotenone 7,200,000 1,363 Grams Rotenone Day = D.R. at 5,000 gpm discharge rate 184,350,203 34,901 grams of Rotenone 5,760,000 1,090 Grams Rotenone Day= D.R. at 4,000 gpm discharge rate 184,350,203 1636 0.00014073 Receiving Stream Concentration @ 6000 gpm 11,624,908 Page 1 of 2 rry 1363 0.00011725 Receiving Stream Concentration @ 5000 gpm 11,624,908 1090 0.000094 Receiving Stream Concentration a@ 4000 gm 11,24,90 LC 0 ppm, 0.05 0.0021 = 0.000105 Calculated regulated limitation A.D.D. DF Calc 2497 + 0.23 = 1.23 2497 Volume Page 2of 2 BIOCIDE/CHEMICAL TREATMENT WORKSNEET-FORM 101 The fallowing calculations are to be performed on any biocidalproducts ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet!is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. 1. Facility Name Duke Energy, McGuire Nuclear Station NPDES # NC 0024392 Outfall # 001` County Mecklenburg Receiving Stream Lake Norman 7Q10 80 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D,D. = 2,497 (in M,G.D.) Please calculate the Instre m Waste Concentration (IWC in percent) of this discharge using the data entered above, IWC - (A.D.D.) X 100 � 2 407 X 100 = 08 % (7Q 10)(0.646) + (A. D. D) (80)(0.646) . (2,497) This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. IL What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? Pren-Fish Please list the active ingredients and percent composition. Rotenone 5 % What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a-24hr period. D.R = 1 &36 grams124hr period See Attachment 1 Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = -fluid oz. of product X 1 cal. water X 8,34 lbs. X specific gravity of product X 45159o. 128 fl. o. 1 gal. water 1 lb, Facility Name' McGuire Nuclear Station NPDES #: NC 0024392 Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (System volume, average cycles per blowdo n, holding lagoon size, etc.) Volume= 2,497 million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. N What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk: The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. = 3 Days The decay rate is equal to H1L. 0.69 = =Decay Rate (D.K,) Calculate degradation factor (D.F.). This is the first order loss coefficient. * D.F. = (Volume + (D.K.) 4 7 + (,23) 1:23 2,497 Calculate Study State Discharge Concentration: Dischg Conc. = D.R. 1,636 - .0001 mg/I (D. F. )(Vol ume)(3785) (1.23)(2,497)(3785) Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) �Dischq. Cone.} x (IWC%o) 100 = (.0001 i x (g8 = .0001 mg/ 100 Receiving Stream Concentration Ill. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mg/I). Please provide copies of the sources of this data, gLqanism Test Duration LC50/EC50 (ma/1) Rainbow Trout Acute LC50 22.5 oob Channel Catfish 2.6 - 2.8 ppb Sluegill 22.5 pbb Daphnia Magna , 21 day EC50 2.1 rmb A W: Q, Form 101 (612000) 2 Facility Name: McGuire Nuclear Station NPI PS #: NC QO24392 Choose the lowest LC50/PC50 listed above: Enter the LC50/FC50: .1 Rb If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0,05 x LC50 = _ M01 ; mg/I If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 - mgll Choose the appropriate regulated limitation from the calculations immediatelyabove and place in this blank: .0001 mg/liter From fart 11 enter the receiving stream concentration: .0001' mg/liter IV. Analysis, If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use. Person in Responsible Charge NameC/ ( rint Signature Date Person Completing This Worksheet (If different from above) �- , ^ i ' Name (Print Signature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 276 g-162 Attn: Todd Christenson Facility Name: McGuire Nuclear Station NPDFS #: NC 0024392 . Sugplemental Metals Analysis If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A separate form must be used for each metal and/or metal compound present in the biocide. List the metal', its chemical formula, molecular weight(MW), formula weight (FW), and the concentration of the metal compound in the biocide (MCC). Complete a separate form for every metal present in the biocide. Metal Chemical Formula Molecular Weight of Metal Formula Wei ht Concentration in'Biocide EXAMPLE Copper CuSO4.5H20 63.546 gimole 249. 680 glmole 0.2 % Dosage rate of Biocide (DR) (from page 1). DR = gramslday Average Daily Discharge (ADD) (from page 1): ADD = million gallons/day_ Discharge Concentration (DC) of Biocide. DR { grmslday) DC ADD ( million gallons/day) grams/million gallons Convert DC to micrograms/liter (ppb). 1 x 19 cll€t DC (pg11) = DC (grams/million gal) x = Pg1I 3.7t3a 10�' liters/million gal.; Calculate the fraction of metal in the metal -containing compound (MF): MW rams/mole MF = FW ( gramslmole) Calculate the fraction of metal in the biocidal compound (BF): BF = MF x MCC % 100 x (100) Calculate the concentration of metal in the discharge (M). M = DC x B = Pgll X pgil Calculate the instrearn metal concentration (IMC) at low flow conditions. IMC = : M x iWC ( lagll x 1 C?0 % - pg1l Regulated limitation of metal (from below): pgil NC General Stat- rfi ! Copper-! ! ! quality action Chr! ! quality standard exceed(�Values which action levels must be addressed directly by aquatic toxicity1. D. W Q. Form 101 (612000) 4 BIOCIDE/CHEMICAL TREATMENT WORKSHEET-FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to b returned with all appropriate data entered into the designated areas with calculations performed as indicated. 1. Facility Name Duke Energy, McGuire Nuclear Station NPDES # NC 0024392 Outfall # 001 County Mecklenburg Receiving Stream Lake Norman 7Q10 80 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D,D. = 2,497 (in MG.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above, IWC A.D.D. 100 2,497 X 100 98 % (7Q10)(0.646) + (ADD) (80)(0.646) - (2,497) This value (IWC) represents the Waste concentration to the receiving stream during low flow conditions. IL What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part ? Pren-Fish Please list the active ingredients and percent composition: Rotenone 5 % What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams of whole product used in a 24hr period, D.R.- 1,636 grams/24hr period See Attachment 1 Please note fluid ounces (a volume) must be converted to grams (a mans). The formula for this conversion is: Grams of product = fluid oz, of product X 1 al. water X 8.34 lbs. X specific gravity of product X 45159g, 128 fl. oz. 1 gal. water 1 lb. Prppppp- Facility Name: McGuire Nuclear Station NPDFS : NC 0024392 Estimate total volume of the water handling system between entry of biocidal product and NPDBS discharge point. On are attached sheet phase provide justification for this estimate (system volume, average cycles per blowdown, holding lagoon size, etc.) Volume= 497 million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter NIA. NA What is the decay rate (D,K,) of the product? If unknown, assume no decay (D,K.=O) and proceed to asterisk. The degradation must be stated at pH level within 1/2 pH standard unit within handling system. ' Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data, H.L. = 3 Gays The decay rate is equal to i O 9 = 23 =Decay mate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. D.F. = (XD.D)+ (D.°K.) 2,497 + (.23) 113 (Volume) ,47 Calculate Steady State Discharge Concentration. Dischg Con. = D.R. 1,999 OglJg94 mg/l (D. F. )(Volume)(3735) (1,23)(2,497)(3785) ` Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Disoh . Cone) x (IWC%) 00011.7 x s 0000921 mil 100 100 Receiving Stream Concentration Ill. Calculate regulated limitation. List all LC50 and BC50 data available for the whole product according to the following columns. (Note that units should be in'mg/1). Please provide copies of the sources of this data. . Organism Test Duration LC50/FC50 m /1 Rainbow Trout Acute LC59 22.5 oDb Channel Catfish 2. - Z8 DDb Blue ill 22.5 b Daphnia Magna-21 da FCSt 21 ppb Ppp- Facility Name: McGuireNuclear Station NPDES #: NC 0024392 Choose the lowest LC501EC50 listed above: Enter the LC501EC50: 2.1 ippb =:0021 m If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = .000105 mgll If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x "LC50 = mg/I Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: .000105 —mg/liter From 'Part II enter the receiving stream concentration: .0000921 —mg/liter IV. Analysis. If the receiving strum concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use. Person in Responsible Charge Name (Print) Signature Gate Person Completing This Worksheet (If different from above) Name (Print) Signature Date Please ;s+ub t to Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 2769 -1621 Attn: Todd Christenson R W Q. Form 101 (612000) 3 P rppp,- Facility Name: McGuire Nuclear Station NPDES #: NC 0024392 Suoolemental Metals Analysis If capper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A separate form must be used for each metal and/or metal compound present in the biocide. List the metal, its chemical formula, molecular weight (MW), formula weight (F ), and the concentration of the metal compound in the biocide (MCC). Complete a separate form for every metal present in the biocide. Metal Chemical Formula Molecular Weight of Metal Formula Weight Concentration in Biocide- EXAMPLE Copper CUS04.5H20 53.546 g1mole 249.660 gfmole 0 % Dosage rate of Biocide (DR) (from page 1)a DR = grams/day Average Daily Discharge (ADD) (from page 1). Alfa = million gallons/day Discharge Concentration (DC) of Biocide: DR ( grams/day) CSC = - ramsimi}#ion gallons ADD( million gallons/day) Convert DC to micrograms/liter (ppb): IBC (pg/1) = DC (grams/million gal) x 1 x 106 u2/,9 pg/I .785 x 106 liters/million gal. Calculate the fraction of metal in the metal -containing compound (MF): MW { grams/mo# MF = W ( grams/mole) Calculate the fraction of metal in the biocidal compound (BF): MCC o� % BF = F x 100 - x (100) Calculate the concentration of metal in the discharge (M)' DC x BF = pg/I x pg/I Calculate the instream metal concentration (IMC) at low -flow conditions: IMC = M x IWC ( -_ leg/I .x 100% leg/I 100 Regulated limitation of metal (from below). pg/1 NC Gene y.0 Copper- water a0 p9/l water quality action level* estandard exceed.(�Values which action levels must be addressed directly by aquatic tgx=.i'�_�'�"• D. W Q. Farm 101 (612000) 4 PV DIVISION OF WATER QUALITY RECEIVED 5 2 012' Duke Energy . McGuire Nuclear Station t S 1 VTi0 A To C" No. 024392A01 MOORESVILLE REGIONAL OF ��u � b Issued June 5, 2009 IF Engineer's Certification 1, r,has as a duly registered Professional Engineer in the State of North Card"a, , having been authorized to observe (periodically/weekly/full tune) the construction of the modifications and improvements to the existing dual parallel 2.5 MG Settling Fonds A and B associated with the conventional wastewater treatment system for the McGuire Nuclear Station, located at 12700 Hagers Ferry Road in Mecklenburg County, hereby' state that, to the best of my abilities, due care and diligence was used in the observation of the following construction: Relining the existing dual 2.5 M (each) Settling Ponds with a top (primary) 60 mil DE synthetic liner, a middle 200 mil geonet; synthetic mesh with imbedded leak detection system, a bottom (secondary) 60 mil HFDE synthetic liner, with associated yard piping, appurtenances and electrical work, in conformity with the project plans, specifications, and other supporting data subsequently filed and approved by the Department of Environment and Natural Resources. i certify that the construction of the above referenced project was observed to be built within substantial compliance and intent of the approved plans and specifications. Signatr�/Registration �� ���No. , Date 2- �1 Send to: Construction Grants & Loans 1633 Mail Service Center 3' a ' Raleigh, NC 27699-1633 �:,-- Duke Energy McGuire Nuclear Station i p 12700 Hager. Ferry Road Hunteisville, NC 28078 a 012 CS IJful .G 1.}1V16" y1V1VV E1LIV LVU.VIVCU OLCFC14t11 kl-41 1./3..€tJ i Vi11 14 if t\ti✓1fV4—r,Jl Lf( vva.aaxxvu cxx No. 024392AO1 in June of2009 to re -line two 2.5 million gallon chemical treatment ponds. Attached are the Engineering Certifications to close out this permit. iPond was completed in December of 2009 A Pond was completed in May of 2012 If you have questions concerning the completion of this project, please contact John C. Williamson by email at John.Willi son@duke-ener .co or phone 9 0- 75-5 94. Since ely, John C. Williamson Duke Energy McGuire Nuclear Station Environmental, health & Safety cc: Allen Stowe - Mailcode. E 131 Gary Sam — Mailcode. ECO7D Pete Bynum - Mailcode: MGO I Cl I AIV pppppp� �WIIZA' "CDAEOWR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins` Dee Freeman Governor DirectorJ� June 10, 2009 Mr. John C. "Williamson Duke Energy McGuire Nuclear Station 12700 Hagers Ferry Road Hunterville` North Carolina 28078 SUBJECT: Authorization to Construct A to C No. 02492AOI Dube Energy McGuire Nuclear Station Relining Wastewater Settling Ponds A and B Mecklenburg County Dear Mr. Williamson: letter of request for an Authorization to Construct was received June 5, 2009, by the Division of Water Quality (Division) d final plans and specifications for the subject project have been reviewed and'`found to be satisfactory. ,Authorization is hereby granted for the construction of modifications to the existing dual parallel 2.5 MG Settling Ponds A and B associated with the conventional wastewater treatment system,' with discharge of treated wastewater into the Catawba River (via NPDES Permit NCO024392 Qutfall No. 002) in the Catawba River Basin. This authorization results in no increase in design or permitted capacity and is awarded for the construction of the following specific modifications: Relining the existing dual 2.5 MG (each) Settling Ponds with a top (primary) 60 mil HPDE synthetic liner, a middle 200 mil geonet synthetic mesh with imbedded leak detection system, a bottom (secondary) 60 mil HPDE synthetic liner, with associated yard piping, appurtenances and electrical work, in conforinity with the project plans, specifications, and other supporting data subsequently filed and approved by the Department of Environment and Natural Resources. This Authorization to Construct is issued in accordance with Part III, Paragraph A of NPDES Permit No. NCO024392 issued February 14, 2006, and shall be subject to revocation unless the wastewater treatment facilities are constructed in accordance with the conditions and limitations specified in Permit No. NC0024392. 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 One Location:512 N. Salisbury St. Raleigh, North Carolina 27604+ Phone:919-807-6300 \ FAX: 919-807.6492 t Customer Service.1.877.623.6748 arolina Internet: wwriewaterquality,org " " An Equal :Opportunity \Affirmative Action Employer Pr� 7rJohn C. Williamson June 10, 2009 Page 2 The sludge generated from these treatment facilities must be disposed of in accordance with G.S. 143-215.1 and in a manner approved by the Division. In the event that the facilities fail to perform satisfactorily, including the creation of nuisance conditions, the Permittee shall take immediate corrective action, including those as may be required by the Division, such as the construction of additional or replacement wastewater treatment or disnosal facilities. The Mooresville Regional maintenance of the facility, and m,ust'comply with all other conditions of T15A:8G.0202. A copy of the approved plans and specifications shall be maintained on file by the Permittee for the life of the facility. During the construction of the proposed additions/modifications, the permittee shall continue tos properly maintain and operate the existing wastewater treatment facilities at all times, and in such a manner, as necessary to comply with the effluent limits specified in the NPEES Permit. A PppppMr, John C. Williamson � June 10, 2009 Page You are reminded that it is mandatory for the project to be constructed in accordance with the North Carolina'Sedimentation Pollution Control Act, and when applicable, the North Carolina Dam Safety Act. In addition, the specifications must clearly state what the contractor's responsibilities shall be in complying with these Acts. Prier to entering into any contract() for construction, the recipient must have obtained all applicable permits from the State. Failure to abide by the requirements contained in this Authorization to Construct may subject the Permittee to an enforcement action by the Divisionin accordance with North Carolina General Statute 14- 1 .6A to 143-215.6C. The issuance of this Authorization to Construct does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed b other government agencies (local, state, and federal) which have jurisdiction. One (1) set of approved plans and specifications is being forwarded to you. If you have y questions or need additional information, please contact Seth Robertson, P.E. at telephone number (19) 1 '-b206 Sincerely, t rs t n kp:sr cc: Ralph CGehrig Aust Mecklenburg C'ota DWQ Mooresville DWQ, Technical' DWQ, Point Sou c Ken;Pohlig, P.E. ATC� File LO'Coleen H. Sullins in, Jr.,, P.E., DukeEnergy, McGuire Nuclear Station, Huntersville, NC my Health Department Regional Office, Surface Water Protection Assistance and Certification. Unit e Branch, NPDES Program ppppr� Duke Energy McGuire Nuclear Station To C No.024392AOI Issued .Tune 5, 2009 Engineer's Certification I, s a club registered Professional Engineer in the Mate of North Carolina, having been authorized to observe (periodically/weekly/full time) the construction of the modifications and improvements to the existing dual parallel 2.5 MG Settling Ponds A and B associated with the conventional wastewater treatment system for the McGuire Nuclear Station, located at 12700 Hagers Perry Road in Mecklenburg County, hereby state that, to the best of my abilities, due care and diligence was used in the observation of the following construction: Relining the existing dual 2.5 MG (each) Settling Fonds with, a top (primary) 60 mil HPDE synthetic liner, a middle 200 mil geonet synthetic mesh with imbedded leak. detection ,system, a bottom (secondary) 60 mil HPDE synthetic liner, with associated yard piping, appurtenances and electrical work, in conformity with the project plans, specifications, and other supporting data subsequently filed and approved by the Department of Environment and Natural Resources, I certify that the construction of the above referenced project was observed to be built within substantial compliance and intent of the approved plans d specifications. Signature Registration No, .date Send to: Construction r is & Leans DElJ WQ 1633 Mail Service Center Raleigh, NC 27699-1633 }a �Duke Energy McGuire Nuclear station PP)FdrIffnergy, 12700 Hagers Ferry Road Huntersville, NC 29078 June 4, 2009 . Ken Pohltg North Carolina Department of Environment And Natural Resources Construction, Grants and Loans Section 2728 Capital Boulevard Raleigh, NC 2 604 Subject: Duke Energy ltl4 McGuire Nuclear Station Authorization to Construct Permit NPDES Permit No. NC 024392 ' 4 Mecklenburg County � .k.. Dear Mr. Pohlig McC��"uire Nuclear Station submits the attached Authorization to Construct permit application to line our two 2.5 million gallon waste water treatment ponds with 60 mil H .APE litters and coat our concrete initial holdup pond with a polyurethane coasting. We intend to coat the initial holdup pond and one of the waste water treatment ponds beginning in July of this year, and line the remaining waste water pond in 2010. e attached ATC permit application includes two sets of project design drawings, signed., sealed and dated by a NC Professional Engineer, two sets of technical specifications signed., sealed and dated by a NC Professional Engineer and other required documents as specified in the ATC application, Additionally, I have included a high level project overview, a drawing showing the ground water lever at the; pond locations (drawing # 9/15), a drawing showing the monitoring wells onsite (drawing # 10/15) a table showing the ground water depth at the various monitoring well locations (table 5) a drawing showing; the current configuration of our waste water treatment ponds and initial holdup pond (drawing MC 1025-01), a drawing showing the piping layout o the pond in its current configuration (MC- 1506-04.85-0 ), and finally a topo trap of the site (drawing 2/15). A high level overview of the projects provided below I. Remove the existing Mudge from the Initial Holdup fond, Waste Water Treatment Ponds A and E, and transport the sludge to the McGuirelandfill for disposal 2. Remove the existing discharge carbon steel piping and replace it with HDPE pipe. 3. Prepare liner bed for installation . Line the waste water treatment ponds A and B with a synthetic 60 mil HPI E double liner with a leak detection. system 5. Leah test the liners i. Coat the Initial Holdup Pond., which is a concrete lined pond, with polyurethane coating Pppp'Install an animal control Fence around the perimeter of the waste water treatment ponds d B. This project will be overseen by McGuire Major Projects and implemented by Tetra. Tech Inc. of Oak Ridge Tennessee. If you have questions concerning this ATC Permit application, please contact John C. Williamson by email at o . ill son duke- ner or phone 704-875-5894. Sin y, Vohn C. Williamson Duke Energy McGuire Nuclear Station Environmental, health & Safety cc: Allen Stowe -- Mailcode: ECt13iC Gary Sain — Mail de. EC 07D Jeff Cage _ Mai code: MG01C"I Mark Francis — Mailcode. MG0273 Gehrig Austin — Mailcode. MG0273 M-20 M- 1' M- 2R M 3 M-3t M M-31' M-3 -' a M-33 ALA' a Paige 1 of 2 *S&ME ;kl 1 Ce�1 4 %99 19 ►. 9, 3224 1.29 15.58 L8611 1014 L28 41.46 "39 887 iYO 5:94 L80 33.5 03 12.06 L05 5.27 44ZIII 16.58 yh.52 44.48 1.72 0:13 1.t37 &q, W7 44.56 Ground elevations surveyed by Duke Energy M ft-bis = Feet below land surface J9 8.7 tt-msl - Feet relative to mean sea level p.88 9:85 1.15 9.65 - �14 »7T J2 10.88 .88 53.21�� 50A 30 '0 28. d dR4 LAKENORMAN MAINTENANCE MONITORING PROGRAM: 07 SUMMARY McGuire Nuclear Station: NPDES No. NCO024392 Principal Investigators: Michael A. Abney John E. Derwort William J. Foris DU ENERGY Corporate EHS Services :McGuire Environmental Center 13339 Halters Ferry Road Huntersvile, NC 207$ December 2008 4 A 4 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Pardue Coleen H. Sullins Dee Freeman Governor Director Secretary R'r r-"*& aRIFD March 2, 2003 Mr. Bruce H. Hamilton Duke Energy McGuire Nuclear Station,. 12700 Hagrs Ferry Road Fl- ; �,.. " Huntersville, NC 8078 % x � � �i° t r� ion Dear Mr. Hamilton: Staff of the Environmental Sciences Section of DWO have reviewed the Lake Norman Maintenance Monitoring' Program: 2007 Summary Report. The report is required by NPDES permit number NG0024392 for the McGuire Nuclear Station. The water chemistry, phytoplankton, zoo lankt n, and fisheries data compiled in the report are within the ranges found in prior years of the maintenance monitoring program, so staff have no major concerns at this time. Sincerely, �Jlmleverton Chief, Environmental Sciences Section cc: Thomas Belnick, Western NDS Program Rob Krebs, M O w/ rpt Environmental Sciences Section 1621 Mail Service Center, Raleigh, North Carolina 27699-1621 One Location-, 4401 Reedy Creek Road, Raleigh, North Carolina 27607 No thCairolin Phone: 19-743.8400 1 FAX: 919-743-8517 0 Customer Service, 1-877-623-6748 Internet http:t/h2oenr.state.nc.us/esb/ An Equal Opportunity t Affirmative Action Employer Duke PO�Energy,-,, Duke Energy McGuire nuclear Station 12700 Hagers Ferry Road iluntersvilte, NC 28078 February 1, 209 r , Mr. Jimmie R. Overton North Carolina Department of Environment d Natural Resources Environmental Sciences Section 1621 Mail Service Center Raleigh, NC 27699-1621 ion Subject; McGuire Nuclear Station Lake Norman Environmental Monitoring Program: : 2007 Sulurnary Report Certified: 7007 0220 0002 5535 228 Dear Mr. Overton. - Enclosed are three copies of the annual Lake Norman Environmental Monitoring program: 2007 Summary deport, as required by NPDES permit NCO024392 Results lts of the 2007 data were comparable with that of previous years. No obvious short-term or long-terlong-teim impacts of station operations were observed in water quality, phytoplankton, zooplankton, and fish communities. additionally, 2007 station operation data demonstrates compliance with permit thermal limits and cool water management requirements, Fishery studies continue to be coordinated with the Division of Inland Fisheries of the forth Carolina Wildlife Resource Commission to address lake Norman's fishery management issues. If you have any questions concerning this report, please contact John Williamson by phone at 70 875- 94 or by email at jcwilliamson@duke-energy.co Sincerely, Bruce H. Hamilton Duke Energy McGuire Nuclear Station Site Vice President LAKENORMAN MAINTENANCE ONITO N u 2007 SUMMARY McGuire Nuclear Station; NPDES No. NCO024392 LLJ Lij Principal Investigators. Uj Michael A. Abney' Jahn E. Derwort William J. Doris Prepared By. Date:c`/ a 4 l Reviewed By Date: Checked By: - Date: Approved By Date: DUKE ENERGY Corporate EHS Services RECFllfi McGuire Environmental Center 13339 Hagers Ferry Road A I� untersville, NC 28078 ` December 2008 x' Pfoi"ed'ion ACKNOWLEDGMENTS The authors wish to express their gratitude to a number of individuals who made significant contributions to this report. First, we are much indebted to the EHS Scientific Services field staff in carrying out a complex, multiple -discipline sampling effort that provides the foundation of this report. Kim Baker, Dave Coughlan, Bob Doby, Duane Harrell, Bryan Kalb, Glenn Long, and 'Todd Lynn conducted fisheries collections and sample processing. Jan Williams, Brandy Starnes, Bill Foris and Glenn Long performed water quality field collections. John Williamson assembled the plant operating data; Jan Williams, Brandy Starnes, Glenn Long, and John l erwort conducted plankton sampling, sorting, and taxonomic processing. e would also like to thank the following reviewers for their insightful commentary nentary and suggestions: Ron Lewis, and Jahn Vlte. Sherry Reid compiled this report. ii TABLE OF CONTENTS EXECUTIVESUMMARY ............................. ............................ .................................... ..:... v LISTOF TABLES......:: ..........................: . .............. ........::.....................................,.. x LISTOF FIGURES ....................... .......................................................... ............................ xii CHAPTER 1- MCGUIRE NUCLEAR STATION............................................................ 1- INTRODUCTION::............................_..................................................................1-1 OPERATIONAL DATA FOR 2007 ........................... ................ ..........................1-1 CHAPTER - WATER CHE T Y............................................................................ -1 INTRODUCTION............... .... ............. ..............::.............................................. -1 METHODS AND MATERIALS .............. ..... ..........___, .......... ....-......................2-1 RESULTS AND DISCUSSION.......................................:.......:...........................2-4 Precipitation and Air Temperature ......... ............................................................ 2-4 Temperature and Dissolved (oxygen ......................................... ........................... -5 Reservoir -Wide Temperature and Dissolved Oxygen .......... ....................................... 2- Striped Bass Habitat..... ...: ................... ............................................................2- Turbidity and Specific Conductance .......... ................................................ ....:...........2-1t} pHand. Alkalinity ........................ ..... . .............................................................. -11 MajorCations and,Anions ......................................................,....................... 2-11 Nutrients..................,.......,...::.,......:......................................., ..........................2-11 Metals.............:......................:..............:...........................:..........., , .............2-12 FUTURESTUDIES ..................................... ....:............................................. ,............2-13 SUMMARY., ..................................................................................... .................2-1 CHAPTER - PHYTOPLANKTON ................................................................................ 3-1 INTRODUCTION....:......................................................................................... 3-1 METHODS AND MATERIALS .....:........... .................::.....,.................................... -1 RESULTS AND DISCUSSION.......................,...............,.::.......................,.........._ 3-2 StandingCrap................................................................................................... -2 Chlorophylla .. ........ .................................................................................................. 3-2 TotalAbundance ...... ............. ............................................................................... ........ -4 Sesto.......... .....................................:::.:......,,..:..;.,,.........,.........::.....................3- SecchiDepths..........................................................................................................-..3- Community Composition,..........................................._..,........................................ 3-5 Species Composition and Seasonal Succession ........................................ .... ........3- FUTURESTUDIES ................................................................................................. 3-7 SUMMARY..................:...............:......,.....................:..:....,.............................. - CHAPTER- ZOOPLANKTON ..................................................................................... 4- INTRODUCTION........... ................................. .............................................. ................. 4-1 METHODS AND MATERIALS ............................................................. .................. -1 iii RESULTS AND DISCUSSION..........::..................................................... . .........4- Total Abundance ............. ........:........... ......................». ,...................................4-2 Community Composition....................................,.:......................... ..................4-4 Coepo a....................................... ............................................ ....,............ ......... ,.... 4-4 Rotifers...:.......::........................:..........:....... . ..........:.:.:.... .......... ....».:.......:; 4-5 FUTURESTUDIES ........... ...........................,...............:.................:................4-5 SUMMARY........................................................................................................ 4-5 CHAPTER5- FISHERIES ..........................................................................................5- INTRODUCTION... ..................... .................. ............ ................. ...............................5-1 METHODS AND MATERIALS ..................................:..................................... -1 Spring Electrofishing Surveys ............ ........ ........................»; .................:........ 5-1 Fall Electrofishing Surveys for Young -of -Year Bass ................... ......................... 5-2 Summer Striped. Bass Mortality Surveys .......................:................................... -2 Striped. Bass Netting Survey .. ............ ............................... :.................................... 5-2 Fall Hydroacoustics and Purse Seine Surveys ........................... ........................... -3 Crappie Trap -Net Survey ...........»...................................................................... 5-3 RESULTSAND DISCUSSION .................... ......:.....:.:,...................:..................5- Spring Electrofishing Surveys»...................................... ....:.................. » ................. 5-3 Fall Electrofishing Young -of -Year Bass Surveys ......................:...:....................... 5-5 Summer Striped Bass Mortality Surveys ...................»........................................ 5-6 StripedBass Netting Survey ............... ......................................................... ......... ...... -6 Fall Hydroacoustics and Purse Seine 5-6 CrappieTrap -Net Study .................................. ....................... ................. . .................. 5-7 FUTSTUDIES ................................ ............... ....,.............................................: 5-7 SUMMARY........... .:......... .»..».....:..........,.....,...,.............:.....:...............................5-7 LITERATURE CITED ......»...........................:....................................................: L-1 iv EXECUTIVE SUMMARY In accordance with National Pollutant Discharge Elimination System DE) pennit number NCO024392 for McGuire Nuclear Station ( S), the Lake Norman Maintenance Monitoring Program continued during 2007. Overall, no obvious long-term impacts o station operationswere observed in water quality or phytoplankton, zooplankton, and fish communities, The 2007 station operation data are summarized and continue to demonstrate compliance with thermal limits and cool water requirements. The monthly average capacity factors for MNS in 2007 were 101.9, 101.4, and 101.6% during July, August, and September, respectively. The average monthly discharge temperature was 97.2 °F 3. °C) for July, 98.8 °F (37.1 °C) for August, and 97.9 °F (36.6 °C) for September 2007, below the 99.0 °F (37.2 °C) thermal limit for these months. The volume of cool water in Lake Norman in 2007 was adequate to comply with both the Nuclear Regulatory Commission Technical Specification requirements and the NPDES discharge water temperature limits. Annual precipitation in the vicinity of MNS in 2007 totaled 78.2 cm and was the third lowest measurement reported over the period 1975 — 2007, with lower values being recorded only in 1981 (6.4 cm) and 1986 (76.5 m). Air temperatures near the S in 2007 were warmer than bath 2006 and the long-term mean for the months of March, .August, September, and October. Temporal and spatial trends in water temperature and DO in 2007 were similar to those observed historically, and all data were within the range of previously measured values. Water temperatures in 2007 for the months of January, March, and April ranged from 0.1 to 3.8 °C warmer than measured in 2006 in both the mixing and background zones, whereas 007 February temperatures were as ;much as 2.2 °C cooler than observed in 2006. These interannual differences in water temperatures paralleled differences exhibited in monthly air temperature data, but with about a one -month lag. Reduced operations of Unit ] at MNS in March and April 2007 also contributed to these interannual differences during the winter and early spring. Summer water temperatures in 2007 were generally similar to those observed in 206 in loth zones, with one notable exception. Surface water temperatures in the mixing zone in June 2007 were up to 2.7 °C cooler than observed in 2006, and appeared to be related primarily to reduced operations of Unit 1 rather than to interannual differences in air temperature. Late summer, fall, and early winter water temperatures in 2007 were consistently warmer in both zones than those measured in 2006, and followed the trend exhibited in air temperatures. The most striking differences were observed in the mixing zone in November when 2007 temperatures were as much as 4.4 °C warmer than measured in 2006. Temperatures at the discharge location in 2007 were generally similar to 2006 and historical data. Temperatures in 2007 were slightly cooler in the spring, and warmer in the fall than observed in 2006. The wan -nest discharge temperature of 2007 at Location 4 (37.8 °C) occurred in September and was identical to the maximum measured in 2006. Seasonal and spatial patterns of DO in 2007 were reflective of the patterns exhibited for temperature; i.e., generally similar in both the mixing and background zones. Winter and spring DO values in 2007 were either equal to or slightly lower, in both the background and mixing zones, than measured : in 2006 and appeared to be related predominantly to the differences in water column temperatures in 2007 versus 2006 Summer DO values in 2007 were highly variable throughout the water column in both the mixing and background zones ranging from highs of 6.0 to 8.4mg/L in surface waters to lows of 0.0 to 2.0mg/L in bottom waters. This pattern is similar to that measured in 2006 and earlier years. All dissolved oxygen values recorded in 2007 during this period were within the historical range. Considerable differences; were observed between 2007 and 2006 late summer and fall DO values in both the mixing and background zone, especially in the metalimnion and hypolimnion during the months of September, October, and November. The 2007 late summer and autumn DO data indicated that fall convective reaeration proceeded slower and was less complete throughout the water column than observed in the corresponding months in 2006. Consequently, 2007 DO levels in either a portion or all of the water column were less than observed in 2006. The seasonal pattern of D4 in 2007 at the discharge location was similar to that measured historically, with the highest values observed during the winter and lowest observed in the summer and early fall. Fall DO levels in 2007 at Location 4.0 were slightly lower than observed in 206 due to warmer temperatures. The lowest DSO concentration measured at the discharge location in 200 (5.5 mg/L) occurred in September and was identical to that measured in August, 2006; it was also 1.4 mg/L higher than the historical minimum measured in August 2003 (4. mg/L); Reservoir -wide isotherm d isopleth information for 2007, coupled with 'heat content and hypolinmetic oxygen data, illustrated that Lake Norman exhibited thermal and oxygen dynamics characteristic of historical conditions and similar to other Southeastern reservoirs of comparable size, depth, flow conditions, and trophic status. Suitable pelagic habitat conditions for adult striped bass in 207 were most recently similar to conditions measured in v1 06 when habitat elimination was observed for a period of about 50 to 60 days during the summer. Observed striped bass mortalities in 2007 totaled thirteen fish. All chemical parameters measured in 2007 were similar to 2006 and within the concentration ranges previously reported for the lake during both preoperational and operational years of S. Specific conductance and nutrient values and all concentrations of cations and anions were tow. Concentrations of metals were also low and often below analytical reporting' limits. All values reported for cadmium, lead, zinc, and copper in 2007 were below the State water ,quality standard or action level for each of these metals. Manganese and iron concentrations in the surface and bottom waters were generally low in 2007, except during summer and fall when bottom waters became anoxic, thereby creating a chemical environment conducive for the release of these species into the water column. Only one iron value recorded in the bottom waters at Location 5.0 in August, exceeded the State action level of 1.0 mg/L. Manganese levels, however, exceeded the State action level 0 µg/L) in the bottom waters at various locations throughout the lake in the summer and fall, This phenomenon, i.e., -the release of iron and manganese from bottom sediments into the water column, in response to law oxygen levels, is common n in stratified waterbodies. Chlorophyll concentrations were generally within historical ranges during 2007. Several record low chlorophyll concentrations were recorded in November. Lake -wide mean chlorophyll increased ftom, February through August, then declined to the annual minimum in November. Maximum chlorophyll concentrations were typically observedup-lake at Location 69.0, while minimum chlorophyll concentrations were recorded from down -lake at Locations 20 through 9.5. The highest chlorophyll value in 2007 (1. µg/L) was well below the NC State Water Quality standard f 40 g/L. Phytoplankton densities and biovolu ` es were generally higher in 2007 than in 2006. Higher standing crops were usually observed at up -lake locations, while lower values were noted down -lake. Standing crop values were lower than the NC guidelines for algae blooms Seston dry and ash -free weights were most often lower in 207 than in 2006. Down -lake to up -lake differences were apparent during all quarters. Maximum dry and ash -free weights were generally observed at Location 69.0, while minimum values occurred at Locations 2. through 8.0. vii ecchi depths reflected suspended solids, with shallow depths related to high dry weights. The lake -wide mean sechi depth was slightly higher in 2007 than in 2006 and within historical ranges observed since 1992. Diversity of phytoplankton taxa in 2007 was the highest recorded since the beginning of this monitoring program. The taxonomic composition during 2007 was similar to many previous years. Cryptophytes were dominant in February, while diatoms were dominant during May d November. Green algae were dominant during August. Blue-green algae were slightly ore abundant in 2007 than in 2006, however, their contribution to total densities was rarely" over 3%. e cryptophyte Rhod monas rninuta was the most abundant alga each year of the Lake Norman Maintenance Monitoring Program: The diatom Fragillar°ia cr otonensis was the most abundant diatom in May, while Tabellar°ia fen strata and Melosira arnbigua were dominant in November. The small des id, C smar°iurn asphearosporum var. str°iggosum was dominant in August 2007. These taxa have been common and abundant throughout the program. Maximum zooplankton densities occurred most often in the spring of 2007. Minimum oopl nkton densities were generally noted in the fall. Epilinmetic densities were higher than whole -column densities as in, previous years. Mean zooplankton densities were usually higher among background locations than among mixing zone locations in 2007. Spatial trends of zooplankton population densities increased from down -lake to up -lake locations. year-to-year -spring trend of increasing zooplankton densities among mixing zone locations was observed from around 1997 through 2005. Densities at these locations declined sharply in 2006 followed by an increase in 2007. Long-term trends showed much higher year-to-year variability at background locations than at mixing zone locations. Epilinmetic zooplankton densities were generally within the ranges of densities observed in previous years. Record high densities were observed during winter at Location 1.9 and summer at Location 9.5. Since the Lake Norman Maintenance Monitoring Program began in 1987, 123 zooplankton taxa have been observed in samples. Of these, 49 were identified in 2007. Additionally; two previously unreported taxa, were identified during 2007. Overall relative abundance of copepods decreased from 2006 to 2007. Copepods were dominant in only three samples. Cladocerans were dominant in two samples and rotifers were dominant in all other samples. The relative abundance of microcrustaceans increased slightly in the epilimnion of the mixing zone, although they decreased among whole -column samples since 2006. At background locations, relative abundances of microcrustaceans i 007 were similar to those of 2006. Historically, copepods and rotifers have most often shown annual peaks in the spring, while cladocerans continued to demonstrate year-to-year variability. Copepods were dominated by immature forms. Adults rarely accounted for more than % o zooplankton densities. As in previous years, the most important adult copepod was 'ropvcycl ps. Bosmina was the dominant cladoceran as in most previous years of the program. B sminopsis dominated several cladoceran populations during the summer. The most abundant rotifers observed in 2007 as in many previous years, were Plyarthra, Kerataella, and Ptyg ra. Conochilus, Asplanchna, and Syncheata were also important among rotifer populations; In accordance with the Lake Norman Maintenance Monitoring Program fish monitoring programs continued during 2007. Spring elctrofihing indicated that numbers and biomass of fish in 2007 were generally similar to those noted since 1993. Additionally, electrofishin indicated that 12 to 20 fish species and two hybrid complexes ;comprised fish populations i the three sampling areas. Largemouth bass numbers and biomass continue to decline, and the 2007 numbers and biomass were some of the lowest recorded since sampling began in 1993. While displacement of largemouth bass since the introduction of spotted bass in the lower lake is apparent, the direct effect on largemouth bass recruitment is indeterminate, possibly due to confounding effects of ether introductions including alewife and white perch. During 2007, the number of summer striped bass mortalities (13) and winter mean relative weight (79.5) were similar to those of previous years. Hydroacoustic sampling estimated the 2007 forage fish population at approximately 72 million. This is comparable to previous years. After an increase in 2006, purse seine sampling indicated a decrease in the percentage of alewives in 2007 to the lowest percent composition since their 199 introduction. Thrafin shad lengths remained at pre -alewife introduction sizes. Lake Norman Maintenance Monitoring results from 27 are consistent with results from previous years. No obvious short-term or long-term impacts were observed in water quality or biota of Lake Norman. I Table Title Page 1-1 Average monthly capacity factors C/o) and monthly average discharge water temperatures for MNS during 2007..................:»,.................. ...., ...........:.........1-2 2-1 Water chemistry program for the McGuire Nuclear Station NPDES Maintenance Monitoring Program on Lake Norman . ........ — ................ ................ -17 2-2 Analytical methods and reporting limits employed in the McGuire Nuclear Station NPDES Maintenance Monitoring Program for Lake No ......... .»..... ..... 2-18 2-3 Heat content calculations for the thermal regime in Lake Norman for 200 d2007. .......................................:.................:.......:;........ ............»............. 2-1 2-4 A comparison of areal hypolinmetic oxygen deficits (AHOD), summer chlorophyll a (Chl a), Secchi depth, and mean depth of Lake Norman and 18 TVA reservoirs. . ................................................................. ............................... 2-20 2-5 Quarterly surface (0.3 )-and bottom (bottom minus 1 m) water chemistry for the McGuire Nuclear Station discharge, mixing zone, and background , locations on Lake Norman during 2006 and 2007 ......... .:.:....... .............................. .. 2- 1 3-1 Mean chlorophyll a concentrations (gg/L) in composite samples and Secchi depths (m) observed in Lake Norman in 2007...........».»...................................... 3-10 3-2 Mean phytoplankton densities (units/ ) and biovol es (m /m3) by location and sample month from samples collected in Lake Norman, NC, during2007»...........................................................:................ .. ................ 3-11 3-3 Total mean seston dry and ash free dry weights ( /L) ftom samples collected in Lake Norman during 2007............................................... ................3-11 3-4 Phytoplankton taxa identified in quarterly samples collected in Lake Norman each year from 1992 to 2007.............................................................. 3-1 3-5 Dominant classes, their most abundant species, and their percent composition (in parentheses) at Lake Norman locations during each sampling period of 2007................................................................ ................. -23 4-1 Total zooplankton densities (Number ;X 100/m3), densities of major zooplankton taxonomic groups, and percent composition (in parentheses) of major taxa in the epilimnion and whole column net tow samples collected from Lake No an in February, May, August, and November 2007.... » ................. 4- -2 Zooplankton taxa identified from samples collected quarterly on Lake Norman from 1987 - 2007...........................................................» ................. -1 4-3 Dominant copepod (adults), cladocran, and rotifer taxa, and their percent composition (in parentheses) of the copepod; claoceran and rotifer densities by location and sample period in Lake Norman in 2007........................... 4-1 5-1 Common and scientific names of fish collected In Lake Norman, during 2007.'....:..........»................................................................................................. 5-8 LIST OF TABLES, Continued Table Title Page -2 Numbers and biomass of fish collected from electrofishing ten 300-m transacts each, at three areas (MSS, REF, S) in Lake Norman March/April 2007 :........................ .......... ....................................................... . - 5-3 Mean total lengths ( ) at age for spotted bass (SPB) and largemouth bass (LMB) collected from electrofishing ten 300-m transects each, at three areas (MSS; REF, S) in Lake No an March/April 2007. ....................................... 5- 5-4 Comparison of mean total length (mm) at age for largemouth bass collected from electrofishing ten 300-m transects each, at three areas (MSS, S) in Lake No March/April 2007 to historical largemouth bass meanlengths........................:...................................................................... 5-1 5-5 Striped bass mortalities observed in Lake Norman during weekly surveys during July and August 2007......... .......................................................... ............... -11 5-6 Lake Norman forage fish densities (number/hectare) and population estimates from hydroaco stir surveys in September 2007.................. ................ 5-11 5-7 Total numbers and percent composition of forage fish, and modal length class of threadfin shad collected in purse seine samples from Lake Norman during late summer/fall, 1993'— 2007...................................:........................... -12 Figure ; Title Page 2-1 Water quality sampling locations (numbered) for Lake Norman. Approximate locations of Marshall Steam Station, and McGuire Nuclear Stationare also shown ...... ......................................................................................... 2-24 -2a Annual precipitation totals in the vicinity ofMcGuire Nuclear Station .................. -25 2-2b Monthly precipitation totals in the vicinity of McGuire Nuclear Station in 2006 and 2007............... ...............................................#;........................... 2-25 2-2c Mean monthly air temperatures recorded at McGuire Nuclear Station beginning in 19 ..................... ....... ...................................:......................... -26 2-3 Monthly mean temperature profiles for the McGuire Nuclear Station background zone in 2006 and 2007.......................................................................... 2-27 2-4 Monthly mean temperature e profiles for the McGuire Nuclear Station mixing zonein 2006 and 2007 ............................................ ............................................ 2-2 2-5 Monthly surface (0'3 m) temperature and dissolved oxygen data at the discharge location (Location .) in 2006 and 2007........:................................... -31 2-6 Monthly mean dissolved oxygen profiles for the McGuire Nuclear Station background zone in 2006 and 2007..............................:....................:.............. -32 2-7 Monthly mean dissolved oxygen profiles for the McGuire Nuclear Station mixing zone in 2006 and2007.:............................. .................................................. -34 2-8 Monthly reservoir -wide temperature isotherms for Lake Norman in 2007............... 2-36 2-9 Monthly reservoir -wide dissolved oxygen isopleths for Lake Norman in 007...................... ......................... ................................................... ,...................... ,. 2-9 -10a Meat content ofthe 'entire water column and the hypolimmon in Lake Norman in 2007...........::................:.................. .......:......... .......................... -42 2-10b Dissolved oxygen content and percent saturation of the entire water column and the hypolimmon of Lake Norman in 2007........ ........................... :.................... 2-42 2-11 Striped bass habitat in Lake Norman in June, July, August, September; and October2007.......................................... :.................................................... 2-43 2-12 Lake Norman lake levels, expressed in meters above mean sea level (msl) for 2002, 2003, 2004, 2005, 2006, and 2007. Lake level data correspond to the water quality sampling dates over this time period .......................................... -45 3-1 Phytoplankton chlorophyll a, densities, biovlumes, and seston weights at locations in Lake Norman, NC in February, May, August, and November 2007 ............................ .........., ................. ......................................................... -24 -2 Lake Norman phytoplankton chlorophyll a seasonal maximum and minimum lake wide means since August 197 compared with the long term seasonal lake wide means and lake wide means for 2007..................................... 3-25 3-3 Phytoplankton mean chlorophyll a concentrations by location for samples collected in Lake Norman, NC, from February and May 1988—2007..................... -26 -4 Phytoplankton mean chlorophyll a concentrations by location for samples collected in Lake Norman, NC, from August and November 1987 — 2007.............. 3-27 xii LIST OF 'Continued! Figure Title Page -5 Class composition (mean density and biovolume) of phytoplankton. from euphotic zone samples collected at Location 2.0 in Lake Norman, NC, during2007......... .................. ........................................................:................. 3-28 3-6 Class composition (mean density and biovolume) of phytoplankton from euphotic zone samples collected at Location 5.0 in Lake Norman, NC during2007 ........ ...................................:..................:........ .......................... -2 3-7 Class composition can density and biovolume) of phytoplankton from euphotic zone samples collected at Location 9.5 in Lake Norman, NC during2007..................................................................................................... 3-30 3-8 Class composition (mean density and biovolume) of phytoplankton from -euphotic zone samples collected at Location 11.0 in Lake Norman, NC during2007................................ .................................................................... ......... 3-31 3-9 Class composition (meandensity and biovolume) of phytoplankton from euphotic zone samples collected at Location 15.9 in Lake Norman, NC during2007. .... . ........ ..................................... ........................... .......................... 3-32 4-1 Total zooplankton density by location for samples collected in Lake Norman in2007..............:..........................................— ..................... ......... ..........,...... -15 4-2 Zooplankton community composition by sample period and location for epilinmetic samples collected in Lake Norman in 2007........................ , ............... 4-16 4-3 Total zooplankton densities by location and year for epilimnetic samples collected in Labe Norman, NC, in the winter periods of 1988 — 2007................... 4-17 4-4 Total zooplankton densities by location and year for epilimnetic samples collected in Lake Norman in the spring periods of 1988-2007......................... ..... 4-18 4-5 Total zooplankton densities by location and year for epilimnetic samples collected to Lake Norman in the summer periods of 1987 — 2007.......:................. -1 4-6 Total zooplankton densities by location and year for epilinmetic samples collected in Lake Norman in the fall periods of 1987 — 2007................................... 4-20 4-7 Annual percent composition of major zooplankton taxonomic groups from mixing zone locations (Locations 2.0 and 5.0 combined) during 1988 - 2007 (Note: Does not include Location 5.0 in the fall of 2002 or winter samples from 20)....................................................:.......,.............................4-21 4-8 Annual percent composition of major zooplanktont onomic groups from background Locations (Locations 9.5, 11.0, and 15.9 combined) during 1988 — 200 (Note: Rocs not include winter samples from 2005)..........................4-22 -9 Copepod densities during each season of each year among epilimnetic samples collected in Lake Norman from 190 — 2007 (mixing zone = mean of Locations 2.0 and 5.0; background = mean of Locations 9.5, 11.0, and 15.9). .... ..................... ....... ............................................. .................... ,................. 4-23 LIST OF FIGURES, Continued F Figure it a 4-10 C;ladoceran densities during each season of each year among epilinmetic samples collected in Lake Norman from 1 — 2007 (mixing zone = mean of Locations 2.0 and 5.0 background = mean of Locations 9.5, 11.0, and 15.9):..........................:..........,.:a;....................................... , .........................4-24 4-11 Rotifer densities during each season of each year among epilinmetic samples collected in Lake Norman from 1990 — 2007 (mixing zone = mean of Locations 2.0 and 5.0, background = mean of Locations 9.5, 11.0, and 15.9)......... 4-5 5-1 Sampling locations and zones associated with fishery assessments in Lake Norman.................. ........................................ .................... ................................... ..... 5-13 5-2 Total a) number and b) biomass of fish collected from electrofishing ten 300-m transacts each, at three areas (MSS, REF, ) in Lake Norman, 1993 —1997 and 1999 — 2007 .......................................................................... -1 -3 Total a) number and b) biomass of spotted bass collected from lectrofishing ten 300-m transects each, at three areas (MSS, REF, ) in Lake Norman, 2001 —200.............. ......................................................... :......., .......................... 5-15 5-4 Size distributions of a) spotted bass and b) largemouth bass collected from electrofishing ten 300-m transts each., at three areas (MSS, REF, S) in LakeNorman, 2007.................................. ............................ .......................... 5-16 -5 Mean relative weights r) for a) spotted bass and b) largemouth bass collected from electrofishing ten 00-m traects each, at three are SS F, S) in Lake Norman, 2007 ............................ ........ ........ ....... ....................... -17 5-6 Total a) number and b) biomass of largemouth bass collected from electrofishing ten 300-m transects each, at three areas (MSS, REF, S) in Lake Norman, 19 —19 7 and 1999 — 2007......... ................................... ............... -1 -7 Total nurnber of young -of -year black bass collected from electrofishing five 300-m transcts each, at three areas (MSS, REF, S) in Lake Norman, 2005 — 200T .............::.....::........:.:...................................:........................... 5-1 5-8 Mean total length and mean relative weight (Wr) for striped bass collected from Lake Norman, December 2007. 'Numbers of fish associated with mean length are inside bars.................................,...............,.............., ....................... 5-1 5-9 Zonal and lake -wide population estimates of pelagic forage fish in Lake Norman, 1997 — 2007 .......................................................................... .......... 5-20 5-10 Size distributions ofthreadfin shad TFS) and alewives (ALE) collected in purse seine surveys of Lake Norman, 2007.........................................................5-20 xiv CHAPTER 1 MCGUIRE NUCLEARSTATION INTRODUCTION The fallowing annual report was prepared for the McGuire Nuclear Station S) National Pollutant Discharge Elimination. System DES) permit # NC0024392 . issued by North Carolina Department of Enviromnent and Natural Resources (NODE ). This report summarizes environmental monitoring of Lake Norman during 2007 OPERATIONAL DATA FOR 2007 Station operational data for 2007 are listed in Table '1-1. Operational maintenancewas performed on Unit`I during the period March — April. The monthly average capacity factors for MNS were 101.9, 101.4, and 101.6% during July, August, and September, respectively. These are the months when conservation of cool water is most critical and compliance with discharge temperatures is most challenging. These three months are also when the thermal limit for MNS increases from a monthly average of 95.0 'F (35.0 °C) to 9.0 °F (37. °C). The average monthly discharge temperature was 97.2 °F (36.2 °C) for July, 98.8 °F (371 °C) for August, and 9.9 °F (36.6 °C) for September 2007, The volume of cool water in Lake Norman was tracked throughout the year to ensure that an adequate volume was available to comply with both the Nuclear Regulatory Commission Technical Specification requirements and the NPDES discharge water temperature limits. MEN CHAPTER 2 WATER CHEMISTRY INTRODUCTION The objectives of the water chemistry portion of the MNS NPDES Maintenance Monitoring Program are to: 1. maintain continuity in the chemical data base of Lake Norman to allow detection of any substantial station -induced and/or natural change in the physicochemical structure ofthelake;and 2. compare, where applicable, these physicochemical data to similar data in other hydropower reservoirs and cooling impoundments in the Southeast. This report focuses primarily on 2006 and 2007. Where appropriate, reference to pre-2006 data will be made by citing reports previously submitted to the N;IENR. METHODS AND MATERLAIS The complete water chemistry monitoring program for 2007, including specific variables, locations, depths, and frequencies is outlined. in Table 2-1. Sampling locations are identified. in Figure 2-1. Measurements oftemperature, dissolved oxygen >), DO saturation, pH and specific conductance were taken, in sitar, at each location with a Hydrolab Data -Sande (Hydrolab 2006) starting at the lake surface (0. ) and continuing at one -meter intervals to lake bottom, Pre- and post -calibration procedures associated with operation of the Hydrolab were strictly followed, and documented in hard -copy fortnat. Hydrolab data were captured and stored electronically, and following data validation, converted to spreadsheet format for archive: Water samples for laboratory analysis were collected with a Kemmerer or Van Dom water bottle at the surface (0. ), and from one meter above bottom, where specified (Table 2-1). Samples not requiring filtration were placed directly in single -use polyethylene terephtalate 2-1 (PET) bottles which were rinsed in the field with lake water just prier to obtaining a sample. Samples requiring acidification, but no filtration, were placed directly in pre -acidified high density polyethylene PE) battles. Samples requiring filtration were first processed in the field by filtering through a 0.45-lun filter (Gelman AquaPrep, 600 Series Capsule) which was rinsed with 500 mL of sample water, and then placed in pre -acidified HDPE bottles (Table - 1). Upon collection, all water samples were immediately stored in the Clark, and on ice, to minimize the possibility of physical, chemical, or microbial transformation. Analytical methods, reporting :limits and sample preservation techniques employed were identical to those used in 2006, and are summarized in Table _2. All laboratory water quality analyses were performed by the Duke Energy analytical laboratory located in Tuntersville, NC. This laboratory is certified to perform analytical assessments for inorganic d organic parameters in North Carolina (North Carolina DWQ Laboratory Certification program, certificate number 248), South Carolina (SouthCarolina Department of Health and Enviromnental Control, certificate number 99005), and New York (New York Department of Health, certificate number 11717). comprehensive Quality Assurance/Quality Control Program (QAIQCP) is fundamental to the collection, reporting, and interpretation of waster duality data, and :most investigators implement some type of QAtQCP to identify, quantify, and document bias and variability in data resulting from the collection, processing, shipping, handling and analysis of samples by field and laboratory personnel. Both the United States Environmental Protection Agency U EPA 1998a, b) and the united States Geological Survey (USGS 1998, 2002) require: that any agency-flinded project have an approved quality assurance program, and that this program incorporate both a field and laboratory component. USGS also requires that any agency funded study that includes laboratory assessments ust also participate in their Standard Reference Program (S ). This program was originally developed. by USGS in the 1960"s and currently involves analysis by participating laboratories of standards (Blind unknowns) created by the agency on a biannual schedule (USGS 2002). The QAIQCP employed for this study followed the recommendation of the USEPA and USGS, and included both a field and laboratory component. Field blanks, i.e. Milli-Q water placed in sample bottles, were subjected to the same sample collection and handling procedures, including filtration; applied to actual samples. Periodically, samples were also split prior to submitting to the laboratory for analysis with the goal of quantifying intra_ sample analytical variability. The Laboratory QAIQCP involved a variety of techniques 2-2 commonly used in analytical chemistry and included reagent blanks, spikes, replicates, and performance samples. To supplement this program, additional performance samples were run on the major inns and nutrients. Beginning in 2005, standards were purchased from the USGS through the agency's SRS program, and submitted biannually to Duke's laboratory t serve as a "double blind" assessment of analytical performance. These standards allowed quantification of the uncertainty of the analytical results against known values that were within the same concentration matrix as actual samples. The goal of this effort is to assemble analytical uncertainty data for chemical analytes which can be incorporated into statistical analyses assessing trends in time or space. Water quality data were subjected to various graphical and statistical techniques in an attempt to describe spatial and temporal trends within the lake, and interrelationships among; constituents. Whenever analytical results were reported to be equal to or less than the method reporting limit, these values were set equal to the reporting limit for statistical purposes. Data were analyzed using two approaches, 'both of which were consistent with earlier Duke Power Company, Duke Power, and Dube Energy studies on the lake (puke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; and Duke Energy 2006, 2007) The first method involved partitioning the reservoir into mixing, background, and discharge zones, consolidating the data into these sub -sets, and making comparisons among zones and years. In this report, the discharge includes only Location 4; the mixing .zone, Locations 1 and 5 the background zone includes Locations 8, 11, and 1 (Figure 2-1). The second approach., applied primarily to the in situ data, emphasized ` a much broader lake -wide' investigation and encompassed the plotting of monthly isotherms and isopleths, and summer striped bass habitat. Several quantitative calculations were also performed on the in situ data.; these included the calculation of the areal hypolimnetic oxygen deficit CAD), maximum whole -water column and hypoli nion oxygen content, maximum whole -water column and hypolimnion heat content, mean epii pion and hypolimnion heating rates over the stratified period; and the Birgean heat budget. Heat content (Kcal/cm), oxygen content (mg/cm), d mean oxygen concentration ( g/L of the reservoir were calculated according to Hutchinson (1957), using the following .equation:: Lt = o-1 71n T4 . Az # dz zO where; 2. Lt reservoir heat all 2) or oxygen ( g1cm) content A. = surface area of reservoir c TO = mean temperature (°C) or oxygen content (mg1L) of layer = area (cm) at depth dz depth interval (c o = surface . = maximum depth Precipitation and air temperature data were obtained from :meteorological monitoring site established. near MNS in 1975. These data are employed` principally by Duke Energy as input variables into meteorological modeling studies as required by the Nuclear Regulatory Commission to address safety issues associated with potential radiological releases into the atmosphere y MNS (Duke Power 2004b). The data also serve to document localized temporal trends in air temperatures and rainfall patterns. Data on lake level and hydroelectric flows were obtained from Duke Energy -Carolinas Fossil/Hydro Generation, which monitors these metrics hourly: ItHRUI , 121001,001i Precipitation and Air Temperature Annual precipitation in the vicinity of MNS in 2007 totaled 78.2 c (Figures 2-2a, b) or 26.8 cm less than observed in 2006 (1.0 cm), and 39.4 cm less than the long-term precipitation average for this area (117.6 cm), based on Charlotte, NC airport data. Annual precipitationtotals for 2007 measured at the MNS site were also the third lowest over the period' 1975 — 2007 with lower values being recorded only in 1981 (64; 4 cm) and 1986 (76.5 cm). Monthly rainfall in 2007 was greatest in March with 10.57 cm, and the least in November with 1.98 cm. Duke Energy reported that air temperatures near the McGuire Nuclear Station in 2007 were generally warmer than the long-term mean, based on monthly average data (Duke Energy 2006). Monthly mean air temperatures in 2007 near the nuclear facility were warmer than both 2006 and the long-term mean for the months of March., August, September and October (Figure 2-). The temporal differences were most pronounced in September and October 2-4 2007 when temperatures averaged 2.8 and 4.1 'C warmer, respectively, than recorded in 2006. Tem erature and Dissolved O&y en Watertemperatures measured in 2007 illustrated similar temporal and spatial trends in the background and mixing zones (Figures 2-3 and -4), as they did in 2006. This similarity in temperature patterns between zones has been a dominant feature of the thermal regime in Lake Norman since MNS began operations in 1983. When between -zone differences in temperatures are observed, they occur predominately during the cooling period, and can b traced to the influence of the thermal discharge at MNS. Additionally, interannual differences in water temperatures in Lake Norman, particularly in surface waters in the background zone, typically parallel differences in air temperatures but with a one -month lag time (Duke Power 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). Water temperatures in 2007 for the months of January, March, and April ranged from 0.1 to 3.8 OC warmer than measured in 2006 whereas 2007 February temperatures were as much as 2.2 °C cooler than observed in 2006 (Figures 2-3 and 2-4). These interannual differences in water temperatures paralleled differences in air temperatures (Figure 2-2c) but because lake sampling is generally performed in the first week of each month, the observed data reflects the cumulative influences of meteorology and hydrology during the previous month, Reduced operations of Unit l in March 2007 (Table 1-1) undoubtedly also contributed to slightly cooler temperatures in April 2007. Minimum water temperatures in 2007 were recorded in early February and ranged from 7.5 °C to 10.8 °C in the background zone and from 8.0 'C to 13.1 °C in the mixing zone.Minimum water temperatures measured in 2007 were within the observed historical range Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991,_ 1992,1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003 2004a, 2005; Duke Energy 2006, 2007). temperaturesStArmw (June, July� and August) water i observed in 2006 in both zones, with one notable exception. Surface water temperatures in the mlxm*g zone in June 2007 were as much as 2.7 IC coolerobserved in 2006, and (Figureappeared to be related primarily to reduced operations of Unit I (Table 1-1) rather than to interannual differences in air temperatures 2- Late -summer, fall and early winter water temperatures (September, October, November, and December) in 2007 were consistently warmer in bath zones than those measured in 2006 and followed the trend exhibited in air temperatures (Figures 2- c, 2-3). The most striking differences were observed in the mixing zone in November when 2007 temperatures were as much as 4.4 °C warmer than measured in 2006. Interannual differences in December' temperature profiles were minimal. Temperatures at the discharge location in 2007 were generally similar to 2006 (Figure 2- a,nd historical data (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996 Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005 Duke Energy 2006, 2007). Temperatures in 2007 were slightly cooler in the spring (March temperatures were taken during a station outage, and warmer in the fall, than observed in 2006, The warmest discharge temperature of 2007 at Location 4 (37.8 °C) occurred in September and was identical to the maximum measured in 2006. Seasonal and spatial patterns of DO in 2007 were reflective of the patterns exhibited for temperature, i.e., generally similar in both the mixing and background zones (Figures 2-6 and -7). As observed with water column temperatures, this similarity in DO patterns between zones has been a dominant feature of the oxygen regime in Lake Norman since MNS began operations in 1983. Winter and spring DO values in 2007 were generally equal to or slightly lower, in berth the background and mixing zones, than measured in 2006, except in February when 2007; DO values ranged from 0.4 to 1.2 mg/L higher than in 2006 (Figures 2-6 and -a7). The interannual differences in DO values measured during this period appear to be related predominantly to the differences in water column temperatures in 2007 versus 2006. Warmer water would be expected to exhibit a lesser oxygen content because of the direct effect of temperature on oxygen solubility, which is an inverse relationship, and indirectly via a restricted convective mixing regime which would limit water column reaeration. Conversely, cooler water column temperatures,' as measured in February 2007, would be expected to exhibit higher oxygen values because of increased oxygen solubility, and an enhanced convective mixing regime which would promote water column reaeration. Summer DO values in 2007variable throughout the watere both backgroundmixing and • of ! to lows of 0.0 to 2.0 mg/L in bottom waters. This pattern is similar to that measured in 2006 - and earlier years (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996 Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005 Duke Energy 2006, 2007). Unlike most Previous years, summer DO profiles in 2007 and 2006 were remarkably similar throughout the water column in both zones, suggesting that those physical and metabolic processes that influence DO within the reservoir were proceeding at about the same rates in 2007 and 2006. All dissolved oxygen values recorded in 2007 during this period were within the historical range. Considerable differences were observed between 2007 and 2006 late summer and fall TAU values in bath the mixing and background zone, especially in the metalimnion and hypolimnion during the months of September, October, and November (Figures 2-6 and. 2-7). These interannual differences in DO levels during the cooling season are common in Catawba River reservoirs and can be explained by the effects of variable weather patterns on water column cooling (heat loss) rates and mixing. Warmer air temperatures delay water column cooling which, in turn, delays the onset of convective mixing of the water column and the resultant reaeration of the metalimnion and hypohmnion. Conversely, cooler air temperatures increase the rate and magnitude of water column heat loss, thereby promoting convective mixing and resulting in higher DO values earlier in the year. The 2007 late summer and autumn 4 data indicate that fall convective reaeration proceeded slower and was less complete throughout the water column than observed in corresponding months in 2006. Consequently, 2007 IBC} levels in either a portion or all of the water were less than observed in 2006. These between -year differences in DO corresponded strongly with the degree of thermal stratification which, as discussed earlier, correlated with interannual differences in air temperatures (Figures : 2-2 2-3, ,and -4). Interannual differences in DO patterns are common not only within the Catawba River Basin, but throughout Southeastern reservoirs and can reflect yearly differences in hydrologic, meteorologic, and li nologic forcing variables (Carle and Hannan 1985; Petts, 1984). The seasonal pattern of DO in 2007'at the discharge location was similar to that measured historically, with the highest values observed during the winter and lowest observed in the summer and early fall (Figure 2-5). fall DO levels in 2007 at location 4.0 were slightly lower than observed in 2006 clue to warmer temperatures. The lowest DO concentration measured at the discharge location in 2007 (5.5 mg/L) occurred in September, and was identical to that measured in August, 2006; it was also 1.4 mg/L higher than the historical minimum, measured in August 2003 (.mg/L). -7 Reservoir -Wide Temnerature and Dissolved Oxvizen The monthly reservoir -wide temperature and DO data for 2007 are presented in Figures 2-8 and 2-9. These data are similar to that observed in previous years and are characteristic of cooling impoundments and hydropower reservoirs in the Southeast (Cole and Hannan 1985; Hannan et al. 1979; Petty 1984). Detailed discussions on the seasonal and spatial dynamics of temperature and dissolved oxygen during both the cooling'and heating periods in Lake Norman have been presented previously (Duke Power Company 1992, 1993, 1994, 1995, 1996). The seasonal heat content of both the entire water column and the hypolimnion for Lake Norman in 2007 are presented in Figure 2-10a; additional information on the thermal regime in the reservoir for the years 2006 and 2007 is presented in Table 2-3. Annual minimum heat content for the entire water column in 2007 (8.88 Kcal/cm; 8.92 'C) occurred in early February, whereas the maximum heat content (28.79 Kcal/cm�; 28.98 -C) occurred in late August. Heat content of the hypolimnion exhibited a somewhat different temporal trend as that observed for the entire water column. Annual minimum hypolinmetic heat content also occurred in early February and measured 4.77 Kcal/CM2 (7.53 'Q, but the maximum occurred in. early September and measured 1.5.77 Kcal/crn' (25.04 -Q. Heating of both the entire water column and the hypolimnion occurred at approximately a linear rate from minimum to maximum heat content, The can heating rate of the epilimmon equaled 0,110 'C/day and 0,089 'C/day for the hypolimnion; both rates were slightly greater than observed in 2006 (Table 2-3). The 2007 heat content and heating rate data for Lake Norman were generally similar to that observed in previous years (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). The seasonal oxygen content and percent saturation of the whole water column, and the hypolininion, are depicted for 2007 in Figure 2-10b. Additional oxygen data can be found in Table 2-4 which presents the 2006 AHOD for Lake Norman and similar earlier estimates for 18 Tennessee Valley Authority (TVA) reservoirs, Reservoir oxygen content was greatest in mid -winter when DO content measured 10.4 mg/L for the whole water column and 10.3 mg/L for the hypolimnion. Percent saturation values at this time approached 90% for the entire water column and 86% for the hypolimnion. Beginning in early spring, oxygen content began to decline precipitously in both the whole water column and the hypolimnion, and continued to decline linearly until reaching a minimum in late summer. Minimum summer 2-8 volume -weighted DO values for the entire water column measured 3.9 ,g/L (52% saturation), whereas the minimum for the hypolimnion was 0.1 g/L (2.2% saturation). The mean rate of DO decline in the hypolimnion over the stratified period, i.e., the AHOD, was 0039 mg/c a/day (0.061 g/L/day) (Figure 2-10b), and is similar to that measured in 2006 (Duke Energy 2007). Hutchinson (1938, 1957) proposed that the decreaseof DO in the hypolimmon of a aterboy should be related to the productivity of the tropogenic zone. Mortimer (941 adopted a similar perspective and proposed the following criteria for .AHODs associated with various trophic states, oligotrophic < 0.025 mg/cm/day, mesotrophc 0.026 mg/c /day to 0.054 mg/cm2/day, and eutrophic 0.05 g/cm�/day. Employing these limits, Lake Norman should be classified as mesotrophic based on the calculated AHOD value of 0.039 mg/c ; 2/day for 2007. The oxygen -based mesotrophic; classification agrees well with the esotrophic classification based on chlorophyll a levels (Chapter 3). ;The 2007 AHOD value is also <similar to that found in other Southeastern reservoirs of comparable depth, chlorophyll ca status, and Secchi depth. (Table -4), Striped Bass Habitat Suitable pelagic habitat for adult sniped bass, defined as that layer of water with temperatures 26 °C and DO levels > 2.0 xrag/L, was found lake -wide from id September 2006 through early July 2007. Beginning in late June 2007, habitat reduction proceeded rapidly throughout the reservoir both as a result of deepening of the 26 °C isotherm and metalinmetic and hypolimnetic deoxygenation (:Figure -11). Habitat reduction was most severe from mid July' through early September when no suitable habitat was observed in the reservoir. These conditions were similar to those observed in most previous gears except that in 2007 no habitat existed in the upper, riverine segments of the reservoir. Historically, a small, but spatially variable zone of habitat is typically observed near and upstream of the confluence of Lyles Creek with Lake Norman, Habitat measured in the upper reaches of the reservoir appears to be influenced by bath inflow from Lyles Creek and discharges from Lookout Shoals Hydroelectric facility, which generally are somewhat cooler than ambient conditions in Labe Norman. Upon entering Lake Norman, this water mixes with ambient waters and then proceeds as a subsurface underflow as it migrates dow "ver (Ford 1955). An additional refuge was also observed in the metalimnion and hypolimnion near the Cowans Ford dam during this period, but this lasted only until 23 July when dissolved oxygen was 2-9 reduced to < 2.0 lL by microbial demands, thereby eliminating suitable habitat in the lower portion of the reservoir, Summer -time habitat conditions for adult striped bass in 2007 were more severe than 2004 when the lamest striped bass die -off ever was observed in the reservoir (2610 fish). Conditions in 2007 were most recently similar to those measured in 2006 when habitat elimination was observed for a period of about 50 to 60 days. Observed striped bass mortalities in 2007 totaled thirteen fish (Chapter 5). Physicochemical habitat expanded appreciably by mid September, primarily as a result of epilimnion cooling and deepening, and in response to changing meteorological conditions: The temporal and spatial pattern of striped bass habitat expansion and reduction observed in 2007 was generally similar to that previously reported in Labe Norman, and many other Southeastern reservoirs (Coutant 1985; Matthews et al. 1985 Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005 `Duke Energy 2006, 2007). Turbidity and Specific Conductance Surface turbidity values were generally low at the MNS discharge, mixing zone, and id -lake background locations during 2007, ranging from. 0.95 to 5.60 NTU's (Table 2- ). Bottom turbidity values were also low over the 2007 study period, ranging from 1.0 to 8.4 NTU's (Table 2-5). Turbidity values observed in 2007 were within the historical range (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). Specific conductance in Lake Norman in 2007 ranged from 51 to 105 umho%c , and was generally similar to that observed in 2006 (Table 2- ), and historically (fluke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power` 1997,'1998, 1999, 2000, 2001, 2002, 2003, 2004a, 200 Duke Energy 2006, 2007). Specific conductance values in surface and bottom waters in 2007 were similar throughout the year except during the period of intense thermal stratification, i.e., :August and November, when an increase in bottom conductance values was observed at locations within the mixing and background zones. These increases in bottom conductance values appeared to be related primarily to the release of soluble iron and manganese from the lake bottom under anoxic conditions (Table 2-5). This phenomenon is common in both natural lakes and reservoirs that exhibit extensive hypolimnetic oxygen depletion (Hutchinson 1957, Wetzel 1975), and is an annually recurring phenomenon in Lake Norman. 2-10 1111111111111111111! 1111 111111 Fp 1111IIIIIII 11111 lip 11��Iiqiiiili 11111111 11111111 111111111 I• . SIM Maior Cations and Anions The concentrations of major ionic species in the MNS discharge, mixing, and mid -lake background zones are provided in Table 2-5. Lake -wide, the major cations were sodium, calcium, magnesium, and potassium, whereas the major anions were bicarbonate, sulfate, and chloride. The overall ionic composition of Lake Norman during 2007 was generally similar to that reported for 2006 (Table 2-5) and previously (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). Nutrients Nutrient concentrations in the discharge, mixing, and mid lake background zones of Lake Norman for 2006 and 2007 are provided in Table 2-5. Overall, nutrient concentrations in 2007 were well within historical ranges (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). Nitrogen and phosphorus levels in 2007 were low and generally similar to those measured in 2006 (Duke Energy 2006.)Historic total phosphorus (TP) and ortho-phosphorus (OP) concentrations were typically measured at or below the analytical reporting limits (ARL) for these constituents, i.e., 5 Ag/L. For total phosphorus, all 44 samples analyzed in 2007 exceeded the ARL, but most measurements (40 of 44) were :5 1.0 g/L. The maximum TP value reported in 2007 was 114 ltg/L and was observed at the bottom at Location 2.0. Similarly, almost all measurements of OP (43 of 44) were recorded as :5 5 gg/L, the ]one exception being a value of 13 gg/L reported at the bottom 2-11 depth at Location 2.0. Nutrients in 2007 were generally somewhat higher uplake than do lake, but the differences were slight and not statistically significant t (p < 0.05). Spatial variability in various chemical constituents, especially nutrient concentrations, is common in long, ' deep reservoirs (Soballe et al. 1992). Nitrite -nitrate and ammonia nitrogen concentrations were low at all locations sampled in 2007 (Table 2-5), and also were generally similar to 2006 and historical values (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a; 2005 Duke Enemy 2006, 2007). Metals Metal concentrations in the discharge, mixing, and inid lake background zones of Labe Norman for 2007 were similar to those measured in 2006 (Table 2-5) and. historically (Duke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996; Duke Power 1997,1998 1999 2000, 2001, 2002 2003 200 a, 2005; Duke Energy 2006, 2007). Iron concentrations in surface and bottom waterswere; generally low (!� 0.4 g/L) during 2007, the lone exceptions being a 0.82-mg/L value measured in the bottom waters at Location 2.0 in November, and a 1.26-mg/L value measured at the bottom depth at Location 5.0 in August. This latter value is the only instance in 2007 that an iron measurement exceeded the North. Carolina water quality action level for iron (1.0 g/L; NCDENR 2004). Similarly, manganese concentrations in the surface and bottom waters were generally low ( 100 µ /L) in 2007, except during the summer and fall when bottom waters were anoxic (Table 2-5). Manganese concentrations in the bottom waters rose above the State water quality action level for this constituent (200 gg/L; NCDENR 2004) at various locations throughout the lake in summer and fall of 2007, and were characteristic of historical conditions (.nuke Power Company 1985, 1987, 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, '1996 Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006, 2007). This phenomenon, i.e., the release of manganese (and iron) from bottom sediments in response to low redox conditions (low oxygen levels), is common in stratified. waterbodies (Stumm and Morgan 1970, Wetzel 1975). Concentrations of other metals in 2007 were typically low, and often below the analytical reporting limit for the specific constituent (Table 2- ). These findings are similar to those observed for earlier years (Duke Power Company 1985, 1987 1988, 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996 Duke Power 1997, 1998, 1999, 2000, 2001, 2002, 2003, 2004a 2-1 2005; Duke Energy 2006, 2007). All values for cadmium and lead were reported as either equal to or below the ARL with the lone exception being a lead value of 3.4 gg/L measured at the bottom depth at Location 2.0 in February. Zinc values were consistently above the ARL and ranged from < 1.0 jig/L to 24.9 jig/L; this maximum was measured at the bottom depth at Location 2.0 in February. All copper concentrations, measured as total recoverable copper, were less than 4 ptg/L, and over half (24 of 44) of the values were less than the ARL. The maximum copper concentration recorded in 2007 (3.13 ptg/L) was measured in the surface waters (0.3 m) at Location 11.0 in May. All values reported for cadmium, lead, zinc, and copper in 2007 were below the State action level for each of these metals (NCDENR 2004). FUTURE STUDIES No changes are planned for the water chemistry portion of the Lake Norman Maintenance - Monitoring Program. SUMMARY Annual precipitation in the vicinity of MNS in 2007 totaled 78.2 cm and was the third lowest measurement reported over the period 1975 — 2007, with lower values being recorded only in 1981 (64.4 cm) and 1986 (76.5 cm). Air temperatures near the McGuire Nuclear Station in 2007 were warmer than both 2006 and the long-term mean for the months of March, August, September and October. The temporal differences were most pronounced in September and October 2007 when temperatures averaged 2.8 and 4.1 'C warmer, respectively, than recorded in 2006. Temporal and spatial trends in water temperature and DO in 2007 were similar to those observed historically, and all data were within the range of previously measured values. Water temperatures in 2007 for the months of January, March, and April ranged from 0.1 to 3.8 OC warmer than measured in 2006 in both the mixing and background zones, whereas 2007 February temperatures were as much as 2.2 T cooler than observed in 2006. These interammal differences in water temperatures paralleled differences exhibited in monthly air temperature data but with about a one month lag. Reduced operations of Unit 1 at MNS in 2-13 Marchand April 2007 also undoubtedly contributed to these interannual differences during the winter and early spring. Summer (June, July, and August) water temperatures in 2007 were generally similar to those observed in 2006 in both zones, with one notable exception. Surface water temperatures in the miring zone in June 2007 were up to 2.7 °C cooler than observed in 2006, and appeared to be related primarily to reduced operations of Unit l rather than to interannual differences in air temperature. Late -summer, fall, and early winter water temperatures (September, October, November, and December) in 2007 were consistently warmer in both zones than those measured in 2006, and followed the trend exhibited inair temperatures, The most striking differences were observed in the mixing zone in November when 2007 temperatures were as much as 4.4 °C wanner than measured in 2006. Temperatures at the discharge location in 2007 were generally similar to 200 (Figure -5) and historical data. Temperatures in 2007 were slightly cooler; in the spring (March temperatures were taken during a station outage), and warmer in the fall than observed in 2006. The warmest discharge temperature of 2007 at Location 4 (37. °C) occurred in September and was identical to the maximum measured in 2006. Seasonal and spatial patterns of DO in 2007 were reflective of the patterns exhibited for temperature, i.e., generally similar in both the mixing and background zones. minter and spring DO values in 2007 were generally equal to or slightly lower, in both the background and mixing zones, than measured in 2006, except in February when 2007 DC values ranged from 0.4 to 1.2 g/L higher than in 2006. The interannual differences in D4 values' measured during this period appeared to be related predominantly to the differences in water column temperatures in 2007 versus 2006. Summer DU values in 2007 were highly variable throughout the water column in both the mixing and background zones ranging from highs of 6.0 to 8.0 g/L in surface waters to laws of 0.0 to 2.0 mg/L in bottom waters. This pattern is similar to that measured in 2006 and earlier years. Unlike most previous years, summer DO profiles in 2007 and 2006 were remarkably similar throughout the water column in both zones, suggesting that those physical and metabolic processes that influence D4 within the reservoir were proceeding at about the same rates in 2007 and 2006. All dissolved oxygen values recorded in 2007 during this period were within the historical range. Considerable differences were observed between 2007 and 2006 late summer and fall DO values in bath the mixing and background zone, especially in the metal "on and 2-14 hypolimnion during the months of September, October, and November. The 2007 late summer and autumn DO data indicated that fall convective reaeration proceeded slower and was less complete throughout the water column than observed in the corresponding months in 2006. Consequently, 2007 DO levels in either a portion or all of the water column were less than observed ed in 2006, These between -year differences in DO corresponded strongly with the degree of thermal stratification and interannual differences in air temperatures. e seasonal pattern of Ua in 2007 at the discharge location was similar to that measured historically, with the highest values observed during the winter and lowest observed in the summer and early fall. Fall DO levels in 2007 at location 4.0 were slightly lower than observed in 2006 due to warmer temperatures. The lowest DO concentration measured at the discharge location in 2007 (5.5 mg/,) occurred in September, and was identical to that measured in August, 2006; it was , also 1.4 /L higher than the historical minimum, measured in August 200 (.1 g/L), Reservoir -wide isotherm and isopleth information for 2007, coupled with heat content and hypolimnetic oxygen data, illustrated. that Lake Norman exhibited thermal and oxygen dynamics characteristic of historical conditions and similar to other Southeastern reservoirs f comparable size, depth., flow conditions, and tophic status. Suitable pelagic habitat for adult striped;bass, defined as that layer of water with temperatures :!� 26 OC and DO levels 2.0 g/L, was found lake -wide from mid September 2006 through early July 2007. Beginning in late June 2007, habitat reduction proceeded rapidly throughout the reservoir both as a result of deepening of the 26 IC isotherm and metalinmetic and hypolimnetic deoxygenatin. Habitat reduction was most severe from id July through early September when no suitable habitat was observed in the reservoir. Summer 2007 habitat conditions were most recently similar to those measured in 2006 when habitat elimination was observed for a period of about 50 to 60 days.. Observed striped bass mortalities in 207 totaled thirteen fish. All chemical parameters measured in 2007 were similar to 2006, and within the concentration ranges previously reported for the lake during both preoperational and operational years o S. Specific conductance values, and all concentrations of cation and anion species measured, were low. Nutrient concentrations were also low with most values reported close to or below the analytical reporting limit for that test. Concentrations of metals in 2007 were low, and often below the analytical reporting limits. All values reported for cadmium, lead, 2-15 zinc, and copper in 2007 were below the State water quality standard or action level for each of these metals. Iron concentrations in surface and bottom waters were generally low (:� 0.40 mg/L) during, 2007 the only exceptions being a 0.2-g/L value measured in the bottom waters at Location 2.0 in November, and a 1.26- g/L value measured at the bottom depth at Location .0 in August. This latter value is the only instance in 2007 that an iron measurement exceeded the North Carolina water quality action level for iron 1.0 mg/L). Similarly, manganese concentrations were generally low (!� 100 g/L) in 2007, except during the summer and :fall when bottom waters were anoxic. Manganese concentrations in the bottom watersrose above the State water quality standard for this constituent (200 gg/L) at various locations throughout the lake in summer and fall of 2007, and were characteristic of historical conditions. This phenomenon, i.e., the release of manganese (and iron) from bottom sediments in response to low redox "conditions (low oxygen levels), is co non in stratified watertodies: -16 Table 2-2. Analytical methods and reporting limits employed in the McGuire Nuclear Station NPDES Maintenance Monitoring Program for Lake Norman. References: USEPA 1983, and APHA 1995 a- Reporting limit for May samples 00 Table -3. Heat content calculations for the thermal regime in Lake Norman for 2006 and 2007. 200E 2007 Maximum Areal Heat Content (°cal/c 2) 28,80 28,787 Minimum .Areal Feat Content (g°calk ) 10,84E 8,882 Birgean Heat Budget (g°call cm) 18,034 19,905 Epili ion (above 11.5 m) Heating Rate ('C /day) 0.091 0.10 l-Fypoli ion (below 11. ) Heating Rate (" C /clay) 0.068 0.089 2- 19 Table 2- . A comparison of areal hypoli r etic oxygen deficits (AHO ), summer chlorophyll a (Chl a), Secchi depth; and mean depth of Lake Norman and 1 TVA reservoirs. CHI Summer Chl a Secchi Depth Mean Depth Reservoir ( g/c 2/day) (ug) (m) ( ) Lake Norman 0.039 4.5 L7 10.3 TVAa 1lainste Kentucky 0.012 9.1 1.0 5.0 Pickwick 0.010 3.9 0.9 6.5 Wilson 0.028 5.91.4 12.3 Wheelee 0.012 4.45.3 Guntersville 0.007 4.8 1 A 5.3 Nickalak 0.016 2.4 1.1 6.8 Chickamauga 0.008 3.0 1.1 5.0 Watts Bar 0.012 6.2 1.0 7.3 Fort London 0.023 5.9 0.9 7.3 Tributary Chatuge 0.041 5.5 2.7 9.5 Cherokee 0.07 10.9 1.7 13.9 Douglas 0.046 6.3 1.6 10. 7 Fontana 0.113 4.1 2.6 32.8 Hiwassee 0.061 5.0 2.4 20.2 Norris 0.058 2.1 3.9 16. South Holston 0.070 6.5 16 23.4 Ti s Ford 0.059 6.1 2 A 14.9 Watauga 0.066 2.9 2.7 24.5 a Data from Higgins et al. (1980), and Higgins and Kim (19 1 2-20 Table 2-5. Quarterly surface (0.3 m) and bottom (bottom minus 1 ru) water chemistry for the McGuire Nuclear Station discharge, mixing zone, and background locations on Lake Norman during 2006 and 2007. Values less than detection were assumed to be equal to the detection limit for calculating a mean. Mixing Zone Mixing Zone MNS Discharge Mixing Zone Background Background LOCATION: 1.0 2 4,0 5Z 8.0 11'0 DEPTH.' Surface Bottom Surface Bottom Surface Surface Bottom Surface Bottom Surface Bottom PARAMETERS YEAR: 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 Turbidity INTL) Feb NA 2.3 NA 230 NA 230 NA 160 NA 210 NA 2,40 NA 2.90 1.6 220 Z3 3.50 22 5,60 U 5,70 May 110 2.0 0 ' 98 1.30 1.2 1.30 1 1 - 50 12 1.50 1,3 1 - 00 1,2 110 1.4 (195 1 .1 1,60 I'l 120 1:5 1.60 Aug 10.00 U 20.00 1,00 9S 1 Ad is too 22 1,50 9.8 1 AD 9 8,40 1A 1.30 11 1 Ari 1.9 1,40 1.8 1.60 Nov 2.00 2.6 3.3 2.70 210 4,30 170 2.70 80 g_ 122 430 __m --Ln --T9-0 6SO 100 -2A &70 -211-0 -21-00 3,40 Annual Mean 437 2,05 __240 8.09 10 _.L40 4,47 _2.0 7,23 2,6 a97 _2_ 2.1 _A& 5.47 1.9 5e3 4,2 1 B8 IS - 2,23 2A 3.28 31 Specific Conductance (umho/crin) Feb 53.0 53A 52.9 52.6 513 5318 531 53A 53.7 543 534 54.3 516 512 52.6 53.8 631 53S 531 51-5 53.2 51 A May 53.9 55,8 53,5 552 619 55,7 532 55 54A 56.3 54,2 56 53A 54.7 1 512 5519 533 55.1 53.5 %6 53A 55.2 Aug 57.7 611 616 73.9 58,2 60.9 67A 712 58.4 61 582 61 6519 68.9 58,0 61.1 59.9 65.6 582 643 64A 68 Nov 573 64A 67A 104,7 57.8 64,9 573 67.2 5&5 663 S&O 65.3 5&3 66.3 58a 64Z 57A 64A 56B 69A 56.7 69,2 Annual Mean 5!L6 58A 563 71,6 55A 58A 57,9 61.6 56.3 59A 56,0 592 STS 60.5 55.5 58A 56,0 591 55A 60A 56a 61.0 pH (units) Feb 7.2 7.3 7,0 61 73 73 7,0 7A 73 7,3 7A 7A 7.1 T5 7,1 7A 6A 7.3 TO 7,3 6,8 71 May 7A 7.2 CS 63 7.4 7.5 6.6 6.5 73 7.4 7.4 7A TO 6.5 T8 I'S 6.7 6.5 7.5 7.5 6.5 6.6 Aug 7.6 7S 6.2 &0 7.6 7.4 6,4 6,0 7A T2 7.3 7,5 6A 6:5 77 8,2 6,2 6,5 7,9 7.9 S3 6.5 Nov 7,3 7A 7,0 71 7,3 7:5 7.2 7.3 7;5 7A 7,5 7A 7A 7A 7,5 7.6 7.5 T6 73 7.6 7.3 7.4 Annual Mean 7,37 6A6 6S6 6.65 7,37 7.43 6,80 S73 T29 7.10 7,39 7,43 6,96 6.98 T52 7,70 6,79 6.98 T42 7158 6,73 gait Alkalinity (mg CaCO31L) Feb 12,5 115 120 13,5 11.5 14,0 12;5 115 12.5 13,5 12.0 14.0 12.0 13.5 12,6 14,0 12.5 14o 12o 110 12,5 13.0 May 12.0 13,5 110 14.0 12,5 13.5 12,5 115 110 13,5 115 14.0 42.5 13.5 12o 136 12.5 13.5 12.5 115 115 13'5 Aug 14,0 15,0 15,5 15.5 14,0 1510 16.0 16,0 14,0 15;0 14,0 15.0 %5 22,5 %0 15.0 15.5 19.0 14:5 15.5 176 lao Nov 14,5 %0 15.0 17.0 15.0 1610 15.0 16,5 15'0 *0 13.0 %5 14.5 15.5 15,0 I1.5 14.5 lao 14:5 1&0 Annual Mean 133 14.5 13.6 15.0 133 14,6 Ise -20-0 15.8 -iii 13S 14,6 13.4114.8 14.3 16,5 133 14,5 13S 145 13A 14�5 143 15A Chloride (mg/L) Feb 4,5 4A 4.6 4.7 4.4 4.6 4A 4,6 4.5 4S 4.3 4.7 4,5 4,5 4A 4,7 4,6 4.7 4:5 4,5 41 4,6 May 4.8 5,1 4.8 4,7 4Y 4.9 4.9 4.8 4.8 5,0 4A 4,8 4:8 4,8 4S 51 4.7 5.1 4A 5.3 4A 53 Aug 4S 5A 4A 4S 4:6 SA 4A 4.7 4,6 6.4 4:5 5,2 4A 5.0 4,5 53 4,9 4,9 4J 5.9 42 C6 Nov 5.0 6a 5.0 1� 6.5 4�9 6. 65 5o -47 6,7 -54 5a -4,7 6,5 510 -4,7 6.7 -5,5 5A -48 6S -53 5A -48 716 5.1 -4,7 T6 Annual Mean 43 &4 4.7 52 ---ii 43 - 5A 4.6 _13 51 41 51 5.2 Sa =5 Sulfate (mg/L) Feb 43 3.8 43 3A 4.4 3,6 4,2 3,9 4,3 16 43 17 51 3.7 4,3 3.7 4.2 17 4A 3S 4.2 3S May 4J 4,2 4.7 4.2 4,7 4.2 4,7 41 41 4,2 4,7 4.2 41 4,2 4,7 42 4,6 42 4A 4A 4A 41 Aug 42 C8 4,0 4.3 4,2 4,5 4,0 4.3 4,2 4.6 4,2 4,6 3A 3a 4,2 4.5 3,7 42 4,1 4.5 3.9 4A Nov 41 4.5 4.0 4A 4,2 4S 42 19 41 4,5 41 4.6. 19 5 0 --.4-2- -.jL _Ll- --M CO C8 4,0 4,8 Annual Mean 4,3 43 43 41 43 42 43 41 43 42 43 43 4a , 4A 4.4 4,3 4.1 5.4 4.2 4,3 V 4,2 Calcium (mg/L) Feb 2,96 3.23 2a6 3,21 2,95 123 Z94 3.26 2,97 3.19 2.96 318 2,97 122 2,97 3,19 102 3,18 3,07 3S2 3.15 141 Map 102 3,44 3.05 3,43 3.02 3,50 3.04 3A4 3,01 3A7 100 3,42 3.02 140 3,00 149 3,09 3A0 3,08 3,92 117 183 Aug 108 176 3.43 3.90 3,10 3.78 151 193 112 3,77 3.11 3.78 3,64 4,26 111 342 149 197 3,18 4.14 154 COS Nov 3.17 4,10 3.11 4,13 3,17 4,09 3,17 4,23 116 4,11 3.16 4,11 3.14 4.07 3,15 4.11 3,08 4,09 3,02 4.44 3.06 4,44 Annual Mean 3,06 163 314 3,67 3106 3,65 3,17 3.72 3,07 164 3,06 3.62 3.19 3.74 3,06 3,66 3,17 171 109 4,01 323 193 Magnesium (mg/L) Feb 1 .51 1.66 1,51 1 AS 1.51 1.65 1,49 1,64 1.52 1 A4 1.52 1,65 1,52 1.65 1,62 1.65 1,51 1,66 ISI 1.63 1,50 1 el May 1 AS 1 ,64 1 AS 1.64 1,47 1.64 1,48 1,64 1,48 IA5 1 if 1.65 1.48 1A3 1A7 1 A7 1.48 1.67 IV 1,74 1 Ag 114 Aug 1.58 1,89 1 :61 1 Al 1159 1,90 1 64 1,84 1.59 1,89 1.58 1.89 1 S9 last 1 8 1,89 1.64 1 A71 1,59 2.06 1.65 1,88 Nov 1 JI 2,06 1,70 205 1,71 2.05 IJI 2,06 1,70 2.06 -t;J1 1 71 2.06 110 -1 2.05 111 2,08 _1,71 eti 169 2,22 1,71 2,22 Annual Mean 1.57 1,81 1,58 1 1� 1�57 1,81 1,38 1,80 1-57 1-57 1-81 rn 1,82 1.57 IA2 1�59 2 1: 8j 157 191 159 186 NS Not Sampled: NA= Not Applicable; FQC = Failed Quality Control r'a c<t cv 104uOD A9aleuo poprj = 06A 'algpo!iddV joM =VN :pal g joX SSvt 0'z 07 07 a 0"z o'z 07 o'z 0'z o z o 6 z vz O z o'z 0 z 07 of 6'z o'z o Z 07ueen ienuuy 0•Z.. 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LOOZ 900Z :N A SLi3l3V Vd w01j09 wePnS w01108 eorpnS W0409 aaeting' 808pns WOU08 8aupng w0110S 80e}fnS N1d3Q Olt 0'9 0.0 :. 011 z o'L :NOIIVOOI punotaryae6 PunaB�neS suoZ 6utxiVq 61e40siQ SNV4 auOZ Ouixijry auo tiuixlij Table - (Continued) Mixing Zone Mixing Zone MINIS Discharge Mixing Zone Background Background LOCATION: 1.0 2.0 4.0 &0 &0 11.0 DEPTH: Surface Bottom Surface Bottom Surface" Surface Bottom Surface Bottom Surface Bottom PARAMETERS YEAR: 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 2006 2007 Zinc (ug/L) Feb 1.0 1.4 1.0 1.6 1.0 to 1.0 24.9 1 A 1.3 1:0 1 A 1.0 5A 1.0 2.8 4.1 2.5 1.1 2.4 1:1 3.6 May 1.0 6:3 1.0 10.2 1.0 10:9 to 52 1.0 6:9 1:0 4.7 1.0 6.5 1.0 4,6 1.0 4A 5.6 6.5 1.0 S 0 Aug 1.8 2.1 1.1 2.6 1.4 1.4 1.0 1.9 1.0 1:0 1.0 13 1.0 ' 2.2 1.2 2:8 1.0 2.1 2.7 1.6 1.0 1.8 Nov 4.7 1.7 1.1 1:6 2.0 1.3 1.0 1 A 1.0 1:7 1:0 1.0 1.0 2.4 , . 1.0 2.4 1:0 1.8 1.0 t8 1.2 1.8 Annual Mean 2.1 2.9 1,1 40 14 3.7 1.0 8A 1.1 2.7 1:0 2.1 10 4.1 1.0 3.2 1.8 2.7 2.6 3.1 11 3.1 Nitrite -Nitrate (ug1L) Feb 200 160 230 170 210 180 220 190 200 200 200 160 210 170 210 160 240 160 260 290 310 350 May 200 190 290 190 210 190 280 200 210 190 210 190 210 190 190 200 290 210 190 230 290 240 Aug 50 70 530 440 60 180 240 450 110 150 90 170 120 450 50 190 220 330 40 210 200 350 Nov 150 130 300 570 90 120 140 80 180 100 120 130 110 120 130 130 140 230 160 260 390 290 Annual Mean 150.0 137,5 337,5 342.5 142.5 167.5 220.0 230.0 175:0 160.0 155.0 162:5 162:5 232.5 145.0 170.0 222.5 232.5 162.5 247.5 297.5 307.5 Ammonia (ug/L) Feb 120 42 140 40 84 37 110 54 87 69 86 72 120 57' 110 38 98 50 85 46 100 58 May 35 20 40 24 30 23 38 20 35 29 31 20 28 25 24 29 45 20 35 21 56 20 Aug 90 20 150 39 80 25 170 68 92 31 90 29 200 180 84 28 120 98 100 43 140 110 Nov 65 92 65 120 65 93 63 220 63 100 69 94 69 110 60 79 56 78 56 60 73 85 Annual Mean 77.5 43.5 98.8 55.8 64.8 44.5 95.3 90.5 69:3 57.3 89.0 5, 104,3 93,0 69.5 43.5 7. 61.5 69,0 42.5 92.3 683 Total Phosphorous (ug1L) Feb 7 9 9 8 8 10- 9 114 8 9 8 8 10 11 9 9 9 9 10 17 14 14 May 8 7 8 6 8 7 7 7 7 7 7 7 7 7 7 6 8 9 7 7 9 7 Aug 7 7 8 10 7 8 10 7 7 7 7 7 8 7- 7 8 7 7 8 8 8 8 Nov 8 7 11 7 9 7 9 8 9 8 8 7 9 8 8 7 12 9 10 "9 15 9 Annual Mean 7.5 7,5 90 7.8 8.0 8.0 8.8 34028 7.8 7.5 7.3 8.5 8.3 7.8 7.5 9,0 8.5 8.8 10:3 11.5 9.5 Orthophosphate (ug/L) Feb 5 5 5 5 5 5 5 13 5 5 5 5 5 5 5 5 5 5 5 5 5 5 May 5 5 5 5 5 5 5 5 9 5 5 5 5 5 5 5 5 5 5 5 6 5 Aug 5 5 5 5= 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 Nov 5 5 5 5 5 5 13 5 5 5 5 5 6 5 5 5 5 5 5 5 ®5 5 Annual Mean &0 5,0 5.0 5.0 &0 5.0 7.0 7 6.0 5 5.0 5 53 5 5.0 5 &0 5 5:0 &0 5.3 5 Silicon (mglL) Feb 4,6 4.2 4.6 3.9 4.6 4.0 - 4.6 4.0 4.5 4.0 4.5 CO 4:6 4A 4.5 4.0 4,6 3.7 4A 4,8 4.6 4.7 May 4.5 42 4.8 4.7 4.5 4.2 4.8 4.6 4.5 4,3 4A 4.0 4.5 4.0 4A 3.9 4.9 3.7 4.2 3.6 4:8 3.6 Aug 4,0 3.8 5.5 &0 4.1 33 5.5 5.2 4.1 3:7 4.1 3.7 5A 5A 4.1 3.8 5.4 5A 4.1 3.9 5.3 5.1 Nov 4:6 4.6 4A 4.9 4.4 4.7 4A 5.0 4A 4:7 -4.21 4.4 4.7 4.5 47 4A 4,6 4.3 4.6 4.6 �5.1 4.5 5.1 Annual Mean 4.4 4.2 4.8 4.6 4,4 4.2 4.8 4.7 4A 4A 4.1 4.8 4.6 4.4 4,0 4.8 4.3 4.3 4.4 4.8 4.6 NS - Not S leda NA=Not Ap liable; FQC = Failed Quality Control 80 72 69 62 15.. MSS 15. N 14.E1 n IWa1y .C} b 0 4 11. . ta .5 INNS 4.0 Figure -1., `Water quality sampling location (numbered) for Lake N r pan. Approximate locations of Marshall Stearn Station, and McGuire Nuclear Station are also _2 :� + #� f i i � «� t 1� t i ! it 01. r M R � � x � �.: ♦ � ♦ � M.. M � R �.. i� V � d 2CCL 24 _ 22 a 20 - - 8.__ 1 1 —— v-_ 0 d Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1 -A__ — 7797 Lang -ter very e 2O 6 � . • 2Ci07 I Figure - c. Mean monthly air temperatures recorded at McGuire Nuclear Station beginning in 1989. Data were complied from tQ average daily temperatures which, in turn, were created from hourly measurements. L-Z C� w Depth (m) Depth (m} o w o (D CD CD Ct3 v, 0 m ZA Er ns ca w cn CP Ma Depth (m) Depth "(m) c� 4 0 0 »isK «kxxwk.............,..,.... -- w _ w 0 Depth (m) Depth (m) CL 8 1., 11 w, w, � N —Z o � o N b C"4 j Id 0 0 a c? 0 8-'z r� Qepth (m) Depth (m) Depth (m) Depth (m) 0 u, 0 m w Depth (m) Depth (m) rya 8 N 8 cn. c, P9 e mm c� C? Depth (m) Depth (m) lzi IS 0 cn 0 w" a o is cn +^4 Depth (m) Depth (m) ZA 8 ZA 84 CG x o � Q`G Depth (m) Depth (m) tD 1 N G7 N C> i -Z cctk m Depth (m) Depth (m) Q tl U Depth (m) Depth (m) r 8 6, 8 o �A 8 Depth (m) Depth (m) 0 ruxxwxrtreaauwxrasexx..aerrt.KKxr... p C o ..e _o w 40 30 f 0 U ° 25 C 2 CL — 1 5 -r------ -- . ------ Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 12 - 11 10 CD E 8 7 6 0 a 5 4 0 _ua C� 1 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure 2-5. Monthly surface (0.3 ) temperature and dissolved oxygen data at the discharge location (Location 4.0) in 2006 ( ) and 2007 (0). 2-31 JAN FEB MAR Dissolved Oxygen (mg1L) Dissolved Oxygen (mgtL) Dissolved Oxygen'(mg[L) 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 -2 4 6 8 10 12 0 0 x 0 z 5 5 5 x * x * 10 10 , 10 S 15 15 E 15 020 .20 x 20 x 25 25 25 x 30 30 z 30 35 35 . 35 0 5 10 E15 .c 20 n 25 30 35 APR MAY JUN Dissolved Oxygen (moo.) Dissolved Oxygen (mgiL) Dissolved Oxygen (mgtL) 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 2 4 6 8 10 12 0 * 5 * ,. 10 1 z X 15 k1 o20 02 ca cs 25 2 X * 30 * ,r Figure 2-6. Monthly mean dissolved oxygen profiles for the McGuire Nuclear Station background zone in 2006 (x and 2007 s +► . -Z ITI c� ca Depth (m) Depth (m) ob4 8 N 8 o N 8 N 8 C.7 CD =, 0 0 cr c� 0 Depth (m) Depth (m) 5c x m Depth (m) Depth (m) x k x. N 'bc" ra ca .a Depth (m) Depth (m) 83 8 c 8 cn c 8 a% o cn o 0 N Q� C tD d Q Depth (m) Depth (m) ._ —81 Ci C t`p C �t Depth (m) Depth (m) N tU N C> C> X x C ram. S-Z ITI 1 Depth (m) Depth (m) r) 0 r m. ,r Depth (m) Depth (m),. N.'' rya e^'n o cn 8 to ct s, o c xxuxxxsixxxxx MExwxx.........xxx 0 0 Depth (m) Depth (m) o u�i o rn o cn.... c} c#""n ' c14''n ZA cx v+ o ox •. CsMxx# ,Q m 240- 240- Sampling Locations Sampling Locations 236 10 8.0 1110 13.0 15,0 15.9 62.0 69.0 72A We 235: 10 810 11.0 13.0 15'0 15a 62.0 69.0 72.0 80A 230:a*b. 230: AA 22225: 5: 22C4 220: 215; 215� M 21 210: 20205: 20 Temperature (deg C) 20Temperature (deg C) Jan 10, 2007 Feb 12, 2007 19 0 ..... ..... .......... . 5 40 -45— ' ZO .... 5 10 15 20 26 30 35 4!0 45 so Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) 240- 240-- — ----- — Sampling Locations Sampling Locations 235 1,0 8,0 IIA 13.0 16.0 15.91 62.0 69,0 72.0 soe 235 1.0 810 Me 1310 16'0 15's 62,0 69.0 72.0 80,0 230 230 --2W :21_20J 1e V �17— I6— rs 225: 225- 17--- 220 220 12\ 21 S: 215: 210- 210 205 205 200 Temperature (deg C) 200 1 Temperature (deg C) Mar 13, 2007 Apr 3,2007 19- 19 �;IW wo- -7-71��-z 5 0 f> 6 Z5 10 1�1 :1 Ott -75 6"0--56 50 56 5' 0 2,5 T 6 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) Figure 2-8. Monthly reservoir -wide temperature isotherms for Lake Norman in 2007. 24 240 Sampling Locations - ' Sampling Locations 23 1.0 6.0 1110 13.9 Ise 15.9 62.0 69.6 72.0 00.0 235 1.9 &0 41.0 13.0 15.0 1519 62.0 69.0 MO 80.0 23 / 22-�✓' IN. .-1 ,..�9-�9 - 230- "'�.... ``2T•�"/�� +L�' �' 22 79 8 _ _ 225-As r s 220 caa 220- 1 21 21 17" 16, to 21 21 205 205 14 20 ' Temperature (deg C) 200Temperature (deg C) May '10, 2007 Jun 5, 2007 ,19 19 q iq 1.5 2q 25. 3q ....35 40 45 5q 55 :q 5 10 15 ..20 25 30 35 40 45 5q 55 Distance from Cowans Ford Clam (km) Distance from Cowan$ Ford Dam (km) 240- 240- Sampling Locations. Sampling Locations 23 i:0 &0 i1.0 13:0 160 15.9 '62.0 .solo 72.0 60.0 231.0 8.0 11.0 13.0 15.0 Me 62.6 see 72.6 60.0 23 23 225� 25 2i' 2 26 21 9s� 21 21 21 ^b ". ca 205 20 2qq Temperature (deg G) 20 Temperature (deg ) Jul 2, 2007 Aug 6, 2007 19rt -ter 19 0 5 10 15 20 25 3q 35 1q 45 5q 55 q. 5 1q 15 20 30 35 4q 45 5055 Distance from Cowan. Ford Dam tkn i Distance from Cowan$ Ford Dam Man Figure 2-. (Continued). 2..: 24 Sampling Locations. Sampling Locations 23 1.0 810 11.0 13.0 15:0 15.9 62.0 69.0 72A 66:0 23 1.0 Co 1t.o 13.0 Mo 15.9 62,0 69.0 MO solo 226 22 22 29 E E 21 � 21 210 ..�.. : 21 224 23 lei. 205 20 .. 1g,... Temperature (deg C) 2a 1 f . Temperature (deg C) Sep 4, 2007 Oct 1, 2007 19 19 0 110 15 24.... 25 30 35 40 45.. 50.. 55 0..: 5 1t}.. 15 0 2.5 305 40 45... 50 55 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) 24 24 :Sampling Locations:: Sampling Locations 23 1:0 8.0 11.0 13.0 15.0 15.9 :62.0 69:0 72.0 80.0 23 1:0 8.0 11A 13.0 Mo M9 62A 69.0. 72.9. 60A b 23 � \ �.,,.. wM.cD us 2322-5- 226- 220 e 220 12 ® 21 M 21 20 20 200 Temperature (deg C) 20 Temperature (deg C) Nov 8, 2007 Dec 11,-2007 ,g 19 0 5 10 15 20 25 30 35 40 45 50 5S 0 5 10 15 0 25 3Ci 35 4t) 45 50 56 Distance from Cowans Ford Dam fkml Distance from Cowans Ford Dam (km) Figure - . (Continued). 24 - 24 Sampling Locations Sampling Locations 23 1.0 8.0 11.0 13.0 16.0 15.9 62.0 69:0 :72.0 80.0 23 co 810 Me 13.0 15.0 15:9 62:0 6910. 72.0 80.0 ( 23 it1 23J 22 i0 22 cYw 22 21 21 21 2i 20 <0 20 20 Dissolved Oxygen (mg/L) 200 Dissolved Oxygen (mg/L) Jan 10, 2007 Feb 12, 2007 i9 19 0 5 10 is 20,.... 25 30... 3s 40 45:. 5a. 5s - 0 5 10 15 20 2s 3i4 3S 40 45 50 55 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) 24 0 24 Sampling Locations:. Sampling Locations 23 1:0 8.0 11.0 13.0 1$.0 15.9 62.0 69.0 72.0 80.0 235 1.0 &0 1110 13.0 15.0 16:9 62;0 69.0 Me 80.0 230- 230- --------------------------- .-. 22 ..-. 22 22 22 ..._ - -8" a a 21 21 Ca 21 21 2 2a 0 20 Dissolved Oxygen (mg/L) 20 Dissolved Oxygen (m /L) Mar 13, 2007 Apr , 2007 1 1g 5 1 t1 15 24 25.. 30 35 0 4 0. s5 i 0 15 20 25 30 3s. 40 45s0 55 Distance from Cowans, Ford Dam (kmY - Distance from :Cowans Ford Dam k ) Figure 2- . Monthly reservoir -wide dissolved oxygen isopleths for Lake Norman in 2007. 24 24 Sampling. Locations Sampling Locations 2 1.0 8.0 11A 13A 1&0 15.9 62.0 6910 72.0 80.0 23 1.0 8.0 110 i3.0 ISM 15.0 62.0 Wo 72:0 solo 23 as _ % 23 10-1 22-t�, n 225 r 21 21 � ® 21 03 21 > 205- 200 Dissolved Oxygen (mg1L) 20Dissolved Oxygen (mg/L) May 10, 2007 Jun 5, 207 19 5 10 15' 20 25 30 35 40 45 5t7 55 0 5 10 is 20 25 30 5 40 45 50 s5 Distance from Cowans Ford Dam (km) Distance from Cowans Font Dam (km) 24 24 Sampling Locations:.: Sampling Locations 23 i.o &0 11..0 13.0 15.0 15.9 62.0 69.0 72.0 solo 23 i:o 8:0 110 :18.0 15.0 15.9 52.0 69.0 72.0 Me L-j )i ....,. 225 22 22 22 2 E 0 21 21 (['ii3n 0 21 2(l 20 «. 0- 20 Dissolved "Oxygen (mg/L) 20 Dissolved Oxygen (mg/L) Jul 2, 2007 Aug 6, 2007 ig 1 0 5 i Cl 1 * 20 25 30 35 40 45 60... 55 0 5 10 15 20 2 3t V 35 4ti 45 50 'Ss Distance from Cowans Ford Dam (km). Distance from Cowans Ford Dam (km) Figure -. (Continued). 24 24 Sampling Locations Sampling Locations 236 1;0 810 11.0 13.0 15.0 15.9 62,0 69.0 72.0 60.0 23 10 3.0 11.0 1a.0 : 15.0 15;9 62.0 69:0 "MCI 80.0 23 A 23 7` 6. 220 22 0 � '4 r a € ° 21 - 21 c `� 21 21 � 0�}` S " Iva 20 20 c . Dissolved Oxygen (mg1L) 20 Dissolved Oxygen (mg/L) 200:Sep 4, 2007 �- Oct 1, 2007 19 19 0 5 10 15 20 25 30 35 40 45 50 55 0 10 15........2t7 25 30 35. 40 45 50 55 .Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) 240 24 Sampling Locations Sampling Locations 23 1.0 010 11_0 13.0 15.0 15.9 62.0 69.0 72.0 80.0 235 1.0 60 1110 13.0 15.0 15.9: 62,0 solo 72:0 $0.0 23 23Co a 9 22 22 21 21 $s � 20 m 20 Vp 20 Dissolved Oxygen (mg/L.) 20 Dissolved Oxygen {mg/L.) Nov 8, 2007 Dec 11, 2007 19 19 i 0 15 20: 25 30 35 ii 45 5ta 55 ik 5 10 15 20 25 20 35 40 45 50 55 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) Fi 2-. (Continued). 35 30 25 E c� 0 ,15 10 5 0 50 100 150 200 250 300 350 Julian Date "figure 2-1 Oa: Heat content of the entire water column ) and the hypolimnion (o) in Lake Norman in 2007. 12 100 „� .■®.T 90 10 0 ■ ■ - 70 •* ■. °° ■ ■ ° f ■ 0 50 31 6 . _ 4t CL 1 0 0 1 31 61 91 11 151 11 211 241 21 301 331 361 Julian Date Figure 2-1 O . Dissolved oxygen content (-) and percent saturation (- -) of the entire water col (■) and the hypoli ion (o) of Lake Norman in 2007. -2 24 24 :LAKE NORMAN STRIPED BASS HABITAT LAKE NORMAN STRIPED BASS HABITAT &0 11.0 13.0 15:0. 15.9 62 0 69a1 72.0 &0,6 23 1.0: 8.0 11.0 13.0 15.0 15.9 62.0. 69.0 72.0 80.0 2 .. 23 22 22 22 26 deg C E >. 26 deg C 21 2 rig/L 21 2 mg/L. ....... 21 21 20 ,, Jun 18, 2007 20 , r .�.•"Jul 2, 2007 20, 20:., 1s 10 95...... 20 25 30 35 40 45 50 55 19 10 15 20 25 34 35 40 +&5 50 55 Distance from Cowans Ford Dam (km) " Distance from Cowans Ford Dam (km) 24 24 LAKE NORMAN STRIPED BASS HABITAT LAKE NORMAN STRIPED BASS. HABITAT 2 1'0 &0 11.0 1.3.a 15.0 15.9 62.0 69:0 72.0 80.0 23 S.a. 8,0 110 13c 15.0 15.9 62.0 69.0 72.0 80.0 23 23 22 22 22 22 26 deg C 9 26 deg C 21 2 mg/L 21 2 mg/L 21 ® 21 " 20 Jul 9, 2007 20 } Jul 1, 2007 2 fa 10 15 20 25 ... 30 35 40 45 O 5 19 10 15. 20 25 30. ... a5 110 4b5 -.50 SS Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (k ) Figure 2-11. Striped bass habitat (shaded areas; tempera es :5 2 °C and dissolved oxygen ? 2 mg/L) in Lake Norman in June, July, August, September, and October 2007. �,, 24 24 CAKE NORMAN STRIPED BASS HABITAT LAKE NORMAN STRIPED BASS HABITAT 110 8.0 11.0 13.0 15.0 15.9 62.0 69.0 72.0 80A 23 1 A 8.0 11 A 13.0 :15.0 15 9.... 62.0 69.0 72.0 80.0 . 23 23 E 26 deg C 26 deg 21 2 g/L 21 2mg/L ® 21 m 21 2a Aug 27, 2007 20 Sep 17, 2007 20 20 0 5 1a 1S 20 2S 3a 5 4a 45 5a 55 19 1a 15 20 25 3f9 35 4a 45 a 5 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) 4 24 LAKE NORMAN STRIPED BASS HABITAT LAKE NORMAN STRIPED BASS HABITAT 23 1.0 8.0 11:0 13.0 : 9SA 16.9 62.0 69.0 72.0 80.0 23 1,Q 8A 11.0 13.0 15.0 15.9 6ZO 69.0 72A 60.0 1 .23 23 a� 22 22 26 deg C V 26 deg C 21 21 ETA 21 :.r 21 . . 20 Sep 24, 2007 20 ./ Oct 1, 2007 20 20 19" 10 15 2a 28 3a 35 i8 45 so 5 19 a 1a 15 a 25 30 35 40 45 60:..75 Distance from Cowans Ford Dam (km) Distance from Cowans Ford Dam (km) Figure -11. (Continued). 232.0 Fall Pond @ 231.65 mmsl 231.5 231.0 Al a 30.5 ID 230.0 229.5 229.0 N N ttl t M LO u) Lo U) t c� Figure 2-12. Lake Norman lake levels, expressed 1n meters above mean sea level ( l) for 2002, 2003, 2004, 2005, 2006, and 2007. Labe level data correspond to the water quality sampling dates over this time period. CHAPTER 3 PHYTOPLANKTON INTRODUCTION Phytoplankton standing crop parameters were monitored in 2007 in accordance with the NPDES permit for McGuire Nuclear Station S). The objectives of the phytoplankton study of the Lake Norman Maintenance Monitoring Program are to: 1. Describe quarterly patterns of phytoplankton standing crop and species composition throughout Lake Norman; and 2. Compare phytoplankton data collected during this current study with data collected i prior study years. In previous studies on " Lake Norman considerable spatial and temporal variability i hyto lankton standing crops and taxonomic composition have been reported (Duke Power Company 1976, 1985; Menhinick and Jensen 1974; Rodriguez 1982). Rodriguez (1982) classified the lake as oligo- esotrophic (low to intermediate productivity) based on phytoplankton abundance, distribution, and taxonomic composition. Past maintenance monitoring program studies have confirmed this classification (Duke Energy 2007). METHODS AND MATERIALS Quarterly sampling was conducted at Locations 2.0, 5.0 (mixing zone), 8.0, 9.5, 11.0, 13.0, 15.9, and 69.0 in Lake Norman (Figure -1). Duplicate grabs from 0. , 4.0, and 8.0 in (i.e., the estimated euhotic zone) were taken and then composited at all locations, except Location 69.0, where grabs were taken at 0., 3.0, and 6.0 in due to the depth. Crab samples were composited for each location. Sampling was conducted in February, May, August, and November 2007. Secchi depths were recorded from all sampling locations. As in previous years and based on the original design study (Duke Power Company 198), phytoplankton density, biovolume, ;and taxonomic composition were determined for samples collected at Locations 2.0, 5.0, 9., 11.0, and 15.9; chlorophyll a concentrations and sston dry and ash - free dry weights were determined for samples from all locations. Chlorophyll a and total 3-1 phytoplankton densities and biovolumes were used in determining phytoplankton standing crop. Field sampling and laboratory methods used for chlorophyll a, seston dry weights, and population identification and enumeration were identical to those used by Rodriguez (1982). Data collected in 2006 were compared with corresponding data from quarterly monitoring beginning in August 1987, RESULTS AND DISCUSSION Standin Crop I,--- Chlorophyll a Chlorophyll a concentrations (mean of two replicate composites) ranged from a low of 1.96 gg/L at Location 8.0 in November, to a high of 13.66 gg/L at Location 69.0 in August (Table 3-1, Figure 3-1). All values were below the North Carolina water quality standard of 40 Itg/L (NCDENR 1991). Lake -wide can chlorophyll concentrations were within ranges of those reported in previous years, but were all below the long-term lake -wide means (Figure 3-2). Seasonally, chlorophyll concentrations increased from February through May to the annual maximum in August then declined to the annual lake -wide minimum in November. used, on quarterly mean chlorophyll concentrations, the trophic level of Lake Norman was in the oligotrophic (low) range during February and November and in the mesotrophic (intermediate) range in May and August 2007. Over 59% of the mean chlorophyll a values were less than 4 gg/L (oligotrophic), while all but one of the remaining chlorophyll a values were between 4 and 12 gg/L (mesotrophic). The chlorophyll concentration from Location 69.0 in August was the only one greater than 12 pg/L (eutrophic, or high range). Historically, quarterly mean concentrations of below 4 gg/L have been recorded on fourteen previous occasions, while lake -wide mean concentrations of greater than 12 gg/L were only recorded during May of 1997 and 2000 (Duke Power 1998, 200 1; Duke Energy 2007). During 2007 chlorophyll a concentrations showed typical spatial variability. Maximum concentrations among sampling locations were observed at Location 69.0 (furthest up -lake) during all sampling periods, while minimum concentrations occurred at Location 9.5 in February, Location 2.0 in May, Location 5.0 in August, and Location 8.0 in November (Table 3-1). The trend of increasing chlorophyll concentrations from down -lake to up -lake, which had been observed during many previous years, was apparent to some extent during all sampling periods (Table 3-1, Figure 3 -1). Flow in the riverine zone of a reservoir is subject to wide fluctuations depending, ultimately, on meteorological conditions (Thornton, et al. 1990), although influences may be moderated due to upstream dams. During periods of high flow, algal production and standing crop would be depressed due in great part to washout. Conversely; production and standing crop would increase during periods of low flow resulting in higher retention time. However, over long periodsof low flow, production and standing crop would gradually decline once more. These conditions result in the comparatively high variability in chlorophyll concentrations observed between Locations 15.9 and 69.0 throughout many previous years, as opposed to Locations 2.0 and 5.0 which have usually shown similar concentrations during sampling periods. Mean quarterly chlorophyll concentrations during the period of record. (August 1987 November 2007) have varied considerably, resulting in moderate to wide historical ranges. During February 2007, chlorophyll values at all but Location 690 were lower than in previous February periods, while the value at Location 69.0 was higher than average (Figure 3-3). Long-term February peaks at Locations 2.0 through 9.5 occurred in 1996 while the long-term February peak at Location 11.0 was observed in 1991. Long-term maxima at Locations 1.0 and 15.9 occurred in 2003. The highest February value at location 69.0 occurred in 2001. , All locations had higher chlorophyll concentrations in February 2007 than in February 2006 (Duke Energy' 2007). During May, mean chlorophyll concentrations at Locations 2.0 and 5.0 were in the mid historical range, while concentrations at Locations 8.0 through 15.9' were in the low range. The concentration at Location 69.0 was once again in the high range (Figure 3-3). Long-term May May peaks at Locations 2.0 and 9.5 occurred in 192; at Location 5.0 in 1991; at Locations 8.0, 11.0, and 13.0 in 1997; at Location 15.9 in 2000; and at Location 69.0 in 2001 May 2007 mean chlorophyll concentrations at all but Location 13.0 were higher than those of 2006 (Duke Energy 2007), Although the lake -wide mean chlorophyll concentration in August 2007 was the highest of the four sampling periods, mean chlorophyll concentrations at all but Location 6.0 were in the low historical range, with Location 6.0 having a concentration in the high range (Figures -2 and 3-. Long-term August peaks at Locations 2.0 and 5.0 were observed in 1998, while 3-3 August peaks at Locations 8.0 and 9.5 occurred in 1993. Long-term august peaks at Locations 11.0 and 13.0 were observed in 1991 and 1993, respectively. The highest August chlorophyll concentration from. Location 1.9 was observed in 1998, while Location ,69.0 experienced its long-term August peak in 2001. Mean chlorophyll concentrations for August 2007 were higher than those of August 2006 at all but Location 5.0 (Duke Energy 2007). The lake -wide mean chlorophyll concentration in November 2007 was the lowest among all four sampling periods (Figure -2). Chlorophyll concentrations at all but Location 69.0 were in the low historical range and concentrations from Locations 5.0, 8.0, 9.5, and 1.9 were the lowest November concentrations recorded from these locations (Figure -4). As was the case during the previous sampling periods, the chlorophyll concentration at Location 69.0 was in the high historical range. Long-term November peaks at Locations 5.0 and 8.0 occurred i 2006, while November maxima at Locations 11.4 and 15.9 occurred in 1996. The highest November value at Location 13.0 was recorded. for 1992, while the November maxima at Locations 2.0 and 9.5 were observed in 1997. The highest November chlorophyll concentration at Location 69.0 occurred in 1991. November 2007 chlorophyll concentrations at all but Location 69.0 were lower than during November 2006 (Duke Energy 2007): Total Abundance Density and biovolume are measurements of phytoplankton standing crops. In most cases standing crop parameters mirror the temporal trends of chlorophyll concentrations. During 2007, mean seasonal standing crops increased from the annual minimum in February through to the annual peak in August then declined through November. The lowest density (761 its/ L) and biovol e (551 mm3/ ) occurred at Location 9.5 in February (Table -2, Figure - ). The maximum density (6,232 its/mL) and biovvol e (4,860 1 3) were observed at Location 1.9 in August. Most standing crop values during February, May, and August 2007 were higher than those of 2006, while values from November 2007 were lower than in November of the previous year (Dube Energy 2007). Phytoplankton densities during 2007 never exceeded the NCB' guidelines for algae blooms of 10,000 units/mL density and 5,000 3/ 3 for biovolume (NCDE 1991). Densities or biovolumes in excess of N guidelines were recorders in 1987, 1989, 1997, 1998, 2000, 2003, and 200 (Duke Power Company 1988, 1990; Duke Power 1998, 1999, 2001, 2004a, Duke Energy 2007). During all sampling periods phytoplankton densities and biovolumes demonstrated a spatial trend similar to that of chlorophyll; that is, lower values at down -lake locations verses up -lake locations (Table -2, Figure -1). 3-4 Seston Seston dry weights represent a combination of algal matter and other organic and inorganic material. Dry weights during 2007 were most often lower than those of 2006. As was observed with chlorophylls and algal standing crops, a general pattern of increasing values from down -lake to up -lake was observed during 2007 (Table 3-3 and Figure 3-1). From 1995 through 1.997 seston dry weights had been increasing (Duke Power 1998). Values from 1998 through 2001 represented a reversal of this trend, and were in the low range at most locations during 1999 through 2001 (Duke Power 2002). Low dry weights during these years were likelya result of prolonged drought conditions resulting in low sedimentation from runoff (Figure 2-2a). From 2002 through 2006, dry weights gradually increased throughout the lake, followed by a dramatic decline in 2007. The lake -wide average dry weight in 2007 was the lowest since dry weights were recorded in 1988. These exceptionally low values were likely due to severe drought conditions throughout the watershed during 2007. Seston ash -free dry weights represent organic material and may reflect trends of chlorophyll a. This relationship held true for the most part during 2007, especially with respect to increasing values from down -lake to up -lake areas, as was the case with chlorophyll concentrations and standing crop values (Tables 3-1 through 3-3). Secchi DWths Secchi depth is a measure of light penetration. Secchi depths were often the inverse of suspended sediment (seston dry weight), with the shallowest depths at Locations 13.0 through 69.0 and deepest from Locations 9.5 through 2.0 down -lake. Depths ranged from 1.10 m at Location 13.0 in February and 69.0 in August, to 3.7 rn at Location 8.0 in May (Table 3-1). The lake -wide mean Secchi depth during 2007 was slightly higher than in, 2006 and was within historical ranges for the years since measurements were first reported in 1992. The deepest lake -wide mean Secchi depth was recorded for 1999 (2.26 m) (Duke Power 2000). Community Compqsjtion One indication of "balanced indigenous populations" in a reservoir is the diversity, or number of taxa, observed over time. Lake Norman typically supports a rich community of 3-5 phyroplankton species. This was certainly true in 2007. Ten classes comprising 98 genera and 257 species, varieties, and forms of phytoplankton were identified in samples collected during 2007, as compared to 91 genera and 23 lower taxa identified in 200 (Table -4). The 2007 total represented the highest number of taxa recorded in any year since monitoring began in 1987 (Duke Energy 007). Fifteen taxa previously"unrecorded during the Maintenance Monitoring program were identified during 2007. Deci s Conmosition and Seasonal Succession The phytoplankton community in Lake Norman varies both seasonally and spatially. Additionally, considerable variation may occur between ;years for the same months sampled. During February 2007, cryptophytes (C tophyceae) dominated densities at all locations (Table 3-5 - Figures 3-5 through 3-. During most previous years, cryptophytes and occasionally diatoms dominated February phytoplankton samples in .Lake Norman. The most abundant cryptophyte during February 2007 was the small flagellate Rhodomonas minuta. R. minuta has been one of the most common and abundant forms observed in Labe Norman samples since monitoring began in 1987. Cryptophytes are characterized as light limited, and are often found deeper in the water column or near surface under low light conditions, which are common during winter (Lee 1989). In May, diatoms (acillariophycea) were dominant at all locations (Table -5, Figures 3-5 through 3-9). The most abundant diatom at all locations was the pennate, F'ragillaria croto ensis. Diatoms have typically been the predominant forms in May samples of previous years; however, cryptophytes dominated May samples in 1988, and were co -dominants with diatoms in May 1990, 1992, 1993, and 1994 (Duke Power Company 1989, 1990, 1991, 1992, 1993,1994, 1995, 1996, 1997 Duke Power 1998, 1999, 2000, 2001, 2002, 2003, 2004a, 2005; Duke Energy 2006 007). During August 2007, green algae (Chlorophyceae) dominated densities at all locations (Figures -5 through 3-9). The most abundant green alga was the small desmid, Cosmarium asphearosporum var. strigos m (Table 3-7). During August periods of the Lake Norman study prior to 1999, green algae, with blue-green algae yxophyceae) as occasional dominants or co -dominants; were the primary constituents of summer phytoplankton assemblages, and the predominant green alga was also C: asphearosporum var. strigosum (Duke Power Company 1989, 1990, 1991, 1992, 1993, 1994, 1995, 1996, 1997; Duke Power 3-6 1998, 1999). During August periods of 1999 through 2001, Lake Norman phytoplankton assemblages were dominated by diatoms, primarily the small pennate, Anomoeoneis vitrea (Duke Power 2000, 2001, 2002). A. vitr°ea has been described as typically periphytic and widely distributed in freshwater habitats and was identified as a major contributor to periphyton communities on natural substrates during studies conducted from 1974 through 1977 (Derwort 1982). The possible causes of this significant shift in summer taxonomic composition were discussed in earlier reports and included deeper light penetration (the three deepest lake -wide secchi depths were recorded from 1999 through 2001), extended periods of low water due to drawdown, and shifts in nutrient inputs and concentrations (Duke Power 2000, 2001, 2002). Whatever the cause; the phenomenon was lake -wide and not localized near MNS- or Marshall Steam. Station (MSS), therefore, it was most likely due to a combination of environmental factors, and not station operations. 'Since 2002, taxonomic composition during the summer has shifted back to green algae predominance (Duke Power 2003, 2004a, 2005 Duke Energy 2006, 2007). During November 2007, densities at all locations were: again dominated by diatoms. The most abundant species at Locations 2.0, 11.0, and. 15.9 was the pennate diatom, 7'abellaria enestrata (Table -5, Figures 3-5 through -9). At Locations 5.0 and. 9.5, the most abundant diatom was the centrate, Melosir°a arnbigua. These diatoms have been among the most common and abundant forms found in Lake Norman throughout the Labe Norman Maintenance Monitoring program. Blue-green algae, which are often implicated in nuisance blooms, were never abundant in 007 samples (Duke Energy 2007). Their overall contribution to phytoplankton densities was slightly higher than in 2006, but densities seldom exceeded 3% of totals, Prier to 1991, blue-green algae were often dominant atup-lake locations during the summer(Duke Power Company 18, 189, 10, 11, 1992). FUTURE STUDIES No changes are planned for the phytoplankton portion of the Lake Norman an Maintenance - Monitoring Program. 3-7 Lake Norman continues to be classified as oligo-mesotrophic based on long-term, annual mean chlorophyll concentrations. Chlorophyll concentrations during 2007 were most often within historical ranges, however, several record low chlorophyll concentrations were recorded in November. Lake -wide mean chlorophyll increased from February through August then declined to the annual minimum in November. Some spatial variability was observed in 2007, however, maximum chlorophyll concentrations were typically observed up -lake at Location 69.0, while minimum chlorophyll concentrations were recorded from down -lake at Locations 2.0 through 9.5. The highest chlorophyll value recorded in 2007, 13.66 gg/L, was well below the NC State Water Quality standard of 40 jig/L. Phytoplankton densities and biovolumes during 2007 were generally higher than in 2006. Phytoplankton densities during 2007 never exceeded the NC guidelines for algae blooms. Standing crop values in excess of bloom guidelines have been recorded during seven previous years of the program. As in past years, higher standing crops were usually observed at up -lake locations, while comparatively lower values were noted down -lake. Seston dry and ash -free weights were most often lower in 2007 than in 2006 and down -lake to up -lake differences were apparent during all quarters. Maximum dry and ash -free weights were generally observed at Location 69.0. Minimum values were noted at Locations 2.0 through 9.5. Secchi depths reflected suspended solids with shallow depths related to high dry weights. The lake -wide mean Secchi depth in 2007 was slightly higher than in 2006 and was within historical ranges recorded since 1992. Diversity or the number of tax a of phytoplankton in 2007 was the highest yet recorded. The taxonomic composition of phytoplankton communities during 2007 was similar to those of many previous years. Cryptophytes were dominant in February, while diatoms were dominant during May and November, Green algae dominated phytoplankton assemblages during August. Blue-green algae were slightly more abundant during 2007 than during 2006, but their contribution to total densities seldom exceeded 3%. 3-8 The most abundant alga, on an annual basis, was the cryptophyte R. manuta. The most abundant diatom in May was F. crotonensis, while the most abundant diatoms during November were T. fenestrata and M ambzgua. The small desmid, C. asphearosporum var. strigosum was dominant in August 2007. All of these to a have been common ion d abundant throughout the Lake Norman Maintenance Monitoring program. Lake Norman continues to support highly variable and diverse phytoplankton communities. o obvious short-term or long-term impacts of station operations were observed. 3- Table 3-1. Mean chlorophyll a concentrations (gg/L) in composite samples and cchi depths (m) observed in Lake Norman in 2007. CHLOROPHYLL A FEB MAY AUG NOV Location 2.0 2.91 2.94 4.47 2.07 5.0 2.94 3.04 3.60 2.18 8.0 3.58 3.11 4.77 1.96 9.5 2.80 3.26 5.02 2.35 11.0 3.78 3.98 5.35 3.32 13.0 3.94 4.41 4.10 3.43 15.9 4.61 5.46 7.70 3.86 69.0 6.19 10.46 13.66 5.59 SECCHI DEPTHS FEB MAY AUG OCT* Location 2.0 2.10 3.20 2.90 2.36 5.0 2.25 2.90 2.40 1.82 8.0 2.60 3.70 2.71 2.26 9.5 2.40 3.10 2.70 2.44 11.0 1.30 2.10 2.35 2.48 13.0 1.10 1.90 1.25 1.50 15.9 1.32 1.20 2.80 1.63 69.01 1.20 1.20 1.10 1.26 Annual mean from all Locations: 2007 2.11 Annual mean from all Locations: 2006 1.94 *Secchi depths were not available for November. 3-10 Table -2. Mean phytoplankton, densities (units/mL) and biovolumes (rnm3/m3) by location and sample month f°om samples collected in Lake Norman, NC, during 2007. denslt Locations Month 2.0 5.0 9.5 11.0 15.9 Mean FEB 911 961 761 1,100 1,884 1,123 MAY 1,454 1,566 1,737 2,730 3,181 2,14 AUG 2,800 1,943 2,957 3,385 6,232 3,463 NOV 783 869 970 1,402 1,723 1,149 Bio olume • ® 9.5 411.0 15.s -* TEB *� #• MAY AUG e a is ►• Table -3. Total mean seston dry and ash free dry weights (m/L) from samples collected in Lake Norman, NC during 2007. Dry Wei hts Locations Month 2.0 5.0 8.0 9.5 11.0 13.0 15.9 69.0 Mean FEB 0.97 0.99 1.2 0.94 1.46 1.5 1.61 2.37 1.34 MAY 0.58 0.76 0.82 1.01 1.28 0.96 1.01 2.75 1.15 AUG 1.29 1.11 1.23 1.29 1.19 1.87 2.01 2.46 1.55 NOV 1.40 1.48 1.17 1.57 1.81 1.85 1.58 2.78 1.70 Ash free dry weiqhts Month FEB0.41 0.46 0.48 0.36 0.57 0.61 0.81 0.83 0.56 MAY 0. 1 0. 6 0.47 0.50 0.60 0.55 0.59 0.86 0.55 AUG0.86 0.76 0.87 0.86 0.89 0.89 1.36 1.19 0.96 NOV.57 0.52 0.33 0.85 0.70 0.65 0.67 1.01 0.66 3-11 Table - . (Continued). s I� e s ♦ ! v soo ®p, 6 ' g i # t i♦ f ♦ R r # M ♦ « M p my t _. MOM ®M®... mmmnmnn 3-1 Table -4. (Continued) G. spp. Stein ®® P. ein f R' taxa found during 1987 - 91 only 3-22 Table 3-. Dominant classes, their most abundant species, and their percent composition (in parentheses) at Lake Norman locations during each sampling period of2007. 2.0 5.0 11.0 15.9 2.0 5.0 w ♦ ! 9.5 111.0 159 3-23 CHLOROPHYLL a (pg/L) DENSITY (unftslml-) 16 ................................. 7000 ................................ 14 ................................ 6000 ............................... . 12 ................................ 5000 --------------------------------- 4000 ........................... . ..... .............................. 8 ............................ . .. 6 ........................ .. .. 3000 .............. ..... 4 . ....... 2000 2 ................. 1000 ....... 0 0 N q q Cq to U') (0 0') M 0 M 0 C� C> Ua Ui C) Ul) SESTON DRY WEIGHT (mg/L) SIOVOLUME (mm3lm) 3.0 --------------------------------- 6000 ................................. 2.5 ................................ 5000 ................................ 2.0 ........................... 4000 .............................. .. 1.5- 6-i� ... . ... .... 3000 -------------------------- ------ to ....... .... 2000 t ................... -- ----- 0.5 ............................... 1000 ........ ......... 0:0 - ----- 0 1 q q q cts <a o 0 0 U) C14 LO M M 0 0 C-i Ui 0i L6 LOCATIONS FEB MAY '& ---- - — mr AUG ----- X— NOV Figure 3-1. Phytoplankton chlorophyll a, densities, biovolumes, and sexton weights at locations in Lake Norman, NC in February, May, August, and November 2007. 3-24 14 . ..................................................................... 12.41 -MAY 1997 9 --- �36�UG 12 . .................. ---------- .................................... 11.36-AUG 1993 111 -06-NOV 1996 1,06-NOV 1996 10 . ................................................... W ---------------­- 9 Cfl 8 ........ ­ ---------------------- -------------------------------------- 2 6­ --------------- ------------------------- .................... 0 4.00 AUG 1988 ..................................... .............. ...... 2.90 NOV 2002 24 2,08 FES 2006 .............. ...................................... 116 MAY 1999 0- FEB MAY AUG NOV --*-MIN --*-2007 -*-MEAN I Figure 3-2. Lake Norman phytoplankton chlorophyll a seasonal maximum and minimum lake wide means since August 1987 compared with the long to seasonal lake wide means and lake wide means for 2007. 3-25 MEAN CHLOROPHYLL a (pg/L) FES MAY 2.0 -5.0 30 ----------------- 30 �4XfN6-i6�E ............... 25 ............................... 25 .............................. 20 ------------------------------- 20 ------------------------------ 15 ------------------------------- 15 ------------------------------ 10 -------------- ---------------- 10 ------ ........ ............ 54---- . . . ......... .. 5 .. . ..... .. 0 0 1 . 87 89 91 93 95 97 99 01 03 05 07 87 89 91 93 95 97 99 01 03 05 07 1-*-8.0 --*-9.51 L --------------- -- j Ei0� ,-A L--o !n 30 ------------------------------- 30 - ----------------------------- 25 ------------------------------- 25 ---------------------------- 20 ------------------------------- 20 -- ---------------------- * ..... 15 t ......... 15 ............................... ... ................ 10 ------- ... ............... 5 10 5 o 0 87 89 91 93 95 97 99 01 03 05 07 87 89 91 93 95 97 99 01 03 05 07 1--*-11.0 --m-13.01 30 ................................ 30 ------------------------------- 25 -------------------------------- 25 ............................... 20 ................................ 20 ------------------------------- 15 ....... ................. ..... 15 ------- ._...--------- 10 ... . ............... ..... 10 --- - -------------- ----- 5 . ..... 5 . ..... 0 ... -All 0 1 A A 9 A I 87 89 91 93 95 97 99 01 03 05 07 87 89 91 93 95 97 99 01 03 05 07 -------------- --+-E;z�-*- 1&9 69-0 30 ------------------------------- 30 . ............................. 25 ........................ ..... 25 ................ ... .......... 20 ------------------------ ..... 20 --------------- - -- --------- 15 ..... f-** .............. ...... 15 ----------- -------- ........ 10 ... ........... . . 10 ------- 5 5 0 0 87 89 91 93 95 97 99 01 03 05 07 87 89 91 93 95 97 99 01 03 05 07 Figure 3-3. Phytoplankton mean chlorophyll a concentrations by location for samples collected in Lake Norman, NC, from February and May 1988 — 2007. 3-26 MEAN OHC U +- .0 .0 35 MIXING ZONE--------------- 30 ............................. 25 ........... .. ......... 15 -------------------- ------ 10 .,.... ..s.... ..:......... 0 87 89 91 93 95 97 99 01 03 05 07 8.0 9.5� 35 --------------------------- 20 .............................. 15 ..... 10 5 ...... '.. 0 87 89 91 93 95 97 99 01 03 05 07 �r-11.0 13.0 25 ........................... 15 --------------------------- 10 .... . ...... 5 0 87 89 91 93 95 97 99 01 03 05 07 �► -15.9 .0 35 ...........:........ 25 ....... .......... . ....... 20....... ......... . ....... Is. ....... ..... . ..... 10 5 ------------ ----------- 0 87 89 91 93 95 97 99 01 03 05 07 Figure 3 -4. Phytoplankton mean chloro OROPHYLL a (Ng/L) NOV --+-- 2.0 5.0 1 30 . MIXING ZQW....._........... 10 .......... 5 0 87 89 91 93 95 97 99 01 03 05 07 —o- 8.0 a 9.5 35 ............................ 30 ...... .. .......... 25 -: .................. .... 20 . `.......................... 15 ............ 10 5 0 87 89 91 93 95 97 99 01 03 05 07 to-- 13.o 35 ..... .... . 30 ......... ................... 25 .............................. 20 .............................. 15 . .................... .... 10 -------- .. . ..------- . 5 0 87 89 91 93 95 97 99 01 03 05 07 15,9 69.0 1 35 ............................... 30------------------------ *...... 25..................... ......": 20 ...................... 15 .... ..... ................ 10 5 ------ 0 87 89 91 93 95 97 99 01 03 05 07 phyll a concentrations by location for samples collected in Lake Norman, NC, from August and November 1987 — 2007. 3-27 4000 - ' ~ 5000 --- ----- OGHLOROPHYCEAE 0 BACILLAR16-PHYCEA-E- "' * " * * 4500 --- ----- MCHRYSOPHYCEAE E3 CRY PTOPHYCEAE -------- MMYXOPHYCEAE M DINOPHYCEAE 4000 ---- ---- N OTHERS ....... 3500 ................................................................... -E 0 3000 ------------------------ ---------------- -------------------------- 2500 --------------------------------------- .................... 2000 --------------------------------------- .................... Z1500 ........... .....I .... ......... . 1000 .................... ......... ......... ..... 500t---- . .......I........ ....-.... ..... 0 — —................... FEB MAY AUG NOV 3000 . ................................................................. 2500 ------------------------------------------------------------------- E M E2000 ................................................................... E w1500 2 ....................................................... .... D 0 1000 ...................... ........ ........ ..... 0 1 00 500 --------------------- ......... ........ 0 FEB MAY AUG NOV Figure 3-7. Class composition (mean density and biovolume) of phytoplankton from euphotic zone samples collected at Location 9.5 in Lake Norman, NC during 2007. 3-30 5000 - -------- 0 CHLOROPHYCEAE CS BACILLARIOPHYCEAE ... 4500 -- -------- IMCHRYSOPHYCEAE SCRYPTOPHYCEAE ... 0 MYXOPHYCEAE M DINOPHYCEAE 4000 .......... 8 OTHERrn ... E3500 --------------- -------------- ------------------------------------ 3000 --------------- ....................... .................. ... 2500 ---------------------- ......... ..................... 2000 -- -------------------- ......... ..................... wZ1500 ---------------------- ......... ..................... 1000 ......... ......... ......... ..... 500 ------ 0 FEB MAY AUG NOV 3000 - ......... -....... ------------------------------------------------ 2500 ----------------- --------------------- ............. ------- E M E2000 ...................... ......... ..................... E w1500 ------ ......... ......... ......... ..... 0 1000 ------ ......... --------- ---------ca .... 0 ca500- ........ ----- ... --------- ----- 0- FEB MAY AUG NOV Figure 3-8. Class composition (mean density and biovolume) of phytoplankton from euphotic zone samples collected at Location 11.0 in Lake Norman, NC during 2007. 3-31 8000-1 OCHLOROPHYCEAE 93 BACILLARIOPHYCEAE MCHRYSOPHYCEAE SCRYPTOPHYCEAE 7000- -- t2MYXOPHYCEAE M DINOPHYCEAE 8 OTHERS 6000 --------------------------------------- ..................... E -a, 5000 ....................................... ..................... 4000 --------------------------------------- ..................... 3000 ...................... ........ .................... U1 2000 ...................... a ......... ..................... 1000 ----- ......... ........ ..... OLM I I FEB MAY AUG NOV 5000 .................................................................... 4000 ....................................... ..................... E M E Ewoo ....................................... ..................... w .j 2000 ------ .......... ......... ......... ..... 0 0 CO 1000 ------ 0 FEB MAY AUG NOV Figure 3-9. Class composition (mean density and biovolume) of phytoplankton from euphotic zone samples collected at Location 15.9 in Lake Norman, NC during 2007. 3-32 CHAPTER ZOOPLANKTON INTRODUCTION The objectives of the Lake Norman Maintenance Monitoring Program for zooplankton are to: 1. Describe and characterize quarterly patterns of zooplankton standing crops at selected locations on Lake Norman d . compare and evaluate, where possible, zooplankton data collected during 2007 with historical data collected during the period 1987 — 2006. Previous studies of Lake Norman zooplankton populations, using monthly data, demonstrated a bimodal seasonal distribution with highest values generally occurring in the spring, and a less pronounced fall peak. Considerable spatial and year-to-year variability has been. observed in zooplankton abundance in Lake Norman (Duke Power Company 1976, 1985; Hamme 1982; Menhinick and Jensen 1974). Since quarterly sampling was initiated in August 1987, distinct bimodal seasonal distribution has been less apparent; due to the lack o transitional data between quarters. METHODS AND MATERIALS Duplicate 10 m to surface, and bottom to surface net tows were taken at Locations 2.0, 5.0, 9.5, 11.0, and 15.9 in Lake Norman (Figure -1,) during each season: winter (February), spring (May), summer (August), and fall (November) 2007. For discussion purposes the 10 m to surface tow samples are called "epili etic" samples and the bottom to surface net tow samples are called "whole -column" samples. Locations 2.0 and 5.0 are defined as the "mixing zone" and Locations 9.5, 11.0 and 15.9 are defined as "background" locations. Field and laboratory methods for zooplankton standing crap analysis were the same as those reported in Harnme (19). Zooplankton standing crop data from 2007 were compared with corresponding data from quarterly monitoring begun in :August 1987. 4-1 RESULTS D DISCUSSION Highest epilinmetic zooplankton densities at Labe Norman locations have predominantly been observed in the spring, with winter peaks observed. about 25% of the time,`and peaks observed only occasionally in the summer and fall (Duke Energy 2007). During 2007, annual epilimnetic maxima were recorded from Locations 2.0, 5.0, and 15.9 in the spring. while Locations 9.5 and. 11.0 demonstrated peak annual densities in February (Table 4-1, Figures -1 and 4-2). The lowest epilimnetic densities occurred in the fall at all but Location 15.9, which had the annual minimum density in the summer. Epilinmetic zooplankton densities ranged from a low of3 ,564/ 3 at Location 2.0 in the fall, to a high of 94,1 2/ 3 at Location 15.9 in the spring. Maximum densities in 2007 whole -column samples were observed during different seasons at different locations. At Locations 9.5 and 11.0, maximum values occurred in the winter, annual maxima at Locations 2.0 and 15.9 were observed in the spring, and the highest density from Location 5.0 occurred in the summer (Table 4-1 and Figure 4- 1). Minimum whole - column densities were observed in the summer at Locations 11.0 and 15.9 and in the fall at Locations 2.0, 5.0, and 9.5. Whole -column densities ranged: from a low' of 30,61 I/M3 at Location 2.0 in the fall, to 21 ,242/ 3 at Location 15.9 in the spring. Consistent with historical data, during 2007 total zooplankton densities were most often higher in epilinmetic samples than in whole -column samples (Duke Energy 2007). This is related to the ability of zooplankton to orient vertically in the water column in response to physical and chemical gradients and the distribution of food sources, primarily phytoplankton, which are generally most abundant in the euphoric zone (Hutchinson 1967). Since epilimnetic zooplankton communities are far more representative of overall seasonal and temporal trends, most of the following discussion will focus primarily on zooplankton communities in this area of the water column. Although spatial distribution varied among locations from season to season, a general pattern of lower average densities ftom the mixing zone, as compared to background locations, was observed during 2007 (Table 4-1, Figures 4-1 and 4- ). Location 15.9, the uppermost background location, had higher epilimnetic densities than mixing zone locations during all sampling periods (Table 4-1). This spatial trend was similar to that of the phytopl on 4.2 (Chapter 3. In most previous years of the program, background locations had higher mean densities than mixing zone locations (Figures 4-3 through 4-6; and Duke Energy 2007). Historically, both seasonal and spatial variability of epilinmetic zooplankton densities have been much higher among background locations than among'mixing zone locations. The uppermost Location 1 . , showed the greatest range of densities during 2007 (Table' 4-1, Figures 4-3 through 4-6). Apparently, epilimnetic zooplankton communities are more greatly influenced by environmental conditions at theup-lake locations than at the down -lake locations. Location 15.9 represents the transition zone between river and reservoir where populations would be expected to fluctuate due to the dynamic nature of this region of Lake Norman. At the locations nearest the dam (Locations 2.0 and 5.0), seasonal variations are dampened and the overall production would be louver due to the relative stability of this area (Thornton, et al. 1990). Additionally, the effects of MNS once -through cording could cause somewhat lower production at these locations. A similar trend was observed in the pbytoplankton communities (Chapter 3). Epilimnetic zooplankton densities during 2007 were most often within historical ranges (Figures 4-3 through 4-6). The exceptions were at Location 9.5 in the summer and Location 15.9 in the winter. On both occasions, these locations demonstrated long-term seasonal maximum densities (Figures 4-3 and 4-6). The highest winter densities recorded from Locations 2.0 and 11.0 occurred in 1996, while the winter maximum at Location 9.5 was recorded. in 19 (Figure 4-3). The winter maxima from Locations 5.0 and 15.9 occurred in 2004 and 2007, respectively. Long-term maximum densities for spring were observed at Locations 2.0 and 5.0 in 2005, while the highest spring values from Locations 11.0 and 1.9 occurred in 2002. The highest spring peak. at Location 9.5 was observed in 2005 (Figure -4). Long-term summer maxima occurred in 1988 at Locations 2.0, 5.0, and 11.0, while summer maxima at Locations 9.5 and 15.9 occurred in 2007 and 2003, respectively (Figure 4-5). Long-term maxima for the fail occurred at all but Location 15.9 in 2006, while the long-term maximum at Location 15.9 was recorded in 1999 (Figure 4-). From 1990 -- 2003, the densities at mixing zone locations in the spring, summer, and fall demonstrated moderate degrees of year-to-year variability, and the long-term trend at mixing zone locations in the spring had been a gradual increase through 2005. During the spring of 2006, zooplankton densities in the mixing zone declined sharply, as compared to 2005 and 4-3 were well within earlier historical ranges. During 2007, mixing zone locations demonstrated increases. Year-to-year fluctuations of densities in the mixing zone during the winter have occasionally been quite striking, particularly between 1991 and 1997. The background locations continue to exhibit considerable year-to-year variability in all seasons (Figures -3 through 4-6). communitV Com osition One hundred and twenty-three zooplankton taxa have been identified since the Lake Norman Maintenance Monitoring Program began in ,August 1987 (Table 4-2). Forty-nine taxa were identified during 2007, as compared to 44 recorded for 2006 (Duke Energy 2007). Two previously unreported taxa, the copepod Eucyclops prionc phorus and the rotifer, Keratella timer Cana, were identified in 2007. In 2006, copepods were the most abundant zooplankters in eight samples; one in the winter and seven in the summer (Duke Energy 2007). During 2007, copepods were dominant in only three samples. the epilimnion at Locations 2.0 and 5.0 in the spring, and the whole column sample from Location 2.0 in the summer (Table 4-1). Cladocerans, most often the leash abundant forms in Lake Norman, were dominant in two whop column samples, one from Location 2.0 in the spring and another from Location 9.5 in the winter (Table -1). Rotifers were dominant in all other samples collected in 2007. During most years,' icros stace s (copepods and cladocerans) dominated mixing zone samples, but were less important among background locations (Figures 4-7 and 4-8). Compared to 2006, microcrustaceans showed a slight increase in relative abundances in the epilimmon of the mixing None, while they demonstrated a slight decrease among whole -column samples at these locations (Figure 4- ). At background locations microcrustacean relative abundances were similar to those of 2006 (Figure 4- ) Cop pod As has always been the case, copepod populations were consistently dominated by immature forms (primarily nauphi) during 2007. Adult copepods seldom comprised more than 7% o the total zooplankton density at any location. Tropoc c ops was the most important genus in adult populations, particularly during summer and fall (Table 4-3). Epishura was important among winter and spring samples, while Cyclops and Diaptom s were occasionally abundant. - Similar patterns of copepod taxonomic distributions were observed in previous years (puke Energy 2007). Copepods tended to be somewhat more abundant at background locations than at mixing zone locations during 2007, and their densities peaked at all locations in the spring, as was typically recorded during past years (Table 4- 1; Figure 4-), Rotif r a olyart ra was the most abundant rotifer at all locations during the fallof 2007, when it demonstrated dominance among all rotifer populations (Table -3). Keratella was the :most abundant rotifer in most spring samples, while Ptygura was most oven dominant among summer populations. During the winter, Asplanchna was the most abundant rotifer in epilimnetic samples from Locations 2.0, 5.0, and: 9.5 and among whole column samples at Locations 2.0 and 9.5. Conoc ails and ,Sync a to were occasionally dominant in samples from 'nter, spring, and summer. All of these taxa.' have been identified as important constituents of rotifer populations, as well as zooplankton communities, in previous studies (Duke Energy 2007, Harmne 12). Long-terrn trackingof rotifer populations indicated high year-to-year seasonal variability. Peak' densities have most often occurred in the winter and spring, with occasional peaks in the summer and fall (Figure 4-11). During 2007, peak rotifer densities were observed at ring zone locations in the summer and at background locations in the spring. FUTURE STUDIES No changes are planned for the zooplankton portion of the Lake Norman Maintenance - Monitoring Program. SUMMARY - Maximum zooplankton densities most often occurred in the spring of 2007, while minimum ooplankton densities were generally noted in the fall. As in past years, epilinmetic densities were higher than whole -column densities. Mean zooplankton densities tended to be higher 4-5 among background locations than among mixing zone locations during 2007. Spatial trends of zooplankton populations were similar to those of the phytoplankton, with increasing` densities from down -lake to up -lake. From around 1997 through 2005, a year-to-year trend of increasing zooplankton densities was observed among mixing zone locations in the spring. Densities at these locations declined sharply in 2006, followed by an increase in 2007. Long- term trends showed much higher year-to-year variability at background locations than at mixing zone locations. Epilinmetic zooplankton densities were generally within ranges of those observed in previous years. The exceptions were record high densities during winter at Location 15.9 and during the summer at Location 9.5. One hundred andtwenty-three zooplankton taxa have been recorded from Lake Norman sine the Program began in 1987 (9 were identified during 2007). Two previously unreported taa were identified during 2007. Overall, relative abundance of copepods in 2007 decreased over 2006, and they were dominant in only three samples. Cladocerans were dominant in two samples, while rotifers were dominant in all remaining samples. The relative abundance of microcrustaceans increased slightly in the epilimnion of the mixing zone since 2006, but decreased among whole -column samples since the previous year. At background locations, relative abundances of microcrustaceans in 2007 were similar to those of 2006. Historically, copepods and rotifers have most often shown annual peaks in the spring, while cladoerans continued to demonstrate year-to-year variability. Copepods were dominated by immature forms with adults rarely accounting for more than 7% of zoopla on densities. The most important adult copepod was Tropocyclops, as was the case in previous years. Bosmina was the predominant cladoceran, as has also been the case in most previous years of the program. Bosminopsis dominated several cladoceran populations during the summer. The most abundant rotifers observed in 2007, as in many previous years, were P l arthra, Keratella, and Ptygura, Conochilus, Asplanchna, and Syncheata were also important among rotifer populations. Lake Norman continues to support a highly diverse and viable zooplankton community. Other than somewhat lower productivity from induced mixing at Locations 2.0 and 5.0, o impacts of plant operations were observed. 4- 00 0 1'i1 3 0. ` 0 .« Q �. 0 3 0 3 0 a, �• -�, W -� rxt N N' W W to N trt W' c ; c a tt C)? is 0)C7 IV to t9 tti z ! * -a ' s C ! C3) C5> �+t N C o co co CO a a p «� -.' p. N G3) 01 0 N FW -� ' V p . . #� N CD Ul - PI Cxt tJ) c trt CJ -ti CO �I -� N :° N CO :� tit -� N V Ct3 (Aaic C (A Gtt GSA hJ C t t£ - P --� C 1O Lq Cy cv C"" C5) N N «a W N co W N Nw W W .P N N a 4hk- of CTi N W CD" COp co P P VI N 0 P to W G a C -* CO ^J c > W C. era to W C 4i , :^ 4 0 N � b) tXa � eo 6 W --' p !\} 0 c:7 " :-4 cQ N of io `p " st)1 NNNMN tTt NWNtS1i..n 0 0) Co tit 0 0 ` 4 tXt ..a N , a a • 4 t7ry � �y C N W 0) tea o - C Cii - ioJp . 3 40 . C> b) io :Pk,tit C> b tit io N - `4 ' � € D N i� tt) io to ty s W^.tN A-' ° CS) --►-a N� "a -.�- °s W C' N N ^*I fJt 'ttttt - N W .a N to txe I p, . c o 3 tta + " tb f rJ co V tJ hJ CD p C37 �J t)D r�a # # A $ $ A * • e r, • w +r * •s w • �, # •: # #.. a #. A $ $ M A W • r esa • s Table -2. Zooplankton taxa identified from samples collected quarterly on Lake Norman from 1987 — 2007. at ,;. .. as ,COPEPODA OWN A r C. ' D. D. reighardi Marsh rt rtSmith E.p�4#q�_Kiefer �® r r' A rr a i spp, Baird i ° r C. Vp. Dana r t. Leach D. Coker�� D. galeata Sars D. ® �® r - D. r -®®® �® A schodleri D. spp. Mullen Diaphanosoma�l I"I III Ic b7lIm L ■®��®�����®� tie i Eubosmina Tp. i . • A�®- gibberum Zaddach--i®® 4-10 Table -2. (Continued). M E3 •MUME3 OFA®� e t IWIMMA t rt' r n r a : • ®®® ®®®®Minim Pleuroxushamulatus re MINIM P� Baird ♦ ♦ ! � " ®IllWll� IMMIMMIMMMIMMOM IN �.p. Lauterborn •e i B. bidentata Anderson IN IN M B. �® : Vp, Pallasin in F r r M Lauterbome, Pit ee r .1�-- ! t MCI ... • ` ®®® • Hlava Imhof G. Vp Imhof in in in Hudson i i.. ♦:. t + # 101110"M Min MM MINIM Table -2. (Continued). 97 98 9$ 00 Q1 02 03 Q5 06 0'T .11 .a3 h h. � �* mayy^ X y yy -�qyy ggrr^^ -�qyy '/q1� 11 `1gp1 11 lyi� Ap r 'lg�i` ^1q.1' `(� j * m 04 6 i®®®� R f R a Monommata -,=a! f®� m®... M. M: f ' '�. t�- Brauer A. truncatum « #: ` f f ' ®®® ®® qrhv in A f. f. , "spp.! P. f f Ehrenberg Schra ®®� f b r . f Mfi ed Well a, i f s • III■ 4-12 Table 4-. Dominant copepod (adults), claoceran, and rotifer taxa and their percent composition (in parentheses) of the copepod, cladoceran and rotifer densities by location and sample period in Lake Norman in 2007. _ Locations MAY AUGUST OEM E2. FF�EB�RUARY pocyclops (5.6) Epishura (0.7) Tropocyclops (6.2)* Tropocyclops (7.2) 5.0 Epishura (2.9) Epishura (.) Tropocyclops (6 0)* Tropocyclops (. ) 9.5 Cyclops (.) Epishura (.4) Tropocyclops (.3)* Tropocyclops (1.2)*, 11.0 Tropocyclops (0.8) Epishura (2.7) Tr pocyclops (. )* Tropocyclops (5.6) 15.9 Cyclops (1.2) No adults Tropocyclops (4.6)* Tropocyclops (30.8) 2.0 Epishura (4.9) Epishura (8.2) Tropocyclops (5..1) Diaptomus (10,0) .0 Tropocyclops (10.8) Epishura (5.2) Tropocyclops (6.9) Tropocyclops (7.1) 9.5 Epishura (4.9) Tropocyclops (8.4)" Tropocyclops (2.2)* Tropocyclops (25.4) 11.0 Tropocyclops (1 A) Epishura (6.0) Tropocyclops (9.0) Diaptomus (12.8) 15.9 Cyclops (4.0) Diaptomus (1.8) Tropocyclops (7.6) Tropocyclops (17.1) 2.0 Bosmina (88.8) Diaphanosoma (38.) Bosminopsis (653) Bosmina (100.0) 5.0 Bosmina (88.2) Bosmina (61.3) Bosminopsis (64.6) Bosmina (98.7) .5 Bosmina (5.1) Diapanosoa (3.9) Bominosis (76.8) Bosmina (9.0) 11.0 Bosmina (98.7) Diaphanoso a (40.2) Bosminopsis (74.0) Bosmina (91.6) 15.9 Bosmina (86.5) Bosmina (92.0) Bosmina (60.9) Bosmina (97.4) 2.0 Bosmina (91.) Bosmina (57.2) Bosmina (42.8) Bosmina (93.1) 5.0 Bosmina (90.6) Bosmina (55.9) Bosminopsis (73.3) Bosmina (89.3) 9.5 Bosmina (94.3) Diaphanoso a (51.8) Bosminopsis (64.7) Bosmina (91.6 11.0 Bosmina (92.1) Diaphanosoma (49.3) Bosminopsis (65;6) Bosmina (58.5) 15.9 Bosmina (8.4) Bosmina (92.2) Bosmina (63.4) Bosmina (6.9) Only adults present in samples. 4-13 Table 4-. (Continued): Locations FEBRUARY MAY AUGUST NtVEMBER 2.0 Asplanchna (29.4) Keratella (34.3) Ptygura (38.3) P lyart ra (88.5) 5.0 Asplanchna (37.) Keratella (35.6) Ptygura (83.7) Polyarthra (91.1) 9.5 Asplanchna (80.3) Keratella (60.) Ptygura (76.8) Polyarthra (688) 11.0 Synchaeta (47.5) Keratella (3.1) Ptygura (60.9) Polyarthra (787) 15.9 Keratella (37.0) Keratella (51.5) Conochilus (84.) Polyarthra (760) 2.0 5.0 9.5 11.0 15.9 Polyarthra (78.8) Polyarthra (93.2) Polyarthra (61.0) Polyarthra (74.1) Polyarthra (75.3) Asplanchna (37.7) Conochilus (27.9) Ptygura (52.4) Keratella (4 .7) Conochilus (41.1) Ptygura (87.6) Asplanchna (62.7) Keratella ( 0.9) Ptygura (79.) Synchaeta (49.2) Keratella (38.7) Ptygura (69.) ; Keratella (41 ) Keratella (55.8) Cocochilus (79.2) 4-14 EPILIMNET'IC FEB w MAY AUG NO 400............ ............................... . .. E350 ----------------------------------------- ----- -- 50 --- ------------------------------------ --- . --- c200........................................ . - 150 100 50 ............. ......................... 2.0 5.0 9.5 11.0 1. Location WHOLE COLUMN FEB ' MAYAUGNOV 25 .... .....:............................... .... ...... a200 -------------------------------------------- --- X1 ------------------------------------ -------- 0 Z 100 y C 50 -- _.- ._------- .--®----------------------- cv 0 2.0 5.0 9.5 11.0 15. Location Figure 4-1. Total zooplankton density by location for samples collected in Lake Norman in 2007. 4-1 FEBRUARY MAY 400 - - 0 COPEP06§- -'- i dD&6&CkWj .... BROTIFERS 400-- -350 BRO IFERS E RJANS INCLADOCERANS D 0 C ...... 350 --L- 0 COPEPODS Co P E P 0 D - E ............... ..................... cp� 300 ................................ —1 250 ..................................... N-250 ................................ X 6200 ........................ ... . . X 6200 .......................... ................................ >-1150 ................. ... ... -150 .... ---------- ............ .................. ........ .... 100 ................. .. ... 100 ..... ..... ---------- ............ ........ ... . .... 50- ... ... 50 -- .... ... .... 0 - 2.0 5.0 M 11.0 15.9 2.0 5.0 M 11.0 15.9 Location Location AUGUST NOVEMBER 200 - 0C0=PEP0D--i—CD0iC—ERANS .... 200 OCOPEPODS NCLADOCERANS 175-MROTIFERS ... 175 MROTIFERS 150 ................. ................ 150 ..................................... 125 ................. ... ......... 125 ........................ x 100 .......... .... ... .... . 100 ........................ 75 ---------- .... ... ... .. 75 ........................ 50- - ... .. 50 ................. ... 25 ... ... .... .. .... 25 0 _j -1 ------ ---- 1 0 2.0 U 9.5 11.0 15�9 2.0 5.0 9.5 11.0 15.9 Location Location Figure 4-2. Zooplankton community composition by sample period and location for epilimnetic samples collected in Lake Norman in 2007. 4-16 MIXING ZONE LOCATIONS WINTER 225 --.................................... „ 20.....................:,........................_...........................__.. 175------------- ....... ............................................... ..:............. c ; 150_._.................................................._............................ x12 ............. ............................. ........................................... -„0 100 .............................................................. ........... 75.................... .......... .. ... . ...................... ........ ' 50 ...... .`................ ........ ....; ..... 5 t ...........,.................................. 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 0,4 05 06 07 Year BACKGROUND LOCATIONS 225 -...................................................... 200 .................................. .............................................. 75.......... .................. ............................. . 15... ......... ......... ..... ... .............. ......... ,.... .......... .. x125 .............. ............................ .... .. ............' ° 100 ........... ... ..... .. ................... _......._.... 75 .. ... .. c50 ........ ....... .................... ..... .................. `_.. 25 ................... .................. ........ ... ....- ................... 0 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 0607 Year Figure - . Total zooplankton densities by location and year for epilinmetic samples collected. in Lake Norman, NC, in the winter periods of 19 -- 2007. -1'7 MIXING ZONE LOCATIONS SPRING .............................................................. .0 5.0 200 ....................................................................... ........ -E 175 .................................................................. .... ....... 150 ----------- ...................... ......... -- ............. ............. x125 .................................................. ...... . ... ........ ... .. 6 z100 ..................... ...... .......... . ..... .. .... .. .......... ..... >, 75 -------- .. ............ ... . ... ..... .. ............. ............ .... 50 ... ........................... .............................................. 25 ................................................................................. 0- 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07 Year BACKGROUND LOCATIONS 600 ................................................... 500 ........................................................ ... .................... C> C> c> 400 .............................................. .... . .................. V- x 300 .. .......................................................... .... . ......... . A 200 ......................... .. ............... . ... ...... ...... .... CD100 -- - --------- . ... ..... ..... . . .... .... .. .. ........ 0 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07 Year Figure 4-4. Total zooplankton densities by location and year for epilinmetic samples collected in Lake Norman in the spring periods of 1988 — 2007. 4-18 MIXING ZONE LOCATIONS FALL 200 - - ............................................................. 175 ................................................................................ E lbu........................................................................... ... 125 .......................................................................... .. .. it C; 100----m ........................................................................... z75 . ... ................................................................... . ,�. I 50 '4 .... ........................ a ...... ........... .. ...... ....... .... 4) 25 -------- ... ...... .... . .... ..... . .............. 0 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07 Year BACKGROUND LOCATIONS 500 ............................................................................... [�9 11.0 1 �59 400 ................................................ .............................. C* x300 .............................................. . ........................ .... z200 .. .. ....................................... .... ........... .. ........ ... 100 --- ------- ----- ..... - - ---- .. ..... .... . .. .. ... ...... 0 J 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 06 07 Year Figure 4-6. Total zooplankton densities by location and year for epilimnetic samples collected in Lake Norman in the fall periods of 1987 — 2007. 4-20 MIXING ZONE: EPILIMNION C:3CgPE PLODS IN L DOCE NS ROTIFERS _ 90°la _ 80°lo 70°l - - - - 60 010 loll _ 4Olo 30°/a 20/0 _ 0% u� r. � 8 ra MIXING : WHOLE-COLUM 100 . . .. . . .. . . . . ,. . . . IM 90°l . . - - ® . .or . 30% _ . . . . . . . . 0° 60%! .. .. . . . . . . . . _ . . t7% 40% 30°!0 _ 20°l0 _ 1O1yo %0 rne,,C c : oa cr, a� cz� as cap as as cry , 0) 0) 0 (D r- V_ r- V" V_ V_ V_ r^ r- V_ c- r- N N N N N N N YEARS Figure -7. Annual percent composition of major zooplankton taxonomic groups from mixing zone locations (Locations 2.0 and 5.0 combined) during 1 — 2007 (Note: Dees not include Location 5.0 in the fall of 2002 or winter samples from 2005). 4-21 s Y i # # # # i e a ;1 i � � "� � ^� �► lye ; i •! .� •:: • •: s •: • w: • •-. • • • • rr • • • era s:: • •. • a: � s s s • • f a. s 4 • we ar t 120 .............. ....... ........ ........ .... ..... ...w .. ..., ... .wY.. ... a o. a M ° AYIAJl®�V Lrir+k. I.A�iY4dlLV V �1 tiSiNV.+ a p e d. : d b.. tl D # i # ♦ # 9 W ♦ b b R # ! # 100 # ..wwY ° w... # ..... ° .... ° .. ° .... ° .... ° .... .r ...w. ......,.......pw......,,....:.»wg..w.....,.w-.... .:�w ..:mow .�. •,w. .�,.. ,p�. ..,... .�. ..;,«. •:p. .�. e ♦ t. gwg j+p. b e R r : a a e x a , . e ... (� p # .,... l... w.wp.•ww« wi.•a>w+wwy... ...... w,y» w...yw..www. y�................... ww ww>.......................... p.. .p.. i # q # # d t. ® 5 # ® # M v. ! a # ! ♦ tl # i t i # A t 4 tl ® 6 tl. tl. ♦ 5 # y b b B t e t f :b .. ...m .... .a w + .................... ..awe .•w• .www.s . w a e a ! . w , a...e .. �r w w .... .. w tl w .. •: w « • � . • w .w t. w w . a .4 w. m � •w � v 6 YuVYs p 4 A # :e A tl M P. ! # t Y B t ♦ .t f fA F X X 4 y Y • i tl b Y. # B # v R b i q P e i 1 F Y 9 1 9 # f .. w . w r. ... .. • r. w w..w w warty w �.ww w w # K#Z M SI Figure - . Copepod densities during each season of each year a 2007 (mixing zone = mean of Locations .0 and .0;1 ons and Years ►ng epilimnetic samples collected in Lake Norman from 199 — kground =` can of Locations 9.5, 1 l .0, and 15.9). 60a......:............................•...... ..._ _. - ..... ............................... ..... s � r tl 50 -------- ....... ........ ........ .... . .... ..... .... ................ ............... ..... ....:e........ ....... L._...:w.....1.... .. .... .... .. .....L................. ... + P + C + A +- tl 4 i z... .L. ..Y. a.1 + . .k •r + + p + p e tl p p + + Y P A + 5 + 30 .. + V . ....�i..w....w .r.... •..r�.v .s. M. au «ametne .:. n..... ......... .... ...........«.... .. .... r a. . v t + ! + m k 'p tr 4 i B g Y ® 6 + + 9 f ® B + 0 0 0 + 9 `) f[t...... v............m.....wm.a.... ....a..aTm v1 «dr.w . w .. «.0 + + tl .g 0 q+ i + +� ++�� a� Q�..C� C."P� � '^�Ty �" 6"`{'�� �..i CL � ""� a... � '+�. . � ..d.. fli ..11� M-.i �".�v. .' „�.a �.� ... .Y�' r. * rwcn uua '+ sus s v� u� LL en u vs m �' ua crs °i ux r, v u� ry � r ua � va rn a cn vs va °' W 2 U vs " r ua S en us " 1990 1991 1992 1993 1994 1996 1996 199T 1996 1999 2000 2001 2002 2003 2004 2005 2006 2007 Seasons and Years Figure -10. Cladoceran densities during each season of each year among epilimnetic samples collected in Lake Norman from 1990 2007 (mixing zone = mean of Locations 2.0 and 5.0; background = mean of Locations 9.5, 11. , and. 15.9). 350 250 0 X Ci 150 100 — —MIXING 6N KG t�UNC LQC ` IONS ...... ..........:.. ....,....... ..... . ................ :....._ ...... ........ ...b.... .8...... ,. °....:,.a...:. .°.._....�.,. ...•..® .. ......a . ......ti..... ......:.... ..a.. ... ... .... ti.... ..... ; 1990 ' 1991 1 1992 1 1993 1 1994 1 1995 1 1996 1 1997 1 1998 1 1999 1 2000 1 2001 1 2002 1 2003 I 2004 1 2006 1 2006 1 2007 Seasons and Years Figure -11. Rotifer densities during each season of each year among epilimnetic samples collected in Lake Norman from 1990 — 2007 (mixing zone = mean ofLocations 2.0 and 5.0; background = mean of Locations 9.5, 1`1.0, and 15.9). v, CHAPTER 5 FISHERIES INTRODUCTION In accordance with the NPDES permit for McGuire Nuclear Station ( S) and associated requirements ftom the North Carolina . Wildlife Resources Commission (NCWRC), monitoring of specific fish population parameters in Lake Norman continued during 2007. The components of this program were: 1. spring electrofishing survey of littoral fish populations with emphasis on age, growth, size distribution, and condition of spatted bass and largemouth bass; fall electrofishing survey to assess largemouth and spotted bass young -of -year abundance; 3. summer striped bass mortality surveys; 4. winter striped bass gill net survey with the NCWRC with emphasis on age, growth, and condition; . fall hydroacoustic and purse seine surveys of pelagic fish abundance and species composition; . fall crappie trap -net survey with the NCWRC with emphasis on age and growth. METHODS AND MATERIALS Spring Electrofishing Survey A spring electrofishing survey was conducted in March and April at three locations: (1) near Marshall Steam Station (MSS) in Zone 4, (2) a reference (REF) area located between een McGuire Nuclear Station S) and MSS in Zone 3, and (3) near MNS in Zone I (Figure - 1). The locations sampled in 2007 were identical to historical locations sampled since 1993 and consisted of ten 300-m shoreline transacts at each location. Tra sects included habitats representative of those found in Lake Norman. Shallow fiats where the boat could not access within 3-4 rn of the shoreline were excluded. All sampling was conducted during daylight, when water temperatures were expected to be between 15 and 20 °C. All stunned fish were 5-1 collected and identified to species (scientific names of fish collected are listed in Table -1). Fish were enumerated and weighed in aggregate by taxon, except for largemouth and spotted ass, where total lengths ( n) and weights () were obtained for each individual collected. Sagittal otoliths were removed from all bass > 125 mm, long (bass < 125 nun were assumed to be age 1 because young -of -year bass are historically not collected in spring samples) and sectioned for age determination (Devries and Frie 1996). Growth was calculated with the mean length for all fish of the same age. Condition based on relative weight was calculated for largemouth bass >150 turn long and spotted bass >100 mm long, using the formula Wr (W x 100, where W — weight of the individual fish (g) and Ws = length -specific mean weight (g) for a fish as predicted by a length -weight equation for that species (Anderson and Neumann 1996), Fall Electrofishine Survevsfor Youne-of-Year Bass A fall electrofishing survey was conducted in November at the same three locations as the spring survey and consisted of five 300-m shoreline transects at each location. Again, shallow flats where the boat could not access within 3-4 m. of the shoreline were excluded. All stunned bass were collected, identified to species, and individually measured and weighed. A year class "cut off" of 150 mm was determined for all black bass by examining length -frequency data. Summer Strined Bass Mortalitv Survevs Mortality surveys were conducted weekly during July and August to specifically search for dead or dying striped bass in Zones 1-. All observed dead striped bass were collected during these surveys and their location was noted. Individual total lengths were measured prior to disposal. Striped Bass Netting u g Striped bass were collected for age, growth, and condition (Wr) determinations in early December by Duke Energy (DE) personnel. Four monofila ent nets (76.2 m, long x 6.1 m deep), two each containing two 3 8. 1 -m panels of 3 8- and 5 1 -imn square mesh and two each containing 3'8.1-m panels of 6- and 76-mm square mesh, were set overnight in areas where striped bass were previously located. Individual total lengths and weights were obtained for 5- all striped bass collected. Sagittal otoliths were removed to determine age, growth, and condition ( r), as described previously for largemouth bass. Additionally, all catfish collected were identified and enumerated by species. Fall Hydroacoustics and Purse Seine Surveys The abundance and distribution of pelagic prey fish in Lake Norman were determined using mobile hydr acoustic (Brandt 1996) ' d purse seine (Hayes et al. 1996) techniques. The lake was divided into six zones (Figure 5-1) due to its large size and spatial heterogeneity. mobile hydroacoustic survey of the entire lake was conducted in mid -September with multiplexing, side- and down -looking transducers to detect surface -oriented fish and deeper fish (Prom 2.0-m depth to the bottom), respectively. Both transducers were capable of determining target strength directly by measuring fish position relative to the acoustic axis. Purse seine samples were also collected in mid -September from the do lake (Zone 1), idlake Gone 2), and u lake (Zone 5) areas of the reservoir. The purse seine measured 118 9 m with a mesh size of 4.8 mm. A subsample of forage fish collected from each area was used to estimate taxa composition and size distribution. Crappie Trap -Net Survey Duke Energy personnel provided logistical; support to the NCWRC during Lake Norman crappie population sampling in early November as described by Nelson and Dorsey (2005). Crappie were collected with trap nets, identified to species, measured for individual total length and weight, and saittal otoliths were removed for age and growth determinations. RESULTS DISCUSSION Sprig Electrofishing Surveys Electr fis i g was conducted at water temperatures ranging from 14.6 to 20.0 'C. One thousand three hundred forty fish (19 species and two hybrid complexes) weighing 125.3 k were collected in the MSS area, 1,673 fish (0 species and two hybrid complexes) weighing 77.8 kg in the REF area, and 1563 fish (12 species andone hybrid complex) weighing 50.6 5- kg in the MNS area (Table 5-). Overall,; bluegill dominated samples numerically, white common carp, largemouth bass, and spotted bass dominated samples gravi etricaly. Total numbers of fish collected in spring 2007 were highest in the REF area, intermediate in the MNS area, and lowest in the MSS area (Figure -2). There is no apparent trend in the number of fish collected within or among areas since 1993. Total biomass of fish was highest in the MSS area, intermediate in the REF area, and lowest in the MNS area, following the trend of previous years. This ;spring trend in Lake Norman fish biomass supports the spatial heterogeneity theory noted by Suer et al. (156). The authors reported that fish biomass was higher uptake than do lake; due to higher levels of nutrients and resulting higher productivity uptake versus downlake. The spatial heterogeneity theory; is further supported by higherconcentrationsof chlorophyll a, greater phytoplankton standing craps, and elevated epilinmetic zooplankton densities in uptake compared to do lake regions of Lake Norman (Chapters 3 and 4). Spotted bass, thought to have originated from angler introductions, were first collected in Lake Norman in the MNS area during a 2000 fish health assessment survey. They have increased in numbers and biomass since 2001 spring electrofishing samples (Figure 5-3) and, in 2007, were most abundant in the MSSarea, intermediate in the REF area; and least abundant in the MNS area. Biomass was highest in the MNS area, intermediate in the REF' area, and lowest in the MSS area. n 2007, small spotted bass (< 150 ) dominated the black bass catch in all areas sampled: (Figure 5-4), and their growth was generally similar among all areas sampled (Table -3). Spotted bass Wr ranged from 6.4 for fish 0-149 runi long in the NWS area to 55.5 for fish 0-399 min long in the MSS area (Figure 5-5). Overall, spotted bass Wr values were highest in the MSS area (75.3), intermediate in the REF,area (7.1), and lowest in the MNS area (71.6); a decrease relative to 2006 values SS=77.2, REF 80.7, S=77.4) and' within the range of observed historical values (71.-52.3) (Duke Power unpublished data, 2004, 2005; Duke Energy 2006, 2007). Relative to 2006, 2007 largemouth bass numbers increased slightly in the REF and MNS areas and decreased slightly in the MSS area (Figure5-6). Largemouth bass biomass increased in the MSS and REF areas and decreased in the MNS area. Numbers and biomass ass values at all locations were generally similar to 2006, the lowest recorded since sampling 5- began in 1993. As in most years, 2007 largemouth bass numbers and biomass were highest in the MSS area, intermediate in the REF area, and lowest in the NMS area. Since 2000, largemouth bass >300 mm dominated -the catch in all three sampling areas (Duke Power 2001, 2002, 2003 2004, 2005 Energy 2006), with largemouth bass < 150 mm, low in abundance. An exception was in 2006, where a high abundance of largemouth bass < 150 mm occurred in the MSS area (Duke Energy 007). In 2007, largemouth bass >00 were relatively abundant, but not dominant (Figure 5-4) There was no trend in largemouth bass growth among areas in 200 (Table -3) however, largemouth bass mean lengths for ages 2, 3 and 4 were generally higher beginning in 2003, relative to historical data (197 — 78, 1993, and 1994)( able 5-4). While displacement of largemouth bass since the introduction of spatted bass in the louver lake is apparent, the direct effect on largemouth bass recruitment is indeterminate, possibly due to confounding effects of other introductions including alewife and white perch (Kohler and Ney 1980, Madenian et al. 2000). Largemouth bass Wr ranged from 791 for Fish 200-249 mm long to 89.9 for fish 00-349 m long, both in the REF area (Figure 5- ). Overall, largemouth bass Wr values were highest in the MNS area (84.8) intermediate in the MSS area (84.6), and lowest in the REF area (82.5); a decrease relative to 2006 values ( = 6. , MSS=87.2, F=88.0) and `thin the range of observed historical values (76.0-89.9). (Duke Power unpublished data, 2004, 2005; Luke Energy 2006, 2007). Fall 207 electrofishing resulted in the colle, young -of -yeas (< 10 m), compared to 95 sl spotted and 20 largemouth bass in 205 (Figs year were collected in 2007. As in 2005 and highest in the MSS area. # f i e" is r., II• . r ��' Iles r � •' •� •- - 5-5 Summer Strined Bass Mortalitv Survevs In 2007, a total of 13 dead striped bass were collected during the July -August surveys (Table 5-5). Since the survey began in 1983, summer mortalities in excess of 25 dead striped bass occurred in three years: 163 in 1983, 43 in 1986, and 2,610 in 2004. Striped Bass Netting Survey Dominated by age I and age 2 fish, 181 striped bass were collected in early December 2007 (Figure 5-8). Striped bass growth was fastest through age 3 and slowed with increasing age. Additionally, mean Wr was highest for age I fish and declined with age. Mean Wr was 79.5 for all striped bass in 2007, within the range of observed historical values (78.5-84. 1). Growth and condition in 2007 were similar to historical values since consistent gillnetting began in 2003 (Duke Power 2004, 2005; Duke Energy 2006, 2007). The December striped bass gillnetting also yielded 76 catfish. Blue catfish (63) dominated the catch, followed by flathead catfish (11), and channel catfish (2). Fall Hvdroacoustics and Purse Seine Average forage fish densities in the six zones of Lake Norman ranged from 1,338 (Zone 1) to 13,421 (Zones 5 and 6) fish/ha in September 2007 (Table 5-6). Zone 6 fish densities were assumed to be the same as Zone 5, as the shallow nature of the riverine Zone 6 limits habitat available for acoustic sampling. The lake -wide population estimate in September 2007, approximately 72 million fish, was within the range of annual estimates since 1997 and well above the lowest estimate of 47.1 million recorded in 2004 (Figure 5-9). As in most years since 1997, Zone 5 had the highest forage fish density estimates. No temporal trends are ® in potagic j�isn ip*p1j-iau*r Purse seine sampling in 2007 indicated hydroacoustics was comprised of 98.3% thre 2006, no gizzard shad were collected in the of threadfin shad was between 41 and 45 rm low numbers in 1999 and increased to , community by 2002. The percent compo,, 5-6 increasing to approximately 5.1 % in 2006, and dawn to 1 7% of the forage fish catch in 2007. The overall increase and subsequent decrease in the percent composition of alewife was concurrent with an increase in the threadfin shad modal length class and subsequent decrease to values measured prior to the alewife introduction. Crappie Trap -Net Study In 2007, NCWRC personnel set 90 overnight trap -nets in Lake Norman. They collected`350 black crappie and 24 white crappie. Various life history data were collected for use in fish management decisions. FUTURESTUDIES In addition to the 2007 Lake Norman Monitoring Program surveys, DE will conduct biennial fall trap -net surveys with the NCWRC for crappies, with emphasis on age and growth. Additionally, DE will conduct purse seine sampling in late June/early July 2008 to assist NCWRC in evaluating the changing forage fish conununity. These changes were approved by NCWRC in a letter dated March 7, 2008. SUMMARY In accordance with the Lake Norman Maintenance Monitoring Program for the MNS NPDES permit, specific fish monitoring programs continued during 2007. Spring ele trofishing indicated that 12 to 20 species of fish and two hybrid complexes comprised fish populations in the three sampling areas, and numbers and biomass of fish in 2007 were generally similar to those noted annually since 1993. Largemouth bass, numbers and biomass continue to decline in recent years and the 2007 numbers and biomass were some of the lowest recorded =since sampling began in 1993. During 2007, the number of summer striped bass mortalities (13) and winter mean relative weight (79.5) were similar to those of previous years. Hydroacoustic sampling estimated a forage fish population of approximately 72 million in 2007, co parable to previous years. After an increase in 2006, purse seine sampling indicated a decrease in the percentage of alewives in 207 to the lowest percent composition since their 1999 introduction. During 2007, threafin shad lengths remained at pre -alewife introduction sizes: 5-7 Table 5-1. Common and scientific names of fish collected in Lake Norman, 2007. RIN Mill 5-8 Table 5-2. Numbers and biomass of fish collected from electrofishing ten 300-m transects each, at three areas (1\4SS, REF, MNS) in Lake Norman, March/April 2007. MSS REF MNS Taxa No. kg No. kq No. Gizzard shad 9 3.93 10 4.89 1 0.49 Threadfin shad 292 1.75 Greenfin shiner 1 < 0.01 1 < 0.01 7 i 0.02 Whit fin shiner 43 0.27 20 0.08 Common carp 20 52.60 5 11.80 5 11.27 Bluehead chub 1 < 0.01 Golden shiner 2 0.01 1 < 0.01 Spottail shiner 14 017 42 0.30 2 0.01 Quillback 1 0.30 Blue catfish 1 2.25 Channel catfish 8 2.80 4 1.34 2 0.72 Flathead catfish 1 0.38 5 2.30 White perch 1 0.02 Redbreast sunfish 139 2.89 392 5.72 240 4.03 Green sunfish 51 0.81 2 0.02 Warmouth 23 0.19 52 0.30 26 0.17 Bluegill 713 8.08 895 7.88 830 7.72 Redear sunfish 113 10.93 98 8.12 51 4.18 Hybrid sunfish 63 1.71 40 0.73 30 0.73 Spotted bass 72 7.39 62 11.94 60 13.68 Largemouth bass 55 29.58 31 17.09 17 5.86 Hybrid black bass 5 1.92 3 0.50 Black crappie 5 1.64 5 2.21 Tessellated darter I < 0.01 2 < 0.01 Yellow perch 1 < 0.01 Total 1340 12534 1673 77.81 1563 50.62 Table 5-3. Mean total lengths (mm) at age for spotted bass (SPB) and largemouth bass (LMB) collected from electrofishing ten 300-m transects each, at three areas (MSS, REF, MNS) in Lake Norman, March/April 2007. !A2e Taxa Location 1 2 3 4 5 6 7 8 9 10 11 SPB MSS 192 287 344 401 REF 175 307 378 421 410 MNS 193 314 389 390 LMB MSS 215 261 363 394 418 412 463 411 465 436 REF 186 285 371 367 369 429 466 MINIS 355 402 433 382 382 Table -. Comparison of mean total length (mm) at age for largemouth bass collected from electrofxshin ten -m transects, each, at three areas (MSS, REF, MNS) in Lake Norman, March/April 2007, to historical largemouth bass mean lengths. Acme Location and year 1 MSS 1974-78" 170 266 310 377 MSS193a 170 277 314 38 MSS 1994b 164 273 308 332 MSS 20030 216 317 349 378 MSS 2004d 176 309 355 367 MSS' 2005" 190 314 ' 358 396 MSS 2006f ' 14 347 346 408 MSS 2007 215 261 363 394 REF 1993b 157 242 279 330 REF 1994b 155 279 326 344 REF 20030 139 296 358 390 REF 2004' 143 288 364 415 REF 20050 139 307 357 386 REF 2006' 180 300 363 378 REF 2007 186 285 371 367 MNS 1971.78a 134 257 325 376 MNS' 1993b 176 256 316 334 MNS 19 4b 169 256 298 347 MNS 20030 197 315 248 389 MINIS 2004' 170 276 335 370 MNS 2005e 136 342 359 429 MNS' 2006f 169 308 361 402 MNS 2007 < 355 402 43 s Siler 1981; b Duke Power unpublished data; C duke Power 2004a; d Duke Power 200; e Duke Energy 2006; f Duke Energy 2007 -10 Table '5- . Striped bass mortalities observed in Lake Norman during weekly surveys during " July and August 2007. Date Number Zone Total length m Jul 5 1 56:,602 4 464, 582, 590 Jul 9 2 2 550 4 520 Jul 3 1 2 583 Aug 6 3 1 572,580 4 586 Aug 30 2 1 608 3 465 Table 5-6. bake Norman forage fish densities (number/hectare) and population estimates from hydroacoustic surveys in September 2007. Zone No,/ha Population Estimate 1 1,338 3,062,55 2 3,176 9,789,539 3 5,61 18,871,072 4 4,531 5,577,740 5 13,421 28,264,588 6 1,421 a 6,415,229 LakeWde total 71,970,725 95% Cl 65,300,347 — 78,641,103 Zone 6 fish density was assumed to be the same as Zane 5 5-11 Table 5-7. Total numbers and percent composition of forage fish, and modal length class of thread fin shad collected in purse seine samples from Lake Norman during late summer/fall, 1993 — 2007. ---- ------ ------ Species Composition Threadfin shad modal Year No. Threadfin Gizzard Alewife ten class mm 1993 13,063 100.00% 0.000/0 0.00% 31-35 1994 1,619 99.94% 0.06% 0.00% 36-40 1995 4,389 99.950I 0.050/0 0.00% 31-35 1996 4,465 100.00% U00/0 0.00% 41-45 1997 6,711 99.99% 0.01% OM% 41-45 1998 5,723 99.95% 0.050/0 0M% 41-45 1999 5,404 99.26% 0.26% 0.48% 36-40 2000 4,265 87.40% 0.22% 12.37% 51-55 2001 9,652 76A7% 0.01% 2152% 56-60 2002 10,134 74.96% 0.000/0 25.04% 41-45 2003 33,660 82,59% 0.14% 17,27% 46-50 2004 21,158 86.55% 0.24% 1120% 51-55 2005 23,147 98.10% 0.000/0 1.90% 41-45 2006 14,823 94.87% 0.000/0 513% 41-45 2007 27,169 98.34% 0.000/0 1.66% 41-45 5-12 Electrofishing locations Purse seine locations Zone is Zone arshMl »' Steam t� Zone c_ gone 2 Zone z t «a Zone 1 1 3 files Covens FCC �^ ut' Nuclear tafiD Figure, 5-1. Sampling locations and zones associated with fishery assessments in Lake Norman. -1 3500 ® MSS REF a 3000 2500 2000 w. 1500 ri 1000 500 0 bear 387 00 MSS 180 ; RE IONS 160 0 120 100 8o M 0 40 0 0 c- t- r V- Year Figure 5-2. Total a) number and b) biomass of fish collected from electrofishing ten 300- transects each, at three areas (MSS, REF, ) in Labe Norman, 193 — 1997 d 199 — 2007 -14 , 140 MSS a 120 REF o MNS - 100 80 60 u� U- 40-- 20-- 0- —,Jim — 2001 2002 2003 2004 2005 2006 2007 Year 1' MSS 16 F 14 o MNS 12 10 ra u- 6 4 2 0 2001 2002 2003 2004 2005 2006 207 Year Figure 5-3. Total a) number and b) biomass of spatted bass collected from electrofishing ten 300-m transects each, at three areas (MSS, REF, S) in Lake Norman, 2001 — 2007. 5-15 45 MSS 40 RED p MNS 35 30 25 VT 20 '1 1 t7 son <150 150-199 ; 200-249 250-2 300-34 '35 -399 400-449 >450 Length group (mm) 15 MSS REF MN 12 CIII 6- -LC 3 il 0-41 I --A <150 15 -199 200- 49 50-299 300- 49 350-399 00 >450 Length group ( m) Figure -4. Size distributions of a) spotted bass and b) largemouth bass collected from electrofisig ten 300-m transects each, at three areas SS, REF, S) 1n Lake Norman, 2007. 5-1 )-149 150-199 200- - 00- Q-x Length group (mm) MSS REF; MS 300 MSS ■ REF 0 c3 MNS 200 "� 10 0 u- 100 50 0 CN Year 70 MSS RED 60 ❑ MNS 0 40 MO U. 0 10 0 Year Figure - . Total a) number and ) biomass of largemouth bass collected from electrofishin ten 300-m transects, each, at three areas ' SS, REF, ) in Lake Norman, 1 -1997 and 1999 — 2007. _1 120 Spotted bass ■ Largemouth bass 100 o Hybrid bass 60 60 40 20 0 2005 2006 2007 Year .Figure 5-7. Total number of young -of -year black bass collected from l trofishln live 00- transects each, at three areas (MSS, REF, S) in Lake Norman, 2005 — 200 700 650 TL 90 500 i 60 00 75 F- 450 70 400 65 350 00 ' ' ` ' 60 1 2 3 4 5 5 7 8 Age Figure5-8. Mean total length and mean relative weight (Wr) for striped bass collected ftorn Labe Norman, December 2007. Numbers of fish associated with mean length are inside bars, 5-1' 1 oo -,� e- 90 X-- 5 r- s -- lakeide 80 70 60 50 40 30 20 10 ""- 0 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 Year Figure-9. Zonal and lake -wide population estimates of pelagic forage fish in Lake Norman, 1997 —2007. 500 450 ci 40 350 300 2"50 200 150 100 50 0 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Length group (mm) Figure -10. Number and size distributions of threadfin shad (TF) and alewives (.ALE) collected in purse seine surveys of Lake Norman, 2007. -0 LITERATURE CITE American Public Health Association (APHA). 1995. Standard Methods for the Examination of Water and Wastewater. 19t' Edition. APHA. Washington,DC. Anderson, RA, and RM Neumann. 1996. Length, weight, and associated structural indices. Pages 447-482 in BR Murphy and DW Willis, editors. Fisheries Techniques. American Fisheries Society. Bethesda, Brandt, SB. 1996. Acoustic assessment of abundance and distribution. Pages 85-432 in BR Murphy and DW Willis, editors. Fisheries Techniques. American Fisheries Society. Bethesda, MD: Cole, TM, and HH Hannan. 1985. Dissolved oxygen dynamics. in Reservoir Li ` ology: Ecological Perspectives. KW Thornton, BL Kimmel and FE Payne, editors. John: Wiley & Sans, Inc. New York, Coutant, C. 1985. Striped Bass, Temperature, and Dissolved Oxygen.: A Speculative Hypothesis for Environmental Risk. Transactions of the American Fishery Society. 114:31- 1, Derwort, JE. 1982. Perihyton Pages 279-14 in JE Hogan and WD Adair, editors. Lake Norman Summary, Volume II. Dube Power Company, Technical Report DUKE PWRJ8-. Duke Power Company, Production Support Department, Production Environmental Services. Huntersvill, NC. Devries, DR, and RV Frie. 1996. Determination of age and growth. Pages 48-512 in BR Murphy and DW Willis, editors. Fisheries Techniques. American Fisheries Society. Bethesda, MD. Duke Energy. 2006. lake Norman Maintenance Monitoring Program. 2005 summary. Duke Energy Corporation. Charlotte; NC. Duke Energy. 2007. Lake Norman Maintenance Monitoring Program: 2006 summary. Duke Energy Corporation. Charlotte, NC. Duke Power. 1997. Lake Norman Maintenance Monitoring Program. 1996 summary. Duke Energy Corporation. Charlotte, NC. Duke Power. 1998. Lake Norman Maintenance Monitoring Program: 1997 summary. Duke Energy Corporation. Charlotte, NC. Duke Power. 1999. Labe Norman Maintenance Monitoring Program: 1998 summary. Duke Energy Corporation. Charlotte, NC. L-1 Duke Power. 2000. Lake Norman Maintenance Monitoring Program.: 1999 summary. Duke Energy Corporation.. Charlotte, NC. Duke Power. 2001. Lake Norman Maintenance Monitoring Program: 2000 summary. Duke Energy Corporation. Charlotte; NC. Duke Power. 2002. Lake Norman Maintenance Monitoring Program: 21 summary. Duke Energy Corporation. Charlotte, NC, Duke Power. 2003. Lake Norman Maintenance Monitoring Program: 2002 summary. Duke Energy Corporation. Charlotte, NC. Duke Power. 2004a. Lake Norman Maintenance Monitoring Program: 2003 summary. Duke Energy Corporation. Charlotte, NC. Duke Power. 20. McGuire Nuclear Station. Updated Final Safety Analysis Report. Duke Energy Corporation. Charlotte, NC. Duke Power. 2005. Lake Norman Maintenance Monitoring Program: 2004 summary. Duke Energy Corporation. Charlotte, NC. Duke Power Company. 196. McGuire Nuclear Station, Units 1 and 2, Environmental Report, Operating License Stage. 6th rev. Volume 2. Duke Power Company. Charlotte, NC. Duke Power Company. 1985` McGuire Nuclear Station, 316(a) Demonstration. Duke Power Company. Charlotte, NC. Duke 'Power Company. 1987. Lake Norman Maintenance Monitoring Program: 1986 summary. Duke Power Company. Charlotte, N. Duke Power Company. 1988. Lake Norman Maintenance monitoring program: 17 summary. Duke Power Company. Charlotte, NC. ;Duke Power Company. 1989. Lake Norman Maintenance Monitoring Program: " 1988' summary. Duke Power Company. Charlotte, NC. Duke Power Company. 1990. Lake Norman Maintenance Monitoring Program: 1989 summary. Duke Power Company. Charlotte, NC. Duke Power Company. 1991. Lake Norman Maintenance Monitoring Program: 1990 summary. Duke Power Company. Charlotte, NC. Duke Power Company. 1992. Lake Norman Maintenance Monitoring Program: 191 summary. Duke Power Company. Charlotte, NC. L-2 Duke Power Company. 1993. Lake Norman Maintenance Monitoring Program: 1992 summary. Duke Power Company. Charlotte, NC. Duke Power Company. 1994, Lake Norman Maintenance Monitoring Program: 1993 summary. Duke Power Company. Charlotte, NC: Duke 'Power Company. < 1995. Lake Norman Maintenance Monitoring Program, 1994 summary. Duke Power Company. Charlotte, NC. Duke Power Company. 1996. Lake Norman MaintenanceMonitoring Program: 199 summary. Duke Power Company. Charlotte,NC. Ford, DE. 1985. Reservoir transport processes. in Reservoir li ology: ecological perspectives. KW Thornton, BL Kimmel and FE Payne, editors. John Wiley & Sons, Inc. New York, Ha me, RE. 1982. Zooplankton. Pages 323-353 in JE Hogan and WD Adair, editors. Lake Norman Summary, Technical Report DU PWR/82-2. duke Power Company. Charlotte, NC. 40 p. Hannan, HH, IR Fuchs, and DC Whittenburg. 1979. Spatial and temporal patterns of temperature, alkalinity, dissolved oxygen and conductivity in an oligo-mesotrophic deep -storage reservoir in Central Texas. Hydrobiologia 51 (30).209-221.. Hayes, DB, CP Ferrier, and WW Taylor. 1996. Active fish capture methods. Pages 19-220 in BR Murphy and DW "Willis, editors. Fisheries Techniques. American Fisheries Society. Bethesda:, MD. Higgins, JM and BR Kim. 1981. Phosphorus retention models for Tennessee Malley Authority reservoirs. Water Resources Research. 17:571-576. Higgins, JM, WL Poppe, and ML Iwanski. 1980. Eutrophication analysis of TVA reservoirs. Pages 412-423 in Surface Water Impoundments. HG Stefan, editor. American Society of Civil Engineers, New York, Hutchinson, GE 1938, Chemical stratification and lake morphometry. Proceedings o National Academy of Sciences. 24:63-69. Hutchinson, GE 1957. A Treatise on Limnology, Volume I. Geography, Physics and: Chemistry. John Wiley& Sons, Inc. New York, Hutchinson; GE. 1967. A Treatise on Li ` ology. Volume U. Introduction to Lake Biology and the Limnoplankton. John Wiley & Sons, Inc. New York, NY. 1115 p'. Hydrolab Corporation. 2006. Hydrolab DS5X, DS5 and MS5 water quality multiprobes. Users manual. February 2006, Edition 3. 71 p. Kohler, CC and JJ Ney, 1980. Piscivority in a land -locked alewife (Alosa pseudoharengus) population. Canadian Journal of Fisheries and Aquatic Sciences. 37 1314-1317. Lee, RE. 1989. Phycology (d edition). Cambridge University Press. 40 West 20th. St., New York, Madenjian, CP, RL Knight, MT Bur, and JL Forney. 2000. Reduction in recruitment of white bass in Lake Erie after invasion of white perch. Transactions of the erican Fisheyes Society. 129:1340-1353. Matthews, WJ, LG Hill, DR E ds, and FP Gelwick. 1985. Influence of water quality and season on habitat use by striped bass in a large southwestern. reservoir. Transactions American Fishery Society. 118:243-250. enhini k, EF and. LD Jensen. 1974. Plankton populations. Pages 120-138 in LD Jensen, editor, Environmental responses to thermal discharges from Marshall Steam Station, Lake Norman, North Carolina. Electric Power Research Institute, Cooling Water Discharge Research Project -4) Report N. 11. Johns Hopkins University. Baltimore, MD. 235 p. Mortimer, CH. 1941. The exchange of dissolved substances between mud and water in lakes (Parts I and 11). Ecology. 29280-329. Nelson, C, and L Dorsey, 2005. Population characteristics of black crappies in Lake Norman 2004Survey Report, Federal Aid in Fish :Restoration Project F-23- . North Carolina Wildlife Resources Commission. Raleigh, NC. North Carolina Department of Environment and Natural Resources, Division o Environmental Management (DEM), Water Quality Section.. 1991. 190 Algal Bloom Report. North Carolina Department of Environment and. Natural Resources. 2004. Red. Book. Surface Waters and Wetland Standards. NC Administrative Code. 15a NCAC 02B.100 .0200 and .000. August 1, 2004, 133 p. Petts, GE. 1984. Irnpounded Rivers: Perspectives for ecological management. John Wiley Sons, Inc. New York, NY, 326 p. Rodriguez, MS. 1982. Phytoplankton. Pages 154-260 in JE Hogan and WD Adair, editors, Lake Norman summary. Technical Report DU P ' 82-02 Duke Power Company. Charlotte, NC: L- Siler, JR 1981. Growth of largemouth bass, bluegill, and yellow perch in Lake Norman, an, North Carolina - A summary of 1975 through 1979 collections. Research Report PES/81- . Duke Power Company. Huntersville, NC. Siler, JR, WJ Foris, and MC clne'' y. 1986. Spatial heterogeneity in fish parameters within a reservoir. Pages 122-1 6 in GE Hall and MJ Van Den Avyle, editors. Reservoir Fisheries Management: Strategies for the <0's. Reservoir Committee, Southern Division American Fisheries Society. Bethesda, oball , DM, BL Kimmel, RH Kennedy, and'RF Gaugish. 1992. Reservoirs. in Biodiversity of the southeastern United States aquatic communities. John Wiley Sons, Inc. New York, turn, W and JJ Morgan. 1970. Aquatic chemistry; An introduction emphasizing chemical equilibria in natural waters. John Wiley & Sons, Inc. New York, NY. 583 p. Thornton, KW, BL Kimmel, and FE Payne. 1990. Reservoir limnology. John Wiley & Sons,, Inc. New York, NY. U.S. Enviro ` entl Protection Agency (USEPA). ;'1983. Methods for the Chemical Analysis of Water and "Wastes. Environmental Monitoring and Support Lab, Office o Research and Development. Cincinnati, OH. U.S. Enviromnental Protection Agency (USEPA).' 199a. Quality assurance project plans. Technical Report. EPA QA/G-5. U.S. Environmental Protection Agency (USEPA). 198b. EPA requirements for quality assurance project plans for environmental data. Technical Report. EPA Q -5. United States Geological Survey. 1998. National field manual for the collection of water quality data. United States Geological Survey. TRI Book 9. 939 p. United States Geological Survey. 2002. Policy for the evaluation and approval of analytical laboratories. Office of Water Quality. Technical Memoranda 2002.05. Wetzel, RG. 1975. Limnology. WB Saunders Company. Philadelphia, P. 743 p. L- N%N A Michael F. Easley, Governor William G, Ross Jr,, Secretary North Carolina Department of Environment and Natural Resources Coleen Sullins, Director Division of Water Quality October 22, 2007 Ms. Lee N. Williams MGOIEM 12700 Hagers Ferry Road Hut-itersville, NC 28078 Subject: Compliance Evaluation Inspection Toxicity Sampling Results McGuire Nuclear Power Plant NPDES Permit No. NCO024392 Mecklenburg County, North Carolina Dear Ms. JarTell: Enclosed please find a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on September 18, 2007 iby Ms. Donna Hood of this Office. Please inform the facility's Operator -in -Responsible Charge of our findings by forwarding a copy of the enclosed report. The report should be self-explanatory; however, should you have any questions concerning this report, please do not hesitate to contact Ms. Hood or me at (704) 663-1699, Sincerely, f NoOr Robert B. Krebs Surface Water Protection Regional Supervisor Enclosure cc: Rusty Rozelle, MCWQP DH AM NUMNA N, C. Division of Water Quality, Mooresville Regional Office, 610 East Center Avenue, Suite 301, Mooresville NC 28115 (704) 663-1699 Customer Service 1-977-623-6748 United States EnvironmentalProtection Agency Form Approved. EPA Washington, J.C. 20460 OMB No. 2040-0 Water Compliance Insoection Report Approval expires Section A.- National Data System Coding (i,e,, PCS) Transaction Code NPDES yr/nno/day Inspection Type Inspector 1 UN, 2 Us 31 NCO024392 Ill 121 07/09/18 117 181'U 1 19L61 Remarks 211 Inspection Work Days Facility Self -Monitoring Evaluation Rating B1 QA ----Reserved 671 2.0 169 70L51 71U LNI 72731 1 174 75L Section B: Facility Data Name and Location of Facility inspected (For Industrial Users discharging to POTW, also include Entry Time/Date Permit Effe POTVV name and NPOES permit Number) McGuire Nuclear Power Plant 10:00 AM 07/09/18 06/c NC Hwy 73 Exit Time/Date Permit Exp Huntersville NC 28078 12:45 PM 07/09/18 10/c Name(s) of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Charles Anthony Bynum/ORC/704-875-4107/ Lee N Williams/Environrriental Health Mnager Safety and/704-V8-5894 Name, Address of Responsible Official/Titte/Phone and Fax Number John C Williamson,12700 Pagers Ferry Rd Hunteroville NC Contacted 28078//704-875-5894/ No Section C' Areas Evaluated During Inspection (Check only those areas evaluated) P Permit a Flow Measurement 0 Operations & Maintenance 0 Records/Reports Self -Monitoring Program 0 Effluent/Receiving Waters 0 Laboratory Section D: Summary of Findinq/Comments (Attach additional sheets of narrative and checklists as ne2taa2aL (See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date A Donn,Y; flood MRCP WQ/// Si f Management 0 A R Agency/Office/Phone and Fax Numbers Date �i �na mature o E ov en A C> Marcia Allocco MRO WQ//704-235-2204/ EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete, Page Compliance Inspection Page 2 Permit: NCO024392 Owner - Facility: McGuire Nuclear Power Plant Inspection Date: 09/18/2GO7 Inspection Type: Compliance Evaluation Permit Yes No NA (If the present permit expires in 6 months or less). Has the permittee submitted a new application? 0 0 N Is the facility as described in the permit? W 0 0 # Are there any special conditions for the permit? 0 in 0 Is access to the plant site restricted to the general public? a 0 0 Is the inspector granted access to all areas for inspection? a 0 0 Comment: McGuire Nuclear Power Plant's permit is effective from 3/1/2006-2/28/2010. The facility has recently named Pete Bynum as the new ORC. A new ER C designation form has been submitted. Regard Keeping Yes No NA Are records kept and maintained as required by the permit? 00 Is all required information readily available, complete and current? in 00 Are all records maintained for 3 years (tab. reg. required 5 years)? a 00 Are analytical results consistent with data reported on DMRs? a 0 0 Is the chain -of -custody complete? a 0 0 Dates, times'and location of sampling a Name of individual performing the sampling a Results of analysis and calibration a Dates of analysis Name of person performing analyses ■ Transported COCs Are DMRs complete: do they include all permit parameters? 00 Has the facility submitted its annual compliance report to users and DWQ? 0 0 (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? 0 0 a Is the ORC visitation log available and current? ■ 0 0 Is the ORC certified at grade equal to or higher than the facility classification? 0 0 Is the backup operator certified at one grade less or greater than the facility classification? 0 C1 Is a copy of the current NPDES permit available on site? 0 0 Facility has copy of previous year's Annual Report on file for review? 0 0 Comment: Labqratot y Yes No NA Pagi Permit: NCO024392 Owner - Facility: McGuire Nuclear Power rinspoection Plant Date: 09/18/2007 Inspection Type: Compliance Evaluation Labpr"o Yes No NA NE Are field parameters performed by certified personnel or laboratory? W 0 0 0 Are all other parameters(excluding field parameters) performed by a certified lab? in 0 0 0 # Is the facility using a contract lab? a D 0 0 Is proper temperature set for sample storage (kept at 1,0 to 4.4 degrees Celsius)? in 0 0 0 Incubator (Fecal Coliform) set to 44,5 degrees Celsius+/- 0,2 degrees? 0 0 a 0 Incubator (SOD) set to 20,0 degrees Celsius +/- 1,0 degrees? 0 0 a 0 Comment: Field analyses are performed under laboratory certification #5153. ri(lons & Maintenance " Pp Yes No NA NE Is the plant generally clean with acceptable housekeeping? 11 00 Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge 0 0 00 Judge, and other that are applicable? Comment: The facility appeared to be well maintained and operated at the time of the inspection, Effluent SaT pling Yes No NA NE Is composite sampling flow proportional? a 0 0 0 Is sample collected below all treatment units? 0 0 0 Is proper volume collected? 0 0 0 Is the tubing clean? in 0 0 0 Is proper temperature set for sample storage (kept at 1.0 to 4,4 degrees Celsius)? 0 0 0 0 Is the facility sampling performed as required by the permit (frequency, sampling type representative)? N 0 0 0 Comment, Both toxicity samples performed on the effluent from outfalls 001 and 002 resulted in two passes. Please see enclosures for sample results. Effluent Pjpq Yes No NA NE Is right of way to the outfall property maintained? in 0 0 0 Are the receiving water free of foam other than trace amounts and other debris? in 0 0 0 If effluent (diffuser pipes are required) are they operating property? 0 0 N 0 Comment: Flow Measurement - Effluent Yes No NA NE # Is flow meter used for reporting? is 0 00 Is flow meter calibrated annually? to 0 00 Is the flow meter operational? is 0 0 0 Page # 4 Permit: NCO02 392 Owner - Facility. McGuire Nuclear Power Plant Inspection Gate:09/18/2007 Inspection Type: Compliance Evaluation Flow Measurement - Effluent Yes No N (if units are separated) Does the chart recorder match the flow meter? 0011 Comment: Flow is measured as follows: 0 1-pump run time on the intake 002-flow meter' 04-flow+ meter 05-v-notch weir `low meters were last calibrated can 8/23/2007 P Test Concentrations 90% sample Test Result Pass Control Survival 100% Test Treatment Survival 100% Sample Conductivity 55.9 micromhos/cm Sample Total Residual Chlorine <0.0052 mg/L Test results for this sample indicate that the effluent would be predicted to not have acute water quality impacts on receiving water. Please contact us if further effluent toxicity monitoring is desired. We may be reached at (919) 733-2136 Basin: CTB32 cc: Central Files Donna Hood, MRO John Lesley, MRO Aquatic ToxicoloV Unit Environmental Sciences Section Michael F. Easley, Governor �( William G. Ross Jr. Secretary North Carolina Department of Environment and Natural Resources Alan W. Klimek, P.E. Director Division of Water Quality December 15, 2006 5193 JW a.. > .. Ms. Sherry Moore Reid AND Nb, k Duke Power Company LLC d/b/a Duke Energy Carolinas, LLC Sci Support R " ` 13339 Hagers Ferry Rd. Huntersville, NC 28078- L SUBJECT: Wastewater/Groundwater Laboratory Certification Renewal Field Parameters Only Dear Ms. Reid: The Department of Environment and Natural Resources, in accordance with the provisions of NC GS 14-21-.3 (a) (10), 15 NBC 2H .800, is pleased to renew certification for your laboratory to perform specified environmental analyses required by EMC monitoring and reporting regulations 15 NCAC 2B .0500, 2H .0900 and 2L .0100, .020, .0300, and 2N .0100 through .000. Enclosed for your use is a certificate describing the requirements and limits of your certification. Please review this certificate to insure that your laboratory is certified for all parameters required to properly meet your certification needs. Please contact us at 19-733-3908 if you have questions or need additional information. Sincerely Pat Donnelly Branch Manager Enclosure cc. Chet Whiting Mooresville Regional Office One NehCarolina' Laboratory Section 1623 Mail Service Center Raleigh, NC 27699.1623 Phone (919) 733-3908 Customer Service Internet uYc,vv.clvvcalah.c�ru Location: 4405 Reedy Creek Road Raleigh„ NC 27607 Fax (919) 733-6241 1-877-623-67.18 An Equal Opportunity/Affirmative Action Employer - 500% Recycled/10% Post Consumer Paper STATE OF NORTH CAROL.INA DEPARTMENT OF THE ENVIRONMENT AND NATURAL RESOURCES DI'VISION OF WATER QUALITY LABORATORY CERTIFICATION PROGRAM In accordance with the provisions ofN.C.%.S. 1 - 1 . (a) (1), 14 -21 . (e)(10) and N AC,2 .08 : Field Parameter Only -�A STAT, w PUMA DUKE POWER COMPANY LLC D/B/A DUKE ENERGY CAROLINAS, LLC SCI SUPPORT 4 e •' e Is hereby certified to perform environmental analysis as listed can Attachment 1 and report monitoring data to DWQ for compliance with NPDES effluent, surface water, groundwater, and pretreatment regulations. By reference 1 A NCAC 2 .0800 is made a part of this certificate. This certificate does not guarantee validity of data generated, but indicates the methodology, equipment, quality control procedures, records, and proficiency of the laboratory have been examined and found to be acceptable. This certificate shall be valid until December 31, 2007 Certificate No. 5193 c a Pat Donnelly :i ". "s r s • •:i8 "s. attFI• _._ kr Laboratory Certification Listing i ONLY .ate Number: 5193 ve Date: 01101 /2007 tion Gate: 12/3112007 If Last Amendment: i6ed for the measurement of the parameters fisted below. WAL CHLORINE Method 4500 C1 G UCTIVITY Method 2510 )LVEG OXYGEN< ethod 400 C G ethod 4500 H B cRATUR ethod 25508 ,ation requires maintance of an acceptable quality assurance program; use of approved methodology, and satisfactory performance on evatuation samples laboratories are ,ivil penalties and/or decertification for infractions as set forth in 1 A NCAC 2H.0807. OV Duke Energy Duke McGuire Nuclear station 12700 Hagers Ferry Road ?O'vEncurgy. Hcrtutcrsvilit~.NC?13t178 February 14, 2008 i C DENNR-1VMooresville ""D 610 East Avenue RECEIV'L Suite 301 Mooresville, NC 281,15 Subject. 5 Day Fallow -up Report Drake Energy McGuire Nuclear Station: Mecklenburg County NPDES Permit No. NC O024392 Certified Hail: 7007 0220 0002 5591 5535 Mr. Mile Parlor This letter is the required 5 day follow-up report to the 24 hour notification made to NC DENT - IVlooresville involving a release that occurred at the McGuire Nuclear Station on February 7, 2(, Description of Non-compliance Release of wastewater through an unapproved discharge point. n 2/7/2008, as part of our on -going investigation into the release reported on 2/4/08 at our Final Holdup Pond, we identified as new release that appears as if it may have existed :since plant start- up. This newly identified discharge is to a wooded area below the final holdup pond. The release is arming from our pH monitoring and adjustment system and loss of flow indication line. The pH monitoring and adjust anent system checks the pH of the discharge flow from our chemical treatment ponds. 1f the pH is out: of specification, it sends as signal to stop the discharge flour. Set points for ply are 6.2 and 8.8 so that we will not exceed our permit limits for pH of 6 - . Once the effluent has passed through the pH probe it is routed to as pipe which discharges to a valve; pit, The valve pit has as pipe in it that discharges to the wooded area about 300 feat from the final holdup pond. This release only occurs during; an effluent discharge to wastewater Outfall 002. The effluent that goes to the pipe in the woods has already gene through treatment and is within release specifications for Outtall 002. The release rate is approximately 1.3 gallons per minute, 1872 gallons per day during wastewater releases, Chemistry personnel were not aware that the pit was being released to the environment. FFPV The release has been stopped and will be re-routed to be in compliance with our NPDES permit requirements. This release also contains a small amount of tritium, a radioactive isotope. Sampling indicates the release is below the drinking water limits for reporting. This release has already been reported to the NRC (Nuclear Regulatory Commission) under our groundwater monitoring program. On /8/008, At around 4:20 pm on /08/2008, the release from the sample lines was reported to NCDENR in Mooresville to Ms. Dee Browder. At that time it was determined that no 5 day follow-up report would be required., however Ms. Browder did request that we follow-up with Mr. Mike Parker on Monday, 2/11 /2008 to see if there were any questions with the report. n /11/08, we contacted Mr. Mike Parker to discuss the release report we made on 2/8/2008 At that time we discussed the potential for this release to have reached surface water during a rain event. The release could potentially reach a wetland area below the discharge point of the pipe: in the wooded area. Mr. Parker suggested that we file a fallow -up report to document the release. During the investigation of the release it was observed that there is a small amount of ground water leaking into the valve pit around the discharge pipe going to Outfall 002. It is estimated that this leakage is less than I gallon per minute. Samples taken of this leak indicate that it is not wastewater based on the amount of tritium contained in it. temporary modification has been implemented to route the discharge from the laid probes and loss of flow instrumentation back to the plant's chemical treatment ponds so that the discharge is routed to our permitted discharge point, Outfall 002. A permanent resolution for this discharge i being developed by our Engineering and Chemistry groups that will be fully compliant with our NPI ES permit. If you have questions about the data reported, please contact John C. Williamson: by email at jcwillia@duke-energy.com or phone 0-875-58 4. Sincerely, Lee N. Williams McGuire Nuclear Station Environmental, Health &. Safety Manager 2 OV cc Allen Stowe — Mailcode: EC 13K Gary Sain — Mailcode. EC07D Charles "Pete" Bynum — Mailcode: MGOICH Robert Wylie Mailcode: EC I3K Gary Rice - Mailcode EC03T Jim Kammer- Mailcode: NIGOIVP Bruce Hamilton - Mailcode: MG}1VP 3 FFV Duke Duke Euergy McGuire Nuclear Station O'Energy 12700 me Hager, }perry I�i Httx�tersvilic. NC 28078 February 6 200 C":I NR�-Mooresville Eli} last Avenue VED Suite 301 �. : I Mooresville, NC 28115 t . Subject. 5 lay Follow-up Report i E Mike Energy McGuire Nuclear Station Mecklenburg County NPDES Permit No. NCO024392 Certified Mail; 70 0220 0002 55915528 Mr. Mike Parker This letter is the required 5 day follow-up :report to the 24 hour notification made to NCDENI Mooresville involving a release that occurred at the McGuire Nuclear Station on February 3, 2008. Description of Non-compliance Release of waste water to the ground from our Final Holdup fond (concrete lined waste water treatment pond). Between 01/28/08 and 1/29/08 we placed approximately 0.8 trillion gallons of waste water in the final holdup pond for further treatment. This effluent was from one of our main chemical treatment ponds. We attempted to release the effluent from one of our main chemical treatment ponds through Outfall 002 and noticed trace amounts of foam being, generated during the release. We stopped the discharge and placed the effluent in the final holdup pond for further treatment. The final holdup pond was placed in recirculation mode for additional treatment. The effluent released was within our discharge requirements at the tune of the event with exception of the trace foam ;generation. On 1/08 the final holdup pond recirculation was secured. An operator thought he noticed that the pond level had decreased. A cheek was made for leaks through the pond piping and in areas around and below the pond. None were observed. Tape was placed on the final holdup pond wall to denote current effluent level.. PPV n 2/2/08 the pond level was checked to see if the level had decreased. Inconclusive as to level drop. n /3/08 (Sunday) the pond level was checked again by the plant's ORC and he determined that the effluent level had dropped based on the tape marks on the side of the pond. The ORC contacted Environmental, Health & Safety informing them of the situation. EHS determined that the release would be reportable. Chemistry began to pump the contents of the final holdup pond back into B treatment pond. On /4/08John Williamson of EHS reported the release to Mr. Mike Farber of NCDENR in Mooresville. The approximate volume of the release reported was 100,000 gallons. The apparent release path was to the ground. EHS, Chemistry, Radiation Protection and others attempted to determine: where the release was going, A'thorough search of the areas near and around the final holdup pond was performed. No visible water was observed. An investigation into how the effluent was released continues with no final determination being, made at this time. There is not an obvious release path (large cracks, piping, etc.). n 02/ 15/08, Chemistry revised their estimate of how much effluent was released to 140,000 gallons. McGuire EHSprovided an update to NCCDENR in Mooresville (Mr. Mike Parker) on the increased volume of the release and that the release contained a small amount of tritium (9,505 5 picocuries/L,). The amount of tritium is well below the Drinking Water limit of 20,000 picoc;uries/G and the CERCLA RCS of 100 curies. Tritium is an issue of concern for the nuclear industry. Attached to this report is a document describing the tritium issue (groundwater talking points for external stakeholders).' The final holdup ;pond was pumpeddownas far as the installed piping would allow. Rental pumps were then used to empty the pond as far as practical. At this time no additional releases are occurring. e are still trying to determine how the effluent was released. Them is approximately I foot of sludge in the bottom of the pond. Plans are being made to remove the sludge if practical. As soon as the sludge is removed, engineering will try to determine how the effluent escaped the pond. Chemistry has procedurally prohibited the use of the Final Holdup Pond until it is repaired and verified not be to leaking. Groundwater well samples were taken on /5/0for sulfate, nitrate, chloride and ammonia in addition to pH, conductivity, and tritium. Once the results have been received we will communicate the results to NCDENR in Mooresville. Additionally, when we :have determined how the effluent from the final holdup pond was released we will also follow-up with NCCI ENR in Mooresville, PV If you have questions about the data reported please contact John C. Williamson by email at jcwillia@duke-energy.com or phone 704-875-5894. Sincerely, Lee N. Williams McGuire Nuclear Station Environmental, Health & Salety Manager cc: Allen Stowe — Mailcode: EC13K Gary Sam — Mailcode: EC07D Charles "Pete" Bynum — Mailcode: MGOICH Robert Wylie - Mailcode: EC 13K Gary Rice - Mailcode: EC03T Jim Kammer - Mailcode: MOO I VP Bruce Hamilton - Mailcode: MGO I VP Attachment - Groundwater Talking Points for External Stakeholders 3 PPV McGuire Nuclear Station Groundwater Talking Points for External Stakeholders Tuesday, Feb. 5,2008 As part of the nuclear industry's groundwater protection initiative, we must activate our communications protocol based on certain criteria. On Sunday, Feb. 3, we identified a leak from a treated wastewater pond on the McGuire site that resulted in a release of water to the environment. Please begin contacting your stakeholders as indicated below) at noon today. All contacts must be made by the end of business today. Also, if any of your contacts have changed, please let me know so we can update our plan/contact list. 11 llylil ill I ill 11� 1 1111111 Ill ill l ! I I I I I I I I i 1 11lib •lerhentlisd4o complYwiih thiaAhitialive. related to groundwater protection, the nuclear industry has adopted an initiative to enhance groundwater protection around all nuclear power plants. • Each nuclear station has radiological reporting requirements included as part of its operating license. This industry initiative is intended to supplement the existing requirements at each nuclear station. • Duke Energy has always maintained radiological environmental sampling and monitoring programs that are subject to oversight by the Nuclear Regulatory Commission. These programs sample and monitor for both off -site and on -site radionuclides, • On Monday, Feb. 4, personnel from McGuire Nuclear Station notified the N.C. Department of Environment and Natural Resources and the NRC that approximately 140,000 gallons of water from a wastewater treatment pond on the site may have leaked into the ground. • The water was being held in the pond prior to its final release in accordance with our permits, • We are in the process of pumping the remaining water in this pond to other ponds on site to prevent any further releases. We will not use this pond until we understand the source of the leakage. • While there are no public health risks from this incident, the water did contain a very low concentration level of tritium — approximately 9,000 picocuries/liter. This is far below the EPA drinking water standard of 20,000 picocuries/liter. • Tritium is found naturally in air and water, and is a by-product of nuclear reactor operations. Tritium emits a very low level of radioactivity. It must be ingested in large amounts to pose any significant health risks. • A thorough and comprehensive investigation is underway. We will share more information as it becomes available. Certificate of Laboratory Analysis This report droll not be reproduced„ except in tall. 6 Samples M GUtRE GW_MNS Job # 08-FEB-0040 24 Teets Included in this Report Lab ICI: 28002 66 Sample Dose: Customer ID., CAMPBELUHUNSUCKER Sample Collected: 215/2008 10:00:00 Collected By: T. HUN UCKER Date Initiated In Lab: 214/2008 14:07:43 ltiNliUi4E l Ci RIM T I Date Analyzed: 216/200810:5&00 Method: EPA 350.1 Reoortina Limit FI AMMONIA < 0.020 mg -NIL 0.020 0 HLOB!D 8 Data Posted: 21712008 14:13:17 " Method: EPA 300.O rt.L+�.�ll-irx�i I CHLORIDE 5A mgr. N1TR i (I) Data Posted: 2171200814:13:17 Method: EPA 300.0 Re nine Limit ft NITRATE 1,6 mg1L it lTE Data Posted. 2/712008 14:1 :17 Method: EPA 300.0 R ortln Lc mil Ff SULFATE 11 mg/L REPORTABLE SPILL FROM CO2 HOUSE PIT • Asp of our on -going investigation of the release reported on 2/4/08, we have identified a new release that appears as if it may have existed since plant start-up This newly identified discharge is to a wooded area below the final holdup pond and was discovered on 2/7/08 • The release is coming from our pH monitoring and adjustment system and loss of flow indication line • The pH monitoring and adjustment system checks the pH of the discharge flow from our chemical treatment ponds. If the pH is out of spec, it sends a signal to stop the discharge flow. Set points for pH are 6.2 and 8.8. • Once the effluent has passed through the pH probe it is routed to a pipe which discharges to a valve pit. • The valve pit has a pipe in it that discharges to the wooded area about 300 feet from the final holdup pond. • This release only occurs during an effluent discharge to waste water Outfall 002 • The effluent that goes to the pipe in the woods is within release specs for Outtall 002 The release is approximately 1.3 gallons per minute, 1872 gallons per day, • Chemistry personnel were not aware that the pit was being released to the environment • The release has been stopped and will be re-routed to be in compliance with our NPDES permit requirements • This release also contains a small amount of Tritium, a radioactive isotope. • Sampling indicates the release is below the drinking water limits for reporting. • This release has already been reported to the NRC (Nuclear Regulatory Commission) under our groundwater monitoring program, 3 rrp,w Duke Duke Energy VEnergy. McGuire Nuclear Station 12700 Hagers Ferry Road Hunte"ville, NC; 28078 October 2, 2007 Attention: Ms. Judy Rhodes NC Dept of Environment and Natural Resources Technical Assistance and Certification Unit 1618 Mail Service Center Raleigh, NC 27 99-1 C 18 Subject, Designation of CRCs and Back-up CRCs Duke Enemy McGuire Nuclear Station NP DES Permit No. NC{24392 Mecklenburg Mount' Certified Mail. 7007 0220 0002 5591 5641 Dear Ms. Rhodes Attached are copies of the Designation ignation Form for CRCs and Backup ORCs for Duke, Energy, McGuire Nuclear Station. As of August 8, 2007 the new CRC` for McGuire Nuclear Station is Charles A Bynum 1f you have questions concerning this letter, please contact John C. Williamson at the McGuire Nuclear Station, Environmental, ental, Health & Safety Department by email at .icwillia@duke-energy.corn or phone 704-8 75-5 94, Sincerely, Lee N. William McGuire Nuclear Station Environmental, Health & Safety Manager cc: Allen Stowe -- Mailcode. EC1 Gary Sain -- Mailcode EC 7D Charles "Pete" Bynum— Mailcode: MGOIC Water Pollution Control System Operator Designation nation orlr 4 WPCSC CC NCAC 1 A, Sty .0201 Permitt+ee Owner/Officer Name: Duke :finer M cQim-. Nuclear Station / Gary Peterson — Site Vice President Mailing Address: 12700 Ha ers e Road City. Hunters i i11: S S Phone #: (7041 8 -4011 Sinatrtre; hate: ..................................................:..................................................:.............................. Facility Name: Duke Encrey McGuire Nuclear Station Per 't #: NCO024392 t SUBMIT A. SEPARATE FORM FOR EACH TYPE OF S STEM f Facility Type & Grade; __Type grade _Type Grade Biological WWTP Surface; Irrigation N/A Physieal/Chernical iT Land .Application N/A Collection System .....k.w..................w.......#.w.Yl:Y4kMY......1a......wkiliw......w...................... ....................................................... + Operator in Responsible Charge (O C) Print Full Narne Charles A. H' taan Certificate Type / Grade / Number: Waste Water / Grade TT/ 1 971 Physical Chemical / Grade'_T1 Conditional 1 93 "6 ork Phone #: l`7t14 8 43 I fi Signature: Date. } I certify that I agree to my designation as the operator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the oRC as set forth in I SA NCAC € 86.02 4 and failing to do say can result in Disciplinary Actions by the Water Pollution Control System operators Certification Commission." ... ......*.*................ .sew......................c:............•.e............e............. ................ W................................. Bach --Lip Operator in Responsible Charge (BU O C Print Trull Name: Mar aret C. Barrow Certificate Type / Grade / Number: Waste Water / grade IT / 26781 Physical /Ch rnical /Grade TT / 27843 Work Phone fZQ41aZ4495 Si natur : Date: _/)912P9I - " I certify that I agree to to esignation as a rack -up operator in Responsible Charge for the facility noted. I understand and will abide by the males and regulations pertaining to the responsibilities of the BU oRC as set forth in 1 SA NCAC 48C .€1205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System operators Certification Commission," ission," .........*.arc................................................................•........................................arse................................. Mail or fax to: WPCSOC 1618 Mail Service Center Raleigh, NC "7699-1618 Fax: 919/733-1 38 Revised -2007 1 Facility Name: Duke ner McGuire Nuclear tation Per t ##: NC0024302 ..##...#..x4.'#...###.#:.#.#..##P...#.#............M..b#.......#.b###.......*................#.MMMbbtlYXMtlb##M....bal........................................ Back -Up Operator in Responsible Charge (BU ORC) Print Full Name: David Haynes Certifide / Grad umber: h sical Chenli al / Grade 11 2885 Work Phone #: {7Cl l) 75-4 C)C) xt 261 f Signature, Datek "I certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted. I understand and will -abide by the rules and regulations pertaining to the responsibilities of the BU ORC as set forth in ISA NCAC 08G ,0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System. Operators Certification Co ission." ........ I...........IWMM#bibbil######..*.... ###RMO M... *1....... #.*....... b.....*...................... * .*........... ............................. Back -Up Operator in Responsible Charge (BU CRC) Print Full Name: David Gaddy Certificate Type / Grade / b PIt rsi al/Chemical / Grade li / 986ZWork :Phone #: 7C} 7 �4147 Sgtaature: Date: I certify that I agree to my designatio as a Back -tip Operator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the BIJ ORC as set forth in 15A NCAC 08G .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System. Operators Certification Commission." ..........#.::b#bb#.......*............b......................b...........b....................I...................0...*.........##aw#bb:.:.............. Back -Up Operator in Responsible Charge (BU ORC) Print Full %Tame. Grc heaver Certificate Type / Grade / Number: sical/Cheinical / Grade it /986282 Work Phone Signature: Date: - 2-0 - "I certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted.. I understand and will abide by the rules and regulations pertaining to the responsibilities of the ICU ORC as set forth in 15A NCAC 08G .0205 and failing to do so can result. in Disciplinary Actions by the Water Pollution Control system Operators Certification Commission." .##..#....#M#..#..##...#k..#4`..#b...M...b#.#...i.##............................. ................b................##.......*..**......... b##.:. tlYb#.bc Back -Up Operator in Responsible Charge (RU ORC) 'Print Full Name: Certificate Type / Grade / Number: Work Phone : Signature: Date: "I certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted: I understand and will abide by the rules and regulations pertaining to the responsibilities of the BU ORC as set forth in 15A NCAC 0 .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." Revised 8-2007' Duke Energy OrEnergy., McGuire Nuclear Station 12700 "agers Ferry Road Attention: Ms. Judy Rhodes NC Dept of Environment and Natural Resources Technical Assistance and Certification Unit 1618 Mail Service Center Raleigh, NC 27699-1618 Subject: Designation of ORCs and Back-up ORCs Duke Energy McGuire Nuclear Station NPDES Permit No. NCO024392 Mecklenburg County Dear Ms. Rhodes: Nuclear Station, Environmental, Health & Safety Department by email at jcwillia@duke-energy.com or phone 704-875-5894, Lee N. Williams McGuire Nuclear Station Environmental, Health & Safety Manager cc: Allen Stowe —Mailcode: EC13K Water Pollution Control System Operator Designation Form WPCSOCC NCAC 15A 8G.0201 Permittee Owner/Officer Name: Duke Enerqv, McGuire Nuclear Station Gary Peterson — Site Vice President Mailing Address: 112Al7YOOq!Hlg,,gegrEs�,F��Roa�d City: LHIuntersyri -40010 S __Z8078 Phone#: ('704) 87 ,ure 0 Signature: "'Oh Date- ................................................................................................................................................. Facility Name: Permit #: NC00243912111 111 ! SUBMIT A SEPARATE FORM FOR EACH TYPE OF SYSTEM! FacilityType & Grade., _jype Grade __Iype Grade Biological WW'171-11 Surface Irrigation N/A Physical/Chernical Land Application N/A Collection System ....................................... * ................... * ................................................................................... Operator in Responsible Charge (ORC) Print Full Name: Certificate Type / Grade / Number. Waste Water / Grade IV 1097 1, Physical Chemical / Grade R — Conditional 28934 Phone #: Signature: Date: I certify that I agree to nry designation as the Operator in Responsible Charge for the facility noted. I understand and will abide by the rules andTegulations pertaining to the responsibilities of the ORC as set forth in 15A NCAC 08G 0204 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." ................................................................................................................................................. Back -Up Operator in Responsible Charge (BU ORC) Print Full Name: M mret C Barrow Certificate Type/ Grade /Number: Waste Water/ Qmde II,/267$Zl Physical /Chemical /Grade 11 / 27843 Work Phone#: (704) 875-4495 Si&piature: Date: '4t.,ig �a I certify that f agree to in eiignation as a Back -tip Operator in Responsible Charge for the facility noted. I understand and will abide by the rules and regulations pertaining to the responsibilities of the BU ORC is set forth in I SA NCAC 08G �0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." ....................................................................................................................... *..* ....................... Mail or Fax to: WPCSOCC 1618 Mail Service Center Raleigh, NC 27699-1618 Fax* 919/733-1338 Revised 8-2007 t lop Facility hone: Duke ner McGu re Nuclear Station PermitCti(i ..........................................................:JX.........................Mil............... ....... +e ........Rbtl#!ba Back-up Operator in Responsible Charge (BU RC) Print Full Name: David Haynes Certific e T e / Grad en b sic Chemic l / Crack li 28859 Work Phone 7{1� 75-4Cif} t Hai Signature.,iJate "I certify that I agree to my designation as a Back-up operator in Responsible Charge for the facility noted, i understand and wilfabide by the rules and regulations pertaining to the responsibilities of the 1 11 ORC as set forth in 1 A NC:AC 08Ci .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." ..............*................... w..*...... *....... *...... *...*............................... *.............................................. Black -dip Operator in Responsible Charge (BU ORC Print lull Name: David Claddv Certificate Type / Grade f be l'l xsi al/Chetnical / Grade IS /' 86 gil Work Plion Signature: Date: 1 certify that I agree to cny designaticr a Back-up Operator in Responsible Charge for the facility noted. i understand and will abide by the rules and regulations pertaining to the responsibilities of the BU ORC8 as set forth in 15A NCAC= Q C .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control System Operators Certification Commission." ...........M....... ........ .............................................:..........:.................... ...M............. ......'...b .... Sack -Up Operator in Responsible Charge (BU O C Print Full Narne: Cre Beaver Certificate e 'Type / Grade / Number: i' °sip alp" "iaerrtieal l Ct«adc it Sal crlC Phone ill l 75- 1 7 Signature: Date: Z- " certify that I agree to my designation as a Back-up Operator in Responsible Charge for the facility noted, i understand and will abide y the rules and regulations pertaining to the responsibilities of the BU OR '' as set forth in 1 A NCAC` 08G .0205 and failing to do so can result in Disciplinary Actions by the 'Water Pollution Control System Operators Certification Commission." i....*.......................-...........................................a............................b..a..................*........*................... :Back -Up Operator in Responsible Charge (BU CRC :print Full Name: Certificate Type / Grade / Number: Work Phone : Signature: Elate: "I certify that I agree to my de ifmation as a Back-up Operator in Responsible Charge for the facility noted. i understand and will abide by the rules and regulations pertaining to the responsibilities of the BU ORC; as set forth in 1 A NCAC 08G .0205 and failing to do so can result in Disciplinary Actions by the Water Pollution Control Systern Operators Certification Commission." .�. .......+:.a .......... ........... ............. ...s .......... .................. ................ .... ........tl.............a..I.......I........................: Revised 8a24 T A r Michael F. Easley Governor 24 Williarri G. Ross, Jr., Secretary 6ENR North Carolina Department of Environment and Natural Resources CO �. Alan W. Klimek, P.E., Director t41 Division of Water Q lity DES r. OFFICE April 8, 2006 2 0'(" Mr. lion Lewis Senior Scientist, Environmental Support Dube Power\q� EC 1I'3/ P.O. Boy 1006 � Charlotte, North Carolina 28201 Subject: Proposal for Information Collection/ Phase II 316 (b) Rule NCO 24392 McGuire Nuclear Station Dear Mr. Lewis: The Division of Water Quality has reviewed the Proposal for Information .:: ...:. . . �-, v r. _ ":'A t`... .._.,.:.L. f"1 r"t f'tfl�: tn cs �'9.i:ri K�S ["•t":YY'1 f*77i"R'" w er Michel F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Alan W , Klimek, P. E. Director Division of Water Quality Col en N, Sullins, DeputyDirector Division of Water Qualify February 9, 2006 'gel Staff of the Environmental Sciences Section of DWQ have i rman Environmental Monitoring Program: 2004 Summary Report. The report is re aired by NPDES permit number NCO024392 for the McGuire Nuclear Station. The water chemistry, phytoplan to , zooplankton, and fisheries data compiled in the report are within the ranges found in prior gears of the maintenance monitoring program, so staff have no major concerns at this time. Bryn Tracy of the Biological Assessment Unit, however, did have these comments: Fishermen' continue to deliberately moue fish around the state. The latest example is striped mullet being 3 collected in Lake Norman. The introduction of alewife into lake Norman now influences the distribution of r° striped bass making them more vulnerable to the habitat squeeze and die -off in mid -late summer. The 2004 kill of striped bass was well documented and explained by DPC„ NCWRC, and DWQ staff. Although the emphasis in the monitoring program is on largemouth bass, are other species, such as blue ill and redbreast sunfish, tracked as well (numbers, biomass, and size distributions)? Or are these data tracked, but just not 'reported? Page -24 -- the reservoirwide population estimates of pelagic forage fish seem to follow a "boom- bust"pattern Sincerely; i ie Overton Chief, Environmental Sciences Section cc Susan Wilson, Western NPDS Program NOne i aro ina �l�ll�,Cti� N. C, Environmental Sciences Section 1621 Mail Service Center Raleigh, NC 27699-1621 Phone (919) 733-9960 Internet. www.esb enr.state.nc.us 4401 Reedy Creek Road Raleigh, NC" 27607 FAX (919) 733-995 An Equal Opportunity7Atfirmetive Action Employer— 0% Recycled1100/6 Forst Consumer Paper .. h. Duke " .. x �*n.� Power E C � H E ire Nuclear Station dkrpowewsuHalters Ferry Road ,,,a, rsville NC 28078 Duke En " v t N,"�� ,, m .. "s`P January 12, 2QC16 Vl8li3 OF WATER i UALI ( ,' C, }•. Ms. Coleen Sullins Deputy Director k Division of Water Quality � t North Carolina Department of Environment d Natural ;Resources 1617 Mail Service Center Raleigh, NC 27699-1617 a '- nds � Subject: McGuire Nuclear Station Lake Nonnam Environmental Monitoring Program. 2003 Summary Report Certified: 7005 1820 000,7 7552 8003 :bear Ms. Sullins: Enclosed are three copies of the annual Lake Norman Environmental Monitoring Program: 2004 Summary Report, as required by NPDES permit NCO 24392 for McGuire Nuclear Station. Fishery studies continue to be coordinated with the Division of Inland Fisheries of the North Carolina Wildlife Resource Commission to address Lake Norman fishery management concerns. Results of the 2004 data xwere comparable with that of previous years. If you have any questionss concerning this report, please contact either, ,John Williamson (704) 875-5894, or Robert W. Caceia 704) 382- 696. Since , Gary Petersen McGuire Site Vice President c: Mr. Scott Van Hom, North Carolina Wildlife Resource Commission Miehae V William I ----- - North Carolina Department of Environment mid Natural Resources Alan W. Klimek, P. E. Director Division of Water Quality November 2, 2005 Mr. John Williamson Duke Energy Corporation 12700 Hagers Ferry Road Mail Code: MGOIEM Huntersville, North Carolina 28078 Subject: Compliance Evaluation Inspection Duke Power McGuire WWTP NPDES Permit No. NCO024392 Mecklenburg County, NC Dear Mr. Williamson: Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection mmendable. Please inform the facility's Operator -in -Responsible Charge c varding a copy of the enclosed report. this report, please do not hesitate to contact Mr. Lesley or me at 704-663-1699. Sincerely, r) r-7 , ;VNNi D, Rex Gleason', P.E. Surface Water Protection Regional Supervisor Enclosure cc: Central Files Mecklenburg County Health Department I One, NroCarolina WNW, 'Wittlailly a, NMUM M C. Division of Water Quality, Mooresville Regional Office, 610 E. Center Ave, Suite 301, Mooresville NC 28115 (704)663-1699 Customer Service 1-877-623-6748 14 j AUnited States Environmental Protection Agency Form Approved, E T" J 1 Wash;ngton, p . 2#7a6t? OMB No. 2040-0€i57 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., P S) Transaction Code NPDES yrtmotday inspection Type inspector Fac Type ) L tat 2 a 1 31 ikCO024 92 11 121 0°,r !1 117 18� 191 <;1 0 1 Remarks #� 21 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1I I I I I I I I I I I I I I 1 6 Inspection Work Clays Facility Self -Monitoring Evaluation Rating R1 CIA ----Reserved------ -- 671 ? . 2 1 69 70 U 71 U, 72 nj 73LJJ 74 75 I 1 1 1 � 1 1 180 Section 8: F cifi Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry TimelDate Permit Effective Date POTW name and NPDES permit Number) McGuire Iuw_lcar Power Pl�lrtt .02 Ai 05/11/ 00/10/01 NC x4. ,, 73 Exit Time/Date Permit Expiration Date Name(s) of Onsite Representative(s)tfittes(s)/Phone and Fax Numbers) Other Facility Data / /1 Name, Address of Responsible Offcial Title/Phone and Fax Number Contacted John C ferry Rd 1 untc t rxvz.11e NC r Section C;: Areas Evaluated Durin2 Inspection (Check only those areas evaluated) Permit N Flow Measurement � Records/Reports � Self -Monitoring Program Effluent/Receiving Waters a Laboratory Section D: Summary of Finding/Comments {Attach additional sheets of narrative and checklists as necessary) {See attachment summary) Name(s) and Signature(s) of Inspector(s) Agency/Office/Phone and Fax Numbers Date E es] 1-v MLE> Wu. ' ,'G m 663 1699 E°xtt.2 0/ I I c'wLt' Signature of Management Q A Reviewer Agency/OfficelPhone and Fax Numbers Date EPA Form 3560.3 (Rev 9-94) Previous editions are obsolete. NPi? yrfmolday Inspection Type (Cont.) 1 3 t t,lt;y.t 3ca2 11 12 I 0 t 11/0S 17 18 Seam C: Summary of Find in /Comments (Attach additional sheets of narrative and checklists as necessary) ) .acri c for tn;, c a,,ww t„'C 4 through August .(tr is..ra I`%r. _a.:.11 _ty uses Duke Er.vir �tt __ tal Lahur tors ' ur .-I-Ir an7 and analyses e. p,ar.ani tc rs , adinl field p&,.at�.�.t.r e.0 ana-lo. cit,y testing. tar Se.t. ;:ran pe:.ct s s=,., x..c.l v .cst sep. Duke Powe.. McGuire Facility discharges from the following ing outfalls,, ;L tu' 1- OR j, s 1wVe of corWanser cooling Ww.o ° aw priftisure sev.i,ce aster, vniti].ation Unit dralnsr i.Fl i udi -C r` beat exchanger drain down, and Z leir Service Wpm, . , O t a ..'. 004 is ) s } Gil 1rprCt d "1.'rJtagh out-fW1a,1a71 andincludes'dlscT.a aae from the _ad wa. ve liquid mmo toring system, floor � nd <ta,r%-aenw cl id, �I,.atu rw.:ti.ea, s, .eac .r .f,olant Qu < tt exchanger chew.,. ql c.1.c.asi.n wastewater, an3 vcrati atio.-I unit drains, 2. MCI 002 (includes 4 t,.}.+_al it 006 ;.h;a,.. is so longer is service) - dist3 aurae of treated wastewaters from heat exchanger and PVAC tube cleaning, YF filter ::tube c` earaln , turbine building sumps, zax er treatment room :notes, tc d s_ ,_ demine.alizer bal washes, cloy cool nq systems, the Standby ._htat own Facility, laboratory draAns, 1:.wa.t_c i leawc aw, sWwn generator ,,.,,rr~an" wat lay-up, dewate.. ng eua,.p.�s, chemical c.lfaa.mi.aar; wpszewater, and other low volume wastewater genecating activities. Ita treatrtent facilLity consists of a 271,0tt-gal on concrete lined ._clduc land, two p,azallw; w:.`r Nlv clay- l_ned settling pon a, a concrete lined ' finw, hold-up pond, Not .. r e1 and t ctut.ic:a.I. ac t.t.i.<.>F7 S, r, .. l.e: Us, andCt72. ra.lt�z � a.t-rrt. The treatment facility ,ppe.a.e d to kaa_tn condition. �cel e t s. Outfall +l discharge of tl-ie t 1 awe settling p any( and wrface skimimar.to i-m ..t system receives writ.€ wzat,wr from Standby nuclear ser lS e.i'pan.1 W rfl aw, administrative building drains, .t ._ condenser ool:nq dewatsrt-zng, t...J......re wa.t_e;r, FIVAC unit drams, yard dr Wa and ,.c.r:*:rse osmosis reject glows. The setAhmg prat, had _een drawn dmn to allow Wr srep, it of the etfluent flow structure ar,d:,as not w..sQa P at the Sho of this rl we^t i. m. Permit: NCO024392 Owner - Facility. McGuire Nuclear Power Plant Inspection mate: 11/01/200 s Inspection Type. Compliance Evaluation Permit Yes (If the; present permit expires in 6 months or less) Has the per ittee submitted a new application? � is the facility as described in the permit? Are there any special conditions for the permit? Is access to the plant site; restricted to the general public? � Is the inspector granted access to all areas for inspection? Comment: Special Condition: Thermal variance for the months of July -September for temperature up to 99 degrees F. Flow Measurement - Effluent Yes Is flow meter used for reporting? ® ; Is flow meter calibrated annually? � Is the flow ureter operational? (if units are separated) Does the chart recorder match the flow meter? 0 Comment; Calibrated quarterly: last calibrated on 10/T2005 outfali 002, Ieortl eepirrq Yes Are records kept and maintained as required by the permit? Is all required information readily available„ complete and current? Are all records maintained for 3 years (tab. rreg, required 5 years)? � Are analytical results consistent with data reported on DMPs? ■ Is the chain -of -custody complete"? Cates; times and location of sampling Narne of individual performing the sampling � Results of analysis and calibration Dates of analysis Name of person performing analyses Transported C OCs Are t7MRs complete: do they include all permit parameters? Has the facility submitted its annual compliance report to users and DWQ? 0 (if the facility is = or > 5 MG0 permitted flow) Do they operate 24/7 with a certified operator on each shift? Q Is the ORC visitation log available and current? is the ORC certified at grade equal to or higher than the facility classification? ■ Is the backup operator certified at one grade less or greater than the facility classification? � Is a copy of the current NPDES permit available on site? Facility has copy of previous year's Annual Report on file for review? Comment: Includes all outfalls Effluerlt aiinr Yes Is composite sampling flow proportional? Q Is sample collected below all treatment units"? ]� Is proper volume collected? ■ Is the tubing clean? 0 Is proper temperature set for sample storage (kept at 1.0 to 4.4 degrees Celsius)' 0 300 300 1 0 0 300 Is the facility sampling performed as required by the permit (frequency, sampling type representative)? U F-1 I Comment: Facility staff performs field parameter sampling (Certificate: No 5153). includes all outfails.