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Geosyntec'
consultants
Geosyntec Consultants of NC, P.C.
NC License No.: C-3500 and C-295
Memorandum
Date: 10 December 2020
To: The Chemours Company, FC LLC
From: Geosyntec Consultants of NC, P.C.
Subject: Fayetteville Works Monomers/IXM Stormwater
Runoff Volume Calculations for Design Storm
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
919.870.0576
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This memorandum was prepared by Geosyntec Consultants of NC, P.C. (Geosyntec) for The
Chemours Company, FC, LLC (Chemours) to outline the calculations for stormwater runoff
volume draining to the Monomers/IXM stormwater treatment system for the design storm. The
Addendum to Consent Order Paragraph 12 (CO Addendum) specifies (in Paragraph 4) that "By
June 30, 2021, Chemours shall complete installation of, and commence operation of, a system that
captures and treats stormwater from the Monomers/IXM area at the Facility. " The CO Addendum
also specifies that "the Monomers/IXM stormwater capture and treatment system consistently
captures stormwater from the MonomersA" area in rain events up to one (1) inch within a 24-
hour period and removes PFAS compounds (as measured by concentrations of indicator
parameters GenX,, PMPA, and PFMOAA) at a minimum removal efficiency of 99%. "
The CO Addendum requirement to capture the 1-inch, 24-hour rain event, or design storm, is
consistent with North Carolina statewide guidance. The North Carolina Department of
Environmental Quality (NCDEQ) Stormwater Design Manual' (Manual) (Part B — Stormwater
Calculations) specifies one inch as the design storm depth, for all inland counties.
The Monomers/IXM stormwater treatment system ("Treatment System") will receive stormwater
runoff from the Monomers/IXM drainage area via the Cooling Water Channel (CWC) and separate
stormwater-only ditch, through an off-line configuration. Stormwater and Non -Contact Cooling
Water (NCCW) will be separated to create a stormwater-only channel (NCCW will be in a separate
pipe), with a sump and diversion structure located in the southwest corner of the Monomers area.
This is illustrated in Figure 1.
' North Carolina Department of Environmental Quality. North Carolina Department of Environmental Quality
Stormwater Design Manual — Stormwater Calculations. 2017. hLtps:Hdeq.nc.gov/sw-bmp-manual
engineers I scientists I innovators
DocuSign Envelope ID: COBF24FB-5071-4B1C-AE82-E891E3AC3233
Stormwater Treatment System Runoff Volume Calculations
10 December 2020
Page 2
Drainage area to Treatment System
Figure 1. Proposed Treatment System Drainage Area
Diverted stormwater will be pumped via an offline2 pump station into a storage tank that will
function as flow equalization and initial pretreatment (via sedimentation) for the Treatment
System. Following treatment, treated stormwater will be piped back into the Site Conveyance
Network, comingling with NCCW and flowing to Outfall 002. This concept is illustrated in Figure
2. When the capacity of the sump and diversion structure is exceeded during storm events with
large total rainfall depths and/or intensities, stormwater flows will overflow the diversion,
comingling with NCCW, and flow to Outfall 002.
2 An offline pump station pumps stormwater flows that do not exceed the capacity of the Treatment System.
DocuSign Envelope ID: COBF24FB-5071-4B1C-AE82-E891E3AC3233
Stormwater Treatment System Runoff Volume Calculations
10 December 2020
Page 3
NCCW
Untreated
stormwater
(potentially when
rainfall is in
excess aft"
design storm)
Treated
stormwater
Diversion -Storage -Treatment Flow Diagram
storage/
pretreatment
treatment
train
Existing
channel (to
OF 002)
- 4-
�14
1-
Proposed pipe for NCCW
*Not to scale (within existing channel)
pump
station
Stormwater runoff greater
than the design storm
diversion
manhole
stormwater flows are
diverted to the treatment
system; high flows (above
design storm) continue
through the channel
(using a weir or different
elevation outlet pipes
Existing concrete -lined channel
(proposed for stormwater only)
Figure 2. Treatment System Design Schematic
This memorandum outlines the calculations for determining the stormwater runoff volume to the
Treatment System, which is used to size the storage tank, from the design storm cited in the CO
Addendum. It should be noted that the storage tank functions together with the Treatment System
design flowrate, diversion structure(s), and pump station(s) to provide adequate capture and
treatment of stormwater runoff from the drainage area. However, this memorandum only outlines
the calculation of the runoff volume from the design storm, to size the storage tank.
It is also important to note that the Treatment System design flowrate (not discussed herein) will
be provided to treatment system vendors, in addition to PFAS concentration reduction
requirements specified in the CO Addendum, and the vendor will design the Treatment System.
The Simple Method for Runoff Volume, as outlined in Part B of the Manual, was used to determine
the runoff volume from the 1-inch rain event (as specified in the CO Addendum) from the drainage
area. This method first determines the runoff coefficient using the impervious fraction of the
drainage area, as shown in Equation 1.
The impervious fraction was determined using aerial imagery. The drainage area to the Treatment
System was divided into the following classifications: building/rooftop, impervious (i.e.,
pavement), gravel/river rock, and open/undeveloped. Building/rooftop and impervious (i.e.,
pavement) areas were assumed to have an imperviousness of 100%, gravel/river rock areas were
assumed to be 80% impervious, and open/undeveloped areas were assumed to be 11% impervious.
These assumed values of imperviousness, based on land cover, were based on guidance from the
DocuSign Envelope ID: COBF24FB-5071-4B1C-AE82-E891E3AC3233
Stormwater Treatment System Runoff Volume Calculations
10 December 2020
Page 4
Manual (Part B, Stormwater Calculations, Table 1)3 and best professional judgement. The
approximate area of each land cover is shown in Table 1, and the resulting impervious fraction of
the drainage area to the Treatment System was 0.83, or 83% impervious.
Table 1. Land Cover of Drainage Area to Treatment System
Land Cover
Area (acre)
Building/rooftop
2.1
Pavement
2.8
Gravel/river rock
8.2
Open/undeveloped
0.8
Total Area
13.9
Equation 1: Runoff Coefficient
Rv=0.05+0.9x'A
where,
R, is the runoff coefficient (unitless); and
IA is the impervious fraction (unitless).
Rv = 0.05 + 0.9 x 0.83 = 0.80
The design volume was then determined using Equation 2 with a design storm depth of one inch.
The drainage area to the Treatment System was determined to be approximately 13.9 acres, as
illustrated in Figure 1. A portion of the drainage area has secondary containment that captures
rainwater for disposal off -site (i.e., it does not drain to the site conveyance network and then to
Outfall 002). Rainwater in process sumps will continue to be disposed of off -site. Rainwater
captured in non -process sumps is planned to be sent to the Treatment System. To be conservative,
the full 13.9 acre drainage area is assumed for use in subsequent calculations.
3 Open/undeveloped areas were assumed to be similar to "Lawns, heavy soils, flat (<2%)", in Table 1 in Part B of the
Manual, which references a rational runoff coefficient of 0.15 (and imperviousness of 0.11).
DocuSign Envelope ID: COBF24FB-5071-4B1C-AE82-E891E3AC3233
Stormwater Treatment System Runoff Volume Calculations
10 December 2020
Page 5
Equation 2: Design Volume
DV=3630xRDxRVxA
where,
DV is the design volume (cubic feet);
RD is the design storm depth (inches);
R,, is the runoff coefficient (unitless); and
A is the drainage area (acres).
cu ft
DV = 3630 in x ac x 1 in x 0.80 x 13.9 ac
DV = 40,214 cu ft = 300,800 gal
The calculations outlined above result in a stormwater runoff volume from the drainage area to the
Treatment System, for the designated design storm, of approximately 300,800 gallons.
The capacity of the storage tank was sized for the runoff volume from the 1-inch rain event (as
specified in the CO Addendum) from the drainage area to the Treatment System, which was
determined based on the Simple Method for Runoff Volume (Part B of the Manual), as outlined
above. The calculated design volume was used to determine the volume capacity of the storage
tank, resulting in a storage tank designed to have a volume capacity of approximately 300,800
gallons.
Part C-6 of the Manual includes information on sand filters, which requires both a stormwater
volume and flow -based sizing process, similar to the Treatment System. It is important to note that
the Treatment System will not operate as a sand filter. NCDEQ design guidance for sand filters is
simply used to aid in developing conceptual design parameters relevant to the storage tank and
Treatment System design flowrate.
Minimum design criteria (MDC) #3 (sediment/sand chamber sizing) notes that, "The volume of
water that can be stored in the sediment chamber and the sand chamber above the sand surface
combined shall be 0.75 times the treatment volume." It further notes to calculate the design volume,
the design volume should be multiplied by 0.75 ("a `discount' that is allowed because stormwater
infiltrates so rapidly through the sand media that the stormwater is treated throughout the storm
event. By the end of the storm, the runoff from the beginning of the storm has already been treated
and has exited the sand filter").
DocuSign Envelope ID: COBF24FB-5071-4B1C-AE82-E891E3AC3233
Stormwater Treatment System Runoff Volume Calculations
10 December 2020
Page 6
Although this discount factor could potentially be applied to the design volume of the storage tank,
based on guidance from the Manual, the full design volume (as calculated with Equation 2) is
recommended as a conservative approach. The capacity of the storage tank is sized to store the
entire runoff volume from the 1-inch design storm, even though stormwater will also be treated by
the Treatment System throughout the storm event, allowing for additional capacity in the storage
tank.