HomeMy WebLinkAboutWI0400561_Permit (Issuance)_20210111NC Department of Environmental Quality — Division of Water Resources (DWR)
NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS
The following are `permitted by rule" and do not require an individualpermit when constructed in accordance
with the rules of I5A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection)
AQUIFER TEST WELLS (15A NCAC 02C .0220)
These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics.
IN SITU REMEDIATION (15A NCAC 02C .02251 or TRACER WELLS (15A NCAC 02C .0229):
1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include
ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be
submitted for replacement of each sock used in ORC systems).
2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000
square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required
for test or treatment areas exceeding 10,000 square feet.
3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a
remediation strategy in order to develop a full scale remediation plan for future implementation, and where the
surface area of the injection zone wells is located within an area that does not exceed five percent of the land surface
above the known extent of groundwater contamination. An individual permit shall be required to conduct more
than one pilot test on any separate groundwater contaminant plume.
4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater.
5) In -Situ Thermal Wells (IST) — Used to `heat' contaminated groundwater to enhance remediation
Print Clearly or Type Information. Illegible Submittals Will Be Returned as Incomplete.
DATE: December 29 , 2020_
PERMIT NO. W 10400561
(to be filled in by DWR)
NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g.,
different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the
previously assigned permit tracking number and any needed relevant information to assess and approve injection:
Permit No.
Issued Date:
A. WELL TYPE TO BE CONSTRUCTED OR OPERATED
(1) Air Injection Well.......................................Complete sections B through F, J, M
(2) Aquifer Test Well.......................................Complete sections B through F, J, M
(3) Passive Injection System...............................Complete sections B through F, H-M
(4) Small -Scale Injection Operation ......................Complete sections B through M
(5) X Pilot Test.................................................Complete sections B through M
(6) In -Situ Thermal (IST) Well...........................Complete all sections except K
B. STATUS OF WELL OWNER: Business/Organization
Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 1
C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to
sign on behalf of the business or agency:
Name(s): Gandhi & Associates, Inc c/o Dilip Gandhi
Mailing Address: 9201 Leesville Road, Suite 201
City: Raleigh State: NC_ Zip Code: 27613 County: Wake
Day Tele No.: 919-781-5269 Cell No.: 919-810-5122
EMAIL Address:gandi1O@msn.com Fax No.: 919-443-1475
D. PROPERTY OWNER(S) (if different than well owner/applicant)
Name and Title: same as well
Company Name _
Mailing Address:
City:
Day Tele No.:
State
Zip Code:
Cell No.:
EMAIL Address: Fax No.:
E. PROJECT CONTACT (Typically Environmental Consulting/Engineering Firm)
Name and Title: Aaron D. Springer, Environmental Scientist
F.
G.
Company Name Agra Environmental,
Mailing Address: PO Box 5611
City:
State: NC_ Zip Code: 27512
Day Tele No.: 919-858-5350
EMAIL Address:aspringer@agraenvironmental.com
PHYSICAL LOCATION OF WELL SITE
Cell No.
County:
County: Wake
336-596-1350
Fax No.: 919-858-5351
(1) Facility Name & Address: UST Incident #44564 Eagle Food Mart 2
3767 Boy Wood Road
City: Graham County. Alamance Zip Code: 27253
(2) Geographic Coordinates: Latitude": "or 36 0. 00554
Longitude": it or 79 0. 3909
Reference Datum: Accuracy:
Method of Collection: Goojzle Earth
"FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY
BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES.
TREATMENT AREA
Land surface area of contaminant plume: 16,200 square feet
Land surface area of inj. well network: 628 square feet (< 10,000 ft2 for small-scale injections)
Percent of contaminant plume area to be treated: 3.9 (must be < 5% of plume for pilot test injections)
Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 2
0
I.
J.
1N
INJECTION ZONE MAPS — Attach the following to the notification.
(1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the
contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and
proposed injection wells; and
(2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical
extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed
monitoring wells, and existing and proposed injection wells.
(3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing
and proposed wells.
DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE — Provide a brief narrative
regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity:
Pilot test iniection for Corrective Action Feasibilitv studv as reauested by NC DEO DWM UST Section to assess
remedial technologies for UST Incident #44564. Ozone and hydrogen peroxide will be injected into existing
groundwater monitoring well MW-2 continuously over 5 day period. Oxygen BioChem (OBC) will injected into
4 DPT injection wells centered around MW-10.
WELL CONSTRUCTION DATA
(1) No. of injection wells: 4 Proposed 1 Existing (provide NC Well
Construction Record (GW-1) for each well)
(2) Appx. injection depths (BLS): 14-32 ft for DPT 17-37 for MW2
(3) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each
injection well in a diagram or table format. A single diagram or line in a table can be used for
multiple wells with the same construction details. Well construction details shall include the
following (indicate if construction is proposed or as -built):
(a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery
(b) Depth below land surface of casing, each grout type and depth, screen, and sand pack
(c) Well contractor name and certification number
INJECTION SUMMARY
NOTE: Onlv iniectants annroved by the enidemioloQv section of the NC Division ofPublic Health. Department
of Health and Human Services can be injected. Approved injectants can be found online at
http: Hdeq.nc. gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water-
protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use.
Contact the UIC Program for more info ifvou wish to get annroval for a different additive. However. please
note it may take 3 months or longer.
Injectant: Ozone (6%) Total Amt. to be injected (gal)/event:
Injectant: Hagen Peroxide (8%)_Total Amt. to be injected (gal)/event: 250 gal
Injectant: Oxygen BioChem (OBC)Total Amt. to be injected (gal)/event: 400 Ibs
Injectant: Total Amt. to be injected (gal)/event:
Injectant: Total Amt. to be injected (gal)/event:
Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 3
L.
lid
Amt. Water to be injected (gal/event):
Total Amt. to be injected (gal/event):
1,000 gal
No. of separate injection events: Est. Total Amt. to be injected (gal):
Source of Water (if applicable): Ci1y of Graham Public Works
MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine
if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity.
Monitoring wells MW-1 MW-2 NM-4 MW-6 MW-7 MW-10 MW-11 MW-12 and VE-1 will be sample
60 days following conclusion of the pilot test activities and quarterly/biannually quarterly/biannuallythereafter at the request of the
NC DEQ DWM UST Section.
SIGNATURE OF APPLICANT AND PROPERTY OWNER
Well Owner/Applicant: "I hereby certify, under penalty of law, that I am familiar with the information
submitted in this document and all attachments thereto and that, based on my inquiry of those individuals
immediately responsible for obtaining said information, I believe that the information is true, accurate and
complete. I am aware that there are significant penalties, including the possibility offines and imprisonment,
for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the
injection well and all related appurtenances in accordance with the I5A NCAC 02C 0200 Rules. "
Signature of Applicant Print or Type Full Name and Title
Property Owner (if the property is not owned by the Well Owner/Applicant):
"As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to
allow the applicant to construct each injection well as outlined in this application and agree that it shall be the
responsibility of the applicant to ensure that the injection wells) conform to the Well Construction Standards
(15A NCAC 02C . 0200). "
"Owner" means any person who holds the fee or other property rights in the well being constructed. A well
is real property and its construction on land shall be deemed to vest ownership in the land owner, in the
abser ct of gontrary agreement in writing.
Z L t F 6A-0Dki o,
Signature* of Pro rty w er (if different from applicant) Print or Type Vull Name and Title
*An access agreement betty e the applicant andproperty owner may be submitted in lieu of a signature on this form.
Please send I (one) hard color copy of this NOI along with a copy on an attached CD or Flash Drive at least
two (2) weeks prior to injection to:
DWR — UIC Program
1636 Mail Service Center
Raleigh, NC 27699-1636
Telephone: (919) 707-9000
Deemed Permitted GW Remediation N01 Rev. 2-14-2020 Page 4
cYt 61
Aaron D Springer
From: Lepard, Mindy <mindy.lepard@ncdenr.gov>
Sent: Wednesday, July 15, 2020 5:27 PM
To: Aaron Springer
Cc: rbshah@agraenvironmental.com
Subject: RE: [External] RE: 44564 - Eagle Food Mart 2 May 18, 2020 MRP
Aaron,
This site was discussed with the Trust Fund. The next step will be a feasibility study that includes the results of pilot tests
for the injections recommended in the latest report. The pilot tests proposed in the discussion were limited events of
ozone/hydrogen peroxide injection in MW-2 and OBC in MW-10. All monitoring wells should be sampled 60 days after
the pilot tests. Make sure the lab analyzes for oxygenates, including tert-butyl alcohol. The other oxygenates were
included in the lab results in the latest report but TBA was not.
We also discussed installing another vertical extent well at the edge of the property in line with SW-2. The well
construction information for SW-2 will need to be obtained first. This may require using a camera to find the fractures in
the bedrock that feed the water supply well. The specialty drilling task can be used for investigating SW-2.
Please let me know if you have any questions.
Thanks,
Mindy
Nimdy Lepard
I{yc�ogeo:o¢is� �.'T��'ecliox�
e`DE��j� Nol#h Cwolulma Department of F -moommud Quallty
�'' 336-776.96S6 (Office)
Mindy.Legard mdenr_¢ov
guy hc} c#��(biF# bo fhrd�r�s
----------------------------------- ** Important Message" ------------------------------------------------------------------
Until further notice, all UST Section "deliverables/documents" (letters, reports, recorded NRPs etc.) must be submitted electronically
to the appropriate Incident Manager (See below for County Assignments and Contact Information). If a document is too large to send
via email, please upload the document onto the Division of Waste Management FTP site. Follow the upload with an email notifying
the Incident Manager of the document's presence on the FTP server. Contact the appropriate Incident Manager for FTP instructions.
Please provide a responsible party email address with each submittal, if available.
COUNTYASSIGNMENTS (Subject to Change. Check List Freauentiv):
Guilford County: Gene Mao (336-641-3589) Ashley Dinkins (336-641-5557)
Christina Schroeter: Ashe and Forsyth (336-776-9683)
Mindy Lepard: Alamance and Surry (336-776-9686)
Linda Estkowski: Caswell, Davie, Rockingham, Stokes, Watauga, Yadkin (336-996-9680)
Doug Whitmire: Allegheny, Davidson, Randolph, Wilkes (336-776-9685)
Karen Hall: All counties and phases through an LSA, Complaints and Spills (336-776-9681)
Shelia McIntosh: File Reviews (336-776-9630)
ALL UST ARCHIVED FILES CAN BE FOUND ON THE FOLLOWING LINK:
fts://deq.nc.gov/about/divisions/waste-management/laserfiche
DWM LOCATOR TOOL: USE MAP FOR LOCATING UST SITES ACROSS THE STATE:
https: //ncdenr. maps. arc,gis. com/apps/webappviewer/index.html?id=7dd59be2750b4Obebebfa49fc3 83 f68 8
r-
00
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® MW-14®
MW-13
' MW-9 MW-12
I® 0 MW-15
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ff Brush f� f► 1
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® VEW-1 0 0
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IP-3 IP-4 1
M W-2
Direct injection of MW-7
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Map Key
®
Shallow Monitoring Well
•
Deep Monitoring Well
Water Supply Well
Former USTs
•
DPT Temporary Injection Point
Approximate Ozone/Peroxide and OBC A.. Environmental,
Scale Injection Pilot Test — Injection
1 inch = 50 feet Point Locations P.O. Box 5611, Cary, NC 27512
Eagle Food Mart 2 — 3767 Boy Wood Road Drawn Checked
Figure 1 Graham, Alamance County, NC By. ADS By. RBS
r,
00
U
Z
------------- Boy Wood Road
Approximate
Scale
1 inch = 50 feet
Figure 3
Shallow Potentiometric Map
April 2020
Eagle Food Mart 2 — 3767 Boy Wood Road
Graham, Alamance County, NC
81.75 81.5 81.25
80.75
r
80.75
1
I
81
I�
MW-15
81.01
81.2i
I
81.5
1
I
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Map Key
®
Shallow Monitoring Well
•
Deep Monitoring Well
Water Supply Well
Former USTs
/V
Groundwater Contour
Groundwater Flow Direction
P.O. Box 5611, Cary, NC 27512
Drawn ADS Checked RBS
Bv: Bv:
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MW-14®
®
BDL
MW-13
BDL
_ _ _,_,_._._._.
1
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i
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3.
MW-15
EW-2
1 BDL
Brush f�
BDL
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fJ Woods
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1
MW-S
'
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—
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♦ i BDL
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® 500 µg/L®
1
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,
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,
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BDL
Asphalt
S Q
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,
�1
Property Line
`I
Ma Ke
-------------- Boy Wood Road
Approximate
Scale
I inch = 50 feet
Figure 7
Benzene Isoconcentration Map
April 2020
Eagle Food Mart 2 — 3767 Boy Wood Road
Graham, Alamance County, NC
®
Shallow Monitoring Well
Deep Monitoring Well
AL
Water Supply Well
Former USTs
— —
Benzene Isocontour
2L Standard Isocontour(1pg/L)
P.O. Box 5611, Cary, NC 27512
Drawn ADS Checked RBS
Bv: Bv:
B
BDL
1.00
By
100'
MW-8
DISPENSER BASIN VEW-1
MW-12 BDL
100'
M W-14
90'
— n
90'
`
80'
�
`
70`
— —
—70'
2L=1 rb,
60'
60'
50'—
50'
40'
2L=1 µg/L
40'
30'—
30'
20'—
20'
10'
10'
0
0'
Legend
Approximate Scale
Geologic Cross -Section B-B'
A' ra
1 inch = 40 feet
Benzene Isoconcentration
Eagle Food Mart 2 - 3767 Boy Wood Road
P.O. Box 5611, Cary, NC 27512
Graham, Alamance County, NC
Figure 9
Drawn ADS
Checked RBS
ec
-
Red -Brown to Orange -Tan, Silt with Varying Clay/Sand Content
BDL
Below Detection Limit
-
Tan, Silt with Varying Clay/Sand/Weathered Rock Content
1.80
Benzene Concentration 4/21/2020 (pg/L)
Mostly Competent Rock
— — —
Benzene Isocontour
-
Remedial Excavation —Gravel and Soil Backfill
NCAC 15A 2L Benzene Groundwater Standard (1 pg/L)
®
Monitoring Well Screened Interval
UST Incident 44564 Eagle Food Mart 2
3767 Boy Wood Road, Graham, Alamance County, NC
Existing Injection Well Information (Ozone/Hydrogen Peroxide Injection)
Well Type
Monitoring
Well ID
MW-2
Install Date
Unknown
Well Diameter
2 inch
Depth of Casing
17 feet
Depth of Screen
32 feet
Proposed Injection Well Information (OBC Injection)
Well Type
Temporary Borehole*
Tooling
Geoprobe/DPT with Injection Tip Tooling
Depth of Casing BGS
N/A
Each Grout Type and Depth
N/A
Depth of Sand Pack BGS
N/A
Treatment Zone BGS
14-32 feet
Treatment Intervals
2 feet
Well Contractor Name
TBD
Well Contractor Certification #
TBD
*Injection point boreholes to be abandoned with bentonite following removal of tooling. Surface to be
restored to match pre-existing.
Rev 5/1/2012
Page 1
SAFETY DATA SHEET for OZONE
(Formerly MSDS)
1. PRODUCT IDENTIFICATION Product
Name: Ozone
Common Names/Synonyms: Triatomic Oxygen, Trioxygen, 03 Ozone
Generator Manufacturer/Supplier:
Pacific Ozone
6160 Egret Court
Benicia, CA 94510
p: 707-747-9600
f. 707-747-9209
Product Use: This SDS is limited to ozone produced in gaseous form on site by an ozone generator, in
varying concentrations in either air or aqueous solution, for the purposes of odor abatement, oxidation of
organic compounds, or antimicrobial intervention, in a variety of applications, from food processing to
ground water remediation.
2. HAZARD IDENTIFICATION
4� 40� <$�
GHS Classifications:
Physical Hazards
Health Hazards
Environmental Hazards
Oxidizing Gas
Skin Irritation — Category 3
Acute Aquatic Toxicity —
Category I
Eye Irritation — Category 2B
Respiratory Systemic Toxicity — Category 1
(Acute & Repeated Exposures)
NOTE: Severe respiratory toxicity will develop before skin or eye irritation go beyond listed categories.
Anyone with chronic pulmonary problems, especially asthma, should avoid exposure to ozone.
WHMIS Classifications (Workplace Hazardous Materials Information System, Canada)
D1A
Acute lethality — Very toxic, immediately
C
Oxidizing
D2A
Chronic Toxicity —Very Toxic
F
Dangerously Reactive
D2B
Muta enicit — Toxic
3. COMPOSITION
Chemical name Ozone
Common names Triatomic oxygen, trioxygen
Chemical Formula 03
CAS Registry Number 10028-15-6
Rev 5/1/2012
Page 2
4. FIRST AID MEASURES
Route of Entry
Symptoms
First Aid
Skin Contact
YES
Irritation
Rinse with water
Skin Absorption
NO
NA
NA
Eye Contact
YES
Irritation
Rinse with water, remove contacts
Ingestion
NO
NA
NA
Inhalation
YES
Headache, cough, dry throat, heavy
chest, shortness of breath
Remove to fresh air, provide
oxygen therapy as needed
For severe cases, or when symptoms don't improve, seek medical help.
5. FIRE FIGHTING MEASURES
While ozone itself is not flammable, it is a strong oxidant and may accelerate, even initiate, combustion, or
cause explosions. Use whatever extinguishing agents are indicated for burning materials.
6. ACCIDENTAL RELEASE MEASURES
Turn off ozone generator, and ventilate the area. Evacuate the area until ozone levels subside.
7. HANDLING AND STORAGE
Ozone must be contained within ozone -resistant tubing and pipes from the generation point to the
application point. Any leaks must be repaired before further use.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OSHA Permissible Exposure Limit: 8 hour Time Weighted Average 0.1 ppm
ANSFASTM: 8 hour TWA 0.1 ppm, Short Term Exposure Limit 0.3 ppm
ACGIH: 8 hour TWA 0.1 ppm; STEL 0.3 ppm
NIOSH: Exposure Limit Ceiling Value 0.1 ppm light; 0.08 ppm moderate; 0.05 ppm, heavy;
Light, moderate, heavy work TWA <= 2 hours, .2 ppm
Immediately Dangerous to Life or Health 5 ppm
Respiratory Protection: Use full face self-contained breathing apparatus for entering areas with
high concentration of ozone.
Engineering controls: use ozone destruct units (thermal and/or catalytic) for off gassing ozone.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state
Gas
pH
NA
Molecular Weight
48.0
Flash point
NA
Appearance
Clear at low concentrations, blue at
higher concentrations
Evaporation rate
NA
Odor
Distinctive pungent odor
Flammability
NA
Odor threshold
0.02 to 0.05 ppm; exposure
desensitizes
Explosive limits
NA
Rev 5/1/2012
Page 3
Melting point
-1930C/-315OF
Relative density
NA
Boiling point
-1 120C/- 1 690F
Partition coefficient
NA
Vapor pressure
> 1 atm
Auto -ignition temperature
NA
Vapor density
1.6 (air = 1)
Decomposition temperature
NA
Solubility in water
570 mg/L @20°C, 100% O3; 0.64
@0°C (Vol/Vol)
Viscosity
NA
10. STABILITY AND REACTIVITY
Ozone is highly unstable and highly reactive. Avoid contact with oxidizable substances, including alkenes,
benzene and other aromatic compounds, rubber, dicyanogen, bromine diethyl ether, dintrogen tetroxide,
nitrogen trichloride, hydrogen bromide, and tetraluorohydrazine. Ozone will readily react and spontaneously
decompose under normal ambient temperatures.
11. TOXICOLOGICAL INFORMATION
Likely routes of exposure: inhalation, eyes, skin exposure.
Effects of Acute Exposure: Discomfort, including headache, coughing, dry throat, shortness of breath, heavy
feeling in chest (including possible pulmonary edema/fluid in the lungs); higher levels of exposure intensify
symptoms. Irritation of skin and/or eyes is also possible.
Effects of Chronic Exposure: Similar to acute exposure effects, with possible development of chronic
breathing disorders, including asthma.
Inhalation Lc50: mice, 12.6 ppm for 3 hours; hamsters, 35.5 ppm for 3 hours
Irritancy of Ozone
YES
Sensitization to Ozone
NO
Carcinogenicity (NTP, IARC, OSHA)
NO
Reproductive Toxicity
Not Proven
Teratogenicity
Not Proven
Mutagenicity
Not Proven
Toxicologically Synergistic Products
Increase susceptibility to allergens, pathogens, irritants
12. ECOLOGICAL INFORMATION
The immediate surrounding area may be adversely affected by an ozone release, particularly plant life.
Discharge of ozone in water solution would also be harmful to any aquatic life. Due to natural decomposition,
bioaccumulation will not occur, and the area affected would be limited.
13. DISPOSAL CONSIDERATIONS
Off -gassing of ozone should be through an ozone destruct unit which uses heat and/or a catalyst to
accomplish the breakdown of ozone to oxygen before release into the atmosphere.
14. TRANSPORT INFORMATION
NOT APPLICABLE, as ozone is unstable and either reacts with other substances in the environment or
decomposes, and therefore must be generated at the location and time of use.
Rev 5/1/2012
Page 4
15. REGULATORY INFORMATION
SARA = Superfund Amendments and Renewal Act
SARA Title III Section 302 Extremely Hazardous Substance TPQ: 100 lbs.
SARA Title III Section 304, EHS RQ: 100 lbs.
SARA Title III Section 313: Ozone is reportable if more than 10,000 lbs. are used/year.
TPQ (Threshold Planning Quantity) requires emergency planning activities if this amount is
on site at any time during year
RQ (Reportable Quantity) requires any release of this amount into the environment to be
reported to the National Response Center
Source: EPA List of Lists
16.OTHER INFORMATION
The half-life of ozone is much shorter in water than in air. Increased temperature in either solvent
decreases the half-life. Published research indicates a half-life of 20 minutes for ozone dissolved in
water at 20°C, and a half-life of approximately 25 hours for ozone in dry air at 24°C (McClurkin &
Maier, 2010). The practical half-life time is actually less, especially in air, due to air circulation,
humidity, the presence of contaminants or walls with which to react, etc. In many situations, with
air movement, warmer temperatures, and normal relative humidity, the half-life of ozone in air
could be 1 hour or less. Further, ventilation of a closed space to other areas will also disperse the
ozone, so that concentration levels can rapidly decrease after generation ceases.
Source websites:
Canadian Centre for Occupational Health and Safety: Chemical Profiles: Ozone
http://www.ccohs.ca/oshanswers/chemicals/chem profiles/ozone/
Haz-Map: Occupational Exposure to Hazardous Agents: Ozone
htq2://hazmap.nlm.nih.gov/chi-bin/hazmap generic?tb1=Tb1Agents&id=68
International Chemical Safety Cards #0068: Ozone
http://www.cdc.gov/niosh/ipcsnen /g neng0068.html
NIOSH Pocket Guide to Chemical Hazards: Ozone http://www.cdc.gov/niosh/npR/npgd0476.html
United States National Library of Medicine ChemIDplus Lite: Ozone 10028-15-6
http://chem. sis.nlm.nih. gov/chemidplus/ProUServlet?obj ectHandle=DBMaint&actionHandle=de
fault&nextPaaee=j sp/chemidlite/ResultScreen. j sp&TXTSUPERLISTID=0010028156
Disclaimer: This information is provided in good faith, but makes no claim as to its
comprehensiveness or accuracy. It is intended solely as a guide for the safe handling of the
product by properly trained personnel, and makes no representations or warranties, express or
implied, of the merchantability or fitness of the product for any purpose.
SAFETY DATA SHEET
Hydrogen Peroxide (8 to 20%)
MSDS Ref. No.: 7722-84-1-2
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR
1910.1200 and Canada's Workplace Hazardous Materials Information System (WHMIS) requirements.
1. PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Hydrogen Peroxide (8 to 20%)
GENERAL USE: Standard 8% is formulated with an inorganic tin -based stabilizer for high stability
and long term storage. Suitable for industrial bleaching, processing, pollution
abatement and general oxidation reactions. Technical grade contains an organic
based stabilizer. It is particularly useful in chemical synthesis where the
presence of inorganic residues is objectionable.
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
E&C Chemicals, Inc. For leak, fire, spill, or accident emergencies, call:
211 Avenue C (800) 424-9300 (CHEMTREC - U.S.A.) (613) 996-6666
Carrollton, Georgia 30117 (CANUTEC - Canada)
Tel: (770) 834-6207
Fax: (770) 834-6277
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW: Clear, colorless, odorless liquid; Oxidizer.
Contact with combustibles may cause fire.
Decomposes yielding oxygen that supports combustion of organic matters and can
cause overpressure if confined.
Extremely irritating to eyes, nose, throat and lungs.
POTENTIAL HEALTH EFFECTS: Extremely irritating to eyes, nose, throat and lungs. May cause skin
irritation.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name
CAS#
Wt.%
EC No.
EC Class
Hydrogen Peroxide
7722-84-1
8 - 20
231-765-0
O, C, Xn; R5- R8-R35-R20/22
Water
7732-18-5
80 - 92
231-791-2
Not classified
4. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Flood with water.
FIRE / EXPLOSION HAZARDS: Product is non-combustible. On decomposition releases oxygen which may intensify fire.
FIRE FIGHTING PROCEDURES: Any tank or container surrounded by fire should be
flooded with water for cooling. Wear full protective clothing and self-contained breathing apparatus.
FLAMMABLE LIMITS: Non-combustible
SENSITIVITY TO IMPACT: No data available
SENSITIVITY TO STATIC DISCHARGE: No data available
Hydrogen Peroxide (8 to 20%) (7722-84-1-2)
Date: 06/03/2008
S. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Dilute with a large volume of water and hold in a pond or diked area until hydrogen peroxide
decomposes. Dispose according to methods outlined for waste disposal.
Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with large amounts
of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon
evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or
other combustibles can cause the material to ignite and result in a fire.
6. HANDLING AND STORAGE
HANDLING: Wear chemical splash -type monogoggles and full -face shield, impervious clothing, such as rubber, PVC, etc.,
and rubber or neoprene gloves and shoes. Avoid cotton, wool and leather. Avoid excessive heat and contamination.
Contamination may cause decomposition and generation of oxygen gas which could result in high pressures and possible
container rupture. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed
manner (see FMC Technical Bulletins). Never return unused hydrogen peroxide to original container, empty drums
should be triple rinsed with water before discarding. Utensils used for handling hydrogen peroxide should only be made
of glass, stainless steel, aluminum or plastic.
STORAGE: Store drums in cool areas out of direct sunlight and away from combustibles. For bulk storage refer to FMC
Technical Bulletins.
COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or
mist into the work environment.
7. EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS
Chemical Name
ACGIH
OSHA
Supplier
Hydrogen Peroxide
1 ppm (TWA)
1 ppm (PEL)
1.4 mg/m3 (PEL)
ENGINEERING CONTROLS: Ventilation should be provided to minimize the release of hydrogen peroxide vapors and
mists into the work environment. Spills should be minimized or confined immediately to prevent release into the work
area. Remove contaminated clothing immediately and wash before reuse.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: Use chemical splash -type monogoggles and a full -face shield made of polycarbonate, acetate,
polycarbonate/acetate, PETG or thermoplastic.
RESPIRATORY: If concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved self-contained breathing
apparatus (SCBA), or other approved atmospheric -supplied respirator (ASR) equipment (e.g., a full -face airline respirator
(ALR)). DO NOT use any form of air -purifying respirator (APR) or filtering facepiece (AKA dust mask), especially those
containing oxidizable sorbants such as activated carbon.
PROTECTIVE CLOTHING: Rubber or neoprene footwear (avoid leather). Impervious clothing materials such as rubber,
neoprene, nitrile or polyvinyl chloride (avoid cotton, wool and leather). Completely submerge hydrogen peroxide
contaminated clothing or other materials in water prior to drying. Residual hydrogen peroxide, if allowed to dry on
materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result
in a fire.
Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008
GLOVES: Liquid proof rubber or neoprene gloves. Thoroughly rinse the outside of gloves with water prior to removal.
Inspect regularly for leaks.
PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Odorless
APPEARANCE: Clear, colorless liquid
AUTOIGNITION TEMPERATURE: Non-combustible
BOILING POINT:102°C (216°F) (8% and 10%)
COEFFICIENT OF OIL / WATER: Not available
DENSITY / WEIGHT PER VOLUME: Not available
EVAPORATION RATE: > 1 (Butyl Acetate = 1)
FLASH POINT: Non-combustible
FREEZING POINT: -5*C (23*F) (8%); -6°C (21*F) (10%)
ODOR THRESHOLD: Not available
OXIDIZING PROPERTIES: Oxidizer
PERCENT VOLATILE: 100
pH: 2.5 - 3.5 5.0 - 6.0 (1% solution)
SOLUBILITY IN WATER: (in H2O % by wt) Above 1
SPECIFIC GRAVITY: (H2O=1) 1.06 @ 20°C/4°C (8%); 1.03 @ 20°C/4°C (10%)
VAPOR DENSITY: (Air = 1): Not available
VAPOR PRESSURE: 31 mmHg @ 30°C (8%); 30 mmHg @ 30°C (10%)
STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Excessive heat or contamination could cause
product to become unstable.
STABILITY: Stable (heat and contamination could cause decomposition)
POLYMERIZATION: Will not occur
INCOMPATIBLE MATERIALS: Reducing agents, wood, paper and other combustibles, iron and other heavy metals,
copper alloys and caustic.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen which supports combustion.
COMMENTS: Materials to Avoid : Dirt, organics, cyanides and combustibles such as wood, paper, oils, etc.
TOXICOLOGICAL INFORMATION
EYE EFFECTS: 8% hydrogen peroxide: Extremely irritating (washed) (rabbit) 8% hydrogen peroxide: Moderately irritating
(unwashed) (rabbit)
10% hydrogen peroxide: Extremely irritating (rabbit)
SKIN EFFECTS: 10% hydrogen peroxide: Slightly irritating after 4 hr. exposure (rabbit) [FMC Study Number: 189-1078]
DERMAL LD50: 35% hydrogen peroxide: > 2,000 mg/kg (rabbit) [FMC Study Number: 183-746] ORAL LD50: 10% hydrogen
peroxide: > 5,000 mg/kg (rat) [FMC Study Number: 189-1077] INHALATION LC50: 50% hydrogen peroxide: > 0.17 mg/I
(rat) [FMC Study Number: 189-1080] TARGET ORGANS: Eyes, nose, throat and lungs
ACUTE EFFECTS FROM OVEREXPOSURE: Extremely irritating to eyes, nose, throat and lungs. May cause skin irritation.
CHRONIC EFFECTS FROM OVEREXPOSURE: The International Agency for Research on Cancer (IARC) has concluded that
there is inadequate evidence for carcinogenicity of hydrogen peroxide in humans, but limited evidence in experimental
animals (Group 3 - not classifiable as to its carcinogenicity to humans). The American Conference of Governmental
Industrial Hygienists (ACGIH) has concluded that hydrogen peroxide is a 'Confirmed Animal Carcinogen with Unknown
Relevance to Humans' (A3).
10. CARCINOGENICITY:
Chemical Name
IIARC
INTP
JOSHA
Other
Hydrogen Peroxide
Not listed
Not listed
Not listed
(ACGIH) Listed (A3, Animal Carcinogen)
Hydrogen Peroxide (8 to 20%) (7722-84-1-2)
Date: 06/03/2008
11. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION: Channel catfish 96-hour LC50 = 37.4 mg/L
Fathead minnow 96-hour LC50 = 16.4 mg/L
Daphnia magna 24-hour EC50 = 7.7 mg/L
Daphnia pulex 48-hour LC50 = 2.4 mg/L
Freshwater snail 96-hour LC50 = 17.7 mg/L
For more information refer to ECETOC "Joint Assessment of Commodity Chemicals No. 22, Hydrogen
Peroxide." ISSN-0773-6339, January 1993
12. CHEMICAL FATE INFORMATION: Hydrogen peroxide in the aquatic environment is subject to various reduction
or oxidation processes and decomposes into water and oxygen. Hydrogen peroxide half-life in freshwater ranged from 8
hours to 20 days, in air from 10-20 hrs. and in soils from minutes to hours depending upon microbiological activity and
metal contaminants.
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: An acceptable method of disposal is to dilute with a large amount of water and allow the hydrogen
peroxide to decompose followed by discharge into a suitable treatment system in accordance with all regulatory
agencies. The appropriate regulatory agencies should be contacted prior to disposal.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
PROPER SHIPPING NAME: Hydrogen Peroxide, aqueous solutions with
not less than 8%, but less than 20% hydrogen peroxide
UN/NA NUMBER: UN 2984
PACKING GROUP: III
LABEL(S): Oxidizer
PLACARD(S): 5.1 (Oxidizer)
ADDITIONAL INFORMATION: DOT Marking: Hydrogen Peroxide,
aqueous solution with not less than 8%, but less than 20% Hydrogen Peroxide, UN 2984
Hazardous Substance/RQ: Not applicable 49 STCC Number: 4918689
DOT Spec: stainless steel/high purity aluminum cargo tanks and rail cars. UN Spec: HDPE drums. Contact FMC for specific
details.
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with
not less than 8%, but less than 20% peroxide.
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) / INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with
not less than 8%, but less than 20% peroxide(*).
OTHER INFORMATION:
(*) Air regulations permit shipment of Hydrogen Peroxide (8 - 20%) in non -vented containers for Air Cargo Only aircraft,
as well as for Passenger and Cargo aircraft. HOWEVER, all FMC Hydrogen Peroxide containers are vented and therefore,
air shipments of FMC H202 is not permitted. IATA air regulations state that venting of packages containing oxidizing
substances is not permitted for air transport. Protect from physical damage. Keep drums in upright position. Drums
should not be stacked in transit. Do not store drum on wooden pallets.
15. REGULATORY INFORMATION
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard
Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 Ibs; however, this product
contains the following ingredients with a TPQ of less than 10,000 lbs.: None, (conc. <52%)
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Unlisted (Hydrogen Peroxide 8-20%); RQ = 100
Ibs.; Ignitability
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA INVENTORY STATUS (40 CFR 710): Listed
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261): Waste Number: D001
CANADA
WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the
MSDS contains all the information required by the Controlled Products Regulations.
Hazard Classification / Division: C
D2B
Ingredient Disclosure List: Listed
Domestic Substance List: All components listed
INTERNATIONAL LISTINGS
Hydrogen peroxide:
China: Listed
Japan (ENCS): (1)-419
Korea: KE-20204
Philippines (PICCS): Listed
HAZARD AND RISK PHRASE DESCRIPTIONS:
EC Symbols: O (Oxidizer) C (Corrosive) Xn (Harmful)
EC Risk Phrases:RS (Heating may cause an explosion.)
R8 (Contact with combustible material may cause fire)
R35 (Causes severe burns.)
R20/22 (Harmful by inhalation and if swallowed.)
16. OTHER INFORMATION
HMIS
Health
1
Flammability
0
Physical Hazard
1
Personal Protection PPE
H
Protection = H (Safety goggles, gloves, apron, the use of a supplied air or SCBA respirator is required in lieu of a vapor
cartridge respirator)
HMIS = Hazardous Materials Identification System
Degree of Hazard Code:
4 = Severe
3 = Serious
2 = Moderate
1= Slight
0 = Minimal
NFPA
Health
1
Flammability
0
Reactivity
1
Special
OX
Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008
SPECIAL = OX (Oxidizer)
NFPA (National Fire Protection Association)
Degree of Hazard Code:
4 = Extreme
3 = High
2 = Moderate
1= Slight
0 = Insignificant
Disclaimer: This information is provided in good faith, but makes no claim as to its comprehensiveness or accuracy. It
is intended solely as a guide for the safe handling of the product by properly trained personnel, and makes no
representations or warranties, express or implied, of the merchantability or fitness of the product for any purpose.
REDQX TECH, LLC 40
"Providing Innovative Ira Silt( Soil and Grotrndivater Treatment"
Material Safety Data Sheet — Oxygen BioChem
1. Identification
Product identifier Oxygen Biochem (OBC)TM
Other means of identification Not available.
Recommended use Oxygen Biochem (OBC)TM is used to promote chemical oxidation and aerobic bioremediation of
petroleum compounds in groundwater.
Recommended restrictions Use in accordance with supplier's recommendations.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer/Supplier Redox Tech, LLC
Address 200 Quade Drive Cary
NC 2751
Telephone +1 919-6780140
E-mail haselow@redox-tech.com
Contact person Dr. John Haselowi
Emergency Telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTRECO, USA: 001 (800) 424-9300
CHEMTRECO, Mexico (Toll -Free - must be dialed from within country):
01-800-681-9531
CHEMTRECO, Other countries: 001 (703) 527-3887
2. Hazard(s) identification
Physical hazards Oxidizing solids Category 3
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Sensitization, respiratory Category 1
Sensitization, skin Category 1
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
OSHA defined hazards Not classified.
Label elements
< >< X >
Signal word Danger
Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Causes skin irritation. Causes serious eye
irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction. May cause respiratory irritation.
Precautionary statement
Prevention Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any
precaution to avoid mixing with combustibles. Wear protective gloves/eye protection/face
protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.
Avoid breathing dust/fume. In case of inadequate ventilation wear respiratory protection.
Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in a
well -ventilated area.
Response In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction. If swallowed: Call
a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If
skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and
wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention. If inhaled: If breathing is difficult, remove person to fresh air and keep
comfortable for breathing. If experiencing respiratory symptoms: Call a poison center/doctor.
Oxygen Biochem (OBC)T"" SDS US
920293 Version X 01 Revision date: - Issue date: 09-May-2014 1 / 7
Storage
Store in a well -ventilated place. Keep container tightly closed. Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
None known.
classified (HNOC)
3. Compositionlinformation on ingredients
Mixtures
Chemical name
CAS number %
Sodium persulfate
7775-27-1 70 - 90
Calcium peroxide
1305-79-9 10 - 20
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Move to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance. For
breathing difficulties, oxygen may be necessary. Call a physician or poison control center
immediately.
Skin contact
Remove and isolate contaminated clothing and shoes. For minor skin contact, avoid spreading
material on unaffected skin. Wash clothing separately before reuse. if skin irritation or an allergic
skin reaction develops, get medical attention.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion
Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs,
keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth
method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask
equipped with a one-way valve or other proper respiratory medical device. Get medical attention if
any discomfort continues.
Most important
May cause redness and pain. Symptoms may include coughing, difficulty breathing and shortness
symptoms/effects, acute and
of breath.
delayed
Indication of immediate
Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing None known.
media
Specific hazards arising from Contact with combustible material may cause fire.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire -fighting in the event of fire, cool tanks with water spray.
equipment/instructions
General fire hazards May intensify fire; oxidizer.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
emergency procedures or spilled material unless wearing appropriate protective clothing. Avoid skin contact and inhalation
of vapors during disposal of spills. Ventilate closed spaces before entering them. Local authorities
should be advised if significant spillages cannot be contained. For personal protection, see Section
8 of the SIDS.
Methods and materials for Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or
containment and cleaning up confined areas. Following product recovery, flush area with water. For waste disposal, see Section
13 of the SIDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
Oxygen Biochem (OBC)'" SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 2/7
7. Handling and storage
Precautions for safe handling Avoid inhalation of vapors/dust and contact with skin and eyes. Wash thoroughly after handling.
Keep away from clothing and other combustible materials. Use only with adequate ventilation. Do
not taste or swallow. Wear appropriate personal protective equipment (See Section 8). Observe
good industrial hygiene practices.
Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (See Section 10).
including any incompatibilities Keep locked up.
8. Exposure controls/personal protection
Occupational exposure limits
US. ACGIH Threshold Limit Values
Components Type Value
Sodium persulfate (CAS TWA 0.1 mg/m3
7775-27-1)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Observe occupational exposure limits and minimize the risk of exposure. Ensure adequate
controls ventilation, especially in confined areas.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear protective gloves.
Other
Neoprene or rubber gloves are recommended. Apron and long sleeves are recommended.
Respiratory protection
In the case of respirable dust, use self-contained breathing apparatus. Wear positive pressure
self-contained breathing apparatus (SCBA).
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
Always observe good personal hygiene measures, such as washing after handling the material
considerations
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Off-white, granular solid.
Physical state
Solid.
Form
Solid.
Color
Off-white.
Odor
Odorless.
Odor threshold
Not available.
pH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
11.7±0.4 (1-40% solution, slurry)
Not available.
Not applicable.
Not available.
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Vapor density
Relative density
Not applicable.
Not applicable.
2.76±0.16 (25°C)
Oxygen Biochem (OBC)T", SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 3/7
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanollwater)
Auto -ignition temperature
Decomposition temperature
Viscosity
Other information
Oxidizing properties
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Soluble in water.
Not available.
Not available.
Not available.
Not available,
Oxidizing.
The product is stable and non -reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with combustibles.
Combustible material. Oxidizing material. Reducing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion Harmful if swallowed.
Inhalation May cause irritation to the respiratory system.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Symptoms related to the May cause redness and pain. Exposed individuals may experience eye tearing, redness, and
physical, chemical and discomfort. Symptoms may include coughing, difficulty breathing and shortness of breath.
toxicological characteristics
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Skin corrosion/irritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
Chronic effects
Further information
12. Ecological information
Causes skin irritation.
Causes serious eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
No data available.
This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
No data available.
May cause respiratory irritation.
No data available.
Not applicable.
Prolonged exposure may cause chronic effects.
No data available.
Ecotoxicity This product's components are not classified as environmentally hazardous. However, this does
not exclude the possibility that large or frequent spills can have a harmful or damaging effect on
the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available for this product.
Oxygen Biochem (OBC)TM SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 4 17
Mobility in soil Not available.
Other adverse effects No data available.
13. Disposal considerations
Disposal instructions Consult authorities before disposal. Dispose in accordance with all applicable regulations.
Hazardous waste code The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues 1 unused Dispose of in accordance with local regulations.
products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT
UN number
UN1479
UN proper shipping name
Oxidizing solid, n.o.s. (Sodium persulfate)
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Packing group
II
Environmental hazards
Marine pollutant
No
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling,
Special provisions
62, I135, IP1
Packaging exceptions
None
Packaging non bulk
211
Packaging bulk
242
IATA
UN number
UN1479
UN proper shipping name
Oxidizing solid, n.o.s. (Sodium persulfate, Calcium peroxide)
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Label(s)
5.1
Packing group
II
Environmental hazards
No
ERG Code
5L
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
IMDG
UN number
UN1479
UN proper shipping name
OXIDIZING SOLID, N.O.S. (Sodium persulfate, Calcium peroxide)
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Label(s)
5.1
Packing group
II
Environmental hazards
Marine pollutant
No
EmS
F-A, S-Q
Special precautions for user
Read safety instructions, SIDS and emergency procedures before handling.
Transport in bulk according to
This product is not intended to be transported in bulk.
Annex II of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
Oxygen Biochem (OBC)I-' SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 5/7
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Calcium peroxide (CAS 1305-79-9)
Sodium persulfate (CAS 7775-27-1)
US. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yeslno)k
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada
Domestic Substances List (DSL)
Yes
Canada
Non -Domestic Substances List (NDSL)
No
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of Existing Commercial Chemical
Yes
Substances (EINECS)
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Yes
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances
Yes
(PICCS)
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
"A "Yes" indicates this product complies
with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more
components of the product are not listed or exempt from listing on the inventory administered
by the governing
country(s)
Oxygen Biochem (OBC)TM SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 6/7
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
Further information
NFPA Ratings
09-May-2014
01
HMISO is a registered trade and service mark of the NPCA.
List of abbreviations NFPA: National Fire Protection Association.
References Registry of Toxic Effects of Chemical Substances (RTECS)
HSDBO - Hazardous Substances Data Bank
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation.
Oxygen Biochem (OBC)TM SIDS US
920293 Version #: 01 Revision date: - Issue date: 09-May-2014 7/7