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HomeMy WebLinkAboutWI0400091_Monitoring (Report)_20090212w T G gO0091 Quarterly HiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 RECEIVED 1 DENR 1 UWQ Aquifer prnfprtir. , gertlpfl P.O. Box 18846 • Zip 27419--8846 • 313 Gallimore Dairy Road • Greensboro, NC 27409 • p 336.668.0093 • f 336.668.3868 February 4, 2009 Mr. Qu Qi Aquifer Protection Section — UIC Staff DENR — Division of Water Quality 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Reference: Quarterly HiSOC Monitoring Report Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 Dear Mr. Qi: Trigon I Kleinfelder, Inc. is pleased to provide our quarterly monitoring report for the Underground Injection Control (UIC) Permit for treatment of groundwater with the HiSOC system at the referenced site. This report summarizes our field activities, observations, and includes the analytical results of the groundwater samples. Should you have any questions or require additional information, please do not hesitate to contact Chris Hay at your convenience. Very truly yours, TRIGON I KLEINFELDER, INC. Christopher W. Hay E.I. Environmental Gro Manager CWH/GGL:cas Gail G. Licayan, P.E. Project Professional j:\share\0420\projects\2008\018\january 5, 2009 sampling event\r97746 jan 09.doc RECEIVED 1 DENR 1 DWL] Aquifer Section www.trigoneng.com Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 GILBARCO Greensboro, North Carolina Groundwater Incident Nos. 12960 And 15123 SITE INFORMATION Address: Contact: Telephone: Latitude and Longitude Risk Classification: Land Use Category: LAND OWNERSHIP Name: Address: Telephone: Attention: RELEASE INFORMATION February 4, 2009 7300 West Friendly Avenue Greensboro, North Carolina Ms. Beth Money 336.547.5130 36.0901°N, 79.9282 °W Low Commercial Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina 27420 336.547.5130 Ms. Beth Money Cause of Release: Release from a 1,000 gallon diesel UST and four 550 gallon gasoline USTs was discovered in November and December 1994. The quantity released is unknown. ENVIRONMENTAL CONSULTANT Name: Trigon I Kleinfelder, Inc. Address: Post Office Box 18846 Greensboro, North Carolina 27419-8846 Telephone: 336.668.0093 Attention: Mr. Christopher W. Hay Seal ao% aiu'�'d rtifying Professional Engineer I, Gad O., caypn� La %p es%iional Engineer for Trigon I Kleinfelder, Inc., do certify that the information contm—nea ins=rggrt Is coect and accurate to the best of my knowledge. Gail G. b" ngineer No. 031532 TRIGON I KLEINFELDER, INC. Page i Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 TABLE OF CONTENTS 1.0 INTRODUCTION..................................................................................................................................1 2.0 GROUNDWATER MONITORING ACTIVITIES...............................................................................1 3.0 GROUNDWATER ANALYTICAL RESULTS....................................................................................2 4.0 HiSOC INSTALLATION AND MONITORING..................................................................................3 5.0 CONCLUSIONS AND RECOMMENDATIONS.................................................................................5 TABLES 1 Groundwater Elevation Data 2 Aquifer Characteristics Field Analysis Summary 3 Summary of Groundwater Sample Results 4 Historical Summary of Groundwater Sample Results 5 Estimated Dissolved Hydrogen Concentrations at Injection Wells 6 Estimated Hydrogen Consumption FIGURES 1 Site Location Map 2 Site Plan 3 Groundwater Potentiometric Surface Map 4 Total VOCs Concentrations 5 Total Chlorinated Hydrocarbons APPENDICES A Laboratory Report and Chain -of -Custody Document B Total VOC Graphs TRIGON I KLEINFELDER, INC. Page ii Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 1.0 INTRODUCTION The subject site is located at 7300 West Friendly Avenue in Greensboro, Guilford County, North Carolina (Figure 1). There are currently two open groundwater incidents (Incident Nos. 12960 and 15123). The incidents have a commingled plume and are being treated with the same corrective action plan. A pump and treat system is currently operating at the site. The system consists of four recovery wells, an oil -water separator, and an air stripping system. In January 2008, Trigon I Kleinfelder submitted a CAP Addendum recommending the use of HiSOC and iSOC technology to degrade the chlorinated and petroleum hydrocarbons in groundwater at the site. This technology will work in concert with the existing groundwater recovery system and supplement the ability of the system to contain the contaminant plume within the property limits and reduce contaminant levels. The HiSOC system was installed in June of 2008 and began operating on June 13, 2008. The baseline sampling event was conducted on June 5, 2008. The purpose of this report is to summarize the quarterly monitoring of the HiSOC system performed on January 5, 2009. 2.0 GROUNDWATER MONITORING ACTIVITIES Static water levels were measured in the existing monitoring wells on -site on January 5, 2009. Groundwater samples were collected from ten of the monitoring wells (MW-7, MW-11, MW-13, MW-1313, MW-14, MW-2313, MW-24, MW-25, MW-42, and MW-45) and analyzed for VOCs by EPA Methods 601 and 602, isopropyl ether, methyl tert-butyl ether, ethylene dibromide, and xylenes. Field parameters including oxidation-reduction potential (ORP), pH, conductivity, dissolved oxygen, and temperature of representative groundwater samples were also recorded from each monitoring well sampled. Groundwater elevations in the existing monitoring wells were used to determine the groundwater flow direction, average hydraulic gradient, and plume orientation. Table 1 provides a summary of monitoring well construction details and the groundwater elevations measured on January 5, 2009. The monitoring well locations are shown on Figure 2. The static water levels measured on January 5, 2009 between monitoring wells MW-32 and MW-45 indicate a horizontal groundwater flow gradient of 0.04 feet per foot to the northwest. A groundwater flow map of the shallow aquifer based on TRIGON I KLEINFELDER, INC. Page I Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 the January 5, 2009 groundwater elevations are shown on Figure 3. Free product was not observed in any of the monitoring wells during the sampling event. Based on data provided in the October 1996 Corrective Action Plan, the surficial aquifer has an average hydraulic conductivity of 0.09 feet per day. The average groundwater velocity is estimated to be 0.01 feet per day (4 feet per year), based on the average groundwater gradient from the January 5, 2009, water level measurements and an estimated effective porosity of thirty percent. Groundwater samples were collected from monitoring wells MW-7, MW-11, MW-13, MW-13D, MW-14, MW-23D, MW-24, MW-25, MW-42, and MW-45 using disposable polyethylene bailers. The wells were purged of three well volumes of water or until they were bailed dry. Groundwater purged from the monitoring wells was disposed of in the on -site groundwater recovery system. Groundwater samples were collected and placed in laboratory prepared containers. The samples were maintained on ice until delivered to Pace Analytical Laboratories in Huntersville, North Carolina. 3.0 GROUNDWATER ANALYTICAL RESULTS The field measurements recorded on January 5, 2009 are summarized in Table 2, which includes the preferred conditions for natural biodegradation of chlorinated compounds within the groundwater plume. However, groundwater aquifer characteristics recorded during the sampling event were not consistent with previously recorded data. The dissolved oxygen and oxidation-reduction potential measurements recorded lead us to believe the field instrumentation was not operating properly. Volatile organic compounds were detected at levels above the respective North Carolina groundwater quality standards established in 15 NCAC, Subchapter 2L (2L Standards) in nine of the ten monitoring wells sampled. The analytical results are summarized in Table 3 and a historical summary of groundwater sampling results is presented in Table 4. A chain -of -custody document was maintained throughout the collection and transportation process and is included in Appendix A with the laboratory report. TRIGON I KLEINFELDER, INC. Page 2 Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, Norlh Carolina Trigon I Kleinfelder Project No. 97746 Historical total volatile organic compound concentrations for each monitoring well sampled are shown in individual graphs included in Appendix B. The individual graphs of the total VOC concentration for each monitoring well indicate MW-7, MW-11, MW-13, MW-13D, MW-14, and MW-23D generally have trends of decreasing contaminant levels. Other graphs of contaminant concentrations indicate the total VOCs levels remain fairly consistent (MW-24, MW-42, and MW-45). The trend of rising contaminant concentrations are of concern in monitoring well MW-25. Total VOCs concentrations detected during the January 5, 2009 sampling event are shown on Figure 4. The current hydrogen injection phase of the corrective action plan targets the reduction of chlorinated hydrocarbon contaminant levels in the groundwater. The oxygen injection phase will target the reduction of petroleum hydrocarbons. The volatile organic compounds targeted during the hydrogen and oxygen injection phases of the corrective action plan are separated in Table 4 by a double line. Total chlorinated hydrocarbons concentrations detected from the groundwater samples collected January 5, 2009 are shown on Figure 5. Historical chlorinated hydrocarbon contaminant levels generally follow the decreasing trend of total VOCs in MW-7, MW-11, MW-13, MW-13D, MW-14, and MW-231); consistent levels in MW-24, MW-42, and MW-45; and the rising trend in MW-25. 4.0 HiSOC INSTALLATION AND MONITORING Trigon I Kleinfelder applied for a permit from the Underground Injection Control (UIC) Program for the installation of a hydrogen and oxygen delivery system for remediation of contaminants in groundwater at the site. A permit dated March 20, 2008 was issued for the site (Injection Well Permit WI0400091). The permit is effective through April 30, 2010. Installation of the injection equipment was initiated on April 9 through April 11, 2008. The existing protective casings were removed from monitoring wells MW-7, MW-10, MW-23D, MW-29, and MW-34. Ten -inch diameter PVC casings were installed to a depth of five feet below ground surface adjacent to the monitoring well locations to hold the hydrogen cylinders. Six to ten inches of gravel was placed in the bottom of each casing. Excavations were completed for installation of twenty four -inch square, steel well vaults and the vaults were set in concrete flush with the ground surface. Protective vaults were also installed adjacent to the existing above grade protective covers for monitoring wells TRIGON I KLEINFELDER, INC Page 3 Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 MW-14D, MW-15, MW-16, MW-24, and MW-43D. The 15-inch by 24-inch PVC protective vaults were installed over the cylinder casings. Vents were installed in the protective vaults to allow hydrogen to be released in the case of a leak from the delivery system. The HiSOC equipment from InVentures was installed at the site in ten existing monitoring wells (MW-7, MW-10, MW-14D, MW-15, MW-16, MW-23D, MW-24, MW-29, MW-34, and MW-43D) on June 13, 2008. Within each injection well is a HiSOC unit and filter. Hydrogen is supplied from a compressed gas cylinder with a regulator and gauge connected to the HiSOC unit by Parflex tubing and a support cable. Four -foot grounding rods were installed and connected to the regulator assembly of the gas cylinders. The HiSOC installation locations are shown on the figures in orange. In anaerobic bioremediation applications, the HiSOC supersaturates the treatment well with dissolved hydrogen, typically at a concentration of 1 to 4 parts per million (ppm) depending on the immersion depth of the HiSOC unit in groundwater. The dissolved hydrogen concentration achieved in the injection well depends on the height of the water column in the well. Each atmosphere of pressure allows for a maximum of approximately 1.6 ppm of dissolved hydrogen. Table 5 estimates the dissolved hydrogen concentrations in each of the injection wells. These concentrations are estimated based on the approximate pressure at the installation depth of the HiSOC based on the depth of the water column in the injection wells. The calculation is made with the assumption that 1.6 ppm of hydrogen is dissolved in the groundwater per atmosphere of pressure. Hydrogen is infused from the HiSOC into the treatment well at a typical rate of 28 standard cubic centimeters per minute or approximately 1.4 cubic feet per day. The hydrogen consumption in each of the injection wells is tracked to estimate the remaining service life of the hydrogen cylinders. Table 6 shows the recorded hydrogen cylinder pressures and estimates a date for each injection well that the cylinder should be replaced. It is anticipated that the hydrogen cylinders will be replaced prior to the next quarterly monitoring event scheduled for March 2009. The HiSOC produces a convection current in the well with a designed release bubble from the top of the HiSOC to distribute dissolved hydrogen rich water throughout the screened interval. A curtain of hydrogen rich water disperses around the well into the adjacent groundwater forming a treatment zone allowing enhanced bioremediation to degrade the target contaminants. TRIGON I KLEINFELDER, INC. Page 4 Ms. Beth Money, Gilbarco February 4, 2009 7300 West Friendly Avenue, Greensboro, North Carolina Trigon I Kleinfelder Project No. 97746 Following installation of HiSOC units in monitoring wells MW-10 and MW-29, the HiSOC units were found to be flooded. The HiSOCs were removed and the units were dried for a period of two weeks prior to re -installation. Otherwise the hydrogen delivery system has been in continuous operation since June 13, 2008. 5.0 CONCLUSIONS AND RECOMMENDATIONS The groundwater potentiometric map indicates that the groundwater flow direction at the site is from the southeast to the northwest under a gradient of 0.04 feet per foot as measured between MW-32 and MW-45. Contaminant levels in monitoring wells MW-7, MW-11, MW-13, MW-14, MW-13D, and MW- 23D have decreased when compared to the groundwater contamination levels during the baseline sampling event in June 2008. Groundwater contaminant levels in monitoring wells MW-24, MW-42, and MW-45 remained consistent with the baseline levels and monitoring well MW-25 showed an increase. These four wells have relatively low chlorinated hydrocarbon levels and were not significantly different than their historical averages. Groundwater aquifer characteristics recorded during the sampling event were not consistent with previously recorded data. It is likely the field instrument was not operating properly. A different instrument will be used next quarter to evaluate the aquifer characteristics. Corrective action monitoring will be conducted on a quarterly schedule and the next event should be scheduled for March 2009. During the next sampling event, we recommend the following wells are sampled: MW-7, MW-13, MW-13D, MW-14, MW-16, MW-23D, MW-24, MW-25, MW-42, and MW-45. Monthly system checks should also be conducted during the next quarter to monitor the rate of hydrogen consumption of the HiSOC delivery system. Copies of this report have been mailed to the Guilford County Department of Environmental Health in Greensboro, North Carolina and the UIC Program in Raleigh, North Carolina. TRIGON I KLEINFELDER, INC. Page 5 TABLES Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trigon I Klemfelder Project No 97746 TABLE 1: GROUNDWATER ELEVATION DATA Well ID Total Depth (feet TOC) TOC Elevation (feet) Date Water Level Measured Static Water Level (feet TOC) Groundwater Elevation feet MW-7 29.9 861.19 01/05/09 6.14 855.05 MW-10 33.6 860.36 01/05/09 8.40 851.96 MW-11 25.1 859.26 01/05/09 13.61 845.65 MW-12 16.8 851.50 01/05/09 7.54 843.96 MW-12D 27.0 851.06 01/05/09 8.39 842.67 MW-13 24.2 861.29 01/05/09 14.23 847.06 MW-13D 39.4 860.40 01/05/09 13.84 846.56 MW-14 24.8 859.32 01/05/09 18.80 840.52 MW-14D 41.0 859.26 01/05/09 19.86 839.40 MW-15 25.2 857.71 01/05/09 12.76 844.95 MW-16 35.2 863.60 01/05/09 28.48 835.12 MW-23D 57.1 860.90 01/05/09 15.38 845.52 MW-24 58.8 858.81 01/05/09 23.78 835.03 MW-25 168.9 861.47 01/05/09 23.46 838.01 MW-27 44.0 862.74 01/05/09 14.30 848.44 MW-28 23.8 861.54 01/05/09 8.15 853.39 MW-29 18.8 861.13 01/05/09 14.90 846.23 MW-30 73.4 862.28 01/05/09 17.79 844.49 MW-31 19.0 861.73 01/05/09 10.31 851.42 MW-32 19.6 861.76 01/05/09 8.56 853.20 MW-33 21.0 861.77 01/05/09 15.09 846.68 MW-34 21.0 860.45 01/05/09 well flooded --- MW-40 29.7 860.62 01/05/09 9.32 851.30 MW-41 20.3 860.52 01/05/09 8.70 851.82 MW-42 35.0 865.32 01/05/09 30.28 835.04 MW-43D 53.0 865.47 01/05/09 30.50 834.97 MW-44 28.5 NM --- --- --- MW-45 36.2 861.79 01/05/09 27.96 833.83 Notes: feet TOC = feet below top of well casing NM = Not measured TRIGON I KLEINFELDER, INC. Page 1 of 1 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trigon I Kleinfelder Project No. 97746 TABLE 2: AQUIFER CHARACTERISTICS FIELD ANALYSIS SUMMARY Monitoring Well Sample P Date Temperature � °C') PH Conductivity s (mS/cm) DissolvedRedox Oxygen m /L (m� Preferred Conditions > 200C 5<pH<9 --- <0.5 mg/L <50 mV MW-7 01/05/09 18.70 7.88 0.250 3.48 -57.2 MW-11 01/05/09 18.94 6.14 0.361 5-6 141.5 MW-13 01/05/09 20.81 6.51 0.432 6.42 183.5 MW-13D 01/05/09 18.71 6.31 0.449 3.18 145.6 MW-14 01/05/09 16.95 6.51 0.155 8.3 231.4 MW-23D 01/05/09 17.99 8.49 0,555 3-5 -665.5 MW-24 01/05/09 16.41 7.55 0.001 11.4 -42.3 MW-25 01/05/09 15.56 8.20 0.252 4-6 -46.6 MW-42 01/05/09 15.29 7.08 0.007 10.89 342.8 MW-45 01/05/09 14.43 7.43 0,504 7.76 191.8 Notes: Redox = oxidation-reduction potential °C = degrees Celsius mS/cm3 = millisiemens per cubic centimeter mg/L = milligrams per liter, analogous to parts per million mV = millivolts Conductivity is measured for consistency in groundwater sample collection. TRIGON I KLEINFELDER , INC. 1 of 1 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 3: SUMMARY OF GROUNDWATER SAMPLE RESULTS February 4, 2009 Trigon I Kleinfelder Project No. 97746 Parameter NCGS 2L Standard Analytic I Results Sample ID MW-7 I MW-11 MW-13 MW-13D MW-14 MW-23D MW-24 MW-25 MW-42 MW-45 Collection Date 01/05/09 1 01/05/09 01/05/09 01/05/09 01/05/09 01/05/09 01/05/09 01/05/09 01/05/09 01/05/09 Volatile Organic Compounds by EPA Method 6011602 (µg/l) Tetrachloroethene 0.7 BDL 2.7 BDL BDL 29.9 BDL 1,610 22.9 5.3 1.4 Trichloroethene 2.8 BDL 1.6 BDL BDL BDL BDL 78.4 6.5 BDL 1.2 cis-1,2-Dichloroethene 70 798 2.6 68.7 17.4 BDL 15.3 517 46.6 BDL BDL 1, 1 -Dichloroethene 7 BDL BDL BDL BDL BDL BDL BDL 1.1 BDL BDL Vinyl Chloride 0.015 BDL BDL BDL 4.2 BDL BDL BDL BDL BDL BDL 1,1-Dichloroethane 70 BDL BDL BDL BDL BDT, BDL BI_]1_ 1.1 BDL BDL Total Chlorinated Hydrocarbons 798 7 69 22 3U 15 2,205 78 5 3 Benzene 1 BDL BDL 3.2 BDL BDL BDL 280 BDL BDL BDL Eth (benzene 550 643 BDL BDL BDL BDL BDL BDL BDL BDL BDL Total X lenes 530 598 BDL BDL BDL BDL BDL BDL BDL BDL BDL MTBE 200 BDL 1.1 5.2 16.3 BDL 37.6 70.9 4.8 BDL BDL Diisopropyl ether 70 BDL BDL BDL 1.1 BDL BDL 116 6.2 BDL BDL Naphthalene 21 308 BDL BDL BDL BDL BDL BDL BDL BDL BDL Total Petroleum Hydrocarbons 1,549 1 8 17 0 38 467 11 0 0 Total VOCs J 2,347 1 8 77 1 39 30 1 53 1 2,672 1 89 1 5 3 Notes: NCGS 2L Standard = North Carolina Groundwater Standard BDL = Below Detection Limits µg/l = Micrograms per liter, analogous to parts per billion BOLD = Concentration exceeds the NCGS 2L Standard MTBE = Methyl-tert-butyl ether TRIGON I KLEINFELDER, INC. I of 1 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trigon I Kleinfelder Project No 97746 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTSI Sample ID Chlorinated Hydrocarbons Total Chlorinated Hydrocarbons Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCs Collection Date Tetrachloroethene Trichloroethene cis-1,2-Dichloroethene l,l-Dichloroethene Vinyl Chloride I,1-Dichloroethane 1,2-Dichloroethane trans-1,2- Dichloroethane I,l,l-Trichloroethane Benzene Toluene Ethylbenzene I Total Xylenes I MTBE I Diisopropyl ether I Naphthalene I NCGS 2L Sid. 0.7 2.8 70 7 0.015 70 0.38 1 100 200 1 1,000 550 1 530 L200 70 1 21 MW-7 09/27/90 790 190 BDL BDL BDL BDL BDL BDL 59 12039 650 5,300 1,500 5,700 BDL BDL BDL 13,150 14,199 01/14/92 BDL 360 BDL BDL BDL BDL BDL BDL BDL 360 490 3,900 2,100 71100 BDL BDL BDL 13,580 13,940 03/11/98 BDL BDL BDL 354 BDL BDL BDL BDL 238 592 468 9,920 2,200 8,990 BDL BDL BDL 20,578 21,170 05/25/99 BDL BDL BDL 723 BDL BDL BDL BDL 347 1,070 253 2,280 2,290 10,800 BDL BDL BDL 15,623 16,693 04/22/03 BDL BDL BDL BDL BDL BDL BDL BDL 88 88 BDL 220 2,400 5,700 BDL 60 BDL 8,380 8,469 06/30/04 BDL BDL 2,300 BDL BDL BDL BDL BDL BDL 2,300 BDL 110 1,800 3,800 BDL BDL 520 6,230 8,530 08/16/05 BDL BDL 2,100 BDL BDL BDL BDL BDL BDL 2,100 BDL BDL 1,600 3,020 BDL BDL 520 5,140 7,240 08/25/06 BDL BDL 2,000 14 BDL BDL BDL 1.5 14 2,030 1.7 1 23 370 390 11 1 3.3 1 82 11 971 2,901 12/14/06 3.6 4 2,100 570 BDL 15 BDL 5.1 13 2,711 4.1 39 1,300 1,660 BDL BDL 440 3,443 6,154 06/05/08 BDL BDL 1,750 BDL BDL BDL BDL BDL BDL 1,750 BDL BDL 1,040 1,280 BDL BDL 401 2,721 4,471 09/04/09 BDL BDL 1,190 BDL BDL BDL BDL BDL BDL 1,190 BDL BDL 788 873 BDL BDL 301 1,962 3,152 01/05/09 BDL BDL 798 BDL BDL BDL BDL BDL BDL 798 BDL BDL 643 598 BDL BDL 308 1,549 2,347 MW-8 (abandoned) 09/27/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL 1 BDL BDL BDL 1 1 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/15/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 MW-9 (abandoned) 09/27/90 10 2 BDL BDL BDL BDL BDL BDL BDL 12 2 BDL BDL BDL BDL BDL BDL 2 14 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/15/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 MW-10 09/27/90 76 140 BDL BDL BDL BDL BDL BDL 140 356 2,900 66 BDL 670 BDL BDL BDL 3,636 3,992 01/14/92 BDL- 78 BDL 120 BDL BDL BDL BDL BDL 199 2,900 BDL BDL 120 BDL BDL BDL 3,020 3,218 03/11/98 - BDL BDL BDL 13.9 BDL BDL BDL BDL BDL 14 234 BDL BDL BDL BDL BDL BDL 234 249 05/26/99 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 36 BDL BDL BDL BDL BDL BDL 36 36 10/10/02 5.9 2.3 BDL 4.4 BDL BDL BDL BDL 7.3 20 220 8.5 16 71 2,200 16 BDL 2,532 2,551 04/22/03 3.2 L3 BDL BDL BDL BDL BDL BDL 2.6 7 47 BDL BDL BDL 1,100 2.9 BDL 1,150 1,157 06/30/04 BDL BDL L B BDL BDDL B 8 232 BDDL 2.8 5D.8L 770 29 L DL 803 812 L DL BD DL D BDLL BOB/16/OS 680 BE 723 723L 08/24/06 BDL BDL 3 BDL BDL BDL BDL BDL BDL 3 8.1 1 BDL BDL BDL 1 360 1 4.3 1 BDL-7t 372 375 MW-11 06/30/04 2.1 3 14 BDL BDL BDL BDL BDL BDL 7 BDL BDL BDL BDL 4.1 BDL BDL 4 11 08/15/05 5 3.6 9.7 BDL BDL BDL BDL BDL BDL 18 BDL BDL BDL BDL 2.2 BDL BDL 2 21 08/24/06 4.9 2.5 5.2 BDL BDL BDL BDL BDL BDL 13 BDL BDL BDL BDL 4A BDL BDL 4 17 06/05/09 6.8 L5 5.0 BDL BDL BDL BDL BDL BDL 13 BDL BDL BDL BDL BDL BDL BDL 0 13 09/04/09 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/05/09 2.7 1.6 2.6 BDL BDL BDL BDL BDL BDL 7 BDL BDL BDL BDL I BDL BDL 1 8 NM-12 09/27/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 03/11/99 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/26/99 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/30/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 09/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 08/24/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 NM-12D 09/27/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 03/11/98 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/26/99 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/30/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 08/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 08/24/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 Notes: All units measured in µg/L BDL - Below Detection Limits NCGS 2L St& - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-tert butyl ether TRIGON I KLEINFELDER, INC. 1 of 4 Ms Beth Money, Cnlbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trigon I Klemfelder Project No 97746 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS❑ Sample ID Chlorinated Hydrocarbons Hydrocarbon Total Chlorinated Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCs Collection Date Tetiachloroethene 7richloroethene cis-1,2-Dichloroethene l,l-Dichloroethene Vinyl Chloride ],I-Dichloroethane 1,2-Dichloroethane trans-1,2- Dichloroethane l,l,l-Tnchloroe[hane Benzine Toluene Ethylbenzaie Total Xylenes MTBE Diisopropyl ether Naphthalene NCGS 2L Sid 0.7 2.8 70 17 0.015 70 0.38 1 100 200 1 1 1,000 550 530 1 200 70 21 MW-13 09/26/90 2 BDL BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 01/14/92 130 36 BDL BDL BDL BDL BDL BDL BDL 166 BDL BDL BDL BDL BDL BDL BDL 0 166 05/15/92 130 20 BDL BDL BDL BDL BDL BDL BDL 150 BDL BDL BDL BDL BDL BDL BDL 0 150 03/11/98 2.5 C7 BDL BDL BDL BDL BDL BDL BDL 7 BDL BDL BDL BDL BDL BDL BDL 0 7 05/26/99 4.2 15 BDL BDL BDL BDL BDL BDL BDL 19 BDL BDL BDL BDL BDL BDL BDL 0 19 06/30/04 BDL 6.5 140 BDL BDL BDL BDL BDL BDL 147 BDL BDL BDL BDL 13 BDL BDL 13 160 08/I5/05 BDL BDL 110 BDL BDL BDL BDL BDL BDL 110 BDL BDL BDL BDL BDL BDL BDL 0 110 08/24/06 BDL 1 2.9 1 110 BDL BDL BDL BDL I 1 BDL 114 BDL BDL BDL BDL 54 BDL BDL 5 119 06/05/008 BDL BDL 94.7 BDL BDL BDL BDL BDL BDL 95 6.4 BDL BDL BDL BDL BDL BDL 6 101 09/04/08 BDL BDL 679 BDL BDL BDL BDL BDL BDL 68 BDL BDL BDL BDL BDL BDL BDL 0 68 01/05/09 BDL BDL 687 BDL BDL BDL BDL BDL BDL 69 3.2 BDL BDL BDL 5.2 BDL BDL 8 77 MW-13D 06/30/04 BDL BDL 18 BDL 1.5 BDL BDL BDL BDL 20 1.1 1 BDL BDL BDL 26 Ll BDL 28 48 08/15/05 BDL BDL 37 BDL 1.4 BDL BDL BDL BDL 38 BDL BDL BDL BDL 20 1.3 BDL 21 60 08/24/06 BDL BDL 30 BDL 13 BDL BDL BDL BDL 31 BDL BDL BDL BDL 19 BDL BDL 19 50 06/05/08 BDL BDL 21.6 BDL 3.2 BDL BDL BDL BDL 25 BDL BDL 3.0 36 125 1.7 BDL 21 46 09/04/08 BDL BDL 15.2 BDL 3.1 BDL BDL BDL BDL IS BDL BDL BDL BDL 17.6 BDL BDL 18 36 01/05/09 BDL BDL 17.4 BDL 4.2 BDL BDL BDL BDL 22 BDL BDL BDL BDL 16.3 1.1 BDL 17 39 MW-14 09/26/90 1,300 BDL BDL BDL BDL BDL BDL BDL BDL 1,300 BDL BDL BDL BDL BDL BDL BDL 0 1,300 01/14/92 1,400 BDL BDL BDL BDL BDL 180 BDL 100 1680 BDL 60 BDL 100 BDL BDL BDL 160 1,840 03/11/98 8o BDL BDL BDL BDL BDL BDL BDL BDL 80 BDL BDL BDL BDL BDL BDL BDL 0 80 05/25/99 67 BDL BDL BDL BDL BDL BDL BDL BDL 67 BDL BDL BDL BDL BDL BDL BDL 0 67 04/22/03 110 BDL BDL BDL BDL BDL BDL BDL BDL 110 1.1 1.7 BDL 1.9 BDL BDL BDL 5 115 06/30/04 8o BDL BDL BDL BDL BDL BDL BDL BDL 80 BDL BDL BDL BDL BDL BDL BDL 0 80 08/16/05 58 BDL BDL BDL BDL BDL BDL BDL BDL 58 BDL BDL BDL BDL BDL BDL BDL 0 58 08/24/06 46 1 BDL BDL BDL I BDL I BDL I BDL I BDL I BDL 11 46 11 BDL I BDL I BDL I BDL BDL I BDL BDL 11 0 46 06/05/08 54.0 BDL BDL BDL BDL BDL BDL BDL BDL 54 BDL BDL BDL BDL BDL BDL BDL 0 54 09/04/08 50.0 BDL BDL BDL BDL BDL BDL BDL BDL 50 BDL BDL BDL BDL BDL BDL BDL 0 50 01/05/09 1 29.9 BDL BDL BDL BDL BDL BDL BDL BDL 30 BDL BDL BDL BDL BDL BDL BDL11 0 30 MW-14D 09/27/90 110 3 BDL 58 BDL 5 BDL BDL 20 196 45 1 BDL 5 BDL BDL BDL 51 247 01/14/92 200 BDL BDL BDL BDL BDL BDL BDL BDL 200 65 3 BDL BDL BDL BDL BDL 68 268 05/15/92 56 BDL BDL 2.1 BDL BDL BDL BDL BDL 58 4.7 BDL BDL BDL BDL BDL BDL 5 63 09/09/92 210 BDL BDL 23 BDL BDL BDL BDL 13 246 220 BDL BDL BDL BDL BDL BDL 220 466 03/11/98 35.4 BDL BDL 10.6 BDL BDL BDL BDL BDL 46 5.6 BDL BDL BDL BDL BDL BDL 6 52 05/25/99 201 BDL BDL 25 BDL BDL BDL BDL BDL 226 67 BDL BDL BDL BDL BDL BDL 67 293 10/10/02 79 2.8 BDL 4 BDL 4.2 BDL BDL BDL 90 83 BDL BDL BDL 11 29 BDL 48 138 04/22/03 40 BDL BDL 1.2 BDL BDL BDL BDL BDL 41 BDL BDL BDL BDL BDL 1.8 BDL 2 43 06/30/04 29 BDL 3.0 3.5 BDL 2.2 BDL BDL BDL 35 BDL BDL BDL BDL 3.3 BDL BDL 3 38 OS/16/OS 55 1.8 15 33 BDL BDL BDL BDL BDL 75 5.4 BDL BDL BDL 3.2 73 BDL 16 91 08/24/06 47 2 17 1.4 BDL BDL BDL BDL BDL 67 13 BDL BDL BDL 24 6.4 BDL 10 78 MW-IS 09/27/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 03/11/98 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/25/99 4.9 3 BDL BDL BDL BDL BDL BDL BDL 8 BDL BDL BDL BDL BDL BDL BDL 0 8 10/10/02 13 7.8 BDL BDL BDL 1.4 BDL BDL BDL 22 BDL BDL BDL BDL 29 BDL BDL 29 51 04/22/03 11 5 BDL BDL BDL 1.4 BDL BDL BDL 17 BDL BDL BDL BDL 17 BDL BDL 17 34 06/30/04 7.5 3.9 86 BDL BDL BDL BDL BDL BDL 97 BDL BDL BDL BDL 18 BDL BDL 18 115 08/16/05 6.8 2.3 47 BDL BDL BDL BDL BDL BDL 56 BDL BDL BDL BDL 15 BDL BDL 15 71 08/24/06 5.5 5 48 BDL BDL BDL BDL BDL BDL 59 BDL BDL BDL BDL 8 BDL BDL 8 67 Notes: All units measured in µg/L BDL - Below Detection Limits NCGS 2L Std - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-tert butyl ether TRIGON ; KLEINFELDER, INC 2 of4 Ms Beth Money, Cnlbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trigon I Kleinfelder Project No 97746 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS❑ Sample ID Chlorinated Hydrocarbons I Total Chlorinated Hydrocabons Petroleum Hydrocarbons Total Petroleum Hydrocarbons otal VOCs Collection Date Tetrachloroethene Trichloroethene cis-1,2-Dichloroethene I,l-Dichloroethene Vinyl Chloride 1,1-Dichloroethane 1,2-Dichloroethane Hans-1,2- Dichloroethane I,1,1-Trichloroethane �!�m-,e Toluene Ethylbe.ene Total Xylenes MTBE Diisopropyl ether Naphthalene NCGS 2L Std. 07 2.8 70 7 0,015 70 038 100 200 1,000 550 530 200 70 121 MW-16 09/26/90 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 03/11/98 1.9 BDL BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 06/02/99 2.4 BDL BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 10/10/02 22 3.8 BDL 18 BDL BDL BDL BDL BDL 28 BDL BDL BDL BDL BDL BDL BDL 0 28 04/22/03 46 9.6 BDL 36 BDL BDL BDL BDL BDL 58 BDL BDL BDL BDL BDL BDL BDL 0 58 06/30/04 31 7-6 24 27 BDL 1 BDL BDL BDL 66 BDL BDL BDL BDL BDL BDL BDL 0 66 08/I S/O1 30 4.4 BDL I8 BDL BDL BDL BDL BDL 36 BDL BDL BDL BDL BDL 17 BDL 17 53 08/25/06 36 7.4 31 2.9 BDL BDL BDL BDL BDL 7? BDL BDL BDL BDL BDL BDL BDL 0 77 NM-17 (abandoned O1/03/06) 09/26/90 1 BDL BDL BDL BDL BDL BDL BDL BDL I BDL BDL BDL BDL BDL BDL BDL 0 1 O1/14/92 BDL 3 BDL BDL BDL BDL BDL BDL BDL 3 BDL BDL BDL BDL BDL BDL BDL 0 3 03/11/98 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/02/99 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/30/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL 17 BDL BDL 17 17 MW-23D 09/27/90 BDL 2 BDL BDL BDL 5 5 BDL BDL 12 1 BDL BDL BDL BDL BDL BDL 1 13 O1/14/92 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 05/15/92 BDL 2.2 BDL BDL BDL 5.3 BDL BDL BDL 8 45 BDL BDL BDL BDL BDL BDL 45 53 09/09/92 1.8 6.3 BDL 5.4 BDL 6.5 2 BDL BDL 22 63 BDL. BDL BDL BDL BDL BDL 6 28 03/11/98 2.5 2.5 BDL 1.4 BDL 2.9 BDL BDL 4 13 7.1 37 BDL BDL BDL BDL. BDL 11 24 05/26/99 BDL 4.1 BDL 2.4 BDL 5.7 2.6 BDL BDL 15 3.1 BDL BDL BDL BDL BDL BDL 3 18 06/30/04 BDL BDL 200 BDL BDL BDL BDL BDL BDL 200 BDL BDL BDL BDL Soo 12 BDL 512 712 08/15/05 BDL BDL 280 BDL BDL BDL BDL BDL BDL 280 BDL I BDL BDL BDL 310 BDL BDL 310 590 08/24/06 BDL 1.1 340 BDL 1.9 BDL BDL BDL BDL 343 1.9 BDL BDL BDL 3I0 91 BDL 321 664 06/OS/OB BDL BDL 166 BDL BDL BDL BDL BDL BDL ]66 DL BDL 202 23.6 208 BDL BDL 252 418 09/04/08 BDL BDL 5.3 BDL BDL BDL BDL BDL BDL 5 DL j BDL BDL BDL 19.3 BDL BDL 19 25 O1/O5/09 BDL BDL I5.3 BDL BDL BDL BDL BDL BDL IS DL BDL BDL BDL 37-6 BDL BDL 38 53 MW-24 09/27/90 630 28 BDL 60 BDL BDL BDL BDL BDL 718 1,500 80 BDL 80 BDL BDL BDL 1,660 2,378 01/14/92 3,800 I10 BDL 200 BDL BDL 56 BDL 80 4,246 1,300 260 BDL 340 BDL BDL BDL 2,400 6,646 05/15/92 1,400 25 SDL 4.9 13DL BDL SDL BDL SDL 1,430 I'm I$0 BDL BDL BDL BDL BDL 1,980 3,410 09/09/92 2,700 BDL BDL BDL BDL BDL BDL BDL 100 2,800 7,500 150 BDL 150 BDL BDL. BDL 2,800 5,600 03/11/98 1,230 BDL BDL BDL BDL BDL BDL BDL BDL 1,230 1,920 BDL BDL BDL BDL BDL BDL 1,920 3,150 05/25/99 637 BDL BDL BDL BDL BDL BDL BDL BDL 637 1,510 BDL BDL BDL BDL BDL BDL 1,510 2,147 10/10/02 2,000 68 BDL 31 BDL 11 2.5 BDL 4.9 2,117 1,700 16 1 4 27 180 530 BDL 2,454 4,572 04/22/03 640 24 BDL 17 BDL 6.4 BDL BDL 1-8 689 500 64 BDL 1 6.3 81 1 180 BDL 774 1,463 06/30/04 870 BDL 370 BDL BDL BDL BDL BDL BDL 1,240 280 BDL BDL BDL 74 200 BDL 554 1,794 08/16/05 1,300 62 570 BDL BDL BDL BDL BDL BDL 1,932 42D BDL BDL BDL 69 170 BDL 659 2,591 08/24/06 2,200 84 770 15 BDL 64 1.2 12 55 3,083 660 4-8 BDL 10.4 78 160 5.6 919 4,002 06/05/08 1,840 BDL 545 BDL BDL BDL BDL BDL BDL 2,385 210 BDL BDL BDL 55-1 140 BDL 405 2,790 09/04/08 1,430 51.7 349 BDL BDL BDL BDL BDL BDL 1,831 253 BDL BDL BDL BDL 60.3 BDL 313 2,144 O1/05/09 1,610 78.4 517 BDL BDL BDL BDL BDL BDL 2,205 280 BDL BDL BDL 70.9 116 BDL 467 2,672 MW-25 03/11/98 9.9 3.5 BDL BDL BDL BDL BDL BDL BDL 12 BDL BDL BDL BDL BDL BDL BDL 0 12 05/26/99 10 3.6 BDL BDL BDL BDL BDL BDL BDL 14 BDL BDL BDL BDL BDL BDL BDL 0 14 06/30/04 9.1 3.5 9.9 BDL BDL BDL BDL BDL BDL 22 BDL BDL BDL BDL BDL 4.4 BDL 4 26 O8/16/05 17 3.9 31 BDL BDL BDL- BDL BDL BDL 52 BDL BDL BDL BDL 3.6 BDL BDL 4 56 08/25/06 20 4A 51 BDL BDL BDL BDL BDL BDL. 76 BDL BDL BDL BDL 18 4.3 BDL 6 82 06/05/08 11.7 3.2 23 5 BDL BDL BDL BDL BDL BDL 38 BDL BDL 1.3 BDL 22 4.2 BDL 8 46 09/04/08 18.7 5.2 33.2 BDL BDL BDL BDL BDL BDL 57 BDL BDL BDL BDL 3 4.8 BDL 8 65 O1/05/09 1 22.9 6.5 46.6 1.1 BDL 1.1 BDL BDL BDL 78 BDL BDL BDL I BDL 4.8 f 6.2 1 BDL 11 89 MW-26 (abandoned 01/03/06) 07/O1/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 O9/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 NM-27 10/10/02 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 23 2 47 18 2.3 BDL BDL 72 72 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 5.4 27 34 7.9 11 BDL. 17 78 78 08/16/O5 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 12 4.1 180 34 35 BDL 30 264 264 11/O1/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 6.2 24 38 3.1 BDL BDL 16 66 66 Notes: All units measured in µ8/L BDL - Below Detection Limits NCGS 2L Std - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl-tert butyl ether TRIGON I KLEINFELDER, INC. 3 of 4 Ms Beth Money, Cnlbarco 7300 West Friendly Avenue, Greensboro, North Carolina February 4, 2009 Trtgon I Klemfelder Project No 97746 TABLE 4: HISTORICAL SUMMARY OF GROUNDWATER SAMPLE RESULTS❑ Sample ID Chlorinated Hydrocarbons Total Chlorinated Hydrocarbon Petroleum Hydrocarbons Total Petroleum Hydrocarbons Total VOCa Collection Date Tetrachloroethene Tnchloroethene cis-1,2-Dtchloroethene 1,1-Dichloroethene Vmyl Chloride l,l-Dmhloroethane 1,2-Dichloroethane trans-l7- Drchloroethane l,l,l-Tnchloroethane Benzene Toluene Ethylbenzene Total Xylenes MTBE Dusopropyl ether Naphthalene NCGS 2L Std, 0.7 2.8 70 7 0,015 70 0.38 100 200 1 1,000 550 530 200 70 21 MW-28 10/10/02 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 10 2.2 45 22.5 BDL 23 BDL 82 82 07/01/04 1 BDL--F BDL BDL BDL BDL BDL BDL BDL BDL 0 95 51 1,50o 1.065 BDL BDL 480 3,191 3,191 08/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 210 76 2,300 750 BDL BDL 740 4,078 4,078 08/25/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 170 56 2,500 1,200 BDL BDL 800 4,726 4,726 12/14/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 100 BDL 2,500 530 BDL BDL 940 4,070 4,070 MW-29 07/01/04 23 BDL 280 BDL BDL BDL BDL BDL BDL 303 BDL BDL 21 BDL BDL BDL BDL 21 324 08/15/05 39 4.2 29 BDL BDL BDL BDL BDL BDL 72 BDL BDL BDL BDL BDL BDL BDL 0 72 08/25/06 5 2.2 38 BDL BDL BDL BDL BDL BDL 45 BDL BDL BDL BDL BDL BDL BDL 0 45 NM-30 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL 2,200 BDL BDL 2,200 2,200 08/16/05 BDL BDL 200 43 77 BDL BDL BDL BDL 320 74 BDL 58 BDL 510 BDL BDL 642 962 08/25/06 BDL BDL 23 2.5 16 BDL BDL BDL BDL 42 23 BDL 2.6 2 1,500 13 BDL 1,541 1,582 MW-31 10/10/02 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL 320 2AN 7,900 BDL BDL BDL 10,820 10,920 04/22/03 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL 310 I,000 4,600 BDL BDL BDL 6,710 6,710 07/01/04 BDL BDL 53 BDL BDL BDL BDL BDL BDL 53 IS 84 5" 1,360 BDL BDL 400 2,452 2,505 08/15/05 BDL BDL 48 BDL BDL BDL BDL BDL BDL 46 BDL 67 1,100 1,490 BDL BDL 750 3,407 3,455 11/01/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL 1,700 390 BDL BDL 720 2,810 2,810 MW-32 07/01/04 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL 290 BDL BDL 290 290 08/15/05 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL I80 BDL BDL 180 180 08/25/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 1,400 280 190 600 I51000 32 160 17,662 17,662 1 ]/Ol/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 1,400 320 340 900 20,000 BDL BDL 22,960 22,960 12/14/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 11 1,500 1 3.700 1,700 3,000 1 16,000 BDL I,100 32,000 32,000 MW-33 10/70/02 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/30/04 BDL BDL 1.6 BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 08/15/05 BDL BDL 5.6 BDL BDL BDL BDL BDL BDL 6 BDL BDL BDL BDL BDL BDL BDL 0 6 08/25/06 BDL BDL 5.7 BDL BDL BDL BDL BDL BDL 6 BDL BDL BDL BDL BDL BDL BDL 0 6 MW-34 04/22/03 BDL 100 BDL 15 BDL 7.2 BDL BDL BDL 122 BDL BDL BDL BDL BDL BDL BDL 0 122 07/01/04 BDL 130 63 6.3 BDL 7.4 BDL BDL BDL 207 BDL BDL BDL BDL BDL BDL BDL 0 207 08/16/05 BDL 90 37 BDL BDL BDL BDL BDL BDL 127 BDL BDL BDL. BDL BDL BDL BDL 0 127 08/25/06 BDL 59 24 48 BDL 2.3 BDL BDL BDL 90 BDL BDL BDL BDL BDL BDL BDL 0 90 MW-40 11/01/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 250 230 290 552 BDL BDL 130 1,442 1,442 NM-41 04/22/03 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 7,200 6,600 2,400 10,800 BDL BDL BDL 27,000 27,000 BDL BDDL BD D DL BD BD BDL 0 7,000 ,6 2,600 3,7,300 DL 532007/O/0 7700 ,790 30,790 / BLBDL L BDL B BDL DLS 9 BDL 20 78 510OS/16O 23,510 08/24/06 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 1 3,100 3,000 1,000 2,900 BDL 6A 16 10,022 10,022 NM-42 Ol/10/06 36.0 BDL 75 6.] BDL 1.6 BDL BDL BDL 51 BDL BDL BDL BDL BDL BDL 3.2 3 54 08/25/06 27.0 BDL 47 3.5 BDL L5 BDL BDL BDL 37 BDL BDL BDL BDL BDL BDL BDL 0 37 06/OS/OB 5.3 BDL BDL BDL BDL BDL BDL BDL BDL 5 BDL BDL BDL BDL BDL BDL BDL 0 5 09/04/08 5.7 BDL BDL BDL BDL BDL BDL BDL BDL 6 BDL BDL BDL BDL BDL BDL BDL 0 6 01/05/09 5.3 BDL BDL BDL BDL BDL BDL BDL BDL 5 BDL BDL BDL BDL BDL BDL BDL 0 5 MWA3D 01/10/06 390 12A 110 42.0 BDL 6.8 BDL BDL BDL 561 4.9 BDL BDL BDL 360 68.0 BDL 109 670 NM-44 04/11/07 BDL 2.1 BDL BDL BDL BDL BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL 0 2 MW-45 09/13/07 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 06/05/08 1.2 BDL BDL BDL BDL BDL BDL BDL BDL I BDL BDL BDL BDL BDL BDL BDL 0 1 06/05/08 1.2 BDL BDL BDL BDL BDL BDL BDL BDL 1 BDL BDL BDL BDL BDL BDL BDL 0 1 09/04/08 BDL BDL BDL BDL BDL BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL 0 0 01/05/09 1.4 L2 BDL BDL BDL BDL BDL BDL BDL 3 BDL BDL BDL BDL BDL BDL BDL 0 3 Notes: All units measured in µg/L BDL - Below Detection Limits NCGS 2L Std - North Carolina Groundwater Standard BOLD - Concentration exceeds the 2L Groundwater Quality Standard MTBE - Methyl -ten butyl ether TRIGON I KLEINFELDER, INC 4 of 4 Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 5: ESTIMATED DISSOLVED HYDROGEN CONCENTRATIONS AT INJECTION WELLS February 4,2009 Trigon I Kleinfelder Project No. 97746 Well ID Total Depth (feet TOC) TOC Elevation (feet) Bottom Elevation (feet) Date Water Level Checked Static Water Level (feet TOC) Groundwater Elevation (feet) Depth of Water (feet) Estimated Dissolved Hydrogen Concentration (Ppm) MW-7 29.9 861.19 831.29 01/05/09 6.14 855.05 23.76 2.7 MW-10 33.6 860.36 826.76 01/05/09 8.40 851.96 25.20 2.8 MW-14D 41.0 859.26 818.26 01/05/09 19.86 839.40 21.14 2.6 MW-15 25.2 857.71 832.51 01/05/09 12.76 844.95 12.44 2.2 MW-16 35.2 863.60 828.40 01/05/09 28.48 835.12 6.72 L9 MW-23D 57.1 _ 860.90 803.80 01/05/09 15.38 845.52 41.72 3.6 MW-24 58.8 858.81 800.01 01/05/09 23.78 835.03 35.02 3.3 MW-29 18.8 861.13 842.33 01/05/09 14.90 846.23 3.90 1.8 MW-34 21.0 860.45 839.45 01/05/09 well flooded --- --- --- MW-43D 53.0 865.47 812.47 01/05/09 30.50 834.97 22.50 2.7 Notes: feet TOC = feet below top of well casing ppm = parts per million Hydrogen concentrations are estimated based on a saturated hydrogen content of 1.6 ppm per atmosphere. TRIGON I KLEINFELDER, INC. Page 1 of I Ms. Beth Money, Gilbarco 7300 West Friendly Avenue, Greensboro, North Carolina TABLE 6: ESTIMATED HYDROGEN CONSUMPTION February 4, 2009 Trigon I Klemfelder Project No 97746 Injection Well ID Date Hydrogen Cylinder Installed Original Cylinder Pressure (psi) Date Water Level and Cylinder Pressure Recorded Cylinder Pressure on 1/5/09 Estimated Volume of Hydrogen Remaining (cubic feet) Days Elapsed Since Cylinder Installation Hydrogen Use per Day - Since Installation (psi/day) Estimated Date Cylinder Must be Changed Based on Pressure MW-7 11/11/08 1,900 01/05/09 200 20 55 30.9 01/08/09 MW-10 09/04/08 2,100 01/05/09 1400 127 123 5.7 08/21/09 MW-14D 11/11/08 1900 01/05/09 700 70 55 21.8 02/01/09 MW-15 09/24/08 2,000 01/05/09 1400 134 103 5.8 08/16/09 MW-16 11/11/08 1,900 01/05/09 1100 111 55 14.5 03/14/09 MW-23D 09/24/08 1900 01/05/09 800 80 103 10.7 03/11/09 MW-24 1.1/11/08 1950 01/05/09 1100 108 55 15.5 03/10/09 MW-29 09/24/08 2,000 01/05/09 900 86 103 10.7 03/20/09 MW-34 11/11/08 2,000 01/05/09 700 67 55 23.6 01/30/09 MW-43D 11/11/08 1,900 01/05/09 1200 121 55 12.7 04/01/09 Notes: psi = pounds per square inch All hydrogen cylinders must be replaced prior to the cylinder pressure falling below 50 psi. TRIGON I KLEINFELDER, INC Page I of I FIGURES j , IT n IST" EM s 'eo, 900 sue, o• ;�_ J �� I �I3M 9O O r f 900GGaAlin ey • I . li 90 • Ga IN e 'e asol ♦ e _ e • • • ' 4• @I'81i11ID 11� ('aI e° • g e i e J :n s ■ i a l FIGURE 1 SITE LOCATION MAP Gilbarco 7300 West Friendly Avenue Greensboro, North Carolina DATE: 1-7-2009 SCALE: 1' - 2 000' NORTH CA 5011A{M 19]1 jPHUT6RLVI {71994M5q$ TOPOORLPHICiti64P-CUaPORDQUADRANGLE PROIECrNO: 97746 Y MW-45 01w MW-42 MW-12D h Y 11 MW-12 MW-14 MW-25 ETA R ATE TANK MW-41 MW-13D Qo 3 MW-11 40 MW-13 MW-40 RW-3 RW-2 MW-28 RW-4 MW-32 Y MW-31 0 T MW-33 NM"-30 MW-27 MW-44 EXISTING PARKING EXISTING PARKING EXISTING BUILDING LEGEND INJECTION WELL LOCATION FIGURE 2 MW-14 MONITORING WELL LOCATION SITE PLAN RW-3 RECOVERY WELL LOCATION [.7A Gilbarco 7300 West Friendly Avenue TRlGON Greensboro, North Carolina i - DATE 1-2-2008 SCALE 1" = 100' GREENSBORO, NORTH CAROLINA DRAWN BY. CWH PROJECT NO: 97746 EXISTING PARKING -$�MW-45 833.83 t 7 �11% 16 935.12 835 940 ssu LEGEND %1H INJECTION WELL LOCATION SH•05 AND GROUNDWATER ELEVATION h MW-14 MONITORING WELL LOCATION Y 840.52 AND GROUNDWATER ELEVATION A RW-3 RECOVERY WELL LOCATION 4400 GROUNDWATER CONTOUR LINE NOTE: GROUNDWATER ELEVATIONS WERE RECORDED JANUARY 5, 2009. MONITORING WELLS MW-13D, MW-23D, AND MW-25 ARE SCREENED BELOW THE WATER TABLE AND WERE NOT USED TO GENERATE THE GROUNDWATER CONTOURS. %I%N ! 11L 834.97 '•115 ? 1 835.0 MW-42 935.04 4 NfW-1 MW-25 840.52 �� 838.01 $39.40 AT1 K4 T MW-41 851.82 MW-40 851.30/ ;ITW-31 85I.4 85; MW-27 � 848.44 EXISTING BUILDING 835 Ball 84d.95 RW MW-12 843.96 SUB ATB MW-12D 942,67 845 851.96 J' NMI-13D 846.56 �W3 5 M!V-11 !NW06 955.05 ��' 845.65 f 847. 1w_ve 845.521 MW 30 844.49 MW-44 MW-33A 846.68 8511 85; EXISTING PARKING EXISTING PARKING LEGEND INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION 30 WITH TOTAL VOCs CONCENTRATION (ug/L) RW-3 RECOVERY WELL LOCATION l fl(10-- "\ TOTAL VOCs ISOCONCENTRATION LINE NOTE: SAMPLES COLLECTED ON JANUARY 5, 2009. 3 2,672 I i MW-14 30 NM-25 A�y 89 TATI 1 ATE TANK -41 ,000 3� RW-3 MW-40 0 B \1N'-7 RW-2 2,347 1, 0 31 MW-28 RW-4�i100 EXISTING BUILDING MW-30 MW44 MW-12D MW-12 39 Imw MW-11 77 \ 8 1 , 53 EXISTING PARKING 73MW-45 MW-42 5 _ ■its BMW-12D \ �� MW-12 30 MW-25 ` SUB ATE *--%7 ` TANK �. 41 i►1 lop MW-13 MW-4 22 N[W-13 X � RW-3 ■ I N 69 ' A► -40 MW it 15 B RW-2 ►I►t 7 7 ►Iki 34 41 MW-28 RWd rFF MW-31 W-32 MW-33 MW-27 MW-30 MW-44 EXISTING PARKING EXISTING LEGEND PARKING EXISTING BUILDING 1Pr ern - INJECTION WELL LOCATION MW-14 MONITORING WELL LOCATION Y 30 WITH TOTAL CHLORINATED HYDROCARBONS CONCENTRATION (ug/L) Q Rw-3 RECOVERY WELL LOCATION I.11(111� TOTAL CHLORINATED HYDROCARBONS ISOCONCENTRATION LINE FIGURE 5 NOTE: SAMPLES COLLECTED ON JANUARY 5, 2009. APPENDIX A laceAnalyticalo wxwpaceiabs.com January 20, 2009 Mr. Chris Hay Trigon/Kleinfelder, Inc. 313 Gallimore Dairy Rd Greensboro, NC 27409 RE: Project: GILBARCO Pace Project No.: 9235442 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Mr. Hay: Enclosed are the analytical results for sample(s) received by the laboratory on January 06, 2009. The results relate only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concerning this report, please feel free to contact me. Sincerely, Bonnie McKee bonnie.mckee@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace eerAnalytical Services, Inc.. Page 1 of 20 'CeAmOa* amw:pace/ebacam Project: GILBARCO Pace Project No.: 9235442 Charlotte Certification IDs West Virginia Certification #: 357 Virginia Certification #: 00213 Tennessee Certification M 04010 South Carolina Drinking Water Cart. #: 990060003 South Carolina Certification M 990060001 Pennsylvania Certification #: 68-00784 North Carolina Wastewater Certification M 12 Asheville Certification IDs West Virginia Certification #: 356 Virginia Certification * 00072 Tennessee Certification #: 2980 South Carolina Certification #: 99030001 South Carolina Bioassay Certification M 99030002 Pennsylvania Certification M 68-03578 North Carolina Wastewater Certification #: 40 Eden Certification IDs Virginia Drinking Water Certification M 00424 North Carolina Wastewater Certification M 633 Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7178 CERTIFICATIONS North Carolina Field Services Certification #: 5342 North Carolina Drinking Water Certification #: 37706 New Jersey Certification #: NCO12 Louisiana/LELAP Certification #: 04034 Kentucky UST Certification #: 84 Florida/NELAP Certification #: E87627 Connecticut Certification #: PH-0104 North Carolina Drinking Water Certification #: 37712 North Carolina Bioassay Certification #: 9 New Jersey Certification #: NCO11 Massachusetts Certification #: M-NC030 Louisiana/LELAP Certification #: 03095 Florida/NELAP Certification #: E87648 Connecticut Certification #: PH-0106 North Carolina Drinking Water Certification M 37738 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 REPORT OF LABORATORY ANALYSIS Page 2 of 20 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ical Pace Analytical 2225 Riverside Dr. Pace9800 K ntcey Ave. rvSuite I100 laceAnalytical www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 SAMPLE SUMMARY Project: GILBARCO Pace Project No.: 9235442 Lab ID Sample ID Matrix Date Collected Date Received 9235442001 MW-13 Water 01/05/0910:29 01/06/0914:55 9235442002 MW-13D Water 01/05/0910:51 01/06/0914:55 9235442003 MW-23D Water 01/05/0912:16 01/06/0914:55 9235442004 MW-11 Water 01/05/09 12:51 01/06/09 14:55 9235442005 MW-14 Water 01/05/0913:28 01/06/0914:55 9235442006 MW-24 Water 01/05/0914:22 01/06/0914:55 9235442007 MW-25 Water 01/05/0914:27 01/06/0914:55 9235442008 MW-42 Water 01/05/0915:04 01/06/0914:55 9235442009 MW-45 Water 01/05/0915:29 01/06/0914:55 9235442010 MW-7 Water 01/05/0916:27 01/06/0914:55 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace �Analytical Services, Inc.. Page 3 of 20 Pace Analytical Services, Inc. Pace Analytical Services, Inc. _ aceAnalytical ® 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 i SAMPLE ANALYTE COUNT Project: GILBARCO Pace Project No.: 9235442 Lab ID Sample ID Method Analysts Analytes Reported 9235442001 MW-13 EPA 601 /602 PPM 40 9235442002 MW-13D EPA 601 /602 PPM 40 9235442003 MW-23D EPA601/602 PPM 40 9235442004 MW-11 EPA601/602 PPM 40 9235442005 MW-14 EPA 601 /602 PPM 40 9235442006 MW-24 EPA 601 /602 PPM 40 9235442007 MW-25 EPA 601 /602 PPM 40 9235442008 MW-42 EPA 601/602 PPM 40 9235442009 MW-45 EPA601/602 PPM 40 9235442010 MW-7 EPA601/602 PPM 40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. uL�S. Page 4 of 20 laceAnalytical" wwwpacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCO Pace Project No.: 9235442 Sample: MW-13 Parameters 601/602 Volatiles Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1, 1, 1 -Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 1-Chloro-3-fluorobenzene (S) Date: 01/20/2009 05:05 PM ANALYTICAL RESULTS Lab ID: 9235442001 Collected: 01/05/09 10:29 Received: 01/06/09 14:55 Matrix: Water Report Results Units Limit MDL DF Prepared Analyzed CAS No. Qual Analytical Method: EPA601/602 3.2 ug/L 2.5 2.5 2.5 01/14/09 16:41 71-43-2 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-27-4 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-25-2 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 74-83-9 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 56-23-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 108-90-7 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-00-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 67-66-3 ND ug/L 5.0 5.0 2.5 01/14/09 16:41 74-87-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 124-48-1 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 106-93-4 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 95-50-1 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 541-73-1 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 106-46-7 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-71-8 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-34-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 107-06-2 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-35-4 68.7 ug/L 2.5 2.5 2.5 01/14/09 16:41 156-59-2 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 156-60-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 78-87-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 10061-01-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 10061-02-6 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 108-20-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 100-41-4 ND ug/L 5.0 5.0 2.5 01/14/09 16:41 75-09-2 5.2 ug/L 2.5 2.5 2.5 01/14/09 16:41 1634-04-4 ND ug/L 5.0 5.0 2.5 01/14/09 16:41 91-20-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 79-34-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 127-18-4 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 108-88-3 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 71-55-6 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 79-00-5 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 79-01-6 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-69-4 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 75-01-4 ND ug/L 5.0 5.0 2.5 01/14/09 16:41 1330-20-7 ND ug/L 5.0 5.0 2.5 01/14/09 16:41 1330-20-7 ND ug/L 2.5 2.5 2.5 01/14/09 16:41 95-47-6 110 % 65-137 2.5 01/14/09 16:41 625-98-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ;r Page 5 of 20 aceAnalytical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW-13D Lab ID: 9236442002 Collected: 01;0.5/09 10:51 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 17:23 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 17:22 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 17:22 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 17:22 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 17:22 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 17:22 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 17:22 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 17:22 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 17:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 17:22 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 17:22 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 17:22 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 17:22 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 17:22 75-71-8 1, 1 -Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 107-06-2 1, 1 -Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 17:22 75-35-4 cis-1,2-Dichloroethene 17.4 ug/L 1.0 1.0 1 01/14/09 17:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 17:22 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 17:22 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 17:22 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 17:22 10061-02-6 Diisopropyl ether 1.1 ug/L 1.0 1.0 1 01/14/09 17:23 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 17:23 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 17:22 75-09-2 Methyl-tert-butyl ether 16.3 ug/L 1.0 1.0 1 01/14/09 17:23 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 17:23 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 79-34-5 Tetrachloroethene ND ug/L 1.0 1.0 1 01/14/09 17:22 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 17:23 108-88-3 1, 1, 1 -Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 17:22 79-00-5 Trichloroethene ND ug/L 1.0 1.0 1 01/14/09 17:22 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 17:22 75-69-4 Vinyl chloride 4.2 ug/L 1.0 1.0 1 01/14/09 17:22 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 17:23 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 17:23 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 17:23 95-47-6 1-Chloro-3-fluorobenzene (S) 101 % 65-137 1 01/14/09 17:22 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 6 of 20 lace Anal ical www.pacelabacom Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW 23D Lab ID: 9235442003 Collected: 01/05/09 12:16 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 18:04 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 18:04 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 18:04 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 18:04 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 18:04 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:04 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 18:04 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 18:04 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 18:04 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 18:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 18:04 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:04 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:04 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01114/0918:04 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 18:04 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01114/0918:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 18:04 75-35-4 cis-1,2-Dichloroethene 15.3 ug/L 1.0 1.0 1 01/14/09 18:04 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01114/0918:04 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01114/0918:04 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 18:04 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 18:04 10061-02-6 Diisopropyl ether ND ug/L 1.0 1.0 1 01/14/09 18:04 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 18:04 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 18:04 75-09-2 Methyl-tert-butyl ether 37.6 ug/L 1.0 1.0 1 01/14/09 18:04 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01114/0918:04 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 18:04 79-34-5 Tetrachloroethene ND ug/L 1.0 1.0 1 01/14/09 18:04 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 18:04 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:04 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:04 79-00-5 Trichloroethene ND ug/L 1.0 1.0 1 01/14/09 18:04 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 18:04 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 18:04 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 18:04 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 18:04 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 18:04 95-47-6 1-Chloro-3-fluorobenzene (S) 83 % 65-137 1 01/14/09 18:04 625-98-9 Date: 01/20/2009 05:05 PM REPI3RT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 7 of 20 ® aceAnalytical Pace Analytical Services, Inc. 2225 Riverside Dr. _,_ www.pacelabs.com Asheville, NC 28804 (828)254-7176 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-11 Parameters Lab ID: 9235442004 Results Units Collected: Report Limit 01/05/09 12:51 MDL DF Received: 01/06/09 14:55 Matrix: Water Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 18:46 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 18:45 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 18:45 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 18:45 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 18:45 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:45 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 18:45 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 18:45 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 18:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 18:45 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:45 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:45 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 18:45 106-46-7 Dichlorod ifluoromethane ND ug/L 1.0 1.0 1 01/14/09 18:45 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 18:45 75-35-4 cis-1,2-Dichloroethene 2.6 ug/L 1.0 1.0 1 01/14/09 18:45 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 18:45 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 18:45 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 18:45 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 18:45 10061-02-6 Diisopropyl ether ND ug/L 1.0 1.0 1 01/14/09 18:46 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 18:46 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 18:45 75-09-2 Methyl-tert-butyl ether 1.1 ug/L 1.0 1.0 1 01/14/09 18:46 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 18:46 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 79-34-5 Tetrachloroethene 2.7 ug/L 1.0 1.0 1 01/14/09 18:45 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 18:46 108-88-3 1, 1, 1 -Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 18:45 79-00-5 Trichloroethene 1.6 ug/L 1.0 1.0 1 01/14/09 18:45 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 18:45 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 18:45 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 18:46 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 18:46 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 18:46 95-47-6 1-Chloro-3-fluorobe nzene (S) 101 % 65-137 1 01/14/09 18:45 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 8 of 20 ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. _ 2225 Riverside Or 9800 KinceyAve. Suite 100 ace Analytical www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW 14 Lab ID: 9235442005 Collected: 01/05/09 13:28 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6011602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 20:09 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 20:08 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 20:08 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 20:08 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 20:08 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 20:08 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 20:08 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 20:08 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 20:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 20:08 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 20:08 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 20:08 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 20:08 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 20:08 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 20:08 75-35-4 cis- 1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 20:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 20:08 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 20:08 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 20:08 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 20:08 10061-02-6 Diisopropyl ether ND ug/L 1.0 1.0 1 01/14/09 20:09 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 20:09 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 20:08 75-09-2 Methyl-tert-butyl ether ND ug/L 1.0 1.0 1 01/14/09 20:09 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 20:09 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 79-34-5 Tetra chloroethene 29.9 ug/L 1.0 1.0 1 01/14/09 20:08 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 20:09 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 20:08 79-00-5 Trichloroethene ND ug/L 1.0 1.0 1 01/14/09 20:08 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 20:08 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 20:08 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 20:09 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 20:09 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 20:09 95-47-6 1-Chloro-3-flucrobenzene (S) 113 % 65-137 1 01/14/09 20:08 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS Page 9 of 20 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. e1 elai `, �-alc e A na l ical www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW-24 Lab ID: 9235442006 Collected: 01/05/09 14:22 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA601/602 Benzene 280 ug/L 50.0 50.0 50 01/14/09 20:50 71-43-2 Bromodichloromethane ND ug/L 50.0 50.0 50 01/14/09 20:50 75-27-4 Bromoform ND ug/L 50.0 50.0 50 01/14/09 20:50 75-25-2 Bromomethane ND ug/L 50.0 50.0 50 01/14/09 20:50 74-83-9 Carbon tetrachloride ND ug/L 50.0 50.0 50 01/14/09 20:50 56-23-5 Chlorobenzene ND ug/L 50.0 50.0 50 01/14/09 20:50 108-90-7 Chloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 75-00-3 Chloroform ND ug/L 50.0 50.0 50 01/14/09 20:50 67-66-3 Chloromethane ND ug/L 100 100 50 01/14/09 20:50 74-87-3 Dibromochloromethane ND ug/L 50.0 50.0 50 01/14/09 20:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 50.0 50.0 50 01/14/09 20:50 106-93-4 1,2-Dichlorobenzene ND ug/L 50.0 50.0 50 01/14/09 20:50 95-50-1 1,3-Dichlorobenzene ND ug/L 50.0 50.0 50 01/14/09 20:50 541-73-1 1,4-Dichlorobenzene ND ug/L 50.0 50.0 50 01/14/09 20:50 106-46-7 Dichlorodifluoromethane ND ug/L 50.0 50.0 50 01/14/09 20:50 75-71-8 1,1-Dichloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 75-34-3 1,2-Dichloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 107-06-2 1,1-Dichloroethene ND ug/L 50.0 50.0 50 01/14/09 20:50 75-35-4 cis-1,2-Dichloroethene 517 ug/L 50.0 50.0 50 01/14/09 20:50 156-59-2 trans-1,2-Dichloroethene ND ug/L 50.0 50.0 50 01/14/09 20:50 156-60-5 1,2-Dichloropropene ND ug/L 50.0 50.0 50 01/14/09 20:50 78-87-5 cis-1,3-Dichloropropene ND ug/L 50.0 50.0 50 01/14/09 20:50 10061-01-5 trans-1,3-Dichloropropene ND ug/L 50.0 50.0 50 01/14/09 20:50 10061-02-6 Diisopropyl ether 116 ug/L 50.0 50.0 50 01/14/09 20:50 108-20-3 Ethylbenzene ND ug/L 50.0 50.0 50 01/14/09 20:50 100-41-4 Methylene Chloride ND ug/L 100 100 50 01/14/09 20:50 75-09-2 Methyl-tert-butyl ether 70.9 ug/L 50.0 50.0 50 01/14/09 20:50 1634-04-4 Naphthalene ND ug/L 100 100 50 01/14/09 20:50 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 79-34-5 Tetrachloroethene 1610 ug/L 50.0 50.0 50 01/14/09 20:50 127-18-4 Toluene ND ug/L 50.0 50.0 50 01/14/09 20:50 108-88-3 1,1,1-Trichloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 71-55-6 1,1,2-Trichloroethane ND ug/L 50.0 50.0 50 01/14/09 20:50 79-00-5 Trichloroethene 78.4 ug/L 50.0 50.0 50 01/14/09 20:50 79-01-6 Trichlorofluoromethane ND ug/L 50.0 50.0 50 01/14/09 20:50 75-69-4 Vinyl chloride ND ug/L 50.0 50.0 50 01/14/09 20:50 75-01-4 Xylene (Total) ND ug/L 100 100 50 01/14/09 20:50 1330-20-7 m&p-Xylene ND ug/L 100 100 50 01/14/09 20:50 1330-20-7 o-Xylene ND ug/L 50.0 50.0 50 01/14/09 20:50 95-47-6 1-Chloro-3-fluorobenzene (S) 112 % 65-137 50 01/14/09 20:50 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of�Pace +Analytical Services, Inc.. Page 10 of 20 aceAnalytical wwwpavelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW-25 Lab ID: 9235442007 Collected: 01/05/09 14:27 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 22:14 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 22:13 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 22:13 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 22:13 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 22:13 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:13 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 22:13 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 22:13 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 22:13 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 22:13 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 22:13 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:13 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:13 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:13 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 22:13 75-71-8 1,1-Dichloroethane 1.1 ug/L 1.0 1.0 1 01/14/09 22:13 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:13 107-06-2 1,1-Dichloroethene 1.1 ug/L 1.0 1.0 1 01/14/09 22:13 75-35-4 cis-1,2-Dichloroethene 46.6 ug/L 1.0 1.0 1 01/14/09 22:14 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 22:13 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 22:13 78-87-5 cis- 1,3-Dichloroprope ne ND ug/L 1.0 1.0 1 01/14/09 22:13 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 22:13 10061-02-6 Diisopropyl ether 6.2 ug/L 1.0 1.0 1 01/14/09 22:14 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 22:14 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 22:13 75-09-2 Methyl-tert-butyl ether 4.8 ug/L 1.0 1.0 1 01/14/09 22:14 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 22:14 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 22:13 79-34-5 Tetrachloroethene 22.9 ug/L 1.0 1.0 1 01/14/09 22:13 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 22:14 108-88-3 1, 1, 1 -Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:13 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:13 79-00-5 Trichloroethene 6.5 ug/L 1.0 1.0 1 01/14/09 22:13 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 22:13 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 22:13 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 22:14 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 22:14 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 22:14 95-47-6 1-Chloro-3-fluorobenzene (S) 119 % 65-137 1 01/14/09 22:13 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Ji Page 11 of 20 ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. /�aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 wwwpacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 i ANALYTICAL RESULTS Project: GILBARCO Pace Project No.: 9235442 Sample: MW-42 Lab ID: 9236442008 Collected: 01/05/09 15:04 Received: 01/06/09 14:55 Matrix: Water Report Parameters Results Units Limit MD- DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 22:56 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 22:55 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 22:55 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 22:55 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 22:55 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:55 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 22:55 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 22:55 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 22:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 22:55 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:55 95-50-1 1,3-Dichlorobe nzene ND ug/L 1.0 1.0 1 01/14/09 22:55 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 22:55 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 22:55 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 22:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 22:55 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 22:55 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 22:55 78-87-5 cis- 1,3-Dichloroprope ne ND ug/L 1.0 1.0 1 01/14/09 22:55 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 22:55 10061-02-6 Diisopropyl ether ND ug/L 1.0 1.0 1 01/14/09 22:56 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 22:56 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 22:55 75-09-2 Methyl-tert-butyl ether ND ug/L 1.0 1.0 1 01/14/09 22:56 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 22:56 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 79-34-5 Tetrachloroethene 5.3 ug/L 1.0 1.0 1 01/14/09 22:55 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 22:56 108-88-3 1, 1, 1 -Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 22:55 79-00-5 Trichloroethene ND ug/L 1.0 1.0 1 01/14/09 22:55 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 22:55 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 22:55 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 22:56 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 22:56 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 22:56 95-47-6 1-Chloro-3-fluorobenzene (S) 98 % 65-137 1 01/14/09 22:55 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Page 12 of 20 ace Analytical www.pacelabs.com i Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 ANALYTICAL RESULTS (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 Project: GILBARCO Pace Project No.: 9235442 Sample: MW-45 Lab ID: 9235442009 Collected: 01/05/09 15:29 Received: 01/06/09 14:55 Matrix: Water Report (704)875-9092 Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 601/602 Volatiles Analytical Method: EPA 601/602 Benzene ND ug/L 1.0 1.0 1 01/14/09 23:37 71-43-2 Bromodichloromethane ND ug/L 1.0 1.0 1 01/14/09 23:37 75-27-4 Bromoform ND ug/L 1.0 1.0 1 01/14/09 23:37 75-25-2 Bromomethane ND ug/L 1.0 1.0 1 01/14/09 23:37 74-83-9 Carbon tetrachloride ND ug/L 1.0 1.0 1 01/14/09 23:37 56-23-5 Chlorobenzene ND ug/L 1.0 1.0 1 01/14/09 23:37 108-90-7 Chloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 75-00-3 Chloroform ND ug/L 1.0 1.0 1 01/14/09 23:37 67-66-3 Chloromethane ND ug/L 2.0 2.0 1 01/14/09 23:37 74-87-3 Dibromochloromethane ND ug/L 1.0 1.0 1 01/14/09 23:37 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1.0 1 01/14/09 23:37 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 23:37 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 23:37 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1.0 1 01/14/09 23:37 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1.0 1 01/14/09 23:37 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 23:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 23:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1.0 1 01/14/09 23:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1.0 1 01/14/09 23:37 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1.0 1 01/14/09 23:37 10061-01-5 trans-1,3-Dichloroprope ne ND ug/L 1.0 1.0 1 01/14/09 23:37 10061-02-6 Diisopropyl ether ND ug/L 1.0 1.0 1 01/14/09 23:37 108-20-3 Ethylbenzene ND ug/L 1.0 1.0 1 01/14/09 23:37 100-41-4 Methylene Chloride ND ug/L 2.0 2.0 1 01/14/09 23:37 75-09-2 Methyl-tert-butyl ether ND ug/L 1.0 1.0 1 01/14/09 23:37 1634-04-4 Naphthalene ND ug/L 2.0 2.0 1 01/14/09 23:37 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 79-34-5 Tetrachloroethene 1.4 ug/L 1.0 1.0 1 01/14/09 23:37 127-18-4 Toluene ND ug/L 1.0 1.0 1 01/14/09 23:37 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1.0 1 01/14/09 23:37 79-00-5 Trichloroethene 1.2 ug/L 1.0 1.0 1 01/14/09 23:37 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1.0 1 01/14/09 23:37 75-69-4 Vinyl chloride ND ug/L 1.0 1.0 1 01/14/09 23:37 75-01-4 Xylene (Total) ND ug/L 2.0 2.0 1 01/14/09 23:37 1330-20-7 m&p-Xylene ND ug/L 2.0 2.0 1 01/14/09 23:37 1330-20-7 o-Xylene ND ug/L 1.0 1.0 1 01/14/09 23:37 95-47-6 1-Chloro-3-fluorobenzene (S) 108 % 65-137 1 01/14/09 23:37 625-98-9 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS Page 13 of 20 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. ,11'!�aceAnalytical www.paMab&com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCO Pace Project No.: 9235442 Sample: MW-7 Parameters 601/602 Volatiles Benzene Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Dibromochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1, 1 -Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Diisopropyl ether Ethylbenzene Methylene Chloride Methyl-tert-butyl ether Naphthalene 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroeth ane 1,1,2-Trichloroeth ane Trichloroethene Trichlorofluoromethane Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene 1-Chloro-3-fluorobenzene (S) Date: 01/20/2009 05:05 PM ANALYTICAL RESULTS Lab ID: 9235442010 Collected: 01/05/09 16:27 Report Results Units Limit MDL DF Analytical Method: EPA601/602 Received: 01/06/09 14:55 Matrix: Water Prepared Analyzed CAS No. Qual ND ug/L 50.0 50.0 50 01/15/09 01:00 71-43-2 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-27-4 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-25-2 ND ug/L 50.0 50 D 50 01/15/09 01:00 74-83-9 ND ug/L 50.0 50.0 50 01/15/09 01:00 56-23-5 ND ug/L 50.0 50.0 50 01/15/09 01:00 108-90-7 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-00-3 ND ug/L 50.0 50.0 50 01/15/09 01:00 67-66-3 ND ug/L 100 100 50 01/15/09 01:00 74-87-3 ND ug/L 50.0 50.0 50 01/15/09 01:00 124-48-1 ND ug/L 50.0 50.0 50 01/15/09 01:00 106-93-4 ND ug/L 50.0 50.0 50 01/15/09 01:00 95-50-1 ND ug/L 50.0 50.0 50 01/15/09 01:00 541-73-1 ND ug/L 50.0 50.0 50 01/15/09 01:00 106-46-7 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-71-8 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-34-3 ND ug/L 50.0 50.0 50 01/15/09 01:00 107-06-2 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-35-4 798 ug/L 50.0 50.0 50 01/15/09 01:00 156-59-2 ND ug/L 50.0 50.0 50 01/15/09 01:00 156-60-5 ND ug/L 50.0 %0 50 01/15/09 01:00 78-87-5 ND ug/L 50.0 50.0 50 01/15/09 01:00 10061-01-5 ND ug/L 50.0 50.0 50 01/15/09 01:00 10061-02-6 ND ug/L 50.0 50.0 50 01/15/09 01:00 108-20-3 643 ug/L 50.0 50.0 50 01/15/09 01:00 100-41-4 ND ug/L 100 100 50 01/15/09 01:00 75-09-2 ND ug/L 50.0 50.0 50 01/15/09 01:00 1634-04-4 308 ug/L 100 100 50 01/15/09 01:00 91-20-3 ND ug/L 50.0 50.0 50 01/15/09 01:00 79-34-5 ND ug/L 50.0 50.0 50 01/15/09 01:00 127-18-4 ND ug/L 50.0 50.0 50 01/15/09 01:00 108-88-3 ND ug/L 50.0 50.0 50 01/15/09 01:00 71-55-6 ND ug/L 50.0 50.0 50 01/15/09 01:00 79-00-5 ND ug/L 50.0 50.0 50 01/15/09 01:00 79-01-6 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-69-4 ND ug/L 50.0 50.0 50 01/15/09 01:00 75-01-4 598 ug/L 100 100 50 01/15/09 01:00 1330-20-7 598 ug/L 100 100 50 01/15/09 01:00 1330-20-7 ND ug/L 50.0 50.0 50 01/15/09 01:00 95-47-6 96 % 65-137 50 01/15/09 01:00 625-98-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc . Page 14 of 20 laceAnalyfical OD www.pacelabs.com Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 (828)254-7176 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: GILBARCO Pace Project No.: 9235442 QUALITY CONTROL DATA QC Batch. GCV/2826 Analysis Method: EPA601/602 QC Batch Method: EPA601/602 Analysis Description: 601/602 GCV Water Associated Lab Samples: 9235442001, 9235442002, 9235442003, 9235442004, 9235442005, 9235442006, 9235442007, 9235442008, 9235442009,9235442010 METHOD BLANK: 222711 Matrix: Water Associated Lab Samples: 9235442001, 9235442002, 9235442003, 9235442004, 9235442005, 9235442006, 9235442007, 9235442008, 9235442009,9235442010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1-Trichloroethane ug/L ND 1.0 01/14/09 16:00 1,1,2,2-Tetrachloroethane ug/L ND 1.0 01/14/09 16:00 1,1,2-Trichloroethane ug/L ND 1.0 01/14/09 16:00 1,1-Dichloroethane ug/L ND 1.0 01/14/09 16:00 1,1-Dichloroethene ug/L ND 1.0 01/14/09 16:00 1,2-Dibromoethane (EDB) ug/L ND 1.0 01/14/09 16:00 1,2-Dichlorobenzene ug/L ND 1.0 01/14/09 16:00 1,2-Dichloroethane ug/L ND 1.0 01/14/09 16:00 1,2-Dichloropropane ug/L ND 1.0 01/14/09 16:00 1,3-Dichlorobenzene ug/L ND 1.0 01/14/09 16:00 1,4-Dichlorobenzene ug/L ND 1.0 01/14/09 16:00 Benzene ug/L ND 1.0 01/14/09 16:00 Bromodichloromethane ug/L ND 1.0 01/14/09 16:00 Bromoform ug/L ND 1.0 01/14/09 16:00 Bromomethane ug/L ND 1.0 01/14/09 16:00 Carbon tetrachloride ug/L ND 1.0 01/14/09 16:00 Chlorobenzene ug/L ND 1.0 01/14/09 16:00 Chloroethane ug/L ND 1.0 01/14/09 16:00 Chloroform ug/L ND 1.0 01/14/09 16:00 Chloromethane ug/L ND 2.0 01/14/09 16:00 cis-1,2-Dichloroethene ug/L ND 1.0 01/14/09 16:00 cis- 1, 3-Dichloropropen e ug/L ND 1.0 01/14/09 16:00 Dibromochloromethane ug/L ND 1.0 01/14/09 16:00 Dichlorodifluoromethane ug/L ND 1.0 01/14/09 16:00 Diisopropyl ether ug/L ND 1.0 01/14/09 16:00 Ethylbenzene ug/L ND 1.0 01/14/09 16:00 m&p-Xylene ug/L ND 2.0 01/14/09 16:00 Methyl-tert-butyl ether ug/L ND 1.0 01/14/09 16:00 Methylene Chloride ug/L ND 2.0 01/14/09 16:00 Naphthalene ug/L ND 2.0 01/14/09 16:00 o-Xylene ug/L ND 1.0 01/14/09 16:00 Tetrachloroethene ug/L ND 1.0 01/14/09 16:00 Toluene ug/L ND 1.0 01/14/09 16:00 trans-1,2-Dichloroethene ug/L ND 1.0 01/14/09 16:00 trans-1,3-Dichloropropene ug/L ND 1.0 01/14/09 16:00 Trichloroethene ug/L ND 1.0 01/14/09 16:00 Trichlorofluoromethane ug/L ND 1.0 01/14/09 16:00 Vinyl chloride ug/L ND 1.0 01/14/09 16:00 Xylene (Total) ug/L ND 2.0 01/14/09 16:00 1-Chloro-3-fluorobenzene (S) % 117 65-137 01/14/09 16:00 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. UI / l.o�o M1r`3 Page 15 of 20 QQ /� n I ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceN laf l /fi al 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: GILBARCO Pace Project No.: 9235442 LABORATORY CONTROL SAMPLE: 222712 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/L 20 21.1 105 41-138 1,1,2,2-Tetrachloroethane ug/L 20 21.4 107 8-184 1,1,2-Trichloroethane ug/L 20 20.8 104 39-136 1,1-Dichloroethane ug/L 20 19.0 95 47-132 1,1-Dichloroethene ug/L 20 21.6 108 28-167 1,2-Dibromoethane (EDB) ug/L 20 21.2 106 50-150 1,2-Dichlorobenzene ug/L 20 18.5 93 1-208 1,2-Dichloroethane ug/L 20 21.7 109 51-147 1,2-Dichloropropane ug/L 20 18.3 91 44-156 1,3-Dichlorobenzene ug/L 20 20.0 100 7-187 1,4-Dichlorobenzene ug/L 20 20.6 103 42-143 Benzene ug/L 20 21.7 108 39-150 Bromodichloromethane ug/L 20 18.5 92 42-172 Bromoform ug/L 20 22.1 111 13-159 Bromomethane ug/L 20 22.3 112 1-144 Carbon tetrachloride ug/L 20 21.7 108 43-143 Chlorobenzene ug/L 20 20.4 102 38-150 Chloroethane ug/L 20 18.7 94 46-137 Chloroform ug/L 20 19.5 97 49-133 Chloromethane ug/L 20 16.8 84 1-193 cis- 1,2-Dich loroethene ug/L 20 18.6 93 38-155 cis-1,3-Dichloropropene ug/L 20 21.2 106 22-178 Dibromochloromethane ug/L 20 21.6 108 24-191 Dichlorodifluoromethane ug/L 20 15.7 78 48-157 Diisopropyl ether ug/L 20 21.0 105 89-108 Ethylbenzene ug/L 20 20.7 104 32-160 m&p-Xylene ug/L 40 39.0 98 82-115 Methyl-tert-butyl ether ug/L 20 21.6 108 88-110 Methylene Chloride ug/L 20 21.0 105 25-162 Naphthalene ug/L 20 19.9 100 50-150 o-Xylene ug/L 20 19.9 99 91-110 Tetrachloroethene ug/L 20 20.0 100 26-162 Toluene ug/L 20 20.9 105 46-148 trans- 1,2-Dichloroethene ug/L 20 20.5 103 38-155 trans- 1, 3-Dichloropropene ug/L 20 22.0 110 22-178 Trichloroethene ug/L 20 19.7 98 35-146 Trichlorofluoromethane ug/L 20 18.6 93 21-156 Vinyl chloride ug/L 20 18.4 92 28-163 Xylene (Total) ug/L 60 58.9 98 50-150 1-Chloro-3-fluorobenzene(S) % 102 65-137 MATRIX SPIKE SAMPLE: 222809 9235442004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1, 1, 1 -Trichloroethane ug/L ND 20 16.4 82 41-138 1,1,2,2-Tetrachloroethane ug/L ND 20 20.9 105 8-184 1,1,2-Trichloroethane ug/L ND 20 19.0 95 39-136 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS Page 16 of 20 This report shall not be reproduced, except in full, without the written consent of Pace eerAnalytical Services, Inc ® Pace Analytical Services, Inc. Pace Analytical Services, Inc. _ aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 www.pacelabs.com Asheville, NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 i QUALITY CONTROL DATA Project: GILBARCO Pace Project No.: 9235442 MATRIX SPIKE SAMPLE: 222809 9235442004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1-Dichloroethane ug/L ND 20 19.8 99 47-132 1, 1 -Dichloroethene ug/L ND 20 22.3 111 28-167 1,2-Dibromoethane (EDB) ug/L ND 20 21.1 106 50-150 1,2-Dichlorobenzene ug/L ND 20 19.1 95 1-208 1,2-Dichloroethane ug/L ND 20 16.0 80 51-147 1,2-Dichloropropane ug/L ND 20 18.1 91 44-156 1,3-Dichlorobenzene ug/L ND 20 20.7 104 7-187 1,4-Dichlorobenzene ug/L ND 20 20.5 102 42-143 Benzene ug/L ND 20 21.6 108 39-150 Bromodichloromethane ug/L ND 20 18.0 90 42-172 Bromoform ug/L ND 20 21.3 106 13-159 Bromomethane ug/L ND 20 19.1 95 1-144 Carbon tetrachloride ug/L ND 20 21.2 106 43-143 Chlorobenzene ug/L ND 20 18.9 95 38-150 Chloroethane ug/L ND 20 19.0 95 46-137 Chloroform ug/L ND 20 19.4 97 49-133 Chloromethane ug/L ND 20 22.1 110 1-193 cis-1,2-Dichloroethene ug/L 2.6 20 211 93 38-155 cis-1,3-Dichloropropene ug/L ND 20 20.6 103 22-178 Dibromochloromethane ug/L ND 20 20.2 101 24-191 Dichlorodifluoromethane ug/L ND 20 16.1 80 48-157 Diisopropyl ether ug/L ND 20 20.4 102 89-108 Ethylbenzene ug/L ND 20 20.9 104 32-160 m&p-Xylene ug/L ND 40 40.2 100 82-115 Methyl-tert-butyl ether ug/L 1.1 20 20.9 99 88-110 Methylene Chloride ug/L ND 20 20.4 102 25-162 Naphthalene ug/L ND 20 20.3 102 50-150 o-Xylene ug/L ND 20 20.5 103 91-110 Tetrachloroethene ug/L 2.7 20 23.1 102 26-162 Toluene ug/L ND 20 21.4 107 46-148 trans-1,2-Dichloroethene ug/L ND 20 20.9 104 38-155 trans- 1, 3-Dichloropropene ug/L ND 20 20.4 102 22-178 Trichloroethene ug/L 1.6 20 19.9 91 35-146 Trichlorofluoromethane ug/L ND 20 19.9 100 21-156 Vinyl chloride ug/L ND 20 19.9 100 28-163 1-Chloro-3-fluorobenzene (S) % 103 65-137 MATRIX SPIKE SAMPLE: Parameter 222811 Units 9235442009 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1-Trichloroethane ug/L ND 20 22.2 111 41-138 1,1,2,2-Tetrachloroethane ug/L ND 20 20.3 101 8-184 1,1,2-Trichloroethane ug/L ND 20 18.9 95 39-136 1,1-Dichloroethane ug/L ND 20 18.5 93 47-132 1, 1 -Dichloroethene ug/L ND 20 21.0 105 28-167 1,2-Dibromoethane (EDB) ug/L ND 20 21.8 109 50-150 1,2-Dichlorobenzene ug/L ND 20 18.9 94 1-208 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS Page 17 of 20 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc m Pace Analytical Services, Inc. Pace Analytical Services, Inc. aceAnalytical 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 i www.pacefabscom Asheville. NC 28804 Huntersville, NC 28078 (828)254-7176 (704)875-9092 QUALITY CONTROL DATA Project: GILBARCO Pace Project No.: 9235442 MATRIX SPIKE SAMPLE: 222811 9235442009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,2-Dichloroethane ug/L ND 20 22.0 110 51-147 1,2-Dichloropropane ug/L ND 20 18.6 93 44-156 1,3-Dichlorobenzene ug/L ND 20 19.6 98 7-187 1,4-Dichlorobenzene ug/L ND 20 19.1 95 42-143 Benzene ug/L ND 20 21.6 108 39-150 Bromodichloromethane ug/L ND 20 18.5 93 42-172 Bromoform ug/L ND 20 21.6 108 13-159 Bromomethane ug/L ND 20 14.5 72 1-144 Carbon tetrachloride ug/L ND 20 22.7 113 43-143 Chlorobenzene ug/L ND 20 19.2 96 38-150 Chloroethane ug/L ND 20 17.2 86 46-137 Chloroform ug/L ND 20 19.6 98 49-133 Chloromethane ug/L ND 20 22.6 113 1-193 cis- 1,2-Dich loroethene ug/L ND 20 18.2 91 38-155 cis-1,3-Dichloropropene ug/L ND 20 19.0 95 22-178 Dibromochloromethane ug/L ND 20 21.0 105 24-191 Dichlorodifluoromethane ug/L ND 20 14.5 73 48-157 Diisopropyl ether ug/L ND 20 19.6 98 89-108 Ethylbenzene ug/L ND 20 21.1 105 32-160 m&p-Xylene ug/L ND 40 39.9 100 82-115 Methyl-tert-butyl ether ug/L ND 20 19.7 98 88-110 Methylene Chloride ug/L ND 20 19.8 99 25-162 Naphthalene ug/L ND 20 20.1 100 50-150 o-Xylene ug/L ND 20 20.8 104 91-110 Tetrachloroethene ug/L 1.4 20 23.0 108 26-162 Toluene ug/L ND 20 21.3 106 46-148 trans-1,2-Dichloroethene ug/L ND 20 20.6 103 38-155 trans-1,3-Dichloropropene ug/L ND 20 18.7 94 22-178 Trichloroethene ug/L 1.2 20 20.9 98 35-146 Trichlorofluoromethane ug/L ND 20 19.0 95 21-156 Vinyl chloride ug/L ND 20 17.9 90 28-163 1-Chloro-3-fluorobenzene(S) % 100 65-137 SAMPLE DUPLICATE: 222810 Parameter 9235442006 Units Result Dup Result RPD Max RPD Qualifiers 1, 1, 1 -Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,3-Dichlorobenzene ug/L ND ND 30 1,4-Dichlorobe nzene ug/L ND ND 30 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS Page 18 of 20 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc m Pace Analytical Services, Inc. aceAnalytical 2225 Riverside Dr. www.pacWabs.com Asheville, NC 28804 i (828)254-7176 QUALITY CONTROL DATA Project: GILBARCO Pace Project No.: 9235442 SAMPLE DUPLICATE: 222810 Parameter Units 9235442006 Result Dup Result RPD Max RPD Benzene ug/L 280 278 .7 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L 517 505 3 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dichlorodifluoromethane ug/L ND ND 30 Diisopropyl ether ug/L 116 111 4 30 Ethylbenzene ug/L ND ND 30 m&p-Xylene ug/L ND ND 30 Methyl-tert-butyl ether ug/L 70.9 76.0 7 30 Methylene Chloride ug/L ND ND 30 Naphthalene ug/L ND ND 30 o-Xylene ug/L ND ND 30 Tetrachloroethene ug/L 1610 1770 10 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans-1,3-Dichloropropene ug/L ND ND 30 Trichloroethene ug/L 78.4 79.2 1 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1-Chloro-3-fluorobenzene(S) % 112 125 11 Date: 01/20/2009 05:05 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. s� Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Page 19 of 20 laceAnalyficalo www.pacelabsxam Pace Analytical Services, Inc. 2225 Riverside Dr. Asheville, NC 28804 Pace Analytical Services, Inc. 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 QUALIFIERS Project: GILBARCO Pace Project No.: 9235442 DEFINITIONS (828)254-7176 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of the sample aliquot, or moisture content. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. S - Surrogate 1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. Pace Analytical is NELAP accredited. Contact your Pace PM for the current list of accredited analytes. U - Indicates the compound was analyzed for, but not detected. 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I of ' Required Client Information: Required Project Information: Invoice Information: i' Company: T. i 1 i 6-i� Report To: C� n Attention: /r I..�S A G •W►!� 1168274 Address: (3 6 Copy To: Company Name: .�K Wt REGULATORY AGMY AIMUSLIMi �� 27 Address: r NPDES (— GROUND WATER r DRINKING WATER UST r RCRA r OTHER Email To: Purchase Order No.: Pace Quote s Ca Reference: e; Fax: PM 3 Project Name: `/�� �� Pace Project �rLoca oli Manager: r , Requested Due DatelTAT: �y Project Number: Pace Pronle III: ' (YIN) Section D Matrix Codes Required Client Information MATRIX / CODE a o COLLECTED Preservatives Drinking Water DW U Waste Water WW ` U 0 Q COMPOSITE START COMPOSITE ENOMW U Z Product P SavSohd SL SAMPLE ID ,alb uOL O w AR (A MUST / . 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