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HomeMy WebLinkAboutWI0400091_Monitoring (Report)_20120723JCL EINFEL DER Bright People. Right Solutions. QUARTERLY HISOC MONITORING REPORT Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Kleinfelder Project No. 97746 Copyright 2012 Kleinfelder All Rights Reserved ONLY THE CLIENT OR ITS DESIGNATED REPRESENTATIVES MAY USE THIS DOCUMENT AND ONLY FOR THE SPECIFIC PROJECT FOR WHICH THIS REPORT WAS PREPARED KL EI NFEL DER J_ Bright People. Right Solutions. July 20, 2012 File No. 97746 1 GS012RO376 Mr, Thomas Slusser Aquifer Protection Section — UIC Staff ❑ENR — Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Quarterly HiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Dear Mr. Slusser: RECErVEDrnFNpjoWQ JUL 2 3 2012 Aquifer Protection Section Kleinfelder is pleased to provide our quarterly monitoring report for the Underground Injection Control {UIC} Permit for treatment of groundwater with a HiSOC system at the referenced site. This report summarizes our field activities, observations, and includes the analytical results of the groundwater samples. Should you have any questions or require additional information, please do not hesitate to contact Chris Hay at your convenience. Very truly yours, KLEINFELDER SOUTHEAST, INC. Firm License No. F-1 143 -'4I � � Annamarie Blauser Staff Professional 11 C"Christpher W. Hays; E.I. Program Manager ABIC W H : cas Enclosure 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1 336.668.0093 f 1336,668.3868 GILBARCO Greensboro, North Carolina Groundwater Incident No. 12960 July 20, 2012 SITE INFORMATION Address: 7300 West Friendly Avenue Greensboro, North Carolina Contact: Ms. Sarita Allen Telephone: 336.547.5086 Latitude and Longitude: 36.0901 °N, 79.9282 °W Risk Classification: Low Land Use Category: Commercial LAND OWNERSHIP Name: Gilbarco Address: 7300 West Friendly Avenue Greensboro, North Carolina 27420 Telephone: 336.547.5086 Attention: Ms. Sarita Allen RELEASE INFORMATION Cause of Release: Release from a 1,000-gallon diesel UST and four 550- gallon gasoline USTs was discovered in November and December 1994. The quantity released is unknown. ENVIRONMENTAL CONSULTANT Name: Kleinfelder Southeast, Inc. Address: 313 Galiimore Dairy Road Greensboro, North Carolina 27409 Telephone: 336.668,0093 Attention: Mr. Christopher W. Hay SEAL AND SIGNATURE OF CERTIFYING PROFESSIONAL GEOLOGIST .r I, Peter F. Pozz&" arPF '6WI Geologist for Kleinfelder Southeast, Inc. do certify that the information c �''�o�is correct and accurate to the best of my knowledge. Peter F. P zjo, G. 2158 NC License !?: ,1 o o G� zyr'fl �% -.; ,4 l •.,�... Kleinfelder Southeast, Inc. is allowed to practice Geology I Engineering in North Carolina. The certification number of the corporation is F-1143. 977461 GS012RO376 Page i July 20, 2012 Copyright 2012 Kleinfelder KLEINFELDER 313 Gallirnore Dairy Road, Greensboro, NC 27409 p 1 336,66&0093 f 1336.668.3868 TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................I............1 2.0 RECEPTOR SURVEY.....................................................................................................1 3.0 HiSOC INSTALLATION AND MONITORING.................................................................2 4.0 GROUNDWATER MONITORING ACTIVITIES...............................................................3 5.0 GROUNDWATER ANALYTICAL RESULTS..................................................................4 6.0 SURFACE WATER SAMPLING...................................................................... .....6 7.0 CONCLUSIONS AND RECOMMENDATIONS...............................................................7 8.0 LIMITATIONS.................................................................................................................8 TABLES 1 Groundwater Elevation Data 2 Estimated Dissolved Hydrogen Concentrations at Injection Wells 3 Estimated Hydrogen Consumption 4 Aquifer Characteristics Field Analysis Summary 5 Summary of Groundwater Sample Results 6 Historical Summary of Groundwater Sample Results 7 Surface water Sample Results FIGURES 1 Site Location Map 2 Site Plan 3 Shallow Groundwater Potentiometric Surface Map 4 Total VOCs Concentrations 5 Total Chlorinated Hydrocarbons Concentrations APPENDICES A Laboratory Reports and Chain -of -Custody Documents B Total Petroleum Hydrocarbons, Chlorinated Hydrocarbons and VOC Graphs 977461 GS012RO375 Page ii July 20, 2012 Copyright 2012 Kieinfelder KLEINFELDER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1336.568.0093 f 1336,668,3868 1.0 INTRODUCTION The subject site is located at 7300 West Friendly Avenue in Greensboro, Guilford County, North Carolina (Figure 1). A groundwater pump and treat system is operating at the site. The system consists of four recovery wells, an oil -water separator, and an air stripping system. In January 2008, Kleinfelder submitted a CAP Addendum recommending the use of HiSOC and iSOC technology to degrade the chlorinated and petroleum hydrocarbons in groundwater at the site. This technology works in concert with the existing groundwater recovery system and supplements the ability of the system to contain the contaminant plume within the property limits and reduce contaminant levels. The HiSOC system was installed in June of 2008 and began operating on June 13, 2008. The baseline sampling event was conducted on June 5, 2008. As a result of contaminant levels detected in MW-47. MW-48 and MW-49, four new wells, three shaltow and one deep, were installed (MW-50, MW-51, MW-52, and MW-53D) between January 12, 2012 and January 18, 2012, The purpose of this report is to summarize the quarterly monitoring of the site performed on June 21, 2012. 2.0 RECEPTOR SURVEY A Receptor Survey was completed in November 2011 and included in the December 2011 Quarterly Groundwater Monitoring Report. Various utilities were identified within 500 feet of the source area. No public or private water supply wells were identifed within 0.5 mile of the site and the nearest surface water intake for the City of Greensboro public water supply is located 4.3 miles from the site. There is a stormwater pond near the northeast corner of the building. Additionally, there is a stream in the northern portion of the site. Two stormwater ponds southwest of the site were identified on the National Wetlands Inventory Map. Properties surrounding the site are industrial and have access to the city water supp#y system and the city sewer system. 97746 1 GSO12R0376 Page 1 of 8 July 20. 2012 Copyright 2012 Kleinfeider KLEINFELDER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1 336.6580093 f 1 336.668.3868 3.0 HiSOC INSTALLATION AND MONITORING Kleinfelder applied for a permit from the Underground Injection Control (UIC) Program for the installation of a hydrogen and oxygen delivery system for remediation of contaminants in groundwater at the site. A renewed permit dated April 20, 2010 was issued for the site (Injection Well Permit W10400091). The permit is effective through March 31, 2015. Installation of the injection equipment was initiated on April 9 through April 11, 2008. The existing protective casings were removed from monitoring wells MW-7, MW-10, MW-23D, MW-29, and MW-34. Ten -inch diameter PVC casings were installed to a depth of five feet below ground surface adjacent to the monitoring well locations to hold the hydrogen cylinders. Six to ten inches of gravel was placed in the bottom of each casing. Excavations were completed for installation of 24-inch square, steel well vaults and the vaults were set in concrete flush with the ground surface. Protective vaults were also installed adjacent to the existing above grade protective covers for monitoring wells MW-14D, MW-15, MW-16, MW-24, and MW-43D. The 15-inch by 24-inch PVC protective vaults were installed over the cylinder casings. Vents were installed in the protective vaults to allow hydrogen to be released in the case of a leak from the delivery system. The HiSOC equipment from InVentures was installed at the site in ten existing monitoring wells (MW-7, MW-10, MW-14D, MW-15, MW-16, MW-23D, MW-24, MW-29, MW-34, and MW-43D) on June 13, 2008. Within each injection well is a HiSOC unit and filter. Hydrogen is supplied from a compressed gas cylinder with a regulator and gauge connected to the HiSOC unit by Parflex tubing and a support cable. Four -foot grounding rods were installed and connected to the regulator assembly of the gas cylinders. On May 13, 2009 the HiSOC equipment was removed from monitoring well MW-10 and installed in monitoring well MW-25. The hydrogen cylinder was placed on the existing concrete well pad and a protective cover was constructed around the well and above ground protective well casing. A new grounding rod was installed. Other details of the HiSOC installation at MW-25 are substantially the same as described for the initial installation. On September 22, 2011 the HiSOC equipment in MW-25 was extended to the bottom of the well. The hydrogen pressure in MW-14D and MW-24 was increased from 45 pounds per square inch (psi) to 65 psi. HiSOC units installed in MW-23D and MW-29 had been working intermittently since May and June 2011, respectively. Following the completion of maintenance and testing, both units were removed in September and shipped to the manufacturer for repair. Both units were re -installed 97746 1 GS012RO376 Page 2 of 8 July 20. 2012 copyright 2012 Kleinfelder KLEINFELaER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1 336.668.0093 f 1336.668.3868 at the site on November 8, 2011. On December 29, 2011, the HiSOC equipment was removed from monitoring wells MW-23D and MW-34 and installed in monitoring wells MW-47 and MW-49, respectively. Current HiSOC installation locations are shown on the figures in orange. In anaerobic bioremediation applications, the HiSOC saturates the treatment well with dissolved hydrogen, typically at a concentration of 1 to 4 parts per million (ppm) depending on the immersion depth of the HiSOC unit in groundwater. The dissolved hydrogen concentration achieved in the injection well depends on the height of the water column in the well. Each atmosphere of pressure allows for a maximum of approximately 1.6 ppm of dissolved hydrogen. Table 2 estimates the dissolved hydrogen concentrations in each of the injection wells. These concentrations are estimated based on the approximate pressure at the installation depth of the HiSOC in the injection wells. The calculation is made with the assumption that 1.6 ppm of hydrogen is dissolved in the groundwater per atmosphere of pressure. Hydrogen is infused from the HiSOC into the treatment well at a typical rate of 28 standard cubic centimeters per minute or approximately 1.4 cubic feet per day. The hydrogen consumption in each of the injection wells is tracked to estimate the remaining service life of the hydrogen cylinders. Table 3 shows the recorded hydrogen cylinder pressures and estimates a date for each injection well that the cylinder should be replaced. The HISOC produces a convection current in the well with a designed release bubble from the top of the HiSOC to distribute dissolved hydrogen rich water throughout the screened interval. ' A curtain of hydrogen rich water disperses around the well into the adjacent groundwater forming a treatment zone allowing enhanced bioremediation to degrade the target contaminants. 4.0 GROUNDWATER MONITORING ACTIVITIES Static water levels were measured in the existing monitoring welts on -site on June 21, 2012. Groundwater samples were collected from a total of ten wells (MW-7, MW-14D, MW-16, MW-24, MW-43D, MW-45, MW-46, MW-47, MW-49, and MW-53D) and were analyzed for volatile organic hydrocarbons by EPA Method 6200B. The monitoring well locations are shown on Figure 2. Field parameters including oxidation-reduction potential (ORP), pH, conductivity, dissolved oxygen, and temperature of representative groundwater samples were also recorded from each monitoring well sampled. 97746 i GSO12R0376 Page 3 of 8 July 20. 2012 Copyright 2012 Kleinfelder KLEINFELDER 313 Gallimo►e Dairy Road, Greensboro, NC 27409 p 1336,668,0093 f 1 336.668,3868 Groundwater elevations in the existing monitoring wells were used to determine the groundwater flow direction and average hydraulic gradient. Table 1 provides a summary of monitoring well construction details and the groundwater elevations measured on June 21, 2012. The static water levels measured between monitoring wells MW-32 and MW-51 indicate a horizontal groundwater flow gradient of 0.05 feet per foot to the northwest. A groundwater flow map of the shallow aquifer based on the June 21, 2012 groundwater elevations is shown on Figure 3. Based on data provided in the October 1996 Corrective Action Plan, the surficial aquifer has an average hydraulic conductivity of 0.09 feet per day. The average groundwater velocity is estimated to be 0.014 feet per day (5 feet per year), based on the average groundwater gradient from the June 21, 2012 water level measurements and an estimated effective porosity of thirty percent. Groundwater samples were collected from the monitoring wells using disposable polyethylene bailers. The wells were purged of three well volumes of water or until they were bailed dry. Groundwater purged from the monitoring wells was disposed of on the ground outside of each well sampled. Groundwater samples were collected and placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersville, North Carolina. Chain -of -custody documents were maintained throughout the collection and transportation process and are included in Appendix A with the laboratory report. 5.0 GROUNDWATER ANALYTICAL RESULTS The field measurements recorded on June 21, 2012, are summarized in Table 4, which includes the preferred conditions for natural biodegradation of chlorinated compounds within the groundwater plume. Conductivity is recorded for quality control and sampling consistency. The groundwater field analyses generally indicate that the subsurface environment is within acceptable limits for anaerobic biodegradation to occur. With seasonal fluctuation, the temperature of the groundwater will increase, and the rate of biodegradation will also increase. The contaminant plume consists of volatile organic compounds (VOCs) either petroleum related or chlorinated hydrocarbons. VCCs. were detected at levels above their respective North Carolina groundwater quality standards established in 15A NCAC, Subchapter 2L (21- 97746 1 GSG12R0376 Page 4 of 8 July 20, 2012 Copyright 2012 Kleinfelder KLEINFELDER 313 Galiimore Dairy Road, Greensboro, NC 27409 p 1336.668.0093 f 1 336-668.3868 Standards] in all of the monitoring wells sampled. The analytical results are summarized in Table 5, and a historical summary of groundwater sampling results is presented in Table 6. The current hydrogen injection phase of the corrective action plan targets the reduction of chlorinated hydrocarbon contaminant levels in the groundwater. The oxygen injection phase will target the reduction of petroleum hydrocarbons. The volatile organic compounds targeted during the hydrogen and oxygen injection phases of the corrective action plan are separated in Tables 5 and 6 by a double line. Total VOCs concentrations detected during the June 21, 2012 sampling event are shown on Figure 4, and total chlorinated hydrocarbons concentrations detected during the sampling event are shown on Figure 5. The concentrations of total VOCs, chlorinated hydrocarbons, and total petroleum hydrocarbons for each monitoring well sampled are shown in individual graphs included in Appendix B. The graphs of the total VOC concentrations indicate a general decreasing trend in MW-7, MW-24, MW-46, MW-47, and MW-49. Since HiSOC units were installed at MW-47 and MW-49 in December 2011. total VOC concentrations have decreased. Total chlorinated hydrocarbon contaminant levels in monitoring well MW-24 have increased during the last quarter. The chlorinated hydrocarbon contaminant levels in monitoring wells MW-7 and MW-14D have decreased. Levels of chlorinated hydrocarbons in monitoring wells MW-14D and MW-43❑ have been variable far over two years. Groundwater in the vicinity of the recently installed wells MW-46, MW-47, MW-49, MW-52 and MW-53D is impacted primarily with chlorinated hydrocarbons. On May 2, 2012 groundwater samples were collected from monitoring wells MW-46, MW-47, and MW-49 and were analyzed for biological oxygen demand (BOD) by EPA Method 5210B. The analytical results indicated that BOD was detected in MW-47 at a concentration of 97.7 mg/L, and in MW-49 at a concentration of 24.3 mg/L 97746 1 GS012RO376 Page 5 of 8 July 20, 2012 Copyright 2012 Kleinfelder KLEINFELDER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1 336,668.0093 f f 336.668,3868 6.0 SURFACE WATER SAMPLING On May 2, 2012 surface water samples from Horse Pen Creek Road were collected from four locations east to west across the site (SW-01, SW-02, SW-03, and SW-04) and were analyzed for volatile organic hydrocarbons by EPA Method 620013. The sample locations are shown on Figure 2. The samples were placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersville, North Carolina. Chain -of -custody documents were maintained throughout the coilection and transportation process and are included in Appendix A with the laboratory report. The analytical results indicated methyl-tert-buty ether (MTBE) was detected in two of the surface water samples. SW-01 at a concentration of 0.66 ug/L, and SW-02 at 1.1 ug/L. Trichloroethene was detected in three of the surface water samples; SW-02 at a concentration of 0.58 ug/L, SW-03 at 1.6 ug/L, and SW-04 at 2.4 ug/L. The ieveIs of MTBE and T C E detected were below the respective 15A NCAC 2B surface water standards. Surface water analytical results are summarized in Table 7. 97746 J GS012RO376 Page 6 of 8 July 20, 2012 Copyright 2012 Kleinfefder KLEINFELDER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1336.668.0093 f 1336.668.3868 7.0 CONCLUSIONS AND RECOMMENDATIONS The groundwater potentiometric map indicates that the groundwater flow direction at the site is from the southeast to the northwest. Groundwater aquifer characteristics monitored during the sampling event indicate suitable conditions for biodegradation of chlorinated hydrocarbons generally exist at the site. Daughter products of PCE and TCE are present in all ten monitoring wells sampled. Historical chlorinated hydrocarbon contaminant levels generally follow the trends of total VOCs in the wells that are sampled during this hydrogen phase. Each monitoring well containing a HiSOC unit with exception of MW-45 has a decreasing total and chlorinated VOC trend. The increasing chlorinated hydrocarbon concentrations in monitoring well MW-43D and MW-45 is of concern. Surface water sample results indicated trichloroethene concentrations increase upgradient of the groundwater plume and originate off -site. Tricloroethene was not detected in surface water samples collected downgradient of the groundwater plume. Kleinfelder is preparing an injection well permit application to install sixteen injection well perpendicular to the plume near the downgradient extent. The objective of the injection strategy is to decrease contaminant levels prior to migrating farther downgradient. BOD samples results at the downgradient extent of the plume do not indicate that levels are elevated such that competition with the proposed injectant (Regenesis 3DMe) will be an issue. Corrective action monitoring should continue to be conducted an a quarterly schedule and the next event should be scheduled in September 2012. Monthly system checks should also be conducted during the next quarter to monitor the rate of hydrogen consumption of the HiSOC delivery system Copies of this report have been mailed to the Guilford County Department of Environmental Health in Greensboro, North Carolina and the UIC Program in Raleigh, North Carolina, as well as the NCDENR Raleigh Regional Office. 97746 G GSO12R0376 Page 7 of 8 July 20, 2012 Copyright 2012 Kleinfekier KLEINFELDER 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1 336.668.0093 # 1336,6683868 8.0 LIMITATIONS Kleinfelder offers various levels of investigative and engineering services to suit the varying needs of different clients. It should be recognized that definition and evaluation of geologic and environmental conditions are a difficult and inexact science. Judgments leading to conclusions and recommendations are generally made with incomplete knowledge of the subsurface conditions present due to the limitations of data from field studies. Although risk can never be eliminated, more -detailed and extensive studies yield more information, which may help understand and manage the level of risk. Since detailed study and analysis involves greater expense, our clients participate in determining levels of service that provide adequate information for their purposes at acceptable levels of risk. During the course of the performance of Kleinfelder's services, hazardous materials may have been discovered. Kleinfelder assumes no responsibility or liability whatsoever for any claim, loss of property value, damage, or injury that results from pre-existing hazardous materials being encountered or present on the project site, or from the discovery of such hazardous materials. Nothing contained in this report should be construed or interpreted as requiring Kleinfelder to assume the status of an owner, operator, or generator, or person who arranges for disposal, transport, storage or treatment of hazardous materials within the meaning of any governmental statute, regulation or order. Gilbarco is solely responsible for directing notification of all governmental agencies, and the public at large, of the existence, release, treatment or disposal of any hazardous materials observed at the project site, either before or during performance of Kleinfelder's services. Gilbarco is responsible for directing all arrangements to lawfully store, treat, recycle, dispose, or otherwise handle hazardous materials, including cuttings and samples resulting from Kleinfelder's services. The information included on graphic representations in the Quarterly HiSOC Monitoring Report has been compiled from a variety of sources and is subject to change without notice. Kleinfelder makes no representations or warranties, express or implied, as to accuracy, completeness, timeliness, or rights to the use of such information. These documents are not intended for use as a land survey product, nor are they designed or intended as a construction design document. The use or misuse of the information contained on these graphic representations is at the sole risk of the party using or misusing the information. 97746 f GS012R0376 Page 8 of 8 July 20, 2012 Copyright 2012 Kleinfelder KLEINFELaER 313 Gal limore Dairy Road, 6reen5boro, NC 27409 p j 336,668.0093 f 1336,6683868 TABLES TABLE 1: GROUNDWATER ELEVATION DATA Well ID Total Depth (feet TOC) TOC Elevation (feet) Date Water Level Measured Static Water Level feet TOC Groundwater Elevation feet MW-7 29.9 861.19 06/21/12 6.15 855.04 MW-10 33.6 857.68 06/21/12 9.55 848.13 MW-11 25.1 859.26 06/21/12 14.90 844.36 MW-12 16.8 851.50 06/21/12 10.50 841.00 MW-12D 27.0 851.06 06/21/12 10.63 840.43 MW-13❑ 39.4 860.40 06/21/12 13.86 846.54 MW-14 24.8 859.32 06/21/12 22.15 837.17 MW-14D 41.0 859.26 06/21/12 22.94 836.32 MW-15 25.2 857.71 06/21/12 15.00 842.71 MW-16 35.2 863.60 06/21/12 29.21 834.39 MW-23D 57.1 860.90 06/21/12 16.81 844.09 MW-24 58.8 858.81 06/21/12 25.29 833.52 MW-25 168.9 861.47 06/21/12 24.18 837.29 MW-27 44.0 862.74 06/21/12 11.50 851.24 MW-28 23.8 861.54 06/21/12 6.79 854.75 MW-29 18.8 861.13 06/21/12 5.11 856.02 MW-30 73.4 862.28 06/21/12 11.97 850.31 MW-31 19.0 861.73 06/21/12 9.17 852.56 MW-32 19.6 861.76 06/21/12 7.73 854.03 MW-33 21.0 861.77 06/21/12 13.81 847.96 MW-34 21.0 860.45 06/21/12 6.96 853.49 MW-40 29.7 860.62 06/21/12 10.44 850.18 MW-41 20.3 860.52 06/21/12 7.89 852.63 MW-42 35.0 865.32 06/21/12 30.72 834.60 MW-43❑ 53.0 865.47 06/21/12 31.20 834.27 MW-44 28.5 NM 06/21/12 16.32 --- MW-45 36.2 861.79 06/21/12 28.13 833.66 MW-46 32.7 856.73 06/21/12 25.51 831.22 MW-47 32.3 857.17 06/21/12 24.35 832.82 MW-48 30.4 844.07 06/21/12 18.49 825.58 MW-49 35.2 853.05 06/21/12 26.44 826.61 MW-50 19.7 834.67 06/21/12 14.88 819.79 MW-51 14.1 834.49 06/21/12 12.12 822.37 MW-52 13.8 831.87 06/21/12 12.13 819.74 MW-53D 46.0 857.48 M21112 25.94 831.54 NOTES: feet TOC = feet below top of well casing NM = Not measured 97746 1 GS012RO376 July 20, 2012 Copyright 2012 Kieinfelder TABLE 1: GROUNDWATER ELEVATION DATA Well ID Total Depth {feet TOCj TOC Elevation (feet) Date Water Level Measured Static Water Level feet TQC Groundwater Elevation feet MW-7 29.9 861.19 06/21/12 6.15 855.04 MW-10 33.6 857.68 06/21/12 9.55 848.13 MW-11 25.1 859.26 06/21/12 14.90 844.36 MW-12 16.8 851.50 06/21/12 10.50 841.00 MW-12D 27.0 851.06 06/21/12 10.63 840.43 MW-13D 39.4 860.40 06l21M2 13.86 846.54 MW-14 24.8 859.32 06/21/12 22.15 837.17 MW-14❑ 41.0 859.26 06/21/12 22.94 836.32 MW-15 25.2 857.71 06/21/12 15.00 842.71 MW-16 35.2 863.60 06/21/12 29.21 834.39 MW-23D 57.1 860.90 06/21/12 16.81 844.09 MW-24 58.8 858.81 06/21/12 25.29 833.52 MW-25 168.9 861.47 06/21/12 24.18 837.29 MW-27 44.0 862.74 06/21/12 11.50 851.24 MW-28 23.8 861.54 06/21/12 6.79 854.75 MW-29 18.8 861.13 06/21/12 5.11 856.02 MW-30 73.4 862.28 06/21/12 11.97 850.31 MW-31 19.0 861.73 06/21/12 9.17 852.56 MW-32 19.6 861.76 06/21/12 7.73 854.03 MW-33 21.0 861.77 06/21/12 13.81 847.96 MW-34 21.0 860.45 06/21/12 6.96 853.49 MW-40 29.7 860.62 06/21/12 10.44 850.18 MW-41 20.3 860.52 06/21/12 7.89 852.63 MW-42 35.0 865.32 06/21/12 30.72 834.60 MW-43❑ 53.0 865A7 06/21/12 31.20 834.27 MW-44 28.5 NM 06/21/12 16.32 --- MW-45 36.2 861.79 06/21/12 28.13 833.66 MW-46 32.7 856.73 06/21/12 25.51 831.22 MW-47 32.3 857.17 06/21/12 24.35 832.82 MW-48 30.4 844.07 06/21/12 18.49 825.58 MW-49 35.2 853.05 06/21/12 26.44 826.61 MW-50 19.7 834.67 06/21/12 14.88 819.79 MW-51 14.1 834.49 06/21/12 12.12 822.37 MW-52 13.8 831.87 06121M2 12.13 819.74 MW-53D 46.0 857.48 06/21/12 25.94 831.54 NOTES: feet TQC = feet below top of well casing NM = Not measured 97746 1 GS012RO376 July 20, 2012 Copyright 2012 Kleinfelder TABLE 2: ESTIMATE❑ ❑ISSOLVE❑ HYDROGEN CONCENTRATIONS AT INJECTION WELLS Well I❑ Total Depth (feet TOC) TOG Elevation (feet) Bottom Elevation (feet) Date Water Level Checked Static Water Level (feet TOC) Groundwater Elevation (feet) Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (ppm) MW-7 29.9 861.19 831.29 ❑6/21/12 6.15 855.04 23.75 2.7 MW-14D 41.0 859,26 818,26 06/21/12 22,94 836.32 18.06 2.5 MW-15 25.2 857,71 832,51 06/21/12 15.00 842.71 10.20 2.1 MW-16 35.2 863.60 828.40 06/21/12 29.21 834.39 5.99 1.9 MW-24 58.8 858,81 800.01 06/21/12 25.29 833.52 33,51 3.2 MW-25 168.9 861.47 692,57 06/21/12 24.18 837.29 144.72 8.4 MW-29 18.8 861.13 842.33 06/21/12 5,11 856,02 13.69 2.2 MW-43D 53.0 865.47 812.47 06/21/12 31.20 834.27 21.80 2.6 MW-47 32.3 857.17 824.87 06/21/12 24.35 832.82 7,95 2.0 MW-49 35.2 853,05 817.85 06/21/12 26.44 826.61 8.76 2.0 NOTES: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of 1.6 ppm per atmosphere. 97746 1 GSO12RO376 July 20, 2012 Copyright 2012 Kleinfelder TABLE 3: ESTIMATED HYDROGEN CONSUMPTION INJECTION WELL I❑ DATE HYDROGEN CYLINDER INSTALLED ORIGINAL CYLINDER PRESSURE (psi) DATE WATER LEVEL AND CYLINDER PRESSURE RECORDED CYLINDER PRESSURE ON 06/21/2012 (psi) ESTIMATED VOLUME OF HYDROGEN REMAINING (cubic feet) DAYS ELAPSED SINCE CYLINDER INSTALLATION AVERAGE HYDROGEN USE PER DAY (psilday) ESTIMATED DATE CYLINDER MUST BE CHANGED BASED ON PRESSURE MW-14❑ 05/22/12 2,000 06/21/12 1,000 96 30 33.3 07/18/12 MW-15 05/22/12 2.300 06/21/12 1,600 133 30 23.3 08/24/12 MW-16 05/22/12 2,300 06/21/12 1,700 141 30 20.0 09/09/12 MW-24 05/22/12 2.300 06/21/12 2,200 183 30 3.3 03/13/14 MW-25 07/16/12 1,500 MW-29 05/22/12 2,100 06/21/12 1,700 155 30 13.3 10/19/12 MW-43D 05/22/12 2,300 06/21/12 2,200 183 30 3.3 03/13/14 MW-47 05/22/12 2,200 1 06/21/12 1,800 156 30 13.3 10/26/12 MW-49 05/22/12 2.300 1 06/21/12 1,500 125 30 26.7 08/12112 NOTES: psi = pounds per square inch -- = HiSOC returned to the factory or service. All hydrogen cylinders must be replaced prior to the cylinder pressure falling below 100 psi. The HiSOC unit in MW-25 was taken out May 17, 2012 to replace the filter and pressure regulator, and re -installed July 16, 2012. 97746 1 GS012RO376 Copyright 2012 Kleinfelder July 20, 2011 TABLE 4! AQUIFER CHARACTERISTICS FIELD ANALYSIS SUMMARY MONITORING WELL SAMPLE DATE TEMPERATURE { °C } pH CONDUCTIVITY (mSICm) DISSOLVED OXYGEN m 1L REDOX (mV) Preferred Conditions a 200C 5<pH<9 --- <0.5 mg/L a50 mV MW-7 06/21/12 18.17 7.75 0.171 0.37 -113.6 MW-14D 06/21/12 16.20 8.65 0.256 3.22 43.7 MW-16 06/21/12 15.34 7.73 0.431 0.92 43.7 MW-24 06/21/12 15.84 7.89 0.527 0.60 -59.7 MW-43D 06/21/12 15.00 6.57 0.298 0.22 -59.7 MW-45 06/21/12 14A1 6.98 0.434 1.21 -35A MW-46 06/21112 14.28 6.58 0.518 1.98 -35.40 MW-47 06/21112 13.90 6.39 0.279 0.11 -103.90 MW-49 1 06/21112 13.90 6.34 0.294 0.58 2.8 MW-53D 1 06/21/12 14.44 6.93 0.460 0.27 -153.5 NOTES: Redox = oxidation-reduction potential °C = degrees Celsius mSlcm = millisiemens per centimeter mgJL = milligrams per liter, analogous to parts per million mV = millivolts Conductivity is measured for consistency in groundwater sample collection. 97746 1 GS012RO376 July 20, 2012 Copyright 2012 Kleinfelder TABLE 5: SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID 2L COLLECTION DATE STANDARD MW-7 MW140 MW16 MW-24 MW-43D MW-45 MW-46 MW-47 MW-49 M53D W 61211201, 6121112 612112012 6121112 6/2112012 6121112 6121/2012 6121112 W112012 6121112 Volatile organic Compounds by EPA Method 6200D(W911.) Tetrachloroethene 07 SOL 27.7 9.6 a98 356 7A 131 30.8 118 41.9 TnctYoroethene 3 SOL 1.1 1.6 52.9 11.4 5.4 357 108 288 32,7 cis-7,2-Dichloroelhene 70 166 7.2 4-6 249 83.7 3.4 360 155 372 Sao 11-D109oroefhene 7 6.6 SOL 0.82 2.5 9.5 BDL 9.1 1.9 7.3 8.2 %nnyl Chloride 003 140 SOL 4.7 60,8 BDL BDL SOL 1.0 SOL SOL 1,1-Dichloroefhane 6 SOL SOL SOL SOL 3 2 BDL 2.1 0.73 1.9 2.6 Total Chlorinated Hydrocarbons 312.6 36 21.3 1.261.2 4638 15.9 859.2 2974 787.2 673.4 Benzene 1 SOL SOL SOL 57.5 2.6 SOL SOL BOL BDL SOL Toluene 600 12.7 SOL 2A SOL SOL BDL BDL SOL BDL SOL Et benzene 600 518 SOL BDL SOL SOL BDL SOL SOL BDL SOL Total X enes 5W 355.6 SOL SOL SOL SOL SOL BDL SOL BDL SOL MTBE 20 SOL 0.61 SOL 22.7 12.2 SOL 1.3 44 2.8 20.3 Dilsopropyl ether 70 SOL 1.3 BDL 46.2 20.5 BDL BDL 1,3 1.7 17.7 Naphthalene 6 194 BDL SOL SOL SOL BDL BDL BDL BDL SOL n-P(opylbenzone 70 214 BDL SOL SOL BDL SOL BDL SOL BOL SOL Isopropytbenzene 70 66.7 BDL SOL 6.2 BDL BDL SOL SDL SOL SOL 1 2,4-Trimethylberpzene 400 1,120 BDL BDL 3 SOL SOL SOL SOL SOL SOL 13,5-Trime1benzene 400 275 BDL BDL SOL SOL SOL SOL BDL SOL BDL TrIchlonoffuoromethane 2 000 SOL BDL BDL 1 11.4 4.0 BDL 4.7 BDL 3.7 1 1 Total Petroleum Hydrocarbons 2,758.0 1.91 2.4 157 35.3 0 6 5 7 8.2 38 Total VOCs 3,070.E 37.9 23 7 1.418.2 1 499.1 1 15.9 f 865.2 1 303.13 1 795.4 1 711 4 NOTES: 21. Standard = North Carolina Groundwater Standard (15A NCAC 2L .0202), effective January 1. 2010 SOL = Below Detection Limits pgIL = Micrograms per liter, analogous to pans per billion SOLD = Concentration exceeds the 2L Standard MTBE = Methyl-terl-buiyl ether NE = A 2L Standard has not been astshiIshed for this compound NA = Not analyzed 97746 1 GS012R0376 July 20. 2012 Cop^hf 2012 KIniMNdw TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID CHLORINATED HYDROCARBONS (yq -) TOTAL CHLORINATED HYDROCARBONS PETROLEUM jpWLI TOTAL PETROLEUM HYDROCARBONS TOTAL VOCa CdNtUon OaG Tetrachlormthene Trichloror/&A a WA-1,2- Picbi0ro4tHane I.I. DichlwoetMrr Hrryl Chlaride 1,1- Okhlvrwth4n4 1,7- OkhlpoelharM vans•1.2- Oichlorwtlrne 1,1,1- Trwoathena Barsf m Tok*! E n m Total X nn MTBE Dakwpropyl Neoftakne AUIRr NCGS 2L Standard 0.7 3 70 7 0.09 6 0.4 100 200 1 fi00 600 500 20 To 6 MW-7 0WTM 799 I" BDL BDL SOL SOL SOL SOL 59 1.039 650 5,300 1.500 5,7" ROL BDL ROL 13.150 14, 189 0IM4192 SOL 360 ROL SOL BDL SOL ROL BDL BDL 36D 440 3,900 $100 7,100 BDL SOL BDL 13.560 13.940 031T119B SOL Bid SOL 334 SOL BOL BDL SOL 239 592 4" 8,920 2.200 8,990 SOL BOL BDL 20,578 21,17D Mies SOL BOL BDL 723 BOL BOL SOL ROL 347 1,070 253 2,280 2.290 10.900 BDL SOL SOL 15.623 16.693 04Rif43 BDL BDL SOL SOL SOL SOL BDL BDL BS Be SOL 220 2.400 5,700 BDL 60 BDL 8.360 8,468 06rdOi04 ROL BDL 2,300 13DL BDL SOL SOL BDL BDL 2,300 9DL 110 1.800 3,609 SOL SOL 520 6230 6,530 mism ROL ROL 2,100 SOL SOL BDL ROL SOL am 2,100 SOL BDL 1,600 3.020 ROL SOL 520 5,140 7.240 MUM SOL BDL 2,000 14 BDL SOL BDL 1.5 14 2.030 1 1.7 23 370 300 11 2.3 82 871 2.901 12114106 3.6 4 2,100 570 SOL 15 SOL 5.1 13 2,711 4_t 39 1.300 1,40 SOL BDL 440 3,443 6.154 0610we SOL SOL 1,730 ROL BOL SOL WL SOL ROL 1.750 WL BDL 1,040 1,280 BDL SOL 401 2.721 4,471 090OV08 BDL ROL 1,190 BOL BDL SOL BDL BDL BDL 1.190 SOL BDL 7" 673 SOL SOL 301 1,90 3.152 011wM SOL SOL 796 BDL BDL BOL SOL SOL SOL 798 SOL ROL 643 596 SOL SOL 306 1,549 2,347 030WO9 SOL 9DL 935 BDL BDL BDL BDL SOL SOL 935 BOL BDL 749 723 ROL SOL 334 1,856 2.791 W24109 BOL SOL 631 SOL SOL SOL ROL SOL 9DL 631 BDL BDL 589 526 BDL BOL 210 1.325 1.956 O9i02109 SOL BDL 556 6.3 27.3 7.8 ROL SOL BDL 597 BDL E.1 519 468 SOL BOL 283 1,29D 107 12AMM SOL SOL 442 7 42 7 SOL 9DL SOL 497 SOL 9.7 57B 563 BOL BDL 255 1,3% 1.893 03rxm0 SOL SOL X2 SOL 5!1 6.7 SOL SOL ROL 427 6.7 15.8 391 346 BDL SOL 24 960 1A06 061T5110 2.9 SOL 696 62 85.4 7.5 SOL SOL 2-4 802 BDL 122 696 M BDL BDL 275 1.000 2,602 Matto BDL BDL 175 BDL 66.5 BDL SOL SOL SOL 242 ROL BDL 446 679 BDL SO- 232 1.357 1.5% 12709110 SOL BDL 86.9 SOL 12.4 BDL SOL BDL BDL 99 SOL BDL 150 114 BDL BDL 156 420 527 03,24111 BDL BDL 356 5.9 265 9.6 SOL SOL SOL 669 SOL 7.2 333 306 SOL SOL 176 822 1,491 WWI SOL ROL 333 4.1 13b 5.9 BDL SOL BDL 481 SOL 9 1 5% 396 1 ROL BOL 227 1.237 1,718 09r it SOL SOL 331 SOL 192 7 BDL SOL BDL 520 BDL 6 513 321 SOL BDL 198 1.062 1,592 12115MI ROL 60L 306 5 271 f02 60L 8DL BDL _ M ROL B 547 326 BOL BDL 167 7,D62 1.654 03r�7172 BDL BOl 375 7 277 13.7 BOL dOL 9DL 673 6 17 557 379 BOL 8DL 2T7 2,850 3.522 D6121112 SOL SOL 166 6.6 140 1 BDL ROL BDL BOL 313 BDL 12.7 510 355.fi1 SOL I SOL T94 2.758 3.071 MIN-6 abandpned 09127W SOL ROL BOL SOL BDL BDL BOL BDL 8DL i1 ROL BDL ROL 1 ROL SOL SOL 1 1 01114792 BDL BDL SOL BOL SOL BOL 9DL BDL SOL f. BDL ROL BOL BDL BDL BDL 8DL 0 0 95/15192 i BDL BDL BOL BOL BDL BDL BDL ROL SOL D ROL BDL BOL ROL BDL SOL BDL 0 0 M4Y-9 abandcmd O9r27W 1 10 2 BDL SOL BDL SOL BDL 8DL BDL $2 2 BDL BDL ROL BDL SOL 9DL 2 14 01/14/92 BDL BDL BDL SOL BDL BDL BDL SOL BOL G SOL BDL BDL BDL BDL B7L BDL 0 0 0&15W BOL SOL SOL I SOL I BDL L BDL BOL BDL BDL SS SOL SOL ROL ROL SOL ROL BDL 0 0 OW-10 09rd7190 76 T40 BDL SOL BDL BDL SOL SOL 1411 356 2.900 66 BDL 670 SOL BDL BDLM234 36 3,992 01/14/92 SOL 76 ROL 120 BDL BOL BDL BDL BDL 1% Z900 ROL BDL 120 BOL BDL SOL2D 1210 0311 it" ROL BDL BDL 13.9 SOL DDL BDL BDL BDL 14 23.4 SOL SOL BDL BDL BDL BDL 2A6 D5r26199 ROL BDL BOL ROL SOL SOL BOL SOL BDL 0 36 9DL BDL BDL BOIL SOL BDL6 36 10110002 5.9 2.3 BDL 4.4 BDL BDL BOL SOL 7.3 20 220 8.5 16 71 2,200 16 SOL32 2.551 04f22103 32 13 BDL ROL BOL SOL SOL BDL 26 7 47 8DL BOL BDL 1,100 2.9 BDL50 1.157 O6rd0104 SOL BDL 8.1 BDL BDL 8DL SOL BDL BDL 6 22 8DL 2.8 5.0 770 28 8DL3 512 0&16N5 BDL BOL BDL 6OL BDL BDL BDL BOL BDL p 43 9DL BDL BDL 660 BDL BOL 723 723 pBr2Aip6 9DL BDL 3 BDL BOL BDL BOL BDL BOL 3 6.1 BDL BOL 9DL 360 4.3 BOL 372 375 M W-11 D6r3B414 2.1 3 1.A BDL SOL SOL SOL BDL SOL 7 SOL ROL SOL SOL 4.1 SOL BDL 4 11 M15105 5 3.8 9.7 SOL BDL SOL SOL BDL SOL 18 SOL 9DL SOL 9DL 22 SOL ROL 2 21 OW44 4.9 2.5 52 ROL ROL 9DL SOL BDL SOL 13 ROL. SOL SOL BOL 4A SOL BOL 4 17 D6K6= 6.1 1.5 5.D BDL ROL SOL SOL ROL SOL 13 SOL BDL SOL BDL SOL BOL 9DL 0 13 09AM" 9DL SOL. am BDL ROL ROL SOL BOL ROL 0 ROL ROL SOL SOL SOL BDL BDL 0 0 Olmsw 2.7 IS 2.6 SOL BDL SOL SOL BOL BDL 7 SOL ROL ROL BDL 1.1 BDL ROL 1 0 0lum 1.3 BOL 1.5 5% BOL SOL SOL BDL BDL 3 BOL BDL SOL BDL BDL BDL SOL 0 3 06241D9 i.i 1,6 4.7 BOL BOL BDL BDL BDL SOL 13 SOL I SOL SOL ROL SOL SOL BDL 1 14 09i02109 4.4 2.3 SOL BDL 8DL ROL BOL ROL ROL 7 SOL Bl7l SOL BOL BDL BOL BDL 0 7 121D6f09 4 2 5 BDL ROL SOL BDL ROL ROL 11 SOL BDL BDL BDL SOL BOL 3 3 14 03rd01f0 ].7 1.5 3.5 9DL SOL SOL ROL SOL SOL 9 SOL BDL SOL BDL BDL SOL BOL 0 9 C5R211D 3.1 1.4 3.9 BOL SOL BOL ROL BDL BDL 8 BDL BDL SOL SOL SOL SOL SOL 0 8 MW12 OW27190 BDL BDLN.,LL BOL SOL SOL SOL SOL BDL 0 SOL SOL SOL SOL ROL BDL SOL 0 0 01/14/92 BDL BDL SOL ROL BDL BDL ROL SOL 0 ROL SOL 80L ROL ROL ROL BDL 0 0 D3I11196 SOL SOL BOL BDL SOL ROL SOL BDL 0 SOL BDL SOL SOL BDL BDL 9DL 0 0 05+~16r99 ROL BDL SOL SOL SOL BDL BDL ROL 0 BDL BOL SOL BDL SOL BDL ROL 0 0 06Id0l04 BDL BOL BDL BDL BOL BOL SOL BOL O BOL SOL SOL BOL BDL BDL BOL O O 08115i05 BOL SOL SOL BDL BDL SOL SOL SOL 0 BDL ROL SOL BOL BOL ROL BOL 0 O DSri4ip6 BOL SOL SOL SOL BOL BDL BDL BDL 0 SOL SOL BOL BOL BOL BDL BDL 0 D MW12D O9r17i9D SOL SOL SOL BDL BDL SOL BOL SOL BDL 0 SOL BDL BDL BDL BDL $OL EDL 0 D 01114192 BDL BDL BDL SOL SOL BDL ROL ROL BDL 0 BDL BDL SOL BDL ROL SOL ROL 0 0 03i11i9B SOL BDL SOL BDL ROL ROL BOL BDL BDL D BDL 9DL ROL SOL ROL BDL BDL 0 D MGM ROL SOL BDL ROL BDL SOL ROL BDL SOL 0 ROL ROL BDL BDL BDL ROL BOL 0 0 O6r3DI04 ROL ROL SOL SOL SOL SOL BDL BOL SOL 0 SOL BOL SOL ROL BDL SOL BDL 0 0 0WI%5 SOL SOL SOL SOL SOL BDL SOL SOL ROL 0 BDL BOL BDL BDL SOL ROL SOL 0 0 Ow24A76 BDL BDL BDL BDL SOL SOL BOL ROL SOL D BDL SOL BDL ROL SOL BDL SOL 0 i) July 20.2012 97746 1 GS012130376 Page 1 of 6 Copyright 2012 Kieinlower TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID ClLOR1NATEp HYDROCARBONS IIHVU TOTAL CHLORINATED HYDROCARBONS PETROLEUM (pg&) TOTAL PETROLEUM TOTAL YDCi HYDROCARBONS CWlecilon bna Tovachlorow&om Tdchioroe'I rw cis-1.2- OichloroyhaM S,I- Dkhiaarlhani VWyl Chloride 1,1- DkhlorollhalM 1,2• DkhlaoNhane Uanrt.Z- Dkhbroeth4ne 1 1 1. TrichldrglhaM Bo�� Tdt+fM Ethylban=w Tool XylaMs YT$E V.-opyl Naphthalene atha NCGS 2L Standard 0.7 3 70 7 0.03 6 0.4 100 200 1 600 600 500 20 70 6 MW-13 ahamkwwcl 09r26m 2 SUL BDL BDL BDL ROL SOL SOL ROL 2 SUL BDL SDL ROL BDL BDL BDL tl 2 011141W 13D 36 SDL BDL BDL BDL BDL BDL BDL 166 SOL BDL BDL BDL BDL SUL BDL 0 166 0&15192 130 20 SUL SDL SDL SDL SOL BDL BDL 15D SDL SOL SOL BDL BDL BUL SOL 0 150 03MIMA 2.5 4-7 BDL SDL BDL $DL SOL ROL BDL 7 SOL SOL BDL SOL SOL SDL BDL 0 7 0546199 4.2 15 SDL BDL BUL BDL BDL Bm BDL 19 SOL SDL SOL SDL BDL BDL SUL 0 19 D6r3OiD4 BDL 6.5 140 BDL BUL SDL BDL BDL BUL 147 BUL SUL SOL BDL 13 SUL BDL 13 160 00115% SOL SDL 110 SDL BDL BDL SOL SOL BDL 110 SOL SDL BDL SDL SOL ROL BDL 0 110 0Br14W ROL 2.9 110 SDL SDL BDL SOL 1.1 BDL 114 BDL SOL BDL SOL SA SOL SUL 5 119 DsfosD8 BDL SOL 94.7 SOL BDL BDL BDL ROL SOL 95 GA BDL SDL SDL SUL BOL BOL $ 101 D9AXIS8 SUL BDL 679 BDL ROL SUL BDL BDL BDL 68 ROL SOL BDL BDL BDL BDL BDL 0 66 DIAMID9 BDL SOL 68.7 SUL SOL BDL BDL SOL SOL 69 3.2 SDL SDL SDL 52 SUL BDL 8 77 03K)SM BUL SOL 119 BDL BDL SOL BOL SOL SUL 119 ROL BDL BUL SUL 3.1 SOL SUL 3 122 0674109 BOL SOL 81.2 BDL ROL BDL SUL SOL SOL 69 SUL BDL BDL BDL SOL BOL SDL tl 69 09N2A9 BDL BDL 411.6 BDL $OL BDL SOL BDL BDL 48 1.2 SOL BDL BDL 3.6 ROL BDL 5 52 721p8+p9 BOL BUL 57 BDL BDL BDL BDL BDL SDL 57 1 ROL SDL SDL 5 BDL BDL 6 63 M N.130 06liOM4 SUL SOL 18 SDL 1.5 BUL SDL SOL BDL 20 1.1 SOL BDL SDL 26 1.7 BDL 28 48 08/15105 ROL SDL 37 BDL 1.4 BDL BDL BDL BDL 38 SDL BDL BDL BDL 20 1.3 BDL 21 60 o8124106 SDL BUL 30 BDL 1.3 BOL SDL ROL BDL 31 SUL BOL ROL BDL 19 BDL SDL 19 50 D6m5m ROL BDL 21.6 BDL 31 BOL SDL BDL SOL 25 ROL BUL 3.0 3.6 1215 1.7 SUL 21 46 09/04M am BUL 152 BDL 3A SOL SOL SDL BDL 18 SDL SOL ROL BDL 17.6 ROL. SOL 18 36 01105m BDL SDL 17.4 BDL &2 ROL SOL SUL ROL 22 ROL BDL ROL SDL 16.3 1.1 SOL 17 38 0141509 SDL SUL 14-6 SUL 3A SUL SDL SUL ROL 18 BOL SOL ROL SOL 13.4 ROL BDL 13 37 06/24109 BUL BUL 19.2 9.4 4.1 BOL BDL SUL SDL 33 SOL BDL SDL SUL 20.2 BDL SDL 20 53 OWU2+D9 BDL SUL 16,7 BDL &3 BDL BUL BUL ROL 22 BDL SUL BDL BDL 23.1 BUL ROL 23 45 12AWd09 SOL BDL 12 BDL 4 SDL SOL BDL BDL 16 6DL SOL BDL SDL 24 BOL BDL 24 40 03r301fa BDL BUL 8.7 SOL 3 SUL BUL BUL BDL 12 ROL SDL BDL ROL 17.6 BDL SOL IB 30 06;1&10 SOL BDL 7.7 BOL 311 BDL ROL SOL BDL 11 BDL BDL BDL BDL 26.1 ROL SOL 26 37 09=10 BDL SOL 10.7 BUL 4.2 BDL SDL BDL BDL 15 ROL SOL SUL ROL 66.6 SDL SOL 70 85 12MIO SOL BDL 11.6 SDL 4.9 BDL ROL SOL BUL 17 BDL SOL SOL BDL 70.1k BOL SOL 71 87 D3r,141i1 SOL BDL 9A BUL 4.5 BDL BDL SDL BUL 14 BDL BDL BUL BDL 76.9 SDL BDL 77 91 OW14111 $DL BDL 7,3 9DL 4.5 BDL BDL BDL BDL 12 SUL BDL SDL SUL 52i BDL BDL 82 94 09R2117 8OL ROL 5.5 ROL 31 BDL SOL BOL BDL 9 BOL BDL SUL BUL 62.7 SDL SUL 83 92 1211511 S ROL SDL 4.1 BDL 2-6 BUL BDL BDL ROL 7 ROL SDL BOL BOL $0.3 BDL BUL 00 67 UW-14 0912&W 1,300 BDL BOL BDL BDL BDL BDL BDL BOL 1,300 BOL SOL BDL SOL SDL BDL BDL 0 1,300 01114M 1,400 ROL SDL BDL BDL BDL 160 BDL 100 1,680 SOL 60 BDL 100 BDL ROL BDL 1€A 1,840 03111M Ise BDL BUL BDL SOL SOL ROL BDL BUL 80 BDL SUL BDL SUL SUL SUL BDL 0 SO 05125% 67 BDL SOL BUL BUL ROL SUL BDL SUL 67 BDL ROL SDL BOL BUL SOL SUL 0 67 041=3 110 BDL SOL BDL BDL SOL ROL SOL SUL 110 1.1 1.7 BDL 1.9 BDL BDL BDL 5 115 O6rZ 04 6o ROL. BOL SOL BDL SOL BDL BUL ROL BD ROL SOL BOL BDL SOL ROL BUL 0 80 D8116M Sd BUL BDL BDL SOL BDL BUL BUL BOL 56 SOL SDL BDL BDL BUL BDL BUL 0 56 68r141W 46 BDL SDL SUL BUL SOL 6DL SOL BDL 46 1 SOL BUL SOL BDL SOL BDL BDL 0 46 0610.JD6 S4.0 BDL SOL BDL BDL SOL BOL BUL ROL 54 SOL SOL SOL BUL ROL BDL SOL 0 54 091D41D8 50-0 SOL SOL SDL BDL BDL BDL SDL BDL 50 BDL BDL BOL BDL SOL BDL BDL 0 50 0110509 29.0 SOL SOL SDL BDL SDL SOL SOL BUL 30 BDL BDL ROL SIX BUL 6D1. SUL D 30 OIVS09 32 SDL BDL BOL BDL SUL 6DL SDL BDL 32 ROL SDL SDL BDL ROL SUL BDL 0 32 0&241D9 31.2 BUL BUL SOL BDL SUL BOL BDL BDL 31 BDL BUL BDL BUL BDL BDL SUL 0 31 OW2R79 23-6 BUL SDL ROL SOL BUL SOL SDL ROL 24 ROL ROL SOL SOL SDL ROL BDL 0 24 12M&W 17 BDL BDL BOL BUL SDL SOL BDL SUL 17 BOL ROL BUL BDL SDL BDL SOL 0 17 031=10 19-7 BDL BDL SOL BDL SUL ROL BDL BDL 19 SOL BDL BOL ROL BDL BDL BDL 0 19 0W15110 13.3 BUL BDL SDL BDL BUL SOL BDL BDL 13 BDL BDL SDL BDL BUL ROL BDL 0 13 D9t22110 15-7 BDL SOL SOL SUL SOL SOL SOL ROL 16 SOL BDL BDL BDL BDL SOL SDL 0 16 12AMIC 14.5 BUL SUL SUL BDL BUL SOL BDL BDL 15 BUL SOL SOL BDL BDL SOL BDL D 15 D394111 14-6 SOL SOL SUL BOL SDL ROL BDL BOL 15 SOL SDL BDL BDL BDL BDL BDL 0 15 06114/11 11.9 BDL BDL BOL SUL BDL BUL SDL BUL 12 SOL BUL SDL ROL BDL SUL SOL 0 12 09raii1 f2 BDL ROL SOL BUL BOL SUL BUL BDL i2 6DL SUL SUL BDL BDL SDL SOL 0 12 1211&11 12.3 SDL SOL SUL ROL BUL BDL BDL BDL 13 BDL ROL BOL BOL SOL SDL BDL 0 t3 July 20, 2012 97746 1 GS012RO376 Page 2 of 6 Copyright 2012 KWWtk w TABLE 6. HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID CHLORINATED HYDROCARBONS (yyrL) TOTAL ChILIXiINA TFD HYDROCARBONS PETROLEUM Sv1KLI - TOTAL PETROLEUM HYDROCARBONS - - -- TOTAL VQCs Cdkcuan Dili Tltrechlorvll7re ne Trknlorpelfre ne [It OkhWroM7iene Okhlaa![Hene V1mo ChWii* 1,1- 1,2• Okhlprpitlµ/y DkhlOroNham pa�u-1.2• 01chtvfo& me 1,5.1" Trichlapltharre So Tot�''4x E11y1Wh m TOW %yb! MTBE DYioWOpyl Ater Niphthikne NCGS 2L 5tm d 0.7 1 70 1 0"03 6 04 100 200 1 i00 600 go20 70 6 MW-140 0W27M 110 3 SOL 55 BOL 5 BDL SDL 20 196 45 1 ROL 5 ROL SUL BOL 51 1 247 01114192 200 BDL BDL SOL ROL SOL SOL 8DL SDL 200 65 3 BDL BOL ROL SOL ROL 68 268 DU15+92 56 BDL SOL 2.1 BDL BDL SOL BOL ROL 58 4.7 am SQL BDL ROL ROL BDL S 63 D.970919Q 210 SOL SDL 23 ROL ROL BDL SOL 13 246 2" BOL ROL BOL BDL ROL SOL 220 466 nil]% 35A ROL SUL 10.6 BDL SQL BOL SOL ROL 46 5.6 SOL BOL SOL SOL BDL BDL 6 52 DWS99 201 BDL BDL 25 SOL BDL BDL BOL BDL 226 67 BDL SOL ROL BDL ROL SDL 67 293 101f0102 79 2.8 BDL 4 BDL 41 BDL BOL SOL 90 013 BOL SOL BDL 11 29 ROL 48 138 OdA21D3 40 BOL SOL 12 BDL BDL SOL SOL BDL 41 BDL ROL ROL BOL SOL 1.0 BDL 2 43 D6r-A pi 29 SOL 10 15 BDL 21 BDL BDL SOL 35 BDL SOL ROL SOL 3.3 BDL 9DL 3 35 08116/05 55 1.8 15 33 SOL SOL BDL SDL ROL 75 5A BDL BDL RDL 3.2 7"3 ROL 16 91 06724/06 47 2 17 1,4 BDL SOL BDL SDL SOL 67 1.3 SDL BDL BDL 2"4 6.4 SOL 10 7$ D3fl71p9 10.$ BDL 1"0 BDL ROL SOL SOL ROL BDL 12 ROL ROL SOL ROL ROL BDL SOL 0 12 ow4109 1161 SOL ROL SOL ROL ROL BOL BDL BDL 12 SOL ROL SOL SOL BDL SDL BDL 0 12 0990M 27.1 14 8.8 BDL ROL BDL SOL BDL ROL 37 1"6 ROL SOL ROL 1.3 7.9 SDL 6 43 12A&D9 13 SOL 2 SOL BDL ROL am 8DL SOL 15 SOL BOL BOL SOL ROL SOL SOL 0 15 0373p110 9.6 8DL am 9DL SOL SOL ROL BDL ROL 10 BDL SOL ROL BDL SOL SOL SDL 0 10 061 yle 117 BDL 22 SOL SOL BDL ROL SOL BDL 14 BOL SOL BDL SOL SDL 1 BDL 1 15 09=10 104 4.1 36"6 SOL 1.0 BOL BDL ROL ROL 147 6-5 SOL BOL SOL 28 5.9 SOL 15 162 1zw10 107 A7 28,2 9Ck SOL BDL SOL ROL SOL 139 5.4 SOL SDL SDL 1.7 3.5 ML 72 151 DN24111 59 22 1717 SOL ROL SOL BDL BDL BDL 79 1.5 SDL SDL SOL 1 22 SOL 13 92 OPJ14111 1" 4.2 32.8 ROL to SOL SAL SDL BDL 147 2.5 SOL BDL 8DL 2"0 5"1 BOL 71 158 09rmlI 167 8.2 69A RQL 4.2 SDL SOL BDL BDL 260 8"3 BDL 39 SOL SOL 6.8 ROL 24 292 12l1S51 $4 BDL 3.0 BOL SOL BDL BDL BDL ROL 17 SOL BDL BDL SOL BOL BDL BDL 0 17 =7112 37 1.S 91 SQL 1.7 SOL BOL BDL BDL 49.9 BDL BDL BOL H[7L 1 1"6 SDL 2-6 52 D612V12 277,7 1.1 72 SOL SOL SOL BDL BDL SDL 36.0 8O4 ROL am BOL 0.61 1.3 ROL 1.9 36 MIN-15 09R719D SDL ROL ROL SOL SQL BDL BDL BDL BOIL 0 BDL BOL SOL ROL BDL SOL BDL 0 0 0101AW SOL BDL ROL BOL BDL BDL SOL SDL SOL 0 BDL BOL ROL BOL BDL SOL ROL 0 0 03r11798 ROL ROL SOL BOL SOL BDL SQL SOL SDL 0 ROL UP 8DL BDL SOL SOL SOL a 0 05R599 4-9 3 SOL BOL SOL BDL SOL SOL BDL 6 BDL ROL ROL SDL BDL BDL ROL 0 6 faM0102 13 7.6 ROL SOL SOL 1.4 BOL SOL BDL 22 BDL SOL SOL BDL 29 BDL ROL 29 51 D4f22103 11 5 BDL BDL BDL 1.4 ROL ROL SOL 17 SDL BDL SOL BDL 17 ROL SOL 17 34 06/30/04 7.5 3.5 a6 SDL SOL SOL SDL SOL SDL 97 BDL SOL ROL SDL 18 SOL BDL 1a 115 08r16105 6"6 2"3 67 BDL 8DL BDL BOL SOL BDL 55 80X SDL BDL 9L7L 15 BDL BOl 15 71 OW4% 5.5 5 68 BL7L $C1L ROL SOL BDL SOL 59 8DL BDL SDL SOL 8 8DL BDL a 67 MW-14 D91AM SDL BOL BDL SOL BDL ROL BDL BDL BDL 0 BDL BDL BDL ROL. ROL SOL BDL a 0 01114= ROL BOL BOX BDL ROL SOL BDL BDL ROL 0 SOL SOL BDL BDL ROL BDL BOL 0 0 OCY11198 169 BDL SOL SOL BDL ROL SOL BDL BOL 2 ROL ROL BDL ROL BOL BDL ROL 0 2 O6t02199 2-4 SOL BDL SOL ROL ROL BDL SOL BDL 2 am BOL SOL 831L BDL BOL ROL 0 2 1011DV02 22 3.8 BDL 18 BDL ROL SOL ROL SQL 28 SOL BOL BDL SOL BDL BDL ROL D 28 D4R2103 46 5.6 8DL 3-6 BDL SOL SDL SDL SOL 58 BDL SOL Boi- SOL SDL ROL SOL 0 58 DGGD/04 31 7.6 24 27 BDL 1 SOL BDL BOL 66 SOL BDL ROL BDL BDL BDL BDL 0 66 0&15435 30 4.4 BDL 1.6 ROL BDL BOL BDL SQL 36 BOL BDL SOL SOL SOL '7 BDL 17 53 Ows" 36 764 31 29 ROL BDL SOL am ROL 77 SOL BDL SOL 8DL 8DL ROL 9DL 0 77 mmula 4.1 BDL 3"7 BDL SIX BDL SDL ROL BDL 8 BDL 1-8 BDL SDL SOL BDL BDL 2 10 12109110 16-7 2.1 a.2 1.3 1.7 6DL ROL SOL BDL 30 SDL BDL SDL SOL BOL SOL SOL 0 3D =4111 8.9 14 6-3 BDL 5-5 BDL SOL BDL ROL 22 SDL SOL SDL BDL SOL BOL SOL 0 22 0&14111 221 3A 101 1.8 2.8 ROL BOL ROL 6DL 41 ROL SOL ROL BDL ROL SDL SOL 0 41 D9l221S1 36 1 5 2217 3 2A BDL BOL 9Q4 BDL 69 SOL BDL BDL BDL BDL BDL SOL 0 69 1211511 4.9 BDL 32 BDL 14 BDL SDL RDL 9DL 14.5 9DL BDL BQL SOL BDL BOL SDL 0 15 M7112 1315 2"0 6-0 0.96 32 SOL BDL SOL 8DL 25 SDL 0.09 SOL BDL BDL BOL BDL 1 26 O6f21112 9.6 11 4.6 0.ffi 4.7 ROL 6DL 8DL BDL 21 BQL 24 ROL SOL $OL S0L BOL 1 24 KW-17 *Ondorkod 01/03106 ffirA90 1 SDL SOL SOL ROL BDL SOL BDL BDL 1 BDL ROL 9DL SOL SOL ROL SDL 0 1 01014M ROL S BDL Si)L BDL BDL BDL BOL 80L 3 ROL aQL ROL SDL ROL BDL ROL a 3 00111198 BDL BOL BOL 9DL SQL BDL ROL BDL BOL 0 1'JOL SDL ROL BDL SDL BDL BDL 0 a DBM2199 BOL SOL I SDL BOL ROL BOL BDL BDL 8OL 0 SOL 9DL ROL SQL SDL SOL SOL 0 0 O61xwd BDL I ROL f ROL I SOL SOL BDL RDL SDL BDL 0 BDL BQL BOL $OL 17 BDL BOL 17 17 MW-230 09R7190 ROL 2 SOL BDL SDL 5 5 ROL SOL 12 1 BDL BDL_ SDL SOL BDL BDL 1 13 01114192 SOL BOL ROL SOL BOL BOL BDL SDL SOL 0 BOL ROL BDL SOL SOL ROL BDL 0 0 O'W1592 SOL 262 BDL ROL BDL 5.3 SOL SDL BDL a 45 SQL SOL ROL ROL BDL ROL 45 53 09K)9t42 IA 6"3 ROL 5.4 ROL 6"5 2 SDL SDL 22 43 SDL BDL SDL BDL ROL ROL 6 28 030IM 2.5 265 am 1.4 SOL 29 ROL BDL 4 13 71 3.1 BDL SOL SOL BDL BDL 11 24 05r28199 SDL 461 SOL 2.4 BDL 5-7 Z6 BOL BDL 15 3-1 SDL SOL BDL SOL SOL BDL 3 18 06r.50rD4 6DL R6L 200 SDL BDL BOL SOL BOL BOL 210 BOL BDL BDL ROL 500 12 ROL 512 712 0&751a5 BDL BQL 280 6DL BDL BQL BDL SOL BOL 280 SOL BDL BDL BDL 3f0 BOX BDL 370 590 July 20, 2012 977461 GSO12R0376 Page 3 o! 6 Copyr l 2012 Kle-lelder TABLE B- HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID CHLORINATED HYDROCARBONS (pgA-) TOTAL CHLORINATED HYDROCARBONS PETROUuM {V9til TOTAL PETROLEUM HYDROCARBONS TOTAL VOC. C011ecOpn pMe TatgchbrdeMane Trlchloronhsne cls-1,2- Dkhko fhene I.I. DlchMproathene YlnytChkwide 1,1- Olchlwmthene 1,2- Dkhlonxrd r lra�1.2• DkhloroeltMne 1,1,1- Trkhkwcelha ne 8enune Tol em EUyl6ensene Tolel%ylenes MTSE 011swopyl womr Naphlhelene *CGS 2L 8mm"re 01 3 70 7 CA3 6 0A 100 200 1 600 600 500 20 70 6 0=4106 SDL 1.1 340 SDI- 1-0 RIX SDL BDL BDL 343 IA SOL SOL SOL 310 So 6DL 321 664 06m wGB SOL BDL 1" BDL BDL BOIL BDL BDL SDL 166 SOL SOL 20.2 23.6 208 BDL SDL 252 418 MW-230 Cant 09144N8 SIX BDL 5.3 SOL SOL BDL SDL BDL BDL 5 BDL SDL SOL BDL 19.3 8DL BDL 19 25 01105w SOL BDL 15.3 SOL SDI- SDI. BDL 60L SDL 15 BOL BDL BOL SOL 37A SOL SDL 38 53 03AMM SDL SOL 173 BOL 11.4 1.1 BOL SOL SOL 194 1.7 BDL BDL BDL 194 BDL BDL 19G 389 OW74M BDL SOL 107 SOL SOL BDL BOL SOL 6DL 107 BOL BDL BDL BDL 331 BDL. SOL 331 438 09102M9 SOL SDL 140 BDL 215 BDL BDL BDL BDL 1 164 2-7 BDL BDL BDL 317 6.4 BDL 326 49D 12A)SW BDL SDL $34 SDL 25 2 SOL SDL SDL 1160 3 BDL BDL SOL 393 7 SOL 403 563 03/30/10 SDL SDL t1i BDL 24.7 ROL SOL SOL BDL 141 24 BDL BDL BOL 417 5.9 BDL 456 5% 06115MO SOL BDL 176 SOL 43.9 22 8DL SOL SDL 222 4.6 BDL BDL BDL 751 10.5 SOL 766 988 09/22110 SOL BDL SDL BDL BOL SDL SDL BDL BDL D BDL BDL SOL But. 1.3 BDL SDL 1 1 12AMID SOL BDL 21LS SOL 2.6 BDL BDL SOL BDL 24 BVL BDL SOL SOIL 2" BDL SOL 211 235 =4111 BDL BDL 0.1 BDL 17A BDL BDL SOL BDL 26 BDL SOL BDL BDL 300 2.1 SOL 302 32B OW14111 SOL BOL SOL SDL 62A BDL SDL BOL SOL 62 24 BDL SDL BOL 915 6$ SDL 824 S87 0922711 BDL BOL SOL SOL 15.8 SDL SOL BDL BDL 76 SOL BDL SOL SOL $86 7.1 BDL 993 1,069 12I75111 SOL BDL BDL SOL to BDL SDL BOL BDL 1.6 BDL SOL BDL BOL 43-7 SDL SOL 44 45 MW24 ODA7190 630 28 BOL 60 BDL SOL SDL BOL SDL 718 1,500 BD SDL 80 BDL SOX BDL 1,660 2,378 61/14/92 3,800 110 B➢L 200 BDL BDL 56 SDL 80 4,246 1,800 260 BDL 340 BDL 8DL SOL 2.400 6,646 05/15/92 lAw 26 SOL 4.9 SDL BDL SDL BOL SDL IA30 1,500 180 BDL BOL BDL 8DL BDL 1.980 3,410 09t09192 2,700 BDL BDL BDL SOL BOL BDL BDL TO0 2,800 2,500 150 BDL 150 SOL SOL BDL ZWO 5,6010 mime 1,230 BDL BDL SOL SOL BOL BDL SOL BOL 1,230 1,920 SOL BDL SDL SOL BDL SOL 1.920 3.150 05r25199 637 BDL BDL BDL SCL BDL BDL BDL BDL 6.37 1,510 ROL BOL BDL SDL BDL SOL 1,510 2,147 1D110102 2.000 68 SDL 31 SDL 11 Z5 BpL 4.9 2,117 1,700 16 1.4 27 180 530 SDL 2,454 4,572 0412m 640 24 BDL 17 BDL 6.4 SOL BDL 1.8 6B9 500 GA BDL 6-3 a 180 BOL T74 1,463 0&WM4 870 SDL 370 BDL SOL SOL BDL BDL SOL 1240 280 SDL BDL BDL 74 200 SDL 55d 1,794 OW16105 1.300 62 570 BDL SOL BDL SOL SOL BDL 1,932 420 BOL BDL SDL 69 170 SDL 6S9 2,591 03r24106 2,200 84 T70 15 SOL 6.4 1.2 1.2 55 3,083 660 4-8 SOL 10.4 78 ISO 5.6 919 4,602 06MGM 1,640 SOL 545 SOL BDL BDL SOL SOL SOL 2,V5 210 BDL BOL BDL 55.1 140 SDL 405 2."0 09I04I08 1,430 5117 348 SDL BDL BDL BDL SDL SOL 1,831 253 SOL SDL SDL BDL 60.3 SOL 313 2.144 0 1 A rVD9 1,610 78A 517 BDL BDL BDL SOL SOL SOL 2205 290 BDL BDL BDL 70.9 116 SOL 467 2,672 oao 1,250 BOL 4" SOL SOL BpL 6DL BDL BDL 1,716 117 6pL SOL SOIL SOL BDL 6DL 117 1,633 0624r09 434 SOL 119 BDL SDL SDL BDL SOL BDL GD3 BDL BDL SOL SOL SOL SOL SOL 0 603 0902m 946 127 7" 1.7 1211 6.2 SOL BDL SDL 1.970 537 BDL SOL 13.7 77,5 16S 1S'S 841 2,811 12MBM 1.650 119 S33 6 25 SDL BDL SOL BDL 2.303 207 BDL BOL 5-8 41 67 SDL 352 2,656 033w10 163 1011 47.2 SDL 362 1 BDL BDL SOL 258 172 BDL SOL SOL 12-4 20.1 SDL 50 3D7 06115'10 1,000 42A 267 8DL 77,5 BDL SOL BDL BDL 1,387 1" SOL SOL. SDL 29.2 68.3 SOL 28O 1,667 09/22/10 1.080 71.4 362 BDL 48 BDL SOL SOL SOL 1.561 110 BDL BOL BDL 24 42A 27-4 210 1,779 12/09/10 1,140 53 379 601. 64-5 SDL BDL SDL SOL 1,637 126 SDL SOL SOL 33 WA 39.1 264 1,901 03/24/11 S47 66 356 BDL 104 SDL 8DL BDL EEL 1.401 130 BDL SOL 8DL 2%5 39 SOL 199 1,680 W14111 1,130 5719 369 SDL 152 SDL BDL BDL BDL 1,571 BOA SDL BDL SOL 24.6 47,6 11 164 1,735 09R2111 am 41.4 337 SOL 15.5 BDL DDL BDL BDL 122E 87A BDL BOL 6IL E7 O VS BDL 163 1,391 12/15/11 807 70,6 368 BDL 62.3 SIX SDL SDL SOL 1,306 88A SOL SOL 8DL 1.6 312 BDL 156 1,464 0W7112 537 272 134 BDL 67.2 SOL BDL SOL SDL 765 34,9 2.5 ROL 8DL 19.6 29.1 12.0 111 876 06121112 996 52.9 240 SDL 60.0 2.5 SOL BOL SQL 1.261 67.S SOL BDL BDL 22.7 462 SOL 157 1,418 MW-2S 0w71198 8.9 3.5 SDL SOL SDL BDL SOL BDL SDL 12 BOL BDL BOL BDL SDL SDL SDL D 12 0526199 10 3.6 BDL BDL SOL SDL BDL SDL SDL 14 BDL SOL SDL BDL BDL BOL SOL 0 14 OG✓3Ot04 ILI 3.5 9.9 SOL BOL BDL SDL BDL SOL 22 BDL SOL SOL BDL BDL 4,4 BOL 4 26 OBISW05 17 3-9 31 SOL BDL SOL SDL BDL SOL 52 SOL BDL BOL SDL 3.6 SOL BDL 4 56 0B1.16" 20 4.8 51 BDL SDL SOL BDL SOL BDL 76 BOL SOL SOL WL 1.B 4.3 BDL 6 82 o6m5 B 11.7 3,2 23.5 SOL SDL BDL BDL BDL BDL 38 SOL SOL 1.3 BDL 21 42 SOL 8 46 091O4A6 10.7 5.2 331 BOL SOL BDL B0L BDL BDL 57 SDL BDL SDL BDL 3 4.8 8DL B 65 OIXA09 1" 6,5 46,6 t.f BDL ti SOL SOL BDL 78 BOL SOL SDL BOL 4.9 6.2 BDL 11 89 03AV 09 24.9 8.3 51 1.1 BDL SDL BDL BOL SOL B5 SOL BDL SOL SDL 4,8 BDL BDL 5 90 OSQV09 301 7A 54.7 2A SDL SDL BOL SOL BDL 95 SDL BDL SOL BDL 5.9 6.9 BDL 13 108 OWWR9 24.8 73 60.1 1.16 BOL 1.1 SOL SOL. SOL 96 SOL BDL BOL SDL 0.9 9.1 BDL 16 114 12RHM 27 9 54 2 BDL 1 BDL SOL SOL 92 1 8DL SDL BDL 15 13 SOL 29 722 OW010 11A 6.0 44.1 1.3 BDL BDL SOL SOL SOL 72 11 SDL SOL SOL 12.3 124 BOL 26 97 DW15110 17.7 6.1 36.9 1.4 BOL SDL BDL am SDL 62 IA SOL BDL SDL 15.9 141 BDL 32 94 ow=10 17.5 517 412 1.3 BOL SOL 8DL SOL BD=Ll 1.9 SDL BDL SOL 27.4 10-3 BOL 47 113 12/09110 2zi 7 49 1.5 BDL 1.1 SOL BDL SOto SOL BDL SOL 28.6 20A SOL 51 132 OM4111 26A 94 6219 1.9 BDL 1.3 SOL SOL SD1,7 SDL SOL 6OL 24 17.6 BDL 43 144 OW14111 36 11.4 74 2-8 SOL 1.6 BDL SDL BD1.7 BDL BDL BDL 25A 18.5 SOL 46 171 09R2111 35 1,7 1 3.1 BDL 1.7 SDL BDL BD1.5 BDL BDL BDL 27.3 18,9 SOL 48 164 12/15/11 1.4 Bpl 5.5 BQL BDL SDLSOL SDL SDBDL BDL BDL SDL 4.13 1.3 BDL 6 13 }eW26 aWnaarre Q7103f06 077p7104 SOL SOL SDL BDL BDL SDL SOL BDL BDL 0 SOL BDL BDL SDL BDL ROL SOL 0 O OB115105 SDL BDL BOL SOL SOL SDL SOL SOL I ROL H 0 11 BOL I SOL I 5GL I SOL SOL SOL BDL 0 f July 20, 2012 97746 1 GS012RO376 Page 4 of 6 Copyright 2012 KlVnfeMel TABLE 5: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE ID CHLORINATED Hl'DROCARBDNS (PAIL) TAL CHLT❑DRl"TED H YpROCARSDH5 PETROLEUM (Pq&) TOTAL PETROLEUM HYpROC ARBDa15 TOT ALVOCs CON46tlon O&W Trlrwh;o there TriChlprdelhmn4 CIA-1.2- DIENorogum 1,1- Dkhlwmlhene VkrylChkr111A 1.1- DIChlor0e7han4 1,2- oklNaroetlMlN 177ny1,2- BiChlprpWlam 1,1,1• TrICeloroethane Bannlne Toluene Ethykw nm TrialltykrMS YTBE DO40propyl 4tl16r Naphthalene NCGS2L Standard 0.7 ] 70 7 0.03 6 0A 190 200 1 NO 600 500 20 70 6 MW-27 1 DI10V02 SOL SOL BDL BI7L RL7 BDL SDL SOL SOL 0 2-3 2 47 18 2.3 SOL BDL 72 72 07A7ro4 ROL SOL BDL RPL RILL BDL BDL ROL 60L D 11 2.7 34 7-9 11 BDL 17 78 76 OB116A5 SOt SOL BDL SOL BDL BDL S]L ROL SDL 0 12 4.1 180 34 3.5 BDL 30 264 264 11A1106 BDL BDL ROL SOL ROL BDL SOL 9DL ROL 0 6-2 2.4 38 3-7 SDL &]L 16 6s 66 1A1Y-28 1Dr7DA72 BDL BDL SOL 80L 8DL BDL BDL ROL SDL 0 10 2.2 45 22.5 SOL 2.3 SOL 82 82 07/01/04 ROL SOL SOL SOL 8DL RDL BDL SOL BDL 0 95 Fl 1,500 1.065 BDL SDL 490 3.191 3,191 ❑B11 r,J05 8DL SOL BDL BDL SOL 8DL 8DL ROL SOL 0 210 78 2,300 750 ROL ROL 740 4,078 4A?8 D845w SDL SIX BDL SDL BDL BDL BDL BDL SOL ❑ 170 56 2,500 1,200 BDL SOL am 4.726 4,726 12UM6 SOL BOL BDL BDL SOL BDL BDL BDL BDL D 100 BDL I 2,500 530 BDL 8DL 940 4.070 4,070 M1V-28 07001104 23 SDL 200 BDL SOL ROL ROL SOL SOL 303 SOL BDL 21 ROL SOL SOL 8DL 21 324 whiz 39 4.2 29 SOL BDL SOL SDL SOL SDL 72 BDL SDL 8DL SOL SOL SOL SDL 0 72 OW25A6 5 38 BDL BDL SDL BDL SOL ROL 45 U BDL I SOL SOL BDL I SOL I SOL Bp4 0 45 NW-30 07A7A4 BDL ROL SDL BDL SOL SOL BDL SOL ROL 0 BDL BDL ROL BDL 2.200 SOL BDL 2,200 2,20Q ❑MK5 BDL SOL 200 43 77 SDL SOL SDL SDL 320 74 80L 58 SOL 510 SOL SOL 642 962 Dw5A6 SOL SIX 23 2.5 16 SDL BDL SOL SOL 42 23 BDL 2-6 2 1.500 13 19DL 1.541 1.582 M W-31 1(viow SOL SDL SOL SDL ROL BDL BOL ROL SOL 0 BDL 320 2,600 7.900 RPL BDL ROL 10,620 10.020 04Y22103 BDL BDL BDL RDL BRL BDL SDL BDL SDL 0 BDL 35❑ 7,60a 4,600 8DL SDL SOL 6,710 6.710 07/01104 SOL S]L 53 BDL SOL BDL ROL BDL SDL 53 78 R4 590 1.360 8DL BDL 400 2.452 2,505 08/15/05 SDL BDL 48 ROL SOL BDL SOL SOL 90L 48 SOL fi7 1.100 1.490 BDL SDL 750 3.407 3,455 11101I06 ROL ROL BDL SOL BDL SDL SOL SOL BDL 0 BDL SOL 1.700 390 SOL SOL 720 2.010 2.010 VW-32 071011D4 SOL SDL ROL SOL SOL BDL BDL SOL BRL 0 BDL ROL SOL BDL 290 ROL ROL 290 290 OB115105 SDL SOL BDL ROL BOL SDL BDL BOL BOL D BDL BDL BOL SDL 180 SDL BDL 18Q 180 ❑B12r SOL BDL 96L SOL SDL BDL BDL BDL BDL D 1,400 280 11 21 19A00 32 S60 17.662 17,662 11A1A6 ROL SOL SOL ROL BDL SOL SDL SDL BOL Q 1.400 am 340 900 20,000 RPL SOL 22.96❑ 22,960 12114A6 ROL SOL ROL SOL BOL BDL SOL ROL RPL D 1.500 3,700 1,700 8,000 16.000 ROL 1,100 32,0D0 32.0D0 MW33 1011=2 SOL BOL SOL BDL SOL SOL Sm BDL BpL 0 RPL 9OL SOL BDL 10 BOL SOL 0 0 O6r3w4 SOL BDL 1.G BOL BOL SOL ROL BDL BDL 2 BDL BDL 8DL ROL BDL ROL SOL ❑ 2 0B115A5 SOL BOL 5.6 BOL BOL BDL SOL ROL ROL fi SOL BDL BDL BDL SOL BDL BDL ❑ 6 D8725b6 BDL SOL 5.7 ROL SOL ROL SOL BDL SOL 6 BDL BDL SDL BDL SDL SDL BL7L 0 6 M W-34 041221p3 SOL 100 BDL 4S BDL 7.2 BOL SDL SDL 722 BOL SDL SDL ROL BOL BDL 8DL 0 122 07A1A4 BDL 730 63 6.3 BOL 1A BDL BDt ROL 2D7 BDL BDL BDL BOL 8DL RDL SDL 0 2O7 08176N5 RPL 90 37 RPL ROL BDL BDL RDL ROL $27 BDL SOL RDL BDL SOL SOL BDL ❑ 127 0825A6 SOL 59 24 4.6 BDL 2.3 SDL BDL SQL 9D SDL SOL BDL SOL SOL RDL RDL 0 8p MW4O 11101/06 BDL SOL ROL BDL SOL ROL BDL SOL SDL 0 250 230 280 552 SOL BDL 130 1,442 1,442 030W10 SOL ROL 5.1 BDL ROL SOL SOL SOL ROL 5 191 350 385 649 SOL 0.87 145 965 990 Y W-41 ❑4Yt7/63 SDL SDL BDL ROL ROL SOL SOL SDL SOL 0 7.200 6.600 2.4110 10.800 BDL SOL ROL 77.000 27,000 07M04 BDL ROL ROL BDL BDL SOL SOL SOL SQL D 7.000 6,600 2,600 13,300 SDL a, 770 30,790 30.790 OB71fi105 SDL SOL SDL SOL WL ROL BOL SOL ROL 0 5,400 4.11K 2.500 0.700 BDL 2]0 780 23,510 23.510 081241D6 SOL BDL BDL BDL RDL ROL SOL SOL BDL 0 3.100 3,000 1,000 2.900 BDL 6-4 16 10,022 10,022 03WID SDL SOL SOL SOL SOL SOL SOL ROL SQL 0 ],110 3,790 2,750 18, 560 BOL 23.3 747 1A,d 17 14.417 YW42 DIPOM6 36.6 ROL 7-5 &1 SOL 1.s SOL BDL BRL $1 BDL BDL SOL BDL BDL BDL 3.2 3 54 0&25% 2tii ROL 4-7 3-5 SOL 1,5 SOL BDL BDL 37 BDL BDL ROL SOL ROL BOL SOL 0 37 061451❑B 5.3 SOL SOL SOL SOL SOL SOL BDL SOL 5 SOL SOL RDL ROL SOL SOL BDL ❑ 5.3 DWD4108 5,7 SOL BDL ROL SDL SOL SOL SDL SOL 6 ROL ROL ROL ROL ROL SOL am 0 5.7 01A5009 5.3 BDL BDL SOL SOL SOL ROL RDL BDL 5 SOL RDL BDL BOL SOL RRL ROL 0 5-3 Dwsw 2-7 SOL SOL BDL SOL SOL BDL SOL. SOL 3 SOL SOL ROL BDL SOL SOL BDL 0 27 OW4109 3.1 BOL 8DL BDL SOL SOL BDL ROL BDL 3 SOL SOL ROL ROL SOL SOL BDL 0 3-1 09A210B 3.4 BDL 8DL S7L ROL RDL SDL SOL ROL 3 BDL SOL ROL ROL SOL BDL SOL ❑ 3.4 1210BM 5 BDL ROL SDL ROL SOL SOL RDL SOL 5 SOL SOL RDL BOL ROL ROL BDL 0 4,5 03r30110 &1 ROL SOL SD1. ROL BDL BDL SOL BDL 3 SOL BDL SDL SOL SOL SDL ROL 0 3-1 D6175110 15 SDL SOL SOL ROL SOL BDL BDL BDL 3 BDL SOL SOL ROL SOL SOL BDL ❑ 2.5 Me=10 2.9 SOL SOL ROL SDL 8DL BDL ROL SOL 3 BDL BDL SOL SOL SOL SOL SOL 0 2.9 12I0911D 4-4 SOL BDL SOL ROL SOL SOL BDL BDL 4 BDL SOL SDL ROL SOL SDL ROL ❑ 4-4 03Y2411I 4 ROL SDL RDL BDL SDL BDL BOIL ROL A SOL SOL ROL BDL ROL SOL SOL O 4.0 06/14111 3 SOL BDL ROL. SDL SOL BDL SOL SDL 3 SOL SOL BPL BDL BDL 66L SOL ❑ 30 09i1?I11 2-8 SL7L SOL BDL BDL RPL BDL 80L RDL 3 60L BDL BOL BDL SDL BDL BDL 0 2.8 12115I71 5.3 ROL SOL BDL SOL SOL ROL BOL ROL 5 RDL SDL SDL ROL. ROL SDL SOL ❑ 5.3 July 20, 2012 97746 j GS012RO376 Page 5 of 6 Copyriphl 2012 KlOrddder TABLE 6: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS SAMPLE M CHLORINATED HYDROCARBONS [lyyll TOTAL CHLORINATED HYDRDC ARSONS PETROLEUM [19A-) TOTAL PETRO LE HYDROC AR601L3 TOTAL VOCa Conecdon Dal! 7eknK woalhww TrWhlcr**Vw 1a cla-1,2- Dichicroethena 1,1- Dichloroalhene Ylrryl Chloride 1,1- IlZ Dichlbraetharr DichlarwlluM trawi,2- Dl[hlofcothene 1,7,1- Trichlonmthane 94�ro TohMne EVW!lmn m Total Xylofws MTSE DIilOproPyt Naphthalene ether NCGS 2L SlAndard 0.7 3 70 7 o,03 6 0.4 100 200 1 600 600 500 20 70 6 MW-43D 0100" 390 12-0 110 42.0 SOL 6.8 SOL BDL SOL 561 4.9 BDL SDL BDL X0 68.0 ROL 109 67D =7109 SOL BDL BOL 9-3 SOL SDL 116 SOL 1.2 12 to SDL 7,5 BDL 3.6 80L 4A 25 37 0&24M 301 11-8 114 SOL SOL BDL SOL SOL 8DL 5O7 SDL BDL ROL BDL 13.6 ROL ROL 14 52D D940PIT19 337 IHIA "A 13,9 BDL 19 BDL SDL BDL 466 3 SOL ROL BDL 16.T 29-9 SOL 57 523 12A)m 327 17 117 21 BDL 4 BDL BDL SDL 486 4 BDL 13DL SDL 24 42 SCL 76 562 03r3Of10 3221 122 SIA 7.7 SOL SOL SDL BDL BDL 433 3-1 SOL SOL SOL 11.0 26-6 ROL 41 474 06/15/10 46a 17 132 18.1 BON. 5,3 90L SDL SOL 660 1 ROL SDL SOL SDL 23-5 40A Bm 76 738 O9Y22110 265 8A 754 14 SDL 4A BDL SOL BDL 36T 1.S BDL SDL SOL 13.8 24.1 1 SOL 47 1 414 12109/10 259 ILS 62A 22A 1.8 54 SDL SOL BDL 38C 1.7 ROL SOL 8DL 17,4 337 BDL 53 433 0=4111 315 9.1 79-8 15.9 SOL 4A BDL 80L SOL 424 BDL BDL BDL 6DL 16.3 30 BDL 46 471 OT IWI 336 9.4 78.6 11.1 SDL 4.1 BDL SOL SOL 441 BDL BDL SOL SDL 15 26-9 SOL 45 466 09R2111 290 TA 71-9 21 Z3 6-3 em SDL BDL 399 SOL SOL SOL SOL 13S 25 BOL 41 439 12/15111 326 10.5 93.1 15.9 22 4.6 SOL SOL SOL 442 2.1 SOL KX SDL 172 272 SOL 5D 492 QW7112 420 14.1 %-1 9.6 BDL 2.9 BOL BDL SOL 543 3A BOL SDL 8DL 15.9 27.9 BDL 5o 593 06/21/12 356 11.4 83-7 9-5 BDL 33 BDL BDL SOL 464 2.6 6DL BDL BDL 12.2 20.5 BDL 35 499 VW-44 04111107 BDL 2.1 SOL SDL BDL SOL BDL SOL SOL 2 BDL BDL BDL 8DL BDL BDL BDL 0 2 OXW-45 OW13W ROL SDL SOL SDL BDL SOL ROL SOL BDL 0 SOL BDL BDL SOL BDL 60L SOL 0 0 OGmulia 1.2 SOL SOL SOL SOL BDL SOL BDL SDL 1 SOL BDL SOL BDL SOL BDL SOL 0 1 091046w SOL BDL SOL SOL SOL SOL SOL SAL SOL 0 BDL BDL BDL ROL BDL SDL SOL 0 0 01nam 1.4 1.2 SOL SOL SDL SOL SOL SDL SOL 3 BDL SOL ROL ROL SOL SOL SOL 0 3 0105M 1.3 SOL BDL SOL BDL SDL SOL BDL SOL 1 SDL SDL SDL SOL SDL SOL SOL 0 1 06124me 1.9 SOL SDL SDL SDL SOL SOL SOL SOL 2 SDL BDL BDL SOL 8DL BDL SOL 0 2 09102/09 2.4 1.1 BDL BDL SOL SOL BDL BDL SOL 4 BDL BDL BDL SOL SOL BDL BDL 0 4 12AW" 3 2 1 SOL 8DL BDL BDL SOL SOL 6 BDL BDL BDL SDL SDL BDL BDL D 6 0313p110 1.2 SOL BDL SOL SOL SOL SOL SOL SOL 1 SDL SDL BDL ROL SOL BDL BDL D 1 06115r10 1-5 SOL SOL BDL SILL BDL BDL BDL BDL 1 BDL BDL BDL BDL SDL SOL BDL 0 1 0912y1D t9 1.9 SOL SOL 6DL BDL BDL SOL BDL 2 BDL SOL BDL BDL ROL BDL SOL 0 2 12+0917D 3.5 2.8 1 SOL BDL BDL SOL SOL SOL 5 ROL BDL BDL am SOL BDL BDL 0 5 03124111 5.4 4.1 2.5 SOL SDL SOL BDL SOL BDL 8 SOL BDL BDL SOL SOL BDL BDL 0 8 W14111 5-7 3-6 2.2 BDL BDL ROL SOL BDL BDL 12-0 SDL SOL BDL Bat BDL BDL BDL 0 12 1=4111 6-3 4-9 3.6 BDL BDL SDL SDL BDL BDL 11.5 SOL BDL SOL BDL BOL BDL BDL 0 12 12115/11 Cs 4.0 3.3 BOL BDL ROL BDL BDL BDL 122 BDL SDL 6DL SOL BOL 6DL SDL 0 12 0312T112 82 41 32 8DL BOL BDL SDL SOL SOL 14_3 BDL SOL BDL SDL BDL BDl BDL 0 14 OWII12 7.1 5.4 3A SOL BDL SDL SOL ROL SOL 15.9 BDL SOL SOL SDL 6DL SOL SOt p 16 INW 44 09=11 149 371 393 14 ROL 2.9 SOL 1 BDL 921 SDL ROL SOL 6DL 3 2 BDL 8 927 1=4111 190 470 450 15-1 SOL 3.2 BDL 1 SDL 1,152 SOL BDL SOL SOL 4 4,1 BDL 11 1,171 12/15111 215 541 487 14.8 BDL 2.9 SOL BDL BDL 1,261 BDL SOL ROL BDL 2.5 BOL BDL 6 1267 DX27112 184 441 400 10-S ROL 2-6 SOL SOL SOL 1,039 SOL SOL SOL SDL 4.2 BDL BOL 4 1.043 OW1112 131 357 360 9.1 BOL 2.1 SOL SOL SOL 859 SOL ROL SOL SQL 1-3 BDL BDL 6 W5 UYYi7 1VDVlI 161 395 2" 13.5 SDL 2.4 BDL BDL BDL 860 SDL SOL SOL SDL 9.7 7.1 BDL 19-7 SOD 12MSMI 1]9 ]76 2" 9.9 BDL 2.O BDL BDL BDL 607,8 BDL 9DL SOL 6DL 7.5 4.7 BDL 12-2820 M27112 39.8 122 96-7 BDL BDL 0-54 BOL Bpl BOL 262 ROL BDL SOL BDL 2.4 0.68 SOL I &1 265 06tlf112 301 SQE 155 1.9 7.0 0.73 BDL BDL BDL 297 SOL BDL BON. SOL 4.4 1.3 SDL 5-7 303 99YM-6 1210dM1 am 31 SDL SDL SDL SOL ROL SOL BDL 3.4 SOL BDL BDL SOL SOL SDL BDL_ 0 3.9 12115M 1 SDL 3.1 SOL SOL BDL BDL ROL BDL BDL 3.1 BDL SOL I SOL SDL SOL I BDL BDL p 3.1 OW48 12AW11 196 502 432 16.6 BDL 3.1 BOL SOL 1,5 1.151 SOL BOL SOL SOL 13.7 12.8 SDL 30 1,182 72/75117 2]] 565 57D 13-6 SDL SOL BDL BDL Bpi 1.384 8DL BDL BOL BDL 76-1 13-6 BDL 30 1,413 OLi127112 127 308 294 6.9 SDL SDL SDL BDL SOL 739 Spl BOL BDL BDL 3.3 1.8 SOL 5 744 0MV12 118 288 372 7.3 SOL t9 BDL BOL SDL 787 BDL SOL BDL SOL 2-6 1.7 SOL 8 795 MW-30 01/27/12 SOL BDL SOL SOL SOL SDL BDL BDL SOL 0 SOL BDL SOL SOL SOL BDL 80L 0 0 MW-51 01/27/12 am SOL SOL BDL SDL SDL SOL BDL SDL 0 SOL SOL SOL BDL BOL SOL BDL 0 0 M W-57 01/27/12 Z5 118 2.6 ROL BDL SOL SOL SOL ROL 16-9 SOL SOL SOL ROL SOL am BDL 0 10.9 UW-53D OW7112 112 263 287 ?A SDL 1.5 BOL BDL SOL 991 SDL BOL SOL SOL 12.6 12-0 SOL 14.6 7D6 OW7112 119 t90 443 10A 22 2-5 SOL 0.73 BDL 788 0.6 BDL SOL SDL 24,1 18.8 SOL 43.7 832 OMI112 41.9 32,7 5" 8.2 BDL 2,6 SOL BOX SOL 673 SOL ROL BDL I BDL 20.3 j 17.7 1, BOLA 304 711 mat"I pg1L s All unrls measured in mcroprams per Her TOW Pevow m Ny&ocarboft uiGude Chlammelhane, *chlproditomm ethane. n-plbpyl benzene, lebprbpylbenzerM. tnchW 0u0r0rrleMne. 1. 2. 44nmeth0bennene RnW& 1. 3. `rVlmeNylDenxene values when detected (see Tatar 5) TOW Chortrwled Hydracarb=; include TrwhIcrc8uoromeNane when deleclad (wee -table 51- NCGS 2L Standard • Ndrlh Cardin GrourldrraW Standard (f 5A NCAC 2L .0202). effective April 1. 2011. BDL s 6aiow Detection Llmils SOLD = C*xeff Von earamd the 21. Grwr4Water Duality Standard %%[THE = htalhy6terl bA)l e81er July 20, 2012 97746 1 GSOI2R0376 Page 6 of 6 Copyright 2012 Kkorddder TABLE 7: SURFACE WATER SAMPLE RESULTS SAMPLE ID 2B STANDARD SW-01 SW-02 SW-03 SW-04 COLLECTION DATE 05/02/12 05/02/12 05/02/21 05/02112 Volatile Organic Compounds by EPA Method 6200D NIL MTBE 1,500 1 0.66 1.1 BDL BDL Trichloroethene 30 BDL 0.58 1.6 2.4 NOTES: 2B Standard = North Carolina Surface water Standard (15A NCAC 2B .0200), effective May 1, 2007. BDL = Below Detection Limits pg/L = Micrograms per liter, analogous to parts per billion MTBE = Methyl-tert-butyl ether 97746 1 GS012RO376 July 20, 2012 Copyright 2012 Kleinfelder FIGURES site K 1001, 1 I �� � L � � l C/ s W 02 ' 9 fy CREr`K � MW�i� . �MWS2 ' Y+ORSElp MW-w MW46 4 , `p45 MW-46 MW-53D MW , 4MW42 MW-1213 --------------- ry —a —+ate+ry —.��ati�aat+ �{ ATIONW- WA �vvy -' TAN �1 �p 1 MW- 30 + + i sv ❑ RW-3 11 I + R -y � MW-34 M1n230 i 0 z cc a a 1 1 U PARKING I n PARKING J J I I — - — OLD FRIENDLY AVENUE W FRIENDLY AVENUE KL EINFEL OHR Bright People. Right Solutions. 313 GALLIMORE DAIRY ROAD GREENSBORO. NORTH CAROLINA PHONE: 338-668.0693 LEGEND INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION RW-3 RECOVERY WELL LOCATION PROPERTY BOUNDARY SURFACE WATER LOCATION SW W FIGURE 2 SITE PLAN Gilbarm 7300 West Friendly Avenue Greensboro, North Carolina APPROVED BY! PATE: 01.23.2612 SCALE: ,'= 290' U� DRAWN BY- CW H I I PROJECT NO: 07748 SEpENC E,IE MW-51 �F fay 822.37 MW-52 815.74 ' MW-50 825 819.79 kfWA8 625 8' 56 826-61 830 I UN-46 83122 MW�3D I 83U 4 831.54 632-82 6833.66 ak 835 834.39 MW-42 I 834-50 841) 942.71 MW-120 834-2T 835-52 843.43 � x � �c- r MW-12 841.DD SS 1 MW-14 837.29 sue 7.17 �f- STATION' � .••xr --+F �I•- fit- �F —+c- �- fit- �I- ..-aF —+c- 825 838.32 RW-1 835 MW 41 MW-10848.1 852.63 MW-11 MW-13D 846.54 J 4 1.J ❑ IV-2D 3 •20 � 844.D9 850.18 RW 5.D4 845 845 850 856.0 MW-28 854.75 MW-33 84 MW-314 852.56 84 � R MW-32 854.03 f MW"27 851.24 MW-30850-31 J I MW-44 85C EXISTING PARKING LEGEND EXISTING INJECTION WELL LOCATION AND BUILDNG 853-39 GROUNDWATER ELEVATION MW-14 MONITORING WELL LOCAT" AND 839.82 GROUNDWATER ELEVATION RW-7 RECOVERY WELL LOCATION 842_�-- GROUNDWATER CONTOUR LINE NOTES: GROUNDWATER ELEVATIONS WERE RECORDED JUNE 21, 2012 JCL EINF-HL ►DHR Bright People. Right Solutions. 313 GALL IMORE DAIRY ROAD GREENSBORO. NORTH CAROLINA PHONE: 336.666 WB3 EXISTING PARKING FIGURE 3 SHALLOW GROUNDWATER POTENTIOMETRIC SURFACE MAP Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina APPROVED BY- DATE:07.06.2012 r-�� SCALE: r=+ar DRAWN BY: W F {f�j� PROJECT NO: 97746 MW-52 MW-50 f I l � MW -48 f� 795.4 ►IW46 IMW-53D 865.2 711.4 MW-45 303.13 15-9 i or a aMW 42 23.7 1' MW-12D 418' 2 --w— --A- � . Ic_ N --A- A x m x x - NW-12 Mw-1a +� •- } SUB STATION I- I -A Syr 379 VIA TAN W-10 F IMW-41 M W-130 W-40 MW-i1 R W— MW-230 RW-2 3,070.E I- M BMW 31 �1nlW'28 1 I I EXISTING PARKING LEGEND lip INJECTION WELL LOCATION 3.070-6 TOTAL VOCa CONCENTRATION (up1L) MW45 MONITORING WELL LOCATION WTfH 15.9 TOTAL VOCs CONCENTRATION (u9fL) I37 9 TOTAL VOCs CONCENTRATION (uWl) IN DEEP WELL RW-7 RECOVERY WELL LOCATION TOTAL VOCS ISOCONCENTRATION LINE (SHALLOW WELLS ONLY) I NOTE- I SAMPLES COLLECTED JIJNE 21, 2012. EXISTING BUILDING MW-33-0�- -W-- -- KLEINFELDER Bright People. Right Solutions. -- 313 GALLIMORE DAIRY ROAD GREENSBORO, NORTH CAROLINA PHONE- 336.669.0093 EXITING PARKING FIGURE 4 TOTAL VOCs CONCENTRATIONS Gilbaroo 730D West Friendly Avenue Greensboro, North Carolina APPROVED By - DATE: 07-10-2012 SCALE- V- 100' DRAWN BV; WJF PROJECT No: 977� I f • � �MW-SO MWAI8 l • MW46 2 MWdr3D MW�3 787-2 678.4 � 15.9 7.4 y now i 6 21.3 31, MW-42 463-8 M W-12D 1 1. r MW-12 MW-14 sue STATION+ L �- �W 3E WAI ER l �yr TANK f AW-10 � MW-13D y ARW 3 ,� MW-11 312.E MW-23p RW-2 MW-34 8 RW-4 MW-31 ❑ *I [7 MW-32 MW-33 1 EXISTING PARKING LEGEND INJECTION WELL LOCATION 312.E TOTAL CHLORINATED HYDROCARBONS CONCENTRATION {u91L) ON-45 MONITORING WELL LOCATION WITH 15.9 TOTAL CHLORINATED HYDROCARBONS CONCENTRATION lug/L] IN SHALLOW WELL 35 TOTAL CHI-OfUNATED HYDROCARBONS CONCENTRATION (uglL) IN DEEP WELL ❑ RW-7 RECOVERY WELL LOCATION iBDL_-,Oe' TOTAL CHLORINATED HYDROCARBONS ISOCONCENTRATKM LINE (SHALLOW WELLS ONLY) NOTE: SAMPLES COLLECTED JUNE 21, 2612. EXISTING BuiLDING MW-w 6DL KLE1NFELDER Bright People. Right Solutions. 313 GALLIMORE DAIRY ROAD GREENSBORO. NORTH CAROLINA PHONE: 336.W.0093 EXISTING PARKING FIGURE 5 TOTAL CHLORINATED HYDROCARBONS CONCENTRATIONS GiWroo 7300 West Friendly Avenue Greensboro, North Carolina APPROVED BY: DATE:07.10.2012 - • ■ SCALE: 1"- 100' DRAWN BY; WJF PROJECT NO: 9774E T O Z W a a a aceAnalXicala +' www.pace,Wb.7.cLAm Pace Analytical Services, Inc. 205 East Meadow Road - Sune A Eden, NC 27285 (336)623-8921 July 09, 2012 Mr. Chris Hay Kleinfelder, Inc. 313 Gallimore Dairy Rd Greensboro, NC 27409 RE: Project: Gilbarc❑ 97746 Pace Project No.: 92122245 Pace Analytical Services, Inc. 2225 Riverside Dr - Asheville, NIC 28804 (828)254-7170 Pace Analytical Services, Inc. 9800 Kincey Ave Suite 100 Huntersville. NC 28078 [704]875.9092 Dear Mr- Hay Enclosed are the analytical results for sampie(s) received by the laboratory on June 22, 2012. The results relate onty to the samples included in this report. Results reported herein conform to the most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin for Charles Hardin tripp.hardin@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be rePMr duced, except in Full. without the w0len consent of Pace Analytical Services, Inc.. Page 1 of 38 IP aCEAnalXical mow--psoalabs.Coln Project Giltrarco 97746 Pare Project No,: 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr, Ashevilie, NC 28804 (828)254-7176 CERTIFICATIONS Charlotte Certification Ms 9800 Kinney Ave. Ste 100, HuntersviPe, INC 28078 Connecticut Certification #: PH-0104 North Carolina Drinking Water Certification M 37706 Florida/NELAP Certification #: E87627 North Carolina Field Services Certification #: 5342 Kentucky UST Certification #: 84 North Carolina Wastewater Certification #- 12 Louisiana DHH Drinking Water # LA100031 South Carolina Certification #: 99006001 West Virginia Certification #: 357 South Carolina Drinking Water Cert. #: 99006003 Virginia/VELAP Certification #- 460144 Virginia Drinking Water Certification #: 00213 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc.. Pace Analytical Services. Inc. 9800 Kincey Ave. Suite I00 Huntersville, NC 28078 (704)875.9092 Page 2 of 38 c ace AnalXical W*wPace+aes com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside 0r. Asheville, NC 28804 (828j254-7176 SAMPLE SUMMARY Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875.9092 Project: Gilbarco 97746 Pace Project No.: 92122245 Lab ID Sample ID Matrix Date Collected Date Receivers 92122245001 MW-7 Water 06121/1212:17 0612211217:25 92122245002 MW-14D Water 06/21112 09:01 06/22/12 17:25 92122245003 MW•16 Water 06/21/12 09:43 06/22/12 17:25 92122245004 MW-24 Water 06/21112 09:03 06/22/12 17:25 92122245005 MW-43D Water 06/21/12 09:54 06/22/12 17 25 92122245006 MW-45 Water 06/21/1210:35 0612211217:25 92122245007 MW-46 Water 06/21J1210:59 06/22/1217:25 92122245008 MW-47 Water 06121/121130 0612211217:25 92122245009 MW-49 Water 0612111211:06 0612211217:25 92122245010 MW-53D Water 0612111211:00 06122/1217:25 92122245011 Trip Blank Water 06/21/12 00:00 06/22/12 17:25 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 3 of 38 ace Ana&ficaJe wwwpacelabs.Cam Pace Analytical Services, Im- 205 East Meadow Road - SuiteA Eden, NC 27288 1336y623.8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254.7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Gilbarco 97746 92122245 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92122245001 MW-7 SM 62008 KJM 64 PAS-C 92122245002 MW-14D SM 62006 KJM 64 PASi-C 92122245003 MW-16 SM 62006 KJM 64 PASI-C 92122245004 MW-24 SM 6200B KJM 64 PASI-C 92122245005 MW-43D SM 6200B KJM 64 PASI-C 92122245006 MW-45 SM 6200B MCK 64 PASI-C 92122245007 MW-46 SM 6200B MCK 64 PASI-C 92122245008 MW-47 SM 6200B MCK 64 PASI-C 92122245009 MW-49 SM 6200B MCK 64 PASI-C 92122245010 MW-53D SM 6200B MCK 64 PASI-C 92122245011 Trip Blank SM 6200B MCK 64 PASI-C REPORT OF LABORATORY ANALYSIS Page 4 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc.. 1)!;a'ceAna1yfica1-' www.pacslebs.cnrn Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden. NC 27288 (338)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytcal Services, Inc. 98DO XInceyAve. Suite 100 Hunters,Alie, NC 28078 (704)875.9092 Project: Gilbarco 97746 Pace Project No.: 92122245 Sample: MW7 Lab ID: 92122245001 Collected 06/21/12 12:17 Received: 06/22/12 17:25 Matrix: Water Report Parameters Results Units Limit MOL OF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 6200B Benzene ND ug/t_ 5.0 5.0 10 06128/12 02:51 71-43-2 Bromoberuene NO uglL 5.0 5.0 10 06/28/12 02-51 108-86-1 Bromochloromethane NO uglL 5.0 5.0 10 06/26/12 02,51 74.97-5 Bromodichlorornethane NO uglL 5.0 5.0 10 06/28/12 02:51 75-274 Bromoform NO uglL 5.0 5.0 10 06/28/12 02:51 75.25-2 Bromomethane NO uglL 50.0 10.0 10 06/28/12 02:51 74-83-9 n-Butylber,zene NO uglL 5.0 6.0 10 06128/12 02-51 104-51.8 sec-Butylbenzene NO uglL 5.0 5.0 10 06/28/12 02:51 135-98-8 tert-Butylbenzene ND uglL 5.0 5.0 10 06/28/12 02.51 98-06-6 Carbon tetrachloride NO ug& &0 5.0 10 W28/12 02:51 56-23-5 Chioroberuene NO uglL 5.0 5.0 10 06128)12 02-51 108-90-7 Chioreethane NO uglL 10.0 10,0 10 06/28/12 02.51 75-00-3 Chloroform NO uglL 5.0 5.0 10 06/28/12 02:51 67-66-3 Chloromethane ND uglL 10.0 10.0 10 06/28/12 02:51 74-87-3 2-Chlorotoluene NO uglL 5.0 5.0 10 06/28/12 02:51 95-49-8 4-Chlorotoluene ND ugk 5.0 5.0 10 06)28112 02-51 106-43-4 1,2-Dibromo-3-chloropropane NO ug& 10.0 10.0 10 06/28/12 02.51 96-12-8 Dibromochloromethane NO uglL 5.0 5.0 10 D6128112 02-51 12448-1 1,2-Dibromoethane (EDB) NO uglL 5.0 5.0 10 W128112 02-51 106.93-4 Dibromomethane NO ug1L 5.0 5.0 10 06/28/12 02-51 74-95-3 1,2-Dichlorobenzene NO uglL 5.0 5.0 10 06/28/12 02:51 95-50-1 1,3-DicNorobenzene NO uglL 5.0 5.0 10 06128/1202751 541-73-1 1,4-Dichlorobenzene NO uglL 5.0 5.0 10 06/28/12 02:51 106-46-7 Oichlorodifluoromethane NO uglL 5.0 5.0 10 06128/12 02:51 75-71-6 1,1-Dichloroethane 6.6 uglL 5.0 5.0 10 06/28/12 02:51 75-34-3 1,2-Dichloroethene N❑ ug1L 5.0 5.0 10 06/28/12 02:51 107-06-2 1.1-Dichloroethene ND uglL 5.0 5.0 10 06/28/12 02.51 75-35-4 cis- 1,2-Dichloroethene 166 uglL 5.0 5.0 10 W28112 02:51 156-59-2 trans-1,2-Dichloroethene ND ug1L 5.0 5.0 10 06/28/12 02:51 156-60.5 1,2•Dichioropropane NO uglL 5.0 5.0 10 06/28/12 02.51 78.87-5 1,3-Dlchloropropane NO uglL 5.0 5.0 10 06/28/12 02:51 142-28-9 2,2-Dichloropropane NO uglL 5.0 5.0 10 D6128112 02:51 594-20-7 1.1-Di chioropropene ND uglL 5.0 5.0 10 06)28112 02:51 563-5W6 cis-1,3-DichIoropropene ND ug1L 5.0 5.0 10 06128/12 02-54 10061-01.5 tra ns- 1, 3- Di chlo ro pro pe ne N❑ uglL 5.0 5.0 10 06/28/12 02:51 10061-02-6 Diisopropyl ether ND uglL 5.0 5.0 10 06/28/12 02:51 108-20-3 Ethylbenzene $18 uglL 5.0 5.0 10 06/28/12 02:51 100-41-4 Hexachloro-1.3-butad iene ND ug1L 20.0 20.0 10 06/28/12 02:51 87-68-3 Isopropy{benzene (Cumene) 68.7 uglL 5.0 5.0 10 06/28/12 02:51 98-82-8 Methylene Chloride NO ugk 20.0 20.0 10 06/28/12 02-51 75-09-2 Methyl-tert-butyl ether NO uglL 5.0 5.0 10 06/28/12 02:51 1634-04-4 Naphthalene 194 uglL 20.0 20.0 10 06/28/12 02:51 91-20-3 n-Propylbenzene 214 uglL 5.0 5.0 10 W28112 02:51 103-65.1 Styrene NO uglL 5.0 5.0 10 06/28/12 02:51 100-42-5 1.1.1,2-Tetrachloroethane ND uglL 5.0 5.0 10 06/28/12 02:51 630-2D-6 1.1.2,2- Tetra chIoroethane NO uglL 5.0 5.0 10 06/28/12 02:51 79-34-5 Date- 07/0912012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 5 of 38 This report shall not M reproduced, except in Full, without the writter, consent of Pace Analytical Services. Inc.. a aceAnalj4kal wwwpaca4abs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (338)623.8921 Pace Anal yt it at Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc- 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (7041875-9092 Project. Gilbarco 97746 Pace Project No.: 92122245 Sample: MW-7 Lab ID: 92122245001 Collected: 06/21/12 12:17 Received: 06122/12 1725 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1.2-Trichtoroethane Trichloroethene Thchlorofluorometha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m9p-Xylene ❑-Xylene Surrogates 12-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Analytical Method: 5M 6200B ND ug/L 5.0 5.0 10 06/28/12 02-51 127-18-4 12.7 ug/L 5.0 5.0 10 06/28/12 02:51 108-88-3 ND ug1L 20.0 20.0 10 06/28/12 02:51 87-61-6 ND ug/L 20.0 20.0 10 06/28/12 02:51 120-82-1 ND ug/L 5.0 5.0 10 06/28/12 02.51 71-55-6 N❑ uglL 5.0 5.0 10 06/28/12 02:51 79-00-5 N❑ ug/L 5-0 5.0 10 06/28/12 02,51 79-01-6 ND uWL 10.0 10.0 10 06/26/12 02:51 75-69-4 N❑ ug/L &0 5.0 10 06/28/12 02:51 96-18-4 1120 uWL 5.0 5.0 10 06/28/12 02:51 95-63-6 275 ug/L 5-0 5.0 10 06/28/12 02.51 108-67-8 140 ug/L 10.0 10.0 10 06/28/12 02:51 75--01-4 347 ug/L 10.0 10.0 10 06/26/12 02:51 179601-23-1 8.6 uglL 5.0 5.0 10 06/28/12 02:51 95-47-6 106 % 70-130 10 06/28/12 02:51 17060-07-0 100 I9 70-130 10 06/28/12 02:51 1868-53-7 98 I 70-130 10 06/28/12 02:51 460-00-4 97 % 70-130 10 06/28/12 02:51 2037-26-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 6 of 38 This report shall not be reproduced, except in full - without the written Consent of Pace Analytical Services, Inc. a,,.I�'ce Analytical' wow.pacslaW.com Project. Gilbarco 97746 Pace Project No.- 92122245 Pace Analytical Services, Inc. 205 Easl Meadow Road • Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (B28)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-140 Lab ID 92122245002 Collected: 06/21/12 09:01 Received: 06122/12 17.25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200B MSV Benzene Bromobenzene Bromochloromethane B ro modi chiororn etha ne Bromoform Bromomethane n-Butylbenzene sec-B utylbenzene tert-Butylbenzene Cartoon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chiorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Di b ro mo ch I orom et ha ne 1,2-❑ibromoethane (ED6) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dich lorod i f iu c ro m etha ne 1.1-Dichloroethane 1, 2-D ich to roetha n e 1,1-Dichloroethene cis-1.2-Dichtoroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-❑ichloropropane 2,2-Dichloropropene 1,1-Dichloropropene cis-1, 3-Dichloropropene trans- 1, 3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachtoro-1,3-butadiene Isopropylbenzene [Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1.1,1,2-Telrachloroethane 1,1,2.2-Tetrachloroethane Analytical Method- 5M 6200D NO ug/L 0.50 050 1 D6128112 01:21 71-43-2 NO ug/L 0.50 0.50 1 06/28/12 01:21 108-86-1 NO uglL 0.50 0.50 1 06/28/12 01:21 74-97-5 NO ug/L 0.50 0.50 1 Db/28112 0 1: 21 75-27-4 NO ug/L 0.50 0.50 1 06/28/12 01,21 75-25-2 NO ug1L 5.0 1.0 1 D6128112 01:21 74-83-9 NO ug/L 0.50 0.50 1 06/28112 01:21 104.51-8 NO ug/L 0.50 0.50 1 06/28/12 01:21 135-98-8 ND ug1L 0.50 0.50 1 06/28/12 01:21 98-06-6 NO ug/L 0.50 0.50 1 06/28/12 01-21 56-23-5 NO ug/L 0.50 0.50 1 D6128112 01 i21 108-90-7 NO ug/L 1.0 1.0 1 D6128112 01:21 75-00-3 NO ug1L 0.50 0.50 1 06/28/12 01:21 67-66-3 NO uglL 1.0 1.0 1 06/28/12 01:21 74-87-3 NO ug/L 0.50 0.50 1 06/28/12 01-21 95-49-6 NO ug1L 0.50 0.50 1 06/2&1201:21 106.43-4 ND uglL 1.0 1.0 1 D612811201-21 96-12-8 ND uglL 0.50 0.50 1 06/28/12 01:21 124-48.1 NO uglL 0,50 0.50 1 061281120121 106-93-4 ND ug/L 0.50 0.50 1 W281120121 74-95-3 ND uglL 0.50 0.50 1 08/28112 91:21 95-50-1 N❑ ugll- 0.50 0.50 1 06/2811201:21 541.73-1 N❑ uWL 0.50 0.50 1 0612W12 01-21 106-46-7 NO uglL 0.50 0.50 1 D6128112 0121 75-71-8 ND uglL 0.50 0.50 1 D6/28112 0121 75-34-3 NO u911- 0.50 0.50 1 06/28/12 01.21 107-06-2 NO uglL 0.50 0,50 1 D612811201:21 75-35-4 7.2 ug1L 0.50 0.50 1 06/28/12 01:21 156.59-2 N❑ ug)L 0.50 0.50 1 06/28/12 01:21 156-60-5 NO u911. 0.50 0.50 1 06/28/12 0111 78-87-5 NO uglL 0.50 0.50 1 06/28/12 0121 142-28-9 NO uglL 0.50 0.50 1 06/28/12 01-21 554-20-7 ND ug& 0.50 0,50 1 D6128112 01:21 563-58-6 NO ug/L 0.50 0.50 1 06/28/12 01:21 1 DD61-01-5 NO uglL 0.50 0.50 1 W28112 0121 10061-02-6 1.3 ug1L 0.50 0.50 1 06/28/12 01,21 108-20-3 NO ug1L 0.50 0.50 1 D6128112 01:21 1D0-01-4 ND uglL 2.0 2.0 1 D6128112 01:21 87-68-3 N❑ uglL 0.50 0.50 1 D6128112 01:21 98-82-8 NO ug/L 2.0 2.0 1 06/28/12 01:21 75-09-2 0.61 ug/L 0.50 0.50 1 06/28/12 01 21 1634-04-4 NO uglL 2.0 2.0 1 06/28/12 01:21 91-20-3 ND ug1L 0.50 0.50 1 D6128/12 01'21 103-65.1 NO ug/L 0.50 0.50 1 06/26/12 01:21 100-42-5 NO uglL 0.50 0.50 1 06/26/12 0121 630.2" NO ug1L 0.50 0.50 1 06/28/12 01:21 79-34-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 7 of 38 This report shall not be reproduced. except in Full. without the written consent of Pace Analytical Services, Inc.. aceAnalytical" www.pe,64bs tqm Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (338)623-892 t Pace Analytical Services, Inc. 2225 Riverside Or Asheville, NC 28804 (528)x54-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvllle, NC 28078 (704)875-9092 Prolecl. Gilbarco 97746 Pace Project No, 92122245 Sample: MW-14D Lab ID: 92122245602 Collected. 661211120901 Received: 06/22/12 17.25 Matrix- Water Report Parameters Results Units Limit MOL OF Prepared Analyzed CAS No. Qual 62008 MSV Tetrachloroethene Toluene 1,2.3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trich4oroethane Trichloroethene Trichlorofluorometha ne 1,2, 3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-xylene o-xylene Surrogates 1,2•Dichloroethane-d4 (S) digromofluoromethane (S) 4-13romofluorobenzene (S) Toluene-d8 (S) Date: 07/09/2012 01.59 PM Analytical Method: SM 62008 27.7 ugit_ 0.50 0.50 1 06/28/12 01:21 127.18-4 NO uglL 0.50 0.50 1 06/28/12 01:21 108-88-3 NO uglL 2.0 2.0 1 06128/12 01:21 87-61-6 NO uglL 2.0 2.0 1 06128/12 01:21 120-82-1 NO uglL 0.50 0.50 1 06128112 0111 71-55-6 NO uglL 0.50 0.50 1 06/28/12 01:21 79-00-5 1.1 uglL 0.50 0.50 1 06/28/12 01.21 79-01-6 NO uglL 1.0 1.0 1 06/28/12 01:21 75-69-4 NO uglL 0.50 0.50 1 06/28/12 01:21 96-18-4 NO uglL 0.50 0.50 1 06/26/12 01.21 95-63-6 NO uglL 0.50 0.50 1 06/28/12 01:21 108-57-8 NO uglL 1.0 1.0 1 06128/1201:21 75.01-4 IN uglL 1.0 1.0 1 06/28/12 0121 179601.23-1 ND uglL 0.50 0.50 1 06/28/12 01:21 95-47-6 106 % 70-130 1 06/28/12 0121 17060-07-0 99 % 70-130 1 06/28/12 0121 1868-53-7 96 % 70-130 1 06/28/12 0121 460-00-4 98 % 70-130 1 D6128112 01 21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not W reproduced, except in full. without the written consent of Pace Analytical Services, Inc.. Page 8 of 38 e aceAnalytical www.pacekWs.cum Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27286 (336)623-8921 Pace Analyticat Services, Inc. 2225 Riverside 0r. Asheville, NC 28804 (828)254-7116 ANALYTICAL RESULTS Pace Ana lyttaI Services, Inc. 9800 Kin"y Ave. Suite 100 Huntersville, NC 28078 (704)B75-9092 Project Gilbarco 97746 Pace Project No.: 92122245 Sample: MW-16 Lab 0: 92122245003 Collected: 06/21/12 09:43 Received: 06/22/12 17:25 Matrix Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene N❑ uglL 0.50 0.50 1 06/28/12 0139 71-43-2 Bromobenzene NO uglL 0.50 0.50 1 06/28/12 01:39 108-86-1 Bromochloromethane ND ug1L 0,50 0.50 1 06/28/12 01:39 74-97-5 Bromod ichioromethane NO ug1L 0.50 0,50 1 06/28112 01:39 75-27-4 Brornoform NO uglL 0.50 0.50 1 06/28/12 01.39 75-25-2 Bromomethane NO uglL 5.0 1.0 1 06/28/12 01:39 74.83-9 n-Butylbenzene NO ug)L 0.50 0.50 1 08/28/12 01:39 104-51-8 sec-Butylbenzene ND ug)L 0.50 0,50 1 06/28/12 01:39 135-98-B tert-Butylbenzene NO uglL 0.50 0.50 1 06/28/12 01.39 98-06-6 Carbon tetrachloride NO uglL 0.50 0.50 1 06/28/12 01:39 56-23-5 Chlorobenzene ND uglL 0.50 0.50 1 OW28112 01:39 108-90-7 Chloroethane N❑ uglL 1.0 1.0 1 D6128/12 01.39 75-00-3 Chloroform NO uglL 0.50 0.50 1 06/28/12 01.39 67-66-3 Chloromethane ND ug1L 1.0 1.0 1 06/28/12 01:39 74-87.3 2-Chlorotaluene ND uglL 0.50 0.50 1 06/28/12 01:39 95-49-8 4-Chlorotoluene ND uglL 0.50 0.50 1 06/28112 01:39 106-43-4 1,2-Dibromo-3-chtoropropane ND ug1L 1.0 1.0 1 06128112 01 : 39 96-12-8 Dibromochloromethane ND uglL 0.50 0,50 1 06/28/12 01:39 124-48-1 1.2-Dibromoethane (EDB) NO uglL 0.50 0.50 1 W28/12 01:39 10B-93-4 Dibromomethane ND uglL 0,50 0.50 1 06/28/12 01:39 74-95.3 1,2-Dichlorobenzene NO uglL 0.50 0.50 1 06/28/12 01:39 95-50-1 1,3-Dichlorobenzene N❑ uglL 0.50 0.50 1 06/28/12 01.39 541.73-1 1,4-Dichlorobenzene N❑ uglL 0.50 0.50 1 06128/12 01.39 106-46-7 Dichlarodifluoromethane ND uglL 0.50 0.50 1 06/28/12 01:39 75-71-8 1,1-Dichloroethane ND ug1L 0.50 0.50 1 0612811201:39 75-34-3 1,2-Diichloroethane ND ug1L 0.50 0.50 1 06128/1201:39 107-06-2 1,1-Dichloroethene 0.82 uglL 0,50 0.50 1 0612811201:39 75-35-4 cis- 1.2-Dichloroethene 4.6 uglL 0.50 0.50 1 06/28/12 01:39 156.59-2 trans-1,2-Dichloroethene ND uglL 0.50 0,50 1 06/28/12 01.39 156-M5 1,2-Dichloropropane N0 uglL 0.50 0.50 1 06128M201:39 78-87-5 1,3-Dichlorop(opane ND ug1L 0.50 0.50 1 06128/12 01:39 142-28-9 2,2-Dichloropropane ND uglL 0.50 0.50 1 06/28/12 01.39 594.20-7 1,1-Dichloropropane ND ug1L 0.50 0.50 1 06/2811201:39 563-58-6 Cis- 1,3-Dichloropropen e NO uglL 0.50 0.50 1 06/28/12 01:39 10061-01-5 trans-1.3-0ichloropropene NO ug)L 0.50 0.50 1 06128/1201.39 10061-02-6 Diisopropyl ether N❑ uglL 0.50 0.50 1 06/28/12 01.39 108-20-3 Ethylbenzene ND ug1L 0.50 0.50 1 p6128l12 01:39 10041-4 Hexachloro-1,3-butad iene ND ug1L 2.0 2.0 1 0612811201:39 87-68-3 isopropylbenzene(Cumene) ND ug1L 0.50 0.50 1 06/2811201.39 98.82-8 Methytene Chloride NO uglL 2.0 2.0 1 06/28/12 01:39 75-09-2 Methyl-tert-butyl ether NO uglL 0.50 0.5D 1 06/28/12 01:39 1634-04-4 Naphthalene NO ug1L 2.0 2.0 1 D6128/12 01:39 91-20-3 n-Propylbenzene N❑ uglL 0.50 0.50 1 0612811201:39 103-65-1 Styrene NO ug1L 0.50 0.50 1 06/28/12 01:39 100-42-5 1.1.1.2-Tetrachioroethane ND ug1L 0.50 0.50 1 O6/28/12 01.39 630-20-6 1.1.2,2-Tetrachloroe thane ND uglL 0.50 0.50 1 06/28/1201:39 79-34-5 Date: 07/09/2012 01 59 PM REPORT OF LABORATORY ANALYSIS Page 9 of 38 This report shah not be reproduced. except in full. without the written consent of Pace Analytical Services. Inc.. e 1�;alce Aria lytical www.Pacefebs.mm Pace Analytical Services, Inc. 205 EasI Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28004 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 f704)875-9092 Project Giibarco 97746 Pace Project No.: 92122245 Sample: MW•16 Lab ID: 92122245003 Collected: 06121/12 09:43 Received: 0612202 17:25 Matrix: Water Report Parameters Results units Limit MIL ❑F Prepared Analyzed CAS No. Llual 620013 MSV Tetrachioroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1. 1, 1 -T rich loroethane 1.1,2-Trichloroethane Trichloroethene Td ch lorofluo rometh a n e 1,2,3-Trichioropropane 1.2 ,4-Tri meth yl be nze ne 1.3.5-Tri m eth yl be nze ne Vinyl chloride m&p-Xylene o-Xylene Surrogates 1.2-Dichloroethane-d4 (S) Dibromo%oromethane (S) 4-Bromofluorobenzene (S) Toluene -dB (S) Analytical Method: SM 62008 9.6 u911 0.50 050 1 06/28112 01:39 127-18-4 2.4 ugll- 0.50 0.50 1 06/28112 01:39 108-88-3 ND ug/L 2.0 2.0 1 06/28112 01:39 87-61-6 ND ug/L 2.0 2.0 1 06/28112 01 39 120-82.1 ND ug/L 0.50 0.50 1 06/28/12 01:39 71-55-6 N❑ ug/L 0.50 0.50 1 06/28/12 01:39 79-00-5 1.6 uglL 0.50 0.50 1 06/28/12 01:39 79-01-6 ND ug/L 1.0 1.0 1 06/28/12 01:39 75-69-4 N❑ ug/L 0.50 0,50 1 06/28/12 01:39 96-15 4 Np ug/L 0,50 0.50 1 06126/12 01:39 95-63-6 ND ug1L 0.50 0.50 1 06/28/12 01:39 108-87-8 4.7 ug1L 1.0 1.0 1 06/28/12 01739 75-014 N❑ ug1L 1.0 1.0 1 W28/12 01:39 179601.23-1 ND uglL 0.50 0.50 1 06/28/12 01:39 95-47-6 109 % 70-130 1 06128/12 01:39 17060-07-0 102 % 70-130 1 06/28/12 0139 1868-53-7 94 % 70-130 1 06/28/12 01.39 460-00-4 97 % M130 1 06/28/12 01:39 2037-26-5 Fate. 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 10 of 38 This report shall not W reproduced, except in full. without the written consent of Pace Analytical Services. Inc.. e Pace Analyt}ea] Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc. ace AnalXical 205 East Meadow Road - Suite A 2225 Riverside ❑r. 9800 KinceyAve. Suite 100 www pac@Wbs aan Eden. NC 27288 Ashev lle, NC 28804 Hunlersville. NC 2867E (336)623-8921 (828)254.7176 {704y875.9092 ANALYTICAL RESULTS Project. Giibarco 97746 Pace Project No.: 92122245 Sample: MW•24 Lab ID: 92122245004 Collected: 0612111209:03 Received: 0612211217:25 Matrix. Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200B VISV Analytical Method: SM 62008 Benzene 67.5 uglL 2.5 2.5 5 G6128/12 03:09 71-43-2 Bromobenzene ND ug)L 2.5 2.5 5 06/26/12 03:09 108-86-1 Bromochloromethane ND ugk 2.5 2.5 5 D6128112 03:09 74-97.5 Bromodichloromethane NO uglL 2.5 2.5 5 D6128112 03:09 75-27-4 Bromotorm ND uglL 2.5 2.5 5 D6128112 03:09 75-25-2 Bromomethane ND uglL 25.0 5.0 5 DW28112 0309 74-83-9 n-Butylbenzene NO ug1L 2.5 2.5 5 06/28/12 03:09 104.51.8 see-Butylbenzene ND uglL 2.5 2.5 5 06/28/12 03.09 135.98-8 tent-Butylbenzene NO uglL 2.5 2.5 5 06/28/12 03:09 98-06-6 Carbon tetrachloride NO uglL 2.5 2.5 5 06/28/12 03 09 56-23.5 Chlorobenzene NO ug1L 2.5 2.5 5 06/28/12 03 09 108-90-7 Chloroethane NO uglL 5.0 5.0 5 06/28/12 03:09 75-00-3 Chloroform N❑ uglL 2.5 2.5 5 06/28/12 03:09 67-66-3 Chloromethane NO ug1L 5.0 5.0 5 06/28/12 03:09 74-87-3 2-Chlorotoluene NO uglL 2.5 2.5 5 06/28/12 03:09 95-49-8 4-Chlorotoluene NO uglL 2.5 2.5 5 06/28/12 03:09 106-43-4 1,2-Dibromo-3-chloropropane ND ug1L 5.0 5.0 5 06/28/12 03.09 96-12-8 Dibromochloromethane ND uglL 2.5 2.5 5 OW28112 03 09 124-48-1 1,2-Dibromoethane (EDB) NO uglL 2.5 2.5 5 M28/12 03 09 106-93-4 Dibromomethane ND uglL 2.5 2.5 5 06/28/12 03:09 74-95.3 1,2-Dichlorobenzene NO ug1L 2.5 2.5 5 0&128112 03:09 95-50-1 1,3-Dichlorobenzene ND ug1L 2.5 2.5 5 D612811203:09 541-73-1 1,4-Dichlorobenzene NO uglL 2.5 2.5 5 06128M2 03:09 106-46.7 Dichlorodifluoromethane NO uglL 2.5 2.5 5 06/28/12 03:09 75.71-8 1,1-Dichloroethane NO uglL 2.5 2.5 5 0612811203:09 75.34-3 1,2-Dichloroethane NO uglL 2.5 2.5 5 06/28/12 03.09 107-06-2 1,1-Dichlorvethene 2.5 uglL 2.5 2.5 5 06/28/12 03:09 75-35.4 cis- 1.2-Dichioroethene 249 ug1L 2.5 2.5 5 06/28/12 03:09 156-59-2 trans-1.2-Dichloroethene NO uglL 2.5 2.5 5 06/28/12 03:09 156-60-5 1,2-Dichloropropane NO uglL 2.5 2.5 5 06/28/12 03:09 78-87-5 1,3-Dichloropropane NO uglL 2.5 2.5 5 06/28/12 03:09 142-28-9 2,2-Dichloropropane ND ug1L 2.5 2.5 5 06/28/12 03:09 594-20-7 1.1-Dichloropropene ND uglL 2.5 2.5 5 06/28/12 03:09 563-58-6 cis- 1.3-Dichloropropene ND ug1L 2.5 2.5 5 D612811203:09 10061-01-5 trans-1.3-Dichloropropene ND uglL 2.5 2.5 5 06/28/12 03:09 10061-02-6 Diisopropyl ether 46.2 ug1L 2.5 2.5 5 06/28/12 03 09 108-20-3 Ethylbenzene NO ug1L 2.5 2.5 5 06/28/12 03 09 100-41-4 Hexachloro-1,3-butad iene ND ug1L 10.0 10.0 5 06/28112 03:09 87-68-3 Isopropylbenzene (Cumene) 6.2 uglL 2.5 2.5 5 06/28/12 03:09 98-82-8 Methylene Chloride NO uglL 1 D,0 10.0 5 D6128112 03:09 75-09-2 Methyl-tert-butyl ether 22.7 uglL 2.5 2.5 5 06128/12 03:09 1634-04.4 Naphthalene NO uglL 10.0 10.0 5 06/28/12 03.09 91.20-3 n-Propylbenzene NO uglL 2.5 2.5 5 06/28/12 03:09 103-65.1 Styrene ND uglL 2.5 2.5 5 06/28/12 03:09 100-42-5 1.1.1,2-Tetra chloroethane NO uglL 2.5 2.5 5 06/28/12 03:09 630-20-6 1.1.2.2-Tetra chloroethane NO ug1L 2.5 2.5 5 06/28/12 03:09 79-34-5 Date: 07109/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 11 of 38 This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc.. R acmnalj tical wwwpacelabs.mm Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NG 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 98GO Kinee y Ave. Suite 100 Huntersville. NC 28078 1704)875-9082 Project. Giibarco 97746 Pace Project No_ 92122245 Sample- MW-24 Lab ID: 92122245004 Collected: 06121112 09 03 Received: 06/22/12 17:25 Matrix, Water Report Parameters Results Units Limit MOL DF Prepared Analyzed CAS No. Dual 6200E MSV Tetrachloroethene Toluene 1,2.3-Thchlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichioroethane 1.1,2-Trichtoroethane Trichloroethene Trich i oro fi uo rometh a n e 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,15-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xyie ne Surrogates 1.2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 07/09/2012 01:59 PM Analytical Method: SM 6200B 896 ug1L 2.5 2.5 5 06/28/12 03:09 127-18-4 ND uglL 2.5 2.5 5 06/28/12 03:09 108-88-3 N❑ uglL 10.0 10.0 5 06/28/12 03:09 87-61-6 ND ug1L 10.0 10.0 5 06/28/12 03:09 120-82-1 ND uglL 2.5 2.5 5 06/28/12 03:09 71-55-6 ND ug1L 2.5 2.5 5 06/28/12 03.09 79-00.5 52.9 uglL 2.5 2.5 5 06128/12 03:09 79-01-6 11.4 ug1L 5.0 5.0 5 06/21V12 0109 75-69-4 ND ug1L 2.5 2.5 5 06/28/12 03:09 96-18-4 3.0 ug1L 2.5 2.5 5 06/28/12 03:09 95-63-6 ND ug1L 2.5 2.5 5 06/28/12 03 09 105-67-8 60.8 ug1L 5.0 5.0 5 06/28/12 03:09 75-014 ND ug1L 5.0 5.0 5 06/28/12 0109 179601-23-1 NO ug1L 2.5 2.5 5 06128/12 D3:09 95-47-6 99 °% 70-130 5 06/28/12 0109 17060-07-0 97 °% 70-130 5 D6128112 03:09 1868-53-7 94 °% 70-130 5 D6128112 03:09 460-00-4 100 °% 70-130 5 06/28/12 0109 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the wriMen consent of Pace Analytical Services. Inc. Page 12 of 36 aceAnalXicalR www.Panviabs.cam Project: Gilbarco 97746 Pace Project No.: 92122245 Pace Anatytical ServiCos, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (3361623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 HUntersVille, NC 28078 (7041875-9092 Sample: MW-43❑ Lap ID: 92122245005 Collected: 06/21/12 09:54 Received. 06/22/12 17-25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Dual 6200B MSV Analytical Method- SM 6200B Benzene 2.6 uglL 2.0 2.0 4 06/28/12 03:27 71-43-2 Bromobenzene NO ug)L 2.0 2.0 4 06128/1203:27 108-86-1 Bromochioromethane NO uglL 2.0 2.0 4 06/28/12 03:27 74-97-5 Bromodichloromethane NO uglL 2.0 2.0 4 06/28/12 03:27 75-27A Bromoform NO uglL 2.0 2.0 4 06128/12 03:27 75-25-2 Bromomethane NO ug& 20.0 4.0 4 06/28/12 03:27 74-83-9 n-Butylbenzene ND uglL 2.0 2.D 4 06128/1203:27 104.51-8 sec-8utylbenzene NO uglL 2.0 2.0 4 06/28/12 03:27 135.98-8 tert-Buty}benzene ND ug& 2.0 2.0 4 06/28/12 03:27 98-06-6 Carbon tetrachloride NO ug1L 2.0 2.0 4 06/28/12 03:27 56-23-5 Chlorobenzene NO uglL 2.0 2.0 4 06/28/12 03:27 108-90-7 Chioroethane NO uglL 4.0 4.0 4 06/28/12 03:27 75-00-3 Chloroform ND ug1L 2.0 2.0 4 W28112 03:27 67-66-3 Chioromethane NO uglL 4.0 4.0 4 06/28/12 03,27 74-87-3 2-Chlorotoluene NO uglL 2.0 2.0 4 06/28/12 03,27 95-49-8 4-Chloratoluene NO ug1L 2.0 2.0 4 06/28/12 03:27 10643-4 1,2-Dibromo-3-chtoropropane NO ug1L 4.0 4.0 4 06128/1203-27 96-12-8 Dibromochloromethane NO uglL 2.0 2.0 4 06128/12 03:27 124-48-1 1,2-Dibromoethane(EOB) ND ug1L 2.0 2.0 4 061261120127 1DB-93-4 Dibromomethane NO uglL 2.0 2.0 4 061281120127 74-95-3 1,2-Dichlorobenzene ND uglL 2.0 2.0 4 0612811203:27 95-50-1 1,3-Dichlorobenzene NO uglL 2.0 2.0 4 0612811203.27 541.73-1 1,4-Dichlorobenzene NO uglL 2.0 2.0 4 06126/1203:27 106-46-7 Dichlorodifluoromethane NO uglL 2.0 2.0 4 06/28/12 03:27 75-71-6 1.1-Dichloroethane 3.2 ug1L 2.0 2.0 4 06/28/12 03-27 75-34-3 1.2-Dichlaroethane NO uglL 2.0 2.0 4 0612811203:27 107-06-2 1.1-Dichtoroethene 9.5 uglL 2.0 2.0 4 06128/1203:27 75-35-4 cis-1,2-Dichtoroethene 83.7 uglL 2.0 2.0 4 06/28/12 03:27 156-59-2 trans-1.2-Dichloroethe ne ND ug& 2.0 2.0 4 06/28/12 0 3:2 7 156-60-5 1,2-Dichloropropane ND uglL 2.0 2.0 4 06/28/12 03:27 78-87-5 1,3-Dichloropropane N❑ uglL 2.0 2.0 4 M28/1203-27 142.28-9 2,2-Dichloropropene ND uglL 2.0 2.0 4 06/28/12 03:27 594-20-7 1.1-Dichloropropene NO uglL 2.0 2.0 4 06/28/12 03:27 563-58-6 cis- 1.3-Dichloropropene ND uglL 2.0 2.0 4 06/2811203:27 10061-01-5 Ira ns-1,3-Dichloropropene ND uglL 2.0 2.0 4 06/28/12 03:27 10061-02-6 Diisopropyl ether 20.5 ugll- 2.0 2.0 4 06/28112 03:27 108.20-3 Ethylbenzene NO uglL 2.0 2.0 4 0&28/12 03:27 100-41-4 Hexachloro-1,3-bu[aid iene ND uglL 8.0 8.0 4 06/28/12 03:27 87-68-3 Isopropylbenzene (Cumene) ND uglL 2.0 2.0 4 0612811203:27 98-82-8 Methylene Chloride NO uglL 8.0 8.0 4 06/26/12 03:27 75-09-2 Methyl-tert-butyl ether 12.2 uglL 2.0 2.0 4 D6128112 03-27 1634-04-4 Naphthalene NO uglL 8.0 8.0 4 D6128112 0 3-2 7 91-20-3 n-Propylbenzene NO uglL 2.0 2.0 4 06128/12 03:27 103-65-i Styrene NO uglL 2.0 2.0 4 06128/1203-27 1DO-42-5 1. 1. 1, 2-Tetra ch lorc etha ne N❑ uglL 2.0 2.0 4 06128/1203:27 630-20-6 1.1.2,2- Tetra chIoroethane ND uglL 2.0 2.0 4 061281120327 79-34-5 01-=61V lF1 7f'i'lM15d &1112 av REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wrinen consent of Pace Analytical Services. Inc.. Page 13 of 38 A Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc aceAwlytical 205 Easl Meadow Road • Suite A 2225 Riverside Or. 9800 Kincey Ave. Suite 100 WWWP@ce4bsmn1 Eden, NC 27268 Asheville. NC 28804 Hunlersville. NC 28078 (336)623-8921 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Gilbarco 97746 Pace Project No.: 92122245 Sample: MW-430 Lab ID: 92122245005 Collected 06/21/12 09:54 Received W22112 17:25 Matrix: Water Report Parameters Results Units Limit MOL OF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 62006 Tetrachloroethene 356 uglL 2.0 2.0 4 06/26/12 03:27 127-18-4 Toluene N❑ uglL 2.0 2.0 4 06/28/12 03:27 108-88-3 11,43-Trichlorobenzene NR uglL 8.0 8.0 4 06128/1203:27 87-61-6 1,2,4-Trichlorobenzene NO uglL 8.0 8.0 4 06/28/12 03:27 120-82-1 1,1.1-Trichloroethane N❑ uglL 2.0 2.0 4 06128/12 03:27 71-55-6 1,1.2-Trichloroethane ND ug& 2.0 2.0 4 06/28112 03:27 79-00-5 Trichloroethene 11.4 ug1L 2.0 2.0 4 06/28/12 03.27 79-01-6 Trichlorofluoromethane NO ug/L 4.0 4.0 4 06/28/12 03.27 75-69-4 1,2,3-Trichloropropane NC ug/L 2.0 2.0 4 0612811203:27 96-18-4 12,4-Trimethylbenzene N❑ uglL 2.0 2.0 4 06/28/12 03:27 95-63-6 1,3,5-Trimethylbenzene NI7 ug/L 2.0 2.0 4 D6128112 03:27 108-67-8 Vinyl chloride NO uglL 4.0 4.0 4 06128/12 03:27 75-01-4 m&p-Xylene NO uglL 4.0 4.0 4 06128/12 03:27 179601-23.1 o-Xylene NO uglL 2.0 2.0 4 06/28/12 03:27 95-47-6 Surrogates 12-Dichloroethane-d4 (S) 104 % 70-130 4 06/28/12 03:27 17080-07-0 ❑ibromolluoromethane (S) 98 % 70-130 4 06/28/12 03.27 1868-53-7 4-Bromofluorobenzene (S) 93 % 70-130 4 06/28/12 03.27 460-00-4 Toluene -dB (S) 100 % 70-130 4 08/28/12 03:27 2037-26.5 Date: 0710912012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 14 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. aceAnalyticaI www pa-ekg&s oxT, Project Gilbarco 97748 Pace Project No. 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Dr Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. SLlne 100 Huntersville, NC 28078 (704)875.9092 Sample: MW-45 LabID: 92122245006 Collected 06/21/12 10:35 Received: 06/22/12 17:25 Matrix: Water Report Parameters Results Unts Limit MDL OF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method- SM 6200B Benzene NO uglL 0.50 0.50 1 07/02/12 18:06 71.43-2 Bromobenzene ND ug& 0.50 0.50 1 0710211218:06 10"6-1 Bromoohloromethane NO ug& 0.50 0.50 1 07102M218:06 74-97-5 Bromodichloromethane NO ug1L 0.50 0.50 1 07/02/12 1806 75-27.4 Bromoform NO ug/L 0.50 0.50 1 07102Ji218:06 75-25-2 Bromomethane NO uglL 5.0 1.0 1 071OW2 18A6 74-83.9 n-Butylbertzene ND uglL 0.50 0.50 1 071021121806 104.51-8 sec-Butybenzene NO uglL 0,50 0.50 1 07142J12 18.06 135-98-8 lert-Butylbenzene NO uglL 0,50 0.50 1 07/02/12 1806 98-06-6 Carlson tetrachloride NO uglL 0.50 0.50 1 07/02/12 18:06 56-23-5 Chlorobenzene NO ug1L 0.50 0.50 1 07/02/12 18-06 108-90-7 Chloroethane NO ug1L 1.0 1.0 1 07/0211218:06 75-DD-3 Chloroform NO uglL 0.50 0.50 1 07107M2 18:06 67.66.3 Chioromethane NO uglL 1.0 1.0 1 07/02/12 18.06 74-87-3 2-Chlorotoluene NO ug1L 0.50 0.50 1 07/02/12 18:06 95-49-8 4-Chlorotoluene NO ug1L 0,50 0.50 1 07102/12 1&06 106-43-4 1.2-Dibromo-3-chloropropane IN uglL 1.0 1.0 1 07/02/12 18.06 96-12-8 Dibromochioromethane NO uglL 0.50 0.50 1 07/02/12 18:06 124-48.1 1.2-Dibromoethane (EDB) NO uglL 0.50 0.50 1 07/02/12 18:D5 1W-93-4 Dibromomethane NO uglL 0.50 0.50 1 07/02/12 18 06 74.95.3 1,2-Dichlorobenzene NO uglL 0.50 0.50 1 0710211218:06 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 0.50 1 07/02/12 18:06 541.73-1 1,4-Dichlorobenzene NO uglL 0.50 0.50 1 07/02/12 1&D6 106-46-7 ❑ichtorodifluoromethane NO uglL 0.50 0.50 1 07/02/12 18:06 75-71-8 1,1-Dichloroethane NO uglL 0.50 0.50 1 07102J121&D6 75-34-3 1,2-Dichloroethane NO uglL 0.50 0.50 1 07/02/12 18:06 107-06-2 1,1-Dichloroethene NO ug1L 0.50 0.50 1 07/02/12 18:06 75-35-4 cis- 1.2-Dichtoroethene 3.4 uglL 0.50 0.50 1 07/02112 18:06 156-59-2 trans-1,2-Dichloroethene NO uglL 0.50 0.50 1 07/02/12 18:D6 156-60-5 1,2-Dichloropropane NO ug)L 0.50 0.50 1 0710211218:D6 78-87-5 1,3-Dichloropropane NO uglL 0.50 0.50 1 07/02/12 18-D6 142-28-9 2,2-Dichloropropane ND uglL 0.50 0.50 1 07/02/12 18:06 594-20-7 1,1-DichIoropropen e ND ug/L 0.50 0.50 1 07/02/12 18-D6 563-58-6 cis-1,3-Dlchtpropropene ND uglL 0.50 0.50 1 07102M2 18-06 10061-01.5 trans-1,3-Dichloropropene ND uglL 0.50 0.50 1 07/02/12 18:D6 10061-02-6 Dlisopropyi ether ND ug1L 0.50 0.50 1 07/02/12 18:06 108-20-3 Ethylbenzene N❑ uglL 0.50 0.50 1 0 7102J 12 18:D6 100-41-4 Hexachioro-1.3-butadiene NO uglL 2.0 2.0 1 07/02/12 18:06 87-68-3 Isopropylbenzene (Cumene) NO uglL 0.50 0.50 1 07/02/12 18:D6 98-82-8 Methylene Chloride NO uglL 2.0 2.0 1 07107J12 18:D6 75.09-2 Methyl-tert-butyl ether NO uglL 0.50 0.50 1 07/02/12 18:06 1634-04-4 Naphthalene ND ug/i_ 2.0 2.0 1 07/02112 18:D6 91-20-3 n-Propylbenzene NO ug1L 0.50 0.50 1 07102J1218:06 103-65-1 Styrene NO ug1L 0.50 0.50 1 07/02/12 18:06 100-42-5 1,1.1,2- Tetra chloroethane NO uglL 0.50 0.50 1 07102J12 18:06 630.20-6 1.1,2,2-Teirachic roethane NO uglL 0.50 0.50 1 07/02/12 18706 79-34-5 Date- 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 15 of 38 This report shall not 6e reproduced, except in full, without the written consent of Pace Analytical Services. Inc.. e laceAnalyfical www.psce✓abs.cem Project: Gilbarco 97746 Pace Project No.: 92122245 Pace Analytical Services, Inc. 2V East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (826)254-7176 ANALYTICAL. RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Nuntersville, NC 28078 (704)675-9092 Sample: MW-45 Lacs ID: 92122245006 Collected: 06/21112 10:35 Received: D6122/12 17:25 Matrix- Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 62006 Tetrachlorcethene 7.1 uglL 0.50 0.50 1 0710211218:06 127-18-4 Toluene ND uglL 0.50 0.50 1 07/02/12 18:06 108-88-3 1,2,3-Trichlorobenzene ND uglL 2.0 2.0 1 07102/1218:06 87-61-6 1,2,4-Trichlorobenzene NO uglL 2.0 2.0 1 07102/1218:06 120-82-1 1,1,1-Trichloroethane N❑ uglL 0,50 0.50 1 07/0211218.06 71-55-6 1,1,2-Trichloroethane NO uglL 0.50 0.50 1 0710211218:06 79-00-5 Trichloroethene 5.4 uglL 0.50 0.50 1 07102/12 18:06 79-01-6 Trichloroftuoromethane ND ug1L 1.0 1.0 1 (17102112 18:06 75-69-4 1,2,3-Trichloropropane ND uglL 0.50 0.50 1 07/02/12 18:06 96-18-4 1,2,4-Trimethylbenzene ND uglL 0.50 0.50 1 07/02/12 18:06 95-63-6 1,3,5-T6methylbenzene NO ug1L 0.50 0,50 1 07/02/12 18 06 168-67-8 Vinyl chloride NQ uglL 1.0 1.0 1 07/02/12 18:06 75-01-4 m&p-Xylene ND uglL 1.0 1.0 1 07/02/12 18:06 179601-23-1 o-Xylene NO uglL 0,50 0.50 1 07/02/12 18:06 95-47-.6 Surrogates 1,2-Dichloroethane-dill (S) 99 % 70-130 1 07/02/12 18.06 17060-07-0 Dibromofiuoromethane (S) 96 % 70-130 1 07/02/12 18:06 1868-53-7 4-6romofluorotsenzene (S) 97 % M130 1 07/02/12 15:06 460-00.4 Toluene-d8 (S) 100 % 70.130 1 07/02/12 18 06 2037-26-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 16 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. aceAnalytical www'paceiaby.cxxn Project. Gilbarco 97746 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 ANALYTICAL RESULTS [828]254.7176 Pace AnalyrlcaI Services, Inc. 9800 Aincey Ave. Suite 100 Huntersville. NC 28078 Pace Project No.. 92122245 Sample: MW-46 Lab ID: 92122245007 Collected 06/21/12 10:59 Received- O6/22112 1725 Matrix: Water Report (704)875.9092 Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 62008 MSV Analydcai Method: SM 62008 Benzene NO ug/L 1.2 1.2 2.5 0710211218:23 71-43-2 Bromobenzene NO ugli- 1.2 1.2 2.5 07102/1218:23 108-Wl Bromochloromethane NO ugIL 1.2 1.2 2.5 07/02/12 18:23 74-97-5 Bromodichtoromethane NO ug/L 1.2 1.2 2.5 07102/12 18:23 75-�74 Bromoform NO uglL 1.2 1.2 2.5 0710211218:23 75-25-2 Bromomethane NO ug/L 12.5 2.5 2.5 07/07J1218:23 74-83-9 n-Butytbenzene NO u911- 1.2 1.2 2.5 07/02112 18:23 104-51-8 sec-Rutylbenzene NO uglL 1,2 1.2 2.5 07J02fl215:23 135-9" tert- Butyl benzene ND uglL 1.2 1.2 2.5 07/02112 18:23 W06-6 Carbon tetrachloride NO ug/L 1.2 1.2 2.5 07/02/12 18:23 56-23-5 Chlorobenzene NO UP& 1.2 1.2 2.5 07/02/12 18:23 IOB-90-7 Chloroethane NO ug)L 2.5 2.5 2.5 0710211218:23 75-DD-3 Chloroform NO ug& 1.2 1.2 2.5 07/02112 18:23 67-86-3 Chloromethane NO vg1L 2.5 2.5 2.5 07/02/12 18:23 74-87-3 2-Chlorotoluene NO ugfL 12 1.2 2.5 0710211218:23 95-494 4-Chlorotoluene NO ug/L 1.2 1.2 2.5 07/02/12 18:23 106-43.4 1,2-Oibromo 3 chioropropane ND uglt 2.5 2.5 2.5 07/02112 18:23 96-12-8 Dibromochloromethane NO ug/L 1.2 1.2 2.5 07/02112 16:23 124-48-1 1,2-Dibromoethane(EDB) ND ug1L 1.2 1.2 2.5 07/02J1218:23 106-93-4 Dibromomethane NO ug1L 1.2 1.2 2.5 07/02/12 18:23 74-95-3 1,2-Dichlorobenzene NO ug1L 1.2 1.2 2.5 07102J12 18:23 95-5(-1 1,3-Dichlorotxe zene NO ug1L 12 1.2 2.5 0710211218:23 541-73-1 1,4-t)ichlorobenzene NO ug]L 1.2 1.2 2.5 07/02/12 18:23 1DB-46-7 Dichlorodifiuoromethane NO ug/L 1.2 1.2 2.5 071021112 18:23 75-71-8 1,1-Dichloroethane 2.1 ug/L 12 1.2 2.5 07102t1218-23 75-34-3 1,2-Dichloroethane NO ug/L 1.2 1.2 2.5 07/02/12 18:23 107-06-2 1,1-Dichloroethene 9.1 ug/L 1.2 1.2 2.5 0710211218:23 75-35-4 cis-1,2-Dichloroethene 360 uglL 1.2 1.2 2.5 07/02/12 18:23 156-59-2 trans- 1, 2-Dichlomethene NO ugh- 12 1.2 2.5 0710211218:23 156-60-5 1,2-Dichloropropane NO ug/L 1.2 1.2 2.5 0710211218:23 78-87-5 1,3-Dichlaropropane NO ug/L 1.2 1.2 2.5 07/02/12 18:23 142-28.9 22-Dichloropropane ND ug/L 12 1.2 2.5 07/02/12 18:23 594-20-7 1,1-Dich(oropropene NO ug/L 1.2 1.2 2.5 07/02)1218:23 563-58-6 cis- 1,3-Dichloropropene ND ug/L 1.2 1.2 2.5 0710211216:23 1DD61-01-5 trans-1.3-Dichloropropene ND uglL 1.2 1.2 2.5 07/02/12 18:23 10061-02-6 Diisopropyl ether N❑ ug/L 1.2 1.2 2.5 07/02112 18:23 1DB-20-3 Ethylbenzene ND ug/L 1.2 1.2 2.5 07/0211218:23 100-41-4 Hexachloro-1.3-butadiene ND ug1L 5.0 5.0 2.5 07/02112 18:23 87-W3 Isopropylbenzene (Currene) ND ug/L 1.2 1.2 2.5 07/02J12 18:23 98-82-8 Methylene Chloride N❑ ug/L 5.0 &0 2.5 07/02112 18:23 75-09-2 Methyl-tert-butyl ether 1.3 ug1L 1.2 1.2 2.5 0710211218:23 1634-04-4 Naphthalene ND ug/L 5.0 5.0 2.5 07107J1218:23 91-20-3 n-Propylberizene N❑ ug1L 1.2 1.2 2.5 0710211218:23 103-65-1 Styrene ND u911- 1.2 1.2 2.5 0710211218:23 1DO-42-5 1,1,1,2-Tetrachloroethane ND ug[L 1.2 1.2 2.5 07MI2 18:23 630.20-6 1,1,2,2 Tetrachloroethane NO uglL 1.2 1.2 2.5 07AM12 18:23 79-34-5 Date: 07109/2012 01:59 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 17 of 38 E (:�;a'cieAnalXical . pacaabs corn Project: Gilbarco 97746 Pare Project No.: 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden,NC 21288 (338)623-8W 1 Pace Anaiytical Services, Inc. 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875.9092 Sample: MW-46 Lab la: 92122245007 Collected: 06/21/12 10:59 Received: 06/22/12 17.25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: 5M 62008 Tetra& loroethen e 131 ug1L 1.2 1.2 2.5 07/021121823 127.18-4 Toluene ND uglL 1.2 1.2 2.5 07/02/12 18:23 108-88-3 1,2,3-Thchlorobertzene ND uglL 5.0 5.0 2.5 07102A218:23 87-61-6 1.2,4-Trichlorabenzene ND uglL 5.0 5.0 2.5 07/07/12 18:23 120-82-1 1,1,1-Trichtoroethane N❑ uglL 1.2 1.2 2.5 0710211218:23 71-55-6 1,1,2-Thchtoroethane NO uglL 1.2 12 2.5 0710211218:23 79-00-5 Trichloroethene 357 uglL 1.2 1.2 2.5 07/02/12 18:23 79-01-6 Tdchlorofluoromethane 4.7 uglL 2.5 2.5 2.5 07/02112 18:23 75-69-4 1,2,3-Trichloropropane NO ug1L 1.2 1.2 2.5 07102/1218:23 96-18-4 1,2,4-Thmethylbenzene ND uglL 1.2 1.2 2.5 07/02/12 18-23 95-63-6 1,3,5-Thmethylbenzene ND uglL 1.2 1.2 2.5 07/02/12 18:23 108.67-8 Vinyl chloride NO uglL 2.5 2.5 2.5 07/02112 18:23 75-01-4 m&p-Xylene NO uglL 2.5 2.5 2.5 07/02/12 18-23 179601-23-1 a-Xylene ND uglL 1.2 1.2 2.5 07/02112 18,23 95-47-6 Surrogates 1.2-Dichloroethane-d4 (S) 99 % 70-130 2.5 07/02/12 1823 17060-07-0 DiInromofluoromethane (S) 98 % 70.130 2.5 07/02/12 18:23 1888-53-7 4-Bromofluombenzene (S) 97 % 70.130 2.5 07/02/12 1823 460-00-4 Toluene-d8 (S) 98 % 70-130 2.5 07/02/12 18.23 2037.26-5 Date. 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 18 of 38 This report shall not 6e reproduced, except in full. without the written consent of Pace Analytical Seances, Inc.. aceAnaij6calc wrw pace�6s. cam Project: Gilbarco 97746 Pace Project No : 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside br. Asheville. NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave SLid e 100 Huntemville, NC 20018 [704]875-9092 Sample: MW47 Lab 10: 92122245008 Collected 06121/12 11:30 Received 06/22/12 17:25 Matrix: Water Report Parameters Resutts Units Limit MDL OF Prepared Analyzed CAS No. Cual 6200E MSV Benzene Bromobenzene Bromochioromethane B romodi ch loro m etha ne Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Ch lorotoluene 4-Chlorotoluene 1.2-Dibromo- 3-chIoropropane Di hro moth to r o m eth a ne 1,2-❑ibromoethane (EDB) Dibromometha ne 1,2-❑ichlorebenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Di ch Ie rod ifl uo ro metha ne 1,1-Di chi oroethane 1.2-Dic3 iloroethane 1,1-Dichloroethene cis- 1.2-0ichloroethene Ira ns-1, 2-Di cNor oethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-DichIaropropene cis-1,3-Dichlorapropene Ira ns-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1.1.1,2-Tetrachloroetha ne 1,1.2.2-Tetrachtoroethane Analytical Method: 5M 6200B ND uglL 0.50 0.50 1 0710211218:40 71-43-2 ND uglL 0.50 0.50 1 0710211218:40 108-86.1 NO uglL 0.50 0.50 1 0710211218.40 74-97-5 NO uglL 0.50 0.50 1 07/02/12 18.40 75-27-4 NO uglL 0.50 0.50 1 07/02/12 18:40 75-25-2 NO ug1L 5.0 1.0 1 07/02/12 18:40 74.83-9 NO uglL 0.50 0.50 1 07/02/12 18:40 104-51-8 ND uglL 0.50 0.50 1 07/02/12 18:40 135-98-8 NO ug1L 0.50 0.50 1 07/02/12 18 40 98.06-6 NO ug1L 0.50 0.50 1 07/02/12 1840 56.23-5 ND uglL 0.50 0,50 1 07/02/12 18:40 108-90-7 ND uglL 1.0 1.0 1 0710211218A0 75-00-3 N❑ uglL 0.50 0.50 1 07/02/12 18A0 67.66-3 ND uglL 1.0 1.0 1 07/02/12 18:40 74-87-3 N❑ uglL 0.50 0.50 1 07/02/12 18:40 95-49-6 ND uglL 0.50 0.50 1 07/02/12 18.40 106-43-4 ND uglL 1.0 1.0 1 07/02/12 18:40 96.12-8 ND ug1L 0.50 0.50 1 07102/12 18:40 124-48-1 ND ug/L 0.50 0.50 1 07/02/12 18 40 106-93-4 NO uglL 0.50 0.50 1 07/02/12 18:40 74-95-3 ND ug1L 0,50 0.50 1 07102112 18A0 95-50-1 NO uglL 0.50 0.50 1 07/02/12 18.40 541-73-1 ND uglL 0.50 0.50 1 07/02/12 18:40 106-46-7 ND uglL 0.50 0.50 1 07/02/12 18:40 75.71-8 0.73 uglL 0.50 0.50 1 07/02/12 18A0 75-34-3 NO uglL 0,50 0.50 1 07/02/12 18:40 107-06-2 1.9 uglL 0,50 0.50 1 07/02/12 18:40 75-35-4 155 ug1L 0.50 0.50 1 07/02/12 18:40 156-59-2 NO uglL 0.50 0.50 1 07/02/12 18:40 156-M5 NO uglL 0.50 0.50 1 07/02/12 18:40 78.87-5 ND uglL 0.50 0.50 1 0710211218:40 142-28-9 ND uglL 0.50 0.50 1 07/02/12 18.40 594-20-7 ND uglL 0.50 0.50 1 07/02112 18:40 563-58-6 ND uglL 0,50 0.50 1 071021121840 10061-01-5 NO ugll- 0.50 0.50 1 07/02J1218:40 10061-02-6 1.3 uglL 0.50 0.50 1 07/02/12 18.40 108-20-3 ND uglL 0.50 0.50 1 07/02112 18:40 100-41-4 ND uglL 2.0 2.0 1 07/02/12 18:40 87-68-3 N❑ uglL 0.50 0.50 1 07/02/12 18.40 98-82-8 ND uglL 2.0 2.0 1 07/02/12 18.40 75-09-2 4.4 uglL 0.50 0.50 1 07/02/12 18.40 1634-04.4 ND uglL 2.0 2.0 1 0710211218:40 91-20-3 N❑ ug1L 0.50 0.50 1 07/02J12 18:40 103-65-1 N❑ uglL 0.50 0.50 1 07/02/12 18:40 100-42-5 NO uglL 0.50 0.50 1 07/02/12 18:40 630-20-6 ND ug1L 0.50 0.50 1 0710211218A0 79.34-5 Date. 07/09/2012 01-59 PM REPORT OF LABORATORY ANALYSIS Page 19 of 38 This report shall not be reproduced, except in Full, without the written consent of Pace Analyl cal Servkes, Inc,. a ;aceAnalAcal www.pecoAabs.com Project: Gilbarco 97746 Pace Project No.: 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 26804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Hunlersvilie, NC 28078 (704)875-9092 Sample: MW-47 Lab ID: 92122245008 Collected: W21112 11 30 Received. 06/22/12 17:25 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method. SM 6200B Tetrachloroethene 30.8 uglL 0.50 0.50 1 07/02/12 18:40 127-18-4 Toluene N❑ uglL 0.50 0.50 1 0710211218A0 108-88.3 1,2,3-Trichlombenzene ND uglL 2.0 2.0 1 0710211218.40 87-61.6 1,2,4-Trichtorobe nzene ND uglL 2.0 2.0 1 0710211218A0 120-82-1 1, 1. 1 -Trich to roetha n e N❑ uglt 0.50 0.50 1 0710211218,40 71-55-6 1,1.2-Trichloroethane ND uglL 0.50 0.50 1 0710211218:40 79-DO-5 Trichloroethene 108 ug& 0.50 0.50 1 07102/12 18:40 79-01-6 Trichioro5uorornelhane ND ug/L 1.0 1.0 1 07/02/12 18:40 75-69-4 1,2,3-Trichloropropane ND uglL 0.50 0.50 1 07102/1218:40 96-18-4 1,2,4-Trimethylbenzene ND uglL 0.50 0.50 1 07/02/12 18:40 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 0.50 1 07/02/1218.40 108-67-8 Vinyl chloride 1.0 uglL 1.0 1.0 1 07/02/12 18:40 75-01-4 m&p-Xylene N❑ ugll- 1.0 1.0 1 07/02/12 18:40 179601-23-1 ❑-Xylene NO uglL 0.50 0.50 1 07/02/12 18:40 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 07/02/12 18:40 17060-07-0 Dibromofluoromethane (S) 99 % 70-130 1 07/02/12 18:40 1868-53-7 4-Bromofluorobenzene (S) 96 % 70-130 1 07/02/12 18:40 460.00-4 Toluene-d8 (S) 98 % 70.130 1 07/02/12 18 40 2037-26-5 Date 07/09/2012 01.59 PM REPORT OF LABORATORY ANALYSIS Page 20 of 38 This report shall not be reproduced, except in Full. without the written consent of Pace Analytical Services, Inc. e ace Analytical www pbrelabs.mm Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)523-892 t Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kinney Ave. Suite 100 Huntersville, NC 28078 (704)875.9D92 Project. Giibarco 97746 Pace Project No.: 92122245 Sample: MW-49 Lab tD: 92122245009 Collected: 0612102 11:06 Received: 06/22/12 17.25 Matrix. Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 62110E MSV Analytical Method: SM 6200B Benzene NO uglL 1.0 1.0 2 0710211218.56 71-43.2 Bromobenzene NO uglL 1.0 1.0 2 0710211218.56 108-86-1 Bromochloromethane ND uglL 1.0 1.0 2 0710211218:56 74-97-5 Bromodichloromethane NO uglL 1.0 1.0 2 0710211218,56 75-27-4 Bromoform NO uglL 1.0 1.0 2 07/02/12 18:56 75-25-2 Bromomethane ND uglL 10.0 2.0 2 07/02/12 18:56 74-83-9 n-Butylbenzene N❑ uglL 1.0 1.0 2 07/02/12 18.56 104-51-8 sec-Butylbenzene NO uglL 1.D 1.0 2 07/02/12 18:56 135-98-8 tert-Butylbenzene N❑ u911- 1.0 1.0 2 07/02112 18:56 98-06-6 Carbon tetrachloride NO uglL 1.0 1.0 2 07102J12 18:56 56-23-5 Chlorobenzene ND uglL 1.0 1.0 2 07/02/12 18:56 108-90-7 Chloroethane NO uglL 2.0 2.0 2 07/02/12 18:56 75-00-3 Chloroform NO uglL 1.0 1.0 2 07/02/12 18:56 67-66-3 Chioromethane NO ugll- 2.0 2.0 2 07/02/12 18:56 74.87-3 2-Chlorotoluene ND ug& 1.0 1.0 2 07102M218:56 95.49-8 4-Ghlorotoluene ND ug1L 1.0 1.0 2 07/02/12 18:56 106-43-4 1,2-Dibromo-3-chforopropane NO uglL 2.0 2.0 2 07102/1218:56 96.12-8 Dibromochloromethane NO uglL 1.0 1.0 2 07/02/12 18:56 124-48-1 1,2-Dibromoethane (EDB) ND uglL 1.0 1.0 2 07102/12 1856 106-93-4 Dibromomethane ND uglL 1.0 1.0 2 07/02/12 18:56 74-95-3 1,2-Dichlorobenzene NO uglL 1.0 1.0 2 0710211218:5E 95.50-1 1,3-Dichlorobenzene NO uglL 1.0 1.0 2 07/02/12 18 56 541-73-1 IA-Dichlorobenzene ND ug1L 1.0 1.0 2 07/02/1216-56 106-46-7 Dichforodifluoromethane NO ug1L 1.0 1.0 2 07/02/1218:56 75.71-8 1,1-Dichioroethane 1.9 uglL 1.0 1.0 2 07/02/12 18 56 75.34-3 1,2-Dichloroethane NO uglL 1.0 1.0 2 07/02/12 18.56 107-06-2 1,1-Dichloroethene 7.3 uglL 1.0 1.0 2 07/02/12 18756 75-35-4 cis-1.2-Dichloroethene 372 uglL 1.0 1.0 2 07/02/12 18.56 156-59-2 trans-1,2-DichImethene ND uglL 1.0 1.0 2 07/02/1218:56 156-60-5 1,2-Dichloropropane ND ugll- 1.D 1.0 2 07/02/12 18:56 78.87-5 1,3-Dichloropropane ND ug1L 1.0 1.0 2 07/02/12 18:56 142-28-9 2,2-Dichloropropane ND uglL 1.0 1.0 2 071M12 18.56 594-20-7 1,1-Dichloropropene ND uglL 1.0 1.0 2 07/02/12 18:56 563-58-6 cis-1,3-Dichloroprope ne N❑ uglL 1.0 1.0 2 0710211218:56 10061-01-5 trans-1.3-Dichloropropene ND uglL 1.0 1.0 2 07/02/12 18.56 10061-02-6 ❑iisopropyl ether 1.7 uglL 1.0 1.0 2 07/02/12 18.56 108-20-3 Ethylbenzene NO uglL 1.0 1.0 2 0710211218:56 100-41-4 Hexachloro-1,3-butadiene ND uglL 4.0 4.0 2 07102J1218:56 87-68-3 Isopropylbenzene (Cumene) ND uglL 1.0 1.0 2 07/02/12 18:56 98-82-8 Methylene Chloride ND uglL 4.0 4.0 2 07102J12 18:56 75-09-2 Methyl-tert-butyl ether 2.8 uglL 1.0 1.0 2 07/02/12 18:56 1634-04-4 Naphthalene ND uglL 4.0 4.0 2 0710211218:56 91.20-3 n-Propylbenzene NO ug1L 1.0 1.0 2 07/02/12 18:56 103-65.1 Styrene NO uglL 1.0 1.0 2 07/02/12 18.56 100-42-5 1.1.1,2-Tetrachi oroethane ND uglL 1.0 1.0 2 0710211218:56 630-20-6 1,12,2-Tetrachloroethane, ND uglL 1.0 1.0 2 0710211218.56 79-34-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, with out the wrluen consent of Pace Analytical Services, Ine.. Page 21 of 38 s Pace Analytical Services, Inc. Pace Analytical Sorvlees, Inc. Pace Analytical Services, Inc. �+n ❑�1�r r aceA alyfic'aI 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave Suite 1D0 W,N, bbs WM Eden, NC 2728E Asheville, NC 28804 Huntersvilie, NC 28078 (336)62M921 (828)254.7176 (704)875-9092 ANALYTICAL RESULTS Project. Gilbarco 97746 Pace Project No. 92122245 Sample- MVV 49 Lab Ip: 92122245009 Collected: 06121/12 11 06 Received: 06122/12 17:25 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 62006 Tetrachloroethene 118 uglL 1.0 1.0 2 07/02/1218:56 127-18-4 Toluene NO uglL 1.0 1.0 2 07/02112 18:56 108-88-3 1,2,3-Trichlorobenzene NO uglL 4.0 4.0 2 0710211218:56 87-61-6 1,2,4-Trichlorobenzene NO uglL 4.0 4.0 2 0710211218!56 120-82-1 1,1,1-T6chloroethane NO uglL 1.0 1.0 2 D710211218.56 71-55-6 1,1,2-Trichloroethane NO uglL 1.0 1.0 2 0710211218:56 79-00-5 Trichloroethene 288 ug1L 1.0 1.0 2 0710211218:56 79-01-6 Trichloroftuoromethane 3.7 uglL 2.0 2.0 2 07/02/12 18.56 75-69-4 1,2,3-Trichloropropane NO uglL 1.0 1.0 2 0710211218:56 96-18-4 1,2,4-Trimethylbenzene NO uglL 1.0 1,0 2 07/02/1218:56 95-63-6 1,3,5- Trim ethytbenzene ND ugJL 1.0 1.0 2 07/02/12 18:56 108-67-8 Vinyl chloride NO uglL 2.0 2.0 2 07/02/12 18:56 75-01-4 m&p-Xylene NO uglL 2.0 2.0 2 07/0211218:56 179601-23-1 o-Xylene NO uglL 1.0 1.0 2 0710211218:56 95-47-45 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 2 07/02/12 18.56 17060-07-0 Dibromofluoromethane (S) 98 % 70-130 2 07/02/12 18:56 1868-53-7 4-Bromofluorobenzene (S) 97 I 70-130 2 07/02/12 18:56 460-0D-4 Toluene-d8 (S) 98 % 7D-130 2 07/02/12 18:56 2037-26-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 22 of 38 This report shall W be reproduced. except in full, without the written consent of Pace Analytical Services, Inc- /� n� f a Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Servkes, Inc. aceAnalytiol 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 KinceyAve. Suite 100 WWW wm Eden. NC 27288 Asheville, NC 28804 Hurnersvllle, NC 28078 [336]623.8921 (828)254-717E (704)875-9092 ANALYTICAL RESULTS Project Gilbaroo 97746 Pace Project No.: 92122245 Sample: MW-530 Lab ID: 92122245010 Collected: 06/21/12 11:00 Received: 06122112 17:25 Matrix Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200E li Analytical Method: SM 6200B Benzene ND uglL 1.2 1.2 2.5 0710211219.13 71-43-2 Bromobenzene NO uglL 1.2 1.2 2.5 0710211219.13 108.8&1 Bromochloromethane NO ug/L 1.2 1.2 2.5 0710211219:13 74-97-5 Bromodichloromethane NO uglL 1.2 1.2 2.5 07102/1219:13 75-27-4 Bromoform NO ug1L 1.2 1.2 2.5 07102/1219:13 75-25-2 Bromomethane NO ug1L 12.5 2.5 2.5 07102J1219:13 74-83-9 n-Butylbenzene NO uglL 1.2 12 2.5 07/02/1219:13 104-51.8 sec-Butylbenzene NO uglL 1.2 1.2 2.5 0710211219A3 135-98-8 teft-Butylbenzene NO uglL 1.2 1.2 2.5 0710211219:13 W06-6 Carbon tetrachloride NO uglL 1.2 1.2 2.5 0710211219:13 W23-5 Chlorobenzene ND uglL 1.2 1.2 2.5 07102J12 19:13 108-90-7 Chioroethane NO uglL 2.5 2.5 2.5 OVUM 19:13 75-00-3 Chloroform N❑ ug1L 1.2 12 2.5 07/0211219:13 67-66-3 Chloromeftne ND uglL 2.5 2.5 2.5 07102J12 19:13 74-87-3 2-Chlorotoluene NO uglL 1.2 1.2 2.5 0710211219.13 95-49-8 4-Chlorotoluene NO ug/L 1.2 1.2 2.5 07102J12 19:13 106-43-4 1,2-Dibromo-3-chloropropane NO ug1L 2.5 2.5 2.5 07102J12 19:13 W12-8 Dibromochloromethane NO ug/L 1.2 1.2 2.5 07/0211219:13 12448-1 1.2-Dibromoethane (EDB) NO ug)L 1.2 1.2 2.5 07102J12 19:13 106-934 Dibromomethane NO ug/L 1.2 1.2 2.5 07/0211219:13 74-95-3 1.2-Dichlorobenzene NO ug/L 1.2 1.2 2.5 0710211219-13 95-50-1 1,3-Dichlorobenzene NO ug1L 1.2 1.2 2.5 07102J12 19:13 541-73-1 1,4-Dichlorobenzene NO u9k 12 1.2 2.5 07102J12 19:13 106-46-7 Oichlorodifluoromethane NO ug/L 1.2 1.2 2.5 07/0211219:13 75-71-8 1,1-Dichloroethane 2A uglL 12 1.2 2.5 07102J12 19:13 75-34-3 1,2-Dichloroethane NO ug1L 1.2 1.2 2.5 07/0211219:13 107-06-2 1, 1 -Dichloroethene 81 ug/L 1.2 1.2 2.5 07/0211219:13 75-35-4 cis-1.2-Dichloroethene 598 ug/L 5.0 5.0 10 D7103/12 17:01 156-59-2 trans-1,2-Dichloroethene NO uglL 1.2 12 2.5 07102J12 19:13 156-60-5 1,2-Dichloropropene NO ug/L 1.2 1.2 2.5 0710211219:13 78-87-5 1,3-Dichloropropane N❑ ug/L 1.2 1.2 2.5 07/0211219:13 142-28-9 2,2-Dichloropropane NO uglL 1.2 1.2 2.5 07102J1219:13 594-20-7 1,1-Dichloropropene NO ug]L 1.2 1.2 2.5 07/02/12 19:13 563-5" cis- 1,3-D ichloropropen e ND uglL 1.2 1.2 2.5 07/02/12 19:13 10061-01-5 trans-1,3-Dichloropropene ND uglL 1.2 12 2.5 07102/12 19:13 10061-02-6 Diisopropyl ether 17.7 ug1L 1.2 1.2 2.5 07/02/12 19:13 108-20-3 Ethylbenzene NO ug)L 1.2 1.2 2.5 0710211219:13 10041-4 Hexachloro-1,3-butadiene NO uglL 5.0 5.0 2.5 07102J12 19:13 87-68-3 Isopropylbenzene {Cumene) ND ug)L 1.2 1.2 2.5 07102/12 19,13 98-82-8 Methylene Chloride NO uglL 5.0 5.0 2.5 07/02/12 19:13 75-09-2 Methyl -tent -butyl ether 20.3 ug/L 1.2 1.2 2.5 07102/12 19:13 1634-04-4 Naphthalene ND ug/L 5.0 5,0 2.5 07102/1219:13 91-20-3 n-Propylbenzene NO uglL 12 1.2 2.5 07102J12 19:13 103-65-1 Styrene NO uglL 1.2 1.2 2.5 07102/1219:13 100-42-5 1.1.1,2-Tetrachtoroethane N❑ ug/L 1.2 1.2 2.5 0710211219:13 630-20-6 1,1,2,2-Tetrachtoroethane ND uglL 1.2 11 2.5 0710211219:13 79-34-5 Date. 07/09/2042 01:59 PM REPORT OF LABORATORY ANALYSIS Page 23 of 38 This report shall not be reproduced, except in Full, without the written eon sent of Pace Analytical Seryces, Inc.. B ace Analytical wMw.pece4bs-mm Project Gilbarco 97746 Pace Project No : 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. A;hevllle, NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve, Suite 1Do Muntersville. NC 28076 (704)875-9092 Sample: MW-53D Lab ID: 92122245010 Collected: W21112 11:00 Received: 06/22/12 17:25 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 62006 Tetrachloraethene 41.9 uglL 1.2 1.2 2.5 07/02/12 19:13 127-18-4 Toluene N❑ uglL 1.2 1.2 2.5 07/02/12 19.13 108-88-3 1,2,3-Trichiorobenzene ND uglL 5.0 5.0 2.5 07102J1219:13 87-61-6 1,24-Trichlorobenzene ND uglL 5.0 5.0 2.5 07102J1219:13 120-82.1 1,1,1-Trichloroethane NO uglL 1.2 1.2 2.5 0710211219:13 71-55-6 1,1,2-Trichioroethane ND uglL 1.2 1.2 2.5 0710211219:13 79-00-5 Trichloroethene 32.7 uglL 1.2 1.2 2.5 07/02/12 1913 79-01-6 Trichiorofluoromethane ND ug1L 2.5 2.5 2.5 07/0211219:13 75-6" 1,2.3-Tdchloropropane ND uglL 1.2 1.2 2.5 07/02/1219:13 96-18-4 1,2,4-Trimethylbenzerle NO uglL 12 1.2 2.5 07/02/12 1913 95-63-6 1,3,5-Trimethylbenzene ND ugiL 1.2 1.2 2.5 07/02/12 19:13 1OM7-8 Vinyl chloride ND uglL 2.5 2.5 2.5 07/02/12 19A3 75-014 m&p-Xyiene N❑ uglL 2.5 2.5 2.5 07/02/12 19:13 179601-23-1 o-Xylene ND uglL 12 1.2 2.5 07/02/12 19.13 95-47-6 Surrogates 1,2-❑ichloroethane-d4 (5) 99 % 70-130 2.5 07/02/12 19:13 17060-07-0 Dibromofluoromethane (S) 99 % 70.130 2.5 07/02/12 19 13 1868-63-7 4-BromoRuorobenzene (S) 95 I9 70-130 2.5 07/02/12 19:13 460-00-4 Toluene-d8 (S) 99 I 70-130 2.5 07/02/12 19:13 2037-26-5 Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 24 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. .1!aceAnalytical ! �:pace�ba.awn Pace Analytical Services, tnc- 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytlea I Services, Inc. 2225 Riverside dr. Asheville. NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Klncey Ave Suite 100 Huntersvllle, NC 28078 (704)875-9092 Project: Gilbarco 97746 Pace Project No.'. 92122245 Samples Trip Blank Lab ID 92122245011 Collected D6121112 00.00 Received06/22/12 17:25 Matrix: Water Reporl Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene NO ug/L 0.50 0.50 1 07/02/12 19:30 71-43-2 Bromobenzene NO uglL 0.50 0-50 1 07102M219:30 108-86-1 Bromochloromethane ND uglL 0-50 0,50 1 07/02/12 19:30 74-97-5 Bromod}chloromethane NO uglL 0,50 0-50 1 07/02/12 19:30 75-27-4 Bromoform ND uglL 0-50 0-50 1 07/02/12 19:30 75-25-2 Bromomethane NO uglL 5.0 1-0 1 071=12 19:30 74-83-9 n-Butylbenzene NO uglL 0-50 0-50 1 07102/1219:30 104-51-8 sec-Butylbenzene ND uglL 0,50 0-50 1 07102/1219:30 135-98-8 tert-Butylbenzene NO ug1L 0-50 0-50 1 07/02112 19:30 98-06-6 Carbon tetrachloride NO uglL 0.50 0-50 1 07/02/12 19 30 56-23-5 Chlorobenzene NO uglL 0.50 0.50 1 07/02/12 19.30 108-90-7 Chloroethane NO ug1L 1.0 1-0 1 071MM219:30 75-00-3 Chloroform NO ug/L 0.50 ❑-50 1 07/02/12 19:30 67-66-3 Chloromethane ND uglL 1-0 1.0 1 07102/12 19.30 74-87-3 2-Chlorotoluene NO uglL 0.50 0.50 1 07102/12 19:30 95-49-8 4-Chlorotoluene NO uglL 0.50 0.50 1 07/02/12 19.30 106-43-4 1,2-Dibromc-3-chioropropane ND uglL 1.0 1.0 1 0710211219.30 96-12-8 Dibromochioromethane NO uglL 0.50 0.50 1 07/02/12 %30 12448.1 1,2-Dibromoethane (EDB) NO uglL 0.50 0.50 1 07102J12 19:30 106-93-4 Dibromomethane NO uglL 0.50 0.50 1 07102/12 19:30 74-95.3 1,2-❑ichiorobenzene NO uglL 0.50 0.50 1 07/02/12 19:30 95-50.1 13-Dichlorobenzene ND uglL 0.50 0-50 1 0710211219:30 541-73-1 1.4-Dichlorobenzene NO uglL 0.50 0,50 1 07/02/12 19.30 10646.7 Dichtorodifluoromethane N❑ uglL 0.50 0.50 1 0710211219:30 75.71-8 1, 1 -Di ch to roetha ne ND u911- 0-50 0-50 t 0710211219:30 75-34-3 1,2-❑ichloroethane NO uglL 0.50 0-50 1 0710211219.30 107-06-2 1,1-0ichtoroethene ND ug1L 0,50 0.50 1 0710211219:30 75-35-4 cis- 1.2-DichIoroethene ND uglL 0,50 0-50 1 07/02/12 19:30 156-59-2 trans-1.2-Dichloroe thene N❑ uglL 0.50 0,50 1 07/02/12 19.30 156-60-5 1,2-Dichloropropane NO ug)L 0.50 0,50 1 07/02/12 19:30 78-87-5 1,3-❑ichloropropane NO uglL 0-50 0.50 1 0710211219:30 142-28-9 2,2-Dichloropropane ND uglL 0-50 0.50 1 07102J12 19:30 594-20.7 1.1-Dichloropropene NO uglL 0.50 0.50 1 07/02/12 19:30 563-58-6 cis-1.3-Dichloropropene ND uglL 0.50 0.50 1 0710211219:30 1DD61-01-5 trans- 1.3-DichIoropropene ND uglL 0-50 0.50 1 0710211219.30 10061-02-6 Diisopropyl ether NO uglL 0.50 0.50 1 07/02/12 19:30 108.2D-3 Ethylbenzene NO uglL 0.50 0.50 1 0710211219:30 1DO-41.4 Hexachioro-1,3-butadiene NO uglL 2.0 2.0 1 (17102M219:30 87-68-3 lsopropylbenzene (Cumene) NO uglL 0.50 0.50 1 07/02112 19:30 98-82-8 Methylene Chloride NO uglL 2.0 2.0 1 07/02112 19:30 75-D9.2 Methyl-tert-butyl ether NO ug1L 0.50 0.50 1 07/02/12 19:30 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 07/02/12 19:30 91-210-3 n-Propylbenzene NO ug)L 0.50 0.50 1 0710211? 19:30 103-65-1 Styrene NO ug)L 0-50 0.50 1 07102J12 19:30 100-42.5 1.1.1,2-Tetrachloroethane ND uglL 0.50 0.50 1 07/02/12 19:30 630-20-6 1.1.2,2-Tetrachloroethane ND uglL 0.50 0.50 1 07/02/12 19:30 79-34-5 pate: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 25 of 38 This report shall not be reproduced, except in full, without the written consent or Pace Analytical Services, Inc.. aceRnalytica!e wwwPrroe7ahs.aam Project: Gilbarco 97746 Pace Projecl No.: 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 272B8 (336)623-8921 Pace Analytical Services, Inc. 2- 25 Riverside Dr. Ashevilia, NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntemville, NC 28078 (704)875-9092 Sarnple: Trip Blank Lab ID: 92122245011 Collected: 06/21/1200:00 Received: 06/22/12 17.25 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 Tetrachloroethene ND ug)L 0.50 0.50 1 07/02/12 19:30 127-18-4 Toluene ND ug)L 0.50 0.50 1 0710D12 19 30 108-88-3 1,2,3-Trichiorobenzene ND ug/L 2.0 2.0 1 0710211219:30 87.61-6 1,2,4-Trichlorobenzene N❑ uglL 2.0 2.0 1 0710211219:30 120-82-1 1.1,1-Trichloroethane ND uglL 0.50 0,50 1 07/0211219.30 71-55-6 1,1,2-Trichloroethane ND uglL 0.50 0.50 1 07/02/1219:30 79-00-5 Trichloroethene N❑ uglL 0.50 0.50 1 07/02/12 19:30 79-01-6 Trichlorofluoromethane N❑ ug1L 1.0 1.0 1 07/02/12 19.30 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 0.50 1 07/02112 19:30 96-18-4 1,2,4-Trimethylbenzene ND uglL 0,50 0.50 1 07/02/12 19:30 95-63-6 1,3,5-Trimethylbenzene ND ug1L 0.50 0.50 1 07/02/12 19:30 10"7-8 Vinyl chloride ND ug/L 1.0 1.0 1 07/02/12 19:30 75-014 m&p-Xylene ND ug/L 1.0 1.0 1 07102J1219-30 179601-23.1 o-Xylene ND ug/L 0.50 0.50 1 07/02/12 19-30 95--47-6 Surrogates 1,2-Dir-Woroettlane-d4 (5) 101 °I 70-130 1 07/02/12 19:30 17060-07-0 Dibromofluoromethane (S) 97 % 70-130 1 07102J12 19:30 1868-53-7 4-Bromofluorobenzene (S) 97 % 7D-130 1 07/02/12 19:30 460-00-4 Toluene-d8 (S) 100 % 70.130 1 07/02/12 19:30 2037-26-5 Date: 07/a9r2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 26 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ace Analytical . �'�'vaosebs.wm Project: Gilbarco 97746 Pace Project No.. 92122245 Pate Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA ❑C BatchM5V119579 Analysis Method: 5M 62008 CC Batch Method 5M 62008 Analysis Description: 6200E MSV Associated Lab Samples. 92122245001. 92122245002, 92122245003, 92122245004, 92122245005 METHOD BLANI(. 786052 Matrix: Water Associated Lab Samples: 92122245001, 92122245002, 92122245003. 92122245004, 92122245005 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethano uglL ND 0.50 06/27/12 22:20 1,1,1-Trichlorcethane ug1L N❑ 0.50 06/27/122220 1.1.2.2-Tetrachloroethane ug1L ND 0.50 06/27112 2220 1,1.2-ThChloroethano uglL NO 0.50 06/27/12 22:20 1,1-Dichloroethane ug1L ND 0.50 06/27/12 22:20 11-Dichloroethene uglL ND 0,50 06127/122220 1,1•Dichloropropene uglL N❑ 0,50 0612711222:20 1,2,3-Trichlorobenzene uglL NO 2.0 06/27/12 22:20 1,2,3-Trichloropropane ug/L NO 0,50 06/27/12 22:20 1,2,4-Trichlorobenzene uglL ND 2.0 06/27/12 22:20 1,2,4-Trimethylbenzene uglL ND 0.50 06/27112 22.20 1,2-0ibromo-3-chloropropano ug/L N❑ 1.0 06/27/12 22 20 1,2-Dibromoethane [EDB] ug& NO 0.50 06/27/12 22:20 1,2-Dichlorobenzene uglL NO 0.50 06/27/12 22:20 1,2-Dichloroethane ug)L ND 0.50 06/27/12 22:20 1,2-Dichieropropane uglL NO 0.50 06/27/12 22.20 1.3,5-Trimethylbenzene uglL NO 0.50 06/27/12 22:20 1,3-Dichiorobenzene ug1L NO 0.50 06/27/12 22:20 1,3•Dichloropropane ug1L ND 0,50 06/27/12 22.20 1,4-Dichlorobenzene uglL NO 0.50 06/27/12 22:20 2,2-Dichloropropane ug1L ND 0.50 06/27/12 22:20 2-Chlorotoiuene uglL ND 0,50 06/27/12 22:20 4-Chlorotoluene ug1L N❑ 0.50 06/27/12 22:20 Benzene ug1L ND 0.50 06/27/12 22:20 Sromobenzene uglL ND 0,50 06/27/12 22:20 Bromochloromethane ug1L ND 0.50 06/27/12 22:20 Bromodichloromethane uglL ND 0.50 06/27/12 22.20 Bromoform uglL N❑ 0,50 06/27/12 22:20 Bromomethane ug1L N❑ 5.0 06/27/12 22.20 Carbon tetrachloride uglL ND 0.50 06/27/12 22:20 Chlorobenzene uglL ND 0.50 06/27/12 2220 Chloroethane uglL ND 1.0 06/27/12 22:20 Chloroform uglL NO 0.50 06/27/12 22:20 Chloromethane uglL ND 1.0 06/27/12 22:20 cis- 1,2-Di chi oroethene uglL ND 0.50 06/27112222C cis- 1,3-Dichloropropene uglL N❑ 0.50 W2711222.20 Dibromochloromethane ug/L N❑ 0.50 06/27/12 22:20 Dibromomethane uglL ND 0,50 06/27/12 22:20 DichlorodiNuoromethane ugll- ND 0.50 06/27/12 2220 Diisopropyl ether uglL ND 0.50 W27112 22-20 Ethylbenzene ug.1L N❑ 0.50 06/27/12 22:20 Hexachloro-1.3-butadiene ugli- NO 2.0 06/27/12 2220 Isopropylbenzene (Cumene) ugel- NO 0.50 06127/12 2220 Date: 07/0912012 01 59 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. without the written consent cf Pace Ana ly licaI Services, Inc. Qualifiers Pace Analytical Services, Inc. 9800 KinceyAve . Suite 1p0 Huntersville, NC 28078 (704$75-9092 Page 27 of 38 /';''ceAnallytical" 1 wwwraGwabs.mm Project: Gilbarco 97746 Pace Project No.: 92122245 Pace Analytical Services, Inc. 205 East Meadow Road • SuiteA Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 (828)254-7176 QUALITY CONTROL DATA METHOD BLANK: 786052 Associated Lab Samples: Parameter Matrix: Water 92122245001, 92122245002. 92122245003. 92122245004. 92122245005 Blank Reporting Units Result Limit Analyzed m&p-Xylene ug/L NU 1.0 06/27/12 22:20 Methyl-tert-butyl ether ug/L NO 0.50 06/27/12 22:20 Methylene Chloride ug/L ND 2.0 06/27/12 22:20 n-Butylbenzene ug/L NO 0.50 06/27/12 22:20 n-Propylbenzene ug/L ND 0.50 06127/12 22:20 Naphthalene uWL ND 2.0 06/27/12 22:20 a-Xylene ugfL NO 0.50 06127/12 22.20 sec-Butylbenzene ug(L NO 0.50 06/27/12 22:20 Styrene uWL ND 0.50 06/27/12 22:20 left-Butylbenzene uWL N❑ 0.50 06/27/12 2220 Tetrachloroethene uWL ND 0.50 06/27/12 2220 Toluene ug/L ND 0.50 06/27/12 22:20 trans-1,2-0ichIoroethene ug/L ND 050 06/27/12 22:20 trans-1,3-Dichloropropene OWL ND 0.50 06127/1222:20 Trichloroethene uWL ND 0.50 06/27/12 22.20 Trichlorofluoromethane uWL ND 1.0 06/27/12 22:20 Vinyl chloride uWL ND 1.0 06/27/12 22:20 1,2-Dichloroethane-d4 (S} % 105 70-130 06/27)12 22:20 4-Bromofluorobenzene (S) % 94 70-130 06/27112 22:20 Dibromofluorom ethane (S) % 100 70-130 06/27/12 22 20 Toluene -dB (S) % 99 70-130 06/27/12 22:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 786053 Units Spike Conc. LCS Result LCS I Rec % Rec Limits 1,1.1,2- Tetra chtoroe thane ug/L 50 54.0 108 60-140 1,1,1-Trichtoroethane ug/L 50 46.1 92 60-140 1,1,2,2-Tetrachtoroethane ug/L 50 50.3 101 60-140 1,1,2-Trichloroethane ug/L 50 62.5 105 60-140 1,1-Di chIoroethane uWL 50 42.6 85 60-140 1,1-Dichloroethene ug1L 50 48.3 97 60-140 1,1-Dichiorapropene uWL 50 45.6 91 60-140 1,2,3-Trichlorobenzene ug/L 50 49.4 99 60-140 1,2,3-Trichloropropane ug/L 50 50.7 101 60-140 1,2,44richlorobenzene ug/L 50 499 1DO 80.140 1,2,4-Tfimethy Then Zen e ug/L 50 53.6 107 60-140 1,2 -Di b rom o- 3- ch lorop ro pa ne ug/L 50 58.0 116 60-140 12-Dibromoethane [EDB] ug/L 50 50.6 101 60-140 1,2-Dichlorobenzene ug/L 50 49.9 100 60-140 1,2-Dichloroethane ug/L 50 46.7 93 60-140 1.2-Dichloropropane ugfL 50 47.2 94 60-140 1.3,5-Trimethylbenzene ug& 50 52.1 104 60-140 1,3-Dichlorobenzene ug/L 50 49.8 100 60-140 1,3•Dichloropropane ugfL 50 48.5 97 60-140 1,4-Dichlorobenzene ug/L 50 48.7 97 60-140 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 28978 (704)875-9092 Qualifiers Date: 07/09/2012 01.59 PM REPORT OF LABORATORY ANALYSIS Page 28 of 38 This report shall not be repn>duced, except in full, without the written consent of Pace Analytical Services, inc.. ace "'W/ trcal b www.pacalabs.com Project Gilbarco 97746 Pace Project No. 92122245 Pace Analytical Sorvtees, Inc. 05 Ea st Meadow Road - Suite A Eden, NC 27268 (336)623-8921 Pace Analytical Services. Inc. 2225 Riverside Or. Asheville, NC 28804 (828)254.7176 QUALITY CONTROL DATA LABORATORY CONTROL SAMPLE. Parameter 786053 Units Spike Cone LCS Result 2,2-❑ichloropropane ugiL 50 42.4 2-Chlorotaluene ugiL 50 48.5 4-Chlorotoluene u911- 50 50.7 Benzene ugiL 50 49.7 Bromobenzene ug1L 50 46.9 Bromochiaromethane ugiL 50 50.5 Bromodichloromethane ug1L 50 50.5 Bromoform ugiL 50 47.9 Bromomethane ugiL 50 568 Carbon tetrachloride ugiL 50 54.9 Chlorobenzene ugll_ 50 50.5 Chloroethane ugiL 50 57.1 Chloroform ugiL 50 48.1 Chloromethane ug1L 50 47.0 cis -1,2-Dichloroethene ugiL 50 47.6 cis- 1,3-Dichloropropene ugiL 50 52.4 Dibrorrrochloromethane ugiL 50 55.2 Dibromomethane ugiL 50 51.9 Dichlorodifluoromethane ugiL 50 43.1 Diisopropyl ether u911- 50 46.2 Ethylbenzene ug1L 50 51.6 Hexachloro-1,3-butad iene ugiL 50 52.8 Isopropylbenzene (Cumene) ugiL 50 48.7 m&p•Xyle ne ugiL 100 104 Methyl-tert-butyl ether ugiL 50 47.6 Methylene Chloride ugiL 50 52.1 n-Butylbenzene ugiL 50 52.9 n-Propytbenzene ug1L 50 48.3 Naphthalene ug1L 50 50A o-Xylene ug1L 50 49.7 sec-Butylbenzene ugiL 50 52.3 Styrene ugiL 50 54.9 ter(-Butylbenzene ug1L 50 50.9 Tetrachloroethene ugiL 50 49.9 Toluene ug1L 50 50.3 Ira ns-1.2-0ichloroethene ugiL 50 46.1 trans•1.3-Dichi oropropene ugiL 50 54.0 Trichloroethene ugiL 50 50.1 Trichlomflucromethane ug1L 50 48.6 Vinyl chloride ug1L 50 44.3 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % ❑ibromofluorometharie (S) I Toluene -dB (S) I LCS % Rec % Rec Limits 85 60-140 97 60-140 101 60-140 99 60-140 94 60.140 101 60-140 101 60-140 96 60-140 114 60-140 110 60-140 101 60-140 114 60-140 96 60-140 94 60-140 95 60-140 105 60-140 110 60-140 104 60-140 86 60-140 92 60.140 103 60.140 106 60.1.40 97 60-140 104 60-140 95 M140 104 60-140 106 60-140 97 60-140 101 60-140 99 60-140 105 60-140 110 60-140 102 60-140 100 60-140 101 60-140 92 60-140 108 60-140 100 60-140 97 60-140 89 OD-140 94 70-130 103 70-130 100 70-130 100 70-130 Pace Anatytical Services, Inc. 9800 Kincey Ave. Suile 100 HUnterSVllle, NC 28078 (704)675-9092 Qualifiers Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 29 of 38 This report shall not be reproduced, except in full. without the written consent of 9ace Analytical Services, inc.. ace AnalX cals "W..Peoera8a.tam Pace Analytical Services, Inc. 205 Easl Meadow Road - Suite A Eden, NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28604 (878)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kinney Ave. Suite 100 Hunter5ville, NC 28078 (704)875-9092 Project. Gilbarco 97746 Pace Project No.: 92122245 MATRIX SPIKES MATRIX SPIKE DUPLICATE 786054 786055 MS MSD 92122252001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua[ 11,12-Tetrachloroethane uglL ND 20 20 16.0 20.1 80 101 60-140 23 30 1.1,1-Tdr-hloroethane uglL ND 20 20 16.1 18.8 80 94 60-140 15 30 1,1,2,2- Tetra chtoroe thane uglL ND 20 20 14.6 15.2 73 91 60-140 22 30 1.1,2-Trichtoroethane uglL ND 20 20 17.7 20.9 Be 105 60-140 17 30 1,1-Dichloroethane uglL NO 20 20 15.1 17.5 76 87 60-140 14 30 1,1-Dichloroethene uglL NO 20 20 18.1 20.3 90 102 60-140 12 30 1,1-Dicflloropropene uglL NO 20 20 16.8 19.4 84 97 60-140 14 30 1,23-Trichlorobenzene uglL NO 20 20 13.0 17.4 65 87 60-140 29 30 1,2,3-Triehloropropane uglL ND 20 20 15.2 19.1 76 96 W140 23 30 1,2,4-Trichlorobenzene uglL ND 20 20 13.0 17.2 65 85 60-140 28 30 1,2,4-Trimethylbenzene uglL ND 20 20 16.2 20.3 81 101 60-140 22 30 1,2-Dibromo-3-chloropropane ug1L NO 20 20 15.4 19.0 77 95 60-140 21 30 1.2-Dibromoethane (EDB) uglL NO 20 20 16.5 20.0 82 100 60-140 20 30 1,2-Dichlorobenzene ug/t- ND 20 20 15.3 18.7 77 94 60-140 20 30 12-Dichlaroethane uglL NO 20 20 16.9 19.7 84 98 60-140 15 30 1,2-Dichloropropane uglL N❑ 20 20 16.3 19.2 81 96 60-140 16 30 1,3,5-Trimethylbenzene uglL ND 20 20 15.7 19.4 79 97 60.140 21 30 1,3-Dichlorobenzene ug& N❑ 20 20 15.2 18.8 76 94 60-140 21 30 1.3-Dichloropropane uglL ND 20 20 16.4 19.6 82 98 60-140 18 30 1,4-Dichlorobenzene uglL NO 20 20 15.3 18.5 76 92 60-140 19 30 2,2-Dichloropropane ug/L NO 20 20 11.3 13.0 57 65 60-140 14 30 MO 2-Chlorotoluene uglL NO 20 20 15.6 18.9 78 95 60-140 20 30 4-Chlorotoluene uglL NO 20 20 15.8 19.5 79 97 60-140 21 30 Benzene ug/L NO 20 20 17.3 20.1 86 101 60-140 15 30 Bromobenzene uglL NO 20 20 14.9 182 74 91 60.140 20 30 Bromochioromethane ug1L ND 20 20 17.2 20.0 86 100 60-140 15 30 Bromodichloromethane uglL ND 20 20 15.8 18.9 79 95 60-140 18 30 Bromoform uglL ND 20 20 13.2 16.4 66 82 60-140 21 30 Bromomethane uglL NO 20 20 18.3 20.0 91 100 60-140 9 30 Carbon tetrachloride ug1L NO 20 20 17.2 20.3 86 102 60-140 16 30 Chlorobenzene uglL NO 20 20 16.4 20.0 82 100 60-140 20 30 Chloroethane ug1L ND 20 20 20.6 232 103 116 60-140 12 30 Chloroform ug1L ND 20 20 16.6 19.7 83 98 60-140 17 30 Chloromethane ug1L N❑ 20 20 15.4 18.2 77 91 60-140 17 30 cis-1,2-0ichioroethene ug1L ND 20 20 16.9 19.6 84 98 60-140 15 30 cis -1,3-DichIoropropene uglL N❑ 20 20 14.7 17.7 74 88 60-140 18 30 Di b rom och I orometh a n e uglL ND 20 20 14.9 19.0 75 95 60-140 24 30 Dibromomethane uglL N❑ 20 20 16.9 20.1 85 100 60-140 17 30 Dichlorodituoromethane uglL N❑ 20 20 16.9 18.1 85 91 60-140 7 30 Diisopropyl ether uglL NO 20 20 16.0 19.1 80 96 60-140 18 30 Ethylbenzene uglL NO 20 20 16.6 20.1 83 100 60-140 19 30 Hexachloro-1,3-butadiene uglL NO 20 20 12.1 16.9 56 80 60-140 33 30 MO,R1 Isopropylbenzene (Cumene) ug)L NO 20 20 14.5 17.9 73 90 60-140 21 30 m5p-Xylene uglL ND 40 40 32.8 40.1 81 100 60-140 20 30 Methyl-tert-butyl ether uglL ND 20 20 16-2 19.3 81 96 60-140 18 30 Methylene Chloride uglL ND 20 20 18.1 20.5 91 102 60-140 12 30 n-Butylbenzene uglL ND 20 20 14.6 184 73 92 60-140 23 30 Date: 07/09/2012 01.59 PM REPORT OF LABORATORY ANALYSIS Page 30 of 38 This report srtiali nol be reproduced, except in tuil. without the written consent of Pace Analytical Services. Inc. 1�;a'ce Analytical wwwps[xlebs.cam Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Or. Asheville. NC 28804 (828)254-7 t 76 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huniersville. NC 28078 (704)875-9092 Project: Giibareo 97746 Pace Project No.: 92122245 MATRIX SPIKE & MATRIX SPIKE ❑LIPLICATE 786054 786055 MS MSD 92122252001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec I Rec Limits RPD RPD Qual n-Propylbenzene ug/L N❑ 20 20 15.1 18.5 76 92 60-140 20 30 Naphthalene uglL ND 20 20 13.7 18.0 68 90 60-140 27 30 o-Xylene ug/L ND 20 20 15.2 18.7 76 94 60-140 21 30 sec-Butylbenzene ug/L ND 20 20 15.2 18.9 76 95 60-140 22 30 Styrene ug/L N❑ 20 20 15.5 19.4 77 97 60-140 22 30 tert-Butylbenzene ug/L ND 20 20 15.2 18.9 76 95 60-140 22 30 Tetra chloroethene ug/L ND 20 20 16.8 19.6 84 98 60-140 16 30 Toluene ug/L ND 20 20 16.7 19.7 84 99 60-140 16 30 trans-1.2-Dichloroethene ug/L ND 20 20 17.2 19.2 86 96 60-140 11 30 trans-1,3-Dichloroprope ne ug/L ND 20 20 14.4 17.8 72 89 60-140 21 30 Trichloroethene ug/L N❑ 20 20 17.5 20.5 88 103 60-140 16 30 Tri ch to rof u o rom e th a n e uglL ND 20 20 18-6 20A 93 102 60.140 9 30 Vinyl chloride ug/L ND 20 20 16.6 18-0 83 90 60.140 8 30 1.2-Dichloroethane-d4 (S) % 99 98 70-130 4-BromoBuorobenzene (S) % 99 100 70-130 Dibromofluoromethane (S) % 99 100 70-130 Toluene-d8 (S) % 99 99 70-130 Date: 07/09/2012 01:59 PM REPORT Of LABORATORY ANALYSIS Page 31 of 38 This report shall not be reprodw-, d, except in full. without the written consent of Pace Analytical Services. Inc.. e• aceAnalyfical wwwpacekba mm Project. Gilbarco 97746 Pace Project No.. 92122245 QC Batch MSV119610 OC Batch Method: SM 6200B Pace Analytical Services, Inc- 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside ❑r. Asheville, NC 28804 QUALITY CONTROL DATA Analysis Method: 5M 6200B Analysis Description: 6200B MSV t828j254.7176 Associated Lab Samples. 92122245006, 92122245007, 92122245008, 92122245009. 92122245010, 92122245011 METHOD BLANK: 788631 Matrix: Water Associated Lab Samples: 92122245006, 92122245007, 92122245008. 92122245009. 92122245010, 92122245011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane uglL ND 0-50 07/02/1215:19 1,1,1-Trichloroethane uglL N❑ 0-50 07102J1215.19 1, 1. 2.2 -Tetrachloroeth a n e uglL N❑ 0-50 07102J1215:19 1.1.2-Trichloroethane uglL ND 0,50 0710211215A9 1,1-Dichloraethane ug1L ND 0.50 07/02/1215.19 1.1-Di chi oroethe ne uglL ND 0-50 07/02/1215:19 1.1-Dichloropropene uglL N❑ 0-50 07102/1215:19 12,3-Trichlorobenzene uglL N❑ 2.0 07102J121519 1,2,34richloropropane uglL ND 0-50 07/0211215.19 1,2,4-Trichlorobenzene uglL ND 2.0 07102/1215:19 1,2,4-Trimethylbenzene uglL ND 0,50 07IM1215:19 12-Dibromo-3-chloropropane uglL ND 1-0 0710211215:19 1,2-Dibromoethane (EDB) ug1L N❑ 0.50 07/02112 15:19 1,2-Dichlorobenzene uglL ND 0.50 0710211215:19 1,2-Dichloroethane uglL NO 0.50 0710211215:19 1,2-Dichloropropane ug1L ND 0.50 0 7107J 12 1519 1,3,5-Trimethylbenzene uglL ND 0.50 07/02/12 15:19 1,3-Dichlorobenzene uglL ND 0.50 0710211215:19 1,3-Dichloropropane ug/L ND 0.50 0710211215:19 1,4-0ichlorobenzene uglL ND 0.50 07/0211216:19 2,2•Dichloropropane uglL ND 0.50 0710211215�19 2-Chlorotoluene uglL ND 0.50 07/02/1215:19 4-Chlorotoluene ug[L N❑ 0.50 07/0211215:19 Benzene uglL ND 0-50 0710211215.19 Bromobenzene uglL ND 0.50 0710211215:19 Bromochloromethane uglL ND 0.50 07102/1215:19 Bromodichloromethane uglL ND 0-50 0710211215:19 Bromoform uglL N❑ 0-50 0710211215:19 Bromomethane uglL ND 5.0 0710211215:19 Carbon tetrachloride uglL ND 0-50 07J02112 15:19 Chlorobenzene uglL ND 0-50 07102/1215:19 Chloroethane uglL N❑ 1.0 07IM121519 Chloroform ug1L ND 0.50 07102M215:19 Chloromethane uglL ND 1.0 07102/1215:19 cis-1.2-Dichloroethene uglL ND 0-50 0710211215:19 69-1,3-Dichloropropene uglL N❑ 0,50 07102/1215:19 Dibromochloromethane ug1L ND 0.50 0710211215:19 Dibromomethane uglL ND 0.50 071D2/1215:19 ❑ichlorodif! uoromethahe uglL ND 0-50 07102/1215:19 ❑iisopropyl ether uglL ND 0.50 07/02/12 15:19 Ethylbenzene uglL ND 0.50 07102J1215:19 Hexachloro-1,3-butadiene uglL ND 2.0 0710211215:19 Isopropylbenzene (Cumene) uglL ND 0.50 07/02/12 15:19 Date 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS This report shall not tie repmduced• except in full. without the wrMen consent of Pace Analytical Services. Inc -. Pace Analytical Services, Inc- 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875.9092 Page 32 of 38 2ace Anap cal www.pacoARU.own Project: Gilbarco 97746 Pace Project No. 92122246 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)523.8921 Pace Anatytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)25A-7176 QUALITY CONTROL DATA METHOD BLANK 788631 Matrix: Water Associated Lab Samples. 92122245006, 92122245007, 92122245008. 92122245009. 92122245010, 92122245011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers m&p-Xylene ug)L NO 1.0 0710211215:19 Methyl-tert-butyl ether uglL ND 0.50 07/02/12 15:19 Methylene Chloride ugll- ND 2.0 07/02/12 15:19 n-Butylbenzene uglL NO 0.50 0710211215:19 n-Propylbenzene uglL ND 0.50 07/02/1215:19 Naphthalene uglL ND 2.0 07/02/12 15A 9 o-Xylene uglL ND 0.50 07102/1215:19 sec-Butylbenzene ug)L ND 0.50 0710211215:19 Styrene uglL ND 0,50 07102/1215:19 tert-Bulylbenzene uglL ND 0.50 07102J12 W19 Tetrachloroethene uglL ND 0.50 07102/12 15: 19 Toluene ug1L NO 0.50 07102/1215:19 trans-1.2-0ichloroethene uglL ND 0.50 071=1215:19 trans- 1,3-0ichloroprope ne ug1L ND 0.50 07=11215A9 Trichloroethene uglL ND 0.50 07102/1215:19 Trich I= Ruorom e tha ne ug.!L ND 1.0 07102/1215:19 Vinyl chloride ug1L NO 1.0 07/02/12 15:19 1,2-0ichloroethane-d4 (S) % 99 70-130 07/02/12 1519 4-Bromolluorobenzene (S) % 97 70-130 071C12/12 15:19 Dibromofluoromethane (5) % 96 70-130 07102/12 15.19 Toluene-d8 (S) Io 100 70-130 07/02/12 15:19 Pace Analytical Services, Inc. 9800 Kincey Ave Suite 100 Hunters0le, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: Parameter 788632 units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 11,12-Tetrachloroethane u91L 50 55.8 112 60-140 1,1,1-Trichloroethane uglL 50 48.6 97 60-140 1.1.2,2-Tetrachloroe thane uglL 50 52.5 105 60-140 1.1.2-Trichtoroethane uglL 50 56.9 114 60-140 1,1-Dichloroethane uglL 50 46.0 92 60-140 1,1-Dichloroethene uglL 50 52.7 105 60-140 1,1-Dichloropropene uglL 50 52.0 104 60-140 1,2,3-Trichlorobenzene ug1L 50 57.7 115 60-140 1,2,3-Trichloropfopane uglL 50 50.9 102 60-140 1,2,4-Trichlorobenzene uglL 50 59.2 118 60-140 1,2,4-Trimethylbenzene uglL 50 60.1 120 60-140 1,2-Dibromo-3-chloropropane uglL 50 57.5 115 60-140 1,2-Dibromoethane {EDB) ug1L 50 56.2 112 60-140 1,2-Dichlorobenzene uglL 50 56.1 112 60-140 1,2-Dichloroethane ug)L 50 49.3 99 60-140 1,2-❑ichlo(opropane ug)L 50 53.4 107 60-140 1,3.5-Trimeth yIbenzene uglL 50 58.0 116 60-140 1,3-Dichlorobenzene uglL 50 55.4 ill 60-140 1,3-Dichloropropane uglL 50 54.0 108 60-140 1,4-❑ichlorcbenzene uglL 50 53.2 106 60-140 Date: 07/09/2012 01.59 PM REPORT OF LABORATORY ANALYSIS Page 33 of 38 This repon shall not be reproduced. except in full. without the written consent of Pace Ana 10caI Services, Inc. R 11�2ce Analytical wwwpscafabs.cam Pace Analytical Services, Inc. 205 EasI Meadow Road - Suite A Eden, NC 27288 (336)623-6921 Pace Analytical Services, Inc. 2225 Rivemlde Dr. Asheville, NC 28804 (828)254.7176 QUALITY CONTROL DATA Pace Anatytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersvilie, NC 28078 (704)875-9092 Project: Gilbarco 97746 Pace Project No.: 92122245 LABORATORY CONTROL SAMPLE. 788632 Spike LCS LCS / Rec Parameter Units Cone. Result % Rec Limits Qualifiers 2,2-Dichioropropane ug1L 50 52.0 104 60.140 2-Chlorotoluene uglL 50 56.4 113 60.140 4-Chlorotoluene ug1L 50 57.9 116 60.140 Benzene ug1L 50 54.6 109 60.140 Bromobenzene uglL 50 53.9 105 60-140 Bromochloromethane uglL 50 53.7 107 60-140 Bromodichloromethane uglL 50 54.6 109 60-140 Bromoform uglL 50 49.8 100 60-140 Bromomethane uglL 50 67.8 136 60-140 Carbon tetrachloride uglL 50 56.5 113 50-140 Chlorobenzene uglL 50 53.2 106 60-140 Chioroethane uglL 50 57.2 114 60-140 Chloroform uglL 50 52.1 104 60-140 Chloromethane uglL 50 49.1 98 60-140 cis-1.2-DichIoroethene uglL 50 51.7 103 60-140 cis-1,3-DichIo rap ropene uglL 5D 58.1 116 60-140 Ribromochloromethane ugll- 50 57.8 116 60-140 Dibromomethane ug1L 50 55.3 ill 60-140 Dichlorodifivaromethane uglL 50 46.2 92 M140 Diisopropyl ether uglL 50 55.8 112 60-140 Ethylbenzene uglL 50 55.0 110 60-140 Hexachloro-1,3-butadiene ug/L 50 58.4 117 60-140 Isopropylbenzene (Cumene) u91L 50 52.9 106 60-140 m&p-Xylene uglL 100 113 113 60`140 Methyl-tert-butyl ether uglL 50 56.2 112 60-140 Methylene Chloride uglL 50 54-6 109 60-140 n-Butylbenzene uglL 50 61.0 122 W140 n-Propyibenzene uglL 50 54.7 109 60-140 Naphthalene uglL 50 59.0 118 60-140 o-xylene uglL 50 55.2 110 60-140 sec-Butylbenzene uglL 50 57.4 115 60-140 Styrene uglL 50 61.7 123 60-140 tert-Butylbenzene uglL 50 55.1 110 60-140 Tetrachloroethene uglL 50 53.1 106 60-140 Toluene uglL 50 53.5 107 60-140 Vans-1,2-Dichloroethene uglL 50 50.5 101 60-140 tra n s- 1, 3- Di ch lo roprope ne uglL 50 60.7 121 60-140 Trichloroethene uglL 50 53.6 107 60-140 Th ch to roSuo ro me tha n e uglL 50 49.6 99 60-140 Vinyl chloride ug& 50 46.2 92 60-140 1,2-Dichioroethane-d4 (S) °I 95 70-130 4-Bromofluorobenzene (S) % 101 70.130 Dibromofiuoromethane (S) % 97 70-130 Toluene-d8 (S) I 101 70-130 Daw 07/09/2012 01 59 PM REPORT OF LABORATORY ANALYSIS Page 34 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. 11!;a1ceAnalyfical" www.paaaiabs (%hM Pace Analytical Services, Inc, 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Of. Asheville, NC 28604 (828)254-7176 QUALfTY CONTROL DATA Pace Analytical Services, Inc. 9800 Kincey Ave. Su 100 Huntersville, NC 28078 (704)875.9092 Project: Gilbarco 97746 Pace Project No.: 92122245 MATRIX SPIKE $ MATRIX SPIKE DUPLICATE: 788633 788634 MS MS❑ 92122246009 Spike Spike MS MS❑ MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Resull I Rec I Rec Limits RP❑ RPD Qual 1,1,1.2-TetrachIoroethane ug/L 20 20 219 17.6 109 89 60.140 20 30 1,1,1-Trichloroethane ug/L 20 20 19.4 16.1 97 81 60-140 18 30 1,1,2,2-TetrachIoroethane ug/L 20 20 21.4 17.3 107 86 60.140 21 30 1,1,2-Trichloroethane ug/L 20 20 23.0 19.3 115 97 60-140 18 30 1,1-Dichlaroethane ug/L 20 20 18.3 15.7 91 79 M140 15 30 1,1-Dichloroethene ug/L 20 20 19.7 17.0 99 85 60-140 15 30 1,1-Dichloropropene ug/L 20 20 20.6 17.6 103 88 60-140 15 30 12,3-Trichlorobenzene ug/L 20 20 21.3 17.6 107 88 60-140 19 30 1,2,3 Tr chlaropropane ug/L 20 20 21.6 17.8 108 89 60-140 20 30 1,2,4-Trichlorobenzene uglL 20 20 20.8 17.6 104 88 60-140 17 30 11,2,4-Trimethylbenzene uglL 20 20 24.2 20.5 117 99 60-140 16 30 12-Dibromo-3-chloropropane uglL 20 20 22.3 18.1 112 90 60-140 21 30 1,2-Dibromaethane (EDB) uglL 20 20 22.1 18.4 110 92 60-140 18 30 1,2-Dichlorobenzene ug/L 20 20 21.3 17,9 106 90 60-140 17 30 1,2-Dichloroethane uglL 20 20 19.6 16-7 98 84 60-140 16 30 1,2-Dichloropropane ug/L 20 20 21.3 17.9 107 90 60-140 17 30 1,3,5-Trimethylbenzene uglL 20 20 22.9 19A 106 89 60-140 17 30 1,3-DiChlorobenzene uglL 20 20 21.3 18.1 106 90 60-140 16 30 1,3-Dichloropropane uglL 20 20 21.7 18.1 108 91 60-140 18 30 1,4-Dichlorobenzene uglL 20 20 20.9 17.9 104 90 60-140 15 30 2,2-Dichloropropane uglL 20 20 18.1 15.2 91 76 60-140 17 30 2-Chlorotoluene uglL 20 20 22.0 18.6 110 93 60-140 17 30 4-Chlorotoluene uglL 20 20 22.3 19.0 112 95 60-140 16 30 Benzene uglL 20 20 22.4 19.0 107 91 60-140 16 30 Sromobenzene uglL 20 20 20.6 17.7 103 86 60-140 15 30 Bromochlorurnethane ug/L 20 20 21.0 17.8 105 89 60-140 17 30 Bromodichloromethane uglL 20 20 20.7 17.6 103 88 60-140 16 30 Bromoform ug/L 20 20 17.7 14.7 89 73 60-140 19 30 Bromomethane uglL 20 20 10.3 11.3 52 57 60-140 9 30 M0 Carbon tetrachloride uglL 20 .20 21.8 18.6 109 93 60-140 16 30 Chlorobenzene uglL 20 20 21.6 18.4 108 92 60-140 16 30 Chloroethane uglL 20 20 17.6 15.5 88 78 60-140 12 30 Chloroform uglL 20 20 20.2 17.1 101 85 60-140 17 30 Chioromethane uglL 20 20 17.8 15.5 89 77 60.140 14 30 cis-1,2-Dichloroethene ug/L 20 20 20.2 17.4 101 87 60.140 15 30 cis-1,3-Dichloropropene uglL 20 20 20.3 17.2 101 86 60-140 17 30 ❑ibmmochloromethane uglL 20 20 20.9 17.4 105 87 60-140 18 30 Dibromomethane uglL 20 20 21.4 18.2 107 91 60.140 16 30 Dichlorodifiuoromethane uglL 20 20 15.0 13.0 75 65 60.140 15 30 ❑iisopropyl ether ug[L 20 20 21.7 18.5 105 89 60-140 16 30 Ethylbenzene ug)L 20 20 22.6 19.5 108 93 60-140 15 30 HexachIoro-1,3-bu(ad iene uglL 20 20 20A 17.7 102 88 60-140 14 30 Isopropylbenzene (Cumene) uglL 20 20 21,3 17.9 105 88 60.140 17 30 m&p-Xylene uglL 40 40 52.0 46.1 111 97 60-140 12 30 Methyl-tert-butyl ether uglL 20 20 294 322 625 764 60.140 9 30 ER6 Methylene Chloride uglL 20 20 20.5 17.0 103 85 60.140 19 30 n-Sulylbenzene uglL 20 20 22.7 19.5 114 97 60-140 15 30 Date: 07/09/2012 01.59 PM REPORT OF LABORATORY ANALYSIS Page 35 of 38 This report Shall not he reproduced, except in Full, without the written consent of Pace Analytical Services. Inc 5ceAnalyfical6 ' wMwpacalebs.cam Pace Anatyticat Services, inc. 205 East N%adow Road - Suite Eden. NC 27288 (338)623.8921 Pace Analytkai Services, Inc. 2225 Riverside dr. Asheville. NC 28804 (828)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9600 Kmcey Ave. Suite 1 D0 Huntersviile, NC 28078 (7D4)875-9092 Project Gilbarco 97746 Pace Project No.: 92122245 MATRIX SPIRE $ MATRIX SPIKE DUPLICATE. 788633 788634 MS MSD 92122246009 Spike Spike MS MSD MS MSD I Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPID RPD Qual n-Propylbenzene uglL 20 20 21.4 18.6 1D6 92 60-140 14 30 Naphthalene uglL 20 20 21.9 17.9 110 90 60-140 20 30 o-Xylene ugll- 20 20 22.3 19.0 106 90 60-140 16 30 sec-Butylbenzene uglL 20 20 22.6 19.3 113 96 60-140 16 30 Styrene uglL 20 20 23.7 19.5 118 98 60-140 19 30 tert-Butytbenzene ug/L 20 20 21.9 18.8 110 94 60-140 15 30 Tetrachlaroethene uglL 20 20 21.5 18.1 107 90 60-140 17 30 Toluene ug1L 20 20 21.0 17.7 104 87 60-140 17 30 Ira ns-1,2-Dichioroethene uglL 20 20 20.3 17.0 102 85 60.140 18 30 trans•1.3-Dichlord propene uglL 20 20 22.0 18.2 110 91 60-140 19 30 Trichloroethene uglL 20 20 21.6 18.5 108 92 M140 16 30 Trichlorofluoromethane uglL 20 20 17.8 15.5 89 77 60-140 14 30 Vinyl chloride uglL 20 20 16.9 14.9 85 74 M140 13 30 1,2-Dichlaroethane-d4 (S) I 94 95 70-130 4-Bromofluorobenzene (S) % 101 99 70-130 Dibromofluoromethane (5) % 98 97 70-130 Toluene-d8 (S) % 99 99 70-130 Date: 07109f2012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 36 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. aceAnalytical" www.pac@,Wbs.cnm Project: Gilbarco 97746 Pace Project No.: 92122245 DEFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-892 t QUALIFIERS Pace Analytical Services, Inc, 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 Pace Analytica! ServIcas, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported. represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusled method detection limit and below the adjusted reporting limit. MD - Adjusted Method Detection Limit. PRL - Pace Reporting Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to caIculale % recovery and RP❑ values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) ❑UP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270 The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes TNI - The NELAC Institute. LABORATORIES PAST-C Pace Analytical Services • Charlotte ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. Mp Matrix spike recovery andlor matrix spike duplicate recovery was outside laboratory control limits. Pg Matrix spike recovery was outside laboratory control limits due to a parent sample concentration notably higher than the spike level, R1 RPD value was outside control limits. Date: 07/09/2012 01:59 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 37 of 38 aceAnalyticale www-pac&ahs cum Project Gllhafc0 97746 Pace Project No.. 92122245 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Or Asheville, NC 28804 (828)254.7176 DUALITY CONTROL DATA CROSS REFERENCE TABLE Lob ID Sample ID GC Batch Method GC Batch 92122245001 MW-7 SM 62006 MSW19579 92122245002 MW-14D SM 6200B MSW19579 92122245003 MW-16 SM 6200B MSV119579 92122245004 MW-24 SM 62006 MSVI19579 92122245005 MW-43t] SM 6200B MSV119579 92122245006 MW-45 SM 6200B MSV119610 92122245007 MW-46 SM 6200B MSV119610 92122245008 MW-47 SM 6200B MSV119610 92122245009 MW-49 SM 6200B MSV119610 92122245010 MW-53D SM 6200B MSV119610 92122245011 Trip Blank SM 62008 MSVI19610 Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Hunlersville, NC 28078 (704)875.9092 Analytical Analytical Method Batch Date: 07/0912012 01:59 PM REPORT OF LABORATORY ANALYSIS Page 38 of 38 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc.. ' ZeAnalytjcal' www.919911M.Cam CHAIN -OF -CUSTODY J Analytical Request Document The CheIn-0f-Custody IS a LEGAL DOCUMENT. AJi relevant Fields must be Completed accwmtoly. Section A Section 8 Section C Pauc of Required Client Jnformaton: RequIrud Project informatioInvoice Infwmatien: 1: �P�y e w- Repor, To. j. S IT,aj Atlention: + ■ {n 7 }�-+, yl.+� 1 5 9 L 5 6 V Address- �j ;y r capr To M { Cam pany nJame:{I� r{`1'e REGULATORY AGENCY C�r.� •a a,1.lc� �7 D Add F_ress: NPDES I_ GROUND WATER DRINKING WATER F_ LST f— RCRA F_ OTHER Email To: '' 11 r 'e f Purchase Order No.: [� u 7� Pace Quote (.1 Pf4 i 7 Ralerenae: P one' Fax: Project Name' . f 6 Pace Pro Jed : Site Location STATE. Requested td Due ReTAT: J; Protect Number. .J "i F- A OmM Pace Requested Analysis Filtered {YIN] Section D Matrfx Codes x Re qukad Uord hft -9on FRATRIx 1 COOE $ COLLECTED FresBNai1VH5 Y Dnridng water ow o water wr Waste Water WW COMPOSITE START4 _PUR� W PrUC SoI�USvYd 81 ai DL Y SAMPLE ID --- Wipe wp {A-Z, D-e f; y A AR o a w z ~ SarnOe IDe MIDST BE UNIQUE Tasue rs ❑ 0 a w v Other DT w w U ry T ? r x N 0 a a d z = 0 L= C TIME ❑s.TE TIME zF z z ,aa it Pace Project NaJ Lab LID,DATE 1 Z�11 2,191,2 3 � t 4 .7 — , Lq 5 1 kv — Odd e 13 7 fj 14 77 1130 9 _— R 6 aid tv Y6%LA/ -53 V v volo!a 11 t� JIME ADDITIONAL COMMENTS RELINQUISHED BY f AFFILIATION DATE ACCEPTED BY 1 AFFILIATION DATE TfMLE SAMPLE CON DMONS SAAIPLER NAME AND SIGNATURE v o svgvq y ORIGINAL $ $ V PRINT Na na of SAMPLER; N SIGNATURE of SAMPLER: DATE Slpn-d �'� CY N •Ircpurunt Now 6y -plop ods roan you av accapeng P-fe'e NET 30 d-y payment forms 00 aor"N to Isla marg-s of 1.51A par momh any -ow not Para wmn $0 cart. F-ALL-Q-020rev.07, 15-May-2DO7 Document Name: Document Revised: May 7, 2012 An31- Sample Condition Upon Receipt (SCUR) Page i of 2 Document Number: issuing Authority: F-CHR-CS-03-rev.07 Pace Huntersville Quality Office Client Name: �' Project # 4a Where Received: _;q-+fofitersviIIe ❑ Asheville ❑ Eden Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial❑ Pa Other_ Custody Seal on CoolerlBox Present: ❑ yes j Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble Wrap ❑ 13le gs ❑ None ❑ Other Thermometer Used: IR Gun 61T1102 Type of Iceo?t Blue None 1--71--samples on ice, cooling process has begun Temo Correction Factor T1101: No Correction Ti 102: No Correction Corrected Cooler Temp.: �� C Biological Tissue is Frozen: vas No NIA Date and In Isis of rsoq examinin contents: Temp should be above ►reeving to 61C Comments: Chain of Custody Present: Yes ON,, ❑wA 1. Chain of Custodx Filled Out: -'57es ❑No ❑NIA 2. Chain of Custody Relinquished: _.8Y9_❑No ❑wA 3. Sampler Name & Signature on CDC: was ❑No ❑wA 4. Samples Arrived within Hold Time: es ❑No ❑VA 5. Short Hold Time Analysis <72hr : ❑Yes ❑wA 6, Rush Turn Around Time Requested: ❑vies pwA 7. Sufficient Volume: rFTF9_s ONO ❑NIA g. Correct Containers Used: t17Ve_B ❑No ❑N!A g_ -Pace Containers Used: es ❑No ❑NIA Containers Intact: Nn ❑NIA 1p, Filtered volume received for Dissolved tests ❑Yes ❑Nv 0rA 11. Sample Labels match COC: 21 as ❑No ❑NIA 12, -Includes dateltime/ID/Analysis Matrix: All containers needing preservatlon have been checked. ©Yas ❑Na N!A 1$, All containers needing preservation are found to be in compliance with EPA recommendation. ❑Yes ❑No ❑ exceptions: VOA, cdffarrn, TOC, 0&G, WI-DRO (water) ❑Yes ❑No Initial when completed Sa mp las checked for dechlorinat! on: []Yes ❑No EKIA 14, Headspace in VOA Vials >6mm : Dyes ❑NIA 15. Trip Blank Present: ---t es .ONo ❑NIA 16. f Trip Blank Custody Seals Present .Yes ❑Nu ❑NIA Pace Trip Blank Lot # ifpurchased): Client Nottficationl Resolution: Field Data Requlred7 Y f N Person Contacted: DatefTime: Comments/ Resolution: SCURF SRF Review:1 IDate: Note: Whenever there is a discrepancy k fecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, inoorrect preservative, out of temp, incorrect containers) ace Analytical www.wcelabs.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)623-8921 May 09, 2012 Mr. Chris Hay Kleinfelder, Inc. 313 Gallimore Dairy Rd Greensboro, NC 27409 RE: Project: Gilbarco 97746 Pace Project No., 92117673 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 Pace Analytical Services, Inc. 9800 Kincey Ave. SuKe 100 Huntersville. NC 28078 (704)875.9092 Dear Mr. Hay: Enclosed are the analytical results for sample(s) received by the laboratory on May 02, 2012. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Analyses were performed at the Pace Analytical Services location indicated on the sample anaiyte page for analysis unless otherwise footnoted. If you have any questions concerning this report, please feel free to contact me. Sincerely, Charles Hardin tripp.hardin a@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in tun, without the written consent of Pace Analytical Services, inc.. Page 1 of 23 A aceAnalytical www.pacefabs.cnm Project: Gilbarco 97746 Pace Project No.: 92117673 Pace Analyt"I Services, Inc. 205 East Meadow Road - Suite A Eden, NC 272U Charlotte Certification IDS 9800 Kincey Ave. Ste 100, Huntersvitle. NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 South Carolina Drinking Water Cart. #: 99OD6003 Virginia Drinking Water Certification #: 00213 Asheville Certification 10s 2225 Riverside Dr., Asheville, NC 28804 FloridalNELAP Certification # E87648 Massachusetts Certification #. M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 (33E)623-8921 Pace Analytical Services, Inc. 2225 Riverside Or. Asheville. NC 28804 CERTIFICATIONS [828]254.7176 Connecticut Certification # PH-0104 FloridalNELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DHH Drinking Water # LA 1000031 West Virginia Certification #: 357 ViirginiaNELAP Certification #: 46 014 4 South Carolina Certification #: 99030001 Virginia Certification #. 00072 West Virginia Certification #: 356 Virglna[VELAP Certification #: 460147 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in Full. without the written consent of Pace Analytical Services. Inc.. Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvilie, NC 28078 (704)875.9092 Page 2 of 23 t: ace►4ria,(Xical * w.pacwabs.cam Pace Analytical Services, Inc. 205 E a s I Meadow Road - Suite A Eden. NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside ❑r. Asheville, NC 28804 (828)254-7176 SAMPLE SUMMARY Project. Pace Project No Lab ID Gilbamo 97746 92117673 Sample 10 Matrix Date Collected Date Received 92117673001 SW-01 Water 051021121113 05102M216:05 92117673002 SW-02 Water W0211210:38 05/02/1216:05 92117673003 SW-03 Water 05/02/12 09:08 05/02 12 1605 92117673004 SW-04 Water 05/02/12 09.22 05/02/12 16,05 92117673005 MW-46 Water 05102J12 09 55 05102J12 16 05 92117673006 MW-47 Water 05102J1210.10 05102/1216:05 92117673007 MW-49 Water 05/02/121025 0510211216:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc . Pace Analytical Servkft, Inc. 9800 Kincey Ave. Suite 100 Huntarswlle. NC 28078 (704)875.9092 Page 3 of 23 ace AnalyticalK www.pacoObs.COm Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analyt"I Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 SAMPLE ANALYTE COUNT Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Nuntersville. NC 28078 (704)675.9092 Project Gilbarco 97746 Pace Project No. 92117673 Ana lyres Lab ID Sample ID Method Analysts Reported Laboratory 92117673001 SW-01 SM 6200B TLS 64 PASI-C 92117673002 SW-02 SM 6200B TLS 64 PASI-C 92117673003 SW03 SM 62006 TLS 64 PASI-C 92117673004 SW-04 SM 6200B TLS 64 PASI-C 92117673005 MW-46 SM 5210B DMN 1 PASI-A 92117673006 MW-47 SM 5210B ❑MN 1 PASI-A 92117673007 MW-49 SM 5210B ❑MN 1 PASI-A REPORT OF LABORATORY ANALYSIS Page 4 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc.. ace Analyfrcal www.pacet9bs.aam Project Gilbarco 97746 Pace Project No.. 92117673 Pace Anal0"1 ServlCos, Inc. 205 East Meadow Road • Suite A Eden. NC 272M (336)623.8921 Pace Analytical ServiC66. Inc. 2225 Riverside ❑r. Asheville. NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Hunterswlle. NC 28078 (704)875-9092 Sample: SW-01 Lab ID: 92117673001 Collected. 05102/12 11:13 Received: 05/02/12 1605 Matrix Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Qual 6200B MISV Benzene Bromoberizene Bromochlommethane 6ro m od ich lorom eth a ne Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chlorometha ne 2-Chlorotoluene 4-Chlorotoiuene 1,2-Dibromo-3-chtoropropane D i bromo ch lorom ethane 1,2-Dibromoethane (EDS) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1 A-Dichlorobenzene Di ch Iorod ifl uoro me tha n e 1,1-Dichloroethane 1.2-Dichloroethane 1.1-Dichloroethene cis- 1.2 -Di ch loroethe n e tra ns-1.2- Di ch Io roeth a ne 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Diehloropropene cis-1,3-OichIaropropene trans-1.3-Dichloropropene Oiisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropyibenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylberizene Styrene 1.1.12-Tetrachloroethane 1.1.2.2 -Te trach loroe th ane Analytical Method: SM 62008 NO ug1L 0.50 0.50 1 05/08/12 23:21 71-43-2 NO uglL 0.50 0.50 1 05/08/12 23:21 108-86-1 NO uglL 0.50 0,50 1 05/08/12 23721 74-97-5 NO uglL 0.50 0.50 1 05/08/12 2321 75-27-4 NO uglL 0.50 0.50 1 05108/12 23 21 75-25-2 NO ug1L 5.0 1.0 1 05/08/12 23:21 74-83-9 NO ug1L 0.50 0.50 1 35/08/12 23:21 104-51-8 NO uglL 0.50 0,50 1 05/08/12 23:21 135-98-8 NO ug1L 0.50 0.50 1 D5108112 23:21 98-06-6 NO uglL 0.50 0.50 1 05/08/12 2321 56-23-5 N❑ uglL 0.50 0.50 1 05/08/12 23 21 108-90-7 NO ug1L 1.0 1.0 1 05108/12 2121 75-00.3 NO uglL 0.50 0.50 1 05/08/12 23:21 67-66-3 ND ugll 1 0 1.0 1 05/08112 23:21 74-87.3 NO uglL 0.50 0.50 1 05/08/12 2121 95-49-8 NO uglL 0.50 0.50 1 05/08112 2321 10643.4 N❑ ug1L 1.0 1.0 1 05/08/12 2121 96-12-8 N❑ uglL 0.50 0.50 1 05/08/12 2121 12448-1 NO uglL 0.50 0.50 1 05/08/12 23:21 106-93-4 N❑ uglL 0.50 0.50 1 05/08/12 23:21 74-95-3 NO uglL 0.50 0.50 1 05/08/12 23:21 95-50.1 NO ug1L 0.50 0.50 1 05/08/12 23:21 541.73-1 NO uglL 0.50 0.50 1 05/08/12 23:21 106-46-7 ND uglL 0.50 0.50 1 05/08/12 2121 75-71-8 ND uglL 0.50 0.50 1 W08112 23.21 75-34-3 NO uglL 0.50 0.50 1 05/08/12 23:21 107-06-2 ND uglL 0.50 0.50 1 05/08/12 23:21 75-35-4 NO uglL 0.50 0.50 1 05/08/12 23.21 156-59-2 N❑ uglL 0.50 0.50 1 05/08/12 23:21 156-60-5 NO uglL 0.50 0.50 1 0"8112 23:21 78-87-5 NO uglL 0.50 0.50 1 05/08/12 23.21 142-28-9 NO uglL 0.50 0.50 1 05/08/12 23.21 594-20-7 N❑ uglL 0.50 0.50 1 05/08/12 23:21 563-58-6 NO uglL 0.50 0.50 1 05/08/12 23:21 10061-01.5 NO ug1L 0.50 0.50 1 05/08/12 23.21 10061-02-6 NO uglL 0.50 0.50 1 05/08/12 23:21 108-20-3 NO ug1L 0.50 0.50 1 05/08/12 23:21 100-41-4 NO ug1L 2.0 2.0 1 05/08/12 2311 87-68-3 ND ugll 0.50 0.50 1 05/08/12 23.21 98-82-8 ND uglL 2.0 2.0 1 05/08/12 23:21 75-09-2 0.6E uglL 0.50 0.50 1 05/08/12 2121 1634-04-4 NO ug1L 2.0 2.0 1 05/08/12 2121 91-20-3 NO uglL 0.50 0.50 1 05/08/12 2321 103-O5.1 NO uglL 0.50 0.50 1 05/08/12 23:21 100-42-5 NO ug1L 0.50 0.50 1 05/08/12 23:21 630.20-6 NO uglL 0.50 0.50 1 05/08/12 23:21 79-34-5 Date: 05/09/2012 05:30 RM REPORT OF LABORATORY ANALYSIS Page 5 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services, Inc.. ace ArtaIXiolR. w+w.pac�abs.cam Project Gilbarco 97746 Pace Project No.: 92117673 Pace Analytical Services, Inc. 205 Easl Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services. Inc, 2225 Riverside Dr. Asheville, NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave Suite 100 Hunlemville, NC 28078 (704)875-9092 Sample: SW-01 Lab ID: 92117673001 Collecled: 05102112 11:13 Received: 05/02/12 16:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. ❑ual 6200E MSV Analytical Method: SM 62006 Tetrachloroethene NO uglL 0.50 0.50 1 D5108112 23:21 127-18.4 Toluene NO uglL 0.50 0.50 1 05/08/12 23:21 108-88.3 1,2,3•Trichlorobenzene ND uglL 2.0 2.0 1 05/08/12 23:21 87-61-6 1,2,4-Trichlorobenzene NO uglL 2.0 2.0 1 05/08/12 23.21 120-82-1 1,1,1-Trichloroethane ND uglL 0.50 0.50 1 0510811223:21 71-55-6 1,1,2-Trichloroethane NO uglL 0.50 0.50 1 0510811223:21 79-DO-5 Trichloroethene NO uglL 0.50 0.50 1 05/08/12 2321 79-01-6 Trichlorotiuoromethane NO uglL 1.0 1.0 1 05/08/12 23:21 75-69-4 1,2,3-Trichforopropane ND uglL 0.50 0.50 1 051081122321 96-18-4 1,2,4-Trimethylbenzene NO ug& 0.50 0.50 1 05/08/12 2321 95-63-6 1,3,5-Trimethylbenzene NO uglL 0.50 0.50 1 0510811223:21 10"7-8 Vinyl chloride ND ug/L 1.0 1.0 1 05/08/12 23:21 75.01-4 m&p-Xylene NO uglL 1.0 1.0 1 05108/12 23:21 179601-23-1 o-Xylene ND ug1L 0.50 0.50 1 05/08/12 23:21 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 05/08/12 2121 17060-07-0 ❑ibromoRuoromethane (S) 100 % 70-130 1 05/08/12 23:21 1868-53.7 4-Bromofluorobenzene (S) 94 % 70-130 1 05/08/12 23:21 460-00-4 Toluene-d8 (S) 99 I 70-130 1 05/08/12 23:21 2037-26-5 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYStS Page 6 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Ir)c. aceAnalytrcale www.paceism.com Pace Analytical Services, Inc. 205 East Meadow Road • Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Se rvl ce3, Inc. 2225 Riverside Dr. Ashaville. NC 20804 j828)254-7176 ANALYTICAL RESULTS Pate Analytical Services, Inc- 9 BDO Kincey Ave. Suite 100 Hunlersville, NC 28078 t704j875-9092 Protect: Gilbarco 97746 Pace Project No . 92117673 Sample: 5W-02 Lab 10: 921t7673002 Collected: 05/02/12 10:38 Received: 05/02/12 16:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Oual 6200E MSV Analytical Method: SM 62009 Benzene ND uglL 0.50 0.50 1 05/08112 23:39 71-43-2 Bromobenzene ND ug& 0 50 0.50 1 05/08112 23.39 108-86-1 Bromochloromethane ND uglL 0.50 0.50 1 05/08112 23:39 74.97-5 Bromodichloromethane ND uglL 0.50 0.50 1 05/08112 23:39 75-274 Bromoform ND uglL 0.50 0.50 1 05/08/12 23.39 75-25-2 Bromomethane ND uglL 5.0 1.0 1 05/08/12 23.39 74-83-9 n-Butylbenzene NO uglL 0.50 0.50 1 05/08/12 23.39 104-54-8 sec-Butylbenzene ND ug& 0.50 0.50 1 05/08/12 23:39 135-98-8 tert-Butylbenzene ND uglL 0.50 0.50 1 05/08/12 23:39 98-06-6 Carbon tetrachloride NO uglL 0.50 0.50 1 M08112 23.39 56-23-5 Chlorobenzene NO uglL 0.50 0.50 1 05108/12 23:39 108-90-7 Chtoroethane NO uglL 1.0 1.0 1 05/08/12 23.39 75-00-3 Chloroform ND uglL 0.50 0.50 1 05/08/12 23.39 67-66-3 Chloromethane NO ug1L 1.0 1.0 1 05/08/12 23:39 74-87-3 2-Chlorotoluene NO uglL 0.50 0.50 1 05M8112 23:39 95-49-8 4-Chlorotoluene NO uglL 0.50 0.50 1 05/08/12 23.39 106-43-4 1,2-0ibromo-3-chlorapropane NO uglL 1.0 1.0 1 0510811223:39 96-12-8 Dibromochloramethane ND uglL 0.50 0.50 1 05/08/12 23.39 124-48-1 1.2-aibromoethanetEDB) NO uglL 0.50 0.50 1 05M811223:39 106-93-4 Dibromomethane NO ug1L 0.50 0.50 1 W08112 23:39 74-95-3 1,2-Dichlorobenzene NO ug1L 0.50 0.50 1 05/08/12 23:39 95-50-1 1,3-Dichlorobenzene ND uglL 0.50 0.50 1 05/08/12 23:39 541-73-1 IA-Dichlorobenzene NO uglL 0.50 0.50 1 05/08/12 23:39 106-46-7 Dichlorodifiuoromethane N❑ uglL 0.50 0.50 1 05/08/12 23:39 75-71-8 1,1-Dichloroethane NO uglL 0.50 0.50 1 05108/1223:39 75-34-3 12-Dichloroethene NO uglL 0.50 0.50 1 05108/1223:39 107-06-2 1,1-Dichloroethene NO uglL 0.50 0.50 1 05108/1223:39 75-35-4 cis -1,2-Dichloroethene ND uglt 0.50 0.50 1 05/08/12 23:39 156-59-2 trans-1,2-Dichloroe the ne N0 uglL 0.50 0.50 1 05/08/12 23:39 156-60.5 1,2-Dichloropropane N0 uglL 0.50 0.50 1 05/08/12 23:39 78-87-5 1,3-Dichloropropane ND uglL 0.50 0.50 1 05108M2 23:39 142-28-9 2,2-Dichloropropane ND uglL 0.50 0.50 1 05/08/12 23:39 594-20-7 1,1-Dichloropropene NO uglL 0.50 0.50 1 05/08/12 23:39 563-58-6 cis -1,3-Dichloropropene ND ug1L 0.50 0.50 1 05/08/12 23:39 10061-01-5 trans-1,3-DichIoropropene ND ug1L 0.50 0.50 1 05108/1223-39 1W61-02-6 Diisopropyl ether NO uglL 0.50 0.50 1 05/08/12 23.39 108-20-3 Ethylbenzene ND ug1L 0.50 0.50 1 0 51D81 12 23:39 100-41-4 H e xachloro- 1. 3- butad One N❑ uglL 2.0 2.0 1 05/08/12 23:39 87-68-3 Isopropylbenzene (Cumene) ND uglL 0.50 0.50 1 05/08112 23:39 W82-8 Methylene Chloride ND ug1L 2.0 2.0 1 05/08/12 23:39 75-09-2 Methyl-tert-butyl ether 1.1 uglL 0.50 0.50 1 05/08/12 23 39 1634-04-4 Naphthalene ND ug1L 2.0 2.0 1 05/08/12 23:39 91.20-3 n-Propylbenzene ND ug1L 0.50 0.5D 1 05/08/12 23.39 103-65-1 Styrene ND uglL 0.50 0.50 1 05/08/12 23.39 100-42-5 1.1,1,2-Tetrachloroethane NO uglL 0.50 0.50 1 0510811223:39 630-20-6 1.1,2,2•Tetrachloroethane N❑ uglL 0.50 0.50 1 05/08112 23:39 79-34-5 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 7 of 23 This report shall not be reproduced. except in full, without the written Consent of Pace Analytical Services, Inc.. a Pace Analytical Services, Inc. Pace AnalyWat Services, Inc. Pace Analytical Services, Inc. 2aceAmlytiml 205 E a s I Meadow Road - SuiteA 2225 Riverside Dr. 9800 KIncey Ave. Suite 100 w bs corn Eden, NC 27288 Asheville, NC 28804 kuntersvilie. NC 28078 (336)623-8921 (828)254-7176 (704)875.9092 ANALYTICAL RESULTS Project. Gilbarco 97746 Pace Project No.. 92117673 Sample: SW-02 Lab (D: 92117673002 Collected 05/02/12 10:38 Received- 05/02/12 16:05 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Tetrachloroethene ND ugk 0.50 0.50 1 05/08/12 23:39 127-18-4 Toluene ND uglL 0-50 0.50 1 05/08/12 23:39 106-88-3 1,2,3-Trichlorobenzene ND uglL 2.0 2.0 1 05/08/1223:39 87-61-6 1,2,4-Trichiorobenzene ND ugIL 2.0 2.0 1 05108/1223.39 120-82-1 1,1,1-Trichloroethane ND uglL 0.50 0.50 1 05/08/1223:39 71-55-6 1,1,2-Trichloroethane N❑ uglL 0-50 0.50 1 05/08112 23:39 79-00.5 Trichloroethene 0.58 uglL 0-50 0.50 1 0510811223:39 79-01-6 Trichloroftuorornethane ND uQ1L 1-0 1.0 1 05/08/12 23:39 75-69-4 1,2,3-TricHaropropane ND ug1L 0.50 0.50 1 05)08/12 23:39 96-18-4 1,2,4-Trimethylbenzene N❑ uglL 0,50 0.50 1 05108/1223-39 95-63-6 1,3,5-Trimethylbenzene N❑ ug/L 0.50 0.50 1 05/08/12 23:39 108-67-8 Vinyl chloride ND ug/L 1-0 1.0 1 05/08/12 23,39 75-01-4 m8p-Xylene ND uglL 1-0 1.0 1 05/08/12 23:39 179601-23-1 n-Xylerie ND ug/L 0,50 0-50 1 05/08/12 23:39 95-47-6 Surrogates 1,2-❑ichloroethane-d4 (S) 104 % 70-130 1 05/08/12 23:39 17060-07-0 Dibromofluoromethane (S) 101 % 70-130 1 05/08/12 23:39 1868-53-7 4-8rom0fluorobenzene (S) 95 I 70-130 1 05/08/12 23:39 460-00-4 Toluene-d8 (S) 101 % 70-130 1 05/08/12 23:39 2037-26-5 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 8 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc„ ace Analpical www. pucNads. cam Project: Gilbatco 97746 Pace Project No 92117673 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336y623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 (928)254.7176 ANALYTICAL RESULTS PaceAnalyt"I Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704 yB 75-9092 Sample: SW-03 Lab ID: 92117673003 Collected 05102M2 09:08 Received: 05/02/12 16:05 Matrix: Water Report Parameters Results Units Limit MDL DP Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 Benzene NO uglL 0.50 0.50 1 05108/12 23:57 71-43-2 Bromobenzene NO uglL 0.50 0.50 1 05108/12 23:57 108-86-1 Bromochioromethane ND u91L 0.50 0.50 1 05108/12 23:57 74-97-5 Bramodichioromethane NO uglL 0.50 0.50 1 05/08/12 23:57 75-27-4 Bromoform ND uglL 0.50 0.50 1 05/08/12 23:57 75-25-2 Bromomethane NO uglL 5.0 1.0 1 05/08/12 23:57 74-83-9 n-Butylbenzene N❑ uglL 0.50 0.50 1 05/08/12 23:57 104-51-8 sec-Butylbenzene NO ug1L 0.50 0.50 1 05/08/12 23:57 135-WB tert-Butylbenzene ND uglL 0.50 0,50 1 05/08/12 23:57 98-06-6 Carbon tetrachloride NO uglL 0.50 0,50 1 05/08/12 23:57 56-23-5 Chlorobenzene NO uglL 0.50 0.50 1 05/08/12 23:57 108-90-7 Chloroethane ND uglL 1 0 1.0 1 05/08/12 23:57 75-00-3 Chloroform NO ugll- 0.50 0.50 1 05/08/12 23,57 67-66-3 Chloromethane NO uglL 1.0 1.0 1 05M8112 23:57 74-87-3 2-Chlorotoluene NO ugll 0.50 0.50 1 05/08/12 23:57 95-49-8 4-Chlorotoluene NO uglL 0.50 0.50 1 05/08112 23-57 106-43-4 12-Dibromo-3-chloropropane NO ugJL 1.0 1.0 1 05J08112 23:57 96-12.8 Dibromochloromethane NO uglL 0.50 0.50 1 05/08/12 23:57 124-48-1 1,2-Dibromoethane (EDB) NO uglL 0.50 0.50 1 05/08/12 23757 106-93-4 Dibromomethane ND uglL 0.50 0.50 1 05/08/12 2 3:5 7 74-95-3 1,2-Dichlarobenzene NO ug1L 0,50 0.50 1 05108/1223:57 95-50-1 1,3-Dichlorobenzene ND uglL 0.50 0.50 1 051OW1223:57 541-73.1 1,4-Dichlarobenzene NO uglL 0.50 0.50 1 05108/1223.57 106-46-7 Dichlorodifluoromethane ND uglL 0.50 0.50 1 05/08/12 23:57 75-71-8 1,1-0ichloroethane N❑ uglL 0,50 0.50 1 0510811223:57 75.34-3 1.2-Dichloroethane ND uglL 0.5❑ 0.50 1 05/09/12 23.57 107-06-2 1.1-DichIoroethene ND ugll- 0.50 0.50 1 05/08/12 23:57 75-35-4 cis-1,2-Dichioroethene ND ugll 0.50 0.50 1 05108/12 23:57 156-59-2 trans-1,2-DichIoroethene ND uglL 0.50 0.50 1 05/08/12 23.57 156-M5 1.2-❑ichloropropane ND uglL 0.50 0.50 1 05/08/12 23.57 78-87-5 1,3-Dichloropropane ND ug/L 0,50 0.50 1 05/08/12 23:57 142-28-9 2,2-Dichloropropane ND uglL 0.50 0.50 1 05/08/12 23:57 594-20-7 1,1-Dichloropropene N❑ uglL 0.50 0.50 1 05/0811223.57 563-58-6 cis-1,3-Dichloropropene ND ugll- 0.50 0.50 1 05/0811223:57 10061-01-5 Vans-1,3-Dichloropropene ND uglL 0.50 0.50 1 05/08/12 23:57 10061-02-6 ❑iisopropyl ether NO uglL 0.50 0.50 1 05/08112 23:57 108-20-3 Ethylbenzene NO uglL 0.50 0.50 1 05/08/12 23:57 100-41-4 Hexachloro-1,3-butadiene ND uglL 2.0 2.0 1 0510811223-57 87-615-3 Isopropylbenzene (Cumene) NO uglL 0,50 0.50 1 05/08/12 23:57 98-82.8 Methylene Chloride NO ug& 2.0 2.0 1 W08112 23:57 75-09-2 Methyl-tert-butyl ether NO uglL 0.50 0.50 1 05J08112 23:57 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 05/08/12 23:57 91-20-3 n-Propylbenzene NO uglL 0.50 0.50 1 05108/12 23:57 103-65-1 Styrene NO uglL 0.50 0.50 1 05/06/12 23.57 100-42-5 1,1,1,2-Tetrachloroethane NO uglL 0.50 0.50 1 05/08/12 23:57 630.20-6 1,1.2,2-Tetrachloroethane ND uglL 0.50 0.50 1 051D8112 23:57 79-34-5 Date- 05109/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 9 of 23 ThIs report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. j� ` sn Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analyt"I Services, Inc. ace I'1f ►R�7 Iyt 'i�G[' I 205 East Meadow Road - Suite A 2225 Riverside Or. 98DO Kinsey Ave. Suite 100 4pbs Eden, NC 27288 Asheville. NC 28804 Huntersviile, NC 28078 (338)623.8921 (828)254.7176 (704)875-9092 ANALYTICAL RESULTS Project: Gilbarco 97746 Pace Project. No.: 92117673 Sample: SW-03 Lab 10: 92117673003 Collected: 051D2112 09:08 Received 05102/12 16-05 Matrix- Water Report Parameters Results Units Limit MIL OF Prepared Analyzed CAS No. Qua] 62008 MSV Analytical Method: SM 6200B Tetrachloroethene NO ug1L 0.50 0.50 1 05/08/12 23:57 127-18-4 Toluene NO uglL 0.50 0.50 1 05/08/12 23:57 108-88-3 12,3-Trichlorobenzene NO ug1L 2.0 2.0 1 0510811223:57 87-61-6 1.2A-Trichlorohenzene NO uglL 2.0 2.0 1 05/08/12 23:57 120-82-1 1,1,1-Trichioroethane N0 uglL 0.50 0.50 1 05/0811223.57 71-55-6 1,1,2-Trichtoroe thane N❑ uglL 0.50 0.50 1 05/0811223.57 79-00-5 Trichloroethene 1.6 uglL 0.50 0.50 1 05/08/12 23:57 79.01-16' Triehlorofluoromethane NO uglL 1.0 1.0 1 05/08/12 23.57 75-69-4 1,2,3-Tdchloropropane NR ug/L 0,50 0.50 1 0510811223:57 96-18-4 1,2,4-Trimethylbenzene N❑ uglL 0.50 0.50 1 05/08112 23:57 95-63-6 1,3,5-Trimethylbenzene NQ uglL 0.50 0.50 1 0510811223:57 10M7-8 Vinyl chloride NO uglL 1.0 1.0 1 M08112 23:57 75-01-4 m&p-Xylene ND uglL 1.0 1.0 1 05108/12 23:57 179601-23-1 o-Xylene ND uglL 0.50 0.50 1 05108/12 23-57 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 1 D4 % 70.130 1 05108/12 23:57 17060-07.0 ❑ibromofluoromethane (S) 101 % 70-130 1 05/08/12 23:57 1868-53-7 4-Bromofluorobenzene (S) 94 % 70-130 1 05/08/12 23-57 460-00.4 Toluene-& (S) 99 % 70-130 1 05/08/12 23:57 2037-26-5 Date 05/09/2012 05.30 PM REPORT OF LABORATORY ANALYSIS Page 10 of 23 This report shall riot be reproduced, except in Full, without the written consent of Pace Analytical Services, Inc. �. Pace AnaryMal Services, Inc. Pace Analytical Services, Inc, Pace Analytical Services, Inc. ce►4nalyfieal 205 East Meadow Road • Suite A 2225 Riverside Dr. 9800 KinGey Ave. SuKe 100 www.patelsbs com Eden. NC 27288 Asnevllle, NC 28604 Huntersville, NC 28078 (338)623-8921 (828)254-7176 (704]875-9092 ANALYTICAL RESULTS Project. Gilbarco 97746 Pace Project No.. 92117673 Sample: 5W-04 Lab ID: 92117673004 Collected: 05/02112 09 22 Received 0-5/02/12 16 05 Matrix Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Quai 6200B MSV Analytical Method: SM 62006 Benzene NO ug1L 0.50 0.50 1 05/09/12 00:15 71-43-2 Bromobenzene NO uglL 0.50 0.50 1 05/09112 00:15 108-86-1 Bromochloromethane NO uglL 0.50 0.50 1 05/09112 00:15 74-97-5 B romod ich lo rometha ne ND uglL 0.50 0.50 1 05/09/12 00:15 75-27-4 Bromoform ND uglL 0.50 0.50 1 05/09/12 00:15 75-25-2 Bromomethane ND ug1L 5.0 1.0 1 05/09/12 00:15 74-83-9 n-Butylbenzene ND uglL 0,50 0.50 1 0510911200:15 104-51-8 sec-Butylbenzene NO uglL 0,50 0.50 1 05/09/12 00:15 135-98-8 tert-Sutylbenzene NO ug1L 0.50 0.50 1 05/09/12 00:15 98-06-6 Carbon tetrachloride NO uglt- 0.50 0.50 1 05/09/12 00:15 56-23-5 Chlorobenzene NO ug1L 0.50 0.50 1 05/09/12 00715 108-90-7 Chloroethane NO ug1L 1.0 1.0 1 05/09/12 = 15 75-00-3 Chloroform NO ug1L 0.50 0.50 1 05/09/12 00 15 67-66-3 Chloromethane NO ug1L 1.0 1.0 1 05109/12 00: 15 74-87-3 2-Chlorotoluene NO uglL 0.50 0.50 1 05/09/12 00:15 95-49-8 4-Chlorotoluene NO u911- 0.50 0.50 1 05/09/12 00:15 106-43-4 1,2-0ibromo-3-chloropropane NO uglL 1.0 1.0 1 05109/1200:15 96-12-8 Dibromochloromethane NO uglL 0.50 0.50 1 05/09/12 00:15 124-48-1 12•0ibromoethane {EDB] N❑ uglL 0.50 0.50 1 05/09/12 00.15 106-93-4 Dibromomethane ND uglL 0.50 0.50 1 05/09/12 00:15 74-95-3 1.2-Dichlorobenzene NO uglL 0.50 0.50 1 06/09/12 00:15 95-50-1 1,3-Dichlorobenzene ND uglL 0.50 0.50 1 05109/1200:15 541-73-1 1,4-Dichlorobenzene ND ugll- 0.50 0.50 1 05/09/12 00.15 106-46-7 ❑ichlorodifluoromethane NO uglL 0.50 0.50 1 05/09/12 00 15 75-71-8 1,1-Dichloroethane NO uglL 0.50 0.50 1 05/09/12 Of 15 75.34-3 1,2-Dichioroethane ND uglL 0.50 0.50 1 05/09/12 00:15 107-06-2 1,1-DichIoroethe ne ND ug& 0.50 0.50 1 05109/12 00:15 75-35-4 cis-1.2-Dichloroet hene ND ugll- 0.50 0.50 1 05MD/l200:15 156-59-2 trans-1,2-Dichioroethene N❑ uglL 0.50 0.50 1 05109/12 00:15 15"0-5 1.2-Dichloropropane N❑ ug1L 050 0.50 1 05/09/12 00:15 78-87-5 1,3-Dichloropropane NO uglL 0.50 0.50 1 05/09/12 00:15 142.28-9 2,2-Dichloropropane NO ug1L 0.50 0.50 1 05/09/12 00:15 594.20-7 1,1-1)ichloropropene N❑ uglL 0.50 0.50 1 05109/12 00.15 563-58-6 cis- 1,3-Di chloropropene ND uglL 0.50 0.50 1 05/09/12 00:15 10061-01-5 trans-1,3-Dichloropropene ND uglL 0.50 0.50 1 05109112 0& 15 10061-02-6 Odsopropyl ether NO uglL 0.50 0.50 1 05/09/12 00.15 108.20-3 Ethylbenzene NO uglL 0.50 0.50 1 05109112 00:15 100-41-4 Hexachloro-1,3-butad iene ND uglL 2.0 2.0 1 05109/12 00:15 67-68-3 Isopropylbenzene (Cumene) ND uglL 0.50 0.50 1 05/09/12 00.15 98-82-6 Methylene Chloride ND uglL 2.0 2.0 1 05/09/12 00.15 75-09-2 MethyMert-butyl ether NO uglL 0.50 0.50 1 05109/12 00:15 1634-04-4 Naphthalene NO uglL 2.0 2.0 1 0&09112 00:15 91.2D-3 n-Propylbenzene NO uglL 0.50 0.50 1 05109/12 00:15 103-65-1 Styrene NO uglL 0.50 0.50 1 05109/12 00:15 100-42-5 1,1,1,2-Tetrachioroethane ND uglL 0.50 0.50 1 05109/1200:15 630.20-6 1.1.2,2-Tetrachloroethane ND uglL 0.50 0.50 1 05/09/12 00:15 79-34-5 bate: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 11 of 23 this report shall not be reproduced, excepl in full, wllhout the writlen con Sent of Pace Analytical Services, Ire-- ace AnalyticaI www. es.com Pace Analytical Services, Inc. 205 East Meadow Road - Suite Eden, NC 27288 (336)623-8921 Pace Analytical Services, Irrc. 2225 Riverside Dr. Asheville, NC 28804 (82B)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9600 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Gilbarco 97746 Pace Project No.: 92117673 Sample.- 5W-04 Lab ID-. 92117673004 Collected. 0510211209.22 Received: 0510211216.05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method- SM 620013 Tetrachloroethene ND uglL 0.50 0.50 1 05/09/12 00A5 127-18-4 Toluene N❑ uglL 0.50 0.50 1 05/09/12 00:15 108-88-3 1,2,3-Trichlorobenzene ND uglL 2.0 2.0 1 05/09/12 00:15 87-61-6 1,2,4-Thchlorobenzene ND uglL 2.0 2.0 1 0510911200:15 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 0.50 1 05109/120015 71-55-6 1.1,2-Trichloroethane ND ug1L 0.50 0.50 1 05/09/12 00 15 79-00-5 Trichloroethene 2.4 ug/L 0.50 0.50 1 051091120015 79-01-6 Trichlorotluoromethane N❑ ug& 1.0 1.0 1 05/09/12 00.15 75-69-4 1.2,3-Trichloropropane ND ugfL 0.50 0,50 1 05/09/12 00:15 96-18-4 1.2,4-Trimethy[benzene ND ug(L 0.50 0.50 1 05/09/12 00:15 95-63-6 1.3,5- Trim ethyThe nzene ND uglL 0.50 0.50 1 05/09/12 00 15 108-67-6 Vinyl chloride N❑ uglL 1.0 1.0 1 05/09/12 00:15 75-014 m&p-Xytene N❑ uglL 1.0 1.0 1 05/09/12 00:15 179601-23-1 o-Xylene ND ug)L 0.50 0,50 1 05/09/12 00:15 95-47-6 Surrogafes 1,2-Dichloroethane-d4 [S] 104 % 70-130 1 05/09/12 00:15 17060-07-0 ❑ibromofluoromethane (S) 102 % 70-130 1 05/09/12 00:15 1868-53-7 4-Bromofluorobenzene (S) 95 % 70-130 1 05/09/12 00:15 460-00-4 Toluene-d8 (S) 98 % 70-130 1 05/09/12 00'15 2037-26-5 Date. 05/09/2012 05.30 PM REPORT OF LABORATORY ANALYSIS Page 12 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. R ace► na1y6cal www.paGetbs.com Pace Analytical Services, Inc. 205 East Meaduw Road - Suite A Eden. NC 27288 [336]623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 1704)875.9092 Project: Gilbarco 97746 Pace Project No. 92117673 Sample: MW-46 Lab ID: 92117673005 Collected: 05102112 09 55 Received: 05102M2 16:05 Matrix- Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qua[ 52108 BOO, 5 day Analytical Mettrod: SM 5210B HOD, 5 day ND mWL 2.0 2.0 1 05/03112 19 53 0510802 17:28 B2 Date: 05/09/2012 05.30 PM REPORT OF LABORATORY ANALYSIS Page 13 of 23 This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc„ e ,1!aceArialytical www.vacowbs.com Pace Analytical Services, Inc. 205 East Meadow Road • Suite A Eden. NC 27288 [33W23-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 Kincey Ave. Sude 100 Huntersville. NC 28078 [704]875-9092 Project: Gitbarco 97746 Pace Project No.: 92117673 Sample: MW-47 Lab ID: 92117673006 Collected: 05/02/12 1010 Received- 05/02/12 16:05 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Qual 52108 BOD, 5 day Analytical Method. SM 5210B BOA, 5 day 97.9 mgll. 2.0 2.0 1 05/03/12 19:53 05/08/12 17 28 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 14 of 23 This report shall not be reproduced, except in full, without the written Consent of Pace Analytical Services, Inc-. F 25ceAnalyfica( www. PaCeimbs. cam Pace Analytical Services. Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)823-$921 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 (028)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9804 Kincey Ave. Suite 100 Hunfersville, NC 28078 (704)875.9092 Project Gilbarco 97746 Pace Project No 92117673 Sample: MW-49 Lab ID: 92117673007 Collected 05102112 10:25 Received: 05/02/12 16 O5 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Qual 5210E BOD, 5 day Analytical Method: 5M 52108 BOD, 5 day 24.3 mg11- 2 0 2.0 1 051OX12 19:53 05/08/12 17 28 82 Date: 051p912012 0 5.3 0 PM REPORT OF LABORATORY ANALYSIS Page 15 of 23 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, inc. aceAnalyticalr www.paceta7s.cam Project: Gilbarco 97746 Pace Project No.:/32117673 Pace Analytical Services, Inc. 205 E a st Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside ❑r. Asheville, NC 28604 (8,28)254-7176 DUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 KinceyAve. 5uite 1DO Huntersville, NC 28078 (704 )875-9092 ❑C Batch: MSV118975 Anaiysis Method: SM 62008 QC Batch Method: SM 620DB Analysis Description: 6200E MSV Associated Lab Samples: 92117673001, 92117673002, 92117673003, 92117673004 METHOD BLANK: 757875 Matrix. Water Associated Lab Samples: 92117673001, 92117673002, 92117673003, 92117673004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1, 1, 1,2 -TetracNa methane uglL ND 0.50 05/0811218:32 1,1,1-Trichloroethane uglL ND 0.50 0510811218:32 1,1,2,2-Tetrachic roethane uglL ND 0.50 0510811218:32 1,1,2-Trichlomethane uglL ND 0.50 0510811218:32 1,1-Dichloroethane uglL ND 0.50 0510811218:32 1,1-0ichloroethene uglL ND 0.50 0510811218:32 1,1-0ichIoroprope ne ug/L ND 0.50 0510811218:32 1,2,3-Trichlorobenzene uglL N❑ 2.0 0510811218:32 1,2,3-Trichloropropane uglL ND 0.50 05108/1218:32 1,2,4-Tdchtorobenzene uglL NO 2.0 0510811218:32 1,2,4-Trimethylbenzene uglL ND 0.50 0510811218:32 1,2-Dibromo-3-chloropropane uglL N❑ 1.0 0510811218,32 1,2-Dibromoethane (EDB) uglL N❑ 0.50 05/08/12 18:32 1.2-Dichlorobenzene uglL ND 0.50 05108/1218:32 1,2-Dichloroethane uglL ND 0.50 05/08/1218:32 1,2-Dichloropropane uglL ND 0.50 05108/1218:32 1.3,5-Trimethylbenzene uglL ND 0.50 05108/1218:32 1,3-Dichlorobenzene uglL ND 0.50 05/08/1218:32 1,3-Dichloropropane ug1L ND 0.50 0510811218:32 1,4-Dichlorobenzene ug1L N❑ 0.50 05/0811718:32 2,2-Dichloropropane uglL N❑ 0.50 0510811218:32 2-Chlorotoiuene uglL N❑ 0.50 0510811218:32 4-Chlorotoluene uglL ND 0,50 0510811218:32 Benzene uglL ND 0.50 0510811218:32 Bromobenzene uglL N❑ 0.50 0510811218:32 Bromochloromethane uglL N❑ 0.50 0510811218:32 Bromodi&loromethane uglL N❑ 0.50 0510811218:32 Brornoform uglL ND 0.50 05/0811218:32 Bromomethane uglL ND 5.0 0510811218:32 Carbon tetrachloride uglL N❑ 0.50 OW08112 18:32 Chlombenzene uglL N❑ 0.50 0510811218:32 Chlomethane uglL ND 1.0 051080218:32 Chloroform ug1L ND 0.50 05108/1218:32 Chloromethane uglL N❑ 1.0 0510811218:32 cis -1,2-Dichtoroethene uglL N❑ 0.50 0510811218.32 cis- 1.3-❑ich toropropene uglL ND 0.50 0510811218:32 Dibromochloromethane ug1L ND 0.50 0510811218:32 Dibromomethane ugll. ND 0.50 0510811218.32 Dichlorodifluoromethane uglL N❑ 0.50 0510811218:32 Diisopropyi ether ug1L N❑ 0.50 05/08/12 18:32 Ethylbenzene ug& N❑ 0.50 05108/1218:32 Hexachloro-1.3-bu[adiene uglL NO 2.0 0510811218:32 isopropylbenzene (Cumene) uglL NO 0.50 05/08/12 18:32 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 16 of 23 This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc aceAnalyticals www.pw-Pwabs-oom Project Gilbarco 97746 Pace Project No.: 92117613 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Ana tykicat Services, Inc. 2225 Riversde ❑r. Asheville, NC 20804 (828)254-7176 QUALITY CONTROL DATA METHOD BLANK: 757875 Associated Lab Samples- Parameter Matrix: Water 92117673001. 92117673002. 92117673003. 92117673004 Blank Reporting Units Result Limit Analyzed m&p-Xylene uglL ND 1.0 05/0811218:32 Methyl-tert-butyl ether uglL N❑ 050 0510802 1$ 32 Methylene Chloride ug)L NO 2.0 M08112 18:32 n-Butylbenzene ug1L ND 0.50 0510811218.32 n-Propyibenzene uglL NO O.50 0510811218:32 Naphthalene uglL ND 2.0 0510811218:32 o-Xylene uglL NO 0.50 05/0811218:32 sec-Butylbenzene uglL NO 0.50 W08/1218:32 Styrene ug)L NO 0.50 05/08/1218:32 tert-Butylbenzene ug)L N❑ 0,50 0510811218:32 Tetra chloroethene uglL NO 0.50 0510811218.32 Toluene uglL ND 0.50 0510811218.32 Ira ns-1.2-Dichloroethe ne uglL ND 0.50 0510811218:32 trans-1,3-Dichloropropene ug1L ND 0.50 0510811218:32 Trichloroethene ug/L N❑ 0.50 05/08/1218:32 Tdchiorofluoromethane ug/L N❑ 1.0 05/0811218:32 Vinyl chloride ug/L N❑ 1.0 05/08/12 18:32 1,2-Dichlofoethane-d4 (S) %q 101 70-130 05/08/12 18:32 4-Bromofluorobenzene (S) I 95 70.130 05/08/12 18:32 Dibromofluoromethane (S) I 98 70-130 05/08/12 18:32 Toluene-d8 (S) % 100 70-130 05/08/12 18:32 LABORATORY CONTROL SAMPLE: 757876 ❑ualifiers Pace Analytical Services, Inc- 9800 KinceyAwe. Suite 1p0 Hwilersville, NC 28078 {704)875.9092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limils Qualifiers 1,1,12-Tetrach1oroethane ug/L 50 49A 98 60-140 1,1,1-Trichloroethane uglL 50 423 85 60-140 1,1,2,2- Tetra chi oroethane uglL 50 48.3 97 60-140 1,1,2-Trichloroethane uglL 50 51.3 103 60-140 1,1-Dichloroethane ug(L 5o 41.1 82 80-140 1,1-Dichloroethene uglL 50 45.9 92 60-140 1,1-Dichloropropene uglL 50 45.5 91 60-140 12,3-Trichlorobenzene ug/L 50 49.8 100 60-140 1,2,3-Trichioropropane uglL 50 47.5 95 60-140 1,2,4-Trichlarobenzene uglL 50 47.6 95 60-140 1,2,4-TrimethyThe nzene uglL 50 50.0 100 60.140 1,2-Dibromo-3-chloropropane ug)L 5o 52.1 104 60-140 1,2-Dibromoethane (ED6) ug& 50 49.1 98 60-140 1,2-Dichlorobenzene uglL 50 47.2 94 60.140 1,2-Dichloroethane uglL 50 43.9 88 60-140 1,2-Dichloropropane ug/L 50 46.9 94 60-140 1,15-Trimethylbenzene uglL 5o 49.3 99 60-140 1,3-Dichlorobenzene ug/L 50 47.3 95 60.140 1,3-Dichloropropane ug/L 50 48.5 97 60-140 1,4-Dichlorobenzene ug1L 50 45.7 91 60-140 Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be repnodueed, except in full, without the written consent of Pace Analytical Services, Inc- Page 17 of 23 Pace Analytical Services. Inc. Pace Analytical Services, Inc. aceAnalytrcal 205 East Meadow Road - Suiie A 2225 Riverside Dr- wwwpeouiebs.com Eden. NC 27286 Ashevilis, NC 28804 (336)823-8921 (828)254.7176 DUALITY CONTROL DATA Project: Gilbarco 97746 Pace Project No.: 92117673 LABORATORY CONTROL SAMPLE: 757876 Spike LC5 LC5 % Rec Parameter Units Conc. Result % Rec Limits 2,2-Dichioropropane u91L 50 44.4 89 60-140 2-Chlorotoluene ug1L 50 47.7 95 6D-140 4-Chlorotoluene ug1L 50 48.0 96 60-140 Benzene ug1L 50 48.8 98 60-140 Bromobenzene ug/L 50 46.1 92 60-140 Bromochioromethane ug1L 50 48.6 97 6D-140 Bromodichloromethane ug1L 50 49.2 98 60-140 Bromoform ug/L 50 42.3 85 60.140 Bromomethane ug/L 50 42.1 84 60-140 Carbon tetrachloride ug/✓_ 50 49.1 98 60-140 Chlorobenzene ug/L 50 47.1 94 60-140 Chloroethane ug1L 50 40.0 80 60-140 Chloroform ug/L 50 45.9 92 60.140 Chiaromethane ug/L 50 43.8 88 60-140 cis-1,2-Dichloroethene ug/L 50 45.3 91 6D-140 cis-1,3-Dichlompropene ug1L 50 52.7 105 60-140 Dibromochloromethane ug1L 50 51.6 103 60-140 Dibromomethane ug1L 50 50.4 101 60-140 Dlchlorodifiuoromethane ug/L 50 37.8 76 60-140 Diisopropyl ether ug1L 50 48.2 96 60-140 Ethylbenzene ug1L 50 48.1 96 60.140 Hexacllloro-1.3-butadiene ug/L 50 52.7 105 60-140 Isopropylbenzene (Cumene) ug/L 50 44.8 90 60-140 m8p-Xylene ug1L 100 95.4 95 6D-140 Methyl-tert-butyl ether ug/L 50 46.7 93 60-140 Methylene Chloride ug/L 50 50.6 101 60-140 n-Butylbenzene ug/L 50 48.6 97 60-140 n-Propylbenzene ug1L 50 45.4 91 60-140 Naphthalene ug/L 50 52.2 104 60-140 o-Xyiene ug1L 50 47.5 95 60-140 sec-Butylbenzene ug/L 50 48.7 97 60-140 Styrene ug/L 50 52.3 105 60-140 tert-Butylbenzene ug/L 50 48.9 98 60-140 Tetrachloroethene ug/L 50 45.9 92 60-140 Toluene ug/L 50 46.7 93 60-140 trans-1,2-Dichioroethene uglL 50 43.5 87 60-140 trans-1,3-Dichloropropene ug/L 50 53.1 106 60-140 Trichloroethene uglL 50 47.8 96 M140 Trichlorofluoromethane ug/L 50 42.5 85 60-140 Vinyl chloride ug/L 50 43.2 86 60-140 1.2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (S) % 101 70-130 ❑ibmmofluoromethane (S) % 99 70-130 Toluene-d8 (S) % 101 70-130 Pace Analytical Services, Inc. 98 DO Kincey Ave. Suite 100 kunlersville, NC 28078 Qualifiers (704)875-9092 Date: 05/09/2012 05.30 PM REPORT OF LABORATORY ANALYSIS Page 18 of 23 This report shall not be repmduced, except in full, without the written consent of Pace Analytical Services, Inc.. N 1)!;a'ce rww.paoelaiSF..crom Pace Analytical Services, Inc. 205 Easl Meadow Road - Suite A Eden. NC 27288 (336)623-8921 Pace Analytical Services. Inc. 2225 Riverside Dr. Asheville, NC 28804 (826)254-7176 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 hincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9D92 Project: Gilbarco 97746 Pace Project No.: 92117673 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 159949 759950 MS MSD 92117382015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Ccnc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1.1,2- Tetra chloroe thane uWL ND 20 20 21.2 21.3 106 107 60-140 1 30 1,1,1-Trichloroethane ug/L ND 20 20 19A 19.9 97 100 60-140 3 30 1,1,2.2-Tetrachloroethane uglL ND 20 20 19A 20.0 97 1D0 60-140 3 30 1,1,2-Trichloroethane ug/L ND 20 20 22.0 22.0 110 110 60-140 0 30 1,1-❑ichtoroethane uglL N❑ 20 20 17.8 17.8 89 89 60-140 0 30 1,1-Dichloroethene ug/L ND 20 20 20.1 20.6 100 103 60-140 3 30 1,1-❑ichtoropropene ug/L N❑ 20 20 19.6 20.3 98 101 60-140 3 30 12,3-Trichlorobenzene ug/L N❑ 20 20 21.0 21.3 105 107 60-140 2 30 1.2,3-Trichloropropane ug/L N❑ 20 20 20.8 20.3 104 101 60-140 3 30 1,2,4-Trichlorobenzene uglL ND 20 20 19.2 20.5 96 102 60-140 6 30 1,2,4-Trimethylbenzene ug/L N❑ 20 20 20.8 21.7 104 109 60-140 4 30 1,2-Dibromo-3-chloropropane ug)L ND 20 20 20.8 20.4 104 102 60-140 2 30 1,2-Dibromoethene (EDB) ug[L ND 20 20 20.7 21.7 104 108 60-140 4 30 1,2-Dichlorobenzene uglL NO 20 20 20.1 20.6 101 103 60-140 2 30 1,2-Dichloroethane ug1L ND 20 20 20.4 20.5 102 103 60-140 1 30 1,2-Dichloroprepane ug/L ND 20 20 19.6 19.2 98 96 60-140 2 30 1,3,5-Trimethylbenzene ug1L NO 20 20 20.2 21.4 101 107 60-140 6 30 1,3-Dichlorobenzene ug/L NO 20 20 19.4 20.5 97 103 60-140 6 30 1,3-Dichioropropane ug/L NO 20 20 20.5 21.0 102 105 60-140 2 30 1,4-Dichlorobenzene ug/L NO 20 20 19.3 20.1 97 101 60-140 4 30 2.2-Dichloropropane ug/L NO 20 20 11.3 11.8 57 59 60-140 4 30 M0 2-Chlorotoluene ug/L N❑ 20 20 19.6 20.4 98 102 60-140 4 30 4-Chlorotoluene uglL NO 20 20 19.7 20.9 98 104 60-140 6 30 Benzene uglL NO 20 20 20.9 21.0 104 105 60-140 1 30 Bromobenzene ugJL ND 20 20 19.0 19.9 95 99 60.140 4 30 Bromochioromethane ug/L ND 20 20 21.2 21.3 106 106 6D-140 1 30 Bromodichloromethane uglL ND 20 20 20.7 21.1 103 106 60-140 2 30 Bromoform uq& NO 20 20 18.5 18.4 93 92 60-140 1 30 Bromomethane ugJL NO 20 20 13.6 17.0 68 85 6D-140 22 30 Carbon tetrachloride ugJL N❑ 20 20 22.5 21.6 113 108 60-140 4 30 Chlorobenzene ug/L ND 20 20 19.8 20.9 99 104 60-140 5 30 Chforoethane ug/L ND 20 20 18.5 18.0 93 90 60-140 3 30 Chloroform ug/L ND 20 20 20.3 20.6 101 103 50-140 2 30 Chioromethane ug/L ND 20 20 17.8 17.5 89 87 60.140 1 30 65-1,2-Dichtoroethene ug/L ND 20 20 20.0 19.7 100 99 60-140 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 18.7 19.2 94 96 60-140 2 30 Dibromochioromethane uglL N❑ 20 20 20.5 21.3 103 107 60-140 4 30 Dibromcmethane ug/L ND 20 20 21.7 21.8 108 109 60-140 1 30 Dichiorodifluoromethane uglL NO 20 20 17.0 17.6 85 88 60-140 4 30 Chisopropyl ether ug/L ND 20 20 20.2 20.9 101 104 60-140 3 30 Ethylbenzene uglL NO 20 20 20.7 20.9 103 105 60-140 1 30 Flexachlaro-1,3-butadiene ug(L N❑ 20 20 19.3 21.3 97 106 60-140 9 30 Isopropy The nzene (Cumene) uglL ND 20 20 18.6 18.7 93 94 60-140 0 30 m&p-Xylene uglL N❑ 40 40 40.8 41.3 i02 103 60-140 1 30 Methyl-tert-butyl ether uglL NO 20 20 19.8 20.5 99 103 60-140 3 30 Methylene Chloride uglL ND 20 20 19.7 19.9 99 99 60-140 1 30 n-Butylbenzene uglL N❑ 20 20 18.9 19.9 95 99 60-140 5 30 Date: 05/09/2012 05 30 PM REPORT Of LABORATORY ANALYSIS Page 19 of 23 This report shall not be reproduced, except In full, without the written consent of Pace Analytical Services. Inc aceAnalAcalR wwwpacewbs com Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Pace Ana"Cal Services, Inc. 2225 Riverside ❑r. Asheville, NC 28804 (828)254.7176 QUALITY CONTROL DATA Pace Analyt"l Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 20078 (704)875.9092 Project Gilbarco 97746 Pace Project No.: 92117673 MATRIX SPIKE 8 MATRIX SPIKE DUPLfCATE: 759949 759950 MS MSD 92117362015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conic. Result Result % Rec I Rec Limits RP❑ RPD Qual n-Propylbenzene uglL ND 20 20 18.6 19.3 93 97 60-140 4 30 Naphthalene uglL ND 20 20 21.4 22.1 107 110 60-140 3 30 o-Xylene uglL ND 20 20 19 7 20.4 99 102 60-140 3 30 sec-Butylbenzene uglL N❑ 20 20 19.7 20.5 99 102 60-140 4 30 Styrene uglL ND 20 20 20.6 22.1 103 110 60-14G 7 30 tent-Butylbenzene uglL ND 20 20 20.2 20.7 101 103 60-140 2 30 Tetrachforoethene uglL ND 20 20 19.1 19.9 95 1DO 60-140 4 30 Toluene uglL ND 20 20 19.7 19.8 99 99 60-140 0 30 trans-1,2-Dichtoroethene ugll- N❑ 20 20 19.4 19.2 97 96 60-140 1 30 trans-1,3-Dichtoropropene uglL N❑ 20 20 19.8 19.2 99 96 60-140 3 30 Trichloroethene uglL N❑ 20 20 21.1 21.0 105 105 60-140 1 30 Trichiorofiuoromethane uglL N❑ 20 20 19.6 20.2 98 101 60-140 3 30 Vinyl chloride ug& ND 20 20 18.8 19.2 94 96 60-140 2 30 1,2-13ichloroethane-d4 (S) % 99 99 70-130 4-8romofluorobenzene (S) % 99 100 70-130 Dibromolluoromethane (S) % 100 98 70-130 Toluene-d8 (S) % 99 100 70-130 Date: 05/09/2012 05 30 PM REPORT Of LABORATORY ANALYSES Page 20 of 23 This report shall nal be reproduced, except in full, without the written Consent of Pace Analytical Services. Inc. 1)!;5'ceAnalytical' wti+wpeceiebs.wrn Pace Analytical Services, Inc. 205 East Meadow Road - SuiteA Eden, NC 27288 (336)623-8921 Pace Analytical Services, Inc. 2225 Riverside Dr. AsheVllle, NC 28804 (828)254-7176 QUALITY CONTROL DATA Project: Gilbarco 97746 Pace Project No.: 92117673 QC Batch WET120705 Analysis Method: SM 5210B OC Batch Method: 5M 5210B Analysis Description: 521OB BOD, 5 day Associated Lab Samples: 92117673005. 92117673006, 92117673007 METHOD BLANK: 759026 Matrix: Water Associated Lab Samples: 92117673005. 92117673006. 92117673007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day mg/L NO 2.0 05/08/12 17:28 Pace Analytical Services, Inc, 9800 K;neey Ave. Suite 100 Huntersville. NC 28078 (704j875-9092 LABORATORY CONTROL SAMPLE: 759027 Spike LC5 LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD. 5 day mg/L 198 203 103 84-115 SAMPLE DUPLICATE: 759028 92117748001 ❑up Max Parameter Units Result Resell RPD RPD Qualifiers BOD, 5 day mg1L NO NO 20 Date. 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS Page 21 of 23 This report shall not be reproduced, except in full. without the written consent of Pare Analytical services, Inc.. R 2ace Analytica! www.pacelaba.mm Project. Gilbarco 97746 Pace Project No.: 92117673 DFFINITIONS Pace Analytical Services, Inc. 205 East Meadow Road - SulteA Eden, NC 27288 (336)623-8921 QUALIFIERS Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville. NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersvdle, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot. or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines. unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample {Duplicate} MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride. Pace Analytical is T N I accredited Contact your Pace PM for the current list of accredited analytes. TNI - The NE LAC Institute LABORATORIES PASI-A Pace Analytical Services - Asheville PAST-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS 132 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated for the dilution using the most amount of sample. MO Matrix spike recovery andlor matrix spike duplicate recovery was outside laboratory control limits. Date: 05/09/2012 05:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services. Inc. Page 22 of 23 zacAnalytical www.peceiebs.cnm Project: Gilbarco 97746 Pace Project No.: 92117673 Pace Analytical Services, Inc. 205 East Meadow Road - Suite A Eden. NC 27288 (336)623.8921 Pace Analytical Services, Inc. 2225 Riverside Or. Asheville, NC 28804 (828)254-7176 QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Nuntersville. NC 28076 (704)875-9092 Lab ID Sample Ip GC Batch Method GC Batch Analytical Method 92111673001 SW01 SM 6200B MSVl18975 92117673002 SW-02 SM 6200B MSV118975 92117673003 SW-03 SM 6200E MSV118975 92117673004 SW-04 SM 6206E MSV118975 92117673005 MW-46 SM 5216B WETI20705 SM 5210B 92117673006 MW-47 SM 5210B WET120705 SM 5210B 92117673007 MW-49 SM 5210B WET120705 SM 52108 Analytical Batch WET120707 W ET120707 W ET120707 ❑ate 05/09/2012 05.30 PM REPORT OF LABORATORY ANALYSIS Page 23 of 23 This report shall riot be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ..>PaceAnalytical *vr.aaoslaha.eom CHAIN -OF -CUSTODY I Analytical Request Document The Chafn-of-Custody is a LEGAL DOCUMENT. All relevant fields must be Completed accuralely. Section A Section 8 Section C page: ` of Required Cllenl Intorrnatw: Required Pro)bd InformnUon- Invoice IMort aVan- Company: Report TO: Attention: 1546134 ' ,1 ■r _ _ Addresti•,'i Copy lo; Company Name: Lt � REGULATORY AGENCY Address: r NP7E5 i- GROUNDWATER DRINKING WATER ST F- RCRA r" OTHER Purcnasa Order No.: ece emote CYIcL fC C LQI c • Refennc.: Pna F•ax: Project Name: Pace pmjact Sltn t.UCetIpN Mro hsan.par C— Requeehd Due DaWTAT: Project Number Pace Prone V: STATE: Requested Analysis Filtered (YIN) S*cWn D Matrtx Code, _ R.gri.dclienl mwrrneeorr MA7Rrx f rppf 9 COLLECTED Preservatives r Drinking wafer Dw o Water WT Wash Water U COSTPARTTRC w Z Product P En a 5VIVS0Iid SL .y �. SAMPLE ID 0pe OL 0 w (A-Z, 0-9I �) Air AR v Uj C a Z !4 Sample IV MUST 9E UNIQUE Tissue TS O a LU E S �i Z rn U Other ar x LU W v ? I} � a a 0 m O v7 ` a 9Z1171-3 z v m E 'y+ DATE TIME DATE TIME '�+ # D _ 1 Y (a z r8" z ZE o C ♦ of Pace Project No./ Lab 1.0, Pat 3 1Q - iEA 10E7 4 SC —] -`Q 111• VL s 4.55T, a - iD : 10 oc 7 W-- lo-, 25 a it to 1, ,2 ADDMCNAL COMMENTS - REI..INQU ISHED 9Y IAFFILIATION D TIkE AC $ 1 AFFILI O DATE TIME SAMPLE t;gNDf7]ONS ILI ORIGINAL SAMPLER NAME AND SIGNATURE o 9 E PRINT Ham. of SAMPLER: .` I m )ATE Signed 81GNATl1RE of SAMPLER: 'L— {MM10DrM: 1, k-L H .lrnpor!wt Note! By sgr•Jng tf 15 form you are accepling Paces NE7 30 Jay paymem terms wd agt"N to late d,arges or 1.5% per month rer any m is nol peed -1tan 30 drays. F-ALL-0-020rev.07, 15-May-2007 Document Name: document Revised: January 30, 2012 e/ Sample Condition Upon Receipt (SCUR) Page 1 of 2 Document Number: Issuing Authority: F-CHR-CS-03-rev.06 Pace Huntersville Quality Office Client Name: J,� Project # "F'Z1r-?rc 73 Where Received: Guntersville ❑ Asheville ❑ Eden Courier: Fed Ex UPS❑ USPS❑ Client❑ Commercial Pace Other r; ❑ ❑ Custody Seal on Cooler/Box Present: ❑ yes J�T/ no Seals intact: ❑ yes ❑ no Packing Material: ❑ Bubble Wrap L?"'Bubble Bags ❑ None ❑ Other Thermometer used: IR Gun Vial: T1102 Type of Ice: et Blue None 7-1 Senples on ice, cooling process has begun Temp Correction Factor No Correction T1102: Subtract 1.2'C Corrected Cooler Tem �y C p Temp should be above freezing to VC Biological Tissue is Frozen: Yes Na NIA Comments: Date I u i on examining cont n Chain of Custody Present: .E5Y,s ONO ❑NIA 1, Chain of Custody Filled Out. I�fes ONO ❑NIA 2. Chain of Custody Relinquished: E]�es ON- ❑NIA 3. Sampler Name & Signature on COC: _Dlr;s ONO ❑NIA 4. Samples Arrived within Hold Time: k es ❑No ❑NIA $. Short Hold Time Ana" IS a72hr : pk,6s ONO ❑NIA s. Rush Turn Around Time Requested: ❑Yes ❑N- ❑WA 7. Sufficient Volume: Yes ONO ❑NIA 8. Correct Containers Used: -Pace Containers Used: _pYes E 1Yes ONO ONO ❑NIA ❑hllA g. Containers Intact: es ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑N❑ ❑ A 11. Sample Labels match CDC: -Includes date/time/ID/Analysis Matrix. A�_Yes ONO ❑NIA 12. All containers needing preservatlon have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions: VOA, coliform. TOC, O&G, WI -SRO (waler) Yes ❑Yes Oyes �.� ❑No -L]NIA Cl No NIA El No 13. Initial when completed Samples checked for dechlorination: OYes El No 01 IA 14, Heads ace in VOA Vials >6mm : ❑Yes 89 ❑NIA 15, Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # if purchased): ElYes []Yes ONO ONO ❑wX NIA 16. Client Notification/ Resolutlon: Person Contacted: Comments/ Resolution: Date/Time: SCURF Review: ff bate: ��- SRF Review: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a oopyi Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Field Data Required? Y / N i%lr1 1Date: Sl I� /JZ_ J s form will be sent to the North Carolina DEHNR APPENDIX B CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-7 25,000 20,OGO z (Q 10,000 5,000 d� V. V. V. V. ✓$ V. %/� ,/� %/. %/� V. d� V. ✓/ V q/. c% V. V. ✓a V. �/ O r c� "� S fi 3 o9 D 1 2 0 S & > 3 O 7 Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14D 500 Chill 300 a D n m nr Q w 200 100 A v1p '`90 %107 '9? '` 0 >'9r 'S '-9 on' &> '9& 4 &0 '% % '01'00 70 WS % % % '09 '70 '77 ),71p Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-16 w 0 n m 50 0 ra r iJ90 >'97 >`9? '100 '!. '`gS ri90 O9> %00 �`�,9 ''00 ''07 V0,1'o f1.Q0 '>7 '>,O5 V0,1%0 %0> '06�� 770 'ter / j,--) Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-24 t Tota1 VOCs t Chlorinated VOCs o ? 7 s 9s .� a r � °� s s � o Date 7,500 5.000 2,500 0 ✓ CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-43D �j O& 09 1p Date 1,000 o 400 200 0 n 0 a n m m 0 z N r CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-45 Kc 18 15 14 12 0 0 0 0 m 10 v 0 z 8 2 4 2 0 �� )29 70 71, r., Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-46 1.400 1,200 1,000 w 0 800 0 N 600 r 400 200 0 Date CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS 1,400 1,200 1,000 400 200 Date f TOTAL VOCS 0 CHLORINATED VOCS —� TOTAL PETROLEUM HYDROCARBONS CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-49 Date iRIlIR m n 0 800 m 0 600 ►,$ Px$l$l --W-- TOTAL VOCS o CHLORINATED VOCS —TOTAL PETROLEUM HYDROCARBONS CHLORINATED AND TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-53D Date 1,400 1.200 1,000 n a 800 � K6111] a] a _ r