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WI0400110_Application_20090827
&-eo,ev)o ) State of N%J1 1 Carolina Department of Environment and Natural Resources Division of Water Quality APPLICATION FOR PERiAITTO CONSTRUCT AND/OR USE A WELLS) FOR INJECTION Type 5I Wefts — In Situ Groundwater Rem ediatioa 1 Type 5T Wells — Tracer- Injection • Bo not use this form For remediation systems that extract contaminaled groundwater, treat it, and reinject the treated groundwater. • Submit TWO copies of the completed application and all attachments to the address on [lie last page of this form • Any changes made to this farm will result iji the appile-ation package being returned. Application Nutnher (to be completed by DWQ): I. GENERAL INFORMATION: 1. Applicant's Name {generally (lie msponsible party): High Point Regional Health Systems 2. Signing Official's Name: lVlS --"Q4 ,�"4W'-&r /-/L"4 Title: 3. Mailing address of applicant: Nigh Point Regional Health Systems Pd t' P.O. Box HP-5 City: High Point State: NG Zip: 27261 Telephone number: (336) 878-6000 (2488) Fax number: (336) 878-6297 4. Property Owner's Name (if different from Applicant): Harry Boles 5. Property Owner's mailing address: 115 S. Main St. City: Kernersville State: NC Zip: 27285 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Lyndai Butler Title -.-Project Manager Company: S&ME, Inc. Add -Tess: 3718 Old Battleground Rd City: Greensboro Telephone number: 336-288-7180 Email Address: (butler@smeinc.com Lt. PERMIT INFORMATION: State: NC Zip: 27410 Fax number: 336-288-8980 1. Project is: O New ❑ Modiftcatiaty of existing permit ❑ Renewal of existing permit without modification ❑ Renewal of existing permit with modification 2. If this application is being submitted for renewal or inodilication to an existing,}�erm provide: existing permit number 19 6V Yo :)//0 and the issuance date AAA Ape:- 9,__ For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owncr's signature to indicate consent (if the applicant is not the owner). For all renewals, you must submit a states report includhig monitoring results of all injection activities to date. Revised 8/07 U1C-5115T Page I of I REGEIV tJ ll:ivr. . i+ 1 AuG2i)2-011 APPLICATION FOR mcm i r TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 51 Wells — In Situ Ground►vater Remediation / Type 5T Wells — Tracer Injection V1. CERTIFICATION 1, _ -J Y4n-t 0--- >_ . • P-� lYt4erg, , hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those iiidividuais iininediatcly responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting False information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature' _ _ Date:_ Title: If authorized agent is acting on behalf of the applicant, supple a letter signed by the applicant authorizing the above agent VI1. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner " means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on laird shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing) I Harry Boles , ,, . , as owner of the property on which the injection well are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200) Signature: - n Date: �I �/ 2 �I Title: Submit TWO copies of the completed application package, including all attachments, to. U1C Prograin Aquifer Protection Section North Carol'inn DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 RE�ENED I oaik 10WQ AQl11F`I~ WOTFTTINl SFCTION Revised 8107 U[C-51/5T Page 7 of 7 ORIGINAL PERMIT APPLICATION iJ ►�- r�'' t vt � w i State of North Carolina RECEIVED IDENRI DWO Department of Eitvironill cnt and Natural Res o40WR PPnTF: Tlf1K} SECTION Division of Water Quality MAY 2 8 2009 APPLICATION FOR PERM IT TO CONS`1'RUCI' AND/OR USE A WELL(S) FOR INJECTION Type 51 WeIla —.flt Sitrr G1-0t[l1(INVIttel- Remediation 1 Type 5T Wells —Tracer Injection ■ Do not use this form for remcdiation systcnis that extract contaminated groundwater, treat it, and reinject the treated groundwater. Submit TWO copies of the completed application and all attachments to (lie address on the last page of this Form. 10 Any changes made to this Form will result in the application package being rye -turned. Application Number (Io be coniplered b), DK'Q): k/—T O //o 1. GENERAL 1NFOR1IATlON: 1. Applicant's Name (generally the responsible party): High Point Regional Health Systems 2, Signing Official's Dame: de yu 5 1 )lk-.? Title: r 3. Mailing address of applicant: High Point Regional Health Systems '] �e?, k r P.O. Box HP-5 City: High Point State: NC Zip.. 27261 Telephone number: (336) 878-6000 (2488) Fax number: (336) 878-6297 4, Property Owner's Name (if different from Applicant): Harry Bales 5, Property Owner's mailing address: 115 S. Main St. City: Kernersvilie State: NC Zip: 27285 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Lyndal Butler Title: Project Manager Company: SBME, Inc. Address: 3718 Old Battleground Rd City: Greensboro State: NC Zip: 27410 Telephone number: 336-288-7180 Fax number: 336-288-8980 Email Address: tbutler@smeinc.com H. PERMIT INFORMATION: 1. Project is: g New ❑ Modification of existing permit f_J Renewal of existing permit without modification Renewal of existing permit with modification 1 If this application is being submitted For renewal or modification to an cxisling permit, provide: existing permit number NA and the issuance date NA For renewal without modifications, fill out sections i & I1 only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). For all renewals, you must submit a status report including monitoring results of all injection activities to date. Revised 8107 t! lC-5i15 T Page 1 of 7 APPLICATION FOR PERMIT TO CONSTRUCT ANIVOR USE A NVELL(S) FOR INJECTION Type 51 Wells — In Sim Groundwater Remediation / Type ST WOls—Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION L Facility name: Dynamic Capital Mortgage, Inc. (Office Building) Complete physical address o[the facility: 133 S. Main St City: Kernersville B, INCIDENT DESCRIPTION I. Describe Elie source of the contamination: Former 550 Gallon UST (heating oil) County: Fors State: NC lip: 27285 2. List all contaminants present in soils or groundwator at the site (contaminants maybe listed in groups, e.g., gasoline, diesel, jet fuel. fuel oil- chlorinated ethenes. chlorinated ctlianes. metals, pesticides/herbicides, etc): Heating Oil #2 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection cone)? ❑ Yes If yes, list maximum measured separate phase thickness feet in soil ®No If no, list maximum concentration of total VOCs observed at site: C-9 C-18 Aliphatics11,925mglk� pp), 4. Agency managing the contamination incident: 91 UST Section ❑ Superfund Section (including REC Program and DSCA sites) ❑ DWQ Aquifer Protection Section ❑ Solid Waste Section ❑ Hazardous Waste Section ❑ Other: 5. Incident managers name Karen full and phone number 33E-771-5000 6. Incident number or other site number assigned by the agency managing the contamination incident: 16401 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: None 2. DWQ Non -Discharge or NPDES permits: None 3. County or DEH subsurface wastewater disposal permits: None 4. Other environmental permits required by state or federal law: None Revised 8107 U IC-511?T Page 2 of 7 AI) pLICATIOrN' FOIt 1'ERINIITT❑ CONSTRUCT AND.:Iflt USE A XVELL(S) FOR INJECTION Type 51 Wells— lit Sittr Groundwater Remediation 1 -I ype 5T Wells— Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA L List all proposed injectants, NOTE: Any substance to be injected as a tracer till to prornole in situ reinediation must be reviewed by the Occupational and Environmental Epideneiolog>> Section (OEES) ofthe Division of Public Health, Department of Health and Human Services. Review the 1W of ee y�r(i (. �i igLr_tyrLisT or cornact the UIC Program to determine if the injectants you are proposing have been reviewed bY OEES. Injectant: Sodium persullate and calcium peroxide (Oxygen No Chem OBC) Concentration at point of injection: 15% Weight by volume Injectant: Concentration at point of injection- Injectant: Concentration at point of injection: Injectant: Concentration at point of injection: Injectant: Concentration at point of injection. - Source of fluids used to dilute or chase the injcctants listed above: ❑ None ® Municipal water supply ❑ Groundwater from private well or any well within `./a mile of injection site ❑ Air ❑ Other: 3. If any welt within '/4 mile of injection site, a private well, or surface water is to be used as the fluid source, supply the following information: a. LocationlID dumber of source; NA Depth of source: c. Formation: Rock/Sediment type: e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE.- If contaminated groundwater is to be used as the dilution or chase fluid, this is tzot the proper- perrrait application forne. Yore must apply for a closed -loop groundwater reanrediation permit using yLiplicatirrn for►rr Gi!•RS_ Revised 8/07 1J1('-51.51 Page 3 of'7 APPLICATION FOR PERMIT TO ( WN.s I RU( I AND1011 USE' .X NVE LL(S) FOR INJECTION Type 51 Wells — In Sim Groundwater Reni diation J Type ST Wells —Tracer Injection B. PROPOSED OPERATfNG PARAMFTHS I . Duration of Injection: Maximum number of separate injection events:? Expected duration of each injection event 6 Hours Expected duration between events (if more than one event): NA ?. Injection rate per well; 2 to 10 gallons per minute (gpmi 3. Total injection volume: 480 gallons per day (gpd ): NA gallons per event (if separate events) 4. Injection pressure: 20 to 110 poundsisquure inch (psi) 5. Temperature at point of injectiot: Ambient °r 6. Briefly describe how the above narameters will he measured and controlled: The injection solution will be mixed on -site pumped with a double diaphragm pump into the borings. Redox Tech will monitor injectant pressures and volumes via the pump system. 7_ Estimated hydraulic capacity of the well: unknown gpel1 C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: ❑ Existing well(s) proposed for use as an injection well. Provide [lie data in (2) tliro ugh (6) below to the best of your knowledge. 9 Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name; Gary Meyers NC Well Contractor Certification number: 3380 3. Date to be constructed: TBD Number of borings: 6 Approximate depth of each boring (feet): 18 4. Screened intervallInjection interval of injection wells: Depth: 8 to 18 feet below ground surlitce (iI' multiple intervals, indicate shallowest and deepest. depth). 5. Well casing (NIA if injections is through direct push rods): Type: ❑ PVC ❑ Stainless steel f 0111er; NA- Injection Through dinectpush rods Casing depth: to ft. 6. Grout (NIA if injection is throLuglt direct push rods): Type: 1F Cement Bentonite L Other: NA Grout depth: In _ ft. Revised 8107 I_J1C-5V5T Page 4 of 7 APPLICATION FOR PERNHT TO C'ONS'1 RUCT AND101i US[_ A WELLS) FOR INJECTION Type 5I Wells — In Situ Lrauttd►vater Recnediation 1 T-pc 5T Wills —Tracer Injection V. ATTACHMENTS Provide the following items as attachments with the given Itiading5: A. SITE HISTORY Provide a brief description of the site history including. (I) site usage historically and present, (2) origin of the contamination, (3) previous remedial action(s). NOTE: G.S. 89E-18 requires that air - geologic plans, rr::ports, or elocutnews in rwltdeb the pe+Jortnance is related to the public vvelfare or safeguarding of the environrnew he prepared by a lice nseel geologist or subordinate under his or her directio)v G.S. 89E-13 requires that all drriwmg. rcpurls, or documents involving geologic work which shall have been prepared or approved by a licensed geologist or a Subordinate tarder his or leer direction he .signed and sealed by hint or her. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) the regional geologic setting; (2) significant changes in lithology; (3) the hydraulic conductivity, transmissivity, anti specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and (4) the depth to the mean seasonal high water table- C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within '!a mile of the injection site is used as the source well, include chemical analysis of source fluid here D. INJECTION RATIONALE Attach a brief description of'the rationale fat- selecting the injectanis uld concentrations proposed for injection, including: (1) goals of the injection project; (2) a description of the reactions between the injectan is and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: (1) construction plans and materials; (2) operation procedures; (3) a detailed diagram ❑f the surface and subsurface portions of the .system: and (4) a planned injection schedule. F. MONITORING PLAN Provide a plan for monitoring the results of the injection, illClUding: (1) a list of existing and proposed monitoring wells to be used: (2) a list of monitoring parameters and analytical methods to be ttsed; and (3) a schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be localedso as to detect an'v Inovenrent ofinjection fluids, process by- products, orformation fluids outside the injection area orsou4 The utoltiluring parameters should include the target contaminants as well as secondary or ittternrediale ronlaminants which ma.y result front the injection and other parameters which may serve to indirrate the prol,Tress uj the ill tended reaviions, such as pH. ORP, dissolved oxygen, and Revised 8/07 UIC-5115'r Page 5 of 7 APPLICATION FOR PLRIIr fo Ct7; s'rIZUCT AND/OR U S F A W LLL(S) FOR INJECTION "Type 5I Wells — ]it Sint Groundwater- Remediation p Type 5'T was —`tracer Injection other electron acceptors and donors. The inonituriug sc hedide .shornId he consi.,aew ivffh the puce of the anticipated reactions and rate of transport nj the inje.ctctnts and c t.miaininultt,s. G. WELL DATA Provide a tabulation of data oil all existing or abandoned wells within '.,4 mile ref the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring weIIs anti w c I Is proposed f'or use as injection wells. Such data shall include a description of each well's use (~eater supplN, monitoring, ctc), total depth, screened or open borehole depth interval, and well construction orabandonmerit record, ifava11able. H. MAPS Attach the following scaled. site-specihc maps (1 ) Area map based on the most recent USGS 7.5' topographic map of [lie area. at a scale of 1:24.000 and showing the location of the propuscd injection sft! (2) Site map including: a. all property boundaries; b. all buildings within the property boundary-- c. existing and proposed injection welts or w c I I lield(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within''/4 mile oftlie injection woll or well system; e. all surface water bodies within 'l4 mile of the injection well or well system; and f, all existing or abandoned wells within'/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring* wells and wells proposed for use as injection wells. (3) Potentiometric surface maps} including- a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant pluntc, including isoconcentraLion lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross -sections) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology Revised 8/07 UIC-5I. �'i Page 6 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A 1VIA.L(S) ],OR INJECTION Tvpe 51 Wells - fit Situ OrUundwaIer Rentoil ialion I Type ST 1VelIs - Tracer Injection V1. CERTIFICATION 1, , hereby certify under penaIiy of law that 1 Have personally examined and ant familiar with the inlormation submitted in this doe ument and all attachments thereto and that, based an Illy inquiry of those individuaIs imntediate] y responsible for obtaining said information, I believe that the information is true, accurate and complete. l ani aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. 1 agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature: late: Title: C _ �� /GK r— ed .' jaurhorired agent is acting on behalfgfthe applicant, suppl), a letter signed bye the applicant authorizing the above agent. V11. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" tneans air). person who hol(ts the jee or other propert, rights in the well being constructed. A well is real propert)? and its emisiruction an land shall he deemed to nest ownership in the land owner, in the absence of contrary agreement in writing.) I Marry Boles as owner of the property on which the injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200) Signature: if �( CL.�-�., _ _a — Dater Title: AF +for° Submit TWO copies of the completed application package, ineluding ail attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-D1 Q 1636 Mail Service Center Raleigh, NC 27699-1636 Tcleplione (919) 733-3221 �b�t I VED 1 DENR 1 DWQ AQUIFI=P PP0TF:rT1()tj SF,,,,, MAY 2 B 2009 Revised 8107 l II Page 7 or7 High Point Regional . ,--._h Systems .... AE Project Number: 1584-08-051 Injection Well Permit North Carolina May B. 2009 A. SITE HISTORY According to the Comprehensive Site Assessment/Corrective Action Plan prepared by S&ME in response to the subject incident in June 1996, the subject property was occupied by a private residence prior to development of the current structure in 1959, The site is currently a commercial building. A 550 gallon heating oil UST for consumptive use at the facility was installed in 1959. No indication of a release of product from the UST system was docurnented prior to closure. The subject UST was closed by removal in February 1996, and approximately 13 tons of petroleum -impacted soil was excavated for off -site disposal. The amount of released product was undetermined. The maximum soil total petroleum hydrocarbon (TPH) concentration detected from the excavated soil was 46,500 parts per million (ppm). A Tank Removal Report was prepared by S&ME in April 1996. Field activities performed in April 1996 delineated the vertical extent of TPH impacts in soil more than 5 feet shallower than the depth to groundwater. A Site Sensitivity Evaluation report was prepared by S&ME in April 1996- Five soil probes were performed in May 1996 to delineate the horizontal extent of TPH impacts. Based on the analytical results of ten soil samples, the horizontal and vertical extent of impacted soil was delineated. The Comprehensive Site Assessment/Corrective Action Flan was submitted in June 1996. Activities related to the release were temporarily suspended in 1996 in response to NC Senate Bill 1317. High Point Regional Health Systems received a Notice of Regulatory Requirements from the North Carolina Department of Environment and Natural Resources requiring a Limited Site Assessment (LSA) in August 2008. On December 1, 2048, S&ME submitted an LSA report documenting the detection of C9-C 18 AIiphatics and C9-C22 Aromatics at concentrations exceeding the corresponding residential Maximum Soil Contaminant Concentration (MSCC) in soil sample SB-10-12 collected and analyzed for the LSA. At 20 feet below grade, no target constituents were detected at concentrations exceeding either the corresponding residential MSCC or sail -to - groundwater MSCC. No dissolved impacts related to heating oil were detected in groundwater. As an NCDENR-DWM low risk site, the site could be closed using a deed restriction; however the responsible party has elected to remediate the subject impacted soil to levels at less than the residential MSCCS. I. Ed Henriques, a Licensed Geo ct ist (# 1216) for S&ME, Inc. do certify that the information contained in i ;report is correct and accurate to the best of my knowledge. n SE At Seal and Signatur S&ME, Inc. is lictice geology (certification #C-145) and engineering (certification # F-0176) in North Carolina. 1-1 High Point Regional th Systems __ME Project Number: 1584-08-051 Injection Well Permit North Carolina May $ 2009 B. HYDROGEOLOGIC DESCRIPTION According to the review of 1985 Geologic Map of North Carolina, the site is in the Charlotte Belt of the Piedmont Physiographic Province, and bedrock at the site and surrounding area is comprised of intrusive Granitic Rock that is described as mega- crystic and equigranular. A review of the USGS Topographic map of the Kernersville quadrangle dated 1969 (photorevised 1987) shows that the site is located on an upland divide. The topographic map shows minimal relief near the intersection of Main Street and Mountain Street, The topography slopes from the upland divide to drainage features located north, south and west of the intersection, Based oil the surrounding topography, the estimated groundwater flow direction from the subject site is generally to the southwest. During soil sampling activities performed by hydraulic -push techniques, apparent backfill soil was encountered to a depth of approximately 9 feet below ground in soil probe SB-6 performed in the former UST basin. Tile underlying residual soil consisted of fine sandy silt to a depth of 12 feet below ground. Underlying the sandy silt was silty fine to medium sand to the probe termination depth of 31 feet below ground. Bedrock was not encountered during soil sampling activities. A permanent groundwater monitoring well (MW-1) was installed at the same location as soil probe S13-6 with hollow -stem augers to a depth of 35 feet below ground. The depth to water in monitor well MW-1 measured on October 15, 2008, was 28.6 feet below ground. On April 2, 1996, the depth to water in temporary well KMC-I was 24.5 feet below ground surface. Data for hydraulic conductivity, transmissivity and specific yield of the injection aquifer are not available. The proposed injection is planned in the unsaturated zone to address soil contamination only. C. INJECTION FLUID COMPOSITION The proposed injectant is Oxygen BioChem (OBC), manufactured by Redox Technology, LLC. OBC is composed of a mixture of sodium persulfate and calcium peroxide. This product is utilized for chemical oxidation and aerobic bioremediation, petroleum hydrocarbon remediation, creosote remediation, and partially halogenated hydrocarbon remediation. It is an odorless, off-white fine granular solid. OBC does not pose a radiological hazard. It is chemically classified as an oxidizer. Additional information concerning OBC is provided in the attached Material Safety Data Sheets (MSDS). D. INJECTION RATIONALE The goals and expected accomplishments of the proposed injection are to remediate the impacted soils in prevent the source area to the extent feasible. The remediation of contaminated soils will help to prevent potential future migration of petroleum contaminants into the groundwater. The total area of soils to be treated is approximately 10 feet by 12 feet in plan view and from 8 feet below ground to 18 feet below ground in High Point Regional th Systems ME Project Number-.. 1584-08-051 Infection Well Permit North Carolina May 8. 2009 depth this soil volume Is equal to approximately 44 cubic yards. Based on recent depth to groundwater measurements, the deepest injection level is approximately 10 feet above groundwater. Groundwater remediation is not proposed nor required by NCDENR-Underground Storage Tank Section because the most recent sampling results do not document dissolved impacts in monitoring well MW-1. Redox Tech has formulated a mixture of sodium persulfate and calcium peroxide that actually combines bioremediation and in -situ chemical oxidation (ISCO). This product, Oxygen BioChem (OBC}r^', supports a two -fold mechanism for treating contaminants of concern. ❑BC delivers the persulfate radical using FMC's patent -pending KlozurTm activation chemistry for short term ISCO, and also provides electron acceptors (oxygen and sulfate) for longer -term biological oxidation once the sulfate radicals are spent. The compounds formed by the reaction of injected materials with groundwater are water, oxygen, and sulfate. The sulfate continues on to react with the soils as part of the anaerobic degradation process (i.e. bioremediation). E. INJECTION PROCEDURE AND EQUIPMENT We propose to use in -situ injection with OBC as the optimal method of remediation at the site. Typically a total oxidant demand (TOD) test is suggested on a soil sample collected from the site, so that the oxidant demand from the natural organics and metals (iron and manganese) can be determined in addition to the stoichiometric oxidant demand of the contaminants. However, due to the limited size of the treatment area, a conservative TOD value has been assumed for this application based on experience in the area. One injection event is proposed. The injection event will be scheduled within approximately three to six weeks after approval of the injection permit. A letter report including logs, field notes, post injection monitoring will be provided after completion of the remediation. JEM163 ►lam%I 1.111 i Lc�111V 1 S&ME would conduct past-remediation monitoring approximately 60 days after injection to document the effectiveness of the soil treatment. Two soil samples each from two soil probes advanced into the core of the contaminated soil zone will be collected. The four soil samples collected at varying depths within the remediation area will be submitted for laboratory analysis by EPA methods 8260 and 8270, and by the MADEP methods for volatile petroleum hydrocarbons (VPH) and extractable petroleum hydrocarbons (EPH). Target cleanup levels for soil will be the Residential MSCC. The target contaminants are petroleum products within the soils onsite. There are no other estimated degradation products including secondary or intermediate contaminants which may result from the injection. The base of the proposed injection zone is approximately 10 feet above the water table. Groundwater monitoring has not indicated that presence of contaminants of concern within the monitoring well. Consequently, there is no proposed groundwater monitoring. High Point Regional :h Systems AE Project Number: 1584-08-051 Infection Well Permit North Carolina May 8, 2009 G. WELL DATA Based on the findings front the well survey completed by S&ME as part of and reported in the LSA dated December 1, 2008, no water supply wells were identified within'/4 mile of the subject site. One monitoring well MW-1 has been installed as part of the assessment activities conducted to date. A well construction record is available for the monitoring well. A copy is attached. The table below depicts a summary of the well data. Well No. MW-1 Date Installed 10-15-08 Well Use Monitoring Total Depth b s) 35 Depth to Water b s 28.60 Screen Interval 20-35 Status of Well Active Distance from Injection Point --•3' Notes: bgs = below ground surface H. MAPS A topographic map depicting the location of the subject site and vicinity is provided as Figure 1. The Potential Receptor Map is provided as Figure 2. Figure 3 depicts site features including a structure, a monitoring well, the former UST location and the soil remediation area. Potentiometric maps are not available as only one monitoring well has been installed. Groundwater impacts have not been detected in the monitoring well and thus groundwater contaminant plume maps and associated cross -sections are not provided. t►AF 08-27-'09 09:01 FROM-DENR 3367714633 3367714633 T-216 P002/006 F-903 PHASE I LIMITED SITE ASSESSMENT Former High Point Health Care Ventures 133 South Main Street Kernersville, Forsyth County, North Carolina S&ME Project No. 1584-08-051 Prepared For: High Point Regional Health Systems P.O, Box HP-5 High Point, North Carolina 27261 Prepared By: S&ME, Inc. 3719 Old Battleground Road Greensboro, North Carolina 27410 (336) 288-7180 December 2008 N.C. Lept. Of e14R DEC I R 2008 M.1510n•salem Regional off Ice 08-27-'09 09:01 FROM-DENR 3367714633 3367714633 T-216 P003/006 F-903 RESEARCh & ANA YTICAt LAbotmraRiES, INC. AnalyticailProcess Consultations I. ,,a„<,,,aaa,,�e rr 'a 7. .•�E��q.; •\y �- NHrnrH,,, Clie►►tical R►talysis for• Selected Pai-ameters acid Water- Santple Idettfifred ris High Pourt Regional HS {�t S & A E, fn Prajert #1584-08-051, collected 17 October 2008} [ Volatile Organics Quantituliorl MWI V. Semi -Volatile Organics Qttantitaliart t4IW-1 EPA Method 602 Limit EPA Method 625 UNA Limit Parameter m IL (me11-1 Parameter m IL 1ME W Benxerle 0-0010 $QL 4 Chloto 3-methylphenol 0.010 BQL Chldrobenzeae 0.0010 RQL 2-Chlaropltenol 0 010 8QL 1,3•Dithlorobenxene 0.0010 BQL 2,4-Drchloeophenol 0.010 BQL 1,4-Dichlomhenune 0.0010 BQL 2,4-Dlnuthylphenoi 0.010 BQL 1,2•Dlchlorobcnaeae 0.0010 BQL 2,4.Dlnnlrophenal 0.050 BQL Fthylbeuulse 0.0010 BQL 2-Me1lsy1•4,6•dinitropheno1 9050 BQL Toluene 0.0010 BQL 2-Xit101111en01 0-010 BQL Tonal Xylcao 0.0010 SQL 4-Nitlapherwl 0.050 BQL MTHE 0.0050 BQL penlachtorophenol 0.050 BQL Phenol ❑ 010 BQL Dilution Faclet I 2,4,6-Trichlnropheno 0.010 SQL Aeemaphlhene 0.010 BQL Atenaphthyle ne 0.010 BQL An(hracene 0-010 BQL • r [[ Method MADEP 98-1 YPH Quantitation MW-1 Benzidine 0.050 BQL 1 PArstrneter Limit Bento(a)awhracene 0-010 BQL m 1L m L) Benza(a)pyrcne 0-010 BQL k C5-C8 Aliphalics O.i00 BQL SCaza(b)fluoranthene 0010 BQL C9-C12 Aliphahcs 0.100 SQL Benso(8h1)pery1rne 0-010 BQI, C9•C 10 AminaIic9 0-100 BQL BellzEKk)nuorz,,a ,v 0.010 BQL Beozyl butyl phthalate 0.010 BQL �'. Dilution Faclor I 8is(2-ch1aroc(hoxy)methane 0010 BQL 111s(2-Chloroelhyt)ether 0-010 BQL Bis(2•ehlorois0propyl)elher 0010 BQL Bis(2-e(hyl-h"y1)ph1hala1c 0,010 BQL IIl. Method MADEP 98-1 EPH Quantitation MWA 4-Bronwphcuyl phenyl ether 0.010 BQL Parameter Limit 2-Chlorassaphshalane 0.010 BQL fmrlL) fm L 4-ChlomphcnylphenyIetlier 0-010 BQI, C9-Ct8 Alsphallcs 0-100 11QL cbrysene 0010 BQL CI9-C36 Aliphalits 0.100 BQL Dftiiu(a,h)anthracene O.OIO BQL C I l C22 Aromatics 0.100 BQL 1,2-Dieblornbumene 0.010 BQL 1,3-D1chlornbc4imne 0,010 BQL Dilution Fa of I 1,4•Dithlomhcnune 0-010 BQL 3,3-Dieblasobenzidinc 0020 BQI. Owhyl plsthaWe 0.010 BQI. Dimcilsyl phthalate 0.010 BQL IV, Tit's DI-N•Butyl phthalate 0.010 BQL 2,4-Dlnitrololuene 0-010 BQL NDPi 2,6•11)mitrololuenc 0010 BQL Di-N-Orly; phthalate 0.010 BQL 1,2-D1phenylhydra6ne 0.050 BQL Fluoranlhene 0.010 BQL Hexachlorobeazene 0,010 BQL Haxachlorobutadlcnc OOIO BQL HexaehlorocydopentadiePie 0.010 BQL f1ruchlornethane 0010 BQL Sample Number 629958 lndeno(1,2,3-td) pyrene 0.010 BQL Sample Dale 10/17/08 )sophorone U10 BQL Sample TitrlC (hrS) [IOU Naphlhalene 0-010 BQL Nitrobenzene 0.010 BQL N-NiuOwdinxlhylalmae 0.010 BQL N-nirraaadi-n-prapylami:se 0.010 BQL N-16imsodiphenylarniae 0.010 BQL BQL - Below Quauldation Limits Phenanthrelse 0 010 BOL asgrl. - milligrams per Lau -parts per mlltion (ppnt) Pyrwt 0.010 BQL MIA - NolAwllable 1,2,4=rrieh;orobeazeim OOW SQL NOPI - No Olhcs PeAt Identlfu4 2-Melhylraphtlla1ene 0.010 SQL DJulie a Faclat I Sample Number 629958 Satnu)e Date l0117109 Sample Titne f11rs) 1100 cv) m to r� w m d' m Q. tY0 cq c-I ti t` co M cyl M C(7 d' c-T t~ n to CY) M a 2 [x I FAG w N m tii M Gn m I M [\J t 00 m Client Name: Project Name: Site Location: S & ME, Inc. High Point Regional - #1584-08-05I RAL # 629958 Laboratory Name: Research & Analytical Laboratories, Inc NC Certification # (Lab) 34 Sample Matrix: Water j�D[ai`ttstiva:atAiTila9>tYticli' Method for Ranges: MADEP EPH Sample Identification MW-1 EPH Surrogate Standards Date Collected 10/17/09 Date Received 10/17/08 Aliphatic: COD Aromatic: o-terphenyl Hate Extracted 10/21/08 EP11 Fractionation Surrogates Date Analyzed 10/21/08 % Dry Sands NIA NIA NIA NIA NIA NIA N/A NIA NIA #1 2-Fluorobiphenyl Dilution Factor 1 #2 2-Bromonaphthalene Hydrocarbo knits of MDL RL Blank NIA NYA NIA NIA NIA NIA NIA NIA N/A a Ran es pleasure C4-cis » mg/L 0.063 0.100 BRL BRL Aliphatic C19 -C35 mgfL 0.031 0.100 BRL BRL Aliphatics Cll -C22 � mglL 0-009 0-100 BRL BRL Amtnatics Sample Surrogaw N/A NIA 40-140% 40-140% 40-140% 40-140% 40-140% 40-140°/a 40-140% 40-140% 40-140% 40-140% Accr taace Range Aliphatic Surrogate % NIA NIA 73 75 Recovery Aromatic Surrogate % Recover NIA NIA 59 66 Fractionation Surrogate NIA NIA 40.140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% Acceptance Range Fractionation Surrogate #1 % Recovery NIA NIA NIA NIA Fractionation Surrogate #2 NIA N/A NIA NIA % Recovery " Unadjusted value. Should exclude the concentration of any sarrogate(s), internal standards, and/or cmImtratioms of other ranges that elute within the specified =ge. MDL = Method' Detection Limit RL- Reporting Limit Blank = Laboratory Method Blank or Trip Blank whichever is higher (indicate type) EFH rev. 11/00 Were all perrormance/acceptable standards for required QAJQC procedures achieved? © Yes No - Details Attached Was blank correction applied as a significant modification of the method? 'yes © No Were any significant modifications to the $P13 method made? � No Yes - Details Attached M m m (c� m m m t9 a m c� [n ti m co M M (a r-I t� rn Cn M z i O w t%J m o) m to m i N l Co t9 VPH (Aliphatics/Aromatics) Laboratory Reporting Form OWN Client Name: S &VIE, Inc - Project Name. High Point Regional - #1584-08-051 Site Location: RAL # 529958 Laboratory Name: Research & Analytical Laboratories, Inc NC Certification # (Lal34 Sample Matrix: Water San,tp e Inf6rinad[lti and a.y tkAIR6Wts Method for Ranges: MADEP VPH Sample Identification MW-1 Collection Option VPH Surrogate Standards N/A NIA NIA NIA NIA NIA NIA NIA NIA (for soil)' Date Collected 10/17/08 Aliphatic: Ftuorobc=crc Date Received 10/17/08 Date Extracted NIA NIA NIA NIA NIA NIA NIA NIA N/A Aromatic: Fluorobemwe Date Analysed t0123/08 % Dry Solids NIA NIA NIA NIA NIA NIA NIA NIA NIA Marlon Factor ] Hydrocarbo units of MDL RL Blank NIA NIA NIA NIA NIA NIA NIA NIA NIA a Ran es Measure C5 - C8 - Miphatics - mgfL 0.052 0.100 BRL BRL C9 • C12 Aliphatics mg/L 0.018 0.100 BRL BRL C9 - CIO - Aromatics mgfL 0.009 0.100 BRL BRL Sample Surrogate Acceptance Range NIA NIA 70-130°/° 70-134°/° 70-130°%v 70130°!0 70-130°i° 70-130'/u 70.130°16 74-330°/° 70-130% 70130°/0 Aliphatic Surrogate'/o Recovery - FID NIA NIA Ito 103 .rvmatic Surrogate'/. recovery - PID NIA NIA 106 101 ' Option 1 = Established fell line on vial Option 2 = Sampling Device (indicate brand, e.g. EnCore) Option 3 = Field weight of soil "Unadjusted value, Should excludc the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range. MDL = Method Detection Limit RL = Reporting Lunit Blank - Laboratory Method Blank or Trip Blank whichever is higher (indicate type) VPH rev. 11100 Were all perforrnanceJacceptable standards for required QA/QC prodedures achieved? Were any significant modifications to the VPH method trade' FTYes a No - Details Attached IKI No a Yes - Details Attached RESEARCH & ANAtyTICA! WmATORIES f INC. Analytical / Process Consultations Phone (336) 996-2841 CHAIN OF CUSTODY RECORD WATER 1 WASTEWATER I MISC. 1 CDMPANY ` JOB NO_ J 504 - 0$ - 05 l v, a o x IV yb. d ti O '�;�0�&&W9 l y a 9r q a a c� ci r� a e�, X . s� F Q0 C7 9z Q' 4. 0`P 10 M� `� ry ti`� ti` �� �" �-• y V REQUESTED ANALYSIS STREET 3AOpRE55 -nib J.O PftOJEC CITY. STATE. Z)P 7 `-dum"IPYAQ � C- V14io SAMPLER NAME (PLEASE PRINT) CONTACT PHONE L.`l r � - g �-ER- 'J34- 2$- 180 SAMPLEIpSIGNA . •. .,.,.�� SANKus�"i'aLYjR PATE TIME r'C CI aaOPOW �iq sort[ N wi SIWPLE LOCATION 1 Lo. 19 1a$ 4 n ROO W mW-f x X L REiINQIfIS :ED �BY pA7Eli1FAE RECEIVED BY REMARKS: , ,( SAMPLE TEMPERATURE AT RECEIPT V �'' RELINOUISHED BY 6ATFffNE RECEIVED BY MATERIAL SAFETY DATA SHEET ❑xvgen BinChent (OBC-)® A'1SDS Ref. iWo„ F18-44-8 *MC flute Approved: IW13f2005 Revision ,No.: I This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200; the Canadas Workplace Hazardous Materials information System (WHMIS) and. the EC Directive, 2001159(F-C. 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT N)S 1NlL.-- GENERAL USF: MANUFACTURER 001` FMC CORPORATION Active Oxidants Division 1735 Market Street Philadelphia. PA 19103 (215) 299-50({} {General Informationy r; - - Oxygen H iaChcm (0BC)O - - — - For clie tnical oxidation and aerobic bioremcdiation, petroleum hydrocarbon remediation. creosote remediation and panially halogcn,sied hydrocarbon rernedimion. EMERGENCY TELEPHONE NUMBERS (3031595.9048 (Medical - U.S. - Call Collcct) For leak, fire. spill. or accident emergencies, call: (906) 424-9300 (CHEMTAEC • U.S.A. & Canada) 2. HAZARDS IDENTIFICATION EIMERGENCY OVERVIEW: • Odorle". off•u.hitc line granular solid (may have separation or noticeable two -lone appearance). • Oxidizer. • Contact with combustihlcs may cause lire. ■ Dtcampases in storage stnderconditions of moisture (wastdwaicr vapor) andlof excessive heat causing rcicasc of oxides of sulfur and oxygen that supports combustion. Dccomposiiion could form a high temperature melt- Sec Section 10 ("Siabiliiv and Reacti vity" y. ■ Deluge container with water at safe distnnce or its protected area, • May be severely irritating to the eyes. POTENTIAL HEALTH EFFECTS: Airborne dust may be irritating to eyes, nose, lungs. throat and skin upon contact. Exposure to high levels of dust may clusu difficulty in breathing in sensitive persons. No signil)cant long term inhalation hazard; irritation usually subsides alter exposure cease%. Nee 10"ho Dxygcn BioChent (08C)@ (F18-41-8) Date: 12/1212005 3. composrriO 1 I INFORMATION ON INGREDIENTS Clternicul'Nattie CaSN WL'YD EC Na. EC Class Proprietary lviixiurc None Not classified 4, FIRST AID MEASURES EYES: Immediately flush with ►►�atcr for at last 1s minutes, lifting ►he upper and lower eyelids intermittently. See a medical doctor or nphthrtl uiologist immediatcly. SKI -. Wash with plenty of snip and water. Get medical attention il' irritation occurs and persist~. INGESTION: Rinse mouth with outer. Dilute by giving 1 or. 2 glasses of water. Do l:ot induce vomiting. Never give anything by mouth to as uncansciaus person. See a medical doctor immediatcly, INHALAT10N: Remove tq Fresh air, If breaching diMeuIIy or disc omfortoccurs and persists, obtain medical attention. NOTES TO M EDICAL DOCTOR: Modest irritation is the only expected effect. No serious consequences ,See expected, except perhaps in the case of direct eye contact. Contaminated cxtemal surfaces should be flooded with water. and direct t:yccontact desci-vus ophthalmnloeic evaluation. I ingested, gastrointestinal irritation but not caustic burns ary to be expected; ditui ion with water indicated as maybe gnstric evacuation via cniesis or lavagc if large doses or severe irritation is evident. Demulcents should be helpful, No systemic effects are expected though human toxiciiy data is sparse. 5. FIRE FIGHTING MEASURES EXTINGI.IISH ING MEDIA: ❑Ougw w h plenty of water. FIRE 1 EXPLOS10N I3AZARDS: Product is non-coanbustible. Cinder fire conditions. may decompose and release oxygen fiat, which timy intemi fy ere. Prescnec of water aeccIcrites decomposition. hlixmures with polysulfidc polymers may ignite. Fl RE FIGHTI NG PROCE❑URES: Use flooding quantitias of water- Use water spray to krcp fire exposed containers cool. Do not uw carhop dioxide or other gas tilled hre exi1rig uishers; IItey wilt have no effect on deeompusi(ion. Wear full protective clothing and sett -contained breathing apparatus. Pale 2 of 10 Oxyecn BioChctn (0BC)@ (F18--3 -8) Date: 12112)2005 Pk FLAMMABLE LIMITS: Non-combustiblc SENSI T€ V IT TO IMPACT: Qxidizabie materials can be ignited by grinding and may become explosive. SENSITIVITY TO STATIC DISCHARGE: Noiavailable 6. ACCIDENTAL RELEASE MEASURES RELEASE NOTES: Confine and collect spill, put into an approved DOT container (do nos return to original con(ainer] and isolate for disposal, Isolated material should be monitored for signs of decomposilioo (fuming l smoking). If spilled material is -wet. dissolve with large quantities of water and dispose as a hazardous waste. Runoff to sewer may crcatc fire or explosion hazard (do not nosh powdered motto tl`isitb s wcr) DiTPY of u u3tvs sccordiag'to-the ]Tye thvd`oudined-in-Section 11-3; "Disposal — Considerations". 7. HANDLING AND STORAGE HANDLING: Avoid contact by using personal proicctivc equipment. Use respiratory protecdvc equipment when release of airborne dust is expected. If compounded with organics or combustible oft materists be sure to exeludc muisiure. Use clean plastic or siainless steel scoops nnly. STORAGE: Keep dry (reacts with moisiurc). Use first in. first out storage system. Store unopened in a cool, clean. dry place away from point sources of heat (e.g, steam pipes, radiant heaters, hot air vents or welding sparks). Keep cdntaincr Iighily closed when not in use. Avoid contamination of opened product. Avoid contact with red ueing'agenis: In cast of Fire or d remposi to i n (fuming 1 smoking) deluge with pienty of water to control decomposition. Fore storage. refer to NFPA Bulletin 430 on storage of liquid and solid oxidizing malcrials. COMMENTS: VENTILATION: Pravidc mechanical general andlor local exhaust ventilation to prevent release of dust into work environment. SpiII%shouId be collected into suitable containers to prevent dispersion into the air. if ventilation is inadequate or not available, use dust respirator and cyc protection, 8. EXPOSURE CONTROLS 1 PERSONAL PROTECTION EXPOSURE LIMITS Chemical \ante ACGIII OS1-1A Supplier Proprietary ingrediem 0,1 mglm) (TWA) Page 3 of 10 Oxygen BioChem;OBQ0 (F1844-1) Uatc: 1 J 1212005 Chemical Name ACCIFI OSFL-k -Ter Supplier Proprietary ingredient 5 myrn {TLVA) a mglm' (TWA)l (TWA] ENGINEERING CONTROLS: Pmvlde mechanical local exhaust ►•enrilation to prevent release of dust into the work area. if release is expected use respiratory protection. Remove contaminated Clothing immediately and wash before reuse. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Use cup type chemical goggles. Full face shield may be used. RESPIRATORY: Use approved dust respirttorwith I'ull face piece. - -PRO TECTI-V-E-C-60-T-H-I,NG:--Lon -sleeve shin; im ryinus'a rori ar-clzithhn . ---- - "� € Pe p � - -- - Rubber or neoprene foutwear- G LOVES: Rubber or neoprene gloves. Thoroughly wash the Outside of gloves with soap and water prior to removal. Inspect regularly I -or leaks. 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Odorless APPEARANCE: Off --white fnc granular solid AUTO IGiNITION TEi1-iPERATIJRE: Non-combustible BOILING POINT: No data available COEF!! IC[ENT OF 01 L I ll'ATER: Not available DEN;SiTY /WEIGIIT PER VOLUME: (Bulk) 60 1bslft' (lousc) EVAPORATION RITE: idol applicable (Butyl Acetate = 1) FLASH POINT: Not applicable NIELTING POINT: Decomposes an heating (About 275°C) OXIDIZING PROPERTIES: Oxidizer PERCFXT VOLATTLE: Nntapplicable PH, 1 1-3- 12.) @ 2S0Cl I hour (I - Q17c. shirty, solulion) SOLUBILITY IN M'ATER: ItZNir (insoluble @ 25°C); 73`k (solubility (LD 25'C) SPECIFIC GRAVITY: 2.6.2.92 VAPOR DENSITY- Not applicable ( Air = 1) VAPOR PRESSURE,: Not:ipplicable r� Page 4 of 10 a I . 0 SA— Oxygen BwChen} (OBQ0 (F 18-14-8) 10. STABILITY AND RE,LACTIVITY COND1T1ONS TO AVOID: STABILITY: POLYMERIZATION MOMPATIBI-L MATERIALS Date: 1 J i V?OD5 Heat (decomposes at 275°C), moisture, reducing agents. Grinding with organics. Stable (decomposition could occur when exposed to heat or moisture) Wil l not accm- Grind i ng iuixtures with organics (oxidizable materials can be ignited by grinding and may become explosive); heavy metals. Acids, alkalk. halidts (Iluoridcs, chlorides, bromides and iodidcs). combustible materials, most metals and heavy metals, oxidizable materials, other oxidizers. reducing agcrtts. rleancrs, and organic or cartion containing co}npounds. Contact with incompatible materials can resuh in a material decomposition or other uncontrolled reactions. Fl:t2ARl)OUS D1:COMPOSITEON. PRODUCTS: Oxygen that supports combustion and oxides of sulfur, nitrogen, and calcium hydroxide. COMMENTS: PRECAUTIONARY STATFMENT: Usu of persul fates in chemical reactions requires appropriate precautions and design considerations for pressure and thennal relief. Decomposing persulfales will evolve large volumes of gas and/or vapor, can :accelerate exponentially with heat generu6on, and create significant and hazardous pressures if contained and not properly controlled or mitigated. Use with alcohols in the presence of water has bccp'demgnstrAied to generate conditions that require rigorous adherence to process safety methods and standards to prevent escaIatinn to an unctnalrol led reaction. 11. TOXICOLOGICAL INFORMATION EYE EFFECTS: No Bala available far the mixture. Proprietary Component: Non -irritating (rabbit) Proprietary Component• Severely irrtaiing (on washcd); Minimally irritating (washed) SKIN EFFECT'S: lqo data available for the mixture. Fxpccled to be non -irritating (rabbit) ❑ERMAL LD-;o: , No data avail ahle for alte mixture. Proprietary Components: > 10 VAS (rat) ORAL Lip{It: No data available for the mixture. Proprietary Component. 895 niglkg (rat) Proprietary Component: 5 rAg (rat) f'agc i of lit Oxyger, BioChem {OBC,16 (F18.44.8) Date: 1 J12/2005 INHALATION LCSO: No data available for the mixture Proprietary Componem: 5.1 mO (rat) Proprietary Component: n 17 mg/1 [ 1 h) (rat) SENSITIZATION: No data available for the mixture. Proprietary Component; (%jn) May be wnsitiriag to allergic persons. (guinea pig) TARGET ORGANS: Eyes, slain, respiratorypassagcs ACUTE EFFECTS FROM OVEREXPOSURE: Modest irritaiion is the only expected effect, No serious consequences are expected. except perhaps in the case of direct eyc contact- Bust may be harmful and imtating to the eyes, nose, throat and lungs. May be harmful if swallowed. CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the mixture. Sensitive persons may develop dermatitk and asthma. One of the proprietary components was fed to groups of male and femnle rats at 0, 300 attd 3,000 ppni in the dirt for 13 wee"' . followed by 5,000 ppm or 5 weeks. MicSas—co pic examination ofiissuus iiiWEIe`d some-injury16 the gastratr�slinallra l 5l the - highesi dose (3,000 ppm) only. This effect is not unexpected for an oxidizer at high concentrations - CARCINOGENICITY: NI'l': Not listed IARC: Not listed OSHA: Not listed OTFFER: ACGihI: Not listed 12. ECOLOGICAL INFORMATION ECOTOXIC0LOGICAL INFORMATION: No data available for the mixture. Effect of low concentrations on aquatic life are tltld�.own. � r Proprietary Component Biuegil) sunfish. 96-hour LCS4 = 771 mglL (FMC Study I92-12501 Rainbow trout, 96-hour LC5a = 163 rriglL I FMC Study 192-12511 Dnphnin, 48-hour LCfo = 133 mg[L I>~h1C Study 192-12521 Grass shrimp, 96•hour LCsQ = 519 mg/L (FMC Study 192-12531 CH EM ICAL FATE IN FORM ATION: As indicated by chemical properties oxygen is released into the euviruntnent. Biodegradability does not apply to inorganic substances. Page 6 of 10 Oxygen 13ioChcm (OB.C)i9 (F18µ4-9) Dnlu: 1?1I712005 13. DISPOSAL. CONSIDERATIONS DISPOSAL METHOD. Dissolve in waicr to allow the release of oxygen and dispose via a treatment system in accordwicc with governmental agencies regulations. Contact appropriate regulatory agency prior to disposal. 14. TRANSPORT INFORMATION U.S. DEPARTMENT OF TRANSPORTATION (DOT) ------PROPER-SItIPPINC, M01E: — --- -Oxidizing solid; mo:s: (sodium persuifatc.— calcium peroxide) PRIiNiARY HAZARD CLASS IDIVISION, 5.1 (Oxidizer) UNINA N1I11BER: UN 1479 PACKING GROUP: 11 LABEL(S): 5.1 [Oxidiz(:r} PL.ACARD(S): 5.1 (Oxidizer) NIARKING(S): Oxidizing solid, n.o.s. (sodium persulfatc. calcium peroxide). UN1479 ADDITIONAL. INFORMATION: Hazardous Substance/RQ: Not -applicable 49 STCC Number: 4918733 This material is shipped in 55 lb. polyethylene pail with vented sercw-on lid (approx 6.5 gallon) INTERNATIONAL MARITIME DANGEROUS GOODS (MIDG) PROPER S1IIPPING NAll'IE: Oxidizing solid. n.o.s. (sodium persulfasc, calcium peroxide) INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) I INTERNATIONAL AIR TRANSPORT ASSOCIATION (XATA) PROPER SIIIITING NAME: ADDITIONAL INFORMATION: r Page 7 410 Oxidizing solid, tl.o.s. (sodium parsulfate, calcium peroxide) Combination packaging is recommended for uir transPon. ► 'f I Oxygen B•:or-1cm (OBCA (F18-k-i•8) Datc. 1 a 12/2005 OTHER I1'NFOMMATION: Place splllcd prodtici in suitableconiainer and wash residue with pieniy of water. See Section b (Accidental Rcicasc Measures) above for additional htstruciions. 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPER FUND AsMENDNIENTS AND REAUTIIORIZATiOtN ACT) SECTION 311 IIAZATID CATEGORIES (40 CFR 370): Fire Hazard, Immediate (Acute) Health Hazard SE t TION 312 "{ IRESHOLD PLANN_LIVS—ANT Y..(���a7 ), The Threshold Planting Quantity (TPQ) far this product, if treated as a mixture, is 10.000 Ibs; however, this product contains the following ingredients with a TPQ of less than 10.000 lbs.: None SECT101 30 REPORTABLE INGREDi EN rS (40 CFR 372): Not listed CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COAIPENSATIO` AND LIABILITYACT) CERCLA DES] GNAT) ON & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4): Proprietary component: [enlisted, RQ = 100 lbs., Ignitsbility TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA CNTVE,NTORY STATus (40 CFR 710): Listed (components) RESOURCE CONSERVATION ANIy RECOVERY ACT {RCRA) RCRA II ENT1FICATION Of I1AZARDOUS WASTE (40 CFR 261): Waste Number. D00} CANADA I%fH;NIIS (WORKPLACE IRDOUS MATERIALS INFORMATION SYSTEM): Chemical Nanic: Proprietary Component Product IdeolllWation Number; 1505 Hazard Classification I Division; Class C (Oxidizer). Class D. Div, ?, SubOiv. B. (Toxic) Ingredient Disclosure List: Listed Chemical Name: Proprietary Component product ldcnti0cadon Number: 1457 , Hazard Classification I Division: Class D, Div 3, Subdiv. B, Clasti C (Oxidirrr) Ingredient Disclosure List- Listed Pagc 8 of 10 P" oph Oxygen BWltcIn (0BC)G IFIS-4-'�I INTERNATIONAL LISTINGS Proprietary Compotscrlt Australia WCS); Listed China: Listed Japan (ENCS): (1)-t 131 Korea: KE-12369 Philippines (PICCS): Listcd Proprietary ComporlLnt Australia (AICS): Listed China: Listed Japan [ENCS): (I)-181 }Cana: K E-04518 Philippines IMCCSI; Listed Proprietary Component Australia (AICS): Listed Japan (ENCS): (1)-190 Korea- KE-04597 Philippines (PICCS): Listed Date: 12/ 121-1005 HAZARD, RISk AND SAFETY PHRASE DESCRIPTIONS: EC Symbols: (Not Classified as hazardnus) EC Risk Phases: (Not classified as hazardous) EC Safely Phrases: (Not classiricd as hazardous) 16. OTHER INFORMATION llnrls �Hcalth _Flanunabilit _ _ 4 J Phvsical Hazard 1 Personal Protection (PPC—j—_ Protection = ] (.Safety gaggles, glovers, apron & combination dust & vapor respirator) HMIS = Hazardous NIUT rials Identification System Degree of Hazard Codc: 4 = Severe 3 = Serious Paoc 9 of In Oxygen 13ioChc m (08010 (F18-44.9) Date: 12MMIX)s 06 2 = Modcrate 1 = Slight U = Minimal r\FPA Health 7 + Flammability B Reactivity 1 Special ❑x SPECIAL. = ❑X (Oxidizer) NFPA = National Fire Protection Association Degree of Hazard Code- 4 = Extreme - - - - - ---� -High --- - — — - - -- 2 = Moderate I = Slight Q = Insignificant REVISION SUNIN1 ARY: New MSDS. OW FMC Logo - FMC Corporation Trademark Oxygen BioChem (08C) -Trademark of Redtrx Teen. LLC Q 2005 FMC Corporation. Ali Rights Reserved. FMC Corpomrian believes that the information and recommesidations cotturincd herein (including daw and statements) are accurate as of the date hcrcof, NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABiLiTY, OR NY OTHER 1VARRANTY. EhPRE5SED OR IMPLIED, IS MADE CON CFRNING THE INFORMATION PROVIDED HEREIN, The information provided herein relAts Only to the specific produc: designated and may not he applicable where such product is used in combinallan with any other materials or in any process. It is a violation of Federal law to USC this product in a manner inconsistent with its labeling. Further, since the conditions and methods or use are hcyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as to any results obtained or prising from any use of tirc product or reliance on such information_ Page 10 of I a �•%.• x' ;�■fit■ * ■ } ��:. - *! ` •`.. _ '! REMEDIATIaN' y ..; AREA *.� l i 1b'� ,� "Jj * •fir �! ! t � � *y } F � •�a` saj- 1 �--_ I /• ! Y•. « �. _ + ' i�.r •_'fir �.. �7; _ isvi WT g ' _ +v,. GRAPHIC SCALE ' e� ,1 L_ S+ .-� Ct cif —� !J! I SCALE 1" = OW Y.c w REFERENCE: KERNERSVILLE, NC. GUADRANGLE. 7 5•MINUTE SERIES USGS TOPOGRAPHIC MAP, DATED 19699REVISE0 1994) SCALE: AS SHOWN USGS FIGURE NO - DATE: oCToBER 2008*S&ME TOPOGRAPHIC MAP DRAWN BY: RDM 133 S. MAIN STREET PROJECT NO: WWW.SMEINC.COM KERNERSVILLE, NORTH CAROLINA 1584-08-051 NATURAL \ GAS LINE PROPOSED INJECTION WELL FIELD \ AND APPROXIMATE HORIZONTAL EXTENT OF CONTAMINATED SOIL \~ ~ GAS METER h+IYIF1lSB-e ` FORMER f'r \ EXCAVATION / \ LIMITS �/ P \ FORMER TANK \ LOCATION �¢ O+,�Q'� r u KEY SOIL PROBE AND MONITORING WELL LOCATION GRAPHIC SCALE 30 15 6 30 SCALE: V = 30' SCALE: AS SHOWN FIGURE NO, 3 DOTE: APRIL 2009 SITE MAP DRA'DRAWNsr #S&MERDM 133 S. MAIN STREET PROJECT NO: WWW.SMEINC.COM KERNERSVILLE, NORTH CAROLINA 1584-0$-d51 ' C 1PLETION REPORT OF WEl Ito. MW-1 Sheet 1 of i PROJECT. Farmer High Point Health Care Ventures PROJECT NO 1584-08-051 WATER LEVEL: 28.6 PROJECT LOCATION Kernersville, North Carolina DRILLING CONTRACTOR: B. grown LATITUDE: DRILLING METHOD: 3 '/." H.S.A. LONGITUDE DATE DRILLED: 10115108 TOP OF CASING ELEVATION NOTES: DATUM: LOGGED By L. Ennis STRATA WELL DETAILS w � W J W WELL CONSTRUCTION DETAILS PROTECTIVE CASING DESCRIPTION m cn F LU n 0 0.00 GS Diameter - Type: Interval: Asphalt 1 0.50 Fill RISER CASING $ Diameter- 2" Type: PVC Interval: 0.2-20 10 GROUT Type: Neat Cement Grout Interval: 0.5-14 Residuum. Tan Gray Sandy SILT; Petroleum Odor from 10' to 12' SEAL Residuum: Tan White Silty Medium to fine SAND; Feldspathic; Structures i5 14.00 Type: Bentonite interval, 14-16 16.00 FILTERPACK Type: #2 Sand Interval: 16-35 20 SCREEN Diameter, 2" Type: PVC Interval: 20-35 25 LEGEND l FILTER PACK _ ■ BENTONiTE TOC TOP OF CASING I 30 GS GROUND SURFACE ® CEMENT GROUT BS BENTONITE SEAL ® CUTTINGS / 13ACKFILL FP FILTER PACK I Uncharacterized TSC TOP OF SCREEN 1 STATIC WATER LEVEL SSC BOTTOM OF SCREEN TD TOTAL DEPTH 35.00 CG CEMENT GROUT F 1 COMPLETION REPORT OF WELL No. MW-1 S&ME y ENGINEERING - TESTING Sheei 1 of 1 ENIIRONMENTAf_ SERVICES North Carolina Beverly Eaves Perdue Govemor James Morton High Point Regional Health Systems P.Q. Box HP-5 High Point, NC 27261 AAA NCDE14R Department of Environment and Natural Resources Division of Water Quality Coleen H. Sullins Director October 17, 2011 Ref: Renewal of Injection Permit W10400110 Dynamic Capital Mortgage, Inc. Office Building Kernersville, Forsyth County, North Carolina Dear Mr. Morton: Dee Freeman Secretary In accordance with the application received on August 29. 2011. we are forwarding herewith renewed permit number W10400110. This permit is to inject Oxygen BioChem to chemically oxidize groundwater contaminated with #2 heating oil at the site referenced above. It is our understanding that the injection portion of this operation has been completed, and that post -injection monitoring is still in progress. This permit shall be effective from the date of issuance until August 31, 2012, and shall be subject to the conditions and limitations stated therein. including the requirement to submit a final project evaluation as stated in PART VE — MONITORING AND REPORTING REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at 919-715-6162 or david.goodrich Lamcdenngov if you have any questions about your permit. Best Regards, David Goodrich Hydrogeologist cc; Sherri Knight, Winston-Salem Regional Office Lyndal Butler- S&ME, Inc.. 3718 Old Battleground Road. Greensboro, NC 27410 Harry Boles. 115 S_ Main Street. Kernersville, NC 27285 WI0400110 Permit File AQUIFER PROTECTION SECTION 1636 Mail 5erv+cb, Cenmr. Rale:nri. North Camllna 27699-163f•. Lmahm. 2728 Capaal Boulevard. Ra�e;gr.. NarM Caralina 27&9 0n: °none 919-733-3221 1 FAY 1 915-1115•05K. FAX 2: 91 5-715-6W Cusromfr.- 7erVrc .ti"-62`a•"o74i NorthCarolina Intemer www.ngwalegualiry.orn ��LI�t(1'aAif �uu�i ��pnnunr 4T:if:Ti311v� nCilCli• C^,ItMyE �' a NCDEN North Carolina Department of Environment and Natura Division of Water Quality Beverly Eaves Perdue Coleen H. Sul ins uovemor Director September 1, 2011 James Morton — Director High Point Regional Health Systems PC Box HP-5 High Point, NC 27261 Dear Mr. Morton: Resources Dee Freeman Secretary Subject: Acknowledgement of Application No. WI0400110 Dynamic Capital Mortgage, Inc Injection In situ Groundwater Remediation Well (51) System Forsyth County The Aquifer Protection Section acknowledges receipt of your permit application and supporting documentation received on August 29, 2011. Your application package has been assigned the number listed above, and the primary reviewer is David Goodrich. Central and Winston-Salem Regional Office staff will perform a detailed review of the provided application, and may contact you with a request for additional information. To ensure maximum efficiency in processing permit applications. the Aquifer Protection Section requests your assistance in providing a timely and complete response to any additional information requests. Please note that processing standard review permit applications may take as long as 60 to 90 days after receipt of a complete application. If you have any questions. please contact David Goodrich at (919) 715-6162 or david.goodrich(ancdenr.gov. Sincerely. ,for Debra J. Watts Groundwater Protection Unit Supervisor cc: Winston-Salem Regional Office, Aquifer Protection Section Lynda[ Butler — S&ME (3718 Old Battleground Road, Greensboro.NC 27410) Harry Boles - 115 S. Main Street, Kernersville, NC 27285 Permit File W10400110 AQL1iFEP PROTECTION SF TION 1En Mail Sempe tenter, Ralegri, Noah Carolina 276%-1636 Lonitun 2728 Lavlal Boulevard, Raleigh. North Carolina 27M4 "none 996.7Y,-3229' F41 919'15-D589 FAX2?19-71f+ Ng Customer Service'-877-67av74E +nsere, www ri ateraualnv.ora One Ivor hCarohrl -• ���. : �nus;�rnr� rn•r �ari�= �G�����mpavr: ORIGINAL PERMIT APPLICATION XXXI WDGN North Carolina Department of Environment and Natural Resources Division of Water Quality Bever#y waves Perdue Coieen H. vuiiins Governor Director August 28, 2009 James Morton High Point Regional Health Systems P.Q. Box HP-3 High Point, NC 27261 Ref: Issuance of Injection Permit W10400110 Dynamic Capital Mortgage, Inc. Office Building Kernersville. Forsyth County. North Carolina Dear Mr. Morton: Dee Freeman Secretary In accordance with the application received on May 28. 2009, we are forwarding permit number W10400110. This permit is to inject Oxygen B1oChem to chemically oxidize groundwater contaminated with #2 heating oil at the site referenced above. This permit shall be effective from the date of issuance until August 31, 2011, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII — MONITORING AND REPORTING REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 49 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the iniection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date:. Please contact me at 919- 715-6164 or if you have any questions about your permit. cc: Sherri knight_ Winston-Salem Regional Office Lyndai Buticr. S&ME. Inc. WI0400110 Permit File AW FER ARM ECTION SEC 71ON 1536 Mail Seiwce Seller. Rbleigh. North Carolina 27699•1634 Locallbri 7728 i..aolral Boulevam, Ra"r,,, Nort. Carom,-eW. Phone 91~-'M-MI � FAk. 1 5J4-715-DSBE, FA; '_ 91E-715-00 CasEornerSwm. 1.877.623-6748 lnlerrW ZW.ncwatemualitv.:)rr: 4� f-qual-,Vpmmiy ' AMr-mamo-;co- wmnlo w Best Regards. Thomas Slusser, L.G, Program Manager Underground Injection Control Program On: '_ti orthCaro:ITILk �A'ldturally Atl7k Mra NCDEN North Carolina Department of Environment and Natural Resources Division of Water Quality_ Beverly Eaves Perdue Golden H. Sullins Governor Director June 1.2009 .lames Morton. Director High Point Regional Health Systems P.O. Box HP-5 High Point. NC 27261 Subject: Acknowledgement of Application No. WI0400110 Dynamic Capital Mortgage. Inc. Injection In situ CGroundwater Remediation Well (5I) Forsyth Dear Mr. Morton: Dee Freeman Secretary The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on May 2 8 - 2009. This application package has been assigned the number listed above and will be reviewed by Thomas Slusser. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications. the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below. must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions. please contact Thomas Slusser at 919-715-6164. or via e-mail at thomas.slusser@. nedenr.gov. If the reviewer is unavailable, you may leave a message. and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart. go to http:11l12o.enr.state.nc-us/documents/�dwrI or2chart-ndf. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAIONG INQUIRIES ON THIS PROJECT. Sincer I . L� for Debra t-tts Supervisor cc Winston-Salem Regional Office, Aquifer Protection Section Lynda] Butler (Project Manager. S&ME, Inc.. 3718 Old Battleground Rd.. Greensboro, NC 27410) Permit Application File WI0400110 AOUIFER PROTECTION 5E; 10N 1636 Mail Service Center, Ralegh. North Carolina 27699-1636 I-ocatior. 2728 Capital $ou*vard. Raleigh. North Carotins 2750,1 Phone- 919-733-32211 FAX 1 919-715-0588; FAY, 2 915415.6048 Customer Service 1.87?-623-6748 intemet www.nrwateerqual4V.orG O NorthCarolina Ar Eaual OopAiunit•:. Athrmallve hCnun Ernviwer Goodrich, David From: Wang, Shuying Sent: Thursday, October 13, 2011 3:12 PM To: Goodrich, David Subject: RE: GW-1 Well Construction Farms for Permit W10400110 i just checked the file, but did not find any. So you may have to ask the permittee/consultant. Thanks! Shuying From: Goodrich, David Sent: Thursday, October 13, 2011 1:30 PM To: Wang, Shuying Subject: GW-1 Well Construction Forms for Permit W10400110 Shuying, We are issuing the permit extension for the High Point Regional Health Systems injection permit. A review of our files has shown that we evidently did not receive any GW-1 well construction forms for the six injection wells at that facility. Do you have copies of the completed forms that you could send to us, or should we contact the permittee / consultant for them? Thank you. David Goodrich L�,,4 I r,,f/" S t I'6- r� l I `1 -e c f 1 1 h � U r/� ei, � U �+�<j 4. �L C Gf YIj �t � � J 0 c� } -t v-4 f f r [4 / " �- t!� . f7 j' Imp 1 cJ r I AQUIFER PROTECTION SECTION --- GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT Date: September 21, 2011 Permittee(s):_ High Point Regional Health Systems Permit No.: W10400110 To: APS Central Office County: Fars Central Office Reviewer: D. Goodrich Project Name: Dynamic Capital Mortgage, Inc Regional Login No: 1. GENERAL INFORMATION 1. This application is [cheek all that apply]: ❑ SFR Waste Irrigation System ® UIC We]l(s) ❑ New ® Renewal ❑ Minor Modification ❑ Major Modification ❑ Surface Irrigation ❑ Reuse ❑ Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment 6 included ❑ 503 regulated ❑ 503 exempt ❑ Distribution of Residuals ❑ Surface Disposal ❑ Closed -loop Groundwater Remediation ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? ❑ Yes or ® No. a. Date of site visit: b. Person contacted and contact information: c. Site visit conducted by: d. Inspection Report Attached: ❑ Yes or ❑ No. 2. Is the following information entered into the BIMS record for this application correct? � ® Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. For SFR Treatment Facilities: a. Location: b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: Method Used (GPS, GoogleTM, etc.); e. Regulated Activities 1 Type of Wastes (e.g., subdivision, food processing, municipal wastewater): For UIC Injection Sites: (If multiple sites either indicate which sites the information applies to, copy and paste a new section into the document for each site, or attach additional pates for each site a. Location(s): b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: Method Used (GPS, GoogleTM, etc.); RECEIVED I DENR r DVQ Aquifer Prolertion SeMon OCT 10 2011 APS-GPU Regional Staff Report (Sept 09) Page 1 of 6 Pages AQUIFER PROTECTION SECTION - GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT IV, INJECTION WELL PEIfMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description of Well(s) and Facilities — New, Renewal, and Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QM/5QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (512 Non -Discharge") ❑ Other (Specify: 2. Does system use same well for water source and injection? ❑ Yes ❑ No 3. Are there any potential pollution sources that may affect injection? ❑ Yes ❑ No What is/are the pollution source(s)? . What is the distance of the injection well(s) from the pollution source(s)7 ft. 4. What is the minimum distance of proposed injection wells from the property boundary? 5. Quality of drainage at site: ❑ Good ❑ Adequate ❑ Poor 6. Flooding potential of site: ❑ Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ❑ Yes ❑ No. Attach map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater monitoring program: S. Does the map presented represent the actual site (property lines, wells, surface drainage)? ❑ Yes or ❑ No, If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow. Injection Well Permit Renewal and Modification Only: 1. For heat pump systems, are there any abnormalities in heat pump or injection well operation (e.g. turbid water, failure to assimilate injected fluid, poor heating/cooling)? ❑ Yes ❑ No. If yes, explain: 2. For closed -loop heat pump systems, has system lost pressure or required make-up fluid since permit issuance or last inspection? ❑ Yes ❑ No. If yes, explain: 3. For renewal or modification of groundwater remediation permits (of any type), will continued/additional/modified injections have an adverse impact on migration of the plume or management of the contamination incident? ❑ Yes ❑ No. If yes, explain: APS-GPU Regional Staff Report (Sept 04) Page 4 of 6 Pages AQUIFER PROTECTION SECTION -- GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT 4. Drilling Contractor: Name: Address: NC Certification number: 5. Complete and attach NEW Injection Facility Inspection Report, if applicable V EIVALUATIONAND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the Application: Since this renew request is only for havingthe expiration date, of the existing permit extended for one year, from August 31, 2011 to August 31, 2012 to collect more data to evaluate the effectiveness, and in addition, the injection activities have been completed, WSRD did not conduct a site visit to verify site conditions or compliance status and has no objection to renew the permit. 2. Attach new Injection Facility Inspection Form, if applicable 3. Do you foresee any problems with issuance/renewal of this permit'' ❑ Yes ® No. If yes, please explain briefly. 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: Condition Reason b. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason APS-GPU Regional Staff Report (Sept 09) Page 5 of 6 Pages AQUIFER PROTECTION SECTION — GROUNDWATER PROTECTION UNIT REGIONAL STAFF REPORT 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft pen -nit by regional office; ❑ Issue upon receipt of needed additional information: Issue; ❑ Deny. If deny, please state reasons: 8. Signature of report Preparer(s): hlgnature of AY7 regional supemisor: Date: V1. ADDITIONAL INFORMATIONAND SITE MAP (Sketch of site showing house and waste irrigation system, spray or drip field, location of weli(sJ, and/or other relevant information- SHOW NORTHARRO99 APS-GPU Regional Staff Report (Sept 09) Page 6 of Pages September 2, 2011 Renewal of Injection Permit W10400110 High Point Regional Health Systems Dynamic Capital Mortgage, Inc. Office Building Note of Clarification to Sherri Knight from David Goodrich: I contacted Lydal Butler of S&ME ((336)-288-7180) to clarify exactly what was being asked for. Evidently, they want to extend the expiration date of the existing permit from August 31, 2011 to August 31, 2012 to allow them mare time. The injection activities at this site have been completed, but they need to continue monitoring to confirm its effectiveness. Please have your staff review this from the standpoint of extending the permit expiration date. AQUIFER PROTECTION SECTION APPLICATION REVIEW REQUEST FORM Date: August 30, 2011 To: ❑ Landon Davidson, ARO-APS ❑ Art Barnhardt, FRO-APS ❑ Andrew Pitner, MRO-APS ❑ Jay Zimmerman, RRO-APS From: David Goodrich , Land Application Unit Telephone; 919 715-6162 E-Mail. david. goodrich&cdenr. eov A. Permit Number: W I04001 10 B. Owner: Harry Boles ❑ David May, WaRO-APS ❑ Charlie Stehman, WiRO-APS X Sherri Knight, WSRO-APS Fax. (919) 715-6048 C. Facility/Operation: Dynamic Ca ital Mortgage, Inc. ❑ Proposed X Existing X Facility X Operation D. Application: 1. Permit 7: pe: ❑ Animal ❑ Surface Irrigation ❑ Reuse ❑ H-R Infiltration ❑ Recycle ❑ VE Lagoon X GW Remediation (ND)SI Injection ❑ UIC - (5A7) open loop geothermal For Residuals: ❑ Land App. ❑ D&M ❑ Surface Disposal ❑ 503 ❑ 503 Exempt ❑ Animal 2. Project Type: ❑ New ❑ Major Mod. ❑ Minor Mod. X Renewal ❑ Renewal wl Mod. E. Comments/Other Information: ❑ I would like to accompany you on a site visit. Attached, you will find all information submitted in support of the above -referenced application for your review, comment, and/or action. Within 30 calendar days, please take the following actions: X Return a. Completed APSARR Form. - Please comment ❑ Attach Well Construction Data Sheet. ❑ Attach Attachment B for Certification by the LAPCU. ❑ Issue an Attachment B Certification from the RO.* * Remember that you will be responsible for coordinating site visits and reviews, as well as additional information requests with other RO-APS representatives in order to prepare a complete Attachment B for certification. Refer to the RPP SOP for additional detail. When you receive this request form, please write your name and dates in the spaces below, make a copy of this sheet, and return it to the appropriate Central Office -Aquifer Protection Section contact person listed above. RO-APS Reviewer: Date: FORM: APSARR 07/06 Page 1 of I Permit Number W10400110 Program Category Ground Water Permit Type Injection In situ Groundwater Remediation Well (51) Primary Reviewer david.goodrich Coastal SW Rule Permitted Flow Facility Facility Name Dynamic Capital Mortgage, Inc. Location Address 133 S Main St Kernersville NC 27285 Owner Central Files: APS 5wp 09/01111 Permit Tracking Slip Status Project Type In review Renewal Version Permit Classification Individual Permit Contact Affiliation Lyndal Butler Manager Project 3718 Old Battleground Rd Greensboro NC 27410 MajorlMinor Region Minor Winston-Salem County Forsyth Facility Contact Affiliation Owner Name Owner Type Individual Harry Boles Owner Affiliation Harry Boles 115 S Main St Kernersville NC 27285 DateslEvents Scheduled Ong Issue App Received Draft Initiated Issuance public Notice Issue Effective Expiration 08/27/09 08/29/11 Reaulated Activities Requested/Received Events Groundwater remediatlon RO staff report received RO staff report requested ❑utfall I:'. _ Waterbody Name Stream index Number Current Class Subbasin ORIGINAL PERMIT APPLICATION AQUIFER PROTECTION REGIONAL STAFF REPORT Date: 06/17/2009 County: Forsyth To: A uifer Protection Central Off ace Permittee: Hieh Point Regional Health -Systems Central Office Reviewer: Thomas Slusser Project Name: Dynamic Capital Moq age Regional Login No: NA Application No.: W10400110 L GENERAL INFORMATION 1. This application is (check an that apply): ® New ❑ Renewal ❑ Minor Modification ❑ Major Modification Surface Irrigation ❑ Reuse ❑ Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment B included ❑ 503 regulated ❑ 503 exempt ❑ Distribution of Residuals ❑ Surface Disposal ❑ Closed -loop Groundwater Remediation ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? ❑ Yes or ❑ No. a. Date of site visit: None b. Person contacted and contact information: NA c. Site visit conducted by: NA d. Inspection Report Attached: ❑ Yes or ® No. 2. Is the following information entered into the BIMS record for this application correct? ® Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. For Treatment Facilities: NA For Disposal_ and Injection Sites: NA IL NEW AND MAJOR MODIFICA TIONAPPLICA TIONS (this section not needed for renewals or minor modifications, skip to next section) Description Of Waste[S] And Facilities 1, Please attach completed rating sheet. Facility Classification: NE 2. Are the new treatment facilities adequate for the type of waste and disposal system? ❑ Yes ❑ No ® NIA. If no, please explain: 3. Are the new site conditions (soils, topography, depth to water table, etc) consistent with what was reported by the soil scientist and/or Professional Engineer? ® Yes ❑ No ❑ NIA. If no, please explain: 4. Does the application (maps, plans, etc.) represent the actual site (property lines, wells, surface drainage)? Yes ❑ No ❑ N/A. If no, please explain: 5. Is the proposed residuals management plan adequate and/or acceptable to the Division. ❑ Yes ❑ No NIA, If no, please explain: wl04001 ta_APSSRR AQUIFER PROTECTION REGIONAL STAFF REPORT 6. Are the proposed application rates for new sites (hydraulic or nutrient) acceptable? ® Yes ❑ No ❑ NIA. If no, please explain: 7. Are the new treatment facilities or any new disposal sites located in a I00-year floodplain? ❑ Yes ® No ❑ NIA. If yes, please attach a map showing areas of 100-year floodplain and please explain and recommend any mitigative measures/special conditions in Part IV: NA 8. Are there any buffer conflicts (new treatment facilities or new disposal sites)? ❑ Yes or ® No. If yes, please attach a map showing conflict areas or attach any new maps you have received from the applicant to be incorporated into the permit: NA g. Is proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ® Yes ❑ No ❑ N/A. Attach map of existing monitoring well network if applicable. Indicate the review and compliance boundaries, If No, explain and recommend any changes to the groundwater monitoring program: NA 10. For residuals, will seasonal or other restrictions be required? ❑ Yes ❑ No ® N/A If yes, attach list of sites with restrictions (Certification B?) III. RENEWAL AND MODIFICATIONAPPLICATIONS (use previous section for new or maiar modifscation s stems NA !V. INJECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description Of Well(S) And Facilities — New, Renewal, And Modification 1. Type of injection system: ❑ Heating/cooling water return flow (SA7) ❑ Closed -loop heat pump system (5QM/5QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (5U Non -Discharge") ❑ Other (Specify: Z. Does system use same well for water source and injection? ❑ Yes ® No 3. Are there any potential pollution sources that may affect injection? ❑ Yes ® No What istare the pollution source(s)? NA. What is the distance of the infection well(s) from the pollution sources ? NA ft. 4. What is the minimum distance of proposed injection wells from the property boundary? —30ftE &---44ftWest 5. Quality of drainage at site: ❑ Good ❑ Adequate ❑ Poor 6. Flooding potential of site: ❑ Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ❑ Yes ❑ No. Attach WI0400110 APSSRR 2 AQUIFER PROTECTION REGIONAL STAFF REPORT map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater monitoring program: 8, Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow, Iniection Well Permit Renewal And Modification Only - NA V. EVAL UATIONAND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the application.: 2. Attach Well Construction Data Sheet - if needed information is available 3. Do you foresee any problems with issuance/renewal of this permit? ❑ Yes ® No. If yes, please explain briefly. 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason None NA 5. List specific Permit conditions that you recommend to be removed from the hermit when issued. Make sure that you provide a reason for each condition: Condition Reason None NA 6. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason None NA 7. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; ❑ Issue upon receipt of needed additional information; Issue; ❑ Deny. If deny, please state reasons: T 8. Signature of report preparer(s): Signature of APS regional supervisor: Date: r7 — ' u r ADDITIONAL REGIONAL STAFF REVIEW ITEMS W104001 l o_APSSRR 3 North Carolina Department of Health and Human Services Division of Public Health — Epidemiology Section Occupational and Environmental Epidemiology Branch 1912 Mail Service Center • Raleigh, North Carolina 27699-1912 Telephone:919-707-5900 Fax: 919-870-4807 hEchael F. Easley, Governor Leah Devlin, DDS, MPFi Dempsey Benton, Secretary State Health Director A��l�CElVEp r aENR 1 August 25, 2008 pw R �nnr�r��rZ�r O �Fcrom MEMORANDUM AUG 2 7 2008 To: Qu Qi — UIC Program Aquifer Protection System Division of Water Quality Department of Environment and Natural Resources From: Sandy Mort Ai-- Epidemiology Section Division of Public Health Department of Health and Human Services Subject: Health Risk Assessment Use of calcium peroxide or sodium hydroxide as activator for groundwaterlsoil remediation with sodium persulfate The following information is provided in response to Aquifer Protection Section's (APS) request for a health risk evaluation regarding the use of sodium persulfate with calcium peroxide or sodium hydroxide as activators for groundwater or soil remediation. These chemicals are proposed for use at a Duracell battery manufacturing site contaminated with chlorinated hydrocarbons, petroleum hydrocarbons, acetone, and carbon tetrachloride. This review is provided as supplemental information to that provided to APS in September 2003 by DPH regarding the use of hydrogen peroxide and iron-EDTA activators with sodium persulfate. The information provided to DPH indicates that calcium peroxide will be used at a proportion of 20% calcium peroxide and 80% sodium persulfate. This mixture is diluted to 30%, resulting in approximately 6% calcium peroxide and 24% sodium persulfate in 70% water. The information also states that sodium hydroxide will be used at 1 to 5% with 30% sodium persulfate. 1 Nord/ Cora Ii"a Pu61re Hea1W �i µyrkpn@ ra. / I.r atth—a-d SGfe• North Cwa6n/ Nerywl,rrc Ere+W�Y kw.-004 Location: 5505 Six Forks U, ?"d Floor, Room 1-'-DI *Raleigh. NC27609 A n Eq*dl Ohxauouty E*o)er Page 2 of9 NC DPH recommends that ail persons that will come into contact with the above chemicals review the MSDS and other appropriate health and safety documents and have undergone appropriate health and safety training. NC DPH also recommends that transport of these chemicals off site be controlled to prevent potential human or ecological impacts. Access to the area of application should be limited to workers applying the product. In order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. SODIUM PERSULFATE HEALTH RISK INFORMATION: Formula: NaZS203 CASH: 7775-27-1 Synonyms: Sodium peroxydisulfate, Sodium persulfate Classification: strong oxidant Sodium persulfate is a strong oxidant and reacts with combustible and reducing materials. Sodium persulfate decomposes on heating producing toxic and corrosive fumes including sulfur oxides. It reacts violently with powdered metals and strong bases. In solution in water it is a weak acid. Sodium persulfate becomes unstable when exposed to heat, moisture and/or contamination. It is incompatible with acids, alkalis, halides (fluorides, chlorides, bromides and iodides), combustible materials, most metals and heavy metals, oxidizable materials, other oxidizers, reducing agents, cleaners, and organic or carbon containing compounds. Oxidizing chemicals, including sodium persulfate, should not be stored or directly mixed with combustible material (such as fuels, papers or solvents) or reducing agents (such as metals or sulfites). Contact with incompatible materials can result in a material decomposition or other uncontrolled reactions. Oxidizing chemicals may react energetically with combustible materials or reducing agents and also release oxygen and heat during decomposition that could help support a fire. Some oxidizing agents are incompatible with one another. Decomposing persulfates will evolve large volumes of gas and/or vapor, can accelerate exponentially with heat generation, and create significant and hazardous pressures if contained and not properly controlled or mitigated. Use with alcohols in the presence of water has been demonstrated to generate conditions that require rigorous adherence to process safety methods and standards to prevent escalation to an uncontrolled reaction. Potential health effects: The primary route of toxicity is through direct inhalation of airborne dust or mist, or direct contact. Airborne persulfate dust may be irritating to eyes, nose, lungs, throat and skin upon contact. Dust dispersion should be controlled. Sodium persulfate in identified as a strong oxidizer and an irritant. Inhalation of dust may cause asthma -like reactions. Acute (short -terns) health effects that may occur immediately or shortly after exposure include severe skin and eye irritation and burns. Breathing sodium persulfate can irritate the nose, throat and lungs, causing coughing, wheezing and/or shortness of breath. Long-term (chronic) or repeated exposure may cause a skin allergy or dermatitis. If allergy develops, very low future exposure can cause itching and a skin rash. An asthma -like allergy may also result from long-term or repeated inhalation exposures with future exposure potentially causing asthma attacks with shortness of La��n bxation: 5505 Sia Fnrks Rd., ?' Flaar, Room 1-2-DI -Raleigh. N.C. '76114 An Equal Qpporrm¢rry Emplr ver Page 3 of U breath, wheezing, cough, and/or chest tightness. General allergic reactions, like urticaria (hives) or shock, may occur. Sodium persulfate has not been tested for its ability to cause cancer or reproductive effects. Evidence of exposure includes: Inhalation: cough, labored breathing, sore throat, wheezing Skin: redness, pain Eves: redness, pain Ingestion: diarrhea. nausea, sore throat, vomiting Recommended personal protective equipment (PPE): Prevent release of dust into the work environment with room ventilation. All persons working with sodium persulfate should use appropriate PPE, including: Eyes and face: Use cup type chemical goggles. Full face shield may be used. Respiratory Use approved dust respirator when airborne dust is expected. A NIOSH 100 HEPA tight -fitting half -face unit is recommended (with fit testing). Protective clothing: Normal work clothes. Rubber or neoprene footwear. Gloves: Rubber or neoprene gloves. Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect regularly for leaks. First Aid: Eye contact: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. Skin Contact: Quickly remove contaminated clothing. Immediately wash contaminated skin with large amounts of soap and water, Breathing: Remove the person from exposure_ Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. Additional safety recommendations: Prevent release of dust into the work environment with room ventilation. Workers whose clothing has been contaminated with sodium persulfate should change into clean clothing promptly. On skin contact immediately wash or shower to remove the chemical. Remove contaminated clothing immediately and wash before reuse. At the end of the work shift, wash any areas of the body that may have contacted sodium persulfate, whether or not known skin contact has occurred. Do not take contamnated work clothes home to prevent exposure of family members. Contaminated work clothes should be laundered by individuals who have been informed of the hazards of exposure to sodium persulfate. Eye wash fountains should be provided in the immediate work area for emergency use. If there is the possibility of skin exposure, emergency shower facilities should be provided. Do not eat, smoke, or drink where sodium persulfate is handled, processed, or stored, since the chemical can be swallowed. Wash hands carefully before eating, drinking, smoking, or using the toilet, Handling and storage: Use adequate ventilation when transferring product from bags or drums. Provide mechanical general and/or local exhaust ventilation to prevent release of Location; 5505 Six Forks R4 ?"`' Flog, Rrrom 1-?-DI • Raleigh, N. C ?7609 An Equal Dpporasnin• Erprplrircr Page 4 of 9 dust into work environment, Spills should be collected into suitable containers to prevent dispersion into the air. Wear respiratory protection if ventilation is inadequate or not available. Use eye and skin protection. Use clean plastic or stainless steel scoops only. Store (unopened) in a cool, clean, dry place away from point sources of heat, e.g. radiant heaters or steam pipes. In case of fire or decomposition (fuminglsmoking) deluge with plenty of water to control decomposition. Use a vacuum or a wet method to reduce dust during clean-up. DO NOT DRY SWEEP. CALCIUM PEROXIDE HEALTH RISK INFORMATION: Formula: Ca02 CASH: 1305-79-9 Synonyms: calcium dioxide, calcium superoxide, Calper, Calper G Classification: oxidizer Calcium peroxide is an oxidizer, thus contact with combustible materials (paper, cotton, organics, leather, reducing agents, and other oxidizers) should be avoided. Calcium peroxide is not flammable but will contribute oxygen to feed a tire. Contamination, heat, and humid conditions will enhance and accelerate decomposition. Decomposition is endothermic, unlike most oxidizers. Store calcium peroxide in a clean, dry place. Do not expose to heat sources or high humidity. Store away from combustible materials. Keep containers closed when not in use. Dilute spills with water. Potential health effects: Contact can severely irritate and bum the skin and eyes with possible eye damage. Breathing calcium peroxide can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. Harmful if swallowed. The following acute (short-term) health effects may occur immediately or shortly after exposure. Contact can severely irritate and bum the skin and eyes with possible eye damage. Breathing calcium peroxide can irritate the nose, throat and lungs causing coughing, wheezing and/or shortness of breath. Chronic (long-term) health effects can occur at some time after exposure and can last for months or years and include lung irritation. Repeated exposure may cause bronchitis with cough, phlegm, and/or shortness of breadth. Calcium peroxide has not been tested for its ability to cause cancer or reproductive effects. Calcium peroxide should be handled in well ventilated, dust controlled areas. When handling large quantities, use a dust mask, goggles, and gloves. Evidence of exposure includes: [nhalation: nose and throat irritation Skin: irritation Eves: irritation Ingestion: irritation of mouth and stomach Recommended personal protective equipment (PPE): Avoid skin contact with calcium peroxide. Eyes and face: Wear chemical safety goggles. Wear a face shield along with goggles when working with corrosive, highly imitating or toxic substances. 1 Location: 5505 Sir Forks Rd.. 3 Floor. Roan l-7-Ql ■ Raleigh, N.C. ?7609 ` An Equal Opporlunin^ E'mplgver page i of IJ Respiratory: Use NIOSH certified toxic dust respirator_ A NIOSH 100 HEPA tight- fitting half -face unit is recommended (with fit testing). Protective clothinK: Wear protective gloves and full cover clothing All protective clothing (suits, gloves, footwear, headgear) should be clean, available each day, and put on before work. First Aid:. Eyes: Immediately flush with water for at least 15-30 minutes, lifting the upper and lower eyelids intermittently. See a medical doctor or ophthalmologist immediately. Skin: Remove contaminated clothing. Wash with plenty of soap and water. Get medical attention if irritation occurs and persists. Ingestion: If conscious rinse mouth with water. Dilute by giving 1 or 2 glasses of water or milk. Do not induce vomiting. See a medical doctor immediately. Inhalation: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain medical attention. Additional safety recommendations: Workers whose clothing has been contaminated by calcium peroxide should change into clean clothing promptly. Do not take contaminated work clothes home. Family members could be exposed. Contaminated work clothes should be laundered by individuals who have been infonrted of the hazards of exposure to calcium peroxide. Eye wash fountains should be provided in the immediate work area for emergency use. If there is the possibility of skin exposure, emergency shower facilities should be provided. On skin contact with calcium peroxide, immediately wash or shower to remove the chemical. Do not eat, smoke, or drink where calcium peroxide is handled, processed, or stored. since the chemical can be swallowed. Wash hands carefully before eating, drinking. smoking, or using the toilet. Use a vacuum or a wet method to reduce dust during clean-up. DO NOT DRY SWEEP, Handling and storage: Calcium peroxide must be stored to avoid contact with combustibles; hydrocarbons; fuels; cellulose. hydrogen peroxide; and organic materials since fires may occur. Store in tightly closed containers in a cool, well -ventilated area. SODIUM HYDROXIDE HEALTH RISK INFORAMTION: Formula: NaOH CASH: 131 0-73-2 Synonyms: Caustic soda. Lye, Soda lye_ Sodium hydrate Classification: alkaline, corrosive s ' Location: �505 Six Furkc' Rd.. 1"d Flom •. Ronny 1-2-DI • Raleigh. N.C. "6I�i+ l An Equal OPPriraanin• FMr1fWer Page h of 9 Sodium hydroxide is classified as a corrosive material. Sodium hydroxide is incompatible with water, acids, flammable liquids, organic halogens, organic peroxides, metals such as aluminum, tin, zinc, or nitromethane. It is corrosive to metals. Keep this compound separated from acids, easily ignitable materials, explosives, metals, organic peroxides, and water or any moisture. Sodium hydroxide will react with water to release heat and contact with aluminum, tin, lead and zinc will release flammable and explosive hydrogen gas. Contact with nitromethane and other nitro compounds may result in the formation of shock -sensitive or explosive salts. Contact with moisture or water may generate sufficient heat to ignite combustible substances. Potential health effects: Sodium hydroxide is a corrosive irritant of the skin, eyes, and mucous membranes. Sodium hydroxide both in solid and in solution has a markedly corrosive action upon all body tissues causing burns and frequently deep maceration, with ultimate scarring. Inhalation of the dust or concentrated mist can cause damage to the upper respiratory tract and to lung tissue, depending upon the severity of the exposure. Effects of inhalation may vary from mild irritation of the mucous membranes at 2 mg/m3 to severe pneumonitis at higher airborne concentrations. Inhalation of alkaline vapors can produce upper airway edema, respiratory failure, wheezing, pulmonary edema, and pneumonitis. Exposure to the dust or mist may cause pain, redness, irritation or full thickness bums. Contact with the eyes causes disintegration and sloughing of conjunctival and corneal epithelium, corneal opacification (renders the cornea opaque), marked edema, and ulceration. Permanent visual loss may occur. After 7 to 13 days, either gradual recovery begins, or there is progression of ulceration and corneal opacification. On the skin, solutions of 25 to 50% sodium hydroxide cause a sensation of irritation within about 3 minutes; with 4% solutions, irritation does not develop for several hours. If it is not removed from the skin, severe burns with deep ulceration may occur. Produces severe abdominal pain, corrosion of the lips, mouth, tongue, esophagus, and pharynx, and the vomiting of large pieces of mucosa. It can cause perforation and scarring. Glottic edema and upper airway obstruction may occur following ingestion. Cases of squamous cell carcinoma of the esophagus have occurred with latent periods of 12 to 42 years after ingestion. These cancers were the sequelae of tissue destruction and possible scar formation, rather than due to a direct carcinogenic action of sodium hydroxide itself: The greatest industrial hazard is rapid tissue destruction of eyes or skin upon contact with either the solid or concentrated solutions. Acute (short-term exposure) health effects which may occur immediately or shortly after exposure include with contact severe irritation and burning the skin and eves with possible eye damage or clouding of the eyes with loss of vision. Breathing sodium hydroxide can irritate the mouth, nose and throat. Breathing can also irritate the lungs causing coughing and/or shortness of breath. Higher exposures can cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. Chronic (long-term exposure) health effects can occur at some time aver exposure to and can last for months or years, Very high chronic exposure may cause lung damage. Sodium hydroxide has not been tested for ability to cause cancer in animals. There is no evidence it effects reproduction. r� n r Locn6on_ 5505 Six For-ks Rd., 2'x1 Floor, Boon: 1-'-OI •Raleigh, MC2?609 An Equal Oppm-itioury Empinver �� Pinar 7 or') E-vidence of exposure includes: Inhalation: irritation of mucous membranes, pneumonitis Skin: irritation, burns. temporary loss of hair Eyes: irritation, corneal damage Ingestion: irritation of mucous membranes, severe abdominal pain, corrosion of the lips, mouth, tongue, and pharynx, and the vomiting of large pieces of mucosa, upper airway obstruction may occur Workplace exposure linxits: These exposure limits are for air levels only. OSHA: The legal airborne permissible exposure limit (PEL) is 2 mglm3 averaged over an 8-hour work shift. NIOSH: The recommended airborne exposure limit is 2 mg31m3, which should not be exceeded at any time. The NIOSH IDLH value is 10 mglm . ACGIH: The recommended airborne exposure limit is 2 mglm3, which should not be exceeded at any time_ Recommended personal protective equipment (PPE): Appropriate, impervious, protective clothing (including gloves) should be worn to prevent skin contact. Protective equipment should not be made of aluminum, copper, soft iron, tin, or zinc (or alloys made of these metals. Eves and face: For solid sodium hydroxide wear impact resistant eye protection with side shields or goggles. For liquids wear indirect -vent, impact and splash resistant goggles. A face shield along with goggles is recommended when working with corrosive, highly irritating or toxic substances. Contact lenses should not be warn when working with this substance. Eyewash fountains should be provided. Respiratory: Use NIOSH certified toxic dust respirator. A NIOSH 100 HEPA tight- fitting half -face unit is recommended (with fit testing). Where the potential exists for exposure over 2 mgitn3, use a MSHAINIOSH approved supplied -air respirator with a full face piece operated in a pressure -demand or other positive -pressure mode. For increased protection use in combination with an auxiliary self-contained breathing apparatus operated in a pressure -demand or other positive -pressure mode. Exposure to 10 rnglm3 is immediately dangerous to life and health. If the possibility of exposure above 10 mg/m' exists, use a MSHAINIOSH approved self-contained breathing apparatus with a full face piece operated in a pressure -demand or other positive -pressure mode. Gloves: Impervious. ACGIH recommends polyvinyl chloride, butyl, butyllneoprene, natural rubber, neoprene, polyethylene, Saranex, Teflon and Vitonlneoprene as protective materials. First Aid: Eves: Irrigate immediately Skin: Water flush immediately. Clothing which becomes significantly contaminated, or wet, should be removed as quickly as possible. Breathing: Respiratory support Ingestion: Medical attention immediately Location- 5505 Sir Fnrks Rd.. '" Floor. Room 1-7 D! • Raleigh. rV.C. 7609 Art Equal OpporthnilY E11rf71h1vr Page 8 of 9 Handling and storage: Store in tightly closed containers in a cool, dry, well -ventilated area away from moisture. Wherever sodium hydroxide is used, handled, manufactured, or stored, use explosion -proof electrical equipment and fittings. Keep sodium hydroxide separated from acids, easily ignitable materials, explosives, metals, organic peroxides, and water (or any moisture). Additional safety recommendations: Workers whose clothing has been contaminated by sodium hydroxide should change into clean clothing promptly. Do not take contaminated work clothes home. Family members could be exposed. Contaminated work clothes should be laundered by individuals who have been informed of the hazards of exposure to sodium hydroxide. Eye wash fountains should be provided in the immediate work area for emergency use. If there is the possibility of skin exposure, emergency shower facilities should be provided. On skin contact sodium hydroxide, immediately wash or shower to remove the chemical. At the end of the work shift, wash any areas of the body that may have contacted sodium hydroxide, whether or not known skin contact has occurred. Do not eat, smoke, or drink where sodium hydroxide is handled, processed, or stored, since the chemical can be swallowed. Wash hands carefully before eating, drinking, smoking, or using the toilet. For solid sodium hydroxide use a vacuum to reduce dust during clean-up. DO NOT DRY SWEEP. Location: 5505 .Sir Forks fld- 2`0 Moor. Room 1 -Ul • Raleigh, N.C. 276U9 Air Equal Oppomewty Emplo►wr I Page 9 01, 1 References: 1. International Chemical Safety Cards (ICSCs): International Programme on Chemical Safety. CDC, NIOSH, ht!p://www.cdc.gov/niosh/ipcs/icstart.html 2. New Jersey Department of Health and Senior Services Hazardous Substances Fact Sheets. 3. Sodium Persul fate MSDS. FMC MSDS no.: 7775-27-4, April 30, 2006, revision no. 12. FMC Corporation. 4. Calcium Peroxide Technical Data Sheet. FMC Corporation. 5. TOXNET Toxicology Data Network. US National Library of Medicine. http-//toxnet.nim.nih.gov 6. Calcium Peroxide MSDS. FMC MSDS no.: 1305-79-9-1, April 30, 2006, revision no. 9. FMC Corporation. 7. Thomson MICROMEDEX. 8. NIOSH Pocket Guide to Chemical Hazards. CDC. 9. Technical and Regulatory Guidance for In Situ Chemical Oxidation of Contaminated Soil and Groundwater, Second Edition. The Interstate technology & Regulatory Council In Situ Chemical Oxidation Team. January 2005. http:l/www.itreweb.org/Documents/ISCO- ?.pdf Nc air_, J 1 Y Location: 3505Sir Forkr Rd., "'Flow-, Flanr, Room 1—'-D! •Raleigh, 1,.C. 2761+� ,� An Equal dpporduna,r Enipl(�ver "�� August 25, 2011 NCDENR-Division of Water Quality Aquifer Protection Section Underground Injection Control Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Attention: Mr. Thomas Slusser, L.G. Program Manager Reference: STATUS REPORT — INJECTION PERMIT WI004001I0 133 South Main Street Kernersville, North Carolina NCDENR Incident #16401 S&ME Project No. 1584-08-05I Dear Mr. Slusser: S&ME appreciates your assistance with the above referenced injection permit dated August 28, 2009, Enclosed with this letter are copies of the following submittals. ■ Field Summary Report for the Former High Point Health Care Venture Site in Kernersviile, NC; Redox Tech, LLC (November 20, 2009) ■ Research & Analytical Laboratories, Inc.; soil analytical report for soil samples PR-1-15, PR-1-19, PR-2-15, PR-2-20, collected on February 24, 2010 following the first injection event • Injection diagram ■ Site Map showing the proposed injection well field • Page 1 of 7 and executed copy of page 7 of 7 of Injection Permit W100400110 Injection of Oxygen BioChem was completed by Redox `Tech, LLC., at the permitted six locations on November 9, 2009. The attached summary report describes the injection procedure and documents the proper abandonment of each injection point. On February 24, 2010, S&ME collected two soil samples each from two soil probes performed within the injection field. The analyses of soil samples collected from probe PR -I performed in the northwest portion of the injection field did not detect target analyses by EPA Methods 8260B and 8270 BNA and by the MADEP Methods for volatile petroleum hydrocarbons (VPH) and extractable petroleum hydrocarbons (EPH). The analyses of soil samples collected from probe PR-2 performed in the southeast portion of the injection field detected one semi -volatile organic compound, C9-C 18 Aliphatics and C11-C22 Aromatics at concentrations above the corresponding targeted MSCC soil to groundwater clean-up goals. SWE, INC. / 3718 Old Battleground Road / Greensboro, NC 2741 a / p 335.288.7180 f 336.288.8980 / www.smeinc.corn Status Report- Injectio -mit WI0400110 58 Project No. 1584-08-051 Farmer High Point Health Care Ventures, Kemersville, NC August 25, 2011 High Point Regional Health Systems (permit holder) has authorized S&ME to provide a second phase of injection using four injection points to be performed in the southeast end of the previous injection field. Please contact S&ME if you have any questions concerning the proposed second injection phase under this permit. Sincerely, S&ME, Inc. Ly dal Butler Project Manager LBllss High Point Regional Health Systems P.O. Box HP-5 High Point, NC 27261 8/19/2011 Project: Kemersville, NC Summary Report Field Summary Report for the Former High Point Health Care Venture Site in Kernersville, N C Prepared by David Halsclawon Novem6er20, 2009 Field Contractor Redox Tech, LLC I Client S&ME Project Lead Dave Holsclaw Project Lead L ndal Sutler Phone Number 843-991-9771 Phone Number 336-288-7180 Email Address Holsclaw redox- Email Address LButler(d,SMEINC.com T tech.com Start Date 1119109 End Date 1119109 Chemical OBC Total Gallons 480 Injection Points 6 Injection Intervals 6 to 18 feet b s Brief Narrative: On November 9, 2009, Redox Tech performed injections at the Former High Point Health Care Venture Site in Kernersville, NC. A total of 480 gallons of OBC solution was injected into 6 locations. Injections were performed using 1.5" direct push technology (DPT) bottom out injection rods. This allowed injections to be completed over a I2-foot interval. (6'-18' bgs) Each of the 6 locations received 80 gallons of OBC solution. If dayiighting occurred the point was either moved or the additional volume was added by reducing injection pressures and flow rates. An injection summary table from this event is provided in Appendix A. The OBC solution was prepared using a Redox Tech injection trailer. A water source for injections was supplied on site, The 480-gallon solution consisted of 800lbs of OBC and 480 gallons of water. The solution was mixed thoroughly using a trash pump and powered mixing rod. Prior to injection S&ME laid out the injection grid and had all utilities cleared. Injection rods were then advanced to a depth of 18' bgs. Injection pressures were maintained between 22 psi and 30 psi. Approximately 27 gallons of solution was injected at 18', 12', and 6' in order to distribute the solution over the vertical interval as described in the Redox Tech work plan. Once the injection was complete, points were abandoned from the top of the injection interval to ground surface using granular bentonite. Asphalt patch was used to complete the abandonment of each injection location. Page l Redox Tech, LLC. 8/19/2011 Project: Kernersville, NC Summary Report APPENDIX A: INJECTION SUMMARY TABLE Injection Summary Data Table For Kernersville, NC Injection Point date Start Time End Time Depth Interval ft. Flow Rate m Amount Injected al. IP-1 11/9/2009 1021 1040 8'-18' 4.2 80 1 P-2 11/9/2009 1358 1446 8'-16' 1.7 80 1P-3 11/9/2009 1113 1205 8'-18' 1.5 80 I P-4 11/9/2009 1050 1515 8'-18' .3 80 IP-5 11/9/2009 1256 1319 8'-18' 3.5 80 IP-6 1119/2009 1206 1254 8'-18' 1.7 80 Page 2 Redox Tech, LLC. RFscARCh & Ar TicAl LAbDRATORIES, INc. - a00ly11callPFo esS Cor$$U1tQuans Chemical Analysis far Selected Parameters and Sampling Locations Identified as 133 S. 4vailr Street _ (A S & ME-, Ine. Project #1584-08-051, collected 24 February 2010) [ Valalile0rgaolcs ifuantilafeon PR•1-I5 PR•1.19 PR-2-19 PH-2-20 EPA Method $260 B Limit pargutetcr fmglkgl tmelkel fenelkel tmglkgl (nwjw Acclnne 0.100 BQI. BQL BQI. BQI, Bemzene 0,005 BQL BQI, BQL BQL Bromob(. v=ne 0,005 HQL BQL BQL BQL Bmmochloromethane 0.005 BQL BQL BQL BQL Brornoft-Nommcthane 0.005 BQL BQL BQL SQL Bromoform OA05 BQI. BQL BQI. BQL Brosnomcthane 0,010 BQL BQL BQL BQL 2-Butanone 0.100 BQL BQL BQL BQL N-Butylbenzene 0.005 BQL BQL 5.07 4.87 Sec-Butylbenzene 0.005 BQL BQL 517 SAS Ten-Butylbenzene 0.005 BQL BQi, BQL BQL Carbon Tetrachloride 0.010 BQL BQL BQI. BQI. Chlombenzene 0.005 BQL BQI- BQL BQL DlhromochIoromethane 0.005 BQL BQL BQL BQL Chlomethane 0.010 BQL BQL BQL BQ[. Chlorofann 0,005 BQL BQL BQi. BQL Chiomilohane 0.010 BQL SQL BQL BQL 2-Chlorololuene 0,005 BQL BQL BQL BQL 4-Chlor010lucne 0,005 BQL BQL BQL BQL 12-Dibromoethane(EDB) 9,005 BQL BQL BQL BQL 12-Dichlomhenzene 0.005 BQL BQL BQL BQI. 1.3-Dichlorubctuene 0.005 BQL BQL BQI. BQL I A-Dichlrrmbenzene 0,005 BQL BQL BQL BQL D1Chloroditluommthane 01005 SQL BQI. BQL BQL l,l-Dielilomcthane 0,005 BQL BQL JBQL I3QL 12-Diehlomethane 0,005 BQL BQL BQL BQL l,l-Dichlaroethene 0.005 BQL BQI. BQL BQL Cis-1,2-Dichloroethcne 0.005 BQL BQI. BQL BQL Trans- l,2-Dichlorocthe ne 0.005 BQL BQL BQL BQL 1,2-Dichloropropam 0.005 BQL BQI. BQL BQL 1.3-DichIompropane 0.005 BQL BQL BQL BQL 2,2-Dichlormpropam 0.005 BQL BQL BQL SQL 1,1-Dichloropropane 0,005 BQL BQL BQi. BQL Cis- 1,3-Dichloropropcne 0,010 BQL BQL BQL BQL Trans-43-Dichlompropene 0.010 BQL BQL BQL BQL Ethyl Acetate 0.010 BQL BQL BQi., BQI. Ethyl Benzene 0,005 BQL BQL BQL BQL 2-Hexanone 0.050 BQL BQL BQL BQL 1-Propyibenzene 0,005 BQL BQL BQL BQL Isopropylether (IPE) 0,010 BQL BQI. BQL BQL p-Isopropyllolucne 0,005 BQL BQL 8,70 7.91 Methylene Chloride 0,020 BQL BQL BQL BQL 4-Methyl-2-Pentanone 0.100 BQL BQL BQL BQL Methyl-Tert-Butyl etlier(MTBE) 0,010 BQL BQL BQL BQI. Naphthalene 0.010 BQL BQL 41.7 8.18 N-Propylberuxnc 0.005 BQL BQL BQi. 3.66 Styrene 0.010 BQL BQL BQL 13QL l,i•2,2-Te1rachloroethane 0.005 BQL BQL BQI, SQL Tetrachloroetliene 0.005 BQL BQL BQL BQL Toluene 0.005 BQL BQL BQL BQL 1, 1. 1 -Trichlormtl we 0,005 BQL BQL BQL BQL l,U-Trichloroethane 0.005 BQL BQL BQL BQL Trichlomethene 0.005 BQL BQL BQL BQL TrichloroOuoromethane U05 BQL BQL BQL BQL 1,2.3•Trichlorobenzetre 0.005 BQL BQL BQL BQL 12,4-Trichlambenzene 0,005 8QL BQL BQL 13QL 1,2,3-TricldompnVane 0.015 BQL BQL BQL BQL 1,44-Trimetlrylbenzene (1005 BQL BQL 36.7 23.6 13.5-Trime1hylbenzene 0.005 BQL BQL 15A 20A Vinyl Acetate 0.050 BQL BQL BQI, 13QL Vinyl Chloride 0,010 BQL BQL BQL BQL Tora1 Xylcrus 0,005 BQL BQL BQL BQL Carbon DisuiCtde 0,100 BQL BQL 13QL BQL Aerylorwrile 0,200 BQI. BQL BQL BQL Tram- l,4-Dichlcro-2-butenc 0,100 BQL BQL 13QL BQL Methyl iodide 0,010 BQL BQL BQL BQL Dibrnmemelhane 0.010 BQL BQL BQL BQL 1,1,12-TetraclJoraethane 0.005 SQL BQL BQL BQL I-'0bramo-3-ChlompropanclDBCP) 0.025 BQL BQI. BQL BQL Dilution Factor l I 500 500 Sample Number 667841 667842 667843 667844 Sample Date C12/24110 02/24/10 02/24/10 02/24/10 Sample Time (hrs) 0935 0948 1012 I042 Date Analyzed 02/26/10 02/26/10 02/26/10 02/26210 rnWkg = milligarns per kiiogam = parts per rruilion (ppmy BQL = Below Quanlitalion Limits �E5EAf2C 4EL AryAL TicAL Rnc7{yrriccalfF'r�CE7ss GE7:i9u1id74C?nS � � �'�F��. f Chemical Analysis for Selected Parameters and .Sannpling Locations Identified as 133 S Main Street (A S & rblF., Inc. Proiect 415$4-08-051, collected 4 I'ehrisar 1010) 11. Semi -Volatile Organics Quantitation Pft-1-15 PR-1-19 PR-2-19 PR-2-20 EPA Method $270 BNA limit Paramcter frng�kg fial [melkel m k fmalkel Acenaphtbene 0.33 BQL BQL BQL BQ1. Acenaphthylene 0.33 BQL BQL BQL BQL Anthracene 0.33 BQL BQL BQL BQL Bertzoic Acid 6.67 BQL BQL BQL BQL Benzo(a)atlivacene 0.33 BQL BQL SQL BQL Benno(b)fluoranthene 0.33 BQL BQL BQL BQI. Benzo(k)Bucranthene 0.33 BQL BQL BQL BQL Benzo(ghi)perylene 0.33 BQL BQL BQL L Benzo(a)yrene 0.33 BQL BQI. BQL BQI. Benzyl Alcohol 3.33 BQL BQL BQL BQL Bis(2-chloroethoxy)methane 0.33 BQI. BQL BQL BQL Bis(2-chloroethyl)ether 0.33 BQL BQL B L BQL Bis(2-chloroisoprapyl)ether 0.33 BQL BQL Bt L BQL Bis(2-ethyl-hcxyl)phthalate 0.33 BQL BQL BQL BQL 4-Bromnphenyl phenyl ether 0,33 BQL BQI, BQL- SQL Benzyl buryi phthalate 0.33 BQL BQL BQL BQL 4-Coroanilim 1.65 BQL BQL BQL SQL 4-Chloro-3-methy[phenol 2-Chloronaphthalene 0.33 0.33 BQL BQL BQL BQL BQL BQL BQL 2-Chlorophenol 0.33 BQL BQL SQL BQL BQL 4-Chlorophenyi phenyl ether 0.33 BQL BQL BQL BQL Chrysene 0.33 BQL BQI, BQL BQL Dibenzo(a,h)anthracene 0.33 BQL BQL BQL BQL Dibenwfitran 0.33 BQL SQL BQL BQL Di -NI -Butyl phthalate 0.33 BQL BQL 13QL BQL 1.2-Dichlorobenzene 0.33 BQL BQL BQL BQI. 1,3-Dichlorobertzene 0.33 BQL BQL BQL BQL 14-Dichlorobenzene 0.33 BQL BQL BQL BQL 3,3-Dichiorobenzidine 0.66 BQL BQL BQL BQL 2,4-Dichlorophenol 0.33 BQL SQL BQL BQI. Diethyl phthalate 0.33 BQL BQL BQL BQL 2 4-DimethyyIphenol 0.33 BQL BQL 8QL B I. 5ienetlryl phtlralnte 0.33 BQL BQL BQL BQL 4,6-Dinitro-2-methylphenol 1.65 9QL BQL BQL BQL 2,4-Dinitrophenol 1.65 BQL BQL BQL BQL 2,4•Dinitrotoluene 0.33 BQL BQL SQL BQL 2 6-Dinitrotoluene 0,33 BQL BQL BQL SQL Di-N{lctyl phthalate 0.33 BQL BQL BQL BQL Azobenzene 3,33 L B BQL SQL BQL Fluoranihene 0.33 BQL BQL SQL BQL Fluorene 0.33 BQL BQL SQL BQL Hexachiombenxene 0.33 BQL BQL BQL BQL llexachlorobutadiene 0.33 BQL BQL BQL BQL Hexachlorocyclopentadiene 0.33 BQL BQL BQL BQL ilexachloroethane 0.33 13QL BQL BQL BQL In&,rw(1,2,3-cd) pyrene 0.33 BQL QL BQLL BQL 0.33 BQL B SIsophorone BQL 2-Methyhaaphtalene 0.33 BL BQL 101 39.9 2-Methylphenol 1.65 BQL BQL BQL BQL 4-Methylphenol 1.65 BQL BQL BQL BQL Nitrobenzene 0.33 BQL BQL BQL BQL 2-Nitropheexrl 0.33 BQL BQL BQL BQL 4-Nitrophewl 1,65 BQL BQL BQL BQL N-Nitrosodiphenylarnim 0.33 BQL BQI. SQL BQL N-nitrosodi-n-propylatnine 0.33 BQL BQL BQL BQL Pentachlorophenol 1.65 BQL BQL BQL BQI. Phenanthrene 0.33 BQL BQL 25.4 9.36 Phenol 0.33 BQL BQI. BQL BQL Pyrene 0.33 BQL BQL BQL BQL 1,2,4-Trichlorobeuene 0.33 BQL BQL BQL BQL 2,4,6-Trichlorophenol 0.33 BQI_ SQL BQL BQL 2-Methyl-4,6dmitrophenol 1.65 BQL BQI. BQL BQL Benzidme 1.65 BQI. BQL BQL SQL l2-Diphcnylhydrazine 1.65 BQL SQL BQL BQI. N-Nitrosodimethylamine 0.33 BQL BQL BQL BQL Dilution Factor 1 1 20 10 Sample Number 667841 667842 667843 667844 Sample Date 02/24/10 02/24/10 02/24/10 02/24110 Sample Time (hrs) 0935 0948 1012 1042 Date Extracted 03/03/10 03103110 03/03/10 03/03/10 Date Analyzed 031041i0 03104110 03/04/10 03/04/10 trtg,kg = nulligranis per kilognun = parts per million (ppm) l3QL = Below Quanfitation i.imits BNA = Base -Neutral Acid EAtraetahles - = Not Available R ESEARCh & r%NA[yT1CA[ ,�•`''b�►�! � • LAbQRATQRIES� INC.cFy-0o= NOON xl S Analytical/Process consuitatians . Clretnical Analysis for Selected Parameters and Sanepling Locations Identified as 133 S. :Vain Street (A S & AfE, 111C. Project 41584-08-051, collected 24 February 2010) 11[, Method MADEP 98-1 Quantization PR-1-I5 PR-1-19 PR-2-19 PR-2-20 VPH Limit Parameter Lrttgllce} fFmA2l (MWIZ rmgrkgl (11WY g] C5-CS Aliphatics 10.0 BQL BQL BQL BQL C9-C12 Aliphatics 10.0 BQL BQL 966 1,050 (79-C10 Aromatics 10.0 BQL BQL 213 158 Dilution Factor l 1 10 1 (} 1V. Method MADEP 98-1 Quantitation PR-1-15 PR-t-19 PR-2-19 PR-2 20 EPH Litnit Parameter fm 1a) fmgzw) (MWI 1 (¢ 1 r 1t ] C9-C18 Aliphatics 10.0 BQL BQL 6,740 4,800 C-19-C-36 Aliphatics 10.0 BQL BQL 518 382 C11-C22 Aromatics 10.0 BQL BQL 3,640 1,390 Dilution Factor 1 I 1 1 Sample Number Sample Date Sample Time (hrs) 667841 667842 667843 667844 02/24/10 0224/10 0?124/10 02/24/10 0935 0948 1012 1042 MADEP EPH 98-1 = Extractable Petroleum Hydrocarbons via the Massachusetts Department of Envimnmentat Protection Method MADEP VP 99-1 = Volatile Petiole= Hydrocarbons via the hassachusem Department of Environmental Protection Method mg/kg = milligrains per kilogram = parts prr million (pptn) BQL = Below Quantization Urnios NR =Nat Requeslcd EPH (Aliphatics/Aromatics) Laboratory Reporting Form Client Name: Project Name: Site Location: S & ME, Inc 133 S. Main Street -# 1584-08-051 RAL Ws 667841-44 Laboratory Name: Research & Analytical Laboratories, Inc NC Certification N (Lab) 34 Sample Matrix: Solid Sample Information and Analytical Results Method for Ranges: MADEP EPH Sample Identification PR-1-15 PR-1-19 PR-2-19 PR-2-20 EPH Surrogate Standards Date Collected 02/24/10 02/24/10 02/24/10 02/24/10 Date Received 02/24/10 L'2J24110 02/24/10 02/24/10 Aliphatic: COD Date Extracted 02/25/10 02/25/10 02/25/10 02/25/10 Aromatic: u-terphenyl Date Analyzed 02/26/10 *62/26/10 02/26/10 02/26/10 EPH Fractionation Surrogates % Dry Solids 79.4 82.2 81.6 78.4 91 2-Fluorohiphcnyl Dilution Factor l l 1 1 92 2-Bromonaphthalene Hydrocarbo Units of MDL RL Blank NIA NIA NIA NIA N. A N A N. A N :� n Ran es Measure C9 - C18 mg/kb 5.3 lrt.[t BRL BRL BRL 6,740 4,800 Aliphatics C19-C36 mglkg 14 Itt i1 13R1 BRL BRL 518 382 Aliphatics Cil-C22 mglkg �. I().i1 BRI- BRL BRL 3,640 1,390 Aromatics Sample Surrogate NIA N/A 40-140% 40-140% Io-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% Aeec tance Range Aliphatic Surrogate % N/A N/A 97 77 85 96 87 Recovery Aromatic Surrogate % MA NIA 99 85 87 89 113 Recovery Fractionation Surrogate NIA NIA 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% 40-140% Acceptance Range Fractionation Surrogate #1 NIA NIA 65 NIA NIA 75 106 % Recovery Fractionation Surrogate 42 NIA NIA 51 NIA NIA 71 78 % Recovery Unadjusted value_ Should exclude the concentration of any surrogate(s), internal standards, and/or concentrations of other ranges that elute within the specified range. MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank or Trip Blank whichever is higher (indicate type) Were all performancelacceptable standards for required QAIQC procedures achieved? Was blank correction applied as a significant modification of the metbod? Yes FI No - Details Attached Yes FT No Were any significant modifications to the EPH method made". KI No ❑ Yes - Details Attached VPH (Aliphatics/Aromatics) Laboratory Reporting; Client Name: Project Name: Site Location: S & ME, Inc 133 S. Main Street-#1584-08-051 RAT. Ws 667841-44 Laboratory Name: Research & Analytical Laboratories, Inc NC Certification # (Lab): 34 Sample Matrix: Solid Sample information and Analytical Results Method for Ranges: MADEP VPH Sample Identification PR-1-15 PR-1-19 PR-2-19 PR-2-20 VPH Surrogate Standards Collection option (for soil)* l 1 l l Aliphatic: Fluorobeimene Date Callected 02/24/10 02/24/10 02/24/10 02'24110 Date Received 02/24/10 02/24/10 02/24/10 02/24/10 Aromatic: Fluorobeuenc Date Extracted NIA N/A NIA NIA NIA MIA N-A N/A Date Analyzed U2126110 02/26/10 02/26/10 02/26/10 % Dry Solids 79.4 82.2 81.6 78.4 Dilution Factor I 1 10 l0 llydrocarbo n Ranges Units of Measure MDL RL Blank NIA N/A NIA NIA NIA NIA NIA NIA C5 - C8 Aliphatics mg/kg 2.84 10.0 BRL BRL BRL BRL BRL C9 -C12 Aliphatics mglkg 0.90 10.0 BRL BRL BRL 966 1,050 C9-C10 Aromatics mg/kg 0.66 10.0 BRL BRL BRL 213 158 Sample Surrogate Acceptance Range N/A NIA 70-130% 70-130% 70-130% 70-130% 70-130% 70-130% 70-130% 70-130% 70-130% Aliphatic Surrogate % Recovery - FID N1A N/A 102 84 76 90 96 Aromatic Surrogate % Recovery - PI D NIA [VIA 85 74 74 79 86 Option I = Established fill line on vial Option 2 = Sampling Device (indicate brand, e.g. Encore) Option 3 = Field weight of soil Unadjusted value. Should exclude the concentration of any surrogates), internal standards, and/or concentrations of other ranges that elute within the specified range. MDL = Method Detection Limit RL = Reporting Limit Blank = Laboratory Method Blank or Trip Blank whichever is higher (indicate type) VPH rev. l IMG Were all performance/acceptable standards for required QA/QC prodedures achieved? EYes F7 No - Details a Were any significant modifeatinos to the VPH method made? EJ No 71Yes - Details RESEARCh & ANA1yTICA1 LAboRATORiES, INC. Analytical 1 Process Consultations Phone (336) 996-2841 CHAIN OF CUSTODY RECORD WATER 1 WASTEWATER I mim COMPANY r - !' _ JOB NO, _{LAB n' r to y p_ C �Q' Z a} Qp c'q 4Q- ry ' c REGIESTED ANALY STREETAO RESS !f k d PROJECT J J 1�'[(iI C[TY. STATE, ZIP SAMPLER NAME (PLEASE PRINT) CONTACT PHONE SAMP ER SIGNATURE NUMBER USE ONLY} GATE TIME DY CNI RES Cl RE�axSAMP h.. RELINQUISHED BY DATEITlME %Y RECEIVED Y REMARKS: SAMPLE TEMPERATURE AT RECEIPT C RELfNQUISHE BY DATEITIME RECElVEq ' RESEARCh of ANALyTiCAL LkORATWES, INC. Analytical/Process Consultations CASE NARRATIVE FOR ORGANICS Four (4) soil samples were received in good condition on 24 February 2010. The samples were analyzed without difficulties unless noted below. Sidney L. Champion Director of Laboratory Services a3-a,7-)0 Date P.C. Box 473 • 106 Short Street • Kernersville, North Carolina 27284 •336-996-2841 ■ Fax 336-996-0328 www.randalabs.com QA/QC Summary Method 8260 (100/200/400/1000/2000 PPB QC} IFILE NAME: SQCO226A CLIENT: S & ME (PROJECT:133 S. MAIN ST.: JOB # 1584-08-051) 1 Page 1 of 2 Sample ID 667841-844 VOA INSTRUMENT(MS-2) Extraction Method 5035 Date Extracted NIA Weight/Volume Used 5G15ML Final Volume 5G15ML Date Analyzed 02/26/10 % Surrogate Recovery 104 100 98 Acceptance Range (70 -130) (70 -130) (70 -130) LCS Range QC LIMITS Compound p MDL m a Method Blank LCS %Acceptance Recover MS % Rec. * MSD ❑/a Rec. * RPD RPD PERCENT RECOVERY Dichlorodifluoromethane 0.00047 ND 74 56 - 126 Chloromethane 0.00050 ND 97 62 - 133 Vinyl Chloride 0.00059 ND 105 67 - 136 Bromomethane 0.00028 ND 102 72 - 130 Chloroethane 0.00029 ND 105 73 - 138 Trichlorofluoromethane 0.00037 ND 98 78 - 131 Acetone 0.00159 ND 74 62 - 119 Acrylonitrile 0.00036 ND 98 76 - 135 2-Butanone 0.00152 ND 94 62 - I22 1,I-Dichloroethene _ 0.00059 ND 106 82 - 133 100 99 1 14 61-145 Methyl Iodide 0.00307 ND 106 70- 136 Carbon Disulfide 0.00042 ND 100 76 - 132 Methylene Chloride 0,00138 ND 103 68 - 135 Trans-1,2-Dichloroethene 0.00107 ND 105 SO- 134 1,1-Dichloroethene 0.00036 ND 103 74- 140 Isopropyl ether (IPE) 0.00024 ND 108 67 - 139 Methyl-Tert-Butyl ether (MTBE) 0.00032 ND 101 68 - 131 Vinyl Acetate 0.00035 ND 107 67 - 127 Cis-1,2-Dichloroethene 0,00031 ND 107 78 - 133 2,2-Dichloropropane 0.00029 ND 85 72-123 Bromochloromethane 0.00049 ND 103 71 - 139 Chloroform H0029 ND 101 8I - 126 1,1,1-Trichioroethane 0.00028 ND 103 76- 129 Carbon Tetrachloride 0.00081 ND 102 81 - 133 1,1-Dichloropropene 0.00059 ND 105 80- 135 Benzene 0.00038 ND 103 78 - 131 94 95 1 11 76-127 Ethyl Acetate 0.00074 ND 103 63 - 122 1,2-Dichloroethane 0.00055 ND 99 72 - I32 Trichloroethene(TCE) 0.00028 ND 98 79 - 126 92 95 3 14 71-120 1,2-Dichioropropane 0.00023 ND 100 79 - 126 Dibromomethane 0.00043 ND 10I 71- 129 NIA = Data Not Available QAIQC summary Method 826Q (100/200/40011000/2000 PPB QC] IFILE NAME: SQCO226A (MS-2) CLIENT: S & NI (PROJECT: 133 S. MAIN ST.: JOB # 1584-08-051) Page 2 ❑f 2 LCS Acceptance Range QC LIMITS Compound MDL mg/kgmg/kg Method Blank LCS % Recovery MS % Ree. * MSD °/„ Rec. * RPD RPID PERCENI RF.COVkRti Bromodichloromethane 0.00026 ND 97 71 - 126 4-Methyl-2-Pentanonc 0.00052 ND 87 67 - 122 Cis-1,3-❑ichloropropene 0,00023 ND 91 70 - 125 Toluene 0A0027 ND 65 - 139 87 88 1 13 76-125 Trans-1,3-Dichloropropene 0.00052 ND 65-131 1,1,2-Trichloroethane 0.00041 ND 2103 64- 137 Tetrachloroethene(PCE) 0,00026 ND 61 - 164 2-Hexanone 0,00050 ND 105 63 - 1 l8 Dibromochloromethane 0.00037 ND 92 60 - 138 1,3-❑ichloropropane 0.00033 ND 103 64 - 135 1,2-Dibromoethane (EDB) 0.00074 ND 91 68 - 131 Chlorobenzene 0.00029 ND 105 87- 121 102 106 4 13 75-130 1,1,2,2-Tetrachtoroethane 0.00041 ND 106 85 - 131 Ethyl Benzene 0.00028 ND 101 91 - 12I Total Xylenes 0.00056 ND 104 88-127 Styrene 0.00037 ND I04 88 - 124 Bromoform 0.00045 ND 113 66 - 133 Isopropyibenzene 0.00027 ND 105 90 - 125 Bromobenzene 0.00028 ND 109 81 - 128 1,2,3-Trichloropropane 0.00043 ND 96 66 - 132 Trans-1,4-Dich]oro-2-butene 0.00050 ND 103 77 - 120 N-Propylbenzene 0.00058 ND 101 88 - 123 2-Chlarotvluene 0.00050 ND 103 86 - 126 4-Chloratoluene 0.00042 ND 104 82 - 125 1,3,5-Trimethylbenzene 0.00054 ND 105 89 - 124 Tert-Butylbenzene 0.00029 ND l08 89 - 128 1,2,4-Trimethylbenzene 0.00056 ND I06 87-125 Scc-Butylbenzene 0.00042 ND 104 88- 127 1,3-Dichlorobenzene 0.00041 ND 106 79- 127 1,1,2,2-Tetrachloroethane 0.00078 ND 107 72- 128 p-Isopropyltoluene 0.00048 ND 103 86 - 128 1,4-Dichlorobenzene 0.00042 ND 104 80 - 122 1,2-Dichlorobenzene 0,00039 ND 106 80 - 123 N-Butylbenzene 0,00033 ND 100 84 - 127 1,2-Dibromo-3 -Ch loropropane(DBCP) 0.00067 ND 107 66- 125 1,2,4-Trichlorobenzene 0.00025 ND 107 76 - 1 l7 Naphthalene 0.00047 ND 106 79 - 119 1,2,3-Trichlorobenzene 0,00036 ND 1 109 72 - 1 I8 NIA = Data Not Available Q?AIQC Summary Method: 8270 100/200 PPP, r C FILE NAME: SLC0304-MSI Page I of 2 CLIENT: S&ME (133 S. MAIN ST) Sample ID: 667841-44 INSTILMENT: MS-1 Extraction Method 3550 Date Extracted 113103Y111 Weight Extracted 1L Final Extract Volume 1ML Date Analyzed 03104/11) % Surrogate Recovery 97 84 91 119 98 110 Acceptance Range (21 - 11{1] (10 - 11(1] (35 - 114) (10 - 123) (43 - 116) (33 - 141) LCS Accept. Range MS MS❑ RPD QC LIMITS Compound MDL Method LCS % % Rec. 'Yo Rec. 1n Ik Blank Recover R1aD '�o REC N-Nitrosodimethylanime 0.047 ND 77 66-109 Bis(2-chloroethyl)ether 0.066 ND 89 64-103 Pheftol 0.066 ND 78 65-104 47 44 8 42 12-110 2-Chlorophenal 0.060 ND 87 63-100 57 55 5 40 27-123 1,3-Dichlorohenzeria 0.085 ND 87 63-97 1,4-Dichlorohenzene 0.050 ND 88 64-97 77 77 0 28 36-97 1,2-Dichlorobenzene 0.047 ND 92 61-91 Ber¢Vl Alcohol 0.087 ND 89 46-122 2-Methyiphenol(O-CREOSOL) 0.072 ND 86 52-107 3&4-Medty1pherto1(M&P CREOSOL) 0.063 ND 86 67-1 13 Bis(2-chloroisopropyl)ether 0.063 ND 84 57-97 N-nitrosodi-n-propylamine 0.057 ND 91 58-102 76 70 '.) 38 41-116 Hexachloroethane 0.069 ND 92 62-95 2-Nitraphenol 0.066 ND 93 60-104 274-Dimelhylphenol 0.079 ND 92 60-105 Nitrohenrene 0.072 ND 94 67-108 Isophara$e 0.079 ND 93 43-123 Sis(2.-ch1oroe1hoxy)methane 0.063 ND 88 63-102 Benzoic Acid 0.348 ND 105 40-111 2,4-Dichlorophenol 0.066 ND 99 65-101 1,2,4-Trichlarobenzene 0.047 ND 95 67-100 88 88 1 28 39-98 4-Chloro-3-methylphenol 0.141 ND 98 59-101 fit 61 3 42 23-97 4-Chloroattiline 0.479 ND 83 33-96 HexachloroUntadiene 0.057 ND 98 65-96 2-Me1hylnaphthalene 0.056 ND 95 68-106 Dihenzotitran 0.063 ND 95 66-97 2,4,6-Trichlorophenal 0.044 ND 97 63-109 2,4,5-Trichlorophenol 0.107 ND 94 56-1(15 NIA = Data Not Avaiia6le = OUT OF RANGE Method: 8270 100/201) PPS OCI IFILE NAME: SLC0304-MS1 Page 2 of 2 CLIENT: S& M E ( 133 S. MAIN ST) LCS Acceptr ange QC LIMITS Compound MDL Nlethod LCS % MS RPD mg/kg Blank Recovery [/R Rec. �MS.D /o Rec. 2-Methyl-4,6-Dinitropltenol 0.170 ND 101 46-118 RPD % REC 4-Nitrophenol 0,232 ND 103 58-124 S9 53 9 50 10-80 Hexachlorocyclopentadiene O} 079 ND 88 56-116 2-Chloronaphthalene O.046 ND 89 65-106 Dirn hyl plthalate O,066 ND 96 67-106 Aunaplithylene 0,066 ND 89 68-101 2,6-Dinitroteluenc 0.075 ND 99 63-108 Aeenaphtltene 0.057 ND 91 66-100 74 74 [1 31 46-118 2,4-Dinitrotoluene 0.079 ND 90 65-105 69 66 3 3$ 24-96 PIuorene 0.060 ND 91 62-109 Diethyl phthalate 0.072 ND 97 63-109 4-Chlorophenyl phenyl ether 0,050 ND 73 62-98 2,4-Dinitropheaml 0.188 ND 92 45-110 Axobetucne 0.083 ND 100 56-144 Pent:uhlomphertol 0.129 ND 99 64-109 55 5[I 11 51) 9-103 N-Witrosodiphenylamina 0.066 ND 84 56-105 4-Bromopliertyl pheml ether 0,085 ND 91 64-105 Hexachlorobenxane 0.069 ND 91 67-104 Phenantkene 0.075 ND 88 68-104 Anthracene. 0.072 ND 86 64-104 Di-N-Butyl phthalate 0.097 ND 90 59-113 Pluoranthene 0.085 ND 87 62-11.3 Benzidine 0.049 ND I3 ❑-47 Pyrene 0,038 ND 81 58-114 37 39 4 31 26-127 Benzyl butyl phthalate 0.060 ND 80 62-1 l4 13enca(a)a2ithra=ic 0.050 ND 81 67-110 3.3-Dichlombenzidine 0.122 ND 40 25-107 Chryscnc 0.060 ND 79 67-107 Ris(2-ethyl-hcVl)plitlta late 0.066 ND 96 63-105 Di-N-Oayl plthalate O.079 ND 76 56-115 Benzo(h)llucrantherie 0.122 ND 74 60-116 Benzo(k)tluorcmthene 0.110 ND 76 68-114 Benxo(a)pyrene 0.047 ND 73 65-116 lndeno(1,2,3-cd)pyrene 0.094 ND 84 67-140 Dibenzo(a,h)anthracene 0.088 ND 79 73-131 Benzo(&ki)perylenc 0.097 ND 83 75-133 NIA OA/QC.Summary Method VPH Project: S & ME -133 S. Main St Page 9 of I Sample ID 667841-844 Date Analyzed 02/24/10 % Surrogate Recovery 102 85 Acceptance Limits (70-130) (70-130) LCS MDL Method Trip/Field LCS % Acceptance MS MSD Control Limits 9'�RP�] Control Limitx Compound m Ik Blank Blank Recovery Range C5-C8 Ali hatics 2.84 BQL NIA 97 70-130 100 106 70-130 6 50% C9-C12 Ali hatics 0,90 BQL NIA 83 70-130 86 70-130 14 C9-C10 Aromatics M6 BQL NIA 123 70-130 121 120 70-130 1 50% NIA = Data Not Available OA1OC summary Method EPH Project: S&ME - 133 S. Main Sat Page 1 of 1 Sample 1D 667841-844 Date Analyzed 02/26/ 10 °/o Surrogate Recovery 97 99 :acceptance Limits (40-1.40) (40-140) LCS MDL Method Trip/Field LCS % Acceptance Compound Fng/kp, Blank Blank Recoveryi Range M5 MSD Control Limits %RlxD Central Limits C9-Cl8 Aliphatic 5.30 BQL NIA 97 40-140 84 80 40-140 5 50% 2.40 BQL NIA 114 40-140 95 9' 40-140 5 50% C-19-C36 Aliphatic 4.30 BQL NIA 104 40-140 89 82 40-140 8 5a°/ti C1 i-C22 Aromatics NIA = Data Not Available JOB NAME SUBJECT JOB NO. �V • ('Jr SHEET NO- I DATfE 4+ #. "k /YA NATURAL GAS LINE PROPOSED INJECTION WELL FIELD \ AND APPROXIMATE HORIZONTAL EXTENT OF CONTAMINATED SOIL �~ ~ GAS METER MwLusa� ~ ` FORMER ff'! \ EXCAVATION LIMITS \ FORMER TANK 4J \ LOCATION �4 }tie' 1z° / C \ f v KEY GRAPHIC SCALE SOIL PROBE AND MONITORING WELL LOCATION w is o as SCALE: 7" = W SCALE: AS SHOWN FIGURE NO. DATE: ApRIL 2009 *S&ME SITE MAP DRAWN BY: RaM 133 S. MAIN STREET PROJECT NOS WWW.SMEINC.COM KERNERSVILLE, NORTH CAROLINA 1584-08-051