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NC0004979_Report_20201221
44 DUKE PaulDraovitch ENERGY® Environm Senior Vice Presides, Environmental,Health&Safety; Operations Support and CCP 526 S.Church Street Mail Code:SCUP Charlotte,NC 28202 (980)373-0408 December 21, 2020 Via Overnight Mail S. Daniel Smith Director of Water Resources Ft aE 1�® North Carolina Department of Environmental Quality 1617 Mail Service Center IN 04 242 2� Raleigh,NC 27699-1617 0 4 t�C pEQlp�n Rick Bolich Csntca�Office Section Chief, Groundwater Resources Section North Carolina Department of Environmental Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Report Under Special Order by Consent—EMC SOC WQ S 17-009 Duke Energy Progress,LLC—Allen Steam Station NPDES Permit NC0004979 Seep Management Amendment to Corrective Action Plan Dear Messrs. Smith and Sledge: On behalf of Duke Energy Carolinas, LLC (DEC), I am submitting to you the Seep Management Amendment to Corrective Action Plan as required by the Allen Steam Station NPDES Permit NC0004979 Special Order by Consent(SOC), SOC No. S 17-009, Section 2.d. This report follows the Seep Characterization Report submitted on October 27, 2020 and addresses management of non-dispositioned seeps at the Allen Plant. Please direct any questions about this submittal to Courtney Murphy at(704) 382-7171 or Chris Hallman at(980) 373-7892. I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, Messrs. Smith and Bolich December 21, 2020 Page 2 and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. ly, Paul Draovitch Senior Vice President Environment, Health& Safety; Operations Support and CCP Duke Energy Attachment: Allen Steam Station Seep Management Amendment to Corrective Action Plan cc: Jim Wells, Duke Energy Ed Sullivan, Duke Energy Matt Hanchey,Duke Energy Richard Baker, Duke Energy Shannon Langley,Duke Energy Elizabeth Glenn, Duke Energy Courtney Murphy, Duke Energy Chris Hallman, Duke Energy Randy Gantt, Duke Energy Tyler Hardin, Duke Energy Bob Sledge,NCDEQ 4 410 .;ynTerra SEEP MANAGEMENT PLAN AMENDMENT TO CORRECTIVE ACTION PLAN ALLEN STEAM STATION 253 PLANT ALLEN ROAD BELMONT, NC 28012 DECEMBER 21, 2020 PREPARED FOR —A%� k DUKE ENERGY CAROLINAs, LLC ChrX- Suttell, NC LG #2426 Project Principal Lee Drago Staff Scientist Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra EXECUTIVE SUMMARY SynTerra prepared this Seep Management Plan Amendment to the Corrective Action Plan (Plan) pertaining to the Allen Steam Station (Allen or Site) to describe plans for the management of identified seeps in a manner that protects public health, safety, and welfare;the environment; and natural resources. This Plan was prepared on behalf of Duke Energy Carolinas, LLC (Duke Energy). Special Order by Consent(SOC)WQ S17-009 was approved on April 18, 2018, and subsequently amended on May 10, 2019. The SOC addresses the management of seeps during the process of ash basin closure under the Coal Ash Management Act(CAMA) of 2014, North Carolina General Statutes (G.S.) 130A-309.200 through 130A-309.231 and the federal Coal Combustion Residuals (CCR) rule, 40 CFR Parts 257 and 261. Section 2(b)(3) of the SOC states: Within 60 days of the submittal of the Seep Characterization Report, Duke Energy shall submit a complete and adequate proposed amendment to the groundwater Corrective Action Plan and/or Closure Plan as appropriate for the Facility describing how any seeps identified in the Seep Characterization Report will be managed in a manner that will be sufficient to protect public health, safety, and welfare, the environment, and natural resources. Findings in the October 2020 Seep Characterization Report (SynTerra, 2020c) indicate identified seeps are either: (1)previously dispositioned as determined by the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Resources (DWR) at the time of issuance of the SOC; (2) candidates for dispositioning per the SOC; (3) covered under the National Pollutant Discharge Elimination System (NPDES) Permit NC0004979 pertaining to the Site; or (4)not exhibiting constituent concentrations that warrant additional corrective action at this time. Duke Energy continues to implement ash basin closure activities to reduce groundwater seepage in a manner that is protective of public health, safety, and welfare;the environment; and natural resources. Completed and ongoing closure activities are summarized below. Date Closure Activity June 2019 Commencement of decanting of the Active Ash Basin. June 2020 Completion of decanting of the Active Ash Basin. June 2020 - Present Commencement of maintenance dewatering of the Active Ash Basin. Maintenance dewatering is ongoing, along with groundwater corrective action and landfill permitting activities. Page ES-1 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra Evaluation of boron concentrations at non-dispositioned seep locations using the Mann- Kendall trend test demonstrates stable to decreasing trends prior to, and since, implementation of ash basin closure. In addition to boron, trend tests were performed on applicable constituents with North Carolina Administrative Code (NCAC), Title 15A, Subchapter 02B-Surface Water and Wetland Standards (02B). Overall, the results of the Mann-Kendall trend analysis indicate that the seep discharges have been geochemically stable prior to, and since, implementation of ash basin closure with constituent concentrations remaining stable or decreasing over time. Only one location (S-2) exhibited increasing trends in constituent concentrations. However, S-2 has been characterized by dry conditions, preventing sample collection at this seep location since August 2019. Non-dispositioned seeps are scheduled to be monitored as required by the SOC until termination of the SOC by DWR, or not later than June 30, 2022. Upon termination of the SOC, continued effectiveness monitoring of the two non-dispositioned seep locations expected to remain (S-10 and S-12) is recommended until either: (1) closure of the associated ash basin is complete or (2) sample data from two consecutive sampling events indicate seep discharges do not contain constituents associated with ash basins or concentrations are less than 02B standards. The contribution of flows from former constructed seeps S-3, S-4, S-8, and S-8B-now NPDES outfalls-would continue to be monitored as required by the NPDES permit. Seeps would be monitored on a semiannual basis consistent with the nearby groundwater monitoring network to correlate changing water quality and geochemical conditions. Page ES-2 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra TABLE OF CONTENTS SECTION PAGE EXECUTIVESUMMARY....................................................................................................ES-1 1.0 INTRODUCTION.........................................................................................................1-1 1.1 Background................................................................................................................1-1 1.2 Purpose and Scope....................................................................................................1-1 1.3 Previous Reporting...................................................................................................1-2 2.0 OVERVIEW OF SEEPS PROPOSED FOR MANAGEMENT..............................2-1 3.0 PROPOSED SEEP MONITORING PLAN...............................................................3-1 3.1 Seeps Associated with the Active Ash Basin........................................................3-1 3.2 Nature and Extent of Source Related Constituents and Seeps...........................3-1 3.3 Ash Basin Closure Activities...................................................................................3-2 3.4 Mann-Kendall Trend Analysis................................................................................3-2 3.5 Seep Characterization Conclusions........................................................................3-3 3.6 Potential Seep Monitoring.......................................................................................3-4 4.0 REFERENCES................................................................................................................4-1 Page i Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra LIST OF FIGURES Figure 1-1 Site Location Map Figure 1-2 Existing Seep Locations and Inspection Areas Figure 3-1 Proposed Seep Dispositional Status, Locations, and Inspection Areas LIST OF TABLES Table 3-1 Seep Characterization Analytical Results—June 2020 LIST OF APPENDICES Appendix A SOC WQ S17-009 Appendix B Mann-Kendall Analysis, October 2020 Page ii Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra LIST OF ACRONYMS 02B North Carolina Administrative Code, Title 15A,Subchapter 02B, Surface Water and Wetland Standards 02L North Carolina Administrative Code, Title 15A, Subchapter 02L, Groundwater Standards µg/L micrograms per liter BTV background threshold values OCRs coal combustion residuals COI constituent of interest CSA comprehensive site assessment CAP corrective action plan DWR Division of Water Resources EMC Environmental Management Commission USEPA U.S. Environmental Protection Agency FGD flue gas desulfurization IMAC interim maximum allowable concentration mg/L milligrams per liter NCAC North Carolina Administrative Code NCDEQ North Carolina Department of Environmental Quality NC L.G. North Carolina Licensed Geologist NPDES National Pollutant Discharge Elimination System SOC Special Order by Consent SOP standard operating procedure USACE United States Army Corp of Engineers UT Unnamed Tributary WOS Waters of the State WOTUS Waters of the United States Page iii Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 1.0 INTRODUCTION SynTerra prepared this Seep Management Plan Amendment to the Corrective Action Plan (Plan) pertaining to the Allen Steam Station(Allen or Site) (Figure 1-1) to describe plans to manage identified seeps in a manner that protects public health, safety, and welfare;the environment; and natural resources. This Plan was prepared on behalf of Duke Energy Carolinas, LLC (Duke Energy). 1.1 Background Special Order by Consent (SOC) WQ 517-009 was approved on April 18, 2018, and subsequently amended on May 10, 2019. The SOC addresses management of seeps related to ash basins during the process of ash basin closure under the Coal Ash Management Act of 2014 (CAMA),North Carolina General Statutes (G.S.) 130A-309.200 through 130A-309.231, and the federal Coal Combustion Residuals (CCR) rule, 40 CFR Parts 257 and 261. The SOC is provided in Appendix A. In preparation for closure of the active ash basin (AAB),wastewater inflows to the AAB ceased on February 9, 2019. Decanting of free water from the AAB began on June 5, 2019. Duke Energy provided a Notification for Completion of Decanting letter to the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Resources (DWR) on July 9, 2020. The notification indicated that decanting of the AAB was completed on June 2, 2020. 1.2 Purpose and Scope As required in Section 2.d. of the SOC, SynTerra is providing this Plan as an amendment to the CAP Update to describe plans to manage seeps identified in the Seep Characterization Report (SynTerra, 2020c). The Seep Characterization Report evaluated seeps based on physical status, chemical composition, and jurisdictional determination. To be considered in this Plan, a seep must: 1) Be non-dispositioned. 2) Constitute, or flow, to Waters of the State (WOS) or Waters of the United States (WOTUS). 3) Exhibit constituent concentrations that are greater than applicable North Carolina Administrative Code (NCAC), Title 15A, Subchapter 02B, Surface Water and Wetland Standards (02B). Page 1-1 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 1.3 Previous Reporting Detailed descriptions of previous SOC assessments and characterizations are documented in the following: • Comprehensive Site Assessment Report—Allen Steam Station Ash Basin (HDR, 2015a). • Corrective Action Plan Part 1 —Allen Steam Station Ash Basin (HDR, 2015b). 0 Corrective Action Plan Part 2 —(including Comprehensive Site Assessment Addendum)—Allen Steam Station Ash Basin (HDR, 2016a). • Comprehensive Site Assessment Supplement 2 —Allen Steam Station Ash Basin (HDR, 2016b). • CAMA Annual Interim Monitoring Report,Allen Steam Station (SynTerra, 2019a). • Surface Water Evaluation to Assess 15A NCAC 02B .0200 Compliance for Implementation of Corrective Action Under 15A NCAC 02L .0106(k) and(l)—Allen Steam Station (SynTerra, 2020a). • 2019 Annual Seep Report,Allen Steam Station (SynTerra, 2020b). • 2020 Final Seep Report,Allen Steam Station (SynTerra, 2020c). • Seep Characterization Report,Allen Steam Station (SynTerra, 2020d). Page 1-2 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 2.0 OVERVIEW OF SEEPS PROPOSED FOR MANAGEMENT According to the SOC, there are eight identified non-constructed seeps at the Site (Appendix A). Of those eight seeps, two seeps (S-1 and S-9)were dispositioned at the time of issuance of the SOC. Four former constructed seeps -S-3 (Outfall 103), S-4 (Outfall 104), S-8 (Outfall 108), and S-8B (Outfall 108B) -are monitored per requirements of the NPDES permit. Six non-constructed seeps (S-2, S-5, S-6, S-7, S-10, and S-12) remain as non-dispositioned. The non-dispositioned seeps identified in the SOC are described below and depicted on Figure 2-1. Seep ID Associated Description Number Ash Basin S-2 AAB Located southeast of AAB at toe of dam. Flows to approximately 3-foot-wide channel that flows to Lake Wylie. S-5 AAB Located east of AAB, between dam and river bank. Intermittent, unconfined diffuse flow toward Lake Wylie. S-6 AAB Located east of AAB, between dam and river bank. Intermittent, unconfined diffuse flow toward Lake Wylie. S-7 AAB Located east of AAB, between dam and river bank. Intermittent, unconfined diffuse flow toward Lake Wylie. Seep located near northwest corner of Primary Pond 1. Seep S-10 AAB flow collected in a French drain system and conveyed to a tank from which seepage is pumped back into the AAB. Overflow discharge of seepage collected from S-10 occurring during temporary, infrequent power outage episodes. S-12 AAB Seepage would flow to a stormwater drainage channel. Seep flow is collected and pumped back into the AAB during normal operations. As described in the Seep Characterization Report(SynTerra, 2020c), seeps S-2, S-5, S-6, and S-7 are candidates for dispositioning because they have been observed as dry or not reaching WOS or WOTUS for three consecutive quarters. Page 2-1 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 3.0 PROPOSED SEEP MONITORING PLAN 3.1 Seeps Associated with the Active Ash Basin With concurrence from the NCDEQ DWR on seep jurisdictional and dispositional status and upon termination of the SOC, all seeps, except S-10 and S-12 would be dispositioned (Figure 3-1). Former seeps S-3 (Outfall 103), S-4 (Outfall 104), S-8 (Outfall 108), and S-8B (Outfall 108B) would be monitored via the NPDES permit. Duke Energy continues to implement ash basin closure activities to reduce groundwater seepage in a manner that is protective of public health, safety, and welfare;the environment; and natural resources. Ash basin closure activities implemented by Duke Energy to date are detailed in Section 3.3. The nature and extent of identified seeps and the effects of ongoing ash basin closure activities are discussed in the following sections. 3.2 Nature and Extent of Source Related Constituents and Seeps Based on groundwater data collected through June 2020, constituents of interest (COIs) associated with the ash basins in groundwater or surface water include: • Boron • Strontium • Cobalt • Sulfate • Iron • Total Dissolved Solids (TDS) • Manganese Of those COIs, only sulfate and TDS are SOC Attachment B surface water constituents with 02B standards. Boron concentrations greater than NCAC, Title 15A, Subchapter 02L—Groundwater Classifications and Standards (02L) generally represent the extent of affected groundwater associated with the AAB. Because boron is non-reactive and mobile in groundwater, it serves as a conservative indicator of the extent of constituent migration -from the ash basins and representative of the overall plume that contains other COIs with concentrations greater than comparison criteria [021, standard/Interim Maximum Allowable Concentration (IMAC) or background concentrations,whichever is greater]. The boron concentration in recent seep characterization data collected from non- dispositioned seep S-10 is less than the 02L standard (Table 3-1). Evaluation of boron concentrations at non-dispositioned seep locations using the Mann-Kendall trend test demonstrates stable to decreasing trends prior to, and since, implementation of ash basin closure activities (Appendix B). Page 3-1 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 3.3 Ash Basin Closure Activities Duke Energy began implementation of ash basin closure activities, which contributes to seep management and surface water protection, for the AAB in 2019. Completed and ongoing ash basin closure activities are summarized in the table below. Year Closure Activity June 2019 Commencement of decanting of the active ash basin. June 2020 Completion of decanting of the active ash basin. June 2020 - present Commencement of maintenance dewatering of the active ash basin. Maintenance dewatering is ongoing, along with groundwater corrective action and landfill permitting activities. 3.4 Mann-Kendall Trend Analysis Ash basin closure is in the early stages. Ash basin decanting was completed in June 2020, and ash basin dewatering is underway. Completion of ash basin dewatering, and subsequent excavation of the AAB and retired ash basin (RAB), are anticipated to further reduce seep flows and constituent concentrations. Mann-Kendall trend tests (Appendix B) were performed on 23 constituent-location pairs to analyze how constituent concentrations at non-dispositioned seep locations have changed over time. The Mann-Kendall trend test evaluates data over time for each non-dispositioned seep to develop a statistical conclusion that pertains to trends— increasing, decreasing, or no trend—of a constituent concentration. In addition to boron, Mann-Kendall trend tests were performed on applicable constituents with 02B standards at non-constructed,non-dispositioned seeps. Overall, the results of the Mann-Kendall trend analysis indicate that seep discharges have been geochemically stable prior to, and since, implementation of ash basin closure with constituent concentrations remaining stable or decreasing over time. Based on the June 2020 seep characterization sampling event, constituent concentrations were not greater than 02B standards at non-constructed, non-dispositioned seeps (Table 3-1). Results from the Mann-Kendall trend tests indicate the following: The average percentage of non-detects for constituent-location pairs included in the Mann-Kendall trend test is 22 percent. The large number of non-detect measurements present in the dataset indicates that many constituent-location pairs have concentrations less than the reporting limit and are not predicted to be of concern. Page 3-2 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra • 82.6 percent of constituent locations (19 constituent-location pairs out of 23 constituent-location pairs) demonstrated stable conditions with no trends. • 8.7 percent of the constituent locations (2 constituent-location pairs out of 23 constituent-location pairs) demonstrated statistically significant decreasing trends. • 8.7 percent of the constituent locations (2 constituent-location pairs out of 23 constituent-location pairs) demonstrated statistically significant increasing trends. Although increasing trends for mercury and sulfate were identified at S-2, dry conditions, likely due to decanting,have prevented sample collection at this seep location since August 2019. Overall, the results of the Mann-Kendall trend tests indicate that the constituent concentrations in seeps have been geochemically stable or decreasing prior to, and since,implementation of ash basin closure. 3.5 Seep Characterization Conclusions To be considered in this management plan, a seep must: 1) Be non-dispositioned, 2) Constitute, or flow to WOS or WOTUS, and 3) Exhibit constituent concentrations that are greater than applicable 02B surface water standards. Based on findings from the Seep Characterization Report(SynTerra, 2020c),no seeps meet the above criteria: • Seeps S-2, S-5, S-6, and S-7 are candidates for dispositioning because they have been observed as dry or not reaching WOS or WOTUS for three consecutive quarters. • Flow from seeps S-10 and S-12 would flow to WOS or WOTUS only if the S-10 seep collection system was not operating (an upset condition of the system). • Former seeps and current NPDES outfalls-S-3 (Outfall 103), S-4 (Outfall 104), S-8 (Outfall 108), and S-8B (Outfall 108B) - are monitored under the NPDES wastewater permit. Page 3-3 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 3.6 Potential Seep Monitoring Non-dispositioned seeps are scheduled to be monitored as required by the SOC until termination of the SOC by DWR, or not later than June 30, 2022. Upon termination of the SOC, continued effectiveness monitoring of the two non-dispositioned seep locations expected to remain (5-10 and S-12) is recommended until either: (1) closure of the associated ash basin is complete or (2) sample data from two consecutive sampling events indicate seep discharges do not contain constituents associated with ash basins or concentrations are less than 02B standards. The contribution of flows from former constructed seeps S-3, S-4, S-8, and S-8B-now NPDES outfalls-would continue to be monitored as required by the NPDES permit. Until that time, the seeps would be monitored on a semiannual basis consistent with the nearby groundwater monitoring network to correlate changing water quality and geochemical conditions. Page 3-4 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 4.0 REFERENCES HDR (2015a). Comprehensive Site Assessment Report, Allen Steam Station Ash Basin. HDR (2015b). Corrective Action Plan Part 1, Allen Steam Station Ash Basin. HDR (2016a). Corrective Action Plan Part 2, Allen Steam Station Ash Basin. HDR (2016b). Comprehensive Site Assessment Supplement 2, Allen Steam Station Ash Basin. SynTerra (2019a). CAMA Annual Interim Monitoring Report, Allen Steam Station. SynTerra (2020a). Surface Water Evaluation to Assess 15A NCAC 02B .0200 Compliance for Implementation of Corrective Action Under 15A NCAC 02L .0106 (k) and (1), Allen Steam Station. SynTerra(2020b). 2019 Annual Seep Report,Allen Steam Station. SynTerra(2020c). 2020 Final Seep Report,Allen Steam Station. SynTerra(2020d). Seep Characterization Report, Allen Steam Station. Page 4-1 Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra FIGURES I DUKE ENERGY CAROLINAS PROPERTY LINE_I a fA4 A�.t 1l••/ ��. _,f_—ALLEN STEAM STATION r 4 ,J 1 RETIRED ASH BASINAl ' 9�, �. k�L RETIRED ASH BASIN i w WASTE BOUNDARY �— RnQ l'. ••L� ACTIVE ASH BASIN If ; ACTIVE ASH BASIN, WASTE BOUNDARY T ti t tv qr lve t.>IRr As_ Lqr'4k NOTES: 1.ALL BOUNDARIES ARE APPROXIMATE. 2.WATER FEATURES DEPICTED WITHIN WASTE BOUNDARIES OFTHEASH ' BASINS ON THE 2019 USGS TOPOGRAPHIC MAP DO NOT REPRESENT ` _ CURRENT CONDITIONS.THE CONDITIONS DEPICTED ARE SIMILAR TO THOSE SHOWN ON THE 1968AND 1973 USGS TOPOGRAPHIC MAPS OFZii THEAREA[(1968 WEST CHARLOTTE(1:24000)AND 1973 BELMONT(1:24000)].. 3.2019 USGS TOPOGRAPHIC MAP,BELMONT&CHARLOTTE WEST QUADRANGLE,OBTAINED FROM THE USGS STORE AT HTTPS:/INGMDB.USGS.GOV/. FIGURE 1-1 �+ DUKE SITE LOCATION MAP ENERGY. VNNSTON-SALEM SEEP MANAGEMENT PLAN AMENDMENT TO CORRECTIVE ACTION PLAN ASHEVUE • ALLEN STEAM STATION CHARLOTTE• GASTON COUNTY,NORTH CAROLINA GASTON DRAWN BY:R.KIEKHAEFER DATE:09/28/2020 GRAPHIC SCALE COUNTY REVISED BY:R.KIEKHAEFER DATE:11/05/2020 l000 0 1.0^^ 2000. WnTena w CHECKED BY:L.L. DRAO DATE:11/5/2020 APPROVED BY.L.DRAGO DATE:11/05/2020 ww. nterracor .com PROJECT MANAGER:C.SUITELL ON FEE I E �. +� �• -ten.—_ - 4 -�� _ IN it 1 41�"till ti •�`Ji 1 � 1 �••q rr rw�lone!._ fir.R,T.••�s�s� ' r=�DTnDs s r, LEGEND 1 .• r�'F+Iu Lor L:�•_,. NPDES TOE DRAIN OUTFACE C NON-CONSTRUCTED SEEP J • DISPOSITIONED SEEP ',1.'r'�'• _�.•` . :ACTIVE ASH BASIN WASTE BOUNDARY RETIREDASH BASIN WASTE BOUNDARY 1p '• - DUKE ENERGY CAROLINAS PROPERTY LINE ^ SPECIAL ORDER BY CONSENT(SOC) INSPECTION AREA �--STREAM(AMEC NRTR 2015) WETLAND(AMEC NRTR 2015) —11 SURFACE WATER FLOW DIRECTION r `� 1DT LOCH IONSARE'E RIBEDINEMCSOCv sLTnDE - •• + - --- - 7 Rw Cai7TEM INPOEsj LOCATIONSARE DESCRIBED PERMIT N 9&SrOILOCATINswEREDERIVED FROMVATI111 THEREFORE ARL A, SUR—EDINPAPPR-IM Y LOCATIONS —R—MATE s.TNEREFDREs ! / iI.S IF THEAUP v¢D ar CREATION, FUNNQ3ES THE—NDS AID STREAMS BOUNDARIES WERE OBTAINED FROM STREAM AND WETLAND _RONMENT'_wmnsrBRucruwEQiRc Hn uauEAEsouRCE TECHNICAL REPORT INRTRI FOR ALLEN STEM STATION DATED MAV]9, �+S DUKE aaD n a5D Raa FIGURE 2-1 is ENERGY- iaAvn>C9GLEni[£I EXISTING SEEP LOCATIONS AND INSPECTION AREAS PROPERTY BOUNDARY PRDN�DED BY DICE ENERG.LARLNNAB. c�atr,N,s SEEP MANAGEMENT PLAN AMENDMENT TO ALL BOUNDARIES ARE APNNIXONATE. DRAwNBr:N.gNG D oA/LD/_ CORRECTIVE ACTION PLAN �� REVEEO BN R.gEgIPEFER D1TE:11/Oi/20M ClEM9ER' a"�RA A COLLLE.T.ONMAF NanPmfe" CHECItfD Bn.TNARDAAN WTE:LUCT— ALLEN STEAM STATION APPRDv MANADDR C. DATE:WO m. GASTON COUNTY,NORTH CAROLINA STATE PLANE COORDINATE SYSTEM FIP6E320DINADB3)RT LMOMNA T PRWECf MANAGER:C.GUTIELL ntRIEBDD 1 I x I � I ! N!•uc r - r 4P``. R i Eo II � •` p—I t )i Y'-dl LEGEND - NPDES TOE DRAIN OUTFACE ® NON-CONSTRUCTED SEEP DISPOSITIONED SEEP ACTIVE ASH BASIN WASTE BOUNDARY •—RETIRED ASH BASIN WASTE BOUNDARY • DUKE ENERGY CAROLINAS PROPERTY LINE 1 - SPECIAL ORDER BY CONSENT(SOC) 1 J INSPECTIONAREA STREAM(AMEC NRTR 2015) rJ --•^•• •• WETLAND(AMEC NRTR 2015) T r SURFACE WATER FLOW DIRECTION i.SE-LOCATIONS ARE DESCRIBED IN EMI SDCwO sn Goe. INATI EM(NPDESI WEREVE RIVED FROM VARIOUS SOURCES AND ARE ND AROMMATE LOCATIONS.THEREFORE,SEEP CATIONSARETDBEDE EDA-RO%IMATE D.1 CREAH—THIS MAP IS ITE USED FOR ILR. SOUNDARIMI-EREOMI RM FROM WET REAM AND—LAND LINEATION CONDUCTED B VAMEC FOSTER WREELER R FOE NCIIAL RESOURCE (. Aco BDD AL REPORT RN SAC AY20. DUE FIGURE 3-1 s EMIM PROPOSED SEEP DISPOSITIONAL STATUS, PROPERTY BOUNDARY PRDIIDEDBy DIKE ENERGY CARCUHAS, c.*MINAS LOCATIONS,AND INSPECTION AREAS ILL BOUNDARIES ARE APPROAIMATE. D Y:KRING ureoA/w/2D>e SEEP MANAGEMENT PLAN AMENDMENT TO T.AERIAL PHOTCORAPHY OBTAINED FROM"'ILE EARTH PROCH CHECKS.-ARHAEFER MTE 1]/OT/2020 DEceMBER(T.zO.s.AERaLwascoLLEITEDDNMARIH3D.zo(A. cxecAEDBv:T.HAxTMAN :wBT/zozD CORRECTIVE ACTION PLAN IroCTAMN IEI 10 DME:ivovzo2O ALLEN STEAM STATION CAROLINA PROTECT MANAGER:CSIITTELL ePUNEcooRDlNAms s i F°si uo°iN1oBii" GASTON COUNTY,NORTH CAROLINA www.s,nterracon!.com Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra TABLES � ■ ! § ! _ _ ; ! k � ; ■ | § ! _ ® ! ; ■ | ! ! _ , { 2caIc 2§ � — §� § � §ix z2 is / In AZ 2■2E2 � ` �! ` { §k§§ § ., ��4� � ■ � ! � ! ; , \ �Z - §| - .� ■ § ! ; ; ! ! / !� } � ] �/ • � — �■| • . . . # ! : } _ �! |� !! |§v0 E E}j�§j\{ § # . ! ■ | 7 � _ § § � ■ � \ ) B k ■ . § ; , . , . � � k ■ !$! ; � �§ - q� § § ; ■ � � ! , §O§§ § _§§§/ § ; E , &E■|] \ ` § k�B§ƒ § ` § ' §k �§ _ k|�422` - - . \ . ` E IL w� | - e,z | 7{ \ `]!!f ! ! ` |§�t;E{}}\{ §)\! Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra APPENDIX A SOC WQi S 17-009 ;•: ROY COOPER Govemor MICHAEL S.REGAN Secretary Water Resources LINDA CULPEPPER Environmental Quality Interim Director April 25,2018 Mr.Paul Draoviteh, Senior Vice President EHS Duke Energy 526 S. Church Street Mail Code EC3XP Charlotte,NC 28202 Subject: SPECIAL ORDER BY CONSENT SOC No.S17-009 Duke Energy Carolinas, LLC Allen Steam Station,Marshall Steam Station&Rogers Energy Complex NPDES Permits NC0004979,NC0004987&NC0005088 Gaston, Catawba&Rutherford Counties Dear Mr.Draovitch: Attached for your records is a copy of the Special Order by Consent(SOC) approved by the Environmental Management Commission on April 12, 2018, and signed by the Chairman of the Commission on April 18,2018. The terms and conditions of the SOC are in Ul effect, including those requiring submittal of written notice of compliance or non-compliance with any schedule date. The following items are brought to your attention as they pertain to the terms and conditions of the SOC: * Payment of the upfront penalty is due no later than May 25, 2018. & Monitoring performed per the terms of the SOC shall commence during the current calendar quarter(April—June),with results submitted to the Division of Water Resources(DWR)no later than July 30,2018. Subsequent monitoring and reporting shall occur as specified in the SOC. DWR acknowledges receipt of Duke Energy's letter dated April 23, 2018,confirming the implementation of dry fly ash handling at the Rogers Energy Complex. With regard to concerns for the safety of personnel collecting samples,the following locations are deemed to be acceptable for the purposes of water quality monitoring required by the SOC near the Rogers Energy Complex: ■ Upstream in the Broad River—at the U.S.Highway 221A bridge. ■ Downstream in the Broad River—at a point along the bank approximately 1,800 feet downstream from seep S-07. A■ Upstream in Suck Creek—at the S.R. 1002 (McCraw Road)bridge. State of North Carolina I Environmental Quality I water Resources 1617 Mail Service Center I Raleigh,North Carolina 27699-1617 (919)-807-6300 (919)-807-6389 FAX Mr. Paul Draovitch SOC WQ S 17-009 Transmittal p.2 Pursuant to North Carolina General Statute 143-215.31), water quality fees have been revised to include an annual fee for activities covered under a Special Order by Consent. Duke Energy will be subject to a fee of$500.00 on a yearly basis while under the Order. The initial fee payment will be invoiced at a later date, with future fee invoicing done on an annual basis. If you have any questions concerning this matter,please contact Bob Sledge at(919) 807-6398. Sincerely, Linda Culpepper Attachment {I� cc: Central Files NPDES Unit—SOC File ec: Asheville Regional Office—DWR/Water Quality Mooresville Regional Office—DWR/Water Quality Shannon Langley—Duke Energy Laurie Jones—EPA Region 4 Jeff Poupart—DWR/WQPS NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION COUNTIES OF GASTON, CATAWBA, AND RUTHERFORD IN THE MATTER OF ) NORTH CAROLINA ) SPECIAL ORDER BY CONSENT NPDES PERMITS NC0004979,NC0004987 ) EMC SOC WQ S17-009 &NC0005088 ) HELD BY ) DUKE ENERGY CAROLINAS, LLC ) Pursuant to the provisions of North Carolina General Statutes(G.S.) 143-215.2, this Special Order by Consent is entered into by Duke Energy Carolinas, LLC, hereinafter referred to as Duke Energy, and the North Carolina Environmental Management Commission, an agency of the State of North Carolina created by G.S. 14313-282, and hereinafter referred to as the Commission. Duke Energy and the Commission are referred to hereafter collectively as the "Parties." 1. Stipulations: Duke Energy and the Commission hereby stipulate the following: a. This Special Order by Consent("Special Order")addresses issues related to the elimination of seeps(as defined in subparagraphs e, f,and g below)from Duke Energy's coal ash basins during the separate and independent process of basin closure under the Coal Ash Management Act, G.S. 130A-309.200 through 130A- 309.231 ("CAMA")and the Federal Coal Combustion Residuals Rule,40 CFR Parts 257 and 261. The Environmental Protection Agency first directed permitting authorities to consider potential impacts on surface water of seeps from earthen impoundments in 2010. At that time,Duke Energy began discussions with the North Carolina Department of Environmental Quality("the Department") regarding seeps at multiple Duke Energy facilities,including identifying certain seeps in permit applications and providing data to the Department regarding seeps. In 2014,Duke Energy provided a comprehensive evaluation of all areas of wetness and formally applied for NPDES permit coverage of all seeps. Since 2014,Duke Energy has performed periodic inspections and promptly notified the Department of new seeps and sought NPDES permit coverage where appropriate. On March 4,2016, the Department issued Notices of Violation("NOVs") to Duke Energy related to seeps. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p.2 Decanting (i.e.,removal of the free water on the surface of the coal ash basins), which is required before ash basins can be closed,is expected to substantially reduce or eliminate the seeps. In order to accomplish this goal of substantially reducing or eliminating seeps,this Special Order affords certain relief to Duke Energy related to the non-constructed seeps (as defined in subparagraphs f and g below), while requiring Duke Energy to accelerate the schedule for decanting as specified more fully below. Constructed seeps (as defined in subparagraphs a and f below) will be addressed in the NPDES permits. After completion of decanting, for any remaining seeps, whether constructed or non-constructed,Duke Energy must take appropriate corrective action as specified more fully below. b. Duke Energy has been issued North Carolina NPDES permits for operation of an existing wastewater treatment works at each of the following coal fired, electric generation facilities ("Duke Energy FaciIities," or in the singular, "Facility"): Permit Issuance Receiving Water Facility Number County for Primary Date Outfall J Allen NCO004979 Gaston 1/18/2011 Catawba River Marshall NC0004987 Catawba 9/9/2016 Catawba River Rogers NC0005088 Rutherford 2/20/2012 Broad River C. The Duke Energy Facilities listed above will continue to operate and generate coal ash, and each is subject to the provisions of this Special Order. d. Wastewater treated at coal-fired electric stations includes water mixed with ash produced through the combustion of coal for the steam generation process. Ash is controlled and collected through the use of water, creating a slurry that is conveyed to impoundments or basins with earthen dike walls. In the ash basin, the solids separate from the liquid portion, with the resulting supernatant discharged under the terms of the NPDES permit. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p. 3 e. The coal ash basins at the Duke Energy Facilities are unlined,having no impermeable barrier installed along their floors or sides. Earthen basins and dike walls are prone to the movement of liquid through porous features within those structures through a process known as seepage. Each of the Duke Energy Facilities covered by this Special Order exhibits locations adjacent to,but beyond the confines of, the coal ash basins where seepage of coal ash wastewater from the coal ash basins may intermix with groundwater, reach the land surface(or "daylight"), and may flow from that area. Once such seepage reaches the land surface,.it is referred to as a"seep." Each of the seeps identified at the Duke Energy Facilities and addressed in this Special Order exhibit some indication of the presence of coal ash wastewater. Both(a) confirmed seeps and(b)areas identified as potential seeps that were later dispositioned, are identified in Attachment A. f. Some of Duke Energy's coal ash impoundments contain constructed features on or within the dam structures (such as toe drains or filter blankets)to collect seepage. This wastewater is conveyed via a pipe or a constructed channel directly to a receiving water. These discrete, identifiable, point source discharges are or will be covered and regulated by the respective NPDES permits and designated as outfaIls therein. The characteristics of these wastewater flows are similar to those discharging from other permitted outfalls for ash basin effluent. In this Special Order, seeps that are(1.) on or within the dam structures and(2) convey wastewater via a pipe or constructed channel directly to a receiving water are referred to as"constructed seeps." Seeps that are not on or within the dam structures or that do not convey wastewater via a pipe or constructed channel directly to a receiving stream are referred to as "non-constructed seeps." g. Non-constructed seeps at the Duke Energy Facilities often exhibit low flow volume and may be both transient and seasonal in nature, and may, for example, manifest as an area of wetness that does not flow to surface waters, a point of origin of a stream feature, or flow to an existing stream feature. These circumstances of the non-constructed seeps make them difficult to discern, characterize, quantify and/or monitor as discrete point source discharges. This creates challenges in permit development and compliance monitoring because it is difficult to accurately monitor for flow and discharge characterization. Non- constructed seeps at the Duke Energy Facilities present significant challenges to their inclusion in NPDES permits as point source discharges,but they do cause or contribute to pollution of classified waters of the State. Therefore,these non- constructed seeps are addressed in this Special Order rather than in an NPDES permit. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p.4 h. Investigations and observations conducted by the Department and U. S. Army Corps of Engineers staff have concluded that some seeps emanating from Duke Energy's coal ash ponds create and/or flow into features delineated as classified waters of the State or Waters of the United States. i. Collectively, the volume of non-constructed seeps is generally low compared to the volume of permitted wastewater discharges at the Duke Energy Facilities. j. In 2014,Duke Energy conducted a survey of each coal-fired electric generation station to identify potential seeps from the coal ash surface impoundments. Duke Energy included all areas of wetness identified around the impoundments as seeps,and submitted applications to include those seeps in NPDES permits. Beginning in 2015,Duke Energy has implemented semi-annual surveys to identify new seeps in the vicinities of the coal ash basins. Additional seeps have been observed and documented during these surveys and reported to the Department pursuant to a Discharge Identification Plan mandated by CAMA. Additional investigation has determined that not all of areas identified in 2014 are seeps,but each Duke Energy facility does have multiple seeps. k. The Department issued NOVs to Duke Energy on March 4, 2016 for the seeps that emanate from the unlined coal ash surface impoundments at the Duke Energy Facilities. 1. Non-constructed seeps create conditions such that certain surface water quality standards may not consistently be met at all Duke Energy monitoring sites. M. The presence of coal ash influenced water in the non-constructed seeps causes or contributes to pollution of the waters of this State,and Duke Energy is within the jurisdiction of the Commission as set forth in G.S. Chapter 143,Article 21. n. A list of seeps identified in the vicinities of the coal ash surface impoundments at the Allen,Marshall and Rogers plants, as well as their locations, and the bodies of water those seeps may flow into (if applicable), can be found in Attachment A to this Special Order. o. Duke Energy must close the coal ash surface impoundments at all North Carolina coal-fired electric generating stations in accordance with applicable requirements set out in CAMA and the Federal Coal Combustion Residuals Rule,requirements of which are independent of the resolution of seeps addressed in this Special Order. p. Decanting of wastewater performed at Duke Energy's coal ash basins is expected to eliminate or substantially reduce the seeps from the ash basins at the Duke Energy Facilities. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p.5 q. Since this Special Order is by consent,the Parties acknowledge that review of the same is not available to the Parties in the N.C. Office of Administrative Hearings. Furthermore,neither party shall file a petition for judicial review concerning the terms of this Special Order. 2. Duke Energy,desiring to resolve the matters causing or contributing to pollution of the waters of the State described above, hereby agrees to do the following: a. Penalties 1) Upfront Penalty. As settlement of all alleged violations due to seepage at these Duke Energy Facilities,pay the Department,by check payable to the North Carolina Department of Environmental Quality, a penalty in the amount of$156,000,calculated based upon$12,000 each for five constructed seeps identified prior to January 1, 2015 and$6,000 each for sixteen non-constructed seeps identified prior to January 1, 2015. A certified check in the amount of$156,000.00 must be made payable to the Department of Environmental Quality and sent to the Director of the Division of Water Resources (DWR)at 1617 Mail Service Center, Raleigh,North Carolina 27699-1617 by no later than thirty(30)days following the date on which this Special Order is approved and executed by the Commission, and received by Duke Energy. No penalty shall be assessed for seeps identified after December 31, 2014, given Duke Energy's inclusion of seeps in permit applications and compliance with the Discharge Identification Plan required under LAMA. By entering into this Special Order, Duke Energy makes no admission of liability, violation or wrongdoing. Except as otherwise provided herein,l payment of the upfront penalty does not absolve Duke Energy of its responsibility for the occurrence or impacts of any unauthorized discharges in the area of the Duke Energy Facilities that may be discovered in the future,nor does the payment preclude DWR from taking enforcement action for additional violations of the State's environmental laws. 2) Stipulated Penalties. Duke Energy agrees that unless excused under paragraph 5,Duke Energy will pay the Department, by check payable to the North Carolina Department of Environmental Quality, stipulated penalties according to the following schedule for failure to perform activities described in paragraphs 2(b, c, and d), or for failure to comply with interim action levels listed in Attachment A. 1 See especially paragraph 2(a)(2) excepting newly identified seeps from future penalties under certain conditions. EMC SOC WQ S17-009 Duke Energy Carolinas,LLC p.6 Failure to meet a deadline in the Compliance $1,000.00/day for the first seven Schedule in 2(b)of this Special Order days; $2,000.00/day thereafter_ Failure to meet any other deadline in this $1,000.00/day for the first seven Special Order days; $2,000.00/day thereafter _ Exceedance of an interim action level listed in Attachment A $4,500.00 per monitored ex.ceedance Monitoring frequency violations $1,000,00 per violation Failure to submit, within 210 days of the completion of decanting at each Facility, adequate amendments to groundwater Corrective Action Plans or Closure Plans to $5,000.00 per day,to a maximum of address all remaining seeps, whether $1 lity. 00.00 per electric generating constructed or non-constructed,through facility: corrective action as applicable under raraera ih 2(d) of this S ecial Order.2 As long as Duke Energy remains in compliance with the terms of this Special Order, as well as CAMA and conditions of any approvals issued thereunder,the Department shall not assess civil penalties for newly identified seeps. b. Compliance Schedule. Duke Energy shall undertake the following activities in accordance with the indicated time schedule. No later than fourteen (14) calendar days after any date identified for accomplishment of any activity,Duke Energy shall submit to the Director of DWR written notice of compliance or noncompliance therewith. In the case of compliance,the notice shall include the date compliance was achieved along with supporting documentation if applicable. In the case of noncompliance, the notice shall include a statement of the reason(s) for noncompliance,remedial action(s) taken, and a statement identifying the extent to which subsequent dates or times for accomplishment of listed activities may be affected. Duke Energy shall accelerate compliance with the requirements of G.S. 130A- 309.210(d) and(f) such that all projects necessary to eliminate discharges of stormwater into the surface impoundments at the Duke Energy Facilities and to convert to dry bottom ash handling shall be complete prior to the deadline for initiating decanting set out below. 2 Failure to adequately implement any amended Corrective Action Plan or Closure Plan will be handled in the normal course. EMC SOC WQ S17-009 Duke Energy Carolinas,LLC p.7 1) Complete dr►-ash handling projects in accordance with the followin:: schedule Facilitv 171 Ash Bottom Ash Allen Complete 3/31/2019 Marshall Complete 1/31/2019 Rogers 3/31/2018 8/31/2018 2) Initiation of Decantint,. Allen 6/30/2019 Marshall 9/30/2019 Rogers 3/31/2019 3) Completion of Decantiny, Allen 6/30/2020 Marshall 3/3 l/2021 Rogers 3/31/2020 This schedule is premised upon timely issuance of necessary permits or approvals, and no requirement imposed by DWR to implement physical/chemical treatment during decanting except as required by an NPDES permit. Should any of these assumptions prove to be incorrect, the Parties shall renegotiate these deadlines, provided that the final expiration date of this Special Order will not be affected by such renegotiation. 4) Termination of S 1.i ecial Order This Special Order shall terminate on a facility-by-facility basis on the later of the following dates: 180 days following completion of decanting; or 30 days following the approval of an amended groundwater Corrective Action Plan and/or Closure Plan as appropriate (if an amendment is submitted in compliance with subparagraph d. below). EMC SOC WQ S17-009 Duke Energy Carolinas,LLC p. 8 C. Additional Compliance Measures. Duke Energy shall undertake the following additional compliance measures: 1) If the monitoring of any classified water of the State receiving flow from seeps regulated by this Special Order indicates exceedance of any interim action level established by the Special Order,Duke Energy shall increase monitoring at that location from quarterly to monthly until concentrations of monitored characteristics return to those observed at the initiation of the Special Order. If any interim action level established by the Special Order is exceeded by more than 20%in a single sampling event, or exceeded for two(2)consecutive monitoring events,in addition to paying the associated stipulated penalty, Duke Energy shall conduct a re-assessment of the contributing seep(s), including,but not limited to,evaluation of proposed remedial actions for treatment and/or control of the seep such that impacts to the receiving waters are quickly mitigated. A report compiling the findings of the re-assessment,including proposed remedial actions, shall be provided to the Director of DWR within 60 days of any applicable exceedance. Following its review,DWR shall notify Duke Energy of its concurrence or disapproval of Duke Energy's proposed remedial actions. 2) Once the decanting process is initiated, within thirty (30) days after the end of each quarter, Duke Energy shall provide reports on the status of decanting work and other activities undertaken with respect to closure of each coal ash surface impoundment to DWR. The quarterly reports are due by April 30,July 30, October 30 and January 30 while this Special Order is in effect. The reports are to be submitted as follows: one copy must be mailed to the appropriate Regional Office Supervisor for each facility and one copy must be mailed to the Water Quality Permitting Program, Division of Water Resources, 1617 Mail Service Center, Raleigh,NC 27699-1617. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC P.9 3) Duke Energy shall conduct annual comprehensive surveys of areas down gradient of ash basins identifying new seeps, and documenting the physical characteristics of previously documented seeps. All examinations of seeps must include identification of seeps by approximate latitude and longitude and date-stamped digital photographs of their appearance. A report summarizing the findings of the surveys, including a section analyzing the effect decanting of the basin(s)has on seep flows, accompanied by copies of the photographs noted above ("Annual Seep Report"), shall be submitted to DWR in conjunction with submittal of the April 30 quarterly report noted in 2(c)(2) above. This Annual Seep Report must list any seep that has been dispositioned(as described below) during the previous year,including an analysis of the manner of disposition. For purposes of this Special Order, "dispositioned"includes the following: (1) the seep is dry for at least three consecutive quarters; (2)the seep does not constitute, and does not flow to,waters of the State or Waters of the United States for three consecutive quarters; (3)the seep is no longer impacted by flow from any coal ash basin such that concentrations of all pollutants listed in Attachment B meet State criteria for four consecutive sampling events with at least seven days separating each event; or(4)the seep has been otherwise eliminated(e.g.,through an engineering solution). If a seep that has been dispositioned through drying up reappears in any subsequent survey, such a seep will no longer be deemed dispositioned and can be subsequently re-dispositioned as specified above. 4) No later than 90 days following the completion of decanting at each Facility, and in the same manner as in the annual surveys, Duke Energy shall conduct a comprehensive survey of areas down gradient of ash basins identifying new seeps, and documenting the physical characteristics of previously documented seeps. All examinations of seeps must include identification of seeps by approximate latitude and longitude and date- stamped digital photographs of their appearance. A report summarizing the findings of this survey,including a section analyzing the effect decanting of the basin(s) has had on seep flows, accompanied by copies of the photographs noted above, shall be submitted to the Director of DWR ("Final Seep Report"). This Final Seep Report must list any seep that has been dispositioned(as described in subparagraph(3) above) during decanting process,including an analysis of the manner of disposition. The determination of whether a seep is dispositioned rests with the Director of DWR. At, or at any time prior to, submission of the Final Seep Report, Duke Energy shall seek formal certification.from the Director of DWR, certifying the disposition of any seep that Duke Energy has characterized as dispositioned. Any seeps not certified as dispositioned by the Director of DWR shall not be deemed as dispositioned. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC P. 10 d. Further Corrective Action. Following completion of decanting, if any seeps (including both constructed and non-constructed seeps) have not been certified by the Director of DWR as dispositioned(as described in subparagraph c. above), Duke Energy shall conduct a characterization of those seeps.3 Duke Energy shall submit a report on the findings of these characterizations ("Seep Characterization Report") to the Director of DWR within 150 days of completion of decanting at each Facility(i.e., within 60 days of the submittal of the Final Seep Report). The Seep Characterization Report must include all sampling data for each remaining seep as well as Duke Energy's evaluation of the jurisdictional status of all seeps at the relevant Facility. The determination regarding whether a surface water feature is a classified water of the State rests with DWR. Within 60 days of the submittal of the Seep Characterization Report,Duke Energy shall submit a complete and adequate proposed amendment to the groundwater Corrective Action Plan and/or Closure Plan as appropriate for the Facility describing how any seeps identified in the Seep Characterization Report will be managed in a manner that will be sufficient to protect public health, safety, and welfare, the environment, and natural resources. This proposed amendment will go to public comment. Duke Energy shall submit documentation that the proposed modification has been submitted to the appropriate division within the Department that has authority for approving modification of the groundwater Corrective Action Plan and/or Closure.Plan. The content of, and DEQ's review of, an amendment to a groundwater Corrective Action Plan shall be consistent with Title 15A, Chapter 2L of the N.C. Administrative Code(specifically including 2L.0106(h)-(o)). The amendment to the Corrective Action Plan and/or Closure Plans shall be implemented by Duke Energy in accordance with the deadlines contained therein, as approved or conditioned by the Department. Failure by Duke Energy to implement the amendment will be handled in the normal course by the Department in accordance with its enforcement procedures (i.e., outside this Special Order). 3 If any seep is dispositioned between the time that the Final Seep Report is submitted and the time the Seep Characterization Report is submitted, an analysis of the manner of disposition must be included in the Seep Characterization Report, and Duke Energy must seek certification of such a disposition from the Director of DWR. Only if such certification is received prior to the due date of the proposed amendment described in paragraph 2(d) may such a seep, certified as dispositioned,be omitted from the proposed amendment. EMC SOC WQ S17-009 Duke Energy Carolinas,LLC P. 11 For clarity,listed below is a summary of the timetable for the documents due after completion of decanting(as described in 2(c)(4) and 2(d) above): Document Due Date Final Seep Report 90 days after completion of decanting 150 days after completion of Seep Characterization Report decanting (i.e., 60 days after submission of Final Seep Report) Proposed amendment to groundwater 210 days after completion of Corrective Action Plan and/or Closure decanting (i.e., 60 days after Plan submission of Seep Characterization Report) e. Interim Action Levels. 1) Duke Energy shall perform monitoring of waters receiving flow from non- constructed seeps in accordance with the schedules listed in Attachments A and B,except as noted in paragraph 2(c)(1) above. 2) Upon the complete execution of this Special Order, with regard to non- constructed seeps,interim action levels for the receiving waters (which are minor tributaries)are hereby established as noted in Attachment A. The interim action levels are site-specific. Duke.Energy shall monitor at approved sampling sites to ensure interim action levels are met. Interim action levels shall remain effective in the designated surface waters until the applicable termination date in paragraph 2(b)(4)is reached. 3) Monitoring associated with seeps covered by this Special Order is exempt from the electronic reporting requirements associated with NPDES permits. Results of monitoring required exclusively per the terms of this Special Order shall be reported to the Director of DWR in a spreadsheet/worksheet format agreed to by Duke Energy and DWR. Monitoring data shall be submitted to the Director of DWR in a digital format no later than 30 days following the end of each calendar quarter for as long as the Special Order is in effect. Monitoring data shall be sent to the following email address: desocdata@ucdenr.gov. Data from those sites with monitoring required exclusively per the terms of the Special Order will be posted on DWR's website to provide the public with the opportunity for viewing. 3. Duke Energy will continue to operate its coal ash surface impoundments in such a manner that their performance is optimized, and potential for surface waters to be affected by seeps is minimized. EMC SOC WQ S17-009 Duke Energy Carolinas,LLC p. 12 4 Duke Energy shall make available on.its external website the NPDES permits,this Special Order and all reports required under this Special Order for each of the Duke Energy Facilities no later than thirty(30) days following their effective or submittal dates. 5. Duke Energy and the Commission agree that the stipulated penalties specified in paragraph 2(a)(2) are not due if Duke Energy satisfies DWR that noncompliance was caused solely by: a. An act of God; b. An act of war; C. An intentional act or omission of a third party,but this defense shall not be available if the act or omission is that of an employee or agent of Duke Energy or if the act or omission occurs in connection with a contractual relationship with Duke Energy; d. An extraordinary event beyond the Duke Energy's control, specifically including any court order staying the effectiveness of any necessary permit or approval. Contractor delays or failure to obtain funding will not be considered as events beyond Duke Energy's control; or e. Any combination of the above causes. 6. Failure within thirty(30) days of receipt of written demand by DWR to pay the stipulated penalties,or challenge them by a contested case petition pursuant to G.S. 15013-23, will be grounds for a collection action, which the Attorney General is hereby authorized to initiate. The only issue in such an action will be whether the thirty(30) days has elapsed. 7. Any non-constructed seeps causing or contributing to pollution of waters of the State associated with the coal ash impoundments at Duke Energy's Allen,Marshall and Rogers electric generation stations, and listed in Attachment A to this Special Order,are hereby deemed covered by this Special Order. Any newly-identified non-constructed seeps discovered during the annual investigations for seeps referenced in paragraph 2(c)(3) above, or at any other time while this Special Order is in effect, and timely reported to the Department per the terms of LAMA and this Special Order, shall be deemed covered by the terms of the Special Order,retroactive to the time of their discovery. Newly- identified non-constructed seeps must be sampled for the presence of those characteristics listed in Attachment B to this Order. Newly-identified non-constructed seeps found to be causing or contributing to pollution of the waters of the State, with the effect of causing a violation of water quality standards in surface waters not already referenced in the Special Order,may require modification of the Special Order to address those circumstances. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p. 13 8. Noncompliance with the terms of this Special Order is subject to enforcement action in addition to the above stipulated penalties, including,but not limited to injunctive relief pursuant to G.S. 143-215.6C or termination of this Special Order by the Director of DWR upon ten (10) days' notice to Duke Energy. Noncompliance with the terms of this Special Order will not be subject to civil penalties in addition to the above stipulated penalties. 9. This Special Order and any terms or conditions contained herein, hereby supersede any and all previous Special Orders,Enforcement Compliance Schedule Letters,terms, conditions, and limits contained therein issued in connection with NPDES permits NC0004979,NC0004987 and NC0005088. 10. This Special Order may be modified at the Commission's discretion,provided the Commission is satisfied that Duke Energy has made good faith efforts to secure funding, complete all construction, and achieve compliance within the dates specified. In accordance with applicable law,modification of this Special Order will go to public notice prior to becoming effective. 11. Failure to pay the up-front penalty within thirty(30) days of execution of this Special Order will terminate this Special Order. 12. In addition to any other applicable requirement,each report required to be submitted by Duke Energy under this Special Order shall be signed by a plant manager or a corporate official responsible for environmental management and compliance, and shall include the following certification: I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. 13. This Special Order shall become effective in accordance with state law, and once effective,Duke Energy shall comply with all schedule dates, terms, and conditions herein. EMC SOC WQ S 17-009 Duke Energy Carolinas,LLC p. 14 This Special Order by Consent shall expire no later than June 30,2022. 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Qa `a a a a a Y Y Y m L m Q E a m O O O O U u u 0 o E � 0 m m` m` co in V) V) o aa+ a8 CJ � <n Ln 0 -0 N � U Q Q m ¢ CY �► Oa C a c W N N O M a > y myO %- >,a L C a a C P a m , C a a m C m m w CO p (n O = mLL m 2L; y Q Y3 a w C cc Em O b Yp_Y ` C N +' m 0 a+ 0 +' m u m a m 0 O m m c E C� M. o a L a 4-1 m s U i 4- P + O ay Q0 Q 4)au m OC-0 M OD Lap a u >L t O p r+uM m O a C ' > S a IA v O ' LL OU m O O 0 o O m a a a - O -0 ro a C ,ONaa op O 3 O a+ a o O C ' o yw 0 Na O a 3 a 3 0 m m p E as m ao o 0 Y o U o y U ° N c a ° s' c a a o "' 3 m ° a o s , 8 a Y y u a a a) 3 = Y c a E � +-„ Q o m ¢ o �, a ,�, o a p o .r 0 M 0 a a -0 0 v) c ' +- a 3 a > m Q O. > m p• N C Q y m LL Mn p a �} C O C coil ` O 3 m s. c y E m y o m `. c y m 3 0 Y 3 > cC0 d c_ 3 c x cr o (D vai 1 vai axi a 0 3 c g m s vai 3 vi a o Q FL- $ E a c a Y - L m N rl 00 'a a o a h LD °ram° coo N c Rr a lD 4o rr at Ln W �D a m .+ a ,mj ,)y f r ram., n Ln n h n n n ,4; i m a O tp a J aa+ p PI ei e-1 ri a-i �-I pmp G. a 7 a c ao op oo ao 0o ao 0o uv - " c o 'a a m ' o L 7 '> C u 'c D a N LA N e-1 L V O U io Ql '1 n 00 a y C a -� Q 4.. 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Q Q Q Q a v a BCD a v 41 c aJ C c aJ c aJ C E a; a, o a, o M o -0 m � aJ(AuO a� o (ua QJ C 'ifJ 'uJ \ N \ iO \ f6 \ f6 •a fO \ f0 N 'rn 41 IJ 'vl 41 c Q O Q o z a Z rs z M z a z is z c ` oLn Wp Q ` ` oa _ a Z a z ° rcc m m m 1 m m CL z z y Q In n n N i n L a b o N I co N Co N N tw 412 C a aJ a aJ Y 4D Y WD Y h013C OD �C OD 3C OD a aJ I a w a aJ `o ac) aJ c ar c aJ E c O E c a, E c w E c aJ E c aJ E c ar c w C v c Q c E to o �' a `o o �' o a v o CU L. w o �' v o �^ ° '^ rn O I '� I an U + V ` ++ U ` 41 U ` ++ U ++ U i w c a ` CL a c o 3 c o c o c o v c o c o OL CL? a *O� O � zD z � 0I ( � (A Mtn Ln Z � zO zO m �+ 0D p O m ate+ > Q �° > > > > > > > > > > > v) a 0) V) Ln cn Ln V> dJ v) vi v) LA o 0 O @ Y �f Y Y Y 44 Y Y X C O E 0) Cl) aJ aJ aJ 0) aJ OJ 01 O = a �-, a u u u U` u u u u u - a U �„� f0 Y 3Y .Y Y .Y Y Y �0 Y Y O a N �O O L.J U U U U U U a U U U O E L- y. O > > 7 O 7 3 p 7 7 W {... U m in cn � CA yr to m `n `n v H '^ O a O ( --- c O v Ln E 9 E Y d a3 aJ aJ a) Y OJ t L t ^ y to 7 ti4 >! CO 7 CtD t'� y7 Oj y to U ++ U 'V4 L C V 1..7 f.' •C.7 C U S� 1/1 L a7 L C7 Y m IA W e`D U � 0 0 O ro O co a@ O (a O rD a) @ U Q fO ++ VI O i- c O 16 aJ eo a) ro aJ ra aJ ro aJ > c C Y d a M m Q r ? y to� o w o � v m aai t'n ? aci hD m ..- � �+ 3 ro �►- ro � m 4- M L+ ra � aJ �. . a O m fl i o R v o a s a O a o 0. o a o o z o O Ql +, c E cC v. a '6 C ,� (J a' m — 0) 4+ aJ — a " L_ � c Y +' m C ° u 3 c o .°)c > �' v w a aJ v a' aJ a v m `= a c l u 0) V m U g a 'r m` w 3 ¢ m 3 3 3 al 3 w 3 0 o m c °a m q J ++ O O SC +' •]C Y Y ++ y y Y r+ Y Y '�••' 9 7 V J p, O +� M t aJ 'a N M O) M a) N aJ M (D M (D C m U @ ... O a c N o Y Y OJ a 3 v 3 �J 3 v 3 3 43) c x c c -7 rmo m -0 3 (D < � u c � cU cU cv cv 41 a, m a) cn o ,n c Q O U m OJ aIn _ro C 5 O I y H S U O O Ln W V) dD N OD to OD N OD N w '' - a j. C C M m m 0 1 7 01'O Cl u0i O Y A 0 -Y y 0 Y in O Y_ o `~ Y_ U O t d > u U C U a E w = .4+ N N m O Y 'O Y a 3 Y a 7 .nt a 3 Y 'a O O m vi y c c Y bo O1 v a •a u C 3 � c c c c c c c c c E �, to m` u u c - . m z o " 3 bD0v n '� v NJa °a � -0ra •rA f6 cc ar o 3 ro = u C t - ns L ca rD f6 m 3 cc 3 a 4 o E 'O a o aJ ° a c o .c o .° o ° o Q.n o a.o CL O a ° w X C C O N 10 aJ N S O C t = C _c d C = a7 @ H m fYO r C O i W O aJ 0 O .. r+ co +� In m w m to N LL T3 Z z N ° OQ 0) Iv o z c to a .— E m a co 1„ m v c a r Y N ~O m �+ v . ao w m rl to at Ln m f6 aJ C -� 07 m r n 0) 0o V Lr) N O M "O G. O 00 01 d• 00 Ch 00 w r, r r, C +-' 3 r-I m to m M M M m Tt m Ln Ln Ln Ln N Ln Ln to LA Ln Ln 0) L M OJ U N dD n t` n N n n h n h n - r0+ p r1 e 4 r4 ri r7 i 4 rq ri rl r1 OOD O. �0) C J O0 CO OO OO Op CO 00 OO C0 OO N ` U C - > m � O E -0m Ln N N to N 00 N LD M •s C U O VaJ 00 N W r. v M co In r. Ln o .00 a, O t0 vt to Ln ,I et N N LM N S ai O 7 r- n e-1 ei ci ri H r1 00 n 00 i/1 C aJ — O. :Ll e-r �i rt -1 p 1-I If 1-1 r1 e-1 O 7 O .0 M (y +� N N N N N N N N N N N O Q J Ln Vl vi Ln Ln Ln Ln Ln ui to N m m ") m m r m m rn m m M d o to a ° DL N 00 Os o r1 N + + I o o.'o C N £ N Lo N N N M M T m M fM I4' Iy z In rn of vJ vJ vJ vJ vJ yr yr y o In o E { J IF a CL EL a E JLn m Q Co m O z 'O Z -0 z v c Qu m m m N V1 VS an co m N N N OD w a L 'L C to wE C > E toO C L m L `J m V j2 M L, C2 O ` U ` O U ay O p 0 0 O Ln C c N C c m C c cc m N 41 N > 0 v> m tto'D m +�+ > > > > V u rCA 3 �' o 0: M U p O C Q. ci y U U V O Q C L m G u u O 0 O E L y 0 V) V) m O j U E 0 p a ti O I� OJ M.0 v N 07 V 0CV) y t V �.- ++ O N N to N c 0 O V YO s w O O a v m m Q L y > ,L +' N u rn a+ p 4A N u :ke -0a&n O LM Y m �' O a ami v 1 4 3 0i aa) v 3 y ° c E L Vp, +� c ' 0 OU mC d LA u cO +a00 w 0 H O+ Qa�m O X \ > O O O) j LL C a m Q m ) d 4-1 y a 9 O V C Q . '+3.tn c 3 v o non 3 w° (D o �' w ° g v ,Y L m c N 00 Zn m` 3 Q. C 0 0 m m �; •pp m C � •Q v V y Q = 0 w O oo L 3 Q v c c a + c '^ LSD c •4 U z +m+ ul d m y `M w. Q p Ln LO u 0 Q 7 y m 0) a� C m a@ co c c a�j >. N .�[ "O C O) C v o °,�' o = m vv, Q u o 3 m tf v o �e c y Y = m Y o X 'a- != c c •vL L a+ L N O a) u 0 C O L d .0 V •a t� c m a0+ N Ln 'C O � 0 C a 0] (4 Y M N QS \ N y Q C 00 N �-4 en 'a p 7 M 00 cm c aC. Q- R Y LMfl imfl VMS 'O m M 'a 0 y c n n n I m O O u v c w op o`p °,-° alai �+ 0) 7 0 m I - > ; O x p O) VAS n0 w C -p u N N Ln A v u -0 OL U y O O 00 j p a r, .-I ,q a N N N _o Z3 m Q J LA LA ui •� •� m 00 m m m v o y c a Q a0 L O y c `a S a 'o n T c a o c a m m m (Uo VS Vt Vi V Ln C LnZ 0 * 0 _ y 1� ' T 41 • ` s ' -_I r r L- •-� .S ~ r 1 1 . r AV - + 1 1 , � �s • f: �a SOC S l 7-009 Duke Energy Carolinas, LLC Attachment B Monitoring Requirements The following represents the parameters to be analyzed and reported at all monitoring locations designated within this Special Order. Parameter l Reporting Units Monitoring Fre uenc TSS mg/L Annually Oil and Grease mg/L Annually pH Standard Units(s.u.) Quarterly Fluoride pg/L Quarterly Total Mercury nglL Quarterly Total Barium ug/L Quarterly Total Zinc erg/L Quarterly Total Arsenic _ fag/L Quarterly Total Boron Ng/L Quarterly Total Cadmium erg/L Quarterly Total Chromium uglL Quarterly Total Copper Ng/L Quarterly Total Thallium lrg/L Quarterly Total Lead _ Ng/L Quarterly Total Nickel Ng/L Quarterly Total Selenium Ng/L Quarteri Y Nitrate/Nitrite as N mg/L Quarterly Bromides mg/L Quarterly Sulfates mg/L Quarterly Chlorides mg/L Quarterly TDS mg/L Quarterly Total Hardness mg/L Quarterly [Temperature °C Quarterly Conductivity, Nmho/cm Nmholcm Quarterly Seep Management Plan Amendment to Corrective Action Plan December 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra APPENDIX B MANN-KENDALL ANALYSIS, OCTOBER 2020 410 r3ynTerra MANN-KENDALL TREND TEST ANALYSIS ALLEN STEAM STATION 253 PLANT ALLEN ROAD BELMONT,r NC 28012 OCTOBER 30,f 2020 PREPARED FOR DUKE ENERGY. DUKE ENERGY CAROLINAS, LLC Mann-Kendall Trend Test Analysis October 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra TABLE OF CONTENTS SECTION PAGE 1.0 THE MANN-KENDALL TREND TEST...................................................................1-1 2.0 TIME VERSUS CONCENTRATION PLOTS .........................................................2-1 3.0 MANN-KENDALL TREND TEST RESULTS.........................................................3-1 LIST OF FIGURES Figure 1 Time vs pH Figure 2 Time vs total suspended solids Figure 3 Time vs total boron concentration Figure 4 Time vs chloride concentration Figure 5 Time vs sulfate concentration Figure 6 Time vs total dissolved solids Figure 7 Time vs total arsenic concentration Figure 8 Time vs total barium concentration Figure 9 Time vs total cadmium concentration Figure 10 Time vs total chromium concentration Figure 11 Time vs total copper concentration Figure 12 Time vs total mercury concentration Figure 13 Time vs total nickel concentration Figure 14 Time vs nitrate+nitrite concentration Figure 15 Time vs total selenium concentration Figure 16 Time vs total thallium concentration Figure 17 Time vs total zinc concentration Figure 18 Time vs bromide concentration Figure 19 Time vs fluoride concentration Figure 20 Time vs hardness Figure 21 Time vs oil and grease LIST OF TABLES Table 1 Sampling Locations and Constituents Included in Concentration over Time Plots Table 2 Results of Mann-Kendall Trend Test Page Mann-Kendall Trend Test Analysis October 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 1.0 THE MANN-KENDALL TREND TEST The Mann-Kendall trend test evaluates data over time for monotonic trends, where monotonic indicates a trend that is solely increasing or decreasing. Mann-Kendall is a useful trend test in that it is non-parametric and does not require normal distribution of data. To perform the Mann-Kendall trend test at Allen, the data must first be processed as follows: • Non-detects greater than regulatory values are removed. If a COI has multiple reporting limits only the lowest reporting limit is kept. • Non-detects are treated as the reporting limit. • Samples with turbidity greater than 50 NTU (nephelometric turbidity units) are removed. • Samples with pH greater than 10 SU are removed. • Samples have to be at least one month apart. If two samples are closer than one month, the less complete sample is removed. If samples are equally complete,the earliest sample is kept. Next, the data must meet the following requirements for a Mann-Kendall trend test to be applicable: • There must be at least four detect measurements. • Non-detects must make up less than or equal to 50 percent of measurements. In a Mann-Kendall trend test, each value is compared to the proceeding values to calculate whether the value has increased, decreased, or stayed the same over time. These comparisons are recorded as simply 1 (increasing), -1 (decreasing), or 0 (stayed the same). These comparisons give an S value, where S indicates the type of trend. A negative S value indicates a decreasing trend, and a positive S value indicates an increasing trend. Whether or not these trends are statistically significant is dependent on the two-sided p value. A p value ranges from 0 to 1 and indicates whether the results are due to chance or the results are statistically significant. Greater p values indicate a trend is not statistically significant, and a p value less than 0.1 indicates a statistically significant trend. All Mann-Kendall trend tests are performed in the program RStudio using the "Kendall" package. Page 1-1 Mann-Kendall Trend Test Analysis October 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 2.0 TIME VERSUS CONCENTRATION PLOTS Plots of concentration over time provide a visual representation of possible trends in the data. All plots can be viewed in Figure 1 to Figure 21. Plots are grouped by constituent, and within the figure, a plot of concentration over time is displayed for each location that has data for that constituent. It is important to note that some constituents, such as hardness,have limited samples in few locations. All locations and constituents included in these plots can be found in Table 1. Trends from the Mann-Kendall tests are displayed on plots with colored borders representing trend conclusions. Blue indicates no trend was present, green indicates a decreasing trend, yellow indicates an increasing trend, and no color indicates the constituent-location pair cannot be analyzed for trends due to a lack of detect measurements. Detect measurements are shown as a black point,whereas non-detect measurements are shown as an open circle. Page 2-1 Mann-Kendall Trend Test Analysis October 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra TABLE 1 SAMPLING LOCATIONS AND CONSTITUENTS INCLUDED IN PLOTS OF CONCENTRATIONS OVER TIME Sampling Locations Constituents S-2 pH S-05 Total Suspended Solids S-6 Total Boron S-07 Chloride S-10 Sulfate Total Dissolved Solids Total Arsenic Total Barium Total Cadmium Total Chromium Total Copper Total Mercury Total Nickel Nitrate + Nitrite Total Selenium Total Thallium Total Zinc Bromide Fluoride Hardness Oil and grease Note: If a location-constituent pair does not have a plot,data was not available for that pair. Page 2-2 Mann-Kendall Trend Test Analysis October 2020 Allen Steam Station-Duke Energy Carolinas,LLC SynTerra 3.0 MANN-KENDALL TREND TEST RESULTS Results of the Mann-Kendall trend tests are displayed in Table 2. Trend analysis could be performed for only 23 location-constituent pairs due to a lack of detect measurements. Either there are less than four samples, less than four detects, or the number of non-detects is greater than the number of detects. The number of non-detect measurements present in the dataset indicates that many constituent-location pairs have concentrations less than the regulatory limit and are not predicted to be of concern at the Site. Locations not displayed in Table 2 are excluded due to having less than minimum number of samples required to run the "Kendall" package in RStudio. Locations must have at least three samples to be included,but individual location-constituent pairs with less than three measurements can be analyzed as long as the location itself has three samples. However, it is important to note that location-constituent pairs with less than four detects cannot be analyzed for trends based on the criteria in Section 1.0. Out of the 23 constituent-location pairs that have trend conclusions, 82.6 percent are stable with no trends (19 out of 23 constituent-location pairs), 8.7 percent have statistically significant decreasing trends (2 out of 23 constituent-location pairs), and 8.7 percent have a statistically significant increasing trend (2 out of 23 constituent-location pairs). All of the increasing trends occur at S-2. Overall, the results of the Mann-Kendall trend tests indicate a system that is been geochemically stable, with the majority of concentrations of constituents remaining stable over time. 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