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HomeMy WebLinkAboutAdvanced Plating Tech_Regional Office Historical File Pre 2018DEC 2 2010 N(, Dr-t:i 'o ProfeHion lw� 11-5ge a— oof x 14 oc�y 411; FILE NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary October 11, 2010 Advanced Plating Technologies 2600 Stitt Street Monroe, North Carolina 28110 Attention: Mike Hanson RE: Notice of Regulatory Requirements NCAC 2T .1003(1) and NCAC 2T .1008(1) Closed Loop Recycle System AdvPlating Facility, Monroe Union County Dear Mr. Hanson: Chapter 143, North Carolina General Statutes, authorizes and directs the Environmental Management commission of the Department of Environment and Natural Resources to protect and preserve the water and air resources of the State. The Division of Water Quality has the delegated authority to enforce adopted pollution control rules. The purpose of this letter is to advise you of your responsibilities regarding the operation of the closed loop recycle system at your facility. Based on a recent telephone conversation between Mr. Baker of your company and staff of this office, your system is considered deemed permitted by regulation (ie. does not require an individual permit) because under NCAC 2T .1003(1), it fits the following description: • Return of wastewater is contained under roof within an industrial or commercial process where there is no anticipated release of wastewater • No earthen basins are used • The facility has developed a spill control plan in the event of a release However, NCAC 2T .1008 also requires that a Residuals Management Plan be maintained for all systems that generate residuals. The plan must include a detailed explanation as to how the residuals will be collected, handled, processed, stored and disposed of. Disposal records, as descibed in your plan, must be retained on -site for five years. Within 60 days, please submit a copy of your Residuals Management Plan to this office. Since some of the residuals are stored outside the building on the loading dock, please include a copy of your spill control plan. Should you have any questions, please call me at 704/663-1699 ext. 2180 or contact me via email at an drew. pitner(a).ncdenr.gov. MAF/advplating Itr 10-8-10 Mooresville Regional Office Location: 610 East Center Ave., Suite 301 Mooresville, NC 28115 Phone: (704) 663-16991 Fax: (704) 663-60401 Customer Service: 1-877-623-6748 Internet: www.ncwaterquality.org An Equal Opportunity 1 Affirmative Action Employer- 50% Recycled/10% Post Consumer paper Sin erely, Andrew Pitner, P.G. Regional Environmental Supervisor Aquifer Protection Section NorthCarohna Natumllry NC DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT HAZARDOUS WASTE SECTION NCDENR ACTIVITY REPORT Date: 9/9/10 Reported by: Mark Burnette ESS Subject: AdvPlating (Advanced Plating Technologies) Name of Company or person in violation Location: 2600 Stitt Street Site address City: Monroe County: Union Zip Code: 28110 Contact Person: Robert Parker Plating Engineer Mike Hanson Owner (Owner, Operator, Manager, other) Reason for Visit: Inspection (CEO Report: On July 15, 2010 a site visit was conducted at AdvPlating to conduct an inspection. The facility is not listed with the State as a hazardous waste generator, and has never been inspected by the Section. Upon arrival to the site a short meeting was conducted with Mr. Parker to discuss the intent of the site visit. Since the facility is not registered as a generator, the contact was questioned about the waste generation procedure and processes. It was discovered that the facility only conducts electroless nickel plating. The waste generated is tested and used at a pH of 4.8-5 when spent, then the facility adjusts it to get it's pH to 6.5-7. The waste and related material is processed through a wastewater treatment system on -site which is closed loop. The filtered water is reused in a tank and the reclaimed sludge is disposed of as non -hazardous waste. A walk-thru was conducted to see what type of processes and waste storage was being used. The facility had approximately 150 fifty-five gallon containers inside the facility that were either already processed sludge or sludge awaiting processing. Additionally, there were approximately 87 fifty-five gallon containers on the back loading dock. The main area of concern was a large area of dead vegetation that appeared to be caused by the spilling or dumping of some material or waste from the loading dock area. The facility contact did not know the source of the spill or what material was spilled. (see below) Dock area with dead vegetation in background Drum storage on dock Copies of manifests were received on July 19, 2010 and reviewed. The waste shipped is described as Filter Cake Non Hazardous/Non Regulated. It is sent to ABM -American Bio Mass in Walterboro, South Carolina. On July 20, 2010 Mr. Mike Hanson was contacted to follow-up on the dead vegetation issue. He stated that he thinks it is from phosphates and he is collecting samples to be analyzed by the county's Department of Agriculture. He stated that the results should be available by July 30tn Information was submitted which included a soil analysis conducted through the Agriculture Extension Agency in Union County. The results showed the soil levels were high in nitrogen and phosphorus levels. The Ag Extension Agency suggested planting a cover crop of buckwheat to help adjust the pH and Potassium. While the analysis did not reveal any hazardous issues, there are some issues related to groundwater and soils that may need to be addressed. Activity type: Complaint (04) Used oil (UOI) (Circle One) Technical Assistance (CAV) Sampling (SPQ Comprehensive evaluation (CEI)Compliance schedule (CSE) Case development (CDI) Finley, Peggy From: Pitner, Andrew Sent: Friday, September 10, 2010 12:01 PM To: Finley, Peggy Subject: FW: Advplating referral -Union CO Attachments: advplating.cei.fy10.doc; advplating.referral. doc; DSC06252.JPG; DSC06253.JPG It sounds like this might be a problem at what could be a deemed permitted facility. Another email to follow... From: Burnette, Mark Sent: Friday, September 10, 2010 11:32 AM To: Pitner, Andrew Cc: Burch, Brent Subject: Advplating referral -Union CO Andrew, Attached is a referral and report for a site I did an investigation at in Monroe where something leaked and killed a lot of vegetation behind the building. It is not hazardous waste but thought you may be interested. Let me know if you have questions, )Kar4 A. $wrhatte Environmental Senior Specialist PO Box 2481 Indian Trail, NC 28079 704-776-4780 mark.burnette@ncdenr.gov ***************************************************************************** NOTICE: E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties by an authorized state official. ***************************************************************************** ALYI-IWA Via NCDENR North Carolina Department of Environment and Natural Resources Michael F. Easley, Governor Division of Waste Management Hazardous Waste Section 9/9/ 10 To: Groundwater/DWM Water Quality/DWM Air Quality/DAQ OSHA Through: Brent Burch Compliance Branch Supervisor Hazardous Waste Section From: Mark Burnette Environmental Senior Specialist Hazardous Waste Section RE: Referral of. Advanced Plating Tech. 2600 Stitt Street Monroe, NC 28110 Owner- Mike Hanson William G. Ross Jr., Secretary Solid Waste Superfund Inactive Sites X Other Aquifer Protection` `E-Z-P� (40 Attached is information regarding the above site. After review, it has been determined that at this time, the hazardous waste regulations (RCRA) do/ do not apply to this site. However, our review did indicate that site conditions might warrant a review by your office. Consequently, we respectfully refer this site to your section for consideration. Attachment cc: Mike Williford Central Files MRO Files SFP 1 3 2010 s7 [J', VQ - At;t!i#c:r Protecti 919 North Main Street, Mooresville, North Carolina 28115 .��. Phone: 704-663-16991 FAX: 704-663-60401 Internet: www.enr.state.nc.us An Equal opportunity/ Affirmative Action Employer - 50 % Recycled 110 % Post Consumer Paper pppppp— NCDENR Date: 9/9/10 Subject NC DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT HAZARDOUS WASTE SECTION ACTIVITY REPORT Reported by: Name of Company or person r .14 � P 1 3 2010 Location: 2600 Stitt Street " Site address City: Monroe County: Union Zip Code: 28110 DWO _ Aquifer Protection Contact Person: Robert Parker Plating Engineer, Mike Hanson, Owner (Owner, Operator, Manager, other) Reason for Visit: Inspection (CEI) Report: On July 15, 2010 a site visit was conducted at AdvPlating to conduct an inspection. The facility is not listed with the State as a hazardous waste generator, and has never been inspected by the Section. Upon arrival to the site a short meeting was conducted with Mr. Parker to discuss the intent of the site visit. Since the facility is not registered as a generator, the contact was questioned about the waste generation procedure and processes. It was discovered that the facility only conducts electroless nickel plating. The waste generated is tested and used at a pH of 4.8-5 when spent, then the facility adjusts it to get it's pH to 6.5-7. The waste and related material is processed through a wastewater treatment system on -site which is closed loop. The filtered water is reused in a tank and the reclaimed sludge is disposed of as non -hazardous waste. A walk-thru was conducted to see what type of processes and waste storage was being used. The facility had approximately 150 fifty-five gallon containers inside the facility that were either already processed sludge or sludge awaiting processing. Additionally, there were approximately 87 fifty-five gallon containers on the back loading dock. The main area of concern was a large area of dead vegetation that appeared to be caused by the spilling or dumping of some material or waste from the loading dock area. The facility contact did not know the source of the spill or what material was spilled. (see below) Dock area with dead vegetation in background Drum storage on dock Copies of manifests were received on July 19, 2010 and reviewed. The waste shipped is described as Filter Cake Non Hazardous/Non Regulated. It is sent to ABM -American Bio Mass in Walterboro, South Carolina. On rpppp"- July 20, 2010 Mr. Mike Hanson was contacted to follow-up on the dead vegetation issue. He stated that he thinks it is from phosphates and he is collecting samples to be analyzed by the county's Department of Agriculture. He stated that the results should be available by July 30t1, Information was submitted which included a soil analysis conducted through the Agriculture Extension Agency in Union County. The results showed the soil levels were high in nitrogen and phosphorus levels. The Ag Extension Agency suggested planting a cover crop of buckwheat to help adjust the pH and Potassium. While the analysis did not reveal any hazardous issues, there are some issues related to groundwater and soils that may need to be addressed. Activity type: Complaint (04) Used oil (UOI) (Circle One) Technical Assistance (CAV) Sampling (SPQ Comprehensive evaluation (CEI)Compliance schedule (CSE) Case development (CDI) pppl0pipo- 03:19P FROM:ADVANCED PLATING TEC 7042961-335 TO:7047764780 P.2/2 From Advanced Plating Tech. Inc. Soil test performed by Robert Parker. 8/10/10 Testing of soil sample was done using Mosser Lee Soil Test Kit purchased @ Lowe's. Test kit included Ph, Nitrogen, Phosphorus, and Potassium. Results were as follows: Ph 6.0 to 7.0 . Nitrogen High low to Medium. Phosphorus Medium. Potassium - Medium. Upon review with the Agricultural Extension Agency, they recommended a cover crop of Buckwheat to adjust to conditions of Ph and Potassium. A test sample of soil was taken and placed in peat cups with buckwheat seeds placed in each cup . The seeds germinated and sprouted in 7/8 days and started to grow. NOTE: Our facility plates only Electroless Nickel which does not generate any hazardous waste. Also we plate for the food industry and arc an NSF approved facility. We are obligated not to have any hazardous materials in house. Our nickel solutions are also Rollas compliant. See cert. Attached. Robert Parker T 2600 Stitt st 28110 - Google Maps Page 1 of 1 Address 2600 Stitt St Goc a maps Monroe, NC 28110 Get Google Maps on your phone 49 Text the word GMAPS"to466453 � a Brave q � • , c 46 8 y It 14 Stwecsids l.^ o W 5 Je H WafkupAve p � Z tN Walkup pve p $ Tan rrnacle S% Christian schow 011s" ll $� a L csso^ St D "1 ■ Q we o � t)�z5, ~ ygft51 Sri"St snh St i ■ '7 Mont; MI I _ Tyson Foods �� ■ $ cp Metav c 3er --' 74 swnosonst L!l PPI"r" Est 02010 Google - Map data 02010 .ogle.com/maps?f=q&source=s_q&hl=en&geocode=&q=2600+Stitt+st+281... 9/ 10/2010 MONITORING REPORT(MR) VIOLATIONS for: Report Date 02r1e/10 Page 5of20 Permit: °S MRs Between 9 and Region: Mooresville Violation Category: Limit Violation Program Category: NPDES WW Facility Name: % Param Name: % County: °i Subbasin: Violation Action: Major Minor: °/c PERMIT: NCO071528 FACILITY: Lake Norman Woods Homeowners Association - Lake COUNTY: Catawba REGION: Mooresville Norman Woods WWTP Limit Violation . / \ MONITORI G OUTFACE / VI TION UNIT OF CALCULATED REPOR PPI L ATION PARAMETE D E FREQUENCY MEASURE LIMIT VALUE VIOLATION TYPE VIOLATION ACTION 03 -2 9 001 Efflue Chi Total Residual 03/09/09 2 ugh 28 Daily Maximum Exceeded No Action, BPV PERMIT: NCO027197 FACILITY: City of Shelby - Shelby WTP Limit Violation MONITORING OUTFALL / REPORT PPI LOCATION PARAMETER 03 -2009 CONV000137 Coliform, Total MF, Immed,LES Endo Agar 03 -2009 CONV000660 Arsenic, Total (as As) 03 -2009 CONV000660 Coliform, Total MF, Immed,LES Endo Agar 03 -2009 CONVO01177 Coliform, Total MF, Immed,LES Endo Agar 03 -2009 CONVO05607 Coliform, Total MF, Immed,LES Endo Agar COUNTY: Cleveland REGION: Mooresville VIOLATION UNIT OF CALCULATED DATE FREQUENCY MEASURE LIMIT VALUE VIOLATION TYPE VIOLATION ACTION 03/31/09 3 X year #/100ml 1 133.4 Limit Exceeded None 03/31/09 3 X year mg/I 0.01 0.08 Limit Exceeded None 03/31/09 3 X year #/100ml 1 313 Limit Exceeded None 03/31/09 3 X year #/100ml 1 151.5 Limit Exceeded None 03/31/09 3 X year #/100ml 1 410.6 Limit Exceeded None 2600 Stitt st 28110 - Google Maps Page 1 of 1 Google maps Address To see all the details that are visible on the screen, use the "Print' link next to the map. Get Directions My Map Print Send Link http://maps.google.com/maps?hl=en&tab=wl 9/10/2010 CM Well Diameter Mullinlientinn Fnctnr• 1 0.0408 aceAnalXical 1.5 Lrzs Mroso a.ON 3' 0.1630 0.3670 4 0.6530 G 1.4680 +8 i.croo GROUNDWATER SAMPLING FIELD DATA SHEET Client:_�D�t�t/�Op'r LocatioirfL�� �IJ /�/L Project ep Name/#: Name & Affiliation (Sampler(s): C f 4<A- Name & Affiliation (Inspector): ' Well Information Well ID:_ I Uen Well Locked: yes Well Diameter: Construction Steel . Stainless 1 Total Well Depth: ft. /ulti. Factor": ius/12)2 X 3.14 x 7.481 Depth to Product: . 4 Product Thicknes ft. Static Water Lev ft. Casing V e: AIW gallons Height of Water Col.: ft. Volumes: gallons Pu un Date Prged: Time Start: Finish: Purge Rate: Purging Method: Total Volume Purged: gallons _Sampling Information Date Sample Collected:_,'7K/..Zo f o Q' Time Sample Collected: /„i : a C am pm Sampling Equipment Used:- Bottle Type Preservation Analysis Required 3-VoY Q Yo-A /-(CL . . 951-6c) Field Measurements/Observations Sample Temp. (OC):_ a I • ?2 Time: A a :d-0 Turbidity (ntu): J Time: Sample pH (s.u.): -7.1 Time: . ao Dis. Oxy. (mg/L)• S o Time: I a* as Specific Cond. (uS): Go Time: la -ego Res. Cl (mg/L): — Time: ReDox (mV): 7- — Time: Other: Time: Odor: NoIVE Appearance: — cfe"a-t — General Observations: Weather Conditions: 4-&-1 d '�IL BS°F S716 /o k,,pb W j Vp SS Sampler S Stabilization Test Date: 0 8 o / 09 Time Purged pH (s.u.) Spec. Cond. (US) Redox. (mV) Turbidity ntu Dissolved Oxy. (mg/L) Temp. ("C) Volume Removed (gals.) Other North Carolina Michael F. Easley, Governor ApT � llllllll; W 0. NCDENR Department of Environment and Division of Waste Management Hazardous Waste Section 9/9/ 10 To: Groundwater/D WM Water Quality/DWM Air Quality/DAQ OSHA Through: Brent Burch Compliance Branch Supervisor Hazardous Waste Section From: Mark Burnette Environmental Senior Specialist Hazardous Waste Section RE: Referral of: Advanced Plating Tech. 2600 Stitt Street Monroe, NC 28110 Owner- Mike Hanson Natural Resources William G. Ross Jr., Secretary Solid Waste Superfund Inactive Sites X Other Aquifer Protection Attached is information regarding the above site. After review, it has been determined that at this time, the hazardous waste regulations (RCRA) do/ do not apply to this site. However, our review did indicate that site conditions might warrant a review by your office. Consequently, we respectfully refer this site to your section for consideration. Attachment cc: Mike Williford Central Files MRO Files 919 North Main Street, Mooresville, North Carolina 28115 Phone: 704-663-16991 FAX: 704-663-60401 Internet: www.enr.state.nc.us An Equal Opportunity/ Affirmative Action Employer - 50 % Recycled l 10 % Post Consumer Paper Electroless nickel plating - Wikipedia, the free encyclopedia Page 1 of 4 Electroless nickel plating From Wikipedia, the free encyclopedia Electroless nickel plating (EN) is an auto -catalytic chemical technique used to deposit a layer of nickel -phosphorus or nickel -boron alloy on a solid workpiece, such as metals or plastic. The process relies on the presence of a reducing agent, for example hydrated sodium hypophosphite (NaP02H2•H20) which reacts with the metal ions to deposit metal. The alloys with different percentage of phosphorus, ranging from 2-5 (low phosphorus) to up to 11-14 (high phosphorus) are possible. The metallurgical properties of alloys depend on the percentage of phosphorus. Contents ■ 1 Overview ■ 2 Pretreatment ■ 3 Advantages and disadvantages ■ 4 Types ■ 4.1 Low phosphorus electroless nickel ■ 4.2 Medium phosphorus electroless nickel ■ 4.3 High phosphorus electroless nickel ■ 5 Applications ■ 6 Standards ■ 7 See also ■ 8 References Overview Electroless nickel plating is an auto -catalytic reaction used to deposit a coating of nickel on a substrate. Unlike electroplating, it is not necessary to pass an electric current through the solution to form a deposit. This plating technique is to prevent corrosion and wear. EN techniques can also be used to manufacture composite coatings by suspending powder in the bath. Electroless nickel plating has several advantages versus electroplating. Free from flux -density and power supply issues, it provides an even deposit regardless of workpiece geometry, and with the proper pre -plate catalyst, can deposit on non-conductive surfaces. Pretreatment Before performing electroless nickel plating, the material to be plated must be cleaned by a series of cleaning chemicals such as bases and acids, this process is called the pre-treatment process. Failure to remove unwanted "soils" from the part's surface would result in poor plating. Each pre-treatment chemical must be followed by water rinsing (normally two to three times) to remove the chemical that adheres to the surface. De greasing removes oils from surface; acid cleaning removes scaling. Activation is done with a weak acid etch, or nickel strike, or, in the case of non-metallic substrate, a proprietary solution. After the plating process, plated materials must be finished with an anti -oxidation or anti - tarnish chemical (trisodium phosphate or chromate) and pure water rinsing to prevent unwanted stains. The rinsing materials must then be completely dried off or sometimes baked off to obtain the full http://en.wikipedia.org[wiki/Electroless nickel_plating 9/15/2010 Electroless nickel plating - Wikipedia, the free encyclopedia Page 2 of 4 hardness of the plating film. The pre-treatment required for the deposition of nickel and cobalt on a non-conductive surface usually consists of an initial surface preparation to render the substrate hydrophillic. Following this initial step, the surface is activated by a solution of a noble metal, e.g., palladium chloride. Silver nitrate is also successfully used for activating ABS and other plastics. Electroless bath formation varies with the activator. The substrate is now ready for nickel deposition.Ic"a"O" needed] Advantages and disadvantages Advantages include: 1. Does not use electrical power. 2. Even coating on parts surface can be achieved. 3. No sophisticated jigs or racks are required. 4. There is flexibility in plating volume and thickness. 5. The process can plate recesses and blind holes with stable thickness. 6. Chemical replenishment can be monitored automatically. 7. Complex filtration method is not required 8. Matte, Semi Bright or Bright finishes can be obtained. Disadvantages include: 1. Lifespan of chemicals is limited. 2. Waste treatment cost is high due to the speedy chemical renewal. Each type of electroless nickel also has particular advantages depending on the application and type of nickel alloy.111 Types Low phosphorus electroless nickel 1. Hard deposits 2. Very uniform thickness 3. Excellent corrosion resistance in alkaline environments Medium phosphorus electroless nickel 1. Very bright and semi -bright options 2. High speed deposit rate 3. Very stable 4. Used for Slurry Disposal Industries 5. The most common type of electroless nickel applied High phosphorus electroless nickel 1. Superior corrosion protection 2. Excellent acid resistance [2] http://en.wikipedia.org/wiki/Electroless_nickel_plating 9/15/2010 Electroless nickel plating - Wikipedia, the free encyclopedia Page 3 of 4 3. Lower porosity 4. Non-magnetic 5. Less prone to staining 6. Pit -free deposits Applications The most common form of electroless nickel plating produces a nickel phosphorus alloy coating. The phosphorus content in electroless nickel coatings can range from 2% to 13%.111 It is commonly used in engineering coating applications where wear resistance, hardness and corrosion protection are required. Applications include oil field valves, rotors, drive shafts, paper handling equipment, fuel rails, optical surfaces for diamond turning, door knobs, kitchen utensils, bathroom fixtures, electrical/mechanical tools and office equipment. It is also commonly used as a coating in electronics printed circuit board manufacturing, typically with an overlay of gold to prevent corrosion. This process is known as electroless nickel immersion gold. Due to the high hardness of the coating it can be used to salvage worn parts. Coatings of 25 to 100 micrometres can be applied and machined back to final dimensions. Its uniform deposition profile mean it can be applied to complex components not readily suited to other hard wearing coatings like hard chromium. It is also used extensively in the manufacture of hard disk drives, as a way of providing an atomically smooth coating to the aluminium disks, the magnetic layers are then deposited on top of this film, usually by sputtering and finishing with protective carbon and lubrication layers; these final two layers protect the underlying magnetic layer (media layer) from damage should the read / write head lose its cushion of air and contact the surface. Its use in the automotive industry for wear resistance has increased significantly, however it is important to recognise that only EOLVD or RoHS compliant process types (free from heavy metal stabilizers) may be used for these applications. Standards ■ AMS-2404 . AMS-C-26074 ■ ASTM B-733 ■ ASTM-B-656 ■ MIL-DTL-32119 See also . Electroplating References 1. ^ a b Fact sheet on Electroless Nickel 2. ^ http://tawasplating.com/process/electrolessnickel.html Retrieved from "http://en.wikipedia.org/wiki/Electroless—nickel_plating" http://en.wikipedia.org/wiki/Electroless—nickel_plating 9/15/2010 Electroless nickel plating - Wikipedia, the free encyclopedia Page 4 of 4 Categories: Metal plating ■ This page was last modified on 10 September 2010 at 13:58. ■ Text is available under the Creative Commons Attribution-ShareAlike License; additional terms may apply. See Terms of Use for details. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization. http://en.wikipedia.org/wiki/Electroless_nickel_plating 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 1 of 12 Restriction of Hazardous Substances Directive From Wikipedia, the free encyclopedia (Redirected from RoHS) The Directive on the restriction of the use of certain European Union directive: hazardous substances in electrical and electronic equipment - 2002/95/EC (* listen ; commonly referred to as the Restriction Directive 2002/95/EC of Hazardous Substances Directive or RoHS) was adopted in February 2003 by the European Union.�11 The RoHS directive Directive on the restriction of the use of certain hazardous substances in took effect on 1 July 2006, and is required to be enforced and electrical and electronic equipment become law in each member state. This directive restricts the _ __._ _................___ use of six hazardous materials in the manufacture of various Made by Council & types of electronic and electrical equipment. It is closely linked Parliament with the Waste Electrical and Electronic Equipment Directive (WEEE) 2002/96/EC which sets collection, recycling and Made under Art. 95 EC recovery targets for electrical goods and is part of a legislative Journal [eur-lex.europa.eu initiative to solve the problem of huge amounts of toxic e-waste. reference L37, 13 February In speech, RoHS is often spelled out, or 2003 PP• ] pronounced /'rus/, /'rof/, /'rouz/, /'rouhoz/ or "rose", v19-23 "roast" without the T "Ross" "raws" "ro-haws" or "ro-hoss". History _..........___._.._ ...._...___.. __ .. .___._.. Made 27 January 2003 Contents Came into 13 February 2003 force ■ 1 Details ■ 1.1 Examples of product components containing Implementation 13 August 2004 restricted substances date ■ 1.2 Product category 8 and 9 exclusions Preparative texts ■ 1.3 Hazardous materials and the high-tech trash problem Commission C365E, 19 ■ 1.4 Changing toxicity perceptions proposal December 2000, ■ 1.5 Life -cycle impact assessment of lead-free p. 195, solder C240E, 28 August F ■ 1.6 Life -cycle impact assessment of BFR-free 2001, p. 303. plastics EESC opinion C 116, 20 April ■ 2 Labeling ! 2001,p.38. ■ 3 RoHS in other regions ■ 3.1 Asia / Pacific CR opinion C148, 18 May 2001, y ■ 3.2 North America P. 1 • ■ 4 Other standards EP opinion C34E, 7 February I ■ 5 C:iti51 III 2002, p. 109. 1 Effect on reliability _ II ■ 5.2 Economic effect Other legislation ■ 6 Benefits Amended by Dir. 2008/35/EC; ■ 6.1 Health benefits Dec. 2005/618/EC, ■ 6.2 Reliability concerns unfounded Dec. 2005/717/EC, ■ 6.3 Flow properties and assembly Dec. 2005/747/EC, ■ 6.4 Some exempt products achieve compliance Dec. 2006/310/EC, http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 2 of 12 ■ 7 Literature ■ 8 See also ■ 9 References ■ 10 External links Details Dec. 2006/690/EC, Dec. 2006/691 /EC, Dec. 2006/692/EC, Dec. 2008/385/EC. Status: Current legislation Each European Union member state will adopt its own enforcement and implementation policies using the directive as a guide. RoHS is often referred to as the lead-free directive, but it restricts the use of the following six substances: 1. Lead (Pb) 2. Mercury (Hg) 3. Cadmium (Cd) 4. Hexavalent chromium (Cr6+) 5. Polybrominated biphenyls (PBB) 6. Polybrominated diphenyl ether (PBDE) PBB and PBDE are flame retardants used in several plastics. The maximum permitted concentrations are 0.1% or 1000 ppm (except for cadmium, which is limited to 0.01 % or 100 ppm) by weight of homogeneous material. This means that the limits do not apply to the weight of the finished product, or even to a component, but to any single substance that could (theoretically) be separated mechanically —for example, the sheath on a cable or the tinning on a component lead. As an example, a radio is composed of a case, screws, washers, a circuit board, speakers, etc. The screws, washers, and case may each be made of homogenous materials, but the other components comprise multiple sub -components of many different types of material. For instance, a circuit board is composed of a bare PCB, ICs, resistors, capacitors, switches, etc. A switch is composed of a case, a lever, a spring, contacts, pins, etc, each of which may be made of different materials. A contact might be composed of a copper strip with a surface coating. A speaker is composed of a permanent magnet, copper wire, paper, etc. Everything that can be identified as a homogeneous material must meet the limit. So if it turns out that the case was made of plastic with 2,300 ppm (0.23%) PBB used as a flame retardant, then the entire radio would fail the requirements of the directive. In an effort to close RoHS loopholes, in May 2006 the European Commission was asked to review two currently excluded product categories (monitoring and control equipment, and medical devices) for future inclusion in the products that must fall into RoHS compliance.[2] In addition the commission entertains requests for deadline extensions or for exclusions by substance categories, substance location or weight. [3] Note that batteries are not included within the scope of RoHS. However, in Europe, batteries are under the European Commission's 1991 Battery Directive (91/157/EEC[4]), which was recently increased in scope and approved in the form of the new battery directive, version 2003/0282 COD,[5] which will be official when submitted to and published in the EU's Official Journal. While the first Battery Directive addressed possible trade barrier issues brought about by disparate European member states' http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 3 of 12 implementation, the new directive more explicitly highlights improving and protecting the environment from the negative effects of the waste contained in batteries. It also contains a program for more ambitious recycling of industrial, automotive, and consumer batteries, gradually increasing the rate of manufacturer -provided collection sites to 45% by 2016. It also sets limits of 5 ppm mercury and 20 ppm cadmium to batteries except those used in medical, emergency, or portable power -tool devices.[6] Though not setting quantitative limits on quantities of lead, lead -acid, nickel, and nickel -cadmium in batteries, it cites a need to restrict these substances and provide for recycling up to 75% of batteries with these substances. There are also provisions for marking the batteries with symbols in regard to metal content and recycling collection information. The directive applies to equipment as defined by a section of the WEEE directive. The following numeric categories apply: 1. Large and small household appliances. 2. IT equipment. 3. Telecommunications equipment (although infrastructure equipment is exempt in some countries) 4. Consumer equipment. 5. Lighting equipment —including light bulbs. 6. Electronic and electrical tools. 7. Toys, leisure, and sports equipment. 8. Medical devices (currently exempt) 9. Monitoring and control instruments (currently exempt) 10. Automatic dispensers. It does not apply to fixed industrial plant and tools. Compliance is the responsibility of the company that puts the product on the market, as defined in the Directive; components and sub -assemblies are not responsible for product compliance. Of course, given the fact that the regulation is applied at the homogeneous material level, data on substance concentrations needs to be transferred through the supply chain to the final producer. An IPC standard has recently been developed and published to facilitate this data exchange, IPC-1752.[7] It is enabled through two PDF forms that are free to use. RoHS applies to these products in the EU whether made within the EU or imported. Certain exemptions apply, and these are updated on occasion by the EU. Examples of product components containing restricted substances RoHS restricted substances have been used in a broad array of consumer electronics products. Examples of leaded components include: ■ paints and pigments . PVC (vinyl) cables as a stabilizer (e.g. power cords, USB cables) . solders . printed circuit board finishes, leads, internal and external interconnects ■ glass in television and photographic products (e.g. CRT television screens and camera lenses) ■ metal parts ■ lamps and bulbs . batteries Cadmium is found in many of the above components, examples include plastic pigmentation, nickel - cadmium (NiCd) batteries and US photocells (used in night lights). Mercury is used in lighting applications and automotive switches, examples include fluorescent lamps (used in laptops for http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 4 of 12 backlighting) and mercury tilt switches (these are rarely used nowadays). Hexavalant chromium is used for metal finishes to prevent corrosion. Polybrominated biphenyls and diphenyl Ethers/Oxides are used primarily as flame retardants. [8] Product category 8 and 9 exclusions Medical devices, and monitoring and control instruments comprise RoHS Category 8 and Category 9 products respectively. The EU recognizes that these products are manufactured in small numbers and generally have a long product life. Further, these products are often used in mission -critical applications where their failure can reasonably be expected to be extremely disruptive, if not catastrophic. Since the long term effects of lead-free solder, a primary RoHS objective, cannot be known for a period of at least five years following the directive's application to the remaining eight categories, the EU has established at least a temporary moratorium for Category 8 and 9 products. In an effort to gain more insight the EU commissioned a study to assess when and if the RoHS directive should be applied to Category 8 and 9 products. Released in July 2006, the Review of Directive 20021951EC (RoHS) Categories 8 and 9 — Final Report recommended that Category 8 and 9 products remain exempt from the RoHS directive until 2012 or 2018 depending upon specific product sub- categories and applications.191 Since the EU has not yet adopted this recommendation, the exact timing of RoHS application to Category 8 and 9 products remains uncertain. Hazardous materials and the high-tech trash problem RoHS and other efforts to reduce hazardous materials in electronics are motivated in part to address the global issue of consumer electronics waste. As newer technology arrives at an ever increasing rate, consumers are discarding their obsolete products sooner than ever. This waste ends up in landfills and in countries like China to be "recycled."1101 "In the fashion -conscious mobile market, 98 million US cell phones took their last call in 2005. All told, the EPA estimates that in the U.S. that year, between 1.5 and 1.9 million tons of computers, TVs, VCRs, monitors, cell phones, and other equipment were discarded. If all sources of electronic waste are tallied, it could total 50 million tons a year worldwide, according to the UN Environment Programme. "111 ] American electronics sent offshore to countries like Ghana in West Africa under the guise of recycling may be doing more harm than good. Not only are adult and child workers in these jobs being poisoned by heavy metals, but these metals are returning to the U.S. "The U.S. right now is shipping large quantities of leaded materials to China, and China is the world's major manufacturing center," Dr. Jeffrey Weidenhamer says, a chemistry professor at Ashland University in Ohio. "It's not all that surprising things are comingfull circle and now we're getting contaminated products back."[12][13] Changing toxicity perceptions In addition to the high-tech trash problem, RoHS reflects contemporary research over the past 50 years in biological toxicology that acknowledges the long-term effects of low-level chemical exposure on populations. New testing is capable of detecting much smaller concentrations of environmental toxins. Researchers are associating these exposures with neurological, developmental, and reproductive changes. RoHS and other environmental laws are in contrast to historical and contemporary law that seek to address only acute toxicology, that is direct exposure to large amounts of toxins causing severe injury or http://en.wikipedia.org/wiki/RoHS 9/ 15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 5 of 12 death.[14] Life -cycle impact assessment of lead-free solder The United States Environmental Protection Agency (EPA) has published a life -cycle assessment (LCA) of the environmental impacts of lead-free and tin -lead solder, as used in electronic products.[151 For bar solders, when only lead-free solders were considered, the tin/copper alternative had the lowest (best) scores. For paste solders, bismuth/tin/silver had the lowest impact scores among the lead-free alternatives in every category except non-renewable resource consumption. For both paste and bar solders, all of the lead-free solder alternatives had a lower (better) LCA score in toxicity categories than tin/lead solder. This is primarily due to the toxicity of lead, and the amount of lead that leaches from printed wiring board assemblies, as determined by the leachability study conducted by the partnership. The study results are providing the industry with an objective analysis of the life -cycle environmental impacts of leading candidate alternative lead-free solders, allowing industry to consider environmental concerns along with the traditionally evaluated parameters of cost and performance. This assessment is also allowing industry to redirect efforts toward products and processes that reduce solders' environmental footprint, including energy consumption, releases of toxic chemicals, and potential risks to human health and the environment. Another life -cycle assessment by IKP, University of Stuttgart, shows similar results to those of the EPA study.l161 Life -cycle impact assessment of BFR-free plastics The ban on concentrations of brominated flame retardants (BFR) above 0.1% in plastics has had an impact on plastics recycling. As more and more products include recycled plastics, it has become critical to know the BFR concentration in these plastics, either by tracing the origins of the recycled plastics to establish the BFR concentrations, or by measuring the BFR concentrations from samples. Plastics with high BFR concentrations are costly to handle or to discard, whereas plastics with levels below 0.1% have value as recyclable materials. There are a number of analytical techniques for the rapid measurement of BFR concentrations. X-ray fluorescence spectroscopy can confirm the presence of bromine (Br), but it does not indicate the BFR concentration or specific molecule. Ion attachment mass spectrometry (IAMS) can be used to measure BFR concentrations in plastics. The BFR ban has had significant impacts both upstream — plastic material selection — and downstream — plastic material recycling. Labeling RoHS does not require any specific product labeling, however many manufacturers have adopted their own compliance marks to reduce confusion. Visual indicators in use today include explicit "RoHS compliant" labels, green leaves, check marks, and "PB-Free" markings. In addition, the closely related WEEE (Waste Electrical and Electronic Equipment Directive) trash -can logo with an "X" through it is an indicator The WEEE that the product may be compliant. Chinese RoHS labels, a lower case "e" within a directive logo circle with arrows, can also designate compliance. The proposed RoHS2 attempts to address this issue by requiring the CE mark, introducing an additional enforcement agency, Trading Standards.["] RoHS in other regions http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 6 of 12 Please note that world wide standards and certification are available under the QC 080000 standard, governed by the NSAI (National Standards Authority of Ireland), to ensure the control of RoHs in industrial applications. Asia / Pacific China Order No. 39: Final Measures for the Administration of the Control and Electronic Information Products(often referred to as China RoHSI18]) has the stated intent to establish similar restrictions, but in fact takes a very different approach. Unlike EU RoHS, where products in specified categories are included unless specifically excluded, there will be a list of included products, known as the catalogue — see Article 18 of the regulation — which will be a subset of the total scope of Electronic Information Products, or EIPs, to which the regulations apply. Initially, products that fall under the covered scope must provide markings and disclosure as to the presence of certain substances, while the substances themselves are not (yet) prohibited. There are some products that are EIPs, which are not in scope for EU RoHS, e.g. radar systems, semiconductor -manufacturing equipment, photomasks, etc. The list of EIPs is available in Chinese and English.1191 The marking and disclosure aspects of the regulation were intended to take effect on July 1, 2006, but were postponed twice to March 1, 2007. There is no timeline for the catalogue yet. Japan does not have any direct legislation dealing with the RoHS substances, but its recycling laws have spurred Japanese manufacturers to move to a lead-free process in accordance with RoHS guidelines. A ministerial ordinance Japanese industrial standard for Marking Of Specific Chemical Substances (J- MOSS), effective from July 1, 2006, directs that some electronic products exceeding a specified amount of the nominated toxic substances must carry a warning label.[20] South Korea promulgated the Act for Resource Recycling of Electrical and Electronic Equipment and Vehicles on April 2, 2007. This regulation has aspects of RoHS, WEEE, and ELV.[21] Turkey announced the implementation of their Restriction of Hazardous Substances (RoHS) legislation effective June 2009.[221 North America California has passed SB 20: Electronic Waste Recycling Act of 2003, or EWRA. This law prohibits the sale of electronic devices after January 1, 2007, that are prohibited from being sold under the EU RoHS directive, but across a much narrower scope that includes LCDs, CRTs, and the like and only covers the four heavy metals restricted by RoHS. EWRA also has a restricted material disclosure requirement. Effective January 1, 2010, the California Lighting Efficiency and Toxics Reduction Act applies RoHS to general purpose lights, i.e. "lamps, bulbs, tubes, or other electric devices that provide functional illumination for indoor residential, indoor commercial, and outdoor use."[23] Other US states and cities are debating whether to adopt similar laws, and there are several states that have mercury and PBDE bans already. Other standards RoHS is not the only environmental standard of which electronic product developers should be aware. Manufacturers will find that it is cheaper to have only a single bill of materials for a product that is http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 7 of 12 distributed worldwide, instead of customizing the product to fit each country's specific environmental laws. Therefore, they develop their own standards, which allow only the strictest of all allowable substances. For example, IBM forces each of their suppliers to complete a Product Content Declaration form to document compliance to their environmental standard Baseline Environmental Requirements for Materials, Parts and Products for IBM Logo Hardware Products. So for example, IBM bans DecaBDE, even though there is a RoHS exception for this material [2], this exemption was lifted on 1 April 2008 [3]• Similarly, here is Hewlett-Packard's environmental standard: General specification for the environment (GSE). Criticism Adverse effects on product quality and reliability, plus high cost of compliance (especially to small business) are cited as criticisms of the directive, as well as early research indicating that the life cycle benefits of lead-free solder versus traditional solder materials are mixed.[151 Criticism early on came from an industry resistant to change and a misunderstanding of solders and soldering processes. Deliberate misinformation was espoused to resist what was perceived as a "non -tariff barrier created by European bureaucrats." Many believe the industry is stronger now through this experience and has a better understanding of the science and technologies involved.[24] One criticism of RoHS is that the restriction of lead and cadmium does not address some of their most prolific applications, while being costly for the electronics industry to comply with. Specifically, the total lead used in electronics makes up only 2% of world lead consumption, while 90% of lead is used for batteries (covered by the battery directive, as mentioned above, which requires recycling and limits the use of mercury and cadmium, but does not restrict lead). Another criticism is that less than 4% of lead in landfills is due to electronic components or circuit boards, while approximately 36% is due to leaded glass in monitors and televisions, which can contain up to 2 kg per screen.[251 The more common Lead-free solder systems have a higher melting point e.g., a 30°C typical difference for tin -silver -copper alloys but wave soldering temperature is approximately the same at—255°0261. however at this temperature most typical lead free solders have longer wetting times than Pb/Sn 37:63 solder.[271 Additionally wetting force is typically lower[271, which can be disadvantageous (for hole filling), but advantageous in other situations (closely spaced components). Care must be taken in selection of RoHS solders as some formulations are harder with less ductility, increasing the likelihood of cracks instead of plastic deformation, which is typical for lead -containing solders.[ct""n needed] Cracks can occur due to thermal or mechanical forces acting on components or the circuit board, the former being more common during manufacturing and the latter in the field. RoHS solders exhibit advantages and disadvantages in these respects, dependent on packaging and formulation. [28] The editor of Conformity Magazine wonders if the transition to lead-free solder will not affect long-term reliability of electronic devices and systems, especially in applications more mission -critical than in consumer products, citing possible breaches due to other environmental factors like oxidation.[29] This article refers to the Newark InOne "RoHS Legislation and Technical Manual",[30] which cites these and other "lead-free" solder issues, such as: http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 8 of 12 1. Warping or delamination of printed circuit boards; 2. Damage to through -holes, ICs and components on circuit boards; and, 3. Added moisture sensitivity, all of which may compromise quality and reliability. Effect on reliability Potential reliability concerns are addressed in Annex, item #7, of the RoHS directive, granting servers exemption from regulation until 2010. These issues were raised when the directive was first implemented in 2003 and reliability effects were less known. [311 Another potential problem that lead-free solders face is the growth of tin whiskers. These thin strands of tin can grow and make contact with an adjacent trace, developing a short circuit. Historically tin whiskers have been associated with a handful of failures, including a nuclear power plant and pacemaker incident where pure tin plating was used, see tin whiskers. However, these failures pre -date RoHS. They also do not involve consumer electronics, and therefore may employ RoHS-restricted substances if desired. To help mitigate potential problems, lead-free manufacturers are using a variety of approaches such as tin - zinc formulations that produce non -conducting whiskers or formulations that reduce growth, although they do not halt growth completely in all circumstances. [321 Fortunately, experience thus far suggests deployed instances of RoHS compliant products are not failing due to whisker growth. Dr. Ronald Lasky of Dartmouth College reports: "RoHS has been in force for more than 15 months now, and —$400B RoHS-compliant products have been produced. With all of these products in the field, no significant numbers of tin whisker -related failures have been reported. "[33] Whisker growth occurs slowly over time, is unpredictable, and not fully understood, so time may be the only true test of these efforts. Whisker growth is even observable for lead -based solders, albeit on a much smaller scale. Some countries have exempted medical and telecommunication infrastructure products from the legislation.[341 However, this may be a moot point, as electronic component manufacturers convert their production lines to producing only lead-free parts, conventional parts with eutectic tin -lead solder will simply not be available, even for military, aerospace and industrial users. To the extent that only solder is involved, this is at least partially mitigated by many lead-free components' compatibility with lead - containing solder processes. Leadframe-based components, such as QFPs, SOICs, and SOPs with gull wing leads, are generally compatible since the finish on the part leads contributes a small amount of material to the finished joint. However, components such as BGAs which come with lead-free solder balls and leadless parts are often not compatible with lead -containing processes.[35] Economic effect There are no de minimus exemptions, e.g., for micro -businesses. Today, only one micro -business is known to have closed down, to investigate the cost of compliance.[36] This economic effect was anticipated and at least some attempts at mitigating the effect were made.[37] Another form of economic effect is the cost of product failures during the switch to RoHS compliance. For example, tin whiskers were responsible for a 5% failure rate in certain components of Swiss Swatch watches in 2006, reportedly triggering a $1 billion recall.[38] Swatch responded to this by applying for exemptions to RoHS compliance for two components. One of these exemptions was effectively approved, with the other still pending after an initial denial. For the denied part Swatch has stated to be using a replacement solder that is almost pure lead, and its application was for permission to switch to a solder with a lower lead content. [39] [40] [41 ] http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 9 of 12 Benefits Health benefits RoHS helps reduce damage to people and the environment in third -world countries where much of today's "high-tech trash" ends up.[42][43][441 The use of lead-free solders and components has provided immediate health benefits to electronics industry workers in prototype and manufacturing operations. Contact with solder paste no longer represents the same health -hazard it did before.[45] Reliability concerns unfounded Contrary to the predictions of widespread component failure and reduced reliability, RoHS's first anniversary (July 2007) passed with little fanfare.[46] Today, millions of compliant products are in use worldwide. Most of today's consumer electronics are now RoHS compliant, examples include Apple's iPod portable music players, Dell and HP home computers and servers, Nintendo's Wii, Motorola and Nokia's wireless phones, Netgear routers, and Panasonic televisions and appliances. Many electronics companies keep "RoHS status" pages on their corporate websites. For example, the AMD website states: An illustration of solder joint reliability, demonstrating A1phaSTAR's reliability versus traditional joints. A1phaSTAR is a RoHS immersion silver PWB assembly process from Cookson Electronics. Copyright 2007 © Enthone Inc. "Although lead containing solder cannot be completely eliminated from all applications today, AMD engineers have developed effective technical solutions to reduce lead content in microprocessors and chipsets to ensure RoHS compliance while minimizing costs and maintaining product features. There is no change to fit, functional, electrical or performance specifications. Quality and reliability standards for RoHS compliant products are expected to be identical compared to current packages. "[47] RoHS printed circuit board finishing technologies are surpassing traditional formulations in fabrication thermal shock, solder paste printability, contact resistance, and aluminum wire bonding performance and nearing their performance in other attributes.[48] One of these finishing products, known as immersion silver, is depicted here. The properties of lead-free solder, such as its high temperature resilience, has been used to prevent failures under harsh field conditions. These conditions include 150°C operating temperatures with test cycles in the range of -40°C - 150°C with severe vibration and shock requirements. Automobile manufacturers are turning to RoHS solutions now as electronics move into the engine bay.[491 Flow properties and assembly One of the major differences between lead -containing and lead-free solder pastes is the 'flow" of the solder in its liquid state. Lead -containing solder has higher surface tension, and tends to move slightly to attach itself to exposed metal surfaces that touch any part of the liquid solder. Lead-free solder conversely tends to stay in place where it is in its liquid state, and attaches itself to exposed metal surfaces only http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 10 of 12 where the liquid solder touches it. This lack of 'Wow "—while typically seen as a disadvantage because it can lead to lesser quality electrical contacts —can be used to place components tighter than they normally could be placed due to the properties of lead -containing solders. For example, Motorola reports that their new RoHS wireless device assembly techniques are "...enabling a smaller, thinner, lighter unit." Their Motorola Q phone would not have been possible without the new solder. The lead-free solder allows for tighter pad spacing.[50] Some exempt products achieve compliance Research into new alloys and technologies is allowing companies to release RoHS products that are currently exempt from compliance, e.g. computer servers.[511 IBM has announced a RoHS solution for high lead solder joints once thought to remain a permanent exemption. The lead-free packaging technology "...offers economical advantages in relation to traditional bumping processes, such as solder waste reduction, use of bulk alloys, quicker time -to -market for products and a much lower chemical usage rate. "[52][53] Test and measurement vendors, such as National Instruments, have also started to produce RoHS- compliant products, despite devices in this category being exempt from the RoHS directive. [54] Literature ■ Hwang, Jennie S. (2004). Introduction to Implementing Lead -Free Electronics. McGraw-Hill Professional. ISBN 0-07-144374-6. See also ■ Battery Directive ■ Electronic waste ■ Green computing ■ Ion attachment mass spectrometry - used to enforce RoHS limits on banned substances ■ List of European Union directives ■ Waste Electrical and Electronic Equipment Directive References 1. ^ Eur-lex.europa.eu 2. ^ European Commission to Plug RoHS Loophole 3. ^ EU Invites Comments on Possible RoHS Exemptions 4. ^ Council Directive of 18 March 1991 on batteries and accumulators containing certain dangerous substances (91/157/EEC) 5. ^ Directive 2006/... /EC of the European Parliament and of the Council on batteries and accumulators and waste batteries and accumulators and repealing Directive 91/157/EEC 6. ^ Conformity Magazine: The EU's RoHS and WEEE Directives 7. ^ IPC 1752 for Materials Declaration 8. ^ Elimination of RoHS Substances in Electronic Products 9. ^ Review of Directive 2002/95/EC (RoHS) Categories 8 and 9 — Final Report 10. ^ Heavy Metals Concentrations of Surface Dust from a -Waste Recycling and Its Human Health Implications http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 11 of 12 in Southeast China 11. ^ High -Tech Trash - National Geographic 12. ^ Study: E-waste recycling poisons people with heavy metals, News.com Green Tech Blog/LaMonica 13. ^ Recycling that Harms the Environment and People - New York Times 14. ^ New Toxicity 15. A, b Solders in Electronics: A Life -Cycle Assessment 16. ^ Life -Cycle Assessment according to ISO 14040 17. ^ RoHS2 18. ^ Kuschnik, Bernhard; The European Union's Energy Using Products - EuP - Directive 2005/32 EC: Taking Transnational Eco - Product Design Regulation One Step Further, 27 Temple Journal of Science Technology & Environmental Law 1 (2008), 1, (2). 19. ^ China RoHS Solutions 20. ^ Law for the Promotion of Effective Utilization of Resources from the Japanese Ministry of Economy, Trade and Industry, accessed 2007-10-15 21. ^ Korean RoHS 22. ^ Intertek Group plc 23. ^ California RoHS Lighting Requirements to Become Effective on January 1, 2010 24. ^ [1] 25. ^ European Power Supply Manufacturers Association 26. ^ FACT AND FICTION IN LEAD FREE SOLDERING from www.dkmetals.co.uk 27. A, b Temperature selection for wave soldering with Lead -Free alloys Circuits assembly May 2001 www.circuitsassembly.com , via www.solderconnection.co.uk 28. ^ Thermal cycling reliability of SnAgCu and SnPb solder joints: A comparison for several IC -packages 29. ^ Conformity Magazine: Removal of Lead Shakes Up the Manufacturing Chain 30. ^ Newark InOne: RoHS Legislation and Technical Manual 31. ^ "Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003 on the restriction of the use of certain hazardous substances in electrical and electronic equipment" (PDF). http://europa.eu/eur- lex/pri/en/oj/dat/2003/1-037/1-03720030213 en00190023.pdf#search=%22rohs%20%22. 32. ^ "New Sn-Zn Solder Bonds at Under 200 celsius". http://techon.nikkeibp.co.jp/NEA/archive/200211/214612. 33. ^ "Frome One Engineer to Another - RoHS". http://blogs.indium.com/blog/rohs. 34. ^ "Digital Control Systems Inc. Prepares for New Restriction of Hazardous Substances Legislation". http://www.dcs-inc.net/RoHS.htm. 35. ^ ST Application Note 2034 - Soldering Compatibility 36. ^ GIMFG.com has suspended retail operations for the moment ... 37. ^ Partial Regulatory Impact Assessment of the Draft Statutory Instrument to Implement the European Directive on the Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment (UK) 38. ^ Within a whisker of failure, The Guardian, April 3, 2008 39. ^ Overview on Exemptions and Pending Requests at EU Level, Orgalime, January 23, 2007, page 8 40. ^ Metal Whiskers: Failure Modes and Mitigation Strategies, Jay Brusse, Dr. Henning Leidecker, Lyudmyla Panashchenko, NASA, December 5, 2007, page 35 41. ^ Adaptation to scientific and technical progress under Directive 2002/95/EC, Oko-Institut e.V., Frauenhofer Institut IZM, July 28, 2006, page 83 42. ^ Laws fail to keep up with e-trash 43. ^ Health effects of high-tech trash in third world countries 44. ^ Technology's Morning After 45. ^ Ogunseitan, Oladele A. (July 2007). "Health and Environmental Benefits of Adopting Lead -Free Solders". Journal of Materials (New York: Springer) 59 (7): 12-17. ISSN 1047-4838. http://www.tms.org/pubs/journals/jom/0707/ogunseitan-0707.html. Retrieved 14 December 2009. 46. ^ One Year Later: The Good News is the Bad News was Wrong 47. ^ AMD Statement on RoHS Compliance: 48. ^ Sunstone Circuits material comparison matrix 49. ^ Adaption to Scientific and Technical Progress Under RoHS 50. ^ Motorola Q: Not Possible without Lead-free Assembly 51. ^ Dell RoHS Products 52. ^ IBM Launches Production of Lead-free Packaging Technology 53. ^ IBM Announces Shipment of Lead-free C4 Joints http://en.wikipedia.org/wiki/RoHS 9/15/2010 Restriction of Hazardous Substances Directive - Wikipedia, the free encyclopedia Page 12 of 12 54. ^ NI premiers RoHS-compliant products External links ■ RoHS compliance guidance for businesses on NetRegs.gov.uk ■ RoHS Compliance in the EU - www.rohs.eu ■ RoHS Compliance Definition & Guidelines ■ EU Regulations compliance (WEEE, RoHS, Batteries, REACH) ■ RoHS directive official text ■ Official United Kingdom site on RoHS ■ Free RoHS regulatory bulletin updates - Bureau Veritas ■ Silicon Valley Toxics Coalition ■ Understanding RoHS (PDF) Shimadzu Scientific Instruments ■ Lead-free RoHS Compliance Material Comparison from Sunstone Circuits ■ RoHS Explained: includes overview and links to related resources? ■ RoHS News ■ Electronic Components and RoHS Compliance News ■ EIATRACK information on RoHS and WEEE Directives ■ RoHS 101 . China RoHS ■ Cleaner products at lower cost (1/3; Hermann Strass; Open Systems Publishing; May 2003 ■ EU RoHS Enforcement Guidance Document, V.1; EU RoHS Enforcement Authorities Informal Network; May 2006 ■ Lead -Free Medical Devices Article from 2005 ■ Understanding RoHS from MEC Innovation ■ Properties of Lead -Free Solders National Institute of Standards and Technology Retrieved from "http://en.wikipedia.org/wiki/Restriction_of_Hazardous_Substances_Directive" Categories: European Union directives I Environmental chemistry I Waste legislation in the European Union I Waste legislation in the United Kingdom 12003 in law 12003 in the European Union Environmental protection I Electronic waste This page was last modified on 9 September 2010 at 11:50. Text is available under the Creative Commons Attribution-ShareAlike License; additional terms may apply. See Terms of Use for details. Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a non-profit organization. http://en.wikipedia.org/wiki/RoHS 9/15/2010