NC0082821_Regional Office Historical File Pre 2018 (5)

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r MR 2 4 2014
2013 Report of
Annual Groundwater Monitoring and
Treatment System Effectiveness
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
Prepared for
Mr. Vance Dann
Southern States Cooperative, Inc.
Post Office Box 26234
Richmond, Virginia 23260
Submitted to
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
Prepared by
Duncklee & Dunham, P.C.
511 Keisler Drive, Suite 102
Cary, North Carolina 27518
March 19, 2014
- DUNCKLEE & DUNHAM, P.C.

ENVIRONMENTAL GEOLOGISTS & ENGINEERS
DUNCKLEE
511 KEISLER DRIVE — SUITE 102
�7��u ��� CARY, NORTH CAROLINA 27518
1 & DUlVHAM OFFICE: [phone]
-- W W W.DUNCKLEEDUNHAM.COM
March 19, 2014
Mr. Andrew Pitner, P.G.
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
Reference: 2013 Report of Annual Groundwater Monitoring and
Treatment System Effectiveness
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
Incident Number 5038
Dear Mr. Pitner:
On behalf of Southern States Cooperative, Inc. (Southern States), Duncklee & Dunham, P.C. is pleased to
submit this 2013 Annual Groundwater Monitoring and Treatment System Effectiveness Report for the
above -referenced site. This report summarizes the work we conducted and recommendations derived
from sampling and monitoring in 2013.
Please contact Jayson Kilcoyne at [phone] ([e-mail]) or Vance Dann of
Southern States at [phone] ([e-mail]) if you have any questions or require
additional information.
Sincerely,
Duncklee & Dunham, P.C.
9r_�
Jayson A. Kilcoyne
Project Environmental Scientist II
Senior Peer Review:
Richard A. Kolb, L.G.
Senior Geologist
Thomas S. Dunham, P.G.
Senior Geologist
copy: Mr. Vance Dann — Southern States Cooperative, Inc. (e-copy)
\\boss\files\Projects\Southern States\Statesville Fertilizer - 50200\Reports\2013\Annual GW Monitoring Report - 14042.doc
MAILING ADDRESS — POST OFFICE BOX 639 — CARY, NORTH CAROLINA 27512
NORTH CAROLINA BOARD OF EXAMINERS FOR ENGINEERS AND SURVEYORS LICENSE C-3559
NORTH CAROLINA BOARD FOR LICENSING OF GEOLOGISTS LICENSE C-261
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NC DENR REGISTERED ENVIRONMENTAL CONSULTANT NUMBER 00061

Table of Contents
1 Introduction
1.1 Site Location, Description and History
1.2 Summary of Remedial Actions
2 Treatment System Monitoring
3 Groundwater Sampling Activities. and Results
3.1 Groundwater Sampling Methodology
3.2 Results from Sampling Events
3.2.1 Nitrate Results and Trends
3.2.2 Ammonia Results and Trends
4 Recommendations
Figures
' 1 Site Location Map, USGS Topographic Map
2 Site Map
3 Treatment System Discharge Line Outfall Map
4 Potentiometric Map - May 2013
5 Potentiometric Map - November 2013
6 Shallow Aquifer Nitrate Isoconcentration Map - May 2013
I7 Deep Aquifer Nitrate Isoconcentration Map - May 2013
8 Shallow Aquifer Nitrate Isoconcentration Map - November 2013
9 Deep Aquifer Nitrate Isoconcentration Map - November 2013
Tables
1 Summary of 2013 Water -table Elevation Data
2 Summary of 2013 Groundwater Analytical and Field Parameter Results
Appendices
A May and November 2013 Laboratory Analytical Reports
B Nitrate in Groundwater Trend Graphs
1
1
1
2
2
2
3
3
4
4

2013 Report of Annual Groundwater Monitoring and
Treatment System Effectiveness
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
1 Introduction
1.1 Site Location, Description and History
The Southern States Cooperative, Inc. (Southern States) fertilizer plant (the site) is located at
2582 Salisbury Highway (Old U.S. Highway 70) approximately six miles east of Statesville, North
Carolina (Figure 1). The site consists of several buildings that include a fertilizer -manufacturing building,
an office building, and several small support buildings (Figure 2). The site is utilized for the
manufacturing, storage, and distribution of fertilizer.
The site is bordered to the north by old US Highway 70, a Purina Feed Mill to the east, residential
properties to the south, and undeveloped land to the west. The U.S. Highway 70 Bypass (70 Bypass)
crosses east to west through the southern portion of the site and separates approximately 13 acres from the
main property to the north (Figure 2).
Groundwater at the site has been impacted by a release of liquid ammonium nitrate from several former
surface -water impoundments. Two impoundments (Former Pond No. 1 and No. 2) were located
approximately 1,000-feet southwest of the main plant (Figure 2). Two additional surface water
impoundments (Former Ponds A and B, Figure 2) were located east and southeast of the main plant.
These impoundments are referenced in the Corrective Action Plan (CAP) dated January 28, 1994,
submitted by Canonie Environmental Services, Inc. (Canonie) to the North Carolina Department of
Environment, Health and Natural Resources (DEHNR), Division of Environmental Management. The
DEHNR approved the CAP in 1994 and based on the CAP, the assessment and impact of groundwater
contamination was defined with reasonable certainty.
The objectives of the CAP were to remediate groundwater and to prevent off -site migration of the
groundwater contamination plume. A groundwater -sampling plan was developed to establish a
semiannual groundwater -sampling schedule and to monitor the effectiveness of the CAP.
1.2 Summary of Remedial Actions
Three groundwater -recovery wells (RW-2, RW-5 and RW-6) were constructed by Canonie as part of the
CAP. However, RW-5 was taken out of service prior to 2005 due to low or no groundwater recovery and
was replaced by RW-5r in September 2008. The recovery wells pump groundwater to a treatment system
where the pH is adjusted by adding a caustic solution prior to discharge into Fourth Creek (Figure 3).
The groundwater -treatment system is permitted under the National Pollution Discharge Elimination
System (NPDES) program. Duncklee & Dunham conducts bi-monthly site visits when the system is
operational to monitor the treatment system and ensure it operates within the permitted discharge limits.
We collect effluent water samples bi-monthly and report the data to the DWQ on monthly Discharge
Monitoring Reports (DMRs).
DUNCKLEE & DUNHAM, P.C.

2013 Report of Annual Groundwater Monitoring and Treatment System Effectiveness
Southern States Cooperative, Inc. — Statesville Fertilizer Plant
March 19, 2014
Page 2 of 4
2 Treatment System Monitoring
The groundwater -treatment system operated during this reporting period from November 5, 2012, to April
4, 2013, and then from November 6, 2013, to December 31, 2013. A North Carolina licensed Grade I
Wastewater Operator (operator) shut off the system for the summer months between April 4, 2013 and
November 6, 2013. Prior to restarting the system in November 2013, Duncklee & Dunham upgraded the
pH -monitoring system. We replaced the previous monitor and sensor probe with newer units to improve
reliability and accuracy. The system has been operational since we completed the upgrades.
In accordance with the NPDES permit, the operator collected effluent samples bi-monthly for analysis of
total suspended solids (TSS) according to Method 2540D and ammonia nitrogen according to EPA
Method 350.1. The operator also collected monthly effluent samples for analysis of copper (EPA Method
200.7), chloride (Method SM 4500-CI-E), TSS, ammonia nitrogen, total Kjeldahl nitrogen, nitrate
nitrogen and phosphorus all by EPA Method 300 series. We submitted the samples for analysis to Pace
Analytical Services, Inc. (Pace), an analytical laboratory certified by DENR.
We submitted monthly DMRs to DENR as required by the NPDES permit. DMRs were not submitted
between May and October 2013, while the system was not operational.
3 Groundwater -Sampling Activities and Results
Duncklee & Dunham conducted semiannual groundwater -monitoring activities on May 22 to 23, 2013,
and November 19 to 20, 2013. Prior to well purging and sampling, we collected water -table
measurements using an electric water level probe and recorded the data on field sampling data sheets.
The water -table measurements are summarized on Table 1. Potentiometric maps that illustrate the
shallow groundwater flow for the May and November sampling events are presented as Figures 4 and 5,
respectively. The direction of groundwater flow during both events was to the south-southwest. During
the May monitoring event, the average hydraulic gradient was 0.032 ft/ft, and during the November
monitoring event the average hydraulic gradient was 0.027 ft/ft.
3.1 Groundwater -Sampling Methodology
Duncklee & Dunham personnel collected groundwater samples from twelve of the fourteen monitoring
wells during the May 2013 sampling event. The two remaining monitoring wells (K65W6D and
K65W7C) were dry during this event.
We collected groundwater samples from ten 'of the fourteen monitoring wells during the November 2013
sampling event. The four remaining monitoring wells (K65W6D, K65W7C, K65W7F, and K65W7G)
were dry.
Duncklee & Dunham purged the wells and collected samples with a submersible electric PVC pump with
new disposable polyethylene tubing from the wells greater than 35 feet in depth, and used a peristaltic
pump with new tubing for the wells less than 35 feet in depth. We collected the groundwater samples
using low -flow sampling techniques. During the sampling process, we recorded field measurements for
dissolved oxygen (DO), oxidation-reduction potential (ORP), pH, temperature, turbidity, and electrical
conductivity (Table 2). The casing to K65W6A is bent approximately two feet below land surface and a
submersible pump cannot advance past the damaged casing. K65W7G did not yield sufficient water for
DUNCKLEE & DUNHAM, P.C.

2013 Report of Annual Groundwater Monitoring and Treatment System Effectiveness
Southern States Cooperative, Inc. — Statesville Fertilizer Plant
March 19, 2014
Page 3 of 4
low -flow sampling. Therefore, we purged three well volumes and collected samples from K65W6A and
K65W7G using new, disposable, polyethylene bailers.
Duncklee &Dunham pumped or poured the groundwater samples directly into labeled laboratory -
provided containers, recorded the samples on a chain -of -custody form, and transported the containers to
Pace in an insulated cooler filled with ice. Pace tested the samples for nitrate according to EPA Method
353.2 and ammonia- according to EPA Method 350.1. The laboratory analytical reports and chain of
custody records for both sampling events are in Appendix A.
3.2 Results from Sampling Events
Nitrate and ammonia isoconcentration maps for the shallow saprolite and deep bedrock monitoring wells
are presented on Figures 6 through 9. The test results are listed on Table 2 and graphs of the nitrate and
ammonia trends over time are included in Appendix B.
3.2.1 Nitrate Results and Trends
We observed the following with respect to the nitrate results.
The nitrate concentrations increased compared to November 2012 during both sampling events in the
samples collected from saprolite monitoring well K65W6A, located near the former Pond B, but
remained within the historical concentration range for samples from this well. Nitrate concentrations
in saprolite monitoring well K65W6B, located near the former Pond A, also increased in May but
decreased in November and remained within the historical concentration range for samples from this
well. Samples from both of these wells exhibited nitrate at concentrations that exceed the North
Carolina groundwater standard (2L standard) of 10 mg/L.
The laboratory detected nitrate in both samples collected from the saprolite well K65W6M, located
along the southeastern edge of the plume. The nitrate concentrations detected in samples from this
well have not exceeded the 2L standard since this well was constructed in 2008. Samples from the
saprolite well along the northwestern edge of the plume (K65W6N) have exhibited nitrate at
concentrations that exceed the 2L standard since it was constructed installed in 2008. After an initial
increasing trend of nitrate concentrations, the concentrations have decreased over time but spiked
upward in November 2013.
• Samples from saprolite well K65W7J, located in the core of the plume, exhibited nitrate at
concentrations that exceed the 2L standard. The range of nitrate concentrations in samples from this
well has remained relatively constant with apparent seasonal fluctuations since November 2007.
• Samples from the two saprolite plume wells at the southern extent of the plume, K65W7G and
K65W7F, exhibited nitrate at concentrations that do not exceed the 2L standard during May 2013
event. Both of these wells were dry during the November event.
• The samples from the saprolite plume delineation well (K65W7D), located in the southwest portion
of the site, did not exhibit nitrate at a concentration that exceeded the laboratory reporting limit in
May and exhibited nitrate at a concentration of 0.15 mg/L in the sample collected in November.
• Saprolite monitoring well K65W7C was dry during the 2013 monitoring period.
• Nitrate concentrations in the sample from bedrock monitoring well K65W6E decreased from 2012 in
May 2013 but the nitrate concentration increased in November and exceeded the 2L standard. The
overall upward trend of nitrate concentrations continues in the samples from this well.
DUNCKLEE & DUNHAM, P.C.

2013 Report of Annual Groundwater Monitoring and Treatment System Effectiveness
Southern States Cooperative, Inc. — Statesville Fertilizer Plant
March 19, 2014
Page 4 of 4
• Samples from the bedrock wells K65W7K and K65W7L, located in the core of the plume, exhibited
nitrate at concentrations that exceeded the 2L standard but have remained consistent since April 2008.
Samples from bedrock delineation well K65W7H, at the southern extent of the plume, have not
exhibited nitrate at concentrations that exceed the 2L standard since the well was constructed in 2008.
3.2.2 Ammonia Results and Trends
We observed the following with respect to the ammonia results.
• The samples from saprolite well K65 W7J, located in the core of the plume, exhibited ammonia at
concentrations that exceed the 2L standard of 1.5 mg/L. The ammonia concentrations in samples
from this well have exceeded the 2L standard since April 2009.
• The samples from saprolite wells K65W6A, K65W6B, and K65W6N exhibited ammonia at
concentrations that did not exceed the 2L Standard.
• The sample collected in May from saprolite well K65W6E, located near former Pond B, exhibited
ammonia at a concentration that did not exceed the 2L standard, but the sample collected in
November exhibited ammonia at a concentration that exceeded the 2L standard.
• The samples from the bedrock wells located in the core of the plume, K65W7K and K65W7L,
exhibited ammonia at concentrations that exceed the 2L standard. The ammonia concentrations in the
samples form both of these wells remained constant during the 2013 monitoring period.
• The sample from down -gradient plume delineation bedrock well K65W7H, in the southwestern
portion of the site, has not exhibited ammonia since it was constructed in 2008.
4 Recommendations
Based on the information presented above, Duncklee & Dunham recommends the following:
• Continue to operate the groundwater -treatment system in accordance with the CAP and NPDES
permit between November and April.
• Conduct annual monitoring of the plume.
DUNCKLEE & DUNHAM, P.C.

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DUNCKLEE & DUNHAM, P.C. Approximate Scale: Title: Site Location Map
ENVIRONMENTAL CONSULTANTS I" = 2000' USGS Topographic Map
` 511 KEISLER DRIVE — SUITE 102 Figure: Project:
CARY, NORTH CAROLINA 27511 1 Southern States Fertilizer Plant
Statesville, North Carolina

Norf°11t S�x e�"R
/yF6urth Creek
Treatment Pli
Approximate
Location of,
Outfall 001
Southern State
Fertilizer Facil'
West Old Well House Road
Inches
0 1 2
0 0.25 0.5
Miles
Source of base map: Canonie Environmental Coreetive Action Plan -January 1994
Discharge Point
to Creek
Treatment System
Discharge Line
Nigh��
Highway 70 Bypass
DL E EO DUNHAP.C. .
EMROMrAGe0AmT&NGRS
SIIRDRV-
RY, NORM ROIKA27518
Job Number
Layers
50200
0,2
Drawing Size
Figure
8.5 x 11"
3
Scale
ate
1 "= 0.25 miles
12-2013
Title
Treatment System Discharge Line Outfall Map
Project Southern States Fertilizer Plant
Statesville, North Carolina

Table 1
Summary of Water -table Elevation Data
Southern States, Statesville, North Carolina
Wells _
Aquifer
Code
Date
� HOC
,Elevation.:
tTotal� ;: "
,Welly �
De the 1ftd s
�Depthuto sWaterTable,
Water Table
�ffbmtc
El'evat 'ong
K65W6A
Sap
05/22/13
g64.52
58
27.21
837.31
11/19/13
25.83
838.69
K65W6B
Sap
05/22/13
871.55
30
23.74
847.81
11/19/13
23.37
848.18
K65W6D
Sap
05/22/13
846.37
38
DRY
DRY
11/19/13
DRY
DRY
K65W6E
BR
05/22/13
864.89
133
27.35
837.54
11/19/13
27.61
837.28
K65W6M
Sap
05/22/13
837.84
50
40.94
796.90
11/19/13
36.62
801.22
K65W6N
Sap
05/22/13
845.30
50
13.38
831.92
11/19/13
12.91
832.39
K65W7C
Sap
05/22/13
809.72
22
DRY
DRY
11/19/13
DRY
DRY
K65W7D
Sap
05/22/13
800.64
23
10.55
790.09
11/19/13
12.89
787.75
K65W7F
Sap
05/22/13
796.15
28
14.55
781.60
11/19/13
DRY
DRY
K65W7G
Sap
05/22/13
795.98
15
14.69
781.29
11/19/13
DRY
DRY
K65W7H
BR
05/22/13
796.07
112
9.82
786.25
11/19/13
12.14
783.93
K65W7J
Sap
05/22/13
848.20
60
46.94
801.26
11/19/13
43.92
804.28
K65W7K
BR
05/22/13
849.32
121
47.45
801.87
11/19/13
45.64
803.68
K65W7L
BR
05/22/13
848.14
200
46.14
802.00
11/19/13
44.65
803.49
otes.
TOC - top of casing
SL - mean sea level
DRY - well was dry during this sampling event
t bmtc -feet below marked top of casing
quifer Code - Represents aquifer being monitored at this well location (Sap.=Saprolite and BR=Bedrock)
11 measurements are in feet
P:\Southern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Table 2
Summary of Groundwater Analytical and Field Parameter Results
Southern States, Statesville, North Carolina
Laboratory Data
Field Parameters
Ammonia
Nitrate
pH
Temp.
Conductivity
Turbidity
ORP
DO
Well #
Date
mg/L
mg/L
Standard
Units
Degrees
Celsius
MS/cm
NTUs
mY
mg/L
2L Standard
1.5
10
05/23/13
<0.10
124
NM
NM
NM
NM
NM
NM
K65W6A
11/20/13
0.12
157
NM
NM
NM
NM
NM
NM
05/23/13
0.33
59.6
4.24
18.36
0.894
1.68
367.7
6.29
K65W6B
11/20/13
0.13
28.5
4.05
14.75
0.790
1.09
367.1
4.95
05/23/13
NS
NS
NM
NM
NM
NM
NM
NM
K65W6D
11/20/13
NS
NS
NM
NM
NM
NM
NM
NM
K65W6E
05/23/13
0.56
196
9.40
17.42
3.434
3.35
176.1
0.43
11/20/13
1.6
297
6.84
14.86
4.917
2.30
238.3
0.64
05/23/13
<0.10
0.44
5.57
18.04
0.058
16.10
182.6
7.18
K65W6M
11/20/13
<0.10
0.49
5.75
15.87
0.059
16.10
196.8
5.54
05/23/13
0.18
32.1
6.44
15.40
0.797
10.00
248.7
0.56
K65W6N
11/20/13
1.1
57.3
6.66
8.89
0.920
72.40
241.7
1.09
05/23/13
NS
NS
NM
NM
NM
NM
NM
NM
K65W7C
11/20/13
NS
NS
NM
NM
NM
NM
NM
NM
K65W7D
05/22/13
<0.10
<0.020
4.68
16.22
0.086
4.94
190.7
0.66
11/19/13
<0.10
0.15
4.82
14.66
0.104
3.19
197.0
0.58
05/22/13
<0.10
4.1
6.34
14.58
0.136
7.08
134.0
8.06
K65W7F
11/19/13
NS
NS
NM
NM
NM
NM
NM
NM
K65W7G
05/22/13
<0.10
1.7
NM
NM
NM
NM
NM
NM
11/19/13
NS
NS
NM
NM
NM
NM
NM
NM
05/22/13
<0.10
0.74
6.45
16.63
0.092
0.99
149.0
5.62
K65W7H
11/19/13
<0.10
0.52
6.40
14.47
0.096
2.08
174.4
4.97
K65W7J
05/22/13
2.5
187
5.58
16.69
1.745
76.20
214.8
0.43
11/19/13
3.8
191
5.89
14.75
1.727
60.80
208.2
0.48
05/22/13
2.8
86.7
6.54
16.62
1.293
9.56
195.5
0.62
K65W7K
11/19/13
3.0
90.2
6.69
14.86
1.292
14.00
205.4
0.44
K65W7L
05/22/13
9.5
94.5
5.80
16.18
1.281
16.60
208.4
1.01
111/19/131
9.5
94.7
6.08
14.21
1.257
13.10
208.3
0.65
Notes:
Bold text indicates above the laboratory method detection limit
Bold text and shaded cell indicate concentration exceeds the 2L Standard
S - not sampled - dry well
low flow parameters not measured
mS/cm - milli-Siemins per centimeter
NT'Us - nephelolometric turbidity units
mV - millivolts
mjzlL - milligrams per liter
P:\Southem States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

aceAnalytical
www.pacelabs.com
June 04, 2013
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite
RE: Project: Statesville SS 50200
Pace Project No.: 92159215
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sampie(s) received by the laboratory on May 23, 2013. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
e
�z�4 ACC�o
�gQORA'S4�
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 21

,�aceAnaljftal"
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 21

,��aceAnalXicalo
www.pacelabs.com
I
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92159215001
K65W7D
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215002
K65W7G
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215003
K65W7H
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215004
K65W7F
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92169215005
K65W6M
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92169216006
K65W6B
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215007
K65W6N
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215008
K65W7K
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215009
K65W7L
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92169215010
K65W7J
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215011
K65W6A
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92159215012
K65W6E
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 21

aceAnalytical o
m»vpacelabs.cam
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7D Lab ID: 92159215001 Collected: 05/22/13 12:05 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/13 15:16 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate ND mg/L 0.020 1 05/24/13 01:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 4 of 21

i acmnalytical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7G Lab ID: 92159216002 Collected: 05/22/13 13:30 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/13 15:18 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 1.7 mg/L 0.020 1 05/24/13 01:24
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 21

aceAna1j&ca1
ww+w.pacebb&com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7H Lab ID: 92159216003 Collected: 05/22/13 14:20 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/13 15:18 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.74 mg/L 0.020 1 05/24/13 01:26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 6 of 21

aceAnalytical
www.pacelab&com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7F Lab ID: 92159215004 Collected: 05/22/13 15:10 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/13 15:20 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 4.1 mg/L 0.020 1 05/24/13 01:27
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 21

i eAnalytical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6M Lab ID: 92159215005 Collected: 05/22/13 16:46 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/13 15:20 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.44 mg/L 0.020 1 05/24/13 01:39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 8 of 21

aceAnalXical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6B Lab ID: 92169216006 Collected: 05/23/13 12:40 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.33 mg/L 0.10 1 05/25/1315:22 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 59.6 mg/L 0.60 30 05/24/13 02:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 9 of 21

aceAnalytical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
I,1. /_1 A A Ij W-11 1190 *'ill] Al-K
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6N Lab ID: 92159215007 Collected: 05/23/13 08:58 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.18 mg/L 0.10 1 05/25/1315:22 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 32.1 mg/L 0.020 1 05/24/13 01:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 10 of 21

,�aceAnalyfica(
www.pacelabsxom
y
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W71K Lab ID: 92159215008 Collected: 05/22/13 17:37 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.8 mg/L 0.10 1 05/25/13 15:23 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 86.7 mg/L 0.60 30 05/24/13 01:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 11 of 21

,�aceAnaljdicalo
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W71- Lab ID: 92169215009 Collected: 05/22/13 18:26 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 9.5 mg/L 0.10 1 05/25/13 15:25 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 94.5 mg/L 0.60 30 05/24/13 01:56
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 12 of 21

1��aloeAnalytical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7J Lab ID: 92169215010 Collected: 05/22/13 19:10 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.5 mg/L 0.10 1 05/25/1315:27 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 187 mg/L 1.0 50 05/24/13 01:58
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 21

aceAnaljltical
www.pacebbs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6A Lab ID: 92159215011 Collected: 05/23/13 11:30 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF - Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/25/1315:29 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 124 mg/L 0.020 1 05/24/13 01:48
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 14 of 21

aceAnalytical
www.pacelabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab ID: 92169215012 Collected: 05/23/13 10:36 Received: 05/23/13 14:54 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.56 mg/L 0.10 1 05/25/13 15:31 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 196 mg/L 0.020 1 05/24/13 01:45
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 21

aceAnalytical9
www.pacplabs.com
Project: Statesville SS 50200
Pace Project No.: 92159215
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/15416 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92159215001, 92159215002, 92159215003, 92159215004, 92159215005, 92159215006, 92159215007,
92159215008,92159215009,92159215010,92159215011,92159215012
METHOD BLANK: 981937 Matrix: Water
Associated Lab Samples: 92159215001, 92159215002, 92159215003, 92159215004, 92159215005, 92159215006, 92159215007,
92159215008,92159215009,92159215010,92159215011,92159215012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 05/25/13 15:09
LABORATORY CONTROL SAMPLE: 981938
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.0 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 981939 981940
MS MSD
92159196001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 20.3 5 5 25.8 26.1 110 116 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 981941 981942
MS MSD
92159215010 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 2.5 5 5 7.9 8.0 107 110 90-110 2
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 21

a
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
4 t 1 g
alyticQI
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
RC�AI
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALITY CONTROL DATA
Project: Statesville SS 50200
Pace Project No.: 92159215
QC Batch: WETA/15396
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92159215001, 92159215002, 92159215003, 92159215004, 92159215005, 92159215006, 92159215007,
92159215008,92159215009,92159215010,92159215011,92159215012
METHOD BLANK: 980878
Matrix: Water
Associated Lab Samples: 92159215001, 92159215002, 92159215003, 92159215004, 92159215005, 92159215006, 92159215007,
92159215008,92159215009,92159215010,92159215011,92159215012
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.020 05/24/13 01:05
LABORATORY CONTROL SAMPLE: 980879
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5 2.5 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 980882
980883
MS MSD
92158889003
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits
RPD Qual
Nitrogen, Nitrate mg/L 0.13
2.5 2.5 2.6 2.6 97 97 90-110
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 980884
980885
MS MSD
92158889004
Spike Spike MS MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits
RPD Qual
Nitrogen, Nitrate mg/L ND
2.5 2.5 2.6 2.6 103 104 90-110
1
Date: 06/04/2013 07:57 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 21

aceAnaljftal
www.pacelabs.com
i(
Project: Statesville SS 50200
Pace Project No.: 92159215
DEFINITIONS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 18 of 21

�aakcc eAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Statesville SS 50200
Pace Project No.: 92159215
Lab ID Sample ID QC Batch Method QC Batch
92159215001
K65W7D
EPA 350.1
WETA/15416
92169216002
K65W7G
EPA 350.1
WETA/15416
92169216003
K65W7H
EPA 350.1
WETA/15416
92169216004
K65W7F
EPA 350.1
WETA/15416
92169216005
K65W6M
EPA 350.1
WETA/15416
92169216006
K65W6B
EPA 350.1
WETA/15416
92159216007
K65W6N
EPA 350.1
WETA/15416
92159215008
K65W7K
EPA 350.1
WETA/15416
92159215009
K65W7L
EPA 350.1
WETA/15416
92159215010
K65W7J
EPA 350.1
WETA/15416
92169216011
K65W6A
EPA 350.1
WETA/15416
92159215012
K65W6E
EPA 350.1
WETA/15416
92159215001
K65W7D
EPA 353.2
WETA/16396
92159216002
K65W7G
EPA 353.2
WETA/15396
92159215003
K65W7H
EPA 353.2
WETA/15396
92159215004
K65W7F
EPA 353.2
WETA/15396
92159216006
K65W6M
EPA 353.2
WETA/15396
92169216006
K65W66
EPA 353.2
WETA/15396
92159215007
K65W6N
EPA 353.2
WETA/15396
92159215008
K65W7K
EPA 353.2
WETA/15396
92169215009
K65W7L
EPA 353.2
WETA/15396
92159215010
K65W7J
EPA 353.2
WETA/15396
92159215011
K65W6A
EPA 353.2
WETA/15396
92159215012
K65W6E
EPA 353.2
WETA/15396
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
This report shall not be reproduced, except in full,
Date: 06/04/2013 07:57 AM without the written consent of Pace Analytical Services, Inc.. Page 19 of 21

/"-�eAltalytlral" bampie t;onctttton upon Receipt St;uK wage .1 oT L
Document Number: Issuing Authority:
i F-CHR-CS-03-rev.10 Pace Huntersville Quality Office
Client Name: �t Z �
Where Received: ZHuntersville ❑ Asheville ❑ Eden ❑ Raleigh
Courier: ❑ Fed Ex C] UPS❑ LISPS❑ Client❑ CommerclajE I Pace Other O ' tionai 7 Y
Custody Seal on Cooler/Box Present: ❑ yes Pao Seals intact: ❑ yes ❑ no Prod., DueDate �r ',
.Jr
Packing Material: ❑ Bubble Wrap ❑��Bubble Bags 0' Non_e ❑ Other
Thermometer Used: IR Gun T1101 T'�10;2 Type of Ice: W&e Blue None ❑Zamples on ice, cooling process has begun
Ti%mn r:nrmnfinn Pni-Mr T11did- Nn (nrrPnfinn T11A2: Nn Cnrrection
Corrected Cooler Temp.: C
Biological Tissue is Frozen: Yes No N/A
Da e d Initials o . so examining
con e� t :
Temp should be above freezing to 6°C
Comments:
Chain of Custody Present:
d Yes
❑No
❑N/A
1.
Chain of Custody Filled Out:
QYes
❑No
❑N/A
2.
Chain of Custody Relinquished:
tldYes
❑No
❑N/A
3.
Sampler Name & Signature on COC:
Pres
❑No
❑NIA
4.
Samples Arrived within Hold Time:
❑No
❑N/A
5.
Short Hold Time Analysis (<72hr):
Q//es
L?Yes
❑No
❑N/A
6.
Rush Turn Around Time Requested:
❑Yes
Pto
❑WA
7. _
Sufficient Volume:
❑No
❑N/A
8.
Correct Containers Used:
Ves
OYes
❑No
❑N/A
9.
-Pace Containers Used:
[7�Yes
-pkr6j
1EAd
Intact:
n
No
tiA
10Containers (�
Filtered volume received for Dissolved tests
❑Yes
❑No
/A
11, ( e
-1 �• I L
Sample Labels match COC:
Yes
ON,
❑N/A
12. i' e I�
— �(L L j
-includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked.
[Vs
❑No
❑N/A
13,
All containers needing preservation are found to be in
$
❑No
❑N/A
compliance ,Mth EPA recommendation.
exceptions: VOA, collform, TOC, O&G, WI-DRO (water)
❑ s
❑No
Samples checked for dechlorination:
❑Yes
❑N .
❑N/A
14.
Headspace in VOA Vials >6mm):
❑Yes
❑No
/A
15,
Trip Blank Present:
❑Yes
❑No
QJHKA
16.
Trip Blank Custody Seals Present
❑Yes
❑No
❑N/A
Pace Trip Blank Lot # (if purchased
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted:
Comments/ Resolution:
Date/Time:
SCURF Review: Date:
SRF Review: Date: =
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, incorrect preservative, out of temp,
incorrect containers)
WO#:92159215
IIIII92IIIIII IIIIBII III
Page 20 of 21

CHAIN -OF -CUSTODY / Analytical Request Document
Tha Chain-nf-Custodv is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Page: of
won A Section B Section C
equircd aerie lirtr. arr. Required Project Information: Invoice Information:
�+ r
I by 0 3� 0
aztpzcm$ Report To:
Attention:
ti
� So�1
I I
ivfess Qt �� Copy To: a 1
ALA&REGULATORY
Company Name:
AGENCY
Address: I
Ii
F NPDES i GROUND WATER (— DRINKING WATER
F UST [— RCRA F- OTHER
'eo. _ Purchase Order No.:
Pace Quote I
I
• 0 /r
Reference:
'SstAe: Project (game; ,�o!t�`, C — , • e /
_r p- G7(p. J�+�'G w
Pace Project
Manager.
I
Site Location
STATE:
equ� ted H�aZeaTs �� Project Number ��
Pace Profile Iq:
I
Requested
Analysis
Filtered
(YIN)
-
Sectiocc ® N,4a8rix Codes
Z
63e,:afrsdtC7lrart(tiMVt4naticra Ir�zsatx r cow
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CQ1,9POSITE
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RELINQUISHED BY AFFILIATION
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TIME
SAMPLE CONDITIONS
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SAMPLER NAME AND SIGNATURE I II
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DATE Signed
(MMIDD1YY)-I,l
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-finl7artralrttl Ig r-1 EDI sig ing ft-. far; m ycrr: � aseporrg Pace's NET 30 day payment terms and agreeing to late charges of 1.5 % per month for any invAc� s not paid within 30 days. I - F-ALL-O-020rev.07, 15-May-2007

aceAnalytical
www.pacelabsxom
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
November 22, 2013
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
RE: Project: SS Statesville 50200
Pace Project No.: 92180335
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 20, 2013.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNl standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a- �1
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc: Jennifer Chesson, Duncklee & Dunham
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 19

aceAnalytical
www.paceiabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 19

,�aceAnalyfical"
www.pacelabs.com
Project: SS Statesville 50200
Pace Project No.: 92180335
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92180336001
K65W6A
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180336002
K65W6B
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180335003
K65W6E
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180336004
K65W6M
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180336006
K65W6N
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180335006
K65W7D
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180335007
K65W7H
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180335008
K65W7J
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180335009
K65W7K
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
92180336010
K65W7L
EPA 350.1
JTM
1
PASI-A
EPA 353.2
DMN
2
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 3 of 19

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W6A
Lab ID: 92180335001 Collected: 11/20/13 09:35
Received: 11/20/13 16:45 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.12 mg/L
0.10 1
11/22/13 11:31 7664-41-7 M1
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
157 mg/L
0.020 1
11/20/13 23:54
Nitrogen, NO2 plus NO3
157 mg/L
0.020 1
11/20/13 23:54
Date: 11/22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 19

,�aceAnalyfical"
www.pacelabs.com
Project: SS Statesville 50200
Pace Project No.: 92180335
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6B
Parameters
Lab ID: 92180335002 Collected: 11/20/13 08:35
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qual
360.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
0.13 mg/L
0.10 1
11/22/1311:34 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
28.5 mg/L
0.020 1
11/20/13 23:47
Nitrogen, NO2 plus NO3
28.6 mg/L
0.020 1
11/20/13 23:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 19

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W6E
Parameters
Lab ID: 92180335003 Collected: 11/20/13 09:20
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.6 mg/L
0.10
1
11/22/13 11:35 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
297 mg/L
0.020
1
11/20/13 23:53
Nitrogen, NO2 plus NO3
297 mg/L
0.020
1
11/20/13 23:53
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 19

,�aceAnalydca(
www.pacelabs.com
Project: SS Statesville 50200
Pace Project No.: 92180335
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6M
Parameters
Lab ID: 92180336004 Collected: 11/19/13 15:30
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10
1
11/22/1311:36 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.49 mg/L
0.020
1
11/20/13 23:41
Nitrogen, NO2 plus NO3
0.51 mg/L
0.020
1
11/20/13 23:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 7 of 19

ZtVGA dQljlca'0
uvmpacelabsxom
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W6N
Lab ID: 92180335005 Collected: 11/20/13 07:45
Received: 11/20/13 16:45 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
1.1 mg/L
0.10 1
11/22/13 11:39 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
57.3 mg/L
0.020 1
11/20/13 23:46
Nitrogen, NO2 plus NO3
67.4 mg/L
0.020 1
11/20/13 23:46
Date: 11/22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 19

aceAnalytical
www.pacelabs.com
I
Project: SS Statesville 50200
Pace Project No.: 92180335
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7D
Parameters
Lab ID: 92180336006 Collected: 11/19/13 12:35
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10 1
11/22/13 11:39 7664-41-7
363.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.15 mg/L
0.020 1
11/20/13 23:40
Nitrogen, NO2 plus NO3
0.15 mg/L
0.020 1
11/20/13 23:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 19

aceAnalXicel o
vhnvpacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W7H
Parameters
Lab ID: 92180335007 Collected: 11/19/13 11:05
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qual
360.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L
0.10 1
11/22/1311:41 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
0.52 mg/L
0.020 1
11/20/13 23:31
Nitrogen, NO2 plus NO3
0.52 mg/L
0.020 1
11/20/13 23:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 10 of 19

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W7J
Lab ID: 92180335008 Collected: 11/19/13 18:25
Received: 11/20/13 16:45 Matrix: Water
Parameters
Results Units
Report Limit DF
Prepared Analyzed CAS No. Qual
360.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
3.8 mg/L
0.10 1
11/22/13 11:41 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
191 mg/L
0.020 1
11/20/13 23:45
Nitrogen, NO2 plus NO3
191 mg/L
0.020 1
11/20/13 23:45
Date: 11/22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 19

aCuMnalytical e
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K
Parameters
Lab ID: 92180336009 Collected: 11/19/13 16:25
Results Units Report Limit DF
Received: 11/20/13 16:45 Matrix: Water
Prepared Analyzed CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
3.0 mg/L
0.10 1
11/22/13 11:43 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
90.2 mg/L
0.020 1
11/20/13 23:43
Nitrogen, NO2 plus NO3
90.3 mg/L
0.020 1
11/20/13 23:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 12 of 19

�aceAnalytica(
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
ANALYTICAL RESULTS
Sample: K65W71-
Lab ID: 92180336010 Collected: 11/19/13 17:30
Received: 11/20/13 16:45 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
9.5 mg/L
0.10
1
11/2211311:43 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
94.7 mg/L
0.50
25
11/21/13 00:11
Nitrogen, NO2 plus NO3
94.7 mg/L
0.50
25
11/21/13 00:11
Date: 11 /22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 13 of 19

aceAnalytical
www.pacekbs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
QUALITY CONTROL DATA
QC Batch: WETA/17243 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92180335001, 92180335002, 92180335003, 92180335004, 92180335005, 92180335006, 92180335007,
92180335008,92180335009,92180335010
METHOD BLANK: 1092328 Matrix: Water
Associated Lab Samples: 92180335001, 92180335002, 92180335003, 92180335004, 92180335005, 92180335006, 92180335007,
92180335008,92180335009,92180335010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 11/22/1311:29
LABORATORY CONTROL SAMPLE: 1092329
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.4 107 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1092330 1092331
MS MSD
92180335001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 0.12 5 5 5.7 5.7 112 111 90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1092332 1092333
MS MSD
92179281001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 5.3 5.3 105 105 90-110 0
Date: 11/22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 19

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SS Statesville 50200
Pace Project No.: 92180335
QUALITY CONTROL DATA
QC Batch: WETA/17213 Analysis Method: EPA 353.2
QC Batch Method: EPA
353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:
92180335001, 92180335002, 92180335003, 92180335004, 92180335005, 92180335006, 92180335007,
92180335008,92180335009,92180335010
METHOD BLANK: 1090959 Matrix: Water
Associated Lab Samples:
92180335001, 92180335002, 92180335003, 92180335004, 92180335005, 92180335006, 92180335007,
92180335008,92180335009,92180335010
Blank Reporting
Parameter
Units Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L ND 0.020
11/20/13 23:22
Nitrogen, NO2 plus NO3
mg/L ND 0.020
11/20/13 23:22
LABORATORY CONTROL SAMPLE: 1090960
Spike LCS
LCS % Rec
Parameter
Units Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L 2.5 2.5
102 90-110
Nitrogen, NO2 plus NO3
mg/L 2.5 2.5
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1090961 1090962
MS MSD
92180131001 Spike Spike MS
MSD MS MSD
% Rec
Parameter
Units Result Conc. Conc. Result
Result % Rec % Rec
Limits
RPD Qual
Nitrogen, Nitrate
mg/L 0.042 2.5 2.5 2.6
2.6 100 100
90-110
0
Nitrogen, NO2 plus NO3
mg/L 0.042 2.5 2.5 2.6
2.6 100 100
90-110
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1090963 1090964
MS MSD
92180335007 Spike Spike MS
MSD MS MSD
% Rec
Parameter
Units Result Conc. Conc. Result
Result % Rec % Rec
Limits
RPD Qua]
Nitrogen, Nitrate
mg/L 0.52 2.5 2.5 3.0
3.0 99 99
90-110
0
Nitrogen, NO2 plus NO3
mg/L 0.52 2.5 2.5 3.0
3.0 99 99
90-110
0
Date: 11/22/2013 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 19

acmnalytical o
www.pacelabs.corn
d
Project: SS Statesville 50200
Pace Project No.: 92180335
DEFINITIONS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 16 of 19

aceAnalytical
www pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: SS Statesville 50200
Pace Project No.: 92180335
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92180335001
K65W6A
EPA 350.1
WETA/17243
92180335002
K65W6B
EPA 350.1
WETA/17243
92180335003
K65W6E
EPA 350.1
WETA/17243
92180335004
K65W6M
EPA 350.1
WETA/17243
92180335005
K65W6N
EPA 350.1
WETA/17243
92180335006
K65W7D
EPA 350.1
WETA/17243
92180336007
K65W7H
EPA 350.1
WETA/17243
92180335008
K65W7J
EPA 350.1
WETA/17243
92180335009
K65W7K
EPA 350.1
WETA/17243
92180335010
K65W7L
EPA 350.1
WETA/17243
92180335001
K65W6A
EPA 353.2
WETA/17213
92180336002
K65W6B
EPA 353.2
WETA/17213
92180335003
K65W6E
EPA 353.2
WETA/17213
92180335004
K65W6M
EPA 353.2
WETA/17213
92180336005
K65W6N
EPA 353.2
WETA/17213
92180336006
K65W7D
EPA 353.2
WETA/17213
92180336007
K65W7H
EPA 353.2
WETA/17213
92180335008
K65W7J
EPA 353.2
WETA/17213
92180335009
K65W7K
EPA 353.2
WETA/17213
92180335010
K65W7L
EPA 353.2
WETA/17213
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/22/2013 04:16 PM without the written consent of Pace Analytical Services, Inc.. Page 17 of 19

i [�C�yfraa/ylr �t °•I——vVvmx%mnl %itivil rvauel l Q%aUr% rd C 1 VI 4
Document Number: Issuing Authority:
F-CHR-CS-03-rev.11 race Huntersville Qualitv Office
Client Name: ALiGf�
Where Received: ��"Huntersviile ❑ Asheville ❑ Eden ❑ Raleigh
Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client[] Commercial❑ Pa O Other
J� 1-
Custody Seal on Cooler/Box Present: ❑ yes Seals intact: ❑ yes ❑ no
Packing Material: ❑ Bubble Wrap Bubble Bags ❑e ❑ Other
C) tlon-
Prof Duel Date
Prof, Name
Thermometer Used: iR Gun T1102 T1301 Type of Ice: Blue None ,r0 Samples on ice, cooling process has begun
Temp Correction Factor T1102: No Correction T1301: No Correction
Corrected Cooler Temp.: - C
Biological Tissue is Frozen: Yes No N/A
g
Date and Ini iats of person examining
contents:
Temp should be above freezing to 6°C
Comments:
Chain of Custody Present:
LIYes ❑No ❑wA
1.
Chain of Custody Filled Out:
_--BYes ❑No ❑N/A
2.
Chain of Custody Relinquished:
--ElYe"s ❑No ❑N/A
3.
Sampler Name & Signature on COC:
,�Y s ONo ❑NIA
4.
Samples Arrived within Hold Time:
--tlYes ❑No ❑N/A
5.
Short Hold Time Analysis (<72hr):
Yes
Rush Turn Around Time Requested:
❑Yes No ❑N/A
7.
Sufficient Volume:
i© rYes- ❑No ❑N/A
8.
Correct Containers Used:
/[s ❑No ❑N/A
9.
-Pace Containers Used:
/1]Yes ❑No ❑wA
Containers Intact:
/[Yes ❑No ❑N/A
10.
Filtered volume received for Dissolved tests
❑Yes ❑No.-CN/A
11.
Sample Labels match COC:
/BY s ❑No ❑N/A
12.
-Includes date/time/ID/Analysis Matrix:
All containers needing preservation have been checked.
Yes ON. ❑NlA
13,
All containers needing preservation are found to be In
Yes ❑No El NIA
compliance with EPA recommendation.
exceptions: VOA, coliform, TOC, 0&G, WI-DRO (water)
❑YeVONo
Samples checked for dechlorination:
i�Yes ❑No ❑N/A
14,
Headspace in VOA Vials >6mm):
❑Yes ❑Nv-ONIA
15,
Trip Blank Present:
i
❑Yes ❑No /❑N/A
16,
Trip Blank Custody Seals Present
❑Yes ❑No ❑K
Pace Trip Blank Lot # (if purchasedy
.�
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review:1 M V Ij L5 Date: 1-- 0'
SRF Review: /3
Note: Whenever ther Us/a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i.e out of hold, incorrect preservative, out of temp,
incorrect containers)
WO#:92180335
110110111111-1111

_ rr
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Page: of
�t+on.A Section B Section C
/;
7 3 2 9 4 0
,quared O4i:rn fans,,0M, m Required Project Information: Invoice Information:
Report To: �n �� Attention:
rra}3aaroy
'1
Ydrrs r
Copy To: /,
Company Name:
REGULATORY AGENCY
➢
Address:
r NPDES r GROUND WATER r DRINKING WATER
F UST j RCRA j OTHER
=37o: >
Purchase Order No.:
Pace Quote
Reference:
1tPYw':
Fa9C
Project Name:
Pace Project
Site Location
-
✓(
ager:
STATE:
n f
aftrP Due AT: ����
Prefect Number. ©?�©
Pace Profile #:
Requested
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0 Nitrate Results
Ammonia Results
®Nitrate 2L Standard
N m et '/1 �o n W D\ O N M 7 V1 'D l- w rn
O� O, O1 ON o, D\ 01 D\ O O O O O O O O O OC-+--.❑r
Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
8/2/95
11/8/95
Nitrate mg/1)
370
252
360
360
311
30
210
340
330
250
260
250
180
Ammonia (mg/1)
I No Data
Date
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
Nitrate (mg/1)
240
260
210
106
243
121
199
236
240
220
200
180
190
Ammonia (mg/1)
I No Data
Date
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
10/15/07
4/25/08
Nitrate (mg/1)
235
170
140
84
200
150
170
190
160
150
140
30.9
92.8
Ammonia (mg/1)
No Data
77
0.24
NS
NS
NS
0.23
NS
0.14
0.13
0.25
0.36
Date
4/9/09
10/30/09
4/6/10
10/21/10
4/22/2011
11/2/11
5/10/2012
11/7/2012
1 5/23/2013
11/20/2013
Nitrate m
152
186
135
122
118
120
162
105
124
157
Ammonia m
NS
0.10
0.16
0.19
0.30
0.33
0.24
0.88
<0.10
0.12

K65W6 B (Saprolite)
160
+Nitrate Results
140
—k Ammonia Results
---Nitrate 2L Standard
120
100
8
0
c
80
w
aoi
60
c
0
U
°.'
40
w
20
O�
N M It
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Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
3/30/99
11/3/99
Nitrate mQ 1
22
22
15
26
16
7.6
6.8
28
29
19
18
89.4
140
Ammonia m 1
No Data
Date
10/24/01
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/l/07
10/15/07
1 4/25/08
4/9/09
Nitrate m 1
78
92
40
41
44
33
35
28
23
31
31
32
40
Ammonia m I
No Data
<0.1
<0.1
<0.1
NS
NS
0.12
<0.1
<0.1
<0.1
NS
<0.1
<0.1
Date
10/29/09
4/6/10
10/22/10
4/21/11
11/1/11
5/9/2012
11/7/2012
5/23/2013
11/20/2013
Nitrate m I
55.9
34.5
30.2
26.9
38.4
34.2
39.8
59.6
28.5
Ammonia m 1
<0.1
<0.10
1.4
0.61
<0.10
<0.10
NS
0.33
0.13

K65W6 D (Saprolite)
2
0 Nitrate Results
1.5
8
a
i 1
O
V
O
U
L
z 0.5
0
T T 91
91
7 7 7
� 44
Date
Date
8/l/90
1/22/92
2/10/93
4/8/93 to 11/20/13
Nitrate m 1
0.63
0.17
0.25
Dry
Ammonia m
No Data
Dry

K65W6 M (Saprolite)
1.5
1.4
_0 Nitrate Results
1.3
-A Ammonia Results
1.2
1.1
1
0.9
C
L
0.8
d
0.7
G
U
0.6
w
0.5
Z
0.4
0.3
0.2
0.1
0
.� rr
Q
Q
Q Q Q Q
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/22/10
4/21/11
11/1/11
5/9/2012
11/6/2012
5/23/2013
11/20/2013
Nitrate m
0.44
<.10
0.15
0.16
0.28
0.14
0.37
<0.20
1.0
0.44
0.49
Ammonia m 1
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
1 <0.10
<0.10
<0.10

K65W6 N (Saprolite)
100.0
Nitrate Results
90.0
tz Ammonia Results
Nitrate 21, Standard
80.0
70.0
60.0
C
°0
50.0
i+
L
40.0
CU
C
O
U
a�
30.0
�a
w
z
20.0
10.0
0.0
00
01
Q\ ON 01
�1
�
'� rn q � ti ri q � •, rn q � �.
� q � '� � Ca
�
Date
Date
12/19/08
4/9/09
10/29/09
4/7/10
10/22/10
11/1/11
5/10/2012
11/6/2012
5/23/2013
11/20/2013
Nitrate m
16.7
61.9
82.3
67.2
66.6
tE�n
50.2
48.5
50.4
32.1
57.3
1
Ammonia m 1
6.6
3.5
1.7
1.4
1.2
0.99
0.35
0.93
1 0.18
1.1

K65W7C (Saprolite)
140
- 0 Nitrate Results
—Ammonia Results
120
—Nitrate 2L Standard
100
s
O
0
80
'C
ti
O
U
0
60
U
cam.
Z
40
20
0
j I
O
p1 Q1
N
01 01 91 O1 11 01 01 Q1 O O O O
00 O
O O O O O O
w w
w w w w w w w w w w w w
w w w w w w w w
Date
Date
2/13/90
1/22/92
2/10/93
10/17/03
7/18/05
10/28/05
4/25/08
12/19/2008 to 10/21/10
4/21/11
11/1/2011 to 11/20/13
Nitrate m
93
130
13
82
33
53
<0.10
Dry
9.4
Dry
Ammonia m
No Data
9
NS
2.3
29.4
Dry
<0.10
D

K65W7 D (Saprolite)
40
- o Nitrate Results
35
-*-Ammonia Results
-Nitrate 2L Standard
30
E
•C
25
O
i+
20
u
C
U
15
L
e+
z
10
5
0
-�► �-
O V In �o
Qi 01 01 O� O� O� C�
r` 00 0� O N M r- 00 CI' O N M
C� C� C� O O O O O O O O
Date
Date
8/l/90
1/22/92
2/10/93
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
Nitrate m
11
2
0.57
0.775
2
1
2
1.1
<0.10
1.1
2.4
1.4
0.05
Ammonia m
No Data
0.41
<0.10
Date
4/16/04
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
4/25/08
4/16/09
10/29/09
4/6/10
10/21/10
4/21/11
Nitrate m
1.3
2.4
0.48
I
2
1.1
15
39
0.48
0.21
10.10
0.22
<0.10
I
0.16
Ammonia m
<0.10
NS
NS
0.12
<0.10
1.1
2.1
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
Date
11/2/11
5/9/2012
11/6/2012
5/23/2013
11/19/2013
Nitrate m
<0.20
<0.20
<0.020
<0.020
0.15
Ammonia m
0.18
1 <0.10 i
<0.10
I <0.10
I <0.10

K65W7 F (Saprolite)
200
Nitrate Results
180
—Ammonia Results
—Nitrate 21, Standard
160
140
6
a
G 120
0
a 100
d
U
O
U 80
w
z 60
40
20
0
d
0 .� N m n oo rn O N m d' v')
rn rn rn rn rn a rn rn o 0 0 0 0 0 0 0 0 0
7 7 7 7
Date
Date
8/1/90
1/22/92 1
4/16/92
J 7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
2/8/96
5/9/96
Nitrate m
99
100
109
79
79
110
100
100
96
1.6
94
150
6.1
Ammonia m
No Data
Date
3/28/00
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
Nitrate m
5.1
0.52
20
33
17
3
21
8.5
<0.1
20
31
31
15
Ammonia m
No Data
<0.10
NS
<0.10
NS
NS
NS
0.12
1.1
Date
4/25/08
4/9/09
10/29/09
4/6/10
1 10/21/10
4/21/11
1 11/l/Il
j 5/9/12
j 11/6/12
1 5/23/2013
j 11/19/2013
Nitrate m
61.9
33.6
Dry
9.2
30.7
6.7
Dry
Dry
10.7
4.1
NS
Ammonia m
<0.10
<0.10
Dry
<0.10
<0.10
<0.10
Dry
Dry
<0.10
<0.10
NS

K65W7 G (Saprolite)
40
+Nitrate Results
— * Ammonia Results
—Nitrate 2L Standard
30
E
C
C
O
it
20
d
C
O
U
d
w
z 10
h 00 N M
Qi Q1 91 C� C, O, C1 C� C� T O O O C� O O O O
Date
Date
8/l/90
1/22/92
2/10/93
2/8/96
11/3/99
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
7/03
10/28/04
7/18/05
Nitrate m I
1.7
1.9
2.6
3.5
2.9
3.6
2.8
31
32
1.3T5,0
.4
4.4
1.7
Ammonia m
No Data
<0.10.10
NS
NS
Date
4/25/06
10/23/06
5/1/07 to 4/6/10
10/21/10
1 4/21/11
11/1/11
5/9/12
11/6/12
5/23/2013
11/19/2013
Nitrate m l
16
29
Dry
3.3
D
D
D
6.2
1.7
NS
Ammonia m l
<0.10
4
D
<0.10
Dry
Dry
Dry
<0.10
<0.10
NS

K65W7 J (Saprolite)
300
0 Nit ate Results
*Ammonia Results
®Nitrate 2L Standard
250
200
a
c
0
ce
150
a
0
U
100
z
50
00 W
O O O O O O O O O O
S
w H w a
O Q O O Q O Q O d O d O Q O Q O O
Date
Date
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
10/15/07
1 4/25/08
12/18/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m 1
100
140
74
150
180
140
14.4
178
204
191
199
157
172
Ammonia m 1
NS
NS
<0.10
<0.10
<0.10
0.10
0.6
0.86
0.79
1.7
1.7
1.4
2.2
Date
4/21/11
11/2/11
1 5/10/2012
11/7/2012
5/23/2013
11/19/2013
Nitrate m l
162
184
134
185
187
191
Ammonia m I
3.3
2.8
4.2
2.2
2.5
3.8

350
300
250
en
8
C
200
O
r;
CQ
L
150
a
0
U
a�
i
100
.,
z
50
oNitrate Results
-+Ammonia Results
-Nitrate 2L Standard
K65W6 E (Bedrock)
0
b r` 00 Ci.N-
01 O� O� O O O O O O O O I:?O
Date
Date
8/1/90
1/22/92
2/10/93
8/2/95
11/8/95
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
Nitrate m
7.3
37
27
4.4
5
56
7.9
8.5
11.7
24.1
30.9
49.9
50.4
Ammonia m
No Data
Date
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
Nitrate m
56
67
68
62
78
81
76
62
60
90
100
120
I
150
Ammonia m
No Data
<0.10
<0.10
<0.10
NS
NS
<0.10
Date
4/26/06
10/23/06
5/l/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/6/10
10/22/10
4/22/11
11/2/11
5/10/2012
Nitrate m I
140
150
150
14.2
169
202
253
1
44.4
1
243
203
311
278
181
Ammonia m
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
0.5
<0.10
1.7
0.62
1.6
1.8
0.33
Date 11
11/7/12
5/23/2013
11/20/2013
Nitrate m 1
223
196
297
Ammonia m
1.2
0.56
1.6

K65W7 H (Bedrock)
1
t Nitrate Results
0.9
-,� Ammonia Results
0.8
0.7
E
C
e
0.6
0
L
0.5
U
C
O
U
d
0.4
R
w
Z
0.3
0.2
0.1
0
r-�T-r�-r-T �r-r-
00
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/21/10
4/21/11
11/1/11
5/9/2012
1 11/6/2012
1 5/23/2013
11/19/2013
Nitrate m 1
0.30
0.26
0.36
0.47
0.36
0.40
0.36
0.72
0.54
0.74
0.52
Ammonia m l
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
I <0.10
I <0.10
<0.10

K65W7 K (Bedrock)
200
o Nitrate Results
180
Ammonia Results
®Nitrate 21, Standard
160
140
6
120
e
0
w
100
fl
0 80
U
60
z
40
20
O ¢ O f' O O ° O d O Q O Qa O Q� O Q O
Q Q Q Q
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/1/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m 1
81
89
190
100
120
89
25.9
99.5
108
95.4
99.4
77.4
84.6
Ammonia m 1
NS
NS
4.1
3.7
11
4.5
4.2
4.8
4.1
4.2
3.6
3.6
3.8
Date
4/21/11
11/2/11
1 5/10/2012
1 11/7/2012
1 5/23/2013 1
11/19/2013
Nitrate m 1
92.3
85.3
87.1
85.6
86.7 1
90.2
Ammonia m 1
2.8
2.7
2.6
2.3
2.8 1
3.0

K65W7 L (Bedrock)
200
Nitrate Results
180
—hAimnonia Results
—Nitrate 2L Standard
160
rl 140
0�8
F 120
c
0
100
�j 80
w
ca
60
z
40
20
0
O O O O
O d d Q O d d
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
1 10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m I
22
98
110
130
120
99
30.5
104
103
93.8
103
85.7
95.2
Ammonia m 1
NS
NS
7.7
7.4
11
111
12.9
12.4
10.4
10.1
9.4
9.0
12.8
Date
4/21/11
11/2/11
5/10/2012
11/7/2012
5/23/2013
11/19/2013
Nitrate m l
96.4
1 116
94.9
97.8
94.5
94.7
Ammonia m 1
7
1 12
10.7
4.9
9.5
9.5

GARAGE
I
OFFICE
I
O
r
I
x
0
Purina Feed Mill Property
K65W6E
Former % �� Treatment System -Pumping Station
pone K65�W66
6�ap
K65W6A
Water -Supply Wells
STORAGE ® for Plant Operations
a DU O RW-5r EB
'ff❑ (NOT IN USE)
ffFHl+�uu,�_u-.„...,,,.,,,,,............. (IN USE)
STATESVILLE
FERTILIZER.
PLANT
Legend
0
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
®
Property Line
H 1 H hi
Railroad Tracks
Locations of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
K65W7K K65WK65W6M
� K65W7J
® ® 6D0
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` J FORMERPOND
\
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FORMER I 1 NO.2
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7
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iI Properties
i
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0 250' 500'
0
z
w
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I Figure
ON

Purina Feed Mill Property
K65W6E
Poi d A K84781) 65W66 F�dB
r % ~®e ❑ Treatment System -Pumping Station
�i�� � P K65W6A Water -Supply Wells
GARAGE 1� (837.31) STORAGE A for Plant Operations I
Q i
RW-5r '
El
o O (NOT IN USE) ®SE I
STATESVILLE
FERTILIZER.
PLANT
Legend
Saprolite Monitoring Well
® Bedrock Monitoring Well
® Recovery Well
Property Line
F Railroad Tracks
(832.06) Water -table Elevation in Feet
Potentiometric Elevation Contour
(Displayed in 10-foot Intervals)
��- Groundwater Flow Direction
Note: Type Ill Wells Were Not Used
for Potentiometric Contouring
Locations of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
:M1
=I
(831.92)\
830
820
DRY
' K65W7K
5W7J ®®
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FO R \
( POND
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I POND
FORMER I NO.2
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I
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Residential
Properties
i
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(781.60)
K65W7F
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K65W7G
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K65W7C /K65W7H —
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0 250' 500' I 4

GARAGE
I
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0
r
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Purina Feed Mill Property
(848.18) K65W6E
Former / 0 —Treatment System -Pumping Station
Pond A ^ K65W66QrF�ormar
® K65W6A
(838.69) Water -Supply Wells
STORAGE �a 0®for Plant Operations
RW-5r
0(NOT IN USE)IN USEw 1..i......1—=...... - ( )
STATESVILLE
FERTILIZER.
PLANT
Legend
0 Saprolite Monitoring Well
® Bedrock Monitoring Well
® Recovery Well
® Property Line
Railroad Tracks
(832.06) Water -table Elevation in Feet
Potentiometric Elevation Contour
(Displayed in 10-foot Intervals)
--� Groundwater Flow Direction
Note: Type 11I Wells Were Not Used
for Potentiometric Contouring
Locations of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
840
01
K65W6 )
(832.39) \
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1
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POND
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Residential
Properties
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DRY
DRY K65W7F
K65W7G
® RW-2, ®l
K65W7C /K65W7H
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K65W7V
®(787.75)
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Residential
STATESVILLE Properties
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Saprolite Monitoring Well
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Bedrock Monitoring Well
®
Recovery Well
~�
Property Line
-H H+I+
Railroad Tracks
(NS)
Not Sampled
(48.5)
Nitrate Concentration in mg/L
Nitrate Isoconcentration Line
Dashed where inferred
Locations of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
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®
Bedrock Monitoring Well
®
Recovery Well
Property Line
Railroad Tracks
(NS)
Not Sampled
(48.5)
Nitrate Concentration in mg/L
f"\
Nitrate Isoconcentration Line
Dashed where inferred
Locations of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
:65W7L A RW-6
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GARAGE
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r.. / 165� � IN, e \ r
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Legend
10
Saprolite Monitoring Well
®
Bedrock Monitoring Well
®
Recovery Well
\
Property Line
H+H+
Railroad Tracks
(NS)
Not Sampled
(48.5)
Nitrate Concentration in mg/L
f'\
Nitrate Isoconcentration Line
Dashed where inferred
Locations
of Ponds A and B are approximate
and based on CAP data (1994 Canonie)
1
50
100
\
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K65 7K K W6D KK65W6M
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APR 2 5 2013
2012 Annual Groundwater Monitoring. and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
Prepared for
Mr. Vance Dann
Southern States Cooperative, Inc.
Post Office Box 26234
Richmond, Virginia 23260
[phone]
Submitted to
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue
Suite 301
Mooresville, North Carolina 28115
Prepared by
Duncklee & Dunham, P.C.
511 Keisler Drive, Suite 102
Cary, North Carolina 27518
April 23, 2013
DUNCKLEE & DUNHAM, P.C.

DUNCKLEE
l_I
& DUNHAM
1
April 23, 2013
ENVIRONMENTAL GEOLOGISTS & ENGINEERS
511 KEISLER DRIVE — SUITE 102
CARY, NORTH CAROLINA 27518
OFFICE: [phone]
W W W.DUNCKLEEDUNHAM.COM
Mr. Andrew Pitner, P.G.
North Carolina Department of Environment and Natural Resources
Division of Water Quality, Aquifer Protection Section
Mooresville Regional Office
610 East Center Avenue, Suite 301
Mooresville, North Carolina 28115
Reference: 2012 Annual Groundwater Monitoring and Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant, Statesville, North Carolina
Groundwater Incident Number: 5038
Dear Mr. Pitner:
As requested by Southern States Cooperative, Inc. (Southern States), Duncklee & Dunham, P.C. is
pleased to submit this 2012 Annual Groundwater Monitoring and Treatment System Effectiveness Report
for the above referenced site. This report discusses the work performed and the conclusions derived from
sampling and monitoring performed during this period.
If you have any questions or require additional information, please do not hesitate to contact
Mr. Jayson Kilcoyne at [phone] ([e-mail]) or Mr. Vance Dann of
Southern States at [phone] ([e-mail]).
Sincerely,
Duncklee & Dunham, P.C.
Jayson A. Kilcoyne
Project Environmental Scientist II
Senior Peer Review:
A4/12f pt
3T"& 5�'
Bryson D. Trexler, Jr., Ph.D., P.G.
Senior Hydrogeologist
603��'Z_
Thomas S. Dunham, P.G.
Senior Geologist
cc: Mr. Vance Dann — Southern States Cooperative, Inc. (e-copy)
R\Southern States\Statesville Fertilizer - 50200\Reports\2012\Annual GW Monitoring Report - 12360.doc
M
1 SEAL z
1924 $
�1v7�
MAILING ADDRESS — POST OFFICE BOX 639 — CARY, NORTH CAROLINA 27512
NORTH CAROLINA BOARD OF EXAMINERS FOR ENGINEERS AND SURVEYORS LICENSE C-3559
NORTH CAROLINA BOARD FOR LICENSING OF GEOLOGISTS LICENSE C-261
NC DENR REGISTERED ENVIRONMENTAL CONSULTANT NUMBER 00061

1
2
3
4
1
2
3
4
5
6
7
8
9
Table of Contents
Introduction
1.1 Site Location, Description and History
1.2 Summary of Remedial Actions
Groundwater Treatment System Monitoring Activities
Groundwater Sampling Activities and Results
3.1 Groundwater Sampling Methodology
3.2 Results from 2012 Sampling Events
3.2.1 Nitrate Results and Trends
3.2.2 Ammonia Results and Trends
Recommendations
Figures
Site Location Topographic Map
Site Map
Treatment System Discharge Line Outfall Map
Potentiometric Map - May 2012
Potentiometric Map - November 2012
Shallow Aquifer Nitrate Isoconcentration Map - May 2012
Deep Aquifer Nitrate Isoconcentration Map - May 2012
Shallow Aquifer Nitrate Isoconcentration Map - November 2012
Deep Aquifer Nitrate Isoconcentration Map - November 2012
Tables
1 Summary of 2012 Well Water Level Gauging Data
2 Summary of 2012 Groundwater Analytical and Field Parameter Results
Appendices
A May and November 2012 Laboratory Analytical Reports
B Nitrate in Groundwater Trend Graphs
1
1
1
2
2
2
3
3
4
4

2012 Annual Groundwater Monitoring and
Treatment System Effectiveness Report
Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina
1 Introduction
1.1 Site Location, Description and History
The Southern States Cooperative, Inc. (Southern States) fertilizer plant (the site) is located at
2582 Salisbury Highway (old US Highway 70) approximately six miles east of Statesville, North Carolina
(Figure 1). The site consists of several buildings including a fertilizer manufacturing building, an office
building, and several small support buildings (Figure 2). The site is utilized for the manufacturing,
storage, and distribution of fertilizer.
The site is bordered to the north by old US Highway 70, commercially developed parcels to the east,
residential properties to the south, and undeveloped land to the west. The US Highway 70 Bypass (70
Bypass) bisects east to west through the southern portion of the site and separates approximately 13 acres
from the main property (Figure 2).
Groundwater at the site has been impacted by a release of liquid ammonium nitrate from several former
surface water impoundments. Two impoundments (Former Pond No. 1 and No. 2) were located
approximately 1,000-feet southwest of the main plant (Figure 2). Two additional surface water
impoundments (Former Ponds A and B, Figure 2) were located east and southeast of the main plant.
These impoundments are referenced in the Corrective Action Plan (CAP) dated January 28, 1994,
submitted by Canonie Environmental Services, Inc. to the North Carolina Department of Environment
and Natural Resources (DENR), Division of Water Quality (DWQ), Aquifer Protection Section (APS). In
1994 the APS approved the CAP. Based on the CAP, the assessment and impact of groundwater
contamination was defined with reasonable certainty.
The objectives of the CAP were to remediate groundwater and to prevent off -site migration of the
groundwater contamination plume. To monitor the effectiveness of the CAP, a groundwater sampling
plan was developed that established semiannual (April and October) groundwater monitoring. The annual
groundwater monitoring reports cover the period from November 1 through March 31.
1.2 Summary of remedial Actions
To reduce the levels of nitrate and ammonia in the groundwater, three recovery wells (RW-2, RW-5 and
RW-6) were installed as part of the CAP. However, RW-5.was taken out of service prior to 2005 due to
low or no groundwater recovery and replaced with RW-5r in September 2008. The recovery wells pump
groundwater into a treatment system where the pH is adjusted with a caustic solution prior to being
discharged into Fourth Creek (Figure 3).
The groundwater treatment system is permitted under the National Pollution Discharge Elimination
System (NPDES) program. Under the program, bi-monthly site visits are conducted when the system is
operational to monitor the treatment system and to be sure it is operating within the permitted discharge
limits. Effluent water samples are collected bi-monthly and the data is reported to the DWQ on monthly
Discharge Monitoring Reports.
DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. - Statesville Fertilizer Plant
2012 Annual Groundwater Monitoring and Treatment System Effectiveness Report
April 23, 2013
Page 2 of 4
Groundwater Treatment System Monitoring Activities
The groundwater remediation system operated during this reporting period from October 25, 2011, to
June 7, 2012, when the system was shut off for the summer months. In accordance with the NPDES
permit, a North Carolina licensed Grade I Wastewater Operator (operator) collected effluent samples bi-
monthly for analysis of total suspended solids (TSS) according to Method 2540D and ammonia nitrogen
according to EPA Method 350.1. The operator also collected monthly effluent samples for copper (EPA
Method 200.7), chloride (Method SM 4500-C1-E), TSS, ammonia nitrogen, total Kjeldahl nitrogen,
nitrate nitrogen and phosphorus all by EPA Method 300 series. The samples were submitted for
laboratory analysis to Pace Analytical Services, Inc. (Pace), a North Carolina certified analytical
laboratory. Discharge monitoring reports (DMRs) were submitted monthly to DENR as required by the
NPDES permit. DMRs were not submitted between July and October 2012, while the system was not
operational. The system was restarted by the operator on November 5, 2012, and operated until April 4,
2013, when it was shut down for the summer months.
3 Groundwater Sampling Activities and Results
Semiannual groundwater monitoring activities were conducted by Duncklee & Dunham personnel on
May 9 to 10, 2012, and November 6 to 7, 2012. Potentiometric maps illustrating the shallow groundwater
flow for the May and November sampling events are shown on Figures 4 and 5, respectively. The
groundwater flow direction during both events was to the south-southwest. During the May 2012
monitoring event the average hydraulic gradient was 0.032 ft/ft. The average hydraulic gradient was
0.028 ft/ft during the November 2012 monitoring event. The K65W7J well casing was damaged in 2011
and therefore not included in the groundwater flow calculation due to a change in the top of casing
elevation. The well will be re -surveyed and included in the next annual report.
3.1 Groundwater Sampling Methodology
Prior to well purging and sampling, water -level measurements were collected by Duncklee & Dunham
using an electric water level probe and recorded on field sampling data sheets. The groundwater -level
measurement data are summarized on Table 1.
Duncklee & Dunham personnel collected groundwater samples from ten (K65W6A, K65W613, K65W6E,
K65W6M, K65W6N, K65W7D, K65W711, K65W7J, K65W7K and K65W7L) of the fourteen
monitoring wells during the May 2012 sampling event. The four remaining monitoring wells (K65W6D,
K65W7C, K65W7F, and K65W7G) were dry during this event.
We collected groundwater samples from twelve (K65W6A, K65W613, K65W6E, K65W6M, K65W6N,
K65W7D, K65W7F, K65W7G, K65W711, K65W7J, K65W7K, and K65W7L) of the fourteen monitoring
wells during the November 2012 sampling event. The two remaining monitoring wells (K65W6D and
K65W7C) were dry.
The sampling process consisted of inserting a two-inch submersible electric PVC pump with new
disposable polyethylene tubing in each well or a peristaltic pump with new tubing to purge and withdraw
the samples. The groundwater samples were collected using low flow sampling techniques. During the
sampling process, field measurements were collected for dissolved oxygen (DO), oxidation reduction
potential (ORP), pH, temperature, turbidity, and electrical conductivity (Table 2).
_ _ DUNCKLEE & DUNHAM, P.C.

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2012 Annual Groundwater Monitoring and Treatment System Effectiveness Report
April 23, 2013
Page 3 of 4
The groundwater samples were pumped directly into the laboratory -provided containers, labeled,
recorded on a chain -of -custody form, and transported to the analytical laboratory in an insulated cooler
filled with ice. The samples were submitted to Pace and analyzed for nitrate according to EPA Method
353.2 and ammonia nitrate according to EPA Method 350.1. The laboratory analytical reports and chain
of custody records for both sampling events are included in Appendix A.
3.2 Results from 2012 Sampling Events
3.2.1 Nitrate Results and Trends
Groundwater nitrate isoconcentration maps for the shallow saprolite and deep bedrock monitoring wells
are presented on Figures 6 through 9. A summary of the 2012 nitrate results are listed on Table 2 and
graphs of the nitrate trends over time are included in Appendix B.
The following observations were made with respect to the nitrate plume for this groundwater monitoring
period.
171 • The saprolite monitoring well K65W6A located near the former Pond B (Figures 6 and 8) showed an
increase in nitrate level during the May 2012 event and a decrease during the November 2012 event,
but remain within the historical concentration range. Nitrate levels in saprolite monitoring well
K65W6B, located near the former Pond A, also decreased in May and increased in November and
remained within the wells historical concentration range. Both of these wells contain nitrate
concentrations greater than the North Carolina groundwater standard (2L standard) of 10 mg/L.
• Nitrate was detected in the November 2012 sample collected from the saprolite well along the
southeastern edge of the plume (K65W6M) at its highest level since the well was constructed in 2008.
The nitrate level still remains well below the 2L standard.
• The saprolite well along the northwestern edge of the plume (K65W6N) has contained nitrate above
the 2L standard since it was installed in 2008. After an initial increasing nitrate trend, the levels
decreased and have stabilized since November 2011.
• The saprolite well K65W7J located in the core of the plume contains nitrate above the 2L standard.
The nitrate level in this well has remained relatively constant with apparent seasonal fluctuations
since November 2007.
• Both of the two saprolite plume wells at the southern extent of the plume, K65W7G and K65W7F,
were dry during the May event. During the November event K65W7G contained nitrate at a level of
6.2 mg/L, while K65W7F contained nitrate at 10.7 mg/L.
• The saprolite plume delineation well (K65W7D), located in the southwest portion of the site, did not
contain nitrate in groundwater above laboratory reporting limits in May and November 2012.
• Saprolite monitoring well K65W7C was dry during the 2012 monitoring period.
• Groundwater in the bedrock monitoring well K65W6E exhibited a decrease in nitrate in May 2012
though the nitrate level increased in November 2012. However, the nitrate level remains above the
2L standard and the overall nitrate concentration trend remains upward in this well.
• The two bedrock wells (K65W7K and K65W7L) located in the core of the plume contain nitrate
above the 2L standard. The nitrate concentrations in these wells have remained consistent since April
2008.
DUNCKLEE & DUNHAM, P.C.
i

Southern States Cooperative, Inc. — Statesville Fertilizer Plant
2012 Annual Groundwater Monitoring and Treatment System Effectiveness Report
April 23, 2013
Page 4 of 4
• The bedrock delineation well (K65W7H) at the southern extent of the plume has not contained nitrate
above the 2L standard since it was installed in 2008.
3.2.2 Ammonia Results and Trends
The ammonia results for this report period are listed on Table 2 and graphs of the ammonia trends over
time are included in Appendix B. The following observations were made with respect to the ammonia
results.
• The saprolite well K65W7J located in the core of the plume contained ammonia above the North
Carolina 2L groundwater standard of 1.5 mg/L. The ammonia level in this well went above the
groundwater standard in April 2009 and has remained above since.
• Ammonia was detected during this monitoring period at concentrations below the 2L Standard in
` saprolite wells K65W6A, K65W6B, and K65W6N.
--' • The bedrock wells located in the core of the plume (K65W7K and K65W7L) contain ammonia above
the 2L standard. The ammonia concentration in K65W7K remained constant during the 2012
monitoring period and decreased in K65W7L during the November 2012 monitoring event.
• -Ammonia has not been detected in the downgradient plume delineation bedrock well (K65W7H) in
the southwestern portion of the site since it was installed in 2008.
4 Recommendations
Based on the information presented above, Duncklee & Dunham recommends the following:
• Continue to operate the groundwater treatment system in accordance with the CAP and NPDES
permit between November and April.
• Continue semiannual groundwater plume monitoring.
• Re -survey the K65W7J well casing damaged in 2011 and include in the 2013 annual report.
DUNCKLEE & DUNHAM, P.C.

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Source Map: U.S. G.S. Statesville East 7.5-Minute Quadrangle.
Approximate Scale: Title:
DUNCKLEE & DUNHAM, P.C. 1" = 2000' Site Location Topographic Map
ENVIRONMENTAL GEOLOGISTS & ENGINEERS
511 KEISLER DRIVE - SUITE 102 Figure: Project.
--- - cARY, NORTH CAROLINA 27518 1 Southern States Cooperative, Inc.
Statesville Fertilizer Plant
Statesville, North Carolina

Inches
0 1 2
0 0.25 0.5
Miles
Sowce of base map: Canonie Environmental Conective Action Plan - January 1994
JVGUU
Drawing ize
Ifigure
8.5 x I
3
Scale
Date
1 "= 0.25 miles
12-2012
Title
Treatment System Discharge Line Outfall Map
Project Southern States Fertilizer Plant
Statesville, North Carolina

Table 1
Summary of 2012 Well Water Level Gauging Data
Southern States, Statesville, North Carolina
Wells
Aquifer
Date
TOC
Elevation
Total
Well
Depth (ft)
Depth to
Water Table
(ft bmte
Water Table
Elevation
ft MSL
K65W6A
Sap
05/09/12
864.52
58
29.48
835.04
11/06/12
28.46
836.06
K65W6B
Sap
05/09/12
871.55
30
25.20
846.35
11/06/12
25.18
846.37
K65W6D
Sap
05/09/12
846.37
38
DRY
DRY
11/06/12
DRY
DRY
K65W6E
BR
05/09/12
864.89
133
30.70
834.19
11/06/12
29.35
835.54
K65W6M
Sap
05/09/12
837.84
50
42.80
795.04
11/06/12
39.00
798.84
K65W6N
Sap
05/09/12
845.30
50
13.24
832.06
11/06/12
17.74
827.56
K65W7C
Sap
05/09/12
809.72
22
DRY
DRY
11/06/12
DRY
DRY
K65W7D
Sap
05/09/12
800.64
23
13.04
787.60
11/06/12
13.83
786.81
K65W7F
Sap
05/09/12
796.15
28
DRY
DRY
11/06/12
20.82
775.33
K65W7G
Sap
05/09/12
795.98
15
DRY
DRY
11/06/12
14.79
781.19
K65W7H
BR
05/09/12
796.07
112
17.33
778.74
11/06/12
11.78
784.29
K65W7J
Sap
05/09/12
851.25*
60
46.23
NA
11/06/12
46.52
NA,
K65W7K
BR
05/09/12
852.30
121
48.47
803.83
11/06/12
47.60
804.70
K65W7L
BR
05/09/12
848.14
200
47.37
800.77
11/06/12
46.54
1 801.60
Notes:
TOC - top of casing
SL - mean sea level
DRY - well was dry during this sampling event
* Well casing repaired and no longer at the surveyed elevation
t bmic -feet below marked top of casing
Aquifer Code - Represents aquifer being monitored at this well location (Sap.=Saprolite and BR=Bedrock)
All measurements are in feet
A - Not Applicable
P:\Southern States\Statesville Fertilizer - 50200\Excel\Current Annual Report tables\Annual Report Tables

Table 2
Summary of 2012 Groundwater Analytical and Field Parameter Results
Southern States, Statesville, North Carolina
Laboratory Data
Field Parameters
Ammonia
Nitrate
pH
Temp.
Conductivity
Turbidity
ORP
DO
Well #
Date
mg/L
mg/L
Standard
Units
Degrees
Celsius
MS/cm
NTUs
mV
mg/L
2L Standard
1.5
10
LL /12
0.24
162
6.03
17.14
3.214
7.2
156.6
0.57
K65W6A
11/07/12
0.88
105
NM
NM
NM
NM
NM
NM
05/09/12
<0.10
34.2
3.53
16.84
0.821
2.3
461
6.53
K65W613
11/07/12
NS
39.8
4.03
15.98
0.842
0.8
210.9
4.13
05/09/12
NS
NS
NM
NM
NM
NM
NM
NM
K65W6D
11/06/12
NS
NS
NM
NM
NM
NM
NM
NM
05/10/12
0.33
181
7.77
16.74
3.827
0.3
44.1
0.34
K65W6E
11/07/12
1.2
223
8.07
16.31
3.986
3.5
68.5
0.19
05/09/12
<0.10
<0.20
4.45
15.38
0.061
2.7
303.7
8.29
K65W6M
11/06/12
<0.10
1.0
5.83
15.24
0.062
8.0
164.8
7.79
05/10/12
0.35
48.5
6.71
15.60
1.144
98
130.8
0.82
K65W6N
11/06/12
0.93
50.4
6.82
14.89
1.037
320
133.2
0.25
05/09/12
NS
NS
NM
NM
NM
NM
NM
NM
K65W7C
11/06/12
NS
NS
NM
NM
NM
NM
NM
NM
05/09/12
<0.10
<0.20
3.16
13.83
0.057
0.0
418.5
2.39
K65W7D
11/06/12
<0.10
<0.020
4.94
14.46
0.060
8.0
137
0.30
05/09/12
NS
NS
NM
NM
NM
NM
NM
NM
K65W7F
11/06/12
<0.10
10.7
6.34
13.96
0.265
3.6
93.6
3.23
05/09/12
NS
NS
NM
NM
NM
NM
NM
NM
K65W7G
11/06/12
<0.10
6.2
NM
NM
NM
NM
NM
NM
22/09/12
<0.10
0.72
5.32
14.75
0.091
0.00
226
7.97
K65W7H
11/06/12
<0.10
0.54
6.59
14.34
0.094
1.95
109.4
5.83
05/10/12
4.2
134
5.41
15.25
1.493
29
202.9
0.47
K65W7J
11/07/12
2.2
185
5.89
15.23
1.884
24
137
0.21
05/10/12
2.6
87.1
6.43
14.87
1.284
12
191.6
0.70
K65W7K
11/07/12
2.3
85.6
6.80
15.02
1.360
1.7
169.1
0.19
05/10/121
10.7
94.9
5.66
14.88
1.337
32
197.1
0.50
K65W7L
11/07/121
4.9
97.8
5.98
14.81
1.369
1.0
161.6
0.17
Notes:
Bold indicates above the laboratory method detection limit
Bold and shaded indicates a 2L Standard exceedence
S- not sampled - dry well
- low flour parameters not measured
mS/cm - milli-Siemins per centimeter
Us - nephelolometric turbidity units
mV - milli -volts
/L - milli rams perliter
\\boss\files\Projects\Southem States\Statesville Fertilizer - 50200\Excel\Current Annual Report tablesWnnual Report Tables

acmnalytical
www.pacelabs.com
May 18, 2012
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on May 09, 2012. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Renee Spencer
[e-mail]
Project Manager
Enclosures
J �5RF�\
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 11
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acmnalytical
.pacebbs com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
CERTIFICATIONS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804 South Carolina Certification #: 99030001
Florida/NELAP Certification #: E87648 Virginia Certification #: 00072
Massachusetts Certification #: M-NC030 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 Virgina/VELAP Certification #: 460147
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 11
2of13

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
I
SAMPLE ANALYTE COUNT
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92118209001
K65W7D
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
92118209002
K65W7H
EPA350.1
DMN
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92118209003
K65W6M
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
92118209004
K65W6B
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS Page 3 of 11
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without the written consent of Pace Analytical Services, Inc..
3of13

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�CqMaocal 205 East Meadow Road - Suite 2225 Riverside -Dr.
WNW.P3097abs.com Eden, NC 27288 Asheville, NC 28804
t [phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7D Lab ID: 92118209001 Collected: 05/09/12 11:10 Received: 05/09/12 16:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/18/12 01:30 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate ND mg/L 0.20 1 05/10/12 02:33
Date: 05/18/2012 10:46 AM REPORT OF LABORATORY ANALYSIS Page 4 of 11
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
4of13

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7H Lab ID: 92118209002 Collected: 05/09/12 12:20 Received: 05/09/12 16:35 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 05/18/12 01:30 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 0.72 mg/L 0.20 1 05/10/12 02:34
Date: 06/18/2012 10:46 AM REPORT OF LABORATORY ANALYSIS Page 5 of 11
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without the written consent of Pace Analytical Services, Inc..
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Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
MNXical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
ww.pacerabs,ccm
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 92118209
Sample: K65W6M
Lab ID: 92118209003 Collected: 05/09/12 14:50
Received: 05/09/12 16:35
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
05/18/12 01:31 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
ND mg/L 0.20 1
05/10/12 02:35
Date: 05/18/2012 10:46 AM REPORT OF LABORATORY ANALYSIS Page 6 of 11
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
[• a Etc]

®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: SS-STATESVILLE
FERT 50200
Pace Project No.: 92118209
Sample: K65W6B
Lab ID: 92118209004 Collected: 05/09/12 15:35
Received: 06/09/12 16:35
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua]
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
05/18/12 01:32 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
34.2 mg/L 2.0 10
05/10/12 02:55
Date: 05/18/2012 10:46 AM REPORT OF LABORATORY ANALYSIS Page 7 of 11
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pecelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
QC Batch: WETA/12146
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92118209001, 92118209002, 92118209003, 92118209004
METHOD BLANK: 765809
Matrix: Water
Associated Lab Samples: 92118209001, 92118209002, 92118209003, 92118209004
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10
05/18/12 01:14
LABORATORY CONTROL SAMPLE:
765810
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 5.3
106
90-110
MATRIX SPIKE SAMPLE:
765811
92117505001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
0.18 5
5.5
106
90-110
MATRIX SPIKE SAMPLE:
765813
92117816001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5
4.9
97
90-110
SAMPLE DUPLICATE: 765812
92117505001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
0.18 0.18
4
SAMPLE DUPLICATE: 765814
92117816001 Dup
Parameter
Units
Result Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND ND
Date: 05/18/2012 10:46 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 11
8of13

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
QC Batch: WETA/12098 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92118209001, 92118209002, 92118209003, 92118209004
METHOD BLANK: 761881 Matrix: Water
Associated Lab Samples: 92118209001, 92118209002, 92118209003, 92118209004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.20 05/10/12 01:59
LABORATORY CONTROL SAMPLE: 761882
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 5 5.1 103 90-110
MATRIX SPIKE SAMPLE:
761883
92118022001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND
5
5.3
106
90-110
MATRIX SPIKE SAMPLE:
761885
92118120002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND
5
5.3
105
90-110
SAMPLE DUPLICATE: 761884
92118022001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
SAMPLE DUPLICATE: 761886
92118120002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
Date: 05/18/2012 10:46 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 11
9of13

ce
cal
ces, Inc.
a205 East Meadow Road'- SuiteA
�aceal�ftica
www.pem?abs.com Eden, NC 27288
[phone]
QUALIFIERS
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
DEFINITIONS
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
Date: 05/18/2012 10:46 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 11
10 of 13

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: SS-STATESVILLE FERT 50200
Pace Project No.: 92118209
Lab ID Sample ID QC Batch Method QC Batch
92118209001
K65W7D
EPA 350.1
WETA/12146
92118209002
K65W7H
EPA 350.1
WETA/12146
92118209003
K65W6M
EPA 350.1
WETA/12146
92118209004
K65W6B
EPA 350.1
WETA/12146
92118209001
K65W7D
EPA 353.2
WETA/12098
92118209002
K65W7H
EPA 353.2
WETA/12098
92118209003
K65W6M
EPA 353.2
WETA/12098
92118209004
K65W6B
EPA 353.2
WETA/12098
Date: 05/18/2012 10:46 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Analytical Method Batch
Page 11 of 11
11 of 13

1!;ZeAnalyticalo
CHAIN -OF -CUSTODY i Analytical Request Documen
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
r wwpaceiaus.cum,
Section A Section B Section C
Required Client Information: Required Project Information_: Invoice Information:
Page. 6 . `
1565289: .
Company: Report
To:
Attention:
'
Address:
N+�
To:
Company Name:
il('N(}i
t
R
7
'•
Address:
j- • :NPDE
r UST
ROUND WATER I. DRINKING WATER
(- RCRA ( OTHER
Email To: Purchase
u
Phone:o l� Project
Order No.:
wyl
Pace Quota
Reference:
Name: +
Pace Project
Manager.
$Ite Lpca;i
n
Requested Due Date/TAT: < Project
Numb
Pens Profile Al,
Requested
Ang(ys(s
Fj
erecj
(Y/iJ)
#
_
Section D Matrix Codes
Required Client information MATRIX I CODE
Drinking Water DW
Water WT
Water WIN waste
Product P
Soil/Solid SL
SAMPLE ID OOL
ipe WP
(A-Z. 0-9 / r) Air AR
Sample IDs MUST BE UNIQUE Tissue' TS
Other OT
8
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Preservatives
2:
COMPOSITE
START
COMPOSITE
END/GRAB
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Pace Proje t N .1 Lab I.D.
DATE
TIME
DD4ATTE .
. TIME
=
a
1,V10AA
Jq5o
a
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7:'
8
9
10
11
'
12
ADDITIONALcOMMENTS.;' _
R UNQUISNEDBY/AFFILIATION
DATE:
TIME
">.'...:
:.
CEP
BY7` -PI TION
.. .,
DATE
-.. .. -
....
.r...
TIME
.
SAMPLECONDRIONS
✓ J.
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ORIGINAL
$AMPkER NAME AND
SIC5NA4TUFiE
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PRINT Name of SAMPLER: � � `r u�
SIGNATURE of SAMPLER:
DATE Signed
(MMIDDIYY):
M
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•Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per morift any Invoices not mid within 30 days. I F-ALL-Q-020rev.07, 15-May-2007

Document Name:
Document Revised: May 7, 2012
Aflape
Sample Condition Upon Receipt (SCUR)
Page 1 of 2
Document Number:
Issuing Authority:
F-CHR-CS-03-rev.07
Pace Huntersville Quality Office
1 Client Name: ,wkl�� r Project #'?z
Where Received: S.Huntersville ❑ Asheville ❑ Eden
j Courier: ❑ Fed Ex ❑ UPS❑ USPS❑ Client❑ Commercial,. Pace Other
Custody Seal on Cooler/Box Present: ❑ yes A no Seals Intact: ❑ yes ❑ no I Rim=
i Packing Material: ❑..Bubb) Wrap L_.I Bubble Bags 6 None ❑ .Other
Thermometer Used: IR G n T1101 T7102. Type of Ice Wet lue None Samples on ice, cooling process has begun
Tamn Cnrrarfinn Farfnr 1101- Nn Cormintinn T1102- Nn Correction
I
Corrected Cooler Temp.: 3, C Biological Tisql�Asue is Frozen: Yes Nconten
Temp should be above freezing to 6°C Comments:
Date and I I of pe n e mining
6
Chain of Custody Present:
VIYes ONO
❑N/A
1.
Chain of Custody Filled Out:
Yes ONO .
❑NIA
2.
Chain of Custody Relinquished:
Yes ❑No
❑NIA
3.
Sampler Name & Signature on COC:
Yes ONO
❑N/A
4.
Samples Arrived within Hold Time:
OY.. ONO
❑N/A
5.
Short Hold Time Analysis <72hr :
Yes ONO
❑NIA
6.
Rush Turn Around Time Requested:
Dyes No
❑NIA
7.
Sufficient Volume:
Yes ONO
❑N/A
8.
Correct Containers Used:
-Pace Containers Used;
Yes ❑No
( Yes ONO
I]N/A
❑N/A
9.
Containers Intact
Yes ONO
❑NIA
10.
Filtered volume received for Dissolved tests
❑Yes ONO
N/A
11.
Sample Labels match COC:
-includes date/time/ID/Analysis Matrix:
Yes ONO
V q
❑NIA
12.
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA, col'ifonn, TOC, OBG, WI-DRO (water)
Yes ONO
Yes ONO
Dyes ❑No
❑N/A
❑N/A
13.
Initial when completed
Samples checked for dechlorination:
OYes ONO
❑N/A
14.
Heads ace in VOA Vials >6mm):
Dyes ONO
N/A
15.
Trip Blank Present:
❑Yes ONO
I�JNIA
16.
Trip Blank Custody Seals Present
Pace Trip Blank Lot # if purchased):
❑Yes ONO
N/A
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review l (Date: 1�—A ali SRF Review:l 11-,V l0ate: 1 S' 0 2
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a this form will be sent to the North Carolina DEHNR
Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers)
13of13

aceAnalyiical
www.pacelabs.com
May 18, 2012
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2012. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
'it-A-U 4I Qyt«
Renee Spencer
[e-mail]
Project Manager
Enclosures
pCCRFO�
l
�9eORA_��,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1 of 15
Page 1 of 13

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pecolabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
CERTIFICATIONS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Asheville Certification IDS
2225 Riverside Dr., Asheville, NC 28804
South Carolina Certification #: 99030001
Florida/NELAP Certification #: E87648
Virginia Certification #: 00072
Massachusetts Certification #: M-NC030
West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712
Virgina/VELAP Certification #: 460147
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS Page 2 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
2of15

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalX
wical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
`ww.paceelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
SAMPLE ANALYTE COUNT
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92118303001
K65W6N
EPA 350.1
DMN
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92118303002
K65W7K
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
92118303003
K65W7L
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
92118303004
K65W7J
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
92118303005
K65W6A
EPA350.1
DMN
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92118303006
K65W6E
EPA350.1
DMN
1
PASI-A
EPA353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS Page 3 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
3 of 15

j ® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
acemalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Sample: K65W6N
Parameters
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2IN03 unpres
Nitrogen, Nitrate
Date: 05/18/2012 10:45 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92118303001 Collected: 05/10/12 10:40 Received: 05/10/12 14:02 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: EPA 350.1
0.35 mg/L 0.10 1 05/18/12 01:51 7664-41-7
Analytical Method: EPA 353.2
48.5 mg/L 2.0 10 05/11/12 18:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 4 of 13
4of15

aceAnaocal10
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7K Lab ID: 92118303002 Collected: 05/10/12 08:45 Received: 05/10/12 14:02 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.6 mg/L 0.10 1 05/18/12 01:51 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 87.1 mg/L 2.0 10 05/11/12 18:34
Date: 05/18/2012 10:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 13
5of15

I
® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Sample: K65W7L
Parameters
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92118303003 Collected: 05/10/12 09:20 Received: 05/10/12 14:02 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 350.1
10.7 mg/L 0.50 5 05/18/12 02:48 7664-41-7
Analytical Method: EPA 353.2
94.9 mg/L 2.0 10 05/11/1218:35
Date: 05/18/2012 10:45 AM REPORT OF LABORATORY ANALYSIS Page 6 of 13
This report shall not be reproduced, except in full,
without the written consent of PaceAnalytical Services, Inc..
6of15

e Pace Analytical Services, Inc. Pace Analytical Services, Inc.
la"eMalja�jG►°, 205 East Meadow Road - Suite A 2225 Riverside Dr.
WW.p& �78i ``bbSZ0M Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7J Lab ID: 92118303004 Collected: 05/10/12 10:00 Received: 05/10/12 14:02 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 4.2 mg/L 0.10 1 05/18/12 01:53 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 134 mg/L 2.0 10 05/11/12 18:37
Date: 05/18/2012 10:45 AM REPORT OF LABORATORY ANALYSIS Page 7 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
7of15

i
IacleAnalytical
(�www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite
Eden, NC 27288
[phone]
ANALYTI
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Sample: K65W6A Lab ID: 92118303005 Collet
Parameters Results Units RI
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.24 mg/L
363.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 162 mg/L
Date: 05/18/2012 10:45 AM
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
05/10/12 11:30 Received: 05/10/12 14:02 Matrix: Water
Limit DF Prepared Analyzed CAS No. Qua[
0.10 1
4.0 20
REPORT OF LABORATORY ANALYSIS
This report shall not be I produced, except in full,
without the written consent of Pace Analytical Services, Inc..
05/18/12 01:55 7664-41-7
05/11 /12 18:52
Page 8 of 13
8of15

CvAnaVicalo
w�vww.p—lbb—
Pace Analytical Services, Inc.
205 East Meadow Road -Suite A
Eden, NC 27288
[phone]
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab ID: 92118303006 Collected: 05/10/12 12:20 Received: 05/10/12 14:02 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 0.33 mg/L 0.10 1 05/18/12 01:57 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 181 mg/L 0.20 1 05/11/12 18:31
Date: 05/18/2012 10:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 13
9of15

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
,�aaeAnalXical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www..pecolabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
I
QC Batch: WETA/12147 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92118303001, 92118303002, 92118303003, 9I 118303004, 92118303005, 92118303006
METHOD BLANK: 765815 Matrix: Water
Associated Lab Samples: 92118303001, 92118303002, 92118303003, 92118303004, 92118303005, 92118303006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 05/18/12 01:41
LABORATORY CONTROL SAMPLE: 765816
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 I 5.0 100 90-110
MATRIX SPIKE SAMPLE:
765817
92117909001 !
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
20.6
5
25.9
106
90-110
MATRIX SPIKE SAMPLE:
765819
92117909002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
17 i0
5
22.0
101
90-110
SAMPLE DUPLICATE: 765818
92117909001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
20.6
it
21.0
2
SAMPLE DUPLICATE: 765820
92117909002
Dup
Parameter
Units
Result j
Result
RPD
Qualifiers
Nitrogen, Ammonia
mg/L
17.0
17.2
1
Date: 05/18/2012 10:45 AM
I
REPORT OF LABORATORY ANALYSIS
This report shall not be (reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 13
10 of 15

ices, Inc.
ical Services, Inc.
9800 K
Pace
Analytical
ow o Pace 2ivPa int
�ce�naicai 2 5East MeadRoad Suite Analytical5 Riverside Dr. ceyAve. Suite 100
ww.pa bSc= Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
QC Batch: WETA112108
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92118303001, 92118303002, 92118303003, 92118303004, 92118303005, 92118303006
METHOD BLANK: 763068
Matrix: Water
Associated Lab Samples: 92118303001, 92118303002, 92118303003, 92118303004, 92118303005, 92118303006
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.20 05/11/12 18:00
LABORATORY CONTROL SAMPLE:
763069
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
5 5.2 104 90-110
MATRIX SPIKE SAMPLE:
763070
92118335001 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.75 5 6.4 114
90-110 M1
MATRIX SPIKE SAMPLE:
763073
92118335002 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.88 5 6.4 110
90-110
SAMPLE DUPLICATE: 763071
92118335001 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
0.75 0.74 1
SAMPLE DUPLICATE: 763074
92118335002 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
0.88 0.88 0
Date: 05/18/2012 10:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 13
11 of 15

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalyilcal
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALIFIERS
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TN accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Date: 05/18/2012 10:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 13
12 of 15

aceAnalytici
www.pacelabs.=rn
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: SS STATESVILLE FERT 50200
Pace Project No.: 92118303
Lab ID Sample ID QC Batch Method QC Batch
92118303001
K65W6N
EPA 350.1
WETA/12147
92118303002
K65W7K
EPA 350.1
WETA/12147
92118303003
K65W7L
EPA 350.1
WETA/12147
92118303004
K65W7J
EPA 350.1
WETA/12147
92118303005
K65W6A
EPA 350.1
WETA112147
92118303006
K65W6E
EPA 350.1
WETA/12147
92118303001
K65W6N
EPA 353.2
WETA/12108
92118303002
K65W7K
EPA 353.2
WETA/12108
92118303003
K65W7L
EPA 353.2
WETA/12108
92118303004
K65W7J
EPA 353.2
WETA112108
92118303005
K65W6A
EPA 353.2
WETA/12108
92118303006
K65W6E
EPA 353.2
WETA/12108
Date: 05/18/2012 10:45 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Analytical Method Batch
Page 13 of 13
13of15

aceAnaljdcal °
www.pmfabs.com
Section A
Required Cilent Information:
CHAIN -OF -CUSTODY / Analytical Request Documei it
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section B . Section C. Page: ( Of. l
Required Project Information: Involoe Information: }
Report To: " Attention: _ 15 65 2 91.
Copy To: Company Name: ?3EG0 ORI� GEN
Address: r NPD Es GROUND WATER. F. .'DRINKING WATER
Phone:/� �q �� /�ip ax:
Project Name: C
'1
race rrolect
M{ (tr7>j('+Df
Manager.
Requested Due Dater=.
Project Number.
PacePromle #: .
Section D Matrix Codes
RequtredClient Information MATRIX / CODE
' E
M
COLLECTED
Preservatives
Drinking Water DW
v
zo
Water WT
Waste Water W W
m
coslre
oENDrros
W
Product P
4Q
START
GRAB
Soil/Solid SL
$
0
0ro
SAMPLE ID w�
0
a
L
„°
Wp
Lu
Z
(AZ,0-9/,) Air AR
w
a
a.
Sample IDS MUST BE UNIQUE Tissue TS
O
U
Fa
Z
d
Other OT
X
.Z
#
a
a
2
n
O'
=d1
O
N
f0
c
y
fD
N
DATE
TIME
DATE
TIME
O
=
_
=
Z
z
M
V&CQ l I(eAl
I\I
. w
10LID
�3
12
ADD iMONAL O"ENTS REl
r UST r RCRA (- OTHER
AA -
Site Loc tiotl
c
c `6:5
U
III Pace Project NO Lab I.D. J
4TIONSAMPLE CONDITIONS
SAMPLER NAME AND $IGNATURE
ORIGINAL PRINT Name of SAMPLER:
� ��
C p Z
E ri m
O
d
n z
SIGNATURE SAMPLER:
DATE Signed
F `—'
V �,�
m
of
yw
(MMIDD/YY):
y
'Important Note: By signing this forth you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5% per mo
ny invoices n t pild within 30 days.
F-ALL-Q-020rev.07, 15-May-2007

Document Name:
Sample Condition Upon Receipt (SCUR)
Document Revised: May 7, 2012
Page 1 of 2
eArfalytii 8/"
Document Number.
Issuing Authority:
1
F-CHR-CS-03-rev.07
Pace Huntersville Quality Office
qjient Name:L�,nA&Q�DcL am Project # °l2 75-303
Where Received: Huntersville ❑ Asheville ❑ Eden
Courier: ❑ Fed Ex ❑ UPS[] USPS❑ Client❑ Cmercial Pace Other
Custody Seal on Cooler/Box Present: ❑ yes ;_`NoneJM*
Is intact: ❑ yes ❑ no
Packing Mateilal: ❑ Bubble ❑ Bubble Bags Other
Thermometer Used: IR GT110 T1102 Type of Ice: Blue None Samples on Ice, cooling process has begun
Temp Correction Factor 1101: No Correction T1102: No Correction
Biological Tissue is Frozen: Yes No WA Date and Initials fperso exam n
Corrected Cooler Temp.:_ C contents: �a
Temp should be above freezing to- Comments:
Chain of Custody- Present: UK. ON. ❑NIA 1.
Chain of Custody Filled Out: es No ❑WA 2.
Chain of Custodv Relinquished: es j1No ❑NIA 3.
er Name & Signature on COC:
as Arrived within Hold Time:
Hold Time Analysis (<72hr):
Tum.Around Time Reauestel
Sufficient Volume:
Correct Containers Used:
-Pace Containers Used:
Filtered volume received for
Sample Labels match COC:
-Includes date/time/ID/Ar
All containers needing preservatic
containers needing preservation are found to be in
nDliance with EPA recommendation.
❑N/A
ONO JQNIA 6.
Palo" ❑N/A 17.
No ❑NIA 8.
;]No ❑N/A 9.
o ❑N/A
❑No ❑WA 11
❑Yes Wo ORA 11.
es [IN. ❑NIA 12.
®Yes ONO ❑NIA 13.
01ers ❑No ❑WA
exceptions: VOA, colifonn, TOC, O&G, WI-DRO (water) ❑Yes o Initial when completed
Samples checked for dechiodnation: pilas ON. ❑N/A 14.
Heads ace in VOA Vials >6mm : ❑Yes ONO EKIA 1 .
Trip Blank Present: ❑Yes ONO PeA
Trip Blank Custody Seals Present ❑Yes ONO RKA
Pace Trip Blank Lot # Ifpurchased):
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Review: i� Date: bI I VI L� SRF Review: Date: rJ to
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of form will be sent to the North Carolina
Certification Office ( i.a out of hold, incorrect preservative, out of temp, incorrect containers)
15 of 15

aceAnalytical
www.pecelabs.com
November 13, 2012
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2012.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
Ncci-
i
��eORATO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 13

e Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
�acmna�1 /f f�^' 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
mmpa•eceFa`bs:wm Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
CERTIFICATIONS
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NC030 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS Page 2 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
SAMPLE ANALYTE COUNT
Project:
STATESVILLE FERTILIZER
PLANT
Pace Project No.:
92137660
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92137660001
K65W7D
EPA 350.1
SDH
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137660002
K65W7F
EPA 350.1
SDH
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92137660003
K66MG
EPA 350.1
SDH
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137660004
K65W7H
EPA 350.1
SDH
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137660005
K65W6M
EPA 350.1
SDH
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137660006
K65W6N
EPA 350.1
SDH
1
PASI-A
EPA353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS Page 3 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
wAv.pa.+cPJa�bs.mrn
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Sample: K65W71)
Lab ID: 92137660001 Collected: 11/06/12 11:30
Received: 11/06/12 18:00
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua[
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
11/12/12 14:42 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
ND mg/L 0.020 1
11/07/12 19:19
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 4 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Analytical
205 East Meadow Road - Suite
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pecelaftcom
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Sample: K65W7F
Lab ID: 92137660002 Collected: 11/06/12 09:08
Received: 11/06/12 18:00
Matrix: Water
-Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA 350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
11/12/12 14:42 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
10.7 mg/L 0.060 3
11/07/12 19:52 M1
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 5 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ace rcal rces, Inc. Pace Analytical5
Services, Inc.
Pa ical Services, Inc.
/
205 East Meadow Road - Suite
R
2iverside Dr.
9800 K intceyA e. Suite 100
www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: STATESVILLE FERTILIZER
PLANT
Pace Project No.: 92137660
Sample: K65W7G
Lab ID: 92137660003 Collected: 11/06/12 08:10
Received: 11/06/12 18:00
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
ND mg/L 0.10 1
11/12/12 14:44 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
6.2 mg/L 0.040 2
11/07/12 19:48 M1
Date: 11/13/2012 08:24AM REPORT OF LABORATORY ANALYSIS Page 6 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs.com
I
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Sample: K65W7H Lab ID: 92137660004 Collected: 11/06/12 10:08 Received: 11/06/12 18:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/12/12 14:44 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.54 mg/L 0.020 1 11/07/12 19:17
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 7 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnaljNcal"
www.,pao0abs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6M Lab ID: 92137660005 Collected: 11/06/12 13:47 Received: 11/06/12 18:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
360.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia ND mg/L 0.10 1 11/12/12 14:45 7664-41-7
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 1.0 mg/L 0.020 1 11/07/12 19:20
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 8 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6N Lab ID: 92137660006 Collected: 11/06/12 15:58 Received: 11/06/12 18:00 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
350.1 Ammonia Analytical Method: EPA350.1
Nitrogen, Ammonia 0.93 mg/L 0.10 1 11/12/12 14:46 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 50.4 mg/L 0.020 1 11/07/12 19:21
Qual
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 9 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace
Services, Pace Analytical Services,
Pace
Analytical
Services, Inc.
eMayical
25East Meadow RodSuite 25 Riverside Dr. 9800 KiceyAve. Suite 100
ww .pacalabs.cam Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
QC Batch: WETA/13724
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92137660001, 92137660002,
92137660003, 92137660004, 92137660005, 92137660006
METHOD BLANK: 870591
Matrix: Water
Associated Lab Samples: 92137660001, 92137660002,
92137660003, 92137660004, 92137660005, 92137660006
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 11/12/12 14:33
LABORATORY CONTROL SAMPLE:
870592
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 4.8 97
90-110
MATRIX SPIKE SAMPLE:
870594
92137258001 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
ND 5 4.7
94
90-110
MATRIX SPIKE SAMPLE:
870596
92136869001 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
1.0 5 5.8
96
90-110
SAMPLE DUPLICATE: 870593
92137258001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
ND ND
SAMPLE DUPLICATE: 870595
92136869001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
1.0 1.0
2
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 10 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalXical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
QC Batch: WETA113689
Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92137660001, 92137660002, 92137660003, 92137660004, 92137660005, 92137660006
METHOD BLANK: 868418
Matrix: Water
Associated Lab Samples: 92137660001, 92137660002, 92137660003, 92137660004, 92137660005, 92137660006
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.020 11/07/12 18:59
LABORATORY CONTROL SAMPLE:
868419
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
2.5 2.5 100 90-110
MATRIX SPIKE SAMPLE:
868420
92137660003 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
6.2 2.5 8.2 81
90-110 M1
MATRIX SPIKE SAMPLE:
868422
92137660002 Spike MS MS
% Rec
Parameter
Units
Result Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate
mg/L
10.7 2.5 14.1 137
90-110 M1
SAMPLE DUPLICATE: 868421
92137660003 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
6.2 6.2 1
SAMPLE DUPLICATE: 868423
92137660002 Dup
Parameter
Units
Result Result RPD Qualifiers
Nitrogen, Nitrate
mg/L
10.7 10.7 0
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 11 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

PaceAnalytical Services,
Pace Analytical Services,
PaceAnalyticalServices, Inc.
CeAnalyiical
25East Meadow Rod- Suite A
225 Riverside Dr.
9800 KiceyAve. Suite 100
wwwpaaabs.wm
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALIFIERS
Project: STATESVILLE FERTILIZER
PLANT
Pace Project No.: 92137660
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 12 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: STATESVILLE FERTILIZER PLANT
Pace Project No.: 92137660
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92137660001
K65W7D
EPA 350.1
WETA/13724
92137660002
K65W7F
EPA 350.1
WETA/13724
92137660003
K65W7G
EPA 350.1
WETA/13724
92137660004
K65W7H
EPA 350.1
WETA/13724
92137660005
K65W6M
EPA 350.1
WETA/13724
92137660006
K65W6N
EPA 350.1
WETA/13724
92137660001
K65W7D
EPA 353.2
WETA/13689
92137660002
K65W7F
EPA 353.2
WETA/13689
92137660003
K65W7G
EPA 353.2
WETA/13689
92137660004
K65W7H
EPA 353.2
WETA/13689
92137660005
K65W6M
EPA 353.2
WETA/13689
92137660006
K65W6N
EPA 353.2
WETA/13689
Analytical
Batch
Date: 11/13/2012 08:24 AM REPORT OF LABORATORY ANALYSIS Page 13 of 13
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

/ ,FaceAnalvtical'
CHAIN -OF -CUSTODY / Analytical Request Document
The Chaln-of-Custody is a LEGAL DOCUMENT. All relevant flelds must be completed accurately.
� mn.p»IeCs.eam
Page: of
'Section A Section B Section C .
16 0 211 �
Required Client bdormeflon: Required Project Information: Invoice Information:
Report To:
��ny.. ..
.. .
ress:
Copy To:
Company Name:
REGULATORY AGENCY; • •::
I" NPDES GROUNDWATER . j ` DRINIQNG WATER
(— UST i RCRA r OTHER
Enrag To c dMrVt
TdvReference:
Purchase Order No.:
Pace caste
Proect Name:
(' I
(k (
P° Pf led
Mere9er
E]
. Site Location
I STAI$
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ph°np, r Falc �---
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Requested Due DateJTAT: f _
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Paea Proree a e7Z 7 , � l
Requested
AitaWd
FlltereN
(YIN)
Section D Matrbt Codes
Cow
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COLLECTED
PIBServajfves
Z
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RequhedajenthdomraUm MATRIx!
8
Ddnidng Water Dw
Water WT
Waste Water WVir
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Product P
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SAMPLE ID WP
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Sample IDs MUST BE UNIQUE Tissue TS
Other
U
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W
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9213:7 t)
0
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U.
f
Z
=
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Lu
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DATE
TIME
DATE
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2
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ADDITIONAL COFAMENTS
REt x(jUISHED BY! AFFILIATION..
:. DATE
'TIME
A D BY7 . ..
T10N
D 1E
TIME
SAMPLE CONDITIONS
Z.11ma
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77
SAMPIERf WME AND SIONATURE
U
O
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ORIGINAL PRINT Name of SAMPLER,m
U •g g
E
SIONATUM of SAMPLER r• DATE Signed
F
-Important Note: By signing thts form you are aecepUng Pace's NET 30 day paymentterms and egreaing to late dmgas of 1.5% Per manth f" 4oices not paid wBh[n 3D days. I * F-ALL-Q-020fev.07, 9 5-MeyFZUUf

I
wocument Name:- uocumern rcevtstsu: vc:touni 1, Av �A
Sample Condition Upon Receipt (SCURI Pa e 1 of 2
Document Number: Issuing Authority:
F-CHR.C6-03-rev.08 . Pace Huntersville QualityOffice
Client Name: Project # qX t
Where Received: .,ffHuntersville ❑ Ashevilie ❑ Eden ❑ Raleigh
Courier. ❑ Fed Ex ❑ UPS[] LISPS❑ Client❑ Commercial❑ t Other
.Custody Seal on CoolerlBox Present: ❑ yes ❑ � Seals intact: ❑yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags ❑ on ❑ Other.
Thermometer Used: IR Gu 11 T1102 Type of lee: & Blue None •Samples on Ice, cooling process has begun
Tamn r!n"Mentinn Var4nr T44A4- Nn r:nrrec:flnn T1102: No Correciion
r i,; C
Corrected Cooler Temp.:
-Temp should be above freezing -to 8°C
Biological Tissue Is Frozen: Yee No N/A
Comments:
Date and Initi s of parson "amiini g
contents: LbaF'
Chain of Cust6dy Present:
s ONo
❑wA
1.
Chain of Cu!!Filled Out:
ONO
❑NA
2.
Chain of Custody Relinquished: ❑No
ONIA
3.
Sampler Name & Signature on COC:
.r-BYes ONo
❑wA
4.
Samples Arrived within Hold Time: •
__-Me—s ONo
❑wA
5..
Short Hold Time Analysis 02hr :
-ElTe-3 ONo
❑wA
6.
Rush Turn Around Time Requested:
❑Yes .2115--OwA
7.
Sufficient Volume:
ONo'
❑N/A
8.
Correct Containers Used:
-Pace Containers Used:
/O�•. ONo
❑Yes ❑No
ONiA
❑wtA
9.
Containers Intact:
Yes ONo
❑wA
10.
�Iltered volume received for Dissolved tests
[]Yes ONo,,PfZA7
11.
Sample Labels match COG:
-includes datetfimeAD/Anal sis Matrix
ONo
❑MA
12.
i All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
6ceptions: VOA, colifonn, TOC, O&G, WI-DRO water)
,�' T a.-- ONo
ONo
OYes ONo
❑wA
❑NiA
13.
Initial when completed
.Samples checked for dechlorination:
❑No
OwA
14.
Heads ace in VOA Vials >6mm :
❑Yes ONo
a
15.
Trip Blank Present~
Trip Blank Custody Seals Present
Pace Trip Blank Lot # i# purchased):
Oyes ONo.
❑Yes ONo
P10A
OwA
16.
Client Notification/ Resolution: Field Data Required? Y / N
Person Contacted: Date/Time:
Comments/ Resolution:
SCURF Revle /PC—"/ Date: 11 7 z_-SRF Review:1 Date! l 111blIZz' I
'Note: Whenever d1rirls a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR
.Certification Office ( l.s out of hold, incorrect preservative, out of temp, Incorrect containers)

aceAnalXical
www.pacelabs.com
November 21, 2012
Mr. Jayson Kilcoyne
Duncklee & Dunham
P.O. Box 33366
Raleigh, NC 27636
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
RE: Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Dear Mr. Kilcoyne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 07, 2012.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
Project Manager
Enclosures
ESQ P«RF���i
/a �o
�eORA�o�y
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 14

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
(�IacmnalXical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
CERTIFICATIONS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Asheville Certification IDS
2225 Riverside Dr., Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 14

aI CoAna ical
wovw.p—)bbs,eom
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Pace Analytical Services, Inc.
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92137776001
K65W6B
EPA353.2
DMN
1
PASI-A
92137776002
K65W7K
EPA 350.1
LIVID
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137776003
K65W7L
EPA 350.1
LMD
1
PASI-A
EPA 353.2
DMN
1
PASI-A
92137776004
K65W7J
EPA 350.1
LMD
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137776005
K65W6A
EPA 350.1
LIVID
1
PASI-A
EPA353.2
DMN
1
PASI-A
92137776006
K65W6E
EPA 350.1
LIVID
1
PASI-A
EPA353.2
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS Page 3 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www..pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
I
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Sample: K65W6B
Lab ID: 92137776001 Collected: 11/07/12 07:35
Received: 11/07/12 14:20
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua[
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
39.8 mg/L 0.30 15
11/07/12 23:52
Date: 11/21/2012 07:47AM REPORT OF LABORATORY ANALYSIS Page 4 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
i
Ana�171ical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www.pacwfabs;com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Sample: K65W71K
Lab ID: 92137776002 Collected: 11/07/12 08:54
Received: 11/07/12 14:20
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua]
360.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
2.3 mg/L 0.10 1
11/14/12 23:44 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
85.6 mg/L 0.50 25
11/07/12 23:56
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 5 of 14
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without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
www.pacala6scom Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7L Lab ID: 92137776003 Collected: 11/07/12 10:15 Received: 11/07/12 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1 -
Nitrogen, Ammonia 4.9 mg/L 0.10 1 11/14/12 23:44 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 97.8 mg/L 0.60 30 11/07/12 23:58
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 6 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aCeMaly'� cal 205 East Meadow Road - Suite A 2225 Riverside Dr.
wavH'WCdbbs.cam Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W7J Lab ID: 92137776004 Collected: 11/07/12 11:00 Received: 11/07/12 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 2.2 mg/L 0.10 1 11/14/12 23:46 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA353.2
Nitrogen, Nitrate 185 mg/L 0.020 1 1 11/08/12 17:20
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 7 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc. Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
aceAnalytical
205 East Meadow Road - Suite A
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
www..pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Sample: K65W6A
Lab ID: 92137776005 Collected: 11/07/12 12:00
Received: 11/07/12 14:20
Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qua[
350.1 Ammonia
Analytical Method: EPA350.1
Nitrogen, Ammonia
0.88 mg/L 0.10 1
11/14/12 23:46 7664-41-7
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
105 mg/L 0.020 1
11/08/12 17:27
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 8 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

ices, Inc.
Pace
Analytical Services, Pace Analyt2a2 East Medow Rod- SuiteA 225 Riverside Dr.
Uu nJ�J
mm..pacetabs.mm Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
ANALYTICAL RESULTS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: K65W6E Lab ID: 92137776006 Collected: 11/07/12 12:46 Received: 11/07/12 14:20 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia Analytical Method: EPA 350.1
Nitrogen, Ammonia 1.2 mg/L 0.10 1 11/14/12 23:48 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 223 mg/L 1.0 50 11/08/12 17:48
Date: 11/21/2012 07:47AM REPORT OF LABORATORY ANALYSIS Page 9 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

®
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
Pace Analytical Services, Inc.
acoAnalytical
205 East Meadow Road - Suite
2225 Riverside Dr.
9800 Kincey Ave. Suite 100
- www.pacelabs.com
Eden, NC 27288
Asheville, NC 28804
Huntersville, NC 28078
[phone]
[phone]
[phone]
QUALITY CONTROL DATA
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
QC Batch: WETA/13748
Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1
Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92137776002, 92137776003, 92137776004, 92137776005, 92137776006
METHOD BLANK: 872868
Matrix: Water
Associated Lab Samples: 92137776002, 92137776003, 92137776004, 92137776005, 92137776006
Blank Reporting
Parameter
Units
Result Limit Analyzed
Qualifiers
Nitrogen, Ammonia
mg/L
ND 0.10 11/14/12 23:30
LABORATORY CONTROL SAMPLE:
872869
Spike LCS LCS
% Rec
Parameter
Units
Cone. Result % Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
5 5.2 104
90-110
MATRIX SPIKE SAMPLE:
872870
92137508001 Spike MS
MS
% Rec
Parameter
Units
Result Cone. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
2.2 5 7.1
98
90-110
MATRIX SPIKE SAMPLE:
872872
92137869001 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Ammonia
mg/L
0.47 5 5.6
103
90-110
SAMPLE DUPLICATE: 872871
92137508001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
2.2 2.3
1
SAMPLE DUPLICATE: 872873
92137869001 Dup
Parameter
Units
Result Result RPD
Qualifiers
Nitrogen, Ammonia
mg/L
0.47 0.47
1
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 10 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
/7 laoeMaVical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wampaca7abs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
QC Batch: WETA/13693
Analysis Method:
EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description:
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92137776001, 92137776002, 92137776003
METHOD BLANK: 868443
Matrix: Water
Associated Lab Samples: 92137776001, 92137776002, 92137776003
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.020 11/07/12 23:08
LABORATORY CONTROL SAMPLE:
868444
Spike LCS
LCS % Rec
Parameter
Units
Conc. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
2.5 2.5
98 90-110
MATRIX SPIKE SAMPLE:
868445
92137649007 Spike
MS MS % Rec
Parameter
Units
Result Conc.
Result % Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.18 2.5
2.7 99 90-110
MATRIX SPIKE SAMPLE:
868447
92137845003
Spike
MS
MS % Rec
Parameter
Units
Result
Conc.
Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
ND
2.5
2.6
104 90-110
SAMPLE DUPLICATE: 868446
92137649007
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
0.18
0.18
1
SAMPLE DUPLICATE: 868448
92137845003
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Nitrogen, Nitrate
mg/L
ND
ND
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 11 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabs.com Eden, NC 27288 Asheville, NC 28804 Huntersville, NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
QC Batch: WETA/13699
Analysis Method:
EPA 353.2
QC Batch Method: EPA 353.2
Analysis Description:
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92137776004, 92137776005, 92137776006
METHOD BLANK: 869107
Matrix: Water
Associated Lab Samples: 92137776004, 92137776005, 92137776006
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate
mg/L
ND 0.020 11/08/12 17:08
LABORATORY CONTROL SAMPLE:
869108
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
2.5 2.5
98 90-110
MATRIX SPIKE SAMPLE:
869109
92137956001 Spike
MS MS % Rec
Parameter
Units
Result Cone.
Result % Rec Limits Qualifiers
Nitrogen, Nitrate
mg/L
0.032 2.5
2.7 106 90-110
SAMPLE DUPLICATE: 869110
92137956001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Nitrogen, Nitrate
mg/L
0.032 0.071 76 D6
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 12 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

Pace Analytical Services, Inc. Pace Analytical Services, Inc.
e?ceAnalXical 205 East Meadow Road - Suite A 2225 Riverside Dr.
wmpncelabs:com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALIFIERS
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
DEFINITIONS
,
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL- Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
ANALYTE QUALIFIERS
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 13 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

® Pace Analytical Services, Inc. Pace Analytical Services, Inc.
aceAnalytical 205 East Meadow Road - Suite A 2225 Riverside Dr.
- www.pacelabs.com Eden, NC 27288 Asheville, NC 28804
[phone] [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Statesville Fertilizer Plant
Pace Project No.: 92137776
Lab ID Sample ID QC Batch Method QC Batch
92137776002
K65W7K
EPA 350.1
WETA/13748
92137776003
K65W7L
EPA 350.1
WETA113748
92137776004
K65W7J
EPA 360.1
WETA/13748
92137776005
K65W6A
EPA 350.1
WETA/13748
92137776006
K65W6E
EPA 350.1
WETA/13748
92137776001
K65W6B
EPA 353.2
WETA/13693
92137776002
K65W7K
EPA 353.2
WETA/13693
92137776003
K65W7L
EPA 353.2
WETA/13693
92137776004
K65W7J
EPA 353.2
WETA/13699
92137776005
K65W6A
EPA 353.2
WETA/13699
92137776006
K65W6E
EPA 353.2
WETA/13699
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Date: 11/21/2012 07:47 AM REPORT OF LABORATORY ANALYSIS Page 14 of 14
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

/I
�;ZeAnalyda*
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody Is a LEGAL DOCUMENT. AR relevantfie(ds must be completed accurately.
i e .pnceme0s.con
Section A Section B Section C
Required Client Information: 7�' Required Project Infwmatt0n: Invoice Information:
Company. �e 1, Re[wrtTo: Attentiom
Pago
1602128
�,y TO.'
Company Name:
iiEGULAT'ORY�A(3ENCi
Address:
r NPDES VGROUNDWATgR r DRINKING WATER
�' UST r" RCRA (' OTHER
Email To: 4
444
Phone arc
Purchase Order No.:
pmCc�
Refermmaar
Project Name: „l B .L
` TifMw1
P1D
Maw
Ske Lorlan
SrAlE:
Aft",
�V �!
Requested Due DafeRAT:
Project Number y�e o
`J
Pace Profiles
P'
Requesfed
Analysis
Filtered
(Y"::.
Section D Matrix Codes
Requtrod0leethftmadon MATRIX / CODE
Drinking Water DW
Water WT
Waste Water W W
Product P
SoillSolid St.
SAMPLE.ID Wipe wP
(A-7, 0.9 /:) Air AR
Sample IDs MUST BE UNIQUE Tissue TS
Other OT
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DATE
11ME
DATE
TIME
1
2
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3
4
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6
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7
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9
10
17
12
ADDDTONAL;COMMENTS
RE1JNgUISHEp.BVAFF1W1TK.W. • '
DATE .
TENE
BYlAFFAIATIO
ID TE
TIIiD?
SAMPLE CONDrr10NS
ORIGINAL.
SAMPLER NAME.AND SIGNATURE
V
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$
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$ $
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PITNTNarrmeofSAlAPLIcR ��
SIGNATURE of SAMPLER / ..
D igrmed �+ /JJ /J
'Important Now By slarkg this fmn you are awept V Paea's NET 30 day payment temms and agrookV to male charges of 1.5% per month far W)J6ice1not ME widn 30 daye. F-ALL-"20rev.07, 15-May-2007

Sam le Condiflon Upon Receipt SCUR Rage e 1 of 2
1 Document Number: Issuing Authority:
F-CHR-CS-03-rev.08 Pace Huntersvitie Quali Office
Client Name: Project#
Where Received: ff-,Huntersville ❑ Asheville ❑ Eden ❑ Raleigh
Courier. d Fed Ex ❑ UPS[] USPA Client❑ Commerdal❑ Pace. Other f
Custody Seal on CoolerBox Present: ❑ yes 11\ no Seals Intact:. ❑ yes ❑ no
Packing Material: ❑ Bubble Wrap ❑ Bubble Bags V" None ❑ Other
Thermometer Used: IR GuQ0:41A)t1-
T1102 Type of Ice: Wet lue None Samples on ice, cooling process has begun
T....-� n�.-..�sa�.. �....a�. Aln e"^wr ^firm T77n • Ain i�rrrnn4lnn 1
Corrected Cooler Temp.: C
-Temp should be above freeaing.to 60C
Biological Tissue is Frozen: Yes Noq1A
ogcontents
Comments:
and 1 a of g examining
Chain of Cu Present:
Yes ON.
OWA
1.
Chain of Custody Filled Out:
fOyes ONo
❑NIA
2.
Chain of Custody Relinquished:
Yes ONo
❑NIA
3.
Sampler Name & Signature on COC:
ea ❑No
❑NIA
4.
Samples Arrlired within Hold Time:
Yes ONo
ON/A
5.
Short Hold Time Analysis 02hr :
0yes, ONo
❑NIA
e.
Rosh Turn Around Time Requested:
OYes No
❑NiA
7.
Sufficient Volume:
0yes ON.
❑NiA
8.
Correct Containers Used:
-Pace Containers Used:
]Yes ONo
/PUYes ONo
❑NIA
❑NIA
g.
Containers Intact
Yes ONo
13WA
10.
�Iltered volume received for Dissolved tests
'[Wes [IN.
41VA
11.
Sample Labels match COC:
-Includes dateltimeAD/Ana sis Matrix:
Yes ONo
❑NIA
12.
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptions: VOA. collform, TOC, 0&G. WI-DRO (water)
Ayes ONo
Yea ONo
(T
❑Yes ONo
❑NiA
ONrA
13.
Wflal when compieted
-$am les checked for dechlorination:
Yes CNo
ONIA
14,
Head ace in VOA Vials :1-6mm :
vas ONo
NIA
15.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # if purchased):
Oyes ONO
❑Yea ❑No
PNiA
i NIA
16.
Client Notification/ Resolution: Field Data Requlred? Y I N
Person Contacted: DateTme,
Comments! Resolution:
SCURF Review: Date: 1 tl(4Il2,,l 3RF Review l &U 10M.1 ffia(142�,' I
Note: Whenever there is a dlscre ancy affecting North Carolina compliancs samples, a copy of this form Wil be sent to the North Carolina OEHNR
Certification Office ( I.e out of hold, Incorrect preservative, out of temp, incorrect containers)

400
350
300
8
0 250
.Q
0
F
�a
C 200
x
V
O
O
U
150
R
4
z
100
50
04A
O
ti
K65W6 A (Saplrolite)
Nitrate Results
—a—Anunonia Results
—Nitrate 2L Standard
T O N m h b r, w T O ti ti N!
g
CC O O Q�+ O O "'I, O O O �p:
C Rf td
�--� ti �--• �. ti ti AA A �--. A�--•
Date
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
8/2/95
11/8/95
Nitrate (mg/1)
370
252
360
360
311
30
210
340
330
250
260
250
180
Ammonia (m0) 11
No Data
Date
218/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
Nitrate (mg/1)
240
260
210
106
243
121
199
236
240
220
200
180
190
Ammonia (mg/1) 11
No Data
Date
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
10/15/07
4/25/08
Nitrate (mg/1)
235
170
140
84
200
150
170
190
160
150
140
30.9
92.8
Ammonia (mg/1)
No Data
77
0.24
NS
NS
NS
0.23
NS
0.14
0.13
0.25
0.36
Date
4/9/09
10/30/09
4/6/10
10/21/10
4/22/2011
11/2111
5/10/2012
11/7/2012
Nitrate
152
186
135
122
118
120
162
105
1
Ammonia
NS
0.10
0.16
0.19
0.30
0.33
0.24
0.88

K65W6 B (Saprolite)
160
140
�1 120
o� 100
E
c
°0 80
60
0
0
U
.: 40
w
z
20
0 1ATi A k-•T.lA :l•ATJ A A A��AT
O N M 7 V1 �O n 00 O\ O N
O� a\ O1 O1 01 0\ 01 0\ 01 D\ O O O
Date
—0 Nitrate Results
—Ammonia Results
—Nitrate 21, Standard
O Opp Opp O❑❑ O O O O N
Date
2/13/90
1/22/92
4/16/92
7/27/92
10/21/92
2/10/93
4/8193
8/3/93
10/7/93
3/8/94
9/27/94
3/30/99
11/3/99
Nitrate m 1
22
22
15
26
16
7.6
6.8
28
29
19
18
89.4
140
Ammonia m
No Data
Date
10/24/01
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
1 4/26/06
1 10/23/06
1 5/1/07
10/15/07
4/25/08
4/9/09
Nitrate m 1
78
92
40
41
44
33
35
28
23
31
31
32
40
Ammonia m 1
No Data
<0.1
<0.1
<0. I
NS
NS
0.12
<0.1
<0. I
<0.1
NS
<0.1
<0.1
Date
10/29/09
4/6/10
10/22/10
4/21/11
11/1/11
5/9/2012
11/7/2012
Nitrate m
55.9
34.5
30.2
26.9
38.4
34.2
39.8
Ammonia m
<0.1
<0.10
1.4
0.61
<0.10
<0.10
NS

K65W6 D (Saprolite)
2
— + Nitrate Results
1.5
8
A
0
� 1
cl
A
u
A
U
w
z" 0.s
0
J
Date
Date
8/l/90
1/22/92
2/10/93
4/8/93 to 11/7/12
Nitrate m l
0.63
0.17
0.25
I
Dry
Ammonia m 1
No Data
Dry

K65W6 M (Saprolite)
1.5
1.4
tNitrate Results
1.3
--AL-Ammonia Results
1.2
1.1
1
0.9
q
0.8
0.7
O
U
0.6
is
0.5
z
0.4
0.3
0.2
0.1
0
0
0
0 0
q
�• Q
•, A ti A �' A
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/22/10
4/21/11
11/1/11
5/9/2012
11/6/2012
Nitrate m
0.44
<.10
0.15
I
0.16
I
0.28
0.14
I
0.37
I
<0.20
1.0
Ammonia m
<0.10
I <0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10

K65W6 N (Saprolite)
100.0
t Nitrate Results
90.0
. —Ammonia Results
®Nitrate 2L Standard
80.0
70.0
aa
e� 60.0
6
.S
°0 50.0
w
d 40.0
a
0
30.0
i
z 20.0
10.0
0.0
Date
Date
12/19/08
4/9/09
10/29/09
4/7/10
10/22/10
4/21/11
11/1/11
5/10/2012
11/6/2012
Nitrate m I
16.7
61.9
82.3
67.2
1
66.6
61.4
50.2
48.5
50.4
Ammonia m l
6.6
3.5
1.7
1.4
1.2
1.3
0.99
0.35
0.93

K65W7C (Saprolite)
140
120
80
4
A
u
u
°0 60
U
d
s,
z 40
20
—s Nitrate Results
b Ammonia Results
Nitrate 2L Standard
0 DATA
A
O
O,
N
C�
M
Q,
7 vn �o l- 00 Qi O .• N M V vl �D n
C� C� o, C1 C� O O O O O O O
.0
91
.n p
A
A p .b .a .8 p .D p .fl Q
w
w w
w
w w w w w w w w w w w w w w
Date
Date
2/13/90
1/22/92
2/10/93
10/17/03
7/18/05
10/28/05
4/25/08
12/19/2008 to 10/21/10
4/21/11
11/1/2011 to 11/6/12
Nitrate m 1
93
130
13
82
33
53
<0.10
Dry
9.4
Dry
Ammonia m 1
No Data
9
NS
2.3
29.4
Dry
<0.10
Dry

K65W7 D (Saprolite)
40
t Nitrate Results
35
:a Ammonia Results
®Nitrate 2L Standard
30
den
a
25
a
a20
u
0
d
15
L
w
10
5
L
OA
0-rsT--
�� i�A-R t ►-�A���-A
ATE- 6-�!
CD
00 00 (71
O O
00 a, O C14
O O O O O O
7 7 7
7 7 7 7 7 a
7 7 7 7 7 7 7
Date
Date
8/1/90
1/22/92
2/10/93
3/30/99
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
Nitrate m
I
2
0.57
0.775
2
1
2
1.1
<0.10
1.1
2.4
1.4
0.05
Ammonia m
No Data
0.41
<0.10
Date
4/16/04
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/1/07
4/25/08
4/16/09
10/29/09
4/6/10
10/21/10
4/21/11
Nitrate m
1.3
2.4
0.48
2
1.1
15
39
0.48
0.21
<0.10
0.22
<0.10
0.16
Ammonia m
<0.10
NS
NS
0.12
<0.10
1.1
2.1
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
Date
11/2/11
5/9/2012
11/6/2012
Nitrate m
<0.20
<0.20
<0.020
Ammonia m )
0.18
<0.10
<0.10

200
180
160
140
a
q
q 120
0
.q
c�
L
d
100
u
q
0
U 80
d
�a
L
Z 60
40
20
0
K65W7 F (Saprolite)
6 Nitrate Results
—Ammonia Results
®Nitrate 21, Standard
O •--� �O r, oo C� O --� N M 7 ul �O oo rn cr
a, p� p� p� 91 p, Qi Q, C� C� O O O O O O O O O O
75
Date
Date
8/l/90
1/22/92
4/16/92
7127/92
10/21/92
2/10/93
4/8/93
8/3/93
10/7/93
3/8/94
9/27/94
2/8/96
5/9/96
Nitrate m
99
100
109
79
79
110
100
100
96
1.6
94
150
6.1
Ammonia m I
No Data
Date
3/28/00
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/O5
10/27/O5
4/26/06
10/23/06
Nitrate m
5.1
0.52
20
33
17
3
21
8.5
<0.1
20
31
31
1 15
Ammonia m 1
No Data
<0.10
NS
<0.10
NS
NS
NS
0.12
1 1.1
Date
4/25/08
4/9/09
10/29/09
4/6/10
10/21/10
4/21/11
1 11/1/11
5/9/12
11/6/12
Nitrate m
61.9
33.6
Dry
9.2
30.7
6.7
Dry
Dry
10.7
Ammonia m 1
<0.10
<0.10
Dry
<0.10
<0.10
<0.10
Dry
Dry
<0.10

K65W7 G (Saprolite)
40
- s Nitrate Results
—Ammonia Results
®Nitrate 21, Standard
30
a
0
a
0
w
a20
0
U
w
L
z
10
Q ,a��aTa A A—�—AAA ATA—Aram/—A— A A
N 00
Q� C� 01 91 91 T C� T O O O O O O O O O O
Date
Date
8/1/90
1/22/92
2/10/93
2/8/96
11/3/99
11/16/00
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
10/28/04
7/18/05
Nitrate m
1.7
1.9
2.6
3.5
2.9
3.6
2.8
31
32
1.3
0.4
I
4.4
1.7
Ammonia m
No Data
<0.10
<0.10
NS
NS
Date
4/25/06
10/23/06
5/l/07 to 4/6/10
10/21/10
4/21/11
11/1/11
5/9/12
11/6/12
Nitrate m
16
29
Dry
3.3
Dry
Dry
Dry
6.2
Ammonia m l
<0.10
4
Dry
<0.10
Dry
Dry
Dry
<0.10

K65W7 J (Saprolite)
300
+-Nitrate Results
—,'—Ammonia Results
—Nitrate 21, Standard
250
200
a
a
0
a
d
150
a
0
U
d
100
z
50
Q
CD C,
00 00 T Q�
CDO .--� .N-� N
O O Q
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6 O
Date
Date
10/28/04
7/18/05
10/27/05
4/26/06
10/23/06
5/1/07
1 10/15/07
1 4/25/08
1 12/18/08
1 4/9/09
10/30/09 1
4/7/10
1 10/22/10
Nitrate m I
100
140
74
I
150
180
140
14.4
178
204
191
199
157
172
Ammonia m 1
NS
NS
<0.10
<0.10
<0.10
0.10
0.6
0.86
0.79
1.7
1.7
1.4
2.2
Date
4/21/11
11/2/11
5/10/2012
11/7/2012
Nitrate m 1
162
184
134
185
Ammonia m 1
3.3
2.8
4.2
2.2

K65W6 E (Bedrock)
350
0 Nitrate Results
300
—Ammonia Results
—Nitrate 21, Standard
250
tw
a
200
A
O
CC
w
150
G
O
V
100
z
50
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Date
Date
8/l/90
1/22/92
2/10/93
8/2/95
11/8/95
2/8/96
5/9/96
11/15/96
5/20/97
11/18/97
5/19/98
11/19/98
3/30/99
Nitrate m
7.3
37
27
4.4
5
56
7.9
8.5
11.7
24.1
30.9
49.9
50.4
Ammonia m 1
No Data
Date
11/3/99
3/28/00
11/16/00
4/5/01
10/24/01
3/29/02
10/18/02
5/2/03
10/17/03
4/16/04
10/28/04
7/18/05
10/27/05
Nitrate m
56
67
68
62
78
81
76
62
60
90
100
120
I
150
Ammonia m
No Data
<0.10
<0.10
<0.10
NS
NS
<0.10
Date
4/26/06
10/23/06
5/1/07
10/15/07
4/25/08
12/18/08
4/9/09
10/30/09
4/6/10
10/22/10
4/22/11
11/2/11
5/10/2012
Nitrate m
140
150
150
14.2
169
202
253
44.4
243
203
311
1
278
1
181
Ammonia m
<0.10
I <0.10
<0.10
<0.10
<0.10
<0.10
0.5
<0.10
1.7
0.62
1.6
1.8
0.33
Date
11/7/12
Nitrate m 1
223
Ammonia m
1.2

K65W7 H (Bedrock)
1
—4 Nitrate Results
0.9
--Ammonia Results
0.8
0.7
E
a
a
0.6
0
0.5
C
O
0.4
Y
CC
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z
0.3
0.2
0.1
0
0 0 0 0
0 0 0 0
Date
Date
12/19/08
4/9/09
10/29/09
4/6/10
10/21/10
4/21/11
11/l/11
5/9/2012
11/6/2012
Nitrate m 1
0.30
0.26
0.36
0.47
0.36
0.40
0.36
0.72
0.54
Ammonia m I
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10

K65W7 K (Bedrock)
200
0 Nitrate Results
180
—e—Ammonia Results
—Nitrate 21, Standard
160
140
8
9
0 120
0
.*. 100
A
d
u
80
�0
w 60
z
40
20
O
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Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
5/l/07
10/15/07
4/25/08
12/19/08
4/9/09
10/30/09
4/7/10
10/22/10
Nitrate m I
81
89
190
1
100
120
89
25.9
99.5
1
108
95.4
99.4
77.4
84.6
Ammonia m 1
NS
NS
4.1
3.7
11
4.5
4.2
4.8
4.1
4.2
3.6
3.6
3.8
Date
4/21/11
11/2/11
5/10/2012
11/7/2012
Nitrate m I
92.3
85.3
1 87.1
85.6
Ammonia m 1
2.8
2.7
1 2.6
1 2.3

K65W7 L (Bedrock)
200
Nitrate Results
180
t Ammonia Results
Nitrate 21, Standard
160
a�
140
120
0
0
ee
100
i
d
C
�j
8o
w
60
Z
40
20
s
Q
1-mil i i i
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l� l� 00 00 01 0l
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i i
O O ti N
Date
Date
10/28/04
7/18/05
10/27/05
4/25/06
10/23/06
1 5/l/07
j 10/15/07
j 4/25/08
j 12/19/08
j 4/9/09
j 10/30/09 1
4/7/10
10/22/10
Nitrate m 1
22
98
110
1
130
1
120
99
30.5
104
1 103
93.8
103
85.7
95.2
Ammonia m
NS
NS
7.7
7.4
11
11
12.9
12.4
1 10.4
10.1
9.4
9.0
12.8
Date 11
4/21/11
11/2/11
1 5/10/2012
11/7/2012
Nitrate m 1
96.4
116
94.9
97.8
Ammonia m
7
12
10.7
4.9