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NC0024392_Regional Office Historical File Pre 2018 (5)
PERMIT NO.: NCOO FACILITY NAME: Du ce Facility Status: (circle one) Permit Status: (circle one) Major Minor, Pipe No: 5 Design Capacity (MGD): Domestic (% of Flow): Industrial (% of Flow): Comments: ,e/r ezvicr ho., /3G i / /1 RECEIVING STREAM: Class: Sub -Basin: w Reference USGS Quad: County: MzeL/n. Regional Office: As (circle ens) Requested By: ` o. Prepared By: Reviewed By: Fa NPDE WASTE L D ALLOCATION ever (please attach) Wa Wi WS Drainage Area (mil) 7410-(.cfs) SC-) Winter 7Q10 (cfs) Toxicity Limits: IWC % (circle Instream Monitoring: Parameters Upstream Downstream Effluent Characterist cs BOD,L (mg/1) NH3-N (mg/1) D.O. (mg/I) TSS (mg/I) F. Col. (/ 100m1) pH (SU) Comments: Location Location Avg. Streamflow (cfs): `'`30Q2 (cfs) cute Peen it Number Facility Name Typecif Waste Status Receiv Stream 3ubbas rig Stream Class 7ASTELCAD ALLOCATION APPROVAL FORM N00024393 DUKE POWER-MCGUIRE COLLECTION BASIN DI EXISTING CATAWBA RIVER WSIII 0 30833 LENEURG CHRIST -7 HARGE ::]age Area Average F'? Summer 7010 Winter 7Q10 RECOMMENDED EFFLUENT LIM 0a is Location: Location: T#" 1 A MODIFICATION TO 3 ,iUTF4LL C 0S FROM THE PERMITTED f F LL ONA!`, WASTE `. ..mac LIMIT i= O P FLOW IS A 4,6 or COMMENTS Reviewed by: Tech. Support Regional Permits rvisor rieeri Request No. :433 AND INVOLVE- PERMITTING . 0 6 4 MOD OF SANITARY TFALL DO 1 (,411 AGD OF O.v 'iREN``., 00'2 RETURN TO TECHNICAL SERVICES BY QEC m03 1988 Facility Name T. N'% Permit# t.9C o 2 q CHRONIC TOXICITY MONITORING REQUIREMENT (QRTRLY) The permittee shall conduct chronic toxicity tests using test procedures outlined in: L) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure - Revised *February 1987) or subsequent versions. The effluent concentration defined as treatment two in the North Carolina procedure document is 12%©. The permit holder shall perform Quarterjv monitoring using this procedure to establish compliance with the permit condition. The first test will be performed after thirty days from issuance of this permit during the months of --Co l — Effluent sampling for this testing shall be performed at the NPD S permitted finale uent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Technical Services Branch North Carolina Division of Environmental Management P.O. Box 27687 Raleigh, N.C. 27611 Test data shal be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NO 1'E: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute a failure of permit condition. 7Q10 cfs Perrnited Flow �.. Z MGD 1WC%© \ Basin & Sub -basin Receiving Stream (bst CountycAl`./.,.., Recommended by: **Chronic Toxicity (Cerio) Monitoring at l7_ %, See Part ' , Condition G NPDES Permit Modification #1 Application for Re -Permitting Collection Basin ' roll, ' OCT G OCT"T Supplemental Information System Description Collection Basin (Wastewater Cc Llding drains, and condenser esigned to provide water ±for The lab sink and floor drains discharge approximately three liters of chemical waste per month. Flow from these drains go to a groundwater sump then to the SNSWP then to the WWCB. The Administrative Building drains include an HVAC sump, floor drains, hot water boiler and chilled water system discharge. Flow is to a yard drain which flows to the WWCB. The Condenser Cooling Water (CCW) System for each of the two (2) units has a volume of approximately 2 million gallons each. Whenever a unit is scheduled down for refueling, periodically during other shutdowns, and for condenser tube leaks, the system must be unwatered for purposes of maintenance. Unwatering must continue while maintenance is performed because of leakage by the valves in the approximately 11-foot diameter CCW piping. The maximum ,x unwatering rate is approximately 2000 gpm; the water is essentially lake grater. Treated liquid radioactive waste effluent (discharge 004) discharges into a crossover line between the CCW system of the two units.inuring unwatering, trace amounts of radioactivity can potentially be released into the water from the unwatering process because of leakage by a 54-inch isolation valve. All yard drains discharge to the WWCB. The WWCB provides sedimentation, natural neutralization, and skimming. inch. 'he overflew from the WWCB mixes with the discharge from the Conventional Wastewater Treatment (WC) system {discharge 002) in a concrete' apron and is discharged to the Catawba River downstream of Cow ns Ford Dam OMB No. 1000-0059 Approval e+pnes 11-31 -85 Pleasefprint or type in the unshaded arras only. it; „EPA OUTFALL LOCATION A. OUTrALt NUMBER (liar) 005 U.S. ENVIRONMENTAL PROTECTION AGILNCY APPLICATION FOR PERMIT TO DISCHARGE WASTEWATER EXISTING MANUFACTURING, COMMERCIAL, A,, MININGG ND SILVICULTURAL OPERATIONS ConsolidatedPermits B. LATITUDE f, Ogg. 35 Z. M#M, 25 1, sac. 59 s an to the nearest 1 C. LONGITUDE F. ©!G, 80 56 55 econds and the name of the receiving w II. FLOWS, SOURCES OF POLLUTION, AND TREATMENT TECHNOLOGIES A. Attach a line drawing showing the water flow through the facility. Indicate and treatment units labeled to correspond to the more detailed descriptions i flows between intakes, operations, treatment units, and outfalls. If a water pictorial description of the nature and amount of any sources of water and any D. RECEIVING WATER (name) Catawba River sources of intake water, operations contribut n Itern B. Construct a water balance on the li balance cannot be determined (e.©., for carol collection or treatment measures. B. For each outfall, provide a description of: (1) All operations contributing w cooling water, and storm water runoff; (2) The average flow contributed by on additional sheets if necessary. (Refer to Supplemental Inf t, OUT- FALLNOr (lia I) 2. OPERATIONIS) CONTRIBUTING FLOW a. OPERATION (liar) b. AVERAGE (include un er to the effluent, ing by showing average hies), provide a astewater to the effluent, including process wastewater, sanitary wastewater, each operation; and (3) The treatment received by a wastewater. Continue or-tttation for Additional Details OW 005 Collection Basin (Wastewater Collection Basin) 7.2 MGD 3. TREATMENT a. DESCRIPTION b. LIST CODES FROM TABLE ZC•I Sedimentation Natural neutralization Skimming Discharge to Surface Waters 1-U 2-K 4- A OFFICIAL USE ONLY (et 4fnt /uldelines aub•eateporlee) CONTINUO FOM THE FRONT C. E xort for stormr(jfl�ff Ieaks, or Spills, re any ot the dacharge describeddescrlbad n Items II -A or B intermittent or sessontll ; YES 'croupier(' MC follou•,ng tahIct X NO (go to S(Cti0n11/) 1. OUTFALL NUMBER PRODUCTION 2. OPERATION(s) CONTRIBUTING FLOW A. )to Il1Wirrrrrrr •ir,rdellrrw rtr-nriorrr)n nrrrmulciatr., rce,rrroi.•tr 3. FREQUENCY 4. FLOW a, DAYS PER Wk.,FI4 b. MONTHS PER VEAR ""'" a FLOW RATE (1,1 Ingd1 b. TOTAL VOLUME (specify with units) th4Le0 i tOtt. ETA taidiii Section 304 of he Cit-ian W3tel Act apply to your tacitity? NO firr t,r Sicl'rrrrr /11 c, DUR- ATION 10 I 414.1. Are the limitations i0 the appiicable effluent guideline expressed in 0:rtri5 ot production (or other measure of operation ] YES ,col,o0, (", NO /kr, Irr Sertiorr 11,t C. f you answered -yeS'' tO inriWB. ],st the otuiputy h sentt, an actual measurement of your level of production, expressed used m The applicable effluent 00oClrno P10 ncicate the af!ected ctatk m' and UnitS 1 AVERAGE DAILY BRT,DUCTION “TION„ evr- 2, AFFECTED OUTFALLS (list ewlfaN /11.1 FYI A. Aol 1 d by any Federal, State Or 'hr.:al aurhor.ty 10 meal any implmnenlal,on schedule o the construction, upgrading or operation of waste oi practices or any [Me, 1..r-rs,r,rwrilirrcrtat programs which, may affect the 0iiiiiuitarges described in this ouplication? This includes, but 7)0,0 to, permit condit,ons, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and giant Or 03/ y ES icontpleo, thc follow1,4 tahlet :-t.to (go lo nemV• I)1) 11, . IDENTIFICATION OF corromo AGREEMENT, ETC. Z. AFFECTED OUTFALLS orr.o. b„ souse* or 151.14C1A1441/t 3. BRIEF DESCRIPTION OF PROJECT FINAL.r+FkiSE OPTIONAL: You may attach additional sheets describing any additional water pollution control programs (or other environmental projects which may affect your discharges) you now have underway or which you plan. Indicate whether each program is no underway or planned, and indicate yOur actual or warmed schedules for constructon, MARK "X" IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED Nmommlimmill& CONTINUE ON PAGE 3, r -2C IRev. 2-851 PAGE 2 OF 4 CONTINit1ED FROM PAGE 2 V. $NTAKE AND EF A, 8, & C: Sae instructions before proceeding — Complete one sat of tablet for t NOTE: Tables V-A, V-8, end V C are included on separate sheets nu to list any of the pollutants listed in Table 2c-3 of the instructions, which you know or have reason to believe is discharged or may be outfell. For every pollutant you list, briefly describe the reasons you believe it to be present end report any analytical date in your Supplemental Information for additional details) SOURCE 1. POLLUTANT Form Approved OMB No. 2000-0059 Ae! exprres 12.31 -8 fall - Annotate the outtatt nu V-1 through V. D. Use the space below discharged from any possession. (See 1. POLLUTANT Vi. POTENTIAL DISCHARGES NOT Is any pollutant listed in Item V-C a substance or a component of a byproduct? OVERED BY ANALYSIS ubstancewhich you currently useor manufactu ' YES iiis( aII ouch polls. toots below) X,No two to !fern VI-B) SOURCE or final product 0 TI'hUE4 FRIMTHE FRONT po you have ert receiving water i knOWteC9e Or rea:t rein;ion to your d ;t any biotc the fart3 y DIVES (identity the test(a) and describe their purposes below) Fathead Minnow Flow -Through Acute Test Ceriodaphnia Survival and Reproduction Test or acute or chrome toxicity hat bean made on any of your ditch n VIM Tests were for informational purposes to determine whether the discharge showed any signs of toxicity. No acute toxicity to fathead minnows was demonstrated during the 96-hour test period. No effluent -related acute toxicity or chronic toxicity to Ceriodaphnia was demonstrated during the 7 day test period. e any of the analyses reported in item V performed by a contract laboratory or consulting ti v ES analyzed (list the nae, address, and, each such laboratory or telephone fnumber rm below) and pollutants B. ADDRES A A NUS Corporation Teledyne Isotopes ( Analyses perfo o to Section IX) 0 1910 Cochran Road (412) 343-9200 Pittsburgh, PA 15220 50 Van Buren Avenue (201) 664-7070 Westwood, NJ 07675 D. POLLUTANTS ANALYZED (list) Item V; Part C Parameters Ra-226 & Total Ra d in 1982; to be retested with renewal in 1989) nder penalty of law that this document end al/ attachments war at qusidled personnel properly gather and evaluate the informat, sons directly responsible for gathering the information, the inforri ra that there are significant penefties for submitting false info Qred under my direction or supervision in accordance with a system designed to submitted. Based on my inquiry of the person or persons who manage the system or ion submitted is, to the best of my knowledge and belief, true, accurate, and complete• anon, including the possibility of fine and imprisonment for knowing violations. A. NAME & OFFICIAL TITLE ((ppe or print) H.B. Tucker Vice President, Nuclear Production B PHONE N©. )urea coda & no.) (704) 373-4531 D. DATE SIGNED 7 C. SIGNATURES / TGq Ladbit(cL,, CART A , I. POLLUTANT t» ctt4�tl.t ,1 C)..yytal t..'xtt.�ttti c 141,1 Ou.j.::MiL i,. t.rej 1. 7 0111fx ,.SGi'(ii:�.:.f rr 1 Tt"t.,, tutu ram. .1 1«A):11.11JM DAILY VALU 4.2 15 5.8 2.05 .20 V AL,. t1 311.75 (Analyses perfotiued in 1982; will be retested for application in 1989). fation Name Outfal'1 Number McGuire Nuclear Station 005 , 1. r/AXILIU\1 1.1 cor.rc r.r _ n 1113.39 430.51 151.43 14.84 8.90 V At_U:. PAW'. : i. 1 1t f'..•c. X X t,o..tat • 6.8 .1AX 1M U.L7 10.5 4.3 V A L UL 4.00 Y V U v ALUC VAL U 14 AJ. I M UP1 v VALU.. 319.17 A4"I4L%. VALUi. _.__ (xl •n res ' VALU 2.46 VALUE VALUC r,4_. 3'� t�,t'.' v •}L 11Z 1 c. L. C1 ANAL YSE astewater Collection Basin t1.CONCEN- TIIAl1Ur: 1 1 A59 b/day .91 mg/1 1 248 259 mg/1 mg/1 m9/1 1:) .nnss 18.67 lb/day 7.11 145.87 A b/day 2.2 MGD b/day 2.5 b/day .05 45.14 51.29 1 1.02 1 2.46 248 VALUe 4c VALUE No./100i wg/1 Ts lb/day 2 6 15. T- AN'I A CAS N J IIrPQan, 1a1 prunnr[ 4 MARK' U r )AILY VALUC 1.4 103.92 CNT A X I M U ht 31i (),A Y V A ** .19 14.10 c Alpha, X Total X 4+.2 4.4+. A k i i (: , V A L U X 4) ftaoaum 25, Total It, st ray 1141t 1. Su Write 4265,45-3) u X 5 4, UNITS ©NCCN•©. MASS ATION mg/1 lb/day 5. INTAKE: At.)' A i tat, <.1 2.05 X NO t>t A NA.1 vsl.s mg/1 lb/day .08 .64 1 pCi/1 X X X o. AIutY (nut T Deal In,9 90 51 11atluffl, �1a1 440 39. X 10 742,26 X X 0,4243) Cut oI1, uul /44C 4.94) Iron, Total 439 H9 6) Total 11439 95 4) yt)aenu 4 11n TPtal 440 31 X X X X .35 25.98 .02 1.48 1pCi/1 1 pCi/1 1 pCi/1 .43+.16 2.4+.28 8.5 .5 nr / 1 1 b/day 0 205.16 X X X 1 mq/1 lb day 1 mq/1 lb/day .055 4.08 .36 26.72 5 259.79 .07 5.19 .01 .44 .01 1 mg/1 lb day 1 mg lb day 1 mg/1 lb/day .02 X .14 .2 X .006 .20 .41 2.87 1 24.62 2 Part C 4�" u A ANC) I:A� rJU.1(1C1 1,1ArtK "X' (Analyses performed in 1982;.will be retested fear application in 1989). s a IC uclear Station MAXIMUM :DAILY V AL.Ui.. TALS. CYANIGE, AND TOTAL PIIENC)LS 1 r.1rLti.unV. 1 i,Ia1 ; /440 • JL.1 0.11•Il.ipn, u td 11 44t1 4 S 91 3r.1 Chrunni.,n 1 u1Jl (1440 41 31 nI Covnrr, TUtal (J..0004) )r.1. Lead, ru Lri 143:1 9 / 461 J l.I F.;ercury, TQtJI 14:490/10 1 u1J1 1 /440 02 0) 1 "LI41 11132 40 2) 111.1.50.e!„ ro14l /440 22 4) 121'.1 1 haliunn I utal (1440 211 0) Jr..) Zinc, Tu[d1 144U 63, Co 1441. CY.nuh>, Iuul;5/ I:.rst. Phenols, I ..c..l N 5.45 025 .1 ,4 r. .0001 01 04 1.94 07 .02 31, 86 07 .37 �FFLtJ NT Ou Number astewater Collection Bas 4. UN1"1 . CONCCN TF:ATK3N r1 MASS ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 mg/1 nib 1 d LC'r A lb/day <2 lb/day 3.7 lb/day <.001 lb/day <.2 1bfday lb/day 4.7 lb/day 1.0 lb/dad ._.'w. iP/day b/ ._ WA 1b/day .03 lb/day ,:.001 lE,/LUy TAK 4 <.00002 <.004 <.01 .10 .02 <.002 <.10 10 <.002 ‹.02 .62 02 t+ r`t tl e•E X 1. F'C`I..LUTANT A N (1 C A 5 C!111,t11U. )7 ACTION) 111. AcettarllU,i*ni, ;83 32 9) Acennphtylenc I. 0U 96 0 ) 39. Anthrecone 120127) i (1. I3rnridine 92 87 5) 1lunro (a) lnihracune 555531 iU. Ilenro (u) 'yrene (50 32 3) 10a. pis f -1l Chfur,, y) 111-91- '10 2-C1,1,,r0 It. y;) F thcr 111 44-4) 1211. Cis (2-Chl„ro 3.153),32 9) 30 O,s (2 Elhy). ".'1)) FlilLal]IC 117 81 7) 4 Ir0rn3- ;hcnylF'hrnyl Inc) (101 55 3) 5il idyl Orntyl hthalate I95.1,6-7) 2 C#;Ioto,, ,r. ntl.)1unc '.I 1 58,7) 4 Ct.luro- 1•Ienyl 1)5 72-31 7U 3) 1,2 U,. hlorri „t,na (95 GU 1 r '11t 1.3 nicl,w,u- ,,<r�ut If,41 13 I ( r MAXI 1.1 c c U liA4. CC)it QUNUS <10 <.74 <10 • <.74 X <10 <.74 X <10 <. 74 X <10 <. 74 X <10 <. 74 X <10 <.74 X <14__ <.74 1_0 _ =14. <10 .74 <10 <10 �_..74 <10 <. 74 <l0 <.74 sl 0. _ _ ,_74 <l.a- _ sJ4 <10 <.74 s10 .74 _.. µ <10__ `.._._4..___ 10 < . 74 UF1 OAILV vr,Lur TNo. oL _. y' I 1 An 1 .�s 1 1 1 1 1 c 1_1NITS n CONCrtr T NATION I+1 A55 5 INTAFKC: • e 1. ().',C, '11 It r.1 .• ug/1 lb/day <10 <.21 ug/1 1b/day < 10 ug/1 lb/day < 10 .2 .21 ug/1 lb/day < 10 < .21 ug/1 lb/day < 10 < .21 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 uy/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ucl/ l l b /day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day 10 ug/1 lb/day 1Cl u9/1 lb/dad 10 Il/1 .21 .21 .21 .2 < .2 .2 .21 .21 .21 .21 .21 .21 .21 .21 .21 1 1 1 1 1. POL,LLITAr1T Alin CAS Liu l„tuClt MA#ttt CTIO' - V i2V, t.1..0 I ,,u CI.Io,1.1u (75 09 21 i3V, 1„1 2,2 Tau(' I11,1:.IUlilnue 17) 14 5) 24V, TcIr:[:hluro. uil.ylr..r. (127,1a-4) 25V, TCI[,cne (100 Cd-a) 20V. 1,2 Trans 115G 00 51 X <10 <.74 1 HUL:Itdr JLdLIUlIw1® UU5_�a._ y• 7. LFF'l_1JL:14-T MAXIMUM t]AILV VALUL 110. of 1.1 I11 M,as Analy j S X <10 <.74 1 X <10 <.74 X <10 <.74 X <10 <.74 L7V, 1.1,1 _LV, 1,1.2Triu u�:oror;:�anc I)9,C05) 29V, Tr I1I ro ,,ny1 ,w 179 01 6) �IOV TrLI.Icro, () 1.9 41 )1v, Vinyl [.lJ„r.r1r (75 01,4) X <10 <.74 1 X <10 <.74 X 10 <.74 1 10 <.74 1 GC/;.3S f.IACTIO (- ACIO C IA : Cr�[,rovl�rno 15slul :.1A 1120 a3 2) :. 2,4 LL n..rhyI Itlus,iul I IU r G/ '..I 4A. 4,6 n,mirn 0 Crrf01 (Sa4 :i2 1) ..A 2.4 0.1ntr+r 1, t..•nr>t 1�1 23.5) A 4 Iiur0lrllenul I UJ U.2 1) P CUI 0 7) DC. 5) X <10 <.74 1 X <10 <.74 1 <10 <.74 X <10 <.74 X <10 <.74 10 <.74 1 X <10 <.74 1 X <10 <.74 X <10 <.74 X <10 <.74 <10 <, 74 VdsL waLeI' LUI Itl LIUII DdSlll tom'-n-a:.•araami ran- aaa/a QRrOK�s*4�1�a. 4, UNITS 5 I1'4TAi£k: CONC'cN THATION ,t 1 t.,r+t. Tr_ r rt.1 MA'5,5 1.0 ug/1 ug/1 lb/day < 10 < .21 lb/day <10 < .21 ug/1 Ir r. A Y Y` b/day < 10 < .21 ug/1 lb/day <10 <.2 ug/1 ug/1 ug/1 ug/1 ug/1 ug/ ug/1 ug/1 lb/day <10 lb/day 1b/day 10 < .21 10 /day < 10 b/day < 10 b/ day < 10 lb/day <:0 lb/day ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 uq/1 ul�/1 lb/day lb/day lb/day b/day lb/day lb/day lb/day 1 b/day lb/day <10 10 <10 <10 <10 < 10 <10 < 10 < 10 .21 .21 .21 .21 .21 .21 .21 .21 . 21 . 21 .21 .21 2 < .21 1 1 1 I. 1 C LLl1TAr1T A14rl c A5 (A,O.1uLl1 2.t-'Ahl'.'x• GC/f 15 FRACTION - 1 V A.( .ole,n 1(1. Lr2 3) ?fir, / rylOnillile 1107.13 I) Lr!1lCnC /r1 43 :1 1)IS iL%IIUr.d. IA, !n .,+ L Il6dr l:. ,..0:(7rrn ,r .., .+) ( CJrl.or' 1. u, r7,1•�t L:IL /V. Cfrl+.: 01.cnt tnu 11(J2. L.J 7) ��a __�.,_ ` n.rl'rta i. _.._. i 12 4 . 11 ) .V. CI..„ru.:: l...rru OL DO .1! 101! 7Chl.Jlo- ,11.1 I: rn, l E slier r11U7L11) 11 V CIvorulorm !d/ Cu .I 1 V l7.(I1ILre7 1:5 2? 41 13 :'. 1..cnlatu 14V. 1,1 DrclJcrO- e:l,uic )75,34-3) 15V, 1,2 D,cnlutu r*Ir.m..•,)f1/ OG 2) lt.V, 1,1,I1.011oru• ourylcne (15.35 41 1 v 1•2 Dit.Wuro I7t10) 5) ir)v. u 0J. y'Ir ,,.-12 /5 yloentene 111)0 •:1 4) 2UV I-irl'iyl .� .++r=r.rt• 1:4 03 0) 11 F. e X X X X A } X 3. Lt F I.IJI NT 4 .5 I N 1" A .. Cor. !'2OU <10 10 <10 <10 <10 <10 <10 <10 0_ <10 <10 'DAILY VALIJL < .74 <.74 <. 74 <.74 <.74 <.74 <.74 <.74 <.74 . 74 < 74 < .74 <.74 <.74 -74 0 <.74 <10 < 10 74 . 74 < / �t of lyses._. 1 1 1 1 1 1 COZ+CLN NATION Jy r V_14 t.ir5 ug/1 lb/day <10 <.21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .2 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 9/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10 < .21 ug/1 lb/day <10.�. < .21 u9/1 lb/day <10 ` .21 uq/h/daY.... <1f) < .21 ug/1 lb/day .10 < .21 ug/1 lb/day <10 < .21 ug/1 lbday <10 < .21 ,/ l)/lay <10 <.21 (110 A44 1 Analyses performed in 1982; will be retested for application in 1989). . 1'Ot_LUTAN f MA4trt "A NU 11;lf'_li ,„ a. MAXIMUM DAILY VAl_r1E .4 M11 OR NI C,T,;S FRACTior) - E3A C/N[alTHAL CC'M O11NUS (conk i L+d) !211. 1,4 Dic hluro utn: cne ( 10G-46, 4 1) 3. DLahyl 0 73.2,4-Dr .Hoene (12 Y 42) SG.2,G Gin»;rn 1trc.1,� (COG 20 21 211, Di ;",.octYl nlh-J31n 117 84-0) ✓;I. 1,2-C1;01o(1yl rt1r.,t.n3 (::+ At(' r•i•I(123 C.; / 113, 1- luororuhel:c ,hG4401 1213 Fluorene l o 73-7) ::.11:. NP:J• nIOu 1 .ntana 1 77-17 4) lii U. IleaaLhloro= uliane 167.72 1) 17U.Im:ono cd) Pyrene 193 30 51 (N11, Isophorona 711 59 1) Nnlrhthaleno ',0 1 2C 3) <10 < .74 <10 <.74 10 �._.. 74____. la_ <_ 10_ < .74 < .74 s.1 __. . 74 <10 <.74 <10 <.74 <10 < 74.. <10 _. 74__.__ 10 <10_ _ . 10 <.74 {10 _ .74 <10 .74 <10 ,. 74 a___ 4 lean Station ). 1I P"t_1411)1 Anal yses 1 1 4e=Al.-.. rr 00 5 Wastewater Collection Basin .. 4. UNIT' 5 1NTAKt. -......._...._.___..._.___ ._......,,_.._..___..._�. _.._._.. _ r t tlrrr t. UM + n COtICI.N A !J.!, .1,F. l ,al iir. It MASS If rl ATlOry ug/1 lb/day ug/1 lb/day u/1 lb/day ug/1 lb/day -_ g/1 lb/d4y ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 lb/day ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 .I . ,. 1;I ..tea♦ 0 <.21 < 10 <.21 < 10 <.21 10 <.21 10 < .21 10 <.21 10 < .21 0 .21 < 10 10 10 0 0 lb/day < 10 lb/day 10 b/day < 10, b/day < 11) b/day < 10 , 10 21 .21 A .21 21 21 .21 <.21 <.21 <.21 .21 21 21 <.21 1, ( OLLUTA r•I ArJ(1 Crli, fIli 1i'.1 ii Ci 1s TRACT' 0 ' 2(1. N r':ur© :oJirlu`nplamine ri) Phenanlhrcr•e (135•01 0) 450, Pyrene 1120000) 4L1d. 1,2,4 - Tr(• c nl ur ol,e n7 enu 120 02.11 rxr.r#v X• asw X X X MAXIMUM DAILY V A.I,.UL 1 t 1,1 AL CP11'C}t1N Gc/r1s FRACTION — I G` TICIDF.S 11', Aldrin (309 00 2) 2P (1 81-IC (3190461 3P. ji 91IC 131965 7) ar.}(IIIC (50 39 9) CtiC (319116 L') Cnluf,l.rne 157 74 9) 7P, 4,4'-DDT 150 211 31 '. P. 4 4'•L DE (72)59) 9;' 4a'DUD I72 54 01 1 OP. D.elUr .n 1(.0'57. 1) 11P. (I Cnau•:u Ilan 1115 29 7) 1'1'. /) Ln:1Osulla (115 2S1 7) 1 31' E nrinfullgn 11,r1� 11C31 07 31 En:1r,n 20E11 1'.r'. Ci• tr�n 10 <.74 `.74 `.74 <.74 Test No, of Analyses 1 ng Not Re' uired 4 (111'111S r, Or/CC rr 110ATIC7N LJ MASS ug/1 ug/1 ug/1 ug/1 1!ITAI;1 .��, I�ir r•r v,t I'I I ..r lb/day <10 lb/day <10 lb/day <10 lb/day' < 10 21 .21 <.21 <.21 is rrs rs )(Nit 4 OLLLITAWT Wastewater Collection Basin CT 57,3 PCfL1242 I(4)-21 i) PC©-1254 ,07 6-3-11 PC! 1221 ©: 2;1.21 PCC 1232 41.15-5) PCB-1;•la 72 .5 61 McGuire Nuclear Station C: f`L U! ^NT� A1LV VALUL No. of Testing Not Required II` Analyses 4 1.1i11:;;; ri MA . I N 1 1! 1'is NPDES Permit Modification #2 Permission to Release Radioactivity to the Catawba River Release of Radioactivity to the Catawba River Normally the McGuire Nuclear Station turbine building sumps are discharged to the conventional wastewater treatment (WC) system for treatment with chemical addition and aeration. The treated wastes are discharged to the Catawba River (discharge 002). Occasionally, the turbine building sumps become contaminated with radioactivity by various means including primary -to -secondary leaks and HVAC condensate drains. Sump discharges may continue to be released to the WC system, may be routed to the normal Liquid Radwaste System discharge line for release to the condenser cooling water (CCW), or may be routed to the Liquid Radwaste Collection tanks for processing prior to release. The selected path of release depends on the level of radioactivity, volume of radioactive wastes, NRC Technical Specification's processing requirements, potential for an oil spill, and the need to process chemical wastes. This permit modification request includes adding the Collection Basin (Wastewater Collection Basin, WWCB) as a permitted discharge point. One of the inputs to the WWCB is the unwatering of the CCW system for maintenance purposes. During the unwatering process, a 54-inch isolation valve between the two units leaks. This leakage sometimes allows processed liquid radwaste to contaminate the unwatering flow. The liquid radwaste has been processed to effluent limitations contained in 10CFR Part 20 and diluted by the CCW flow; it is diluted farther by the unwatering flow and the WWCB. All radioactive releases will be made in accordance with effluent release technical specifications. All radioactivity released from the site will meet the concentration and dose limitations specified in 10CFR Part 20, 10CFR Part 50, and McGuire Nuclear Station Operating License Technical Specifications. Attached is the NRC approval for releasing radioactivity to the Catawba River. The addition of this requested release path will not increase the quantity of radioactivity released from the station. The dose due to radioactivity from this requested release path (combination of the discharge from the WC and WWCB) will be limited to 41% of the maximum permissible concentration and will be added to the dose due to radioactivity released from the present release path (discharge 004). As such there will be no change to the health and safety of any member of the public. The additional release path will provide more flexibility to the manner in which contaminated wastes can be treated and released. The requested release path will not result in an increase in the discharge of any NPDES regulated pollutant. UNITED STATES NUCLEAR REGULATORY COMMISSION WASHINGTON, 0. C. 20555 June 5, 1987 Docket Nos.: 50-369 and 50-370 Mr. H. B. Tucker, Vice President Nuclear Production Cepartment Duke Power Company 422 South Church Street Charlotte, North Carolina 28242 Dear Mr. Tucker: Subject: Issuance of Amendment No. 72to Facility Operating License NPF-9 and Amendment No. 53to Facility Operating License NPF-17 - McGuire Nuclear Station, Units 1 and 2 (TAGS 61179/61180) The Nuclear Regulatory Commission has issued the enclosed Amendment No, 72 to Facility Operating License NPF-9 and Amendment No. 53to Facility Operating License NPF-17 for the McGuire Nuclear Station, Units 1 and 2. These amend- ments consist of changes to the Technical Specifications in response to your application dated March 19, 1986, as supplemented December 3, 1986, and June 4, 1987. The amendments change Technical Specification Figure 5.1-4 to add another discharge point from the Conventional Wastewater Basin into the Catawba River. The amendments are effective as of their date of issuance. A copy of the related safety evaluation supporting Amendment no.72 0 Operating Facility Operating License NPF-9 and Amendment No. Facility p g License NPF-17 is enclosed. Notice of issuance of amendments will be included in the Commission's next bi-weekly Federal Register notice. Sincerely, 1, Darl Hood, Project Manager Project Directorate II-3 Division of Reactor Projects-I/II Enclosures: 1. Amendment No. 72 to NPF-9 2. Amendment No.53 to NPF-17 3. Safety Evaluation cc w/enclosures: See next page Mr. H. B. Tucker Duke Power Company cc: Mr. A.V. Carr, Esq. Duke Power Company P. 0. Box 33189 422 South Church Street Charlotte, North Carolina McGuire Nuclear Station Dr. John M. Barry Department of Environmental Health Mecklenburg County 1200 Blythe Boulevard 28242 Charlotte, North Carolina 28203 County Manager of Mecklenburg County 720 East Fourth Street Charlotte, North Carolina 28202 Mr. Robert Gill Duke Power Company Nuclear Production Department P. 0. Box 33189 Charlotte, North Carolina 28242 J. Michael McGarry, III, Esq. Bishop, Liberman, Cook, Purcell and Reynolds 1200 Seventeenth Street, N.W. Washington, D. C. 20036 Senior Resident Inspector c/o U.S. Nuclear Regulatory Commission Route 4, Box 529 Hunterville, North Carolina 22078 Regional Administrator, Region II U.S. Nuclear Regulatory Commission, 101 Marietta Street, N.W. Suite 2900 Atlanta, Georgia 30323 L. L. Williams Area Manager, Mid -South Area ESSD Projects Westinghouse Electric Corporation MNC West Tower - Bay 239 P. 0. Box 355 Pittsburgh, Pennsylvania 15230 Chairman, North Carolina Utilities Commission Dobbs Building 430 North Salisbury Street Raleigh, North Carolina 27602 Mr. Dayne H. Brown, Chief Radiation Protection Branch Division of Facility Services Department of Human Resources 701 Barbour Drive Raleigh, North Carolina 27603-2008 UNITED STATES NUCLEAR REGULATORY COMMISSION WASHINGTON, D. C. 20555 DUKE POWER COMPANY DOCKET NO. 50-369 McGUIRE NUCLEAR STATION, UNIT 1 AMENDMENT TO FACILITY OPERATING LICENSE Amendment No. 72 License No. NPF-9 The Nuclear Regulatory Commission (the Commission) has found that: A. The application for amendment to the McGuire Nuclear Station, Unit 1 (the facility) Facility Operating License No. NPF-9 filed by the Duke Power Company (the licensee) dated March 19, 1986, as supplemented December 3, 1986 and June 4, 1987, complies with the standards and requirements of the Atomic Energy Act of 1954, as amended (the Act) and the Commission's rules and regulations as set forth in 10 CFR Chapter I; 8. The facility will operate in conformity with the application, as amended, the provisions of the Act, and the rules and regulations of the Commission; C. There is reasonable assurance (i) that the activities authorized by this amendment can be conducted without endangering the health and safety of the public, and (ii) that such activities will be conducted in compliance with the Commission's regulations set forth in 10 CFR Chapter I; C. The issuance of this amendment will not be inimical to the common defense and security or to the health and safety of the public; and E. The issuance of this amendment is in accordance with 10 CFR Part 51 of the Commission's regulations and all applicable requirements have been satisfied. Accordingly, the license is hereby amended by page changes to the Technical Specifications as indicated in the attachments to this license amendment, and Paragraph 2.C.(2) of Facility Operating License No. NPF-9 is hereby amended to read as follows: (2) Technical Specifications The Technical Specifications contained in Appendix A, as revised through Amendment No. 72 are hereby incorporated into the license. The licensee shall operate the facility in accordance with the Technical Specifications and the Environmental Protection Plan. This license amendment is effective as of its date of issuance. FOR THE NUCLEAR REGULATORY COMMISSION B. J. 'Youngblood, Director Project Directorate II-3 Division of Reactor Projects-I/II Attachment: Technical Specification Changes Date of Issuance: June 5, 1987 UNITED STATES NUCLEAR REGULATORY COMMISSION WASHINGT©N, D. C. 20555 DUKE POWER COMPANY DOCKET NO. 50-370 McGUIRE NUCLEAR STATION, UNIT 2 AMENDMENT TO FACILITY OPERATING LICENSE Amendment No. 53 License No. NPF-17 The Nuclear Regulatory Commission (the Commission) has found that: A. The application for amendment to the McGuire Nuclear Station, Unit 2 (the facility) Facility Operating License No. NPF-17 filed by the Duke Power Company (the licensee) dated March 19, 1986, as supplemented December 3, 1986 and June 4, 1987, complies with the standards and requirements of the Atomic Energy Act of 1954, as amended (the Act) and the Commission's rules and regulations as set forth in 10 CFR Chapter I. B. The facility will operate in conformity with the application, as amended, the provisions of the Act, and the rules and regulations of the Commission; C. There is reasonable assurance (i) that the activities authorized by this amendment can be conducted without endangering the health and safety of the public, and (ii) that such activities will be conducted in compliance with the Commission's regulations set forth in 10 CFR Chapter I; !. The issuance of this amendment will not be inimical to the common defense and security or to the health and safety of the public; and E. The issuance of this amendment is in accordance with 10 CFR Part 51 of the Commission's regulations and all applicable requirements have been satisfied. 2 Accordingly, the license is hereby amended by page changes to the Technical Specifications as indicated in the attachments to this license amendment, and Paragraph 2.C.(2) of Facility Operating License No. NPF-17 is hereby amended to read as follows: (2) Technical Specifications The Technical Specifications contained in Appendix A, as revised through Amendment No.53, are hereby incorporated into the license. The licensee shall operate the facility in accordance with the Technical Specifications and the Environmental Protection Plan. This license amendment is effective as of its date of issuance. FOR THE NUCLEAR REGULATORY COMMISSION (--41.4jer oungblo d, Director Pro?�ec Directorate II-3 Division of Reactor Projects-I/II Attachment: Technical Specification Changes Date of Issuance: June 5, 1987 ATTACHMENT TO LICENSE AMENDMENT NO. 72 FACILITY OPERATING LICENSE NO. NPF-9 DOCKET NO. 50-369 AND TO LICENSE AMENDMENT NO. 53 FACILITY OPERATING LICENSE NO. NPF-17 DOCKET NO. 50-370 Replace the following page of the Appendix "A" Technical Specifications with the enclosed page. The revised page is identified by Amendment number and contains vertical lines indicating the area of change. Amended Page 5-5 FIGURE 5.1-4 SITE BOUNDARY FOR LIQUID EFFLUENTS GUIRE NUCLEAR STATION McGUIRE - UNITS 1 and 2 ,5-5 Amendment No. 72 (Unit 1) Amendment No. 53 (Unit 2) UNITED STATES NUCLEAR REGULATORY COMMISSION WASHINGTON, D. C. 20555 SAFETY EVALUATION BY THE OFFICE OF NUCLEAR REACTOR REGULATION RELATED TO AMENDMENT NO. 72 TO FACILITY OPERATING LICENSE NPF-9 AND AMENDMENT NO. 53 TO FACILITY OPERATING LICENSE NPF-17 DUKE POWER COMPANY DOCKET NOS. 50-369 AND 50-370 McGUIRE NUCLEAR STATION, UNITS 1 AND 2 INTRODUCTION Existing Technical Specification (TS) 3.11.1.1 and its referenced Figure 5.1-4, "Site Boundary for Liquid Effluents" define the authorized discharge point for radioactive material released in liquid effluents to unrestricted areas as being only to Lake Norman, an upstream impoundment of the Catawba River. By letter dated March 19, 1986, Duke Power Company (the licensee) requested a change to the TSs for McGuire Nuclear Station, Units 1 and 2. This proposed change would modify Figure 5.1-4 to add a new release point for radioactive liquids and thereby permit the release of liquids containing trace quantities of radio- activity into the Catawba River, via the conventional waste water treatment system. The change would affect only the discharge location, and would not increase existing TS limits regarding (1) the quantity of radioactive material contained in the treatment pond, (2) allowable doses to the public from releases to unrestricted areas, and would not decrease existing TS requirements regarding liquid discharge monitoring. The licensee provided additional information to support the request by letters dated December 3, 1986 and June 4, 1987. The change would be accomplished by deleting from TS Figure 5.1-4 an existing, obsolete footnote which authorized a one-time discharge to the Catawba River on June 20, 1986, but retaining the existing arrow at the river and its label, "Liquid Waste Discharge Point." (The existing arrow, label, and footnote were added in response to a separate application by the licensee submitted subsequent to the March 19, 1986 request.) EVALUATION The McGuire plant is designed to release radioactive liquid effluents to Lake Norman and effluent controls are based on the concentrations of activity at the point of release to Lake Norman. The outflow from Lake Norman is into the Catawba River. Conventional ("non -radioactive") waste water is released through another discharge point directly to the Catawba River. Water from the turbine building sump is normally released through the conven- tional wastewater treatment system. The quantity of radioactive material contained in each treatment pond, and in each batch of slurry (used power resins) to be transferred to the treatment ponds, is limited consistent with 10 CFR 20, Appendix B, Table II by existing TS 3/4.11.1.5 and is not changed 2 by these amendments. There are provisions for releasing turbine building sump water through the liquid radwaste system if the sump water is contaminated with radioactivity. The liquid radwaste system is capable of processing 27,500 gpd, whereas the turbine building sumps can add up to 120,000 gpd during operation with primary to secondary leakage. Thus, the liquid radwaste system is not capable of handling the turbine sump discharge on a continuing basis as would be required by the present technical specifications if there were small steam generator tube leaks. Furthermore, when low levels of radioactivity are detected in a large pond (e.g., in one of the two 2.5 million gallon settling ponds of the conventional wastewater treatment system) release through the liquid radwaste system is impracticable. The licensee investigated several alternatives to the proposed additional release point and concluded that other possible solutions were unduly costly and were unwarranted in view of the low levels of radioactivity and doses involved. Therefore the licensee requested approval to release low level liquid radwaste through the conventional wastewater treatment system. The TS change does not decrease the existing monitoring requirements (TS 3.3.3.8 and referenced TS Table 3.3-12) which assure that instantaneous radioactive release rates remain within 10 CFR 20, Appendix B limits, and that radioactive liquid effluent monitoring instrumentation remains operable or appropriate compensatory action taken. There are provisions for sampling and monitoring the water going into, and being released from, the conventional waste water system. The licensee has committed to make these measurements with the sensitivity necessary to assure that the concentrations are below the levels needed for compliance with the dose design objectives of 10 CFR 50 Appendix I. Specifically, the licensee committed to maintaining a lower limit of detection of 0.1 pCi/L or less for Cs-137. These provisions satisfy General Design Criterion 64 which require that a means be provided for monitoring effluent discharge paths. The dose or dose commitment to a member of the public from radioactive materials in liquid effluents released from each McGuire unit is limited consistent with 10 CFR 50, Appendix I by existing TS 3/4.11.1.2 and is not changed by these amendments. The licensee has committed to ensuring that the use of this new release point does not increase the total permitted release from the station. To accomplish this, doses at both the new and old release points will be added and the total will be maintained below the limits of Technical Specification 3.11.1.2. The concentration of radioactive material released in liquid effluents to unrestricted areas is limited consistent with 10 CFR 10, Appendix B, Table II by existing TS 3/4.11.1.1 and is not changed by these amendments. The change also, will not increase the concentration of radioactivity in the Catawba River. The radioactive material that is released to Lake Norman reaches the Catawba River after some delay. Use of the new release point is a more direct release path for some of the material into the River. This will lower concentrations in Lake Norman without materially changing the concentrations in the River. This is true because almost all of the activity released by the new pathway will be relatively long lived (i.e. tritium and Cs-137) which are not affected by the delay. Also in the low concentrations permitted by the technical specifications the short lived materials are inconsequential. The staff concludes that this proposed technical specification change is in accordance with release requirements of 10 CFR Part 50.36a, Part 50 Appendix I and 10 CFR 20 Appendix B; and in accordance with 10 CFR Part 50 Appendix A, General Design Criterion 64 requirements for monitoring radioactivity releases. The change does not increase the liquid effluent release rates or the annual dose resulting from station liquid effluent releases. Thus, although the effluent release path is changed, neither the dose, quantity nor concentration of radioactive effluent in the River is changed. Therefore the proposed change is acceptable. ENVIRONMENTAL CONSIDERATION These amendments involve changes to the installation or use of facility com- ponents located within the restricted area as defined in 10 CFR Part 20. The staff has determined that the amendments involve no significant increase in the amounts, and no significant change in the types, of any effluents that may be released offsite and that there is no significant increase in individual or cumulative occupational exposure. The NRC staff has made a determination that the amendments involve no significant hazards consideration, and there has been no public comment on such finding. Accordingly, the amendments meet the eligibility criteria for categorical exclusion set forth in 10 CFR 51.22(c)(9). Pursuant to 10 CFR 51.22(b) no environmental impact statement or environmental assessment need be prepared in connection with the issuance of these amendments. CONCLUSION The Commission made a proposed determination that the amendments involve no significant hazards consideration which was published in the Federal Re ister (51 FR 36088) on October 8, 1986. The licensee's subsequent submitia s ate December 3, 1986, and June 4, 1987, do not alter the scope of the licensee's requested amendments as described in the October 8, 1986 Federal Rye ister; nor do they affect the Commission's proposed no significant hazards cons ation determination. The Commission consulted with the state of North Carolina. No public continents were received, and the state of North Carolina did not have any comments. We have concluded, based on the considerations discussed above, that: (1) there is reasonable assurance that the health and safety of the public will not be endangered by operation in the proposed manner, and (2) such activities will be conducted in compliance with the Commission's regulations, and the issuance of these amendments will not be inimical to the common defense and security or to the health and safety of the public. Principal Contributors: D. Hood, PD#II-3 C. Willis, PRPB Dated: June 5, 1987 NPDES Permit Modification #3 Application for Clean Water Act Section 311 Exemption Application for Clean Water Act Section 311 Exclusion In relation to oil and hazardous substance liability, the Clean Water Act Section 311 defines "discharge" as "include[s] but is not limited to, any spilling, leaking, pumping, pouring, emitting, emptying or dumping but excludes ... (B) discharges resulting from circumstances identified and reviewed and made a part of the public record with respect to a permit issued or modified under section 402 of this Act, and subject to a condition in such permit ..." [311 (a) (2) ] . The implementing regulations promulgated by the Environmental Protection Agency specifies "[a] discharge results 'from circumstances identified...and subject to a condition in such permit,' whether or not the discharge is in compliance with the permit, where: (1) the permit application, the permit, or another portion of the public record contains documents that specifically identify: (i) The substance and the amount of the substance; and (ii) the origin and source of the substance; and (iii) The treatment which is to be provided for the discharge either by:...(B) A treatment system designed to treat the permittee's normal discharge and which is additionally capable of treating the identified amount of the identified substance...and (2) The permit contains a requirement that the substance and amounts of the substance...be treated...in the event of an on -site release; and (3) The treatment to be provided is in place." [40CFR117.12 (c)]. Following is a description of the treatment provided by each of the McGuire Nuclear Station treatment systems and the substances on site that will be treated by that system in the event of an on -site release. Part of the substances are maintained and used at multiple locations and therefore may be released through more than one treatment system. The inventory data system lists the total quantity of the substance that is on site. Therefore, the total quantity of the substance on site is listed for each treatment system through which it can be discharged. In the event of a spill, the total quantity listed will probably not be released. Discharge 001-Condenser Cooling Water (CCW, RC) Condenser Cooling Water is drawn from Lake Norman. It is pumped through the condensers and component heat exchangers and discharged back into Lake Norman. In addition to removing heat, it provides natural neutralization and dilution. Oil booms are placed across the discharge canal to prevent the discharge of oil. Maximum flow is 2.8 billion gallons per day. Attached are the chemical substances that can be discharged via the condenser cooling water. MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH RC PRODUCT NAME ACETONE, ACS GRADE; (P/N: A-184): ARMSTRONG'S 520 ADHESIVE: BRAWN: CLOVER LAPPING COMPOUND: CP-52 CHIL LAG: CP-82 CHIL-STIX F-R-N: CRC 5-56 PENETRANT; (P/N 05004, CR&W P/N 556): DIESEL FUEL OIL 12: DYKEM STEEL BLUE; (P/N DX-100): FOSTER 85-20; SPARK-FAS ADHESIVE: GENERAL PURPOSE ADHESIVE ^77^: HYDRAZINE SOLUTION (54%): M & S STRIP -IT: METAL POLISHING COMPOUND; (P/N 41500): MOLYKOTE G-RAPID SPRAY; (P/N 87504-24): MOLYKOTE PENE-LURE SPRAY; (AEROSOL): MOLYKOTE 111: MS-450 PROTECTIVE VARNISH: NEVER-SEEZ PURE NICKEL SPECIAL NUCLEAR GRADE: PAINT, 1200 PRIME COAT, RED: PAINT, 1201 PRIMER: PLACCO RA-6602: RUGBEE SOIL RELEASE CONCENTRATE; (P/N 1368-001): TAP MAGIC CUTTING FLUID: TERESSTIC 32: TERESSTIC 46: VARSOL C OIL SOLVENT VARSOL 1; (FISHER P/N S4574): 6500/6200 DRUM CLEANING SOLVENT; (P/N 43P63): 702 DIFFUSION PUMP FLUID: 704 DIFFUSION PUMP FLUID; (P/N 837-5): AMOUNT 32.97 GAL 12.00 GAL 45.00 GAL 87.69 GAL 5.00 GAL 2.00 GAL 4.25 GAL 206000 GAL 7.79 GAL 3.00 GAL 5.00 GAL 992.80 GAL 220.00 GAL 3.30 GAL 0.11 GAL 75.79 GAL 39.28 LBS 5.63 GAL 80.00 LBS 0.21 GAL 0.13 GAL 2.00 GAL 135.00 GAL 147.66 GAL 60069 GAL 995.75 GAL 21.00 GAL 0.25 GAL 0.26 GAL 6.20 GAL Discharge 002 - Conventional Wastewater Treatment System (WC) The Conventional Wastewater Treatment System treats waste through a system of basins with chemical additions and aeration. Wastes are initially directed to the initial holdup pond where primary sedimentation occurs. This 200,000 gallon capacity basin has a retention time of 12 to 24 hours and acts as a surge tank to prevent overloading and subsequent degradation of effluent quality throughout the remainder of the system. This pond can be bypassed depending on influent quality. The initial holdup pond is followed by parallel settling ponds. These two 2.5 million gallon ponds provide 6-12 day retention. The ponds are operated such that one pond is in service while the other is on standby. Coagulent aids may be used for settling lighter solids along with pH adjustment to neutralize or precipitate various chemical compounds. The wastewater then flows to the final holdup pond where it is aerated. This pond has a volume of one million gallons and a retention time of 5 days. The final holdup pond can be bypassed if the effluent from the settling basins are within specifications. The final effluent can flow by gravity or be pumped to the Catawba River with the pH adjusted with an automatic CO addition system. An oil trap is provided to prevent of spills to the receiving water. The holding capacity and recirculating capabilities designed into the treatment facility assure a high quality effluent to the Catawba River. Attached are the chemical substances that can be discharged via the conventional wastewater treatment system. MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH WC PRODUCT NAME ACETIC ACID, GLACIAL; (FISHER P/N A-38): 9.35 GAL ACETONE, ACS GRADE; (P/N: A-184): 32.97 GAL ALKALINE IODIDE-AZIDE REAGENT POWDER PILLOWS: 10.00 GALX 4.00 ALL CLIMATE HIGH VACUUM PUMP OIL: 16.11 LAS AMMONIUM CHLORIDE; (P/N A-661): AMMONIUM HYDROXIDE; (FISHER P/N A-669): 225.20 GAL ARMSTRONG'S 520 ADHESIVE: 12.00 GAL BELZONA MOLECULAR RELEASE AGENT: 0.19 GAL BUFFER SOLUTION, PH 4.00; (P/N SO-B-99(CONC) & 50-B-101) 4.38 GAL CL-371 LOW TEMPERATURE RADWASTE ANTIFOAM: 55.00 GAL CLOVER LAPPING COMPOUND: 87.69 GAL CP-52 CHIL LAG: 5.00 GAL CP-82 CHIL-STIX F-R-N: 2.00 GAL CRC 5-56 PENETRANT; (P/N 05004, CR&W P/N 556): 4.25 © GAL LAS CS CORROSION INHIBITOR: 206000225GAL DIESEL FUEL OIL 112: DIGESTION SOLUTION FOR COD, 0-150 PPB RANGE; (P/N 21258 0.32 GAL DYKEM STEEL BLUE; (P/N DX-100): 7.79 GAL FEL-PRO N-5000 NUCLEAR GRADE; (PART NO. 51269): 487.00 LBS FENSO 71; (P/N 390180 - 03746): 110.00 GAL FERRIC CHLORIDE; (FISHER P/N I-88): 0.52 LBS FIBRAX 370: 217.00 GAL FIRE -PREP 8256: 5.00 GAL FORMIC ACID; (P/N A-118): 0.38 GAL FOSTER 85-20; SPARK-FAS ADHESIVE: 3.00 GAL GEAR OIL; GX 85W-140: 97.00 GAL GENERAL PURPOSE ADHESIVE "77": 5.00 GAL HERMES CEMENT; (P/N 999-125): 9.38 GAL HYDRAZINE SOLUTION (54%): 992.80 GAL HYDROCHLORIC ACID; (FISHER P/N A-144): 11.311.88 GAL 01 GAL KEROSENE; (P/N K10-1*FISHER): 345.00 GAL KUTWELL 40; (P/N 350040 - 03777): LEAD/ACID STORAGE BATTERY, ANTIMONY: 11780 LBS LOW LEVEL SODIUM REAGENT; (P/N 15111/181153): 068 GAL GAL LYSOL LIQUID DISINFECTANT:72.00 M & S STRIP -IT: 220.00 GAL MARVEL MYSTERY OIL: 24.80 GAL METAL POLISHING COMPOUND; (P/N 41500): 3.30 GAL METHANOL; (FISHER P/N A-4124): 5.98 GAL METHYL ISOBUTYL KETONE; (P/N M-213): 5.64 GAL MOBIL SHC 824: 5317.8 GAL MOBIL 1 5W-30 OIL: 48.63 GAL MOLECULAR N.F. CLEANER/DEGREASER: 0.73 GAL MOLYKOTE G-RAPID SPRAY; (P/N 87504-24): 0.11 GAL MOLYKOTE PENE-LUBE SPRAY; (AEROSOL): 75.79 GAL MOLYKOTE 111: 39.28 LBS MOLYKOTE 44 GREASE; (P/N'S 16390-23 & 16390-79): 327.35 LBS MOTOR OIL; 10W-40: 332.00 GAL MS-450 PROTECTIVE VARNISH: 5.63 GAL MULTI -PURPOSE CLEANER; (M 8 S P/N 4790): 110.00 GAL NEOLUBE 12 DRY FILM CONDUCTIVE LUBRICANT: 302.10 GAL NEVER-SEEZ PURE NICKEL SPECIAL NUCLEAR GRADE: 80.00 LBS NITRAVER 6 NITRATE REAGENT; (P/N 14119): 100.00 PIL NITRIC ACID (BAKER P/N 4801); (FISHER P/N A200S, A200, A 11.05 GAL AMOUNT MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH WC PRODUCT NAME NUTO H-32 LUBRICANT; (P/N 363010-01335): NUTO H-68: PAINT, 1200 PRIME COAT, RED: PAINT, 1201 PRIMER: PHENYLARSINE OXIDE; (P/N 2205-16): PLACCO RA-6602: PLATINUM COBALT COLOR STANDARD; (P/N SO-P-120): POTASSIUM CHROMATE; (FISHER P/N P-220, P-220-3): POTASSIUM HYDROXIDE; (P/N P-250): POTASSIUM PERMANGANATE; (P/N P-279): PROPIONIC ACI➢; (P/N A-258): PRUSSIAN BLUE; (P/N 35): RANDO OIL HD 68; (P/N 01659): REAGENT SOLUTION W/DIFFUSION; (P/N 15-17-11): RED GAGE OIL; (P/N A103): RIGID DARK CUTTING OIL: RUGBEE SOIL RELEASE CONCENTRATE; (P/N 1368-001): SANURIL 115 CHLORINE TABLETS: SAVOGRAN STRYPEEZE SEMI PASTE: SCOTCHKOTE ELECTRICAL COATING; (P/N 80-6100-3260-1): SILVER NITRATE; (P/N 5-181): SODIUM BISULFATE; (P/N S-654/FISHER): SODIUM ELECTRODE RINSE SOLUTION; (P/N 15-11-13*18-11-40) SODIUM FLUORIDE; (P/N S-299/FISHER): SODIUM HYDROXIDE PELLETS; (P/N 5-318): SODIUM HYDROXIDE 50% SOLUTION; (FISHER P/N SO-S-254): SODIUM NITRITE; (P/N S-347/FISHER): SODIUM REFERENCE STANDARD SOLUTION; (P/N 50-S-139): SODIUM SULFHYDRATE; (P/N 5-423): SPARTAN EP 460 OIL; (P/N 475375 - 05375): SPARTAN EP-150 OIL: SPARTAN EP-220 OIL: SPARTAN EP-680 OIL: SPINESSTIC 22 LUBRICANT; (P/N 372038-01125): SULFURIC ACID (93%); (FISHER P/N A-300): SURETT N-80K OIL; (PIN N-8K): TAP MAGIC CUTTING FLUID: TERESSTIC 100; (P/N 376045 - 01180): TERESSTIC 150: TERESSTIC 220: TERESSTIC 32: TERE55TIC 46: TERESSTIC 68: TOLUENE; (P/N T-3245/FISHER): TRISODIUM PHOSPHATE; (P/N 5-377,5-376/FISHER): UNIREX N2 LUBRICATING GREASE: VACUUM PUMP PRECISION OIL; (CAT 1-69126): VARSOL C OIL SOLVENT VARSOL 1; (FISHER P/N S4574): W-INCONEL WELDING ROD 182: W-METCO 44 POWDER: W-METCO 447 POWDER: W-METCO 450 POWDER: W-METCO 451 POWDER: W-1/8 SIL FLO WIRE: AMOUNT 70.00 GAL 627.00 GAL 0.21 GAL 0.13 GAL 1.75 GAL 2.00 GAL 0.13 GAL 766.00 LBS 19.14 LBS 16.60 LBS 0.13 GAL 39.60 LBS 15.00 GAL 0.45 GAL 0.53 44.00 GAL 135.00 GAL 855.00 LBS 9.00 GAL 1.29 GAL 2.10 GAL 15.20 LBS 0.13 GAL 5.50 LBS 14.80 LBS 6058.3 GAL 2091.3 LBS 0.51 GAL 2.53 LBS 401.85 GAL 785.00 GAL 33.00 GAL 74.00 GAL 40.00 GAL 10264 GAL 237.00 LBS 147.66 GAL 55.00 GAL 1162.2 GAL 275.25 GAL 60069 GAL 995.75 GAL 4038.3 GAL 5.60 GAL 1920 LBS 558.59 LBS 22.50 GAL 21.00 GAL 20.00 LBS 5.00 LBS 5.00 LBS 5.00 LBS 5.00 LBS 15.00 LBS MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH WC PRODUCT NAME AMOUNT W-3/32 SIL FLO WIRE: XYLENE: ZERICE 46 OIL; (P/N 386040 - 02970): 6500/6200 DRUM CLEANING SOLVENT; (P/N 43P63): 702 DIFFUSION PUMP FLUID: 704 DIFFUSION PUMP FLUID; (P/N 837-5): 15.00 LBS 12.00 GAL 665.00 GAL 0.25 GAL 0.26 GAL 6.20 GAL Discharge 003 - Sanitary Waste Treatment System (WT) The sanitary waste treatment system is a four (4) cell aerated lagoon system. It provides approximately 5 day retention and allows for variable level discharge. Maximum volume (depth of 8 feet) is approximately 321,300 gallons. The first cell provides a two day retention and is kept in full suspension by surface mechanical aerators. The second and third cells provide one day retention each and are kept partially suspended providing for partial settling. The final cell is the settling cell and has a one day retention. Flow from the final cell is through a Sanuril chlorinator and a chlorine contact chamber. Discharge is into the Wastewater Collection Basin. Attached are the chemical substances that can be discharged via the sanitary waste treatment system. MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH WT PRODUCT NAME AMOUNT BRAWN: CLOROX LIQUID BLEACH: CRC 5-56 PENETRANT; (P/N 05004, CR&W P/N 556): KEPRO ETCHING SOLUTION; (KEPRO P/N E-1QT, E-1G, E-4G): LYSOL LIQUID DISINFECTANT: MOLYKOTE 44 GREASE; (P/N'S 16390-23 & 16390-79): MULTI -PURPOSE CLEANER; (M & 5 P/N 4790): TAP MAGIC CUTTING FLUID: 45.00 GAL 2.00 GAL 4.25 GAL 0.50 GAL 72.00 GAL 327.35 LBS 110.00 GAL 147.66 GAL Discharge 004 - Liquid Radwaste Treatment System (Radwaste, WL) The Liquid Radwaste Treatment system collects radioactively contaminated water from equipment drains, spills, or leaks within the auxiliary and reactor buildings. The system utilizes filters, evaporators, and ion exchange demineralizers for the treatment process. Releases are made to assure compliance with 10CFR Part 20 and 10CFR Part 50. Attached are substances that can be released via the Liquid Radwaste Treatment System. MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH RADWASTE PRODUCT NAME ACETIC ACID, GLACIAL; (FISHER P/N A-38): 32.979.35 GAL GAL ACETONE, ACS GRADE; (P/N: A-184): ALKALINE IODIDE-AZIDE REAGENT POWDER PILLOWS: 10.00BOX GAL ALL CLIMATE HIGH VACUUM PUMP OIL: 4.00 LAS AMMONIUM ACETATE CRYSTALS; (P/N C-64): 16.111LBS AMMONIUM CHLORIDE; (P/N A-661): AMMONIUM HYDROXIDE; (FISHER P/N A-669): 225.20 GAL 25.20 GAL ARKALONE P; (LIQUID): 2.50 GAL BENZENE; (P/N B-414, B-245): BUFFER SOLUTION, PH 4.00; (P/N SO-B-99(CONC) & SO-B-101) 4.381. GAL 211.0 CARBON TETRACHLORIDE: 0 GALAS CAZAR 2 GREASE; 20000 LBS CEMENT C-320: 1.50 GAL CHROMERGE; (P/N C-577): 87.69 GAL CLOVER LAPPING COMPOUND: COPPER REFERENCE STANDARD SOLUTION; (P/N SO-C-194): 0.40 GALLBS COPPER SULFATE; (P/N C-493, C-495): CRC 5-56 PENETRANT; (P/N 05004, CR&W P/N 556): 4.25 GAL GAL DAG; (P/N154): DESSICANT, INDICATING GEL; (P/N HDMI 103-6); 8.00 LBS GAL DYKEM STEEL BLUE; (P/N DX-100): FEL-PRO N-5000 NUCLEAR GRADE; (PART NO. 51269): 48©.00 LBS 00 LBS FERRIC CHLORIDE; (FISHER P/N I-88): 10.52 LBS FERRIC NITRATE; (P/N I-110): 1.10 LBS FERROUS AMMONIUM SULFATE; (P/N I-77): 217.00 GAL FIBRAX 370: 97.00 GAL GEAR OIL; GX 85W-140: GAL 4i HERMES CEMENT; (P/N 999-125): 999.38.3GAL HYDRAZINE SOLUTION (5): HYDROCHLORIC ACID; (FISHER P/N A-144): 11.311.88 GAL 8 GAL KEROSENE; (P/N K10-1*FISHER): LEAD REFERENCE STANDARD SOLUTION; (P/N SO-L-21): 0.13 GAL LEA➢/ACID STORAGE BATTERY, ANTIMONY: 11780 LBS 2.00 GAL LYSOL LIQUID DISINFECTANT: 220.007GAL M & S STRIP-IT:GAL 0.00 MARVEL MYSTERY OIL: 20.25 AS MERCURIC CHLORIDE; (P/N M-155): 10.25 LBS MERCURIC THIOCYANATE; (P/N M-197): 5.98 GAL METHANOL; (FISHER P/N A-4124): 5.64 GAL METHYL ISOBUTYL KETONE; (P/N M-213): 5354 GAL 31 MOBIL SHC 824: .8 GAL 4.63 MOBIL 1 5W-30 OIL: MOLYKOTE PENE-LOBE SPRAY; (AEROSOL): 39.28 GALLAS MOLYKOTE 111; MOLYKOTE 33 GREASE (P/N'S 14770-79 AND 14770-99): 1.28 GAL MOLYKOTE 44 GREASE; (P/N'S 16390-23 & 16390-79): 332.35 LBS 35 GAL MOTOR OIL; 10W-40: 302.10 GAL NEOLUBE #2 DRY FILM CONDUCTIVE LUBRICANT: NITRIC ACID (BAKER P/N 4801); (FISHER P/N A2005, A200, A 61105 GAL .05 GAL NUTO H-68: 8.10 GAL PETROLEUM ETHER; (P/N E139-4, E-139-5): 0.50 GAL PHOSPHORIC ACID; (P/N A-242):AL PLATINIZING SOLUTION; 0.50 19.14 GALL POTASSIUM HYDROXIDE; (P/N P-250): AMOUNT MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH RADWASTE PRODUCT NAME POTASSIUM PERMANGANATE; (P/N P-279): PRUSSIAN BLUE; (P/N 35): RIGID DARK CUTTING OIL: SCOTCHKOTE ELECTRICAL COATING; (P/N 80-6100-3260-1): SILVER NITRATE; (P/N 5-181): SILVER SULFATE; SODIUM BISULFATE; (P/N S-654/FISHER): SODIUM FLUORIDE; (P/N 5-299/FISHER): SODIUM HYDROXIDE PELLETS; (P/N 5-318): SODIUM HYDROXIDE 50% SOLUTION; (FISHER P/N SO-S-254): SODIUM NITRITE; (P/N S-347/FISHER): SODIUM REFERENCE STANDARD SOLUTION; (P/N 50-5-139): SPARTAN EP 460 OIL; (P/N 475375 - 05375): SPARTAN EP-150 OIL: SPARTAN EP-220 OIL: SPARTAN EP-680 OIL: SULFURIC ACI➢ (93%); (FISHER P/N A-300): SURETT N-80K OIL; (P/N N-8K): SYNESSTIC 32 OIL; (P/N 343101 - 03101): TAP MAGIC CUTTING FLUID: TERESSTIC 100; (P/N 376045 - 01180): TERESSTIC 150: TERESSTIC 220: TERESSTIC 32: TERESSTIC 46: TERESSTIC 68: TOLUENE; (P/N T-3245/FISHER): UNIREX N2 LUBRICATING GREASE: URANYL NITRATE; (P/N U-7): VACUUM PUMP PRECISION OIL; (CAT it-69126): XYLENE: AMOUNT 16.60 LBS 39.60 LBS 44.00 GAL 1.29 GAL 2.10 GAL 0.50 LBS 15.20 LBS 5.50 LBS 14.80 LBS 6058.3 GAL 2091.3 LBS 0.51 GAL 401.85 GAL 785.00 GAL 33.00 GAL 74.00 GAL 10264 GAL 237.00 LBS 322.00 GAL 147.66 GAL 55.00 GAL 1162.2 GAL 275.25 GAL 60069 GAL 995.75 GAL 4038.3 GAL 5.60 GAL 558.59 LBS 0.25 LBS 22.50 GAL 12.00 GAL Discharge 005 - Wastewater Collection Basin (Collection Basin, WWCB) The Wastewater Collection Basin is a 13.4 acre collection basin having a total capacity of approximately 40 million gallons; drawdown capacity is approximately 11 million gallons. The basin provides sedimentation, natural neutralization and skimming. Flow from the basin ranges from 0 to 15,000 gpm. Holdup is minimal; if the Standby Nuclear Service Water Pond is being flushed, no holdup of the basin is possible. The overflow from the basin mixes with the discharge from the WC system in a concrete apron and is discharged to the Catawba River downstream of Cowans Ford Dam. Attached are the chemical substances that can be discharged via the Wastewater Collection Basin. MCGUIRE NUCLEAR STATION POSSIBLE DISCHARGES THROUGH WWCB PRODUCT NAME ACETIC ACID, GLACIAL; (FISHER P/N A-38): 935 GAL GAL ACETONE, ACS GRADE; (P/N: A-184):32.97 ALKALINE IODIDE-AZIDE REAGENT POWDER PILLOWS: 10.00 GALX ALL CLIMATE HIGH VACUUM PUMP OIL: AMMONIUM ACETATE CRYSTALS; (P/N C-64): 16.111.10 LBS LBS AMMONIUM CHLORIDE; (P/N A-661): AMMONIUM HYDROXIDE; (FISHER P/N A-669): 225.20 GAL GAL BENZENE; (P/N B-414, B-245): BUFFER SOLUTION, PH 4.00; (P/N SO-B-99(CONC) 8 SO-B-101) 4.38 GAL CARBON TETRACHLORIDE: 1.00 GAL CHROMERGE; (P/N C-577): 1.50 GAL COPPER REFERENCE STANDARD SOLUTION; (P/N SO-C-194): 0.40 GAL COPPER SULFATE; (P/N C-493, C-495): 201.10 LBS 10 GAL DIESEL FUEL OIL #2: FERRIC CHLORIDE; (FISHER P/N I-88): 15.400.52 LBS LBS FERRIC NITRATE; (P/N I-110):1.10 LBS FERROUS AMMONIUM SULFATE; (P/N I-77): GAL GASOLINE, UNLEADED: 1100992.80 GAL HYDRAZINE SOLUTION (547): HYDROCHLORIC ACID; (FISHER P/N A-144): 11.311.88 GAL 01 GAL KEROSENE; (P/N K10-1*FISHER): LEAD REFERENCE STANDARD SOLUTION; (P/N SO-L-21): ©.13 3 GAL LAS MERCURIC CHLORIDE; (P/N M-155): 19.20 LBS MERCURIC THIOCYANATE; (P/N M-197):5.98 GAL METHANOL; (FISHER P/N A-4124): 5.64 GAL METHYL ISOBUTYL KETONE; (P/N M-213): NITRIC ACID (BAKER P/N 4801); (FISHER P/N A200S, A200, A 11.05 GAL PETROLEUM ETHER; (P/N E139-4, E-139-S): 8.10 GAL GAL PHOSPHORIC ACID; (P/N A-242): 0.180GAL PLATINIZING SOLUTION: POTASSIUM HYDROXIDE; (P/N P-250): 19.1,4 LBS POTASSIUM PERMANGANATE; (P/N P-279): 16.60 SILVER NITRATE; (P/N S-181): 0.502GAL AL LBS SILVER SULFATE; 10.50 LBS SODIUM BISULFATE; (P/N S-654/FISHER): 5.50 LBS SODIUM FLUORIDE; (P/N S-299/FISHER): 14.80 LBS SODIUM HYDROXIDE PELLETS; (P/N S-318): SODIUM HYDROXIDE 50% SOLUTION; (FISHER P/N SO-S-254): 6058.3 GAL SODIUM REFERENCE STANDARD SOLUTION; (P/N SO-S-139): 0.51 GAL SULFURIC ACID (937..); (FISHER P/N A-300): 102110264 GAL 4 GAL TERESSTIC 150: 1162.2 GAL TERESSTIC 68: TOLUENE; (P/N T-324S/FISHER): 5.60 GAL URANYL NITRATE; (P/N U-7): 0.25 LBS VACUUM PUMP PRECISION OIL; (CAT *-69126): 12.0022.50 GAL GAL XYLENE: AMOUNT Plot Plan McGuire Nuclear Station NPDES Discharge Locations LAKE NORMAN COWANSFORD DAM CATAWBA RIVER INTAK ASTE WATER COLLECTION BASIN 004 001 SCHARGE WASTE RELEASE POINT SNSW POND *Requested modifications McGUIRE NUCLEAR STATION DISCHARGE POINTS DUKE POWER COMPANY P.O. sox 33188 cruom T 1 . N.G. 28242 HAL a. TI:GKER 'ICE ►AEAED W T C^I. PIPDOCC1101. September 29, 1987 Dr. George T. Everett, Chief Water Quality Section Division of Environmental Management Department of Natural Resources and Community Development P.O. Box 27687 Raleigh, N.C. 27611 SUBJECT: McGuire Nuclear Station NPDES Permit Modification File: MC-702.13 Dear Sir: TLLEPHONT 1704) :773-453I On several occasions we have discussed various discharges from our McGuire Nuclear Station with your staff. As a result, we have decided to request that the McGuire NPDES permit (NC0024392) be modified. The modifications include (1) re -permitting the Collection Basin and (2) allowing very low-level radioactivity to be discharged into the Catawba River below Cowans Ford Dam, and (3) applying for a Clean Water Act Section 311 exemption. Attached is the information substantiating the request. Re -permitting the Collection Basin will alleviate the necessity of case -by -case approvals for condenser cooling water system unwatering. Permitting very low-level radioactivity to be discharged into the Catawba River will result in no increase in the quantity or dose of radioactivity released from the station; therefore the health and safety of the public will not be impacted. Enclosed please find a check (No. 311792) for $100.00 for the permit processing. Also enclosed is a sketch of the station showing all discharge locations. We would appreciate the opportunity to discuss the specifics of our request with you while you are developing the modification. Should you have any questions or desire additional information, please contact R.T. Simril ((704) 373-2310] or W.T. Griffin ((704) 373-5764]. Sincerely, % H.B. Tucker, Vice President Nuclear Production Department WTG/rhm Attachment xc: D.H. Brown, Department of Human Resources Document Control Desk, NRC bc: W.A. Haller E.O. McCraw M.L. Birch J.C. Painter R.W. taker D.W. Phillips N.A. Rutherford M.E. Bridges J.E. Lansche Staff O.N. Hamilron MC-2002.02-01 W.M. Funderburke DUKE POWER COMPANY. NUCLEAR PRODUCMON DEPARTMENT P.O. H©X 33189, 422 SOUTH CHURCH STREET CHARLOTTE. N.C. 28242 (704) 373-4011 April 1, 1988 Mr. Charles Wakild, Chief Water Quality Section Division of Environmental Management Department of Natural Resources and Community Development P. O. Box 27687 Raleigh, N. C. 27611 Attention: Mr. Dale Overcash Subject: McGuire Nuclear Station NPDES Permit Modification File: MC-702.13 Dear Sir: On September 29, 1987 we requested that the McGuire Nuclear Station NPDES permit (NC0024392) be modified. The requested modifications included (1) re -permitting the Collection Basin, (2) allowing very low-level radioactivity to be discharged into the Catawba River below Cowans Ford Dam, and (3) applying for a Clean Water Act Section 311 exemption. On November 17, 1987 we met with your personnel to discuss our request. As a result of our discussion we desire to amend our modification request. With this letter, we withdraw part 2 of our modification request. Another in- depth review of the regulations and additional discussions with our legal staff indicated that radioactive waste releases regulated by the Nuclear Regulatory Commission are not subject to state regulation under the water program, Northern State Power Co. V. Minnesota, 447 F. 2d 1143 (1971), aff'd. 405 U.S. 1035, 92 S. Ct. 1307, 31 L. Ed. 2d 576 (1972). In view of this regulatory interpretation and the distinction between NRC and EPA/state authority, we withdraw the request for your approval to allow very low-level radioactivity to be discharged into the Catawba River below Cowans Ford Dam. Additionally, in 1983 an instream administrative limitation was approved by the Department of Natural Resources and Community Development for hydrazine. The limitation was 0.06 mg/l. We desire to incorporate this currently approved administrative limit into the NPDES permit. The limitation applies instream to Lake Norman and the Catawba River below Cowans Ford Dam, depending on the release pathway. Since 1983, the regulatory climate has changed and there are overlapping regulatory requirements. It is for this reason that we request the hydrazine administrative limitation be formally incorporated into Part III of the NPDES permit. Procedures are in place to assure compliance with the above mentioned limit. We will submit the procedures to you for your review should you desire. Mr. Charles Wakild, Chief April 1, 1988 Page Two Once completed, we would appreciate the opportunity to discuss the draft permit with you prior to it going to public notice. Should you have any questions or desire additional information, please contact R. T. Simril [(704)373-2310] or M. C. Griggs [(704)373-7080]. Sincerely, W. A. Haller, Manager Nuclear Technical Services WTG/1518/sbn xc: D. H. Brown, Department of Human Resources Document Control Desk U. S. Nuclear Regulatory Commission Washington, D. C. 20555 Mr. Charles Wakild, Chief April 1, 1988 Page Three bxc: R. E. Baker G. M. Barker S. Biswas M. E. Bridges C. C. Brown R. W. Eaker W. M. Funderburke J. E. Lansche E. 0. McCraw D. W. Phillips G. S. Rice R. 0. Sharpe Staff MC-2002.02-01 State of North Carolina Department of Natural Resources and Community Development Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27611 James G. Martin, Governor S. Thomas Rhodes, Secieury Mr. W. A. Haller, Manager Nuclear Technical Service Duke Power Company P. O. Box 33189 Charlotte, NC 28242 Dear Mr. Haller: May' 5, 1988 R. Paul Wilms Director SUBJECT: NPDES Permit No. NC0024392 Biocide Additives Duke Power Company -McGuire Nuclear Station Mecklenburg County The Division of Environmental Management has reviewed the information in the letter of April 11, 1988, concerning the use of chlorine (as sodium hypochlorite) in the cooling water at your facility. Our review has found that the chlorine should be appropriate for use in your application. Therefore, the Division of Environmental Management grants approval to Duke Power Company for the use of the above mentioned additive in its cooling water. Should youplan to change to a different additive in the future, you should contact this office and submit the appropriate information prior to the change. If you have any questions, please contact Mr. Dale 0vercash at 919/733-5083. cc : 0141.11110Miwak Mr. Steve Tedder Mr. Pale Overcash Pollution Prerrntion Pay, P.O. Box 27687, Raleigh, North Carolina 27611-7687 Telephone 919-733-7015 An Eaual Opporruniry Affirmative Action Emolover -LUTANT • r. UL.maila 2 rr: LUCHT lb. MAXIMUM! 34,) • 1.1.A.Y.Latua; DAILY v/ILLU 11 .82 8538.92 CCW . • v A7C151, 1.1 C.A.0 4 t tit. . 111 ••• AS, J. Norco A:LALlISES. . U 1 a CUNCI. THAT ION b/day a LON.; Irt 48,4 1.1 .91 7530.96 I4 NU t..” rwv- iune -0,313.0 Oct 3.95 2.3 7.2 41132.63 23950.64 74975.9 .04 416.53 1248.6 VALUE_ 1055.1 2.5 20689.5 L,ALUL 992.3 1 22 62 May 7.11 lb/day lb/day lb/day VAL .4t: 20.3 V ALUE 20.3 10.1 31 'C VALUt. 00 311.14 1 4 U U1 6.4 84 A IMUNI 8.5 V A LUE 26.1. VALUE 21.6 31 GC • 4.1A): MAU 61 x 334 :3 1 .4, 4 ------. 11..''. 3 El•tit, ,14 i i`t7LUC‘31 I. . LC:i. l"0-".1 7ti, I WCt'..t .i., X _ <2 1 ... 1.0 10413.32 .11,4 1,A2' laA.:th!tber i 1 lid a on 1 V ILtltrL lure Ler) Dvcomber 1961 (L)la only 4. U1111-.71 No/100m 2.2 2.5 .05 VALUL 88 _18206.72 20689.5 413.79 992.3 VALUC 9.4 VAL 19.5 2 4 !fl 141- m9/1 lb/ddy ./6 (0119.59 22 1 31 fFl_U(NT 4. UNITS INTAKC" 1 • 1XC14 C U T- ALIT AN13 CAS NO. ••ir ,.•r x L .�iu :•- a. MAXIMUM IJAILY VALUC L,MAXIMUM SQ(,AV VALUt. C�L[l 1X G.T tlM AY)I �.• VALUE a ttO.0 t A tIAL- YI• ., [tItXGCte T/txllcl.t t1 MxS.$ A t .t+ IIM f, nvt 11Ai.1 tl,l..,c tatx A+ �.i Y I x � L ..---- -11 CUX•.C#wl•• 00. 1.1 r••• Tr (pw.(X nf••f.f rr 1.1 ..... tf1MC#toXM.•XIPaa ., ..... IEi C{MMC•X.Y•4X.4w 111 w.•X it Nltrog.n, I©/y.nlc <. 1 <1041. 33 1 111q/ 1 1llday < r 1 82 .58 h. 011 end a1••N x 4 x `"tl•,IX6#"• .08 833.06 lb/day .08 662.06 't►1 Alyll•, "l0l•1 x <.26 1 pCi/1 .43±.16 Tolwl x 2.72+.29 1 pCi/1 2.4+.28 1 x < 8,5 1 pCi/1 <8.5 toy •,.n um x < <.5 1 1 l)Ci/1 + Sult•14 01 . 5.8 60397.28 Itlg/1 lb/day 10 82757.82 1:j• 9 I. Sulfa• tom S) x x m. S'i1I11• flu Sujl 114245 45 3) X X n Su11•cs.nta X x o. Aluminum, l u 1.1 4,42090 51 x ,11 1145.5 1 1tig/1 lb/day .J7 579.30 1 1 n Uolium, 1u1•I )I4111]9.31 X .01 104.13 1 t11g/1 lb/day .01 82.8 ,. 4 tluton, Tu1.l )i44042 a) X .03 312.40 l lit]/l lb/day .02 ,.-1 G' 1u1.) l?440.40 4) x X • lion, Total 1)43911961 x 34 3540.5 14 1158.6 10 11Iq%1 1b/d y .14 1, AI•yn.tlum, luul )I4]99. 41 X 1 . 2 12495.99 .1- MUIvLJ.num, luial 1/43 90 11 , X 1`_ 171".,/I, 1 lia3a9L51 % .007 72.889 y 11,/,1,�,� .__.LliJfs_..,.._.._ x ri .a. 1111, 10101. 1)440 31 L1 x "��,,.�,., � 1 �III1fl TA AS Station Name McGuire Nuclear Su 2 t$AIiK 'i:• utfall,Numbe 001 C 4. U S. 1NLA jLS. CYANIDE, AND T 411440 20 01 Tulrl o.1n2) 11, 1. 40 41 )1 C4.►.,1..,. .111 14a 43 91 41.i.•n.,..n 1111440 41' 31 C JPPa« T.+la1 ,u 50 0) I ..U, TuI+I .► 9) GI 1.1.I1.u1y, Told IS hl b) • 11,ck rl. To111 Ili 0► SCIVr.1,,..1, .107:124921 :i.N4t, Total i0 22 41 I TI,JIb...n, Ili (1440 20 01 3,nc, Total 10 tat lit I. C r an.J.r, ,1151 I[ 5) 1. f 1.l:nol/, x x MAXIMUM DAILY VALUI fA AYIi C.. VALUC f.0 G► 1.1 iE NOLS <2 .002 <.001 .40 .80 .001 1:00 .20 5.00 5.00 <20826.6 20.8 <10.41 4.2 8.3 10.41 10:41 2.08 52.06 52.06 <.1 30:00 <.001 .005 <1041 .002 .22 .55 .001 1.00 .11 5.00 5.00 I:1 16.55 1.8 4.6 8.27 8.27 .91 ALAI.- GONCCN 13. MAS Y SLS TRATION 10 10 10 mg/1 mg/1 ug/1 ug/1 10 10 10 ug/ 1 ug/1 b/day lb/day lb/day lb/day lb/day lb/day b/day ug/1 41.38 41.38 10 10 1 10413.32 312.40 <10.41 52.06 6.24 51.64 1 10 1 ug/1 Ug/ 1 mg/ 1 lb/day lb/day lb/day lb/day mg/1 lb/day ug/1 lb/day mg/1 .lb/day mg/1 lb/day l:'l.(. 1. IIrA -AIj E-I A(:1... V.11 IJ.. 1.1 r..,..tl.. <2 002 .001 .22 .55 .001 1.00 5.00 5.00 <.1 6.24 .001 .005 16551.6 16.55 8.28 1.8 4.6 27 27 .91 41.38 41.38 1. I.t) A i. .. I 0 1 10 10 10 10 i27. 58 1 275. h. 1 1 64 10) 8«27 1 41.3t3 ►A1f1 Iit 1.•1 a • 0. (1 I I.-1 U 1 Ts 1'OLL/JT AlIT l,111"1 0. AS 1/".1IOC It J I"I 1 1 IAt:MI 4 drill S !I1S PfiACI I%iJ - 1,0 !., . .I1,'.0 1: 02 2) p:.ylnn,u Je . 1) IJ 1) I.rn:11:nC i.1 .1 U.i . i1:1.In1- 11..1. [Il,c/ ,4l`: 1) 1,1 .4.,(111LIun Cn1..:QI.C' LnU i.;L.J J) ?.CI.I.IQ E:her IL It 111 •1 CI.1oIQl111In (,. -1 ., .; •c111L10 ': 41 p. ,ra.rrtr.°:Ir,l r.0 11 J. 1.1 Orudclo .u.1, 1 JS 34 31 / �..° ;:U) GG 2) /. 1,I G.cnw,u• rime 176 / 0,2 0.4.1.110,0 ,•.i.IitlU7!) 1. 1,2 O..I.Ioio opleve 2 Jf. GI l 11.04,Int.•ne U•,1 •1 ,'.TILL COI. x x x x 10 < 104.13 < 10 < 104.13 < 10 < 104.13 1 1 CCI:ICLh 1H AT IUr4 ug 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104. < 10 < 104. 10 < 104.13 10 < 104.13 10 < 104.13 10 < 104.13 < 10 < 104.13 < 10 < 104.13 10 < 104 10 <104.13 4 41. 1 1 1 1 1 1 1 1 1 ug/1 u day day day VI" 10 6 Y .,t . 4 ug u ug/1 ug/1 ug/1 ug/ ug/1 b/day day day day day day day 10 10 0 6 <82.76 <82.76 10 1 1 <82.76 e 0 10 10 10 10 ug/1 ug/1 ug/1 b/day b/day b/day ug/ b/day ug/1 ug/1 u ug/1 ug/1 b/day b/day b/day b/day b/day b/day IJ/ da y 10 10 10 10 10 10 10 )0 0 <82.76 82.76 82.76 82.76 82.76 <82.76 82.76 <82.76 76 <82.76 76 <82.76 <82.76 1 I l'ILLA1 11 C 111.11.. 1 t:t11' Jita 1 101) UU) a ammaa.....i•na• ••••••••••••••••••• •••,-.4 101. ama woo •Nlia••• 'Fa • y ma 40.0 AI I , a )I 1,11T ANT 110 CAS 1 Mnfit., A. IPo NI A A 1.4441PA DAILY V ALCM '4, I I • a *we.% •• .11 1.1 161 ea. •6 is - • _ iFRACTION - VOL T ILL C.,0%il'OUNL 1c(111,»4e41,1 ad 31 1,2 Tian*, 1..:1U4i1ly Wok( Cu 51 x x x x x x Vookol 4..4. 115 01-41 X ..*.S FRACTION - ca.) ccw,pcm. d '041.00014:no 2111 ILO 11:20114 11 2,4 (0 10-, (a I ¶.I 4I 14.0.1000 1.1 0) 4:1 11 UH g!..1-2:1 51 f..liopticnial 15 51 ioiruialllowl )02 11 e LLI 11 1.4:4111,40110,0 6. h, ; UG 1.66. *0 114 ox ,I+1,1 x x x x x x- x x 0 <10 10 <10 <104.1 < 104.1 104.13 < 104.1 <10 <10 <10 0 0 0 <10 <10 <10 <10 <10 <10 <10 <10 < 104.13 < 104.13 < 104.13 < 104.13 < 104.13 4. < 104.1 < 104.1 < 104.1 < 104.1 J. CrUIAJLA4r Anallscs < 104.1 < 104.13 < 104.13 104.13 1 1 1 1 1 1 1 LLW • •.•••••••• son ••,,• • • ,'•• ••••4 ar.) 4. 11.1411% ▪ CONCiiN h A 110h INIA:r1 0 0 t“itt. JO --AV ti 46644 6 6, 4366 CO 6, 461.4." -------- u9/1 lb/day <10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 lb/day < 10 ug/1 ug/1 ug/1 ug/ ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 day < 10 b day < 10 lb/day < 10 day < 10 lb day lb/day lb/day 1b/day lb/day lb/day b/day b/day b/day_ t_PY, .76 2.76 2.76 2.76 , 82.76 • 82.76 ( 82.76 46 1446 4 444644 .4 .66 .4 ". 1 1 1 1 1 1 1 1 < 10 < 10 10 10 10 0 < 10 .< 10 < 10 < 10 /cloy ,10 .76 82.76 < 82.76 82.76 • 82.76 82.76 - 82.76 82./6 82.76 8?.16 16 1 -374."1 1 1 L.I.U1 ANT : .40 CAS 1/11111 11 At41:+11/1,1 ttAtt-Y At-IIE 11/.04 Of.. II - - F RACT ION - r, /NE Ui A E coalroutjus crroapliihcibe t 91 cc/./ohtylaia: 01 2-21 -5) nio :Ciltft• n:o (a/ )50 32 3) 1 Elanio• itlicraa 9 2) riso Uhl/ id 4 2; 1140 idi 111:Wr..4 is g2 1 11 )2Chluru iI.cr 4 4) ia - (2-Chloiro E 32 9) .s(i7.040 r1111.41.110 1 3) IU 1.1.erbyll 101 E5 3) tlenijyl Ile 015-1.42 / Ctiloro- /005 12 3) .6 y 9) x x x x <10 < 10 . 0 •-•-• <104.13 104.13 104.13 10 10 10 10 10 < 10 10 < 10 < 10 < 104.13 < 104.13 < 104.13 < 104.13 <104.13 <104.13 104. 13 <104.1 <104.1 10 < 10 9 0 10 10 10 10 <10 <104.13 <104.13 104 13 • 104.13 104.13 104.13 104.13 104.1 3 <104.13 _ . Analysis 1 1 1 1 1 1 1 4 s-441.....•1.4....• 4 UNITE. C 014C r 14 AT ION 14 A% torrowertaw,.., t. ire/ At*.t a 1 4.,1444. 14 (sit -AYLf#1*".1 I,/ 44^ it. $ it. ug/1 b/day <10 82.76 u b/day <10 <82.76 ugfI day <10 2.76, day <10 2.76 ug/1 b/day <10 <82.76 ug/1 lb/day <10 <82.76 ug/1 b/day <10 <82 76 _y9/ b/day <10 <82 76 ug/1 b/day__ <10 <8276 _09/1 ijlday u9/1 b/day <10 02.76 uq/1 b/day 1O <82.76 u9/1 u9/1_ b/dav < 0 <112/6,_ ug/1 b/day ;82.76 9/1 b/day <10 <82.76 uq/1 b day <10 ug/1 'b/day <10 82.76 ug/1 /day < 10 82./6 ug/1b/day ‹10 82./6 / 00y 10 .132. to trklit tki A ttlAt 111.4 t 1 82.16_ 1 b/day 0 -8276 1:)Lailu11 Namu f McGuire Nuclear Station ii I At 141.1blisi la 001 CCW LLUTAN 1. C AS; J04111211 ilACT102 1,4 Chchiu/;.. 1.0 1101'1-41, 1 wItioto liono 1111 )aaihyl 31,3 21 $unctilyi ale 1 31 N 1101Y1 A (lui;tro 00:21 1421 .G CIA;;(01 2,0 21 ; riOctiel 1,;(1 4 0; 1.0.111lan11` 13 f:s• li22C64 li. 3/ .. nal AA 4. 1,11 1./1.11O a) Pyre:Ir., f...) uphoil4311.1 I) 341311lialle A ell MA141.04.334 °AMY V.3,1 IM r. • r • . DA '• I I i• 1 111-11-11.. CO111,011CS <10 10 < 10 < 10 < 10 < o < 10 10 10 0 <104.13 104.13 104.13 104.13 <104.13 W.C.13 104.13 <104,13 <104.13 104.13 1 4.13 10 <104.13 • 10 104.13 . <104.13< 10 s_ 104-13_ _10 104.13 10 104.13 0 • 0 • 10 < 10 <104.13 04._13 .___104.1 3 <104.13 r11 I I ill IA No. Andlyties 1 1 _ 1 1 1...• .........,.......rr, +.•*01,4,1rrerrrearr WI.. WWWWµS, 011.104110 .0.1.1.1.11....liv.... lyory.....,........ ,,,, ,,,,,,,,,............y. 1 1/011 F..... t); 11141 A'.:, • C Or4C C:o74 4 i .:10.-,i 1IIATi31 i441/t!'!'. . I it ..1 _ .i r.- ,r, , i , , . 171 t. ,... r 01.....‘ ug/1 lb/day <10 <82.76 ug/1 ug/1 ug/1 ug/1 u 139/1 ug/1 ug/l ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 lb/day lb/day /day lb/day lb/day lb/day day lb/day lb/day b/day Ib/day 1 /day lb/day lb/day lb/ddy u9/1 lb/day u9/1 16/ddy lb/day <10 2.76 lb/day <10 2.76 lb/day <10 2.76 0 2.76 10 <82.76 10 .76 0 <82 76 < 10 <82J6 0 2.76 < 10 <82.76 < 10 2.76 <10 <82.76 <10 <82.76 <10 12.76 <10 2./6 <10 76 <10 <10 <10 <82.76 . _ -8 2: /6 <82 7 /6 1 1 1 1 1 1 I ):..LulF.I,;T 4141 L.\S 7111,.1454 11 F13l.0 Tl(; - ?U I! P:[I10 .•u114 rr lrnnno 1 u .'.1 61 Wn•ndnifrcr.o )5.01 0) 5a I've( e 129 00 0) Lfi, 1,2,4 - T/1- 111o1oUenlune 120 C2.11 C!r.;S FRACTICrJ - PE TICIt ES A P. A 1,111.1 {0') 00 2 ) Y. fi flHC 11 L 1_ 4 tij ;I tl)1C 119 U u C11C 119UI.U) C1.iotJble 7.749► 44` ^.or 0 2 J 3; • 4 4 I.DE 25i91 e 4 •1 1,01.., 2 t,.1 U:/1) P 11 I. nJN...11r.1 it. :9 7) <10 <10 <10 <10 Al1,Y Vrl,tli. NU. Of I I..,., _.LAuoly P§ iihlna. 1: <104.1 104. <104 <104.1 ------------ 11 MA!.% ug/1 lb/day ug/1 lb/day ug/1 lb/day /day. / fkf.'. 41 l44.1 - ".1.1t i 1.1 ton 17c ).1. t).).... <10 <10 <10 <10 <82.76 82.76 2.76 <82.76 1 wire Nuclear Stt 14. J 1.1-11 ;WI c PCO 1? i•1 1Tu)-11 PCf: 1221 la2J31 rCii-12)2 11.16 5► ?Cd i�•ld '?::5u1 'CO-1:43 ,60?51 'C!: 1016 �11?1 Nlonl CCW f DUKE POWER COMPANY P.O. BOX 33189 CHARLOTTE. N.C. 28242 WILLIAM A. HALLER MANAGER NUCLEAR TECHNICAL SERVICES (704) 373 S506 February 9, 1987 Operations Branc Water Quality Section Division of Environmental Management Department of Natural Resources and Community Development P.O. Box 27687 Raleigh, NC 27611 ATTENTION: Mr. Dale Overcash SUBJECT: Draft NPDES Permit McGuire Nuclear Station - NC0024392 File: MC-702.13-1 Dear Sir: Duke Power Company appreciates the opportunity to review the draft permit for McGuire Nuclear Station. Attached are our comments. Also attached is a copy of the permit as we would like to see it. Should you desire additional information, please contact R.T. Simril (704) 373-2310 or W.T. Griffin (704) 373-5764. Very truly yours W.A. Hailer, Manager Nuclear Technical Services WTG/rhm Attachment xc: M.D. McIntosh w/o att M.L. Birch H.B. Tucker w/o att J.E. Lansche W.M. Funderburke w/att Staff J.C. Painter MC-2002.02-07 R.W. Eaker Comments on Draft NPDES Permit McGuire Nuclear Station (Permit No. NC0024392) Item 4 of the "Supplement to Permit Cover Sheet" should be changed to read "[c]ontinue to discharge condensate demineralizer backwash water, wafer treatment system backwash water, deminera`lizer backwash water, diesel generator sump water;; and tiirbine building sump water (Outfall No. 002) into . . . " The other flows, steam generator blowdown water and metal cleaning wastes, constitute part of turbine building sump water. 2. Item 5 of the "Supplement to Permit Cover Sheet" should be changed to read " . treated domestic wastewater (Outfall No. 003), via Collection Basin, into the Catawba River . . . " The domestic wastewater does not discharge directly to the Catawba River but into the Collection Basin which discharges to the river. Discharge 001 - Delete the statement "[a]dditional monitoring to determine for its other power plants." Duke Power performed a successful 316(a) demonstration. (Attachment 1). 4. Discharge 001 - Add the phrase "outside of an area five meters from the discharge point" at the end of the statement "[t]here shall be no discharge of floating solids or visible foam in other than trace amounts." The added statement is in the current permit. The statement should be added to all other discharge pages as well. 5. Discharge 002 - Change daily maximum discharge limitation for total suspended solids to 100mg/1. Steam electric effluent limitations guidelines (40CFR423) specify 100 mg/1 as the daily maximum discharge limitation. 6. Discharge 004 - The statement concerning turbine building sumps should be changed to read "[i]n the event the turbine building sumps are discharged . . . to the turbine building sump discharge." The work "building" was omitted in two (2) places. 7. Part III G should be deleted. It is a duplication of Part III E. 8. Part III J should be changed to 60 day notification. The current permit specifies 60 days. There can be situations when a biocide would be needed in which 60 day notice may be difficult to meet. 9. Change Part III S to read "[t]he Division of Environmental Management has approved the submitted 316(a) demonstration and has concluded that the existing thermal limits are sufficient to protect the aquatic environment of Lake Norman." Duke Power performed at successful 316(a) demonstration. (See item 3) . Permit No. NC0024392 STATE OF NORTH CAROLINA DEPARTMENT OF NATURAL RESOURCES & COMMUNITY DEVELOPMENT DIVISION OF ENVIRONMENTAL MANAGEMENT PER M IT To Discharge Wastewater Under The NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Duke Power Company is hereby authorized to discharge wastewater from facilities located at McGuire Nuclear Station Mecklenburg County to receiving waters designated as the Catawba River in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, and III hereof. This permit shall be effective This permit and the authorization to discharge shall expire at midnight on August 31, 1989 Signed this day of R. Paul Wilms, Director Division of Environmental Management By Authority of the Environmental Management Commission Permit No. NC0024392 SUPPLEMENT TO PERMIT COVER SHEET Duke Power Company is hereby authorized to: 1. After receiving an Authorization to Construct from the Division of Environmental Management, construct and operate additional wastewater treatment facilities necessary to comply with the final effluent limitations contained in this permit located at the McGuire Nuclear Station (See Part III of this permit), and 2. Continue to discharge condenser cooling water, conventional low pressure service water, and nuclear service water (Outfall No. 001) into Lake Norman which is classified Class "WS-III & B" waters in the Catawba River Basin, and Continue to discharge low level liquid radwaste and turbine building sump water (Outfall No. 004) into the condenser cooling water, conventional low pressure service water, and nuclear service water discharge (Outfall No. 001) which ultimately discharges into Lake. Norman and is classified Class "WS-III & B" waters in the Catawba River Basin. 4. Continue to discharge s't dt L i, immoiremPt condensate demineralizer backwash water, water 3utreatmlent sstem backwash water, demineralizer backwash ate`` ,'^� Ovand turbine building sump water (Outfall No. 002) into the Catawba River which is classified Class "WS-III" waters in the Catawba River Basin, and 5. Continue to discharge 0.064 MGD wastewater (Outfall No. 003 in which is classified Class WS-I Catawba River Basin. treated domestic o the Catawba River I" waters in the CO//«i, In 895/» A. ( 1). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Final During the period beginning on the effective date of the permit and lasting until expiration, the permittee is authorized to discharge from outfall(s) serial number(s). 001. Once through cooling water Such discharges shall be limited and monitored by the permittee as specified below: ffluent Characteristics Flow Discharge Limitations Monitoring Requirements Kg/day (lbs/day) Other Units (Specify) Daily Avg. Daily Max. Daily Avg. Daily Max. Temperature 95 deg F *Sample location for temperature is the discharge canal bridge. Measurement Sample Sample Frequency type Location Daily Pump Log Influent Daily Recorder Radwaste system discharges are regulated, monitored and reported to the Nuclear Regulatory Commission. The pH shall not be less than n/a standard units nor greater than n/a standard units and shall be monitored n/a. There shall be no discharge of floating solids or visible foam in other than trace amounts 0 mrea Daily Avg. Daily Max. Flow Oil and Grease Total Suspended Solids Total Copper** Total Iron** pH A. (2). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Final During the period beginningon the effective date of the permit and lasting until expiration, the permittee 1s authorized to discharge from outfall(s) serial number(s). 002 Conventional Wastewater Treatment Such discharges shall be limited and monitored by the permittee as specified below: Facility affluent Characteristics Discharge Limitations Monitoring Requirements Kg/day (lbs/day) Other Units (Specify) Daily Avg. Daily Max. /N. v 15.0 mg/1 ! 20.0 mg/1 30.0 mg/1 Aim mg/1 1000.0 u g/ 1 1000.0 u g/1 1000.0 ug/1 1000.0 ug/1 Measurement Frequency Weekly' 1/year*** 1/year*** 1/batch 1/batch 2/month Sample Type Instantaneous Grab Grab Grab Grab Grab *Effluent sampling shall be conducted at the discharge prior to mixing with any other waste stream. **Monitoring, analysis and reporting for iron and copper are required only when chemical metals cleaning is performed. ***Sample frequency is based on demonstrated performance. Should additional sampling be indicated, this permit shall be modified to include additional sampling for these parameters. The pH shall not be less than 6.0 standard units nor greater than and shall be monitored as indicated above. 9.0 standard units * Sample Location Effluent Effluent Effluent Effluent Effluent Effluent Or r♦ There shall be no discharge of floating solids or visible foam Mk 1+7S yru"77 (JO ig13 rf,* C ::Y +;1 1 other than trace amounts), w E TATIONS AND MONITORING REQUIREMENTS Final During the period beginning on the effective date of the permitand lasting until expiration, the permlttee 1s authorized to discharge from outfall(s) serial number(s) 003 Domestic wastewater treatment Such discharges shall be limited and monitored by the permittee as specified below: plant Effluent Characteristics Discharge Limitations Kg/day (lbs/day) Monthly Avg. Weekly Avg. Other -Units (Specify) Monthly Avg. Weex ly Avg. Flow BOD,5Day,20°C 30.0 mg/1 45.0 mg/1 TSS 90.0 mg/1 135.0 mg/1 Fecal Coliform (geometric mean) 1000.0/100 ml 2000.0/100 ml The pH shall not be less than n/a standard units nor greater shall be monitored monthly at the effluent by grab sample. There shall be no discharge of floating solids or visible foam Monitoring Requirements Measurement Frequenq► Monthly Monthly Monthly Monthly a��le S 11e_ Type Uxat on Instantaneous Effluent Grab Effluent Grab Effluent Grab Effluent than n/a standard units and in other than trace amounts. A. (4). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Final During the period beginning cn the effective date of the permit and lasting until expiration, the permittee is authorized to discharge from outfall(s) serial number(s).004-Radwaste Processing System ** Such discharges shall be limited and monitored by the permittee as specified below: .ffluent Characteristics Kg/day (lbs/daY) Daily Avg. Daily Max. Flow TSS Oil & Grease Discharge Limitations Monitoring Requirements Other Units (Specify) Measurement Sample Sample Daily Avg. Daily Max. Frequency Type Location Annually Instantaneous Effluent 30.0 mg/1 100.0 mg/1 Annually Grab Effluent 15.0 mg/1 20.0 mg/1 Annually Grab Effluent *Effluent - Monitoring will be required after radwaste treatment but prior to any dilution with cooling water. bo:Wof **In the event the turbinAumps are discharged to Lake Norman and are not treated in the radwaste processing system, the above discharge limitations and monitoring requirements shall also apply to the turbineomsump discharge. The pH shall not be less than n/a standard units nor greater than n/a standard units and shall be monitored n/a. There shall be no discharge of floating solids or visible foam in other than trace amounts. Part III Continued Permit No. NC0024342 Toxicity Reopener This permit shall be modified, or revoked and reissued to incorporate toxicity limitations and monitoring requirements in the event toxicity testing or other studies conducted on the effluent or rcedvin8thestream receivingindicate streamthat asdetrimental ofeffects may be thisdischarge. expecte If the permittee, after monitoring for at least six months, determines that he is consistently meeting the effluent limitations contained herein, the permittee may request of the Director that the monitoring requirements be reduced to a lesser frequency. There shall be no discharge of polychlorinated biphenyl compounds such as those commonly used for transformer fluid. The permittee shall not use any biocides except these approved in conjunction with the permit application. The permittee notify the Director in writing not later than ninety daps prior to instituting use of any additional biocide used in cooling systems which may be toxic to aquatic life other than those previously reported to the Division of Environmental Management. Such notification shall locatinginclude the dischargecompletion pointBiocide receivinget Form 101 andP stream. Continued intake screen backwash discharge is permitted without limitations or monitoring requirements. Nothing contained in this permit shall beconstrued as a rued asrauwaiver by the permittee or any right to a hearing it may State or Federal Laws or regulations. The term "low volume waste sourcesmeans the waste is taken collectively as if from one source except those for which specific limitations are otherwise established in this part. Low volume wastes sources include but are not limited to: wastewaters from wet scrubber air pollution control systems, ion exchange water treatment system, water treatment evaporator blowdown, laboratory and sampling streams, boiler blowdown, floor drains, cooling tower house ice water basin ning tes, and and air conditioninggwastes are not systems. Sanitarynot included. The term "metal cleaning waste" means any wastewater resulting grom cleaning (with or without chemical cleaning compounds) any metal process equipment including, but not limitedir pto, uoil cltubeng. cleaning, boiler fireside cleaning, a Part III Continued Permit No. NC0024392 0. It has been determined from information submitted that the plans and procedures in place at McGuire Nuclear Station are equivalent to that of a BMP. P. Yard drains may be discharged without limitations or monitoring requirements. Q. "Upset" means an exceptional incident in which there is unintentional and temporary noncompliance with technology based permit effluent limitations because of factors beyond the reasonable control of the permittee. An upset does not include noncompliance to the extent caused by operational error, improperly designed treatment facilities, inadequate treatment facilities, lack of preventive maintenance, or careless or improper operations. R. Collection basin may be discharged without limitations or monitoring requirements. S• The Division of Environmental Management has approved the submitted 316(a demonstration and has concluded that the existing thermal limits are sufficient to protect the aquatic environment of Lake Norman. T. Mixing Zone A mixing zone has been defined containing an area of no more than 3500 acres and lying upstream of the dam and south of a line originating on the west bank of NC Coordinates E-1, 416,900 and N-633,600 and extending south 70 -00 east intersecting the point of land on the eastern shore. U. The term "chemical metals cleaning waste" means any wastewater resulting from the cleaning of any metal process equipment with chemical compounds, including, but not limited to boiler tube cleaning. P4 RECEwE State of North Carolina Department of Natural Resources and Community Devel►p Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27611 James G. Martin, Governor S. Thomas Rhodes, Secretary October 18, 1985 Mr. H. B. Tucker, Vice President Nuclear Production Duke Power Company P.O. Box 33189 Charlotte, North Carolina 28242 RE: McGuire Nuclear Station 316(a) Demonstration NPDES Permit No. NC0024392 Mecklenburg County 2 1985 r,• ffe ul Wilms Director Dear Mr. Tucker: The report entitled "McGuire Nuclear Station, 316(a) Demonstration", June 1985 has been received and evaluated by the staff of the Division of Environmental Management. The North Carolina Department of Natural Resources and Community Development, Division © Environmental Stativnt,agement effectivesMadrehP28s 19781andNo. NC0024392 for the McGuire re -issued this permit on September 1, 1984. One of the conditions of the previously mentioned permit required Duke Power to submit the resultThis requireme©tmwastration includedras per©Titletl5n of best available technology. NCAC 28.0204 of the State of North Carolina Administration Code. This demonstration was to include open;aional effects zovplanktonMcGuire as©detailedwater ginlity, fish, periphyton, benthos, phytopnkton, Section 316(a) of the Federal Water Pollution Control Act and to address interaction between the McGuire and Marshall power facilities located on Lake Norman. Pollution Prrm111irr>t Pay P©. Box 27687, Raleigh, North Carolina 27611.7687 Telephone 919-733.7015 Mr. H. B. Tucker October 18, 1985 Page 2 The Division of Environmental Management has completed its review of the submitted 316(a) Demonstration and has concluded that this submittal sufficiently fulfills the requirements of the NPDES permit conditions. It is the conclusion of the Division that the effects of the discharge from the McGuire Nuclear Station is such that the protection and propagation of a balanced indigenous aquatic community is assured in Lake Norman and that interaction of the two thermal plumes of McGuire and Marshall do not occur. The Division of Environmental Management, therefore, approves the sub- mittal as a successful 316(a) Demonstration and that this demonstration confirms that McGuire's existing NPDES thermal limits are sufficient to pro- tect the aquatic environment of Lake Norman and that these limits are approved. The Division would like to acknowledge the exceptional efforts of the Duke Power staff throughout this extensive study period and look forward to continuation of such cooperation in the future. Sinc ely, cc: Mr. Jack Ravan Mr. George T. Everett Mr. Steve W. Tedder Mr. Dick Hamilton Mr. Dennis Ramsey Date: September 4, 1986 NPDES STAFF REPORT AND RECOMMENDATIONS County: Mecklenburg NPDES Permit No. NC 0024392 PART I - GENERAL INFORMATION 1. Facility and Address: Duke Power Company McGuire Nuclear Station Post Office Box 33189 Charlotte, N. C. 28242 2. Date of Investigation: March 27, 1986 3. Report Prepared By: J. Thurman Horne, P. E. 4. Persons Contacted and Telephone Number: Mr. W. T. Griffin (704) 373-5764 5. Directions to Site: From the intersection of Highway 16 and Highway 73 travel east on Highway 73 approximately 3.2 miles. The facility is on the left (north) side of Highway 73 on the southern shore of Lake Norman. 6. Discharge Point - 001 002 & 003 Latitude: 35°26'10" 35°25'40" Longitude: 80°56'30" 80°57'20" Attach a USGS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No. F15NW 7. Size (land available for expansion and upgrading): The existing site encompasses approximately fifty (50) acres. There is adequate land available to construct additional treatment facilities and modifications. 8. Topography (relationship to flood plain included): Mildly rolling, slopes are generally less than 10%. The existing facilities do not appear to be within any flood plain. 9. Location of nearest dwelling: None within 1000 feet 10. Receiving stream or affected surface waters: 001 002 & 003 Lake Norman Catawba River WS III & B WS III 03-08-32 03-08-33 a. Classification: b. River Basin and Subbasin No.: c. Describe receiving stream features and pertinent downstream uses: Outfall 001: The receiving water body (Lake Norman) is used extensively for primary and secondary recreation and as a municipal water supply. The nearest water intake is for the Town of Huntersville and is located approximately 3 miles northeast of the discharge. -2- 0utfall 002 & 003: The receiving river is used extensively for primary and secondary recreation and as a municipal water supply. The nearest water intake is for the City of Charlotte and is located approximately 10 miles downstream. PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. Type of wastewater: 001 002 003 0 0 100 % Domestic 100 100 0 % Industrial a. Volume of Wastewater: 001 002 003 2525 .41 0.04 MGD (average daily) (based on flow schematic attached to application) b. Types and quantities of industrial wastewater: 0utfall 001 (Cooling Water Discharge): This discharge i a combination of condenser cooling water (1,727,100 gpm), conventional low pressure service water (6,500 gpm); nuclear service water (20,000 gpm), low level liquid radwaste (8 gpm) and *turbine building sumps (70 gpm). **0utfall 002 (conventional treatment system discharge): This discharge consists of steam generator blowdown, condensate demineralizer backwash, meter treatment_ systew ba kwasi% tdemineralizer backwash, building drains, metal cleaning wastes and *turbine building sumps. Outfall 003 (sanitary waste treatment system): This discharge consists of the domestic type waste generated by plant personnel. c. Prevalent toxic constituents in wastewater: 0utfall 001 ***Outfall 002 0utfall 003 Biocides (see attached Low level radioactivity None letter dated 2/28/86) low level radioactivity)- .. chlorine, sodium hydroxide,_. lithium hydroxide ,„e.,.--..--� monohydrate, sulfuric acid, boric acid d. Pretreatment Program (POTWs only): N/A. 2. Production rates (industrial discharges only) in pounds: Information not available in any application submittals received by MRO. If information is needed it should be requested from the applicant. Description of industrial process (for industries only) and applicable CFR Part and Subpart: 40 CFR Part 423 - Steam Electric Power Generation 4. Type of treatment (specify whether proposed or existing):. 0utfall 001 The existing liquid radwaste system consists of filters, evaporators and demineralizers. (Note: this process treats only a small portion of the total discharge of outfall 001). The combined wastewaters of outfall 001 flow into Lake Norman via a discharge canal approximately 2500 feet long and 200 feet wide. The canal is for the purpose of heat dissipation. 0utfall 002 Wastewater is treated in the plant's existing conventional wastewater treatment system which consists of a 200,000 gallon initial holding pond, two (2) settling ponds (in parallel) each with 2.5 million gallon capacity, a 1 million gallon final holding pond (aerated -diffused air) and effluent pH adjustment consisting of automated GO addition. The initial holding pond acts as a flow equalization basin. This pond may be bypassed, depending on the nature of the wastewater. The two settling ponds are operated such that one pond remains in standby. Treatment can be enhanced by the addition of coagulant aids and pH adjustment :in these ponds. The effluent from the settling ponds may be discharged directly to the receiving stream via outfall 002 or it may be routed to the final holding pond. Effluent from the final holding pond may be discharged through outfall 002 or recirculated to the settling ponds, depending upon effluent quality. 0utfall 003 The existing sanitary WWTP consists of a multicellular aerated -facultative lagoon, a chlorine contact chamber (tablet), and a parshall flume. The discharge from outfall 003 enters an impoundment which also receives area surface runoff. The overflow from the impoundment•, combines with the discharge from outfall 002 prior to discharge into the Catawba -River. The sanitary WWTP is designed for a maximum of 64,000 gpd. 5. Sludge handling and disposal scheme: (Information received by telephone from Mr. W. T. Griffin on 8/26/86). Outfall 001: Sludges which accumulate in the liquid radwaste system are disposed as low level radioactive wastes at approved repositories such as Barnwell, S. C. 0utfall 002: Sludges are disposed by landfarming at a designated on -site disposal area. This disposal is permitted by DEM Permit No. 7641R2. 0utfall 003: Sludge is periodically removed from the lagoon and disposed at a municipal WWTP. Currently, the disposal is made at CMUD's McDowell Creek WWTP. 6. Treatment plant classification: Attached are copies of suggested revised rating sheets being sent to John Campbell for consideration. If approved the revised rating will be as follows: 0utfall 001: Class IV; 0utfall 002: Class III, 0utfall 003: Class I *Based on information given to the investigator during the inspection. Note: The turbine building sump water will normally go to the conventional wastewater treatment system for discharge thru outfall 002. However, in instances where the radioactivity of the sump water is sufficiently low (within NRC requirements) the water may be released directly thru outfall 001. If radioactivity level exceeds NRC requirements, the sump water must first be routed to the liquid rad- waste processing system prior to discharge thru outfall 001. -4- **The application does not provide sufficient information to ascertain specific quantities for each type of wastewater included in this outfall (002). If this information is necessary, it should be requested. ***Refer to information submitted by letter from Duke dated June 18, 1982 for full listing of metals, etc. If a copy is not available in Central Files, please contact MRO for a copy. PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grants Funds (municipals only)? N/A. 2. Special monitoring requests: See Part IV 3. Additional effluent limits requests: None 4. Other: None PART IV - EVALUATION AND RECOMMENDATIONS Duke's application for amendment essentially covers three (3) changes to and clarifications of operations at the plant that have occurred since last issuance of the permit (9/1/84) as outlined below: 1. Duke has modified their operations such that turbine sump water may now be discharged via outfall 001 (see part II * for detail). The manner of release is reportedly governed by NRC approved plant procedures. Duke has submitted a copy of these approved procedures (copy attached). 2. Duke has begun using biocides and chemical additives which are ultimately discharged thru Outfall 001. (See attached report from Duke dated 2/28/86 for explanation and listing of materials used). 3. Duke has now placed the new multicellular aerated facultative lagoon WWTP (sanitary treatment system) in service and has abandoned the previously used package WWTPs. As is typical with any such request for permit renewal or amendment, the investigator has attempted to review the adequacy of the existing permit, least we should continue any inadequacies in a new, revised permit. This review has prompted serious concern with respect to the monitoring of possible radioactive releases thru outfalls 001 and 002. We can find nothing in our file copy of Duke's permit which provides any assurance that such releases>are being monitored or that they are properly limited. In Duke's application documents (for this latest modification and for applications in years past) Duke has indicated that such releases are low level a and are in accordance with NRC approved station operating procedures. Further, it is our understanding, thru conversations with Duke personnel, that Duke submits reports regularly to NRC with respect to the amounts and types of radiation released. If thisis the case, then NRC is regulating the levels of radioactivity released thru DEM permitted outlets (001 & 002). This is no problem if NRC is reviewing Duke's releases in a responsible manner (and we are confident that they are) and that the controls which they impose take into consideration DEM's concerns to protect water quality (not just human health). Obviously the answer to this question is not easily obtained and would appear to be a matter best resolved by a written -5- agreement between the NRC and DEM. An agreement such as this would be advisable since NRC is obviously the more qualified of our agencies for such a matter and this would merely be an official acknowledgement that this is, in fact, their responsibility. DEM could then ma* reference to such fact in the NPDES Permit and establish that the reporting and procedures for radioactive releases will be done in accordance with NRC requirements. Thus, if there should ever be a problem with such releases DEM would have some avenue for action. Such an avenue does not exist in the current permit. eL This matter has been discussed with Mr. Dayne Brown, NC-DHR-Radiological Unit and Mr. Darrel Hood, NRC. Neither are aware of the existence of any such agreement and both agree that this may be advisable and warrants further consideration. We recommend that this matter be discussed with the Water Quality Section Chief and that negotiations be initiated with NRC with the goal of developing an inter -agency memorandum of understanding. We believe that this is in the best interest of both DEM and NRC not just for the McGuire Station but for all nuclear stations within the State. Upon resolution of this matter, it is recommended that the NPDES Permit be reissued with limitations and monitoring requirements appropriate for this industrial category and for the revised class of each outfall. Note: The permit should not be drafted until the proposed revised facility rating has been reviewed and classifications assigned. Signature of report preparer Water Quality Regional Supervisor C K -!L Alwil f N. C. DEPT. OF NATURAL RESOURCES AND COMMUNITY DEV. ENVIRONMENTAL MANAGEMENT COMMISSION NAL POLLUTANT DISCHARGE ELIMINATION SYSTEM \I CATION FOR PERMIT TO DISCHARGE WASTEW4TER STANDARD FORM C — MANUFACTURING AND COMMERQ$L ,41 pia SECTION I. APPLICANT AND FACILITY DESCRIPTION Unless otherwise Spei cirAdhis form all Items are to be completed. If ari item Is not applicable Indicate INA.' ADDITIONAL INSTRUCrIDNSTOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS INgiliCINVED. REFsfii\ TO BOOKLET BEFORE FILLING OUT THESE ITEMS: Legal Name of Applicant (see Instructions) Mailing Address of Applicant (see instructions) Number & Street City State Zip Code Applacant's Authorized Agent (see Instructions) Name and Title Number & Street Address City State Zip Code Telephone 4. Previous Application If a previous application for a National or Federal discharge per- mit has been made, give the date of application. Use numeric designation for date. Please Print or Type Duke Power Company P.O. Box 33189 Charlotte North Carolina 28242 H. B. Tucker Vice President, Nuclear Production P.O. Box 33189 Charlotte North Carolina 28242 704 373-4531 Area Code Number 82 07 20 YR MO DAY I certify that I am familiar with the information contained In this application and that to the best of my knowledge and belief such Information Is true, complete, and accurate. H. B. Tucker Printed Name of Person Signing Vice President, Nuclear Production Title YR MO DAY Signature of Applicant or Authorized Agent Date Application Signed North Carolina. General Statute 143-215.6(b) (2) provides that: Arty person who knfringly makes any false statement representation, or certification in any application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowly renders inaccurate any recording or monitoring device or method required to be operated cr maintained under Article 21 or regulations of the Environmental Management Cowls it implementing that Article, shall be guilty of a misdemeanor pin.ishahle by a fine not to exceed $10,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provi( a punishment by a fine of not more than S10,000 or imprisonment not more than 5 years, Or both, for a similar offense.) f=aWiitY/Aettvtty (see InstruCtions) Give the nama, ownership, and Physical location of the plant or other operating facility where dis- charge(*) does or will occur. Name Ownership (Public, Private or Both Public and Private) Check block If Federal Facility and glve GSA Inventory Control Number Location Street & Number City County State Nature of Muslims State the nature of the business conducted at the plant or operating faclllty. 7. Facility Intake Water (see Instruc• tions) Indicate water Intake volume per day by sources. Estimate average volume per day in thousand gallons per day. Municipal or private water system Surface water Groundwater Other` Total Item 7 "If there is Intake water from 'other,' specify the source. Facility Water Use Estimate average volume per day In thousand gallons per day for the following types of water usage at the facility. (see Instructions) Noncontact cooling water Boller feed water Process water (including contact cooling water) Sanitary water Other* Total Item 8 *If there+re•discharges to 'other,' specify. If there Is 'Sanitary' water use, give the number of people served. McGuire Nuclear Station UB ®PRV ©BPP © FEO Mecklenburg Generation of electric power from nuclear fuel NJA thousand gallons per day thousand gallons per day thousand gallons per day nd gallons per day thousand gallons per day N/A thousand gallons per day thousand gallons per day thousand gallons per day thousand gallons per day thousand gallons per day thousand gallons per day Wople served I-2 STANDARD FORM C — MANUFACTURING AND COMMERCIA SECTIONU. BASIC DISCHARGE DESCRIPTION Complete this section for each discharge indicated in Section I, Item 9, that is to surface waters, This includes discharges to municipal sewerage systeMS in which the wastewater does not go through a treatment works prior to being discharged to surface waters, Discharges to wells must be described where there are also dischargeS to surface waters from this facility. SEPARATE DESCRIPTIONS OF EACH DISCHARGE ARE REQUIRED EVEN IF SEVERAL DISCHARGES ORIGINATE IN THE SAME FACILITY. All values for an existing discharge should be repre- sentative of the twelve previous months of operation. If this is a proposed discharge, values should reflect best engineering estimates. ADDITIONAL INSTRUCTIONS FOR SELECTED ITEMS APPEAR IN SEPARATE INSTRUCTION BOOKLET AS tNDICATED. REFER TO BOOKLET BEFORE FI LING OUT THESE ITEMS, 1,, Discharge Serial No, and Name a, Discharge Serial No, (see instructions) b. Discharge Name Give name of discharge, if any. (see instructions) c, Previous Discharge Serial No. II Previous permit application was made or this discharge (see item 4, ,iiiction I), provide Previ- ous diqiiargo serial number. Discharge Operating Dates a. Discharge Began Date If the discharge described below is in operation, give the date (within best estimate) the cliScharge began, h. Discharge to Begin Date If the discharge has never occurred but Is planned for sorne future date, give the date (within best esti- mate) the discharge will begin. c. Discharge to End Date If dis- charge is scheduled to be discon- tinued within the next 5 years, give the date (within best esti- mate) the discharge win end. 3. Engineering Report Available Check it 311 engineering report IS available to roviewing ncy upon request, (see instructi)ns) 4. Discharge Location Name the political boundaries within which the point of discharge is located, State County (it applicable) City or Town 5, Discharge Point Description Discharge is into (Check one): (see inStiuctions) Stream (includes ditches, arroyos, and other intermittent watercourses) Lake Ocean Municipal Sanitary Wastewater Transport System Municipal Combined Sanitary and Storm Transpor t System 001 _Conc1enser Coolingyater N/A YR MO MO YR MO North Carolina Mecklenburg TR K E DOCE DMIS DMC5 This t,kort re000i0,0 0 DISCHARGE SERIAL NUMBER 001 Municipal Storm Water Transport System Well (Injection) Other if 'other' is checked, specify 6. Discharge Point — Lat/Long Give the precise location of the point of discharge to the nearest second, Latitude Longitude Discharge Receiving Water Name Name the waterway at the point of dlscharge,(see instructions) tf the discharge Is through an out - tact that ex tends beyond the shore - tine or is below the mean low water line, complete Item 8. P STS PWEL POTH 2� 35 DEG 25 MIN 59SEC 24I _8DEG 56 MIN 55SEC Offshore Discharge a- Discharge Distance from Shore 20 k b. Discharge Depth Below Water Surface 20111b Discharge Type and Occurrence a. Type of Discharge Check whether the discharge Is con- tinuous or intermittent. (see instructions) b. Discharge Occurrence Days per Week Enter the average num- ber of days per week (during periods of discharge) this dis- charge occurs, c. Discharge Occurrence —Months if this discharge normally operates (either intermittently, or continuously) on less than a year -around basis (excluding shutdowns for routine mainte- nance), check the months dur- ing the year when the discharge is operating. (see instructions) ompiete items 10 and 11 if "Inter- iittent" is checked in Item 9.a. )iherwise, proceed to Item 12. 0, Intermittent Discharge Quantity State the average volume per dis- charge occurrence in thousands of gallons, It„ Intermittent Discharge Duration and Frequency a. Intermittent Discharge Duration Per Day State the average number of hours per day the discharge is operating. b. Intermittent Discharge Frequency State the average number of discharge occur- rences per day during days when discharging. 12, Maximum Flow Period Give the time period in which the maximum flow of this discharge occurs. Lake Norman feet [(con) Continuous 0 (int) Intermittent days per week ©JAN( DFEB OMAR DAPR DMA 0JUN 0JUL ['AUG PSEP POET ID NOV POEC For Agency Use 303e thousand gallons per discharge occurrence. .hours per day discharge occurrences pet day From June to October month month n-s DISCHARGE SERIAL NUMBER nni 13. Activity °ascription Give a narrative description of activity producing thls discharge.(see instructions) 14. Activity Causing Discharge For each SIC Code which describes the activity causing this discharge, supply the type and maximum amount of either the raw material consumed (Item 14a) or the product produced (Item 14b) in the units specified in Table I of the Instruc- tion Booklet. For SIC Codes not listed in Table I, use raw material or production units normally used for measuring production.(5ee instructions) a, Raw Materials SIC Code 213 General - Conversion of nuclear energy into electrical energy Specific - Condenser cooling water serving steam condensers, plus blowdown from steam ,generators, treated low- level radioactive liquid wastes�W N/A Name t2i Maximum Unit Shared Discharges Amount/Day (See Table I) (Serial Number) b„ Products SIC Code Name Maximum Unit Amount/Day (See Tabl Shared Discharges (Serial Number) 11-3 15. Waste Abatement Waste Abatement Practices tiev r b, the. waste abatement tsar Fit es Tisch ,n, this discharge with a brief narrative. (see instructions) b. Waste Abatement Codes Using the cotes listed in Table It of the Instruction Booklet, describe the waste abatement proccsscs for this discharge in the order in which they occur ,1 In,t :rblr:. DISCHARGE SERIAL NUMBER 001 Na„,, Condenser cooling water , drawn from Lake.hiarman, pumped through the condenser and discharges back into Lake Norman. Steam generator blowdown is monitored and then dis- charged into the condenser cooling water or recycled for cleanup if needed. Plant drains which may contain radio- activity are collected in Liquid Radwaste System. The Liquid Radwaste System collects all radioactively contaminated water from the equipment drains, spills, or leaks within the auxiliary and reactor buildings. The system is onitored and o erated such that low level radioactive (4) (7) PSCREE ESURFA RECOVE ((0) �1.F CdbS (13) MTfNOY (16) (19) (22) (25) ESEPAR. (2) (5) EMERGE 0) RECYCL (3) ESEGRE (6) EPTTMPS LOCALS 00 TEVAPO ( t I ) TPR©CE (14) ...„. (15) (17) (18) (20) (21) (23) , (24) waste may be released when its activity is below prescribed limits or may be recycled to the Reactor Coolant System. The system utilizes filters, evaporators, and demineral- izers for the treatment process. All releases are regulated by the Nuclear Regulatory Commission and are made to assure compliance with 10 CFR 50 Appendix I. Maximum flow from the system is 300 gpm. NOTE: The turbine building sumps are normally routed to the Conventional Wastewater Treatment System (WC). How- ever, when the sump has radioactive contamination, its discharge may continue to be released to the WC system, may be routed to the normal Liquid Radwaste System discharge ,line for release to the condenser circulat- ing water or to the Liquid Radwaste Collection tanks for processing prior to release. The release method to be used depends on the level of radioactivity, volume of wastes, other wastes to be processed, NRC Technical Specifications processing requirements, potential for an oil spill, and on the need to process chemical wastes. 11-4 At r,4t,##m. i)UKE POWER COMPANY .EAR PRODUCTION DEPARTMENT x 33189, 422 SOUTH CHURCH STREET CHARLOTTE, N.C. 28242 (704) 373-401.1 February 28, 1986 Mr. D. Rex Gleason, Pf.E. Water Quality Regional Engineer North Carolina Department of Natural Resources and Community Development Division of Environmental Management 919 North Main Street Mooresville, NC 28115 SUBJECT: McGuire Nuclear Station Use of Biocide Containment Spray Heat Exchanger File: MN-208.38, 702.12, 730.65 Dear Sir: On November 27, 1985, we requested permission to use a biocide, Calgon H-106 in the containment spray (NS) heat exchangers at McGuire Nuclear Station to assist in cleaning the exchangers and to restore their efficiency and ensure their operability. Should the efficiency deteriorate excessively, the unit(s) would have to be shut down. In providing approval to use the biocide, you requested a report on the chemical(s) used, the amount of the chemical(s) used, and the discharge concentration. Attached is a listing of the heat exchangers cleaned, the chemicals used, the amount of the chemical, and the maximum discharge concentration as well as flow rates. Also attached is a short description of each chemical. As can be seen, the biocide was used in only two (2) of the heat exchangers. We found that equal or better cleaning was obtained by using surfactants, penetrants, and disperants for this particular fouling. Biocides may be more effective on other types of fouling. Only three of the four heat exchangers were cleaned at this time. It may be necessary in the future to clean the fourth heat exchanger and/or to reclean one that was cleaned at this time. If a biocide is needed in a future cleaning, we will contact you for approval. Mr. D. Rex Gleason, P.E. February 28, 1986 Page Two Should you have any; questions or desire additional information, please contact me at (704) 373-2310. Sincerely, R. T. Simril, System Engineer Nuclear Environmental Compliance WTG:hj p Attachments cc: W.A. Haller R.W. Esker P.W. Downing W.M. Suslick MN-2002.02 MN-2002.03-04 HEAT EXCHANGER CLEANINGS Date Time HX. # Chem. Flush Time Length CCW Flow Max. Dischg. HX. Vol., Chemical Used. Rate, gpm of Disch. min. Rate, gpm Conc. ppm gal. 12/12/85 1330 "lA" NS 4,000 H-106 12/12/85 2000 "lA" NS 4,000 PCL-2000 4.3 5,000 5.2 5,000 0.8 0.8 12/31/85 1430 "lA" NS 4,000 H-106 4.3 2,250 1.8 12/31/85 1430 "lA" NS 4,000 CL-361 4.5 2,250 1.8 1/6/86 2300 "lA" NS 4,000 CL-361 4.5 5,000 0.8 1/6/86 2300 "lA" NS 4,000 PCL-2000 10.4 5,000 0.8 2,032,000 2,032,000 2,032,000 2,032,000 2,032,000 2,032,000 0.32 0.38 0.14 0.15 0.33 0.77 1/14/86 1000 "lA" NS 4,000 TSP 150 33 120 1,883,000 0.079 1/14/86 1000 "lA" NS 4,000 Triton X-100 7.1 33 120 1,883,000 0.0037 1/14/86 1000 "lA" NS 4,000 PCL-2000 5.2 33 120 1,883,000 0.0027 1/27/86 0830 "2B" NS 4,000 TSP 150 200 20 2,032,000 0.44 1/27/86 0830 "2B" NS 4,000 Triton X-100 4.7 200 20 2,032,000 0.014 1/27/86 0830 "2B" NS 4,000 PCL-2000 5.2 200 20 2,032,000 0.015 2/5/86 0900 "2B" NS 4,000 TSP 150 33 120 2,032,000 0.073 2/5/86 0900 "2B" NS 4,000 Triton X-100 7.1 33 120 2,032,000 0.0035 2/5/86 0900 "2B" NS 4,000 PCL-2000 5.2 33 120 2,032,000 0.0025 2/12/86 0900 "2A" NS 4,000 TSP 150 33 120 1,948,000 0.076 2/12/86 0900 "2A" NS 4,000 Triton X-100 7.1 33 120 1,948,000 0.0036 2/12/86 0900 "2A" NS 4,000 PCL-2000 5.2 33 120 1,948,000 0.0026 Definition of Chemicals H-106 - Calgon H-106 Microbiocide (a quaternary ammonium biocide) PCL-2000 - Calgon Powergaurd 2000 (an anionic, polyacyrlic acid dispersant/scale inhibitor) CL-361 - Calgon CL-361 Deposit Inhibitor (a blend of penetrants, surfactants, and dispersants) Triton X-100 - Rohm & Haas Triton X-100 (a non-ionic, poly - ether alcohol surfactant/detergent) TSP - Trisodium Phosphate Date: September 4, 1986 NPDES STAFF REPORT AND RECOMMENDATIONS County: Mecklenburg NPDES Permit No. NC 0024392 PART I - GENERAL INFORMATION 1. Facility and Address: Duke Power Company McGuire Nuclear Station Post Office Box 33189 Charlotte, N. C. 28242 2. Date of Investigation: March 27, 1986 3. Report Prepared By: J. Thurman Horne, P. E. 4. Persons Contacted and Telephone Number: Mr. W. T. Griffin (704) 373-5764 5. Directions to Site: From the intersection of Highway 16 and Highway 73 travel east on Highway 73 approximately 3.2 miles. The facility is on the left (north) side of Highway 73 on the southern shore of Lake Norman. 6. Discharge Point 001 Latitude: 35°26'10" Longitude: 80°56'30" 002 & 003 35°25'40" 80°57'20" Attach a USGS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No. F15NW 7. Size (land available for expansion and upgrading): The existing site encompasses approximately fifty (50) acres. There is adequate land available to construct additional treatment facilities and modifications. 8. Topography (relationship to flood plain included): Mildly rolling, slopes are generally less than 10%. The existing facilities do not appear to be within any flood plain. 9. Location of nearest dwelling: None within 1000 feet 10. Receiving stream or affected surface waters: 001 002 & 003 Lake Norman Catawba River WS III & B WS III 03-08-32 03-08-33 a. Classification: b. River Basin and Subbasin No.: c. Describe receiving stream features and pertinent downstream uses: 0utfall 001: The receiving water body (Lake Norman) is used extensively for primary and secondary recreation and as a municipal water supply. The nearest water intake is for the Town of Huntersville and is located approximately 3 miles northeast of the discharge. -2- 0utfall 002 & 003: The receiving river is used extensively for primary and secondary recreation and as a municipal water supply. The nearest water intake is for the City of Charlotte and is located approximately 10 miles downstream. PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. Type of wastewater: 001 002 003 0 0 100 % Domestic 100 100 0 % Industrial a. Volume of Wastewater: 001 002 003 2525 .41 0.04 MGD (average daily) (based on flow schematic attached to application) b. Types and quantities of industrial wastewater: 0utfall 001 (Cooling Water Discharge): This discharge is a combination of condenser cooling water (1,727,100 gpm), conventional low pressure service water (6,500 gpm), nuclear service water (20,000 gpm), low level liquid radwaste (8 gpm) and *turbine building sumps (70 gpm). **0utfall 002 (conventional treatment system discharge): This discharge consists of steam generator blowdown, condensate demineralizer backwash, water treatment system backwash, demineralizer backwash, building drains, metal cleaning wastes and *turbine building sumps. 0utfall 003 (sanitary waste treatment system): This discharge consists of the domestic type waste generated by plant personnel. c. Prevalent toxic constituents in wastewater: 0utfall 001 ***0utfall 002 Outfall 003 Biocides (see attached Low level radioactivity None letter dated 2/28/86) low level radioactivity, chlorine, sodium hydroxide, lithium hydroxide, monohydrate, sulfuric acid, boric acid d. Pretreatment Program (POTWs only): N/A. 2. Production rates (industrial discharges only) in pounds: Information not available in any application submittals received by MRO. If information is needed it should be requested from the applicant. Description of industrial process (for industries only) and applicable CFR Part and Subpart: 40 CFR Part 423 - Steam Electric Power Generation 4. Type of treatment (specify whether proposed or existing): 0utfall 001 The existing liquid radwaste system consists of filters, evaporators and demineralizers. (Note: this process treats only a small portion of the total discharge of outfall 001). The combined wastewaters of outfall 001 flow into Lake Norman via a discharge canal approximately 2500 feet long and 200 feet wide. The canal is for the purpose of heat dissipation. 0utfall 002 Wastewater is treated in the plant's existing conventional wastewater treatment system which consists of a 200,000 gallon initial holding pond, two (2) settling ponds (in parallel) each with 2.5 million gallon capacity, a 1 million gallon final holding pond (aerated -diffused air) and effluent pH adjustment consisting of automated CO2 addition. The initial holding pond acts as a flow equalization basin. This pond may be bypassed, depending on the nature of the wastewater. The two settling ponds are operated such that one pond remains in standby. Treatment can be enhanced by the addition of coagulant aids and pH adjustmentin these ponds. The effluent from the settling ponds may be discharged directly to the receiving stream via outfall 002 or it may be routed to the final holding pond. Effluent from the final holding pond may be discharged through outfall 002 or recirculated to the settling ponds, depending upon effluent quality. 0utfall 003 The existing sanitary WWTP consists of a multicellular aerated -facultative lagoon, a chlorine contact chamber (tablet), and a parshall flume. The discharge from outfall 003 enters an impoundment which also receives area surface runoff. The overflow from the impoundment combines with the discharge from outfall 002 prior to discharge into the Catawba River. The sanitary WWTP is designed for a maximum of 64,000 gpd. 5. Sludge handling and disposal scheme: (Information received by telephone from Mr. W. T. Griffin on 8/26/86). 0utfall 001: Sludges which accumulate in the liquid radwaste system are disposed as low level radioactive wastes at approved repositories such as Barnwell, S. C. 0utfall 002: Sludges are disposed by landfarming at a designated on -site disposal area. This disposal is permitted by DEM Permit No. 7641R2. 0utfall 003: Sludge is periodically removed from the lagoon and disposed at a municipal WWTP. Currently, the disposal is made at CMUD's McDowell Creek WWTP. 6. Treatment plant classification: Attached are copies of suggested revised rating sheets being sent to John Campbell for consideration. If approved the revised rating will be as follows: 0utfall 001: Class IV; 0utfall 002: Class III, 0utfall 003: Class I *Based on information given to the investigator during the inspection. Note: The turbine building sump water will normally go to the conventional wastewater treatment system for discharge thru outfall 002. However, in instances where the radioactivity of the sump water is sufficiently low (within NRC requirements) the water may be released directly thru outfall 001. If radioactivity level exceeds NRC requirements, the sump water must first be routed to the liquid rad- waste processing system prior to discharge thru outfall 001. -4- **The application does not provide sufficient information to ascertain specific quantities for each type of wastewater included in this outfall (002). If this information is necessary, it should be requested. ***Refer to information submitted by letter from Duke dated June 18, 1982 for full listing of metals, etc. If a copy is not available in Central Files, please contact MR0 for a copy. PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grants Funds (municipals only)? N/A. 2. Special monitoring requests: See Part IV 3. Additional effluent limits requests: None 4. Other: None PART IV - EVALUATION AND RECOMMENDATIONS Duke's application for amendment essentially covers three (3) changes to and clarifications of operations at the plant that have occurred since last issuance of the permit (9/1/84) as outlined below: 1. Duke has modified their operations such that turbine sump water may now be discharged via outfall 001 (see part II * for detail). The manner of release is reportedly governed by NRC approved plant procedures. Duke has submitted a copy of these approved procedures (copy attached). 2. Duke has begun using biocides and chemical additives which are ultimately discharged thru 0utfall 001. (See attached report from Duke dated 2/28/86 for explanation and listing of materials used). 3. Duke has now placed the new multicellular aerated facultative lagoon WWTP (sanitary treatment system) in service and has abandoned the previously used package WWTPs. As is typical with any such request for permit renewal or amendment, the investigator has attempted to review the adequacy of the existing permit, least we should continue any inadequacies in ,a new, revised permit. This review has prompted serious concern with respect to the monitoring of possible radioactive releases thru outfalls 001 and 002. We can find nothing in our file copy of Duke's permit which provides any assurance that such releases are being monitored or that they are properly limited. In Duke's application documents (for this latest modification and for applications in years past) Duke has indicated that such releases are low level and are in accordance with NRC approved station operating procedures. Further, it is our understanding, thru conversations with Duke personnel, that Duke submits reports regularly to NRC with respect to the amounts and types of radiation released. If this is the case, then NRC is regulating the levels of radioactivity released thru DEM permitted outlets (001 & 002). This is no problem if NRC is reviewing Duke's releases in a responsible manner (and we are confident that they are) and that the controls which they impose take into consideration DEM's concerns to protect water quality (not just human health). Obviously the answer to this question is not easily obtained and would appear to be a matter best resolved by a written agreement between the NRC and DEM. An agreement such as this would be advisable since NRC is obviously themore qualified of our agencies for such a matter and this would merely be an official acknowledgement that this is, in fact, their responsibility. DEM could then makereference to such fact in the NPDES Permit and establish that the reporting and procedures for radioactive releases will be done in accordance with NRC requirements. Thus, if there should ever be a problem with such releases, DEM would have some avenue for action. Such an avenue does not exist in the current permit. This matter has been discussed with Mr. Dayne Brown, NC-DHR-Radiological Unit and Mr. Darrel Hood, NRC. Neither are aware of the existence of any such agreement and both agree that this may be advisable and warrants further consideration. We recommend that this matter be discussed with the Water Quality Section Chief and that negotiations be initiated with NRC with the goal of developing an inter -agency memorandum of understanding. We believe that this is in the best interest of both DEM and NRC not just for the McGuire Station but for all nuclear stations within the State. Upon resolution of this matter, it is recommended that the NPDES Permit be reissued with limitations and monitoring requirements appropriate for this industrial category and for the revised class of each outfall. Note: The permit should not be drafted until the proposed revised facility rating has been reviewed and classifications assigned. Signature-bf reporti)reparer Water Quality Regiona, upervisor PA NY 'AI2TNIENT IN)X :1:11)13), •1,22 sr>rrrr crruu4;rr tii'r+r:rrr i ;lrn Ni,(YITI , \.(;., 21i (70;) :i7:3-•).011 December 4, 1985 DEC 1985 PERMITS & ENGINEERING Mr. R. Paul Wilms, Director N. C. Division of Environmental. Management P. O. Box 27687 Raleigh, NC 27611-7687 SUBJECT: McGuire Nuclear Station NPDES Permit Application Modification FILE: MC-704.15 Dear Sir: The McGuire Nuclear Station NPDES permit (permit no. NC0024392), Part II.A.1., specifies that notice is to be provided to the Division of Environmental Management of process modifications that affect discharge of pollutants. This letter provides notice of such a modification, specifically pertaining to the turbine building sump discharge. Attached are the parts of the permit application that are affected by the modification, as well as an update on approved modifications to the sewage treatment system. Very truly yours, H. B. Tucker, Vice President Nuclear Production Department WTG/wmc Attachment cc: South Piedmont Office U. S. Nuclear Regulatory Commission, Region II Reactor Coolant System (NC) The Reactor Coolant. System transports heat from the reactor to the steam generators where the heat is again transferred to the Feedwater/Main Steam System. Approximately 120 pounds of Lithium hydroxide monohydrate are used in each unit per year for p11 control. The lithium is removed by demineralizers in the NC system or by the Radioactive Liquid Waste Recycle System. The resins and the cvap<car;at.or bottoms are drummed for offsite disposal scar i_n either •case, lithium is not normally discharged. Approximately 60,000 pounds of boric acid per year pose unit are used for reactor shim. Boric acid wastes are concentrated and the evaporator bottoms are drummed for offsite disposal. Small quantities of boron are released from the Radioactive Liquid Waste Recycle System as a result of evaporator carryover and when radiation levels are low enough so as not to require evaporation. The discharge from the system will be diluted by large quantities of condenser cooling water. Liquid Radwaste System The Liquid Radwaste System collects all radioactively contaminated water from the equipment drains, spills, or leaks within the auxiliary and reactor buildings. The system is monitored and operated such that low level radioactive waste may be released when its activity is below prescribed limits or may be recycled to the Reactor Coolant System. The system utilizes filters, evaporators, and demineralizers for the treatment process. All releases are regulated by the Nuclear Regulatory Commission and are made to assure compliance with 10 CFR 50 Appendix I. Maximum flow from the system is 300 gpm. NOTE: The turbine building sumps are normally routed to the Conventional Wastewater Treatment System (WC). However, when the sump has radioactive contamination, its discharge may continue to be released to the WC system, may be routed to the normal Liquid Radwaste System discharge line for release to the condenser circulating water or to the Liquid Radwaste Collection tanks for processing prior to release. The release method to be used depends on the level of radioactivity, volume of wastes, other wastes to be processed, NRC Technical Specifications processing requirements, potential for an oil spill, and on the need to process chemical wastes. Outfall 002 Outfall 002 discharges treated water from the Conventional Wastewater Treatment System to the Catawba River below Cowans Ford Dam. Co11Vc: Conventional Wastewater non -radioactive plant: (WC) t System acc pts (excluding ry sew ) treats it through a system of basins with cherni.c 11 <a€3ditian and acrat1011 and discharges i.t 1Lo the Catawba River. The turbine building sump, water treatment system filter backwashes, condensate demineralizer backwashes, and make up deminer.alizer regeneration wastes will be routed through this system aric:aa to discharge to the Catawba River. Wastes are initially directed to a concrete lined initial holdup pond where primary sedimentation occurs. This 200,000 gallon capacity basin has a retention time of from 12 hours to 24 hours and acts as a surge tank to prevent overloading and subsequent degradation of effluent quality throughout the remainder of the system. This pond may be bypassed depending on influent quality. Initial holdup pond is followed by parallel stream settling ponds. These two 1.1 acre, 2.5 million gallon ponds are lined with tamped clay and are equipped for recirculation. The ponds are operated such that one pond is in service while the other is on standby. Coagulent aids may be used for settling lighter solids along with p11 adjustment to neutralize or precipitate various chemical compounds. Holdup time for each of these basins ranges from 6 to 12 days. The wastewater then normally flows by gravity to the final holdup pond where it is aerated; retention time for this basin is 5 days. This final holdup pond is used to remove any persistent oxygen demand of the wastes. The pond has a capacity of one million gallons. Its contents may be pumped to the head of the settling basins or back to its own inlet for recirculation if the effluent does not meet the established discharge limits. The final holdup pond may be bypassed and the discharge flows by gravity or is pumped to the river if the effluent from the basin is within specifications. The final effluent pH is normally adjusted with an automatic CO2 addition system before discharge. NOTE: In as much as the WC system accepts influent from the turbine building sump, any primary to secondary leak may result in contamination of one of the settling basins and possibly the initial hold-up pond. In this case, the basin is isolated to allow for dilution and radioactive decay as required by NRC Technical Specifications. In addition, demineralizers 3]_ additives may be used to process the waste cases from the pond will comply with McGu ire Speci fi..cations. CB) The Collection Basin receives treated sanitary effluent, yard drainage and overflow from the Standby Nuclear Service Water Pond. The overflow from the CB mixes with the discharge from the WC system in a concrete protected apron and is discharged to the Catawba River downstream of Cowans Ford Dane. Outfall 003 Outfall 003 discharges treated sanitary waste from the Sanitary Waste Treatment System to the Collection Basin. Sanitary Waste Treatment System The Sanitary Waste Treatment System consists of an aerated -facultative lagoon system which is a trapezoidal multicellular arrangement consisting of a completely suspended cell followed by three partially suspended cells in series. The lagoon provides an approximate 5-day retention time and will allow for variable flow discharge. The wastewater effluent from the aerated lagoon flows through chlorinators, a chlorine contact chamber and a Parshall Flume before discharging to the Collection Basin. Expansion space is provided should a sand filter be required in the future. The lagoon is lined with a flexible synthetic material such as hypalon, it is divided into four cells by a curtain material such as a polymer coated polyester with a weighted chain ballast and floatation collar. The first cell provides for a two day retention time and is kept in complete suspension by surface mechanical aerators. The second and third cells are kept partially suspended providing for partial settling. Each of these two cells has a retention time of one day. The final cell is the settling cell with a retention time of one day. The surface of this cell is kept slightly agitated to minimize algal growth. From the final cell, the wastewater discharges to a chlorination installation. After passing through the chlorinators, a retention time in excess of 30 minutes is provided by a contact chamber before being discharged to the Collection Basin. The sewage lagoon capability at 5, different levels provide a 5-day flow rates of 40,000 respectively. a multiple level discharge and 8 feet. At each of these tion, the lagoon is able to time for influent wastewater gpd, 52,000 gpd, and 64,000 gpd, LAKE NORMAN NSW INTAKE FIRE PROTECTION LAKE NOR AN NTAKE INTAKE SCREEN BACKWASH 4 NSW SYSTEM CCW SYSTE M LPSWNV. © SYSTEM FILTERED WATER SYSTEM 2 271 6 250 DEMIN. WATER $YSTEM ACKWASH REENERATIV SANITARY POTABLE WATER SEWAGE TREATMENT SYSTEM OUTFALL 003 2 ASTE SECONDARY & AUX, COOLANT SYSTEMS STEAM GEN. BLOWDOWN LEAKAGE & DRAINAGE METAL CLN. WASTES D/G SUMPS REACTOR COOLANT SYSTEM TURBINE BUILDING SUMPS COND. DEMIN. BACKWASH QUID DWAST E OCESSING NOTE ALL FLOWS ARE IN GPM FOR AVERAGED CONDITIONS. ELECTION BASIN RAINFALL SNSW POND RUNOFF E VAP. & SEEPAGE CONY. WASTE WATER TREATMENT OUTFALL C2 2B2 ©2 LAKE NORVAN OUTFALL DO1 CATAWBA. RIVER (DUKE POWER COMPANY MCGUIRE NUCLEAR STATION WATER FLOW SCHEMATIC April 14, 1986 SiONVOrt Ftk�..tl C N7A 1. MANAGLMENV YORESYKAA Mr Thurman Horne Water Quality Section South Piedmont Regional Office N.C. Department of Natural Resources and Community Development Division of Environmental Management 919 North Main Street Mooresville, NC 28115 SUBJECT: Turbine Building Sump Release Radwaste Discharge Point File: MC-704.15 Dear Mr. Horne: During your inspection at McGuire Nuclear Station on March 27, 1986, you requested information concerning releasing the turbine building sump through the radwaste release point. Attached, for your information, is a copy of the station procedure, Radioactive Liquid Waste Release. Section 4.4 is the procedure for releasing the turbine building sump. During the inspection, as you may recall, we stated that we were limited by NRC on the release of specific radioisotopes as well as total radiation. Section 3.3 of the attached procedure addresses this. Enclosure 5.3, Manual Calculations, is the method for calculating the amount of activity that is released. As you can see, for each isotope, the isotopic concentration ( uCi/ml) is divided by the maximum permissible concentration (MPC,MCi/ml); all isotopic concentrations are then totalled. The release rate is then calculated to ensure sufficient dilution. Should you have any additional questions, please contact me at (704) 373-5764. Sincerely, R.T. Simril, System Engineer Nuclear Environmental Compliance by: W.T. Grii 'n Environmental Engineer WTG/rhm attachment rVED Form 34731 (R8-85) 1 PREPARATION (2) STATION bra Nuclear Station (3) PROCEDURE TITLE Radioactive Liquid Waste Release (LWR) 10 Change(%) —5 .__Incorpora (4) PREPARED BY -, DATE . /1Je7 G (5) REVIEWED BY 1J1 /h Ce Y, /�rG r1 DATE Cross -Disciplinary Review By N/R laiFer3 (6) TEMPORARY APPROVAL. (If Necessary) By (SRO) Date By (7) APPROVED BY Atie,A404z,0*-- Data DATE (81 MISCELLANEOUS Approved By Date .ai ► —,""' Reviewed/Approved By Date (91 COMMENTS (For procedure reissue indicate whether additional lunges. other than previously approved charges, are inctuded. Attach additional page, if necessary.) OAODITIONAL CHANGES INCLUDED. COMPLETION (10) COMPARED WITH CONTROL COPY DATE (11) DATE(S) PERFORMED (12) PROCEDURE COMPLETION VERIFICATION © Yes © N/A Cited' Nees and/or Menem property initialed. signed. dated or filled in N/A or N/R. • appropriate? © Yes 0 N/A LMatimaisolros astednd? CI Yes 0 WA Om dross attached, cornpbt.d dated and tied? © Yes 0 WA CaIIi, mks. tee. attached and properly dated. identified and monied? © Yes 0 N/A Aawpsanaa arisen. nett VERIFIED SY DATE (131 PROCEDURE COMPLETION APPROVED DATE 1141 REMARKS (Attach additional pages, if necessary. 1 HP/0/B/1003/02 DUKE POWER COMPANY McGUIRE NUCLEAR STATION RADIOACTIVE LIQUID WASTE RELEASE (LWR) 1.0 Purpose This procedure describes the proper method of aastpling, initiating and documenting a radioactive liquid release from a Waste Monitor Tank (WMT) or Recycle Monitor Tank (RMT), Containment Ventilation Unit Condensate Drain Tank (CVUCDT), or Turbine Building Sump (TBS) to the RC System. 2.0 References 2 1 Duke Power Company, McGuire Nuclear Station, Liquid and Gaseous Radwaste Computer Program User's Documentation. 2.2 McGuire Nuclear Station, Technical Specifications 3.11.1.1 2.3 Station Health Physics Manual, Section 13.5: Preparation of Sample for Count Room Analysis. 2.4 Station Health Physics Manual, Section 13.6; Composite Sampling. 2.5 HP/0/B/1003/08, Determination of Radiation Monitor Setpoints (EMF's). 2.6 HP/0/B/1009/13, Health Physics Actions for Inoperable Liquid Effluent Monitoring and Sampling Devices. 2.7 PT/0/B/4600/18, Radioactive Liquid Effluent Sampling and Analysis Frequency. 2.8 0P/0/8/6200/35, Radwaste Procedure for Discharging a Waste Monitor Tank to the Environment. 2.9 OP/0/B/6200/43, Radwaste Procedure for Discharging a Recycle Monitor Tank to the Environment. 2.10 Code of Federal Regulations, Title 10, Part 20, Appendix B. 2.11 OP/0/1/62OO/56, Radwaste Chemistry Response to Indication of a !Timmy to Secondary Leak. 2.12 0P/1/I/6400/OIA, Condenser Circulating Water and Low Level Intake; Enclosure 4.11, Operation of Turbine Building Sump with High Activity to RC Discharge. 2.13 OP/0/A/6500/O1A, Ventilation Unit Condensate Drain Tank Operation. 3.0 Limits and Precautions 3.1 Proper Health Physics methods shall be used when handling radioactive or potentially radioactive liquids. -2- 3.2 All liquid waste release (LWR) and dose calculations shall be made by use of appropriate computer codes per Reference 2.1. The manual methods presented shall be used if the computer is not available. 3.3 All releases shall be added to the total quarterly release using the appropriate computer codes (Reference 2.1) to ensure that quarterly and annual limits are not exceeded. 3.4 Corrections to the LWR Computer Program after the program has been terminated shall be handled by the Radioactive Materials Control Group personnel with assistance from the General Office Radwaste Engineering staff as necessary. 3.5 If for any reason the EHF, composite sampler, or flow totalizer is inoperable, refer to HP/O/B/1009/13 for required action. 3.6 Sample analysis results shall be valid for 4 hours for a CVUCDT and TBS release and 24 hours for a WMT/RMT release from the time sample was obtained. 3.7 Radwaste Chemistry shall be allowed 3 consecutive attempts at releases via EMF49(L) with Hi-Rad Trips before a resample shall be required. 3.8 If for any reason the release has to be terminated prior to completion, the H.P. controlled valve (WH116 for WMT-A, WM43 for WHT-B, WM222 for 1-CVUCDT, WM225 for 2-CVUCDT, WM47 for TBS) shall be locked closed. 3.9 Boron analysis shall be performed when the effluent is expected to contain 2 1000 ppm Boron. 3.10 TBS sampling and the release may be terminated when all of the following are true: 1. No activity (except dissolved and entrained gases) above background is identified in two consecutive samples. 2. •o additional sources of activity to the sumps are anticipated. 3. Tda total activity of dissolved and entrained gases is less than 2.0E-4 Mci/ml. 3.11 Manual adjustments of EMF trip setpoints shall be performed using HP/0/B/1003/08 Enclosure 5.4. 3.12 Five LWR spares shall be entered on the VAX computer as soon as possible on the first day of the month. 4.0 Procedure 4.1 For a WMT/RMT release go to Section 4.2. For CVUCDT release go to Section 4.3. For a TBS release go to Section 4.4. 4.2 WMT/RHT Release NOTE 1: Prior to WMT/RMT release read the Limits and Precautions and Section 4.2 of this procedure. NOTE 2: This procedure is performed in conjunction with Chemistry release procedure Reference 2.8 or 2.9. NOTE 3: If EMF49(L) is inoperable, refer to HP/0/B/1009/13 for inoperable action. 4.2.1 Determine the Recommend Release Rate using Enclosure 5.1. 4.2.2 Record EMF49(L) as the EMF Utilized. 4.2.3 If EMF49(L) is inoperable, record EMF49(L) Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.2.5. 4.2.4 Determine the EMF49(L) Setpoints using HP/0/B/1003/18. Record setpoints and sign the Discharge Document. 4.2.5 Independently verify the following and sign adjacent to the performing Health Physics Technicians signature (see Enclosure 5.2, page 1 of 3). 4.2.6 (a) Any manual calculations such as Boron Release Rate and Multiple Release Calculations. (b) Recommended Release Rate. (c) EMF Trip 2 Value. Take the Discharge Document and associated paperwork as prescribed in the Chemistry release procedure to the Control Room. NOTE: The isotopic analysis printout can be replaced with the computer program MGLIQRPT (Reference 2.1). -4- 4.2.7 Adjust the EMF49(L) Setpoints, record in the EMI' Log Book and deliver the document to the Operations Shift Supervisor for appropriate signoffs. I.V. Trip 4.2.8 Take the discharge document and Chemistry release procedure to Radwaste Chemistry personnel (716 Elevation). NOTE: ,Ensure that all Health Physics signoffs in the Chemistry release procedure are completed up to this point. 4.2.9 As requested by Radwaste Chemistry, complete the Health Physics portion of the Chemistry release procedure. 4.2.10 After the release is terminated, return EMF49(L) Setpoints to the values in HP/0/B/1003/08 Enclosure 5.1 and record in the ME Log Book. I.V. Trip 4.2.11 Review the LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.2.12 Record release information on PT/0/B/4600/18 Enclosure 13.1 and composite the appropriate volume as per reference 2.4. 4.3 CVUCDT Release 4.3.1 At the request of Operations, and after the CVUCDT has been in recirc for thirty (30) minutes, obtain a Grab Sample (cube container) from valve 1 or 2 WL403. Allow the sample line to purge until no air is observed prior to obtaining sample. Note the composite jug level. 4.3.2 Analyze 3500 ■1 sample for principal gamma emitters and tritium per Reference 2.7. NOTE 1: If the composite sampler is inoperable, label and retain this sample for the weekly coapositing and refer to HP/0/B/1009/13 and H.P. Manual Section 13.6 for inoperable, action. NOTE 2: If EMF44(L) is inoperable, refer to HP/0/B/1009/13 for inoperable action. -5- 4.3.3 Determine the Recommended Release Rate using Enclosure 5.1. 4.3.4 Record 1 or 2 EMF44(L) as the EMF Utilized. 4.3.5 If EMF44(L) is inoperable, record 1 or 2 EMF44(L) Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.3.9. 4.3.6 Obtain the EMF44(L) reading from the Control Room and record as the EMF Background Reading on the Discharge Document. 4.3.7 Determine the Expected CPM of the EMF by multiplying the EMF Correlation Concentration (Cs-137 Equivalent Activity from HP/0/B/1003/18) times the EMF Correlation Factor from HP/0/8/1003/08 Enclosure 5.3. NOTE: If the EMF Correlation Concentration (Cs-137 Equivalent Activity from HP/O/B/1003/18) is 5.0E-4 NCi/ml, notify the H.P. Shift Supervisor for approval of the release or send the tank contents to the Floor Drain Tank. 4.3.7.1 Record the value from Step 4.3.6 or 4.3.7 (whichever is greater) as the Expected CPM of the EMF. 4.3.8 Determine the EMF44(L) Setpoints as follows, record setpoints and sign the Discharge Document. 4.3.8.1 Trip 2 Setpoint S 3.0E4 (#P) where: 3.0E4 = derived from HP/0/B/1003/08 Enclosure 5.1 Note 12B for 1 RC pump running and the release rate (f) is 120 gpm. +1P = the number of RC pumps dedicated to the release NOTE 1: Trip 1 shall be greater than background but less than Trip 2. _b_ NOTE 2: If needed, the maximum Trip 2 setpoint shall be calculated using HP/0/B/1003/08 Section 4.2. 4.3.9 Independently verify the following and sign adjacent to the performing Health Physics Technician's signature (see Enclosure 5.2, page 1 of 3). (a) Any manual calculations such as Boron Release Rate and Multiple Release Calculations. (b) Recommended Release Rate. (c) EMF Trip 2 Value. 4.3.10 Take the Discharge Document to the Control Room, have Operations adjust EMF44(L) Setpoints, record in the EMI' Log Book, and deliver the document to the Operations Shift Supervisor. I.V. Trip ; 4.3.11 NOTE: If the flow totalizer is inoperable, notify Operations to manually calculate the volume discharged. I.V. WM222 4.3.12 Record the start date and tine, and the LWR # on the CVUCDT chart recorder (0 WL 5900), initial it and inform Operations of this action. 4.3.13 Coordinate with Operations to achieve the desired release rate. 4.3.14 Once the release has started and daily if continuous release, 4.3.14.1 Check the operation of the flow totalizer by observing an appropriate change in the totalizer count when compared to the actual release rate. 4.3.14.2 Check the operation of the composite sampler by observing sample collection or a change in the composite jug level. At the request of Operations, rezero the CVUCDT flow totalizer, and unlock and open WM222 (Unit 1) or WM225 (Unit 2). Report these actions completed and your name to Operations. or WM225 -7- NOTE I: If the flow totalizer or composite sampler is inoperable, refer to HP/O/B/1009/13 and H.P. Manual Section 13.6 for action. NOTE 2: pH adjust the composite sample per reference 2.4 step 4.7. 4.3.14.3 Obtain a grab sample at least once per 24 hours by having Operations put the tank in recirc and obtaining a sample after recirc has been in progress for thirty (30) minutes. 4.3.14.4 Analyze 3500 ml sample for principal gamma emitters and tritium. 4.3.14.5 If the sample results indicate a new isotope, an isotope disappears or the concentration of any isotope changes by a factor of 10, generate a new LWR per 4.3.3 through 4.3.10. Go to 4.3.14.7. 4.3.14.6 If the current LWR is to continue, read and rezero the totalizer reporting the volume to Operations. Continue step 4.3.14. 4.3.14.7 Close out the current LWR by obtaining the volume released and rezeroing the flow totalizer. 4.3.14.8 Perform steps 4.3.12 and 4.3.13. 4.3.14.9 Perform steps 4.3.16 and 4.3.17. 4.3.14.10 Continue step 4.3.14. 4.3.15 When notified by Operations that the release is secured, 4.3.15.1 Close and lock WM222 (Unit 1) or WM225 (Unit 2). 4.3.15.2 Record the totalizer reading for discharge volume. 4.3.15.3 Record the stop date and time on the CVUCDT chart recorder and initial it. 4.3.15.4 Report to Operations the volume discharged, WM222 or W!l225 is locked closed, and the chart recorder marked. 4.3.15.5 Ensure that Operations returns 1 or 2 EIIF44(L) Setpoints to the values stated in HP/0/B/1003/08 Enclosure 5.1. Record in the EMF Log Book. I.V. Tri -8- 4.3.15.6 Check the composite jug level to ensure an adequate amount has been collected. 4.3.16 Review the LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.3.17 Record the required release information on PT/0/13/4600/18, Enclosure 13.3 and composite as per reference 2.4. 4.4 Turbine Building Sump Release to RC System NOTE: If EMF31 Trip 2 alarms while discharging to RC, perform the following: 1. Obtain a sample. 2. Obtain the EMF reading. 3. Calculate the new EMF31 Trip 2 setpoint per 4.4.8.1 below. This setpoint must be above the ENF reading. 4. Evaluate this setpoint for multiple releases in progress per Enclosure 5.1 step G or have Operations secure any other release in progress. 5. Have Operations record the totalizer reading, rezero the totalizer, and close out the current TBS LWR. 6. Have Operations reset E!!F Trip 2 setpoint and give them permission to initiate a new release without LWR paperwork to prevent overflowing of the sump. Operations shall keep track of the volume from the start of the release. 7. Generate a new LWR for the TBS as soon as possible and reinitiate any secured releases from other sources, ensuring multiple release calculations are performed (Enclosure 5.1, Step G). 4.4.1 Obtain a representative sample of the TBS per RP/00/1009/18 Enclosure 5.2, Sampling Instructions. 4.4.2 Analyze 3500 ml sample for principal gamma emitters and tritium per Reference 2.7. NOTE 1: Label and retain this sample for weekly compositing. 4.4.3 -9- NOTE 2: During a 1° to 2° leak Radwaste Chemistry may use portable demineralizers to clean TBS effluent. In this case samples for release rate determination shall be obtained from the demineralizer outlets. NOTE 3: If EF31 is inoperable, refer to HP/0/B/1009/13 for inoperable action. Determine the Recommended Release Rate using Enclosure 5.1. NOTE: If Operations is unwatering the condenser of the affected unit, ensure that 1RC21 (Unit 1) or 1RC22 (Unit 2) is closed. 4.4.4 Record 1 or 2 EMF31 as the EMF Utilized. 4.4.5 If EMF31 is inoperable, record 1 or 2 EMF31 Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.4.9. 4.4.6 Obtain the EMF31 reading from the Control Room and record as the EMF Background Reading on the Discharge Document. 4.4.7 Determine the Expected CPM of the EMF by multiplying the EMF Correlation Concentration (Cs•137 Equivalent Activity from HP/0/B/1003/18) times the EMF Correlation Factor from HP/0/8/1003/08 Enclosure 5.3. 4.4.7.1 Record the value from Step 4.4.6 or 4.4.7 (whichever is greater) as the Expected CPM of the EMF. 4.4.$ Determine the EHF31 Setpoints as follows, record and sign the Discharge Document. 4.4.8.1 Trip 2 Setpoint S 6..0E3(#P) where: 6.0E3 = derived from HP/0/B/1003/08 Enclosure 5.1 Note 181 for 1 RC pump running and the release rate (f) is 500 gp.. UP = the number of RC pumps dedicated to the release. 4.4.9 4.4.10 4.4.11 4.4.12 4.4.11.2 4.4.11.3 Once the 4.4.12.1 4.4.12.2 -10- NOTE 1: Trip 1 shall be greater than background but less than Trip 2. NOTE 2: If needed, the maximum Trip 2 setpoint shall be calculated using HP/0/B/1003/08 Section 4.4 for 1EMF31 or 2EMF31. Independently verify the following and sign adjacent to the performing Health Physics Technician's signature (see Enclosure 5.2, page 1 of 3). Any manual calculations such as Boron Release Rate and Multiple Release Calculations. Recommended Release Rate. EMF Trip 2 Value. Take the Discharge Document to the Control Room and notify Operations to align the TBS for discharge to the RC system. NOTE: If the TBS flow totalizer is inoperable, notify Operations to manually calculate the volume discharged. Prior to release, 4.4.11.1 Nave Operations rezero the TBS adjust the EMF31 Setpoints and ENT Log Book. Open the compo Unlock i 147. release has started and daily, Check the operation of the flow totalizer by observing an appropriate change in the totalizer count when compared to the actual release rate. Check the operation of the composite sampler by observing sample collection or a change in the composite jug level. flow totalizer record in the e sampler isolation valve. I.V. Trip -11- NOTE 1: If the flow totalizer or composite sampler is inoperable, refer to HP/O/B/1009/13 and H.P. Manual Section 13.6. NOTE 2: pH adjust the composite sample per reference 2.4 step 4.7. NOTE 3: If Operations is unwatering the condenser of the contaminated unit, sample the WU system at the following frequency. a. Once the TBS pumps are aligned to RC and then once per 12 hours. b. One hour after the initiation of any WMT or CVUCDT release. Obtain the sample for the affected WU system, at Column 1H27 (valve 1WU18) or Column 2H27 (valve 2WU18) located in the Turbine Building Basement. 4.4.12.3 Obtain a grab sample at least once per 24 hours. 4.4.12.4 Analyze 3500 ■1 sample for principal gamma emitters and tritium. 4.4.12.5 If the sample results indicate a new isotope, an isotope disappears or the concentration of any isotope changes by a factor of 10, generate a new LWR per 4.4.3 through 4.4.10. Go to 4.4.12.7. 4.4.12.6 If the current LWR is to continue, continue step 4.4.12. 4.4.12.7 Closeout the current LWR by ensuring the volume discharged is recorded and Operations rezeros the flow totalizer. 4.4.12.8 Perform steps 4.4.14 and 4.4.15. 4.4.12.9 Continue step 4.4.12. -12- 4.4.13 When the release is terminated, 4.4.13.1 Lock close WM47. 4.4.13.2 Close the composite sampler isolation valve. 4.4.13.3 Collect any water from the composite sampler. 4.4.13.4 Have Operations return EMF31 Setpoints to the values in HP/0/B/1003/08 Enclosure 5.1. Record in the EMF Log Book. I.V. Trip 4.4.14 Review tie LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.4.15 Record release information on PT/0/B/4600/18 Enclosure 13.9 and composite as per reference 2.4. 4.5 RMC Review and QA Check 4.5.1 Compare the computer isotopic input sheet or manual calculation worksheet with the sample results used to calculate the release rate. 4.5.2 After any errors have been corrected using Enclosure 5.4, sign the LWR as Reviewed by RMC. 4.5.3 After the volume update of the LWR, a final QA check shall be performed to ensure the correct volume, start/stop time and date was entered. Use Enclosure 5.4 to correct any errors. 5.0 Enclosures 5.1 Release Rate Deteruinatio 5.2 Release Rate Determination Fors 5.3 Manual Calculations 5.4 Liquid Error Correction Request. RELEASE RATE DETERMINATION Computer Method HP/0/8/1003/02 Enclosure 5.1 Page 1 of 3 NOTE 1: An LWR number shall be assigned by the computer; verify in the GWR/LWR Log Book that the correct LWR cumber has been assigned. If this number is not correct, use the back-up procedure (Section II fo this Enclosure) assigning the higher LWR# (from VAX or GWR/LWR Log). Investigate discrepancy as soon as possible. A. Use Reference 2.1 and enter the isotopic analysis results, tritium, boron, and current Teledyne analysis results. Independently verify and sign the computer isotopic input sheet (see Enclosure 5.2, page 3 of 3). NOTE: The computer does not calculate the release rate based on boron. B. Attach the computer input sheet to the isotopic analysis. C. If required, record the Boron concentration on the Discharge Document and if Boron a 1000 ppm, calculate the Instantaneous Release Rate (fB) based on Boron Concentration as follows. (#RC Pumps Running) (2.5E5 gpa/puap)(1 SB #RC Pumps Running = obtained from Control Room (1-8 pumps) LB = ppm Boron in Lake. This value (current to within 6 weeks of release date, and less than 1 ppm) is obtained from Chemistry and monthly is posted in the Shift Lab. SB = ppm Boron in the sample D. Release rate calculations based on Hydrazine are not required; eater N/A. E. Record the System Release Rate or the calculated !lost Restrictive Instantaneous Release Rate based on the number of RC pumps required (whichever is less) as the Recommended Release Rate. RP/0/B/1003/02 Enclosure 5.1 Page 2 of 3 xOTZ: Unless the tank discharge flowrate is manually restricted, the Maximum System Release Rates are as follows: WMT = 120 gpm RMT : 120 gpm TBS = 500 gpm CVUCDT = 120 gpm F. Record Tank Concentration, Dilution Flow Available, or Maximum System Release Rate as Release Limited By. G. When performing multiple releases (i.e., WMT/RMT, TBS, CVUCDT) a calculation shall be performed to assure that MPC levels are not exceeded. 1. Determine the number of RC Pumps required for each release point. The total #RC pumps required for all releases shall not exceed 8. 2. Perform calculations to assure that MPC levels are not exceeded as follows. Record on the LWR. or RMT example: 120 + 500 + 500 + 120 500 1E4 1E5 8E3 '4E3 where: 120 .34 < 1 CVUCDT a Recommended Release Rate = Most Restrictive Instantaneous Release Rate based on the number of RC pumps required for each release point. The total #RC pumps required for all releases shall not exceed 8. NOTE: If sufficient dilution flow is not available to discharje sources simultaneously, one or .ore of the release rates (fREC) may be manually reduced or the CVUCDT may be sent to the Floor Drain Tank. Dilution flow shall first be allocated to the TBS, second to the WMT or RMT and third to the CVUCDT. HP/0/8/1003/02 Enclosure 5.1 Page 3 of 3 Also perform the following calculation and record on the LWR. # P used for TBS Trip 2 sp t # P used for CVUCDT Trip 2 sp # P available example: 1-TBS 0 #P available t 2 t 1.5 t -TBS 81-CVUCDT 82-CVUCDT #P used for WMT #P available where: # P available = # RC pumps running The total # RC pumps used for all releases shall not exceed 8. The information on the Release Rate Determination Form (Enclosure 5.2, page 2 of 2) labeled "To Be Completed Prior To Release" may be entered and signed off by Health Physics, Chemistry or Operations rather than the Shift Supervisor. II. Back-up Procedure; G.O. VAX Computer Method A. Use this procedure section if the Station VAX is inoperable. This method does not enter the release on the McGuire Liquid Release Program or assign an LWR number. When the Station VAX is operable again, enter all releases done on the G.O. VAX on the Station VAX, chronological order prior to entering any new releases. B. Record the LWR number in the GWR/LWR Log Book. C. Perform Enclosure 5.1 Section I. Steps A through H. III. Manual Method A. Use this procedure section if the Station VAX and G.O. VAX are inoperable/unavailable. B. Calculate the release rates using Enclosure 5.3, page 1,2,3 of 5. Record results on Enclosure 5.3 page 4. Independently verify and sign the Manual Calculation Worksheet (see Enclosure 5.3, page 2 of 5). NOTE: Ensure Tritium and current Teledyne analysis results are included. C. Perform Enclosure 5.1 Section I. Steps C through H and attach the Manual Calculation worksheet to the isotopic analysis. Enclosure 5.2 Page 1 of 3 A. [MR// Tank Tank Level Before Release x, Special Instruction(s) and/or Permiss Date Time Desired Tank Level After Release n for this Release RELEASE RATE DETERMINATION - TANK CONC. NCi/sl Instantaneous Release Rate 1. Fission & Activation Products 2. Tritium Concentration 3. Dissolved & Entrained Gases 4. Gross Alpha Concentration 5. Boron Concentration (ppm) NOTE: Release Rate Calculation Required Yes No If yes, List 6. Hydrazine Concentration NOTE: Release Rate Calculation Required Yes No If yes, List 0.00E+00 0.00E+00 0.00E+00 0.00E+00 cGUIRE NUCLEAR STATION TANK DISCHARGE RATE IN GPM 1 Pump 2 Pumps 3 Pumps 4 Pumps 5 Pumps 6 Pumps 7 Pumps 8 Pus 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.,50E+02 1.50E+02 1.50E 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E Recommended Release Rate GPM with RC pumps Release Limited By EMF Utilized EMF Correlation Concentration (Fission and Activation Products) Expected CPM of the EMF EMF Background heading EMF Trip 2 Setpoint EMF Trip 1 Setpoint Health Physics Technician Date Time NCi/m1 CPM CPM CPM CPM Reviewed by INC: Date: I.V. Date Time Enclosure 5.2 Page 2 of 3 Shift Supervisor Authorizing Release To Be Completed Prior To Release (Signature To Be Completed After Release Initial, Initial EMF Operable and Alarm (Trip 1) Set at CPM Recorder Stamped - LWR# Stop EMF Trip 2 Set at CPM Time/Date Release Secured No. of RC pumps operating Tank Level After Release Recorder Stamped - LWR# at Start Commence Flush per Procedure OP/Q/B/62 Time/Date Release Started Procedure OP/©/B/6400/43 Flush Secured Volume Release Completion of Release Acknowledged By Shift Supervisor Date: Time: Gallons Shift H.P. Review Date: Time: (Signature) (Signature) HP/0/B/1003/02 Enclosure 5.2 Page 3 of 3 EXAMPLE: COMPUTER ISOTOPIC INPUT SHEET System Rev-1.0 VAX/VMS Rev 4.1 Username: RWD7320 Password: Welcome to VAX/VMS - Duke Power Company Enter Name of Program: MGLIQUID THIS RELEASE NUMBER IS 0081 IS THIS THE CORRECT LWR#? (Y/N) Y PLEASE ENTER THE TYPE OF RELEASE EXAMPLE: RMT-A, RMT-B, WMT-A, WMT-B, 1-CVUCDT, 2-CCDT WC, SPARE, 1-TBS, 2-TBS 1-CVUCDT ENTER RADIONUCLIDE NAME XE-133 ENTER CONCENTRATION 4.01E-5 ENTER RADIONUCLIDE NAME CO-60 ENTER CONCENTRATION 3.51E-6 ENTER RADIOSOCLIIX RAM STOP CO-60 3.511-6 XE-133 4.01E-5 ARE THESE VALUES CORRECT? (Y/N) Y BETA -GAMMA TOTAL = 3.51E-6 ENTER NAME OF PERSON RUNNING REPORT H. SLOAN I.V. MANUAL CALCULATIONS Fissiomr-aad Activation Products a. Total all isotopic concentration (NCi/ml) NOTE 1: NOTE 2: b. Calculate HP/0/B/1003/02 Enclosure 5.3 Page 1 of 5 Tritium, dissolved and entrained gases, and gross alpha concentrations are to be included as valid isotopes in addition'to their separate concentration calculations. Tritium is not to be included in the sum for EMT' correlation concentration. release rate in GPM for conditions when 1 - 8 RC pumps ° are in service for dilution using the following formula: (P) (2.5E+5) Where: 2.5E+5 = gpm per RC pump P = number of pumps operating v = recirculation factor at equilibrium = 2.4 C. = the concentration of radionuclide, i, in undiluted effluent as determined by laboratory analysis in pCi/ml. MPC1 the concentration of radionuclide, i, from 10CFR20, appendix B. Table II, column 2 or Enclosure 5.3 page 3 of 5. Tritium Concentration a. Use same basic formula as in fission and activation products, except: C fa the concentration of tritium, i, in diluted effluent as determined by laboratory analysis, in NCi/al for tritium, value It 3.0E-3 Dissolved and entrained gases a. Use same basic formula as activation products, except: MPCi = 2.0E-4 NCi/al for all dissolved and entrained noble gases. 4. Gross alpha concentrations a. Use same basic formula as in fission and activation products, except: MPC1 = 3.0E-8 NCi/ml for gross alpha concentrations. fission and MANUAL CALCULATIONS WORKSHEET Flagon and Activation Products Isotope C. MPC. (P)(2.5E+5) (2.4) +c Ci MPC. i 2. Tritium: C. MPC. — 3.0E-3 (P)(2.5E+5) (2.4) f Ci Total HP/O/B/1003/02 Enclosure 5.3 Page 2 of 5 Dissolved and Entrained Gases: C Isotope f ci = (P)(2.5 (2.4) B C i=1 4. Gross Alpha: Ci MPC. 3.0E- (P)(2.5E+5) (2.4)! ci MPC MPCi 2.0E-4 2.0E-4 2.0E-4 2.0E-4 2.0E-4 Total. Performed by i=1 ci Ci I.V. HP/0/B/1003/02 Enclosure 5.3 Page 3 of 5 MPC. VALUES FROM 10CFR20 TRITIUM 3.00E-03 NB-95 1.00E-04 CS-138 3,00E-06 ALPHA ACT 3.00E-08 NB-95M 3.00E-06 BA-133 3.00E-06 BE-7 2.00E-03 NB-97 9.00E-04 BA-139 3,00E-06 F-18 5.00E-04 NB-97M 3.00E-06 BA-140 2,00E-05 NA-24 3.00E-05 MO-99 4.00E-05 BA-141 3,00E-06 CL-38 4.00E-04 TC-99M 3.00E-03 BA-142 3,00E-06 K-40 1.00E+130 TC-101 3.00E-06 LA-140 2.00E-05 CR-51 2.00E-03 RU-103 8.00E-05 LA-142 3.00E-06 MN-54 1.00E-04 RU-105 1.00E-04 CE-141 9.00E-05 MN-56 1.00E-04 RU-106 1.00E-05 CE-143 4,00E-05 FE-55 8.00E-04 AG-108M 3.00E-06 CE-144 1,00E-05 FE-59 5.00E-05 AG-110M 3.00E-05 PR-143 5,00E-05 CO-57 4.00E-04 CD-115 3.00E-05 PR-144 3,00E-06 CO-58 9.00E-05 CD-115M 3.00E-05 ND-147 6,00E-05 CO-60 3.00E-05 IN-113H 1.00E-03 W-187 6.00E-05 NI-63 3.00E-05 IN-115M 4.00E-04 BI-212 4.00E-04 NI-65 1.00E-04 I-130 3.00E-06 BI-214 3,00E-06 CU-64 2.00E-04 I-131 3.00E-07 PB-212 2,00E-05 ZN-65 1.00E-04 I-132 8.00E-06 PB-214 3,00E-06 ZN-69 2.00E-03 I-133 1.00E-06 TL-208 7.00E-06 ZN-69M 6.00E-05 I-134 2.00E-05 AC-228 9,00E-05 SE-75 3.00E-04 I-135 4.00E-06 TH-228 7.00E-06 BR-82 4.00E-05 SB-122 3.00E-05 NP-239 1.00E-04 BR-83 3.00E-06 SB-124 2.00E-05 AR-41 2.00E-04 BR-84 3.00E-06 SB-125 1.00E-04 KR-83M 2.00E-04 BR-85 3.00E-06 SN-113 8.00E-05 KR-85 2.00E-04 RB-86 2.00E-05 SN-123 3.00E-06 KR-85M 2.00E-04 RB-88 3.00E-06 SN-126 3.00E-06 KR-87 2.00E-04 RB-89 3.00E-06 TE-125M 1.00E-04 KR-88 2.00E-04 SR-89 3.00E-06 TE-127 2.00E-04 KR-89 2.00E-04 SR-90 3.00E-07 TE-127M 5.00E-05 KR-90 2.00E-04 SR-91 5.0M-05 TE-129 8.00E-04 XE-131M 2.00E-04 SR-92 CASK-05 TE-129M 2.00E-05 XE-133 2.00E-04 Y-90 E41111-05 TE-131 3.00E-06 X8-133H 2.00E-04 Y-91 3.0111-03 TE-131M 4.00E-)5 a 135 2.00E-0 4 Y-91M 3.01W03 TE-132 2.00E-05 XE•135M 2.00E-04 Y-92 6.00E-05 TE-134 3.00E-06 XE•137 2.00E-04 Y-93 3.00E-05 CS-134 9.00E-06 XE•138 2,00E-04 ZR-95 6.00E-,5 CS-136 6.00E-05 ZR-97 2.00E-05 CS-137 2.00E-05 11{ / V/ L IvvJ/ VL Enclosure 5.3 Page 4 of 5 A. Instantaneous Release Rate 1. Fission & Activation Products 2. Tritium Concentration 3. Dissolved & Entrained Gases 4. Gross Alpha Concentration 5. Boron Concentration (ppm) NOTE: Release Rate Calculation Required Yes No If yes, List 6. Hydrazine Concentration NOTE: Release Rate Calculation Required Yes No If yes, List Recommended Release Rate Release Limited By EMF Utilized EMF Correlation Concentration (Fission and Activation Products) Expected CPH of the EMF EMF Background Reading EMF Trip 2 Setpoint EMF Trip 1 Setpoint Health Physics Technician Date Time GWR# Tank Tank Level Before Release % Desired Tank Level After Release % Special Instructions) and/or Permission for this Release Date Time MANUAL RELEASE RATE DETERMINATION - McGUIRE NUCLEAR STATION TANK CONC. NCi/ml TANK DISCHARGE RATE IN GPM 2 Pumps 3 Pumps 4 Pumps 5 Pumps 6 Pi ps 7 Pumps 8 Pt GPM with RC pumps NCi/m1 CPM CPM CPM CPM Reviewed by WIC: I.V. Date Date: Time Enclosure 5.3 Page 5 of 5 Shift Supervisor Authorizing Release To Re Completed Prior To Release Initial (Signature) ENF Operable and Alarm (Trip 1) Set at CPH EHF Trip 2 Set at CPH No. of CCW pumps operating Recorder Stamped - LWR# at Start Time/Date Release Started To Be Completed After Release Initial Recorder Stamped - LWR# Stop Time/Date Release Secured Tank/Level After Release Commence Flush per Procedure OP/O/B/62©0/35 or Procedure OP/O/B/6400/43 Flush Secured Volume Release Gallons Completion of Release Acknowledged By Shift Supervisor Date: Time: Shift H.P. Review Date: Time: (Signature) (Signature) Form 34629 (R11-84) Liquid Re! Type of Release Release Rate LIQUID ERROR CORRECTION REQUEST STATION (Actual( ERRORS: Name Effective 1.1.85 RP/©/B/1003/Cs: Enclosure 5.4 Date/Time (Making Error) (Of Release) Entered as Should be Should be Entered as Entered as Should be Should be Corrected Bets -Gamma Total (if applicable) µCi/ml (See Back For Additional Corrected Noble Gas Total (if applicable) Information) µCi/ml Notified Entered as (Name) at (Time) (Date) of error request. Error correction request mailed to the Radioactive Waste Management Group at the General Office by for correction. (Name) (Date) ...........................FORGENERALOFFICE USE ONLY ••• ••••.•••••••••••••••.. Above errors corrected and request returned to originator by on (Date) (Name COMMENTS: • s ♦ * • • ♦ • • • • s • • • • • • • • • • • * • • • •.♦ ♦ s • ♦ • • * • s • * * • • • • • • • ♦ • • * . * * • • • ♦ • • • • • • • • • • • • • • * • .. .. * . . . . COPY DISTRIBUTION: Original • To Radioactive Waste Management Group then to applicable release file when corrected. Canary Copy • Retained at General Office Pink Copy • To be filed in outstanding error log book Goldenrod Copy • To be filed temporarily with applicable release file v y4,) Q rl s S •S 3_00.1 0.'10 NI ;C5« S d u mr?G (INV -31,1815,1.1 ne +uuad TVM OTm as %uoddr n, [C 3 s a �n 1.1 s,op j■ a $0 G -411¥ I J9# c$ SmallidMo2 Tandg«ay; s&IUCg d wlu d1:Oun> QUQ« t m 9ueS2n (ooW T ) sdPns xMdnddJd 1« uma OEbz df oC aa« uu 1.) SNaksn p9IC Ilubd6 t&5uung Udd Too F'1 YOzo+Zd udddud VSIg DUN genom3 G mgk awlyGlxa . ua19n gtllOOa dJSNJONOJ QOIIVIG dValOON AdInaDW-dAMOd JW00 ; WUOJ 1VAOmddV NOTIV3O1'JY CQOaals'M (I uan nm m » ea axnsvaadmal rT oq txac / SS nomm2 ocS BvB-< n o ; ;1.0 1. avK nn,v, Jo adR1 'nN mswnbaw PUKE POWER COMPANY NUCLEAR PRODUCTION DEPARTMENT ay. opx 33189, 422 SOUTH CHURCH STREET CHARLOTTE, N.G. 28242 (704) 373-4011 February 28, 1986 Mr. D. Rex Gleason, P.E. Water Quality Regional Engineer North Carolina Department of Natural Resources and Community Development Division of Environmental Management 919 North Main Street Mooresville, NC 28115 SUBJECT: McGuire Nuclear Station Use of Biocide Containment Spray Heat Exchanger File: MN-208.38, 702.12, 730.65 Dear Sir: On November 27, 1985, we requested permission to use a biocide, Calgon H-106 in the containment spray (NS) heat exchangers at McGuire Nuclear Station to assist in cleaning the exchangers and to restore their efficiency and ensure their operability. Should the efficiency deteriorate excessively, the unit(s) would have to be shut down. In providing approval to use the biocide, you requested a report on the chemical(s) used, the amount of the chemical(s) used, and the discharge concentration. Attached is a listing of the heat exchangers cleaned, the chemicals used, the amount of the chemical, and the maximum discharge concentration as well as flow rates. Also attached is a short description of each chemical. As can be seen, the biocide was used in only two (2) of the heat exchangers. We found that equal or better cleaning was obtained by using surfactants, penetrants, and disperants for this particular fouling. Biocides may be more effective on other types of fouling. Only three of the four heat exchangers were cleaned at this time. It may be necessary in the future to clean the fourth heat exchanger and/or to reclean one that was cleaned at this time. If a biocide is needed in a future cleaning, we will contact you for approval. Mr. D. Rex Gleason, P.E. February 28, 1986 Page Two Should you have any questions or desire additional information, please contact me at (704) 373-2310. Sincerely, R. T. Simril, System Engineer Nuclear Environmental Compliance WTG : h j p Attachments cc: W.A. Haller R.W. Eaker P.W. Downing W.M. Suslick MN-2002.02 MN-2002.03-04 HEAT EXCHANGER CLEANINGS HX. # Chem. Flush Time Length CCW Flow Max. Dischg. Date Time H.X. Vol., Chemical Used. Rate, gpm of ➢isch. min. Rate, gpm Conc. ppm gal. 12/12/85 1330 "lA" NS 4,000 H-106 4.3 5,000 12/12/85 2000 "lA" NS 4,000 PCL-2000 5.2 5,000 12/31/85 12/31/85 1430 "lA" NS 4,000 H-106 1430 "lA" NS 4,000 CL-361 4.3 2,250 4.5 2,250 1/6/86 2300 "lA" NS 4,000 CL-361 4.5 5,000 1/6/86 2300 "lA" NS 4,000 PCL-2000 10.4 5,000 0.8 2,032,000 0.32 0.8 2,032,000 0.38 1.8 2,032,000 0.14 1.8 2,032,000 0.15 0.8 2,032,000 0.33 0.8 2,032,000 0.77 1/14/86 1000 "lA" NS 4,000 TSP 150 33 120 1,883,000 0.079 1/14/86 1000 "lA" NS 4,000 Triton X-100 7.1 33 120 1,883,000 0.0037 1/14/86 1000 "lA" NS 4,000 PCL-2000 5.2 33 120 1,883,000 0.0027 1/27/86 0830 "213" NS 4,000 TSP 150 200 20 2,032,000 0.44 1/27/86 0830 "213" NS 4,000 Triton X-100 4.7 200 20 2,032,000 0.014 1/27/86 0830 "213" NS 4,000 PCL-2000 5.2 200 20 2,032,000 0.015 2/5/86 0900 "2B" NS 4,000 TSP 150 33 120 2,032,000 0.073 2/5/86 0900 "213" NS 4,000 Triton X-100 7.1 33 120 2,032,000 0.0035 2/5/86 0900 "2B" NS 4,000 PCL-2000 5.2 33 120 2,032,000 0.0025 2/12/86 0900 "2A" NS 4,000 TSP 150 33 120 1,948,000 0.076 2/12/86 0900 "2A" NS 4,000 Triton X-100 7.1 33 120 1,948,000 0.0036 2/12/86 0900 "2A" NS 4,000 PCL-2000 5.2 33 120 1,948,000 0.0026 Definition of Chemicals H-106 - Calgon H-106 Microbiocide (a quaternary ammonium biocide) PCL-2000 - Calgon Powergaurd 2000 (an anionic, polyacyrlic acid dispersant/scale inhibitor) CL-361 - Calgon CL-361 Deposit Inhibitor (a blend of penetrants, surfactants, and dispersants) Triton X-100 - Rohm & Haas Triton X-100 (a non-ionic, poly - ether alcohol surfactant/detergent) TSP - Trisodium Phosphate April 14, 1986 ater Quality Section South Piedmont Regional Office N.C. Department of Natural Resources and Community Development Division of Environmental Management 919 North Main Street Mooresville, NC 28115 SUBJECT: Turbine Building Sump Release Radwaste Discharge Point File: MC-704.15 Dear Mr. Horne: During your inspection at McGuire Nuclear Station on March 27, 1986, you requested information concerning releasing the turbine building sump through the radwaste release point. Attached, for your information, is a copy of the station procedure, Radioactive Liquid Waste Release. Section 4.4 is the procedure for releasing the turbine building sump. During the inspection, as you may recall, we stated that we were limited by NRC on the release of specific radioisotopes as well as total radiation. Section 3.3 of the attached procedure addresses this. Enclosure 5.3, Manual Calculations, is the method for calculating the amount of activity that is released. As you can see, for each isotope, the isotopic concentration ( PCi/ml) is divided by the maximum permissible concentration (MPC,pCi/ml); all isotopic concentrations are then totalled. The release rate is then calculated to ensure sufficient dilution. Should you have any additional questions, please contact me at (704) 373-5764. Sincerely, R.T. Simril, System Engineer Nuclear Environmental Compliance oil Li by: W.T. Griffin Environmental Engineer WTG/rhm attachment V . C©,y RECEIVED (7) APPROVED BY Form 34731 (R8.85) PREPARATION (2) STATION Masora Nuclear Station (3) PROCEDURE TITLE 7 1986 b. Radioactive Liquid Waste Release (LWR) ID NoHP/0/B/1003/0, Change(%) 0 to 's Incorporated (4) PREPARED BY (5) REVIEWED BY Cross -Disciplinary Review By (6) TEMPORARY APPROVAL (If Necessary) By (SRO) Date By Date DATE DATE /! Z7 DATE A.44„..iefr N/R LUFre (8) MISCELLANEOUS Approved By!" �*rrr� Date Reviewed/Approved By Date (9) COMMENTS (For procedure reissue indicate whether additional changes, other than previously approved changes, are included. Attach additional pages, if necessary.) ©ADDITIONAL CHANGES INCLUDED. COMPLETION (10) COMPARED WITH CONTROL COPY DATE (11) DATE(S) PERFORMED (12) PROCEDURE COMPLETION VERIFICATION C Vas 0 N/A Check um and/er blanks properly initialed, signed. dated or filled in N/A or N/R, as appropriate? C Yes 0 N/A Lieu f'aia Anal attached? C Yes © N/A 0111111 dims shacked, completed, dated and signed? C Yes © N/A a'ilk SNOW eta. attached and properly dated, identified and marked? © Yas ©N/A Astai Lance criteria reset? VERIFIED BY DATE (13) PROCEDURE COMPLETION APPROVED DATE (14) REMARKS (Attach additional pages, if necessary.) HP/0/B/1003/02 DUKE POWER COMPANY McGUIRE NUCLEAR STATION RADIOACTIVE LIQUID WASTE RELEASE (LWR) 1.0 Purpose This procedure describes the proper method of sampling, initiating and documenting a radioactive liquid release from a Waste Monitor Tank (WMT) or Recycle Monitor Tank (RMT), Containment Ventilation Unit Condensate Drain Tank (CVUCDT), or Turbine Building Sump (TBS) to the RC System. 2.0 References 2.1 Duke Power Company, McGuire Nuclear Station, Liquid and Gaseous Radwaste Computer Program User's Documentation. 2.2 McGuire Nuclear Station, Technical Specifications 3.11.1.1 2.3 Station Health Physics Manual, Section 13.5: Preparation of Sample for Count Room Analysis. 2.4 Station Health Physics Manual, Section 13.6; Composite Sampling. 2.5 HP/0/B/1003/08, Determination of Radiation Monitor Setpoints (EMF's). 2.6 HP/0/B/1009/13, Health Physics Actions for Inoperable Liquid Effluent Monitoring and Sampling Devices. 2.7 PT/0/B/4600/18, Radioactive Liquid Frequency. 2.8 OP/0/B/6200/35, Radwaste Procedure Tank to the Environment. 2.9 OP/0/B/6200/43, Radwaste Procedure Tank to the Environment. 2.10 Code of Federal Regulations, Title Effluent Sampling and Analysis for Dischar a Waste Monitor for Discharging a Recycle Monitor 10, Part 20, Appendix B. 2.11 O /0/1/6200/S6, Radwaste Chemistry Response to Indication of a Prfrry to Secondary Leak. 2.12 010/1/1/6400/01A, Condenser Circulating Water and Low Level Intake; Enclosure 4.11, Operation of Turbine Building Sump with High Activity to RC Discharge. 2.13 OP/0/A/6500/01A, Ventilation Unit Condensate Drain Tank Operation. 3.0 Limits and Precautions 3.1 Proper Health Physics methods shall be used when handling radioactive or potentially radioactive liquids. -2- 3.2 All liquid waste release (LWR) and dose calculations shall be made by use of appropriate computer codes per Reference 2.1. The manual methods presented shall be used if the computer is not available. 3.3 All releases shall be added to the total quarterly release using the appropriate computer codes (Reference 2.1) to ensure that quarterly and annual limits are not exceeded. 3.4 Corrections to the LWR Computer Program after the program has been terminated shall be handled by the Radioactive Materials Control Group personnel with assistance from the General Office Radwaste Engineering staff as necessary. 3.5 If for any reason the EMF, composite sampler, or flow totalizer is inoperable, refer to HP/0/B/1009/13 for required action. 3.6 Sample analysis results shall be valid for 4 hours for a CVUCDT and TBS release and 24 hours for a WMT/RMT release from the time sample was obtained. 3.7 Radwaste Chemistry shall be allowed 3consecutive attempts at releases via EMF49(L) with Hi-Rad Trips before a resample shall be required. 3.8 If for any reason the release has to be terminated prior to completion, the H.P. controlled valve (WM116 for WMT-A, WM43 for WMT-B, WM222 for 1-CVUCDT, WM225 for 2-CVUCDT, WM47 for TBS) shall be locked closed. 3.9 Boron analysis shall be performed when the effluent is expected to contain = 1000 ppm Boron. 3.10 TBS sampling and the release may be terminated when all of the following are true: 1. No activity (except dissolved and entrained gases) above background is identified in two consecutive samples. 2. 10 additional sources of activity to the sumps are anticipated. 3. The total activity of dissolved and entrained gases is less than 2.O11-4 Nci/ml. 3.11 Manual adjustments of EMT trip setpoints shall be performed using HP/0/B/1003/08 Enclosure 5.4. 3.12 Five LWR spares shall be entered on the VAX computer as soon as possible on the first day of the month. 4.0 Procedure 4.1 For a WMT/RMT' release go to Section 4.2. For CVUCDT release go to Section 4.3. For a TBS release go to Section 4.4. 4.2 WMT/RMT Release NOTE 1: Prior to WMT/RMT release read the Limits and Precautions and Section 4.2 of this procedure. NOTE 2: This procedure is performed in conjunction with Chemistry release procedure Reference 2.8 or 2.9. NOTE 3: If EMF49(L) is inoperable, refer to HP/0/B/1009/13 for inoperable action. 4.2.1 Determine the Recommend Release Rate using Enclosure 5.1. 4.2.2 Record EMF49(L) as the EMF Utilized. 4.2.3 If EMF49(L) is inoperable, record EMF49(L) Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.2.5. 4.2.4 Determine the EMF49(L) Setpoints using HP/0/B/1003/18. Record setpoints and sign the Discharge Document. 4.2.5 Independently verify the following and sign adjacent to the performing Health Physics Technician's signature (see Enclosure 5.2, page 1 of 3). 4.2.6 (a) Any manual calculations such as Boron Release Rate and Multiple Release Calculations. (b) Recommended Release Rate. (c) EMF Trip 2 Value. Take the Discharge Document and associated paperwork as prescribed in the Chemistry release procedure to the Control Room. NOTE: The isotopic analysis printout can be replaced with the computer program MGLIQRPT (Reference 2.1). -4- 4.2.7 Adjust the EMF49(L) Setpoints, record in the EMF Log Book and deliver the document to the Operations Shift Supervisor for appropriate signoffs. I.V. Trip 2 4.2.8 Take the discharge document and Chemistry release procedure to Radwaste Chemistry personnel (716 Elevation). NOTE: Ensure that all Health Physics signoffs in the Chemistry release procedure are completed up to this point. 4.2.9 As requested by Radwaste Chemistry, complete the Health Physics portion of the Chemistry release procedure. 4.2.10 After the release is terminated, return EMF49(L) Setpoints to the values in HP/0/B/1003/08 Enclosure 5.1 and record in the EMF Log Book. I.V. Trip 2 4.2.11 Review the LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.2.12 Record release information on PT/0/B/4600/18 Enclosure 13.1 and composite the appropriate volume as per reference 2.4. 4.3 CVUCDT Release 4.3.1 At the request of Operations, and after the CVUCDT has been in recirc for thirty (30) minutes, obtain a Grab Sample (cube container) from valve 1 or 2 WL403. Allow the sample line to purge until no air is observed prior to obtaining sample. Note the composite jug level. 4.3.2 Analyze 3500 ml sample for principal gamma emitters and tritium per Reference 2.7. If the composite sampler is inoperable, label and retain this sample for the weekly compositing and refer to HP/0/B/1009/13 and H.P. Manual Section 13.6 for inoperable action. NOTE 2: If EMF44(L) is inoperable, refer to HP/0/B/1009/13 for inoperable action. -5- 4.3.3 Determine the Recommended Release Rate using Enclosure 5.1. 4.3.4 Record 1 or 2 EMF44(L) as the EMF Utilized. 4.3.5 If EMF44(L) is inoperable, record 1 or 2 EMF44(L) Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.3.9. 4.3.6 Obtain the EMF44(L) reading from the Control Room and record as the EMF Background Reading on the Discharge Document. 4.3.7 Determine the Expected CPM of the OF by multiplying the EMF Correlation Concentration (Cs-137 Equivalent Activity from HP/0/B/1003/18) times the EMF Correlation Factor from HP/O/B/1003/08 Enclosure 5.3. NOTE: If the EMF Correlation Concentration (Cs-137 Equivalent Activity from HP/O/B/1003/18) is 5.0E-4 pCi/ml, notify the H.P. Shift Supervisor for approval of the release or send the tank contents to the Floor Drain Tank. 4.3.7.1 Record the value from Step 4.3.6 or 4.3.7 (whichever is greater) as the Expected CPM of the EMF. 4.3.8 Determine the EMF44(L) Setpoints as follows, record setpoints and sign the Discharge Document. 4.3.8.1 Trip 2 Setpoint S 3.0E4 (#P) where: 3.0E4 = derived from HP/0/B/1003/08 Enclosure 5.1 Note 12B for 1 RC pump running and the release rate (f) is 120 gpm. IMP = the number of RC pumps dedicated to the release NOTE 1: Trip 1 shall be greater than background but less than Trip 2. -6- NOTE 2: If needed, the maximum Trip 2 setpoint shall be calculated using HP/O/B/1003/08 Section 4.2. 4.3.9 Independently verify the following and sign adjacent to the performing Health Physics Technician's signature (see Enclosure 5.2, page 1 of 3). (a) Any manual calculations such as Boron Release Rate and Multiple Release Calculations. (b) Recommended Release Rate. (c) EMF Trip 2 Value. 4.3.10 Take the Discharge Document to the Control Room, have Operations adjust EMF44(L) Setpoints, record in the EMF Log Book, and deliver the document to the Operations Shift Supervisor. NOTE: If the flow totalizer is inoperable, notify Operations to manually calculate the volume discharged. I.V. Trip 2 4.3.11 At the request of Operations, rezero the CVUCDT flow totalizer, and unlock and open WM222 (Unit 1) or WM225 (Unit 2). Report these actions completed and your name to Operations. I.V. WM222 or 2 4.3.12 Record the start date and time, and the LWR # on the CVUCDT chart recorder (0 WL 5900), initial it and inform Operations of this action. 4.3.13 Coordinate with Operations to achieve the desired release rate. 4.3.14 Once the release has started and daily if continuous release, 4.3.14.1 Check the operation of the flow totalizer by observing an appropriate change in the totalizer count when compared to the actual release rate. 4.3.14.2 Check the operation of the composite sampler by observing sample collection or a change in the composite jug level. -7- NOTE 1: If the flow totalizer or composite sampler is inoperable, refer to HP/O/B/1009/13 and H.P. Manual Section 13.6 for action. NOTE 2: pH adjust the composite sample per reference 2.4 step 4.7. 4.3.14.3 Obtain a grab sample at least once per 24 hours by having Operations put the tank in recirc and obtaining a sample after recirc has been in progress for thirty (30) minutes. 4.3.14.4 Analyze 3500 ml sample for principal gamma emitters and tritium. 4.3.14.5 If the sample results indicate a new isotope, an isotope disappears or the concentration of any isotope changes by a factor of 10, generate a new LWR per 4.3.3 through 4.3.10. Go to 4.3.14.7. 4.3.14.6 If the current LWR is to continue, read and rezero the totalizer reporting the volume to Operations. Continue step 4.3.14. 4.3.14.7 Close out the current LWR by obtaining the volume released and rezeroing the flow totalizer. 4.3.14.8 Perform steps 4.3.12 and 4.3.13. 4.3.14.9 Perform steps 4.3.16 and 4.3.17. 4.3.14.10 Continue step 4.3.14. 4.3.15 When notified by Operations that the release is secured, 4.3.15.1 Close and lock WM222 (Unit 1) or WM225 (Unit 2). I.V. 4.3.15.2 Record the totalizer reading for discharge volume. 4.3.15.3 Record the stop date and time on the CVUCDT chart recorder and initial it. 4.3.15.4 Report to Operations the volume discharged, WM222 or WM225 is locked closed, and the chart recorder marked. 4.3.15.5 Ensure that Operations returns 1 or 2 EMF44(L) Setpoints to the values stated in HP/0/B/1003/08 Enclosure 5.1. Record in the EMF Log Book. I.V. Trip 4.3.15.6 Check the composite jug level to ensure an adequate amount has been collected. 4.3.16 Review the LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.3.17 Record the required release information on PT/0/B/4600/18, Enclosure 13.3 and composite as per reference 2.4. 4.4 Turbine Building Sump Release to RC System NOTE: If EMF31 Trip 2 alarms while discharging to RC, perform the following: 1. Obtain a sample. 2. Obtain the EMF reading. 3. Calculate the new EMF31 Trip 2 setpoint per 4.4.8.1 below. This setpoint must be above the EMF reading. 4. Evaluate this setpoint for multiple releases in progress per Enclosure 5.1 step G or have Operations secure any other release in progress. 5. Have Operations record the totalizer reading, rezero the totalizer, and close out the current TBS LWR. 6. Have Operations reset EMF Trip 2 setpoint and give them permission to initiate a new release without LWR paperwork to prevent overflowing of the sump. Operations shall keep track of the volume from the start of the release. 7. Generate a new LWR for the TBS as soon as possible and reinitiate any secured releases from other sources, ensuring multiple release calculations are performed (Enclosure 5.1, Step G). 4.4.1 Obtain a representative sample of the TBS per HP/0/B/1009/18 Enclosure 5.2, Sampling Instructions. 4.4.2 Analyze 3500 ■1 sample for principal gamma emitters and tritium per Reference 2.7. NOTE l: Label and retain this sample for weekly compositing. _9_ NOTE 2: During a 1° to 2° leak Radwaste Chemistry may use portable demineralizers to clean TBS effluent. In this case samples for release rate determination shall be obtained from the demineralizer outlets. NOTE 3: If EMF31 is inoperable, refer to HP/O/B/1009/13 for inoperable action. 4.4.3 Determine the Recommended Release Rate using Enclosure 5.1. NOTE: If Operations is unwatering the condenser of the affected unit, ensure that 1RC21 (Unit 1) or 1RC22 (Unit 2) is closed. 4.4.4 Record 1 or 2 EMF31 as the EMF Utilized. 4.4.5 If EMF31 is inoperable, record 1 or 2 EMF31 Inoperable and N/A for the EMF Expected CPM, Background Reading, and Trip 1 and 2 Setpoints on the Discharge Document. Go to Step 4.4.9. 4.4.6 Obtain the EMF31 reading from the Control Room and record as the EMF Background Reading on the Discharge Document. 4.4.7 Determine the Expected CPM of the EMF by multiplying the EMF Correlation Concentration (Cs-137 Equivalent Activity from HP/0/8/1003/18) times the EMF Correlation Factor from HP/O/B/10O3/08 Enclosure 5.3. 4.4.7.1 Record the value from Step 4.4.6 or 4.4.7 (Whichever is greater) as the Expected CPM of the EMF. 4.4.$ Determine the EMF31 Setpoints as follows, record and sign the Discharge Document. 4.4.8.1 Trip 2 Setpoint 5 6.0E3(#P) where: 6.0E3 = derived from HP/O/8/1003/08 Enclosure 5.1 Note 1B1 for 1 RC pump running and the release rate (f) is 500 gpm. IMP = the number of RC pumps dedicated to the release. 4.4.9 -1©- NOTE 1: Trip 1 shall be greater than background but less than Trip 2. NOTE 2: If needed, the maximum Trip 2 setpoint shall be calculated using HP/0/B/1003/08 Section 4.4 for 1EMF31 or 2EMF31. Independently verify the following and sign adjacent to the performing Health Physics Technician's signature (see Enclosure 5.2, page 1 of 3). (a) Any manual calculations such as Boron Release Rate and Multiple Release Calculations. (b) Recommended Release Rate. (c) EMF Trip 2 Value. 4.4.10 Take the Discharge Document to the Control Room and notify Operations to align the TBS for discharge to the RC system. NOTE: If the TBS flow totalizer is inoperable, notify Operations to manually calculate the volume discharged. 4.4.11 Prior to release, 4.4.11.1 Have Operations rezero the TBS flow totalizer, adjust the EMF31 Setpoints and record in the EMF Log Book. I.V. Trip 2 4.4.11.2 Open the composite sastpler isolation valve. 4.4.11.3 Unlock WM47. 4.4.12 Once the release has started and daily, 4.4.12.1 Check the operation of the flow totalizer by observing an appropriate change in the totalizer count when compared to the actual release rate. 4.4.12.2 Check the operation of the composite sampler by observing sample collection or a change in the composite jug level. -11- NOTE 1: If the flow totalizer or composite sampler is inoperable, refer to HP/0/B/1009/13 and H.P. Manual Section 13.6. NOTE 2: pH adjust the composite sample per reference 2.4 step 4.7. NOTE 3: If Operations is unwatering the condenser of the contaminated unit, sample the WU system at the following frequency. a Once the TBS pumps are aligned to RC and then once per 12 hours. b. One hour after the initiation of any WMT or CVUCDT release. Obtain the sample for the affected WU system at Column 1H27 (valve 1WU18) or Column 2H27 (valve 2WU18) located in the Turbine Building Basement. 4.4.12.3 Obtain a grab sample at least once per 24 hours. 4.4.12.4 Analyze 3500 ml sample for principal gamma emitters and tritium. 4.4.12.5 If the sample results indicate a new isotope, an isotope disappears or the concentration of any isotope changes by a factor of 10, generate a new LWR per 4.4.3 through 4.4.10. Go to 4.4.12.7. 4.4.12.6 If the current LWR is to continue, continue step 4.4.12. 4.4.12.7 Closeout the current LWR by ensuring the volume discharged is recorded and Operations rezeros the flow totalizer. 4.4.12.8 Perform steps 4.4.14 and 4.4.15. 4.4.12.9 Continue step 4.4.12. -12- 4.4.13 When the release is terminated, 4.4.13.1 Lock close WM47. 4.4.13.2 Close the composite sampler isolation valve. 4.4.13.3 Collect any water from the composite sampler. 4.4.13.4 Have Operations return EMF31 Setpoints to the values in HP/0/B/1003/08 Enclosure 5.1. Record in the EMF Log Book. I.V. Trip 2 4.4.14 Review the LWR for complete documentation and sign below the Shift Supervisor's signature for completion of release. 4.4.15 Record release information on PT/0/B/4600/18 Enclosure 13.9 and composite as per reference 2.4. 4.5 RMC Review and QA Check 4.5.1 Compare the computer isotopic input sheet or manual calculation worksheet with the sample results used to calculate the release rate. 4.5.2 After any errors have been corrected using Enclosure 5.4, sign the LWR as Reviewed by RMC. 4.5.3 After the volume update of the LWR, a final QA check shall be performed to ensure the correct volume, start/stop time and date was entered. Use Enclosure 5.4 to correct any errors. 5.0 Enclosures 5.1 Release Rate Determination 5.2 Release Rate Determination Form 5.3 Manual Calculations 5.4 Liquid Error Correction Request. RELEASE RATE DETERMINATION Computer Method HP/0/8/1003/02 Enclosure 5.1 Page 1 of 3 NOTE 1: An LWR number shall be assigned by the computer; verify in the GWR/LWR Log Book that the correct LWR number has been assigned. If this number is not correct, use the back-up procedure (Section II fo this Enclosure) assigning the higher LWR# (from VAX or GWR/LWR Log). Investigate discrepancy as soon as possible. A. Use Reference 2.1 and enter the isotopic analysis results, tritium, boron, and current Teledyne analysis results. Independently verify and sign the computer isotopic input sheet (see Enclosure 5.2, page 3 of 3). NOTE: The computer does boron. 0 calculate the release rate based on B. Attach the computer input sheet to the isotopic analysis. C. If required, record the Boron concentration on the Discharge Document and if Boron 1000 ppm, calculate the Instantaneous Release Rate (f ) based on Boron Concentration as follows. (#RC Pups R ) (2.5E5 gpm/pump)(1 #RC Pump SB = obtained from Control Room (1-8 pumps) = ppm Boron in Lake. This value (current to within 6 weeks of release date, and less than 1 ppm) is obtained from Chemistry and monthly is posted in the Shift Lab. = ppm Boron in the sample D. Release rate calculations based on Hydrazine are not required; enter N/A. E. Record the Maximum System Release Rate or the calculated Most Restrictive Instantaneous Release Rate based on the number of RC pumps required (whichever is less) as the Recommended Release Rate. HP/0/B/1003/02 Enclosure 5.1 Page 2 of 3 NOT!: Unless the tank discharge flowrate is manually restricted, the Maximum System Release Rates are as follows: WMT = 120 gpm RMT = 120 gpm TBS = 500 gpm CVUCDT = 120 gpm F Record Tank Concentration, Dilution Flow Release Rate as Release Limited By. G. When performing multiple releases (i.e., calculation shall be performed to assure exceeded. Available, or Maximum System WMT/RMT, TBS, CVUCDT) a that MPC levels are not 1. Determine the number of RC Pumps required for each release point. The total #RC pumps required for all releases shall not exceed 8. 2. Perform calculations to assure that MPC levels are not exceeded as follows. Record on the LWR. or RMT example: 120 500 where: -T -TB 500 + 500 + 120 + 120 1E4 1E5 8E3 4E3 Recommended Release Rate .34 Most Restrictive Instantaneous Release Rate based on the number of RC pumps required for each release point. The total #RC pumps required for all releases shall not exceed 8. NOTE: If sufficient dilution flow is not available to discharge sources simultaneously, one or more of the release rates (fREC) may be manually reduced or the CVUCDT may be sent to the Floor Drain Tank. Dilution flow shall first be allocated to the TBS, second to the WMT or RMT and third to the CVUCDT. HP/0/B/1003/02 Enclosure 5.1 Page 3 of 3 Also perform the following calculation and record on the LWR. # P used for TBS Trip 2 sp + # P used for CVUCDT Trip 2 sp # P available example: #P available + 0.5 1-TBS 82-TBS 81-CVUCDT 82-CVUCDT+ #P used for WMT #P available where: # P available # RC pumps running The total # RC pumps used for all releases shall not exceed 8. The information on the Release Rate Determination Form (Enclosure 5.2, page 2 of 2) labeled "To Be Completed Prior To Release" may be entered and signed off by Health Physics, Chemistry or Operations rather than the Shift Supervisor. II. Back-up Procedure; G.O. VAX Computer Method A. Use this procedure section if the Station VAX is inoperable. This method does not enter the release on the McGuire Liquid Release Program or assign an LWR number. When the Station VAX is operable again, enter all releases done on the G.O. VAX on the Station VAX, chronological order prior to entering any new releases. B. Record the LWR number in the GWR/LWR Log Book. C. Perform Enclosure 5.1 Section I. Steps A through H. III. Manual Method A. Use this procedure section if the Station VAX and G.O. VAX are imparable/unavailable. B. Calculate the release rates using Enclosure 5.3, page 1,2,3 of 5. Record results on Enclosure 5.3 page 4. Independently verify and sign the Manual Calculation Worksheet (see Enclosure 5.3, page 2 of 5). NOTE: Ensure Tritium and current Teledyne analysis results are included. C. Perform Enclosure 5.1 Section I. Steps C through H and attach the Manual Calculation worksheet to the isotopic analysis. Ht'/ u/ n/ i vu.10/L Enclosure 5.2 Page 1 of 3 Expected CPM of the EMF EMF Background Reading EMF Trip 2 Setpoint EMF Trip 1 Setpoint IMR# Tank Tank Level Before Release % Date Time Desired Tank Level After Release Special Instruction(s) and/or Permission for this Release RELEASE RATE DETERMINATION - McGUIRE NUCLEAR STATION TANK CONC. NCi/m1 A Instantaneous Release Rate 1. Fission & Activation Products 2. Tritium Concentration 3. Dissolved & Entrained Gases 4. Gross Alpha Concentration 5. Boron Concentration (ppm) NOTE: Release Rate Calculation Required Yes No If yes, List 6. Hydrazine Concentration NOTE: Release Rate Calculation Required Yes No If yes, List Recommended Release Rate Release Limited By EMF Utilized 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TANK DISCHARGE )LATE IN GPM 1 Pump 2 Pumps 3 Pumps 4 Pumps 5 Pumps 6 Pumps 7 Pumps 8 Pump 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+ 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+1 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+1 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+02 1.50E+1 GPM with RC pumps EMF Correlation Concentration NCi/m1 (Fission and Activation Products) CPM CPM CPM CPM Health Physics Technician Date Time Reviewed by MC: Dote: I.V. Date Time HP/0/R/1003/02 Enclosure 5.2 Page 2 of 3 Shift Supervisor Authorizing Release To Be Completed Prior To Release (Signatu To Be Completed After Release Initial Initial EMF Operable and Alarm (Trip 1) Set at CPM Recorder Stamped - LWR# Stop EMF Trip 2 Set at CPM Time/Date Release Secured No. of RC pumps operating Tank Level After Release Recorder Stamped - LW at Start Commence Flush per Procedure OP/O/B/6200/35 or Time/Date Release Started Procedure OP/O/B/6400/43 Flush Secured Volume Release Gallons Completion of Release Acknowledged By Shift Supervisor Date: Time: Shift H.P. Review Date: Time: (Signature) (Signature) Username: Password: HP/0/B/1003/02 Enclosure 5.2 Page 3 of 3 EXAMPLE: COMPUTER ISOTOPIC INPUT SHEET RWD7320 System Rev-1.0 VAX/VMS Rev 4.1 Welcome to VAX/VMS - Duke Power Company Enter Name of Program: MGLIQUID THIS RELEASE NUMBER IS 0081 IS THIS THE CORRECT LWR#? (Y/N) Y PLEASE ENTER THE TYPE OF RELEASE EXAMPLE: RMT-A, RMT-B, WMT-A, WMT-B, 1-CVUCDT, 2-CVUCDT WC, SPARE, 1-TBS, 2-TBS 1-CVUCDT ENTER RADIONUCLIDE NAME XE-133 ENTER CONCENTRATION 4.01E-5 ENTER RADIONUCLIDE NAME CO-60 ENTER CONCENTRATION 3.51E-6 ENTER RADIO11t1CLIDI MAMR STOP CO-60 3.51E-6 XE-133 4.01E-5 ARE THESE VALUES CORRECT?' (Y/N) Y BETA -GAMMA TOTAL = 3.51E-6 ENTER NAME OF PERSON RUNNING REPORT H. SLOAN I.V. HP/0/B/1003/02 Enclosure 5.3 Page 1 of 5 MANUAL CALCULATIONS Fissiouraad Activation Products a. Total all isotopic concentration (NCi/ml) NOTE 1: Tritium, dissolved and entrained gases, and gross alpha concentrations are to be included as valid isotopes in addition to their separate concentration calculations. NOTE 2: Tritium is not to be included in the sum for EMF correlation concentration. b. Calculate release rate in GPM for conditions when 1 - 8 RC pumps are in service for dilution using the following formula: (P) (2.5E+5) Where: 2.5E+5 = gpm per RC pump P = number of pumps operating a = recirculation factor at equilibrium = 2.4 C. = the concentration of radionuclide, i, in undiluted effluent as determined by laboratory analysis in NCi/ml. MPC. = the concentration of radionuclide, i, from 10CFR2O, appendix B. Table II, column 2 or Enclosure 5.3 page 3 of 5. 2. Tritium Concentration a. Use same basic formula as in fission and activation products, except: C at the concentration of tritium, i, in diluted effluent as determined by laboratory analysis, in NCi/ml i s for tritium value = 3.0E-3 3. Dissolved and entrained gases a. Use same basic formula as in fission and activation products, except: MPC. = 2.0E-4 NCi/ml for all dissolved and entrained noble gases. 4. Gross alpha concentrations a. Use same basic formula as in fission and activation products, except: MPC. = 3.0E-8 NCi/al for gross alpha concentrations. HP/0/B/1003/02 Enclosure 5.3 Page 2 of 5 MANUAL CALCULATIONS WORKSHEET Fisson and Activation Products Isotope Ci MPC. C. (P)(2.5E+5) (2.4)r Ci i=1 MPCi 2. Tritium: Ci MPC. (P)(2.5E+5) (2.4) / Ci 3.0E-3 Dissolved and Entrained Gases: Ci . Isotope .001.1111111.011011111101111. 4. Gross Alpha: Ci MPC. i Total MPCi 2.0E-4 2.0E-4 2.0E-4 2.0E-4 2.0E-4 3.0E-8 Total Performed by I.V. C. i MPC. i HP/0/B/1003/02 Enclosure 5.3 Page 3 of 5 MPC. VALUES FROM 10CFR20 TRITIUM 3.00E-03 NB-95 1.00E-04 CS-138 3.00E-06 ALPHA ACT 3.00E-08 NB-95M 3.00E-06 BA-133 3.00E-06 BE-7 2.00E-03 NB-97 9.00E-04 BA-139 3.00E-06 F-18 5.00E-04 NB-97M 3.00E-06 BA-140 2.00E-05 NA-24 3.00E -05 MO-99 4.00E-05 BA-141 3.00E-06 CL-38 4.00E-04 TC-99M 3.00E-03 BA-142 3.00E-06 K-40 1.00E+00 TC-101 3.00E-06 LA-140 2.00E-05 CR-51 2.00E-03 RU-103 8.00E-05 LA-142 3.00E-06 MN-54 1.00E-04 RU-105 1.00E-04 CE-141 9.00E-05 MN-56 1.00E-04 RU-106 1.00E-05 CE-143 4.00E-05 FE-55 8.00E-04 AG-108M 3.00E-06 CE-144 1.00E-05 FE-59 5.00E-05 AG-110M 3.00E-05 PR-143 5.00E-05 CO-57 4.00E-04 CD-115 3.00E-05 PR-144 3.00E-06 CO-58 9.00E-05 CD-115M 3.00E-05 ND-147 6.00E-05 CO-60 3.00E-05 IN-113M 1.00E-03 W-187 6.00E-05 NI-63 3.00E-05 IN-115M 4.00E-04 BI-212 4.00.E-04 NI-65 1.00E-04 1-130 3.00E-06 BI-214 3.00E-06 CU-64 2.00E-04 1-131 3.00E-07 PB-212 2.00E-05 ZN-65 1.00E-04 1-132 8.00E-06 PB-214 3.00E-06 ZN-69 2.00E-03 1-133 1.00E-06 TL-208 7.00E-06 ZN-69M 6.00E-05 1-134 2.00E-05 AC-228 9.00E-05 SE-75 3.00E-04 I-135 4.00E-06 TH-228 7,00E-06 BR-82 4.00E-05 SB-122 3.00E-05 NP-239 1.00E-04 BR-83 3.00E-06 SB-124 2.00E-05 AR-41 2.00E-04 BR-84 3.00E-06 SB-125 1.00E-04 KR-83M 2.00E-04 BR-85 3.00E-06 SN-113 8.00E-05 KR-85 2.00E-04 RB-86 2.00E-05 SN-123 3.00E-06 KR-85M 2.00E-04 RB-88 3.00E-06 SN-126 3.00E-06 KR-87 2,00E-04 RB-89 3.00E-06 TE-125M 1.00E-04 KR-88 2.00E-04 SR-89 3.00E-06 TE-127 2.00E-04 KR-89 2.00E-04 SR-90 3.001-07 TE-127M 5.00E-05 KR-90 2.00E-04 SR-91 5.0C1-05 TE-129 8.00E-04 XE-131M 2.00E-04 SR-92 6.016-05 TE-129M 2.00E-05 XE-133 2.00E-04 Y-90 3•S-05 TE-131 3.00E-06 XE-133M 2.00E-04 Y-91 3.05 TE-131M 4.00E-05 XE-135 2.00E-04 Y-91M 3.088-03 TE-132 2.00E-05 XE-135M 2.00E-04 Y-92 6.00E-05 TE-134 3.00E-06 XE-137 2.00E-04 Y-93 3.00E-05 CS-134 9.00E-06 XE-138 2.00E-04 ZR-95 6.00E-05 CS-136 6.00E-05 2R-97 2.00E-05 CS-137 2.00E-05 HP/O/B/ Iuu.i/uL Enclosure 5.3 Page 4 of 5 A. Instantaneous Release Rate 1. Fission & Activation Products 2. Tritium Concentration 3. Dissolved & Entrained Gases 4. Gross Alpha Concentration 5. Boron Concentration (ppm) NOTE: Release Rate Calculation Required Yes No If yes, List 6. Hydrazine Concentration NOTE: Release Rate Calculation Required Yes No If yes, List LWRI/ Tank Date Time Tank Level Before Release X Desired Tank Level After Release Special Instruction(s) and/or Permission for this Release MANUAL RELEASE RATE DETERMINATION - McGUIRE NUCLEAR STATION TANK CONC. TANK DISCHARGE RATE IN GPM NCi/ml 1 Pump 2 Pumps 3 Pumps 4 Pumps 5 Pumps 6 Pumps 7 Pumps 8 Pu m Recommended Release Rate GPM with RC pumps Release Limited By EMF Utilized EMF Correlation Concentration NCi/ml (Fission and Activation Products) Expected CPM of the EMF CPM EMF Background Reading CPM EMF Trip 2 Setpoint CPM EMF Trip 1 Setpoint CPM Health Physics Technician Date Time Reviewed by RMC: I.V. Date Date: Time nr/ u/ n/ i vv„ t,,.. Enclosure 5.3 Page 5 of 5 Supervisor Authorizing Release To Be Co Prior To Release (Signature To Be Completed After Release Initial Initial EMF Operable and Alarm (Trip 1) Set at CPN EMF Trip 2 Set at CPM No. of CCW pumps operating Recorder Stamped - LWR# at Start Time/Date Release Started Recorder Stamped - LWR# Stop Time/Date Release Secured Tank/Level After Release Commence Flush per Procedure OP/0/0/6200/35 or Procedure OP/0/B/6400/43 Flush Secured Volume Release Gallons Completion of Release Acknowledged By Shift Supervisor Date: Time: Shift N.P. Review Date: Time: (Signature (Signature) Form 34629 (R11-84) LIQUID ERROR CORRECTION REQUEST STATION Liquid Release Type of Rel Release Rate (Actual) ERRORS: Entered as Should be Entered as Should be Name Effective 1.1.85 HP/0/B/1003/02 Enclosure 5.4 DatefTime (Making Error) (Of Release) Entered es Should be Entered as Should be Corrected Bets -Gamma Total (if applicable) µCi/ml (See Back For Additional Information) Corrected Noble Gas Total (If applicable) µCi/ml Notified at on of error request. (Name) (Time) (©ate) * Error correction request mailed to the Radictitre Waste Management Group at the General Office by (Name) (Date) for correction. .FOR GENERAL OFFICE USE ONLY .......................... . Above errors corrected and request returned to originator by on (Date) (Name) COMMENTS: COPY DISTRIBUTION: Original • To Radioactive Waste Management Group then to applicable release file when corrected. Canary Copy • Retained at General Office Pink Copy • To be filed in outstanding error log book Goldenrod Copy . To be filed temporarily with applicable release file ALLOCATION APPROVAL FORM Requeu« No. z1G ?eI.:I.F :«//,) Ag2RL mr 9ER1-1.I1' POQER�MCCUTPC r,c1 AR yTATTnN 922D m« en2 e<RPI9r q:1LST2S < miPs E?nT»C ?29?2t9« d 61 PJ© bI #4 £ 2A5 CEc9 PL91D:Lb G>n !2 5 ?C91 4*) Q 4 is. &') m c,t.h c6. STAFF REPORT AND RECOMMENDATIONS Part I - INSPECTION OF PR©POSED/EXISTING WASTEWATER TREATMENT Pi.ANT SITE 1. a. Place visited: Duke Power Company McGuire Nuclear Station b. Mailing Address: General Offices 422 South. Church Street Charlotte, North Carolina 28242 Mecklenburg County 2. Date of Investigation: 8/16/82 3. By: J. Thurman Horne, P. E. 4. a. Persons contacted: Mr.°Rarker. Downing, P. E. b. Phone No.: 704/373-8779 Date of Report: 9/27/82 0?6 5. Directions to site: From the intersection of Highway 16 and Highway 73, travel east on Highway 73 approximately 3.2 miles. The facility is on the north (left) side of Highway 73 on the southern shore of Lake Norman. 6. a. The coordinates to the existing points of effluent discharge are: Latitude: (Outfall 001) 35°26'10" (Outfall 002 & 003) 35°25'40 Longitude: 80°56'30" 80°57'20 b. USGS Quad No.: F15NW (see attached map) 7. Size (land available for expansion and upgrading): Adequate area is available for the proposed wastewater treatment plant modifications. 8. Topography: Mildly rolling, 3-10% slopes. 9. Location of nearest dwelling: None within 1000 feet. 10. Receiving Stream: (Outfall 001) - Lake Norman - Class A -II & B (Outfall 002 & 003) - Catawba River - Class A -II River Basin and Sub -Basin No.: 03-08-32 Part II - DESCRIPTION OF PROPOSED/EXISTING TREATMENT FACILITIES 1. Existing Facilities: Outfall 001 - Cooling water discharge - This discharge is a combination of condenser cooling water (1,727,100 gpm - avg.), conventional low pressure service water (6,500 gpd - avg.) nuclear service water (20,000 gpd - avg.) and low level liquid radwaste (8 gpd - avg.). The cooling water discharge flows to Lake Norman via a discharge canal approximately 2,500 feet long and 200 feet wide. Page Two ©utfall 002 - Conventional Wastewater Treatment System Discharge - This system treats a non -radioactive waste from the plant with the exception of domestic wastewater. Wastewater generated by steam generator blowdown, condensate demineralizer backwashes, water treatment system backwashes, demineralizer backwashes, building drains, and metal cleaning wastes are treated in this system. The facilities consist of a 200,000 gallon initial holding pond, two settling ponds, installed in parallel, each with 2.5 million gallon capacity, a 1 million gallon aerated (diffused air) final holding pond, and final effluent pH adjustment consisting of an automated CO addition. The initial holding pond acts as a flow equalization basin. This pond may be bypassed, depending on the nature of the wastewater. The two settling ponds are operated such that one pond remains in standby. Treatment can be enhanced by the addition of coagulant aids and pH adjustment in these ponds. The effluent from the settling ponds may be discharged directly to the receiving stream via outfall 002 or it may be routed to the final holding pond. Effluent from the final holding pond may be discharged through outfall 002 or recirculated to the settling ponds, depending upon effluent quality. autfall 003 - Wastewater Collection Basin Discharge - The-13.4 acre wastewater collection basin receives wastewater from the domestic wastewater treatment system, the overflow from the standby (emergency) nuclear service water pond, and area surface runoff. The existing domestic wastewater treatment system consists of an extended aeration type facility followed by a 200,000 gallon aeration basin for tertiary treatment. Note: ©utfall 002 and 003 join at a common point before flowing into the Catawba River. 2. Proposed Modifications: The existing domestic wastewater treatment system is to be replaced by a proposed new facility. This facility will be a 64,000 gpd aerated lagoon (mechanical aerators), divided into four (4) cells with flexible curtains. The lagoon will be followed by a chlorine contact chamber, Parshall flume and existing polishing pond, before discharging into the existing wastewater collection basin. Note: Plans, specifications and application for Authorization to Construct this facility have been submitted and are available for review in the Permits & Engineering Section. Page Three Part III EVALUATION AND RECOMMENDATIONS 1. Performance Evaluation: The facility has a history of non-compliance with the pH limitations for the discharge from the wastewater collection basin during the warmer months of the year. This non-compliance appears to be a result of increased photosynthesis in the basin during these warmer months. Duke has requested a waiver of the existing pH limitation. 2. 0 & M Evaluation: The facilities appear to be very well operated and maintained. Recommendations and/or Special Conditions: It is recommended that the Permit be renewed as requested. Although Duke has requested that their Permit be issued such that only two discharge points are identified in the Permit, it is our understanding that the Federal guidelines for this industrial category will not allow this. As for Dukes request for a waiver of the pH limitation for the discharge from the wastewater collection basin, the Mooresville Regional Office recommends that the pH limitations recommended by Technical Services be included in the Permit. However, considering that this discharge is essentially domestic wastewater, and considering the large dilution thAt the discharge will be subject to (the Catawba River), it is recommended that Technical Services be requested to re-evaluate the effluent pH limitations for this discharge. It is our understanding that in cases of sufficient dilution of domestic dischargers, pH limitations are not necessary.