WQ0004797_Groundwater Monitoring Report November 2020_20201228

Anchor QEA of North Carolina, PLLC ANCHOR
231 Haywood Street
Asheville, North Carolina 28801 kZ QEA
828.281.3350
December 11, 2020
Tracy Wolfe
Lassonde Pappas & Co., Inc.
125 Industrial Park Road
Hendersonville, North Carolina 28792
Re: November 2020 Groundwater Sampling Event
Clement Pappas NC, LLC
Dear Ms. Wolfe,
Anchor QEA of North Carolina, PLLC, is pleased to present the results of the November 2020 water quality
monitoring event at the Clement Pappas NC, LLC (Clement Pappas) facility (the Site), located at
485 Brookside Camp Road in Hendersonville, North Carolina. The company that operates the facility
rebranded to Lassonde Pappas & Company in 2016. However, for permitting purposes, the
Hendersonville facility retains the Clement Pappas NC LLC name that is designated on the property deed.
Groundwater Quality
Anchor QEA performed the groundwater sampling event at the subject facility (the Site) on
November 6, 2020. A Site location map is included in Figure 1. The groundwater sampling event was
performed in accordance with North Carolina Department of Environmental Quality (DEQ) wastewater
irrigation system permit No. WQ0004797 issued September 3, 2015, and renewed May 15, 2020
(referred to as the permit in this letter; effective September 1, 2020, and expires July 31, 2026).
Anchor QEA used low -flow methods to purge and collect groundwater samples from six monitoring
wells: MW-4, MW-5, MW-6, MW-7R, MW-8, and MW-9. Monitoring well MW-9 was installed April 14,
2015, to replace the previously damaged monitoring well MW-2R. Monitoring well MW-5 is an
upgradient (background) monitoring well. The locations of the monitoring wells are shown in Figure 2.
Anchor QEA submitted the groundwater samples to Pace Analytical Services, Inc., a
North Carolina -certified laboratory, for analysis of the parameters specified in the permit, as follows:
• Total organic carbon • Total nitrate
• Chloride • Phosphorous
• Fecal coliform • Total dissolved solids
• Total ammonia • Volatile organic compounds (VOCs) by 6200
Groundwater Elevation
Table 1 summarizes current and historical groundwater elevations from May 2018 to November 2020.
Except for monitoring well MW-9, all monitoring well concrete pads and top -of -well casing elevations
\\ashevillel\Asheville\Projects\Clement Pappas\Reports\2020\November\Files for review\20201211_November 2020 Groundwater Sampling Event Clement Pappas NC, LLC.docx

December 11, 2020
Page 2
were surveyed by Wes Cole Land Surveying, PA, on November 21, 2012. Monitoring well MW-9 was
surveyed by Wes Cole Land Surveying, PA, on May 29, 2015. The surveyed top -of -casing elevations are
indicated in Table 1.
Groundwater Analytical Results
Table 2 summarizes the current and historical groundwater analytical results from May 2018 to
November 2020. During the current sampling event, the parameters analyzed were within the
groundwater standards provided in the permit,' except as follows:
• The nitrate concentration exceeded the permit groundwater standard of 10 milligrams per
liter (mg/L) in the sample collected from one monitoring well, MW-7R (13.0 mg/L) but has
decreased significantly from the previous sampling event.
The Title 15A, North Carolina Administrative Code [NCAC], Subchapter 2L, Section .0202 standard
(2L standard) for total coliform is 1 colony -forming unit per 100 milliliters (1 CFU/100 mQ. There is
not a specific permit limit or 2L standard for fecal coliform; however, total coliform includes fecal
coliform. The following summarizes fecal coliform results from the groundwater monitoring wells:
• Fecal coliform concentrations exceeded the 2L standard for total coliform in monitoring
wells MW-5 (8.0 CFU/100 mQ, MW-6 (3.0 CFU/100 mQ, MW-8 (14.0 CFU/100 mQ, and MW-9
(16.0 CFU/100 mQ.
• Fecal coliform was not detected at or above laboratory detection limits in the samples
collected from monitoring wells MW-4 and MW-7R.
The pH of the samples collected from MW-4 (5.30 standard units [SU]), MW-5 (5.65 SU), MW-6 (5.23
SU), MW-7R (5.54 SU), and MW-9 (4.93 SU) were below the groundwater standard range of 6.5 to 8.5
SU. The sample collected from the background monitoring well, MW-5, has a pH that is similar to the
other groundwater monitoring wells.
Volatile Organic Compounds
Analytical results for VOCs, analyzed by U.S. Environmental Protection Agency Standard Method
620013, are presented in Table 2. In accordance with permit requirements, samples are analyzed for
VOCs annually in November. No VOCs were detected at concentrations above the method detection
limits in monitoring wells MW-4, MW-6, MW-7R, MW-8, or MW-9. VOC concentrations detected in
MW-5 (the background monitoring well for the Site) are summarized as follows:
Two VOCs (tetrachloroethene and trichloroethene) were detected in monitoring well MW-5.
— Tetrachloroethene was detected at a concentration of 0.80 microgram per liter (pg/L),
which exceeds its 2L standard (0.70 pg/L).
Most of the groundwater standards are represented by the 2L standards, with the exception of nitrate and total organic carbon,
which are set in the Wastewater Irrigation System Permit Number WQ0004797.

December 11, 2020
Page 3
— Trichloroethene was detected at a concentration of 1.0 pg/L, which is below the permit
groundwater standard (3.0 pg/L).
— Concentrations of historically detected VOCs decreased during this sampling event to
the lowest level since sampling began.
Surface Water Quality
Beginning in May 2017, Clement Pappas voluntarily collected surface water samples from Mud Creek,
analyzing for the same constituents as those sampled in groundwater. The renewed permit issued in
May 2020 and effective September 2020 requires semiannual sampling of the surface water
locations. Sampling point SW-1 is located upstream of the Site, and sampling point SW-2 is located
downstream of the Site. Sampling locations are shown in Figure 2.
Surface Water Analytical Results
Table 3 summarizes the historical and current surface water analytical results. For the
November 2020 sampling event, no parameters were detected at concentrations above the
associated 15A NCAC 2B surface water standards (2B standards).
Since collection of surface water samples for all permit constituents began in May 2017, nitrate
concentrations have been similar in SW-1 (upstream) and SW-2 (downstream). The fall 2020
sampling showed a similar relationship: upstream sample SW-1 showed a concentration of
0.71 mg/L, and downstream sample SW-2 showed 0.70 mg/L. The results for total organic carbon,
chloride, total dissolved solids (TDS), ammonia, and total phosphorus were also similar for upstream
and downstream samples, indicating the unlikelihood that the Site is impacting Mud Creek. The fecal
coliform concentration was higher in the upstream sample SW-1 (145 CFU/100mL) than the
downstream sample SW-2 (97 CFU/100mL).
The Site irrigation fields have experienced significant flood events since over the last several years.
The regular flooding of Mud Creek and its nutrient loading associated with runoff from agricultural
fields upstream of the facility is suspected to have impacts on Site groundwater.
Discussion
Taking a proactive approach, in 2016 Clement Pappas contracted Nutter and Associates to analyze
the overall health and performance of the land application system to determine ways to improve the
longevity of the system while reducing the likelihood of impacts on groundwater. Based on this work,
Clement Pappas has implemented the following activities:
• To avoid introducing additional nitrogen into soils at the subject facility, Clement Pappas has
implemented the practice of baling harvested fescue and removing it from the irrigation fields,
instead of mowing it and allowing it to decompose.
— Removing the harvested fescue should result in improved vegetative growth, which will
allow the fescue to uptake additional available nitrogen.

December 11, 2020
Page 4
— Additionally, it is expected that removing the harvested fescue will result in greater
assimilation of nitrogen into facility soils and reduce the potential for nitrogen leaching.
All of the samples collected during the November 2020 sampling event were below the permit
standard for nitrate except for MW-7R; however, the nitrate concentration in MW-7R has decreased
significantly since the last monitoring event.
In accordance with the spray irrigation permit WQ0004797, Clement Pappas is required to submit the
following to the DEQ by December 31, 2020 (on or before the last working day of the month
following the sampling month):
• Laboratory analytical reports and chain -of -custody forms (Attachment 1)
• Well sampling logs and the equipment documentation and instrument calibration data sheet
(Attachment 2)
• DEQ GW-59A — Compliance Report Form (Attachment 3)
• DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Form, for each
monitoring well (Attachment 4)
Anchor QEA proposes to complete the next scheduled groundwater and surface water sampling
event in May 2021.
If you have any questions or would like additional information, please do not hesitate to contact me
at [phone] [e-mail].
Sincerely,
/ _/ /J V" �_
Jennifer Verde
Managing Engineer
Attachments
Table 1 Current and Historical Groundwater Elevation Measurements
Table 2 Current and Historical Groundwater Analytical Results
Table 3 Current and Historical Surface Water Analytical Results
Figure 1 Site Location Map
Figure 2 Site Plan Map
Attachment 1 Laboratory Analytical Reports and Chain -of -Custody Forms
Attachment 2 Well Sampling Logs and Instrument Calibration Data Sheet
Attachment 3 DEQ GW-59A — Compliance Report Form
Attachment 4 DEQ GW-59 — Groundwater Quality Monitoring: Compliance Report Forms

Tables

Table 1
Current and Historical Groundwater Elevation Measurements
Well
Identification
MW-4
Screened
Interval
(ft bgs)
Date Measured
Depth to
Groundwater
Top -of-
Casing
Elevation
Top -of -Casing
Height Above
Ground Surface
Groundwater
Elevation
5.0 - 15.0
05/02/2018
8.44
2063.77
2.43
2055.33
11/02/2018
8.00
2055.77
05/21/2019
8.49
2055.28
11/14/2019
8.82
2054.95
05/06/2020
7.98
2055.79
11/06/2020
8.02
2055.75
MW-5
9.0 - 19.0
05/02/2018
8.47
2085.60
3.00
2077.13
11/02/2018
8.23
2077.37
05/21/2019
8.57
2077.03
11/14/2019
8.90
2076.70
05/06/2020
8.28
2077.32
11/06/2020
8.90
2076.70
MW-6
5.0 - 10.0
05/02/2018
5.36
2061.17
3.00
2055.81
11/02/2018
5.03
2056.14
05/21/2019
5.53
2055.64
11/14/2019
5.59
2055.58
05/06/2020
5.41
2055.76
11/06/2020
5.33
2055.84
MW-7R
5.0 - 15.0
05/02/2018
10.99
2062.86
3.00
2051.87
11/02/2018
10.33
2052.53
05/21/2019
10.88
2051.98
11/14/2019
11.33
2051.53
05/06/2020
10.11
2052.75
11/06/2020
10.05
2052.81
MW-8
3.0 - 13.0
05/02/2018
9.39
2060.80
3.00
2051.41
11/02/2018
8.85
2051.95
05/21/2019
9.38
2051.42
11/14/2019
9.75
2051.05
05/06/2020
8.54
2052.26
11/06/2020
8.37
2052.43
MW-9
3.0 - 13.0
05/02/2018
5.07
2060.23
1.44
2055.16
11/02/2018
4.55
2055.68
05/21/2019
4.89
2055.34
11/14/2019
5.15
2055.08
05/06/2020
4.30
2055.93
11/06/2020
4.10
2056.13
November 2020 Groundwater Sampling Event Page 1 of 2
Clement Pappas, Hendersonville, North Carolina December 2020

Table 1
Current and Historical Groundwater Elevation Measurements
Notes:
Top -of -casing elevations: MW-5 through MW-8 top -of -casing elevations are based upon a survey by Hill and Associates
Surveyors, dated January 10, 2002, through May 2012. MW-2R and MW-4 top -of -casing elevations are based upon
differential level measurements made by Altamont Environmental, Inc., on June 26, 2006, through May 2012. The top -of -
casing elevations for the monitoring wells were resurveyed on November 21, 2012, by Wes Cole Land Surveying. The top -of -
casing elevations for MW-9 were surveyed on May 29, 2015, by Wes Cole Land Surveying.
ft bgs: feet below ground surface
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective
on September 1, 2020.
November 2020 Groundwater Sampling Event Page 2 of 2
Clement Pappas, Hendersonville, North Carolina December 2020

Table 2
Current and Historical Groundwater Analytical Results
Sample
Name
Sample Date
O.
,�
O
p
S
F V
O
V
£
0
LL
Z
V)
>
O
F V)
O
£
Q
o
s
N-
0.
F
a
a
d
0
F
a
s
i+
77
O
O
H
a
a=i
N
S
V_
V M
a
a0i
L
y V_
F M
M
L
O
VT
i
t
O
L
O
0V
(SU)
(mg/L)
(mg/L)
(CFOs per
100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
(Ng/L)
2L Groundwater Standards
6.5 - 8.5
10
250
1
NL
500
500
7.5
NL
0.7
3
70
700
0.03
7
Groundwater Standards Provided in Permit No. WQ0004797
6.5 - 8.5
10
250
NL
10
250
500
7.5
NL
0.7
3
70
100
0.03
7
05/02/2018
5.86
3.0
10.0
<1.0
2.1
NA
167
<0.020
0.11
NR
11/02/2018
5.47
3.6
9.0
<10.0
0.48
NA
137
<0.10
0.070
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW-4
05/21/2019
5.81
3.0
11.3
<1.0
3.3
NA
170
<0.050
0.044J
NR
11/14/2019
5.82
3.7
11
<1.0
0.42
NA
190
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/06/2020
5.70
2.3
7.6
<1.0
3.7
172
<0.10
<0.050
NR
11/06/2020
5.30
2.8
6.9
<1.0
0.73
148
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.69
5.7
16.1
2.0
0.0
NA
90
<0.10
0.097
NR
11/02/2018
5.53
5.1
23.9
<10.0
<0.020
NA
86
<0.10
0.085
39.1 6.0 6.7 1 < 0.50 < 1.0 < 0.50
MW-5
05/21/2019
5.68
9.4
26.8
7.0
0.1
NA
91
<0.050
0.120
NR
11/14/2019
5.59
6.0
20.1
7.0
0.055
NA
202
<0.10
0.081
22.4 4.4 5.0 I < 0.50 < 1.0 < 0.50
05/06/2020
5.90
6.9
7.3
8.0
<0.040
116
<0.10
0.083
NR
11/06/2020
5.65
4.6
6.9
8.0
< 0.040
61.0
<0.10
0.060
0.80 1.0 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.28
2.3
9.4
1.0
0.1
NA
81
<0.10
0.097
NR
11/02/2018
5.02
2.5
10.1
69.0
0.6
NA
88
<0.10
0.057
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW-6
05/21/2019
5.46
3.3
11.3
23.0
0.4
NA
78
<0.050
0.068
NR
11/14/2019
5.30
2.9
9.3
44.0
0.56
NA
342
<0.10
0.052
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/06/2020
5.38
2.0
9.7
3.0
1.1
96.0
<0.10
<0.050
NR
11/06/2020
5.23
2.6
12.5
3.0
3.2
139
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.41
3.2
22.6
<2.0
15.5
NA
207
<0.10
0.320
NR
11/02/2018
5.48
5.3
20.2
<10.0
15.7
NA
243
<0.10
0.170
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW-7R
05/21/2019
5.58
3.0
29.0
<2.0
20.2
NA
234
<0.050
0.130
NR
11/14/2019
6.42
3.0
22.7
<2.0
17.1
NA
73
<0.10
0.084
< 0.50 < 0.50 < 0.50 < 0.50 < 1.0 < 0.50
05/06/2020
5.20
1.2
20.9
<1.0
21.5
219
219
<0.10
<0.050
NR
11/06/2020
5.54
1.7
17.8
<1.0
13.0
205
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
6.74
10.8
12.9
<2.0
14.4
NA
548
<0.10
0.190
NR
11/02/2018
6.52
9.5
8.0
19.0
6.8
NA
351
<0.10
0.250
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW 8
05/21/2019
6.89
7.9
7.3
<10.0
6.2
NA
249
<0.050
0.290
NR
11/14/2019
6.71
7.7
7.2
2.0
1.2
NA
51
<0.10
0.10
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/06/2020
6.41
2.7
2.8
<1.0
3.6
139
<0.10
<0.050
NR
11/06/2020
6.34
2.8
2.3
14.0
2.4
127
<0.10
<0.050
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
05/02/2018
5.52
4.6
4.9
<2.0
0.6
NA
69
<0.10
0.370
NR
11/02/2018
5.11
8.4
5.8
<10.0
0.6
NA
88
<0.10
0.470
< 0.50 < 0.50 < 0.50 1 < 0.50 < 1.0 < 0.50
MW 9
05/21/2019
5.64
7.2
4.6
<10.0
0.2
NA
80
<0.050
0.230
NR
11/14/2019
5.57
6.1
5.4
<1.0
0.89
NA
56
<0.10
0.076
< 0.50 < 0.50 1 < 0.50 1 < 0.50 1 < 1.0 1 < 0.50
05/06/2020
5.52
5.9
1.8
<1.0
<0.040
68.0
<0.10
0.099
NR
11/06/2020
4.93
4.5
1.4
16.0
0.043
88.0
<0.10
1 0.095
< 0.50 1 < 0.50 1 < 0.50 1 < 0.50 1 < 1.0 1 < 0.50
Notes:
2L standards are set in North Carolina Administrative Code, Title 15A Subchapter 2L - Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Total organic carbon and nitrate standards are set in
Wastewater Irrigation System Permit Number WQ0004797. There is no defined 2L standard for fecal coliform; therefore, the standard listed is for "total coliform."
Bolded values indicate a concentration above the respective permit groundwater standard or outside the permit groundwater standard range.
pH is analyzed by Anchor QEA of North Carolina, PLLC; NC lab certification number 5445
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
< indicates that the constituent concentration was not detected above the method detection limit
pg/L: micrograms per liter
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliter
NL : No 2L standard exists.
NR: not reported
SU: standard unit
November 2020 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina December 2020

Table 3
Current and Historical Surface Water Analytical Results
G.
C
Oam
L
H 0 U
L
U
=
i
O
V 4V 0
LL U
a
Z
�O
>
.a
IA
VI
C Vf
R
0
1=
Q
iA
3
L
S
iA
0
a
(CFUs per
Sample Name
Sample Date
(SU)
(mg/L)
(mg/L)
100 mL)
(mg/L)
(mg/L)
(mg/L)
(mg/L)
28 Standard
6.5 - 8.5
NL
230
200
NL
NL
NL
NL
5/2/2018
6.88
1.5
4.8
53.0
0.74
54.0
<0.10
0.044 J
11/2/2018
6.28
2.9
5.1
780
0.72
54.0
<0.10
0.077
SW-1
5/21/2019
7.02
1.6
5.0
98.0
0.75
42.0
<0.050
0.067
(Upstream)
11/14/2019
6.76
1.9
5.3
118
0.83
57.0
<0.10
0.1
5/6/2020
7.20
1.6
4.6
290
0.76
49.0
<0.10
0.092
11/6/2020
5.83
1.6
4.4
145
0.71
56.0
<0.10
< 0.050
5/2/2018
6.98
1.4
4.4
118.0
0.72
51.0
0.052 J
0.045 J
11 /2/2018
7.08
2.9
4.6
940.0
0.75
53.0
0.099 J
0.076
SW-2
5/21/2019
6.99
1.6
4.9
200.0
0.76
47.0
<0.050
0.068
11/14/2019
7.01
1.9
5.4
127
0.82
83.0
<0.10
0.089
(Downstream)
5/6/2020
6.67
1.7
4.2
420
0.72
53.0
<0.10
<0.050
11/6/2020
6.19
1.6
4.4
97.0
0.70
59.0
<0.10
<0.050
Notes:
2B standard: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and
Wetland Standards (last amended in September 2017), or the standard obtained from the U.S. Environmental Protection Agency Nationally Recommended Water Quality
Criteria for Aquatic Life and Human Health.
Bolded values indicate a concentration equal to or above the respective 2B standard or a value outside the 2B standard range.
< indicates that the constituent concentration was not detected above the laboratory reporting limit
Monitoring is performed in accordance with Permit No. WQ0004797 issued to Clement Pappas on May 15, 2020 and effective on September 1, 2020.
CFU: coliform-forming unit
J: The concentration is above the adjusted method detection limit and below the adjusted reporting limit and is therefore considered an estimate.
mg/L: milligrams per liter
mL: milliliters
NL: No NC21L standard exists
SU: standard unit
November 2020 Groundwater Sampling Event Page 1 of 1
Clement Pappas, Hendersonville, North Carolina December 2020

Figures

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1 / /�� :r, III \``, �/ 1 I l - `' � � ' _ •L.,, ;. ® --

Attachment 1
Laboratory Analytical Reports and
Chain -of -Custody Forms

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
November 16, 2020
Jennifer Verde
Anchor QEA
231 Haywood Street
Asheville, NC 28801
RE: Project: Lassonde Pappas
Pace Project No.: 92504561
Dear Jennifer Verde:
Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2020. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(Z/� ` -
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: Lassonde Pappas
Pace Project No.: 92504561
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Lassonde Pappas
92504561
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
92504561001
MW-4
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561002
MW-5
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561003
MW-6
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561004
MW-7R
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561005
MW-8
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Lassonde Pappas
Pace Project No.:
92504561
Analytes
Lab lD
Sample ID
Method
Analysts
Reported
Laboratory
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561006
MW-9
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561007
SW-1
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92504561008
SW-2
SM 6200B
SAS
63
PASI-C
SM 2540C-2011
ALP
1
PASI-A
SM 9222D-2006
ECH
1
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 365.1 Rev 2.0 1993
MDW
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 00:42
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 00:42
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 00:42
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 00:42
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 00:42
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 00:42
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 00:42
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 00:42
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 00:42
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 00:42
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 00:42
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 00:42
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 00:42
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 00:42
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 00:42
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 00:42
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 00:42
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 00:42
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 00:42
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 00:42
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 00:42
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 00:42
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 00:42
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 00:42
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 00:42
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 00:42
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 00:42
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 00:42
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 00:42
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 00:42
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 00:42
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 00:42
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 00:42
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 00:42
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 00:42
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 00:42
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 00:42
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 00:42
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 00:42
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 00:42
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 00:42
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 00:42
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 00:42
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 00:42
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 00:42
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 00:42
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 00:42
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 00:42
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 00:42
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 00:42
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
96 %
70-130
1
11/11/20 00:42
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/11/20 00:42
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 00:42
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
148 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:35
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.73 mg/L
0.040
1
11/07/20 03:03
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:12
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
6.9 mg/L
1.0
1
11/09/20 23:41
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-4 Lab ID: 92504561001 Collected: 11/06/20 13:21 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 2.8 mg/L 1.0 1 11/12/20 17:07 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:00
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:00
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:00
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:00
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:00
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:00
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 01:00
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:00
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:00
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:00
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:00
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:00
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:00
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:00
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:00
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:00
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:00
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:00
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:00
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:00
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:00
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:00
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:00
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:00
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:00
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:00
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:00
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:00
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:00
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:00
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:00
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:00
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:00
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:00
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
0.80 ug/L
0.50
1
11/11/20 01:00
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:00
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:00
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:00
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:00
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:00
79-00-5
Trichloroethene
1.0 ug/L
0.50
1
11/11/20 01:00
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:00
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:00
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:00
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:00
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:00
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:00
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:00
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
98 %
70-130
1
11/11/20 01:00
17060-07-0
4-Bromofluorobenzene (S)
95 %
70-130
1
11/11/20 01:00
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 01:00
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
61.0 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
8.0 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:40
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND mg/L
0.040
1
11/07/20 03:00
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.060 mg/L
0.050
1
11/09/20 19:00 11/10/20 21:16
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
6.9 mg/L
1.0
1
11/09/20 23:42
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-5 Lab ID: 92504561002 Collected: 11/06/20 13:15 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 4.6 mg/L 1.0 1 11/12/20 17:31 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:18
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:18
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:18
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:18
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:18
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:18
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:18
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:18
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 01:18
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:18
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:18
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:18
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:18
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:18
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:18
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:18
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:18
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:18
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:18
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:18
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:18
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:18
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:18
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:18
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:18
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:18
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:18
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:18
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:18
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:18
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:18
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:18
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:18
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:18
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:18
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:18
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:18
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:18
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:18
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:18
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:18
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:18
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:18
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:18
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:18
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:18
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 01:18
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:18
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:18
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:18
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:18
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:18
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 01:18
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:18
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:18
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:18
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:18
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:18
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:18
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:18
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
11/11/20 01:18
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/11/20 01:18
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 01:18
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
139 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
3.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:47
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
3.2 mg/L
0.040
1
11/07/20 02:58
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:18
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
12.5 mg/L
1.0
1
11/09/20 23:43
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-6 Lab ID: 92504561003 Collected: 11/06/20 10:34 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 2.6 mg/L 1.0 1 11/12/20 18:44 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:35
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:35
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:35
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:35
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:35
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:35
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 01:35
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:35
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:35
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:35
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:35
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:35
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:35
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:35
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:35
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:35
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:35
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:35
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:35
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:35
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:35
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:35
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:35
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:35
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:35
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:35
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:35
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:35
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:35
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:35
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:35
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:35
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 01:35
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:35
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:35
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:35
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:35
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:35
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 01:35
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:35
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:35
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:35
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:35
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:35
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:35
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:35
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
11/11/20 01:35
17060-07-0
4-Bromofluorobenzene (S)
98 %
70-130
1
11/11/20 01:35
460-00-4
Toluene-d8 (S)
102 %
70-130
1
11/11/20 01:35
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
205 mg/L
25.0
1
11/08/20 11:43
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation
Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:52
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
13.0 mg/L
0.40
10
11/07/20 03:19
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:18
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
17.8 mg/L
1.0
1
11/09/20 23:44
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-7R Lab ID: 92504561004 Collected: 11/06/20 08:49 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 1.7 mg/L 1.0 1 11/12/20 20:09 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-8 Lab ID: 92504561005 Collected: 11/06/20 09:27 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 01:53
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 01:53
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 01:53
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 01:53
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 01:53
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 01:53
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:53
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 01:53
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 01:53
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 01:53
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 01:53
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 01:53
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 01:53
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 01:53
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:53
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 01:53
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 01:53
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 01:53
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 01:53
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 01:53
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:53
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:53
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 01:53
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 01:53
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:53
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 01:53
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:53
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:53
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 01:53
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:53
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:53
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 01:53
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:53
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:53
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 01:53
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 01:53
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 01:53
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 01:53
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 01:53
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 01:53
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 01:53
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 01:53
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 01:53
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 01:53
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:53
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 01:53
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-8 Lab ID: 92504561005 Collected: 11/06/20 09:27 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 01:53
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 01:53
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:53
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 01:53
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:53
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 01:53
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 01:53
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 01:53
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 01:53
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:53
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 01:53
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 01:53
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 01:53
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 01:53
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
100 %
70-130
1
11/11/20 01:53
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/11/20 01:53
460-00-4
Toluene-d8 (S)
100 %
70-130
1
11/11/20 01:53
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
127 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
14.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:53
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
2.4 mg/L
0.040
1
11/07/20 02:55
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:19
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
2.3 mg/L
1.0
1
11/09/20 23:45
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-8 Lab ID: 92504561005 Collected: 11/06/20 09:27 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 2.8 mg/L 1.0 1 11/12/20 20:33 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-9 Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 02:11
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 02:11
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 02:11
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 02:11
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 02:11
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 02:11
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:11
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:11
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 02:11
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 02:11
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 02:11
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 02:11
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 02:11
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 02:11
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:11
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:11
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 02:11
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 02:11
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 02:11
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 02:11
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:11
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:11
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:11
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 02:11
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:11
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:11
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:11
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:11
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:11
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:11
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:11
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:11
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:11
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:11
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:11
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 02:11
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 02:11
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 02:11
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 02:11
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 02:11
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 02:11
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 02:11
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 02:11
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 02:11
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:11
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:11
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-9 Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 02:11
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 02:11
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:11
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:11
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:11
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:11
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 02:11
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 02:11
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 02:11
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:11
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:11
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 02:11
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 02:11
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 02:11
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99 %
70-130
1
11/11/20 02:11
17060-07-0
4-Bromofluorobenzene (S)
96 %
70-130
1
11/11/20 02:11
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 02:11
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
88.0 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
16.0 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:54
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.043 mg/L
0.040
1
11/07/20 02:59
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.095 mg/L
0.050
1
11/09/20 19:00 11/10/20 21:20
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
1.4 mg/L
1.0
1
11/09/20 23:47
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: MW-9 Lab ID: 92504561006 Collected: 11/06/20 12:16 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 4.5 mg/L 1.0 1 11/12/20 20:58 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-1 Lab ID: 92504561007 Collected: 11/06/20 14:00 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 02:29
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 02:29
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 02:29
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 02:29
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 02:29
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 02:29
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 02:29
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 02:29
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 02:29
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 02:29
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 02:29
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:29
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:29
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 02:29
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 02:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 02:29
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 02:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:29
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 02:29
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:29
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:29
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:29
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:29
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:29
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 02:29
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 02:29
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 02:29
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 02:29
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 02:29
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 02:29
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 02:29
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 02:29
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:29
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:29
79-34-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-1 Lab ID: 92504561007 Collected: 11/06/20 14:00 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 02:29
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 02:29
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:29
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:29
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:29
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:29
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 02:29
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 02:29
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 02:29
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:29
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:29
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 02:29
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 02:29
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 02:29
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
11/11/20 02:29
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/11/20 02:29
460-00-4
Toluene-d8 (S)
100 %
70-130
1
11/11/20 02:29
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
56.0 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
145 CFU/100 mL
1.0
1
11/06/20 17:08 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:56
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.71 mg/L
0.040
1
11/07/20 03:07
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:20
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.4 mg/L
1.0
1
11/09/20 23:48
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-1 Lab ID: 92504561007 Collected: 11/06/20 14:00 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 11/12/20 21:28 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical
Services - Charlotte
Benzene
ND
ug/L
0.50
1
11/11/20 02:47
71-43-2
Bromobenzene
ND
ug/L
0.50
1
11/11/20 02:47
108-86-1
Bromochloromethane
ND
ug/L
0.50
1
11/11/20 02:47
74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
11/11/20 02:47
75-27-4
Bromoform
ND
ug/L
0.50
1
11/11/20 02:47
75-25-2
Bromomethane
ND
ug/L
5.0
1
11/11/20 02:47
74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
135-98-8
tert-Butyl benzene
ND
ug/L
0.50
1
11/11/20 02:47
98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
11/11/20 02:47
56-23-5
Chlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
108-90-7
Chloroethane
ND
ug/L
1.0
1
11/11/20 02:47
75-00-3
Chloroform
ND
ug/L
0.50
1
11/11/20 02:47
67-66-3
Chloromethane
ND
ug/L
1.0
1
11/11/20 02:47
74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:47
95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
11/11/20 02:47
106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
11/11/20 02:47
96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
11/11/20 02:47
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
11/11/20 02:47
106-93-4
Dibromomethane
ND
ug/L
0.50
1
11/11/20 02:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
11/11/20 02:47
106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
11/11/20 02:47
75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:47
75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
11/11/20 02:47
107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
11/11/20 02:47
156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
11/11/20 02:47
594-20-7
1,1-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
0.50
1
11/11/20 02:47
10061-02-6
Diisopropyl ether
ND
ug/L
0.50
1
11/11/20 02:47
108-20-3
Ethylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
11/11/20 02:47
87-68-3
Isopropylbenzene (Cumene)
ND
ug/L
0.50
1
11/11/20 02:47
98-82-8
Methylene Chloride
ND
ug/L
2.0
1
11/11/20 02:47
75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
11/11/20 02:47
1634-04-4
Naphthalene
ND
ug/L
2.0
1
11/11/20 02:47
91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
11/11/20 02:47
103-65-1
Styrene
ND
ug/L
0.50
1
11/11/20 02:47
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:47
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
11/11/20 02:47
79-34-5
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 48

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ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
Tetrachloroethene
ND ug/L
0.50
1
11/11/20 02:47
127-18-4
Toluene
ND ug/L
0.50
1
11/11/20 02:47
108-88-3
1,2,3-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:47
87-61-6
1,2,4-Trichlorobenzene
ND ug/L
2.0
1
11/11/20 02:47
120-82-1
1,1,1-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:47
71-55-6
1,1,2-Trichloroethane
ND ug/L
0.50
1
11/11/20 02:47
79-00-5
Trichloroethene
ND ug/L
0.50
1
11/11/20 02:47
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/11/20 02:47
75-69-4
1,2,3-Trichloropropane
ND ug/L
0.50
1
11/11/20 02:47
96-18-4
1,2,4-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:47
95-63-6
1,3,5-Trimethylbenzene
ND ug/L
0.50
1
11/11/20 02:47
108-67-8
Vinyl chloride
ND ug/L
1.0
1
11/11/20 02:47
75-01-4
m&p-Xylene
ND ug/L
1.0
1
11/11/20 02:47
179601-23-1
o-Xylene
ND ug/L
0.50
1
11/11/20 02:47
95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
101 %
70-130
1
11/11/20 02:47
17060-07-0
4-Bromofluorobenzene (S)
97 %
70-130
1
11/11/20 02:47
460-00-4
Toluene-d8 (S)
101 %
70-130
1
11/11/20 02:47
2037-26-5
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
59.0 mg/L
25.0
1
11/08/20 11:44
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
97.0 CFU/100 mL
1.0
1
11/06/20 15:47 11/07/20 15:33
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L
0.10
1
11/10/20 12:57
7664-41-7
353.2 Nitrogen, NO2/1403 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
0.70 mg/L
0.040
1
11/07/20 02:56
14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
ND mg/L
0.050
1
11/09/20 19:00 11/10/20 21:21
7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
4.4 mg/L
1.0
1
11/09/20 23:50
16887-00-6
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 27 of 48

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2225 Riverside Dr.
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[phone]
ANALYTICAL RESULTS
Project: Lassonde Pappas
Pace Project No.: 92504561
Sample: SW-2 Lab ID: 92504561008 Collected: 11/06/20 09:52 Received: 11/06/20 14:55 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 11/12/20 22:04 7440-44-0
Date: 11/16/2020 01:39 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 28 of 48

leAnalyiical
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Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579267 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3064425
Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,1-Trichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1,2-Trichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
1,1-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
1,2,3-Trichlorobenzene
ug/L
ND
2.0
11/11/20 00:06
1,2,3-Trichloropropane
ug/L
ND
0.50
11/11/20 00:06
1,2,4-Trichlorobenzene
ug/L
ND
2.0
11/11/20 00:06
1,2,4-Trimethylbenzene
ug/L
ND
0.50
11/11/20 00:06
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
11/11/20 00:06
1,2-Dibromoethane (EDB)
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichloroethane
ug/L
ND
0.50
11/11/20 00:06
1,2-Dichloropropane
ug/L
ND
0.50
11/11/20 00:06
1,3,5-Trimethylbenzene
ug/L
ND
0.50
11/11/20 00:06
1,3-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
1,3-Dichloropropane
ug/L
ND
0.50
11/11/20 00:06
1,4-Dichlorobenzene
ug/L
ND
0.50
11/11/20 00:06
2,2-Dichloropropane
ug/L
ND
0.50
11/11/20 00:06
2-Chlorotoluene
ug/L
ND
0.50
11/11/20 00:06
4-Chlorotoluene
ug/L
ND
0.50
11/11/20 00:06
Benzene
ug/L
ND
0.50
11/11/20 00:06
Bromobenzene
ug/L
ND
0.50
11/11/20 00:06
Bromochloromethane
ug/L
ND
0.50
11/11/20 00:06
Bromodichloromethane
ug/L
ND
0.50
11/11/20 00:06
Bromoform
ug/L
ND
0.50
11/11/20 00:06
Bromomethane
ug/L
ND
5.0
11/11/20 00:06
Carbon tetrachloride
ug/L
ND
0.50
11/11/20 00:06
Chlorobenzene
ug/L
ND
0.50
11/11/20 00:06
Chloroethane
ug/L
ND
1.0
11/11/20 00:06
Chloroform
ug/L
ND
0.50
11/11/20 00:06
Chloromethane
ug/L
ND
1.0
11/11/20 00:06
cis-1,2-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
cis-1,3-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
Dibromochloromethane
ug/L
ND
0.50
11/11/20 00:06
Dibromomethane
ug/L
ND
0.50
11/11/20 00:06
Dichlorodifluoromethane
ug/L
ND
0.50
11/11/20 00:06
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 48

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
METHOD BLANK: 3064425 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Diisopropyl ether
ug/L
ND
0.50
11/11/20 00:06
Ethylbenzene
ug/L
ND
0.50
11/11/20 00:06
Hexachloro-1,3-butadiene
ug/L
ND
2.0
11/11/20 00:06
Isopropylbenzene (Cumene)
ug/L
ND
0.50
11/11/20 00:06
m&p-Xylene
ug/L
ND
1.0
11/11/20 00:06
Methyl-tert-butyl ether
ug/L
ND
0.50
11/11/20 00:06
Methylene Chloride
ug/L
ND
2.0
11/11/20 00:06
n-Butylbenzene
ug/L
ND
0.50
11/11/20 00:06
n-Propylbenzene
ug/L
ND
0.50
11/11/20 00:06
Naphthalene
ug/L
ND
2.0
11/11/20 00:06
o-Xylene
ug/L
ND
0.50
11/11/20 00:06
sec-Butylbenzene
ug/L
ND
0.50
11/11/20 00:06
Styrene
ug/L
ND
0.50
11/11/20 00:06
tert-Butyl benzene
ug/L
ND
0.50
11/11/20 00:06
Tetrachloroethene
ug/L
ND
0.50
11/11/20 00:06
Toluene
ug/L
ND
0.50
11/11/20 00:06
trans-1,2-Dichloroethene
ug/L
ND
0.50
11/11/20 00:06
trans- 1,3-Dichloropropene
ug/L
ND
0.50
11/11/20 00:06
Trichloroethene
ug/L
ND
0.50
11/11/20 00:06
Trichlorofluoromethane
ug/L
ND
1.0
11/11/20 00:06
Vinyl chloride
ug/L
ND
1.0
11/11/20 00:06
1,2-Dichloroethane-d4 (S)
%
96
70-130
11/11/20 00:06
4-Bromofluorobenzene (S)
%
96
70-130
11/11/20 00:06
Toluene-d8 (S)
%
100
70-130
11/11/20 00:06
LABORATORY CONTROL SAMPLE:
Parameter
3064426
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.7
105
60-140
1,1,1-Trichloroethane
ug/L
50
49.5
99
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
50.9
102
60-140
1,1,2-Trichloroethane
ug/L
50
50.0
100
60-140
1,1-Dichloroethane
ug/L
50
49.2
98
60-140
1,1-Dichloroethene
ug/L
50
50.7
101
60-140
1,1-Dichloropropene
ug/L
50
48.9
98
60-140
1,2,3-Trichlorobenzene
ug/L
50
52.9
106
60-140
1,2,3-Trichloropropane
ug/L
50
49.2
98
60-140
1,2,4-Trichlorobenzene
ug/L
50
55.4
111
60-140
1,2,4-Trimethylbenzene
ug/L
50
52.1
104
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
54.7
109
60-140
1,2-Dibromoethane (EDB)
ug/L
50
51.4
103
60-140
1,2-Dichlorobenzene
ug/L
50
53.9
108
60-140
1,2-Dichloroethane
ug/L
50
44.7
89
60-140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48

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2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
LABORATORY CONTROL SAMPLE:
Parameter
3064426
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloropropane
ug/L
50
50.3
101
60-140
1,3,5-Trimethylbenzene
ug/L
50
51.8
104
60-140
1,3-Dichlorobenzene
ug/L
50
53.7
107
60-140
1,3-Dichloropropane
ug/L
50
52.0
104
60-140
1,4-Dichlorobenzene
ug/L
50
53.7
107
60-140
2,2-Dichloropropane
ug/L
50
47.8
96
60-140
2-Chlorotoluene
ug/L
50
52.8
106
60-140
4-Chlorotoluene
ug/L
50
50.7
101
60-140
Benzene
ug/L
50
50.1
100
60-140
Bromobenzene
ug/L
50
50.2
100
60-140
Bromochloromethane
ug/L
50
49.1
98
60-140
Bromodichloromethane
ug/L
50
49.6
99
60-140
Bromoform
ug/L
50
50.6
101
60-140
Bromomethane
ug/L
50
56.1
112
60-140
Carbon tetrachloride
ug/L
50
46.8
94
60-140
Chlorobenzene
ug/L
50
51.1
102
60-140
Chloroethane
ug/L
50
39.1
78
60-140
Chloroform
ug/L
50
51.3
103
60-140
Chloromethane
ug/L
50
41.6
83
60-140
cis-1,2-Dichloroethene
ug/L
50
48.5
97
60-140
cis-1,3-Dichloropropene
ug/L
50
52.1
104
60-140
Dibromochloromethane
ug/L
50
54.2
108
60-140
Dibromomethane
ug/L
50
52.4
105
60-140
Dichlorodifluoromethane
ug/L
50
37.3
75
60-140
Diisopropyl ether
ug/L
50
47.7
95
60-140
Ethylbenzene
ug/L
50
50.0
100
60-140
Hexachloro-1,3-butadiene
ug/L
50
49.4
99
60-140
Isopropylbenzene (Cumene)
ug/L
50
53.1
106
60-140
m&p-Xylene
ug/L
100
102
102
60-140
Methyl-tert-butyl ether
ug/L
50
49.4
99
60-140
Methylene Chloride
ug/L
50
46.6
93
60-140
n-Butylbenzene
ug/L
50
53.1
106
60-140
n-Propylbenzene
ug/L
50
51.2
102
60-140
Naphthalene
ug/L
50
55.8
112
60-140
o-Xylene
ug/L
50
51.0
102
60-140
sec-Butylbenzene
ug/L
50
50.7
101
60-140
Styrene
ug/L
50
52.7
105
60-140
tert-Butyl benzene
ug/L
50
44.3
89
60-140
Tetrachloroethene
ug/L
50
50.4
101
60-140
Toluene
ug/L
50
49.2
98
60-140
trans-1,2-Dichloroethene
ug/L
50
48.8
98
60-140
trans- 1,3-Dichloropropene
ug/L
50
51.0
102
60-140
Trichloroethene
ug/L
50
50.6
101
60-140
Trichlorofluoromethane
ug/L
50
39.3
79
60-140
Vinyl chloride
ug/L
50
42.4
85
60-140
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 48

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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
LABORATORY CONTROL SAMPLE: 3064426
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits
Toluene-d8 (S) % 98 70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3064427
MS
92504571003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3064428
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
4000
4000
4320
4180
108
104
60-140
3
1,1,1-Trichloroethane
ug/L
ND
4000
4000
4300
4290
108
107
60-140
0
1,1,2,2-Tetrachloroethane
ug/L
ND
4000
4000
3920
3900
98
97
60-140
0
1,1,2-Trichloroethane
ug/L
ND
4000
4000
4170
4070
104
102
60-140
2
1,1-Dichloroethane
ug/L
ND
4000
4000
4080
4150
102
104
60-140
2
1,1-Dichloroethene
ug/L
ND
4000
4000
4590
4630
115
116
60-140
1
1,1-Dichloropropene
ug/L
ND
4000
4000
4290
4300
107
108
60-140
0
1,2,3-Trichlorobenzene
ug/L
ND
4000
4000
4060
4170
102
104
60-140
3
1,2,3-Trichloropropane
ug/L
ND
4000
4000
3890
3920
97
98
60-140
1
1,2,4-Trichlorobenzene
ug/L
ND
4000
4000
4270
4270
107
107
60-140
0
1,2,4-Trimethylbenzene
ug/L
1180
4000
4000
5580
5540
110
109
60-140
1
1,2-Dibromo-3-chloropropane
ug/L
ND
4000
4000
3960
3960
99
99
60-140
0
1,2-Dibromoethane (EDB)
ug/L
358
4000
4000
4550
4510
105
104
60-140
1
1,2-Dichlorobenzene
ug/L
ND
4000
4000
4310
4290
108
107
60-140
0
1,2-Dichloroethane
ug/L
177
4000
4000
3810
3850
91
92
60-140
1
1,2-Dichloropropane
ug/L
ND
4000
4000
4270
4300
107
107
60-140
1
1,3,5-Trimethylbenzene
ug/L
ND
4000
4000
4750
4740
119
118
60-140
0
1,3-Dichlorobenzene
ug/L
ND
4000
4000
4380
4380
109
109
60-140
0
1,3-Dichloropropane
ug/L
ND
4000
4000
4170
4180
104
104
60-140
0
1,4-Dichlorobenzene
ug/L
ND
4000
4000
4350
4340
109
109
60-140
0
2,2-Dichloropropane
ug/L
ND
4000
4000
3440
3470
86
87
60-140
1
2-Chlorotoluene
ug/L
ND
4000
4000
4420
4370
111
109
60-140
1
4-Chlorotoluene
ug/L
ND
4000
4000
4280
4320
107
108
60-140
1
Benzene
ug/L
4730
4000
4000
8930
9240
105
113
60-140
3
Bromobenzene
ug/L
ND
4000
4000
4230
4160
106
104
60-140
2
Bromochloromethane
ug/L
ND
4000
4000
4060
4020
102
101
60-140
1
Bromodichloromethane
ug/L
ND
4000
4000
4070
4040
102
101
60-140
1
Bromoform
ug/L
ND
4000
4000
3710
3740
93
93
60-140
1
Bromomethane
ug/L
ND
4000
4000
4930
5050
123
126
60-140
2
Carbon tetrachloride
ug/L
ND
4000
4000
4170
4300
104
107
60-140
3
Chlorobenzene
ug/L
ND
4000
4000
4260
4230
107
106
60-140
1
Chloroethane
ug/L
ND
4000
4000
3860
4020
97
101
60-140
4
Chloroform
ug/L
ND
4000
4000
4300
4040
107
101
60-140
6
Chloromethane
ug/L
ND
4000
4000
3510
3680
88
92
60-140
5
cis-1,2-Dichloroethene
ug/L
ND
4000
4000
4160
4120
104
103
60-140
1
cis-1,3-Dichloropropene
ug/L
ND
4000
4000
4040
4090
101
102
60-140
1
Dibromochloromethane
ug/L
ND
4000
4000
4240
4110
106
103
60-140
3
Dibromomethane
ug/L
ND
4000
4000
4190
4250
105
106
60-140
1
Dichlorodifluoromethane
ug/L
ND
4000
4000
3740
3720
94
93
60-140
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 32 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3064427
MS
92504571003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3064428
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Diisopropyl ether
ug/L
ND
4000
4000
3870
3950
96
98
60-140
2
Ethylbenzene
ug/L
1140
4000
4000
5420
5410
107
107
60-140
0
Hexachloro-1,3-butadiene
ug/L
ND
4000
4000
4100
4020
102
101
60-140
2
Isopropylbenzene (Cumene)
ug/L
ND
4000
4000
4550
4560
114
114
60-140
0
m&p-Xylene
ug/L
5010
8000
8000
13600
13900
107
111
60-140
2
Methyl-tert-butyl ether
ug/L
ND
4000
4000
3980
3910
100
98
60-140
2
Methylene Chloride
ug/L
ND
4000
4000
3760
3850
94
96
60-140
2
n-Butylbenzene
ug/L
ND
4000
4000
4300
4380
108
110
60-140
2
n-Propylbenzene
ug/L
ND
4000
4000
4630
4590
116
115
60-140
1
Naphthalene
ug/L
ND
4000
4000
4340
4420
104
105
60-140
2
o-Xylene
ug/L
3010
4000
4000
7380
7480
109
112
60-140
1
sec-Butylbenzene
ug/L
ND
4000
4000
4380
4390
110
110
60-140
0
Styrene
ug/L
ND
4000
4000
4320
4290
108
107
60-140
1
tert-Butyl benzene
ug/L
ND
4000
4000
3840
3840
96
96
60-140
0
Tetrachloroethene
ug/L
ND
4000
4000
4310
4320
108
108
60-140
0
Toluene
ug/L
21100
4000
4000
25000
26300
98
131
60-140
5
trans-1,2-Dichloroethene
ug/L
ND
4000
4000
4210
4300
105
107
60-140
2
trans- 1,3-Dichloropropene
ug/L
ND
4000
4000
3950
3960
99
99
60-140
0
Trichloroethene
ug/L
ND
4000
4000
4340
4270
109
107
60-140
2
Trichlorofluoromethane
ug/L
ND
4000
4000
3980
4030
100
101
60-140
1
Vinyl chloride
ug/L
ND
4000
4000
3780
3840
94
96
60-140
2
1,2-Dichloroethane-d4 (S)
%
98
101
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8(S)
%
98
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 33 of 48

leAnalyiical
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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 578777 Analysis Method: SM 2540C-2011
QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3062340 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 11/08/20 11:41
LABORATORY CONTROL SAMPLE: 3062341
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 248 99 90-110
SAMPLE DUPLICATE: 3062342
92504334001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 106000 ug/L 116 9
SAMPLE DUPLICATE: 3062343
92504561002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 61.0 60.0 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 578682 Analysis Method: SM 9222D-2006
QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3061988 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms CFU/100 mL ND 1.0 11/07/20 15:33
SAMPLE DUPLICATE: 3061989
92504561004 Dup
Parameter Units Result Result RPD Qualifiers
Fecal Coliforms CFU/100 mL ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 35 of 48

leAnalyiical
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Pace Analytical Services, LLC
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Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579004 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001
METHOD BLANK: 3063400
Associated Lab Samples: 92504561001
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 3063401
Parameter Units
Nitrogen, Ammonia mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 11/10/2011:53
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 4.8 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063402 3063403
MS MSD
92503866004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 1.1 5 5 5.8 5.8 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063404 3063405
MS MSD
92503881001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 29.8 5 5 34.7 34.0 97 84 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579005 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007, 92504561008
METHOD BLANK: 3063406 Matrix: Water
Associated Lab Samples: 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007, 92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 11/10/20 12:37
LABORATORY CONTROL SAMPLE: 3063407
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 4.8 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063408 3063409
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 95 95 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063410 3063411
MS MSD
92504561003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.7 4.7 94 94 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 48

leAnalyiical
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Pace Analytical Services, LLC
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Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 578705 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3062116 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.040 11/07/20 02:43
LABORATORY CONTROL SAMPLE: 3062117
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 1.5 1.5 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3062118 3062119
MS MSD
92504561004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 13.0 1.5 1.5 15.1 14.2 142 84 90-110 6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3062120 3062121
MS MSD
92504561001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0.73 1.5 1.5 2.2 2.2 98 97 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 578977 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3063304 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 11/10/20 21:11
LABORATORY CONTROL SAMPLE: 3063305
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063306 3063307
MS MSD
92504561001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L ND 2.5 2.5 2.5 2.5 98 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063308 3063309
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.060 2.5 2.5 2.6 2.6 100 101 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579054 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005
METHOD BLANK: 3063590
Matrix:
Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
11/09/2023:19
LABORATORY CONTROL SAMPLE:
3063591
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.6
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063627 3063628
MS MSD
92503890002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 54.6 10 10 65.6 63.7 110 91 90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063629 3063630
MS MSD
92503896001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 6.7 10 10 16.7 16.6 100 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579055 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561006, 92504561007, 92504561008
METHOD BLANK: 3063596
Matrix:
Water
Associated Lab Samples: 92504561006, 92504561007, 92504561008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND
1.0
11/09/2023:45
LABORATORY CONTROL SAMPLE:
3063597
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Chloride
mg/L
20
20.6
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063631 3063632
MS MSD
92504093001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 9.6 10 10 19.1 19.0 94 94 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3063633 3063634
MS MSD
92504093006 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 1.7 10 10 12.1 11.9 103 102 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 41 of 48

leAnalyiical
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Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: Lassonde Pappas
Pace Project No.: 92504561
QC Batch: 579489 Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
METHOD BLANK: 3065625 Matrix: Water
Associated Lab Samples: 92504561001, 92504561002, 92504561003, 92504561004, 92504561005, 92504561006, 92504561007,
92504561008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/11/20 23:33
LABORATORY CONTROL SAMPLE: 3065626
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065627 3065628
MS MSD
92502998001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 25.7 25.8 99 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3065629 3065630
MS MSD
92504561002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 4.6 25 25 29.2 29.3 99 99 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 48

leAnalyiical
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Asheville, NC 28804
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QUALIFIERS
Project: Lassonde Pappas
Pace Project No.: 92504561
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas
Pace Project No.: 92504561
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92504561001
MW-4
SM
6200B
579267
92504561002
MW-5
SM
6200B
579267
92504561003
MW-6
SM
6200B
579267
92504561004
MW-7R
SM
6200B
579267
92504561005
MW-8
SM
6200B
579267
92504561006
MW-9
SM
6200B
579267
92504561007
SW-1
SM
6200E
579267
92504561008
SW-2
SM
6200E
579267
92504561001
MW-4
SM 2540C-2011
578777
92504561002
MW-5
SM 2540C-2011
578777
92504561003
MW-6
SM 2540C-2011
578777
92504561004
MW-7R
SM 2540C-2011
578777
92504561005
MW-8
SM 2540C-2011
578777
92504561006
MW-9
SM 2540C-2011
578777
92504561007
SW-1
SM 2540C-2011
578777
92504561008
SW-2
SM 2540C-2011
578777
92504561001
MW-4
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561002
MW-5
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561003
MW-6
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561004
MW-7R
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561005
MW-8
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561006
MW-9
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561007
SW-1
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561008
SW-2
SM 9222D-2006
578682
SM 9222D-2006
578683
92504561001
MW-4
EPA 350.1 Rev 2.0 1993
579004
92504561002
MW-5
EPA 350.1 Rev 2.0 1993
579005
92504561003
MW-6
EPA 350.1 Rev 2.0 1993
579005
92504561004
MW-7R
EPA 350.1 Rev 2.0 1993
579005
92504561005
MW-8
EPA 350.1 Rev 2.0 1993
579005
92504561006
MW-9
EPA 350.1 Rev 2.0 1993
579005
92504561007
SW-1
EPA 350.1 Rev 2.0 1993
579005
92504561008
SW-2
EPA 350.1 Rev 2.0 1993
579005
92504561001
MW-4
EPA 353.2 Rev 2.0 1993
578705
92504561002
MW-5
EPA 353.2 Rev 2.0 1993
578705
92504561003
MW-6
EPA 353.2 Rev 2.0 1993
578705
92504561004
MW-7R
EPA 353.2 Rev 2.0 1993
578705
92504561005
MW-8
EPA 353.2 Rev 2.0 1993
578705
92504561006
MW-9
EPA 353.2 Rev 2.0 1993
578705
92504561007
SW-1
EPA 353.2 Rev 2.0 1993
578705
92504561008
SW-2
EPA 353.2 Rev 2.0 1993
578705
92504561001
MW-4
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561002
MW-5
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561003
MW-6
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561004
MW-7R
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561005
MW-8
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
92504561006
MW-9
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993
579311
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 48

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Lassonde Pappas
Pace Project No.: 92504561
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92504561007
SW-1
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993 579311
92504561008
SW-2
EPA 365.1 Rev 2.0 1993
578977
EPA 365.1 Rev 2.0 1993 579311
92504561001
MW-4
SM 4500-CI-E-2011
579054
92504561002
MW-5
SM 4500-CI-E-2011
579054
92504561003
MW-6
SM 4500-CI-E-2011
579054
92504561004
MW-7R
SM 4500-CI-E-2011
579054
92504561005
MW-8
SM 4500-CI-E-2011
579054
92504561006
MW-9
SM 4500-CI-E-2011
579055
92504561007
SW-1
SM 4500-CI-E-2011
579055
92504561008
SW-2
SM 4500-CI-E-2011
579055
92504561001
MW-4
SM 5310B-2011
579489
92504561002
MW-5
SM 5310B-2011
579489
92504561003
MW-6
SM 5310B-2011
579489
92504561004
MW-7R
SM 5310B-2011
579489
92504561005
MW-8
SM 5310B-2011
579489
92504561006
MW-9
SM 5310B-2011
579489
92504561007
SW-1
SM 5310E-2011
579489
92504561008
SW-2
SM 5310E-2011
579489
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /16/2020 01:39 PM without the written consent of Pace Analytical Services, LLC.
Page 45 of 48

�aceAnalytical'
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: October 28, 2020
Page 1 of 2
Document
F-CAR-CS-033-Rev.07
Issuing Authority:
Pace Carolinas Quality Office
Laboratory re eiving samples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Cliewfi
me; W®# • J25®4561
Upon Receipt i �� �'e '0q Project #:
Courier: ❑Fed Ex ❑UPS ❑USPS dent
❑ Commercial ❑Pace ❑other: 92504561
Custody Seal Present? []Yes Vo Seals Intact? ❑Yes '�2<
Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other
Thermometer: j���/ ❑wet []Blue�R Gun ID: a Type of Ice:
Correction Factor:
Cooler Temp: Add/Subtract i
Cooler Temp Corrected ("C):
USDA Regulated Soil ( KN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps}?
Date/Initials Person Examining Contents: !/ Q
Biological Tissue Frozen?
[]Yes❑No ZN/A
❑None
Temp should be above freezing to i
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source {internationally,
❑Yes []No
including Hawaii and Puerto Rico)! L}res LJrvU
Comments/Discrepancy:
Chain of Custody Present?
es
❑No
❑NIA
1.
Samples Arrived within Hold Time?
es
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
o
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
o
❑N/A
4.
Sufficient Volume?
es
[]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
el -Yes
es
❑No
❑No
❑N/A
❑NIA
6.
Containers Intact?
es
[-]NO
[—]N/A
7.
Dissolved analysis: Samples Field Filtered?
(—]Yes
❑No
/A
8.
Sample Labels Match COC?es
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm}?
Trip Biank Present?
Trip Blank Custody Seals Present?
[—]Yes
❑Yes
❑Yes
❑No
ONO
[:)No
[—]No
_]N/A9.
/A
/A
A
10.
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
hu" . _` ju-,/6.1.
Field Data Required? Des ❑No
Lot ID ofsplit containers:
Date/Time: �� 41f i
Date: f [ ' u
Date: ' I i1 D�
Page 46 of 48

Document Name:
Document Revised: October 28, 2020
'
Sample Condition Upon Receipt(SCUR)
Page 2 of 2
Document No.:
Authority:
c3Ce%�I alytical
F-CAR-CS-033-Rev.07 JLIssuing
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
Projectt# --Wa# : 925Q4561
PM: UP Due Date: 11/13/20
CLIENT: 93—ALTAMONT
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pH Adjustment Log for Preserved Samples
Sample 11)
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy Of this form will 6e sent to the North Carolina UFHNR certification Orrice ti.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 47 of 48

/..-PaceAnaiytrcal�
www,vxC[L�BSt OM
Section A
Required Client Information:
Company, ANCHOR AEA OF NC, PLLC
Address: 231 Havwocd Street
lEmail:
SAMPLE ID
One Character per box.
lA-Z. D-s r . -1
U Sample Ids must be unique
w
hALA-
Section B
Required Project Information:
Report To: eZj'
Copy To: li ^V%i�!ii
rrolecl Name, Lassonde Pappa
Project #:
0.
MATRIX COOL
Dunking Wale, OW
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CHAIN -OF -CUSTODY 1 Analytical Request Document00
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. 0)
Cu
Section C
Invoice Information: Pa e : Of 1
Attention
Company Name:
Address. Regulatory A ene
Pace Quote.
Pace Project Manager: lorri, palton pacelabs_cam, State I Location
Pace Profile #: B114
Recuested Analvsis Filtered (YIN)
COLLECTED
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ADDITIONAL COMMENTS I RELINQUISHEDBYIAFFILIATION DATE I TIME ACCEPTED BY r AFFILIATION DATE I TIME SAMPLE CONDITIONS
.�.f, NA U VEIO. IJUu�O. 1 l f W 70 '� IS c. C 6 (fit., — � C r, t - C� 1 L-1 5 5 `( (J
PLER NAME AND SIGNATURE
PRINT Name of SAMPLER:
SIGNATURE of SAMPLER:
DATE Signed: `i 1 �

Attachment 2
Well Sampling Logs and Instrument
Calibration Data Sheet

,� ANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Location: Hendersonville, NC
Sampling Personnel: -
Well ID: MW-4
Screen Interval: 5-15 ft bgs
Depth to Water: D , G- ft
Measuring Point: TOC
Depth of Pump Intake: 11.5 ft
Drawdown Set: , I'D ft
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments: t STD Y.
Project Number:
Date:
Weather:
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter:
C01482-01.01 t 02
I t & (�
C
13
3
in
Purge Rate:
Tagged bottom at:
ft
Time:
Total Volume Purged:
Pump Speed:
Time
DTW (feet)
Temp CQ
DO (mg/L)
Specific Cond. (NS)
pH (S.U.)
report tt opO. i' S.U.
ORP (mV)
Turbidity (NTU)
me
A
03
tf
q JIM
10 R4
3,3ar-
b
t .5
."
r
, I
-'
a.
+
1)
.�
�•
LIY�s
Sampling Personnel Signature:
Date:
Notes:
Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,* +/- 3% Conductivity,* +/- 0.1 pH unit' +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
°C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 0 G-2011
mv: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
S.U: standard units
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1982
pH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
Low -Flow Sampling Log
Project Name: Lassonde Pappas Groundwater Sampling _
Location: Hendersonville, NC
Sampling Personnel: W
Well ID: MW-5
Screen Interval: 9-19 ft bgs
Depth to Water: a- ft
Measuring Point: TOC
Depth of Pump Intake: 14 ft
Drawdown Set: g �a� ft
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments:
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Number: C01482-01.01 t 02
Date: it tivit
Weather: V dS
Arrive at Well: [ 0159-
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter. OILin
Purge Rate:
Total Volume Purged:
Tagged bottom at: ILLO ft Time: Pump Speed:
i
r
>
W-60
0J
Sampling Personnel Signature: 111111e�
Notes
�,tamhzatlon (3 successive reaaings, s mmuies aparq: wimm +/- ru7o uv ana rurolairy; +/- 17, Lonaucavlry,+/- u.I pn unu; +>- ru my ror VKY
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
uS: micro-Siemen
mV: millivolt
'C: degrees Celsius
NTU: nephelometric turbidity units
bgs: below ground surface
ORP: oxidation reduction potential
DO: dissolved oxygen
S.U.: standard units
mg1L: milligrams per liter
toc: top of casing
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Page 1 of 1

,� ANCHOR
QEA` y"
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Location: Hendersonville, NC
Sampling Personnel: JV1
Well ID: MW-6
Screen Interval: 5-10 ft bgs
Depth to Water: — _ __1 :3 ft
Measuring Point: TOC
Depth of Pump Intake: 7.5 ft
Drawdown Set: ft
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments:
Project Number:
Date:
Weather:
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter:
CO1482-01.01 t 02
1 l 16 1 av
Su"%AtA
0 1 O
l 3
�� 5
in
Purge Rate:
Tagged bottom at:
ft
Time:JWff
Total Volume Purged:
Pump Speed:
Time
DTW (feet)
Temp (°C)
DO (mg/L)
Specific Cond. (pS)
PH (S.U.)
report to 0.1 SX.
(m1)
Turbidity (NTU)
r
5,
'OLRP
`�C �.
_
5.�
14 .
- .1
64Lt
C5.3
-w i 3
9`S -
.a-
o
3
3�
a �
,a
2_
,a
-
a
o
(01
2-
'.
a
r
u
U:?
2—
a,5
(a
, 0
(0
5-
Sampling Personnel Signature:
Date: k L I G
T/ l!
Notes:
Stabilization (3 successive readings, nutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity, +/- 0.7 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
uS: micro-Siemen mV: millivolt
°C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO:SM 4500 O G-2011
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1962
pH:SM 4500-H'8-2011
Page 1 of 1

ANCHOR
\4 QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Location: Hendersonville, NC
Sampling Personnel: M�
Well ID: MW-7R
Screen Interval: 5-15 ft bgs
Depth to Water. _ M Q G ft
Measuring Point: TOC
Depth of Pump Intake: 12 ft
Drawdown Set: ; O co ft
•
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments:
Project Number:
Date:
Weather:
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter:
C01482-01}.01 t 02
tt ) � ++ �
^� ma y`
3
QC)
L b j
ih
Purge Rate:
thN�►
Total Volume Purged:
Tagged bottom at: TU,
. ft
Time: _
Pump Speed:
Ids -
Time
DTW (feet)
Temp (°C)
DO (mg/L)
Specific Cond. (pS)
PH (S.U.)
report to 0.1 S U.
ORP (mV)
Turbidity (NTU)
t
D
rr.
45[[jj
S. r
�.Al
a
si
WJ
as —
1.60
It 0
W3
ln
Personnel Signature:
r
r�
Date: �' n
Notes: V
Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity; +/- 3% Conductivity, +/- 0.1 pH unit; +/- 70 mV%r ORP
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
°C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 O G-2011
mV: millivolt
NTU: nephelometric turbidity units
K Irk ORP: oxidation reduction potential
ti S.U.: standard units
1a[ toc: top of casing
• Specific conductivity: EPA Method 120.1, Rev. 1982
PH: SM 4500-H` B-2011
Page 1 of 1

elANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Location: Hendersonville, NC
Sampling Personnel: Oil V­
Well ID: MW-g
Screen Interval: 3-13 ft bgs
Depth to Water: Q ft
Measuring Point: TOCuu
Depth of Pump Intake: 10.5 ft
Drawdown Set: ,tko ft
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments: _
Tagged bottom at: Amft Time:
Project Number:
Date:
Weather.
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter:
C01482-01.01 t 02
1L 1 (a j )'p
tv ty" 4"
I Olt
O
v
e�
0 of05
r] in
fr
Purge Rate:
Total Volume Purged_
Pump Speed:
Time
DTW (feet)
Temp (°C)
DO (mg/L)
Specific Cond. (pS)
pH (S.U.)
report to 0.1 S.U.
ORP (m1)
Turbidity (NTU)
d
'ram
1613.
5'
3
10r
I r�
iA
Q.p{lA!
n
O 1
4
�}
!
39—
liqV
r
Le, 31
qF
Sampling Personnel Signature:
Date: l
Notes:
Stabilization (3 successive readings, 3 min _ �41within +/- 10% DO and turbidity- +/- 3% Conductivity, +/- 0.1 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen mV: millivolt
'C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 0 G-2011
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1982
pH: SM 4500-H' B-2011
Page 1 of 1

kZANCHOR
QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Location: Hendersonville, NC _
Sampling Personnel: _
Well ID: MW-9
Screen Interval: yakno lr ram- ftbgs
Depth to Water. L+. 10 ft
Measuring Point: TOC+ uu
Depth of Pump Intake:
Drawdown Set: ft
Pump Used (circle): Peristaltic Bladder Other (describe):
Comments:
Project Number:
Date:
Weather:
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter:
C01482-01.01 t 02
L 1 ' Juc P0
W001NIA
Tj
1�
in
Purge Rate:
Total Volume Purged:
Tagged bottom at: IS, 0 ft
Time:
Pump Speed:
Time
DTW (feet)
Temp ('Q
DO (mg/L)
Specific Cond. (pS)
PH (S.U.)
reportto O.I S.U.
ORP (mv)
Turbidity (NTU)
.0
01
S
5
_
HADI
o.
5
55,5
.(01(v
1
3
- 3
- ' 2
2-LiAs
�t
! v
In
Sampling Personnel Signature:
Date:
+� /
Notes:
Stabilization (3 successive readings, , s apart): within +/- 70% DO and turbidity +/- 3% Conductivity; +/- 0.7 PH unit, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
Samples are analyzed immediately upon collection.
pS: micro-Siemen
`C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 0 G-2011
mv: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
S.0 : standard units
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1982
pH: SM 4500-H' B-2011
Page 1 of 1

tZANCHOR
CIEA
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number. C01482-01.01 t 02
Sampling Personnel: Typmy--
Sample Name: SW-1 �
Comments: Upstream of site) 5 Lrlri Y
Date:
Weather:
Sample Method:
Grab
Syringe
Pump
Bailer-Disp. Other.
Time Temp ("C)
Dissolved
Oxygen (mg/L)
Specific Cond.
(PS/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction Turbidity
Potential (mV) (NTU) Comments
�acA
1
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
Ck(6Nou-
125 mL Plastic
Arw"Vtiot r7 Ni
40 mL Glass
V) G
1 L Glass
Other
Vegetation: �D
Access: -�V �
Sampling Personnel Signature: 12 Date: { L t
.. Math—1 Rnfara — VVV
Samples are analyzed immediately upon collection.
"C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U: standard units
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
Q� 4-4-4-0
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: Lassonde Pappas Groundwater Sampling
Project Number. C01482-01.01 t 02
Sampling Personnel:
Sample Name: SW-2
Comments: Downstream of site
Date: I
Weather:
Sample Method:
Grab Syringe Pump
Bailer-Disp. Other.
Time
Temp (°C)
Dissolved Specific Cond. pH (S.U.)
Oxygen (mg/L) (PS/cm) report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
1
250 mL Plastic
v
125 mL Plastic
40 mL Glass
71 L
1 L Glass
Other
Vegetation: (�
Sampling Personnel Signature:
Notes: j
Samples are analyzed immediately capon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Access: Q �—'— — iA UC Si" a ( Tve4—
Date: I (1 L- In
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pK SM 4500-H' B-2011
Page 1 of 1

ANCHOR
QEA
Equipment Documentation and Instrument Calibration Data Sheet
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
/ CALIBRATION DOCUMENTATION
Project Name: Li b5 (%Vi �QUp� Gj Person Conducting Calibration:
Project Number. Date of Calibration: lk }()
Project Location: Date of Field Measurements: k
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
ui ment lkpe
Brand Serial Number
Date of Use
Rental Comparrj
13k-�oogao
U V
Select Turbidimeter: Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Instrument Reading
Instrument Reading
(Hach 2100Q)
(HF Scientific MicrOTPW)
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
0.02 NTU
Calibration Expiration
r71
ti
Date:I
Cal: ,
Cal: /,j �
Cal: �
Cal:
Cal:
Cal:
Time: �q
[�
Time:'�l
Time: 2
Time:
Time:
Time:
Calibration
*Pre -Analysis
Meas:
��
Time:
UT5-17-
*Pre -Analysis
Meas:
Time:
Verification:
Check (10 NTU):
��
Check (10 NTU):
*Post -Analysis
Meas:
�b t �Li]
Time: l
*Post -Analysis
Meas:
Time:
Check (10 NTU):
I
Check (10 NTU):
YSI Professional Plus Multiparameter Meter (s/n 18B101802)
Instrument Readings
Calibration Lot No.
& Expiration Date
Dissolved Oxygen
Initial: �� O
Cal:
lJ
uo
mmHg:
Temperature (°C):
Time:
pH75.U.
Initial yc/
C0
pHmV:
`�
Cal:
pHmV:
Time:,
��
report to 0.7 S.U.
l
PH 4 S.U.
Initial: , r I , `C
y� `l•l
pHmV:
�
Cal: Lt. �
pHmV:
Time��
U `
report to 0.7 S.U.
t
PH 10 S.U.
Initial: 1,101
pHmV:
Cal: 1 0
pHmV:
��
Time: _ - (a
��V
V� d
report to 0.1 S.U.
QC* pH 7 S.U. report
AM Time-
Meas:j /`� �y
lQ� S
Mid Day Time:
Check:
PM Time:
C eck:
�ft+ ,
` v
to0.iS.U.
U'1`d
Spec. Cond.
wdc)
Initial:
1o3o
Cal:
)000
Time:
OTOg
�� (
Put.
QC*:
AM Time:�j
Meas: �(
Mid Day Time:
Check:
PM Time:
4 o q
Check:
PS/CM
t/ 1
C)
% Recovery=
ry,��
ORP O Vy mV
Initial:3
v
t)l�� ,
Temperature
�"' ll --Il
Time:
v ` �
()Ojai
Signature: Date:
Notes:
Revision 3, 04/30/20, MHF
1. Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10 % of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
5. * QC check must be performed prior to sampling and following completion of sampling, at a minimum.
6. % Recovery = (Value Obtained, pS/cm = True Value, pS/cm) x 100
Method Reference: Temp: SM 2550 8-2010 I Conductivity. EPA Method 720.7 1 DO: SM 4500 0 G-2071 I pH: SM 4500-H+8-2071 I Turbidity: SM 2730 8-207 7
r , rl * Page 1 of 1

ENVIRO—EQUIPMENTINC.
YSI PRO+ CALIBRATION DATA SHEET
Serial Number: 2 MDate: [ j c} ns ctoe
9
�W
Catibrut on Check (Performed At Lub Room Temperuture)
SolutionlV'alue
ManuLacturer Lot Number Expiration Readh
lccttrac !
pH 4.00
AquaPhoenix 01. cc
±0.2,
pH 7.00
AquaPhoenix . d 7-
pH 10.00
AquaPhoenix ' •
=0
Conductivitsr
1000 pis/cm
r
AquaPhoenix � US/CM 1%
ullrtrutrV {rltte
.cttciiactterer LrrtNttrnber Eytrattojt Reading
cc�s°a
ORP 200 mV
AquaPhoenix .6111V
±,-01-,1V
SolutionlValue
Calibration Type Temperature Barometer Readin Readin
Accuractr
Dissolved Oxygen
Saturated Air ���,LW,,4tJ1
Date of last RO. membrane cap replacement: Ic "s Z11-1
Dissolved oxygen accuracy: 0 - 200% air saturation: +2% of reading or 2% air saturation
200% to 500% air saturation. ±6% of readin
"Note all standard solution values are at .25°C. **
Temperature Cheek
Testo 925 (MST Traceable) , (� -C. ±0.5 C
YI Pro+ 'Z-q-0 °C --0.2 C
Inspector's Maintenance Notes

CHAIN -OF -CUSTODY / Analytical Request Document
aceAnalytical"
WWW.PkCEUEr.COM
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
SectionlA
Section B
Section C
Required Client Information:
Required Project Information:
Invoice Information: P8 0 : 1 Of 1
Company: ANCHOR QEA OF NC, PLLC
ReportTo: ace
;
Atlerrtron
Address: 231 Haywood Street
Copy To: YVVJ(/,x
Ccrnnany Name-
Asheville,NC28601
Address:
t2e Mato ,. ,.A-` i-lc.
Email: �y cj 7 i. ErEo�7 �:
Purchase Order#: '+ I
Pace Quote:
Phone: 1828j707_5827 Fax
Project Name:
Lassonde Pappas
Pace Project Manager: lord.patton pacelabs.com,
State!'Logatiml
Requested Due Date:
Project #:
Pace Profile #: 8114
RequIetated.AtialYeWl=iltej'
d'W1N
2
MATRIX
CODE
c0i
COLLECTED
Z
Preservatives
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Drinking Water DW
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SAMPLE ID
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PLER NAME AND SIGNATURE'
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PRINT Name of SAMPLER: a
n m o @ m E
SIGNATURE of SAMPLER: `
DATE Signed: g j r w m m
U

Attachment 3
DEQ GW-59A — Compliance Report Form

GW-59A COMPLIANCE REPORT FORM Permit #
(Submit one each monitoring period with GI1'-59 fornis.)
1
Enter date monitoring results were due. ( ) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the ansiver is " 3 es ", contact the Regional Office for guidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
8
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with G W-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permittee (or Authorized Agent) Date
GR'-59A 12/8/2003

Attachment 4
DEQ GW-59 — Groundwater Quality
Monitoring: Compliance Report Forms

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION
Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 / 31 / 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside
Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC
28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect
dissolved
and colloidal concentrations.
COD 00335
mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616
/100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504
/100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300
mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403
units
Ba - Barium 01007
ug/L
TOC 00680
mg/L
Ca - Calcium 00916
mg/L
Chloride 00940
mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002
ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552
mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730
ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945
mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095
µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610
mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625
mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 64 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 mg/L
Al - Aluminum 01105
mg/L Tetrachloroethene - 0.80 pg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L Trichloroethene - 1.0 pg/L
TOC 00680 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
• •
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
GROUNDWATER QUALITY MONITORING:
DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 -
6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name:
No. of wells to be sampled:
6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit):
Date sample collected:
FIELD ANALYSES:
WAS
Well Depth: ft.
Well Diameter:
in. pH 00000: units Temp. 000lo: °C
DRY at
Depth to Water Level 82546: ft. below measuring point Screened Interval:
ft. to _ft. Spec. Cond. 00094: µMhos
time ofsampling,
Measuring Point is ft. above land surface
Relative M.P. Elevation:
ft. Odor 00085:
check
Volume of water pumped/bailed before sampling:
gallons
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES
❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report Laboratory Name: Pace
Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 /100mL
Nitrate (NO3) as N 00620
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee (or Authorized Agent) (Date)

Attachment 3
DEQ GW-59A — Compliance Report Form

GW 59A COMPLIANCE REPORT FORM Permit # WQ0004797
(Srrhnrit one each nronitnring period with Gil 59 jorna )
1
Enter date monitoring results were due. (12 /31/2020) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
X
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES, list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? If the answer is 1es ", contact the Regional Office for guidance.
X
4
Are any monitored constituents equal to or above the established standards?
YES
NO
if the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrations)
exceeding standards in the space provided below:
Nitrate (2L = 10 mg/L): MW-7R0 13.0 mg/L
Fecal Coliform (Total Coliform 2L standard = 1.0 CFU/100mL): MW 5C 8.0 CFU/100mL, MW 6q 3.0 CFU/100ML, MW 8: 14.0 and
MW-90 16.0
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
X
If the answer to question 5 is "NO", skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentrations) reported, and sample collection date for each occurrence (for the last two years).
Nitrate Fecal Coliform Fecal Coliform Fecal Coliform Fecal Coliform
MW-7R (mg/L) MW 5 (CFU/100mL) MW-6 (CFU)100mL) MW-8 (CFU/l00mL) MW-9 (CFU/100mL)
05/21/19: 20.2 05/21/19: 7.0 05/21/19: 23.0 05/21/19: <10.0 05/21/19; <10.0
11/14/19: 17.1 11/14/19: 7.0 11/14/19: 44.0 11/14/19: 2.0 11/14/19: <1.0
05/06/20: 21.5 05/06/20: 8.0 05/06/20: 3.0 05/06/20: <1.0 05/06/20: <1.0
11/06/20: 13.0 11/06/20: 8.0 11/06/20: 3.0 11/06/20: 14.0 11/06/20: 16.0
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
NO
X
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
X
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO" contact the Regional Office within 90 days; an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subiect the permittee to a Notice of Violation,
fines, and/or penalties.
Fecal coliform should not be attributable to site operations. Historical monitoring of an on -site tributary of Mud
Creek has found high levels of fecal coliform. The surface water sample collected in Mud Creek upstream of the site
had higher fecal coliform concentrations than the sample collected downstream of the site.
High nitrate concentrations may be attributable to the frequent flooding of Mud Creek. As a proactive approach to
avoid introducing additional nitrogen into soils at the facility, Clement Pappas has implemented the practice of
baling harvested fescue and removing it from the irrigation fields, instead of mowing it and allowing it to decompose.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
Signature of Permittee (or Authorized Agent) Date
GN1 59 \ 12/8/2003

Attachment 4
DEQ GW-59 — Groundwater Quality
Monitoring: Compliance Report Forms

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
•
AD
.
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
OF WATER RESOURCES - INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
�
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 / 31 / 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW- 4
Date sample collected: 11 / 0 6 /
2 0 2 0
FIELD ANALYSES:
WAS
Well Depth: 18 _ 2 pft.
Well Diameter: 2 in.
pH 00400:5 . 30 units Temp. 000to: 18 . 1 oC
DRY at
Depth to Water Level 82546: 8 . 02 ft. below measuring point
Screened Interval: r ft.
to
ft. Spec. Cond. 00094: 230.4 µMhos
time of
Measuring Point is 2 . 43 ft. above land surface
Relative M.P. Elevation: 2063 . 77
ft.
Odor 00085: none
sampling,check
Volume of water um ed/bailed before sampling: 0 . 4 0
p p p g:
*screened interval is relative to land surface
gallons Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑
NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 < 1 . 0 /100mL
Nitrate (NO3) as N 00620 0.73
mg/L Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 < 0 . 0 5
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 148 mg/L
Al - Aluminum of im
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC omn 2.8 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 6.9 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 rng/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia com < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese o1055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
WAGE 4JV01595),,1 f 4G _)(1Vtr4,V,+G-eve_
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Signature of Permittee
(Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
. .,
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
•
..
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 828 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from P-0
SAMPLING INFORMATION MW- 5
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 0 6 / 2 0 FIELD ANALYSES:
WAS
Well Depth: 18 _ - nft.
Well Diameter: 2 in.
pH 00400: 5 .65 units Temp. oomo: 18 •2 °C
DRY at
Depth to Water Level 82546: 8 , 9 0 ft. below measuring point Screened Interval: 9 * ft.
to 19 * ft. Spec. Cond. 00094: 64.5 µMhos
time of
Measuring Point is 3 . 0 0
g ft. above land surface
Relative M.P. Elevation: 2085. 6o
ft. Odor 000a5: none
sampling,
check
Volume of water pumped/bailed before sampling: 0 . 3 6 gallons screened interval is relative to land surfac'Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑
NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 8.0 /100mL
Nitrate (NO3) as N 00620 <0 . 040mg/L Zn -Zinc 01092 m9 /L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 0 . 0 6 0 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 61.0 mg/L
AI - Aluminum 01105
mg/L Tetrachloroethene - 0.80 pg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L Trichloroethene - 1.0 pg/L
TOC 00680 4.6 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 6.9 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L (Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance o0095 µMhos
K - Potassium 00937
mg/L method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L method #
(Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L , method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
WA PF_ AAIDE(ZScrl kA r," (xblA(re%�
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
Permittee (or Authorized Agent)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
DEPARTMENT OF ENVIRONMENT 8, NATURAL RESOURCES
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2 02 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION MW- 6
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 0 6 / 2 02 0
FIELD ANALYSES:
WAS
Well Depth: 11 —5a ft.
Well Diameter: 2 in.
pH 00400: 5 • 23 units Temp. 000lo: 16 .4 °C
DRY at
Depth to Water Level 82546: 5 . 3 3 ft. below measuring point Screened Interval: 5* ft. to
10 *
ft. Spec. Cond. 00094: 202.6 µMhos
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2061.17 ft.
Odor 00085: none
sampling,
check
Volume of water um ed/bailed before sampling: 0 _ ] tJ *screened interval is relative to land surface
p p p g: gallons Appearance
here:
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1o51 ug/L
Coliform: MF Fecal 31616 3.0 /100ml-
Nitrate (NO3) as N 00620 3.2
mg/L Zn -Zinc 01092 mg/L
Coliform: M F Total 31504 /100ml-
Phosphorus: Total as P 00665 < 0 . 0 5 mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 139 mg/L
All - Aluminum o1105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 2 . 6 mg/L
Ca - Calcium oo916
mg/L
Chloride 00940 12 . 5 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3 as N: Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remedlation Systems Only •Total• •
certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a
DWR-certified laboratory, I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations.
ittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or
GW-59 Rev.8/2013
(Date)
Z

SUBMIT FORM ON YELLOW PAPFR ON[ Y
GROUNDWATER QUALITY MONITORING:
....
:
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
..
11617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2026
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
® Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation Area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION MW- 7R
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 0 6 / 2 0
FIELD ANALYSES:
WAS
Well Depth: 17 _ -� 7 ft.
Well Diameter: 2 in.
pH 00400: 5 . 54 units Temp. 000lo: 14. 3 °C
DRY at
Depth to Water Level 82546: 10 . 0 Sft. below measuring point Screened Interval: 5 ft.* to
15
ft* Spec. Cond. 00094: 311.6 µMhos
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2062.86 ft.
Odor 00085: none
sampling,
check
Volume of water um ed/bailed before sampling: 0 . 4 7 ;screened interval is relative to land
p p p g: gallons
surface
Appearance
here:
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616 <1 , p /100mL
Nitrate (NO3) as N 00620 13.0
mg/L
Zn -Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL
Phosphorus: Total as P 00665 < 0 - 0 5
mg/L
(Note: Use WIN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 205 mg/L
Al - Aluminum oil o5
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 1.7 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 17.8 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 000s5 µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 <0 . 10 mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NHS as N; Ammonia Nitrogen, Total)
Mn - Manganese o1 o55
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
ittee (or Authorized Agent) Name
GW-59 Rev.8/2013
type
of Permittee (or Authorized Agent)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
•
•
DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES
COMPLIANCE REPORT FORM
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 3 1 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION MW 8
If WELL
WELL ID NUMBER (from Permit):
Date sample collected: 11 / 0 6 / 2
0
FIELD ANALYSES:
WAS
Well Depth: 13—a eft.
Well Diameter: in.
e
pH ooaoo: 6 . 34 units Temp. 000�o: 14 . 5 C
DRY at
Depth to Water Level 82546: 8 _ 3 7 ft. below measuring point Screened Interval: 3 ft* to
13
ft* Spec. Cond. 00094: 229.0 µMhos
time of
Measuring Point is 3 . 0 0 ft. above land surface
Relative M.P. Elevation: 2060.80 ft.
Odor 000m: none
sampling,
check
Volume of water um ed/bailed before sampling: 0 _ 6 Q *screened interval is relative to land
p p p g: gallons
surface
Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 37712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
mg/L
Pb - Lead o1051 ug/L
Coliform: MF Fecal 31616 14.0 /100mL
Nitrate (NO3) as N 00620 2.4
mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100ml-
Phosphorus: Total as P 00665 < 0 . 0 5
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 127 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 2.8 mg/L
Ca - Calcium 00916
mg/L
Chloride 00940 2.3 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance 00095 µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 < 0 . 10 mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
, method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
N� (rep__ 1
Signature of Permittee (or Authorized Agent) (Date)

SUBMIT FORM ON YELLOW PAPER ONLY
GROUNDWATER QUALITY MONITORING:
.
DEPARTMENT OF ENVIRONMENTS NATURAL RESOURCES
DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM
1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: [phone]
FACILITY INFORMATION Please Print Clearly or Type
PERMIT Number: Expiration Date: 7 31 2 0 2 6
Facility Name: Clement Pappas
Non -Discharge WQ0004797 UIC
Permit Name (if different):
NPDES Other
Facility Address: 485 Brookside Camp
Road
TYPE OF PERMITTED OPERATION BEING MONITORED
Hendersonville NC 28792 County Henderson
❑ Lagoon ❑ Remediation: Infiltration Gallery
IN Spray Field ❑ Remediation:
Contact Person: Mrs. Tracy Wolfe
Telephone#: 8 2 8 - 3 2 9 - 6 6 4 7
❑ Rotary Distributor ❑ Land Application of Sludge
Well Location/Site Name: Irrigation area
No. of wells to be sampled: 6
❑ Water Source Heat Pump ❑ Other:
from Permit
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (from Permit): MW- 9
Date sample collected: 11 / 0 6 / 2 0
FIELD ANALYSES:
WAS
Well Depth: 18 - 1 ft.
Well Diameter: 2 in.
pH 00400: 4 • 93 units Temp. 000lo: 18.4 °C
DRY at
Depth to Water Level 82546: 4 . 10 ft. below measuring
point Screened Interval: 3 ft* to
13
ft* Spec. Cond. oo0sa: 55 .4 µMhos
time of
Measuring Point is 3 . 00 ft_ above land surface
Relative M.P. Elevation: 2060.23 ft.
Odor000m: none
sampling,
check
Volume of water pumped/bailed before sampling: 0.30 gallonsscreened interval is relative to land
surfac'Appearance
here:❑
Samples for metals were collected unfiltered: ❑ YES
❑ NO and field acidified: ❑ YES ❑ NO
LABORATORY INFORMATION
Date sample analyzed: varies; see analytical report LaboratoryName: Pace Analytical
Services Certification No. 3 7712
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L
Nitrite (NO2) as N 00615
rng/L
Pb - Lead 01051 ug/L
Coliform: MF Fecal 31616 16.0 /100mL
Nitrate (NO3) as N 00620 0.043 mg/L
Zn - Zinc 01092 mg/L
Coliform: MF Total 31504 /100ml-
Phosphorus: Total as P 00665 0.095
mg/L
(Note: Use MPN method for highly turbid samples)
Orthophosphate 70507
mg/L
Other (Specify Compounds and Concentration Units):
issolved Solids:Total 70300 88 - 0 mg/L
Al - Aluminum 01105
mg/L
pH (Lab) 00403 units
Ba - Barium 01007
ug/L
TOC 00680 4.5 mg/L
Ca - Calcium oo916
mg/L
Chloride 00940 1.4 mg/L
Cd - Cadmium 01027
ug/L
Arsenic 01002 ug/L
Chromium: Total 01034
ug/L
Grease and Oils 00552 mg/L
Cu - Copper 01042
mg/L
ORGANICS: (by GC, GC/MS, HPLC)
Phenol 32730 ug/L
Fe - Iron 01045
ug/L
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate 00945 mg/L
Hg - Mercury 71900
ug/L
Lab Report Attached? ® Yes (1) ❑ No (0)
Specific Conductance o0095 µMhos
K - Potassium 00937
mg/L
method #
Total Ammonia 00610 < 0 - 10 mg/L
Mg - Magnesium 00927
mg/L
method #
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese 01055
ug/L
,method #
TKN as N 00625 mg/L
Ni - Nickel 01067
ug/L
method #
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Permittee (or Authorized Agent) Name and Title - Please print or type
GW-59 Rev.8/2013
of Permittee (or Authorized
1 Z/
(Date)