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HomeMy WebLinkAboutNC0024392_Regional Office Historical File Pre 2018 (6)Du Po R Go d P.O. Box 33189 cxARLoTTE, x.c. 28242 'I TE)U �•ktiIa ): r 28, 198 Paul, Wilms, Director n of Environmental Management ent of Natural Resources and mmunty Development ox 2`I687 NC 27611. McGuire Nuclear Station Renewal of NPDES Permit NCO024392 File: MC-702.13 Wilms: e subject permit require submittal of an a 5t 180 clays prior to expiration. ybject; permit and a check (no 158304) for $200.00 for sine fee. We request notification that the application you have any questions or desire additional info at t R. T. Simril [(704) 373--2310 ] . ely, £C'u kr, ice President r Production Department /rhm ores Document Control Desk r C1Li l NJ7iAw:% W*dwvia Bank a Trust Company P.O. $OIL 33 Chadoae, N.C. CHARLOTTE, NORTH C. DATE 12/21/88 PAY 00% rO T14E „ ., .._. 3F ATUK L RC URC 3 i D ELBPMENT 7 NC 27611 -.%J PA.NY BECK i 19 158 FtOI INA 28242 PAY ******200.00 ease prim or typo in the unshaded areas only Pfall—ift AMAI AP* .rnacsd fer alita runs..L a.. 12 charattatxlr' CM. 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's+.�ds. zru `y..✓ r 'sr. ww z `a}'?a: ..:Y f •+' �.. a F 2::.x � "55:,. s 5. .v .k Wf 1. :;:;t r,• ti ��.. a�•'tbrf WF� +^,T'.t` :� a, k 2Sa' t ;,.. �.. w,„ fi .^ k � 'w zap T � .:,. „ r «z �.X�`x:::a•s{ �. fi 5..:: w $ \ `fa k• � 5::.., «•,� .. �''G:,+ l• w ^ir. .^� "�, w�h „ir a"tx,� �,r :;.,aw Y�sC�•,, jj Y 5 v ; : �', „}� �:w ?i w 59 �� 3 z xr 1 nR $ « t } t { z`*a rstry,5y{t 7}k3, COWANS FORD <rt DAM UNDERDRAIN , DISCHARGE CONVENTIONAL - �_._____ k, „ 1 C==D : [� y??�L•t ui lr �,�i}��� j'1�..s}(r s, �� r WASTE WATER ? SE�,ph�+p�Lt; .WAGE last Lei aYi s}1 e. tt{al5 }ttit1 eN i r t 5tt 1 w , TREATMENT r x t �. TREATMENTL;, 1t t tt L�3ls rs y tit t t, �S 1 tt t „ STEM a (y1; Lilt, t} Lr tt tt t � �q FACILITY F r y��� � 1t tttti�'tlsrt�ty},���� a t}tu� ���ttt4.4• : tt °ss ,r'. �1 si+'�f��z'.• y t }ni U������i�t��i�i�tinat 3t�tit}k�2 fi• 5tnt +'ttt at i L'' x x J ) 003 }y :x:�Y y��t •, "��•€i�, fix.>. :V { F�^r5�tts tppa .:«« �*L4}L��1att}�5�1�1s�11 �1C �Lri;t�'sLtt it 3 s P1 1 ttr a 4 c� rr�'r5 � s CG r z. '9 l�1i�a 1 Lt� �Lt 002 uu x� i I 4 =RONT leaks, or spills, are any of the discharges described In Items II -A or 8 intermittent or seasonal? :te the folic wmg table) NO lgri to Section 1111 3, FREQUENCY A. FLOW 2, OPERATION(Si a, FLOW RATE 8 DAYS b. MONTHS a,mgd) I b, TOTAL VOLUME (specify with wnits,i c� OUR- :ONTRIBUTING FLOW PER W EEK PER YEAR - -------- - ATiON fsp�,Cf% MAXIMUM ai,craz, 11 1. 1 DAILY 1� LONG TERM AVERAGE 21 ..Xlmum I DAILY Iin daysl al metal cleaning Frequency and durationicannot lie predi ted from past. as necessary. Various Need based on the theroal-hydraulic performance. systems cleaned/flushed' any of the following: hydrazine, citric acid,� saris acid, oxalic acid,' ium phosphate, soda ash ascription of chemical ng.) Cooling Systems drain-' The sy4tems ma drained individually for note-routin ontains nitrite,borax maintel'ance . M i:urn irdividual system volume *'s 30,00 riazole corrosion gallon ations in the applicable effluent guideline expressed in terms of production for other memne of operatiorill? S fcomptete Ite"I 111-C) NO (go to Section IV') `red "yes" to Item 111.8, list the quantity which represents an actual measurement of your level of production, expressed in the terms and units 3pplicallite effluent guideline, and indicate the affected outfalls. 1. AVERAGE DAILY PRODUCTION Z.AFFECTED MATERIAL, CTC. OUTFALLS A DAY ti, u-Ts SURE C, OPER^T flint outtall numbers) OF MEASURE -P you tow required by any Federal, State or local author ty to meet any .mplementatron schedule for the construction, upgrading or operation of waste - ilea treatment equipment or practices or any other environmental programs which may affect the discharges described in thts application? This includes, it is not limited to, permit conditions, administrative or enforcement orders, enforcement compliance schedule letters, stipulations, court orders, and grant loan conditions. ..�Yes icomplete the following table) No (00 to Item IV-B) 1 1 14AMA OF CONDITION. 2. AFFECTED OUTF^LLS I I P614. AMr. GATE AGREEMENT, ETC, 3. BRIEF DESCRIPTION OF PROJECT a. NO. to souac or eau i......� a. Re- t7 P*01. N/A ITIONAL: You may attacm additional sheets clescribmig any additional water pollution control programs (or other environmental projects which may affect ur discharges) you now have underway or which yoj plan. Indicate whether each program is now underway or planned, and Inoicate your actual or inned schedules for construcvon, ]MARK "X"IF DESCRIPTION OF ADDITIONAL CONTROL PROGRAMS IS ATTACHED arm 3510-2C (Rev. 2-857 PAGE 2 OF 4 CONTINUE ON PAGE [Dyes (list all such pollu tan ts below) :21NO (go to Item VI-B) PAGE 3 OF 4 CONT SM1tSWP JLRAINFALL NOFF -LAKE LOW LEVEL 1' I NSW ' 200 NORMAN INTAKE SYSTEM � t La r CW 1727100 SYSTEM CONY. 6600' LPSW SYSTEM OUTFALL -- FILTERED 250 DEMIh. REACTOR LIQUID 1763808 LAKE 1734000 WATER WATER COOLANT RADWASTE SYSTEM SYSTEM SYSTEM PROCESSING NORMAN BACKWASH REGENERATIVE O iTFALL- WASTE t 001 FIRE ISO SECONDARY PROTECTION & AUX, 1 COOLANT 200 SYSTEMS LAKE LPS SANITARY STEAM GEN. BLOWDOWN TURBINE CONY, NORMA INTAKE POTABLE WATER BUILDING SUMPS WASTE WATER LEAKAGE R — - TREATMENT DRAINAGE 14 INTAKE METAL CLN. SCREEN WASTES GUTFALL BACKWASH GOND. 002 OEMIN, BACKWASht COWANS FORD TREATMENT DIG SUMPS DAM UNDERDRAIN SYSTEM DISCHARGE L����SEWAGE OUTFALL 2$2 0 003' 2E3 OUTFAL:L WWCB 16t#B 005 CATAWBA RIVER RAINFALL 102 RUNOFF NOTE. ALL FLOWS ARE IN GPM DUKE POWER COMPANY FOR AVERAGED CONDITIONS. MCGUIRE NUCLEAR STATION EVAP, & 00 NORMAL FLOWPATH SEEPAGE WATER :FLOWSCHEMATIC' — -- i ALTERNATE FLOWPATH NPDES Supplemental Information for McGuire Nuclear Station December 22, 198 TABLE OF CONTENTS Page STATION INTAKE 3 Surface Intake - 3" Subsurface Intake 3 NUCLEAR SERVICE WATER Containment Spray Meat Exchangers CONVENTIONAL LOW PRESSURE SERVICE WATER 5 FIRE PROTECTION 'SYSTEM 5 Condenser Cooling Water OUTFALL 002 Water Treatment Room Sump 8 Filtered Water System 8 Drinking Water System g ieminerali ed Water System Turbine Building Sump S Diesel Generator Room Sumps 10 Lab Drains 10 Floor Wash 10 Condensate Polisher Backwash 10 Condensate Polisher Element Cleaning 11 Wet Lay-up 11'' Auxiliary Electric Boiler Blowdown 12 Groundwater Drainage System 12 CCW System Unwatering 12 Standby Shutdown Facility/Closed Cooling Systems 12 Stearn Generator Cleaning 13 Miscellaneous System/Component Cleaning' 13 OUTFALL 003 1 OUTFALL 004 15 Floor, Equipment, and Laundry Drains 16 Ventilation Unit... Drains 17 Chemical Volume and Control System 1.7 Standby Nuclear Service Water Pond 18' Sanitary Waste Treatment System 18 Lab and Floor brains 18 Administrative Building drains 18 CCW System Unwatering 18 Yard Drains 19 COWANS FORD DAM UNDERDRAIN SYSTEM 1 APPENDIX: Boren Use and Control 20 2 The McGuire Nuclear" Station is a two ( unit nuclear fission steam electric generating station. It is owned and operated by Due Power Company. Each unit is a four loop pressurized water reactor.: Reactor fuel is zircaloy clad sintered uranium oxide pellets. Reactor heat absorbed by the Reactor Coolant System produces steam in four (4) steam generators sufficient to drive a turbine generator unit with a design net electrical rating of 1180 megawatts. The nuclear ruction is controlled by control rods and chemical neutron absorption. Boric acid is used as a chemical neutron absorber and to provide borated water for safety injection. During reactor operation, changes are made in the reactor coolant boron concentration. Appended is a description of how boron concentration changesare implemented. schematic diagram of water use and discharges indicating average rates of flow for individual wastestreams of McGuire Nuclear Station is attached. Actual flows through individual systems may vary significantly depending on operational needs and meteorological conditions. Normally, liquid radio- active waste are discharged only -;.through Outfall 004. However, it is possible for any of the discharges to be contaminated by low levels of radioactivity. All discharges of radioactivity are regulated by the Nuclear Regulatory Commission in accordance to 10 CFR Part 20 and 10 CFR Part 50. The following is a brief description of the major systems. STATION INTAKE All water for McGuire Nuclear Station is withdrawn from Lake Norman through a duel intake system - a surface and a subsurface system. These systems supply the lain Condenser Cooling Water (CW), Conventional Low Pressure" Service Water, Nuclear Service Water, Fire Protection System, and Filtered Water Make-up. Surface Intake McGuire Nuclear Station has two (2) power generating units with four (4) CCW pumps per unit. There are two (2) intake screens per pump for a total of 16 screens. The intake screens are backwashed on an intermittent basis to prevent pressure differential buildup across the intake screens. The frequency of cleaning is determined by the amount of debris on the screens. The normal frequency is daily. Approximately 8,500 gallons of water are used to backwash each screen.` The water is returned to Lake Norman at the intake bay. The debris collected from :the screens is placed in sanitary containers and transported to a licensed sanitary landfill. No chemicals are used in the "backwash water. Subsurface Intake The subsurface lint ( Low Level Intake) is located near' the bottom of Lake Norman at Cowans Ford Dam. There are six (6) low` level intake pumps with a capacity of 150,000 gpm each. This pump system pumps cool water` from the lake hypolimnion and mixes it with the warmerwater in the surface intake structure during times of high lake surface water 3 temperatures. The Low Level intake is also the primary source of water for the Containment Ventilation Cooling Water System and the Nuclear Service Water System. NUCLEAR SERVICE WATER The Nuclear Service Water System is a safety related once -through non - contact cooling water system. The Nuclear Service Water System supplies cooling water to various heat loads in both the primary and secondary portions of each unit. There are two (2) pumps per unit (four (4) pumps total) that are capable of delivering 17,500 gpm per pump. The water supply is f rom Lake Norman or the Standby Nuclear Service Water Pond. Water from Lake Norman can be supplied by the main condenser circulating water system from the surface intake or by the Low Level Intake. The normal source of water is the Low Level Intake system. The normal discharge is to Lake Norman through Outfall 001. The Standby Nuclear Service Water Pond (SNSWP) is a 34.9 acre pond designed to provide water for the safe shutdown of the station in the unlikely event that Cowans Ford Dam is lost. The level in the pond is maintained, per requirements of the McGuire Nuclear Station Operating License Technical Specifications, by pumping water from Lake Norman into the pond. The pond overflows to the Catawba River via the Wastewater Collection Basin (WWCB, Discharge 005). The pond also receives runoff from a drainage area of 171 acres. When the Nuclear Service Water System is aligned to take suction from the SNSWP, discharge is back to the SNSWP. This recirculation mode is normally implemented for three (3) hours every six (6) weeks. This testing frequency can change based on the results of the test. As a result of accelerated corrosion of the nuclear service water system piping, a corrosion inhibitor program is being considered. Corrosion inhibitors under evaluation include zinc, nitrites, polyphosphates, phosphates, borateslysilicates, molybdates, benzotriazole (BZT), toyltriazole (TT), and mercaptobenzothiazole (MBT). Low levels of one or two of these corrosion inhibitors will be discharged at environmentally acceptable levels. Macrofouling by Corbicula (Asiatic clams) can impact the safe operation of the station; microbial influenced corrosion (MIC) has caused failures of piping and heat exchanger tubing due to pitting. Non - oxidizing biocides or chlorine (or sodium hypochlorite) will be used at concentrations that result in environmentally acceptable discharge levels to address macrofouling and MIC. Containment S]2r!ly Heat Exchangers As part of normal heat exchanger maintenance, one (1) of four (4) heat exchangers per month is treated with an alkaline flush. These flushes may consist of 1-2% sodium hydroxide, 1-2% sodium metasilicate, 1-2% sodium carbonate, 1-3% trisodium phosphate, and 1% surfactant, solution and an approved biocide. The waste volume is approximately 5000 gallons per cleaning. Approved biocides (sodium hypochlorite and organic biocides) are used to control biological growth in these heat exchangers. The flush water may be discharged via the Condenser Cooling Water (CCW) System or the Standby Nuclear Service Water Pond (SNSWP). Alternative flushes may be performed using mild organic acids 4 (citric, oxalic, or formic) if< needed to remove excessive corrosion deposits or Corbicula. In this case, if treatment is necessary, the waste can be directed to the Conventional Wastewater Treatment (WC) system. in order to mitigate corrosion of the carbon steel, wet lay-up systems are being installed. Various corrosion inhibitor solutions including zinc, ortho-phosphates, polyphosphates, polysilicat es, nitrites, boraces, and molybdates may be used. organic biocides or sodium hypochlorite (chlorine) will be added for biofouling control. The corrosion inhibitor solution will be released during the flow balance and heat exchanger performance testing. CONVENTIONAL LOW PRESSURE SERVICE WATER The Conventional Low Pressure Service Water System supplies low pressure cooling water for various functions on the secondary side of the station. The system takes suction from the condenser cooling water cross -over lines and supplies cooling water to various motor bearings, seals, Tube oil coolers, vacuum breaker valves, and blowdown separator. Discharge is back into the condenser cooling water system. The Low Pressure Service Water System is the supply for process water. FIRE PROTECTION SYSTEM The Fire Protection System provides the plant site with protection from postulated fires. The system is equipped with two (2) 200 gpm jockey pumps which take suction from the Condenser Cooling Water System. One pump is capable of maintaining system pressure; however, the second pump is used to supplement the jockey pump system capacity. In the event the jockey pumps can no longer supply enough water to maintain system pressure, the three (3) 2500 gpm main fire pumps will start sequentially. The fire protection system is continuously chlorinated to a concentration of approximately 1-3 ppm to assure that Corbicula are not present in the system's piping. The fire protection system is used as the source of water for bearing lubrication and gland seal on the low level intake pumps. System operability is demonstrated by periodically performing specific tests on the system. A summary of the current testing schedule follows. Monthly, the main fire pumps are started, then stopped, to assure operability. Very little, if any, water is discharged during this test. Each valve on each hydrant is stroked annually to assure proper operation; no water is discharged. At this same time, each hydrant is opened and flushed to verify flow. Very little water is discharged; any water discharged flows across paved lots, dirt, or grass to yard drains from which it discharges to the SNSWP or Wastewater Collection Basin (WWCB). Generally twice per month, a valve at the farthest point from chlorine injection in the system is opened, flushed, and the water tested for chlorine to assure the system is properly chlorinated. Administrative procedures are in'place to assure that the water flows across dirt or grass to yard drains. This 'test is performed only if the system is being chlorinated (i.e., the jockey pumps are operating and the chlorine cylinders are open). 5 The transformer emulsifier system is tested annually. The transformers are subjected to a wet or dry test, whichever is appropriate for that particular transformer. Any water discharged flows across paved lots, dirt, or grass to yard drains. Also annually, the head curve for =each of the three (3) main fire pumps is verified. For the test, each pump is isolated; the flow path is from the lake, through the pump and a test header, and discharged back to the lake. No chlorine is in the water since the pump is isolated from the fire protection loop. Every 18 months, the system is tested to verify sequential starts of the pumps and automatic valve actuation. The water that is discharged during the test flows across paved lots, dirt, or grass to the yard drain system. Every three (3) years, flow through the hydrant loop in the station yard is evaluated to assure the hydrants maintain the proper pressure and flow. The water discharged flows across paved lots, dirt, or grass to the yard drain system. There is a non -routine test performed at the discretion of the system coordinator. During the test, several hydrants are opened simultaneously to verify the velocity and chlorination level. The water discharged flows across paved lots, dirt, or grass to the yard drain system, and hence to the SNSWP or WWCB. Any chlorine residual present should be dissipated by the chlorine demand of the water in the SNSWP or WWCB. Additional testing is performed on the system. These tests, however, do not discharge any water. These tests include visual inspections of the system to verify flow path by verifying valve alignment and to verify the condition of the system and/or equipment. Other tests include simulating conditions that will actuate alarms. OUTFALL 001 Outfall 001 is comprised of the main Condenser Cooling Water (CCW), Conventional Low Pressure Service Water, Nuclear Service Water, and Liquid Radioactive Waste (Radwaste). Outfall 001 discharges into Lake Norman. Condenser Cooling Water The CCW System is a once -through non -contact cooling water system that removes heat rejected from the main and feedwater pump turbine condensers and other selected heat exchangers. Each of the two (2) power generating units has four (4) CCW pumps for a total of eight (8) pumps. The flow for each unit depends on the number of pumps operating as shown by the following table. Number of Pumps 22eratin2 Total Flow Unit (gpm) 1 254,000 2 640,000 3 867,000 4 1,016,000 6 The operational schedule of the pumps of each unit is a function of the intake water temperature and the unit load. At 100 per cent load and the intake temperature near its summer high, three and sometimes four CCW pumps are used. When the unit load is less than 100 per cent and intake temperatures are lower, fewer pumps may be needed. Condenser cleaning is by mechanical means (trade name "Amertap"). This system circulates small sponge rubber balls through the condenser continuously. It may become necessary to institute chemical control for macroinvertebrate infestation, general corrosion, and microbiologically induced corrosion (MIC). Chemicals anticipated to be added include chlorine (sodium or calcium hypochlorite), organic biocides, dispersants, and corrosion inhibitors. The corrosion inhibitors may include zinc, nitrite, polyphosphates, phosphates, borates, silicates, and molybdates. Discharge concentrations will be maintained below approved discharge levels. A 316(a) study was submitted August 9, 1985 and a 316(a) variance was granted October 18,1985. Plant operating conditions and load factors are unchanged and are expected to remain so for' the term of the reissued permit. A Lake Norman aquatic environment maintenance monitoring program was implemented July 8, 1987. Duke Power Company is not aware of any changes to plant discharges or other discharges in the plant site area which could interact with the thermal discharge or to the biotic community of Lake Norman. Duke therefore requests a continuation of the existing 316(a) variance, or as modified by the outstanding 316(a) permit modification request. OUTFALL 002 Outfall 002 discharges treated wastewater from the Conventional Wastewater Treatment (WC) System through a Parshall flume to the Catawba River below Cowans Ford Dam. The WC system consists of a concrete lined initial holdup pond (IHP, 200,000 gallons), two (2) parallel clay -lined settling ponds (2.5 million gallons each), and a concrete lined final holdup pond (FHP, 1 million gallons). Normally, inputs are received in the IHP but can be routed directly to an in-service settling pond. The IHP serves as a common mixing point for all wastewater, a surge -dampening function to the remainder of the system, and allows the heavy solids to settle for periodic removal. Retention time in the IHP is 12 to 24 hours. Solids removed from the IHP are dewatered and disposed of on a State licensed land arm or landfill. Flow is directed to the in-service settling pond through the chemical addition building where caustic, acid, and/or other chemicals may be injected into the water by a metering pump. Sulfuric acid and sodium hydroxide are added for PH control or to precipitate various chemical compounds. Coagulants may be added to facilitate the settling of lighter solids. Additional treatment may include chemical oxidation with hypochlorite (calcium or sodium) or catalyzed hydrogen peroxide. Retention time for each, of the settling ponds range between 6 and 12 days. The settling ponds can discharge to the FHP or directly to the Catawba River. Treatment and discharge are normally on a batch basis. 7 The FHP is aerated and is used to remove any persistent oxygen demand or to provide additional holdup capacity. The FHP retention time is 1 to 2 days. The capability is available for recirculation intra- or inter -basin. Flow to the Catawba River may be by gravity at a rate of approximately 200 gpm or be pumped at a rate of approximately 500 gpm. The pH of the discharge from the WC system is adjusted by the automatically controlled addition of carbon dioxide. The WC system accepts all nonradioactive plant waste except sanitary sewage. The inputs can be contaminated with very low levels of radioactivity. Any discharges of radioactivity are monitored and accounted for, being regulated by the Nuclear Regulatory Commission (NRC). Inputs to the system are from the turbine building sumps, water treatment room sump, condensate demineralizer backwashes, standby shutdown facility (SF'), and laboratory drains. Steam generator blowdown, wet lay-up, and the unwatering pump discharges may be routed through this system. Water Treatment Room S2M Inputs to the Water Treatment Room Sump consist of drainage from all equipment including pump seal le off and bearing cooling water located in the Water Treatment Room. Other inputs include the Diatomaceous Earth (DE) Slurry Tank drain, acid and caustic day -tank storage overflow drains, carbon filter backwash and sluice, pressure filter backwash, demineralizer regeneration waste, and backflow preventer drains. In addition, floor wash and sample line flush water are routed to this sump. Antifoaming agents and wax strippers are routinely present in this waste stream. The drains in the plant "boiler room" are also routed to this sump. The drains contain sodium nitrite/borax/benzotriazole (BIT) corrosion inhibitor and microbiocide due to lea off and sample purging from the HVAC systems. Filtered Water Svstern Water from Lake Norman is treated for both process and potable use. Filtration is performed by DE filters. Water from the Low Pressure Service Water System is treated with chlorine for disinfection purposes and polyelectrolytes to coagulate colloidal material. The water is filtered through one (1) 750 gpm DE filter while a second filter is on standby. The filtered water is stored in three (3) 42,500 gallon Filtered Water Storage Tanks. When the administratively determined pressure differential across the filter is achieved, the filter is backwashed thereby removing the filter cake. The system utilizes approximately 100 pounds of DE and 16 ounces of polyelectrolyte per day. Backwashing requires approximately 3,000 gallons of water per day. Approximately every 2-5 years, citric acid is used to clean the filter elements because of tube fouling. The approximately 110 gallons per year of waste citric acid is collected in drums -and treated with caustic to adjust the pH and precipitate any metals that may be present. The waste is then discharged to the WC system. 8 Drinking Water System The Drinking Water System takes suction from the filtered Water System and pumps it to the 5,000 gallon Drinking Water Storage Tank. ; Deminerali ed Water S stem. The Demineralized Water System provides high purity water for make --up to the primary and secondary systems and for laboratory usage. There are two (2) carbon filters and two (2) mixed bed regenerative demneraliers with a system design flowrate of 475 m. Normally, two (2) carbon bens and one (1) demineralizer is in use while the other is being regenerated or is on standby. The Demineralized Water System takes suction from the Filtered Water System. The carbon filters remove organic substances and any residual chlorine. These filters may be cleaned by backwashing, steam cleaning, and rinsing. The cleaning occurs twice per months 15,000 gallons of waster are used for the cleaning. Each carbon bed is replenished every six to twelve months. With normal demineralied water requirements, regeneration of one deminerali er occurs approximately every fire (5) days. To regenerate the resins, sulfuric acid and sodium hydroxide are flushed through; the: bed. At the ;present time, each normal regeneration takes approximately 90 gallons of sulfuric acid, 400 gallons of 5 % sodium hydroxide, and 75,000 gallons of water. The amounts of required acid and caustic will Crary as dictated by operational requirements. ;The demineralier beds are surfactant cleaned approximately two to four times per year, caustic soaked annually, and brine soaked as necessary to remove foul is from the resin. The frequency of cleaning may vary depending on the need as determined by the quality of the water produced. The deminerali er beds are sluiced and replenished approximately every four () to seven (7) years. Turbine SLiM The Turbine Building Sumps receive inputs from leakage, drainage, and liquid wastes from equipment and floor drains located in the Turbine Building. inputs include Groundwater Drainage Sump, Auxiliary Electric Boiler Blowdown, Steam Generator Blowdown, filter air handling units, Diesel Generator Room Sumps, lab drains, ;floor washes, and condensate polisher backwashes. dither possible inputs include CCW Un atering, and steam generator wet lay --up. Chemicals that may be in this flow include the following: ammonia hydrazine morpholine (planned for future use) nitrite bor- /ben otria ole (B T) corrosion inhibitor m crobiocide industrial cleaning products laboratory chemicals 9 The Turbine Building Sumps normally are routed to the WC System. However, if radioactivity limits are exceeded, these sumps can be routed through,Radwaste or to the radwa to discharge point depending on the treatment needed. Very low levels of radioactivity can be routed to the WC System. All radioactivity is; accounted for and regulated by the NRC. Diesel C,enerator Room S s The Diesel generator Room Sumps receive; inputs from leakage or draining the diesel generator engine cooling water, fuel oil, and lubrication systems. Each diesel generator room has two 2) s ps . The smaller sump has a volume of 600 gallons and one (l ) pump with a capacity of 25 gpm. The Larger sump has a volume of approximately 4,000 gallons, two 2) pumps with a capacity of 450 pm, and a third pump with a capacity of 50 gpm. The diesel generator engine coaling water systems :have a volume of 800 gallons each. The systems are treated with a mixture of sodium nitrite, borax (sodium tetr orate), sodium bicarbonate, and sodium mercaptobenothiaole (' Tto maintain a minimum concentration of 2000 mg/1 nitrite. The system is drained and flushed to the WC System approximately once per year. Additionally, the fuel oil contains residualbiocide to reduce bacterial breakdown of the oil.. Lab Drains 'here are several laboratories that provide analyses on the processes within the plant and which drain to sumps that discharge to the WC system. The discharges contain the standard and typical laboratory chemicals used in analytical procedures performed to verify the quality of process streams. Floor Wash The floors throughout the station are maintained by a contract vendor. Products used to clean and maintain the floors consist of the typical commercial products. Condensate Polisher Backwash Over time, trace impurities in the condensate system increase in concentration. In carder to maintain the integrity of the condensate system, the condensate is processed through powdered .ion exchange resin. A condensate polisher is backwashed on an average of once per day. The backwash contains approximately' 1 -20 cubic feet of resin, 120 milliliters of polymer, and requires approximately 10,000 gallons of water. The resin may contain trace quantities of radioactivity from primary to secondary leaks. The NRC-approved Technical Specifications specify whether the resin is to be treated in the WC System or by Radwaste based on the amount of radioactivity present. 10 Condensate Polisher Element Cleanin The stainless steel filter elements used in the Condensate Polisher tube bundles will be acid washed to clean any fouled elements. ]wring the cleaning process, the elements will be placed in an acid bath consisting either of phosphoric acid, oxalic acid, citric acid or self is acid. Initially, ;because of its effectiveness, a twenty (0) percent phosphoric acid solution will be used although the option is available for switching to any of the ether three () acids. Elements washed, with acid will be placed in a rinse tank to remove the :bulk, of the acid adhered' to the elements. From the rinse tank, the elements are backwashed at a flaw rate of approximately 60 gpm can a, flush stand. With 1218 elements per bundle, approximately 2400 gallons of flush water will be generated monthly assuming one bundle is cleaned each month. Wastewater from the acid and rinse tanks will be routed to two () 500-gallon treatment tanks for pH adjustment or metal precipitation utilizing a dilute sodium hydroxide solution. Wastewater from the flush stand can be routed to a holding tank of approximately 4000 gallons before discharge. All waste will be discharged via a turbine building sump to the WC System or Eadwaste depending on the presence of radioactive contamination. Wet Lau Each of the four (4) steam generators per unit has a volume of `0,000 gallons. Each unit is provided with a Steam Generator Hlowdown Recycle System, Steam generator'blowdown is continuous at a rate of approximately 5000 gallons per hour to maintain acceptable steam generator water chemistry. The blowdown is directed to either the condensate polisher demineralizer or to the steam generator bl.owdown dexineralizer. If the blowdo n water quality is unacceptable, it is discharged. It can be discharged to the WC system or to radwste depending on whether it is contaminated with radioactivity. During normal operation hydrazine is added to the condensate system for oxygen scavenging. The hydrazine concentration' is maintained within a concentration range of 25- 200 ppb. Ammonia is added for phi control. The steam generators and hotwell are placed in wet lay-up if a unit is to be in cold shutdown for two days or more; Each unit is normally shutdown on a 10 month cycle for refueling. Wet lay-up is the method used for protecting the steam generators against corrosive attack during inactive periods. Chemical additions are made up in a 150 gallon Conventional Condensate Addition System tank. Normally, 55 gallons of 54 hydrazine and 0 gallons of aqua ammonia are made up for transfer to the steam generators. Any remaining chemical solution is drained to the WC system via the turbine building sump. prior to returning the unit 11 to operation, this wet lay-up solution (75- 50 ppm hydrazine) is drained to the WC System or Radwaste via the turbine building sump. The hotwell on each unit has a volume of approximately 250,000 gallons. During each unit shutdown that is two days or more in length, the hotwell is placed in vet lay-up. Maximum chemical concentrations should be approximately 50 mg/l hydrazine with the B adjusted to 10.2 with ammonium hydroxide.- Prior to returning the unit to operation, this wet lay -pup solution is drained to the WC system or Radwaste via the turbine building sump. AuxiliaLy Electric Broiler Blowdown The Auxiliary Electric Boiler; is supplied feedwdter from the 'condensate system which contains hydrazine and ammonia. Trisodium phosphate is added as an electrolyte. The blowdown from the boiler contains these three chemicals and approximately 1, 000- , 0 0 ppb suspended solids. Blowdown is routed to the WC System via the Turbine Building, Sump. The system is used approximately 10 claim per year. Groundwater Drainage_ System The Groundwater Drainage System is designed to relieve hydro- static pressure from the Reactor and Auxiliary Buildings by discharging groundwater collected in sumps to either a yard drain or the turbine building sumps. There are three (3) groundwater sumps with two () 2 }- m sump pumps each. Two; of the sumps 'discharge to the turbine building sumps hi;.e the third sump discharges to a'yard drain that is routed to the SNSWP. CCW Unwate in The CCW system for each of the two () units has a volume o approximately 2 million gallons. Whenever a' unit is scheduled down for refueling, periodically during rather shutdowns, and for condenser tube leaks, the system must be unwatered for maintenance purposes. The water is essentially lake water. The principle discharge route is through the Wastewater Collection Basis ( ), but it can: be routed through the WC System for short periods of time. Standby Shutdown FacilityZClosed Cochin stem The Standby Shutdown Facility (SSF) is an alternate and independent means to shutdown the station during emergencies should the need arise. The independent power supply for the SS is a diesel generator system. The S F contains a sump to collect system leakage, floor wash, and drainage of the equipment for maintenance. The coaling system for the- diesel generator system is a closed cooling system. The coaling system is maintained at approximately 2000 to 3000 ppm of a sodium nitrite/sodium tetraborate/soda benotriaol.e (BZT) corrosion inhibitor. The 91 cooling system is flushed to the WC system annually to maintain efficiency. There are approximately 10 to 15 closed cooling systems within the station. The largest system has a volume of approximately 0,000 gallons. The main portions of these systems are constructed of carbon steel. A sodium nitrite (2 00 mg/l)/borax (sodium tetraborate)/sod ben atria ole (BZT) corrosion inhibitor is added to control corrosion. An organic biocide is added to control biofouling. These systems may need to be drained, individually, for non` -routine maintenance.. should this occur, these systems would, be drained to the CCW discharge, WC System, or Radwaste if contaminated with radioactivity. Steam generator 21±Aninq Each electrical generating unit contains four (4) steam generators that have a capacity of approximately 40,€00 gallons each. There have been no chemical cleaning of the steam venerators to date. However, whenever a chemicalcleaning is performed, all four steam generators will be cleaned based on need as determined by the the al -hydraulic performance. One possible cleaning solution, based on previous experience, consists of 15ammoniated ethylene diamine tetracetic acid (EDTA), 1% CCI 80/. (a proprietary corrosion inhibitor), l hydrazine and ammonium hydroxide fear pH adjustment. The spent solvent may contain radioactivity, iron, and other metals in trace quantities. It will possibly be treated by demineralization and neutralization/ ; precipitation. Treatment will be either performed in Radwaste' or the WC System depending on the level of radioactivity. Additionally, rinse/passiv tion'( 00 ppm Hydrazine with the pH adjusted to 10.2 with ammonium hydroxide) water will be required. The rinse water will be: processed' followed by neutralization/precipitation in the WC System. The process may be modified for each cleaning depending on the scale deposited within the steam generators. Other solutions may be utilized; in the cleaning. Miscellaneous System/Component CleaniE2 Other systems may need to be; cleaned periodically because o scaling or plugging. Other components will be cleaned a necessary for various fouling problems. Solutions utilised will be these used in standard chemical cleaning methodologies. Chemicals utilized by these methodologies, alone or in combination, include the following. Alkaline Boilout Solutions non -:ionic surfactants anionic surfactants cationic surfactants sodium hydroxide soda ash 13 trisodium phosphate sodium metasilicate disodium phosphate monosodium phosphate sodium bicarbonate Acid Solutions hydrochloric acid sulfuric acid phosphoric acid formic acid hydro acetic acid self is acid citric acid nitric acid Acid Solution Additives thiourea ammonium bifluoride oxalic acid EDTA Compounds and HE TA pH adjusted tetra -ammonium EDTA tetra -ammonium EDTA di -ammonium EDTA hydro xyethylenediaminetriacetic acid tetra -sodium EDTA Miscellaneous g2Mp2unds chlorothene sodium chloride potassium permanganate aqua ammonia ammonium persulfate sodium nitrite antifoam sodium sulfite chlorine corrosion inhibitors(e.g., phosphates, borax -nitrite, silicates, etc.) organic biocides These solutions are described in the Devel2pment Document for Effluent Limitations, Guidelines and New Source Performance Standards for the Steam Electric Power Generatinq Point Source Cateqory (Development Document). The spent solvents from these cleanings will be treated in the WC System or the Radwaste System. The acid compounds will be 14 neutralized; the other compounds will be mixed, oxidized, and/or- precipitated as necessary for treatment. OUTFALL 003 Outfall 003 discharges treated sanitary waste from the Sanitary Waste Treatment System to the WWCB. The Sanitary Waste Treatment System is a four () cell aerated lagoon system. The system was designed to process domestic sewage from rest rooms, showers, lab drains,, and station cafeteria. The lagoon provides a 5-day retention time and will allow for variable level discharge. The wastewater effluent from the aerated lagoon flows through chlorinators, a chlorine contact chamber and a Parshall flume before discharging to the WWCB. The lagoon is lined with a flexible synthetic material such as h alon it is divided into four (4) cells by a curtain material such as a polymer coated polyester with a weighted chain ballast and floatation collar. The first: cell provides for a two day retention time and is kept in complete suspension by surface mechanical aerators. The second and third cells are kept partially suspended providing for partial settling. Each of these two cells has a retention time of one day. The final cell is the settling cell with a retention time of one day. The surface of this cell is'kept slightly agitated to minimize algal, growth. If it becomes necessary to control algae growth, an algicide, such as CUTRINF-PLUS, may be added to the lagoon. From the final cell, the wastewater discharges to a chlorination installation. After passing through the chlorinators, a retention time in excess of 30 minutes is provided by a contact chamber before being discharged to the CB. The sewage lagoon has a multiple level discharge capability at 5 1/2, and 8 feet. At each of these different levels of operation, the lagoon is le to provide a 5-day retention time for influent wastewater flaw rates of 40,000 gpd, 52,000 gpd, and 64,000 gpd, respectively. Accumulated solids are removed from the lagoon approximately every 12 to 18 months to facilitate removal of non -biodegradable material and to optimize the treatment process. The sludge bottoms are +dewatered utilizing a filter press or other suitable method. The solids are treated with lime and disposed of in a State licensed landfill or landfarm. The filtrate is returned: to the sewage lagoon or is treated by neutralization and carbon adsorption or other suitable methods when released directly to the WWCB. An alternative method of sludge disposal is to tank it to a municipal sewage treatment system. OUTFALL 004 Outfall 004 discharges flow from the liquid radwaste system. This flow combines with the C before discharging through the concrete discharge structure (Outfall 001) into Lake Norman. All radioactive and potentially radioactive liquids are collected, segregated and processed prior to release. 'These effluents are classified as recyclable or non -recyclable liquids. Recyclable liquids are recirculated Haack to the process streams. Non -recyclable liquids are collected and processed to Nuclear Regulatory Commission (NRC) requirements (8 CFR Part 20 and 10 CFR Part 58) prior to 1 release with the type of processing depending on the type of waste. The maximum discharge rate from radwaste is '150 qpm. The discharge flow for a Taste Monitor 'lank release is a function of activity level, the number of C:CwW pumps in operation, and the resultant boron concentration in Lake Norman. The liquid radwaste system collects waste in, three () sub -systems (floor and equipment drains, laundry waste, and ventilation unit drains). Chemicals that may be present in the liquid radwaste system include: boric acid borax nitrate Sonia morpholine (planned for future use) lithium hydroxide ethylene glycol benotriaole (ZT) nitrite/borax corrosion inhibitor hydrazine chlorine/hypochlorite hydrogen peroxide ethylene diamine tetracet.c acid (EDTA)_ containment spray heat exchanger lair -up chemicals pump bearing cleaning chemicals laboratory chemicals detergents surfactants olyelectrolytes :industrial cleaning products chemical metals cleaning waste The Turbine Building Sump; can become contaminated with radioactivity. When this occurs, it can be pumped to the :door Drain. Tank ( ') or to the Radwate release paint in the CCW crossover line. The decision: on the method of treatment depends on the amount of radioactivity in the waste stream. Any chemicals listed as being in the Turbine Building Sump may be in Radwaste when the waste stream is routed to Rad aste. Any solids generated in the treatment process are solidified or dewatered and transported to a State and NRC licensed low level' radioactive waste disposal facility. Floor,,EqLiipment, and Laundr Trains All floor drains in the auxiliary building, drains from all equipment (pumps, tanks, heat exchangers, etc,) which process aerated radioactive waste, waste from showers in the change rooms and washing equipment which is used to decontaminate protective clothing, and waste from the Unit 1 and Unit 2 containment floor and equipment sumps are routed to the Floor Drain Tank (FDT), Waste Evaporator Feed ".Dank (WEFT), Auxiliary Floor gain Tank ( DT), Auxiliary Waste Evaporator Feed 'Tank (A FT) , <and/or Laundry and riot Shower Tank (LMST) . The total tank' volume is 125,000 gallons. "These collection tanks are used 16 ri interchangeably and/or as backup and surge capacity for waste collection upstream of processing. Waste from these collection tanks is then processed using filters and/or demineral.izers. The processed effluent is collected in waste niter tanks for sampling and analysis prior to release. Release i to Lake Norman via the CCW crossover line. Ventilation Unit Drains The Ventilation Unit Condensate Drain Tanks (VUCDT) collect condensate from air handling units from each reactor building. Each VUCDT has a volume of 4,000 gallons: This waste typically has little radionuclide contamination and no chemical contamination. The waste is sampled for radionuclide contamination. If this sampling indicates the need, the VUCDT contents are transferred to the FDT for processing. If no need for processing is indicated, the waste is released from the VUCDT via the CCW to Lake Norman. Twice per year 'a portion of the ice in, the 'annulus in the reactor building is melted and drained to the VUCDT. The VUCDT could contain boric 'acid from the ice melt, Chemical Volume and Control System The Chemical Volume and Control System regulates the concentration o chemical neutron absorber in the Reactor Coolant System to control reactivity changes and maintain the required water inventory in the Reactor Coolant System.. Soren is used as the chemical neutron absorber. Appended is a description of the changes in the boron concentration. Other control elements introduced into the Reactor Coolant System by e Chemical Volume and Control' System include lithium and hydrazine. Approximately 120 pounds of lithium hydroxide monohydrate are used in each unit per year for pH control. The lithium is removed by demineralizers in the Reactor Coolant System of the liquid radwate system. During cold shutdown, hydrazine is used as an oxygen scavenging agent. It is removed during start up and is not used at any other time. During shutdown, hydrogen peroxide is added to the Reactor Coolant System to facilitate the removal of activated corrosion products. OUTFALL 00 Dutfall 005 discharges flow from the Wastewater Collection Basin ( C ). The WWCB is a 13.4 acre collection basin having a total capacity of approximately 40 million gallons, drawdown capacity is approximately 11 million gallons. Discharge from the basin ranges from 0 to 20,000, gpm. If the Standby Nuclear Service Water Pend (SNS ) is being flushed, no holdup of the WWCB is possible; otherwise,_holdup is minimal. The WWCB provides 17 sedimentation, natural neutralization, and skimming. The overflow from the WWCB mixes with the discharge from the WC System (Discharge 002) in a concrete apron and is discharged to the Catawba River downstream of Cowans, Ford Dam. An algicide, such as CUTRINE-PLUS, may be needed to control algae growth in the pond. Inputs into the basin include overflow from the SNSWP, treated sanitary waste effluent, yard drains, a lab sink and floor drains, miscellaneous Administrative Building drains, and CCW system unwatering. Standby Nuclear Service Water Pond The SNSWP is a 34.9 acre pond designed to provide water for the safe shutdown of the station in the unlikely event that Cowans Ford Dam is lost. The level in the pond is maintained, per requirements of the McGuire Nuclear Station Operating License Technical Specifications, by pumping water from Lake Norman into the pond. The pond will receive runoff from a drainage area of 171 acres. The containment spray heat exchanger cleaning solutions may occasionally be routed to the SNSWP. Sanitary Waste Treaeat stern The sanitary waste treatments system is a four (4) cell aerated lagoon system. It provides approximately 5 days retention and allows for variable level discharge. The effluent flows through chlorinators, a chlorine contact chamber, and a Parshall flume before discharging into the WWCB. The sanitary waste treatment system is regulated as Discharge 003. Lab and Floor Drains The lab sink and floor drains discharge approximately three (3) liters of chemical waste per month. These chemicals are standard and typical laboratory chemicals used in analytical procedures performed to verify the quality of process streams. Flow from these drains go to a groundwater sump then to the SNSWP and then to the C. Administrative Buildin2 Drains The Administrative Building drains include an HVAC sump, floor drains, hot water boiler and chilled water system discharge. Any chemicals in the drains would include the typical commercial products used to clean and maintain the floors as well as sodium nitrite/borax/benzatria zole corrosion inhibitor, phosphate corrosion inhibitor, and microbiocide from leakage/drainage of the HVAC systems. CCW System Unwaterin2 The CCW System for each of the two (2) units has a volume of approximately 2 million gallons. Whenever a unit is scheduled down for refueling, periodically during other shutdowns, and for condenser tube leaks, the system must be unwatered for purposes of maintenance. Unwatering must continue while maintenance is performed because of leakage by the valves in the approximately 11-foot diameter CCW 18 piping. The maximum unwatering rate is approximately 2000 m; the water; is essentially lake'water. Discharge is via the turbine building sumps. Administrative controls are in palace, however, to restrict inputs to the sumps during unwatering. Treated liquid radioactive waste effluent (Discharge 0 ) discharges into a crossover line between the CCW system of the two units. During unwatering, the possibility exists for trace amounts of radioactivity to be released into the water from the unwatering process because of isolation valve leaf -by. All radioactivity is accounted for and regulates by the NRC. The principle discharge route of the unwatering is through the WWCB. However, it may be routed through the WC System for short periods` of time. Yard Train Most yard drains discharge to the WWCB or SNSWP. The drainage area for the plant site is approximately 250 acres. COWANS FORD DAM UNDERDRAIN SYSTEM The Cowans Ford Dam underdrain system discharges flaw to a ravine that leads to the Catawba` River. prior to the construction of Cowans Ford Dam and McGuire Nuclear Station, there were indigenous springs in the area. When the dam, and subsequently the station, were constructed, the dam underdrain system and the springs/groundwater in the vicinity of the Low Level Intake Pump structure were collected and piped assay from the area. Part of the water was piped to a ravine. The water is believed to be lake or groundwater based on the quality of the water as demonstrated by the Fart i analyses: Fire protection water is used as bearing lubrication and gland seal water for the Low bevel Intake pumps. This water is processed by cyclone separators to remove any silt or sediment that could damage the pumps. The drains from the separators discharge into the underdrain system. Yard drains in the area discharge through this systems 19 APPENDIX Boron Use and Control Boric acid is used as a chemical neutron absorber in the reactor coolant system scar;; reactivity control and to provide water for safety injection. During reactor operation, changes are made in the reactor coolant boron concentration for the following conditions: Reactor start-up - baron concentration must be decreased from shutdown concentration. Load followboron concentration must be either increased or decreased following a change in load.:, Fuel burn -lap - boron concentration must be; decreased to compensate for fuel burn-up and the buildup of fission products in the fuel. Cold shutdown - baron concentration must be increased to the cold shutdown concentration.. The concentration of boron in the Reactor Coolant System varies from g to 2500 ppm depending on core life. The boron concentration is controlled through the Chemical and Volume Control System. The boric acid is stored in the Concentrated Boric Acid :storage Tank at a concentration of 7C}00 -' ,"700 ppm boron. The boron concentration in the Reactor Coolant System is varied by blending reactor makeup water from the Reactor Makeup Water Storage lank and boric acid from the Boric Acid Storage Tank as needed to reach the desired concentration. Excess liquid effluents from the reactor coolant system which contains 0 to 2500 ppm boron are diverted (or letdown) to the Recycle Holdup Tanks in the Boron Recycle System, Water from the Recycle Holdup Tanks can be processed as a batch through the boric acid evaporators where the boron is recovered and recycled to the boric acid tanks.'Any boric acid that is not of sufficient quality to be recycled is processed further in the Radwate System. It is further concentrated, solidified, and transported to a State and Nuclear Regulatory Commission C)licensed love level radioactive landfill. The distillate: from the evaporators is ;either returned to the Recycle Water Holdup Tank or transferred to the ReactorMake-up Water Storage Tank. Water containing boron can also be released to the monitor tanks for discharge as a result of system leakage and flushing operations. The maximum concentration of boron that can be present in the liquid radwaste system discharge is estimated to be 200 ppm. The maximum release rate from the liquid radwaste system is approximately 150 gpm. The liquid radwaste system discharges through a valve" which is controlled by a radiation monitor and flow meter. This valve is designed as an interlocking device which will not open unless the radioactivity is within limits specified' by the Nuclear Regulatory Commission in lg C"R Part 20 and a minimum flow rate is established in the CCW System so that the offsite dose will be within 2 limits specified in 10 CFR Part 50. The resulting concentration in Lake Norman is Less than 0.75 ppm as specified by the Administrative Limits. 1 `(Ti-M V-0 CONTINUED FROM FRONT I 'MCI a-0 1 I> POLLUT- 2. MAfaft 3, EFFLUENT 4, UNITS S. INTAKE (irk titan d) ANT AND AS NO a, r�#c 1e[v C'. i.4.xe . ._.. L##.VYh a, MAXIMUM L'f AiLY .. .. ,.... YAC�C,iE ii MAXIM M 3,q{ p {y��Y' VAC.I.JE C.C. C. '�+p- V A UE (a( fPt#fii2Cbi?fC.' : {iF #Ii!dX1fCl 4r�' f1. NCi Cif 8. G"QNC �S+i�' : a YANG re"M A4ii E.F�l�IFV VAL.. 4i E. " 4 NCA. Of" fit aiaaddabia) ro r#. s e«r An- ...., ._....w.»... # r r t <.11FY"t N'NtiiA�:tt4N ........._._.,..... r Flk !e#K!n i5 _ ..._ �........w ...._. ANAL, —1-1—N Fi'i MASB #SOW %1-111T11— # WY R±i4 Y4'f, �h TO TION h, M ASS ,,.,�.. ,„.. ....... �. C i•"c' nrt if hYixs.N !I Mp"«'4 ANAL, / Yf: .4 . g. NItrogsn, 41,252 _.... ... _ . Total Organic t CCi / I + C . FJ (as N) _ .. _ _ _ h. Off and x 13 w 1,627 1 lb/Day .13 , i. are � f yya0 yP)yy, Tottalal x < a 1� m l < . 0 < 1 ). Radioactivity Total I1 Ci/L X <a4 X (2) Bata, Total X <2 }( 1 pCi/L X2.1+.6 X 1 (3) Radium, Total { 0.'9±. 2 X 1 pCi/L X <1.5' X 1 (4) Radium 226. Total x .3±. 2 x 1 i /L X 1.4±.4 X 1 Sulfate ( $04) X 9.2 115,161 -1 mg/L 1 b/D,aiy 9.6 187,462 1 1 . i5u)fklw' (419) X <1 <12, 51 1 m /L l b/Dav <1 <19. 527 1 1 - x <2 <25,035 1 m /L lb/D y <2 <39,055 1 3) ". Surfactlertt X <.2 < ,50 1 1b/Day <.2 <3,905 1 X 72 9,013 1 ±mg/L l b/Daa--15)61 11,912 1 P. Total (1440-; -) X 02 250 l m j L l b/11i y .02 390 1 .ran Total (7440-4 -a) X . 09 1,126 1 : mg/L 1 b/Day ,11 2,14 1 Total 4is4) X <.1 <1,252 1 mg/ L lb/Day <,1 <1,953 1 a. Iron, Total ("743+3.89) x 44 5f 50 1 m /L 1b/Da .3 5,058 1 Total X 1.2 15,021 1 mg/L 1 b/Day 1.2 23,433 1 u. Molybdenum, Total X .09 1,1 6 1 m /L l b/Day . 07 1,367 1 (7439-91i:-) i Total ax .04 501 1 mg L l b/Day 390 1 (7439.96-5) .02 W. tin, Total 44a .) 1.3 16,273 1 mg/L 1b/Day 1.2 13,433 1 x. T tan tam, Total X .02 250 1 mg/L 1 b/Day .02 390 1 (7440.32-5) 1- EPA Form 3510-2C (Rev. 2-85) PAGE'V-Z CONTINUEON PAGE V .3 EPA I.D. NUMBER (curry frarin Beer 7 Of Porto i) i>ti'Y"1.�ALL NUMBER Fcsrrri Approved CO0 4392 001 OM8 No 2040,0086 gxtaaxrvrrt expires 7 31.88 CONTINUED FROM feAE" OF FORM� . PART C - If you are a primary industry and this outfall contains process wastewater, refer to Tabte c-2 in the instructions to determine which of the GC/MS fractions you mast test for, Mark .. "• in column -a for all scach GC/MSGC/MS fractions that apply to your industry and for ALL toxic metals, cyanides, and total ()barrels. If you are not required to mark column 2•a (secondary industries, no"priocess wastewater outfafls, anti tronrequired taL`1MS fractions). mark "X" in column -h for each pollutant: you kno or have reason to believe is present, Mark "X" in column -c for each pollutant you believe rs absent. If youmark column a for any pollutant, You must provide the results of at least one analysis for that pollutant. If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 pptr or greater. If you mark column 2b for <acrolem acrylonitrile, 2.4 door ophenol, or 2 -methyl-4, 6 dinitrophenot, you toast :provide the results of at least one analysis for each of those pollutants which you kirow or have reason to believe that you discharge In cuncenn ahons calf pf,b or greater, Otherwise, for pollutants for whali you trrark column 2b, you must either submit ;at least one analysis ur br e;fly describe the reasons the pollutant is expected to bar tltsc:lrar tied !Vote than there ate 7 pages to this part-, please review c ach carefully- Complete one table fall? pages/ for each outfall. See Instructions for additional dettails and requirements. I, POLLUTANT L MA+4K 'sc 3. EFFLUENT 4, UNITS S. INTAKE foritionattj AND CAS : _p.. NiltvlL3E r'i a sr t>. +a c u+.- .MAXIMUM OAtL,r VALUE t3. MAr{rMtaM 3t! tF Y VALUE tit e.LCiNG T{" M }�j G, 6rAitrE rr. Nc?.Cit 8. LONGTERM ka rt:? C a ". +. c __.... ..„,.m„...,,.,. (it aval ,rt+0) f+1t ueiatr`kp tad0 _R d CONCEN ik.,�" VALUE ...... _... _,»..._.__ ._.. ,. ..__,.:. ._ ANAL.- Li,MASS ANAL - fit -te'atllalble) �. a++ ae `+ s+i'�r++ !+l tal MAlb l+l ttl. MA.0 ysus TRA'TIONl+l catae1ia- lzl MAUS YSES- :. k..6.., ....,.._ M"t. N't NTRATION fit MASS CS71Y♦ tNT+ AtI." a. t.tNC E'N a• HAIfoF �.._ TRATme METALS, CYANIDE, AND TOTAL PHENOLS IAntimony, Tc tall (7440.36 O) X <. 6 <7510 1 mg/L l b/Day <.-6 <11, 716 1 2M. Arsenic 17440 38 2I' Trust } <1 <12 1 pg/L lb/Day <1 <20 1 3 . Beryllium , . 002 25 1 mg/L l b/Day Total, 744p 41 7l .002 39 4M. Cadmium, Total f744043-1 X .01 125 1 L l b/Day .01 195 1 SM. al (Chromium,7.3) X . 04 501 1 mg/L lb/Day .04 781 1 W CoWer, Total (7440.60.8) X .04 501 1 mg/L lb/Day .03 586 1. IM, IAW,Total y 17439-92-1l .08 m._1001 1 m /L lb/Da e.08 <1,562 1 of Skit, s t` Total X < 1 <1 1 pg L lb/Day < 1. <2 t. Nickel, TotalX <.0 <501. 1 /L lb/Da <.8 < 81 1 f7�t40-02o-oa of y To al (778 Seleniva9'2l X <2 < 5 Mfg/L lb/Daye < 9 1 (7' t Silver, Total X <. 04 <501 1 m /L l b/Day <. 04 <781 1 1 M. Thallium, . 5 < 25 1 m L lb/Da <.5 <9 764 1 Total f7440- •ol 0 s 13M. Zinc, Total X009 113 1 m /L lb/Day .02 390 1 17440-66.61 14M, Cyanide, X <.02 <250 _.1_ /L__. lb/Da <.02 <390 1 Total 15a7 1 5l 0 5M.Phenol$, X <.005 <62 1 m /L lb/Da <.005 <98 1 Total g DIOXIN *. .�3 7estY«5 C?ESGRIDE RESULTST _ �......__.._.._....�.:........_...........v.,:.._.__......:...__._....:..........._..�._ u.®...,.......w...:..: cr luraa+rllaatalaaa tk X - 0tovin It7640161 NEG ATIVE EPA Form 510-2 (Rev, 2- S+I PAGE V•3 ; CONTINUE ON REVERSE CONTINUED FROM THE FRONT MN a-001 1. POLLUTANT AND CA z> MAIMS 3. EFFLUENT 4, UNITIS 3, INTAKE f'raptionaf) NtAECR rN:* AriR4iY; 0J*vr . Y Mc vAcuE ccaN YMr�tVALUE d. NoloF t#fa CONCEN•b, siri VALUE T�E9}� b, NO.OF ffp ###Ba Aw< FAt Fait 6ON+c ENtrNtl bN ($)MASS : ANAE-a. o "A%$ VSES C@NC Jffi NtMA tkt}N CONC C MtFt At1L)M. .':: tT ION MA' tit ht9C}H M� A a ANAL - *Sea G FAA&I6k- VOLATILE COMPOUNDS IV, A f*h't I1#I7:° X <5 <62 1 fag/L 1 b/Day <5 <98 2U�,1� �irl5fl . X < 5 <62 X <1 <12 1 g/L 1b/Day <1 <20 1 4V fs eChlo r m'Xy1f Ether {J� /i"k �{ Fl } } ll �[ �( (04 438.1) ; fl i4 Jk ffV,'8 F{}rm (76.25.2) X <1 <12 1 Mfg/L 1 b/Day <1 <20 1 8V. Cerbon Totrach)orfd* X <1 <12 1 /L 1 b/Day <1 <20 1 (fib-3*) 7V. Chfo nz*na (1 -90-7) X <1 <12 1 g/L 1 b/Day <1 <20 1 @V. Chfor " ). (bromomo 124- 1t)hime X <1 <12 _.w.. 1 g/L 1 b/Day <1 <20 1 OV. Chfor hank (76- -3) X <2 <25 1 pg/'L 1 b/Day <2 < 9 1 1OV.-Chforo- I*t ylviny )Ether X <1 <12 1 g/L 1 b/Day <1 <20 1 11 V> Chloroform (87• -3) X <1 <12 1 g/L 1 b/Day <1 <20 1 12V..01ehloro* brromo tjthene X , <1 <12 1 Mfg/L 1 b/Day <1 <20 1 1311. %?fohfdro- dflluorometh*n* X A X X X X x X X I7fI714f) 14W,1,1-otchloro- «ne (1"4.3) X <1 <12 1 g/L 1 b/Day <1 <20 .�.� 1 1sv, 1,2-01chforo *then* (107-06-2) X <1 <12 1 g/L 1 b/Day <1. <20 1 16v, 1,1-01chloro• otftyl*n* (75-3 .4) X <1. <12 1 pgtp L 1 b/Dad" <1. <20 1. 171f. t,2.l�fchforca- prop*ne (7 -87-) x <1. <12 1 } g/L 1 b/D f,y <1 <20 1: 18V:13•fi 2- t54-76-ff) X < 1 < 12 1 fag/L 1b/Day <1 <20 1 f1.dE'#h4y)f*nz*n* X <1 <12 1 g/L 1b/Day <1 <20: 1 20*-M yl 4rfr+fde {i . s) X <2 <25 1 fag/L 1 b/Day <2 <39 1 L:*;�ethylelf^ide (7 7*3) X <12 1 Mfg/L 1 b/Day <1 <20 1 EPA Form 3510- (Rory. -85) PAGE V•4 CONTINUE ON PAR 71' CONTINUED OR EPA 1.0. "U ER (copy from Itent I of For 1) OU rFALL NUM19EFt NCO024392 001 Form Approved, OA48 No 2040 0086 i I PAGr- v_4 Approval expires 7-31-88 1,POL4.UTANT ANDCAS 2. MA"K'A' I NOW 3. EFFLUENT 4. UNITS ml ., OWN flonw) NUMBER ok. c- 14,44 #'LVK a. MAXIMUM DAlt.Y VALUE b. MAXIM M 3&R/kjY VALUE 00 e soar VALUE CLONG Tl�tpM A d No. - or 8, LONG TERM It 040 of (it available I Or, pft�- As- **,my Lu , It caft'LN't E RAYI : 0" , , : Iz) ��� ANAL- I YSES TRATtON b� MASS --- I toweaft. 11) **A** ANAL- YSS* GCIMS FRACTION VOLATILE COMPOUNDS (continued) 22V. Methylene Chloride (75.09-2) x <1 <12 1 pg/L lb/Day <1 <20 1 23V. 1,1,2,2-Totm chloroathane (79.34-6) x <1 <12 1 pg/L lb/Day <1 <20 1 24V. Tstrechforo- ethylene (127.18-4) x <1 <12 1 pg/L lb/Day <1 <20 1 25V. Toluene (108-88-3) —1,2Trans— x <1 <12 1 pg/L lb/Day <1 <20 1 ifivi' Dichloroethylene (156-60-6) x <1 <12 1 pg/L lb/Day <1 <20 1 'T7_V. _10.1 __i7fl chloroothano (71.65-6) x <1 <12 1 pg/L lb/Day <1 <20 1 chloroathano (7900_5) x <1 <12 1 pg/L lb/Day <1 <20 1 29V. TrIchloro- ethylene (79.01-6) x <1 <12 1 pg/L lb/Day <1 <20 1 30V, Trichloro- fluoromethane (76-69,4) X N/A x x x x x x x 31VVinyl Chloride (75-01.4) - x <2 <25 1 pg/L lb/Day <2 <39 1 GCJM$ FRACTION — ACID COMPOUNDS IA. 2-Chloropheno! (95-57-8) x <10 <125 1 pg/L lb/Day <10 <195 1 2A. 2,4-01chloro- Phenol (120-83-2) x <10 <125 1 pg/L lb/Day <10 <195 1 3A, 2,4�Dirnethyl, phenol (105-67-9) x <10 <125 1 pg/L lb/Day <10 <195 1 4A. 4,6-Dinftro-o' Crosol (534-52,1 j x <10 <125 1 pg/L lb/Day <10 <195 1 5A. 2.4-01rntro- phenol (51-28.5) x <10 <125 1 pg/L lb/Day <10 <195 1 6A. 2-Nitrophenof (80-75-6) <10 <125 1 pg/L lb/Day <10 <195 1 IA. 4-Nitrophonol (100-027) x <10 <125 1 pg/L lb/Day <10 <195 1 8A, P-Chloro-M. ctasof (59,50-7) x <10 <125 1 pg/L lb/Day <10 <195 1 9A: Pontschloro Phervol (87,86-5) x <10 <125 1 pg/L lb/Day <10 <195 1 10. Phenol t15 2) x <10 <125 1 pg/L lb/Day <10 <195 1 chlorop6o (88 06-2) not x <10 <125 pg/L 7b/Day <10 <195 1 3.tVVLULNT —7—c UNITS IVILK IT IitateJoil ruo k7i;; To;;- 1 00 10010 fit I 00""a It) ".st vsfs 8, co"crw TRATION t,-M^SS '414 A, 4, yscs RACTION — BASEINEUTRAL COMFCiUNDi x <10 <125 1 pq/L 1 b/D.ay <10 < 195 1 x <10 <125 1 _pg/L jA/Day <10 <195 1 x <10 <125 1 <10 <195 1 plracane Idlna x <20 <250 1 lb/p. <20 < 390 1 o (a) X <10 <125 1 pg/L 1 b/Day <10 <195 1 W-32A) x <10 <125 1 lb/Qy_ <10 <195 1 to no x <10 <125 1 Vg/L 1 /Day <10 <195 1 o (Ohl) 2) - x <10 <125 I b/Day <10 <195 1 f- foars"T (207-08-9) <10 <125 1 pg/L lb/Day <195 1 108. Dis (2-Chloro. ethoxy) Methane (11191.1} - X A r <10 <125 1 pg/L I b/Day —<10 <10 <195 1 - --- I Z) a efs(2 c ethyl) th4�h toro- fill-44-4) x <10 < 125 1 pg/L lb/Day < 10 <195 1 12t ft f2-Chkroilto- wW#EtfwfIO2-WI) X <10 <125 1 pg/L lb/Day <10 <195 1 ---- hexyl) (117-01-7)Phtholsto x <10 <125 1 pg/L 1 b/Day <10 <195 1 148. 4-9romo- ph#nVIPh*rvVI Ethel, (101-55-31 —0-ty, x <10 <125 1 pg/L lb/Day <10 <195 1 Bgnzyl <10 < 125 1 /L 1 b/Day <10 1 <195 1 lss7-Chloro- nophtholotto 1 < 10 <125 1 pg/L 1 b/Day <10 <195 1 4-Chloro- pho"VI ' pb4nvl Ether 171605-72,3) X <10 <125 <10 <195 1 188. Chryssne (216,01-9) x <10 <125 pg/L <10 <195 1 198. Dlbonzii -I —lb/Day Aothrocono (63-70-3) x <10 <125 1 Wg/L lb/Day <10 <195 1 208.1,2-Dichloto- benzene (95-50-1) x <10— <125 1 pg/L -lb/Day- <10 <195 -F---F- 1 2M 1,3-Dichloro- F1.8; I .4.3-Dl.jhl7-r- _ 3_; bonz*rnt (541-73-1 x <10 <125 1 pg/L lb/Day <10 <195 1 EPA Form 3510-2C (Rev. 2-85) PAGE V-6 CONTINUE ON PAGE V • • VM Of • II : .. n e 1 • (111-84�0) IF a. Haxi- tiltiorobutadlene • t. t s 8 i !! C(11+iT)Nl1ECt FROM THE FRONT 1. !'C?L UTANT ' 2. r#v rr+t ^x* 3. EFFLUENT . UNITS 5. INTAKE (f)iatiattatj AND CAS N l.i M i2 A ♦e •w iA ae C. wC.- 3WYn 3R.V#E# 4BMl+F ,_� _ _ at. DAILY V,t4LUiz. �..;aXtMcMtv'a��u f itL+ftt tt C _. c twcrnr Mi F A8trt7t tt # P ff NO t9F tf iiu a. t t>rt��r*W :A 4k'?N t: t r t'tM t rt E k'4 !� 4 C...Y.. 8- t,1, Ix fat'# CAB' �r {tP iit3r d�94�' �t M. 9t NY *w"T aat..... .«.MAXIMUM_M. _......,. _.. ._ # f �i� MRhi # l%t#NfA#AT#Ca� _ „, ,_r!..,......-.-...,_...w,.; t#� �i�:M A4±. #33:WY1#AftdLN _ _ .�......,� nrant. tf� ( �- naU •®.•,• Ydet :Y: C433akC itiA9F33M �i����t�R*a it ateici �d� r'. A tit �.li MAY% #ttA3tEY.f xr+na h'$rs GC FRACTION -- BASEINEUTRAL COMPOUNDS UNDS (r#srA ismett) WNW*- li d�y. gqhtytvi#yisrnfre <10 <125 1 g/L l b/Day <10 <195 1 "0. Phoosothrone (85=01.8) <1.0 <125 1 g/L l b/Day <10 <195 1 no i 29 P o x <10 <125 1 dig/L l b/Day <10 <195 1 . 1,2,4 - TO- x <10 <125 1 - g /L lb/Day<10 <195 1 (12 2-1 QCNS FRACTION - PESTICIDES 1P. Aidrin } (-2) 2P. 4.9HC 1319.84-5) x x (1 -85.7) 4P�.t 1{jy}yBHC x aP. 8.8HC °.., x (319.88 8) . 5P. Chiordsne x (67.74-9) 7P3.yy 4yy�,4*-- DT y]{} 8P. 4,4'.DDE } (72-55.9) 9P, 4,43-OOO (72-54-8) IOP, Wotdrin x (60.57-1) 11P. it•8ndorutfon 115-29.7) i 12P. -8 osuifen (115-29.7) x 12P.8ndosuifan Suifoto (1 1.07-8) 14P. Endrin ._ P (72-2 ) 15P.5ndrit Aidohydo (7421-93.4) 18p. Hootsehior x (7'6-44.5) EPA Form 3610- C (Rev. 2-55) PAGE -8 CONTINUE ON PAGE -9 ITIM V-0 CONTINUED FROM FRONT MNS-002 I. PoLwr- 2� MA"*!I'X' 3, EFFLbENT 4, UNITS 5, INTAKE (t,11thowtj ANT AND CAS NO wwVCcLW"" MAXIMUM MAILY VALUE b MA I 'PAY VALUE VALUE (11 W1011. 0010 LION It '�- --� a CONCEW tl� MAS% A t� EY2^NtC;r.'TVVA"LM1J E Of ANAL. - P*V- 11 ---,--T - 'T - tPI -�ASS TT' --- -- - ANAI, 14-j MA�S 111-1) =- 111 ' "T'F4 ACT 10 N 1 111- :I Total Organic fas N1 x .57 3 1 mg/L 1 b/Day <. 08 <1,562 --i h� Off and x .33 1 .22 .5 2 mg/ L 1 b/Day .13 2,538 1 W- (A# r), Total (7723-14,0) x 08 4 1 mg/L lb/Day <.02 <390 1 1. RedloactivitV (1) Alpha, Total x <.9 x I pCi/L x <.4 x 1 (2) gout, Total x 5±1.4 x 1 pCi/L x 2. 1±. 6 x 1 (3) Radium, Total <.5 x 1 pCi/L x <1. 5 x 1 (4) Radium 226, Total x <.1 x 1 pCi/L x 1.4±. 4 x 1 x 430 2,225 1 mg/L I b/Day 9.6 187,462 1 1. Suffide, loot g) x < 1 < 5 1 mg/L I b/Day < 1 <19,527 1 x < 2 <10 I mg/L I b/Day < 2 <39,055 1 n. suffeatents x <.2 <1 I mg/L I b/Day <.2 <3,905 1 0. Aluminum. Total (7429-90-5) x 1 5 1 mg/L .61 11,912 1- WT P To- U-M. -lb/Day Total 47440-39-3) x .04 .2 1 mg/L I b/Day .02 390 1 Total (14010-42-8) x .34 2 1 mg/L I b/Day 11 2,148 1 Total 17440-48-4) x 5 1 mg/L I b/Day 1 < 1, 953 1 a. Iron, Total X .3 2 1 mg/L I b/Day .3 5,858 1 Total. (74" 05-4) x 1.8 9 1 mg/L lb/Day 1.2 23,433 1 U� Molybdonum, Total (1439-98-7) x .14 .7 1 mg/L lb/Day .07 1,367 1 v. Total (741111-915-15) x .07 .4 1 mg/L lb/Day .02 390 1 w. Tin. Total (7440�31-5) x 2.5 13 1 mg/L lb/Day 1.2 23,433 1 x. Titan um, Total (7440-32-6) x .04 2 1 mg/L lb/ Day .0 2, 3 90 1 1 1 EPA Form 3510-2C (Rev, 2-85) PAGE�V-Z CONTINUE ON PAGE V - 3 CONTINUED FROM PAGE 3 OF FORM 2-C :PA I.D. NUMBER (copy front lle»t 1 of Forth 1) OUTFALL NUMBER Torn: Approved t7M8 Atca 2040 0086 NCO024392 002 Approval expires 7 1.88 ran I k, - It you are apt omary mctusiry ano ttus outtait contains process wastewater, tefer to Talale 2c-2 in the instructions to determine' hi h of the GC/MS fractions you mustiest for. Mark'X mcolumn 2 a for all such GC/MS fractions that apply to your industry and for ALL toxic; metals, cyanides, and total phenols. If you are not required to mark column 2-a fsecondary industries. nonprocess wastewater outtalls, and nonre uared taf~I MS fractions),` mark -X- in cotutrin 2-b for each pollutant you know or have reason to believe IS present. Mark "X" in column -c for each pollutant you believe is absent. If you mark column 2a for any pollutant, you must provide the results of at teast one analysis for that pollutant; If you mark column 2b for any pollutant, you must provide the results of at least one analysis for that pollutant if you know of have reason to believe it will be discharged in concentrations of 10 ppta or greater. If you mark column 2b for acrolein, acrylonittile, 2,4 dinitiophertrtl, or 2-methyl-4, fa dinittophenoi, you mist provide the results of at least one analysis for each (if these pollutants which you know or have reason to believe that you discharge in concenti ations of 100ppbor greater. Otherwise, for pollutants for whtch you mark column 2b, you must either submit at least one analysis of briefly desrritte the reasons the pollutant is expected to be dischatgwl Note that there are 7 pages to this part; please review each carefully. Complete one table (all 7 pages) for each outtalt. See instructions for additional' details and requirements. t. FOLLUTANT Hamra 'X' 3a:N. EFFLUENT _ 4. UNITS Tit i\Tla. ANIN TAKE (opthmal/ At -ID CA NUMB b. MAXIMyM I?VALUE C,1-0NCTki VALUE . LONG TERM [-- _ua ,MCK.Cta ii, 140 Cw 7 yc.". it CONCEN ANAL acrtrla) a i°-HNA4TRATIOri t. MR55 Irp ccNcarNin a Its mAss rs M. teI MAU6 VSES LL-1, - t""ATatN METALS, CYANIDE, AND TOTAL PHENOLS i all ( Antimony, of X <. 6 <3 1 mg/L lb/Day < 6 <11,71 1 2M, Arsenic, Total (7440 38 2) X 1. .006 1 erg/L lb/Day <1 <2( 1 3M. 8ary l l iu rn, Total, 7440-4t-7) X .003 .02 1 mg/L 1 b/Day .002 1 AM. Cadmium Total (7440 ci ) X .02 1 1 g/L 1 b/Day .01 19 1 5M. Chromium, Total (744047-3) X .08 .4 1 /L 1 b/Day .04 781 1 (7440�60.8) Total X .1 1 mg/L 1 b/Day .03 586 11W Used, ' (7439«I X .18 - .9 1 mg/L 1b/Day <.08 <1,562 1 8M, Mercury, Total' (7439.97-6) X <.1 <.0005 1 Ng/L 1b/Day <.1 <2 1 ( 440--0Nickel,Total X < . 0 .5 1 m /L 1 b/D y < . 04 <781 1. to . selenium (7782.4s� 2) <2 <. 01 1:.. pg/L lb/Day <2 <39 1. 7 sa lver Total _X <.0 1 g;/L 1b ay <. 04 < 781 1 um Total (7442. 0 a of X <. 5 <2 1. m /L 1b/Day . 5 <9,764 1: 13M. Zinc, Total (7 40-5fa 6) X .03 .2 1 g/L 1 b/Day .02 390 1 t 4M. Cyanide, Total(57.12-5} X <.02 .1 1 mg/L 1b/Day <' 02 <390 1 Total nia �hats, lX .005 .02 1Mg/L 1b/Day <:005 98 1 DIOXIN tetra T TQESCRISE RESULTSw. ciztoroUittc+rtcea i' to as Tilt (1764 01 tit X NCGA 1 6 EPA Forn 3510-2C (Rev. 2.8 ) PAGE; V-3 CONTINUE ON REVERSE CONTINUED FkIOM THE FRONT M[NS-00 1. POLLUTANT T AND +GAS 2. M rtK 1x* 3 FFLUEN ' 4. UNITS X S. INTAKE fi)pti fsalj F1l,tM iI 4,rant •c^ C. •a• P» .rat &. tk�AXIMUM DAILY VALU1�` neat M317A.� VALUE c.c es� t y VALUE ai at ittrm ah „.: �f. t�tCt. tt� e, LONG TERM rM1 !> Ni?.C7i 5i( Oihl� lO ti dF Out*- #*r#v **#4T it) C iXNC. #_##TMAT00N (41 MA%% `i� (1) Nf% tw� ¢t� MA'.Y Y5� GONG 6#.TN A'Y##W cc#ivc R:rvrq ATPir#1 TPA`�ION �A� corsc tw �X} atl +%i• r#CATt0" vSrs Q S FRACTION VOLATILE COMPOUNDS Zvi r1h C1t17 .s . X <5 <. 02 1 M'g //{1. •. lb/Day "� Q \ Cl '1 Llg/L lb/Day <5 <90 1 <1 <. 005 1 �1g/L lb/Day . <20 1 },�#rr erce ryl Fx Ggttw N/A +e IY } ii ft (155.z) X <1 <.005 1 pg/L l b/Day <1 <20 1 BV,CarbonTotrochlo t 0 lrldo <1 <.005 1 g/L lb/Day <1 <20 1 _ 7V. Chloro naons 11 t 71 j�jj x <1 p�(g <.005 1 g/L lb/Day <1 <20 1 8V. Chlorodi> m bro thboo tf4,t1 11 t <1 <.005 1 .........«... .. Fig/L .... lb/Day <1 <20 1 gV, Chkt pent l76 31 x <2 <.01 �.. 1 .._..... .».. _ pg/L w..._ ««. lb/Day .» <2 <39 1 IOV. •Chloro- t0110-7B-81 Ether <1 <.005 1 pg/L lb/Day <1 <20 1 11V. Chloroform (87- -3) X <1 <.005 1 g/L lb/Day <1 <20 1 12V. Dleli bra thane 116-27.41 x <1 <.005 1 g/L lb/Day <1 <20 1 13V. Dichloro^ dlfluoromathime, t711»71.8) , ( } } }( }i }( 14V. 1#1.01*hloro aft (75• 3) x <1 <.005 1 pg L l b/Day <1 <20 1 *the" (107.06-2) x <1 <.005 1 Llg1L lb/Day <1 <20 1 othyl (7-3FX.41 x <1 <.005 1 pg/L lb/Day <1 <20 1 17V. i#2-DIchtaro- pr n.17 . 7-h1 x <1 <.005 1 Llg/L lb/Day <1 <20 1 48Y.1.3- bran ( -15-$) x <1 <.005 1 pg/L lb/Day <1 <20 1 19V. Ethyl "zone' (1 41-4) x <1 <.005 1 g/L lb/Day <1 <20 1 20*Mothyl 0 ►.t7 3.0 X <2 <. 01 1 g/L l b/Day <2 < 9 1 21 Methyl Ch t7 7-31 x <1 <.005 1 g L lb/Day <1 <20 1 EPA For 10- C (Rev. .86) PAGE V-4 CONTINUE ON PAGE t_.,... jL . ErSA i.i3. NUMB is (copy from If4>tn 1 of Form !) dater aGt u eE korro Approved, OMB No 040 0086 CGNTINtIED FROM PAGF VA NC 24392 00Z Approval expires 7 l •88 !.POLLUTANT 2, MAr+et 'ac" L iIEiVT . EFFLUENT 4, UNITS S. INTAKE (optional) NI..fMbFt fB,aase YNYw Ikrit• Cu'u- r�..wa 1.isva e, MA?tiMClMC1AEL"Y VAL.Ui't. p A # MAXIM M 9, Y VALU C.LONG T M VALUE bt j! cd Nli',. 6iF i tit#tit it t) t oucsila c A. L.ikNC. TENM �� A (a%'oud»$Jcrbldt) NC• ac.#w- NAY k.^ A®1• tANr i*Nt t#I co,L NTNATY+JN Ik) MAY&{ ANAL- #kI::MAma t#} l2):"^Us Y�tES GONG k. N#TNhT#GYN CidNCQN7HATktlH e LQINCEN- TRATION b, MASS t#I conertw .. TN.sI'!"tQM is) Y%YnN a� Y*9111 GC/MS FRACTION- VOLATILE COMPOUNDS (cuithatted) 22V. e(76ene Chloride i76-05-2) - <1� <.005 1 pg/L lb/Day <1 <20 1 23 V. 1,1,272-Tetra• ......... ,»::.........«.,v...... .. �.....:.:. ..:,........... .:. ..... (7-3A-6)ene X <1 <.005 1 g/L lb/Day <1 <20 1 ethylene (127-18.4) X <1 <.005 1 pg/L l b/Day <1 <20 1 25V. Toluene f1 -88.3) X <1 <m005 1 pg/L lb/Day <1 <20 1 Dichloroethylene x <1. <. 005 1 /L l b/Da y <1 <20 1 (156.60.5) 27 . 1,1,1 •Trt• chloroathane X <1 <. 005 1 }Ig/L _ lb/Day <1 <20 t11.65.6I X <1 <.005 1 pg/L lb/Day <1 <20 1 (7 0 5)ene 2 V. Trichloro- ethylene t79-01.6) X <1 <.005 1 pg/L l b/Day <1 <20 1 flooromethane } N/A x x x X X X x (75-68..4) 31V, VIny I Chforlde(75.01.4) X' <2 <.01 1 pg/L lb/Day <2 < 9 1 GC/MS FRACTION -- ACID COMPOUNDS itloropftenaa (9I18-6-67-57.8) X <10 <.05 1 pg/L lb/Day <10 <19 1 2A. 2,4-Dichloro- phenol (I20.83-2) X <10" <.05 1 pgl/L lb/Day <10 <195 1 3A.2,4.00nethyl• phenol t105-67. ) X <10 <.05 _ 1 pg/L lb/Daylb/Day <10 <195 1 4A: 4,6• 34-5r Cresol (534.52-1) .1) X <10 <.05 ,. pg/L lb/Da <10 <19 1 5A. 2,4-01riltro- phenol (51-28-5) X <10 <.05 1 pg/L lb/Daylb/Day <10 <195 1 6A.2-itrophenot 18845.5) X <10 <.05 1 Ng L lb/Day <10 <195 1 (100,02t7) tthenot X <10 .05 1 pg/L lb/Day <10 <195 1 8A. P-Chloro-M- Cresot (59-5€ -7) X <10 <.05 1 pg/L lb/Day <10 <195 1 ' Pentec6-5 ph faereol (87 86.5) X <10 <.05 1 g/L l b/Da < 10 <195 1 t1 5 2) 10A. Phenol X <10 <.05 1 pg/L lb/Daylb/Day <10 <195 1 iticrrrala#ianc X <10 <.05 1 / L lb/Daylb/Day <10 <195 1 ttt8 06- i ONTINOEA FROM THE FRONT MNS-002 1. POLLUTANT ANC}: A z. MARN `xx 3. EFFLUENT _ 4. UNITS 5, INTAKE foptional) �_.«.._. NUMBER strati 0-0 O&W*w ;ta. ram�A:W, r- a, MAXIMUM DAtt:V VALUE - MAXI M 3. ....,... a7lat pp V VAL.UV 9 bre a C C„LONG °t' jF t4Y t #:ViB I Joy} VAC.0 i(3 P N ! 7! ct. rfo� or . CGBN, tit. W LONG TERM tt, Alo} '. fita t, +g fitovallakte) 01#414M• *W"I" t Bad C#NC "12 A� Y4#N e �!! MM4i ...�...»,.......:............ iF� d:#HCCF•T4tA8A#N eHt M l} ,_...... �a� Y„iS d4'CCN6NN1t tr:5N ..___ Y �ip Mn3C JRNAO„.- YS�Y� r�A�t#ti tf. MASS ... fit CYtR4CEM TWATi#N .. t jr) MAO* wANA: YS C3 /M5 FRACTION -- BASEINEUTRAL COMPOUNDS ..___.:. .,._..... _....... w.:..,.. ®..._....,:«._.... .. ...«.:.... .,...... ._..._.. .....w_ mow. 1B. Acenephthene (83-32.9) X <10 <.05 1 L 1 b/Da <10 <195 1 28. AconaphtViene (2t1B•B-a) X <10 <. 05 1 /L 1 /Da <10 <195 1 39. Anthrecene d12a12} X <10 <:0 1 q!L lb/Da <10 <195 1 48. BenzIdine (2 s7) x <0 <.1 b/Da <0 <90 1 6. Benzes (a) Anthrecene 56- } �{ < 10 < . 05 pg/L 1 b/Day <10 <195 1 68. Benzes (a) yrene lso 3z 1 }( <10 <; 05 1 /L 1 b/ ay <10_V < 195 1 70. 3.4-8enzo= __w _ #tuorenthene (205.99. ) X <10 <. 05 1 pg/L 1b/Day <10 <195 1 B. Remo (ght) Perytene (191t24-} X <10 <. 05 1 Fig/L 1b/Day <10 <195 1 90. Sent* (k) F luorenthene (207• • ) X m <10 <.05 1 pg/L lb/Day"—<10 <195 1 108. Bls(2•Chloro- ,ethoxy) Methane X <10 05 1 pg/L -lb/Day <10 <1 5 1 118. Bis (2-Chloro —<. ethyl) Ether 1111.44.4) X <10 <. 05 1 pg L 1b/Day <10 <195 1 126, Bic t2-E o- Ettw(102-eat) } <10 <. 05 1 Dg/L 1 b/Day <10 <195 1 138. Bit (-�Sthyl- �_... ___ _. hexyt) Phthelate 1117 B1•/} X <10 <. 05 1: pg/L lb/Day <10 <195 1 phenylPhenyt Ether (101.55-3) X <10 <. 05 1 pg L 1 b/Day <10 < 195 1 168. Butyl Benzyt Phtheleta (85- 7 .. 10_ 05_.�<10 <195 1 1'BB. 2-Chloro. naphthateine { 1.58,7) <10 <. 0 ._- ._ . _ .__ ..__ w /L 1 b/Da <10 <195 1 178. 4-Chloro- _ _ _.._1_ phenyl Phenyl Ether (7005�72 3) X <10 <. 05 _ _ _. _ _ _.._ L 1 b/Da <10 <195 1; 108, Chrysena (21B.a1 ) X <10 <_. 05 /Da <10 <1 i 10B. Cilh�nzo (o.) _ _ _ _ -. . _ Anthracene (3.70.3) X <10 „ <. 05 _ 1 /L _Lb /Day_ <10 <195 r 1 208. 1.2-Utchloro- tsenzena (85.50.1) X <10 <. 05 _ _. /L 1 b/Dam <10 <195 1 18.1,3- 1chtorp- nxene t541-73- X <10 < 05 1 pg/L lb/Daylb/Day <10 , <195 1 EPA Form 3510- C (Rev. -85) PAGE; it-6 CONTINUE ON PAGE ,298 otyll 0 1 b/Day Phtfil I b/Day 31 B� F luoranthene—T < <. 05 1 1 b/Day (206-"-0) 3213 Fluorens x <10 <. 05 1 1 b/Day <10 < 195 (86-�3-7� 3M. no X <10 <. 05 1 pg/L Ilb/Day <10 < 195 34E,7H.-a—, --x <10 <. 05 1 pg/L Ilb/Day < 10 < 195 358. Hexachforo- v � " <10 <. 05 1 pg/L Ib/Day <10 < 195 cyolopental (77-47-4) 368. Haxachloro- x <10 <. 05 1 pg/L lb/Day <10 < 195 *thmm (67-72-1) --i7-0-. Indono x <10 <. 05 I pg/L b/Day <1 0 <195 (1.2.3-ed) Py one " (193-39-5) 380. Isophorons, X <10 <. 05 1 pg/L lb/Day <10 <195 398, Naphthalene X <10 <. 05 1 pg/L lb/Day <10 < 195 (91-20-3� 408, Nitrobenzetle X <10 <. 05 1 pg/L Ib/Day <10 <195 (98-95-3) 4M N-Nitro, x <10 <. 05 1 pg/L Ib/Day <10 < 195 sodimethylarnino 428, N-Nitrosodil X <10 <. 05 1 Pg/L Ib/Day <10 <195 N-PrOPYISMins 14521-64-7) L MNS-002 CONTINUED FROM THE FRONT I, POLLUTANT t MArttt 'x 3 EF'F"F U;LN1 4 UNt FS 5 tN VAKF: (optional} AND CAS x — DAILY VALUE.': Fd "ytA7itM, M 3 Y VAVUL #: Gs?N r' G VALUE UE. dT tars c)# X0. N n k i#. {QR{Ct r'{_rd trtA"t1caty I o Rp A 5'a # t r#nti, 3 # $4Rp J"A sERMAXIMUM liL 1a+x #rx tTMix txp rax � f xnxtenxxar+d idi�».,+`� nxtr,«' idt � rax+�nx,�dry i'i ,d. _ _ GC11 .+ FRItiC`TIOPI 13A EINEUTRAi COMPOUNDS tr'tfrttfrridrri! 438. N Nitro- - aodiphanyiarnina < 449.. Pherwilthrons. (6a•o1 6) X <10 <. 05 1 nd 7 460 Pyrww (129 11) x <'10 <. 05 1 1,2,4.Tri- sane <10 <. 05 QCAN FRACTION - PE TICIGiE 1P. Atdrin $ -2) 2P, f1.8HC- (319-84-6) P. SHC (3111i5 7) 4P, 8HC ( 9 9)( SP. S- HC 1319.864) }( 6P. Chiordna (67-74-) - ( 7P. 4,4'-DO 1' (0-29-) }( 8P: 4,4'-DDE (7 65-9) ( 9P, 4,4'-DDD (72 }( 10P, Diaidrin (60.57-1) }( I IP. a-Endotutta## (11-29-7) -{ 12P+. Q-Enddautfan } 9uifata (1 17.8): 14P. Endrin (72-20-8) 16P. Endrin' Ai ydo (7 1.93,4) 16P. Holptachlor x (7 8) EPA Form 3510-2C (Rev, 2-86) PAGE V-8 CONTINUE ON PAGE VW9 :ONTTINUE' 3 FROM PAGE V-8 t. Pd�at1 PANT x wt crrc tx AND G AS b se Nr sr wt {rp wanes : (xd; w+n s5 :a=• (t0 wan�.s TSE *a:: r"i •. •.••, '" itR rWw;f TiG *j ___ _ __ C{YWGi Neu Jett iYaN ¢ 4'tWY 6Wt ri dN T #5wC! WritntJa W. t#YRr(drN dCi MS Fii. C&60N -- PESTICIDES (continued) 17P. Hop2echlor E pox ids (1 24-67-3) }( 18P. PCB-1242 (53469- 1-9) 19P. PCB-1254 (11097.69.1 ) 20P. PCB-1221 Zip. PCB-1232 (11141-16> 22P, PCB,1248 (12672 29. ) P. PC13-1260 (11 9-82.5) 2 P. PCB 1016 (1274-11-2) 2 P. ToxePhene (8 1.35-2) PAGE V- ITEM Y.1) CONTINUED I o POLLiJT- -ANT Anici CAS rii.C3. dl+'<Kli®i8i�jPw7 g. Nitrogen, {asTotal NlCirganlc 2, MARK'X' 8, err:- acne; PRO^ % X FROM I?, ea F.- t<pp_vrsa A"- bt.:wv FRONT .r.• ..�._ 8. MAXIMUM ITAILY _.... ..... �r�..,..... 424 89 _ ...._.�. ......_..®. VALUE ^.......®..._....._....._ ..._ ! TeAi" 113 2 3. b MAXIM M 3r} iti cJJ+ndtni) .._ f„„#»wr Y..w Yren (,rsiy EFFLUENT p Y: VAC.0 ..0 t i#I. hi ltSS C.LC?N + T M AI <l .A.eIFIT. ....�a : ! t TtY kirt r!rTw t'C1H t VAI..UE .....�. y. . l?I.!#e 1455 Ef, ha to C>t ANAL,:: Y�rE C 1 4, UNITS a. CONC1EN_ 3"#'7 nr.'T Rt'p h# mg/L m L__ : Ie. MASS l b/Day W i b/Day MN -003' 5. INTAKE 8 I t7NC Ae/Etint _.,... "� ._'__ � (r'�ll.e rtt A#:n TtteN <. 08 � .13 (ipri aFr,d) Tt: 6xM c Wnt.ltE Y...ff _ """` i ) "A- <1, 562 2,538 ANAL. Y„`I. s .... 1 1 h. tiff and Gromos X I. PhoaAhtlrus -" ^ io�t72 t Total X 7.0 1 mg/L - - lb/Day <.02 <390 1 J. Radioactivity _ ----- TotallPbat X <.3 X 1 pC1/L X <.4 X 1. Tot*( X 1 .2+3. 6 X 1 pCi/L X 2.1-!~< X 1 (3I Radium, Total X X 1 pC1/L X <1.5 X 1 2) Radius' X <.1 X 1 pCi/L X, 1.4±..4 X 1 (804) X 29 8 1 m /L lb/Day 9.6 187,462 1 iiMpq--7918) 1. fed $)fiid# X <1 <.3 1 mg/L lb/Day <1 <19, 527 1 itit. $U r.cs X 3 8 1` m /L g lb/Da y < <39,05 (14285.45-3) to. surt nts X <.2 <.05 1 mg/L lb/Day <.2 <3,905 1 o. Aluminum, - --_ Total X 66 2 1 mg/L l b/Day 11,912 1 (7429-90-5) .61 arum.Total ~- X .04 .01 1 mg/L l b/Day 390 1 (7440 3) .02 q• orcm, t otat X .91 .2 1. m /L - l b/Day .11 2,148 1 •tx) _ Totaal #' X I <.1 <.03i v 1 Ong/L 1b/Day v___ <.1 . <1,9 1 a iron. Total trams ss .51 1 1 mg/L 1 b/Day .3 5,858urn 1 ~total X 3.6 1 1 m/L l b/Day 1.2 23,433 1 (7439.95-4) v u. Molybdenum. Total X .08 .02 1 mg/L l b/Day .07 1,367 1 a� v. Totain°erlasa> X 04 .01. 1 mg /L 1b/Day .02 390 1 (74 -sly-s) w. Tin. Total (7440-31-5) X 2.0 5 1 g/L 1b/Day 1.2 23,433 1 x. Titanitini, ono 'si X . 0 008 1 m /L 1 b/Day . 02 1: 0 EPA Form 810-2C (Rev. -85) PACE W-7 CONTINUE ON PAGE it - EPA LCL NUMBER (COPY front Item I otporm 1) OUTFALL NUMBER form Approved NCO024392 003 OM8 No, 2040-0086 CONTINUED FROM PAGE 3 OF FORM 2-C Aripjrovidexprres 7 31-88 PART C - Ifyou are a primary industry andilosoutfall contains process wastewater, refer to Table 2c-2 in the instructions redetermine which of the GC/MS fractions you must test for. Mark "X" incolumn 2-a for all such GC/MS fractions that apply to your industry and tot ALL toxic metals, cyanides, and total phonols. If you are not required to mark column 2-a I'secondalry indUSItte.l. nonptocOSS wastewater outfalls, andnonrequited 6CIA4S fractions), mark "X" in column 2-b for each pollutant you know or have reason to believe is present, Mark "X'* in column 2,c for each pollutant you believe is absent� If you mark column 2a forany pollutant, you must provide the results of at least one analysis for that pollutant. if you ma(kcolumn 2bfor any pollutant, you must provide the results of at least orre analysis for that pollutant if you know or have reason to believe it will be discharged in concentrations of 10 ppl) or greater, Ifyou mark colunin 2b for acrolem, acrylonitrile, 2,4 dinittophonol, or 2-methyl-4, 6 dinitrophenol, you must provide the results of at least one analysis for each of these pollutants whichyou know o( have reason to believe thatyou discharge in cunceno abortsof 100ppbor greater, Otherwise, forpollutants forwhich you tuarli,column 2b, you must either submit at least one analystsof brieflydescttbe the reasons thepollutant isexpectedto budischaiqud Note that there are 7 pages to this part; please review each carefully. Complete one table rall 7tragesi for each outialt, See instructions for additional details and requirements. I.POLLUTANTJ MARK 'X* 3. EFFLUENT 4. UNITS 5. INTAKE foptional) AND CAS lu. MAXiMPM 3? C,LONG T G V ALUE a� LONG TE14M at MAXIMUM OAILY VALUE Y VALUE t NO.Or tl)� NO 0 ANAL, Li, M ASS —LU —E A N A L NUM p eI d CONCEW (it atmilable) —6-F YSES TRATION M.us YSES METALS, CYANIDE, AND TOTAL PHENOLS 1tvi Antimony, Total (7440-36 0) X 2M. Arsenic, Total (7440�38-2I X 3M. Sorylliur", Total, 7440-41-7) AM. Cadmium, Total (7440,43-9) X — ------- -- 5M, Chromium, Total (7440A7-3) X 6W Ccm Total I � a 7440- -8) X 7M. Load, Total (7439-92-1) X illyl. Mercury, Total (7439-97-6) X 9M. Nickel, Total (7440-02-0) X I OM. Selenium. Total (7782-49�2) X I I M, Silver, Total (7440-22-4) X 12M. Thallium, X Total (7440-28-0) 13M. Zinc, Total X (7440-666) 14M. Cyanide, Total (57-12-5r ISM, Phervots, Total — ------------- DIOXIN ESCRISE RESULTS lorodit)fmzo t ox iii (1764 0' X NEGATIVE EPA Form 3510-2C (Rev, 2-85) PAGE V- CONTINUE ON REVERSE an" rue ectnadlr MN -003 a LUTANT 1 CAS vr8�R :AACrION— 2, at�eat +ajt wa• et++w+ VOLATWE MARK % r�• +ava. p«�. ittn+t W c.+ee- a.+Iva ��, ow"T COMPOUNDS S. MAXIMUM CSw9i VALUE (c} (a) #+nss C#t+C i.N$MJ1teOM+ 3. , MXX6 M +8t�f61�Qd1@ :r+r YC KkfiC aENtN AtiiaN EFFLUENT p at. VALUE q/► (ar'e+wss gd �g g� C.Lot4G T VALUE 1 #trOtdQ &E rar r�r Gi+MC KNtIq lAtlON t8. NO.c?r' ANAG.- vsEs C UNITS S. Ci GEN- TRATION b MASS S. INTAKE a LONG (®I eawCa±ra T+PAt+Q14 fopticsrall tER O b. NO.ti i» ANAL; rar �+x.. yeas xr motor," r on x )ride rob*nzons V fl 7) rthene t }` rootbane ! ,, hroro- -- rt Ether i} drotor Moro; wthene r- i` •D)ohroro- PS- . } -Olchroro- 107.06-2 j (76•35-4) s7-1i7-5} (khkwo- 642.76.41 ey(benrone a} ^thyl (7a•s.9) �thr anr_c to®x Ct)NTINUE ON PAGE I CONTINUED OROM PAGF-V-141 I.POLLUTANT ,129V. Trfthforo- othylone (1 -01-6) SA� 2 4-Dinkro- phon�l (51-28-5) '6A. 2-Nitroph -= anot i SA� P.Chloro.M. (69-50-7) I OA, Pheno 0 08-95 2) W- S. MAXIMUM DAILY VALUE b.MAXIMIM3, 0,LONGT M#,Vr apa?a?,�)V VALUE ova �VALUE 0 W Cali" --Eoftck"THATION POUNDS (continued) NOS toved 7S 4 MASS 1I.INTAKE S, LON --A-VAIL" fit Coke*"- (optional) TERM Lug fit bmo,o ANAL - Yoe* CONTINOED-FROM T14E FRONT MNS-003 1. POLLUTANT 2-MARK'X' 3. CFrLUENT 4, UNITS 5. INTAKE loptionall ANDCAS NUM BIER &ire* �J� %. I - $r. MAXIMUM DAILY VALUE M YVA au o e CZ5NE VALVE I No ' or 0, LONG TERM b - No ' 0 040 ". I o".. *W."r I I OWN* ^"A$-- F. VS S 4� CONCEW T"ATION b� M^$S —AVAU"Ag W9-- (of Mkos ANAL- YSES GCIMS FRACTION — FIASENEUTRAL COMPOUNDS IW Aconsphthens (83-32-9) 20. Atonaphtylone (200-96-8) 38. Anthrecone (120-12-7) 49. SontIdIne (92-87-5) SW Sonzo (a) Anthrocano (56-56-3) as. sanzo (a) Pyrone (50-3243) 78. 3,4-Senzo- fluoranthane (205-99-21 I as, sonzo (ghf) perylons, (191-24-2) 90. sonzo Fk—) F tuorenthone (207-08-9) 108. at$ (Fc—hl.ro- othoxy) Methane 1113. 819 (2-Chloro- ethyl) Ether (111-44-4) l2w sit p-ChAarmo. pwyV Ether (102-WI) 138. Bit (2-Sthyl- hexyl) Phtholato (117-81-7) phonylPhonyt Ether (101-55-3) Ise. Flutyl senryl Phtholate (85-68-71, 168. 2-Chloro- naphthalene (91-58-7) 178. 4-Chloro- phonylPhonVi Ether (7005-72 3) 108. Chryseoe (2111-01-9) X lw-wbenzo- Art,threcone J53-70-3) 200.1,2-Dichloro- benzene (95-50-1) 218.1,3-01chloro- bonrono (541-73-1 16� EPA Form 3510-2C (Rev, 2-85) PAGE V-6 CONTINUE ON PAGE V foon Ap>puazved �.. "EPA #105 NUMSE# (copy ; front Item I of Form I) DUTFAL:L NUMBER OM11 No 2040 8: NC4 Apparrrvalexjxres 7 31-88 CONTINUED FROM PAGE V-6 t. PCILLU'TANT z MARK x, 3; EFFLUENT ENT . UNITS 5. INTAKE toptsonal/ ANDCAS NUMBER area exr ir.: ar- +�. ra a. MAXIMUM DAILY` VALUE li.'M XIM 9`I LAj1.Y VALUE 8 aurxect a c.i. NC. f M iil� tAl U at+ Uie tl.i r,c>,ct a CONCEN' a r,.rsw t'�raM tlre4 (if available) crc°re+wta aav� arae aA•V• •nax _ I'} Ix1 *seas co,r rash wwtijN iel cure*.. a,:wswesevra la} ee s �`} c. aaea&erarsanroeone:. la} wet ANaL- YSt=S TRATION te. A4 tt} c teca w- YFt eetreAra ANAL' Itl wsxsa YRE GC' FRACTION — 8 _ E/NEUTRAL COMPOUNDS (continued' 228, I A-Dichloro- borexene (1; .7 _ 23W 3,3'-Dichloro banzld[n* (91-94.1) 248, Diethyl Phthalate (84.66-2) 258. Dimethyl Phthalate (131-11 3) 28. DI-N-Butyl Phthalate j (84.74 2) jt 278. 2,4-DAnitro- toluene (11.14.2 ) }{ 288, 2,6-Dinitro- toluene (606 20.2)( 298. DA-N-CFctyi Phthalate x tl176401 308. 1,24)iphanyi- hydrazine fas Azo- x benzene) 022.661 31 B. F luoranthena t2 .gip 328, Fluorena x (86-73-7) nxarr i11.7a.tA 3,i8 Fiexm chlot utrtlrr adiane (87.68 3)' 358. liexachtoro, cyclopentediene (77.41.4) 8. Nexechloro- }( *then* (67-72-1) 370.Ind®no (,2,3-cd) Pyri n t 1193.39-5) 8.lsophoroe x (78 59.1) 398, Naphthalene (91- 0-3)' 408 Nltrobenzell ag (98 95 3) , R 418, N-Nitro- sodiAnethylaroina (62-75 9) 428. N-Nitrosucii- N •Propylarnina (621-64 7) CONiINUEtir FROM THE FRONT I. POLLUTA9NT 2 MArrK 'X' 3 EI`I`I_Ui:N7 4 UNITS . _ ,:-_ 5 1N I AKL- , _,: AND CAS :. -,...-._. _.... _. ._... _ .. NUMBEF2 Fxx+er b wt t rbe A. MAXOMOM DAILY ._ ._ VALCJ 6. 1, MAXIM M�3 f9 (#9 {li gypp Y VALLrr: £dax' Y i't i _ Ji C LONG tk, M I4 (7 f1#�d#li4t F ...... G. VALOC f' / it racy xsi .._,... r+ COWL N .. .t 9 ON . / V4ilF +.t It 9aaee V RLt1k t tlA+. L6PN00 dfF 4Px we ♦ixa nrr Ir(#J#�otlable) �,++ a x •rtix l k { l,l„nM I i I$i +i w+yn> '} AN Ai r r#rArr«r# it F1Ati*` a ' ( ( E y'A GCANS FRACTION — BASK/NEUTRAL COMPOUNOS+ Ix'+rr+ldrtJer+il 438. N Nitro- rodiphenviernine (88 30-6) S. (n rtho"nthrene: 458. Pyrsns TO- chloroboort WAA FRACTION -- PESTICIOES 1P. Aldrin i '. -2I 2P. -8HC i319- - } 3P. •BHC (31i -885 7) 4P. 8HC (be 9-91 SP. 6>8HC (319.86-8) } 6P Chlordeoe (61-74 9) }( 7P. 4,4'-ODT (72.66-9) 9P; 4,4 -000 (72-64.8) }� lop, Dieldrin Ill 11P. a Endorulten (115-29. 7) i{ 12P. P-EndosuIten i 11-29-71{ 1 )'. Endosuliere uiirtt( I1_ 1-07 81 14P. Endriti }� (72.20.8) 15P. Endrin Aidehyde }( 47421.03-41 1SP. Hopt hior (76.44-81 EPA Form 3510-2C (Rev. 2.85) PAGE Va8 CONTINUE ON PAGE V-3' forin Apprt orn Itent I of Forin OUTFALL NUi�OEW­­ OMH No 21 M App oval e, 2 003 4. UN#TS L Epoxide x 18P, PCB- 1242 (53469-21.9) 19P. PC B- 1254 x (11097-69-1) 20P. PCB-1221 x (11104-28-2) 2 IP, PCO, 1232 x 22P, PC8-1248 x (12672-29-6) 23PPCB-1260 x (11090-82-5) 24P. PCB,1016 x (12674-11-2) P. Taxaph-2 .. x (8006 3 1- PAGE V-9 MNS-004 NTINUED FROM FRONT 1. POLLUT- 2. MARK 3, CFFLbrNT 4, UNITS 5, INTAKE (tphotfal) ANT AND 4, -8 W CAS N0. fMVCCLWVf,0 at MAXIMUM 0AILY - VALUE b MAXI Y 'VALUE (TIP., M j� No 0 F ANAL, CONCEN. A hMASS VIR,"t I E 6, Noov. ANAL - pot* 0- fitavallable) S T f, I � N ....... III MASS Y.;t Ttl A I t (IN [F14 9. Nitrogen, Total Organic x 1.3 .06 1 mg/L I b/Day <. 08 <1,562 1 h. and ax 5 1 mg/L I b/Day .13 2,538 1 area" .2 1. Phospho u (as Pl. Total x 1 .005 1 mg/L 1 b/Day <. 02 <390 1 (7723-14,0) ). Radioactivity t I) alpha, X 11000±640 X 1 pCi/L x <.4 x 1 Total (2) sots, Total x 600000±3700 X 1 pCi/L x 2.1±.6 x 1 (3) Radium, 33±3 x 1 pCi/L x <1.5 x Total (4) Ascifur" x 13.2±6.6 x 1 pCi/L x 1.4±.4 x 1 226, Total fat $yyy04) x <1 <.05 1 mg/L lb/Day 9.6 187,462 1 1. glgl.iii x <1 <.05 1 mg/L lb/Day <1 <19,527 1 (at SO,?) x <2 <.1 1 mg/L lb/Day <2 <39,055 1 (142§5-45-3) n. Surfactants x <.1 <.005 1 mg/L lb/Day <.2 <3,905 1 o. Aluminum, Total x <.4 <.02 1 mg/L lb/Day .61 11,912 1 (7429-60-5) P. Ts-rTu-i". Total x <.1 <.005 1 mg/L lb/Day .02 390 1 (7440-39-3) q. on, Total x 5.3 .3 1 mg/L lb/Day .11 2,148 1 (7"0-424) r. CO Total ME, x <.05 <.002 1 mg/L lb/Day <A <1,953 1 (7"0-48-4) a. Iran, Total 1 mg/L lb/Day .3 5,858 1 .3 .02 Total x .15 .008 1 mg/L lb/Day 1.2 23,433 1 t7439-95-4) u. MolVbdonum, Total X <.2 <.01 1 mg/L lb/Day .07 1,367 1 (7439-98-7) Total x <.02 <.001 1 mg/L lb/Day .02 390 1 17439-96-5) x <1 <.05 1 mg/L lb/Day 1.2 23,433 1 urn, Total x Total x [E(7440�312-6) -- <1 <. < - 0 1 mg/L lb/Day A2 7177�3 90 1 I :.� EPA Form 3510-2C (Rev. 2.85) PAGEV-z CONTINUE ON PAGE V EPA t.D : NUMBER (copy jrutrt Item 1 of Forrit t) OUTFALL NUMBER Fctrnt Approved N0024392 �4 �or�Itt tv�t expires t �e� CONTINUED FROM PAGE OF FORM -C M u are a primary industryand this outfall contains process wastewater, refer to Table 2cm2 in the instructions to determine which of the GCJMS fractions you mast test fear. Mark"X" its column ear all such GC/MS fractions that apply to your industry and fur ALL toxic ntetaals, cyanides, and total phenols. If you are not requ red to mark column 2-a(secondary industries. nonprocesewatr;r oratfalls, ant!nonre uiredGCIAA tractions), tnark "X' in column 2-ta for each pollutant you know or have reason to believe is present. Mark -X- in column -c for each pollutant you ve is absent. If you mark column 2a for any pollutant, you rrtust f trovide the results of at least one aanalysis fear that pollutant. if yoga mark colutnn 2b for any pollutant, you must provide the results least cane analysis for that pollutant if you know cat have reason to believe it will be discharged in concentrations of 1€} ppl, or greater Ifyou mark column 2b for acrotern, acrylonitrite, 2,of henol, or 2-methyt-4, 6 dinitrophenot, you must provide the results of at least one analysis for each of these pollutants which you know or have reason to believe that you discharge in cuncenti abonsof 100ppbor greater. Otherwise, for pollutants for which you rtrark eolumn 2b, you must either submit at least one analysis or hrrefly desctibe the reasons the pollutant is expected tp be dischauycad Note that there are 7 pages to this part; please teviow each carefully. Complete one table iaa11 pages) for each o uttalP See instructions for additional details and requirements, t. P01..LUTANT -4 �. MARK 'X' 3, EFFLUENT 4. UNITS 5. INTAKE (iiptfutialj AND CAS - __ " " ba MA11tiM4,Nr 3 µ'Y VALUE C.LO G"B_ Nr. G..VA-t�ue Ar,N<).a�r a. LONG TERM tt.NCa r3F +t �[ St t5 Nt t�, ial War.�MAxirar.rM DAILY StALta. NUMBER auee .t via _ _ (ij ,atirttlt d D fd urv,tid riite'$ " CONCIEN A— y . ANAL' tt MASS """'�" ANAL-. (itavaitutil 1 `a ` '"`+<t ltl (41 MASu l'1 (,} All (A} (.} uSt S TRATION it) cortcxr,- t } txas YSES � tc)ka..i taYN)t7tbtd £t5 tr rl ttckN .a NC el Y'HAtAV+*+ Ttrt ARRICSM METALS, CYANIDE, AND TOTAL PHENOLS t43Toaf(74os of X ;. <.01 1 m /L lb/Day <. 6 <11 716 1 (74do-` Total 3B 2}X <10 <.0005 1 g/L l b/Day <1 <20 1 3M. BervIlluin, Total, 744o- 17I X <.01 < 0005 1 mg/L lb/Day .002 39 1 Toall17440 -9) X a01 < 0005 1 m /L lb/Day .01 195 1 Chromium, a .3) <. 05 < 002 1 m /L l b/Day 04 781 1 BM: Copper, Total (7 4o-50.0) X .03 001. 1 mt /L lb/Day .03 586 1 tal 4 Load, 1) X <. <-01 1 mg L lb/Day <.08 <1,562 1 SM. Mercury, Total tX <. 0000 1 pg/L lb/Day <. I <2 1. t744a'aa0I.Total X <.05 <.002 1 mg/L lb/Day <.04 <781 1 72410M.o (7si;2) X <10 <. 0005 1 pg/L l b/Day <2 <39 ,1 (7 Silver, T�atel X <.01 < 0005 1 mtg/L lb/Day <.04 <781 1. Tote (744utn, .1 <.005 , 1 ` m /L lb/Da <.5 <9,764 1 Total f7aaU�28 0l J y 13M (744 6-6)Total X 09 00 1 m /L l b/Da 0 390 1 (7+tC0-i3�Bl � Y 14 .Cyanide, Total (57.12.6) X 2 01 1 mg/L lb/Day <.02 <390 1 ISM, Pltenrit , X < m 001 < . 00005 1 mg/L l b/Day <.005 < 8 1 TCriai DIOXIN t, ,7,8 Tetra CiE SCRIDE RESULTS sitioresulburazo it tatrixin (17640, al X NEGATIVE EPA Form 3510-2C tRev. 2-85) PAGE v-3 CONTINUE ON REVERSE CONTINUED FROM THE FRONT MNS-004 1.POLLUTANT 2.MAOK W 3. EFFLUENT 4� UNITS S. INTAKE (op4tionall AND CAS NUMB aTxrT to r4K• G Wit- , rasa serve 1"a a. MA iMUM DAILY VALUE ° M! l pp Y'VALUE atta6ab� C.LONG T M A t VALUE. aStaiicr 0 cS. NCi.itiS` ANAL- a �f#GEN• b, MASS W LONGTERM : to Net.c>f ANAL- yyp. .§p! �pAR ♦Mr• wbW 'OAUdN• 1&t9#T t MT a 14 GOHC'E MTr ATIatY It) MASS f co"es"THAyloft �I� MARt : �f 8� Mh4Y GtiMNCr NTNAT1iEM s PATION �1` Ci`nNC 'N- TNATt€AN �8� MA6► ----- Y ES ' OCAM FRACTION —VOLATILE C UND$ _ .4,, X <5 <.0002 1 g/L 1 /Day <5 <98 1 2*1 1iYl*,ta: 1 g/L 1 b/Day <5 90 1 3�1,W9 X <1 <.00005 1 pg/L 1b/Day <1 <20 1 o u ro dYs�yl p e X N & 9 PO x x x x x (540 •1) (M 2)oform X 1 .00005 1 fag/L 1b/Day <1 <20 1 TV. Carbon etroohlorlde X <1 <.00 05 1 pg/L 1 /Day <1 <20 1 {68-23.5) V. Chloro mans (1 -90.7) X <1 <.00005 1 pg L 1b/Day <1 <20 1 $V. Chlorodl- brdmomethane X <1 <.00005 1 g/pL 1b/Day <1 <20 1 (1 4-4$-1) $V.Chlo ane .b { .` X <2 <.0001 1 pg/L 1b/Day <2 <3 1 OV, 2-Chloro othyhrloyl Ether x <1 <. 0000 1 pg L 1 b/Day <1 <20 1 41 Iti-75-$) _ __ _ {$ Chloroform X <1 <.00005 1 pg/L 1b/Day <1 <20 1. 12V. - lthforo- broom athane X <1 <.00005 1 g L 1b/Day <1 <20 1 {7s•2ia4) 13 i. Dlehfero• enunethane /A } } x{ } x xdifl 14V.1,1-Olchloro' X <1 <.`00005 1 pg/L 1b/Day <1 <20 1 • (75-34-3) 16V. t42-Dlchlr 1 <.00005 1 it /L 1b/D <1 <20 1 oth" (17-0-2) hloro- X <1 <.00005; 1 erg/L 1 b/Day <1 <20' 1 wthvia'nee {1.° sat 4.2-Dlc87-5) X <1 <. 00005. 1 g /L 1 b/Da y <1 <20 1 aarapono (78-�t7-5) rop lNV.Ww( ` c�iz-��-a) v� <1 <.00005 1 g�/L 1b/Day <1 <20 1 4)l ten:anr X <1 <. 00005 1 pgf L 1 b/Day < 1. <20 1 (100 i 20*Moth l flraIvItft t14-$3-9) X <`2 <.0001 1 g/L 1b/Day < 2 < 9 vl 3) X . 1 g/LCh 1 b/Day <1 <20 1 01 EPA Form 510- D (Rev. 2-86) PAGE V- CONTINUE ON PAGE V 1,1,2,2-Tetra- rroathane 4-5 ) Tetrachloro- lona (127-18-41 M 1,1,1-Tri- eloroothane p1-Cs5^6) 9V; 1,1,2^Tri» iloroathane P9.00.6) 9V, Trlchloro- thylana (79.01.6) 6A. 2-N i tropheo0l (8-75.5) torm Approved EPA 9.0, NUMBER (COPY 1'rorn IlCol I of Form 1) OU rF'ALt- HUM BAR OMB No 2040-0086 P AC F v a N0002492 Q0 Approval expires 7.3I.88 x, MAR *X' 3. EFFLUENT 4. UNITS S. INTAKE (Op#fts»�lj r},sr kN4 b aI- 4k.Vi C Ae• 4.irVii #•MA�t.tMttM.t`AtL "VALt6E b. MAXIM M 5�iy a i2tMEitQblf') dr�1y/� tY t6At UE c.LOiVG T M o.,.,larbld" Ay }p�' ,VALUE allo,oF� CONCEW e. �aNCs TERM b,tio,or Re:- fiklOR• wRmw ♦#NT Aw.. ffi6NT g (4) G CTN&4.NYR ATiUN lE):MATrY 1:41 GiJNCk NYRATk4N ii)MAbo (.tl) GIiN&CN7RAT#0N ($l ►oAYt ANAL- YJES TRAT#094 b. MASSY p {e) CG}}eC AM� FRA reON (g) keAif AMAL- Yse* VOLATILE COMPOUNDS (Continued) <1 <.00005 1 pg/L lb/Day <1 <20 1 X <1 <.00005 1 pg/L lb/Day <1 <20 1 X <1 <.00005 1 pg/L lb/Day <1 <20 1 X <1 <.00005 1 pg/L lb/Day <1 <20 1 X <1 <.00005 1. pg/L lb/Day <1 <20 1 X <1 <.00005 1 pg/L lb/Day <1 <20 1 X <1 <.00005 1pg/L lb/Day <1 <0 1 X <1 <.00005 1 pg/L lb/Day <1 <20 1 X N/A X *1... X X X. X X X 1 <2 <.0001 1 pg/L lb/Day <2 < 9 1 ACID COMPOUNDS X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1 pg/L lb/Day <10 <195 1. X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1pg/L lb/Day <10 <195 1 X <10 <.000 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <.0005 1 pg/L lb/Day <10 <195 1 X <10 <,0005 1 pg/L lb/Day <10 <195 1 X <10 <}0005 1 A 1194 1b%Da <10 <195 1 YTINOEn FROM THE FRONT MNS-004 ARMSIMARMILK Mom M1111-00. ME m Aconsphthono 1-32-9) x <10 <. 0005 1 _Lb/D jy_ <10 < 195 1 AcensphtVIons 0-964) x <10 <. 0005 --1 _tq/L jt/Day <10 <195----" Anthrocens ;0-12_7) x <10 <. 0005 lb/D,av —<10 <195 1 sonzidine x <20 <. 001 1 1 b <20 <9 30 1 so"Zo -co, throcon" x <10 <. 0005 1 pg/L 1 b/Day < 10 <195 1 Benno (a) ,one (60-32-8) x <10 <. 0005 1 pg/L I b/D f <10 <195 1 orantheme M-99-2) x <10 <. 0005 1 pg/L I b/Day < 10 <195 1 Senzo (ehl) lon* 11-24-2) x -- -- — <10 -- — <. 0005 — 1 pg/L I b/Day <10 <195 1 , sionto Fkj— ---- ---- - --- - --- — lorenthon" x <10 <. 0005 1 pg/L I b/Day <10 <195 1 81# (2-Chloro- bxy) Mothano <10 <. 0005 1 pg/L I b/Day <10 <195 1 3. sit afhlowo- �I) Sthor 1-44-4) x <10 <. 0005 1pg/L 1 b/Day < 10 <195 1 Bit f2-ctdwv*#- YljEftw(IO2-WI) x <.0005 1— pg/L 1 b/Day <10 <195 1 5. Bit (2-Fthyl- --<10 ryl) phtholate x <10 <. 0005 1 pg/L I b/Day <10 <195 1 R. 4-aromo- onyl phonyl for (101-55-3) x <10 <. 0005 1 pg/L I b/Day <10 <195 1 0. Butyl senzyl tholate (86.68-7 x <10 < - 0005 1 A 1 b/Day <10 <195 1 x <10 <. 0005 1 pg/L jA/Da <10 < 195 1 B. 4-Chloto- NnyfPhonyt lot (70M72-3) x <10 <. 0005" <10 <195 1 B. Chrysene IR-01.9) x <10 <. 000 1<10 <195 1 S. Wbonzo (a,h) F 1-10-3)ithrecono x <10 — -,-, - I,------.,-- <. 0005 — 1 A /Da <10 <195 1 B. 1,2-0;cbloro- _— — nZeno (95-50-1) x <10 <. 0005 /L _11b/Day <10 <195 1 S. 1,3-01chloro- 1 nz I isno (541-73-1 x <10 <. 0005 1 pg/L lb/Day <10 1 <195 1 k Form 3510-2C (Rev. 2-85) PAGE V-6 CONTINUE ON PAGE V I ml ON*INUfU FROM THE FRONT I. POLLUTANT 2, MA"K 'X' 3, EFFLUENT 4, UNITS AND CAS N UMBER h .. L WE' h- *-- , "� iw.0 V IF r ILY VALUE MAXIMlymp 3,?,o Y VALUE 'PAt: *.MAXIMUM0A Pat C A N A b, MASS (it "&I W A I E-ri: yl�lf GC/MS FRACTION — BASE/NEUTRAL COMPOUNDS (cmitimsed) 438. N-NItro- todiph*ny#emfno f86*30-6) 440, Phonenthrone 185-01-8) 458. Pyrono (129-MO) yy 460. 1,2,4 - Fr—l- thforobonsono _t120-82-1)_ QC/MS FRACTION — PESTICIDES IP. Aldrin (309-00-2) 2p. a-amC 319-84-6) lb/T),qv 3PlqHC (31 -85-7)—IhLDAY- 4P.1-SHC (So 0-9) 1 jWdL lb/Day 5P. S-Omc 019-86.8)' 6P. Chlordone (61-74-9) X <20 < I uR/L lb/Dav 7P. 4.4*-DDT f50-29-3) x <20 OP. 4,4'-DDE (72-65-9) 9P. 4,4'-000 (72-64-8) <20 <. 001 lb Da 10P01oldrin (60-57-1) --X— --<20-- —K-01— 'I IP, a-Endoswulfan V 12P. P-Enclosuffen (115.29-7) < 13P. EndosurFf—s;n— Su0sto (1031-07-8) Y <20 < ou- 14P. endrin (12-20a) --<-2D- --<,-0-0-1-. 15P. Endrin Aldohvdo 47421.93-4) I op> Hoptochlor �(16-44-8) EPA Form 3510-2C (Rev. 2-85) PAGE V-0 CONTINUE ON PAGE V-9 s s t • '"r: «7.« 'Y:rl :.. ""+MAY" e e r :. «• a OWN i _• fff B-1016 flit i PAGE V.g MN fEPA #s ' Wu M 615 R (Copy trom lie"I i tr%Fc>rrrr tj for Approved WWC1 CHARGE POLLUTANT 2.EFFLUENT MAXIMUM DAILY ALUE 0 LON ----M-455; --TrrER VAL Irm a t, JIM a. 'Wbirink) TU14—M b, No, OF 1. a� -1 ova e) If (1, NO, OF ANALYSES a, CONCEW ASS b. m (2) MASS ANALYSES (2) AS. lel M A— TRATION CONOC.".AT§01S W. —0.0chernical Oxygen Demand 2.0 20 1 mg/L lb/Day 1 19 527 1 b, Chemical Oxygen Demand 8.4 84 1 mg/L lb/Day <5 <97,636 1 c. Total Organic Carbon (7'()C) 2.6 26 1 mg/L lb/Day 1.8 35,149 1 c[, Total Solids (TSS)Suspended <4 <40 1 mg/L lb/Day <4 <78,109 1 9. Ammonia (as N) .18 2 1 mg/L lb/Day .07 1,367 1 VALUE VALUE VALUE VALkV I. Flow 1.2 2 MGD X 2,340 CR 9. Temperature 0C VALUE (winter) h. Temperature VALUE 'VALUE 0C VALUE 21 faurnmert MINIMUM IMAXIMUM MINIMUM— i. pH 1 00.2 PARTS- Mark ""X" in column 2-a for each pollutant you know or an which is limited either directly, or indirectly but expressly,hich ark column 2a, you must provide quantitative data or an exptaraation of their presence it youi discharge. Complete one table for each outfall. See the instructions for<additionai details and nts. I.POLLUT- 2, MARK 'X' 3, EFFLUENT A. UNITS 5, INTAKE (optional) ANT AND a, —a . MAXIMUM DAILY VALUE b. MAXIM M 3,?, (11 aval, VjAY VALUE a e C.LONG T M VALUE aVa a ("O� OF a, LONCEW b, MASS AVERAGE VALUE — --TZT- tX NO. OF ANA L- CAS NO LIEV�L (if available*) (2) MASS CONC*.NTAATWON (Z) MASS MASS ANAL- YSES -$;t^TlOr4 CONCENTR^TtON MASS YSES CONCENTRATION a. Bromide X <1 1 mg/L lb/Day <.I <1,953 1 (24969-67-9) b, Chlroeine X 1 mg/L lb/Day .05 976 1 Total Frvl�ual .05 .5 t. Color X 5 X I PCU X <5 X 1 No./ d. Fecal X 5 X 1 X 5 X 1 Coliform e, F'l u For i d a �8.. X <1 1 mg/L lb/Day <.1 <1,953 1 169B4 48-SY ( '9 If. Nitrate — X 2 1 mg/L 1'b/Day 1 1,953 1 Nitrite (as N) .21 EPA Form 3510-2C (Rev. 2-85) PAGE V-1 CONTINUE ON REVERSE "TFM V-6 CONTINUED FROM FRONT MNS -00 I.L T +t hi rt we � 3 I" F" F L it F• tU t ._ ....... :. . ......�,.. _ .,-.......;. ___._ :..... AWT A GA'F . MAXIMUM DAILY VALUE0. "YALU t v> t`I5 (4( Rttl`C.l.�ixl. tf r(., m ANl .a PS!.`fFrlea !P } :` ...N_t...+.i_.tt. Ft,i Fc.N. a (if ovailable) fia•Preer±n t .em4 e5 tf { . !Yh f M _{....., q: A .� #�fSt "k i } Y ,1 Total Organicx (as NJ 31 3 y 1 f y b D iJ/ I,I C . LJG? 08 y 2 ..[. y G. y .L and h, Groom (fir .13 1 1 mg/L i b/Day .13 2,538 1 i, Ix),rhorus fog T Total . 06 1 m / L 1 b/Da y < » 02 < 390 1 17 73 14 Ol 1. Radioactivity (1 ) Alpha, Total x <. 8 x 1 pCin x <. 4 x 1 Tottaleta, x 3. 9±1. 2 x 1 07 % x 2.1±. x 1 Total Radium, < . 5 X 1 01 / x <1. 5 x 1 6, t l' x<.1x 1 pCiA x 1» 4±. 4 x 1 So r` 04) x 6.9 69 1 g/L lb/Day 9.6 187,462 1 R 14St1S-7J•t1l 1. Sulfide r) x <1 <10 1 mg/L lb/Day <1 <19,527 1 c7ex <2 <20 1 m /L g lb/Day<2 <39,055 1 (14 65-46-3) n. Surfactonts x <.2 <2 1 mg/L lb/Day <.2 <3,905 1 b. A Uin nuara, Total x 47 5 1 m /L g i b/Da .61 11,912 1 (74 9.90.5) P. Total x .02 .2 1 mg/L lb/Day .02 390 1 � 3t .. ...... _.._ ».__... _ _. ..., _ _.. _.W __..v... Total T T .19 1 mg/L lb/Day .11 2,148 1 (144t -8) Total x <.1 <1 1 mg L lb/Day <.1 <1,9 1 (7 0-40-4) R Iron, Total t74"-811- > »12 1 1 mg/L lb/Day ,858 1 Total 'x 1.4 14 1 mg/Llb/Day 1.2 23,433 1 I r4�g-g11.41 u, Molybdenum, Total x .08 .8 1 mg/L lb/Day .07 1,367 1 t743f1•98} Total x .05 .5 1 mg/L lb/Day .02 390 1 C.743S-S•St .. Tin, Total (740-1•) x 1..6 16 1 mg/L lb/Day 1.2 23,433 x T turn, �rtal x .02 .2 1 mg/L lb/Day .02 390 1 (1440- • ) EPA Farm- 3 10- C (Rev. - Si PAGE V-2 CONTINUF ON PAGE V, 3 :EPA 1.0, NUMBER fetal y frwn Rein 1 trfform dI OUTFALL NUMBER I in tt r A/alrrl OMH No 2 NCO024 92 005 Apptovir€, CONTINUED FROM PAGE 3 OF FORM .0 P""Poir51 t,.:_. re ytru ar�<s tx varrrsry tre+.st�.rey atrutccea cerrar:�ee for ,,.uc t C C/`MS fractions that a 1 t to our tncto�h aria lot ALL toxic inet its, cyanides, and total Irfaknots If you area that rerfru ed to nook column 2-aa l'se tnotfeary industries, rtraraprocess 2 to � a 6 Kr Y Y Y w^:Fastewatet eau€f<o'ls anti tionre wired tiCIMS fr7actolrisi, mark "X" to cobjern, 2 to fir ejc:h pollutant you know or have reason to beheve i, present Mark "X*' to column 2 v for each pollutant you a a r n pollutant, oo nova lovide thrr rt s1 rlts ut tat #t za:.r ont3 <anaalysis for that pollutant It yott rrook € olumn 2b tart any pollutant, yo€s roust provide the results !r ltev� as alh5t'.tit If you ta,atk coltaraar 2K for any 6 Y I , know or huvt€ rt.a son to beliewe it will be dischatt ec it, t,:am,erntt ations> of 10 pule or grt ater If ycru mask COMM) 2ta for aactolerrt, act ylonitrile, 2, r,€ at least trtae analysis for that pollutant at you � ,h- You dischargern dinto o :heool or 2 rnetli I YI to dinitra henot, tics most provides the :ttt.ult" of it tt e yt 0;W analysis for each h of these pullutaantts which You kt, ow or have rt..ascm to believe t at r I Y fa Y I , r t «, l" ,r 4 him t least one antal %is ut Irr jefl dest,rttrt- the re asons tho ollutant is ext ected to t,urt+.cart,.<atatara„,caf1t7C7p{>bran}rraraterCC?ttaerlse„ftatlacaflt.t,arltstorwtaactryt,aalrtastkc.trltattan,�kr,yeatraatrs.l.t c �ta to y y P bu di,,-J a,t a;t9 Notethat there are 7 pages to this pall, fafe ase It�wt>vv n�,ec:t; { <art�tellly t"canapfc.ttt taratt i<Ibtr: t`trJf 7t`aaary"a:�,iJ ftrr ". aerie wrtfaafl See insrvoc- nons> for additional details and rerloirenaents t. fr+:Jt..t..U-TA T trAetlt .x. t; F.VF1,11E N T 4 ItNIT 5. tNTfit{C {<arrn+air=rta tltlta AS la. M.Ai ttv,�ti § 1� �AY`VALU1„ t:a.t3NC Ti t p} q' ir, -VAt'J ... LUNG T rtM tt NfJ (al "it1MCiE:> t, a htlk}CtMUM pAitYVAt Itttt,xetet, r of e+e.ttFrs+l Nca cla r t - e . _ ._...._. _ . _... - _.. -. ,. }'. N A t. A V R A L+ A _ ANAL '(tt (zl rans�. r v,x new t it rr.,., ri rt a7taar� ._e raxao, i enu„. -,. R A71CiN METALS, CYANIDEL AND TC)TAL PHENOLS t'inal t1440 36W X 6 <6... 1- mg/L lb/Day <.6 <11,716 :.1 (. , t,tat 7440 38 2) X <1 <. 01 1 pg/L l b/Day <1 <20 M, Beryllium Total, 7440 47 1) X .002 .02 1 m g/L l b/Day .002 39 1 4M. Cadmium Total (7440 45 9) X : .01 .1 1 mg/L l b/Day 01 195 1 5M, Chromium Total (7440 47 3) X .05 .5 1 m /L l b/Day .04 781 1 BM Copper, Total W (7 s0-e) X .05 1 mg/L 1 b/Day .03 586 1 7M Load, Total (74 9.92.1) X 1 mg/L l b/Day <. 08 <1,562 1 e 439.97 i Total X <. 001 1 ' peg/L Ib/Day <.1 <2 1 (7Mna0t02 0) Total X .05 .5 1 m /L 1 b/Day <. 04 <781 1 IMW Salenttttrr, Total $778 �" 2# X < <.02 1 pg/L lb/Day <2 < 9 1 1ttwn.Silver, Total X .04� <. 1 /L lb/Da <.04 <781 1 t7a�t-22-�� y 12M.Thsltunl, X <.5 <5 1 m /L 1b/Dad < 5 <9,764 1 Total (7440 2S 0) y 1 44o Eta � � D 3� �tl,t=, Total t7aa06 6 1 m /L l b/Da .02 390 1 14M(51 12 S} Ico (yentae, X <.02 <.2 1 /L lb/Day <.02 < 90 1 Total 15PA,Plater [ale, X <.005 <.05 1Ong/L lb/Day < 005 <98 1 DIOXIN 3 it's tea rxt C)E.5Cttlat- RESULTS c ii€urtata tlrtrieccr 1, t.atraatt7t,ttt€ X NEOAfI1/6 EPA Fora' 3510 2C: (Rev 2-55) PAGL v-3 CONTINUE ON txL VEEtSE t1NTINUFA FROM THE FRONT at MNS7005 1. POLLUTANT 2. MARK `x' 3. EFFLUENT k UNITS S. INTAKE (optionall AND GAS NItNIEIII R e rssc vrtc: t0. •c icVre """ c's - catvtt a. MAXIMUM DAILY VALUE •`.V'�' b. MAXIM M 3 ava#4Lat4 p,qV VALUE ..,.••.._, ---.--.. c.LONG T y7M aX nticztHabdt') pY VALUE it No or ANAL- a. CONCEW b. MASS a LONG TERM wm 17At {a, tr NO QI ANAI of {tF tlabtel wawa- rae- ott"T ass® . «. 1+I G ,iNCi Nia A7:1 Ci9M :l MASS : 1,t <: C}iVGH Nj$ AT44N Irl A 5 1 C.Ir N+. RNTN AYaCJN Itti A..� rsk TRATION {vlr v.rrrs». CiT ATix}N ITI « sf sEs P t —VOLATILE COMPOUNDS IV* t1 # <5 .05 1 pg/L 1b/Day 5 <00 1 R A F <5 <, 0 1 _ g/L 1 b/Day <5 <98 1 pg L : 1 b/Da <1 <20 1 iz ja - _ 6.2ffiA21atoF <1 <. 01 1tg/L 1/Day <1 <20 1 <1 <.01. 1 g/L 1b/Day <1 <2 1 he FC-h#*rodi- <1 <.01 1 D/L 1b/day <1 <20 1 . x <1 <,01 1 ICJ/L lb/Clay <1 <20 1 4 6 3) hhaaT <2 <. 02 ' 1 l+g/L 1 b/Clay <2 <30 1 ttIV,2-Mora- ethyWInYEther <_1 <.01 _ . _.. 1 /L 1/Day <1 <20 1 {11ih7l '7-" Chloroform 6 <1 <«01 1 pg/L lb/Day <1 <20 1 bro thane x<1 <.01 1: pg/L lb/Day <1 <20 1 1711.27•d� 31V, Olchloro- difluoroma'thane X N/A x x x x x x x 4V. 1,11-DICITIoro- othant 175- t x <1 <.01 1 leg/L lb/Day <1 <20 1 ISV. 1,2-Ellchloro- of tr 7- t 1 <.01 1 N /L lb/Day <1 <20 1 16V. 1.1•Dichloro- x <1 <.01 1 pg/L lb/Day <1 <20 1 ethvle {76-35.4) "17V. 1,2-010hloro- x <1 <.01 1 pg/L lb/Day <1 <20 1 propane(78.87- ) i$V.1,3-o a- tsax-7ffi s► x <1 <.01 1 pg/L lb/Day <1 <20 1 19V.. ethylbe"Zone <1 <.01 1 pg/L lb/Day <1 <20 1 a (1 41.41 t iya�.9I < <.02 1 leg/L lb/Day <2 <0 1 171 7-, <1 <a01 1tg/L lb/Day <1 <20 1 EPA IFUFIrt 3510=2 (Rev, -81 PAGE V-4 CONTINUE ON PANE' A'Lta, NUMBER f(70PV fr(oll IN'ttl I of Form OMS No 2040 0086 Appt oval expires 7 31-88 CONTINUED FROM PAGE V-4 I.POLLUTA, NT 2. MARK 'A' 3, EFFLUENT 4. UNITS 5 INTAKE: (optiona, I AND CAS NUMBER a, MAXIMUM DAILY VALUE b. MAXIM, M 3,? at, Y VALUE C a? ,�A cJ-ONG T M ava VALUE M No, a. CONCEW b,MASS ANAL tat:* (if opurlabic) "to put,.- or ^&- MASS MASS 0) T..To, (If MASS ANAL TRATION (s) co"cwkw 141 YSIES GEMS FRACTION VOLATILE 1�- A I COMPOUNDS (coutinuciff t. ONC!�!IT!,tAl!0N 22V. Methylene x <1 <.01 pg/L lb/Day <1 <20 1 Chloride t75-O9-2) 23V. 1.1,2,2-Tatra- chloroothane x <1 <.01 I pg/L lb/Day <1 <20 1 (79-34-5) 24V. Tstrachlorct- x <1 <.01 1 pg/L lb/Day <1 <20 1 ethylene (127 18 4) 25V. Tolue 110888-3)ne x <1 <.01 1 pg/L lb/Day <1 <20 1 26V, 1,2-Trans - Dichloroethylene x <1 <.01 I pg/L lb/Day <1 <20 1 (156-60-5) 1.1,1 Tti- chloroothane x <1 <.01 I pg/L lb/Day <1 <20 1 (71.55-6) -- chloroethane x <1 <.01 1 pg/L lb/Day <1 <20 1 (79,00-5 )-- 29V, Trichloro- x <1 <.01 I pg/L lb/Day <1 <20 1 ethylene (79-01-6) -iC\i-- foro- . Tr7j.h- fluoromethane x N/A <.01 x x x x x x (75-69 4) 31V. Vinyl(75-01 x <2 <.02 1 pg/L lb/Day <2 <39 1 Chloride GC/MS FRACTION — ACID COMPOUNDS I A, 2-Chlorophenol x <10 <.1 I pg/L lb/Day <10 <195 1 (95-67-8) 2A2,4-Dichlora V A <10 <.1 1 pg/L lb/Day <10 <195 1 phonof (120-83-2) 3A 2,4 Doricthyl V A <10 <.1 1 pg/L lb/Day <10 <195 1 phonol (105-67 9) 4A, 4,6-Dinitto 0 V <10 <.1 I pg/L lb/Day <10 <195 1 Cresol (534-52-1i SA, 2,4-01rdtro- <10 < .1 1 pg/L lb/Day <10 <195 1 Phenol (51-28-5) 6A, 2-Nitrophanol x <10 <.1 1 pg/L lb/Day <10 <195 1 (88-75-6) 7A, 4 Nitrophenof x <10 <.I I pg/L lb/Day <10 <195 1 000-02 7) 8A.p-Cfiloro-ML x <10 pg/L lb/Day <10 <195 CreSof (59 50-7) 4A,Pentachloro <10 <.I I pg/L lb/Day <10 <195 1 i phenol (87 86 5) 10A.-Phenol <10 1 pg/L lb/Day <10 <195 1 (108952) cMoro ph 01 x <10 <.1 1 pg/L lb/Day <10 <195 1 (88-06-2) Ct NTINUEP FROM THE FRONT i1 'tJ05 I,POLLUTANT a. MAPK `X' UVVLU4.NT 4, ITS _-._. _ , INTAKE (z/+rrzzrtfalf .,.... ,.h� AND AS NUMBER v� aaailehir «r V •rwt .MAXIMUMC9All � } crx �+c r.ann„ri+5 y VAt )1. lt} wrnsa _ _p (7 M-AX IM, Irasraxc rt+rve. a. re+wtrtartr ..•.. Y VAC tll• pp l>i C. C. C7 ril C� 7 M a4 fit�a ._ (zfr,�rtz,drCera .._ verMr ta+ �¢«xan: «� �` x- V,'t L.t,a 6: sl (:{ rrn s� ac? ry r" t C? AwA.P.>. Y ,r�"� ar M,asSfit W_mt KaN (:. iC. i7 4 vAi.tt.__ vrxwt a N43 OF ANAC GC/MS FRACTION -- BASElNEUTRAL _ COMPOUNDS 1R. Acenephthena (83 32.9) 28. Acenaphtylana (206-96-6) x <10_� R, Anthracena (120-12-7) x <10 <. 1 a g ( WTay y (y # 48. Remidina ( 2- 7-) < 0 <. 2j g yp /gy j} py Anthracene ( 6- ► _ ---w - <10 _-_ <..1 .. _ l 1 w _fag/L lb/Day <10 <195- l 6R. RanXo (o) Pyreno (50- 2- } { /L lb/D / <10 <195 _..._ 78, 3,4-Renzo- tluoranthena (2 -99.2) _ _. . _ . _.<10 . _ _ 1 . !O L. _lb/Day # ci <i _._ _:. ._ _ Be. 6anzo (I)hi):.. Parylena (191-24-) � . _. _ _ .__._ _10 _ .1. 1__ . FAD L 1b/D4y <10 _.._<1 _. -1-n W Renzo (h) Fluorenthena (207.OR-9> <10 .__. _ .., , -D'—m _1/DaY w <10 _ 15 1 108. Rig (2-Chlaro- ethoxy) Methane (111-911 _. __. <10 _ _._ .. _ _ _ . .. 1..__., _N_ /L lb/Day .,.m<10. _. <1 —__l 1R. Ris(2-Chlarfa- +ethyl) Ether (111-44.4) x _. g/Llb/Day <10.. .__.<195 mil_, 126, 81e(2-GH�(10-2-$D. Ether <10 <.1 1 pg/L 1b/Day <10 <1 5 113R. Rig (hexyl) PhV A <10 <.1 1 pg/L lb/Day <10 <195 1, phenyl Phenyl Ether (101-55.3) X <10 <.1 1 pg/L lb/Day <10 <195 1 1513. outyl Renzyl Pltthalato (85-M-71 X <10 .1 1 . /L 1 <10 <195 1 1 CIR. 2-C'ti lore. (91an#h58_7) <10 <.1 1 g/L lb/Da <10 <195 1 17R, 4-Chloro- phenylPhonyl <10 < 1 1 /L l b/Day <195 ? Ether (7005.72 3) _ _.:.._ _,..... , _ ...__.._ _ ...,.<10 198. Chrysone (21R 01 9) x<10 <.1 1 g/L lb/Day <10 <195 1 198. Dibenzo (a,h) Anthrecene (53-70.3) x <10 <.1 .. _...____.._ w. 1 p�iL lb/Day <10 <195 1 208. 1,2-Dich loro- benzene(95.50,1,) <10 <.1 1 pg/L lb/Day, ._.. 10_ _:. _<195 1 21 R. 1,3-pichloro- nzene(541,731 x <10 <A 1 Dg/L lb/Day <10 <195 1 EPA Farm 3510- C (Rev. -85) PAGE -5 CONTINUE N INUE ON PAGE L forin Approved I.D. NUMBER (COPY frOM Ileat I of Form 1) OUTFALL NUMBER OMB No, 2040.0086 J'EPA Approval expires 7-31-88 CONTINUED FROM PAGE V-6 I.POLLUTANT 2, MARK 'X' EFFLUENT 4, UNITS S. INTAKE fop - AND CAS NUMBER .jb, *E- r- OIL- lrmve, 8M^XjMUM DAILY VALUE -3, b, MAXI M 3,?,R/kY VALUE e -=a. 0 e C.I. ONGT M au VALUE 4 NO OF a CONCEW b, MASS A. L014G TERM b r4O,d`F 0 - (it available) Alopt", Pat, **NY 11-1---- t4 YSES TRATION (1) YSES OCAM FRACTION - BASENEUTRAL COMPOUNDS (continued, 228.1,4-Dichloro- benzene (106-46-71 X <10 <.1 1 pg/L lb/Day <10 <195 1 238. 3,T-Dichloro. bonzidins X <20 <.2 1 pg/L lb/Day <20 <390 1 (91-94-1) 248. Dlathyl Phthatate X <10 <.1 1 pg/L lb/Day <10 <195 1 (84-66-2) 258.Dim Wt-hVl--- Phthalate X <10 <A 1 pg/L lb/Day <10 <195 1 (131-11-3) 268. DI-N-Butyl Phthalate X <10 <.1 I pg/L lb/Day <10 <195 1 (84-74-2) 2M 2,4-Dinitro- toluene (121-14-2) X <10 <.1 I pg/L lb/Day <10 <195 1 288, 2,6-Dinitro- toluene (606-20-2) X <10 <.1 1 pg/L lb/Day <10 <195 1 29B. Di-N-Octyl Phthalate X <10 <.1 1 pg/L lb/Day <10 <195 1 (117-84-0) 308.1,2-Olphonyt- hydrazine (as Azo- X <10 <A 1 pg/L lb/Day <10 <195 1 benzene) (122-66-71 31 BF X <10 <.1 1 pg/L lb/Day <10 <195 1 (206-44-0)luoranthene 328. Fluorene (86-73-7) X <10 <.1 I pg/L lb/Day <10 <195 1 338, He"chlorebenzene x <10 <.1 1 pg/L lb/Day <10 <195 1 thlorobutadiene X <10 <.1 1 pg/L lb/Day <10 <195 1 (87-68-3) 358. Hexachloro- cyolopentediene X <10 <.1 1 pg/L lb/Day <10 <195 1 (77 368. Hexachloto- ethano (67-72-1) V A <10 <.1 1 pg/L lb/Day <10 <195 1 378. Indeno (1,Z3-cd) I'Vrene X <10 <.1 I pg/L lb/Day <10 <195 1 (193-39-5) 386. loophn oroo (78-59-1) X <10 <.1 1 pg/L lb/Day <10 <195 1 398. Naphthalene X <10 <.1 1 pg/L lb/Day <10 <195 1 (91-20-3) 408 hrobenzene X <10 <.1 I pg/L lb/Day <10 <195 1 5-3) sodimethylamine X <10 <.1 I pg/L lb/Day <10 <195 1 (62.75-9) -428. N-Nitrosodi- N-Propylarnine X <10 <.1 I pg/L lb/Day <10 <195 1 t (621-64,7) J I a t'ONTIN(IF ON REVEr, MNS-005 C6NT#NU1E FR THE FRONT 1,POL.LUTA4NT � MA"11 x. 1. UVrL,i;fi NI d UNITi � fNT1AKf-_ p,j,: xre=ail AND CAS _ ... :a ra at is er, G ion- NUMBER .. 4, MAXIMUM 0ACLY t ALRt C" i, MAX#' 3 �yqY tTALfis 6: C 4"?Nfia 'Y � iA K/C. P4 V AAC 4Pi".. , y €t j it tli: St)Ll k4' IF{tf! FI VIl eJP ,t COW C N ;r t matt.. t c ftM 6A.V t,.la ,�= I,s i. Uf4LQfi� d� ra r:s f#f tNt+ 1.iE YFY dkk'vM fit ii{rMi iabit+f +J t♦ 'f ?Y..I+Y i �.E wx w.. ^. Ic f fxf nx ei .• i F' „ +l hi fi l.. "«d x rti A4, TtttN K� M.RA ry ( } a A04ft6 L.i�iPa . tMt fY It YY{ GC/MS FRACTION -- BASE/NEUTRAL COMPOUNOS [t`t)'Ihwfvdf S =438, N'Nitto- iiP nylamine B.Phenanthrene (85-01-8) FL !" �y y . . 1t2, - Tri- yy� ma�ftt o r. 61F ' ! :.:<10 QC#A FRACTION -- PESTICIDE 2P. a-11H1 (19-8 -6) 3P, -8HC t31E1S'7 y } 4P„ 8HC d -9) x SPY 8.8HC (319.86-S) hfor Brie (67-74-9 ) (50.29.3) SP:4,4'-D E (72-SS-9 ) iP. +4r4'-00 (12.54-8) ----- 10P. Dieidrin (60-57.1 ) 11P, a.Frdosulfsn f 115-29.7) �. ..m— �. _.,....-....»,...»..,..... _........_._ ....., ._..»., ,,...»...„.„_„ ._...».._.. ,._ .,,_.... .. ate .... .. .. ..:.... .. ...._,,.. ..>...., ....,.. _...,. <. � .wWa. u.=.„.>.n .....,. ., ....,......, _.., .... .._ 1 P. -Ender ifan 1116.29.7i 6uifate }� { 1 i?31-ti7-8► _ ..... drirt }}1r+�4qP.E.p 16P+ Endlri Ai vde #7 1-93*wa t1 EPA Form 3510-2C {Rev. 2•86} PAGE v*8 CONTINUE ON PAGE V-9 HEM (it '67cWs-fi'�A�c�iiiN — PESTICIDES (continued) 7P Heptachlor Epoxide (1024.57-3) lap, PCB-1242 (53469-21-9) 19P. PCB-1254 (11097-69-1) 20P. PCB-1221 (11104-28-2) 21P, PCB-1232 (11141.16-5) 22P. PCB-1248 (12672-29-6) 23P, PCB-1260 (11096-82-5) 24P. PCB-1016 (.12674-11-2) 25P. TOXOPhone (8001-36-2) -L- PAGE V-9 M a'- UN E iN ITEM V-.0 CO-- 1 PC LLuT'- ANTAND :.: N ($/atxailable) . N1tt TotalyC>reanlc INUEI7 FROM FRUN t 2. MAttK .,... v.d-.,.. a. m ' tr.{es' a. MR. ttMiJM #.roA4LW #eevC xx.ueRx P:w at - A tw" q- arNr array $*�-..F_...®•,..••.. y„ixN{;p N11}A YYkN a if 1' _ VAL.t4E. ..M..... ,_..«-„».- $t4.PAws <w 06 _ 06 * 4 3. h tatAMIN# M 9 ( # tx#a#tx TT f{trN�aAYN&CPatN 6 FL ENT .p.,.R...»�.....,.........� bt Y VAI.tAI : 4: $xl..AeAs• c"L R-47': # #t#Rr#a ....a.,. cove{s•���3nr„xN. +w+. G. 1tq,�t9.c4, a #r : $xlr:sAco NO Hsu' ANR# VStK 1 1.._ 4. UNITS a. CONCEN- 7 ## A 1 I #"r N /L mg/L m/L tP, ttiASxa µ Ib/Day lb/Day l b/Day S. INTAKE (dPryr##tf#ud) a rA G tf '.aM tr A6ft, Ba :E A#.UE �.e-t•oYYaASP:,N $<4MA+4 <. 06 <1, w13 2,538 _ <. 02 <390 Nti:or ANrAL- Y�aE" 1 1 1 h:Off Sod I. Photphotua (at P). Total 17123-14401 !. Redloactiv$ty 1,1t Alpha. Total < _ 1 pC i/ L x < w 4 (2) secs, ! e 1 pCi/L 2w 1±. 6 Ax, Total <. 1 _ pCi/L x <1. 5 (3) Raulµ Total (4) Rattlu#n <* 1 pCi/L 1.4±.4 228e Total k. Su aca 1 m/L 1 b/Day 9.6 187,462 1 #sat apt. 041 14 '79-8l < <. 1 mg/L l /Day <1 <1 ,527 1 1. ulf1dor.x ,S�y.a� < `�` <T 1 mg/L lb/D.ay < <3 ,05 1 (w oj) (14286.46-3) �<w <.1 1 mg/ L lb/Day <.2 <3,905 1 n.8utf enta a.A r#urn ,5 .3 1 mg/L lb/D:ay .61- 11,912 1 $1429-90-5) _ p. K 03 02 1 mg/L 1b/Day .02 390 1 Total (7440.39-3) 4. orb"' m 07 D4 1 mg/ L 1 b/Day .11 2,148 1 Total <. 06 1 m /L l /Day <.1 <1,953 1 Total 11440.48.41 1 mg/L 1b/Day .3 5,858 1 a. Iron, Tyotal e1 1 mg/ L 1 b/Day 1.2 23,433 1 Total $7439.98-41 47 -Molybdenum .09 .06 1 m/L 1b/Day .07 1,367 1 jTotal y y u. lingon000, Tot a�ly l 1 mg/L l b/Day .02 390 1 yyg y . Tln* Total 37'64 — 1 1 mg/L l b/Day 1.2 23,43 1 $744 A. T4ta#l{t,;_ T allot C m Cl - 1 m/L lb/Day .0 0 1 4 1440 32 61 .., ... .._ , . :. f . . �.. . _ . . . - .» Vr"c a-r Y jrutwt fta:ttt t of': orrrk t) OUTFALL NUMaER farnt.4pprova 24392 N/A UNDER?) IN Omit No 2040,0086 FAtt) C It sat# ate a to onto mildly ano Hills, unit art contains process wastewater, rekrtat to k alit" 4%.•re ,tr ,tin is raft, uc,ru,ra rar-- „ .. rvm.:.,rra, — Y a fur all S.tt2tk GCMha4twtins that apply to your tntiiistry and for ALL liiwttsC mf#[all`a', cyakdits, and )rate) pnEkngl. If you a#8 not rest#artwtl to )nark Ct>)ttntrk 2 •al'sa'i:skndry inristriiys, nonprrkces wa,stellil ;r outill antinonreyuiretst GCIM.S tractions). mark " C°` in cotumn 2-t7 tot each pollutant you know or have reason to believe is present, Mark "" to column 2-c for each pollutant You believe wa. absent, it you mark column 2a for any pollutant, you must loovkdu the results of at least one analysts fist that; pollutant, It you mark cofuum 2b fat any pollutant, you mustprovide the results of at')trast one analysis for that pollutant if you; know or have ru sctn to believe it will be discharged in concentrations of Ili Plitt or greater, If you mark cotoom 2b for acrolem, actylortktrile. 2,4 thothop hcsrtot; or 2-methyl•4, 6 dtnilrophenol, you must Provide the results of at least one analysis for each of these pollutants which you kneor w Have reason to believe that you discharge in cunr.ckrtlkatwsk+is stf t b f) p of rcwatstr, Otherwise, fttl fkoll}ttantafor which you ,slm,ta ats column 2b, you us, either submit at least analysis or briefly describe the Mesons the pollutant is expected to p tasty stisk.hnttyt,sil Note that ,bete art# 7 pages to this part, Ttl,;askt ra:vtktw ustcla carefully Complete one table )'aff iwaes for each uutfalt See instructions for additional details and requirements, I.POLLUTANTI AitK `x' 3. Er FLU ENT' j}{� 3 4. UNITS tit INTAKE or tion tf A td t A ...^_ ,._...._ _®. __t _ _..,,. ,"".. '•..." ir. A.kM tAM 9(�y,q�Y idALUE C. i.QNG T M .t $t#a`AG V It. 6.0NGK TERM NUMBER d t x, it r,t c l,. aMAXIMUM DAI Y 4tAi.VL lit rttiattt Pd.'1 ftduw.trct ,a #JN6ENYi crt, ,:c ul.._ _...........: .. .„.... a.. —.,.--._ 4^ ANAL, t1 MASS ANAk rtr xn+ttGtttr# ! _ TRATkCiN )rlrtcrwM '" fa)MAtrtw ) 1 lal >. )Y1 let .ems. rYSiS )*)Y!iAtrit YE'S t.t:r.. t#t,a al t xa a, r IYTN Atia}N 4e),t .. N,d Ri.;ai Ply.... .._.........�."m".„�.{L°titN a,Ft)ri w......+.w.m...�. ...«..®. METALS,: CYANIDE, AND TOTAL PHENOLS INA Antlrnony,. Tutat 47440air Ol ZM, Ateanic, 1 otol x (t440 2) 3M, Britylliton, Total, 7440 41 7) 4M_ Cadailum. R T otal ) 7440 43 9) M. Chromium, x Toted 17440 47t 6M Coppial Testa )7 •64.8) 7 . Tiara) 17439.92.11 8M. Mercury. Total 1e439.97.61 N. Nicked, Total st 1440-02-0) i M. etsnium, xoral (7782-49 2) 1M. Silver, Total x r440-22.4) M. Thaltium, ��r€ A oral (7440-2 0) ..� _ ....._ _..._.�__ _ ...... 3M. Zinc. Total{ . _ _.._ ._....._. �. _..yam._ ......_ t44A 66.6) '.((.ilk Y`.. AIM IVI l nits .ti Cl Jk., xt tit 3xk PA t•ornk 3b)ti 2C. )tiov Ai t)b) VAs..,L v•s Ct)NTtNUE ON f11FVLftSk form A7cgrrtrv*d pTOU FA -FA LL NUM8W OMS So 2040- 6 CONTINUED FROM PAGF V-4 NGUtJ 4 N/A UN DERDRAIN Appr#uar#xWr#s 7•31-e6 I. POLLUTANT 2. "AMA ' 3.IEFFL.UENT 4. UNITS A. INTAKE optf AND CAS NUMBER ara er Lt ee- G aa^ b. MAXI Spp Ulf VALUE a. MAXIMUM DAILY VALUE auel(able cl-0#4 r T Vp VALUE atr# aeb78 d NO, OF a. L N+ TSMA Is N4.Ai1F t rrrc. rkvrr rates (r/avaita le) Areia- isNY Y2 Nt (rl lr} MAIN (rl (4) a^*$ i (rl (2} 4sY4 ANAL^ yeas ■ CQNcaN- bL MA1$. TwATtoN ANAL- (r} GOrrCatYr IJI wwae YSIKS COamti pr.Nrrtar#fr.N is otac apYat ATrd9lM CttrgGattYw Arit#tr: Ta Y a« GC/MS FA TION -tr VOLATILE COMPOUNDS (condtnu#d) 22V. Mathylane Chloride (76.09-2) 23V. 1,1.2,2-Tatra- chleroethan# (19.34-51 24V, Tatrachloro- ( ethylene (127-18-4 25V. Toluene (1-88.3)- 28V. 1,2-Tram. Diehloroethylene 1166-60.6} 27V. 1.1,1-Tri- chforoathane (71.66.6} - 28Vr-- chlaroethono (79.00-6} 29V. Trichloto• }( athylsne (79.01-6) lluo(orriethan# IM69 4} 31V. Vinyl }( Chloride (75.01-4) GC' FRACTION •- ACID CDMPO4 IA. 2-Chloropheno (9t1=67.8} 2A.2a4-Dlchrloro- phsenol (120.83.2) 3A= 2,4 Diniettiyi phenot (105-67 9} 4A: 4.6-01rietto,0 } Cresol (634.52.1 ) 6A 2.4•Din tro• { ph l (61-28.5} 6A. 2-Nitrophanol } 7A 4-Nitrophanot 41 •02 7} 5 8A P-Chtoro-M- /t Cresol (69 60.7} 9APootachturo irhaticr9 t87 86 5) 10A MrEa,ra s ::X t ttut3 *,.rG 1! itj I I A 2.44 1 rF ij MNS-UNI R TN CONTINUED FROM THE FRONT r.-POL.t UTANT t, MARK 'x 3; EFFLUENT 4. UNITS , INTAKE (4 pNr44na1) AND CAS MAXIMUM Di4rtY vxcv Mx%iM M Sp Y VALUEe,L MGT t p #I VRt...UE tr P4olo ctaevcE4a • 8.t7t1 TERM re.�tC9.Ci�' NUMBER rear b •e- G.r• a. di4144o 6r _ cr4a4r4ate -.^ ANA4- , t4. MA$S M ANAL (r( 4aao aivar tarvr #<r,. (r (rr i,r �+�re vsE raa tesrwr% i+r wrr xsE� coacrr+raaxtceaork r, cars ce r.n%awere'a« cTMu rrce«ea.w saw>rr>++ ._:..,�.M. ,,: t3 CTIQN — SASEMEUTRAL. C POUNDS 18. A4: hthrno (93.32.9) 28. AtonoPhIV1600 { (208.9Er�Et} 38. Antht no{ (120.12-1) 48. 8ontidino ( (247•6) _ 98, 86020 (a) Anthr w 88. 80nzo (o){ Pyrono (0-32.) 7B. X4-8+1"110- 4uorolthono (3 •99.2) 88. 8+nto (gh)) PorYlons ' 9e. 84020 (k) fluoroothatm (2- hroro-Mothano r1l (hamh)oro- 4 126. "(2-i m }( ET t107- T► 13e. Bra f2w8#riyi- txy() Phthalate -eromo- tPraonyr r148. 1101.56.34 44twl eonzyt ato (88 -ee.2. Iona- nmphth*1*o* 17e. 4-Chforo- phonyr Phonyr Ether (7_ -72-3) FX Ise. Chr so t21a e1•a t e« p#hwnto (4. ) Anthr ns 63.10-3) ta*nrsne (95 5ti 1ii 2t iR3Ca#cta#csrtr CPA Fnt Th1t)-2C: tRev. 2-05) PAGE V-6 CONTINUE ON PAGE 1 MNTIr, UM FROM PAGE V4 1, POLLUTANT ` A. ANDCAS NUMBER Ta.T #a:.- rr- ,N�. ,$ 4t.. fitavado&te) a"fwa ffi we .� Nt OCfin FRACTION IEME TIRAL bonsono (1 -7 a. btwx#1Jw#t_y vw#.4#e #'1 #al a.ac$$ C #NYC. m:.N TRATfVX COMPOUNDS (eontenuedt 3. EFFLUENT MAX# # x a �y V^I.u6 ava #r# #l1 .ew$$ va"Ca NTNATooft 4. UNITS S. #NTAKE top �l c.#. r#a V'a#.u6 , o, raraec e### #� ap!#RW- Aw��- Mir: ww }®} to) •+aa$$ vi At#iCe }s! a«e w lot aowoa Y aC csNC NTNa$ 9GON : MX t aT t � 238. 3,T-D1chlora naW#no (9194-1 } 248. Dlothy# Phtha#otat (94 66-2} 268. D#othy# Phtho#oto (131.11.3) 268. COPN- uty# Phtha#ot t ( -74- ) 278. 2,4• D#na#tro- to#ono (121.1-2) 288. 2.6-01nitra- tofuono (6 -20.2) 298. Di-N-00ty# hthx#ote (117.84.0) 308. 1,•D#Shony#- hydror#ns (" xo hen ent) 11 2.66-7 n _u 318. F #uorsnthena (2 44.0) . Fluarionto (06.73-7) 330. 4msxs r348L orabutadiene 8. Ho%ochlora- cyclopeot #wns 8. Ha%aCh#ora- athww (67-72-1 ) 3718. # d#a yr ( ,2,3-cd) Pyrono /# (193-39.6) 388. Nophorona (78-69.1) ; 8. Naphthalene 191.20-3) 408 Nitrobaniene 1$.98 9 2} 4$#S N N+i+dt idJil atTS.9tt y:B.rrain. «a Pranvlsra#nv +! MNS-UNDERDRAIN FROM THE FRONT 1. POLLUTANT 2. MARK M° 3. EFFLUENT4. UNITS SE ).#t#tt.t" 4aritQA tj AND CAS NUMBER *,MAXIMUM QAti4VALUE . v VALUE cLAriml tCt tztut : ai ii p!rrfftltCGm+a .#NTA## YENt CiACLl! i.tl#" #ea#: 4tl:- #ijataltt#atr# OM" tomaarms akaa• •o +v •ae«v _,.:.## 1+! #aj �4.as GYaiVitl WYaa#Ytak#'4 « ,......... ...,_.,._:: ._.. A"At#tFAS4 µ #}1 i'H:pQ tN #,! ..4 i,1 *aa . r*t 5 444M8l n#NAa#4A#+t :. 4" Ma i.:MY#a dk Y4KAM .�..W ®. m. ....:. ..®. _.. _:; .,,.. ...m. _..„.„.. l## rnraK rx+ #a! �+••• x5e •Np94U#sp ..®. ,.". »......... «-." ....-..: .. GC FRACTION — BASE/NEUTRAI. COMPOUNDS (eett4l ttatrtt) 438, N-Nttro- k* YI�ilna jj as C�Il1�3RO-�� 44a. R#ea " thrana I815-o1°8) 468. PyrWW 029 0) . 1,2. - Tr!- aftwo r y x 1 -1 QCJAAS FRACTION P- PESTICIDES 1P: A1clt9ta (2) 2P. 4-8k1 3P. -SHC (3I1 •8 -7) �{ i 9.9) }f OP. 8-0040 8P. Ohlordono (67-14.9) }( 7P. 4.4'-CLOT (60.29-31 }( 8P. 4a4'•006 9P. 4,4'-DDD (12-64-9) }{ 10P. 01oldr lwt 11P. a-Endosuf#an 12P.p-EndoWAtfaA 1116.29.1) }� 13P, Endoaullan Sulfate (1 1 4) 14P. Endrin (12.20'8) 11#P. E"dr#n Atdahvdw (7421 93 4) 16P, *4#pfaCtA10( t76448i EPA Form 3610-2 (Rev. 2-85) PAGE V>8 C014TINUE ON PAGE V4 I I ^*- F- lot "^*a 1 441 M^** reaxsx9—n lot COMc *4#-1 coftet VOAI# GC/MS FRACTION PESTICIDES icontloued) I ?P. Hoptuhtor epoxidoo 11024-67-31 18P. PCO-1242 (63469-21-9) 14P. PCO-1264 111097-69-1) 20P. PCO-1221 I 11104-28-21 21P. PCB-1232 (11141-16-61 221`, PCB-1240 (12672-"-6) 23P, PC9-1260 24P. PCB-1016 t-12674.11-21 26P. Tolicoophootea 18001-36-2) PAGE V-9 Date: August 31, 1988 NPDES STAFF REPORT AND RECOMMENDATIONS County: Mecklenburg NPD S Permit No. NC 0024392 PART I- GENERAL INFORMATION 1. Facility and Address. Duke Power Company McGuire Nuclear Station Post Office Box`33189 Charlotte, North Carolina 28242 2. Date of Investigation: N/A 3`. Report Prepared By: J. Thurman Horne, P. E. 4. Person Contacted and 'telephone Number: Mr. W. T. Griffin; (704) 7-5764 5. Directions to Site. From the intersection of Highway 1 and Highway 73 travel east on Highway 73 approximately 3.2 miles. The facility is on the left (north) side of Highway 73 on the southern share of Lake Norman. 6. Discharge Point - 001 & 004 002t 003 & 005 Latitude. 3502611011 30 `251 4011 Longitude: 8005613011 8005712011 Attach a"USGS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No.: F 15 NW 74 Size (land available for expansion and upgrading): The existing site encompasses approximately fifty (50) acres. There is adequate land available to construct additional treatment facilities and modifications. 8. Topography (relationship to flood plain included): Mildly rolling, slopes are generally less than 10. The existing facilities do not appear to be within any flood plain. 9. Location of Nearest Dwelling: None within'1000 feet 10. Receiving Stream or Affected Surface Waters: 001 & 004 002, 003 & 005 a. Classification Lake Norman Catawba Raver b. River Basin and WS III & B WS III Subbasan No.: 0 -08-32 03- 8-33 Rage Two C. Describereceiving stream features and pertinent downstream uses. Outfall 001 & 004: The receiving water body (Lake Norman) is used extensively for primary and secondary recreation and as a municipal water supply. The nearest water intake is for the Town of Huntersv,ille and is located approximately 3 miles northeast of the discharge. Outfall 002 003 005: The receiving river (Catawba River) is used extensively for primary and secondary recreation and as a municipal water supply. The nearest 'water intake is :for the City of Charlotte and is located approximately 10'miles downstream. :CART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORT 1. Type of wastewater: 001 002' 003 004 00 0 0 100 0 0.3 % Domestic 100 100 0 100 99.7 % Industrial a. Volume of Wastewater: 001 002 003 004 005 2525 .41 0.04 .014 7.2 MGD b. Types and quantities of industrial. wastewater: Outfall 001 (Cooling Water Discharge): This discharge .s a combination of condenser cooling water (1,727,100 gpm), conventional low pressure service water (6,500 gpm), nuclear service water (,20,000 gpm) and. *turbine building sumps (70 gpm) . **Outfall 002 (conventional treatment system discharge) : This discharge consists of steam generator blowdo n, condensate demineralier backwash, water treatment system backwash, demineralier backwash, building drains, metal cleaning wastes and *turbine building s ps . Outfall 003 (sanitary waste treatments stem): This discharge consists of the domestic type waste generated by plant personnel. Outfall 004 (liquid radwaste treatmentsystem),: This discharge consists of low level liquid raw to (8 gpm) from minor spills, leaks, etc. in the auxiliary and reactor buildings Page Three Outfall 005 (wastewater collection basin, WWCB): The basin �receives the effluent from the sanitary waste treatment system (Outfall 003), overflow from the emergency standby nuclear service water pond, a laboratory sink and floor drains, miscellaneous building drains and condenser cooling water system unwatering (2000 gpm). C. Prevalent toxic constituents in wastewater: Outfall 001 ***Outfall 002 Biocides (see attached letter Low level radio - dated 2/28/86) low level radio- activity hydrazine activity, chlorine, sodium hydroxide, lithium hydroxide, monohydrate, sulfuric acid, boric acid, hydrazine. Outfall 003 Outfall 004 None Low level radio- activity hydrazine Outfall 005 Low level radioactivity d. Pretreatment Program (POTWs only): N/A 2. Production Rates (industrial discharges only) in Pounds: I] ri r, N C C >plicable CFR Part and Subpart: 40 CFR Part 423 - steam .ectric Power Generation rpe of Treatment (specify whether proposed or existing): itfall 001: None other than a discharge canal )proximately 200 feet wide and 2,500 feet long for the irpose of heat dissipation. itfall 002: Wastewater is treated in the plant's existing >nventi-onal wastewater treatment system which consists of 200,000 gallon initial holding pond, two (2) settling )nds (in parallel) each with 2.5 million gallon capacity, 1 million gallon final holding pond (aerated -diffused _r) and effluent pH adjustment consisting of automated CO 2 idition. pa.gc `our The initial holding pond act This pond may be bypassed, c wastewater. The two settlir one pond remains In standby. the addition of coagulant as ponds. •I■ • 5. Slu by ai,.. art as a flog equalization basin. ?ending on the nature of the ponds are operated such that Treatment can be enhanced by and pH adjustment in these ponds may be discharged aam via outfall 002 or it may pond. Effluent from the --hargd through outfall 002 or sands depending upon effluent aitary wastewater treatment alar aerated -:facultative amber (tablet), and a parshall .dlephone from Mr. W. T. Griffin on /2/). ,all 001 • None :all 002: Sludges are disposed' by l.andfarming at .mated on -site disposal area. This disposal is Utted by ITEM Permit No. 741R2. :all 00:3: ;Mudge is periodically removed from the agoon and disposed at a municipal wastewater treatment plant. Currently', the disposal is made at CMU r McDowel Creek Wastewater 'Treatment Plant. Outfall 00 : Sludges which accumulate in the liquid radw ste system are disposed as low level radioactive wastes at approved repositories such as Barnwell, South Carolina. Pagi 6. **T Five L11 k1%-111t-1:CLJ. OTHER PERTINENT DTION -ucted with Construction ia.-s ,syUQ.L.L.Lt:" _L11 kw= Va.11CLL X-UL"-LJNZA-J--1 Specifications and Environmental Statement for the McGuire Nuclear Station. Additional effluent limits request: In accordance with Duke's request, the current administrative limit for hydrazine (.06 mg/l instream) should be included in the Permit. X Page Six Outfall 005 (WWCB Basin) has previously been included as a permitted outfall. It was removed years ago, but now is proposed to be reinstated due to changes that have occurred in Duke's operations. When this discharge was previously permitted, Duke had considerable difficulty complying with the maximum pH limitation (9.0 s.u.) during summer months. The elevated pH was attributed to increased photosynthetic activity in the WWCB. Through conversations with Mr. Trevor Clements, Technical Services, the MRO is aware that there are new or revised modeling procedures that can be used where appropriate to define the required pH limitations. Considering the large dilution ratio of the receiving stream as compared to the discharge volume, it is suggested that Technical Services consider whether a relaxed pH limitation is appropriate. PART IV - EVALUATION AND RECOMMENDATIONS over the past several months, Duke has submitted several requests for permit modifications, deletions of requests for modifications, etc. From discussions with Dale Overcash, it is our understanding that Duke has requested that we temporarily withhold consideration of all requests except: 1. Request to include the discharge from the WWCB as a separate permitted outfall (005). 2. Request that the Permit indicate that radioactive releases be conducted in accordance with and under the auspices of the NRC. 3. That the current administrative limitation for release of hydrazine be incorporated directly into the PDES Permit. ecommend their approval. Attached is a copy of the NRC requirements pertaining to active Release at this facility. S"4na-fure of Report Prepar er vii—ter Quarity Re final Supervisor /Ramp Tr -ad r Park Marna t r s 14 t T Q' Manna c x71 Creek Ampgrol C) 1 / trra �"" f '+,� =' E ' *'- --•:J bra} f"t, 'li r __--� . (I � �.i 1, 4 '^�"✓ /�'! � l� k � (�1 �9� 'ice .. � "�d`� a,� ��, � py,�.`�, .: } t i rir8 `,'.'7i0 ..� % r 4uwerpLB t \31 rth t'}lii t. � ,+*`X,• i �._- �\y "� �-..... � •r \ t�i: � �" � �`�• � e � f ,� 4 V"'� Ba kr i' 00 seta Y ,✓z a � �y � of p RECEIVED OF rj Cacilina Department of Human Resources Division of Facility Services UWAM cow 701 Barhotir Drive Raleigh, N, ( , ? 7603- 00 Jarnes t . Maiti , Governor a 0. Wilkerson, Jr., Director David 'L Flaherty, `secretary Telephone (919) 7 -420 Tanury 27, 190 Thurman an Horn Natural Resources anity velopt rrt P. o x 950 Mooresville, N. C. 28115 Dear Mr. Horne: This is in response to your telephone conversation of January 15, 1988 with Dayne Brown, Chid of thee Radiation Protection ' Section regarding iquid effluents containing radioactivity discharged rr the McGuire Nuclear Power Station into Lake Nonnan and/car ti-te CatawbaRiver. Fc l se , please find copies of relevant information t we obtained through the searching of; volumes of the Final Safety Analysis tie (' ) , Technical Specifications and Environuental Statement froto the McGuire Nuclear Station. We dope that you will find this information helpful. If you have any further questions, please feel free to calf me. Sincerely yours, ,t p S. W. (Felix) Fong, Ph.I , Head Nuclear ear 'acilities and Environmental Radiation Surveillance Branch 'Radiation Protection Section ao Enclosures Ar WRCE TERMS i-product inventory in the reactor core and the diffusion to the cladding gap are discussed in Subsection 15.1.7. ACTIVITIES IN THE REACTOR COOLANT 1 Fission Products glil 111011111 cietermination OT anticipatea TIssion product activities are summarized e 11.1.1-1, and the concentrations appear in Table 11.1.1-3. Amum fission product activities in the reactor coolant during operation iputed using the following differential equations (Ref. 1): tient nuclides in the coolant, dN wi = DV i N ci (xi + Rn i + 6 B1 B'0 IN wi dt 0 ighter nuclides in the coolant, dN Wi = DV.NQ - - ( x + RN + 81 N wj + N i N wi 3 B W dt 0 N = nuclide population (atoms) D = fraction of fuel having defective cladding initial boron concentration (ppm) B' = boron concentration reduction rate by feed and bleed (ppm per second) n = removal efficiency of purification cycle X = radioactive decay constant (sec 1) - V = escape rate coefficient for diffusion into coolant (sec 1) t = time (sec) Subscript c refers to core Subscript w refers to coolant Subscript i refers to parent nuclide Subscript j refers to daughter nuclide The results of the calculations are presented in Table 11.1.1-4. The fission product inventory in the reactor core and the diffusion to the fuel pellet - cladding gap are discussed in Section 15.1. 12/83 maximum fission product ations. Experience to date ie fuel defect for all operc- zircaloy clad fuel -is con! lure and burnup experience `ission products (eg., xen( do not take into account a space which transports fi! 83MUMMEEM Ift.t I.AfG V`Q7GM wit Tritium two principal contributors to tr ly lower than this ;cussed in Chapter 4. :ontinuous purge OT tne Sion product gases to the i.e.. Cr-51. Mn-54. Mn-56. ".5 ano are oasea on Lne-ju-5/ are included inn -Table ith operating reactors. duction within the PWR 4-VV t CXI IV. n%AU IV I VI IQ I a ItIQ If VV It&, I I LIM V IV I I Zi Q I K-. MQUI= MY L. I , L»f QIIU Mic7ul"Ut futil fit the reactor water. Tritium production from different sources is shown in Table 11.1.1-2. These sources are discussed below. 11.1.1.3.1 Fission Source Tritium is formed within the fuel material and may 1. remain in the fuel rod uranium matrix, 2. diffuse into the cladding and become hydrided and fixed there, 3. diffuse through the clad into the primary coolant, or be 4. released to the coolant through microscopic cracks or failures in the fuel cladding. Previous Westinghouse design has conservatively assumed that the ratio of fission tritium released into the coolant to the total fission tritium formed was approximately 0.30 for zircaloy clad fuel. The operating experience at the R. E. Ginna Plant of the Rochester Gas and Electric Company, and at other operating reactors using zircaloy clad fuel, has shown that the tritium release through the zircaloy fuel cladding is substantially less than the earlier estimates used to predict. Consequently, the release fraction used is ten percent as indicated in Table 11.1.1-2. 11.1.1.3.2 Control Rod Source The full and part length rods for these units are zircaloy-clad silver -indium - cadmium rather than boron. There are no "reactions in these absorber materials which would produce tritium, thus eliminating any contribution from the control rods. 11.1-2 12/83, n A direct contribution to the reactor coolant tritium concentration is made by neutron reaction with the boron in solution. The concentration of boric acid varies with core life and load follow so that this is a steadily decreasing source during core life. The principal boron reactions are the B10,(n,20) H3 and B10 (n,a) Li reactions. 11.1.1.3.4 Burnable Shim Rod Source These rods are*in the core only during the first operating cycle and potential tritium contribution is only during this period as indicated in Table 11.1.1-2. 11.1.1.3.5 , Minor Sources Lithium and deuterium reactions contribute only minor quantities to the tritium inventory. The Liz reaction is controlled by limiting the overall lithium concentration to approximately two ppm during operation. 06 is essentially excluded from the system by utilizing 99.9 percent U7. Tritium generated from these sources is shown in Table 11.1.1-2. 11.1.1.3.6 Reactor Coolant Tritium Concentration The tritium concentration shown in Table 11.1.1-3 is the equilibrium result of the source term in Table 11.1.1-2 and the releases in Table 11.2.6-1. It is assumed that the tritium in the station is mixed in both reactor coolant Mtn 16 cooled reactor, the hydrogen in the circulating water P -.7u, f-l-v. 11, - =11117:6lull ul Per it! Gr-d I. i rig rdu-id-Li on are: 0-16 (n, p) N-16 0-17 (n, p) N-17 0-18 (n, X) N-19 The N-16 isotope decays with a half-life of 7.35 seconds, emitting high energ gammas in 75 percent of the disintegrations (70 percent at 6.13 Mev and 5 percent at 7.11 Mev). The resulting reactor coolant activity is shown in Tab' 12.1.3-4. 11.1.2 SECONDARY COOLANT ACTIVITIES Primary -to -secondary leakage will result in the buildup of activity in the U-tube steam generators. The anticipated concentrations in Table 11.2.2-3 ari 11.1-3 12/81 tt- •t « .t .t t t t t t t t t Standard N237. Values of parameters utilized in ble 11.1.1-1. g secondary side steam activities are given in used to obtain these- activities assumed primary activity input to steam generator secondary side y and steam generator blodown were assumed to be team generator secondary water. The secondary' 2-2 are the equilibrium levels. All noble gases e secondary system in steam leaks and via the air si derd in Table 11.1`. 2-2. NS-SL-653 of June 18, 1973 from R. Salvatori to , Directorate of Licensing, USAEC. 2. Source Term Data for Westinghouse Pressurized hater Reactors, WCAP 8253, May, 1974. 3. Locante, J. and Malinowski, D. D., "Tritium in Pressurized Water Reac- tors," American Nuclear Soviet Transactions, Vol. 1.4, No. 1, 1971. 4. ANSI Standard N237-1976 "Source Term Specification," American Nuclear Society, May, 1976. 5. Schreiker, R. E. and Lorii, J. A.', Operation Experiences with Westinghouse Core, WCAP-8183, December, 1976. 11.1.-4 12/83 1. Ultimate core thermal power, MWt 3636 2. Clad defects, as a present of rated core thermal power being generated by rods with clad defects 0.12 3. Reactor coolant liquid mass, lbm 4.62 x 10 5 4. Reactor coolant full power average temperature, F 590 S. Purification flow rate (normal) gpm 75 6. Effective cation demineralizer flow, gpm 3.0 7. Volume contra A tank volumes a. Vapor, ft 3 240 160 b. Liquid, ft B. Fission product escape rate_ioefficients: 1 a. Noble gas isotopes, sec -1 6.5 x, 1.3 1 b. Br, Rb, 1 and Cs sotopes, sec x c. Te isotopes, sec 1.0 x 9 d. Mo isotopes, sec 2.0 x 1 10 11 e. Sr and Ba isotopes, sec 1.0 x 12 f. Y, La, Ce, Pr isotopes, sec 1.6 x,10 9. Mixed bed demineralizers decontamination factors: a. Noble gases and Cs-134, 136, 137, Y-90, 91 and Mo-99 b. All other isotopes including corrosion products 10. Cation bed demineralizer decontamination factors *Escape rate coefficients are based on Westinghouse Fuel defect tests performed at the Saxton reactor. Recent experience at two plants operating with fuel rod defects has verified the listed escape rate coefficients. .t.L. gut "'Okf I6iLIT :UI tCUIN 11UUIU ydb b GT'1PPIfly Id(::.WT-t . I rlt-0 o Stri ping Fraction Kr--85 2.3 x 1_ 1 Kr-85m 2.7 x 10 Kr-87 6.0 x 10_1 Kr-88 4.3 x 10 X -131 m 1.0 x 1 r, Xe-133 1.6 x 10 X -1. 3 3 m 3.7 x 10 X -135 1.8 x 10 X -135m 8.0 x 10 1 X-1381.0 12. Baron Concentration and Reduction Rates a. B0 (initial cycled 85 ppm B' (initial cycle) 2.1 ppm/day b. 80 (equilibrium circle) 1080 ppr ' (equilibrium cycle). 3.9 ppmlday 13. Pressurizer Volumes a. Vapor 720 ft3 b'. Liquid 1080 ft 14. Spray Line Flow 1.0 gpm 15. Pressurizer Stripping Fractions a. Noble gases 1. b. All other elements Volume control tank purge rate is 0.7 scfm. Volume control tarok stripping efficiency is 40 percent. 12/83 Table 111.1- Desi n Basis Tritium Production fur Ong Unit Expected Release Total Produced to Reactor Coolant ritim Source curies/yr) (curies/yr) ernary Fission 10500 1050 Wrnabl e Poison Rods' ;Initial Cycle) 120 152 Soluble Boron ,Initial Cycle) 222 222 'Equilibrium Cycle) 309 30 Lithium and Deuterium reactions 110 110 Total Initial Cycle 12352 1540 Total Equilibrium Cycle 10919 1470 Basis: Power Level 3555 MWt Load Factor 0•B Release Fraction from Fuel 10 Release Fraction from Burnable Portion Pods 10 Burnable Poison Rod B-10 Mass 6160 cdpm Reactor Coolant: Boron Concentration (Initial Cycle) 860 ppm Reactor Coolant Boron Concentration (Equilibrium Cycle) 1200 ppm 12/B3 Table 11.1.1- Reator Coolant Fission and Corrosion Product Activities During Normal Operation Activity Activity Isotope (Ci/ m) Istope (kci/ m H-3 1.0 _ Cs-134 2.8 x 10-1 Br-83 5.9 10_3 I-135 2.3 x 10_2 Br-84 3.3 x 10_ -136 . x 10-2' Br-85 3.8 10 Cs-137 2.0 x 10 Rb-86 9.5 x 10 Ba-137m 2.0 x10-9 Rb-88 2.5x 10 8a•-140 2.4 x 10- Sr-89 3.7 x 10_ La-140 1.7 x 10 ' Sr-9 1.1 x 10_ Ce141 .4 x 10 5 Y-90 1. x 10_ e-143 4.4 x 10-5 Sr-91 7.6 x 10 Pr-143 5.3 x' 10 Y-91M 4.5 x 10 Ce-144 3.5 x 10 Y-91 6.8 x 10_5 Pr-144 4.2 x 10_3 -9 4.0 x 10 Cr�-51 .0 x 10 7r-95 6.4 x 10- Mn-54 3.3 x' 10 Nb-95 5.3 x 10_ e-55' 1.7 x 10�3 Mo-99 9.1 x 10_ Fe5 1.1 x 10-2 Tc-99m 5.7 x 10 Co-58 1.7 x 10 Ru-103 4.8 x 10 Co-60 2.1 x`10 Rb-103m 5.6 x 10 5 Kr-83m2.2 x 10 Ru-°106 1.1 x 10 Kr-85m 9.3 x 10 Rh-106 1.3 x 10 5 Kr-85 2.2 x 10_2 Te-125m 3.1 x 10 Kr-87 6.7 x 10 Te-127m 3.0 x 10- Kr-88 1.9 x 10- Te-127 9.9 x 10 Kr-89 .3 x 10 Te�-129 2.0 x 10- e-131m 5.6 x 10 1-130 2.4 x 10 Xe-1m 4.1 x' 10 Te-131m 2.8 x 104 Xe-133 1.7 -2 Te-131 1.4 x 10 Xe-135m 1.6 x' 10 1-131. 2.9 x 10- Xe-135 2.2 x` 10 Te-132 2.9 x 10 Xe-137 1..1 x 10 1-132 1.2 x 10 Xe�138 5.4 x 10-2 1-133 4.3 x 10 1-134 5.9 x 10 12/83 Table 11.1.1-4 Reactor Coolant Fission and Corrosion Product Activities During Normal Operation` Activity Activity Isotope Ci/) toe (EC i/ ) H-3 3.5 _ Cs-136 0.15 Br-84 4.3 x 10 C -137 1.5 Rb-88 3.7 _1 Cs-138 0.98 _3 Rb-89 1.1 x 10 Ba-140 43 x 111 Sr-89 3.3 x 10- L -140 1.5 x 10 Sr-90 1.7 x 10 C-144; 34 x 10 Sr-1 1.9 x '10_� Pr-144 3.4 x 10�4 Sr-92 7.4 x 10 -A Kr-85 88 Y-90 2.0 x 10_3 Kr-85m` 21 Y-91 6.1 x 10_Kr-87 1.2 Y-92 7.2 x 10_4 Kr-88 3.7 7r-95 7.0 x 10_4 Xe-131m 1.9 2 Nb-95 6.9 x_10 Xe-133 2.81 x 10 Mo-99 5.3 e-1 3 3.1 I-131 2.5 Xe°-135 63 -132 0.9 Xe-13m 0.7 1-133 4.0 Xe-138 0. -134 0.6 C-51 2.0 x 10_ I-135 2.2 Mn-54 7.9 x 10_2 Te-132 0.26 Mn-56 3.0 x 10 e-13 2.9 x 10-2 Co-58 2.6 x lo- s-134 0.3 Co-60 2.1 x 10 NOTE: Based on operation 'with 'defects in cladding of rods generating 1 percent of the core rated power and with the Waste Gas System remove from service. ti /83 Table e 11 Parameters Used in Cal�olati Fuel Defect Fraction Primary to Secondary Leak Rate 0.12% 100 lbs/dav Steam Generator Water Mass 88,000 lbs/generator Steam Generator Blowdown Rate 45,000 lbs/hr. Steam Generator Internal 0.01 Partition Factor for Iodine Secondary System Demineralizer 10 Iodine Decontamination Factor (DO 12/83 Tab Pain Steam Iodine From Steam 1ste a . itions Rasuitina 1-131 9.7 x 10 1-132 2.9 x 10®8 1-133 1.3 x 10-7 1-134 9.8 x 10- 9 1-135 5.8 x 10- 12/83 Table 11.2.2-1 (Page 1 of 2) Desi n Basis Source Strn the for Radioactiue Taste S'stems In ut Streams The following list is an explanation of source strengths identified on Figures 11.2.2-1., .1..2, - , 11. . ~- , 1. . .2-4, 9. . -1, and . . -2 by alphabetical flag designations as follows: Y Y. Maximum anticipated nuclide concentration X . Normal 'operational nuclide concentration Flag Letter Source Strength Reactor coolant containing fission and corrosion products B Reactor coolant downstream of mixed -bed demineralizer Reactor coolant downstream of mined -bed and cation - bed demineraliers D Reactor coolant, demineralized, gas -stripped (see Volume Control Tank Activities - Table 112.2-2) F Reactor coolant, fully degasses F Reactor coolant, fully degasses, diluted with other leakage (drain header, dilution factor = 1/50) Reactor coolant; dilated with other 'leakage (flush header, factor = 1/50) Reactor coolant, degassed, evaporated (DF = 1000) I Reactor coolant, degassed demineralized, diluted 1/4.8 (Refueling water storage tank) ,] Reactor coolant, degassed, demineralized, diluted 1/4.8 (Refueling mode) Reactor coolant, design basis LDCA sump L Reactor coolant, degassed, demineralized, diluted 1/8 (Fuel pool water) Fuel Fool water, demineralized (Fuel Pool eminraliers effluent) N Evaporator concentrates, nonreyclable (see Table 11.5.2-1 and fable 11.. .4-1, see Subsection 1.1..5.2' for inputs) 12/83 Table 11.2.2-1 (Page ,2 of Flack Letter Source Strn th Demineralizer resins (1 part combined resins plus 2 parts sluice water (spent resin cone. from Table 1.5.-1 divided by factor of 3, see Subsection 11..2 for inputs) emineralizer resin sluice water return (equal to Flag ) Waste Gas Tank (normal) (See Table 11.3.2-1 and divide by tank volume of 600 F. for concentration) Secondary side activity caused by steam generator tube leak (See Table 11.2.2-) Mixing and settling tank sludge (equal to Flag F) T Liquid waste systems tanks vent header (vapor); U Containment ventilation unit, condensate drains' Spent resins (combined and decayed for 6 months assuming demineralizer resins replaced once per year See Table 11.5.-1 and Subsection 11.5.4) Maximum activity allowed by Environmental Technical' Specifications divided by tank volume of 600 ft. for e concentration 12/ 3 Table 112.- Maximum Volume Control Tank Activities t (Based on parameters given in Table 11.1.1-1) Vapor Activity (Curies) *Stripping Fractions with Assuming Operations Plant Without Isotope WGS 02erating of WCS WGS Kr-85 0.35 6.8 x 10-1 1.4 Kr-8 m 0.50 6.6 6.6 Kr-87 0.69 2.2 2.3 Kr°- 0.57 1.0 x 101 1.1 x 10 Xe-131m 0.39 1.4 9.8 Xe-133 0.40 4.1 x 102 1.4 x 10 Xe-133m 0.41 8.3 1.5 x 101 Xe-135 0.48 2.6 x 101 2.6 x 101 Xe-138 1.00 4.5 x 10-1 4.7 x 10-1 a * Volume control tank purge rate is 0.7 scfm. Stripping efficiency is 100 percent. 12/83 Table 11. 2. 2-3 Steam Generator Blewdown Concentrations Activity Activity Isotope { Ci/ m) Isotope Ci/ m} H-3 1.0 x 10 1-134 5.9 x 10- Br-83 1.1 x 10 Cs-134 2.4 x 10 Br-84 2.3 x 100 I-135 5. x 10 Br-89 3.0 10 C-136 1.3 x 10 Rb-86 8.3 x 10 9 Cs-1371.8 x 10- Rb-88 1.1 x 10. _11 Ba-137m .4 x 10_8 Sr--89 3.4 x 10_ , Ba-140 .7 x 10 Sr-90 6.8 x 10_10 10 L -140 1.2 x'10- Y-90; 1.4 0 Ce-141 6.8 x 10 Sr-91 3.4 x 10$ Ce-143 3.4 x 10 Y-91M 1.6 x 10_ r-143 3.4 x 10_ Y-91 5.1 x 10 Ce-144 3.4 x 10_16 Y-93° 1.7 x 10 Pr-144 1.5 x'10 Zr95 6.8 x 10- Cr-51 1.5 x 10_ Nb-95 6.8 x 10 Mn-54 3.4 x+ 10 Mo-99 6.8 x 10- Fe-55 .4 x' 10-7 Tc-99m 5.0 x 10 Fe-59 1.0 x'10 Ru-103 .4 10 Co-58 1.4 x' 10� Rh-°183m 3.1 x 10 Co-60 .5 x' 10 Ru 106 .8 x 10-10 r-83 .6 x" 10- R 196 6.0 x 10 Kr-85m 2.4 x 10 10 e-125m 1.7 10-8 Kr-85 5.6 x 10- Te127m 1.7 x 10 Kr-87 .6 x 10 Te�-1.7 5.1 x 108 r-88 4.9 x 10_ Te-19m 1.0 x 10 Kr-89 1.6 x 10 Te-129 9.5 x 10-g Xe-1 1m 1.5 x 10- 1-130 6.9 x 10 Xe-1 3m 1.1 xi 10 Te-131m 1.7 x 10_ Xe-133 4.4 x 10_ Te-131 3.1 x 10 Xe-15m 4>1 x 10 1-131 9.7 10 Xe-135 5.6 10� 0 Te-132 1.7 10 Xe-137 2.9 x 10 1-132 2.9 x 10 Xe-1 8 1.4 x 10-8 1-13 1.3 x 10 12/83 Table 12.1.- Reactor Coolant System nitro en-16 Actiuit N-16 Component Ci/cam Reactor Vessel, Core 95 Reactor Vessel, Upper Region 125 Reactor Outlet Pipe 113 Steam Generator 92 Coolant Pump 69 Reactor Inlet Pipe 65 12/3 14 IJ io 3-39 XIOACTIVE WASTE SYSTEMS Iiiveccluter ��, � i�� t i) are useo systems(. F 11 l'i 111, - r-- -- 11- "CAJ-V-ill 1:,Va-LU41-J-VL1 Lscussion of the radioactive I,--- --- —1— . ----- ------ lear power plants consistent with keeping radioactivity in effluents resultant radiation exposures to levels which are as low as practicable. .1 Liouid Waste liquid radioactive waste treatment system will consist of the tanks, in, pumps, evaporators, process equipment, and instrumentation necessary collect, process, store, analyze, monitor, and discharge any potentially ioactive wastes from the plant. Although the liquid waste will be collected } 1' -0 continuously, the process and storage systems will be sized so that proeesE of this waste will be done on a periodic basis. Thus, treated liquid waste to be released will be handled on a batch basis as required, permitting optimum control measures and reducing the chancre for an inadvertent discha of radioactive liquid in excess of release limits. Prior to release of any treated liquid wastes, samples will be analyzed to determine the amount o radioactivity in the 'batch to assure conformance with release limits. diation monitors will automatically terminate liquid waste discharges if -high radiation levels are detected in the discharge line. 'the bulk of the radioactive liquids that will be released from the reactor coolant system will be processed and recycled through use of the baron recycle system (see dig. .1). The function of the boron recycle system will be to process part of the reactor coolant letdown for reuse of the baron and purified water, but a small portion of this water will be dis- charged for plant tritium control. The boron recycle system for the McGuire plant is not designed to process reactor i-nni not` cat-,4^, 4 » 1 --A C— t I ___s is ! � • � �:> 9! .y �. is to be di ran be ated react' Lant . A processed liquids will normally be recycled to the reactor makeup water storage tank or the baron recycle holdup tank for reuse in the plant. Operating e` evi nce at `other si ilar,!planto.<ha ,'sho x,that,=it-will b E n c asa y tc discharge' tritium at ° th Iarrata,, 01 eix=2000c' Qi/yea r,from the' plant'"pr'ir cool "t systems ins.;circlet� preVent ru desi;rabl.y', h Lgh tri.ti acc " 3:ationt' °thin ' the t:pl tl; This is accomplished by occasional release of treated tritiated water from Channel A to the condenser cooling water discharge instead of returning it to the reactor makeup water storage tank or the boron recycle holdup t k'for reuse in the primary coolant system. S TEAM TURBINES REACTORS STEAM GENERATORS CONDENSATE CONDENSERS tS uoon VOLUME CONTROL BORON THERMAL REGENERATION LETDOWN TO PRIMARY COOLANT LOOPS TANK SYSTEM DEMINERALIZERS CONDENSATE REACTOR MAKEUP : .STORAGE :..WATER STORAGE TANK � DEAERATED TRITIATED STEAM WATER: GENERATOR "BORON RECYCLE SLOWDOWN FLANGE LEAKOF`.fS, VALVE LEAKOFFs, PUMP SEAS REACTOR COOLANT BORON RECYCLE EVAPORATOR CONDENSATE :TANK LExKQFFS, DRAIN TANKS I HOLDUP TANK '..bEMfNERALdZER I STEAM 1. BORON: RECYCLE BORON RECYCLE GENERATOR I.. EVAPORATOR EVAPORATOR SLOWDOWN I FEED GAS STRIPPER DEMINERALIZER I I DEMINERALIZER: PACKAGE AERATED TRITIATED ----- ^-�---------- WASTE: (CHANNEL Ad EQUIPMENT LEAKS AND DRAINS VALVE LEAKOFFS, POMP SEAL WASTE HOLDUP WASTE WAS!: WASTE EVAPORATOR CONDENSATE RECYCLE ( LEAKOFFS,TAIaaOVERFLOWS, OTHER SOURCES.: I DEMINERALIZER MONITOR l AERATED NONTRITIATED WASTE (CHANNEL B) 1 FLOOR DRAINS, SINK DRAINS, SOME.. EQUIPMENT DRAINS,. FLOOR :DRAIN MIXING AND SETT G WASTE I MONITOR WASTE MONITOR OTHER SOURCES TANK TANK DEMINERALIZER TANKS LAUNDRY AND SHOWER LAUNDRY AND WASTE.. WATER.: SHOWER TANK 2.,900 cos: SPENT RESINS, .EVAPORATOR WASTE ON -SITE OFF -SITE 9OTTOMS, MISCELLANEOUS DRUMMING --°— STORAGE DISPOSAL SOLID WASTES ROOM DISCHARGE INTAKE STRUCTURE �:;-.-• STRUCTURE --_-- ALTERNATE y t EA_W{ i0j� ara zz Figure 3.16 Liquid waste disposal system. 3-42 Channel B will be designed to handle low -purity waste (nontritiated) from the laundry and personnel shower drain tanks (normally the largest volume sources) and the floor drain tanks. This waste will normally have low activity. The waste treatment equipment provided in Channel B will include a mixing and settling ;tank for the laundry and shower drain waste, filters, a waste monitor carbon filter, and waste monitor demineralizer. Interconnections (not shown in Fig. 3.16) will be provided with the waste evaporator in Channel A so that Channel. B wastes can be processed through the waste evaporator in the event of an unexpected high level of 'activity. In addition to the Channel A and Channel B liquid waste subsystems, the applicant will incorporate a steam generator blowdown recycle system to treat the blowdo' (water periodically flushed from the secondary coolant system to maintain chemical purity of the secondary coolant) should steam generator tube leakage result in the presence of radioactivity in the secondary side. The steam generator blowdown water, when contaminated with radioactivity, will be processed by the steam genexator blowdown recycle system and reused in the plant. The applicant has stated that there will be significant design margin in the liquid waste treatment system to feceive and ocess liquid AO waste. For instance, the applicant has estimated that 163gal of reactor coolant per; year will be treated by the liquid waste treatment system, although the capacity of the 5- pm waste ev poratwor at a 25% load factor is 657,00 gal (four times the estimated input). From our review of the liquid waste disposal system in the plant, there appears t be sufficient capacity, redundancy, and flexibility to assure that, ;under any reasonably expected conditions, the plant can be operated so that the radioactivity concentrations in liquid effluents :can be held to a small fraction of the limits defined by 10 CFR Fart. 20 and that these concen- trations may be said to be as low as practicable in accordance with 10 CFR Part 5. In the absenceof a firm commitment from Duke Power Company And a horough' engineering evaluation by the staff at the construction permit stage of the concentration doses and environmental effe is of radioae Ye'releases from the McGuire Station. The average expect d annual rele for each nuclide is given in Column 2 of Table 3.13. 41,1111 Column 3, headed "initial concentration in discharge canal," is the expected annual release diluted by the annual volume of water flowing through the condenser cooling w t r di'harge canal. This is normally the maximum concentration of nuclides eleaxed to a beady of water from a PWR power plaint. In the present case, however, it appears that, under reason- ably expected conditions, a fraction'of the activity entering Lake �y in liquid eMuents from MGi,, Units I and 2 'large canal 2.9 x 103 efir met 2.6 x I or efir 2,9 x to, cis net 10 x to' its I'll X 108 ft3 barge canal -'"initial concentration" concentration in channel Annual concentration" Steady-state(PCIMI) Radionuclide release in discharge Assuming no dilution by lake -con-ft"a"On Assuming dilution by take (0/year) canal (Acvml) Channel Pool Channel: Pont 86 Re 0.0026 1.0 x to-" 1.1 X 10-" Ll X 102 LO x 10-12 2.o x 16-11 99 Sr 0.0024 9.3 x 10-11 I'll x to-,, 20 x 10-12 l'o x to -12 2.0 x to-, 2 90 St C000080 3.1 x 10-14 3.5 X 10-" 65 X 10-14 3,5 x 10-14 6.5 X 10-14 OAMI 1 4.2 x 10-" IS X 10-14 6.5 X to-14 3,5 X 10-14 6.5 x 10-14 91 0.50 L9 x 10-18 2,2 x 10-'o 4A X 10-10 2A X 10-10 4.0 X 10-'0 45 75 0,00040 1.5 x to-13 LI X 10-" 3.3 X 10-13 1.7 x 10-13 3,2 x lo-13 9s Nb 000040 1.5 x Ut-" 1,7 x 10" 33 x 10-13 L7 X 10-13 3,2 X 10-" 99 Me 0.20 7,7 x to-,, 8,6 X 10-" L6 x 100 5,5 x lo'" 1,2 x 10-10 103 it. 0.00028 I'l x to-,' 1.2 X 10-" 2.3 X 10-13 1.2 X 10-t3 2.3X 10-11 tot, Ru 01000078 3.0 x to-,, 3A X 10-14 6.4 x 10-44 3.4 x 10-14 6A x 10-" loatep, 0.00028 1.1 x to-,, 1,2 x to-" 2,1 x to -13 1,2 x to -13 2.3 x to-,, OS Rh 0,000046 l,8 x 10-11 2,0 X 10-14 3.9 x j0-14 93 x 10-15 2.3 x 104 125 so 0X)"26 I'l x to-,, 1.2 x 10-" 2.3 x 10"s 1,0 x 10-15 2.1 x 10-" 127 Sb 0,000015 5.8 x to-" &S x 10-" 1,2 X 10-t4 4.6 x 10-15 9,7 x 10-11 Mm 7t 0,00024 93 x 10-" 1.0 X It)-" 2,0 X W" 1.0 x 10-11 l.q x 10-11 12?. Te 0LO019 7.3 x 10-13 8.2 x W" L6 X 102 8'1 X 10-t3 I "'i x to-,, 121 Te 1 0,0019 73 x 10-" 8,2 x 10-" E6 x 10-12 8, X j0-t3 1_6 X 10-11 129. Te 0.20 7.7 x 10-" 8 6 x 10' 1 6 x 10' 83 x 10-" 1.6 x lo-10 a29 Te 0.20 7.7 x 10-" 8.6 x to-,, 1.6 x 10" 83 x W" 1-6 x 100 131. Te 0M28 1.1 x to-,, 1 2 x 10-" 2.3 x 10-12 5.1 x to-13 I'l X 10-12 M TV 0.00052 2', X 10-13 23 x 10-" 4A x 10-" 9.7 X 10-14 2.5 x 10-13 132 To 0A94 3,6 x W" 4.1 X 10-' ' 7.7 x W" 2,7 x W" 5,9 x to _tj 431 1 0.54 2.1 x 100 13 x U)_'O 4-4 x 10-10 IA x 10-10 19 x 10-' 0 134 (7% 2.2 8's x 10-10 9.5 x 10-10 1,$ x 10-9 9,5 X 10-" 1-8 x 10-4 t36c, 0.74 In x 10-'o 3.2 x 10' 6.0 X 100 2,9 x 10-'o 5.6 x 10-'o 137 Cs 0.12 4,6 x 10-" 5,2 x to-,, 9'8 x to -11 5.2 x 10'11 9.8 x to-,, 137. Ha 0.14 SA X W" 5.2 x W" 9,8 X 10-1' 5,2 x 10-" 9.8 x 10-" t40 0. 0,0026 I�o x to-,, I'l x in-,, 2:1 x 10-11 1.() X Io-12 2, X 10-11 t40 L. 0,0022 &S x to-,, 1.3 X W" 2.4 X W" 1.2 x 10-11 2.3 x to-," 14 IC, 0M04 2 L6 x 10-" 1.8 x I0_13 3A x 10-t3 117 x W" 33 x 10 -13 a43 0.000062 2A X 10-" 2.7 X Io-" S', X 10-14 1,2 X 10-11 3.0 X 10-14 144 cc (100024 9,3 X 10-14 1.0 x to-,, 2'(1 x to -4 1.0 x 10- t 2.0 x to-,, 143 of 0.00034 1,3 X 10-13 LS x 10-" 2 8 X 10" 1.3 x 10-" 2,6 x 10-" 147 No 0M014 SA X W" 6,0 x 10-14 I'l X jo-l3 5.3 X 10-14 I'd X 10-11 W47pm 0.000026 1.0 X 10-14 1', X 10-14 2, X 10-11 I8 X 10-14 2,1 X 10-14 149PM O.ODOIO 3.9 X 10-14 43 X 10-14 8,2 X 10-14 IS x 10-14 5.6 x 10" SiC, 0,08 341 X to-" .1.5 X to-" 6,5 x 10-" 33 X 10' 63 X 10-" 54 Mn 0.12 4.6 x W" 52 x to-,' 9:8 x w" 5.2 x to-,, 9.8 x to-11 5 1 I�c OA6 1,8 x to -,a m x 10-10 m x 10`0 2,0 x to-10 3.8 x 10-11 $9 Fc 0.10 3.9 x to-,, 4-3 x 10-" 8,2 X 10-" 4,2 x 10-" 8,0 x to-" 58 (70 4.2 1,6 x to, 1.8 x to, 3A x 10­9 1.$ x to-, 3A X 10-9 60C. 0.12 4.6 X 10-'' _;,; 5,2 x to-,, 9.8 x to-" 5.2 x to-" 9.8 x 10 -11 Total 10.0 - X to- 4.31 X 10 - 871 X to- 4.2 x to- 1,1 x M- ,U 2000 7,7 x 10-' 8.6 x 10-' 1.6 x to, 8.6 X 10-' In X 10-* 3-43 Appendix MODEL USED TO ESTIMATE RADIONUCLI Liquid effluents will be released from the discharge canal for the condenser CONCENTRATIONS IN LAKES McGuire Nuclear Station by ing water. After release in tially diluted by an annual rate cis (see Sect. 3.3.3). The Lake Norman in the old river ections 11 and III) and discharged to Lake 0 LL L 01 Lhe SLatlon (sections T A IV), as shown in Figs. 3.8 and 3.9. Water is returned to the channel from the pool by one or more small outlets north of the station at the same rate as the flow of condenser cooling water through the station. Because the yearly average stream flow of the Catawba River into and out of the channel portion of 2600 cfs (see Table 1-1) is smaller than the flow of condenser cooling water through the station, the final dilution in the channel is smaller than the initial dilution of liquid effluent in the condenser cooling water. The final dilution of the condenser cooling water and pool is also smaller because of recirculation of liquid effluent from the channel to the pool in the condenser cooling water. The model shown schematically in Fig. 1-1 was used to predict the concentration of any radionuclides in the channel and pool portions of Lake Norman near the station and in the downstream lakes of the Catawba River system within a 50-mile radius of the station. The differential equations describing the amount of activity in the different compartments of the model as a function of time are: dN P= Ne [N dt P — [A + R _V_ RPC + ANC (1) V� � P] P ] dNC = Np� NC — —Rpc-- �c-R,M+—R +XN (2) dt VP [VC VC CP dNm Nc NNE —=—Rem --- V RMW+ANC (3) dt V': M I dNw NM NW —=—RV gym —RWF+XNW(4) dt Vm IW ] dNF Nw NF dt VW RWF­ — Rog. + XN (5) V F Table l-1. Data on Lake Norman and the downstream lakes of the Catawba River system within SO miles of the McGuire Nuclear Station Lake Area of lake` Volume of lakes' Flow of water from lake' (acres) (fta) (cfs) Lake Norman 3.25 x 104 4.76 X 10'0 2.60 X 103 Mountain Island lake 3.24 X 103 2.50 X 109 170 X 103 Lake Wylie 1,25 X 104 1.23 x 10§° 4.10 X 103 Fishing Creek Lake 137 X 103 2.61 X 109 4.86 x 103 aDuke Power Company, McGuire Nuclear Station, Units 1 and 2, Environmental Report, Fig. 2.4- , sect. 2 (Dec. 4, 1970). bDuke Power Company, applicant's answer to ORNL question 1 of Past E. 1-2 I C R pc g, CHANNEL OF LAKE POOL OF LAKE NORMAN NEAR STATION Rcp, NCRMAN NEAR STATION , Cc V! Nc!) (VP, Np, Cp), RCM n A MT. ISLAND LAKE (Vm, Nm, Cm) A RATE OF DISCHARGE OF RADIONUCLIDE FROM STATION R FLOW RATE OF WATER FROM RMW PC CHANNEL TO POOL R FLOW RATE OF WATER FROM 3 cp POOL TO CHANNEL LAKE WYLIE RIC FLOW RATE OF WATER INTO (Vw, Nw! Cw) CHANNEL RCM FLOW RATE OF WATER FROM CHANNEL TO MT. ISLAND LAKE 21 WF ROF FLOW RATE OF WATER OUT OF FISHING CREEK LAKE $� N C CURIES OF RADIONUCLIDE IN FISHING` CREEK LAKE CHANNEL 000 ,. (VF! NF, F) N F . CURIES OF RADIONUCLIDE IN at FISHING CREEK LAKE; V VOLUME OF CHANNEL R VF M • VOLUME OF FISHING CREEK LAKE Figure l-l. Model used to estimate radionuclide concentrations in lakes. t_ 5 1-4 with t = time and A = 0.693/Tl/2, where h is the decay constant and T1/ is the half-life of the radionuclide. Other symbols are defined in Fig. I--l. These equations and models are similar to ones given in a Vir inia Electric and Power Company report can the North Anna Nuclear Station l and in Peterson et al, Equilibriumsolutions (dN/dt = 0) to these equations are used, since all that is required in the estimates of dose to biota and man is the concentration of the radionuclides averaged over the period of a year. "these equilibrium solutions are: C = ARCM + RCP + XVC)(b) V (R + `R + V ) (R + AV ) - R cpRpc C Nc ARpc C1,Rpc () _— VC (Rare + Rep +'XVc) (RPC + XVp) -- RcPRpc Rc + Rcp + XVp N CCRc CM _ V _ R + AV () mw NW CMRMW Cyy-VW Rye,F+?, � (9) CF =VR �'=C�,R+hV (10) r O F where A is the yearly average rate of release of a radionuclide in liquid effluents discharged at the station. The concentration of the radionuclide in the discharge canal, CD, is p R c i c cp where Cl = A/Rcp is the initial activity (or initial concentration) of the radionuclide in the discharge canal. If the half-life of the radionuclide is very large (the 'decay con- stant is very small), the equilibrium solutions have the approximate for Cp=C1+Cc— (1 ) pc I-5 Rp (13) Cc = Cl RCM RCM RPC (14) CM =CcRM `Ct Raw C _ RMw = CF RPac (1) v, Cm RWr : R wF Rw - R�,c C = Cw r (16) OF r Equations 12) and (13) are also applicable when the mixing volumes of the pool, V and the channel V , are very small. In this case, there are k , no benefitspfrom the reduction of concentrations of radionuclides with short half --laves by radioactive decay during large volume mixing. The concentrations of radionuclides deposited on the shore areas in the lower portions of Lake Norman and the downstream lakes were esti- mated by the empirical equation3,4 CsHoxs = 100 V T1/2 CWATER (17) where C is the concentration of the radionuclide per unit volume of the waterwate al the specified location, T1/ is the if -life of the radio- nuclide and C is the concentration of the radionuclide deposited per 7 unit area on tieore sore by sedimentation from the water. Estimates of radionuclide concentrations in the channel and pool portions of Lake Norman near the McGuire Nuclear Station are given in Table I-2 One set of estimatesgiven in the table was calculated by Eqs® (11), (12), and (13), which assumes negligible or zero dilution volumes in these portions, and another set was calculated by Eqs. 6) and (7) and the assumption of dilution volumes of 3 108 and l x 108ft3 in the channel and pool portions, respectively. These latter volumes, which represent less than 2` of the total volume of Lake Norman, were used b the applicant in estimating the radionuclide concentrations in the lake near the station.5 The differences in the two sets of radionucl de con- centration are small in most cases, but the choice of these small dilutlo:, volumes is not a conservative one when the maximum drawdown of the lake was indicated to be 735 ft msl. FE Table 1-2. Concentrations of radionuclides in the channe of Lake Norman near the McGuire Nuclear! F'low rate: Discharge canal 2,9 x I Channel 2,6 x I Pool- 2,9 x I Dilution volume: Channel 3.0 x Pool 1,0 x Steady-state concentration in discharge canal = "initial in discharge canal plus concentration in char "Initial Steady-state Annual concentration" Radionuclide release in discharge Assuming no dilution by I (Ci/year) canal Channel Pool (Act MI) 3 H 2000 7.7 x 10-' 8.6 x 10-" 1,6 x 10 5 'Cr 0.08 31 X 10- 1 1 3.5 x to- 11 6.5 x 10 54Mn OA2 4.6 x 10-' ' 5.2 x 10-' ' 9.8 x 10 SsFe 0.46 1.8 x 10-" 2.0 x 10-" 3.8 x 10 5917e OAO 19 x 10-' 43 x 10-' 8.2 x 10 58CO 4.2 1.6 X 10-' L8 x 10-' 3A x 10 60co O. 12 4.6 x t0-11 5,2 x 10-' 9,8 x 10 86 Rb 0,0026 1.0 X 10-12 1,1 x to-,, 2.1 x 10 89sr 0.0024 93 x 10-" I.o x to-,, 2,0 x 10 90 Sr 0.000080 3.1 x to-,' 3,5 x 10-' 14 6.5 x 10 90Y 0.0001 1 4.2 x> 10-14 3,5 x 10-14 6,5 x 10 91 Y 0,50 1.9 x to- to 2,2 x 10-10 4.1 x 10 95 Zr 0.00040 1.5 x to-,, 1.7 x 10-13 3.3 x 10 95Nb 0.00040 1.5 X 10-13 1.7 x 10-13 33 x 10 99NIO 0.20 7,7 x to- 1 &6 x 10-' ' 1.6 x 10 99 mTcd 9's x 10-11 1,8 x 10 103 Ru 0.00028 1.1 x to- 13 1.2 x 10-" 23 x 10 I and pool portions to tion ), efs )3 Co, )3 CfS )11 ft3 )11 ft, oncentration" net oncentration ()Xi/ml) ke Assuming dilution by lake Channel Pool 8.6 x 10-" 1.6 x 10' it 33 x 10-" 63 x 10-" 11 5.2 x 10-" 9.8 x 10-" to 2,0 X 10- to 3,8 x to-10 It 4.2 x 10-" 8.0 x to-,, 9 1,8 x 10-9 3,4 X 10-' 11 5,2 X 10-" 9.8 x to-,, 12 1,0 x 10 -11 -11 ).O X ()-12 12 1.0 X 10-12 2,0 x 10-12 14 15 x 10-14 6.5 x 10-14 14 3,5 x 10-14 6,5 X 10-14 10 2.1 x 10-'0 4.0 x 10-'o 13 1.7 x 10- 13 3,2 x 10-" 13 1.7 x 10-" 3,2 x 10-13 10 5,5 x 10-" 1,2 x I0_10 ,10 6,0 x 10-" 13 x 10-" ,13 1.2 x 10-13 23 x 10-" lubRu 0,000078 10 X 10" 3A x 10- 6.4 x 10 " 3.4 X 10 * ' ().4 X 1U - 103 .. Rh 0M028 I.l x 10-13 1.2X 10-" 23 x 10-13 1.2 x t0-13 2.3 X 10-13 Jos Rh 0.000046 1.8 X 10-14 2.0 X 10-14 3,8 X 10-14 93 x 10-15 13 x to- 14 106Rha 3A x 10-14 6A X 10-14 3.4 X 10-14 6.4 X 10-14 125 Sn 0.0000026 1.1 x 10-15 1.2 x 10-" 2.3x 10-" 1.0 x to-" 2A x 10-1s 12'Sb 0,000015 5.8 x to-,, 6.5 x 10-' ' 1,2 x 10-14 4,6 x 10-" 9.7 x 10-'s 125 mTe 0.00024 93 x 10-14 1.0 X 10-13 2,0 X 10-13 I.o X 10-13 1.9 x 10-13 127 mTe 0,0019 7.3 x 10-13 8,2 x 10-13 1,6 x 10-12 8'1 X 10-13 1.6 x 10-" 127 Te 0.0019 7.3 x 10-13 8.2 x 10-12 1.6 x 10-" 8.1 x 10-'3 1.6 x 10- 12 129mTe UO 7.7 x 10-11 8.6 x 10-" 1,6 x 10-10 8.3 x 10-11 1.6 X 10-10 129 Te 0.20 7.7 X 10-" 8.6 x 10-" 1.6 x 10-'0 8.3 X 10-" 1.6 X 10-10 131 ruTe 0:0028 1�1 x to-,, 1,2 x 10-" 23 x 10-'2 S', X 10-13 1.3 X 10-"' 131 Te 0.00052 2.1 x 10-13 23 x 10-13 4.4 X 10-13 9.7 X 10-14 2.5 X 10-13 132 Te 0.094 3.6 x 1_' I 0 4.1 X 10-11 I I 7.7 x 10- 2�7 X 10 _' I 5�9 x 10 1311 0,54 11 X 10-10 23 x I0_10 4A x to- to 2,0 x 10o 3,9 x 10-10 132ta 4.2 x 10-" 7,9 X 10-1' 2,8 x 10-" 6,0 x 10-" 134 CS 2,2 8.5 x 10-10 9.5 x 10-10 1.8 x to-' 9'5 x 10-10 1.8 x 10-9 1-6 , m Table 1-2 (continued) Annual "Initial concentration" Steady-state concentration (gCi/ml) , Radionuclide release in discharge Assuming no dilution by lake Assuming dilution by lake (Ci/year) canal Channel Pool Channel Pool b Ouci/ml) 136Cs 0.74 2.9 x 10-10 3.2 x 10`'0 6.0 x 10`10 .9 x 10-'0 5.6 X 10-10 137Cs 0.12 4.6 x 10-' 1 5.2 X 10%11 9.8 x 10`t l 5.2 x 10`11 9.8 x 10`f t 137m0a 0.14 5.4 x 10-" 5,2 x 10-' � 9.8 x 10-11 5.2 x 10-1 t 9.8 x 10-11 140E 0.0026 1,0 X 10-12 1.1 x 10-12 2.1 x 102 t.O x 10-12 .0 x 10-12 140 La 0.0022 8. 10"�� 1.3 x 10-" 2.4 X 102 1.2 x 10`-12 2.3 x 10'12 141 Cc 0.00042 ` 1.fi X I0M13 1.8 x 10` 13 3,4 x 10-13 13 1.7 10` i3 3.3 X 10� 143Ce 0.000062 2A x 10`14 2.7 x 10-14 .1 x 10' 1.2 x 10-" 3.0 X 10-14 144Cc 0.00024 9.3 x 10-14 1.0 X 10-13 .0 x 10%13 1.0 x 10-13 2.0 x 10-13 143Pr 0.00034 1,3 x 10`13 1.5 X 10-13 .8 x 10-13 1.3 x 10`-13 .6 x 10`13 144pru 1.0 X 10-13 2.0 x 10``13 1.0 x 10-13 2.0 x 10-13 147Nd 0.00014 5.4 X 10-14 6.0 x 10-14 1.1 x 10Mt2 5.3 x 10-14 1.0 x 1Ct"13 147Pm 0.00002 1.0 10-1# 1,1 x 10 14 2.1 X 10-14 1.1 X 10µ1`1 .1 x 10'14 14Pm 0.00010' 3.9 X 10 )`1 4.3 x 10 14 8.2 X 10-1a .5 x 14 1�1 5.6 x 10`1a °Radioactive daughter products not listed in anticipated releases of gaseous effluents. 7 4 vi 1 1-i , ro 1-8 Data: on volumes and flow rates used in estimating the radionuclide concentrationsof downstream lakes of the Catawba River system within a 0-mile radius of the station are given in Table I-1. i a.aK E NoRMAra y x . , I ,,.COwaNs fDRp UAM �+' k ihTk NE ,~ X. / uCLE QR STATI" x -CATAWBA RNER Figure 3.8. Lake Norman in vicinity of McGuire Nuclear Station at full pond. . . ' . �:. .. ... LEGAL MIXING .. ZONE 4[MIT 1E LAKE ' ca / NCaRMAN `t SHALLOW ..._....AREA tIS5 la MSL7DISCHARGE s «+ v y. CANAL ^- — 20 t7 DROP TORO DADA (IOWANS # INTAKE > 0 xs MrGUIRE . r. NUCLEAR STATION CATAWBA RIVER Figure 3.9. Lake Norman in vicinity of McGuire Nuclear Station at a lake drawdown of 10 ft and 20 ft. 3 `4.11 RADIOACTIVE EFFLUENTS 4.11.1 L.I UIU EFFLUENTS CONCENTRATION LIMITING CONDITION FOR OPERATION .11.1.1; The concentration of radioactive material released from the site ,ration shall be limited to 2 kILITY: At all times. :he above limits, immediat limits. ,E REQUIREMENTS n 2 for radionuclides other than dissolved` lved_ r'entrained noble gases, the x 10 microcurie/ml total activity. material released from the site ely restore the concentration to within . �� I� I it {� � • w i ntai ned within the l' imi' within the limits of Specification 3.11.1.1. • IRE - UNIT 1 3/4 11-1 TABLE .11-1 RADIOACTIVE LI tllD WASTE SAMPLING AlD AIAI'SIS PROGRAM Lower Limit Minimum of Detection Liquid Release Sampling Analysis Type of Activity (LLD) Type Frequency Frequency Analysis (pCi/ml)a A. Batch Waste P P Released Each Batch Each Batch P incipa Gamma 5x1O_ Tanks Emitters 1, Waste Monitor I-131 1x1O-5 Tanks (2) P M Dissolved and 1x10-5 2. Recycle One BtchM Entrained uses Monitor (Gamma emitters) Tanks () P M -3 110-'S Each Batch b Composite Gross Alpha 1x1O 7 r P-32 1x1O-5 P Q Sr-89, Sr-90 5xlO_ Each Batch b Composite Fe•- 5 1x1O-6 B. Continuous e W Principal Gamma 5xlO�' Releases Continuousc Composites Emitters 1. Ventilation Unit Conden- I-131 1x10- sate Drain f� Tank Line; . Conventional M M Dissolved and 1x10-5 Waste- Grab Sample Entrained Gases Water (Gamma Emitters)'' Treatment Line M H-3 1xl0_ 1� Continuous Composites Gross Alpha, 1x10 P-32 1x10_5 Q Sr-89, r-90 5xlo- c Continuos Composite c Fe-55 1x10-Q McGUIRE - UNIT 1 3/4 11-2 JtN 1981 t TABLE .11-= TABU l a. The LLD is the smallest concentrat concluding that a blank observation rep For a particular measurement system (wh separation): 4.66 sb LLB = 2.22 x 10 , . e Where:' LLD is the "a priori" lower limit (as microcurie per unit mass or vo s is the standard deviation of th to counting rate of a blank'sampl minute), E is the counting efficiency (as c is the sample size (in units of! .22 x 106 is the number of transf Y is the fractional radiochemical is the radioactive dewy conta Hued) y with % probability of falsely seats a "real` signal. h may include radiochemical (-ant detection as defined above e), background counting rate or of as appropriate (as counts per nts per transformation), ions per minute t t a ♦ . counting rate or of the counting rate of the blank samples as appropriate) rather than on an unverified theoretically predicted variance. Typical 'values of E, V, Y, and At shall be used in the calculation.; RE - UNIT 1 3,4 1-3 ti nued A the method of representative C. To be represen materals,in l in proportion analyses, all mixed in order effluent r±l p batch relea TABU 4. 11 TABLE' AMMKIMISM" . • . e 'or the composite sz above nuclides, shall also be identified and reported. cGUI E - UNIT 1 3/4 11--4 RADIOACTIVE EFFLUENTS DOSE LIMITING CONDITION FOR OPERATION 3.11.1.2 The dose or dose commitment to an materials in liquid effluents released, from (see Figure 5.1-4) shall be limited: a. During any calendar quarter to les total body and to less than or equ b. During any calendar year to less t total body and to less tha APPLICABILITY: At all times. ACTION: a. With the calculated dose f in liquid effluents exceed an othpr rAnort rPntiirPH idividual from radioactive each reactor unit, from the site ,o 5 mrem to any organ, and or enual to 3 mrPm to the water supplies with regard to the requirements of 40 CFR 141, Safe Drinking Water Act. b. The provisions of Specifications 3.0.3 and 3.0.4 are not applicable. SURVEILLANCE REQUIREMENTS 4.11.1.2 Dose Calculations, Cumulative dose contributions from liquid effluents shall be d-et-e-r-m--in-e-d--i"n -accordance with the ODCM at least once per 31 days. Mc DIRE - UNIT 1 3/4 11-5 RADIOACTIVE EFFLUENTS LIQUID WASTE TREATMENT LIMITING CONDITION FOR OPERATION 3.11.1.3 The liquid radwaste treatment; system shall be OPERABLE. The appro- priate portions of the system shall be used to reduce the radioactive materials in liquid wastes prior to their discharge when the projected doses due to the liquid effluent from the site (see Figure 5.1-4) when averaged over 31 days, would exceed 0.05 mrem to the total body or 0.2 mrem to any organ.* APPLICABILITY. At all times. ACTION: . With the liquid radwaste treatment; system inoperable for more than 31 days or with radioactive liquid waste being discharged without treatment and in excess of the above limits, in lieu of any other report required by Specification 69.1, prepare and submit to the Commission within 30 days pursuant to Specification 6..2 a'Special Report which includes the following information: 1. Identification of the inoperable equipment or subsystems and the reason for inoperability,` 2. Action(s) taken to restore the inoperable equipment to OPERABLE status, and 3. Summary description of action(s) taken to prevent a recurrence. b. The provisions of Specifications 30.3 and 3.0.4 are not applicable. SURVILLAECE RE UIRMENT 4.11.1.3.1 In, the event that the liquid radwaste treatment system is not operating and liquid waste releases are being made, doses due to liquid releases shall be projected at least once per 31'days, in accordance with the ODCM. 4.11.1.3.2 The liquid radwaste treatment system shall be demonstrated OPERABLE by operating the liquid radwaste treatment system equipment for at least 90 minutes at least once per 92 days unless the liquid radwaste system has been utilized to processradioactive liquid effluents during the previous 92 days. Per reactor unit. McUIRE - UNIT 3/4 1-5 RADIOACTIVE EFFLUENTS LIQUID HOLDUP TANKS LIMITING CONDITION FOR OPERATION 3.11.1.4 The quantity of radioactive material contained in each outside temporary tank shall be limited to less than or equal to 10 curies, excluding tritium and dissolved or entrained noble gases. APPLICABILITY: At all times. ACTION: a. With the quantity of radioactive material in any outside temporary tank exceeding the above limit, immediately suspend all additions of radioactive material to the tank and within 40 hours reduce the tank contents to withinthe ;limit, b. The provisions of Specifications 3.0.3 and 3.0.4 are not applicable. SURVEILLANCE REQUIREMENTS ►tity of radioactive material contained in radioactive materials are being added to the tank. Mc UIRE - UNIT 1 3/4 11-7 RADIOACTIVE EFFLUENTS CHEMICAL TREATMENT PONDS LIMITING CONDITION FOR OPERATION 3.11.1. The quantity of radioactive material contained in each Chemical Treatment Pend shall be limited by the following expression: 264 2 : �i < 1.0 V j C excluding tritium and dissolved or entrained noble gases, where, Aj = pond inventory limit for single radionuclide "j", in curies C = 10 CFR 20, Appendix B, Table II, Column 2, concentration for single J radionuclide " ", microcurie ml V = design volume of liquid and slurry in the pond, in gallons 264 = conversion unit, microcuriescurie per milliliter/gallon. APPLICABILITY: At all times. ACTION: a. With the quantity of radioactive material in any o f the above listed ponds exceeding the above limit, immediately suspend all additions of radioactive material to the pond and within 48 hours reduce the pond contents to within the limit, b. The provisions of Specifications 3 0.3 and 3;0.4 are not applicable. SURVEILLANCE RE UIREMENT 4.11..1.5 The quantity of radioactive material contained in each batch of slurry (used powdex resin) to be transferred to the chemical treatment ponds shall be determined to be within the above limit by analyzing a representative sample of the slurry, and batches to be transferred to the chemical treatment pond's shall be limited by the expression: 6. x 105 i/ m ml where concentration of radioactive materials in wet, drained slurry (used powdex resin) for radionuclide "j", excluding tritium, dissolved or entrained noble gases, and radionuclides with greater than 8 day half-life. The analysis shall include at least Ce-144, Cs-134, Cs-13 , Co-58 and Co-60, in picocuries/gram. Estimates of the Sr-39 and.Sr-9t batch concentration shall be included based on the previous' monthly composite analysis. Cj = 10 CFR 20, Appendix B, Table II, Column 2, concentration for single radionuclide,"j", in microcuries/milliliter. McGUIRE - UNIT 1 3/4 11-8 RADIOACTIVE EFFLUENTS 3/4.11.4 TOTAL DOSE LIMITING CONDITION ,FOR OPERATION 3.11.4 The dose or dose commitment to any member of the public, due to releases of radioactivity and radiation, from uranium fuel cycle sources shall be limited to less than or equal to 23 mrem to the total body or any organ (except the thyroid, which shall be limited to less than or equal to'75 mrem) over 1 consecutive months. APPLICABILITY. At all times. ACTION: a. With the calculated doses from the release of radioactive materials in l quid=or gaseous effluents exceeding twice the limits of;Specifica- tion 3.11 1.2.a, 3.11.1.2.b, 3.11.2.2.a, 3.11.2.2.b, 3.11.2.3.a, or 3.112.3.b, inlieu of any other report required by Specification 5.9.1, prepare and submit a Special Report to the Director, Nuclear Reactor Regulation, U.S. Nuclear Regulatory Commission, Washington, D.C. 20555, within 30 days, which defines the corrective action to be taken to reducesubsequent releases to prevent recurrence of 'exceeding the limits of Specification 3.11.4. This Special Report shall include an analysis which` estimates the radiation exposure (dose) to a member of the public from uranium fuel cycle sources (including all effluent pathways and direct radiation) for a 12-month consecutive period that includes the release(s) covered by this report. If the estimated dose(s) exceeds the limits of Specification 3.11.4, and if the release condition resulting in violation of 40 CFR 190 has not already been corrected,, the Special Report shall include a request for a variance in accordance with the provisions of 40 CFR 190 and including the specified information of § 190.11(). Submittal of the report is considered a timely request, and a variance is granted until staff action on the 'request is complete.' The variance only relates to the limits of 40 CFR 190, and does not apply in any way to the requirements for dose limitation of 10 CFR Part 20, as addressed in other sections' of this technical specification: b. The provisions of Specifications 3-.0.3 and 3.0.4 are not applicable. SURVEILLANCE RE UIREMENTS 4.11.4 Dose Calculations Cumulative close contributions from liquid and gaseous effluents shall be determined in accordance with Specifications 4.11.1., 4.11.2.2, and 4.11.2.3, and in accordance with the ODCM. McGUIRE - UNIT 1 /4 11-20 0. z App. B App. B PART 20 STANDARDS FOR PROTECTION AGAINST RADIATION APPENDIX A Corvoirobv6sms In Ab sad Wrmw About Natural background tSee notes at end of appendix) _ Teblo I Table I1 Nomw (otamk numbod Isotope Column I 1 Column 2 Column I Column 2 AIr Watot Ak Water / Asfnlum(09)... _------- At227 S 2XIO`U 6X10`$ 1xW14 2XTO-°` 1 3X10_11 9X10-3 9x10'13 3XIO 1 At 228 5 4 X10`' 3 X10-3 3 x10"$ 9 X10-1 I 2XIO-1 3x10`3 6XIO`10 9X10"41 Amwitlum (95)_._..m._.. Am 241 S 6 X10-12 1 X10-4 2'X10-13 4 XIO'"', I Ixto-s SX10-1 4x10-12 3`X10-$ Am 242m S 6 XIO-12 I XIO- 2 XIO`13 4 xTO"' 1 3X10_10; 3XTo-' 9X10'13 9XTO'1 Am 242 S 4 X 104 4 X TO'3 1 5C 10 * 1 X 10-4 1 5X10-4 410-3 X 2XIO-0 IX10-4 Am 243 S 6X10`1$' 1X10-4 2XIO-13 4XIO4 I IX10"t0' SX10-4 4-X10`13 3XIO`3 Am 244 S 4xI0`s I X10`1 I xI0'F 5 X10`3 1 2X10-3 1XIO`t 4X10-7 3XIO-3 Antimony (31)__....__._ Sbt22 S 2X10-7 4X10-4 6x10`3 3XIO-$ 1 1X10-7 SX10-4 5X10'0 3XIO`3' Sb 124 S 2XIO-1 7xIO-4 3X10-1 2X10`f p� 1 2 XIO"1 7 X10-4 7x1O-70 '. 2 XI0-' td Sb 125 S 5 X10-3 3X10-3 2 xIO-11 1 X10`4 t0 1 3 xlO-1 3 XIO 3 9 X10-F0 1 XIO-a:: :Argon (10)............. A 37 :. Sub3 6 X10-3 ._. .__::... 1 X10`4 ;:. ... ..: A 41 Sub 2 x10-' 4 xIO-1 Arsontt(33).......:..... As73 S 2x10`'' IX10-1 7X10-1 5X10`"4 1 4 XIO-1 1 X10`3 1 X10-1 5 X10`4 ' As 74 S 3 xl0'3 2 X10-1 I XIO-' 5 XTo-$ 1 1XTo-? 2XTO-3 4xIO`° 3xIW-$ As76 S IX10`$ 6X10`4 4xIO" 2xTo-$ I I X 10`1 6 X 10`4 3 1 O"$ 2 xl O-$ As:77 S 3X10 t` 2xIO`1 2XI0`3 4XT0`$ 1 4X10`3" 2X10`3 IxIO`3 IxTo-$' Astatln• (93) .. At 211 S 7 XTO" S XI0-3 2 k 10 10 2 X IO-0 1 3 X I0" 4 2 X 10-S I X 10"° 7 X I O`3 barlum(36)__...__. .._. Bo13T S IX10-6 3XIO-3 4xlO-3 2XIO-1 1 4 X10`7 3 xw, I X10`3 2 X10-4 Be M S 1 X10-7 4 X10-4 4 XIO t 3 XIO-$ 1 4 X 10-$ - 7 x I O-1 1 x I0 `3 2 X I O-$ s)lum(97)__.._r..__ 4k249 S 9XIO-10 2X10'3 3 tO`t1 6XIO-1 ' I 1 X10`3 ; 2 XIO'3 4 x1O`'f 6 XIO-1 :. Ilk 230 S IXTO`T 6XIO"3 5X104 2XIO-1 I 1X10`' 6X10-1 4XIO"$ 2XIO-4 Soryfflum Bo7 S 6X10`4 3XTO-$ 2xIO'* 2XIO-1 I I X 104 5 X 10`3 4 x I O-1 2 X I O-S Bismuth(93).._ __:.__.. 1112 S 2X10`7 IXTO-3 6xlO-' 4X10_5. 1 1 X10-7 1 X10-3 5 is10-1 4 X10-1 ; ITT 207 S 2 X10`3 2 XIO-3 6 X10:'0 6 X10`4' I I X I O"s 2 X 10 "3 5 X 10-10 6 x 10-$ 51210 S 6XIO"* 1 X10-3 2x)0-10 4XIO`$ I 6 X10`° 1 X10-3 2 xIO-10 4 XIO-1 01212 S 1 X10`3 I X10-3 3 X10 3 4 XTO_' I 2X10-7 1XW? IxIO-'t 4XIO-4 20-15 December 30,1982tt } ( PROTECTION AGAINST RADIATION Arf'EFi01X e Contentratlons In Air and Water wove Natural eatkWound—Contlnuod CSoe . notes of end of o x) table I tokto 11 8tomont (otomtt numbe0 leotop t Column 1 Column 2 Column t Column 2 Air Water Air Wolof tc�f�7tuft}(,cf�t�fcll> t t 8ramine (35) 8r 82 S 1 X10`4 6 X10`2 4 X10`2 3 x10-1 l 2xlo_2 1X10"Y 6xto`1 4X10I Cadmium : (46) Cd 109 $ S x10_o.:. ' 5 X10-1 2 X10`1 2 x10 t 1 7xto-1 5x10-2 3X10`t 2X1o' Cd llsm S 4 X10`0 " 7 X10'"' t x10"t 3 x1o"° 1 4 X10`9 7 X10"" t X10'1 3 X10"1 Cd its $ 2X10-7 1 X10-3 4X10_1 3X10-2 1 2X10-' 1X10`2 6X10"1 4X10`5 Cattlum (20) Co 45 S 3 xto-, 3 X10-1 1 X10-t 9 X10-1 I 1x10"7 5X10'3 4x10`0 2X10' Cc47 S 2x10-7 1X10-2 6X10`1 5x1o's 1 2X10..2 1X10-3 6X10-t 3X10'2 Californium (98) Cf 249 S 2 X10-1' 1 X10`' 5 Xt0-1' 4 X10_1 I I X10-14 . 7 X10-1 3'X10-12 2 x10-2. Cf 230 S 5 x l0"12 4 X10_4 2 X10-t2 t X10-1 s? I 1 X10`91 7 X10—' 3 Xt0"12 ' 3 X10' s Cf 251 S 2 x10-12 1 X10-1 xlo-w, 4 X10*° t 1X10"to 8x10"' 3X10"12 3xto-1 Lcr L Cf 252 S 6 Xf0 r1 2 x10`' 2 X10-t2 7 X10'*Ul)' yR I 3 xto'" 2xto`' I x1o"`t2 '., 7.X10 C4 Cf 253 S 8 x10`t° 4 X10-' 3 X10-11 1 X10 t 8x10-'p° 4X10`2 3X10`tt 1x101 Cf 254 S 5 X10`12 4 Xto-t 2 X10`t2 1 X10`r I Sx10-12 4X10-1 2X10" 1X10"1 Corbon (6) C 14 S 4 X10-' 2 X10-2 1 X10-7 8 X10-1 (CO2) Sub 5 X10-1 1 X10`6 Cortum (58) Co 141 S 4 x1o`' i 3 x10-1 2 x10_t 9 x10- $ 1 2X10_1 I 3X 0"2 5X10`t e' 9X10-1 Co 143 S 3 X10`7 1 X10-3 qxlo-1 4 X10-3 1 2x10-T I 1X10"2 7X10"'t 4X10'$ Co 144 5 1 X10- 3 X10' 3 X10-te ; 1 X10-1 1 6xto-' ° $X10`' 2X10`10 1X10-1 Coolum ($5) Co 131 S 1 xto-f 7 X10-2 4 X10"2 1 2 X10"1 ti 3x10-4 3X10_2 1X10"7 9x10- s 134m S 1 4 X10-1 6xw' 2 X10-1 3Xto`2 1 X10-A 2X10-7 a 6 X10`1 1X10-3 Cs 134 S 4 x10-4 { 3 X10`' 1 X10-t 9 X10-1 I 1 xto-, 1 1 X10`2 4 X10 t° ( 4 X10-1 CS 195 S 3 x10-1 i 3 x10-3 2 x10`1 ; t 10`1 1 9x10-4 7x10`2 3x1o`t 2x101 Ge 136 S 4 X10-7 2 x10-1 1 X10`1 . 9 xlo-$ 1 2X10'2 2X10`2 6X10- E 6x10 s Cs 137 S 6 x10-0 4 X10`" 2 xIo`t 1 2 x10-1 I 1X10-1 i 1X10-t Sx10'1A 4x10"t Chlorin (17) Cl 36 S 4 X10-7 2 X10-2 1 X10-1 I a X10-1 1 2xl0`$ 1 2X10`2 •X10-1®.:. 6X10-1 C136 S 3X10-1 1X10-2 9xto`4 f 4X10`1 t 2 X10-1 1 X10`2 7 X10'0 4 X10-' Chromium (24) Cr 31 S 1 X10-1 3 X10-2 4 xto'T ' 2 X10-2 1 2 X10®t 3 X10_2 8 X10-1 2 X10-1 oftember 30,1982(reset) 20-16 App. B App. PART 20 • STANDARDS FOR PROTECTION AGAINST RADIATION APPENDIX B Coneo am Its AM and Above Natural Eaekvrovnd_C*mfnved Mee notes at end of•appendix) Toblo 1 ; Table If somw { "Mono} 1 1 Column 1 j :Column 2 i Column 1$ Column 2 Air �*W Ak Water / (27) Ca $7 S 3 x10-4 3 XTO-2 ( 1 X10"7 E S X10-4 E 2X1Q"7 1 1-2 1 6 Xt0"* k 4 X1Q-4 Co Sam S 2 X10-3 l X10-2 E 6 XTO-7 ( 3 x1Q'3 1 9X10-4, 6X10-2 3Xto®1 t 2xT0'1 Casa a 9XTd-1 4X10-3 3X10`1 1jj 1X10-4 T SX10`r 3XtQ-1 2x10'1 E 9X1Q'1 Co 60 3 3 X10-1 t X10-4, 1 X10`1 S x1Q®1 1 9X10'* III 1X10`4 3X10`10 3X10`1 (24j Cv64 S 2X10`6 1X1Q'#- 7X10-1 3Xt6"4 cw4v$K (96} : Cm 242 1 S 1:X1Q-4 1 X10`10 6 XTQ`4 7 X10`4: 4 XT0'1 4 X10'11 2 x10'4 2-Xt0-a 1 2x10-t# 7X10-4 6X10`11 2X10-s Cm 243 S 6 XIQ 11 1 XtQ'4 2 x10-11 I S 10-4 T 1X10-10 7X10-4 3X10`11 2xIO-1 Con 244 S 9X1Q'14 2x10`4 II 3X10`11 7X10""# 1 1X10`1k i aX10"4 3Xt0`11 � 3X10`1 Cm 245 s S XTo-', ' : 1 X10-4 ; � 2 xt0'11 4 XIO-# U. 1 1X10`10 aX10`1 ! 4X10`11 3X10-1 Cm 246 S S X10-11 T Xlb-4 2 XIO 11 4 X1Q`1 l 1 Xto`1# IT X10®4 4 X10`11 3 X10-$ Cm 247 S S XIO-12 1 X10-1 2 X10`14 4 X1Q`6 t T XT0'1# 6 X10`4 4 Xt0`11 2XTO-1 Cm 248 S 6XTQ'11 1 X10-3 2 xTQ`11 4 X1Q-1 I. 1 X10"1t 4 xtQ`1' i 4 Xt0`14 1 Xto`# Cm249 S 1>X10®4 6X10-1 4X10®1 2X10`3 um {66) by 16S 1 S 1 XTQ'S 3 XTQ`* 6 XTQ"1 1 X10�-`4 4 X10`7 9 X.10"1 2 XTO-3 4 X10`4 l 2 XtQ"# 1 X10-1 7 XtQ_# 4 X10-4 dy164 S i 2xTQ'1 TXt0'4 aXTQ`* 4Xt0"1 11mintlalum, Q99I 11253 1 a 2XT0`1 a XtO-10 1X10-3 7 X10 `4 7X10--* 3 X10-i1 4X1Q"'4 2 Xt0' 4 1 6x10'10 7x10", G 2x1Q'11 2TQ-1 Es 254m S # X1Q"* S XTO" 2 XTO 1* 2 XTQ" 3 # 6XT01 3XtQ`4 2X10`1# 2X10-1 Ee2S4 3 2XtQ"11 4X1Q`1 6x10 11 1Xt0-1 t T X10`t# f ; 4 X10'4 4 XTQ'11 1 X10-1 Es235. 5: 5XIO-11 aXW: 2Xt0 t1 3X10'1 E 4X10`1* aXIQ': 1X10-11 I 3X10"'4 #um(6a) E1r169 S 6X1Q`1 3X10'1 2X10 r i 9X1Q 1 t 4X10"1 3XT0`3 :. 1X10-1 1 9x10'1 Er171 S 7X10-1 3xTQ 1 2X10'# I 1X104 swolelvat (63) 1v 132 1 s 6 X10'1 4 X10' 7 > 3 x1Q"4 ( 2 XIO-1 2 X10.1 1 x10`i 1 1 IO-a 6 rt0 1 (T%2=9.4Tura) 1 3Xt0-1 2x1Q"11 f 1 x10 # 6XtQ 1 Eu132 S 1XTQ`1 ( 2X1Q'4 4x101Q? ax10`1 (Tf2=13yrs) 1 2X10"1# E 2X10'4 r 6X1o"it . ax10 1 to134 S 4x1Q'? ` 6xtQ-" 1X10"t#i 2X101 1 7Xt0"* 6x10'* 2x10't* 2xtQ`1 Eu1S$ S 9.. - 6X10'1 3X10* 2x1Q-4 1 7 lQ"# 6x1Q`3 3X10"* I 2X10-4 C 20-17 December 30,1982(reset) pp. B Appr ' PART 20 • STANDARDS FOR ' ROT CTIO AGAINST RADI TI ► APPENDIX 9 Coneentrat(one In Air and Water Above Notwal Baekgravadr- Co"flnusd (See notes at and of a rAx) 1 i Element totemic number} I*otopt I Co1u { d 9 Table It nn 2 Column I :Column t 1 7XlO"1 4x10®1 ' 2xlO'-1 1X10`4 Fm 255 S 2 X I O-# P I X W1 6 X I0-14 3 X 10`I I I X10-1 I XIO"1 4 XIO`Ie 3 XIO`I Pm 256 S 3 xiO`* 3 XEO`t I X10-14 9 X10-1 1 ! 2xIO"1 3XIO 1 III 6xW11 9X10_1 PluorlaM (9i . P Is $ {� 5 XIO-1 2 XIO-' 2 XIO-7 E XIO-' l 3 XIO-1 i I XIO'' 9 XIO"* 5 X10`' Otodollnlum (64) Old 153 S 2 x10 "p ( 6 xtO-$ It x10"* 2 X10'-1 l 9x10-1 6XIO`I I 3xI0"' 2X10-1 od159 S 5X101 1 2XIO`I ( 2x10_I axw1 1 4 XIO-1' 2 XIO-1 1 XIO-1 a XIO-1 alum (31) qa 72 S 2 x10 7 1 XIO-1 S XIO- { 4 XIO-- 1 2 XTO°"' 1 I XIO-1 6 XIO- i 4 XIO`I m Oerefdom (32) .. 4o 71 S I xlO-$ i S X10`I 4 XIO-7 i 2 XIO-1 0oW (19)_. I Au 1% 1 S 6 XIO"1 I xIO`"° ! 5 X10-1 E 5 x10`I 2 XIO-1 4 XIO"1 { 2 XIO`I 2 XIO'' I 6 xlO-1 4 xI0_I I 2 Xl0`I I I XIO-1 Au 194 S 3 xi0"' 2 x 0`I I x10`* 5 xTo-$ ev I 1 2 XIO-1 1 I X10'1 + Y x10"* 5 X10-S Au I S I X 10`1 S XIO-1 4 3e 10"* 2 x lO-1 1 AT x 1O"? i 4 X IO'1 3 X I O`* 2 x 10"' Halalum (72) ITT I II I S 4 X I O"* 2 x i 0" 1 i X I O* 7 X lO'1 1 7X10-1 2X10'1 I 3XIO`* 7x10`$ Helmluen (671 - I ire 166 S 2 XIO"' 9 XIO`' 7 X10-4 3 XIO-$ Hydrogen (ij It3 1 S 2 X10"1 0 S X10_,1 9 X10-1 I XIO 6 X10"* I 2 xl0-I f 3 X10`1 3 X14-1 1 5XIO-* IXIO` ? 2X1O'' 3XIO"1 1 $ab 2 X10-3 4 xl0'1 Indlam (49) In 113m S IT XIO-1 j 4 XIO-1 ` 3 X10-1 1 XIO-' 1 7 X10`4 2 4 XIO-1 "t 2 X10-1 t I X10"1 I In 114m S I XIO-1 ' S XIO_' 4 X10" ( 2 X10'-$ I i 2x10-4 1 SXIO_' 7X10-'0 2X10'r In I ISm It 2 xto-* I x10`1 t 6 XIO'* 4 xl0`4 III 1 I 2 xTO-* I X10"1 6 x10`4 4 x10®' In113 S I 2X10-7 ; 3xT0'1 +4xIO-t 9x10"I t `•" IV XIO-1 1 3XtO'1 I IXW* 9xTO-$ lodlne (33) 1 12S S 5 x1O"° 4 XTO's 6 X10-11 2 X10_7 1 2 xiO`' 6 X10`3 6 Xt0'* 2 X10`I 1 126 5 aXIO ° 5X10-1 9x10-11 3X10-1 I 3x10-1 3x10"1 Ix10"f (4 4x10_$ 11 129 S { 2x10`* 1 xIO 1 2X10- 6X10-# 1 7X10`1 1 6X101 2x10`* 1 2xt0'' 1`131 S 9XIO"1 6xto_1 1XTO"1* 3XIO-' 1 3x1O" 2x10"1 1X10`* 1 6xt0-, 1132 S 2xlO-1 5 2x1O-1 3x10'* 1 0x10'4 f 9x10 1 1 5X10-1 j 3xTo- ± 2x10`' 1133 S1 3 xIO'* 2 xt0'' ! 4 X10"I* XIO_' XIO` 1 i 2 Xt0, I XIO-1 I T x10* 4 x10'1 1 1 134 S _ 5 00-1 4 x10-' I 6 X10i1 r 2 X10"1 et} 20-1$ App. B pp. B PART 20 STANDARDS FOR PROTECTIONAGAINST RADIATION APPENDIX 8 Concontrattans in AM and Water Abava Natural Background—Cansinvad (See : not" at and Y1 apper4x3 Table 1 l Tabta 0 Element (aromle number) Isotope 1 Column i I Column 2 Column l Column 2 Air Water a/ Air Wow : y f: [ y. lodine(33)__.-------- 1134 1 3X10`4 2xW-1 IX10-7 6X10-4 1 133 S 1 X10"7' 7 X10-4 1 Xl0"* 14 Xl0'* 1 4 X10"7 2 X10"1 1 X10-9 7 X10-S Irldium (77)....m w_v._. _ or 190 S 1 X10-6 6 X10'4 4 X10"4 2 xW4 1 4 X10" 1 3 X10-1 1 X10`4 2 X10-4; lr I"5 1 X10`7 1 X10"4 4,X10 t 4 Xl0"4 1 3 Xto--t ` 1 X10'e 9;X10" 1a 4 X10`4 lr 194 S 2 X10-7 1 X10`1 a X10'"t 3 X10"1' 1 2 X10-1 9 X10-4 5 X 10't 3 X 10-4 Fe $5 5 4 X10"7' 2 Xi0'2 3 X10-4 a X10_4 l 1X10'4 7X10`t 3X10"4 2X10"'3 Fe 59 S 1 X10`7 2 X10-11 3 X10'1 6 X10"t t 5 X10-4 2 X10®4 2 xl0't S X10-s (Krypton (36).__.. a.e KraSm Sub 6X10`4` 1X10`7 Kr;3 Sub 1X10'4' 3Xlll`7, Kr $7 Sub 1 X10`4 2X10"4 Kr 84 Sub 1 X10_4 .... _ 2 X10`1 Y.Loothenum (S7)..... . . to 14 S 2 Xl0`7 7 X10"4 3 X10't I 2 X10`4 et1 i 1 X10-1 7X10-1 4X10`t I 2X10`4 Land (a2).. ,. _ Ph"203 S 3 X10-4 1 Xl0`2 9 xi0`4 4 X10`4; 1 2 X10`4 1 X10"1 6"Xl0'°4 4 X10'4 Ph 210 S 1 X10-14 4 Xl0'4 4 X10`1t 1 X10`7 1 2X10'1e 5Xt0`4 8X10-12 2X10`4: Ph 212 S 2 Xl0'4 6 X10`4 6 X10-14 2 X10-$ 1 2X10't 5X10-4 7X10"10 2X10""4; to 177 S 6 X10'7 3 X10`3 2 X10'4 1 X10-4; 1 5X10-7 3X10`* 2X10't 1X10'4; Mangan•!e (2$). , Mn 52 5 2 X10`7 1 X10" 4 7 X10`1, '. 3 X10"'t.- 1 1 X10-1 9 X10-1 3 X10'"t 3 Xl0`4 Mn 54 4 S 4 X10""r 4 X10'1 1 x10 4 1 X10-4 G i 4X10`1 3X10"4 l X10., 1 X10"4 { Mn 56 5 a X10®7 4 X1G"7 3 X10-4 1 X10' a:: 1 3 X10-1 3 X10®4 2 X10-4 l X10®4' Mercury(80)___.:--. _ He107m S 7X10"7 6X10"1 3X10'°4 2X10-4' 1 aXtd--'' 3X10'1 3X10-9 2X10'4 Hg 197 S 1 X10`4 9 X10"4 4 X10`4 3 X10`4 1 3 X 10"4 :' 1 X 10'"t 9 X l*-'4 : 3 X 10'4 : Hp203 5 7Xl0'4 3X10`4 2X10-# 2Xl0'4 1 1 X10-1, 3 X10`1 4-X10i0 1 X10-4 Molybdenum (42). Me 49 S 7 X10-1 5 X10'4 3X10'4 2 X1ti`4 1 2 X10`1 1 X10-1 7 X10", 4 X10'4 Neodymium (60) . , ... m Nd 144 5 a X10-11 2 X10-1 3X10`12 7 Xt0`4- 1 3X10`10 2X10"4 1X10"11 axio-4 NO 147 S 4 X10®7 2 X10"4 1 X10"1 6 X10-5 1 2X10"/ 2X10®1 4X10-t 6XtO'4 NO 149 S 2 X10-1 a X10`1 6 x10"4 3 X10`4 i 1 X10`1 a X10-1 3 X10'4 ;: 3 X10-4" 0-19 i December 30,1982(r ) App. PART 20 + STANDARDS FOR PROT APPE1i Concentrations In Air and Water Abe [Sae notes at end Element (atomic number) Isotopy a Cato t � t (}CI Neptunium (93) Np237 S 4 ) 1 15 Np 239 S 6 1 c77 Nitkal (211) Ni 59 S " S' 8 Ni 63 S 6"# 1 3" NI6S S 9 f 1 S; Nloblum Nb 93m S I (Columbium) (41). NF 95 1 S 27 S { Nb 97 1 S I: 6 cc Osmium (76) Os TITS S S i U. 1 S Os 191m S i 2 1 9. S 1 �Os191 1 i 4 Os 193 S II 4' 1 1 3 palladium (46) 1 Pa 103 S I Pd ld9 1 S 7" 6 1 4 Phosphorus (15) ! P 32 $ 7 i I a Platinum'(76) # PI'191 S a 1 6 1 Pt 193m S 7 1 1 S �} l Pt I93 s t I 3 Pt 197m S 6 PI 197 1 S i S 4 1 6 Plutonium (94) ( P. 236 S 2 P. 239 1 S i 3 2 t 4 Pu 240 S 2 1 4 P. 241 S 9 1 4 :TION AGAINST RADIATION Apt. B e iatural BatkOround—Continual pe"KI Table I Table It n 1 Column 2 Column I Column 2 i .Air Water 'ml),(Pci/mIj(PC /ml.} ( Ci/M ) 1-1-1- 1 10-12 9 X10"4 I X10-I3 i 3 X10`6 0-10 9 XIn-4 4 X10-t2 , 3 XIO`5 10 1 I 4 X10"° 3 X10"® 1 X10"" in-7 I a VIA-1 h via-$ i 1 xtQ-. 2 X1O, 4 . 2 X 10-3 3 XIO"4 7 X10`1 1 XIO`4 A heV � ro.I eer t Xt0"7 1 S-XIO'r I 4 XTO`' 3 X10-3 j 2 XIO-6 I I XIO-4 3 X101 I 3X10-1 1 X10-1 3 X10-2 2 X10-1 ' 9 X10-1 3X10`1 i1 2X10-7 ' 9XIO'' 2 X10`1 2 XIO-1 1 7 XIO-S 2X10'7 2XIO'r 7XIO-7 7X10"7 6X10-7 3XIO"3 7 XTO-7 3 XIO-7 2 XIO`7 5X10'4 4xTO`$ j 2XIO" 5X10-1 tX1O"s 2XIO"4 2 XW-3 I i X10-1 j 6 X14 1 2xl0_3 � 9XIO"° t 5X10-t IX10'7 5:X10-6 3XIO1. aX10-3 ( 3XIO"4 3XIO' 3X10"3 2XI0 6 9XIO`' 2Xt0`7 I XIO s : 7X10'7 SX10"4 2XtO-9 2X10`§ 7XIO'4 3xTO"r 2XIO 4XIO'3 3XIO'* IX1O' 3 <10 ' 4.­10 r 9 . 10 ' KtO r S <10 t I.y10 r i 2 .10 s XIO`6 3XIO`7 r 2X107 IX107 xlO_4. 3 xTO`2 'i 2 X1O�7 :. 9 XiO'"; X1O`J 4 X10-1 3XIO ` i 1 X10'4 X10-1 1 3 XI#1 s 2XIO r j I x10"r X10-i1 I X10 4 j 7XI6 #a k 5X10 b. X10-11 I 8XIO"' I I XIO tl7 3X1O 5 Xto 12 i 1 X10 ' 6X10"1' S X10 6. X10 If a 0"' 1X20"I 3xt0 i X1O-11'2 ) t XIO ' 6X1O 14 S x1O a. x10' a x10 ' I XSO-Ix 3 .e10 $ x10 t4 7 x*O 1 '"3 x00 �7 2 xtO.':'. X10-1 4 X"tO ' 1 X10'r I X10 riber 30,1982(reset) 20-20 App. B FART 20 *STANDARDS FOR AP C00,96ntrattnnt In Air and Water Isoo notes }t i ilsmrnl (atemic: numhor) :: Isotope t Plutonium (94) Pu 242 s ' I Pv 242 s i Pu 244 ' s Nionlues (44) Pa 210 $ I Polasslvm (19) K 42 s I prosoodymium (39) Pr 142 1 1 Pr 143 s r 1 Pr othivm (611 Pm 147 " 1 1 Pm 149 s U. Pr ettnlum (91) Pa 230 I s � Pe 231 I 3 I Pe 233 s I Radium (Yi) Re 223 3 I Re 224 3 I Re 226 3 I Re 229 1 1 IOTECTI©N AGAINST ADIATIt, App. ENDIX a ,bovo Natural Eaekpraand—Can#Hued t 8n4 Of SMOMW table I Tablo I1 1 � r Column I I Column 2Column i Column 3 Air Water Air i Water pCi/ 1)�(yC /M1)()l i/1111) (pa/mi) 2 XI0't2 1 7d10'' 1 6 XIO-14 3 4X10`1t 9X10:: 1 I110-1t 3X10`1 2X10+ IX10-t 6X10", 3X10`4 3XI0ry6 IX10- aX10- 3X10"' 2X10-12 1X10-1 6X10-1" 4X10 r 3 X10-11 3'X10"' 1 X10"11 1 X10`1 3X10-10 2Xt0-' 2X10"11 7X10"r 2X10-10 SX10"4 7XIO-12 3X10-1 2 X 10-4 9 X 10-2 7 X 10-1 3 X10-4 1X10`1 6X10-4 4X10"'1 2X10`' 2X10®r 9X10-1 7X10-# 3X10`3 2X20"1 9X10'' 3X10-w* 3X10`t 3 X10-1 I X10-1 1 X10-1 3 X10" 1 2X10-1 IX10-r ( 6X10`1 3X10`' .^.. tX10`r 4A1V - 6X10 2 : 6A— 3X10-1 .A— 2X10`4 3 X10'2 I X10-1 1 X10`1 4 X10`1 2 X10"2 1 X10"2 + 6 X10-f 4 X10'' 2X10"* 7X10-2 6X10`11 2X1 "r EX10-10 7X10`2 i 3 X1011 2X11Y4 IX10-1t 3X10"$ 4X10`1" 9X10"1 t vsh-:d III a v1n-4 f v i —12 II 9 -In-$ Radon (Y6) Re 2" $ 1 3 X tin 2223.: *ws **03 3 Rhonfam (73) Re 163 1 3 X 1 2X Re 1R6 S 6 X 1 2X No 147 s 9 X: 1 3x IN198 1 4 x 1 2X Rhod v t (431 Rh 103m s ! x 1 6 Rh 103 s # x 1 3X Rubldlum (37) Rb $6 s 3 X I I Rb 67 s 3 x 2 X 70'•:.. 1 1 X 14 6 X10`1 � I X10`1 6 X10`11 7 X10'r 6X1 -11 4X10-* 3 X 10'11 3 X 10u2 2Xt0 t 3X10`s 2 X10tr 3X101 I X10`ss 3 X10'1 I X 10, 3 X 10'1 9 X10`# 6 X10'" e: m 1 I 7 XI'0'° I S X10-1 I 2 X10`r I 2 X10"' 0-1 December 0, 1932{reset} App. B PART 20 STANDARDS FOR PROTECTION IO AGAINST RADIATION App. B APPENDIX s Concentrations In Air and Water Above Natural Sockpround—ConNnNed 1 :motes at end of slut Table I i Table If Element (atomic number) Isotope, Column I �(( Column 3 1 Column I Column 2 Air { wow At Water t (),gCif Mj- .(,p .'iiit1j�(pU/it11. + + B ( cihi1l). Ruthenium (44) Ro 97 S 2 x10_6 Y 1 X10-2 + 3 X10'1 4 xlO-'t 1 2x10-t 1X10`1 6X10-1 3X10-1 Ru 103 5 3 X10-1 2 x1O-1 2 x10-4 A xI0"S I ItX10-t 2x10"1 3XIO`t 6X10`t Ito t0$ 3 I X10`1 3 X10-1 2 X10`t I X10-4 t S X10-7 3 X10`' 2 X10-1 1 X10 4 Ro 106 s ! x10-t 4 x10-4 3 X10-t 1 X10-' 1 6 xw* 3 x10'' 2 X10®16 I xio-s Somodam (62) Sm 141 S 7 xl0'tt 2 X10`1 2 xi0" t1 6 xI0'' 1 3 xI0`10 2 X10-1 9 X10" t2 7 x10"' Sm 151 S 6x10-9 1X10'1 2X10-9 4x10' I 1 X10-1 I X10-1 3X10"9 4 xI0-4 Sm 133 3 S X10`7 2 XIO`1 2 XtO`t It X10"' 1 4 x10-1 2 x10-3 1 X10-4 I1 x10-' 3candlum (21) Sc 46 S 2 X10-) , 1 X10-3 � • X10`tt 4 xlO-$ 1 2 x10 I X10- t X10 a 4 X10 Sc47 S 6X10-1 3X10'-1 2X10-0 4x10-.' � t f 5X10-1 3x10-' � 2x1O-t 9X10-' ut i Se4• S 2X10-1 6X10-4 6x10"t 3X10"3 .s ra F 1 ¢ I X10-1 E X10-4 ; S xI0 t 3 X10-1 t Selenium (34) St 73 s I x10`t 9 x10 1 4 X10-t { 3 XIO 4 1 1 X10_7 it X10 1 4 X10-t f 3 X10`4 S11lcon (14) $1 31 s 6 x10-t 3 X10-1 2 X10'1 P 9 XIo-, I 1X10`1 6X10-3 3XI0.t r 2x10-4 $liver (47) Ali 105 s 6 xI0-1 3 X10-1 2 XIO`t I X10-1 I i X10-1 3 X10`1 3 X10-r $ I X10-4 AS floor S I 2X10-7 9X10'" 7x1O`t 3X10`' I 1X10`t 9X10-' 3X10-Ie 3X10`' Ay M S 3 X10-1 I x10-1 I xtO-t 4 X10-1 I 2 xl0`1 I X10-3 If x10`t 4 xIO-' sodlum (11) Na 22 3 2 x10'1 I X10"1 6 X10`t 4 x10-1 1 ( 9X10`1 9x10-4 3xIO-10 3x10'' Na 24 S I x10`t 6 XI0-a 4 X10-t S 2 X10-4 1 ; 1 X10`1 8 X10`4 S X10-1 j 3 X10-° Strontium (311) St tam S 4 X10' 2x10`r 1 X10-1 7 X10-1 I 3X10-5 2X10-1 IX10`4 7x10-1 sr Its 2XIO-1 aX10-3 8 X10-1 I xlo-. I 1 X10 `1 S X10`3 4 X10-t 2 X10-4 Sr 49 S 2 x10-4 3 x10-4 3 x10-tt j 3 xlO' I i 4 X10`' It X10-1 iii I X10-1 ii 3 x10-' Sr 90 S I X10-9 I X10-' 3 X10-11 3 xI0'1 I S X10`t I X10-1 2 XIO-10 4 X10-5 St9I S 4xt0`1 2x10®1 2X10-4 7X10"' I 1 3910'1 ( I X10'3 9X10`t S X10-1 f Sr 92 s 4 X10_7 i. 2 X10-3 ' 2 X10-1 7 X10""1 t 3 xto-1 ` 2 xto-) I X10-0 6 X10-5 Sulfur (16) ' S 35 S 3 X10"1 2 X10-1 9 XIO-t 6 X10-3 ! ( 3 xI0 1 S X10-1 9 x10-t 3 x10'4 tantalum (73) to I92 S ! 4 XI0`t III I X10'' I X10-0 4 x10`' I 2X10-t 1XIO't 7xl(I-W 4XIO®1 December 30,1$82(reset) 20-22 ` ''" PART 20 STANDARDS FOR I Apt Cow"oftotloas lot Air and Water (Soo notes i App ROTECTION AGAINST DIATI+ N. " N#X 6 bovs ►Aata# 6achgrouni-Csntinuod "W Of opwdxl Tout* 1 Tabb 11 . !)omoM (atomic numborl Isotope A Column 1 l Column 2 ! Column 1 ; Column 2 i } Air }; Wow Air Water t X10-3 TaehooNum (43)- _ Ts gam s e X1o`6 4 X10-1 3 x10-6 1 3X10`6 3X10`' 1 X10'6 1 X10'2 Ts 3 6X10`1 3X10'1 2X10"* 1X10'* 1 2 X10"t 1X10"1 IX10"* 5X10 0 Ts 97m S 2 X10-* I X10"1 4 X10"6 4 X10'4 1 2X10-7 3X10'3 3X10-* 2'X10-4 Tt 97 3 I X10'6 5X10`1 4XI0 t 2X10`6 1 3X10-7 2 X10`1 1 X1'0-6 4 X10"; Ts94m 3 4XI0_6 2X10`1 1X10-6 6X10'6 1 1X10-'6 4X10`t IX10`1 3 X10-3 Ts99 3 2X10"* IX10`1 7X0'-* 3X10", 1 6X10`6 3X10'1 2X10'-v 2X10-1 TstturlYm(321._... .-_ To123m 3 4Xl0`t 5X10"1 1X10"i 2Xl0`* t I X10"1 3 X10-I 4 XI®-* I X10"" To 127m $ 1 X10"t 2 X10`1 5 X1'0`r 6Xt0"6 1 4 X10-* 2 Xt0-6 I X10`* 5 X10`6 To 127 s 2X10-4 4Xt0-6 6XIO-1 3XI0`4 ii 1 9X10-7 5X10-S 3X10`6 2X10-1 u" To 129m 5 4 Xt0'* I X10`6< 3 X10`* 3 X10-3 N 1 3X10-6 6X10-1 1X10--r 2X10`6 To 129 3 S X10-4 : 2 X10'2 2 XIO-,' I-'X10`* 1 4 X10`* 2 X10"1 1 X10-1, I X10`4 To 131m s 4 XTO-? 2 X10"1 1 X10-1 6 X10`6 1 2 X10-7 I X10-1 6 X14'* 4 X10'6 To 132 S 2 X'10-1 9 X10`4 7 X10-9 3 X10_6 1 I X10`7 6 X10-4 4 X10-1 2 X10-1 T•rblum (63). _ .. � . _ "_ Th 160 s I- X10-1 I X 10'1 I x to'-' 4 X 10"6 I 3 XI0""* 1 X#0®6 1 XTO-f 4 X10'6 Tha111um(4I1-_n_.-•.'--. it 200 3 3Xt0"'* 1X10-2 9XW" 1 4X10'6 # 1 X10-4 7 X#0 6. 1 4 X10"6 2 X10"* n2Q1 3 2X10`6 9X10`6 7X10'6 3x10-1 I 9x10-7 3 X10`*; 3 X10'* 2 X10'' it 202 3 4 X10"7, 4 x10"'6: 3 X10"'* I 1 x10'* 1 2x10_7 2X10`6: lX10 r 7x10-6 T# 204 3 6 X10')r 3 X10";. 2 xlO'* I:x10" 1: 3X10`6 2X10`6. 9X10'A* 6:X10`6 Thsatuml90l-. ... + Th227 S 3X10"t* SX10`4 1X10" 2X10`6 1..: 2X10"1* $X10"° $xio-'% 2X1006 Th228 s SX10'76 2X10"1 3X10-cs 7x t0'6 1 6X10-11 4X10-4 2X1:0'16 1X10`6 To230 5 2X10`A2 5Xt0'$ SXIO-14 2X10'6 1.. :1Xt0'1A :. SX10"1 3X10"la 3X10`6 ♦ Th 231 :S 1X10`6 7X10-1 SX10`1 2X10`6 1 1Xt0-* 7Xt0"1 4X1.4 6 2X10-4 Th232 S 3X10`A° $Xto`$ 1X10`16 2Xto-, 1 3Xt0-1 9 1X10"6 1X10"A6. 4X10`6 ¢s Thniluri/ S 6XTo'AA 6X10`g) 2X10"°91 2Xtd-6 6X10'IA 6X10"& 2X10`°6 2X10'6 0-23 December 30,198 {reset} Apt B App. B PART 20 STANDARDS FOR PROTECTION AGAINST RADIATION g APPENDIX a ij Cont#nkations to Air and Water Above Natural Background-»CuMinutd [Soo testa* at and of appandO ...� �_._. Table, I { Table 11 Element (alamlx numbor) t Isotope, a Column 1 wmLL Column 2 Column 1 Column 2 Air Wat)®r Ak Water i t f /M1)(}9�..�.#ti11)(vCi/it 1j (11cii/Ml.) 1�1�il. Thorium (90) Th 234 S 6 x10`* 3 x to--' � 2-XIO-`* 2 XID I 3X10`' 3X10`' 1x10"* 2XIQ1 Tbaliam (69) Tan 170 1 4 x10 ° 1 XIO'1 t x10"+ S X10 1 3 x10"1 1 X10-1 I xIO'* $Xt0 1 I'm 171 S 1 x10"1 1 X1 't 4 X10-f S X10®1 'p a 1 2 x10'7: I XI0-1 iii i.X10't 3 X10`^.. ,Tin(30) So 113 S 4X10.1 Y 2X103 a 1XIO'* 9x1O 1 1 3XIO"° Y 2X10-'1 2x10®* 3x101 fSo123 S IX10_r 3x101 I 4x10`* 2X10`1 j 1 ! *X10`4 5X10-1 a 3X10`* i 2XIO"1 Tungsten (Walfram) (74) 1 W lit S 2x10-6 1X101 ; sx10'* p 4XI0'' 1 IX10`I 1X10-* i 4x10-* j 3x10'1 133 S t X10®r 4 X10"1 3 XIO'* I X10-1 I I X10`? 3 X10`1 11 4X10- I x10'" 1417 1 I 4X10-1 2X10`1 i2 X10-0 7X10-1 I 3X10'r i 2X10"1 j 1"X10`* 6x10"1 Uranium (92) U 230 1 3 X10-#° ' I x10"' E I xt0`At j 3 X10 4 I t X10`10 I X1014 4X10"11 S XIO'*' U 232 1 1 X10`1* ! XIG`1 3 xt0'12 3 xIo-, ram+ 1 3 X10-11 ' I X10-1 9 xto ,$ i 3 XIO-3; U 233 S 3 XIO-14 9 x10-4 2X10"11 ' ; 3 X10-1 1 I IX10-10I 9X10`4 4X10't1' 3XIO-" ** U234 54 6XIO-10 9X10`1 2XIO"11 3X10-1 I IX10-14 I 9xw, 4XIO-12 3X10`1 MsU 235 34 3XW14 3X10`1 2x10`11 ': 3X10-1" s I IX10-441 aX10`1 4XW" i 3X10'5 U 236 S 6 X10-14 ' 1 X10-1 2 X10-11 . XI*-$ i 1 X10`r4 1 X10`* 4 x10`12 3 X10-1 If* U 213 34 7 X10-11 I X10'* 3 xw1* � 4 x10`$ 1 1 X10-14 I XW1 S X10-1, III 4 XW$ C U 240 S 2 X10"1 I X10"* 4 X10'* 3 X10..1 1 2X10-r 1X10`1 6X10"* axt0-$ 99 »naW t S4 1 X10`14 I X10'1 SxI0'1* 3xto-$ 1 1 X10-r4 I X10-1 SX10-41 3 X10'1 Vanadium(23) v 48 S 2X10_r 9x10`1 6X10-4' � 3X10-1 I 1 6X10'* 3X10`1 2XI*` 3X10`1 Xenon (34) Xo 1311" Sub 2 x10"1 & 4 X10`7 p Xo 133 Sub 1 X10"1 3 XI0 ' i Xa 133m Sub 1 x10-° 3XIO 1 X• 133 Sub 4 xlO"* I x10 1 a Yttsrblum (70) Yb US S 7 XIO-1 3 x10`1 2 XIO'• I X10-1 1 6X10'r 3x10-1 2XIO"* 1X10`4 YMrlum (39) Y S I x I O `r 6 X10-1 4 X 10`* 2 X 10`* t 1X1O'I 6X10`1 3X10'* 2X10'1 Y 91m S 2x10'1 I X10-1 aX10'1 3X10"1 1 2 X10-1 I X10-1 6 x10"1 3 X10`1 Y 91 S 4 x10-1 3 10`"1 I X10`* 3 X10-t 1 3 x10-1 a X10-1 I X10-4 3 xto-$ Y92 S ,4X10'1 2x10"1 IX10'* 6XIO`1 1 3X10`1 2x10`1 IX10-4 6xlO"* Y 93 S 2 XI0`7 $ X10-1 6 X10-9 3 x1O'1 t IX10-1 4X10-1 3X10-1 3x10..1 December 30, 1 982{reset} 20- 4 Ap B App. B PART 20 STANDARDS FOR PROTECTION AGAINST RADIATION APPENDIX d Concentrations In Air and Water Above Natural Background-Conttou*d ( } Tobto I Table It , i Element (atomic number) Isotope r Column I Column 2 Column I Column 2 j Air We. ; At, i(u i/ (11Ci/ml)(-tC i /e111 ( Water (J}Ci/cal) Zinc (S0) Zn 65 S ( I X10'' 3 X10"3 d 4 X10"'s I XIo ' 1 6 Xid's S x10's 2 I0`s 2 X10`' Zn 64m It 4 x10'1 2 XIo:" ± 1 Xtoo s 7 Xto-$ 1 ( '3 XI 'r 2 X10-2 ( 1 X10`1 6 X10`3 Its 69 S IX10`s l 3X10'2 2X10'7 I 2X10-3 1 9 X10-* 5 X10-1 3 X10'r 2 X10`1' Zkconlum (40) Zr 93 S I X10-1 2 X10`t 4 X10"+ S X10-4 b' 1 3 X10'7 2 X10`2 1 X10-4 :3 X10-4 Zr95 S IX10"r 2X10'1 4x10`t 6Xle`s 1 3 X10`4 2 X10-1 I X10 * 6 X10`s Zr 47 5 I X10`7 S X10-1 4 X10'11 2 X10`"s 1 9X10's 5X10`' 3X10`s y 2X10-1 tvAny single radionuclide Sub I X10"4 j 3 X10-s f net listed above with I decay made other than j alpha *mission or spontaneous fission t and with radlaactiv* I j hate -III* last then 2 hours. j Any single radionuclide 3 Xi0`s 9 X10-1 I X10-10 3 X10`6 net listed above with l decay mode other then alpha •tttlsston or spontaneous fission and with radioactive { hall' -life grander than 2 hours. Any single rodlonuelddo 6 X10'tt 4 XI0 t Y 2 XI0 t" t 3 X10-s not If red above* which 1 decays by alpha *tuts- I sion or spontaneous r i , • 'Soubit,(8);Insotubwit}. ,"Rub" moans lust values given *ro for submersion in a *Amended 37 F'k 233t9. t 4. $or soluble mixtures at XI-238, it-234 m: , infinite cloud of airborne matennt. and t7 285 In air chemical toxicity may ba the "Amended 39 YR 23990, footnote re- ing factor. it the percent by weight (en- designated 40 Fit 50904. si ent) at U-2$6 1* Ion than b, the eon. *"Amended 44 FK $0704. *Themradon oonoentratious ap pri- eentration valve for a 40-hour workweek, Table r, Is 0.2 ntilligr um per cubic % to ended 38 b'k 29314. eta for protection from radon-222 combined meter, of air avenge. Vur any enrichment, $Amended 39 Fit 25463; redesignated with Its short-lived daughters. Alternatively, the product of the average oiancentetiitan and 40 I- k .50904. the value In Table f may be replaced by one- time of exposure during a 40-hour workweek third ( ? "work level." (A ; "working level°* 1s defined as any, bination of shorn* sholinot fix 8 10-t �cCl-hriml,'whom r av the x fdc activity of kilo uranium in. C lived radon-222 daughters, alum-218, as lead-214* b ath-214 end po -214, In M haled. The coneentristion value for Table it to u. C007 MUIIV—uranium cnbie motor of one Ilter of air. without regard to the degree* per U. ibri the o activity for natal uranium that t la to : on of S.3 xl(PNOV of alpha of ' ha a Is 6.77X10-s U. specific ' pwUde e .) The le n value y Ins ivitr for other mixtures at U-23E, 1U-235 1 replaced by tbirit ' (klw) of • "working and-23; if not known, abs11 be: I. The t on one Wens - 3.0 10-* cur/gram, tT 1 -deq In o y be on an an- -(0A+0 X+0. W) 10-s Bzo. noel *"rap. where E Is the n by weight of 11-235. { i exp as porcenk tit,,,...... 20-25 December 30, 182(reset) Alp. App. ` PART 24 • STANDARDS FOR PROTECTION AGAINST RADIATION NOTE TO APPENDIX B 3. rf any of the conditions specified below I;ors: In any where there is a mixture in air or are met, the corresponding values'specified water of more than one rsdionuolide, the limiting values below may be used in lien of those soecMed for Purposes of this Appendix should be determined w% in paragraph 2 abovc foi}owst a. It the identity of a radionuclide in i. If the Identlty and concentration of each radionu. the mixture is known but the conosntrat0 €lids in tits mixture are known, the limiting each ran of one or more of the radionuclides in the should be derived as"folloers. Determine, for each ra- dionuclidein the mixture, the ratio bet weerthequantlty a Is not kno oon tion ppresent In the mixture and the limit otherwise estsb• lfmit for the mixture is the t specified lishad in Appendix B for the specific radfanuchde when Appendix for the radionuclide in ilea m not to a mixture. The sum of such ratios for all tit€mixture 11a the lowest oOncGntraton 1L radionuclides in the mixture way not €xoe€$ '°i" (f.€.« � °•nnitY"}.: u'limit,• or : ry ErAxrtx: If radionuclides A B, and C are present9 b. If t^e identity of each onuende in in concentrations CA, a, sn$ Glc, and it the applksble the is not known, but it is known NPC"s« are NIPCA„ and NIPCs, and ?APCc respee- that certain r4diolluclides specified in Ap- llvelY, then the concentrations shall be limited so that pendix ..B.. an not present in the ure,. the to relationship exists: the concentration limit for the mixture is CA + OR CC 91 the lowest concentration limit Specified in 'a1PCA i1PCa i:PCc Appendix "A" for any radionuclide which is . It either the xi 0"Ir 5r ttw rormntrw1"t, of any not known to be a nt from the :or ra Ilonv.-ilde i i ",i:a.ure G no. knu,vn, the luniting cola€, for pur1K ,.' ,Avitendtx 13 shall be: CC a. For purposes of Table I, Col. 1--S X 10-10 b. For purpo.es of "Table I. Cal, 2--4 X 10-1 p c, For purposes of "Table 11, Col. 1---2 X 10-1" d. For purposes of Table U. Col. X 10-4 O ta. o. Element (stomio number) and isotope Table I Tabu 11 Air (AClhnl) Air (ACffxdl) Water 4Water) ( If it Is known that Sr pl, 1 lie, 1 126, 1 129, 1 131, (1133, 11 At YaI231,t t23, Ra 10, Th�'i3u,, Tb- Ral2 Ac 227, PTh,g2, nat, Cm 248, CI 254 and Pm 256 are not present .. ........... It it is known that Sr 90,1 125, 1 126, 1120, it 131, 1 133, ... 9XI(t't ------------- SX104 table It only) Ph 210 Po 210 Ra 223 RA 22d Re, 229, m Pa 231, T`h nat Cm 248 C(254 and Pm are not present_ .. .................... 1 1131, table 11 __ $XI0 t 2XI04 If it 3a known that Sr 90 1129 (I t25 106, only), Ph 210 Ra 226RA 228Cm 248 and Ct 254 are not present ........:..... .:........ ._...... 2Xltt s __- ._......... axio r if it is known that {1129 table 11 onty) Ra 220 and Ra' , 228 are not present ._ ......... .............. Me If It is known that alppha•emitters and Sr 90 1 129 Pb 210, Ao 22i Ra 228 Pa 230 Pu 24I and Bk 240 era not '. . 3XI" 1XI0-1+ li 3t is known € and Pb 210 Ae Ica 228, and Pu 24t are not nt........:........... .: u 2 1 are t pros 3XI0^n ... .......... 1Xi0^11 ..::..._.___.« It It is known that alpha•omitters and At M an not present-.,.. .... .-............ .. - 3XI0-n 1XI0`15 It it is known that At 227Th 230, Pa 231Pu 238 Pu 239, Pu 240« PU 242, Pu 244 Cm248. Of 249 and C f 25f on not.. present.................................... .... 3XIO-0 -------------- IXI0--s -------------- C If a mixture of radionuclides consists of uranium and its daughters In ore dust prior 0 to chemical separation of the u um from u7 the ore, the values specified below may be u:usedfor uranium and its daughters through radlurn-226, instead of those from paragmphs 1, 2, or 3.above. a. Forp of Table 1, Col. 3-IX30-de "Cl/ml gross alpha activity; or 6 X 10-- act/ mI msturst uranium; or 76 m1orogromax per 14 cubic meter of air natural uranlum. tr b. For purposes of Table n, Col, 1--3 X 10-u u. sCitml gross aephs, activity; or 2 X 10-u ACII 0 rel natural uranium.. or 8 micrograms per (_ cubic meter of air natural urWUUUL 6. Far p of this *bit, a 10-; nuclide y be considered as not present in a mixture if (a) the ratio of the Miam mt"s- tion of that radionuclide in the mixture (CA) to the concentration limit for that: radionuclide specified in Table It of Ap- pendix 11 (6(P A) does not exceed Us 0C U.(i.e, ' �) wad (b) the of such MPCA -10 cv satos for all the radionuclides considered as not present in Use mixture does not "toe Y4 CA L"x ° + ... PCx. .JF December 30,1982treset) 20-26 App. C DART 20 tr STANDARDS FOR PROTECTION AGAINST RADIATION A noix c rear Any alpha omitting radionuclide not listed, above or mixturseof Material Microcurtes lum-191rn 100 100 alpha smitters of unknown kmerS€ium-241 - Antimony-122 01 100 0amlum-101 0smium-19s ---. 100 position _._®- __ .01 tr Any rwilonuelldo other thanalpha ------------------ Antimony-124 10 Palladlum-103 100 U. emittingradionuclides, one listed Antimony-126 _ 10 Palladlum-109--,---._..----------- 100 above or'mixtum of bets a90t- Arsenic.7s 1 Pla -__:_-----_- :----- 10 iari of unknown composition--- 1 " Arsenic-74 _ Platinum-1912 Platinum-191 - 100 Arselai€ 76 __ Arsenic 77 10 ; too Platinum-193m - -- Platinum-198 100 too its" Now. —For purposes of 1 2"M where _ $urn 131 .. 10 Platinum-197m _ too t ; there is involved a1 b of to in ttirium 13.t .,.. to Platinum-197 --- _ Pluton$rn-210 t 01 «a n'°, ; known amounts. limit t combination Sarium-140 sti Polonium-2t0 ,.. ..,. 0 1 should be derived a: follows. Determine, for Bismuth-210 . _ I Pot ium-42 _ 10 p„ a each isotope to the comb►nati the ratio Bromine-62 _ 1I Praseodymium-142 - 100 s. between: quantitythe tin the Cadmium-100 Cadmium-115aax 10 10 Pray ymum-142 '- 100 combination and file t otherwise Cadmium-116 ------- ----------- Calclum-45 - _ - 100 100 10: Promathlum-147_ Promethlum-14 ----------------- Radium-220 "` 10 10 01 0 established for the in combination. specific isotope when not Tfie sum of such raliaas for all Calcium-47 _" 10 _ Rhentum-166 """ 1 the Isotopes in the combination may not fK Y ____ Carbon-14 ___.. 1iS0' ---- Rhenlum-1186 "'' 1 exceed1"(i.e. ty"� Cerium.143 -r 100 ..,..._. h um-108 l oo -.---- Cerlii -144 _» I ..->-_.->-.-_ Rh ium-t06----- ------------ 110 Cesium-131 _ - L Rubidium-86 - Rubidium to 10 Cesium-1341n 100 ; Ruthenlum 97 210 Cesium-134 "' - 1 ------------------ Cesitga l35 .-.._______________:._.. 10 Ruthenlum-108 Ruthenium-i05------------------ 10 IQ Cesium-136 ---------------------- 10 Ruthenium -too -.--..------------ 1 Cesium-137 -_--__--__®_---_-- _ 10 Samartum-161 "_-" 10 Chlorine-36 _--_- 10-: -.---_-- 100 Chlorine- 8---------------------- 10:Scandium-46 ----- .------------- 10 Chromium-61 _— -------------- 1,000 Scandium-47 --- ---- 100 Cobalt-Sam10 -_- - Scandl -48 .. _®._ 10 Cobalt-$$ --- ------------------- 10 Selenium-75 _---..-.----_-_--.__. 10 halt-60 ------------------- -- 1 Silicon.31-_-.-------._-.- - _ -- 100 Copper-64-m--------------------- 100 Silver-106....................... 19 Dysprosium-1 5 ----------------- 10 Silver-110m------ ---------------- I Dysprosium-186 ----------------- 100 Silver -III ___---------- ---... 100 Erbluin-169 _:------------------- 100Sodium-24 ---------------------- 10 Erbitim-171 --------------------- 100 Strontium-65-.--.-.--.-_ -_---- 10 Europittin-152 0.2 b-------------- 100 Strontium-89-------------------- 1 ev Ettrop}tim-152 13 yr _ i Strontium-90 0.1 Etiropwin.i54 ________________;:__ I Strontium-91 ...._.:_.___-------- to Cc Europlum.156 ___.,.-.. __._--_-_. 10 CC Strontium-92-------------------- 10 u. fluorine-18 - ------------------- 1,000 w. Sulphur-35-.-..---.------------. 100 Gadolinium-153_________________ 10 "Tantalum-182 ------------------ 10 Gadolmitim-1 9----------- I0wo T chnetturn-96------------------ 10 Galli tnl-72 __«_..---------------- 10 Technetium-97m--.---__-- _-._., 100 Germanium-71 ------------------ too Techuati -97---------------- 100 Gold-108 ----- ------------------- 100 Technettum-99m ---------------- 100 Gold-i99 ------------------------ 100% Technettum-99-.--_._--.----_--_ 10 HariAltuaa-181-------------------- 10 Tellurium-125m ®_:-_-_-_. ,._®__- 10 Holmium-166 ___________________ 100 Tellurium-127m ----------------- 10 Hydrogen-3 - ------------------ 1,000 Tellurium-127-------- _---------- 100 Indicant-)131n-------------------- 100 Te}lurlorn-129m----------------- 10 111dimu-114m-.._.__.__r-____-.--- 10 Telluriu -129 ------------------- 100 Indium-115in _________________s_- 100 Tell urium-l3lm----------------- to Indium.115 _____________________ 10 T"ellmlum-132 -..-._____- ----. t0 Iodine-125 -- ---------------- -. i "Terbium-160--_---------_----- t0 ludine-ate ______________________ 1 'Thallium-200 -------------------- 100 lvdalle-129...................... 0::1 "Thathum-201 .................... :too Icdaaae-131 ---------------------- 1 "Thallium-202 ------------------ 100 lodine-132 .. ---------------------- 10 "Thallium- 04 ____.u________ _____ 10 lodino-133 ______________________ 1 * orlum natural)x-_----:--__-. Ste} loduae-134 ---------------------- 10 Thulitim-170 -------------------- 10 lodine-1 5 ---------------------- to 10 °Thullum-171 -------------------- 10 lrid}aim-192 --------------------- 10 Tin-113-----___.«-___m_-®------ 10 Indium-194 ______________®_ ---- 100 Tin-125 :W----------------------- 10 lnol-"55 _____-_--®--- ---------- 100 '1'uuasten-lal-------------------- 10 lrot­59 ------------------------- 10 'Ttwg.ten-185 _-_-a__---_ ----------------- 10 xr4ptola-as _« : 100 Ttingsten-187 __--- _ _.. 100 Krypton-87 _____________________ 10, #Riiranlum ........ too Lanthanum-140 __.._r.____._.- _ 10 Uranwin-213-__:-.._------------ .01 Lutetium-177 ------------------- 100 Ur.niuto- 34- Uranlum-235 ------ .01 Ala^aranese-52-®__-.-_.-_».--_ --- 10 Cian:aditim-48.................... 10 Manganese-54 _------------------ 10 fen 11-131ut »..------------------ 1. 000 Man}ranese-56 --------------- :__ 10 7 enon-1 2 _._ ._ -------------- too Wer€tary-197m------------------- 100 Xenon.135 ---------------------- 100 Alerciiry-197 --------------------- 100 Ytterblum-175.......::......... 100 Merc fry-203 _-._-____.>____-__- _ 10 lttrinm-90 ___.--:__------------ 10 Alntcbdentaln-99______________ __ 100 Yttrium-91 ---------------------- 10 N _______ __ gaxaStlm-147 ______ 1tXt Yttrium-92 _.__.:____._-.--___-- 100 Neodcmium-149 ---- 100 'Yttrium-93 _.____:® __.-- ___-_ Zinc-65 -. 100 10 rR on alpha dials lion rate of on * of Ut Nicke4 59 _.-: _ Mekcl 63 too 10 ------ Zinc-69m -_- 100 T11Jess, T and Chair daughter u. 6 p __---------------------- Nickel-65 100 Zan€-69 -.. _____..:: ____.:-_.__>_.1; 1 $ on alpha disintegration rat* of ._.._:.___. N}rihlciln-93m -__. ____.,_______-._ 10 Zirconium-93 _____ ____________.._- 10 1I-238, U-234, and U-285. Mohttam-95 10 Zirconium.-95 ::_.. _.__-::....______-- 10 � Anieaitlo:d 36 FK 16899. ---------------------- Zir€ontum-97 -------------------- 10 KK° Amended Jai VK 23990 0<mium-185____________________ 10 20.27 December 30,1932iresetf PART 20 • STANDARDS FOR PROTECTION AGAINST RADIATION APPENDiX D,--UNiTED STATES NUCLEAR REGULATORY COMMISSION REGIONAL OFFICES ' Adolresses IT (24 r8) rAO- 1: oN1eCfim t; Delaware, Disbid at Columbia: Mains, USNRC, $31 Park Averwo, King of (215) 337-SM Murylanda M kt9, shire, Now , Now Pmmsia, PA 4 (FTS) 488-1000 Y Islanrt VarMont m ti. F , GOwgii, K i , North USNAC, 101 Marietta Street NW, (404) 331-4503 ua RsM T ssoe, VVsr Suite 29W Atlanta, GA 30323. (FTS) 242-4 m and wast veginik' 0: ROOM Of' Gir ' Iowa n, tK Mmoun, USNRC, 798 Roosvelt Road. Glen (312) 790- LL OW. end Wisoonsin. Ellyn, IL 60137. (FTS) Region IV*' K RC, 611 Ryan Plau Drive, Suft (817) 100 i Moxiotl, ta, OkW=W SO4th 1000, Arlington, TX 76011. (ITS) 7 100 Toxw Mak end WWnlng ' Region IV: w. „;: ,..USNRC, Region IV Ur R000very ) 236-2805 F' Office, 730 k (ITS) 776-2805 P.O. Box 25W5, Denver, 00 W225. Region V. ' a ak Nevada. Oregon, USNRC, 1450 Maria Lww, Sift 210, (415) 3700 Pacft Trw T W4 Wa aMut Crook, CA 0459& (FTS) 3700 October 31, 1986 20-28 cooling water. To enhance the detector perfori ing it at a lower temperature, the continuous of the component cooling water coolers. The r, tive concentrations monitored is from approxim� mately 1 x 10 2 pCi/ml. To preclude the relea in the event of cooler leakage, an interlock f a valve that normally vents the component cool ance and reliability by operat- amples are obtained downstream ige of gamma emitting radioac- tely 1 x 10 5 pCi/mI to approxi- ? of volatile fission products )m the radiation monitor closes ig water surge tank to the 11.4-5 12/83 source is incorporated to verify the operation of the monitor, Abnormal conditions of high activity or loss of sample flow are alarmed in the Control Room. The setpoint for high activity is adjustable over the full range of the instrument. The operator has sufficient indication to determine heat exchanger tube Failure and can isolate the defective heat exchanger before significant activity is released. 11.4.2.1.8 Containment Ventilation Unit Condensate Drain Tank Monitor The containment ventilation unit condensate drain tank monitor is provided to continuously monitor the activity of liquids discharged from the CVUCDT to the plant "discharge `header. The monitor consists of an off-line lead shielded Nai' scintillation detector identical to the conventionalwaste water treatment monitor. The monitor is interlocked to chose a valve on the discharge of the drain pumps o insure liquids will not be discharged with activities in excess of limita- tion defined by Appendix B of 10CFR2 , including dilution. The receipt of an alarm' will alert the operator to insure the discharge valve has shut and to evaluate if processing by the liquid waste system is necessary. A flow propor- tional sampler is also installed on the drain line of the CVUCDT. Thisar- rangement permits monitoring of the flow as well as radioactivity of the discharge. 11.4. .1.9 Boron Recycle Evaporator Condensate Monitor The baron recycle evaporator condensate monitor is provided to continuously monitor the boron recycle evaporator condensate downstream of the filter. " Normally, the condensate will be routed to Reactor Makeup Water Storage Tanks. On a high radiation alarm, valve 1NB219 will divert this flow to the boron recycle holdup tank. 11.4.2.2 Airborne Monitorin Airborne activity process radiation monitoring equipment (Table 11.4.2-2 summarizes continuous monitoring equipment that is available. By monitoring ventilation systems, which remove air from locations where systems containing' radioactivity are housed, for airborne activity, indications and alarms indica- tive of a loss of integrity of these systems are provided. Monitors provide Control Room information regarding personnel access limitation to areas within the station during normal operation or anticipated operational occurrences. These areas include Reactor Containment, Auxiliary Building, Spent Fuel Build- ing and Control Room.` The monitors also provide information and alarms regard- ing airborne activity releases from the station. Control of airborne activity releases is based on laboratory analysis. The Containment Purge, Containment Annulus Ventilation, Auxiliary Building Ventilation, Condenser Air Ejector, Fuel Pool Ventilation, and other poten- tially radioactive systems such as sample hoods discharge through the unit vents. The unit: vents are continuously monitored for airborne radioactivity. Effluent flow rate monitors installed on the unit vent stacks are used for calculating discharge rates and/or total activities discharged as required by Technical Specifications. The airborne process radiation monitoring equipment. 11.4-6 1984 L )d to E` TABLE I1.4.2-1 Page 1 of 2 I LIQUID PROCESS RADIATION MONITORING E UIPMENT DETECTOR DETECTOR TYPICAL RANGE DESIGN NUMBER IDENTIFICATION LOCATION FUNCTION TYPE SENSITIVITY COUNTS/MINUTE SERVICE 1- MF-31 Conventional Wastewater Turbine Bldg. Monitor effluent to Nat Scint. 3x1O8 cpm per 101 - 107 Normal Operation Treatment Monitor EL 741 conventional waste- pCml Cs-137 Gross Gamma I-C- 4-25 water treatment system. Stop turbine room pumps and terminate discharge on high alarm when turbine; room pump align to conventional waste- water treatment system. I-EMF-32 Steam Generator Blowdown EL 716 Monitor effluent and Nat Sant. 3x108 cpm per 101 - 107 Normal Operation Recycle Demineralizer FF, GG-3 terminate discharge on pCi/ml Cs-137 Gross Gamma Effluent Monitor high alarm I-EMF-34 Steam Generator sample EL 716 Detect Steam Generator Nat Sant. 3x108 cpm per 101 - 107 Normal Operation FF-55,56 tube leak, and terminate pCi/ml Cs-137 *10' - 10e Gross Gamma sampling I-EMF-44 Containment Ventilation EL 716 Monitor effluent and Nat Scint. 3xlO8 cpm per 101 - 107 Normal Operation Unit Condensate Monitor BB 50 terminate discharge can pCi/mI Cs-1 7 *101 - 10e Gross Gamma high alarm I-EMF-45A Nuclear Service Water EL 733 Detect Containment Nal Scint, 3xIO8 cpm per 101 _ 107 Post LOU 1-EMF-4 B Monitor JJ-55 Spray Neat exchanger pCi/ml Cs-1 7 *101 - 106 Gross Gamma tube failure I- MF-46A Component Cooling EL 750 Detect Neat exchanger Nat Scint. 3x1O8 cpm per 101 - 107 Normal Operation 1-EMF-46B Water Monitor GG.56 leaks pCi/ml Cs-137 Gross Gamma 1-EMF-47 Boron Recycle EL 733 Monitor and divert Nat Sant: 3x1O8 cpm per 101 - 107 Normal Operation Evaporator Condensate MM 56 evaporator condensate pCi/mI Cs-137 Gross Gamma Monitor I-EMF-48 Reactor Coolant Monitor EL 716 Detect Fuel Clad Nal Scint 8x1O3 cpm per 101 - 107 Normal Operation EE, FF-54 Failure pCi/ml F.P. Gross Gamma *High Range (Shielded) Mf+P TABLE 11.4.2-1 Page 2 of 2 l LIQUID PROCESS RADIATION MONITORING EQUIPMENT DETECTOR IDENTIFICATION LOCATION' FUNCTION DETECTOR TYPICAL RANGE DESIGN NUMBER TYPE SENSITIVITY CQUNTS/MINUTE SERVICE 1-EMF- 9 Waste Liquid Monitor EL 716 Monitor effluent and Nal Scant. 3x108 cpm per 101 _ 107 Normal Operation KK, LL-56,57 terminate discharge on GM pC1/ml Cs-137 *101 - 10e Gross Gamma high alarm 2-EMF-31 Condensate Wastewater Turbine Bldg. Monitor effluent to Nal Scant. 3xlO8 cpm per 101 _ 107 Normal Operation Monitor EL 741 conventional waste- GM pCi/ml Cs-137 Gross Gamma U=28 water treatment system. Stop turbine room pumps on high level alarm 2-EMF-32 Steam Generator Blowdown EL 716 Monitor effluent and Nal Scant. 3x10$ cpm per 101 _ 107 Normal Operation recycle demineralizer FF GG-57 terminate discharge on GM pCi/ml Cs-137 Gross,Gamma effluent monitor, high alarm 2-EMF-34 Steam Generator Sample EL 716 Detect Steam Generator Nal Sc'int. 3x1O8 cpm per 101 - 107 Normal Operation monitor EE, FF-57,58 tube leak and terminate GM pCi/ml Cs-137 *101 - 106 Gross Gamma sampling 2-EMF-44 Containment Ventilation EL 716 Monitor effluent and Nal Saint. 3xJO8 cpm per 101 - 107' Normal Operation Unit Condensate Monitor BB 62 terminate discharge on GM pCi/ml Cs-137 *101.- 106 Gross Gamma high alarm -EMF-45A Nuclear Service Water EL 733 Detect Containment Nal Scant. 3x1Q8 cpm per 101 - 107 Post LOCA 2-EMF- 5B Monitor JJ-57 Spray heat exchanger GM pCi/ml Cs-137 *101 - 10e Gross Gamma tube failure 2-EMF-46A Component Cooling EL 750 Detect heat 'exchanger Nal Scint. 3x108 cpm per 101 - 107 Normal Operation 2-EMF-468 Water Monitor GG 56 leaks WCi/ml Cs-137 Gross: Gamma 2-EMF-48 Reactor Coolant Monitor EL 716 Detect Fuel Clad NaI Scant. 8x103 cpm per 101-- 107 Normal Operation 4 EE, FF-57,58 Failure pCi/mI F.P. Gross Gamma f *Nigh Range (Shielded) 1. G OFFSITE RADIOLOGICAL MONITORING 'PROGRAM During operation of McGuire Nuclear Station, small amounts of radioact materials are released to the environment from releases of low level g and liquid waste disposal ;operators make in accordance with NRC regula and the Technical Specifications. The design and operation of the'rad waste 'systems maintain the quantities of 'radioactive materials release s reasonably achievable and within regulatory limits. The objective m t• f .• i; f m• t» if f m naturally occurr)*nQ radioactive materials in his own body, from food, water and air intake): The variations from time to time of the naturally occurring and the manmade components of background dose (consisting of radioactivity in air and water) are to be expected based on differences in area and local climatology inclu- ding windspeed, temperature, barometric pressure, rainfall and runoff condi- tions, etc. For example,: the concentrations of naturally occurring radio- active radon gas may varyconsiderably at a given location depending on the weather; the greater concentration being encountered during inversion conditions: The average of terrestrial gamma background measurements made at the McGuire location indicates the variability from place to place: 11.6-1 183 Calculated whole Distance from body gamma dose, an (as designated in Table 11.6.3-2 Site mrem/year Within Site and Exclusion Area 44 Exclusion Area Boundary & Hwy 73 35 Ramsey Creek Access Area 3.4 miles NE 44 Westport, Golf Club 4.9 miles NNW 132 Cowan's Ford Country Club 1.1 miles WNW 70 Homes on Shore nears Discharge Area 0.5 mile E 38 Huntersville 6.2 miles ESE 35 Beatty's Ford Road 3.7 miles SSE 26 Lucia 4.8 miles SW 70 Cornelius 5.5 miles NE 53 Hick's Crossroads 1.8 miles ESE 53 ncentration of activity in the Catawba River below the station, from 1 and manmade sources, has been reported as follows: Gross Beta on RtgaELed By Dates Activity pCi/I tte, N.C. N.C. Department of Human Resources 1968 3. Radiation Protection Branch 1969 <3.00 1970 <3.00 1971 <3.00 ncentrations of activity in milk samples near the site have been re - as follows: 90 137 on Reported By Dates Sr CS pCi/1 FC i _71 tte, N.C. N.C. Department of Human Re- 1968 10 12 sources 1969 12 12 Radiation Protection Branch 1970 12 12 1971 10 <17 t radioactivity from nuclear weapons and radioactivity from other installations contribute an extremely small fraction of the average )n dose due to natural background radioactivity (for example, perhaps as 0 ( 031 millirem per year is contributed from other nuclear ?s). 3 CRITICAL PATHWAYS the amounts of radioactivity added to the environment from station i are minimal and as low as practicable the possible critical exposure to man have been evaluated in accordance with Regulatory Guide 1.109 to estimate the dose to the hypothetical maximum exposed individual, as to establish the sampling requirements for the Offsite Radiological )g Program. The pathways are: 11.6-2 12/83 1. Submersion in air (gaseous effl 2. Inhalation 3. Consuming milk and other dairy gaseous waste effluents. fts from locations affected by 'n areas or on feed affected by ig along the shore of Lake Norman. -ake Norman affected by radioactive flrectly associated with this portion ? Norman affected by radioactive i included in the Offsite Radio - )cation 24 hours per day, 365 days per year. PRE -OPERATIONAL RADIOLOGICAL MONITORING PROGRAM ?-operational phase of the Radiological Monitoring Program for McGuire - ng methods,- ------ ­z7_-- ' frequ'ency of sampling, analytical procedures,and somewhat ctly, laboratory instrumentation. This program provides surveillance of itical exposure pathways to man and satisfies legitimate interests of mpany, of the public, and of the state and federal agencies concerned he environment. These agencies include the N.C. Department of Human ces, Radiation Protection Section; the Environmental Protection Agency; e U.S. Department of Interior, Fish, and Wildlife Service. e-operational Radiological Monitoring Program is described in full in the McGuire Environmental Report -Operating License Stage. OPERATIONAL RADIOLOGICAL MONITORING PROGRAM erational Radiological Monitoring Program provides surveillance and support of detailed effluent monitoring which is necessary to evaluate dual and population exposures and the ecological significance, if any, 11.6-3 12/83 of the contributions to the existing en result from station operation. This monitoring program is based on NRC ized Radiological Effluent'Technical Sp media,'! sampling locations, sampling metl ticl sensitivitv requirements. This o tal radiological levels that al "Investigation of Natura 13(1960) 1959, pp. 11-12. 4 Y ! -1 MW to ,ith regar RMATIMMUMM California, Lawrence Radiation Laboratory,, October 1972., 11.C- 13 Tabu 11.6.2-1 Estimated Doses Concerning Critical Pathways to Man for Radion5c11Tdes Releases to the Environment Airborne Related Pathways mremlyr 1. Submersion (all ages -skin) 0.75 2. Inhalation (infant -thyroid) 0.58 3. Milk (infant -thyroid) 1.7 4, Vegetation (child -thyroid) 0.77 Water Related Pathways 5. Lake and Shoreline Recreation (teenager -whole body) 0.00 6. Water (infant -thyroid) 0.53 7. Fish (adult -liver) 0.59 12/86 Tables: 11. .3-1 (1 of 3 through 3 of 3) 11 > .`-2 11.6.3-3 DELETED 1985 Update Table 11.6.6-1 ExaTples of Analytical Sensitivity Versus Permissible and Discharge Cana]—Con-centrations A. Releases into Water Discharge Caoal Con- Caul Concentration Permitted b Sensitivity — by AEC Regulations of Analysis Radionuclides pCi/ml pCi/ml PCi/mI Tritium 1.9 x 10-6 3 x 10-3 2 x 10-9 Sr90 3.3 x 10-14 3 x,10-1 1 x 10-9 CS137 4.4 x 10-10 2 x 10-5 1 x 10-9 C060 1.5 x 10-12 5 x 10-5 1 x 10-8 1131 4.1 x 10-10 3 x 10-7 1 x 10-8 B. Releases into Air Radionuclide 1131 3.7 X 10-14 1 x 10-10 1 X 10-14 a See Table 11.2.8-1 b 10 CFR 20 Appendix B, Table II Limits 12/83 T""�Pc 3/4.12 RADIOLOGICAL ENVIRONMENTAL MONITORING 3/4.12.1 MONITORING PROGRAM LIMITING CONDITION FOR OPERATION 3.12.1 The radiological environmental�monitoring program shall be conducted as specified in Table 3.12-1. APPLICABILITY: At all times. ACTION: a. With the radiological environmental monitoring program not being conducted as specified in Table 3.12-1, in lieu of any other report required by Specification 6.9.1, prepare and submit to the Commission, in the Annual Radiological Operating Report, a description of the reasons for not conducting the program as required and the plans for preventing a recurrence. b. With the level of radioactivity in an environmental sampling medium exceeding the reporting levels of Table 3.12-2 when averaged over any calendar quarter, in lieu of any other report required by Specification 6.9.1, prepare and submit to the Commission within to Specification 6.9.1.13. When more than one of the radionuclides in Table 3.12-2 are detected in the sampling medium, this report shall be submitted if: concentration (1) + concentration (2) + > 1.0 limit level limit lev-e--l--(-2-)-- 3. Th LANCE REQUIREMENTS ,al monitoring samples shall be collected cations given in the table and figure in cant to the requirements of Tables 3.12-1 d 4.1-1, 4c UIRE - UNIT 1 3 4 12-2 m Number of 'Samples Exposure Pathway and Sampling and Type and Frequency*** and/or Sample Sample Locations" Collection Frequency of Analysis 1. AIRBORNE Radioiodine and 5 Locations Continuous operation of Radioiodine canister. Particulates sampler with sample col- Gamma isotopic analysis_ lection as required by for I-1.31 on each sample. dust loading but at least once per 7 days. Particulate sampler. Gamma isotopic analysis on each sample. . DIRECT RADIATION 40 Locations Continuous integration Gamma dose. > 2 dosimeters or > 1 with collection at least instrument for con- once per 92 days. tinuously measuring and recording dose rate at each location. Samp-- locations are given on the figure and table in the`ODCM. ***Frequency of analysis stated only if different from collectionfrequency. rn Number of Samples Exposure Pathway and Sampling and Type and Frequency** and/or Sample Sample Locations * Collection Frequency of Anajyr 3. WATERBORNE a. .Surface 3 Locations Composite* sample collected Gamma isotopic analysis over a period of < 31 days. of each composite sample. Tritium analysis ofcom- posite sample at least once per 92 days. b. Drinking 4 Locations Composite* sample collected Gross beta and gamma over a period of;< 31 days. isotopic analysis of each composite sample. Tritium analysis of composite sample at least once per 92 days. c. Sediment from 3 Locations At least once per 184 days.' Gamma isotopic analysis Shoreline of each sample. be collected by collecting an aliquot at intervals not exceeding 2 hours. Composite samples shall **Sample locations are shown on the figure in the ODC . ***Frequency of analysis stated only if different from 'collection frequency. TABLE 3.12-1; (Continued) m RADIOLOGICAL ENVIRONMENTAL MONITORING PROGRAM i Number of Samples Exposure Pathway and/or Sample and Sampling and Type and Frequency*** Sample Locations** Collection Fre uenc of Anajy i. 4. INGESTION a. Milk 4'Locations At least once per 15 days Gamma isotopic and when animal are on pasture; I-131 analysis at least once per 31 days at other times. b. Fish and Invertebrates 2 Locations One sample in season, or at Gamma isotopic analysis least once per 184 days if on edible portions on not seasonal. One sample of each sample. each of the following species: 1. Game Fish 2. Bottom Feeders c. Broad Leaf Vegetation 3 Locations at least once per 31 days Gamma isotopic analysis. Sample locations are shown on the figure in the ODCM. **Frequency of analysis stated only if different from collection frequency. l AbLt REPORTING LEVELS FOR RADIOACTIVITY CONCENTRATIONS IN ENVIRONMENTAL SAMPLES Repo. Levels c Broad Leaf -, Water Airborne Particulate Fish Milk Vegetation Analysis (pC%/1) or Gases (pCi/ma) (pCi/ g, wet) (pCi/ (pCi/Kg, wet) (a) H-3 2 x 10 N.A. N.A. N.A. N.A. Mn-54' 1 x 103 N.A. 3 x I04 N.A. N.A._, Fe-5 4 x 102 N.A. I x 104 N.A. N.A. ' Co-58 I x 103 N.A. 3 x 104 N.A. N.A. 41. r o-6 'x 10 N.A. I x 104 N.A. N.A. Zn-65` 3 x 102 N.A. 2 x 104 N.A. N.A. Zr-Nb-95 4 x' 102 N.A. N.A. N.A. N.A. I-131 2b 1 N.A. 3 1 x 102 Cs-134 30 10 I x 103 60 1 x 103 Cs-137 50 20 2 x 103 70 2 x 103 Ba-La-140 2 x 102 N.A. N.A. 3 x 10 N.A. (a) For drinking water samples. This is 40 CFR Part 141 value.; (b); If low level 1-131 analysis are performed. TABU4.12-1 ., MAXIMUM VALUES FOR THE LOWER LIMITS OF DETECTION (LLD)"' m Airborne Particulate Broad Leaf Water or Gas Fish Milk Vegetation Sediment Analysis; (pCi/1) (pCi/ma) (pCi/kg,wet)' (Pci/1) (pCi/kg, wet) (pCi/kg, dry gross beta 4 N.A. N.A. N.A. N.A. N.A. H-3 2000 N.A N.A. N.A. N.A. N.A. Mn-'54 15 N.A. 10 N.A. N.A. N.A. Fe-59 30 N.A. 260 N.A. N.A. N.A. Co-58, 60 15 N.A. 130 N.A. N.A. N.A. ,.a Zn-65 30 N.A. 260 N.A. N.A. N.A. r Zr-95 30 N.A. N.A. N.A. N.A. N.A. Nb-95 15 N.A. N.A. N.A. N.A. N.A. I-131 15b 7 X 10-2 N.A. 1 60 N.A. s-134 15 5 X 10-2 130 15 60 10 Cs-137 18 - 6 X 10-2 150 18 80 180 Ba-140 60 N.A. N.A. 60 N.A. N.A. La-1.40 15 N.A. N.A. 15 N.A. N.A. c re tr c r <z n fl + C 17 C T t C> t--s •r W- 4-) ..+ CQ 6"�i ia.l LU CL E t1 -i- i8 C Q r u +-> 'S r 0 0 c r- U r- (1) " i ` Qu S- •r 4- t 0 � A _ �- CL aj � r +3 r 3 +to CU CL r M 4- C3 its r C L 0 w a) Cll 0 ,C r V) 0 R3 ni � 4- Mr C tCS •r- r^^ Ci ttz u � 4— (1) Ci : � +> i). r-» ctz > xi3 c- .. tTi C3 r Ci 4 4- 4- 0)s 0 (U cn csi s 4-% - C row U r C C CL t: : t`3 t'Ci U S- rCi. .0S- iCi b r t1J 0) 4-) is l 0> U tJ} 0 4w W +% S S- r r y I C r U tt% U 4J Ul ui C�! tti V; t�i r r C r c r 4-> m : $ -. ti3 r- r- C . 9 U- Vi': ` 0 ton C Ue-,�+ ca <14 : O r s4.) U U s 0 s_ 0 W -- U0 0 cu us U 4— C 4- -a to V) U +>, t '+> r Ui 4-) 0 {Ii Ftri C C ui s C C81 dJ +) C M W E -0 0 0 r» W +> ro .r ro .. 4-- 4- -r U CD S-..4-) > 0) -0 0 ON � aw-^ tCi = rCi > LU ttJ rI C r- 4- U ;0) >t <1 4— 0) (0 4-) . C Qj a) V)CL > 4-) � S- 0) ZO 0) K -O Q) 1 0 (a 0) +r- -0 =r- 4-) L +� l,: Qi +> C 6 U cn 4- -� `+ 'r- 4-• 0) 4-) C t3 +r k r O 0 U r-- ) Ci ua C7 tlJ > titi tra U > V) 4- 0 N ua ? r— Q. CL U 0 to 4- S > >to to r- ..0 i_ C C) 0 r^- r-- V) to 0 0 S- r-- CO > i r Qt C r W i f 4-) Ri CU U S C C= ro C (0 0 >^, t^w v) S- 4J :4-) .0 TABLE 4.1' TABL liter shall be at ihtinued) `ION .1 in drinking water samples. .ter will not be; routinely Dr low level analyses of I-1.31 radionuclides; in Table 4.12-1 , shall be identified an `reported. McGUIRE - UNIT 1 3/4 1.2-9 ; RADIOLOGICAL ENVIRONMENTAL MONITORING 3/4.12.2 LAND USE CENSUS LIMITING CONDITION FOR OPERATION 3.12.2 A land use census shall be conducted and shall identify the location of the nearest milk animal and the nearest residence in each of the 16 meteoro- logical sectors within'a distance of five miles. Broad leaf vegetation sampling shall be performed at the site boundary in the direction sector with the highest D/Q in lieu of the garden census. APPLICABILITY: At all times. ACTION: a. With a land use census identifying a location(s) which yields a calculated dose or dose commitment greater than the values currently being calculated in Specification 4.11.2.3, in lieu of any other report required by Specification 6.9.1., prepare and submit to the Commission within 30 days, pursuant to Specification 6.9.2, a Special Report which identifies the new location(s). b. With a land use census identifying a location(s) which yields a calculated dose or dose commitment (via the same exposure pathway) 20 percent greater than at a location from which samples are currently being obtained in accordance with Specification 3.12.1, in lieu of any other report required by Specification 6.9.1, prepare and submit to the Commission within 30 days, pursuant to Specification 6.9.2, a Special Report which identifies the new location. The new location shall be added to the radiological environmental monitoring program within 30 days. The sampling location, excluding the control station the same exposure pathway) may be deleted from this monitoring program after October 31 of the year in which this land use census was conducted. C. The provisions of Specifications 3.0.3 and 3.0.4 are not applicable. SURVEILLANCE -RE UIREENTS 4.12.2 The land use census shall be conducted at least once per 12 months between the dates of June 1 and October I using that information which will provide the best results, such as by a door-to-door survey, aerial survey, or by consulting local agriculture authorities. McGUIRE - UNIT 1 3/4 12-10 RADIOLOGICAL ENVIRONMENTAL MONITORING 3 4.12. 3 INTERLAB ORATORY COMPARISON PROGRAM LIMITING CONDITION FOR OPERATION 3.123 Analyses shall be performed on radioactive materialssupplied as part of an Interlaberatory Comparison Program which has been approved by the Commission. APPLICABILITY: At all times. ACTION: a. With analyses not being performed as required' above, report the corrective actions taken to prevent a recurrence to the Commission in the Annual Radiological Environmental; Operating Report. b. The provisions of Specifications 3.0.3 and 3..4 are not applicable. SURVEILLANCE REQUIREMENTS 4.12.3 A summery of the results obtained as part of the above required Inter - in the tPA cro sche k program sha1( provide the LPA program code designation for the unit) shall be included in the Annual Radiological Environmental Operating Report. Mc U RE -'UNIT 1 3/4 2-1 DT-TRE POWER C)O--4PA--,Y P.o. Y3ox 331€ 9 C; .'.RLOTTE, :ti.c. 28242 HAL, B. TUCKER TELFPHON vic y PRPSIDev-r (704) 373-4531 December 3, 1986 Mr. Harold R. Denton, Director Office of Nuclear Reactor Regulation ,µ U.S. Nuclear Regulatory Commission Washington, D.C. 205 ATTENTION: Mr. B.J. Youngblood, s Director PWR Project Directorate No. 4 Subject: McGuire Nuclear Station Docket No. '0--69 and 50-370 Response to RFI Regarding Radioactive Discharge From Conventional Waste Streams Dear Mr. Denton: On March 19, 1986Duke Power submitted a proposed Technical Specification change to allow slightly radioactive water to be discharged from. the Conventional Waste (WC) system. By letter of October �6 1986, the Staff requested additional information. Attached are ;the questions asked by the Staff, together with the responses. For clarification purposes Figure 1'has been included to identify the various' components of the WC system and adjacent water sources. If the Staff desires additional information, please contact Duke through normal Licensing channels. Very truly yours, Hal B. 'Tucker SAG/4/gm Attachments :. Trenton 3, 1986 J. Nelson Grad., Regional Administrator >. Nuclear Regulatory Commission - Region II Marietta Street, Suite 2900 .at, Georgia" 3033 W.T. Orders Lion Resident Inspector wire Nuclear Station Da. ne Brown, Chief .iaton Protection Branch 'ision of Facility Services artment of Human Resources 1. Box 12200 eigh, N.C. 2605 (AG4) ATTACHMENT STAFF QUESTIONS AND RESPONSES Premise For Questions Is Through if Radioactive liquid effluents from theaMcGuire Nuclear Station are now sampled, analyzed, and released by a monitored pathway. The radioactive liquids are diluted by the circulating water and released to Lake Norman. The lake provides additional dilution and delay before the radioactivity reaches the river. Question la The proposed new release pathway will not have the dilution and delay provided by the lake. Discuss the provisions made for assuring that the radioactivity concentrations are sufficiently low at the proposed point of release and 'provide a comparative analysis of river concentrations for the: proposed and existing release paints. Response: Radioactive releases from the existing monitored pathway are diluted by Condensate Cooling Water (CCW) and released to Lake Norman. However, the recirculation/buildup is included in Offsite Dose Calculation Manual (ODCM) release; rate and dose calculations effectively reduces CCW dilution by a factor of 2.. Although Lade Norman provides additional delay before radionuclide releases reach the Catawba River downstream of Cowas Ford Turn, ODCM release rate and dose calculation procedures applicable to the existing monitored release point 'would be unaffected by the proposed new release pathway; existing ODCM procedures are applicable to maximum individual liquid pathways for Lake Norman adjacent to the existing release point. Additionally, since the proposed new release point is downstream of Cows s Ford Dam, radionuclide releases from the new release point will not affect maximum individual pathways in Lake Norman. The combined effect of radionuclide releases from both the existing release point and the proposed new release points downstream of the new release point on Catawba River maximum individuals shall be assessed in the future and compared to Lake Norman maximum individual doses in accordance with revised ODCM Section B4.3.1 procedures. Only;maximum calculated close values (i.e., Lake Norman maximum individual or downstream Catawba River maximum individual calculated doses) shall be used for compliance or reporting purposes. Operational history has shown that the maximum individual doses will continue to result from `Lake Norman pathways'. The combined effect of both the existing release point and the proposed new release point on procedures assuring radionuclide concentrations remain / sufficiently low is addressed by revised ODCM Section B >1.3. Since recirculation/buildup of radionuclides in Lake Norman is considered to increase lake concentrations by as mach as a factor of 2.4, it can be sho th C^t wb River o entry iJijil, L2111ILstream of Cowans yard Dam resultin from n release point releases will not exceed S o x mum Permissible Concentration Dre, ODCM Section B3.1.3 has been e proposed new release paint to 3 to limit radionuclide releases resulting in less than 41% of MPC 3 revision assures MPC values are :he Catawba River due to the release points. =quation to Section 4.3.1 to WC system to the Catawba River. Like a'discharge to Lake Norman via a. discharge to the river via WC. >{ 1.0. pursuant to the releases are to be controlled spa the combined doses from both is (existing and proposed) do not collectively exceed the Appen in our response to la above, ODCM Section B4.3.1 has been nevi educes to assure that the new release point in combination with es shall be perfo d to assure only maximum dose values+ e and reporting purposes. Lfications should require appropriate sampling and analy from. the :n Appendix % evaluations; the LLD for Cs-137 for releases from the µ example, should be no greater than 0.1 pCill. discuss the various ind analyses associated with the proposed action and .identify the it sensitivity for the instruments to be used. Specification 4.11.1.1.1, Fable .11-1 lists radioactive liquid'wast .nd'analysis program requirements.. Each release through this release .1 comply with these technical specification: requirements. __ wm with a Germanium detector. The laboratory red in; Specification .11..1.1 Table t these requirements,for example, the .uuu ror us- .5/ ror releases from the WC system shall be no greater than 0.1 pCi/l; therefore no difficulty is anticipated. Question Id: Address the capability to obtain representative samples .from the Conventional Wastewater Collection System. Response Prior to release the appropriate pond will be isolated and recirculated to ensure thorough mixing for representative sampling. Question le:' Discuss the capability to prevent unmonitored releases to and from the Conventional Wastewater Basin. Response To prevent unmonitored releases from turbine building sump to the conventional• wastewater system there are radiation monitors installed on each Turbine Building .LICj. = L.LJ Ci LIVWever, uney cannot detect very low levels of tritium The station has implemented routine sampling and analyses for tritium Lrbine Building sumps, in the WC system, in the Sanitary Waste Treatment A in the: Standby Nuclear Service Water Pond. Et unmonitored releases from the conventional waste water system, in to the routine sampling program discussed above, a continuous composite .s located at the discharge point to preclude unmonitored releases. Any ctivity discovered` will be investigated immediately to determine the correct the problem. om Conventional Wastewater Treatment System (WC) are initially directed ret-lined initial holdup pond where primary sedimentation occurs. This allon capacity basin has a retention time of from 12 hours to 24 hours as a surge tank to prevent overloading and subsequent degradation of quality throughout the remainder of the system. This pond may be depending on influent quality, t --- The initial holdup pond is followed by parallel stream settling ponds. These two 1.1 acre, 2#5 million gallon ponds are lined with tamped 'clay and are equipped for recirculation. The ponds are operated such that one pond is in service while the other is on'standby. Coagulent aids may be used for settling lighter solids along with pH adjustment to neutralize or precipitate various chemical compounds. Holdup time for each of these basins ranges from 6 to 12 days. The wastewater then normally flaws by gravity to the final holdup pond where it is aerated.; retention time for this basin is 5 days. This final holdup pond is used to remove any persistent oxygen demand of the wastes. The pond has a capacity of one million; gallons. Its contents may be ,pumped to the head of the settling basins or back to its own inlet for recirculation if the effluent does not meet the established discharge limits. The final holdup 'pond may be bypassed and the discharge flows by gravity or is pumped to the river if the effluent is within specifications. NOTE: In as much as the WC system accepts influent from the turbine building; sump, any primary to secondary leak may result in contamination of one of the settling basins and possibly the initial hold-up pond.. In this case, the basin is isolated to allow for dilution and radioactive decay as required by NRC Technical Specifications. In addition, demineralizers and chemical additives may be used to process the 'waste water. Releases from the pond will comply with McGuire Technical Specifications. Question If Discuss the capabilities to determine the quantities to be released so they can be reflected in dose calculations, Response: Representative samples will be taken and analyzed as discussed in the response to Ic, above. From this the total curie content can be calculated for use in the offsite dose equations given in response lb. Question 2: Address theaccumulation of radioactivity in the sludge in the Conventional Wastewater Basin, the frequency and method of sludge removal and disposal, the radiological concentrations and exposures projected for sludge control and procedures used to maintain these exposures ALARA. Response: As shown in Figure 1, the Wastewater Collection Basin (formerly the Conventional Wastewater Collection Basin) is not in the WC flow path. Therefore, this response addresses sludge accumulation in the initial holdup pond, where the 'vast majority of sludge accumulates. The volume of waste being generated per year is projected to range from 8,000 t • M. i ing of this sludge is projecte table for landfilling where t1 l the sludge at a suitable site and incorporate it into the soil The disposal procedures which are already approved for use b .r Landfarming permit are as follows: zo.rtation Procedure To remove this sludge, the _;pond is drained and the sludge is dre from the bottom and transferred by dump truck to the disposal si The sludge will be transported to or from the disposal site in s' that liquid or solid spills will be kept to a minimum. accordance with station Health Physics procedures and stationT directives. oral Procedure Turing and after the disposal process access to the proposed disposal site will be controlled. Proper warnings will be maintained as described in the Landfarming permit. The waste sludge (water treatment residues) will be spread on the surface of the proposed disposal site over an approximate area and dep' of one acre and six inches, respectively. The sludge will be incorporated approximately six inches into the soil' after drying to the extent practical.' Because of water retention by t resins, there will be no inhalation hazard from diatomaceous earth particles. A suitable year round vegetative cover will be established and maintained after the waste has been incorporated and covered with topsoil as needed, if necessary. The workers handling the waste disposal will be properly dressed in accordance with station Health :Physics procedures and station directives. Administration Procedure o The waste volume of each batch' and documented. o For each batch of waste genera - locations will be taken for rat documented. o The total waste volume and rad and the total accumulating dos( oThe disposal ragas will be lim: inches/acre/year) . ;posed of will be properly estimated a composite sample from different .ogical analysis, and results will be :tivity inventories will be documented, .11 be periodically evaluated to 500 cubic yards per year (6 to prevent wind erosion and surface unozz from conveying poiiutants trom the waste material applicati isposal area onto the adjacent property. e (1) design changes to upgrade the capacity of the LRS,`and (2) oper, Lions consistent with existing LRS capacity. Justify the proposed a of available alternatives. se: cal Specifications 3/4.11 1.5 allow small < concentrations of radionucl system. These may enter ,the system as a result ofprimary to second< and may be present as radionuclides which cannot be removed (e.g. trig ich will result in an insignificant increase in offsite dose. They m< ionuclides which are at detectable concentrations, but cannot be r-reduced by available plant processing equipment (ion exchange, filt ich will result in an insignificant' increase in offsite dose commitmei as include cesium--134 and 137 at less than 5E-07 microCi/ml. Ling to route this 100 gpm waste source to the 20 gpm radwaste system in reactor shutdown due to 'Turbine Building Hotwell Pit flooding. TI ad amendment would allow the release of WC system radioactivity at trations within the current Tech Spec limit if the calculated offsite` trations and dose are within Tech Spec, 10 CFR 20, and 10 CFR 50 limi :here will be no change to the health and safety to the public. _- ternatives examined included a) pumping the contents of a contaminated WC pond (2 million gallons) back to the Turbine Building for portable Ion Exchange process and then release to the CCW; b) Ion Exchange/filtration of trace quantities o radionuclides in the 2 million gallon basin; and c) install increased LRS capacity. None of these options will significantly affect offsite dose due to tritium. None; of the options would significantly reduce instantaneous effluent concentrations for other nuclides. Casts for the above options range from $250,000 for option a) to $8,000,000 for option c) for an offsite dose reduction of less than: 0.3 /year® Question 4: Identify any waste stream otherthan that of the Conventional Wastewater Treatment System that will also be released at the proposed alternate release point. Discuss the measures taken to ensure' adequate control of releases via any such other waste streams through this release point. Include sampling, analysis and monitoring provisions for any such waste stream. Response: See figure 1. Collection Basin (CB) e Collection Basin receives treated sanitary effluent, yard drainage and overflow from the Standby Nuclear Service Water Pond. The overflow from the .. _ • " • • .. e • • IBM 11 003 discharges treated sanitary waste from the Sanitary Waste ment System to the Collection Basin. ante TreaLMnt System anitary Waste Treatment System consists of an aerated -facultative m which is a trapezoidal multicellular arrangement consisting of etely suspended cell followed by -three partially suspended cells' s. The lagoon provides an approximate 5-day retention time and to for variable .flaw discharge. The wastewater effluent from the 4 flows through chlorinators, a -chlorine contact chamber ' d a"Fz before discharging to the Collection Basin. Expansion space is ded should a sand filter be required in the future. lagoon is lined with a flexible Tided into four cells by a curtaJ _yester with a weighted chain ba' elm.«� 1 1 0 tic material such as hypalon, it is; ial such as a polymer coated d floatation collar. The first and is kept in complete suspension d and third cells are kept settling. Each of these two cells ace of this cell is kept slightly ae final cell, the wastewater After passing; through the f 30 minutes is provided by a the Collection Basin. ;har e capability at=5, 6 , and 8 f operation, the lagoon is able to t wastewater flow rates of 40,000 52,000 gpd, and 64,000 gpd, respectively. analyses and monitoring programs to prevent unmonitored releases are in, response to Question le INITIAL HOLDUP WT POND INFT TFNT SETTLING PONDS �' A AND B 4 WT LAGOON l � FINAL< HOLDUP h POND YARD DRAINS WT EFFLUENT WC (OUTFALL 002) EFFLUENT (OUTFALL 003) STANDBY NUCLEAR S tr".RV I C: E' WATER CATAWBA RIVER WASTEWATER Col,l,r TLON BASIN SITE BOUNDARY FIGURE' I: 11.2-2 1985; Updat M, .ste drain tank can processing in this subsys )ntamination area showers, hand washes, Auxiliary Building servifce fecontamination sinks, and laundry machine effluent. The radioacti- tanks should be below the level required for processing to reduce )activity. However, in on urging this liquid it is 1 D minimize the environmental effe sled through the fallowing equipm ral ner. imary filter (A&B). ondary filter. pment the liquid is 'collected in M i M ! i' M M *• 11.®4 nthe contai .nk Subsystem .i 1 ati on units s tank will b adwaste+Portion) ts'of the 50,000 gallon auxiliar y waste evaporator feed tanka<. t' • i i t t i • t -i .2 Electrical Power Requirements ectrically powered equipment in the liquid waste systems, with the ion of the Residual Heat Removal and Containment Spray Room sump puml plied from station non -vital buses,as it is not required to be oiler; emergency conditions. No duplication of power supplies is made. .3 Water Chemistry ste evaporator distillate water chemistry for water suitable for rec is as follows: Electrical Conductivity 2.0 uho/cm @ 25 C pH 4.0 to 0.`0 Oxygen (dissolved) <0.1 ppm Chloride <0.15 ppm Fluoride <0.15 pp 11.2-5 1 Particulates it is used as a recycle e) >ntration should rance bet SYSTEM DESIGN • 1s 1 W <100 ppb (as iron oxide) ►rater, the waste evaporator feed boron itration should range between 7,000 feat Tracing design parameters of equipment in the liquid waste systems are ( 1.2.3-1. The criteria used to establish the system design para� relationship to key equipment in the system are discussed in th( paragraphs. Safety Classes and ASE Code Classes are given in Table 3.2.2-2. ipment listed as ANS Class NNS (NRC Class D) have an absence of gases, thus a failure of any NNS class equipment contributes nol ite exposure since all liquids'are contained by the Auxiliary Bt aaste evaporator and its associated pump and filter are listed cause of their use as a backup to the boron recovery evaporator 11.2-6 ,ion, both pumps sign performanc ,e operated to meet 11.2- 121 udge Pump i capacitv at 200 feet developed head is this pump t( ition Unit Cot :ontents of the ven s complete. Pump se,, Waste Evaporator Feei ~ lump )e pump capable of deliveri Floor Drain Tank Pumps ,dwaste facility. These pumps are used to recirculate and transfer t �ntents of the two 50,000 gallon radwaste facility tanks. Mechanical Seal Cooling Water Pump iis, small 60 psi @ 2 gpm pump is used to supply cooling water to the faporator concentrates pump. Reactor Coolant Drain Tank Heat Exchanger ie heat exchanger meets the following requirements: Maintains the RCDT fluid at 170OF or less with a nominal 10 gpm of 600OF reactor coolant. Maintains the RCDT fluid at 170'F or less with a 25 gpm flow frot excess letdown exchanger during heatup or draining operations. Cools the contents of the pressurizer relief tank from 200OF to less than 8 hours. ie heat exchanger is cooled by the Component Cooling System on the sl Mechanical Seal Cooling Water Heat Exchanger iis heat exchanger cools seal water to the waste evaporator concentr t cools 2 gpm from 140'F to 1100F. This heat exchanger is cooled by )mponent Cooling System on the shell side. 11.2-9 ictor Coolant Drain Tank '4-1, 4- ----4A—A -F-- —,-k .-4+ Tk- mA�mr%ee I M, M a ?ed Tank , valve and pump seal leakoffs (outside Containment), aj ed water sources. The design bases for the required tai itional margin to accept a 10 gpm leak from one unit fo, gallons). itional 200 gallon margin. Tank gn bases for the size are essentially the same as that for the wast ,or feed tank. ycle Monitor Tanks !sand gallons of tankage are provided to collect distillate from the and waste evaporator. The size is sufficient to allow a 15 gpm eva operate without interruption for an 8 hour period. Due to space ons, two 5,000 gallon tanks are provided to meet the tankage requir Each of these tanks is provided with a diaphragm to exclude air fro ,e condensate. te Evaporator Reagent Tank ik is provided to add chemicals to the evaporator liquid if requirec 11.2-10 12/8" Floor Drain Tank day surgecapacity Tanks ospheric tanks are r ank 114 jAs MEMM 'Aling Tank M W. ided for liquid holdup and moni provided for mixing specialty ,Patina lintjiri-, rnI1Prt_ArI in the 1985 Updat 1. Auxiliary Floor Drain Tank This 50,000 gallon seismic tank is pa for temporary storage of floor drain is also used, where necessary, to che M. Mechanical Seal tooling Water Ta Filters izer with : the radwaste facility and is used waste until it can be processed. It ly adjust waste. Ll i zer -ycle this to the primary s cystems. The deminerali ve its apacity. ze 20 ft3 of resin is used to process laundry.or fl( - - 4.1-- -1 -* -- - - - I- I - - - .-1 --.: .1 -- A 1 11 t.! 1 1 - -- t- - Ai - - -1-1 u — aar.t .ieY , I g . I 4IfV %.%JVIIIIV lTQ LGI I I I %UI I --wcx III ,cent of 5 microns or larger particles. Filters that retain 98 percent microns or larger particles are as follows: !ante evaporator feed filter Paste evaporator condensate filter. ,aundry and hot shower tank primary filters (A&B). Este monitor tank filter. 'loor drain tank filters (A&B). 11.2-12 12 ers llowing strainers are provided in this system: aundry and hot shower tank strainer. loor drain tank strainers loor drain tank pre -strainers. ,undry and hot shower tank strainers and the floor drain tank strainer r larger from entering the floor drain tank. All sti tainless steel. ent r r is provided in the Liquid Waste Recycle System. & - . - - _11 - J L - L__ ___ __ - .___ __ A .4-­ upon its origin. Evaporator bottoms are generally reclaimed in the or Tanks. b. Waste Evaporator Condensate Return Unit �eheater and evaporator and returns the condensate to the condensate, The unit consists of a 100 gallon receiver, two 25 qpm pumps, valv instrumentation, and automatic controls. ip is automatically started'when the receiver water reaches high leve level in the receiver the pump is automatically stopped. In the nex [n alternator switches control to the other pump. operating pump cannot handle the,condensate load the standby pump is .ically started on a high -high level signal.. (aporator Concentrate Lines Flush Tank iter heater is used after the recycle or waste evaporator bottoms hav imped through a concentration line to be drummed. The capacity is ient to flush the full length of pipe from the waste evaporator to th ig station. The flush water is taken from the W.E.F.T. and pumped by C. pump. Instrumentation Design irm originating on the system panel is relayed to the common annuncia Control Room. 11.2-13 1985 Upc a . . 1111OP41V Il. Coolant Dr :em ink Liquid Temperature.. This channel prc n tank liquid temperature on the system s'also provided.' ink Pressure. This channel provides ind ';LIOW F.dI Wtl 644GLi. 170-Reactor Coolant Dr ate locally the disch mentation .. r e pressure of ROOT pumps A and E 1. This channel provides indic< Wild this 10'-This instrument indicates the total RCT pump flow at the system A low -flow signal from this instrument automatically stops any?operat- pump. m RO'-This instrument indicates the recirculation flow to the RCDT`from the it exchanger, at the system panel. A low -flow alarm is also provided to se operator that recirculation flow has been lost. -ain Tank Subsystem I ssure Instrumentation 10„ OWLPG5670-Waste Drain Tank Discharge Pressure -This instrument is locally the di-scharge pressure of the waste drain tank pump. 11. 2-14 1.2f 8 Level Instrumentation !vel-This instrument indicates the liqw les high and low level alarms, and intei .ank level so that the pump shuts off ai suction when'the tank level falls beb s furnished locally and at the system I temperature of the tank on the liquid waste panel. alarms on high temperature downstream of the rupture disc. The a vaste evaporator panel alerts the operator that the rupture disc i :-6370-Recycle Evaporator Rupture Disc Downstream Temperature - Thi alarms on high temperature downstream of the rupture disc. The a ,ecycle evaporator panel alerts the operator that the rupture disc :-6320-Seal Cooling Water Hx Outlet Temperature - This instrument i exchanger outlet temperature locally and trips the concentrates F Pressure Instrumentation -15010, OWLPG5680-Waste Evaporator Feed Pump Discharge Pressure - 1 �ument indicates the discharge pressure of the waste evaporator fe ie evaporator control panel. '15020-Waste Evaporator Feed Filter Differential Pressure - This ir :ates locally the differential pressure across filters A and B. 35040-Waste Evaporator Condensate Filter Differential Pressure - I rument indicates locally the differential across the waste evaporz ?nsate filter. 36160-Vent Condenser Pressure - This instrument indicates the pre� im downstream of the vent condenser locally. 36170-Feed Preheater Discharge Pressure - This instrument indicatE iarge pressure of the feed preheater on the evaporator panel. 36180-Distillate Cooler Outlet Pressure - This instrument indicat( iarge pressure of the distillate cooler on the evaporator panel. al Cooling Wate gal Cooling Wate imp Suction Pressure - This instrument trips suction pressure. imp DischargePressure - This instrument ind - the seal cooling water pump on the evapora 'Iter Differential Pressure - This instrumen )ressure on the evaporator panel- il Cooling Water Supply Pressure - This inst seal water supply pressui 1. ized Water Supply Pressui ation I e - This instrument alarms essure gets too low. so w a predetermined value. Indication is furnished locall nel. mentation Evaporator Feed Pump Discharge Flow - This instrument pr ,-Concentrates Pump Discharge Flow - This instrument indicates and concentrates discharge flow on the evaporator panel. -Concentrates Pump Seal Water Supply - This instrument trips the tes pump on low seal cooling water flow. -Conductivity Analyzer Flow - This flow glass allows visual verifica- low through the conductivity analyzer. -Sodium Analyzer Flow - This flow glass allows visual verification of ugh the sodium analyzer. 11.2-16 12/83 OWLF66260-Oxygen Analyzer 'Flow +- This flaw glass allows visual verification of flow through the oxygen analyzer. 11. 2°-17 12/86 OWMLT5050-Floor Drain Level - This instrument indicates liquid level in ti floor drain tank, both at the system panel and locally, the instrument al! provides high and low level alarms at the system panel, and interlocks th( floor drain tank pump with the tank level, so that the pump automatically when the1evel falls below a predetermined value. OWMLT5260-Mixing and Settling Tank Level - This instrument is used to conl valve 1SM172 on the pump discharge and to provide local indication. The r and settling tank pump is shutoff automatically on low level. alarms on the WPS.Panel, and interlock the waste -mot !vel, so that the pumps shut off automatically if the letermined value. Level indicators are located on th( .ntation .40-Waste Monitor Tank A Pump Flow, Waste Monitor Tani -uments indicate waste monitor pump flow on the systen ow to Mixing and Settling Tank - This instrument proN if waste flow to this tank. ;ubsy.Ltem '.rumentation 60 and OWMPG5420-Floor Drain Tank Filter Diffarp-ntial he floor tank filter. The AP across the filter at full flow may be Jetermine filter cleanliness.. )-Floor Drain Tank Pump Discharge Pressure - This instrument provides lication of the discharge pressure of the floor drain tank pump. Derature Instrumentation )-Floor Drain Tank Temperature - This instrument provides a computer high temperature. !on Unit Condensate Drain Tank Subsystem ;sure Instrumentation 1WLPG5630-Vent Unit Condensate Drain Tank Pump Discharge Pressure trument provides local indication of the discharge pressure of the ?l Instrumentation 11.2-18 121E r5590-Vent Unit Condensate Drain Tank Level - This instrument indic id level of the ventilation unit condensate drain tank in the contr instrument interlocks the ventilation unit condensate drain tank pu tank level, so that the pump automatically shuts off when the level N a predetermined value. ante Facility S stem Subs Pressure Instrumentation 6010 Auxiliary FDT Pump Discharge Pressure This instrument give cation of pump discharge pressure. 6030 Auxiliary WEFT Pump Discharge Pressure This instrument giv cation of pump discharge pressure., Level Instrumentation T 6000 Auxiliary FDT Level - This instrument indicates tank level, on to level and alarms on hi level. T 6020 Auxiliary WEFT Level - This instrument indicates tank level, on to level and alarms on hi level. S 6040 Radwaste Facility Sump Level This instrument starts the su i level and stops pump on to level. Radwaste Facility Pipe Trench Sump A Level - This instrument, alarms ump, level. Radwaste Facility Pipe Trench Sump B Level - This instrument starts ump on hi level, stops the pump on lo level and alarms on hi -hi Radwaste Facility Pipe Trench Sump A Level - This instrument starts ump on hi level and stops the pump on lo level. Instrumentation Auxiliary WEFT Pump Recirculation Flow - This instrument indicates ecirculation flow to the tank remotely. Auxiliary FDT Pump Recirculation Flow - This instrument indicates the ,culation flow to the tank remotely. Auxiliary FDT'Pump to L&HST Filter Flow;- This instrument indicates to the L&HST filter remotely. 11.2-19 12/83 OPERATING PROCEDURES and alarm funciions to aeration., rmal !22tLation on except opera The system 14 15�� 6id Waste Monitor <and Disposal e functions of the reactor coolant 11.2-20 1985 Update nitrogen from the liquid collected in this tank. The procedure to uipment in the systems listed above in order to exclude nitrogen fror ids in this tank is as follows: se all equipment isolation valves. n the flush line from the reactor makeup water storage tank. n the line to the waste drain tank and leave open until liquids with rained fissi-on product gases have been flushed from the tank. se the line to the waste drain tank. se the flush line from the reactor makeup water storage tank. n the equipment vent line. n the equipment drain line to the waste evaporator feed tank. ceure assures that no nitrogen gases enter the 'waste gas decay tank no fission product gases are released to the environment. In many s system maintenance occurs during refueling when systems are often after circulating aerated reactor coolant. In these 'cases equipment' directly to the waste evaporator feed tank and the above procedure is tank is filled, the contents are pumped to one of the recycle holdup r evaporation.' hvdronpn 7S HiSfinlvpd in fha moor>tnr rnnlant a nnrtinn r*an hn avnar-+ 11. - i 12/86 a Line up the standby waste gas compressor to the recycle holdup tank eductur. Normally, the standby compressor feeds the other waste gas compressor which is lined; up to a catalytic recomb ner and a high'ac 1 « • 1 . .e• • a -• . _. a my«•. • .. he station. If radioactivity dictates that further process—A.w 1 .2-22 12 6 ing is required, the WM system demineralier can be used. Water from the waste circulating water at a rate n'the Reactor Building deon- Wer LdnK, d LWO TOOL Minimuit ievei shower 'tank. # llaneuus chemical processing requirements. 4.2 Faults of Moderate Frequency ystem is designed to handle the occurrence of equipment faults of moderat envy such as. Malfunction in the waste processing system. Excessive leakage in Reactor Coolant System equipment. Excessive leakage in auxiliary system equipment. 11. 2- 12 6 fiction in the Waste Processin System fiction in this system could include such incidents as pump or valve RA not normally operate during a blackout. Accident iot required to operate during, or immediately following, irted manually as required when electrical power is available.' PERFORMANCE TESTS 1.1 Results of Initial Tests J performance tests are performed to verify the operability of the ients, instrumentation and control equipment and applicable alarms and I setpoints. lecific objectives are to demonstrate the following: lumps are capable of producing flow and head as required. 11.2-24 1985 Update . Waste filters are capable of passing required flow. C. Waste evaporator is operable nentati on, controllers and al , pressures, and flow rates, ad, npli'ng points are available f ration the system is u ED RELEASES ntities are largely dep s capable of maintaining the temper- ed n point. to Anah"Z+a e #icf ^Fnr7ly +n id indicate, record and alarm as sampling. ?d at all times and hence is Conti' �.M •. . i ® * . r r i r i`i •r ; . i * i i r •. •. * « M ;:.r r i i • r : • * • ! :i i i i it # ; r • r • *i ir# ;* . • +, i .. ': «.. .. ! i ': w ! r' •... ! . r i ! ' i i r • * A .: - r:. i r .. ,• `. * . a. ! : i r ,... i r i.: i .. ...... !* !• i . i!` r ! . i . it *i #i``r • r i r ` . ! r r ®. . . t. r i ! * r r `• i i i ii ! i : ! • ` • i ! i ! r • r • I of actual radioactive liquid releases from Westinghouse PWR Plants in Table 11..6-4. RELEASE POINTS 14A t.rne+11 i•n kn A4ee—knwrvnr% 'i*1% +kn nnwiv^mmnn+ -FI^we +kv+neenk n ft.4;!N+4^n at ng waterf(R) system a . LUTION FACTORS r � :� ®� ! �I� • III * i. * The pathways used in 2. Iratorl es , May 19/b. condenser circulating water fl Cowan's Ford Dam result of radioactive liquid rel 6 lLn . uurK 'f'ar-v, DU F foully .L, U.J.- riuc lt::ci1 nt-vutawl y 11.2'-27