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HomeMy WebLinkAboutWI0400561_Permit (Issuance)_20210111NC Department of Environmental Quality — Division of Water Resources (DWR) NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are `permitted by rule" and do not require an individualpermit when constructed in accordance with the rules of I5A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS (15A NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (15A NCAC 02C .02251 or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells is located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. 5) In -Situ Thermal Wells (IST) — Used to `heat' contaminated groundwater to enhance remediation Print Clearly or Type Information. Illegible Submittals Will Be Returned as Incomplete. DATE: December 29 , 2020_ PERMIT NO. W 10400561 (to be filled in by DWR) NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g., different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the previously assigned permit tracking number and any needed relevant information to assess and approve injection: Permit No. Issued Date: A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well.......................................Complete sections B through F, J, M (2) Aquifer Test Well.......................................Complete sections B through F, J, M (3) Passive Injection System...............................Complete sections B through F, H-M (4) Small -Scale Injection Operation ......................Complete sections B through M (5) X Pilot Test.................................................Complete sections B through M (6) In -Situ Thermal (IST) Well...........................Complete all sections except K B. STATUS OF WELL OWNER: Business/Organization Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 1 C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): Gandhi & Associates, Inc c/o Dilip Gandhi Mailing Address: 9201 Leesville Road, Suite 201 City: Raleigh State: NC_ Zip Code: 27613 County: Wake Day Tele No.: 919-781-5269 Cell No.: 919-810-5122 EMAIL Address:gandi1O@msn.com Fax No.: 919-443-1475 D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: same as well Company Name _ Mailing Address: City: Day Tele No.: State Zip Code: Cell No.: EMAIL Address: Fax No.: E. PROJECT CONTACT (Typically Environmental Consulting/Engineering Firm) Name and Title: Aaron D. Springer, Environmental Scientist F. G. Company Name Agra Environmental, Mailing Address: PO Box 5611 City: State: NC_ Zip Code: 27512 Day Tele No.: 919-858-5350 EMAIL Address:aspringer@agraenvironmental.com PHYSICAL LOCATION OF WELL SITE Cell No. County: County: Wake 336-596-1350 Fax No.: 919-858-5351 (1) Facility Name & Address: UST Incident #44564 Eagle Food Mart 2 3767 Boy Wood Road City: Graham County. Alamance Zip Code: 27253 (2) Geographic Coordinates: Latitude": "or 36 0. 00554 Longitude": it or 79 0. 3909 Reference Datum: Accuracy: Method of Collection: Goojzle Earth "FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. TREATMENT AREA Land surface area of contaminant plume: 16,200 square feet Land surface area of inj. well network: 628 square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated: 3.9 (must be < 5% of plume for pilot test injections) Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 2 0 I. J. 1N INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE — Provide a brief narrative regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity: Pilot test iniection for Corrective Action Feasibilitv studv as reauested by NC DEO DWM UST Section to assess remedial technologies for UST Incident #44564. Ozone and hydrogen peroxide will be injected into existing groundwater monitoring well MW-2 continuously over 5 day period. Oxygen BioChem (OBC) will injected into 4 DPT injection wells centered around MW-10. WELL CONSTRUCTION DATA (1) No. of injection wells: 4 Proposed 1 Existing (provide NC Well Construction Record (GW-1) for each well) (2) Appx. injection depths (BLS): 14-32 ft for DPT 17-37 for MW2 (3) For Proposed wells or Existing wells not having GW-ls, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number INJECTION SUMMARY NOTE: Onlv iniectants annroved by the enidemioloQv section of the NC Division ofPublic Health. Department of Health and Human Services can be injected. Approved injectants can be found online at http: Hdeq.nc. gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info ifvou wish to get annroval for a different additive. However. please note it may take 3 months or longer. Injectant: Ozone (6%) Total Amt. to be injected (gal)/event: Injectant: Hagen Peroxide (8%)_Total Amt. to be injected (gal)/event: 250 gal Injectant: Oxygen BioChem (OBC)Total Amt. to be injected (gal)/event: 400 Ibs Injectant: Total Amt. to be injected (gal)/event: Injectant: Total Amt. to be injected (gal)/event: Deemed Permitted GW Remediation NOI Rev. 2-14-2020 Page 3 L. lid Amt. Water to be injected (gal/event): Total Amt. to be injected (gal/event): 1,000 gal No. of separate injection events: Est. Total Amt. to be injected (gal): Source of Water (if applicable): Ci1y of Graham Public Works MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. Monitoring wells MW-1 MW-2 NM-4 MW-6 MW-7 MW-10 MW-11 MW-12 and VE-1 will be sample 60 days following conclusion of the pilot test activities and quarterly/biannually quarterly/biannuallythereafter at the request of the NC DEQ DWM UST Section. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/Applicant: "I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility offines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the I5A NCAC 02C 0200 Rules. " Signature of Applicant Print or Type Full Name and Title Property Owner (if the property is not owned by the Well Owner/Applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection wells) conform to the Well Construction Standards (15A NCAC 02C . 0200). " "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the abser ct of gontrary agreement in writing. Z L t F 6A-0Dki o, Signature* of Pro rty w er (if different from applicant) Print or Type Vull Name and Title *An access agreement betty e the applicant andproperty owner may be submitted in lieu of a signature on this form. Please send I (one) hard color copy of this NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 707-9000 Deemed Permitted GW Remediation N01 Rev. 2-14-2020 Page 4 cYt 61 Aaron D Springer From: Lepard, Mindy <mindy.lepard@ncdenr.gov> Sent: Wednesday, July 15, 2020 5:27 PM To: Aaron Springer Cc: rbshah@agraenvironmental.com Subject: RE: [External] RE: 44564 - Eagle Food Mart 2 May 18, 2020 MRP Aaron, This site was discussed with the Trust Fund. The next step will be a feasibility study that includes the results of pilot tests for the injections recommended in the latest report. The pilot tests proposed in the discussion were limited events of ozone/hydrogen peroxide injection in MW-2 and OBC in MW-10. All monitoring wells should be sampled 60 days after the pilot tests. Make sure the lab analyzes for oxygenates, including tert-butyl alcohol. The other oxygenates were included in the lab results in the latest report but TBA was not. We also discussed installing another vertical extent well at the edge of the property in line with SW-2. The well construction information for SW-2 will need to be obtained first. This may require using a camera to find the fractures in the bedrock that feed the water supply well. The specialty drilling task can be used for investigating SW-2. Please let me know if you have any questions. Thanks, Mindy Nimdy Lepard I{yc�ogeo:o¢is� �.'T��'ecliox� e`DE��j� Nol#h Cwolulma Department of F -moommud Quallty �'' 336-776.96S6 (Office) Mindy.Legard mdenr_¢ov guy hc} c#��(biF# bo fhrd�r�s ----------------------------------- ** Important Message" ------------------------------------------------------------------ Until further notice, all UST Section "deliverables/documents" (letters, reports, recorded NRPs etc.) must be submitted electronically to the appropriate Incident Manager (See below for County Assignments and Contact Information). If a document is too large to send via email, please upload the document onto the Division of Waste Management FTP site. Follow the upload with an email notifying the Incident Manager of the document's presence on the FTP server. Contact the appropriate Incident Manager for FTP instructions. Please provide a responsible party email address with each submittal, if available. COUNTYASSIGNMENTS (Subject to Change. Check List Freauentiv): Guilford County: Gene Mao (336-641-3589) Ashley Dinkins (336-641-5557) Christina Schroeter: Ashe and Forsyth (336-776-9683) Mindy Lepard: Alamance and Surry (336-776-9686) Linda Estkowski: Caswell, Davie, Rockingham, Stokes, Watauga, Yadkin (336-996-9680) Doug Whitmire: Allegheny, Davidson, Randolph, Wilkes (336-776-9685) Karen Hall: All counties and phases through an LSA, Complaints and Spills (336-776-9681) Shelia McIntosh: File Reviews (336-776-9630) ALL UST ARCHIVED FILES CAN BE FOUND ON THE FOLLOWING LINK: fts://deq.nc.gov/about/divisions/waste-management/laserfiche DWM LOCATOR TOOL: USE MAP FOR LOCATING UST SITES ACROSS THE STATE: https: //ncdenr. maps. arc,gis. com/apps/webappviewer/index.html?id=7dd59be2750b4Obebebfa49fc3 83 f68 8 r- 00 U Z ® MW-14® MW-13 ' MW-9 MW-12 I® 0 MW-15 VEW-2 ff Brush f� f► 1 fJ Woods M W-5 ® 1 I � IP-1 IP-2 MW-6 MW-4 Eta Eta MW-11 ® VEW-1 0 0 0:W-10 1 IP-3 IP-4 1 M W-2 Direct injection of MW-7 Concrete f� 03 and H2O2 M W-1 I I MW 8® Store (vacant) I I I ff Asphalt f� M W-3 Canopy I Asphalt S Grass •—— Property Line Il 11 f Grass J� _------------- Boy Wood Road Map Key ® Shallow Monitoring Well • Deep Monitoring Well Water Supply Well Former USTs • DPT Temporary Injection Point Approximate Ozone/Peroxide and OBC A.. Environmental, Scale Injection Pilot Test — Injection 1 inch = 50 feet Point Locations P.O. Box 5611, Cary, NC 27512 Eagle Food Mart 2 — 3767 Boy Wood Road Drawn Checked Figure 1 Graham, Alamance County, NC By. ADS By. RBS r, 00 U Z ------------- Boy Wood Road Approximate Scale 1 inch = 50 feet Figure 3 Shallow Potentiometric Map April 2020 Eagle Food Mart 2 — 3767 Boy Wood Road Graham, Alamance County, NC 81.75 81.5 81.25 80.75 r 80.75 1 I 81 I� MW-15 81.01 81.2i I 81.5 1 I 1 I I I I I I I 1 Map Key ® Shallow Monitoring Well • Deep Monitoring Well Water Supply Well Former USTs /V Groundwater Contour Groundwater Flow Direction P.O. Box 5611, Cary, NC 27512 Drawn ADS Checked RBS Bv: Bv: r- 00 U Z MW-14® ® BDL MW-13 BDL _ _ _,_,_._._._. 1 I M W-9 1 1 BDL MW- ® 1 i ® 3. MW-15 EW-2 1 BDL Brush f� BDL ♦� fJ Woods 1 1 MW-S ' ®BDL 1 I MW-6 MW-4 — MW -I W-iU ♦ -11 I 1 1.80 VEW-1 0.930 ♦ i BDL ® �11 ® 500 µg/L® 1 I ' I M W -1 100 µg/L , 1 ®O 2L = 1 µg/L 1 I �' MW-7 ®BDL , Con cret�J -R/I 2-1 1 D I M W -8 ® 1 BDL Store (vacant) , I ff Asphalt J� I ' MW-3 1 • Canopy BDL Asphalt S Q 1 G ra ss , �1 Property Line `I Ma Ke -------------- Boy Wood Road Approximate Scale I inch = 50 feet Figure 7 Benzene Isoconcentration Map April 2020 Eagle Food Mart 2 — 3767 Boy Wood Road Graham, Alamance County, NC ® Shallow Monitoring Well Deep Monitoring Well AL Water Supply Well Former USTs — — Benzene Isocontour 2L Standard Isocontour(1pg/L) P.O. Box 5611, Cary, NC 27512 Drawn ADS Checked RBS Bv: Bv: B BDL 1.00 By 100' MW-8 DISPENSER BASIN VEW-1 MW-12 BDL 100' M W-14 90' — n 90' ` 80' � ` 70` — — —70' 2L=1 rb, 60' 60' 50'— 50' 40' 2L=1 µg/L 40' 30'— 30' 20'— 20' 10' 10' 0 0' Legend Approximate Scale Geologic Cross -Section B-B' A' ra 1 inch = 40 feet Benzene Isoconcentration Eagle Food Mart 2 - 3767 Boy Wood Road P.O. Box 5611, Cary, NC 27512 Graham, Alamance County, NC Figure 9 Drawn ADS Checked RBS ec - Red -Brown to Orange -Tan, Silt with Varying Clay/Sand Content BDL Below Detection Limit - Tan, Silt with Varying Clay/Sand/Weathered Rock Content 1.80 Benzene Concentration 4/21/2020 (pg/L) Mostly Competent Rock — — — Benzene Isocontour - Remedial Excavation —Gravel and Soil Backfill NCAC 15A 2L Benzene Groundwater Standard (1 pg/L) ® Monitoring Well Screened Interval UST Incident 44564 Eagle Food Mart 2 3767 Boy Wood Road, Graham, Alamance County, NC Existing Injection Well Information (Ozone/Hydrogen Peroxide Injection) Well Type Monitoring Well ID MW-2 Install Date Unknown Well Diameter 2 inch Depth of Casing 17 feet Depth of Screen 32 feet Proposed Injection Well Information (OBC Injection) Well Type Temporary Borehole* Tooling Geoprobe/DPT with Injection Tip Tooling Depth of Casing BGS N/A Each Grout Type and Depth N/A Depth of Sand Pack BGS N/A Treatment Zone BGS 14-32 feet Treatment Intervals 2 feet Well Contractor Name TBD Well Contractor Certification # TBD *Injection point boreholes to be abandoned with bentonite following removal of tooling. Surface to be restored to match pre-existing. Rev 5/1/2012 Page 1 SAFETY DATA SHEET for OZONE (Formerly MSDS) 1. PRODUCT IDENTIFICATION Product Name: Ozone Common Names/Synonyms: Triatomic Oxygen, Trioxygen, 03 Ozone Generator Manufacturer/Supplier: Pacific Ozone 6160 Egret Court Benicia, CA 94510 p: 707-747-9600 f. 707-747-9209 Product Use: This SDS is limited to ozone produced in gaseous form on site by an ozone generator, in varying concentrations in either air or aqueous solution, for the purposes of odor abatement, oxidation of organic compounds, or antimicrobial intervention, in a variety of applications, from food processing to ground water remediation. 2. HAZARD IDENTIFICATION 4� 40� <$� GHS Classifications: Physical Hazards Health Hazards Environmental Hazards Oxidizing Gas Skin Irritation — Category 3 Acute Aquatic Toxicity — Category I Eye Irritation — Category 2B Respiratory Systemic Toxicity — Category 1 (Acute & Repeated Exposures) NOTE: Severe respiratory toxicity will develop before skin or eye irritation go beyond listed categories. Anyone with chronic pulmonary problems, especially asthma, should avoid exposure to ozone. WHMIS Classifications (Workplace Hazardous Materials Information System, Canada) D1A Acute lethality — Very toxic, immediately C Oxidizing D2A Chronic Toxicity —Very Toxic F Dangerously Reactive D2B Muta enicit — Toxic 3. COMPOSITION Chemical name Ozone Common names Triatomic oxygen, trioxygen Chemical Formula 03 CAS Registry Number 10028-15-6 Rev 5/1/2012 Page 2 4. FIRST AID MEASURES Route of Entry Symptoms First Aid Skin Contact YES Irritation Rinse with water Skin Absorption NO NA NA Eye Contact YES Irritation Rinse with water, remove contacts Ingestion NO NA NA Inhalation YES Headache, cough, dry throat, heavy chest, shortness of breath Remove to fresh air, provide oxygen therapy as needed For severe cases, or when symptoms don't improve, seek medical help. 5. FIRE FIGHTING MEASURES While ozone itself is not flammable, it is a strong oxidant and may accelerate, even initiate, combustion, or cause explosions. Use whatever extinguishing agents are indicated for burning materials. 6. ACCIDENTAL RELEASE MEASURES Turn off ozone generator, and ventilate the area. Evacuate the area until ozone levels subside. 7. HANDLING AND STORAGE Ozone must be contained within ozone -resistant tubing and pipes from the generation point to the application point. Any leaks must be repaired before further use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA Permissible Exposure Limit: 8 hour Time Weighted Average 0.1 ppm ANSFASTM: 8 hour TWA 0.1 ppm, Short Term Exposure Limit 0.3 ppm ACGIH: 8 hour TWA 0.1 ppm; STEL 0.3 ppm NIOSH: Exposure Limit Ceiling Value 0.1 ppm light; 0.08 ppm moderate; 0.05 ppm, heavy; Light, moderate, heavy work TWA <= 2 hours, .2 ppm Immediately Dangerous to Life or Health 5 ppm Respiratory Protection: Use full face self-contained breathing apparatus for entering areas with high concentration of ozone. Engineering controls: use ozone destruct units (thermal and/or catalytic) for off gassing ozone. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Gas pH NA Molecular Weight 48.0 Flash point NA Appearance Clear at low concentrations, blue at higher concentrations Evaporation rate NA Odor Distinctive pungent odor Flammability NA Odor threshold 0.02 to 0.05 ppm; exposure desensitizes Explosive limits NA Rev 5/1/2012 Page 3 Melting point -1930C/-315OF Relative density NA Boiling point -1 120C/- 1 690F Partition coefficient NA Vapor pressure > 1 atm Auto -ignition temperature NA Vapor density 1.6 (air = 1) Decomposition temperature NA Solubility in water 570 mg/L @20°C, 100% O3; 0.64 @0°C (Vol/Vol) Viscosity NA 10. STABILITY AND REACTIVITY Ozone is highly unstable and highly reactive. Avoid contact with oxidizable substances, including alkenes, benzene and other aromatic compounds, rubber, dicyanogen, bromine diethyl ether, dintrogen tetroxide, nitrogen trichloride, hydrogen bromide, and tetraluorohydrazine. Ozone will readily react and spontaneously decompose under normal ambient temperatures. 11. TOXICOLOGICAL INFORMATION Likely routes of exposure: inhalation, eyes, skin exposure. Effects of Acute Exposure: Discomfort, including headache, coughing, dry throat, shortness of breath, heavy feeling in chest (including possible pulmonary edema/fluid in the lungs); higher levels of exposure intensify symptoms. Irritation of skin and/or eyes is also possible. Effects of Chronic Exposure: Similar to acute exposure effects, with possible development of chronic breathing disorders, including asthma. Inhalation Lc50: mice, 12.6 ppm for 3 hours; hamsters, 35.5 ppm for 3 hours Irritancy of Ozone YES Sensitization to Ozone NO Carcinogenicity (NTP, IARC, OSHA) NO Reproductive Toxicity Not Proven Teratogenicity Not Proven Mutagenicity Not Proven Toxicologically Synergistic Products Increase susceptibility to allergens, pathogens, irritants 12. ECOLOGICAL INFORMATION The immediate surrounding area may be adversely affected by an ozone release, particularly plant life. Discharge of ozone in water solution would also be harmful to any aquatic life. Due to natural decomposition, bioaccumulation will not occur, and the area affected would be limited. 13. DISPOSAL CONSIDERATIONS Off -gassing of ozone should be through an ozone destruct unit which uses heat and/or a catalyst to accomplish the breakdown of ozone to oxygen before release into the atmosphere. 14. TRANSPORT INFORMATION NOT APPLICABLE, as ozone is unstable and either reacts with other substances in the environment or decomposes, and therefore must be generated at the location and time of use. Rev 5/1/2012 Page 4 15. REGULATORY INFORMATION SARA = Superfund Amendments and Renewal Act SARA Title III Section 302 Extremely Hazardous Substance TPQ: 100 lbs. SARA Title III Section 304, EHS RQ: 100 lbs. SARA Title III Section 313: Ozone is reportable if more than 10,000 lbs. are used/year. TPQ (Threshold Planning Quantity) requires emergency planning activities if this amount is on site at any time during year RQ (Reportable Quantity) requires any release of this amount into the environment to be reported to the National Response Center Source: EPA List of Lists 16.OTHER INFORMATION The half-life of ozone is much shorter in water than in air. Increased temperature in either solvent decreases the half-life. Published research indicates a half-life of 20 minutes for ozone dissolved in water at 20°C, and a half-life of approximately 25 hours for ozone in dry air at 24°C (McClurkin & Maier, 2010). The practical half-life time is actually less, especially in air, due to air circulation, humidity, the presence of contaminants or walls with which to react, etc. In many situations, with air movement, warmer temperatures, and normal relative humidity, the half-life of ozone in air could be 1 hour or less. Further, ventilation of a closed space to other areas will also disperse the ozone, so that concentration levels can rapidly decrease after generation ceases. Source websites: Canadian Centre for Occupational Health and Safety: Chemical Profiles: Ozone http://www.ccohs.ca/oshanswers/chemicals/chem profiles/ozone/ Haz-Map: Occupational Exposure to Hazardous Agents: Ozone htq2://hazmap.nlm.nih.gov/chi-bin/hazmap generic?tb1=Tb1Agents&id=68 International Chemical Safety Cards #0068: Ozone http://www.cdc.gov/niosh/ipcsnen /g neng0068.html NIOSH Pocket Guide to Chemical Hazards: Ozone http://www.cdc.gov/niosh/npR/npgd0476.html United States National Library of Medicine ChemIDplus Lite: Ozone 10028-15-6 http://chem. sis.nlm.nih. gov/chemidplus/ProUServlet?obj ectHandle=DBMaint&actionHandle=de fault&nextPaaee=j sp/chemidlite/ResultScreen. j sp&TXTSUPERLISTID=0010028156 Disclaimer: This information is provided in good faith, but makes no claim as to its comprehensiveness or accuracy. It is intended solely as a guide for the safe handling of the product by properly trained personnel, and makes no representations or warranties, express or implied, of the merchantability or fitness of the product for any purpose. SAFETY DATA SHEET Hydrogen Peroxide (8 to 20%) MSDS Ref. No.: 7722-84-1-2 This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200 and Canada's Workplace Hazardous Materials Information System (WHMIS) requirements. 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Hydrogen Peroxide (8 to 20%) GENERAL USE: Standard 8% is formulated with an inorganic tin -based stabilizer for high stability and long term storage. Suitable for industrial bleaching, processing, pollution abatement and general oxidation reactions. Technical grade contains an organic based stabilizer. It is particularly useful in chemical synthesis where the presence of inorganic residues is objectionable. MANUFACTURER EMERGENCY TELEPHONE NUMBERS E&C Chemicals, Inc. For leak, fire, spill, or accident emergencies, call: 211 Avenue C (800) 424-9300 (CHEMTREC - U.S.A.) (613) 996-6666 Carrollton, Georgia 30117 (CANUTEC - Canada) Tel: (770) 834-6207 Fax: (770) 834-6277 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Clear, colorless, odorless liquid; Oxidizer. Contact with combustibles may cause fire. Decomposes yielding oxygen that supports combustion of organic matters and can cause overpressure if confined. Extremely irritating to eyes, nose, throat and lungs. POTENTIAL HEALTH EFFECTS: Extremely irritating to eyes, nose, throat and lungs. May cause skin irritation. 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# Wt.% EC No. EC Class Hydrogen Peroxide 7722-84-1 8 - 20 231-765-0 O, C, Xn; R5- R8-R35-R20/22 Water 7732-18-5 80 - 92 231-791-2 Not classified 4. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: Flood with water. FIRE / EXPLOSION HAZARDS: Product is non-combustible. On decomposition releases oxygen which may intensify fire. FIRE FIGHTING PROCEDURES: Any tank or container surrounded by fire should be flooded with water for cooling. Wear full protective clothing and self-contained breathing apparatus. FLAMMABLE LIMITS: Non-combustible SENSITIVITY TO IMPACT: No data available SENSITIVITY TO STATIC DISCHARGE: No data available Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 S. ACCIDENTAL RELEASE MEASURES RELEASE NOTES: Dilute with a large volume of water and hold in a pond or diked area until hydrogen peroxide decomposes. Dispose according to methods outlined for waste disposal. Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire. 6. HANDLING AND STORAGE HANDLING: Wear chemical splash -type monogoggles and full -face shield, impervious clothing, such as rubber, PVC, etc., and rubber or neoprene gloves and shoes. Avoid cotton, wool and leather. Avoid excessive heat and contamination. Contamination may cause decomposition and generation of oxygen gas which could result in high pressures and possible container rupture. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed manner (see FMC Technical Bulletins). Never return unused hydrogen peroxide to original container, empty drums should be triple rinsed with water before discarding. Utensils used for handling hydrogen peroxide should only be made of glass, stainless steel, aluminum or plastic. STORAGE: Store drums in cool areas out of direct sunlight and away from combustibles. For bulk storage refer to FMC Technical Bulletins. COMMENTS: VENTILATION: Provide mechanical general and/or local exhaust ventilation to prevent release of vapor or mist into the work environment. 7. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMITS Chemical Name ACGIH OSHA Supplier Hydrogen Peroxide 1 ppm (TWA) 1 ppm (PEL) 1.4 mg/m3 (PEL) ENGINEERING CONTROLS: Ventilation should be provided to minimize the release of hydrogen peroxide vapors and mists into the work environment. Spills should be minimized or confined immediately to prevent release into the work area. Remove contaminated clothing immediately and wash before reuse. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Use chemical splash -type monogoggles and a full -face shield made of polycarbonate, acetate, polycarbonate/acetate, PETG or thermoplastic. RESPIRATORY: If concentrations in excess of 10 ppm are expected, use NIOSH/DHHS approved self-contained breathing apparatus (SCBA), or other approved atmospheric -supplied respirator (ASR) equipment (e.g., a full -face airline respirator (ALR)). DO NOT use any form of air -purifying respirator (APR) or filtering facepiece (AKA dust mask), especially those containing oxidizable sorbants such as activated carbon. PROTECTIVE CLOTHING: Rubber or neoprene footwear (avoid leather). Impervious clothing materials such as rubber, neoprene, nitrile or polyvinyl chloride (avoid cotton, wool and leather). Completely submerge hydrogen peroxide contaminated clothing or other materials in water prior to drying. Residual hydrogen peroxide, if allowed to dry on materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in a fire. Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 GLOVES: Liquid proof rubber or neoprene gloves. Thoroughly rinse the outside of gloves with water prior to removal. Inspect regularly for leaks. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Odorless APPEARANCE: Clear, colorless liquid AUTOIGNITION TEMPERATURE: Non-combustible BOILING POINT:102°C (216°F) (8% and 10%) COEFFICIENT OF OIL / WATER: Not available DENSITY / WEIGHT PER VOLUME: Not available EVAPORATION RATE: > 1 (Butyl Acetate = 1) FLASH POINT: Non-combustible FREEZING POINT: -5*C (23*F) (8%); -6°C (21*F) (10%) ODOR THRESHOLD: Not available OXIDIZING PROPERTIES: Oxidizer PERCENT VOLATILE: 100 pH: 2.5 - 3.5 5.0 - 6.0 (1% solution) SOLUBILITY IN WATER: (in H2O % by wt) Above 1 SPECIFIC GRAVITY: (H2O=1) 1.06 @ 20°C/4°C (8%); 1.03 @ 20°C/4°C (10%) VAPOR DENSITY: (Air = 1): Not available VAPOR PRESSURE: 31 mmHg @ 30°C (8%); 30 mmHg @ 30°C (10%) STABILITY AND REACTIVITY CONDITIONS TO AVOID: Excessive heat or contamination could cause product to become unstable. STABILITY: Stable (heat and contamination could cause decomposition) POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: Reducing agents, wood, paper and other combustibles, iron and other heavy metals, copper alloys and caustic. HAZARDOUS DECOMPOSITION PRODUCTS: Oxygen which supports combustion. COMMENTS: Materials to Avoid : Dirt, organics, cyanides and combustibles such as wood, paper, oils, etc. TOXICOLOGICAL INFORMATION EYE EFFECTS: 8% hydrogen peroxide: Extremely irritating (washed) (rabbit) 8% hydrogen peroxide: Moderately irritating (unwashed) (rabbit) 10% hydrogen peroxide: Extremely irritating (rabbit) SKIN EFFECTS: 10% hydrogen peroxide: Slightly irritating after 4 hr. exposure (rabbit) [FMC Study Number: 189-1078] DERMAL LD50: 35% hydrogen peroxide: > 2,000 mg/kg (rabbit) [FMC Study Number: 183-746] ORAL LD50: 10% hydrogen peroxide: > 5,000 mg/kg (rat) [FMC Study Number: 189-1077] INHALATION LC50: 50% hydrogen peroxide: > 0.17 mg/I (rat) [FMC Study Number: 189-1080] TARGET ORGANS: Eyes, nose, throat and lungs ACUTE EFFECTS FROM OVEREXPOSURE: Extremely irritating to eyes, nose, throat and lungs. May cause skin irritation. CHRONIC EFFECTS FROM OVEREXPOSURE: The International Agency for Research on Cancer (IARC) has concluded that there is inadequate evidence for carcinogenicity of hydrogen peroxide in humans, but limited evidence in experimental animals (Group 3 - not classifiable as to its carcinogenicity to humans). The American Conference of Governmental Industrial Hygienists (ACGIH) has concluded that hydrogen peroxide is a 'Confirmed Animal Carcinogen with Unknown Relevance to Humans' (A3). 10. CARCINOGENICITY: Chemical Name IIARC INTP JOSHA Other Hydrogen Peroxide Not listed Not listed Not listed (ACGIH) Listed (A3, Animal Carcinogen) Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 11. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: Channel catfish 96-hour LC50 = 37.4 mg/L Fathead minnow 96-hour LC50 = 16.4 mg/L Daphnia magna 24-hour EC50 = 7.7 mg/L Daphnia pulex 48-hour LC50 = 2.4 mg/L Freshwater snail 96-hour LC50 = 17.7 mg/L For more information refer to ECETOC "Joint Assessment of Commodity Chemicals No. 22, Hydrogen Peroxide." ISSN-0773-6339, January 1993 12. CHEMICAL FATE INFORMATION: Hydrogen peroxide in the aquatic environment is subject to various reduction or oxidation processes and decomposes into water and oxygen. Hydrogen peroxide half-life in freshwater ranged from 8 hours to 20 days, in air from 10-20 hrs. and in soils from minutes to hours depending upon microbiological activity and metal contaminants. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: An acceptable method of disposal is to dilute with a large amount of water and allow the hydrogen peroxide to decompose followed by discharge into a suitable treatment system in accordance with all regulatory agencies. The appropriate regulatory agencies should be contacted prior to disposal. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) PROPER SHIPPING NAME: Hydrogen Peroxide, aqueous solutions with not less than 8%, but less than 20% hydrogen peroxide UN/NA NUMBER: UN 2984 PACKING GROUP: III LABEL(S): Oxidizer PLACARD(S): 5.1 (Oxidizer) ADDITIONAL INFORMATION: DOT Marking: Hydrogen Peroxide, aqueous solution with not less than 8%, but less than 20% Hydrogen Peroxide, UN 2984 Hazardous Substance/RQ: Not applicable 49 STCC Number: 4918689 DOT Spec: stainless steel/high purity aluminum cargo tanks and rail cars. UN Spec: HDPE drums. Contact FMC for specific details. INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG) PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with not less than 8%, but less than 20% peroxide. INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) / INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA) PROPER SHIPPING NAME: Hydrogen peroxide, aqueous solution with not less than 8%, but less than 20% peroxide(*). OTHER INFORMATION: (*) Air regulations permit shipment of Hydrogen Peroxide (8 - 20%) in non -vented containers for Air Cargo Only aircraft, as well as for Passenger and Cargo aircraft. HOWEVER, all FMC Hydrogen Peroxide containers are vented and therefore, air shipments of FMC H202 is not permitted. IATA air regulations state that venting of packages containing oxidizing substances is not permitted for air transport. Protect from physical damage. Keep drums in upright position. Drums should not be stacked in transit. Do not store drum on wooden pallets. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A): Not listed SECTION 311 HAZARD CATEGORIES (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370): The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 Ibs; however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.: None, (conc. <52%) CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT) CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Unlisted (Hydrogen Peroxide 8-20%); RQ = 100 Ibs.; Ignitability TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA INVENTORY STATUS (40 CFR 710): Listed RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) RCRA IDENTIFICATION OF HAZARDOUS WASTE (40 CFR 261): Waste Number: D001 CANADA WHMIS (WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM): This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Hazard Classification / Division: C D2B Ingredient Disclosure List: Listed Domestic Substance List: All components listed INTERNATIONAL LISTINGS Hydrogen peroxide: China: Listed Japan (ENCS): (1)-419 Korea: KE-20204 Philippines (PICCS): Listed HAZARD AND RISK PHRASE DESCRIPTIONS: EC Symbols: O (Oxidizer) C (Corrosive) Xn (Harmful) EC Risk Phrases:RS (Heating may cause an explosion.) R8 (Contact with combustible material may cause fire) R35 (Causes severe burns.) R20/22 (Harmful by inhalation and if swallowed.) 16. OTHER INFORMATION HMIS Health 1 Flammability 0 Physical Hazard 1 Personal Protection PPE H Protection = H (Safety goggles, gloves, apron, the use of a supplied air or SCBA respirator is required in lieu of a vapor cartridge respirator) HMIS = Hazardous Materials Identification System Degree of Hazard Code: 4 = Severe 3 = Serious 2 = Moderate 1= Slight 0 = Minimal NFPA Health 1 Flammability 0 Reactivity 1 Special OX Hydrogen Peroxide (8 to 20%) (7722-84-1-2) Date: 06/03/2008 SPECIAL = OX (Oxidizer) NFPA (National Fire Protection Association) Degree of Hazard Code: 4 = Extreme 3 = High 2 = Moderate 1= Slight 0 = Insignificant Disclaimer: This information is provided in good faith, but makes no claim as to its comprehensiveness or accuracy. It is intended solely as a guide for the safe handling of the product by properly trained personnel, and makes no representations or warranties, express or implied, of the merchantability or fitness of the product for any purpose. REDQX TECH, LLC 40 "Providing Innovative Ira Silt( Soil and Grotrndivater Treatment" Material Safety Data Sheet — Oxygen BioChem 1. Identification Product identifier Oxygen Biochem (OBC)TM Other means of identification Not available. Recommended use Oxygen Biochem (OBC)TM is used to promote chemical oxidation and aerobic bioremediation of petroleum compounds in groundwater. Recommended restrictions Use in accordance with supplier's recommendations. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier Redox Tech, LLC Address 200 Quade Drive Cary NC 2751 Telephone +1 919-6780140 E-mail haselow@redox-tech.com Contact person Dr. John Haselowi Emergency Telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY (spill, leak, fire, exposure or accident), call CHEMTREC at CHEMTRECO, USA: 001 (800) 424-9300 CHEMTRECO, Mexico (Toll -Free - must be dialed from within country): 01-800-681-9531 CHEMTRECO, Other countries: 001 (703) 527-3887 2. Hazard(s) identification Physical hazards Oxidizing solids Category 3 Health hazards Acute toxicity, oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Sensitization, respiratory Category 1 Sensitization, skin Category 1 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation OSHA defined hazards Not classified. Label elements < >< X > Signal word Danger Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. Precautionary statement Prevention Keep away from heat. Keep/Store away from clothing and other combustible materials. Take any precaution to avoid mixing with combustibles. Wear protective gloves/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume. In case of inadequate ventilation wear respiratory protection. Contaminated work clothing must not be allowed out of the workplace. Use only outdoors or in a well -ventilated area. Response In case of fire: Use foam, carbon dioxide, dry powder or water fog for extinction. If swallowed: Call a poison center/doctor if you feel unwell. Rinse mouth. If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a poison center/doctor. Oxygen Biochem (OBC)T"" SDS US 920293 Version X 01 Revision date: - Issue date: 09-May-2014 1 / 7 Storage Store in a well -ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) 3. Compositionlinformation on ingredients Mixtures Chemical name CAS number % Sodium persulfate 7775-27-1 70 - 90 Calcium peroxide 1305-79-9 10 - 20 Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First -aid measures Inhalation Move to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance. For breathing difficulties, oxygen may be necessary. Call a physician or poison control center immediately. Skin contact Remove and isolate contaminated clothing and shoes. For minor skin contact, avoid spreading material on unaffected skin. Wash clothing separately before reuse. if skin irritation or an allergic skin reaction develops, get medical attention. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Get medical attention if any discomfort continues. Most important May cause redness and pain. Symptoms may include coughing, difficulty breathing and shortness symptoms/effects, acute and of breath. delayed Indication of immediate Provide general supportive measures and treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire -fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing None known. media Specific hazards arising from Contact with combustible material may cause fire. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire -fighting in the event of fire, cool tanks with water spray. equipment/instructions General fire hazards May intensify fire; oxidizer. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear protective equipment and appropriate protective equipment and clothing during clean-up. Do not touch damaged containers emergency procedures or spilled material unless wearing appropriate protective clothing. Avoid skin contact and inhalation of vapors during disposal of spills. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see Section 8 of the SIDS. Methods and materials for Stop the flow of material, if this is without risk. Prevent entry into waterways, sewer, basements or containment and cleaning up confined areas. Following product recovery, flush area with water. For waste disposal, see Section 13 of the SIDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Oxygen Biochem (OBC)'" SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 2/7 7. Handling and storage Precautions for safe handling Avoid inhalation of vapors/dust and contact with skin and eyes. Wash thoroughly after handling. Keep away from clothing and other combustible materials. Use only with adequate ventilation. Do not taste or swallow. Wear appropriate personal protective equipment (See Section 8). Observe good industrial hygiene practices. Conditions for safe storage, Store in original tightly closed container. Store away from incompatible materials (See Section 10). including any incompatibilities Keep locked up. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Type Value Sodium persulfate (CAS TWA 0.1 mg/m3 7775-27-1) Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Observe occupational exposure limits and minimize the risk of exposure. Ensure adequate controls ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves. Other Neoprene or rubber gloves are recommended. Apron and long sleeves are recommended. Respiratory protection In the case of respirable dust, use self-contained breathing apparatus. Wear positive pressure self-contained breathing apparatus (SCBA). Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Off-white, granular solid. Physical state Solid. Form Solid. Color Off-white. Odor Odorless. Odor threshold Not available. pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate 11.7±0.4 (1-40% solution, slurry) Not available. Not applicable. Not available. Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure Vapor density Relative density Not applicable. Not applicable. 2.76±0.16 (25°C) Oxygen Biochem (OBC)T", SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 3/7 Solubility(ies) Solubility (water) Partition coefficient (n-octanollwater) Auto -ignition temperature Decomposition temperature Viscosity Other information Oxidizing properties 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Soluble in water. Not available. Not available. Not available. Not available, Oxidizing. The product is stable and non -reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. No dangerous reaction known under conditions of normal use. Contact with combustibles. Combustible material. Oxidizing material. Reducing agents. No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Harmful if swallowed. Inhalation May cause irritation to the respiratory system. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Symptoms related to the May cause redness and pain. Exposed individuals may experience eye tearing, redness, and physical, chemical and discomfort. Symptoms may include coughing, difficulty breathing and shortness of breath. toxicological characteristics Information on toxicological effects Acute toxicity Harmful if swallowed. Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information 12. Ecological information Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. No data available. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. No data available. May cause respiratory irritation. No data available. Not applicable. Prolonged exposure may cause chronic effects. No data available. Ecotoxicity This product's components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available for this product. Oxygen Biochem (OBC)TM SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 4 17 Mobility in soil Not available. Other adverse effects No data available. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Dispose in accordance with all applicable regulations. Hazardous waste code The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues 1 unused Dispose of in accordance with local regulations. products Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. Transport information DOT UN number UN1479 UN proper shipping name Oxidizing solid, n.o.s. (Sodium persulfate) Transport hazard class(es) Class 5.1 Subsidiary risk - Packing group II Environmental hazards Marine pollutant No Special precautions for user Read safety instructions, SIDS and emergency procedures before handling, Special provisions 62, I135, IP1 Packaging exceptions None Packaging non bulk 211 Packaging bulk 242 IATA UN number UN1479 UN proper shipping name Oxidizing solid, n.o.s. (Sodium persulfate, Calcium peroxide) Transport hazard class(es) Class 5.1 Subsidiary risk - Label(s) 5.1 Packing group II Environmental hazards No ERG Code 5L Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. IMDG UN number UN1479 UN proper shipping name OXIDIZING SOLID, N.O.S. (Sodium persulfate, Calcium peroxide) Transport hazard class(es) Class 5.1 Subsidiary risk - Label(s) 5.1 Packing group II Environmental hazards Marine pollutant No EmS F-A, S-Q Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. Transport in bulk according to This product is not intended to be transported in bulk. Annex II of MARPOL 73178 and the IBC Code 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. Oxygen Biochem (OBC)I-' SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 5/7 US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Not regulated. US. New Jersey Worker and Community Right -to -Know Act Calcium peroxide (CAS 1305-79-9) Sodium persulfate (CAS 7775-27-1) US. Pennsylvania Worker and Community Right -to -Know Law Not listed. US. Rhode Island RTK Not regulated. US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. International Inventories Country(s) or region Inventory name On inventory (yeslno)k Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List (DSL) Yes Canada Non -Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes "A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s) Oxygen Biochem (OBC)TM SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 6/7 16. Other information, including date of preparation or last revision Issue date Revision date Version # Further information NFPA Ratings 09-May-2014 01 HMISO is a registered trade and service mark of the NPCA. List of abbreviations NFPA: National Fire Protection Association. References Registry of Toxic Effects of Chemical Substances (RTECS) HSDBO - Hazardous Substances Data Bank Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety standards and government regulations are subject to change and, therefore, holders and users should satisfy themselves that they are aware of all current data and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user of the product. (Carus and design) is a registered service mark of Carus Corporation. Oxygen Biochem (OBC)TM SIDS US 920293 Version #: 01 Revision date: - Issue date: 09-May-2014 7/7