NCG500077_Regional Office Historical File Pre 2018 (3)

DMSION OF WATER QUALITY
J�rlyy 15, 1998
MEMORANDUM JUN. 1998
To: Dave Goodrich
Through: Matt Matthews f" E,;* .if
From: Melissa Rosebrock
Subject: JPS Converter and Industrial Corporation-Lincolnton
Biocide/Chemical Treatment Use
NPDES No. NCG500000
Lincoln County
JPS Converter and Industrial Corporation has submitted Spectrus biocides OX103 and NX102 for
approval. Data submitted by the facility and chemical supplier concerning dosage rates, degradation,
system volume, average daily discharge, toxicity of the active ingredient(s) and/or breakdown products,
and minimum stream flow have been reviewed.
While performing our review, we noted several discrepancies. I have been in contact (by phone) with
the chemical supplier several times over the last three to four months in an attempt to clarify concerns
regarding the submittal. To date, we have not received appropriate documentation. Items which need
clarification are outlined below:
Permit number NCG500077
Biocide worksheet is submitted for OX 103 only, while the cover letter requests approval for OX 103 and
NX102
Cover letter requesting approval refers to facility as permit number NCG50000
Biocide worksheet for OX103 was signed in 1995, with only the trade name corrected with "white -out"
Half-life documentation was not included for OX103
Aquatic Toxicology data submitted (see MSDS) for OX103 does not match that which is on the worksheet
Permit number NCG50000
Biocide worksheet is submitted for NX102 only, while the cover letter requests approval for NX102 and
OX103
Biocide worksheet for NX102 was signed in 1994, with only the trade name corrected with "white -out"
Half-life documentation was not included for NX 102
Aquatic Toxicology data submitted and active ingredients listed (see MSDS) for NX102 does not match
that which is on the submitted worksheet
Submitted worksheet utilizes an older version of Biocide Form 101 (7/92) rather than the most recent
version (2/95)
Due to the many errors, questions and discrepancies noted on this submittal, we are unable to
recommend approval for either of these biocides for use at JPS Converter - Lincolnton. If there are
questions concerning this review please contact me at [phone].
Attachments
cc: Rex Gleason-MRO
Central files

REGISVED
BetmDearborn
Water Management Group
March 3, 1998
Ms. M. Melissa Rosebrock
North Carolina Department of Environmental,
Health and Natural Resources
Division of Environmental Management
Water Quality Section
4401 Reedy Creek Road
Raleigh, NC 27607
Reference: JPS - Lincolnton
Dear Melissa:
BetzDearborn Inc.
Water Management Group
Carolinas District
7092 Howard Street, Suite B
Spartanburg, SC 29303-2057
864 591-0880
800 476-2412
800 468-7194 Fax
Fax #[phone]
Attached are the worksheets and MSDS sheets for the biocide products for JPS - Lincolnton
- NPDES # NC - G 500000.
Spectrus NX102 which replaces Entec 345A in name only.
Spectrus OX103 which replaces Entec 367 in name only.
These products are identical to the products that the plant has been permitted to use. We
only had a name change.
If I can be of any further assistance, please let me know.
Sincerely,
BetzDearborn, Inc.
Water Management Group
C L� L�-) �-�
Rick Wirth
Account Manager
RW/tb
Enclosures
Shaping the Future of Water & Process Treatment

BIOCIDEJCHEMtCAL TREATMENT
WORKSHEET•FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface 'Naters =f
North Carolina. This woricsheet musj be completed separately for each biocida.f product in use. This workSheet is :o bi
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name BPS Converter
NPDES # NC G 500000 _
County Lincoln
Receiving Stream _� �10 0 (cfsl
(All above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water oco
A.D.D. = _0.020 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
(A.D.D.) x 100
IWC = (7Q 10 x 0.646) + (A.D.D.) ( 0 )(0.646) + ( }
100 %
This value (IWC) represents the waste concentration to the receiving stream during low 11ow conditions.
What is the name of the whole product Chemical treatment proposed for use in the discharge identified in =ar,
�p2�.livr,. *c4,,,l rA(jcZ*See bottom of page for two ingredients.
?lease list the active ingreoients and percent composition: 5.0% °�o
DBNPA (2,2-Dibromo-3-Nitrilo ro iona '
Sodium Bromide 1.0% %
Dibromoacetonitrile .25%
Monobromo-3-Nitrilopropionamide .25% %
2,2-Dibromo ro anediamide .25% °�°ofepagettom
Note: If ingredients contain the metals copper, chromium, cr zinc, also complete page a :41'
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whom
product used per day.
D.R.= 454 grams/day
D.E.M. Form 101 (7/92) 1
*Polyethylene Glycol 30%
Water 63.25%

acttrty Name:
JPS Converter NpDES #: NC G 500000
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown, holding lagoon size, etc.)
volume= 0.0292 million gallons
7.5-8.5
What is the pH of the handling system prior to biocide addition? It unknown, enter NIA. _
What is the decay rate (D.K.) of the product? It unknown, assume no decay (O.K.=0) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the naif
life (Half Life is the time required for the initial product to'degrade to half of its original concentration). Please
provide copies of the sources of this data.
H.L. - 0.08 Days
The decay rate is equal to H L. X 0.69 . 8.625 _.Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
A� D D) ( 0.020 } 1. 309
D.F. _ (Volume) * (D.K.} _ { 0.0292 ) * ($.625 ) = —
Calculate Steady State Discharge Concentration:
(D.R.} _ ( 454 ) = 0.44 rrtg�t
Dischg Conc. _ (D.F,)(voiurne)(3785) { 5.3G9 ) Q.0292 } (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
LDischg. Conc.)_ x 0.44 1 x ( 100 ) _ 0.44 mgrl
100 - 100
Receiving Stream Concemrauor
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units ShOUld t
in mg/l). Please provide copies of the sources of this data.
Organism Test Duration LC50 rnYj'l)
Rainbow Trout 96 hr. Static Acute Bioassay 9.2
Daphnia Magna 48 hr. Static Acute Bioassay 11.2 _
D.E.I. Form 101 (7/92) 1

=acdity Name:
JPS Converter NPDES 4: NC G 500000
Choose the lowest LC50 listed above:
Enter the LCSO: 9.2
;f the had life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LCSO = 0.46 mg/i
It the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Umitation = 0.01 x LC50 = mg/l
Choose the appropriate regulated limitation from the calculations immediately above and place in this b:anW
0.46 rrig/liter
From Part 11 enter the receiving stream concentration:
0.44 mglliter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocid= is
unacceptable for use.
r�LO VCR 47"'f
Name (Pnrn)
° 'j
Signatur� Date
Person in Responsible Charge
D.E.M. Form 101 (7/92) 3

acility Name:
JPS Converter
NPOES #: NC G 500000
Supplementpf MetelS Analysis
if copper, zinc, or chromium are present in the proposed biocidal compound, complete this worKsheet. A
separate form must be used for each metal and/or metal compound present in the biocide. List the metal,
its chemical formula, molecular weight (MW), formula weight (FM and the concentration of the metal
compound in the biocide (MCC). Complete a separate form for every metal present in the biocide.
Metal Chemical Formula Mglecular Wei Formula Vskilat Soncentraticn in Tocida
EXAMPLE
Copper CuSO4.5H2O 63.546 g/mola 249.680 9/mols 0.2 %
None
Dosage rate of Blocide (DR) (from page 1):
DR = grams/day
Average Daily Discharge (ADD) (from page 1):
A00 = million gallons/day
Discharge Concentration (DC) of Blocide:
OR ( crams/day) grams/million gallons
DC = AAIDE)= ( million gallons/day)
Convert DC to micrograms/liter (ppb):
CC (µg/I) = DC (grams/million gal) x 1 x810s / ug/I
3.785 x 10 liters/million gal.
Calculate the fraction of metal In the metal -containing compound (MF):
M( grarnsrmolel
MF = FW = ( grams/mole) _
Calculate the fraction of metal In the biocidal compound (BF):
BF = MF x MCC "e1 _ x % _
100 (100)
Calculate the concentration of metal in the discharge (M):
M=DCXSF= ug/Ix
ug/I
Calculate the Instream metal concentration (IMC) at low -flow conditions:
IWC f%
IMC = M x 100 = ug/l x 100 _ ugtl
Regulated limitation of metal (from below): ug/I
GeneralNC
tatutes 15A NCAC 28.0211 define:
Copper- 7 µgil water quality action level' Ztnc- 50 µg/I water quality action level'
Chromium- 50 µg/I water quality standard
('Values which exceed action levels must be addressed directly by aquatic toxicity testing.)
D.E.M. Form 101 (7/92) 4

BETZDEARBORN MATERIAL Bed -Dearborn
SAFETY DATA SHEET
FFECTIVE DATE: 17-SEP-1997
'RINTED DATE: 21-OCT-1997
1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SPECTRUS NX102
PRODUCT APPLICATION AREA: BIOCIDE
COMPANY ADDRESS:
Betz Water Management Group, Division Betz Laboratories, Inc.
200 Witmer Road Horsham PA 19044
Information phone number (Z15) 773-6269
EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA)
2) COMPOSITION / INFORMATION ON INGREDIENTS
Information for specific product ingredients as required by the
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to
additional sections of this MSDS for our assessment of the potential
hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME
10222-01-2 DBNPA (2,2-DIBROMO-3-NITRILOPROPIONAMIDE)
Corrosive (eyes); potential sensitizer
7647-15-6 SODIUM BROMIDE
Irritant
No component is considered to be a carcinogen by the National Toxicology
Program, the International Agency for Research on Cancer, or the
Occupational Safety and Health for
at OSHA thresholds for
carcinogens.
PAGE 1 CONTINUED

PRODUCT NAME: SPECTRUS NX102
EFFECTIVE DATE: 17-SEP-1997
3) HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER
Severe irritant to the skin. Potential skin sensitizer. Corrosive
to the eyes. Mists/aerosols may cause irritation to upper
respiratory tract.
DOT hazard is not applicable
Emergency Response Guide is not applicable
Odor: Amine; Appearance: Yellow, Liquid
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face -piece type). Proper fire -extinguishing media:
dry chemical, carbon dioxide, foam or water
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; Severe irritant to the skin. Potential
skin sensitizer.
ACUTE EYE EFFECTS:
Corrosive to the eyes.
ACUTE RESPIRATORY EFFECTS:
Mists/aerosols may cause irritation to upper respiratory tract.
INGESTION EFFECTS:
May cause gastrointestinal irritation. Very large doses may cause
diarrhea, depression, colic and death. May also cause severe
allergic reactions in sensitive individuals.
TARGET ORGANS:
Repeated skin contact may cause sensitization.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
Causes redness or itching of skin, possibly leading to burns
(dependent on the length of exposure).
PAGE 2 CONTINUED

'RODUGT NAME: SPEGIIKU5 NA1UZ
FFECTIVE DATE: 17-SEP-1997
1) FIRST AID MEASURES
SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap solution or
water for 15 min. Immediately contact physician.
EYE CONTACT:
Immediately flush eye with water for 30 minutes continuously -
imperative. Immediately contact physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid
treatment. Immediately contact a physician.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
5) FIRE FIGHTING MEASURES
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face -piece type).
EXTINGUISHING MEDIA:
dry chemical, carbon dioxide, foam or water
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 20OF SETA(CC)
3) ACCIDENTAL RELEASE MEASURES
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Flush area with water. Spread sand/grit. Neutralize with soda ash.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer
treatment facility,in accordance with any local agreement,a permitted
waste treatment facility or discharged under a permit. Product
as is - Dispose of in approved pesticide facility or according to
label instructions.
7) HANDLING AND STORAGE
HANDLING:
Acidic. Corrosive(Eyes). Do not mix with alkaline material.
STORAGE:
Keep containers closed when not in use. Do not store at elevated
temperatures.
'AGE 3 CONTINUED

PRODUCT NAME: SPECTRUS NX102
EFFECTIVE DATE: 17-SEP-1997
8) EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS
CHEMICAL NAME
DBNPA(2,2-DIBROMO-3-NITRILOPROPIONAMIDE)
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
MISC: Note- manufacturer's recommended exposure limit: 2
mg/m3(ceiling)-for powder.
SODIUM BROMIDE
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED
WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR -RESPIRATORS.
If air -purifying respirator use is appropriate, use a
respirator with organic vapor/acid gas cartridges and
dust/mist prefilters.
SKIN PROTECTION:
nitrile gloves-- Wash off after each use. Replace as
necessary.
EYE PROTECTION:
splash proof chemical goggles
9) PHYSICAL AND CHEMICAL PROPERTIES
Specific Gray. (70F) 1.155
Freeze Point (F) < -30.00
Viscosity (cps 70F) 62
Odor
Appearance
Physical State
Flash Point (F)
pH As Is (approx.)
Evaporation Rate (Water=l)
NA = not applicable
ND = not determined
Vapor Pressure (mmHG)
Vapor Density (air=1)
Solubility (water)
Amine
Yellow
Liquid
> 200
2.5
ND
PAGE 4 CONTINUED
SETA (CC)
24.0
< 1.00
100.0

PRODUCT NAME: SPECTRUS NX102
EFFECTIVE DATE: 17-SEP-1997
10) STABILITY AND REACTIVITY
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
Above 120 deg. C bromine, cyanogen bromide and dibromoacetonitrile
are formed. May react with bases or strong oxidizers.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
"B"
11) TOXICOLOGICAL INFORMATION
Oral LD50 RAT:
Dermal LD50 RABBIT:
Inhalation LC50 RAT:
Skin Sensitization G.PIG:
NOTE - 50-. Solution of
Skin Sensitization HUMAN:
NOTE - 0/26 Positive
Ames Assay BACTERIA:
Non -Ames Mutagenicity
>1,000 mg/kg
>2,000 mg/kg
>2,000 ppm/6hr
POSITIVE
active ingredient: 7/10 sensitized
NEGATIVE
from 1,250 ppm aqueous DBNPA (active)
NEGATIVE
NEGATIVE
NOTE - CHO/HGPRT; Micronucleus Test; Rat Hepatocyte unscheduled DNA
repair
PAGE 5 CONTINUED

PRODUCT NAME: SPECTRUS NX102
EFFECTIVE DATE: 17-SEP-1997
12) ECOLOGICAL INFORMATION
AQUATIC TOXICOLOGY
Rainbow T 96 Hour Static Acute Bioassay
LC50: 9. g/L
No E Level: 7.2 mg/L
Fathead Minnow 96 Hour Static Renewal Bioassay
LC50: 35 mg/L
No Effect Level: 12.5 mg/L
Daphnia magna 21 eDayo -Thru Life -Cycle Chronic Bioassay
EC50 Reproductig/L
Reproduction NO mg/L
Daphnia ma�,48 Hour Static Renewal Bioassay
LC50: j 15 mg/L
No Effe Level: 10.6 mg/L
Bluegiil S! fi h 96 Hour Static Acute Bioassay
_URLCSA�,mg/L
Sheepsh,,eaaG�l nnow 96
LC50/'28,mg/L
BIODEGRADATION
COD (mg/gm): 990
TOC (mg/gm): 340
BOD-5 (mg/gm): 0
BOD-28 (mg/gm): 160
Hour Static Acute Bioassay
13) DISPOSAL CONSIDERATIONS
If this undiluted product is discarded as a waste, the US RCRA
hazardous waste identification number is
Not applicable.
Please be advised; however, that state and local requirements for
waste disposal may be more restrictive or otherwise different from
federal regulations. Consult state and local regulations regarding
the proper disposal of this material.
PAGE 6 CONTINUED

3RODUCT NAME: SPECTRUS NX102
FFECTIVE DATE: 17-SEP-1997
14) TRANSPORT INFORMATION
DOT HAZARD: Not Applicable
UN / NA NUMBER: Not applicable
DOT EMERGENCY RESPONSE GUIDE #: Not applicable
15) REGULATORY INFORMATION
TSCA:
This is an EPA registered biocide and is exempt from TSCA
inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds
FIFRA REGISTRATION NUMBER:
34571-10-3876
SARA SECTION 312 HAZARD CLASS:
Immediate(acute); Delayed (Chronic)
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds
SARA SECTION 313 CHEMICALS:
CAS# CHEMICAL NAME RANGE
10222-01-2 DBNPA 2.0-5.00-.
(2,2-DIBROMO-3-NITRILOPROPIONAMIDE
CALIFORNIA REGULATORY INFORMATION
CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds
MICHIGAN REGULATORY INFORMATION
No regulated constituent present at OSHA thresholds
"'AGE 7 CONTINUED

PRODUCT NAME: SPECTRUS NX102
EFFECTIVE DATE: 17-SEP-1997
16) OTHER INFORMATION
NFPA/HMIS CODE TRANSLATION
Health 3 Serious Hazard
Fire 1 Slight Hazard
Reactivity 0 Minimal Hazard
Special NONE No special Hazard
(1) Protective Equipment B Goggles,Gloves
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGE LOG
MSDS status:
PAGE 8
EFFECTIVE
DATE REVISIONS TO SECTION:
15-SEP-1997
17-SEP-1997 12
SUPERCEDES
** NEW **
15-SEP-1997

aDi� LJ E
En tec
-
AQUATIC TOXICITY DATA
-
Betz Entec 345A
Rainbow Trout 96 hr. Static Acute Bioassay LC50 9.2 mq/l.
Daphnia magna 48 hr. Static Acute Bioassay LC50 11.2 nglL
The active ingredient in 5�+.�; Nx+�� degrades rapidly in aqueous, alkaline systems
(particularly above pH 4,0) to yield predominantly dibromoacetic acid which is
approximately 100 times less toxic than the original active ingredient,
dibromonitrilopropionamide.
Hydrolysis of DBNPA ultimately forms carbon dioxide, ammonia and bromide ions via
the following sequence of degradation products: dibromoacetonitrile,
dibromoacetamide, dibromoacetic acid, glycolic acid and oxalic acid. DBNPA reacts
rapidly with various ions such as bisulfite to form cyanoacetamide. Decomposition
under the influence of sunlight also leads to the formation of cyanocetamide.
Contact with soil organisms degrades DBNPA. A detailed discussion on the rates
and products of DBNPA decomposition may be found in J. Agr. Food Chem., Vol. 21,
No. 5, pp. 838 - 42, 1973, by J. H. Exner et: al.
Tests performed in accordance with criteria set forth in the "Practice for Conducting
Acute Toxicity Tests with Fish, Macro inver-tebrates, and Amphibians" (ASTM Standard
E729-88).

03/30/95 16:44
NGG 500077
Facility Name: JPS Converter Cor t
NPDES t#; NC
810CIOEICHEMICAL TREATMENT
WORKSHEET-FORM 101
9
The followin calculations are to be performed on any biocidal products ultimately discharged to the SWaters � be
North Carolina This worksheet must be completed separately for each biocidai product in use. This
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
Facility Name JPS Converter Cor orat'on
NPDES n NC
NGG 500077 Outfall #�
County Lincoln 0
cfs)
ReceivingSueam Unnamed tributary to Lithia Branc 7o10
(All above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling"systems to the receiving water body?
A.D.D. = 0.0141 (in M.G.D.)
WC in percent) of this discharge using the data entered
Please calculate the Instream Waste Concentration (I
above.
(A.D.D.) X 100 _
(0.0141) X 100 _ 100
f11VC (7Q10)(0. 6) + (A.D.D) — ( 0 )(0.646) + (0.0141
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
Betztiecrtlr..
Please list the active ingredients and percent composition: 92.5 %
1-Bromo-3-Chloro-5 5-Dimeth d t 7.5 %
Inert Inciredients
What feed or dosage rate (D.R.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.—
23.5 grams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula foconversion
Q.
A. lbs. X specific gravity product Grams of product = fluid oz. of product X L alq... �� X 1 lb.
128 fl. oz. 1 gal. water
D.E.M. Form 101 (2J95) 1
03i30 '95 16:49

03/30/95 16:44
U DZIL, r.1N1Lv. a11v
Facility Name:
NPDES #: NC
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown. holding lagoon size, etc.)
Volume= 0.0336 million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter N/A.
7.5-8.5
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The
degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the hatf life (Halt
Life is the time required for the initial product to degrade to half of Its original concentration). Please provide
copies of the sources of this data.
H.L. = 0.04 Days
The decay rate is equal to 1 X 0.69 = 17.25 =Decay Rate (D.K.)
H.L.
Calculate degradation factor (D.F.). This Is the first order loss coefficient.
A.D.D. 0141) 17.66
D.F. _ (Volume) (D.K.) _ (0.0336 ) + ( 17.25) _
Calculate Steady State Discharge Concentration: 23.56
(O.R.) ( ) = 0.0104 mg/l
Dischg Cont. _ (D.F.)(Volume)(3785) ' ( 17.66 ) ( 0.0336
) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Discho. Conc.) x (IWC%) (0.0104 ) x 100 ) _ 0.0104 mg/I
100 100
Receiving Strsam ConcentraWn
III. Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should be in
mg/1). Please provide copies of the sources of this data.
Organism
Rainbow Trout
Fathead Minnow
Daphnia magna
LC50(mrA
96 hr. Static Acute Bioassay .87
96 hr. Static Acute Bioassay 2.2
4E hr. Static Acu Rioas
D.E.M. Form 101 (2J95) 2
03/30 '95 16:49

Ua/JU/Va—
Facility Name: NPOES #: NC
Choose the lowest LC50 listed above:
Faster the LC50: 0.46
If the half life (H.L) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x I = = 0.023 mg/I
It the half life (H.L) is greater than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 = mg/I
Choose the appropriate regulated limitation from the calculations immediately above and place In this blank:
0.023 mg/liter
From Part 11 enter the receiving stream concentration:
0.0104 mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated Ilmitation, then this biocide is
unacceptable for use.
Fl o,y d ,D C10 nl/ n✓q e- r
Name (Print) .
Person in Responsible Charge
Helen R. Cerra
Person Completing This worksheet
(If pltfwent From Above)
Betz Entec, Inc.
20C Witmer Road
Horsham, PA 19044
3 ,3r s
Date
3/28/95
`—� Data
D.E.M. Form 101(2/95) 3
03/30 '95 16:49

03/30/95 16:45 Ty BETZ ENTEC. INC. tODU/007
Facility Name: NPDES #: NC
Supplemental Metals Analv8f$
If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheaL A separate form
must be used for each metal and/or metal compound present in the biocide. List the metal, its chemical formula, molecular
weight (MW), formula weight (FW), and the concentration of the metal compound in the biocide (MCC). Complete a
separate form for every metal present in ttte biocide.
Metal Chemical Formula Molecular Weight of Metal Formula Weight Concentration_ in Biocide
EXAMPLE
Copper CUS04.5H20 63.:46 g/mole 249.680 g/mole 0.2
None
Dosage rate of Biocide (DR) (from page 1):
DR = grams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallons/day
Discharge Concentration (DC) of Biocide:
Ix _ DR _ ( grams/day) _ gramstmillion gallons
ADD - (_million gallonsiday) -
Convert DC to mlcrogram s/liter (ppb):
DC (µg/1) = DC (grams/million gz) x 1 x 106 4q/q 99A
3.785 x 106 liters/million gal.
Calculate the fraction of metal in the metal -containing compound (MF):
MN ( grams/mole)
MF Z. FW = ( _grams/mo8e) _
Calculate the fraction of metal in the biocidal compound (BF):
SF = MF x MCC (%)
100
s�o
(100) -
Calculate the concentration of metal in the discharge (M):
M=DCxBF= _ .fox ugA
Calculate the Instream metal concentration (IMC) at low -flow conditions:
IMC = M x IWC N x %
100 100
Regulated limitation of metal (from below): ug/I
NC eneral Statutes 15 28.0211define:
Copper- 7 µg/l water quality action level* Zino- 50 µgli water quality action level'
Chromium- 50 µgA water quality standard
('Values which exceed action levels must be addressed directly by aquatic toxkity testing.)
D.E.M. Form 101 (2J95) 4
03/30 '95 16:49

bt ' LUtARgUKN MATERIAL S Bit �,���„�0,,,�
SAFETY DATA SHEET
EFFECTIVE DATE: 06-OCT-1997
PRINTED DATE: 21-OCT-1997
1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: SPECTRUS OX103
PRODUCT APPLICATION AREA: BIOCIDE
COMPANY ADDRESS:
Betz Water Management Group, Division Betz Laboratories, Inc.
200 Witmer Road -Horsham PA 19044
Information phone number (�15) 773-6269
EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA)
2) COMPOSITION / INFORMATION ON INGREDIENTS
Information for specific product ingredients as required by the
U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to
additional sections -of this MSDS for our assessment of the potential
hazards of this formulation.
HAZARDOUS INGREDIENTS:
CAS# CHEMICAL NAME
16079-88-2 1-BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN
Oxidizer; irritant (eyes and skin)
No component is considered to be a carcinogen by the National Toxicology
Program, the International Agency for Research on Cancer, or the
Occupational Safety and Health ,administration at OSHA thresholds for
carcinogens.
PAGE 1 CONTINUED

EFFECTIVE DATE: 06-OCT-1997
3).HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER
Moderately irritating. May be corrosive in contact with moist skin.
Severe irritant to the eyes. Dusts cause irritation to the upper
respiratory tract.
DOT hazard: Oxidizer
Emergency Response Guide #35
Odor: Halogen; Appearance: White, Tablets
Fire fighters should wear positive pressure self-contained breathing
apparatus(full face -piece type). Proper fire -extinguishing media:
Flood with water. Use of CO2 or foam may not be effective.
POTENTIAL HEALTH EFFECTS
ACUTE SKIN EFFECTS:
Primary route of exposure; Moderately irritating. May be corrosive
in contact with moist skin.
ACUTE EYE EFFECTS:
Severe irritant to the eyes.
ACUTE RESPIRATORY EFFECTS:
Dusts cause irritation to the upper respiratory tract.
INGESTION EFFECTS:
May cause severe irritation or burning of the gastrointestinal
tract.
TARGET ORGANS:
No evidence of potential chronic effects.
MEDICAL CONDITIONS AGGRAVATED:
Not known.
SYMPTOMS OF EXPOSURE:
May cause redness or itching of skin.
PAGE 2 CONTINUED

EFFECTIVE DATE: 06-OCT-1997
4).FIRST AID MEASURES
SKIN CONTACT:
Remove clothing. Wash area with large amounts of soap solution or
water for 15 min. Immediately contact physician.
EYE CONTACT:
Immediately flush eyes with water for 15 minutes. Immediately
contact a physician for additional treatment.
INHALATION:
Remove victim from contaminated area. Apply necessary first aid
treatment. Immediately contact a physician.
INGESTION:
Do not feed anything by mouth to an unconscious or convulsive
victim. Do not induce vomiting. Immediately contact physician.
Dilute contents of stomach using 3-4 glasses milk or water.
5) FIRE FIGHTING MEASURES
FIRE FIGHTING INSTRUCTIONS: -
Fire fighters should wear positive pressure self-contained breathing
apparatus (full face -piece type).
EXTINGUISHING MEDIA:
Flood with water. Use of CO2 or foam may not be effective.
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
FLASH POINT:
> 20OF > 93C P-M(CC)
MISCELLANEOUS:
Oxidizer
UN1479;Emergency Response Guide #35
6) ACCIDENTAL RELEASE MEASURES
PROTECTION AND SPILL CONTAINMENT:
Ventilate area. Use specified protective equipment. Contain and
absorb on absorbent material. Place in waste disposal container.
Product releases chlorine when wet. Spill residue may be
neutralized with 3% hydrogen peroxide solution.
DISPOSAL INSTRUCTIONS:
Water contaminated with this product may be sent to a sanitary sewer
treatment facility,in accordance with any local agreement,a permitted
waste treatment facility or discharged under a permit. Product
as is - Dispose of in approved pesticide facility or according to
label instructions.
PAGE 3 CONTINUED

EFFECTIVE DATE: 06-OCT-1997
71 HANDLING AND STORAGE
HANDLING:
Oxidizer. Avoid all contact with reducing agents, oils, greases,
organics and acids.
STORAGE:
Keep containers closed when not in use. Keep dry. Do not store at
high temperature or near oxidizables or combustibles.
8) EXPOSURE CONTROLS/PERSONAL PROTECTION
CHEMICAL NAME EXPOSURE LIMITS
1-BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN
PEL (OSHA): NOT DETERMINED
TLV (ACGIH): NOT DETERMINED
MISC: Note- manufacturer's recommended exposure limit: 0.2 mg/m3.
ENGINEERING CONTROLS:
Adequate ventilation to maintain air contaminants below exposure
limits.
PERSONAL PROTECTIVE EQUIPMENT:
Use protective equipment in accordance with 29CFR 1910 Subpart I
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR
1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER
WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE.
USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED
WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR -RESPIRATORS.
If air -purifying respirator use is appropriate, use a
respirator with acid gas cartridges and dust/mist prefilters.
SKIN PROTECTION:
gauntlet -type rubber gloves, chemical resistant apron-- Wash
off after each use. Replace as necessary.
EYE PROTECTION:
airtight chemical goggles
PAGE 4 CONTINUED

EFFECTIVE DATE: 06-OCT-1997
9) PHYSICAL AND CHEMICAL PROPERTIES
Density 60.000 lb/cu. Vapor Pressure (mmHG)
Freeze Point (F) NA Vapor Density (air=1)
Freeze Point (C) NA
Viscosity(cps 70F,21C) NA o Solubility (water)
Odor Halogen
Appearance White
Physical State Tablets
Flash Point P-M(CC) > 20OF > 93C
pH 5o Disp. (approx.) 4.7
Evaporation Rate (Ether=l) < 1.00
NA = not applicable ND = not determined
10) STABILITY AND REACTIVITY
STABILITY:
Stable under normal storage conditions.
HAZARDOUS POLYMERIZATION:
Will not occur.
INCOMPATIBILITIES:
Slowly releases halogen gases when contaminated with moisture. May
react with alkalies, acids, organics or reducing agents.
DECOMPOSITION PRODUCTS:
Thermal decomposition (destructive fires) yields elemental oxides.
BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES:
1,811
'AGE 5 CONTINUED
< 1.0
< 1.00
0.1

EFFECTIVE DATE: 06-OCT-1997
11) TOXICOLOGICAL INFORMATION
Oral LD50 RAT: 578 mg/kg
NOTE - 600 mg/kg per alt. source; dehalogenated byproduct Rat Oral
LD50: >4,000 mg/kg
Teratology RAT:
NOTE - Dehalogenated byproduct study had terata (secondary) at
maternal toxic doses
Reproductive Toxicity RAT: 4,500 mg/kg/day
NOTE - Dehalogenated byproduct study had no adverse reproductive
toxicity
Dermal LD50 RABBIT: >2,000 mg/kg
NOTE - Alternate source concurs
Inhalation LC50 RAT: 1.88 mg/L/4hr
NOTE - >3.2 mg/L/4hr at 100 ppm (no deaths) per alternate source
Skin Irritation Score RABBIT: 6.1
NOTE - 6.98 per alternate source; reversible; dehalogenated
byproduct score: 0.8
Eye Irritation Score RABBIT: 103
NOTE - 14 Day-irreversible-max.at day 3; dehalogenated byproduct
score: 12.8-reversible
90 Day Feed Study RAT:
NOTE - Dehalogenated byproduct 90-day oral LD50: >2,000 mg/kg/day
Skin Sensitization G.PIG: POSITIVE
NOTE - Buehler Test; dehalogenated byproduct was negative in
Buehler Test
Ames Assay BACTERIA: NEGATIVE
NOTE - +/- Metabolic activation; dehalogenated byproduct: negative
Non -Ames Mutagenicity YEAST: NEGATIVE
NOTE - Dehalogenated byproduct negative for: Mouse Lymphoma, SCE,
Cell transformation
°AGE 6 CONTINUED

EFFECTIVE DATE: 06-OCT-1997
12) ECOLOGICAL INFORMATION
AQUATIC TOXICOLOGY
Rainbow Trout 96 Hour Static Acute Bioassay
LC50: .94 mg/L
No Effect Level: .54 mg/L
Fathead Minnow 96 Hour Static Acute Bioassay
LC50: 2.43 mg/L
No Effect Level: 1.83 mg/L
Daphnia magna 48 Hour Static Acute Bioassay
507:4
;�
Level: .32 mg/L
Sheepshead Minnow 96 Hour Static Acute Bioassay
LC50: 21.6 mg/L
No Effect Level. 12.1 mg/L
BIODEGRADATION
COD (mg/gm): 920
TOC (mg/gm): 250
BOD-5 (mg/gm): 6
BOD-28 (mg/gm): 11
13) DISPOSAL CONSIDERATIONS
If this undiluted product is discarded as a waste, the US RCRA
hazardous waste identification number is
D001=Ignitable.
Please be advised; however, that state and local requirements for
waste disposal may be more restrictive or otherwise different from
federal regulations. Consult state and local regulations regarding
the proper disposal of this material.
14) TRANSPORT INFORMATION
DOT HAZARD:
UN / NA NUMBER:
DOT EMERGENCY RESPONSE
SAGE 7
Oxidizer
UN1479
GUIDE #: 35
CONTINUED

EFFECTIVE DATE: 06-OCT-1997
15) REGULATORY INFORMATION
TSCA:
This is an EPA registered biocide and is exempt from TSCA
inventory requirements.
CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ):
No regulated constituent present at OSHA thresholds
FIFRA REGISTRATION NUMBER:
5185-420-3876
SARA SECTION 312 HAZARD CLASS:
Immediate(acute); Fire
SARA SECTION 302 CHEMICALS:
No regulated constituent present at OSHA thresholds
SARA SECTION 313 CHEMICALS:
No regulated constituent present at OSHA thresholds
CALIFORNIA REGULATORY INFORMATION
CALIFORNIA SAFE DRINKING WATER AND TOXIC
ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT:
No regulated constituent present at OSHA thresholds
MICHIGAN REGULATORY INFORMATION
No regulated constituent present at OSHA thresholds
16) OTHER INFORMATION
NFPA/HMIS CODE TRANSLATION
Health 2 Moderate Hazard
Fire Slight Hazard
Reactivity Slight Hazard
Special OXY DOT or NFPA Oxidizer
(1) Protective Equipment C Goggles,Gloves,Apron
(1) refer to section 8 of MSDS for additional protective equipment
recommendations.
CHANGELOG
EFFECTIVE
DATE
MSDS status: 06-OCT-1997
?AGE 8
REVISIONS TO SECTION:
SUPERCEDES
w* NEW w`

- A Q U A T I C T O X I C I T Y D A T A -
Betz Entec 367
Fathead
Minnow
96
hr.
Static
Acute
Bioassay
LC50
2.25
mg/L
Rainbow
Trout
96
hr.
Static
Acute
Bioassay
LC50
0.87
mg/L
Daphnia
magna
48
hr.
Static
Acute
Bioassay
LC50
0.46
mg/L
Betzi'Ic-'--., tio&is a pelletized form of 1-Bromo-3-Chloro-5, 5-Dimethylhydantoin.
The material is a slow -release halogen donor which also dissolves slowly.
The rate of solution is influenced by the surface area of the product, the
water temperature and the rate with which water flows over the pellets or
tablets. Relatively simple devices are used to feed the product.
I���ieoft,ur,�
s�r�,y1 cx,o� exhibits a toxicity which is characteristic of halogens. The material
is usually fed at substoichiometric levels, and no free -available halogen
is present in the tower blowdown. When the bromine and chlorine are released,
the remaining molecule is 5,5-Dimethylhydantoin. Acute toxicity studies with
fathead minnows have shown that this material is nontoxic at a concentration
of 8000 mg/L.
Testing for active hydantoin is relatively simple. Any standard test for
free -available chlorine will rapidly strip off any bromine or chlorine which
is still attached to the molecule. This makes it possible to detect bromine
expressed as available chlorine or chlorine itself.

State of North Carolina
Department of Environment,
Health and Natural Resources
Division of Environmental Management
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary
A. Preston Howard, Jr., P.E., Director
May 5, 1995
Mr. Reggie Deaton
JPS Converter & Industrial Corp.
Boger City Plant
Lincolnton, North Carolina 28092
Dear Mr. Deaton:
ffl�.'�VA
�EHNF1
N.C. DEPT. OF
ENVIRONMENT, HEALTH,
& NATURAL RESOURCES
MAY 9 WS
DIVISION OF ENVIRONMENTAL MANAGEMENT
MOORESVILLE REGIGNAL OFFICE
Subject: Biocide Approval
Pdrmit: NCG500077
Lincoln County
The Aquatic Toxicology Unit has reviewed your request to use the compound Betz
Entec 367 in your cooling water system and has deemed it acceptable at the stated rates
and application levels.
If you have any questions concerning this matter, please contact Susan Robson at
[phone].
Sincerely,
. Preston Howard, Jr., P.E.
cc:
Central Files
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper

DMSION OF ENVIRONMENTAL MANAGEMENT
/ I
MEMORANDUM:
To: Susan Robson
April 20, 1995
Through: Matt MaE-iews '0 � AW
From: Melissa Rosebrock
Subject: JPS Converter and Industrial Corp. -Boger City Plant
Use of Bixides
NPDES No. NCG500077 (formerly NC0004871)
Lincoln County
11.C. DEFT. nF
I�ONAJE T, HE4i_TT-1
UI2AL RES;.,S,
OURC
APR 26 1995
DIVISION OF ENVIROKIENTAL MANAGEMENT
MOORESVILll JU19mL Oulu
JPS Converte_ and Industrial Corp. has submitted Betz Entec 367 for approval. Data submittee
by the subject facilin- concerning the dosage rate of the compound, system volume, average daily
discharge, toxicity of the active ingredients and/or breakdown products, and minimum stream flow ha-,-_
also been reviewed a -id evaluated.
Calculations Summarized on the accompanying worksheet predict that the use of Betz Entec 367
at the stated dosage rite and discharge conditions will not result in toxic impact to aquatic life in the
receiving stream. Th_refore, the use of this product as a biocide at JPS Converter and Industrial Corp.
is deemed acceptable.
If there are q-.:estions regarding this review please contact me at [phone].
Attachments
cc:
Central files

JPS Converter and Industrial Corp. BIOCIDE WORKSHEET
PERMITn NCG500077 (formerly NC0004871)
RECEIVING STREAM_ LIT to Lithia Branch
7Q10 (cfs): 0.00
I.W.C.%: 100.00
PRODUCT: Betz Entec 367
ACTIVE INGREDIENT: 92.5% 1-Bromo-3-chloro-5,5-dimethylhydantoin
HALF LIFE (DAYS):
3.04
STEADY STATE DISC CONC:
0.0105
LC50 OF SELECTED TOX DATA (MG/L):
3.46
DEGRADATION FACTOR:
17.670
DECAY RATE:
17.2500
APPLICATION FACTOR:
0.050
DOSAGE RATE (GRAMS/DAY):
23.50
AVG DAILY DISCHARGE (MGD):
3.0141
INSTREAM BIOCIDE CONC:
0.010
VOLUME OF SYSTEM (MIL. GAL'S):
3.0336
REGULATED LIMITATION:
0.023
PASS/FAIL:
PASS

State of North Carolina
Department of Environment,
Health and Natural Resources
Division of Environmental Management
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary
A. Preston Howard, Jr., P.E., Director
April 4, 1995
MEMORANDUM
To: Melissa Rosebrock, Aquatic Toxicology
From: Susan Robson, Permits and Engineering r
Subject: Request for Biocide Review
JPS Converter and Industrial Corp.
Lincoln County
N-PDES: NCG500077
AM
C)EHNFi
Aaached please find Biocide 101 Worksheets and supporting information for the subject
facility. We are requesting that you review and comment on these worksheets.
Thank you for your help in this matter.
4p Fp
s199s
"bee
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10r% post -consumer paper

` �.y 3,,�• V': Ali
JPSCONVERTER AND
INDUSTRIAL CORP.
BOGER CITY PLANT
March 31, 1995
Ms. Suzan Rcnson
NCD=HN=_
NPD S =ermit Group
P. =ox 29535
Raleig'- NC 27626-0535
REF: JPS Converter & Industrial Corp.
Boger City Plant
Lincoln Coun-y
Li ncolnton NC
COC NCG 500077
Dea= M_. Robson:
Please -find enclosed form 101 work sheet for Betz Entec
367 biocide. We hereby request approval to use Betz
Ent=c �67 as a biocide. If there are any questions do not
hes-ta_e to call [phone].
Since -rely,
Reggie Deaton,
Cerica_ Contol Officer
CC: S ::i Griggs - Greenville SC
TRD/kw-
N
2130 E. '•!.-\IN ST. • P.O. BOX 658 • LINCOLNTON, N.C. 28092 • [phone] • FAX [phone]

03/30/95 16:44 V BETZ ENTEC, INC. 0 003/007
Facility Name: JPS Converter CoroQration
NPDES #: NC_ NGG 500077
BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged n the surface waters of
North Carolina This worksheet must be completed separately for each biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with-caloulations performed as indicated.
I. Facility Name JPS Converter Corporation
NPDES tt NC NGG 500077 Outfall #
County Lincoln
0
Receiving Stream Unnamed tributary to Lithia Branch 7QI0 (cfs)
(All above information supplied cy the Division of Environmental Management)
What is the Average Daily Discharge (AL.D.) volume of the water handling systems tc the receiving water body?
A.D.D. = 0.0141 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
(A.D.D.) X 100 (0.0141) X 100 100 %
ANC ' 77Q10)(0.646)+(A.D.D) — ( 0 )(0.646) + (0.0141
This value (IWC) represents the waste concentration to the receiving stream during l;-w flow conditions.
II. What is the name of the whole croduct chemical treatment proposed for use in the discharge identified in Pag1?
Betz Entec 367
Please list the active ingredien and percent composition: `
1h dant^i 92.5
1-Brornc-3-Chloro-5 5-�Jimethv��
Inert Ingredients 7.5
What feed or dosage rate (D.R.) is used in this application? The units must be conveded to maximum grams
of whole product used in a 24hr period.
D.R.- 23' S gr-ams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The t:rmula for this conversion is:
Grams of product = fluid oz. of oroduct X 1 gal. water X 8 34 ibs. X specific aavity of product X 4559 Q
128 fl. oz. 1 gal: water 1 lb.
D.E.M. Form 101 (2/95) 1
03/30 '95 16:45

03/30/95 16:44 `8 BETZ ENTEC, INC. 1@ 004/007
Facility Name: NPDES 4: NC
Estimate total volume of the wafer handling system between entry of biocidal product and NPDES discharge
point On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown, holding lagoon size, etc.)
Volume= 0.0336 million gallons
What is the pH of the handling system prior to biocide addition? If unknown, enter NIA.
7.5-8.^
What Is the decay rate (D_K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The
degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half
Life is the time required for the initial product a degrade to half of its original concentration). please provide
copies of the sources of this data.
H.L. = 0.04 pays %' eJ�l j;;G� Ujiu.ttte�
The dewy rate is equal to H.
X 0.69 = 17.25 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
A.D.D. .0141) 17.66
D.F. _ (Volume) (D.K') _ (0.0336 ) + ( 17.25) _
Calculate Steady State Discharge Concentration: 23.56
Dischg Conc. = (D.R.) _ ( ) = 0 ^0104 mgA
(D.F.)(Volume)(3735) ( 17.66 ) ( 0.0336 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Dlschg. Conc.) x (IWC%l (0.0104 ) x ( 100 ) _ 0.0104 mg11
100 - 100
AecaMng Stream C-mcentration
Calculate regulated limitation.
List all LC50 data available for -me whole product according to the folloMng columns. (Note that unite should be in
mg/l). Please provide copies of the sources of this data.
Organism Test Duration LC50 (MTI
Rainbow Trout 96 hr. Static Acute Bioassay .87
Fathead Minnow 96 hr. Static Acute Sioassay 2.25
Daphnia magna 48 hr. Stati-c Acute B1oas5iiY -46
D.E.M. Form 101 (2195) 2
ORAO ' A5 1 F : dq

03/30/95 16:45 a BETZ 24TEC, INC.
Q 005/007 ,
Facility Name: NPDES #: NO
Choose the lowest LG50 listed above:
Enter the LC50: 0.46
If the half life (H.L) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC-1-0 = 0.023 mgA
If the half life (H.L) is greater than cr equal to 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x L EO = mg/I
Choose the appropriate regulated li,-nitrtian from the caiculadons immediately above and place In this blank:
0.023 mg/liter
From Part II enter the receiving stream concentration:
0.0104
mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use.
F1 o yal D C/ow,:✓T er
fume (PdM)
1
0
Person in Responsible Char
Helen R. Cerra
Person CompLuting This 4k6waet
(If Different From #bare)
Betz Entec, Inc.
20C Witmer Road
Horsham, PA 19044
s
Date
3/28/95
Date
D.B.M. Fo= 101(2/95) 3
03/30 '95 16:49

03/30/95 16:45 %Y BETZ ENTEC, INC. Q1006/007
Facility Name:
NPDES #: NC
$ e!3tal Metals Analysis
If copper, zinc, cc chromium are present in the proposed biocidai compound, complete th* worksheet. A separate form
must be used for each metal and/or metal compound present in the biocide, last the metal, its chemical formula, molecular
weight (MW), formula weight (FW), and the concentration of the metal compound in the biocide (MCC). Complete a
separate form for every metal present in the biocide.
Metal C:�emical Formula Molecutr Weight Formula Weight Qoncentra-6on_in Biocide
EXAMPLE
Capper ,uSO4r5H2D 63.i46rmole 249.680glmOle 0.2
None
Dosage rate of Biocide (DR) (from page 1):
DR = grams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallonsiday
Discharge Concentration (DC) of Siocide:
DC _ DR _ ( grams/day) _ crams/million gallons
ADD — (_million gallons/day)
Convert DC to micrograms/liter (ppb):
DC (µg/I) = DC (grams/million ga=) Y 1 x 106 µg/a = ugll
3.785 x 106 liters/million gal.
Calculate the fraction of metal in the metal -containing compound (MF):
MF = HMV — rams/mole _
FAN ( grams/mote)
Calculate the fraction of metal in the blocidal compound (BF):
SF = MF x MCC - x
(100)
Calculate the concentration of metal in the discharge (Mt);
M = DC x BF x
Calculate the Instream metal concentration (IMC) at low -flow conditions:
IMC = M x im % ug/l x o = �1
100 100
Regulated limitation of metal (from below): ug/I
NC 69neral Statutes 15 2B.0211 de ne:
Copper- 7 49/1 water chilly action level' Zino- 50 µfill water quality action level"
Chromium- 50 49A water gLo1iry standard
('Values which exceed action levels must be addressed direcdy by aquatic tmicity tasting.)
T.E.M. Forin 101 (2/95) 4
03/30 ' 95 16 : -'9

04 19/95 16:48 V BETZ E\TEC, INC. 2 003%003
Facsimile Cover Sheet
To: NI. Melissa Rosebrock
Company: North Carolina DNR
Phone:
Fax: [phone]
From: Helen Cerra
Company: Betz
Phone: 2,15-773-6303
Fax: 2, 5-675-4023
Date: 04/19/95
Pages including this 3
cover page:
Comments: Melissa,
I hope this information is adequate for evaluating bcth
JPS Converter and Cone Mllls (Florence Plant),

0 4/19/9 5 1b:41 "a
April 17, 1995
Ms. M. Melissa Rosebrock
North Carolina Department
of Environment, Health, and Nalural Resources
Division of Environmental Management
Water Quality Section
4401 Reedy Creek Road
Raleigh, NC 27607
Dear Melissa:
Attached is aquatic toxicity data for Betz Entec 367.
bntec
Betz Entec Inc.
200 Wit rr. r 1iu-.:
HonOom, PA 7>r '-;)998
2I5 674 C100
215 675 'OZ3
At this time, I am unable to senc half-life data for Betz Entec 367. Howe:=r, this letter
will document our discussion Dn March 27, 1995, regarding the ha =-i fe of Betz
Entec 367. You agreed to a half-life of 0.04 days. Should I acquire ha'-*iTe data for
Betz Entec 367, 1 will forward it to your office.
Sincerely,
BETZ ENTEC, INC.
�i
Helen R. Cerra
Environmental and Regulatory Affairs Manager
H RC/lg
Attachment
9

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N.C. DEPT. OF
ENVIRONMENT, HEALTA,-
& NATURAL RESOURCT$%"
DIVISION OF ENVIRONMENTAL MANAGEMENT DEC 6 19od
December 1, 1994 DIVISION GF ENVIRCN,%liENTRL .'Ay- *
MOORESVILLE REGIONAL OFFICE
To: `Susan Robson
Through: Matt Matthews n^
From: Melissa Rosebrock Wl�
Subject: JPS Converter and Industrial Corp. -Boger City Plant
Use of Biocides
NPDES No. NCG500077 (formerly NC0004871)
Lincoln County
JPS Converter and Industrial Corp. initially submitted Betz Entec biocide products 365 and 367
for approval. Since the initial submital, the facility has requested that we disregard the review for 367.
The facility has now submitted Betz-Entec 345A for review. Data submitted by the subject facility
concerning the dosage rate of the compounds, system volume, average daily discharge, toxicity of the
active ingredients and/or breakdown products, and minimum stream flow have also been reviewed and
evaluated.
Calculations summarized on the accompanying worksheet predict that the use of Betz Entec 365
and Betz Entec 345A at the stated dosage rates and discharge conditions will not result in toxic impact to
aquatic life in the receiving stream. Therefore, the use of these products as biocides at JPS Converter
and Industrial Corp. is deemed acceptable.
If there are questions regarding this review please contact me at [phone].
Attachments
cc: ex Gleason-MRO
Central files

s
JPS Converter and Industrial Corp. BIOCIDE WORKSHEET
PERMIT#: NCG500077 (formerly NC0004871)
RECEIVING STREAM: UT to Lithia Branch
7Q10 (cfs): 0.00
I.W.C.%: 100.00
PRODUCT: Betz Entec 365
ACTIVE INGREDIENT: 20% 2,2,-Dibromo-3-nitrilo-propionamide
HALF LIFE (DAYS):
LC50 OF SELECTED TOX DATA (MG/L)
DECAY RATE:
DOSAGE RATE (GRAMS/DAY):
AVG DAILY DISCHARGE (MGD):
VOLUME OF SYSTEM (MIL. GAL'S):
0.08
STEADY STATE DISC CONC:
0.1108
3.30
DEGRADATION FACTOR:
9.310
8.6250
APPLICATION FACTOR:
0.050
114.00
0.02
INSTREAM BIOCIDE CONC:
0.111
0.0292
REGULATED LIMITATION:
0.165
PASS/FAIL:
PASS
7Q10 (cfs): 0.00
I.W.C.%: 100.00
PRODUCT: Betz Entec 367
ACTIVE INGREDIENT: 5% 2,2,-Dibromo-3-nitrilo-propionamide
1% Sodium bromide
HALF LIFE (DAYS):
LC50 OF SELECTED TOX DATA (MG/L)
DECAY RATE:
DOSAGE RATE (GRAMS/DAY):
AVG DAILY DISCHARGE (MGD):
VOLUME OF SYSTEM (MIL. GAL'S):
0.08
STEADY STATE DISC CONC:
0.4412
9.20
DEGRADATION FACTOR:
9.310
8.6250
APPLICATION FACTOR:
0.050
454.00
0.02
INSTREAM BIOCIDE CONC:
0.4412
0.0292
REGULATED LIMITATION:
0.4600
PASS/FAIL:
PASS

November 15, 1994
Ms.TAelissa Rosebrock
State of North Carolina
Department of Environment, Health
and Natural Resources
4401 Reedy Creek Road
Raleigh, NC 27607-6445
Dear Melissa:
Re: JPS Converster Corporation
Boger City, NC
General Permit #NC G500000
Enclosed is a biocide worksheet for Betz Entec 365.
O [:gff/ 7
Entec
Betz Entec Lu.
200 Witmer Road
Horsham, P.9 19044-0998
215 674 9200 (2 Xi ' U3
215 675.102 i Fax
As we discussed during our conversation today, I have used a half-life of 0.08 days.
This product is very similar to a biocide that was previously approved in July, 1994.
I have attached aquatic toxicity data and a product fact sheet for Betz Entec 365. 1
have also attached aquatic toxicity data for Betz Entec 367. The worksheet for this
biocide has been sent under previous cover.
Since this is not a permit renewal, your immediate review is very much appreciated.
Sincerely,
BETZ ENTEC, INC.
Helen R. Cerra
Environmental and Regulatory Affairs Manager
HRC/Ig
Attachments

0.
Rainbow Trout
Bluegill Sunfish
Daphnia magna
Fathead Minnow
Sheepshead Minnow
,
- A Q U A T I C T O X I C I T Y D A T A -
Betz Entec 365
96
hr.
Static
Acute
Bioassay
LC50
5.0
mg/L
96
hr.
Static
Acute
Bioassay
LC50
6.5
mg/L
48
hr.
Static
Acute
Bioassay
LC50
3.3
mg/L
96
hr.
Static
Acute
Bioassay
LC50
6.8
mg/L
96
hr.
Static
Acute
Bioassay
LC50
7 mg/L
The active ingredient in Entec 365 degrades rapidly in aqueous, alkaline systems
(particularly above pH 4.0) to yield predominantly dibromoacetic acid, which
is approximately 100 times less toxic than the original active ingredient,
dibromonitrilopropionamide.
Hydrolysis of DBNPA ultimately forms carbon dioxide, ammonia and bromide ions
via the following sequence of degradation products: dibromoacetonitrile,
dibromoacetamide, dibromoacetic acid, glycolic acid and oxalic acid. DBNPA
reacts rapidly with various ions such as bisulfite to form cyanoacetamide.
Decomposition under the influence of sunlight also leads to the formation of
cyanoacetamide. Contact with soil organisms degrades DBNPA. A detailed
discussion on the rates and products of DBNPA decomposition may be found in
J. Agr. Food Chem., Vol. 21, No. 5, pp. 838-42, 1973, by J. H. Exner et al.

-
a
A Q U A T I
C
T O X I
C I T
Y D A T
A -
Betz Entec 367
Fathead Minnow
96
hr.
Static
Acute
Bioassay
LC50
2.25 mg/L
Rainbow Trout
96
hr.
Static
Acute
Bioassay
LC50
0.87 mg/L
Daphnia magna
48
hr.
Static
Acute
Bioassay
LC50
0.46 mg/L
Sheepshead Minnow
96
hr.
Static
Acute
Bioassay
LC50
20 mg/L
Betz Entec 367 is a pelletized form of 1-Bromo-3-Chloro-5, 5-Dimethylhydantoin.
The material is a slow -release halogen donor which also dissolves slowly.
The rate of solution is influenced by the surface area of the product, the
water temperature and the rate with which water flows over the pellets or
tablets. Relatively simple devices are used to feed the product.
Entec 367 exhibits a toxicity which is characteristic of halogens. The material
is usually fed at substoichiometric levels, and no free -available halogen
is present in the tower blowdown. When the bromine and chlorine are released,
the remaining molecule is 5,5-Dimethylhydantoin. Acute toxicity studies with
fathead minnows have shown that this material is nontoxic at a concentration
of 8000 mg/L.
Testing for active hydantoin is relatively simple. Any standard test for
free -available chlorine will rapidly strip off any bromine or chlorine which
is still attached to the molecule. This makes it possible to detect bromine
expressed as available chlorine or chlorine itself.

Ffl[�ff� ENTEC...
H O R S H A M, PENNSYLVANIA 1 9 0 4 4
product facts
BETZ ENTEC° 365
• Easy -to -feed liquid product
• Nonfoaming
• Mild oxidizing compound
• Does not harm tower wood
• Fast acting — can be detoxified
• Hydrolyzes to form essentially nontoxic by-
products
• Compatible with Betz Entec corrosion inhibitors
DESCRIPTION AND USE
BETZ ENTEC 365 aids in the control of bacterial, fungal
and algal slimes in evaporative condensers, heat ex-
change water systems, commercial and industrial cool-
ing towers, influent systems such as flow through, Infilco
units, filters, lagoons, etc., industrial scrubbing systems
and brewery pasteurizers.
The product may also be applied to once -through and
closed cooling systems, cooling ponds, canals and
lagoons.
BETZ ENTEC 365 is registered for use in air washer
systems. It is also effective in inhibiting the growth of
bacteria, fungi, and yeasts that may deteriorate metal-
working fluids that contain water.
TREATMENT AND FEEDING REQUIREMENTS
Proper treatment levels for BETZ ENTEC 365 depend on
factors such as the severity of the problem and conditions
particular to a given installation. The product should be
used in accordance with the label instructions and control
procedures BETZ ENTEC, INC. establishes for a specific
application.
In use concentration, the blended product is compatible
with the usual corrosion inhibitors. However, it should
not be mixed with other chemicals prior to introduction
into the water being treated.
GENERAL PROPERTIES
2, 2-dibromo-3-nitrilopropionamide ............... 20%
Inert ingredients .............................. 80%
EPA Registration Number ............... 3876-95-34571
Appearance ........................... yellow liquid
Density(60F) ..................... 10.5 pounds/gallon
pH (undiluted) .......................... less than 7.0
cr
D
0
M
``; 10
J
a
x
a[i
t•
4
pH
1L
Graph showing the relationship between the half-life of BETZ
ENTEC 365, temperature (°C) and pH.
If retention time is insufficient, BETZ ENTEC 365 can be
detoxified with BETZ ENTEC 733. Requirements are 1.0
ppm BETZ ENTEC 733 for each ppm BETZ ENTEC
365.
PFC 365 8801

SAFETY PRECAUTIONS
A Material Safety Data Sheet containing detailed informa-
tion relative to this product is available upon request.
PACKAGING INFORMATION
BETZ ENTEC 365 is blended as a liquid, and is supplied in
30-ga►Ion (114-liter), bung -type, nonreturnable steel drums.
Approximate neLweight-275 pounds (125 kilograms) per
drum.
The product should be stored at moderate temperatures
and protected from freezing. If frozen, thaw completely and
mix thoroughly prior to use.
FREIGHT CLASS
Compounds, Industrial Water Treating, Liquid
Item 50227, Class 60

BIOCIDE/CHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is ,o be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
1. Facility Name JPS Converter ,A#1r w006N 5
NPDES # NC NC G500000
County Lincoln
Receiving Stream 7010 0 (cfs)
(All above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body
A.D.D. = 0.020 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
IWC _ (A.D.D.) x 100 _ ( .020 ) X 100
(7Q 10 x 0.646) + (A.D.D.) — ( 0 ) (0.6 4 6) + ( .020 )
100
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
I. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I
Betz Entec 365
Please list the active ingredients and percent composition:
DRIvpA 2 2-Di bromo-3-Ni tri l opropi onami dO) 20
°
Note: If ingredients contain the metals copper, chromium, or zinc, also complete page a, Suooiemental Metals Ana vs,s
What feed or dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
product used per day.
D.R.= 114 grams/day
D.E.M. Form 101 (7/92) 1

JPS Converter
acility Name:
NPDES #: INC G500000
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown, holding I on size, etc.)
Volume= 0. 65 million gallons
a ac) �l
Wf at is the pH of the handling system prior to biocide addition? If unknown. enter N/A.
7.5-8.5
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
H.L. = 0.08 Days
8.625 =Deca Rate (D.K.
The decay rate is equal to H L. X 0.69 = Y )
Calculate degradation factor (D.F.). This is the first order loss coefficient.
D.F. _ (A.Du.DD.) + (D.65
K.) = (0.05( 0.0.020 ) + (8.625 ) _
Calculate Steady State Discharge Concentration: 114
Dischg Conc. =
(D.F.)(Volume)(3785) (9.012 ) (0.05165
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
q_012
= 0.065 mg/I
)(31785)
(Dischq. Conc.) x (IWC%) ( 0.065 ) x ( 100 =
100 - 100
0.065
mg/I
Receiving Stream Concentration
III. Calculate regulated limitation.
List all LC50 data available for the whole product according to the followinc columns. (Note that units should be
in mg/1). Please provide copies of the sources of this data.
Organism Test Duration LC50 (mg1)
Rainbow Trout 96 hr. Static Acute Bioassay 5.0
Bluegill Sunfish
Daphnia magna
Fathead Minnow
Sheenshead Minnow
96 hr Static Acute Bioassay
48 hr. Static Acute Bioassay
96 hr. Static Acute Bioassay
96 hr. Static Acute Bioassay
6.5
33
6.8
7 0
D.E.M. Form 101 (7/92)

Facility Name:
NPDES #: NC
Choose the lowest LC50 listed above:
Enter the LC50: 3.3
If the half life (H.L.) is less than 4 days, perform the following calculation.
Regulated Limitation = 0.05 x LC50 = 0.165 mg/I
If the half life (H.L.) is greater than 4 days or unknown, perform the following calculation.
Regulated Limitation = 0.01 x LC50 = mg/I
Choose the appropriate regulated limitation from the calculations immediately above and place in this bank:
0.165 mg/liter
=,om Part II enter the receiving stream concentration:
0.065
mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is
unacceptable for use.
Name (Print)
Signature Date
Person in Responsible Charge
D.E.M. Form 101 (7/92) 3

Facility Name:
NPDES #: NC
Supplemental Metals Analysis
If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A
separate form must be used for each metal and/or metal compound present in the biocide. List the metal,
its chemical formula, molecular weight (MW), formula weight (FW), and the concentration of the metal
compound in the biocide (MCC). Complete a separate form for every metal present in the biocide.
Metal Chemical Formula Molecular Weight of Metal Formula Weioht Concentration in Biocide
EXAMPLE -
Copper CuSO4.5H2O 63.546 g/mole 249.680 g/mole 0.2 %
None
Dosage rate of Biocide (DR) (from page 1):
RM
rams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallons/day
Discharge Concentration (DC) of Biocide:
DR ( arams/day) grams/million gallons
DC = ADD — ( million gallons/day)
Convert DC to micrograms/liter (ppb):
DC (µg/I) = DC (grams/million gal) x 1 x1 06 µq/q = ug/I
3.785 x 106liters/million gal.
Calculate the fraction of metal in the metal -containing compound (MF):
MN ( arams/mole)
MF = FW = ( grams/mole)
Calculate the fraction of metal in the biocidal compound (BF):
BF=MFxMCC°o _
100
X (100) _
Calculate the concentration of metal in the discharge (M):
M = DC x BF = ug/I x
ug/I
Calculate the instream metal concentration (IMC) at low -flow conditions:
IMC = M x IWC (%) = ug/I x
100 100
Regulated limitation of metal (from below): ug/I
NC GeneralStatutes 15A NCAC 213.0211 define:
Copper- 7 µg/I water quality action level' Zinc- 50 µg/I water quality action level'
Chromium- 50 µg/I water quality standard
('Values which exceed action levels must be addressed directly by aquatic toxicity testing.)
D.E.M. Form 101 (7/92) 4

ENE,
BETZ
Betz Entec Inc.
200 Witmer Road
Horsham, PA 19044-0�
November 9, 1994 215 674 9200
215 675 4023 Fax
a
Ms. Melissa Rosebrock
4401 Reedy Creek Road
Raleigh, NC 27607-6445
Dear Ms. Rosebrock:
Re: JPS Converter Corporation �Z
Boger City, NC
General Permit # NCG500000
�� 1T
�n
Enclosed is a biocide worksheet for Betz Entec 367.
We are anxious and eager to apply this biocide at the subject account. Your
expeditious review is most appreciated.
If you have any questions, please contact me at [phone].
Sincerely,
BETZ ENTEC, INC.
d
Helen R. Cerra
Environmental and Regulatory Affairs Manager
H RC/Ig
Attachments

BIOCIDEJCHEMICAL TREATMENT
WORKSHEET-FORM 101
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for eacn biocidal product in use. This worksheet is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
b
I. Facility Name
J P S Converter Corporation
NPDES # NC 0004871 -
r`.niinty Lincon
Receiving Stream Unnamed tributary to Lithi a. Branch 70100 (cfs)
(All above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water cca,,
A.D.D. = .020 (in M.G.D.)
Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
(A.D.D.) x 100 ..020 ) X 100
IWC = (7Q 10 x 0.646) + (A.D.D.) — ( 0 ) (0.6 4 6) + (.020 )
100 170
This value (11,VC) represents the waste concentration to the receiving stream during low flow conditions.
il. What is the name of the whole product chemical treatment prcposea for use in the discharge identified in Part
Betz Entec 367
Please list the active ingredients and percent composition:
1-Bromo-3-Chloro-5,5-Dimethylhydantoin 92.5
Inert Ingredients 7.5
Note: If ingredients contain the metals cooper, chromium, or zinc, also complete page 4, Suoolemental Metals Ana s =
What feed cr dosage rate (D.R.) is used in this application? The units must be converted to grams of whole
proauct usea per day.
D.R.= 3.98* grams/day
*D.R. based on 0.2 ppm maximum free -available halogen residual expressed
as C12.
D.E.M. Form 101 (7/92) 1

=acm1v Name:
NPDES #: NC
Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown, holding lagoon size, etc.)
Volume= 0.05165 million gallons h`Q
J
What is the pH of the handling system prior to biocide addition? If unknown, enter N/A.
7.5-8.5
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk.
The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half
life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please
provide copies of the sources of this data.
H.L. = 0. 02Z Days
The decay rate is equal to 1 H.L. X 0.69 = 34.5 =Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient.
D.F. _ (A.D.D.) + (D.K.) ( .020 ) + (34.5 ) = 34.89
(Volume) (.05165 )
Calculate Steady State Discharge Concentration:
(D.R.) ( 3. 98 ) _ .0005 ma l
Dischg Conc. = (D.F.)(Volume)(3785) (34.89 ) (.05165 ) (3 7 8 5 )
Calculate concentration of biocide instream during low flow conditions.
(Receiving Stream Concentration)
(Dischg. Conc.) x (IWC°o) (.0005 ) x ( 100 ) _
100 100
.0005
mgil
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Note that units should bE
in mg/I). Please provide copies of the sources of this data.
Organism Test Duration LC50 (mg,l)
Rainbow Trout 96 hr. Static Acute Bioassay .87
Fathead Minnow 96 hr Static: Acute R-Ioassay 2.20
Daphnia magnna 48 hr �tatir AriitP Nioassa,�C .46
D.E.M. Form 101 (7/92)

=acility Name:
;NPDES #: NC
Choose the lowest LC50 listed above:
Enter the LC50: 0.46
If the haft life (H.L.) is less than 4 days, perform the following calculation.
regulated Limitation = 0.05 x LC50 = 0.023 mg1l
If the half life (H.L.) is greater than 4 days or unknown. perform the following calculation.
Regulated Limitation = 0.01 x LC50 = mg/l
Choose the appropriate regulated limitation from the calculations immediately above and place in this bank:
0.023 mg/liter
From Part II enter the receiving stream concentration:
0.0005 mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the calculated regulated limitation, then this biocids is
unacceptable for use.
Helen R. Cerra
Name (Print)
Environmental & Regulatory Affairs Manager
November 2, 1994
Signature Date
Person in Responsible Charge
D.E.M. Form 101 (7i92) 3

aciiity Name: NPDES #: NC
Supplemental Metals Analysis
If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A
separate form must be used for each metal and/or metal comoound present in the biocide. List the metal,
its chemical formula, molecular weight (MW), formula we!ent (FW), and the concentration of the metal
compound in the biocide (MCC). Complete a separate form for every metal present in the biocide.
Metal
s
EXAMPLE
Copper
None
Chemical Formula Molecular Weight of Metal =ermula Weight Concentration in Biocide
CuSO4.5H2O 63.546 g/mole 249.680 g/mole 0.2 0%
Dosage rate of Biocide (DR) (from page 1):
DR = grams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallons/day
Discharge Concentration (DC) of Biocide:
DR ( arams/day) grams/million gallons
DC = ADD -million ( million gallons/day)
Convert DC to micrograms/liter (ppb):
� �o
DC (µg.,l) = DC (grams/million gal) x 1 x ug/q = ug/I
3.785 x 100 liters/million gal.
Calculate the fraction of metal in the metal -containing compound (MF):
1VIVY ( crams/mole)
MF = _ ( crams/mole)
Calculate the fraction of metal in the biocidal compound (BF):
MCC (°0) _
BF=`.1Fx 100
a,
x (100) _
Calculate the concentration of metal in the discharge (M):
M = CC x BF = ug/l x
ug/I
Calculate the instream metal concentration (IMC) at low -flow conditions:
IMC = M x IWC (%) = ug/ _
100 I x 100 ug/I
Regulated limitation of metal (from below): ug/I
NC Generai Statutes 15A N AC 23.0211 define:
Copper- 7 µg/l water quality action level' Zinc- 50 µg/1 water quality action level'
Chromium- 50 µg/I waver c::a;ity standard
('Values which exceed action levels must be acdressed directly by aquatic toxicity testing.)
D.E.M. Form 101 (7/92) 4

ll/,Ie/ID4 16:14 ROGER CITY PLANT NO.019 001

11/10/d9 1D.aV- _L BETZ hN'1'hU, 1NC.
LC001/009
SIOCIDEICHEMlCAL TREATMENT
WORKSHEET-FOAM 101
The following calculations are to be performed on any blocidal products uitlmatety discharged to the SUH&cie-Naterg Of
North Caroling, This worksheet must be completed separately for each blacloal product in use. This worksheet is ;o bi
,etumed �Wth all appropriate data entered Into the deslgnated areas with calculations p0ormed as indicated,
raellity Name J P S Converter Corporation
NPDES # NO W 0_0045ZI
County Lincon
Receiving Slream Unnamed tributary tq Lithi a 0 Brang� 7010 (cfaI
(All above information suppilea by the Division of Environmental Management)
What is the Average Dolly 01�charge (A,D.D,) volume of the water handiing systems,to the receiving water xc
A,D,D, . .020 (in M,G,D.)
Please Calculate the Instrearn Waste Concentration (IWC in paresnt) of this disonarge using the data enterso
above,
A,b.D,) x 100
In ' (7 Q 10 x 0. 6 4 + (A, 5,D,)
(.020 X 1001
( 0 )(0-646) + (.020 )
Thla value (IWC) represents the waste concentration to the receiving stream duringllaw few coneltions.
What Is the name of the whole product chemical treacnant proposed for use in the OlacMarge idenimea tr, Par
Betz Entec 367
Please list the active Ingredlents and percent composition;
1-Bromo-3-Chloro-5,6-Dimethylhydantoin 92.5 %
Inert Inoradient s- �^ °1e
%
Note., it Ingr4dlems COntai) the. metals Copper, chromium, or time, a.ee camplatm Paso a, n I a T I mix - I
What feed er doegge rate (C.R.) Is useo i' this applicaticn? The Units must t:a conv�rted to grama at whais
product used per day.
D.R.■ 3.98* -- grams/day
*D.R. based on 0.2 ppm maximum free -available halogen residual expressed
as C12.
D,E.M. Form 101 (7/92)

11/ Lo/Oy 1a. nu y --__ __._.
=acai!av Name: BPS Convet•ter NPOES 0: NC 13500000
Ssti,rate total volume of the water haandilrtg system norwoon entry of blocidal product and NPDES d!3cna3rge
point. On an attached shoat please pravida juatfficatlon for this estimate (system volume, average cyeles per
blowdown, holding lagoon size, eto.)
Volume• 0.05165 million gallons
What Is the pH of the handling system prior to blocide addition? If un,4nown, enter NIA. 7.5-8'5
a
What Is the decay rate (DX) of the product? If unknown, asauma no dotty (DA -0) and pmesed to asterisk.
'f'he degradation must be stated at pH level within /2 pH stasrdaard unit within handling system. Enter Ina Wait
life ;Haft Life is the time required for the initial prodL:t toydegrade to ha:f of its original concentration), = ease
provide copies of the scurcels of this data.
H,L. %v 0.08 Qaya
The decay rate is equal to H�L X 0.69 $.626 -Decay Rate (O.K.)
Calculate degradation factor:(D.F.). This is the first order loss coefficient.
A.D.Q. ( ""L 012
(Volume) (0.05165 )
Calculate Steady State Discharge Concentration;
14
lWg Conn, - (a,R.)
C W 0.065 mil
(D.F,)(Volurne;(~3785) ( 9.012 ) {0.06166 } { 0 }
Calculate concentration of bipcide instrearn during ow flow canditions,
(Recelving Stream Concentration)
cOischa, cone) x (IWCPIgl ( 0.065 „1 9 f 100 ) 0.065 mgn
100 - 100
4oniving Stream Concentration
ill, Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns, (Note that units shou:c t
in mq/q, please provide copies of the sources of this data.
Organism
Test auraton
Rainbow
Trout
96
hr. Static Acute
Bioassay
Bluegill
Sunfish
96
hr. Static Acute Bioassay
Daphnia
rnagna
46
hr. Static Acute Bioassay
Fathead
Minnow
96
.r,r. Static Acute Sioassay
Sheepshead Minnow
96
hr. StA:I; Acute BiIlaasay
D.E.M. Form 101 (7/92) 2
LC50 (mg^)
5.0
6.5

11/12/94 1s:16 BOGER CITY PLRNT Nu.b1'-4 a'it
++1..v10V AV. j 1- l3ETZ EINTEC, INC. OOT/009
Iaciiity Name :
JPS Converter ,Npp; NC
ig3 *G500000
Choose the lowest LC50 I18160 above:
Enter the LC50: 3.3
It the haft life (H.L.) la lees thar, 4 days, perform the tollowing calculation,
Regulated Limitation ■ 0.03 x LCSO 0.165 MWI
f fhe half life (H.L.) Is greater inan 4 days or unknown, perform the following 041Culatlon.
Regulated Limitation - 0,01 x LC50 m i
Choosy the appropriate regulated limitation Irom the calculations Irnmediateiy above and place In this blank:
0.165 mg/ilter
From Part II eater the receiving stream concentration;
0.065 ��,mfl�llter
IV, Analysis.
it the reC@IvInq stream concentration is greaser than the calculated reguAteo iimitatlon, then this biocide Is
unacceptable for use.
r
Name (Prtntl
Zuc
Spnature Dale
Person In Re:.ponsible Charge
D.E.M. Forty. 101 (7/92) 3

11 i 12/94 _ G ; 17 BOGER C I TY PLANT NO. 019 008
1.1/18/a4 10,az 'Q b6i'L L"NIV— 1NU. 4009/002
SIQCIDElCHEMiCAL TREATMENT
WCaKSHEET•FOAM 101
T,he following calculations are to be parformaa on any blociaa! :roducts ultimately dlsoharged to the surface waters of
'.ottrt Carolina, his worksheet must he completed separately for each biocidai product in use. This workshest is to bi
returnea jith all appropriate data entered into the designated areas with calculltlons performed as indicated.
Paoiltty Name JP5 Converter
NPDES # NC NC G500000
County Lincoln
Receiving alreom 7Q1 G 0 (ofe)
(All above information suppiiea by the f01visiom of Environmental Management)
What Is the Aver8ge [)ally Dipcharge (A,D.D,) volume of the water handifnQ eyatarrt: tQ thr rouiving water ood'
A.D.D.. 0.020 (in M,(3.D,)
Please calculate the instream Waste Concentration OWC In peroRnt) of this discharge using the data entered
above,
x 100 .020 X 100
IWC (7 10 x + (A. D.) 0 )(0.640) .020
100 %
This value (IWC) represents the waste tc^tcentratio n to the receiving stream during low flow conditions.
What !s the name of the whgie product chemical treatmant proposed for use in the discharge Idrntified in Pan
Betz Entec 365
Please list the active ingraelents and percent camposRion;
nanlpa j2.2�Di romo- -N qx��-�,�j�a1 20 %
Ye
Now if ingrodients Contain the metals GQpPgr, c,,�roRTium, or zinc, a110 complete page 4, lideienvial h�1Qt�I�.An v�
what Iced or dosage rate (DA) is usso'n this application? The units must be converted to grams of whole
product used per day.
D P 114 gramsrday
10.E,M, form 101 (7/92)

0
11/10/�!+! la:Jl
%i
aai�. L:�iLt+r 1+�.+•
��•vr•.vvv _.•
?ac;lity Name:
JPS
Converter--
NPOES e�
NC
0004871
Estimate total volume of the water hsnaling system between entry of blo:idal product and NPCIES discharge
point. On an attached sheet please provide justification for this estimate (system volume, average cycles per
blowdown, holding lagoon size, ete.)
Volume. 105165 miillon gallons
gist Is the pH of the handling system prior to dlocide addition? If unknown, enter WA, 7.5.8.5
What is the decay rate (D.K.) of the product? If unknown, assume r,,o cecuy (D.K.■o) and proceed to averlsk.
The degradation must be stated at pH level within 1/7 pH standard unit within handling System. Enter the halt
life (Half Life is the time required for the Initial product tadegrade to half Qf Ita original concentration). Please
provide oopies of the eouroe8 of this data.
H.L. ■ 0.02 pays
The decay rate is equal to H- - K 0,69 34.5 •Decay Rate (OX)
Calculate degraeation factor (O,F,), This is the IV order loss coelicient.
D.F. (Vo me) + AK.) ( .0516502Q ) + ( 34.5 ) ■ 34.59
Calculate Steady State Discharge Concentration:
rn a
Dlschg Canc. ■ - - '- .0005 mgN
(D.F•);Volume)(3785) ( 34.89 ) (.051b5 (3 y 6 )
Calculate concentration of biocide instrearn during low flow conditions.
(Recelving Stream Concentration)
tDischQ, Gonc.l x 0WCY.1 ,_j&005 ;_ x ( 100 .0005 mgrl
100 100
Receiving stream catteeAtrailar
Calculate regulated limitation,
List all LC50 data available for the whole product according to she following columns. (Note that units should n
In mgii), Please provide copies of the sources of this data.
Orgarw Test Duration LCW (inyt)
Rainbow Trout 96 hr. Static Acute Bioassay
Fathead Minnow 25
_ 4 f�C. Starir Ar i+. rri0dS&Lg_=
Daohfli� magna R t,r Static snits Bioasra%i 066
D.E.M. Form 101 (7/92) 3

11/ 18/G4 16: 16 BOGER CITY PLANT NO. ©19 005 �1005/OOD
11�1r5�a4 je:sl � � 8b1�+ �1418L. 11�L.
=acility Name:. JPS Converter NPDES #, NC nnnaazY
Choose the lowest LC50 116140 above:
Inter the LC50: 0.46
If the hag life (H.L,) is lose than 4 days, perfomn the following calculation,
Regulated Unlltation ■ 0.05 x LC50 - Q.C23 — mg1l
If tie half life (H.L.) Is greater tnAn 4 days or unknown, perform thf following calculation.
Regulated Umitation ■ 0,01 x L050 mpr*l
Choose the appropriate rrgulated firnitatlon from the cslewlatians Immediately above and plat* In thil bank;
0,023 mg/llter
Frorrf Part It ont9r the recafvino stream conerrtuatlon:
0.000$ mgmter
IV, Anaiyais.
!f the receiving stream concentratlon is greater thin tha calculated ragulated Ilmltatlon, then this blocietr is
unacceptable fgr use.
p � �r
Natrre (Pont)
Dr�e
Person In Responsible Charge
D.E.M. Form 101 (7/92) 3

i 1/219,11,94 17:15 SC-113ER C.7� F'LkIT I Cl. Cl 71
lb
ZL?— Y3;.r�-
FAX PAGE
JPS CONVERTER & INDUSTRIAL CORP. PAGE(S)
BOGER CITY PLANT
LINCOLNTON, N.C. 28092
TELEPHONE 704— 735— 2581 - FAK 704-736-1808
OF
A:FA.NFM,WK3
TO: AT:
M AT:
CC: AT:
REFERENCE:
MESSAGE: A�/
z9
FROM: DATE:
LOCAL COPIES:

11:29/' 4 17: 1 BOGER C'7 T`i' PLANT HO. 037 002
+r•V9 ! BETZ ENTEC, INC. 2 006/00
BIOC3�f"1CHlwMICAL TFIPATMFNT
*RKSHEET-pORM 101
The following calculations are to be performed on any blocidal products uJtlmotely d?80harged to the surlace waters of
Ncnh Carolina. This workshoet must he completed separately for each bioeidai product In woo, This worxsnaat is to t
returned wiih all appropriate data entered into the designated areas with calculations performed as indicated
Facility Nara JPS COnver
NPO ES * NO N C 6 . S-D66-7 7
County Lincoln
Receiving Stream ,T lAnAt-:a rQy)Lh -- ,7010 0 (cfs)
All above Information sUpplled by the !Division of Environmental Management)
What I8 the Average Daily Clachuan2e (A.O.D.) volume of the water handling systems to the receiving water Doc
A.D.O. - 0-02�, (in M,a.[).)
Please calcuiate the Instrearn Waste Concentration (IWC In pgrcant) of this discharge using the cata enterab
above.
A.D.Q. x 100
(7 I x 4 '+ (A )
100 _%
( 0.2 X 100
(o �(0, 6 4 6) +
This value (IWC) represents the w€fate concentration to the recelving stream during low flow conoitions.
i, What is the name of the whole product chemical trsatmr3nt proposed for use in the discharge identifloo in -art
Betz Entec 345A *See bottom of page for two _ingredients,
Please list the active ingreglents and percent composhicin:
OSNPAs2,2-Dibromo-3-Nitriloar__ooionamide) 5.0X a,
Sodium Bromide 110% `%
01bromoacetonitrile „ 251 %
Monobromo-3-Nitriloprop'lonamide 25% y,
262-01bromoprovangdiartif_cie .25% %*N bottom
o page
Note: If ingredients contain tho meals copper, chmmiurm. er zinc, also complete pegs 4, „"I9men!2Malmo en . v!1
What faed or dosage rate (O.R,) Is used in lhls application? The untta must be oanveRad to g�Ama of whole
product used per day.
DAM +454 gram$, day
D.E.M. Fo= 101 (7/92)
*Polyethylerue Glycol
Water
309
63.25%

11r29i94 16 BOGER C"TY PLANT NO. F37 00s C002/uuo
14/29/94 17:06 n 1--.-• ­ .- _. .
41
: JPS Converter
'Vp0jS 0: NC G 500000
aci<<ty Nam$
Estimate total volurr.9 of the water hanoling,aYstem detween entry Ot blocidal product and NPDES discharge
Point. On an attached sheet please provides Iustificsdon for tnis estimate (system volume, average Cycles per
blowdown, holding lagoon 50, etc.,)
volume. 0.0292 million gallons
7'
What is !r,e pH of the handling syst�sm Prior to bi"'cla addition? if unknown, enter NIA.
What is the decay rate (O.K•) of the product? if unknown, assume no decay (D.K,•0) and proceed to asterisk,
The degmdatlan must ae stated at pH Ievei within 1 /2 pH standard unit within handling sy
stem. Enter the hail
life (Hail je Is the time required tot the initial product 101"aegrada to halt of its original Concentration). Please
provide copies of the sources of this data
H.L.- 0.08 0aya
The decay rate is equal to HX 0.61, ■ 8,625 ■laecay Rate (O.K.)
Calculate dearadatlon factor (D.F.Y. Tills Is the first order loss coefficient.
A D t 0.020 r 9.309
C.F. • (vat' lu + (D.K.) ■ 0.0292 +
Calculats Steady State Discharge Concentration: 454 0.44 m�i
D.R Discrtg Cona. (p,F )(volurne)(3785) ( 9. Q9 ; 0.0292 ) (3 7 8 5 )
Calculate concentration of blocide instream during low flow condltlone.
(Receiving Stream Concentret(an)
t o 44 , 100 mg�
�D(scna. Gong,)_ x (iWC°/,1 x 0.44
100 I
'� 00
RICIMnp Stream Canc�niretio�
�I. Calculate regulated (Imitation.
Liar ail 'LC50 data available for till? whcle product accc^aing to the following colurnn5. (Nate that units should t
in m 1). Pieaaa provide coplea ol'thd sources of this data.
To Duration t,C50 (mG'tf
96 hr. Static Acute,Sioassay 9.2 _
ehms-
48 hr. Static Acute Bioassay 11,2
Organism
rainbow Trout
Daphnia magna
D.E m. Form 101 (7/92) 2

11 i'29/ 94 1 ^r : 16 EiOG=P C :: TY PLANT NO. 037
r 11/ LM/ }!4 11 : UO 7.i' tsr,'1L �ii125t,'1N4:. 009/008
=acdity Name: JPS Converter NPOES 0: NC G 500000
Choose the lowest LCSO Ilsteo above:
Enter the LC50: 9.2 _
:f the half life (H,L.) Is fuss than 4 days, peHarrn the following calCulatfgn.
Regulated Limitation • 0.05 x LCSO a 0,46 mWl
If the had Iife (H.L.) Is greater than 4 days or unknown, perform the following calculation.
Regulated Urnitatlon - 0,01 x LC50 ■ mglI
Choose the appropriate regulated limitation from the calculations Irrmedfately above and place in this b:ank:
0.46 m8/liter
?ram Part 11 enter the receding struAm canaentration:
0.44 mg;;ifer
IV. Analysis.
If the receiving stream concentration is grotar than the calculated regulate# HrMatlon, ,!+rn this blocids Is
unacceptable for use,
Name ( rn)
SJgr�u Data
Person in Responsible Charge
D.E.M. Form 101 (7/92)

V
1
11/Lb/W4 1f:UI
xx
iSlSiL 8PI1L'l., 1PlG.
WUVD/VVO
4.
Rainbow Trout
Daphnia magna
M
-AO-VATIC TOXICITY DATA -
I$etx €Oteg 345A
96 hr. Static Acute Bioassay LC50 9.2 mg/L
48 hr. Static Acute Sioassay LC50 11.2 mg/L
The active ingredient in Entac 34EA degrades rapidly in aqueous, alkaline systems
(particularly above pH 4.0) to yield predominantly dibromoacetic acid which is
approximatel,yy 100 times less toacic than the original active ingredient,
dibromonitrilopropionamide.
Hydrolysis of QBNPA ultimately forms carbon dioxide, ammonia and bromide ions via
the following sequence of degradation products: dibromoacetonitrile,
dibromoacetamide, dibromoac.etic acid, glycolic acid and oxalic acid. OBNPA reacts
rapidly with various ions such as bisulfite to form cyanoacetamide. Decomposition
under the influence of sunlight also leads to the formation of Cyanocetamide.
Contact with soil organisms degrades QBNPA. A detailed discussion on the rates
and products of QBNPA decomposition may be found in J. Agr, Food Chem., Vol. 21,
No. 5, pp. 838 - 42, 1973, by J, H. Exner et _id.,
Tests performed in accordance with criteria set forth in the "Practice for Conducting
Acute Toxicity Tests with Fish, Macro invertebrates, and Amphibians" (ASTM Standard
E729-88),

DIVISION OF ENVIRONMENTAL MANAGEMENT
February 16, 1993
Memorandum To: Susan Robson
From: D. Rex Gleason
Prepared By: Kim H. Colson K�'i/X�-_
Subject: JPS Converter and Industrial Corp.
NPDES Permit No. NC0004871
Lincoln County, NC
This Office has reviewed the request for coverage of the
subject facility under General Permit NCG500000. It is recommended
that the facility be covered by the General Permit.
If you have any questions concerning this matter, please
advise.

James G. Martin, Governor
William W. Cobey, Jr., Secretary
d ✓�
f N rth Carolina
ECEIVED
R
N.C. Dept. of EHNR
%oV 3 n 1992
\Kinston -Salem
Regional Office
State o 0 h and
Department of Environment, oEnvironmental
Management al Resources
Divisionf
rth Salisbury Street • Raleigh, North Carolina 27611
512 No
Preston Howard, Jr., P.E.
Acting Director
0
November 25, 1992 \ I b �
l At^
Mr. Samuel H. Griggs
JPS Convertor and Industrial Corp.
33 Stevens St.
P. O. BOX 208 �. G DEpT. Of, NATURAL
Greenville, SC 29602 RESOURCES AND
COMMUN13-y pl.,NELOPNMNT
Subject: NPDES:Renewal Application
NC0004971
JPS Convertor and In ,uN-r�
.0 � dr-Gounty -- co �.. N
Dear Mr. Griggs: VVISIOII you about the response to
YOORE UE REx6011AL 0FHCF
this letter is to inform y
Per our conversation on November 16, 1992, estion for using sodium sulfite to dissipate
your biocide approval request. We have reviewed your Bugg
and have agreed to that procedure providd you
and also provide
monitoring data
tion of the
the remaining halogen1 the sodium sulfite to the waste stream
methods you will use to apply
showing that it will completely reduce the residual halogens. a while, our policy on low -flow streams
Even though you have been utilizing these biocides forinto
since your last issued permit. Thus, the use of such biocides in facilities discharging
has changed
such streams has been made more restrictive.
have uestions regarding this matter, please contact Susan Robson at [phone].
If you Q
Sincerely,,
Coleen Sulling, P.E.
Supervisor, NPDES Group
A. �ObiQ�i ��sz✓
C? Regional Office
�� �' gi Unit
Permits and En neering
TN
k,I Central Files
L?
D t Regional Offices
I':•f Raleigh Washington Wilmington Winston-Salem
Asheville Fayetteville Mooresville 919/896-7007
704/251-6208 919/486-1541 704/663-1699 919/571-4700 919/946-648] 919/395-3
M!_
Pollution Prevention Pays
I: P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone]
fa An Equal Opportunity Affirmative Action Employer
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N
JPS
CONVERTER AND
INDUSTRIAL CORP.
BOGER CITY PLANT
January 7, 1993
H- C. Jlk:. i . Of' r(,a'ruttAk.
RESOURCES AND
COMMUNITY DEVELOPMENT
Ms. Susan Robson .��N 1 1 i993
NC Division of Environmental Management
512 North Salisbury Street
Raleigh NC 27611 EMIR OF 1?;1/ ;rH-;T'TAL i tk !! !EMT
NUORES IUI E GEG1601 OFFICE
RE: JPS Converter & Industrial Corp.
Boger City Plant
NPDES: NC 0004871
Lincoln County
Dear Ms. Robson:
This letter is in response to your letter of November 25,
1992, concerning biocide usage and assurance of depletion
of any residual chlorine in the discharge to the creek.
We have been monitoring for residual chlorine routinely
for more than two years and have maintained residuals of
less than 0.01 mg/liter. We propose to add a sodium or
sodium bisulfite solution to our discharge at a concen-
tration sufficient to distroy any residual chlorine.
We will maintain a daily log indicating the pumping rate
and assuring that sufficient solution is available to be
pumped. The completed system will be installed by
February 1, 1993.
If you have any questions concerning this please let me
know.
Sincerely,
L7�L `,,- � U
Emmett W. Eagle,
Plant Manager
CC: Sam Griggs/Greenville SC
Mooresville Regionald Office
EWE/kwm
2130 E. MAIN ST. 9 P.O. BOX 658 • LINCOLNTON, N.C. 28092 • (704) 7 35-2581 • FAX [phone]

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� EFFLUENT OCT 1 5
N PDES PERMIT NO: 'QC ;, 7 0'? �? % DISCHARGE NO: MONTH: YEAR:,.
FACILITY NAME: Belding Hausman Inc. CLASS: I COUNTY: L ncol nton
OPERATOR IN RESPONSIBLE CHARGE (ORC): 12; ,zk Sa; Q. GRADE: T
CERTIFIED LABORATORY: Belding Hausman Inc.
CHECK BLOCK IF ORC HAS CHANGED PERSON(s) COLLECTING SAMPLES: Earl Proctor
Mad original ar.d one copy to I CERTIFY THAT THIS REPORT
ATT Central Files IS ACCURATE AND COMPLETE TO ©�
Division of Environmental Management
N C Department of NRCD ` \
PO Box 27687 THE BEST OF MY KNOWLEDGE
Raleigh North Carolina 27611 j(
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Facility Status: ( Please check one of the following)
All monthly averages and / or other limitation do meet permit monitoring requirements
( Compliant)
All monthly averages and / or other limitation do not meet permit monitoring requirements =
( Noncompliant)
If the facility is noncompliant, please comment on corrective actions
being taken in respect to equipment, operation, maintenance, etc. and
a time table for improvements to be made.
( Attach additional sheets if necessary)
I certify that this Report is accurate
and complete to the best of my knowledge:
-----------------------
Signature of Permittee
PARAMETER CODES
00010
Temperature
00556
Oil and Grease
00950
Dissolved Fluoride
01077
Silver
39516
?CBS
00065
Stream Stage
00600
Total Nitrogen
01002
Total Arsenic
01087
Total
Vanadium
39941
Roundup
00076
Turbidity
00610
Ammonia Nitrogen
01027
Cadmium
01092
Zinc
50047
Max. flow during
24-hr. period
003nn
Dissolved
1)00;25
Total K4eldahl
01037
Nexaval-nt
n1105
Total
A!,-nin=
50048
?-i.a. flow during
Oxygen
Nitrogen
Chromium
24-hr. period
00310
BOD_
00665
Total Phosphorous
01034
Chromium
01147
Total
Selenium
50050
Flow
00340
COD
00720
Cyanide
01037
Total Cobalt
31504
Total
Coliform
50060
Total Residual
Chlorine
00400
pH
00745
Total Sulfide
01042
Cooper
31614
Fecal
Coliform,
71880
Formaldehyde
MPN,
Tube
00500
Total Solids
00927
Total Magnesium
01045
Total Iron
31616
Fecal
Coliform
71900
Mercury
00530
TSS
00929
Total Sodium
01051
Lead
3r 30
Total
Phenolics
81318
Ferrocyanides
00545
Settleable
00940
Total Chloride
01067
Nickel
38260
MBAS
85652
Time
Solids
The monthly average for fecal coliform is to be reported as a geometric MEAN.
If using alternate units for reporting data, please designate.
OCI 9 Luv!
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a50007:7 DISCHARGE MC), 001 MONTH: Pot . YEAR: 01
PLITPYNAPAME:�Rel di ncr Hausman Tn . C04JNTY:Llnco1n
STREAM: Boa r Creek 50 yds. Above Eff STREAM' Roger Creek 50 yds Below Eff
Upstream
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LOCATION: Outlet Boger City
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CENTRAL. FILES