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HomeMy WebLinkAboutWI0400091_Monitoring (Report)_20090420KL EINFEL DER �� _ - Bright People. Right Solutions. r -A o°� Quarterly HiSQC Monitoring Report Gilbarco 7304 West Friendly Avenue Greensboro, North Carolina Kleinfelder Project No. 97746 w T o yooc) ?/ RECEIVED I DENR / DWO AOUIFFR WTFr71M SFr TIOH APR 2 0 ?oqq (KL EI NFEL DER 8rrght People. Right Soluroans. April 17, 2009 Mr. Qu Qi Aquifer Protection Section — UIC Staff DENR — Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Quarterly HiSQC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Kleinfelder Project No. 97746 Dear Mr. Qi: Kleinfelder is pleased to provide our quarterly monitoring report for the Underground Injection Control {UIC} Permit for treatment of groundwater with the HiSOC system at the referenced site. This report summarizes our field activities, observations, and includes the analytical results of the groundwater samples. Should you have any questions or require additional information, please d❑ not hesitate to contact Chris Hay at your convenience. Very truly yours, Christopher W. ay, E.I. Environmental Group Manager Gail G. Licayan, P.E. Project Professional CWHIGGL:cas RECEIVED I DENR ! %10 AOUIF;P ppnTFrTlnN gFrMON APR 2 0 ?nnq 313 Gallimore Dairy Road, Greensboro, NC 27409 p 1336.668.0093 f 1 336.668.3868 GILBARCO Greensboro, North Carolina Groundwater Incident Nos. 12960 And 15123 SITE INFORMATION Address: Contact: Telephone: Latitude and Longitude Risk Classification: Lana Use Category - LAND OWNERSHIP Name: Address: Telephone: Attention: RELEASE INFORMATION April 17, 2009 7300 West Friendly Avenue Greensboro, North Carolina Ms. Beth Money 336.547.5130 36.0901 °N, 79.9282 °W Low Commercial Gilbarcv 7300 West Friendly Avenue Greensboro, North Carolina 27420 336.547.5130 Ms. Beth Money Cause of Release: Release from a 1,000-gallon diesel UST and four 550-gallon gasoline USTs was discovered in November and December 1994. The quantity released is unknown. ENVIRONMENTAL CONSULTANT Name: Kleinfelder Address: Post Office Box 18846 Greensboro, North Carolina 27419-8846 Telephone: 336.668.0093 Attention: Mr. Christopher W. Hay Seal and Si]6►fiertifying Professional Engineer �' 'E Si ���f���� I, Gail cite-Q , a s ivnai Engineer for Kleinfelder do certify that the information contained ir)i%m*Drt�' c&rect and accurate to the best of my knowledge. Gail G ..p?�'r 7��1 Registered ioplira Engineer No. 031532 977461 GS009R022 Page l RELOVED DENR i DWO April 17, 2009 Copyright 2009 Kleinfelder AQIIIFFP PRnTFrTIN4 qR-TION APR 2 0 ?i11r'9 TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................. ....... ...........1 2.0 GROUNDWATER MONITORING ACTIVITIES ............... ...................... I ..... ........ I ... 11 3.0 GROUNDWATER ANALYTICAL RESULTS............................................................2 4.0 HiSOC INSTALLATION AND MONITORING...........................................................3 5.0 CONCLUSIONS AND RECOMMENDATIONS.........................................................5 TABLES 1 Groundwater Elevation Data 2 Aquifer Characteristics Field Analysis Summary 3 Summary of Groundwater Sample Results 4 Historical Summary of Groundwater Sample Results 5 Estimated Dissolved Hydrogen Concentrations at Injection Wells 6 Estimated Hydrogen Consumption FIGURES 1 Site Location Map 2 Site Plan 3 Groundwater Potentiometric Surface Map 4 Total VOCs Concentrations 5 Total Chlorinated Hydrocarbons APPENDICES A Laboratory Reports and Chain -of -Custody Documents B Total VOC Graphs 977461 GS009R022 Page ii April 17, 2009 Copyright 2009 Kieinfelder 1.0 INTRODUCTION The subject site is located at 7300 West Friendly Avenue in Greensboro, Guilford County; North Carolina (Figure 1). There are currently two open groundwater incidents (Incident Nos. 12960 and 15123). The incidents have a commingled plume and are being treated with the same corrective action plan. A pump and treat system is operating at the site. The system consists of four recovery wells, an oil -water separator, and an air stripping system. In January 2008, Kleinfelder submitted a CAP Addendum recommending the use of HiSOC and iSOC technology to degrade the chlorinated and petroleum hydrocarbons in groundwater at the site. This technology will work in concert with the existing groundwater recovery system and supplement the ability of the system to contain the contaminant plume within the property limits and reduce contaminant levels. The KSOC system was installed in June of 2008 and began operating on June 13, 2008. The baseline sampling event was conducted on June 5, 2008. The purpose of this report is to summarize the quarterly monitoring of the HiSOC system performed on March 5 and 27, 2009. 2.0 GROUNDWATER MONITORING ACTIVITIES Static water levels were measured in the existing monitoring wells on -site on March 5, 2009. Groundwater samples were collected from ten of the monitoring wells (MW-7, MW-11. MW-13, MW-13D, MW-14, MW-23D, MW-24, MW-25, MW-42. and MW-45) and analyzed for VOCs by EPA Methods 601 and 602, isopropyl ether, methyl tert-butyl ether, ethylene dibromide, and xylenes. In response to a letter from NCDENR requesting that MW-14D and MW-43D be included in future monitoring events, groundwater samples were collected from these wells on March 27, 2009. Field parameters including oxidation-reduction potential (ORP), pH, conductivity, dissolved oxygen, and temperature of representative groundwater samples were also recorded from each monitoring well sampled. Groundwater elevations in the existing monitoring wells were used to determine the groundwater flow direction, average hydraulic gradient, and plume orientation. Table 1 provides a summary of monitoring well construction details and the groundwater elevations measured on March 5, 2009. The 97746 1 GS009R022 Page 1 April 17, 2009 Copyright 2009 Kleinfelder monitoring well locations are shown on Figure 2. The static water levels measured on March 5, 2009 between monitoring wells MW-32 and MW-45 indicate a horizontal groundwater flow gradient of 0.04 feet per foot to the northwest. A groundwater flow map of the shallow aquifer based on the March 5, 2009 groundwater elevations are shown on Figure 3. Free product was not observed in any of the monitoring wells during the sampling event. Based on data provided in the October 1995 Corrective Action Plan, the surficial aquifer has an average hydraulic conductivity of 0.09 feet per day. The average groundwater velocity is estimated to be 0.01 feet per day (4 feet per year), based on the average groundwater gradient from the March 5, 2009. water level measurements and an estimated effective porosity of thirty percent. Groundwater samples were collected from monitoring wells MW-7, MW-11, MW-13, MW-13D, MW-14, MW-14D, MW-23D, MW-24, MW-25, MW-42, MW-43D, and MW-45 using disposable polyethylene bailers. The wells were purged of three well volumes of water or until they were bailed dry. Groundwater purged from the monitoring wells was disposed of in the on -site groundwater recovery system. Groundwater samples were collected and placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersville, North Carolina. 3.0 GROUNDWATER ANALYTICAL RESULTS The groundwater field analysis generally indicates that the subsurface environment is within acceptable limits for biodegradation to occur. The field measurements recorded on March 5 and 27, 2009 are summarized in Table 2, which includes the preferred conditions for natural biodegradation of chlorinated compounds within the groundwater plume. Conductivity is recorded for quality control and sampling consistency. Volatile organic compounds were detected at levels above the respective North Carolina groundwater quality standards established in 15 NCAC, Subchapter 2L (2L Standards) in each of the twelve monitoring wells sampled. The analytical results are summarized in Table 3 and a historical summary of groundwater sampling results is presented in Table 4. Chain -of -custody documents were maintained throughout the 97746 J GS009R022 Page 2 April 17, 2009 Copyright 2009 Kleinfeider collection and transportation process and are included in Appendix A with the laboratory reports. Historical total volatile organic compound concentrations for each monitoring well sampled are shown in individual graphs included in Appendix B. The individual graphs of the total VCC concentration for each monitoring well indicate MW-7, MW-11, MW- 13D, MW-14, MW-14D, MW-24, MW-42, and MW-43❑ generally have trends of decreasing contaminant levels. The graph of contaminant concentrations in MW-45 indicates the total VOCs level remains fairly consistent. Monitoring wells MW-13 and MW-23D graphs show a recent increase; however, they have tetrachloroethene concentrations below the laboratory detection limits. The increase in contaminant levels in these weals is caused by increases in cis- 1,2-dichloroethene and vinyl chloride which are degradation components of tetrachloroethene. The trend of rising contaminant concentrations are of concern in monitoring well MW-25. Total VOCs concentrations detected during the March 2009 sampling event are shown on Figure 4. The current hydrogen injection phase of the corrective action plan targets the reduction of chlorinated hydrocarbon contaminant levels in the groundwater. The oxygen injection phase will target the reduction of petroleum hydrocarbons. The volatile organic compounds targeted during the hydrogen and oxygen injection phases of the corrective action plan are separated in Table 4 by a double line. Total chlorinated hydrocarbons concentrations detected during the March 2009 sampling event are shown on Figure 5. Historical chlorinated hydrocarbon contaminant levels generally follow the decreasing trend of total VOCs in MW-7, MW-11, MW-13D, MW-14, MW- 14D, MW-24, MW-42, and MW-43D; consistent levels in MW-13, MW-23D, MW-45; and the rising trend in MW-25. 4.0 HiSGC INSTALLATION AND MONITORING Kleinfelder applied for a permit from the Underground Injection Control (UIC) Program for the installation of a hydrogen and oxygen delivery system for remediation of contaminants in groundwater at the site. A permit dated March 20, 2008 was issued for the site (Injection Well Permit W10400091). The permit is effective through April 30, 2010. 97746 I GS009R022 Page 3 April 17, 2009 Copyright 2009 Kleinfelder Installation of the injection equipment was initiated on April 9 through April 11, 2008. The existing protective casings were removed from monitoring wells MW-7, MW-10, MW-23D, MW-29, and MW-34. Ten -inch diameter PVC casings were installed to a depth of five feet below ground surface adjacent to the monitoring well locations to hold the hydrogen cylinders. Six to ten inches of gravel was placed in the bottom of each casing. Excavations were completed for installation of twenty four -inch square, steel well vaults and the vaults were set in concrete flush with the ground surface. Protective vaults were also installed adjacent to the existing above grade protective covers for monitoring wells MW-14D. MW-15, MW-16, MW-24, and MW-43D. The 15-inch by 24- inch PVC protective vaults were installed over the cylinder casings. Vents were installed in the protective vaults to allow hydrogen to be released in the case of a leak from the delivery system. The HiSOC equipment from InVentures was installed at the site in ten existing monitoring wells (MW-7, MW-10, MW-14D, MW-15. MW-16, MW-23D, MW-24, MW- 29, MW-34, and MW-431D) on June 13, 2008. Within each injection well is a HiSOC unit and filter. Hydrogen is supplied from a compressed gas cylinder with a regulator and gauge connected to the HiSOC unit by Parflex tubing and a support cable. Four - foot grounding rods were installed and connected to the regulator assembly of the gas cylinders. The HISOC installation locations are shown on the figures in orange. In anaerobic bioremediation applications. the HiSOC supersaturates the treatment well with dissolved hydrogen, typically at a concentration of 1 to 4 parts per million (ppm) depending on the immersion depth of the HiSOC unit in groundwater. The dissolved hydrogen concentration achieved in the injection well depends on the height of the water column in the well. Each atmosphere of pressure allows for a maximum of approximately 1.6 ppm of dissolved hydrogen. Table 5 estimates the dissolved hydrogen concentrations in each of the injection wells. These concentrations are estimated based on the approximate pressure at the installation depth of the HiSOC based on the depth of the water column in the injection wells. The calculation is made with the assumption that 1.6 ppm of hydrogen is dissolved in the groundwater per atmosphere of pressure. Hydrogen is infused from the HiSOC into the treatment well at a typical rate of 28 standard cubic centimeters per minute or approximately 1.4 cubic feet per day. The hydrogen consumption in each of the injection wells is tracked to estimate the 97746 1 GS009R022 Page 4 April 17. 2009 copyright 2009 Kleinfelder remaining service life of the hydrogen cylinders. Table 6 shows the recorded hydrogen cylinder pressures and estimates a date for each injection well that the cylinder should be replaced. It is anticipated that the hydrogen cylinders will be replaced prior to the next quarterly monitoring event scheduled for June 2009, The HiSOC produces a convection current in the well with a designed release bubble from the top of the HiSCC to distribute dissolved hydrogen rich water throughout the screened interval. A curtain of hydrogen rich water disperses around the well into the adjacent groundwater forming a treatment zone allowing enhanced bioremediation to degrade the target contaminants. 41IMI61DON RDS]Z&V_'L'18JM:me]&IAI =1K'IITAd[a]iI'll The groundwater potentiometric map indicates that the groundwater flow direction at the site is from the southeast to the northwest under a gradient of 0.04 feet per foot as measured between MW-32 and MW-45. Groundwater aquifer characteristics monitored during the sampling event indicate suitable conditions for biodegradation of chlorinated hydrocarbons exist at the site. Both the total chlorinated hydrocarbons and petroleum hydrocarbons contaminant levels in monitoring wells MW-7, MW-11, MW- 13D, MW-14, MW-24, and MW-42 have decreased when compared to the groundwater contamination levels during the baseline sampling event in June 2008. Monitoring wells MW-14❑ and MW-43❑ were not sampled during the June baseline sampling event; however, contaminant levels in both wells have decreased since their most recent sampling in 2006. Groundwater contaminant levels in monitoring wells MW-13, MW-23D and MW-45 remained consistent with the baseline levels and monitoring well MW-25 showed an increase. Monitoring well MW-13 and MW-23D have tetrachloroethene concentrations below the laboratory detection limits. The increase in contaminant levels in these wells is caused by increases in cis-1,2-dichloroethene and vinyl chloride which are degradation components of tetrachloroethene. Monitoring well MW-25 also shows an increase in these degradation components; however, there is an increase in tetrachloroethene as well. A comparison of total chlorinated hydrocarbons in the ten monitoring wells sampled since the baseline sampling event in June 2008 indicate a reduction by 33 percent. 977461 GS009R022 Page 5 April 17, 2009 Copyright 2009 Kleinfelder Corrective action monitoring will be conducted on a quarterly schedule and the next event should be scheduled for June 2009. During the next sampling event, we recommend the following wells are sampled: MW-7, MW-13, MW-13D, MW-14, MW-14D, MW-16, MW-23D, MW-24, MW-25, MW-42, MW-43D, and MW-45. We also recommend moving the HiSQC unit from monitoring well MW-10 to MW-25. Monthly system checks should also be conducted during the next quarter to monitor the rate of hydrogen consumption of the HiSOC delivery system. Copies of this report have been mailed to the Guilford County Department of Environmental Health in Greensboro, North Carolina and the SIC Program in Raleigh, North Carolina. 977461 GS009R022 Page 6 April 17, 2009 Copyright 2009 Kleinfelder TABLE 1: GROUNDWATER ELEVATION DATA Well ID Total Depth {feet TOC) TOC Elevation (feet} Date Water Level Measured Static Water Level feet TOC Groundwater Elevation feet MVV-7 29.9 861.19 03/05/09 5.82 855.37 MVV-10 336 857.68 03/05/09 7.1E 850.52 MW-11 25.1 859.26 03/05/09 12.80 846.46 MW-12 16.8 851.50 03/05/09 4.17 847.33 MW-12D 27.0 851.06 03/05/09 5.85 845.21 MW-13 24.2 861.29 03/05/09 14.10 847.19 MW-13D 39.4 860.40 03/05/09 12.93 847.47 MVV-14 24.8 859.32 03/05/09 17.65 841.67 MW-14❑ 41.0 859.26 03105M9 18.80 840.46 MW-15 25.2 857.71 03/05/09 12.08 845.63 MW-16 35.2 863.60 03/05/09 27.95 835.65 MW-23D 57.1 860.90 03/05/09 15.26 845.64 MW-24 58.8 858.81 03/05/09 20.40 838.41 MW-25 168.9 86147 03/05/09 22.83 838.64 MW-27 44.0 862.74 03/05/09 13.13 849.61 MVV-28 23.8 861.54 03/05/09 8.04 853.50 MW-29 18.8 861.13 03/05/09 4.28 856.85 MW-30 73.4 862.28 03/05/09 12.83 849.45 MW-31 19.0 861.73 03/05/09 10.74 850.99 MW-32 19.6 861.76 03105/09 9.27 852A9 MW-33 21.0 861.77 03/05/09 14.83 846.94 MW-34 21.0 860.45 03/05/09 well flooded --- MW-40 29.7 860.62 03/05/09 9.53 851.09 MW-41 20.3 860.52 03/05/09 6.90 853.62 MW-42 35.0 865.32 03/05/09 29.37 835.95 MW-43D 53.0 865.47 03/05/09 29.62 835.85 M W -44 28.5 NM --- --- -- MVV-45 36.2 86179 03/05/09 27.29 834.50 Notes: feet TOC = feet below top of well casing NM = Not measured 97746 1 GS009RO22 Copyrighl 2009 Kleinfelder Page 1 of 1 April 17. 2009 TABLE 2: AQUIFER CHARACTERISTICS FIELD ANALYSIS SUMMARY Monitoring Well Sample Date Temperature [ °C j pH Conductivity (m5lcm) DissolvedRedox Oxygen m �L (mV) Preferred Conditions 200C S<pH<9 -- <0.5 mg1L <50 mV MW-7 03/05/09 17.78 7.72 0.234 0.70 -134.7 MW-11 03/05/09 18.07 6.40 0.323 0.85 131.7 MW-13 03/05/09 19.94 6.31 0.396 1.92 427.7 MW-130 03/05/09 18.32 6.41 0.412 0.93 98.3 MW-14 03/05/09 16.35 6.61 0.166 5.37 115.3 MW-14D 03/27/09 16.21 6.52 0.283 1.18 68.7 MW-23D 03/05/09 17.36 7.51 0.705 0.52 -117.7 MW-24 03/05/09 15.79 6.96 0.557 0.29 -61.7 MW-25 03/05/09 15.94 8.22 0.254 0.19 -122.0 MW-42 03/05/09 15.00 7.30 1.415 5.27 292.1 MW-43❑ 03/27/09 14.83 6.81 0.393 1.71 -38.0 MW-45 03/05/09 14.37 7.41 0.457 1.03 -26.5 Notes: Redox = oxidation-reduction potential °C = degrees Celsius m51cm = millisiemens per centimeter mg/L = milligrams per liter, analogous to parts per million mV = millivolts Conductivity is measured for consistency in groundwater sample collection. 97746 1 GS009R022 Copyright 2009 Kleinfelder Page 1 of 1 April 17, 2009 TABLE 3: SUMMARY OF GROUNDWATER SAMPLE RESULTS Parameter NCGS 2L Standard Analytic I Results Sample ID MVV-7 MW-11 MW-13 MW-13D MVV-14 MW-140 MVV-23D MVV-24 MW-25 I MW-42 I MW-43❑ j MW-45 Collection Date 03/05/09 03/05/09 1 03/05/09 03/05/09 03/05/09 03/27/09 03/05/09 03/05/09 03/05109 1 03/05/09 t 03/27/09 1 03/05/09 Volatile Organic Com ounds by EPA Method 6011602 IL Tetrachloroethene 0.7 BDL 1.3 BDL BDL 32 10.6 BDL 1,250 24.9 2J BDL 1.3 Trichloroethene 2.8 BDL BDL BDL BDL BDL BDL BDL BDL 8.3 BDL BDL BDL cis-1,2-Dichloroethene 70 935 1.5 119 14.6 BDL 1.0 173 466 51 BDL BDL 8DL 1,1-Dichloroethene 7 BDL BDL BDL BDL BDL BDL BDL BDL 1.1 BDL 9.3 BDL Vinyl Chloride 0.015 BDL BDL BDL 3.4 BDL BDL 19.4 BDL BDL BDL BDL BDL 1,1-Dichloroethane 70 BDL BDL BDL 8DL BDL BDL 1.1 BDL BDL BDL 1.6 BDL 1.1,1•Trichloroethane 200 BDL BDL t BDL j BDL I BDL I BDL I BDL I BDL I BDL I BDL 1 1.2 1 BDL Total Chlorinated Hydrocarbons 935 3 119 18 32 12 194 1,716 85 3 12 1 Benzene 1 BDL BDL BDL BDL BDL BDL 1.7 117 BDL BDL 9.0 BDL Eth (benzene 550 749 BDL SQL BDL BDL BDL BDL BDL BDL BDL 7.5 BDL Total X lenes 530 723 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL MTBE 200 BDL BDL 3.1 13.4 BDL BDL 194 BDL 4.8 BDL 3.6 BDL Diisopropyl ether 70 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Naphthalene 21 384 BDL BDL BDL BDL BDL BDL BDL BDL BDL 4.4 BDL Total Petroleum Hydrocarbons 1,856 0 3 13 0 0 196 117 5 0 25 0 Total VOCs 2,791 3 122 31 32 12 389 1.833 90 3 37 1 Notes: NCGS 2L Standard = North Carolina Groundwater Standard BDL = Below Detection Limits pg1L = Micrograms per liter, analogous to parts per billion BOLD = Concentration exceeds the NCGS 2L Standard MTSE = Methyl-tert-butyl ether 97746 1 G5009RO22 Copyright 2009 Kleinfelder Page 1 of 1 April 17, 2009 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample 10 Chlorinated H dracarbone Total Chlorinated Hydrocarbons Petroleum H drocarborm Total Benzene Toluene Ethylbenzene Totalxylenes MTBE DiLsopropylelher Naphthalene Petroleum Hydrocarbons 1 1.000 550 530 2D0 70 21 TotalVOCs Collection Date Tesrachlprnetnene TrtChioroelhene c45 o et Dlrhirohane 1,1-Drchloroelhena Vinyl Chloride 11-oichlorowhane 1,2-Dichloroethane Irans•1,2- ❑Ichtoroathane 111-Trnchloroethan NCGS 2L Std 0.7 2 8 70 7 0 015 TO 0 38 100 200 MW-7 09/27/90 790 190 SOL BDL BDL BDL BDL BOL 59 1.039 6SO 5,309 1,600 5,700 BDL BDL BDL 13150 14.189 01/14192 BDL 360 BDL BDL BDL BDL BDL BDL BDL 360 480 3,900 2,100 7,11D0 BDL BDL BDL 13 5B0 13.940 0311IM BDL SOL BDL 354 BOL BDL BDL BDL 239 592 468 8,920 2,200 8,99D BDL SOL BDL 20.578 21.170 05,r25199 8DL BDL SOL 723 BDL BDL BDL BDL 347 1.070 253 2,280 2,290 10,80D BDL BDL BDL 15.623 16.693 04122/03 BDL BDL BDL BDL BDL 8DL BDL BDL Be Be BDL 220 2,400 5,700 BDL 60 BDL 8.380 8468 06/30104 BDL BDL 2,300 BDL BDL BDL BDL BDL BOL 2.300 BDL 110 1,800 3,800 BDL 8DL 620 6.230 B.530 OWM05 BDL BDL 2,1D0 BDL BDL SOL BDL BDL SOL 2.1DO BDL BDL 1,600 3,020 BOL BDL 520 5.140 7.240 OBI25106 BDL BDL 2,000 14 BDL BOL BDL 1 5 14 2030. 1.7 23 370 380 11 3 3 82 B71 2 901 1211410G 3,6 4 2,100 570 BDL 15 BDL 51 13 2711 4.1 39 5,300 1,660 80L BDL 440 3.443 6.154 06/05108 BDL BDL 1,750 BDL SOL BDL SOL BDL BDL 1.750 SOL SUL 1,040 1,280 BDL BDL 401 2.721 4.471 09/04/06 SUL BDL 1,190 BDL BDL SUL BDL BDL BDL 1190 8pL BDL 788 873 BDL SUL 301 1.962 3.152 01/05109 BDL SOL 7" BDL BDL BDL BDL BDL BDL 798 BDL BDL 643 598 BDL BDL 3" 1.549 2.347 03J05109 BDL BOL 935 BDL BDL BDL BDL SDL BDL 935 BDL BDL 748 723I BDL BDL 384 1.B56 Z791 MW-8{ehandonedl 0W27190 BOL SDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL 1 BDL BDL BDL 1 1 01114192 SUL SDL BDL BDL BDL BDL BDL SOL BDL 0 BDL SOL _ SUL BDL BDL BDL BDL 0 0 05/15/92 BDL SUL BDL BDL BDL BDL SOL BDL BDL 0 SOL BDL BpL SUL SOL BDL BDL 0 0 MW-9(abandoned) OW27M 10 2 SOL BDL SOL BDL SOL BOL BDL 12 2 SOL SDL SOL BOL SOL BDL 2 14 01/14192 SOL SOL SOL BDL BOL BOL BOL BDL SOL 0 SOL SOL BDL BOL I SOL SOL BDL D 0 051T5192 SDL BDL BDL BDL SOL BDL BOL BDL BDL 0 BDL BDL BDL SOL SOL SOL BDL 0 0 MW-10 09/27/90 76 140 SOL SOL SOL BDL SOL BDL 140 356 2,900 66 801 670 SOL BDL SOL 3.635 3.992 01/14/92 SOL 78 SOL 120 SOL BDL SOL BDL SOL 198 2,900 BDL SOL 120 SOL BDL BDL 3.020 3.215 03111/98 SOL BDL BDL 13,9 BDL BDL BDL SOL BDL 14 234 BDL BDL BDL SOL BDL BDL 234 248 0512M9 SOL SUL BDL SOL SOL SOL BOL BDL SOL 0 36 BOL BDL SOL SDL BDL SOL 36 36 10110102 6.9 23 SDL 44 BOL SOL BOL BOL 73 20 220 85 15 71 2,200 16 BDL 2.532 2.551 04/22103 3.2 1 3 BOL BDL BUL BDL SOL BAL 2 6 7 47 BDL SOL SOL 1,100 2 9 SOL 1.150 1.157 Dfil''J0104 BDL BDL 8 T BDL BDL BDL 8DL BDL BDL 8 22 BOL 2 B 5.8 770 2 8 BDL 803 812 06/24 5 BDL BDL BDL BOL SOL BDL 8DL BDL BDL 0 43 BDt BDL BOL 690 BDL BDL 723 723 08/24106 BDL BDL 3 SOL SOL BDL BDL BDL SOL 3 8.1 SOL BDL BDL 360 4 3 BDL 372 375 MW-11 06/30/04 Z.1 3 1 4 SOL SOL BDL BDL SUL SOL 7 SOL BDL BDL BDL 41 SOL BOL 4 11 08/15/05 S 3.4 97 BDL BDL BOL BOL 8131. SOL 18 SOL BDL BDL BDL 22 SOL 8DL 2 21 08P24106 4.9 25 52 SOL BDL BDL SOL SOL BDL 13 SOL BDL 81)L BDL 44 SOL SOL 4 17 MOWS 6,9 15 50 BOL BDL BDL BDL BOL BDL 13 SOL BDL SOL BDL BDL SOL BDL 0 13 09104108 BDL BDL BDL SOL BDL 8DL BDL SOL SOL 0 BOL BDL SOL SOL BDL SOL BDL 0 0 01105109 2.7 1 6 2 5 BDL BDL BDL SDL BOL BOL 7 BDL 81)L BDL BDL 1 1 BDL SOL 1 8 03105M 1.3 BOL 15 SOL BDL BDL SOL SOL BOL 3 SUL SOL SOL SOL SOL BDL BpL 0 3 MW-12 D9127190 BDL BDL BDL SOL BDL BDL SOL BDL BDL 0 SOL BDL 8DL BDL BDL BDL BDL 0 a 01/14/92 BDL SOL 8DL SOL BDL BDL BDL BOL BDL 0 SOL BDL BDL BOL BDL BDL BDL 0 0 03111/98 BDL SOL BDL SOL SOL BDL BDL BDL SOL 0 SUL BDL BDL SOL SOL SOL SOL 0 0 05/26/99 SOL BDL BDL BOL SOL SUL BDL SUL SOL 0 BDL SOL BDL 13DL BDL BDL SOL 0 0 06W04 BDL SOL SOL BDL SOL SUL BDL SUL BDL 0 BDL BDL BOL SOL BDL SOL SOL 0 0 08/15/05 SOL BOL SOL BDL BDL BDL BDL BDL BDL 0 BDL BDL SOL SOL 90L SOL SOL 0 0 08/24/06 BDL BDL SOL SOL BDL SOL BDL SOL BDL 0 BDL BDL BDL BOL SOL SOL BDL 0 0 MW-12D 09/27/90 SOL BDL SOL SOL BDL 8DL BDL SOL SOL 0 BDL BDL SOL BDL SOL BDL SOL 0 0 01/14192 BDL SOL SOL BDL BDL SOL BDL SOL BDL 0 SOL SOL SDL SOL SOL BDL BDL 0 0 03/11198 BDL BOL BDL BDL BDL BDL SOL BDL BDL 0 SDL BDL BOL BDL SOL BDL SOL 0 0 05128/99 SUL BOL SOL BDL SOL SOL SOL SOL BDL 0 SOL BDL BDL SOL SOL 8DL BOL 0 0 OW30/04 BDL SOL SOL SOL SUL BDL SOL SOL SOL 0 SOL SOL BDL SOL BDL BDL BDL 0 0 08/15/05 SOL 8DL BDL SOL SOL BDL SOL BDL SOL 0 BDL BDL BDL BDL SDL BDL SOL 0 0 D8I24M6 BOL BDL BOIL 9DL SOL BDL SOL BDL BDL 0 BDL SDL BDL SOL SOL BDL BDL 0 0 Notes: All units measured in ygfL BDL - Below Detection Llmils NCGS 2L Sid - North Carolina Groundwater Standard BOLO - Concenlralion exceeds the 2L Groundwater quality Standard MTSE - Methyl *W butyl ether 97746 1 GS0O9R022 Copyright 2009 Klemtelder Page 1 of 4 April 17, 2009 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated H drocarbons Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOcs Collection Dare os-1.2 Tetrachlaroethene Trichldroetnene c D,Crtloroelhene 7 T-pichloromhene Vinyl Chlonde 1 1-Dichloroethane 1.2-Dirhmreelhane 0ans-1 2 Dichioroelhane 1.1.1-Tnchicroe! Benzene Toluene Elhylhenzene Total %ylenes MTBE Onsopropyl ether Naphthalene NCGS2LSid 07 2.8 79 7 0015 70 0.38 100 200 1 1,000 550 530 200 J 70 21 MW-13 09/26/90 2 BDL SOL SOL SOL SOL SOL BDL SOL 2 SOL. BDL SOL SOL BDL SOL BDL 0 2 01114/92 130 36 SOL SOL. SOL SOL SOL BpL BDL 166 BDL BDL SOL SOL BOL SOL SOL 0 166 05115192 130 20 SOL SOL SOL SOL SOL SOL SOL 15O SOL SOL SOL BDL BDL SOL SOL 0 ISO 0311IM 2.5 41 BDL BOL BDL SOL SOL SOL BDL 7 SOL SOL SOL SOL BOL BDL SOL a 7 05126I99 41 1s BpL SOL BDL BDL BDL SOL SOL 19 BpL SOL SOL SOL BDL BDL SOL 0 19 06/30104 BDL 6.5 140 SOL BDL BDL BDL SOL SOL 147 BDL BDL 8DL SOL 13 BDL SOL 13 160 09/15/05 SOL SOL 110 BDL SOL BDL SOL SOL SOL 110 SDL 8DL SOL SOL BDL BDL SOL O 1 110 08+24l06 BDL 2.9 110 SOL SOL SOL BDL 1 t SOL 114 SOL SDL SOL SOL 5.4 SOL SOL 5 119 ❑610510e SOL BDL 94.7 SOL SOL SOL BDL SOL SOL 95 SA SDL BDL SOL BDL SOL BDL 6 101 09104me BDL SDL 679 BDL SOL SOL SDL SDL SOL 68 BDL 8DL SOL SOL BDL SOL SOL 0 Be 01105109 SOL SOL 667 SOL SOL BDL SOL SOL BOL 69 3.2 SDL BDL SOL 52 SOL SOL 8 77 03105109 BDL SOL 11S BDL SOL 8DL SOL SOL SOL 119 BDL BDL BDL BDL 3.1 SOL BOL 3 122 MW-13D 06130104 SOL SOL t8 BDL 1.5 BDL SOL BDL SOL 20 IA SOL BDL BDL 26 11 SOL 28 48 08115105 SOL SOL 37 BDL 1.4 SOL SOL BDL SOL 38 SOL 8DL BDL BDL 20 1.3 SOL 21 60 OW41DS BDL SOL 30 SOL 1.3 SOL SOL BDL SOL 31 SOL BDL Dot SOL 19 BDL SOL 19 50 0610510E SOL SOL 216 SOL 3.2 SOL SOL SOL SOL 25 SOL SOL 30 36 12.5 17 SOL 21 46 09104M BDL SOL 152 BDL 3A BDL BDL SOL BOL 18 SOL BDL SOL SOL 176 BDL SOL 18 36 OV05109 SOL SOL 174 SOL 4.2 SOL SOL SOL BOL 22 SOL SOL SOL SOL 16.3 1 1 BDL 17 39 03105/09 BDL BDL 146 BDL 34 SOL BDL SOL SOL 18 SOL BDL BDL SOL 134 BDL BDL 13 31 MW-14 09/26/90 1,300 8DL BDL 9DL SDL SOL BDL SDL BDL 1.300 SOL SOL SOL BDL BDL SOL SOL 0 01114/92 1,400 8DL SOL BDL BDL SOL 180 SOL 100 1.680 SOL 60 SOL 100 ROL SOL SOL 160 840 03/11/98 en SOL SOL BDL SOL BpL BDL Dot BOL 80 SOL SOL BDL SOL BDL SOL BDL 0 0 0512SMS 67 SOL SOL SOL SOL SOL aDL SOL SOL 67 SOL SOL SOL SOL BDL SOL SOL 0 j30' 7 D4122103 110 BDL SOL BDL SOL SOL SOL SOL SDL 110 1.1 1.7 SOL 19 BDL SOL SOL 5 15 06MX4 80 SOL 6OL BDL SOL BDL BDL SOL SOL 80 SOL SOL SDL SOL BOL BDL BDL 0 0 08/16/05 58 SOL 8DL BDL SOL BOL SOL SOL 8DL 58 SOL BOL SOL SOL BDL BDL BOL 0 e 08/24106 46 SOL SOL BDL BDL BDL SOL SOL SOL 46 BDL BDL BDL SOL DDL BDL BDL 06 06/,05108 54.0 SOL SOL SOL BDL BDL BDL BDL BDL 54 SOL SOL BOL BOL BDL SOL BDL ❑ 54 09/04100 50.0 SOL SOL SOL SOL SOL SOL SOL SOL 50 SOL BDL SOL SOL BOL SOL 8DL 0 50 ❑,05+❑9 293 SOL BDL SOL SOL 8Dl SOL SOL SOL 30 BDL SOL SOL SOL SOL SOL SOL 0 30 03105109 32 SOL BOL SOL BDL BOL BpL SOL BDL 32 BOL BDL BDL SDL SOL BDL BDL 0 32 MW-14D 09127M 110 3 BDL sa BDL 5 SOL BOL 20 196 46 1 BDL 5 BDL SOL SOL 51 247 01114/92 200 SOL SOL BDL BDL BpL SOL SOL SOL 200 65 3 SOL SOL BDL SOL aDL 68 268 05/15/92 55 SOL SOL 2.1 8DL SOL SOL BDL SOL 58 4,7 SOL SOL BDL BDL BOL ODL 5 63 09109/92 210 BDL SOL 23 SOL SM SOL BDL 13 246 220 SOL SOL SOL BDL SOL BDL 220 466 03111/98 3S,4 BDL BDL 10.6 SOL SOL SOL BDL BDL 46 SA SOL BDL BDL BDL SOL 8DL 6 52 05/25/99 201 BDL SDL 25 BDL SOL BDL SOL BOL 226 67 SOL BDL BDL BDL SOL SOL 67 293 1011=2 1 79 28 BOL 4 SOL 4.2 BDL BDL SOL 90 6.3 BDL SOL BDL 11 29 SOL 48 138 04122J03 40 SOL BDL 12 SOL SOL SOL SOL SOL 41 SOL SOL SOL BDL SOL 15 SOL 2 43 06/30104 29 SOL 30 35 SOL 2.2 SOL SOL SOL 35 BpL SOL SOL BDL 33 8DL BDL 3 38 ❑81161D5 55 } 8 15 3.3 BDL BDL SOL BOL SOL 75 5.4 SOL SOL SOL 3.2 7 3 DDL 16 91 OB114106 47 2 17 14 BOL HDL SOL Dot BDL 67 1.3 SOL SOL BOL 2.4 64 SDL 10 78 03/27109 10.0 SOL 10 SOL BDL SOL SOL BpL BpL 12 8DL SOL BDL BDL 80L SOL BDL ❑ 12 MW-i 5 0927190 SOL SOL SOL SOL BDL BDL SOL SOL BDL 0 BDL SOL BDL BDL SOL SOL SOL 0 0 01/14/92 SOL SOL SOL SDL BDL BDL SDL SOL 8DL 0 SOL SOL SOL BDL BDL SOL SOL 0 0 03111198 BDL SOL SOL BDL BDL 8DL SOL SOL BDL 0 SOL BDL BDL BOL BOL SOL BDL 0 0 05125199 4.9 3 SOL BDL BDL SOL SOL SOL SOL 8 BOL BDL BDL BOL 6DL SOL SDL 0 B 10110/02 13 7A SOL BDL BDL 14 SOL SOL 8DL 22 SOL BDL BDL SOL 29 SOL BDL 29 51 04/22/03 11 5 BDL SDL SOL 14 SOL BDL 8DL 17 SOL 8DL SOL SOL 17 SOL 8DL 17 34 06/30/04 7.5 3.9 a8 SOL SOL SOL SOL BDL 8DL 97 SOL SRL BDL SOL 18 SOL BDL 18 OW16105 5.8 2 3 47 SDL BDL BOL BDL 8DL BDL 56 BDL BpL BDL 8OL 15 BDL SDL 15 08/24/06 5.5 5 48 BDL BDL B17L BDL BDL BDL 59 BOL BOL BDL 8DL 8 BDL BDL 6 67 Notes: All units measured in N91 BDL - Below Detection Lim its NCGS 2L Std - North Carolina Groundwater Standard SOLD - Concen0ation exceeds the 2L Groundwater Quality Standard MTBE • Methyl -left butyl ether 97746 1 GS009R022 Copyright 2009 Kleinfelder Page 2 of 4 April 17, 2009 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample 10 Chlornated H drocarbons Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCs Collection Dale Telradlloroethene Tnchlordelhana Cis 1'2 Dichloraaihene i 1-Dichlor9athene Vinyl Chloride f,1-Dlchloraelhane 1,2-Dahlomethane Irans 1'2 Dichloroethane 7,1 1-Tnchlcroethan 8enxene Toluene Elhylbenzene Total Xylenes MTSE ❑lisopropyl ether Naphthalene NCGS 2L Std 0.7 28 70 7 0 015 70 0 3B 100 200 i 1 am 550 530 200 70 21 MW-16 Os126190 ROL SOL BDL ROL SOL SDL BDL BDL BDL 0 SDL SDL SOL SOL SDL SDL BDL 0 0 01/14/92 ROL BDL BDL ROL SDL ROL SOL ROL ROL 0 ROL BDL BOL SOL SOL ROL BDL 0 0 0317115E 1.9 SOL SOL SOL SOL ROL BDL SOL SOL 2 ROL HDL ROL SOL SDL SDL ROL 0 2 DW2199 2.4 BDL SOL BDL SOL SOL SDL ROL SOL 2 SOL BDL BDL BDL SOL BDL SOL 0 2 10/10102 22 3.a ROL 18 SOL SOL SOL SOL SOL 28 SOL BDL ROL ROL SOL BDL SDL 0 28 04/22/03 46 6.6 BDL 3.6 ROL ROL SOL ROL ROL 58 BDL BRL SOL SOL dDL SDL BOL 0 58 1761301D4 31 7A 24 2 7 BDL t BDL SOL SOL 66 BDL SOL SOL SOL SDL SOL BDL 0 66 061151D5 30 4.4 ROL 18 BDL SDL 8DL BDL SDL 36 SDL RQL 8DL 8DL BRL 17 BOL 77 53 06125/06 36 7,4 31 2.9 BDL ROL SOL BDL ROL 77 SRL SOL BDL SDL SDL BDL SOl- 0 77 MW-17(aoandoned 01143105) 09126/90 1 BDL SOL SOL SDL BDL SOL ROL SOL 1 SOL BDL SOL SOL SOL ROL RDL 0 1 01/14/92 SOL 3 ROL BDl ROL SOL BDL ROL BDL 3 8QL BDL SOL BOL BDL SDL SOL 0 3 03/11/90 SDL SOL BDL ROL BDL ROL BDL ROL ROL 0 SOL BDL BRL SQL 6DL BDL BDL D D 05102199 ROL ROL SOL SOL SOL ROL BDL ROL BDL 0 BDL 9DL 130L SQL ROL SOL BDL D 0 0613004 Sal- SDL BDL BDL BDL BDL ROL SOL 0 SDL 8DL SOL 8DL 17 SOL BDL 17 17 -RDL MW-23D 09/27/90 ROL 2 BDL ROL BDL 5 5 BDL SDL 12 1 SOL SDL SOL ROL 8DL SOL 1 13 01114W SDL BDL BDL BDL BDL 8DL ROL BDL BDL D ROL BDL SOL ROL SQL RDL BDL 0 0 05115192 BDL 22 ROL SOL ROL 5.3 ROL BDL BDL 8 46 8DL SOL ROL SOL SOL ROL 45 53 09M9192 1.8 6.3 SOL 54 BDL 65 2 BDL BDL 22 6.3 RDL ROL BDL ROL RDL SOL 6 28 0311119E 2.5 25 SOL 1 4 ROL 2.9 BDL BDL 4 13 T1 37 SOL SDL ROL SDL SOL 11 24 175J26199 ROL 4.1 SOL 24 ROL 5 7 2.6 BDL SOL 15 3,1 SOL SOL SDL ROL BDL SOL 3 1B 06/30/04 ROL ROL 200 SOL ROL SDL BDL SOL BDL 2DO SOL ROL BDL BDL 500 12 SOL 512 712 08115ro5 ROL ROL 280 BDL SDL SOL SOL BDL SOL 280 BDL SDL SOL BDL 310 SOL BDL 310 590 DW4106 SOL f 1 340 SOL 1.9 SOL SDL BDL SOL 343 1.8 9OL BDL BDL 310 9.1 ROL 321 664 OM908 SDL BDL 166 SOL BDL ROL aDL SOL SOL 166 SOL SOL 20.2 236 208 8DL ROL 252 418 09/04108 SOL BDL 5.3 ROL ROL ROL SOL SOL SDL 5 BDL SOL SOL BDL 19.3 SDL 8DL 19 25 Ut1O" SOL ROL 15.3 SOL BDL ROL SOL BDL ROL 15 SDL SOL ROL SOL 376 8DL BDL 315 53 03/05109 SOL BDL 173 BDL 19.4 11 SOL BDL ROL 194 1J SOL ROL BDL 794 SDL SOL 196 389 MW-24 09127/90 630 28 SDL 60 BDL ROL SOL SOL BDL 718 1,500 80 BDL 80 SDL SDL SOL 1.660 2 378 01114/92 3,11100 110 BDL 200 ROL ROL 56 SOL 80 4.246 1,800 260 ROL 340 BOL 130L BDL 2.400 6646 05115/92 1,400 25 SDL 49 8DL ROL ROL ROL SOL 1.4W 1,800 150 ROL 801- BDL SOL BDL 1.980 3.410 09/09192 2,700 ROL SOL SOL SOL SOL ROL SOL 100 2.800 2,500 150 ROL 15D BDL SOL BDL 2800 SAW 03/11196 1,230 ROL SOL SOL ROL ROL SOL SOL ROL 1.230 1,920 8DL SOL SOL ROL SOL RDL 1.920 3.150 05125199 637 ROL SDL BDL SDL BDL ROL ROL BDL 637 1,610 SOL ROL SOL SOL SOL BDL 1.510 2.147 1oil W02 2,000 66 BDL 31 SOL 11 2.9 SOL 4.9 2.117 1,700 16 14 27 180 530 BDL 2.454 4.572 04122103 640 24 SOL 17 SOL 64 8DL ROL 7 8 689 No 64 ROL 63 81 18O SOL 774 1.463 0613" 870 SOL 370 SOL ROL ROL ROL SOL SOL 1.240 280 ROL ROL SOL 74 200 SOL $54 1794 D8116ro5 1,300 62 570 ROL ROL SDL ROL BDL SOL 1.932 420 ROL BDL SOL 69 170 SOL 059 2,591 OEr24106 2,200 94 770 15 SOL 64 1.2 1 2 6.5 3.083 660 4.8 ROL 104 78 t60 5.6 919 4 002 06105/08 1,840 ROL 545 SOL ROL SOL BDL BDL SOL 2.385 210 ROL ROL ROL 551 140 SOL 405 2,790 09/04/08 1,430 51.7 349 BDL ROL SOL ROL SOL ROL 1.831 253 ROL BDL BOL BDL 603 RDL 313 2.144 01105109 1,610 78.4 517 SOL SOL SOL BDL SOL SOL 2.205 28O ROL BDL ROL 70.9 716 SOL 467 2,672 03/65/09 1,260 SDL 466 ROL BDL ROL SOL SOL SOL 1.716 117 SDL BDL SOL ROL SOL SQL 117 1.633 MW-25 03111/98 8,9 3,5 BDL ROL ROL ROL SOL SOL ROL 12 8DL ROL SDL ROL SOL SOL RDL 0 12 0s26199 10 3.8 SDL ROL RDL ROL SDL SDL ROL 14 ROL BDL RDL SOL BDL SOL BDL 0 14 06/30104 6.1 3.5 99 ROL BDL ROL SOL BDL ROL 22 ROL SOL BDL ROL SOL 4.4 8DL 4 26 08116/05 17 3.9 31 ROL ROL ROL ROL BDL SDL 52 HDL BDL SOL ROL 36 SOL BDL 4 56 013l25106 20 4.9 51 SOL BDL ROL 8DL SOL BDL 76 8DL SOL SOL SDL 1 a 4.3 SOL 6 82 06105M 11.7 3,2 23.5 SOL SOL ROL SOL SOL BDL 38 SOL ROL 1.3 SOL 22 4.2 SOL a 46 M04M 18.7 5.2 332 SRL SOL ROL SDL SOL ROL 57 SOL ROL BOL SOL 3 48 BDL 8 65 D1ros109 22 9 6.5 46.6 1 1 BDL 1 1 ROL BOL BDL 78 BDL RDL ROL ROL 4 8 6.2 BRL 11 89 03rO5ro9 249 6.3 51 11 BDL RQL SDL BDL BDL 85 BDL 8GL ROL ROL 4.8 6OL BDL 5 90 MW-26 {abandoned 01103106) 27121104 SOL SOL ROL SOL SDL SOL ROL SOL SOL 0 SOL SOL SOL BDL RDL SOL ROL 0 0 0&15105 SOL BDL 8DL SDL SOL SOL SOL ROL ROL 0 SOL SOL 81)1- SOL RDL ROL SOL 0 0 MW-27 10110102 SOL SOL SOL BDL ROL SOL ROL ROL SDL 0 2,3 2 47 78 2.3 SOL ROL 72 72 071011D4 SOL ROL BOL BDL BDL SOL BDL RDL SOl- 0 5,4 2 7 34 7 9 11 8OL 77 TB 7a 08/16105 RDL SAL RDL BDL BDL BDL ROL BDL SOL 0 12 4.1 18D 34 3.5 Bill 30 264 264 11101105 SOL SOL 6DL SOL BDL SOL ROL ROL BDL 0 6,2 2 4 38 3 1 BDL 80L 16 fib 66 Notes: All units measured in NgIL BDL - Below Detection Limits NCGS 2L Std. - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater 0uably Standard MTBE - Malhyl-lerl butyl ether 97746 1 GS009R022 Copyright 2DD9!Slain}elder Page 3 of 4 April 17, 2009 TABLE 4-, HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS Sample ID Chlorinated arbO H drocns Tonal Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petrotsum Hydrocarbons Total VOCs Dale Teiractrloroelherte Trichloroerhene CM-1 1,1-Drchlaroethene Dichlaroet hene Vinyl Chloride 1 1-Drchloraethane 1.2-DIdllnroatkiane trans-1.2• Drchl oetnane 1 1 1-Trichlwoelhan Benzene Toluene E0lylbenxane Total Xylenes MTBE Dnsopropyl ether Naphthalene NCGSron CGS 2L Std 0.7 2.8 70 7 0015 70 038 t00 200 1 ],000 55Q 530 200 70 2t MM1.28 10110/02 SOL SOL SOL SOL SOL BDL BDL BDL BDL 0 11 10 1 22 1 45 225 BDL 23 BRL 82 62 07101/04 BDL SOL SOL SOL BOL SOL BDL BDL BDL 0 95 51 1,50D 1,066 BDL BDL 480 3.191 3.191 08/15/05 RL BDL[ BOL SDL BDL DL O 0 210 8 , 750 4.078 4.078 DL 8DL BD L SOL SOL DL 85 SOL Q 170 6 200 BDL BL 8005/2 4.726 4 725 12/14106 BDL BDL BDL SOL SOL SOL BDL BOL BOL 0 400 BOL 1 2,500 530 SOL BDL 940 4.070 4.070 MVV-29 0710110-0 23 SOL 250 BDL 8DL SOL SOL BDL SOL 303 BDL SOL 21 BDL BDL BDL SOL 21 324 08/15/05 39 4,2 29 BOL BDL SOL SOL BDL BDL 72 BDL BOL SOL BDL BDL BDL BOL 0 11 72 08125M6 5 22 38 BDL BDL SOL BDL BDL BDL 45 BDL I SOL I BDL I SOL BDL BDL I SOL 11 0 H 45 MW-30 07/01104 SOL SOL BDL BDL BDL BOL BDL BDL BDL 0 BDL BDL SOL BDL 2,200 SOL SOL 2.200 2,200 0&16105 SOL SOL 200 43 77 BDL BDL BDL BOL 320 74 BDL 56 BDL 510 SOL BDL 642 962 08/25/06 BDL SOL 23 1 25 16 BDL SOL BDL SOL 42 23 SOL 26 2 1,500 13 BDL 1541 1,5B2 MW-31 10110102 BDL SOL SOL SOL SOL SOL SOL 8DL BDL ❑ BOL 320 2,600 7,900 SOL BDL SOL 10.820 10,820 04122103 BDL SOL BDL SOL SOL SOL SOL SOL BDL 0 BDL 310 1,800 4,600 SQL SOL SOL 6 710 6.710 07/01104 BDL BDL 53 SOL SOL SOL BDL SOL SOL 53 18 64 590 1,360 SOL BRL 400 2452 2.505 W15105 BDL SOL 46 SOL BDL SOL BDL BDL SOL 48 SOL 67 1,100 1,490 BDL SOL 750 3407 3,455 11101/06 BDL BDL SOL SOL SOL SOL BDL BDL 9DL 0 SOL BDL 1,700 390 BRL SOL 720 2.510 2.810 MW-32 07101104 SOL BDL SOL BDL BDL SOL BOL BOL BDL ❑ BDL BOL BDL SOL 290 SOL ROL 29D 290 08115M5 BOL BDL BDL SOL SOL SOL SOL BDL BDL ❑ BDL BOL SOL SOL 180 SOL BDL 180 180 00/25/06 BDL 6OL BDL SDL BDL BDL SOL SOL SOL 0 1,400 280 190 900 16,000 32 180 17.662 17662 11101/06 SDL BDL SOL BDL BDL BOL ROL SOL SOL 0 1,400 320 340 9DD 20,000 SOL SOL 22.950 229W 121141❑6 BDL SOL BDL SOL BDL SOL BDL SOL SOL 0 1,50D 3.700 1,700 8,000 16,000 SDL 1,100 32.000 32OW VW-23 10/10/02 SOL BDL I BDL I SOL I 9DL T SOL I BDL I SOL BOt 0 8DL BDL BDL 8p4 8QL BOL BDL 0 0 06/30/04 BDL BDL 7.6 SDL 8DL BDL BDL SOL BDL 2 BDL BDL BDL 8DL BDL SOL SOL 0 2 08115/05 SOL SOL 5.6 BDL 8DL SOL SOLSOL SOL 6 BDL BDL BDL SOL SOL 81311. BDL 0 6 08/25106 SOL BDL 5.7 SOL BDL SOL SOL SDL SOL 6 BOL BDL BDL I 9DL I SOL I SOL I BDL 110 6 MW-34 D4122103 BDL 100 BDL 15 BDL 72 BDL SOL SOL 122 BDL SOL BDL SOL BDL SOL SOL 0 122 07/01104130 63 6.3 BDL7.4 SDL BDLL 207 5 BDL 9 37 SOL BDL BDL BDL BDL BDL 127 BDL [—BDL L D08/16 BDL BD BDL BDL 0 127 06/25106 8DL 59 24 4.8 SOL 23 SOL SDL BDL 90 SOL SOL 8DL SOL BDL BOL 0 90 MW-40 11/01106 BDL BDL BDL BDL BDL BDL BOL SOL SOL 0 250 230 280 552 ROL BDL 134 11 1.442 1.442 MLV-01 04f22103 SAL SOL BDL BDL SOL SOL SOL BDL BDL 0 7,200 1 5,600 1 2,400 1 t0,8D0 SOL SOL SOL 27,000 27,000 07/08/44 SOL SOL SOL SOL SOL SOL SOL ROL BDL 0 7,DDD 6,600 2,600 1.3,309 1 SOL 520 770 30.790 30.790 08116/05 BDL SOL SOL BDL SOL SOL SOL SOL BDL 0 5,400 4,900 2,500 9,700 SOL 230 780 23.510 23,510 08124M BDL SOL BOL SOL SOL SOL BDL SOL SOL 0 3,100 3,000 1,000 2,900 ROL 64 16 10.022 10.022 MW-42 01/10/06 36.0 BDL 7 5 61 BOL 16 BDL BDL BDL 51 BDL SOL BDL 8DL SQL SOL 32 3 54 08125106 27A BDL 47 35 SOL 15 BDL ROL BDL 37 SOL BDL SOL 8DL BDL SOL SOL 0 37 061051Q8 6.3 BDL BDL SOL SOL BOL SOL BDL SOL 5 SOL SOL SOL BDL BDL SOL BDL 0 5 091D4108 5,7 SOL SOL BDL SOL SOL BDL BDL BDL 6 SOL SOL BDL BDL SOL BOL BDL 0 6 011051D9 5.3 BDL SOL SOL SOL SOL SOL BDL SOL 5 SOL SOL BDL SOL SOL SOL BDL 0 5 03IM09 2.7 SOL SOL BDL SOL SOL BDL BDL SOL 3 SOL SOL SOL SOL BDL SOL SOL 0 3 N1W-43❑ 01/10106 1 390 12.0 110 42.0 SOL 6.8 SOL BDL BDL 561 4A BDL SOL SOL 36.0 6B.0 SOL 109 670 03/27109 SOL SOL SOL 9.3 SOL SOL 1.6 BDL 1 12 JL 12 H 9.0 1 SOL 1 75 1 SDL 1 36 SOL 1 4.4 H25 37 MW-44 04/11/07 ROL 21 BDL SOL SOL SOL BDL BDL BOL 2 SOL SOL SOL BDL SOL BDL SOL 0 2 MW-46 09113/07 BDL BDL BDL SOL SOL BOL BDL SOL BDL 0 BDL BDL SOL BDL SOL SOL BDL 0 0 06105108 1,2 SOL SOL BDL SOL SOL SOL SOL SOL 1 BDL SOL ROL BDL SOL SOL SOL 0 1 W05108 1.2 BDL BDL SOL ROL BDL SOL SOL SOL 1 601- BDL BDL SOL SOL BDL SOL 0 1 091041o' BDL BDL BDL BDL BDL BDL SOL BOL SOL 0 SOL BDL SOL SOL SOL SOL RUL 0 0 01,05*9 1,4 12 BDL BOL BDL BDL SOL SOL BOL 3 SOL SOL BOL SOL SOL SOL BDL ❑ 3 03/05/09 1.3 SOL BDL BOL BDL BDL SOL BDL SOL 1 SOL SOL SOL BOL SOL BOL BDL 0 1 Notaa: All unis measured to NgIL SOL - Below Detection Limns NCGS 2L Sid - North Carolina Groundwater Standard BOLO - Concentration axooeds the 2L Groundwater Quality Standard MTBE - Methyl-1eS butyl ether 97746 [ GS009RO22 Copyright 2009 Klarntelder Page 4 of 4 April 17, 2009 TABLE 5: ESTIMATED DISSOLVED HYDROGEN CONCENTRATIONS AT INJECTION WELLS Well ID Total Depth (feet TOC) TOC Elevation (feet) Bottom Elevation (feet) Date Water Level Checked Static Water Level (feet TOC) Groundwater Elevation (feet) Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (ppm) MW-7 29.9 861.19 831.29 03/05/09 5.82 855.37 24.08 2.7 MW-10 33.6 860.36 826.76 03/05/09 7.16 853.20 26.44 2.8 MW-14❑ 41.0 859.26 818.26 03/05/09 18.80 840.46 22.20 2.6 MW-15 25.2 857.71 832.51 03/05/09 12.08 845.63 13.12 2.2 MW-16 35.2 863.60 828.40 03/05/09 27.95 835.65 7.25 1.9 MW-23D 571 860.90 803.80 03/05/09 15.26 845.64 41.84 3.6 MW-24 58.8 858.81 800.01 03/05/09 20.40 838.41 38.40 3.4 MW-29 18.8 861.13 842.33 03/05/09 4.28 856.85 14.52 2.3 MW-34 21.0 860.45 839.45 03/05/09 well flooded --- --- --- MW-43D 53.0 865.47 812.47 03/05/09 29.62 835.85 23.38 2.7 Notes: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of 1.6 ppm per atmosphere. 97746 1 GS009R022 Copyright 2009 Kleinfelder Page 1 of 1 April 17, 2009 TABLE 6: ESTIMATED HYDROGEN CONSUMPTION Date Water Original Cylinder Estimated Volume Estimated Date Date Hydrogen Level and Days Elapsed Average Hydrogen Injection Cylinder Pressure on of Hydrogen Cylinder Must be Cylinder Cylinder Since Cylinder Use per Day Well ID Pressure 3127109 Remaining (cubic Changed Based on Installed Pressure Installation (psi/day) �pstf (psi) feet] Pressure Recorded MW-7 03/27/09 2,000 03/27/09 2,000 191 0 27.3 06/04/09 MW-10 02/11/09 1,500 03/27/09 900 115 44 13.6 05/24/09 MW-14❑ 03/27/09 1.700 03/27/09 1,700 191 0 19.1 06/18/09 MW-15 01/30/09 1.900 03/27/09 1,300 131 56 10.7 07/17/09 MW-16 03/27/09 1.900 03/27/09 1,900 191 0 15.0 07/25/09 MW-23D 03/27/09 1.900 03/27/09 1.900 191 0 36.8 05/14/09 MW-24 03/27/09 2,000 03/27/09 2.000 191 0 17.1 07/16/09 MW-29 01 /30/09 1.900 03/27/09 1.000 101 56 16.1 05/22/09 MW-34 03/27/09 2.000 03/27/09 2,000 191 0 22.1 06/20/09 MW-43D 02/11/09 1.900 03/27/09 1.000 101 44 20.5 05/10/09 Notes: psi = pounds per square inch All hydrogen cylinders must be replaced prior to the cylinder pressure tailing below 50 psi. 97746 1 GS009RO22 Copyright 2009 Kleinfelder Page 1 of 1 April 17, 2009 FIGURES a .�7i wl V �+II T P • i dsh' ip.Ch : A. sss aae qw goo • • � -- — I' �Gas'Eline�• 4 r '� V II ■ `.. �. Ga8ornes � .. aso ,'� � _ • � sa Ch J MIA f , `*� •if_. • liSJ y'� ! 4 -� ■ + 5 FIGURE 1 SITE LOCATION MAP KL EINFEL DER GFdena 730Q West Friendly Avenue Bright People. Right Solutions. Greensboro, North Carolina APPRCVEDBY 313 GALLIMORE DAIRY ROAD DATE 4-14-2009 SCALE. 1" = 2.000 GREENSBORO, NORTH CAR OLINA PHONE: 336.668.0093 SOURCE VSGS 7.5 TOPOGRAPHIC MAP. GUILFORD QUADRANGLE C44, PROJECT NO: 97746 M W-45 4 r MW-42 MW-12D MW-12 MW-14 SUf3 MW-25 TATIQ R _ ATER TANK 4�MW-41 N 1 MW-130 MW-40 ❑ MW-ii MW-13 LL RVV-3 RW-2 AV a� MW-28 RW-4 MW-32 MW-31 L W-33 MW-2 MW-30 M W-44 EXISTING PARKING EXISTING PARKING EXISTING BUILDING LEGEND INJECTION WELL LOCATION MW-94 MONITORING WELL LOCATION � FIGURE 2 SITE PLAN ❑ RW-3 RECOVERY WELL LOCATION � rL EINFEL E►4 Friendly 7300 West Friendly Avenue Bright People. Right Solutions. Greensboro, North Carolina APPROVED BY 313 GALLIMORE DAIRY ROAD WE 4-54-2009 SCALE I" = IN' GREENSOOR0. NORTH CAROLINA PHONE. 336 668.0093 DRAWN 8Y CWk PROJECT NO 97746 835 4MW-45 834.50 835 840 rv, �ti 836.65 v, �ti• :: ; 835.86 845 MW-42 :.� V..Vv Mw-1xD 835.95 838.41 845.63 845.21 MW-12 MW44 MW-25 >� 847.33 840 84167 838.64 sue TATIO 840 - ATER 8 T MW-41 Mrir +u 1 Mw-13D 853.62 Q 853.20 847.47 845 MIN-40 W-3 MW-11 MW-13 851.09 W-2 MVv � ❑ 855.37 4 846.45 f 847.19 85or") 845 845.64 MW-34 1,61 MW 2- 7 856.88 mr MW-28 853.50 RW-4 850 MW-32 845 852,49 MW-31—/ 850 Mw-33* 846.94 850.99 M W -30 855 855 849.45 MW-27 _ 849,61 r lit W -44 EXISTING PARKING LEGEND EXISTING i INJECTION WELL LOCATION AND EXISTING PARKING 855.37 GROUNDWATER ELEVATION BUILDING MW-14 MONITORING WELL LOCATION AND 841.67 GROUNDWATER ELEVATION ❑ RW-7 RECOVERY WELL LOCATION 842_,,, GROUNDWATER CONTOUR LINE NOTES - GROUNDWATER ELEVATIONS WERE RECORDED MARCH 5, 2009 MONITORING WELLS MW-13D, MW-23D. AND MW-25 ARE SCREENED BELOW THE WATER TABLE AND WERE NOT USED TO GENERATE THE GROUNDWATER CONTOURS. EXISTING PARKING LEGEND i MW-7 INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION WITH 30 TOTAL VOCs CONCENTRATION (ug/L) ❑ RW-3 RECOVERY WELL LOCATION 1.000_^ TOTAL VOCs ISOCONCENTRATION LINE NOTE SAMPLES COLLECTED ON MARCH 5 AND 27. 2009 A MW-42 3 37 M W-12 MW-12D M W-1 'ti 32 MW-25 90 TATI 1 ATER TANK BUL MW-41 F i 12 U7 1 MW-13D 1 10,000 RW-3 � 31 MW-13 122 M W-i 1 � MW-40 3A, R W-2 2,791 1,00 369 100 OL MW-31 -MW^28 I EXISTING BUILDING MW-30 MW-44 EXISTING PARKING EXISTING PARKING 1 8DL ti 12 M 3 -42 1 . Q00 M W-12D Af r,t : MW-1 1.71fi4 Mw-12 32 MW-25 sus BS ATE❑ .12 ATE TANK mFl BDL ' MW-13d MW-41 AIF 19 ,&RW-3 mw-13 MW�O MW-T 1 119 DL 3 RW-2 935 } 194 MW-34 r. M W-28 RW-4 M W-31 -33 W-32 MW Mw-2 �► LEGEND 'S MW-7 INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION WITH 30 TOTAL CHLORINATED HYDROCARBONS CONCENTRATION (ug/L) ❑ RW-3 RECOVERY WELL LOCATION r, r, TOTAL CHLORINATED HYDROCARBONS ISOCONCENTRATION LINE NOTE: SAMPLES COLLECTED ON MARCH 5 AND 27, 2009 EXISTING BUILDING MW-30 M W-44 EXISTING PARKING x Pace Analytical Services, Inc. Pace Analytical Services, Inc. zfflaeeAnalytical 2225 Riverside Or 9800 KinCey Ave. Suite 100 www.pace;abs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254.7178 March 20, 2009 Ms. Gail Licayan Trigon/Kleinfelder, Inc. 313 Gallimore Dairy Rd Greensboro, NC 27409 RE: Project: Gilbarcc 042-08-018 Pace Project No. 9239387 Dear Ms. Licayan: Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable. unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Bonnie McKee bonnie. m ckee@paceia bs. corn Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent or Pace Analytical services, irnc.. (704)875-9092 Page 1 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. - la eAnal �[ral 2225 Riverside [)r 9600 KinceyAve. Suite 100 www-pacelabs.com Asheville, NC 28804 Huntersvifle, NC 28078 (828)254-7176 (704)875-9092 Projecl: Gilbarco 042-08-018 Pace Project No.: 9239387 Charlotte Certification IDS West Virginia Certification #: 357 Virginia Certfication #: 00213 Tennessee Certification #: 04010 South Carolina prinking Water Cart. #: 990060003 South Carolina Certification #- 99DO60001 Pennsylvania Certification #: 68-00784 Connecticut Certification # PH-0104 Asheville Certification IDs West Virginia Certification #: 356 Virginia Certification #: 00072 Connecticut Certification #: PH-0106 Florida/NELAP Certification #: E87548 Tennessee Certification #: 2980 South Carolina Certification #: 99030001 South Carolina Bioassay Certification #: 99030002 Eden Certification IDS North Carolina Wastewater Certification #- 633 Virginia Drinking Water Certification #- 00424 CERTIFICATIONS North Carolina Field Services Certification # 5342 North Carolina Drinking Water Certification #: 37706 New Jersey Certification #- NC012 Louisiana/LEtAP Certification #: 04034 Kentucky UST Certification #. 84 Florida/NELAP Certification # E87627 North Carolina Wastewater Certification # 12 Pennsylvania Certification #: 68-03578 North Carolina Wastewater Certification # 40 North Carolina Drinking Water Certification #: 37712 North Carolina Bioassay Certification #: 9 New Jersey Certification # NCO11 Massachusetts Certification # M-NC030 LouisianalLELAP Certification #: 03096 North Carolina Drinking Water Certification #: 37738 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of PaCe Analytical Services, Inc. ir Page 2 of 18 q. aceAnalytrcal wrrw.pacelabs.c= Pace Analytical Services, Inc. 2225 Riverside ❑r Asheville, INC 28804 t828y254-7176 Pace Analytical Services, Inc. 9800 Kmcey Ave. Suite 100 Huntersvifle, NC 28078 (704)875.9092 Project: Gilbarco 042-08-018 Pace Project Na 9239387 SAMPLE SUMMARY Lab ID Sample ID Matrix date Collected Date Received 9239387001 MW-7 Water 03105r0915-10 03105/0915.00 9239387002 MW-11 Water 03/05/09 09:43 03/06/09 15.00 9239387003 MW-13 Water 03/05/09 09:45 03/06/09 15:00 9239387004 MW-13D Water 03/05/09 09:08 03/06/09 15:00 9239387005 MW-14 Water 0310510914-50 03106/0915-00 9239387006 MW-23D Water 03/05/09 09:32 03/06/09 15:00 9239387007 MW-24 Water 03/05/09 15:03 03/06/09 15 00 9239387008 MW-25 Water 03/05/09 14:46 03/06/09 15 00 9239387009 MW-42 Water 03/0510911:04 03/0610915:00 9239387010 MW-45 Water 03105/0911:11 03/0610915.00 REPORT OF LABORATORY ANALYSJS This report shall not be reproduced, except in full. without the written consent of�Pace ,Analytical Services. inc Page 3 of 18 e. Pace Analytical Services, Inc. Pace Analytical Services, Inc, aeeAnalytieal 2225 Riverside dr. 9800 Kincey Ave. Suite 100 wwwpacePabs.mm Asheville, NC 28804 Huntersville, NC 2HO75 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT Project: Gilbarco 042-08-018 Pace Project No.. 9239387 Analytes Lab ID Sample I❑ Method Analysts Reported 9239387001 MW-7 EPA 6 01160 2 DHW 40 9239387002 MW-11 EPA 6011602 DHW 40 9239387003 MW-13 EPA 601 /602 DHW 40 9239387004 MW13D EPA 6011602 DHW 40 9239387005 MW-14 EPA601/602 DHW 40 9239387006 MW-23D EPA601/602 ❑HW 40 9239387007 MW-24 EPA601/602 DHW 40 9239387008 MW-25 EPA601/602 DHW 40 9239387009 MW-42 EPA 6011602 DHW 40 9239387010 MW-45 EPA 6011602 DHW 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc Page 4 of 18 www.pacela6tmm Project: Gllbarco 042-08-018 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 29804 (828)254-7176 ANALYTICAL RESULTS Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersviile, NC 28078 (704)875-9092 Pace Protect No.: 9239387 Sample: MW-7 Lab ID:/3239387001 Collected: 03/05/09 15:10 Received: 03/06/09 15:00 Matrix. Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. Dual 6011602 Volatiles Analytical Method: EPA 601/602 Benzene NO ug/L 50.0 50.0 50 03/19/09 11:42 71-43-2 Bromodichloromethene ND ug/L 50.0 50.0 50 03119/09 11:41 75-27-4 Bromoform ND ug/L 50.0 50.0 50 03119/0911,41 75-25-2 Bromomethane NO ug/L 50.0 50.0 50 03/19/09 11 Al 74-83-9 Carbon tetrachloride NO ug/L 50.0 50.0 50 03/19/09 11:41 56-23-5 Chlorobenzene NO ug/L 50,0 50.0 50 0311 9/09 11:41 108-90-7 Chloroethane NO uglL 50.0 50.0 50 03/19/09 11:41 75-00-3 Chloroform NO ug1L 50.0 50.0 50 03/19/09 11:41 67-66-3 Chloromethane NO ug/L 100 100 50 03/19/09 11:41 74-87-3 Dibromochlaromethane ND ug/L 50.0 50.0 50 0311910911,41 124-48-1 1,2-Dibromoethane (EDB) ND ug1L 50.0 50.0 50 03/19/09 11 Al 106-93-4 1,2-Dichlorobenzene NO ug/L 50.0 50.0 50 03/19/09 11:41 95-50-1 1,3-Dichlorobenzene NO ug/L 50.0 50.0 50 03119/0911.41 541-73-1 1.4-Dichlorobenzene NO ug/L 50.0 50.0 50 03/19/09 11 Al 106-46-7 ❑ichlorodifluoromethane NO ug/L 50.0 50.0 50 03/19/09 11:41 75-71-8 1,1-Dichloroethane NO ug/L 50-0 50A 50 03/19/09 111-41 75-34-3 1,2-Dichlorcethane NO ug/L 50.0 50.0 50 03/19/09 11:41 107-06-2 1,1-Dichloroethene NO ug/L 50.0 50.0 50 03/1910911:41 75-35-4 cis- 1,2-DthIoroethene 935 ug/L 50.0 50.0 50 03/19/09 1141 156-59-2 trans-1,2-Dichloroethene ND ug/L 50.0 50.0 50 0311910911-41 156-60-5 1,2-Dichloropropane N❑ uglL 50.0 50.0 50 0311910911:41 78-87-5 cis- 1,3-DichIoropropene ND uglL 50.0 50.0 50 0311910911Al 10061-01-5 trans-1,3-Dichtoropropene NO ug/L 50.0 50.0 50 03/79/0911,41 10061-02-6 Diisopropyl ether NO ug/L 50.D 50.0 50 03119/0911,42 108-20-3 Ethylbenzene 749 ug/L 50.0 50.0 50 03/19/09 11:42 100-41-4 Methylene Chloride NO ug/L 100 100 50 03/19/09 11:41 75-09-2 Methyl-tert-butyl ether NO ug/L 50.0 50.0 50 03/19/09 11:42 1634-04-4 Naphthalene 384 ug/L 100 100 50 03119109 11:42 91-20-3 1.1.2,2-Tetrachloroethane N❑ uglL 50.0 %0 50 03/19/09 11:41 79-34-5 Tetrachloroethene NO uglL 50.0 50.0 50 03/19/09 11:41 127-18-4 Toluene NO ug/L 50.0 50.0 50 03119/09 11:42 108-88-3 1,1,1-Trichloroethane ND ug/L 50.0 50.0 50 0311910911:41 71-55-6 1,1,2-Trichloroethane NO ug/L 50.0 50.0 5D 03/19/09 11:41 79-00-5 Trichloroethene NO ug/L 50.0 50.1) 50 0311910911:41 79-01-6 Tdchlo►ofluaromethane NO ug/L 50.0 50.0 50 03/19/09 11:41 75-69-4 Vinyl chloride ND ug/L 50.0 50.0 50 03/19/09 11:41 75-01-4 Xylene (Total) 723 ugIL 100 100 50 03/19/09 11 A2 f 330-20-7 m&p-Xylene 723 ug/L 100 100 50 03/19/09 11:42 1330-20-7 o-Xyiene NO ug/L 50.0 50.0 50 03/19/09 11:42 95-47-6 1-Chioro-3-fluorobenzene (S) 125 % 65-137 50 03/19/09 11:41 625-98-9 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS Page 5 of 18 This report shall not be reproduced, except in Tull, without the written consent of Pace Analytical Services, Inc.. s Pace Analytical Services, Inc. Pace Analytical Services, Inc. lace Analytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wwwpaa43b,s.wm Asheville. NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Gil barco 042-0M18 Pace Project No,: 9239387 Sample: MW 11 Lab Id: 9239387002 Collected: 03105/09 09:43 Received: 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 6011602 Volatiles Analytical Method: EPA 6011602 Benzene ND uglL 1.D 1.0 1 03/19/09 13:05 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 03/19/09 13:04 75-27.4 Bromoform NO uglL 1.0 1 A 1 03/19/09 13:04 75-25-2 Bromomethane NO uglL 1.0 1.0 1 03/19/09 13:04 74-83-9 Carbon tetrachloride NO ug1L 1.0 1 A 1 03/19/09 13:04 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 03119/0913:04 108-90-7 Chloroethane NO ug1L 1.0 1.0 1 03/19/0913:04 75-00-3 Chloroform NO uglL 1.0 1.0 1 03/1910913:D4 67.-66-3 Chloromethane ND uglL 2.0 2.0 1 D311910913:04 74-87-3 Dibromochloromethane NO uglL 1.0 1.0 1 03/19/09 13:04 124-48.1 1,2-Dibromoethane (EDB) NO uglL 1.0 1.0 1 03/19/09 13:04 106-93-4 1,2-Dichlorobenzene NO uglL 1.0 1.0 1 03/1910913:04 95-50-1 1,3-Dichlorobenzene NO uglL 1.0 1.0 1 03119/0913:04 541-73-1 1 A-Dichlorobenzene NO ug1L 1.0 1 A 1 03119/09 13:04 1 D646-7 ❑ichlorodifiuoromethane NO uglL 1.0 1.0 1 03119/0913:04 75-71-8 1,1-Dichloroethane NO uglL 1.0 1.0 1 03/1910913:04 75-34-3 1,2-Dichloroethane NO uglL 1.0 1.0 1 03/1910913:04 107.06-2 1,1-Dichloroethene NO uglL 1.0 1.0 1 03119/0913:D4 75-35-4 cis-1,2-Dichloroethene 1.5 uglL 1.0 1.0 1 03/1910913-D4 156-59-2 trans-f ,2-Dichloroethene NO ug/L 1 A 1-0 1 03/19/09 13:04 156-60-5 1,2-Dichloropropane NO uglL 1.0 1.0 1 03/19/09 13:04 78-87-5 cis- 1,3-Dichloropropene ND uglL 1.0 1.0 1 03/1910913:04 10061-01-5 trans-1,3-Dichloropropene NO uglL 1.0 1.0 1 03/1910913:04 10061-02-6 Diisopropyl ether NO uglL 1.0 1.0 1 03/19/09 13:05 1 o8-20-3 Ethyibenzene NO uglL 1.D 1.0 1 03119/0913:05 1OD-41-4 Methylene Chloride ND uglL 2.0 2.0 1 03/19/09 13:04 75-09-2 Methyl-tert-butyl ether NO uglL 1.0 1.0 1 03/19109 13:05 1634-04-4 Naphthalene ND uglL 2.0 2.0 1 03/1910913:05 91-20-3 1,1,2,2-Tetrachloroethane ND uglL 1.0 1.0 1 0311910913:D4 79-34-5 Tetrachloroethene 1.3 uglL 1.0 1.0 1 03/19/09 13:04 127-18-4 Toluene NO uglL 1.0 1.0 1 03/19/09 13:05 108-88-3 1,1,1-Trichloroethane NO uglL 1.0 1.0 1 03/1910913:04 71-55-6 1.1,2-Trichloroethane ND uglL 1.0 1.0 1 0311910913:04 79-00-5 Trichloroethene NO ug1L 1.0 1.D 1 03/1910913:04 79-01-6 Trichlorofluoromethane ND uglL 1.0 1.0 1 03/19/09 13:04 75-69-4 Vinyl chloride NO ug1L 1.0 1.0 1 03/19/09 13:04 75-01-4 Xylene (Total) NO uglL 2.0 2.0 1 03/19/09 13:05 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 03/19/09 13:05 1330-20-7 o-Xylene NO uglL 1.0 1.0 1 03/19/09 13:05 95-47-6 1 -C h lo ro- 3-ftu o ro benze n e (S) 126 % 65-137 1 03/19/09 13:04 625-98-9 Date. 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace AnalyhcaI Services, Inc.. Page 6 of 18 N Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical 2225 Riverside Dr. H00 Kincey Ave. Suite 100 w wparwaosclom Asheville, NC 28804 Huntersviile. NC 28078 (828)254-7176 (704)875-9082 ANALYTICAL RESULTS Project Gilbarco 042-08-018 Pace Project No.: 9239387 Sample: NW-13 Lab ID: 9239387003 Collected: 03/05/09 09745 Received: 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL OF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 6011602 Benzene ND ug)L 2.5 2.5 2.5 03/19109 14:27 7143-2 Bromodichloromethane ND uglL 2.5 2.5 2.5 03/19/09 14:26 75-27-4 Bromoform NO uglL 2.5 2.5 2.5 0311910914:26 75-25-2 Bromornethane ND uglL 2.5 2.5 2.5 D311910914:26 74-83-9 Carbon tetrachloride NO uglL 2.5 2.5 2.5 03/19/09 14:26 56-23-5 Chlorobenzene ND uglL 2.5 2.5 2.5 03/19/09 14:26 108-90-7 Chloroethane N❑ uglL 2.5 2.5 2.5 03/1910914:26 75-00-3 Chloroform NO ug1L 2.5 2.5 2.5 03/19/09 14:26 67-66-3 Chloramethane NO uglL 5.0 5.0 2.5 03/19/09 14:26 74-87-3 ❑ibromochloromethane NO uglL 2.5 2.5 2.5 03/19/09 14:26 124-48-1 1,2-Dibromoethane (EDB) NO uglL 2.5 2.5 2.5 03/19/09 14:26 106-93-4 1,2-Dichlorobenzene NO uglL 2.5 2.5 2.5 03/19/09 1416 95-50-1 1,3-Dichlorobenzene ND uglL 2.5 2.5 2.5 03/1910914:26 541-73-1 1,4-Dichlorobenzene ND uglL 2.5 2.5 2.5 03/19/09 14:26 106-46-7 Dichlorod i8uoromethane NO uglL 2.5 2.5 2.5 03/1910914:26 75-71-8 1,1-Dichloroethane NO uglL 2.5 2.5 2.5 03/19/09 14:26 75-34-3 1,2-❑ichloraethane NO uglL 2.5 2.5 2.5 0311910914:26 107-06-2 1,1-Dichloroethene ND uglL 2.5 2.5 2.5 03/19/09 14:26 75-35.4 cis-1,2-Dichloroethene 119 uglL 2.5 2.5 2.5 03/19/09 14:26 156-59-2 trans-1,2-Dichloroethene ND uglL 2.5 2.5 2.5 0311910914:26 156-60-5 1,2-Dichloropropane ND uglL 2.5 2.5 2.5 03119/09 14:26 78-87-5 cis- 1,3-DichIoreprope ne ND ug1L 2.5 2.5 2.5 03/19/09 14:26 10061-01-5 trans-1,3-❑ichloropropene ND uglL 2.5 2.5 2.5 03/19/09 14.26 10061-02-6 Diisopropyl ether ND uglL 2.5 2.5 2.5 03/19/09 14:27 108-20-3 Ethylbenzene NO uglL 2.5 2.5 2.5 03/1910914:27 100-41-4 Methylene Chloride NO ug1L 5.0 5.0 2.5 03/19/09 14.26 75-D9.2 Methyl-tert-butyl ether 3.1 uglL 2.5 2.5 2.5 03/19/09 14:27 1634-04-4 Naphthalene ND uglL 5.0 5.0 2.5 0311910914:27 91-2D-3 1.1,2,2-Tetrachloroethane ND uglL 2.5 2.5 2.5 03/1910914,26 79-34-5 Tetrachloroethene ND uglL 2.5 2.5 2.5 031191D914.26 127-18.4 Toluene NO uglL 2.5 2.5 2.5 03/19/09 14:27 108-88-3 1,1,1-Tdchloroethane NO uglL 2.5 2.5 2.5 0311910914:26 71-55-6 1,1,2-Trichloroethane NO uglL 2.5 2.5 25 03/19/09 14:26 79-00-5 Tdchloroethene ND uglL 2.5 2.5 2.5 03/19/09 14:26 79.01-6 Trichlorofluoromethane NO ug1L 2.5 2.5 2.5 03/19/09 1426 75-69-4 Vinyl chloride NO uglL 2.5 2.5 2.5 03119J09 14,26 75-01-4 Xylene (Total) NO uglL 5.0 5.0 2.5 03/19/09 14,27 133D-20-7 m&p-Xylene NO ug& 5.0 5.0 2.5 03/19/0914-27 1330-20-7 o-Xylene NO uglL 2.5 2.5 2.5 03/19/0914:27 95-47-6 1-Chloro-3-fluorobenzene (S) 105 % 65-137 2.5 03/19/09 14:26 625-98-9 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS Page 7 of 18 This report shall not be reproduced. except in full, without the written con sent of�Pare ..Ana lytical Services, Inc. J�4 m Pace Analytical Services, Inc, Pace Analytical Services, Inc. aceAnalXical 2225 Riverside Dr. 980o KinceyAve. Suite 1 oo WWWpavelabxmm Asheville, NC 28B04 Huntersvi4e, NC 2807E (828)254-7178 (704)875.9092 ANALYTICAL RESULTS Project: Gilbarco 042-08-018 Pace Project No.: 9239387 Sample- MW-130 Lab ID: 9239387004 Collected; 03/05/09 09:08 Received- 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Anatyzed CAS No. Qual 601/602 Volatiles Benzene Bromodich loromethane Bromofomn Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane D i bromo ch lorometh a n e 12-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Di ch I orod ifl uo romettl a ne 1,1-Dichloroethane 1,2-Dichloroethane 1, 1 -Di ch lo roethene cis- 1,2-Dichloroethene trans-1,2-Dichloroethene 1, 2-Dichloropropane cis-1,3-Dichloropropene trans-1 ,3-Dichloropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,22-Tetrachloroethane Tetra ch lo roethene Toluene 1,1,1-Trichloroethane 1,1,2-Thchloroethane Trichloroethene Trich to roftuo ro meth an e Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 1-Chloro-3-fluorobenzene (S) Date: 03/20/2009 04:43 PM Analytical Met had: EPA 6 01160 2 ND ug/L 1.0 1.0 1 03/19/09 15:09 71-43-2 ND ug/L 1.0 1.0 1 03/19/09 15:08 75-274 ND ug/L 1.0 1.0 1 03/1910915:08 75-25-2 NO ug/L 1.0 1,0 1 03119M915:08 74-83-9 NO ug/L 1.D 1.0 1 03/1910915:08 56-23-5 NO uglL 1.0 1.0 1 03/19M 15:08 108-90-7 ND uglL 1.0 1.0 1 03119/0915:08 75-00-3 NO ug/L 1.0 1.0 1 0311910915:08 67-68-3 NO ug/L 2.0 2.0 1 03/19/09 15:08 74-87-3 NO ug/L 1.0 1.0 1 03/19/09 15:08 124-48-1 NO ug/L 1.0 1.0 1 0311910915:08 106-93-4 NO ug1L 1.D 1.0 1 D3/19/0915:08 95-50-1 NO uglL 1.0 1.0 1 03/19/09 15:08 541-73-1 N❑ uglL 1.0 1.0 1 03/19/09 15:o8 106-46-7 NO ug/L 1.0 1.0 1 0311910915:08 75-71-8 NO ug/L 1.0 1-0 1 03119/0915:08 75-34-3 NO ug/L 1.0 1.0 1 03/19/09 15:08 107-06-2 NO ug/L 1.0 1.0 1 03/1910915-08 75-35-4 14.6 ug/L 1.0 1.0 1 031191D9 15:08 156-59-2 N❑ ug/L 1.0 1.0 1 03/19/09 15:08 156-60-5 NO ug/L 1.0 1.0 1 03/19/09 15:08 78-87-5 NO ug/L 1.0 1.0 1 03/19/09 15:08 10061-01-5 NO ug/L 1-0 1.0 1 03119/0915:08 10061-02-6 NO ug/L 1.0 1 A 1 03119/09 15:09 108-20-3 ND uglL 1.0 1.0 1 03/19/09 15:09 100-41-4 N❑ ug/L 2.0 2.0 1 03/19/09 15:08 75-09-2 13.4 ug/L 1.0 1.0 1 03/19/09 15:09 1634-04-4 NO ug/L 2.0 2.0 1 03/19109 15:09 91-20-3 NO ug/L 1.0 1.0 1 03/19/09 15:08 79-34-5 NO ug/L 1.0 1.D 1 03/1910915:08 127-18-4 NO ug/L 1.0 1.0 1 03/1910915:09 108-88-3 ND ug/L 1.0 1.0 1 03/19/09 15:08 71-55-6 NO ug/L 1.0 1-0 1 03/19/09 15:08 79-00-5 NO ug/L 1.D 1.0 1 03/19/09 15:08 79-01-6 NO ug/L 1.0 1.0 1 03/19/09 15:08 75-69-4 3.4 ug/L 1.0 1.0 1 03/19/09 15:08 75-01-4 NO ug/L 2.0 2,0 1 03/19/0915:09 1330-20-7 ND ug/L 2.0 2.0 1 03)19109 15:09 1330-20-7 NO uglL 1.0 1.0 1 03119/09 15:09 95-47-6 127 % 65-137 1 03119/09 15:08 625-98-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Page 8 of 18 ; laceAnaiXkal www.pacelabsrorn Project: Gilbarco 042-08-018 Pace Analytical Services. Inc. 2225 Riverside Dr Asheville, NC 2 88 04 (828)254.7176 ANALYTICAL RESULTS Pace Analytical Services, Inc, 98DO Kincey Ave. Suite 100 Huntersville, NC 28078 (704)675-9092 Pace Project No.: 9239387 Sample: MW-14 Lab ID: 9239387005 Collected: 03/05/09 14:50 Received: 031D6109 15.00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No Qual 6011602 Volatiles Analytical Method: EPA 6011602 Benzene ND ug/L 1.0 1.0 1 03/19/09 15.50 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 03/19/09 15.50 75-27-4 Bromoform ND uglL 1.0 1.0 1 03/1910915:50 75-25-2 Bromomethane ND ug1L 1 0 1.0 1 03/19/09 15:50 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 03/19/09 15:50 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 03/19/09 15:50 108.90-7 Chloroethane ND uglL 1.0 1.0 1 03/19/09 15:50 75-00-3 Chloroform N❑ ug1L 1.0 1.0 1 03/19/09 15:50 67-66-3 Chloromethane ND uglL 2.0 2.0 1 03/19/09 15:50 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 03/19/09 15:50 124-48.1 1,2-Dibromoethane (EDB) ND uglL 1.0 1.0 1 03/19/09 15:50 106-93-4 1,2-Dichtorobenzene ND ugIL 1 0 1.0 1 03/19109 15750 95-50-1 1,3-Dichlofobenzene ND ug/L 1.0 1.0 1 03/1910915:50 541-73-1 1,4-DichIOrobenzene ND ug/L 1.0 1.D 1 03/19/0915:50 106.46-7 D i ch to rod M u o ro metha ne ND uglL 1.0 1.0 1 0311910915:50 75-71-8 1,1-Dichloroethane ND ug1L 11,01 1.0 1 03/19/09 15:50 75-34-3 1,2-Dichloroethane ND uglL 1.0 1.0 1 03/19/0915,50 107-05-2 1.1-Dichloroethene ND uglL 1.0 1.0 1 03/19/09 15:50 75-35-4 cis-1,2-Dichloroethene ND ug1L 1.0 1.0 1 03119/09 15:50 156-59-2 trans-1.2-Dichloroethene ND ug1L 1.0 1.0 1 03/19/09 15:50 156-60-5 1,2-Dichloropropane ND ug1L 1.0 1.0 1 03119/09 15:50 78-87-5 cis-1.3-DichIoropropene ND ug/L 1.0 1.0 1 03/19/09 15:50 10061-01-5 trans 1 3-❑ichloropropene ND ug/L 1.0 1.0 1 03/19/09 15:50 10061-02-6 Diisopropyl ether ND ug1L 1.0 1.D 1 03/19/09 15:50 108-20-3 Ethylbenzene ND uglL 1.0 1.0 1 03/19/09 15:50 100-41-4 Methylene Chloride ND uglL 2.0 2.0 1 03/19/09 15:50 75-09-2 Methyl-tert-butyl ether ND uglL 1.0 1.0 1 03/19/09 15:50 1634-044 Naphthalene ND ug/L 2.0 2.0 1 03/19/09 15:50 91-20-3 1,1,2,2-Tetrachforoethane ND ug1L 1.0 1.0 1 03/19/09 15:50 79-34-5 Tetrachloroethene 32.0 ug1L 1.0 1.0 1 D311910915:50 127-18-4 Toluene ND ug/L 1.0 1.0 1 03119M915:50 108-88-3 1. 1, 1 -Trich lo roet h a ne ND uglL 1.0 1.0 1 03/19/09 15 50 71-55-6 1,1,2-Trichioroethane ND uglL 1.0 1.0 1 D311910915,50 79-00-5 Tfichloroethene ND uglL 1.0 1.0 1 0311910915:50 79-01-6 Trichlorofluoromethane ND uglL 1.0 1.0 1 031t9109 15:50 75-69-4 Vinyl chloride ND uglL 1.0 1.0 1 03/19/09 15,50 75-01-4 Xylene (Total) ND ug/L 2 0 2.0 1 03/19/09 15:50 1330-20-7 m&p-Xyiene ND ug1L 2.0 2.0 1 03/19/09 15:50 1330-2D-7 o-Xylene ND uglL 1.0 1.0 1 03/19/0915:50 95-47-6 1-Chlore-3-ffuorobenzene (S) 142 % 65-137 1 03/19/09 15:50 625-98-9 50 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS Page 9 of 18 This report shall not be reproduced, except in full, without the written consent of Pare Analytical Services, Inc.. A Pace Analytical Services, Inc. Pace Analytical Services, Inc. ceAnalj&cal 2225 Riverside dr. 9800 IGncey Ave. Suite 100 wn,N,paoeWs Gam Asheville, NC 28804 Huntersville, NC 28078 (829)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: Gilbarco 042-08-018 Pace Project No.: 9239387 Sample: MW-23D Lab ID: 9239387006 Collected: 03/05/09 09:32 Received: 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL ❑F Prepared Analyzed CAS No. 601/602 Voiatiles Analytical Method: EPA 6011602 Benzene 1.7 uglL 1.0 1.0 1 03/19/09 16:31 71-43.2 Bromodichioromethane NO uglL 1.0 1.0 1 03/19/09 16:31 75-27-4 Bromoform ND uglL 1.0 1.0 1 03/19/09 16:31 75-25-2 Bromomethane NO ug1L 1.0 1.0 1 03/1910916:31 74-83-9 Carbon tetrachloride NO ug1L 1.0 1.0 1 03119/09 16:31 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 0311910916:31 108-90-7 Chloroethane NO uglL 1.0 1.0 1 0311 GIM9 16:31 75-00-3 Chloroform ND uglL 1.0 1.0 1 03/19/09 16:31 67-66-3 Chloromethane NO uglL 2.0 2.0 1 03/19/09 16,31 74-87-3 Dibromochloromethane NO ug1L 1.0 1.0 1 03/19109 16:31 124-48-1 1,2-Dibromoethane (EDB) NO uglL 1.0 1.0 1 03/19/09 16:31 106-934 1,2-Dichlorobenzene ND uglL 1.0 1.0 1 03/19/09 16:31 95-50-1 1,3-Dichlorobenzene NO uglL 1.0 1 A 1 03/19/09 16:31 541-73-1 1,4-Dichlorobenzene ND uglL 1.0 1.0 1 03/19/09 16:31 106-46-7 DichiorodMuoromethane ND uglL 1.0 1.0 1 03/19/09 16:31 75-71-8 1,1-Dichloroethane 1.1 uglL 1.0 1.0 1 03119/0916:31 75-34-3 1,2-Dichloroethane ND uglL 1.0 1.0 1 03/19/09 16:31 107-06-2 1,1-Dichloroethene NO uglL 1.0 1.0 1 0311910916:31 75-35-4 cis- 1.2-Dichloroethene 173 ug1L 1.0 1.0 1 03/19/09 16:31 156-59-2 trans-1,2-Dichloroethene ND ug1L 1.0 1.0 1 03/19/09 16:31 156-60-5 1,2-Dichloropropane NO ug1L 1.0 1.0 1 03/19/09 16,31 78-87-5 cis-1,3-Dichloropropene N❑ ug1L 1.0 1.0 1 03/19/09 16:31 10061-01-5 trans-1,3-Dichloropropene ND uglL 1.0 1.0 1 03/19/09 16,31 10061-02-6 Diisopropyt ether NO uglL 1.0 1.0 1 03/19109 16:31 108-20-3 Ethylbenzene ND uglL 1.0 1.0 1 03/19/09 16:31 100-41-4 Methylene Chloride NO uglL 2.0 2.0 1 03/19/09 16:31 75-09-2 Methyl-tert-butyl ether 194 uglL 1 A 1.0 1 03/19/09 16:31 1634-04-4 Naphthalene NO uglL 2,0 2.0 1 03119/0916:31 91-20-3 1,1.2,2-Tetrachtoroethane ND uglL 1.0 1.0 1 03/19/09 16:31 79-34-5 Tetrachloroethene NO uglL 1.0 1.0 1 03/19/09 16:31 127-18-4 Toluene ND ug1L 1.0 1.0 1 0311910916:31 108-88-3 1,1,1-Trichloroethane ND uglL 1.0 1.0 1 03/1910916:31 71-55-6 1,1,2-Trichloroethane ND ug1L 1.0 1.13 1 03/1910916.31 79-00-5 Trichloroethene ND uglL 1.0 1.D 1 03/1910916:31 79-01-6 Trichloroiluoromethane NO uglL 1.0 1.0 1 0311910916.31 75-69-4 Vinyl chloride 19.4 ug1L 1.0 1.0 1 03/19/09 16:31 75-01-4 Xylene (Total) N❑ uglL 2.0 2.0 1 03/19/09 16:31 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 03/19109 16:31 1330-20-7 o-Xylene NO ug1L 1.0 1.0 1 03/19/09 16.31 95-47-6 1-ChIoro-3-fluorobe nzene (S) 115 °% 65-137 1 03/19/09 16:31 625-98-9 E Qual Date: 03/20/2009 04 43 PM REPORT OF LABORATORY ANALYSIS Page 10 of 18 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. c Pace Analytical Services, Inc. Pace Analytical Services, Inc. IaXAnalytical 2225 Riverside Dr. 9800 ttincey Ave. Suite too www Qacpiaas mm Asheville, NC 28804 Huntersville, NG 28078 (828)254-7178 (704)875-9092 ANALYTICAL RESULTS Project: Gilbarco 042-08.018 Pace Project No.: 9239387 Sample: MW-24 Lab ID: 92393870D7 Collected: 03/05/09 15:03 Received: 03/06/09 15:00 Matrix: Water Report Parameters Resu{ts Units Limit MDL DF Prepared Analyzed CAS No. Llual 6011602 Volatiles Benzene Br omod ich l orometh ane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chioroethane Chloroform Chloromethane D ib romoch iorometh a n e 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene D ich lorod if f u o rom eth a n e 1,1-Dichloroethane 1,2-Dichloroethene 1, 1 -Dichloroethene cis-1,2-Dichloroethene trans-1, 2-0ichloroethene 1.2-Dichloropropane cis-1,3-D ich I o rop ro pen e trans-1 ,3-Dichloropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Tdchloroethane 1,1,2-Trichloroethane Trich loroethene Trich io rofl u o ro metha n e Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 1 -C h I oro-3 A u o robenze n e (S) Date: 03/20/2009 04:43 PM Analytical Method: EPA 6011602 117 uglL 50,0 50.0 50 03/191091712 71-43-2 NO uglL 50.0 50.0 50 03/19/09 17:12 75-27-4 NO uglL 50.0 50.0 50 03/19/09 17:12 75-25-2 NO uglL 50.0 50.0 50 03/19/09 17:12 74-83-9 NO uglL 50.0 50.0 50 03/19/09 17:12 56-23-5 ND uglL 50.0 50.0 50 03/19/091T12 108-90-7 ND ug1L 50.0 50.0 50 031191D9 17:12 75-00-3 NO uglL 50.0 50.0 50 03/19/09 17:12 67-66-3 NO ug1L 100 100 50 03/19/09 17,12 74-87-3 ND uglL 50,0 50.0 50 03/19/09 17:12 124-48-1 ND uglL 50.0 50.0 50 03/19/09 17:12 106-93-4 NO uglL 5D.0 50.D 50 03/19/09 17.12 95-50-1 NO uglL 50.4 50.0 50 03/19/0917 12 541-73-1 ND uglL 50.0 50-0 50 03/19/09 17:12 106-46-7 NO uglL 50.0 50.0 50 03/19/09 17712 75-71-8 NO uglL %0 50.0 50 03/19/091712 75-34-3 NO uglL 50.0 50.0 50 03/19/091712 107-06-2 NO uglL 50.0 50.0 50 03/19/09 1712 75-35-4 466 uglL 50.0 50.0 50 03/19/09 1712 156-59-2 ND uglL 50.0 50-0 50 03/19/09 1712 156-60-5 ND uglL %0 50-0 50 03/19/09 17.12 78-87-5 NO uglL 50A 50.0 50 0311910917:12 10051-01-5 NO uglL 50.0 50.0 50 03/1910917:12 10061-02-6 NO uglL 50.0 50.0 50 03/19/09 1712 108-20-3 NO uglL 50.0 50.0 50 03/19/09 17:12 100-41-4 ND ug1L 100 100 50 03/19/09 17:12 75-09-2 NO uglL 50.D 50.0 50 03/19/0917:12 1634-04-4 ND uglL 100 100 50 03/1910917:12 91-20-3 ND uglL 500 50.0 50 03/19/09 17:12 79-34-5 1250 uglL 50.0 50-0 50 03/19/09 17:12 127-18-4 ND ug1L 50.0 50.0 50 03/19/09 17:12 108-88-3 ND uglL 50.0 5D.0 50 D311910917:12 71-55-6 ND uglL 50.0 50.0 50 03/19/09 17:12 79-00-5 NO uglL 50.0 50,D 50 03/1910917:12 79-01-6 NO uglL 50.0 50.0 50 0311910917A2 75.69-4 NO uglL 50.0 50.0 5o 03/191091T12 75-01-4 NO uglL 100 100 50 03/19/09 17:12 1330-20-7 NO uglL 100 100 50 03/19/09 17:12 1330-20-7 ND ug/L 50.0 50.0 50 03/19/09 1712 95-47-6 140 % 65-137 50 03/19/09 17:12 625-98-9 50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent ry ' of Pace Analytical Seices, Inc.. 11E&C. Page 11 of 18 e 'CeAnalyfical www.paoelahs.mm Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 26804 (828)254-7176 Pace Analytical Services, Inc. 9800 Klncey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Project. Gilbarco 042-08-018 Pace Project No. 9239387 ANALYTICAL RESULTS Sample: MW-25 Parameters Lab ID: 9239387008 Results Units Collected: Report Limit 03105/09 14A6 MDL OF Received: 03/06/09 15:00 Matrix: Water Prepared Analyzed CAS No. Quaff 6011602 Volatiles Analytical Method: EPA 601/602 Benzene NO uglL 1,0 1.0 1 03/19/09 17:54 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 03/19/09 17:54 75-27-4 Bromoform ND uglL 1.0 1.0 1 03/19/09 17:54 75-25-2 Bromomethane ND ug1L 1.0 1.0 1 03/19/09 17:54 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 03/19/09 17:54 56-23-5 Chlorobenzene NO uglL 1.0 1.0 1 03/19/0917754 108-90-7 Chloroethane NO ug1L 1.0 1.0 1 03/19/09 17.54 75-00-3 Chloroform NO uglL 1.0 1.0 1 03119/0917:54 67-66-3 Chloromethane NO uglL 2.0 2.0 1 03/19/0917:54 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 03/19/09 17:54 124-48-1 1,2-Dibromoethane (ED8) NO uglL 1.0 1.0 1 03/19/09 17:54 106-93-4 1,2-Dichlorobenzene NO uglL 1.0 1.0 1 03/19109 17:54 95-50-1 1,3-DicNorobenzene ND ug1L 1.0 1.0 1 03/19109 17:54 541-73-1 1,4-Dichlorohenzene ND ug1L 1.0 1.0 1 03/19/09 17:54 106-46-7 ❑ichlorodifluoromethane NO uglL 1.0 1.0 1 D3119109 17:54 75-71-8 1,1-Dichloroethane ND uglL 1.0 1.0 1 D311910917.54 75-34-3 1,2-Dichloroethane NO uglL 1.0 1.0 1 0311910917:54 107-06-2 1.1-Di chloroethane 1.1 uglL 1.0 1.0 1 03/19/0917.54 75-35-4 cis- 1,2-Dichloroethene 51.0 uglL 1.0 1.0 1 03/19/09 17:54 156-59-2 trans-1,2-Dichloroethane ND uglL 1.0 1.0 1 03/19/09 17:54 156-60-5 1,2-Dichloropropane NO uglL 1.0 1.0 1 03/19/09 1 T54 78-87-5 cis-1,3-Dichloropropene NO uglL 1.0 1.0 1 03/19/09 17:54 10061-01-5 trans-1,3-Dichlorop rope ne ND ug1L 1.0 1.0 1 0311910917:54 10061-02-6 Diisopropyl ether NO uglL 1.0 1.0 1 03/19/09 17:54 108-20-3 Ethylbenzene NO uglL 1.0 1.0 1 03/19109 17:54 100-41-4 Methylene Chloride NO uglL 2.0 2.D 1 03/19/09 17:54 75-09-2 Methyl -tent -butyl ether 4.8 uglL 1.0 1.0 1 03/19/09 17:54 1634-04-4 Naphthalene NO uglL 2,0 2.0 1 03/19/0917:54 91-20-3 1,1,2,2-Tetrachloroethane N❑ uglL 1.0 1.0 1 03/19/09 17:54 79-34-5 Tetrachloroethene 24.9 uglL 1.0 1.0 1 03/19109 17:54 127-18-4 Toluene NO ug1L 1.0 1.0 1 03/19109 17:54 108-88-3 1,1,1-Trichloroethane ND uglL 1.0 1-0 1 03/19/09 17:54 71-55-6 1.12-Trich0oroethane NO uglL 1.0 1.0 1 031191D91T54 79-00-5 Trichloroethene 8.3 uglL 1.0 1.0 1 03/19/09 17:54 79-01-6 Thchlarol9uoromethane ND ug1L 1.0 1.0 1 03/19/09 17:54 75-69-4 Vinyl chloride NO uglL 1.0 1.0 1 03/19/09 17:54 75-01-4 Xylene (Total) ND ug1L 2.0 2.0 1 03/19/09 17:54 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 03/19/09 17:54 1330.20.7 o-Xylene NO uglL 1-0 1.0 1 03/19/09 17:54 95-47-6 1 -C h loro-3 -flu o ro benzen e (5) 131 % 65-137 1 03/19/09 17:54 625-98-9 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in to. witheut the written consent of Pace Analytical Services, Inc.. Page 12 of 18 n Pace Analytical Services, Inc. Pace Analytical Services, Inc. _ laceAnalyfical 2225 Riverside Dr 9800 Kincey Ave. Suile 100 wrrw,parslabs.rom Asheville, NC 28804 Huntersville. NC 28078 (828)254.7176 (704)875-9092 ANALYTICAL RESULTS Project: Gilbarco 042-08.018 Pace Project No.' 9239387 Sample: MNW-42 Lab ID: 9239387009 Collected: 03/05/09 11:04 Received: 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL DP Prepared Analyzed CAS No. Qual 6011602 Volatiles Benzene B ro mad ich I o ro metha ne Bromoform Bromomethane Carbon tetrachloride Chiorobenzene Chloroethane Chloroform Chloromethane D ib ro m och to rometha n e 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene D ich to rod ifl uo rometh a n e 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis- 1,3-❑ichtoroprope ne trans- l,3-Dich ioropropen e Diisopropyl ether Ethylbenzene Methylene Chloride MethyMert-butyl ether Naphthalene 1.1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichtoroethane 1,1.2-Thchtoroethane Trichloroethene Trich to rofl u o rometh ane Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 1-Chioro-3-fluorobenzene (S) Date: 03/20/2009 04A3 PM Analytical Method: EPA 601 /602 NO uglL 1.0 1.0 1 03/19/09 18:36 71-43-2 NO uglL 1.0 1.0 1 03/19/09 18:35 75-27-4 NO uglL 1.0 1.0 1 03/19/09 18,35 75-25-2 NO uglL 1.0 1.0 1 03/19/09 18:35 74-83-9 NO uglL 1.0 1.0 1 03/19/09 18'35 56-23-5 NO uglL 1.0 1.0 1 03119/0918:35 108-90-7 NO uglL 1.0 1.0 1 03/1910918:35 75-00-3 NO uglL 1 0 1,0 1 031191091835 67-66-3 ND ug1L 2.0 2.0 1 03/19/09 18:35 74-87-3 NO uglL 1.0 1 A 1 03/19/09 18:35 124-48-1 NO uglL 1.0 1.0 1 03/19/09 18735 106-93-4 NO uglL 1.0 1.0 1 03/19/09 19:35 95-5D-1 NO uglL 1.0 1.0 1 03/19/0918,35 541-73-1 NO uglL 1-0 1.0 1 03/1910918,35 1D6-46-7 NO uglL 1.0 1.0 1 03119/0918:35 75-71-8 ND ug1L 1.0 1.0 1 03/19/09 18:35 75-34-3 ND uglL 1.0 1.0 1 03/19/09 18:35 107-06-2 NO uglL 1.0 1.0 1 03/19/09 18!35 75-35-4 NO uglL 1.0 1.0 1 03/19/09 18:35 156-59-2 ND uglL 1.0 1,0 1 03/19/09 18:35 156-60-5 NO uglL 1.0 1.0 1 03/19/09 18:35 78-87-5 NO uglL 1,0 1.0 1 0311910918:35 10061-01-5 NO uglL 1.0 1.0 1 03/19/09 18'35 10061-02-6 NO uglL 1,0 1.0 1 03119/0918:36 108-20-3 NO uglL 1.0 1.0 1 03119/0918:36 100-41-4 NO uglL 2.0 2.0 1 03/19/09 18:35 75-09-2 ND uglL 1.0 1.0 1 03/19/09 1836 1634-04-4 NO uglL 2.0 2A 1 03/19/09 18:36 91-20-3 ND ug1L 1.0 1.0 1 03/19M918:35 79-34-5 2.7 uglL 1.0 1.0 1 03119/0918:35 127-18-4 NO uglL 1.0 1.0 1 03/1910918:36 108-88-3 ND uglL 1A 1,0 1 03/19/09 18:35 71-55-6 NO uglL 1.0 1.0 1 03/19/09 18:35 79-00-5 NO uglL 1.0 1.0 1 03119/0918:35 79-01-6 NO uglL 1.0 1.0 1 03119/09 18:35 75-69-4 NO uglL 1.0 1,0 1 0311910918,35 75-01-4 NO uglL 2.0 2.0 1 03/19/09 18:36 1330-20-7 NO uglL 2.0 2.0 1 03/19/09 18:36 1330-20-7 NO ug1L 1.0 1.0 1 03/19/09 18:36 95-47-6 127 % 65-137 1 03119/09 18:35 625-98-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc.. Page 13 of 18 laceAnalyfical Pace Analytical Services. Inc. Pace Analytical Services, Inc. 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 swwpa+�efahscorn Asheville, NC 28804 Huntersville, NC 28078 (828)254-7178 t704j875-9092 ANALYTICAL RESULTS Project. Gilbarco 042-08-018 Pace Project No.: 9239387 Sample: MW 45 Lab ID: 9239387010 Collected: 03/05/09 11:11 Received 03/06/09 15:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6011602 Volatiies Analytical Method: EPA6011602 Benzene NO uglL 1.0 1.0 1 03119/09 19: 17 71-43-2 Bromodichloromethane NO uglL 1.0 1.0 1 03/19/09 19:17 75-27-4 Bromoform NO uglL 1.0 1 0 1 03/19/09 19:17 75.25-2 Bromomethane NO ug1L 1.0 1.0 1 03/19/09 19:17 74-83-9 Carbon tetrachloride NO ug/L 1-0 1.0 1 03/19/09 19 17 56-23-5 Chlorobenzene NO ug1L 1.0 1.0 1 03/19109 19,17 108-90-7 Chioroethane NO ug/L 1.D 1.0 1 03/19/09 19:17 75-00-3 Chloroform ND ug/L 1.0 1.0 1 03/19/09 19:17 67-66-3 Chloromethane NO ugIL 2.0 2.0 1 03/19/0919:17 74-87-3 Dibromochlor0methane NO uglL 1.0 1.0 1 03119/0919:17 124-48-1 1,2-Dibromoethane (EDB) NO ug1L 1.0 1 A 1 03/19/09 19:17 106-93-4 1,2-Dichlorobenzene NO uglL 1.0 1.0 1 03/19/09 1 9: 17 95-50-1 1,3-Dichiorobenzene NO ugIL 1.0 1.0 1 03/19/09 19,17 541-73-1 1,4-Dichlorobenzene NO ug/L 1.0 1.0 1 0311910919:17 106-46-7 Dichiorodi luoromethane ND ug/L 1.0 1.0 1 OW19109 19:17 75-71-8 1,1-Dichloroethane NO ugIL 1.0 1.0 1 03/19/09 19:17 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 03/19/09 19.17 107-06.2 1,1-Dichloroethane ND uglL 1.0 1.0 1 03/19/09 19:17 75-35-4 cis-1,2-Dichloroethene NO ugIL 1.0 1.a 1 03/19/0919717 156-59-2 trans-1,2-Dichloroethene ND ug1L 1.0 1.0 1 03/1910919:17 156-60-5 1,2-Dichloropropane N❑ uglL 1.0 1.0 1 03119/0919:17 78-87-5 cis-1,3-Dichioropropene ND ug11 1.0 1.0 1 03/19109 19:17 10061-01-5 trans-1,3-Dichtoropropene ND uglL 1.0 1.0 1 03119/0919:17 10061-02-6 Diisopropyl ether NO ug/L 1 A 1.0 1 03/19/09 19:17 108-20-3 Ethylbenzene NO ug/L 1.0 1.0 1 03/19109 19:17 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 03/19/09 19:17 75-09-2 MethyMert-butyl ether NO ug/L 1.0 1.0 1 03/19109 19,17 1634-D4-4 Naphthalene NO ugIL 2.0 2.0 1 0311910919:17 91-20-3 1,1,2,2-Tetrachloroethane N❑ uglL 1,0 1,0 1 031191091917 79-34-5 Tetfachloroethene 1.3 uglL 1.0 1.0 1 03/19/09 19.17 127-18-4 Toluene ND uglL 1.0 1.0 1 03/19/09 19:17 108-88-3 1,1,1-Trichloroethane NO ugIL 1.0 1.0 1 03/1910919:17 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 10 1 03119/0919:17 79-00-5 Trichloroethane NO uglL 1.0 1,0 1 03/19/091917 79-01-6 ThchloTofluoromethane NO ug/L 1.0 1.0 1 03119/0919:17 75-69-4 1Cnyi chloride NO ug/L 1.0 1.0 1 D3119109 19,17 75-01-4 Xylene (Total) NO ugIL 2.0 2.0 1 03/19109 19:17 1330-20-7 m&p-Xylene NO uglL 2.0 2.0 1 03/19109 1917 1330-20-7 a-Xylene NO uglL 1.0 1.0 1 03/19/09 19,17 95-47-6 1-Chloro-3-fluorobenzene (5) 119 % 65-137 1 03/19/09 19:17 625-98-9 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS This report shalt not be reproduced, except in full. without the written consent of Pace .A�nalyticaI Services, Inc.. s Page 14 of 18 acePace Analytical Services, Inc. Pace Analytical services, Inc. Analytrcal' 2225 Riverside Dr 9800 KinceyAve. Suite 100 wrvw.pareWs.cum Asheville, NC 28804 Huntersviile, NC 28078 028)254.7178 (704)875.9092 QUALITY CONTROL DATA Project. Giibarco 042-08-018 Pace Project No 9239387 QC Batch: GCV12999 Analysis Method: EPA 601 /602 QC Batch Method. EPA 60 V602 Analysis Description: 6011602 GCV Water Associated Lab Samples. 9239387001, 9239387002, 9239387003. 9239387004, 9239387005. 9239387006, 9239387007, 9239387008. 9239387009.9239387010 METHOD BLANK. 251095 Matrix: Water Associated Lab Samples. 9239387001, 9239387002. 9239387003, 9239387004, 9239387005. 9239387006, 9239387007. 9239387008, 9239387009.9239387010 Parameter Units Blank Result Reporting Limit Analyzed Qualifiers 1,1,1-Trichloroethane uglL NO 1.0 03119/0911.00 1112,2-Tetrachioroethane ug/L NO 1.0 0311910911:00 1,12-Trichloroethane ug/L NO 1.0 03/19109 11 :00 1.1-Dichloroethane ug/L ND 1.0 03/19109 11 :00 1,1-Dichloroethene uglL NO 1.0 03/19/09 11 00 12-❑ibromoethane (EDB) ug/L NO 1.0 03/19/09 11:00 12-Dichlorobenzene ug/L NO 1.0 03/1910911:00 1,2-Dichloroethane ug/L NO 1.0 03119/09 11 :00 1,2-Dichloropropane ug/L ND 1.0 0311910911:00 1,3-Dichlorobenzene ug/L ND 1.0 03119/091100 1.4-Dichlorobenzene ug/L NO 1.0 03119/09 11 :00 Benzene ug/L NO 1.0 03119/0911:00 Bromodichloromethane ug/L ND 1.0 0311910911:00 Bromoform ug/L ND 1.0 0311910911:00 Bromomethane ug/L ND 1.0 03/1910911:00 Carbon tetrachloride ug1L NO 1.0 03/19/09 11,00 Chlorobenzene uglL NO 1.0 03/1910911:00 Chioroethane ug/L NO 1.0 03/19109 11 :00 Chloroform ug/L NO 1.0 03/19/091100 Chloromethane ug/L NO 2.0 0311910911,00 cis-1.2-Dichloroethene ug/L NO 1.0 03119/0911:00 cis-1.3-Dichloropropene ug/L NO 1.0 03119/0911:00 Dibromochloromethane ug/L NO 1.0 0311910911:00 ❑ichlorodifluoromethane ug/L N❑ 10 03/19/0911:00 Diisopropyl ether ug/L ND 1.0 03/19/09 11:00 Ethylbenzene uglL ND 1.0 03119/0911100 m&p-Xylene ug/L ND 2.0 03119/0911,00 Methyl-tert-butyl ether ug/L NO 1.0 03/19/09 WOO Methylene Chloride ug/L ND 2.0 03/19/09 11:00 Naphthalene ug/L ND 2.0 03119/0911:00 o-Xylene ugJL ND 10 03/1910911.00 Tetrachloroethene ug/L ND 1.0 0311910911:00 Toluene ug/L ND 1.0 03/19/0911:00 trans- 1,2-Dichloroethene ug/L ND 1.0 03/1910911:00 trans- 1,3-Dichloropropene ug1L ND 1.0 0311910911:00 Trichlorciethene ug/L NO 1.0 03/19109 11 : 00 Trichlorofluoromethane ug/L NO 1.0 03/1910911:00 Vinyl chloride ug/L NO 1.0 03/19/09 11.00 Xylene (Total) ug/L NO 2.0 03119109 11:00 1-Chloro-3-fluorobenzene (S) % 121 65-137 03/19/09 11 00 Date : 0312012OD9 04A3 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pac/e+Analybral Services, Inc . Page 15 of 18 e Pace Analytical Services, Inc. acmwlytical 2225 Riverside Qr. xavn:pacels6s. caul Asheville, NC 28004 (828)254-7178 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Wuntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Gilbarco 042-08-018 Pace Project No.: 9239387 LABORATORY CONTROL SAMPLE. 251096 Spike LC5 LCS % Rec Parameter Units Conc. Result % Rec Limits 1,1.1-Trichloroethane uglL 20 22.9 115 41-138 1,1,2,2-TetrachIoroethane uglL 20 20.9 104 8-184 1,1,2-T6chloroethane uglL 20 21.7 109 39-136 1, 1 -Dichloroethane uglL 20 20.7 103 47-132 1,1-Dichloroethene uglL 20 23.0 115 28-167 1,2-Dibromoethane (EDB) uglL 20 23.1 116 50-150 1,2-Dichlorobenzene uglL 20 20.7 104 1-208 1,2-Dichloroethane uglL 20 21.6 108 51-147 1,2-Dichloropropane uglL 20 19.6 98 44-156 1,3-Dichlorobenzene uglL 20 20.3 101 7-187 1,4-Dichlorobenzene uglL 20 21.5 107 42-143 Benzene uglL 20 20.8 104 39-150 Bromodichloromethane uglL 20 20A 102 42-172 Bromoform uglL 20 21.8 1 D9 13-159 Bromomethane uglL 20 26.2 131 1-144 Carbon tetrachloride uglL 20 24.1 120 43-143 Chlorobenzene ug/L 20 21.5 107 38-150 Chloroethane uglL 20 22.1 111 46-137 Chloroform uglL 20 22.2 111 49-133 Chloromethane uglL 20 30.9 155 1-193 cis-1,2-Dichioroethene uglL 20 21X 105 38-155 cis, 1,3-Dichloropropene uglL 20 21A 107 22-178 Dibromochloromethane uglL 20 21.5 108 24-191 Dichloroddluoromethane uglL 20 21.5 108 48-157 Diisoprapyl ether uglL 20 20.2 101 89-108 Ethylbenzene ug1L 20 21.1 105 32-160 m8p-Xylene uglL 40 42.8 107 82-115 Methyl-tert-butyl ether uglL 20 20.0 100 88-110 Methylene Chlonde uglL 20 18.9 94 25-162 Naphthalene uglL 20 19.6 98 50-150 o-Xylene uglL 20 21.8 109 91-110 Tetrachloroethene uglL 20 21.7 108 26-162 Toluene uglL 20 21,2 106 46-148 trans-1,2-Dichloroethene ug1L 20 22.5 112 38-155 trans-1,3-Dichloropropene uglL 20 19.4 97 22-178 Trichloroethene uglL 20 21.7 108 35-146 Trichlorofluoromethane uglL 20 23.2 116 21-156 Vinyl chloride uglL 20 24.8 124 28-163 Xylene (Total) uglL 60 64.6 108 50-150 1-Chloro-3-fluorobenzene (S) % 117 65-137 Qualifies SAMPLE DUPLICATE: 251097 9239387001 Dup Max Parameter Units Result Result RPD RPD 1,1.1-Trichloroethane uglL NO NO 30 1,1,22-Tetrach1oroethane uglL ND ND 30 1,1,2-Trichloroethane uglL ND NO 30 Date: 03/20/2009 04:43 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Qualifiers Page 16 of 18 Pace Analytical Services, Inc. Pace Analytical Services, Inc. I)FaceAnalj4ical 2225 Riverside Dr 9800 KmceyAve Suite 100 www.Pare7aas.curr Asheville. INC 28804 Huntersvilie, NC 28078 (828)254-7176 (704)875.9092 DUALITY CONTROL DATA Project Gilbarco 042-08-018 Pace Project No.. 923,3387 SAMPLE DUPLICATE: 251097 Parameter Units 9239387001 Resutt ❑up Result 1, 1 -Dichloroethane ug/L NO R NO 1,1-Dichloroethene ug/L NO NO 1,2-Dibromoethane (EDB) uglL NO NO 1,2-Dichlorobenzene ug/L ND NO 1,2-Dichlaroethane ug/L ND NO 1,2-Dichloropropene ug/L NO NO 1.3-Dichlorobenzene ug/L NO N❑ 1,4-Dichlorobenzene uglL NO ND Benzene ug/L NO NO Bromodichloromethane ug/L ND ND Bromoform ug/L N❑ ND Bromomethane ug/L N❑ NO Carbon tetrachloride ug/L ND NO Chlorobenzene ug/L N❑ ND Chloroethane ug/L ND NO Chloroform uglL ND N❑ Chloromethane ug/L NO NO cis-1,2-Dlchloroetnene ug/L 935 852 cis- 1.3-Dichloropropene ug/L NO NO ❑ibromochloromethane ug/L Na NO Dichlorodrttuoromethane ug/L ND NO Diisopropyl ether ug/L ND NO Ethylbenzene ug1L 749 752 m&p-Xylene ug/L 723 729 Methyl-tert-butyl ether ug/L NO ND Methylene Chloride ug/L ND NO Naphthalene ugfL 384 376 o-Xylene ug/L NO ND Tetrachloroethene ug/L NO NO Toluene ug/L ND ND trans-1,2-Dichlorcethene uglL NO ND trans-1,3-Dichloropropene ug/L NO ND Trichioroethene ug/L NO ND TriChlorofiuoramethane uglL NO ND Vinyl chloride ug/L ND NO Xylene (Total) ug/L 723 729 1-Chloro-3-fluorobenzene (S) % 125 116 Date. 03/20/2009 04 43 PM Max RPD RPD REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pack -Analytical Services, inc. • i.i la 9 4 8 2 8 8 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Qualifiers Page 17 of 18 ace Anal rcal r www.panWabs.com Pac*Ana" cal Services, tnc. 2225 Riverside Dr. Asheville. NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800KinceyAve. Suile loo Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Gilbarco 042-08-018 Pace Project No.: 9239387 t17*1f211[193ni OF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. S - Surrogate 1.2-0iphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) ❑UP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical Is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. LJ - Indicates the compound was analyzed for, but not detected. ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. So Surrogate recovery outside laboratory control limits. Date- 03/20/2009 04A3 PM REPORT OF LABORATORY ANALYSIS Page 18 of 18 This report shall not be reproduced. except in rule, w4thout the written consent of Pace Analytical Services, Inc . dceMa�yt+ca� Section A Required Client infortnafion: Section 9 Required Project Information; CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information' Pa e : 1 Of + Company Trl onlKleinfelder, Inc. Report To. Gail Lica an Alters ion Gail Lica an Address 313 Gallimore Dairy Rd Copy To: Company Name Tri onlKleinfelder, Inc - Greensboro, NC 27409 Address 313 Gal}imore Dairy Rd, Greensboro, N Email To glicayanQkleinfelder.corn Purchase Order No Pace Quote Reference Phone 336 668-0093 Irax Ctienl Project ID GILBARCO 042-08-018 Pace Pra}ect Manager McKee, Bonnie Requested Due Date(TAT 10 Da Default Container Order Number 8484 Pace Profile N North Carolina ru.leix CODE r a ❑ U COLLECTED Preservatives Gilnking W►1�Cnk www W* u U � W-is Wr1e, WW Pr = 4 w aeon P SAMPLE ID o;'V6°i'° n; " [7 �_ START END Ed ❑ Y V s One character Per box. W.P. '� w w a i i5 d_g ar AR Or ❑ ❑ow" w e [� # Sample Ids must be unique T .e Tg "'f F a a V a ° ❑ i 2 m N NMm L L O a a N DATE TIME DATE TIME Q N n ❑ rNv _ _ U = z O d L� 1112 MW7 I - .5 1510 � x C MW-11 WT I I I 't+ef, x MW13 WT I r q5 x1 00:3 MW-130 WT rr.+ x MW-14 WT j�[rD x 5 MW-23D HVT `i-3 L x �k,-, 00 �5D3 7 MW-24 WT x oo MW-zs WT x 00y MW-42 WT 110q x 012 MW-45 W1 till x O i Q 3 5i1 r7op is >; PRINT Name of SAMPLER: m v'' c 4 i H °� -e-�- a u o m o U V R .-. E 2 0} SIGNATURE of SAMPLER: �/]®.�y �fGIrR.L DATE Signed: /� ` c,` lJ Pace Analytical Services. Inc. Pace Analytical Services, Inc. aeeftlytical 2225 Riverside DF 9800 KinceyAve Suite 100 www.pare4b5.f0m Asheville. NC 28804 Hunlersviile NC 28078 l828)254.7176 April 08. 2009 Ms. Gail Licayan Trigon/Kleinfelder, Inc. 313 Gallimore Dairy Rd Greensboro. NC 27409 RE: Project: GILBARCD 97746 Pace Project No.: 9240955 Dear Ms. Licayan: Enclosed are the analytical results for sample(s) received by the laboratory on March 27, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report. please feel free to contact me. Sincerely, Bonnie McKee bonnie-mckee@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSES This report shall not be reproduced, except in lull, without the written ccnseyntt of Pace Aria lyllcaI Services, Inc. (704)875.9092 page t of 9 m Pace Analytical Services, Inc. Pace Analytical Services, Inc. laceAnalytical 2225 Riverside ❑r 9800 KinceyAve. Suite loo AvwpaceraGsr-'Gm Asheville, NG 28804 Huntersville, NC 28078 (828)254.7178 (704)875.9092 CERTIFICATIONS Project: GILBARCO 97746 Pace Project No.: 9240955 Charlotte Certification IDs West Virginia Certification #: 357 North Carolina Field Serwces Certification #: 5342 Virginia Certification #: 00213 North Carolina Drinking Water Certification # 37706 Tennessee Certification #: 04010 Mew Jersey Certification #: NC012 South Carolina Drinking Water Cert. #: 990060003 Louisiana/LELAP Certification #- 04034 South Carolina Certification #: 990060001 Kentucky LIST Certification #: 84 Pennsylvania Certification #: 88-00784 Florida)NELAP Certification # E87627 Connecticut Certification #: PH-0104 North Carolina Wastewater Certification #: 12 Asheville Certification lDs West Virginia Certification * 356 Pennsylvania Certification #: 68-D3578 Virginia Certification #: 00072 North Carolina Wastewater Certification #: 40 Connecticut Certification #: PH-0106 North Carolina Drinking Water Certification #: 37712 FloddalNELAP Certification #: E87648 North Carolina Bioassay Certification #: 9 Tennessee Certification #: 298D New Jersey Certification #: NCO11 South Carolina Certification #. 99030001 Massachusetts Certification #: M-NC030 South Carolina Bioassay Certification #: 99030002 Louisiana/LELAP Certification #: 03095 Eden Certification IDs North Carolina Wastewater Certification * 633 North Carolina prinking Water Certification #: 37738 Virginia Drinking Water Certification #: 00424 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc Page 2 of 9 �aceAnal ical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr Asheville INC 28804 t828j254.7176 SAMPLE SUMMARY Project GILBARCO 97746 Pace Project No. 9240955 Lab ID Sample ID Matrix 9240955001 MW-14❑ Water 9240955002 MW-43❑ Water Hate Collected Date Received 03/27/09 09:09 03/27/09 14A0 03/2710910:07 03127/0914.40 REPORT OF LABORATORY ANALYSIS This report shall riot be reproduced, except in full, without the written consent of Pacee►Ana lytical Services, Inc. Pace Analytical Services, Inc. 9800 Kinney Ave. Suite 100 Huntersville, NC 28078 (704)875-9D92 Page 3 of 9 Pace Analytical Services, Inc. Pace Analytical ServIcea, Inc. aceAnalylical ' 2225 RNerside Dr. 9800 IOncey Ave. Suite 100 WWWwParelabsxonl Asheville, NC 28804 Huntersville. NC 28078 (828)254-7176 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: GILBARCO 97746 9240955 Analytes Lab ID Sample I❑ Method Analysts Reported 9240955001 MW-14D EPA601/602 ❑H11V 40 9240955002 MW-431) EPA6011602 ❑HW 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduoed, except in full. without the written consent of Pac�e+A:nalytical Services. Inc.. Page 4 of 9 e Pace Analytical Services, Inc. Pace Analytical Services, Inc. aeeA,aalXica1 2225 Riverside Dr. 9800 KinceyAve. Suite top www4pa,BJabs corn Asheville. NC 28804 Huntersville, NC 28078 (82B)2547175 (704)a75-9092 ANALYTICAL RESULTS Project: GILBARCO 97746 Pace Project No.: 9240955 Sample: MW-14D Lab ID: 9240955001 Collected: 03/27/09 09:09 Received: 03/27/09 14:40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Clual 6011602 Volatiles Analytical Method: EPA 6011602 Benzene ND uglL 1.0 1.0 1 04/03/09 01:17 7143-2 Bromadichloromethane ND uglL 1.0 1.0 1 04/03/09 01:17 75-274 Bromoform N❑ uglL 1.1) 1.0 1 04/03/09 01:17 75-25-2 Bromomethane ND uglL 1,0 1 A 1 04/03109 0 1; 17 74-83-9 Carbon tetrachloride ND uglL 1.a 1.0 1 04/03/09 01:17 56-23-5 Chlorobenzene ND uglL 1.0 1.0 1 04/03/09 01:17 108-90-7 Chloroethane ND uglL 10 1.0 1 D4103109 01:17 75-00-3 Chloroform ND ug1L 1.0 1.0 1 04/03/09 01:17 67-66-3 Chloromethane N❑ uglL 2.0 2.0 1 04/03/09 01;17 74-87-3 Dihromochloromethane ND uglL 1.0 1.0 1 04/03/09 01.17 124-48-1 1,2-Dibromoethane (EDB) ND ug1L 1.0 1.0 1 04/03/09 01:17 106-93-4 1,2-Dichlorobenzene ND ug1L 1.D 1.D 1 04/03/09 01 17 95-50-1 1.3-Dichlorobenzene N❑ ugJL 1.0 1.0 1 04103/090117 541-73-1 1.4-Dichlorobenzene ND uglL 1.0 1.a 1 04/03/09 01:17 10646--7 Dichlorodifluoromethane ND uglL 1.0 1.a 1 04/03/09 01:17 75-71-8 1,1-Dichloroethene ND uglL 1.0 1.0 1 04/03/09 01,17 75-34-3 1.2-Dichioroethane ND uglL 1.0 1.0 1 04/03/09 01:17 107-06.2 1,1-Dichloroethene ND uglL 1.0 1.0 1 04103/0901:17 75-35-4 cis- 1,2-Dichloroe the ne 1.0 uglL 1.0 1.0 1 04/03/09 01:17 156-59-2 trans-1,2-Dichloroethene ND uglL 1.0 1.0 1 04/03/09 01:17 156-60-5 1,2-Dichlaropropane ND uglL 1.0 1.0 1 04/03/09 01:17 78-87-5 cis-1,3-Dichloropropene ND uglL 1.0 1.0 1 04/03/09 0117 10061-01-5 trans- 1,3-Dichloropropene N❑ uglL 1.0 1.0 1 04103/09 01 ; 17 10061-02-6 Diisopropyl ether ND uglL 1.0 1.0 1 04/03/09 01:17 108-20-3 Ethylbenzene ND ugJL 1.a 1.0 1 04/03/09 01:17 100-41-4 Methylene Chloride ND ugJL 2,0 2.0 1 04/03/09 01:17 75-09-2 Methyl-tert-butyl ether ND uglL 1.0 1.0 1 04/03/09 01:17 1634-04-4 Naphthalene ND uglL 2.0 2.0 1 04/03/09 01:17 91-20-3 1.1.2.2-Tetrachloroethane ND uglL 1.0 1.0 1 D4103109 01.17 79-34-5 Tetrachloroethene 10.6 uglL 1.0 1.0 1 W03/09 01:17 127-18-4 Toluene ND uglL 1.D 1.0 1 D4103109 01:17 108-88-3 1,1,1-Trichloroethane N❑ ugJL 1.0 1.0 1 04103/0901;17 71-55-6 1,1,2-Trichtoroethane ND uglL 1.0 1.0 1 W0310901,17 79-00-5 Trichloroethene ND uglL 1.0 1.0 1 04/03/09 01.17 79-01-6 Trichlorofluoromethane ND ugJL 1.0 1.4 1 04/03/09 01 ' 17 75-69-4 Vinyl chloride ND uglL 1.0 1.0 1 04/03/09 0117 75-01-4 Xylene (Total) ND ugJL 2.a 2.0 1 04/03/09 01:17 1330-20-7 m&p-Xylene ND uglL 2.0 2.0 1 04/03109 01:17 1330-20-7 o-Xylene N❑ ugJL 1.0 1.0 1 04/03/09 01:17 95-47-6 1-Chlaro-3-fluarobenzene (S) 124 % 65-137 1 04/03/09 01:17 625-98-9 Date: D410812009 04 15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, 1nc.. Page 5 of 9 IMAnalytical" www.pacewaccvn Pace Analytical Services, Ine. 2225 Riverside Or Asheville, NC 28804 (82B)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28076 (704)875.9092 Project GILBARCQ 97746 ANALYTICAL RESULTS Pace Project No.: 9240955 Sample: MW43D Lab ID: 9240965002 Collected: 03/27/09 10:07 Received: 03/27/09 14.40 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6011602 Volatiles Analytical Method- EPA 601/602 Benzene 9.0 uglL 1.D 1.0 1 04/04/09 05:02 71-43-2 Bromodichloromethane ND uglL 1.0 1.0 1 04/04/09 05:02 75-27-4 Bromoform ND uglL 1.0 1.0 1 D4104109 05:02 75-25-2 Bromomethane N❑ uglL 1.0 1.0 1 04/04/09 05:02 74-83-9 Carbon tetrachloride ND uglL 1.0 1.0 1 04/04/09 05:02 56-23-5 Chlorobenzene ND uglL 1.0 1 A 1 04/04/09 05:02 108-90-7 Chioroethane ND uglL 1.0 10 1 D4104109 05:02 75-00-3 Chloroform ND uglL 1.0 1.0 1 04/04/09 05:02 67-66-3 Chloromethane N❑ uglL 2.0 2.0 1 04104/09 05:02 74-87-3 Dibromochloromethane ND uglL 1.0 1.0 1 04/04/09 05:02 124-48-1 1,2-Dibramoethane (EDB) ND ug1L 1.0 1.0 1 04/04/09 05702 106-93-4 1.2-Dichlorobenzene ND ug1L 1.0 1.0 1 04/04/09 05.02 95-50-1 1,3-Dichlorobenzene ND ug1L 1.0 1.0 1 04/04/09 05:02 541-73-1 1,4-Dichlorobenzene ND uglL 1.0 1.0 1 04/04/09 05:02 106-46-7 Dichlorodifluoromethane ND uglL 1.0 1.0 1 04/04/09 05:02 75-71-8 1,1-Dichloroethane 1.6 uglL 1.0 1.0 1 04/04/0905:02 75-34-3 1,2-Dichloroethane N❑ uglL 1.0 1.0 1 04/04/09 05:02 107-06-2 1,1-Dichloroethene 9.3 uglL 1.0 1.0 1 04/04/09 05702 75-35-4 cis-1,2-Dichloroethene ND uglL 1.0 1.0 1 04/04/09 05:02 156-59-2 trans-1,2-Dichloroethene ND uglL 1.0 1.0 1 041D4109 05:02 156-60-5 1,2-Dichloropropane ND uglL 1.0 1.D 1 04/04/09 05 02 78-87-5 cis-1,3-Dichloropropene ND ug1L 1.0 1.0 1 04/04/0905:02 1D061-01-5 tra ns- 1 .3-D ich to ro prope n e IN ug1L 1.0 1.0 1 041D4109 05,02 10061-02-6 Diisopropyl ether ND ugIL 1.0 1,0 1 04/04/09 05:02 108-20-3 Ethylbenzene 7.5 ug/L 1.0 1.0 1 04/04109 05702 100-41-4 Methylene Chloride ND uglL 2.0 2.0 1 04/04/09 05:02 75-09-2 Methyl-tert-butyl ether 3.6 uglL 1.0 1.0 1 04/04/09 05:02 1634-04-4 Naphthalene 4.4 ug1L 2.0 2.0 1 04/04/09 05:02 91-20-3 1,1,2,2-Tetrachtoroethane ND uglL 1.0 1.0 1 D4104109 05A2 79-34-5 Tetrachloroethene ND uglL 1.0 1.0 1 041041D9 D5:02 127-18-4 Toluene ND uglL 1.0 1.0 1 04104/09 05:02 108-88-3 1, 1, 1 -Trich loroeth a n e 1.2 uglL 1.0 1.0 1 04/04/09 05:02 71-55-6 1,1,2-T6chloroethane ND ug1L 1.0 1.0 1 04104/09 05:02 79-00-5 Trichloroethene ND ug/L 1,0 1.0 1 0410410905:02 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 04/04/09 05,02 75-69-4 Vinyl chfohde ND uglL 1.0 1.0 1 04/04/09 05A2 75-01-4 Xylene (Total) ND ug1L 2.0 2.0 1 04/04/09 05:02 1330-20-7 m&p-Xylene ND uglL 2.0 2,0 1 04/04/09 05:02 1330-20-7 o-Xylene ND uglL 1.0 1.0 1 04/04/09 05:02 95-47-6 1-Chloro-3-fluofobenzene (S) 105 % 65-137 1 04/04/09 05:02 625-98-9 Date? 04108/2009 04:15 PM REPORT OF LABORATORY ANALYSIS Page 6 of 9 This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc.. laceAnal rca� www.parefabs.wm Project: GILBARCO 97746 Pace Project No : 9240955 Pace Analytical Services, Inc. 2225 Riverside Or Asheville, INC 28804 (628)254-7176 QUALITY CONTROL DATA QC Batch- GCV13043 Analysis Method EPA 601/602 QC Batch Method EPA 601 /602 Analysis Description. 6011602 GCV Water Associated Lab Samples, 9240955001. 9240955002 METHOD BLANK- 268263 Matrix Water Associated Lab Samples: 9240955001. 9240955002 Blank Reporting Parameter Units Result Limit Anatyzed 1,1,1-Trichloroethane uglL ND 1.0 04/02/09 18.21 1,1.2.2-Tetrachloroethane ug1L ND 1.0 04/02/0918.21 1,1.2-Trichloroethane uglL ND 1.0 0410210918:21 1,1-Dichloroethane uglL ND 1.0 04/0210918:21 1,1-Dichioroethene uglL ND 1.0 04/0210918-21 1,2-Dibromoethane (EDS) ug/L N❑ 1.0 04/02/09 18:21 1,2-Dichlorobenzene uglL ND 1.0 041021091821 1,2-Dichlorcethane ug1L ND 1.0 04102M918:21 1,2-Dichloropropane uglL ND 1.0 04102/0918:21 1,3-Dichlorobenzene uglL ND 1.0 04/02/09 18:21 1,4-Dichlorobenzene uglL ND 1.0 04/02/091811 Benzene ug/L ND 1.0 0410210918721 Bromodichloromethane uglL ND 1.0 04/0210918:21 Bromoform uglL ND 10 04/0210918:21 Bromomethane ug1L NO 1.0 0410210910:21 Carbon tetrachloride uglL ND 1.0 04/02/09 18:21 Chlorobenzene uglL ND 1.0 04/02/09 18 21 Chloroethane ug/L ND 1.0 0410210918.21 Chloroform uglL ND 1.0 04/02/09 18 21 Chloromethane ug1L ND 2.0 04102/0918:21 cis-1,2-1Dichloroethene uglL ND 1.0 04102/0918:21 cis- 1,3-Dichloropropene uglL ND 1.0 04/0210918:21 Dibromochloromethane uglL ND 1.0 04/0210918:21 Dichlcrodifiuoromethane ug/L N❑ 1.0 04102/091821 Diisopropyl ether uglL ND 1.0 04/02/09 18 21 Ethylbenzene ug/L ND 1.0 04/02/09 18:21 m&p-Xylene uglL ND 2.0 04102M9 18:21 Methyl-tert-butyl ether uglL N❑ 1.0 04/02/09 18:21 Methylene Chloride uglL ND 2.0 04/02/09 18:21 Naphthalene uglL N❑ 2.0 04/02/09 18:21 o-Xylene uglL ND 1.0 04/02/0918:21 Tetrachloroethene uglL ND 1.0 0410210918:21 Toluene uglL N❑ 1.0 04/0210918:21 trans-1.2-Dichloroethene ug/L ND 1.0 04/02/09 18 21 trans- 1,3-Dichloropropene uglL N❑ 1.0 04/0210918,21 Trichloroethene uglL ND 1.0 04/0210918:21 Trichlorofluoromethane uglL N❑ 1.0 04/02/09 18 21 Vinyl chloride uglL ND 1.0 04/02/09 18:21 Xylene (Total) uglL N❑ 2.0 04/02/09 18 21 1-Chloro-3-fluorobenzene (S) °I 109 65-137 04/02/09 18.21 Date: 04/08/2009 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Qualifiers Pace Analytical Services, Inc. 9800 Kinrey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 9 e pace Analytical Services, Inc. lj/ iml 2225 Riverside Dr. wawpaceiabscom Asheville, NC 288D4 (828)254-7176 QUALITY CONTROL DATA Project: GILBARCO 97746 Pace Project No.. 9240955 LABORATORY CONTROL SAMPLE Parameter 258264 Units Spike Conc. LCS Result LCS °% Rec °% Rec Limits 1,1,1-Trichloroethane uglL 20 19.8 99 41-138 1,1,22-Tetrachloroethane ugfL 20 20.2 101 8-184 1,1,2-Trichloroethane ug/L 20 21.6 108 39-136 1,1-Dichloroethane ugIL 20 20.0 100 47-132 1,1-Dichloroethene uglL 20 20.3 101 28-167 1,2-Dibromoethane (EDB) uglL 20 21.8 109 50-150 1,2-Dichlorobenzene uglL 20 19.3 96 1-208 1,2-Dichloroethane uglL 20 21.3 107 51-147 1,2-Dichloropropane uglL 20 19.6 98 44-156 1,3-Dichlorobenzene ug/L 20 22.0 110 7-187 i ,4-Dichlorobenzene ugfL 20 17.5 88 42-143 Benzene ug1L 20 19.9 100 39-150 Bromodichloromethane ug/L 20 21.2 106 42-172 Bromoform uglL 20 21.2 106 13-159 Bromamethane uglL 20 18.3 91 1-144 Carbon tetrachloride uglL 20 20.8 1 D4 43-143 Chlorobenzene ug/L 20 19.4 97 38-150 Chloroethane uglL 20 19.5 97 46-137 Chloroform uglL 20 20.6 103 49-133 Chloromethane uglL 20 18.3 91 1-193 cis- 1,2•Dichtoroethene uglL 20 19.7 98 38-155 cis-1,3-Dichloropropene ugfL 20 21.8 109 22-178 Dibromachloromethane uglL 20 21.1 106 24-191 Dichlerodifluofomethane uglt- 20 13.2 66 48-157 Diisopropyl ether uglL 20 18.3 91 89-108 Ethyibenzene uglL 20 21.1 105 32-160 m&p-Xylene uglL 40 43.3 108 82-115 Methyl-tert-butyl ether uglL 20 18.2 91 88-110 Methylene Chloride uglL 20 19.4 97 25-162 Naphthalene ug/L 20 17.9 90 50-150 o-Xylene ug/L 20 21.3 106 91-110 Tetrachloroethene uglL 20 19.7 98 26-162 Toluene uglL 20 20.4 102 46-148 trans-1,2-❑ichioroethene uglL 20 21.0 105 38-155 trans-1,3-Dichloropropene uglL 20 20.5 103 22.178 Trichloroethene ug/L 20 21.2 106 35-146 Trichlorofluoremethane ug/L 20 20.5 103 21-156 Vinyl chloride ug/L 20 18.7 93 28-163 Xylene (Total) uglL 60 64.6 108 50-150 1 -C h I oro-3-fluo ra be nze n e (S) % 119 65-137 Date: 04/08/2009 04:15 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent � of Pace Analytical Services, Inc.. leg PacaAnalyticaI Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Page 8of9 Pace Analytical Services, Inc. Pace Analytical Services. Inc. /aceAna,(Xieal • 2225 Riverside Dr 9900 Kincey Ave. Suite 100 www,paWab&COm Asheville. NC 28804 Huntefsville, NC 28078 (828)254.7175 (704)875.9092 QUALIFIERS Project: GILSARCO 97746 Pace Project No : 9240955 DEFINITIONS DF - Dilution Factor, if reported. represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. NO - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit S - Surrogate 1.2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene. Consistent with EPA guidelines. unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NEtAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. Date 04M812009 04:15 PM REPORT OF LABORATORY ANALYSIS Page 9 of 9 This report shall not be reproduced. except in full, without the written consent of Pare Analytical Services, Inc . Lk I. . . PaceAnalltical J` iuww naru[ahc rnm CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOGLIMENT. All relevant fields must be completed accurately. Section A Section B Section Page: of r Required Cllenl Informallan: Required Project Information: Invoice Informalion. Company. Report To- Attention: 1305897 G h.� ri 8r J klPi •+{� s! F T Address. 31 M0frV DA.f copy To Company Name:REGULATORY SQi AGENCY GlmeAsbe" Address: � NPOES i ' GROUND WATER j DRINKING WATER UST f RCRA r OTHER- Email To: rd Al G PSrrChase Order No: Pace Quole Rofarenee. Pnone: `.� Fax: � Prnject Name G i I Pace Project Site Location •�ppr{,ar f7! Manager �jC Requested Due Data/TAT; Project Number: Pace P.vraa p: A a tld 3i ��� �f J ^ STATE: Requested Analysis Filtered (Y1NJ Section D Matrix Cvdea y x R.qul red Chent rrdormahan MATRIX 1 CODE 9 COLLECTED Preservafives i Dunking Water DW U 'O Water wT o14 Waste Water WW Product P SOiUSoUd SL t : 0 COMPoSITE SrnRT COMPaS[TF EN07GRAE V J p .y 2 SAMPLE ID wpe wP a w w {A-Z. 0-9 1.-j Alf AR O uy a ♦` ` N• o Sample IDs MUST DE UNIQUE Tissue TS O a w 2 Z 6R + U Dlher 6T X w w O m 7� # S: w H a a Q U 0 0 p Cn IC ]C O .. d 4 C 41 f"- }'- �' -o N < N DATE TIME DATE TIME '� Y z M U = 2 C z `� ❑ Q .I, e1 d Pace Project No.l Lab I.C. I - 19 D G 3-111 9019 3 X. z - 4 MW t{ 4 % ion H r /1 3 A S 6 7 B 9 7D 1t 12 ADDITIONAL COMMENTS RELINQUISHED BY 1 AFFILIATION DATE TIME ACCEPTED BY 1 AFFILIATION TIME SAMPLE CONDITIONS yy 1 �JD.AATTE,J SAMPLER NAME AND SIGNATURE v o _m ORIGINAL c a m a o U 2 x a z m PRINT Name of SAMPLER: a� �1 `—� [] . E + `- DATE Signed + SIGNATURE of SAMPLER: 1&') �. �xe„r_ - z +an Ina TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-T 25,000 Q 15,000 0 n m v 0 in 7- ca i�: 10,000 5,000 11 4-- -- i - f - -T i i r -- • 7 . T I 'T - r �9 ~1•�9 �i9 ?9 rJ �� 9 79 �19 �J,9 70 r,� /�0 r!D /1, /J4 �4 �� �4 �1 f!7 o 0 l s e t o r � °� s s 6 o Date 25 20 i 10 5 m TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-11 ;al VOCs . L/o�0 ���0 �01) �ol�� �0�o S 6' 0 Date 180 160 140 120 W, 3 N 80 LS] ME 40 20 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13 .31 - Y 10 �d �a �d �� �� �a � �� Ll to ��, 14 L1 ��, tl 1, L1 10 �� ll 79 �s 79 79 'a �9 �9 ')� ri0 7b �0 �0 �0 h r!0 h0 �i0 '�o '�0 'J � o i ? 0 s b' J o j ? �u S b' .9 O Date ZE 0 n 40 m m 0 30 r 20 90 0 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-13❑ °s o6' 1--Total VOCs Date ✓a1) , 0 am 1,800 1,600 1,400 0 1,000 EA .11 400 0 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14 190 r 2 s '96' � 0 O 7 2 o 07 s 0 l> & .9 0 Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-14D Axis] 450 350 0 300 n m ¢1. 250 0 200 150 100 kill Total VOCs 0 i I r V. '0n �9� �9 �0 'i0Q h9 '9 ri.9 ' �i0o '0 �0 �i Rios �i0 �J,0� ''0 � � s 9s � � 9 � � � 0 � °� � Q � s n Date m 700 n 500 7- t r 300 200 100 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-23D 9 rls 7s9 '7� ,79 't9 �9 /!.� 7' rla 'ia 'lp �0 �o �a rl, /ia /ia rid / 19 Date 7,000 i iTi 5,000 n n 4,000 m w u 3,000 r 1,000 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-24 9 �9 'o '9 A 'o 1 '9 'o 'o 'o 'o 'o 70 go 0 7 ? 0 Q s 0 � � - � � s s 9 0 Date TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-25 w m m 70 40 30 20 10 0 I --- -- - - - - - - 1 1 --I I l vo �a Vol), '0 70 ?o 'o �, go o 'o �� �W, 9 a 0 � s 6 j s 9 0 Date Al 40 w n m 30 r Wi 10 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-42 Date 800 700 600 500 0 3 n m 3 rr °* 400 a N fa Q 300 200 100 0 TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-43D Date --$-- Total VOCs 3 2 0 n co m a' TOTAL VOLATILE ORGANIC COMPOUNDS VERSUS TIME IN MW-45 o6, oy Date 0