WQ0035207_Modification_20210121

Initial Review
Reviewer Thornburg, Nathaniel
Is this submittal an application? (Excluding additional information.)*
r Yes r No
Permit Number (IR)* WQ0035207
Applicant/Permittee Synagro Central, LLC
Applicant/Permittee Address 284 Boger Rd. Mocksville, NC 27028
Is the owner in BIMS? r Yes r No Is the facility in BIMS? r Yes r No
Owner Type Organization
Facility Name Synagro Central DCAR
County Davie
Fee Category Major Fee Amount $395
Is this a complete
application?*
r Yes r No Complete App Date 01/21/2021
Signature Authority
Signature Authority Title
Signature Authority Email
Document Type (if non -application)
Email Notifications
Does this need review bythe hydrogeologist?* r Yes r No
Regional Office
CO Reviewer
Admin Reviewer
Below list any additional email address that need notification about a new project.
Email Address
Comments to be added to email notfication
Comments for Kendall
Comments for RO

Comments for Reviewer
Comments for Applicant

Submittal Form
Project Contact Information
Rease provide information on the person to be contacted by N B Staff
Name * Robert Roth
Email Address*
[e-mail]
electronic subnittal, confirmation of receipt, and other correspondence.
Phone Number*
3364034324
Project Information
........ ......... ........................................................................................................................................ ......... .... ... .... ........ ... ... .... .... .... ... ... ... .... .... .... ... .... .... ......... ......
Application/Document Type* r New (Fee Req ui red)
c Modification - Major (Fee Required)
r Renewal with Major Modification (Fee
Required)
r Annual Report
r Additional Information
r Other
O Modification - Minor
C Renewal
C GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
r Residual Annual Report
r Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
r Wastewater Irrigation
r High -Rate Infiltration
r Other Wastewater
r Reclaimed Water
r Closed -Loop Recycle
r Residuals
r Single -Family Residence Wastewater
r Other
Irrigation
Permit Number:*
WO0035207
Fbs Current Existing permt number
Applicant/Permittee*
Synagro Central, LLC
Applicant/Permittee Address*
284 Boger Rd. Mocksville, NC 27028
Facility Name *
Synagro Central DCAR
Please provide comments/notes
on your current submittal below.
Addition of Roanoke River Service
Authority WTP as a source.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form Engineering Rans, Spec'rfications, Calculations, Rc.)
WQ0035207 Mod 1_18_21.pdf 9.97MB
upload only 1 RDF document (less than 250 NS). NL@iple documents nest be combined into one RDF file unless file is larger than
upload limit.
* W By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order
and made payable to the North Carolina Department of Environmental Quality
(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date 1/18/2021

APPLICATION FOR MODIFICATION OF
PERMIT NO. WQ00352O7
DISTRIBUTION OF CLASS A RESIDUALS
SYNAGRO, LLC
Prepared by:
SYNAGRO CENTRAL, LLC
i : • • - ' •.
Mocksville, NC 27028
P 336-790-1610
January 18, 2021

SYNAGRO
January 18, 2021
NCDENR-DEQ
Division of Water Resources
Land Application Permitting and Compliance Unit
Aquifer Protection Section
1636 Mail Service Center
Raleigh, NC 27699-1636
ATTENTION: Mr. Nathaniel Thornburg
REFERENCE: MODIFICATION OF PERMIT NO, WQ0035207
Synagro Central DCAR
Davie County
Dear Mr. Thornburg:
Synagro is submitting an application to modify the company's residuals land application Class
A permit. Requested changes to the current permit include:
• Addition of Roanoke River Service Authority WTP as a source.
A check for $395.00 is provided as the above request constitutes a "Major Modification".
This application package should contain all information necessary to complete the requested
modification of Synagro's permit. However, if you require additional information or have
further questions, please contact me at [phone] or [e-mail]. o.com. Thank you in
advance for the timely and efficient review of this modification application.
Sincerely,
Am� /I /W--
Robert N. Roth
284 Boger Road, Mocksville, NC 27028 . Phone [phone]

DWR
State of North Carolina
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T. I 100 — DISTRIBUTION OF CLASS A RESIDUALS
INSTRUCTIONS FOR FORM: DCAR 06-16 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items arc submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit websile
General —This application is for treatment, storage, transport, distribution, land application, and/or marketing of Class A (or Equivalent)
residuals under 15A NCAC 02T . 1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Distribution of Class A Residuals (FORM: DCAR 06-16):
® Submit the completed and appropriately executed Distribution of Class A Residuals (FORM: DCAR 06-16) form. Please do
not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to
the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
The project name should be consistent on the plans, specifications, etc.
The Applicant's Certification on Page 3 of this form shall be signed in accordance with 15A NCAC 02T .0106(b). An alternate
person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A
NCAC 02T .0106(b).
Z If this project is for a modification of an existing permit, submit one copy of the existing permit.
® Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
® Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental
Quality (NCDEQ).
Facility Classification
New Permit
[Major Modification 1
Major (residuals permitted for distribution > 3,000 dry tons/year)
[_ $1,310
$395
Minor (residuals permitted for distribution < 3,000 dry tons/year)
F_ $810
$245
I - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
adds additional residuals sources; or includes the addition of new treatment or storage units/processes not previously permitted.
There is no fee for minor permit modifications.
C. Cover Letter (All Application Packages)
M List all items included in the application package, as well as a brief description of the requested permitting action.
INSTRUCTIONS FOR FORM: DCAR 06-16 Page I of 3

D. Program Information (All Application Packages)
® Provide a narrative explaining the following:
® How the materials will be handled and transported from where the residuals were produced to where it will be treated.
How the residuals will be processed/treated (attach process flow diagram),
® How leachate collection will be handled.
® Where the residuals will be stored until processed.
® How the final product will be distributed (packaging, bulk, etc.)
® What nutrients or other constituents (i.e. nitrogen, phosphorous, aluminum, calcium, etc.) are used or recommended as the.
limiting parameter for determination of residuals loading rate to ensure that it does not overload the soil and cause
contravention of surface water or groundwater standards, limit crop growth, or adversely impact soil quality.
Attach a marketability statement detailing destinations and approximate amounts of the final product to be distributed.
Provide either a label that shall be affixed to the bagged processed residual or an information sheet that shall be provided to the
person who receives the processed residual. The label or information sheet shall contain, at a minimum, the following
information:
Name and address of the person who prepared the residual that is sold or given away.
A statement that application of the residuals to the land shall be in accordance with the instructions on the label or
information sheet.
® A statement that the residuals shall not be applied to any site that is flooded, frozen or snow-covered.
® A statement that adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.
® Information on all applicable setbacks in accordance with 15A NCAC 02T A 108(b).
A statement that the residuals shall be applied at agronomic or recommended rates for intended uses.
E. Detailed Plans and Specifications (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit detailed plans and specifications that have been signed, sealed, and dated by a NC Professional Engineer per 15A
NCAC 02T .l 104(a}. Specifications for standard equipment may only be omitted for municipalities with approved standard
specifications, but use of the standard specifications must be noted on each sheet of the plans.
❑ Plans must include the following minimum items: a general location map, a topographic map, plan and profile view of the
residuals treatment and storage units as well as the proximity of the residuals treatment and storage units to other utilities and
natural features within 500 feet of all treatment and storage facilities, and detail drawings of all items pertinent to the residuals
treatment and storage units. Depict minimum separations required in 15A NCAC 02T .I 108(a} on the plans.
❑ Specifications must include, at a minimum, the following for all items pertinent to residuals treatment and storage units:
description of materials to be used, methods of construction, quality of construction testing procedures to ensure the integrity
of the final product in accordance with 15A NCAC 02T. I 104(a)(2)(B}, including leakage and pressure testing as appropriate.
❑ Plans and specifications must not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR
CONSTRUCTION, etc.) that indicate that they are anything other than final plans and specifications. However, the plans and
specifications may be labeled with the phrase: FINAL DESIGN —NOT RELEASED FOR CONSTRUCTION.
F. Engineering Calculations (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit all design calculations that have been signed, sealed, and dated by a NC Professional Engineer per 15A NCAC 02T
.1 104a .
G. Environmental Assessments (May be Required— See 15A NCAC 1C .0300)
❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals
treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for
the construction of the subject facilities.
INSTRUCTIONS FOR FORM: DCAR 06-16 Page 2 of 3

H. Operation and Maintenance Plan (New and Renewal Application Packages)
® For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
® Submit the O&M Plan in accordance with 15A NCAC 02T . 1110 and include at a minimum:
® Operational functions; describe the operation of the program to show what operations are necessary for the program to function
and by whom the functions are to be conducted.
Maintenance schedules; may include equipments calibration, maintenance of signs, etc.
Safety measures; may include safety training program, manuals, signs, etc.
Spill response plan; including control, containment, remediation, emergency contact information, etc.
® Inspection plan including the following information;
Names and titles of personnel responsible for conducting the inspections.
® Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the selected
location(s) and inspection fi•equency are representative of the residuals management program.
Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event
that noncompliance is observed.
® SampIing and monitoring plan including the following information;
® Names and titles of personnel responsible for conducting the sampling and monitoring.
® Detailed description of monitoring procedures including parameters to be monitored.
® Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature, flow,
and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling
plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to meet
pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per year but have an annual
sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected
by cold temperatures.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
By U.S. Postal Service:
1617 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1617
TELEPHONE NUMBER: [phone]
By Courier/Special Delivery:
512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27604
FAX NUMBER: [phone]
INSTRUCTIONS FOR FORM: DCAR 06-16 Page 3 of 3

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS
FORM: DCAR 06-16
I. APPLICANT INFORMATION:
1. Applicant's name: Synagro Central LLC
Applicant type: ❑ Individual ❑ Corporation ❑ General Partnership ❑ Privately -Owned Public Utility
❑ Federal ❑ State ❑ Municipal ❑ County
Signature authority's name per 15A NCAC 02T ,O t06: Robert N Roth Title: Technical Services Manager
Applicant's mailing address: 284 Boger Rd.
City: Mocksville State: NC Zip: 27028-
Telephone number: 336 403-4324 Email Address: [e-mail]
2. Consultant's name: NIA License Number (for P.E.):
Affiliation: ❑ On Staff ❑ Retained (Firm: )
Consultant's mailing address:
City: State: Zip:1 -
Telephone number: (_) _- Email Address:
3. Fee submitted: 395.00 (See Instruction B)
II. PERMIT INFORMATION:
1. Application is for (check all that apply): ❑ new, ® modified, ❑ renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number; WQ0035207
Date of most -recently issued permit: 11/3/2020
Date of most -recently certified Attachment A (if different than the permit): 1/15/2021
111. FACILITY INFORMATION:
1. Name of residuals processing facility: Source Specific
City:. State:
Coordinates: Latitude:
Datum:
Method of measurement:
Zip: -
Longitude:
Level of accuracy:
County where facility is located:
2. Facility contact (person familiar with residuals preparation):
Name: Robert Roth Title: Technical Services Manager
Mailing address: 284 Boger Rd.
City: Mocksville State: NC Zip: 27028
Telephone number: [phone] E-mail address: [e-mail]
FORM: DCAR 06-16 Page 1 of 3

3. Is the residual process facility also the generator? ❑ Yes; ® No
If No, please specify delivery frequency and quantity of residual to be processed: Source Specific
{ 4. Length of residuals storage at facility: Source Specific days (Note: the Division requires minimum 30 days storage in units that
are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.)
IV. RESIDUALS QUALITY INFORMATION:
1. Specify how these residuals will be distributed:
❑ sold or given away in bags or other containers; ❑ lawn (bulk); ❑ home garden (bulk);
other (explain); Land applied b,Lynaero as bulk residuals at agronomic rates
Note: Bulk residuals shall mean residuals that are transported and not sold or giving away in a bag or other receptacles with a
load capacity of one metric ton or less.
2. Complete the following if residuals are to be mixed with other materials:
Type of Materials Amounts to be added
Der 1.0 dry ton of residuals (dry ton)
3. Approximate amounts of the residuals received and processed at the facility: Source Specific dry tons per year.
4. Approximate amounts of the final product (processed residuals) to be distributed: Source Specific dry tons per year.
5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and
maximum storage times prior to distribution): Source Specific
6. Does the facility have a stormwater management plan? ❑ Yes; ❑ No
Explain whether the treatment and storage areas are under roof or how stormwater runoff will be handled: Source Specific
V. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the attached Residuals Source Certification and all associated documentation.
im
RSC 06--16.doc
FORM: DCAR 06-16 Page 2 of 3

Professional Engineer's Certification: (Application Involving New or Changes to Treatment or Storage Units)
1, , attest that this application for
has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge
the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package
may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed
this material and have judged it to be consistent with the proposed design.
North Carolina Professional Engineer's Seal, Signature, and Date:
Applicant's Certification:
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
Yes ❑ No, Explain;
^11iGr
(Signature Authority's Name — PLEASE PRINT) (Title)
attest that this application for Synagro Central, LLC
(Facility Name)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes § 143-215.6A and § 143-215.613, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.
V ,
Signature: /% Date: 0 %
FORM: DCAR 06-16 Page 3 of 3

Roanoke River Service Authority WTP
Narrative for Class A Residuals
This project involves the removal of treatment plant residuals from Roanoke River
Service Authority WTP. Operationally, Synagro will mix the storage lagoon, load
tanker trucks to transport to the fields, where the material will be offloaded to
liquid applicators for surface application. No additional processes or treatments
will be conducted on the material in question. The residuals will be land applied
to agricultural fields at concentrations below or up to the agronomic rate based
on nitrogen content of the material. The residuals receive no further treatment
after they are placed in the lagoon. Synagro is going to flag the fields to make
sure all buffers are followed as outlined in the permit. Synagro is also going to
spread all the material to further ensure that all buffers are followed.

SYNAGRO
DCAR Marketability Statement
Roanoke River Service Authority WTP
Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for
the local farmers who choose to receive residuals or establish an agreement for the farmers to apply
themselves at the direction of Synagro. The spreaders will able to spread the material in an even and
consistent manner. The material is going to be land applied on fields that have grass growing on them
that are going to either be grazed or cut for hay for animal feed some fields may be in row crop
production and rates will be determined by RYE for the crop that is going to be grown for animal
consumption. An estimated 1600 dry tons will be land applied from the Roanoke River Service Authority
WTP.

Synagro Central
Land Application Permit WQ0035207
Label for Land Application
The residuals that are land applied from Roanoke River Service Authority WTP are produced at: 5419
US-1 Bracey, VA 23919. Mr. Paul Malone, Roanoke River Service Authority Executive Director is the
preparer of the residuals and responsible for the plant operations.
The residuals from Roanoke River Service Authority WTP will be applied to agricultural fields at
agronomic rates based on the RYE rate for the fields and crops to be grown. The residuals will not be
applied to frozen, snow covered or flooded fields. The fields will be flagged with the following buffers to
help prevent runoff from the applied fields:
Setback Description
Setback by residual type (feet)
Liquid
CakeY
Private or public water supply
100
100
Surface waters (streams — intermittent and perennial,
perennial waterbodies, and wetlands
100
25
Surface water diversions (ephemeral streams,
waterways, ditches
25
0
Groundwater lowering ditches (where the bottom of
the ditch intersects the SHWT)
25
0
Wells with exception to monitoring wells
100
100
Bedrock outcrops
25
0
Residuals produced by Roanoke River Service Authority WTP will be applied to agricultural fields in bulk
and will be applied according this label as well as following all permit conditions as listed in the land
application permit WQ0035207.
Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207 (Synagro Central)
Operational Functions
The operation function of this project is going to involve mixing the lagoon up with either a tractor powered Houle pump
or through the utilization of a dredge to achieve a well -mixed and consistent material that is suitable for land application
from the Pittsboro WTP, Dunn WTP, Franklin WTP, SJWD WTP, Graham Mebane WTP, City of Reidsville WTP,
Mooresville WTP, Charlotte Water Lee S. Dukes WTP, City of Albemarle Tuckertown WTP, L.B. Stovall WTP, Roanoke
River Service Authority WTP, and South Fork Industries Maiden Plant. Brunswick IOW WTP and Elizabeth City material
will be either mixed on site or hauled via tankers to a belt press to press material to a cake material. This material will
be loaded on to tractor trailers and hauled to land application sites. City of Durham, Williams WTP is going to be hauled
to the City of Durham Brown WTP and mixed with the Brown plant alum residuals. Once the 2 materials are mixed they
will be pumped to a belt filter press and dewatered for cake land application. City of Greensboro WTP residuals will be
dredged and dewatered through use of a centrifuge. Piedmont Triad RWA's John F. Kime WTP material, and Charlotte
Water's Walter M. Franklin WTP material will be dewatered via belt filter press. Both cake materials that are produced
will be land applicable. All material is going to be spread at agronomic rates that are determined by the nutrient and
metal sample that is current for that monitoring period. Pittsboro WTP, Dunn WTP, Franklin WTP, City of Reidsville WTP,
Tuckertown WTP, Lee S. Dukes WTP, South fork Industries, and L.B. Stovall material is going to be spread with a liquid
applicator that will use pressure to spread the material in such a way to achieve a consistent spread pattern. Brunswick
NW WTP, Durham Brown, Williams WTP, John F. Kime WTP, Elizabeth City and Walter M. Franklin WTP material is going
to be dumped in the field and loaded into a cake spreader with a front-end loader. The spreader will able to spread the
material in an even and consistent manner. The material is going to be land applied on fields that have grass growing on
them that are going to either be grazed or cut for hay for animal feed some fields may be in row crop production and
rates will be determined by RYE for the crop that is going to be grown for animal consumption.
SAFETY MEASURES
Synagro believes in operating in a safety conscious manner and is has all employees participate in quarterly online safety
course that are designed to help its employees recognize safety issues and take steps to prevent accidents from
occurring. In addition, all Synagro employees have the authority to stop operations if they think any aspect of the
operation is going to cause environmental or personal harm.
Maintenance Schedule
Synagro will follow the maintenance schedule as recommended by the Synagro fleet manager for the equipment
necessary to complete the job.

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207 (Synagro Central)
Inspection Plan
Inspections for the land application of residuals will be conducted on a weekly basis at the land application site during the land
application activities of this project. The inspection frequency is based on the time frame that it is going to take to complete the
project and the amount of dry tons to be land applied from this facility. The inspections will consist of inspecting a current field
that is being applied as well as inspecting random fields that have been completed. These inspections will consist of:
1. Verifying that the Pre -Operations Check list has been completed and signed by both Operations and Technical staff.
2. Checking the calculated loads to insure the correct amount of residuals are being land applied.
3. Insure that all manned equipment has a copy of the spill control plan, the permit, and the operations and maintenance
plan.
4. Insure that the field has been flagged properly and that all buffers are being adhered to.
5. Insure that the Crop and Landowner Verification form has been filled out.
6. Verifying that the correct number samples of the residuals have been taken and that it meets the criteria for land
application.
7. The records will be kept in the project files in the respective office for the project.
8. The Permittee or Inspector shall report by telephone to the Raleigh Regional Office by Telephone at 919-791-4200
Asheville Regional Office by telephone at 828-296-4500, Wilmington Regional Office at 910-796-7215,Winston Salem
Regional Office at 336-776-9800, Mooresville Regional office at 704-663-1699, Fayetteville Regional Office 910-433-3300
or Washington Regional Office at 252-946-6481 as soon as possible but no later than 24 hours after or the next working
day following the occurrence or the first knowledge of the occurrence of the following.
• Any occurrence with the distribution program resulting in the land application of significant amounts of material
that is abnormal in quantity or characteristics.
• Any failure of the distribution system that results in the release to surface waters.
• Any time that self -monitoring indicates that the facility has gone out of compliance with the permit.
• Any process failure that results in the system not adequately treating the residuals.
• Any spill or discharge from a vehicle or piping system during residuals transportation.
• Any release that requires immediate reporting outside of normal business hours shall be called in to DE.NR at 1-
800-662-7956, 1-800-858-0368, or 1-919-733-3300. These numbers are to be called in the event of a release to
surface waters, imminent failure of a storage system when the event occurs outside of normal business hours.
• Within 5 days of the first notice of on occurrence a written response in the form of a letter shall be sent to DENR
outlining the actions taken or purposed actions taken to ensure that the problem does not recur. Persons
responsible for inspections on this project are as follows:
Nate Roth; Technical Services Manager, or his designee

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207
Sampling Plan
Sampling for this project consists of sampling the residuals during the time that land application is occurring. This will
result in one round of sampling to occur before land application commences in order to ensure that the residuals are
suitable for land application. The TCLP sample is only required to be sampled once per year.
The residuals shall be sampled annually for the following: (Regulatory level in milligrams per liter in parentheses.)
Arsenic (5.0)
1, 4-Dichlorobenzene (7.5)
Nitrobenzene (2.0)
Barium (100.0)
1, 2-Dichloroethane (0.5)
Pentachlorophenol (100.0)
Benzene (0.5)
1, 1-Dichloroethylene (0.7)
Pyridine (5.0)
Cadmium (1.0)
2, 4-Dinitrotoluene (0.13)
Selenium (1.0)
Carbon tetrachloride (0.5)
Endrin (0.02)
Silver (5.0)
Chlordane (0.03)
Hexachlorobenzene (0.13
Tetra chloroethylene (0.7)
Chlorobenzene (100.0)
Heptachlor (and its hydroxide) (0.008) Toxaphene (0.5)
Chloroform (6.0)
Hexachloro-1,3-butadiene (0.5)
Trichloroethylene (0.5)
Chromium (5.0)
Hexachlorethane (3.0)
2,4,5-Trichlorophenol (400.0)
M-Cresol (200.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
o-Cresol (200.0)
Lindane (0.4)
2,4,5 TP ( Silvex) (1.0)
p-Cresol (200.0)
Mercury (0.2)
Vinyl Chloride (0.2)
Cresol(200.0)
Methoxychlor(10.0)
2,4-D (10.0)
Methyl ethyl ketone (200.0)
The residuals will also be sampled based on the chart below for the following constituents based on production per year
Dry Tons Generated
(short tons per year)
Monitoring Frequency
(Established in 40 CFR 503 and 15A NCAC 02T.1111)
<319
1 time per year
=>319-<1,650
1 per Quarter (4 times per year)
=>1,650-<16,500
1 every 60 days (6 times per year)
=>161500
1 every month (12 times per year)
Aluminum
Ammonia -Nitrogen
Arsenic
Cadmium
Calcium
Copper
Lead
Sodium Adsorption Ratio (SAR)
Magnesium
Mercury
Molybdenum
Nickel
Nitrate -Nitrite Nitrogen
Phosphorous
Potassium
pH
Plant Available Nitrogen (calculation)
Selenium
Sodium
Total Solids
Total Kjeldahl Nitrogen
Zinc
In order to meet pathogen requirements, the material will be sampled for fecals to prove that the residuals have met the
pathogen requirements of the permit. There are no pathogen or vector attraction reduction requirements for non -biological
materials with no domestic wastewater contribution to them or have not been mixed with any other residuals. Only biological
residuals will be tested to comply with pathogen and vector attraction reduction requirements. The samples will be pulled from
the sample points that are designated in the residuals sampling plan. The samples that will be pulled are a TCLP, nutrient and
metals sample and pathogen/VAR samples as needed to prove that the material is suitable for land application. The nutrient and
metal and TCLP sample will be collected randomly and consist of at least 10 individual samples mixed together in order to get the
composite sample for these parameters. Overall, the material in question are very consistent and there should not be any
seasonal fluctuations in these residuals.
The following people are responsible for sampling:
Nate Roth; Technical Services Manager; or his designee.

DWR
Division of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
PIease use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For snore information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General -- This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 1145).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC I1-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
® For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
® Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated fiom a similar facility along with the description of similarities of the two
facilities,
INSTRUCTIONS FOR FORM: RSC 06-46 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: Synaao Central LLC
Status
Code
Facility Permit Holder
Facility Name
County
Permit Number
Maximum Dry Tons Per Year
Current b
Proposed
N
Roanoke River Service
Authority
Roanoke River Service
Authority Water
Treatment Plant
Mecklenburg
VA0088919
0
1600
8 Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted)
b The amount of residuals currently permitted for distribution, land application, or disposal (i.e, not applicable to new facility).
SUMMARY FOR FORM: RSC 06-16 Page 1

Q�
Dlvlslon of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Roanoke River Service Authority Water Treatment Plant
2. Facility permit holder is: ❑ Federal, d State, M Local Government, or ❑ Private.
Facility permit issued by: ® Div. of Water Resources, Ej Div, of Environmental Health,
or ❑ Other (explain: �).
3. Facility contact person and title: Paul Malone, Executive Director
Complete mailing address: 5419 US-1
City: Bracey State: VA Zip: 239197
Telephone number: (434)-689-7771 E-mail address: [e-mail]
gmaiI.com
4. Facility physical address: 5419 US-1
City: Bracey State: VA Zip: 23919-
Coordinates: Latitude: 36°37' 14" Longitude: 78. 13' 00"
Datum: WADS Level of accuracy: `Seconds
Method of measurement: RAP
5. Purpose of the facility:
❑ treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
® treatment of potable water, ❑ treatment of 100% industrial wastewater,
❑ treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: F—1 % industrial and " % domestic)
❑ other (explain: ).
6. Does the facility have an approved pretreatment program: ® Yes ❑ No
7. Facility permitted/design flow: 4.OMGD and facility average daily flow: 1_5 MGD
8. Average amount of residuals being generated at this facility est. 300 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water Treatment Process
Type and volume of residuals storage (i.e., outside of residuals treatment units): 2 lagoons estimated 2.5 million gal each
H. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
❑ 40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestichnunicipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1 t02(6) as:
❑ BiologicaI N Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page 1 of

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: ❑ yes no.
If yes, list the number(s): L--.'
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
26 L24: [] yes Z no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Microbac Labs and Date of analysis: 12/01/2020
Passed corrosivity test: ® yes ❑ no. pH: s.u. (2 <pH < 12.5)
Passed ignitability test: ® yes ❑ no. Flashpoint: not ignite OF (> 140°F)
Passed reactivity test: ®yes ❑no. HCN: ND mg/kg (<250) & H25: ND mg/kg (<500)
TCLP Parameter
Limit
(ingll)
Result
(mgll)
TCLP Parameter
Limit
(mgll)
Result
(mg/1)
Arsenic
5.0
ND
Hexachlorobenzene
0.13
ND
Barium
100.0
0.763
Hexacliloro-1,3-Butadiene
0.5
ND
Benzene
0.5
ND
Hexachloroethane
3.0
ND
Cadmium
I.0
ND
Lead
5.0
ND
Carbon Tetrachloride
0.5
ND
Lindane
0.4
ND
Chlordane
0.03
ND
Mercury
0.2
ND
Chlorobenzene
100.0
ND
Methoxychlor
10.0
ND
Chloroform
6.0
ND
Methyl Ethyl Ketone
200.0
ND
Chromium
5.0
ND
Nitrobenzene
2.0
ND
m-Cresol
200.0
ND
Pentachlorophenol
100.0
ND
o-Cresol
200.0
ND
Pyridine
5.0
ND
p-Cresol
200.0
ND
Selenium
1.0
ND
Cresol
200.0
ND
Silver
5.0
ND
2,4-D
10.0
ND
TetrachloroethyIene
0.7
ND
1,4-Dichlorobenzene
7.5
ND
Toxaphene
0.5
ND
1,2-Dichloroethane
0.5
ND
Trichloroethylene
0.5
ND
I,I-Dichloroethylene
0.7
ND
2,4,5-Trichloropbenol
400.0
ND
2,4-Dinitrotoluene
0.13
ND
2,4,6-Trichlorophenol
2.0
ND
Endrin
0.02
ND
2,4,5-TP (Silvex)
1.0
ND
Heptachlor and its Hydroxide
0.008
ND
Vinyl Chloride
0.2
ND
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a.. For Distribution/Land Application: hill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Microbac Labs and Date of analysis: 12/01/2020
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(mg/kg)
Monthly Average
Concentration Limits
(Class A Only)
(mg/kg)
Result
(r) ig/kg)
Arsenic
75
41
7.56
Cadmium
85
39
0.446
Copper
4,300
I,500
23.7
Lead
840
300
799
Mercury
57
17
<0.982
Molybdenum
75
nla
ND
Nickel
420
420
7.15
Selenium
100
100
ND
Zinc
7,500
2,800
62.2
b. For Surface Disposal Unit (lasrdll): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laborator
y: and Date of analysis:
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic
(ing/kg)
Chromium
(ig/kg)
Nickel
(nigAg)
❑ > 0 but < 25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (nigAg)
FORM: RSC 06-16 Page 3 of 5

5. Nutrient/Micronutrient Determination: Complete the following:
a. Total solids: 2.3 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Reed and Associates and Date of analysis: 06/22/2020
Parameter
Result
(mg/kg)
Aluminum
TBD
Ammonia -Nitrogen
812
Calcium
TBD
Magnesium
TBD
Nitrate -Nitrite Nitrogen
21.4
pH (Standard Unit)
5.2
Phosphorus
410
Potassium
207
Sodium
TBD
Total Kjeldahl Nitrogen
1029
c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): TBD
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 20 %. This
rate is a (check one): 0 default value, or [] actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals; Water Treatment Process
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method
First 0") Year PAN
Five -Year
Maximum Adjusted. PAN
(rng/k�
N09)
Surface
471
504
Injection/incorporation
877
910
6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses: None
FORM: RSC 06-16 Page 4 of 5

7. Path oeen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For DistrihutionJLaird Application of Class A or Equivalent:
A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
El A sahnonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
❑ Alternative 1 [15A NCAC 02T.1106(b)(3)(A)] - Time/Temperature Compliance.
❑ Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
❑ Alternative 3 [15A NCAC. 02T. 1 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
❑ Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
❑ Alternative 5 [15A NCAC 02T.1106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: ❑ composting, ❑ heat drying, ❑ heat treatment,
❑ thermophilic aerobic digestion, ❑ beta ray irradiation,
❑ gamma ray irradiation, or ❑ pasteurization.
b. For Land Application of Class B:
Alternative 1 [15A NCAC 02T.1106(c)(1)] -Fecal Coliform Density Demonstration.
El Alternative 2 [I5A NCAC 02T. 1 106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: ❑ aerobic digestion, ❑ air drying, ❑ anaerobic digestion,
❑ composting, or [] lime stabilization.
c. For Surface Disposal
Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item 11. 7a. above.
❑ Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item 11. 7b. above.
❑ Exempt -If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T. ] 106(a)(2)].
❑ Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VARY: Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
❑ Alternative 1 [15A NCAC 02T.I I07(a)(1)1 - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
d Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
❑ Alternative 3 [15A NCAC 02T. 1 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
❑ Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
❑ Alternative 5 [15A NCAC 02T. I 107(a)(5)] - 14-Day Aerobic Processes.
❑ Alternative 6 [15A NCAC 02T. 1 107(a)(6)] - Alkaline Stabilization.
❑ Alternative 7 [15A NCAC 02T.1107(a)(7)] - Drying of Stabilized Residuals.
❑ Alternative 8 [15A NCAC 02T.1 107(a)(8)] - Drying of Unstabilized Residuals.
❑ Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection.
❑ Alternative 10 [15A NCAC 02T. ] ] 07(a)(I0)] - Incorporation.
❑ Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.I 107(b)(2)].
M Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

VICINITY MAP SYNAGRO
r
a
OS\\54 19 US-1,
Bracey, VA 2 9
515
.sy4
1l a�0do
COUNTY: Mecklenburg OWNERS): Roanoke River Service Authority WTP

Roanoke River Service Authority WTP
QUANTITATIVE JUSTIFICATION FOR RESIDUALS
Due to the lack of recent residuals removal and fluctuating plant operations the quantity
of stored residuals is a function of historical data and a recent lagoon survey. Calculations
are shown below:
-Estimated 5.0 Million gallons
-8.0 % solids possible
-8.34 lbs/gal
(5,000,000 X 8.34 X 8.0%) / 2000 � 1668 Dry Tons
Given the lacy of recent historical land application data, Synagro is requesting Roanoke
River Service Authority WTP be permitted for an annual maximum of 1600 Dry Tons

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Residuals Sampling Plan
Synagro Residuals Land Application for WQ0035207
Roanoke River Service Authority WTP
Nutrients and Metals Analysis
0 Sampling Point: Lagoon
• Sampling Frequency: Diy ton dependent
• Sample Type: Composite
• Lab: Pace Labs
Pathogen Reduction (not required)
Vector Attraction Reduction (not required)
f TCLP
• Sampling Point: Lagoon
• Sampling Frequency: Annually
• Sample Type: Composite
• Lab: Pace Labs

SYNAGRO
Several of the nutrient analysis requested by the RSC form are lacking
from the provided analytics. The lack of these results also impedes the
ability to calculate the SAR of the Roanoke River Service Authority
WTP material. It is requested that Roanoke River Service Authority
WTP be added to the permit based on the provided results and the
understanding that additional samples will be collected and analyzed
to conform with current permit requirements prior to any distribution
of material.

OMICROBAC(q)
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Project Description
PA Landfill
For:
Carolanne Whiteside
Synagro
435 Williams CT
Baltimore, MD 21220
Project Manager
Alicia Walker
Thursday, December 3, 2020
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories. Review and compilation of
your report was completed by Microbac Laboratories Inc., - Marietta, OH. If you have any questions, comments, or require
further assistance regarding this report, please contact your service representative listed above.
I certify that all test results meet all of the requirements of the accrediting authority listed within this report. Analytical results are
reported on a'as received' basis unless specified otherwise. Analytical results for solids with units ending in (dry) are reported
on a dry weight basis. A statement of uncertainty for each analysis is available upon request. This laboratory report shall not be
reproduced, except in full, without the written approval of Microbac Laboratories. The reported results are related only to the
samples analyzed as received.
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

�DMICROBAC
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Synagro
Project Name: PA Landfill
Carolanne Whiteside
Project/ PO Number: NIA
435 Williams CT
Received: 11/18/2020
Baltimore, MD 21220
Reported: 12/03/2020
Sample Summary Report
Sample Name
Laboratory ID
Client Matrix
Sample Type Sample Begin Sample Taken
Lab Received
Roanoke River
MOK1247-01
Solid
11/16/20 12:00
11/18/20 09:50
Roanoke River
MOK1247-02
Solid
11/16/20 12:00
11/18/20 09:50
Roanoke River
MOK1247-03
Solid
11/16/20 12:00
11/18/20 09:50

6)MICROBAC"
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Analytical Testing Parameters
Client Sample ID: Roanoke River
Sample Matrix: Solid
Lab Sample ID: MOK1247-01 Collection Date: 11/16/2020 12:00
Inorganics Total
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
EPA 7.3.3.2
Reactive Cyanide
<10.0
10.0
mglkg
1
12101/20 1038
12101/20 1414
APH
EPA 7.3.4.2
Reactive Sulfide
<100
100
mglkg
1
12101/20 1036
12/01/20 1535
APH
EPA 9045D
pH
6.4
S.U.
1 H4
11/30/20 1231
11/30/20 1553
APH
EPA 9071 HIE PA 9071 B
Oil & Grease
<326
326
mglkg
163
11/11/20 1310
11123/20 1130
JDH
EPA 9095B
Free Liquid (Paint Filter Test)
No Free Liquids
NA
1
11/24/20 0828
11/24/20 0833
ADG
SM 2540 G-2011
Total Solids
225000
10000
mglkg
1
11/21/20 1915
11/21/20 1236
RLb
Total Volatile Solids - TVS
578000
mglkg
1
11121/20 1015
11/23120 1030
RLD
General Parameters
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
ASTM D2216-10
Percent Solids
23.8
1.00
% (by wt.)
1
Y1
11/19/20 0621
11120120 0650
JMH
EPA 1030
Ignitability of Solids
[aid not ignite.
mmisec
1
11/25/20 1045
JDH
Metals Total by AA
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
EPA 74711 EPA 7471 A
Mercury
<0.982
0.982
mglkg dry
1
11119120 0655
11/19/20 1528
TMM
Motals Total by ICP
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
EPA 3051AIEPA 6010B
Arsenic
7.56
3.07
mglkg dry
4
11/20/20 0604
11/20/20 1004
JYH
Barium
125
1.53
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Cadmium
0.446
0.307
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Chromium
66.4
0.767
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Copper
23.7
3.07
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Lead
7.99
3.07
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Molybdenum
<9.20
9.20
mglkg dry
1
11/20/20 0604
11/20/20 1004
JYH
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Client Sample ID: Roanoke River
Sample Matrix: Solid
Lab Sample ID: MOK1247-01 Collection Date: 11/16/2020 12:00
Metals Total by ICP
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
Nickel
7.15
6.13
mg/kg dry
1
11/70/20 0604
11/20/20 1004
JYH
Selenium
<3.07
3.07
mg/kg dry
1
11/20/20 0604
11/20/20 1004
JYH
Silver
<1.53
1.53
mglkg dry
1
li120120 0604
li120120 1004
JYH
Zinc
62.2
3.07
mg/kg dry
1
11/20/20 0604
11/20/20 1004
JYH
Polychlorinated Biphenyls (PCBs) by
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
GC/ECD
EPA 3550BIEPA 8082A
Aroclor-1016 (PCB-1016)
<63.2
63.2
uglkg dry
1
11/19/20 1325
11/23/20 1644
ECL
Aroclor-1221 (PCB-1221)
<63.2
63.2
uglkg dry
1
11/19/20 1325
11/23/20 1644
ECL
Aroclor-1232 (PCB-1232)
<63.2
63.2
uglkg dry
1
11119/20 1325
11/23/20 1644
ECL
Aroclor-1242 (PCB-1242)
<63.2
63.2
uglkg dry
1
11119120 1325
11/23/20 1644
ECL
Aroclor-1248 (PCB-1248)
<63.2
63.2
uglkg dry
1
11119/20 1325
11123120 1644
ECL
Aroclor-1254 (PCB-1254)
<63.2
63.2
uglkg dry
1
11119120 1325
11/23/20 1644
ECL
Aroclor-1260 (PCB-1260)
<63.2
63.2
uglkg dry
1
11119/20 1325
11123/20 1644
ECL
Surrogate: 2,4,5,6-Tetrachloro-m-xylene
34.6
Limit: 26-138
% Rec
1
11/19/20 1325
11/23/20 1644
ECL
Surrogate: Decachlorobiphenyl
38.0
Limit: 20-125
% Rec
1
11/19/20 1325
11/23/20 1644
ECL
(BZ-209)
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1 800.373.4071 p I www.microbac.com

OMICROBACc-
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Client Sample ID: Roanoke River
Sample Matrix: Solid
Lab Sample ID: MOK1247-02 Collection Date: 11/16/2020 12:00
Inorganics Total
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
EPA 13111EPA 1311
pH Final Leachate
5.2
S.U.
1
11119120 1423
11/20/20 0830
ARC
General Parameters
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
ASTM D2216-10
Percent Solids
22.9
1.00
% (by wt.)
1
Y1
11119/20 0821
11/20/20 0650
JMH
Metals TCLP by AA
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
EPA 7470A
Mercury
<O.DO200
0.00200
mglL
1
11123/20 0724
11/23/20 1559
KHL
Metals TCLP by ICP
EPA 3015AIEPA 6010B
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Volatile Organic Compounds TCLP
by GCMS
EPA 503OClEPA 62608
Benzene
2-Butanone
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,1-Dichloroethene
Telrachloroethene
Trichloroetherie
Vinyl chloride
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane-d4
Surrogate: Totuene-d8
Result RL Units Dilution Note
Prepared Analyzed Analy
<0.200
0.200
1
11/23/20 0707
11/23/20 1152
KHL
0.763
0.100
1
11/23/20 0707
11/23/20 1152
KHL
<0.0200
0.0200
1
11/23/20 0707
11123/20 1152
KHL
<0,0500
0.0500
1
11/23/20 0707
11/23/20 1152
KHL
<0.200
0.200
1
11/23/20 0707
11/23/20 1152
KHL
<0.350
0.350
1
11/23/20 0707
11/23/20 1152
KHL
<0A00
0.100
1
11/23/20 0707
11/23/20 1152
KHL
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
<50.0
50.0
uglL
10
11/23/20 1944
EEA
<100
100
uglL
10
11/23/20 1944
EEA
<50.0
50.0
uglL
10
11/23/20 1944
EEA
<50.0
50.0
uglL
10
11/23/20 1944
EEA
<50.0
50.0
uglL
10
11/23/20 1944
EEA
<50.0
50.0
ug1L
10
11/23/20 1944
LLA
<50.0
50.0
ug1L
10
11/23/20 1944
EEA
<50.0
50.0
ug1L
10
11/23/20 1944
EEA
<50.0
50.0
ug1L
10
11/23/20 1944
EEA
<100
100
uglL
10
11/23120 1944
EEA
93.2
Limit: 86-115
% Rec.
10
11/23/20 1944
EEA
104
Limit: 86-118
% Rec.
10
11/23120 1944
EEA
96.9
Limit: 80-120
% Roc
10
11123120 1944
EEA
102
Limit: 88-110
% Roc
10
11123120 1944
EEA
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 [ 800.373.4071 p I www.microbac.com

Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Client Sample ID: Roanoke River
Sample Matrix: Solid
Lab Sample ID: MOK1247-02 Collection Date: 11/16/2020 12:00
Herbicides TCLP by GCIECD
Result RL
Units
Dilution Note
Prepared
Analyzed
Analyst
EPA 8151AIEPA 8151A
2,4,5-TP (Silvex)
<2.00 2.00
ug1L
1
111241ZO 1550
11/30/20 2339
ECL
2,4-D
<20.0 20.0
ug1L
1
11/24/20 1550
11/30120 2339
ECL
Surrogate: 2,4-Dichloraponylacetic acid
49.0 Limit: 20-144
% Rec
1
11/24/20 1550
11130120 2339
ECL
Pesticides TCLP by GCIECD
EPA 3510CIEPA 8081A
alpha -Chlordane
Endrin
gamma Chlordane
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogate: 2,4,5, 6-Tetrachloro-m-xylene
Surrogate: Decachlorobiphenyl
(BZ-209)
Semivolatile Organic Compounds
TCLP by GCMS
EPA 3510C1EPA 8270C
1,4-Dichlorobenzene
2,4-Dinilrotoluene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
2-Melhylphenol
3-,4-Methylphenol
Nitrobenzene
Pentachlorophenol
Pyridine
2,4, 6-Trichlorophenol
2,4,5-Trichlorophenol
Surrogate: 2-FI uorobiphenyl
Surrogate: 2-FI uorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d5
Surrogate: p-Terphenyl-d14
Surrogate: 2,4,6-Tribromophenol
Result RL Units Dilution Note Prepared Analyzed Analyst
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24/20 2058
ECL
<0.500
0.500
uglL
1
11/23/20 1125
11/24120 2058
ECL
<10.0
10.0
uglL
1
11/23/20 1125
11/24/20 2058
ECL
89.6
Limit: 20-130
% Rec
1
11/23/20 1125
11/24/20 2058
ECL
59.4
Limit: 25-140
% Rec
1
11/23/20 1125
11124120 2058
ECL
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
<50.0
50.0
ug1L
1
11/20/20 1530
11/24/20 1947
JDS
<50.0
50.0
ug/L
1
11120120 1530
11/24/20 1947
JDS
<50.0
50.0
uglL
1
11/20120 1530
11/24/20 1947
JDS
<50.0
50.0
uglL
1
11/20/20 1530
11/24/20 1947
JDS
<50.0
50.0
uglL
1
11/20/20 1530
11124/20 1947
JDS
<50.0
50.0
ug1L
1
11/20120 1530
11/24/20 1947
JDS
<50.0
50.0
ug1L
1
11/20/20 1530
11124120 1947
JDS
<50.0
50.0
ug1L
1
11/20/20 1530
11I24120 1947
Jos
<250
250
uglL
1
11/20/20 1530
11/24/20 1947
JDS
<250
250
uglL
1
11/20/20 1530
11/24/20 1947
JDS
<50.0
50.0
uglL
1
11/20/20 1530
11/24120 1947
JDS
<50.0
50.0
uglL
1
111201201530
111241201947
JDS
78.6
Limit: 43-116
% Rec
1
11120/20 1530
11/24/20 1947
JDS
55.9
Limit: 19-119
% Rec
1
11/20120 1530
11/24/20 1947
JDS
75.4
Limit: 35-114
% Rec
1
11/20/20 1530
11/24/20 1947
JDS
35.4
Limit: 10-120
% Rec
1
11/20/20 1530
11/24/20 1947
JDS
85.6
Limit: 10-130
% Rec
1
11/20/20 1530
11/24/20 1947
JDS
102
Limit: 22-142
% Rec
1
11/20/20 1530
11/24/20 1947
JDS
Microbac Laboratories, Inc.
158 Stariite Drive 1 Marietta, OH 45750 1800.373.4071 p I www.microbac.com

(�)MICROBAC'P'
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Client Sample ID: Roanoke River
Sample Matrix: Solid
Lab Sample ID: MOK1247-03 Collection Date: 11/16/2020 12:00
Inorganics ASTM D3987
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
EPA1664B
Oil & Grease
<5.0
5.0
mg1L
1
12102120 0553
12/02/20 1140
JRH
EPA350.1, Rv. 2 (1993)
Ammonia as N
<0.100
0.100
mg1L
1
12/01/20 1130
1210t120 1536
TB
EPA 410.4, Rv. 2 (1993)
Chemical Oxygen Demand (COD)
<20.0
20.0
mg/L
1
12/01/20 1045
12/01/20 1245
DEA
Definitions
% (by wt.):
Percent by Weight
H4:
The test was performed outside of the EPA recommended holding time of 15 minutes.
mg/kg:
Milligrams per Kilogram
mg1L:
Milligrams per Liter
mmisec:
Millimeter per Second
NA:
Not Applicable
RL:
Reporting Limit
S.U.:
Standard Units
ug/L:
Micrograms per Liter
uglmL:
Micrograms per Milliliter
Y1:
Accreditation is not offered by the accrediting body for this analyte.
Cooler Receipt Log
Cooler ID: Default Cooler
Temp: 0.6°C
Cooler Inspection Checklist
Ice Present or not required?
Yes
Shipping containers sealed or not required?
Yes
Custody seals intact or not required?
Yes
Chain of Custody (COC) Present?
Yes
COC includes customer information?
Yes
Relinquished and received signature on COC?
Yes
Sample collector identified on COC?
Yes
Sample type identified on COC?
Yes
Correct type of Containers Received
Yes
Correct number of containers listed on COC?
Yes
Containers Intact?
Yes
COC includes requested analyses?
Yes
Enough sample volume for indicated tests received?
Yes
Sample labels match COC (Name, Date & Time?)
No
Samples arrived within hold time?
Yes
Correct preservatives on COC or not required?
Yes
Chemical preservations checked or not required?
Yes
Preservation checks meet method requirements?
Yes
VOAvials have zero headspace, or not recd.?
Yes
Project Requested Certification(s)
Microbac Laboratories Inc., - Marietta, OH
68-01670
PA Department of Environmental Protection
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOK1247
Report Comments
Samples were received in proper condition and the reported results conform to
applicable accreditation standard unless otherwise noted.
The data and information on this, and other accompanying documents, represents only the
sample(s) analyzed. This report is incomplete unless all pages indicated in the footnote are
present and an authorized signature is included. The services were provided under and
subject to Microbac's standard terms and conditions which can be located and
reviewed at <hftps://www.microbac.com/standard-terms-conditions.
Reviewed and Approved By:
Alicia Walker
Project Manager
R e p o ried: 12/03/2020 11:29
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

Instructions for completing the Chain of Custody Record on uack.
ICR Bx
158 Starllte Drive, Marietta Ohio 45750
www.microbac.com
Chain of Custody Record
Customer Project Information Turn Around Time
Name: SYNAGRO Name: Roanoke River O Standard © RUSH*
Address: 1681 Ta pahannock Blvd Number. Needed By.•
Tappahannock, VA 22560 P0:
Contact
Name: Carolanne Whiteside
Number. 804-466-5007
Emay: chiteside s na ro.com
Sampler
Name I
Phone
Cert ID: —
Page =1 of =
Compliance
Qw Yes O No
Agency..
State of VA, PA and NC
Report Options
❑ EDD
M Email
❑ Fax
cwhiteside@synaaro•com
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Client Sample ID
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Arr
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Roanoke River
S
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l2 U,D M
1
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QC Pacakge
QQ Level I
p Level II**
O Level III**
Q Level IV**
Comments
Dispose as appropriate Return ]Archive
Sample Disposal I X] E pE l i M O K 1 2 4 7
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elih,�y s d e 9 Ire2 Na �� Offs -" l , rYe fdF,Ca S r s� ` y • d n, �
Please notify lab prior to drop off. _ Fage—hf--1
s
"Surcharge May Apply to add'I QC Packages Please send certificate of analysis to the following: cwhiteside @ yna gro.com
Rev 1 41512018
Matrix - Sludge 1 Soil

SAMPLE Ib
Bottle 1
Bottle 2
Bottle 3
Bottle 4
Bottle 5
Bottle
6
i
i
f
�J
e -
S �
e k 3 i c' '°
�.-.
L �f-I
Document Contro[ # 1957
Last 04-10-2019
AS DOTED
Issued to; Document Plaster File

REPORT OF ANUS
CLIENT:
B & B Consultants
SAMPLE RECEIPT
ATTN:
Denise Longo
DATE: 6110/2020 TIME:
1000
ADDRESS:
P. 0, Box 101
GRAB COLLECTION
REED
CITY:
Chase City, VA 23924-0101
DATE: 6/9/2020 TIME;
1115 vQci�
PHONE:
[phone]
FMAIL/[e-mail]
REPORT NO: 20-09568
13:47
SPECIAL NOTES:
RE: RRSA WTP BLACKWASH SLUDGE LAGOON
SAMPLE 1D: LAGOON
SAMPLE NO 20-09568
-
EPA
Regulatory
^�
HW Method
IRA
levei
Parameter
No, Number
QL (mg/L)
(mgtL)
Result (mg/L)
Analyst/Date Time
Aroclor 1016
8082A
4.3
<4.3 m /Kg
ADT
6/22/2020
1730
Arocior 122I
8082A
4.3
< 4.3 mg/Kg
ADT
6/22/2020
1730
Aroclor 1232
8082A
4.3
<4.3 mg/KS
ADT
6/22/2020
1730
Aroclor 1242
8082A
4.3
<43) mg/Kg
ADT
6/22/2020
1730
Aroclor 1248
8082A
4.3
<4.3 mg/Kg
ADT
6/22/2020
1730
Aroclor 1254
8082A
1.7
< 1.7 mg/i<g
ADT
6/2-2/2020
1730
Aroclor 1260
8082A
1,7
< 1.7 mg/t<g
ADT
612212020
1730
Total Solids
*25408
10
2.3 %
AAH
6/10/2020
1401
Total Nitrogen
351.2/353.2
1029
5468 mg/Xg
LRR
6/36/2020
1537
Total Kjeldalil Nitrogen
351.2
1029
5468 mg/I<g
LRR
6/16/2020
1537
Nitratefftrite
3332
21.4
<21.4mg/Kg
AAH
6/17/2020
1310
Arumonia
*4500N1-13D
812
1049 mglKg
SEH
6/16/2020
1500
Phosphorus
365.1
410
2052 mg/Kg
AAH
6/15/2020
1 152
Total Arsenic
6010D
20.7
<20.7 mgXg
AME
6/29/2020
1321
Total Lead
60101)
20.7
< 20.7 mglKg
AME
6/29/2020
1321
Total Cadmium
6010D
2.07
<2.07 mg/Kg
AME
6/29/2020
1321
Total Selenium
60101)
20.7
<20.7 mg/Kg
AME
6/29/2020
1321
Mercury
7471 B
0.404
< 0.404 mgtkg
AME
6/30/2020
1613
James R. Reed & Associates
770 Pilot House Drive, Nmvpon News, VA 23606
[phone] 0 Fax:[phone]
Page 1 of 3
VELAP# 4600I3 w ,�
EPA# VA00015

PORT cc. 'Sig
SAMPLE ID: LAGOON
SAMPLE NO 20-09568
EPA
Regulatory
14W
Method
JRA
level
Parameter
No.
Number
QL (m;/L)
(mg/L)
Result (mg/L)
Analyst/Date/Time
Total Molybdenum
6010D
20.7
<20.7 mg/Kg
AME
6129/2020
1321
Total Zinc
6010D
20.7
148 mg/Kg
AME
6/29/2020
1321
Total Nickel
6010D
20.7
<20.7 tng/l(g
AME
6/29/2020
1321
Total Copper
601011D
4.13
31.9 mg/Kg
AME
6/29/2020
1321
Total Potassium
601 OD
207
537 mg/Kg
AME
6/29/2020
1321
Total Magnesium
6010D
207
994 mg/4
AME
6/29/2020
1321
Total Iron
601 OD
41,3
22202 mg/1(g
AMC
6/29/2020
1321
Total Chromium
6010D
4.13
81.0 mg/1(g
AME
6/29/2020
1321
% TVS
*254OG
0.1
55.1 H %
AA14
6/30/2020
1615
Toxic Characteristic Leaching
Procedure
by SW-846 Method 1311
Arsenic
D004
6010D
0.050
5
< 0.050
AME
6/25/2020
1144
Barium
D005
6010D
0.500
100
< 0.500
AME
6/25/2020
1144
Benzene
DOIS
8260D
0.01
0.5
< 0.01
ARP
6/20/2020
0455
Cadmium
D006
6010D
0.005
I
<0.005 D
AME
6/25/2020
1144
Carbon Tetrachloride
D019
8260D
0.01
0.5
< 0.01
ARP
6/20/2020
0455
Chlordane
D020
8270E
0.025
0.03
<0.025
ADT
6/25/2020
1910
Chlorobenzene
D021
8260D
0.01
100
<0.01
ARP
6/20/2020
0455
Chloroform
D022
9260D
0.01
6
< 0.01
ARP
6/20/2020
0455
Chromium
D007
6010D
0.010
5
<0.010
AME
6/25/2020
1144
o-Cresol
D023
8270E
0.025
200
< 0.025
ADT
6/25/2020
1910
m/p-Cresol
D024
8270E
0.02
200
<0.02
ADT
6/25/2020
1910
Cresol
D026
8270E
0.02
200
< 0.02
ADT
6/25/2020
1910
2,4-D
D016
8151A
0.004
10
<0.004
BR13
6/26/2020
0213
1,4-Dichlorobenzene
D027
8260D
0.01
7.5
< 0.01
ARP
6/20/2020
0455
1,2-Dichloroethane
D028
8260D
0.01
0.5
<0.01
ARP
6/20/2020
0455
1,1-Dichloroethylene
D029
9260D
0.01
0.7
<0.01
ARP
6/20/2020
0455
2,4-Dinitrotoluene
D030
8270E
0.025
0.13
<0.025
ADT
6/25/2020
1910
Endrin
D012
8270E
0.005
0.02
< 0.005
ADT
6/25/2020
1910
Heptachlor (-epoxide)
D031
8270E
0.005
0.008
< 0.005
ADT
6/25/2020
1910
Hexachlorobenzene
D032
8270E
0.025
0.13
< 0.025
ADT
6/25/2020
1910
James R. Reed & Associates
770 Pilot House Drive, Newport News, VA 23606
[phone] 0 Fax:[phone]
Page 2 of 3
VELAP4460013
EPA4 VAOOO15
`s

;;_=;REFQRT OF �NAtIYSI� , ;
SAMPLE ID: LAGOON
SAMPLE NO 20-09568
EPA
Regulatory
HW
Method
JRA
level
Parameter
No.
Number
QL (sng!L)
(mg/L.)
Result (rng/L)
Analyst/Date/Time
1-1exachloro-1,3-butadiene
DO33
8270E
0,025
0.5
<0.025
ADT
6/25/?020
1910
Hexachloroethane
D034
8270E
0,025
3
< 0.025
ADT
6/25/2020
1910
Lead
DOGS
601 OD
0,050
5
< 0.050
AME
6/25/2020
1 144
Lindane
D013
8270E
0.025
0.4
< 0.025
ADT
6!25/2020
1910
Mercury
D009
7470A
0,0020
0.2
<0.0020 P
AME
6/26/2020
1159
Methoxychlor
DOM
8270E
0.025
1D
<0.025
ADT
6/25/2020
1910
Methyl ethyl Ketone
D035
8260D
0.2
200
<0.2
ARP
6/20/2020
0455
Nitrobenzene
D036
8270E
0.025
2
<0.025
ADT
6/25/2020
1910
Pentachlorophenol
D037
8270E
0.1
100
<0.1
ADT
6/25/2020
1910
Pyridine
D038
8270E
0,025
5
<0.025
ADT
6/25/2020
1910
Selenium
DOIO
601 OD
0.050
1
<0.050
AME
6/25/2020
1144
Silver
DO] 1
601 OD
0.010
5
< 0.010
AME
6/25/2020
1144
Tetrachloroethylene
D039
8260D
0.01
0.7
<0.01
ARP
6/20/2020
0455
Toxaphene
DOl 5
8270E
0.1
0.5
< 0. l
ADT
6/25/2020
1910
Trichloroethylene
D040
8260D
0,0I
0.5
<0.01
ARP
6/20/2020
0455
2,4,5-Trichlorophenol
D041
8270E
0.025
400
<0.025
ADT
6/?5/2020
19I0
2,4,6-Trichlorophenol
D042
8270E
0,025
2
<0.025
ADT
60-5/2020
1910
2,4,5-TP
DO17
8151A
0.004
1
<0.004
BRB
6/26/2020
0213
Vinyl Chloride
D043
8260D
0.01
0.2
<0.01
ARP
6/20/2020
0455
IIbTE:
]RA Quantification Level is the concentration of (lie lowest enlibration standard about zero with a reliable signal.
Reproduction of this report is not pennilted, except in full, without wrincri approval from James R Reeti & Associates.
The results on this report relate only to the samplers) provided for annlysis.
Results conform to NELAC standards, where applicable, tmless mhcrwisc indicated,
vW 2011
}RESPECTFULLY SUBMITTED
Coicium Carbonnta Equilyalt ncy subcontracted to Waypoint.
see Attached Report,
Results (meJke) reported on dn- weight basis
D: Duplicate outside QC acceptance range
Elaine Claiborne
P; QL based an dilution due to sample mLaboratory Director
atrix 06-Jul-20
H: Holding 011ie exceeded
Jaynes R. Reed & Associates
VELAP# 460013r"7
770 Pilot T Iouse Drive, Newport News, VA 23606 EPA# VADOD IS(757) 873-4703 0 Pax: [phone] qm.
Page 3 of 3

R��s`TncYt*�`
CHAIN OF CUSTODY
ANALYSES REQUESTED
Battle ID A1-A3 $
Company Name; B&B Consultants, Inc, Preserv. 1
Company Contact: Denise Longo Telephone; 434•-372-3393
Results To: Denise Longo Fax: [phone]
Address: 316 East Third Street, Chase City , VA 23924 - x
o z v
> z a m c
Project 1D: RRSA WTP Blackwash Sludge Lagoon o
E
Composite Grab = o o nt
JRA /Sample Sampfe Location Start Start End End Date Time Total # S m m .w 3
f❑ , Type Date Time Date Time afcont � n� � 1° �, � ¢ 0 ,U
4 X X X X X X
'WW=Wastewater, GW = Groundwater, I7lR! -Drinking Water HW - Hazardous Waste, OTHERS
Sarrlple�i By
—�DatefTirra:
Preservaves;
°
RelirlgLdshed By:
/1-1 •. „��
. . .C 6 = Na2S103+ HCI
D�telTlme: - ._ ��cl`� 2 = HNO3 7 = NaOH
10=Ascorbic Acid + MCl
Received By:
Relinquished By:
� _t ; ��
+ ZnOAc
Datemme: �� _ t� f 2 3 = H2SO4 8 = H2SO4 + FAS
11=HC1
12=Zinc Acetate + NaOH
€J
Received By:
zl-r61
DatefTime: 4 = NaOH 9 = NH�CI
13 = H2S0, + Na2S03
Datemme: 5 = Na2$203
ej
•,,,for Compliance
�}
�GC�! z L 2 =
"L<" &
`t^
1 /, --A-
` t fie'
-Not
•,._hint for Compliance
fe3 —e� 0 f aC�
*Metals - Arsenic, Dead, Cadmlurn,Selenium, Mercury,Molybdenurn, Zinc, Nickel, Copper, Potassium, Magnesium, Iron, Chromium
'Subcontract to Waypoint. Arrival Temp: I f °c
,JAMES R. REED and ASSOCIATES [phone]; FAX [phone]
770 Pilot House Drive, Newport News, VA 23606

D a
Waypigin't-
A
LYTICAL
6/24/2020
JAMES R REED & ASSOCIATES
770 PILOT HOUSE DR
NEWPORT NEWS, VA, 23606
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
wwwmaypointanalytical.com
Ref: Analytical Testing
Report Number: 20-168-0001
Project Description: 20-09568-Sludge/Lagoon
Waypoint Analytical Virginia, Inc. received sample(s) on 6/1612020 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub-uuntracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method, Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite_._) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repealing the
analysis in question at laboratorys expense, or the refund of the charges paid for performance of said analysis.

a.
Waypoun, 7621 Whitepine Road, Richmond, VA 232V
Main 804-743-9401 ° Fax [phone]
ANIAI_YTICAI_ wwwwaypointanalv6cal com
Sample Summary Table
Report Number: 20-168-0001
Client Project Description: 20-09568-Sludge/Lagoon
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
72656
20-09568-Sludge/Lagoon
Solids
06/09/2020
11:15
06/16/2020
SM-2590C
WP MTN
72.656
20.09568-Sludge/Lagoon
Solids
06/09/2070
11:15
06/16/2020
AOAC 955.01
WP MTN
WP MTN - Memphis, YN: Waypoint Analytical - TN, Memphis, TN

A.
Waypoint,7621
Whitepine
Road, Richmond, VA 23237
Main 804-743-9401. ° Fax [phone]
ANALYTICAL
www.waypolntanaiytical.com
79552
3AMES R REED & ASSOCIATES
Project
20-0956B-Slud9e/Lagoon
770 PILOT HOUSE DR
Report Date; 06/2-4/202U
Information
:
Recelved : 06/16/2020
NEWPORT NEWS, VA 23606
Pauric McGroary
Report Number : 20-168-0001
REpmrOFANALYS'1S
Agronomist
Lab No ; 72656
Matrix: Solids
Sample ID: 20-09568-51udge/Lagoon
Sampled: 6/9/2020 11:15
Test
Results
Units MQL
DF Dale I Time By Analytical
Analyzed Method
Moisture
99.7 H
% 0.010
1 06/18/20 16:54 FMM SM-254OG
Calcium Carbonate Equivalent
5.4
%Q - dry 0.1
1 06/23/20 16:43 DXT AOAC 955.01
Test
Results
Units MQL
DF Date ITime By Analytical
Analyzed Method
Total Solids 0.300 H % 0.010 1 06/18/20 16.51 FMM SM-254OG
Qualifiers/ DF Dilution Factor H Beyond holding time
Definitions L Limit Exceeded MQL Method Quantitation Limit

a
WaypointTF
ANALYTICAL
7621 Whltepine Road, Richmond, Vie 23237
Main 804-743-9401'Pax 804-771-6446
W WW.WaypointanaIytical.coln
Shipment Receipt Form
Customer Number: 79552
Customer Name: .TAMES R REED & ASSOCIATES
Report Number: 20-168-0001
Shipping Method
O Fed Ex O us Postal 0 Lab Q Other: F TT�
O UPS 40 Client Q Courier Thermometer ID: i
Shipping container/cooler uncornprom(sed?
0 Yes
O No
Number of coolers/boxes received
�i 1
Custody seals intact on shipping containericooler?
O Yes
O No I* Not Present
Custody seals intact on sample bottles?
O Yes
Q No Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COO properly completed
Yes
Q No
Samples in proper containers?
• Yes
0 No^
Sample containers intact?
0 Yes
Q No
Sufficient sample volume for indicated test(s)?
0 Yes
O No
All samples received within holding time?
0 Yes
No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice. 0 Yes 0 No
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved O Yes O No 18 NIA
Water - VOA vials free of headspace a Yes Q No 0 NIA
Trip Blanks received with VOAs Q Yes Q No N/A
Soil VOA method 5035 -- compliance criteria met 0 Yes O No NIA
High concentration container (48 hr) i Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
Comments: I---'
Signature: randi Watson
0 Yes * No
Date & Time: P6116/2Q20 13.5 4

�j I l�il lli kll�ll11111111111�151 , 320-1 � t
i�1- jWES R RcF❑ i�aS lAl'><S
�a.�5gg_55urluC
A h I A I YSFC RFr)1Tl=.c,'Tr-n
Bottle ID
Company Name; James R. Reed & Associates Preserv.
Company Contact: Elaine Claiborne Telephone: [phone]
Results To: Elaine Claiborne emsil; claifsu,r>eti�jrr�crJ_cr�nt
Address: 770 Pilot douse Drive
Newport News, VA 23606
Project 1D:
Corn osite Grab
is
g
CT
0 w
Sample
Type*
Sample Location
Start
Date
Start
Time
End
Date
End
Time
Date
Time
Total #
of cunt_
20-09568
Sludge
Lagoon
6-9-20
1115
1
X
'VVW= Wastewater, GW = Groundwater, DIN - Drinking Water, HW - Hazardous Waste. OTHERS
Sampied By: Client DateMrne: I see above
Relinquistled By. -� ` rs: j st Datefi ime : 1p-%fie -� -- - 0.9057 -
Received By:
Relinquished By_ Date/Time: �r, - %� ' �U �� 7r_-61
Received By: _r ram' Daterrime: j, I1,,. 16 'Uri
for Campliance
_Not for Compliance
preservativas'
1 = K6°C 6 = NarSaOa
2 = HNO, 6 = Na,SO,+ HCI
3 = H,SO, 7 = NaOH + ZnCAc
4 = N30H B = HMSO,+ FAS
9 = NH4CI
1 o=Ascorbic Acid + HCI
t1=HCk
12-Zinc Acelato I KGOH
Arrival Temp: °C
JAMES R. REED and ASSOCIATES (757) 873--4703; FAX [phone]
77D pilot House Drive, Newp, Jews, VA 23606

y
itmcs IUMV
R. ILec:d & Associntcs
7741 Pilot I loww Nve
Nvwpoyt 1caa. VA 'Z i(j6
7a7.$73-4705 ph 1VFINIDOR
757-8'd3-I•}J8 ins
m xs --
PAM
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ach
11.0. NU.:
1303
unc 12,,2020
m
Supply-M-pt. Code:
Requemcr:
INainc Chiburne
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is o�wc
cn-M—
lCora}tatlr Naau:' l\':t�"I�UI;v I: •,", 2
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EStn:ct-lrlalrestij a
�Piusncj
QiY ITEivl# DESCRIPTION jan UNITPRiCE_ , i.WEVO AL
2t1.1i)j(�;1
srll3xoxAl.
1. Please entef P.O. Wvober oo VOUI Invodce.
t Gntes tadsOrder in accordance Willi lire prices, terms, delivery method, and
sped(icatloas listed a%ve. ---
3. Plc+sa nadHly>n lminedialety It you are unable to ship as spe;died TAI
A. Send atl.cosrespmdenre to:
James R.Rafid Cs 1tsaClatcs
770 Plltat
x Hat:se Drive
kcwpam Harr, VA 2361A
757•973•4703 Plane 757.813-1498 Fax
r
,tw•rn•:, ls� 17a4