NC0082821_Regional Office Historical File Pre 2018 (7)

2011 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
Prepared for
Mr. Vance Dann
Southern States Cooperative, Inc.
Post Office Box 26234
Richmond, Virginia 23260
[phone]
Submitted to
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue
Suite 301
Mooresville, North Carolina 28115
Prepared by
Duncklee & Dunham, P.C.
511 Keisler Drive, Suite 102
Cary, North Carolina 27518
February 22, 2012
DUNCKLIiL & DIJNI IAM, P.C.

- - - DUNCKLEE
__-- -_ & DUNHAM
February 22, 2012
ENVIRONMENTAL CONSULTING & ENGINEERING
511 KEISLER DRIVE - SUITE 102
CARY, NORTH CAROLINA 27518
OFFICE: [phone]
W W W.DUNCKLEEDUNHAM.COM
Mr. Andrew Pitner, P.G.
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
Reference: 2011 Annual Groundwater Monitoring and Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant, Statesville, North Carolina
Groundwater Incident Number: 5038
Dear Mr. Pitner:
As requested by Southern States Cooperative, Inc. (Southern States), Duncklee & Dunham, P.C. is
pleased to submit this 2011 Annual Groundwater Monitoring and Treatment System Effectiveness Report
for the above referenced site. This report discusses the work performed and the conclusions derived from
sampling and monitoring performed during this period.
If you have any questions or require additional information, please do not hesitate to contact
Mr. Tom Dunham at [phone] ([e-mail]) or Mr. Vance Dann of
Southern States at [phone] ([e-mail]).
Sincerely,
Duncklee & Dunham, P.C.
qr-6�f �'
Jayson A. Kilcoyne
Project Environmental Scientist II
Senior Peer Review:
Bryson D. Trexler, Jr., Ph.D., P.G.
Senior Hydrogeologist
Thomas S. Dunham, P.G.
Senior Geologist
cc: Mr. Vance Dann — Southern States Cooperative, Inc. (e-copy)
P:\Southern StateStatesville Fertilizer - 50200\Reports\2011\Annual GW Monitoring Report - 11326.doc
MAILING ADDRESS — POST OFFICE BOX 33366 — RALEIGH, NORTH CAROLINA 27636
+ NORTH CAROLINA BOARD OF EXAMINERS FOR ENGINEERS AND SURVEYORS LICENSE C-3559
j NORTH CAROLINA BOARD FOR LICENSING OF GEOLOGISTS LICENSE C-261
NC DENR REGISTERED ENVIRONMENTAL CONSULTANT NUMBER 00061

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Table of Contents
Introduction
1.1 Site Location, Description and History
1.2 Summary of Remedial Actions
Groundwater Treatment System Modifications and Monitoring Activities
2.1 Groundwater Treatment System Upgrades and Recovery Well Repairs
2.2 Groundwater Treatment System Monitoring Activities
Groundwater Sampling Activities and Results
3.1 Groundwater Sampling Methodology
3.2 Results from 2011 Sampling Events
3.2.1 Nitrate Results and Trends
3.2.2 Ammonia Results and Trends
Recommendations
Figures
Site Location Topographic Map
Site Map
Treatment System Discharge Line Outfall Map
Potentiometric Map - April 2011
Potentiometric Map - November 2011
Shallow Aquifer Nitrate Isoconcentration Map - April 2011
Deep Aquifer Nitrate Isoconcentration Map - April 2011
Shallow Aquifer Nitrate Isoconcentration Map - November 2011
Deep Aquifer Nitrate Isoconcentration Map - November 2011
Tables
Summary of 2011 Well Water Level Gauging Data
Summary of 2011 Groundwater Analytical and Field Parameter Results
Appendices
April and November 2011 Field Data Sampling Forms
April and November 2011 Laboratory Analytical Reports
Nitrate in Groundwater Trend Graphs
B
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2011 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
Introduction
1.1 Site Location, Description and History
The Southern States Cooperative, Inc. (Southern States) fertilizer plant (the site) is located at
2582 Salisbury Highway (old US Highway 70) approximately six miles east of Statesville, North Carolina
(Figure 1). The site consists of several buildings including a fertilizer manufacturing building, an office
building, and several small support buildings (Figure 2). The site is utilized for the manufacturing,
storage, and distribution of fertilizer.
The site is bordered to the north by old US Highway 70, commercially developed parcels to the east,
residential properties to the south, and undeveloped land to the west. The US Highway 70 Bypass (70
Bypass) bisects east to west through the southern portion of the site and separates approximately 13 acres
from the main property (Figure 2).
Groundwater at the site has been impacted by a release of liquid ammonium nitrate from several former
surface water impoundments. Two impoundments (Former Pond No. 1 and No. 2) were located
approximately 1,000-feet southwest of the main plant (Figure 2). Two additional surface water
impoundments (Former Ponds A and B, Figure 2) were located east and southeast of the main plant.
These impoundments are referenced in the Corrective Action Plan (CAP) dated January 28, 1994,
submitted by Canonie Environmental to the North Carolina Department of Environment and Natural
Resources (DENR), Division of Water Quality (DWQ), Aquifer Protection Section (APS). In 1994 the
APS approved the CAP. Based on the CAP, the assessment and impact of groundwater contamination
was defined with reasonable certainty.
The objectives of the CAP were to remediate groundwater and to prevent off -site migration of the
groundwater contamination plume. To monitor the effectiveness of the CAP, a groundwater sampling
plan was developed that established semiannual (April and October) groundwater monitoring. The annual
groundwater monitoring reports cover the period from November 1 through March 31.
1.2 Summary of Remedial Actions
To reduce the levels of nitrate and ammonia in the groundwater, three recovery wells (RW-2, RW-5 and
RW-6) were installed as part of the CAP. However, RW-5 was taken out of service prior to 2005 due to
low or no groundwater recovery and replaced with RW-5r in September 2008. The recovery wells pump
groundwater into a treatment system where the pH is adjusted with a caustic solution prior to being
discharged into Fourth Creek (Figure 3).
The groundwater treatment system is permitted under the National Pollution Discharge Elimination
System (NPDES) program. Under the program, bi-monthly site visits are conducted when the system is
operational to monitor the treatment system and be sure it is operating within the permitted discharge
limits. Effluent water samples are collected bi-monthly and the data is reported to the DWQ on monthly
Discharge Monitoring Reports.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2011 Annual Groundwater Monitoring Report
February 22, 2012
Page 2 of 4
Groundwater Treatment System Modifications and Monitoring Activities
2.1 Groundwater Treatment, System Upgrades and Recovery Well Repairs
The groundwater remediation system operated during this reporting period from November 9, 2010, to
April 20, 2011, when the system was shut off for the summer months. In November 2010 Duncklee &
Dunham, P.C. (Duncklee & Dunham) personnel along with Air Drilling, Inc. of Statesville, North
Carolina inspected the condition of each recovery well and the associated submersible pumps. It was
determined that all three pumps required replacement or repairs. Recovery pumps were replaced in RW-2
and RW-6 and the impellers on the pump in RW-5r were replaced. The pumps were fully operational on
November 24, 2010. The system was restarted on October 25, 2011.
2.2 Groundwater Treatment System Monitoring Activities
In accordance with the NPDES permit, effluent samples were collected bi-monthly between November
2010 and April 2011 for analysis of total suspended solids (TSS) according to Method 2540D and
ammonia nitrogen according to EPA Method 350.1. Monthly effluent samples were also collected and
analyzed for copper (EPA Method 200.7), chloride (Method SM 4500-C1-E), TSS, ammonia nitrogen,
total Kjeldahl nitrogen, nitrate nitrogen and phosphorus all by EPA Method 300 series. The samples were
submitted for laboratory analysis to Pace Analytical Services, Inc. (Pace), a North Carolina certified
analytical laboratory. During the 2011 compliance reporting period, discharge monitoring reports
(DMRs) were submitted monthly to DENR as required by the NPDES permit. Monthly DMRs were not
submitted between May and September 2011, while the system was not operational as approval by the
DENR-DWQ on June 9, 2011.
Groundwater Sampling Activities and Results
Semiannual groundwater monitoring activities were conducted on April 21 to 22, 2011, and November 1
to 2, 2011. Potentiometric maps illustrating the shallow groundwater flow for the April and November
sampling events are shown on Figures 4 and 5, respectively. The groundwater flow direction during both
events was to the south-southwest. During the April 2011 monitoring event the average hydraulic
gradient in the northern portion of the aquifer, north of the 70 Bypass, was 0.028 feet per foot (ft/ft) and
0.023 ft/ft south of the 70 Bypass. The average hydraulic gradient was 0.025 ft/ft north of the 70 Bypass
and 0.012 ft/ft south of the 70 Bypass during the November 2011 monitoring event. The K65W7J well
casing was damaged during the November 2011 sampling event and therefore not included in the
groundwater flow calculation due to a change in the top of casing elevation.
3.1 Groundwater Sampling Methodology
Prior to well purging and sampling, water level measurements were collected using an electric water level
probe and recorded on field sampling data sheets (Appendix A). The groundwater level measurement
data is summarized on Table 1.
DUNCIa.BF; & DUNI IAA4, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2011 Annual Groundwater Monitoring Report
February 22, 2012
Page 3 of 4
Groundwater samples were collected from twelve (K65W6A, K65W6B, K65W6E, K65W6M, K65W6N,
K65W7C, K65W7D, K65W7F, K65W711, K65W7J, K65W7K and K65W7L) of the fourteen monitoring
wells during the April 2011 sampling event. The two remaining monitoring wells, (K65W6D and
K65W7G) were dry during this event.
Groundwater samples were collected from ten (K65W6A, K65W6B, K65W6E, K65W6M, K65W6N,
K65W7D, K65W7H, K65W7J, K65W7K, and K65W7L) of the fourteen monitoring wells during the
October 2010 sampling event. The four remaining monitoring wells were dry (K65W6D, K65W7C,
K65W7F and K65W7G).
The sampling process consisted of inserting a two-inch submersible electric PVC pump with new
disposable polyethylene tubing in each well to purge and withdraw the samples. The groundwater
samples were collected using low flow sampling techniques. During the sampling process, field
measurements were collected for dissolved oxygen (DO), oxidation reduction potential (ORP), pH,
temperature, turbidity, and electrical conductivity. The field measurement data collected during each
sampling event are summarized in Table 2 and the field data sampling forms are included in Appendix A.
Groundwater samples were collected and placed directly in laboratory -provided containers, labeled,
recorded on a chain -of -custody form, and transported to the analytical laboratory in an insulated cooler
filled with ice. The samples were submitted to Pace and analyzed for nitrate according to EPA
Method 353.2 and ammonia nitrate according to EPA Method 350.1. The laboratory analytical reports
and chain of custody records for both sampling events are included in Appendix B.
3.2 Results from 2011 Sampling Events
3.2.1 Nitrate Results and Trends
Groundwater plume maps illustrating nitrate concentrations in the shallow saprolite and deep bedrock
monitoring wells are presented on Figures 6 through 9. Nitrate results in groundwater are listed on Table
2. Graphs of the nitrate trends over time are included in Appendix C.
The following observations have been made with respect to the nitrate plume for this groundwater
monitoring period.
• The saprolite monitoring well K65W6A located near the former Pond B, (Figures 6 and 8) showed
consistent nitrate levels during the 2011 monitoring period while levels in saprolite monitoring well
K65W6B located near the former Pond A increased during the November 2011 monitoring event but
remained within historical levels. Both of these wells contain nitrate concentrations greater than the
North Carolina groundwater standard (2L standard) of 10 mg/L.
• The saprolite well along the southeastern edge of the plume (K65W6M) did not contain nitrate above
the 2L standard.
• The saprolite well along the northwestern edge of the plume (K65W6N) has contained nitrate above
the 2L standard since it was installed in 2008. After an initial increasing nitrate trend immediately
after the well was installed, the levels have decreased since October 2009.
• The saprolite well K65W7J located in the core of the plume contains nitrate above the 2L standard.
The nitrate level in this well had been on an increasing trend until October 2009 but has since leveled
off.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2011 Annual Groundwater Monitoring Report
February 22, 2012
Page 4 of 4
• Of the two saprolite plume wells at the southern extent of the plume, K65W7G was dry
during this monitoring period and the slightly deeper well (K65W7F), contained nitrate at 6.7 mg/L in
April 2011 and was dry in November 2011.
• The saprolite plume delineation well (K65W7D), located in the southwest portion of the site, did not
contain nitrate in groundwater above the ' laboratory reporting limit of 0.20 mg/L in April and
November 2011.
• The nitrate level in the samples collected from saprolite monitoring well K65W7C in April 2011 was
9.4 mg/L and the well was dry during the November 2011 sampling event.
• Groundwater in the bedrock monitoring well K65W6E exhibited an increase in nitrate in April 2011
though the nitrate level decreased in November 2011. However, the nitrate level remains above the
2L standard and the overall nitrate concentration trend remains upward in this well.
• The two bedrock wells (K65W7K and K65W7L) located in the core of the plume contain nitrate
above the 2L standard. The nitrate concentrations in these wells fluctuated but remain within
historical levels.
• The bedrock delineation well (K65W7H) at the southern extent of the plume has not contained nitrate
above the 2L standard since it was installed in 2008.
3.2.2 Ammonia Results and Trends
Ammonia results in groundwater are listed on Table 2. Graphs of the ammonia trends over time are
included in Appendix C. The following observations have been made with respect to the ammonia plume
for this groundwater monitoring period.
• The saprolite well K65W7J located in the core of the plume contains ammonia above the North
Carolina 2L groundwater standard of 1.5 mg/L. The ammonia level in this well has been on a slightly
increasing trend since 2007.
• Ammonia was detected during this monitoring period at concentrations below the 2L Standard in
saprolite wells K65W6A, K65W6B, K65W6N and K65W7D.
• The bedrock well K65W6E and the bedrock wells located in the core of the plume (K65W7K and
K65W7L) contain ammonia above the 2L standard. The ammonia concentrations in K65W6E,
K65W7K, and K65W7L remained constant during the 2011 monitoring period.
• Ammonia has not been detected in the downgradient plume delineation bedrock well (K65W7H) in
the southwestern portion of the site since it was installed in 2008.
4 Recommendations
Based on the information presented above, Duncklee & Dunham recommends the following:
• Continue to operate the groundwater treatment system in accordance with the NPDES permit during
the time period between November 1, 2011 and March 31, 2012. However, Southern States may
elect to operate the treatment system between April 1 and October 31 if aquifer conditions allow.
• Continue semiannual groundwater plume monitoring.
DUNCKLEE & DUNHAM, P.C.

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Treatment P
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Solute of base map: Canonie Environmental Corrective Action Plan - January 1994
Discharge Point
to Creek
Treatment System
Discharge Line
70
Highway 70 Bypass
DUNVLEE
ENVIRONMENTALCONSULTAN
511 KEISLER DRIVE SUITE 107
DTT1TJ_JJQCARY.
NORTH CAROLINA 27518
OFFICE (919)85& 98
WEB DUNCKLEEDUNHAALCOM
Job Number
Layers
50200
0,2
Drawing Size
figure
8.5 x 11"
3
Scale
Date
1"= 0.25 miles
11-2011
Title
Treatment System Discharge Line Outfall Map
Project Southern States Fertilizer Plant
Statesville, North Carolina

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DUNCKLEE & DUNHAM, P.C. Approximate Scale: Title: I" = 2000' Site Location Topographic Map
ENVIRONMENTAL CONSULTANTS
511 KEISLER DRIVE - SUITE 102 Figure: Project: Southern States Cooperative, Inc.
CARY, NORTH CAROLINA 27511 1 Statesville Fertilizer Plant
Statesville, North Carolina

Table 1
Summary of 2011 Well Water Level Gauging Data
Southern States, Statesville, North Carolina
Wells
Aquifer
Code
Date
TOC
Elevation
Total Well
Depth (ft)
Depth to
Water Table
(ft bmtc)
Water Table
Elevation
(ft 1VMSL
K65W6A
Sap
04/21/11
864.52
58
27.69
836.83
11/01/11
28.09
836.43
K65W613
Sap
04/21/11
871.55
30
22.78
848.77
11/01/11
24.61
846.94
K65W6D
Sap
04/21/11
846.37
38
DRY
DRY
11/01/11
DRY
DRY
K65W6E
BR
04/21/11
864.89
133
27.86
837.03
11/01/11
31.79
833.10
K65W6M
Sap
04/21/11
837.84
50
38.62
799.22
11/01/11
35.84
802.00
K65W6N
Sap
04/21/11
845.30
50
9.86
835.44
11/01/11
13.20
832.10
K65W7C
Sap
04/21/11
809.72
22
19.98
789.74
11/01/11
DRY
DRY
K65W7D
Sap
04/21/11
800.64
23
8.63
792.01
11/01/11
13.28
787.36
K65W7F
Sap
04/21/11
796.15
28
23.35
772.80
11/01/11
DRY
DRY
K65W7G
Sap
04/21/11
795.98
15
DRY
DRY
11/01/11
DRY
DRY
K65W7H
BR
04/21/11
796.07
112
11.22
784.85
11/01/11
11.81
784.26
K65W7J
Sap
04/21/11
851.25
60
42.30
808.95
11/01/11
40.27*
NA
K65W7K
BR
04/21/11
852.30
121
43.49
808.81
11/01/11
43.84
808.46
K65W7L
BR
04/21/11
848.14
200
43.06
805.08
11/01/11
42.88
805.26
otes:
TOC - top of casing
MSL - mean sea level
DRY - well was dry during this sampling event
* Well casing damaged and no longer at the surveyed elevation
t bmtc -feet below marked top of casing
quifer Code - Represents aquifer being monitored at this well location (Sap.=Saprolite and BR=Bedrock)
All measurements are in feet
A - Not Applicable
P:\Southern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Table 2 .
Summary of 2011 Groundwater Analytical and Field Parameter Results
Southern States, Statesville, North Carolina
Laboratory Data
Field Parameters.
Ammonia
Nitrate
pH
Temp.
Well
Date
Conductivity
Turbidity
ORP
DO
mg/L
mg/L
Standard
Units
Degrees
Celsius
MS/cm
NTUs
mV
mg/L
2L Standard
1.5
10
04/22/11
0.30
118
NM
NM
NM
NM
NM
NM
K65W6A
11/02/11
0.33
120
5.66
16.24
3.7
68.2
247
0.58
04/21/11
0.61
26.9
4.38
19.12
0.89
28.4
468
5.20
K65W613
11/01/11
<0.10
38.4
3.95
17.03
0.99
20.9
375
0.00
04/21/11
NS
NS
NM
NM
NM
NM
NM
NM
K65W6D
11/01/11
NS
NS
NM
NM
NM
NM
NM
NM
04/22/11
1.6
3.11
6.57
15.82
6.3
40.3
323
1.09
K65W6E
11/02/11
1.8
278
6.42
16.22
6.3
37.2
191
0.66
04/21/11
<0.10
<0.20
5.91
16.83
0.07
132
394
6.66
K65W6M
11/01/11
<0.10
0.37
5.34
15.52
0.07
37.8
338
1.82
04/21/11
1.3
61.4
7.33
17.08
1.9
109
255
2.71
K65W6N
11/01/11
0.99
50.2
6.64
15.57
1.5
230
225
1.33
04/21/11
<0.10
9.4
6.00
13.83
0.32
32.8
440
5.94
K65W7C
11/01/11
NS
NS
NM
NM
NM
NM
NM
NM
04/21/11
<0.10
<0.20
4.99
12.88
0.11
46.8
465
1.57
K65W7D
11/02/11
0.18
<0.20
5.13
13.30
0.10
37.3
97
1.27
04/21/11
<0.10
6.7
6.53
14.38
0.39
51.2
409
5.80
K65W7F
11/01/11
NS
NS
NM
NM
NM
NM
NM
NM
04/21/11
NS
NS
NM
NM
NM
NM
NM
NM
K65W7G
11/01/11
NS
NS
NM
NM
NM
NM
NM
NM
04/21/11
<0.10
0.40
6.45
14.44
0.12
27.6
399
5.91
K65W7H
11/01/11
<0.10
0.36
6.24
14.44
0.12
48.6
279
2.30
04/21/11
3.3
162
5.90
16.20
2.1
420
235
1.22
K65W7J
11/02/11
2.8
184
5.48
14.87
2.3
43.1
253
0.00
04/21/11
2.8
92.3
6.89
16.36
1.7
135
212
1.50
K65W7K
11/02/11
2.7
85.3
6.48
14.12
1.7
147
205
0.74
04/21/11
7.0
96.4
6.30
15.54
1.7
54.7
274
1.36
K65W7L
11/02/11
12.0
116
5.71
14.22
1.8
27.3
278
0.00
Motes.
Bold indicates above the laboratory method detection limit
Bold and shaded indicates a A Standard exceedence
NS - not sampled - dry well
low flow parameters not measured
S/cm - milli-Siemins per centimeter
NTUs - nephelolometric turbidity units
V- milli -volts
�nglL - milligrams per liter
PASouthem States\Statesville Fertilizer - 5020MExceXutrent Annual Report tables\Annual Report Tables

DiJNCKLEE 71
8c DLJNHAM
Ground Water Sample Collection Record
WailiSamplo ID: ? O--t_
Client: 43 5 — C-1rk:Soal,f. Dater
Project No: 5--1'A -v; 120'
Site Location: ' 4(011�.._
Weather Conds: �} (_\!1� Cq nr ��Gf �' ` Collector(s): irJ t�
WATER LEVEL DATA: `�— Watl Plezomotor O
a. Total Well Depth (ft bmp) Q 3 c. Casing Material 1'� L e. Length of Water Col. (a•b)
,
b. Water Table Depth (ft bmp) } I d. Casing Diameter t f. Calculated Wall Vol.
2"=617mllft and 4'=2470mlM
a. Purge MethodlEquipment_C) D'f.5'i ,-1Ii- V `
'per -� jaj
b. Total Purge Volume ^- u� Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate
(11min)
- Maximum Allowable Turbidity
NTUs
- Stabilization of parameters
d. Field Testing Equipment Used: Make
Model Serial Number
h�r,Yx•_
r : ���
��_—����f4'41i►7�—
e. Acceptance cntena passrrau
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low now been maintained at <O.1fumin
If no or WA - Explain in comments
SAMPLE COLLECTION:
roe Na / /
u o
❑ ❑
❑ ❑
Dissolved CO, ■
Sulfide
Fo+2
NO3
Sample ID
Container Typo
No. of Containers Prose rally
Analysis
Time
i
Comments:
IDW (Note other mothad of handl(n®):
Signature:

DUNCKLEE
c4c DUNHAM
Ground Water Sample Collection Record
Well/Sample ID: 1/ &5 =444
Date: L- 'li("1
Project NO:
LJ
Site Location:
.Cy7Nt:
lylW
WeatherConds:
N
Co1leMogs):
WATER LEVEL DATA:
Well TC-�' Piezometer
a. Total Well Depth (ft bmp)
�� _
c. Casing Material PV
e. Length of Water Col. (a-b)
b. Water Table Depth (fi bmp)
tl. Casing Diameter fr
1. Calculated Well Vol.
2"=617mVft and 4"=2470mVh
WELL PURGING DATA:
a. Purge MothodlEqutpment /� X l VVlp-
b. Total Purge Volume ^' : L Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate
IVmir0
• Maximum Allowable Turbidity
NTUs
Stabilization of parameters
%
d. Field Testing Equipment Used: Make
Model Serial Number
e. Acceptance criteria passlfail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at -0.1 ft1min
If no or NIA - Explain in comments
SAMPLE COLLECTION:
Yes No LY
O
f9 /� ❑ ❑
Dissolved COr
Sulfide
Fet2 L'
NO3
Sample ID
Container Typo
No. of Containers Preserativi
Analysis
Time
n 1:
- -
II&V
0
1
Comments:
IDW (Note other method of handling):
yr
Signature:
I I �CL '✓/'(,i y' ///

DLTNCKL..EE
mac. DUNHAM
Ground Water Sample Collection Record
Wa1lfSampIs ID: tj l ram.
Client:.
�i-t•�C1Jt��/. ��•��l�t'•'Y
Date: �� I
Project No:
Site Location:
��
ttYi �1rJ
I_U L
I
R
N (`'` r
Collector(s):��)
Weather Conds:
[ CIACIGL
WATER LEVEL DATA:
Well Piezometer O
a. Total Well Depth (ft bmp)
!
On
c. Casing Material
Length of Water Col. (a•b)
b. Water Table Depth (it bmp)
t
3( ) J
d. Casing Diameter ��
f. Calculated Well Vol.
2"=617mUft and 4"=2470mU(t
WELL PURGING DATA:
n
a. Purge Method/Equipment
b. Total Purge Volume Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate (ymin)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
Time
(military)ft
WL
bmp)liters
Vol Evac
Flow
(liters/min)(standard)NTUs
pH
Turbidity
DO
m
T•`
celsius
ORP
mV)
Odor/Color
Other
,.
*P9;
e. Acceptance criteria.passlrall
Les
No
N
❑,%
❑
Has required volume been removed
Dissolved 007 =
•--��
[�
❑
❑
Has required turbidity been reached
/
Sulfide
'
Have parameters stabilized[
❑
❑
FeF2
Has Low now been malntained at c0.lnlmin
❑
❑
NO3
If no or NIA - Explain in comments
SAMPLE COLLECTION:
sample ID
Container Typo
No..of Containers Prescradvt
Analysis
Time
s
Comments:
IDW (Note other method of handling):
Signature: L %

A
DUN C KL EE
8r. DLTNHAM
Ground Water Sample Collection Record
SS - � 7tC�-iC'�,sJ i l I.� �c�,�•�i 1 rZe K
Project No: �5'-YA tJ L) 1
Site Location: �C(}CSJ` l�{ (l t.
Weather Conds: �IJV1f'l( 1� k ? UD
WATER LEVEL DATA:
a. Total Well Depth (ft bmp) , I C. Casing Material «!
+ll
b. Water Table Depth (ft bmp) �� t' t•� d. Casing Diameter U
a. Purge Method/Equipment /1(',KiC•�Ca�r}l1: - ��-�'�j)S
b. Total Purge Volume ram' Oij S Gallons
Well/Sample ID: 1 j
tl
Date:
T.
Collector(s): 'IA .1"A r
i
Well Plezometer O
e. Length of Water Col. (a•b)
I. Calculated Well Vol.
c. Acceptance Criteria:
- Purge Volume (Q _ well volumes) or rate (I/min)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters
d. Field Testing Equipment Used: Make Model Serial Number
e. Acceptance criteria passlfall
ea❑
No
Has required volume been removed
�
IS
�
Dissolved CO=.
Has required turbidity been reached
O
Sulfide
Have parameters stabilized
/
❑
Fe*2
f7•
Has Low flow been maintained at <0.ttUmin
[gy
❑
❑
NOJ
If no or WA - Explain in comments
SAMPLE COLLECTION:
Sample ID
Conlolner Typo
No. of Containers Preserath,4
Analysts
Time
Comments:
IDW (Note other method of handling):
i111 !d1 i
Signature: >> 7 Vu• CA

DUNCKLIF, E
8r. DUN F-IANi
Ground Water Sample Collection Record
Well/Sample ID:
Client: `1` f=� i 114 �'t-.t -ViYi Z{i Y Date: `i 1
Project No:
Site Location: -,-A
WeatherConds: c lic5-VtO.-•{ .'L in Collector(s): LJ't'il
WATER LEVEL DATA: Well Plezometer O
a. Total Well Depth (ft bmp) c. Casing Material �j/ L e. Length of Water Col. (a-b)
b. Water Table bm (it Depth �� �� g Diameter i / Calculated Well Vol.
p ( p) �' d. Casing 'i L
a. Purge Method/Equlpment
b. Total Purge Volume 't-'�r C> Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate
(Vmin)
- Maximum Allowable Turbidity
NTUs
• Stabilization of parameters
%
d. Field Testing Equipment Used: Make
Model Serial Number
1' u'ItS.Ta •
t�y,��'.�
Time
(military)ft
WL
bm)
Vol Evac
liters
Flow
liters/min
pH
standard
Spec. Cond
(S/cm
Turbidity
NTUs
DO
m
T° °
Celsius
ORP
mV
Other
`Oil
1
' 3&rLI
SU
oi
Or/Color
L
7
6,ot
n q,b,i
o
`b is
Q
e. Acceptance cntena passnau
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at <0.1ft/min
If no or N/A - Explain in comments
SAMPLE COLLECTION:
Yes DLO NNE
0 ❑ C'l Dissolved CO2
Sulfide =
u ❑ ❑ Fe+2
❑ Cl NOJ -
Sample ID
Container Type
No. of Containers Proserative
Analysis
Time
Comments:
IDW (Note other method of handling):
Signature:
f

DILTNCKLEE
SL Y> IJ N IAA M
Ground Water Sample Collection Record
Client:
.\u,.ljj
Project No:
(a ol-)
Site Location:
CL�P`�l?y�
iWeatherConds:
S
i)!-t
WATER LEVEL DATA:
a. Total Well Depth in bmp) •.,� >,.% t C. Casing Material JV
b. Water Table Depth (ft bmp) 0 a. d. Casing Diameterrt
Well/Sample ID: r� w�
Date: } I
Collector(s): (.`•%` l F
Well 12:5� Plezometer O
e. Length of Water Col. (a-b)
f. Calculated Well Vol.
a. Purge Method/Equipment
b. Total Purge Volume Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate (Vmin)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
Time
milita
WL
ft bm
Vol Evac
liters
Flow
literslmin
pH
standard
Spec. Cond
S/cmi
Turbidity
NTUs
DO
m 1L
To `
Celsius
ORP
mV
Odor/Color
Other
i 1l-
U
L
�)
C
.; ,
a c
c.
19 90
�-I •
e. Acceptance criteria passlfall
T-
NJP/
Has required volume been removed
❑es
Dissolved C%=
i�
❑
Has required turbidity been reached
/
Sulfide
�j
c9rU
Have parameters stabilized
Fe*2
Has Low flow been maintained at <0.1ftlmin
d
NO3
If no or N/A - Explain in comments
SAMPLE COLLECTION:
Sample ID
Container Typo
No. of Containers Preserativ
Analysis
Time
Comments:
IDW (Note other method of handling):
1
f 2C r'
Signature:
V r
i.'

DLTNCKLEE
8c. DLJNI-IAM
Ground Water Sample Collection Record
Walusamplo ID: Gs
s Loa !
Client:
t
5..}- �"�e"C'riy:}
( Q _
Date:
Project No:
_yx;C:?q o--)
Site Location:
��Ct}�?tii)'.Clp ') (- - -
} �n D F
Collector(s):
Weather Conds:
Pit C-l(.',.- C
fit. C.' LA= -
WATER LEVEL DATA:
Well EZZ Plezometer
a. Total Well Depth (ft 6mp)
i�'i C 1
r
c. Casing Malarial
Length of Water Col. (a-b)
e.
7�
b. Water Table Depth (it bmp)
4(.�t✓
d. Casing Diameter -
f. Calculated Well Vol.
2"=617mUft and 4"=2470m11ft
WELL PURGING DATA:
n_
a. Purge Method/Equipment ' 1- • r 6Wl �lAJ
b. Total Purge Volume -"-Q f O Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate (11min)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters
d. Field Testing Equipment Used: Make Model Serial Number
r;f ir, ct - ( A ;2a
f�i��fL����e�7��]l�C��G�11l�7f�
c •
�
e. Acceprance cmmna pasanau
Te`3
0
no
1'IIM/
Has required volume been removed
a
Dissolved CO, =
0"
❑
Has required turbidity been reached
SulfideHave
�(
0
parameters stabilized
Fo+2
Has Low flow beon maintained of c0.lftrmin
d
N07
If no or NIA . Explain in comments
SAMPLE COLLECTION:
sample ID
Container Typo
No. of Containers Prestrativc
Analyele
Time
Comments:
IDW (Nato other method of handling)i
Signature ALI, 4&1V4h,&1L

TSUNC�T`LT:—:7E
Ground Water Sample Collection Record
act No: Da C li
Location:
ther Conds: <l4?C'� �Li i'.�oU (A1d
WATER LEVEL DATA:
a. Total Well Depth (R bmp)) e. Casing Material
b. Water Table Depth (ft bmp) 1.� . J l �L\ d. Casing Diameter �) 1
We1115ample ID:
Date: I- _ n) - I )
r
Collector(s): 1 .V tiM {'
Well E:�Z Plezometer O
e. Length of Water Col. (a-b)
f. Calculated Well Vol.
a. Purge Method/Equipment fl:l.rin eo ^
b. Total Purge Volume -q L) Gallons
c. Acceptance Criteria:
- Purge Volume (@ _well volumes) or rate (Ilmin)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
Time
(military)ft
WL
bm
Vol Evac
liters
Flow
liters/mint
pH
standard
Spec. Cond
(PS/Cm)(NTUs
Turbidity
DO
m IL
T° `
(Celsius)
ORP
mV1
Odor/Color
Other
- �7
)
�- L n
.�
3: �
�J. CSC
/ �
lei -f
o ^r Tr
^
C) -
`1
l IG. a
- �5
,Ci Q
1, w,
i 5. C'
e. Acceptance Criterla passliall
yes
No
Nam/
Has required volume been removed
Dissolved CO,
t3L�
❑
❑
�^
Has required turbidity been reached
Sulfide =
❑
❑
Have parameters stabilized
Fe+2
Has Low flow been maintained at <0.tft/min
❑
❑
NO3
If no or N/A - Explain in comments
SAMPLE COLLECTION:
Sample ID
Container Type
No. of containers Preserativ
Analysis
Time
f
6/
I
. C-
4 i G
Comments:
IDW (Note other method of handling):
Signature:
/ I

D' JNCK.LEE
8t DLINHAM
Ground Water Sample Collection Record
We111Sample ID: L
Client: Date:
Project No:
Site Location: . T,�e?i•�j,�`a ,�{�i9�.
WeatherConds: :1-�'(i'�t A r`jtylllV,�. �' �liG Collector(s): w�
WATER LEVEL DATA: Well Plezometer 0
a. Total Well Depth (ft bmp) r i i ( c. Casing Material s V e. Length of Water Col. (a-b)
b. Water Table Depth (itbmp) q3, l7J y6 d. Casing Dlemeter� f. Calculated Well Vol.
a. Purge Method/Equipment
1
b. Total Purge Volume fl' ,�j Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate
(11min)
- Maximum Allowable Turbidity
NTUs
- Stabilization of parameters
oA
d. Field Testing Equipment Used: Make
Model Serial Number
Time
(milita
WL
n bm
Vol Evac
liters
Flow
liters/min
pH
standard
Spec. Cond
Slcm
Turbidity
NTUs
T°`ORPOdorlColor
Celsius
mV
Other
gDO
t 5
U' J�1
1
'L
Ll ps
rgq
5
y
0. Acceptance criteria passffall
Ye§
IVO
NIA /
Has required volume been removed
❑ /
•4lr/
Dissolved CO,
Has required turbidity been reached
Sulfide
'J
Have parameters stabilized
/
Fer2
�.
Has Low flow been matntalned at <0.1 rr/min
d
NO3
If no or N/A - Explain in comments
SAMPLE COLLECTION:
Samplo ID
Container Typo
No. of Containers Proscrativc
Analysis
Time
, r `
f
, L2
j --I 05
�r �!
b
'lug•..
Commante :
IDW (Note othor method of handling):
signature: ✓ -4L

DUNC!F-1
S-- DUNHAM
Ground Water Sample Collection Record
Well/Sample ID: ��J J•-fY
Date: -
Project No:
(�',
V
Site Location:
e C14tayt1U
0
Weather Conds:
W O VA-
C [1\XWQ L�n�
Collector(s): \-A,- M
U
i
WATER LEVEL DATA:
Well Plezometer O
a. Total Well Depth (ft bmp)
�V
c. Casing Material Pr.
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
�13L
d. Casing Diameter fi
f. Calculated Well Vol.
7'=617mVft and 4"=247DmVft
WELL PURGING DATA:
a. Purge MethodlEqulpment C I n yJ ��
b. Total Purge Volume Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate (Vmin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Mod Serial Number
�M�
��
�
�®
e. Acceptance cntena passman
rotes
NO
rvy
(�
Has required volume been removed
_ /
Dissolved COr =
❑
❑
Has required, turbidity been reached❑d
Sulfide
❑
Have parameters stabilized
Fei2
Has Low flow been maintained at <0.11`Vmin
❑
❑
13
NO3
If no or NIA - Explain in comments
SAMPLE COLLECTION:
Sample ID
Container Type
No. of Containers Preserativc
Analysis
Time
G
f
ba
ivf
r
mmc1 ic,
Comments: PiLtel [u) •' f] ^i' `f I
I ( Q
IDW (Note other method of handling):
Signature:ill,/ - a
/ r
t

DU2V CK:LEE Wall/Sample ID:
�c DCJNI3AM �t�5 w fo,4 _
i
Ground Water Sample Collection Record
Client:
`;� '.Zir F�`i 1i
Date: i k !t
Project No:
Site Location:
'n `�,A.fnv 1 lik
1 t tC:�
t!
WeatherConds:
Got, 1
. \ ti
Collector(a): W Y
WATER LEVEL DATA:
Well Piozometer O
a. Total Well Depth (ft bmp)
d
c 1`73
1n5
c. Casing Material t' ��
e. Length of Water Col. (a-b)
It. Water Table Depth (it bmp)
r' • f ari
d. Casing Diameter •�i• 1
f. Calculated Well Vol.
21'=B17mltft and 4"=2470MVft
WELL PURGING DATA:
a. Purge Method/Equipment II ,,hVkYiLr l n—A t U t(
b11). Total Purge Volume l.Gallons
c. Acceptance Criteria:
- Purge Volume (@ _ well volumes) or rate (Umin)
- Maximum Allowable Tumidity NTLIs
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Acceptance cnteno pasarrau
r
r)_O
Has required volume been removed
E1
❑
O
Dissolved CO, o
i
❑
❑
Has required turbidity been reached
Sulfldo
Have parameters stabilized
❑
❑
f
/
Fer2
ii `
❑
❑
p/
Has Low now been maintained at <0.1 fumin
NO3
It no or WA - Explain in comments
SAMPLE COLLECTION:
Sample ID
ContainerContainer Typo
No. of Contalnors Prasorativ
Analysis
Time
/
1 ilak
•L,
Commonte: ? l t?1v e CA��
IDW (Nola other method of handling):)
Signature: J

DUI- CICLE E
BSc DUNI3AM
Ground Water Sample Collection Record
Well/Sample-ID:
Client: ��'��(,ttQ�lVll� Date:
Project No: r r
Site Location:
WeatherConds: t% n If1Ll ' k (00Collector(s): %JVlll
WATER LEVEL DATA: n �
Well Plezometer 1
a. Total Well Depth (R bmp) )) C. Casing Material r V L e. Length of Water Col. (a b)
i
b. Water Table Depth (it bmp) d. Casing Dlamoter.f. Calculated Well Vol.
7=617mIHt and 4"=2470m11ft
WELL_ PURGING DATA:
a. Purge Method/Equipment JOIJ -rl Cw
I
b• Total Purge Volume Gallons ,�LLf Y�'�-�C� 1i iJ `�G':)5 \{ ��'1 DUI• �-` t GX '�l G 4 t. I+L+✓�t'��,
c. Acceptance Criteria: J
- Purge Volume (@ _ well volumes) or rate (Ilmin)
- Maximum Allowable Turbidity NTUs
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
W,Qci it-�;a
MEN
ELM".
e. Acceptance criteria pasWfall
Yes r�Q
❑
N
Has required volume been removed
Dissolved CO=
Has required turbidity been reached
Sulfide
Have parameters stabilized
HQ"// ❑
❑
Fe+2
Has Low flow been maintained at <0.11tlmin
❑
❑
NO3
If no or WA - Expian in comments
SAMPLE COLLECTION:
Sample10
Container Type _
No. of Containers Preserative
Analysis
Time
t7 (,,t
Comments:
IDW (Note other method of handling):
Il,
Signature: d—r �L

D LJN C It L.EE Well7plezo :
.9L ]D, UN " A-M Sample ID
Ground Water Sample Collection Record
Client: SS -Statesville Date:
Project No: 50200 Time: Startam/pm
Site Location: Statesville. NC Finish am/pm
Weather Conds: Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well d Piezometer
a. Total Well Depth (ft bmp)$ O t c. Casing Material P V L e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) :� d. Casing Diameter '�)" f. Calculated Well Vol
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used:
Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes
No
NI l
Has required volume been removed
❑
❑
/ Dissolved CO2 = MA
Has required turbidity been reached
❑
❑
M Sulfide =NA
Have parameters stabilized
❑
❑
Fe+2= -^ t l
Has Low flow been maintained at >O.1ft/min
❑
❑
©NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample ID
Container Tv a
No, of Containers
Preservation
Analysis
Time
;'4 .•
!ta5 tin masaa
n
ime=
Iu etc
r
125 ml plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in drum or note other method of handling
Signature l xi: (/1' J` 9 .. Dale t'
Dunakidu Dunham, P.D.
(:nVlPanmanlal d0n§unAms
511 I mler Dt, 6une 792 Phone 919.AAA.9A9B
Cary, Nonh darohna V git Pax; 919 UO.9A99

DUNCKI,E]F— e lezo
8-- ISam le ID /
Ground Water Sample Collection Record
Client: SS -Statesville Dater I _ I - ) I
Project No: 50200 Time: Start I. L`3 am/pm
Site Location: Statesville, NC Finish am/pm
Weather Conds: Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer
a. Total Well Depth (ft bmp) 5t, c. Casing Material FIu e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) Cl. Casing Diameter ft f. Calculated Well Vol.
2"=617mllft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used:
Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
ft bmp
VolWL
Evac. I
ow
Ilmin
T'.
pH
Spec.Cond
mS/cm)
I urniclity
(NTUs)
DO
ORP
Odor/Color
Other
i
i5.1-i
�. a
►,
33d
(D�C'D
'3
qt)(6,
,co
3i
1 -51
In (i5
�,�i
(P5S
t5
Z9
DO
(11
li,55
0'0
5 li
6-�o
1,5
►(0
0,511
3 5
5,
GI&I-1
I I 5
' C11
o,
L4
3
0-3
� S
3.3
o'
3c:>
e. Acceptance criteria pass/fail
Yes
No No/
Has required volume been removed
❑
❑ /
Dissolved CO2 = MA
Has required turbidity been reached
0
p' ❑
Sulfide =NA
Have parameters stabilized
❑ ❑
Fe+2= \
Has Low flow been maintained at >0.1ft1min
❑
l� ❑
NO3 =
If no or N/A - Explain below.
Gt61 St'C6'115ILA)r k'0-rhrrl-;:/,
yn
iFutl.�— ;r,'.S
cI',(,lorl-4L.r?-ilt;,k;-r,3o 1�c,�/
SAMPLE COLLECTION: Method:
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
�t
125 MI Plastic
1
none
Nitrate
1,
125 mi plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in tlmm or note other method of handling
Signature
Date
Duncklee Dunham, P.C.
Environmental Consultants
511 KOS. Dr, Suite 102 Phone 00,858.9898
Cary, North Carolina 27518 Fax: B1B.888.8884

DUNCKLEE a Iezo : ,C u-Tf ;
ISam IeID A/ a
Ground Water Sample Collection Record
Client: SS -Statesville Date: 1 I •-
Project No: 50200 Time: Startam/pm
Site Location: Statesville, NC Finish am/pm
Weather Conds: i. U1.1 r- , 1/11i ° �- Collectors) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well (ff Piezometer El
a. Total Well Depth (ft bmp) t c. Casing Material Put, e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) '-f . {SJ d. Casing Diameter N tL f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (1/min) �u,�W d f— r, S �r- L
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
�fLi:llii��L3U����
• - •
• •
��
•
e. Acceptance criteria pass/fail
Yes No
N/A
Has required volume been removed
o/
Has required turbidity been reached
Q O
❑
Have parameters stabilized
❑
❑
Has Low flow been maintained at >0.lfUmin
❑
❑
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Dissolved CO2 = MA
Sulfide =NA
Fe+2= fr, t
NO3= NA
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
125 MI Plastic
1
none
Nitrate
�' d
125 ml plastic
1
H2804
Ammonia
GtlrnMollie 1
I W Ploca In drum or not® other method of handling
r t !r
I,—Signoture /— �4�1
1l Dew
Dunokloo Dunham, P.C.
Enwrenmontal consultalrb
611 0111or Dr. aulto 102 Phono 010s39.Dt10e
Cary, North Carolina 27610 Fax: 010,11K0000

9-- ]DUTTHA -%4 Sample ID
Ground Water Sample Collection Record
Client: SS -Statesville
Project No: 50200
Site Location: Statesville. NC
Weather Conds: ('wli:`^( — ql>7 '1 Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing)
a. Total Well Depth (ft bmp) _'74-0G,t c. Casing Material N'.
b. Water Table Depth (ft bmp) (:l'� : d. Casing Diameter
WELL PURGING DATA
a. Purge Method/Equipment Low flow using pump and hodba
b. Acceptance Criteria defined (from workplan)
Purge Volume A well volumes) or rate (1/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model
Date: 1li 9,9- i I
Time: Startam/pm
Finish am/pm
Well 1Z Piezometer 0
e. Length of Water Col. (a-b)
I. Calculated Well Vol.
2"=617m11ft and 4"=2470ml/ft
�L V-4y tl
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #.
Serial Number
Time
ft bm
VolOW
Evac. I
I/min
T° ©OpH
peC. on
mSlcm
U I I
NTUs
DO
ORP
Odor/Color
Other
W; S '
N *
Ll
11�-0�.5A
''1tl
(,C
1tp5
C',CD
yo
o;
L.10
lu
')3
'A
qM(I
t�111
,gib
J
1l�v
t7a-t
31,3
e. Acceptance criteria pass/fail
Yes No
NIP
Has required volume been removed
n � El
Q
Dissolved CO2 = MA
Has required turbidity been reached
LDS l�
❑
Sulfide NA
Have parameters stabilized
[� ❑
❑
Fe+2= �
Has Low flow been maintained at >0.1ft/min
❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
125 MI Plastic
1
none
Nitrate
125 ml plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in drum or note other method of handling
Signature 4 I Date t
J
Duncklee Dunham, P.C.
Environmental Consultants
511 Kelsler Dr, Suite 102 Phone [phone]
Cary, North Carolina 27518 Fax: [phone]

]DUNCKL,7EE a ezo „ Lc.
I3UNI�AM Sam le ID
Ground Water Sample Collection Record
Client: SS -Statesville Date:
Project No: 50200 Time: Start am/pm
Site Location: Statesville, NC Finish am/pm
Weather Conds: (moo t Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well E9 Piezometer ❑
a. Total Well Depth (ft bmp) c. Casing Material e. Length of Water Col. (a-b)
Water Table Depth (ft bmp) H VI ) d. Casing Diameter f. Calculated Well Vol.
Ylci / �;l as�xt% CIiW iYl ivl air.:? `net l 2"=617mVft and 4"=24,
WELL PURGING DATA T(;(,-
a. rurge memoo:tquipment_ LOW r1oW using pump anc
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (1/min) NTUs
Maximum Allowable Turbidity
Stabilization of parameters %
c. Field Testing Equipment Used:
Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes
No
N/A�
Has required volume been removed
❑ /
❑
Dissolved CO2 = MA
Has required turbidity been reached
Have parameters stabilized
Gd
[�
❑
❑
❑
❑
Sulfide NA
Fe+2= 77
Has Low flow been maintained at >0.1ft/min
❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample ID
Container Typo
No. of Containers
keservatjon
Anal sis
Time
(.'7F - J
125 MI Plastic
t
nona
Nitrate
0 S
120 ml plastic
t
142SO4
Ammonia
Commonts : C1r.� a VLa:(�; i �W Y �111 •s FS�l1jf'te j�. GP i1 :-.: ��C_: ur�a<1 r-,A-Ul #x 1.41ilfl# 4 i lrlVi f tint �t1.
IDW: Placo in dru n or note other method of handling
17
r. 1
Signaturo � � CQp-A! Data - -JJ--
ff- I Ir
Dullemdd Dunhdlh, t':0,
FRWIM11MMO eumultdht5
A, l'cwltf Dr, Suite W f hWe 010.996.0508
0dry, NMIA 0ataliha 0514 Pdk: 60.69kot§o

D�JNCKLEE a lezo : v
8L I�UN�IAM Sam IeID
Ground Water Sample Collection Record
Client:
SS -Statesville
Date:
Project No:
50200
Time: Start am/pm
Site Location:
Statesville, NC
Finish am/pm
Weather Cords:
l"CPtY f 1 C` '
Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well LJ Piezometer (]
a. Total Well Depth (ft bmp)
f
c. Casing Material
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
d. Casing Diameter
f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes No
NIX'
Has required volume been removed
❑/ ❑
LI
Dissolved CO2 = MA
Has required turbidity been reached
❑
❑
Sulfide = A
Have parameters stabilized
f� ❑
❑
Fe+2= )
Has Low flow been maintained at>0.1ft1min
❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
+ t; 4
125 MI Plastic
1
none
Nitrate
L�
125 ml plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in drum or note other method of handling
Signature _ / G{4` �� Date l ' 01 — it
Duncklee Dunham, P.C.
Environmental Consultants
511 Kelsler or, Suite 102 Phone [phone]
Cary, North Carolina 27518 Fax: [phone]

DUNCKLEE I
WellipiezoN,
8L L UNHAM Sam le ID
Ground Water Sample Collection Record
Client: SS -Statesville Date: 11 " 1 1
Project No: 50200 Time: Startam/pm
Site Location: Statesville, NC Finish am/pm
Weather Conds: tlA(r- Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) I Well �] Piezometer ❑
a. Total Well Depth (ft bmp) '31 �c. Casing Material VJV e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) _N,JJ d. Casing Diameter �� � f. Calculated Well Vol.
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (1/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
ft bm
VolWL
Evac. I
ow
Ilmin
T° ©
H
bpec. onTurbidity
mS/cm
NTUs
DO
ORP
Odor/Color
Other
+�
I-rb
,o o
L1i.5
C"Co
�N8
LID
�e (t
G .�
r
o -7
C1C>c.
033
I
"„H©
�,''�
3: 1
(0,.-2)
3
o,Cyc�
�t
a. Acceptance criteria pass/fail
Yes No
13 Ely�'
NIA/
Has required volume been removed
Dissolved CO2 = MA
Has required turbidity been reached
❑
❑ Sulfide =NA
Have parameters stabilized
NJ ❑
❑ Fe+a= .0
Has Low flow been maintained at >0.1ft/min
❑
❑ NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample
Container Type
No. of Containers
Preservation
Analysis
Time
125 MI Plastic
1
none
Nitrate
1 L
125 ml plastic
1
H2SO4
Ammonia
Commons;
IDW: Placo In drum or note other method of handling _
Signature —,+I- �1Date 0--l
Dunthteo Dunnanl, P.C.
Eno(lonaiaalaI CMU118111s
$11 Katslar or, aufle 102 Phan 010.888.0808
Cary, Noah Cmollna 27818 Fax: 010.868.D80D

DZJNCKL,EE e iezo
`�
82 DXTNMA lN4 iSample ID
Ground Water Sample Collection Record
Client: SS -Statesville Date: 1`i
Project No: 50200 Time: Startamlpm
Site Location: Statesville, NC Finish am/pm
WeatherConds: C1Eitr — �-)C"'I Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer ED
a. Total Well Depth (ft bmp) )a i c. Casing Material PVC e. Length of Water Col. (a -lb)
b. Water Table Depth (ft bmp) 13, d. Casing Diameter<i I' f. Calculated Well Vol.
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used:
Make Model
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
��tivC�ci N' I.�' Jet
Serial Number
e. Acceptance criteria pass/fail
Yes No
N/
Has required volume been removed
❑ ❑
Dissolved CO2 = MA
Has required turbidity been reached
�j ❑
❑
Sulfide =NA
Have parameters stabilized
C3- ❑
❑
Fe+2= u '"
Has Low flow been maintained at >0.1ft/min
❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
Ut16 U;q L�
125 MI Plastic
1
none
Nitrate
011 S
125 ml plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in drum or note other method of handling
;1
Signature '%i(/� tr Date �[ J
t
Duncklee Dunham, P.C.
Environmental Consultants
511 Kessler Dr, Suite 102 Phone 919,858.9898
Cary, North Carolina 27518 Fax: 910,858,0899

Project No:
Site Location:
Weather Conds:
IDUT-4CItLEE a lezo :
8.r— DUN1-4AM Sample ID
Ground Water Sample Collection Record
SS -Statesville
50200
Statesville, NC
Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing)
a. Total Well Depth (ft bmp) 1 e c. Casing Material
b. Water Table Depth (ft bmp) I I d. Casing Diameter
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model
Date:
Time: Start am/pm
Finish am/pm
Well KI Piezometer
e. Length of Water Col. (a-b)
f. Calculated Well Vol.
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
v
Serial Number
e. Acceptance criteria pass/fail
Yes No
N/ l
Has required volume been removed
❑ ❑
Has required turbidity been reached
LI /El
Have parameters stabilized
❑
❑
Has Low flow been maintained at >0.1ft1min
`p/
LY ❑
❑
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate!
Dissolved CO2 = MA
Sulfide =NA
Fe+2= r, . r
NO3C NA
Sample ID
Container Typo
No. of Containers
Preservation
Analysis
Time
125 MI Plastic
1
none
Nitrate
.Y
125 ml plastic
1
H2804
Ammonia
comments:
IDW: Place in drum or noto other method of handling
signature w. �Ac Dnto
J r---F-ff
Duneklae Duanam, P.C.
DnVllunluutllal �`bu1MI101119
sit Ke6der Dr. guile 102 Phone ®18.858,9888
Cary, NonN Carolina Vgili Fax: M.858.0849

act No:
Location:
ther Cords:
D-LJN CK L.EE e lezo
�Fi Ct;
84 DUNI-IAM Isarnpie ID °t
Ground Water Sample Collection Record
SS -Statesville
50200
Statesville. NC
/' `p p f n. �Z O F- Collectors) WMF
Date:_
Time: Startamlpm
Finish am/pm
WATER LEVEL DATA: (measured from MP at Top of Casing) Well EZ] i Piezometer El
a. Total Well Depth (ft bmp) SO t c. Casing Material a V( e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) `Kj ,j8-1 d. Casing Diameter � 1 f. Calculated Well Vol.
2"=617ml/ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and
b. Acceptance Criteria defined (from workplan)
Purge Volume (® well volumes) or rate (Ilmin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters e/
c. Field Testing Equipment Used: Make Model
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Serial Number
Time
ft bmp
VolWL
Evac. I)
ow
(Ilmin
T° ©
pH(MS/CM)
Spec.Cond
I urbiclity
NTUs)
DO
ORP
Odor/Color
Other
515,18
SqY '
, V--�
16,5
2,c-,C!
30 I;,
i 5i 3 S
13 5
0, a 7
S7,,
yL>
-5 •:
IS.y9
5-," :?
0, 0--T
L4 3cI
,-it 6
335
.r }?.LSD
e. Acceptance criteria pass/fail
Yes
No
N
Has required volume been removed
El.
❑
Qlyi
Dissolved CO2 = MA
Has required turbidity been reached
❑
❑
Sulfide NA
Have parameters stabilized
[�j
❑
❑
Fe*2= 0, 0
Has Low flow been maintained at >0.1ftlmin
❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sample ID
ContainerType
No, of Containers
Preservation
Analysis
Time
GM
125 MI Plastic
1
none
Nitrate
Cob
125 ml plastic
1
H2SO4
Ammonia
Comments:
IDW: Place in drum or note other method of handling
Signature !/� * n —' Date
I;
J
Duncklee Dunham, P.C.
Environmental Consultants
511 Keisler or, Suite 102 Phone 919.M.9898
Cary, North Carolina 27518 Fax: [phone]

DLJNCKLEE I
a 18Z0 S L;S (c 1.>
4& ISample ID 4/1
Ground Water Sample Collection Record
Client: SS -Statesville Date: J l I- i i
Project No: 50200 Time: Start am/pm
Site Location: Statesville NC Finish am/pm
Weather Conds: Collector(s) WMF
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer
a. Total Well Depth (ft bmp) i c. Casing Material qV e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) d. Casing Diameter 7" f. Calculated Well Vol.
2"=617m1/ft and 4"=2470mUft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (Umin)
_ Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model
d_ Field Testino Eauipment Calibration Documentation Found in Field Notebook # Page #
Serial Number
e. Acceptance criteria pass/fail
Yes No
NIA/
Has required volume been removed
❑ ❑
Q
Dissolved CO2 = MA
Has required turbidity been reached
L/ ❑
❑
Sulfide =NA
Have parameters stabilized
p/ ❑
❑
Fe+2= UT
Has Low flow been maintained at >0.1ft/min
❑ ❑
❑
NO3 = NA
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Sample ID
Container Type
No, of Containers
Preservation
Analysis
Time
Jl �, 1,L1 ZGl
125 MI Plastic
1
none
Nitrate
125 ml plastic
1
H2SO4
Ammonia
Comments:
or note other method of
,f 11)
Signature
Date 11- 1— 11
Duncklee Dunham. P.C.
Environmental Consultants
511 Keisler Dr, Suite 102 Phone [phone]
Cary, North Carolina 27518 Fax: [phone]

aceAnalytical
mvwpace/abs.com
November 11, 2011
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on April 22, 2011. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Report re -issued on 11 /11 /11 to report only Nitrate result, per client's initial request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
li,pl v . 4'0u Get_
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 20
`9eORA���

ce Analytical Servies, Inc.
205 aEast Meadow Road c Suite A Pace Analytical
2225 Riverside Dr.
aceAnalytical
wmpawabs.00m Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
CERTIFICATIONS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
South Carolina Certification #: 99030001
Florida/NELAP Certification #: E87648
Virginia Certification #: 00072
Massachusetts Certification #: M-NC030
West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712
Virgina/VELAP Certification #: 460147
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 20

aceMalXical
www.paceiabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Lab ID
Sample ID
9292601001
K65W7D
9292601002
K65W7H
9292601003
K65W7F
9292601004
K65W7C
9292601005
K65W6M
9292601006
K65W6B
9292601007
K65W6N
9292601008
K65W7K
9292601009
K65W7L
9292601010
K65W7J
9292601011
K65W6A
9292601012
K65W6E
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2,
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Analysts Reported Laboratory
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
DMN
1
PASI-A
LEP
1
PASI-A
JDA
1
PASI-A
LEP
1
PASI-A
JDA
1
PASI-A
Page 3 of 20

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.corn
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Sample: K65W71)
Lab ID: 9292601001 Collected: 04/21/11 08:25
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
04/27/11 18:33 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
ND mg/L 0.20 1
04/22/11 22:11
as
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 4 of 20
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®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www..pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersviile, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
Sample: K65W7H
Lab ID: 9292601002 Collected: 04/21/11 09:25
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
04/27/11 18:34 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.40 mg/L 0.20 1
04/22/11 22:15
ace
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 5 of 20
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Pace
aceAnalytical
® 205 East Meadow Road l- Suite ces, Inc. Pace Analytical
Riverside Dr. Pace9800 KintceylInc.Ave.
A e. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Sample: K65W7F Lab ID: 9292601003 Collected: 04/21/11 10:15 Received: 04/22/11 10:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/02/11 16:56 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 6.7 mg/L 0.20 1 04/22/11 22:17
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 6 of 20
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without the written consent of Pace Analytical Services, Inc..

7
®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pecelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
Sample: K65W7C
Lab ID: 9292601004 Collected: 04/21/11 11:10
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
05/02/11 16:58 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
9.4 mg/L 0.20 1
04/22/11 22:18
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 7 of 20
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without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical
Services, Inc.
Pace Analytical Services, Inc.
acema11/ is 1
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
mm..pacce"i' a`bs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
Sample: K65W6M
Lab ID: 9292601005 Collected: 04/21/11 13:15
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua[
360.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
05/02/11 17:00 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
ND mg/L 0.20 1
04/22/11 22:22
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 8 of 20
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aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Sample: K65W6B Lab ID: 9292601006 Collected: 04/21/11 14:00 Received: 04/22/11 10:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.61 mg/L
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 26.9 mg/L
0.10 1 05/02/1117:02 7664-41-7
2.0 10 04/22/11 22:31
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 9 of 20
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lac,
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
malytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
mvw.pawabs.com
Eden, NC 27288
Asheville, NC 28804.
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
Sample: K65W6N
Lab ID: 9292601007 Collected: 04/21/11 14:58
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.3 mg/L 0.10 1
05/02/11 17:05 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
61.4 mg/L 0.20 1
04/22/11 22:25
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 10 of 20
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without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyfical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K Lab ID: 9292601008 Collected: 04/21/11 16:00 Received: 04/22/11 10:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.8 mg/L 0.10 1 05/02/11 17:07 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 92.3 mg/L 5.0 25 04/22/11 22:33
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 11 of 20
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without the written consent of Pace Analytical Services, Inc..

PaceAnalytical Services, Pace Analytical
Services,
PaceAnalytical Services, Inc.
aeAalyical�
c
25East Meadow Rod- Suite A
225 Riverside Dr.
9800 KieyAve. Suite 100
mvw.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
Sample: K65W7L
Lab ID: 9292601009 Collected: 04/21/11 17:05
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
7.0 mg/L 0.10 1
05/02/11 17:07 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
96.4 mg/L 0.20 1
04/22/11 22:27
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 12 of 20
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without the written consent of Pace Analytical Services, Inc..

m
Pace Analytical Services, Inc. Pace Analytical
Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www..pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Sample: K65W7J
Lab ID: 9292601010 Collected: 04/21/11 17:50
Received: 04/22/11 10:40
Matrix: Water
- Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua[
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
3.3 mg/L 0.10 1
05/02/11 17:09 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
162 mg/L 0.20 1
04/22/11 22:28
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 13 of 20
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without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical
Services, Inc.
Pace Analytical Services, Inc.
act. Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
w .pacefabacom
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Sample: K65W6A
Lab ID: 9292601011 Collected: 04/22/11 08:15
Received: 04/22/11 10:40
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
0.30 mg/L 0.10 1
05/02/11 17:09 7664-41-7
363.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
118 mg/L 5.0 25
04/23/11 14:40 M6
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 14 of 20
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without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalyfical 205 East Meadow Road - Suite 2225 Riverside Dr.
www.pecalabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab ID: 9292601012 Collected: 04/22/11 09:15 Received: 04/22/11 10:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.6 mg/L 0.10 1 05/02/11 17:11 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 311 mg/L 10.0 50 04/23/11 15:06
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 15 of 20
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without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�aciemalXicalv 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
w ,w.pacelabs.cam Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
QC Batch: WETA/9575
Analysis Method:
EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description:
350.1 Ammonia
Associated Lab Samples: 9292601001, 9292601002
METHOD BLANK: 596360
Matrix: Water
Associated Lab Samples: 9292601001, 9292601002
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND
0.10 04/28/11 15:12
LABORATORY CONTROL SAMPLE:
596361
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 5.1
101
90-110
MATRIX SPIKE SAMPLE:
596362
9292267001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5 6.3
124
90-110 M1
MATRIX SPIKE SAMPLE:
596366
9292267003 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
12.2
5 18.6
128
90-110 M1
SAMPLE DUPLICATE: 596367
9292268001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
SAMPLE DUPLICATE: 596368
9292269001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 16 of 20
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without the written consent of Pace Analytical Services, Inc..

© Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceMaOca! 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/9619 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 9292601003, 9292601004, 9292601005, 9292601006, 9292601007, 9292601008, 9292601.009, 9292601010,
9292601011,9292601012
METHOD BLANK: 599602
Matrix: Water
Associated Lab Samples:
9292601003, 9292601004; 9292601005, 9292601006, 9292601007, 9292601008, 9292601009, 9292601010,
9292601011,9292601012
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10
05/02/11 16:55
LABORATORY CONTROL SAMPLE: 599603
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5. 4.9
99 90-110
MATRIX SPIKE SAMPLE:
599604
9292601003 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5
5.1 101 90-110
MATRIX SPIKE SAMPLE:
Parameter
599608
Units
Nitrogen, Ammonia
mg/L
SAMPLE DUPLICATE: 599609
Parameter
Units
Nitrogen, Ammonia
mg/L
SAMPLE DUPLICATE: 599610
Parameter Units
Nitrogen, Ammonia mg/L
9292601004 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 5 5.4 109 90-110
9292601006 Dup
Result Result RPD Qualifiers
ND ND
9292601006 Dup
Result Result
0.61 0.63
RPD Qualifiers
2
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 17 of 20
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without the written consent of Pace Analytical Services, Inc..

aceArral.Ximl e
www.pac6labs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/9554 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9292601001, 9292601002, 9292601003, 9292601004, 9292601005, 9292601006, 9292601007, 9292601008,
9292601009,9292601010
METHOD BLANK: 595647 Matrix: Water
Associated Lab Samples: 9292601001, 9292601002, 9292601003, 9292601004, 9292601005, 9292601006, 9292601007, 9292601008,
9292601009,9292601010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.20 04/22/11 22:07
LABORATORY CONTROL SAMPLE: 595648
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.1 102 90-110
MATRIX SPIKE SAMPLE:
Parameter
595649
Units
9292601001
Result
Spike MS MS % Rec
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND
5 5.1 99 90-110
SAMPLE DUPLICATE: 595650
9292601001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS. Page 18 of 20
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,��aaeAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www..pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 9292601
QC Batch: WETA/9565 Analysis Method: EPA 353.2
QC Batch Method: ` EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9292601011, 9292601012
METHOD BLANK: 595798 Matrix: Water
Associated Lab Samples: 9292601011, 9292601012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.20 04/23/11 14:31
LABORATORY CONTROL SAMPLE:
595799
Parameter
Units
Nitrogen, Nitrate
mg/L
MATRIX SPIKE SAMPLE:
595800
Parameter
Units
Nitrogen, Nitrate
mg/L
SAMPLE DUPLICATE: 595801
Parameter
Units
Nitrogen, Nitrate
mg/L
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
5 5.0 101 90-110
9292601011 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
118 5 125 157 90-110 M6
9292601012 Dup
Result Result RPD Qualifiers
311 312 0
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 19 of 20
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without the written consent of Pace Analytical Services, Inc..

®
Paceces, Inc.
1-
Pace Analytical
Pace9800
aceAnalytical
205 East Meadow Road Suite A
Riverside Dr.
K nceylInc.Ave.
A e. Suite 100
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALIFIERS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 9292601
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date: 11/11/2011 10:56 AM REPORT OF LABORATORY ANALYSIS Page 20 of 20
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CHAIN -OF -CUSTODY 1 Analytical Request Document
ace/`Vlalyiical ® The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
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RELI(�l3UISNE�IBY/1FFt�V1tQNa
' tp#
TIME
I
gCC�EFi1
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D/1TE
1iME
SAMP E CONDITIONS
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ORIGINAL
PRINT Name of SAMPLER: 1 ` p(InChikWa
>
H
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E
SIGNATURE of SAMPLER:Of
DATE Signed
( MM/DD vP�
ro
'Important Note: By signing this form you are accepting Paces NET 30 day payment terms and agreeing to late charges of 1.5 % per monthA Ay invoices not pale Uiln 30 days. F-ALL-Q-020rev.07, 15-May-2007

aceAnalytical
wvnvpacelabs.com
November 11, 2011
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
RE: Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 01, 2011.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report. .
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Report re -issued on 11/11/11 to report only Nitrate result, per client's initial request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 10

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceMalXiical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.c»m Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
CERTIFICATIONS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia Certification #: 00072
West Virginia Certification #: 356
Virgina/VELAP Certification #: 460147
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 10

acmnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Lab ID Sample ID
92105535001
K65W7D
92105535002
K65W7H
92106535003
K65W7M
92105535004
K65W6B
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analyses
Analysts Reported Laboratory
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
Page 3 of 10

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aaeMalXical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
WW..paWabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Sample: K65W7D Lab ID: 92105535001 Collected: 11/01/11 10:15 Received: 11/01/11 16:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.18 mg/L 0.10 1 11/09/11 12:54 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate ND mg/L 0.20 1 11/02/11 18:55
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 4 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Sample: K65W7H Lab ID: 92105535002 Collected: 11/01/11 11:55 Received: 11/01/11 16:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/09/11 12:54 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.36 mg/L 0.20 1 11/02/11 19:09
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 5 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalXica!
www.pacetabs.cwn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical. Services, Inc.
9800 Kincey Ave: Suite 100
Huntersville, NC 28078
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Sample: K65W7M Lab ID: 92105535003 Collected: 11/01/11 14:10 Received: 11/01/11 16:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/09/11 12:56 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.37 mg/L 0.20 1 11/02/11 19:11
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 6 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnal tical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
Sample: K65W6B Lab ID: 92105535004 Collected: 11/01/11 14:50 Received: 11/01/11 16:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/09/11 12:56 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 38.4 mg/L 2.0 10 11/02/11 19:24
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 7 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace
Services, Pace Analytical Services,
Pace
Analytical
Inc.
,IYacieAnalyticalo 205East Meadow RoadSuite A 225 Riverside Dr. 9800 KiceyAvervSuite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
QC Batch: WETA/10928 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92105535001, 92105535002, 92105535003, 92105535004
METHOD BLANK: 684218 Matrix: Water
Associated Lab Samples: 92105535001, 92105535002, 92105535003, 92105535004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 11/09/11 12:42
LABORATORY CONTROL SAMPLE:
684219
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg/L
5
5.5
110
90-110
MATRIX SPIKE SAMPLE:
684221
92105192002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
17.8
5
23.2
108
90-110
MATRIX SPIKE SAMPLE:
684223
92105535004
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5
5.1
101
90-110
SAMPLE DUPLICATE: 684220
92105192002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
17.8
18.1
2
SAMPLE DUPLICATE: 684222
92105535004
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 8 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Eden; NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
QC Batch: WETA/10887
Analysis Method:
EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description:
353.2 Nitrate+ Nitrite, Unpres.
Associated Lab Samples: 92105535001, 92105535002, 92105535003, 92105535004
METHOD BLANK: 681847
Matrix: Water
Associated Lab Samples: 92105535001, 92105535002, 92105535003, 92105535004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.20 11/02/11 18:37
LABORATORY CONTROL SAMPLE: 681848
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
5 5.5
109 90-110
MATRIX SPIKE SAMPLE: 681849
92105507002 Spike
MS MS % Rec
Parameter Units
Result Conc.
Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
24.8 5
33.9 182 90-110 M1
MATRIX SPIKE SAMPLE:
681851
92105498002
Spike
MS
MS % Rec
Parameter
Units
Result
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
8.1
5
16.0
158 90-110 M1
SAMPLE DUPLICATE: 681850
92105607002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
24.8
24.8
0
SAMPLE DUPLICATE: 681852
92105498002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
8.1
8.1
0
Date: 11/11/2011 10:55AM REPORT OF LABORATORY ANALYSIS Page 9 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
CeAnalytica1 205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
wwwpacwabs.corn
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALIFIERS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105535
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Date: 11/11/2011 10:55 AM REPORT OF LABORATORY ANALYSIS Page 10 of 10
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

, aceAnalytical
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of --Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Page: of
Section A Section B Section C
Required Client Information: Required Project Information: Invoice Information:
Company: Report To: Attention:
A
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Address: Copy
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Reference:
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Important Note: By signing this forth you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per mont&aFy Invoices not pa in 30 days. F-ALL-Q-020rev.07, 15-May-2007

aceAnalytical
www.pacelabs.com
November 11, 2011
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 02, 2011.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Report re -issued on 11/11/11 to report only Nitrate result, per client's initial request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
-eBY _P C 41.�
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 13

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceMalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pawabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
i
CERTIFICATIONS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804 South Carolina Certification #: 99030001
Florida/NELAP Certification #: E87648 Virginia Certification #: 00072
Massachusetts Certification #: M-NC030 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 Virgina/VELAP Certification #: 460147
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 13

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Lab ID Sample ID
92105634001
K65W6N
92105634002
K65W7L
92105634003
K65W7K
92105634004
K65W7J
92105634005
K65W6A
92105634006
K65W6E
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Method
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
EPA 350.1
EPA 353.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Analysts Reported Laboratory
SDH
1
PASI-A
AES
1
PASI-A
SDH
1
PASI-A
AES
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
SDH
1
PASI-A
DMN
1
PASI-A
Page 3 of 13

acmnaljNcal
wwwpacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Sample: K65W6N Lab ID: 92106634001 Collected: 11/01/11 16:10 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.99 mg/L 0.10 1 11/09/11 13:23 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 50.2 mg/L 1.0 5 11/03/11 12:23
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 4 of 13
This report shall not be reproduced, except in full, .
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
accAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Sample: K65W7L Lab ID: 92105634002 Collected: 11/02/11 08:20 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 12.0 mg/L 0.50 5 11/09/11 14:41 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 116 mg/L 6.0 30 11/03/11 12:36
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 5 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pawabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Sample: K65W7K Lab ID: 92105634003 Collected: 11/02/11 09:10 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.7 mg/L 0.10 1 11/09/11 13:28 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 85.3 mg/L 5.0 25 11/03/11 17:59
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 6 of 13
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without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacetabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Sample: K65W7J Lab ID: 92105634004 Collected: 11/02/11 10:05 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.8 mg/L 0.10 1 11/09/11 13:28 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 184 mg/L 6.0 30 11/03/11 18:09
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 7 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

�ceAnal�tic�l
205 ace Analytical East Meadow Road Ices, Inc. - SuiteA Pace Analytical
2225 Rivices, Inc. erside Dr. Pace9800 KintceylServices, Inc.
Ave. Suite 100
"M..pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Sample: K65W6A Lab ID: 92105634005 Collected: 11/02/11 11:00 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.33 mg/L 0.10 1 11/09/11 13:30 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 120 mg/L 0.20 1 11/03/11 17:55
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 8 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab ID: 92105634006 Collected: 11/02/11 11:45 Received: 11/02/11 14:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.8 mg/L 0.10 1 11/09/11 13:30 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 278 mg/L 7.0 35 11/03/11 18:12
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 9 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnaIXical
mnvpacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
QC Batch: WETA/10929 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92105634001, 92105634002, 92105634003, 92105634004, 92105634005, 92105634006
METHOD BLANK: 684226 Matrix: Water
Associated Lab Samples: 92105634001, 92105634002, 92105634003, 92105634004, 92105634005, 92105634006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 11/09/11 13:09
LABORATORY CONTROL SAMPLE:
684227
Parameter
Units
Nitrogen, Ammonia
mg/L
MATRIX SPIKE SAMPLE:
684229
Parameter
Units
Nitrogen, Ammonia
mg/L
Spike LCS
Conc. Result
5 5.4
92105312003 Spike
Result Conc.
1.5 5
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LCS % Rec
% Rec Limits Qualifiers
108 90-110
MS MS % Rec
Result % Rec Limits Qualifiers
6.6 102 90-110
MATRIX SPIKE SAMPLE:
Parameter
684231
Units
92105634002
Result
Spike MS MS % Rec
Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
12.0
5 16.5 91 90-110
SAMPLE DUPLICATE: 684228
92105312003
Dup
Parameter
Units
Result
Result RPD Qualifiers
Nitrogen, Ammonia
mg/L
1.5
1.5 1
SAMPLE DUPLICATE: 684230
92105634002 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Ammonia mg/L 12.0 12.3 2
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 10 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,��acmnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.p8ce/abs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
QC Batch: WETA/10890 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92105634001, 92105634002
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 681973
Matrix: Water
Associated Lab Samples:
92105634001, 92105634002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.20
11/03/11 11:07
LABORATORY CONTROL SAMPLE: 681974
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
5 4.9
99 90-110
MATRIX SPIKE SAMPLE: 681975
92105678001 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 9.4 5 19.2 197 90-110 M1
MATRIX SPIKE SAMPLE:
681978
92105681002
Spike
MS
MS % Rec
Parameter
Units
Result
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.21
5
5.5
106 90-110
SAMPLE DUPLICATE: 681976
92105443006
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
SAMPLE DUPLICATE: 681977
92105681001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
0.44
0.48
7
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 11 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�aceMalXical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pawabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
QC Batch: WETA/10894 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92105634003, 92105634004, 92105634005, 92105634006
METHOD BLANK: 682347 Matrix: Water
Associated Lab Samples: 92105634003, 92105634004, 92105634005, 92105634006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.20 11/03/11 17:36
LABORATORY CONTROL SAMPLE: 682348
Parameter Units
Nitrogen, Nitrate mg/L
MATRIX SPIKE SAMPLE: 682349
Parameter Units
Nitrogen, Nitrate mg/L
SAMPLE DUPLICATE: 682350
Parameter
Nitrogen, Nitrate
Spike LCS LCS
Conc. Result % Rec
5 4.9 98
92105634003 Spike MS
Result Conc. Result
85.3 5 91.2
92105634003 Dup
Units Result Result
mg/L 85.3 85.7
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
% Rec
Limits Qualifiers
90-110
MS % Rec
% Rec Limits Qualifiers
118 90-110 M6
RPD Qualifiers
0
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 12 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
acmnalXical 205
East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelab&com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
I
[phone]
[phone]
[phone]
QUALIFIERS
Project: SS-STATESVILLE 50200
Pace Project No.: 92105634
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date: 11/11/2011 10:52 AM REPORT OF LABORATORY ANALYSIS Page 13 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ace?" ical
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
^- r ...
Page: \ of
Section A Section B Section C
A I
9 4 11
Required Client Information: Required Project Information: Invoice Information:
Company: Report To: Attention:
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REG�tiAjORYEIGf�(�dY s., ¢.r
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Preservatives
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'Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per month for a�yrnvolces not paid wminrodays. F-ALL-Q-020rev.07, 15-May-2007

K65W6 A (Saprolite)
400
tNitrate Results
350
—�—Ammonia Results
—Nitrate 2L Standard
300
a
e
250
0
200
0
U
d 150
z
100
50
0
O N r- o0 Oi O
T pi C� C� C� Q\ U C� Q\ C� O❑❑ O❑❑ O O O O O O O OCC -❑❑-� CC
Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
8/2/95
11/8/95
Nitrate (n.A)
370
252
360
360
311
30"
210
340
330
250
260
250
180
Ammonia (mgA)
No Data
Date
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
Nitrate (mg/1)
240
260
210
106
243
121
199
236
240
220
200
190
190
Ammonia (mg/l) 11
No Data
Date
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
10/15/07
4/25,108
Nitrate (�ng/I)
235
170
140
84
200
150
170
190
160
150
140
30.9
92.8
Ammonia (mg/l)
No Data
77
0.24
NS
NS
NS
0.23
NS
0.14
0.13
0.25
0.36
Date
4/9/09
10/30/09
4/6/10
10/21/10
4/22/2011
11/2/11
Nitrate (m
152
186
135
122
118
120
Ammonia (m 1)
NS
0.10
0.16
0.19
0.30
0.33

K65W6 B (Saprolite)
160
--*—Nitrate Results
140
­k—Ammonia Results
®Nitrate 2L Standard
120
Caen
100
E
a
c
80
L
60
a
0
U
+�
�a
40
z
20
0
d�AT�
O
p�
N M V N
Q� O� O� QC� 01 Q�
n 00 0i CD
O� O� OCR OC O Op OC
00
OC OC I?OC CD
cad cad cCO cd c0 C
«f cd cd cd
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Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
3/30/99
11/3/99
Nitrate m 1)
22
22
15
26
16
7.6
6.8
28
29
19
18
89.4
140
Ammonia (m 1)
No Data
Date
10/24/01
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
4/9/09
Nitrate m 1
78
92
40
41
44
33
35
28
23
31
31
32
40
Ammonia (m 1)
No Data
<0.1
<0.1
<0. I
NS
NS
0.12
<0.1
<0.1
<0.1
NS
<0.1
<0.I
Date
10/29/09
4/6/10
10/22/10
4/21/11
11/1/11
Nitrate (m l)
55.9
34.5
30.2
26.9
38.4
Ammonia m 1)
<0.1
<0.10
1.4
0.61
<0.10

K65W6 D (Saprolite)
2
+Nitrate Results
1.5
E
e
�o
0
L
C
Cad
A
U
L
z 0.s
0
o N N M
T C� C
O\ 0
w w w
Date
Date
8/1/90
1/22/92
2/10/93
4/8/93 to 11/2/I 1
Nitrate (m 1)
0.63
0.17
0.25
Dry
Ammonia m I
No Data
Dry

K65W6 E (Bedrock)
350
4 Nitrate Results
300
—1—Ammonia Results
—Nitrate 2L Standard
250
aa
e�
E
c
200
C
O
a+
L
150
C
O
U
100
50
ors-,--
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O •-• N Cl 00 01 N M h 00 01 O
91 Qi 91 C� O O O O O O O O
79 7 E 7 7 7 F3 �J ;9 7 7 :9 7 7 7 7
Date
Date
8/1/90
1/22/92
2/10/93
8/2/95
11/8/95
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
Nitrate m 1)
7.3
37
27
4.4
5
56
7.9
8.5
11.7
24.1
30.9
49.9
50.4
Ammonia m 1)
No Data
Date
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
Nitrate (m 1)
56
67
68
62
78
81
76
62
60
90
100
120
150
Ammonia (m
No Data
<0.10
<0.10
<0.10
NS
NS
<0.10
Date
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/6/10
10/22/10
1 4/22/11
11/2/11
Nitrate (m 1)
140
150
150
14.2
169
202
253
44.4
243
203
311
278
Ammonia (m l)
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
0.5
<0.10
1.7
0.62
1.6
1.8

K65W6 M (Saprolite)
1
—e Nitrate Results
0.9
Ammonia Results
0.8
0.7
e�
E
0.6
C
O
a.
0.5
u
C
U
0.4
z03
0.2
0.1
0
co
rn
CN 0
U
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/22/10
4/21/11
11/l/11
Nitrate (m 1)
0.44
<.10
0.15
0.16
0.28
0.14
0.37
Ammonia(mg/1)
<0.10
I <0.10
<0.10
<0.10
<0.10
<0.10
<0.10

K65W6 N (Saprolite)
100.0
tNitrate Results
90.0
—a—Ammonia Results
80.0
®Nitrate 21, Standard
70.0
a
e� 60.0
E
a
c 50.0
L
40.0
a
0
Ud,
30.0
L
z 20.0
10.0
a � �
0.0
co � o 0 0 0
0 0 0 0 0
CL
Q y GOQ ti � Q cn ca
Date
Date
12/19/08
4/9/09
10/29/09
4/7/10
10/22/10
4/21/11
11/1/11
Nitrate m 1
16.7
61.9
82.3
67.2
66.6
61.4
50.2
Ammonia m 1)
6.6
3.5
1.7
1.4
1.2
1.3
0.99

K65W7C (Saprolite)
140
+Nitrate Results
120
--*—Ammonia Results
—Nitrate 2L Standard
100
a
s
O
°0
80
L
A
u
0
60
U
i
z
40
20
0
s
O
01
C� O�
O1 O
Q� 91 Q� O� Q� O O O O
O O O O O C?
.O .D P .0 p D
N CJ N N N N
N N
w w
N N N
w w w
7J N N N N N N N N
w w w w w w w w w
N N
w w w w w w w w
Date
Date
2/13/90
1/22/92
2/10/93
10/17/03
7/18/05
10/28/05
4/25/08
12/19/2008 to 10/21/10
4/21/11
11/1/11
Nitrate (m I
93
130
13
82
33
53
<0.10
D
9.4
Dry
I
Ammonia m 1)
No Data
9
NS
2.3
29.4
Dry
<0.10
Dry

K65W7 D (Saprolite)
40
- o Nitrate Results
35
-6, Ammonia Results
-Nitrate 21, Standard
30
E
25
a
0
20
�
U
O
U
H
15
Cd
L
z
10
5
0
O N
C� C� p1
00 O1 O -+ N M It 00 O1 O
O O O O O O O O
7 7 7 7
7 7 7 a a '3 Ei 7 7 7 7
Date
Date
8/1/90
1/22/92
2/10/93
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
Nitrate m I
11
2
0.57
0.775
2
1
2
1.1
<0.10
1.1
2.4
1.4
0.05
Ammonia (m 1)
No Data
0.41
<0.10
Date
4/16/04
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
4/25/08
4/16/09
10/29/09
4/6/10
10/21/10
4/21/11
Nitrate m )
1.3
2.4
0.48
1 2
1.1
15
39
0.48
0.21
<0.10
0.22
<0.10
0.16
Ammonia m )
<0.10
NS
NS
1 0.12
<0.10
1.1
2.1
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
Date
11/2/11
Nitrate(m )
<0.20
Ammonia (m
0.18

K65W7 F (Saprolite)
200
0 Nitrate Results
180
*Ammonia Results
®Nitrate 21, Standard
160
140
E
G
a 120
0
C 100
d
u
C
O
U 80
z 60
40
20
0
O - N M 7 1 0 r-
p1 91 Q1 C1 91 91 91 O1 O O O O O O O O O O
Date
Date
8/1/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
2/8/96
5/9/96
Nitrate (m I)
99
100
109
79
79
110
100
100
96
1.6
94
150
6.1
Ammonia m I
No Data
Date
3/28/00
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
Nitrate (m
5.1
0.52
20
33
17
3
21
8.5
<0.1
20
31
31
15
Ammonia m 1)
No Data
<0.10
NS
<0.10
NS
NS
NS
0.12
I.1
Date
4/25/08
4/9/09
10/29/09
4/6/10
10/21/10
4/21/11
HAM
Nitrate (m l)
61.9
33.6
Dry
9.2
30.7
6.7
Dry
Ammonia m 1
<0.10
<0.10
Dry
<0.10
<0.10
<0.10
Dry

40
K65W7 G (Saprolite)
4 Nitrate Results
-—Ammonia Results
®Nitrate 2L Standard
N m V Vl �o lI_ 00 O, O (V m R
p� p� 91 Oi C� T 91 91 O O O O O O O O O O
7 7 a 7 : 7 Ei 7 7 :5 S 5 S 7 7 S
Date
Date
8/l/90
1/22/92
2/10/93
2/8/96
11/3/99
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
10/28/04
7/18/05
Nitrate (m 1)
1.7
1.9
2.6
3.5
2.9
3.6
2.8
31
32
1.3
0.4
4.4
1.7
Ammonia m 1
No Data
<0.10
<0.10
NS
NS
Date
4/25/06
10/23/06
5/1/07 to 4/6/10
10/21/10
11/1/11
Nitrate m l
16
29
D
3.3
4D*_
DAmmonia
(m 1)
<0.10
4
D
<0.10
D

K65W7 H (Bedrock)
1
+Nitrate Results
0.9
—Ammonia Results
0.8
0.7
8
c
c
0.6
w
6
0.5
C
O
d
0.4
Z
0.3
0.2
0.1
0
00
0
o rn
0 0
rn rn o 0 0 0
0 0
v) q
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/21/10
4/21/11
11/1/11
Nitrate (m 1)
0.30
0.26
0.36
0.47
0.36
0.40
0.36
Ammonia m 1)
<0.10
1 <0.10
<0.10
<0.10
<0.10
<0.10
<0.10

K65W7 J (Saprolite)
300
Nitrate Results
L Ammonia Results
250
Nitrate 2L Standard
a
200
c
0
ea
L
C 150
V
O
U
d
` 100
z
50
0 a —ems— 3��--�s�i �� —� .—_A
00 00 01 rn o 0
0 0 0 0 0 0 0 0 0 0 0
0 is o ;Z. a a a n c
O Q O Q O Q O Q O Q O Q O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/7110
10/22/10
Nitrate m 1)
100
140
74
150
180
140
14.4
178
204
191
199
157
172
Ammonia (m I)
NS
NS
<0.10
<0.10
<0.10
0.10
0.6
0.86
0.79
1.7
1.7
1.4
2.2
Date
4/21/11
11/2/11
Nitrate m I
162
184
Ammonia (m l)
3.3
2.8

K65W7 K (Bedrock)
200
—o Nitrate Results
180
Ammonia Results
®Nitrate 2L Standard
160
140
E
120
0
w
100
a
u
0 80
U
60
z
40
20
0
v n v c r r` o0 00 rn rn o o
0 0 0 0 0 0 0 0 0
O Q O d O O O d O d O d O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m 1)
81
89
190
100
120
89
25.9
99.5
1
108
95.4
99.4
77.4
84.6
Ammonia m 1
NS
NS
4.1
3.7
11
4.5
4.2
4.8
4.1
4.2
3.6
3.6
3.8
Date
4/21/11
11/2/11
Nitrate m I
92.3
85.3
Ammonia m 1
2.8
2.7

K65W7 L (Bedrock)
200
�—Nitrate Results
180
Ammonia Results
®Nitrate 2L Standard
160
a
140
en
E
120
C
O
w
100
C
u
C
U
u
80
m
z
60
40
20
0
d�-
v n n c 00 00
0 0 0 0 0 0 0 0 0
rn rn
0 0
o 0
a a a n
O Q O Q O Q O Q O
i
Q O
i a
Q O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/1/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
1 4/7/10
10/22/10
Nitrate m 1
22
98
110
130
120
99
1
30.5
104
103
93.8
103
85.7
95.2
Ammonia m 1)
NS
NS
7.7
7.4
11
11
12.9
12.4
10.4
10.1
9.4
9.0
12.8
Date
4/21/11
11/2/11
Nitrate (m 1)
96.4
116
Ammonia m )
7
12

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11
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®
Bedrock Monitoring Well
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Recovery Well
Property Line
Railroad Tracks
Locations
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and based on CAP data (1994 Canonie)
Purina Feed Mill Property
(203)��'\
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Purina Feed Mill Property
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Purina Feed Mill Property
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Note: Type III Wells Were Not Used
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Locations of Ponds A and B are approximate
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Purina Feed Mill Property
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6

2010 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
`^ Statesville Fertilizer Plant
Statesville, North Carolina
Prepared for
Mr. Vance Dann
Southern States Cooperative, Inc.
Post Office Box 26234
Richmond, Virginia 23260
[phone]
Submitted to
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Branch
Mooresville Regional Office
610 East Center Avenue
Suite 301
Mooresville, North Carolina 28115
Prepared by
Duncklee & Dunham, P.C.
511 Keisler Drive, Suite 102
Cary, North Carolina 27518
January 31, 2011
- DUNCKLEE & DUNHAM, P.C.

DUNCKLEE
i
-- & DUNHAM
L4
l January 31, 2011
�i
ENVIRONMENTAL CONSULTING & ENGINEERING
511 KEISLER DRIVE — SUITE 102
CARY, NORTH CAROLINA 27518
OFFICE: [phone]
W W W.DUNCKLEEDUNHAM.COM
Mr. Andrew Pitner, P.G.
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Branch
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
w V E F�
P
FEB - 2 2011 1
E
Reference: 2010 Annual Groundwater Monitoring and Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant, Statesville, North Carolina
Groundwater Incident Number: 5038
Dear Mr. Pitner:
As requested by Southern States Cooperative, Inc. (Southern States), Duncklee & Dunham, P.C. is
pleased to submit this 2010 Annual Groundwater Monitoring and Treatment System Effectiveness Report
for the above referenced site. This report discusses the work performed and the conclusions derived from
sampling and monitoring performed during this period.
If you have any questions or require additional information, please do not hesitate to contact
Mr. Tom Dunham at [phone] ([e-mail]) or Mr. Vance Dann of
Southern States at [phone] ([e-mail]).
Sincerely,
Duncklee & Dunham, P.C.
Jayson A. Kilcoyne
Project Environmental Scientist H
Senior Peer Review:
Bryson D. Trexler, Jr., Ph.D., P.G.
Senior Hydrogeologist
cc: Mr. Vance Dann — Southern States Cooperative, Inc. (e-copy)
P:\Southem States\Statesville Fertilizer - 50200\Reports\2010 Annual Report\2010 Annual GW Monitoring Report - 11024.doc
MAILING ADDRESS — POST OFFICE BOX 33366 — RALEIGH, NORTH CAROLINA 27636
_ NORTH CAROLINA BOARD OF EXAMINERS FOR ENGINEERS AND SURVEYORS LICENSE C-3559
NORTH CAROLINA BOARD FOR LICENSING OF GEOLOGISTS LICENSE C-261
NC DENR REGISTERED ENVIRONMENTAL CONSULTANT NUMBER 00061
_J

2010 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
-, Southern States Cooperative, Inc.
Statesville Fertilizer Plant
- Statesville, North Carolina
Introduction
1.1 Site Location, Description and History
The Southern States Cooperative, Inc. (Southern States) fertilizer plant (the site) is located at
2582 Salisbury Highway (old US Highway 70) approximately six miles east of Statesville, North Carolina
(Figure 1). The site consists of several buildings including a fertilizer manufacturing building, an office
building, and several small support buildings (Figure 2). The site is utilized for the manufacturing,
storage, and distribution of fertilizer.
The site is bordered to the north by old US Highway 70, commercially developed parcels to the east,
residential properties to the south, and undeveloped land to the west. The US Highway 70 Bypass (70
Bypass) bisects east to west through the southern portion of the site and separates approximately 13 acres
from the main property (Figure 2).
Groundwater at the site has been impacted by a release of liquid ammonium nitrate from several former
surface water impoundments. Two impoundments (Former Pond. No. 1 and No. 2) were located
approximately 1,000-feet southwest of the main plant (Figure 2). Two additional surface water
impoundments (Former Ponds A and B, Figure 2) were located east and southeast of the main plant.
These impoundments are referenced in the Corrective Action Plan (CAP) dated January 28, 1994,
submitted by Canonie Environmental to the North Carolina Department of Environment and Natural
Resources (DENR), Division of Water Quality (DWQ), Aquifer Protection Section (APS). In 1994 :the
APS approved the CAP. Based on the CAP, the assessment and impact. of groundwater contamination
was defined with reasonable certainty.
The objectives of the CAP were to remediate groundwater and to prevent off -site migration of the
groundwater contamination plume. To monitor the effectiveness of the CAP, a groundwater, sampling
plan was developed that established semiannual (April and October) groundwater monitoring.
- 1.2 Summary of Remedial Actions
To reduce the levels of nitrate and ammonia in the groundwater, three recovery wells (RW-2, RW-5 and
RW-6) were installed as part of the CAP. However, RW-5 was taken out of service prior to 2005 due to
low or no groundwater recovery and replaced with RW-5r in September 2008. The recovery wells pump
groundwater into a treatment system where the pH is adjusted with a caustic solution prior to . being
discharged into Fourth Creek (Figure 3).
The groundwater treatment system is permitted under the National Pollution Discharge Elimination
System (NPDES) program. Under the program, bi-monthly site visits are conducted when the system is
operational to monitor the treatment system and be sure it is operating within the permitted discharge
- limits. Effluent water samples are collected bi-monthly and the data is reported to the DWQ on monthly
Discharge Monitoring Reports.
I`
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2010 Annual Groundwater Monitoring Report
January 31, 2011
Page 2 of 4
2 Groundwater Treatment System Modifications and Monitoring Activities
2.1 Groundwater Treatment System Upgrades and Recovery Well Repairs
The groundwater remediation system operated during this reporting period from October 31, 2009, to
March 31, 2010. During this period the electric submersible pump and motor in recovery well RW-2
were replaced. On March 31, 2010, the system was shut -down due to a low water table and for system
repairs and upgrades. The repairs and upgrades were performed to restore the system to . proper
operational status and as preventative maintenance measures to ensure future operation. The system did
not operate through the remainder of this annual monitoring period that ended on October 31, 2010.
Although outside this annual reporting period, the following information is being presented to document
the system repairs and upgrades have been completed and the system is operational. In November 2010
Duncklee & Dunham, P.C. (Duncklee & Dunham) personnel along with Air Drilling, Inc. (Air Drilling)
of Statesville, North Carolina inspected the . condition of each recovery well and the associated
submersible pumps. It was determined that all three pumps required replacement or repairs. Air Drilling
completed the necessary recovery pump repairs in November 2010. Details of the well repair activities
will be further discussed in the subsequent monitoring report.
2.2 Groundwater Treatment System Monitoring Activities
In accordance with the NPDES permit, effluent samples were collected bi-monthly between November
2009 through March 2010 for analysis of total suspended solids (TSS) according to Method 2540D and
ammonia nitrogen according to EPA Method 350.1. Monthly effluent samples were also collected and
analyzed for copper (EPA Method 200.7), chloride (Method SM 4500-C1-E), TSS, ammonia nitrogen,
total Kjeldahl nitrogen, nitrate nitrogen and phosphorus all by EPA Method 300 series. The samples were
submitted for laboratory analysis to Pace Analytical Services, Inc. (Pace), a North Carolina certified
analytical laboratory. During the 2010 compliance reporting period, discharge monitoring reports
(DMRs) were submitted monthly to DENR as required by the NPDES permit. Monthly DMRs were not
submitted between June to October 2010, while the system was not operational per approval by the
DENR-DWQ on May 24, 2010.
3 Groundwater Sampling Activities and Results
Semiannual groundwater monitoring activities were conducted on April 6 to 7, 2010, and October 21 to
22, 2010. Groundwater flow maps illustrating the shallow groundwater flow for the April and October
sampling events are shown on Figures 4 and 5, respectively. The groundwater flow direction during both
events was to the south-southwest. During the April 2010 monitoring event the average hydraulic
gradient in the northern portion of the aquifer, north of the 70 Bypass, was 0.022 feet per foot (ft/ft) and
0.016 ft/ft south of the 70 Bypass. The average hydraulic gradient was 0.023 ft/ft north of the 70 Bypass
- and 0.010 ft/ft south of the 70 Bypass during the October 2010 monitoring event.
3.1 Groundwater Sampling Methodology
Prior to well purging and sampling, water level measurements were collected using an electric water level
probe and recorded on field sampling data sheets (Appendix A). The groundwater level measurement
data is summarized on Table 1.
- DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2010 Annual Groundwater Monitoring Report
January 31, 2011
Page 3 of 4
Groundwater samples were collected from eleven (K65W6A, K65W613, K65W6E, K65W6M, K65W6N,
K65W7D, K65W7F, K65W7H, K65W7J, K65W7K and K65W7L) of the fourteen monitoring wells
during the April 2010 sampling event. The remaining monitoring wells, (K65W6D, K65W7C and
K65W7G) were dry during this event.
Groundwater samples were collected from twelve (K65W6A, K65W6B, K65W6E, K65W6M, K65W6N,
K65W7D, K65W7F, K65W7G, K65W7H, K65W7J, K65W7K, and K65W7L) of the fourteen monitoring
wells during the October 2010 sampling event. The remaining monitoring wells were dry.
The sampling process consisted of inserting a two-inch submersible electric PVC pump with new
disposable polyethylene tubing in each well to purge and withdraw the samples. The groundwater
samples were collected using low flow sampling techniques. During the sampling process, field
measurements were collected for dissolved oxygen (DO), oxidation reduction potential (ORP), pH,
temperature, turbidity, and electrical conductivity. The field measurement data collected during each
sampling event are summarized in Table 2 and the field data sampling forms are included in -Appendix A:
Groundwater samples were collected and placed directly in laboratory -provided containers, labeled,
recorded on a chain -of -custody form, and transported to the analytical laboratory in an insulated cooler
filled with ice. The samples were submitted to Pace and analyzed for nitrate according to EPA
Method 353.2 and ammonia nitrate according to EPA Method 350.1. The laboratory analytical reports
and chain of custody records for both sampling events are included in Appendix B.
3.2 Results from 2010 Sampling Events and Nitrate Trends
Groundwater plume maps illustrating nitrate concentrations in the shallow saprolite and deep bedrock
monitoring wells are presented on Figures 6 through 9. Graphs of the nitrate trends over time are
included in Appendix C.
The following observations have been made with respect to the nitrate plume for this groundwater
monitoring period.
• The two saprolite monitoring wells (K65W6A and K65W6B) located near the two former ponds
(Ponds A and B, Figures 6 and 8) showed a decreasing nitrate trend during the 2010 monitoring
period. However, both of these wells contain nitrate concentrations greater than the 2L standard.
• The saprolite well along the southeastern edge of the plume (K65W6M) does not contain nitrate
above the 2L standard.
• The saprolite well along the northwestern edge of the plume (K65W6N) contained nitrate above the
2L standard and showed an initial increasing nitrate trend immediately after the well was installed in
2008. The nitrate level has remained fairly constant in the well since 2009..
• The saprolite well K65W7J located in the core of the plume contains nitrate above the 2L standard.
The nitrate level in the saprolite well had been on an increasing trend since 2004 but has become
constant since April 2008.
• Of the two saprolite plume wells at the southern extent of the plume, K65W7G had been dry
from May 2007 to April 2010, but contained water in October 2010 and was sampled. The nitrate
concentration in K65W7G was below the 2L standard. The slightly deeper well (K65W7F),
contained nitrate at 9.2 mg/L in April 2010 and increased in October 2010 to 30.7 mg/L. The nitrate
concentration in this well has fluctuated above and below the 2L standard since March 1994.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc.-- Statesville Fertilizer Plant
2010 Annual Groundwater Monitoring Report
January 31, 2011
- Page 4 of 4
• The saprolite plume delineation well (K65W7D), - located in- the southwest portion of the site,
contained 0.22mg/L of nitrate in groundwater in April 2010 and less than 0.1 mg/L in October 2010.
• Saprolite monitoring well K65W7C was dry during both sampling events in 2010.
• Groundwater in the bedrock monitoring well K65W6E exhibited a increase in nitrate .in April 2010
though the nitrate level did decrease in October 2010. However, the nitrate level remains above the
2L standard and the overall nitrate concentration trend remains upward in this well.
• The two bedrock wells (K65W7K and K65W7L) located in the core. of the plume contain nitrate
above the 2L standard. The nitrate concentrations in the two wells remain constant.
• The bedrock delineation well (K65W7H) at the southern extent of the plume has not contained nitrate
above the 2L standard since it was installed in 2008.
4 Conclusions
Based on the results of the semiannual groundwater sampling events and treatment system activities for
the 2010 reporting period, the following conclusions can be made at this time.
• The nitrate trend in the saprolite wells (K65W6A and K65W6B) near former Ponds A and B show an
overall downward trend. The saprolite plume is defined to the southeast in the middle of the plume —
by .
I ! by K65W6M but not to northwest (K65W6N). The southern, downgradient extent of the plume is
defined by K65W7D to the west. The nitrate level in saprolite well K65W7F located at the
southernmost portion of the site fluctuated above and below the 2L standard during this reporting
period.
• The nitrate trend in groundwater in the bedrock well near former Pond B continues an increasing
trend while the nitrate concentrations in the two bedrock wells in the core of the plume (K65W7K and
K65W7L) remain fairly constant. Nitrate is below the 2L groundwater standard in the downgradient
bedrock well K65W7H.
5 Recommendations
Based on the information presented above, Duncklee & Dunham recommends the following.
• Continue to operate the groundwater treatment system in accordance with the NPDES permit during
the time period of November 1, 2010 and March 31, 2011, as agreed to by the APS. However, the
treatment system may be operated between April 1 and October 31 if aquifer conditions allow.
• Continue semiannual groundwater plume monitoring.
DUNCKLEE & DUNHAM, P.C.
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DUNCKLEE & DUNHAM, P.C. Approximate Scale: Title: I" = 2000' Site Location Topographic Map
ENVIRONMENTAL CONSULTANTS
511 KEISLER DRIVE - SUITE 102 Figure: Project: Southern States Cooperative, Inc.
CARY, NORTH CAROLINA 27511 1 Statesville Fertilizer Plant
Statesville, North Carolina

Inches
0 1 2
0 0.25 0.5
Miles
Somce of base map: Canonie Environmental Cometive Action Plan January 1994
DULVV
Drawing
Figure
50200-3
3
Scale
Date
1 "= 0.25 miles
January 27, 2010
Title
Treatment System Discharge Line Outfall Map
roject Southern States Fertilizer Plant
Statesville, North Carolina

Table 1. Summary of 2010 Well Water Level Gauging Data
Southern States, Statesville, North Carolina
Depth to
Water Table
Wells
Aquifer
Date
TOC
Total Well
Water Table
Elevation
Code
Elevation
Depth 00
ft bmtc
ft MSL
04/06/10
23.70
840.82
K65W6A
Sap
864.52
58
10/21/10
22.69
-841.83 .
04/06/10
20.80
850-75
K65W6B
Sap
871.55
30
10/21/10
21.21
850.34
04/06/10
DRY
DRY
K65W6D
Sap
846.37
38.
10/21/10
DRY
DRY
04/06/10
23.83
841.06
K65W6E
BR
864.89
133
10/21/10
23.05
841'.84.
04/06/10
37.36
800.48
K65W6M
Sap
837.84
50
10/21/10
35:52
802.32 .
04/07/10
8.70
836.60
K65W6N
Sap
g45.30
50
10/21/10
11.89
833.41
04/06/10
DRY
DRY
K65W7C
Sap
809.72
22
10/21/10
DRY
DRY
04/06/10
8.22
793:49
K65W7D
Sap
800.64
23
10/21/10
12.44
788.20
04/06/10
16.17
779.98
K65W7F
Sap
796.15
28
10/21/10
10.20
785.95
04/06/10
DRY
DRY
K65W7G
Sap
795.98
15
10/21/10
10.10
785.88
04/06/10
8.69
787.38
K65W7H
BR
796.07
112
10/21/10
5.85
790.22
04/07/10
41.50
809.75
K65W7J
Sap
851.25
60
10/21/10
40.05
811.20
04/07/10
41.52
810.78
K65W7K
BR
852.30
121
10/21/10
41.11
811.19
K65W7L
BR
04/07/10
848.14
200
40.52
807.62 .
10/21/10
40.08
808.06.
Notes:
TOC - top of casing
SL - mean sea level
RY - well was dry during this sampling event
t bmic -feet below marked top of casing
Aquifer Code - Represents aquifer being monitored at this well location (Sap.=Saprolite and BR=Bedrock)
11 measurements are iri feet
PASouthern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Table 2. Summary of 2010 Groundwater Analytical and Field Parameter Results
Southern States, Statesville, North Carolina
Labora -ry Data
Field Parameters
Ammonia
Nitrate
p13
Temp.
Conductivity
Turbidity
ORP
DO
Well #
Date
mg/L
mg/L
Standard
Units
Degrees
Celsius
mS/cm
NTUs
my
mg/L
2L Standard
1.5
10
04/06/10
0.16
135
NM
NM
NM
NM
NM
NM
K65W6A
10/22/10
0.19
122
NM
NM
NM
NM
NM
NM
04/06/10
<0.10
34.5
NM
NM
NM
NM
NM
NM .
K65W6B
10/22/10
1.4
30.2
3.9
12.83
1.0
74.7
421
8.9
04/06/10
NS
NS
NM
NM
NM
NM
NM
NM
K65W6D
10/22/10
NS
NS
NM
NM
NM
NM
NM
NM
04/06/10
1.7-
243
6.76
19.34
30.1
148
131
0.0
K65W6E
10/22/10
0.62
203
6.7
12.58
3.6
100
280
2.1
04/06/10
<0.10
0.16
5.06
18.98
0.368
273
323 -
1.74
K65W6M
10/22/10
<0.10
0.28
5.5
10.85
0.07
302
323
13.4
04/07/10
1.4
67.2
9.41
15.86
2.60
49.8
24
0.0
K65W6N
10/22/10
1.2
66.6_
6.9
11.09
1.8
277
271
2.1
04/06/10
NS
NS
NM
NM
NM
NM
NM
NM
K65W7C
10/22/10
NS
NS
NM
NM
NM
NM
NM
NM
04/06/10
<0.10
0.22
4.91
14.60
99.9
37.2
347
0.0
K65W7D
10/21/10
<0.10
<0.10
4.5
11.57
0.11
90.5
221
-2.0
04/06/10
<0.10
9.2
6.21
16.39
0.651
28.4
262
4.98
K65W7F
10/21/10
<0.10
30.7
6.0
11.68
0.69
64.3
289
2.8
04/06/10
NS
NS
NM
NM
NM
NM
NM
NM
K65W7G
10/21/10
1 <0.10
3.3
6.1
13.29
0.24
64.5
300
9.7
04/06/10
<0.10
0.47
6.18
18.00
0.273
27.7
248
2.05
K65W7H
10/21/10
<0.10
0.36
6.3
1 11.27
0.12
57.3
274
9.6
04/07/10
1.4
157
5.99
18.04
49.3
67.8
298
0.0
K65W7J
10/22/10
2.2 _
172
5.6
11.02
2.1
336
303
1.9
04/07/10
3.6
77.4
7.35
16.72
99.9
91.8
254
0.0
K65W7K
10/22/10
3.8
84.6
6.6
11.86
1.6
712
283
2.1
04/07/10
9.0
85.7
6.4
16.76
99.9
22.4
280
0.0
K65W7L
10/22/10
12.8
95.2
5.8
11.34
1.6
123
291
2.0
Notes:
Bold indicates above the laboratory method detection limit
Bold and shaded indicates a 2L Standard exceedence
S - not sampled - dry well
M- low flow parameters not measured
NTUs - nephelolometric turbidity units
mg/L - milligrams per liter
mS/cm - milli-Siemins per centimeter
my - milli -volts
R\Southern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

fit ---.gip D U.NCI�LEE e I iezo ID:
I'® �L DUNI IAM Sam le ID yj L
Ground Water Sample Collection Record
Client: SS -Statesville
Date: t
Project No: 50200
Time: Start_jC2J H am/pm
Site Location: Statesville, NC
Finish _ am/pm
Weather Conds: d h')n; i—r ram`
Collector(s)a�
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well � Plezometer E]
f r��
a. Total Well Depth (ft bmp) —�— c.
Casing Material(
e. Length of Water Col. (a-b)
b. Water Table Depth (it bmp) r t d.
Casing Diameter art
f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horlba ii�6�l,�1aA&T&jL- '1�
b. Acceptance Criteria defined (from workplan) �t J
Purge Volume (@ well volumes)
Maximum Allowable Turbidity NTUs
Stabilization of parameters
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
MIMOIIBK�,
MOM
r
e. Acceptance criteria pass/fall
Ye No
NIA
Has required volume been removed
❑
❑
Dissolved CO;
Has required turbidity been reached
E ❑
❑
Sulfide
Have parameters stabilized
Qr ❑
❑
Fe+2= •
Has Low flow been maintained at >0.1 h/min
Lf El
❑
NO3 = �
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method: �
M....
Sample ID
Container Type
No. of Containers
Preservation
Time
{
{{
/Amlysis
joLj
Gotriments :
IDW: Place In drgl or note other rtlt?ttldd dt handling
5rgnalute ���.s� date .
t)unckiap Btnunun, RcC
6nvnonm�nlal Gannunatna
511 Koblel 0%Smtc tn2 i?hatic 910.B58 ati'Jd
Cary. NutiN Carolina 27518 Fua. 9 t 9.BSB.9B99'

0go2
(A06
A
OR
Project No:
Site Location:
Weather Conds:
relPezoID:
I)UNCK.LUU m Ie1D
Ground: Water Sample Collection Record
SS -Statesville
50200
Statesville. NC
Collectors)
Date:
Time: Start ��� am/pm
Finish am/pm
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer
a. Total Well Depth (it bmp) la 1= c. Casing Material V e. ngt of Water Col. (a-b)
b. Water Table Depth (it bmp) 4J ri (1,_ d. Casing Diameter i.� (f f. Calculated Well Vol.
2"=617ml/ft and 4"=2470m1/ft
DELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horibalA((Z_ �Cfjtli.
b. Acceptance Criteria defined (from workplan) / 1
Purge Volume (@ well volumes) or rate (Ilmin) , J q� ��5 iriC4 �}(
Maximum Allowable Turbidity NTUs J . `
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook k Page N
®a
e. Acceptance criteria pass/fail
Ye No
NIA
Has required volume been removed
91 ❑
❑
Dissolved CO2 =
Has required turbidity been reached
❑❑
❑❑
Sulfide =
Have et paramers stabilized
Fe+2= j!
Has Low flow been maintained at >0.1 ft/min
❑� ❑
❑
NO3 =
I1 no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Sam le ID
Container Type
. No. of Containers
Preservation
Analysis
Time
W
ti
�.�06
-
a(
�o r
comments,
IDW: Place in dru .or note other method'of handling
Signature Date
_ - - DunGklee Dunaam, P.C.
_ Environmon@d Consullanls
811 Keisler Dr, Suite 102 Plrano 919,858.9898
- - Cary. North Carolina 27518 Pox: 919.858.9899

DUNCKLEE
�'t .)DUNHAM
Ground' Water Sample Collection Record .
Client: SS -Statesville Date: i 7�
Project No: 50200 Time: Startham/pm
Site Location: Statesville, NC _ Finish am/pm'
Weather Conds: i uC'2 Collector(s) I/!J�'
WATER LEVEL DATA: (measured from MP at Tap of Casiq) Well Piezometer .
a. Total Well Depth (ft bmp) G'0 C. Casing Material/ e. Lengt of Water Col. (a-b)
b. Water Table Depth (it bmp) d. Casing Diameter u t`-_ f. Calculated Well Vol.
L 2"=617m11ft and 4"=2470m1/tt
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba n
b, Acceptance Criteria defined (from workplan)
Purge Volume ( t� well volumes) or rate (1/min)
Maximum Allowable Turbidity NTUs -
Stabilization of parameters
c. Field Testing Equipment Used: Make . Model
Cold
` -Ai 21 `7 �ci ((61,49
Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook it Page H
•_���®�=�®
•t^Jm7
•
t�I_LLit�J
i
_--.�M
A��
e. Acceptance criteria pass/fail
Y,^
No
N/A
Has required volume been removed
L I
❑
❑
Dissolved CO2 = ^—
Has required turbidity been reached
C
❑
❑
Sulfide =
Have parameters stabilized
[1]/'
❑
❑
Fe+2= _
Has Low flow been maintained at >0.1 ft/min
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION;
Method:
owe
COO
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
t
S t,t art
w
0 o 0
cornments :
IDW: Place in dr 1 or noto other lndthe
Signature
Date
Dunakle Dunham, P.C. -
Grnnmmumt.-A Cansuttanls
811 K'Di510T DT. Sui10 1Q _ f'hon0 U19.858:JYTJ9
Cary, Nonni Cataunn 27518 Fah: 919.8.58,9969

DUN4CX-ILU)C Well/Piezo ID:KLL��
,
]DUT141-1-I'l-M Sam le ID .a✓ !A/ -- (1 file,
Ground Water Sample Collection Record
Client: SS -Statesville Date: "L
Project No: 50200 Time: Start am/pm
Site Location: Statesville, NC Finish am/pm
Weather Conds: V-44-M Colleclor(s) '" L_m F
WATER LEVEL DATA: (measured from MP at Top of Casing) WelNo
Piezometer (�
a. Total Well Depth (ft bmp) _ c. Casing Material L e. L. of Water Col. (a-b)
b. Water Table Depth (ft bmp)t; d. Casing Diameter f. Calculated Well Vol.
2"=617ml/ft and 4"=2470mllft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba iii i1n L (Q� n1t.S OCY1
b. Acceptance Criteria defined (from workplan)
Purge Volume (@) well volumes) or rate (I/min) ue
Maximum Allowable Turbidity NTUs
Stabilization of parameters
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
m
91W. . .
—Turbidity
••
•®"'
•.. ..
•
e. Acceptance criteria pass/fail
Y,eNo
s/
N/A
Has required volume been removed
L❑
0
Dissolved CO2 = '�
Has required turbidity been reached
❑
❑
Sulfide =
Have parameters stabilized
❑
❑
Fe+2=
Has Low flow been maintained at >0.1 ft/min
f3' ❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
111- (j
S•
i
'
It
Lt•
`
(c
comments:
IDW: Place in drum.or note other method of handling j j�
Signature Date 9V-T`Yv
Duncklee Dunham. P.C.
Environmental Consultants
511 Kelslor Dr. Suite 102 Phone [phone]
919 tl5t195!YJ
Cary. North Carolina 27518 rns:

DUNCKLEE WeV iezoID:
.9—, DUNS I M Sam le ID
Ground Water Sample Collection Record
Client: SS -Statesville
Date:
Project No: 60200
Time: Start Cti am/pm
Site Location: Statesville, NC
Finish (IA—am/pm
Weather Conds: C 'r Su.utln+l Collector(s)
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well Piezometer
r
a. Total Well Depth (ft bmp)_ c. Casing Material
e. Length of Water Col. (a-b)
ail
}
b. Water Table Depth (it bmp) ti,1 d. Casing Diameter
f. Calculated Well Vol.
2"=617ml/ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba 6t=r7" c,
b. Acceptance Criteria dd fined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Tb ldity NTUs
Stabilization of parameters °o
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testinq Equipment Calibration Documentation Found in Field Notebook # Page #
•
•
1
�-�■IIa�L
�
" /
n
e. Acceptance criteria pass/fail
Yes
No
NIA
Has required volume been removed
/
❑
❑
Dissolved CO, _
Has required turbidity been reached
Sulfide =
Have parameters stabilized
❑
❑
Fet2=
Has Low flow been maintained at >0.1 ft/min
❑
❑
NO3 =
If no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Sam le ID
ContainerType
No. of Containers
Preservation
Analysis
Time
Comments:
IDW: Place in drum or note other method of handling
`-1
Signature / ' / Date—�
Duncklee Dunnanl, P.C.
Enviror mantil Co ultaAs -
511 Keisler �, Sude 102 --Phone. [phone]a9H
Faz; 919.859.9849
Cary, North Candela 27516

- DLINCIG�EE
11- IDUP-41 tAM
Ground Water Sample Collection Record
Well/Piezo ID:
L044
Sam le ID 114 —o 1
Client: SS -Statesville Date: Q-1*"�U
Project No: 50200 Time: Start lQ39 am/pm
Site Location: Statesville, NC Finish 4 5 00 am/pm
Weather-Conds: rtgLal- Collector(s)
WATER LEVEL DATA: (measured from.MP at Top of Casing)
a. Total Well Depth (ft bmp) L1 ai c. Casing Material V V C.
b. Water Table ft Depth bm t1
p ( p) R ,(, d. Casing Diameter
Well ED Piezometer ❑
e_ Length of Water Col. (a-b)
f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba.��CQ 5'1A
b. Acceptahce Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters 96
c. Field Testing Equipment Used: Make Model Serial Number
d: Field Testinq Equipment Calibration Documentation Found in Field Notebook N Page N
RM
R.r
_O
��
i •.
��W
..�
.
e. Acceptance criteria pass/fail
Ye
No
NIA
Has required volume been removed
❑
❑
Dissolved CO, _ —
Has.required turbidity been reached
10�
❑
❑
Sulfide = _
Have parameters stabilized
01-
❑
❑
Fe+2=
Has Low flow been maintained at >0.1 ft/min
-❑
Cl
NO3 =
If no or N/A - Explain below. .
-.SAMPLE COLLECTION:
Method:
Sample ID
Container Type
No. of Containers
Analysis
,,``
=0LtL0
r A • ti
<Preservation
/ EftK�iG
TTime
6
��
4l
comments:
IDW: Place in drum or note other method of handling
Signature Date�j
_ Duncklee Dunham. P.C.
Environmental Consultants
- 511 Kelsler Dr, Suite 102 Phono 919.HSH.9e9tt
- Cary, Noah Carolina 2751 a - - Fax: [phone]e99

L� U N C KL [_. I Well/Piezo
U NIsam le ID
Ground Water Semple Collection Record
Client. SS -Statesville Date:
Project No: 50200 Time: Stan _ am/pm
Site Location: Statesville, NC Finish_ am/pm
Weather Conds: Collector(s)'
WATER LEVEL DATA: (measured from MP at Top of Casing) Well 1 Piezometer
a. Total Well Depth (ft bmp) //�i _ c. Casing Material _ V e. Length o1 Water Col. (a-b)
b. Water Table Depth (ft bmp) % D d. Casing Diameter 2-if f. Calculated Well Vol.
2"=617m1/ft and 4"=2470ml/h
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba t i L C
b. Acceptance Criteria defined (from workplan) 0p t
Purge Volume (@ well volumes) or rate (I/min) Uc� A
Maximum Allowable Turbidity NTUs 'J J
Stabilization of parameters °o
c. Field Testing Equipment Used: Make Model Serial Number
Field Testing Equipment Calibration Documentation Found in Field Notebook # Page H .
Time
WL
It bmp
Vo
Evac. I
F low
1/min
T" U
pH
Spec.Cond
mS/cm)
Turbidity
.-(NTUs)
DO
ORP
Odor/Color
Other
Lt
Sit
CV1-
b
e. Acceptance criteria pass/fail
Yes
No N,
Has required volume been removed
El❑
Dissolved CO, = ^
Has required turbidity been reached
❑
❑
Sulfide =
Have parameters stabilized
❑
❑
Fe+2=
Has Low flow been maintained at >0. I ft/min
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Iinfn•
Sareple ID
Container T e
No. of Containers
Preservation
Anal is
Time
��
tt
to
fe
comments:
IDW: Place in dr i or note other method of handling_
Signature Date
nancm- Dunhsm,P C.
fnvnonmental Consullmis
ht 1 Ku;MM DI. Suite 102 989A
.at Nonit Cdrolina 2/Glti I'nM,9n),BCAi,tl&99

DIJNCKLEE e/ lezol : _
ek DUNI-ISM Sam IeID - • G`L' lr
Ground Water Sample Collection Record
Client: SS -Statesville
Date:
Project No: 50200
Time: Start am/pm
Site Location: Statesville, NC
Finish am/pm
WeatherCDrids:
V '4g.
Collector(s)
WATER LEVEL DATA: (measured from MP at Top of C sing)
Well [i� Piezometer
a_Total Well Depth (ft bmp)
W ,a
c. casing -Material
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
,U
�t !r
d. Casing Diameter Ot
t. Calculated Well Vol.
2"=617m1/ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan) i l l-
-,Purge Volume (@ well volumes) or rate (I/min) �u 2 V0 igcti1lO�5
Maximum Allowable Turbidity NTUs J
Stabilization of parameters °b
c. Field Testing Equipment Used: Make Model Serial Number
d. -Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes
No
A
Has required volume been removed
❑
❑
Dissolved CO2 _
Has required turbidity been reached
❑
❑
Sulfide =
-Have parameters stabilized
❑
❑
Fe+2=
Has Low flow been maintained at >O.tft/miri
❑
❑
NO3 = __
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
—(`
- - Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
,-
Dunckl00 Dunham, P.C.
_ - EnwronlneMnl ConsulIMIB '
.. 511 Kmaler Of. Suite 102 - "" " Phano. 919.05e.9808 .
- City. With Cmollnii 21510 " - Fiu: 919.858.9600

nU
w
bL
DU 1\T4--I{LEE
sc ourI-1ANC
Ground Water Sample Collection' Record
ell! iezo 1 : :
Sam le ID .. r-U/oyip
Client: SS -Statesville Date:
Project No: 50200 . Timei Start am/pm .
Site Location: Statesville, NC Finish _ .am/prn
WeatherConds: k91--W, r_Snunt( Collector(s) l
WATER LEVEL DATA: (measured from MP at Top of Casing) n.r', Well Piezometer
a. Total Well Depth (ft bmp), � c. Casing Material Y V V e. Len�thof Water Col. (a-b)
Al
b. Water Table Depth (ft bmp) 1.1Mi d. Casing Diameter _ I. Calculated Well Vol. _
2"=617ml/ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba
b. Acceptance Criteria defined (from workplan) + -
Purge Volume ( well volumes) or rate (1/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters `'
c. Field Testing Equipment Used: Make - Model Se ' I Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook N Page .#
T�tl�Ill,
•'
tUWWlfa��
••
�
•.. ..
•
®��AIMSr
��
�MM__--■um.
lm®�M�--
�BMMMNM
4V7M�=
a •
s :
mo
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
it
❑
❑
Dissolved CO2 = —"
Has required turbidity been reached
❑
❑
Sulfide = —'
Have parameters stabilized
❑
Fe+2=
Has Low flow been maintained at >0.1 ft/min
Cl
❑
NO3
It no or NIA - Explain below.
. -
SAMPLE COLLECTION: Method:
Sam le ID
Container Tyjie
No, of Containers
Preservation
Analysis
Time
j W —Nip
04—ott
l*" C't r
Z—
t
�r
Comments
IUW: Place in drum or note other method of handling —X
W �• \ A.tn .ram �
^`
Signature 1
�L¢/���TtMt�\ Etiq.� � � Date / L .,,
l� G&S Q K` Uc , S i K I 1ti/U. (r i' �aS %>-t
7v kc - ..
Dunckiao Cunnam, C. V (� �t� r�, i
Envi,onmental Consunantsle�
S t ry, Nwth CAroi ,m 47818 \ S�n - r�Fra: 919.8858.9a99 �Af .
a�� t,�Zl� CAiQc 40. iLetad�J JY� ' 1Mf (1`i,Y��,1�L,���5•
to AV.&CAN C's �OJ'\l LL , J

{� DUNCKLE.)C Well/ iezo ID: i
Sam le ID (]
Ground Water Sample Collection Record
Client:
Project No-.
Site Location:
Weather Conds:
SS -Statesville
50200
Statesville. NC
Collector(s)
Date:0
Time: Start amlpm
Finish JkIL, am)pm
WATER LEVEL DATA:. (measured from MP at Top of Ca sing) Well Piezometer
a. Total Well Depth (ft bmp) _ Qry��/.fA c. Casing Material �VC e. Length of Water Col. (a-b)
b. Water. Table Depth (it bmp) 1 • ){O d. Casing Diameter ' r I. Calculated Well Vol.
2°=617m)M and 4°_2470m1/ft
WELL PURGING DATA
a. Purge Method/Equipment_ Low flow using pump and horiba M (13I _ sm'(nn )o6 1()
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (1/min) �u
Maximum Allowable Turbidity NTUs
Stabilization of parameters °b
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook M Page N
KIM
a
�-�M-
Nmwmm
my
_r=
OEM
w ►
�w=
e. Acceptance criteria pass/fail
Yes/ No
N/A
Has required volume been removed
❑
❑
Dissolved COz =
Has required turbidity been reached
❑ ��
❑
Sulfide =
Have parameters stabilized
-❑
❑
Fe+2= -
Has Low flow been maintained at>0.1ft/min
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
)
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time-
-X&5t4#Jffl- Nib
of
(
%Ic
t%Ta
I(
uommems
IDW: Place in drum r note other method of handling
Signature Date
i
_ - - nunckleo Duntuun, P,C, - -
_ -Envn_onmenlal Ccnsullnmc
611 Kelsler Dr, Swte 102
.. Quy.. North Catolinn 2701 B
Phone.Ul U.Brre.UBUB

Client: SS -Statesville Date: U
Project No: 50200 Time: Start, MA, m/pm .
Site Location: Statesville. NC. I- Finish (32 am/pm.
WeatherConds: ULlut(t Collector(s) K
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer
a. Total Well Depth (it bmp) c. Casing Material _LVCI , e. Le gth of Water Col. (a-b)
n (r
b. Water Table Depth (ft bmp) b'.Z2� d. Casing Diameter 1� f. Calculated Well Vol.
9"=A17ml/ftanri 4"_947(im1lft - -
WELL PURGING DATA
a. Purge MethodlEquipment_ Low flow using pump and horiba
b. Acceptance.Criteria defihed (from workplan)
Purge Volume W -s' i - well volumes) or rate (1/miin)
Maximum Aliowadl rbidity. NTUs -
Stabilization of parameters %
c. Field Testing Equipment Used: Make .. Model Serial Number .
d. Field Testing Equipment Calibration Documentation Found -in Field Notebook 9 Page #
e. Acceptance criteria pass/fail
Yes No,
NIA
Has required volume been removed
/ ❑
❑
Dissolved CO=
Has required turbidity been reached
❑
Sulfide
Have parameterS stabilized
❑
❑
I FC+2=. �aQ_
Has Low flow been maintained at>0,tfUmin
❑
❑
NO3
If no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Sample ID
Container Type
No. of Containers
Preservation
Anal is
Time
6 5 W —OLt IQ
1,2/
eOa
'
comments : ' r
IDW: Place in drt 1 or noto othot mothod of handling
signature _ � -� Data
f8
Dtmtklue Dutthatn, RID.
Environmental Consultants
G11 1Caisier Dr, Saito 102 Phrnlv.a10.B58.9808
Caty, Nmth cnroUna 7r01s . - : .-. r5u: sts.asasass:

DUNCKLEE
DUNHAM
Ground Water_Sample .Collection Record
WeIVPiezo iD-2t (&E EID
Sam le ID: , , W
Client: •- �, ZyiIL9 ��dti �i�Y �k�;;U1�' Date: - ,1-ld
Project No: ;;-I,:R a v Time: Start I W am/prn
Site Location: +ca��1ilP lar);T4+" �GFb� v+a Finish: TV1h5 am/pm
Weather Conds: Collector(s)
WATER LEVEL DATA: (measured from MP at Top of Casing) , Well ® Piezometer O
a. Total Well Depth (ft bmp) —b1�— c. Casing Material e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) la,gy— d. Casing Diameter . a►, I. Calculated Well Vol.
7=617mllft and 4"=2470inVft
WELL PURGING DATA
a. Purge Method/Equipment I-' ll L' •- )i avo -Q10 )
b. Total Purge Volume A- I2,A IGallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (Vmin)
- Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fall
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved CO2 _
Has required turbldity, been reached
❑ /
❑
❑
. Sulfide
Have parameters stabilized
[g'
❑
❑ '
Fe,+2 CL -
Has Low flow been maintained at <0.Ift(min
❑
❑
❑
NO3 =
If no or NIA - Explain below.
SAMPLE COLLECTION: Method:
Rwfw-
tl )
am e (D
Container Type
No. of Containers
Preservatim
Analysts
Time
MIA
Comments:
IDW: Plaea EndnlM note other mothed ott�hatiOng r'
signaturo L w Date
Dmtwe Dunham, P.C.
Envlmnmemal Consu"W1 Erq(ft nn0
511 Kefsler Dr• Sala 102 PMna 018.8562M
Cary, too camana 27518 -

DUNCKLEE Well/Piezo ID:
SL DUN3- AAM iSample ID:
Ground Water Sample Collection Record
Client: `6''34CA—(-S' 7l U _ <'�C�'.� t"�(� Date: 10 - r1, 1- i0
Project No: IV,ca 0D Time: Start `� L v amlpm
Site Location: Finish: t O $ am/pm
Weather Conds: Cti !r Collector(s)
LATER LEVEL DATA: (measured from MP at Top of Casing) Well = Piezometer O
Total Well Depth (ft bmp) c. Casing Material e. Length of Water Col. (a-b)
Water Table Depth (ft bmp) b 5 d. Casing Diameter f. Calculated Well Vol.
WELL PURGING DATA ll r
a. Purge Metho IlEquipment �r b1 V V t (C 1 ULl 60 t 4 D 1.0
b. Total Purge Volume i ( Gallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Field Testina Eauipment Calibration Documentation Found in Field Notebook # Page #
Time
WL
ft brnp
Vol
Evac. 1)
Flow
(Ilmin
PH
Spec. Cond
m S/cm
Turbidity
NTUs
DO
T° ©
ORP
Odor/Color
Other
5s
T.; -q
IA—
64-
�
S io
(a '
c�
(o
, �
•L
1 4
,qi7
C,
nIf
(oi,
`,,?
a"
) 3 )
1
q1
e. Acceptance criteria pass/fail
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved CO2 =
Has required turbidity been reached
❑
❑
❑
Sulfide =
Have parameters stabilized
[�
❑
❑
Fe+ _ —`-' _
Has Low flow been maintained at <0.1ft/min
❑
❑
❑
NO3 =� — ----
If no or NIA - Explain below.
SAMPLE COLLECTION: Method:
O\L7
Sample ID
ContainerType
No. of Containers
Preservation
Analysis
1,c7
1 G
tTime
'J
Comments:
IDW: Place in drum or note other method of handling
Signature � J
Date j V ' -'�l 10
DunWee Dunham. P.C.
Envlronmental Consulting Engineering
511 WSW Dr, Suito 102 Phone [phone]
Cary, North Carolina 27518

D U-T qC K L E E lWeIVPiezo ID: ' i.c f, s l-
d& 1DUTJ ,TMA.M SamplelD:
Ground Water Sample Collection Record
Client: t�Date: I0-g1-I J
Project No: C) Oft O O Time: Start (L/A5 amlpm
r
Site Location: L—`i�ti I L ,n (" F2d-i f :' fm Finish: Wn am/pm
WeatherConds: ("�Illl.'T �` j UL�� Collector(s) J
WATER LEVEL DATA: (measured from MP at Top of Casing) t Well =5-� Piezometer O
a. Total Well Depth (ft bmp) 15 c. Casing Material L e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) d. Casing Diameter -2l f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment_E'ri S�alfi� L �t 161n >
b. Total Purge Volume 'V ! ,Sri rA ( Gallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used:
Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
®-
e. Acceptance criteria passifail
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved CO2
Has required turbidity been reached
❑/
❑
❑
Sulfide =
Have parameters stabilized
1�
❑
❑
Fe+2
Has Low flow been maintained at <0.1ft/min
❑
❑
❑
NO3 =
If no or NIA - Explain below.
SAMPLE COLLECTION: Method: r i
Rate:
Sample lD
ontarner Type
No, of Containers
Presenratro
sis
Time
�ul�Lfrl'b
Comments :
IDW: Place in drum or ote other method of handling
, Signature / ✓ Y'
V�
Duncklee Dunham, P.C.
Envacumental CormAting Engtneenng
.511 KeiWer Dr. Suae 102
Cary, Nodh Carotin 275ta
Date l 0 " Q 1-1 c
Phone 919.85a.9aga

DLJNCKLEE WelUPlezolD:
8� DUNHAM Sam le ID:
Ground Water Sample Collection Record
Client: 5 5- Date: 1Q -- •A l • 10
Project No: Rn C L) Time: Start j-)- I •a am/pm
Site Location: 5:�J- lg'St )i 111 --{'Q sJL ` ,,r -e I7 el Finish: Ta35 am/pm
Weather Conds: tRG,. N —Toff—_ r Collector(s)
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer O
a. Total.Well Depth (R bmp) _�2 c. Casing Material e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) d. Casing Diameter r f. Calculated Well Vol`
a. Purge Method/Equipment OAtIV:l S +CA 11) L, — 1 fSw +) T%,—)
b. Total Purge Volume —*'I- l C1 O i Gallons
c. Acceptance Criteria defined (from workplan) "
Purge Volume (@ well volumes) or rate (Ilmin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fall
Yes
No
N/A
Has required volume been removed
❑
❑
❑
Dissolved CO2 _
Has required turbidity been reached
❑
❑
❑
Sulfide =,
Have parameters stabilized
Er'
El
ElFe+2
=---- ---_�
Has Low flow been maintained at <0Jft/min
❑
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
o.�e.
L,)
Sample ID
Container Type
O. of Contalners
Preservation
Analysis
I ime
r W F
l
I
bl I
i cl
�
cad
•�5
Comments : .
IDW: Place In drum or note other method of handling _
Signature-
DunrXee Dunham, P.C.
Erivlronmeritel Consulgng Engineering
511 Kelsler or, Suge 102
_ Cary, North Carotlno 2751E-
Date 0-31-4e )
Phone 919.958.989E .

DLJNCKLEIE
� DUNHAM
Ground -Water Sample Collection Record.
WelUPi.ID:
Sam le ID: / ,I
Client:
�5- `�:14'S�:.14�P (� . t'l(;�1
H
Date:
Project No: _Gj;�
C l
Time: Start r 19 am/pm
Site Location:
1 Ci�iS� ;� 4 ��
_
Finish: _M j'lo am/pm
Weather Conds:
_
Collector(s)
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well �, Piezometer 0
a. Total Well Depth (ft bmp)
c, Casing
Material c L
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
d: Casing
Diameter Q'r
L Calculated Well Vol.
a. Purge Method/EquipmentVI C)
b. Total Purge Volume i Gallons
c. Acceptance Criteria defined (from workplan)
-Purge Volume (@ ' well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters 0/0
d. Field Testing Equipment Used: Make- Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Feld Notebook # Page #
Time
WL
ft bmpEvac.
Vol
1
pec. Cond
m Skm
DO
T° ©
ORP
Odor/Color
Other
'S
r�.�
3r�
c.(10.
MpH
b+
kNTUs
3 N
-7 -3
'13. 3
U $5
'3
101Z40
r
Q. 04
Q I
13.N
O.`,iq
S
ol
r;4
10.`,S
'3
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
❑
❑
❑
Dissolved CO2
Has required turbidity been reached
❑
❑
❑
Sulfide
Have parameters,stabiltzed
[
❑
❑
Fe+•2
Has Low flow been maintained at <0.1ftfmin
❑
❑
❑
NO3 =
If no or NIA - Explain below.
SAMPLE COLLECTION: Method:
Resew -
It") X
i t)W
am le ID
oatarner
No. of Containers
Preservation
Analysis
Time
1
Commenta :
IDW: Piece In drum 0 noto other mothod of handling
Signature !�'t / Date I
1
`1
Duncueo Dunham, P.C.
Eavironmenral Consorting Engine"
511 Kersler Or, Suits 102 Pilo" 919.858.0888
Carp,North CamOna 2TS18

DLJNCKL EE WeIIIPiezo ID: Q
c4L I�LJNI-YAIV1 Sam le ID:
Ground Water Sample Collection Record
Client: SS �(.i�ESt).�t� 1`r?i�. it("I Date: i0,"-,�%I4%
Project No: D Time: Start V(I i cf arrUpm
Site Location: Finish: amlpm
Weather Conds: ; ��'r.1t� . N tv,C> "Y Collector(s) k�, Y 1-
ATER LEVEL DATAt (measured from MP at Top of Casing) Well O Piezometer O
Total Well Depth (It bmp) _ c. Casing Material f �2L. e. Length of Water Col. (a-b)
Water Table Depth (ft bmp) rl 1 d. Casing Diameter "hIt f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment nl'3 !
b. Total Purge Volume Ctn 1 Gallons
c. Acceptance Criteria defined (from workplan) Lj
Purge Volume (@ well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used:
Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
WL
Itbm
Vol
Evac. I
pH
Spec. Cond
m S/cm)
Turbidity
(NTUs)
DO
T° ©
ORP
Odor/Color
Other
CI
1
(CA
CI ,
i .0
L1 L,
nUmin
�'�.�
Div.
C'L-
is:r`
-
�(
L�
f- 3
L
.?�
(`
G c
L
�7'Ll
1
C
5
b
"
-1 13
1 L4 ( C
e. Acceptance criteria pass/fall
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved CO2 - -- --
Has required turbidity been reached
❑
❑
❑
Sulfide = —
Have parameters stabilized
[,
❑
❑
Fe+2 = _
Has Low flow been maintained at <0.1ft/min
Cl
❑
❑
NO3
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Rate-
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
U
r I1
.O
5.
V)o
r
Comments:
IDW: Place in drum Ar note other method of handling
Signature I !
r`
1
Date f c, , a la t 10
Duncklee Dunham, P.C.
Environmental Consuring Engineering
511 Kelsler or, Suite 102 Phone [phone]
Cary. North Carolina 27518

Well/Piezo ID: W �
c�'L J�'�JNA jam: Sam le ID:
Ground Water Sample Collection Record
Client:
`� `� 1 �<� . ��{t
�11"
Date:
Project No:
^t C) h U
Time: Start 0 f am/pm
Site Location:
S ACriL1h I(P . I
1 L
Finish: 1_ am/pm
Weather Conds
Collector(s)
/
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well C(2" Piezometer O
a. Total Well Depth (ft bmp)
t7c f
c. Casing Material P VI-
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
i J .CbQ
d. Casing Diameter '�
f. Calculated Well Vol.
2"=617mVft and 4"=2470m1/ft
WELL PURGING DA
a. Purge Method/Equipment lrn, n t - W) no .t-� i�:ii
C)LU vU
b. Total Purge Volume — 9 � c2 I
Gallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate
(I/min)
Maximum Allowable Turbidity
NTUs
Stabilization of parameters
%
d. Field Testing Equipment Used:
Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
WL
It lomp
Vol
Evac. (I)
Flow
(1/min
pH
Spec. Cond
m S/cm)
Turbidity
NTUs
DO
TIC
ORP
Odor/Color
Other
IL•r ��
L"',li
�.��
I ,�t
���
,J
�1. .�
,E,
tiv
�,►
a
Fvl�
r c
�
i. i1i
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
❑
❑
❑
Dissolved COx -
Has required turbidity been reached
❑
ElElSulfide
=
Have parameters stabilized
❑---�
❑
❑
r�
Fe*2 =
Has Low flow been maintained at <O.1fUmin
❑
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Rate:
Sample 10
Conialner T— o -_.
No. of Containers
Presaivation
Ar alvsis
ime
viS_r, Ci
CSCC v
YIc.LC
lG J o
Comments:
IDW: PI©eo In drum or,noto other ineitied of hawing
Dunctdc,3 DuMam, RC,
PaVUeninantal Camuhing anualsenn®
511 Kal'loror, sulto 102
Cary, Noah Comllna 27516
Date
Phony 919.856.9899

DUNCICY— EE WeIVPIezoID: sS Lo—
IDU1',JI-3AM J ISample ID: ,U
Ground Water Sample Collection Record
Pie
Project No:
Site Location:
Weather Conds:
ATER LEVEL DATA: (measured from MP at Top of Casin )
Total Well Depth (ft bmp) I 1 C. Casing Material PVC
Water Table Depth (ft bmp) d. Casing Diameter �-J it
WELL PURGING DATA
a. Purge Method/Equipment t ti IA YV i (ftt wi - Vcw 4 ILT�J
b. Total Purge Volume -,/ F Gr I Gallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (® well volumes) or rate (Vminj
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used:
Date:_ 1
Time: Start I11 am/pm
Finish: \\by am/pm
Well = Piezometer 0
e. Length of Water Col. (a-b)
I. Calculated Well Vol.
2"=617mVft and 4"=2470ml/ft
Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
WL
ft bmp
Vol
Evac. 1
Flow
(Umin
PH
Spec. Cond
(m S/cm)
Turbidity
NTUs
DO
T° ©
ORP
Odor/Color
Other
G
1-
�_.
L'r
� r�
`
"`6
lit�L( Cf
Icl
a
C
-c
1 5
(.
I rj
Li
XL�
(; -
C-
'1,
7
3.
,
ttr
to •
1
to
t,'
C
`fib
- j
1prr iG
��rL-,9'1
;�
.mob cl
}S-
�jD
_
e. Acceptance criteria passffail
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved C04=-----
Has required turbidity been reached
❑
❑
❑
Sulfide =
Have parameters stabilized
[�
❑
❑
Fe+2 =
Has Low flow been maintained at 40.1ft/min
❑
❑
❑
NO3 = ---�
If no or N/A - Explain below.
—'-
SAMPLE COLLECTION: Method:
Rate:
Sam le ID
Container T
No. of Containers
Preservation
Analysis
Time
1�.
�� ' ..
t
3.1yY�{
t.
IV) V-
-tYcA
Comments :
IDW: Place in dru /or note other method of handling
Signature --
t
Dunddee Dunham, P.C.
Environmental Consulting Engineering
511 Keisler Or, Suite 102
Cary, North Carolina 27518
Date l C)
Phone [phone]

1WeI1/Piezo ID:'4
:L)W�
ISample ID: (1, W-4W'� L
Ground Water Sample Collection Record
Client:
3itJALSQ'AV-
rMl A
Date: I0 -a i Z'-)
-4L
Project No:
Ol7
Time: Start am/pm
Site Location:
1' Sk i
Finish: � am/pin
Weather Conds:
e CAI(
—Collector(s)
WATER LEVEL DATA: (measured from MP at Top of CaSIP91)
Well M� Piezometer 1=
a. Total Well Depth (ft bmp)
c. Casing Material . pv
e. Length of Water Col. (a-b)
b. Water Table Depth (it bmp)
QQ, 6%
d. Casing Diameter
f. Calculated Well Vol.
1,
7=6117ml/ft and 4"=2470mlift
WELL PURGING DATA
a. Purge Method/Equipment
b. Total Purge Volume Gallons
c. Acceptance Criteria defined (from workplan)
Purge Volume (@ _ well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field testing Equipment Used: Make. Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance Criteria pass/fail
Yes
No
N/A
Has required volume been removed
E]
0
El
Dissolved CO2 d'----- —
Has required turbidity been reached
11
1:1
El
Sulfide
Have parameters stabilized
0
0
0
Fe+2
Has Low flow been maintained at <0.1ft1min
13
0
❑
NO3
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
-Rate."
Sample ID
Container ryp--e
No. of Containers
Preservation
Analysis
Time
YzAt
-Ig
Comments:
IDW: Place In drum or noto other Method at handling
Signature Date
to 16
Dunclam DWIRM, P.C.
811 ftsW Or, W16 102 Ph"d
Gary, NoAh Catalina 27518,

Project No:
Site Location:
Weather Conds:
D[JNCKLEE Well/Piezo ID:
�LT�1A Sample ID:
Ground Water Semple Collection Record
Date:
Time: Start I ` I am/pm
Finish: 1?) am/pm
WATER LEVEL DATA: (measured from MP at Top of Casing) Well O Piezometer
a. Total Well Depth (ft bmp) /ct ' C. Casing Material (�V e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) LAC!,, lb� d. Casing Diameter f. Calculated Well Vol.
T'=617mI/ft and 4"=2470m1(ft
WELL PURGING DATA
a. Purge Method/Equipment im � R\i ' k 11 o''-)- v'� — 4 01� _kA `vim
b. Total Purge Volume `.-) C -,I Gallons
c. Acceptance Criteria defined (from workplan)
-.Purge Volume (@ well volumes) or rate (Itmin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
Time
WL
ft bmp
Vol
Evac. 1)
Flow
pH
Spec. Cond
m Slcm)
Turbidity
(NTUs)
DO
T' ©
ORP
Odor/Color
Other
t fo. J
iF,
r
?i
(0 ,
1.DL
�ck'( t
_
7
1 I. p�
✓� •
7
,
I•
'L2
`j . 1�7
i
Zl (^.
19.0
414 lit
" f (1
r{
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
❑
❑
❑
Dissolved CO2Has
required required turbidity been reached
❑/'
❑
❑
Sulfide =
Have parameters stabilized
13
❑
❑
Fe+2 =
Has Low flow been maintained at <0,1ftlmin
❑
❑
❑
NO3 = _
If no or N/A - Explain -below.
SAMPLE COLLECTION: Method:
O�fn•
I i7 1
_ S I Jli
Sample ID
containg—rT—ype
No. of Containers
Preservation
Anatysis
Time
iJ
tn( i' �t
j1Rl n[
Am Mtr dir
AIT
'1 t1 c
r
Comments:
IDW: Place in drum or note other method of handling _
Signature fI i�
l
Dum;YJee Dunham. P.C.
Environmental Consulting Engineering
511 Nelslor Dr, Suite 102
Cary, North Carolina 27518
Date
Phone [phone]

DUN CKLEE WeIYPiezO ID:
8i DL7NHAM Sam le ID: 14.WCo h
Ground Water Sample Collection Record
Client `,��j� J'7lCi�c�U<<�, Date: r 02P
IL
Project No: v U Time: Start 1Ll 01)�am1pm
Site Location:Finish: L1 t) am/pm
WeatherConds: elrr Collectors) VA`
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer O
a. Total Well Depth (ft bmp) Fj c. Casing Material /L e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) i . (O `f d. Casing Diameter I. Calculated Well Vol.
2"=617m1fft and V'=2470m1/ft
WELL PURGING DATA
a. Purge Method/Equipment loe'Ack r ( I .
b. Total Purge Volume ^-,^ 1Si rAA I UV15 Gallons
c. Acceptance Criteria defined (from workplan)
- Purge Volume (@ well volumes) or rate (Vmin)
- Maximum Allowable Turbidity NTUs.
- Stabilization of parameters %
d. Field Testing Equipment Used: Make Model Serial Number
e. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes
No
NIA
Has required volume been removed
❑
❑
❑
Dissolved CO2 =
Has required turbidity been reached
❑
❑
❑
Sulfide =
Have parameters stabilized
❑
❑
Fe+2 =
Has Low flow been maintained at <0.1tt1min
❑
❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
P.-
Sum��
- ontalnee —e----
No. of once hers
Preservaw
smaw3is
Time
b
� .n (,
�i,fir
' L Q o
Comments:
IDW: Place In drum or to other method of handling
Signature /
T(-",-
Date . (0 � 3Q - L
Dunchke Dunham, P.C,
Envlronmomal CanUAIng EngmeeAng
611 Kct*t Or, Suao 102 - Phone lllfa.666.D99B
eery, North CAMERA 27515

DUNC]KLEE WeIVPiezoID: f'l% 1 12(7
�UHA Sam le ID: tc f^ t > f
Ground Water Sample Collection Record
Client:
>`r �j�t i ),IDS
tiE' ('� C�`C1<l 1
Date: !0
Project No:
Time: Start !` tiL am/pm
Site Location:
Finish: amlpm
Weather Conds:
i i (C, / ,1 jCT' Collector(s)
\>+n1
-
I
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well Piezometer O
a. Total Well Depth (ft bmp)
\3�3 r
c. Casing Material tP- VL
e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp)
c
r>> 3, u J
L '`
d. Casing Diameter j
I. Calculated Well Vol.
2•'=617mVft and 4"=2470mlift
WELL PURGING DATA f
a. Purge MethodlEquipment
b. Total Purge Volume 7 n C7 CI�J(c54) S r14 �lSj CI �1Z�rl cjallons ci rar5
c. Acceptance Criteria defined (from workplay
Purge Volume (® v:zll volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
d. Field Testing Equipment Used: Make Model
e. Field Testino Ecuipment Calibration Documentation Found in Field Notebook # Page #
5434t, wilItU a erl e4,4 9+4i
Serial Number
Time
WL
ft bm
Vol
Evac. 1(1/min
Flow
PH
Spec. Cond
m Slcm)
Turbidity
NTUs)
DO
T° ©
ORP
OdodColor
Other
Y
5v
r
cI
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at <0.1fUmin
If no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
NIA
❑
❑
❑
Dissolved CO2 =
❑
❑
❑
Sulfide =
❑
❑
❑
Fe+2 =
❑
❑
❑
NO3=
Sample ID
Container T e
No. of Containers
Preservation
Analysis
Time
v' S'R I ''� (,
JN1�u.i�
.-it :1 r, .�i�
��' r✓
Comments: T Y.,XwY
IDW: Place in drum or note other method of handling
1 �A
Signature 1) AA " -4 (� LV—
Dunciclee Dunham. P.C.
Environmental Consulting Engineering
511 Keisler or, Suite 102
Cary, North Carolina 27518
Date
Phone [phone]B98

Q n / ® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
ace/'V lal �/ ical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.paJce'la`bs.com Asheville, NC 28804 Huntersville, NC 28078.
[phone] [phone]
April 19, 2010 .
Mr. Jayson Kilcoyne
Duncklee & Dunham '
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Dear Mr. Kilcoyne:
Enclosed are the.analytical results for sample(s) received by the laboratory on April 07, 20.10. The:
results relate only.to the samples included inthis-report. Results'reported herein conform to the`
most current NELAC standards, where applicable, unless otherwise narrated inthe body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where.the samples were received.
If you have any questions concerning this report, please feel free to contact me:
Sincerely,
Renee Spencer-
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS Page 1. of 16
'This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
,

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
2225 Riverside Dr.
9800 KinceyAve. Suite 100
+CioaJCiII
WmpSeelabsCVm
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
CERTIFICATIONS
Project: SS STATESVILLE 50200
Pace, Project No.:. . 9266833
Asheville Certification IDs
2225 Riverside Dr. Asheville, NC 28804
North Carolina Drinking Water Certification* 37712
Connecticut Certification M PH-0106
North Carolina Bioassay Certification M 9
Virginia Certification M 00072
New Jersey Certification #: NC011
Tennessee Certification #: 2980
Massachusetts Certification M M-NCO30
South Carolina Certification #: 99030001
Louisiana/LELAP Certification M 03095
South Carolina Bioassay Certification M 99030002
Florida/NELAP Certification M E87648
Pennsylvania Certification M 68-03578
West Virginia Certification M 356
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
Page 2 of 1.6
-This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
M ACCOgO'
�z

®
Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
Anal ft aL
2225 Riverside Dr.
9800 Kincey Ave: Suite 100
www.paccelabs.com
Asheville, NC28804
Huntersville, NC 28078-
.[phone]
[phone]
. ... ....
ANALYTICAL RESULTS
....
Project:. SS STATESVILLE 50200
Pace Project No.: 9266833
Sample: K66W6A-0410
Lab ID: 9266833001 Collected: '04/06/10 17:40
Received: 04/07/10 12:00
-Matrix: Water
Parameters
Results Units Report Limit. DF
Prepared Analyzed
CAS No.. Qua l.-
'350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
016 mg/L 0.10 1.
04/13/10 17:36 766441-7.
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
135 mg/L 2.5 25
04/08/10 12:05' -
a
Date: 04/19/2010 04:18 PM REPORT OF LABORATORY ANALYSIS Page 3" of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

acer4nalyticaJ�
. www.pacelabs.com
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: _ SS STATESVILLE 50200
Pace Project No.: 9266833
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6B-0410 Lab ID: 9266833002 Collected: 04/06/10 15:18 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/10 17:37 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 34.5 mg/L 0.50 5 04/08/10 11:50
Date: 04/19/2010 04:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 16

�a
® Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical 2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Sample: K66W6E-0410 Lab ID: 9266833003 Collected: 04/06/10 16:42 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.7 mg/L 0.10 1 04/13/10 17:37 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2 - .
Nitrogen, Nitrate 243 mg/L 2.5 25 04/08/10 12:04- .
Date: 04/19/2010 04:18 PM REPORT OF LABORATORY ANALYSIS Page 5 of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
4 C cccyc'
c

laceAn8ly Ca1�
wowvpacelaLs,�un
Project: - - SS STATESVILLE 50200
Pace Project No.: 9266833
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7D-0410 Lab ID: 9266833005 Collected: 04/06/10 11:32 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/10 17:41 7664-41-7
353.2 Nitrogen, N07JN03 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 0.22 mg/L 0.10 1 04/08/10 11:17 Mo
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace,Analytical Services, Inc..
.O H Acco,
i
Page 7 of 16

®
5aceftlyfical
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
- _ Pace Project No.: 926,6833
Sample: K65W7F-0410
Lab ID: 9266833006 Collected: 04/06/10 12:22
Received: 04/07/10 12:00
Matrix: Water
Parameters
Results - Units Report Limit DF
Prepared Analyzed
CAS NO., Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
04/13/10 17:43 7664741-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
. .
Nitrogen, Nitrate
9.2 mg/L 0:10 . 1
04/08/10 11:20 - MO

aceAnaIXical
www.,pacelabs.com
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Sample: K65W6M-0410 Lab ID: 9266833004 Collected: 04/06/10 14:22 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/10 17:39 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.16 mg/L 0.10 1 04/08/10 11:30
Date: 04/19/2010 04:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
A-oV
ux
Page 6 of 16

aceAnalytieal
www.pacei8bs.com
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7H-0410 Lab ID: 9266833007 Collected: 04/06/10 13:00 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual
350.1 Ammonia Analytical Method.: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/1017:45 7664-41-7-
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.47 mg/L 0.10 1 04/08/10 11:24
Date: 04/19/2010 04:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
o �N AC.C,.
n
Page 9 of 16

aceAnalytical
W'mpacetabs a om
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Sample: K65W7J-0410 Lab ID: 9266833008 Collected: 04/07/10 10:44 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.4 mg/L
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 157 mg/L
Date: 04/19/2010 04:18 PM
0.10 1 04/13/1017:46 7664-41-7
2.5 25 04/08/1012:06
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
EC ACCCCoo�y"[C�,\
VL.LLL[Hd�1�J z
Page 10 of 16

aceAnalytical
www.pacelabs.com
I
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K-0410 Lab ID: 9266833009 Collected: 04/07/10 10:15 Received: 04/07/10 12:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. - Qua] -
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 3.6 mg/L 0.10 1 04/13/10 17:46 7664-41-7
363.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 77.4 mg/L 1.0 10 04/08/10 11:56 .
Date: 04/19/2010 04:18 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
e 6
Page 11 of 16

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
acomalytrcal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wwvpac2Pabsawm Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.:.. 9266833
Sample: - MW7L-0410 Lab ID: 9266833010 Collected: 04/07/10 10:00 Received: 04/07/10 12:00 Matrix: Water
Parameters' Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 9.0 mg/L 1.0 10 04/13/10 19:01 7664-41-7
353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 85.7 mg/L 1.0 10 04/08/10 11:55
Date: 04/19/2010 04:18 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. .
- - .- VL11Vlf.4rllx '
Page 12 of 16

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnaI l tical
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
V www.pacelabs.com
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.: 9266833 .
Sample: K65WSN-0410
Lab ID: 9266833011 Collected: 04/07/10 08A5
. Received:. 04/07/10 12:00
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No, Qua[
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.4 mg/L 0.10 1
04/13/10 17:48 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA363.2
Nitrogen, Nitrate
67.2 mg/L 1.0 10
04/08/10-11:53

a Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,�-,aceMalyical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE
50200
Pace Project No.: 9266833
QC Batch: WETA/7141
Analysis Method: EPA350.1
QC Batch Method: EPA350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 9266833001, 9266833002,
9266833003, 9266833004, 9266833005, 9266833006, 9266833007, 9266833008,
9266833009,9266833010,9266833011
METHOD BLANK: 427822
Matrix: Water
Associated Lab Samples: 9266833001, 9266833002,
9266833003, 9266833004, 9266833005, 9266833006, 9266833007, 9266833008,
9266833009,9266833010,9266833011
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 04/13/10 17:25
LABORATORY CONTROL SAMPLE:
427823
Spike LCS LCS %
Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 4.9 99
90-110
MATRIX SPIKE SAMPLE:
427824
9267142001 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
31.9 5 35.6
75 90-110 MO
MATRIX SPIKE SAMPLE:
427826
9266833005 Spike MS
MS % Rec
Parameter
Units
Result Conc. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5 5.4
107 90-110
SAMPLE DUPLICATE: 427825
9267142002 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
27.4 27.7 1
SAMPLE DUPLICATE: 427827
9266833006 Dup
Parameter
Units
. Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND ND
Date: 04/19/2010 04:18 PM REPORT OF LABORATORY ANALYSIS Page 14 of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H. ACCo'.
.,LJC•�L'ldJ0�4�IJ x

aceAnalXical
www,pacelabs.com
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/7112 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9266833001, 9266833002, 9266833003, 9266833004, 9266833005, 9266833006, 9266833007, 9266833008,
9266833009,9266833010,9266833011
METHOD BLANK: 425909 Matrix: Water
Associated Lab Samples: 9266833001, 9266833002, 9266833003, 9266833004, 9266833005, 9266833006, 9266833007, 9266833008,
9266833009,9266833010,9266833011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.10 04/08/10 11:14
LABORATORY CONTROL SAMPLE:
425910
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Nitrogen, Nitrate
mg/L
5
4.6
93
90-110
MATRIX SPIKE SAMPLE:
425911
9266833005
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.22
5
6.7
130
90-110 MO
MATRIX SPIKE SAMPLE:
425912
9266833006
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
9.2
5
15.3
124
90-110 MO
SAMPLE DUPLICATE: 425913
9266833007
Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
0.47
0.49
3
SAMPLE DUPLICATE: 425914
Parameter
Nitrogen, Nitrate
Date: 04/19/2010 04:18 PM
9266833004 Dup
Units Result Result
mg/L 0.16 0.15
RPD Qualifiers
3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
o,�^
u�% N ACC _
Page 15 of 16

aceAnalytal
wdrw.paseia6s.com
QUALIFIERS
Project: SS STATESVILLE 50200
Pace Project No.: 9266833
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
Date: 04/19/2010 04:18 PM REPORT OF LABORATORY ANALYSIS Page 16 of 16
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

. ,4 ceAnal1tical
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
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aceAnalytical
www.pacelabs.com
October 29, 2010
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on October 22, 2010..
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the .
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
46IL" 41V, .
Renee Spencer
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�N ACeOAp�
"�/+\n
�LJJ_ �fA�3i
Page 1. of 19

(��acpeftlXical
WMpacelabs com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Connecticut Certification #: PH-0106
Florida/NEIAP Certification M E87648
Massachusetts Certification #: M-NC030
New Jersey Certification* NC011
North Carolina Bioassay Certification #: 9
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Drinking Water Certification M 37712
North Carolina Wastewater Certification M 40
Pennsylvania Certification #: 68-03578
South Carolina Bioassay Certification M 99030002
South Carolina Certification M 99030001
Virginia Certification #: 00072
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
ACCO,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 19

acmnalytical
wvmpacelabs.com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 .
Huntersville, NC 28078
[phone]
Sample: K65W7D Lab ID: 9280452001 Collected: 10/21/10 14:55 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 10/27/10 17:37 7664-41-7 M1
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate ND mg/L 0.10 1 10/23/10 00:41
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H ACCo, .
ux.
Page 3 of 19

aceAnalytical
mimpacelabs.com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7H Lab ID: 9280452002 Collected: 10/21/10 15:05 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 10/27/10 17:39 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.36 mg/L 0.10 1 10/23/10 00:43
Date: 10/29/2010 10:58 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H CCpq�
LH�.f�Y.J z
Page 4 of 19

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
ANALYTICAL RESULTS
[phone] [phone]
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Sample: K65W7G Lab ID: 9280452003 Collected: 10/21/10 17:05 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. -Qua[
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia ND mg/L 0.10 1 10/27/10 17:41 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 3.3 mg/L 0.10 1 10/23/10 00:49
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
N ACCO,
♦O c
V s
Page 5 of 19

aceaiyticl
wwwpac0abs wm
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452.
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7F Lab ID: 9280452004 Collected: 10/21/10 17:35 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 10/27/10 17:41 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 30.7 mg/L 1.0 10 10/23/10 01:57
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
- \%Acco,
r 0
�z
Page 6 of 19

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
c
�i✓eAlia�,yllCa�
2225 Riverside Dr.
9800 KinceyAve. Suite 100 -
www.pacelabs.com
Asheville, NO 28804
Huntersville, NO 28078.
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Sample: K65W6M
Lab ID: 9280452005 Collected: 10/22/10 08:46
Received: 10/22/10 16:45
Matrix: Water .
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual--
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
10/27/10 17:42 7664-41-7,
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.28 mg/L 0.10 1
10/23/10 01:16 .
Date: 10/29/201010:58 AM REPORT OF LABORATORY ANALYSIS Page 7 of 19
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ti�eAnad j#ifca
www.pacelabs.com
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Sample: K65W613 Lab ID: 9280452006 Collected: 10/22/10 09:50 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia . Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.4 mg/L 0.10 1 10/27/10 17:43 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 30.2 mg/L 0.50 5 10/23/10 01:59
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
CC\
� LL�9�C1fi�1�LJ x
Page 8 of 19

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
/ lll'd1i1iaI
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacalabs.com
Asheville, NC 28804
Huntersville, NC 28078.
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Sample: K65W6N
Lab ID: 9280452007 Collected: 10/22/10 10:50
Received: 10/22/10 16:45
Matrix: Water
Parameters
Results Units - Report Limit DF
Prepared Analyzed
CAS No. Qual..
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.2 mg/L 0.10 1
10/27/10 17:44 7664-41-7.
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
66.6 mg/L 0:10 1
10/23/10 02:02
ace
Date: 10/29/2010 10:58 AM REPORT OF LABORATORY ANALYSIS Page 9 of 19
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
u�J--L1fl1�CYJi. .

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Q„+�J e�)�
'dc�/�U1Gii/]Ci�f
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Sample: K65W71K
Lab ID: 9280452008 Collected: 10/22/10 11:50
Received: 10/22/10 16:45
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
3.8 mg/L 0.10 1
10/27/10 17:46 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
84.6 mg/L 0.10 1
10/23/10 02:04
Date: 10/29/201010:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
o,N Acco,
A 0
Page 10 of 19

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aCeAnalXicalf 2225 Riverside Dr. 9800 KinceyAve. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
ANALYTICAL RESULTS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
[phone] [phone]
Sample: K65W7L Lab ID: 9280462009 Collected: 10/22/10 12:50 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual . .
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 12.8 mg/L 0.50 5 10/27/10 17:48 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 95.2 mg/L 1.0 . 10 10/23/10 03:57 .
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS.
This report shall not be reproduced, except in full, -
without the written consent of Pace Analytical Services, Inc..
\N ACCCgO' _
�4 n
U x

aceAnalAcal
www.pacelabs.mm
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7J Lab ID: 9280452010 Collected: 10/22/10 13:35 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.2 mg/L 0.10 1 10/27/10 17:48 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 172 mg/L 3.0 30 10/23/10 02:06 M6
Date: 10/29/2010 10:58 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
CCpq�
4EV n
� z
Page 12 of 19

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalXical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
ANALYTICAL RESULTS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
[phone] [phone]
Sample: K65W6A Lab ID: 9280452011 Collected: 10/22/10 14:20 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.19 mg/L 0.10 1 10/27/10 17:50 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 122 mg/L 0.10 1 10/23/10 02:15
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
C N ACCCgC
M1ex
Page 13 of 19

acmnaljNcal
www.pacelabs.com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab iD: 9280462012 Collected: 10/22/10 15:20 Received: 10/22/10 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.62 mg/L 0.10 1 10/27/1017:50 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 203 mg/L 0.10 1 10/23/10 02:16
Date: 10/29/2010 10:58 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
4EV \N ACCOOp'
Qual
Page 14 of 19

aceAnalytical
www.pacelabs.com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2226 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/8457 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 9280452001, 9280452002, 9280452003, 9280452004, 9280452005, 9280452006, 9280452007, 9280452008,
9280452009,9280452010,9280452011,9280452012
METHOD BLANK: 518648 Matrix: Water
Associated Lab Samples: 9280452001, 9280452002, 9280452003, 9280452004, 9280452005, 9280452006, 9280452007, 9280452008,
9280452009,9280452010,9280452011,9280452012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 10/27/10 17:30
LABORATORY CONTROL SAMPLE: 518649
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.0 101 90-110
MATRIX SPIKE SAMPLE:
518650
9280101001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5
6.1
120
90-110 M1
MATRIX SPIKE SAMPLE:
518652
9280452001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5
6.0
118
90-110 M1
SAMPLE DUPLICATE: 518651
9280101001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
SAMPLE DUPLICATE: 518653
9280452001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND
ND
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Amlac-.
Page 15 of 19

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalXical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.p2mlabs.mm Asheville, NC 28804 Huntersville, NC 28078
QUALITY CONTROL DATA
[phone] [phone]
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
QC Batch: WETA/8419 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9280452001, 9280452002, 9280452003, 9280452004
METHOD BLANK: 516781 Matrix: Water
Associated Lab Samples: 9280452001, 9280452002, 9280452003, 9280452004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.10 10/23/10 00:11
LABORATORY CONTROL SAMPLE:
516782
Spike LCS
LCS
% Rec
Parameter
Units
Cone. Result
% Rec
Limits
Qualifiers
Nitrogen, Nitrate
mg/L
5
5.1
103
90-110
MATRIX SPIKE SAMPLE:
516783
9280442001
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND
5 5.8
115
90-110 M1
MATRIX SPIKE SAMPLE:
516785
9280450002
Spike
MS
MS
% Rec
Parameter
Units
Result
Cone.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
7.4
5 12.0
91
90-110
SAMPLE DUPLICATE: 516784
9280442001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
SAMPLE DUPLICATE: 516786
9280450002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
7.4
7.4
0
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
fifi
Page 16 of 19

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
9cmnal y fica' 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
GV ww�ppaceelabs.coom Asheville, NC 28804 - Huntersville, NC 28078
QUALITY CONTROL DATA
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
[phone] [phone]
QC Batch: WETA/8420
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9280452005, 9280452006,
9280452007, 9280452008, 9280452009
METHOD BLANK: 516797
Matrix: Water
Associated Lab Samples: 9280452005, 9280452006,
9280452007, 9280452008, 9280452009
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.10 10/23/10 00:51
LABORATORY CONTROL SAMPLE:
516798
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
5 5.1 102
90-110
MATRIX SPIKE SAMPLE:
516799
9280442008 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND 5 4.5
90
90-110
MATRIX SPIKE SAMPLE:
516801
9280450010 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
2.4 5 7.5
102
90-110
SAMPLE DUPLICATE: 516800
9280442008 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND ND
SAMPLE DUPLICATE: 516802
9280450010 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Nitrate
mg/L
2.4 2.4 2
Date: 10/29/2010 10:58 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
� LLI�lO�IJ z
Page 17 of 19

aceAnalAcal
www.pacdabs.com
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
QC Batch: WETA/8421 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9280452010, 9280452011, 9280452012
METHOD BLANK: 516814 Matrix: Water
Associated Lab Samples: 9280452010, 9280452011, 9280452012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.10 10/23/10 01:36
LABORATORY CONTROL SAMPLE: 516815
Parameter Units
Nitrogen, Nitrate mg/L
MATRIX SPIKE SAMPLE: 516816
Parameter Units
Nitrogen, Nitrate mg/L
SAMPLE DUPLICATE: 516817
Parameter Units
Nitrogen, Nitrate mg/L
Date: 10/29/2010 10:58 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
5 5.1 102 90-110
9280452010 Spike MS MS % Rec
Result Cone. Result % Rec Limits Qualifiers
172 5 180 169 90-110 M6
9280452010 Dup
Result Result RPD Qualifiers
172 171 0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
o N ACCo,
� l_lJSl11Y�rJ z
Page 18 of 19

aceAnalytical
www.pacelabs.com
QUALIFIERS
Project: SS Statesville Fert. 50200
Pace Project No.: 9280452
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9806 Kincey Ave. Suite 100
Huntersville, NC 28078
DF - Dilution Factor, if reported, represents the factor applied to the. reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
[phone]
Date: 10/29/2010 10:58 AM REPORT OF LABORATORY ANALYSIS Page 19 of 19
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
uLL_YfO acA

ZeAnalydcal
warmpacelabs.com
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B' Section C
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C
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Company: Report To: Attention:
1 408200
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Nitrate Concentration in mg/L
N N W W A
CJ7 O CT7 O (n O V7 O
O O O CDO O O O O
Jan-90
Jan-91
Jan-92
Jan-93
Jan-94
Jan-95
Jan-96
Jan-97
Jan-98
a
Jan-99
ty Jan-00
a
Jan-01
.o
c
Jan-02
Jan-03
Jan-04
Jan-05
Jan-06
Jan-07
Jan-08
}
I Z
� y
Jan-09
a �
N
Jan-10
Jan-11

K65W6 B (Saprolite)
160
140
—♦—Nitrate Results
120
—2L Standard
e
100
C
0 80
C
60
0
U
40
L
♦+
'z'
20
0
_ _
O N M c0 f� M M O N M M V (U I� aD O
M M M M M M M M M O O O O O O O O O O �'-
C C C C C C C C C C C C C C C C C C C C C C
(6 m (o m m m (o m m m m m m m m m m m m m c0 m
Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
3/30/99
1 1/3/99
Nitrate m
22
22
15
26
16
7.6
6.8
28
29
19
18
89.4
140
Ammonia m
No Data
Date
10/24/01
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
1 10/23/06
1 5/1/07
10/15/07
1 4/25/08
4/9/09
Nitrate m 1
78
92
40
41
44
33
35
28
23
31
31
32
40
Ammonia m )
No Data
<0.1
<0.1
<0.1
NS
NS
0.12
<0.1
<0.1
<0.1
NS
<0.1
40
Date
10/29/09
4/6/10
10/22/10
Nitrate m
55.9
34.5
30.2
Ammonia m I
<0.1
<0.10
1.4

K65W6 E (Bedrock)
300
—4 Nitrate Results
250
— 2L Standard
200
8
a
a
0
150
a
u
a
0
.V
100
co.
z
50
0
O N CO IT to (0 h 00 O O N m et u7 (0 r- 00 m O
O O W W O d) W d) W O O O O O O O O O O
i i. i
> > 7 7 7 7 > > 7 7 7 7 5 7i 7 7 7 7 7
Date
Date
8/1/90
1/22/92
2/10/93
8/2/95
11/8/95
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
Nitrate m
7.3
37
27
4.4
5
56
7.9
8.5
11.7
24.1
30.9
49.9
50.4
Ammonia m I
No Data
Date
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
Nitrate m
56
67
68
62
78
81
76
62
60
90
100
120
150
Ammonia (m I)
No Data
<0.10
<0.10
<0.10
NS
NS
<0.10
Date
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/6/10
10/22/10
Nitrate m
140
150
150
14.2
I
169
202
253
44.4
243
203
Ammonia m
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
0.5
<0.10
1.7
0.62

O
12/1 /2008
1 /1 /2009
Nitrate Concentration in mg/L
0 0 0 0 0 0 0 0 0
W A 07 0) 11 1b CO
2/1 /2009
z
3/1 /2009
4/1 /2009
y
5/1 /2009
6/1/2009
7/1 /2009
8/1 /2009
9/1/2009
1011 /2009
i
d
11/1/2009
►-
12/1 /2009
0
1 /1 /2010
211 /2010
3/1 /2010
4/1 /2010
5/1/2010
6/1 /2010
7/1 /2010
8/1 /2010
9/1 /2010
10/1 /2010
11/1/2010

Nitrate Concentration in mg/L
N CO A M m v O O O
O O O O O O O O O O O
O O O O O O O O O O O
12/1 /2008
1 /1 /2009
2/1 /2009
'
3/1/2009
m �
� y
G
4/1 /2009
5/1 /2009
6/1 /2009
7/1 /2009
8/1 /2009
9/1 /2009
10/1 /2009
a
d
to
11/1/2009
z
12/1 /2009
1 /1 /2010
■s
0
2/1 /2010
3/1 /2010
4/1 /2010
5/1 /2010
6/1 /2010
7/1 /2010
8/1 /2010
9/1 /2010
10/1 /2010
11/1/2010

K65W7C (Saprolite)
140
—Nitrate Results
120
—21, Standard
100
8
c 80
1;
L
A
u
°0 60
U
d
_
s.
Z
40
20
0
O
O W W O T O O O O O O O O O O O O O
b .d A A .6 A .6 .d .6 A a n a 6 a � .6 A d
N N CI N N N N 0 N 4) N N N N N N d N N
LL LL LL LL LL LL LL LL LL LL LL LL U.LL LL l.L LL LL LL
Date
Date
2/13/90
1/22/92
2/10/93
10/17/03
7/18/05
10/28/05
4/25/08
12/19/2008 to 10/21/10
Nitrate m
93
130
13
82
33
53
<0.10
1
Dry
Ammonia m
No Data
9
NS
2.3
29.4
D

K65W7 D (Saprolite)
40
35
Nitrate Results
— 21, Standard
30
aa
e�
8
25
c
0
F
a 20
V
d
O
U
! 15
'z
10
5
0
O N M O (O I- 00 O O N M It U) (O Ih 00 d) O
W T O O O O O O O O O O O O O O
7 7 7 7 3 7 7 7 7 7 7 7 75 7 7 7 7 75
Date
Date
8/l/90
1/22/92
2/10/93
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
Nitrate m
11
2
0.57
0.775
2
1
2
1.1
<0.10
1.1
2.4
1.4
0.05
Ammonia m
No Data
0.41
<0.10
Date
4/16/04
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
4/25/08
4/16/09
10/29/09
4/6/10
10/21/10
Nitrate m
1.3
2.4
0.48
2
1.1
15
39.
0.48.
0.21
<0.10
0.22
I
<0.10
Ammonia m
<0.10
NS
NS
0.12
<0.10
1.1
2.1
<0.10
<0.10
1 <0.10
<0.10
<0.10

K65W7 F (Saprolite)
200
+.Nitrate Results
180
—2L Standard
160
a
aO
140
a
'
d.
0 120
sr
.loo
U 80
d
z 60
40
20
OO N m 't U) w t` 00 0) CD N M st le CD n 00 CA C,
. CA C D) T CP C CT CA O O O O O O O, O 9 OO
7 75 7 7 7 7 7 7 7
Date
Date
8/1/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
2/8/96
5/9/96
Nitrate m 1
99
100
109
79
79
110
100
100
96
1.6
94
150
6.1
Ammonia m 1
No Data
Date
3/28/00
11/16/00
10/24/01
3/29/02
10/18/0
55/2/03
10AW03
4/16/04
10/29/04
7/18/05
10/27/05
4/26/06
10/23/06
Nitrate m 1
5.1
0.52
20
33
17
3
21
8.5
<0.1
20
31
1 31
15
Ammonia m 1
'No Data
<0.10
NS
<0.10
NS
NS
NS
I . 0.12
1.1
Date
4/25/08
4/9/09
10/29/09
4/6/10
10/21/10
Nitrate m 1
61.9
33.6
Dry
9.2
30.7
Ammonia m I
<0.10
<0.10
Dry
<0.10
<0.10

K65W7 G (Saprolite)
40
—s Nitrate Results
— 21, Standard
30
8
a
a
p 20
u
G
O
U
d
L
z
10
0
O N cM 'V' In co 1- co W O N CM It O Cfl rl- 00 O O
O O O Q) d) O W d) T O O O O O O - O O O O
7 7 7 7 7 7'5 75 7 7 7 7 7 7 7 7 7 7 7 7
Date
Date
8/l/90
1/22/92
2/10/93
2/8/96
11/3/99
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
10/28/04
7/18/05
Nitrate m
1.7
1.9
2.6
3.5
2.9
3.6
2.8
31
32
1.3
0.4
4.4
1.7
Ammonia m
No Data
<0.10
<0.10
NS
NS
Date
4/25/06
10/23/06
5/l/07 to 4/6/10
10/21/10
Nitrate (mg/IL
16
29
Dry
3.3
Ammonia m 1
'Olo4
4
Dry
<0.10

Nitrate Concentration in mg/L
0 o O o 0 0 0 o O
O IV 41 ? (T 0) v CO (D
12/1 /2008
1 /1 /2009
2/1 /2009
z
3/1 /2009
7
4/1 /2009
c
5/1 /2009
6/1 /2009
7/1 /2009
8/1 /2009
9/1 /2009
10/1 /2009
d 11 /1 /2009
x
A
�
12/1 /2009
O.
K
0
A
1 /1 /2010
2/1 /2010
3/1 /2010
4/1 /2010
5/1 /2010
6/1 /2010
7/1 /2010
8/1 /2010
9/1 /2010
10/1 /2010
11/1/2010

K65W7 J (Saprolite)
300
Nitrate Results
—2L Standard
250
200
0
•q
0
a+
M 150
e
0
U
d
L
100
z
50
0
�r Ln U') co to ti 1- ro ao rn rn C. 0
0 0 0 Co 0 0 0 0 0 0 0
n r; CL a ii a a n
O Q O Q O Q O Q O Q O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m
100
140
74
156
180
140
14.4
178
204
191
199
157
172
Ammonia m
NS
NS
<0.10
<0.10
<0.10
0.10
0.6
0.86
0.79
1.7
1.7
1.4
29

K65W7 K (Bedrock)
250
+Nitrate Results
®2L Standard
200
8
a
150
0
O
d
u
F7
U 100
d
34
z
50
0
"r LA CO (0 n n 00 CO rn W O O
0 0 0 0 0 0 0 0 0
a 0 a i� CL i, a t a o a o
O Q O Q O Q O Q O Q O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/1/07
1 10/15/07
1 4/25/08
12/19/08
4/9/09
10/30/09
1 4/7/10
10/22/10
Nitrate m
81
89
190
100
120
89
25.9
99.5
108
95.4
99.4
77.4
84.6
Ammonia m
NS
NS
4.1
3.7
11
4.5
4.2
4.8
4.1
4.2
3.6
3.6
3.8

K65W7 L (Bedrock)
200
180
4 Nitrate Results
160
- 2L Standard
140
8
120
ti
0
a 100
u
A
U 80
i
L
60
z
40
20
0
v u'> u, co co r r- o CO rn m o 0
0 0 0 0 0 0 0 0 0 0 0
p, U p, U p. U p_ U p. U
O Q O Q O Q O Q O ¢ O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/1/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m
22
98
110
130
120
99
30.5
104
103
93.8
103
85.7
95.2
Ammonia m 1
NS
NS
7.7
7.4
11
11
12.9
12.4
10.4
10.1
9.4
9.0
12.8

g AUG 2 4 2(110
2009 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
August 23, 2010
Prepared for
Mr. Vance Dann
Southern States Cooperative, Inc.
Post Office Box 26234
Richmond, Virginia 23260
[phone]
1
Submitted to
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Branch
Mooresville Regional Office
610 East Center Avenue
Suite 301
Mooresville, North Carolina 28115
Prepared by
Duncklee & Dunham, P.C.
511 Keisler Drive, Suite 102
Cary, North Carolina 27518
DUNCKLEE & DUNHAM, P.C.

DUNCKLEE
��✓ -' &DUNHAM
-gym
August 23, 2010
ENVIRONMENTAL CONSULTING & ENGINEERING
511 KEISLER DRIVE - SUITE 102
CARY, NORTH CAROLINA 27518
OFFICE: [phone]
W W W.DUNCKLEEDUNHAM.COM
AUG 2 4 2010
Mr. Andrew Pitner, P.G.
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Branch
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
Reference: 2009 Annual Groundwater Monitoring and Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant, Statesville, North Carolina
Groundwater Incident Number: 5038
Dear Mr. Pitner:
As requested by Southern States Cooperative, Inc. (Southern States), Duncklee & Dunham, P.C. is
pleased to submit this 2009 Annual Groundwater Monitoring and Treatment System Effectiveness Report
for the above referenced site. This report discusses the work scope performed and the conclusions
derived from sampling and monitoring performed during this period.
If you have any questions or require additional information, please do not hesitate to contact
Mr. Tom Dunham at [phone] ([e-mail]) or Mr. Vance Dann of
Southern States at [phone] ([e-mail]).
Sincerely,
DUNCKLEE & DUNHAM, P.C.
Jayson A. Kilcoyne
Project Environmental Scientist II
Senior Peer Review:
Bryso D. Trexler, Jr., Ph.D., P.G.
Senior Hydrogeologist
cc: Mr. Vance Dann — Southern States Cooperative, Inc. (e-copy)
P:\Southem States\Statesville Fertilizer - 50200\Reports\2009 Annual Report\2009 Annual GW Monitoring Report - 09219.doe
MAILING ADDRESS — POST OFFICE BOX 33366 — RALEIGH, NORTH CAROLINA 27636
NORTH CAROLINA BOARD OF EXAMINERS FOR ENGINEERS AND SURVEYORS LICENSE C-3559
NORTH CAROLINA BOARD FOR LICENSING OF GEOLOGISTS LICENSE C-261
NC DENR REGISTERED ENVIRONMENTAL CONSULTANT NUMBER 00061

Table of Contents
1 Introduction
1.1 Site Location, Description and History
1.2 Summary of Remedial Actions
2 Groundwater Treatment System Modifications and Monitoring Activities
2.1 Recovery Well Installation and Groundwater Treatment System Upgrades
2.2 Groundwater Treatment System Monitoring Activities
3 Groundwater Sampling Activities and Results
3.1 Groundwater Sampling Methodology
3.2 Results from 2009 Sampling Events and Nitrate Trends
4 Conclusions
5 Recommendations
1
1
1
2
2
2
2
3
3
4
4

Figures
Figure
Title-
1
Site Location Topographic Map
2
Site Map
3
Treatment System Discharge Line Outfall Map
4 .
Shallow Aquifer Groundwater Contour Map - April 2009
5
Shallow Aquifer Groundwater Contour Map - October 2009
6
Shallow Aquifer Nitrate Isoconcentration Map - April 2009
7
Deep Aquifer Nitrate Isoconcentration Map - April 2009
8
Shallow Aquifer Nitrate Isoconcentration Map - October 2009
9
Deep Aquifer Nitrate Isoconcentration Map - October 2009
Tables
Table Title
1 Summary of 2009 Well and Water Level Gauging Data
2 Summary of 2009 Groundwater Analytical and Field Parameter Results
Appendices
Appendix Title
A April and October 2009 Field Data Sampling Forms
B April and October 2009 Laboratory Analytical Reports
C Nitrate in Groundwater Trend Graphs
t> iv

2009 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
— Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
- August 23, 2010
1 Introduction
1.1 Site Location, Description and History
The Southern States Cooperative, Inc. (Southern States) fertilizer plant (i.e., the site) is located at 2582
Salisbury Highway (old US Highway 70) approximately six miles east of Statesville, North Carolina (see
Figure 1). The site consists of several buildings including a fertilizer manufacturing building, an office
building, and several small support buildings (see Figure 2). The site is utilized for the manufacturing,
storage, and distribution of fertilizer.
The site is bordered to the north by old US Highway 70, commercially developed parcels to the east,
residential properties to the south, and undeveloped land to the west. The US Highway 70 Bypass bisects
east to west through the southern portion of the site and separates approximately 13 acres from the main
property (see Figure 2).
Groundwater at the site has been impacted by a release of liquid ammonium nitrate from several former
surface water impoundments. Two impoundments (Former Pond No. 1 and No. 2) were located
approximately 1,000-feet southwest of the main plant (see Figure 2). Two additional surface water
impoundments (Former Ponds A and B, see Figure 2) were located east and southeast of the main plant.
These impoundments are referenced in the Corrective Action Plan (CAP) dated January 28, 1994,
submitted by Canonie Environmental to the North Carolina Department of Environment and Natural
Resources (DENR), Division of Water Quality (DWQ), Aquifer Protection Section (APS). In 1994 the
APS approved the CAP. Based on the CAP, the assessment and impact of groundwater contamination
was defined with reasonable certainty.
The objectives of the CAP were to remediate groundwater and to prevent off -site migration of the
groundwater contamination plume. To monitor the effectiveness of the CAP, a groundwater sampling
- plan was developed that established semi-annual (April and October) groundwater monitoring.
1.2 Summary of Remedial Actions
To reduce the levels of nitrate and ammonia in the groundwater, three recovery wells (RW-2, RW-5 and
RW-6) were installed as part of the CAP. However, RW-5 was taken out of service prior to 2005 due to
low or no groundwater recovery. The recovery wells pump groundwater into a treatment system where
the pH is adjusted with a caustic solution prior to being discharged into Fourth Creek (see Figure 3).
r DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2009 Annual Groundwater Monitoring Report
August 23, 2010
Page 2 of 4
The groundwater treatment system is permitted under the National Pollution Discharge Elimination
System (NPDES) program. Under the program, bi-monthly site visits are conducted when the system is
operational to monitor the treatment system and be sure it is operating within the permitted discharge
limits. Effluent water samples are collected bi-monthly and the data is reported to the DWQ on monthly
Discharge Monitoring Reports.
2 Groundwater Treatment System Modifications and Monitoring Activities
2.1 Recovery Well Installation and Groundwater Treatment System Upgrades
In September 2008, Duncklee & Dunham personnel supervised the installation of one groundwater
recovery well (RW-5r) to replace RW-5 for improved water removal and to achieve a greater radius of
influence. RW-5r was installed adjacent to recovery well RW-5 by Geologic Exploration, Inc. of
Statesville, North Carolina. The well was installed to a depth of 135 feet and screened from 65 to 135
feet for optimal groundwater recovery.
Groundwater remediation system repairs and component upgrades were conducted in September 2008
and January 2009 to restore the system to proper operational status. On January 15, 2009, after the
completion of system upgrades and repairs, the system and three recovery wells were restarted and fully
operational. The system operated through the remainder of this annual monitoring period that ended on
October 30, 2009.
2.2 Groundwater Treatment System Monitoring Activities
In accordance with NPDES permit, effluent samples were collected bi-monthly for analysis of total
suspended - solids (TSS) according to Method 2540D and ammonia nitrogen according to EPA
Method 350.1. Monthly effluent samples were analyzed for copper (EPA Method 200.7), chloride
(Method SM 4500-C1-E), TSS, ammonia nitrogen, total Kjeldahl nitrogen, nitrate nitrogen and
phosphorus all by EPA Method 300 series. The samples were submitted for laboratory analysis to Pace
Analytical Services, Inc. (Pace), a North Carolina certified analytical laboratory. During the 2009
compliance reporting period, NPDES reporting sheets were submitted each month to DENR as required
by the NPDES permit.
3 Groundwater Sampling Activities and results
Semiannual groundwater monitoring activities were conducted on April 9 and 16, 2009, and October 29
and 30, 2009. Groundwater flow maps illustrating the shallow groundwater flow for the April and
October sampling events are shown on Figures 4 and 5, respectively. The groundwater flow direction for
both events was to the south-southwest with an average hydraulic gradient of 0.028 feet per foot (ft/ft)
during the April event and 0.022 ft/ft in October.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2009 Annual Groundwater Monitoring Report
August 23, 2010
Page 3 of 4
3.1 Groundwater Sampling Methodology
Prior to well purging and sampling, water level measurements were collected using an electric water level
probe and recorded on field sampling data sheets (see Appendix A). The groundwater level measurement
data is summarized on Table 1.
Groundwater samples were collected from eleven (K65W6"A", K65W6`B", K65W6"B", K65W6"M",
K65W6"N", K65W7"D", K65WTV',` K65W7"H", K65W7"J", K65W7"K" and K65WTV') of the
fourteen monitoring wells during the April 2009 sampling event. The remaining monitoring wells,
(K65W6"D", K65W7"C" and K65W7"G") were dry during this event.
Groundwater samples were collected from ten (K65W6"A", K65W6`B", K65W6"E", K65W6"M",
K65W6"N", K65W7"D", K65W7"H", K65W7"J", K65W7"K", and K65W7"L") of the fourteen
monitoring wells during the October 2009 sampling event. The remaining monitoring wells were dry.
The sampling process consisted of inserting a two-inch submersible electric PVC pump with new
disposable polyethylene tubing in each well to purge and withdraw the samples. The groundwater
samples were collected using low flow sampling techniques. During the sampling process, field
measurements were collected for dissolved oxygen (DO), oxidation reduction potential (ORP), pH,
temperature, turbidity, and electrical conductivity. The field measurement data collected during each
sampling event are summarized in Table 2 and the field data sampling forms are included in Appendix A.
Groundwater samples were collected and placed directly in laboratory -provided containers, labeled,
recorded on a chain -of -custody form, and transported to the analytical laboratory in an insulated cooler
filled with ice. The samples were submitted to Pace and analyzed for nitrate according to EPA
Method 353.2 and ammonia nitrate according to EPA Method 350.1. The laboratory analytical reports
and chain of custody records for both sampling events are included in Appendix B.
3.2 Results from 2009 Sampling Events and Nitrate Trends
Groundwater plume maps illustrating nitrate concentrations in the shallow saprolite and deep bedrock
monitoring wells are presented on Figures 6 through 9. Graphs of the nitrate trends over time are
included in Appendix C.
The following observations have been made with respect to the nitrate plume for this groundwater
monitoring period.
• The two saprolite monitoring wells (K65W6A and K65W6B) located near the two former ponds
(Ponds A and B, see Figures 6 and 8) have shown an increasing nitrate trend since 2007, after a
period of overall decreasing nitrate levels. Both of these wells contain nitrate concentrations greater
than the 2L standard.
The deep monitoring well K65W6E, paired with saprolit6 well K65W6A, exhibited a considerable
drop in nitrate in October 2009. However, the nitrate level remains above the 2L standard and the
- overall nitrate concentration trend is upward in this well.
The saprolite plume well to the southeast (K65W6M), which was installed to replace K65W6D
because it has been dry since 1993, did not contain nitrate above 0.15 mg/L for this reporting period.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2009 Annual Groundwater Monitoring Report
August 23, 2010
Page 4 of 4
• The saprolite plume well along the northwestern edge of the plume (K65W6N) contained nitrate at
levels above the 2L standard and has shown an overall increasing nitrate trend since the well was
installed in 2008.
• The saprolite well K65W7J and the two bedrock wells (K65W7K and K65W7L) located in the core
of the plume contain nitrate levels above the 2L standard. The nitrate levels in the saprolite well have
been on an increasing trend since 2004 while the nitrate concentrations in the two bedrock wells have
been fairly constant.
• The deep plume delineation well (K65W7H) at the southern extent of the plume has not contained
nitrate above the analytical method detection limit since it was installed in 2008.
• Of the two saprolite plume wells at the southern extent of the plume, K65W7G has been dry
since 2007. The slightly deeper well (K65W7F), contained nitrate at 33.6 mg/L in April 2009 but
was dry in October 2009. The nitrate concentration in this well has been on an increasing trend
since 2000.
• The saprolite plume delineation well (K65W7D), located in the southwest portion of the site,
contained 0.21mg/L in April 2009 and less than 0.1 mg/L in October 2009.
• Shallow monitoring well K65W7C was dry during both sampling events in 2009.
r-i
4 Conclusions
Based on the results of the semiannul groundwater sampling events and treatment system activities for
the 2009 reporting period, the following conclusions can be made at this time.
• The nitrate trend in the bedrock well near former Pond B continues on an increasing trend while the
nitrate concentrations in the two bedrock wells in the core of the plume (K65W7"K" and K65WTV')
remain fairly constant. Nitrate is below the 2L groundwater standard in the downgradient bedrock
well K65W7"H".
The nitrate trend in the saprolite wells (K65W6"A" and K65W6`B") near former Ponds A and B
show and overall downward trend, although there has been an increase in nitrate 'concentrations in
2008 and 2009. The saprolite plume is defined to the southeast in the middle of the plume by
K65W6"M" but not to northwest (K65W6"N"). The southern, downgradient end of the plume is
defined by K65W7"D" to the west. However, the two saprolite wells K65W7"F" and K65W7"G"
were either dry or above the 2L standard during this monitoring period.
5 Recommendations
Based on the information presented above, Duncklee & Dunham recommends the following.
• Continue to operate the groundwater treatment system in accordance with.the NPDES permit during
the time period of November 1 to March 31 as agreed to by the APS. However, the treatment system
may be operated between April 1 and October 31 as aquifer conditions allow.
• Continue semiannual groundwater plume monitoring.
DUNCKLEE & DUNHAM, P.C.

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Source Map: U.S. G.S. Statesville East 7.5-Minute Quadrangle.
Approximate Scale: Title:
DLJNCKLEE & DUNHAM, P.C. 1" = 2000' Site Location Map
(' ENVIRONMENTAL CONSULTANTS
511 KEISLER DRIVE - SUITE 102 Figure: Project:
+— CARY, NORTH CAROLINA 27511 1 Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina

Inches
0 1 2
0 0.25 0.5
Miles
Source of base map: Canonie Environmental Corrective Action Plan January 1994
JVLVV
v,
Drawing
Pigure
50200-3
3
Scale
Date
1 "= 0.25 miles
February 3, 2009
Title
Treatment System Discharge Line Outfall Map
roject Southern States Fertilizer Plant
Statesville, North Carolina

Table 1. Summary of 2009 Well and Water Level Gauging Data
Southern States, Statesville, North Carolina
Wells
Aquifer
Code
Date
TOC
Elevation
Total Well
Depth (ft)
Depth to
Water
ft bm
Ground Water
Elevation
ft MSL
K65W6A
Sap04/09/09
864.52
58
31.03
833.49
10/30/09
9.57*
854.95*
K65W6B
Sap
04/09/09
871.55
30
24.56
846.99
10/29/09
25.41
846.14
K65W6D
Sap
04/09/09
846.37
38
DRY
DRY
10/29/09
DRY
DRY
K65W6E
BR
04/09/09
864.89
133
34.51
830.38
10/30/09
31.69
833.20
K65W6M
Sap
04/09/09
837.84
50
42.06
795.78
10/29/09
39.20
798.64
K65W6N
Sap
04/09/09
845.30
50-
9.59
835.71
10/29/09
11.77
833.53
K65W7C
Sap
04/09/09
809.72
22
DRY
DRY
10/29/09
DRY
DRY
K65W7D
Sap
04/09/09
800.64
23
7.15
793.49
10/29/09
13.61
787.03
K65W7F
Sap
04/09/09
796.15
28
27.78
768.37
10/29/09
DRY
DRY
K65W7G
Sap
04/09/09
795.98
15
DRY
DRY
10/29/09
DRY
DRY
K65W7H
BR
04/09/09
796.07
112
16.41
779.66
10/29/09
18.23
777.84
K65W77
Sap
04/09/09
851.25
60
46.65
804.60
10/30/09
45.89
805.36
K65W7K
BR
04/09/09
852.30
121
47.23
805.07
10/30/09
47.79
804.51
K65W7L
BR
04/09/09
848.14
200
46.08
802.06
10/30/09
46.75
801.39
otes:
TOC=Top of Casing in feet Mean Sea Level (MSL)
ry= Well was dry during this sampling event
t bmp feet below measuringpoint
Aquifer Code - Represents aquifer being monitored at this well location (Sap. =Saprolite and BR=Bedrock)
11 measurements are in feet
* Water level was anomalously hiph in comparison to historical levels and not used to contour the ground water
uthern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Table 2. Summary of 2009 Ground Water Analytical and Field Parameter Results
Southern States, Statesville, North Carolina
Well # I Date
2L Standard
K65W6A
04/16/09
10/30/09
K65W6B
04/09/09
10/29/09
K65W6D
04/16/09
10/29/09
K65W6E
04/09/09
10/30/09
K65W6M
04/09/09
10/29/09
K65W6N
04/09/09
10/29/09
K65W7C
04/09/09
10/29/09
K65W7D
04/09/09
10/29/09
K65W7F
04/09/09
10/29/09
K65W7G
04/09/09
10/29/09
K65W7H
04/09/09
10/29/09
K65W7J
04/09/09
10/30/09
K65W7K
04/09/09
10/30/09
K65W7L
Ir 04/09/09
Laboratory Data
Ammonia
mg/L
Nitrate
mg/L
1.5
10
0.21
152
0.10
186
<0.10
40
<0.10
55.9
NS
NS
NS
NS
0.5
253
<0.10
44.4
<0.10
<0.10
<0.10
0.15
3.5
61.9
1.7
82.3
NS
NS
NS
NS
<0.10
0.21
<0.10
<0.10
<0.10
33.6
NS
NS
NS
NS
NS
NS
<0.10
0.26
<0.10
0.36
1.7
191
1.7
199
4.2
95.4
3.6
99.4
10.1
93.8
d indicates a 2L Standard exceedence
- not sampled - dry well
- low flow parameters not collected
11- milligrams per liter
'cm - milli-semins per centimeter
- milli -volts
Field Parameters
PH
Standard
units
Temp.
Celsius
Conductivity
mS/cm
ORP
my
DO
mg/L
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NS
NS
NS
NS
NS
4.22
18.81
0.99
430
4.0
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
7.01
18.6
>99.9
88
0.53
6.20
16.41
1.2
195
2.2
5.07
17.9
2.49
>999
7.81
5.37
16.7
0.115
288
5.95
9.98
16.8
17.2
-108
4.9
10.57
18.18
2.62
65
2.21
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NA
NA
NA
NA
NA
4.39
16.19
0.158
232
0.85
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
6.36
15.8
2.17
112
7.25
5.71
15.4
0.155
271
5.09
6.25
16.4
19.6
141
0.0
5.73
15.11
2.41
226
0.38
5.85
18.3
>99.9
100
0.54
7.00
15.3
1.78
250
1.93
6.27
16.6
50.2
117
0.68
6.23
14.97
1.75
1 191
1 0.23
uthern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Well! iezo ID:
�UNCKLEE (v57n1 7
Gl�` I�UNI CAM Sam le ID C(!, in) `7 0 6
Ground Water Sample Collection Record
Client.
SS- Statesville
Date: _4/9/09
Project No:
50200
Time: Start am/pm
Site Location:
Statesville, NC
Finish am/pm
Weather Conds:
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing)
WePiezometer Ela.
2g�th
Total Weil Depth (ft bmp)
��c.
Casing Material
e. Water Col. (a-b)
b. Water Table Depth
(ft bmp) hr `
d. Casing Diameter i/
f. Calculated Well Vol.
2"=617m11ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook q Page H
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >O.Ift/min
If no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
NIA
❑
❑
❑
Dissolved CO2 =
❑
❑
❑
Sulfide =
❑
❑
❑
Fe+2==_
❑
Cl
❑
NO3 =
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
comments: /
IDW: Place in drum or note other nethod of I ndl' .'
Signature ?G� J! / Date
Duncklee Dunham. P.C.
Envaonmentnl Consultanls
511 Koislat Dr. Suilo lag Phona 919.85B.9898
Ceuy, Nonh C8rolins 2751a Fax: [phone]U9

�--�m� DUNCIGL�E WeIllPiezo ID: �„ f
!!—•-� �. ��NH�� � Sam !e ID _ Uu I,'
Ground Water Sample Collection Record N5
Client:
SS- Statesville
Project No: 50200
Site Location: Statesville. NC
Weather Conds: Collector(s) GD JK
WATER LEVEL DATA: (measured from NIP at Top of Casing)
a. Total Well Depth (ft bmp) c. Casing Material
b. Water Table Depth (ft bmp) d. Casing Diameter
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used:
Date: 4/9/09
Time: Start am/pm
Finish am/pm
Well '�4 Piezometer ❑
a. Length of Water Col. (a-b)
f. Calculated Well Vol.
Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook k Page n
Time
L
ft bmp
Vol
Evac. 1
Flow
I/min
T` ©
pH
Spec.Cond
mS/cm)
Turbidity
(NTUs)
DO
ORP
Odor/Color
Other
e. Acceptance criteria pass/fail
Yes
❑
No
❑
N/A
❑
Has required volume been removed
Dissolved CO. =
Has required turbidity been reached
❑
❑
❑ Sulfide =
Have parameters stabilized
❑
❑
❑ Fe+2=
Has Low flow been maintained at >0.1ft/min
❑
❑
❑ NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Rate:
Sam le ID Container Type y No. of Containers Preservation Analysis Time
Comments :
IDW: Place in drum note other method of handling
Signature . Date
Duncklee Dunham, P.C.
Environmental Consultants
511 Keisler Or, Suite 102 Phone [phone]
Cary. North Carolnul 27518 Fox: 919.858.9M

DUNCLtI-EE uOr
WelUPiezolD:
8z D1LJ1*-T14AIV4 ISample ID O - Or/d
Ground Water Sample Collection Record
Client:
SS- Statesville
Date: _419/09
Project No:
50200
Time: Start am/pm
Site Location:
Statesville, NC
Finish am/pm
Weather Conds:
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing) .
Well Piezometer ❑
a. Total Well Depth (ft bmp)
30 r SQ
c. Casing Material /" t'L
e. Length of Water Col. (a-b)
b. Water Table Depth
(ft bmp) Z7.78
d. Casing Diameter
I. Calculated Well Vol.
2"=617ml/ft and 4"=2470m1/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters °6
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook 4 Page #
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >0.1ft/min
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
NIA
❑
❑
Cl
Dissolved CO2 =
Cl
❑
❑
Sulfide =
❑
❑
Cl
Fet2=
❑
❑
❑
NO3 =
Sam le ID Container Type No. of Ccmainers Preservation Analysis Time
Dut ck" Dwdt . P.C.
En' romma 7 Coic nartl5
511 Y.e 1s Dr, Sure 192
Cary. Naft camwl 27518
Pnm 919.ssa.9s9a
Fax: [phone]R99

DUNCKLEE Weul iezo : ) -5W
cam. l )uiNJ CAM ISample ID (p5 1,Jd7
Ground Water Sample Collection Record
Client:
SS- Statesville
Date: 4/9/09
Project No:
50200
Time: Start am/pm
Site Location:
Statesville. NC
Finish am/pm
Weather Conds:
/0
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well Piezometer ❑
a. Total Well Depth (ft bmp)
c.
Casing Material
e. Lengt of Water Col. (a-b)
b. Water Table Depth
(ft bmp) • b3 d.
Casing Diameter f
f. Calculated Well Vol.
2"=617ml/ft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (Q well volumes) or rate (1/min)
Maximum Allowable Turbidity NITUs
Stabilization of parameters 9.
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook N Page H
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >0.1 ft/min
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
N/A
❑
❑
❑
Dissolved CO2 =
❑
❑
❑
Sulfide =
❑
❑
❑
Fe+2=
❑
❑
❑
NO3=
Sample ID Container Type No. of Containers Preservation Analysis Time
comments:
i
IDW: Place in drum or ote oth r meat ling
9 Signature Date Q
Duncklee Dunham. P.C.
Environmental Consuhanls
511 Keisler M. Suite 102 Phone 919,858.9898
Cary. North Carolina 27518 Fax: [phone]

DUNCKLEE I
Well/Piezo ID: W . J!�7
cg-- D U NHAM Sam le ID 6 6 C "O
Ground Water Sample Collection Record
Client:
SS- Statesville
Date: _4/9109
Project No:
50200
Time: Start am/pm
Site Location:
Sta esville, NC
Finish J!510 am/pm
Weather Conds:
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing)
j?I/�—
Well Piezometer ❑
a. Total Well Depth (ft bmp)
c. Casing Material
e. Lengt of Water Col. (a-b)
b. Water Table Depth
1
(ft bmp) . 5 /
d. Casing Diameter
I. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook tr Page #
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at>0,1ft/min
If no or N/A - Explain below.
SAMPLE COLLECTION:
Comments:
Yes
No
N/A
❑
❑
❑
Dissolved CO. =
❑
❑
❑
Sulfide =
❑
❑
❑
Fe+2=
❑
❑
❑
NO3 =
Method:
Sample ID Container Type No, of Corrtamers Preservation Artalysis Time
Signature ! i ✓�� Date
©uncle : Dunrum, P.C.
LnV17
0
nmmaal c4muaants
511 Keisler Dr. Sale 102 Pr,ana 919.858.9898
Cory, hYrdh C-V,, rva 27518 Fax: [phone]

DLJNCKLEE I
ell/PiezoID: KO
S..q
��. c& DUN"AM I I Sample ID SW •-Df�D
Ground Dater Sample Collection Record
Client:
SS- Statesville
Date: _419/09
Project No:
50200
Time: Start am/pm
Site Location:
Statesville, NC
Finish i3c(L am/pm
Weather Conds:
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing)
Well -'E�P Piezometer ❑
a. Total Well Depth (It bmp)
50 c. Casing Material
e. Length of Water Col. (a-b)
b. Water Table Depth
(ft bmp) d. Casing Diameter �1 +r
f. Calculated Well Vol.
�
2'=617m1/ft and 4°=2470mi/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)__
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testinq Equipment Calibration Documentation Found in Field Notebook # Page a
Kw�"Ad-R
lwl�a:
_,
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >0.1ft/min
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
N/A
❑
❑
❑
Dissolved CO2 =
❑
❑
❑
Sulfide =
❑
❑
❑
Fe+2=
❑
❑
❑
NO3 =
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
comments: c -
S G4Gin ,M
IDW: Place in drum or note other method of handling
Signature
Duncklee Dunham. P.C.
Environmontal Consultants
511 K6sler Dr. Suite 102
Cary. North Carolina 27518
Date
Phone [phone]
rax: 919.658.9899

DUNCKLEEI
Well/Piezo ILL ' -s /'"7
Sr- DUNHAM sam leo k=65k)-7K
_
Ground Water Sample Collection Record
Client: SS- Statesville Date: _419109
Project No: 50200 Time: Startam/pm
Site Location: Statesville, NC Finish +&`;—ZLam/pm
Weather Conds: Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer ❑
a. Total Well Depth (ft bmp) c. Casing Material T e. L ng of Water Col. (a-b)
b. Water Table Depth (ft bmp) q /7 . 7-3� d. Casing Diameter —Q I. Calculated Well Vol.
2"=617mllft and 4"=2470ml/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >0.1 ft/min
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
N/A
❑
❑
❑
Dissolved CO. =
❑
❑
❑
Sulfide =
Cl
❑
❑
Fe+2= _ r
❑
❑
❑
NO3=
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
1
/1
V
� r
C_
Dunrkleo Dunham, P.C.
Erwiroornental Consultants
511 Keisler Or, Suite 102 Phone [phone]
Cary, Nonh Carolina 27518 Fax: 919,858.9899

I3UNC �L�� elUPiezo ID: &.S VJ —7L _
�r�. DUN�LAll� Sam le ID k vJ 7
Ground Water Sample Collection Record
Client: SS- Statesville Date: _419/09
Project No: 50200 Time: Start am/pm
Site Location: Statesville, NC Finish am!pm
Weather Conds: Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing) Well Piezometer ❑
a. Total Well Depth (ft bmp) c. Casing Material e. Length o Water Col. (a-b)
b. Water Table Depth (ft bmp) d. Casing Diameter — f. Calculated Well Vol.
2"=617mli t and 4"=2470m1/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (Vmin)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testino Eauioment Calibration Documentation Found in Field Notebook # Page #
Cond
IV
71��7�0�1������Y
e. Acceptance criteria pass/fail
Yes
No
N/A
❑
Has required volume been removed
❑
❑
Dissolved C% =
Has required turbidity been reached
❑
❑
❑ Sulfide =
Have parameters stabilized
❑
❑
❑ Fe+2=
Has Low flow been maintained at >0.1 fl/min
❑
❑
❑ NO3 =
if no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Rate-
Sample ID Container Type No. of Containers Preservation Analysis Time
Comments :
IDW: Place in d r note other method of handling
f 0
Signature �, l� Date
r
Ouncklee Dunham. P.C.
Environmental Consultants
511 Keislef Or. Suite let Phone 919.s5a.9a98
Cary. North Carolina 27518 Fax: [phone]

D UNCI{.LEE Well/Piezo ID:
(I� .9,- DUNHAM
Sam le IDW� �U
Ground Water Sample Collection Record
Client:
SS- Statesville
Date: _4/9109�"
Startl
Project No:
50200
Time:
am/0
Site Location:
Statesville, NC
Finish z�am/pm
Weather Conds:
Collector(s) GD JK
WATER LEVEL DATA: (measured from MP at Top of Casing)L65-
Well Piezometer ❑
a. Total Well Depth (it bmp)
c. Casing Material
e.'C gth of Water Col. (a-b)
b. Water Table Depth
s
(ft bmp) d. Casing Diameter �_-
f. Calculated Well Vol.
2"=617ml/ft and 4"=2470m1/ft
WELL PURGING DATA
a. Purge Method/Equipment Low flow with Horiba
b. Acceptance Criteria defined (from workplan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of parameters %
c. Field Testing Equipment Used: Make Model
rl Pialri T—t inn Fniiinment Calihration Dncumentation Found in Field Notebook N Page N
Serial Number
e. Acceptance criteria passifail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has Low flow been maintained at >O.1fVmin
If no or N/A - Explain below.
SAMPLE COLLECTION:
Method:
Yes
No
N/A
❑
❑
❑
Dissolved CO. =
❑
❑
❑
Sulfide = ,
❑
❑
❑
Fe+2=
Cl
❑
❑
NO3 =
Sample ID
Container T
4 No. of Containers
Preservation
Anal 's
Time
1w 777
M
Comments: r i v C1 1 + v •
- -
t �, ��
IDW: Place in dtul r note other method of handling
Signature Date ®�
D m6ee Ounnan, P.C.
Lrv4on¢1leraai Com�s
511 Kmo T 01, S.I. 102 PAO— 919.858,9898
Cary, NmY.1 Cardin 27519 Fax: [phone]

�-•y DUNCKL Well/Piezol : �S �J6 <
& DUNHA4 Isa.pl. ID ' ' - /VC) 7
Ground Water Sample Collection Record
Client: SGJ�`��� Date: ly `
Project No: bU��� 71me: Start am/pm
Site Location: Finish c) V S am/pm
Weather Conditions: Collector(s)
WATER LEVEL DATA: (measured from MP at Top of Casing)n Well Q Piezometer ❑
a. Total Well Depth (it bmp) _ C. Casing Material I V L e. Length of Water Col. (a-b)
b. Water Table Depth (it bmp) t�_ d. Casing Diameter Q. f. Calculated Well Vol
WELL PURGING DATA
a. Purge Method/Equipment ��✓i��
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (Umin)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters /-v %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook f1 Page k
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
91
❑
❑
Dissolved C%=
^�
Has required turbidity been reached
❑
❑
Er
Sulfide =
/
Have parameters stabilized
C?'
❑
❑
Fe+2=
0• 0
Has low flow been maintained at >0.1ft/min
a
❑
❑
NO3 =
/✓yi
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:
Lytr
-
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
jti 6� w6 - low
L Sn,�
I
,/ Af
1/0 vs-
Sc
Comments:
IDW: Place in drum or note other method of handling
Signature Date
Dum6leo Dunham. P.C.
EnvltonmonW Consultants
511 Keislor Dr. Sulto 102
Cary. North Cmolina 27518
Ph.- 919.858.9898
Fax: [phone]

DUNCKLE
& DUNHA
4
Ground Water Sample Collection Record
SS S tz; t/tom
Project No: SU Lvri
Site Location:
Weather Conditions: O�r..�- Collector(s) Cam..
ATER LEVEL DATA: (measured from MP at Top of Casing)
Total Well Depth (ft bmp) 4Z_ c. Casing Material PU L
Water Table Depth (ft bmp) ���• d. Casing Diameter
Well/Piezo ID: KGSZ-, 7X.
[Sample ID '�� 7K- -/� i
Date: �U ' U 17
Time: Start y;ti?yam/pm
Finish am/pm
Well � Piezometer ❑
e. Length of Water Col. (a-b)
f. Calculated Well Vol.
WELL PURGING DATA 1
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan) �✓�
Purge Volume (@ well volumes) or rate (1/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters to %
c. Field Testing Equipment Used: ��11 Make Model Serial Number
A.t, I,-I.22
d. Field Testing Equipment Calibration Documentation Found in Field Notebook N Page N
Time
ft bmp
VolWL
Evac. I
ow
1/min
T°
pH
Spec.Cond
Ms/cm)
Turbidity
(NTUs)
DO
ORP
Odor/Color
Other
ba
o7-
1/7,
�1 ►
k, l�
6�
fl `�
Z •
2
7Yo
%r
you
VZ
V
2,3
tiS
tL
D��
yob'
l
as�
A
q3,
D
b6
J r 7-
-1�.
/�
<
r
o Gov
y71Y
e. Acceptance criteria pass/fail
Yes,
No
N/A
Has required volume been removed
❑
❑
/
Dissolved CO2
Has required turbidity been reached
❑
❑
e-1
Sulfide =
Have parameters stabilized
❑
❑
Fe+2= O • "L
Has low flow been maintained at >0. f Wmin
❑
❑
M03 =
If no or NIA - Explain below.
SAMPLE COLLECTION:
Method:
Sam le ID
ContainerType
No. of Containers
Preservation
Analysis
Time
k%
/t0l
-III t-IW .
drum or note other method of
Signature
Date I -A / U i
r �
lSmrMS V—tr.ua. P.C.
Hre�enwl Cecs9tards
511 Keisb' or, SU163 102 Ptt a 919.ass.sm
Cary, N.-MQa+ %M1 27506 Fa 919.858.9999

�--� DUN'CKLE
-� & DUNHA
Ground 'Water Sample Collection Record
We]YPiezo :
Sam le ID
Client: Date: (0- 30
Project No: Time: Start am/pm
Site Location: Finish OF, 5Z) am/pm
Weather Conditions: 17v��t✓r Collectors) G�
WATER LEVEL DATA: (measured from MP at Top of Casing) Well � Piezometer ❑
a. Total Well Depth (h bmp) 7-- C. Casing Material OYZ e. Length of Water Col. (a-b)
b. Water Table Depth (it bmp) `/L 7s d. Casing Diameter f. Calculated Well Vol.
2"=617mUft and 4'=2470ml/h
WELL PURGING DATA
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ _ well volumes) or rate_ (Urnin)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters %
o, Field Testing Equipment Used: Make Model Serial Number
Fjyr,,1,,_ L—vL
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Yes No
N/A
Has required volume been removed
❑
Dissolved CO2 = yf(
Has required turbidity been reached
❑ El+�'
,❑—, /
Sulfide = /�
Have parameters stabilized
❑
❑
Fe+2= 0
Has low flow been maintained at >0.lft/min
❑
❑
NO3 = A-11
If no or N/A - Explain below.
SAMPLE COLLECTION: Method: r)"--, : ✓
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
� .S-(„i7 L -!vp i
r Z srti. (. (J/c�vr
✓
/Vi`l
U
ILI
Comments:
IDW: Place in drum or note other method of handling
%O
Signature\ !/' / Date 1
Dur-Mee Dunham, P,C.
Environmental Consultants
511 Keisler Dr. Suite 102 Phone [phone]
Cary. North Carolina 27518 Fax: [phone]

DUNCKLE-El
�--� & DUNHA
Ground Water Sample Collection Record
W ell Piezo ID: 1C G 5—t, 'TT
Sample ID k .
Client:
i 5 Sfi.�l-�, II E
Date: /0 —3 — d P
Project No:
S'O 2✓"
Time: Start 0/ 40 am/pm
Site Location:
3tzitn,.Y1���C
Finish 10Vc: am/pm
Weather Conditions:
T
Collector(s)
w
/
Ela.
WATER LEVEL DATA: (measured
from MP at Top of Casing)
Well C� Piezometer
Total Well Depth (ft bmp)
c.
Casing Material
e. Length of Water Col. (a-b)
b. Water Table Depth
(ft bmp) r 'Ir!q d.
Casing Diameter
f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment /Iv�ltanr�
b. Acceptance Criteria Defined (from work plan) L. /D�
Purge Volume (@ -�_ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook 9 Page lt.
ISIi]u1:��t1lLttt111i��
• •
•®" '
• .. ..
•
e. Acceptance criteria pass/fail
Yes
No
A
Has required volume been removed
ElY
Dissolved CO2 = yLS
Has required turbidity been reaetied
❑
❑
El-
Sulfide =
Have parameters stabilized
8'
❑
❑
Fe+2= Q. Z
Has low flow been maintained at >0.tf ImEn
��
0
❑
NO3 =
If no or NIA - Explain betow.
s
SAMPLE COLLECTION: Method: C1-34 01�
Rate -
Sample ID
Container Type
No. of Contaeiem
Preservation
Ana is
Time
1
�v
S,6
L
Ccmmems:
Place in dtutn or note other
Signature�� J s^� ✓ C&Zte �c%� Op
ire: 000sA. P.G.
Emmxr enmT Caw& s
st t ftis N M. sate 1e2 P[mna 913,658,3ft39
Guy, Nu[tR, G3an?rcl �7576 F,i!c; 919.65e.9�J

DUNCKLE
& DUN]AA
4
oject No:
:e Location:
eather Conditions:
Ground Water Sample Collection Record
fv�o
Collector(s) a C—
ATER LEVEL DATA: (measured from MP at Top of Casing)
Total Well Depth (ft bmp) /� c. Casing Material
Water Table Depth (it bmp) /, %% d. Casing Diameter Z
WELL PURGING DATA �!
a. Purge Method/'Equipment l"�r�• 1��+��c?��
Well/Piezo ID: . `96) 41
Sam le 1D � C c� hr
Date: /U - %d -.O/'
Time: Start am/pm
Finish am/pm
Well.M Piezometer ❑
e. Length of Water Col. (a-b)
f. Calculated Well Vol.
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters 440
c. Field Testing Equipment Used: Makq od 1 Serial Number
�.� he-- .
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #
e. Acceptance criteria pass/fail
Has been
Yes No
�� ❑
N/A
❑--.
Dissolved CO2
required volume removed
Has required turbidity been reached
❑ ❑
❑
= ,st/,+it
Sulfide = L
Have parameters stabilized
❑
❑
Fe+2= 0. 0
Has low flow been maintained at >0.1 ft/min
❑
❑
NO3 = X-
If no or N/A - Explain below.
SAMPLE COLLECTION: Method:elz,-- f61-
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
ASS&- N V at
(2s1 L
tD YI1/N
/6Qa
1,
Al
/
Comments :
IDW: Place in drum or note other method of
Signature
Date �d 2
Dumcklee Dunham. P.C.
Enuonmenlal Consultants
5n Heisler Dr. suite 102 Phone [phone]
Cary. North Carolina 2751 B Rix: 919.858.9899

Well/Piezo ID:
DUNCKLE 146Sf.,�6
& DUNHA Sample ID it65�6 4 -/oz r
Ground Water Sample Collection Record Id
Client: SS r4le'l1c. Date: ly ' 3o - U 1
Project No: Sa?v Time: Start am/pm
Site Location: Finish amipm
Weather Conditions: Collector(s) CA —
WATER LEVEL DATA: (measured from MP at Top of Casing) Well © Piezometer ❑
a. Total Well Depth (it bmp) S—d c. Casing Material e. Length of Water Col. (a-b)
b. Water Table Depth (ft bmp) d. Casing Diameter Z f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters %
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook N Page P
e. Acceptance criteria pass/fail
Has required volume been removed
Has required turbidity been reached
Have parameters stabilized
Has low flow been maintained at>0.IfUmin
If no or N/A - Explain below,
SAMPLE COLLECTION:
Method:
Dot —
❑s ® No N`Q
Dissolved CO2 = .�
❑ ® d Sulfide = [_
❑ ® Fe+2= o. o
❑ ® NO3= r�
Sample ID
Contai_neer Type
No. of Containers
Preservation
Ana6 a
Time
6 sue, .
R
,/
Abn
v 3 r
Ucnnmenis :
IDW: Place in d�ru�m4 or note other method of handling
Signature -IAl
Cnx�7co Imo, n.c.
Em+aatrn±Ns! C�su9rdls
st r t�eR4u f1v, h`rJe ro.2 r^{mna 91°6.859,fl6'38
Guy, P#au? GasuKal Ea�cB Fax: 9I9.853.3843

lc>
DUN+CKL
& D1JNH:AjE7
Ground Water Sample Collection Record
WelUPiezo ! : G SW 7-D
Sam le ID It- 1, T U 7 l7 - / UO'(
Client: s s s���r< ��P Date: I n L` 4'
Project No: Time: Start J amlpm
Site Location: Finish amfpm
Weather Conditions: f Collector(s)
WATER LEVEL DATA: (measured from MP at Tap of teasing) Well � Piezometer ❑
a. Total Well Depth (fl bmp) 7 � c. Casing Material VL e. Length of Water Col. (a-b)
b. Water Table Depth (H bmp) (�7. 6 ( d. Casing Diameter �_ f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment
J
b. Acceptance Criteria Defined (from work plan) '
Purge Volume (@ well volumes) or rate (Ilmin) �tt ��p1nyD
Maximum Allowable Turbidity NTUs
Stabilization of Parameters ;n %
c. Field Testing Equipment Used: /J/ M�Jse vModeelZ Serial Number
d�f.�
d. Field Testing Equipment Calibration Documentation Found in Field Notebook fl Page H.
e. Acceptance criteria pass/fail
Ye No
NIA
Has required volume been removed
1❑
❑
Dissolved COZ = .v"a
Has required turbidity been reached
❑ ❑
Sulfide = L
Have parameters stabilized
❑
❑
Fe+2= f{ P1
Has low flow been maintained at>0.Ift/min
d ❑
❑
NO3 = kll;
If no or N/A - Explain below.
SAMPLE COLLECTION: Method: CG F/, °-
Rate:
Sample ID
Container T e
No. of Containers
Preservation
Analysis
Time
_ \
�R
oC
I L7 hn CSt
.ZSG4
i41�
t'�
i
Comments:
IDW: Place in drum or note (other method of h%andling
Signature C�'l-tit / i l Date
Duncklee Dunham. RC.
Emironmen411 Consutianis
511 Keish" Dr. Sul' let
Cary. North Cazol"ure 27518
PhMo 919.856.9898
Ftur. 919.858.9699

jr:�o =DUNCKLE
Well/Piezo ID: &4 S W (3
Sample ID 6 s'fw
Ground Water Sample Collection Record
Client: Sl 5�ir �f� �t Date: /I) r/
Project No: Time: Start r/10 am/pm
Site Location: S f r.� r�, Al- _ Finish am/pm
Weather Conditions: S,n^—t Collector(s) �--
WATER LEVEL DATA: (measured from MP at Top of Casing) �n yL Well p Piezometer Ela. Total Well Depth (ft bmp) o c. Casing Material U e. Length of Water Col. (a-b)
r.
b. Water Table Depth (ft bmp) z/ d. Casing Diameter _ f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters 96
c. Field Testing Equipment Used: Make Mode Serial Number
#�,/, ., L
d. Field Testing Equipment Calibration Documentation Found in Field Notebook N Page #
7
'•
��M
• • •10200,
11 00!•
••• • •
•
e. Acceptance criteria pass/fail
Yes
No
N/A
Has required volume been removed
0
❑
❑
Dissolved COZ
Has required turbidity been reached
❑/
❑
Sulfide =
Have parameters stabilized
❑
❑
Fe+2=
Has low flow been maintained at >0.Ift/min
❑
Cl
NO3 = /u,A
If no or N/A - Explain below.
SAMPLE COLLECTION: Method: L✓ f"
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
I
/✓� t{V flir
Comments :
IDW: Place in drum or note other method of handling
Signature
i
Date /y/ %41
Duncklee Dunham, P.C.
Emua[unental Can U-ts
511 Kemfer Dr, Swe 102 Pne 919.858.9898
Cary. N(4h CaokM 27516 Faz: 919.856.9699

DUNCKLE
!-� &DUNHAM
Ground Water Sample Collection Record
1 e1U iezo ID:
Sam le ll) tiv 'b-
Client: S S S�ky�!/C` Date: 10 — a9 ' Q
Project No: 571 " Time: Start /0 id' am/pm
Site Location: j },.�w ti r +`rz Finish i l:�;7 " am/pm
Weather Conditions: y /ta`j CoIDector(s) �/�--�-
WATER LEVEL DATA: (measured from MP at Top of Casing) ta Well d Piezometer ❑
a. Total Well Depth (ft bmp) S— c. Casing Material e. Length of Water Col. (a-b)
b. Water Table Depth (fit bmp) _ 9 2 Z) d. Casing Diameter f. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (i/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters T%
c. Field Testing Equipment Used:
2.auv Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook #/ Page p
--
/
HIM
e. Acceptance criteria pass/fail
Yes No
a ❑
N/A
❑c
Dissolved COz dvA
Has required volume been removed
=
Has required turbidity been reached
❑
L
Sulfide =
Have parameters stabilized
�❑[
CJ ❑
❑
Fe+2= O
Has low flow been maintained at >0.1 ft/min
C1 ❑
❑
NO3 =
If no or N/A - Explain below.
SAMPLE COLLECTION: Method: LJW fl t:w
Rate:
Sample ID
Container Type
No. of Containers
Preservation
Analysis
Time
(41d4M _ too s
/ti �zyti-t
1
rI Su
/7'L
Comments:
IDW: Place in drum or note other method of handling
Signature
Date
Duncklee Dunham. P.C.
Environmontal Consultants
511 KeWer Dr, Suite 102 Phone 919.858.989B
Cary, North Carolina 27518 Fax: [phone]

DUNCKLE
—!° & DUNHA
Ground Water Sample Collection Record
We I/Piezo ID: K&s-v 7H loU7
Sam le ID
Client: 5S 5 %> as �Q(," Date: /0 '-Zl- vs
Project No: Time: Start 0�" am/pm
Site Location: Finish Zi �%� am/pm
Weather Conditions: S.) nA "J Collector(s) c� i
ATER LEVEL DATA: (measured from MP at Top of Casing) Well 2'-'] Piezometer ❑
Total Well Depth (ft bmp) 11-L c. Casing Material PVL e. Length of Water Col. (a-b)
Water Table Depth (ft bmp) 1910�-1 d. Casing Diameter Z I. Calculated Well Vol.
WELL PURGING DATA
a. Purge Method/Equipment
b. Acceptance Criteria Defined (from work plan)
Purge Volume (@ well volumes) or rate (I/min)
Maximum Allowable Turbidity NTUs
Stabilization of Parameters -%
c. Field Testing Equipment Used: Make Model Serial Number
d. Field Testing Equipment Calibration Documentation Found in Field Notebook # Page #.
rililtll�t3tl'sUl����
. -
� .
• •
�
• .. ..
•
e. Acceptance criteria pass/fail
Yea/
No
NIA
AIA
Has required volume been removed
n
❑
❑
Dissolved CO2 =
Has required turbidity been reached
❑
❑
pr
Sulfide =
Have parameters stabilized
❑
❑
Fer2=
Has low flow been maintained at >0.Ift/min
❑
❑
NO3
If no or NIA - Explain below.
SAM PLE COLLECTION: Method:
�� V-
q -
Sam le ID
Container Type
No, of Containers
Ptesemtton
Alta sis
Time
comments:
IDW: Place in drum or note other method of handling
Signature Date
nsm:ka:e 4unhsm, P.G
Cnvilvnmental �w+5u4anly
911 KetSle 0', ajAe IQ RIM% 919,tt59.2tLH
Quy, Nutth Ccuckpa 2t al t1 Fox: 919,Ci49 �849

aceAnaljftal
www.pscetabs.com
April 16, 2009
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2009. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely, n
►t'U
Renee Spencer
[e-mail]
Project Manager
Enclosures
cc: Mr. Tom Dunham, Duncklee & Dunham
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
y.1.- -ac•.
[phone]
Page 1 of 15

rlacmnalytical
www.paceJabs.com
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Charlotte Certification IDs
West Virginia Certification #: 357
Virginia Certification #: 00213
Tennessee Certification #: 04010
South Carolina Drinking Water Cert. #: 990060003
South Carolina Certification #: 990060001
Pennsylvania Certification #: 68-00784
Connecticut Certification* PH-0104
Asheville Certification IDs
West Virginia Certification #: 356
Virginia Certification #: 00072
Connecticut Certification #: PH-0106
Florida/NELAP Certification #: E87648
Tennessee Certification #: 2980
South Carolina Certification #: 99030001
South Carolina Bioassay Certification #: 99030002
Eden Certification IDs
North Carolina Wastewater Certification #: 633
Virginia Drinking Water Certification #: 00424
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Field Services Certification #: 5342
North Carolina Drinking Water Certification #: 37706
New Jersey Certification #: NC012
Louisiana/LELAP Certification #: 04034
Kentucky UST Certification #: 84
Florida/NELAP Certification M E87627
North Carolina Wastewater Certification #: 12
Pennsylvania Certification #: 68-03578
North Carolina Wastewater Certification #: 40
North Carolina Drinking Water Certification #: 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification #: NC011
Massachusetts Certification #: M-NC030
Louisiana/LELAP Certification #: 03095
North Carolina Drinking Water Certification #: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 15

aceAnalytical
www.pacelabs.com
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: KSSW7H-0409 Lab ID: 9241921001 Collected: 04/09/09 10:04 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/09 10:25 7764-41-7
353.2 Nitrogen, NO2IN03 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.26 mg/L 0.10 1 04/11/09 08:38
Date: 04/16/2009 02:50 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc,.
Qual
Page 3 of 15

aceAnal. cal
wwwpac ebbs c m
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7F-0409 Lab ID: 9241921002 Collected: 04/09/09 10:45 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/09 10:27 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 33.6 mg/L, 2.0 20 04/11/09 09:21
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
r ehel
Page 4 of 15

® Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr.
www.pacelabs.com Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6N-0409 Lab ID: 9241921003 Collected: 04/09/09 13:55 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia 3.5 mg/L 0.10 1 04/13/09 10:27 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 61.9 mg/L 2.0 20 04/11/09 09:23
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
_71e% .
Page 5 of 15

ace,AnaIXical
j/ www.pasefabs.cam
I
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W613-0409 Lab ID: 9241921004 Collected: 04/09/09 14:20 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/09 10:28 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 40.0 mg/L 2.0 20 04/11/09 09:24
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
'VT1eO�C'.
Page 6 of 15

®
Pace Analytical Services, Inc.
Analytical
2225 Riverside Dr.
www.pacelabs.Cam
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7L-0409 Lab ID: 9241921005 Collected: 04/09/09 17:22 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 10.1 mg/L 1.0 10 04/13/09 11:36 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 93.8 mg/L 2.0 20 04/11/09 09:30
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
a : Ct1.y1
Page 7 of 15

aceAnalytical
www.pacWabs.com
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E-0409 Lab ID: 9241921006 Collected: 04/09/09 15:10 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.50 mg/L 0.10 1 04/13/09 10:34 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 253 mg/L 5.0 50 04/11/09 11:07
Date: 04/16/2009 02:50 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
helact.
Page 8 of 15

aceAnaly kal
www..pacelabs.com
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6M-0409 Lab ID: 9241921007 Collected: 04/09/09 15:46 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/13/09 10:36 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate ND mg/L 0.10 1 04/11/09 08:55
Date: 04/16/2009 02:50 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 15

WWPM*b&-M
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K-0409 Lab ID: 9241921008 Collected: 04/09/09 16:52 Received: 04110/09 13:56 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 4.2 mg/L 0.10 1 04/13/09 10:37 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 95.4 mg/L 2.0 20 04/11/09 09:27
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Aida
Page 10 of 15

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200 419
Pace Project No.: 9241921
Sample: K65W7J-0409 Lab ID: 9241921009 Collected: 04/09/09 17:44 Received: 04/10/09 13:56 Matrix: Water
Parameters Results Units ReportLimit , DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia 1.7 mg/L 0.10 1 04/13/09 10:38 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 191 mg/L 2.0 20 04/11/09 09:36
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 15

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,�A'*`ce Analytic2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
QC Batch: WETA/4847
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 9241921005, 9241921006, 9241921007, 9241921008, 9241921009
METHOD BLANK: 262428
Matrix: Water
Associated Lab Samples: 9241921005, 9241921006, 9241921007, 9241921008, 9241921009
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 04/13/09 10:29
LABORATORY CONTROL SAMPLE:
262429
Spike LCS LCS
% Rec
Parameter
Units
Cone. Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 5.2 104
90-110
MATRIX SPIKE SAMPLE:
262430
9241921005 Spike MS
MS
% Rec
Parameter
Units
Result Cone. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
10.1 5 15.3
103
90-110
MATRIX SPIKE SAMPLE:
262432
9241446002 Spike MS
MS
% Rec
Parameter
Units
Result Cone. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
10 5 14.5
91
90-110
SAMPLE DUPLICATE: 262431
9241921006 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
0.50 0.46
6
SAMPLE DUPLICATE: 262433
9241457001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND ND
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 15 .

aceAnalytical
www.pacelabs,cam
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/4842 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9241921001, 9241921002, 9241921003, 9241921004, 9241921005, 9241921006, 9241921007, 9241921008,
9241921009
METHOD BLANK: 262274 Matrix: Water
Associated Lab Samples: 9241921001, 9241921002, 9241921003, 9241921004, 9241921005, 9241921006, 9241921007, 9241921008,
9241921009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.10 04/11/09 08:34
LABORATORY CONTROL SAMPLE: 262275
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.1 103 90-110
MATRIX SPIKE SAMPLE:
262276
9241921001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
..Nitrogen, Nitrate
mg/L
0.26
5
5.2
98
90-110
MATRIX SPIKE SAMPLE:
262278
9241921008
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
95.4
5
100
97
90-110
SAMPLE DUPLICATE: 262277
9241921002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
i
mg/L
33.6
33.1
2
SAMPLE DUPLICATE: 262279
9241921005
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
93.8
94.1
.3
Date: 04/16/2009 02:50 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
ascn.�
�{MlY3
Page 13 of 15

Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Ana"cal
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www,pwOabs.wm
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
QUALITY CONTROL
DATA
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
QC Batch: WETA/4846
Analysis Method:
EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description:
350.1 Ammonia
Associated Lab Samples: 9241921001, 9241921002, 9241921003, 9241921004
METHOD BLANK: 262422
Matrix: Water
Associated Lab Samples: 9241921001, 9241921002, 9241921003, 9241921004
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 04/13/09 10:02
LABORATORY CONTROL SAMPLE:
262423
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 5.3
107 90-110
MATRIX SPIKE SAMPLE:
262424
9241345002 Spike
MS MS
%Rec l
Parameter
Units
Result Cone.
Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
9.7
5 15.0 107
90-110
MATRIX SPIKE SAMPLE:
262426
9241378001 Spike
MS MS
% Rec
Parameter
Units
Result Cone.
Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND
5 5.6 111
90-110 MO
SAMPLE DUPLICATE: 262425
9241376001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Nitrogen, Ammonia
mg/L
4.6
4.6 .5
SAMPLE DUPLICATE: 262427
9241410001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Nitrogen, Ammonia
mg/L
138
143 4
Date: 04/16/2009 02:50 PM REPORT OF LABORATORY ANALYSIS Page 14 of 15
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
r•CNR�

aceAnalytical
ww.pawlabs.com
QUALIFIERS
Project: SS STATESVILLE FERT 50200 4/9
Pace Project No.: 9241921
10=IJI:11111101 :69
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
MO Matrix spike recovery was outside laboratory control limits.
Date: 04/16/2009 02:50 PM
0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Me '
Page 15 of 15

: ceAnal ical'
1HYI.p86a18w.Cam
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
of
Section A Section B Section C
Required Client Information: Required Project Information: Invoke Information:
E
Company: Report To: Attention:
t 1305693
Address: Uopy To: L Company Name: REGULATORY AGENCYz
NPDES GROUND WATER I" DRINKING WATER
r UST r RCRA ( OTHER
Email To��Adder'
Q
Purchase Order No.:
Pace quote
RZ:
Phone: `
Project Name: �Y
JJ V .��Q/
Pct
M.
Site Locetlon
STATE:
Requested Due Date/TAT:�rj
Project Number: 0,2.00
Ple 41.
Regtrested
Analysis
Fittdrdd
(YIN)
Section D Matrix Codes
Required talent hdvmetkn MATRIX /CODE
$
o
COLLECTED
Preservatives
..
DrIWng Water DW
ii
6
zz
Water WY
Waste Water WIN
Product P
0
COMPOSITE
START
COM
F
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SoiySolld SL
SAMPLE ID wpa OL
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WP
(A-Z, 0-9 I,-) Air AR
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Sample IDS MUST BE UNIQUE Tissue TS
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t
U
Other OT
X
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DATE
TIME
DATE
TIME
#
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1
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kg5wU -- 041A
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k4W7K - OHM
11651-
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[
9
10
11
12
ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIATION
DATE
TIME
ACCEPTED'BY I AFFILIATION
DATE
TIM�E,q
SAMPLE CONDITIONS
'
)
en
LCQd (lam-
3'•
g
�,�
SAMPLER NAME AND SIGNATURE
ORIGINAL
a _
_
PRINT Name of SAMPLER: Sa sdIA t r,
E
SIGNATURE of SAMPLER: a
DATE Signed
D U
IEm-
t�J
to
(MMIDDIYY):
v,
F. ^e rw nm- a�Uiri Fuws NET su say paymentterms and agreeing to late chargesof 1.5% permamh forAftin*Icea not pall wifhin'5D days. r F-ALL-Q-020 .0 `rMay-2007
� � �■■� r�'i�Ii �s m

aceAnal ical
www.pacelabs.com
April 21, 2009
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on April 17, 2009. The
results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
`� 'L
Renee Spencer
[e-mail]
Project Manager
Enclosures
cc: Mr. Tom Dunham, Duncklee & Dunham
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
me -
[phone]
Page 1 of 7

acoAnaIXical
www.pacelabs.wm
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
Charlotte Certification IDs
West Virginia Certification #: 357
Virginia Certification #: 00213
Tennessee Certification #: 04010
South Carolina Drinking Water Cert. #: 990060003
South Carolina Certification #: 990060001
Pennsylvania Certification #: 68-00784
Connecticut Certification* PH-0104
Asheville Certification IDs
West Virginia Certification #: 356
Virginia Certification #: 00072
Connecticut Certification #: PH-0106
Florida/NELAP Certification #: E87648
Tennessee Certification #: 2980
South Carolina Certification #: 99030001
South Carolina Bioassay Certification #: 99030002
Eden Certification IDs
North Carolina Wastewater Certification * 633
Virginia Drinking Water Certification #: 00424
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Field Services Certification #: 5342
North Carolina Drinking Water Certification #: 37706
New Jersey Certification* NC012
Louisiana/LELAP Certification #: 04034
Kentucky UST Certification #: 84
Florida/NELAP Certification #: E87627
North Carolina Wastewater Certification #: 12
Pennsylvania Certification #: 68-03578
North Carolina Wastewater Certification #: 40
North Carolina Drinking Water Certification #: 37712
North Carolina Bioassay Certification #: 9
New Jersey Certification #: NC011
Massachusetts Certification #: M-NC030
Louisiana/LELAP Certification #: 03095
North Carolina Drinking Water Certification #: 37738
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
nela&
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 7
0
u

aceAnalXical
www.pacelabs.cnm
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6A-0409 Lab ID: 9242405001 Collected: 04/16/09 13:02 Received: 04/17/09 14:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.21 mg/L 0.10 1 04/19/09 15:57 7764-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 152 mg/L 0.10 1 04/18/09 09:51
Date: 04/21/2009 12:41 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
%lad
Page 3 of 7

��. aceAnalyticlle
www.pacelabs.com
t'
i
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242406
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7D-0409 Lab ID: 9242405002 Collected: 04/16/09 13:55 Received: 04/17/09 14:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia ND mg/L 0.10 1 04/19/09 15:57 7764-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.21 mg/L 0.10 1 04/18/09 09:09
Date: 04/21/2009 12:41 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
n.el .
Page 4 of 7
I
A
s

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,�acieAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
QC Batch: WETA/4885
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9242405001, 9242405002
METHOD BLANK: 265440
Matrix: Water
Associated Lab Samples: 9242405001, 9242405002
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.10 04/18/09 08:49
LABORATORY CONTROL SAMPLE:
265441
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
5 5.2 103
90-110
MATRIX SPIKE SAMPLE:
265442
9242396010 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.63 5 5.5
98
90-110
MATRIX SPIKE SAMPLE:
265444
9242396009 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND 5 4.9
98
90-110
SAMPLE DUPLICATE: 265443
9242405001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Nitrate
mg/L
152 150
2
SAMPLE DUPLICATE: 265445
9242396003 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Nitrate
mg/L
0.34 0.34
1
Date: 04/21/2009 12:41 PM
REPORT OF LABORATORY ANALYSIS
Page 5 of 7
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
•g.
nelac°°

aceAnalXical
www.pacelabs.com
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
QC Batch: WETA/4888
QC Batch Method: EPA 350.1
Associated Lab Samples: 9242405001, 9242405002
METHOD BLANK: 265548
Associated Lab Samples: 9242405001, 9242405002
Parameter Units
Nitrogen, Ammonia mg/L
LABORATORY CONTROL SAMPLE: 265549
Parameter Units
Nitrogen, Ammonia mg/L
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 04119/0915:45
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike LCS LCS % Rec
Cone. Result % Rec Limits Qualifiers
5 5.1 102 90-110
MATRIX SPIKE SAMPLE: 265550
9241926002 Spike MS MS % Rec
Parameter Units Result Cone. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5.1 5 19.6 290 90-110 MO
MATRIX SPIKE SAMPLE:
265552
9241678004
Spike MS MS % Rec
Parameter
Units
Result
Cone. Result % Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
2.8
5 7.5 95 90-110
SAMPLE DUPLICATE: 265551
9241927002
Dup
Parameter
Units
Result
Result RPD Qualifiers
Nitrogen, Ammonia
mg/L
4.0
4.0 2
SAMPLE DUPLICATE: 265553
9241953001 Dup
Parameter Units Result Result RPD Qualifiers
Nitrogen, Ammonia mg/L ND ND
Date: 04/21/2009 12:41 PM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
.elac
Page 6 of 7

aceAnalytical
www.pacelabs.com
QUALIFIERS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 9242405
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
MO Matrix spike recovery was outside laboratory control limits.
Date: 04/21/2009 12:41 PM REPORT OF LABORATORY ANALYSIS Page 7 of 7
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
s�.
t1eh

;2ceAnal ical°
w".oacelabs eom
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C Page: of
Required Client Information: Required Protect Information: Invoice Information•
Company: Report To: � Attention:
1305694
Address: py To: L Company Name:
REGULATORY AGENCY
Address:
j� NPDES GROUNDWATER (— DRINIdNG WATER
UST r RCRA (- OTHER
5rtail To: \ Purchase
Order No.:
Pace Ouote
—� lrL,
Reference: A
Phone: (
Fax: Project
Name:S_S
Pace Protect
WW
Site Location
_
ManaP
srarE:
/ Jn
Requested Due DaterrAT: Protect
Number: 5DUO
Pace Profile &: � ✓ �
Requested
-Analysis
Filtered
(YIN)
Section D Matrix Codes
=
Required talent lrdonnarmn MATRtx I CODE
8
o
COLLECTED
Preservatives
Drinking Water DW
z
Water Wi
Waste Water WW
Product P
U
m
Q
COMPOWE
STPRT
COMPPPPPP 9����011%��
ENO/0.B)
o
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Soil(Solid SL
1
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SAMPLE ID oil OL
8
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(A-Z. 0-9 /.) Air AR
p
~
a
w
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Sample We MUST BE UNIQUE Tissue TS
O
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tID
s
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Other OT
U
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to
2
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m
O
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1—
till
2
— 0
1
355
Is
1
3
4
S
6
7
8
9
10
11
12
ADDITIONAL COMMENTS
MLINGUISHED BY /AFFILIATION
DATE
TIME
ACCEPTED BY / AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
SAMPLER NAME AND SIGNATURE
U
o'
m
ORIGINAL
a_
i✓
v
PRINT Name of SAMPLER: C�
SIGNATURE of SAMPLER: DATE Signed
o '
—�'
m
(a
(MMIDDNY):
co
*Important Note: 6y signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.6% per month Vany if aloes not paid within 30 days. ' - F ALL-W20rev.07, 15-May-2007

acmnalytical
www.pacelabs.com
November 18, 2009
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on October 30, 2009.
The results relate only to the samples included in this report. Results reported herein conform to the
most current NELAC standards, where applicable, unless otherwise narrated in the body of the
report.
Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and
Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All
Microbiological analyses were performed at the laboratory where the samples were received.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
(_1p
Renee Spencer
[e-mail]
Project Manager
Enclosures
cc: Mr. Tom Dunham, Duncklee & Dunham
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
[phone]
Page 1 of 15

aceAnalytica!®
www.pacelab&cum
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Asheville Certification IDS
West Virginia Certification #: 356
Virginia Certification #: 00072
Tennessee Certification #: 2980
South Carolina Certification M 99030001
South Carolina Bioassay Certification #: 99030002
Pennsylvania Certification #: 68-03578
Connecticut Certification* PH-0106
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Drinking Water Certification #: 37712
North Carolina Bioassay Certification M 9
New Jersey Certification #: NCO 11
Massachusetts Certification M M-NC030
Louisiana/LELAP Certification #: 03095
Florida/NELAP Certification #: E87648
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 15

aceAnalytical
www.pacelabs.com
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7H-1009
Lab ID: 9266442001 Collected: 10/29/09 09:30
Received: 10/30109 15:20 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
ND mg/L
0.10
1
11/05/09 10:29 7664-41-7
363.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.36 mg/L
0.10
1
10/30/09 22:07 MO
Nitrogen, NO2 plus NO3
0.36 mg/L
0.10
1
10/30/09 22:07 M0
Date: 11/1812009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
C1 lacF
Page 3 of 15

(�IacmnalAcal
wwwpacelabs.com
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6M-1009
Parameters
Lab ID: 9266442002 Collected: 10/29/09 10:30
Results Units Report Limit DF
Received: 10/30/09 15:20 Matrix: Water
Prepared Analyzed CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10
1
11/05/09 10:31 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.15 mg/L
0.10
1
10/30/09 22:20
Nitrogen, NO2 plus NO3
0.15 mg/L
0.10
1
10/30/09 22:20
Date: 11/18/2009 10:07 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
MIela&,
Page 4 of 15

® Pace Analytical Services, Inc.
acmnalytical 2225 Riverside Dr.
www.pacelabs.com Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6B-1009
Lab ID: 9256442003 Collected: 10/29/09 11:45
Received: 10/30/09 15:20 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10
1
11/05/09 10:33 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
55.9 mg/L
0.10
1
10/30/09 22:21
Nitrogen, NO2 plus NO3
55.9 mg/L
0.10
1
10/30/09 22:21
Date: 11 /18/2009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Cie
Page 5 of 15

aceAnalWical
wvmpacelabs.cam
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Sample: K65W7D-1009 Lab ID: 9256442004 Collected: 10/29/09 13:46 Received: 10/30/09 15:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/05/09 10:34 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate ND mg/L 0.10 1 10/30/09 22:22
Nitrogen, NO2 plus NO3 ND mg/L 0.10 1 10/30/09 22:22
Date: 11/1812009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Vl' el
Page 6 of 15

aceAnalytical
www.pac81abs.com
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6N-1009
Parameters
Lab ID: 9256442005 Collected: 10/29/09 16:00
Results Units Report Limit DF
Received: 10/30/09 15:20 Matrix: Water
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
1.7 mg/L
0.10
1
11/05/0910:36 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
82.3 mg/L
0.10
1
10/30/09 22:26
Nitrogen, NO2 plus NO3
83.0 mg/L
0.10
1
10/30/09 22:26
Date: 11/18/2009 10:07 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
.' nela
Page 7 of 15

aceAnalytical
wwpam1t6 rem
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K-1009
Lab ID: 9266442006 Collected: 10/30/09 08:00
Received: 10/30/09 15:20 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
3.6 mg/L
0.10
1
11/05/09 10:36 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
99.4 mg/L
0.10
1
10/30/09 22:27
Nitrogen, NO2 plus NO3
99.4 mg/L
0.10
1
10/30/09 22:27
Date: 11 /18/2009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of PaceAnalytical Services, Inc..
��nelac"
Page 8 of 15

aceAnalyiical
www.paWabs.cam
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Sample: K65W7L-1009 Lab ID: 9256442007 Collected: 10/30/09 08:50 Received: 10/30/09 15:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia 9.4 mg/L 0.10 1 11/05/09 10:38 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 103 mg/L 0.10 1 10/30/09 22:28
Nitrogen, NO2 plus NO3 103 mg/L 0.10 1 10/30/09 22:28
Date: 11/18/2009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
moo`' G
:. RIaC
Page 9 of 15

®
Pace Analytical Services, Inc.
Analytical
2225 Riverside Dr.
www.pacelabs.com
Asheville, NC 28804
[phone]
ace
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7J-1009
Lab ID: 9256442008 Collected: 10/30/09 10:00
Received: 10/30/09 15:20 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.7 mg/L
0.10 1
11/05/09 10:38 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
199 mg/L
0.10 1
10/30/09 22:29
Nitrogen, NO2 plus NO3
199 mg/L
0.10 1
10/30/09 22:29
Date: 11 /18/2009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
nelac
Page 10 of 15

® Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical 2225 Riverside Dr.
9800 KinceyAve. Suite 100
www.pscelabs'.com Asheville, NC 28804
a
Huntersville, NC 28078
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Sample: K65W6E-1009
Lab ID: 9256442009 Collected: 10/30/09 10:45
Received: 10/30/09 15:20 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10
1
11/05/09 10:40 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
44.4 mg/L
0.10
1
10/30/09 22:34
Nitrogen, NO2 plus NO3
44.4 mg/L
0.10
1
10/30/09 22:34
Date: 11/18/2009 10:07 AM REPORT OF LABORATORY ANALYSIS Page 11 of 15
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
wvmpacabbs.cam
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6A-1009
Parameters
Lab ID: 9256442010 Collected: 10/29/09 14:35
Results Units Report Limit DF
Received: 10/30/09 15:20 Matrix: Water
Prepared Analyzed CAS No. Qua]
360.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.10 mg/L
0.10
1
11/05/09 10:42 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
186 mg/L
0.10
1
10/30/09 22:25
Nitrogen, NO2 plus NO3
186 mg/L
0.10
1
10/30/09 22:25
Date: 11 /18/2009 10:07 AM REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
'Vnelacr':
Page 12 of 15

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelahs.com Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
QC Batch: WETA/6159
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 9256442001, 9256442002, 9256442003,
9256442004, 9256442005, 9256442006, 9256442007, 9256442008,
9256442009,9256442010
METHOD BLANK: 359540
Matrix: Water
Associated Lab Samples: 9256442001, 9256442002, 9256442003, 9256442004, 9256442005, 9256442006, 9256442007, 9256442008,
9256442009,9256442010
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.10 10/30/09 22:04
Nitrogen, NO2 plus NO3
mg/L
ND 0.10 10/30/09 22:04
LABORATORY CONTROL SAMPLE:
359541
Spike LCS LCS % Rec
Parameter
Units
Cone. Result % Rec Limits
Qualifiers
Nitrogen, Nitrate
mg/L
5 5.3 106 90-110
Nitrogen, NO2 plus NO3
mg/L
5 5.3 106 90-110
MATRIX SPIKE SAMPLE:
359542
9256442001 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.36 5 6.6 124
90-110 MO
Nitrogen, NO2 plus NO3
mg/L
0.36 5 6.6 124
90-110 MO
MATRIX SPIKE SAMPLE:
359544
9256472001 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND 5 6.0 120
90-110 MO
Nitrogen, NO2 plus NO3
mg/L
0.13 5 6.0 118
90-110 MO
SAMPLE DUPLICATE: 359543
9256442001 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
0.36 0.35 2
Nitrogen, NO2 plus NO3
mg/L
0.36 0.35 2
SAMPLE DUPLICATE: 359W
9256472001 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
ND ND
Nitrogen, NO2 plus NO3
mg/L
0.13 ND
Date: 11/18/2009 10:07 AM REPORT OF LABORATORY ANALYSIS Page 13 of 15
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
�@�C .

Abe- I
av Pace Analytical Services, Inc. Pace Analytical Services, Inc.
11�`� aceAnalcal 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wwwpacalabs.wm Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
QC Batch: WETA/6172
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 9256442001, 9256442002, 9256442003, 9256442004, 9256442005, 9256442006, 9256442007, 9256442008,
9256442009,9256442010
METHOD BLANK: 360241
Matrix: Water
Associated Lab Samples: 9256442001, 9256442002, 9256442003, 9256442004, 9256442005, 9256442006, 9256442007, 9256442008,
9256442009,9256442010
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 11/05/09 10:15
LABORATORY CONTROL SAMPLE:
360242
Spike LCS LCS
% Rec
Parameter
Units
Cone. Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 4.8 96
90-110
MATRIX SPIKE SAMPLE:
360243
9255905001 Spike MS
MS % Rec
Parameter
Units
Result Cone. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5 5.2
104 90-110
MATRIX SPIKE SAMPLE:
360245
9256442002 Spike MS
MS % Rec
Parameter
Units
Result Cone. Result
% Rec Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5 5.4
108 90-110
SAMPLE DUPLICATE: 360244
9255905003 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
14.6 13.4
8
SAMPLE DUPLICATE: 360246
9256442003 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND ND
Date: 11 /18/2009 10:07 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
-neiaC':
Page 14 of 15.

acmnalytical
www.pacelabs.com
QUALIFIERS
Project: SS STATESVILLE 50200
Pace Project No.: 9256442
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes.
U - Indicates the compound was analyzed for, but not detected.
ANALYTE QUALIFIERS
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
[phone]
Date: 11/18/2009 10:07AM REPORT OF LABORATORY ANALYSIS Page 15 of 15
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
e :oy
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eAnal ical
nwr.pacelebtr.esn
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A Section B Section C Page: ,' of /
Required Client Information: Required Project Information: Invoice Information:
Company DV11 'Report SnI1 kdeo lLr' �Q
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Reference:
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K65W6 A (Saprolite)
400
350
Nitrate Results
—2L Standard
300
aa
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a 250
a
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Date
Date 1 2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
8/2/95
11/8/95
Nitrate (mg/1) 370
252
360
360
311
30
210
340
330
250
260
250
180
Ammonia (mg/1 No Data
Date
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
11/3/99
3/28/00
11/16/00
415101
10/24/01
Nitrate (mg/I)
240
260
210
106
243
121
199
236
240
220
200
180
190
Ammonia (mg/1
No Data
Date 3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
10/15/07
4/25/08
Nitrate (mg/1) 235
170
140
84
200
150
170
190
160
150
140
30.9
92.8
Ammonia (mgA No Data
77
0.24
NS
NS
NS
0.23
NS
0.14
0.13
0.25
0.36
Date
4/9/09
10/30/09
Nitrate m
152
186
Ammonia m
NS
0.1

K65W6 B (Saprolite)
160
140
Nitrate Results
120
— 2L Standard
100
A
C
80
i
A
c 60
0
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F 40
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C C C C C C C C C C C C C C C C C C C C C
m m co m m m m m m m m m m m m m m m m m m
Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
3/30/99
11/3/99
Nitrate m
22
22
15
26
16
7.6
6.8
28
29
19
18
89.4
140
Ammonia m
No Data
Date
10/24/01
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
4/9l09
Nitrate m I
78
92
40
41
44
33
35
28
23
31
31
32
40
Ammonia m
No Data
<0.1
<0. I
<0.1
NS
NS
0.12
<0.1
<0.1
<0.1
NS
<0.1
40
Date
10/29/09
Nitrate m
55.9
Ammonia m
<0.1

K65W6 D (Saprolete)
2
—� Nitrate Results
1.5
�eu
e
A
e
0
1
0
u
G
U
:3
z 0.5
0
O N N M
W CP W CP
7 N 7 N 7 N
Q U- Q U- Q LL
Date
Date
8/1/90
1/22/92
2/10/93
4/8/93 to 10/30/09
Nitrate m
0.63
0.17
0.25
Dry
Ammonia m
No Data
Dry

K65W6 E (Bedrock)
300
+Nitrate Results
250
—2L Standard
200
c
c
O
150
a
u
c
0
U
100
z
50
0
O N CM V' LO CO r- 00 m C. N M Cn CO r` 00 O
CA W 91 (A O O CA O CA m O O O O O O O O O O
7 7 7 7 7 7 7 75 7 75 7 7 7 7 7 7 7 7
Date
Date
8/l/90
1/22/92
2/10/93
8/2/95
11/8/95
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
Nitrate m
7.3
37
27
4.4
5
56
7.9
8.5
11.7
24.1
30.9
49.9
50.4
Ammonia m I
No Data
Date
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
Nitrate m
56
67
68
62
78
81
76
62
60
90
100
120
150
Ammonia m
No Data
<0.1
<0.1
<0.1
NS
NS
<0.10
Date
4/26/06
10/23/06
5/1/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
Nitrate m
140
150
150
14.2
169
202
253
44.4
Ammonia m
<0.1
<0.1
<0.1
<0.1
<0.1
<0.1
0.5
<0.1

12/1 /2008
1 /1 /2009
Nitrate Concentration in mg/L
O o 0 0 0 0 0 0 0
. (n O v W (O --�
I
z
a
2/1 /2009
3/1 /2009
4/1 /2009
$all
5/1 /2009
d
"C
6/1 /2009
7/1 /2009
8/1 /2009
9/1 /2009
10/1 /2009
11 /1 /2009

Nitrate Concentration in mg/L
N W A M 0) --1 00 O O
O O O O O O O O O O O
O O O O O O O O O O O
12/1 /2008
1 /1 /2009
I I
w
c
77
a c
2/1 /2009
N
3/1 /2009
4/1/2009
5/1 /2009
C
6/1 /2009
�s
0
7/1 /2009
8/1 /2009
9/1 /2009
10/1 /2009
11/1/2009

K65W7C (Saprolite)
140
t Nitrate Results
120
-2L Standard
100
8
a
c 80
F
L
O
u
°0 60
U
d
Z
40
20
0
O N f0 v N f0 n eo rn O N M v <o n W
rn M rn rn rn m rn rn m 0)o 0 0 0
� .b ri h 0 0 0 0 0
.6 6 .6 .6 a .6 � .6 .6 A A .6 h h
w w w w w w w a> w w w w w w w w w w w
LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL LL
Date
Date
2/13/90
1/22/92
2/10/93
10/17/03
7/18/05
10/28/05
4/25/08
12l19/08
4/9/09
10l29/09
Nitrate m
93
130
13
82
33
53
<0.1
D
D
Dry
Ammonia m l
No Data
9
NS
2.3
29.4
D
Dry
Dry

40
R47
30
E
25
G
O
r
ed
F.
C 20
d
c>
C
O
U
15
L
y.n
z
10
5
0 4-
O
m
7
—♦-Nitrate Results
—2L Standard
N M V to CO n
d) T W T T O1
K65W7 D (Saprolite)
0
7 7 7
Date
0
3 75 7 7 7 7 75 7 75
Date
8/l/90
1/22/92
2/10/93
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
Nitrate m 1
11
2
0.57
0.775
2
1
2
1.1
0.1
1.1
2.4
1.4
0.05
Ammonia m
No Data
0.41
<0.1
Date
4/16/04
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
4/25/08
4/16/09
10/29/09
Nitrate m
1.3
2.4
0.48
2
1.1
15
39
0.48
0.21
<0.1
Ammonia m
<0.1
NS
NS
0.12
<0.1
1.1
2.1
<0.1
<0.1
<0.1

K65W7 F (Saprolite)
200
180
Nitrate Results
- 2L Standard
160
140
a
c 120
cCO.
100
u
0
0
U 80
d
Z 60
40
20
0
O N m u7 co n co O C. N m sr u�, CO rl- co O
T CA m A A A O O O O O
7 7 7 > 75 7 7 7 7 > 5 > 7 7 7 7 7 7 7
Date
Date
8/1/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
2/8/96
5/9/96
Nitrate m
99
100
109
79
79
110
100
100
96
1.6
94
150
6.1
Ammonia m
No Data
Date
3/28/00
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
Nitrate m
5.1
0.52
20
33
17
3
21
8.5
<0.1
20
31
31
15
Ammonia m
No Data
<0.1
NS
<0.1
NS
NS
NS
0.12
1.1
Date
4/25/08
4/9/09
10/29/09
Nitrate m
61.9
33.6
Dry
Ammonia (m I)
<0.1
<0.1
Dry

K65W7 G (Saprolite)
40
— 4 Nitrate Results
—2L Standard
30
E
C
q
O
i+
L
20
u
A
O
U
z
10
0
O N M U) O I` 00 O O N CM V' to co
O O a) O O O) O O d) O O O O O O O
7 7 7S 7 7 7 7 7 7 73 7 7 7 7 7 7
Date
Date
8/l/90
1/22/92
2/10/93
2/8/96
11/3/99
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
10/28/04
7/18/05
Nitrate m 1
1.7
1.9
2.6
3.5
2.9
3.6
2.8
31
32
1.3
0.4
4.4
1.7
Ammonia m
No Data
<0.1
<0.1
NS
NS
Date
4/25/06
10/23/06
5/1/07 to 10/29/09
Nitrate m
16
29
Dry
Ammonia m I
<0.1
4
Dry

Nitrate Concentration in mg/L
0 0 0 0 0 0 0 0 0
O W A <T 0) v Oo f0
12/1 /2008
1 /1 /2009
1
z
CD
CD
2/1 /2009
3/1 /2009
4/1 /2009
5/1/2009
d
x
a
6/1 /2009
0
7/1 /2009
8/1 /2009
9/1 /2009
10/1 /2009
11 /1 /2009

K65W7 J (Saprolite)
300
Nitrate Results
-21, Standard
250
200
a
.Q
0
w
150
c
0
U
100
Z
50
0
v uO U') co co r` co co rn rn
0 0 0 0 0 0 0 0 0 0 0
U Q_ U ❑. U CL V Q
O < O < O < O < O < 0
Date
Date
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
Nitrate m (
100
140
74
I
150
180
140
14.4
178
204
191
199
Ammonia m
NS
I NS
<0.1
<0.1
<0.1
0.1
0.6
0.86
0.79
1.7
1 1.7

K65W7 K (Bedrock)
250
-4—Nitrate Results
—2L Standard
200
s
d
a 150
cam,
a
d
u
C
100
U
d
z
50
0
v Ln Ln co m r- n co 00 rn rn
0 0 0 0 0 0 0 0 0 0 0
U p. U CL U CL U CL U CL U
O Q O Q O Q O Q O Q O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
Nitrate m
81
89
190
100
1
120
89
25.9
99.5
108
95.4
99.4
1
Ammonia (mo
NS
NS
4
4
11
4.5
4.2
4.8
4.1
4.2
3.6

K65W7 L (Bedrock)
200
180
-+-Nitrate Results
160
-21, Standard
140
19
120
a
0
0 100
d
q
U 80
so
z
40
20
0
v n n co cD n r CO eo m rn
0 0 0 0 0 0 0 0 0 0 0
U p. U p. U a U p. U p. U
0 Q 0 Q 0 Q 0 Q O ¢ O
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
Nitrate m
22
98
110
130
120
99
30.5
104
103
93.8
103
1
Ammonia m
NS
NS
7.7
7.4
11
11
12.9
12.4
10.4
10.1
9.4

GARAGE
I
OFFICE
O
r
f
o�
O
I
1
Purina Feed Mill Property I
I
i
Property Line o I
Former ' (6�® ` APWOXIMATE OF I
Pond A K65®"B" Former
Pond B \ \(44.4) 65W6 � \ P I (; ATION APPROXIMATE I
LOCATION OF
STORAGE \_5 ® e \ \\ \ WATER SUPPLY
a� O WELLS FOR PLANT I
� ❑ o � \ \ OPERATIONS '
RATLROAD TRACKS \ (NOT IN USE) \ NS\\ \ \ I
\ \ \\ \
FERTILIZER \ \ \ \ \ I
PLANT f56
\ \ t00 \ \ \
\ \ \K .,5 �Q I
\ \ \ \ % 5a \ \ K6 "K`\
\ \ \\ g „�„ ® (9 .4) \® \
\ K�W6�`ivl" I
\ 10 % K65W7"C ® RW\6 \\ \ \ f
t \ \ \ \ (103)
Legend
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
`\
Property Line
(NS)
Not Sampled
(30.3)
Nitrate Concentrations in mg/L
Isoconcentration Line
I%\\Nitrate
Dashed where inferred
Note: Ponds A and B are approximate
locations based on CAP data (1994 Canonie)
� \ \
f� Southern States Cooperative Inc. \ � \
�® Property Line
Statesville Fertilizer Facility \ \
o
�
Q%
�O1
aNv
c
�
nwZ
0
Y F� =
6
En > >
zovv
w
any
rn
C
A
v
Residential
w
o
f Properties
o
c
N
QS
N
Q
M
N
00
I
\ \ \ 1 0
\ K65W7"F"
m \ K65W7"G"
\ RW-2®®Q
5W7"H"
(0.36)
K65W7"D"
Stream I
0 250' 500'
Graphical Scale

GARAGE
Ir
Purina Feed Mill Property
Property Line
e / K6 6"E \ \ \� \
For r / / ®� �_�_\ App��R�X]M�TE
PonA ` K6'5W6"B" rmer OC' Tlt�jlOF\
nd B K65W6 A" \ P IG ATIO APPROXIMATE
I ®(eS 9) ® (186) \ LOCATION OF
STO GA \� \ \ WATER SUPPLY
RW 5r \ \ \ WELLS FOR PLANT '
\ \OPERATIONS I
fit' ❑ � \
iLR ADD TR\4 KS \ \ (NOT IN USE \ \ \ \ r
V1M)\ \ I
r
l
FERTILINR
PLANT \ \ \ \\\ \ \ \\ I
\ \ \ s K60 "D" I
\ �fC657
\ \ \ \ K65 6"N® 150\ 65W7"J 0 00 \
7 \ \\ (82.3) 100 \\\(\)
Legend
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
%\
Property Line
(NS)
Not Sampled
(30.3)
Nitrate Concentrations in mg/L
Nitrate Isoconcentration Line
Dashed where inferred
Note: Ponds A and B are approximate
locations based on CAP data (1994 Canonie)
\ \ IN, `� ✓ \
"'S uthern States Cooperative Ins, \
\ St�sle Fertilizer Facility ' 50
IN, \
\
\ \ 10
\
�® Property Line
(0.15)
�p
PkNL'
�wZ
Y
U
Z o
> '>
d U
I
�•i Y
� )
�
a �
C
�
Residential
z to
h,
1
Properties
0
v,
ON
0
o
N
N
q N
M
N
00
I�OO
I
w
O
o
tn O
q
o
NO
�
NCO
N
K65W7"F"
V)
Z
K65W7"G"
o
(NS)
v
RW-2S®�
F z
(Ns)
3
K65W7„G„®
5W7"H"
a
0 0 3
(INS)
rn
Stream
I
O
U
�3
/
W
J/
� w
0
250'
S00'
Graphical Scale

GARAGE
I
OFFICE
G
r
O
1
Purina Feed Mill Property I
I
Propertv Line
I / K65W6"E"< \\\ '
Former o �rt ` �®® ���\ ROXIMATE
PondA OF
K65W6"B" Pp (253) K65W6"A"t \,f'kV0N ATION APPROXIMATE
\ \ \ \ LOCATION OF I
STORAGE \ \ \ , \ \\ WATER SUPPLY
WELLS FOR PLANT '
Do 0 \ \W-5r \ \ OPERATIONSF1
I
RAILROAD TRACKS \ \ (NOT IN USN (IN
NE)
150 \ \ \ \ \
\ IN. \ \ \
FERTILIZER %\ \ 100 \ \ \ \ \ '
\" "'K6 6"D"
\ K65W7'K \ ®\ \ I
a\50 65W7"J" ® (9s.4} \ K5� 11- I
Legend
®
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
*6\
Property Line
(NS)
Not Sampled
(30.3)
Nitrate Concentrations in mg/L
r\
Nitrate Isoconcentration Line
Dashed where inferred
Note; Ponds A and B are approximate
locations based on CAP data (1994 Canonie)
Property Line
m
10 \
� \ ho K65W7'L"® RW
\ \ \ \ \ (93.8)
•1 \ �
\
\\ \ \\
States Cooperative Inb, \ \ \ \ \
Fertilizer Facility \ \
\ \
Residential
Properties
\
\\ K65W7"F"
K65W7"G"
RW-2®®Q
5W7"H"
(0.26)
Stream
K65W7"D"
i
�o
Ole
0 250' 500'
Graphical Scale

GARAGE
OFFICE
I
G
r
.N
0
I
Purina Feed Mill Property I
I
Property Line
Former /7R—
� u \ \ APPROXIMATE
Pond A / K65W6"B" Former a� „\ iipCA�ION OF
1 ®(40) Pond B K65W62' \ \PUIQINTS\STATION APPROXIMATE
OF
STORAGF� ® \ \ \ \ WATER SUPPLY
\ ooWELLS FOR PLANT
\\ � \ �\ r \��\ \ � OPERATIONS
RATLR0+4D TRACKS o \ \ \ \ (NOT IN NE \ (INSEN
FERTILIZER \ \ \ \
PLANT
\ \ \ \
\ \
Legend
®
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
r\
Property Line
(NS)
Not Sampled
(30.3)
Nitrate Concentrations in mg/L
Nitrate Isoconcentration Line
Dashed where inferred
Note: Ponds A and B are approximate
locations based on CAP data (1994 Canonie)
-1-1 iiu 6 ..K
(NS)
j� 6"N" \ \ 65W7"J'® K65W6"IM"
(61.9) 100 \ \ (191) (<O.10)
\\50 \\
N, \
:hemN&ates Cooperative Inc. \ \
;sville FeQizer Facility \ \
\ \
to
\
\
\
\ I
\
\
Property Line
r
Residential
Properties
I
\ IN.
t \ \ IN \ \ \
IN \ \
\ \ ,�65W7"F"
\ \ \ \ K65W-)-<
I\ \ (NS) \
' (NS)
SRW 2•�®
\ I .e (33.6)
K65W7"C„ 5W7"H" j
\
I
I� Cg
I
I
I
I
K65W7"D j
0
1
0 250' 500'
Graphical Scale
O .� ON
O I N

r
I
OFFICE
C
da
Legend
C:�L
Former
Pond A
GARAGE
STORAGE
11
Purina Feed Mill Property
I
I
1
i
I
® Property Line
K65W6"E"
Former APPROXIMATE
K65W6"B" (846.14) �� 06�A" LOCATION OF APPROXIMATE '
® Pond B PUMPING STATION I
LOCATION OF
�� ® WATER SUPPLY
Q c RW-5r WELLSFORPLANT
EJ o o \
FERTILIZER 844
PLANT
Y6"'N";6
(833.53)
830
lhern States Cooperative Inc.
;sville Fertilizer Facility
®
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
r
Property Line
(850)
Ground Water Elevation in Feet
Ground Water Elevation Contour
(Displayed in 10-foot Intervals)
Dashed Where Inferred
—�
Ground Water Flow Direction
Dashed where inferred
Note: Ponds A and B are approximate
locations based on CAP data (1994 Canonie)
Property Line
OPERATIONS
(NOT IN USE)
(IN USE)
K65W7"K" K
aW7"ill
(805.36) ®K65W71" ® f
820
810
I
I
I
I
"D" I
K6516" MI, I
(798.64)
I
I
i
i
/
I s
1800
I
I
I� 8
I
1
1
I
19
K65W7"C"®
(DRY)
790
K65W7"D" . /
Residential
Properties
K65W7"F"
K65W7"3" (DRY)
RW-2®®®
5W7"H" (DRY)
Stream k
.00
.,O�
.40
0 250' 500'
Graphical Scale
o.00�E
wN�O
x
x �
N Z 2
�Z
a o
d u
Ga U
O Z
� L>
' 00
E�
Q U
W�
L) o
QW

I
O J
Purina Feed Mill Property I I 4 y 0 ��
.�
_ Property Line
K65W6"E"
® e I Off— w Z
Former \ APPROXIMATE
Pond A K65W6' B F er ®� „ LOCATION OF
(846.99 and B K65W6 A PUMPING STATION APPROXIMATE O Q '> '5
GARAGE ) 833.49 LOCATION OF w v
STORAGE ®( ) WATER SUPPLY
O WELLS FOR PLANT + v�
aRW-5r OPERATIONS I rc
RAILROAD TRACKS (NOT IN US ® (IN USE) I C
OFFICE 840 Residential ti
FERTILIZER Properties o 0
PLANT (DRY) '^ CDcV
K65W7' K' K65V� D" I °' N "'
°i cV
® q
K65 6"N;b W7"40 K65W6"M" I o
a (835.71) (804.60) ®K65W7" "a RW-6 (795.78)
O �
� 830 � �,
Southern States Cooperative Inc. oo o
x Statesville Fertilizer Facility r, I o Co o
q
tn
L CID
CIO
006��
O 820 rr1 CP w ^ " °
N x U
N Q Q
I K65W7"F"
Le end s 65W7"G" (DRY) o
g
® cz
Saprolite Monitoring Well 810 RW-2•®® O
I ^z..o
® Bedrock Monitoring Well r U
' K65W7"C' 5W7"H" (768.37) U 0'
viUO'
A Recovery Well I (DRY)
e tream
Property Line F ,
I 800 780
(850) Ground Water Elevation in Feet COO
Ground Water Elevation Contour I K65W7"D" I A U
(Displayed in 10-foot Intervals) Property Line ' 8� (793.49) 790 ° a
Dashed Where Inferred
Ground Water Flow Direction ' W
Dashed where inferred I
I QW
Note: Ponds A and B are approximate 0 250' 50I
locations based on CAP data (1994 Canonie) I
Graphical Scale

1
Purina Feed Mill Property j
I ® Property Line — °p
' U c
Former K65W6"E" APPROXIMATE I ° y y^
Pond A K65W6"B" Former 00 ❑ LOCATION OF r Y = =
Pond B K65W6 A PUMPING STATION APPROXIMATE ' r' v� '>
® LOCATION OF
GARAGE ®
R W— 5r WATER SUPPLY I a�
STORAGE O WELLS FOR PLANT ' v�
OPERATIONS I o
❑ 0 ® ® r
RAILROAD TRACKS (NOT IN USE) (IN USE) 1 w
r V
OFFICE
I � Residential
FERTILIZER r Properties
0
0 0
PLANT r N N
K65 6"D"
� ~ K65W7'K" Cv � � � � Q
K65 6"N65W7"J'®® K65W6"M"
K65W7"l_"® RW-6
N
C)
r O
o �C) N ti
1
p N
Southern States Cooperative Inc. � o
Statesville Fertilizer Facility ' o o �k o
O j o�0
M W N a C
^^mall x
�• Q x
K65W7"F" o
Lj K65W7"G"
Legend L) °w
' �9 u
® Saprolite Monitoring Well r i®� o
RW-2 z A
® Bedrock Monitoring Well — s� P
i K65W7' C" 5W7"H" o re
® Recovery Well rn
Stream
® Property Line r F,
z
IK65W7"D" O
�® Property Line 80 "C� ,_4
®
s W z
1 e U O
Q w
I 0 250' 500'
Note: Ponds A and B are approximate I
locations based on CAP data (1994 Canonie)
Graphical Scale