NCG500659_Regional Office Historical File Pre 2018

OY COOPER
MICT AEL S. REGAN
,,�,OVIWV
WaterResourcei S. JAB' ZIMMERMAN
June 1., 3017
Mr. David Valdes
Director of Energy and Sustairability, CPCC
P.Q. Box 3500
Charlotte, NC 28235
Subject:Rescision of Certificate of Coverage
N C500659
Facilities Services Central Campus
Mecklenburg County
}dear Mr. valder
Division staff has confirmed that the subject Certificate of Coverage (CoC)
is no longer required. Therefore, in accordance with your request, NPDES
CoC NCG500659 is rescinded, effective immediately.
If in the future your client wishes to discharge wastewater to the
State*s surface waters, you must -first apply for and receive a new
NPDES permit.
If you have any questions concerning this matter, please contact.. Charles H.
Weaver at (91 ) 17- 391 or via e-mail [charles.weaver ncdenr.gov].
Sincerely, ,
6
IW
V "I, 1441W
for S . Jay Zimmerman, Director
Division of rater Resources
ccMOM,
NPDES files
Teresa Revis Budget
I
i
State of North Carolina Environmental Quality I Water Resources �
1617 Mail Service Center I Raleigh, NC 2769 -1617
9198076300 919-807-63 9 FAX
https.//deq.ne.gov/ ut/div ions//water-resources/water-resources-pe its( ast water-branch/npdes- astewater-permits
t

From: Zack Lester III [e-mail]>
Sent; Wednesday, September 28, 20161.1:43 AM
To. Bell, Wes
Cc: Lance 011ivierre; Medley, George
Subject: RE: Inspection Report/Required Response
Hey dies,
I apologize for the delay in my response as I have been out of town since icy previous email to, you.
CPCC will abide by the requirements stated in the permit (ICG500659) and the specifications detailed in regards to the
effluent discharge associated with C 's Kratt building (" ratt"). 6 rats is slated to be demolished at the beginning of
the year (Jan —Feb, 2017). At that time, CPCC will no finger perform testing per the permit as no discharge will exist in
that location. Upon Kratt being demolished, I will send notice that said demo has taken place and you can advise on
what the process/ if any will be at that time.
`shanks,
Zack Lester, IIl
Grounds And Site Coordinator, Facilities Service
Central Campus, Drumm Building
704133012722 ext, 3838
www.gppc.edu
From. Bell, Wes [mailto:wes.bellncdenr.gov]
Sent: Monday, September 19, 2016 2.40 PM
To. Zack Lester III czack.lestercpcc.edu>
Subject. RE Inspection Report/Requires! Response
Zack,
Thanks for the results. I need for you to send me a written response indicating how the facility will ensure sampling will
be performed according to the permit. In addition, the letter should Include an update can the status of this
discharge.... it was indicated during the inspection that the discharge would either be eliminated or connected to City
sewer. You can email me the response and the response needs to be sent to me by this Friday.
Thanks.
Wes
From: Zack Lester Ill rnailto.zack.lester c cc.eduj
Sent; Monday, September 19, 2016 2:03 PM
To: Bell, Wes <wes:bell ncdenr, ov>
Cc. Medley, George <gMedle caser ices.com>; Lance 011ivierr <Lance. llivierre c cc.edu>
Subject: FW: Inspection Report/Required Response
Wes,
Please see the results attached from our recent effluent discharge analysis.
t

Facilities Services
19
\A
:.edu>; Lance 011ivierre I(Lance. 011ivierre@c ccedu)
.esponse
'JII
id Site Coordinator, Facilities Services
opus, Drumm Building
22 ext, 3838
adu
Wes [rnaiIt:o:wes,bgj1@ncdenr&ov
,day, August 11, 2016 10:45 AM
ster III <[e-mail]>
Medley <ggqrgg,�Medle cc.edu>
ipection Report/Required Response
,e,
if you have any additional questions or concerns.
Thanks for all your cooperation in this matter.
Wes
Wes Bell - [e-mail]
North Carolina Dept. of Environmental Quality
Division of Water Resources
Water Quality Regional Operations Section
610 E. Center Ave., Suite 301
Mooresville, NC 28115

�� � !a ew •1�f
r
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Cara Paraae se,€�c�rvct this �=-a�a�s1 h e��rs�r. t.te.r. r3c.#nt n �€ad %rr?tiana�r�`t,€, notify th 3
t

01�1`.
PACCRORYGovernor
DONALD R. VAN TIER VAAR"T`
arer)Zes urces S. JAY ZIMMERMANENVIRONMENTAL QUALITY Dinxior
July 15, 2016
CERTIFIED MAIL ##. 70151520 0002 6984 7733
RETURNCEIPT REQUESTED
Mr. Bo Hightower
Ececutive Director of Facilities Management
Central Piedmont Community College
Past Office Box 35009
Charlotte, North Carolina 28235-5009
Subject: Notice of Violation
Compliance Evaluation Inspection
Central Piedmont Community College
ICES Permit No. NCG 00659
Mecklenburg County
Tracking # NOV- 016-PC-023
Dear Mr. Hightower:
Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted
at the subject facility on July 7, 2016 by Mr. Wes Bell of this Office. Please inform the facility staff that
oversee the cooling systems and NPDES sampling program of our findings by forwarding a copy of the
enclosed. report.
This report is being issued as a Notice of Violation (NOV) due to the facility's failures to monitor
the effluent discharges in 2013 2014, and 2015, which are violations of the subject N DES ]Permit and
North Carolina General Statute (G.S.) 1 3-215.1, as detailed in the Effluent Sampling; Section of the
attached report. Pursuant to G.S. 143-215.6A, a civil penalty of not more than twenty-five thousand
dollars ( 25,000.00) per violation, per day may be assessed against any person who violates or fails to act
in accordance with the terms, conditions, or requirements of any permit issued pursuant to G.S. 14-
21.1.
It is requested that a written response be submitted to this Office by Auggst 5, 2016, addressing
the above -noted violations in the attached report. The response should also include the measures taken to
ensure that future effluent sampling events will be performed (at all applicable outfalls) in accordance
with the subject permit. In responding, please address your comments to the attention of Mr. Wes Bell.
State of North Carolina I Environmental Quality] Water Resouroes j Water Quality Regional Operations
Mooresville Regional office 1610 East Center Avenue, Suite 3011 Mooresville, North Carolina 28115
704`663 1699

ter
P
meat`
WB
Sincerely,
,A .
W. Carey F

Untied States Environmental Protection Agency Form Approved.
EPA Mshington, DZ. 2OW OMS No.204"067
FrI Water Compliance Inspection Report Approval expires 8-31-98
Section A. National Data System Coding (i.e., PC$)
Transaction Code NPDES ydmo/day Inspection Type Inspector Fat Type
2 15
1 3 NCG500659 111 121 16/07/07 117 181"l 191SI 2OU
j UJ
21111
Inspection Work Days Facility Self -Monitoring Evaluation Rating 81 QA ------Reserved---
67 110 70 Lj 7
1 U 72 LNJ 73 [_LJ74 750
LJJJ_LLU8
Section B- Facility Data
Name and Location of Facility Inspected (For Industrial Users discharging to PO'tW, also include Entry Time/Date Permit Effective Date
POTW name and NPDES oermit Number), 09:20AM 16107/07 16/04/26
Facilities Services Central Campus E)dt TmetDate Permit Expiration Date
1201 Elizabeth Ave
Charlotte NC 28202 10-46AM 16/07107 20107/31
Name(s) of Onsite Representative(s)/,rttles(s)/Phone and Fax Number(s) Other Facility Data
111
Name, Address of Responsible OfficialrTittelPhone and Fax Number
Contacted
So Hightower,PO Box 36009 Charlotte NC 28235500911704-330-6234t7043306166 Na
Section C: Areas Evaluated During Inspection (Check only those areas evaluated)
n Permit N Flow measurement Operations & Mainteriana RecordslRepoits
Self -monitoring Program N Sludge Handling Disposal Facility Site Review EffluenttReceiving Waters
Laboratory
Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary)
(See attachment summary)
Name(s) and Signature(s) of Ins or(s) Agency/Office/Phone and Fax Numbers Date
Was Bell MRO WO/1704-663-1699 Ext.21921 '711
Signature of Management Q A Reviewer AgencylOffice/Phone and Fax Numbers Date
W. Corey Basinger MRO WQ/1704-236-2I94/
EPA F 3660-3 (Rev 9-94) PrevlQus editions are obsolete,
Ak
Page#

Permit. NCG500669 owrlar»lracllity- Facilities Services Central Campus
inspection Date: 0710712016 inspection Type: Compliance Evaluation
i'ermit Yes No MA —NE
(If the present permit expires in 6 months or less). Has the permittee submitted a new 0 0 a 0
application?
Is the facility as described in the permit? wool]
# Are there any special conditions for the permit? 00011
Is access to the plant site restricted to the general public? [logo
Is the inspector granted access to all areas for inspection? M000
Comment: The last coLnglignpia evaluation inspection was Derformed at the facility on 9/11/13 by QWR
staff.
Record KeeDlng Yes No NA NE
Are records kept and maintained as required by the permit? 0 oon
Is all required information readily available, complete and current? 0 0 Oa
Are all records maintained for 3 years (lab. reg. required 5 years)? 0 0 0 M
Are analytical results consistent with data reported on DMRs? 11 0 11 M
Is the chain -of -custody complete? 13 0 [Is
Dates, times and location of sampling 11
Name of individual performing the sampling 11
Results of analysis and calibration 11
Dates of analysis 0
Name of person performing analyses 0
Transported COCs 0
Are DMRs complete: do they include all permit parameters? 0 0 0 0
Has the facility submitted its annual compliance report to users and DWO? 0 0 a 0
(If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator 0 0 M 0
on each shift?
Is the ORC visitation log available and current? 0 0 a 0
Is the ORC certified at grade equal to or higher than the facility classification? 0 0 a 0
Is the backup operator certified at one grade less or greater than the facility classification? 0= 0 a 0
Is a copy of the current NPOES permit available on site? a 0 0 13
Facility has copy of previous year's Annual Report on file for review? 13 0 a 11
Comment: No self -monitoring documentation was "available for review due to the facilily nit saLnpfin
g
according to the permit.
Effluent Sam gtin g Yes No NA NEE
Is composite sampling flow proportional? 0000
page# 3

500659 Owner • Facility: Facilities Services Centrg
12016 Inspection Type: Compliance Evaluation;
glow all treatment units?
cted?
e'set for sample storage {kept at less than or equal to 6.0 degrees
i performed as required by the permit (frequency, sampling type
i required by the permit (frequency, sampling type, and
ausekeeping?
imeters, for ex: MISS, MIST, Settleable
are applicable?
outfall property maintained?
Cc

FILE
Rib"E"N""Ra
North Carolina Department of Environment and Natural Resources
Division of Water Resources
Water Quality Programs
Pat McCrory Thomas A. Reeder John E. Skvaria, III
Governor Director Secretary
September 13, 201")
Mr. B.L. Hightower
Executive Director of Facilities Management
Central Piedirrom Community College
Post Office Box 35009
Charlotte, North Carolina 28235-5009
Subject: Notice of Deficiency
Compliance Evaluation Inspection
Central Piedmont Community College
NPDES Permit No. NC G500659
Mecklenburg County
Dear Mr. Hightower:
Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the
subject facility on September 11, 2013 by Mrs. Marcia Allocco and Mr. Wes Bell of this Office. This Office
appreciates all the efforts and cooperation by you and your staff to comply with the conditions of this NPDES
Permit.
It is requested that a written response be submitted to this Office by Qctober 20IJ3, addressing the
deficiencies noted in the Effluent Sampling Section in the attached report. In responding, please address your
comments to the attention of Mrs. Marcia Allocco.
The report should be self-explanatory; however, should you have any questions concerning this report, please
do not hesitate to contact Mr. Bell at [phone] or at jyes..be,1I(a-)ncdenrgov.
Sincerely,
,e;V"Michael L. Parker
Regional Supervisor
Surface Water Protection Section
Enclosure:
Inspection Report
cc: Rusty Rozzelle, MCWQP
WEI
Mooresville Regional Office One
Location: 610 East Center Ave,, Suite 301 Mooresville, NC 28115 thCaro
Phone: [phone] k Fax: [phone], Customer Service: 1-877-623-6748 N lin a
Intemet: wwwrliawaterqUality,org NO
Witrally
An Equal Oppor unity, Affirmativeaction Employer - 30% RecycledilCMPost Consurner paper

United States Environmental Protection Agency Form Approved,
EPA Washington, D.C. 20460 OMB No, 2040-0057
Water C , i!!'':1 i 11�>Pnnrf Approval expires 8-31-98
Section A, National Data System Coding (i.e., PCS)
Transaction Code NPDES yr/mo/day Inspection Type Inspector Fay: Type
1 LN1 2 U5 31 NCG500669 111 121 13/09/11 17 18 ILC 1 i
191 20, L1
Remarks
211 1 1 1 1 1 1 1 1 1 1 11 1 1 1 1 1 1 1 1 1 1 1 I—Lii- -1 1 1 1 1 1 1 1 1 LL-LL-Lii"
Inspection Work Days Facility Self -Monitoring Evaluation Rating BI QA - ---------- - -------------Reserved-------___-_. __ - --
671 1'0 169 70L21 71LNI 72LNI 731 1 174 75 8
LLLLi-0
-
Section El- Facility Data
- ----------- --
Name and Location of Facility Inspected (For Industrial Users discharging to P0TVV, also include Entry Time/Date Permit Effective Date
PO TW name and NPDES permit Number)
11:15 AM 13/09/11 12108/01
Facilities Services Central Campus —
1201 Elizabeth Ave Exit Time/Date Permit Expiration Date
Charlotte NC 28202 12:50 PM 13/09/11 15107/31
Name(s) of Onsite Representative(s)/Tittes(s)/Phone and Fax Number(s) Other Facility Data
X
Bo Hightower/Director Executive Facilities Mgt/704-330-6234 /7043306166
Craig K Johnson/Chief Engineer/704-330-6627 I
Name, Address of Responsible Official/TittelPhone and Fax Number
Bo Hightower,PO Box 35009 Charlotte NC 282355009/Executive Director Facilities Contacted
Mgt/704-330-623417043306166 Yes
Section C: Area Evaluated During Inspection (Check only those areas evaluated)
Permit a Flow Measurement 0 operations & Maintenance 0 Records/Reports
Self -Monitoring Program M Sludge Handling Disposal 0 Facility Site Review 0 EffluentlReceiving Waters
Laboratory
Section D: Surnm of Findin 1Co m nts Attach additional sheets of narrative and checklists a2_nft2t2§2ryL_
(See attachment summary)
Name(s) and Signature(s) of Inspect9i(s) Agency/Office/Phone and Fax Numbers Date
W es BeR MRO WQ//704-663-1699 Ext,21921
Marcia Allocco MRO WQI/704-663-1699 Ext.2204/
Sign ature of Management Q Reviewer Agency/Office/Phone and Fax Numbers D
arcia Allocco MRO WQI/704-663-1699 Ext,2204/
EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete,
Page # 1

yrlrncldey Inspection Type
12, 13/09/1, 117 18l d
Page

FPermit: NCG500659 Owner - Facility: Facilities Services Central Campus
Inspection Date: 09/1112013 Inspection "type: Compliance Evaluation
Permit
Yes
No NA NE
(if the present permit expires in 6 months or less). Has the permittee submitted a new application?
o
o a n-
Is the facility as described in the permit?
o
0 0 0
# Are there any special conditions for the permit?
o
no a o
Is access to the plant site restricted to the general public?
11000
Is the inspector granted access to all areas for inspection?
8000
Comment- The Division received the permit application on 2/2/2012 and issued the
subject permit on July 31, 2012 (also effective date). No instream monitoring (upstream
and downstream) will be required due to the effluent being discharged into a stormwater
drainage system.
The facility has not been previously inspected.
Record Keeping
Yes
No NA NE
Are records kept and maintained as required by the permit?
Is all required information readily available, complete and current?
n
it 0 0
Are all records maintained for 3 years (lab. reg. required 5 years)?
0 0 11 0
Are analytical results consistent with data reported on DMRs?
n-
0 in D
Is the chain -of -custody complete?
o
0 a 0
Dates, times and location of sampling
0
Name of individual performing the sampling
D
Results of analysis and calibration
D
Dates of analysis
0
Name of person performing analyses
0
Transported COCs
0
Are DMRs complete: do they include all permit parameters?
n_
0 0 C)
Has the facility submitted its annual compliance report to users and DWQ?
0
0 is 0
(if the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift?
0
0 a 0
Is the ORC visitation tog available and current?
0
0 a 0
Is the ORC certified at grade equal to or higher than the facility classification?
0
0 M 0
Is the backup operator certified at one grade less or greater than the facility classification?
0
0 is 0
Is a copy of the current NPDES permit available on site?
Ig
Cj n_ 0
Facility has copy of previous year's Annual Report on file for review?
0
0 in 0
Page # 3

Permit: NCG500659 owner!- Facility: Facilities Services Central Campus
on Date: 0911112013 Inspection Type: Compliance Evaluation
(eeping Yes No
The facility staff must ensure that all documentation (monitoring
Lion, calibration/maintenance records, reports, etc.) is kept for a minimum of
n-ars as required by the subject permit (Part 11, Section D, Records Retention).
�ry Yes No N
:)arameters performed by certified personnel or laboratory? o no I
ter parameters(excluding field parameters) performed by a certified lab? 001
icility using a contract lab? 001
r"I rn .
Incubator (Fecal Coliform) set to 44.5 degrees Celsius+/- 02 degrees? 00no
Incubator (BOD) set to 20,0 degrees Celsius +/- 1.0 degrees? 00110
Comment: The COD analysis must be performed by a laboratory certified in NC to
perform this analysis. If the on -site staff performs the field analyses (pH, temperature,
total residual chlorine), then all laboratory instrumentation must be calibrated/verified
according to Standard Methods for the Examination of Water and Wastewater, 18th -
20th Editions.
Effluent Sampling Yes No NA NE
Is composite sampling flow proportional? 0 0 a 0
Is sample collected below all treatment units? 1) 0 a 0
Is proper volume collected? 0 0 a 0
Is the tubing clean? 0 0 a 0
# Is proper temperature set for sample storage (kept at less than or equal to 6.0 degrees Celsius)? o Li im no
Is the facility sampling performed as required by the permit (frequency, sampling type representative)? 0 a 0 0
Comment, No effluent sampling has been performed since the issuance of the permit
(7/31/2012). Please be advised that the subject permit requires twice per year
monitoring of the effluent discharge. Two separate effluent sampling events should be
performed prior to the end of 2013. The facility staff must ensure that all
monitoring/sampling documentation is maintained according to the conditions of the
subject permit (Part 11, Section D, Monitoring and Records).
Operations & Maintenance Yes No NA NE
Is the plant generally clean with acceptable housekeeping? 0000
Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge 0 0 11 0
Judge, and other that are applicable?
Page # 4

FPermit: NCG500659 Owner - Facility: Facilities Services Central Campus
Inspection Date: 09/11/2013 Inspection Type: Compliance Evaluation
Operations & Maintenance
Yes No NA NE
Comments Currently, the facility has two cooling tower systems in operation. Two
biocides (alternated) and one corrosion inhibitor are used for these systems. The facility
staff are in the process of determining if one of the biocides currently being used is the
same as the listed biocide (Chem -Aqua 42171) in the permit application package. This
Office should be contacted for further guidance if a different biocide is being used.
The facility staff must ensure that any accumulated debris/sludge from these cooling
tower systems is properly collected and disposed (not discharged into storm drainage
system). In addition, the facility may have to dechlorinate the effluent discharges to
reduce the total residual chlorine levels.
Flow Measurement - Influent
Yes No NA NE
# Is flow meter used for reporting?
0 0 a 0
Is flow meter calibrated annually?
0 0 a 0
Is the flow meter operational?
00110
(If units are separated) Does the chart recorder match the flow meter?
DONO
Commeft The facility staff must ensure to measure and document the flow for each
sampling event.
Effluent Pipe
Yes No NA NE
Is right of way to the outfall property maintained?
0 0 is 0
Are the receiving water free of foam other than trace amounts and other debris?
C) 0 in 0
Ifeffluent (diffuser pipes are required) are they operating properly?
00110
Comment- The facility was not discharging at the time of the inspection.
Page # 5

Fe#1,es
we
P_
From: Johnson, Craig K [[e-mail]
Sent: Friday, September 13, 2013 3,26 PM
To: Justin Nelson
Cc: B.L "Bo" Hightower (bo.hightower@cpcc,edu); Talton Sanders (tsanders@cpcc,edu); Bell,
Wes
Subject: RE: MSDS
Thanks Justin. I'll forward your responce to them
Craig K. Johnson
Chief Engineer, COCA Education Services, Inc
Central Piedmont Community College
1325 East 7 1h Street
Charlotte, NC 28204
ckLohnson caservices.com
craiA.Lohnson2cpcc.edu
Office: 704-330-6627
Cell: 704-574-2272
From: Justin Nelson [e-mail]
Sent: Friday, September 13, 2013 14:32
To: Johnson, Craig K
Cc: B.L Bo Hightower ([e-mail]); Talton Sanders
Subject: Re: MSDS
I will get the labels corrected for the Bacticide 45B and Chem -Aqua 42171. They are the same products just a name changed,
The ANCOOL 3700 is the same product as ANCOOL 3720 but the 3720 is a more concentrated version. I was trying to save you guys a
little bit of money and billed you all the same price as the 3700. Let me know what you need me to do on this, I apologize if I have caused
any confusion.
Sent from Justin's Whone
On Sep 13, 2013, at 2:22 PM, "Johnson, Craig K" <cLkohnson(�i,,(,,ct,-,crvice. s.corn> wrote:
Justin,
CPCC's NPDES permit for Kraft and Giles is up for renewal. The chemicals listed as being used are:
Bacticide 45B
ChemAqua 42171
Ancool3700
Ancool3390
The people at NC Dept of Environment & Natural REsources (NCDENR) have some questions.
• Is Bacticde 45B the same as Bacticide 45? The chemical drum label says Bacticide 45, The MSDS
says Bacticide 45B. The permitt says 45B What is the difference? It there is no difference, the
labels need to match the MSDS and permit
• What is Aquabrorn Plus? This is not listed on the application as a chemical we use. If this is
ChemAqua42171, None of the drums label have this number on it. Again, the drum label needs
to match the MSDS and permit
• Did we stop using ANCOOL 3700? When? The permitt shows we are still using this chemical.
• Is ANCOOL 3720 the same as ANCOOL 37007 If not, what is the difference? We have to let
NCDENR know

PPP"_ PpAny Pchanges to the chemicals used at these building have to be submitted to NCDENR 90 days before we
start using the chemicals.
Please answer these questions as soon as possible.
Thanks for your help.
Craig K. Johnson
Chief Engineer, GCA Education Services, Inc
Central Piedmont Community College
1325 East 7 th Street
Charlotte, NC 28204
ck*oh 1_ [e-mail]
[e-mail]
Office: 704-330-6627
Cell: 704-574-2272
From: Justin Nelson Unelson.9c25chema ua.com]
Sent: Thursday, September 12, 2013 08:51
To: Johnson, Craig K
Cc: 'Justin Nelson'
Subject: RE: MSDS
Craig,
For the towers at these facilities we use the following products:
LRC - No Tower (Now on Central Plant)
Giles - ANCOOL 3390, Aquabrom+/Chem-Aqua 42171, Bacticide-45
Kratt - ANCOOL 3390, Aquabrom+/Chem-Aqua 42171, Bacticide-45
For the Chill and Hot Water Loops at these facilities we us the following product:
ANCOOL 3720
Giles - ANCOOL 3720
Kratt - ANCOOL 3720
The MSDS for all the products listed are attached above.
Thanks,
Justin Nelson
District Manager
Chem -Aqua, Inc.
Cell: [phone]
----- Original Message--__-
From: Johnson, Craig K [ma-'Ll.t.o.ckl-�_ohron@(�caservi'.cc.�s.(,ortiI
Sent: Wednesday, September 11, 2013 9:14 AM
To: Justin Nelson
Subject: MSDS
Justin,
I need the MSDS for the chemicals
Thanks
Sent from my ASUS Pad
used at LRC, Kratt and Giles.
2

PAT MCCRORY
DONALD R. VAN DER. VAART
S..iAY ZIMMER AN
r. 31r e s S F
April 26 2016 Fir""t i
Mr. Bo Hightower
Central Piedmont Community College
P.O. Box 35009
Charlotte, NC 8235-5009 :., AL 0FFI CE
Subject: Renewal of General :Permit NCG50000O
Facilities Services Central Campus
Certificate of Coverage NC5OO65
Mecklenburg County
Dear Permittee:
The Division hereby reissues Certificate of Coverage (C.ioC) NCG5009 under General Permit
777777777-
permit application. Unless such demand is made, the ce.
;a ua e:aaa Ly#..
General Permit, please contact Charles Weaver of the NPDES staff [919 807-6391 or
charles.weaverCncdenr.gov]: '
Sine ely,
k
for S. Jay Zimmerman, ector
Division of Water Resources
cc:
ftS"eWN~
.
State of North Carolina Environmental Quality E Water Resources
1617 Mail Service tenter I Raleigh, NC 27699-1617
919 807 6300" 919-807-6389 FAX
https://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/np es -wastewater -permits

D:EI
CERrr
--DISCHARGE-OF NO]
WITH HYDROELEC'
NATIONAL l
In compliance with the prof
regulations promulgated an
t:
is hereby authorized to
to receiving waters designs
subbasin 03-08-34 of the C
monitoring requirements,
This certificate of covera
This Certificate of Cover
Signed this day April 26

A*4
NCNEWR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Beverly Eaves Perdue Charles Wgild, P.E. Dee Freeman
Governor Director Secretary
RECEIVED
DIVISIONOF WWTER QUALITY
July 31, 2012
Mr. Bo Hightower AUG 2 0 201Z
CPCC Leaming Resources Center
1201 Elizabeth Avenue SWP SECT ' =ON
Charlotte, NC 28204 MOOSV REILLE REGIONAL OFFiCt'..
Subject: Certificate of Coverage NCG500659
General Permit NCG500000
Central Piedmont Community College
Mecklenburg County
Dear Mr. Hightower:
In %AA+h vn,i ir cinnfif-ofinn fnr tlict-h--%rna ffism nivicinn i.-- f(InAlZird inn htzrpwith thp -,I ihip.nt r.P-rtifir..qtF* of Cnvprnrip
WIN
10'=LL 1Gf.Ff lwlwi' lluljlwj + 4'WW4 -w-w, W1 WY
Sincere
des Wakild, P.F.
cc,
wiftwwt#
@meck1enbuMgcgqnn1ty�n
NPDES General Permit Files
Central Files
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Location: 512 N. Salisbury St. Raleigh, North Carolina 27604
One
Phone: [phone] \ FAX: [phone] k Customer Service: 1--877-623-6748
NghCarolina
Internet, www,nrwaterquatiV.org
WulfallY
An Equal Opportunity 1 Affirmative Action Employer

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Now
1011IME
00: Non -contact cooling water, boiler blowdown, cooling tower blowdown, condensa
grit source discharges
(Please print or type)
1) Mailing address* of ownerloperator:
Company Name
Owner Name Eo i-Tini-iTooer,
Street Address = Je—
city ja�— State ZIP Code ;:)q�—)64
Telephone No. -1t Fax: I Jp4g
Address to which all permit correspondence will be mailed
2) Location of facility producing discharge: (6�-
Facility Name r(AY"A lt--ke-5 iP90N
Facility Contact
Street Address
City State ZIP Code
-T
County L
Telephone No. Fax: :Ibq
3) Physical location information:
Please provide a narrative description of how to get to the facility (use street names, state road numbers,
and distance and direction from a roadway intersection). ju-n 'l hr-np OU4 �)Lt"} k4�O
SO -
I L
(A copy of a county map or US GS quad sheet with facility clearly located on the map is required to be sZ­itted with this application)
4) This NPDES permit application applies to which of the following:
Newor Proposed ':z:1'4e-4ef4 241*"
0 Modification
Please describe the modification:
0 Renewal
Please specify existing permit number and original issue date:
5) Does his facility have any other NPDES permits? FER 2
'*WR. WATER QUALITY
No 071ftiAND STORMWATCR SRAKH
0 Yes
If yes, list the permit numbers for all current NPDES permits for this facility:
6) What is the nature of the business applying for this permit? 0-bi
Page I of 4 04/05

PPFF-
NCG a0f OOO N.O.I.
e) Final specifications for all major treatment components (if applicable). The specifications must be
signed and sealed by a North Carolina registered Professional Engineer and shall include a narrative
description of the treatment system to be constructed.
I certify that I am familiar with the information contained in this application and that to the best of my
knowledge and belief such information is true, complete and accurate.
Printed dame of Person Signing.
Title.- C «t
I I a>ol
('Signature of Applicant) (Gate Signed)''
North Carolina General Statute 143-215.6 b (i) provides that;
Any person who knowingly makes any false statement, representation, or certification in any
application, record, "report, plan or other document filed or required to be maintained under Article 21
or regulations of the Environmental Management Commission implementing that Article, or who
falsifies, tampers with or knowingly renders inaccurate any recording or monitoring device or method
required to be operated or maintained under Article 21 or regulations of the Environmental
Management Commission' implementing that Article, shall be guilty of a misdemeanor punishable by
a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U,S.C.
Section 1001 provides a punishment by a fine of not more than $25,000 or; imprisonment not more
than 5 years, or both, for a similar offense.)
Notice of Intent must be accompanied by a check or money order for $100.00 made payable to:
NCDENR
Mail three (3) copies of the entire package to;
PiS Permits Unit
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina 2769-117
E) e"kli
This application will be returned as incomplete unless all of the following items have been
included.
Check for $Kitt made payable to NCQENR
0 3 copies of county map or U GS quad sheet with location of facility clearly marked on map
0 3 copies of this completed application and all supporting documents
3 sets of plans and specifications signed and sealed by a North Carolina P.E.
11 Thorough responses to items 1-7 on this application
11 Alternatives analysis including present value of costs for all alternatives
The submission of this document does not guarantee the issuance of an NPDES permit
Page 4 of 4 04/05

To: NPDES Stormwater and General Permits Unit
Water Quality Section
Attention: Bob Guerra
Date- March 16,2012
NPDES STAFF REPORT AND RECOMMENDATIONS
County: Mecklenburg
NPDES Permit No.: NCG500659
Facility and address: CPCC Facilities Services
1201 Elizabeth Ave
Charlotte, NC 28204
Date of investigation: March 14, 2012
Report prepared by: Samar Bou-Ghazale, Environmental Engineer 11
Person contacted and telephone number- Michael Talbot, [phone]
take 2 ri onto Elizabeth Avenue to site on right.
6. Discharge point(s), List for all discharge points: -
Attach a USGS Map Extract and indicate treatment plant site and discharge point on map.
7. Site size and expansion area consistent with application- Yes.
& Topography (relationship to flood plain included): Gently rolling, 2- 4% slopes, The site
is not located in any flood plain.
9. Location of nearest dwelling: Several businesses within 500 feet from the site.

au
.Page Two
� � N
i
W. rceceiving stream or alaecteu sumac waLCIN. IALLIe Sugar Creek
a. Classification. C
b. River Basin and Subbasin No.: Catawba 03034
C. Describe receiving stream features and pertinent downstream uses`: The existing
discharge is in a storm drain system that discharges into Little Sugar Creek
approximately 200 feet from the site. Little Sugar Creek has good flow at the
time of the investigation.
PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS
1. a. Volume of wastewater: ;z� 2500 gpd (Design Capacity)
b. What is the current permitted capacity. NIA
C. Actual treatment capacity of current facility (current design capacity): 2500 gpd
d. Date(s) and construction activities allowed by previous ATs issued in the
previous two years: N/A
e. Description of existing or substantially constructed W T facilities. There are no
existing WWT facilities. The discharge consists of condensate and cooling tower
blowdown.
f. Description of proposed T' facilities: There are no proposed WWT facilities.
g. Possible toxic impacts to surface waters: Biocidal additive such as Bacticide 4 B
is being used in the wastewater. Also, Ancool 3390 (540LB) is being used in the
wastewater.
h. Pretreatment Program (POTWs only): Not Needed.
2. Residual handling and utilization/disposal scheme: Residuals generation is not expected.
3. Treatment plant classification: Does not meet minimum criteria for a Class I rating.
4. SIC Code(s): 8221 Wastewater Code(s): 14 MTU Code(s): /A'
PART III'- OTHER PERTINENT INFORMATION
1. Is this facility being constructed with Construction Grant Funds or are any public monies
involved (municipals only)? No public monies were used in the construction of this
facility.
2. Special monitoring or limitations (including toxicity) requests: None at this time.
3. Important SOC/JOC or Compliance Schedule dates: /A

f
PageThree
4. Alternative analysis evaluation:
a. Spray Irrigation: This option is not available given the limited space near the
facility.
K Connect to regional sewer system: Sewer system is available on site. However,
according to Mr. Talbot it is costly and requires some time and planning in order
to connect to it given the location of the discharge to the sewer system.
C. Subsurface: This option is not available given the limited space near the facility.
d. Other disposal options: None that we are aware ol".
PART IV - EVALUATION AND RECOMMENDATIONS
The applicant, CPCC Facilities Services, has applied for a GP for the discharge of up to
2500 gpd of condensate and non -contact cooling water.
The discharge is being released into a storm drain system. The discharge will travel
approximately two hundred feet in the storm water system before discharging into the receiving
stream. The receiving stream is on the 303d list for Copper and Mercury.
It is recommended that a GP be issued provided the biocide has been approved by the
Aquatic Toxicology Unit. Also, we recommend that the permit be issued for only one cycle after
that the permittee is to connect the discharge to the sanitary sewer. -
12,
Signature of Rep arer Date
Water Quality Regional Supervisor Date

NCDENR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Beverly Eaves Perdue Charles Wakild ' RE. Dee Freeman
Governor Director Secretary
February 2, 2012
FEB 14 2 10 12
Mr. Bo Hightower
CPCC Facilities Services
1201 Elizabeth Ave
Charlotte, N.C. 28204
Subject: Receipt of NCG500659 application
Facilities Services Central Campus
Mecklenburg County
Dear Mr. Hightower:
renewal application.
pare astall repurt, WILLI U1116 FrujuUt'.
Lone number or e-mail address listed at the bottom of this page.
Sincerely,
4 �, V
Charles H. Weaver, Jr.
NPDES Unit
One
Vwq NofthCi�
Or

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F500000 N.O.I.
I El - B Z 0. 1 �
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arrative
ny
Printed Name of Person Signing: r� C '4 g�'
Title: 7 ! Yt C
(Signature of Applicant) 3 3 c: (Date Signed)
North Carolina General Statute 143-215.6 b (i) provides that:
Any person who knowngly makes any Use statement, representation, or certification in any
application, record, report, plan or other document filed or required to be maintained under Article 21
or regulations of the Environmental Management Commission implementing that Article, or who
falsifies, tampers with or knowingly renders inaccurate any recording or monitoring device or method
required to be operated or maintained under Article 21 or regulations of the Environmental
Management Commissionimplementing that Article„ shall be guilty of a misdemeanor punishable by
fine not to exceed $2 ,000, or by imprisonment not to exceed six months, or by both, (18 U.&C.
Section 1001 provides a punishment by a fine of not more than $25 000 or imprisonment not more
than 5 years„ or both, for a similar offense.)
Notice of Intent must be accompanied' by a check or money order for $100.00 matte payable to:
NCD NR
Mail three (3) copies of the entire package to:
NPDES Permits Unit
[division of Water Quality
1517 flail Service Center
Raleigh, North Carolina 2 9S-161
Final Checklist
This application will be returned as incomplete unless all of the fallowing items have been
included:
0 Check for $100 made payable to NC©ENR`
0 '3 copies of county map or USGS quad sheet with location of facility clearly marked on map
13 3 copies of this completed application and all supporting documents
113 sets of plans and specifications signed and sealed by a North Carolina P.E.
11 Thorough responses to items 1-7 on this application
0 Alternatives analysis including present value of coats for all alternatives
t
The submission of this document does not guarantee the issuance of an NPDES permit
Page 4 of 4 04/0
nplete and accurate.

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0 2005 Aerial Photography..
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17Community
01 Nexrad Weather Radar
Cloud Cover
Engineering Grid
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I: Traffic
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-ad

Material Safety Data Sheet: CHEM-AQUA 42171
reedes Date Not applicable Issuing Date 03/08/2010
CHEM-AQUA 42171 Product Code TV1 1
of Use Water treatment chemical Blocidal product Chemical Nature Aqueous solution Alkaline
n Manufacturer Emergency Telephone Number
C CHEMTREC 9 800-424-9300
75015
— ---------- E—mergency Overview
DANGER
Corrosive
Causes skin and eye burns
May cause delayed lung injury and burns
Harmful or fatal if swallowed
ow
Physical State Liquid Odor Sll�
4lealth Effects
Route of Exposure
Skin contact, Eye contact, Inhalation,
outes of Entry
None known,
mts
,as
Corrosive to the eyes and may cause severe damage including blindness.
Skin Causes skin burns.
Inhalation Harmful by inhalation. Causes bums.
Ingestion If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and
stomach.
Chronic Toxicity Inhaled corrosive substances can lead to a toxic edema of the lungs
Target Organ Effects Skin, Respiratory system, Spleen,
Aggravated Medical Conditions Skin disorders, Respiratory disorders.
Potential Environmental Effects See Section 12 for additional Ecological information,
9H
ff�l T maim
a��gm'nelkll M2
11 ----Component
CA$ -No
Suffamic acid, n-bromo, sodium salt
Sood—ium hydroxide
1310-73.2-
------ Sod—iurn chloride
General Advice Do not get In eyes, on skin, or on clothing. Do not breathe vapors or spray mist.
Eye Contact Immediately flush with plenty of water, After initial flushing, remove any contact lenses and continue flushing for at
least 15 minutes. Call a physician or poison control center immediately.
Skin Contact Remove immediately all contaminated clothing, Wash off immediately with plenty of water for at least 15 minutes, Call
a physician or poison control center immediately.
Inhalation Move to fresh air. If not breathing, give artificial respiration, Call a physician or poison control centre immediately.
Ingestion Calf a physician or Poison Control Centre immediately, Do NOT induce vomiting, Never give anything by mouth to an
unconscious person,
Notes to Physician The product causes burns of eyes, skin and mucous membranes. Control of circulatory system, shock therapy if
needed,
W­
"A"A" g
Flash Point Not combustible Method Not applicable
Autoignition Temperature No information available,
Flammability Limits In Air % Hydrogen, by reaction with metals. Upper 75 Lower4
Suitable Extinguishing Media
Water spray. Foam, Alcohol -resistant foam, Carbon dioxide (CO2). Dry chemical, Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Specific hazards arising from the chemical
Material can create slippery conditions, Contact with metals liberates hydrogen gas,
Protective Equipment and Precautions for Firefighters
As In any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NJ0SH (approved or equivalent) and full protective gear.
NFPA Health 3 Flammability I Instability 0
HMIS Health 3 Flammability I Instability 0
Page 1 /4

- H ull A 2UA 42171 Issuing
0
notions
Use personal protective equipm,
conditions,
Precautions
Do not flush Into surface water
)ntainment
Contain spillage, soak up with nt
and transfer to a container for di
waning Up
Pick up and transfer to properly
lent
Acetic acid, diluted
Handling Do not get In eyes, on skin, or on di
Storage Store In original container. Keep co
must be lined. Do not freeze. Keep
Storage Temperature Minimum 45°F!7°C
Storage Conditions Indoor ' X Gutd
.. 1
Exposure Guidelines
•.leakage or spillage if safe to do so. Matt
>ystem.
,led :containers:.
rom direct sunlight.
Maximum 100°F138'
Heated Refri
Component
ACGIH TLV
I OSHA PEL
NIOSH
Sutfamie acid, n-bromo, sodium salt
No data available ;
No data available
No data available
Sodium hydroxide
ceiling: 2 mg/Ms
TWA: 2 mg/ma
JOLH: 10 mgtms Ceiling. 2 mg/ms
Sodium chloride
No data available
5 im/ma RNOR (as solid)
No:tlata avalfatfe
Engineering Measures
Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/Face Protection
Tightly fitting safety goggles. Face -shield.
Skin Protection
Wear suitable protective clothing, Impervious gloves.
Respiratory Protection
Use NIOSH approved respiratory protection. When workers are facing concentrations above the exposure limit they
must use appropriate certified respirators,
General Hygiene Considerations
Wear protective gloves/clothing. Ensure that eyewash stations and safety showers are chase to the workstation
location;
Physical State
Liquid Viscosity
Non viscous
Color
Yellow Odor
Slight chlorine
Appearance
Transparent pH
>13
Specific Gravity
1.32 Evaporation Rate
0.38 (Butyl acetate=l )
Percent Volatile (Volume)
715 VOC Content (%)
0
VOC Content (g/l)
0 Vapor Pressure
11.8 mmHg @ 70 °F
Vapor Density
0.6 (Air = 1.0) Solubility
Completely soluble
Boiling Point/Range
No data available
Chemical Stability
Stabler Hazardous polymerization does not occur.
Conditions to Avoid
None known.
Incompatible Products
Strong: oxidizing agents, Acids, Metals:
Hazardous Decomposition Products
Carbon oxides, Nitrogen oxides (NOx), Sulfur oxides, Sulfur compounds, Sodium''
oxides, Bromine, Fumes of bromine, hydrogen bromide,
Possibility of Hazardous Reactions
None under normal processing.
Product information No information available.
Component Information
Acute toxicity
Component
LD50 Oral
LD5tS Dermal
LC50 Inhalation
Chronic Toxicity
Component
Mutagen city
ensitization
Developmental Toxicity
Repraduetiva Toxicity
Target Organ Effects
8ulfamc acid, n-bromo, sodium salt
no data available
no Data avaitabie
: no data available
Hddata ava'rlabia
no data available
Sodium hydroxide
no data available
no data available
no data available
no data available
eyes, respiratory system,
iiralxa Test
Other
Suifamic acid, rnbromo, sodium sett
` no data available
no data available,
no data available
nci data available
no data available
Sodium Hydroxide
no data available
195i? mglhg {Rabbit }
no data available
no data available
no data available
Sodium chloride
3 glkg {Rat)
togtag { Rabbitj
42 glma {Flat } 1 h
no data available
no data available
Paget

CHEM-AQUA 42171
1 1 1
Issui
Carcinogenicity There are no known carcinogenic chemicals in this product.
Component ACG(H C NTP Other
I ulfamfe acid. n-bromo, sodium salt I not emolica '4R not awlicable
6 rl I ble nor �—.. Gbl. not awlicable, not apollcable
criforice I I I
not applicaole not apiaticame not appicamie
Triation No information available.
n1formiation
Component
Toxicity to Algae
Toxicity to Fish
microtox
Water Flea
laug ow
Sultarmc acid, n-bromo, sodium salt
no data available
no date available
no data available
no data available
NIA
Sodium hydroxide
no data available
96 Hr LC50 Oncorhynchus myluss: 45.4
no data available
no data available
NIA
mg/L (static]
Sodium chloride
no data available
96 Hr LC50 Leporris macrochirus; 5560-
no data available
48 Hr EC56--D—aphnia magna:
—N/A
6080 mg/L (flow-throughl� 96 Fir LC50
1000 mg/L; 48 Hr EC50
Lepornis macrochirus: 12946 mg/L [static);
Daphnis mailed: 3403 - 469,2
96 Hr LC50 Pimephales prommac 6020-
mg/L [Static)
7070 mg/L [static]; 96 Hr LC50 Pimermales
promelas: 7050 mg/L [somi-static]: 96 Hr
LCSO Pimernales promelas: 6420-6700
mg/L tsla4fi;]�,,96 Hr LC50 Oncorhymhus
arrykcia, 4 .7824 mg/L [flow -through]
Persistence and Degraclability No information available.
Bloaccumulation No information available.
Mobility No information available,
P,
Una,
=22=1'i
2
Product Disposal Dispose of in accordance with local regulations.
Container Disposal Empty containers should be taken for local recycling, recovery, or waste disposal.
DOT
Proper Shipping Name
Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class
UN -No
UN3266
Parking Group
[it
Description
UN3266, Corrosive liquid, basic, inorganic, n,o.s,(Sodium hydroxide), 8, PG III
TDG
Proper shipping name
Corrosive liquid, basic, inorganic, n,o.s.
Hazard Class
8
UN -No
UN3266
Packing Group
III
Description
UN3266,Corrosive Liquid, Basic, Inorganic, N.0,S.(Sodium Hydroxide ),B,PG III
ICAO
UN -No
UN3266
Proper Shipping Name
Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class
8
Packing Group
III
Shipping Description
UN3266, Corrosive liquid, basic, inorganic, n.o.s.(Sodium hydroxide),8,PG III
IATA
UN -No
UN3266
Proper Shipping Name
Corrosive liquid, basic, inorganic, n,o.s.
Hazard Class
8
Packing Group
III
ERG Code
8L
Shipping Description
UN3266,Corrosive liquid, basic, inorganic, n,o,s,(Sodium hydroxide ),8,PG III
IMDGAMO
Proper Shipping Name
Corrosive liquid, basic, inorganic, n.o.s.
Hazard Class
8
UN -No
UN3266
Page 3 / 4

P,
(111 - CHEM-AQUA 42171
Packing Group III
EmS No. F-A, S-B
Shipping Description UN3266, Corrosh
Complies
Does not Comply
Regulations
'Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA)i, This product does not contain any chemicals which are subject to the
rements of the Act and and Title 40n of the Code of Federal Regulations, Part 372,
2 Hazardous Calteocrization
No I No
tions
ition 65 This product contains the following Pa
Hazard
No
pillcable 4
Natalia
00 In
Notapp,
)placable
Notapp
isition 65 chemicals
Leon
!a I
--nai— . ...... .' .— lot " — --V
initial date 2127187
Mercury...7439-97-6
developmental toxicity,:initial dah
Nickel
1440-02-0
carcinogen, initial date 617104 carcinogii
1011/89
Arsenic
7440-38.2
carcinogen, initial date 2J271
Cariniurn
7440-43-0
carcinogen, initial date 1011/67 develorin
initial date 511197 mate reproductive text
anala
his product may not be commercially placed on the market in Canada
IIHMIS Hazard Class
at applicable
Dan Hollas
li Not applicable
03/0812010
ilon No information available.
No information available.
Ds. No information available.
considered as a warranty or quality specification. The Information rotates only to the specific material closignated and may not be valid for such
material used In combination with any other material or In any process, unless specified In the text.
Page 414

Material Safety Data Sheet: BACTICIDE 458
rdes Date 06112/2007
Issuing Date 05/1812010
Us," , P" � 5 � T, —M
Name BACTICIDE 458
Product Code 0684
vended Use Blocidal product
Chemical Nature Aqueous solution
than on Manufacturer
Emergency Telephone Number
WA, INC
CHEMTREC 0 800-424-9300
170
TEXAS 75015
-Emergency Overview
DANGER
Corrosive
Causes skin and eye bums
May cause allergic skin reaction
May cause delayed lung injury and burns
Harmful or fatal if swallowed
alorless
Physical State Liquid Odor Pungent
it Health Effects
a Route of Exposure
Skin contact, Eye contact, Inhalation.
Routes of Entry
Skin Absorption, Ingestion,
ffects
-Yos
Corrosive to the eyes and may cause severe damage including blindness.
akin
Causes skin burns. May cause allergic skin reaction.
nhalation
Harmful by inhalation. Causes bums.
ingestion
If ingested, severe bums of the mouth and throat, as well as a danger of perforation of the esophagus and the
stomach. May cause central nervous system effects such as headache, dizziness, weakness, staggering gait,
nausea, blurred vision, excitation, and in extreme cases, coma or death,
Toxicity
May cause sensitization by skin contact, Liver injury may occur,
)rgan Effects
Respiratory system, Skin, Central nervous system, Bone Marrow, Liver,
ited Medical Conditions
Respiratory disorders, Skin disorders, Liver disorders, Neurological disorders,
it Environmental Effects
See Section 12 for additional Ecological information.
pq romp" 'p"T
MA
Component
CA-S-No
Glufaraldehyde-
11 1Fso__8
ce Do not get in eyes, on skin or on clothing. Do not breathe vapors or spray mist.
If in eyes, rinse with water for 15 minutes. Remove contact tenses. Call a physician or poison control center
immediately.
Take off all contaminated clothing immediately. Wash off Immediately with plenty of water for at least 15 minutes. Call
a physician or poison control center Immediately.
Move to fresh air. Give oxygen or artificial respiration if needed. Call a physician or poison control center immediately,
Call a physician or Poison Control Center immediately, Do NOT induce vomiting,
;Ician Aspiration hazard if swallowed - can enter lungs and cause damage, Probable mucosal damage may contraindicate
the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsions may be
needed
Flash Point >201'F/>94'C Method Closed cup
Autolginificin Temperature No information available.
Flammability Limits In Air % Hydrogen, by reaction with metals. Upper 75 Lowsr4
Suitable Extinguishing Media
Foam, Alcohol -resistant foam, Carbon dioxide (CO2), Dry chemical. Water spray. Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Specific hazards arising from the chemical
Contact with metals liberates hydrogen gas. Material can create shop" conditions.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA Health 3 Flammability I Instability 0
HMIS Health 3 Flammability I Instability 0
Pagel / 4

34i- BACTICIDIE 45B Issuing C
to 18-May- 01
ins Use personal protective equipment,
conditions.
wautions Do not flush into surface water or "s
lament Contain spillage, soak up with non-(
and transfer to a container for dispc
ng Up Pick up and transfer to properly lath
Not applicable.
31 can create slippery
.sous earth, vermiculite)
3),
d containers.
F..N ,�.s.r,..a ... f!*a. •', ',' t .,.,.. w...t
Leo not get in eyes, on skin or on clothing. Do not breathe vapors or spray mist.
Keep away from open flames, heat surfaces and sources of Ignition. Store in original container. Keep containers
tightly closed in a dry, cool and well -ventilated place. Metal containers must be lined, Do not freeze.
iture Minimum 25°Ft-4'C Maximum 104°FF3a"C
is Indoor X Outdoor Heated Refrigerated
! aOT
Exposure Guidelines
Component
ACGFH TLv
Glularaldehyde
.05 ppm Ceiling (activated and inae
Engineering Measures
Ensure adequate ventilation, espt
Personal Protective Equipment
Eye/Face Protection
Tightly fitting safety goggles. Feet
Skin Protection
Wear suitable protective clothing,
Respiratory Protection
in case of insufficient ventilation i
above the exposure limit they mu
General Hygiene Considerations
Remove and wash contaminated
close to the workstation location.
Y„vld?'R NMAOO k``" \'� J.^a'. 'u
Physical State "'
Liquid
Color
Colorless
Appearance
Transparent
Specific Gravity
1,12
Percent Volatile (Volume)
100
VOC Content (g!I)
509
Vapor Density
1.0 (Air = 1.0)
Selling PointlRange
213*Ff101°C
Comp
Acute
ff
Chron
on Products
r Reactions
"M
L050 Oral
rat 1 111 mg/kg�
"Skin
Sensitization
May cause allergic skin
reaction
it Information
City
:omponent
LO60 Orel LD50 thermal...
utaraldehyde
66 mgtkg ( Rat) 2000 mg/kg ( Rat) 560 pL
t Rabbit 1
ter system.
d:
vious gloves.
unable respiratory equipment. When workers are facing concentrations
appropriate certified respirators.
ig before re -use. Ensure that eyewash stations and safety showers are
cosity
Non viscous
or
Pungent
3.1
aporation Rate
1.0 (Butyl acetate-1 )
C Content (%)
45,5
oor+Pressure
0.2 mmHg toy °F
utillity
Completely soluble
azardous polymerization does not occur.
Res, and sparks
on; oxides
a under normal processing.
LDS' Dermal
ratlb{t 1,,m-3,170 mg/k�
LC50 inhalation 7 tlrxlze Test O;liar
0.1 mall. ( Rat) 4 h I no data available no data ova
Mutagenicity ensitization Developmental Toxicity Reproductive Toxicity
no data available skin sensitization no data available no data available 0
Doge 214

4 - BACTICIDI: 45B Issuing
nogenicity There are no known carcinogenic chemicals in this product.
Umiaramenya. I not appicame I noi 8PPRCaDle net aeetCaDle not appucam. ncn app,rue
Product Information Toxic to aquatic organisms.
Comnanant Information
Component
Toxicity to Algae
Toxicity to Fish
Microtox
Water Flea
log Pow—
Glutaraldehyde
EC60= 0.61 mg/L —
M90=- 57 ;79/1 Pimephales promelas 96 h
EC50 = 13,3 mg/L 17 h
EC50 0,56 - 1.0 mglL 48 h
0.22 at 25
Desmodesmus subspicatus 72
t-050 7.8-22 mg/L Lopornis macrochirus 96
EC50 = 76,0 mg/L 5 min
EC50 - 14 m91L 48 It
C [OECD
h EC50= 0,84 mg/L
h LC50 7.8-13 mg/L OncorhynchUS mykiss
Guideline
Desmodesmus subspicatus 96
96 h LC60 2.6-4.8 mg/L Oncorhynchus
1071
h
mykiss 96 h
Persistence and Degradability No information available.
Sioaccumulation No information available,
Mobility No information available.
Inventc
TSCA
DSL
Dispose of In accordance with local regulations.
I Empty containers should be taken for local recycling, recovery, or waste disposal. Do not re-u
- Shipping Name
Corrosive liquid, acidic, organic, n.o.s.
I Class
8
UN3265
ig Group
11
ption
UN3265, Corrosive liquid, acidic, organic, ri.o.s.,(Glutaraldehyde), 8, PC 11
r shipping name
Corrosive liquid, acidic, organic, n.o.s.
I Class
8
UN3265
ig Group
11
ption
UN3266,Corrosive Liquid, Acidic, Organic, mo,s., (Glutaraldehyde),UG 11
UN3265
r Shipping Name
Corrosive liquid, acidic, organic, n.o.s.
11 Class
8
ig Group
11
ng Description
UN3265, Corrosive liquid, acidic, organic, n,o.s.,(Glutaraidehyde ),8,PG 11
UN3265
Shipping Name
Corrosive liquid, acidic, organic, n.o.s.
I Class
8
ig Group
11
ode
8L
ng Description
UN3265,Corrosive liquid, acidic, organic, n.o.s.,(GIutaraIdehyde),8,PG It
, Shipping Name
Corrosive liquid, acidic, organic, n.o.s.
I Class
8
UN3265
ig Group
11
0.
F-A, S-B
ng Description
UN3265, Corrosive liquid, acidic, organic, n.o.s.,(GIutaraIdehyde),8,PG 11
Complies
Complies
Page 3 /4

0684 - ACTICID4 aB Issuing Date 18-Maur- g10
U.S, Federal Regulations
SA 313
Section 313 of Title III of the SuperfundAmendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the
reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372,
SARA 311f312 Hazardous Categorization
Acute Health Hazard: Chronic Health Hazard ire Hazard' Sudden Release of Pressure Reactive Hazard
Hazard
Yes Yes No No No
CERCLA
Component Hazardous Substances TEE
CIRCLA aHs RQa
lutaraidehyde Not applicable Not app4cobte
U.S. State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
Canada
This product Is exempt from WHMIS due to PCP registration
WHMIS Hazard Glass
Exempt
R l�l i f�
Prepared By pan Hellas
Supercedes Date 06112/2007
Issuing Date 05/18/2010
Reason for Revision No information available.
Glossary No information available.
List of References, No information available.
CHEM-AQUA, INC assumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product In a
manner not recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the
product. The Information provided on this MSDS Is correct to the best of our knowledge, Information and belief at the date of its publication. The
information given Is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be
considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such
material used in combination with any other material or In any process,' unless specified in the text.
Peg / 4

I
4S 75015
Material Safety Data Sheet:
• P
G
Causes $I
May cause delay
Harmful or
Color Yellow Physics
Potential Health Effects
Principle Route of Exposure Skin contact, Eye contact, Inht
Primary Routes of Entry inhalation
Acute Effects
Eyes Corrosive to the eyes and me,,
Skin Causes skin burns.
Inhalation Harmful by inhalation. Causes
Ingestion if ingested, severe burns of in
stomach:,
Chronic Toxicity Inhaled corrosive substances
Target Organ Effects Respiratory system, Liver, Kid
Aggravated Medical Conditions Respiratory disorders, Skin di
Potential Environmental Effects See Section 12 for additional I
Component
odium hydroxide
Polyethylene glycol
2-Propenoic acid, ethyl ester, polymer with ethenyl acetate and 2,5-furandionr
hvdrnlvra:ci sodium salt
ANCOOL 3390 (540 LB)
'e'i t=-JO-v
403 2-66-
hSl11', t'i4rJi3'^}, h"FWr *,Y.1:., s,`?ta,
General Advice Do not get in eyes, on skin or on clothing.. Do not breathe vapors or spray mist.
Eye Contact immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at
least 15 minutes. Get medical attention immediately.
Skin Contact Remove immediately all contaminated clothing. Wash off immediately with plenty of water for at least 15 minutes. Get
medical attention immediately.
Inhalation Move to fresh air. In case of shortness of breath, give oxygen, If not breathing, give artificial respiration, Get medical
attention immediately.
Ingestion Drink 1 or 2 glasses of water. Do NOT induce vomiting, Get medical attention immediately, Never give anything by
mouth to an unconscious person.
Notes to Physician The product causes burns of eyes, skin and mucous membranes, Control of circulatory system, shock therapy if
needed.
Flash Point >201°Fl>94°C Method Estimated
Autolgnition Temperature No information available
Flammability Limits in Air % Hydrogen, by reaction with metals, Upper 75 Lower 4
Suitable Extinguishing Media
Water spray. Foam. Alcohol -resistant foam. Carbon dioxide (CO2). Dry chemical. Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment:
Specific hazards arising from the chemical
Page 1 1

-.A 1COOL °33 0 (540 LB) Issuing Cate
with metals liberates hydrogengas. Material can create slippery conditions.
:lve Equipment and Precautions for Firefighters
ty fire, wear self-contained breathing apparatus pressure -demand, MSHAINIOSH (approved or equivalent) and full protective gear,
Health 3 Flammability 1 instability 0
Health 3 Flammability 1 instability 0,
titans
Use personal protective equipment. Prevent further leakage or spillage if safe to do so. Mat€
conditions.
recautions
Do not flush into surface water or sanitary sewer system,
nainment
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatom
and transfer to a container for disposal according to local / national regulations (see section
fining Up
Pick up and transfer to properly labeled containers,
at
Acetic acid, diluted.
Handling
Do not get in eyes, on skin or on (
Storage
Store in original container. Keep c
must be listed, Do not freeze.
Storage Temperature
Minimum 3°F/2°C
Storage Conditions
Indoor X Ou
kit Y F'
Exposure Guidelines
Component
ACGIH TLV
Sodium hydroxide
2 mglm3 Gelling
Polyethylene glycol
No data available
2-Propohoic acid, ethyl ester, polymer With e#henyl acraide No dstd-avaiiable
and 2,6-furardione, hydrolyzed, sodium salt
2-Fhctstrhontsbutana.: i„2,4•tncatboxyiac acid,.sodiunt salt No data available '.
Sodium tolyltrlazole
No data available
Sodium polyacrylate
3 rmc m3 PNQS
Phosphontc acid, tnitrifobisn'romyleneftns; sodium salt No data available
Sodrum molybdate
TWA: 0,5 mgtm3
Engineering Measures
Use with local exhaust ventilation:
Personal Protective Equipment
Eye/Face Protection
Tightly fitting safety goggles, Faci
Skin Protection
Wear suitable protective clothing,:
Respiratory Protection
In case of inadequate ventilation
exposure limit they must use appi
General Hygiene Considerations
Wear protective gloves/clothing, l
location.
Liquid
Yellow
Transparent
1,14
Volume) 79.1
0
0.6 (Air =1.0)
le 212°F/100°C
Maximum 105*F141°C
r Heated Refrigerated
1
:Deity Non viscous
r Slight
14
poration Rate 0,46 (Butyl acetate-1 )
Content (°k) 0
or Pressure 14.9 mmHg(,?a 70 °F
ability Completely soluble
Chemical Stability Stable, Hazardous polymerization does not occur.
Conditions to Avoid Heat, flames, and sparks
ncompatible Products Strong oxidizing agents, Reducing agents, Acids, Aldehydes, Haloge
hydrocarbon, Leather, Oxides of phosphorus, Tetrahydrofuran, MetE
Hazardous decomposition Products Carbon oxides, Nitrogen oxides (NOx), Oxides of phosphorus, Phosi
compounds, Alcohols, Ketones„ Hydrogen cyanide, Contact with met
hydrogen gas.
Possibility of Hazardous Reactions None under normal processing.
Product Information No information available
Pe
; 15
:rates

PFF47TZ- ANCOQC3 0 (540 LB) Issuing Cate 0 -Aug-2010
Component Information'
Acute toxicity
Component 1-050 Oral LOSO Dermal Los0 inhalation Dralze Test other
Sodium hydroxide no data available 1350 mglkg ( Rabbit } no data available no data available no data available
: Polyethylene glycol 28 glkg ( Rat ) 20 glkg ( Rabbit ). no data available no data available = no data available
-Propenote acid, ethyl ester, poly e no data available no data available: no data available no data available no data available
with ethenyl acetate and 2,5-
furandione, hydrolyzed, sodiuln salt
7,.Phosphonot,utane-1,2,4-tricarboxylic no data available no data available :: no data available no data available ` no data available
acid, sodium salt
=tm0hylene)Itris-,
' Iniazole no data available no data available: no data available no data available no data available
yacrylato 44 glRg (Rat) no data available no data systems no data available no data available
id, tnittdiot€is: Inc+ data available no date avaitable' no data available no data available no data available
sodium salt
olybdate 4 9/kg ( Rat) no data available: 2080 mglmd (: Rat ) 4 h no data available no data available
Chronic Toxicity
Compc nont utagenicity Sensitization Developmental Toxicity Reproductive Toxicity Target Organ Effeots
Sodium hydroxide no data available no data available: no data available no data available ayes, respiratory system,':
skid
Polyethyte»e glycol no data available no data available- no data available no data available no data available
-Propenoic acid, ethyl ester, polymer ' 11 na 11 data available no data available: no data available no data available :: no data available
witYethonyd acetate and 2,5-
furandlone, hydrolyzed, sodium salt
-phosphonobutane•:1,2,44ricarbbxyli no data available no data available . no data available no data available : no data available
acid, sodium salt
i Sodium lolyttriazoie no data available no data available no data available no data availat:Yei no data available
Sodium polyacryiate no data available no data available no data available no data available no data available
Phosphorite acid, f abbotre, :no data available no data available: no data available no data available no data available
(methydems)Jois:, sodium salt
Sodium molybdate no data available no data available: no data available no data available Bones, CNS, kidneys, liver,
blood
Carcinogenicity
component AColl IARC ;IYTP OSHA Other
Sodium hydroxide not applicable not: applicable not applicable - not applicable not applicable
Polyethylene glycol not applicable not applicable ": not applicable not applicable not applicable
-Propereem acid, ethyl ester, polyma not applicable not applicable not applicable :: not applicable not applicable
with:ethenyl acetate and 2,5-
furandlone, hydrolyzed, sodium salt
2-Pliosphonobutane-1,2,4-tricarboxytic not applicable not: applicable : not applicable not applicable not applicable
acid, sodium salt
Sodium tolyttriazole not applicable n
ot applicable not applicable : not applicable not applicable
Sodium polyacrylism not applicable dents not applicable not applicable no# apptcabto
Phosphoric sold, (nitrilolds� not applicable cable not applicable not applicable not applicable
{methylona)1tris-, sodim salt
Sodium molybdate AS cable not applicable not applicable not applicable
4� "a`, •. ,'�'' ?,"i;N..��::..:?..�v s�. y,1, w;>'.`'�z'xre "z xt C ��3 tt;.,�,2",'^e, qua' a't"w'�':?:a,.'WsMt,�i
Product Inflammation No information available.
Component Information
component Toxicity to Algae Toxicity to Fish Illiterates Water Elea log Pow
Sodium hydroxide : no data available 7C50= 41, 4 mgn. Oncorhymmus myk ss 96 n data avettablo' no data available NIA
h
Polyethylene glycol no data available LC50>:$000 mg1L Caresses auratus 24 h EC50 = 100000 mgiL 15 min no data available N/A
2-Propenoic acid, ethyl ester, polymer no data available no data available no data available no data available NIA
with othenyl acetate and 2,54uranddone,
hydrolyzed,: sodium salt
2-Phosphonobutane-1.2,4-tricarboxylic be date available no data available.... no data available: no data available N/A
acid, sodium salt
sodium tolyariazon, : no data available no data available.: no data available : no data available NIA
Sodium polyacrylate no data: available no data available:... no data available. :. no data available NIA
Phosphondc acid, biltrilotilipmethyieno)i no data:: available .. no data available :.. no data available no data available NIA r.
Iris-, sodium salt
Sodium molybdade no data available no data available no data available no data available N/A
Persistence and Degradability No information available.
ioaccumulation No information available.
Nubility No information available,
E;~'.k C �:#a .'§*"3 �,,,^: cue
Product Disposal Dispose of in accordance with local regulations.
Page 315

Z -: ANCC 912 3390 (540 LB)
issuing Gate 06-Aug-201
Container Disposal
Empty containers should be taken for local
recycling, recovery, or waste disposal.
c
DOT
Proper Shipping Name
Sodium hydroxide solution
Hazard Class
8
UN -No
UN1824
Packing Group
It
Reportable Quantity (RQ)
Sodium hydroxide, RQ Kg=12061.64
Description
UN1824, Sodium hydroxide solution 8, PG it
TDG
Proper Shipping name
Sodium hydroxide solution
Hazard Class
8
UN -No
UN1824
Packing Group
it
Description
UN1824, Sodium hydroxide solution„ 8, PG It
ICAO
UN -No
UN1824
Proper Shipping Name
Sodium hydroxide solution
Hazard Class
8
Packing Group
11
Shipping Description
UN1824, Sodium hydroxide solution, 8, PG 11
IATA
UN -No
UN1824
Proper Shipping Name
Sodium hydroxide solution
Hazard Class
8
Packing Group -
ll
ERG Code
8L
Shipping Description
UN1824 Sodium hydroxide solution, 8, PG 11
IM0011 ICf
Proper Shipping Name
Sodium hydroxide solution
Hazard Class
8
UN -No
UN1824
Packing Group
It
Sm$ No.
F-A, µS
Shipping Description
UN1824, Sodium hydroxide solution,8,PG 11
Complies
Complies
I Regulations
of Title Ili of the Superlund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals whiet
ulrements of the Act and and Title 40n of the Code of Federal Regulations, Part 372,
12 Hazardous Catefforization
Acute Health Hazard Chronic Health Hazard
Fire Hazard
Sudden Release of :Pressure
Reactive Hazard
Hazard
I
Yes Yes
N i
No
No
omponent Hazardous Substances R a I CERCt,A ells Rao
';ao lurrl nyoroxicle
p
'Vat appacaote
Not appiFcaoie
PCiyethylene glycol
Not applicable
Not applicable
C acid, ethyl ester, pofyiner with ethenyl acetate and
Not applicable
Not applicable
2,5-furandione, hydrolyzed, sodium salt
Jho6o6pati6e-1 2,4-tricarboxylic aold,:sodium salt
Not applicable
Not applicable
odium tolyltnazoie
Not applicable
Not applicable
Sodium polyacrylate
Not applicable
Not applicable
ionic acid, fnitrilot(is(m6thyfe6qi)lfeie--I Sodium Salt
Not applicable
Not applicable
Sodium molybdate
Not applicable
Not applicable
agulations
re....ul .n en This roduct contains the fall -win
Pro osition 65 chem`cals
i
mponent CAS -No .:California Prop. &S
t-Dioxane 123-91.1 carcinogen, initial date 111188
Page 4/5

ICOOL 3390 (540 LB) Issuing Da
Lead
1317-36.8
carcinogen, initial date 1011M developmental toxicity„ .'.
initial date 2127/87
Formaldehyde.
50-00-0
carcinogen, initial date it1188 (gas)
Mercury
7439-87-6
developmental toxicity, initial date 711/90
Nickel
7440-02-0
carcinogen, initial date 5t7104�arc ogogen, initial date
1011/89
Arsenic
7440=38-2
carcinogen, initial date 2127/87
Cadmtum
744043-9
carcinogen, initial hate 1011187: developmental tox0ty,
initial elate 511197 male reproductive toxicity, initial date
5/ 1197
Acetaldehyde;
75-07-0
carcinogen, Initial hate 411/88
Ethylene oxide
75-21-8
carcinogen, initial:. date 711/87:;developmental toxicity,
r777initial
date 8/7109 male reproductive toxicity, Initial date`-
817f09 female reproductive toxicity, initial date 2127/87'
is been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the
ulred by the CPR.
'lass
net, D2A Very toxic materials.
r
Dan Hollas
Ito 05/0112007
08/06/2010
rislon No information available.
No information available.
CM No information available,
material used in combination with any other material or In any process, unless specified in the text.
Page 515

Material Safety Data Sheet: ANCOOL 3700 (575 LIB)
oereedes Date 10130/2006 Issuing Date
no ANCOOL 3700 (575 LB) Product Code 48TZ
led Use Water treatment chemical Chemical Nature Aqueous solution of alkali safts,
on Manufacturer Emergency Telephone Number
INC CHEMTREC 0 800-424.9300
M
Causes
r Light yellow
Physic
ntlat Health Effects
-iple Route of Exposure
Skin contact, Eye contact, In
sty Routes of Entry
None known
a Effects
Eyes
Corrosive to the eyes and in
Skin
Causes skin burns
Inhalation
Harmful by inhalation. Cause
Ingestion
If ingested, severe bums of
stomach. Blood disorder me)
nic Toxicity
Inhaled corrosive substance
may lead to the formation of
injuries may occur, May caul
at Organ Effects
Respiratory system, Liver, K
ovated Medical Conditions
Skin disorders, Respiratory i
Kidney disorders.
ntial Environmental Effects
See Section 12 for additional
ney Over - biniv
Danger
orrosive
In and eye burns
ad lung injury and burns
fatal if swallowed
it State Liquid Odor Odorless
nation.
cause severe damage including blindness
burns. Blood disorder may occur after prolonged inhalation. Methemoglobinemia
,al information
arvous system.
--Component
CA$ -No
odium hydroxide
1310-73-2
odiumboratedecarniffmite
1303-96-4
---§Rium —nitrite
—76- M70U-6
S"odium silicate - ---- ----
ivice Do not get in eyes, on skin, or on clothing. Do not breathe vapors or spray mist
Immadately flush with plenty of water. After initial flushing, remove any contact tenses and continue flushli
least 16 minutes. Get medical attention immediately
let Remove immediately all contaminated clothing. Wash off immediately with plenty of water for at least 15 it
medical attention immediately
Move to fresh air. In case of shortness of breath, give oxygen. If not breathing, give artificial respiration. Ge
attention immediately
Drink 1 or 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately. Never give anyth'
mouth to an unconscious person
hysician The product causes burns of eyes, skin and mucous membranes. Control of circulatory system, shock the
needed
Flash Point Not combustible Method Not applicable
Autoignition Temperature No information available
Flammability Limits in Air % Hydrogen, by reaction with metals Upper 75 Lower
Suitable Extinguishing Media
Water spray. Foam. Atcohol-resistant foam. Carbon dioxide (CO2), Dry chemical, Use extinguishing measures that are appropriate to local circumstances and If
surrounding environment
Specific Hazards Arising from the Chemical
Material can create slippery conditions, Contact with metals liberates hydrogen gas
Protective Equipment and Precautions for Firefighters
Page I / 5

00L'3700 (57 LB) issuing Cute 23-Jul-200
mr self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear
Health 3 Flammability 0 Instability i
Health 3 Flammability 0 Instability 1
Personal Precautions
Use personal protective
Material can create slip)
Environmental Precautions
Do not flush into surfae
Methods for Containment
Contain spillage, soak
and transfer to a Conte
Methods for Cleaning Up
Never return spills In
Neutralizing Agent
Acetic acid, diluted
apple ventilation. Prevent further leakage or spillage if safe to do so.
,at system
Handling
Do not get in eyes, on skin, or on clothing, Do not breathe vapors or spray mist
Storage
Store in original container. Keep containers tightly closed in a Cary, coot and well -ventilated place. Metal cont
must be lined. Do not freeze
Storage Temperature
Minimum 35'Fl2'C Maximum 120°Fi49'C
Storage Conditions
Indoor X Outdoor Heated Refrigerated
L *�. c A`. ; *, -, '`.'i`• l !
Exposure Guidelines
Component
ACGIH TLV GSHA PEL
:Sodium hydra ade
mi" Cal
Ceiling:2 mgtm3 ; TWA: 2 mgfma IC7LH, iD mglmat#tng: 2
Sodium bxate dercanydrate
STEL: S mgim3 TWA: 2 mg1m3 No data available TWA: 1 mgtma TWA« 5 rrr
Sodium nitrite
No data available No data available No data availablea::.
Sodium silicate
No data available No data available No data available �.
Engineering Measures
Use with local exhaust ventilation. Ensure adequate ventilation, especially in confined areas
Personal Protective Equipment
Eye/Face Protection
Tightly fitting safety goggles. Face -shield
Skin Protection
Wear suifabie protective clothing, Impervious gloves.
Respiratory Protection
When workers are facing concentrations above the exposure limit they must use appropriate certified resp
case of inadequate ventilation wear respiratory protection
General Hygiene Considerations
Wear protective gloves/clothing. Ensure that eyewash stations and safety showers are close to the works
location
Liquid
Viscosity
Non viscous
Light yellow
Odor
Odorless
Transparent
pH
14
ly
1.26
Evaporation Rate
0.4 (Butyl acetate= )
its (Volume)
83.6
VOC Content (%1
0
;911)
0
Vapor Pressure
12.7 mmHg as 70 °F
0.6 (Air = 1.0)
Solubility
Completely soluble
Lange
212°F1100°C
Chemical Stability Stable. Hazardous polymerization does not occur
Conditions to Avoid Extremes of temperature and direct sunlight
Incompatible Products Strong oxidizing agents, Reducing agents, Amines; Cyanides; Acids, Halogenated
hydrocarbon, Tetrehydrofuran, Aldehydes, Contact with metals liberates hydrogen
gas.
Hazardous Decomposition Products Carbon oxides, Sodium oxides, Nitrogen oxides (NOx), Hydrogen gas (flammable
and potentially explosive),
Passibility of Hazardous Reactions None under normal processing
C:ahte�i,'
a
..
Product Information No information available
Component Information
Acute toxicity
Page 21

PP48TZ -.ANCOQL 3700 (575 LB) Issuing Dal
Component I LOSO Oral LOSO Dermal LCSO inhalation ar-aize Test
Sodium hydroxide ;a data available 1360 mating Rabbit no data available no data available
Sodium colors, decahydrate 2403 ing/kit Rat 2660 2060 -ingilig Rabbit no data available no data available
mglkg Rat j
---6mg)L( Rat )4 h no data available
Sodium nitrite 85 miclat (.Rat I no data available
sodium silicate 1163 meted (.:Rat 4640 mining ( Rabbit) no data available no data available
Chronic Toxicity None known
Component atlimhl Mail &Y— "fisitization --delliteo—prilentat Toxicity Reproductive Toxicity To
t i�j
Sodium hydroxide no data available no data available no data available no data available ey,
Sodium before decahydrate no data available no data available no data available no data available rem
Sodium nitrite no data available no data available no data available no data available flin
syste
Sodium silicate no data available no data available no data available no data available
Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen
Component )CCGIH IARC NTP OSHA
Sodium hydroxide not applicable not applicable not applicable not applicable
Sodium hotels dainarydrate not applicable not applicable riot applicable not applicable
sodium aimed not applicable art applicable not applicable not applicable
Sodium ruill—ca—te—­ not applicable not applicable nail—appliCable 7m —applicable
blood, htnol
l eyoly
$
her
pildatrfa
Auct Information
No information available
important Information
Component
Toxicity to Algae — Toxicity to fish
Mtarotox
Water a
Sodium hydroxide
no data available oncorliynchus mykiss: 45A
76 HT LC50
no data available
no data available
mg/L Isunic]
Sodium borate decamirdralre
96 Hr EC60 Sconedesmus 96 Hr LC50 Limanda ficiandan 340 mitti.
nic data available
48 Hr LC50 Daphnis inagniv
subspicatus: 158 mg/L
1085-1402 bad.
Sodium nitrite
no data available — 9$HrLC500neorhyfichusniykiss:0.19
no data available
no data available
rated- illow-throughl (Juvenile); 96 Hr LC50'
Oncorhynchus mykiss:0,092.0,13 mg/L
[flow-throuidd; 96 Hr LC50 Oncorhynchus
inylinscOA-0.6 rmpL plent-staficl; 96 Hr
LC50 Oncorhynchus mykiss:0,65.1 m9d.
[static]; 96 Hr LCSO Pirnerrhalas
promelas:2,3 mg/L tflovv-throuqhl, 96 Hr
LCSO Pimephides promoms:20 mail, lahslell
I
Sodium silicate
no data available 96 Hr LC50 Lepomis macroohrrus� 301-478
no data available
96 Hr ECSO Daphnis magna:
mg/L; 96 Hr LC50 Braphydanki, rorio:3185
216 nuid.
moil. [semi -static]
rildstance and Degractabillity,
No information available
)accumulation
No information available
�blllty
No information available
Product Disposal Dispose of in accordance with local regulations
Container Disposal Empty containers should be taken for local recycling, recovery or waste disposal
DOT
Proper Shipping Name Sodium hydroxide solution
Hazard Class 8
UN -No UN1824
Packing Group it
Description UN1824, Sodium hydroxide solution, 8, PG It
TDG
Proper shipping name Sodium hydroxide solution
Hazard Class 8
UN -No UN1824
Packing Group It
Description Sodium Hydroxide SoIutiorl,8,UN1824,PG 11
ICAO
UN -No UN1824
Proper Shipping Name Sodium hydroxide solution
Page 3 / 5

T - 4 C O� 3700 (575 LB)
Issuing Date28-Jul-2009
Hazard Mass
8
Packing Group
ll
Shipping Description
UN1824, Sodium hydroxide solution,8,PG If
IAT
Uhl -No
UN1824
Proper Shipping Name
Sodium Hydroxide solution
Hazard Mass
8
Packing Group
it
ERG Code
8L
Shipping Description
UN1824,odium hydroxide solution,8,PG It
IMDGAMt}
Proper shipping Name
Sodium hydroxide solution
Hazard Class
8
UN -No
UN1824
Packing Group
11
Ems No
8-A, SWS
Shipping Description
UN1824, Sodium hydroxide solution,8,PG 11
LA 1Si. .., sue:, .. $Ut icy '• U ? ��'�` tA'3�, ty ., `;;as 't MATtA?t
Inventories
TSCA
Complies
DSL
Complies
U.S. Federal Regulations
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA), This product contains a chemical or chemicals which are subject to the
reporting requirements of the Act and Title 40n of the Code of Federal Regulations, Park 372
Component
I CAS -No
I Weight 6 PAkA 31 -T reshot a ues
Sodium nitrite
7632-00«
15-40 i.fl
SARA 3111312 Hazardous Categorization
Acute Health azard' Chronic Health Hazard Fire Hazard
Sudden Release of Pressure Reactive Hazard
Hazard
Yes
Yes No
No No
CERCtA
Component
Hazardous Substances R s CeRCLA 6Hs Rqs
Sodium hydroxide
1000 lb
Not applicable
Sodium borate decahydrate
Not applicable
Not applicable
aidium nitrite
100 fb
Not applicable
Sodium silicate
Not applicable
Not applicable
U.S. State Regulations
California Proposition 655
This product contains the following Proposition 65 chemicals
Component
CAS -No
California Prop. 65
Mercury
7439-97-6
developmental toxicity, 4lat date 711l90
Nickel
794q-02.0
carcinogen, initial state 517,04 carcinogen, Initial date
1011/89
Lead
7439-92-1
carcinogen, initial date 1011192 developmental toxicity,.
initial date 2127187 male reproductive toxicity, initial data
2/27/87 female reproductive toxicity, initial date 2127187
'. Arsenic
7440-38.2
carcinogen, initial date 2127187
::Cadmium and compounds {as cot
7440.43.9
carcinogen, initial date 1011187 developmental toxicity,
initial date 5tV97;male reproductive toxicity, initial date
5f1197
Canada
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the M DS contains all the
Information required by the CPR
WHMIS Hazard Class
E Corrosive material, D1B Toxic materials, D28 Toxic materials.
101- AL
ITI
�t
,_ to
g'g '.3a .:, ,.. ,. ..,;...� ON
.. Sa.,o.`•a"'.. ., , ,..,.:, , e».. . x .tip•.
Prepared By
Mike McDowell
Supercades Date
10/30/2006
Issuing Date
07128/2009
Reason for Revision
No Information available
Glossary
No information available
Page 41

i\NC OL 3700 (575 LB) Issuing Date 2 -Elul-2009
ferences. No information available
UA, INCassumes no responsibility for personal injury or property damage caused by the use, storage, or disposal of the product In a
of recommended on the product label. Users assume all risks associated with such unrecommended use, storage or disposal of the
material used in combination with any other material or In any process, unless specified In the text
Page 515